EPA 904/9-78-023
DECEMBER 1978
VOLATILE ORGANIC COMPOUND
EMISSION INVENTORY FOR
TENNESSEE EASTMAN COMPANY
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION 4
AIR AND HAZARDOUS MATERIALS DIVISION
ATLANTA, GEORGIA 30308
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This document is available to the public through the
National Technical Information Service, Springfield,
Virginia 22151.
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EPA-904/9-78-023
VOLATILE ORGANIC COMPOUND EMISSION INVENTORY
FOR TENNESSEE EASTMAN COMPANY
by
Arthur B. Nunn III
TRW Environmental Engineering Division
201 N. Roxboro St., Suite 200, Durham, North Carolina 27701
Contract No. 68-02-2541
Task No. 3
Winston Smith, Project Officer
Air Programs Branch
U. S. Environmental Protection Agency, Region 4
345 Courtland Street, N. E.
Atlanta, Georgia 30308
Library/Region IV
U.S. Environment! Protection Agency
345 Courtland Street, N.E.
Atlanta, Georgia 30308
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This report was furnished to the Environmental Protection
Agency by the TRW Environmental Engineering Division in fulfillment of
EPA Contract No. 68-02-2541, Task No. 3. This report has been reviewed
by the Air Programs Branch, Region 4, EPA, and approved for publication.
Approval does not signify that the contents necessarily reflect the views
and policies of the Environmental Protection Agency, nor does mention of
trade names or commercial products constitute endorsement or recommenda-
tion for use.
ii
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ACKNOWLEDGEMENT
This study was performed for the Air Programs Branch, Region 4
of the U. S. Environmental Protection Agency. The technical direction and
assistance of Mr. Archie Lee and Mr. Winston Smith of the Air Programs Branch
in the execution of the task is gratefully acknowledged. The successful
completion of the study is due in large part to the excellent cooperation
extended by the staff of the Tennessee Division of Air Pollution Control,
particularly Mr. Doug Kemper. In addition, the outstanding cooperation
of Mr. Ron Lewis and numerous other members of the Clean Environment Branch
of Tennessee Eastman Company is greatly appreciated. The assistance of
Mr. Radford C. Adams, Mr. John Dadiani, Mr. Stephen W. Mulligan, and
Mr. Conrad W. Petersen of the TRW Environmental Engineering Division in the
data collection and report preparation of this project is gratefully
acknowledged.
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TABLE OF CONTENTS
Acknowledgement -jj
1. Introduction
2. Background 2-1
References for Section 2 2-2
3. Methodology 3-1
References for Section 3 3-4
4. Results 4-1
Appendix A VOC Emission Sources A-l
Appendix B Pilot Plant and Laboratory emissions B-l
Appendix C Compound Specific Emissions C-l
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vi
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SECTION 1
INTRODUCTION
An emission inventory of volatile organic compounds (VOC)
has been compiled for the Tennessee Eastman Company complex in Kingsport,
Tennessee. This facility is located in an area which is not attaining the
National Ambient Air Quality Standard for photochemical oxidants and has
therefore been designated a non-attainment area by the Environmental Protection
Agency. Under the requirements of the 1977 Clean Air Act Amendments a revi&ed
State Implementation Plan (SIP) is required for all such areas and must contain
a current emission inventory. The SIP must be submitted to the EPA no later
than January 1, 1979 and must be approved by July 1, 1979. This emission
inventory is designed to aid the Air Pollution Control Division of the State
of Tennessee in the preparation of the required implementation plan.
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SECTION 2
BACKGROUND
Under the mandate of the 1970 Clean Air Act, the U. S. Environmental
Protection Agency (EPA) promulgated primary and secondary National Ambient Air
Quality Standards (NAAQS) for six criteria air pollutants.Each state and
territory was then required to submit to the Administrator of the EPA a plan
for implementation, maintenance and enforcement of the air quality standards for
each air quality control region (AQCR) within the state. Also included in the
plans were attainment dates for the air quality standards in each AQCR. In
those states that did not meet their attainment date a revised State Implementation
Plan (SIP) was required which demonstrated attainment of the standards. The
Clean Air Act Ammendments of 1977 retain the fundamental approach to air pollu-
tion control and also retain the SIP as the mechanism for instituting this
approach. Under the 1977 amendments, each state is required to submit to the
EPA Administrator a list of air quality control regions which have attained
the standard, those which have not, and those for which there are insufficient
data for classification.
For the air quality control regions not attaining the standards,
the respective states must submit a revised SIP by January 1, 1979 which
demonstrates attainment of the standards as soon as possible but not later than
December 31, 1982. For photochemical oxidants an extension to 1987 is available
if the state demonstrates that attainment by 1982 is not possible utilizing
reasonably available control technology. The 1977 Amendments specify that the
revised SIP include a comprehensive, accurate, and current inventory of actual
emissions from all sources. Toward satisfying this requirment, an inventory of
volatile organic compound (VOC) emissions has been compiled for the Tennessee
Eastman Company in Kingsport, Tennessee.
2-1
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REFERENCES
1. Clean Air Act, 42 U.S.C. 7401 et. seg., as amended by the
Air Quality Act of 1967; Clean Air Amendments of 1970, PL 91-604;
Clean Air Act Amendments of 1977, PL 95-95, August 7, 1977.
2-2
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SECTION 3
METHODOLOGY
This section describes the general approach and methodology
that was utilized in compiling the volatile organic compound emission inven-
tory for the Tennessee Eastman Company Plant.
3.1 GENERAL APPROACH
The data presented in this document are the result of the
collection and analysis of information dealing with the operation of known
sources of VOC emissions within the Tennessee Eastman Company complex. The
study was conducted in two phases, the first being a review of current permit
applications and the second being a plant survey.
3.2 PERMIT REVIEW
All current permit applications submitted by Tennessee
Eastman w3re reviewed at the Office of the Tennessee Air Pollution Control
Division. Emissions were recorded for each permit unit which corresponds to
each building number within the plant. Emissions of only those compounds
which are photochemically reactive were recorded. In order to distinguish
reactive from non-reactive substances the EPA guidelines, as published in the
Federal Register of July 8, 1977 were followed. The compounds listed in
table 3-1 were not included in the inventory and are therefore exempt from
regulation. The compounds listed in Table 3-2 are of low photochemical
reactivity but do contribute to oxidant formation during periods of multiday
stagnations. They are, therefore, included in the inventory.
3-1
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TABLE 3-1 VOLATILE ORGANIC COMPOUNDS EXEMPT FROM REGULATION
UNDER STATE IMPLEMENTATION PLANS
METHANE
ETHANE
1,1,1- TRICHLOROETHANE (METHYL CHLOROFORM)
TRICHLOROTRIFLUOROETHANE (FREON 113)
TABLE 3-2 VOLATILE ORGANIC COMPOUNDS OF LOW REACTIVITY
PROPANE TERTIARY ALKYL ALCOHOLS
ACETONE METHYL ACETATE
METHYL ETHYL KETONE PHENYL ACETATE
METHANOL ETHYL AMINES
ISOPROPANOL ACETYLENE
METHYL BENZOATE N, N-DIMETHYL FORMAMIDE
All permits were reviewed with the following information
recorded:
PERMIT NUMBER
BUILDING NUMBER
PROCESS DESCRIPTION
SOURCES WITHIN EACH BUILDING
EMISSION RATES (TONS/YEAR)
POLLUTANT(S)
TYPE OF CONTROL EQUIPMENT
CONTROL EFFICIENCY
The information was then placed in order by building numbers and emissions
were rounded to the nearest tenth of a ton. All points with emissions of less
than 0.05 tons/year were considered negligible and were not reported.
3-2
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3.3 PLANT SURVEY
The second phase of the study involved a visit to the plant itself.
The purpose of this was to verify the accuracy of all of the data collected
from the permit applications. Specific areas of interest include:
(1) Verification that all sources were covered
by permits.
(2) Partial operation of any sources during 1977.
(3) Method of measurement or estimation of emissions.
(4) Method of measurement or estimation of control
equipment efficiencies.
Meetings were held with representatives of each plant area within
the Tennessee Eastman Complex. The meetings were followed by a tour of each
section of the facility with the appropriate representatives. Within each
area several representative sources were studied in depth in order to
determine the validity of the data reported in the permit applications. TRW
personnel were not granted entry into the VEREL Polymer section of the plant.
This included buildings 102 and 194. The method of emission estimation for
these buildings was discussed with the plant area representatives.
For instances where the data were obtained by measurement, the
method of sample collection and analysis was investigated for applicability
and accuracy. For cases where the emissions were estimated, the method of
estimation was investigated for accuracy. This procedure was also carried
out to determine the validity of reported control equipment efficiencies.
The results of both phases of this study are presented in the
following section with a detailed listing in Appendix A. In Appendix C is a
listing, by compound, for those compounds emitted in excess of 50 tons per
year.
3-3
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3.4 LABORATORY AND PILOT PLANT FACILITIES
A listing of laboratory and pilot plant facilities by building
number was obtained from the Tennessee Eastman Company. These buildings
were then checked in the permit files of the Tennessee Division of A1r
Pollution Control and the reported emissions were recorded. These emissions
are listed in Appendix B. Tennessee Eastman Company is in the process of
reviewing and updating the emission estimates from all laboratories and
pilot plants. The method of estimation for each building is the material
balance method as previously described.
3-4
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REFERENCES
1. "Recommended Policy on Control of Volatile Organic Compounds,"
Federal Register, Vol. 42, No. 131, July 8, 1977. pp. 35314-35316.
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SECTION 4
RESULTS
A listing of emissions from each source within the Tennessee
Eastman Complex is presented in Appendix A. The total emissions for the
plant are 12,390.5 tons per year for 1977. This figure and the listing in
Appendix A include all sources within the Tennessee Eastman Plant which were
in operation during 1977. All figures are based on a 100% production rate
for the entire year. Meetings with plant area representatives revealed that
all operations within the plant operated at virtually full capacity during
1977. Any less than full capacity operations were not reported in the permit
applications therefore the reported figures may be slightly higher than actual.
No new operation came on line during 1977 for which there was no permit appli-
cation on file with the State of Tennessee.
Less than half of the sources within the plant have been tested for
VOC emissions. The procedure consists of sample collection in an evacuated
chamber for subsequent laboratory analysis. Analysis is usually carried out
using gas chromatography. In the case of acetic acid emissions, however,
analysis is performed by a pH titration with standardized NaOH. In many
cases the stack flow is measured continuously. In other cases it is measured
at the same time the gas sample is collected.
Measurements to determine control equipment efficiencies are made
in a similar manner with samples being collected at the inlet and outlet of
the unit. This type of process is used to determine the efficiencies of all
carbon adsorbers in the plant.
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For sources where there were no physical measurements made, emissions
were estimated by material balance calculations. The quantity of raw materials
used is, of course, known as is the quantity of products yielded. Also known,
by measurement, is the quantity of materials lost to the waste water. For
uncontrolled sources, it is assumed that all compounds not accounted for by
these three variables are lost to the atmosphere through the vent. As previously-
mentioned, these calculations are based on full scale production.
In the case of sources with some type of control equipment installed,
a fourth variable is involved in the material balance calculation. This is
the amount of materials recovered from the control equipment.
Control equipment efficiency calculations are based also on a
material balance. A balance is calculated on the process with the assumption
that all materials not accounted for by the three aforementioned variables
enter the scrubber. The amount of material recovered from the scrubber is
a known quantity. The ratio of the quantity recovered over the quantity
entering the scrubber yields the scrubber efficiency.
Storage tank emissions are calculated on the basis of the physical
properties of the compounds stored, the tank dimensions, and climate conditions.
All necessary variables are considered in the calculations and all tanks are
done on an individual basis by computer.
Methods of measurement and estimation were discussed with
representatives from all plant areas. It is apparent that the methods
utilized are appropriate and complete.
4-2
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APPENDIX A
VOC EMISSION SOURCES
A-l
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TABLE A-l. VOC EMISSION SOURCES
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B—3-1 7760P
Dye Manufacturing Plant
Vent B
Wet Scrubber/95%
Isopropanol
Furan
Methanol
0.2
0.1
0.1
Vent C
Wet Scrubber/98%
Isopropanol
Methanol
Ethanol
0.1
0.1
0.1
Vent D
Wet Scrubber/98%
Acetic Acid
0.1
B-3TF-1 8435P
PERMIT TOTAL
0.8
Building 3 Storage Tanks
Tank 3Y-7
None
Ethyl Acetate
0.1
Tank 3Y-8
None
Acetone
0.1
Tank 19
None
Methanol
0.1
B-3Y-1 8436P
PERMIT TOTAL
0.3
Building 3 Waste
Solvent Dumpster
Tank Vent
None
Mi xture:
Toluene
Isopropanol
o-Nitro Toluene
PERMIT TOTAL
0.1
0.1
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TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-5R-1 5945P
Solvent Manufacture
Vent A
Condenser/99%
Acetic Acid
Isobutanol
Isopropanol
Sec-butanol
19.4
7.4
6.3
2.4
Vent B
Condenser/99%
Isobutyl Acetate
Isopropyl Acetate
Sec-butyl Acetate
PERMIT TOTAL
3.0
2.5
0.9
41.9
B-5R-2 5946P
Solvent Manufacture
Vent A
Condenser/99%
2-Ethyl Hexanol
Acetic Acid
Ethanol
Ektasolve
Ethylene Glycol
3.7
20.9
13.9
16.7
4.3
Vent B
Condenser/99%
1
Ectasolve Acetate
2-Ethylhexyl Acetate
Ethylene Glycol Diacetate
Ethyl Pivalate
PERMIT TOTAL
5.2
1.1
1.7
1.1
68.6
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TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-5R-3 5947P
Solvent Manufacture
Vent A
Condenser/99%
Acetic Acid
n-Propanol
30.9
30,8
Vent B
Condenser/99%
n-Propyl Acetate
PERMIT TOTAL
3.4
64.1
B-6C-27 & 28 7561P
Vent A
Wet Scrubber/99%
Propane
Ethylene
PERMIT TOTAL
0.6
1.1
1.7
B-7R-3 7828P
Acetic Anhydride Mfg.
Vent J
None
Propane
Ethylene
67.0
114.0
Vent K
None
Propane
Ethylene
27.0
46.0
Vent L
None
Propane
Ethylene
3.0
4.0
Vent R
None
Propane
Ethylene
11.0
1.2
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TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-7R-3 7828P
Continued
Vent S
None
Propane
Ethylene
Other Unsaturates
18.7
2.0
7.7
Vent T
None
Propane
Ethylene
Other Unsaturates
18.7
2.0
7.7
Vent U
None
Propane
Ethylene
Other Unsaturates
18.7
1.9
7.7
Vent V
None
Propane
Ethylene
Other Unsaturates
33.5
3.5
13.9
Vent W
None
Propane
Ethylene
Other Unsaturates
18.7
1.9
7.7
Tank 36
None
Acetic Acid
0.1
Vent Y
None
Propane
Ethylene
Other Unsaturates
45.6
4.8
18.9
Vent Z
None
Propane
Ethylene
Other Unsaturates
4.4
0.5
1.8
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TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-7R-3 7828P
Continued
Tank 40
None
Mixture:
Acetic Acid
Acetic Anhydride
0.1
Tank 41
None
Mixture:
Acetic Acid
Acetic Anhydride
PERMIT TOTAL
0.1
513,8
B-10-1 7766
Special Acids and
Alcohol Manufacturing
Vent A
Vent D
Condenser
None
Heptane
Crontonaldehyde
Crontonaldehyde
Crotonic Acid
Mixture:
Propionic Acid
Butyric Acid
Formic Acid
Acetic Acid
0.1
0.6
1.1
0.2
0.1
Vent E
None
Crontonic Acid
0.8
Reactor B
Condenser
2-Methyl-l,3-Pentadiene
0.2
Reactor C
Condenser
2-Methyl-l,3-Pentadiene
0.2
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TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-10-1 7766
Continued
Refining E
Refining F
Condenser
Condenser
2-Methyl-l,3-Pentadiene
2-Methyl-l,3-Pentadiene
PERMIT TOTAL
0.4
0.1
3.8
B-10-2 5949P
Acid and Alcohol
Manufacture
Oxidier
Vent
None
2-Ethylhexaldehyde
PERMIT TOTAL
5.0
5.0
B-10-4 7443P
Vent A
Vapor Recovery/99%
2-Ethyl-Hexene
2-Ethyl-Hexanol
Methanol
2.0
3.0
6.0
Vent B
Vapor Recovery/99%
2 Ethyl-Hexene
2 Ethyl-Hexanol
Methanol
1.8
4.5
4.5
Vent C
Vapor Recovery/99%
2-Ethyl-Hexanol
Methanol
0.1
0.1
Vent D
Vapor Recovery/99%
2-Ethyl-Hexanol
Methanol
0.1
0.1
Vent E
None
2-Ethyl-Hexene
0.1
Vent F
None
2-Ethyl-Hexene
0.1
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TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
Di-2-Ethyl-hexylpthalate
Production
Vent A
Vapor Recovery/99%
2-Ethyl-Hexanol
2-Ethyl-Hexene
1.3
0,9
Vent B
Vapor Recovery/99%
2-Ethyl-Hexanol
2-Ethyl-Hexene
5.5
2.1
Vent C
Vapor Recovery/99%
2-Ethyl-Hexanol
0.1
Vent D
Vapor Recovery/39%
2-Ethyl-Hexanol
0.1
Vent E
None
2-Ethyl-Hexanol
0.2
Vent F
None
2-Ethyl-Hexanol
0.1
Vent M
None
2-Ethyl-Hexanol
PERMIT TOTAL
0.1
32.8
B-10-5 7444P
Ester Production
Vent 3A
None
Acetic Acid
Acetic Anhydride
PERMIT TOTAL
0.1
0.1
0.2
B-10-6 7445P
Process 1
None
Methanol
0.1
Plasticizer Production
Process 3
None
Mixture:
Acetic Acid
Acetic Anhydride
0.2
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TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-10-6 7445P
Continued
PERMIT TOTAL
0.3
B-10-7 7447P
Plasticizer Production
Process
Vents
None
Mixture:
2-Ethyl-Hexanol
n-Butanol
Ektasolve
2-Ethyl-Hexanoic Acid
n-Hexanol
Pelargnoic Acid
PERMIT TOTAL
0.1
0.1
B-10-8 7446P
Plasticizer Production
Process
Vents
None
Mixture:
n-Butanol
Ektasolve
2-Ethyl-Hexanol
PERMIT TOTAL
0.1
0.1
B-10-9 7448P
Plasticizer Production
Process
Vents
None
Mixture:
Acetic Anhydride
Isobutyric Anhydride
Acetic Acid'
Isobutyric Acid
Butanol
PERMIT TOTAL
0.1
0.1
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TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-10-10 7449P
Vent 3C
None
Diethyl Ether
0.1
Plasticizer Production
Vent 3K
None
Ethyl Alcohol
0.1
Diethyl Ether
56.5
PERMIT TOTAL
56.7
B-10-11 741 IP
Vent 1A
None
T rimethylpentanedi ol
0.3
PERMIT TOTAL
0.3
B-13-12 7328P
Vent A
None
Mixed Organic
33.5
Solvents
Cyclic Intermediats
Production
PERMIT TOTAL
33.5
B-13-13 8141P
Vent H
None
Toluene
0.3
Cyclic Intermediate
Vent Q
None
To!uene
0.4
Production
Vent T
None
Toluene
0.1
Vent LL
None
Acetone
0.1
Vent NN
None
Acetone
0.2
Vent PP
None
Toluene
0.3
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TABLE A-1 (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-13-13 8141P
Vent RR
None
Toluene
0.4
Continued
Vent SS
None
Toluene
0.4
Isopropanol
0.1
PERMIT TOTAL
2.3
B-134-1 8013P
Dumpsters
None
Mixture:
0.1
1 and 2
Toluene
Waste Solvent Trailers
Acetone
and Dumpsters
Isopropanol
Methanol
2-Ethozyethanol
Trailers
None
Mixture:
0.7
451 & 492
Toluene
Acetone
Isopropanol
Methanol
2-Ethoxyethanol
PERMIT TOTAL
0.8
B-29-2 8392P
Vents
None
Benzene
0.1
A and B
Adhesive Production
Vent G
None
Heptene
0.1
PERMIT TOTAL
0.2
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TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-34-TF 6333P
Vent A
None
Mixture:
0.6
Building 34 Storage
Acetic Anhydride
Acetic Acid
Tank
PERMIT TOTAL
0.6
B-51-20 8134
Tank
None
Isobutylene
2.4
Vent
Isobutylene Storage
PERMIT TOTAL
2.4
B-55-TF 6334P
9 Tanks
Wet Scrubber/95%
Acetic Acid
7.4
through
Propionic Acid
0.7
Chemical Storage
Common
Butyric Acid
1.1
Vent
Tanks
None
Butyric Anhdride
3.0
11 and 12
PERMIT TOTAL
12.2
B-57-4 7786
#1 Jet
None
Qui none
0.8
Hydroquinone Production
#2 Jet
None
Quimome
0.7
PERMIT TOTAL
1.5
B-57A-3 7789P
Vent B
None
Heptane
0.3
Cyclic Intermediate
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TABLE A-l (CONTINUED)
BUILDING
PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
B-57A-3 7789P
Continued
Vent E
Vent F
Vent G
Vent H
Vent I
None
None
None
None
None
Mixture:
Methanol
Acetone
Toluene
Heptane
Isopropanol
Acetic Acid
Mixture:
Methanol
Acetone
Toluene
Heptane
Acetic Acid
Isopropanol
Mixture:
Methanol
Acetone
Toluene
Heptane
Acetic Acid
Isopropanol
PERMIT TOTAL
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TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-57B-1 7412P
Vent A
None
Isopropanol
4.2
Methanol
0.2
Color Developers
Ethanol
1.4
Production
Vent C
None
Isopropanol
0.2
Vent D
None
Ethanol
0.5
Methanol
0.3
Vent E
None
Ethanol
1.3
Benzene
0.4
Vent F
None
Isopropanol
3.6
Vent G
None
Isopropanol
3.3
Vent H
None
Acetone
2.9
PERMIT TOTAL
18.3
B-57B-2 7788P
Vent C
None
Acetone
0.2
Cyclic Intermediate
Vent D
None
Acetone
0.5
Production
PERMIT TOTAL
0.7
B-57BTF-] 8368P
Tank 52-4
None
Toluene
0.1
Building 57 Tank Yard
Tank 52-S
None
Acetone
0.1
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TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-57BFT-1 8368P
Continued
Tank 52-11
None
Isopropanol
0.2
Tank 52-13
None
Ethanol
0.1
Tank 52-14
None
Ethanol
0.1
Tank 52-32
None
Formaldehyde
PERMIT TOTAL
0.2
0.8
B-57TF-1 8360P
Tank 51-14
None
Isopropanol
0.1
Building 57 Storage
PERMIT TOTAL
0.1
B-67-1 6492P
Conveyor and Dryer
Exhaust
Vent A
Vent B.
Wet Scrubber/95%
Wet Scrubber/95%
Acetic Acid
Propionic Acid
Butyric Acid
Acetic Acid
Propionic Acid
Butyric Acid
1.8
0.4
0.9
7.5
0.4
1.3
Vent C
Wet Scrubber/95%
Acetic Acid
Propionic Acid
Butyric Acid
8.5
0.9
2.2
Vent D
Wet Scrubber/95%
Acetic Acid
Propionic Acid
Butyric Acid
21.0
1.3
3.1
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-67-1 6492P
Continued
Vent E
Wet Scrubber/95%
Acetic Acid
Propionic Acid
Butyric Acid
PERMIT TOTAL
20.5
0.9
2,2
72.9
B-80-2 8328P
Large Storage Tanks
Crude
Tank
Tank 3
None
None
Acetone
Acetone
PERMIT TOTAL
0.1
0.7
0.8
B-81-1 7451P
Vent A
Wet Scrubber/95%
Acetic Acid
29.8
Dryer Exhaust
Vent B
Wet Scrubber/95%
Acetic Acid
162.0
Vent C
Wet Scrubber/95%
Acetic Acid
11.7
Vent D
Wet Scrubber/95%
Acetic Acid
19.8
Vent E
Wet Scrubber/95%
Acetic Acid
21.0
Vent F
Wet Scrubber/95%
Acetic Acid
' 5.5
Vent G
Wet Scrubber/95%
Acetic Acid
11.0
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-81-1 7451P
Continued
Vent 6G
Wet Scrubber/95%
Acetic Acid
PERMIT TOTAL
11.0
271.8
B-82TF 6491P
Building 82 Tank Farm
Common
Vent
Wet Scrubber/95%
Acetic Acid
Propionic Acid
Butyric Acid
PERMIT TOTAL
6,3
0.6
0.9
7.8
B-82-1 6001P
Pnumatic Unloading
Station
Fume
Vent
Wet Scrubber/95%
Acetic Acid
PERMIT TOTAL
5.8
5.8
B-85-1 7416P
Vent A
Carbon Beds/98%
Acetone
133,0
Carbon Bed Exhaust
PERMIT TOTAL
133.0
B-86-101
Fuel Stoage Tanks
Gasoline
Tank
Underground
Gasoline Vapors
PERMIT TOTAL
3.1
3.1
B-90B-1 7775
Hydroxyanisole Production
Vent A
None
Mixture:
n-Propanol
Cyclohexane
Heptane
Toluene
Dimethyl sulfate
1.0
-------
TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-90B-1 7775
Vent H
None
Cyclohexane
0.1
Continued
Vent I
None
Acetone
3.9
Vent K
None
Heptane
0.1
PERMIT TOTAL
5.1
B-99-1 7417P
Vent B
Wet Scrubber/99%
Ethyl Acetate
0.1
Ethyl Formate
0.1
Acetaldhyde Manfuacture
Vent C
Wet Scrubber/93%
Ethyl Acetate
0.3
PERMIT TOTAL
0.5
B-99-2 7761P
Vent A
Wet Scrubber/99%
Acetaldehyde
0.1
Ethanol
0.1
Acetic Acid Production
Ethyl Acetate
0.2
Ethyl Formate
2.5
Vent E
Condenser/99%
n-Propyl Acetate
3.4
Tank 21
None
n-Propyl Acetate
0.1
PERMIT TOTAL
6.4
B-99-3 6615P
Vent A
Carbon Bed/95%
Acetaldehyde
0.3
Acetic Acid
0.1
Inert Gas Purification
Methyl Acetate
0.1
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-99-3 6615P
Continued
Vent B
None
Acetaldehyde
Acetic Acid
Ethanol
Methyl Acetate
PERMIT TOTAL
16.6
4.4
2.7
1.8
26.0
B-99-4 7419P
Ethyl Acetate Production
Vent A
None
Isopropyl Acetate
Ethanol
PERMIT TOTAL
1.3
0.5
1.8
B-99A-1 7762P
N-Butyric Acid Production
Vent A
Wet Scrubber/99%
Butyraldehyde
PERMIT TOTAL
1.1
1.1
B-99A-2 7763P
Propionic Acid Manufacture
Vent A
Wet Scrubber/99%
Propionaldehyde
PERMIT TOTAL
305.7
305.7
B-99A-3 7420P
Butryic Acid Production
Vent A
Wet Scrubber/99%
Butyraldehyde
PERMIT TOTAL
1.1
1.1
B-99A-6 7327P
Aliphatic ester production
Vent A
Condenser/99%
Mixture:
Isobutyl Acetate
Isobutyl Alcohol
Isopropyl Acetate
Isopropyl Alcohol
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-99A-6 7327P
Continued
PERMIT TOTAL
0.1
B-99A-8 7421P
Crotonoldehyde Production
Vent A
None
Acetaldelhyde
Crotonaldehyde
PERMIT TOTAL
1.8
0.1
1.9
B-99A-11 8114P
Tank 29
None
n-Propyl Acetate
0.1
Acetic Acid Distillation
PERMIT TOTAL
0.1
B-100TF 6352P
Tank 33
None
Crotonaldehyde
0.2
n-Butyric Acid Production
Storage Facilities
PERMIT TOTAL
0.2
B-102A-1 5657P
Vent A
Carbon Bed/98%
Acetone
60.0
VEREL Fiber Production
Room
Exhaust
None
Acetone
PERMIT TOTAL
1,200.0
1,260,0
B-102C-1 8370P
VEREL Fiber Processing
Room
Exhaust
None
Acetone
PERMIT TOTAL
1.400,0
1,400,0
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-118-2 8104P
Acetone Manufacture
Vent A
Vent B
Piste Column Scrubbers,
99%
Ammonia Condenser/99%
Acetone
Isopropanol
Acetone
8.4
0.4
75.0
Vent C
None
Acetaldelhyde
PERMIT TOTAL
45.6
129.4
B-120-1 7425P
Vent A
Wet Scrubber/95%
Various Hydrocarbons
61.5
Acetate Production
Vent B
Wet Scrubber/95%
Various Hydrocarbons
65.5
Vent C
Wet Scrubber/95%
Various Hydrocarbons
84.0
Vent D
Wet Scrubbers/95%
Various Hydeocarbons
PERMIT TOTAL
97.0
308.0
B-120TF 7424P
Tank 14
None
Acetic Anhydride
1.1
Building 120 Tank Farm
Tank 51
None
Propionic Acid
PERMIT TOTAL
0.6
1.7
B-120TF 654OP
Building 120 Storage
Tank 1
None
Mixture:
Acetic AnhydHde
Butyric Anhydride
0.6
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-120TF 6540P
Continued
Tank 4
None
Mixture:
Acetic Acid
Propionic Acid
0.3
Tank 5
None
Mixture:
Acetic Acid
Butyric Acid
0.1
Tank 9
None
Butyric Acid
0.6
Tank 10
None
Mixture:
Acetic Acid
Butyric Acid
PERMIT TOTAL
1.9
3.5
B-122-3A 7781P
Tank 1
None
Quione
0.6
Tecmangam Production
Tank 2
None
Quione
0.7
Tank 3
None
Qui one
0.6
Tank 7
None
Quione
PERMIT TOTAL
0.7
2.6
-------
TABLE A-l (CONTINUED^
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-122-4 7792P
Acid Sludge
Neutralization
Tanks 1-3
None
Acetic Acid
PERMIT TOTAL
0.1
0.1
B-123-1 6715P
Triethyl Phosphate
Production
Ether
Condenser/50%
Mixture:
Diethyl ether
Ethylene
PERMIT TOTAL
350.0
350.0
B-125-1 8097P
Filter Tow Dryers
Vent A
None
Acetone
PERMIT TOTAL
57.0
57.0
B-125A-3 8098P
Second Stage Filter
Tow Dryers
Vent A
None
Acetone
PERMIT TOTAL
54.0
54.0
B-127-1 7770P
Filter Products
Vent A
Carbon Bed/92%
Acetone
PERMIT TOTAL
340.0
340.0
B-127-2 7764P
Filter Products
Vent A
Carbon Bed/90%
Acetone
PERMIT TOTAL
288.0
288.0
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-137TF 6493P
Tank 352
None
Acetic Anhydride
0.3
Building 137 Tank Farm
Tank 356
None
Acetic Anhydride
PERMIT TOTAL
0.8
1.1
B-174B-1 614DP
Vent A
None
Various Solvents
31.2
Laboratory Pellet
Coating
PERMIT TOTAL
31.2
B-174B-2 7438P
Vent A
None
Various Solvents
1.1
Polymer Production
Various Hydrocarbons
PERMIT TOTAL
0.2
1.3
B-176-1 7440P
Vent A
None
Acetone
3.8
Cleaning Vats
PERMIT TOTAL
3.8
B-190C-4 6125P
Vent A
None
Saturated Hydrocarbons
0.7
Plastic Pellet Production
PERMIT TOTAL
0.7
B-190C-6 6356P
Vent A
None
Saturated Hydrocarbons
1.2
Plastic Pellet Production
PERMIT TOTAL
1.2
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-190C-7 6357P
Vent A
None
Saturated Hydrocarbons
0.1
Banbury Mixer
PERMIT TOTAL
0,1
B-190E-3 6330P
Vent A
None
Saturated Hydrocarbons
0.8
Plastic Processing
PERMIT TOTAL
0.8
B-194-1 6000P
Vent C
None
Xylene
0.1
VEREL Polymer
Manufacturing
Vents D-G
None
Xylene
Isopropanol
Acrylonitrile
0.1
0.1
0.1
Vents I-K
None
yinylidenechl orlde
Acrylonitrile
0.3
1.3
Vents L&M
None
Vinyl1denechlori de
Acrylonitrile
0.3
1.1
Vent V
None
Vinylidenechloride
Acrylonitrile
1.1
1.9
Vent W
None
Vi nyli denechlori de
Acrylonitrile
8.0
4.0
Vent X
None
Vinylidenechloride
Acrylonitrile
8.2
6.2
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-194-1 6000P
Continued
PERMIT TOTAL
32.8
B-200TF 6331P
Tank 40-75
None
Propionaldehyde
15.1
Long Island Tank Farm
Tank 90-54
None
2-Butyraldehyde
1.7
Tank 43-51
None
2-Ethylhexaldehyde
0.1
Tank 43-55
None
2-Ethylhexaldehyde
0.1
Tank 40-61
None
n-Butyraldehyde
1.1
Tank 40-74
None
Propionaldehyde
PERMIT TOTAL
15.1
33.4
B-212TF 7452P
Building 212 Tank Fark
Various
Tanks
None
Mixture:
Acetic Acid
Acetic Anhydride
Crotonaldehyde
PERMIT TOTAL
0.2
0.2
B-218TF-1 8140P
Building B-13 Tanks
Tank 83
None
Mixture:
Toluene
Acetone
Isopropanol
Methanol
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-218TF-1 8140P
Continued
2-Ethoxyethanol
PERMIT TOTAL
0.1
B-220-1 6327P
Dimethyl Terephthalate
Production
Storage
Tank
Hold
Tank
None
None
Methanol
Methanol
PERMIT TOTAL
26,7
47.2
73.9
B-221-2 8383P
No.l CHDM Plant
Letdown
Tank
None
Methanol
PERMIT TOTAL
8.4
8.4
B-221A-l 8385P
No. 2 CHDM Plant
Letdown
Tank
None
Methanol
PERMIT TOTAL
8.4
8.4
B-221B-l 8384P
No.3 CHDM Plant
Letdown
Tank
None
Methanol
PERMIT TOTAL
8.4
8.4
B—225-1 7768P
Vent A
None
Various Hydrocarbons
0.1
No. 1 Hydrogen Plant
Vent B
None
Methyl ethyl amine
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-225-1 7768P
Continued
PERMIT TOTAL
0.2
B-225A-1 7793P
Vent A
None
Various Hydrocarbons
0.1
Inert Gas Plant
PERMIT TOTAL
0.1
B-226P-1 6799P
Vents 1H-1K
None
Methanol
0.3
Polyester Polymer
Production
Vent 1L
Vent 1M
None
None
Methanol
Methanol
0.6
0.1
Vent IN
None
Methanol
1.1
Vent 2A
None
Methanol
2.1
Vent 2B
None
Methanol
0.9
Vents 4A-4R
None
Methanol
PERMIT TOTAL
128.0
133.1
B-232-1 7777P
Terephthalic Acid
Manufacture
1
Vents A&B
Plate Column
Scrubber/46%
Methyl Acetate
Xylene
Acetic Acid
Acetaldehyde
91.0
6.0
2.0
23.0
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-232-1 7777P
Continued
Vent C
Plate Column
Scrubber/82%
Methyl Acetate
Acetaldehyde
p-Xylene
Acetic Acid
252.0
33.0
32.0
143.0
i/ents D & E
Plate Column
Scrubber/46%
Methyl Acetate
Acetic Acid
p-Xylene
Acetaldehyde
82,0
8.0
5.0
24.0
Vent F
Inert Gas
Scrubber/76%
Methyl Acetate
Acetic Acid
p-Xylene
Acetaldehyde
27.0
0.5
5.0
0.6
Vent G
None
Methyl Acetate
Acetic Acid
p-Xylene
Acetaldehyde
9.0
0.2
2.0
0.2
Vent H
None
Methyl Acetate
Acetic Acid
p-Xylene
Acetaldehyde
9.0
0.2
2.0
0.2
Vent I
Condenser/90%
Acetic Acid
Methyl Acetate
p-Xylene
63,0
4.6
0.2
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-232-1 7777P
Continued
Vent K
Condensor/85%
Acetaldehyde
Methyl Acetate
n-Propyl Acetate
2.0
0.8
0.2
Vent L
None
Acetaldehyde
Methyl Acetate
n-Propyl Acetate
76.0
21.0
5.0
Vent T
None
Acetic Acid
3.2
Vent U
Plate Column
Scrubber/66%
Methyl Acetate
p-Xylene
Acetic Acid
Acetaldehyde
272.0
47.0
72.0
118.0
Vent V
Condenser/50%
Methyl Acetate
Acetaldehyde
n-Propyl Acetate
Ethyl Acetate
5.0
0.4
0.7
0.3
Vent W
Wet Scrubber/50%
Methyl Acetate
Acetaldehyde
p-Xylene
4.0
0.2
2.0
Vent X
None
Acetic Acid
1.5
Vent Z
Wet Scrubber/60%
Methyl Acetate
Acetaldehyde
p-Xylene
8.0
0.2
4.0
-------
TABLEA-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-232-1 7777P
Continued
Vent AA
None
Acetaldehyde
Methyl Acetate
p-Xylene
0.2
0.1
0.4
Tanks 29,
38 & 42
None
Mixture:
Acetaldehyde
Acetic Acid
Ethyl Acetate
Methyl Acetate
Xylene
Methanol
1.1
Tank 03
None
p-Xylene
0.5
Tank 09
Underground
Mixture:
Acetaldehyde
Ethyl Acetate
Methyl Acetate
Methanol
N-Propyl Acetate
2.0
Tanks 36
and 43
None
Mixture:
Acetic Acid
Cobalt Acetate
Terephthalic Acid
Xylene
12.1
Tanks 34,
37 & 44
None
Acetic Acid
3.1
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-233-1 7777P
Continued
Vent AC
None
Acetaldehyde
Methyl Acetate
Methanol
n-Propyl Acetate
PERMIT TOTAL
6.9
17.3
0.1
0.2
1,512.3
B-236TF-1 6325P
Tank HB-01
None
Methanol
2.6
Storage and Feed Tanks
Tank HC-01
and HD-01
None
Methanol
0.2
Tank HC-01
None
Methanol
2.2
Tank HH-01
None
Methanol
6.4
Tanks HI-01
and HJ-01
None
O-Xylene
0.2
Tank HL-01
None
Methanol
PERMIT TOTAL
9.1
20.7
B-237-1 6326P
Dimethyl Terphehalate
Plant No. 1
Tank QB-52
None
Mixture:
Dimethyl Terephthalate
Methyl Paratoluate
Methyl benzoate
Methylparformyl
benzoate
0.1
-------
TABLE A-l (CONTINUED)
!
BUILDING PERMIT
SOURCE
1
CONTROL EQUIPMENT/
EFFICIENCY
|
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-237-1 6326P
Continued
Tank OC-51
|
None j
i
4
1 |
Dimethyl Terephthalate
PERMIT TOTAL
36.0
36.1
B-237A-1 8361P
i Vent D
! None |
[ I
Methanol
1.8
Dimethyl Terephthalate
Plant No. 2
| Vent E
j Vent F
|
i
1
i
1
I None
i
i
j None
5
I
!
Xylene
Mixture:
Methyl-p-Toluate
Dimethyl Terephthalate
Methyl Benzoate
Methyl-p-Formyl Benzoate
0.1
0.2
Tank TD-51
j None
Mixture:
Methyl-p-Formyl Benzoate
Methyl-p-Toluate
Dimethyl Terphthalate
| Methyl Benzoate
0.4
Vent J
; Baffle Tray Scrubber
1
iMethanol
39.5
Vent K
None
Acetaldehyde
j Dimethyl Ether
jMethyl Acetate
j Methanol
232.0
1 ,830.0
452.0
127.0
Tank TB-50 Pressure Tank
\
i
| o-Xylene
0.1
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-237A-1 8361P
Continued
Vent 0
None
o-Xylene
PERMIT TOTAL
2.2
2,685.3
B-239-4 8355P
Vent D
Condenser
Various Hydrocarbons
PERMIT TOTAL
0.3
0.3
-------
TABLE ft-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-244-1 8143P
Jet Pot
Condenser/62%
Ethylene
0.9
Diketene Refining
Propane
1, 3-Butadiene
PERMIT TOTAL
2.1
0.7
3.7
B-244-2 8363P
Jet Pot
Condenser/92%
Methanol
7.4
Acetoacetic Esters
Production
Ethanol
PERMIT TOTAL
0.3
7.7
B-244A 7765P
Vent A
Wet Scrubber/90%
Acetone
4.3
Ketone Production
Methyl propyl ketone
0.3
Tanks 83
and 84
None
Various Ketones
0.5
Tanks 64
and 65
None
Various Ketones
0.4
Tanks 70
and 63
None
Various Ketones
0.1
Tank 92
None
Isobutyraldehyde
5.9
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-244A 7765P
Continued
Tank 93
Tank 201
None
None
Acetone
Various Ketones
PERMIT TOTAL
7.3
0.4
19.2
B-244B-1 8372P
Vent A
Wet Scrubber/88%
Acetone
32.2
Ketone Production
Isopropanol
Methyl Isobutyl Ketone
0.2
3.4
Tank 243
None
Mixture:
N-Butyraldehyde
Propi on aldehyde
0.2
Tanks 272,
264,265,283
269,273,201 ,
271,270,263,
284
None
Various Ketones
2.1
Tank 292
None
Acetone
PERMIT TOTAL
8.1
46.2
B-244D-2 8336P
Dimethyl Acetoacetimide J
Tanks 109
and 110
1
None
Mixture:
Dimethyl Actoacetimide
Monomethyl Acetoacetimide
0.7
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-244D-2 8336P
Production
Continued
PERMIT TOTAL
0.7
B-244E-2 999696P
Acetoaceta ryli des
Reaction Facility
Vents F, G
and H
Vent J
None
None
Acetic Acid
Acetone
PERMIT TOTAL
0.1
0.1
0.2
B-246-2 8337P
Vent A
Wet Scrubber/95%
Ethylene
0.8
Cyclic Intermediates
Production
Vent H
None
Isopropanol
Methanol
Ethanol
0.1
0.1
0.1
Vents I, J
K, M, N, 0
T
None
Isopropanol
Methanol
Ethanol
1.0
1.0
1.0
Vents P,
A, R
None
Isopropanol
Methanol
Ethanol
PERMIT TOTAL
0.2
0.2
0.2
4.7
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-254-1 7428P
Vent A
Wet Scrubber/92%
Acetone
152,4
Filter Products
PERMIT TOTAL
152.4
B-255-1 7530P
Polyester Polymer
Manufacture
Vents 1A
and IB
Vents 1C
And ID
None
None
Methanol
Ethylene Glycol
35.0
4.4
Vent 2C
None
Methanol
4.4
Vent 2D
None
Ethylene Glycol
0.9
Vents 5A-
56
None
Ethylene Glycol
PERMIT TOTAL
3.4
48.1
B-261-1 8362P
Vent C
None
Methanol
1.8
Dimethyl Terephthalate
Plant No. 3
Tank DA-53
None
Dimethyl Terephthalate
o-Xylene
0.6
0.2
Tank CS-50
None
Mixture:
o-Xylene
Dimethyl Terephthalate
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-261-1 8362P
Continued
Tank DB-52
None
Mixture:
Dimethyl Terephthalate
Methyl-p-Toluate
Methyl Benzoate
Methyl-p-Formyl Benzoate
0.2
Tanks DD-51
and 628
None
Mixture:
Methyl-p-Toluate Benzoate
Methyl-p-Formyl Benzoate
Dimethyl Terephthalate
Methyl Benzoate
1.1
Vent L
None
Methanol
41.2
Vent M
None
Dimethyl Terephthalate
8.8
Tank DB-50
None
o-Xylene
0.1
Tank 431
None
Mi xture:
n-Butanol
Ethylene Glycol
Methanol
2-Ethoxyethanol
PERMIT TOTAL
0.3
54.4
B-261A-1 6 MOP
Tank FA-53
None
Mi xture:
Dimethyl Terephthalate
8.2
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
i
' CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-261A-1 6440P
Xylene
Dimethyl Terephthalate
Plant No. 4
Continued
Tank FB-52
None
Mi xture:
Dimethyl Terephthalate
Methyl paratoluate
Methyl Benzoate
0.2
Tank FD-51
None
Mixture:
Methyl-p-Formyl Benzoate
Methyl Paratoluate
Methyl Benzoate
Dimethyl Terephthalate
0.6
Vent E
None
Methyl Paratoluate
Methyl Benzoate
Xylene
49.0
56.0
28.0
Vent F
None
Methanol
PERMIT TOTAL
79.0
221.0
B-262-1 7827P j
1
Raw Material Storage
Tanks AA-01
Through
AE-01
None
Methanol
i
i
5.8
1
i
Vents H,
I and J
Methyl Acetate |
Acetaldehyde
p-Xylene j
34.6
0.8
f
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
1
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-262-1 7827P
Continued
Acetic Acid
PERMIT TOTAL
0.6
43.3
B-263-4 8354P
Tank MF55
None
Fuel Oil Vapors
0.1
Fuel Storage
PERMIT TOTAL
0.1
B-265B-2 7429P
Specialty Polymer Plant
Vent D
Vent E
None
None
Methanol
p-Dioxarce
Methanol
4.3
0.2
0,3
Vents G,
H and I
None
Methanol
PERMIT TOTAL
0.1
4.9
B—267-1 7430P
Organic Chemical
Production
Vents A,
B and C
Vent D
Wet Scrubbers/50%
Wet Scrubber/90%
Mixed Solvents
Mixed Solvents
132.0
8.8
Vents E,
F and G
Wet Scrubbers/50%
Mixed Solvents
PERMIT TOTAL
132.0
272.8
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
EMISSIONS
POLLUTANT (TONS/YEAR)
B-267-2 6495P
Organic Chemical
Producti on
Vent C
Vent D
Vent E
None
Wet Scrubber/50%
Wet Scrubber/50%
Mixed Solvents 43.8
Mixed Solvents 22.0
Mixed Solvents 4.4
1
PERMIT TOTAL ; 70.2
B-267-4 7453P
Drum MeIters
Vent A
.
Wet Scrubber/70%
]
Mixture: , 0.1
Acetone j
Methanol I
Isopropanol
Heptane |
Toluene
PERMIT TOTAL \ 0.1
B-267-5 7457P
Organic Chemical
Production
Vents A, None i Mixture: 1.8
B and C Acetone
Methanol
Isopropanol
Heptane
To!uene
PERMIT TOTAL 1.8
Vents A ;
Through E Wet Scrubber/50% Mixed Solvents 220.00
B-267A-1 7324P
Organic Chemical
Production
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-267A-1 7324P
Continued
PERMIT TOTAL
220.0
B-267A-2 6633P
Organic Chemical Drying
Vents A
And B
Wet Scrubber/50%
Mixed Solvents
PERMIT TOTAL
4.4
4.4
B-267A-3 6634P
Organic Chemical
Producti on
Vent A
Vent B
Wet Scrubber/50%
Wet Scrubber/50%
Xylene
Xylene
PERMIT TOTAL
1.1
2.0
3.1
B-267D-1 6635P
Organic Chemical
Production
Vents A
through F
Wet Scrubber/50%
Mixed Solvents
PERMIT TOTAL
264.0
264.0
B-267D-2 6636P
Organic Chemical
Production
Vent A
Vent B
Wet Scrubber/50%
Wet Scrubber/50%
Mixed Solvents
Mixed Solvents
PERMIT TOTAL
44.0
43.8
87.8
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-267D-3 7323P
Organic Chemical
Production
Vent A
Wet Scrubber/90%
Mixed Solvents
PERMIT TOTAL
8.8
8.8
B-267D-4
Organic Chemical
Production
Vents A
And B
None
Mixture:
Acetone
Methanol
Isopropanol
Heptane
Toluene
3.2
Vents C
and D
None
Mixture:
Acetone
Methanol
Isopropanol
Heptane
Toluene
PERMIT TOTAL
0.2
3.4
B-267TF-2 8132P
Building 267
Storage Tanks
Tanks 3002
and 3003
Tank 3007
None
None
Isopropanol
Heptane
0.3
0.9
Tank 3008
None
Toluene
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-267TF-2 8132P
Continued
Tank 3009
None
Methanol
1.5
Tank 3010
None
Isopropanol
0.7
Tanks 3052
and 3053
None
Methanol
0.5
Tanks 3054
and 3060
None
Mixture:
Isopropanol
Methanol
Acetone
Toluene
Heptane
0.7
Tank 3039
None
Acetic Acid
0.1
Tank 3012
None
Acetone
2.3
Tank 3018
None
Heptane
0.1
Tank 3020
None
Mixture:
Acetone
Methanol
0.3
Tank 3021
None
Acetone
0.4
Tank 3022
None
Heptane
0.3
-------
TABLE A-1 (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-267TF-2 8132P
Continued
Tank 3023
None
Toluene
0.1
Tank 3024
None
Mixture:
Acetone
Isopropanol
Methanol
0.1
Tank 3025
None
Toluene
0.1
Tank 3061
None
Acetone
0.1
Tank 3062
None
Mixture:
Methanol
Toluene
0.1
Tank 3063
None
Heptane
0.3
Tank 3064
None
Toluene
0.1
Tank 3068
None
Mixture:
Isopropanol
Methanol
Acetone
PERMIT TOTAL
0.1
9.2
-------
TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDIiNG PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-267Y-1 6956P
Vents B
None
Methanol
0.9
c and D
Acetone
0.9
Waste Stripping
Heptane
0.9
Toluene
0.9
Isopropanol
0.9
PERMIT TOTAL
4.5
B-267Y-2 6800P
Vent A
None
Ispropanol
1.1
Isopropariol Refinery
PERMIT TOTAL
1.1
B-267Y-3 6801P
Vent A
None
Toluene
1.1
Toluene Refinery
Vent B
None
Toluene
1.1
PERMIT TOTAL
2.2
B-267Y-4 7018P
Vent SC-01
None
Heptane
0.9
Toluene
0.9
Vent SC-02
None
Heptane
1.3
Toluene
0.5
Vent SC-03
None
Heptane
0.4
Toluene
0.9
PERMIT TOTAL
4.9
-------
TABLE A-1 (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-267Y-5 7435P
Tank
None
Methanol
0.1
Vent
Acetone
0.1
Filtrate Neutralization
Heptane
0.1
Toluene
0.1
Isopropanol
0.1
PERMIT TOTAL
0.5
B-267Y-6 7322P
Vent IB
None
Acetone
0.3
Methanol
0.2
Solvent Seperation
Vent 2B
None
Acetone
0.3
Methanol
0.2
PERMIT TOTAL
1.0
B-267Y-7 7436P
Vent A
None
Isopropanol
0.1
Solvent Seperation
Vent B
None
Isopropanol
0.1
PERMIT TOTAL
0.2
B-267Y-8 999689P
Vent A
None
Ethylene Glycol
0.8
Ethylene Glycol Recovery
PERMIT TOTAL
0.8
B-267Y-9 8366P
Dumpsters
None
Mixture:
0.5
Organic Waste Disposal
651, 652,
Acetone
653 & 654
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-267Y-9 8366P
Continued
Methanol
Isopropanol
Heptane
Toluene
Dumpsters
662, 663
664, 670
671, 672
None
Mixture:
Acetone
Methanol
Isopropanol
Heptane
Toluene
1.7
Trailers
294, 443,
455,283,
Mixture:
Acetone
Methanol
Isopropanol
Heptane
Toluene
PERMIT TOTAL
5.3
7.5
B-270-1 999902P
Polyester Polymer
Manufacture
Vents 1A
and 11B
Vents 1C
and 10
None
None
Dioxolane
Methanol
Ethylene Glycol
30.0
28.0
2.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-270-1 999902P
Continued
Vents IE
and IN
None
Ethylene Glycol
28,0
Vents IF
and 10
None
Triethylene Glycol
0.2
Vents
1G and IS
None
Mixture:
Dioxolane
Methanol
5.9
Vents 1 H
None
Diethylene Glycol
0.1
Vent 1 J
None
Ethylene Glycol
2.2
Vents 1 L
and 1 M
None
Ethylene Glycol
5.3
Vent 1 P
None
n-Butanol
0.4
Vent 1Q
None
Dowtherm A
1.1
Vents 2A
rhrough 2T
None
Ethylene Glycol
0.2
Vents 3A
rhrough 3T
None
Various Hydrocarbons
2.9
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-270-1 999902P
Continued
Vents 4A
Through 4D,
41 and 4J
None
Methanol
79.8
Vents 4E
Through 4H,
4K and 4L
None
Methanol
PERMIT TOTAL
0.2
186.4
B-270-1-IV 999759P
Tank SA-01
None
Monomer
0.5
Polymer Sludge Storage
PERMIT TOTAL
0.5
B-270-1-IX 999758P
Rail Car Storage
Tank Car
None
Mixture:
Monomer
Ethylene Glycol
PERMIT TOTAL
0.9
0.9
B-270-2
Drying System Vent
Vent IB
None
Acetaldehyde
Ethylene Glycol
PERMIT TOTAL
0.2
5.0
5.2
B-271TF-1 8456P
Polymer Division Tank
Farm
Tanks 83-3
and 83-4
None
Ethylene Glycol
0.1
-------
TABLE A-l (CONTINUED)
BUILDING
PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
B-271TF-1 8456P
Continued
Tank 83-6
Tanks 54-4
54-5,54-6
Rail Car
None
None
None
Ethylene Glycol
Mixture:
Acrylonitrile
Isopropanol
Dimethyl Terephthalate
PERMIT TOTAL
B-273-1 5980P
Dye Manufacturing
Vent A
None
Acetic Acid
PERMIT TOTAL
B-273TF-1 8365P
Building 273 Tank Farm
Tank YF-6
Tanks YF-3
and YF-5
None
None
Acetone
Toluene
PERMIT TOTAL
-------
TABLE A-l (CONTINUED)
CONTROL EQUIPMENT/
EMISSIONS
BUILDING PERMIT
SOURCE
EFFICIENCY
POLLUTANT
(TONS/YEAR)
B-274-101
Gasoline
Underground
Gasoline Vapors
4.3
Fuel Storage
Tanks
PERMIT TOTAL
4.3
B-290-1 999747P
Vent A
None
Acetic Acid
14.7
Filtering Process
PERMIT TOTAL
14.7
B-294-1 7153P
Vent D
None
Various Hydrocarbons
0.3
No. 3 Hydrogen Plant
Vent E
None
Various Hydrocarbons
0".3
PERMIT TOTAL
0.6
B-303A-1 6798P
Vent F
Wet Scrubber/95%
Various Hydrocarbons
4.4
Predryer Exhaust
PERMIT TOTAL
4.4
B-303A-2 5220P
Vent C
Wet Scrubber/95%
Various Hydrocarbons
3.6
Predryer Exhaust
PERMIT TOTAL
3.6
B-319-1 999729
Vent A
Condensor/99%
o-Xylene
4.8
Cobalt Recovering Facility
PERMIT TOTAL
4.8
-------
TABLE A-l (CONTINUED)
BUILDING
PERMIT,
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
ETR-55A-1
Tank Farm
8009P
Tanks 68
and 69
None
Propionic Anhydride
PERMIT TOTAL
0.2
0.2
T-10-1
8119P
Tank 1
None
Mi xture:
Crotonaldehyde
Heptane
Crotonic Acid
0.1
Tank 2
None
2-Ethylhexaldehyde
0.1
Tank 12
None
Mixture:
Crotonic Acid
Heptone
Crotonaldehyde
Acetic Acid
Propionic Acid
Formic Acid
0.2
Tank 15
None
Crotonaldehyde
0.1
Tank 19
None
Methanol
0.4
Tank 20
None
Methanol
0.4
Tank 530
None
Mi xture:
2-Ethyelhexanoic Acid
Crotonic Acid
0.1
-------
TABLE A-l (CONTINUED)
BUILDING
PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
Propionic Acid
Formic Acid
Butyric Acid
PERMIT TOTAL
1.4
T-12-1
8131P
Tank 525
None
Sucrose Acetate
0.4
Tank Farm
Tank 526
None
Isobutyrate
PERMIT TOTAL
0.4
0.8
T-18-1
8133P
Tank 125
None
Di-2-Ethylhexylazelate
0.1
Tank Farm
Tank 126
None
Di-2-Ethylhexylazelate
0.1
Tank 127
None
Di-2-Ethylhexylazelate
0.1
Tanks 128
and 129
None
Di-2-Ethylhexyl
terephlhalate
0.2
Tank 131
None
Di-2-Ethylhexylazelate
PERMIT TOTAL
0.1
0.6
T-18-2
Tank Farm
8375P
Tank 141
None
Mi xture:
Methyl Benzoate
Methyl p-toluate
o-Xylene
1.0
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT.
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
PERMIT TOTAL
1.0
T—21 — 1 8142P
Tanks 17
and 18
None
Isopropyl Acetate
2.8
Tank Farm
Tanks 25
and 26
None
Isopropy1 Acetate
3.6
Tanks 29
and 30
None
Isobutyl Acetate
1.6
Tanks 33
and 34
None
Mixture:
n-3utyl Acetate
n-Propyl Acetate
1.6
Tank 37
None
Mixture:
2-Ethylhexanol
Methanol
0.1
Tanks 38
and 39
None
Heptane
0.2
Tank 62
None
Ethanol
0.8
Tank 65
None
Isopropanol
0.4
Tank 66
None
. Mixture:
s-Butyl Alcohol
Ethyl Acetate
1.9
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT,
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
PERMIT TOTAL
13.0
T-21-2 8096P
Tank 41
None
n-Propyl Alcohol
0.4
Tank Farm
Tank 43
None
Methanol
1.4
Tank 48
None
Isopropanol
0.2
Tank 50
None
n-Propyl Acetate
PERMIT TOTAL
0.8
2.8
T-22-1 8369P
Tank Farm
Tanks 65
and 66
None
Glyceryl Triacetate
0.2
T-57-PS-1 8494P
Waste Chemical Storage
Waste
Tank
None
Mixture:
Isopropanol
Methanol
PERMIT TOTAL
0.3
0.3
T-57-PS-1 8494P
Waste Chemical Storage
Waste
Tank
None
Mi xture:
Isopropanol
Acetone
Toluene
Heptahe
PERMIT TOTAL
1.6
1.6
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT.
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
T-83-PS-4 8338P
Building 83 Tank Farm
Tank 49-1
None
Ethylene Glycol -
monomethyl ether
0.1
Tank 49-2
None
n-Butyl Alcohol
0.2
Tank 49-3
None
Isobutyl Alcohol
0.3
Tank 49-4
None
Ethanol
PERMIT TOTAL
0.2
0.8
T-100-A-2 8]09P
Tank Farm
Tanks 44
and 49
None
Mi xture:
i-Butyl Acetate
n-Butyl Acetate
0.8
Tanks 45
and 46
None
n-Butyraldehyde
PERMIT TOTAL
0.2
1.0
T-100-A-4 8107P
Tank 5
None
Isopropanol
1.7
Tank Farm
Tank 7
None
Ethanol
2.1
Tank 8
None
Isopropanol
1.3
Tank 9
None
Isopropanol
PERMIT TOTAL
0.9
6.5
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT.
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
T—119-1 8118P
Chemical Storage
Tank 79
None
Mi xture:
Acetone
Isopropanol
PERMIT TOTAL
0.1
0.1
T-161-1 811 OP
Tank Farm
Tanks 38
and 39
None
Ethylene Glycol-
monomethyl ether
0.2
Tanks 38-
57 and 38-
58
None
Acetic Acid
PERMIT TOTAL
11.2
11.4
T-161-A-1 8111P
Tank 16
None
Various Acetates
2.2
Tank Farm
Tank 30
None
n-Propyl Acetate
0.2
Tanks 40-
36 and 40-
37
None
Mixture:
Isopropyl Acetate
Isobutyl Acetate
PERMIT TOTAL
3.8
6.2
T-161-A-2 7773P
Tank 43
None
Ethylene Glycol -
monomethyl ether Acetate
PERMIT TOTAL
0.1
0.1
-------
TABLE A-l (CONTINUED)
BUILDING PERMIT
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
T-200-1 8010P
to
T-200-8
Tanks 49-178
and 49-179
None
2-Ethylhexanol
0.2
Tank Farm
Tanks 35-67
and 35-68
None
Mixture:
n-Propyl Alcohol
n-Propyl Acetate
0.9
Tanks 38-70
and 38-71
None
Acetic Acid
12.7
Tanks 35-101
and 35-103
None
Ethylene Glycol-
monoethyl ether Acetate
0.2
Tank 89-116
None
Diethylene Glycol
PERMIT TOTAL
0.2
14.2
T-218-1 8112P
Tank Farm
Tanks 1
through 4
None
Mixture:
Acetic Acid
Butyric Acid
Propionic Acid
PERMIT TOTAL
5.0
5.0
T-212-39-48 6332P
Tank 39-48
None
Acetic Anhydride
0.1
Tank Farm
PERMIT TOTAL
0.1
-------
TABLE A-1 (CONTINUED)
BUILDING
PERMIT,
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
T-220-TF-1
Tank Farm
8394P
Tanks CH-100,
CH-101 , XH-50
XH-51, UH-50,
WH-50, ZH-50
Uone
Methanol
PERMIT TOTAL
6.6
6.6
T-221-TF-1
Tank Farm
8434P
Tanks CG-101,
XG-50, XG-5T
it one
Mi xture:
Methyl Formcel
Ethanol
Crude Tocopherol
Methanol
2.1
T-221-TF-1
Continued
Dumpster 627
None
Mi xture:
Ethanol
Crude Tocophenol
PERMIT TOTAL
0.9
3.0
T-244-1
Tank Farm
8012P
Tank 4
None
Mixture:
Methanol
Ethanol
PERMIT TOTAL
0.2
0.2
T-248-PS-3
8395P
Tanks A, B,
C, P
None
Various Hydrocarbons
1.5
-------
TABLE A-l (CONTINUED)
BUILDING
PERMIT.
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
T-248-PS-4
Tank D
Various Hydrocarbons
0.1
Tank Farm
PERMIT TOTAL
1.6
T-272-PS-4
8135P
Fuel Oil
Storage
None
Fuel Oil Vapors
0.1
Fuel Storage
Dowthern
Storage
None
Dowthern Vapors
PERMIT TOTAL
0.1
0.2
T-291-1
Tank Farm
8386 P
Tank 046
None
Mixture:
Acetic Acid
Col bait Acetate
Terephthalic Acid
PERMIT TOTAL
0.9
0.0
TF-120-1
Tank Farm
8330P
Tank 30
None
Mixture:
Acetic Acid
Butyric Acid
0.1
Tanks 31
and 36
None
Mixture:
Acetic Acid
Butyric Acid
Propionic Acid
0.4
-------
TABLE A-1 (CONTINUED)
BUILDING
PERMIT.
SOURCE
CONTROL EQUIPMENT/
EFFICIENCY
POLLUTANT
EMISSIONS
(TONS/YEAR)
PERMIT TOTAL
0.5
TR-73-1
Tank Farm
8432P
Common Vent
:or Tanks 131
through 1616
Wet Scrubber
Various Hydrocarbons
PERMIT TOTAL
12.2
12.2
WTF-55-1
Tank Farm
8331P
Tanks 13, 14
and 15
None
Mixture:
Acetic Anhydride
Butyric Anydride
0.7
Tank 30
None
Propionic Acid
0.1
Tanks 96
and 97
None
Mixture:
Acetic Acid
Butyric Acid
Propionic Acid
0.2
Tanks 102,
309 and 110
None
Aceti c Aci d
PERMIT TOTAL
0.5
1.5
PLANT TOTAL
12,390.5
-------
THIS PAGE INTENTIONALLY LEFT BLANK
A-64
-------
APPENDIX B
PILOT PLANT AND LABORATORY EMISSIONS
B-l
-------
PILOT
BUILDING
B-96-1
Spray Drying of Aqueous
Polymer Slurries
B-104A-1
Laboratory Extruder
B-104A-2
Oxidation Unit
B-152-1
Polymer Pilot Plant
B-159-1
Organic Chemical Pilot
Plant
B-167-1
Fiber Spinning Pilot
Plant
TABLE B-l
PLANT AND LABORATORY EMISSIONS
EMISSIONS
PERMIT POLLUTANT (TONS/YEAR)
7126 P None 0
7129 P Polymer Decomposition 0.6
Product
5402 P None 0
8460 P None 0
8459 P None 0
8438 P None 0
TOTAL 0.6
B-2
-------
APPENDIX C
COMPOUND SPECIFIC EMISSIONS
C-l
-------
TABLE C-l
ACETALDEHYDE EMISSIONS
Page 1
BUILDING
PERMIT
SOURCE
emission
B-99-2
7761 P
VENT A
0.1
B-99-3
6615 P
VENT A
VENT B
PERMIT TOTAL
0.3
16.6
16.9
B-99A-8
7421 P
VENT A
1.8
B-118-2
8104 P
VENT C
45.6
B-232-1
7777 P
VENTS A&B
VENT C
VENTS D&E
VENT F
VENT G
VENT H
VENT K
VENT L
VENT U
VENT V
VENT W
VENT Z
VENT AA
VENT AC
PERMIT TOTAL
23.0
33.0
24.0
0.6
0.2
0.2
2.0
76.0
118.0
0.4
0.2
0.2
0.2
6.9
284.9
B-237A-1
8361 P
VENT K
232.0
B-262-1
7827 P
VENTS H.I.J
0.8
B-270-2
999758P
VENT IB
0.2
TOTAL ACETALDEHYDE SAP.3
C-2
-------
TABLE
C-2
ACETIC
ACID
EMISSIONS
Page 1
EMISSIONS
building
PERMIT
SOURCE
B-3-1
7760 P
VENT D
0.1
B-5R-1
5945 P
VENT A
19.4
B-5R-2
5946 P
VENT A
20.9
B-5R-3
5947 P
VENT A
30.9
B-7R-3
7828 P
TANK 36
0.1
B-10-5
7444 P
VENT 3A
0.1
B-55-TF
6334 P
9 TANKS
THROUGH
COMMON HEAT
7.4
B-67-1
6492 P
VENT A
VENT B
VENT C
VENT D
VENT E
PERMIT TOTAL
1.8
7.5
8.5
21.0
20.5
59.3
B—81-1
7451 P
VENT A
VENT B
VENT C
VENT D
VENT E
VENT F
VENT G
VENT GG
PERMIT TOTAL
29.8
162.0
11.7
19.8
21.0
5.5
11.0
11.0
271.8
B-82TF
6491 P
COMMON VENT
6.3
B-82-1
6001 P
FUME VENT
5.8
B-99-3
6615 P
C-
-3
VENT A
VENT B
PERMIT TOTAL
0.1
4.4
4.5
-------
Page 2
Acetic Acid
BUILDING
PERMIT
SOURCE
emission
B-122-Y
7792 P
TANKS 1-3
0.1
B-232-1
7777 P
VENTS A&B
VENT C
VENTS D&E
VENT F
VENT G
VENT H
VENT I
VENT T
VENT U
VENT X
TANKS 34,27,44
PERMIT TOTAL
2.0
143.0
8.0
0.5
0.2
0.2
63.0
3.2
72.0
1.5
3.1
296.8
B-244E-2
999696P
VENTS F,G,H
0.1
B-262-1
7827 P
0.6
B-267TF-2
8132 P
TANK 3039
0.1
B-273-1
5980 P
VENT A
0.9
B-290-1
999747P
VENT A
14.7
T-161-1
8110 P
TANKS 38-57,
38-58
11.2
T-200-8
8010 P
TANKS 38-70,
38-71
12.7
WTF-55-1
8331 P
TANKS 102,
109,110
0.5
TOTAL ACETIC ACID
764.3
-------
TABLE C-3
ACETONE EMISSIONS
Page
building
PERMIT
SOURCE
EMISSION
B-3TF-1
8435 P
TANK 3Y-8
0.1
B-13-13
8141 P
VENT LL
VENT NN
PERMIT TOTAL
0.1
0.2
0.3
B-57B-1
7412 P
VENT H
2.9
B-57B-2
7788 P
VENT C
VENT D
PERMIT TOTAL
0.2
0.5
0.7
B-57BTF-1
8368 P
TANK 52-S
0.1
B-80-2
8328 P
CRUDE TANK
TANK 3
PERMIT TOTAL
0.1
0.7
0.8
B-85-1
7416 P
VENT A
133.0
B-90B-1
7775
VENT I
3.9
B-102A-1
5657 P
VENT A
ROOM EXHAUST
PERMIT TOTAL
60.0
1200.0
1260.0
B-102C-1
8370 P
ROOM EXHAUST
1400.0
B-118-2
8104 P
VENT A
VENT B
PERMIT TOTAL
8.4
75.0
83.4
B—125-1
8097 P
VENT A
57.0
B-125A-3
8098 P
VENT A
54.0
B-127-1
7770 P
VENT A
340.0
B-127-2
7764 P
VENT A
288.0
C-5
-------
Page 2
Acetone
BUILDING
PERMIT
SOURCE
EMISSION
B-176-1
7440 P
VENT A
3.8
B-244A
7765 P
VENT A
TANK 93
PERMIT TOTAL
4.3
7.3
11.6
B-244B-1
8372 P
VENT A
TANK 292
PERMIT TOTAL
32.2
8.1
40.3
B-244E-2
999696 P
VENT J
0.1
B—254-1
7428 P
VENT A
152.4
B-267TF-2
8132 P
TANK 3012
TANK 3021
TANK 3061
PERMIT TOTAL
2.3
0.4
0.1
3.8
B-267Y-1
6956 P
VENTS B,C,D
0.9
B-267Y-5
7435 P
TANK VENT
0.1
B-267Y-6
7322 P
VENT IB
VENT 2B
PERMIT TOTAL
0.3
0.3
0.6
B-273TF-1
8365 P
TANK YF-6
0.2
ACETONE TOTAL
3838.0
C-6
-------
TABLE C-4
DIETHYL ETHER EMISSIONS
Page 1
BUILDING PERMIT SOURCE EMISSION
B-10-10 7449 P VENT 3C 0.1
VENT 3K 56.5
PERMIT TOTAL 56.6
TOTAL DIETHYL ETHER 56.6
C-7
-------
TABLE C-5
DIMETHYL EHTER EMISSIONS
Page 1
building permit source emission
B-237A-1 8361 P VENT K 1,830.0
TOTAL DIMETHYL ETHER 1,830.0
C-8
-------
TABLE C-6
FTHYLENE EMISSIONS
Page 1
building
PERMIT
SOURCE
EMISSION
B-6C-27&28
7561 P
VENT A
1.1
B-7R-3
7828 P
VENT J
VENT K
VENT L
VENT R
VENT S
VENT T
VENT U
VENT V
VENT W
VENT Y
VENT Z
114.0
46.0
4.0
1.2
2.0
2.0
1.9
3.5
1.9
4.8
0.5
PERMIT
TOTAL
181.8
B-244-1
8143 P
JET POT
0.9
B-246-2
8337 P
VENT A
0.8
TOTAL
ETHYLENE
184.6
C-9
-------
TABLE C-7
ETHYLENE GLYCOL EMISSIONS
Page 1
BUILDING PERMIT SOURCE EMISSION
B-5R-2 5946 P VENT A 4.3
B-255-1
7530 P
VENTS 1C & ID
4.4
VENT 2D
0.9
VENTS 5A-5G
3.4
PERMIT TOTAL
8.7
B-267Y-8
999689 P
VENT A
0.8
B-270-1
999902 P
VENTS 1C & 10
2.1
VENTS IE & IN
28.0
VENT 1J
2.2
VENTS 1L & 1M
5.3
VENTS 2A-2T
0.2
PERMIT TOTAL
37.8
B-270-2
999758 P
VENT IB
5.0
B-271TF-1
8456 P
TANKS 83-3 & 83-4
0.1
TANK 83-6
0.1
PERMIT TOTAL
0.2
TOTAL ETHYLENE GLYCOL
56.8
C-10
-------
TABLE C-8
METHANOL EMISSIONS
Page 1
building
PERMIT
SOURCE
EMISSION
B— 3-1
7760 P
VENT B
VENT C
PERMIT TOTAL
0.1
0.1
0.2
B-3TF-1
8435 P
TANK 19
0.1
B-10-4
7443 P
VENT A
VENT B
VENT C
VENT D
PERMIT TOTAL
6.0
4.5
0.1
0.1
10.7
B-57B-1
7412 P
VENT A
VENT D
PERMIT TOTAL
0.2
0.3
0.5
B— 220-1
6327 P
STORAGE TANK
HOLD TANK
PERMIT TOTAL
26.7
47.2
73.9
B—221-2
8383 P
LET DOWN TANK
8.4
B-221A-1
8385 P
LET DOWN TANK
8.4
B—221B-l
8384 P
LET DOWN TANK
8.4
B-226P-1
B-236TF-1
6799 P
6325 P
TANK HB-Ol
TANK HC-Ol
& HD-Ol
TANK HC-Ol
TANK HH-Ol
TANK HL-Ol
0.3
VENT 1L 0.6
VENT 1M 0.1
VENT IN 1.1
VENT 2A 2.1
VENT 2B 0.9
VENT 4A-4R 128.0
PERMIT TOTAL 133.1
PERMIT TOTAL
2.6
0.2
2.2
6.4
9.1
20.5
C-ll
-------
Page 2
METHANOL
BUILDING
PERMIT
SOURCE
EMISSION
B-237A-1
8361 P
VENT D
VENT J
VENT K
PERMIT TOTAL
1.8
39.5
127.0
168.3
B-244-2
8363 P
JET POT
7.4
B-246-2
8337 P
VENT H
VENTS I,J,K,
M.N.O
VENTS P,A,R
PERMIT TOTAL
0.1
1.0
0.2
1.3
B-255-1
7530 P
VENTS 1A & IB
VENT 2C
PERMIT TOTAL
35.0
4.4
39.4
B-261-1
8362 P
VENT C
VENT L
PERMIT TOTAL
1.8
41.2
43.0
B-261A-1
6440 P
VENT F
79.0
B-262-1
7827 P
TANKS AA-01
through AE-01
5.8
B-265B-2
7429 P
VENT D
VENT E
VENTS G.H.I
PERMIT TOTAL
4.3
0.3
0.1_
4.7
B-267TF-2
8132 P
TANK 3009
TANKS 3052
& 3053
PERMIT TOTAL
1.5
0.5
2.0
B-267Y-1
6956 P
VENTS B.C.D
0.9
B-267Y-5
7435 P
TANK VENT
0.1
B-267Y-6
7322 P
VENT IB
VENT 2B
PERMIT TOTAL
0.2
0.2
0.4
C-l 2
-------
Page 3
METHANOL
BUILDING
PERMIT
SOURCE
EMISSION
B-270-1
999902 P
VENTS 1A ,11B
VENTS 4A
through 4D,
41 & 4J
VENTS 4E
through 4H,
4K & 4L
PERMIT TOTAL
28.0
79.9
0.2
108.0
T-10-1
8119
P
TANK 19
TANK 20
PERMIT TOTAL
0.4
0.4
0.8
T-21-2
8096
P
TANK 43
1.4
T220-TF-1
8394
P
TANKS CH-100,
CH-101, XH-50,
XH-51, UH-50,
WH-50, ZH-50
6.6
TOTAL METHANOL
733.3
C-13
-------
TABLE C-9 Page 1
METHYL ACETATE EMISSIONS
BUILDING
PERMIT
SOURCE
EMISSION
B-99-3
6615 P
VENT A
VENT B
PERMIT TOTAL
0.1
1.8
1.9
B-232-1
7777 P
VENTS A&B
VENT C
VENTS D&E
VENT F
VENT G
VENT H
VENT I
VENT K
VENT L
VENT U
VENT V
VENT W
VENT Z
VENT AA
VENT AC
PERMIT TOTAL
91.0
252.0
82.0
27.0
9.0
9.0
4.6
0.8
21.0
272.0
5.0
4.0
8.0
0.1
17.3
802.8
B-237A-1
8361 P
VENT K
452.0
B-262-1
7827 P
VENTS H,I,J
34.6
TOTAL METHYL ACETATE 1291.3
C-14
-------
TABLE C-10
METHYL BENZOATE EMISSIONS
Page 1
ruiloing PERMIT SOURCE EMISSION
B-261A-1 6440 P VENT E 56.0
TOTAL METHYL BENZOATE 56.0
-------
TABLE Oil
PROPANE EMISSIONS
Page 1
BUILDING
PERMIT
SOURCE
EMISSION
B-6C-27&28
7561 P
VENT A
0.6
B-7R-3
7828 P
VENT J
VENT K
VENT L
VENT R
VENT S
VENT T
VENT U
VENT V
VENT W
VENT Y
VENT Z
PERMIT TOTAL
67.0
27.0
3.0
11.0
18.7
18.7
18.7
33.5
18.7
45.6
4.4
266.3
B-244-1
8143 P
JET POT
2.1
TOTAL PROPANE
269.0
C-16
-------
TABLE C-12
PROPIONALDEHYDE EMISSIONS
Page 1
BUILDING PERMIT SOURCE EMISSION
B-99A-2 7763 P VENT A 305.7
B-200TF 6331 P TANK 40-75 15.1
TANK 40-74 15.1
PERMIT TOTAL 30.2
TOTAL PROPIONALDEHYDE 335.9
C-17
-------
TABLE C-13
Page 1
P-XYLENE EMISSIONS
BUILDING PERMIT
B-232-1 7777 P
SOURCE EMISSION
VENT C 32 0
VENTS D&E c"n
VENT F
VENT G
VENT H p "
VENT I n 9
VENT U
VENT W
VENT Z i'°Q
VENT AA „ a
TANK 03 °J
PERMIT TOTAL 100.1
TOTAL P-XYLENF 100.1
C-18
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1 . REPORT NO. 2.
EPA-904/9-78-023
3. RECIPIENT'S ACCESSION NO.
A. TITLE AND SUBTITLE
Volatile Organic Compound Emission Inventory For
Tennessee Eastman Company
5. REPORT DATE
December 1978
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Arthur B. Nunn, III
8. PERFORMING ORGANIZATION REPORT NO.
0. PERFORMING ORGANIZATION NAME AND ADDRESS
TRW Environmental Engineering Division
201 N. Roxboro St., Suite 200
Durham, N. C. 27701
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
EPA 68-02-2541
Task #3
1 2. SPONSORING AGENCY NAME AND ADDRESS
u. S. Environmental Protection Agency
Region IV, Air Programs Branch
345 Courtland St.
Atlanta, Ga. 30308
13. TYPE OF REPORT AND PERIOD COVERED
14. SPONSORING AGENCY CODE
1 g. SUPPLEMENTARY NOTES
rj-gf ABSTRACT — "
This document is an emission inventory of volatile organic compounds (VOC) for
-the Tennessee Eastman Company complex in Kingsport, Tennessee. A listing of
emissions, VOC compound, and level of control is listed for each emission source
based on data in the State's permit files and plant inspection.
KEY WORDS AND DOCUMENT ANALYSIS
1 — —
^ DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
e. COSATI l;ield/Group
/\ir Pollution
^mission Inventory
Volatile Organics
Control Equipment
l
------- |