USEPA Region 4
Military Canal Special Study
Homestead Air Force Base, Florida
SESD Project No. 98-0062
October, 1999
Final Report
Volume 1 of 2
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USEPA REGION 4
MILITARY CANAL SPECIAL STUDY
HOMESTEAD AIR FORCE BASE, FLORIDA
SESD PROJECT 98-0062
OCTOBER 1999
US EPA REGION 4 LIBRARY
AFC-TOWER 9™ FLOOR
61 FORSYTH ST. SW
ATLANTA, GA 30303
Homestead
Air Force Base
U.S. ENVIRONMENTAL PROTECTION AGENCY ^£DST^
REGION 4, SCIENCE & ECOSYSTEM SUPPORT DIVISION
HAZARDOUS WASTE SECTION
980 COLLEGE STATION ROAD
ATHENS, GEORGIA 30605-2720 \ VW/ #
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USEPA Region 4
Military Canal Special Study
Homestead Air Force Base, Florida
SESD Project No. 98-0062
October, 1999
Final Report
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MILITARY CANAL SPECIAL STUDY
US EPA, REGION 4, SESD, EIB
This report is approved by Region 4.
/y*&-
Approved By:
Russell L. Wright, Jr. Director
Science and Ecosystem Support Division
Date:
jproved
tichard D. Green, Director
Waste Management Division
u
(3 l?i
Date:
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Distribution List
L. Anthony, RAB
D. Brittain, USEPA, Region 4-15 copies
J. Carter, DERM
C. Crenshaw, AFRC/CEVV
B. Dodson, RAB
J. Mitchell, 482nd SPTG/CEV
W. O'Sullivan, BNP
M. Richardson, RAB
K. Rist, RAB
T. Dillon, NOAA
J. Jeansonne, NOAA
R. Alleman, SFWMD
T. Bartol, AFBCA/DD Homestead
J. Caspary, FL-DEP
D. Frost, BNP
R. Harvey, USEPA, Region 4
M. Kraus, National Audubon Society
B. Lange, Friends of the Everglades - 2 copies
S. Markley, DERM
G. Sloane, FL-DEP
A. Abernathy, OSW-ER/FFRO
H. Vick, Ganett Fleming
L. Wellman, USEPA, Region 4
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Abbreviations
ACC
- Air Combat Command
ANOVA
- Analysis of Variance
BCA
- Base Conversion Agency
BNA
- Base/Neutral/Acid
BNP
- Biscayne National Park
BRA
- Baseline Risk Assessment
CERCLA
- Comprehensive Environmental Response, Compensation, and Liability Act
(Superfund)
CTD
- Conductivity, Temperature, DO
CVAF
- Cold Vapor Atomic Fluorescence
CVAA
- Cold Vapor Atomic Absorption
DC AD
- Dade County Aviation Department
DCPC
- Dade County Pollution Control
DERM
- Dade County Department of Environmental Resources Management
DO
- Dissolved Oxygen
DOC
- Dissolved Organic Carbon
EAB
- Ecosystem Assessment Branch
EDL
- Estimated Detection Limit
EISOPQAM
- Environmental Investigations Standard Operating Procedures and Quality
Assurance Manual
EV
- Effects Value
GFAA
- Graphite Furnace Atomic Absorption
GPM
- Gallons Per Minute
HAFB
- Homestead Air Force Base
HARS
- Homestead Air Reserve Station
ICP
- Inductively Coupled Plasma
ICP-MS
- Inductively Coupled Plasma - Mass Spectrometer
MQL
- Minimum Quantitation Limit
NOAA
- National Oceanographic and Atmospherics Administration
NPL
- National Priority List
OM
- Organic Matter
ORP
- Oxidation Reduction Potential
OU
- Operable Unit
PAH
- Polyaromatic Hydrocarbon
POC
- Particulate Organic Matter
PSD
- Particle Size Distribution
QA
- Quality Assurance
RAGS
- Risk Assessment Guidance for Superfund
RI
- Remedial Investigation
RSMAS
- Rosenstiel School of Marine and Atmospherics Science
SAS
- Statistical Analysis Software
SOP
- Standard Operating Procedure
SESD
- Science and Ecosystem Support Division
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Abbreviations (Continued)
SFWMD
- South Florida Water Management District
SWIM
- Surface Water Improvement and Management
TFW
- Tactical Fighter Wing
TKN
- Total Kjeldahl Nitrogen
USAF
- United States Air Force
USEPA
- United States Environmental Protection Agency
VOC
- Volatile Organic Compounds
WWTP
- Wastewater Treatment Plant
YCTM
- Yeast, Cerophyll® and Tetra Min®
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Executive Summary
The Science and Ecosystem Support Division (SESD), has been tasked by the United
States Environmental Protection Agency (USEPA) Region 4, Federal Facilities Branch, with
conducting a comprehensive investigation of the sediments within the storm water conveyance
system of the former Homestead Air Force Base (HAFB), which includes the Boundary Canals,
storm water reservoir, and Military Canal. Military Canal ultimately discharges to Biscayne Bay,
within the boundaries of the Biscayne National Park (BNP), which is also designated an
Outstanding Florida Water.
The development of the workplan and this report has been a collaborative effort.
Participants include the Air Force, Air Force Reserve, National Park Service, National Oceanic
and Atmospheric Administration, National Fish and Wildlife Service, Florida Department of
Environmental Protection, South Florida Water Management District, Dade County
Environmental Resources Management, and the Tropical Audubon Society. This report
represents the best efforts of these agencies and organizations.
This investigation was conducted to provide a unified and complete dataset on the
contaminants present in the sediments in Military Canal, and, to the extent possible, identify
sources of these contaminants. To keep the focus of the investigation upon Military Canal, no
additional samples were collected from adjacent or similar canals. In addition, this report
presents the analytical results of the sampling effort, with data interpretation. No risk assessment
(human health or ecological) will be conducted by USEPA. In addition, USEPA has performed
no quantitative or qualitative sediment contaminant transport modeling or sampling (i.e, no
bedload samplers were utilized to determine contaminant transport to Biscayne National Park).
The sampling and analytical methods used were the standard primary investigative techniques
used successfully for remedial investigations nationwide, and all applicable quality criteria were
met. Some additional tests (toxicity, grain size, butyltins, alkyl-substituted PAHs, etc.) were
performed at the request of the stakeholders to meet the special needs of this site. It should also
be noted that NOAA recently completed a comprehensive survey of Biscayne Bay (including
Biscayne National Park) and the canals feeding into Biscayne Bay (including Military Canal). It
was agreed with the stakeholders that this investigation would serve to provide information on
sediment toxicity in the tidewater portion of Military Canal. That report is included as Appendix
E. Because of this, USEPA conducted no sediment toxicity tests in the tidewater portion of
Military Canal (salinity 4 > ppt).
The primary purpose of Military Canal is to convey storm water from the former Air
Base, keeping the runway from flooding. In addition, Military Canal is one of several canals in
South Florida that are managed by the South Florida Water Management District (SFWMD) to
control groundwater levels for agricultural purposes. Prior to 1983 it also conveyed the treated
effluent of the former Homestead Air Force Base.
For this investigation, SESD collected 80 sediment samples from Military Canal, 6
sediment samples from the Boundary Canal, and 10 sediment samples from the storm water
reservoir. These samples were analyzed for extractable organic compounds, pesticides, PCBs,
volatile organic compounds, metals, cyanide, herbicides, and mono-, di-, tri-, and tetrabutyltin.
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At every third sampling station (36 total) samples were also collected for grain size analysis,
organic carbon content, and nutrients. Twenty-five of these also underwent toxicity testing
(whole sediment and pore water) using Hyalella azteca, and whole sediment toxicity testing
using Ceriodaphnia dubia.
Sediment samples were also collected from the ditches draining the former WWTP and
the sludge/incinerator ash disposal area. Five samples were collected and analyzed for
extractable organic compounds, pesticides, PCBs, volatile organic compounds, metals, cyanide,
herbicides, and mono-, di-, tri-, and tetra-butyltin.
SESD also collected two surface water samples while Military Canal was operating, i.e.
while the pumps at the storm water reservoir were discharging and flow control structure S-20G
was open. These samples were analyzed for extractable organic compounds, pesticides, PCBs,
volatile organic compounds, metals, cyanide, herbicides, and alkyl substituted polyaromatic
hydrocarbons (PAHs). No contaminants were detected which exceeded their respective RAGS
EV concentration.
The data discussed in this report documents the following contaminant release
mechanisms to Military Canal from the former Homestead Air Force Base:
• The oil-water separators on the fighter washrack.
The former WWTP.
• The ditches surrounding the former WWTP and sludge/incinerator ash disposal
area.
Sources of contaminants to these areas are documented in:
• The October, 1975 United States Air Force (USAF) letter to USEPA outlining
various industrial discharges to the WWTP.
• USEPA's Dade County Industrial Waste Survey (1971) documenting the presence
of several heavy metals in the effluent discharging to Military Canal via tributaries
to Boundary Canal.
• The December, 1975 USAF letter to USEPA stating that the washracks were now
discharging to the WWTP.
• The Air Force Draft OU-11 RI/BRA (Operable Unit-11 Remedial
Investigation/Baseline Risk Assessment) which documents the presence of
contaminants typical of the types of facilities found in the USAF correspondence
from 1975.
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• The July 1999 USEPA Report on Environmental Investigation History of
Homestead Air Force Base and Present Environmental Conditions.
• The SESD investigation of the ditches surrounding the former WWTP and
sludge/incinerator ash disposal area, confirming the presence of these
contaminants in this pathway to Military Canal.
• The SESD Military Canal Special Study, which thoroughly documents the
presence of these contaminants in the sediments of Boundary Canal, the storm
water reservoir, and Military Canal.
Many sediment samples had one or more contaminants present at levels above those cited
in the Risk Assessment Guidance for Superfund (RAGS), or were otherwise significant. In
particular, silver, mercury, lead, cadmium, copper, zinc, total mercury, arsenic, silvex, DDE,
chlordene, several PAHs, and PCB-1254, were present in most samples, often at concentrations
above their respective RAGS EV value (if any). Likewise, many samples exhibited some degree
of toxicity.
Taken as a whole, the analytical and toxicological results of the current investigation are
not remarkably different from earlier investigations performed at Military Canal by SESD,
DERM, and NOAA, The current investigation does, however, provide a much clearer picture of
the quality of Military Canal sediments through much more intensive sampling, and closely links
past HAFB activities to detected contaminants.
Because of USEPA's desire that the quality of this report and its' supporting data be fully
acceptable for decisions made regarding Military Canal, the draft report was subjected to the
external Peer Review process. Three nationally recognized experts independent of USEPA were
selected and given the draft report for formal review. Their comments are addressed in the body
of this report, but in general, the Peer Reviewers were in agreement with the USEPA that sound
scientific methods were used, and that the conclusions are in agreement with the data.
In conclusion, the documents and investigations cited above clearly show the former
Homestead Air Force Base to be a source for many of the contaminants discussed in this report to
the sediments of Military Canal.
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Table of Contents
1. Introduction 1
1.1 Purpose of Report 1
1.2 Site Background 1
1.2.1 Site Description 2
1.2.2 Site History 3
1.2.3 Previous Investigations 4
1.3 Report Organization 8
2. Study Area Investigation 10
2.1 Introduction
2.2 Field Activities 10
2.3 Mapping 12
2.3.1 Surface Water Investigation 12
2.3.2 Sediment Investigation 12
3. Methodology 14
3.1 Introduction 14
3.2 Sediment Sampling Procedures 14
3.3 Field Quality Assurance 15
3.4 Analytical Chemistry - Inorganics 18
3.4.1 Total Metals in Sediment and Surface Water 18
3.4.2 Pore Water 18
3.4.3 Cyanide 19
3.4.4 Nutrients 20
3.5 Analytical Chemistry - Organics 20
3.5.1 Organic/Pesticide Data 20
3.5.2 Extractable Organic Compounds and Pesticides/PCB's 20
3.5.3 Volatile Organic Compounds 21
3.5.4 Organotin Compounds 21
3.6 Sediment Physical Characteristics 21
3.7 Toxicity Testing 21
3.7.1 Hvalella azteca Ten-dav Survival Test 22
3.7.2 Ceriodavhnia dubia Tests 23
3.7.3 Hvalella azteca Pore Water Tests 24
3.7.4 Marine Tests 24
4. Physical Characteristics 25
4.1 Surface Water 25
4.2 Sediment 26
4.2.1 Sediment Core Characterization 26
4.2.2 Sediment Metal/PSD/OM Relationships 28
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5. Nature and Extent of Contamination 29
5.1 Introduction 29
5.2 Military Canal Surface Water 29
5.2.1 Cyanide 29
5.2.2 Extractable Organic Compounds 29
5.2.3 Pesticides/PCBs 30
5.2.4 Volatile Organic Compounds 30
5.2.5 Metals 30
5.3 Canal/Reservoir Sediment Analytical Data 30
5.3.1 Nutrients and Cyanide 31
5.3.2 Extractable Organic Compounds 32
5.3.3 Organotins 34
5.3.4 Alkyl-Substituted PAHs 35
5.3.5 Herbicides 35
5.3.6 Pesticides/PCBs 36
5.3.7 Volatile Organic Compounds 38
5.3.8 Metals 39
5.4 WWTP and Sludge/Incinerator Ash Disposal Area Sediment Data 41
5.4.1 Cyanide 41
5.4.2 Organotins 41
5.4.3 Extractable Organic Compounds 42
5.4.4 Pesticides/PCBs 42
5.4.5 Volatile Organic Compounds 42
5.4.6 Metals 43
5.4.7 Herbicides 43
5.5 Canal/Reservoir Sediment Toxicity 44
5.5.1 Whole Sediment 44
5.5.2 Pore Water 44
6. Summary and Conclusions 45
6.1 NOAA Investigation (Biscayne Bay) 45
6.2 Data Limitations 45
6.3 Summary 46
6.3.1 Sediment Transport 46
6.3.2 Toxicity 47
6.3.3 Sediment Contaminant Distribution 48
6.3.4 Contaminant Sources 52
6.4 Conclusions 55
7. References 58
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Appendices
Appendix A: Figures
Appendix B: Tables
Appendix C: EAB Toxicity Testing SOP
Appendix D: Surface Water Quality Data
Appendix E: Magnitude and Extent of Chemical Contamination and Toxicity in Sediments of
Biscayne Bay and Vicinity. Final Draft
Appendix F: Mote Marine Report
Appendix G: Memorandum - Probable Sources for Military Canal Sediments
Appendix H: Risk Assessment Guidance for Superfund
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1. Introduction
The Science and Ecosystem Support Division (SESD), USEPA, has been tasked with
conducting a comprehensive investigation of the sediments within the storm water conveyance
system of the former HAFB, which includes the Boundary Canal, storm water reservoir, and
Military Canal. In addition, as part of the source area investigation, samples were collected from
the ditches surrounding the former WWTP and sludge/incinerator ash disposal area. This report
presents the results of these investigations.
The primary purpose of Military Canal is to convey storm water from the former Air
Base, keeping the runway from flooding. In addition, Military canal is one of several canals in
South Florida that are managed by the South Florida Water Management District to control
groundwater levels for agricultural purposes. Prior to 1983 it also conveyed the treated effluent
of the former Homestead Air Force Base. Military Canal ultimately discharges to Biscayne Bay,
within the boundaries of the Biscayne National Park.
This investigation was conducted to provide a unified and complete dataset on the
contaminants present in the sediments in Military Canal, and, to the extent possible, identify
sources of these contaminants. To meet this objective, samples were collected from the
Boundary Canal, the storm water reservoir, the ditches surrounding the former wastewater
treatment plant and sludge/incinerator ash disposal area, and Military Canal. This objective has
been met.
1.1 Purpose of Report
This report summarizes the sampling and analysis data collected for this investigation of
the surface water and sediments of the Boundary Canal, the storm water reservoir, Military
Canal, and the ditches surrounding the former WWTP and sludge/incinerator ash disposal area.
To keep the focus of the investigation upon Military Canal, no additional samples were collected
from adjacent or similar canals. In addition, this report presents the analytical results of the
sampling effort, with data interpretation. No risk assessment (human health or ecological) has
been performed by USEPA.
1.2 Site Background
Homestead Air Force Base is located in southern Dade County, Florida, approximately 25
miles southwest of Miami and 7 miles east of the town of Homestead, Florida (Figure 1-1). The
main Base covers approximately 2,916 acres (1).
The topography at HAFB is relatively flat. Most of the trees and buildings previously on
the Base were destroyed by Hurricane Andrew. Some of the flight line support buildings,
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hangars and several office type buildings have been repaired or rebuilt since the hurricane.
Portions of the Base (currently designated the Homestead Air Reserve Station), including the
runways and adjacent areas are surrounded by a security fence and access is restricted through a
series of staffed security gates. Residential areas surround the Base to the north and southwest,
with farmland and plant nurseries on the other boundaries (1), see Figure 1-2.
1.2.1 Site Description
A series of canals form the Boundary Canal system. The Boundary Canal system
surrounds and drains the majority of the Base, discharging to a storm water reservoir, which in
turn discharges to Military Canal. A pumphouse containing three large pumps, is operated by the
Dade County Aviation Department (DCAD) to keep storm water and groundwater at the Base
from interfering with flight line activity. Military Canal and the Boundary Canal were both
constructed prior to 1942 (1).
Military Canal is designed to receive surface drainage solely from the HAFB. Levees (or
berms) have been constructed along the outer edges of the Boundary Canal and Military Canal to
prevent surface drainage from other areas. Prior to 1983, Military Canal also received the treated
effluent from the HAFB WWTP. The HAFB WWTP was closed in 1983. The Base also
formerly operated several washracks that discharged to the Boundary Canals via oil/water
separators. These were later routed to the WWTP (2).
Military Canal ultimately discharges to Biscayne Bay, within the boundaries of the BNP,
approximately 2 miles east of the storm water reservoir. Discharge to the bay is controlled by the
SFWMD flow control structure, S-20G (1).
Vehicular access to Military Canal is controlled with locked gates maintained by the
SFWMD. Foot traffic is not restricted. Currently the canal is crossed by one public road, South
107th Avenue. Prior to the closing of the Base WWTP, South Allapattah Rd. crossed the canal
immediately downstream of the Base. This bridge was removed at about the same time the
WWTP was taken out of service.
The former WWTP and sludge/incinerator ash disposal area are completely surrounded
by an earthen berm approximately 6' to 8' in height. Immediately inside the berm, encircling the
former WWTP and sludge/incinerator ash disposal area is a ditch cut into the limestone rock
native to the area (Miami oolite). This ditch discharges to the storm water reservoir via a culvert
in the northwest corner of the site. At the time of the investigation of this unit (October 15,
1998) the culvert was still open to the storm water reservoir, although it is nearly silted in.
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1.2.2 Site History
The following discussion is taken from the proposed Operable Unit No. 9 Boundary
Canal Record of Decision, June 19971 (3). The land now occupied by HAFB was originally
developed by Pan American Air Ferries, Inc., and used for pilot training. The Boundary Canal
was constructed prior to 1942 (Geraghty and Miller, 1993a). In September 1942, the Caribbean
Wing Headquarters took over the air field, and Homestead Army Air Field was activated.
Homestead Army Air Field was initially used by the Army Transport Command for dispatching
aircraft overseas. However, in 1943, the Second Operational Training Unit began using the
airfield to train the transport pilots and crews.
In October 1945, the base was placed on inactive status due to extensive damage caused
by a hurricane the previous month and anticipated post-war reductions in military activities. The
Base property was turned over to Dade County. Crop dusters used the runways and a few small
industrial and commercial industries used the buildings. The Dade County Port Authority
managed the Base until 1953, when the federal government re-aquired it along with the
surrounding property.
By 1955, the Homestead facility had been rebuilt as a Strategic Air Command Base,
Homestead Air Force Base, and in February, the first operational squadron arrived. The Base
was formally reactivated in November of the same year. During 1960, modifications were made
to the facility to accomodate B-52 aircraft.
A command change from SAC to the Tactical Air Command occurred in July 1968. The
4351st Tactical Fighter Wing (TFW), which flew F-lOOs, was the new host unit until October
1970. In October 1970, the 31st TFW, which flew F-4s, returned from Southeast Asia and
became the host unit for HAFB. In 1981, the 31st TFW was renamed the 31st Tactical Training
Wing, but was changed back to the 31st TFW in October 1984. The 31st TFW was redesignated
again in 1991 to the 31st Fighter Wing. In Junel992, HAFB was reassigned under the newly
formed Air Combat Command (ACC).
On August 24,1992, HAFB was struck by Hurricane Andrew. Approximately 97 percent
of the Base facilities were rendered dysfunctional. As a result of the hurricane, most of the
previous 33 tenants vacated the Base, and many of the damaged buildings were demolished and
removed. Following Hurricane Andrew, the Base was operated by a small contingent of Base
personnel from September 1992, until April 1994. During this period, the administration of
environmental programs at HAFB changed to reflect a change in Base command structure from
ACC to the USAF Base Conversion Agency (BGA). On April 1,1994, approximately one-third
of the Base officially became Homestead Air Reserve Station (HARS). Currently, the 482nd
Fighter Wing of the U.S. Air Force Reserves utilizes this portion of the Base for daily operations
and training. The remainder of the Base is currently under an interim short-term lease to Dade
*Not yet approved by USEPA as of October, 1999.
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County and is being considered for property transfer to DCAD in accordance with the USAF
Base Realignment and Closure program.
In addition to the overwhelming loss of operational facilities, Andrew destroyed nearly all
of the records for the Base. No Base records pertaining to the characterization of facility
operations or discharges appear to have survived.
1.2.3 Previous Investigations
Numerous investigations have been conducted to evaluate the sediments in Military
Canal. These earlier studies are summarized solely to provide a context to the current
investigation. The earliest report USEPA could locate was issued in 1983. The tables discussed
are located in Appendix B.
B1SCAYNE BA Y HYDROCARBON STUDY-1983
This report (4), prepared by the Rosenstiel School of Marine and Atmospheric Science
(RSMAS) in December, 1983, is the earliest study that could be located involving sediment
sampling in Military Canal. Sediments were collected in two phases over a two year period
throughout Biscayne Bay, and analyzed for hydrocarbons. One sample (103, collected 5/13/82)
was taken from the mouth of Military Canal, and in phase II three more samples were collected
from the tidewater channel of Military Canal (samples 238, 239, and 240, collected 8/5/83).
Reportedly the second set of samples were collected because the first sample (103) had contained
relatively high concentrations of petroleum hydrocarbons (771.12 mg/kg total aliphatic
hydrocarbons,). These aliphatic hydrocarbons were in fact diesel range organics, C15 - C25.
During a file search of canal management records, it was noted that the SFWMD had applied
106.0 gallons of diesel fuel to the canal in the previous month (5). When the tidewater sediments
of Military Canal were sampled the following year, concentrations of total aliphatic hydrocarbons
were much lower, and were no longer indicative of diesel. Concentrations of aliphatic
hydrocarbons in mg/kg were 28.50,4.84, and 269.31 (samples 238, 239, and 240, respectively).
Sample locations for this study are presented in Figure 1-3.
MILITARY CANAL ENVIRONMENTAL INVESTIGATION -1995
Four sediment samples were collected in May 1995 by the Environmental Services
Division (now SESD) (7). Analytical results are summarized in Table 1-1, and sampling
locations are shown in Figure 1-4. Cadmium was not detected at quantitation limits of 10-12
mg/kg in the four sediment samples collected. With a quantitation limit of 25 mg/kg, copper was
detected in three of the four samples at concentrations ranging from 32 to 210 mg/kg. Zinc was
reported in all four samples at concentrations ranging from 35 to 420 mg/kg, lead with a
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quantitation limit of 25 mg/kg was reported in two samples at 48 and 66 mg/kg. With a
quantitation limit of 20 to 25 mg/kg, silver was detected in one sample at 95 mg/kg. These
samples were apparently the first sediment samples collected from Military Canal to be analyzed
for silver. Mercury was detected at concentrations ranging from 0.29 to 4.3 mg/kg in three of the
four samples and was not detected at 0.05 mg/kg in the fourth.
In addition, all four of the sediment samples underwent analyses for MicroTox and whole
sediment toxicity. Only one sample (SD-003) exhibited any toxic effect, and it was very mild.
Because of the limited toxic response, no general trend was observed. It should be noted,
however, that sample SD-003 was the closest sample collected to the 107th Ave. bridge.
Apparently, these were the first sediment samples from Military Canal to undergo toxicity
analyses.
MIAMI-DADE TRIBUTARY SEDIMENT TOXICITY STUDY -1995
Three sediment samples were collected in Military Canal by DERM in October 1995 as
part of a larger study of Miami-Dade County canals. The study included a total of 88 sediment
samples collected from 28 canals from July 1995 through may 1996. It was designed as a
complimentary study (upgradient of the saltwater control structures) to a concurrent NOAA study
of Biscayne Bay sediments (NOAA Technical Memorandum NOS ORCA xxx, Final Draft,
9/10/98, Magnitude and Extent of chemical Contamination and Toxicity in Sediments of
Biscayne Bay and Vicinity, Appendix E, see below.). The study included analysis for a variety of
parameters in three major chemical groups (metals, organics, and butyltins) and two bio-toxieity
assays (amphipod and microtox). Sampling locations in Military Canal are presented in Figure
1-5, with selected analytical results from the study presented in Table 1-2.
A final report of the data has not yet been completed, however, all of the laboratory data
and some summary tables have been provided to USEPA. Review of the results and tables
provided from the study identified elevated levels of metals present in Military Canal sediments.
Military Canal sediments contained the highest concentrations for seven of the fourteen metals
analyzed in this study. They include arsenic at 27.3 mg/kg, cadmium at 33.97 mg/kg, copper at
507 mg/kg, chromium at 83.9 mg/kg, mercury at 5.646 mg/kg, silver at 35.72 mg/kg and zinc at
881.9 mg/kg.
None of the samples from Military Canal analyzed using MicroTox exhibited significant
toxicity. However, one of the three sediment samples from Military Canal was significantly
toxic in the whole sediment amphipod text, and was also the only sample collected in all df the
south Miami-Dade canals that exhibited toxicity in this test.
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BOUNDARY CANAL REMEDIAL INVESTIGATION - 1996
Six sediment samples were collected from Military Canal as part of the Boundary Canal
Remedial Investigation in January, 1996 (9). Analytical results are given in Table 1-3, and
sampling locations are shown in Figure 1-6.
Cadmium was not detected in four of these six sediment samples at quantitation limits
ranging from 1.1 to 2.1 mg/kg. Cadmium was detected in the two remaining samples at 1.6 and
2.5 mg/kg. Copper concentrations ranged from 32.9 to 66.3 mg/kg. Lead ranged from 17.1 to
38.8 mg/kg, and zinc from 45.7 to 188 mg/kg. Mercury concentrations were low, and it was not
detected in five of the six samples at quantitation limits of 0.67 to 0.91 mg/kg, but was reported
at 0.73 mg/kg in the remaining sample. Silver was detected in four of the samples at
concentrations of 4.4 to 11.3 mg/kg.
Toxicity tests were performed on these 6 sediment samples. SD-001 and SD-003 were
toxic for H. azteca, and sample SD-004 exhibited a toxic affect for Lumbriculus. Sample SD-
003 exhibited the greatest toxic affect at various concentrations of sediment. This sample was
collected immediately above the flow control structure (S-20G), away from the base.
BISCAYNE BAY SWIM PLAN -1995
The Surface Water Improvement and Management Act (Ch. 373.451-373.459, F.S.), as
passed by the Florida Legislature in 1987 and amended inl991, mandates the preparation and
implementation of a SWIM plan for Biscayne Bay. The SFWMD subsequently prepared the
SWIM plan in 1988, with modifications in 1989, and an extensive revision in 1995 (10).
Appendix B of the Biscayne Bay SWIM plan provides a summary of water quality data
collected from a number of the canals draining Dade County. The monitoring station for Military
Canal is located on the east side of the 107th Ave. bridge. For Military Canal the period of record
is 1988 through 1994. Physical parameters, nutrients, and bacteria are monitored monthly, with
metals monitored bi-monthly. Only the number of samples collected, the mean of the measured
parameter(s), the standard deviation, and the median are reported. Table 1-4 lists the median
concentrations reported for stations in all monitored canals at the first sampling station
upgradient of the flow control structure (first freshwater station) for the period of record.
The summary of Biscayne Bay Projects in Appendix F of the SWIM plan lists "Specific
Water Quality Problems and Areas of Contamination". Military Canal is discussed on pages F8
and F9. The plan states that "The results of the water quality and sediment studies indicated that
Military Canal is polluted with macro-nutrients, trace metals and pesticides. The mercury
content of some of the sediment samples was the highest detected anywhere in Dade County.
The geographical pattern of contamination observed in the sediments points to Homestead Air
Force Base as the probable source of the contamination." A 1990 memo from DERM is then
cited. The 1990 DERM memo cites the probable source of all noted water quality problems
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(specifically phosphorous, nitrate, dissolved oxygen (DO) and color) to be related to agricultural
activities.
The water quality monitoring results indicated four parameters which could be related to
activities at the Base: cadmium, copper, lead and zinc. As can be seen in Table 1-4, the median
concentration of cadmium for the period of record is 0.00 ug/1, copper is 0.1 ug/1, lead is 0.0 ug/1
and zinc is 0.0 ug/1. A fifth contaminant, tributyltin, was monitored on one occasion and
reported at 0.001 ug/1 (the reported detection limit was 0.002 ug/1). Table 1-5 presents the water
quality criteria targets for critical parameters of the SWIM plan.
In addition, three sediment quality evaluations of various canals in Dade County are
summarized in the SWIM plan. The following summary of these investigations is taken from the
SWIM Plan:
Three sediment sampling projects have been funded through SWIM to obtain
relative contaminant loading information in specific locations. The first project focused
on the lower reaches of major tributaries to the bay, including the Miami River. Core
samples were analyzed for aluminum, cadmium, copper, lead and zinc. Overall, the most
contaminated tributaries characterized by this effort were Wagner Creek/Seybold Canal,
Miami River and Military Canal. The least contaminated according to these results, were
Black Creek, Snapper Creek and Snake Creek.
The second sediment project was restricted to South Dade tributaries and was
designed in two phases to gather information in the most contaminated canals. Sediment
pesticides and trace metal concentrations were examined from Black Creek,
Princeton/Moody Canal, Military Canal, Mowry Canal, and Aerojet Canal. The data
indicated that while low level trace metal contaminants were present in all of the canal
sediments, pesticides were absent. Military Canal, however, was discovered to be grossly
contaminated with excessive levels of some trace metals including mercury and some low
level concentrations of organic compounds.
The third sediment project was completed in 1991. The objective in this effort
was to study marina basins. Fourteen basins, in all, were included in the study and one
station located along the Safety Valve in South Biscayne Bay. The results indicated an
accumulation of organic compounds (PAHs, PAEs, and Aroclor 1254) and trace metals
(As, Cu, Hg, Pb, and Zn) in most of the marina sediments. One marina basin apparently
contained sediments with a concentration of total polynuclear aromatic hydrocarbons
exceeding 54,000 ppb. The EPA-recommended water quality criterion for PAHs is zero,
due to the cancer causing potential of these compounds.
7
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1995/1996 NOAA INVESTIGATION OF BISCAYNE BAY
The Magnitude and Extent of Chemical Contamination and Toxicity in Sediments of
Biscayne Bay and Vicinity - Final Draft was issued in September of 1998. Rather than reproduce
the necessary tables and figures here, the reader is encouraged to read the report in its entirety
(Appendix E). This investigation examined Biscayne Bay and the tidewater portion of the
canals feeding into the bay.
It is worth noting, however, that while this study was not specifically targeted at Military
Canal, three sediment sampling stations were established in the tidewater channel. All three
stations exhibited some degree of toxicity, and zinc, lead, total PAHs, and total PCBs were
reported for all three samples. The technical memorandum does not report any finding that
Military Canal is currently having a detrimental impact upon the sediment or surface water
quality of Biscayne National Park. It does note the following, however: "Chemical analyses
indicated the presence of complex mixtures of chemical substances in the most toxic samples.
Overall, contamination was highest by a considerable amount in the lower Miami River,
intermediate in Military Canal and several other tributaries and canals, and lowest in the open
basin south of the Rickenbacker Causeway.
1.3 Report Organization
This report is organized as follows:
• Section 1 - Site description, site history, summaries of previous investigations.
• Section 2 - Description of field activities and description of field mapping
activities.
• Section 3 - Description of sampling, analytical, and toxicity methodologies.
• Section 4 - Description of field activities, results of surface water characterization,
results of visual sediment evaluation.
• Section 5 - The nature and extent of sediment contamination is described.
• Section 6 - The results are summarized and conclusions are presented.
• Section 7 - References.
• Appendix A - Figures.
• Appendix B - Tables.
8
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Appendix C - EAB Toxicity Testing SOP
Appendix D - Surface Water Quality Data
Appendix E - Magnitude and Extent of Chemical Contamination and Toxicity in
Sediments of Biscayne Bay and Vicinity. Final Draft
Appendix F - Mote Marine Report
Appendix G - Memorandum: Probable Sources for Military Canal Sediments
Appendix H - Risk Assessment Guidance for Superfund
9
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2. Study Area Investigation
2.1 Introduction
SESD performed a number of activities in the course of this investigation, in accordance
with the Military Canal Special Study Plan (11). These included extensive field and laboratory
characterizations of sediment samples collected from 95 stations in the canal system draining the
HAFB. At 25 of these stations, extensive toxicity analyses were performed. Surface water
conditions at each sampling station were fully characterized with in-situ measurements. Surface
water samples for chemical analysis were performed at two locations while the canal was
discharging. In addition, 5 sediment samples were collected from the drainage ditches
surrounding the former WWTP and sludge/incinerator ash disposal area. All locations were
positively located using standard surveying techniques (GPS). The field activities performed in
the course of this investigation are outlined below.
2.2 Field Activities
The sampling design selected for the Military Canal sediment investigation was stratified
systematic (i.e., samples were collected at specified intervals). The drainage system for HAFB
was divided into eight strata based principally upon the design of the drainage system and
potential sources. Sampling density for each strata was selected based upon the objectives of the
investigation. The strata (or reaches) of the system and sediment sampling stations were chosen
as follows:
• Tidewater Channel - Ranging from structure S-20G (the SFWMD salinity barrier)
to the endpoint of Military Canal, this is the portion of the system that discharges
directly to the Biscayne National Park (BNP). The tidewater channel is
approximately 2800 feet long. This area is considered critical to the investigation
both because it is the discharge point for the HAFB drainage system, and because
it is freely available to the wildlife of the BNP. Because of the importance of
protecting this critical resource, a sampling station was established every 100 feet
(samples SD-101 to SD-128,28 stations total).
• Downstream Reach - This is the portion of Military Canal lying between the 107th
Ave. bridge and structure S-20G. Being thd futt&est reach from the HAFB,
excepting the tidewater channel, sampling stations were established every 250 feet
(stations SD-202 to SD-222,21 stations total).
• Bridge Reach - This is the reach of Military Canal immediately downstream of the
107th Ave. bridge. Because of input to SESD regarding the possibility of car
dumping being a potentially significant source of contaminants, sampling stations
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were established over a 200 foot segment to determine if a significant "hotspot"
could be located. Sampling stations were established every 50 feet on the
assumption that the "hotspot" (if any) might be quite small and localized (stations
SD-301 to SD-304,4 stations total).
• Upstream Reach - This is the portion of Military Canal lying between the
discharge area of the storm water reservoir and the 107th Ave bridge. Being
immediately downgradient of the receiving area, it is crucial to have a thorough
knowledge of contaminant distribution patterns within this reach. Accordingly,
sampling stations were established at 100 foot intervals within this 2500 foot long
portion of Military Canal (stations SD-401 to SD-425, 25 stations total).
• Receiving Area - The pumps draining the storm water reservoir discharge directly
to this reach, which is wider and shallower than the rest of Military Canal. This
small area formerly received the direct discharge of the HAFB wastewater
treatment plant, and still receives the runoff from the storm water reservoir.
Initially seven sampling stations were planned for this area, but on-site
examination by the dive team revealed very little sediment. One station was
successfully established, SD-503.
• Storm water Reservoir - The Boundary Canal drains directly into the storm water
reservoir, which is approximately 1015 feet long and 224 feet wide. Discharge is
manually controlled via pumps. Two sampling transects were established along
the long axis of the reservoir, 100 feet apart. Sampling stations were established
every 150 feet along the transects (stations SD-610, 10 stations total).
• North/East Boundary Canal - This canal follows the northern perimeter of the
HAFB, ultimately discharging to the storm water reservoir. Complete
characterization of this canal was well beyond the scope of this study. Sample
stations were established at 150 foot intervals at the lower end of the canal,
immediately upgradient of the storm water reservoir (stations SD-700 to SD-703,
3 stations total).
• South/West Boundary Canal - This canal follows the southern perimeter of the
HAFB, ultimately discharging to the storm water reservoir. Complete
characterization of this canal was well beyond the scope of this study. Sample
stations were established at 150 foot intervals at the lower end of the canal,
immediately upgradient of the storm water reservoir (stations SD-800 to SD-803,
3 stations total).
All sediment sample locations are shown in Figures 2-1 through 2-6.
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Two surface water samples were collected under the nominal discharge conditions of the
Canal. Two of the pumps (rated at 100,000 GPS, or gallons per minute, each) at the storm water
reservoir were turned on and the flow control structure S-20G was opened simultaneously.
Sample collection was begun 20 minutes later, after the system had a chance to move some
water. The samples were collected at the following locations:
• Receiving Area - This sample was collected from the shallow spot at the
conjunction of the receiving area and the downstream reach.
• Tidewater Channel - This sample was collected at the endpoint of Military Canal
where the grade of the canal rises to the level of the BNP, at the point of discharge
to the BNP.
Five sediment sampling stations were selected for sampling from the ditches surrounding
the former WWTP and the sludge/incinerator ash disposal area. These samples were collected
from approximately 0" to 6" in depth using a hand auger.
2.3 Mapping
All sampling stations were located using global positioning system (GPS)
instrumentation. A sounding was performed at each station to determine the depth of the water
column. No soundings were performed at the former WWTP. Water was present at most
stations, however, approximately 6" (or less) deep.
2.3.1 Surface Water Investigation
Conductivity, temperature, pH, redox, and dissolved oxygen were measured at 1 foot
intervals at each sampling station using a multiparameter instrument. All instrumentation was
properly calibrated each morning prior to the beginning of field work. In addition, all
instrumentation underwent post-calibration checks at the end of each day's field activities to
ensure that "drift" or other significant problems had not occurred. This data was used to
determine surface water quality in the canal system. No surface water investigation was
performed at the former WWTP.
2.3.2 Sediment Investigation
A thorough field examination of the sediment was performed at each sampling station.
This included general observations such as debris noted in the area, sulfide odors, vegetation,
sunken logs, etc. This information is presented in Table 2-1. In addition, clear coring devices
were pushed to refusal at each location, and depth, compaction (if any), and color horizons were
12
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precisely noted (color was determined using a Munsell color chart). This sediment
characterization was not performed at the former WWTP.
13'
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3. Methodology
3.1 Introduction
In order to ensure sample integrity and minimize loss of the fine particulates during
sample transport to the surface and transfer for mixing, sediment samples were collected using
two teams of three divers each. Samples were relatively undisturbed in the sampling process and
kept upright (or capped) at all times to prevent mixing of overlying water with pore water.
Divers were outfitted with dry suits and full face masks with positive pressure ventilation.
Sampling at most stations was limited to 6" depth as this interval was considered to be the
maximum that was bioavailable. In addition, the upper 6" interval was considered to be the most
likely to be re-suspended and thus made available for re-deposition in the BNP.
3.2 Sediment Sampling Procedures
It was logistically impossible to collect sediments in one large core of sufficient sample
volume to split between several containers to meet the analytical requirements of the study (e.g.,
synthetic organics, metals, volatile organic compounds, x-ray fluorescence, particle size
distribution, toxicity testing, and profile characterization). For instance, if an eight-inch diameter
core was utilized, there would have been a high probability of sample loss, especially from the
silt and clay particle size classes. In addition, it would have been physically impossible to
enclose the bottom of a core of that size for transportation to the surface for processing.
Therefore, based on these limitations, the requirement to collect sufficient sediment for chemical
analysis as well as physical characterization, while at the same time keeping the sample relatively
undisturbed, necessitated the use of individual core tubes for the collection of multiple aliquots.
Visual observations, as described above, demonstrated that the spatial distribution of sediment
was relatively homogeneous between sample stations within a given reach, with a few
exceptions. Consequently, variation in sediment chemistry between aliquots from a sample
station was assumed to be insignificant. In order to minimize sample variability at each sample
station, divers transported the sampling devices to the bottom within a basket to ensure that
samples were collected within the same vicinity (i.e., less than 1 square meter unless logistically
impossible; e.g., trees, limerock).
Given the hiq^ porosity and water content of the organic floe, complete exclusion of
water from the water column was logistically impossible. However, based on the little to no
velocity along the bottom during sampling, geochemical equilibrium between the organic floe
and the immediate overlying water column is assumed.
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Given the difficult and heterogenous site conditions, samples were collected as follows:
• The particle size and organic content samples were collected in duplicate, utilizing
2 inch acrylic core tubes that were pushed to refusal and then visually classified
according to texture by sight and/or feel, structure, presence of shell fragments,
and color utilizing Munsell Soil Color Charts. The upper 6" of the strata was then
transferred to containers for laboratory analysis;
• sampling for chemical analyses was performed upon samples collected from the
0" - 6" depth, utilizing 2 inch Teflon core tubes cleaned in accordance with the
EISOPQAM, or pre-cleaned sample jars, depending upon the bottom conditions
(in general, sample jars were used for sample collection in Military Canal between
the saltwater control structure and the pumphouse, where the algal mat was
thickest). Upon being brought to the surface, the clear overlying water was very
gently decanted off the sample, then the remaining sample was processed
according to the Environmental Investigations Branch Standard Operating
Procedures and Quality Assurance Manual (EIBSOPQAM) (12), as specified in
the Military Canal Special Study Plan (11);
• a 1 quart glass container was used to collect samples for toxicity testing. The
process was repeated until a sufficient volume was collected for testing. The
toxicity sample was then mixed and placed into a sample jar; and
• four "deep" profiles were collected and vertically composited for analysis.
Sediment samples for volatile organic compounds (VOC) analyses were containerized
underwater by the divers. They were then subsampled within 30 minutes of collection, consistent
with the requirements of USEPA Method 5035.
3.3 Field Quality Assurance
Field Quality Assurance (QA) activities were integrated into the field activities at all
levels. Preservative blanks, equipment rinse blanks, blanks of the field organic-free water system
and VOC trip blanks were all collected as specified in the EIBSOPQAM and the study plan.
Table 3-1 is a summary of all the field QA blanks that were collected as part of this effort.
Table 3-2 is a summary of the analytical results of the field blanks. Tables 3-3 through 3-7
present all of the reported field QA information, including minimum quantitation limits. Sample
handling, preservation, shipment, etc., was conducted in accordance with EIBSOPQAM and the
study plan. The following blank samples were collected during the primary field sampling effort
in November 1997:
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Portable Organic-Free Water System Blank (sample QA-900) - No cyanide,
pesticides, or PCB's were reported in the water system blank. Two metals were detected: zinc at
1.5 ug/1 and lead at 0.11 ug/1. These concentrations are not significant. One extractable organic
compound, (methylethylidene) bisphenol was detected at 10 ug/1. In addition, the VOC aliquot
for this blank was not analyzed. The impact of this is minimal, if any, based on examination of
the environmental and QA/QC data.
Preservative Blank (sample QA-903) - No cyanide was detected in the cyanide blank.
Calcium (0.087 mg/1) and sodium (0.47 mg/I) were detected in the metals blank. These metals at
these concentrations are not significant.
Equipment Rinse Blanks (samples QA-904 and QA-911) - No metals, cyanide,
extractable organic compounds, pesticides, or PCB's were reported in the equipment rinse
blanks. Acetaldehyde (20JN ug/1) and 1,4-dichlorobenzene (0.50J ug/1) were reported in QA-
911. Acetaldehyde was not detected in any environmental samples and its presence in the blank
is therefore insignificant. The potential significance of 1,4-dichlorobenzene in the VOC blanks
will be discussed separately. The VOC aliquot for sample QA-904 was not analyzed. The
impact of this is minimal, if any, based on examination of the environmental and QA/QC data.
Trip Blanks (samples QA-901, QA-902, QA-905, QA-906, QA-907, QA-910, QA-
912) - Samples QA-901, QA-902, and QA-905, were not analyzed because their corresponding
environmental samples were not analyzed either due to missed holding times or improper
preservation. The environmental samples were subsequently re-collected. For the remaining trip
blanks, no VOC's were detected in QA-907, QA-910, and QA-912. Sample QA-906 contained
3.7 ug/1 toluene and 0.55 ug/1 trichlorofluoromethane, which are discussed below.
Field Prepared Blanks (samples QA-908, QA-909, QA-913) - Sample QA-908
contained 7.0 ug/11,4-dichlorobenzene. Sample QA-909 contained petroleum product (no
concentration reported), and sample QA-913 contained 0.69J ug/11,4-dichlorobenzene, 0.64J
ug/1 (m- and/or p-)xylene, and 0.6J ug/1 toluene. No (m- and/or p-)xylene was repotted in any
environmental samples and its presence in the blank is therefore insignificant. The potential
significance of 1,4-dichlorobenzene will be discussed below.
A number of contaminants not normally associated with volatile organic compounds
blanks were present in both the field prepared blanks and environmental samples. The precise
source of the contaminants is unknown, but is believed to be tfffi field organic free water system.
Trichlorofluoromethane was detected in 3 of the 80 environmental samples analyzed at
concentrations ranging from 0.67J ug/kg to 12 ug/kg. Because trichlorofluoromethane was
detected in only one trip blank at a low (0.55 ug/1) concentration and was only detected at low
concentrations in 3 of 80 samples its presence had no significant impact upon the study, and is
considered insignificant.
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Toluene was reported in 23 of the 80 environmental samples analyzed at concentrations
ranging from 0.86J ug/kg to 34J ug/kg. While the number of samples with reported toluene is
relatively high, the presence of toluene in one of the trip blanks at (3.7 ug/1) indicates a near
baseline presence.
1,4-dichlorobenzene was detected in 13 of 80 samples tested for VOC's at concentrations
ranging from 0.59J ug/kg to 32 ug/kg. It was also reported at 0.50 ug/1 in an equipment rinse
blank and 7.0 ug/1 in a field prepared blank. The presence of 1,4-dichlorobenzene in these field
QA samples again indicates a near baseline presence.
As discussed above, some stations had the volatile organic compounds sample recollected
to ensure that the submitted samples were of the best quality, and ten percent of the samples were
collected as duplicates to ensure proper sample handling.
Because the volatile organic compounds samples could not be preserved (the sediments
reacted with the preservative) the volatile organic compounds samples were shipped overnight
back to the SESD laboratory on ice for analysis using a closed loop purge and trap system within
48 hours of collection. This inability to chemically preserve samples necessitated the
recollection of volatile organic compounds samples at several stations. These samples were
identified by appending an "R" (Resampled) to the sample ID. This volatile organic compounds
data is included with the other chemical data for a given sampling station, although, of course,
the date and time of collection differs from the remaining analyses.
Sediment for the remaining laboratory analyses was placed into large glass bowls and
thoroughly mixed prior to being placed into the appropriate sample jar. Ten percent of the
samples were duplicates, where a second sample was collected from the same mixing bowl, as a
check on sample handling. Duplicate samples were identified by appending "DUP"
(DUPLICATE) to the sample ID.
The following blank samples were collected during the surface water sampling event in
February 1998:
Trip Blank (QA-001-TB) - No volatile organic compounds were reported in this sample.
Preservative Blank (QA-001-PB) - No cyanide was detected in this sample. Two metals
were reported, sodium at 1.2 mg/1 and zinc at 1.2 ug/1. Sodium was detected in the two surface
water samples at 1600 and 22 mg/1. These values are significantly higher than the preservative
blank, indicating that sodium is actually present in the surface water at Military Canal, which is
to be expected. The reported presence of zinc in the surface water samples at 3.4 and 4.1 ug/1,
however, indicates at near baseline presence.
The following blank samples were collected during the investigation of the ditches
surrounding the former WWTP:
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Trip Blank Spike (QA-993-TSK) - All recoveries were within acceptable limits.
Trip Blank Soil (QA-000-TBS) - No volatile organic compounds were detected in this
blank sample.
Trip Blank Water (QA-992-TBB) - No volatile organic compounds were detected in
this blank sample.
3.4 Analytical Chemistry - Inorganics
3.4.1 Total Metals in Sediment and Surface Water
All metal samples were prepared for analysis by a hot acid extraction, USEPA Method
200.2. All metals were analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)
with the exception of selenium, mercury, strontium, tellurium, yttrium, aluminum, calcium,
magnesium, iron, sodium and potassium. Selenium was analyzed by Graphite Furnace Atomic
Absorption (GFAA). Mercury was analyzed by Cold Vapor Atomic Absorption (CVAA) or
Cold Vapor Atomic Fluorescence (CVAF). Most samples were analyzed for mercury by CVAA.
CVAF was utilized for those sediment samples whose concentration was below the CVAA
minimum quantitation level (MQL) of 0.05 mg/kg. The remainder of the noted elements were
analyzed by Inductively Coupled Plasma (ICP). Precision and accuracy guidelines of the
analytical methods (EPA 200.8,200.7,245.1,245.7 and Standard Methods 3113B) were met.
3.4.2 Pore Water
Pore Water samples (Section 3.7.3) of approximately 50 mis each were received for low
level metal analyses Results have been reported for both total metals and acid soluble metals.
Some analytes have results reported for total metais only, some for acid soluble metals only and
some analytes have results reported for both.
Quality control blank solutions indicated that trace levels of copper, lead, barium and zinc
and aluminum were introduced during the sample preparation process. (The SESD Athens
facility does not have a 'metals clean room'). limited sample volume precluded another sample
digestion, however, enough original sample was available to perform ..direct.analysisfor 'acid
soluble'metals, USEPA Method 200.1 R-4- (R4modtf.cat.onof Method200 1 is ad,rect
analysis of the acid preserved sample after settling of any pamculates rather than filtration pnor
to analysis.) These five metals have been reported as acid soluble only because of a possible
high bias introduced during sample digestion.
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Acid soluble metals were analyzed by ICP-MS. The following metals were reported with
acid soluble results: silver, barium, beryllium, cadmium, cobalt, chromium, copper,
molybdenum, nickel, lead, antimony, tin, titanium, thallium, yttrium, zinc, aluminum and
uranium.
Total metals were analyzed by ICP-MS, ICP and GFAA. The following metals were
reported with total metal results: silver, arsenic, beryllium, cadmium, cobalt, chromium,
molybdenum, nickel, antimony, selenium, tin, strontium, tellurium, titanium, thallium, vanadium,
yttrium, manganese, calcium, magnesium, iron, sodium, potassium and uranium.
Silver detection limits have been elevated 10 fold to 1 ug/1 to preclude the possibility of
reporting false positives. Silver is subject to 'carryover' problems at levels below 1 ug/1. Long
wash periods do not necessarily solve the problem because PVC pump tubing can trap silver and
release it sporadically at a later time. Limited sample volume did not allow for multiple analyses
or analyses at multiple dilutions to confirm the presence of low level silver. Levels above 1 ug/1
can be considered valid.
Arsenic and selenium were analyzed for both total and acid soluble metals. Arsenic
results for acid soluble metals were consistently biased higher than total metals. The bias ranged
from 0 to 20% and was observed by both ICP-MS analysis (EPA Method 200.8) and GFAA
analysis (Standard Methods 3113B). Insufficient sample precluded re-analysis or further
investigation of the bias. (All selenium results were less than detection limit). Total metal
results were reported for arsenic and selenium since an extensive data base documenting the
accuracy and precision of this test exists. Additionally, both preparation and analysis quality
control data indicated that the Total Metal data were 'in control'. Acid soluble results were not
reported for either of these metals since some doubt surrounded the analyses.
Titanium and tin results for acid soluble metals are higher than total metal results for
some of the pore water samples. This is not unexpected. A nitric acid digestion was performed
on the samples (omitting hydrochloric acid) to minimize chloride interferences for the ICP-MS
analysis. Titanium and tin are subject to forming oxides in a nitric acid digestion which will
result in a slightly low bias in the total metal analysis vs the acid soluble analysis. Biases
between total metals and acid soluble results ranged from 0 to 50% with the largest differences
generally occurring in the lower concentration samples.
3.4.3 Cyanide
Cyanide was analyzed by USEPA Method 335.4. Detection limits in sediment samples
were impacted by sulfide interferences.
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3.4.4 Nutrients
Total Kjeldahl Nitrogen was analyzed using USEPA Method 351.2, Phosphorus was
analyzed using USEPA Method 365.1, modified for sediments. (Modification consists of
changing digestion reagents to 5 mL of sulfuric acid and 10 mL of persulfate.) Nitrate/nitrite was
analyzed using USEPA Method 353.2, modified for sediments. (Modification consists of
digesting the sample in 2.5 mL of 10% sulfuric acid.) Ammonia was analyzed by USEPA
Method 350.1, modified for sediments. (Modification consists of reducing sodium hydroxide
amounts to 1ml and distilling into 0.4N sulfuric acid).
3.5 Analytical Chemistry - Organics
3.5.1 Organic/Pesticide Data
All data were generated by methods based on USEPA's Methods for Evaluating Solid
Waste Physical/Chemical Methods, SW-846 unless otherwise noted. The specific method is
listed along with the parameters.
3.5.2 Extractable Organic Compounds and Pesticides/PCB's
Water Samples - Samples were extracted using continuous liquid extraction, USEPA
Method 3520B. Determinations were made for pesticides/PCB's using USEPA Method 8081.
Determinations for extractable organic compounds was by method 8270C. In order to obtain
lower levels of detection for Polynuclear Aromatic and Alkyl substituted Polynuclear Aromatic
Compounds, Gas Chromatography/Mass Spectrometry Selected Ion Monitoring was used. This
determination was based on Geochemical and Environmental Research Group Trace Organics
Contaminant Analytical Techniques, Texas A & M University, College Station, Texas (13).
Sediment Samples - Samples were extracted using sonication, USEPA Method 3550A.
Determinations were made for pesticides/PCB's using USEPA Method 8081. Determinations for
extractable organic compounds was by method USEPA Method 8270C. Determinations were
made for herbicides was by method USEPA Method 8151 A. In order to obtain lower levels of
detection for Polynuclear Aromatic and Alkyl substituted Polynuclear Aromatic Compounds,
Gas Chromatography/Mass Spectrometry Selected Ion Monitoring was used. This determination
was based on method Geochemical and Environmental Research Group Trace Organics
Contaminant Analytical Techniques, Texas A & M University, College Station, Texas (Sampling
and Analytical Methods of the National Status and Trends Program, Volume IV. 121, National
Oceanographic and Atmospherics Administration (NOAA) Technical Memorandum NOS ORCA
71) (13).
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3.5.3 Volatile Organic Compounds
Water Samples - Samples were analyzed using USEPA Method 8260B.
Sediment Samples - Samples were prepared using USEPA Method 5035.
Determinations were made using USEPA Method 8260B.
3.5.4 Organotin Compounds
All samples were prepared using a method from the Skidaway Institute of Oceanography,
University of Georgia, #10 Ocean Science Circle, Savannah, Georgia. Determinations were
made by Gas Chromatography/Mass Spectrometry Selected Ion Monitoring (14).
3.6 Sediment Physical Characteristics
The particle size distribution (PSD) and percent organic matter was determined by Mote
Marine Laboratory utilizing a laser particle size analyzer. The process was overseen by two US-
EPA employees. Mote Marine Laboratory's report is included as Appendix F.
3.7 Toxicity Testing
Since the focus of this study was on sediment contamination and toxicity in Military
Canal as a potential threat to Biscayne National Park, sediment and pore water toxicity tests were
used. Sediments collected by divers and were distributed intact to sample containers for
transport to the laboratory on ice. Once they were received at the laboratory, sediments were
held at 4°C and used in toxicity tests within six weeks of collection. Porewater was extracted <
24 h prior to use in tests, and held at 4°C until ready to use. Toxicity tests were performed on 25
(-25%) of the sediments collected for chemical analysis (samples SD-202, SD-205, SD-208, SD-
211, SD-214, SD-217, SD-220, SD-301, SD-304, SD-401, SD-404, SD-407, SD-410, SD-413,
SD-416, SD-419, SD-422, SD-425, SD-503A, SD-601, SD-604, SD-607, SD-610, SD-702 and
SD-802). Toxicity tests were not performed for porewaters with salinity >4 ppt.
Pore waters used in toxicity tests were analyzed for metals, PCBs, pesticides, nutrients,
organotins, herbicides, and alkyl-substituted PAHs. Toxicity test protocols are detailed in
Appendix C. The procedure utilized is a slight modification of that proposed in the study plan,
which results in a smaller sediment test volume.
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3.7.1 Hvalelfa azteca Ten-day Survival Test
Preparation for H. azteca sediment tests began with the isolation of seven to ten-day old
H. azteca between standard #35 and #45 sieves. After being collected from the in-house culture,
the amphipods were placed in moderately hard water at 25 °C. fed, and held overnight. No
acclimation to the test conditions was required. Exposure chambers were prepared by placing
and compacting 20 g of sediment in a 100 ml glass beaker, and adding 80 ml of moderately hard
reconstituted freshwater (15). Test chambers were then placed in an incubator at 25 °C and
allowed to stand overnight before test animals were added (See EAB/SOP (Standard Operating
Procedures) in Appendix C). Six replicates containing five animals each were used per test site.
This test is a miniaturized version derived from USEPA Method 1000.0. It was the
standard test protocol in use by the Ecological Assessment Branch of the SESD for CERCLA
(Comprehensive Environmental Response, Compensation, and Liability Act) projects at the time
of this study to minimize the collection of hazardous sediments. Periodic-reference toxicant tests
are performed on animals from the in-house culture using KC1 to track general health and
sensitivity, therefore, none were conducted side-by-side with the sediment tests. Instead, a
control sediment of sand and a reference sediment collected from the Ogeechee River, Georgia
were run with each set of Military Canal sediments. The analytical results from the reference
sediment are presented in Table 3-8 (A-F).
The alkalinity, pH, temperature and conductivity of overlying water were measured in
each container, then five amphipods were added to each using a transfer pipette. Finally, the
chambers were randomly distributed in an environmental chamber set at 25°C with light
equivalent to 10-20 |iE/nr/s, or 50 to 100 foot-candles (ft-c) and a photoperiod of 16 h of light
and 8 h of darkness. After two hours, each chamber was examined to determine if any animals
were floating on the water's surface. Such organisms were removed, and replaced. Then the
amphipods were fed 0.1 ml of YCTM (yeast, Cerophyll® and Tetra Min®) and 0.1 ml of a
Selenastrum capricomutum suspension. Test maintenance included daily measurement of
dissolved oxygen concentration, pH and temperature in one replicate from each site, and an 80%
replacement of overlying water (60 - 65 mis) every other day. The dissolved oxygen
concentration did not fall below 40% of saturation (approx. 3.2 mg/L), therefore no aeration was
necessary.
Organisms were counted on day 0 and again at test termination. Animal activity or
behavior was recorded daily on bench sheets as observed. After ten days, the test was
terminated, the sediment was passed through a series of sieves (500 um to 64 um), animals were
counted and the number of surviving and dead amphipods was recorded. Test results were
acceptable if mean control survival was at least 80%. Toxicity was determined by comparing the
survival of amphipods in test samples to their survival in the control. Statistical analyses were
performed on arcsine transformed percent survival data at each site. The Shapiro-\Yilkes and
Bartlett's tests were used to determine if the data represented a normal population. If the test
data failed either the test for normality or the test for homogeneity of variance, the Steel's Many-
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One Rank Test or the Wilcoxon Rank Sum Test was used instead of Dunnett's test as
recommended.
The relationship between toxicity and sediment contaminant concentrations was
investigated on log,0 transformed, dry weight adjusted chemical data using correlation and
regression analysis (16).
3.7.2 Ceriodavhnia dubia Tests
Whole sediment toxicity tests were also performed using C. dubia. Zooplankton are used
in sediment toxicity tests because they integrate water column and sediment exposure impacts,
represent an additional life form that is important in aquatic systems, can give a sublethal
measure of toxicity in a short period of time, and a large database has been developed relating
their sensitivity to various contaminants (17). The C. dubia test (See SOP in Appendix C) was
conducted using methods similar to those in the "Ceriodaphnia dubia Three-brood Survival and
Reproduction Test" (USEPA Method 1002.0). Adult zooplankton were isolated in individual
cups to permit collection of known-age neonates (young). Test chambers were prepared by
placing 20 ml of sediment in the 100 glass beaker, then adding 80 ml of moderately hard
reconstituted freshwater and letting them settle overnight in a 25 °C environmental chamber with
a 16 h light and 8 h dark photoperiod at 50-100 foot-candle. Tests were not performed using
pore waters with salinity > 4 ppt.
At the start of the test, one neonatal zooplankton (<24 h old) was placed in each 100 ml
sediment test chamber containing 20 ml of sediment and 80 ml moderately hard reconstituted
freshwater (15). Acclimation to the test conditions was not necessary. Each day young produced
in the previous 24 hours were counted prior to the replacement of overlying water. The test was
concluded after 7 days or when three broods of young had been produced by at least 60% of the
adults. Standard reference toxicant tests are performed regularly with the in-house culture to
track their health and sensitivity, therefore none were conducted with these samples. However.
10 replicates of the control and reference sediments were included along with each set of Military
Canal sediments. The Shapiro-Wilkes and Bartlett's tests were used to determine if the data
represented a normal population. If the test data foiled either the test for normality or the test for
homogeneity of variance, the Steel's Many-One Rank Test or the Wilcoxon Rank Sum Test was
used instead of Dunnett's test as recommended.
The relationship between toxicity and sediment contaminant concentrations was
investigated on log10 transformed, dry weight adjusted chemical data using correlation and
regression analysis (16).
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3.7.3 Hvalelfa azteca Pore Water Tests
Pore water samples were collected in the laboratory from sediments by centrifugation in a
Sorvall ultracentrifuge for 10 min at 5,000 g and was not filtered prior to its distribution into
sample containers or toxicity test chambers. Only porewater with salinity < 4 ppt were used in
toxicity tests. Samples and blanks collected for chemical analysis were preserved, tagged,
transported and analyzed according to guidelines contained within USEPA Region 4 Analytical
Support Branch Standard Operating Procedures (18). Sulfide concentrations were measured
using a Hach colorimetric method.
Fifteen nils of pore water were placed in each 30 ml glass beaker containing a one inch
square of Nitex® netting that gave the amphipods a surface under which to hide. The test
chambers were placed in a 25 °C environmental chamber and allowed to come to temperature.
Then, five H. azteca. seven to ten days old, were randomly distributed into each of six replicates
per site. They were fed a 0.25 ml aliquot of Tetra Min® fish food per chamber at the start of the
test (and after 48 h), then the chambers were covered with plastic wrap to minimize evaporation
and placed in the 25°C environmental chamber with a 16 h light:8 h dark photoperiod. At the
end of the 96-h test period, the number of live and dead amphipods were counted for each
replicate and sample, and recorded. Pore water pH, D.O., conductivity, temperature, alkalinity
and hardness were measured at the start of each test and at the end. Mortality data were
evaluated by analysis of variance (ANOVA) and Dunnett's Test to determine in which sediments
survival was significantly different from the related control. LogI0 transformed, dry weight
adjusted toxicity data were also compared to sediment chemical concentrations via correlation
and regression analyses to identify compounds related to mortality.
3.7.4 Marine Tests
No additional toxicity tests were performed with marine sediments and organisms. The
1995 NOAA Draft Technical Memorandum (Appendix E) provides extensive data in this area.
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4. Physical Characteristics
4.1 Surface Water
The in situ characteristics of surface water quality are directly related to the
physicochemical processes within a waterbody. Since such processes are complex and
interrelated, it was not the intent of the present study to address such processes which have been
previously visited in various waterbodies by the research community. However, since
assessment of insitu water quality parameters cannot only be used in characterization of a
waterbody, but also provide some insight toward explanation of the distribution of sediment
material as well as the potential for sequestration or release of contaminants from the sediments
to the water column, certain insitu parameters were measured longitudinally and vertically
throughout Military Canal and the associated storm water retention basin and boundary canals.
Those parameters were as follows: DO; temperature; conductivity/salinity; pH, and oxidation
reduction potential (ORP). The collected data is presented in tabular and graphical formats in
Appendix D.
Multiprobe water quality monitors were the instruments of choice for characterization of
insitu water quality. Each project team (one working seaward and another working upstream of
the S-20G water control structure) used Hydrolab H20 multiprobe sondes to obtain profiles of the
previously stated parameters at each station associated with sediment collection. Each sonde was
calibrated at the beginning of each day using laboratory and/or commercially prepared standards
for conductivity, pH, and ORP. Dissolved oxygen calibration was conducted using the azide
modified Winkler titration method. At the end of each sampling day, each instrument was again
checked against these standards and known dissolved oxygen concentration to assess calibration
drift that might have occurred during the day. All instruments performed optimally and within
limits specified in the SESD, Ecological Assessment Branch (EAB) SOP or manufacturers'
specifications.
As expected, and as confirmed in station specific data within this report, Military Canal is
distinctively two separate water bodies as dictated by the S-20G water control structure. Seaward
of the structure, the influence of Biscayne Bay dictates conductivity/salinity considerably higher
than found upstream of the S-20G structure. Although salinity at Stations 101-128 revealed this
segment of Military Canal to be generally well mixed both longitudinally and vertically, this
segment of Military Canal exhibited depressed dissolved oxygen particularly with progression
from the mouth of the canal to the water control structure. Since diel oxygen dynamics was
clearly not the focus of this study, and since profiling at each station was conducted only once
irrespective of time and tidal stage, explanation for the suppressed DO is only speculative.
Upstream of water control structure S-20G, Military Canal exhibits gradation in density
(conductivity/salinity) stratification both vertically and longitudinally. The degree of vertical
stratification is clearly, and as expected, more pronounced with proximity to the S-20G water
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control structure (Series 200 Stations). If a background conductivity generally in the 475-500
microsiemens/centimeter range is assumed based upon measurements taken in the storm water
retention basin, boundary canals, and immediately downstream of the storm water pumping
station, then Figure 4-1 presents a general depiction of the longitudinal density gradient
throughout the segment of Military Canal between the pumping stations and S-20G water control
structure. Review of station specific vertical CTD (conductivity, temperature, DO) profiles
(Appendix D) allow a discriminant observation of the relative degree of stratification through
the canal. Essentially, a "salt wedge", decreasing in intensity upstream, exists through a
considerable portion of the canal above the S-20G control structure. At the most downstream
stations (respective to the S-20G structure) the strength in concentration of the wedge produces
pronounced stratification at generally the eight foot (8') depth, with the lower approximate two
feet of the water column being of considerably higher conductivity than the water column above
it. This stratification does not, however, affect the dissolved oxygen concentration within the
higher density layer. Dissolved oxygen concentrations at all stations throughout the portion of
Military Canal upstream of the S-20G structure are quite high, well above saturation during the
survey period. Observation of morning and afternoon DO measurements at different stations
throughput this segment of the canal clearly indicates the absence of suppressed dissolved
oxygen as exhibited by the seaward segment of the canal.
Probably the most important consideration relative to the horizontal and longitudinal
conductivity profiles throughout Military Canal is the influence that the density gradient might
have respective to sediment distribution throughout the canal. The interface between fresh and
salt water has long been recognized for its affect on the precipitation or "flocculation" of
dissolved and finely divided material associated with upland runoff and discharges (19). The
role of this process is clearly evident in Military Canal with its accumulation of finely divided,
fluid sediments. Again, with the assumption that baseline conductivity may be considered
generally between 475-500 usm/cm, then Figure 4-1 reveals Military Canal, for nearly its entire
length, to be a flocculation zone conducive to the precipitation of dissolved materials and their
associated constituents.
4.2 Sediment
4.2.1 Sediment Core Characterization
Sediment core characterizations were segregated based on artificial structures along the
Canal as follows (oriented from west to east):
• Boundary Canal and Storm water Reservoir, stations SD-803 to SD-601 (Table
4.1 and Figure 4.2);
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• Upstream Reach - Military Canal from the pump station east to the 107th Ave.
bridge, stations SD-503 to SD-401 (Table 4.2 and Figure 4.3);
• Bridge and Downstream Reach - Military Canal from the 107th Ave. bridge east to
the saltwater barrier, stations SD-304 to SD-202 (Table 4.3 and Figure 4.4); and
• Tidewater Channel - Military Canal from the saltwater barrier east to the mouth of
the Canal at Biscayne Bay, stations SD-128 to SD-101 (Table 4.4 and Figure
4.5).
In general, the sediment profiles were characterized by an organic floe comprised of
decomposed plant and animal matter overlying marl and limestone (i.e., calcite). Various strata,
formed from translocation, intermixing and incorporation of organic matter from above and
weathering of limestone below, were observed between the organic and calcite horizons. In
addition, various amounts of whole shell and shell fragments were observed, especially near the
mouth of the Canal at the Bay and near the pump structure. Located within the Canal
immediately to the east of the pump structure, four stations (SD-505, SD-504, SD-502 and SD-
501) were exceptions to the above generalization. These four stations were characterized by
large cobble and boulder sized limestone covered with periphyton. Consequently, no sediment
samples were collected at these stations. Several stations exhibited a thick surface horizon of
organic flocculent which was easily suspended in the water column when disturbed during
sediment sampling by divers. This characteristic resuspension was especially obvious east of the
saltwater barrier. Several decomposing logs (possibly Australian Pine, Casuarina equisetifolia)
were observed on the Canal bottom to the west of the saltwater barrier. In addition, bank failure
and erosion was observed throughout the Canal contributing to "U-shaped" cross-sectional
geomorphology as compared to a trapezoidal shape.
Thirty-five sediment stations (i.e., every other station) were analyzed for PSD and percent
organic matter. As an aid in assessing the relative spatial distribution of sediment particle sizes
and similarity/dissimilarity of sample stations, skewness and kurtosis were plotted against
coefficient of variation of the whole sample (organic and inorganic) and inorganic fraction.
Skewness measures distortion from a symmetrical distribution with a skewness of zero being
perfectly symmetrical. For example, samples with a larger amount of relatively finer size classes
(i.e., higher percent clay PSD) are right-hand skewed (positive). In contrast, samples with a
larger amount of coarser size classes (i.e., higher percent silt and larger PSD) are left-hand
skewed (negative). With one exception (station SD-110), the PSDof the whole sample collected
from all stations exhibited left-hand skewness indicating a PSD composed of predominantly
coarser material (Figure 4.6). In contrast with the exception of stations SD-413, SD-601, SD-
604, SD-607, SD-610, SD-702, and SD-802, the PSD of the inorganic fraction was observed to
be right-hand skewed indicating a PSD composed of predominantly finer material (Figure 4.7).
The shift in PSD between the whole sample versus the inorganic fraction can be attributed to the
presence of fine and coarse particulate organic carbon in the whole sample and its absence in the
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inorganic fraction. In other word, the organic matter represented a large fraction (volumetrically)
of the whole sample.
Kurtosis measures the peakedness of a distribution where zero values represent a normal
distribution, positive values represent a sharper peak, and negative values represent a broad or
flat distribution. Consequently, a negative kurtosis represents a PSD spread over several size
classes. In general, sediment samples collected east of the saltwater barrier (series 100 stations)
exhibited a negative kurtosis indicating a wide range of PSD from clays through sands and gravel
sizes (shell fragments). In contrast, sediment samples collected west of the 107th Ave. bridge
exhibited a positive kurtosis indicating a sharper peak with a PSD relatively concentrated around
one or two particle sizes (Figures 4.8).
Percent moisture was regressed against percent organic matter and tested by ANOVA at a
significance level of a = 0.05, log transformed (Figure 4.9). A significant relationship (r2 =
0.89) was observed indicating the slurry nature of the organic floe on the surface layer of the
sediments. Even though no distinct pattern emerged, several organic matter peaks were observed
from samples collected immediately upstream and downstream of the 107th Ave. bridge (Figure
4.10).
In contrast to organic matter, the spatial distribution of particle size classes (segregated by
percent silt, sand, and clay classes) was observed to be variable throughout the study (Figure
4.11).
4.2.2 Sediment Metal/PSD/OM Relationships
Sediment metal concentrations were regressed against percent organic matter (OM) and
particle size distribution at an a = 0.05 (F-test). In addition, significance was determined at a
minimum regression coefficient (R2) of 0.20 (untransformed linear dataset). Prior to statistical
analysis, a subset was created by removing all flagged analytical results for metals. Hence,
metals not included in this analysis were antimony, cobalt, nickel, selenium, sodium, thallium,
and titanium.
A positive relationship was observed between percent organic matter and aluminum,
arsenic, cadmium, chromium, copper, manganese, total mercury, tin, and zinc (Figures 4.12 -
4.27). Chromium exhibited the highest regression relationship followed closely by zinc and
cadmium. In contrast, a negative regression relationship was observed between percent organic
matter and calcium and strontium.
Sediment metals were also regressed against sediment calcium (Figures 4.28 - 4.41). A
positive relationship was observed between strontium and sediment calcium. Negative
relationships were observed when aluminum, chromium, manganese, and zinc were regressed
against sediment calcium concentrations.
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5. Nature and Extent of Contamination
5.1 Introduction
This section presents the analytical results for the sediment and surface water
investigation conducted at the Homestead Air Force Base Boundary Canal, storm water reservoir,
and Military Canal. The findings are presented in the context of the Risk Assessment Guidance
for Superfund (RAGS), which is included as Appendix H. The RAGS EV concentrations for
both freshwater and saltwater were derived from Ambient Water Quality Criteria. The RAGS
EV concentrations for sediment were derived from statistical interpretation of effects databases
obtained from the literature as reported in publications from the State of Florida, NOAA, and a
joint publication by Long et al (22). The analytical data is presented in Appendix B. Note that
the column headings indicate the time and date of sample collection.
5.2 Military Canal Surface Water
Two surface water samples were collected from Military Canal as it was discharging to
Biscayne Bay Sample SW-500-000 was collected near the pumphouse, immediately
downgradient of the former South Allapattah bridge. Sample SW-101 was collected from the
tidewater channel, at the point where the canal discharges to Biscayne Bay.
The samples were analyzed for extractable organic compounds, pesticides/PCBs, cyanide,
metals and volatile organic compounds. Detected analytes are presented in Table 5-1, with their
respective RAGS freshwater chronic screening values. Tables 5-2 through 5-6 present all of the
available data for these samples, again with their respective RAGS freshwater chronic screening
values. Where the estimated detection limit (EDL) exceeds the RAGS effects value (EV), those
values are shown in italics.
5.2.1 Cyanide
No cyanide was detected in either sample, at a minimum quantitation limit of 2 ug/1. The
RAGS chronic screening value for cyanide is 0.2 ug/1 (Table 5-2).
5.2.2 Extractable Organic Compounds
No extractable organic compounds were detected in either sample. The estimated
detection limits of two analytes exceeded their RAGS chronic screening values. The RAGS
chronic value for hexachlorobutadiene is 0.93 ug/1. The estimated detection limit for
this analyte in both samples was 1 ug/1. The RAGS chronic screening value for
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hexachlorocyclopentadiene (HCCP) is 0.07 ug/1. The estimated detection limit for this analyte in
both samples was 1 ug/1 (Table 5-3).
5.2.3 Pesticides/PCBs
No pesticides or PCBs were detected in samples SW-500 and SW-101. Eight pesticides
had estimated detection limits above their respective RAGS chronic screening values (see Table
5-4). All seven PCBs exceeded their respective RAGS chronic screening values, as did several
pesticides (see Table 5-4).
5.2.4 Volatile Organic Compounds
No volatile organic compounds were detected in samples SW-500 and SW-101. None of
the reported minimum quantitation limits (or estimated detection limits) exceeded their
respective RAGS chronic screening values (Table 5-5).
5.2.5 Metals
Three metals were detected which have RAGS chronic screening values for freshwater.
None of the reported analytes exceeded the screening values, however. Antimony was detected
at 0.12 ug/1 in SW-500 and 0.21ug/l in SW-101. The RAGS chronic screening value for
antimony is 160 ug/1. Lead was detected at 0.1 ug/1 in SW-500, and was un-detected at 0.1 ug/1
in SW-101. The RAGS chronic screening value for lead is 0.32. Zinc was detected at 4.1 ug/1 in
SW-500, and 3.4 ug/1 in SW-101. The RAGS chronic screening value for zinc is 58.91 ug/1. In
addition, the minimum quantitation limits for two metals exceeded their respective RAGS
values. The RAGS chronic screening value for copper is 6.54 ug/1, the reported minimum
quantitation limit for copper in SW-500 is 3 ug/1, and in SW-101 is 1 ug/1. The RAGS chronic
screening value for selenium is 5.00 ug/1, the reported minimum quantitation limit for selenium
in SW-500 is 5 ug/1, and in SW-101 is 5 ug/1 (Table 5-6).
5.3 Canal/Reservoir Sediment Analytical Data
Tables 5-7 through 5-36(C) present all of the available analytical data, including
minimum quantitation limits. Figures have been prepared that graphically depict amounts and
locations of analytes (see Figures 5-1 through 5-25).
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5.3.1 Nutrients and Cyanide
The nutrients ammonia, total kjeldahl nitrogen (TKN), and total phosphorous were
analyzed in every third sample collected in support of the toxicity evaluation. Cyanide was
analyzed for in every sample. Reported values or minimum quantitation limits are listed in
Tables 5-7 through 5-11. None of these analytes are listed in the RAGS guidance. Findings for
these analytes will be discussed by reach (sampling area).
Tidewater Channel - No cyanide or nitrate-nitrite nitrogen was detected in any of the
100 series sediment samples collected from the tidewater channel. Ammonia, TKN, and total
phosphorus were detected in all samples for. which they were analyzed. Ammonia concentrations
ranged from a low of 14 mg/kg in SD-101 to 140 mg/kg in SD-122. TKN concentrations ranged
from a low of 600 mg/kg in SD-104 to 7100 mg/kg in SD-122. Total phosphorus concentrations
ranged from a low of 140A mg/kg in SD-107 and 140 mg/kg in SD-113 to 710 mg/kg in SD-119.
Analytical results are summarized in Table 5-7. It should be noted that samples SD-101
(collected at 13:35 on 11/13/97) and SD-104 (collected at 15:30 on 11/13/97) were not used in
support of the toxicity testing. Because of concerns over the use of stainless steel bowls for
mixing the samples, these samples were re-collected (SD-101 collected at 09:40 on 11/16/97 and
SD-104 collected at 10:02 on 11/16/97. The earlier samples cited here are kept in the dataset for
completeness.
Downstream Reach - No nitrate-nitrite nitrogen was detected in any of the 200 series
sediment samples collected from the downstream reach. Cyanide was detected in one sample,
SD-207 at 1 6J mg/k* Ammonia, TKN and total phosphorus were detected in all samples for
which they were analyzed. Ammonia concentrations ranged from a low of 27 mg/kg in SD-202
to 130 mg/kg in SD-205. TKN concentrations ranged from a low of 3600 mg/kg in SD-220 to
9300 mg/kg in SD-217. Total phosphorus ranged from a low of 390 mg/kg in SD-202 to 2700
mg/kg in SD-208. Analytical results are summarized m Table 5-8.
Bridge Reach - No cyanide or nitrate-nitrite nitrogen was detected in any of the 300
series sediment samples collected from the bridge reach. Ammonia, TKN and total phosphorus
were detected in both samples for which they were analj^Ammoma ^rentotions woe 91
mg/kg in SD-304 and 110 mg/kg in SD-301. TKN was 12000 mgflcg in SD-304 and SD-
301. Total phosphorus was 2300 mg/kg in SD-304 and 2400 mg/kg in SD-301. Analytical
results are summarized in Table 5-9.
Upstream Reach- No cyanide or nitrate-nitrite nitrogen was detected inlanyof the
400/500 series sediment samples collected from the upstream reach. Amnoma, TKN and total
, , j . aamnies for which they were analyzed. Ammonia concentrations
in SD-413- ™
anged from a ® ma/ks in SD-404. Total phosphorus concentrations
are summarized in Table 5-10.
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Reservoir and Boundary Canal - No cyanide or nitrate-nitrite nitrogen was detected in
any of the 600/700/800 series sediment samples collected from the reservoir and boundary canal.
Ammonia, TKN and total phosphorus were detected in all samples for which they were analyzed.
Ammonia concentrations ranged from a low of 21 mg/kg in SD601 to 160 mg/kg in SD-802.
TKN ranged from 1800 mg/kg in SD-601 to 9000 mg/kg in SD-802. Total phosphorus ranged
from 220A mg/kg in SD-601 to 780 mg/kg in SD-604. Analytical results are summarized in
Table 5-11.
5.3.2 Ex tractable Organic Compounds
All sediment samples were analyzed for base/neutral/acid (BNA) extractable organic
compounds. Reported values or minimum quantitation limits are presented in Tables 5-12(A)
through 5-16(G). The RAGS EV are also included in these tables for comparison. Where
reported concentrations exceed the RAGS EV, those values are shown in bold typeface. Where
the EDL exceeds the RAGS EV, those values are shown in italics. Findings for these analytes
will be discussed by reach (sampling area).
Tidewater Channel - Ten of the thirty-six 100 series sediment samples collected from
the tidewater channel had one or more extractable organic compounds present at concentrations
that exceeded RAGS EV concentrations (Table 5-12(A) through 5-12(L)). Fluoranthene was the
contaminant that most commonly exceeded its RAGS EV concentration, with eight samples
containing concentrations above 113 mg/kg (Figure 5-1). Three samples contained
dibenzo(a,h)anthracene at concentrations above its RAGS EV concentration of 6.22 ug/kg
(Figure 5-2). Two samples contained pyrene at concentrations above its RAGS EV
concentration of 153 ug/kg (Figure 5-3). In addition, one sample contained benzo-a-pyrene
above its RAGS EV concentration of 88.8 ug/kg (Figure 5-4). Benzo(a)anthracene exceeded its
RAGS EV concentration of 74.8 ug/kg in one sample (Figure 5-5). It must be noted that the
number of RAGS EV concentration exceedances cited above may not exactly match the figures.
This is because all available data was considered in this discussion (and summarized in the
tables), and some stations were sampled more than once. The figures depict what is considered
the most appropriate sample for each station, generally the last sample collected at the station.
Downstream Reach - All twenty-six of the 200 series sediment samples collected from
the downstream reach had one or more extractable organic compounds present at concentrations
that exceeded RAGS EV concentrations (Table 5-13(A) through Table 5-13(1)). Again,
fluoranthene was the contaminant most often exceeding its RAGS EV concentration of 113
ug/kg, with all twenty-six samples exceeding this value (Figure 5-1). Twenty of the twenty-six
samples contained concentrations of dibenzo(a,h,)anthracene exceeding its RAGS EV
concentration of 6.22 ug/kg (Figure 5-2). The following analytes were also detected at
concentrations exceeding their respective RAGS EV concentrations; benzo(a)anthracene (Figure
5-5); benzo-a-pyrene (Figure 5-4); chrysene (Figure 5-6); pyrene (Figure 5-3); anthracene
(Figure 5-7); phenanthrene (Figure 5-8); and acenaphthylene (Figure 5-9). It must be noted that
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the number of RAGS EV concentration exceedances cited above may not exactly match the
figures. This is because all available data was considered in this discussion (and summarized in
the tables), and some stations were sampled more than once. The figures depict what is
considered the most appropriate sample for each station, generally the last sample collected at the
station.
Bridge Reach - All five of the 300 series sediment samples collected from the bridge
reach had one or more extractable organic compounds present at concentrations that exceeded
RAGS EV concentrations (Table 5-14(A) and Table 5-14(B)). Six analytes exceeded their
RAGS EV concentrations in all five samples: benzo(a)anthracene (Figure 5-5); benzo-a-pyrene
(Figure 5-4); chrysene (Figure 5-6); dibenzo(a,h)anthracene (Figure 5-2); fluoranthene (Figure
5-1); and pyrene (Figure 5-3). Two analytes exceeded their RAGS EV concentrations in three of
the five samples: acenaphthylene (Figure 5-9); and phenanthrene (Figure 5-8). Anthracene
exceeded its RAGS EV concentration in one sample (see Figure 5-7). It must be noted that the
number of RAGS EV concentration exceedances cited above may not exactly match the figures.
This is because all available data was considered in this discussion (and summarized in the
tables), and some stations were sampled more than once. The figures depict what is considered
the most appropriate sample for each station, generally the last sample collected at the station.
Upstream Reach - All twenty-nine of the 400/500 series sediment samples collected
fam the upstream reach had one or more extractable or^iccom^mds preset at
concentrations that exceeded RAGS EV concentrations (Table 5.15(A) through Table 5-15(J)).
Two analytes exceeded their RAGS EV concentrates m 28 samples: dibenzo(a,h)anthracene
(Figure 5-2) and fluoranthene (Figure 5-1). Three analytes exceeded their RAGS EV
concentrations in 27 samples: benzo(a)anthracene (figure 5-5); benzo-a-pyrene (Frgure 5-4);
and pyrene (Figure 5-3). One analyte exceeded its RAGS EV concenttation in 26 samples:
chrysene (Figure 5-«). One analyte exceeded US RAGS EV^concentration in 12 samples:
acenaphthylene (Figure 5-9). One analyte exceeded its RAGS EV concentration m 9 samples:
phenanthrene (Figure 5-8). Two analytes exceeded to RAGS EV concemrationsm 6 samples:
Lenaphthene (Figure 5-10). One analyte exceeded its RAGS EV concentration in 4 samples:
fluorene (Fimre 5-11) It must be noted that the number of RAGS EV concentration
iluorene (figures li). m This is because all available data
exceedances cited above may not exacuy maim 1 &
was considered in this discussion (and summarized in .he tabtes , and some stations were
sampled more than once. The figures depict what is cons.deied the most appropriate sample for
each station, generally the last sample collected at the station.
Reservoir and Boundary Canal - All nineteen of the 600/700/800 series sediment
iveservuii « ^„,rtir/hnundarv canal had one or more extractable organic
samples collected from the RAGS Ev concentrations (Table 5-16(A)
r^T^r^ene exceeded its RAGS EV concentration 113 ug/kg in 10
through Table 5*J6(G)^ QS EV concentration of 6.22 ug/kg for dibenzo(a,h)anthracene
samples (Figure 5-1). T 5.2y Benzo(a)anthracene exceeded its RAGS EV
was exceeded in 9 sample ( g" fFicure 5-5). The RAGS EV concentration of 88.8
concentration of 74.8 ug/kg m 6 samples (figure :>
33
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ug/kg for benzo-a-pyrene was exceeded in 5 samples (Figure 5-4). Chrysene exceeded its RAGS
EV concentration of 108 ug/kg in 4 samples (Figure 5-6). The RAGS EV concentration of 86.7
ug/kg for phenanthrene was exceeded in 3 samples (Figure 5-8). It must be noted that the
number of RAGS EV concentration exceedances cited above may not exactly match the figures.
This is because all available data was considered in this discussion (and summarized in the
tables), and some stations were sampled more than once. The figures depict what is considered
the most appropriate sample for each station, generally the last sample collected at the station.
5.3.3 Organotins
All sediment samples were analyzed for mono-, di-, tri-, and tetrabutyltin. However, no
RAGS EV values for these compounds have been established and so no comparison to screening
values was made. Findings for these analytes will be discussed by reach (sampling area). The
analytical results are located with the extractable organic compounds in Tables 5-12(A) through
5-16(G).
Tidewater Channel - Mono-, tri-, and tetrabutyltin were not detected in any of the 100
series sediment samples collected from the tidewater channel. Dibutyltin was detected in four
samples (Tables 5-12(A), 5-12(F), and 5-12(J)), with concentrations ranging from 47J ug/kg
(SD-101) to 92J ug/kg (SD-123). Dibutyltin was also detected in SD-112DUP at 79J ug/kg,
which was a duplicate of SD-112.
Downstream Reach - Mono-, and tetrabutyltin were not detected in any of the 200 series
sediment samples collected from the downstream reach. Tributyltin was detected in one sample
(SD-222) at 1100 ug/kg (Table 5-131). Dibutyltin was detected in four samples (Tables 5-
13(D), 5-13(E), 5-13(H), and 5-13(1)), with concentrations ranging from 76J ug/kg (SD-211B) to
330J ug/kg (SD-222).
Bridge Reach - Mono-, and tetrabutyltin were not detected in any of the 300 series
sediment samples collected from the bridge reach. Dibutyltin was detected in two samples at
280J ug/kg (SD-302) and 540 ug/kg (SD-301), Table 5-14(A). Tributyltin was detected in all
five samples (Tables 5-14(A) and 5-14(B)). Reported concentrations of tributyltin ranged from
860 ug/kg to 1500 ug/kg.
Upstream Reach - Mono-, tri-, and tetrabutyltin were not detected in any of the 400/500
series sediment samples collected from the upstream reach. Dibutyltin was detected in four
samples (Tables 5-15(1), and 5-15(J)). Concentrations ranged from 45J ug/kg (SD-503B) to
160J ug/kg (SD-425).
Reservoir and Boundary Canal - Mono-, tri-, and tetrabutyltin were not detected in any
of the 600/700/800 series sediment samples collected from the reservoir and boundary canal.
Dibutyltin was detected in ten samples (Tables 5-16(B), 5-16(C), 5-16(D), 5-16(E), 5-16(F), 5-
34
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16(G)). Concentrations ranged from 93J ug/kg (SD-605DUP) to 290J ug/kg (SD-801 and SD-
803). Sample SD-605DUP was a duplicate of SD-605.
5.3.4 Alkyl-Substituted PAHs
All sediment samples were analyzed for alkyl substituted PAHs. However, no RAGS EV
values for these compounds have been established and so no comparison to screening values was
made with the following exception: 2-methylnaphthalene is an alkyl-substituted PAH that is a
routine analyte with a RAGS EV value. 2-methylnaphthalene is discussed in section 5.3.2.
Findings for these analytes will be discussed by reach (sampling area). The analytical results are
located with the extractable organic compounds in Tables 5-12(A) through 5-16(G).
Tidewater Channel - No alkyl substituted PAHs were detected in any of the 100 series
sediment samples collected from the tidewater channel. The analytical results are summarized in
Tables 5-12(A) through 5-12(L).
Downstream Reach - No alkyl substituted PAHs were detected in any of the 200 series
sediment samples collected from the downstream reach. The analytical results are summarized
in Tables 5-13(A) through 5-13(1).
Bridge Reach - No alkyl substituted PAHs were detected in any of the 300 series
sediment samples collected from the bridge reach. The analytical results are summarized in
Tables 5-14(A) through 5-14(B).
Upstream Reach - One sample (SD-503A) contained 12 alkyl substituted PAHs. None
of the other 400/500 series sediment samples collected torn the upstream reach contained
detectable alkyl substituted PAHs. Sample SD-503A (see Table 5-15(J ) contamed,dkyl
substituted PAHs ranging in concentration from 27JN ug/kg CI naphMenes to 7100JN ugftg
CI fluoranthenes/pyrenes. The analytical results are summanzed m Tables S-IS(A) through 5-
15(J).
R.«.rv»ip and Boundary Canal - One sample (SD-701) contained 1 alkyl substituted
PAH, CI phenanthrenes/anthracenes at 100JN ugflcg (Table None of the other
600^00/800 series sediment samples collected from the reservotr and boundary canal contained
detectable alkyl substituted PAHs. The analytical results are summarized in Tables 5-l«(A)
through 5-16(G).
5.3.5 Herbicides
„ t ,oC analyzed for the herbicides 2,4,5-T, 2,4,-D, dicamba, and
All sediment samp values for these compounds have been established
silvex (2,4,5-TP). However, no RAUb fiv vai
35
-------
and so no comparison to screening values was made. Findings for these analytes will be
discussed by reach (sampling area). The analytical results are summarized in Tables 5-17
through 5-21.
Tidewater Channel - 2,4,5-T, 2,4-D, and dicamba were not detected in any of the 100
series sediment samples collected from the tidewater channel. Silvex (2,4,5-TP), however, was
detected in 13 of the 36 samples. Concentrations of silvex (2,4,5-TP) ranged from a low of
3.7JN ug/kg in sample SD-110 to 35JN ug/kg in sample SD-103. The analytical results are
summarized in Table 5-17.
Downstream Reach - 2,4,5-T, 2,4-D, and dicamba were not detected in any of the 200
series sediment samples collected from the downstream reach. Silvex (2,4,5-TP), however, was
detected in 17 of the 26 samples. Concentrations of silvex (2,4,5-TP) ranged from a low of 15JN
ug/kg in samples SD-202 and SD-215 to 140JN ug/kg in sample SD-219. The analytical results
are summarized in Table 5-18.
Bridge Reach - 2,4,5-T, 2,4-D, and dicamba were not detected in any of the 300 series
sediment samples collected from the bridge reach. Silvex (2,4,5-TP), however, was detected in
all five samples. Concentrations of silvex (2,4,5-TP) ranged from a low of 45JN ug/kg in sample
SD-302DUP to 130JN ug/kg in sample SD-304. The analytical results are summarized in Table
5-19.
Upstream Reach - 2,4-D, and dicamba were not detected in any of the 400/500 series
sediment samples collected from the upstream reach. 2,4,5-T was detected in three of the 29
samples. Concentrations of 2,4,5-T ranged from 4.3JN ug/kg in sample SD-401 to 7.2JN ug/kg
in sample SD-417. Silvex (2,4,5-TP) was detected in five samples. Concentrations of silvex
(2,4,5-TP) ranged from a low of 5.2JN ug/kg in sample SD-420 to 61JN ug/kg in sample SD-
421. The analytical results are summarized in Table 5-20.
Reservoir and Boundary Canal - 2,4,5-T, and 2,4-D were not detected in any of the
600/700/800 series sediment samples collected from the reservoir and boundary canal. Dicamba
was detected in one sample (SD-801DUP) at 7.1JN ug/kg. SD-801DUP is a duplicate sample of
SD-801. Silvex (2,4,5-TP) was detected in 10 of the 19 samples collected in this area.
Concentrations of silvex (2,4,5-TP) ranged from a low of 4.4JN ug/kg in sample SD-603 to 17JN
ug/kg in sample SD-605DUP. SD-605DUP is a duplicate sample of SD-605. The analytical
results are summarized in Table 5-21.
5.3.6 Pesticides/PCBs
All sediment samples were analyzed for pesticides/PCBs. Reported values or minimum
quantitation limits are presented in Tables 5-22(A) through 5-26(G). The RAGS EV are also
included in these tables for comparison. Where reported concentrations exceed the RAGS EV,
36
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those values are shown in bold typeface. Where the EDL exceeds the RAGS EV, those values
are shown in italics. Findings for these analytes will be discussed by reach (sampling area).
Tidewater Channel - Nearly all (35) of the 36 100 series sediment samples collected
from the tidewater channel had one or more pesticides/PCBs present at concentrations that
exceeded RAGS EV concentrations (Table 5-22(A) through Table 5-22(E)). The RAGS EV
concentration of 2.07 ug/kg for 4,4'-DDE (P,P'-DDE) was exceeded in 35 samples (Figure 5-
12). 4,4"-DDD (P,P'-DDD exceeded its RAGS EV concentration of 1.22 ug/kg in 13 samples
(Figure 5-13). The RAGS EV concentration of 1.19 ug/kg for 4,4-DDT )P,P'-DDT) was
exceeded in 6 samples (Figure 5-14). PCB-1254 exceeded its RAGS EV concentration of 21.6
ug/kg in 22 samples (Figure 5-15).
Downstream Reach - Each of the 26 200 series sediment samples collected from the
downstream reach had one or more pesticides/PCBs present at concentrations that exceeded
RAGS EV concentrations (Table 5-23(A) through Table 5-23(D)). The RAGS EV
concentration of 2.07 ug/kg for 4,4'-DDE (P,P'-DDE) was exceeded in all 26 samples (Figure 5-
12) 4 4"-DDD (P P'-DDD exceeded its RAGS EV concentration of 1.22 ug/kg in 2 samples
(Figure 5-13) The RAGS EV concentration of 1.19 ug/kg for 4,4 -DDT )P,P -DDT) was
exceeded in 3 samples (Figure 5-14). PCB-1254 exceeded its RAGS EV concentration of 21.6
ug/kg in 25 samples (Figure 5-15).
Bridge Reach - Each of the 5 300 series sediment samples collected from the bridge
reach channel had one or more pesticides/PCBs present at concentrations that exceeded RAGS
EV concentrations (Table 5-24). The RAGS EV concentration of 2.07 ug/kg for 4,4 -DDE (P,P -
DDE) vvas Exceeded in all 5 samples (Figure5-12). 4.4VDDD(Pf-DDD exceeded its RAGS
EV concentration of 1.22 ug/kg in 1 sample (Figure 5-13) PCB-1254 exceeded its RAGS EV
concentration of 21.6 ug/kg in all 5 samples (Figure
UDStream Reach - Each of the 29 400/500 series sediment samples collected from the
upstream reach had one or more pesticides/PCBs present at concentrations that exceeded RAGS
upstream reacn nao on f 5-25(D)). The RAGS EV concentration of
2 07crzn™ » all 26 samp,es (Figure 5-12). 4.4"-DDD
(P P' BdD exceeded its RAGS EV concentration of 1.22 ug/kg i« 10 samples (Figure 5-13).
The RAGS EV concentration of 1.19 ug/kg for 4,4'-DDT (P,P'-DBT) was exceeded to 3 samples
(Figure 5-14). PCB-1254 exceeded its RAGS EV concentration of 21.6 ug/kg in 27 samples
(Figure 5-15).
Reservoir/Boundary Canal - Each of the 19 600/700/800 seriessediment samples
Keservoir/D canal had one or more pesticides/PCBs present at
collected from the rese^ir^ ^y concentrations (Table 5-26(A) through Table 5-26(C)).
concentrations that exceeded RAUb a ^ 4 4..DDE (p,P'-DDE) was exceeded in all 19
The RAGS EV c°n^tr*TDDD ^ p'.pDD exceeded its RAGS EV concentration of 1.22
samples (Figure 5-12). 4,4 -uuu \,r,r
37
-------
ug/kg in 2 samples (Figure 5-13). PCB-1254 exceeded its RAGS EV concentration of 21.6
ug/kg in 8 samples (Figure 5-15).
5.3.7 Volatile Organic Compounds
All sediment samples were analyzed for volatile organic compounds. However, no
RAGS EV values for these compounds have been established, therefore, no comparison to
screening values was made. Findings for these analytes will be discussed by reach (sampling
area). The analytical results are summarized in Tables 5-27(A) through 5-31(B). It should be
noted that the VOCs 1,4-dichlorobenzene, toluene, and trichlorofluoromethane were detected in
field blanks (section 3.3).
Tidewater Channel - Due to field quality assurance issues, only 23 of the 47 sediment
samples collected from the tidewater channel were analyzed. Further, while all of the data from
these 23 samples is shown in Table 5-27(A) through Table 5-27(E), only the samples
recollected on 11/19/97 (those samples whose identification number ends in "A", "B", "BDP",
and "R") will be discussed here as these stations were recollected and analyzed with better
quality assurance controls (13 stations). Carbon disulfide was detected in 7 of the 13 samples at
concentrations ranging from 1.2J ug/kg in SD-107R to 55J ug/kg in sample SD-120B. Toluene
was detected in two samples, SD-120A (7.7J ug/kg) and SD-120B (3.5J ug/kg). 1,3-
dichlorobenzene was also detected in these two samples, at concentrations of 3.7J ug/kg in SD-
120A and 21J ug/kg in SD-120B. 1,2,4-trichlorobenzene (4.3J ug/kg) and 1,4-dichlorobenzene
(2.6J ug/kg) were also detected in SD-120B. In addition, sample SD-125R contained 0.57J ug/kg
of p-isopropyltoluene.
Downstream Reach - Due to field quality assurance issues, only 18 of the 33 sediment
samples collected from the upstream reach were analyzed. Further, while all of the data from
these 18 samples is shown in Table 5-28(A) through Table 5-28(D), only the samples
recollected on 11/19/97 (those samples whose identification number ends in "R" and "RB") will
be discussed here as these stations were recollected and analyzed with better quality assurance
controls (8 stations). Carbon disulfide was detected in all 8 stations, at concentrations ranging
from 3.3J ug/kg in sample SD-202R to 11J ug/kg in SD-208R. 1,3-dichlorobenzene was
detected in three of these samples: 0.91 J ug/kg in SD-208R, 2.7 ug/kg in SD-211RB, and 0.66J
ug/kg in SD-220R. In addition, 1,4-dichlorobenzene was detected in SD-211RB at a
concentration 0.59J ug/kg.
Bridge Reach - Due to field quality assurance issues, only 5 of the 7 sediment samples
collected from the bridge reach were analyzed. Further, while all of the data from these 5
samples is shown in Table 5-29, only the samples recollected on 11/19/97 (those samples whose
identification number ends in "R") will be discussed here as these stations were recollected and
analyzed with better quality assurance controls (2 stations). Carbon disulfide was detected in
both samples at concentrations of 11J ug/kg in SD-301R and 7.6J ug/kg in SD-304R. No other
volatile organic compounds were detected in these 2 samples.
38
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Upstream Reach - Due to field quality assurance issues, only 24 of the 31 sediment
samples collected from the upstream reach were analyzed. The data from these 24 samples is
shown in Table 5-30(A) through Table 5-30(C). Carbon disulfide was detected in 17 of the 23
samples with concentrations ranging from 3.5J ug/kg in SD-418 to 48J ug/kg in SD-417DUP (a
duplicate sample of SD-417). P-isopropyltoluene was detected in 10 samples with
concentrations of 2.4J ug/kg in SD-420 to 130J ug/kg in SD-421. 1,4-dichlorobenzene was
detected in 3 samples at concentrations of 13J ug/kg (SD-407) to 32 ug/kg in SD-408. Toluene
was also detected in 3 samples with concentrations ranging from 0.86J ug/kg in SD-503B to 2.1 J
ug/kg in SD-409. The following analytes were also reported in these samples: menthene, 200JN
ug/kg in SD-419; limonene, 20JN ug/kg in SD-422; and pinene, 20JN ug/kg in SD-422.
Reservoir/Boundary Canal - Eighteen of the 19 samples collected in these areas were
analyzed. The remaining sample was broken in the laboratory. The analytical results for these
samples are summarized in Table 5-31(A) and 5-31(B). Of the 18 samples analyzed, 3 contained
toluene at concentrations from 0.93J (SD-601) ug/kg to 1.4J ug/kg (SD-602 and SD-604).
Trichlorofluoromethane was detected in samples SD-601 (12 ug/kg) and SD-602 (8.5J ug/kg).
1,3-dichlorobenzene was detected at 7.6J ug/kg in SD-602, and 1.1J ug/kg in SD-604. 1,4-
dichlorobenzene was detected at 1.7J ug/kg in SD-602. In addition, carbon disulfide was
reported in one sample at 4.2J ug/kg (SD-608) and chloroform was reported at 7.9J ug/kg in SD-
803.
5.3.8 Metals
All sediment samples were analyzed for metals. Reported values or minimum
quantitation limits are presented in Tables 5-32(A) through 5-36(0). The RAGS: EV are also
Win^H in these tables for comparison. Where reported concentrations exceed the RAGS EV,
those values are shown in bold typeface. Where the EDL exceeds the RAGS EV, those values
are shown in italics. Findings for these analytes will be discussed by reach (sampling area).
Tidewater Channel - Nearly all (32) of the 39 100 series sediment samples collected
from the tidewater channel had 1 or more metals; present at concen^ons exceeding their
respective RAGS EV concentrations (Table 5-32(A) through Table S-3W1). The RAGS EV
concentration of 0.676 mg/kg for cadmium was exceeded in 19 «m£es Copjsr
its RAGS EV concentration of 18.7 mg/kg in 24 samples (Figure 5-17). The RAGS
EV -inmitrati™ of 0 733 mg/kg for silver was exceeded in 32 samples (Figure 5-18). Mercury
e^Mdlriits^AGS EV concentration of 0.13 mg/kg in 24 samples figure 5-19). Zinc was
present at concentrations exceeding its RAGS EV screening value of 124 mg/kg m 3 samples
(Figure 5-20), lead also exceeded to RAGS EV concentraaon of 302 mg/kg in 3 samples
ffleure 5-21 and nickel exceeded its RAGS EV screening concentration of 15.9 mg/kg m 1
sample (Figure 5-22). It must be noted that the number of RAGS EV cot^tration exceedances
cited above may not exactly match the figures. This is because all available dam was considered
citea aoove may o , • the tables), and some stations were sampled more tiaan
in this discussion (and summarized in tne moia,),
-------
once. The figures depict what is considered the most appropriate sample for each station,
generally the last sample collected at the station.
Downstream Reach - All of the 26 200 series sediment samples collected from the
downstream reach had 4 or more metals present at concentrations that exceeded their RAGS EV
concentrations (Table 5-33(A) through Table 5-33(D)). The RAGS EV concentration of 0.676
mg/kg for cadmium was exceeded in 26 samples (Figure 5-16). Copper exceeded its RAGS EV
concentration of 18.7 mg/kg in 26 samples (Figure 5-17). The RAGS EV concentration of 0.733
mg/kg for silver was exceeded in 26 samples (Figure 5-18). Mercury also exceeded its RAGS
EV concentration of 0.13 mg/kg in 26 samples (Figure 5-19). Zinc was present at concentrations
exceeding its RAGS EV screening value of 124 mg/kg in 25 samples (Figure 5-20), lead
exceeded its RAGS EV concentration of 30.2 mg/kg in 17 samples (Figure 5-21), arsenic
exceeded its RAGS EV screening concentration of 7.24 mg/kg in 13 samples (Figure 5-23).
Antimony exceeded its RAGS EV screening concentration of 2 mg/kg in 2 samples (Figure 5-
24), and chromium exceeded its RAGS EV concentration of 52.3 mg/kg in 1 sample (Figure 5-
25). It must be noted that the number of RAGS EV concentration exceedances cited above may
not exactly match the figures. This is because all available data was considered in this discussion
(and summarized in the tables), and some stations were sampled more than once. The figures
depict what is considered the most appropriate sample for each station, generally the last sample
collected at the station.
Bridge Reach - All 5 of the 300 series sediment samples collected from the bridge reach
had 7 or more metals present at concentrations that exceeded their RAGS EV concentrations
(Table 5-34A). The RAGS EV concentration of 0.676 mg/kg for cadmium was exceeded in 5
samples (Figure 5-16). Copper exceeded its RAGS EV concentration of 18.7 mg/kg in 5
samples (Figure 5-17). The RAGS EV concentration of 0.733 mg/kg for silver was exceeded in
5 samples (Figure 5-18). Mercury also exceeded its RAGS EV concentration of 0.13 mg/kg in 5
samples (Figure 5-19). Zinc was present at concentrations exceeding its RAGS EV screening
value of 124 mg/kg in all 5 samples (Figure 5-20). Lead exceeded its RAGS EV concentration
of 30.2 mg/kg in all 5 samples also(Figure 5-21). Arsenic exceeded its RAGS EV screening
concentration of 7.24 mg/kg in all 5 samples (Figure 5-23). Antimony exceeded its RAGS EV
screening concentration of 2 mg/kg in 2 samples (Figure 5-24). It must be noted that the number
of RAGS EV concentration exceedances cited above may not exactly match the figures. This is
because all available data was considered in this discussion (and summarized in the tables), and
some stations were sampled more than once. The figures depict what is considered the most
appropriate sample for each station, generally the last sample collected at the station.
Upstream Reach - Nearly all (28) of the 29 400/500 series sediment samples collected
from the upstream reach had 4 or more metals present at concentrations that exceeded their
RAGS EV concentrations (Table 5-35 (A) through 5-35(E)). The RAGS EV concentration of
0.676 mg/kg for cadmium was exceeded in 28 samples (Figure 5-16). Copper exceeded its
RAGS EV concentration of 18.7 mg/kg in 28 samples (Figure 5-17). The RAGS EV
concentration of 0.733 mg/kg for silver was exceeded in 28 samples (Figure 5-18). Mercury
40
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also exceeded its RAGS EV concentration of 0.13 mg/kg in 28 samples (Figure 5-19). Zinc was
present at concentrations exceeding its RAGS EV screening value of 124 mg/kg in 23 samples
(Figure 5-20). Lead exceeded its RAGS EV concentration of 30.2 mg/kg in 23 samples
also(Figure 5-21). Arsenic exceeded its RAGS EV screening concentration of 7.24 mg/kg in 21
samples (Figure 5-23). Antimony exceeded its RAGS EV screening concentration of 2 mg/kg in
9 samples (Figure 5-24). It must be noted that the number of RAGS EV concentration
exceedances cited above may not exactly match the figures. This is because all available data
was considered in this discussion (and summarized in the tables), and some stations were
sampled more than once. The figures depict what is considered the most appropriate sample for
each station, generally the last sample collected at the station.
Reservoir/Boundary Canal - Fifteen of the 19 600/700/800 series sediment samples
collected from the upstream reach had 2 or more metals present at concentrations that exceeded
their RAGS EV concentrations (Table 5-36 (A) through 5-36(C)). The RAGS EV concentration
of 0.676 mg/kg for cadmium was exceeded in 11 samples (Figure 5-16). Copper exceeded its
RAGS EV concentration of 18.7 mg/kg in 12 samples (Figure 5-17). The RAGS EV
concentration of 0.733 mg/kg for silver was exceeded in 15 samples (Figure 5-18). Mercury
also exceeded its RAGS EV concentration of 0.13 mg/kg in 15 samples (Figure 5-19). Zinc was
present at concentrations exceeding its RAGS EV screening value of 124 mg/kg in 1 sample
(Figure 5-20). Arsenic exceeded its RAGS EV screening concentration of 7.24 mg/kg in 4
samples (Figure 5-23). It must be noted that the number of RAGS EV concentration
exceedances cited above may not exactly match the figures. This is because all available data
was considered in this discussion (and summarized in the tables), and some stations were
sampled more than once. The figures depict what is considered the most appropriate sample for
each station, generally the last sample collected at the station.
5.4 WWTP and Sludge/Incinerator Ash Disposal Area Sediment Data
5.4.1 Cyanide
All sediment samples were analyzed for cyanide. However, no RAGS EV values for
cyanide has been established, therefore no comparison to screening values has been made. No
cyanide was detected in these samples. The minimum quantitation limits are presented in Table
5-37.
5.4.2 Organotins
All sediment samples were analyzed for organotins. However, no RAGS EV values for
organotins has been established, as a result no comparison to screening values has been made.
41
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No organotins were detected in these samples. The minimum quantitation limits are presented in
Table 5-38.
5.4.3 Extractable Organic Compounds
All sediment samples were analyzed for extractable organic compounds and alkyl-
substituted PAHs. Reported values or minimum quantitation limits are presented in Table 5-39.
The RAGS EV are also included in these tables for comparison. Where reported concentrations
exceed the RAGS EV, those values are shown in bold typeface. Where the EDL exceeds the
RAGS EV, those values are shown in italics. Figures 5-26 to 5-36 present the extractable
organic compounds data graphically for all analytes with a RAGS EV concentration.
Of the 5 sediment samples collected from the ditches surrounding the abandoned
wastewater treatment plant, 3 had one or more extractable organic compounds present at
concentrations that exceeded RAGS EV concentrations. The RAGS EV concentration of 6.22
ug/kg for dibenzo(a,h)anthracene was exceeded in 3 samples (Figure 5-27). Benzo(a)pyrene
exceeded its RAGS EV concentration of 88.8 ug/kg in 1 sample (Figure 5-29). No alkyl-
substituted PAHs were detected in these samples.
5.4.4 Pesticides/PCBs
All sediment samples were analyzed for pesticides/PCBs. Reported values or minimum
quantitation limits are presented in Table 5-40. The RAGS EV are also included in these tables
for comparison. Where reported concentrations exceed the RAGS EV, those values are shown in
bold typeface. Where the EDL exceeds the RAGS EV, those values are shown in italics.
Figures 5-37 to 5-40 present the pesticides/PCBs data graphically for all analytes with a RAGS
EV concentration.
Nearly all (4) of the 5 sediment samples collected from the ditches surrounding the
abandoned wastewater treatment plant had one or more pesticides/PCBs present at concentrations
that exceeded RAGS EV concentrations. The RAGS EV concentration of 2.07 ug/kg for 4,4'-
DDE (P,P'-DDE) was exceeded in 4 samples. 4,4"-DDD (P,P'-DDD exceeded its RAGS EV
concentration of 1.22 ug/kg in 1 sample. PCB-1254 exceeded its RAGS EV concentration of
21.6 ug/kg in 1 sample.
5.4.5 Volatile Organic Compounds
All sediment samples were analyzed for volatile organic compounds. However, no
RAGS EV values for these compounds have been established and so no comparison to screening
values has been made. The analytical results are summarized in Table 5-41.
42
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P-isopropyltoluene was detected in 3 of the 5 samples with concentrations ranging from
7.6J ug/kg (SD-004-000) to 1000J ug/kg in SD-002-000. Three analytes were detected in 2
samples: benzene, 4.1J ug/kg in SD-002-000 and 1.5J ug/kg in SD-005-000; carbon disulfide,
15J ug/kg in SD-001-000 and 6.7J ug/kg in SD-002-000; and toluene, 6.4J ug/kg in SD-002-000
and 2.3J ug/kg in SD-005-000. The following analytes were detected only in sample SD-002-
000: acetone, 85J ug/kg; dimethyloctene, 70JN ug/kg; and menthene, 100JN ug/kg. In addition,
pinene was reported at 700JN ug/kg in SD-004-000.
5.4.6 Metals
All sediment samples were analyzed for metals. Reported values or minimum
quantitation limits are presented in Table 5-42. The RAGS EV are also included in these tables
for comparison. Where reported concentrations exceed the RAGS EV, those values are shown in
bold typeface. Where the EDL exceeds the RAGS EV, those values are shown in italics.
Figures 5-41 to 5-50 present the metals data graphically for all analytes with a RAGS EV
concentration.
All of the sediment samples collected from the ditches surrounding the former WWTP
had 2 or more metals present at concentrations that exceeded their RAGS EV concentrations.
The RAGS EV concentration of 18.7 mg/kg for copper was exceeded in all 5 samples. The
RAGS EV screening concentration of 0.13 mg/kg for mercury was exceeded in 4 samples.
Cadmium exceeded its RAGS EV concentration of 0.676 mg/kg in 3 samples. Silver also
exceeded its RAGS EV concentration of 0.733 mg/kg in 4 samples. Lead exceeded its RAGS
EV screening concentration of 30.2 mg/kg in 2 samples. Zinc exceeded its RAGS EV screening
concentration of 124 mg/kg in 2 samples. Arsenic exceeded its RAGS EV screening
concentration of 7.24 mg/kg in 1 sample.
5.4.7 Herbicides
All sediment samples were analyzed for the herbicides 2,4,5-T, 2,4-D, dicamba, and
Silvex (2 4 5-TP) However, no RAGS EV values for these compounds have been established
and so no comparison to screening values has been made. The analytical results are summarized
in Table 5-43 2 4 5-T, 2,4-D, and dicamba were not detected in any of these sediment samples.
Silvex (2,4,5-TP), however, was detected in 4 of the 5 samples. Figure 5-51 shows the locations
and relative amounts of silvex in these sediment samples
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5.5 Canal/Reservoir Sediment Toxicity
5.5.1 Whole Sediment
Hyalella azteca - Based on the statistical analyses prescribed in USEPA Method 1000.0
seven sampling stations within Military Canal were identified as toxic based on the H azteca: 10-
day sediment test (Table 5-44 and Figure 5-52). These were samples SD-214. SD-4.2. SD-425,
SD-503A, SD-604, SD-610 and SD-702. All control sediments produced 80% or greater
survival of amphipods (p< 0.05). Chemical constituents in many of these sediments exceeded
the Region 4 RAGS Effects Values (Appendix H). The relationship between chemical
constituents or concentrations and toxicity test results were not improved by norma lzing
sediments for organic content or percent clay and silt. However, in many sediment samples high
concentrations of metals. PCBs, PAHs, etc. did not result m significant (p< OXb) toxicity. Only
six chemicals were significantly (p< 0.05) correlated with H. azteca mortality: arsenic,
cadmium, cobalt, nickel, aluminum and total kjeldahl nitrogen. The Stepwise Regression
procedure identified four constituents accounting for 74% of the variance m the relationship
between toxicity and chemical concentrations in the sediment. These were nickel (37%), aldrin
(22%), cobalt (7%) and cadmium (7%).
Ceriodaphnia dubia.. - Two sediment samples, SD-304 and SD-604, were toxic to C.
dubia adults (Table 5-44 and Figure 5-52). Reproductive effects were detected m zooplankton
exposed to nine samples-SD-202, SD-304, SD-401, SD-407, SD-413 SD-503A. SD-601 SD-
604 and SD-802. The statistical procedures described above provided tew insights into what
sediment constituents might be related to or the cause of toxicity in C. dubia. There weie no
correlations between toxicity or reproduction and chemical concentrations in the sediments of
Military Canal. Silvex concentrations accounted for 22% of the variance in a regression between
chemicals and zooplankton survival. It was the only parameter to be identified as significant.
Arsenic was found to be responsible for 10% of the variance in the legression of reproduction on
sediment chemical concentrations, but the model was not significant at the p<0.05 level.
5.5.2 Pore Water
Porewater samples were found to be non-toxic to H. azteca after 96 h exposures (Table
5-44 and Figure 5-52). The eighty percent or greater survival rate of the amphipods appears to
be consistent with the relatively low concentrations of sulfides, ammonia and other potentially
toxic chemicals (Tables 5-45 through 5-49) present in the pore water. Virtually no pesticides,
PAHs or other organic compounds were detected in pore water. There are currently no federal
standards or known state standards regulating the quality of porewater.
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6. Summary and Conclusions
6.1 NOAA Investigation (Biscayne Bay)
In the approved study plan for this evaluation of Military Canal sediments, it was stated
that for the determination of toxicity in the tidewater channel and impacts upon Biscayne Bay,
data from the NOAA investigation would be used. Since then, NOAA has issued a technical
memorandum (final draft) detailing the results of that investigation (Appendix E).
Samples from the three stations located in the tidewater channel of Military Canal
exhibited some degree of toxicity, and zinc, lead, total PAHs, and total PCBs were reported for
all three samples. The technical memorandum does not report any finding that Military Canal is
currently having a detrimental impact upon the sediment or surface water quality of the Biscayne
National Park. However, it does note the following: "Chemical analyses indicated the presence
of complex mixtures of chemical substances in the most toxic samples. Overall, contamination
was highest by a considerable amount in the lower Miami River, intermediate in Military Canal
and several other tributaries and canals, and lowest in the open basin south of the Rickenbacker
Causeway".
6.2 Data Limitations
While this dataset can identify some source areas for contaminants, all of the potential
sources cannot be identified, nor can the contaminants be apportioned. For example, silvex can
be shown to be currently discharging from the ditches surrounding the former WWTP and the
sludge/incinerator ash disposal area. While no records exist, it is unlikely to have been applied
since the unit was abandoned in 1982. In contrast, file material shows that the SFWMD applied
silvex to Military Canal in 1974. In either case, silvex was discontinued in 1984. Further, this
dataset cannot apportion the contaminants, i.e. state conclusively that a documented source is
solely responsible for a given contaminant, or some specified percent of a given contaminant
This investigation was conducted to provide a unified and complete dataset on the
contaminants present in the sediments in Military Canal, and, to the extent possible, identify
sources of these contaminants. To keep the focus of the investigation upon Military Canal, no
additional samples were collected from adjacent or similar canals,. In addition, this report
presents the analytical results of the sampling effort, with data interpretation. No risk assessment
(human health or ecological) has been performed by USEPA. In addition, USEPA has performed
no quantitative or qualitative sediment contaminant transport modeling or sampling (i.e, no
bedload samplers were utilized to determine contaminant transport to Biscayne National Park).
It must be noted that while it can be fairly stated that the sediment investigation was
exhaustive, the two water samples were collected for a different purpose. Specifically, these two
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samples were collected to determine if the surface water discharging to the Biscayne National
Park under nominal conditions posed an imminent threat to the Park. These two samples were
collected for this screening purpose only, and in no way are intended to present a complete
picture of the hydrology of Military Canal, or even a comprehensive evaluation of an imminent
threat.
6.3 Summary
6.3.1 Sediment Transport
Even though a complete carbon budget was not conducted on Military Canal, a
conceptual organic carbon model is critical in the identification of contaminant transport
mechanisms. The water column of Military Canal was considered the carbon compartment for
this exercise. Consequently, carbon produced from within Military Canal is considered
autochthonous and sources introduced to Military Canal from outside of the compartment are
allochthonous. Probable sources of carbon import into Military Canal were 1) atmospheric (CO,
in photosynthesis), 2) Biscayne Bay during flood tides (particulate and dissolved organic carbon,
POC and DOC, respectively), 3) leachate of predominantly DOC from subsurface interflow from
the adjacent landscapes, and 4) the storm water reservoir in the form of POC and DOC. In
addition, moderate to large amounts of organic carbon produced in place from primary
production of algae, periphyton, and phytoplankton was obvious, especially west of the saltwater
barrier. Carbon can be exported from Military Canal by 1) vertical translocation and
incorporation into the subhorizon(s) of the sediments, 2) release to the atmosphere during
primary and secondary respiration, and 3) ebb tides and storm water releases to Biscayne Bay.
Given this, carbon export to Biscayne Bay (Biscayne National Park) would likely be accentuated
when the hydraulic head differential between the storm water reservoir and the BNP is greatest
(i.e., during storm water releases, opening of the saltwater barrier, and maximum velocity ebb
cycles coincide). The predominant source of carbon to Military Canal, aside from the in-place
primary production, is likely from the storm water reservoir which was characterized by dense
submersed aquatic vegetation (e.g., Hydrilla and filamentous algae) and surrounded by robust
macrophytic growth. However, an accumulation of organic carbon in the form of organic
flocculation was not observed on the surface horizon of the sediment of the storm water reservoir
as compared to Military Canal (i.e., USEPA divers observed areas of exposed marl with no
organic floe especially in the vicinity of the pump intakes). Consequently, it is assumed that large
quantities of organic carbon were being released to Military Canal. In contrast to the storm water
reservoir, the sediment surface of Military Canal west of the saltwater barrier exhibited
filamentous algae growth overlaying a thick surface layer of organic matter. Also, Military Canal
east of the storm water reservoir was characterized with a thick surface layer of organic matter.
In addition, coarse woody debris from cut trees (possibly following Hurricane Andrew inl992)
were present in Military Canal between the pump structure and the saltwater barrier.
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With few exceptions, a natural accumulation of organic matter in the form of a floe was
observed on the sediment surface horizon throughout Military Canal. This organic floe exhibited
various degrees of ease of resuspension depending upon the presence or absence of periphyton
and filamentous algae growth which coated the sediment surface, especially west of the saltwater
barrier. Once disturbed, the organic floe remained suspended during sediment sampling, and in
some cases, a plume was observed for several minutes following resuspension. It is assumed that
the floe can easily be mobilized and transported during storm flow and pump activation.
Naturally produced organic compounds exhibit a pH-variable charge on predominantly
carbonylic and phenolic functional radicals. In general, under acidic conditions organic
compounds have a net negative charge, consequently, a high affinity for cations such as heavy
metals. As evidenced by the positive relationship observed between organic matter and nine
metals, naturally produced organic matter coupled with storm flow, activation of pumps, opening
of the saltwater barrier, and tidal influences provides a mechanism for heavy metals and possibly
synthetic organics to be transported in the water column from the storm water reservoir to
Military Canal, and thus to the Biscayne National Park. In contrast, strontium may be
transported by substitution with natural calcium compounds such as shell and dissolved calcite.
6.3.2 Toxicity
Sediment toxicity is the result of its physical and chemical properties. Properties such as
particle size and organic content tend to affect the partitioning of contaminants onto sediments
and out of the water column. Indeed, this is the major reason that the study focused on sediment
depth, physical characteristics and chemical constituents, and it is the reason that toxicity tests
were conducted with sediments or their extracted porewaters. As in this study, toxicity is not
always explainable based on observed characteristics or the presence of a particular contaminant.
The fact that 14 of 25 (56%) sediments collected from the Military Canal were toxic [18 of 75
individual tests (24%) identified toxicity to one of the test species, 7 of 25 (28%) were toxic to H.
azteca, 2 of 25 (8%) were toxic to C. dubia adults and 9 of 25 (36%) sediments had reproductive
effects in C. dubia] indicates that a substantial number of Military Canal sediments are toxic.
Toxic sediments were identified in every reach of Military Canal, but were more common with
increasing proximity to the Base.
Cadmium and arsenic concentrations exceeded USEPA Region 4 RAGS values
throughout Military Canal. Arsenic was correlated with both survival of Hyaiella azteca in 10-
day sediment tests, and reproductive success of Ceriodaphnia dubia in 7-day survival and
reproduction tests. Cadmium was a significant predictor of toxicity to H. azteca based on
regression analysis. While there is not a RAGS value for silvex, it accounted for nearly 25%-of
the variability in the survival of C. dubia adults and was elevated in many sediment samples
collected in Military Canal. Other constituents such as aldrin, nickel, cobalt, aluminum and total
kjeldahl nitrogen which lack RAGS values, were also found to be significantly correlated with
toxicity in H. azteca. In short, there is a demonstrable relationship between chemical
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constituents and toxicity in sediments collected from each reach of the canal upstream of the salt
barrier. Many of these chemicals have been connected to activities performed on Base, as
discussed below.
While correlation between chemical constituents and toxicity do not prove causation, the
fact that many of these chemicals were present at concentrations exceeding sediment quality
guidelines suggests that these constituents are likely sources of the toxicity.
In summary, no samples collected in the Tidal Reach were tested for toxicity due to the
high salinity of sediments and porewaters. However, two samples collected in the Downstream
Reach were toxic, one sample (two tests) were toxic in the Bridge Reach, six samples (seven
tests) in the Upstream Reach were toxic and five samples (seven tests) in the Reservoir Reach
were toxic.
6.3.3 Sediment Contaminant Distribution
Contaminant concentrations and locations are summarized below. All detected
contaminants are listed in the summary tables and in Section 5. The contaminants summarized
here are those for which the respective RAGS EV value was repeatedly exceeded, or are
otherwise noteworthy. Please note that detected contaminants not listed here are not being
categorized as environmentally insignificant.
A total of 96 sediment sampling stations were established in the storm water conveyance
system of HAFB. This includes 80 stations on Military Canal, 10 stations in the storm water
reservoir, and 6 stations in the Boundary Canals, 118 total samples. An additional 5 sediment
sampling stations were established in the ditch encircling the former WWTP. Duplicate samples
are included in the above totals.
Extractable Organic Compounds
The following extractable organic compounds have such similar distributions that a
separate discussion of each analyte is not warranted: fluoranthene, dibenzo(a,h)anthracene,
pyrene, benzo-a-pyrene, benzo(a)anthracene, chrysene, anthracene, and phenanthrene. Moving
from east to west (see Figures 5-1 through 5-8), it can be seen that concentrations of these
contaminants at station SD-101 are relatively low (often below detection limits) up to the
saltwater control barrier. From the saltwater control banier westward, there is a gradual increase
in concentrations to station SD-419, located approximately 2/3 of the distance from the bridge to
the pumphouse. The highest concentrations are found either in the receiving area, or
immediately downgradient. Much lower concentrations of these contaminants are again found
upgradient of the pumphouse, in the storm water reservoir and the Boundary Canals. The
relative concentrations of these analytes in the sediments of the ditch surrounding the WWTP can
be seen in Figures 5-26 through 5-33.
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Three other extractable organic compounds have distributions similar to those discussed
above, but with a slight difference. Acenaphthylene, acenaphthene, and fluorene have similar
distributions from the mouth of Military Canal to the pumphouse (acenaphthene has a spike just
west of the bridge), but were not found in samples taken from the storm water reservoir, the
Boundary Canals, or the ditch surrounding the WWTP (see Figures 5-9 through 5-11 and 5-34
through 5-37).
Herbicides
Silvex (2,4,5-TP) was detected in every reach of the storm water conveyance system and
in the sediments of the ditch surrounding the former WWTP. As no RAGS EV concentration has
been established for this compound, there is no corresponding figure to show the concentration of
silvex relative to its RAGS EV concentration. While silvex was the most widely reported
herbicide, others were also detected in some samples: 2,4,5-T and dicamba. Silvex was detected
in 50 of the 118 samples collected - 35 of the samples it was detected in were located from the
bridge eastward, away from the HAFB. Of the remaining 15 samples where silvex was detected,
10 were in the storm water reservoir/Boundary Canal area, above the pumphouse. Detections of
the other herbicides were much less frequent: 2,4,5-T was detected in 3 samples, in the upstream
reach of Military Canal; dicamba was detected in one sample only in the storm water
reservoir/Boundary Canal area. 2,4,5-T and dicamba were not detected in the samples collected
from the ditch surrounding the former WWTP, however silvex was detected in 4 of these 5
samples.
Organotins
As with the herbicides discussed above, the organotins have no established RAGS EV
concentration, and again there is no corresponding figure to show the concentration of the
organotins relative to their RAGS EV concentrations. Only two organotins were detected:
dibutyltin and tributyltin. Dibutyltin was detected in 24 of 118 samples, with detections in every
reach of the system. The highest reported concentrations were in the area of the bridge, but the
greatest number of detections is in the storm water reservoir/Boundary Canal area. Tributyltin
was detected in 6 samples: the 5 samples collected in the bridge reach, and one sample
downgradient of this area. No organotins were detected in the ditch surrounding the former
WWTP.
Pesticides/PCBs
Only four of these analytes were consistently found: 4,4-DDD, 4,4'-DDE, 4,4'-DDT,
PCB-1254, and chlordene.
4,4'-DDD (see Figures 5-13 and 5-38) was detected above its RAGS EV concentration of
1.22 ug/kg in 28 of 118 samples. 4,4'-DDE was detected above its RAGS EV concentration in
every reach of the storm water system that was examined, and the ditch surrounding the former
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WWTP. Most detections (and the highest concentrations) are in the western end of the upstream
reach of Military Canal, with some higher concentrations in the tidewater channel and around the
bridge. It was also detected above its RAGS EV concentration in 2 of the 5 samples collected
from the ditch surrounding the former WWTP.
4,4'-DDT was detected above its RAGS EV concentration of 1.19 ug/kg in 12 of 118
samples (see Figure 5-14). The highest concentration was from a sample collected at the
western end of the upstream reach, all other detections were much lower. 4,4-DDT was not
detected in any of the samples collected from the ditch surrounding the former WWTP (see
Figure 5-39).
4,4'-DDE was very widespread. It was detected above its RAGS EV concentration of
2.07 ug/kg in 111 of 118 samples collected from the storm water conveyance system, with the
highest concentrations located around the western third of the upstream reach (see Figure 5-12).
4,4'-DDE was also detected above its RAGS EV concentration in all 5 samples collected from
the ditch surrounding the former WWTP (see Figure 5-37).
PCB-1254 was also very widespread. It was detected above its RAGS EV concentration
of 21.6 ug/kg in 87 of 118 samples collected from the storm water conveyance system, with the
highest concentrations at three stations located in the upstream reach, another station located in
the downstream reach and two stations located in the bridge reach. PCB-1254 also exceeded its
RAGS EV concentration in one station at the former WWTP.
Chlordene was detected was detected in every reach of the storm water conveyance
system and in the sediments of the ditch surrounding the former WWTP. As no RAGS EV
concentration has been established, there is no corresponding figure to show the concentration of
silvex relative to its RAGS EV concentration. Chlordene was detected in 113 of 118 samples
collected from the storm water conveyance system, and 4 of the five samples collected from the
ditches surrounding the former WWTP.
Metals
Cadmium - Cadmium exceeded its RAGS EV concentration of 0.676 mg/kg in 88 of the
samples collected from the HAFB storm water conveyance system (see Figure 5-16). The
highest concentrations were located near the SW 107th Ave. bridge. Relatively high
concentrations of cadmium were also found in some of the samples collected east of the bridge.
Cadmium also exceeded its RAGS EV concentration in three of the five sediment samples
collected from the former WWTP, see Figure 5-41.
Copper - Copper exceeded its RAGS EV concentration of 18.7 mg/kg in 89 of the
samples collected from the HAFB storm water conveyance system (see Figure 5-17). The
highest concentrations were located west of the SW 107th Ave. bridge, nearer the Base.
Relatively high concentrations of copper were also found in several of the samples collected east
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of the bridge, and at the bridge itself. Copper also exceeded its RAGS EV concentration in all
five sediment samples collected from the former WWTP, see Figure 5-42.
Silver - Silver exceeded its RAGS EV concentration of 0.733 mg/kg in 106 of the
samples collected from the HAFB storm water conveyance system (see Figure 5-18). The
highest concentration was located immediately west of the SW 107th Ave. bridge. Similarly high
concentrations were detected at the bridge. Silver also exceeded its RAGS EV concentration in
four of the five sediment samples collected from the former WWTP, see Figure 5-43.
Total Mercury - Total Mercury exceeded its RAGS EV concentration of 0.13 mg/kg in 96
of the samples collected from the HAFB storm water conveyance system (see Figure 5-19). The
highest concentration was located approximately midway between the SW 107th Ave. bridge and
the saltwater control barrier. Relatively high concentrations were also detected at the bridge and
midway between the bridge and the pumphouse. Total mercury also exceeded its RAGS EV
concentration in four of the five sediment samples collected from the former WWTP, see Figure
5-44.
Zinc - Zinc exceeded its RAGS EV concentration of 124 mg/kg in 57 of the samples
collected from the HAFB storm water conveyance system (see Figure 5-20). The highest
concentration was located approximately midway between the SW 107th Ave. bridge and the
pumphouse. Relatively high concentrations were also detected at the bridge and approximately
midway between the bridge and the saltwater control barrier. Zinc also exceeded its RAGS EV
concentration in two of the five sediment samples collected from the former WWTP, see Figure
5-45.
Lead - Lead exceeded its RAGS EV concentration of 30.2 mg/kg in 48 of the samples
collected from the HAFB storm water conveyance system (see Figure 5-21). The highest
concentration was located in the tidewater channel, near the shoreline. Relatively high
concentrations were also detected immediately downgradient of the bridge, at the bridge itself,
and in several samples collected west of the bridge. Lead also exceeded its RAGS EV
concentration in two of the five sediment samples collected from the former WWTP, see Figure
5-46.
Arsenic - Arsenic exceeded its RAGS EV concentration of 7.24 mg/kg in 43 of the
samples collected from the HAFB storm water conveyance system (see Figure 5-23). The
highest concentration was located immediately downgradient of the bridge. Relatively high
concentrations were also detected at the bridge, at the bridge itself, and in several samples
collected west of the bridge. Arsenic also exceeded its RAGS EV concentration in one of the
five sediment samples collected from the former WWTP, see Figure 5-48.
To summarize metals contamination by reach: 32 of the 39 samples collected in the
tidewater channel (100 series) had one or more metal exceeding their RAGS EV concentration.
All 26 of the samples collected in the downstream reach (200 series) had 4 (or more) metals
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exceed their RAGS EV concentrations. All 5 of the samples collected in the bridge reach (300
series) had 7 (or more) metals exceed their RAGS EV concentration. Of the 29 samples
collected in the upstream reach, 28 had 4 (or more) metals exceed their RAGS EV concentration.
In the reservoir/Boundary Canal reach, 15 of the 19 samples had 2 (or more) metals exceed their
RAGS EV concentration. Therefore, while sediment samples collected from the bridge reach did
not necessarily have the highest concentration of a given metal, this reach could be fairly stated
to have the greatest amount of metals contamination.
6.3.4 Contaminant Sources
This investigation and previous ones have documented the presence of various
contaminants and toxicity within the sediments of the canal. Prior to this investigation, however,
sufficient information to fully document contaminant sources was not available.
A letter to USEPA dated October 23,1975 (20), from Captain Blonshine, the Base
Environmental Coordinator, lists the following activities as discharges to the sanitary sewage
treatment plant:
• Potable and Industrial Water Treatment Facilities
• Cooling Systems, except for buildings 360 and 585.
• Boilers
• Vehicle and Equipment Cleaning Facilities
• Painting and Corrosion Control Facilities
• Petroleum Storage and Handling Areas - the letter notes that some of this material
is disposed of by contracting agencies.
• Vehicle and Equipment Maintenance Facilities, except for building 793.
• Battery Rework Facilities
• Photographic Laboratories
Prior to this, these facilities discharged to the various tributary canals or "blind drains".
With the exception of herbicides and pesticides, the contaminants found in Military Canal
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sediment samples and the surface soil and sediment samples collected at the former WWTP are
typically discharged by these types of facilities.
Contaminated Soil Sites
Ultimately, all surface water drainage at the former Homestead Air Force Base discharges
through Military Canal. Therefore all surface water runoff from contaminated soil sites at HAFB
also discharges to Military Canal. Although this investigation did not attempt to link these sites
directly to contamination in Military Canal (with the exception of the former WWTP and
incinerator ash pile, see below), it is reasonable to assume that any or all of these sites of
documented contaminant releases to soil may have contributed to the contaminant load in
Military Canal sediments. This contribution may have been historical, specifically, many of
these sites have now been excavated, paved over, or have buildings on them. Figure 6-1 (taken
from the Report On Environmental Investigation History Of Homestead Air Force Base And
Present Environmental Conditions, USEPA, 1999) shows the locations of all identified
contaminated soil sites and their primary contaminants. Arsenic, lead, nickel, chromium, VOC's
(chlorinated and aromatic), PAH's, PCB, xylene, pesticides, and "metals" are listed.
Wastewater Treatment Plant and Sludge/Incinerator Ash Disposal Area
In August 1990, the USEPA placed HARS (while it was still known as Homestead Air
Force Base) on the National Priority List (NPL). Numerous Superfund investigations have been
conducted by the Air Force to fulfill the statutory requirements of CERCLA. Three previous Air
Force investigations and a previous USEPA investigation had failed to find a clear linkage
between the CERCLA sites being investigated at the former Air Base and contaminants/toxicity
within the sediments of Military Canal.
Comparison of the Air Force data from surface soil samples and SESD sediment samples
collected from the former WWTP and the sludge/incinerator ash disposal area to sediment
samples collected from the reservoir and Military Canal show a clear linkage of this CERCLA
site to Military Canal. Table 6-1 summarizes the contaminants found in these areas and clearly
shows their similarities. For the purposes of establishing a CERCLA release, the detection of
these contaminants in the surface soils and ditches of the former WWTP and the
sludge/incinerator ash disposal area, the documentation of a viable surface water pathway (the
still functional culvert connecting this site to the reservoir), the Air Force correspondence listing
the various industrial activities discharging to the WWTP, and the detection of these same
contaminants in the reservoir and Military Canal clearly establishes the former WWTP and the
sludge/incinerator ash disposal area as a source for these contaminants to the reservoir and
Military Canal.
In addition, this data establishes the former WWTP itself as a source of these
contaminants to Military Canal. Their presence in the various units investigated by the Air Force
(particularly the sludge drying beds) demonstrates that these contaminants were present and
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released during the operation of the former WWTP. A more detailed discussion of these findings
can be found in the memorandum included as Appendix G.
Washrack Oil-Water Separator
This unit is discussed here because it is the only HAFB unit discharging to Military Canal
(via the Boundary Canals) for which USEPA can find effluent data. All other records pertaining
to effluent discharges have either apparently been destroyed by the various Agencies, or were lost
during Hurricane Andrew.
A predecessor organization of SESD (the Southeast Water Laboratory) ^ducted an
investigation of the oil-water separator that serviced the fighter jet washrack in 1971 (2). At that
time, there were six operational washracks for vehicles and aircraft at the Base. The receiving
water is described as "tributary canals to Military Canal . The waste was c aractenze as
"solvents, detergents, oil, and grease". One effluent grab sample was co ecte. s ou e
noted, however, that by December 1975 all of the washracks on the Base had been connected to
the sanitary sewer (21).
The following contaminants were detected in the effluent sample: total phosphoras, 6.50
mg/1 (0.48 lbs/day); oil & grease, 20.2 mg/1 (1.49 lbs/day); phenols, 890 mg/1 (0.066 lbs/day),
copper, 0.03 mg/1 (0.002 lbs/day); zinc, 0.26 mg/1 (0.019 lbs/day); chromium, 1.42 mg/1 (0.105
lbs/day); lead, 0.41 mg/1 (0.030 lbs/day); cadmium, 0.05 mg/1 (0.004 lbs/day). Five other similar
(but smaller) washracks were not sampled. The Air Base was subsequent y issue a oi ice o
Violation (NOV) by Dade County Pollution Control (DCPC, predecessor agency to DERM) (2).
With the exception of phenols, all of these contaminants were found in sediment samples
collected from the Boundary Canal, storm water reservoir, the drainage ditches at the former
WWTP, and Military Canal itself.
Canal Maintenance Practices
The canals are artificial constructs that were originally intended to lower the groundwater
table in Dade County, and now also serve as flood water control mechanisms. As such, aquatic
vegetative growth must be controlled to permit the unrestricted flow of water. This has been
accomplished with the use of aquatic and ditchbank herbicides. Typically the aquatic herbicides
are mixed with inverted (emulsified^ oil and another agent (historically diesel fuel was often
used). The mixture forms a dense paste resembling mayonnaise which then sinks to the bottom
of the water column. This potential source of contaminants/toxicity has not been examined in
previous investigations.
The sediment samples were analyzed for some of the herbicides used by the SFWMD,
many of which are toxic to non-target organisms at low concentrations. Table 6-2 lists some of
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the chemicals used during canal maintenance, and their amounts. The period of record is 1973 to
1996 (5).
Silvex is the only herbicide specifically identified by the SFWMD as having been used in
Military Canal that was detected during this investigation. Diesel and "inverted oil" were also
used, and may perhaps be present in sediment samples collected during this investigation as
petroleum product. However, these analytes (silvex and petroleum product) were also present in
the Boundary Canal, reservoir, and the ditches surrounding the former WWTP and
sludge/incinerator ash disposal area, locations upgradient of Military Canal itself (i.e., these areas
were not treated by the SFWMD). In summary, while the SFWMD canal maintenance practices
were a source for the silvex (and possibly petroleum product), they cannot be considered the sole
source for either.
Illegal Disposal
Prior to the investigation, there was considerable speculation about the types, amounts,
and significance of illegal disposal of materials into Military Canal. The very nature of this
activity makes it impossible to quantify, but examination of contaminant trends does reveal some
patterns.
The 107th Ave. bridge was investigated as a potential "hot spot" for contamination due to
illegal dumping. Examination of the data indicates that several analytes (mostly metals) in fact
do have their highest concentrations at or near this structure. However, with the exception of the
organotins, all of these contaminants can also be linked to the former Air Base via the source
area of the former WWTP and sludge/incinerator ash disposal area, the fighter washrack oil-
water separator, or both.
An unexpected finding of this investigation was the "hot spot" of extractable organic
compounds immediately below the pump house on the reservoir. While many of these
compounds can be linked to the former WWTP and sludge/incinerator ash disposal area, their
peak concentrations (by an order of magnitude difference, or more) coincides with a pile of
asphalt shingles illegally disposed in Military Canal, which must also be considered an additional
source for these analytes. In addition, the following analytes were detected only in the immediate
area of the shingles (or downgradient) but not in the ditches surrounding the former WWTP and
sludge/incinerator ash disposal area, the reservoir, or the Boundary Canal: acenaphthylene,
acenaphthene, and fluorene. This is a strong indication that these shingles are the source of these
particular contaminants to Military Canal sediments.
6.4 Conclusions
The data discussed in this report clearly documents the following contaminant release
mechanisms to Military Canal from the former Homestead Air Force Base:
55
-------
The oil-water separators on the fighter washrack.
• The former WWTP.
The ditches surrounding the former WWTP and sludge/incinerator ash disposal
area.
Sources of contaminants to these areas are documented in:
The October, 1975 USAF letter to USEPA outlining various industrial discharges
to the WWTP (20).
USEPA's Dade County Industrial Waste Survey (1971) documenting the presence
of several heavy metals in the effluent discharging to Military Canal via tributaries
to Boundary Canal (2).
The December, 1975 USAF letter to USEPA stating that the washracks were now
discharging to the WWTP (21).
The Air Force Draft OU-11 RI/BRA which documents the presence of
contaminants typical of the types of facilities found in the USAF correspondence
from 1975 (1).
The SESD investigation of the ditches surrounding the former WWTP and
sludge/incinerator ash disposal area, confirming the presence of these
contaminants in this pathway to Military Canal.
• The SESD Military Canal Special Study, which thoroughly documents the
presence of these contaminants in the sediments of Boundary Canal, the storm
water reservoir, and Military Canal.
Many sediment samples had one or more contaminants present at levels above those cited
in the Risk Assessment Guidance for Superfund (RAGS), or were otherwise significant. In
particular, silver, mercury, lead, cadmium, copper, zinc, total mercury, arsenic, silvex, DDE,
chlordene, several PAHs, and PCB-1254, were present in most samples, often at concentrations
above their respective RAGS EV value (if any). Likewise, many samples exhibited some degree
of toxicity.
Taken as a whole, the analytical and toxicological results of the current investigation are
not remarkably different from earlier investigations performed at Military Canal by SESD,
DERM, and NOAA, The current investigation does, however, provide a much clearer picture of
the quality of Military Canal sediments through much more intensive sampling, and closely links
past HAFB activities to detected contaminants.
56
-------
In conclusion, the documents and investigations cited above clearly show the former
Homestead Air Force Base to be a source for many of the contaminants discussed in this report to
the sediments of Military Canal.
57
-------
7. References
1. Draft Final Remedial Investigation/Baseline Risk Assessment Report: OU-11,
Sewage Treatment Plant/Sludge Incinerator Ash Disposal Area and Outfall Canal,
Homestead Air Force Base. Air Force Center For Environmental Excellence.
September, 1998.
2. Industrial Waste Survey, Dade County, Florida. USEPA. September, 1971.
3. Operable Unit No. 9, Boundary Canal Record of Decision, Homestead Air Force
Base. USAF. June, 1997.
4. Corcoran, et. al. Biscayne Bay Hydrocarbon Study, Final Report. University of
Miami, Rosenstiel School of Marine and Atmospheric Sciences. December,
1983.
5. Agency file material, South Florida Water Management District.
6. DERM Memorandum (untitled). From Rick Alleman of DERM to Mat Christ
USAF. December 12, 1990.
7. Military Canal Investigation, Final Report. USEPA Region 4/SESD. Project No.
95-0279. December, 1995.
8. Sediment Chemistry and Toxicity Study, unpublished study data. DERM. 1995.
9. Draft Final Boundary Canal Remedial Investigation Report. USAF. 1996.
10. Surface Water Improvement and Management (SWIM) Plan for Biscayne Bay.
SFWMD. November, 1995.
11. Final Workplan for Military Canal Special Study, Homestead AFB, Florida.
USEPA Region 4/SESD. November, 1997.
12. Environmental Investigations Branch Standard Operating Procedures and Quality
Assurance Manual. USEPA Region 4/SESD/EIB. May, 1995.
13. Sampling and Analytical Methods of the National Status and Trends Program,
Volume IV. 121, NO A A Technical Memorandum NOS ORCA 71).
14. Environmental Toxicity and Chemistry, 15:1996. As modified by the Skidaway
Institute of Oceanography and USEPA Region 4 SESD ASB.
58
-------
15. Short-Term Methods for Evaluating the Chronic toxicity of Effluent Receiving
Waters to Freshwater Organisms. EPA/600/4-91/002. July 1994.
16. SAS Manual. 1995.
17. ASTM Method E1383. ASTM Annual Book of Standards. 1993.
18. Analytical Support Branch Laboratory Operations and Quality Control Manual.
December 1997.
19. Snedaker, S. et. al. A Review of the Role of Freshwater in Estuarine Ecosystems.
University of Miami, Rosenstiel School of Marine and Atmospheric Sciences,
May 1977.
20. Correspondence from Captain Blonshine, Homestead Base Environmental
Coordinator, to USEPA. October, 1975.
21. Correspondence from Captain Blonshine, Homestead Base Environmental
Coordinator, to USEPA. December, 1975.
22. Long, E.R. MacDonald, S.L. and F.D. Calder. Incidence of adverse biological
effects within ranges of chemical concentration in marine and estuarine sediments.
Environ. Management 19:81-97. 1995.
-------
Appendix A
Figures
-------
Figure 1-1
Homestead Air Force Base Location
Military Canal Special Study
November, 1997
Homestead
Air Force Base
-------
-------
Figure 1-3 j
Biscayne Bay Hydrocarbon Study -1983 -f"
Military Canal Special Study
November, 1997
Stormwater
Reservoir.
Boundary
239 238
I ! Hoodoate""'
ROAD ON LEVFF
Tidewater Channel
Upstream Reach
Receiving
Area
Bridge
Reach
Downstream Reach
Biscayne
National
Park
Former.
WWTP
highway
1 Miles
¦
# Sediment Sampling Station
-------
Stormwater
Reservoir*
Boundary
Canal _
l.Vi.V/1 .•
)AD ON LfVfF
Tidewater Channel
_~b A'
Downstream Reach
Bridge
Reach
Biscayne
National
Park
Former,
WWTP
Upstream Reach
Receiving
Area
HIGHWAY
Figure 1 -4
Military Canal Environmental Investigation
Military Canal Special Study
November, 1997
0 1 Miles
d
Sediment Sampling Station
-------
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Miami-Dade DERM Tributary Sediment m
Toxicity Study '95/*96
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Figure 1-5
Miami-Dade Tributary Sediment
Toxicity Study - 1995
Military Canal Special Study
November, 1997
KX101
ft
1 _J
U1B9301
Sample Locations
0
N
6 Miles
-------
Figure 1-6
Boundary Canal Remedial Investigation
Military Canal Special Study
November, 1997
Stormwater
Reservoir.
/ Boundary
Canal Z
SD-0003
SD-0001
U-
MiUlXiiY
ROAD ON LBVPF
Tidewater Channel
« J «-
a - . -
jew
\ntis Upstream Reach
Receiving
Area
Downstream Reach
Bridge
Reach
Biscayne
National
Park
Former,
WWTP
highway
1 Miles
Sediment Sampling Station
-------
IN
Figure 2-1 -4-
Sediment Sample Stations '
Military Canal Special Study
November, 1997
Salt
Barrier
Biscayne
National
Parte
Stonmw iter
Reservoir.
Boundary
Floodgate
.1'
ROAD ON LEVEE
Tidewater Channel
Downstream Reach
N^ncs Upstream Reach
Receiving
Area
Bridge
Reach
Former.
WWTP
UiCMWA Y
A Sediment Sampling Station
0
0.5
1 Miles
-------
Figure 2-2 ^4^
Sample Stations Above Pump Station
Military Canal Special Study
November, 1997
Stormwater
Reservoir
i610 609 '
*605A 604
Upstream
Boundary Canal
Pump
Station
Former
WWTP
200
200
400
600
800
1000 Feet
~ Sediment Sampling Station
-------
Figure 2-3 -4-
Upstream Reach Sample Stations "
Military Canal Special Study
November, 1997
Stomriwater
Resei^oir
f'yryw
Upstream Reach
Pump
Station
Ponds
200
200 400 600 800 1000 1200 1400 1600 Feet
~ Sediment Sampling Station
-------
IN
Figure 2-4 -4^
Bridge Reach Sample Stations '
Military Canal Special Study
November, 1997
_ „ 4 ^ 0. .. 200 0 200 400 600 800 Feet
Sediment Sampling Station
Upstream Reach
¦miff - ,'r— "Til v .
{
-------
IN
Figure 2-5 —
Downstream Reach Sample Stations '
Military Canal Special Study
November, 1997
Mi LL&
Downstream Reach
222 221 220 219 218 217 216 215 214 213 212 211A 210 209 208 207 206 205 204
GANAl
iU
o-
Floodgate
202Tidewa,ler —|
Channel^*
agjfiBOui i i
W "
!^J H
200 0 200 400 600 800 1000 1200 1400 1600 Feet
A Sediment Sampling Station
-------
IN
Figure 2-6 ^4^
Tidewater Channel Sample Stations *
Military Canal Special Study
November, 1997
'
Bisciayne
National
Park
Tidewater Channel
200
200 400 600 800 1000 1200 1400 1600 Feet
~ Sediment Sampling Station
-------
Figure 4-1
Military Canal
Conductivity (Salt Wedge) Upstream From Barrier
c/)
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CD
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CL
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Distance (Feet)
10' COND.VALUES
-------
p
FIGURE 4.2: Sediment Descriptions
Homestead Military Canal (Nov 97)
Stations 601-803
Pump Station
610 609 60S 607
Station Number
Org. Floe 5Y 5/3
Silty Marl 5Y5/1
If
my-
Marl SY6/1
m
Marl 5Y7/1
Marl 5Y8/1
V
-------
FIGURE 4.3 Sediment Descriptions
Homestead Military Canal (Nov 97)
Stations 401-505
107 St.Bridge
505 504 503 502 501 426 425 424 423 422 421 420 419 418 417 416 415 414 413 412 411 410 409 408 407 406 405 404 403 402 401
Station Number
Org. Floe 5Y4/2
Silty Marl 5Y5/1
Silty Shell 5Y 4/2
Marl 5Y6/1
IjpsrJ
mm
Sandy Silt 5Y 3/2
Marl 5Y7/1
Silt 5Y4/2
Marl 5Y8/1
Sandy Silt 5y 4/2
Rock Surface
-------
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-------
FIGURE 4.6: SKEWNESS DISTRIBUTION WHOLE SEDIMENT SAMPLE
MILITARY CANAL, HOMESTEAD, FL
-0.2
V)
til
z
5
LU
*
to
-0.4
-0.6
-0.8
0.1
0.2 0.3
COEFFICIENT OF VARIATION
0.4
0.5
0.6
-------
FIGURE 4.7: SKEWNESS DISTRIBUTION INORGANIC FRACTION SEDIMENT SAMPLES
MILITARY CANAL, HOMESTEAD, FL
CO
(/>
Ui
z
5
LU
*
CO
0.2 0.3 0.4
COEFFICIENT OF VARIATION
-------
FIGURE 4.8: KURTOSIS DISTRIBUTION WHOLE SEDIMENT SAMPLE
MILITARY CANAL, HOMESTEAD, FL
CO
CO
O
h-
cr
3
-0.5
0.1
0.2
0.3
0.4
0.5
0.6
COEFFICIENT OF VARIATION
-------
FIGURE 4.9: SEDIMENT MOISTURE vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
10 15 20 25
PERCENT ORGANIC MATTER
ANOVA: % MOISTURE vs. % OM
Regression Statistics
Multiple R
R Square
Adjusted R Square
Standard Error
Observations
0.941301
0.886047
0.882594
0.037213
35
Analysis of Variance
Regression
Residual
Total
Intercept
x1
LINEAR y-INTERCEPT
EQUATION:
df
Sum ofS
Mean Squ F
Significance F
1
0.355335
0.355335 256.5925
3.98E-17
33
0.045699
0.001385
34
0.401035
Coefficie
Standard
t Statistic P-vaiue
Lower 95. Upper 95.00%
1.506868
0.019796
76.11861 0
1.466592 1.547144
0.289368
0.018065
16.0185 2.08E-17
0.252615 0.326121
32.12686
Y = 32.1 * X A 0.29
-------
FIGURE 4.10: SEDIMENT ORGANIC MATTER SPATIAL DISTRIBUTION
MILITARY CANAL, HOMESTEAD, FL
z
LU
o
tr
LU
CL
107th ST.
SALTWATER BARRIER
2000
4000 6000 8000
DISTANCE FROM STATION 503 (ft)
10000
12000
% ORGANIC MATTER
'% MOISTURE
-------
FIGURE 4.11: PARTICLE SIZE CLASS SPATIAL DISTRIBUTION
MILITARY CANAL, HOMESTEAD, FL
400's
300's
2000
4000 6000 8000
DISTANCE FROM STATION 503 (ft)
—^PER_SILT— - PER3aND— 'PER_CLAY|
10000
—I
12000
100's
-------
FIGURE 4.12: SEDIMENT ALUMINUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
E.
2
3
3
J
<1
4100
3100
2100
1100
6100
5100
20 30
ORGANIC MATTER (%)
ALUM vs OM
Regression Statistics
Multiple R 0.4685336
R Square 0.2195238
Adjusted R 0 195873
Standard E 1147.3572
Observatio 35
ANOVA
df
SS
MS
h ignificance ~F
Regression
1
12218928
12218928
9.2818771 0.0045287
Residual
33
43442141
1316428.5
Total
34
55661069
Intercept
X Variable 61.017547 20.027966 3.0466173 0.0045^ 202^\l ZTtZV* ^ ^ ^
— ^^12 101.76478 70 97mi9 101.76478
-------
FIGURE 4.13: SEDIMENT ARSENIC vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
ARSENIC vs OM
Regression Statistics
Multiple R 0.5454519
R Square 0.2975177
Adjusted R 0.2762304
Standard E 6.5951479
Observatio 35
ANOVA
df
SS
MS
F ignificance F
Regression
1
607.91167
607.91167
13.976274 0.0007022
Residual
33
1435.3672
43.495975
Total
34
2043.2789
•r,rsaffirionts tandard Err Fstat P-value Lower 95% Upper 95% ower 95.0 pper95 0%
— ^4256559 2 0001948 1.2127098 0.2338511 -1.643774 6.4950861 -1.643774 6.4950861
intercept n-i-m-m? 3 7384855 0.0007022 0.1961663 0 6646063 0.1961663 0.6646063
X Variable 0 4303863 niihi^
-------
FIGURE 4.14: SEDIMENT BARIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
3
a.
<
CO
180
160
140
120
100
80
60
40
20
0
< * ~ t A ~
~ ~ * ~ * ~
10
20 30
ORGANIC MATTER (%)
40
50
BARIUM vs OM
Regression Statistics
Multiple R 0.0832866
R Square 0.0069367
Adjusted R -0 023156
Standard E 28 512967
Observatio 35
ANOVA
df
SS
MS
F ignificance F
Regression
1
187.40097
187.40097
0.2305085 06343143
Residual
33
26828 646
812.98929
Total
34
27016.047
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 22.444269 8.6474921 2 5954656 0.0139901 4 8507996 40.037738 4.8507996 40.037738
X Variable 0.2389594 0.4977149 0.480113 0.6343143 -0.77365 1.2515687 -0.77365 1.2515687
-------
FIGURE 4.15: SEDIMENT CADMIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
CADMIUM vs OM
Regression Statistics
Multiple R 0.5650819
R Square
Adjusted R
Standard E
Observatio
0.3193176
0.2986909
3.9976314
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
247.39891
247.39891
15.48076 0.000405
Residual
33
527.37488
15.981057
Total
34
774 77379
Coefficients tandard Err t Stat P-vaiue Lower 95% Upper 95% ower 95 0 pper 95.0%
Intercept 0.2498489 1.2124128 0.2060758 0 8379978 -2.216825 2.7165233 -2.216825 2.7165233
X Variable 0.2745599 0.0697816 3.9345597 0.000405 0.132588 0 4165317 0.132588 0.4165317
-------
FIGURE 4.16: SEDIMENT CALCIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
CALCIUM vs OM
Regression Statistics
Multiple R 0.6738724
R Square 0.4541041
Adjusted R 0.4375618
Standard E 32270 865
Observatio 35
ANOVA
df
SS
MS
F ignificance F
Regression
1
2.859E+10
2 859E+10
27.451083 9 105E-06
Residual
33
3.437E+10
1.041E+09
Total
34
6.295E+10
Coefficients tandard Err t Stat ~ Lower 95% Upper 95% ower 95 0 pper 95 0%
Intercept 319433.24 9787.1979 32.637865 1.071E-26 299521.02 339345 46 299521.02 339345 46
X Variable -2951 403 563.31174 -5.239378 9.105E-06 -4097.47 -1805.336 -4097 47 -1805 336
-------
FIGURE 4.17: SEDIMENT CHROMIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
20 30
ORGANIC MATTER (%)
CHROMIUM vs OM
Regression Statistics
Multiple R 0.6011982
R Square
Adjusted R
Standard E
Observatio
0.3614393
0.342089
9.9185556
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
1837.5704
1837.5704
18.678721 00001338
Residual
33
3246.4656
98.377745
Total
34
5084.036
Coefficients tandard Err t Stat
P-value
Lower 95% Upper 95%
ower 95.0
pper 95.0%
Intercept
X Variable
11585625 3.0081272 3.851441
0.7482732 0.1731357 4.3218886
0.0005119
0.0001338
5.4655389 17.70571
0 3960257 1.1005207
5 4655389
0.3960257
17.70571
1.1005207
-------
FIGURE 4.18: SEDIMENT COPPER vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
01
g
CC
LU
Q.
CL
o
O
300
250
200
150
100
50
~
~
i
, ._j
~ ~
~~
~
I
I
_ j
~ l ~
~
~ ~ *
~
j
--- "¦ ^ ~ ~- — — "
St. •
10 15 20 25 30
ORGANIC MATTER (%)
35
40
45
50
COPPER vs OM
Regression Statistics
Multiple R
0 547819
R Square
0.3001056
Adjusted R
0.2788967
Standard E
76.314063
Observatio
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
82407.12
82407.12
14 149972 0 0006583
Residual
33
192186.6
5823.8362
Total
34
274593.72
Coefficients tandard Err
t Stat
P-value
Lower 95% Upper 95%
ower 95.0
pper 95.0%
Intercept
X Variable
25.624813 23.144742
5.0109557 1.3321182
1 1071548
3.7616449
0.2762323
0.0006583
-21 46356 72.713182
2.3007386 7.7211728
-21.46356
2.3007386
72.713182
7.7211728
-------
FIGURE 4.19: SEDIMENT IRON vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
IRON vs OM
Regression Statistics
Multiple R
0.2779762
R Square
0.0772708
Adjusted R
0.0493093
Standard E
1427.701
Observatio
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
5632865.4
5632865.4
2.7634706 0.1059102
Residual
33
67264895
2038330.1
Total
34
72897760
Coefficients tandard Err t Stat
P-value
Lower 95% Upper 95% ower 95.0
pper 95.0%
Intercept
X Variable
2750.3592 432.99714 6 3519109
41 428851 24.921574 1.662369
3.437E-07
0.1059102
1869 4192 3631 2992 1869 4192
-9.274512 92.132213 -9.274512
3631 2992
92.132213
-------
8000
7000
=- 6000 -
o>
— 5000
s
2 4000
05
LU
2 3000
a
i 2000
1000 -
0 -
MAGNESIUM vs OM
Regression Statistics
Multiple R
0.1388305
R Square
0.0192739
Adjusted R
-0.010445
Standard E
1499.5357
Observatio
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
1458309.5
1458309.5
0.648539 0.4264003
Residual
33
74204045
2248607.4
Total
34
75662354
Coefficients tandard Err
t Stat
P-value
Lower 95% Upper 95%
ower 95.0
pper 95.0%
Intercept
X Variable
2037 0541 454.78338
21.079633 26.175502
4.4791745
0.8053192
8.482E-05
04264003
1111.7896 2962.3186
-32.17487 74.334134
1111.7896
-32.17487
2962.3186
74.334134
FIGURE 4.20: SEDIMENT MAGNESIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
n
~ ~
10
20 30
ORGANIC MATTER (%)
40
50
-------
FIGURE 4.21: SEDIMENT MANGANESE vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
MANGANESE vs OM
Regression Statistics
Multiple R 0 4901307
R Square 0.2402281
Adjusted R 0.2172047
Standard E 6.7524457
Observatio 35
ANOVA
df
SS
MS
F ignificance F
Regression
1
475.74773
475.74773
10.434089 0.0028004
Residual
33
1504 6523
45 595523
Total
34
1980.4
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 21.907578 2.0479006 10.697579 2.913E-12 17.74109 26 074067 17 74109 26.074067
X Variable 0.3807383 0.1178689 3.230184 0.0028004 0.140932 0.6205446 0.140932 0.6205446
-------
FIGURE 4.22: SEDIMENT SILVER vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
SILVER vs OM
Regression Statistics
Multiple R
0.3168819
R Square
0.1004142
Adjusted R
0.073154
Standard E
26.036634
Observatio
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
2497.1002
2497.1002
3.6835477 0.0636338
Residual
33
22370.909
677.90632
Total
34
24868.009
Coefficients tandard Err
f Stat
P-value
Lower 95% Upper 95%
ower 95.0
pper 95 0%
Intercept
X Variable
12.194444 7.896463
0.8722805 0.4544886
1.544292
1.9192571
0.1320544
0 0636338
-3 871043 28.259932
-0.052384 1.7969454
-3.871043
-0.052384
28 259932
1.7969454
-------
FIGURE 4.23: SEDIMENT STRONTIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
4500
4000
o>
E
z
o
a.
h
c/)
10 20 30
ORGANIC MATTER (%)
40
50
STRONTIUM vs OM
Regression Statistics
Multiple R 0.5257282
R Square 0.2763901
Adjusted R 0.2544626
Standard E 524.69997
Observatio 35
ANOVA
df
SS
MS
F
ignificance F
Regression
1
3470196.6
3470196.6
12.604685
0.0011813
Residual
33
9085232
275310.06
Total
34
12555429
Coefficients tandard Err
t Stat
P-value
Lower 95% Upper 95%
ower 95.0
pper 95.0%
Intercept
X Variable
2900 5147 159.13247
-32.51736 9.1590249
18.227045
-3.550308
8.55E-19
0.0011813
2576 757 3224.2724
-51.15155 -13.88317
2576.757
-51.15155
3224.2724
-13.88317
-------
FIGURE 4.24: SEDIMENT TIN vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
TIN vs OM
Regression Statistics
Multiple R 0.4487844
R Square 0.2014074
Adjusted R 0.1764514
Standard E 32.865122
Observatio 34
ANOVA
df SS MS F ignificance F
Regression 1 8717.0717 8717.0717 8 070494 0.0077624
Residual 32 34563.72 1080 1162
Total 33 43280.791
0 5 10 15 20 25 30 35 40 45 50
ORGANIC MATTER (%)
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 9.9858862 9.9701517 1 0015782 0.3240614 -10.32263 30.294404 -10.32263 30 294404
X Variable 1.646683 0.5796421 2.8408615 0.0077624 0.4659916 2.8273743 0.4659916 2.8273743
-------
0 10 20 30 40 50
ORGANIC MATTER (%)
FIGURE 4.25: SEDIMENT TOTAL MERCURY vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD. FL
TOTAL MERCURY vs OM
Regression Statistics
Multiple R 0.4762036
R Square 0.2267698
Adjusted R 0.2033386
Standard E 1.2480846
Observatio 35
ANOVA
df SS MS F ignificance F
Regression 1 15.075734 15.075734 9.6781078 0.0038314
Residual 33 51.404597 1.557715
Total 34 66.480331
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
"intercept 0.3450223 0.3785226 0.9114972 0.3686442 -0.425088 1.1151328 -0 425088 1 1151328
X Variable 0.0677762 0.0217862 3.1109657 0.0038314 0.0234518 0.1121007 0.0234518 0 1121007
-------
FIGURE 4.26: SEDIMENT VANADIUM vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
VANADIUM vs OM
Regression Statistics
Multiple R 0.428814
R Square 0.1838815
Adjusted R 0.1591506
Standard E 7.3856994
Observatio 35
ANOVA
df SS MS F ignificance F
Regression 1 405.58508 405.58508 7.4353037 0.0101615
Residual 33 1800.1023 54.548556
Total 34 2205.6874
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 9.577304 2.2399555 4.2756671 0 0001529 5 0200767 14 134531 5 0200767 14.134531
X Variable 0.3515436 0.1289228 2.7267753 0.0101615 0.0892479 0 6138393 0.0892479 0.6138393
-------
FIGURE 4.27: SEDIMENT ZINC vs. ORGANIC MATTER
MILITARY CANAL, HOMESTEAD, FL
ORGANIC MATTER (%)
ZINC vs OM
Regression Statistics
Multiple R 0.5683685
R Square 0.3230427
Adjusted R 0.3025289
Standard E 146.29927
Observatio 35
ANOVA
df SS MS F ignificance F
Regression 1 337052.05 337052.05 15 747538 0 0003681
Residual 33 706314.7 21403.476
Total 34 1043366.7
Coefficients tandard Err
t Stat P-value
Lower 95% Upper 95% ower 95.0
pper 95.0%
Intercept
X Variable
54.825006 44 37005
10.134135 2 5537616
1.2356309 0.22532
3 9683168 0.0003681
-3544661 145.09662 -35.44661
4 9384639 15.329806 4 9384639
145.09662
15.329806
-------
FIGURE 4.28: SEDIMENT ALUMINUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
ALUM vs CALCIUM
Regression Statistics
Multiple R
0.446822
R Square
0.1996499
Adjusted R
0.1753968
Standard E
1161.8734
Observatio
35
ANOVA
df
SS
MS
F ignificance F
Regression
1
11112725
11112725
8 2319538 0.0071263
Residual
33
44548344
13499498
Total
34
55661069
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 7070.924 1296.9961 5.4517695 4.861E-06 4432.1635 9709 6846 4432.1635 9709 6846
X Variable -0.013286 0 0046307 -2.869138 0.0071263 -0.022707 -0 003865 -0 022707 -0.003865
-------
FIGURE 4.29: SEDIMENT ARSENIC vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
ARSENIC vs CALCIUM
Regression Statistics
Multiple R 0.367515
R Square 0 1350673
Adjusted R 0.1088572
Standard E 7.3180946
Observatio 35
ANOVA
df SS MS F ignificance F
Regression 1 275 98009 275.98009 5 153256 0.0298606
Residual 33 1767.2988 53.554508
Total 34 2043.2789
Coefficients tandard Err t Stat P-value Lower 95% Upper 95% ower 95.0 pper 95.0%
Intercept 26.965108 8 1691691 3.3008386 0.0023206 10.344796 43.585421 10 344796 43 585421
X Variable -6.62E-05 2.917E-05 -2.270078 0.0298606 -0 000126 -6 87E-06 -0 000126 -6 87E-06
-------
FIGURE 4.30: SEDIMENT BARIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
0 — —
100000 150000 200000 250000 300000 350000 400000
CALCIUM (mg/l)
BARIUM vs. CALCIUM
Regression Statistics
Multiple R
0.119954
R Square
0.014389
Adjusted
-0.01548
Standard
28.40578
Observati
35
ANOVA
df
SS
MS
F gnificance F
Regressio
1
388.7304
388.7304
0.481765 0.492482
Residual
33
26627.32
806.8884
Total
34
27016.05
Coefficient
andard Err
t Stat
P-value
ower 95%
pper 95% ower 95.0
pper 95.0
Intercept 47.64684
X Variable -7.9E-05
31.7093
0.000113
1.502614
-0.69409
0.142449
0.492482
-16.8663
-0.00031
112.1599 -16.8663
0.000152 -0.00031
112.1599
0.000152
-------
FIGURE 4.31: SEDIMENT CADMIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CADMIUM vs. CALCIUM
Regression Statistics
Multiple R 0.421072
R Square 0.177301
Adjusted 0.152371
Standard 4.394919
O bs e rva ti 35
anova
df SS MS F gnificance F
Regressio 1 137.3685 137.3685 7.111896 0.01177
Residual 33 637.4053 19.31531
Total 34 774.7738
Coefficient
andard Err
t Stat
P-value
ower 95%
pper 95% ower 95.0
pper 95.0
Intercept 17.1432
X Variable -4.7E-05
4.906036
1.75E-05
3.494307
-2.66681
0.001377
0.01177
7.161782
-8.2E-05
27.12461 7.161782
-1.1E-05 -8.2E-05
27.12461
-1.1E-05
-------
FIGURE 4.32: SEDIMENT CHROMIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
CHROMIUM vs. CALCIUM
Regression Statistics
Multiple R 0.484856
R Square 0.235085
Adjusted
0.211906
Standard
10.8556
Observati
35
ANOVA
df
SS
MS
F ignificance F
Regressio
1
1195.181
1195.181
10 14205 0.00315825
Residual
33
3888 855
117.8441
Total
34
5084.036
Coefficient andard Err t Stat P-value Lower 95% pper 95% ower 95.0 pper 95.0
Intercept 60.52695 12.11808 4.994765 1.87E-05 35.8725164 85.18139 35.87252 85.18139
X Variable -0.00014 4.33E-05 -3.18466 0.003158 -0 0002258 -5E-05 -0.00023 -5E-05
-------
FIGURE 4.33: SEDIMENT COPPER vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
COPPER vs CALCIUM
Regression
Statistics
Multiple R
0.424452
R Square
0.18016
Adjusted
0.155316
Standard
82.59485
Observati
35
ANOVA
df_ SS MS F ignificance F
Regressio 1 49470.7 49470.7 7.251738 0.01104297
Residual 33 225123 6821.91
Total 34 274593.7
Coefficient
andard Err
t Stat
P-value
Lower 95%
pper 95% ower 95.0
pper 95.0
Intercept 343.3355
X Variable -0.00089
92.20041
0.000329
3.723796
-2.69291
0.000732
0.011043
155.752181
-0.0015562
530.9188 155.7522
-0.00022 -0.00156
530.9188
-0.00022
-------
FIGURE 4.34: SEDIMENT IRON vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
IRON vs. CALCIUM
Regression Statistics
Multiple R 0.425777
R Square 0.181286
Adjusted 0.156477
Standard 1344.826
Observati 35
ANOVA
df
SS
MS
F ignificance F
Regressio
1
13215350
13215350
7.30712 0.01076864
Residual
33
59682410
1808558
Total
34
72897760
Coefficient andard Err t Stat P-value Lower 95% pper 95% ower 95.0 pper 95.0
Intercept 7359.275 1501.226 4.902176 2.46E-05 4305.00508 10413.54 4305.005 10413.54
X Variable -0.01449 0.00536 -2.70317 0.010769 -0.0253933 -0.00358 -0.02539 -0.00358
-------
FIGURE 4.35: SEDIMENT MAGNESIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
MAGNESIUM vs. CALCIUM
Regression Statistics
Multiple R 0.404068
R Square
Adjusted
Standard
Observati
0.163271
0.137915
1385.082
35
ANOVA
df
SS
MS
F ignificance F
Regressio
Residual
Total
1
33
34
12353444
63308910
75662354
12353444
1918452
6.439278 0.01606922
Coefficient andard Err t Stat
P-value
Lower 95%
pper 95% ower 95.0
pper 95.0
Intercept 6219.405 1546.163 4.022476
X Variable -0.01401 0.00552 -2.53757
0.000316
0.016069
3073.70949
-0.0252393
9365.1 3073.709
-0.00278 -0.02524
9365.1
-0.00278
-------
FIGURE 4.36: SEDIMENT MANGANESE vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
MANGANESE vs CALCIUM
Regression Statistics
Multiple R
0.535207
R Square
0.286446
Adjusted
0.264823
Standard
6.543843
Observati
35
ANOVA
df
SS
MS
F ignificance F
Regressio
1
567.2779
567.2779
13.24738 0.00092364
Residual
33
1413.122
42.82188
Total
34
1980.4
Coefficient andard Err t Stat P-value Lower 95% pper 95% ower 95.0 pper 95.0
Intercept 53.68095 7.304874 7.348648 1.94E-08 38.8190575 68.54284 38.81906 68.54284
X Variable -9.5E-05 2.61 E-05 -3.6397 0.000924 -0.000148 -4.2E-05 -0.00015 -4.2E-05
-------
FIGURE 4.37: SEDIMENT SILVER vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
SILVER vs CALCIUM
Regression Statistics
Multiple R 0.205246
R Square 0.042126
Adjusted 0.013099
Standard 26.86691
Observati 35
AN OVA
cIf
SS
MS
>- ignificance F
Regressio
1
1047.583
1047.583
1.451286 0.2368907
Residual
33
23820.43
721.8311
Total
34
24868.01
. 'S'a( p-"3'"e pper on n ^ o
intercept60 49162 29 99146 2.016961 0.051895 -0 5265198 121 5098 -0 52652 121 5098
X Variable -0 00013 0 000107 -1 20469 0.236891 -0,0003469 8.89E-0S -0 00035 8 89E 05
-------
FIGURE 4.38: SEDIMENT STRONTIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
STRONTIUM vs CALCIUM
Regression Statistics
Multiple R
0.676513
R Square
0.45767
Adjusted
0.441236
Standard
454.2454
Observati
35
AN OVA
df
SS
MS
F ignificance F
Regressio
1
5746244
5746244
27.84857 8.143E-06
Residual
33
6809184
206338.9
Total
34
12555429
Coefficient andard Err t Stat P-value Lower 95% pper 95% ower 95.0 pper 95.0
Intercept -213.629 507.073 -0.4213 0.676269 -1245.2774 818.0196 -1245.28 818.0196
X Variable 0.009554 0.00181 5.277175 8.14E-06 0.00587055 0.013237 0.005871 0.013237
-------
FIGURE 4.39: SEDIMENT TOTAL MERCURY vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
100000 150000 200000 250000 300000 350000 400000
CALCIUM (mg/l)
TOTAL MERCURY vs calcium
Repression
Statistics
Multiple R
0.325264
R Square
0.105796
Adjusted
0.078699
Standard
1.342171
Observati
35
anova
^ MS F ignificance F
Regressio 1 7.033381 7.033381 3.904348 0.05657118
Residua! 33 59.44695 1.801423
Total 34 66.48033
" Coefficient andard Err
t Stat
P-value
Lower 95%
pper 95% ower 95.0
pper 95.0
Intercept 4.249085 1.498262
X Variable -1.1E-05 5.35E-06
2.83601
-1.97594
0.007745
0.056571
1.20084659
-2.145E-05
7.297324 1.200847
3.13E-07 -2.1E-05
7.297324
3.13E-07
-------
FIGURE 4.40: SEDIMENT VANADIUM vs. CALCIUM
MILITARY CANAL, HOMESTEAD, FL
CALCIUM (mg/l)
VANADIUM vs CALCIUM
Regression Statistics
Multiple R 0.414609
R Square 0.1719
Adjusted 0.146806
Standard 7.439715
Observati 35
ANOVA
df
SS
MS
F gniftcance F
Regressio
1
379.1584
379.1584
6.850275 0.013273
Residual
33
1826.529
55.34936
Total
34
2205.687
Coefficient andard Err t Stat P-value ower 95% pper 95%ower 95.0 pper 95.0
Intercept 36.13446 8.304934 4.350963 0.000123 19.23794 53.03099 19.23794 53.03099
X Variable -7.8E-05 2.97E-05 -2.6173 0.013273 -0.00014 -1.7E-05 -0.00014 -1.7E-05
-------
Regression Statistics
Multiple R 0.447697
R Square 0.200433
Adjusted 0.176203
Standard 158.9971
Observati 35
anova
df ^ MS F gnificance F
Regressio 1 209124.7 209124.7 8.272316 0.007001
Residual 33 834242.1 25280.06
Total 34 1043367
-------
Fluoranthene
Above RAGS EV of 113 ug/kg
Below RAGS EV of 113 ug/kg
Below Estimated Detection Limits
Former.
WWTP
7 h=* ^ ffc t? VV
. y >| Pynds U pstream Reach
PU Tip
Sta ion
Receiving
Area
Bridge
Reach
Downstream' Reach
8
Tidewater Channel
UJKMUUAY-
HJ " -a! -
Zf" ^
2
4T „¦
t 'M
Minimum reported value = 17 ug/kg
Maximum reported value = 5400 ug/kg
0.5
1 Miles
Figure 5-1
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
k
-------
Dibenzo(a,h)anthracene
Above RAGS EV of 6.22 ug/kg
Below Estimated Detection Limits
Salt
Barrier
ROAD on L£ VFF
Tidewater Channel
-«r~
-
JC u
-< -*¦ i*. yt
» >•
Wis Upstream Reach
Receiving
Area
Downstream! Reach
Bridge
Reach
UirMWAY
1 Miles
LStommi rater
Reseryoir
Boundary
Canal jfc
Former
WWTP
Minimum reported value = 17 ug/kg
Maximum reported value = 550 ug/kg
Figure 5-2
Military Canal Special Study N
Homestead Air Force Base
November, 1997
-------
Pyrene
Above RAGS EV of 153 ug/kg
Below RAGS EV of 153 ug/kg
Below Estimated Detection Limits
Salt
Barrier
Biscayne
National
Park
Stormv ater
Reser /oir*
Boundary
Canal AFF~j
Floodgate"
fwMTffiggSMEEgS]
few Gtsf.
Wis Upstream Reach
Receiving
Area
road on levff
Tidewater Channel
Downstream Reach
Bridge
Reach
uuzuwa v
Former
WWTP
a- - u. - AH 2
-zl'X 2L _
Minimum reported value = 14 ug/kg
Maximum reported value = 4500 ug/kg
1 Miles
Figure 5-3
Military Canal Special Study N
Homestead Air Force Base \
November, 1997
-------
Benzo-a-pyrene
¦ Above RAGS EV of 88.8 ug/kg
_ Below RAGS EV of 88.8 ug/kg
¦ Below Estimated Detection Limits
Salt
Barrier
Stormvlater 5
Reser/oir.
Boundary \
£ANAt
ROAD ON LEVFF
Tidewater Channel
yew tfisp — —
Wjs Upstream Reach
Receiving
Area
Downstream' Reach
Bridge
Reach
uirMWA V
Former
WWTP
Minimum reported value =11 ug/kg
Maximum reported value = 2400 ug/kg
i-'A
•
-------
Benzo(a)anthracene
mm Above RAGS EV of 74.8 ug/kg
SiS Below RAGS EV of 74.8 ug/kg
I Below Estimated Detection Limits
Salt
Barrier
Stormv rater
Reser /oir.
Boundary
Canal A*yr~>
Floodgate1*"
*11 itary
ROAD ON LEVFF
Tidewater Channel
Downstream Reach
Wis Upstream Reach
Receiving
Area
Bridge
Reach
Former.
WWTP
uinuMJLV
Minimum reported value = 13 ug/kg
Maximum reported value = 3400 ug/kg
0.5 1 Miles
~ '
Figure 5-5
Military Canal Special Study N
Homestead Air Force Base A
November, 1997 y
-------
Chrysene
¦ Above RAGS EV of 108 ug/kg
..! Below RAGS EV of 108 ug/kg
I Below Estimated Detection Limits
Salt
Barrier
Stormv ater
Reser/oir.
Boundary
Canal /rr10"
|_Floodgatf^_
£AMAt.
ROAD ON LEVFF
Tidewater Channel
\
tew-wsp — —
Wtds Upstream Reach
Receiving
Area
Downstream' Reach
Bridge
Reach
Former.
WWTP
U1/-.UIA/AY
Minimum reported value = 12 ug/kg
Maximum reported value = 2100 ug/kg
Figure 5-6
Military Canal Special Study
Homestead Air Force Base
November, 1997
0.5 1 Miles
— "
N
+
-------
Anthracene
¦I Above RAGS EV of 46.9 ug/kg
i ' i Below RAGS EV of 46.9 ug/kg
¦ Below Estimated Detection Limits
Salt
Barrier
Bridge
Biscayne
National
Park
Floodgate*"
road on levff
w
Wis Upstream Reach
Receiving
Area
Tidewater Channel
Downstream Reach
Bridge
Reach
Former.
WWTP
nmuWAY
Minimum reported value = 16 ug/kg
Maximum reported value = 450 ug/kg
Figure 5-7
Military Canal Special Study
Homestead Air Force Base
November, 1997
0.5 1 Miles
N
-------
Phenanthrene
Above RAGS EV of 86.7 ug/kg
Below RAGS EV of 86.7 ug/kg
Below Estimated Detection Limits
i j ^av
>. if*-- *2$
Minimum reported value = 12 ug/kg
Maximum reported value = 1500 ug/kg
0.5
1 Miles
J
Figure 5-8
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
-------
Acenaphthylene
¦I Above RAGS EV of 5.87 ug/kg
¦ Below Estimated Detection Limits
Salt
Barrier
Tidewater Channel ^ 1
ROAD ON LEVFF
Downstream Reach
Bridge
Reach
j.urzuuuA y
nds Upstream Reach
Former
WWTP
Receiving
Area
Minimum reported value = 14 ug/kg
Maximum reported value = 260 ug/kg
J
'
1 Miles
Figure 5-9
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
-------
Acenaphthene
Mi Above RAGS EV of 6.71 ug/kg
I Below Estimated Detection Limits
Salt
Barrier
Stormy rater j r-
Reser/oir.
Boundary \ j 1
{ft /yrtt*
Floodgate^
Tidewater Channel
Bridge
Reach
Former.
WWTP
umnvuA v
Minimum reported value = 31 ug/kg
Maximum reported value = 110 ug/kg
1 Miles
Upstream Re
Receiving
Area
Figure 5-10
Military Canal Special Study N
Homestead Air Force Base a
November, 1997 np
-------
Fluorene
Above RAGS EV of 21.2 ug/kg
Below Estimated Detection Limits
Salt
Barrier
Stormvtaters
Reser/oir.
Boundary \
Floodgate'
road on lcvff
)t»w-B+sp
Wis Upstream Reach
Receiving
Area
Tidewater Channel
Downstream Reach
Bridge
Reach
Lunma/A v
Former
WWTP
Minimum reported value = 31 ug/kg
Maximum reported value = 180 ug/kg
1 Miles
Figure 5-11
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
-------
4,4'-DDE
Above RAGS EV of 2.07 ug/kg
Below RAGS EV of 2.07 ug/kg
Minimum reported value = 0.85 ug/kg
Maximum reported value = 600 ug/kg
0.5
1 Miles
Figure 5-12
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
-------
4,4'-DDD
Above RAGS EV of 1.22 ug/kg
Below Estimated Detection Limits
Salt
Barrier
Biscayne
National
Park
Stormv 'ater 3
Reser /oir.
Boundary \
Canal / ¦¦ * ¦
¦ ¦II ¦
jvm rAii
HO AO ON LEVFF
Tidewater Channel
Downstream Reach
Upstream Reach
Bridge
Reach
Former,
WWTP
Receiving
Area
uir.t-IWAV
Minimum reported value = 7.2 ug/kg
Maximum reported value = 22 ug/kg
Figure 5-13
Military Canal Special Study
Homestead Air Force Base
November, 1997
0.5 1 Miles
N
+
-------
4,4'-DDT
Above RAGS EV of 1.19 ug/kg
Below Estimated Detection Limits
Salt
Barrier
Stormv ater
Reserrairv
Mil 1TARY
ROAD ON LEVFF
rfjW Disl
Sends Upstream Reach
Receiving
Area
Tidewater Channel
Downstream 'Reach
Bridge
Reach
njnuuuAV
Boundary
Canal /
Former
WWTP
UJ
1 Miles
Minimum reported value
Maximum reported value
= 2.1 ug/kg
= 740 ug/kg
Figure 5-14
Military Canal Special Study N
Homestead Air Force Base {
November, 1997
-------
Salt
Barrier
Blscayne
National
Park
Stormv rater £
Reser /oir»
Boundary \!
Caf>a> /'•"*
fffcwvV i IPU B
alP^nds 1 Upstream Reach
Receiving
Area
UCTED
Tidewater Channel
„-=£> * r .
DownstreanrReach
Bridge
Reach
uinuiA/A y
PCB-1254
Above RAGS EV of 21.6 ug/kg
Below RAGS EV of 21.6 ug/kg
Below Estimated Detection Limits
Figure 5-15
Military Canal Special Study
Homestead Air Force Base
November, 1997
Former
WWTP
Minimum reported value = 20 ug/kg
Maximum reported value = 780 ug/kg
1 Miles
-------
Cadmium
Above RAGS EV of 0.676 mg/kg
Below RAGS EV of 0.676 mg/kg
Salt
Barrier
.
Blscayne
National
Park
Floodgate1^
RESTRICTED
iew-Eksp— |f-
Wjs Upstream Reach
Receiving
Area
Tidewater Channel
• ..r ..
Downstream! Reach
Bridge
Reach
Former,
WWTP
uir.u\AJA V
Minimum reported value = 0.05 mg/kg
Maximum reported value = 16 mg/kg 0 °-5 1 Miles
Figure 5-16
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
-------
Copper
Above RAGS EV of 18.7 mg/kg
Below RAGS EV of 18.7 mg/kg
Salt
Barrier
Biscayne
National
Park
Stormvater
Reser /oir»
Boundary
Canl
Floodgate*"
RESTRICTED
Tidewater Channel
>6 W -Q+S# *1 §*-=
\>nds Upstream Reach
Receiving
Area
Downstream! Reach
Bridge
Reach
Former.
WWTP
liir.t-IXAtA V
Minimum reported value = 2.2 mg/kg
Maximum reported value = 360 mg/kg
Figure 5-17
Military Canal Special Study
Homestead Air Force Base
November, 1997
0.5 1 Miles
N
-------
Silver
Above RAGS EV of 0.733 mg/kg
Below RAGS EV of 0.733 mg/kg
Minimum reported value = 0.12 mg/kg
Maximum reported value = 110 mg/kg
0.5
1 Miles
Figure 5-18
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
-------
Total Mercury
¦i Above RAGS EV of 0.13 mg/kg
WM Below RAGS EV of 0.13 mg/kg
Salt
Barrier
Biscayne
National
Park
Stormv ater
Reser /oir.
Boundary
Canal
Floodgate'
restricted
Wjs Upstream Reach
Receiving
Area
Tidewater Channel
Downstream1 Reach
Bridge
Reach
Former.
WWTP
j.jjnuia/A Y
Minimum reported value = 0.02 mg/kg
Maximum reported value = 12 mg/kg 0 0 5 1 Miles
Figure 5-19
Military Canal Special Study N
Homestead Air Force Base j
November, 1997
-------
Zinc
Above RAGS EV of 124 mg/kg
Below RAGS EV of 124 mg/kg
Salt
Barrier
Blscayne
National
Park
Stormv ater
Reser /oir\
Boundary
Canal /fuTp"
Floodgate'*^
tlCTED
Tidewater Channel
Downstream! Reach
Sends Upstream Reach
Receiving
Area
Bridge
Reach
Former,
WWTP
j.j tr.uWAY
Minimum reported value = 2.7 mg/kg
Maximum reported value = 670 mg/kg 0 °-5 1 Miles
Figure 5-20
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
-------
Lead
Above RAGS EV of 30.2 mg/kg
Hi Below RAGS EV of 30.2 mg/kg
Salt
Barrier
Biscayne
National
Park
Stormv rater
Reser/oir.
Boundary
jlIS
Floodgate*"
RESTRICTED
Tidewater Channel
;«vV 1 i-li
Wjs Upstream Reach
Receiving
Area
Downstream Reach
Bridge
Reach
Former.
WWTP
Minimum reported value = 1.8 mg/kg
Maximum reported value = 160 mg/kg
Figure 5-21
Military Canal Special Study N
Homestead Air Force Base {
November, 1997 y
-------
Nickel
Below RAGS EV of 15.9 mg/kg
Below Estimated Detection Limits
Salt
Barrier
Blscayne
National
Park
Floodgate^
Boundary
Canal
>6tfV-Dl6p u —
Wjs Upstream Reach
Receiving
Area
Tidewater Channel
—" — I
Uir.UiA/AY
Former
WWTP
Minimum reported value = 0.74 mg/kg
Maximum reported value = 11 mg/kg
1 Miles
Figure 5-22
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
-------
Arsenic
Above RAGS EV of 7.24 mg/kg
Below RAGS EV of 7.24 mg/kg
Salt
Barrier
Blscayne
National
Park
Stormwater
Reser /oir.
Floodgate*"
iZANA
RESTRICTED
je w
Wis Upstream Reach
Receiving
Area
Tidewater Channel
*-j JT ••
Downstream! Reach
Bridge
Reach
Ujr.UWA Y
Boundary
Canal
U U tt—^
Former
WWTP
Minimum reported value = 0.59 mg/kg
Maximum reported value = 50 mg/kg
1 Miles
Figure 5-23
Military Canal Special Study N
Homestead Air Force Base {
November, 1997 y
-------
Antimony
1 Above RAGS EV of 2.0 mg/kg
IS Below RAGS EV of 2.0 mg/kg
¦ Below Estimated Detection Limits
Salt
Barrier
Biscayns
National
Park
Stormwater
Reser /oir»
Boundary
Canal
Floodgate1^
RESTRICTED
Tidewater Channel
-*- r -r-
Downstream1 Reach
Bridge
Reach
Former.
WWTP
Receiving
Area
umuiA/A V
Minimum reported value = 0.5 mg/kg
Maximum reported value = 3.1 mg/kg 0 0 5 1 Miles
Figure 5-24
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
-------
Chromium
Above RAGS EV of 52.3 mg/kg
Below RAGS EV of 52.3 mg/kg
Salt
Barrier
Biscayns
National
Parte
LStormwater
Reser/oir.
Boundary ^
Canal /ff{| rlhj
Tidewater Channel
3-e w-TOs{ t>—hJ
Sends Upstream Reach
Receiving
Area
Downstream Reach
Bridge
Reach
Former.
WWTP
UJSZUWAY
Minimum reported value = 2.4 mg/kg
Maximum reported value = 54 mg/kg
0.5 1 Miles
Figure 5-25
Military Canal Special Study
Homestead Air Force Base
November, 1997
N
+
-------
Minimum displayed value = 9 ug/kg
Maximum displayed value = 5400 ug/kg
Figure 5-26
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
Fluoranthene
Above RAGS EV of 113 ug/kg
Below RAGS EV of 113 ug/kg
Below Estimated Detection Limits
Stormwater Reservoir
Boundary
Canal
Receiving
Area
Military
Canal
Upstream
Reach
-------
Dibenzo(a,h)anthracene
Hi Above RAGS EV of 6.22 ug/kg
¦i Below Estimated Detection Limits
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
Minimum displayed value = 7.5 ug/kg
Maximum displayed value = 550 ug/kg
I Former
j WWTP
Figure 5-27
Military Canal Special Study
Homestead Air Force Base
November, 1997
Upstream
Reach
--"E
— i
100
100
200
300
400
500 Feet
-------
Minimum displayed value = 9 ug/kg
Maximum displayed value = 4500 ug/kg
i
Figure 5-28
Military Canal Special Study
Homestead Air Force Base
November 1997 100 o. 100 200 300 400 500 Feet
Stormwater Reservoir
Above RAGS EV of 153 ug/kg
Below RAGS EV of 153 ug/kg
Below Estimated Detection Limits
Boundary
Canal
Receiving
Area
Military
Canal
Upstream
Reach
Pyrene
-------
Benzo-a-pyrene
Above RAGS EV of 88.8 ug/kg
Below RAGS EV of 88.8 ug/kg
Below Estimated Detection Limits
Minimum displayed value = 9 ug/kg
Maximum displayed value = 2400 ug/kg
Figure 5-29
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
J J.
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Benzo(a)anthracene
¦i Above RAGS EV of 74.8 ug/kg
S3 Below RAGS EV of 74.8 ug/kg
!¦ Below Estimated Detection Limits
Figure 5-30
Military Canal Special Study
Homestead Air Force Base
November, 1997
Boundary
Canal
N
+
Stormwater Reservoir
Minimum displayed value = 8 ug/kg
Maximum displayed value = 3400 ug/kg
Receiving
Area
Military
Canal
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Chrysene
Above RAGS EV of 108 ug/kg
Below RAGS EV of 108 ug/kg
Below Estimated Detection Limits
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
Minimum displayed value = 9 ug/kg
Maximum displayed value = 2100 ug/kg
V^C»¦ Qv- z_- •
Figure 5-31
Military Canal Special Study
Homestead Air Force Base
November, 1997
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Minimum displayed value = 6 ug/kg
Maximum displayed value = 450 ug/kg
Figure 5-32
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
Stormwater Reservoir
Anthracene
Above RAGS EV of 46.9 ug/kg
Below Estimated Detection Limits
Receiving
Area
Upstream
Reach
Boundary
Canal
N
+
Military
Canal
-------
Phenanthrene
¦¦ Above RAGS EV of 86.7 ug/kg
Below RAGS EV of 86.7 ug/kg
¦I Below Estimated Detection Limits
Boundary
Canal
N
4-
Upstream
Reach
Figure 5-33
Military Canal Special Study
Homestead Air Force Base
November, 1997
Receiving
Area
Military
Canal
Minimum displayed value
Maximum displayed value
= 7.5 ug/kg
= 1500 ug/kg
Stormwater Reservoir
-------
Acenaphthylene
¦L Above RAGS EV of 5.87 ug/kg
¦¦ Below Estimated Detection Limits
Minimum displayed value = 6 ug/kg
Maximum displayed value = 260 ug/kg
Figure 5-34
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
'.*¦ 7 ¦ ------i: r.:ritr ~ 1
pstream
Reach
100
100
200
300
400
500 Feet
-------
Acenaphthene
¦L Above RAGS EV of 6.71 ug/kg
¦I Below Estimated Detection Limits
Minimum displayed value = 6 ug/kg
Maximum displayed value = 90 ug/kg
Figure 5-35
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
'} Former
j WWTP
Upstream
Reach
U_ LlTrfSS
r-"E=
•4- 'WJfcjL 4
100
100
200
300
400
500 Feet
-------
Fluorene
: Above RAGS EV of 21.2 ug/kg
I Below Estimated Detection Limits
Minimum displayed value = 6 ug/kg
Maximum displayed value = 180 ug/kg
Figure 5-36
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
__ ' '
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Above RAGS EV of 2.07 ug/kg
Stormwater Reservoir
Figure 5-37
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
-------
4,4'-DDD
Above RAGS EV of 2.07 ug/kg
Below Estimated Detection Limits
Minimum displayed value = 0.28 ug/kg
Maximum displayed value = 14 ug?kg
Figure 5-38
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
Upstream
Reach
U
100
100
200
300
400
500 Feet
-------
4,4'-DDT
RAGS EV = 1.19 ug/kg
Below Estimated Detection Limits
Boundary
Canal
N
+
Stormwater Reservoir
Minimum displayed value = 0.28 ug/kg
Maximum displayed value = 0.85 ug/kg
i
4 .. -I—*——~ ^
Receiving
Area
4=*--
I?
25-4, { f • —*-
r.Cf- — '
j* Former
] WWTP
Figure 5-39
Military Canal Special Study
Homestead Air Force Base
November, 1997
r-i
i
Military
Canal
Upstream
Reach
¦j ij
i
100
100
200
¦—
300
400
500 Feet
I
-------
PCB-1254
Above RAGS EV of 21.6 ug/kg
Below Estimated Detection Limits
Minimum displayed value = 1.7 ug/kg
Maximum displayed value = 93 ug/kg
Figure 5-40
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
J
:h~sr. * 01
... { _ /
Wpl^gBfcMK
'&r I
j Former
] WWTP
Military
Canal
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Cadmium
Above RAGS EV of 0.676 mg/kg
Below RAGS EV of 0.676 mg/kg
Minimum displayed value = 0.16 mg/kg
Maximum displayed value = 7 mg/kg
Figure 5-41
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Copper
Above RAGS EV of 18.7 mg/kg
Below RAGS EV of 18.7 mg/kg
Minimum displayed value = 8.3 mg/kg
Maximum displayed value = 100 mg/kg
Figure 5-42
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
Military
Canal
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Silver
Above RAGS EV of 0.733 mg/kg
Below RAGS EV of 0.733 mg/kg
Minimum displayed value = 0.32 mg/kg
Maximum displayed value = 25 mg/kg
Figure 5-43
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
N
+
Receiving
Area
ffi
Military
Canal
sja| ii 111 ; X
! — "jar' - U"—
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Minimum displayed value = 0.10 mg/kg
Maximum displayed value = 1.48 mg/kg
Figure 5-44
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
Boundary
Canal
N
+
Stormwater Reservoir
Upstream
Reach
Total Mercury
Above RAGS EV of 0.13 mg/kg
Below RAGS EV of 0.13 mg/kg
Receiving
Area
Military
Canal
'} Former
j WWTP
-------
Boundary
Canal
> Former
WWTP
Stormwater Reservoir
Above RAGS EV of 124 mg/kg
Below RAGS EV of 124 mg/kg
Minimum displayed value = 14 mg/kg
Maximum displayed value = 530 mg/kg
Figure 5-45
Military Canal Special Study
Homestead Air Force Base
November, 1997
Military
Canal
Upstream
Reach
Receiving
/ Area
-------
Figure 5-46
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
-------
Minimum displayed value = 0.74 mg/kg
Maximum displayed value = 8.2 mg/kg
Figure 5-47
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
-------
Arsenic
¦1 Above RAGS EV of 7.24 mg/kg
H Below RAGS EV of 7.24 mg/kg
E3
m
Minimum displayed value = 2.5 mg/kg
Maximum displayed value = 14 mg/kg
Figure 5-48
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
m
Boundary
Canal
N
+
Receiving
Area
eh
Military
Canal
J i-i-H
Upstream
Reach
iJl '
100
100
200
300
400
J"
500 Feet
-------
Minimum displayed value = 0.20 mg/kg
Maximum displayed value = 1.2 mg/kg
Figure 5-49
Military Canal Special Study
Homestead Air Force Base
November, 1997
100
100
200
300
400
500 Feet
Boundary
Canal
Receiving
/ Area
Former
WWTP
Stormwater Reservoir
Antimony
Below RAGS EV of 2.0 mg/kg
Below Estimated Detection Limits
Military
Canal
Upstream
Reach
-------
Chromium
Below RAGS EV of 52.3 mg/kg
Minimum displayed value = 10 mg/kg
Maximum displayed value = 31 mg/kg
Figure 5-50
Military Canal Special Study
Homestead Air Force Base
November, 1997
Stormwater Reservoir
Boundary
Canal
N
+
Receiving
Area
.I ,—~ ... L * 1—/ ...
a
Military
Canal
Upstream
Reach
100
100
200
300
400
500 Feet
-------
Minimum displayed value = 3.2 ug/kg
Maximum displayed value =17 ug/kg
Figure 5-51
Military Canal Special Study
Homestead Air Force Base
November, 1997
100 0 100 200 300 400 500 Feet
Stormwater Reservoir
Compound Detected
Below Estimated Detection Limits
Boundary
Canal
Receiving
Area
Silvex
Military
Canal
Upstream
Reach
-------
Hyalella azteca Whole Sediment o 0'5 1 Miles
~ Not Toxic i
~ Toxic
Ceriodaphnia dubia Adult
A Not Toxic
A Toxic
Ceriodaphnia dubia Reproduction
O Not Toxic
O Toxic
Salt
Barrier
Stormwater
Reservoir
r--vn
Boundi
Canal
"in MurQRY a
ROTRICTEt?
ROAD 0)N LEV&D
Q-SLosni
iPsyids Upstream Reach
| ] Receiving
Area
Downstream Reach
Bridge
Reach
Figure 5-52
Sediment Toxicity Test Results
Military Canal Special Study
November, 1997
Former
WWTP
(No pore water tests were toxic.)
-------
PAGE NOT
AVAILABLE
DIGITALLY
-------
Appendix B
Tables
-------
Table 1-1
Sediment Analytical Results - Metals
Military Canal Environmental Investigation - 1995
Homestead Air Force Base
INORGANIC ELEMENTS
Military Military
Canal Canal
SD-001 SD-002
MG/KG MG/KG
Military Military
Canal Canal
SD-003 SD-004
MG/KG MG/KG
Arsenic <60
Cadmium <10
Silver <20
Chromium <20
Copper 3 8
Lead 48
Vanadium 4 6
Zinc 130
Mercury 0.29
Aluminum 1800
Manganese 32
<75
<75
<75
<12
<12
<12
<25
95
<25
<25
25
<25
<25
210
32
<25
66
<25
<25
30
<25
35
420
75
<0. 05
4.3
0.52
2200
3600
4200
34
39
36
<# - Minimum Detection Limit
-------
TtMa 1-2
Mfaml-DadaD6RM Tributary Swflntwii Toxicity Study
Matate Data RacuKt
Aluminum
hen Arsenic Cadmium Coppar
Chromium
Laad Lithium Mmimm Mercury
Nleinl
Sllvar Vanadium
Zinc
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppb
ppm
ppm
ppm
ppm
MDL 0.066
0.028
1.4
0.03
1.0
4.0
0.8
05
1.0
7.0
15
0.04
0.01
1.1
STATION
AC0101
0.5
0.75
8.5
046
38.8
44.3
84.4
13.3
1855
98
18.8
0.08
30
196.4
ACQ102
0.72
102
8.4
2.11
28.4
32.1
94.5
8.8
84.2
83
95
038
185
1452
AC0103
059
1.04
11.8
0.44
48.1
56.5
113.1
17.3
334.8
80
16.8
0.1
39.6
286.9
BD0101
052
0.66
4.3
0.2
11.2
19j8
87.5
11.4
52.9
143
85
0.05
51.3
48.3
C1000101
0.48
0.65
4.1
024
37.8
185
29
82
62.5
87
8.8
0.08
5
49.3
C100A0101
0.66
0.78
5.7
0.18
15.5
18.2
22.2
9.8
41.8
58
93
0.08
8
45.8
cioceoioi
0.4
037
32
0.11
22.8
10.3
18.8
55
38.4
52
7.8
0.04
4.3
79.9
C100C0101
056
~ 66
22
0.14
21.9
13.4
11.1
8.8
20.5
53
7.8
0.05
4.7
67.9
C10101
056
OAS
9.5
0.33
38.1
17.1
37.8
8
83.1
70
8.6
033
16.9
110.7
C102D101
0.89
0.92
BDL
0.09
11.3
23
11.6
11.3
S3
23
92
0.05
16.5
29.5
C1020204
0.40
0.57
2.9
BOL
9
11.4
12.4
6
99.4
21
7S
BDL
95
18.1
C1020301
0.S4
031
2.2
oor
12.4
15.4
8.7
6.6
712
24
82
0.05
7.2
250
C1D2N0104
0.33
027
BOL
0.03
22.2
9.8
4.3
4.1
21
18
8.1
0.05
9.8
16.2
C1000101
0.7
0.8
BDL
0.12
17.2
18.4
10.4
8.3
82
28
10.4
0.05
14.9
51.4
C1030201
0.3
024
4
028
20.5
12.8
20.7
3.4
170.8
57
8.4
0.16
5/4
83.8
C1030301
0.36
022
4.7
021
13.9
15.2
7.8
4.8
892
39
8.4
0.08
5.4
22.8
C1Q3N0101
0.49
028
BDL
0.12
38.9
1317
9.2
6.2
19.7
17
8.8
BDL
8.7
5X7
C1110101
0.87
1.05
1.8
0.15
15.5
27.3
15.6
11.7
53.3
20
11.3
0.06
22.7
23.5
C1110201
059
2
7.4
0.1
8.7
17.8
5.9
7.9
152.8
28
9.7
BDL
18.8
20.4
CINCH 01
0.39
024
2.7
0.08
8.9
8.5
4.7
3.8
55.3
29
85
BDL
52
23.8
C1N0101
0.51
0.32
8.8
1.25
31.9
13.1
19.1
8
404.2
62
7.1
0.06
5.6
248.1
C1WO102
057
0.71
3.9
0.03
7.5
13.8
10.3
8.8
715
26
7
BDL
16
33,7
C1WOZ01
056
0.85
BDL
0.14
12.9
18.7
17.7
7-7
62.8
30
8.1
0.04
12.3
44.1
C20101
0.62
1.17
BDL
0.54
27.2
34.8
TO
8.7
655
150
26.6
1.01
16
98.8
C20201
0.81
155
BDL
0.77
33.6
29.5
33.4
10.9
77.3
234
10.8
1.46
165
100.2
C20301
0.7
0.88
4.8
028
9
19.8
40.4
9.5
385
81
9.3
0.17
28.7
56.7
C30101
0.52
1.84
12.6
1.82
109
47.4
282.8
11.2
71.3
144
21.9
2.08
31.9
514.7
040102
0.93
0.45
5.5
0.13
14.2
39
50.1
25.1
80.7
77
at
0.04
42.3
113.3
C40103
1.41
0.68
4.8
0.21
19.1
57.1
52-7
38.2
982
88
25
0.07
57.8
77.2
C4C201
0.64
158
8.4
0.6
25.9
38
131.1
18.8
88.9
117
235
0.09
38.9
204
C40202
0.51
1.41
8.7
039
11.3
17.4
71.1
8.2
45.6
94
10.3
0.08
19.8
158.5
C40301
1.81
2.97
4.1
3.5
81
77
333.3
19.3
163.3
337
18.4
1.4
31.5
245.3
C40302
0.88
3.08
6.3
9.72
1B.7
40.7
56.3
15.6
87.7
142
10
1.15
20.3
68.4
C50101
0.64
0.78
22
1.71
101
40.S
587.9
6.5
44.2
121
12.2
0.21
14.4
401.8
C50102
0.99
122
3.5
4.79
207
52.8
891.8
10.2
44.6
625
19.8
0.99
20
827.8
C601DJ
1.23
0.81
4.7
0.12
4
22.4
4.7
17.6
50.2
44
9
0.04
19
15.8
C80102
1.44
1.07
5.2
0.09
2.4
24.7
69
22.5
42.5
36
95
0.04
34.9
7.3
C60201
0.51
0.88
22
0.1
6.5
10.3
73
6.5
30.4
31
5.1
BDL
10.9
24.1
C80202
0.98
1.28
2
0.32
86.9
18.4
43.7
12.2
36.3
65
8.1
0.06
23.2
81.7
C60301
128
1.49
3.1
0.68
25.8
28.4
79.7
17.7
52.2
124
10.8
0.09
22.8
116.3
C60302
0.8
1.55
4.7
0.45
12.8
16.3
81.7
104
34.2
83
6.4
0.07
23.2
87.1
C60401
0.9
095
1.7
1.0G
26.9
23.6
192.3
12
45.6
203
93
0.39
17.4
148.3
ceo4oa
048
0.5S
2.2
0.63
13.5
14.1
107.0
G.8
27.8
98
7J2
0.29
10.9
77.4
G70101
1.33
0.81
BDL
1.05
21.4
32.2
98.8
18.6
41.9
108
12.5
0.33
283
124.4
C70102
0.87
0.83
2.3
1.23
23.3
37.1
201.7
13
31.1
121
13.2
05
19.1
223.3
C70103
0.88
0.73
3.1
0.8S
17.8
22.4
83.4
11.9
29.9
90
9
0.39
20.6
179
C70201
0.14
0.09
.. BDL
0.14
2.4
BDL
16.1
2.9
1.8
15
1.3
0.18
1.7
18.8
C70202
032
0.34
BDL
048
1&9
11
90.6
4.7
9.1
109
35
0.58
6.1
141.4
* IdanHfiu stmptos ftom MllRary Canal
-------
1at>l»1-2(Conttmmd)
Mtaml-Dtd* DERM Trlbubry S«dfirwnt Toufcty Study
MetabDataRtMM
Aluminum
Iraii
Amnio Cadmium Coppw 1
Chromium
%
*
ppm
ppm
ppm
ppm
MDL 4.068
0.028
14
0.03
1.0
4-0
STATION
C70203
0.56
076
3.1
0.63
16.2
21.8
C70301
134
2.01
1.9
2.36
74.1
09
C70302
1.13
1.73
6.2
1.74
32.8
37.1
070303
1.05
1.46
2.6
208
70.8
42.6
C80101
1.03
0.73
2.6
024
7.7
24.9
C601Q2
080
OA
2.8
0.13
8.6
22.1
C60103
133
0.91
2.6
0/46
14.6
28. B
CB0201
0.33
0.67
BDL
0.75
72.6
17.8
caosos
0.46
0.36
SQL
0.41
11.6
14.2
C80S09
2.33
0.33
BDL
0.09
2.3
4
C 00101
127
ass
1.5
0.46
6.6
24.8
C90192
1.43
0.91
BCL
0.16
16.6
27.7
C0O1O3
0.50
1.0*
4.6
O.OB
6.4
15.1
C90201
0.93
082
1.6
0.1
10.6
19.3
CS0202
1.81
1.96
4.3
0.22
10
39.3
C90203
0.17
O.OB
BDL
BDL
1.3
BDL
C90S01
0.16
0.29
SDL
0.03
3.1
4.3
C80302
0.18
0.31
ecu.
QjOS
4
4.0
C80303
056
1.12
2.1
022
14.7
121
C9CM01
0.87
0.73
2.6
0.21
17.4
16
C90403
0.42
1.06
4.6
0-41
19.6
13.6
C90404
0.35
0£6
BDL
0.11
77
7.6
FC0101
0.43
0.22
1.3
0.14
121
15
GUB101
0.35
026
7.1
0.23
288
16.1
GLD102
0.4
0.3
BDL
0.17
14.6
18.4
L290101
1.68
1.22
20
026
6.4
27,2
L2S0201
2.04
1.67
4.5
027
62
424
L300101
1.BS
154
4.2
0.16
12.7
32.2
L30010Q
1.S6
1.96
6.0
0.2
14.3
31 4
L300100
2.1
1.25
4.8
0.11
M
39.2
L30Q201
1.79
0.75
4.5
0.07
9.1
30.7
LSIEfllOZ
0.42
0.3B
BDL
0.24
31.6
19
uieokb
0.4
0.37
2.8
0.06
11.4
9-1
L91E0M1
0.S
0.47
3.7
0.07
2.6
12.6
L31N0101
1.69
1.05
3
0.07
92
30.4
L31N0201
0.69
0.72
BDL
0.08
10.1
25.2
MNH 01
1.06
0.69
27.3
33.87
807
>3.9
M10101
0.33
0.43
85
4.05
61.6
17.3
MW1OT
0.6
0.62
12.0
12.04
268
47.6
FP0102
O.S1
0.39
2.6
0.12
169
21.8
WC0104
0.26
1.41
2.4
0.6
17.6
37
Lwd Lithium MttiganvM MMcuty NiekM Silvw Vwidtun Zinc
ppm
PP»
ppm
ppb
ppm
ppm
PPm
ppm
0.9
0.6
1.0
7.0
1.0
0.04
0.01
1.1
132.3
6.1
25-5
117
10.3
1.38
15.7
141.3
393.3
14.7
36
328
14.8
3.01
27.1
3893
521.3
16.6
25.2
246
12.3
1.26
22.8
206.8
361.9
12.9
33
310
12
2.34
22.7
381.6
25.3
16.4
49.2
36
6.2
0.2
10.1
43
16.3
14.7
70.7
40
7.8
0.Q4
9.2
37.9
36.8
16.3
614
97
9.6
366
11.3
83.5
922.2
34
27.8
101
6.6
0.29
4.3
211
546
7.2
24.7
60
4.9
122
5.6
963
9.8
4.3
10.2
24
1.4
0.22
2.3
6.2
37.2
16.1
51
19
7.6
046
22.9
16,3
716
52.1
54.5
31
8.6
0.07
34.9
31.4
24
11.6
509
20
6
004
29.7
18.8
238
18.2
46.4
22
?
0.04
26.4
25.6
37.4
42.3
107.4
52
122
008
45
47.3
23
5.2
7.2
SOL
12
BDL
3.1
3.8
93
46
21.7
8
IjB
BDL
5
11.6
06
5.4
23
21
16
BDL
58
16.1
24.2
12
64.8
72
6.1
0.06
12.6
52.5
37.3
14.3
37.6
30
6
0.12
19
58
74.4
9.5
66.7
108
5.8
0.2
14.8
69
16.7
6.8
37
62
26
0.05
7,5
31 7
52
6.2
33.1
26
62
BDL
«,4
26.4
20.1
3.4
73.6
56
94
0.06
3.7
34.7
14.6
7.1
56.9
32
6.6
0.06
14
31.3
27
31
60.7
102
10.3
0.04
193
32.3
35.4
37.4
123.7
94
14.6
0.04
32.8
42.5
20.1
26.6
68.6
76
12.2
0.08
385
44.6
20.1
26
92.6
106
11.6
0.06
31.6
54.3
17.6
360
99.4
42
12.6
0.07
31.5
23.6
11.9
243
54
44
11,5
0.04
32.4
15.9
24.9
7.1
117.9
51
6.6
0.1
13,8
56.2
14.3
&8
56
36
7.6
0.08
8.1
24.4
3.7
5.6
96.4
»
8.2
BDL
3.1
16.5
12.6
238
66.6
34
11
0.04
25.2
16.7
20.7
11.4
40.6
17
10.2
0.05
1&4
12.8
267
7.3
37.4
5646
21.7
3461
18.5
881.9
45.2
4.2
24
949
6.4
16.87
13.4
239.3
101.2
8.4
41.5
2568
143
35.72
1&6
587
6&4
15.1
46
68
95
0.07
15.4
111.2
273.8
3.6
1052
83
13:9
023
6.B
70.6
• IdetKHes wmpM Itam MWwy C«mI
-------
INORGANIC ELEMENTS
Aluminum
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Lead
Manganese
Mercury
Nickel
Silver
Zinc
Table 1-3
Sediment Analytical Results - Metals
Boundary Canal Remedial Investigation - 1996
Homestead Air Force Base
Military
Canal
SD-0001
MG/KG
3790
5.7
27.8
0.25
<2.1
18.3
53.6
38.8
42.6
<0.91
<4.3
4.4
140
Military
Canal
SD-0002
MG/KG
2080
7.5
26.2
0.14
<2.1
12
56
32.5
38.5
<0.91
<2.6
7.5
154
Military
Canal
SD-0003
MG/KG
3640
5.8
16.8
0.19
2.5
17 .6
66.3
29.1
35 .7
0.73
3.5
11.3
188
Military
Canal
SD-0004
MG/KG
3700
4.7
12.2
0.3
1.6
18.2
58.1
22.6
28.6
<0 .77
4.2
8.2
142
Military
Canal
SD-0005
MG/KG
2740
3.6
8.2
0.2
<1.5
10.5
32.9
28.9
28.8
<0.76
<3.2
<3.2
65
Military
Canal
SD-0006
MG/KG
4960
6.1
14.4
0.24
<1.1
16.8
34.9
17.1
65.1
<0.67
<2.3
<2.3
45.7
<# - Minimum Detection Limit
-------
Table 1-4
Water Quality Summary
SWIM Plan -1995
SWIM MI03 AR03 BL03 BS04 CG07 LR06 MR08 MW04 PR03 SK02 TM03
PLAN MBLI. C-lll C-100
Dissolved Oxygen1 (mg/1)
*54
6.6
6.8
7.1
5.3
3.0
N>
OO
L/\
©
7.0
6.1
5.9
4.9
Dissolved Oxygen2 (mg/1)
s54
4.6
6.3
6.8 2.3 2.3 2.9 3.2 7.4 6.3 4.2 3.6
Turbidity (NTU)
*294
1.3
1.5
0.8
0.9
2.4
1.3 1.1
1.0
1.0
1.0
0.8
Water Column Color (PCU)
None
10.0
15.0
5.0
3 0.0
22.5
50.0 40.0
2.5
2.5
37.5
25.0
Ammonia Nitrogen (mg/1)
0.5
0.04
0.05
0.03
0.10
0.10
0.19 0.06
0.06
0.10
0.09
0.03
Nitrate/Nitrite (mg/1)
0.05
0.38
0.03
0.03
0.21
0.10
0.30 0.12
1.90
3.60
0.18
0.17
Total Phosphorous (mg/1)
s.OOOl4
0.018
0.005
0.011
0.023
0.054
0.040 0.017
.013
0.012 0.015
0.016
Cadmium (ug/1)
<104
0.00
0.00
0.00
0.00
0.00
0.00 0.00
0.00
0.00
0.00
0.00
Copper (ug/1)
Complex4
0.1
0.0
0.0
0.0
0.0
0.0 0.3
0.0
0.0
0.0
0.6
Lead (ug/I)
Complex4
0.0
0.0
0.0
0.0
0.0
0.0 0.3
0.0
0.0
0.0
0.2
Zinc (ug/1)
Complex4
0.0
0.0
0.0
4.4
2.0
6.0 0.0
0.0
0.0
0.0
0.0
Fecal Coliform MPN/100 ml3
2004
230
20
240
700
3000
2400 3000
80
300
500
500
Total Coliform CFU/100 ml3
1000
800
80
800
3000
50000
5000 9000
800
2400
2400
5000
Total Suspended Solids (mg/l)
None4
5
3
2
2
N/A
8 3
N/A
N/A
4
4
Tributyltin (ug/1)
0.010
0.001
N/A
N/A
N/A
N/A
N/A N/A
N/A
N/A
N/A
N/A
Transparency (k-1)
0.7
N/A
N/A
N/A
N/A
N/A
N/A N/A
N/A
N/A
N/A
N/A
Notes: 'Measurements taken at 1 meter depth
Measurements taken at bottom
390% quant.
4Surface Water Quality Criteria (17-302.560) F.A.C. 1-5-93
AR = Aerojet Canal
MI = Military Canal
MR = Miami River
MW = Mowry Canal
LR = Little River Canal
PR = Princeton Canal
BL = Black Creek
BS = Biscayne Canal
CG = Coral Gables
SK = Snake Creek
TM = Tamiami Canal
N/A - Not Analyzed
-------
Ammonia
Nitrate/Nitrite
Coiliform Bacteria
Tributyltin
Transparency
Table 1-5
Water Quality Targets For Critical Parameters
Biscayne Bay SWIM Plan
1995
0.5 mg/1
0.05 mg/1 (total)
1000 cfu/100 ml
0.010 ug/1
0.7 average attenuation coefficient
-------
Sample Station Table 2-1
Note: All samples were analyzed for chemical parameters as folows: voc's,
pesticides/PCB's, extractable organics, herbicides, cyanide, metals, alkyl
substituted hydrocarbons, and organotin. At noted stations samples also were
analyzed for the additional parameters nutrients, psd, % organic fraction and
underwent toxicity testing. All samples were collected from 0-15 cm. (0-6")
unless otherwise noted.
Station
Date
Time
Add.
Parms.
Comments/Notes
SD-101
11/16/97
0940
X
SD-101R
11/19/97
1335
VOC sample for this station was re-
collected. Sample collected after BMW
hydrocarbon slick released near station
402 .
SD-102
11/13/97
1403
Sample collected in duplicate. Strong
sulfide odor noted by support boat crew.
No voc sample due to reaction of
preservative.
SD-102-DUP
11/13/97
1410
Sample collected in duplicate. No voc
sample due to reaction of preservative.
SD-103
11/13/97
1500
NoVOC sample due to reaction of
preservative.
SD-104
11/16/97
1002
X
SD-104R
11/19/97
1336
VOC sample for this station. Sulfide odor
noted by support boat crew. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-105
11/13/97
1555
VOC sample discarded due to reaction of
preservative.
SD-106
11/14/97
1602
VOC sample discarded due to reaction of
preservative. Sulfide odor noted by
support boat crew.
SD-107
11/16/97
1018
X
SD-107R
11/19/97
1337
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-108
11/14/97
1645
VOC sample discarded due to reaction of
preservative.
SD-109
11/15/97
0845
VOC sample discarded due to reaction of
preservative. No sulfide odor noted by
support boat crew.
SD-110
11/16/97
0800
X
VOC sample discarded due to reaction of
preservative. Strong sulfide odor noted by
support boat crew.
-------
SD-110-A
11/19/97
0920
This station was selected for a deep core
sample. The surface sediment sample was re-
collected. Sulfide odor noted by support
boat crew.
SD-110-B
11/19/97
0920
This is the deep core sample for this
station, collected as a duplicate. Sulfide
odor noted by support boat crew.
SD-110-BDP
11/19/97
0920
This is the deep core sample for this
station, collected as a duplicate. This
portion of the duplicate also underwent
testing for radiation.
SD-111
11/15/97
0825
VOC sample discarded due to reaction of
preservative.
SD-112
11/15/97
0900
VOC sample discarded due to reaction of
preservative. This sample was collected as
a duplicate. Very slight sulfide odor
noted by support boat crew.
SD-112-DUP
11/15/97
0920
VOC sample discarded due to reaction of
preservative. This sample was collected as
a duplicate. This portion of the duplicate
also underwent testing for radiation.
SD-113
11/15/97
0935
X
Sulfide odor noted by support boat crew.
SD-113-R
11/19/97
1138
VOC sample for this station.
SD-114
11/14/97
1205
VOC sample discarded due to reaction of
preservative. Moderate sulfide odor noted
by support boat crew.
SD-115
11/14/97
1130
VOC sample discarded due to reaction of
preservative. Strong sulfide odor noted by
support boat crew.
SD-116
11/15/97
1000
X
SD-116-R
11/19/97
1139
VOC sample for this station.
SD-117
11/15/97
0947
VOC sample discarded due to reaction of
preservative. Strong sulfide odor noted by
support boat crew.
SD-118
11/15/97
1110
VOC sample discarded due to reaction of
preservative. Strong sulfide odor noted by
support boat crew.
SD-119
11/15/97
1545
X
VOC sample discarded due to reaction of
preservative. No voc sample for this
station. Strong sulfide odor noted by
support boat crew.
SD-120
11/15/97
1405
VOC sample discarded due to reaction of
preservative. Sulfide odor noted by
support boat crew.
-------
SD-120-A
11/19/97
1000
This station was selected for a deep core
sample. The surface sediment sample was re-
collected. Sulfide odor noted by support
boat crew. Sample depth was approximately
0" to 12".
SD-120-B
11/19/97
1000
This is the deep core sample for this
station. Sulfide odor noted by support
boat crew.
SD-121
11/15/97
1335
VOC sample discarded due to reaction of
preservative. Little odor (sulfide?) noted
by support boat crew.
SD-122
11/15/97
1600
X
Sulfide odor noted by support boat crew.
SD-122-R
11/19/97
1341
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 4 02.
SD-123
11/15/97
1333
Sample collected as a duplicate. Very
light sulfide odor noted by support crew.
SD-123-DUP
11/15/97
1335
Sample collected as a duplicate. This
portion of the sample also underwent
testing for radiation.
SD-124
11/15/97
1433
Very light sulfide odor noted by support
boat crew.
SD-125
11/15/97
1525
X
Light sulfide odor noted by support boat
crew.
SD-125-R
11/19/97
1342
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-126
11/15/97
1600
Large trees on station. Moderate sulfide
odor noted by supported boat crew.
SD-127
11/15/97
1628
SD-128
11/16/97
0910
X
Strong odor (sulfide?) noted by support
boat crew.
SD-128-R
11/19/97
1343
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402. _
SD-202
11/14/97
1130
X
Filamentous algae. _
SD-202-R
11/19/97
1320
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402. .
SD-203
11/13/97
1510
VOC sample discarded due to reaction of
preservative. Dive boat crew noted
odor at bottom of core.
-------
SD-2 04
11/13/97
1602
VOC sample discarded due to reaction of
preservative. Dive boat crew noted no
sulfide odor.
SD-205
11/14/97
1620
X
This sample was re-collected the following
day because of concerns over the use of the
stainless steel mixing bowl. However, this
sample was used for the toxicity testing
and is therefore left in the data set.
SD-205
11/15/97
0950
X
Large brush and limbs on station,
filamentous algae.
SD-205-R
11/19/97
1330
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-206
11/14/97
1005
VOC sample discarded due to reaction of
preservative. Sample collected as a
duplicate. Numerous brush and limbs,
filamentous algae. Sample collected by
scooping with 32 oz. sample jar because
sediment thickness was not adequate for
vertical penetration. 4' alligator noted at
this station at 0940 on 11/13/97.
SD-206-DUP
11/14/97
1010
VOC sample discarded due to reaction of
preservative. Sample collected as a
duplicate. This portion of the sample also
underwent testing for radiation.
SD-207
11/14/97
1225
VOC sample discarded due to reaction of
preservative. Much brush and limbs,
filamentous algae noted.
SD-208
11/15/97
1515
X
SD-208-R
11/19/97
1345
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-209
11/15/97
1025
VOC sample discarded due to reaction of
preservative. Debris and limbs noted, also
filamentous algae.
SD-209-DUP
11/15/97
1040
VOC sample discarded due to reaction of
preservative.
SD-210
11/15/97
1320
VOC sample discarded due to reaction of
preservative.
SD-211
11/15/97
1332
X
SD-211-R
11/19/97
1340
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
-------
SD-211-A
11/19/97 1400
SD-211-B
11/19/97 1405
SD-211-RB 11/19/97 1345
SD-212
SD-213
11/15/97 1350
11/15/97 1318
SD-214
11/15/97 | 1345 | X
SD-214-R I 11/19/97 I 1421
SD-215
11/15/97 1415
SD-215-DUP 11/15/97 j 1420
SD-216 11/15/97 | 1450
SD-217
SD-217-R
SD-218
SD-219
11/15/97 1519
11/19/97 1426
11/15/97 1555
11/15/97 1620
SD-220
SD-220-R
SD-221
SD-222
SD-301
This station was selected for a deep core
sample. The surface sediment sample was re-
collected. Sample collected after BMW
hydrocarbon slick released near station
402.
Deep core sample for this station. The voc
sample for this station was mis-labeled SD-
211-RB. Sample collected after BMW
hydrocarbon slick released near station
402.
VOC sample for the deep core collected at
this station. Sample collected after BMW
hydrocarbon slick released near station
402.
VOC sample discarded due to reaction of
preservative.
Discharge culvert (abandoned?) noted near
station. Sparse woody debris.
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 402
Sample collected as a duplicate. Woody
debris.
Sample collected as a duplicate.
Wood debris.
Woody debris.
VOC's re-sampled for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
Mats of algae, variable depth.
Algae mat covered with silt. Bottom has
jelly-like consistency. Dive boat crew
noted a sulfide odor.
11/15/97 1645 | X
11/19/97 1422
11/16/97 0945
11/16/97 1025
11/16/97 1050 | X
Debris.
VOC's re-sampled for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
Thin layer of filamentous algae.
Woody debris, lots of leaf litter.
Wood debris.
-------
SD-301-R
11/19/97
1437
VOC's re-sampled for this station. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-302
11/16/97
1125
Sample collected as a duplicate. Small
debris.
SD-302-DUP
11/16/97
1130
Sample collected as a duplicate. This
portion of the sample also underwent
testing for radioactivity.
SD-303
11/16/97
1200
VOC sample discarded. Dense layer of algae
covered with silt plus a lot of debris from
bridge (cans, bottles, etc.)
SD-304
11/16/97
1220
X
SD-3 04-R
11/19/97
1443
VOC's re-sampled for this station. Sample
collected after BMW hydrocarbon slick
released near station 4 02.
SD-401
11/16/97
1255
X
SD-401-R
11/19/97
1449
VOC's re-sampled for this station Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-402
11/16/97
1315
VOC sample discarded. BMW on station.
Black oily substance that smeared tube
noted at 15 cm. BMW removed at
approximately 1200 on 11/19/97.
SD-403
11/16/97
1344
VOC sample discarded. Sample collected as
a duplicate. Sediment thickness patchy,
woody debris and large trees noted.
SD-403-DUP
11/16/97
1350
VOC sample discarded. Sample collected as
a duplicate. This portion of the sample
also underwent testing for radiation.
SD-404
11/16/97
1500
X
Silty debris, large tree.
SD-404-R
11/19/97
1453
VOC sample for this station. Sample
collected after BMW hydrocarbon slick
released near station 4 02.
SD-405
11/16/97
1520
VOC sample discarded.
SD-406
11/16/97
1535
VOC sample discarded.
SD-407
11/18/97
0900
X
Thick algal mat beneath layer of flocculent
material. Large wood debris beneath silt.
SD-408
11/18/97
0923
SD-409
11/18/97
0955
SD-410
11/18/97
1020
X
Exposed rock, thick algal mat with silt and
woody debris.
-------
SD-411
11/18/97 1050
Shallow sediment deposits.
SD-412
11/18/97 1115
SD-413
11/18/97 1145
Smear on outside of core at 13 15 cm.
SD-414
SD-415
SD-416
SD-417
11/18/97 1235
Erroneous time of 1301 on chain-of-custody
sheet. Bottom sediment thickness is
patchy.
11/18/97 1301
Deep black oily smear along inside edge of
tube. Divers glove coated with black
substance that felt like used diesel oil.
11/18/97 1320
X
4"-6" of woody debris.
11/18/97 1345
Sample collected as a duplicate.
SD-417-DUP 11/18/97 1350
SB-418
SD-419
SD-420
SD-421
SD-422
SD-423
SD-424
SD-425
Sample collected as a duplicate. This
portion of the sample also underwent
testing for radiation.
11/18/97 1403
Flocculent material on top of aquatic
plants.
11/18/97 1427
11/18/97 1447
Small woody debris, leaf litter
11/18/97 1520
11/18/97 I 1547 1 X
Very little sediment, located in deposits
[Very patchy, with twigs, woody debris.
Much algae.
11/18/97 1615
11/19/97 0917
Organic debris.
11/19/97 I 0925 X
Organic debris, old boat, asphalt shingles,
thick algal mat, treeB, woody debris.
SD-503-A
SD-503-B
SD-601
SD-602
11/19/97 1115 X
This station was selected for a deep core
sample. Thick algal mat.
11/19/97 1115
Deep core sample for this station.
1/18/97 0845
Mud odor noted by support boat crew.
11/18/97 0908
Slight sulfide odor noted by support boat
crew.
SD-603
11/18/97 0931
Slight sulfide odor noted by support boat
crew.
SD-604
11/18/97 0955
Sulfide odor noted by support boat crew.
SD-605
11/18/97 1020
Sample collected as a duplicate. Sulfide
odor noted by support boat crew.
-------
SD-605-DUP
11/18/97
1025
Sample collected as a duplicate. This
portion of the duplicate sample also •
underwent testing for radiation.
SD-606
11/18/97
1148
Sulfide odor noted by support boat crew.
SD-607
11/18/97
1302
X
Sulfide odor noted by support boat crew.
SD-608
11/18/97
1326
Very light sulfide odor noted by support
boat crew.
SD-609
11/18/97
1434
Slight sulfide odor noted by support boat
crew.
SD-610
11/18/97
1500
X
Sulfide odor noted by support boat crew.
SD-701
11/19/97
1620
Sulfide odor noted by support boat crew.
Sample collected after BMW hydrocarbon
slick released near station 402.
SD-702
11/19/97
1622
X
Sulfide odor noted by support boat crew.
Sample collected after BMW hydrocarbon
slick released near station 402.
SD-703
11/19/97
1625
Sample collected as a duplicate. Sulfide
odor noted by support boat crew. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-703-DUP
11/19/97
1625
Sample collected as a duplicate. This
portion of the sample also underwent
testing for radiation.
SD-801
11/19/97
1410
Sample collected as a duplicate. Sulfide
odor noted" by support boat crew. Sample
collected after BMW hydrocarbon slick
released near station 402.
SD-801-DUP
11/19/97
1410
Sample collected as a duplicate. This
portion of the sample also underwent
testing for radiation.
SD-802
11/19/97
1445
X
Sulfide odor noted by support boat crew.
Sample collected after BMW hydrocarbon
slick released near station 402.
SD-803
11/19/97
1516
Sample collected after BMW hydrocarbon
slick released near station 402.
-------
Table 3-1
Summary of Field QA Samples
Military Canal Special Stud
Homestead Air Force Base
November, 1997
y
Sample ID
Date
Time
Type of Sample
Comments/Notes
QA-900
11/13/97
0945
Milli-Q System
VOC aliquot not analyzed
QA-901
11/14/97
1500
Trip Blank'
Sample not analyzed
QA-902
11/15/97
1230
Trip Blank
Sample not analyzed
QA-903
11/15/97
1235
Pres. Blank
VOC aliquot not analyzed
QA-904
11/15/97
1245
Rinse Blank
VOC aliquot not analyzed
QA-905
11/15/97
1645
Trip Blank
VOC aliquot not analyzed
QA-906
11/17/97
1055
Trip Blank
QA-907
11/18/97
1045
Trip Blank
QA-908
11/18/97
1158
Field Trip Blank
Field prepared trip blank
QA-909
11/18/97
1235
Field Trip Blank
Field prepared trip blank
QA-910
11/18/97
1240
Field Trip Blank
Field prepared trip blank
QA-911
11/18/97
1215
Rinse Blank
QA-912
11/18/97
1600
Trip Blank
QA-913
11/19/97
1520
Trip Blank
QA-001-PB
1/30/98
1035
Pres. Blank
QA-001-TB
1/30/98
1020
Trip Blank
-------
Table 3-2
Quality Assurance Results
Military Canal Special Study
Homestead Air Force Base
November, 1997.
QA900
MILLI-Q
11/13/97
09:45
EXTRACTABLE ORGANIC COMPOUNDS
(METHYLETHYLIDENE)BISPHENOL
UG/L
10
JN
QA001PB
QA900
QA903
PRESERV
MILLI-Q
PRESERV
01/30/98
11/13/97
11/15/97
10:35
09:45
12:35
METALS
CALCIUM
MG/L
U
U
0.087
LEAD
UG/L
U
0.11
U
SODIUM
MG/L
1.2
U
0.47
ZINC
UG/L
1.2
1.5
U
QA906
QA908
QA911
QA913
VOCBLK
40MLBLK
RINSBLK
UNPRS TRIP
11/17/97
11/18/97
11/18/97
11/19/97
10:55
11:58
12:15
15:20
VOLATILE ORGANIC COMPOUNDS
(M- AND/OR P-)XYLENE
UG/L
u
U
U
0.64
J
1,4-DICHLOROBENZENE
UG/L
u
7
0.5
J
0.69
J
ACEJALDEHYDE
UG/L
U
NR
20
JN
NR
TOLUENE
UG/L
3.7
U
U
0.6
J
TRICHLOROFLUOROMETHANE
UG/L
0.55
J
U
u
u
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected.
-------
Table 3-3
Quality Assurance Results - Cyanide
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA001PB
PRESERV
01/30/98
10:35
CYANIDE UG/L
Data Qualifiers
2 U
QA900
MILLI-Q
11/13/97
09:45
4 U
QA903
PRESERV
11/15/97
12:35
4 U
QA904
RINS BLK
11/15/97
12:45
4 U
QA911
RINS BLK
11/18/97
12:15
2 U
U-Material was analyzed for but not detected.
-------
Table 3-4
Quality Assurance Results - Extractables
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA900
QA904
QA911
MILLI-Q
RINS BLK
RINS BLK
11/13/97
11/15/97
11/18/97
09:45
12:45
12:15
(3-AND/OR 4-)METHYLPHENOL
UG/L
2
U
2
U
2
U
(METHYLETHYLIDENE)BISPHENOL
UG/L
10
JN
NR
NR
1,2,4-TRICHLOROBENZENE
UG/L
2
U
2
U
2
U
2,3,4,6-TETRACHLOROPHENOL
UG/L
2
u
2
U
2
U
2,4,5-TRICHLOROPHENOL
UG/L
2
u
2
U
2
U
2,4,6-TRICHLOROPHENOL
UG/L
2
u
2
U
2
u
2,4-DICHLOROPHENOL
UG/L
2
u
2
u
2
u
2,4-DIMETHYLPHENOL
UG/L
2
u
2
u
2
u
2,4-DINITROPHENOL
UG/L
4
u
4
u
4
u
2,4-DINITROTOLUENE
UG/L
2
u
2
u
2
u
2,6-DINITROTOLUENE
UG/L
2
u
2
u
2
u
2-CHLORONAPHTHALENE
UG/L
2
u
2
u
2
u
2-CHLOROPHENOL
UG/L
2
u
2
u
2
u
2-METHYL-4,6-DINITROPHENOL
UG/L
4
u
4
u
4
u
2-METHYLNAPHTHALENE
UG/L
2
u
2
u
2
u
2-METHYLPHENOL
UG/L
2
u
2
u
2
u
2-NITROANILINE
UG/L
2
u
2
u
2
u
2-NITROPHENOL
UG/L
2
u
2
u
2
u
3,3'-DICHLOROBENZIDINE
UG/L
2
u
2
u
2
u
3-NITROANILINE
UG/L
2
u
2
u
2
u
4-JBOMOPHENYL PHENYL ETHER
UG/L
2
u
2
u
2
u
4-CHLORO-3-METHYLPHENOL
UG/L
2
u
2
u
2
u
4-CHLOROANILINE
UG/L
2
u
2
u
2
u
4-CHLOROPHENYL PHENYL ETHER
UG/L
2
u
2
u
2
u
4-NITROANILINE
UG/L
2
u
2
u
2
u
4-NITROPHENOL
UG/L
4
u
4
u
4
u
ACENAPHTHENE
UG/L
2
u
2
u
2
u
ACENAPHTHYLENE
UG/L
2
u
2
u
2
u
ANTHRACENE
UG/L
2
u
2
u
2
u
BENZO(A)ANTHRACENE
UG/L
2
u
2
u
2
u
BENZO(B)FLUORANTHENE
UG/L
2
u
2
u
2
u
BENZO(GHI)PERYLENE
UG/L
2
u
2
u
2
u
BENZO(K)FLUORANTHENE
UG/L
2
u
2
u
2
u
BENZO-A-PYRENE
UG/L
2
u
2
u
2
u
BENZYL BUTYL PHTHALATE
UG/L
2
u
2
u
2
u
BIS(2-CHLOROETHOXY)METHANE
UG/L
2
u
2
u
2
u
BIS(2-CHLOROETHYL) ETHER
UG/L
2
u
2
u
2
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/L
2
u
2
u
2
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/L
2
u
2
u
2
u
CI CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
CI FLUORANTHENES/PYRENES
UG/L
2
UJ
2
UJ
2
UJ
CI FLUORENES
UG/L
2
UJ
2
UJ
2
UJ
CI NAPHTHALENES
UG/L
2
UJ
2
UJ
2
UJ
CI PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C2 FLUORENES
UG/L
2
UJ
2
UJ
2
UJ
C2 NAPHTHALENES
UG/L
2
UJ
2
UJ
2
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C3 FLUORENES
UG/L
2
UJ
2
UJ
2
UJ
-------
Table 3-4 (Continued)
Quality Assurance Results - Extractables
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA900
QA904
QA911
MILLI-Q
RINS BLK
RINS BLK
11/13/97
11/15/97
11/18/97
09:45
12:45
12:15
C3 NAPHTHALENES
UG/L
2
UJ
2
UJ
2
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
C4 NAPHTHALENES
UG/L
2
UJ
2
UJ
2
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
2
UJ
CARBAZOLE
UG/L
2
u
2
U
2
u
CHRYSENE
UG/L
2
u
2
U
2
u
FLUORANTHENE
UG/L
2
u
2
U
2
u
FLUORENE
UG/L
2
u
2
U
2
u
HEXACHLOROBENZENE (HCB)
UG/L
2
u
2
u
2
u
HEXACHLOROBUTADIENE
UG/L
2
u
2
U
2
u
HEXACHLOROCY CLOPENTADIENE (HCCP)
UG/L
2
u
2
U
2
u
HEXACHLOROETHANE
UG/L
2
u
2
U
2
u
INDENO (1,2,3-CD) PYRENE
UG/L
2
u
2
u
2
u
ISOPHORONE
UG/L
2
u
2
U
2
u
N-NITROSODI-N-PROPYLAMINE
UG/L
2
u
2
u
2
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/L
2
u
2
u
2
u
NAPHTHALENE
UG/L
2
u
2
u
2
u
NITROBENZENE
UG/L
2
u
2
u
2
u
PENTACHLOROPHENOL
UG/L
4
u
4
u
4
u
PHENANTHRENE
UG/L
2
u
2
u
2
u
PHENOL
UG/L
2
u
2
u
2
u
PYRENE
UG/L
2
u
2
u
2
u
Data Qualifiers
J-Estimated value.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 3-5
Quality Assurance Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA001PB
QA900
QA903
QA904
QA911
PRESERV
MILLI-Q
PRESERV
RINS BLK
RINS BLK
01/30/98
11/13/97
11/15/97
11/15/97
11/18/97
10:35
09:45
12:35
12:45
12:15
ALUMINUM
UG/L
10
U
10
U
10
U
10
U
10
u
ANTIMONY
UG/L
0.1
U
0.5
U
0.5
U
0.5
U
0.5
u
ARSENIC
UG/L
5
U
0.5
U
0.5
u
0.5
U
0.5
u
BARIUM
UG/L
0.5
U
0.5
U
0.5
u
0.5
u
0.5
u
BERYLLIUM
UG/L
0.1
U
0.1
U
0.1
u
0.1
u
0.1
u
BORON
UG/L
NA
10
U
10
u
10
u
10
u
CADMIUM
UG/L
0.1
U
0.1
U
0.1
u
0.1
u
0.1
u
CALCIUM
MG/L
0.5
U
0.01
u
0.087
0.01
u
0.01
u
CHROMIUM
UG/L
3
u
0.5
u
0.5
u
0.5
u
0.5
u
COBALT
UG/L
0.5
u
0.5
u
0.5
u
0.5
u
0.5
u
COPPER
UG/L
1
u
0.5
u
0.5
u
0.5
u
0.5
u
IRON
MG/L
0.05
u
0.01
u
0.01
u
0.01
u
0.01
u
LEAD
UG/L
0.1
u
0.11
0.1
u
0.1
u
9.1
u
MAGNESIUM
MG/L
0.1
u
0.01
u
0.01
u
0.01
u
0.01
u
MANGANESE
UG/L
0.5
u
0.5
u
0.5
u
0.5
u
0.5
u
MOLYBDENUM
UG/L
0.5
u
0.5
u
0.5
u
0.5
u
0.5
u
NICKEL
UG/L
1
u
0.5
u
0.5
u
0.5
u
0.5
u
POTASSIUM
MG/L
2
u
0.01
u
0.01
u
0.01
u
0.01
u
SELENIUM
UG/L
5
u
0.5
u
0.5
u
0.5
u
0.5
u
SILVER
UG/L
0.1
u
0.1
u
0.1
u
0.1
u
0.1
u
SODIUM
MG/L
1.2
0.01
u
0.47
0.01
u
0.01
u
STRONTIUM
UG/L
10
u
0.5
u
0.5
u
0.5
u
0.5
y
TELLURIUM
UG/L
50
u
OJ
u
0.5
u
0.5
u
0.5
u
THALLIUM
UG/L
0.1
u
0.1
u
0.1
u
0.1
u
0.1
u
TIN
UG/L
0.5
u
0.5
u
0.5
u
0.5
u
0.5
u
TITANIUM
UG/L
1
u
0.5
u
0.5
u
0.5
u
0.5
u
TOTAL MERCURY
UG/L
0.002
u
0.2
u
0.2
u
0.2
u
0.2
u
URANIUM, TOTAL METAL
UG/L
0.1
u
NR
0.5
NR
NR
NR
VANADIUM
UG/L
1
u
0.5
u
u
0.5
u
0.5
U
YTTRIUM
UG/L
0.5
u
0.5
u
0.5
u
0.5
u
0.5
U
ZINC
UG/L
1.2
1.5
0.5
u
0.5
u
0.5
U
ZIRCONIUM
UG/L
NA
0.5
u
0.5
u
0.5
u
0.5
U
Data Qualifiers
NA-Not analyzed.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit
-------
Table 3-6
Quality Assurance Results - Pesticides/PCBs
Homestead Air Force Base
Military Canal Special Study
November, 1997
QA900 QA904 QA911
MILLI-Q RINS BLK RINS BLK
11/13/97 11/15/97 11/18/97
09:45 12:45 12:15
1 -HYDROXYCHLORDENE /2
4,4'-DDD (P.F-DDD)
4,4'-DDE (PJP'-DDE)
4,4'-DDT (P.F-DDT)
ALDRIN
ALPHA-BHC
ALPHA-CHLORDANE 12
ALPHA-CHLORDENE /2
BETA-BHC
BETA-CHLORDENE 12
CHLORDANE (TECH. MIXTURE) /I
CHLORDENE 12
CIS-NONACHLOR 12
DELTA-BHC
DIELDRIN
ENDOSULFANI (ALPHA)
ENDOSULFANII (BETA)
ENDOSULFAN SULFATE
ENDRIN
ENDRIN KETONE
GAMMA-BHC (LINDANE)
GAMMA-CHLORDANE 12
GAMMA-CHLORDENE 11
HEPTACHLOR
HEPTACHLOR EPOXIDE
METHOXYCHLOR
OXYCHLORDANE (OCTACHLOREPOXIDE) /2
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
TOXAPHENE
TRANS-NONACHLOR /2
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
0.054 U
0.031 U
0.054 U
0.023 U
0.023 U
0.023 U
0.13 U
0.054 U
0.026 U
0.054 U
0.026 U
0.026 U
0.026 U
0.13 U
0.052 U
0.024 U
0.052 U
0.024 U
0.024 U
0.024 U
0.13 U
0.023
U
0.026
U
0.024
U
0.028
U
0.026
u
0.024
U
0.023
u
0.026
U
0.024
U
0.054
u
0.054
U
0.052
u
0.054
u
0.054
U
0.052
u
0.054
u
0.054
U
0.052
U
0.054
u
0.054
U
0.052
u
0.023
u
0.026
u
0.024
u
0.023
U
0.026
U
0.024
U
0.023
U
0.026
U
0.024
U
0.1
u
0.1
U
0.1
U
0.27
u
0.27
u
0.26
U
0.27
u
0.27
u
0.26
U
0.27
u
0.27
U
0.26
U
0.27
u
0.27
u
0.26
U
0.27
u
0.27
u
0.26
u
0.27
u
0.27
u
0.26
u
0.27
u
0.27
U
0.26
U
2
u
2
U
2
U
Data Qualifiers
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1 When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
, Table 3-7
lity Assurance Results - Volatiles
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA001TB
QA900
QA901
QA902
QA904
QA905
TRIP
MILLI-Q
TRIP
TRIP
RINS BLK
BOTTBLK
01/30/98
11/13/97
11/14/97
11/15/97
11/15/97
11/15/97
10:20
09:45
15:00
12:30
12:45
16:45
(M- ANCHOR P-)XYLENE
UG/L
1
U
NA
NA
NA
NA
NA
1,1,1 ,2-TETRACHLOROBTH ANE
UG/L
1
U
NA
NA
NA
NA
NA
1,1,1-TRIGHLOROETHANE
UG/L
1
U
NA
NA
NA
NA
NA
1,1,2,2-TBTRACHLOROETHANE
UG/L
1
U
NA
NA
NA
NA
NA
1,1,2-TRICHLOROETI 1ANE
UG/L
1
U
NA
NA
NA
NA
NA
1,1 -DICHLOROETH ANE
UG/L
1
u
NA
NA
NA
NA
NA
1,1 -DICHLOROETHENE (1,1 -DICHLOROETH YLENE)
UG/L
1
u
NA
NA
NA
NA
NA
1,1-BICHLOROPROPENE
UG/L
1
u
NA
NA
NA
NA
NA
1,2,3-TRICHLOROBENZENE
UG/L
1
u
NA
NA
1AMTUCHLOROPROPANE
UG/L
1
u
NA
NA
NA
NA
NA
H&4-TRICHLOROBENZENE
UG/L
1
u
NA
NA
NA
NA
NA
1i2,4»TRIMETHYLBENZENE
UG/L
1
u
NA
NA
NA
NA
NA
4HNnKtCM«0-3-CHLOROPRDPANB (DBCP)
UG/L
1
u
NA
NA
NA
NA
NA
M-DiWtOMQETHANE (EDB^
UG/L
1
u
NA
NA
NA
NA
NA
S^-D(CHLORDBENZENE
UG/L
1
u
NA
NA
NA
NA
NA
^EBCHlJOROBTHANE
UG/L
1
u
NA
NA
NA
NA
NA
*2j8ICHW?WOPROPANE
UG/L
1
u
NA
NA
NA
NA
NA
J .34-TRB14BTH YLHfiNZSS#
UG/L
1
u
NA
NA
NA
NA
NA
13-DKm,QftOBENZBNE
UG/L
1
u
NA
NA
NA
NA
NA
13-MCHL^OPROPANE
UG/L
1
u
NA
NA
NA
NA
NA
i^ICBLORQBBNZENE
UG/L
1
u
NA
NA
NA
NA
NA
3JHMCHLOROPR0PANE
UG/L
1
u
NA
NA
NA
NA
NA
ACBTALDBHYDE
UG/L
NR
NR
NR
NR
NR
NR
ACETONE
UG/L
25
u
NA
NA
NA
NA
NA
80N2ENB
UG/L
1
u
NA
NA
NA
NA
NA
BROMOBENZENE
UG/L
1
u
NA
NA
NA
NA
NA
BRQMOCHLOROMETHANE
UG/L
1
u
NA
NA
NA
NA
NA
BROMODICHLOROMETHASE
UG/L
1
u
NA
NA
NA
NA
NA
pROMOTORM
UG/L
1
u
NA
NA
NA
NA
NA
1RQMOMETHANE
UG/L
1
u
NA
NA
NA
NA
NA
CARBON DISULFIDE
UG/L
2.5
u
NA
NA
NA
NA
NA
CARBON TETRACHLORIDE
UG/L
I
u
NA
NA
NA
NA
NA
CHLOROBBNZENE
UG/L
1
u
NA
NA
NA
NA
NA
CHLORCSffHANE
UG/L
1
u
NA
NA
NA
NA
NA
-------
CHLOROFORM UG/L
CHLOROMETHANB UG/L
CIS-1,2-DICHLOROETHENE UG/L
CIS-1,3-DICHLOROPROPENE UG/L
DIBROMOCHLOROMETHANE UG/L
DIBROMOMETHANE UG/L
ETHYL BENZENE UG/L
HEX ACHLORO-1,3-BUTADIENE UG/L
ISOPROPYLBENZENE UG/L
METHYL BUTYL KETONE UG/L
METHYL ETHYL KETONE UG/L
METHYL ISOBUTYL KETONE UG/L
METHYLENE CHLORIDE UG/L
N-BUTYLBENZENE UG/L
N-PROPYLBENZENE UG/L
O-CHLOROTOLUENE UG/L
O-XYLBNE UG/L
P-CHLOROTOLUENE UG/L
P-ISOPROPYLTOLUENE UG/L
PETROLEUM PRODUCT UG/L
SEC-BUTYLBENZENE UG/L
STYRENE UG/L
TERT-BUTYLBENZENE UG/L
TETRACHLOROETHENE (TETRACHLOROETHYLENE) UG/L
TOLUENE UG/L
TRANS-1,2-DICHLOROETHENE UG/L
TRANS-1,3-DICHLOROPROPENE UG/L
TRICHLOROETHENE (TRICHLOROETHYLENE) UG/L
TRICHLOROFLUOROMETHANE UG/L
VINYL CHLORIDE UG/L
Table 3-7 (Continued)
Quality Assurance Results - Volatiles
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA001TB
TRIP
01/30/98
10:20
QA900
MILLI-Q
11/13/97
09:45
QA901
TRIP
11/14/97
15:00
QA902
TRIP
11/15/97
12:30
QA904
RINS BLK
11/15/97
12:45
QA905
BOTT BLK
11/15/97
16:45
1
U
NA
NA
NA
NA
NA
1
U
NA
NA
NA
NA
NA
1
U
NA
NA
NA
NA
NA
1
U
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
2.5
u
NA
NA
NA
NA
NA
25
u
NA
NA
NA
NA
NA
2.5
u
NA
NA
NA
NA
NA
5
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
NR
NR
NR
NR
NR
NR
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
1
u
NA
NA
NA
NA
NA
I
u
NA
NA
NA
NA
NA
I
u
NA
NA
NA
NA
NA
I
u
NA
NA
NA
NA
NA
-------
(M- AND/OR P-)XYLENE
1,1,1,2-TETRACHLOROETH ANE
1,1,1-TMCHLOROETHANE
1,1,2,2-TETRACHLOROETH ANE
1, 1,2-TRICHLOROETH ANE
1,1 -DICHLOROETH ANE
1,1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1,1 -MCHLOROPROPENE
1,2,3-TRICHLOROBENZENE
1,2,3-TRICHLOROPROP ANE
lA'MKICHLOROBENZENE
T,2,4-TRIMBTHYLBENZENE
UMMBROMO-3-CHLOROPRQPANE (DBCP)
t^niftRflMOBTHANE (EDB)
[J DICHtOROBENZENE
t.3 D1CHLQRQETHANE
W-DICHWIH3PROPANE
1,3,5-tRIMBTHYLBBNZBNE
1,3-DlCHLOROBENZENE
1.3-DICHLOROPROPANE
1.4-DICHLOROBENZENE
&2-DICHLOROPROPANE
JfCBTALDEHYDE
ACETONE
BENZENE
BROMOBENZENE
BROMOCHLOROMETHANE
BROMODICHLOROMETHANfi
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBINZENE
CHLOROgHaANE
(Table 3-7 (Continued)
Quality Assurance Results - Volatiles
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA906
QA907
QA908
QA909
QA910
QA911
VOCBLK
BOTTBLK
40MLBLK
40ML BLK
40ML BLK
RINS BLK
11/17/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
10:55
10:45
11:58
12:35
12:40
12:15
UG/L
2
U
2
U
2
U
2
U
2
u
2
U
UG/L
2
U
2
U
2
U
2
U
2
u
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/I.
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
u
2
U
UG/L
2
U
2
U
2
U
2
u
2
u
2
U
UG/L
2
U
2
U
2
U
2
u
2
u
2
U
UG/L
2
U
2
U
2
U
2
u
2
u
2
U
UG/L
2
U
2
U
2
U
2
u
2
u
2
u
UG/L
2
U
2
U
2
U
2
u
2
u
2
u
UG/L
2
U
2
U
2
U
2
u
2
u
2
u
UG/L
2
U
2
U
2
U
2
u
2
u
2
u
UG/L
2
U
2
u
2
U
2
u
2
u
2
u
UG/L
2
U
2
u
7
2
u
2
u
0.5
J
UG/L
2
U
2
u
2
U
2
u
2
u
2
u
UG/L
NR
NR
NR
NR
NR
20
JN
UG/L
100
U
100
U
100
U
50
U
100
U
50
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
U
2
U
2
U
2
U
UG/L
2
U
2
U
2
u
2
u
2
U
2
u
UG/L
2
U
2
U
2
u
2
u
2
U
2
u
UG/L
2
U
2
U
2
u
2
u
2
U
2
u
UG/L
2
U
2
U
2
u
2
u
2
U
2
u
UG/L
5
u
5
U
5
u
5
u
5
U
5
u
UG/L
2
u
2
U
2
u
2
u
2
U
2
u
UG/L
2
u
2
u
2
u
2
u
2
U
2
u
UG/L
2
u
2
u
2
u
2
u
2
U
2
u
-------
Table 3-7 (Continued)
Quality Assurance Results - Volatiles
Military Canal Special Study
Homestead Air Force Base
November, 1997
QA912
QA913
VOC BLK
UNPRS BLK
11/18/97
11/19/97
16:00
15:20
CHLOROFORM
UG/L
2
U
2
U
CHLOROMETHANE
UG/L
2
U
2
U
CIS-1.2-DICHLOROETHENE
UG/L
2
U
2
U
CIS-1.3-DICHLOROPROPENE
UG/L
2
U
2
U
DIBROMOCHLOROMETHANE
UG/L
2
U
2
U
DIBROMOMETHANE
UG/L
2
u
2
U
ETHYL BENZENE
UG/L
2
u
2
U
HEXACHLORO-1.3-BUTADIENE
UG/L
2
u
2
U
ISOPROPYLBENZENE
UG/L
2
u
2
U
METHYL BUTYL KETONE
UG/L
5
u
5
U
METHYL ETHYL KETONE
UG/L
50
u
50
U
METHYL ISOBUTYL KETONE
UG/L
5
u
5
U
METHYLENE CHLORIDE
UG/L
10
u
10
u
N-BUTYLBENZENE
UG/L
2
u
2
u
N-PROPYLBENZENE
UG/L
2
u
2
u
O-CHLOROTOLUENE
UG/L
2
u
2
u
O-XYLENE
UG/L
2
u
2
u
P-CHLOROTOLUENE
UG/L
2
u
2
u
P-ISOPROPYLTOLUENE
UG/L
2
u
2
u
PETROLEUM PRODUCT
UG/L
NR
NR
SEC-BUTYLBENZENE
UG/L
2
U
2
U
STYRENE
UG/L
2
U
2
U
TERT-BUTYLBENZENE
UG/L
2
u
2
U
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
UG/L
2
u
2
U
TOLUENE
UG/L
2
u
0.6
J
TRANS-1,2-DICH LOROETH EN E
UG/L
2
u
2
U
TRANS-1,3-DICHLOROPROPENE
UG/L
2
u
2
U
TRICH LOROETH ENE(TRICHLOROETHYLENE)
UG/L
2
u
2
u
TRICHLOROFLUOROMETHANE
UG/L
2
u
2
u
VINYL CHLORIDE
UG/L
2
u
2
u
Data Qualifiers
A-Average value. NA-Not analyzed. NAI-Interferences. J-Estimated value.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 3-8 (A)
Ogeechee Reference Sediment Data - Metals
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
% MOISTURE
ALUMINUM
ANTIMONY
ARSENIC
BARIUM
BERYLLIUM
BORON
CADMIUM
CALCIUM
CHROMIUM
COBALT
COPPER
IRON
LEAD
MAGNESIUM
MANGANESE
MOLYBDENUM
NICKEL
POTASSIUM
SELENIUM
SILVER
SODIUM
STRONTIUM
TELLURIUM
THALLIUM
TIN
TITANIUM
TOTAL MERCURY
VANADIUM
YTTRIUM
ZINC
ZIRCONIUM
Data Qualifiers
OGEE1
%
78
MG/KG
30000
MG/KG
0.1
U
MG/KG
5.1
MG/KG
140
MG/KG
1.4
MG/KG
NA
MG/KG
0.47
MG/KG
2900
MG/KG
35
MG/KG
14
MG/KG
9.5
MG/KG
20000
MG/KG
29
MG/KG
2100
MG/KG
580
MG/KG
0.5
U
MG/KG
11
MG/KG
850
MG/KG
0.6
MG/KG
0.1
U
MG/KG
400
MG/KG
34
MG/KG
15
U
MG/KG
0.34
MG/KG
2.5
U
MG/KG
180
MG/KG
0.12
MG/KG
46
MG/KG
16
MG/KG
74
MG/KG
NA
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 3-8 (B)
Ogeechee Reference Sediment Data - Pesticides/PCBs
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
OGEE1
% MOISTURE
1-HYDROXYCHLORDENE 12
4,4'-DDD (P.P'-DDD)
4,4'-DDE (P,P'-DDE)
4,4'-DDT (P,P'-DDT)
ALDRIN
ALPHA-BHC
ALPHA-CHLORDANE /2
ALPHA-CHLORDENE /2
BETA-BHC
BETA-CHLORDENE /2
CHLORDANE (TECH. MIXTURE) /1
CHLORDENE /2
CIS-NONACHLOR /2
DELTA-BHC
DIELDRIN
ENDOSULFAN I (ALPHA)
ENDOSULFAN II (BETA)
ENDOSULFAN SULFATE
ENDRIN
ENDRIN KETONE
GAMMA-BHC (LINDANE)
GAMMA-CHLORDANE /2
GAMMA-CHLORDENE /2
HEPTACHLOR
HEPTACHLOR EPOXIDE
METHOXYCHLOR
OXYCHLORDANE (OCTACHLOREPOXIDE) /2
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
TOXAPHENE
TRANS-NONACHLOR /2
%
69
UG/KG
UG/KG
7.1
U
UG/KG
1.2
J
UG/KG
7.1
U
UG/KG
3
U
UG/KG
3
U
UG/KG
UG/KG
UG/KG
3
U
UG/KG
UG/KG
15
U
UG/KG
UG/KG
UG/KG
3
U
UG/KG
3
U
UG/KG
3
U
UG/KG
7.1
U
UG/KG
19
U
UG/KG
7.1
U
UG/KG
6.9
U
UG/KG
3
U
UG/KG
UG/KG
UG/KG
3
U
UG/KG
3
U
UG/KG
19
U
UG/KG
UG/KG
37
U
UG/KG
37
U
UG/KG
37
U
UG/KG
37
U
UG/KG
37
U
UG/KG
37
U
UG/KG
37
u
UG/KG
300
u
UG/KG
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 3-8 (C)
Ogeechee Reference Sediment Data - Herbicides
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
2,4,5-T
2,4-D
DICAMBA
SILVEX (2,4,5-TP)
Data Qualifiers
OGEE1
UG/KG
10
U
UG/KG
15
U
UG/KG
10
U
UG/KG
10
U
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 3-8 (D)
Ogeechee Reference Sediment Data - Extractables
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRlCHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4.6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B) FLUORANTHEN E
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BlS(2-ETHYLHEXYL) PHTHALATE
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
OGEE1
%
68.7
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
390
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
390
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
U
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
390
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
14
J
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
280
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
u
UG/KG
200
' u
-------
Table 3-8 (D) (Continued)
Ogeechee Reference Sediment Data - Extractables
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
DIETHYL PHTHALATE
UG/KG
200
U
DIMETHYL PHTHALATE
UG/KG
200
U
FLUORANTHENE
UG/KG
14
J
FLUORENE
UG/KG
200
U
HEXACHLOROBENZENE (HCB)
UG/KG
200
U
HEXACHLOROBUTADIENE
UG/KG
200
U
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
200
U
HEXACHLOROETHANE
UG/KG
200
U
INDENO (1,2,3-CD) PYRENE
UG/KG
14
J
ISOPHORONE
UG/KG
200
U
N-NITROSODI-N-PROPYLAMINE
UG/KG
200
U
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
200
u
NAPHTHALENE
UG/KG
200
U
NITROBENZENE
UG/KG
200
U
PENTACHLOROPHENOL
UG/KG
390
U
PHENANTHRENE
UG/KG
200
U
PHENOL
UG/KG
200
U
PYRENE
UG/KG
10
J
C1 CHRYSENES/BENZANTHRACENES
UG/KG
200
UJ
C1 FLUORANTHENES/PYRENES
UG/KG
200
UJ
C1 FLUORENES
UG/KG
200
UJ
C1 NAPHTHALENES
UG/KG
200
UJ
C1 PHENANTHRENES/ANTHRACENES
UG/KG
200
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
200
UJ
C2 FLUORENES
UG/KG
200
UJ
C2 NAPHTHALENES
UG/KG
200
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
200
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
200
UJ
C3 FLUORENES
UG/KG
200
UJ
C3 NAPHTHALENES
UG/KG
200
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
200
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
200
UJ
C4 NAPHTHALENES
UG/KG
200
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
200
UJ
PETROLEUM PRODUCT
UG/KG
N
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 3-8 (E)
Ogeechee Reference Sediment Data - Nutrients
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
AMMONIA
NiTFlATE-NITRlTE NITROGEN
TOTAL KJELDAHL NITROGEN
TOTAL PHOSPHORUS
Data Qualifiers
A-Average value. J-Estimated value.
OGEE1
MG/KG 110 JA
MG/KG 91 A
MG/KG 5800 JA
MG/KG 830 A
-------
Table 3-8 (F)
Ogeechee Reference Sediment Data - Organotins
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
DIBUTYL TIN
MONOBUTYL TIN
TETRABUTYL TIN
TRIBUTYLTIN
Data Qualifiers
OGEE1
UG/KG
190
U
UG/KG
190
U
UG/KG
190
U
UG/KG
190
U
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 4.1
Sediment Profile Descriptions
Stations 601-803
Homestead Air Force Base, Florida
November, 1997
STA
urg. rioc
5Y5/3
only Man
5Y5/1
MAPI br
6/1
Man bv
7/1
Man bY
8/1
IUIAL
DEPTH
803
-14
14
802
-17
-14
31
801
-18
-7
-11
36
703
-8
8
702
-22
22
701
-23
23
610
-8
-13
-1
22
609
-12
-11
23
608
-3
-8
11
607
-4
-6
10
606
-3
-5
8
605
-13
-9
22
604
-9
-12
21
603
-10
-4
14
602
-6
-8
-4
18
601
-2
-16
-2
20
-------
Table 4.2
Sediment Profile Descriptions
Stations 401-505
Homestead Air Force Base, Florida
November, 1997
"ST7T
urg. hoc
5Y 4/2
biiiy snen
5Y4/2
sanaysiu
5Y3/2
bill bV
4/2
banoy sin
5y 4/2
biiiy Man
5Y5/1
Man bv
6/1
Man by
7/1
Man
5Y8/1
KOCK
Surface
IUIAL
DEPTH
UlStShte
Apart (Ft.)
uuffluiaiivG
Distance (Ft.)
505
-10
0
0
504
-10
55
55
503
-1
-15
-37
53
55
110
502
-10
111
221
501
-10
108
329
426
-10
111
440
425
-2
-6
-9
17
111
551
424
-3
-4
-8.5
15.5
53
604
423
-1
-14
-9
-11
35
111
715
422
-1
-8
-4
-19
32
111
826
421
-1
-9
10
111
937
420
-1
-8
-5
-1
15
108
1045
419
-2
-6
-6
-2
16
111
1156
418
-2
-4
-11
-5
-13
-2
37
55
1211
417
-1
-8
-10
-1
20
111
1322
416
-2
-19
-5
-1
27
55
1377
415
-4
-24
28
111
1488
414
-3
-16
-2
-6
27
108
1596
413
-2
-13
15
111
1707
412
-0.5
-17.5
18
111
1818
411
-1
-7
-7
-4
-2
21
108
1926
410
-1
-12
-1
14
55
1981
409
-2
-6
-9
-3
20
111
2092
408
-1
-5
-19
-3
28
111
2203
407
-1
-5
-23
-6
35
108
2311
406
-1
-18
-6
-11
36
111
2422
405
-1
-13
-9
-10
33
111
2533
404
-2
-13
-6
-4
25
79
2612
403
-2
-2
-11
-4
-6
25
85
2697
402
-0.5
-3.5
-10
-4
18
111
2808
401
-1
-15
-3
19
108
2916
-------
Table 4.3
Sediment Profile Descriptions
Stations 202-304
Homestead Air Force Base, Florida
November, 1997
"5T7T
urg. hoc
5Y4/2
siiry sneii
5Y3/2
sanoybin
5Y3/2
Sin bT
4/2
sanay sin
5y 4/2
sury Man
5Y5/1
Man bv
6/1
man ot
7/1
man ot
8/1
—IUIAL
DEPTH
uisiance
Apart
uumuiativs
Distance
304
-2
-14
-10
26
126
3042
303
-1
-28
29
82
3124
302
-4
-24
-13
-8
49
55
3179
301
-4
-9
-5
18
55
3234
222
-1
-9
-19
-6
35
174
3408
221
-1
-11
-4
-18
34
221
3629
220
-1
-9
-13
-17
40
274
3903
219
-1
-4
-37
-6
-3
51
274
4177
218
-1
-3
-18
-2
-3
27
221
4398
217
-1
-2
-13
-3
19
274
4672
216
-1
-5
-15
-6
27
219
4891
215
-18
-2
20
274
5165
214
-1
-15
-10
26
274
5439
213
-15
15
221
5660
212
-22
-8
-8
38
274
5934
211
-2
-12
-10
-14
-6
44
221
6155
210
0.5
-13
-17
29.5
274
6429
209
-24
-9
-16
49
274
6703
208
-3
-10
-12
-6
-4
35
219
6922
207
-2
-17
-2
21
277
7199
206
-1
-11
-20
-11
-12
55
274
7473
205
-0.5
-16.5
-15
32
227
7700
204
-15.3
15.25
221
7921
203
-6
-2
-1.5
-10.5
20
274
8195
202
-1
-7
I
-9
-3I
20
219
8414
-------
Table 4.4
Sediment Profile Descriptions
Stations 101-128
Homestead Air Force Base, Florida
November, 1997
5TA
snen 'iuy
4/3
urg. hmk
5Y3/2
blU bV
3/2
Sill b?
4/2
sanay bin
5y 4/2
biny Man
5Y5/1
Man bv
6/1
Man bv
7/1
Man b v
8/1
Man by
6/1
IUIAL
DEPTH
Ui§lSPIC5-
Apart (Ft.)
UUMUI£tlV6
Distance (Ft.)
128
-14
-11
25
230
8644
127
-15
-8
23
108
8752
126
-8
-9
17
111
8863
125
-24
-7
-15
-4
50
55
8918
124
-9
-4
-4
-3
-3
23
111
9029
123
-8
-6
-2
-3
19
108
9137
122
-2
-10
-5
-3
20
111
9248
121
-10
-14.5
24.5
55
9303
120
-13
-14
27
108
9411
119
-6
-9
-10
25
111
9522
118
-11
-2
-6
19
111
9633
117
-4
-4
-11
19
108
9741
116
-9
-9
-22
-5
45
82
9823
115
-9
-5
-9
23
111
9934
114
-4
-8
12
126
10060
113
-6
-6
12
124
10184
112
-10
-12
22
111
10295
111
-11
-15
26
55
10350
110
-12
-14
26
111
10461
109
-8
-8
-4
20
108
10569
108
-11
-13
24
111
10680
107
-11
-6
17
111
10791
106
-10
-2.5
12.5
55
10846
105
-14
-9
23
108
10954
104
-18
-13
-19
-3
-12
65
111
11065
103
-12
-9
21
111
11176
102
-1
-12.5
13.5
108
11284
101
-25
25
177
11461
-------
Table 5-1
Surface Water Analytical Data
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
SW-500
SW-101
Chronic
01/26/98
01/26/98
Freshwater
10:50
11:00
ANTIMONY
UG/L
160
0.12
0.21
BARIUM
UG/L
10
9.9
CALCIUM
MG/L
64
110
LEAD
UG/L
1.32
0.1
0.1
MAGNESIUM
MG/L
3.2
200
MANGANESE
UG/L
1.6
1.4
MOLYBDENUM
UG/L
0.5
U
2
POTASSIUM
MG/L
5.2
64
SODIUM
MG/L
22
1600
STRONTIUM
UG/L
970
1800
TITANIUM
UG/L
1
U
5.3
URANIUM, TOTAL METAL
UG/L
2.2
2.6
VANADIUM
UG/L
1.8
1
ZINC
UG/L
58.91
4.1
3.4
Note: Extractables, pesticides, PCBs, volatiles and cyanide were analyzed for,
but were not detected.
Data Qualifiers
U-Material was analyzed for but not detected.
-------
Table 5-2
Surface Water Analytical Data - Cyanide
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
Chronic
Freshwater
SW101
01/26/98
11:00
SW500
01/26/98
10:50
CYANIDE UG/L
5.2
2 U
2 U
Data Qualifiers
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-3
Surface Water Data - Extractables
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
Chronic
Freshwater
SW101
01/26/98
11:00
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORON APHTH ALEN E
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHEN OL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHEN OL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BEN ZO(B)FLU ORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
B1S(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
36.5
UG/L
21.2
UG/L
6.2
UG/L
UG/L
UG/L
UG/L
43.8
UG/L
2.3
UG/L
UG/L
UG/L
UG/L
3500
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
82.8
17
2380
0.3
U
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
2
2
2
2
2
2
2
4
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
SW500
01/26/98
10.50
U
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
UJ
UJ
UJ
UJ
UJ
u
U
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
2
2
2
2
2
2
4
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
U
U
U
u
u
u
u
u
u
u
u
u
u
u
u
u
UJ
UJ
UJ
UJ
UJ
-------
Table 5-3 (Continued)
Surface Water Data - Extractables
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
SW101
SW500
Chronic
01/26/98
01/26/98
Freshwater
11:00
10:50
C2 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
C2 FLUORENES
UG/L
2
UJ
2
UJ
C2 NAPHTHALENES
UG/L
2
UJ
2
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
C3 FLUORENES
UG/L
2
UJ
2
UJ
C3 NAPHTHALENES
UG/L
2
UJ
2
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/L
2
UJ
2
UJ
C4 NAPHTHALENES
UG/L
2
UJ
2
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/L
2
UJ
2
UJ
CARBAZOLE
UG/L
2
U
2
U
CHRYSENE
UG/L
2
U
2
U
DI-N-BUTYLPHTHALATE
UG/L
2
U
2
U
DI-N-OCTYLPHTHALATE
UG/L
2
U
2
u
DIBENZO(A,H)ANTHRACENE
UG/L
2
U
2
u
DIBENZOFURAN
UG/L
2
U
2
u
DIETHYL PHTHALATE
UG/L
521
2
U
2
u
DIMETHYL PHTHALATE
UG/L
330
2
U
2
u
FLUORANTHENE
UG/L
39.8
2
U
2
u
FLUORENE
UG/L
2
U
2
u
HEXACHLOROBENZENE (HCB)
UG/L
2
U
2
u
HEXACHLOROBUTADIENE
UG/L
0.93
2
U
2
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/L
0.07
2
u
2
u
HEXACHLOROETHANE
UG/L
9.8
2
u
2
u
INDENO (1,2,3-CD) PYRENE
UG/L
2
u
2
u
ISOPHORONE
UG/L
1170
2
u
2
u
N-NITROSODI-N-PROPYLAMINE
UG/L
2
u
2
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/L
2
u
2
u
NAPHTHALENE
UG/L
62
2
u
2
u
NITROBENZENE
UG/L
270
2
u
2
u
PENTACHLOROPHENOL
UG/L
4
u
4
u
PHENANTHRENE
UG/L
2
u
2
u
PHENOL
UG/L
2
u
2
u
PYRENE
UG/L
2
u
2
u
Note: Results in Bold/Italic exceed RAGS chronic screening values for freshwater.
Note: Divide the minimum quantitation limit by 10 to determine the estimated detection limit.
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-4
Surface Water Analytical Data - Pesticides/PCBs
Military Canal Special Study
Homestead Air Force Base, Florida
November, 199 7
1-HYDROXYCHLORDENE 12
2,4,5-T
2,4-D
4,4'-DDD (P,P'-DDD)
4,4-DDE (P.P'-DDE)
4,4-DDT (P,P'-DDT)
ALDRIN
ALPHA-BHC
ALPHA-CHLORDANE 12
ALPHA-CHLORDENE 12
BETA-BHC
BETA-CHLORDENE 12
CHLORDANE (TECH. MIXTURE) /1
CHLORDENE 12
CIS-NONACHLOR 12
DELTA-BHC
DICAMBA
DIELDRIN
ENDOSULFAN I (ALPHA)
ENDOSULFAN 11 (BETA)
ENDOSULFAN SULFATE
ENDR1N
ENDR1N KETONE
GAMMA-BHC (LINDANE)
GAMMA-CHLORDANE 12
GAMMA-CHLORDENE 12
HEPTACHLOR
HEPTACHLOR EPOXIDE
METHOXYCHLOR
OXYCHLORDANE (OCTACHLOREPOXIDE) /2
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
SILVEX (2,4,5-TP)
TOXAPHENE
TRANS-NONACHLOR 12
RAGS
SW101
SW500
Chronic
01/26/98
01/26/98
Freshwater
11:00
10:50
UG/L
UG/L
0.075 U
0.11 u
UG/L
0.1 U
0.1 u
UG/L
0.0064
0.25 U
0.25 U
UG/L
10.5
0.25 U
0.25 U
UG/L
0.001
0.25 U
0.26 U
UG/L
0.3
0.25 U
0.25 U
UG/L
5005
0.25 U
0.25 U
UG/L
UG/L
UG/L
50005
0.25 U
0.25 U
UG/L
UG/L
0.0043
0.63 U
0.63 U
UG/L
UG/L
UG/L
0.25 U
0.25 U
UG/L
0.075 U
0.25 U
UG/L
0.0019
0.25 U
0.25 U
UG/L
0.056
0.25 U
0.25 U
UG/L
0.056
0.25 U
0.25 U
UG/L
0.25 U
0.25 U
UG/L
0.056
0.25 U
0.25 U
UG/L
0.26 U
0.25 U
UG/L
0.08
0.25 U
0.25 U
UG/L
UG/L
UG/L
0.0023
0.25 U
0.25 U
UG/L
0.0038
0.25 U
0.25 U
UG/L
0.03
0.62 U
0.62 U
UG/L
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.014
1.3 U
1.3 U
UG/L
0.075 U
0.05 U
UG/L
0.0002
10 u
10 u
UG/L
Note: Results in Bold/Italic exceed the RAGS chronic screening values for freshwater.
Note: Divide the minimum quantitation limit by 10 to determine the estimated detection limit.
Data Qualifiers
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 5-5
Surface Water Analytical Data - Volatiles
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
SW101
SW500
Chronic
01/26/98
01/26/98
Freshwater
11:00
10:50
(M- AND/OR P-)XYLENE
UG/L
1
U
1 U
1,1,1,2-TETRACHLOROETH ANE
UG/L
240
1
U
1 u
1,1,1 -TRICHLOROETH ANE
UG/L
528
1
u
1 u
1,1,2,2-TETRACHLOROETHANE
UG/L
240
1
u
1 u
1,1,2-TRICHLOROETH ANE
UG/L
1
u
1 u
1,1 -DICHLOROETH ANE
UG/L
1
u
1 u
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/L
303
1
u
1 u
1,1 -DICHLOROPROPENE
UG/L
1
u
1 u
1,2,3-TRICHLOROBENZENE
UG/L
1
u
1 u
1,2,3-TRICHLOROPROPANE
UG/L
1
u
1 u
1,2,4-TRICHLOROBENZENE
UG/L
1
u
1 u
1,2,4-TRIMETH YLBENZENE
UG/L
1
u
1 u
1,2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/L
1
u
1 u
1,2-DIBROMOETH ANE (EDB)
UG/L
1
u
1 u
1,2-DICHLOROBENZENE
UG/L
1
u
1 u
1,2-DICHLOROETHANE
UG/L
2000
1
u
1 u
1,2-DICHLOROPROPANE
UG/L
1
u
1 u
1,3,5-TRIMETH YLBENZENE
UG/L
1
u
1 u
1,3-DICHLOROBENZENE
UG/L
1
u
1 u
1,3-DICHLOROPROPANE
UG/L
1
u
1 u
1,4-DICHLOROBENZENE
UG/L
1
u
1 u
2,2-DICHLOROPROPANE
UG/L
1
u
1 u
ACETONE
UG/L
25
u
25 u
BENZENE
UG/L
53
1
u
1 u
BROMOBENZENE
UG/L
1
u
1 u
BROMOCHLOROMETHANE
UG/L
1
u
1 u
BROMOD1CHLOROMETHANE
UG/L
1
u
1 u
BROMOFORM
UG/L
293
1
u
1 u
BROMOMETHANE
UG/L
1
u
1 u
CARBON DISULFIDE
UG/L
2.5
u
2.5 U
CARBON TETRACHLORIDE
UG/L
352
1
u
1 u
CHLOROBENZENE
UG/L
195
1
u
1 u
CHLOROETHANE
UG/L
1
u
1 u
CHLOROFORM
UG/L
289
1
u
1 u
CHLOROMETHANE
UG/L
1
u
1 u
CIS-1,2-DICHLOROETHENE
UG/L
1
u
1 u
CIS-1,3-DICHLOROPROPENE
UG/L
1
u
1 u
DIBROMOCHLOROMETHANE
UG/L
1
u
1 u
DIBROMOMETHANE
UG/L
1
u
1 u
ETHYL BENZENE
UG/L
453
1
u
1 u
HEXACHLORO-1,3-BUTADIENE
UG/L
1
u
1 u
ISOPROPYLBENZENE
UG/L
1
u
1 u
METHYL BUTYL KETONE
UG/L
2.5
u
2.5 U
METHYL ETHYL KETONE
UG/L
25
u
25 U
METHYL ISOBUTYL KETONE
UG/L
2.5
u
2.5 U
METHYLENE CHLORIDE
UG/L
1930
5
u
5 U
N-BUTYLBENZENE
UG/L
1
u
1 U
N-PROPYLBENZENE
UG/L
1
u
1 V
-------
Table 5-6
Surface Water Analytical Data - Metals
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
RAGS
SW101
SW500
Chronic
01/26/98
01/26/98
Freshwater
11:00
10:50
ALUMINUM
UG/L
87
10
U
10
U
ANTIMONY
UG/L
160
0.21
0.12
U
ARSENIC
UG/L
90
5
U
5
BARIUM
UG/L
9.9
10
BERYLLIUM
UG/L
0.53
0.1
U
0.1
U
BORON
UG/L
750
NA
NA
CADMIUM
UG/L
0.66
0.2
U
0.1
U
CALCIUM
MG/L
110
64
CHROMIUM
UG/L
17.32
3
U
3
U
COBALT
UG/L
0.5
U
0.5
u
COPPER
UG/L
0.54
3
U
1
V
IRON
MG/L
1000
0.05
u
0.05
u
LEAD
UG/L
0.32
0.1
u
0.1
MAGNESIUM
MG/L
200
3.2
MANGANESE
UG/L
1.4
1.6
MOLYBDENUM
UG/L
2
0.5
u
NICKEL
UG/L
7.71
1
u
1
u
POTASSIUM
MG/L
64
5.2
SELENIUM
UG/L
0
5
u
5
u
SILVER
UG/L
0.12
0.1
u
0.1
u
SODIUM
MG/L
1600
22
STRONTIUM
UG/L
1800
970
TELLURIUM
UG/L
50
u
50
u
THALLIUM
UG/L
4
0.1
u
0.1
u
TIN
UG/L
0.5
u
0.5
u
TITANIUM
UG/L
5.3
1
u
TOTAL MERCURY
UG/L
0.12
0.002
u
0.002
u
URANIUM, TOTAL METAL
UG/L
2.6
2.2
VANADIUM
UG/L
1
u
1.8
YTTRIUM
UG/L
0.5
u
0.5
u
ZINC
UG/L
8.91
3.4
4.1
ZIRCONIUM
UG/L
NA
NA
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-7
Sediment Analytical Results - Nutrients and Cyanide
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD101
SD101
SD102
SD102DUP
SD103
SD104
SD104
SD105
SD106
SD107
11/13/97
11/16/97
11/13/97
11/13/97
11/13/97
11/13/97
11/16/97
11/13/97
11/14/97
11/14/97
13:35
09:40
14:03
14:10
15:00
15:30
10:02
15:55
16:02
16:25
AMMONIA
MG/KG
14
18
NR
NR
NR
78
79
A
NR
NR
30
CYANIDE
MG/KG
0.42
JU
0.45
JU
1.2
JU
1.2 JU
2.2
JU
0.95
JU
0.87
JU
0.61
JU
0.61
JU
0.57
JU
NITRATE-NITRITE NITROGEN
MG/KG
26
U
29
U
NR
NR
NR
60
U
52
AU
NR
NR
35
AU
TOTAL KJELDAHL NITROGEN
MG/KG
700
1200
NR
NR
NR
600
6100
A
NR
NR
1500
TOTAL PHOSPHORUS
MG/KG
220
320
NR
NR
NR
630
490
NR
NR
270
A
SDI07
SD108
SD109
SDI10
SD110A
SD110B
SD110BDP
SDIII
SDK 2
SD112DUP
11/16/97
11/14/97
11/15/97
11/15/97
11/19/97
11/19/97
11/19/97
11/15/97
11/15/97
11/15/97
10:18
16:45
08:45
08:00
09:20
09:20
09:20
08:25
09:00
09:20
AMMONIA
MG/KG
17
NR
NR
36 A
NR
NR
NR
NR
NR
NR
CYANIDE
MG/KG
0.43
JU
0.43
JU
0.57
JU
0.59 JU
0.5
JU
0.43
JU
0.43
JU
0.41
JU
0.5
JIJ
0.48
JU
NITRATE-NITRITE NITROGEN
MG/KG
26
U
NR
NR
37 U
NR
NR
NR
NR
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
1800
NR
NR
3600 A
NR
NR
NR
NR
NR
NR
TOTAL PHOSPHORUS
MG/KG
140
A
NR
NR
190
NR
NR
NR
NR
NR
NR
SDII3
SDII4
SDII5
SDH 6
SD117
SDI18
SD119
SD120A
SD120B
SD121
11/15/97
11/14/97
11/14/97
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
09:35
12:05
11:30
10:00
09:47
11:10
15:45
10:00
10:00
13:35
AMMONIA
MG/KG
25
NR
NR
17
NR
NR
230
A
NR
NR
NR
CYANIDE
MG/KG
0.59
JU
0.67
JU
0.83
JU
0.56 JU
0.62
JU
1.8
JU
1
JU
1.4
JU
0.57
JU
1
JU
NITRATE-NITRITE NITROGEN
MG/KG
37
U
NR
NR
35 U
NR
NR
60
AU
NR
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
3200
NR
NR
2500
NR
NR
6700
A
NR
NR
NR
TOTAL PHOSPHORUS
MG/KG
140
NR
NR
100
NR
NR
710
NR
NR
NR
SD122
SD123
SDI23DUP
SD124
SDI25
SD126
SD127
SD128
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/16/97
16:00
13:33
13:35
14:33
15:25
16:00
16:28
09:10
AMMONIA
MG/KG
140
NR
NR
NR
110
NR
NR
50
CYANIDE
MG/KG
1.3
JU
1
JU
0.77
JU
1 JU
1.4
JU
0.91
JU
0.74
JU
1
JU
NITRATE-NITRITE NITROGEN
MG/KG
82
U
NR
NR
NR
87
U
NR
NR
62
U
TOTAL KJELDAHL NITROGEN
MG/KG
7100
NR
NR
NR
4400
NR
NR
5300
TOTAL PHOSPHORUS
MG/KG
480
NR
NR
NR
600
NR
NR
400
Note: Cyanide results estimated, QC limits exceeded for all samples
Data Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-8
Sediment Analytical Results - Nutrients and Cyanide
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD202
SD203
SD204
SD205
SD205
SD206
SD206DUP
SD207
SD208
SD209
11/14/97
11/13/97
11/13/97
11/14/97
11/15/97
11/14/97
11/14/97
11/14/97
11/15/97
11/15/97
11:30
15:10
16:02
16:20
09:50
10:05
10:10
12:25
15:15
10:25
AMMONIA
MG/KG
27
NR
NR
NR
130
NR
NR
NR
83
NR
CYANIDE
MG/KG
0.77
JU
1.1
JU
1.1
JU
1.1
JU
1.4
JU
1.5
JU
1.3
JU
1.6
J
1.5
JU
1.3
JU
NITRATE-NITRITE NITROGEN
MG/KG
48
U
NR
NR
NR
89
U
NR
NR
NR
95
U
NR
TOTAL KJELDAHL NITROGEN
MG/KG
3900
NR
NR
NR
8200
NR
NR
NR
6400
NR
TOTAL PHOSPHORUS
MG/KG
390
NR
NR
NR
770
NR
NR
NR
2700
NR
SD210
SD211
SD211A
SD211B
SD212
SD213
SD214
SD215
SD215DUP
SD216
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
13:20
13:32
14:00
14:05
13:50
13:18
13:45
14:15
14:20
14:50
AMMONIA
MG/KG
NR
90
NR
NR
NR
NR
87
NR
NR
NR
CYANIDE
MG/KG
1.7
JU
0.91
JU
1
JU
0.61
JU
0.91
JU
1
JU
1.5
JU
1
JU
1.1
JU
1
JU
NITRATE-NITRITE NITROGEN
MG/KG
NR
56
U
NR
NR
NR
NR
94
U
NR
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
NR
6300
NR
NR
NR
NR
6900
NR
NR
NR
TOTAL PHOSPHORUS
MG/KG
NR
2200
NR
NR
NR
NR
1400
NR
NR
NR
SD217
SD218
SD219
SD220
SD221
SD222
11/15/97
11/15/97
11/15/97
11/15/97
11/16/97
11/16/97
15:19
15:55
16:20
16:45
09:45
10:25
AMMONIA
MG/KG
86
NR
NR
66
NR
NR
• ""'ANIDE
MG/KG
1.7
JU
0.95
JU
1.5
JU
0.91
JU
1.2
JU
2.9
JU
NITRATE-NITRITE NITROGEN
MG/KG
100
U
NR
NR
56
U
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
9300
NR
NR
3600
NR
NR
TOTAL PHOSPHORUS
MG/KG
2100
NR
NR
1500
A
NR
NR
Note: Cyanide results estimated, QC limits exceeded for all samples
Qlig Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-9
Sediment Analytical Results - Nutrients and Cyanide
300 Series Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD301
SD302
SD302DUP
SD303
SD304
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
10:50
11:25
11:30
12:00
12:20
AMMONIA
MG/KG
110
NR
NR
NR
91
CYANIDE
MG/KG
1.8
JU
1.2
JU
1.2
JU
1.7
JU
1.7
JU
NITRATE-NITRITE NITROGEN
MG/KG
110
U
NR
NR
NR
100
U
TOTAL KJELDAHL NITROGEN
MG/KG
12000
NR
NR
NR
12000
TOTAL PHOSPHORUS
MG/KG
2400
NR
NR
NR
2300
Note: Cyanide results estimated, QC limits exceeded for all samples
Data Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-9
Sediment Analytical Results - Nutrients and Cyanide
300 Series Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD301
SD302
SD302DUP
SD303
SD304
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
10:50
11:25
11:30
12:00
12:20
AMMONIA
MG/KG
110
NR
NR
NR
91
CYANIDE
MG/KG
1.8
JU
1.2
JU
1.2
JU
1.7
JU
1.7
JU
NITRATE-NITRITE NITROGEN
MG/KG
110
U
NR
NR
NR
100
U
TOTAL KJELDAHL NITROGEN
MG/KG
12000
NR
NR
NR
12000
TOTAL PHOSPHORUS
MG/KG
2400
NR
NR
NR
2300
Note: Cyanide results estimated, QC limits exceeded for all samples
Data Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-10
Sediment Analytical Results - Nutrients and Cyanide
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD401
SD402
SD403
SD403DUP
SD404
SD405
SD406
SD407
SD408
SD409
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/18/97
11/18/97
11/18/97
12:55
13:15
13:44
13:50
15:00
15:20
15:35
09:00
09:23
09:55
AMMONIA
MG/KG
44
NR
NR
NR
110
NR
NR
120
NR
NR
CYANIDE
MG/KG
0.91
JU
0.91
JU
0.83
JU
0.77
JU
2
JU
1.3
JU
1.2
JU
1.2
JU
t.7
JU
0.8
JU
NITRATE-NITRITE NITROGEN
MG/KG
55
U
NR
NR
NR
120
U
NR
NR
120
U
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
7200
NR
NR
NR
13000
NR
NR
12000
NR
NR
TOTAL PHOSPHORUS
MG/KG
2200
NR
NR
NR
1700
NR
NR
4000
NR
NR
SD410
SD411
SD412
SD413
SD4I4
SD415
SD4I6
SD417
SD417DUP
SD418
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
10:20
10:50
11:15
11:45
13:01
13:01
13:20
13:45
13:50
14:03
AMMONIA
MG/KG
64
NR
NR
160
NR
NR
86
NR
NR
NR
CYANIDE
MG/KG
1.7
JU
0.74
JU
1.3
JU
1.8
JU
0.87
JU
0.62
JU
1.4
JU
I.I
JU
1.1
JU
0.71
JU
NITRATE-NITRITE NITROGEN
MG/KG
100
U
NR
NR
106
U
NR
NR
86
U
NR
NR
NR
TOTAL KJELDAHL NITROGEN
MG/KG
9100
NR
NR
10000
NR
NR
8000
NR
NR
NR
TOTAL PHOSPHORUS
MG/KG
1200
NR
NR
2800
NR
NR
3600
NR
NR
NR
SD4I9
SD420
SD421
SD422
SD423
SD424
SD425
SD503A
SD503B
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
14:27
14:47
15:20
15:47
16:15
09:17
09:25
11:15
11:15
AMMONIA
MG/KG
58
NR
NR
38
NR
NR
90
A
61
NR
CYANIDE
MG/KG
1.2
JU
0.56
JU
0.95
JU
0.87
JU
1.1
JU
0.91
JU
2
JU
0.91
JU
0.36
JU
NITRATE-NITRITE NITROGEN
MG/KG
73
U
NR
NR
52
U
NR
NR
122
AU
56
U
NR
TOTAL KJELDAHL NITROGEN MG/KG
6000
NR
NR
4600
NR
NR
7500
A
2000
NR
TOTAL PHOSPHORUS
MG/KG
1700
NR
NR
1300
NR
NR
1200
1900
NR
Note: Cyanide results estimated, QC limits exceeded for all samples
Data Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-11
Sediment Analytical Results - Nutrients and Cyanide
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD601
SD602
SD603
SD604
SD605
SD605DUP
SD606
SD607
SD608
SD609
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
08:45
09:08
09:31
09:55
10:20
10:25
11:48
13:02
13:26
14:34
AMMONIA MG/KG
21
NR
NR
28
A
NR
NR
NR
44
NR
NR
CYANIDE MG/KG
0.42 JU
0.45
JU
0.57
JU
0.57
JU
0.77
JU
0.83
JU
1.1
JU
0.91
JU
1
JU
0.87
JU
NITRATE-NITRITE NITROGEN MG/KG
26 U
NR
NR
35
AU
NR
NR
NR
53
U
NR
NR
TOTAL KJELDAHL NITROGEN MG/KG
1800
NR
NR
2100
A
NR
NR
NR
4000
NR
NR
TOTAL PHOSPHORUS MG/KG
220 A
NR
NR
780
NR
NR
NR
620
NR
NR
SD610
SD701
SD702
SD703
SD703DUP
SD801
SD801DUP
SD802
SD803
11/18/97
H/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
15:00
16:20
16:22
16:25
16:25
14:10
14:10
14:45
15:16
AMMONIA MG/KG
40
NR
64
A
NR
NR
NR
NR
160
NR
CYANIDE MG/KG
0.95 JU
1.2
JU
1
JU
0.83
JU
0.8
JU
2
JU
2
JU
2.5
JU
2.5
JU
NITRATE-NITRITE NITROGEN MG/KG
58 U
NR
62
AU
NR
NR
NR
NR
156
U
NR
TOTAL KJELDAHL NITROGEN MG/KG
3600
NR
4500
A
NR
NR
NR
NR
9000
NR
TOTAL PHOSPHORUS MG/KG
500
NR
600
NR
NR
NR
NR
450
A
NR
Note: Cyanide results estimated, QC limits exceeded for all samples
Data Qualifiers
A-Average value. J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(A)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD101
Effects 11/16/97
Value 09:40
SD102 SD102DUP
11/13/97 11/13/97
14:03 14:10
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRICHLOROBENZENE
2 UNIDENTIFIED COMPOUNDS
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DI CHLOROPHEN OL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DI'NITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONA.PHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3 UNIDENTIFIED COMPOUNDS
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
acenaphthene
ACENAPHTHYLENE
anthracene
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHl)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 20.23
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 6.71
UG/KG 5.87
UG/KG 46.9
UG/KG 74.8
UG/KG
UG/KG
UG/KG
UG/KG 88.8
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 182
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
40.1
230 U
230 U
4000 J
230 U
230 U
230 U
230 U
230 U
470 U
230 U
230 U
230 U
230 U
470 U
230 U
230 U
230 U
230 U
NR
230 U
230 U
230 U
230 U
230 U
230 U
230 U
470 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 U
230 UJ
230 UJ
230 UJ
230 UJ
230 UJ
230 UJ
230 UJ
84
760 U
760 U
NR
760 U
760 U
760 U
760 U
760 U
1500 U
760 U
760 U
760 U
760 U
1500 U
760 V
760 U
760 U
760 U
50000 J
760 U
760 U
760 U
760 U
760 U
760 U
760 U
1500 U
760 U
760 U
760 U
760 U
50 J
50 J
92 J
38 J
1400 U
760 U
760 U
760 U
760 U
760 UJ
760 UJ
760 UJ
760 UJ
760 UJ
760 UJ
760 UJ
83.6
700 U
700 u
700 J
700 U
700 lj
700 U
700 u
700 U
1400 U
700 U
700 u
700 u
700 U
1400 U
700 (j
700 U
700 \j
700 u
NR
700 L)
700 y
700 u
700 lj
700 y
700 u
700 U
1400 u
700 (j
7 oo a
700 U
700 U
52 J
49 j
91 J
45 J
720 U
700 U
700 U
700 U
700 U
700 UJ
700 UJ
700 UJ
700 UJ
700 UJ
700 UJ
700 UJ
-------
Table 5-12(A) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Value
SD101
11/16/97
09:40
SD102
11/13/97
14:03
SD102DUP
11/13/97
14:10
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYLPHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEX ACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
HEX ADECEN OIC ACID
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYLTIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 UJ
760 UJ
700 UJ
230 U
760 U
700 U
230 U
61 J
70 J
2100 U
6100 U
4100 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
47 J
430 U
420 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
110 J
130 J
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
2000 JN
NR
NR
230 U
38 J
38 J
230 U
760 U
700 U
110 U
430 U
420 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
230 U
760 U
700 U
470 U
1500 U
1400 U
NR
N
N
230 U
69 J
42 J
230 U
760 U
700 U
230 U
57 J
80 J
110 U
430 U
420 U
110 U
430 U
420 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported . .
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(B)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD103
SD104
Effects
11/13/97
11/16/97
Value
15:00
10:02
% MOISTURE
%
82.5
75.8
(3-AND/OR 4-)METHYLPHENOL
UG/KG
720 U
510 U
1 UNIDENTIFIED COMPOUND
UG/KG
NR
5000 J
1,2,4-TRICHLOROBENZENE
UG/KG
720 U
510 U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
720 U
510 U
2,4,5-TRICHLOROPHENOL
UG/KG
720 U
510 U
2,4,6-TRICHLOROPHENOL
UG/KG
720 U
510 U
2,4-DICHLOROPHENOL
UG/KG
720 U
510 U
2,4-DIMETHYLPHENOL
UG/KG
720 U
510 U
2,4-DINITROPHENOL
UG/KG
1400 U
1000 U
2,4-DINITROTOLUENE
UG/KG
720 U
510 U
2,6-DINITROTOLUENE
UG/KG
720 U
510 U
2-CHLORONAPHTHALENE
UG/KG
720 U
510 U
2-CHLOROPHENOL
UG/KG
720 U
510 U
2-METHYL-4,6-DINITROPHENOL
UG/KG
1400 U
1000 U
2-METHYLNAPHTHALENE
UG/KG
20.23
720 U
510 U
2-METHYLPHENOL
UG/KG
720 U
510 U
2-NITROANILINE
UG/KG
720 U
510 U
2-NITROPHENOL
UG/KG
720 U
510 U
3 UNIDENTIFIED COMPOUNDS
UG/KG
10000 J
NR
3,3 '-DICHLOROBENZIDINE
UG/KG
720 U
510 U
3-NITROANILINE
UG/KG
720 U
510 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
720 U
510 U
4-CHLORO-3-METHYLPHENOL
UG/KG
720 U
510 U
4-CHLOROANILINE
UG/KG
720 U
510 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
720 U
510 U
4-NITROANILINE
UG/KG
720 U
510 U
4-NITROPHENOL
UG/KG
1400 U
1000 U
ACENAPHTHENE
UG/KG
6.71
720 U
510 U
ACENAPHTHYLENE
UG/KG
5.87
720 U
510 U
ANTHRACENE
UG/KG
46.9
720 U
510 U
BENZO(A)ANTHRACENE
UG/KG
74.8
43 J
510 U
BENZO(B)FLUORANTHENE
UG/KG
83 J
53 J
BENZO(GHI)PERYLENE
UG/KG
69 J
30 J
BENZO(K)FLUORANTHENE
UG/KG
10 J
510 U
BENZO-A-PYRENE
UG/KG
88.8
65 J
510 U
BENZYL BUTYL PHTHALATE
UG/KG
720 U
510 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
720 U
510 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
720 U
510 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
720 U
510 U
BI S(2-ETHYLH EXYL) PHTHALATE
UG/KG
182
720 U
510 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
720 UJ
510 UJ
CI FLUORANTHENES/PYRENES
UG/KG
720 UJ
510 UJ
CI FLUORENES
UG/KG
720 UJ
510 UJ
CI NAPHTHALENES
UG/KG
720 UJ
510 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
720 UJ
510 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
720 UJ
510 UJ
C2FLUORENES
UG/KG
720 UJ
510 UJ
SD105
11/13/97
15:55
54.8
290 U
NR
290 U
290 U
290 U
290 U
290 u
290 U
590 U
290 U
290 U
290 U
290 U
590 U
290 U
290 U
290 U
290 U
NR
290 U
290 U
290 U
290 U
290 U
290 U
290 U
590 U
290 U
290 U
16 J
23 J
37 J
26 J
57 J
31 J
290 U
290 U
290 U
290 U
290 U
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
-------
Table 5-12(B) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Value
SD103
11/13/97
15:00
SD104
11/16/97
10:02
SD105
11/13/97
15:55
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
D1BENZOFURAN
DIBUTYLTIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYLTIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
720 UJ
720 UJ
720 UJ
720 UJ
720 UJ
720 UJ
720 UJ
720 UJ
720 UJ
720 U
87 J
5600 U
720 U
720 U
720 U
330 U
720 U
720 U
150 J
720 U
720 U
720 U
720 U
720 U
51 J
720 U
330 U
720 U
720 U
720 U
720 U
1400 U
N
43 J
720 U
120 J
330 U
330 U
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 U
510 U
4900 U
510 U
510 U
510 U
270 U
510 U
510 U
79 J
510 U
510 U
510 U
510 U
510 U
25 J
510 U
270 U
510 U
510 U
510 U
510 U
1000 U
NR
30 J
510 U
46 J
270 U
270 U
Note: The estimated detection limit can be
Note: Reported values exceeding the RAGS EV are in
Data Qualifiers
calculated by dividing the minimum quantitation limit by 20.
bold. Values with EDL exceeding RAGS EV are italicized.
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 U
50 J
2500 U
290 U
290 U
290 U
150 U
290 U
290 U
95 J
290 U
290 U
290 U
290 U
290 U
22 J
290 U
150 U
290 U
290 U
290 U
290 U
590 U
NR
31 J
290 U
97 J
150 U
150 U
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(C)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD106
SD107
SD108
Effects
11/14/97
11/16/97
11/14/97
Value
16:02
10:18
16:45
% MOISTURE
%
68.8
47.8
69.8
(3-AND/OR 4-)METHYLPHENOL
UG/KG
400 U
250 U
250 U
1 UNIDENTIFIED COMPOUND
UG/KG
NR
2000 J
NR
1,2,4-TRlCHLOROBENZENE
UG/KG
400 U
250 U
250 U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
400 U
250 U
250 U
2,4,5-TRICHLOROPHENOL
UG/KG
400 U
250 U
250 U
2,4,6-TRICHLOROPHENOL
UG/KG
400 U
250 U
250 U
2,4-DICHLOROPHENOL
UG/KG
400 U
250 U
250 U
2,4-DIMETHYLPHENOL
UG/KG
400 U
250 U
250 U
2,4-DINITROPHENOL
UG/KG
800 U
510 U
490 U
2,4-DINITROTOLUENE
UG/KG
400 U
250 U
250 U
2,6-DINITROTOLUENE
UG/KG
400 U
250 U
250 U
2-CHLORONAPHTHALENE
UG/KG
400 U
250 U
250 U
2-CHLOROPHEN OL
UG/KG
400 U
250 U
250 U
2-METHYL-4.6-DINITROPHENOL
UG/KG
800 U
510 U
490 U
2-METHYLNAPHTHALENE
UG/KG
20.23
400 U
250 U
250 U
2-METHYLPHENOL
UG/KG
400 U
250 U
250 U
2-NITROANILINE
UG/KG
400 U
250 U
250 U
2-NITROPHENOL
UG/KG
400 U
250 U
250 U
3,3-DICHLOROBENZIDINE
UG/KG
400 U
250 U
250 U
3-NITROANILINE
UG/KG
400 U
250 U
250 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
400 U
250 U
250 U
4-CHLORO-3-METHYLPHENOL
UG/KG
400 U
250 U
250 U
4-CHLOROANILINE
UG/KG
400 U
250 U
250 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
400 U
250 U
250 U
4-NITROANILINE
UG/KG
400 U
250 U
250 U
4-NITROPHENOL
UG/KG
800 U
510 U
490 U
ACENAPHTHENE
UG/KG
6.71
400 U
250 U
250 V
ACENAPHTHYLENE
UG/KG
5.87
400 U
250 V
250 U
ANTHRACENE
UG/KG
46.9
400 U
250 U
250 U
BENZO(A)ANTHRACENE
UG/KG
74.8
24 J
20 J
250 U
BENZO(B)FLUORANTHENE
UG/KG
40 J
35 J
250 U
BENZO(GHI)PERYLENE
UG/KG
38 J
23 J
250 U
BENZO(K)FLUORANTHENE
UG/KG
83 J
20 J
250 U
BENZO-A-PYRENE
UG/KG
88.8
30 J
13 J
250 U
BENZYL BUTYL PHTHALATE
UG/KG
400 U
250 U
250 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
400 U
250 U
250 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
400 U
250 U
250 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
400 U
250 U
250 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
400 U
250 U
250 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
400 UJ
250 UJ
250 UJ
CI FLUORANTHENES/PYRENES
UG/KG
400 UJ
250 UJ
250 UJ
CI FLUORENES
UG/KG
400 UJ
250 UJ
250 UJ
CI NAPHTHALENES
UG/KG
400 UJ
250 UJ
250 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
400 UJ
250 UJ
250 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
400 UJ
250 UJ
250 UJ
C2 FLUORENES
UG/KG
400 UJ
250 UJ
250 UJ
C2 NAPHTHALENES
UG/KG
400 UJ
250 UJ
250 UJ
-------
Table 5-12(C) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD106
SD107
SD108
Effects
11/14/97
11/16/97
11/14/97
Value
16:02
10:18
16:45
C2 PHENANTHRENES/ANTHRACENES
UG/KG
400
UJ
250
UJ
250
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
400
UJ
250
UJ
250
UJ
C3 FLUORENES
UG/KG
400
UJ
250
UJ
250
UJ
C3 NAPHTHALENES
UG/KG
400
UJ
250
UJ
250
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
400
UJ
250
UJ
250
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
400
UJ
250
UJ
250
UJ
C4 NAPHTHALENES
UG/KG
400
UJ
250
UJ
250
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
400
UJ
250
UJ
250
UJ
CARBAZOLE
UG/KG
400
U
250
u
250
U
CHRYSENE
UG/KG
108
50
J
15
J
250
u
DI-N-BUTYLPHTHALATE
UG/KG
2200
U
990
u
1800
u
DI-N-OCTYLPHTHALATE
UG/KG
400
U
250
u
250
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
400
U
250
u
250
u
dibenzofuran
UG/KG
400
U
250
u
250
u
DIBUTYL tin
UG/KG
210
u
120
u
120
u
DIETHYL PHTHALATE
UG/KG
400
u
250
u
250
u
DIMETHYL PHTHALATE
UG/KG
400
u
250
u
250
u
FLUORANTHENE
UG/KG
113
61
J
28
J
250
u
FLUORENE
UG/KG
21.2
400
u
250
u
250
u
HEXACHLOROBENZENE (HCB)
UG/KG
400
u
250
u
250
u
hexachlorobutadiene
UG/KG
400
u
250
u
250
u
HEXACHLOROCY CLOPENTADIENE (HCCP)
UG/KG
400
u
250
u
250
u
HEXACHLOROETHANE
UG/KG
400
u
250
u
250
u
INDENO (1,2,3-CD) PYRENE
UG/KG
30
J
19
J
250
u
ISOPHORONE
UG/KG
400
u
250
u
250
u
MONOBUTYL TIN
UG/KG
210
u
120
u
120
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
400
u
250
u
250
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
400
u
250
u
250
u
naphthalene
UG/KG
34.6
400
u
250
u
250
u
NITROBENZENE
UG/KG
400
u
250
u
250
u
PENTACHLOROPHENOL
UG/KG
800
u
510
u
490
u
phenanthrene
UG/KG
86.7
26
J
13
J
250
u
PHENOL
UG/KG
400
u
250
u
250
u
PYRENE
UG/KG
153
70
J
34
J
250
u
TETRABUTYL tin
UG/KG
210
u
120
u
120
u
tributyl tin
UG/KG
210
u
120
u
120
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(D)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD109
Effects 11/15/97
Value
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRlCHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITRO ANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLORO ANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2 FLUORENES
C2 NAPHTHALENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
182
08:45
57.7
280 U
280 U
280 U
280 U
280 U
280 U
280 U
560 U
280 U
280 U
280 U
280 U
560 U
280 U
280 U
280 U
280 U
280 U
280 U
280 U
280 U
280 U
280 U
280 U
560 U
280 V
280 U
280 U
280 U
16 J
280 U
20 J
280 U
280 U
280 U
280 U
280 U
280 U
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
SD110
11/15/97
08:00
SD110A
11/19/97
09:20
57.5
320 U
320 U
320 U
320 U
320 U
320 U
320 U
630 U
320 U
320 U
320 U
320 U
630 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
24 J
24 J
24 J
320 U
320 U
320 U
320 U
320 U
320 U
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
56.5
270 U
270 U
270 U
270 U
270 U
270 U
270 U
550 U
270 U
270 U
270 U
270 U
550 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
550 U
270 V
270 V
270 U
19 J
40 J
19 J
15 J
14 J
270 U
270 U
270 U
270 U
270 U
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
-------
Table 5-12{D) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Value
SD109
11/15/97
08:45
SD110
11/15/97
08:00
SD110A
11/19/97
09:20
C2 PHENANTHRENES/ANTHRACENES UG/KG 280 UJ 320 UJ
C3 CHRYSENES/BENZANTHRACENES UG/KG 280 UJ 320 UJ
C3FLUORENES UG/KG 280 UJ 320 UJ
C3 NAPHTHALENES UG/KG 280 UJ 320 UJ
C3 PHENANTHRENES/ANTHRACENES UG/KG 280 UJ 320 UJ
C4 CHRYSENES/BENZANTHRACENES UG/KG 280 UJ 320 UJ
C4 NAPHTHALENES UG/KG 280 UJ 320 UJ
C4 PHENANTHRENES/ANTHRACENES UG/KG 280 UJ 320 UJ
CARBAZOLE UG/KG 280 U 320 U
CHRYSENE UG/KG 108 280 U 320 U
DI-N-BUTYLPHTHALATE UG/KG 1000 U 1600 U
DI-N-OCTYLPHTHALATE UG/KG 280 U 320 U
DIBENZO(A,H)ANTHRACENE UG/KG 6.22 280 U 320 U
DIBENZOFURAN UG/KG 280 U 320 U
DIBUTYLTIN UG/KG 160 U 140 U
DIETHYL PHTHALATE UG/KG 280 U 320 U
DIMETHYL PHTHALATE UG/KG 280 U 320 U
FLUORANTHENE UG/KG 113 17 J 44 J
FLUORENE UG/KG 21.2 280 U 320 U
HEXACHLOROBENZENE (HCB) UG/KG 280 U 320 U
HEXACHLOROBUTADIENE UG/KG 280 U 320 U
HEXACHLOROCYCLOPENTADIENE (HCCP) UG/KG 280 U 320 U
HEXACHLOROETHANE UG/KG 280 U 320 U
INDENO (1,2,3-CD) PYRENE UG/KG 280 U 17 J
ISOPHORONE UG/KG 280 U 320 U
MONOBUTYLTIN UG/KG 160 U 140 U
N-NITROSODI-N-PROPYLAMINE UG/KG 280 U 320 U
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE UG/KG 280 U 320 U
NAPHTHALENE UG/KG 34.6 280 U 320 U
NITROBENZENE UG/KG 280 U 320 U
PENTACHLOROPHENOL UG/KG 560 U 630 U
PHENANTHRENE UG/KG 86.7 280 U 320 U
PHENOL UG/KG 280 U 320 U
PYRENE UG/KG 153 14 J 44 J
TETRABUTYL TIN UG/KG 160 U 140 U
TRIBUTYLTIN UG/KG 160 U 140 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 U
270 U
270 U
270 U
270 U
270 U
120 U
270 U
270 U
23 J
270 U
270 U
270 U
270 U
270 U
16 J
270 U
120 U
270 U
270 U
270 U
270 U
550 U
270 U
270 U
25 J
120 U
120 U
-------
Table 5-12(E)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD110B
SD110BDP
SD111
Effects
11/19/97
11/19/97
11/15/97
Value
09:20
09:20
08:25
% MOISTURE
%
48.7
49
46.6
(3-AND/OR 4-)METHYLPHENOL
UG/KG
230 U
220 U
240 U
1,2,4-TRICHLOROBENZENE
UG/KG
230 U
220 U
240 U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
230 U
220 U
240 U
2,4,5-TRICHLOROPHENOL
UG/KG
230 U
220 U
240 U
2,4,6-TRICHLOROPHENOL
UG/KG
230 U
220 U
240 U
2,4-DICHLOROPHENOL
UG/KG
230 U
220 U
240 U
2,4-DIMETHYLPHENOL
UG/KG
230 U
220 U
240 U
2,4-DINITROPHENOL
UG/KG
450 U
430 U
480 U
2,4-DINITROTOLUENE
UG/KG
230 U
220 U
240 U
2,6-DINITROTOLUENE
UG/KG
230 U
220 U
240 U
2-CHLORONAPHTHALENE
UG/KG
230 U
220 U
240 U
2-CHLOROPHENOL
UG/KG
230 U
220 U
240 U
2-METHYL-4,6-DINITROPHENOL
UG/KG
450 U
430 U
480 U
2-METHYLNAPHTHALENE
UG/KG
20.23
230 U
220 U
240 U
2-METHYLPHENOL
UG/KG
230 U
220 U
240 U
2-NITROANILINE
UG/KG
230 U
220 U
240 U
2-NITROPHENOL
UG/KG
230 U
220 U
240 U
3,3'-DICHLOROBENZIDINE
UG/KG
230 U
220 U
240 U
3-NITRO ANILINE
UG/KG
230 U
220 U
240 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
230 U
220 U
240 U
4-CHLORO-3-METHYLPHENOL
UG/KG
230 U
220 U
240 U
4-CHLORO ANILINE
UG/KG
230 U
220 U
240 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
230 U
220 U
240 U
4-NITROANILINE
UG/KG
230 U
220 U
240 U
4-NITROPHENOL
UG/KG
450 U
430 U
480 U
ACENAPHTHENE
UG/KG
6.71
230 U
220 U
240 U
ACENAPHTHYLENE
UG/KG
5.87
230 U
220 U
240 U
ANTHRACENE
UG/KG
46.9
230 U
220 U
240 U
BENZO(A)ANTHRACENE
UG/KG
74.8
230 U
220 U
240 U
BENZO(B)FLUORANTHENE
UG/KG
230 U
220 U
240 U
BENZO(GHI)PERYLENE
UG/KG
230 U
220 U
240 U
BENZO(K)FLUORANTHENE
UG/KG
230 U
220 U
240 U
BENZO-A-PYRENE
UG/KG
88.8
230 U
220 U
240 U
BENZYL BUTYL PHTHALATE
UG/KG
230 U
220 U
240 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
230 U
220 U
240 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
230 U
220 U
240 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
230 U
220 U
240 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
230 U
220 U
240 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
230 UJ
220 UJ
240 UJ
CI FLUORANTHENES/PYRENES
UG/KG
230 UJ
220 UJ
240 UJ
CI FLUORENES
UG/KG
230 UJ
220 UJ
240 UJ
CI NAPHTHALENES
UG/KG
230 UJ
220 UJ
240 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
230 UJ
220 UJ
240 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
230 UJ
220 UJ
240 UJ
C2 FLUORENES
UG/KG
230 UJ
220 UJ
240 UJ
C2 NAPHTHALENES
UG/KG
230 UJ
220 UJ
240 UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
230 UJ
220 UJ
240 UJ
-------
Table 5-12(E) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Value
SD110B
11/19/97
09:20
SD110BDP
11/19/97
09:20
SD1I1
11/15/97
08:25
C3 CHRYSENES/BENZANTHRACENES UG/KG 230 UJ
C3 FLUORENES UG/KG 230 UJ
C3 NAPHTHALENES UG/KG 230 UJ
C3 PHENANTHRENES/ANTHRACENES UG/KG 230 UJ
C4 CHRYSENES/BENZANTHRACENES UG/KG 230 UJ
C4 NAPHTHALENES UG/KG 230 UJ
C4 PHENANTHRENES/ANTHRACENES UG/KG 230 UJ
CARBAZOLE UG/KG 230 U
CHRYSENE UG/KG 108 230 U
DI-N-BUTYLPHTHALATE UG/KG 230 U
DI-N-OCTYLPHTHALATE UG/KG 230 U
DIBENZO(A,H)ANTHRACENE UG/KG 6.22 230 U
DIBENZOFURAN UG/KG 230 U
DIBUTYLTIN UG/KG 100 U
DIETHYL PHTHALATE UG/KG 230 U
DIMETHYL PHTHALATE UG/KG 230 U
FLUORANTHENE UG/KG 113 230 U
FLUORENE UG/KG 21.2 230 U
HEXACHLOROBENZENE (HCB) UG/KG 230 U
HEXACHLOROBUTADIENE UG/KG 230 U
HEXACHLOROCYCLOPENTADIENE (HCCP) UG/KG 230 U
HEXACHLOROETHANE UG/KG 230 U
INDENO (1,2,3-CD) PYRENE UG/KG 230 U
ISOPHORONE UG/KG 230 U
MONOBUTYLTIN UG/KG 100 U
N-NITROSODI-N-PROPYLAMINE UG/KG 230 U
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE UG/KG 230 U
NAPHTHALENE UG/KG 34.6 230 U
NITROBENZENE UG/KG 230 U
PENTACHLOROPHENOL UG/KG 450 U
PHENANTHRENE UG/KG 86.7 230 U
PHENOL UG/KG 230 U
PYRENE UG/KG 153 230 U
TETRABUTYL TIN UG/KG 100 U
TRIBUTYLTIN UG/KG 100 U
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 U
220 U
220 U
220 U
220 U
220 U
110 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
110 U
220 U
220 U
220 U
220 U
430 U
220 U
220 U
220 U
110 U
110 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 U
240 U
1100 U
240 U
240 U
240 U
120 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
120 U
240 U
240 U
240 U
240 U
480 U
240 U
240 U
240 U
120 U
120 U
-------
Table 5-12(F)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD112
Effects 11/15/97
Value
09:00
SD112DUP
11/15/97
09:20
SD113
11/15/97
09:35
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRICHLOROBENZ ENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHEN OL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHEN OL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BEN ZO( A) ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
88.8
182
52.5
240 U
240 U
240 U
240 U
240 U
240 U
240 U
480 U
240 U
240 U
240 U
240 U
480 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 V
480 U
240 U
240 U
240 U
17 J
24 J
18 J
240 U
240 U
240 U
240 U
240 U
240 U
240 U
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
240 UJ
53.1
270 U
270 U
270 U
270 U
270 U
270 U
270 U
540 U
270 U
270 U
270 U
270 U
540 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 U
540 U
270 U
270 U
270 U
270 U
22 J
15 J
270 U
270 U
270 U
270 U
270 U
270 U
270 U
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
270 UJ
43.4
220 U
220 U
220 U
220 U
220 U
220 U
220 U
440 U
220 U
220 U
220 U
220 U
440 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
220 U
440 U
220 U
220 U
220 U
13 J
18 J
16 J
220 U
11 J
220 U
220 U
220 U
220 U
220 U
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
-------
Table 5-12(F) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD112
SD112DUP
SD113
Effects
11/15/97
11/15/97
11/15/97
Value
09:00
09:20
09:35
C3 CHRYSENES/BENZANTHRACENES
UG/KG
240
UJ
270
UJ
220
UJ
C3 FLUORENES
UG/KG
240
UJ
270
UJ
220
UJ
C3 NAPHTHALENES
UG/KG
240
UJ
270
UJ
220
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
240
UJ
270
UJ
220
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
240
UJ
270
UJ
220
UJ
C4 NAPHTHALENES
UG/KG
240
UJ
270
UJ
220
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
240
UJ
270
UJ
220
UJ
CARBAZOLE
UG/KG
240
u
270
u
220
U
CHRYSENE
UG/KG
108
12
J
270
u
220
U
DI-N-BUTYLPHTHALATE
UG/KG
790
u
1200
u
1500
u
DI-N-OCTYLPHTHALATE
UG/KG
240
u
270
u
220
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
240
u
270
u
220
u
DIBENZOFURAN
UG/KG
240
u
270
u
220
u
dibutyl TIN
UG/KG
130
u
79
J
110
u
DIETHYL PHTHALATE
UG/KG
240
u
270
u
220
u
DIMETHYL PHTHALATE
UG/KG
240
u
270
u
220
u
FLUORANTHENE
UG/KG
113
26
J
19
J
25
J
fluorene
UG/KG
21.2
240
u
270
u
220
u
HEXACHLOROBENZENE(HCB)
UG/KG
240
u
270
u
220
u
hexachlorobutadiene
UG/KG
240
u
270
u
220
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
240
u
270
u
220
u
hexachloroethane
UG/KG
240
u
270
u
220
u
INDENO (1,2,3-CD) PYRENE
UG/KG
13
J
270
u
11
J
ISOPHORONE
UG/KG
240
u
270
u
220
u
MONOBUTYL TIN
UG/KG
130
u
130
u
110
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
240
u
270
u
220
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
240
u
270
u
220
u
NAPHTHALENE
UG/KG
34.6
240
u
270
u
220
u
NITROBENZENE
UG/KG
240
u
270
u
220
u
PENTACHLOROPHENOL
UG/KG
480
u
540
u
440
u
PHENANTHRENE
UG/KG
86.7
240
u
270
u
12
J
PHENOL
UG/KG
240
u
270
u
220
u
PYRENE
UG/KG
153
25
J
13
J
18
J
TETRABUTYL TIN
UG/KG
130
u
130
u
110
u
TRIBUTYL TIN
UG/KG
130
u
130
u
110
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(G)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD114
SD115
SD116
Effects
11/14/97
11/14/97
11/15/97
Value
12:05
11:30
10:00
% MOISTURE
%
54.2
64.1
71.5
(3-AND/OR 4-)METHYLPHENOL
UG/KG
270 U
340 U
470 U
1,2,4-TRICHLOROBENZENE
UG/KG
270 U
340 U
470 U
2 UNIDENTIFIED COMPOUNDS
UG/KG
NR
8000 J
NR
2,3,4,6-TETRACHLOROPHENOL
UG/KG
270 U
340 U
470 U
2,4,5-TRICHLOROPHENOL
UG/KG
270 U
340 U
470 U
2,4,6-TRICHLOROPHENOL
UG/KG
270 U
340 U
470 U
2,4-DICHLOROPHENOL
UG/KG
270 U
340 U
470 U
2,4-DIMETHYLPHENOL
UG/KG
270 U
340 U
470 U
2,4-DINITROPHENOL
UG/KG
540 U
690 U
940 U
2,4-DINITROTOLUENE
UG/KG
270 U
340 U
470 U
2,6-DINITROTOLUENE
UG/KG
270 U
340 U
470 U
2-CHLORONAPHTHALENE
UG/KG
270 U
340 U
470 U
2-CHLOROPHEN OL
UG/KG
270 U
340 U
470 U
2-METHYL-4.6-DINITROPHENOL
UG/KG
540 U
690 U
940 U
2-METHYLNAPHTHALENE
UG/KG
20.23
270 U
340 U
470 U
2-METHYLPHENOL
UG/KG
270 U
340 U
470 U
2-N1TROANILINE
UG/KG
270 U
340 U
470 U
2-NITROPHENOL
UG/KG
270 U
340 U
470 U
3,3'-DICHLOROBENZIDINE
UG/KG
270 U
340 U
470 U
3-NITROANILINE
UG/KG
270 U
340 U
470 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
270 U
340 U
470 U
4-CHLORO-3-METHYLPHENOL
UG/KG
270 U
340 U
470 U
4-CHLORO ANILINE
UG/KG
270 U
340 U
470 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
270 U
340 U
470 U
4-NITROANILINE
UG/KG
270 U
340 U
470 U
4-NITROPHENOL
UG/KG
540 U
690 U
940 U
ACENAPHTHENE
UG/KG
6.71
270 U
340 U
470 U
ACENAPHTHYLENE
UG/KG
5.87
270 U
340 U
470 U
ANTHRACENE
UG/KG
46.9
270 U
340 U
470 U
BENZO(A)ANTHRACENE
UG/KG
74.8
270 U
41 J
470 U
BENZO(B)FLUORANTHENE
UG/KG
270 U
59 J
470 U
BENZO(GHI)PERYLENE
UG/KG
270 U
45 J
470 U
BENZO(K)FLUORANTHENE
UG/KG
270 U
50 J
470 U
BENZO-A-PYRENE
UG/KG
88.8
270 U
24 J
470 U
BENZYL BUTYL PHTHALATE
UG/KG
270 U
340 U
570 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
270 U
340 U
470 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
270 U
340 U
470 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
270 U
340 U
470 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
270 U
340 U
470 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
270 UJ
340 UJ
470 UJ
CI FLUORANTHENES/PYRENES
UG/KG
270 UJ
340 UJ
470 UJ
CI FLUORENES
UG/KG
270 UJ
340 UJ
470 UJ
CI NAPHTHALENES
UG/KG
270 UJ
340 UJ
470 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
270 UJ
340 UJ
470 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
270 UJ
340 UJ
470 UJ
C2 FLUORENES
UG/KG
270 UJ
340 UJ
470 UJ
C2NAPHTHALENES
UG/KG
270 UJ
340 UJ
470 UJ
-------
Table 5-12(G) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD114
SD115
SD116
Effects
11/14/97
11/14/97
11/15/97
Value
12:05
11:30
10:00
C2 PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
340
UJ
470
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
340
UJ
470
UJ
C3 FLUORENES
UG/KG
270
UJ
340
UJ
470
UJ
C3 NAPHTHALENES
UG/KG
270
UJ
340
UJ
470
UJ
C3 PHENANTHRJENES/ANTHRACENES
UG/KG
270
UJ
340
UJ
470
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
340
UJ
470
UJ
C4 NAPHTHALENES
UG/KG
270
UJ
340
UJ
470
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
340
UJ
470
UJ
CARBAZOLE
UG/KG
270
U
340
u
470
u
CHRYSENE
UG/KG
108
270
u
21
J
470
u
DI-N-BUTYLPHTHALATE
UG/KG
810
u
2300
u
3400
u
DI-N-OCTYLPHTHALATE
UG/KG
270
u
340
u
470
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
270
u
17
J
470
u
dibenzofuran
UG/KG
270
u
340
u
470
u
dibutyl tin
UG/KG
150
u
180
u
220
u
diethyl phthalate
UG/KG
270
u
340
u
470
u
dimethyl phthalate
UG/KG
270
u
340
u
470
u
fluoranthene
UG/KG
113
270
u
91
J
470
u
fluorene
UG/KG
21.2
270
u
340
u
470
u
HEXACHLOROBENZENE (HCB)
UG/KG
270
u
340
u
470
u
hexachlorobutadiene
UG/KG
270
u
340
u
470
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
270
u
340
u
470
u
HEXACHLOROETHANE
UG/KG
270
u
340
u
470
u
INDENO (1,2,3-CD) PYRENE
UG/KG
270
u
22
J
470
u
ISOPHORONE
UG/KG
270
u
340
u
470
u
MONOBUTYL TIN
UG/KG
150
u
180
u
220
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
270
u
340
u
470
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
270
u
340
u
470
u
naphthalene
UG/KG
34.6
270
u
340
u
470
u
NITROBENZENE
UG/KG
270
u
340
u
470
u
PENTACHLOROPHENOL
UG/KG
540
u
690
u
940
u
PETROLEUM PRODUCT
UG/KG
NR
340
UJ
NR
phenanthrene
UG/KG
86.7
270
u
340
u
470
u
PHENOL
UG/KG
270
u
340
u
470
u
pyrene
UG/KG
153
270
u
36
J
470
u
TETRABUTYL TIN
UG/KG
150
u
180
u
220
u
TRIBUTYL TIN
UG/KG
150
u
180
u
220
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(H)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD117
SD118
SD119
Effects
11/15/97
11/15/97
11/15/97
Value
09:47
11:10
15:45
% MOISTURE
%
66.2
81.5
78.2
(3-AND/OR 4-)METHYLPHENOL
UG/KG
410
U
710
U
590
U
1,2,4-TRICHLOROBENZENE
UG/KG
410
U
710
U
590
u
2 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
20000
J
2,3,4,6-TETRACHLOROPHENOL
UG/KG
410
U
710
U
590
u
2,4,5-TRICHLOROPHENOL
UG/KG
410
U
710
u
590
u
2,4,6-TRICHLOROPHENOL
UG/KG
410
U
710
u
590
u
2,4-DICHLOROPHENOL
UG/KG
410
U
710
u
590
u
2,4-DIMETHYLPHENOL
UG/KG
410
U
710
u
590
u
2,4-DINITROPHENOL
UG/KG
820
U
1400
u
1200
u
2,4-DINITROTOLUENE
UG/KG
410
u
710
u
590
u
2,6-DINITROTOLUENE
UG/KG
410
u
710
u
590
u
2-CHLORONAPHTHALENE
UG/KG
410
u
710
u
590
u
2-CHLOROPHENOL
UG/KG
410
u
710
u
590
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
820
u
1400
u
1200
u
2-METHYLNAPHTHALENE
UG/KG
20.23
410
u
710
u
590
u
2-METHYLPHENOL
UG/KG
410
u
710
u
590
u
2-NITRO ANILINE
UG/KG
410
u
710
u
590
u
2-NITROPHENOL
UG/KG
410
u
710
u
590
u
3,3'-DICHLOROBENZIDINE
UG/KG
410
u
710
u
590
u
3-NITROANILINE
UG/KG
410
u
710
u
590
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
410
u
710
u
590
u
4-CHLORO-3-METHYLPHENOL
UG/KG
410
u
710
u
590
u
4-CHLORO ANILINE
UG/KG
410
u
710
u
590
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
410
u
710
u
590
u
4-NITROANILINE
UG/KG
410
u
710
u
590
u
4-NITROPHENOL
UG/KG
820
u
1400
u
1200
u
ACENAPHTHENE
UG/KG
6.71
410
u
710
u
590
u
ACENAPHTHYLENE
UG/KG
5.87
410
u
710
u
590
u
ANTHRACENE
UG/KG
46.9
410
u
710
u
590
u
BENZO(A)ANTHRACENE
UG/KG
74.8
61
J
39
J
53
J
BENZO(B)FLUORANTHENE
UG/KG
140
J
57
J
110
J
BENZO(GHI)PERYLENE
UG/KG
86
J
74
J
91
J
BENZO(K)FLUORANTHENE
UG/KG
37
J
710
u
64
J
BENZO-A-PYRENE
UG/KG
88.8
75
J
710
u
74
J
BENZYL BUTYL PHTHALATE
UG/KG
650
u
710
u
1600
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
410
u
710
u
590
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
410
u
710
u
590
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
410
u
710
u
590
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
410
u
710
u
590
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
CI FLUORANTHENES/PYRENES
UG/KG
410
UJ
710
UJ
590
UJ
CI FLUORENES
UG/KG
410
UJ
710
UJ
590
UJ
CI NAPHTHALENES
UG/KG
410
UJ
710
UJ
590
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C2 FLUORENES
UG/KG
410
UJ
710
UJ
590
UJ
C2 NAPHTHALENES
UG/KG
410
UJ
710
UJ
590
UJ
-------
Table 5-12(H) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD117
SD118
SD119
Effects
11/15/97
11/15/97
11/15/97
Value
09:47
11:10
15:45
C2 PHENANTHRENES/ANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C3 FLUORENES
UG/KG
410
UJ
710
UJ
590
UJ
C3 NAPHTHALENES
UG/KG
410
UJ
710
UJ
590
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
C4 NAPHTHALENES
UG/KG
410
UJ
710
UJ
590
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
410
UJ
710
UJ
590
UJ
CARBAZOLE
UG/KG
410
U
710
U
590
U
CHRYSENE
UG/KG
108
55
J
50
J
62
J
DI-N-BUTYLPHTHALATE
UG/KG
2900
u
3600
u
3100
u
DI-N-OCTYLPHTHALATE
UG/KG
410
u
710
u
590
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
24
J
710
u
590
u
dibenzofuran
UG/KG
410
u
710
u
590
u
DIBUTYL TIN
UG/KG
200
u
350
u
290
u
DIETHYL PHTHALATE
UG/KG
410
u
710
u
590
u
DIMETHYL PHTHALATE
UG/KG
410
u
710
u
590
u
fluoranthene
UG/KG
113
170
J
320
J
170
J
fluorene
UG/KG
21.2
410
u
710
u
590
u
HEXACHLOROBENZENE(HCB)
UG/KG
410
u
710
u
590
u
HEXACHLOROBUTADIENE
UG/KG
410
u
710
u
590
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
410
u
710
u
590
u
HEXACHLOROETHANE
UG/KG
410
u
710
u
590
u
INDENO (l,2,3-CD) PYRENE
UG/KG
69
J
60
J
77
J
ISOPHORONE
UG/KG
410
u
710
u
590
u
MONOBUTYL TIN
UG/KG
200
u
350
u
290
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
410
u
710
u
590
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
410
u
710
u
590
u
NAPHTHALENE
UG/KG
34.6
410
u
710
u
590
u
nitrobenzene
UG/KG
410
u
710
u
590
u
pentachlorophenol
UG/KG
820
u
1400
u
1200
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
22
J
60
J
32
J
phenol
UG/KG
410
u
710
u
590
u
PYRENE
UG/KG
153
160
J
82
J
110
J
tetrabutyl tin
UG/KG
200
u
350
u
290
u
tributyl tin
UG/KG
200
u
350
u
290
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(1)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD120
SD120A
SD120B
Effects
11/15/97
11/19/97
11/19/97
Value
14:05
10:00
10:00
% MOISTURE
%
75
80.5
63.4
(3-AND/OR 4-)METHYLPHENOL
UG/KG
530 U
600 U
350 U
1,2,4-TRICHLOROBENZENE
UG/KG
530 U
600 U
350 U
2 UNIDENTIFIED COMPOUNDS
UG/KG
9000 J
NR
NR
2,3,4,6-TETRACHLOROPHENOL
UG/KG
530 U
600 U
350 U
2,4,5-TRICHLOROPHENOL
UG/KG
530 U
600 U
350 U
2,4,6-TRICHLOROPHENOL
UG/KG
530 U
600 U
350 U
2,4-DICHLOROPHENOL
UG/KG
530 U
600 U
350 U
2,4-DIMETHYLPHENOL
UG/KG
530 U
600 U
350 U
2,4-DINITROPHENOL
UG/KG
1100 U
1200 U
700 U
2,4-DINITROTOLUENE
UG/KG
530 U
600 U
350 U
2,6-DINITROTOLUENE
UG/KG
530 U
600 U
350 U
2-CHLORONAPHTHALENE
UG/KG
530 U
600 U
350 U
2-CHLOROPHENOL
UG/KG
530 U
600 U
350 U
2-METHYL-4,6-DINITROPHENOL
UG/KG
1100 U
1200 U
700 U
2-METHYLNAPHTHALENE
UG/KG
20.23
530 U
600 U
350 U
2-METHYLPHENOL
UG/KG
530 U
600 U
350 U
2-NITRO ANILINE
UG/KG
530 U
600 U
350 U
2-NITROPHEN OL
UG/KG
530 U
600 U
350 U
3,3'-DICHLOROBENZIDINE
UG/KG
530 U
600 U
350 U
3-NITROANILINE
UG/KG
530 U
600 U
350 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
530 U
600 U
350 U
4-CHLORO-3-METHYLPHENOL
UG/KG
530 U
600 U
350 U
4-CHLORO ANILINE
UG/KG
530 U
600 U
350 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
530 U
600 U
350 U
4-NITROANILINE
UG/KG
530 U
600 U
350 U
4-NITROPHENOL
UG/KG
1100 U
1200 U
700 U
ACENAPHTHENE
UG/KG
6.71
530 U
600 U
350 (J
ACENAPHTHYLENE
UG/KG
5.87
530 U
600 U
350 U
ANTHRACENE
UG/KG
46.9
530 U
600 U
350 U
BENZO(A)ANTHRACENE
UG/KG
74.8
61 J
39 J
42 J
BENZO(B)FLUORANTHENE
UG/KG
210 J
87 J
120 J
BENZO(GHI)PERYLENE
UG/KG
85 J
57 J
49 J
BENZO(K)FLUORANTHENE
UG/KG
45 J
45 J
30 J
BENZO-A-PYRENE
UG/KG
88.8
160 J
33 J
31 J
BENZYL BUTYL PHTHALATE
UG/KG
530 U
600 U
350 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
530 U
600 U
350 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
530 U
600 U
350 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
530 U
600 U
350 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
530 U
600 U
350 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
530 UJ
600 UJ
350 UJ
CI FLUORANTHENES/PYRENES
UG/KG
530 UJ
600 UJ
350 UJ
CI FLUORENES
UG/KG
530 UJ
600 UJ
350 UJ
CI NAPHTHALENES
UG/KG
530 UJ
600 UJ
350 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
530 UJ
600 UJ
350 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
530 UJ
600 UJ
350 UJ
C2FLUORENES
UG/KG
530 UJ
600 UJ
350 UJ
C2 NAPHTHALENES
UG/KG
530 UJ
600 UJ
350 UJ
-------
Table 5-12(1) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYLTIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE(HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
HEXADECANOIC ACID
HEXADECENOIC ACID
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
RAGS
SD120
SD120A
SD120B
Effects
11/15/97
11/19/97
11/19/97
Value
14:05
10:00
10:00
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 UJ
600 UJ
350 UJ
530 U
600 U
350 U
108
77 J
30 J
31 J
3000 U
600 U
350 U
530 U
600 U
350 U
6.22
530 U
600 U
350 U
530 U
600 U
350 U
240 U
300 U
170 U
530 U
600 U
350 U
530 U
600 U
350 U
113
300 J
60 J
80 J
21.2
530 U
600 U
350 U
530 U
600 U
350 U
530 U
600 U
350 U
530 U
600 U
350 U
530 U
600 U
350 U
NR
5000 JN
NR
NR
4000 JN
NR
77 J
51 J
45 J
530 U
600 U
350 U
240 U
300 U
170 U
530 U
600 U
350 U
530 U
600 U
350 U
34.6
530 U
600 U
350 U
530 U
600 U
350 U
1100 U
1200 U
700 U
N
NR
N
86.7
40 J
600 U
350 U
530 U
600 U
350 U
153
200 J
48 J
66 J
240 U
300 U
170 U
240 U
300 U
170 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(J)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD121
SD122
SDI23
Effects
11/15/97
11/15/97
11/15/97
Value
13:35
16:00
13:33
% MOISTURE
%
71.4
82.4
78.5
(3- AND/OR 4-)METHYLPHENOL
UG/KG
430
U
700
U
550
U
1,2,4-TRiCHLOROBENZENE
UG/KG
430
u
700
u
550
U
2 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
10000
J
2, B t4,6-T ETRA CHLOROP HEN OL
UG/KG
430
U
700
U
550
u
2,4,5-TRlCHLOROPHENOL
UG/KG
430
u
700
U
550
u
2,4,6-TRICHLOROPHENOL
UG/KG
430
u
70fJ
U
550
u
2,4-DICHLGRGPHENOL
UG/KG
430
u
70Q
U
550
u
2,4-DIMETHYLPHENOL
UG/KG
430
U
700
U
550
u
2,4-DINITROPH ENOL
UG/KG
870
u
1400
u
1100
u
2,4-D INITROTOLUEN E
UG/KG
430
u
700
u
550
u
2,6-D IN ITROT OLUENE
UG/KG
430
u
700
U
550
u
2-CHLORONAPHTHALENE
UG/KG
430
u
700
u
550
u
2-CHLOROPHENOL
UG/KG
430
u
700
u
550
u
Z-METHYL^^-DINITROPHENOL
UG/KG
870
u
1400
u
1100
u
2-METHYLNAPHTHALENE
UG/KG
20.23
430
u
700
u
550
u
2-METHYLPHENOE
UG/KG
430
u
700
u
550
u
2-NITROANILINE
UG/KG
430
u
700
u
550
u
2-NITROPHENOL
UG/KG
430
u
700
u
550
u
S^-DICHtOROBENZIDrNE
UG/KG
430
u
700
u
550
u
3-NITROANILINE
UG/KG
430
u
700
u
550
u
4 UNIDENTIFIED COMPOUNDS
UG/KG
NR
30000
J
NR
4-BROMOPHENYL PHENYL ETHER
UG/KG
430
U
700
u
550
u
4-CHLGRO-3-METHYLPHENOL
UG/KG
430
u
700
u
550
IJ
4-CHLOROANILIME
UG/KG
430
u
700
u
550
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
430
u
700
u
550
u
4-NITRO ANILINE
UG/KG
430
u
700
u
550
u
4-NITROPHENOL
UG/KG
870
u
1400
u
1100
u
5 LrNlDENTIFIED COMPOUNDS
UG/KG
30000
J
NR
NR
ACENAPHTHENE
UG/KG
6.71
430
u
700
u
550
U
ACENAPHTHYLENE
UG/KG
5.87
430
u
700
u
550
u
ANTHRACENE
UG/KG
46.9
430
u
700
u
550
u
BENZO(A)ANTHRACENE
UG/KG
74,8
37
J
42
J
31
J
BENZO(B)FLUORANTHENE
UG/KG
54
J
81
J
58
J
BEN ZO(GHI)P ER Y L EN E
UG/KG
39
J
70
J
53
J
B£NZO(K)FLUORANTHENE'
UG/KG
24
J
39
J
550
u
BENZ0-A-PYRENE
UG/KG
8&.S
35
i
46
J
42
j
BENZYL BUTYL PHTHALATE
UG/KG
680
u
1100
u
550
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
430
u
700
u
550
u
B1S(2-CHLOROETHYL) ETHER
UG/KG
430
u
700
u
550
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
430
u
700
u
550
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
430
u
700
u
550
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
430
UJ
700
UJ
550
UJ
CI FLUORANTHENES/PYRENES
UG/KG
430
us
700
UJ
550
UJ
CIFLUORENES
UG/KG
430
Ui
700
UJ
550
UJ
CI NAPHTHALENES
UG/KG
430
UJ
700
UJ
550
UJ
CI PHENANTHRENES/ANTHR^CENES
UG/KG
430
UJ
700
UJ
550
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
430
UJ
700
UJ
550
UJ
-------
Table 5-12(J) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD121
SD122
SDI23
Effects
11/15/97
1 1/15/97
11/15/97
Value
13:35
16:00
13:33
02 FLUORENES
UG/KG
430
U J
700
UJ
550
UJ
C2 NAPHTHALENES
UG/KG
430
UJ
700
UJ
550
UJ
02 P H EN AN TH REN ES/A NTH RA CENE. S
UG/KG
430
UJ
700
UJ
550
UJ
C3 CH RYS EN E S/B ENZANT H RA C EN E S
UG/KG
430
UJ
700
UJ
550
UJ
C3 FLUORENES
UG/KG
430
UJ
700
UJ
550
UJ
C3NAPHTHALENES
UG/KG
430
UJ
700
UJ
550
UJ
C3 PH£NANTHRENES/ANTHRACENES
UG/KG
430
UJ
700
UJ
550
UJ
C4 CHRYSENES/BEN2ANTHRACENES
UG/KG
430
UJ
700
UJ
550
UJ
C4 NAPHTHALENES
UG/KG
430
UJ
700
UJ
550
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
430
UJ
700
UJ
550
UJ
CARBAZOLE
UG/KG
430
u
700
u
550
U
CHRYSENE
UG/KG
108
35
J
42
J
31
J
DI-N-B UTYL P H TH A L A TE
UG/KG
2200
u
4600
u
2800
u
DI-N-OCTYLPHTHALATE
UG/KG
430
u
700
u
550
u
DI8ENZO(A,H)ANTHRACENE
UG/KG
6.22
430
u
700
V
550
u
DIBENZOFURAN
UG/KG
430
u
700
u
550
u
DJBUTYL TIN
UG/KG
86
J
350
u
92
J
DIETHYL PHTHALATE
UG/KG
430
u
700
u
550
u
DIMETHYL PHTHALATE
UG/KG
430
u
700
u
550
u
FLUORANTHENE
UG/KG
113
65
J
91
u
69
J
FLUORENE
UG/KG
21.2
430
u
700
u
550
u
HEXACHLOROBENZENE (HCB)
UG/KG
430
u
700
u
550
u
HEXACHLOROBUTADIENE
UG/KG
430
U
700
u
550
u
H EX AC H LOROC Y CLO PENTADI EN E (HCC P)
UG/KG
430
u
700
u
550
u
HEXACHLOROETHANE
UG/KG
430
u
700
u
550
u
H EXADECENOIC ACID
UG/KG
2000
JN
5000
JN
NR
INDENO (1,23-CD) PYRENE
UG/KG
30
J
53
J
44
J
ISOPHORONE
UG/KG
430
u
700
u
550
u
MONOBUTYL TIN
UG/KG
230
u
350
u
270
u
N-NITROSODI-N-P RO P Y L AMIN E
UG/KG
430
u
700
u
550
u
N-NITROSO D r P H EN Y LA M1N E/DIP H EN Y LAM IN E
UG/KG
430
u
700
u
550
u
NAPHTHALENE
UG/KG
34.6
430
u
700
u
550
u
NITROBENZENE
UG/KG
430
u
700
u
550
u
PENTACHLOROPHENOL
UG/KG
870
u
1400
u
itoo
u
PETROLEUM PRODUCT
UG/KG
NR
N
N
PHENANTHRENE
UG/KG
8&7
430
u
700
u
550
u
PHENOL
UG/KG
430
u
700
u
550
u
PYRENE
UG/KG
153
46
J
63
J
53
J
TETRA BUTYL TIN
UG/KG
230
u
350
u
270
u
TRIBUTYL TIN
UG/KG
230
u
350
u
270
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note; Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(K)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD123DUP
SD124
SD125
Effects
11/15/97
11/15/97
11/15/97
Value
13:35
14:33
15:25
% MOISTURE
%
66.4
73.9
81.2
(3-AND/OR 4-)METHYLPHENOL
UG/KG
370
U
520
U
700
u
1 UNIDENTIFIED COMPOUND
UG/KG
2000
J
5000
J
6000
J
1,2,4-TRICHLOROBENZENE
UG/KG
370
u
520
u
700
u
2,3,4,6-TETRACHLOROPHENOL
UG/KG
370
u
520
u
700
u
2,4,5-TRICHLOROPHENOL
UG/KG
370
u
520
u
700
u
2,4,6-TRICHLOROPHENOL
UG/KG
370
u
520
u
700
u
2,4-DICHLOROPHENOL
UG/KG
370
u
520
u
700
u
2,4-DIMETHYLPHENOL
UG/KG
370
u
520
u
700
u
2,4-DINITROPHENOL
UG/KG
740
u
1000
u
1400
u
2,4-DINITROTOLUENE
UG/KG
370
u
520
u
700
u
2,6-DINITROTOLUENE
UG/KG
370
u
520
u
700
u
2-CHLORONAPHTHALENE
UG/KG
370
u
520
u
700
u
2-CHLOROPHENOL
UG/KG
370
u
520
u
700
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
740
u
1000
u
1400
u
2-METHYLN APHTH ALEN E
UG/KG
20.23
370
u
520
u
700
u
2-METHYLPHENOL
UG/KG
370
u
520
u
700
u
2-NITROANILINE
UG/KG
370
u
520
u
700
u
2-NITROPHENOL
UG/KG
370
u
520
u
700
u
3,3'-DICHLOROBENZIDINE
UG/KG
370
u
520
u
700
u
3-NITROANILINE
UG/KG
370
u
520
u
700
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
370
u
520
u
700
u
4-CHLORO-3-METH YLPH EN OL
UG/KG
370
u
520
u
700
u
4-CHLOROANILINE
UG/KG
370
u
520
u
700
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
370
u
520
u
700
u
4-NITROANILINE
UG/KG
370
u
520
u
700
u
4-NITROPHENOL
UG/KG
740
u
1000
u
1400
u
ACENAPHTHENE
UG/KG
6.71
370
u
520
u
700
u
ACENAPHTHYLENE
UG/KG
5.87
370
u
520
u
700
u
ANTHRACENE
UG/KG
46.9
370
u
520
u
700
u
BENZO(A)ANTHRACENE
UG/KG
74.8
26
J
81
J
42
J
BENZO(B)FLUORANTHENE
UG/KG
46
J
100
J
67
J
BENZO(GHI)PERYLENE
UG/KG
39
J
76
J
74
J
BENZO(K)FLUORANTHENE
UG/KG
24
J
47
J
35
J
BENZO-A-PYRENE
UG/KG
88.8
30
J
63
J
46
J
BENZYL BUTYL PHTHALATE
UG/KG
460
u
520
u
700
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
370
u
520
u
700
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
370
u
520
u
700
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
370
u
520
u
700
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
370
u
520
u
700
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
CI FLUORANTHENES/PYRENES
UG/KG
370
UJ
520
UJ
700
UJ
CI FLUORENES
UG/KG
370
UJ
520
UJ
700
UJ
CI NAPHTHALENES
UG/KG
370
UJ
520
UJ
700
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C2FLUORENES
UG/KG
370
UJ
520
UJ
700
UJ
C2 NAPHTHALENES
UG/KG
370
UJ
520
UJ
700
UJ
-------
Table 5-12(K) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD123DUP
SD124
SD125
Effects
11/15/97
11/15/97
U/15/97
Value
13:35
14:33
15:25
C2 PHENANTHRENES/ANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C3FLUORENES
UG/KG
370
UJ
520
UJ
700
UJ
C3 NAPHTHALENES
UG/KG
370
UJ
520
UJ
700
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
C4 NAPHTHALENES
UG/KG
370
UJ
520
UJ
700
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
370
UJ
520
UJ
700
UJ
CARBAZOLE
UG/KG
370
u
520
u
700
U
CHRYSENE
UG/KG
108
20
J
50
J
39
J
DI-N-BUTYLPHTHALATE
UG/KG
2200
u
3300
u
4500
u
DI-N -OCTYLPHTH AL ATE
UG/KG
370
u
520
U
700
U
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
370
u
520
u
700
u
DIBENZOFURAN
UG/KG
370
u
520
u
700
U
dibutyl TIN
UG/KG
190
u
260
u
320
U
diethyl PHTHALATE
UG/KG
370
u
520
u
700
u
DIMETHYL PHTHALATE
UG/KG
370
u
520
U
700
u
FLUORANTHENE
UG/KG
113
57
J
110
J
88
J
FLUORENE
UG/KG
21.2
370
u
520
u
700
u
HEXACHLOROBENZENE (HCB)
UG/KG
370
u
520
U
700
u
HEXACHLOROBUTADIENE
UG/KG
370
u
520
u
700
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
370
u
520
u
700
u
HEXACHLOROETHANE
UG/KG
370
u
520
u
700
u
HEXADECENOIC ACID
UG/KG
4000
JN
4000
JN
5000
JN
INDENO (1,2,3-CD) PYRENE
UG/KG
31
J
63
J
56
J
ISOPHORONE
UG/KG
370
u
520
u
700
u
MONOBUTYL TIN
UG/KG
190
u
260
u
320
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
370
u
520
u
700
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
370
u
520
u
700
u
NAPHTHALENE
UG/KG
34.6
370
u
520
u
700
u
NITROBENZENE
UG/KG
370
u
520
u
700
u
octadecenoic ACID
UG/KG
2000
JN
3000
JN
6000
IN
pentachlorophenol
UG/KG
740
u
1000
u
1400
u
petroleum product
UG/KG
NR
N
N
phenanthrene
UG/KG
86.7
370
u
26
J
700
U
phenol
UG/KG
370
u
520
u
700
U
pyrene
UG/KG
153
41
J
80
J
60
J
tetrabutyl tin
UG/KG
190
u
260
u
320
u
tributyl tin
UG/KG
190
u
260
u
320
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-12(L)
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD126
SD127
SD128
Effects
11/15/97
11/15/97
11/16/97
Value
16:00
16:28
09:10
% MOISTURE
%
83.2
70.2
73.6
(3-AND/OR 4-)METHYLPHENOL
UG/KG
750
U
450
u
480
U
1,2,4-TRlCHLOROBENZENE
UG/KG
750
U
450
u
480
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
750
u
450
u
480
U
2,4,5-TRICHLOROPHENOL
UG/KG
750
u
450
u
480
U
2,4,6-TRICHLOROPHENOL
UG/KG
750
u
450
u
480
U
2,4-DICHLOROPHENOL
UG/KG
750
u
450
u
480
U
2,4-DIMETHYLPHENOL
UG/KG
750
u
450
u
480
U
2,4-DINITROPH EN OL
UG/KG
1500
u
900
u
970
U
2,4-DINITROTOLUENE
UG/KG
750
u
450
u
480
U
2,6-DINITROTOLUENE
UG/KG
750
u
450
u
480
U
2-CHLORONAPHTHALENE
UG/KG
750
u
450
u
480
U
2-CHLOROPHENOL
UG/KG
750
u
450
u
480
U
2-METHYL-4,6-DINITROPHENOL
UG/KG
1500
u
900
u
970
U
2-METHYLNAPHTHALENE
UG/KG
20.23
750
u
450
u
480
u
2-METHYLPHENOL
UG/KG
750
u
450
u
480
U
2-NITROANILINE
UG/KG
750
u
450
u
480
u
2-NITROPHENOL
UG/KG
750
u
450
u
480
u
3 UNIDENTIFIED COMPOUNDS
UG/KG
NR
20000
J
NR
3,3'-DICHLOROBENZIDINE
UG/KG
750
u
450
u
480
U
3-N1TRO ANILINE
UG/KG
750
u
450
u
480
U
4-BROMOPHENYL PHENYL ETHER
UG/KG
750
u
450
u
480
U
4-CHLORO-3 -METH YLPHENOL
UG/KG
750
u
450
u
480
U
4-CHLOROANILINE
UG/KG
750
u
450
u
480
U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
750
u
450
u
480
U
4-NITROANILINE
UG/KG
750
u
450
u
480
u
4-NITROPHENOL
UG/KG
1500
u
900
u
970
u
8 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
70000
J
ACENAPHTHENE
UG/KG
6.71
750
U
450
u
480
u
ACENAPHTHYLENE
UG/KG
5.87
750
V
450
u
480
u
ANTHRACENE
UG/KG
46.9
750
u
450
u
480
u
B EN ZO( A) ANTHRAC EN E
UG/KG
74.8
64
J
52
J
46
J
BENZO(B)FLUORANTHENE
UG/KG
120
J
70
J
84
J
BENZO(GHI)PERYLENE
UG/KG
98
J
52
J
63
J
BENZO(K)FLUORANTHENE
UG/KG
56
J
41
J
58
J
BENZO-A-PYRENE
UG/KG
88.8
83
J
52
J
56
J
BENZYL BUTYL PHTHALATE
UG/KG
750
u
450
u
480
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
750
u
450
u
480
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
750
u
450
u
480
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
750
u
450
u
480
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
1100
u
450
u
480
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
CI FLUORANTHENES/PYRENES
UG/KG
750
UJ
450
UJ
480
UJ
CI FLUORENES
UG/KG
750
UJ
450
UJ
480
UJ
CI NAPHTHALENES
UG/KG
750
UJ
450
UJ
480
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C2FLUORENES
UG/KG
750
UJ
450
UJ
480
UJ
-------
Table 5-12(L) - Continued
Sediment Analytical Results - Extractables
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD126
SD127
SD128
Effects
11/15/97
11/15/97
11/16/97
Value
16:00
16:28
09:10
C2 NAPHTHALENES
UG/KG
750
UJ
450
UJ
480
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C3FLUORENES
UG/KG
750
UJ
450
UJ
480
UJ
C3 NAPHTHALENES
UG/KG
750
UJ
450
UJ
480
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
C4 NAPHTHALENES
UG/KG
750
UJ
450
UJ
480
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
750
UJ
450
UJ
480
UJ
CARBAZOLE
UG/KG
750
U
450
u
480
U
CHRYSENE
UG/KG
108
64
J
34
J
43
J
DI-N-BUTYLPHTHALATE
UG/KG
3400
U
2900
u
4400
u
DI-N-OCTYLPHTHALATE
UG/KG
750
u
450
u
480
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
750
u
450
u
24
J
DIBENZOFURAN
UG/KG
750
u
450
u
480
u
DIBUTYL TIN
UG/KG
400
u
250
u
250
u
DIETHYL PHTHALATE
UG/KG
750
u
450
u
480
u
DIMETHYL PHTHALATE
UG/KG
750
u
450
u
480
u
FLUORANTHENE
UG/KG
113
310
J
90
J
130
J
FLUORENE
UG/KG
21.2
750
u
450
u
480
u
HEXACHLOROBENZENE (HCB)
UG/KG
750
u
450
u
480
u
HEXACHLOROBUTADIENE
UG/KG
750
u
450
u
480
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
750
u
450
u
480
u
HEXACHLOROETHANE
UG/KG
750
u
450
u
480
u
INDENO (1,2,3-CD) PYRENE
UG/KG
83
J
41
J
48
J
ISOPHORONE
UG/KG
750
u
450
u
480
u
MONOBUTYL TIN
UG/KG
400
u
250
u
250
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
750
u
450
u
480
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
750
u
450
u
480
u
NAPHTHALENE
UG/KG
34.6
750
u
450
u
480
u
NITROBENZENE
UG/KG
750
u
450
u
480
u
PENTACHLOROPHENOL
UG/KG
1500
u
900
u
970
u
PETROLEUM PRODUCT
UG/KG
N
N
NR
PHENANTHRENE
UG/KG
86.7
49
J
22
J
31
J
phenol
UG/KG
750
u
450
u
480
u
PYRENE
UG/KG
153
120
J
54
J
84
J
TETRABUTYL TIN
UG/KG
400
u
250
u
250
u
TRIBUTYL TIN
UG/KG
400
u
250
u
250
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(A)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD202
SD203
SD204
Effects
11/14/97
11/13/97
11/13/97
Values
11:30
15:10
16:02
% MOISTURE
%
69.4
71.3
79.2
(3-AND/OR 4-)METHYLPHENOL
UG/KG
380 U
590 U
600 U
1,2,4-TRICHLOROBENZENE
UG/KG
380 U
590 U
600 U
2 UNIDENTIFIED COMPOUNDS
UG/KG
6000 J
NR
NR
2,3,4,6-TETRACHLOROPHENOL
UG/KG
380 U
590 U
600 U
2,4,5-TRICHLOROPHENOL
UG/KG
380 U
590 U
600 U
2,4,6-TRICHLOROPHENOL
UG/KG
380 U
590 U
600 U
2,4-DICHLOROPHENOL
UG/KG
380 U
590 U
600 U
2,4-DIMETHYLPHENOL
UG/KG
380 U
590 U
600 U
2,4-DINITROPHENOL
UG/KG
760 U
1200 U
1200 U
2,4-DINITROTOLUENE
UG/KG
380 U
590 U
600 U
2,6-DINITROTOLUENE
UG/KG
380 U
590 U
600 U
2-CHLORONAPHTHALENE
UG/KG
380 U
590 U
600 U
2-CHLOROPHENOL
UG/KG
380 U
590 U
600 U
2-METHYL-4,6-DlNITROPHENOL
UG/KG
760 U
1200 U
1200 U
2-METHYLNAPHTHALENE
UG/KG
20.23
380 U
590 U
600 U
2-METHYLPHENOL
UG/KG
380 U
590 U
600 U
2-NITRO ANILINE
UG/KG
380 U
590 U
600 U
2-NITROPHENOL
UG/KG
380 U
590 U
600 U
3 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
40000 J
3,3'-DICHLOROBENZIDINE
UG/KG
380 U
590 U
600 U
3-NITROANILINE
UG/KG
380 U
590 U
600 U
4 UNIDENTIFIED COMPOUNDS
UG/KG
NR
20000 J
NR
4-BROMOPHENYL PHENYL ETHER
UG/KG
380 U
590 U
600 U
4-CHLORO-3-METHYLPHENOL
UG/KG
380 U
590 U
600 U
4-CHLOROANILINE
UG/KG
380 U
590 U
600 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
380 U
590 U
600 U
4-N1TROANILINE
UG/KG
380 U
590 U
600 U
4-NITROPHENOL
UG/KG
760 U
1200 U
1200 U
ACENAPHTHENE
UG/KG
6.71
380 U
590 U
600 U
ACENAPHTHYLENE
UG/KG
5.87
380 U
590 U
600 U
ANTHRACENE
UG/KG
46.9
380 U
590 U
600 U
BENZO(A)ANTHRACENE
UG/KG
74.8
59 ;
74 J
78 J
BENZO(B)FLUORANTHENE
UG/KG
89 J
74 J
140 J
BENZO(GHI)PERYLENE
UG/KG
87 J
120 J
84 J
BENZO(K)FLUORANTHENE
UG/KG
87 J
80 J
110 J
BENZO-A-PYRENE
UG/KG
88.8
49 J
71 J
66 J
BENZOFLUORENONE
UG/KG
NR
-6000 JN
NR
BENZYL BUTYL PHTHALATE
UG/KG
380 U
590 U
600 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
380 U
590 U
600 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
380 U
590 U
600 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
380 U
590 U
600 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
380 U
590 U
600 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
380 UJ
590 UJ
600 UJ
CI FLUORANTHENES/PYRENES
UG/KG
380 UJ
590 UJ
600 UJ
CI FLUORENES
UG/KG
380 UJ
590 UJ
600 UJ
CI NAPHTHALENES
UG/KG
380 UJ
590 UJ
600 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
380 UJ
590 UJ
600 UJ
-------
Table 5-13(A) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD202
SD203
SD204
Effects
11/14/97
11/13/97
11/13/97
Values
11:30
15:10
16:02
C2 CHRYSENES/BENZANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
C2FLUORENES
UG/KG
380
UJ
590
UJ
600
UJ
C2 NAPHTHALENES
UG/KG
380
UJ
590
UJ
600
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
C3 FLUORENES
UG/KG
380
UJ
590
UJ
600
UJ
C3NAPHTHALENES
UG/KG
380
UJ
590
UJ
600
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
C4NAPHTHALENES
UG/KG
380
UJ
590
UJ
600
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
380
UJ
590
UJ
600
UJ
CARBAZOLE
UG/KG
380
U
590
U
600
U
CHRYSENE
UG/KG
108
42
J
44
J
42
J
DI-N-BUTYLPHTHALATE
UG/KG
1600
U
3100
U
3200
U
DI-N-OCTYLPHTHALATE
UG/KG
380
u
590
u
600
U
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
36
J
41
J
33
J
D1BENZOFURAN
UG/KG
380
u
590
u
600
u
DIBUTYL TIN
UG/KG
220
u
300
u
300
u
DIETHYL PHTHALATE
UG/KG
380
u
590
u
600
u
DIMETHYL PHTHALATE
UG/KG
380
u
590
u
600
u
FLUORANTHENE
UG/KG
113
160
J
240
J
220
J
FLUORENE
UG/KG
21.2
380
u
590
u
600
u
HEXACHLOROBENZENE(HCB)
UG/KG
380
u
590
u
600
u
HEXACHLOROBUTADIENE
UG/KG
380
u
590
u
600
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
380
u
590
u
600
u
HEXACHLOROETHANE
UG/KG
380
u
590
u
600
u
INDENO (1,2,3-CD) PYRENE
UG/KG
62
J
92
J
72
J
ISOPHORONE
UG/KG
380
u
590
u
600
u
MONOBUTYL TIN
UG/KG
220
u
300
u
300
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
380
u
590
u
600
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMrNE
UG/KG
380
u
590
u
600
u
NAPHTHALENE
UG/KG
34.6
380
u
590
u
600
u
NITROBENZENE
UG/KG
380
u
590
u
600
u
PENTACHLOROPHENOL
UG/KG
760
u
1200
u
1200
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
380
u
590
u
600
u
PHENOL
UG/KG
380
u
590
u
600
u
PYRENE
UG/KG
153
100
J
140
J
140
J
TETRABUTYL TIN
UG/KG
220
u
300
u
300
u
TRIBUTYL TIN
UG/KG
220
u
300
u
300
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(B)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD205
SD205
SD206
SD206DUP
Effects
11/14/97
11/15/97
11/14/97
11/14/97
Values
16:20
09:50
10:05
10:10
% MOISTURE
%
55.2
77.5
79.9
78.7
(3-AND/OR 4-)METHYLPHENOL
UG/KG
270
U
570
U
620
U
570
U
1 UNIDENTIFIED COMPOUND
UG/KG
6000
J
NR
NR
NR
1,2,4-TRICHLOROBENZENE
UG/KG
270
u
570
U
620
U
570
U
2 UNIDENTIFIED COMPOUNDS
UG/KG
NR
20000
JN
NR
20000
J
2,3,4,6-TETRACHLOROPHENOL
UG/KG
270
U
570
u
620
U
570
U
2,4,5-TRICHLOROPHENOL
UG/KG
270
u
570
u
620
U
570
u
2,4,6-TRICHLOROPHENOL
UG/KG
270
u
570
u
620
U
570
u
2,4-DICHLOROPHENOL
UG/KG
270
u
570
u
620
U
570
u
2,4-DIMETHYLPHENOL
UG/KG
270
u
570
u
620
U
570
u
2,4-DINITROPHENOL
UG/KG
540
u
1100
u
1200
U
1100
u
2,4-DINITROTOLUENE
UG/KG
270
u
570
u
620
u
570
u
2,6-DINITROTOLUENE
UG/KG
270
u
570
u
620
u
570
u
2-CHLORONAPHTHALENE
UG/KG
270
u
570
u
620
u
570
u
2-CHLOROPHENOL
UG/KG
270
u
570
u
620
u
570
u
2-METHYL-4.6-DINITROPHENOL
UG/KG
540
u
1100
u
1200
u
1100
u
2-METHYLNAPHTHALENE
UG/KG
20.23
270
u
570
u
620
u
570
u
2-METHYLPHENOL
UG/KG
270
u
570
u
620
u
570
u
2-NITRO ANILINE
UG/KG
270
u
570
u
620
u
570
u
2-NITROPHENOL
UG/KG
270
u
570
u
620
u
570
u
3 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
30000
J
NR
3,3'-DICHLOROBENZIDINE
UG/KG
270
u
570
u
620
u
570
u
3-NITROANILINE
UG/KG
270
u
570
u
620
u
570
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
270
u
570
u
620
u
570
u
4-CHLORO-3-METHYLPHENOL
UG/KG
270
u
570
u
620
u
570
u
4-CHLORO ANILINE
UG/KG
270
u
570
u
620
u
570
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
270
u
570
u
620
u
570
u
4-NITRO ANILINE
UG/KG
270
u
570
u
620
u
570
u
4-NITROPHENOL
UG/KG
540
u
1100
u
1200
u
1100
u
ACENAPHTHENE
UG/KG
6,71
270
u
570
u
620
u
570
u
ACENAPHTHYLENE
UG/KG
5.87
270
u
570
u
620
u
570
u
ANTHRACENE
UG/KG
46,9
24
J
570
u
40
J
40
J
BENZO(A)ANTHRACENE
UG/KG
74.8
59
J
65
J
80
J
74
J
BENZO(B)FLUORANTHENE
UG/KG
83
J
130
J
150
J
110
J
BENZO(GHI)PERYLENE
UG/KG
78
J
96
J
130
J
120
J
BENZO(K)FLUORANTHENE
UG/KG
150
J
37
J
130
J
220
J
BENZO-A-PYRENE
UG/KG
88.8
67
J
91
J
86
J
79
J
BENZYL BUTYL PHTHALATE
UG/KG
740
u
1500
u
1900
u
1200
u
BIS(2-CHLOROETHOXY)METHAN E
UG/KG
270
u
570
u
620
u
570
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
270
u
570
u
620
u
570
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
270
u
570
u
620
u
570
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
270
u
570
u
620
u
570
(J
CI CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
CI FLUORANTHENES/PYRENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
CI FLUORENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
CI NAPHTHALENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
-------
Table 5-13(B) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD205
SD205
SD206
SD206DUP
Effects
11/14/97
11/15/97
11/14/97
11/14/97
Values
16:20
09:50
10:05
10:10
C2 FLUORENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C2 NAPHTHALENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C3FLUORENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C3 NAPHTHALENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C4 NAPHTHALENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
270
UJ
570
UJ
620
UJ
570
UJ
CARBAZOLE
UG/KG
270
u
570
u
620
u
570
U
CHRYSENE
UG/KG
108
93
J
59
J
150
J
150
J
Dl-N-BUTYLPHTHALATE
UG/KG
1600
u
2900
u
4200
u
3100
u
Dl-N-OCTYLPHTHALATE
UG/KG
270
u
570
u
620
u
570
u
D1BENZ0(A,H)ANTHRACENE
UG/KG
6.22
30
J
570
u
43
J
45
J
dibenzofuran
UG/KG
270
u
570
u
620
u
570
u
dibutyl tin
UG/KG
120
u
270
u
330
u
330
u
DIETHYL PHTHALATE
UG/KG
270
u
570
u
620
u
570
u
DIMETHYL PHTHALATE
UG/KG
270
u
570
u
620
u
570
u
DODECANOIC ACID, HEXADECYL ESTER
UG/KG
1000
JN
NR
3000
JN
NR
fluoranthene
UG/KG
113
210
J
250
J
280
J
260
J
fluorene
UG/KG
21.2
270
u
570
u
620
u
570
u
HEXACHLOROBENZENE(HCB)
UG/KG
270
u
570
u
620
u
570
u
HEXACHLOROBUTADIENE
UG/KG
270
u
570
u
620
u
570
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
270
u
570
u
620
u
570
u
HEXACHLOROETHANE
UG/KG
270
u
570
u
620
u
570
u
1NDENO (1,2,3-CD) PYRENE
UG/KG
67
J
82
J
110
J
100
J
ISOPHORONE
UG/KG
270
u
570
u
620
u
570
u
MONOBUTYL TIN
UG/KG
120
u
270
u
330
u
330
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
270
u
570
u
620
u
570
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
270
u
570
u
620
u
570
u
naphthalene
UG/KG
34.6
270
u
570
u
620
u
570
u
NITROBENZENE
UG/KG
270
u
570
u
620
u
570
u
PENTACHLOROPHENOL
UG/KG
540
u
1100
u
1200
u
1100
u
PETROLEUM PRODUCT
UG/KG
N
N
N
N
PHENANTHRENE
UG/KG
86.7
26
J
40
J
55
J
57
J
PHENOL
UG/KG
270
u
570
u
620
u
570
u
PYRENE
UG/KG
153
140
J
140
J
160
J
140
J
TETRABUTYL TIN
UG/KG
120
u
270
u
330
u
330
u
TRIBUTYL TIN
UG/KG
120
u
270
u
330
u
330
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(C)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD207
SD208
SD209
Effects
11/14/97
11/15/97
U/15/97
Values
12:25
15:15
10:25
% MOISTURE
%
81.4
80.4
77.6
(3-AND/OR 4-)METHYLPHENOL
UG/KG
710 U
710 U
560 U
1,2,4-TRICHLOROBENZENE
UG/KG
710 U
710 U
560 U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
710 U
710 U
560 U
2,4,5-TRICHLOROPHENOL
UG/KG
710 U
710 U
560 U
2,4,6-TRICHLOROPHENOL
UG/KG
710 U
710 U
560 U
2,4-DICHLOROPHENOL
UG/KG
710 U
710 U
560 U
2,4-DIMETHYLPHENOL
UG/KG
710 U
710 U
560 U
2,4-DINITROPHENOL
UG/KG
1400 U
1400 U
1100 U
2,4-DINITROTOLUENE
UG/KG
710 U
710 U
560 U
2,6-DINITROTOLUENE
UG/KG
710 U
710 U
560 U
2-CHLORONAPHTHALENE
UG/KG
710 U
710 U
560 U
2-CHLOROPHENOL
UG/KG
710 U
710 U
560 U
2-METHYL-4,6-DINITROPHENOL
UG/KG
1400 U
1400 U
1100 U
2-METHYLNAPHTHALENE
UG/KG
20.23
710 U
710 V
560 U
2-METHYLPHENOL
UG/KG
710 U
710 U
560 U
2-NITROANILINE
UG/KG
710 U
710 U
560 U
2-NITROPHENOL
UG/KG
710 U
710 U
560 U
3,3'-DICHLOROBEN2IDINE
UG/KG
710 U
710 U
560 U
3-NITROANILINE
UG/KG
710 U
710 U
560 U
4 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
40000 J
4-BROMOPHENYL PHENYL ETHER
UG/KG
710 U
710 U
560 U
4-CHLORO-3-METHYLPHENOL
UG/KG
710 U
710 U
560 U
4-CHLOROANILINE
UG/KG
710 U
710 U
560 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
710 U
710 U
560 U
4-NITRO ANILINE
UG/KG
710 U
710 U
560 U
4-NITROPHENOL
UG/KG
1400 U
1400 U
1100 U
5 UNIDENTIFIED COMPOUNDS
UG/KG
60000 J
NR
NR
ACENAPHTHENE
UG/KG
6.71
710 U
710 U
560 V
ACENAPHTHYLENE
UG/KG
5.87
710 V
710 U
560 U
ANTHRACENE
UG/KG
46.9
710 U
710 U
560 U
BENZO(A)ANTHRACENE
UG/KG
74.8
710 U
78 J
81 J
BENZO(B)FLUORANTHENE
UG/KG
220 J
120 J
150 J
BENZO(GHI)PERYLENE
UG/KG
190 J
140 J
140 J
BENZO(K)FLUORANTHENE
UG/KG
140 J
78 J
50 J
BENZO-A-PYRENE
UG/KG
88.8
150 J
54 J
70 J
BENZYL BUTYL PHTHALATE
UG/KG
1900 U
710 U
1200 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
710 U
710 U
560 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
710 U
710 U
560 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
710 U
710 U
560 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
710 U
1700 U
560 U
B1S(DIMETHYLETHYL)PHENANTHRENE
UG/KG
10000 JN
NR
NR
CI CHRYSENES/BENZANTHRACENES
UG/KG
710 UJ
710 UJ
560 UJ
CI FLUORANTHENES/PYRENES
UG/KG
710 UJ
710 UJ
560 UJ
CI FLUORENES
UG/KG
710 UJ
710 UJ
560 UJ
CI NAPHTHALENES
UG/KG
710 UJ
710 UJ
560 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
710 UJ
710 UJ
560 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
710 UJ
710 UJ
560 UJ
-------
Table 5-13(C) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 FLUORENES
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DESLUPENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
D1BUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TR1BUTYL TIN
RAGS
SD207
SD208
SD209
Effects
11/14/97
11/15/97
11/15/97
Values
12:25
15:15
10:25
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
UJ
710
UJ
560
UJ
UG/KG
710
u
710
u
560
u
UG/KG
108
710
u
74
J
81
J
UG/KG
10000
JN
NR
NR
UG/KG
5100
U
4100
u
1800
U
UG/KG
710
U
710
u
560
U
UG/KG
6.22
60
J
710
u
560
u
UG/KG
710
U
710
u
560
U
UG/KG
340
u
330
u
280
u
UG/KG
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
113
320
J
380
J
220
J
UG/KG
21.2
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
150
J
100
J
100
J
UG/KG
710
u
710
u
560
u
UG/KG
340
u
330
u
280
u
UG/KG
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
34.6
710
u
710
u
560
u
UG/KG
710
u
710
u
560
u
UG/KG
1400
u
1400
u
1100
u
UG/KG
N
N
N
UG/KG
86.7
46
J
710
u
45
J
UG/KG
710
u
710
u
560
u
UG/KG
153
340
J
160
J
150
J
UG/KG
340
u
330
u
280
u
UG/KG
340
u
330
u
280
u
N°te: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(D)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1 UNIDENTIFIED COMPOUND
1.2.4-TRJCHLOROBENZENE
2 UNIDENTIFIED COMPOUNDS
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRlCHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DlMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITRO ANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BlS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CIFLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2 FLUORENES
RAGS
SD210
SD211
SD211A
Effects
11/15/97
11/15/97
11/19/97
Values
13:20
13:32
14:00
%
68.6
82.5
79.2
UG/KG
630 U
750 U
610 U
UG/KG
NR
20000 J
20000 JN
UG/KG
630 U
750 U
610 U
UG/KG
20000 J
NR
NR
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
1300 U
1500 U
1200 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
1300 U
1500 U
1200 U
UG/KG
20.23
630 V
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
1300 U
1500 U
1200 U
UG/KG
6.71
630 U
750 U
610 U
UG/KG
5.87
630 U
750 U
610 U
UG/KG
46.9
630 U
45 J
52 J
UG/KG
74.8
130 J
110 J
140 J
UG/KG
130 J
160 J
300 J
UG/KG
140 J
150 J
150 J
UG/KG
32 J
90 J
92 J
UG/KG
88.8
73 J
71 J
110 J
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
630 U
750 U
610 U
UG/KG
182
630 U
3600 U
3200 U
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
UG/KG
630 UJ
750 UJ
610 UJ
-------
Table 5-13(D) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD210
SD211
SD2UA
Effects
11/15/97
11/15/97
11/19/97
Values
13:20
13:32
14:00
C2NAPHTHALENES
UG/KG
630
UJ
750
UJ
610
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/ICG
630
UJ
750
UJ
610
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
630
UJ
750
UJ
610
UJ
C3 FLUORENES
UG/KG
630
UJ
750
UJ
610
UJ
C3 NAPHTHALENES
UG/KG
630
UJ
750
UJ
610
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
630
UJ
750
UJ
610
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
630
UJ
750
UJ
610
UJ
C4 NAPHTHALENES
UG/KG
630
UJ
750
UJ
610
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
630
UJ
750
UJ
610
UJ
CARBAZOLE
UG/KG
630
U
750
U
610
U
CHRYSENE
UG/KG
108
110
J
120
J
130
J
DI-N-BUTYLPHTHALATE
UG/KG
2600
u
4400
u
610
u
DI-N-OCTYLPHTHALATE
UG/KG
630
u
750
u
610
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
41
J
45
J
49
J
DIBENZOFURAN
UG/KG
630
u
750
u
610
u
D1BUTYL TIN
UG/KG
340
u
370
u
100
J
DIETHYL PHTHALATE
UG/KG
630
u
750
u
610
u
DIMETHYL PHTHALATE
UG/KG
630
u
750
u
610
u
FLUORANTHENE
UG/KG
113
300
J
520
J
560
J
FLUORENE
UG/KG
21.2
630
u
750
u
610
u
HEXACHLOROBENZENE(HCB)
UG/KG
630
u
750
u
610
u
HEXACHLOROBUTADIENE
UG/KG
630
u
750
u
610
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
630
u
750
u
610
u
HEXACHLOROETHANE
UG/KG
630
u
750
u
610
u
INDENO (1,2,3-CD) PYRENE
UG/KG
110
J
130
J
130
J
ISOPHORONE
UG/KG
630
u
750
u
610
u
MONOBUTYL TIN
UG/KG
340
u
370
u
290
u
N-NITROSODI-N-PROPYLAM1NE
UG/KG
630
u
750
u
610
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
630
u
750
u
610
u
NAPHTHALENE
UG/KG
34.6
630
u
750
V
610
u
NITROBENZENE
UG/KG
630
u
750
u
610
u
PENTACHLOROPHENOL
UG/KG
1300
u
1500
u
1200
u
PETROLEUM PRODUCT
UG/KG
N
N
NR
PHENANTHRENE
UG/KG
86.7
110
J
93
J
52
J
PHENOL
UG/KG
630
u
750
u
610
u
PYRENE
UG/KG
153
220
J
240
J
290
J
TETRABUTYL TIN
UG/KG
340
u
370
u
290
u
TRIBUTYL TIN
UG/KG
340
u
370
u
290
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(E)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD211B
SD212
SD213
Effects
11/19/97
11/15/97
11/15/97
Values
14:05
13:50
13:18
% MOISTURE
%
67.4
71.7
74.2
(3-AND/OR 4-)METHYLPHENOL
UG/KG
360
U
460
U
490
U
1 UNIDENTIFIED COMPOUND
UG/KG
NR
NR
3000
J
1,2,4-TRICHLOROBENZENE
UG/KG
360
U
460
U
490
U
2 UNIDENTIFIED COMPOUNDS
UG/KG
4000
J
NR
NR
2,3,4,6-TETRACHLOROPHENOL
UG/KG
360
u
460
U
490
U
2,4,5-TRICHLOROPHENOL
UG/KG
360
u
460
u
490
U
2,4,6-TRICHLOROPHENOL
UG/KG
360
u
460
u
490
U
2,4-DICHLOROPHENOL
UG/KG
360
u
460
u
490
U
2,4-DIMETHYLPHENOL
UG/KG
360
u
460
u
490
U
2,4-DINITROPHENOL
UG/KG
720
u
920
u
980
u
2,4-DINITROTOLUENE
UG/KG
360
u
460
u
490
u
2,6-DINITROTOLUENE
UG/KG
360
u
460
u
490
u
2-CHLORONAPHTHALENE
UG/KG
360
u
460
u
490
u
2-CHLOROPHENOL
UG/KG
360
u
460
u
490
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
720
u
920
u
980
u
2-METHYLNAPHTHALENE
UG/KG
20.23
360
u
460
u
490
u
2-METHYLPHENOL
UG/KG
360
u
460
u
490
u
2-NITROANILINE
UG/KG
360
u
460
u
490
u
2-NITROPHENOL
UG/KG
360
u
460
u
490
u
3,3'-DICHLOROBENZIDINE
UG/KG
360
u
460
u
490
u
3-NITROANILINE
UG/KG
360
u
460
u
490
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
360
u
460
u
490
u
4-CHLORO-3-METHYLPHENOL
UG/KG
360
u
460
u
490
u
4-CHLORO ANILINE
UG/KG
360
u
460
u
490
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
360
u
460
u
490
u
4-NITRO ANILINE
UG/KG
360
u
460
u
490
u
4-NITROPHENOL
UG/KG
720
u
920
u
980
u
ACENAPHTHENE
UG/KG
6.71
360
u
460
V
490
u
ACENAPHTHYLENE
UG/KG
5.87
360
u
460
u
490
u
ANTHRACENE
UG/KG
46.9
50
J
460
u
490
u
BENZO(A)ANTHRACENE
UG/KG
74.8
130
J
99
J
68
J
BENZO(B)FLUORANTHENE
UG/KG
300
J
210
J
190
J
BENZO(GHI)PERYLENE
UG/KG
160
J
170
J
160
J
BENZO(K)FLUORANTHENE
UG/KG
160
J
73
J
63
J
BENZO-A-PYRENE
UG/KG
88.8
110
J
94
J
100
J
BENZYL BUTYL PHTHALATE
UG/KG
360
u
460
u
490
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
360
u
460
u
490
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
360
u
460
u
490
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
360
u
460
u
490
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
1700
u
460
u
490
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
Cl FLUORANTHENES/PYRENES
UG/KG
360
UJ
460
UJ
490
UJ
CI FLUORENES
UG/KG
360
UJ
460
UJ
490
UJ
Cl NAPHTHALENES
UG/KG
360
UJ
460
UJ
490
UJ
Cl PHENANTHRENES/ANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C2FLUORENES
UG/KG
360
UJ
460
UJ
490
UJ
-------
Table 5-13(E) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD211B
SD212
SD213
Effects
11/19/97
11/15/97
11/15/97
Values
14:05
13:50
13:18
C2NAPHTHALENES
UG/KG
360
UJ
460
UJ
490
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C3FLUORENES
UG/KG
360
UJ
460
UJ
490
UJ
C3NAPHTHALENES
UG/KG
360
UJ
460
UJ
490
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
C4 NAPHTHALENES
UG/KG
360
UJ
460
UJ
490
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
360
UJ
460
UJ
490
UJ
CARBAZOLE
UG/KG
360
u
460
u
490
U
CHRYSENE
UG/KG
108
140
J
87
J
78
J
DI-N-BUTYLPHTHALATE
UG/KG
360
u
1900
u
2600
u
DI-N-OCTYLPHTHALATE
UG/KG
360
u
460
u
490
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
54
J
50
J
39
J
DIBENZOFURAN
UG/KG
360
u
460
u
490
u
D1BUTYL TIN
UG/KG
76
J
240
u
250
u
DIETHYL PHTHALATE
UG/KG
360
u
460
u
490
u
DIMETHYL PHTHALATE
UG/KG
360
u
460
u
490
u
FLUORANTHENE
UG/KG
113
480
220
J
160
J
FLUORENE
UG/KG
21.2
360
u
460
u
490
V
HEXACHLOROBENZENE(HCB)
UG/KG
360
u
460
u
490
u
HEXACHLOROBUTADIENE
UG/KG
360
u
460
u
490
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
360
u
460
u
490
u
HEXACHLOROETHANE
UG/KG
360
u
460
u
490
u
INDENO (1,2,3-CD) PYRENE
UG/KG
150
J
140
J
110
J
ISOPHORONE
UG/KG
360
u
460
u
490
u
MONOBUTYL TIN
UG/KG
180
u
240
u
250
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
360
u
460
u
490
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
360
u
460
u
490
u
NAPHTHALENE
UG/KG
34.6
360
u
460
u
490
u
NITROBENZENE
UG/KG
360
u
460
u
490
u
PENTACHLOROPHENOL
UG/KG
720
u
920
u
980
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
66
J
41
J
36
J
PHENOL
UG/KG
360
u
460
u
490
u
PYRENE
UG/KG
153
340
J
160
J
120
J
TETRABUTYL TIN
UG/KG
180
u
240
u
250
u
TRIBUTYL TIN
UG/KG
180
u
240
u
250
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(F)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD214
Effects 11/15/97
SD215 SD215DUP
11/15/97 11/15/97
Values
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1 UNIDENTIFIED COMPOUND
1.2.4-TRJCHLOROBEN ZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRlCHLOROPHENOL
2.4.6-TRJCHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITRO ANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITRO ANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLORO ANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITRO ANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHl)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BlS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
88.!
182
13.45
79.2
600 U
NR
600 U
600 U
600 U
600 U
600 U
600 U
1200 U
600 U
600 U
600 U
600 U
1200 U
600 V
600 U
600 U
600 U
600 U
600 U
600 U
600 U
600 U
600 U
600 U
1200 U
600 U
600 V
600 U
130 J
220 J
220 J
42 J
170 J
600 U
600 U
600 U
600 U
2300 U
600 UJ
600 UJ
600 UJ
600 UJ
600 UJ
600 UJ
600 UJ
600 UJ
14:15
74.6
440 U
3000 J
440 U
440 U
440 U
440 U
440 U
440 U
890 U
440 U
440 U
440 U
440 U
890 U
440 V
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
890 U
440 V
24 J
440 U
110 J
230 J
170 J
110 J
80 J
440 U
440 U
440 U
440 U
2300 U
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
14:20
82.4
440 U
NR
440 U
440 U
440 U
440 U
440 U
440 U
890 U
440 U
440 U
440 U
440 U
890 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
440 U
890 U
440 U
440 U
440 U
88 J
170 J
140 J
91 J
71 J
440 U
440 U
440 U
440 U
1900 U
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
440 UJ
-------
Table 5-13(F) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD214
SD215
SD215DUP
Effects
11/15/97
11/15/97
11/15/97
Values
13:45
14:15
14:20
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 UJ
440 UJ
440 UJ
UG/KG
600 U
440 U
440 U
UG/KG
108
100 J
120 J
76 J
UG/KG
3600 U
2000 U
3000 U
UG/KG
600 U
440 U
440 U
UG/KG
6.22
67 J
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
300 U
250 U
240 U
UG/KG
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
113
420 J
530
410 J
UG/KG
21.2
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
180 J
150 J
120 J
UG/KG
600 U
440 U
440 U
UG/KG
300 U
250 U
240 U
UG/KG
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
34.6
600 U
440 U
440 U
UG/KG
600 U
440 U
440 U
UG/KG
1200 U
890 U
890 U
UG/KG
N
N
N
UG/KG
86.7
67 J
55 J
46 J
UG/KG
600 U
440 U
440 U
UG/KG
153
230 J
240 J
180 J
UG/KG
300 U
250 U
240 U
UG/KG
NR
4000 JN
NR
UG/KG
300 U
250 U
240 U
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
D1BENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE(HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TETRAHYDRONAPHTHALENE
TRIBUTYL TIN
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but no! detected. The number is the minimum quantitation limit.
-------
Table 5-13(G)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD216
SD217
SD218
Effects
11/15/97
11/15/97
11/15/97
Values
14:50
15:19
15:55
% MOISTURE
%
75.7
82.5
77
(3-AND/OR 4-)METHYLPHENOL
UG/KG
550 U
730
U
550
U
1 UNIDENTIFIED COMPOUND
UG/KG
3000 J
4000
J
NR
1,2,4-TRlCHLOROBENZENE
UG/KG
550 U
730
U
550
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
550 U
730
u
550
u
2,4,5-TRlCHLOROPHENOL
UG/KG
550 U
730
u
550
u
2,4,6-TRICHLOROPHENOL
UG/KG
550 U
730
u
550
u
2,4-DICHLOROPHENOL
UG/KG
550 U
730
u
550
u
2,4-DIMETHYLPHENOL
UG/KG
550 U
730
u
550
u
2,4-DINITROPHENOL
UG/KG
1100 U
1500
u
1100
u
2,4-DINITROTOLUENE
UG/KG
550 U
730
u
550
u
2,6-DINITROTOLUENE
UG/KG
550 U
730
u
550
u
2-CHLORONAPHTHALENE
UG/KG
550 U
730
u
550
u
2-CHLOROPHENOL
UG/KG
550 U
730
u
550
u
2-METHYL-4,6-DINITROPHENO L
UG/KG
1100 u
1500
u
1100
u
2-METHYLNAPHTHALENE
UG/KG
20.23
550 U
730
u
550
u
2-METHYLPHENOL
UG/KG
550 U
730
u
550
u
2-NITRO ANILINE
UG/KG
550 U
730
u
550
u
2-NITROPHENOL
UG/KG
550 U
730
u
550
u
3,3'-DICHLOROBENZIDINE
UG/KG
550 U
730
u
550
u
3-NITROANILINE
UG/KG
550 U
730
u
550
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
550 U
730
u
550
u
4-CHLORO-3-METHYLPHENOL
UG/KG
550 U
730
u
550
u
4-CHLOROANILINE
UG/KG
550 U
730
u
550
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
550 U
730
u
550
u
4-NITRO ANILINE
UG/KG
550 U
730
u
550
u
4-NITROPHENOL
UG/KG
1100 U
1500
u
1100
u
ACENAPHTHENE
UG/KG
6.71
550 U
730
u
550
u
ACENAPHTHYLENE
UG/KG
5.87
550 U
730
u
550
V
ANTHRACENE
UG/KG
46.9
550 U
730
u
550
u
BENZO(A)ANTHRACENE
UG/KG
74.8
120 J
80
J
80
J
BENZO(B)FLUORANTHENE
UG/KG
300 J
230
J
250
J
BENZO(GHI)PERYLENE
UG/KG
240 J
170
J
140
J
BENZO(K)FLUORANTHENE
UG/KG
120 J
130
J
75
J
BENZO-A-PYRENE
UG/KG
88.8
140 J
160
J
130
J
BENZYL BUTYL PHTHALATE
UG/KG
550 U
730
u
550
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
550 U
730
u
550
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
550 U
730
u
550
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
550 U
730
u
550
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
560 U
3700
u
3000
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
550 UJ
730
UJ
550
UJ
CI FLUORANTHENES/PYRENES
UG/KG
550 UJ
730
UJ
550
UJ
CI FLUORENES
UG/KG
550 UJ
730
UJ
550
UJ
CI NAPHTHALENES
UG/KG
550 UJ
730
UJ
550
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
550 UJ
730
UJ
550
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
550 UJ
730
UJ
550
UJ
C2FLUORENES
UG/KG
550 UJ
730
UJ
550
UJ
C2NAPHTHALENES
UG/KG
550 UJ
730
UJ
550
UJ
-.4
-------
Table 5-13(G) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD216
SD217
SD218
Effects
11/15/97
11/15/97
11/15/97
Values
14:50
15:19
15:55
C2 PHENANTHRENES/ANTHRACENES
UG/KG
550
UJ
730
UJ
550
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
550
UJ
730
UJ
550
UJ
C3 FLUORENES
UG/KG
550
UJ
730
UJ
550
UJ
C3 NAPHTHALENES
UG/KG
550
UJ
730
UJ
550
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
550
UJ
730
UJ
550
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
550
UJ
730
UJ
550
UJ
C4 NAPHTHALENES
UG/KG
550
UJ
730
UJ
550
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
550
UJ
730
UJ
550
UJ
CARBAZOLE
UG/KG
550
u
730
u
550
u
CHRYSENE
UG/KG
108
110
J
95
J
80
J
DI-N-BUTYLPHTHALATE
UG/KG
3800
u
3900
u
3800
u
DI-N-OCTYLPHTHALATE
UG/KG
550
u
730
u
550
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
77
J
730
u
50
J
DIBENZOFURAN
UG/KG
550
u
730
u
550
u
DIBUTYL TIN
UG/KG
260
u
350
u
290
u
DIETHYL PHTHALATE
UG/KG
550
u
730
u
550
u
DIMETHYL PHTHALATE
UG/KG
550
u
730
u
550
u
FLUORANTHENE
UG/KG
113
440
J
470
J
250
J
FLUORENE
UG/KG
21.2
550
u
730
u
550
u
HEXACHLOROBENZENE (HCB)
UG/KG
550
u
730
u
550
u
HEXACHLOROBUTADIENE
UG/KG
550
u
730
u
550
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
550
u
730
u
550
u
HEXACHLOROETHANE
UG/KG
550
u
730
u
550
u
INDENO (1,2,3-CD) PYRENE
UG/KG
180
J
130
J
120
J
ISOPHORONE
UG/KG
550
u
730
u
550
u
MONOBUTYL TIN
UG/KG
260
u
350
u
290
u
N-N1TROSODI-N-PROPYLAMINE
UG/KG
550
u
730
u
550
u
N-NITROSODIPHENYLAMINE/DIPHENYLAM1NE
UG/KG
550
u
730
u
550
u
NAPHTHALENE
UG/KG
34.6
550
u
730
u
550
u
NITROBENZENE
UG/KG
550
u
730
u
550
u
PENTACHLOROPHENOL
UG/KG
1100
u
1500
u
1100
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
66
J
77
J
50
J
PHENOL
UG/KG
550
u
730
u
550
u
PYRENE
UG/KG
153
240
J
180
J
160
J
TETRABUTYL TIN
UG/KG
260
u
350
u
290
u
TETRAHYDRONAPHTHALENE
UG/KG
3000
JN
10000
JN
6000
JN
tributyl TIN
UG/KG
260
u
350
u
290
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-13(H)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD219
Effects 11/15/97
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1 UNIDENTIFIED COMPOUND
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DlNITROPHENOL
2-METHYLNAPHTHALENE
2-M ETH YLPHENOL
2-NITROAN1LINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-N1TROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLORO ANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITRO ANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHl)PERYLEN E
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BlS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
Values
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 20.23
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
6.71
5.87
46.9
74.8
182
16:20
84
1400
NR
770 U
770 U
770 U
770 U
770 U
770 U
1500 U
770 U
770 U
770 U
770 U
1500 U
770 U
770 U
770 U
770 U
770 U
770 U
770 U
770 U
770 U
770 U
770 U
1500 U
770 U
54 J
770 U
130 J
230 J
200 J
140 J
92 J
770 U
770 U
770 U
770 U
7400 V
770 UJ
770 UJ
770 UJ
770 UJ
770 UJ
770 UJ
770 UJ
770 UJ
SD220
11/15/97
16:45
SD221
11/16/97
09:45
69.5
410 U
2000 J
410 U
410 U
410 U
410 V
410 U
410 U
820 U
410 U
410 U
410 U
410 U
820 U
4)0 U
410 U
410 U
410 U
410 U
410 U
410 U
410 U
410 U
410 U
410 U
820 U
410 U
410 U
410 U
92 J
320 J
180 J
73 J
100 J
410 U
410 U
410 U
410 U
410 U
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
77.3
480 U
NR
480 U
480 U
480 U
480 U
480 U
480 U
950 U
480 U
480 U
480 U
480 U
950 U
480 U
480 U
480 U
480 U
480 U
480 U
480 U
480 U
480 U
480 U
480 U
950 U
480 U
480 U
480 U
81
130
130
83
100
480 U
480 U
480 U
480 U
2800 U
480 UJ
480 UJ
480 UJ
480 UJ
480 UJ
480 UJ
480 UJ
480 UJ
J
J
J
J
J
-------
Table 5-13(H) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD219
SD220
SD221
Effects
11/15/97
11/15/97
11/16/97
Values
16:20
16:45
09:45
C2 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
410
UJ
480
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
770
UJ
410
UJ
480
UJ
C3FLUORENES
UG/KG
770
UJ
410
UJ
480
UJ
C3NAPHTHALENES
UG/KG
770
UJ
410
UJ
480
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
410
UJ
480
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
770
UJ
410
UJ
480
UJ
C4 NAPHTHALENES
UG/KG
770
UJ
410
UJ
480
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
410
UJ
480
UJ
CARBAZOLE
UG/KG
770
u
410
u
480
u
CHRYSENE
UG/KG
108
110
J
92
J
69
J
Dl-N-BUTYLPHTHALATE
UG/KG
5600
u
2800
u
3500
u
DI-N-OCTYLPHTHALATE
UG/KG
770
u
410
u
480
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
69
J
63
J
45
J
DIBENZOFURAN
UG/KG
770
u
410
u
480
u
D1BUTYL TIN
UG/KG
370
u
210
u
78
J
DIETHYL PHTHALATE
UG/KG
770
u
410
u
480
u
DIMETHYL PHTHALATE
UG/KG
770
u
410
u
480
u
FLUORANTHENE
UG/KG
113
980
280
J
340
J
FLUORENE
UG/KG
21.2
770
u
410
u
480
u
HEXACHLOROBENZENE(HCB)
UG/KG
770
u
410
u
480
u
HEXACHLOROBUTADIENE
UG/KG
770
u
410
u
480
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
770
u
410
u
480
u
HEXACHLOROETHANE
UG/KG
770
u
410
u
480
u
INDENO (1,2,3-CD) PYRENE
UG/KG
180
J
160
J
110
J
ISOPHORONE
UG/KG
770
u
410
u
480
u
MONOBUTYL TIN
UG/KG
370
u
210
u
280
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
770
u
410
u
480
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
770
u
410
u
480
u
NAPHTHALENE
UG/KG
34.6
770
u
410
u
480
u
NITROBENZENE
UG/KG
770
u
410
u
480
u
PENTACHLOROPHENOL
UG/KG
1500
u
820
u
950
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
96
J
55
J
48
J
PHENOL
UG/KG
770
u
410
u
480
u
PYRENE
UG/KG
153
280
J
200
J
150
J
TETRABUTYL TIN
UG/KG
370
u
210
u
280
u
TETRAHYDRONAPHTHALENE
UG/KG
6000
JN
NR
NR
TRIBUTYL TIN
UG/KG
370
u
210
u
280
U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRlCHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRiCHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DlCHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPH ENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITRO ANILINE
2-NITR0PHEN0L
3,3'-DICHLOROBENZIDINE
3-NITROANILrNE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BlS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2 FLUORENES
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
Table 5-13(1)
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD222
Effects 11/16/97
Values 10:25
%
86.1
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
1900 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
1900 U
UG/KG
20.23
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
1900 U
UG/KG
6.71
960 U
UG/KG
5.87
53 J
UG/KG
46.9
960 U
UG/KG
74.8
170 J
UG/KG
440 J
UG/KG
250 J
UG/KG
120 J
UG/KG
88.8
230 J
UG/KG
1300 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
182
8100 U
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
-------
Table 5-13(1) - Continued
Sediment Analytical Results - Extractables
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD222
Effects 11/16/97
Values 10:25
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
1NDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSOD1PHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
Note- Th«. detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 UJ
UG/KG
960 U
UG/KG
108
150 J
UG/KG
8800 U
UG/KG
960 U
UG/KG
6.22
87 J
UG/KG
960 U
UG/KG
330 J
UG/KG
960 U
UG/KG
960 U
UG/KG
113
800 J
UG/KG
21.2
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
960 U
UG/KG
190 J
UG/KG
960 U
UG/KG
460 U
UG/KG
960 U
UG/KG
960 U
UG/KG
34.6
960 V
UG/KG
960 U
UG/KG
1900 U
UG/KG
N
UG/KG
86.7
92 J
UG/KG
960 U
UG/KG
153
350 J
UG/KG
460 U
UG/KG
1100
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-14(A)
Sediment Analytical Results - Extractables
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD301
SD302
SD302DUP
Effects
11/16/97
11/16/97
11/16/97
Values
10:50
11:25
11:30
% MOISTURE
%
85.9
85.4
81
(3-AND/OR 4-)METHYLPHENOL
UG/KG
890
U
940
U
660
U
(BUTYLOCTYL)BENZENE
UG/KG
NR
7000
JN
3000
JN
(PENTYLHEPTYL)BENZENE
UG/KG
NR
8000
JN
5000
JN
1,2,4-TRICHLOROBENZENE
UG/KG
890
U
940
U
660
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
890
U
940
U
660
U
2,4,5-TRICHLOROPHENOL
UG/KG
890
u
940
u
660
u
2,4,6-TRICHLOROPHENOL
UG/KG
890
u
940
u
660
u
2,4-DICHLOROPHENOL
UG/KG
890
u
940
u
660
u
2,4-DIMETHYLPHENOL
UG/KG
890
u
940
u
660
u
2,4-DINITROPHENOL
UG/KG
1800
u
1900
u
1300
u
2,4-DINITROTOLUENE
UG/KG
890
u
940
u
660
u
2,6-DINITROTOLUENE
UG/KG
890
u
940
u
660
u
2-CHLORONAPHTHALENE
UG/KG
890
u
940
u
660
u
2-CHLOROPHENOL
UG/KG
890
u
940
u
660
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
1800
u
1900
u
1300
u
2-METHYLNAPHTHALENE
UG/KG
20.23
890
u
940
u
660
u
2-METHYLPHENOL
UG/KG
890
u
940
u
660
u
2-NITROANILINE
UG/KG
890
u
940
u
660
u
2-NITROPHENOL
UG/KG
890
u
940
u
660
u
3,3'-DICHLOROBENZIDINE
UG/KG
890
u
940
u
660
u
3-NITRO ANILINE
UG/KG
890
u
940
u
660
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
890
u
940
u
660
u
4-CHLORO-3-METHYLPHENOL
UG/KG
890
u
940
u
660
u
4-CHLOROANILINE
UG/KG
890
u
940
u
660
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
890
u
940
u
660
u
4-NITROANILINE
UG/KG
890
u
940
u
660
u
4-NITROPHENOL
UG/KG
1800
u
1900
u
1300
u
ACENAPHTHENE
UG/KG
6.71
890
u
940
u
660
u
ACENAPHTHYLENE
UG/KG
5.87
58
J
56
J
39
J
ANTHRACENE
UG/KG
46.9
53
J
940
u
660
u
BENZO(A)ANTHRACENE
UG/KG
74.8
370
J
220
J
180
J
BENZO(B)FLUORANTHENE
UG/KG
450
J
510
J
320
J
BENZO(GHI)PERYLENE
UG/KG
370
J
370
J
240
J
BENZO(K)FLUORANTHENE
UG/KG
200
J
180
J
180
J
BENZO-A-PYRENE
UG/KG
88.8
240
J
180
J
140
J
BENZYL BUTYL PHTHALATE
UG/KG
890
u
940
u
1800
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
890
u
940
u
660
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
890
u
940
u
660
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
890
u
940
u
660
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
15000
u
12000
u
9400
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
CI FLUORANTHENES/PYRENES
UG/KG
890
UJ
940
UJ
660
UJ
CI FLUORENES
UG/KG
890
UJ
940
UJ
660
UJ
CI NAPHTHALENES
UG/KG
890
UJ
940
UJ
660
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C2FLUORENES
UG/KG
890
UJ
940
UJ
660
UJ
-------
Table 5-14(A) - Continued
Sediment Analytical Results - Extractables
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
SD301
11/16/97
10:50
SD302
11/16/97
11:25
SD302DUP
11/16/97
11:30
C2 NAPHTHALENES
UG/KG
890
UJ
940
UJ
660
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C3 FLUORENES
UG/KG
890
UJ
940
UJ
660
UJ
C3 NAPHTHALENES
UG/KG
890
UJ
940
UJ
660
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
C4 NAPHTHALENES
UG/KG
890
UJ
940
UJ
660
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
940
UJ
660
UJ
CARBAZOLE
UG/KG
890
u
940
u
660
u
CHRYSENE
UG/KG
108
290
J
210
J
150
J
DI-N-BUTYLPHTHALATE
UG/KG
8300
u
6700
u
4400
u
DI-N-OCTYLPHTHALATE
UG/KG
890
u
940
u
660
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
130
J
130
J
88
J
DIBENZOFURAN
UG/KG
890
u
940
u
660
u
DIBUTYL TIN
UG/KG
540
280
J
330
u
DIETHYL PHTHALATE
UG/KG
890
u
940
u
660
u
DIMETHYL PHTHALATE
UG/KG
890
u
940
u
660
u
FLUORANTHENE
UG/KG
113
1800
1700
1300
FLUORENE
UG/KG
21.2
890
u
940
u
660
u
HEXACHLOROBENZENE(HCB)
UG/KG
890
u
940
u
660
u
HEXACHLOROBUTADIENE
UG/KG
890
u
940
u
660
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
890
u
940
u
660
u
HEXACHLOROETHANE
UG/KG
890
u
940
u
660
u
INDENO (1,2,3-CD) PYRENE
UG/KG
310
J
320
J
220
J
ISOPHORONE
UG/KG
890
u
940
u
660
u
MONOBUTYL TIN
UG/KG
430
u
460
u
330
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
890
u
940
u
660
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
890
u
940
u
660
u
NAPHTHALENE
UG/KG
34.6
890
u
940
u
660
u
NITROBENZENE
UG/KG
890
u
940
u
660
u
PENTACHLOROPHENOL
UG/KG
1800
V
1900
u
13 00
u
PETROLEUM PRODUCT •
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
240
J
140
J
92
J
PHENOL
UG/KG
890
u
940
u
660
u
PYRENE
UG/KG
153
610
J
510
J
390
J
TETRABUTYL TIN
UG/KG
430
u
460
u
330
u
TETRAHYDRONAPHTHALENE
UG/KG
7000
JN
NR
NR
TRIBUTYL TIN
UG/KG
860
1200
1000
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-14(B)
Sediment Analytical Results - Extractables
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(PENTYLHEPTYL)BENZENE
1 UNIDENTIFIED COMPOUND
1.2.4-TRICHLOROBENZENE
2 UNIDENTIFIED COMPOUNDS
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3 '-DICH LOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3 -METH YLPHENOL
4-CHLOROAN1LINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
RAGS
SD303
SD304
Effects
11/16/97
11/16/97
Values
12:00
12:20
%
83.3
83.3
UG/KG
770 U
740 U
UG/KG
NR
4000 JN
UG/KG
NR
30000 J
UG/KG
770 U
740 U
UG/KG
10000 J
NR
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
1500 U
1500 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
1500 U
1500 U
UG/KG
20.23
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
1500 U
1500 U
UG/KG
6.71
770 U
740 U
UG/KG
5.87
770 U
740 U
UG/KG
46.9
770 U
740 U
UG/KG
74.8
140 J
180 J
UG/KG
380 J
320 J
UG/KG
290 J
280 J
UG/KG
150 J
280 J
UG/KG
88.8
150 J
160 J
UG/KG
2900 U
1700 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
770 U
740 U
UG/KG
182
830 U
3600 U
UG/KG
770 UJ
740 UJ
UG/KG
770 UJ
740 UJ
UG/KG
770 UJ
740 UJ
UG/KG
770 UJ
740 UJ
UG/KG
770 UJ
740 UJ
UG/KG
770 UJ
740 UJ
-------
Table 5-14(B) - Continued
Sediment Analytical Results - Extractables
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD303
SD304
Effects
11/16/97
11/16/97
Values
12:00
12:20
C2 FLUORENES
UG/KG
770
UJ
740
UJ
C2 NAPHTHALENES
UG/KG
770
UJ
740
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
740
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
770
UJ
740
UJ
C3FLUORENES
UG/KG
770
UJ
740
UJ
C3 NAPHTHALENES
UG/KG
770
UJ
740
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
740
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
770
UJ
740
UJ
C4 NAPHTHALENES
UG/KG
770
UJ
740
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
770
UJ
740
UJ
CARBAZOLE
UG/KG
770
u
740
u
CHRYSENE
UG/KG
108
150
J
170
J
DI-N-BUTYLPHTHALATE
UG/KG
5100
u
4600
u
DI-N-OCTYLPHTHALATE
UG/KG
770
u
740
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
96
J
110
J
DIBENZOFURAN
UG/KG
770
u
740
u
DIBUTYL TIN
UG/KG
390
u
430
u
diethyl PHTHALATE
UG/KG
770
u
740
u
DIMETHYL PHTHALATE
UG/KG
770
u
740
u
FLUORANTHENE
UG/KG
113
630
J
900
fluorene
UG/KG
21.2
770
u
740
u
HEXACHLOROBENZENE (HCB)
UG/KG
770
u
740
u
HEXACHLOROBUTADIENE
UG/KG
770
u
740
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
770
u
740
u
hexachloroethane
UG/KG
770
u
740
u
INDENO (1,2,3-CD) PYRENE
UG/KG
240
J
230
J
isophorone
UG/KG
770
u
740
u
monobutyl tin
UG/KG
390
u
430
u
n-nitrosodi-n-propylamine
UG/KG
770
u
740
u
n-nitrosodiphenylamine/diphenylamine
UG/KG
770
u
740
u
naphthalene
UG/KG
34.6
770
u
740
u
nitrobenzene
UG/KG
770
u
740
u
pentachlorophenol
UG/KG
1500
u
1500
u
petroleum product
UG/KG
N
N
phenanthrene
UG/KG
86.7
77
J
85
J
phenol
UG/KG
770
u
740
u
PYRENE
UG/KG
153
350
J
610
J
tetrabutyl tin
UG/KG
390
u
430
u
tetrahydronaphthalene
UG/KG
10000
JN
10000
JN
tributyl tin
UG/KG
1500
1200
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-15(A)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD401
SD402
SD403
Effects
11/16/97
11/16/97
11/16/97
Values
12:55
13:15
13:44
% MOISTURE
%
82.5
82.1
73.2
(3-AND/OR 4-)METHYLPHENOL
UG/KG
450
U
440
U
480
U
1 UNIDENTIFIED COMPOUND
UG/KG
NR
NR
5000
J
1,2,4-TRICHLOROBENZENE
UG/KG
450
U
440
U
480
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
450
u
440
U
480
U
2,4,5-TRICHLOROPHENOL
UG/KG
450
u
440
U
480
U
2,4,6-TRICHLOROPHENOL
UG/KG
450
u
440
u
480
U
2,4-DICHLOROPHENOL
UG/KG
450
U
440
u
480
u
2,4-DIMETHYLPHENOL
UG/KG
450
u
440
U
480
u
2,4-DINITROPHENOL
UG/KG
890
u
880
u
960
u
2,4-DINITROTOLUENE
UG/KG
450
u
440
u
480
u
2,6-DINITROTOLUENE
UG/KG
450
u
440
U
480
u
2-CHLORONAPHTHALENE
UG/KG
450
u
440
u
480
u
2-CHLOROPHENOL
UG/KG
450
u
440
u
480
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
890
u
880
u
960
u
2-METHYLNAPHTHALENE
UG/KG
20.23
450
u
440
u
480
u
2-METHYLPHENOL
UG/KG
450
u
440
u
480
u
2-NITROANILINE
UG/KG
450
u
440
u
480
u
2-NITROPHENOL
UG/KG
450
u
440
u
480
u
3,3'-DICHLOROBENZIDINE
UG/KG
450
u
440
u
480
u
3-NITROANILINE
UG/KG
450
u
440
u
480
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
450
u
440
u
480
u
4-CHLORO-3-METHYLPHENOL
UG/KG
450
u
440
u
480
u
4-CHLOROANILINE
UG/KG
450
u
440
u
480
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
450
u
440
u
480
u
4-NITROANILINE
UG/KG
450
u
440
u
480
u
4-NITROPHENOL
UG/KG
890
u
880
u
960
u
ACENAPHTHENE
UG/KG
6.71
450
u
440
u
110
J
ACENAPHTHYLENE
UG/KG
5.87
450
u
440
u
24
J
ANTHRACENE
UG/KG
46.9
36
J
440
u
31
J
BENZO(A)ANTHRACENE
UG/KG
74.8
ISO
J
55
J
170
J
BENZO(B)FLUORANTHENE
UG/KG
400
J
190
J
350
J
BENZO(GHI)PERYLENE
UG/KG
260
J
110
J
220
J
BENZO(K)FLUORANTHENE
UG/KG
240
J
68
J
120
J
BENZO-A-PYRENE
UG/KG
88.8
180
J
130
J
160
J
BENZYL BUTYL PHTHALATE
UG/KG
450
u
440
u
520
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
450
u
440
u
480
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
450
u
440
u
480
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
450
u
440
u
480
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
1500
u
490
u
480
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
440
UJ
480
UJ
CI FLUORANTHENES/PYRENES
UG/KG
450
UJ
440
UJ
480
UJ
CI FLUORENES
UG/KG
450
UJ
440
UJ
480
UJ
CI NAPHTHALENES
UG/KG
450
UJ
440
UJ
480
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
440
UJ
480
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
440
UJ
480
UJ
C2FLUORENES
UG/KG
450
UJ
440
UJ
480
UJ
C2NAPHTHALENES
UG/KG
450
UJ
440
UJ
480
UJ
-------
Table 5-15(A) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD401
SD402
SD403
Effects
11/16/97
11/16/97
11/16/97
Values
12:55
13:15
13:44
C2 PHENANTHRENES/ANTHRACENES
ug/kg
450
UJ
440
UJ
480
UJ
C3 CHRYSENES/BENZANTHRACENES
ug/kg
450
u;
440
UJ
480
UJ
C3 FLUORENES
ug/kg
450
UJ
440
UJ
480
UJ
C3 NAPHTHALENES
ug/kg
450
UJ
440
UJ
480
UJ
C3 PHENANTHRENES/ANTHRACENES
ug/kg
450
UJ
440
UJ
480
UJ
C4 CHRYSENES/BENZANTHRACENES
ug/kg
450
UJ
440
UJ
480
UJ
C4 NAPHTHALENES
UG/KG
450
UJ
440
UJ
480
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
440
UJ
480
UJ
CARBAZOLE
UG/KG
450
U
440
U
480
U
CHRYSENE
UG/KG
108
280
J
79
J
150
J
DI-N-BUTYLPHTHALATE
UG/KG
3300
u
2700
U
3600
u
DI-N-OCTYLPHTHALATE
UG/KG
450
u
440
u
480
U
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
96
J
35
J
72
J
dibenzofuran
UG/KG
450
u
440
u
480
U
DIBUTYL TIN
UG/KG
220
u
190
u
240
U
diethyl phthalate
UG/KG
450
u
440
u
480
U
dimethyl phthalate
UG/KG
450
u
440
u
480
U
fluoranthene
UG/KG
113
660
180
J
1300
fluorene
UG/KG
21.2
450
u
440
u
480
u
HEXACHLOROBENZENE (HCB)
UG/KG
450
u
440
u
480
U
hexachlorobutadiene
UG/KG
450
u
440
u
480
U
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
450
u
440
u
480
U
hexachloroethane
UG/KG
450
u
440
u
480
U
INDENO (1,2,3-CD) PYRENE
UG/KG
240
J
98
J
170
J
ISOPHORONE
UG/KG
450
u
440
u
480
U
monobutyl tin
UG/KG
220
u
190
u
240
U
n-nitrosodi-n-propylamine
UG/KG
450
u
440
u
480
u
n-nitrosodiphenylamine/diphenylamine
UG/KG
450
u
440
u
480
u
naphthalene
UG/KG
34.6
450
u
440
u
480
u
nitrobenzene
UG/KG
450
u
440
u
480
u
pentachlorophenol
UG/KG
890
u
880
u
960
u
petroleum product
UG/KG
N
N
N
phenanthrene
UG/KG
86.7
76
J
35
J
74
J
phenol
UG/KG
450
u
440
u
480
u
pyrene
UG/KG
153
540
120
J
860
tetrabutyl tin
UG/KG
220
u
190
u
240
u
tributyl tin
UG/KG
1200
u
920
u
1100
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-15(B)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD403DUP
SD404
SD405
Effects
11/16/97
11/16/97
11/16/97
Values
13:50
15:00
15:20
% MOISTURE
%
75.2
82.7
82
(3-AND/OR 4-)METHYLPHENOL
UG/KG
520
U
660
U
830
U
(BUTYLOCTYL)BENZENE
UG/KG
NR
NR
4000
JN
(PENTYLHEPTYL)BENZENE
UG/KG
NR
NR
5000
JN
1 UNIDENTIFIED COMPOUND
UG/KG
NR
7000
J
NR
1,2,4-TRICHLOROBENZENE
UG/KG
520
U
660
U
830
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
520
U
660
U
830
U
2,4,5-TRICHLOROPHENOL
UG/KG
520
U
660
u
830
U
2,4,6-TRICHLOROPHENOL
UG/KG
520
u
660
u
830
U
2,4-DICHLOROPHENOL
UG/KG
520
u
660
u
830
U
2,4-DIMETHYLPHENOL
UG/KG
520
u
660
u
830
U
2,4-DINITROPHENOL
UG/KG
1000
u
1300
u
1700
U
2,4-DINITROTOLUENE
UG/KG
520
u
660
u
830
U
2,6-DINITROTOLUENE
UG/KG
520
u
660
u
830
U
2-CHLORONAPHTHALENE
UG/KG
520
u
660
u
830
U
2-CHLOROPHENOL
UG/KG
520
u
660
u
830
U
2-METHYL-4.6-DINITROPHENOL
UG/KG
1000
u
1300
u
1700
u
2-METHYLNAPHTHALENE
UG/KG
20.23
520
u
660
u
830
u
2-METHYLPHENOL
UG/KG
520
u
660
u
830
u
2-NITROANILINE
UG/KG
520
u
660
u
830
u
2-NITROPHENOL
UG/KG
520
u
660
u
830
u
3,3'-DICHLOROBENZIDINE
UG/KG
520
u
660
u
830
u
3-NITROANILINE
UG/KG
520
u
660
u
830
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
520
u
660
u
830
u
4-CHLORO-3-METHYLPHENOL
UG/KG
520
u
660
u
830
u
4-CHLOROANILINE
UG/KG
520
u
660
u
830
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
520
u
660
u
830
u
4-NITROANILINE
UG/KG
520
u
660
u
830
u
4-NITROPHENOL
UG/KG
1000
u
1300
u
1700
u
ACENAPHTHENE
UG/KG
6.71
50
J
660
u
830
u
ACENAPHTHYLENE
UG/KG
5.87
520
u
660
u
830
u
ANTHRACENE
UG/KG
46.9
520
u
660
u
830
u
BENZO(A)ANTHRACENE
UG/KG
74.8
160
J
130
J
200
J
BENZO(B)FLUORANTHENE
UG/KG
370
J
280
J
550
J
BENZO(GHI)PERYLENE
UG/KG
280
J
230
J
330
J
BENZO(K)FLUORANTHENE
UG/KG
140
J
190
J
190
J
BENZO-A-PYRENE
UG/KG
88.8
180
J
160
J
240
J
BENZYL BUTYL PHTHALATE
UG/KG
850
u
1500
u
1700
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
520
u
660
u
830
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
520
u
660
u
830
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
520
u
660
u
830
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
520
u
810
u
2600
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
CI FLUORANTHENES/PYRENES
UG/KG
520
UJ
660
UJ
830
UJ
CIFLUORENES
UG/KG
520
UJ
660
UJ
830
UJ
CI NAPHTHALENES
UG/KG
520
UJ
660
UJ
830
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
-------
Table 5-15(B) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD403DUP
SD404
SD405
Effects
11/16/97
11/16/97
11/16/97
Values
13:50
15:00
15:20
C2FLUORENES
UG/KG
520
UJ
660
UJ
830
UJ
C2 NAPHTHALENES
UG/KG
520
UJ
660
UJ
830
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
C3FLUORENES
UG/KG
520
UJ
660
UJ
830
UJ
C3 NAPHTHALENES
UG/KG
520
UJ
660
UJ
830
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
C4 NAPHTHALENES
UG/KG
520
UJ
660
UJ
830
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
520
UJ
660
UJ
830
UJ
CARBAZOLE
UG/KG
520
U
660
U
830
U
CHRYSENE
UG/KG
108
160
J
130
J
200
J
DI-N-BUTYLPHTHALATE
UG/KG
3100
u
3800
u
3000
u
DI-N-OCTYLPHTHALATE
UG/KG
520
u
660
u
830
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
78
J
69
J
100
J
dibenzofuran
UG/KG
520
u
660
u
830
u
DIBUTYL TIN
UG/KG
250
u
360
u
330
u
DIETHYL PHTHALATE
UG/KG
520
u
660
u
830
u
DIMETHYL PHTHALATE
UG/KG
520
u
660
u
830
u
fluoranthene
UG/KG
113
980
590
J
680
J
fluorene
UG/KG
21.2
520
u
660
u
830
u
HEXACHLOROBENZENE(HCB)
UG/KG
520
u
660
u
830
u
HEXACHLOROBUTADIENE
UG/KG
520
u
660
u
830
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
520
u
660
u
830
u
HEXACHLOROETHANE
UG/KG
520
u
660
u
830
u
INDENO (1,2,3-CD) PYRENE
UG/KG
220
J
190
J
290
J
ISOPHORONE
UG/KG
520
u
660
u
830
u
MONOBUTYL TIN
UG/KG
250
u
360
u
330
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
520
u
660
u
830
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
520
u
660
u
830
u
NAPHTHALENE
UG/KG
34.6
520
u
660
u
830
u
NITROBENZENE
UG/KG
520
u
660
u
830
u
PENTACHLOROPHENOL
UG/KG
1000
u
1300
u
1700
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
55
J
56
J
99
J
PHENOL
UG/KG
520
u
660
u
830
u
PYRENE
UG/KG
153
680
330
J
510
J
TETRABUTYL TIN
UG/KG
250
u
360
u
330
u
TETRAHYDRONAPHTHALENE
UG/KG
5000
JN
10000
JN
NR
TRIBUTYL TIN
UG/KG
1100
u
2000
u
1300
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-15(C)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD406
SD407
SD408
Effects
11/16/97
11/18/97
11/18/97
Values
15:35
09:00
09:23
% MOISTURE
%
81.5
81.5
86.3
(3-AND/OR 4-)METHYLPHENOL
UG/KG
620
U
650
U
840
U
(PENTYLHEPTYL)BENZENE
UG/KG
NR
NR
4000
JN
1,2,4-TRICHLOROBENZENE
UG/KG
620
U
650
U
840
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
620
U
650
u
840
u
2,4,5-TRICHLOROPHENOL
UG/KG
620
U
650
u
840
u
2,4,6-TRICHLOROPHENOL
UG/KG
620
U
650
u
840
u
2,4-DICHLOROPHENOL
UG/KG
620
U
650
u
840
u
2,4-DIMETHYLPHENOL
UG/KG
620
U
650
u
840
u
2,4-DINITROPHENOL
UG/KG
1200
u
1300
u
1700
u
2,4-DINITROTOLUENE
UG/KG
620
u
650
u
840
u
2,6-DINITROTOLUENE
UG/KG
620
u
650
u
840
u
2-CHLORONAPHTHALENE
UG/KG
620
u
650
u
840
u
2-CHLOROPHENOL
UG/KG
620
u
650
u
840
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
1200
u
1300
u
1700
u
2-METHYLNAPHTHALENE
UG/KG
20.23
620
u
650
u
840
u
2-METHYLPHENOL
UG/KG
620
u
650
u
840
u
2-NITROANILINE
UG/KG
620
u
650
u
840
u
2-NITROPHENOL
UG/KG
620
u
650
u
840
u
3,3'-DICHLOROBENZIDINE
UG/KG
620
u
650
u
840
u
3-NITROANILINE
UG/KG
620
u
650
u
840
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
620
u
650
u
840
u
4-CHLORO-3-METHYLPHENOL
UG/KG
620
u
650
u
840
u
4-CHLOROANILINE
UG/KG
620
u
650
u
840
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
620
u
650
u
840
u
4-NITROANILINE
UG/KG
620
u
650
u
840
u
4-NITROPHENOL
UG/KG
1200
u
1300
u
1700
u
ACENAPHTHENE
UG/KG
6.71
620
u
650
u
840
u
ACENAPHTHYLENE
UG/KG
5.87
620
u
45
J
46
J
ANTHRACENE
UG/KG
46.9
620
u
650
u
840
u
BENZO(A)ANTHRACENE
UG/KG
74.8
160
J
250
J
170
J
BENZO(B)FLUORANTHENE
UG/KG
330
J
410
J
780
J
BENZO(GHI)PERYLENE
UG/KG
190
J
240
J
260
J
BENZO(K)FLUORANTHENE
UG/KG
120
J
230
J
110
J
BENZO-A-PYRENE
UG/KG
88.8
ISO
J
200
J
200
J
BENZYL BUTYL PHTHALATE
UG/KG
1500
u
1600
u
1500
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
620
u
650
u
840
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
620
u
650
u
840
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
620
u
650
u
840
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
630
u
5800
u
6400
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
CI FLUORANTHENES/PYRENES
UG/KG
620
UJ
650
UJ
840
UJ
CI FLUORENES
UG/KG
620
UJ
650
UJ
840
UJ
CI NAPHTHALENES
UG/KG
620
UJ
650
UJ
840
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C2 FLUORENES
UG/KG
620
UJ
650
UJ
840
UJ
C2 NAPHTHALENES
UG/KG
620
UJ
650
UJ
840
UJ
-------
Table 5-15(C) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD406
SD407
SD408
Effects
11/16/97
11/18/97
11/18/97
Values
15:35
09:00
09:23
C2 PHENANTHRENES/ANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C3 FLUORENES
UG/KG
620
UJ
650
UJ
840
UJ
C3NAPHTHALENES
UG/KG
620
UJ
650
UJ
840
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
C4 NAPHTHALENES
UG/KG
620
UJ
650
UJ
840
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
620
UJ
650
UJ
840
UJ
CARBAZOLE
UG/KG
620
u
650
u
840
u
CHRYSENE
UG/KG
108
140
J
200
J
170
J
DI-N-BUTYLPHTHALATE
UG/KG
2800
u
3600
u
3700
u
DI-N-OCTYLPHTHALATE
UG/KG
620
u
650
u
840
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
68
J
75
J
89
J
DIBENZOFURAN
UG/KG
620
u
650
u
840
u
DIBUTYL TIN
UG/KG
330
u
320
u
430
u
DIETHYL PHTHALATE
UG/KG
620
u
650
u
840
u
DIMETHYL PHTHALATE
UG/KG
620
u
650
u
840
u
FLUORANTHENE
UG/KG
113
450
J
1200
1000
FLUORENE
UG/KG
21.2
620
u
650
u
840
u
HEXACHLOROBENZENE (HCB)
UG/KG
620
u
650
u
840
u
HEXACHLOROBUTADIENE
UG/KG
620
u
650
u
840
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
620
u
650
u
840
u
HEXACHLOROETHANE
UG/KG
620
u
650
u
840
u
INDENO (1,2,3-CD) PYRENE
UG/KG
170
J
210
J
230
J
ISOPHORONE
UG/KG
620
u
650
u
840
u
MONOBUTYL TIN
UG/KG
330
u
320
u
430
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
620
u
650
u
840
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
620
u
650
u
840
u
NAPHTHALENE
UG/KG
34.6
620
u
650
u
840
u
NITROBENZENE
UG/KG
620
u
650
u
840
u
PENTACHLOROPHENOL
UG/KG
1200
u
1300
u
1700
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
140
J
78
J
42
J
PHENOL
UG/KG
620
u
650
u
840
u
PYRENE
UG/KG
153
330
J
600
J
480
J
TETRABUTYL TIN
UG/KG
330
u
320
u
430
u
TETRAHYDRONAPHTHALENE
UG/KG
NR
4000
JN
7000
JN
TRIBUTYL TIN
UG/KG
1900
u
320
u
430
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-15(D)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD409
SD410
SD411
Effects
11/18/97
11/18/97
11/18/97
Values
09:55
10:20
10:50
% MOISTURE
%
70.2
79.5
67.6
(3-AND/OR 4-)METHYLPHENOL
UG/KG
450
U
560
U
350
U
1,2,4-TRICHLOROBENZENE
UG/KG
450
U
560
u
350
U
2,3,4,6-TETRACHLOROPHENOL
UG/KG
450
U
560
u
350
U
2,4,5-TRICHLOROPHENOL
UG/KG
450
U
560
u
350
U
2,4,6-TRICHLOROPHENOL
UG/KG
450
U
560
u
350
U
2,4-DICHLOROPHENOL
UG/KG
450
U
560
u
350
U
2,4-DIMETHYLPHENOL
UG/KG
450
u
560
u
350
U
2,4-DINITROPHENOL
UG/KG
900
u
1100
u
700
U
2,4-DINITROTOLUENE
UG/KG
450
u
560
u
350
U
2,6-DINITROTOLUENE
UG/KG
450
u
560
u
350
U
2-CHLORONAPHTHALENE
UG/KG
450
u
560
u
350
U
2-CHLOROPHENOL
UG/KG
450
u
560
u
350
U
2 -METH YL-4,6-DINITROPHENOL
UG/KG
900
u
1100
u
700
U
2-METH YLN APHTH ALEN E
UG/KG
20.23
450
u
560
u
350
U
2-METHYLPHENOL
UG/KG
450
u
560
u
350
U
2-NITROANILINE
UG/KG
450
u
560
u
350
U
2-NITROPHENOL
UG/KG
450
u
560
u
350
U
3,3 '-DICHLOROBENZIDINE
UG/KG
450
u
560
u
350
U
3-NITRO ANILINE
UG/KG
450
u
560
u
350
U
4 UNIDENTIFIED COMPOUNDS
UG/KG
NR
20000
J
NR
4-BROMOPHENYL PHENYL ETHER
UG/KG
450
u
560
u
350
U
4-CHLORO-3-METHYLPHENOL
UG/KG
450
u
560
u
350
U
4-CHLOROANILINE
UG/KG
450
u
560
u
350
U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
450
u
560
u
350
U
4-NITROANILINE
UG/KG
450
u
560
u
350
U
4-NITROPHENOL
UG/KG
900
u
1100
u
700
U
ACENAPHTHENE
UG/KG
6.71
450
u
560
u
350
U
ACENAPHTHYLENE
UG/KG
5.87
450
u
560
u
350
U
ANTHRACENE
UG/KG
46.9
450
u
560
u
350
u
BENZO(A)ANTHRACENE
UG/KG
74.8
130
J
170
J
160
J
BENZO(B)FLUORANTHENE
UG/KG
700
470
J
750
BENZO(GHI)PERYLENE
UG/KG
330
J
180
J
280
J
BENZO(K)FLUORANTHENE
UG/KG
660
180
J
480
BENZO-A-PYRENE
UG/KG
88.8
250
J
62
J
200
J
BENZYL BUTYL PHTHALATE
UG/KG
460
u
660
u
350
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
450
u
560
u
350
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
450
u
560
u
350
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
450
u
560
u
350
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
450
u
560
u
350
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
CI FLUORANTHENES/PYRENES
UG/KG
450
UJ
560
UJ
350
UJ
CI FLUORENES
UG/KG
450
UJ
560
UJ
350
UJ
CI NAPHTHALENES
UG/KG
450
UJ
560
UJ
350
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C2FLUORENES
UG/KG
450
UJ
560
UJ
350
UJ
C2 NAPHTHALENES
UG/KG
450
UJ
560
UJ
350
UJ
-------
Table 5-15(D) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD409
SD410
SD411
Effects
11/18/97
11/18/97
11/18/97
Values
09:55
10:20
10:50
C2 PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C3 FLUORENES
UG/KG
450
UJ
560
UJ
350
UJ
C3 NAPHTHALENES
UG/KG
450
UJ
560
UJ
350
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
C4 NAPHTHALENES
UG/KG
450
UJ
560
UJ
350
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
450
UJ
560
UJ
350
UJ
CARBAZOLE
UG/KG
450
U
560
u
350
u
CHRYSENE
UG/KG
108
110
J
170
J
120
J
DI-N-BUTYLPHTHALATE
UG/KG
2400
u
3700
u
2500
u
DI-N-OCTYLPHTHALATE
UG/KG
450
u
560
u
350
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
110
J
67
J
96
J
DIBENZOFURAN
UG/KG
450
u
560
u
350
u
DIBUTYL TIN
UG/KG
200
u
280
u
180
u
DIETHYL PHTHALATE
UG/KG
450
u
560
u
350
u
DIMETHYL PHTHALATE
UG/KG
450
u
560
u
350
u
FLUORANTHENE
UG/KG
113
340
J
360
J
430
FLUORENE
UG/KG
21.2
450
u
560
u
350
u
HEXACHLOROBENZENE (HCB)
UG/KG
450
u
560
u
350
u
HEXACHLOROBUTADIENE
UG/KG
450
u
560
u
350
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
450
u
560
u
350
u
HEXACHLOROETHANE
UG/KG
450
u
560
u
350
u
HEXADECENOIC ACID
UG/KG
NR
8000
JN
NR
INDENO (1,2,3-CD) PYRENE
UG/KG
300
J
170
J
250
J
ISOPHORONE
UG/KG
450
u
560
u
350
u
MONOBUTYL TIN
UG/KG
200
u
280
u
180
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
450
u
560
u
350
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE UG/KG
450
u
560
u
350
u
NAPHTHALENE
UG/KG
34.6
450
u
560
u
350
u
NITROBENZENE
UG/KG
450
u
560
u
350
u
PENTACHLOROPHENOL
UG/KG
900
u
1100
u
700
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
43
J
39
J
78
J
PHENOL
UG/KG
450
u
560
u
350
u
PYRENE
UG/KG
153
280
J
350
J
370
TETRABUTYL TIN
UG/KG
200
u
280
u
180
u
TETRADECANOIC ACID
UG/KG
NR
5000
JN
NR
TRIBUTYL TIN
UG/KG
200
u
280
u
180
U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(PENTYLHEPTYL)BENZENE
1 UNIDENTIFIED COMPOUND
1.2.4-TRICHLOROBENZENE
2 UNIDENTIFIED COMPOUNDS
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CIFLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
Table 5-15(E)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD412
Effects 11/18/97
Values 11.15
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
182
80.1
680 U
3000 JN
NR
680 U
8000 J
680 U
680 U
680 U
680 U
680 U
1400 U
680 U
680 U
680 U
680 U
1400 U
680 U
680 U
680 U
680 U
680 U
680 U
680 U
680 U
680 U
680 U
680 U
1400 U
680 V
680 U
680 U
170 J
940
380 J
720
250 J
680 U
680 U
680 U
680 U
2900 U
680 UJ
680 UJ
680 UJ
680 UJ
680 UJ
680 UJ
SD413
11/18/97
11:45
81.7
650 U
NR
10000 J
650 U
NR
650 U
650 U
650 U
650 U
650 U
1300 U
650 U
650 U
650 U
650 U
1300 U
650 U
650 U
650 U
650 U
650 U
650 U
650 U
650 U
650 U
650 U
650 U
1300 U
650 U
36 J
650 U
210 J
680
320 J
170 J
230 J
650 U
650 U
650 U
650 U
3800 U
650 UJ
650 UJ
650 UJ
650 UJ
650 UJ
650 UJ
SD414
11/18/97
13:01
70.6
430 U
NR
5000 J
430 U
NR
430 U
430 U
430 U
430 U
430 U
860 U
430 U
430 U
430 U
430 U
860 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
860 U
430 U
430 U
430 U
140 J
520
220 J
150 J
160 J
430 U
430 U
430 U
430 U
820 U
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
-------
Table 5-15(E) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD412
SD413
SD414
Effects
11/18/97
11/18/97
11/18/97
Values
11:15
11:45
13:01
C2 FLUORENES
UG/KG
680
UJ
650
UJ
430
UJ
C2 NAPHTHALENES
UG/KG
680
UJ
650
UJ
430
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
680
UJ
650
UJ
430
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/KG
680
UJ
650
UJ
430
UJ
C3 FLUORENES
UG/KG
680
UJ
650
UJ
430
UJ
C3 NAPHTHALENES
UG/KG
680
UJ
650
UJ
430
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/KG
680
UJ
650
UJ
430
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/KG
680
UJ
650
UJ
430
UJ
C4 NAPHTHALENES
UG/KG
680
UJ
650
UJ
430
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/KG
680
UJ
650
UJ
430
UJ
CARBAZOLE
UG/KG
680
U
650
U
430
U
CHRYSENE
UG/KG
108
140
J
210
J
120
J
DI-N-BUTYLPHTHALATE
UG/KG
3700
u
3800
u
2900
u
DI-N-OCTYLPHTHALATE
UG/KG
680
U
650
u
430
u
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
130
J
95
J
69
J
DIBENZOFURAN
UG/KG
680
U
650
u
430
u
DIBUTYL TIN
UG/KG
310
u
330
u
200
u
DIETHYL PHTHALATE
UG/KG
680
u
650
u
430
u
DIMETHYL PHTHALATE
UG/KG
680
u
650
u
430
u
FLUORANTHENE
UG/KG
113
600
J
880
430
J
FLUORENE
UG/KG
21.2
680
u
650
u
430
u
HEXACHLOROBENZENE(HCB)
UG/KG
680
u
650
u
430
u
HEXACHLOROBUTADIENE
UG/KG
680
u
650
u
430
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/KG
680
u
650
u
430
u
HEXACHLOROETHANE
UG/KG
680
u
650
u
430
u
INDENO (1,2,3-CD) PYRENE
UG/KG
330
J
260
J
190
J
ISOPHORONE
UG/KG
680
u
650
u
430
u
MONOBUTYL TIN
UG/KG
310
u
330
u
200
u
N-NITROSODI-N-PROPYLAMINE
UG/KG
680
u
650
u
430
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
680
u
650
u
430
u
naphthalene
UG/KG
34.6
680
u
650
u
430
u
NITROBENZENE
UG/KG
680
u
650
u
430
u
PENTACHLOROPHENOL
UG/KG
1400
u
1300
u
860
u
PETROLEUM PRODUCT
UG/KG
N
N
N
PHENANTHRENE
UG/KG
86.7
47
J
52
J
52
J
PHENOL
UG/KG
680
u
650
u
430
u
PYRENE
UG/KG
153
340
J
430
J
320
J
TETRABUTYL TIN
UG/KG
310
u
330
u
200
u
TETRAHYDRONAPHTHALENE
UG/KG
NR
6000
JN
NR
TRIBUTYL TIN
UG/KG
310
U
330
u
200
u
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORON APHTH ALEN E
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-N1TROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CIFLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
Table 5-15(F)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 20.23
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 6.71
UG/KG 5.87
UG/KG 46.9
UG/KG 74.8
UG/KG
UG/KG
UG/KG
UG/KG 88.8
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG 182
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
SD415
11/18/97
13:01
64.9
360 U
360 U
360 U
360 U
360 U
360 U
360 U
710 U
360 U
360 U
360 U
360 U
710 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
710 U
360 U
360 U
360 U
100 J
210 J
170 J
120 J
100 J
360 U
360 U
360 U
360 U
360 U
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
SD416
11/18/97
13:20
79.3
570 U
570 U
570 U
570 U
570 U
570 V
570 U
1100 U
570 U
570 U
570 U
570 U
1100 U
570 U
570 U
570 U
570 U
570 U
570 U
570 U
570 U
570 U
570 U
570 U
1100 U
570 U
40 J
570 U
180 J
370 J
290 J
190 J
180 J
570 U
570 U
570 U
570 U
9500 U
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
SD417
11/18/97
13:45
79.2
590 U
590 U
590 U
590 U
590 U
590 U
590 U
1200 U
590 U
590 U
590 U
590 U
1200 U
590 U
590 U
590 U
590 U
590 U
590 U
590 U
590 U
590 U
590 U
590 U
1200 U
590 U
590 U
590 U
150 J
280 J
220 J
130 J
130 J
590 U
590 U
590 U
590 U
4800 U
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
-------
Table 5-15(F) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
108
6.22
H3
21.2
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
fluorene
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAM)
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TETRAHYDRONAPHTHALENE
tributyl tin
Note: The estimated detection limit can be calculated by dividing thP m,„.
Note: Reported values exceeding the RAGS EV are in bold Values with Rnr" qUant,tatlon hmit by 20¦
aiues with EDL exceeding RAGS EV
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
34.6
UG/KG
UG/KG
UG/KG
UG/KG
86.7
UG/KG
UG/KG
153
UG/KG
UG/KG
UG/KG
SD415
11/18/97
13:01
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 U
87 J
2600 U
360 U
52 J
360 U
160 U
360 U
360 U
340 J
360 U
360 U
360 U
360 U
360 U
140 J
360 U
160 U
360 U
360 U
360 U
360 U
710 U
N
34 J
360 U
280 J
160 U
NR
160 U
SD4I6
11/18/97
13:20
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 UJ
570 U
160 J
3000 U
570 U
97 J
570 U
280 U
570 U
570 U
1300
570 U
570 U
570 U
570 U
570 U
240 J
570 U
280 U
570 U
570 U
570 U
570 U
1100 U
N
43 J
570 U
460 J
280 U
NR
280 U
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD417
11/18/97
13:45
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 UJ
590 U
120 J
3500 U
590 U
71 J
590 U
280 U
590 U
590 U
990
590 U
590 U
590 U
590 U
590 U
180 J
590 U
280 U
590 U
590 U
590 U
590 U
1200 U
N
39 J
590 U
300 J
280 U
4000 JN
280 U
are italicized.
-------
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(DIMETHYLHEXYL)BENZENE
(PENTYLHEPTYL)BENZENE
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHEN OL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4 UNIDENTIFIED COMPOUNS
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
Table 5-15(G)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD417DUP
Effects 11/18/97
Values 13:50
SD418
11/18/97
14:03
SD419
11/18/97
14:27
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
182
79.2
610 U
NR
3000 JN
610 U
610 U
610 U
610 U
610 U
610 U
1200 U
610 U
610 U
610 U
610 U
1200 U
610 V
610 U
610 U
610 U
610 U
610 U
NR
610 U
610 U
610 U
610 U
610 U
1200 U
610 U
610 U
610 U
190 J
310 J
280 J
180 J
170 J
7700 U
610 U
610 U
610 U
610 U
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
68.1
370 U
3000 JN
NR
370 U
370 U
370 U
370 U
370 U
370 U
740 U
370 U
370 U
370 U
370 U
740 U
370 U
370 U
370 U
370 U
370 U
370 U
NR
370 U
370 U
370 U
370 U
370 U
740 U
370 U
370 U
370 U
140 J
270 J
190 J
110
120
370 U
370 U
370 U
370 U
810 U
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
J
J
77.4
560 U
NR
NR
560 U
560 U
560 U
560 U
560 U
560 U
1100 U
560 U
560 U
560 U
560 U
1100 U
560 U
560 U
560 U
560 U
560 U
560 U
30000 J
560 U
560 U
560 U
560 U
560 U
1100 U
560 U
19 J
110 J
2100
2200
990
1400
1400
560 U
560 U
560 U
560 U
640 U
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
-------
Table 5-15(G) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD417DUP
Effects 11/18/97
C2 FLUORENES
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
dibenzofuran
dibutyl tin
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
fluorene
HEXACHLOROBENZENE (HCB)
hexachlorobutadiene
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
monobutyl tin
n-nitrosodi-n-propylamine
n-nitrosodiphenylamine/diphenylamine
naphthalene
nitrobenzene
pentachlorophenol
petroleum product
phenanthrene
phenol
pyrene
tetrabutyl tin
tetrahydronaphthalene
tributyl tin
Values
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
13:50
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 UJ
610 U
140 J
2800 U
610 U
92 J
610 U
300 U
610 U
610 U
1100
610 U
610 U
610 U
610 U
610 U
230 J
610 U
300 U
610 U
610 U
610 U
610 U
1200 U
N
52 J
610 U
510 J
300 U
NR
300 U
SD418
11/18/97
14:03
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 UJ
370 U
100 J
2100 U
370 U
63 J
370 U
190 U
370 U
370 U
410
370 U
370 U
370 U
370 U
370 U
160 J
370 U
190 U
370 U
370 U
370 U
370 U
740 U
N
46 J
370 U
350 J
190 U
4000 JN
190 U
SD419
11/18/97
14:27
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 U
990
3400 U
560 U
440 J
560 U
280 U
560 U
560 U
1400
560 U
560 U
560 U
560 U
560 U
800
560 U
280 U
560 U
560 U
560 U
560 U
1100 U
N
220 J
560 U
1400
280 U
3000 JN
280 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-15(H)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD420 SD421
Effects 11/18/97 11/18/97
Values 14:47 15:20
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(DIMETHYLHEXENYL)BENZENE
1 UNIDENTIFIED COMPOUND
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITRO ANI LIN E
4-NITROPHENOL
5 UNIDENTIFIED COMPOUNDS
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
61.7
290 U
NR
2000 J
290 U
290 U
290 U
290 U
290 U
290 U
580 U
290 U
290 U
290 U
290 U
580 U
290 U
290 U
290 U
290 U
290 U
290 U
290 U
290 U
290 U
290 U
290 U
580 U
NR
290 U
J
J
J
J
J
J
U
182
14
20
ISO
380
220
100
160
290
290 U
290 U
290 U
480 U
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
76.8
560 U
5000 JN
NR
560 U
560 U
560 U
560 U
560 U
560 U
1100 U
560 U
560 U
560 U
560 U
1100 U
560 U
560 U
560 U
560 U
560 U
560 U
560 U
560 U
560 U
560 U
560 U
1100 U
30000 J
100 J
47 J
160 J
1000
1200
670
660
810
590 U
560 U
560 U
560 U
1200 U
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
560 UJ
SD422
11/18/97
15:47
67.5
360 U
NR
NR
360 U
360 U
360 U
360 U
360 U
360 U
720 U
360 U
360 U
360 U
360 U
720 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
720 U
NR
360 U
40 J
81 J
540
960
490
370
560
360 U
360 U
360 U
360 U
360 U
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
-------
Table 5-15(H) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 FLUORENES
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
Dr-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
RAGS SD420
Effects 11/18/97
Values 14:47
290
290
290
290
108
6.22
113
21.2
INDENO (1,2,3-CD) PYRENE
UG/KG
ISOPHORONE
UG/KG
MONOBUTYL TIN
UG/KG
N-NITROSODI-N-PROPYLAMINE
UG/KG
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/KG
NAPHTHALENE
UG/KG
34.6
NITROBENZENE
UG/KG
PENTACHLOROPHENOL
UG/KG
PETROLEUM PRODUCT
UG/KG
PHENANTHRENE
UG/KG
86.7
PHENOL
UG/KG
PYRENE
UG/KG
153
TETRABUTYL TIN
UG/KG
TETRAHYDRONAPHTHALENE
UG/KG
TRIBUTYL TIN
UG/KG
UJ
UJ
UJ
UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 UJ
290 U
130 J
1800 U
290
73
290
160
290
290
340
290
290
290
290
290
190
290
160
290
290
290
290
580
U
J
U
u
u
u
53
290
310
160
160
U
u
u
u
u
J
u
u
u
u
u
u
u
N
J
u
u
NR
u
SD421
11/18/97
15:20
560 UJ
560 UJ
560 UJ
560 UJ
560
560
560
560
560
560
560
670
6900
560
270
560
260
560
560
2300
77 J
560 U
560 U
560
560
540
560
260
560
560
560
560
1100
UJ
UJ
UJ
UJ
UJ
UJ
U
U
U
J
U
U
U
u
U
u
J
u
u
u
u
u
u
u
N
600
560 U
1700
260 U
3000 JN
260 U
Note: The estimated detection limit can be calculated by dividing the minimum Mu«nuianon Urn.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD422
11/18/97
15:47
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 U
690
2500 U
360 U
200 J
360 U
190 U
360 V
360 U
940
360 U
360 U
360 U
360 U
360 U
480
360 U
190 U
360 U
360 U
360 U
360 U
720 U
N
170 J
360 U
660
19 0 U
NR
190 U
quantitation limit by 20.
EV are italicized.
-------
Table 5-15(1)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD423
SD424
SD425
Effects
11/18/97
11/19/97
11/19/97
Values
16:15
09:17
09:25
% MOISTURE
%
74.8
76
66.8
(3-AND/OR 4-)METHYLPHENOL
UG/KG
450 U
510 U
630 U
(DIMETHYLHEXENYL)BENZENE
UG/KG
NR
NR
4000 JN
1,2,4-TRICHLOROBENZENE
UG/KG
450 U
510 U
630 U
2 UNIDENTIFIED COMPOUNDS
UG/KG
NR
NR
40000 J
2,3,4,6-TETRACHLOROPHENOL
UG/KG
450 U
510 U
630 U
2,4,5-TRICHLOROPHENOL
UG/KG
450 U
510 U
630 U
2,4,6-TRICHLOROPHENOL
UG/KG
450 U
510 U
630 U
2,4-DICHLOROPHENOL
UG/KG
450 U
510 U
630 U
2,4-DIMETHYLPHENOL
UG/KG
450 U
510 U
630 U
2,4-DINITROPHENOL
UG/KG
890 U
1000 U
1300 U
2,4-DINITROTOLUENE
UG/KG
450 U
510 U
630 U
2,6-DINITROTOLUENE
UG/KG
450 U
510 U
630 U
2-CHLORONAPHTHALENE
UG/KG
450 U
510 U
630 U
2-CHLOROPHENOL
UG/KG
450 U
510 U
630 U
2-METHYL-4.6-DINITROPHENOL
UG/KG
890 U
1000 U
1300 U
2-METHYLNAPHTHALENE
UG/KG
20.23
450 U
510 U
630 U
2-METHYLPHENOL
UG/KG
450 U
510 U
630 U
2-NITROANILINE
UG/KG
450 U
510 U
630 U
2-NITROPHENOL
UG/KG
450 U
510 U
630 U
3,3 '-DICHLOROBENZIDINE
UG/KG
450 U
510 U
630 U
3-NITROANILINE
UG/KG
450 U
510 U
630 U
4-BROMOPHENYL PHENYL ETHER
UG/KG
450 U
510 U
630 U
4-CHLORO-3-METHYLPHENOL
UG/KG
450 U
510 U
630 U
4-CHLOROANILINE
UG/KG
450 U
510 U
630 U
4-CHLOROPHENYL PHENYL ETHER
UG/KG
450 U
510 U
630 U
4-NITRO ANILINE
UG/KG
450 U
510 U
630 U
4-NITROPHENOL
UG/KG
890 U
1000 U
1300 U
ACENAPHTHENE
UG/KG
6.71
450 U
31 J
48 J
ACENAPHTHYLENE
UG/KG
5.87
450 U
110 J
200 J
ANTHRACENE
UG/KG
46.9
29 J
160 J
270 J
BENZO(A)ANTHRACENE
UG/KG
74.8
190 J
1500
3400
BENZO(B)FLUORANTHENE
UG/KG
430 J
3000
6700
BENZO(GHI)PERYLENE
UG/KG
240 J
1000
1800
BENZO(K)FLUORANTHENE
UG/KG
150 J
820
1300
BENZO-A-PYRENE
UG/KG
88.8
180 J
1200
2400
BENZYL BUTYL PHTHALATE
UG/KG
600 U
510 U
630 U
BIS(2-CHLOROETHOXY)METHANE
UG/KG
450 U
510 U
630 U
BIS(2-CHLOROETHYL) ETHER
UG/KG
450 U
510 U
630 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
450 U
510 U
630 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
450 U
1200 U
630 U
CI CHRYSENES/BENZANTHRACENES
UG/KG
450 UJ
510 UJ
630 UJ
CI FLUORANTHENES/PYRENES
UG/KG
450 UJ
510 UJ
630 UJ
CI FLUORENES
UG/KG
450 UJ
510 UJ
630 UJ
CI NAPHTHALENES
UG/KG
450 UJ
510 UJ
630 UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
450 UJ
510 UJ
630 UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
450 UJ
510 UJ
630 UJ
C2 FLUORENES
UG/KG
450 UJ
510 UJ
630 UJ
-------
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TETRAHYDRONAPHTHALENE
TRIBUTYL TIN
Table 5-15(1) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
212
34.6
86.7
153
SD423
11/18/97
16:15
450 UJ
450 UJ
450 UJ
450 UJ
450 UJ
450 UJ
450 UJ
450 UJ
450 UJ
450 U
170 J
2400 U
450 U
78 J
450 U
240 U
450 U
450 U
NR
540
450 U
450 U
450 U
450 U
450 U
200 J
450 U
240 U
450 U
450 U
450 U
450 U
890 U
NR
150 J
450 U
360 J
240 U
NR
240 U
SD424
11/19/97
09:17
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 UJ
510 U
1200
510 U
510 U
390 J
510 U
100 J
510 U
510 U
NR
3100
31 J
510 U
510 U
510 U
510 U
900
510 U
250 U
510 U
510 U
510 U
U
U
NR
J
U
510
1000
220
510
2400
250 U
NR
250 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit bv 20
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD425
11/19/97
09:25
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 U
2100
630 U
630 U
550 J
630 U
160 J
630 U
630 U
6000 JN
5400
51 J
630 U
630 U
630 U
630 U
1700
630 U
310 U
630 U
630 U
630 U
630 U
1300 U
N
250 J
630 U
4500
310 U
5000 JN
310 U
-------
Table 5-15(J)
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD503A
SD503B
Effects
11/19/97
11/19/97
Values
11:15
11:15
% MOISTURE
%
57.8
38.7
(3-AND/OR 4-)METHYLPHENOL
UG/KG
300
U
200
u
1,2,4-TRICHLOROBENZENE
UG/KG
300
U
200
u
2,3,4,6-TETRACHLOROPHENOL
UG/KG
300
U
200
u
2,4,5-TRICHLOROPHENOL
UG/KG
300
U
200
u
2,4,6-TRJCHLOROPHENOL
UG/KG
300
U
200
u
2,4-DICHLOROPHENOL
UG/KG
300
U
200
u
2,4-DIMETHYLPHENOL
UG/KG
300
U
200
u
2,4-DINITROPHENOL
UG/KG
600
u
410
u
2,4-DINITROTOLUENE
UG/KG
300
U
200
u
2,6-DINITROTOLUENE
UG/KG
300
u
200
u
2-CHLORONAPHTHALENE
UG/KG
300
u
200
u
2-CHLOROPHENOL
UG/KG
300
u
200
u
2-METHYL-4.6-DINITROPHENOL
UG/KG
600
U
410
u
2-METHYLNAPHTHALENE
UG/KG
20.23
27
J
200
u
2-METHYLPHENOL
UG/KG
300
U
200
u
2-NITROANILINE
UG/KG
300
U
200
u
2-NITROPHENOL
UG/KG
300
u
200
u
3,3'-DICHLOROBENZIDIN E
UG/KG
300
u
200
u
3-NITROANILINE
UG/KG
300
u
200
u
4 UNIDENTIFIED COMPOUNDS
UG/KG
30000
J
NR
4-BROMOPHENYL PHENYL ETHER
UG/KG
300
u
200
u
4-CHLORO-3-METHYLPHENOL
UG/KG
300
u
200
u
4-CHLOROANILINE
UG/KG
300
u
200
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
300
u
200
u
4-NITROANILINE
UG/KG
300
u
200
u
4-NITROPHENOL
UG/KG
600
u
410
u
ACENAPHTHENE
UG/KG
6.71
90
J
200
u
ACENAPHTHYLENE
UG/KG
5.87
260
J
200
u
ANTHRACENE
UG/KG
46.9
450
200
u
BENZO(A)ANTHRACENE
UG/KG
74.8
2100
45
J
BENZO(B)FLUORANTHENE
UG/KG
1900
47
J
BENZO(GHI)PERYLENE
UG/KG
860
21
J
BENZO(K)FLUORANTHENE
UG/KG
150
J
19
J
BENZO-A-PYRENE
UG/KG
88.8
1400
24
J
BENZYL BUTYL PHTHALATE
UG/KG
300
u
200
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
300
u
200
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
300
u
200
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
300
u
200
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
300
u
200
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
1700
JN
200
UJ
CI FLUORANTHENES/PYRENES
UG/KG
7100
JN
200
UJ
CI FLUORENES
UG/KG
500
JN
200
UJ
CI NAPHTHALENES
UG/KG
27
JN
200
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
3500
JN
200
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
330
JN
200
UJ
C2 FLUORENES
UG/KG
300
UJ
200
UJ
C2NAPHTHALENES
UG/KG
360
JN
200
UJ
-------
Table 5-15(J) - Continued
Sediment Analytical Results - Extractables
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHLOROBIS(CHLOROPHENYL)ETHANONE
CHRYSENE
DI-N-B UTY LPHTH ALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
SD503A
11/19/97
11:15
1200 JN
300 UJ
300 UJ
570 JN
390 JN
300 UJ
230 JN
67 JN
300 U
3000 JN
1300
300 U
300 U
220 J
300 U
83 J
300 U
300 U
2600
180 J
300 U
300 U
300 U
300 U
650
300 U
140 U
300 U
300 U
45 J
300 U
600 U
N
1500
300 U
3600
140 U
140 U
SD503B
11/19/97
11:15
200 UJ
200 UJ
200 UJ
200 UJ
200 UJ
200 UJ
200 UJ
200 UJ
200 U
NR
35 J
200 U
200 U
200 U
200 U
45 J
200 U
200 U
110 J
21 J
200 U
200 U
200 U
200 U
18 J
200 U
92 U
200 U
200 U
200 U
200 U
410 U
NR
200 U
200 U
110 J
92 U
92 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-16(A)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD601
SD602
SD603
Effects
11/18/97
11/18/97
11/18/97
Values
08:45
09:08
09:31
% MOISTURE
%
41
54.7
53.4
(3-AND/OR 4-)METHYLPHENOL
UG/KG
220
U
250
U
260
U
1 UNIDENTIFIED COMPOUND
UG/KG
NR
1000
J
NR
1,2,4-TRICHLOROBENZENE
UG/KG
220
U
250
U
260
U
2,3,4,6-TETRACH LOROPHEN OL
UG/KG
220
U
250
U
260
U
2,4,5-TRICHLOROPHENOL
UG/KG
220
u
250
U
260
U
2,4,6-TRICHLOROPHENOL
UG/KG
220
u
250
U
260
u
2,4-DICHLOROPHENOL
UG/KG
220
u
250
u
260
u
2,4-DIMETHYLPHENOL
UG/KG
220
u
250
u
260
u
2,4-DINITROPHENOL
UG/KG
430
U
500
u
530
u
2,4-DINITROTOLUENE
UG/KG
220
u
250
u
260
u
2,6-DINITROTOLUENE
UG/KG
220
u
250
u
260
u
2-CHLORONAPHTHALENE
UG/KG
220
U
250
u
260
u
2-CHLOROPHEN OL
UG/KG
220
U
250
u
260
u
2-METHYL-4,6-DINITROPHENOL
UG/KG
430
u
500
u
530
u
2-METHYLNAPHTHALENE
UG/KG
20.23
220
u
250
u
260
u
2-METHYLPHENOL
UG/KG
220
u
250
u
260
u
2-NITROANILINE
UG/KG
220
u
250
u
260
u
2-NITROPHENOL
UG/KG
220
u
250
u
260
u
3,3'-DICHLOROBENZIDINE
UG/KG
220
U
250
u
260
u
3-NITRO ANILINE
UG/KG
220
u
250
u
260
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
220
u
250
u
260
u
4-CHLORO-3-METHYLPHENOL
UG/KG
220
u
250
u
260
u
4-CHLOROANILINE
UG/KG
220
u
250
u
260
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
220
u
250
u
260
u
4-NITROANILINE
UG/KG
220
u
250
u
260
u
4-NITROPHENOL
UG/KG
430
u
500
u
530
u
ACENAPHTHENE
UG/KG
6.71
220
u
250
u
260
u
ACENAPHTHYLENE
UG/KG
5.87
220
u
250
u
260
u
ANTHRACENE
UG/KG
46.9
220
u
250
u
260
u
BENZO(A)ANTHRACENE
UG/KG
74.8
15
J
73
J
25
J
BENZO(B)FLUORANTHENE
UG/KG
19
J
100
J
54
J
BENZO(GHI)PERYLENE
UG/KG
13
J
79
J
36
J
BENZO(K)FLUORANTHENE
UG/KG
220
u
61
J
22
J
BENZO-A-PYRENE
UG/KG
88.8
11
J
65
J
24
J
BENZYL BUTYL PHTHALATE
UG/KG
280
u
580
u
260
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
220
u
250
u
260
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
220
u
250
u
260
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
220
u
250
u
260
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
220
u
600
u
260
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
220
UJ
250
UJ
260
UJ
CI FLUORANTHENES/PYRENES
UG/KG
220
UJ
250
UJ
260
UJ
CI FLUORENES
UG/KG
220
UJ
250
UJ
260
UJ
CI NAPHTHALENES
UG/KG
220
UJ
250
UJ
260
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
220
UJ
250
UJ
260
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
220
UJ
250
UJ
260
UJ
C2 FLUORENES
UG/KG
220
UJ
250
UJ
260
UJ
C2 NAPHTHALENES
UG/KG
220
UJ
250
UJ
260
UJ
-------
Table 5-16(A) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (),2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYL AMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
SD601
11/18/97
08:45
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 UJ
220 U
220 U
820 U
220 U
220 U
220 U
92 U
220 U
220 U
28 J
220 U
220 U
220 U
220 U
220 U
12 J
220 U
92 U
220 U
220 U
220 U
220 U
430 U
NR
220 U
220 U
22 J
92 U
92 U
SD602
11/18/97
09:08
250 UJ
250 UJ
250 UJ
250 UJ
250 UJ
250 UJ
250 UJ
250 UJ
250 U
66 J
1400 U
250 U
250 U
250 U
130 U
250 U
250 U
170 J
250 U
250 U
250 U
250 U
250 U
69 J
250 U
130 U
250 U
250 U
250 U
250 U
500 U
N
43 J
250 U
110 J
130 U
130 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumpti ve evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD603
11/18/97
09:31
260 UJ
260 UJ
260 UJ
260 UJ
260 UJ
260 UJ
260 UJ
260 UJ
260 U
22 J
910 U
260 U
260 U
260 U
130 U
260 U
260 U
80 J
260 U
260 U
260 U
260 U
260 U
30 J
260 U
130 U
260 U
260 U
260 U
260 U
530 U
NR
14 J
260 U
39 J
130 U
130 U
-------
Table 5-16(B)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(PHENYLMETHYL)NAPHTHALENE
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
RAGS
SD604
SD605 :
SD605DUP
Effects
11/18/97
11/18/97
11/18/97
Values
09:55
10:20
10:25
%
62.8
63.2
64.3
UG/KG
340 U
330 U
320 U
UG/KG
NR
3000 JN
NR
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
670 U
660 U
640 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
670 U
660 U
640 U
UG/KG
20.23
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
670 U
660 U
640 U
UG/KG
6.71
340 U
330 U
320 U
UG/KG
5.87
340 U
330 U
320 U
UG/KG
46.9
340 U
330 U
320 U
UG/KG
74.8
57 J
34 J
32 J
UG/KG
120 J
85 J
77 J
UG/KG
77 J
52 J
47 J
UG/KG
70 J
23 J
26 J
UG/KG
88.8
57 J
34 J
34 J
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
340 U
330 U
320 U
UG/KG
182
340 U
330 U
320 U
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
UG/KG
340 UJ
330 UJ
320 UJ
-------
L
RAGS
Effects
Values
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
DODECANOIC ACID, TETRADECYL ESTER
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
UJ
UJ
U J
UJ
UJ
UJ
SD604
11/18/97
09:55
340
340
340
340
340
340
340 UJ
340 UJ
340 U
49 J
340 U
340 U
17 J
340 U
150 U
340 U
340 U
NR
JN
J
U
U
u
u
2000
120
340
340
340
340
340
69
340
150
340
340
340
340
670
24
340
89
150
150
U
J
U
U
u
u
u
u
u
N
J
u
J
u
u
SD 605
11/18/97
10:20
330 UJ
330 UJ
330 UJ
330 UJ
330 UJ
330 UJ
330 UJ
330 UJ
330 U
28 J
330 U
330 U
330 U
330 U
150 U
330 U
330 U
2000 JN
NR
70 J
330 U
330 U
330 V
330 U
330 U
43 J
330 U
150 U
330 U
330 U
330 U
330 U
660 U
N
U
U
J
u
u
330
330
49
150
150
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the mmmum quantitation limit.
are italicized.
SD605DUP
11/18/97
10:25
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 UJ
320 U
27 J
320 U
320 U
320 U
320 U
93 J
320 U
320 U
2000 JN
NR
69 J
320 U
320 U
320 U
320 U
320 U
40 J
320 U
170 U
320 U
320 U
320 U
320 U
640 U
N
320 U
320 U
47 J
170 U
170 U
-------
Table 5-16(C)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1 UNIDENTIFIED COMPOUND
1.2.4-TRlCHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DlMETHYLPHENOL
2,4-DINITROPHEKOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLN APHTH ALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DlCHLOROBENZIDINE
3-N1TROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2 FLUORENES
C2 NAPHTHALENES
RAGS
Effects
Values
SD606
11/18/97
11:48
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
182
SD607
11/18/97
13:02
67.8
380 U
2000 J
380 U
380 U
380 U
380 U
380 U
380 U
760 U
380 U
380 U
380 U
380 U
760 U
380 U
380 U
380 U
380 U
380 U
380 U
380 U
380 U
380 U
380 U
380 U
760 U
380 V
380 V
380 U
92 J
270 J
170 ]
63 J
110 J
380 U
380 U
380 U
380 U
2500 U
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
SD608
11/18/97
13:26
71.9
400 U
NR
400 U
400 U
400 U
400 U
400 U
400 U
800 U
400 U
400 U
400 U
400 U
800 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
800 U
400 V
400 V
400 U
44 J
110 J
86 J
48 J
52 J
400 U
400 U
400 U
400 U
400 U
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 VJ
400 UJ
69.8
430 U
NR
430 U
430 U
430 U
430 U
430 U
430 U
850 U
430 U
430 U
430 U
430 U
850 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
850 U
430 V
430 U
430 U
49 J
130 J
83 J
32 J
53 J
430 U
430 U
430 U
430 U
540 U
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 VJ
430 UJ
430 UJ
-------
Table 5-16(C) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
Effects
Values
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEX ACHLOROBUT ADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHEN OL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
113
21.2
34.6
86.7
153
SD606
II/l 8/97
11:48
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 UJ
380 U
80 J
380 U
380 U
36 J
380 U
190 U
380 U
380 U
NR
230 J
380 U
380 U
380 U
380 U
380 U
140 J
380 U
190 U
380 U
380 U
380 U
380 U
760 U
N
32 J
380 U
150 J
190 U
190 U
SD607
11/18/97
13:02
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 U
34 J
400 U
400 U
400 U
400 U
120 J
400 U
400 U
5000 JN
86 J
400 U
400 U
400 U
400 U
400 U
72 J
400 U
210 U
400 U
400 U
400 U
400 U
800 U
N
400 U
400 U
68 J
210 U
210 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD608
11/18/97
13:26
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 U
40 J
430 U
430 U
430 U
430 U
210 U
430 U
430 U
NR
110 J
430 U
430 U
430 U
430 U
430 U
68 J
430 U
210 U
430 U
430 U
430 U
430 U
850 U
N
430 U
430 U
81 J
210 U
210 U
-------
Table 5-16(D)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1.2.4-TRlCHLOROBENZENE
2 UNIDENTIFIED COMPOUNDS
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINlTROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
RAGS SD609
Effects 11/18/97
Values
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
182
14:34
68
360 V
360 U
5000 J
360 U
360 U
360 U
360 U
360 U
720 U
360 U
360 U
360 U
360 U
720 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
720 U
360 U
360 U
360 U
49 J
120 J
87 J
51 J
61 J
360 U
360 U
360 U
360 U
360 U
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
360 UJ
SD610
11/18/97
15:00
70.3
430 U
430 U
NR
430 U
430 U
430 U
430 U
430 U
870 U
430 U
430 U
430 U
430 U
870 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
430 U
870 U
430 U
430 U
430 U
65 J
180 J
110 J
48 J
78 J
430 U
430 U
430 U
430 U
430 U
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
SD701
11/19/97
16:20
80.8
630 U
630 U
20000 J
630 U
630 U
630 U
630 U
630 U
1300 U
630 U
630 U
630 U
630 U
1300 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
1300 U
630 U
630 U
41 J
490 J
1300
800
490 J
630 J
630 U
630 U
630 U
630 U
630 U
630 UJ
630 UJ
630 UJ
630 UJ
100 JN
630 UJ
630 UJ
630 UJ
-------
Table 5-16(D) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-B UT YLPHTH ALA TE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
DODECANOIC ACID, HEXADECYL ESTER (2 ISOMERS UG/KG
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
HEXADECANOIC ACID
HEXADECENOIC ACID
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
RAGS SD609
Effects ] 1/18/97
Values 14:34
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 UJ
UG/KG 360 U
UG/KG 108 45 J
UG/KG 360 U
UG/KG 360 U
UG/KG 6.22 20 J
UG/KG 360 U
UG/KG 98 J
UG/KG 360 U
UG/KG 360 U
UG/KG 4000 JN
NR
UG/KG 113 120 J
UG/KG 212 360 U
UG/KG 360 U
UG/KG 360 U
UG/KG 360 U
UG/KG 360 U
UG/KG NR
UG/KG NR
UG/KG 72 J
UG/KG 360 U
UG/KG 200 U
UG/KG 360 U
UG/KG 360 U
UG/KG 34.6 360 U
UG/KG 360 U
UG/KG 720 U
UG/KG N
UG/KG 86.7 360 U
UG/KG 360 U
UG/KG 153 81 J
UG/KG 200 U
UG/KG 200 U
SD6I0
11/18/97
15:00
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 UJ
430 U
54 J
430 U
430 U
26 J
430 U
120 J
430 U
430 U
NR
NR
120 J
430 V
430 U
430 U
430 U
430 U
NR
NR
96 J
430 U
190 U
430 U
430 U
430 U
430 U
870 U
N
430 U
430 U
89 J
190 U
190 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD701
11/19/97
16:20
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 UJ
630 U
440 J
630 U
630 U
160 J
630 U
160 J
630 U
630 U
NR
20000 JN
940
630 V
630 U
630 U
630 U
630 U
6000 JN
5000 JN
690
630 U
300 U
630 U
630 U
630 U
630 U
1300 U
N
120 J
630 U
760
300 U
300 U
-------
Table 5-16(E)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
(PHENYLMETHYL)NAPHTHALENE
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DIN ITROT O LU EN E
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3 UNIDENTIFIED COMPOUNDS
3,3'-DICHLOROBENZIDINE
3-NITRO ANILINE
4 UNIDENTIFIED COMPOUNDS
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLORO ANILIN E
4-CHLOROPHENYL PHENYL ETHER
4-NITRO ANILINE
4-NITROPHENOL
5 UNIDENTIFIED COMPOUNDS
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
BIS(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CIFLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
RAGS SD702
Effects 11/19/97
SD703 SD703DUP
11/19/97 11/19/97
Values
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
16:22
70.1
400 U
4000 JN
400 U
400 U
400 U
400 U
400 U
400 U
810 U
400 U
400 U
400 U
400 U
810 U
400 U
400 U
400 U
400 U
NR
16:25
72.6
410 U
NR
410 U
410 U
410 U
410 U
410 U
410 U
820 U
410 U
410 U
410 U
410 U
820 U
410 U
410 U
410 U
410 U
NR
16:25
62.6
280 U
NR
280 U
280 U
280 U
280 U
280 U
280 U
570 U
280 U
280 U
280 U
280 U
570 U
280 U
280 U
280 U
280 U
8000 J
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
10000 J
NR
NR
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
810 U
820 U
570 U
UG/KG
NR
20000 J
NR
UG/KG
6.71
400 U
410 U
280 U
UG/KG
5.87
400 U
410 V
280 U
UG/KG
46.9
28 J
41 J
300
UG/KG
74.8
450
640
480
UG/KG
790
1300
870
UG/KG
560
620
490
UG/KG
380 J
310 J
260 J
UG/KG
88.8
470
590
450
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
400 U
410 U
280 U
UG/KG
182
400 U
410 U
280 U
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
UG/KG
400 UJ
410 UJ
280 UJ
-------
Table 5-16(E) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 NAPHTHALENES
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
RAGS SD702
Effects 11/19/97
Values 16:22
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 UJ
400 U
108
6.22
DODECANOIC ACID, HEXADECYL ESTER (2 ISOMERS UG/KG
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
HEXADECANOIC ACID
HEXADECENOIC ACID
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
113
21.2
34.6
86.7
153
300 J
400 U
400 U
180 J
400 U
110 J
400 U
400 U
2000 JN
NR
790
400 U
400 U
400 U
400 U
400 U
2000 JN
2000 JN
470
400 U
190 U
400 U
400 U
400 U
400 U
810 U
N
67 J
400 U
670
190 U
190 U
SD703
11/19/97
16:25
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 UJ
410 U
500
410 U
410 U
160 J
410 U
120 J
410 U
410 U
2000 JN
NR
1100
410 U
410 U
410 U
410 U
410 U
2000 JN
NR
550
410 U
210 U
410 U
410 U
410 U
410 U
820 U
N
110 J
410 U
890
210 U
210 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD703DUP
11/19/97
16:25
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 UJ
280 U
380
280 U
280 U
110 J
280 U
150 U
280 U
280 U
NR
5000 JN
830
230 J
280 U
280 U
280 U
280 U
2000 JN
NR
440
280 U
150 U
280 U
280 U
280 U
280 U
570 U
N
890
280 U
670
150 U
150 U
-------
Table 5-16(F)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD801 SD801DUP
Effects 11/19/97 11/19/97
V alues
% MOISTURE
(3-AND/OR 4-)METHYLPHENOL
1 UNIDENTIFIED COMPOUND
1.2.4-TRICHLOROBENZENE
2,3,4,6-TETRACHLOROPHENOL
2.4.5-TRICHLOROPHENOL
2.4.6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITRO ANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)FLUORANTHENE
BENZO-A-PYRENE
BENZYL BUTYL PHTHALATE
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL) ETHER
BIS(2-CHLOROISOPROPYL) ETHER
B1S(2-ETHYLHEXYL) PHTHALATE
CI CHRYSENES/BENZANTHRACENES
CI FLUORANTHENES/PYRENES
CI FLUORENES
CI NAPHTHALENES
CI PHENANTHRENES/ANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C2FLUORENES
C2 NAPHTHALENES
%
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
20.23
6.71
5.87
46.9
74.8
88.8
182
14:10
85.6
740 U
NR
740 U
740 U
740 U
740 U
740 U
740 U
1500 U
740 U
740 U
740 U
740 U
1500 U
740 U
740 U
740 U
740 U
740 U
740 U
740 U
740 U
740 U
740 U
740 U
1500 U
740 U
740 U
740 U
92 J
130 J
96 J
77 J
88 J
740 U
740 U
740 U
740 U
740 U
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
14:10
85
790 U
5000 J
790 U
790 U
790 U
790 U
790 U
790 U
1600 U
790 U
790 U
790 U
790 U
1600 U
790 U
790 U
790 U
790 U
790 U
790 U
790 U
790 U
790 U
790 U
790 U
1600 U
790 U
790 U
790 U
67 J
99 J
79 J
67 J
67 J
790 U
790 U
790 U
790 U
790 U
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
SD802
11/19/97
14:45
63.6
800 U
4000 J
800 U
800 U
800 U
800 U
800 U
800 U
1600 U
800 U
800 U
800 U
800 U
1600 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
1600 U
800 U
800 U
800 U
52 J
80 J
60 J
800 U
48 J
800 U
800 U
800 U
800 U
800 U
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
-------
Table 5-16(F) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
C2 PHENANTHRENES/ANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIB UTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
DODECANOIC ACID, HEXADECYL ESTER
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
HEXADECANOIC ACID
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
108
6.22
RAGS SD801
Effects 11/19/97
Values 14:10
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 UJ
740 U
70 J
740 U
740 U
41 J
740 U
290 J
740 U
740 U
4000 JN
ISO J
740 U
740 U
740 U
740 U
740 U
4000 JN
77 J
740 U
420 U
740 U
740 U
740 U
740 U
313
21.2
34.6
86.7
153
1500 U
N
59 J
740 U
130 J
420 U
420 U
SD801DUP
11/19/97
14:10
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 UJ
790 U
51 J
790 U
790 U
790 U
790 U
120 J
790 U
790 U
NR
99 J
790 U
790 U
790 U
790 U
790 U
NR
63 J
790 U
360 U
790 U
790 U
790 U
790 U
1600 U
N
790 U
790 U
87 J
360 U
360 U
SD802
U/19/97
14:45
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 UJ
800 U
40 J
800 U
800 U
800 U
800 U
390 U
800 U
800 U
NR
76 J
800 U
800 U
800 U
800 U
800 U
NR
52 J
800 U
390 U
800 U
800 U
800 U
800 U
1600 U
NR
800 U
800 U
68 J
390 U
390 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20
Note: Reported values exceeding the RAGS EV are m bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-16(G)
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD803
Effects
11/19/97
Values
15:16
% MOISTURE
%
87.5
(3-AND/OR 4-)METHYLPHENOL
UG/KG
890
U
1,2,4-TRICHLOROBENZENE
UG/KG
890
u
2,3,4,6-TETRACHLOROPHENOL
UG/KG
890
u
2,4,5-TRICHLOROPHENOL
UG/KG
890
u
2,4,6-TRICHLOROPHENOL
UG/KG
890
u
2,4-DICHLOROPHENOL
UG/KG
890
u
2,4-DIMETHYLPHENOL
UG/KG
890
u
2,4-DINITROPHENOL
UG/KG
1800
u
2,4-DINITROTOLUENE
UG/KG
890
u
2,6-DINITROTOLUENE
UG/KG
890
u
2-CHLORONAPHTHALENE
UG/KG
890
u
2-CHLOROPHENOL
UG/KG
890
u
2-METHYL-4.6-DINITROPHENOL
UG/KG
1800
u
2-METHYLNAPHTHALENE
UG/KG
20.23
890
u
2-METHYLPHENOL
UG/KG
890
u
2-NITROANILINE
UG/KG
890
u
2-NITROPHENOL
UG/KG
890
u
3,3'-DICHLOROBENZIDINE
UG/KG
890
u
3-NITROANILINE
UG/KG
890
u
4-BROMOPHENYL PHENYL ETHER
UG/KG
890
u
4-CHLORO-3-METHYLPHENOL
UG/KG
890
u
4-CHLORO ANILINE
UG/KG
890
u
4-CHLOROPHENYL PHENYL ETHER
UG/KG
890
u
4-NITROANILINE
UG/KG
890
u
4-NITROPHENOL
UG/KG
1800
u
ACENAPHTHENE
UG/KG
6.71
890
u
ACENAPHTHYLENE
UG/KG
5.87
890
u
ANTHRACENE
UG/KG
46.9
890
u
BENZO(A)ANTHRACENE
UG/KG
74.8
49
J
BENZO(B)FLU ORANTHENE
UG/KG
62
J
BENZO(GHI)PERYLENE
UG/KG
58
J
BENZO(K)FLUORANTHENE
UG/KG
890
u
BENZO-A-PYRENE
UG/KG
88.8
890
u
BENZYL BUTYL PHTHALATE
UG/KG
890
u
BIS(2-CHLOROETHOXY)METHANE
UG/KG
890
u
BIS(2-CHLOROETHYL) ETHER
UG/KG
890
u
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
890
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
890
u
CI CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
CI FLUORANTHENES/PYRENES
UG/KG
890
UJ
CI FLUORENES
UG/KG
890
UJ
CI NAPHTHALENES
UG/KG
890
UJ
CI PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
C2 CHRYSENES/BENZANTHRACENES
UG/KG
890
UJ
C2FLUORENES
UG/KG
890
UJ
C2NAPHTHALENES
UG/KG
890
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/KG
890
UJ
-------
Table 5-16(G) - Continued
Sediment Analytical Results - Extractables
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
C3 CHRYSENES/BENZANTHRACENES
C3 FLUORENES
C3 NAPHTHALENES
C3 PHENANTHRENES/ANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
C4 NAPHTHALENES
C4 PHENANTHRENES/ANTHRACENES
CARBAZOLE
CHRYSENE
DI-N-BUTYLPHTHALATE
DI-N-OCTYLPHTHALATE
DIBENZO(A,H)ANTHRACENE
DIBENZOFURAN
DIBUTYL TIN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
MONOBUTYL TIN
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PETROLEUM PRODUCT
PHENANTHRENE
PHENOL
PYRENE
TETRABUTYL TIN
TRIBUTYL TIN
UG/KG
VG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
RAGS
SD803
Effects
11/19/97
Values
15:16
890 UJ
890 UJ
890 UJ
890 UJ
890 UJ
890 UJ
890 UJ
890 U
108
890 V
890 U
890 U
6.22
890 U
890 U
290 J
890 U
890 U
113
76 J
21.2
890 U
890 U
890 U
890 U
34.6
86.7
153
890 U
49 J
890 U
470 U
890 U
890 U
890 U
890 U
1800 U
N
890 U
890 U
67 J
470 U
470 U
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the
minimum quantitation limit.
-------
Table 5-17
Sediment Analytical Results - Herbicides
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD101
SD102
SD102DUP
SDI 03
SD104
11/16/97
11/13/97
11/13/97
11/13/97
11/16/97
09:40
14:03
14:10
15:00
10:02
2,4,5-T UG/KG
11
UJ
39
U
37
U
34
U
26
U
2,4-D UG/KG
23
UJ
75
U
73
U
68
U
52
U
DICAMBA UG/KG
11
UJ
39
U
37
U
34
U
26
U
SILVEX (2,4,5-TP UG/KG
11
JN
47
U
18
JN
35
JN
8
JN
SD110
SD110A
SDII0B
SD110BDP
SDI 11
11/15/97
11/19/97
11/19/97
11/19/97
11/15/97
08:00
09:20
09:20
09:20
08:25
2,4,5-T UG/KG
14
IJ
13
IJ
12
U
11
U
11
U
2,4-D UG/KG
24
U
26
U
23
U
22
U
21
U
D1CAMBA UG/KG
14
U
13
U
12
U
11
IJ
11
U
SILVEX (2,4,5-TP UG/KG
3.7
JN
8.4
JN
12
U
11
U
11
u
SDII6
SDI17
SDI 18
SDI 19
SDI 20
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
10:00
09:47
11:10
15:45
14:05
2,4,5-T UG/KG
7
U
7
U
9.9
U
10
U
12
u
2,4-D UG/KG
15
U
12
U
40
U
19
U
27
u
DICAMBA UG/KG
7
U
7
U
9.9
U
8.1
U
8
u
SILVEX (2,4,5-TP UG/KG
7
U
10
u
9.9
U
21
U
12
IJ
SD123DUP
SD124
SDI 25
SD126
SD127
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
13:35
14:33
15:25
16:00
16 28
2,4,5-T UG/KG
11
U
1 1
u
15
U
18
U
8
u
2,4-D UG/KG
12
U
18
u
20
U
26
U
15
u
DICAMBA UG/KG
6
U
7.7
u
10
U
12
U
6 5
u
SILVEX (2,4,5-TP UG/KG
II
U
18
u
31
u
33
U
35
u
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD105 SDI06
11/13/97 11/14/97
15:55 16:02
16 U 22 U
28 U 37 U
16 U 22 U
16 U 4.9 JN
SD107 SD108
11/16/97 11/14/97
10:18 16:45
13 UJ 11
26 UJ 21
13 UJ 11
11 JN 11
SD109
11/15/97
08:45
U 14 U
U 27 U
U 14 U
U 8.6 JN
SD112 SD112DUP SDI13 SDU4 SOI 15
11/15/97 11/15/97 11/15/97 11/14/97 11/14/97
09:00 09:20 09:35 12:05 11:30
14 li 15 IJ 4 U 14 IJ 18 U
24 U 26 U 7 U 25 I) 35 U
14 U 15 IJ 4 U 14 IJ 18 IJ
14 U 15 U 4 U 4 JN 5.7 JN
SDI20A
11/19/97
10:00
30 U
60 U
30 U
32 JN
SDI20B
11/19/97
10:00
3 I)
7.6 U
2.6 U
3.7 IJ
SO 121
11/15/97
13:35
11 U
14 II
7 IJ
10 U
SDI22
11/15/97
16:00
11 U
22 U
10 U
30 U
SD123
11/15/97
13:33
9.1 U
19 U
9.1 IJ
29 U
SD128
11/16/97
09:10
22 U
44 U
22 U
21 JN
-------
Table 5-18
Sediment Analytical Results - Herbicides
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD202 SD203 SD204 SD205 SD205
11/14/97 11/13/97 11/13/97 11/14/97 11/15/97
11:30 15:10 16:02 16:20 09:50
2,4,5-T UG/KG 18 U 28 U 29 U 15 U 8.8 U
2,4-D UG/KG 35 U 56 U 57 U 26 U 20 U
DICAMBA UG/KG 18 U 28 U 29 U 15 U 8.8 U
SILVEX (2,4,5-TP UG/KG 15 JN 110 JN 27 JN 15 U 23 U
SD210 SD211 SD211A SD211B SD212
11/15/97 11/15/97 11/19/97 11/19/97 11/15/97
13:20 13:32 14:00 14:05 13:50
2,4,5-T UG/KG 15 U 16 U 13 U 3.1 U 12 U
2,4-D UG/KG 18 U 22 U 20 U 9.3 U 15 U
DICAMBA UG/KG 9.1 U 12 U 6.3 U 3 U 8 U
SILVEX (2,4,5-TP UG/KG 33 U 22 U 10 U 4.8 U 19 U
SD217
11/15/97
15:19
2,4,5-T UG/KG 36
2,4-D UG/KG 70
DICAMBA UG/KG 36
SILVEX (2,4,5-TP UG/KG 87
Data Qualifiers
SD218 SD219
11/15/97 11/15/97
15:55 16:20
UJ 27 U 38
UJ 76 U 76
UJ 27 U 38
JN 22 JN 140
SD220 SD221
11/15/97 11/16/97
16:45 09:45
UJ 20 UJ 28 U
UJ 40 UJ 53 U
UJ 20 UJ 28 U
JN 28 JN 52 JN
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD206 SD206DUP SD207 SD208 SD209
11/14/97 11/14/97 11/14/97 11/15/97 11/15/97
10:05 10:10 12:25 15:15 10:25
29 U 28 U 35 U 11 U 10 U
58 U 57 U 66 U 21 U 17 U
29 u 28 U 35 U 10 U 8.5 U
44 JN 78 JN 36 JN 59 U 66 U
SD213
11/15/97
13:18
26 U
50 U
26 U
33 JN
SD214
11/15/97
13:45
33 U
64 U
33 U
20 JN
SD215
11/15/97
14:15
26 U
49 U
26 U
15 JN
SD215DUP
11/15/97
14:20
22 U
43 U
22 U
23 JN
SD216
11/15/97
14:50
25 U
50 U
25 U
73 JN
SD222
11/16/97
10:25
45 U
89 U
45 U
24 JN
-------
Table 5-19
Sediment Analytical Results - Herbicides
300 Series Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD301
SD302
SD302DUP
SD303
SD304
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
10:50
11:25
11:30
12:00
12:20
2,4,5-T
UG/KG
45
U
44
U
33
U
36
UJ
43
UJ
2,4-D
UG/KG
88
U
88
U
65
U
72
UJ
86
UJ
DICAMBA
UG/KG
45
U
44
U
33
U
36
UJ
43
UJ
SILVEX (2,4,5-TP)
UG/KG
56
JN
74
JN
45
JN
75
JN
130
JN
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-20
Sediment Analytical Results - Herbicides
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD401
SD402
SD403
SD403DUP
SD404
SD405
SD406
SD407
SD408
SD409
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/18/97
11/18/97
11/18/97
12:55
13:15
13:44
13:50
15:00
15:20
15:35
09:00
09:23
09:55
2,4,5-T UG/KG
4.3
JN
6.4
U
7.3
U
9.8
U
14
U
10
U
12
U
13
U
20
U
8.3
U
2,4-D UG/KG
18
U
37
U
19
U
18
U
24
U
24
U
21
U
20
U
37
U
19
U
DICAMBA UG/KG
6.9
U
6.4
U
7.3
U
6.7
U
12
U
16
U
9.5
U
10
U
14
U
6.5
U
SILVEX (2,4,5-TP UG/KG
33
U
10
U
18
u
13
u
23
U
14
U
18
U
19
U
25
U
10
U
SD410
SD411
SD412
SD413
SD414
SD415
SD416
SD417
SD417DUP
SD418
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
10:20
10:50
11:15
11:45
13:01
13:01
13:20
13:45
13:50
14:03
2,4,5-T UG/KG
13
U
6.7
U
11
u
11
u
6.4
u
12
U
9
u
7.2
JN
10
U
oo
JN
2,4-D UG/KG
43
u
23
U
31
u
22
u
24
u
18
U
20
u
17
UJ
19
U
10
U
DICAMBA UG/KG
8.9
u
5.3
U
8.4
u
11
u
6.4
u
5
U
9
u
8.4
UJ
8.1
U
5.2
U
SILVEX (2,4,5-TP UG/KG
31
u
8.2
U
18
u
23
u
18
u
13
U
24
u
32
UJ
24
U
20
U
SD419
SD420
SD421
SD422
SD423
SD424
SD425
SD503A
SD503B
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
14:27
14:47
15:20
15:47
16:15
09:17
09:25
11:15
11:15
2,4,5-T UG/KG
27
u
16
U
25
u
19
u
24
u
5.4
U
7.2
u
3.7
u
1.4
U
2,4-D UG/KG
53
u
31
U
50
u
38
u
48
u
12
U
12
u
5
u
2.9
U
DICAMBA UG/KG
27
u
16
U
25
u
19
u
24
u
4
u
5.1
u
3.8
u
1.4
U
SILVEX (2,4,5-TP UG/KG
32
JN
5.2
JN
61
JN
9.9
JN
44
JN
9.3
u
17
u
17
u
1.4
U
J9ata Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-21
Sediment Analytical Results - Herbicides
600/700/800 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD60I
SD602
SD603
SD604
SD605
SD605DUP
SD606
SD607
SD608
SD609
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
08:45
09:08
09:31
09:55
10:20
10:25
11:48
13:02
13:26
14:34
2,4,5-T UG/KG
11
U
14
U
13
U
16
u
17
U
19
U
20
U
18
U
18
U
21
U
2,4-D UG/KG
22
U
27
U
26
U
31
u
33
U
36
U
38
U
37
U
36
U
39
U
DICAMBA UG/KG
11
U
14
U
13
u
16
U
17
U
19
U
20
U
18
U
18
U
21
U
SILVEX (2,4,5-TP UG/KG
12
U
8.8
JN
4.4
JN
13
JN
12
JN
17
JN
13
JN
15
JN
15
JN
12
JN
SD610
SD701
SD702
SD703
SD703DUP
SD801
SD801DUP
SD802
SD803
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
15:00
16:20
16:22
16:25
16:25
14:10
14:10
14:45
15:16
2,4,5-T UG/KG
22
U
8
U
4.3
U
4.5
u
3.6
U
9.3
U
7,7
V
8
U
9.4
U
2,4-D UG/KG
42
U
10
U
8.5
u
7.1
U
8.1
U
14
U
22
U
14
U
15
U
DICAMBA UG/KG
22
U
5.2
U
3.3
u
4
U
3
U
7.2
u
7.1
JN
6.8
U
11
u
SILVEX (2,4,5-TP UG/KG
15
JN
31
U
26
u
12
U
23
U
16
U
33
U
26
U
35
u
Data Qualifiers
J-Estimated value.
N-Prcsumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-22 (A)
Sediment Analytical Results - Pesticides and PCBs
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD101
SD102
SD102DUP
SD103
SD104
SD105
SD106
SD107
Effects
11/16/97
11/13/97
11/13/97
11/13/97
11/16/97
11/13/97
11/14/97
11/16/97
Values
09:40
14:03
14:10
15:00
10:02
15:55
16:02
10.18
% MOISTURE
%
45
84
84
82
76
55
69
48
1-HYDROXYCHLORDENE 12
UG/KG
4,4-DDD (P.P'-DDD)
UG'KG
1.22
3
U
10
U
13
U
11
U
7
U
5.7
U
6.7
U
3.1
u
4,4'DDE (P.P'-DDE)
UG/KG
2.07
0.85
5.2
12
8.8
26
15
26
18
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
3
u
10
U
13
u
11
U
7
U
5.7
u
6.7
u
3.1
U
ALDRIN
UG/KG
2
u
4.7
U
5.7
u
4.8
U
5
u
1.6
u
2.1
u
2
U
ALPHA-BHC
UG/KG
1.5
u
4.7
u
5.7
u
4.8
U
3.6
13
1.6
u
2.1
u
1.3
u
ALPIIA-CHLORDANE i2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
BETA-BHC
UG/KG
3
u
4.7
u
5.7
u
4.8
U
15
U
1.6
u
2.1
u
4.1
u
BETA-CHLORDENE 12
UG/KG
CHLORDANE(TECII. MIXTURE) /I
UG/KG
8
u
32
u
40
u
23
U
20
IJ
13
u
23
u
8
u
CHLORDENE SI
UG/KG
0.48
N
0.79
J
2.5
J
I.I
J
7.4
2.4
7.4
3.8
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
1.6
IJ
9
u
17
u
10
U
5
U
1.6
u
9.7
u
2.7
u
DIELDRIN
UG/KG
0.02
1,6
U
6.2
u
6.8
u
4.8
u
3.6
U
1.6
V
2.1
V
1.3
u
ENDOSULFAN 1 (ALPHA)
UG/KG
1.6
u
4.7
u
5.7
u
4.8
u
3.6
u
1.6
u
2.1
u
1.3
u
ENDOSULFAN II (BETA)
UG/KG
3
U
10
u
13
u
11
u
7
u
5.7
u
6.7
u
3.1
u
ENDOSULFAN SULFATE
UG/KG
3
u
10
u
13
u
11
IJ
7.2
u
5.7
u
6.7
u
3.1
u
ENDRIN
UG/KG
0.02
5
u
JO
u
13
u
11
u
7
u
5.7
u
6.7
u
3 /
u
ENDRIN KETONE
UG/KG
3
u
10
u
1 1
u
11
u
1
u
5.7
u
6.7
u
3.1
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
1.5
u
4.7
u
5.7
u
4.8
u
3.6
u
1.6
u
2.1
u
1.3
u
GAMMA-CHLORDANE SI
UG/KG
GAMMA-CHLORDENE /2
UG/KG
HEPTACHLOR
UG/KG
1.5
u
4.7
u
5.7
IJ
4.8
u
3.6
u
1.6
u
2.1
u
1.3
u
HEPTACHLOR EPOXIDE
UG/KG
1.5
u
4.7
u
5.7
u
4.8
u
3.6
u
1.6
u
2.1
u
1.3
u
METIIOXYCHLOR
UG/KG
8
u
20
u
22
u
\9
u
22
u
6.9
u
9.8
u
8.6
u
OXYCHLORDANE (OCTACHLORF.POXIDE) 11 UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
18
u
54
u
56
u
49
u
50
u
20
u
28
u
18
u
'CB-I22I (AROCLOR 1221)
UG/KG
18
u
54
u
56
u
49
u
50
IJ
20
u
28
V
18
u
'<:B-l232(AROCLOR 1232)
UG/KG
18
u
54
u
56
u
49
V)
50
IJ
20
u
28
u
18
u
PCB-1242 (AROCLOR 1242)
UG/KG
18
u
54
u
56
u
49
u
50
u
20
u
28
u
18
u
PCB-1248 (AROCLOR 1248)
UG/KG
18
u
54
u
56
u
49
u
50
u
20
u
28
u
18
u
PCB-I2S4 (AROCLOR 1254)
UG/KG
21.6
20
J
70
J
87
56
J
130
31
57
31
PCB-1260 (AROCLOR 1260)
UG/KG
18
u
54
u
56
u
49
u
50
u
20
u
28
u
18
u
TOXAPHENE
UG/KG
120
u
370
u
410
u
370
u
270
V
140
u
190
u
130
V
TRANS-NONACHLOR /2 UG'KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
tyite: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
I- ;te: Samples SD-101, 102, 102DUP, 103, 104, 105, 106, and 107 had a mix ofaorclors. Closest matches reported.
Data Qualifiers
J-Eslimatcd value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
I .When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 5-22 (B)
Sediment Analytical Results - Pesticides and PCBs
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SDl 08
SDI09
SDl 10
SDl 10A
SDII0B
Effects
11/14/97
11/15/97
11/15/97
11/19/97
11/19/97
Values
16:45
08:45
08:00
09:20
09:20
% MOISTURE
%
46
58
58
56
49
1 -HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P,P'-DDD)
UG/KG
1.22
3.8
1.4 JN
2.1 JN
3.3
2.4 J
4,4-DDE (P.P'-DDE)
UG/KG
2.07
3
8.5
19
22
6.1
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
22
4.2 U
4 U
3.7
6.9 U
ALDRrN
UG/KG
1.5 U
1.8 U
1.9 U
5.3 U
4.6 U
alpha-bhc
UG/KG
1.5 U
1.8 U
1.9 U
5.3 U
4.6 U
ALPHA-CHLORDANE Z2
UG/KG
ALPHA-CHLORDENE 12
UG/KG
BBTA-BHC
UG/KG
1.5 U
1.8 U
1.9 U
5.3 U
4.6 U
BETA-CHLORDENE 11
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
10 U
10 u
12 U
21 U
18 U
CHLORDENE /2
UG/KG
1
1.2
1.8
2 J
1.3
CIS-NONACHLOR 11
UG/KG
DELTA-BHC
UG/KG
5.5 U
4.2 U
7.5 U
16 U
9.4 U
DIELDR1N
UG/KG
0.02
IJ V
1.8 U
4 U
5 3 U
4.6 V
ENDOSULFAN I (ALPHA)
UG/KG
1.5 U
(.8 U
1.9 U
5.3 1/
4.6 1/
ENDOSULFAN II (BETA)
UG/KG
3 U
4.2 U
4 U
11 i;
6.9 U
ENDOSULFAN SULFATE
UG/KG
20 U
4.2 U
4 U
11 U
6.9 IJ
ENDRIN
UG/KG
0.02
3 U
4 2 U
4 U
11 V
6 9 U
ENDRIN KETONE
UG/KG
3.3 U
4.4 U
4.1 U
13 U
6 U
GAMMA-BHC (LINDANE)
UG/KG
0.32
1.5 U
1.8 U
1.9 U
5.3 U
4.6 U
GAMMA-CHLORDANE 12
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
1.5 U
1.8 U
1.9 U
5.3 U
4.6 U
HEPTACHLOR EPOXIDE
UG/KG
1.5 U
1.8 U
1.9 U
5.3 V
4.6 U
METHOXYCHLOR
UG/KG
7 U
8.1 U
7.6 U
18 U
14 U
O.P-DDE
UG/KG
NR
NR
NR
22 N
11 N
OXYCHLORDANE(OCTACIILOREPOXIDE) 12 UG/KG
PCB-1016 (A ROCLOR 1016)
UG/KG
15 U
24 U
27 U
38 U
23 U
PCB-1221 (AROCLOR 1221)
UG/KG
15 U
24 U
27 U
38 U
28 U
PCB-1232 (AROCLOR 1232)
UG/KG
15 U
24 U
27 U
38 U
28 U
PCB-1242 (AROCLOR 1242)
UG/KG
15 U
24 U
27 U
38 U
28 U
PCB-1248 (AROCLOR 1248)
UG/KG
15 U
24 U
27 U
38 U
28 U
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
15 U
24 U
27 LT
47 U
31 U
PCB-1260 (AROCLOR 1260)
UG/KG
15 U
24 U
27 U
47 U
31 U
TOXAPHENE
UG/KG
120 V
160 U
150 U
280 U
220 U
TRANS-NONACHLOR /2
UG/KG
Note: Reported values exceeding the RAGS HV are in bold. Values with EDL exceeding RAGS EV are ilalicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Data Qualifiers
J-Estimated value.
N-Pfcsumptive evidence of presence of material.
NR-Not Requested
U-Matcrial was analyzed for but not defected. 77ie number is the minimum quantitation limit.
I .When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
SDl I0BDP
11/19/97
09:20
49
2 J
8.7
7.5 U
5.8 U
5.8 U
5.8 U
21 U
1.2 J
12 U
38 U
5.8 V
7.5 U
7.5 U
7.5 ('
7.2 U
5.8 U
5.8 U
5.8 U
15 U
12 N
30 U
30 U
30 U
30 U
30 U
34 U
34 ti
240 U
SDMI
11/15/97
08:25
47
1.3 J
5.1
3.4 U
1.4 U
1.4 U
1.4 U
9.7 U
1.1
5.5 U
1.9 U
1.4 V
3.4 U
3.4 U
3.4 U
3 U
1.4 U
1.4 U
1.4 U
5.9 U
NR
18 1.1
18 U
18 V
18 U
18 V
18 Lf
18 LI
120 U
SDl 12
11/15/97
09:00
52
2.1 J
IS
2.7 J
2 U
2 U
2 U
8,9 U
1.8
8.9 U
3.8 U
2 V
3.5 U
3.5 U
3.5 V
3.7 LJ
2 U
2 U
2 u
7.1 U
NR
28 U
28 U
28 U
28 U
28 U
28 U
28 U
140 V
-------
Table 5-22 (C)
Sediment Analytical Results - Pesticides and PCBs
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SDU2DUP
SOI 13
SD1I4
SD1I5
SD116
Effects
11/15/97
11/15/97
11/14/97
11/14/97
11/15/97
Values
09:20
09-.35
12:05
11:30
10:00
% MOISTURE
%
53
43
54
64
n
l-HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
1.7 J
5.4
U
2.5
N
2.1
JN
13
U
4,4'-DDE (P,P"-DDE)
UG/KG
2.07
12
4.2
12
14
4.8
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
2.1 J
5.4
u
3.5
U
5.8
U
13
u
ALDRrN
UG/KG
1.5 U
3.1
u
1.5
u
2.5
u
6.4
u
ALPHA-BHC
UG/KG
1.5 U
3.1
u
1.5
U
2.5
u
6.4
u
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
BETA-BHC
UG/KG
1.5 U
4.8
u
1.5
u
2.5
u
6.4
U
BETA-CHLORDENE 12
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
D
00
00
16
u
7.8
u
12
u
31
u
CHLORDENE /2
UG/KG
1.5
1.3
1.7
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
3.8 U
3.1
u
4.7
u
4.7
u
6.4
u
DIELDRIN
UG/KG
0.02
2 9 V
3.1
V
1.5
u
2.5
u
6.4
V
ENDOSULFAN 1 (ALPHA)
UG/KG
1.5 U
3.1
u
1.5
u
2.5
u
6.4
u
ENDOSULFAN II (BETA)
UG/KG
4.3 U
5.4
u
3.5
u
5.8
u
13
u
ENDOSULFAN SULFATE
UG/KG
4.3 U
5.4
u
3.5
u
5.8
u
11
u
ENDRIN
UG/KG
0.02
4.3 U
5.4
V
3.5
u
5.8
V
13
u
ENDRIN KETONE
UG/KG
3.6 U
S.4
u
3.3
u
5.8
u
13
V
GAMMA-BHC (LINDANE)
UG/KG
0.32
1.5 U
3.1
u
1.5
u
2.5
u
6.4
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CIILORDENE /2
UG/KG
HEPTACHLOR
UG/KG
1.5 U
3.1
u
1.5
u
2.5
u
6.4
u
HEPTACHLOR EPOXIDE
UG/KG
1.5 U
3.1
u
1.5
u
2.5
u
6.4
u
METIIOXYCHLOR
UG/KG
7 U
11
u
6.3
u
10
u
23
u
OXYCHLORDANE (OCTACHLOREPOXIDE) 12 UG/KG
°CB-I016 (AROCLOR 1016)
UG/KG
22 U
28
u
17
u
25
u
58
u
iiCB-122l (AROCLOR 1221)
UG/KG
22 U
28
u
17
u
25
u
58
u
B-l 232 (AROCLOR 1232)
UG/KG
22 U
28
u
17
u
25
u
58
V
FCB-1242 (AROCLOR 1242)
UG/KG
22 U
28
u
17
u
25
u
58
u
PCB-1248 (AROCLOR 1248)
UG/KG
22 U
28
u
17
u
25
u
58
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
22 U
28
u
17
u
25
u
58
u
PCB-1260 (AROCLOR 1260)
UG/KG
22 U
28
u
17
u
25
u
65
u
TOXAPHENE
UG/KG
140 U
250
u
120
u
180
u
480
u
TRANS-NONACHLOR 12 UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized,
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
N^le: Samples SD-117, 118, and 119 had a mix of aorclors. Closest matches reported.
Data Qualifiers
N-Presumptive evidence of presence of material.
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
I .When no value is reported, see chlordane constituents.
2.Constilucnts or metabolites of technical chlordanc.
SD! 17
11/15/97
09:47
SD118
11/15/97
11:10
SDI19
11/15/97
15:45
66 81
17 U 19
150 100
17 U 19
6.9 U 10
6.9 U 10
78
U 14 U
99
U 14 U
U 9.8 U
U 9.8 U
6.9 U
47 U
15
32 U
27 U
6.9 U
17 U
20 U
17 U
17 U
6.9 V
10 U
120 U
17
28 U
10 V
10 U
19 U
37 U
19 V
21 U
10 U
II U
60 U
39
34 U
9.8 U
9.8 U
14 U
21 U
14 U
18 U
9.8 V
6.9 U
6.9 U
19 U
74 U
74 U
74 U
74 U
74 U
110
74 U
SIO U
10 U
10 U
39 U
130 U
130 U
130 U
130 IJ
130 U
260
130 U
1000 U
9.8 U
9.8 U
36 U
83 U
83 U
83 U
83 U
83 U
91
83 U
720 U
-------
Table 5-22 (D)
Sediment Analytical Results - Pesticides and PCBs
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD120
SD120A
SD120B
SDI2I
SDI22
SDI23
SDI23DUP
SDI24
Effects
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
Values
14:05
10:00
10:00
13:35
16:00
13:33
13:35
14:33
% MOISTURE
%
75
80
63
71
82
79
66
74
t-HYDROXYCHLORDENE 12
UG/KG
4,4' DDD (P,P-DDD)
UG/KG
1.22
16
U
4.3
JN
20
U
8.6
U
14
u
9.1
u
8.7
U
12
N
4,4'-DDE (P.P'-DDE)
UG/KG
2.07
200
22
J
65
10
15
20
44
60
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
16
U
10
UJ
20
U
6
U
14
u
5.7
JN
5.2
N
11
N
ALDRIN
UG/KG
6.6
U
4.1
UJ
II
U
3.7
U
6.7
u
6.2
U
3.7
U
12
U
ALPHA-BHC
UG/KG
6.6
u
4.1
UJ
8
U
3.7
U
6.7
u
6.2
u
3.7
U
12
U
ALPIIA-CHLORDANE il
UG/KG
ALPHA-CIILORDENE 12
UG/KG
BETA-BHC
UG/KG
6.6
u
4.1
UJ
11
u
3,7
U
6.7
u
6.2
u
3.7
u
12
u
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
76
u
31
UJ
45
u
22
U
38
u
28
u
20
IJ
42
u
CHLORDENE il
UG/KG
85
2.5
J
15
2
5.8
3.9
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
41
u
4.1
UJ
11
U
3.7
U
6.7
u
6.2
u
3.7
u
12
IJ
DIELDRrN
UG/KG
0.02
6.6
u
4.1
UJ
11
u
5.7
U
6.7
u
6.2
u
9.2
u
19
u
ENDOSULFAN I (ALPHA)
UG/KG
6.6
u
4.1
UJ
II
u
3.7
U
6.7
u
6.2
u
3.7
u
12
11
ENDOSULFAN II (BETA)
UG/KG
16
u
10
UJ
20
u
6
u
14
u
9.1
u
8.7
u
23
u
ENDOSULFAN SULFATE
UG/KG
42
IJ
12
UJ
20
u
8.7
u
14
u
9.1
u
8.7
U
24
IJ
ENDRIN
UG/KG
0.02
16
u
10
UJ
20
u
6
u
14
('
9/
u
8.7
V
23
('
ENDRIN KETONE
UG/KG
17
u
8.5
UJ
20
u
6
u
10
u
9.1
u
8.7
u
23
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
6,6
V
4.1
UJ
8
u
3.7
u
6.7
u
6.2
u
3.7
u
12
('
GAM MA-CHI.OR DANE /2
UG/KG
GAMMA-CHLORDENE a
UG/KG
HEPTACHLOR
UG/KG
6.6
u
4.1
UJ
8
u
3.7
u
6.7
u
6.2
u
3.7
L!
12
u
HF.PTACHLOR EPOXIDE
UG/KG
6.6
u
4.1
UJ
8
U
3.7
II
6.7
u
6.2
u
3.7
II
12
u
METHOXYCHl.OR
IJG/KG
30
U
19
UJ
40
u
11
u
21
u
13
u
9
U
24
u
O.P-DDF
UG/KG
NR
3.2
JN
NR
NR
NR
NR
NR
Nh
OXYCHLORDANE(OCTACHLOREPOXIDE) /2 UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
98
u
41
UJ
J00
U
32
U
59
u
39
U
36
U
74
V
PCB-1221 (AROCLOR 1221)
UG/KG
98
u
41
UJ
100
u
32
U
59
u
39
U
36
U
74
u
PCB-1232 (AROCLOR 1232)
UG/KG
98
u
41
UJ
100
(J
32
U
59
u
39
U
36
U
74
IJ
PCB0242 (AROCLOR 1242)
UG/KG
98
u
41
UJ
100
u
32
u
59
u
39
U
36
U
78
u
PCB-1248 (AROCLOR 1248)
UG/KG
98
u
41
UJ
100
u
32
u
59
u
39
U
36
U
74
u
PCB-I254 (AROCLOR 1254)
UG/KG
21.6
170
46
J
160
28
J
50
J
36
J
55
70
PCB-1260 (AROCLOR 1260)
UG/KG
98
u
45
UJ
100
u
32
u
59
V
39
U
50
U
74
u
TOXAPffENE
UG/KG
740
u
4 40
UJ
710
u
440
u
770
u
640
u
200
1/
640
V
TRANS-NONACHLOR 12 UG/KG
Note: Reported values exceeding the RAGS ['V are in bold. Values wilh EDL exceeding RAGS I: V are italicized.
Note; The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-120, 121, ! 22, 123, I23DUP, 1 24, 120A, and 120B had a mix ofaorclors. Closest matches reported.
Note: Sample SD-120A exceeded recommended holding time.
Data Qualifiers
N-Prcsumptive evidence of presence of material.
NR-Not Requested
J-Estimated value.
U-Material was analyzed for but not delected. The number is (he minimum quantitation limit.
\ When no value is reported, see chlordane cpnstiluenls
ICotisltlmlsofmetMcfofiickkilcMofilttie.
-------
Table 5-22 (E)
Sediment Analytical Results - Pesticides and PCBs
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SDI25
SD126
SDI27
SD128
Effects
11/15/97
I l/l 5/97
11/15/97
11/16/97
Values
15:25
16:00
16:28
09:10
% MOISTURE
%
81
83
70
74
1 -HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P,P'-DDD)
UG/KG
1.22
8.9
U
22
u
14
U
6
u
4,4'-DDE (P.P'-DDE)
UG/KG
2.07
36
140
38
16
4,4' DDT (P,P'-DDT)
UG/KG
1.19
8.9
U
22
U
14
U
6
I!
ALDRIN
UG/KG
7.6
u
16
U
7.9
U
4
U
ALPHA-BHC
UG/KG
7.6
u
16
u
7.9
U
2.2
u
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE 12
UG/KG
BETA-BIIC
UG/KG
7.6
u
16
u
7.9
U
6
u
BETA-CHLORDENF. /2
UG/KG
CHLORDANE(TECH. MIXTURE.) /I
UG/KG
37
u
150
u
37
u
15
u
CHLORDENE /2
UG/KG
4.5
21
4
2.4
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
7.6
u
36
u
7.9
U
4.9
u
DIELDRfN
UG/KG
0.02
7.6
u
16
V
7.9
u
4.9
u
ENDOSULFAN I (ALPHA)
UG/KG
7.6
u
16
u
7.9
U
4.9
u
ENDOSULFAN II (BETA)
UG/KG
8.9
IJ
22
u
14
u
6
u
ENDOSULFAN SULFATE
UG/KG
13
IJ
40
u
15
u
6
u
ENDRIN
UG/KG
0.02
8 9
u
22
V
14
u
6
u
ENDR1N KETONE
UG/KG
10
u
22
u
12
I)
6
u
GAMMA-BIIC (LINDANE)
UG/KG
0.32
7.6
u
16
u
7.9
u
2.2
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE 12
tJG/KG
I1EPTACHLOR
UG/KG
7.6
u
16
u
7.9
u
2.2
u
MEPTACHLOR EPOXIDE
UG/KG
7.6
u
16
IJ
7.9
u
2.2
IJ
METHOXYCHLOR
UG/KG
17
u
39
u
35
u
22
u
OXYCHLORDANE(OCTACIILOREPOX1DE) /2 UG/KG
PCB-I
-------
Table 5-23 (A)
Sediment Analytical Results - Pesticides and PCBs
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
__
RAGS
SD202
SD203
SD204
SD205
SD205
SD206
SD206DUP
SD207
Effects
11/14/97
11/13/97
11/13/97
11/14/97
11/15/97
11/14/97
11/14/97
11/14/97
Values
11:30
15:10
16:02
16:20
09:50
10:05
10:10
12:25
% MOISTURE
%
69
79
79
55
78
80
79
81
1 -HYDROXYCHLORDENE /2
UG/KG
4,4'-DDD (P,P'-DDD)
UG/KG
1.22
6.3 U
2.2
JN
2.2
JN
5
u
14
U
10
U
9.6
U
11
U
4,4'-DDE (P.P'-DDE)
UG/KG
2.07
10
29
36
25
74
30
29
44
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
6.3 U
8.7
U
2.1
JN
5
U
14
U
10
u
9.6
u
1 1
U
ALDRIN
UG/KG
3.1 U
6.8
u
4.2
U
2.6
u
8.5
u
5.3
u
5.3
U
5.8
u
ALPHA-BHC
UG/KG
3.1 U
6.8
u
4.2
U
2.6
u
8.5
u
5.3
u
5.3
U
5.8
u
ALPHA-CfJLORDANE /2
UG/KG
ALPHA-CHLORDENE 11
UG/KG
BETA-BHC
UG/KG
3.1 U
6.8
u
4.2
u
2.6
u
25
u
5.3
u
5.3
U
5.8
u
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
19 U
34
u
43
u
27
u
62
u
21
u
34
U
47
u
CHLORDENE /2
UG/KG
0.7 J
2.4
5.5
2.4
13
2.6
2.4
3.6
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
6.3 U
14
u
15
u
4.8
u
17
u
5.3
IJ
8.2
u
10
u
D1ELDRIN
UG/KG
0.02
3.1 U
6.8
V
7.2
u
4.8
u
12
u
5.3
u
5.3
V
5.8
u
ENDOSULFAN I (ALPHA)
UG/KG
3.1 U
6.8
u
4.2
u
2.6
u
8.5
u
5.3
V
5.3
u
5.8
u
ENDOSULFAN II (BETA)
UG/KG
6.3 U
9.2
u
9.9
u
5
u
14
u
10
u
9.6
u
11
u
ENDOSULFAN SULFATE
UG/KG
6.7 U
9.2
u
9.9
u
5
u
30
u
10
u
9.6
u
11
u
ENDRIN
UG/KG
0.02
6 3 V
9.2
V
9.9
u
5
u
14
u
10
11
9.6
V
11
u
ENDRIN KETONE
UG/KG
6 U
9.2
u
9.9
u
7.1
u
22
u
8.9
u
8.5
u
11
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
3.1 U
6.8
a
4.2
u
2.6
u
12
u
5.3
u
5.3
u
5.8
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE tl
UG/KG
HEPTACHLOR
UG/KG
3.1 U
6.8
u
4.2
u
2.6
u
8.5
u
5.3
u
5.3
u
5.8
u
HEPTACHLOR EPOXIDE
UG/KG
3.1 U
6.8
u
4.2
u
2.6
u
8.5
u
5.3
u
5.3
u
5.8
u
METHOXYCIILOR
UG/KG
12 U
17
V
14
u
8.6
u
87
u
18
u
17
U
19
u
OXYCHLORDANE (OCTACHLOREPOXfDE) C UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
u
54
u
PCB-1221 (AROCLOR 1221)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
u
54
u
PCB-1232 (AROCLOR 1232)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
U
54
u
PCB-1242 (AROCLOR 1242)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
u
54
u
PCB-1248 (AROCLOR 1248)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
u
54
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
29 U
67
74
41
99
66
66
81
PCB-1260 (AROCLOR 1260)
UG/KG
29 U
52
u
43
u
24
u
94
u
50
u
48
u
54
LI
TOXAPHENE
UG/KG
210 U
310
u
280
u
150
u
650
u
320
u
320
u
410
u
TRANS-NONACHLOR a UG/KG
No(e: Reported values exceeding Che RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-205, 206, 206DUP, 207, 203, and 204 had a mix of aorclors. Closest matches reported.
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constitucnts or metabolites of technical chlordane.
-------
Table 5-23 (B)
Sediment Analytical Results - Pesticides and PCBs
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD208
SD209
SD210
SD211
SD211A
SD21IB
SD212
SD213
Effects
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
Values
15:15
10:25
13:20
13:32
14:00
14:05
13:50
13:18
% MOISTURE
%
80
78
80
82
79
67
72
74
l-HYDROXYCHLORDENE !2
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
21 U
19
U
17 U
32
U
36 V
19
U
18
U
15
U
4,4'-DDE (P,P'-DDE)
UG/KG
2.07
290
59
110
290
270
330
2S0
100
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
21 U
19
U
17 U
32
V
36 U
3.1
J
87
N
15
U
ALDR1N
UG/KG
8.9 U
12
U
13 U
25
U
40 U
24
U
13
u
10
U
ALPHA-BHC
UG/KG
8.9 U
12
U
13 U
25
u
14 U
8
u
13
u
6
U
ALPHA-CHLORDANE 12
UG/KG
ALPHA-CHLORDENE 12
UG/KG
7.3
BETA-BHC
UG/KG
8.9 U
15
U
13 U
25
u
31 U
17
u
13
u
14
U
BETA-CHLORDENE 12
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
38 U
61
u
70 U
77
u
85 U
47
u
44
u
35
U
CHLORDENE /2
UG/KG
49
5
J
11
61
92
92
16
U
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
33 U
12
U
13 U
66
u
29 U
26
u
24
u
10
u
DIELDRIN
UG/KG
0.02
8.9 U
12
V
13 V
25
u
14 U
8,9
u
33
u
6
u
ENDOSULFAN I (ALPHA)
UG/KG
8.9 U
12
u
13 U
25
u
14 U
20
u
13
u
6
U
ENDOSULFAN II (BETA)
UG/KG
21 U
19
u
17 U
32
u
36 U
19
u
18
u
15
u
ENDOSULFAN SULFATE
UG/KG
65 U
21
u
24 U
140
u
36 U
22
u
100
u
15
u
ENDRIN
UG/KG
0.02
21 U
19
u
17 U
32
u
36 U
19
u
18
u
15
u
ENDR1N KETONE
UG/KG
21 U
21
u
17 U
25
u
36 U
19
u
14
u
25
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
33 U
12
u
13 V
25
V
14 U
8
u
13
u
6
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
8.9 U
12
u
13 U
25
u
14 U
8
u
13
u
6
u
HEPTACHLOR EPOXIDE
UG/KG
8.9 U
12
u
13 U
25
u
14 U
25
13
u
6
u
METHOyYCHLOR
UG/KG
30 U
34
u
33 U
36
u
86 U
47
u
23
u
35
u
OXYCH1 '.»RDANE (OCTACHLOREPOXIDE) t\ UG/KG
PCB-lOlt. AROCLOR 1016)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
PCB-1221 (aROCLOR 1221)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
PCB-1232 (AROCLOR 1232)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
PCB-1242 (AROCLOR 1242)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
PCB-1248 (AROCLOR 1248)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
460
67
ISO
730
780
420
190
310
PCB-1260 (AROCLOR 1260)
UG/KG
220 U
94
u
120 U
270
u
400 U
150
u
96
u
150
u
TOXAPHENE
UG/KG
970 U
660
u
740 U
920
u
1400 U
890
u
730
u
520
u
TRANS-NONACHLOR 12
UG/KG
Nole: r ^rtcd values exceeding the RAGS EV are in bold. Values witli EDL exceeding RAGS EV are italicized.
Nc>e: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-208,209, 210, 211,212,213,21 i A, and 21 IB had a mix of aorclors. Closest matches reported.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constitucnts or metabolites of technical clilordanc.
-------
Table 5-23 (C)
Sediment Analytical Results - Pesticides and PCBs
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD214
SD215
SD215DUP
SD216
Effects
11/15/97
11/15/97
11/15/97
11/15/97
Values
13:45
14:15
14:20
14:50
% MOISTURE
%
79
75
72
76
1 -HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P,P'-DDD)
UG/KG
K22
15
U
15
U
15
U
15
u
4,4'-DDE (P,P'-DDE)
UG/KG
2.07
110
180
150
96
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
15
U
15
U
15
U
15
U
ALDR1N
UG/KG
10
U
7
U
7
U
9
U
ALPHA-BHC
UG/KG
6
U
5
U
5
U
6
U
ALPHA-CHLORDANE 12
UG/KG
ALPHA-CHLORDENE 12
UG/KG
3
J
2.5
J
BETA-BHC
UG/KG
14
U
23
U
18
U
13
U
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) II
UG/KG
40
U
30
U
30
U
35
U
CHLORDENE 12
UG/KG
11
30
22
9.5
N
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
14
u
10
u
9 2
u
13
U
DIELDRIN
UG/KG
0.02
6
u
5
u
5
u
6
V
ENDOSULFAN I (ALPHA)
UG/KG
6
u
5
u
5
u
6
u
ENDOSULFAN II (BETA)
UG/KG
15
u
32
u
30
u
15
u
ENDOSULFAN SULFATE
UG/KG
15
u
15
u
15
u
15
u
ENDR1N
UG/KG
0.02
15
u
IS
u
15
u
15
u
ENDRIN KETONE
UG/KG
15
u
15
u
15
u
15
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
6
u
5
u
5
u
6
u
GAMMA-CHLORDANE 12
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
6
u
5
u
5
u
6
u
HEPTACHLOR EPOXIDE
UG/KG
6
u
5
u
5
u
6
u
METHOXYCHLOR
UG/KG
40
u
30
u
30
u
35
u
OXYCHLORDANE (OCTACHLOREPOXIDE) /: UG'KG
PCB-1016 (AROCLOR 1016)
UG/KG
150
u
120
u
100
u
90
u
PCB-I22I (AROCLOR 1221)
UG/KG
150
u
120
u
100
u
90
u
PCB-1232 (AROCLOR 1232)
UG/KG
150
u
120
u
100
u
90
u
PCB-1242 (AROCLOR 1242)
UG/KG
150
u
120
u
100
u
90
u
PCB-1248 (AROCLOR 1248)
UG/KG
150
u
120
u
100
u
90
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
290
360
290
200
PCB-1260 (AROCLOR 1260)
UG/KG
150
u
120
IJ
100
u
90
u
TOXAPHENE
UG/KG
570
u
460
u
500
u
540
u
TRANS-NONACHLOR /2 UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-214, 215, 215DUP, 216, 217, 218, 219, and 220 had a mix of aorciors. Closest matches reported.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Malerial was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constituentf or metabolites of technical chlordane.
SD217
11/15/97
15:19
83
20 U
210
20 U
II U
8 U
9 J
30 U
50 U
60
14 U
8 V
8 U
20 V
20 U
20 V
23 U
8 V
8 U
8 U
50 U
180 U
180 U
180 U
180 U
180 U
460
180 U
770 U
SD218
11/15/97
15:55
77
20 U
130
20 U
8 U
6 U
4 J
20 U
50 U
61
10 U
6 U
6 U
20 U
20 U
20 U
20 U
6 U
6 U
6 U
50 U
90 U
90 U
90 U
90 U
90 U
200
90 U
590 U
SD219
11/15/97
16:20
83
20 U
150
20 U
10 U
8 U
9.5
50 U
50 U
75
12 U
8 V
8 U
20 U
20 U
20 U
25 U
8 U
8 U
8 U
50 U
170 U
170 U
170 U
170 U
170 U
360
170 U
750 U
SD220
11/15/97
16:45
70
11 U
400
II U
10 u
4.3 U
20 U
30 U
24
13 U
4.3 U
4.3 U
11 U
II U
n u
n u
4.3 U
4.3 U
4.3 U
30 LI
82 U
82 U
82 U
82 U
82 U
250
82 U
470 U
-------
Table 5-23 (D)
Sediment Analytical Results - Pesticides and RGBs
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD221
SD222
Effects
11/16/97
11/16/97
Values
09:45
10:25
% MOISTURH
%
77
86
1 -HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
16
U
25
U
4,4'-DDE (P,P'-DDE)
UG/KG
2.07
180
160
4.4'-DDT(P,P'-DDT)
UG/KG
1.19
16
U
25
u
ALDR1N
UG/KG
8
U
8.9
u
ALPHA-BHC
UG/KG
5.5
u
8.9
u
ALPHA-CHLORDANE 12
UG/KG
ALPIIA-CHLORDENE /2
UG/KG
BETA-BHC
UG/KG
22
U
21
u
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
35
u
60
u
CHLORDENE /2
UG/KG
34
22
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
12
u
28
u
DIEI-DRIN
UG/KG
0.02
5.5
u
8.9
u
ENDOSUI.FAN I (ALPHA)
UG/KG
5 5
u
8.9
u
ENDOSULFAN II (BETA)
UG/KG
16
u
25
u
ENDOSULFAN SULFATE
UG/KG
16
u
25
u
ENDRIN
UG/KG
0.02
16
u
25
u
ENDRIN KETONE
UG/KG
17
u
25
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
5.5
u
8.9
(/
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
5.5
u
8.9
u
HEPTACHLOR EPOXIDE
UG/KG
5.5
u
8.9
u
METHOXYCHLOR
UG/KG
36
u
51
u
OXYCW URDANE (OCTACHLOREPOXIDE) K UG/KG
PCB-IOn. aROCLOR 1016)
UG/KG
130
u
190
u
PCB-1221 (AROCLOR 1221)
UG/KG
130
u
190
u
PCB-1232 (AROCLOR 1232)
UG/KG
130
u
190
u
PCB-1242 (AROCLOR 1242)
UG/KG
130
u
190
u
PCB-1248 (AROCLOR 1248)
UG/KG
130
u
190
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
400
380
PCB-1260 (AROCLOR 1260)
UG/KG
130
u
190
u
TOXAPHENE
UG/KG
550
u
890
u
TRANS-NONACHLOR 12
UG/KG
»
Note: p • -^rt-d values exceeding the RAGS EV arc in bold. Values with EDL exceeding RAGS EV are italicized.
No'-. 1 lie estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-221, and 222 had a mix ofaorclors. Closest matches reported.
Data Qualifiers
U-Matcrial was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, sec chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 5-24 (A)
Sediment Analytical Results - Pesticides and PCBs
300 Series Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD301
SD302
SD302DUP
SD303
Effects
11/16/97
11/16/97
11/16/97
11/16/97
Values
10:50
11:25
11:30
12:00
% MOISTURE
%
86
85
81
83
l-HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
25
U
7.1
JN
20
U
20
U
4,4'-DDE (P,P'-DDE)
UG/KG
2.07
230
130
J
280
100
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
25
U
18
UJ
20
U
20
U
ALDRIN
UG/KG
13
U
9.9
UJ
11
u
13
U
ALPHA-BHC
UG/KG
10
u
9.9
UJ
7
u
8
u
ALPHA-CHLORDANE 11
UG/KG
ALPHA-CHLORDENE 12
UG/KG
4.3
J
4.4
J
BETA-BHC
UG/KG
34
u
9.9
UJ
35
u
8
u
BETA-CHLORDENE 12
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
60
u
79
UJ
45
u
50
u
CHLORDENE /2
UG/KG
28
12
J
37
9.7
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
16
u
9.9
UJ
16
u
14
u
DIELDRIN
UG/KG
0.02
10
u
9.9
UJ
7
u
8
u
ENDOSULFAN I (ALPHA)
UG/KG
10
u
9.9
UJ
7
u
8
u
ENDOSULFAN 11 (BETA)
UG/KG
25
u
18
UJ
20
u
20
u
ENDOSULFAN SULFATE
UG/KG
25
u
18
UJ
20
u
20
u
ENDRIN
UG/KG
0.02
25
u
18
UJ
20
u
20
u
ENDRIN KETONE
UG/KG
26
u
15
UJ
24
u
20
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
JO
u
9.9
UJ
7
u
8
u
GAMMA-CIILORDANE 12
UG/KG
GAMMA-CHLORDENE tl
UG/KG
HEPTACHLOR
UG/KG
10
u
9.9
UJ
7
u
8
u
HEPTACHLOR EPOXIDE
UG/KG
10
u
9.9
UJ
7
u
8
u
METHOXYCHLOR
UG/KG
86
u
24
UJ
45
u
50
u
O.P-DDE
UG/KG
NR
11
JN
NR
NP
OXYCHLORDANE (OCTACHLOREPOXIDE) K UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
270
U
120
UJ
200
u
120
u
PCB-1221 (AROCLOR 1221)
UG/KG
270
u
120
UJ
200
u
120
u
PCB-1232 (AROCLOR 1232)
UG/KG
270
u
120
UJ
200
u
120
u
PCB-1242 (AROCLOR 1242)
UG/KG
270
u
120
UJ
200
u
120
u
PCB-1248 (AROCLOR 1248)
UG/KG
270
u
120
UJ
200
u
120
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
490
270
J
600
330
PCB-1260 (AROCLOR 1260)
UG/KG
270
u
250
UJ
200
u
120
u
TOXAPHENE
UG/KG
920
u
560
UJ
690
u
760
u
TRANS-NONACIILOR 12 UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-301, 302, 302DUP, 303, and 304 had a mix of aorclors. Closest matches reported.
Note: Recommended holding (inte exceeded for sample SD-302
Data Qualifiers
J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1 .When no value is reported, see chlordane constituents.
ICimlitmtt otiiKtiboki ofltchnkil chMm
SD304
11/16/97
12:20
83
20 U
330
20 U
11 U
8 U
75 U
50 U
9.6
20 U
8 V
8 U
20 U
20 U
20 V
20 U
8 U
8 U
8 U
50 U
NR
180 U
180 U
180 U
180 U
180 U
600
180 U
750 U
-------
Table 5-25 (A)
Sediment Analytical Results - Pesticides and PCBs
400/500 Series Samples - Upstream
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD401
SD402
SD403 SD403DUP
Effects
11/16/97
11/16/97
11/16/97
11/16/97
Values
12:55
13:15
13:44
13:50
% MOISTURE
%
72
72
73
75
1-HYDROXYCHLORDENE /2
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
18 U
16 U
19 U
16
U
4,4*-DDE (P,P*-DDE)
UG/KG
2.07
370
170
150
67
4,4'-DDT (P,P*-DDT)
UG/KG
1.19
18 U
16 U
9.2 U
16
U
ALDRIN
UG/KG
5 U
5 U
8.8 U
8.4
U
ALPHA-BHC
UG/KG
5 U
5 U
8.8 U
8.4
U
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
BETA-BHC
UG/KG
5 U
5 U
8.8 U
8.4
U
BETA-CHLORDENE il
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
31 U
36 U
35 U
37
U
CHLORDENE 12
UG/KG
120
22
9.2
4
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
14 U
5 U
8.8 U
8.4
U
D1ELDRIN
UG/KG
0.02
5.6 U
5 V
8.8 U
8.4
V
ENDOSULFAN 1 (ALPHA)
UG/KG
5 U
8.9 U
8.8 U
16
u
ENDOSULFAN H (BETA)
UG/KG
18 U
16 U
19 U
16
u
ENDOSULFAN SULFATE
UG/KG
18 U
16 U
19 U
16
u
ENDRrN
UG/KG
0.02
18 U
16 V
19 U
16
V
ENDRIN KETONE
UG/KG
18 U
15 U
18 U
15
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
5 U
5 U
8.8 U
8.4
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE /2
UG/KG
HEPTACHLOR
UG/KG
5 U
5 U
8.8 U
8.4
u
HEPTACHLOR EPOXIDE
UG/KG
5 U
5 U
8.8 U
8.4
u
METHOXYCHLOR
UG/KG
27 U
25 U
28 U
30
u
O.P-DDE
UG/KG
51
16
23
7.6
J
O.P-DDT
UG/KG
NR
NR
NR
NR
OXYCHL^RDANE(OCTACHLOREPOXIDE) /: UG/KG
PCB-I0W AsHOCLOR 1016)
UG/KG
120 U
100 U
77 U
82
U
PCB-1221 VAROCLOR 1221)
UG/KG
120 U
100 U
77 U
82
U
PCB-1232 (AROCLOR 1232)
UG/KG
120 U
100 U
77 U
82
u
PCB-1242 (AROCLOR 1242)
UG/KG
120 U
100 U
77 U
82
u
PCB-1248 (AROCLOR 1248)
UG/KG
120 U
100 u
77 U
82
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
580
260
120
75
PCB-1260 (AROCLOR 1260)
UG/KG
550 U
250 U
100 u
70
u
TOXAPHENE
UG/KG
720 U
560 U
600 U
540
u
TRANS-NONACHLOR 12
UG/KG
Note: Reporte^atues exceeding (he RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Notg; Th<*>stij ated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Not?- Sanipies SD-401,402,403,403DUP, 404,405,406, and 407 had a mix of aorclors. Closest matches reported.
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
I .When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
SD404 SD405
11/16/97 11/16/97
15:00 15:20
83 82
21 U 20 U
100 220
21 U 20 U
15 U 7.2 U
15 U 7.2 U
SD406 SD407
11/16/97 11/18/97
15:35 09:00
82 82
25 V 20 U
290 130
25 U 20 U
7 U 16 U
7 U 9.3 U
15 U
53 U
19
15 U
15 U
15 U
21 U
21 U
21 U
21 U
15 U
7.2 U
170 U
77
7.2 U
7.2 U
14 U
20 U
20 U
20 U
24 U
7.2 U
7.8 U
47 U
34
7 U
7 V
7 U
25 U
25 U
25 U
23 U
14 U
9.3 U
50 U
15
9.3 U
9.3 U
9.3 U
20 U
20 U
20 U
21 U
23 U
15 U
15 U
37 U
12
NR
120 U
120 U
120 U
120 U
120 U
250
200 U
710 U
7.2 U
7.2 U
44 U
45
9 N
120 U
120 U
120 U
120 U
120 U
500
450 U
840 U
7 U
7 U
40 U
26
6.9 N
140 U
140 U
140 U
140 U
140 U
520
500 U
870 U
9.3 U
9.3 U
44 U
16
NR
170 U
170 U
170 U
170 U
170 U
380
350 U
800 U
-------
Table 5-25 (B)
Sediment Analytical Results - Pesticides and PCBs
400/500 Series Samples - Upstream
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD408
SD409
SD4I0
SD411
SD4I2
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
Values
09:23
09:55
10:20
10:50
11:15
% MOISTURE
%
86
70
79
68
80
1-HYDROXYCHLORDENE /2
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
23 U
12 U
21 U
19 U
22 U
4,4'-DDH (P.P'-DDE)
UG/KG
2.07
200
220
56
300
290
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
23 U
12 U
21 U
33
22 U
ALDRTN
UG/KG
29 U
4.7 U
9.7 U
7.4 U
7.4 U
ALPHA-BHC
UG/KG
13 U
4.7 U
9.7 U
7.4 U
7.4 U
ALPHA-CHLORDANE 12
UG/KG
ALPHA-CHLORDENE 12
UG/KG
BETA-BHC
UG/KG
13 U
4.7 U
9.7 U
7.4 U
7.4 U
BETA-CHLOR DENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
83 U
26 U
42 U
24 U
42 U
CHLORDENE 12
UG/KG
38
10
2.9 J
13
47
C1S-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
13 U
4.7 U
9.7 U
24 U
17 U
DIELDRIN
UG/KG
0.02
13 U
28 V
9.7 V
42 V
7.4 i?
ENDOSULFAN I (ALPHA)
UG/KG
13 U
4.7 U
9.7 U
12 U
7.4 U
ENDOSULFAN II (BETA)
UG/KG
23 U
12 U
21 U
19 U
22 U
ENDOSULFAN SULFATE
UG/KG
23 U
12 V
21 U
19 U
22 U
ENDRIN
UG/KG
0.02
23 U
12 U
21 U
19 V
22 V
ENDRIN KETONE
UG/KG
29 U
12 U
20 U
12 U
21 U
GAMMA-BHC (LINDANE)
UG/KG
0.32
31 U
4.7 U
9.7 U
7.4 V
7.4 U
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE /2
UG/KG
HEPTACHLOR
UG/KG
3.6 J
4.7 U
9.7 U
7.4 U
7.4 U
HEPTACHLOR EPOXIDE
UG/KG
13 U
4.7 U
9.7 U
7.4 U
7.4 U
METHOXYCHLOR
UG/KG
71 U
23 U
39 U
21 U
38 U
O.P-DDE
UG/KG
24 N
28
4.2 J
29
22 N
OfP-DDT
UG/KG
11 N
NR
NR
NR
NR
OXYCIILORDANE (OCTACHLOREPOXIDE) r. UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
240 U
65 U
84 U
69 U
180 U
PCB-1221 (AROCLOR 1221)
UG/KG
240 U
65 U
84 U
69 U
180 U
PCB-1232 (AROCLOR 1232)
UG/KG
240 U
65 U
84 U
69 U
180 U
PCB-1242 (AROCLOR 1242)
UG/KG
240 U
65 U
84 U
69 U
180 U
PCB-1248 (AROCLOR 1248)
UG/KG
240 U
65 U
84 U
69 U
180 U
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
680
180
73
180
620
PCB-1260 (AROCLOR (260)
UG/KG
650 U
150 U
70 U
150 U
600 U
TOXAPHENE
UG/KG
1200 U
440 U
630 U
450 U
840 U
TRANS-NONACHLOR 12
UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Nole: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-408,409,410,411,412, 413,414, and 415 had a mix of aorclots. Closest matches reported.
Data Qualifiers
J-Estiniated value.
N-Presumplive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
l.When no value is reported, see chlordane constituents.
SD4I3
11/18/97
11:45
SD4I4
11/18/97
13:01
SD415
11/18/97
13:01
82
18 U
130
18 U
10 U
10 U
71
18 U
170
18 U
4.8 U
4.8 U
65
23 U
440
23 U
3.9 U
3.9 U
10 U
54 U
18
10 U
10 U
11 U
18 U
)8 U
18 U
20 U
10 U
4.8 U
30 U
32
4.8 U
51 U
11 U
18 U
18 U
18 U
15 U
4.8 U
3.9 U
21 U
39
33 U
8! U
13 U
23 U
23 U
23 U
II U
3.9 U
10 U
10 U
47 U
29 J
NR
130 U
130 U
130 U
130 U
130 U
330
300 U
780 U
4.8 IJ
10 U
25 U
23
NR
77 U
77 U
77 U
77 U
77 U
210
200 U
490 U
3.9 U
3.9 U
21 U
52 JN
NR
60 U
60 U
60 U
60 U
60 U
210
200 U
450 U
-------
Table 5-25 (C)
Sediment Analytical Results - Pesticides and PCBs
400/500 Series Samples - Upstream
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD416
SD417
SD417DUP
SD418
SD419
SD420
SD421
SD422
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
1 1/18/97
11/18/97
Values
13:20
13:45
13:50
14:03
14:27
14:47
15:20
15:47
% MOISTURE
%
79
79
79
68
77
62
77
67
1-HYDROXYCHLORDENE tl
UG/KG
4,4'-DDD (P,P'-DDD)
UG/KG
1.22
16
U
44
V
22
U
7.2
J
22
N
17
N
22
N
11
N
4,4'-DDE (P.P'-DDE)
UG/KG
2.07
100
320
240
410
190
440
160
370
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
85
N
740
N
22
U
26
V
32
U
31
U
22
N
24
U
ALDRfN
UG/KG
6.8
U
6.7
u
9.4
U
19
u
10
U
3.8
u
5.7
U
4.9
u
ALPHA-BHC
UG/KG
6.8
u
6.7
U
9.4
U
10
u
10
U
3.8
U
5.7
U
4.9
u
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
5.9
BETA-BHC
UG/KG
6.8
u
6.7
U
9.4
U
19
u
10
U
3.8
U
5.7
U
4.9
u
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) i\
UG/KG
55
u
51
u
40
U
60
u
52
U
17
U
95
u
24
u
CHLORDENE /2
UG/KG
22
57
47
34
13
24
12
21
CIS-NONACHLOR il
UG/KG
DELTA-BHC
UG/KG
6.8
u
39
u
33
U
29
u
29
U
37
u
56
u
43
u
DIELDRrN
UG/KG
0.02
6.8
u
6-7
u
9,4
U
12
u
32
U
170
u
40
V
240
u
ENDOSULFAN 1 (ALPHA)
UG/KG
11
u
6.7
u
11
U
19
u
26
U
3.8
u
45
u
4.9
u
ENDOSULFAN 11 (BETA)
UG/KG
16
u
15
u
22
U
25
u
14
U
7
u
14
u
7.5
u
ENDOSULFAN SULFATE
UG/KG
16
u
480
u
22
u
25
u
14
U
7
u
14
u
7.5
u
ENDRIN
UG/KG
0.02
16
u
15
u
22
u
2!
u
14
U
7
u
14
V
7.5
u
ENDRIN KETONE
UG/KG
20
u
19
u
19
u
26
u
19
u
9.3
u
20
u
14
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
6.8
u
6.7
V
9.4
u
10
u
10
u
3.8
u
5.7
u
4.9
u
GAMMA-CHLORDANE 12
UG/KG
GAMMA-CHLORDENE /2
UG/KG
HEPTACHLOR
UG/KG
6.8
u
6.7
u
9.4
u
10
u
10
u
3.8
u
5.7
u
4.9
u
HEPTACHLOR EPOXIDE
UG/KG
6.8
u
6.7
u
9.4
u
10
u
10
u
3.8
u
5.7
u
4.9
u
METHOXYCHLOR
UG/KG
47
u
38
u
39
u
60
u
35
u
17
u
47
u
28
u
O.P-DDE
IJG/KG
n
J
40
JN
33
N
NR
25
N
120
N
20
N
120
N
O.P-DDT
UG/KG
9.4
N
33
JN
NR
NR
NR
NR
NR
NF
OXYCH' :«RDANE (OCTACHLOREPOXIDE) /: UG/KG
PCB-101 » ,**OCLOR 1016)
UG/KG
140
u
240
U
190
U
190
u
140
u
60
u
94
U
53
U
PCB-1221 (AROCLOR 1221)
UG/KG
140
u
240
U
190
U
190
u
140
U
60
u
94
U
53
u
PCB-1232 (AROCLOR 1232)
UG/KG
140
u
240
u
190
u
190
u
140
U
60
u
94
U
53
u
PCB-1242 (AROCLOR 1242)
UG/KG
140
u
240
u
190
u
190
u
140
u
60
u
94
U
53
u
PCB-1248 (AROCLOR 1248)
UG/KG
140
u
240
u
190
u
190
u
140
u
60
u
94
U
53
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
320
760
660
420
290
220
200
180
PCB-1260 (AROCLOR 1260)
UG/KG
300
u
750
u
650
u
190
u
250
u
200
u
150
U
150
u
TOXAPHENE
UG/KG
740
u
840
u
790
u
950
u
710
u
510
u
730
U
440
u
TRANS-NONACHLOR 12 UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Nole: T- timated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Nc.c: SamplesSD-416,417,4I7DUP, 418,419,420,421, and 422 had a mix of aorclors. Closest matches reported.
Data Qualifiers
J*Estimatcd value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
I .When no value is reported, sec clilordanc constituents.
2.Cous(i(ucn(s or metabolites of technical chlordane.
-------
Table 5-25 (D)
Sediment Analytical Results - Pesticides and PCBs
400/500 Series Samples - Upstream
Military Canal Special Study
Homestead Air Force Base
November, 1997
y
RAGS
SD423
SD424
SD425
SD503A
Effects
11/18/97
11/19/97
11/19/97
11/19/97
Values
16:15
09:17
09:25
11:15
% MOISTURE
%
75
76
8)
58
1-HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P.P'-DDD)
UG/KG
1.22
16 N
3.4 N
4.9 JN
14
4,4'-DDE (P.P'-DDE)
UG/KG
2.07
190
44
9.9 J
600
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
19 U
7 U
8.5 UJ
21 U
ALDRIN
UG/KG
10 U
4.1 U
4.5 UJ
8.5 U
ALPHA-BHC
UG/KG
10 U
3.1 U
4.5 UJ
8.5 U
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
40
BETA-BHC
UG/KG
10 u
4.7 U
4.5 UJ
10 U
BETA-CHLORDENE 11
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
37 U
20 U
30 UJ
54 U
CHLORDENE fl
UG/KG
12
7.2
2.3 J
22
CIS-NONACHLOR /2
UG/KG
DELTA-BIIC
UG/KG
39 U
13 U
4.5 UJ
65 U
DIELDRIN
UG/KG
0.02
NO U
4.4 U
4 5 UJ
8.S U
ENDOSULFAN 1 (ALPHA)
UG/KG
10 u
4.4 U
4.5 UJ
8.5 U
ENDOSULFAN 11 (BETA)
UG/KG
15 U
14 U
8.5 UJ
25 U
ENDOSULFAN SULFATE
UG/KG
15 U
11 U
8.5 UJ
24 U
ENDRIN
UG/KG
0.02
IS U
6 V
5.5 UJ
21 U
ENDRIN KETONE
UG/KG
18 U
14 U
10 UJ
25 U
GAMMA-BHC (LINDANE)
UG/KG
0.32
10 u
3.1 U
4.5 UJ
8.5 U
GAMMA-CHLORDANE H
UG/KG
GAMMA-CHLORDENE fl
UG/KG
HEPTACHLOR
UG/KG
10 u
3.6
4.5 UJ
8.5 U
HEPTACHLOR EPOXIDE
UG/KG
10 u
3.1 U
4.5 UJ
4.5 N
METHOXYCHLOR
UG/KG
31 U
23 U
22 UJ
47 U
O.P-DDD
UG/KG
NR
NR
NR
5.6 N
O.P-DDE
UG/KG
44 N
NR
4.4 JN
27 J
OXYCHLORDANE (OCTACHLOREPOXIDE) /: UG/XG
PCB«I016 (AROCLOR 1016)
UG/KG
55 U
44 U
42 UJ
150 U
PCB-1221 (AROCLOR 1221)
UG/KG
55 U
44 U
42 UJ
150 U
PCB-1232 (AROCLOR 1232)
UG/KG
55 U
44 U
42 UJ
150 IJ
PCB-1242 (AROCLOR 1242)
UG/KG
55 U
44 U
42 l/J
150 U
PCB-1248 (AROCLOR 1248)
UG/KG
55 V
44 U
42 UJ
150 U
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
110
81
26 J
150 U
PCB-) 260 (AROCLOR 1260)
UG/KG
100 u
44 U
42 UJ
150 U
TOXAPHENE
UG/KG
440 U
440 U
380 UJ
860 U
TRANS-NONACHLOR 12
UG/KG
Note: Reported values exceeding (he RAGS EV are in bold. Values with HDL exceeding RAGS EV are italicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-423,424, and 42S had a mix oraorclors. Closest matches reported.
Note: Sample SD-425 exceeded recommended holding time-
Data Qualifiers
J'Estimated value.
N-Presurnptive evidence of presence ofmaterial.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
I II/mAM MM IIMIIIA §M JJJ jumgJkfmMMA MflW/ZjIJIl/i
ItfflrCfl n\f rf/wTV /OWOT/ fCv winnvMlK wflfflluCfllSi
ICoffttfltitfitiOfffltMitti ofttcMcilchfofdtiit
SD503B
\V\9f97
11:15
39
3.2
76
5 U
2 U
2 U
6.5
2.7 U
13 U
7.9
24 U
2 U
2 U
5 U
5 U
5 U
5 U
2 U
2 U
2 U
II U
1 JN
1.9 J
38 U
38 U
38 U
38 U
38 U
38 U
38 U
200 U
-------
Table 5-26 (A)
Sediment Analytical Results - Pesticides and PCBs
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD601
SD602
SD603
SD604
SD605
SD605DUP
SD606
SD607
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
Values
08:45
09:08
09:31
09:55
10:20
10:25
11:48
13:02
% MOISTURE
%
41
55
53
63
63
64
68
72
1-HYDROXYCHLORDENE /2
UG/KG
4,4-DDD (P.P'-DDD)
UG/KG
1.22
5,6 U
7.6
U
7.3
U
9.6
U
9.9
U
9.7
U
11
U
14
U
4,4'-DDE (P.P-DDE)
UG/KG
2.07
22
53
17
71
15
15
26
23
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
5.6 U
7.6
U
7.3
U
9.6
U
9.9
U
9.7
u
11
U
14
U
ALDRIN
UG/KG
4.1 U
4.9
u
6.1
u
8
U
4.6
U
5.4
u
8.8
U
6.5
U
ALPHA-BHC
UG/KG
4.1 U
4.9
u
6.1
u
8
u
4.6
U
5.4
u
8.8
u
6.5
U
ALPHA-CHLORDANE 12
UG/KG
ALPHA-CHLORDENE 12
UG/KG
BETA-BHC
UG/KG
4.1 U
4.9
u
6.1
u
8
u
4.6
U
5.4
u
8.8
u
6.5
u
BETA-CHLORDENE 12
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
13 U
16
u
18
u
19
u
23
u
22
u
29
u
29
u
CHLORDENE /2
UG/KG
0.71 J
9.2
2
JN
18
2.3
2.1
J
1.4
J
2.1
J
CIS-NONACHLOR /2
UG/KG
DELTA-BHC
UG/KG
6.3 U
9.1
u
9.4
u
15
u
13
u
11
u
21
u
14
U
D1ELDRIN
UG/KG
0.02
5.6 U
7.6
u
6!
u
8
u
4.6
u
5.4
u
8.8
u
6.5
u
ENDOSULFAN I (ALPHA)
UG/KG
4.1 U
4.9
u
6.1
u
8
u
4.6
u
5.4
u
8.8
u
6.5
u
ENDOSULFAN II (BETA)
UG/KG
5.6 U
7.6
u
7.3
u
9.6
u
9.9
u
9.7
u
11
u
14
u
ENDOSULFAN SULFATE
UG/KG
5.6 U
7.6
u
7.3
u
9.6
u
9.9
u
9.7
u
11
u
14
u
ENDRIN
UG/KG
0.02
56 U
7.6
u
7.3
u
9.6
u
9.9
u
9.7
u
11
V
N
u
ENDRIN KETONE
UG/KG
7.8 U
8.9
u
9.7
V
10
u
12
u
12
u
14
u
19
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
4.1 U
4.9
u
6.1
V
8
u
4.6
u
5.4
u
8.8
u
6.5
u
GAMMA-CHLORDANE /2
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
4.1 U
4.9
u
6.1
V
8
u
4.6
u
5-4
u
8.8
u
6.5
u
HEPTACHLOR EPOXIDE
UG/KG
4.1 U
4.9
u
6.1
u
8
u
4.6
u
5.4
u
8.8
u
6.5
u
METHOX YCIILOR
UG/KG
13 U
21
u
15
u
32
u
20
u
23
u
21
u
25
u
O.P-DDE
UG/KG
5.2
7.1
N
3.6
JN
7.1
N
2
JN
2
JN
2
JN
NF
OXYCHL %J?1>ANE (OCTACHLOREPOXIDE) K UG/KG
PCB-1016(.AKOCLOR 1016)
UG/KG
26 U
47
u
42
u
67
u
50
u
52
u
55
u
65
u
PCB-1221 (AROCLOR 1221)
UG/KG
26 U
47
u
42
u
67
u
50
u
52
u
55
u
65
u
PCB-1232 (AROCLOR 1232)
UG/KG
26 U
47
u
42
u
67
u
50
u
52
u
55
u
65
u
PCB-1242 (AROCLOR 1242)
UG/KG
26 U
47
u
42
u
67
u
50
u
52
u
55
u
65
U
PCB-1248 (AROCLOR 1248)
UG/KG
26 U
47
u
42
u
67
u
50
u
52
u
55
u
65
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
34 U
58
29
J
93
82
u
83
u
54
J
38
J
PCB-1260 (AROCLOR 1260)
UG/KG
34 U
55
u
25
u
90
u
82
u
83
u
50
u
35
u
TOXAPHENE
UG/KG
210 U
320
u
340
u
350
u
360
u
360
u
410
u
540
u
TRANS-NONACHLOR /2 UG/KG
»
Note; values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-602,603,604, 606, and 607 had a mix of aorclors. Closest matches reported.
Data Qualifiers
J-Estimated value.
.N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constitucnts or metabolites of technical chlordane.
-------
Table 5-26 (B)
Sediment Analytical Results - Pesticides and PCBs
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD608
SD609
SD610
SD70I
SD702
SD703
SD703DUP
SD801
Effects
11/(8/97
11/(8/97
f 1/18/97
11/19/97
11/19197
11/19/97
11/19/97
11/19/97
Values
13:26
14:34
15:00
16:20
16:22
16:25
16:25
14:10
% MOISTURE
%
70
68
70
81
70
73
63
86
l-HYDROXYCHLORDENE 12
UG/KG
4,4'-DDD (P.P-DDD)
UG/KG
1.22
13 U
11 U
10 U
2
J
5 U
1.5 J
1.1 J
10 U
4,4'*DDE (P.P-DDE)
UG/KG
2.07
17
17
18
54
20
57
32
7.9
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
13 U
11 U
10 U
7.6
U
5 U
5.1 U
3.6 U
10 U
ALDRJN
UG/KG
7.2 U
7.4 U
8.8 U
3
u
2.1 U
2.3 U
2 U
4.3 U
ALPHA-BHC
UG/KG
7.2 U
7.4 U
8.8 U
3
u
2.1 U
2.3 U
2 U
4.3 U
ALPHA-CHLORDANE 12
UG/KG
ALPHA-CHLORDENE 12
UG/KG
BETA-BHC
UG/KG
7.2 U
7.4 U
8.8 U
5.2
u
D
00
r"i
3.8 U
3,1 U
6.8 U
BETA-CHLORDENE 12
UG/KG
CHLORDANE (TECH. MIXTURE) /I
UG/KG
27 U
24 U
27 U
19
u
15 U
13 U
9 U
25 U
CHLORDENE /2
UG/KG
1.7 J
1.2 J
4.6
5.5
2 N
4.2
3 N
1.9 J
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
11 U
7.4 U
8.8 U
14
u
9.1 U
8.9 U
6.5 U
6.6 U
DIELDRJN
UG/KG
0.02
7.2 U
7.4 V
8.8 U
4.8
u
3.2 V
2.3 V
2 V
4.3 U
ENDOSULFAN I (ALPHA)
UG/KG
7.2 U
7.4 U
8.8 U
4.8
u
3.2 U
2.3 U
2 U
4.3 U
ENDOSULFAN II (BETA)
UG/KG
13 U
11 U
10 u
11
u
6.4 U
7.5 U
5.2 U
10 u
ENDOSULFAN SULFATE
UG/KG
13 U
II u
10 u
7.6
u
5 U
5.1 U
5.2 U
10 u
ENDRIN
UG/KG
0.02
13 U
11 V
10 u
6.5
u
5 U
5.1 V
3 6 V
10 V
ENDRIN KETONE
UG/KG
13 U
13 U
13 U
16
u
9.9 U
10 U
7.8 U
12 U
GAMMA-BHC (LINDANE)
UG/KG
0.32
7.2 V
7.4 V
8.8 V
3
u
2.1 U
2.3 U
2 U
4.3
GAMMA-CHLORDANE 12
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
7.2 U
7.4 U
8.8 U
6.4
u
2.1 U
2.3 U
2 U
4.8
HEPTACHLOR EPOXIDE
UG/KG
7.2 U
7.4 U
8.8 U
3
u
2.1 U
2.3 U
2 U
4.3 U
METHOXYCHLOR
UG/KG
36 U
21 U
24 U
25
u
17 U
17 U
14 U
25 U
O.P-DDE
UG/KG
NR
1.5 JN
NR
NR
NR
NR
NR
NR
OXYCHLORDANE (OCTACHLOREPOXIDE) /; UG/KG
PCB-1016 (AROCLOR 1016)
UG/KG
55 U
90 U
55 U
43
U
28 U
36 U
33 U
95 ir
PCB-1221 (AROCLOR 1221)
UG/KG
55 U
90 U
55 U
43
u
28 U
36 U
33 U
95 U
PCB-1232 (AROCLOR 1232)
UG/KG
55 U
90 U
55 U
43
u
28 U
36 U
33 U
95 U
PCB-1242 (AROCLOR 1242)
UG/KG
55 U
90 U
55 U
43
u
28 U
36 U
33 U
95 U
PCB-1248 (AROCLOR 1248)
UG/KG
55 U
90 U
55 U
43
u
28 V
36 U
33 U
95 U
PCB-I254 (AROCLOR 1254)
UG/KG
21.6
48 J
80 U
80 U
74
JN
28 U
61 JN
33 U
95 U
PCB-1260 (AROCLOR 1260)
UG/KG
45 U
80 U
80 U
43
u
28 U
36 U
33 U
95 U
TOXAPHENE
UG/KG
480 U
370 U
400 U
300
U
200 U
200 U
140 U
410 U
TRANS-NONACHLOR /2
UG/KG
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note: The estimated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note: Samples SD-608, 701 and 703 had a mix of aorcfors Closest matches reported.
Data Qualifiers
J'Esiimafed value.
N-Presumptive evidence of presence of material.
NR-Nol Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation finn'l.
I.When no value is reported, see chlordane constituents.
^Constituents or metabolites of technical chlordane.
-------
Table 5-26 (C)
Sediment Analytical Results - Pesticides and PCBs
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD801DUP
SD802
SD803
Effects
11/19/97
11/19/97
11/19/97
Values
14:10
14:45
15:16
% MOISTURE
%
85
86
88
1-HYDROXYCHLORDENE J2
UG/KG
4,4'-DDD (P.P -DDD)
UG/KG
1.22
8.4
U
11
U
12
V
4,4'-DDE (P,P*-DDE)
UG/KG
2.07
5.7
11
11
4,4'-DDT (P.P'-DDT)
UG/KG
1.19
8.4
U
It
u
12
U
ALDRIN
UG/KG
3.8
u
5.4
U
5.5
u
ALPHA-BHC
UG/KG
3.8
u
5.4
U
4.6
u
ALPHA-CHLORDANE /2
UG/KG
ALPHA-CHLORDENE /2
UG/KG
BETA-BHC
UG/KG
5.1
u
9.2
U
8
u
BETA-CHLORDENE /2
UG/KG
CHLORDANE (TECH. MIXTURE) !\
UG/KG
25
u
30
U
29
u
CHLORDENE 12
UG/KG
2.6
2.3
3.9
N
CIS-NONACHLOR 12
UG/KG
DELTA-BHC
UG/KG
6.2
u
12
u
8
u
DIELDRIN
UG/KG
0.02
3.8
u
5.4
u
4.6
u
ENDOSULFAN I (ALPHA)
UG/KG
5.5
u
5.4
U
6.6
u
ENDOSULFAN II (BETA)
UG/KG
8.4
u
11
u
12
u
ENDOSULFAN SULFATE
UG/KG
8.4
u
11
u
12
u
ENDRJN
UG/KG
0.02
8.4
u
//
u
n
V
ENDRIN KETONE
UG/KG
8.4
u
11
u
12
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
3.8
u
5.4
u
4.6
u
GAMMA-CHLORDANE fl
UG/KG
GAMMA-CHLORDENE 12
UG/KG
HEPTACHLOR
UG/KG
5
5,4
u
5,1
u
HEPTACHLOR EPOXIDE
UG/KG
3.8
u
5.4
u
4.6
u
METHOXYCHLOR
UG/KG
20
u
29
u
25
u
OXYCHLORDANE (OCTACHLOREPOXIDE) /; UG/KG
PCB-10I6 AROCLOR 1016)
UG/KG
47
u
60
u
70
u
PCB-122. -AftOCLOR 1221)
UG/KG
47
u
60
u
70
u
PCB-1232 (AROCLOR 1232)
UG/KG
47
u
60
u
70
u
PCB-1242 (AROCLOR 1242)
UG/KG
47
u
60
u
70
u
PCB-1248 (AROCLOR 1248)
UG/KG
47
u
60
u
70
u
PCB-125 4 (AROCLOR 1254)
UG/KG
21.6
47
u
60
u
70
u
PCB-1260 (AROCLOR 1260)
UG/KG
47
u
60
u
70
u
TOXAPHENE
UG/KG
390
u
450
u
500
u
TRANS-NONACHLOR /2 UG/KG
Note: Reportet^values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Note: Th^*sti<-«ated detection limit can be calculated by dividing the minimum quantitation limit by 20.
Note- Samples SD-608, 701 and 703 had a mix of aorclors. Closest matches reported.
Data Qualifiers
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, sec chlordanc constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 5-27 (A)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD10I
SD101
SD101R
SD102
SD102DUP
SD103
SD104
SD104
SD104R
SD105
11/13/97
11/16/97
11/19/97
11/13/97
11/13/97
11/13/97
11/13/97
11/16/97
11/19/97
11/13/97
13.35
09:40
13:35
14:03
14:10
15:00
15:30
10:02
13:36
15:55
% MOISTURE
%
45.1
75.8
(M- AND/OR P-)XYLENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1.1,1,2-TETRACHLOROETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1,1 -TRICHLOROETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1,2,2-TETRACHLOROETH ANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1,2-TRICHLOROETH ANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1-DICHLOROETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,1 -DICHLOROPROPENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,2,3-TRlCHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,2,3-TRICHLOROPROPANE
UG/KG
NA
3.5
UJ
16 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,2,4-TRICHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
2.5
J
1.6
U
NA
1,2,4-TRIMETHYLBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
U
NA
1,2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
16
U
NA
1,2-DIBROMOETHANE (EDB)
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
1,2-DICHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
1,2-DICHLOROETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
16
u
NA
1,2-DICHLOROPROPANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
1,3,5-TRJMETHYLBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
16
u
NA
1,3-DICHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
1,3-DICHLOROPROPANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
16
u
NA
1,4-DICHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6 IJ
NA
NA
NA
NA
2.9
J
16
u
NA
2,2-DICHLOROPROPANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
ACETONE
UG/KG
NA
88
UJ
41 U
NA
NA
NA
NA
600
UJ
48
u
NA
BENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
BROMOBENZENE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
BROMOCHLOROMETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
IJ
NA
BROMODICHLOROMETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
BROMOFORM
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
BROMOMETHANE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
CARBON DISULFIDE
UG/KG
NA
8.8
UJ
4.1 U
NA
NA
NA
NA
34
J
2.3
J
NA
CARBON TETRACHLORIDE
UG/KG
NA
3.5
UJ
1.6 U
NA
NA
NA
NA
7
UJ
1.6
u
NA
-------
Table 5-27 (A) (Continued)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SDIOI
SDI01
SD101R
11/13/97
11/16/97
11/19/97
13:35
09:40
13:35
CHLOROBENZENE
UG/KG
NA
3.5
UJ
1.6
U
CHLOROETHANE
UG/KG
NA
3.5
UJ
1.6
U
CHLOROFORM
UG/KG
NA
3.5
UJ
1.6
U
CHLOROMETHANE
UG/KG
NA
3.5
UJ
1.6
U
CIS-1,2-DICHLOROETHENE
UG/KG
NA
3.5
UJ
1.6
u
CIS-1.3-D1CHLOROPROPENE
UG/KG
NA
3.5
UJ
1.6
u
DIBROMOCHLOROMETHANE
UG/KG
NA
3.5
UJ
1.6
u
D1BROMOM ETHANE
UG/KG
NA
3.5
UJ
1.6
u
ETHYL BENZENE
UG/KG
NA
3.5
UJ
1.6
u
HEXACHLORO-1,3-BUTADlENE
UG/KG
NA
3.5
UJ
1.6
u
ISOPROPYLBENZENE
UG/KG
NA
3.5
UJ
1.6
u
METHYL BUTYL KETONE
UG/KG
NA
8.8
UJ
4.1
u
METHYL ETHYL KETONE
UG/KG
NA
88
UJ
41
u
METHYL ISOBUTYL KETONE
UG/KG
NA
8.8
UJ
4.1
u
METHYLENE CHLORIDE
UG/KG
NA
18
UJ
8.2
u
N-BUTYLBENZENE
UG/KG
NA
3.5
UJ
1.6
u
N-PROPYLBENZENE
UG/KG
NA
3.5
UJ
1.6
u
O-CHLOROTOLUENE
UG/KG
NA
3 5
UJ
1.6
u
O-XYLENE
UG/KG
NA
3.5
UJ
1.6
u
P-CHLOROTOLUENE
UG/KG
NA
3.5
UJ
1.6
u
P-ISOPROPYLTOLUENE
UG/KG
NA
3.5
UJ
1.6
u
PETROLEUM PRODUCT
UG/KG
NR
NR
N
SEC-BUTYLBENZENE
UG/KG
NA
3.5
UJ
1.6
u
STYRENE
UG/KG
NA
3.5
UJ
1.6
u
TERT-BUTYLBENZENE
UG/KG
NA
3.5
UJ
1.6
u
TETRACU LOROETHENE (TETRACHLOROETHYLENE) UG/KG
NA
3.5
UJ
1.6
u
TOLUEN':
UG/KG
NA
1.9
J
1.6
u
TRANS-1.2-DICHLOROETHENE
UG/KG
NA
3.5
UJ
1.6
u
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
3.5
UJ
1.6
u
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
NA
3.5
UJ
1.6
u
TRICHLOROFLUOROMETHANE
UG/KG
NA
3.5
UJ
1.6
u
VINYL CHLORIDE
UG/KG
NA
3.5
UJ
1.6
u
Note: Sample SD-101, and 104 exceeded recommended holding time before sample receipt.
Note: Sample SD-101R, and 104R results reported on a wet weight basis.
Note: Sample lD-104 exceeded QC limits, results estimated.
Data Qualifiers
SD102DUP
SD103
SD104
SD104
SD104R
SD105
11/13/97
11/13/97
11/13/97
11/16/97
11/19/97
11/13/97
14:10
15:00
15:30
10:02
13:36
15:55
NA
NA
NA
NA
7
UJ
1.6
U
NA
NA
NA
NA
NA
7
UJ
1.6
U
NA
NA
NA
NA
NA
7
UJ
1.6
U
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
18
UJ
4
u
NA
NA
NA
NA
NA
180
UJ
40
u
NA
NA
NA
NA
NA
18
UJ
4
u
NA
NA
NA
NA
NA
35
UJ
8.1
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NR
NR
NR
NR
N
N
NR
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
2.1
J
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA
NA
NA
NA
7
UJ
1.6
u
NA
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-27 (B)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD106
SD107
SD107
SD107R
SD108
SD109
SD1I0
SDI10A
SD110B
SD110BDP
11/14/97
11/14/97
11/16/97
11/19/97
11/14/97
11/15/97
11/15/97
11/19/97
11/19/97
11/19/97
16:02
16:25
10:18
13:37
16:45
08:45
08:00
09:20
09:20
09:20
% MOISTURE
%
47.8
56.5
48.7
49
(M- AND/OR P-)XYLF.NE
Uti/KG
NA
NA
2.9
UJ
1.6
U
NA
NA
NA
3.2
u
3.9
U
3.5
U
1,1,1,2-TETRACHLOROETH ANE
UG/KG
NA
NA
2.9
UJ
1.6
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
1,1,1 -TRICHLOROETHANE
UG/KG
NA
NA
29
UJ
1.6
u
NA
NA
NA
3.2
U
3.9
u
3.5
U
1,1,2,2-TETRACHLOROETHANE
UG/KG
NA
NA
29
UJ
1.6
u
NA
NA
NA
3.2
U
3.9
u
3.5
U
1,1,2-TRICHLOROETH ANE
UG/KG
NA
NA
2 9
UJ
1.6
u
NA
NA
NA
3.2
U
3.9
u
3.5
U
1,1 -DICHLOROETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,1 -DICHI.OROETHENE (1, 1-DICHLOROETH YI.ENE)
UG/KG
NA
NA
2,9
UJ
1.6
u
NA
NA
NA
3,2
u
3.9
u
3.5
U
1,1 -DICHLOROPROPENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3 5
U
1,2,3-TRICHLOROBENZF.NE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,2,3-TRICHLOROPROPANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
1J
3.9
u
3.5
U
1,2,4-TRICHLOROBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,2,4-TRlMETHYLBENZENF.
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1.2-DIBROMO-3-CHLOROPROPAN E (DBCP)
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,2-DlBROMOETHANE (EDB)
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3 5
U
1,2-DICHLOROBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,2-DICHLOROETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,2-DICHLOROPROPANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,3,5-TRlMETHYLBENZENE
UG/KG
NA
NA
2.9
UJ
16
u
NA
NA
NA
3.2
u
3.9
u
3 5
IJ
1,3-DICHLOROBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
U
1,3-DICHLOROPROPANE
UG/KG
NA
NA
2 9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
1,4-D!CHLOROBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
2,2-DICHLOROPROPANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
ACETONE
UG/KG
NA
NA
71
UJ
41
u
NA
NA
NA
84
u
300
u
88
u
BENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
BROMOBENZENE
UG/KG
NA
NA
2.9
UJ
16
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
BROMOCHLOROMETHANE
UG/KG
NA
NA
29
UJ
16
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
BROMODICHLOROM ETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
BROMOFORM
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
BROMOMETHANE
UG/KG
NA
NA
2 9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
CARBON DISULFIDE
UG/KG
NA
NA
7.1
UJ
1.2
J
NA
NA
NA
16
18
13
CARBON TETRACHLORIDE
UG/KG
NA
NA
2.9
UJ
1.6
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
-------
Table 5-27 (B) (Continued)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD106
SD107
SD107
SD107R
11/14/97
11/14/97
11/16/97
11/19/97
16.02
16:25
10:18
13:37
CHLOROBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
U
CHLOROETHANE
UG/KG
NA
NA
2.9
UJ
1.6
U
CHLOROFORM
UG/KG
NA
NA
2.9
UJ
1.6
U
CHLOROMETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
CIS-1.2-D1CHLOROETHENE
UG/KG
NA
NA
2.9
UJ
1.6
u
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
NA
2.9
UJ
1.6
u
DIBROMOCHLOROMETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
D1BROMOMETHANE
UG/KG
NA
NA
2.9
UJ
1.6
u
ETHYL BENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
HEXACHLORO-1.3-BUTADIENE
UG/KG
NA
NA
2.9
UJ
1.6
u
ISOPROPYLBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
METHYL BUTYL KETONE
UG/KG
NA
NA
7.1
UJ
4.1
u
METHYL ETHYL KETONE
UG/KG
NA
NA
71
UJ
41
u
METHYL ISOBUTYL KETONE
UG/KG
NA
NA
7.1
UJ
4.1
u
METHYLENE CHLORIDE
UG/KG
NA
NA
14
UJ
8.2
u
N-BUTYLBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
N-PROPYLBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
O-CHLOROTOLUENE
UG/KG
NA
NA
2.9
UJ
1.6
u
O-XYLENE
UG/KG
NA
NA
2.9
UJ
1.6
u
P-CHLOROTOLUENE
UG/KG
NA
NA
2.9
UJ
1.6
u
P-ISOPROPYLTOLUENE
UG/KG
NA
NA
2.9
UJ
1.6
u
PETROLEUM PRODUCT
UG/KG
NR
NR
NR
N
SEC-BUTYLBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
STYRENE
UG/KG
NA
NA
2.9
UJ
1.6
u
TERT-BUTYLBENZENE
UG/KG
NA
NA
2.9
UJ
1.6
u
TETRACftLOROETHENE (TETRACHLOROETHYLENE) UG/KG
NA
NA
2.9
UJ
1.6
u
TOLUEN'
UG/KG
NA
NA
1.2
J
1.6
u
TRANS- i ,2- JICHLOROETHENE
UG/KG
NA
NA
2.9
UJ
1.6
u
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
NA
2.9
UJ
1.6
u
TR1CHLOROETHENE (TR1CHLOROETHYLENE)
UG/KG
NA
NA
2.9
UJ
1.6
u
TRICHLOROFLUOROMETHANE
UG/KG
NA
NA
0.77
J
1.6
u
VINYL CHLORIDE
UG/KG
NA
NA
2.9
UJ
1.6
u
Note: Sample SD-107 exceeded recommended holding time before sample receipt.
Note: Sample SD-107R results reported on a wet weight basis.
DatfrQu' ¦''¦zia
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD109
SD110
SD110A
SDI10B
SDI 10BDP
11/15/97
11/15/97
11/19/97
11/19/97
11/19/97
08:45
08:00
09:20
09:20
09:20
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
8.1
U
9.7
U
8.8
U
NA
NA
NA
81
U
97
U
88
U
NA
NA
NA
8.1
U
9.7
U
8.8
U
NA
NA
NA
16
U
19
U
18
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
U
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
u
3.9
u
3.5
U
NR
NR
NR
NR
NR
NR
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
U
3.9
u
3.5
U
NA
NA
NA
3.2
u
3.9
u
3.5
u
NA
NA
NA
3.2
u
3.9
u
3.5
u
-------
•/.MOISTURE
(M- AND/OR P-)XYLENE
1,1,1,2-TETRACHLOROETHANE
1,1,1 -TR1CHLOROETHANE
1,1,2,2-TETRACHLOROETH ANE
1.1.2-TRICHLOROETHANE
1,1 -DICHLOROETH ANE
1,1 -DICHLOROETHENE (1,1 -DICHLOROETH
1,1 -DICHLOROPROPENE
1.2.3-TRICHLOROBENZENE
1.2.3-TRICHLOROPROPANE
1.2.4-TRlCHLOROBENZENE
1.2.4-TRIMETHYLBENZENE
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
1,2-DIBROMOETHANE (EDB)
1,2-DICHLOROBENZENE
1,2-DICHLOROETHANE
1.2-DICHLOROPROPANE
1.3.5-TRIMETHYLBENZENE
1.3-DICHLOROBENZENE
1.3-DICHLOROPROPANE
1.4-DICHLOROBENZENE
2,2-DICHLOROPROPANE
ACETONE
BENZENE
BROMOBENZENE
BROMOCHLOROMETHANE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
Table 5-27 (C)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SDlll SD112 SD112DUP SD113
11/15/97 11/15/97 11/15/97 11/15/97
08:25
09:00
09:20
09:35
%
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
UG/KG
NA
NA
NA
NA
3R
SD114
SD115
SDU6
SD116R
SD117
m
11/14/97
11/14/97
11/15/97
11/19/97
11/15/97
:38
12:05
11:30
10:00
11:39
09:47
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
U
NA
NA
NA
1.8
U
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
42
u
NA
NA
NA
45
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
4.2
u
NA
NA
NA
4.5
u
NA
1.7
u
NA
NA
NA
1.8
u
NA
-------
Table 5-27 (C) (Continued)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SDlll SDl 12 SDI12DUP SDl 13
11/15/97 11/15/97 11/15/97 11/15/97
08:25
09:00
09:20
09:35
CHLOROBENZENE
UG/KG
NA
NA
NA
NA
CHLOROETHANE
UG/KG
NA
NA
NA
NA
CHLOROFORM
UG/KG
NA
NA
NA
NA
CHLOROMETHANE
UG/KG
NA
NA
NA
NA
CIS-1,2-DICHLOROETHENE
UG/KG
NA
NA
NA
NA
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
NA
NA
NA
DIBROMOCHLOROMETHANE
UG/KG
NA
NA
NA
NA
DIBROMOMETHANE
UG/KG
NA
NA
NA
NA
ETHYL BENZENE
UG/KG
NA
NA
NA
NA
HEXACHLORO-1.3-BUTADIENE
UG/KG
NA
NA
NA
NA
ISOPROPYLBENZENE
UG/KG
NA
NA
NA
NA
METHYL BUTYL KETONE
UG/KG
NA
NA
NA
NA
METHYL ETHYL KETONE
UG/KG
NA
NA
NA
NA
METHYL ISOBUTYL KETONE
UG/KG
NA
NA
NA
NA
METHYLENE CHLORIDE
UG/KG
NA
NA
NA
NA
N-BUTYLBENZENE
UG/KG
NA
NA
NA
NA
N-PROPYLBENZENE
UG/KG
NA
NA
NA
NA
O-CHLOROTOLUENE
UG/KG
NA
NA
NA
NA
O-XYLENE
UG/KG
NA
NA
NA
NA
P-CHLOROTOLUENE
UG/KG
NA
NA
NA
NA
P-ISOPROPYLTOLUENE
UG/KG
NA
NA
NA
NA
PETROLEUM PRODUCT
UG/KG
NR
NR
NR
NR
SEC-BUTYLBENZENE
UG/KG
NA
NA
NA
NA
STYRENE
UG/KG
NA
NA
NA
NA
TERT-BUTYLBENZENE
UG/KG
NA
NA
NA
NA
TETRACBuOROETHENE (TETRACHLOROETHYLENE) UG/KG
NA
NA
NA
NA
TOLUENE
UG/KG
NA
NA
NA
NA
TRANS-1,2-DICHLOROETHENE
UG/KG
NA
NA
NA
NA
TRANS-I.3-DICHLOROPROPENE
UG/KG
NA
NA
NA
NA
TRICHLOROETHENE(TRICHLOROETHYLENE)
UG/KG
NA
NA
NA
NA
TRICHLOROFLUOROMETHANE
UG/KG
NA
NA
NA
NA
VINYL CHLORIDE
UG/KG
NA
NA
NA
NA
Note: Sample SD-113R and 116R results reported on a wet weight basis.
Data Quajiflffs
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SDII3R SDl 14 SDl 15 SD116 SD116R SD117
11/19/97 11/14/97 11/14/97 11/15/97 11/19/97 11/15/97
11:38 12:05 11:30 10:00 11:39 09:47
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
4.2 U
NA
NA
NA
4.5 U
NA
42 U
NA
NA
NA
45 U
NA
4.2 U
NA
NA
NA
4.5 U
NA
8.5 U
NA
NA
NA
8.9 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
NR
NR
NR
NR
NR
NR
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
1.7 U
NA
NA
NA
1.8 U
NA
-------
Table 5-27 (D)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD118
SD119
SD120
SD120A
SD120B
SD121
SD122
SD122R
SD123
SD123DUP
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
11/19/97
11/15/97
11/15/97
11:10
15:45
14:05
10:00
10:00
13:35
16:00
13:41
13:33
13:35
% MOISTURE
%
80.5
63.4
78.5
66.4
(M- AND/OR P-)XYLENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1,1,2-TETRACHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1,1 -TRICHLOROETH ANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1,2,2-TETRACHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1,2-TRICHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1 -DICHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,1-DICHLOROPROPENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2,3-TRICHLOROBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2,3-TRICHLOROPROPANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.3
J
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2,4-TRIMETHYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2-DIBROMOETHANE (EDB)
UO/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2-DICHLOROBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2-DICHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,2-DICHLOROPROPANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,3,5-TRIMETHYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,3-DICHLOROBENZENE
UG/KG
NA
NA
NA
3.7
J
21
J
NA
NA
1.9
U
8.9
UJ
5
UJ
1,3-DICHLOROPROPANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
1,4-DICHLOROBENZENE
UG/KG
NA
NA
NA
6.5
UJ
2.6
J
NA
NA
1.9
U
3
J
2
)
2,2-DICHLOROPROPANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
ACETONE
UG/KG
NA
NA
NA
280
U
680
u
NA
NA
48
U
220
UJ
120
UJ
BENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
BROMOBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
BROMOCHLOROMETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
BROMODICHLOROM ETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
BROMOFORM
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
BROMOMETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
CARBON DISULFIDE
UG/KG
NA
NA
NA
46
J
55
J
NA
NA
4.8
u
22
UJ
12
UJ
CARBON TETRACHLORIDE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
-------
Table 5-27 (D) (Continued)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD118
SD119
SD120
SD120A
SD120B
SD12I
SD122
SDI22R
SD123
SD123DUP
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
11/19/97
11/15/97
11/15/97
11:10
15:45
14:05
10:00
10:00
13:35
16:00
13:41
13:33
13:35
CHLOROBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
CHLOROETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
CHLOROFORM
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
CHLOROMETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
CIS-1,2-DICHLOROETHENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
DIBROMOCHLOROMETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
D1BROMOM ETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
U
8.9
UJ
5
UJ
ETHYL BENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
HEXACHLORO-1,3-BUTADIENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
ISOPROPYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
METHYL BUTYL KETONE
UG/KG
NA
NA
NA
16
UJ
12
UJ
NA
NA
4.8
u
22
UJ
12
UJ
METHYL ETHYL KETONE
UG/KG
NA
NA
NA
160
UJ
64
UJ
NA
NA
48
u
220
UJ
120
UJ
METHYL ISOBUTYL KETONE
UG/KG
NA
NA
NA
16
UJ
12
UJ
NA
NA
4.8
u
22
UJ
12
UJ
METHYLENE CHLORIDE
UG/KG
NA
NA
NA
32
UJ
25
UJ
NA
NA
9.6
u
45
UJ
25
UJ
N-BUTYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
N-PROPYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
O-CHLOROTOLUENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
O-XYLENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
P-CHLOROTOLUENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
P-ISOPROPYLTOLUENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
PETROLEUM PRODUCT
UG/KG
NR
NR
NR
N
N
NR
NR
N
NR
NR
SEC-BUTYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ .
NA
NA
1.9
u
8.9
UJ
5
UJ
STY RENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TERT-BUTYLBENZENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TETRACBfcOROETHENE (TETRACHLOROETHYLENE) UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TOLUENE
UG/KG
NA
NA
NA
7.7
J
3.5
J
NA
NA
1.9
u
11
J
21
J
TRANS-1.2-DICHLOROETHENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TRICHLOROETHENE(TRICHLOROETHYLENE)
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
TRICHLOROFLUOROMETHANE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
VINYL CHLORIDE
UG/KG
NA
NA
NA
6.5
UJ
4.9
UJ
NA
NA
1.9
u
8.9
UJ
5
UJ
Note: Sample SD-123,123DUP exceeded recommended holding lime before sample receipt.
Note: Sample SD-122R results reported on a wet weight basis.
Note: Satn|IbSF-120A, 120B, 123, and 123DUP results estimated, QC limits exceeded.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
SDI24
11/15/97
14:33
•/. MOISTURE
•/.
73.9
(M- AND/OR P-)XYLENE
UG/KG
6.7
UJ
1,1,1,2-TETRACHLOROETH ANE
UG/KG
6.7
UJ
1,1,1 -TRICHLOROETHANE
UG/KG
6.7
UJ
1,1,2,2-TETRACHLOROETHANE
UG/KG
6.7
UJ
1,1,2-TRICHLOROETHANE
UG/KG
6.7
UJ
1,1 -DICHLOROETHANE
UG/KG
6.7
UJ
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/KG
6.7
UJ
1,1-DICHLOROPROPENE
UG/KG
6.7
UJ
1,2,3-TRICHLOROBENZENE
UG/KG
6.7
UJ
1,2,3-TRlCHLOROPROPANE
UG/KG
6.7
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
6.7
UJ
1,2,4-TRIMETHYLBENZENE
UG/KG
6.7
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
6.7
UJ
1,2-DIBROMOETHANE (EDB)
UG/KG
6.7
UJ
1,2-DICHLOROBENZENE
UG/KG
6.7
w
1,2-DICHLOROETHANE
UG/KG
6.7
UJ
1,2-DICHLOROPROPANE
UG/KG
6.7
UJ
1,3,5-TR1METHYLBENZENE
UG/KG
6.7
UJ
1,3-DICHLOROBENZENE
UG/KG
6.7
UJ
1,3-DICHLOROPROPANE
UG/KG
6.7
UJ
1,4-DICHLOROBENZENE
UG/KG
8.3
J
2,2-DICHLOROPROPANE
UG/KG
6.7
UJ
ACETONE
UG/KG
170
UJ
BENZENE
UG/KG
6.7
UJ
BROMOBENZENE
UG/KG
6.7
UJ
BROMOCHLOROMETHANE
UG/KG
6.7
UJ
BROMODICHLOROMETHANE
UG/KG
6.7
UJ
BROMOFORM
UG/KG
6.7
UJ
BROMOMETHANE
UG/KG
6.7
UJ
CARBON DISULFIDE
UG/KG
17
UJ
CARBON TETRACHLORIDE
UG/KG
6.7
UJ
Table 5-27 (E)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
D125
SDI25R
SD126
SD127
SD128
SD128R
15/97
11/19/97
11/15/97
11/15/97
11/16/97
11/19/97
15:25
13:42
16:00
16:28
09:10
13:43
81.2
83.2
70.2
73.6
8.7
UJ
1.9
U
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
U
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
U
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
U
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
U
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
4.2
J
5.6
J
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
220
UJ
48
u
300
UJ
100
UJ
100
UJ
41
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
22
UJ
4.8
u
30
UJ
10
UJ
10
UJ
4.1
u
8.7
UJ
1.9
u
12
UJ
4.2
UJ
4.2
UJ
1.6
u
-------
Table 5-27 (E)
Sediment Analytical Results - Volatiles
Series 100 Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD124
11/15/97
14:33
SD125
11/15/97
15:25
SD125R
11/19/97
13:42
SD126
11/15/97
16:00
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1.2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
D1BROMOM ETHANE
ETHYL BENZENE
HEXACHLORO-1,3-BUT ADIENE
ISOPROPYLBENZENE
METHYL BUTYL KETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYLENE CHLORIDE
N-BUTYLBENZENE
N-PROPYLBENZENE
O-CHLOROTOLUENE
O-XYLENE
P-CHLOROTOLUENE
P-ISOPROPYLTOLUENE
PETROLEUM PRODUCT
SEC-BUTYLBENZENE
STYRENE
TERT-BUTYLBENZENE
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
TETRAOBXJROETHENE (TETRACHLOROETHYLENE) UG/KG
toluene ug/kg
TRANS-1,2-MCHLOROETHENE UG/KG
TRANS-1,3-DICHLOROPROPENE UG/KG
TRICHLOROETHENE (TRICHLOROETHYLENE) UG/KG
TR1CHLOROFLUOROMETHANE UG/KG
VINYL CHLORIDE UG/KG
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
17 UJ
170 UJ
17 UJ
34 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
NR
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
18 J
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
6.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
22 UJ
220 UJ
22 UJ
44 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
NR
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
6.4 J
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
8.7 UJ
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
4.8 U
48 U
4.8 U
9.6 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
0.57 J
NR
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
1.9 U
0,67 J
1.9 U
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
30 UJ
300 UJ
30 UJ
60 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
NR
12 UJ
12 UJ
12 UJ
12 UJ
17 J
12 UJ
12 UJ
12 UJ
12 UJ
12 UJ
Note: Samples SD-124, 125,126, 127, and 128 exceeded recommended holding time before sample receipt.
Note: Sample SD-125R and 128R results reported on a wet weight basis.
Note: SatuoJe ¦'•-124 results estimated, QC limits exceeded.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD127
11/15/97
16:28
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
10
100
10
21
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
7.7
4.2
4.2
4.2
4.2
4.2
SD128
11/16/97
09:10
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 10
UJ 100
UJ 10
UJ 21
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
NR
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
J 2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
UJ 4.2
SD128R
11/19/97
13:43
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
4.1 U
UJ
41 U
UJ
4.1 U
UJ
8.2 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
NR
N
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
J
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
UJ
1.6 U
-------
% MOISTURE
(M- AND/OR P-)XYLENE
1,1,1,2-TETRACHLOROETH ANE
1,1,1 -TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1.1.2-TRICHLOROETH ANE
1,1-DICHLOROETHANE
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
1.1-D1CHLOROPROPENE
1.2.3-TRICHLOROBENZENE
1.2.3-TRICHLOROPROPANE
1.2.4-TRICHLOROBENZENE
1.2.4-TRIMETHYLBENZENE
1.2-D1BROMO-3-CHLOROPROPANE (DBCP)
1,2-DIBROMOETHANE (EDB)
1,2-DICHLOROBENZENE
1,2-DICHLOROETHANE
1.2-DlCHLOROPROPANE
1.3.5-TRIMETHYLBENZENE
1.3-DlCHLOROBENZENE
1.3-DICHLOROPROPANE
1.4-DlCHLOROBENZENE
2,2-DICHLOROPROPANE
ACETONE
BENZENE
BROMOBENZENE
BROMOCHLOROMETHANE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
Table 5-28 (A)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD202
SD202R
SD203
SD204
11/14/97
M/19/97
11/13/97
11/13/97
11:30
13:20
15:10
16:02
%
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
42
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
3.3
J
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
SD205
SD205R
SD206
SD206DUP
SD207
11/15/97
11/19/97
11/14/97
11/14/97
11/14/97
09:50
13:30
10:05
10:10
12:25
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
180
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
NA
NA
00
J
NA
NA
NA
NA
NA
1.8
UJ
NA
NA
NA
-------
Table 5-28 {&) (^Continued)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
DIBROMOMETHANE
DIMETHYL DISULFIDE
ETHYL BENZENE
HEXACHLORO-1,3-BUTADIENE
ISOPROPYLBENZENE
METHYL BUTYL KETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYLENE CHLORIDE
N-BUTYLBENZENE
N-PROPYLBENZENE
O-CHLOROTOLUENE
O-XYLENE
P-CHLOROTOLUENE
P-ISOPROPYLTOLUENE
PETROLEUM PRODUCT
SEC-BUTYLBENZENE
STYRENE
TERT-BUTYLBENZENE
TETRACHUWOETHENE (TETRACHLOROETHYLENE)
TOLUENE
TRANS-l,2-DfCHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE(TRICHLOROETHYLENE)
TRICHLOROFLUOROMETHANE
VINYL CHLORIDE
SD202
SD202R
SD203
SD204
11/14/97
11/19/97
11/13/97
11/13/97
11:30
13:20
15:10
16:02
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NR
NR
NR
NR
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
4.2
UJ
NA
NA
UG/KG
NA
42
UJ
NA
NA
UG/KG
NA
4.2
UJ
NA
NA
UG/KG
NA
8.4
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NR
N
NR
NR
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
UG/KG
NA
1.7
UJ
NA
NA
Note: Samples SD-202R and 205R reported on a wet-weight basis.
Note: Sample SD-202R results estimated, QC limits exceeded.
Note: Sampte
-------
Table 5-28 (B)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD208
SD208R
SD209
SD209DUP
SD210
SD211
SD2UR
SD211RB
SD212
SD213
11/15/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
15:15
13:45
10:25
10:40
13:20
13:32
13:40
13:45
13:50
13:18
% MOISTURE
%
74.2
(M- AND/OR P-)XYLENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
1,1,1,2-TETRACHLOROETH ANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
1,1,1-TRICHLOROETH ANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,1,2,2-TETRACHLOROETH ANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,1,2-TRICHLOROETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,1-DICHLOROETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,1 -DICHLOROETHENE (1,1 -DICHLOROETH YLENE)
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,1 -DICHLOROPROPENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2,3-TRICHLOROBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2,3-TRICHLOROPROPANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2,4-TRIMETHYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2-DIBROMOETHANE (EDB)
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2-DICHLOROBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2-DICHLOROETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,2-DICHLOROPROPANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,3,5-TRIMETHYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,3-DICHLOROBENZENE
UG/KG
NA
0.91
J
NA
NA
NA
NA
1.9
u
2.7
NA
7.2
UJ
1,3-DICHLOROPROPANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
1,4-DICHLOROBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
0.59
J
NA
7.2
UJ
2,2-DICHLOROPROPANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
ACETONE
UG/KG
NA
43
UJ
NA
NA
NA
NA
70
u
80
U
NA
180
UJ
BENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
BROMOBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
BROMOCHLOROMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
BROMODICHLOROMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
BROMOFORM
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
BROMOMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
CARBON DISULFIDE
UG/KG
NA
11
J
NA
NA
NA
NA
7.3
10
NA
18
UJ
CARBON TETRACHLORIDE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
-------
Table 5-28 (B) (Continued)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD208
SD208R
SD209
SD209DUP
SD2I0
SD21I
SD211R
SD211RB
SD212
SD2I3
! 1/15/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
11/15/97
11/15/97
15:15
13:45
10:25
10:40
13:20
13:32
13:40
13:45
13:50
13:18
CHLOROBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
TJ
NA
7.2
UJ
CHLOROETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
CHLOROFORM
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
CHLOROMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
CIS-1.2-DICHLOROETHENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
DIBROMOCHLOROMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
DIBROMOMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
DIMETHYL DISULFIDE
UG/KG
NR
NR
NR
NR
NR
NR
NR
NR
NR
20
JN
ETHYL BENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
HEXACHLORO-1,3-BUTADlENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
ISOPROPYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
METHYL BUTYL KETONE
UG/KG
NA
4.3
UJ
NA
NA
NA
NA
4.8
U
4.5
U
NA
18
UJ
METHYL ETHYL KETONE
UG/KG
NA
43
UJ
NA
NA
NA
NA
48
U
45
U
NA
180
UJ
METHYL ISOBUTYL KETONE
UG/KG
NA
4.3
UJ
NA
NA
NA
NA
4.8
U
4.5
U
NA
18
UJ
METHYLENE CHLORIDE
UG/KG
NA
8.6
UJ
NA
NA
NA
NA
9.6
U
8.9
U
NA
36
UJ
N-BUTYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
N-PROPYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
O-CHLOROTOLUENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
O-XYLENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
u
NA
7.2
UJ
P-CHLOROTOLUENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
u
NA
7.2
UJ
P-ISOPROPYLTOLUENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
u
NA
7.2
UJ
PETROLEUM PRODUCT
UG/KG
NR
N
NR
NR
NR
NR
N
N
NR
NR
SEC-BUTYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
U
1.8
U
NA
7.2
UJ
STYRENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
TERT-BUTYLBENZENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
U
NA
7.2
UJ
TETRACHBQROETHENE (TETRACHLOROETHYLENE) UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
TOLUENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
34
J
TRANS-1.2-DICHLOROETHENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
TRICHLOROFLUOROMETHANE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
VINYL CHLORIDE
UG/KG
NA
1.7
UJ
NA
NA
NA
NA
1.9
u
1.8
u
NA
7.2
UJ
Note: Samples SD-208R, 211R, and 211 KB reported on a wet-weight basis.
Note: Samples SD-208R, and 213 results estimated, QC limits exceeded.
Note: Samnlfs S^-208R, and 213 exceeded recommended holding time.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-28 (C)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD2I4
SD214R
SD215
SD2I5DUP
11/15/97
11/19/97
11/15/97
11/15/97
13:45
14:21
14:15
14:20
% MOISTURE
%
74.6
72.4
(M- AND/OR P-)XYLENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1,1,2-TETRACHLOROETH ANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1,1-TRICHLOROETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1,2,2-TETRACHLOROETH ANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1,2-TRICHLOROETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1-DICHLOROETHANfi
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1 -DICHLOROETHENE (1, 1-DICHLOROETH YLENE)
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,1 -DICHLOROPROPENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2,3-TRlCHLOROBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2,3-TRICHLOROPROPANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2,4-TRIMETHYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2-DIBROMOETHANE (EDB)
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2-DICHLOROBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2- DICHLOROETH ANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,2-DlCHLOROPROPANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,3,5-TRIMETHYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,3-DICHLOROBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,3-DICHLOROPROPANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
1,4-DICHLOROBENZENE
UG/KG
NA
1.8
U
2.4
J
6.7
UJ
2,2-DICHLOROPROPANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
ACETONE
UG/KG
NA
44
U
180
UJ
170
UJ
BENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
BROMOBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
BROMOCHLOROMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
BROMODICHLOROMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
BROMOFORM
UG/KG
NA
1.8
u
4.7
J
2.3
UJ
BROMOMETHANE
UG/KG
NA
1.8
u
7
UJ
6.7
UJ
CARBON DISULFIDE
UG/KG
NA
1.6
J
4.5
J
17
UJ
CARBON TETRACHLORIDE
UG/KG
NA
1.8
u
7
UJ
6.7
UJ
D216
SD2I7
SD217R
SD2I8
SD2I9
SD220
15/97
11/15/97
11/19/97
11/15/97
11/15/97
11/15/97
14:50
15:19
14:26
15:55
16:20
16:45
75.6
82.5
77
83.4
69.5
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
2.9
J
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
13
J
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
7
J
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
200
UJ
120
UJ
80
UJ
300
UJ
540
UJ
ISO
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2
UJ
20
UJ
15
J
8.1
J
20
J
83
J
15
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2
UJ
-------
Table 5-28 (C) (Continued)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD2I4
SD2I4R
SD215
SD215DUP
SD2I6
SD217
SD217R
SD218
SD219
SD220
11/15/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/15/97
11/15/97
11/15/97
13:45
14:21
14:15
14:20
14:50
15:19
14:26
15:55
16:20
16:45
CHLOROBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
CHLOROETHANE
UG/KG
NA
I.S
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
CHLOROFORM
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
U
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
CHLOROMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
CIS-1.2-DICHLOROETHENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
DIBROMOCHLOROMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
DIBROMOMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
DIMETHYL DISULFIDE
UG/KG
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
ETHYL BENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
HEXACHLORO-I.3-BUTADIENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
ISOPROPYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2 UJ
METHYL BUTYL KETONE
UG/KG
NA
4.4
U
18
UJ
17
UJ
20
UJ
27
UJ
4.7
UJ
20
UJ
28
UJ
15 UJ
METHYL ETHYL KETONE
UG/KG
NA
44
U
180
UJ
170
UJ
200
UJ
270
UJ
47
UJ
200
UJ
280
UJ
150 UJ
METHYL ISOBUTYL KETONE
UG/KG
NA
4.4
U
18
UJ
17
UJ
20
UJ
27
UJ
4.7
UJ
20
UJ
28
UJ
15 UJ
METHYLENE CHLORIDE
UG/KG
NA
8.8
U
35
UJ
33
UJ
39
UJ
54
UJ
9.4
UJ
40
UJ
56
UJ
31 UJ
N-BUTYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
N-PROPYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
O-CHLOROTOLUENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
O-XYLENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
P-CHLOROTOLUENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
P-ISOPROPYLTOLUENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
PETROLEUM PRODUCT
UG/KG
NR
N
N
N
N
N
N
N
N
N
SEC-BUTYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
STYRENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
TERT-BUTYLBENZENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
II
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
TETRACHIHiOETHENE (TETRACHLOROETHYLENE)
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
TOLUENE
UG/KG
NA
1.8
U
18
J
63
J
5.3
J
6.8
J
1.9
UJ
4.7
J
4.7
J
1.8 J
TRANS-1,2-DKHLOROETHENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
TR1CHLOROETHENE (TR1CH LOROETHYLENE)
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
II
UJ
6.2 UJ
TRICHLOROFLUOROMETHANE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
VINYL CHLORIDE
UG/KG
NA
1.8
U
7
UJ
6.7
UJ
7.9
UJ
11
UJ
1.9
UJ
7.9
UJ
11
UJ
6.2 UJ
Note: Samples SD-214R and 217R reported on a wet-weight basis.
Note: Samples SD-215,215DUP, 217,217R, 218, and 219 results estimated, QC limits exceeded.
Note: Sanipte# 15, 215DUP, 216,217, 217R, 218, 219, and 220 exceeded recommended holding time.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
ti-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
% MOISTURE %
(M- AND/OR P-)XYLENE UG/KG
1,1,1,2-TETRACHLOROETH ANE UG/KG
1.1.1-TRICHLOROETHANE UG/KG
1,1,2,2-TETRACHLOROETH ANE UG/KG
1.1.2-TRICHLOROETH ANE UG/KG
1,1 -DICHLOROETHANE UG/KG
1,1 -DICHLOROETHBNE (1,1 -DICHLOROETH YLENE) UG/KG
1.1-D1CHLOROPROPENE UG/KG
1.2.3-TRICHLOROBENZENE UG/KG
1.2.3-TRICHLOROPROPANE UG/KG
1.2.4-TRlCHLOROBENZENE UG/KG
1.2.4-TRlMETHVLBENZENE UG/KG
1.2-DIBROMO-3-CHLOROPROPANE (DBCP) UG/KG
1,2-DlBROMOETHANE (EDB) UG/KG
1,2-DICHLOROBENZENE UG/KG
1,2-DICHLOROETHANE UG/KG
1.2-DlCHLOROPROPANE UG/KG
1.3.5-TRIMETHYLBENZENE UG/KG
1.3-DICHLOROBENZENE UG/KG
1.3-DICHLOROPROPANE UG/KG
1.4-DICHLOROBENZENE UG/KG
2,2-DICHLOROPROPANE UG/KG
ACETONE UG/KG
BENZENE UG/KG
BROMOBENZENE UG/KG
BROMOCHLOROMETHANE UG/KG
BROMODICHLOROMETHANE UG/KG
BROMOFORM UG/KG
BROMOMETHANE UG/KG
CARBON DISULFIDE UG/KG
CARBON TETRACHLORIDE UG/KG
Table 5-28 (D)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
)220R
SD221
SD222
mm
11/16/97
11/16/97
14:22
09:45
10:25
77.3
86.1
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
0.66 J
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
90 UJ
190 UJ
420
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
1.8 UJ
7.7 UJ
13
UJ
7.6 J
19 UJ
12
J
1.8 UJ
7.7 UJ
13
UJ
-------
Table 5-28 (D) (Continued)
Sediment Analytical Results - Volatiles
Series 200 Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD220R
SD221
SD222
11/19/97
11/16/97
11/16/97
14:22
09:45
10:25
CHLOROBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
CHLOROETHANE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
CHLOROFORM
UG/KG
1.8
UJ
7.7
UJ
13
UJ
CHLOROMETHANE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
CIS- 1,2-DICHLOROETHENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
CIS-1,3-DICHLOROPROPENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
DIBROMOCHLOROMETHANE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
DIBROMOMETHANE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
DIMETHYL DISULFIDE
UG/KG
NR
NR
NR
ETHYL BENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
HEXACHLORO-1.3-BUTADIENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
ISOPROPYLBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
METHYL BUTYL KETONE
UG/KG
4.5
UJ
19
UJ
33
UJ
METHYL ETHYL KETONE
UG/KG
45
UJ
190
UJ
330
UJ
METHYL ISOBUTYL KETONE
UG/KG
4.5
UJ
19
UJ
33
UJ
METHYLENE CHLORIDE
UG/KG
8.9
UJ
39
UJ
67
UJ
N-BUTYLBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
N-PROPYLBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
O-CHLOROTOLUENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
O-XYLENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
P-CHLOROTOLUENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
P-ISOPROPYLTOLUENE
UG/KG
1.8
UJ
12
J
13
UJ
PETROLEUM PRODUCT
UG/KG
N
N
N
SEC-BUTYLBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
STYRENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TERT-BUTVLBENZENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TETRACHBBROETHENE (TETRACHLOROETHYLENE)
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TOLUENE
UG/KG
1.8
UJ
19
J
12
J
TRANS-1,2-DKHLOROETHENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TRICHLOROETHENE(TR!CHLOROETHYLENE)
UG/KG
1.8
UJ
7.7
UJ
13
UJ
TRICHLOROFLUOROMETHANE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
VINYL CHLORIDE
UG/KG
1.8
UJ
7.7
UJ
13
UJ
Note: Sample SD-220R reported on a wet-weight basis.
Note: Samples SD-221, and 222 results estimated, QC limits exceeded.
Note: Sainp|££l$220R, 221, and 222 exceeded recommended holding time.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
SD301
11/16/97
10:50
% MOISTURE % 85 9
(M- AND/OR P-)XYLENE UG/KG 14 UJ
1,1,1,2-TETRACHLOROETHANE UG/KG 14 UJ
1,1,1 -TRICHLOROETHANE UG/KG 14 UJ
1,1,2,2-TETRACHLOROETHANE UG/KG 14 UJ
1.1.2-TRICHLOROETHANE UG/KG 14 UJ
1,1 -DICHLOROETHANE UG/KG 14 UJ
1,1 -DICHLOROETHENE (1,1 -DICHLOROETH YLENE) UG/KG 14 UJ
1,1 -DICHLOROPROPENE UG/KG 14 UJ
1.2.3-TRlCHLOROBENZENE UG/KG 14 UJ
1.2.3-TRICHLOROPROPANE UG/KG 14 UJ
1.2.4-TRICHLOROBENZENE UG/KG 14 UJ
1.2.4-TRIMETHYLBENZENE UG/KG 14 UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP) UG/KG 14 UJ
1,2-DIBROMOETHANE (EDB) UG/KG 14 UJ
1,2-DlCHLOROBENZENE UG/KG 14 UJ
1,2-DICHLOROETHANE UG/KG 14 UJ
1.2-DlCHLOROPROPANE UG/KG 14 UJ
1.3.5-TRIMETHYLBENZENE UG/KG 14 UJ
1.3-DICHLOROBENZENE UG/KG 14 UJ
1.3-DICHLOROPROPANE UG/KG 14 UJ
1.4-DICHLOROBENZENE UG/KG 14 UJ
2,2-DlCHLOROPROPANE UG/KG 14 UJ
ACETONE UG/KG 350 UJ
BENZENE UG/KG 14 UJ
BROMOBENZENE UG/KG 14 UJ
BROMOCHLOROMETHANE UG/KG 14 UJ
BROMOD1CHLOROMETHANE UG/KG 14 UJ
BROMOFORM UG/KG 14 UJ
BROMOMETHANE UG/KG 14 UJ
CARBON DISULFIDE UG/KG 35 UJ
CARBON TETRACHLORIDE UG/KG 14 UJ
Table 5-29
Sediment Analytical Results - Volatiles
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD301R
SD302
SD302DUP
SD303
SD304
SD304R
11/19/97
11/16/97
11/16/97
11/16/97
11/16/97
11/19/97
14:37
11:25
11:30
12:00
12:20
14:43
85.4
81
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
150
UJ
330
UJ
260
UJ
NA
NA
100
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
u
1.8
UJ
13
UJ
3.1
J
NA
NA
1.8
u
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
7.6
u
11
J
33
UJ
26
UJ
NA
NA
J
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
-------
Table 5-29 (Continued)
Sediment Analytical Results - Volatiles
Series 300 Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD30I
SD301R
SD302
SD302DUP
SD303
SD304
SD304R
11/16/97
11/19/97
11/16/97
11/16/97
11/16/97
11/16/97
11/19/97
10:50
14:37
11:25
11:30
12:00
12:20
14:43
CHLOROBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
CHLOROETHANE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
CHLOROFORM
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
CHLOROMETHANE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
CIS-1,2-DlCHLOROETHENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
CIS-1,3-DICHLOROPROPENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
U
D1BROMOCHLOROMETHANE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
DIBROMOMETHANE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
ETHYL BENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
HEXACHLORO-1,3-BUTADIENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
ISOPROPYLBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
METHYL BUTYL KETONE
UG/KG
35
UJ
4.5
UJ
33
UJ
26
UJ
NA
NA
4.5
u
METHYL ETHYL KETONE
UG/KG
350
UJ
45
UJ
330
UJ
260
UJ
NA
NA
45
u
METHYL ISOBUTYL KETONE
UG/KG
35
UJ
4.5
UJ
33
UJ
26
UJ
NA
NA
4.5
u
METHYLENE CHLORIDE
UG/KG
70
UJ
9.1
UJ
66
UJ
52
UJ
NA
NA
9.1
u
N-BUTYLBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
N-PROPYLBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
O-CHLOROTOLUENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
O-XYLENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
P-CHLOROTOLUENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
P-ISOPROPYLTOLUENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
PETROLEUM PRODUCT
UG/KG
N
N
N
N
NR
NR
N
SEC-BUTWLBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
STYRENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TERT-BUTYLBENZENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TETRACHLOROETHENE(TETRACHLOROETHYLENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TOLUENE
UG/KG
14
UJ
1.8
UJ
5.5
J
6.7
J
NA
NA
1.8
u
TRANS-1,2-DICHLOROETHENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TRANS-1,3-DICHLOROPROPENE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
TRICHLOROFLUOROMETHANE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
VINYL CHLORIDE
UG/KG
14
UJ
1.8
UJ
13
UJ
10
UJ
NA
NA
1.8
u
Note:- Samples SD-301,301R, 302, 302DUP, and 304 exceeded recommended holding time.
Note: Samples SD-301 R and 304R are reported on a wet weight basis.
Note: Samples SD-301R and 304R results estimated, QC limits exceeded.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-30 (A)
Sediment Analytical Results - Volatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD401
SD401R
SD402
SD403
SD403DUP
SD404
SD404R
SD405
SD406
SD407
11/16/97
11/19/97
11/16/97
11/16/97
11/16/97
11/16/97
11/19/97
11/16/97
11/16/97
11/18/97
12:55
14:49
13:15
13:44
13:50
15:00
14:53
15:20
15:35
09:00
% MOISTURE
%
81.5
(M- AND/OR P-)XYLENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1,1,2-TETRACHLOROETH ANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
l,l(l -TRICHLOROETHANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1,2,2-TETRACHLOROETHANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1,2-TRICHLOROETH ANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1 -DICHLOROETH ANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1-DlCHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,1-DICHLOROPROPENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2,3-TRJCHLOROBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2,3-TRICHLOROPROPANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2,4-TRI METH YLBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2-DIBROMOETHANE (EDB)
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2-DICHLOROBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2-DlCHLOROETHANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,2-DICHLOROPROPANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,3,S-TRIMETH YLBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,3-DICHLOROBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,3-DICHLOROPROPANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
1,4-DlCHLOROBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
13
J
2,2-DICHLOROPROPANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
ACETONE
UG/KG
NA
no
UJ
NA
NA
NA
NA
49
UJ
NA
NA
240
UJ
BENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
BROMOBENZENE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
BROMOCHLOROMETHANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
BROMODICHLOROMETHANE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
BROMOFORM
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
BROMOMETHANE
UG/KG
NA
L8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
CARBON DISULFIDE
UG/KG
NA
6.9
J
NA
NA
NA
NA
4.9
UJ
NA
NA
24
UJ
CARBON TETRACHLORIDE
UG/KG
NA
1.8
UJ
NA
NA
NA
NA
2
UJ
NA
NA
9.7
UJ
-------
Table 5-30 (A) (Continued)
Sediment Analytical Results - Votatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD401
SD40IR
SD402
SD403
11/16/97
11/19/97
11/16/97
11/16/97
12:55
14:49
13:15
13:44
CHLOROBENZENE
UG/KG
NA
1.8 UJ
NA
NA
CHLOROETHANE
UG/KG
NA
1.8 UJ
NA
NA
CHLOROFORM
UG/KG
NA
1.8 UJ
NA
NA
CHLOROMETHANE
UG/KG
NA
1.8 UJ
NA
NA
CIS-1,2-DlCHLOROETHENE
UG/KG
NA
1.8 UJ
NA
NA
CIS-1,3-DICHLOROPROPENE
UG/KG
NA
1.8 UJ
NA
NA
DIBROMOCHLOROMETHANE
UG/KG
NA
1.8 UJ
NA
NA
D1BROMOMETHANE
UG/KG
NA
1.8 UJ
NA
NA
ETHYL BENZENE
UG/KG
NA
1.8 UJ
NA
NA
HEXACHLORO- I,3-BUTADIENE
UG/KG
NA
1.8 UJ
NA
NA
ISOPROPYLBENZENE
UG/KG
NA
1.8 UJ
NA
NA
LIMONENE
UG/KG
NR
NR
NR
NR
MENTHENE
UG/KG
NR
NR
NR
NR
METHYL BUTYL KETONE
UG/KG
NA
4.5 UJ
NA
NA
METHYL ETHYL KETONE
UG/KG
NA
45 UJ
NA
NA
METHYL ISOBUTYL KETONE
UG/KG
NA
4.5 UJ
NA
NA
METHYLENE CHLORIDE
UG/KG
NA
8.9 UJ
NA
NA
N-BUTYLBENZENE
UG/KG
NA
1.8 UJ
NA
NA
N-PROPYLBENZENE
UG/KG
NA
1.8 UJ
NA
NA
O-CHLOROTOLUENE
UG/KG
NA
1.8 UJ
NA
NA
O-XYLENE
UG/KG
NA
1.8 UJ
NA
NA
P-CHLOROTOLUENE
UG/KG
NA
1.8 UJ
NA
NA
P-ISOPROPYLTOLUENE
UG/KG
NA
1.8 UJ
NA
NA
PETROLEUM PRODUCT
UG/KG
NR
N
NR
NR
PINENE
UG/KG
NR
NR
NR
NR
SEC-BUTYLBENZENE
UG/KG
NA
1.8 UJ
NA
NA
STYRENE
UG/KG
NA
1.8 UJ
NA
NA
TERT-BUT VUJENZEN E
UG/KG
NA
1.8 UJ
NA
NA
TETRACHUHDETHENE (TETRACHLOROETHYLENE) UG/KG
NA
1.8 UJ
NA
NA
TOLUENE
UG/KG
NA
1.8 UJ
NA
NA
TRANS-1,2-DICHLOROETHENE
UG/KG
NA
1.8 UJ
NA
NA
TRANS-1,3-DICHLOROPROPENE
UG/KG
NA
1.8 UJ
NA
NA
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
NA
1.8 UJ
NA
NA
TRICHLOROFLUOROMETHANE
UG/KG
NA
1.8 UJ
NA
NA
VINYL CHLORIDE
UG/KG
NA
1.8 UJ
NA
NA
Note: Samples SD-401R, 404R and 407 exceeded recommended holding time.
Note: Samples SD-40IR and 404R reported on a wet weight basis.
Note: Sample£D-404R results estimated, QC limits exceeded.
Data i^uatiiiers
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD404
SD404R
SD405
SD406
SD407
11/16/97
11/19/97
11/16/97
11/16/97
11/18/97
15:00
14:53
15:20
15:35
09:00
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NA
NA
4.9
UJ
NA
NA
24
UJ
NA
NA
49
UJ
NA
NA
240
UJ
NA
NA
4.9
UJ
NA
NA
24
UJ
NA
NA
9.8
UJ
NA
NA
48
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NR
NR
N
NR
NR
N
NR
NR
NR
NR
NR
NR
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
NA
NA
2
UJ
NA
NA
9.7
UJ
-------
% MOISTURE
(M- AND/OR P-)XYLENE
1,1,1,2-TETRACHLOROETH ANE
1,1,1 -TRICHLOROETH ANE
1,1,2,2-TETRACHLOROETH ANE
1.1.2-TRIOMLOROETH ANE
1, l-DICHLOROETHANE
1.1-D1CHLOROETHENE (1,1 -DICHLOROETH YLENE)
1,1 -DICHLOROPROPENE
1.2.3-TRICHLOROBENZENE
1.2.3-TRICHLOROPROPANE
1.2.4-TRJCHLOROBENZENE
1.2.4-TRlMETH YLBENZENE
1.2-DI BROMO-3-CHLOROPROPAN E (DBCP)
1,2-DlBROMOETHANE (EDB)
1,2-DICHLOROBENZENE
1,2-DICHLOROETHANE
1.2-DICHLOROPROPANE
1.3.5-TRlMETHYLBENZENE
1.3-DICHLOROBENZENE
1.3-DICHLOROPROPANE
1.4-DICHLOROBENZENE
2,2-DICHLOROPROPANE
ACETONE
BENZENE
BROMOBENZENE
BROMOCHLOROMETHANE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
Table 5-30 (B)
Sediment Analytical Results - Volatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD408
SD409
SIM 10
SD4II
11/18/97
11/18/97
11/18/97
11/18/97
09:23
09:55
10:20
10:50
%
86.3
70.2
79.5
67.6
UG/KG
14
U
6.5
U
9.6 U
6.1
UJ
UG/KG
14
U
6.5
U
9.6 U
6.1
UJ
UG/KG
14
u
6.5
U
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u-
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14 U
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
32
18
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
420
u
240
u
240 U
320
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
UG/KG
32
J
9.6
J
24 U
41
J
UG/KG
14
u
6.5
u
9.6 U
6.1
UJ
D412
SD4I3
SD414
SD415
SD4I6
SD417
18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11:15
11:45
13:01
13:01
13:20
13:45
80.1
81.7
70.6
64.9
79.3
79.2
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
3.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
240
UJ
260
UJ
190
U
320
U
220
UJ
620
UJ
9.7
UJ
to
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
8.4
J
26
UJ
3.9
J
22
22
UJ
23
J
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
-------
Table 5-30 (B) (Continued)
Sediment Analytical Results - Volatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD408
SD409
SD4I0
SD411
SD412
SD413
SD4I4
SD415
SD4I6
SD4I7
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
09:23
09:55
10:20
10:50
11:15
11:45
13:01
13:01
13:20
13:45
CHLOROBENZENE
UG/KG
14
U
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
CHLOROETHANE
UG/KG
14
u
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
CHLOROFORM
UG/KG
14
u
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
CHLOROMETHANE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
aS-1,2-DICHLOROETHENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
C1S-I.3-DICHLOROPROPENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
DIBROMOCHLOROMETHANE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
u
8.9
UJ
8.4
UJ
DIBROMOMETHANE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
ETHYL BENZENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
HEXACHLORO-1.3-BUTADIENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
ISOPROPYLBENZENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
LIMONENE
UG/KG
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
MENTHENE
UG/KG
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
METHYL BUTYL KETONE
UG/KG
35
U
16
U
24
U
15
UJ
24
UJ
26
UJ
15
u
12
U
22
UJ
21
UJ
METHYL ETHYL KETONE
UG/KG
350
U
160
U
240
U
150
UJ
240
UJ
260
UJ
150
u
120
U
220
UJ
210
UJ
METHYL ISOBUTYL KETONE
UG/KG
35
u
16
u
24
U
15
UJ
24
UJ
26
UJ
15
u
12
U
22
UJ
21
UJ
METHYLENE CHLORIDE
UG/KG
70
u
32
u
48
U
30
UJ
48
UJ
52
UJ
30
U
25
U
45
UJ
42
UJ
N-BUTYLBENZENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
N-PROPYLBENZENE
UG/KG
14
U
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
U
8.9
UJ
8.4
UJ
O-CHLOROTOLUENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
U
8.9
UJ
8.4
UJ
O-XYLENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
U
8.9
UJ
8.4
UJ
P-CHLOROTOLUENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
P-ISOPROPYLTOLUENE
UG/KG
18
26
9.6
u
6.1
UJ
8.3
UJ
10
UJ
3
J
5
U
8.9
UJ
8.4
UJ
PETROLEUM PRODUCT
UG/KG
N
N
N
N
N
N
N
N
N
N
PINENE
UG/KG
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
SEC-BUTYLBENZENE
UG/KG
14
U
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
U
8.9
UJ
8.4
UJ
STYRENE
UG/KG
14
U
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
TERT-BUTYLBENZENE
UG/KG
14
U
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
U
5
U
8.9
UJ
8.4
UJ
TETRACHBIROETHENE (TETRACHLOROETHYLENE) UG/KG
14
U
6.5
U
9.6
U
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
TOLUENE
UG/KG
14
U
2.1
J
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
TRANS-I.2-DKHLOROETHENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
10
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
TRICHLOROFLUOROMETHANE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
to
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
VINYL CHLORIDE
UG/KG
14
u
6.5
u
9.6
u
6.1
UJ
9.7
UJ
to
UJ
6.1
u
5
u
8.9
UJ
8.4
UJ
Note: Samples SD-411, 412,413,416, and 417 exceeded recommended holding time.
Data Qualifiers
NA-N61 analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Material was anaJyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-30 (C)
Sediment Analytical Results - Volatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD417DUP
SD418
SIM 19
SD420
11/18/97
11/18/97
11/18/97
11/18/97
13:50
14:03
14:27
14:47
% MOISTURE
%
79.2
68.1
77.4
61.7
(M- AND/OR P-)XYLENE
UG/KG
8.6
UJ
5.3
Ul
8.7 UJ
4.7 U
1,1,1,2-TETRACHLOROETH ANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
l!l! i-trichloroethane
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1 1 2,2-TETRACHLOROETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
i ; 1 ;2-trichloroethane
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,1-DlCHLOROETHANE
UG/KG
8.6
UJ .
5.3
UJ
8.7 UJ
4.7 U
l,l-DICHLOROETHENE(I,l-DICHLOROETHYLENE)
UG/KG
8.6
u;
5.3
UJ
8.7 UJ
4.7 U
1,1 -DICHLOROPROPENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
i ,2,3-TRICHLOROBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,2,3-TRICHLOROPROPANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,2,4-TRICHLOROBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1.2,4-TRIMETHYLBENZENE
UG/KG
8.6
UJ
S.3
UJ
8.7 UJ
4.7 U
1,2-D1BROMO-3CHLOROPROPANE(DBCP)
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
6-dibromoethane (EDB)
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,2-dichlorobenzene
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,2-DICHLOROETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,2-DICHLOROPROPANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,3,5-TRIMETHYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,3-DlCHLOROBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,3-DtCHLOROPROPANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
1,4-DICHLOROBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
2,2-DlCHLOROPROPANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
ACETONE
UG/KG
860
UJ
130 UJ
220 UJ
120 U
BENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
BROMOBENZENE
UG/KG
8.6
UJ
5.3
w
8.7 UJ
4.7 U
BROMOCHLOROMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
BROMODICHLOROMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
BROMOFORM
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
BROMOMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
CARBON DISULFIDE
UG/KG
48
J
3.5
J
22 UJ
5.2 J
CARBON TETRACHLORIDE
UG/KG
8.6
UJ
5.3
UJ
8.7 UJ
4.7 U
iD42l
SD422
SD423
SD424
SD425
SD503A
SD503B
'18/97
M/18/97
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
15:20
15:47
16:15
09:17
09:25
11:15
11:15
76.8
67.5
74.8
76
8)
59.2
38.7
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
U
4.4
U
3
U
00
in
UJ
5.5
UJ
7.3
UJ
8
U
9.6
U
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
U
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
U
9.6
u
4.4
U
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
U
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
U
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
U
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
U
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
210
UJ
140
UJ
180
UJ
200
u
240
u
400
u
160
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
21
UJ
12
J
7.6
J
23
10
J
29
24
8.5
UJ
5.5
UJ
7.3
UJ
8
u
9.6
u
4.4
u
3
u
-------
Table 5-30 (C) (Continued)
Sediment Analytical Results - Volatiles
Series 400/500 Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD4I7DUP
SD418
SD419
SD420
11/18/97
11/18/97
11/18/97
11/18/97
13:50
14:03
14:27
14:47
CHLOROBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
CHLOROETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
CHLOROFORM
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
CHLOROMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
CIS-1,2-DICHLOROETHENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
CIS-1.3-DICHLOROPROPENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
DIBROMOCHLOROMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
DIBROMOMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
ETHYL BENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
HEXACHLORO-1 ^-BUTADIENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
ISOPROPYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
LIMONENE
UG/KG
40
JN
NR
NR
NR
MENTHENE
UG/KG
NR
NR
200
JN
NR
METHYL BUTYL KETONE
UG/KG
21
UJ
13
UJ
22
UJ
12
U
METHYL ETHYL KETONE
UG/KG
210
UJ
130
UJ
220
UJ
120
U
METHYL ISOBUTYL KETONE
UG/KG
21
UJ
13
UJ
22
UJ
12
U
METHYLENE CHLORIDE
UG/KG
43
UJ
27
UJ
43
UJ
23
U
N-BUTYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
N-PROPYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
O-CHLOROTOLUENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
O-XYLENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
P-CHLOROTOLUENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
U
P-ISOPROPYLTOLUENE
UG/KG
8.6
UJ
8.1
J
34
J
2.4
J
PETROLEUM PRODUCT
UG/KG
N
NR
NR
N
PINENE
UG/KG
NR
NR
NR
NR
SEC-BUTYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
STYRENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TERT-BUTYLBENZENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TETRACH«OROETHENE (TETRACHLOROETHYLENE)
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TOLUENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TRANS-1,2-MCHLOROETHENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TRANS-1,3-DICHLOROPROPENE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
TR1CHLOROFLUOROMETHANE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
VINYL CHLORIDE
UG/KG
8.6
UJ
5.3
UJ
8.7
UJ
4.7
u
Note: Samples SD-4I7DUP, 418,419,421,422, and 423 exceeded recommended holding lime.
Note: Sample SD-4I7DUP results estimated, QC limits exceeded.
Data Qualm
NA-Not analyzed. J-Estimated value.
N-Presuniptive evidence of presence of material.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD421
11/18/97
15:20
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
NR
NR
21 UJ
210 UJ
21 UJ
42 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
130 J
NR
NR
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
8.5 UJ
SD422 SD423
11/18/97 11/18/97
15:47 16:15
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
20 JN
NR
14 UJ 18
140 UJ 180
14 UJ 18
28 UJ 37
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.2 J 7.3
N
20 JN
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
1.8 J 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
5.5 UJ 7.3
SD424
11/19/97
09:17
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
NR
NR
NR
NR
UJ
20 U
UJ
200 U
UJ
20 U
UJ
40 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
2.6 J
N
N
NR
NR
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
UJ
8 U
SD425 SD503A
11/19/97 11/19/97
09:25 11:15
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
NR
NR
24 U II
240 U 110
24 U 1\
48 U 22
9.6 U 2
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
NR
NR
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
9.6 U 4.4
SD503B
11/19/97
11:15
U
3 U
U
3 U
U
3 U
U
3 U
U
3 U
U
3 U
U
3 U
U
3 V
U
3 U
U
3 U
U
3 U
NR
NR
NR
20 JN
U
7.6 U
u
76 U
u
7.6 U
u
15 U
J
3 U
u
3 U
u
3 U
u
3 U
u
3 U
u
42
N
NR
NR
NR
U
3 U
U
3 U
U
3 U
U
3 U
U
0.86 J
U
3 U
u
3 U
u
3 U
u
3 U
u
3 U
-------
Table 5-31 (A)
Sediment Analytical Results - Volatiles
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD601
SD602
SD603
11/18/97
11/18/97
11/18/97
08:45
09:08
09:31
% MOISTURE
%
41
54.8
53.4
(M- AND/OR P-)XYLENE
UG/KG
2.9
U
4.3
U
3.9
U
1,1,1,2-TETRACHLOROETHANE
UG/KG
2.9
U
4.3
U
3.9
U
1,1,1 -TRICHLOROETHANE
UG/KG
2.9
U
4.3
u
3.9
U
1,1,2,2-TETRACHLOROETHANE
UG/KG
2.9
U
4.3
u
3.9
U
1,1,2-TRlCHLOROETHANE
UG/KG
2.9
u
4.3
u
3.9
U
1,1 -DICHLOROETHANE
UG/KG
2.9
u
4.3
u
3.9
u
1,1 -DICHLOROETHENE (1,1 -DICH LOROETH YLENE)
UG/KG
2.9
u
4.3
u
3.9
u
1,1 -DICHLOROPROPENE
UG/KG
2.9
u
4.3
u
3.9
u
1,2,3-TRICHLOROBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
1,2,3-TRlCHLOROPROPANE
UG/KG
2.9
u
4.3
u
3.9
u
1,2,4-TRICHLOROBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
1,2,4-TRIMETHYLBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
1,2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
2.9
u
4.3
u
3.9
u
1,2-DIBROMOETHANE (EDB)
UG/KG
2.9
u
4.3
u
3.9
u
1,2-DICHLOROBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
1,2-DICHLOROETHANE
UG/KG
2.9
u
4.3
u
3.9
u
1,2-DICHLOROPROPANE
UG/KG
2.9
u
4.3
u
3.9
u
1,3,5-TRIMETHYLBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
1,3-DICHLOROBENZENE
UG/KG
2.9
u
7.6
3.9
u
1,3-DICHLOROPROPANE
UG/KG
2.9
u
4.3
u
3.9
u
1,4-DICHLOROBENZENE
UG/KG
2.9
u
1.7
J
3.9
u
2,2-DICHLOROPROPANE
UG/KG
2.9
u
4.3
u
3.9
u
ACETONE
UG/KG
80
u
220
u
98
u
BENZENE
UG/KG
2.9
u
4.3
u
3.9
u
BROMOBENZENE
UG/KG
2.9
u
4.3
u
3.9
u
BROMOCHLOROMETHANE
UG/KG
2.9
u
4.3
u
3.9
u
BROMODICHLOROMETHANE
UG/KG
2.9
u
4.3
u
3.9
u
BROMOFORM
UG/KG
2.9
u
4.3
u
3.9
u
BROMOMETHANE
UG/KG
2.9
u
4.3
u
3.9
u
CARBON DISULFIDE
UG/KG
7.2
u
8.5
J
9.8
u
CARBON TETRACHLORIDE
UG/KG
2.9
u
4.3
u
3.9
u
D604
SD605
SD605DUP
SD606
SD607
SD608
SD609
18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
39:55
10:20
10:25
11:48
13:02
13:26
14:34
62.8
63.2
64.3
67.8
71.9
69.8
68
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
1.1
J
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
110
u
120
u
110
UJ
150
UJ
170
UJ
150
UJ
120
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
11
u
12
u
11
UJ
15
UJ
17
UJ
4.2
J
12
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
-------
Table 5-31 (A) (Continued)
Sediment Analytical Results - Volatiles
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD60I
SD602
SD603
SD604
SD605
SD605DUP
SD606
SD607
SD608
SD609
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
08:45
09:08
09:31
09:55
10:20
10:25
11:48
13:02
13:26
14:34
CHLOROBENZENE
UG/KG
2.9
U
4.3
U
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
CHLOROETHANE
UG/KG
2.9
U
4.3
U
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
CHLOROFORM
UG/KG
2.9
U
4.3
U
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
CHLOROMETHANE
UG/KG
2.9
U
4.3
U
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
CIS-1,2-DICHLOROETHENE
UG/KG
2.9
U
4.3
U
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
CIS-1,3-DICHLOROPROPENE
UG/KG
2.9
U
4.3
U
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
DIBROMOCHLOROMETHANE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
DIBROMOMETHANE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
ETHYL BENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
HEXACHLORO-1,3-BUTADIENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
U
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
ISOPROPYLBENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
METHYL BUTYL KETONE
UG/KG
7.2
U
11
u
9.8
U
11
u
12
U
11
UJ
15
UJ
17
UJ
15
UJ
12
U
METHYL ETHYL KETONE
UG/KG
72
U
110
u
98
U
no
u
120
U
110
UJ
150
UJ
170
UJ
150
UJ
120
U
METHYL ISOBUTYL KETONE
UG/KG
7.2
U
11
u
9.8
U
11
u
12
U
11
UJ
15
UJ
17
UJ
15
UJ
12
U
METHYLENE CHLORIDE
UG/KG
14
U
22
u
20
U
22
u
24
U
23
UJ
30
UJ
35
UJ
31
UJ
24
U
N-BTJTYLBENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
N-PROPYLBENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
O-CHLOROTOLUENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
O-XYLENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
P-CHLOROTOLUENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
P-ISOPROPYLTOLUENE
UG/KG
2.9
U
4.3
u
3.9
u
4.4
u
13
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
PETROLEUM PRODUCT
UG/KG
N
N
NR
NR
NR
NR
NR
NR
N
NR
SEC-BUTYLBENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
STYRENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TERT-BUTYLBENZENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
U
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TETRACIBOROETHENE (TETRACHLOROETHYLENI
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TOLUENE
UG/KG
0.93
J
1.4
J
3.9
U
1.4
J
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TRANS-1.2-MCHLOROETHENE
UG/KG
2.9
U
4.3
u
3.9
U
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TRANS-1,3-DICHLOROPROPENE
UG/KG
2.9
U
4.3
u
3.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
u
TRICHLOROETHENE(TRICHLOROETHYLENE)
UG/KG
2.9
u
4.3
u
3.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
TRICHLOROFLUOROMETHANE
UG/KG
12
2
J
3.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
VINYL CHLORIDE
UG/KG
2.9
u
4.3
u
3.9
u
4.4
u
4.8
u
4.5
UJ
6
UJ
7
UJ
6.1
UJ
4.9
U
Note: Samples SD-605DUP, 606,607, and 608 exceeded recommended holding time.
Data Oualif
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Materia! was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-31 (B)
Sediment Analytical Results - Volatiles
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD6I0
SD701
SD702
SD703
SD703DUP
SD801
SD801DUP
SD802
SD803
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
15:00
16:20
16:22
16:25
16:25
14:10
14:10
14:45
15:16
% MOISTURE
%
70.3
80.8
57.8
72.6
62.6
85
13.7
87.5
(M- AND/OR P-)XYLENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
U
1.8
UJ
15
U
1,1,1,2-TETRACHLOROETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
U
1,1,1-TRICHLOROETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
U
1,1,2,2-TETRACHLOROETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
U
1,1,2-TRlCHLOROETH ANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
II
u
1.8
UJ
15
U
1,1 -DICHLOROETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
U
1,1 -DICHLOROETHENE (1,1 -DICHLOROETH YLENE)
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
U
1,1 -DICHLOROPROPENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
II
u
1.8
UJ
15
U
1,2,3-TRICHLOROBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2,3-TRICHLOROPROPANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2,4-TRICHLOROBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2,4-TRlMETHYLBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2-DIBROMOETHANE (EDB)
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2-DICHLOROBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2-DlCHLOROETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,2-DICHLOROPROPANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,3.5-TRIMETH YLBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,3-DICHLOROBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,3-DICHLOROPROPANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
1,4-DICHLOROBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
2,2-DlCHLOROPROPANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
ACETONE
UG/KG
130 U
240 U
81 U
150
UJ
120 U
NA
270
u
46
UJ
370
u
BENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
BROMOBENZENE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
BROMOCHLOROMETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
BROMODICHLOROMETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
BROMOFORM
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
BROMOMETHANE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
CARBON DISULFIDE
UG/KG
13 U
24 U
8.1 U
15
UJ
12 U
NA
27
u
4.6
UJ
37
u
CARBON TETRACHLORIDE
UG/KG
5.3 U
9.6 U
3.2 U
6.1
UJ
4.7 U
NA
11
u
1.8
UJ
15
u
-------
Table 5-31 (B) (Continued)
Sediment Analytical Results - Volatiles
Series 600/700/800 Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD6I0
SD701
SD702
SD703
SD703DUP
SD801
SD801DUP
SD802
SD803
11/18/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
15:00
16:20
16:22
16:25
16:25
14:10
14:10
14:45
15:16
CHLOROBENZENE
UG/KG
5.3
U
9.6
U
3.2
U
6.1
UJ
4.7
U
NA
11
U
1.8
UJ
15
U
CHLOROETHANE
UG/KG
5.3
U
9.6
U
3.2
U
6.1
UJ
4.7
U
NA
11
u
1.8
UJ
15
U
CHLOROFORM
UG/KG
5.3
U
9.6
u
3.2
U
6.1
UJ
4.7
U
NA
11
u
1.8
UJ
7.9
J
CHLOROMETHANE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
U
NA
11
u
1.8
UJ
15
U
CIS-1,2-DICHLOROETHENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
U
NA
11
u
1.8
UJ
IS
u
CIS-1,3-DICHLOROPROPENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
U
NA
11
u
1.8
UJ
15
u
DIBROMOCHLOROMETHANE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
DIBROMOMETHANE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
ETHYL BENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
HEXACHLORO-1.3-BUTADIENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
ISOPROPYLBENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
METHYL BUTYL KETONE
UG/KG
13
U
24
u
8.1
u
15
UJ
12
u
NA
27
u
4.6
UJ
37
u
METHYL ETHYL KETONE
UG/KG
130
U
240
u
81
u
150
UJ
120
u
NA
270
u
46
UJ
370
u
METHYL ISOBUTYL KETONE
UG/KG
13
U
24
u
8.1
u
15
UJ
12
u
NA
27
u
4.6
UJ
37
u
METHYLENE CHLORIDE
UG/KG
27
U
48
u
16
u
30
UJ
23
u
NA
55
u
9.2
UJ
74
u
N-BUTYLBENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
II
u
1.8
UJ
15
u
N-PROPYLBENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
O-CHLOROTOLUENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
O-XYLENE
UG/KG
5.3
u
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
P-CHLOROTOLUENE
UG/KG
5.3
u
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
P-ISOPROPYLTOLUENE
UG/KG
5.3
u
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
PETROLEUM PRODUCT
UG/KG
NR
N
NR
N
N
NR
NR
NR
NR
SEC-BUTYLBENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
U
STYRENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
U
TERT-BUTYLBENZENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
U
TETRACHLCBOETHENE (TETRACHLOROETHYLENE UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
U
TOLUENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
U
TRANS-1,2-DICHLOROETHENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
1.8
UJ
15
u
TRANS-1,3 -DICHLOROPROPENE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
UJ
15
u
TRICHLOROETHENE(TRICHLOROETHYLENE)
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
UJ
15
u
TRJCHLOROFLUOROMETHANE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
1.8
1.8
UJ
15
u
VINYL CHLORIDE
UG/KG
5.3
U
9.6
u
3.2
u
6.1
UJ
4.7
u
NA
11
u
UJ
15
u
Note: Samples SD-703 and 802 exceeded recommended holding lime.
Note: Sample SD-801 lost during preparation or analysis
Data Qua'—'s
NA-Not analyzed. J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Matcrial was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (A)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD101
SD101
SD102
SD102DUP
SD103
SD104
SD104
Effects
11/13/97
11/16/97
11/13/97
11/13/97
11/13/97
11/13/97
11/16/97
Values
13:35
09:40
14:03
14:10
15:00
15:30
10:02
% MOISTURE
%
52
57
84
84
91
79
77
ALUMINUM
MG/KG
510
650
2800
2500
3200
3400
4400
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
ARSENIC
MG/KG
7.24
1.3
0.59
2
1.9
2.9
2.6
2.3
BARIUM
MG/KG
6.6
8.8
7.1
9.1
8.8
11
16
BERYLLIUM
MG/KG
0.2
U
0.2
u
0.2
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.24
0.2
0.66
1.1
1.5
2.4
1.2
CALCIUM
MG/KG
360000
350000
140000
150000
160000
180000
250000
CHROMIUM
MG/KG
52.3
2.3
2.4
12
13
16
19
15
COBALT
MG/KG
NA
4.7
0.5
U
0.5
U
0.54
0.54
0.5
U
COPPER
MG/KG
18.7
37
12
28
37
53
69
49
IRON
MG/KG
300
710
2700
2800
3300
3400
3800
LEAD
MG/KG
30.2
12
8.9
17
18
26
29
18
MAGNESIUM
MG/KG
3600
2900
8000
8500
11000
6900
7600
MANGANESE
MG/KG
12
11
31
31
33
35
38
MOLYBDENUM
MG/KG
1.2
1.7
5.9
7.5
9.8
8.3
6.3
NICKEL
MG/KG
15.9
1.2
5.2
3.2
3.2
3.7
3.9
3
POTASSIUM
MG/KG
2000
U
2000
u
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.81
0.65
0.5
U
0.5
U
0.5
U
0.5
U
0.55
SILVER
MG/KG
0.733
0.25
0.43
2.7
4.5
6.1
9.6
5.2
SODIUM
MG/KG
12000
12000
40000
43000
61000
28000
26000
STRONTIUM
MG/KG
2000
1800
1200
1200
1400
1500
1900
TELLURIUM
MG/KG
50
U
50
u
50
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
1.2
1.8
5.3
10
14
18
8.6
TITANIUM
MG/KG
3.3
3.6
27
25
32
33
32
TOTAL MERCURY
MG/KG
0.13
0.017
0.031
0.19
0.33
0.37
0.6
0.62
VANADIUM
MG/KG
1.8
1.7
8.6
12
13
12
9.7
YTTRIUM
MG/KG
10
U
10
u
10
U
10
U
10
U
10
u
10
U
ZINC
MG/KG
124
21
12
46
64
87
120
63
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (B)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD105
SD106
SD107
SD107
SDI08
SD109
SD110
Effects
11/13/97
11/14/97
11/14/97
11/16/97
11/14/97
11/15/97
11/15/97
Values
15:55
16:02
16:25
10:18
16:45
08:45
08:00
% MOISTURE
%
67
67
64
54
52
65
66
ALUMINUM
MG/KG
4700
3800
5300
5200
3400
3800
5200
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
0.5
U
0.5
u
ARSENIC
MG/KG
7.24
2.5
1.8
2.7
3.4
1.8
2.4
2.8
BARIUM
MG/KG
14
12
15
13
8.2
9.4
11
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.55
0.6
0.57
0.24
0.052
0.23
0.43
CALCIUM
MG/KG
260000
220000
290000
320000
340000
310000
270000
CHROMIUM
MG/KG
52.3
16
14
18
18
14
15
17
COBALT
MG/KG
0.5
U
0.5
U
0.5
U
0.63
0.5
u
0.5
U
0.5
U
COPPER
MG/KG
18.7
20
22
19
11
2.2
8.5
13
IRON
MG/KG
3500
3300
4100
4200
2300
2700
3600
LEAD
MG/KG
30.2
9.5
10
9.4
160
1.8
5.1
8.4
MAGNESIUM
MG/KG
4700
4600
4500
3200
2400
3300
4100
MANGANESE
MG/KG
36
36
40
36
22
25
37
MOLYBDENUM
MG/KG
2.6
2.8
2.6
2
1.3
2.3
2.6
NICKEL
MG/KG
15.9
2.3
2.3
2.6
3.1
2
1.4
1.9
POTASSIUM
MG/KG
2000
U
2000
u
2000
U
2000
u
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.5
0.5
u
0.5
u
0.6
0.5
U
0.52
0.5
U
SILVER
MG/KG
0.733
5
7.1
8.7
2.9
0.12
1.1
3.1
SODIUM
MG/KG
15000
14000
12000
8900
8500
13000
12000
STRONTIUM
MG/KG
2600
2100
2800
3400
4200
3400
2600
TELLURIUM
MG/KG
50
U
50
u
50
u
50
u
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
u
0.5
u
0.5
u
0.5
U
0.5
u
0.5
U
TIN
MG/KG
5.1
6.4
5.3
30
0.5
U
1.2
1.8
TITANIUM
MG/KG
44
37
48
49
29
34
50
TOTAL MERCURY
MG/KG
0.13
0.21
0.21
0.23
0.13
0.022
0.074
0.058
VANADIUM
MG/KG
8.2
7.1
8.3
8.7
7.2
8.1
8.8
YTTRIUM
MG/KG
10
U
10
u
10
u
10
u
10
U
10
u
10
U
ZINC
MG/KG
124
39
43
50
18
2.7
13
24
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-iyiaterial was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (C)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD110A
SD110B
SD110BDP
SD111
SD112
SD112DUP
SD113
Effects
11/19/97
11/19/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
Values
09:20
09:20
09:20
08:25
09:00
09:20
09:35
% MOISTURE
%
60
53
53
51
60
58
66
ALUMINUM
MG/KG
1700
4200
4600
4500
4500
4700
3400
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
ARSENIC
MG/KG
7.24
3.1
2.2
2.2
2.7
2.8
3.1
3.1
BARIUM
MG/KG
12
9.9
10
9.5
10
10
8.7
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
u
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.24
0.051
0.044
0.07
0.19
0.17
0.28
CALCIUM
MG/KG
320000
340000
330000
330000
320000
320000
280000
CHROMIUM
MG/KG
52.3
18
16
17
16
15
16
14
COBALT
MG/KG
1
U
1
U
1
U
0.5
U
0.5
U
0.51
0.5
U
COPPER
MG/KG
18.7
7.7
2.4
2.6
3.1
7.7
6.3
10
IRON
MG/KG
1400
2800
2900
3000
3100
3300
2500
LEAD
MG/KG
30.2
5.3
2
2.3
2.7
4
3.6
5.4
MAGNESIUM
MG/KG
1000
2600
2600
2600
2800
2600
3000
MANGANESE
MG/KG
34
26
27
26
25
26
23
MOLYBDENUM
MG/KG
1.7
1.1
1.1
0.99
1.4
1.2
3
NICKEL
MG/KG
15.9
2.7
2.2
2.3
1.5
1.7
1.7
6.2
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.59
0.71
0.73
0.59
0.5
U
0.5
U
0.5
U
SILVER
MG/KG
0.733
1.8
0.16
0.12
0.21
2.3
1.9
1.2
SODIUM
MG/KG
1000
U
7900
7600
8600
10000
8700
12000
STRONTIUM
MG/KG
3000
3800
3700
3300
3600
3500
2900
TELLURIUM
MG/KG
120
U
120
U
120
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
0.83
0.5
U
5.7
0.5
U
1.5
1.3
1.9
TITANIUM
MG/KG
50
36
42
47
42
46
34
TOTAL MERCURY MG/KG
0.13
0.068
0.019
0.023
0.027
0.05
0.092
0.058
VANADIUM
MG/KG
9.7
9
9.3
8.2
8.6
8.4
19
YTTRIUM
MG/KG
25
U
25
U
25
U
10
U
10
U
10
U
10
U
ZINC
MG/KG
124
13
3.3
3.4
4.3
12
11
56
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Materia) was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (D)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD114
SD115
SD116
SD117
SD118
SD119
SD120
Effects
11/14/97
11/14/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
Values
12:05
11:30
10:00
09:47
11:10
15:45
14:05
% MOISTURE
%
70
76
64
68
79
80
79
ALUMINUM
MG/KG
4500
4000
2900
4200
5700
3800
3800
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
0.64
0.5
U
0.5
U
ARSENIC
MG/KG
7.24
3.4
3.7
3.4
2.4
5.5
4.1
4.7
BARIUM
MG/KG
9.8
11
6.9
41
82
17
28
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.23
0.48
0.16
1.4
7
1.7
1.9
CALCIUM
MG/KG
320000
270000
310000
300000
240000
260000
270000
CHROMIUM
MG/KG
52.3
16
17
13
19
30
18
20
COBALT
MG/KG
0.51
0.62
0.5
U
0.5
U
0.84
0.67
0.54
COPPER
MG/KG
18.7
9
16
5.7
SO
160
57
75
IRON
MG/KG
3500
3300
3000
3300
4800
3300
3300
LEAD
MG/KG
30.2
4.8
8.2
2.9
18
54
23
24
MAGNESIUM
MG/KG
3100
3300
2900
3600
5000
5500
5600
MANGANESE
MG/KG
27
28
14
30
40
29
32
MOLYBDENUM
MG/KG
2
2.6
3.3
2.3
5.5
4.2
3.4
NICKEL
MG/KG
15.9
1.7
2
1
U
2
5.3
3.3
3.2
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.5
U
0.5
0.5
U
0.5
U
0.5
U
0.57
0.57
SILVER
MG/KG
0.733
1.4
2.5
0.51
31
28
14
28
SODIUM
MG/KG
12000
12000
12000
12000
21000
25000
23000
STRONTIUM
MG/KG
3300
2700
2900
2800
2100
2200
2400
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
1.3
2.9
0.68
15
51
12
22
TITANIUM
MG/KG
44
46
32
39
50
36
38
TOTAL MERCURY
MG/KG
0.13
0.057
0.12
0.074
0.72
1.4
0.66
1.1
VANADIUM
MG/KG
10
10
32
7.4
12
11
11
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
10
U
10
u
ZINC
MG/KG
124
14
32
8.6
92
280
120
140
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (E)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD120A
SD120B
SD121
SD122
SD123
SD123DUP
SD124
Effects
11/19/97
11/19/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
Values
10:00
10:00
13:35
16:00
13:33
13:35
14:33
% MOISTURE
%
86
65
81
85
81
74
81
ALUMINUM
MG/KG
3900
4600
3100
3700
3400
3600
4200
ANTIMONY
MG/KG
2
0.5
U
1.4
0.5
U
0.5
U
0.5
u
0.5
U
0.5
U
ARSENIC
MG/KG
7.24
5.3
6.7
3.3
3.7
3.4
3
4
BARIUM
MG/KG
13
26
10
12
11
15
11
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
u
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
1.6
1.4
0.86
1.3
1
0.75
0.94
CALCIUM
MG/KG
240000
300000
280000
230000
260000
300000
270000
CHROMIUM
MG/KG
52.3
20
26
14
17
15
15
16
COBALT
MG/KG
1
U
1.3
0.5
U
0.5
U
0.5
u
0.5
U
0.5
U
COPPER
MG/KG
18.7
58
88
28
47
37
28
38
IRON
MG/KG
3600
8200
2500
3100
3000
310Q
3400
LEAD
MG/KG
30.2
25
18
17
17
15
12
14
MAGNESIUM
MG/KG
5600
3100
3200
4500
4000
3100
3200
MANGANESE
MG/KG
30
42
25
30
32
26
30
MOLYBDENUM
MG/KG
5.3
7.5
4.5
5.5
5.4
2.1
3.7
NICKEL
MG/KG
15.9
4.8
25
2.1
3.1
2.4
1.4
2.3
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
u
2000
U
2000
U
SELENIUM
MG/KG
0.54
0.6
0.66
0.55
0.59
0.66
0.59
SILVER
MG/KG
0.733
14
23
4.9
5.6
5.1
9.2
7.1
SODIUM
MG/KG
28000
7200
12000
20000
11000
9600
11000
STRONTIUM
MG/KG
2000
3000
2200
1900
2100
2800
2400
TELLURIUM
MG/KG
120
U
120
U
50
u
100
U
50
u
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
u
0.5
u
0.5
U
0.5
U
0.5
U
TIN
MG/KG
11
22
4.7
6.6
6.3
6.4
5.9
TITANIUM
MG/KG
38
45
30
39
32
35
41
TOTAL MERCURY
MG/KG
0.13
0.65
0.86
0.2
0.28
0.22
0.28
0.21
VANADIUM
MG/KG
27
23
28
13
13
8.9
14
YTTRIUM
MG/KG
25
U
25
U
10
U
20
u
10
U
10
U
10
U
ZINC
MG/KG
124
110
100
54
88
74
56
67
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Materiai was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-32 (F)
Sediment Analytical Results - Metals
100 Series Samples - Tidewater Channel
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD125
SD126
SD127
SD128
Effects
11/15/97
11/15/97
11/15/97
11/16/97
Values
15:25
16:00
16:28
09:10
% MOISTURE
%
86
77
73
81
ALUMINUM
MG/KG
3800
4000
3000
2900
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
ARSENIC
MG/KG
7.24
4.4
4.2
4.5
3.2
BARIUM
MG/KG
13
16
9
9
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
1.3
4.5
1.4
1
CALCIUM
MG/KG
230000
250000
270000
250000
CHROMIUM
MG/KG
52.3
17
22
15
13
COBALT
MG/KG
0.52
0.5
U
0.5
U
0.5
U
COPPER
MG/KG
18.7
47
100
41
38
IRON
MG/KG
5100
3600
2800
2700
LEAD
MG/KG
30.2
26
39
16
15
MAGNESIUM
MG/KG
3400
3000
2000
4600
MANGANESE
MG/KG
34
31
22
24
MOLYBDENUM
MG/KG
4.9
4.7
4.2
6.2
NICKEL
MG/KG
15.9
3
3
1.2
2.4
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.6
0.6
0.59
0.64
SILVER
MG/KG
0.733
6.2
16
6.9
4.6
SODIUM
MG/KG
14000
12000
4700
20000
STRONTIUM
MG/KG
1900
2100
2200
1800
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
8
29
10
7.7
TITANIUM
MG/KG
38
37
31
26
TOTAL MERCURY MG/KG
0.13
0.25
1.1
0.34
0.27
VANADIUM
MG/KG
15
12
30
18
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
ZINC
MG/KG
124
100
200
82
79
ZIRCONIUM
MG/KG
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italiciz
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-33 (A)
Sediment Analytical Results - Metals
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD202
SD203
SD204
SD205
SD205
SD206
SD206DUP
Effects
11/14/97
11/13/97
11/13/97
11/14/97
11/15/97
11/14/97
11/14/97
Values
11:30
15:10
16:02
16:20
09:50
10:05
10:10
% MOISTURE
%
74
82
82
82
86
87
85
ALUMINUM
MG/KG
2000
2400
3800
4100
3400
3200
3000
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
ARSENIC
MG/KG
7.24
3.4
3.8
5.8
5.1
4.9
5.4
5.1
BARIUM
MG/KG
U
21
14
20
18
21
20
BERYLLIUM
MG/KG
0.2
U
0.2
u
0.2
U
0.2
u
0.2
U
0.2
u
0.2
u
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.93
2.3
2.6
2.5
2.9
2.6
2.6
CALCIUM
MG/KG
210000
210000
250000
330000
210000
270000
270000
CHROMIUM
MG/KG
52.3
10
14
20
19
19
18
17
COBALT
MG/KG
0.5
U
0.71
0.69
0.8
0.72
0.87
0.88
COPPER
MG/KG
18.7
29
59
75
68
79
71
70
IRON
MG/KG
2100
2700
3700
4200
3400
3300
3200
LEAD
MG/KG
30.2
13
26
29
26
29
28
26
MAGNESIUM
MG/KG
3000
3100
3700
3100
3100
3600
3300
MANGANESE
MG/KG
19
22
30
29
29
28
28
MOLYBDENUM
MG/KG
1.6
1.7
5
2.6
3.6
2.2
2.1
NICKEL
MG/KG
15.9
1
1.9
3
2.9
3.1
2.7
3.9
POTASSIUM
MG/KG
2000
U
2000
u
2000
U
2000
u
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.5
U
0.5
u
0.5
U
0.64
0.5
U
0.62
0.67
SILVER
MG/KG
0.733
5
11
15
16
16
14
14
SODIUM
MG/KG
14000
12000
11000
8000
8400
15000
12000
STRONTIUM
MG/KG
1600
1600
2100
2900
1900
2300
2200
TELLURIUM
MG/KG
50
U
50
u
50
U
50
u
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
u
0.5
U
0.5
u
0.5
U
0.5
U
0.5
U
TIN
MG/KG
6.4
18
24
20
24
19
19
TITANIUM
MG/KG
22
23
36
32
33
30
28
TOTAL MERCURY MG/KG
0.13
0.3
0.59
0.9
0.76
0.73
0.74
0.65
VANADIUM
MG/KG
5.7
7.1
20
11
13
11
10
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
10
U
10
U
ZINC
MG/KG
124
87
130
150
140
160
150
140
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-33 (B)
Sediment Analytical Results - Metals
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD207
SD208
SD209
SD210
SD211
SD211A
SD211B
Effects
11/14/97
11/15/97
11/15/97
11/15/97
11/15/97
11/19/97
11/19/97
Values
12:25
15:15
10:25
13:20
13:32
14:00
14:05
% MOISTURE
%
85
87
85
88
78
80
67
ALUMINUM
MG/KG
3800
4500
2500
4000
4600
4400
4400
ANTIMONY
MG/KG
2
0.5
U
1.3
0.5
U
0.5
U
1.3
1.4
0.7
ARSENIC
MG/KG
7.24
8.2
13
4.6
5.7
14
17
10
BARIUM
MG/KG
18
26
24
23
100
130
65
BERYLLIUM
MG/KG
0.2
u
0.2
U
0.2
u
0.2
u
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
3.8
10
2.3
3.1
9.2
8.5
3.6
CALCIUM
MG/KG
250000
260000
260000
280000
240000
270000
310000
CHROMIUM
MG/KG
52.3
24
37
15
22
41
41
26
COBALT
MG/KG
1.6
1.3
0.83
0.91
1.3
1
U
0.5
U
COPPER
MG/KG
18.7
99
220
58
74
240
300
120
IRON
MG/KG
4400
4800
2900
3800
5100
4800
3800
LEAD
MG/KG
30.2
39
68
23
31
70
79
37
MAGNESIUM
MG/KG
3000
2200
2400
2300
2600
2200
2100
MANGANESE
MG/KG
31
38
26
40
42
39
35
MOLYBDENUM
MG/KG
3.5
3.7
2.1
3.7
5
3.5
1.9
NICKEL
MG/KG
15.9
3.9
7.4
1.9
4.2
8.2
8.4
2.7
POTASSIUM
MG/KG
2000
u
2000
U
2000
U
2000
u
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.56
0.7
0.5
U
0.68
0.77
0.63
0.6
SILVER
MG/KG
0.733
20
49
15
19
48
74
64
SODIUM
MG/KG
9100
4600
6000
3000
2600
2300
1900
STRONTIUM
MG/KG
2200
2600
2000
2400
2400
2700
3300
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
50
U
120
U
120
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
33
76
18
22
87
73
43
TITANIUM
MG/KG
34
40
25
37
43
31
45
TOTAL MERCURV
MG/KG
0.13
1.2
3.4
0.55
0.86
3.4
12
3.2
VANADIUM
MG/KG
20
19
8.8
12
17
15
9.4
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
25
U
25
U
ZINC
MG/KG
124
200
410
130
150
430
590
260
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimatcd value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-33 (C)
Sediment Analytical Results - Metals
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD212
SD213
SD214
SD215
SD215DUP
SD216
SD217
Effects
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
11/15/97
Values
13:50
13:18
13:45
14:15
14:20
14:50
15:19
% MOISTURE
%
77
81
87
80
82
81
88
ALUMINUM
MG/KG
3800
3200
4100
3400
3300
2700
4500
ANTIMONY
MG/KG
2
0.54
0.51
2.1
0.91
0.93
0.57
1.5
ARSENIC
MG/KG
7.24
6
5.9
8.9
9.5
9.5
6.5
18
BARIUM
MG/KG
25
20
31
32
31
20
22
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
3.6
2.8
7
5.5
5.8
3.3
10
CALCIUM
MG/KG
290000
280000
260000
290000
290000
290000
230000
CHROMIUM
MG/KG
52.3
24
20
32
28
28
20
42
COBALT
MG/KG
0.96
0.74
1.1
0.96
0.97
0.79
1.5
COPPER
MG/KG
18.7
94
77
140
140
150
86
240
IRON
MG/KG
3700
3200
4400
3700
3700
3500
6000
LEAD
MG/KG
30.2
36
28
70
46
49
31
74
MAGNESIUM
MG/KG
2000
1800
1800
1800
1700
1700
1800
MANGANESE
MG/KG
37
30
32
30
30
26
31
MOLYBDENUM
MG/KG
2
2.7
3.3
2.5
2.5
2
6.6
NICKEL
MG/KG
15.9
4
3.3
5.5
5.3
5.1
3.5
8.3
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.59
0.69
0.64
0.67
0.74
0.71
0.69
SILVER
MG/KG
0.733
40
17
34
37
37
20
47
SODIUM
MG/KG
1600
2400
1600
1400
1700
1400
1300
STRONTIUM
MG/KG
2900
2500
2400
3000
2800
2600
2200
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
35
23
53
54
54
31
92
TITANIUM
MG/KG
38
32
32
33
31
25
34
TOTAL MERCURY MG/KG
0.13
1.3
0.89
1.8
2.2
2.1
1.1
3.5
VANADIUM
MG/KG
9.4
17
13
12
12
11
28
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
10
U
10
U
ZINC
MG/KG
124
180
150
270
270
280
200
470
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-33 (D)
Sediment Analytical Results - Metals
200 Series Samples - Downstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD218
SD219
SD220
SD221
SD222
Effects
11/15/97
11/15/97
11/15/97
11/16/97
11/16/97
Values
15:55
16:20
16:45
09:45
10:25
% MOISTURE
%
79
87
78
84
93
ALUMINUM
MG/KG
3100
4700
3200
3100
5300
ANTIMONY
MG/KG
2
0.71
1.7
0.52
0.67
2.2
ARSENIC
MG/KG
7.24
8
15
6.6
7.8
50
BARIUM
MG/KG
22
87
32
88
54
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
4.4
11
3.4
3.8
13
CALCIUM
MG/KG
280000
200000
310000
310000
240000
CHROMIUM
MG/KG
52.3
23
42
23
23
54
COBALT
MG/KG
0.73
1.4
1.1
1.1
2.1
COPPER
MG/KG
18.7
no
240
no
130
270
IRON
MG/KG
3600
5600
3500
3600
8600
LEAD
MG/KG
30.2
44
84
36
39
100
MAGNESIUM
MG/KG
1300
2100
1600
1700
1800
MANGANESE
MG/KG
23
30
34
28
34
MOLYBDENUM
MG/KG
2.8
3.7
1.3
2.1
7.6
NICKEL
MG/KG
15.9
3.6
8.8
9.7
3.1
9.1
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.68
0.89
0.67
0.73
0.5
U
SILVER
MG/KG
0.733
26
41
64
33
56
SODIUM
MG/KG
1400
2000
1500
1600
1700
STRONTIUM
MG/KG
2200
1900
3300
2800
1900
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
41
88
44
45
100
TITANIUM
MG/KG
24
32
35
29
27
TOTAL MERCURY MG/KG
0.13
1.1
3
1.9
2
3.6
VANADIUM
MG/KG
12
15
6.9
8.3
16
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
ZINC
MG/KG
124
220
470
200
220
480
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Materiai was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-34 (A)
Sediment Analytical Results - Metals
300 Series Samples - Bridge Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD301
SD302
SD302DUP
SD303
Effects
U/16/97
11/16/97
11/16/97
11/16/97
Values
10:50
11:25
11:30
12:00
% MOISTURE
%
89
84
84
88
ALUMINUM
MG/KG
4800
3700
4200
3300
ANTIMONY
MG/KG
2
2
1.9
1.6
1.3
ARSENIC
MG/KG
7.24
22
15
13
12
BARIUM
MG/KG
160
140
130
25
BERYLLIUM
MG/KG
0.2 U
0.2 U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
16
14
12
5.9
CALCIUM
MG/KG
270000
280000
280000
240000
CHROMIUM
MG/KG
52.3
42
44
43
23
COBALT
MG/KG
1.7
1.5
1.4
1.7
COPPER
MG/KG
18.7
270
260
220
120
IRON
MG/KG
6600
5000
4900
5200
LEAD
MG/KG
30.2
110
81
73
50
MAGNESIUM
MG/KG
1700
2000
2100
1700
MANGANESE
MG/KG
31
31
33
25
MOLYBDENUM
MG/KG
5.3
5.1
4.6
4
NICKEL
MG/KG
15.9
8.6
6.8
6.3
4.6
POTASSIUM
MG/KG
2000 U
2000 U
2000
U
2000
U
SELENIUM
MG/KG
0.5 U
0.5 U
0.5
U
0.5
U
SILVER
MG/KG
0.733
49
60
63
27
SODIUM
MG/KG
1700
3200
3300
1000
U
STRONTIUM
MG/KG
2100
2400
2700
1900
TELLURIUM
MG/KG
50 U
50 U
50
U
50
U
THALLIUM
MG/KG
0.5 U
0.5 U
0.5
U
0.5
U
TIN
MG/KG
110
100
94
58
TITANIUM
MG/KG
31
38
42
25
TOTAL MERCUfO MG/KG
0.13
2.2
3.3
3.3
1.8
VANADIUM
MG/KG
12
12
12
17
YTTRIUM
MG/KG
10 U
10 U
10
U
10
U
ZINC
MG/KG
124
550
470
420
270
ZIRCONIUM
MG/KG
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are ii
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
SD304
U/16/97
12:20
88
4900
2.4
39
30
0.2 U
NA
13
220000
49
2
270
12000
93
1800
38
10
11
2000 U
0.55
92
1300
2100
50 U
0.5
130
33
4.6
20
10 U
560
NA
-------
Table 5-35 (A)
Sediment Analytical Results - Metals
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD401
SD402
SD403
SD403DUP
SD404
SD405
SD406
Effects
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
11/16/97
Values
12:55
13:15
13:44
13:50
15:00
15:20
15:35
% MOISTURE
%
78
77
76
74
90
85
84
ALUMINUM
MG/KG
4000
2400
3200
3400
3400
4100
3200
ANTIMONY
MG/KG
2
1.8
1.4
1.3
1.2
1.6
2.1
2.9
ARSENIC
MG/KG
7.24
19
14
6.7
7
11
17
15
BARIUM
MG/KG
36
27
20
U
21
24
27
29
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
u
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
6.5
4.2
2.3
2.5
6.4
6.6
7
CALCIUM
MG/KG
300000
310000
290000
320000
250000
260000
270000
CHROMIUM
MG/KG
52.3
33
20
18
19
27
32
35
COBALT
MG/KG
1.9
1.5
1.6
1.7
2.4
2.5
4.4
COPPER
MG/KG
18.7
210
120
54
56
140
170
220
IRON
MG/KG
4400
3100
3400
3400
4400
4500
4100
LEAD
MG/KG
30.2
64
37
22
25
47
55
69
MAGNESIUM
MG/KG
1400
1200
1300
1400
1600
1500
1400
MANGANESE
MG/KG
35
23
24
26
27
30
29
MOLYBDENUM
MG/KG
5.2
3.8
2.2
2.3
5
6.3
7.7
NICKEL
MG/KG
15.9
5.5
2.8
2.4
2.4
4.3
5.3
5.8
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
u
SELENIUM
MG/KG
0.8
0.71
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
SILVER
MG/KG
0.733
110
50
24
26
31
43
76
SODIUM
MG/KG
1100
1100
1000
U
1000
U
1100
1000
U
1000
U
STRONTIUM
MG/KG
3100
2400
2600
3000
2200
2400
2300
TELLURIUM
MG/KG
50
U
50
U
50
U
50
U
50
U
50
U
50
U
THALLIUM
MG/KG
0.5
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
0.51
TIN
MG/KG
97
50
29
24
54
67
96
TITANIUM
MG/KG
40
24
28
31
31
36
32
TOTAL MERCURV
MG/KG
0.13
4.6
1.9
1.1
0.9
0.97
2.3
3.6
VANADIUM
MG/KG
17
12
14
16
20
22
31
YTTRIUM
MG/KG
10
U
10
U
10
U
10
U
10
U
10
u
10
U
ZINC
MG/KG
124
390
230
110
120
270
300
390
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-35 (B)
Sediment Analytical Results - Metals
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD407
SD408
SD409
SD410
SD411
SD412
SD413
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
Values
09:00
09:23
09:55
10:20
10:50
11:15
11:45
% MOISTURE
%
90
88
75
88
73
85
89
ALUMINUM
MG/KG
4800
4000
3400
2900
3400
3900
3500
ANTIMONY
MG/KG
2
2.4
3.1
1.1
1.5
1.3
3
2.5
ARSENIC
MG/KG
7.24
18
24
13
9.4
14
20
15
BARIUM
MG/KG
37
29
22
21
20
26
25
BERYLLIUM
MG/KG
0.2 U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
15
15
3.4
2.9
3.6
10
11
CALCIUM
MG/KG
250000
240000
300000
290000
310000
250000
240000
CHROMIUM
MG/KG
52.3
44
44
24
18
25
43
35
COBALT
MG/KG
3.3
3.8
3.3
2.9
2.9
5.4
4.9
COPPER
MG/KG
18.7
240
290
110
78
130
300
210
IRON
MG/KG
5000
5000
3400
3400
3400
5800
4500
LEAD
MG/KG
30.2
100
110
44
40
52
120
88
MAGNESIUM
MG/KG
1400
1200
1300
1200
1200
1200
1200
MANGANESE
MG/KG
32
26
30
26
31
28
24
MOLYBDENUM
MG/KG
6.8
8.5
3.2
3
3.6
6.7
6
NICKEL
MG/KG
15.9
6.4
6.4
2.5
1.7
2.5
7.8
4.8
POTASSIUM
MG/KG
2000 U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.67
0.78
0.64
0.7
0.74
0.83
0.67
SILVER
MG/KG
0.733
39
47
56
17
89
72
42
SODIUM
MG/KG
1000 u
1200
1000
1000
U
1000
U
1000
U
1000
U
STRONTIUM
MG/KG
1900
1800
3000
2100
3300
2300
2000
TELLURIUM
MG/KG
120 U
120
U
100
U
120
U
120
U
120
U
120
U
THALLIUM
MG/KG
0.69
0.6
0.5
U
0.55
0.5
U
0.86
0.75
TIN
MG/KG
68
62
34
22
52
89
58
TITANIUM
MG/KG
22
14
33
28
37
26
19
TOTAL MERCURV MG/KG
0.13
3.3
3.9
2.2
1.6
3.6
5
2.7
VANADIUM
MG/KG
21
29
27
22
24
71
39
YTTRIUM
MG/KG
25 U
25
U
20
U
25
U
25
U
25
U
25
U
ZINC
MG/KG
124
510
570
190
160
270
570
460
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Materjal was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-35 (C)
Sediment Analytical Results - Metals
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD414
SD415
SD416
SD417
SD417DUP
SD418
SD419
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
Values
13:01
13:01
13:20
13:45
13:50
14:03
14:27
% MOISTURE
%
77
68
86
82
82
72
84
ALUMINUM
MG/KG
2900
3600
4400
3200
3300
3100
3000
ANTIMONY
MG/KG
2
0.86
1
2.1
2.2
2.3
1.2
1.5
ARSENIC
MG/KG
7.24
6.7
8.3
15
18
17
9.4
11
BARIUM
MG/KG
29
27
33
27
26
28
20
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
3.6
3.5
12
10
10
3.8
3.5
CALCIUM
MG/KG
300000
320000
250000
270000
260000
310000
270000
CHROMIUM
MG/KG
52.3
21
24
38
45
45
24
22
COBALT
MG/KG
2.2
1.7
2.8
2.6
2.7
1.5
2.7
COPPER
MG/KG
18.7
110
130
230
360
360
140
110
IRON
MG/KG
3000
5800
4600
4600
4600
3100
3700
LEAD
MG/KG
30.2
54
60
99
120
110
58
50
MAGNESIUM
MG/KG
1000
1200
1400
1200
1200
1100
1100
MANGANESE
MG/KG
24
33
28
29
29
30
25
MOLYBDENUM
MG/KG
1.8
2.4
5
5
5.1
2.7
3.9
NICKEL
MG/KG
15.9
1.7
1.8
4.7
6
5.9
2
2.4
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.7
0.62
0.67
0.68
0.79
0.66
0.72
SILVER
MG/KG
0.733
47
68
36
24
90
82
48
SODIUM
MG/KG
1000
U
1000
1000
U
1100
1100
1200
1000
U
STRONTIUM
MG/KG
2600
3500
2200
2500
2400
3000
2500
TELLURIUM
MG/KG
100
U
120
U
120
U
120
U
120
U
120
U
120
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.56
0.59
0.6
0.5
U
0.54
TIN
MG/KG
36
60
30
69
110
54
34
TITANIUM
MG/KG
29
32
9.7
13
26
31
30
TOTAL MERCURY
MG/KG
0.13
2.1
2.9
2.9
6.9
6.4
3.9
1.7
VANADIUM
MG/KG
18
11
21
21
22
12
21
YTTRIUM
MG/KG
20
U
25
U
25
U
25
U
25
U
25
U
25
U
ZINC
MG/KG
124
190
300
450
670
660
300
260
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-35 (D)
Sediment Analytical Results - Metals
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD420
SD421
SD422
SD423
SD424
SD425
SD503A
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/19/97
11/19/97
11/19/97
Values
14:47
15:20
15:47
16:15
09:17
09:25
11:15
% MOISTURE
%
64
79
77
82
79
90
78
ALUMINUM
MG/KG
3300
2500
2500
2000
2100
1800
1200
ANTIMONY
MG/KG
2
0.88
0.92
0.62
0.71
1.1
0.79
0.5
U
ARSENIC
MG/KG
7.24
7.8
7.1
4.1
5.8
12
7.9
2.5
BARIUM
MG/KG
21
20
24
24
17
19
21
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
3.1
2.4
1.9
1.1
2.3
0.88
0.99
CALCIUM
MG/KG
320000
300000
320000
330000
290000
280000
320000
CHROMIUM
MG/KG
52.3
26
17
17
15
14
12
12
COBALT
MG/KG
1.4
1.6
1.3
1.3
0.5
U
0.5
U
0.5
U
COPPER
MG/KG
18.7
110
88
68
47
65
38
33
IRON
MG/KG
3000
3300
2800
2800
3100
2700
2400
LEAD
MG/KG
30.2
48
32
28
62
28
22
46
A
MAGNESIUM
MG/KG
1100
1200
1200
1200
980
1100
840
MANGANESE
MG/KG
31
22
24
20
19
20
20
MOLYBDENUM
MG/KG
2
2.4
1.3
1.7
3
2.2
0.59
NICKEL
MG/KG
15.9
1.5
2
1
U
1.3
1
U
1
U
2
U
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
u
SELENIUM
MG/KG
0.68
0.91
0.81
0.93
0.64
0.74
0.74
SILVER
MG/KG
0.733
42
22
45
24
12
3.9
5.4
SODIUM
MG/KG
1000
U
1000
U
1000
U
1000
U
1000
U
1000
U
1200
STRONTIUM
MG/KG
3300
2300
3000
2400
2100
2000
1900
TELLURIUM
MG/KG
120
U
120
U
120
U
120
U
120
U
120
U
100
u
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
TIN
MG/KG
37
28
30
15
17
5.5
6.2
TITANIUM
MG/KG
26
22
24
18
17
17
12
TOTAL MERCURY MG/KG
0.13
2.2
1.4
1.6
0.62
0.68
0.35
0.42
VANADIUM
MG/KG
13
21
12
15
13
12
3.5
YTTRIUM
MG/KG
25
U
25
U
25
u
25
U
25
U
25
U
20
u
ZINC
MG/KG
124
250
180
140
120
160
120
100
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-35 (E)
Sediment Analytical Results - Metals
400/500 Series Samples - Upstream Reach
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD503B
Effects 11/19/97
Values 11:15
% MOISTURE
%
45
ALUMINUM
MG/KG
3600
ANTIMONY
MG/KG
2
0.5
U
ARSENIC
MG/KG
7.24
4.2
BARIUM
MG/KG
17
BERYLLIUM
MG/KG
0.2
U
BORON
MG/KG
NA
CADMIUM
MG/KG
0.676
0.088
CALCIUM
MG/KG
340000
CHROMIUM
MG/KG
52.3
13
COBALT
MG/KG
0.5
U
COPPER
MG/KG
18.7
8.9
IRON
MG/KG
2300
LEAD
MG/KG
30.2
7
MAGNESIUM
MG/KG
1200
MANGANESE
MG/KG
28
MOLYBDENUM
MG/KG
0.33
NICKEL
MG/KG
15.9
1
U
POTASSIUM
MG/KG
2000
U
SELENIUM
MG/KG
0.71
SILVER
MG/KG
0.733
0.26
SODIUM
MG/KG
1100
STRONTIUM
MG/KG
4000
TELLURIUM
MG/KG
120
U
THALLIUM
MG/KG
0.5
U
TIN
MG/KG
0.83
TITANIUM
MG/KG
41
TOTAL MERCUR>
MG/KG
0.13
0.095
VANADIUM
MG/KG
8
YTTRIUM
MG/KG
25
U
ZINC
MG/KG
124
9.8
ZIRCONIUM
MG/KG
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are i
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-36 (A)
Sediment Analytical Results - Metals
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD601
SD602
SD603
SD604
SD605
SD605DUP
SD606
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
11/18/97
Values
08:45
09:08
09:31
09:55
10:20
10:25
11:48
% MOISTURE
%
52
57
65
65
74
76
82
ALUMINUM
MG/KG
3400
3100
2500
2400
2000
2200
1900
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.5
0.5
U
0.5
U
0.6
ARSENIC
MG/KG
7.24
3.9
6.3
4
5.6
3.1
3.6
5.8
BARIUM
MG/KG
14
22
19
18
15
15
16
BERYLLIUM
MQ/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
0.18
0.56
0.89
1
0.47
0.64
1.3
CALCIUM
MG/KG
360000
340000
350000
340000
340000
340000
320000
CHROMIUM
MG/KG
52.3
14
14
13
13
10
11
13
COBALT
MG/KG
0.69
0.66
0.58
0.57
0.5
U
0.5
U
0.7
COPPER
MG/KG
18.7
8.3
20
23
33
14
19
34
IRON
MG/KG
2500
2400
2000
1900
1500
1600
2100
LEAD
MG/KG
30.2
4.5
7.7
8.8
11
5.9
7.3
16
MAGNESIUM
MG/KG
1200
1100
1300
1200
1200
1200
1000
MANGANESE
MG/KG
24
24
20
24
21
20
16
MOLYBDENUM
MG/KG
0.5
U
0.56
0.58
0.62
0.55
0.64
0.86
NICKEL
MG/KG
15.9
1
U
1
U
1
U
1
1
U
1
U
0.74
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.97
0.95
0.9
0.79
0.82
0.86
0.73
SILVER
MG/KG
0.733
1.4
5.9
4.6
11
2.5
3.4
5.7
SODIUM
MG/KG
1000
U
1200
1000
1000
U
1000
U
1000
U
1000
U
STRONTIUM
MG/KG
4200
4000
4200
3600
3700
3700
3800
TELLURIUM
MG/KG
120
U
120
U
100
U
120
U
120
U
120
U
120
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
1.6
6
6.7
9.4
3.1
4.4
8.6
TITANIUM
MG/KG
35
30
22
22
18
20
15
TOTAL MERCURY MG/KG
0.13
0.11
0.38
0.39
0.43
0.19
0.31
0.46
VANADIUM
MG/KG
9.7
8.4
6.6
5
5.4
5.5
11
YTTRIUM
MG/KG
25
U
25
U
20
U
25
U
25
U
25
U
25
U
ZINC
MG/KG
124
14
34
43
64
32
43
83
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-36 (B)
Sediment Analytical Results - Metals
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD607
SD608
SD609
SD610
SD701
SD702
SD703
Effects
11/18/97
11/18/97
11/18/97
11/18/97
11/19/97
11/19/97
11/19/97
Values
13:02
13:26
14:34
15.00
16:20
16:22
16:25
% MOISTURE
%
78
81
77
79
83
80
76
ALUMINUM
MG/KG
1800
2000
1700
1700
3400
5400
3200
ANTIMONY
MG/KG
2
0.5
U
0.51
0.54
0.73
0.58
0.53
0.5
u
ARSENIC
MG/KG
7.24
3.5
4.3
3.9
4
8.4
7.4
8.1
BARIUM
MG/KG
17
17
16
17
16
18
14
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
1.2
1.8
0.84
1.3
0.86
0.87
0.81
CALCIUM
MG/KG
330000
360000
330000
320000
280000
280000
260000
CHROMIUM
MG/KG
52.3
12
13
11
12
16
27
18
COBALT
MG/KG
0.51
0.6
1
U
1
U
0.5
U
0.5
U
0.5
U
COPPER
MG/KG
18.7
36
44
21
32
22
21
17
IRON
MG/KG
1600
2000
1200
1400
2400
2400
1800
LEAD
MG/KG
30.2
13
16
9.7
12
21
21
19
MAGNESIUM
MG/KG
1200
1200
1100
1000
1100
1200
990
MANGANESE
MG/KG
18
18
18
19
26
23
22
MOLYBDENUM
MG/KG
0.6
1.1
0.87
1.1
1
1.3
0.88
NICKEL
MG/KG
15.9
1
U
1
U
1
1
U
1.8
4.2
2.1
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.74
0.77
0.75
0.69
0.75
0.7
0,71
SILVER
MG/KG
0.733
9.7
8.2
4.6
7.1
2.4
2.3
2.7
SODIUM
MG/KG
1000
U
1000
U
1000
U
1000
U
1000
U
1000
u
1000
U
STRONTIUM
MG/KG
3100
3700
3300
3000
2600
2600
2400
TELLURIUM
MG/KG
120
U
120
U
120
U
120
U
120
U
120
u
120
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
0.5
U
TIN
MG/KG
9
12
4.5
8.1
1.1
2.2
2.1
TITANIUM
MG/KG
15
15
16
15
22
27
21
TOTAL MERCURY MG/KG
0.13
0.61
0.53
0.23
0.38
0.22
0.19
0.1S
VANADIUM
MG/KG
4
8.2
7.3
11
10
14
9.2
YTTRIUM
MG/KG
25
U
25
U
25
U
25
U
25
U
25
u
25
U
ZINC
MG/KG
124
75
90
52
71
170
120
100
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. ./-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-36 (C)
Sediment Analytical Results - Metals
600/700/800 Series Samples - Reservoir and Boundary Canal
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS SD703DUP
SD801
SD801DUP
SD802
SD803
Effects
11/19/97
11/19/97
11/19/97
11/19/97
11/19/97
Values
16:25
14:10
14:10
14:45
15:16
% MOISTURE
%
75
90
90
92
92
ALUMINUM
MG/KG
3300
900
820
930
810
ANTIMONY
MG/KG
2
0.5
U
0.5
U
0.5
U
0.56
0.5
U
ARSENIC
MG/KG
7.24
9.2
2.5
2.3
3.6
2.4
BARIUM
MG/KG
15
20
20
20
22
BERYLLIUM
MG/KG
0.2
U
0.2
U
0.2
U
0.2
U
0.2
U
BORON
MG/KG
NA
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
1
0.16
0.15
0.34
0.16
CALCIUM
MG/KG
270000
300000
280000
300000
300000
CHROMIUM
MG/KG
52.3
18
3.7
3.5
4
3.2
COBALT
MG/KG
0.5
U
1
U
1
U
1
U
1
U
COPPER
MG/KG
18.7
20
7.2
7
9.9
7.1
IRON
MG/KG
2000
560
490
580
460
LEAD
MG/KG
30.2
20
4
3.7
5.7
3.5
MAGNESIUM
MG/KG
1000
1300
1200
1100
1200
MANGANESE
MG/KG
23
17
17
18
16
MOLYBDENUM
MG/KG
0.92
0.93
0.92
1.6
1.2
NICKEL
MG/KG
15.9
2
1
U
1
U
1
U
1
U
POTASSIUM
MG/KG
2000
U
2000
U
2000
U
2000
U
2000
U
SELENIUM
MG/KG
0.67
0.85
0.95
0.91
0.83
SILVER
MG/KG
0.733
3.8
0.44
0.37
0.66
0.39
SODIUM
MG/KG
1000
U
1000
U
1000
U
1000
U
1000
U
STRONTIUM
MG/KG
2600
1600
1500
1600
1700
TELLURIUM
MG/KG
100
U
120
U
120
U
120
U
120
U
THALLIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TIN
MG/KG
2.7
0.5
U
0.5
U
0.5
U
0.5
U
TITANIUM
MG/KG
24
8.4
8
8.4
7.4
TOTAL MERCURY
MG/KG
0.13
0.17
0.058
0.054
0.079
0.52
VANADIUM
MG/KG
9.5
6.7
6.4
9
5.8
YTTRIUM
MG/KG
20
U
25
U
25
U
25
U
25
U
ZINC
MG/KG
124
110
45
44
48
37
ZIRCONIUM
MG/KG
NA
NA
NA
NA
NA
Note: Reported values exceeding the RAGS EV are in bold. Values with EDL exceeding RAGS EV are italicized.
Data Qualifiers
NA-Not analyzed. J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-37
Sediment Analytical Results - Cyanide
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD00100 SD00200 SD00300 SD00400 SD00500
10/15/98 10/15/98 10/15/98 10/15/98 10/15/98
10:20 11:10 11:55 14:30 15:15
CYANIDE MG/KG 1.4 UJ 1.4 UJ 1.4 UJ 2.3 UJ 0.94 UJ
Note: QC limits exceeded, results estimated for all samples
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-38
Sediment Analytical Results - Organotins
WWTP Ditches
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD00100
SD00200
SD00300
SD00400
SD00500
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
10:20
11:10
11:55
14:30
15:15
DIBUTYL TIN
UG/KG
62
U
43
U
55
U
89
U
37
U
MONOBUTYL TIN
UG/KG
62
U
43
u
55
U
89
U
37
U
TETRABUTYL TIN
UG/KG
62
U
43
u
55
U
89
U
37
U
TRIBUTYL TIN
UG/KG
62
U
43
u
55
U
89
U
37
u
Data Qualifiers
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-39
Sediment Analytical Results - Extractables
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
. November, 1997
RAGS 5D-001-000
SD-002-000
SD-003-000
SD-004-000
SD-005-000
Effects
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
Value
1020
1110
1155
1430
1515
% MOISTURE
%
70.8
58.8
64.5
80.5
48.4
(3-AND/OR 4-)METHYLPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,3,4,6-TETRACHLOROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,4,5-TRICHLOROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,4,6-TRICHLOROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,4-DICHLOROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,4-DIMETHYLPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2^4-DINITROPHENOL
UG/KG
420
UJ
290
UJ
370
UJ
660
UJ
230
UJ
2,4-DINITROTOLUENE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2,6-DINITROTOLUENE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-CHLORONAPHTHALENE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-CHLOROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-METHYL-4,6-DINITROPHENOL
UG/KG
420
UJ
290
UJ
370
UJ
660
UJ
230
UJ
2-M ETH YLNAPHTHALEN E
UG/KG
20.23
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-METHYLPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-NITROANILINE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
2-NITROPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
3,3'-DICHLOROBENZIDINE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
3-NITROANILINE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-bromophenyl phenyl ether
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-CHLORO-3-METHYLPHENOL
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-CHLOROANILINE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-CHLOROPHENYL PHENYL ETHER
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-NITROANILINE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
4-NITROPHENOL
UG/KG
420
UJ
290
UJ
370
UJ
660
UJ
230
UJ
acenaphthene
UG/KG
6.71
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
acenaphthylene
UG/KG
5.87
210
UJ
ISO
UJ
180
UJ
330
UJ
120
UJ
anthracene
UG/KG
46.9
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
B ENZO(A)ANTHRAC ene
UG/KG
74.8
24
J
8
J
180
UJ
40
J
11
J
BENZO(B)FLUORANTHENE
UG/KG
48
J
15
J
180
UJ
96
J
29
J
BENZO(GHI)PERYLENE
UG/KG
49
J
150
UJ
180
UJ
55
J
71
J
BENZO(K)FLUORANTHENE
UG/KG
34
J
10
J
180
UJ
78
J
18
J
BENZO-A-PYRENE
UG/KG
88.8
70
J
12
J
180
UJ
190
J
58
J
BENZYL BUTYL PHTHALATE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
BIS(2-CHLOROETHOXY)METHANE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
BIS(2-CHLOROETHYL) ETHER
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
BIS(2-CHLOROISOPROPYL) ETHER
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
BIS(2-ETHYLHEXYL) PHTHALATE
UG/KG
182
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
CARBAZOLE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
CHRYSENE
UG/KG
108
50
J
13
J
180
UJ
84
J
20
J
DI-N-BUTYLPHTHALATE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
di-n-octylphthalate
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
DIBENZO(A,H)ANTHRACENE
UG/KG
6.22
19
J
ISO
UJ
180
UJ
40
J
20
J
DIBENZOFURAN
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
DIETHYL PHTHALATE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
DIMETHYL PHTHALATE
UG/KG
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
FLUORANTHENE
UG/KG
113
32
J
14
J
180
UJ
51
J
13
J
-------
Table 5-39 (Continued)
Sediment Analytical Results - Extractables
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
FLUORENE
HEXACHLOROBENZENE (HCB)
HEXACHLOROBUTADIENE
HEXACHLOROC Y CLOPENT ADIENE (HCCP)
HEXACHLOROETHANE
INDENO (1,2,3-CD) PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
naphthalene
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
CI NAPHTHALENES
C2 NAPHTHALENES
C3 NAPHTHALENES
C4 NAPHTHALENES
CI FLUORENES
CI PHENANTHRENES/ANTHRACENES
C2 PHENANTHRENES/ANTHRACENES
C3 PHENANTHRENES/ANTHRACENES
C4 PHENANTHRENES/ANTHRACENES
CI FLUORANTHENES/PYRENES
CI CHRYSENES/BENZANTHRACENES
C2 CHRYSENES/BENZANTHRACENES
C3 CHRYSENES/BENZANTHRACENES
C4 CHRYSENES/BENZANTHRACENES
2 UNIDENTIFIED COMPOUNDS
4 UNIDENTIFIED COMPOUNDS
HEXADECANOIC ACID
PETROLEUM PRODUCT
Data Qualifiers
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
Effects
Value
21.2
34.6
86.7
153
1-000
SD-002-000
SD-003-000
SD-004-000
SD-005-000
15/98
10/15/98
10/15/98
10/15/98
10/15/98
1020
1110
1155
1430
1515
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
34
J
150
UJ
180
UJ
50
J
18
J
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
420
UJ
290
UJ
370
UJ
660
UJ
230
UJ
210
UJ
150
UJ
180
UJ
25
J
14
J
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
78
J
22
J
180
UJ
120
J
40
J
210
UJ
150
UJ
190
UJ
330
UJ
120
UJ
210
UJ
150
UJ
190
UJ
330
UJ
120
UJ
210
UJ
150
UJ
190
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
210
UJ
150
UJ
180
UJ
330
UJ
120
UJ
6000
J
NR
NR
NR
NR
NR
4000
J
NR
NR
NR
NR
NR
NR
NR
900
JN
N
NR
NR
N
N
J-Estimated value.
N-Presumptive evidence of presence of material.
NR-Not Reported
U-Matenal was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-40
Sediment Analytical Results - Pesticides/PCBs
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD00100
SD00200
SD00300
SD00400
SD00500
Effects
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
Value
10:20
11:10
11:55
14:30
15:15
% MOISTURE
%
71
59
65
80
48
4,4'-DDD (P,P'-DDD)
UG/KG
1.22
11
U
7.1
U
8.5
3.6
J
6.5
u
4,4'-DDE (P,P'-DDE)
UG/KG
2.07
120
11
22
41
63
4,4'-DDT (P,P'-DDT)
UG/KG
1.19
11
U
7.1
u
11
U
17
u
6.5
u
aldrin
UG/KG
4.7
U
2.8
u
3.4
U
7.5
u
2.6
U
ALPHA-BHC
UG/KG
4.4
U
2.8
u
3.4
U
6.8
u
2.6
U
ALPHA-CHLORDANE /2
UG/KG
7.6
U
2.8
u
3.4
U
16
3.8
ALPHA-CHLORDENE 12
UG/KG
1.2
J
2.8
u
3.4
U
6.8
u
2.6
U
BETA-BHC
UG/KG
4.4
u
3.9
u
3.4
U
6.8
u
2.6
u
BETA-CHLORDENE /2
UG/KG
4.4
u
2.8
u
3.4
U
6.8
u
2.6
u
CHLORDENE /2
UG/KG
13
2.6
J
0.76
JN
2.5
JN
2.6
u
CIS-NONACHLOR /2
UG/KG
3.5
N
0.82
J
5.5
U
12
2.8
DELTA-BHC
UG/KG
10
U
3.9
u
12
U
6.8
u
3.1
u
dieldrin
UG/KG
0.02
10
U
2.8
u
3.4
u
6.8
u
2.6
u
ENDOSULFAN I (ALPHA)
UG/KG
4.4
U
2.8
u
3.4
u
6.8
u
2.6
u
ENDOSULFAN II (BETA)
UG/KG
11
U
7.1
u
8.4
u
17
u
6.5
u
ENDOSULFAN SULFATE
UG/KG
16
U
9.2
u
10
u
25
u
7.8
u
endrin
UG/KG
0.02
11
u
7.1
V
8.4
u
17
u
6.5
u
endrin ketone
UG/KG
11
U
7.1
u
8.6
u
18
u
6.5
u
GAMMA-BHC (LINDANE)
UG/KG
0.32
4.4
U
2.8
u
3.4
u
6.8
u
2.6
u
GAMMA-CHLORDANE /2
UG/KG
10
U
2.8
u
3.4
u
15
N
2.6
N
GAMMA-CHLORDENE /2
UG/KG
4.7
u
4
u
4.7
u
6.8
u
2.6
u
HEPTACHLOR
UG/KG
4.4
u
2.8
u
3.4
u
6.8
u
2.6
u
HEPTACHLOR EPOXIDE
UG/KG
4.7
u
2.8
u
3.4
u
6.8
u
2.6
u
methoxychlor
UG/KG
22
u
14
u
17
u
34
u
13
u
OXYCHLORDANE (OCTACHLOREPOXIDE)
/2 UG/KG
4.7
u
4.1
u
5.1
u
10
u
4
u
PCB-1016 (AROCLOR 1016)
UG/KG
55
u
35
u
44
u
96
u
33
u
PCB-1221 (AROCLOR 1221)
UG/KG
55
u
35
u
44
u
96
u
33
u
PCB-1232 (AROCLOR 1232)
UG/KG
55
u
35
u
44
u
96
u
33
u
PCB-1242 (AROCLOR 1242)
UG/KG
55
u
35
u
44
u
96
u
33
u
PCB-1248 (AROCLOR 1248)
UG/KG
55
u
35
u
44
u
96
u
33
u
PCB-1254 (AROCLOR 1254)
UG/KG
21.6
92
J
35
u
44
u
96
u
33
u
PCB-1260 (AROCLOR 1260)
UG/KG
90
u
35
u
44
u
96
u
33
u
TOXAPHENE
UG/KG
510
u
280
u
340
u
720
u
260
u
trans-nonachlor a
UG/KG
4.4
u
0.85
J
0.75
JN
30
8.8
Data Qualifiers
J-Estimated value.
N-Presumptive evidence of presence of material.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1 .When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
-------
Table 5-41
Sediment Analytical Results - Volatiles
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD001000
SD002000
SD003000
SD004000
SD005000
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
10:20
11:10
11:55
14:30
15:15
% MOISTURE
%
70.8
58.8
64.5
80.5
48.4
(M- AND/OR P-)XYLENE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
1,1,1,2-TETRACHLOROETHANE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
1,1,1 -TRICHLOROETHANE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
1,1,2,2-TETRACHLOROETHANE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
1,1 ^-TRICHLOROETHANE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
1,1 -DICHLORO ETHANE
UG/KG
16
U
6.2
U
5.3
u
24
UJ
4.5
UJ
1,1 -DICHLOROETHENE (1,1 -DICHLOROETHYLENE)
UG/KG
16
u
6.2
U
5.3
u
24
UJ
4.5
UJ
1,1 -DICHLOROPROPENE
UG/KG
16
u
6.2
U
5.3
u
24
UJ
4.5
UJ
1,2,3-TRICHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,23-TRICHLOROPROPANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,2,4-TRICHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1 ,2,4-TRIMETHYLBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1.2-DIBROMO-3-CHLOROPROPANE (DBCP)
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,2-DIBROMOETHANE (EDB)
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,2-DICHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,2-DICHLOROETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1 ,2-DICHLOROPROPANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,3,5-TRIMETHYLBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,3-DICHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1 ,3-DICHLOROPROPANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
1,4-DICHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
2,2-DICHLOROPROPANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
ACETONE
UG/KG
390
u
85
J
130
u
610
UJ
110
UJ
BENZENE
UG/KG
16
u
4.1
J
5.3
u
24
UJ
1.5
J
BROMOBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
BROMOCHLOROMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
BROMODICHLOROMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
BROMOFORM
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
BROMOMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CARBON DISULFIDE
UG/KG
15
J
6.7
J
13
u
61
UJ
11
UJ
CARBON TETRACHLORIDE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CHLOROBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CHLOROETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CHLOROFORM
UG/KG
16
u
6.2
u
5.3
u
37
J
4.5
UJ
CHLOROMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CIS-1 ^-DICHLOROETHENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
CIS-13-DICHLOROPROPENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
DIBROMOCHLOROMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
DIBROMOMETHANE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
DIMETHYLOCTENE
UG/KG
NR
70
IN
NR
NR
NR
ETHYL BENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
HEXACHLORO-1.3-BUTADIENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
ISOPROPYLBENZENE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
MENTHENE
UG/KG
NR
100
JN
NR
NR
NR
METHYL BUTYL KETONE
UG/KG
39
U
16
u
13
u
61
UJ
11
UJ
METHYL ETHYL KETONE
UG/KG
390
u
160
u
130
u
610
UJ
110
UJ
METHYL ISOBUTYL KETONE
UG/KG
39
u
16
u
13
u
61
UJ
11
UJ
-------
Table 5-41 (Continued)
Sediment Analytical Results - Volatiles
WWTP Sediment
Military Canal Special Study
. Homestead Air Force Base
November, 1997
METHYLENE CHLORIDE
UG/KG
78
U
31
U
27
U
120
UJ
23
UJ
N-BUTYLBENZENE
UG/KG
16
U
6.2
U
5.3
U
24
UJ
4.5
UJ
N-PROPYLBENZENE
UG/KG
16
u
6.2
u
5.3
U
24
UJ
4.5
UJ
O-CHLOROTOLUENE
UG/KG
16
u
6.2
u
5.3
U
24
UJ
4.5
UJ
O-XYLENE
UG/KG
16
u
6.2
u
5.3
U
24
UJ
4.5
UJ
P-CHLOROTOLUENE
UG/KG
16
u
6.2
u
5.3
U
24
UJ
4.5
UJ
P-ISOPROPYLTOLUENE
UG/KG
27
1000
J
5.3
U
7.6
J
4.5
UJ
PINENE
UG/KG
NR
NR
NR
700
JN
NR
SEC-BUTYLBENZENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
STYRENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TERT-BUTYLBENZENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TETRACHLOROETHENE (TETRACHLOROETHYLENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TOLUENE
UG/KG
16
u
6.4
5.3
U
24
UJ
2.3
J
TRANS-1,2-DICHLOROETHENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TRANS-1,3-DICHLOROPROPENE
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TRICHLOROETHENE (TRICHLOROETHYLENE)
UG/KG
16
u
6.2
U
5.3
U
24
UJ
4.5
UJ
TR1CHLOROFLUOROMETHANE
UG/KG
16
u
6.2
u
5.3
U
24
UJ
4.5
UJ
VINYL CHLORIDE
UG/KG
16
u
6.2
u
5.3
u
24
UJ
4.5
UJ
Data Qualifiers
J-Estimated value.
NR-Not Requested
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-42
Sediment Analytical Results - Metals
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
RAGS
SD00100
SD00200
SD00300
SD00400
SD00500
Effects
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
Value
10:20
11:10
11:55
14:30
15:15
% MOISTURE
%
65
66
64
78
47
ALUMINUM
MG/KG
6000
4100
2500
7200
6100
ANTIMONY
MG/KG
2
0.72
0.26
0.38
1.2
0.2
ARSENIC
MG/KG
7.24
14
3.6
3.3
3.1
2.9
BARIUM
MG/KG
30
18
18
110
33
BERYLLIUM
MG/KG
0.32
0.14
0.1
u
0.21
0.22
BORON
MG/KG
NA
NA
NA
NA
CADMIUM
MG/KG
0.676
2.5
0.16
0.74
7
0.47
CALCIUM
MG/KG
280000
330000
320000
190000
290000
CHROMIUM
MG/KG
52.3
27
14
11
31
18
COBALT
MG/KG
NA
NA
NA
NA
W
COPPER
MG/KG
18.7
97
19
20
100
23
IRON
MG/KG
4800
2500
1600
3500
3500
LEAD
MG/KG
30.2
35
8.3
15
66
13
MAGNESIUM
MG/KG
1200
1100
980
1200
1400
MANGANESE
MG/KG
51
38
16
49
60
MOLYBDENUM
MG/KG
1.3
0.5
0.5
u
2.2
0.5
u
NICKEL
MG/KG
15.9
5.4
2.1
1.4
8.2
3
POTASSIUM
MG/KG
160
120
110
300
140
SELENIUM
MG/KG
1.9
0.5
0.5
U
1.4
0.5
u
SILVER
MG/KG
0.733
25
0.32
1.4
8.8
1.6
SODIUM
MG/KG
460
340
430
380
320
STRONTIUM
MG/KG
2100
1900
2300
1600
1700
TELLURIUM
MG/KG
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
THALLIUM
MG/KG
0.2
U
0.2
u
0.2
U
0.2
u
0.2
u
TIN
MG/KG
30
5
u
7
U
26
5
u
TITANIUM
MG/KG
120
51
31
73
97
TOTAL MERCURY
MG/KG
0.13
1.48
0.096
0.42
1.4
0.18
VANADIUM
MG/KG
20
8.4
6.2
30
17
YTTRIUM
MG/KG
4.8
3.6
2.8
4.5
4.7
ZINC
MG/KG
124
530
15
49
210
47
ZIRCONIUM
MG/KG
NA
NA
NA
NA
n;
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-43
Sediment Analytical Results - Herbicides
WWTP Sediment
Military Canal Special Study
Homestead Air Force Base
November, 1997
SD00100
SD00200
SD00300
SD00400
SD00500
10/15/98
10/15/98
10/15/98
10/15/98
10/15/98
10:20
11:10
11:55
14:30
15:15
% MOISTURE
%
71
59
65
80
48
2,4,5-T
UG/KG
8
U
5.9
U
8.6
U
12
U
5.1
2,4-D
UG/KG
12
U
18
u
12
U
18
U
7.7
DICAMBA
UG/KG
6
u
4.1
u
6
U
8.8
u
3.8
SILVEX (2,4,5-TP)
UG/KG
11
8.6
3.2
J
6.7
J
4.6
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-44
Sediment Toxicity Test Results
Military Canal Special Study
Homestead Air Force Base
November, 1997
Site
Number
Hyallela azteca
Ceriodaphnia dubia
Pore Water
Test
(% survival)
Whole
Sediment Test
(% survival)
Adult
¦ Survival (%)
# Young Per
Female
Control
80
96.7
90
24 .4
202
100
96 .7
90
13 . 0*
Control
83 .3
90
100
24 .4
205
100
90.0
100
28.3
208
100
90.0
100
28.4
211
100
83 .3
100
23 .7
214
96.7
70 . 0*
90
28.2
217
100
93 .3
90
28.4
220
100
90.0
80
20.1
301
100
83 .3
90
24.2
Control
100
96 .7
100
24 . 9
304
100
90 . 0
20*
0.4*
Control
80
96.7
90
24 .4
401
100
96.0
100
17.4*
404
100
93 .3
80
27.9
Control
100
86.7
100
26.1
407
100
86.7
90
1.3*
Control
80
96.7
100
24.9
410
100
96.0
100
22 . 9
4!3
93 .3
86.7
100
18.0*
-------
Table 5-44 (Continued)
Sediment Toxicity Test Results
Military Canal Special Study
Homestead Air Force Base
November, 1997
Sample
Number
Hyalella. azteca
Ceriodaphnia dubia
Pore Water
Test
(% survival)
Whole
Sediment Test
(% survival
Adult
Survival (%)
# Young Per
Female
Control
100
100
100
22 .7
SD-416
96.7
83 .3
90
18 . 0
SD-419
100
83 .3
90
24.3
Control
100
96.7
100
22.7
SD-422
100
16.7*
80
23 .0
Control
93 .3
96.7
100
26.1
SD-425
96.7
73 .3*
100
27.5
Control
93 .3
100
96. 7
26.1
SD-503A
93.3
26.6*
80
20 . 1*
Control
100
96.7
100
22 .7
SD-601
100
83 .3
80
18.0*
Control
100
96.7
100
24 . 9
SD-604
100
63 .3*
30*
2.3*
Control
100
100
100
22.7
SD-607
100
80.0
100
24.8
Control
100
96.7
100
22.7
SD-610
100
36.7
100
28.1
Control
93 .3
96.7
100
26.7
SD-702
100
76.7*
100
26.8
Control
93.3
86.7
100
26.1
SD-802
96.7
80.0
80
21.4*
Note: Sediment controls presented here and used to calculate significant
differences were from the Ogeechee River, Ga except for C. dubia tests for samples
SD-304, SD-410, SD-413 and SD-604. Calculations for the exceptions were based on
the sand controls because two adult zooplankton were trapped in a Ogeechee River
sediment fissure in the test chamber and died by day three without producing any
offspring. Sand controls performed at least as well as did the sediment from the
Ogeechee River for all sites.
Note: An asterisk (*) after a number indicates that its value is significantly
different (p^O.05) from the corresponding value for the control.
-------
Table 5-45
Pore Water Analytical Results - Ammonia
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW202
12/02/97
11:00
AMMONIA MG/L 3.2
PW205 PW208 PW211
11/25/97 11/25/97 11/25/97
10:00 10:45 11:30
9.9 A 2.2 9.5
PW214 PW217 PW220
11/25/97 11/25/97 11/25/97
12:15 13:00 13:40
1.7 1.5 5.3
PW301 PW304 PW401
11/25/97 12/02/97 12/02/97
14:30 11:30 12:15
2.6 1.6 A 2
PW404 PW407 PW4J0 PW413 PW416 PW419 PW422 PW425 PW503
12/02/97 12/02/97 12/02/97 12/02/97 12/09/97 12/09/97 12/09/97 12/16/97 12/16/97
13:00 13:40 14:15 15:00 10:00 11:00 13:00 10:00 10:45
AMMONIA MG/L 2.7 2 2.2 2.5 2.8 2.3 3.5 3.1 6.6
PW802
12/16/97
14:30
6
Data Qualifiers
A-Average value.
AMMONIA MG/L
PW604 PW607
12/09/97 12/09/97
14:15 15:00
4.5 5.3
PW610 PW702
12/09/97 12/16/97
15:45 13:30
2.8 3.7
-------
Table 5-46 (A) - Continued
Pore Water Analytical Results - Extractables
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW202
PW205
PW208
PW211
PW214
PW217
PW220
PW301
PW304
PW401
12/02/97
11/25/97
11/25/97
11/25/97
11/25/97
11/25/97
11/25/97
11/25/97
12/02/97
12/02/97
11:00
10:00
10:45
11:30
12:15
13:00
13:40
14:30
11:30
12:15
C2 CHRYSENES/BENZANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C2 FLUORENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C2 NAPHTHALENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C3 FLUORENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C3 NAPHTHALENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C4 NAPHTHALENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/L
8.9
UJ
7.1
UJ
6.2
UJ
5
UJ
6.7
UJ
7.3
UJ
5
UJ
4.9
UJ
8.9
UJ
4.4
UJ
CARBAZOLE
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
U
7.3
u
5
U
4.9
U
8.9
u
4.4
U
CHRYSENE
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
u
7.3
u
5
U
4.9
U
8.9
u
4.4
U
DI-N-BUTYLPHTHALATE
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
u
7.3
u
5
U
4.9
U
8.9
u
4.4
U
DI-N-OCTYLPHTHALATE
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
u
7.3
u
5
U
4.9
U
8.9
u
4.4
U
DIBENZO(A,H)ANTHRACENE
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
u
7.3
u
5
U
4.9
U
8.9
u
4.4
U
DIBENZOFURAN
UG/L
8.9
U
7.1
U
6.2
U
5
U
6.7
u
7.3
u
5
U
4.9
U
8.9
u
4.4
U
DIETHYL PHTHALATE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
U
8.9
u
4.4
U
DIMETHYL PHTHALATE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
U
8.9
u
4.4
U
FLUORANTHENE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
0.54
J
8.9
u
4.4
U
FLUORENE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
HEXACHLOROBENZENE (HCB)
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
HEX ACHLOROBUT ADIENE
UG/L
8.9
U
7.1
U
6.2
u
S
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
HEXACHLOROETHANE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
INDENO (1,2,3-CD) PYRENE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
U
ISOPHORONE
UG/L
8.9
U
7.1
U
6.2
u
5
u
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
N-NITROSODI-N-PROPYLAMINE
UG/L
8.9
u
7.1
U
6.2
u
5
u
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
UG/L
8.9
u
7.1
u
6.2
u
5
u
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
NAPHTHALENE
UG/L
8.9
u
7.1
u
6.2
u
5
u
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
NITROBENZENE
UG/L
8.9
u
7.1
u
6.2
u
5
u
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
PENTACHLOROPHENOL
UG/L
18
u
14
u
12
u
10
u
13
u
15
u
10
u
9.8
u
18
u
8.9
u
PETROLEUM PRODUCT
UG/L
NR
NR
NR
NR
N
N
NR
NR
NR
NR
PHENANTHRENE
UG/L
8.9
U
7.1
U
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
PHENOL
UG/L
8.9
u
7.1
u
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
PYRENE
UG/L
8.9
U
7.1
u
6.2
u
5
U
6.7
u
7.3
u
5
u
4.9
u
8.9
u
4.4
u
Data Qualifiers
J-Estimated value.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit
-------
Table 5-46 (B)
Pore Water Analytical Results - Extractables
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW404
PW407
PW410
PW413
PW416
PW419
PW422
PW425
PW503
12/02/97
12/02/97
12/02/97
12/02/97
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
13.00
13:40
14:15
15:00
10:00
11:00
13:00
10.00
10:45
(3-AND/OR 4-)METHYLPHENOL
UG/L
5
U
3.5
U
8 U
8
U
8
UJ
10
u
8
U
5.9
U
13 U
1,2,4-TRICHLOROBENZENE
UG/L
5
U
3.5
U
8 U
8
U
8
UJ
10
u
8
U
5.9
U
13 U
2,3.4,6-TETRACHLOROPHENOL
UG/L
5
U
3.5
U
8 U
8
U
8
UJ
10
u
8
U
5.9
U
13 U
2,4,5-TRICHLOROPHENOL
UG/L
5
U
3.5
U
8 U
8
U
8
UJ
10
u
8
U
5.9
U
13 U
2,4,6-TRICHLOROPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
U
13 U
2,4-DICHLOROPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2,4-DIMETHYLPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2,4-DINITROPHENOL
UG/L
10
U
6.9
U
16 U
16
u
16
UJ
20
u
16
U
12
u
25 U
2,4-DINITROTOLUENE
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2,6-DINITROTOLUENE
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-CHLORON APHTHALEN E
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-CHLOROPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-METHYL-4.6-DINITROPHENOL
UG/L
10
U
6.9
U
16 U
16
u
16
UJ
20
u
16
U
12
u
25 U
2-METHYLNAPHTHALENE
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-METHYLPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-NITROANILINE
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
2-NITROPHENOL
UG/L
5
U
3.5
U
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
3,3'-DICHLOROBENZIDINE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
3-NITROANILINE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
4-BROMOPHENYL PHENYL ETHER
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
4-CHLORO-3-METHYLPHENOL
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
4-CHLOROANILINE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
4-CHLOROPHENYL PHENYL ETHER
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
U
5.9
u
13 U
4-NITROANILINE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
4-NITROPHENOL
UG/L
10
u
6.9
u
16 U
16
u
16
UJ
20
u
16
u
12
u
25 U
ACENAPHTHENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
ACENAPHTHYLENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
ANTHRACENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZO(A)ANTHRACENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZO(B)FLUORANTHENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZO(GHI)PERYLENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZO(K)FLUORANTHENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZO-A-PYRENE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BENZYL BUTYL PHTHALATE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BIS(2-CHLOROETHOXY)METHANE
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BIS(2-CHLOROETHYL) ETHER
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BIS(2-CHLOROISOPROPYL) ETHER
UG/L
5
u
3.5
u
8 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
BIS(2-ETHYLHEXYL) PHTHALATE
UG/L
5
u
3.9
u
23 U
8
u
8
UJ
10
u
8
u
5.9
u
13 U
CI CHRYSENES/BENZANTHRACENES
UG/L
5
UJ
3.5
UJ
8 UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13 UJ
CI FLUORANTHENES/PYRENES
UG/L
5
UJ
3.5
UJ
8 UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13 UJ
CI FLUORENES
UG/L
5
UJ
3.5
UJ
8 UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13 UJ
CI NAPHTHALENES
UG/L
5
UJ
3.5
UJ
8 UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13 UJ
CI PHENANTHRENES/ANTHRACENES
UG/L
5
UJ
3.5
UJ
8 UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13 UJ
-------
Table 5-46 (B) - Continued
Pore Water Analytical Results - Extractables
Military Canal Special Study.
Homestead Air Force Base
November, 1997
PW404
PW407
PW410
PW413
PW416
PW419
PW422
PW425
PW503
12/02/97
12/02/97
12/02/97
12/02/97
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
13:00
13:40
14:15
15:00
10:00
11:00
13:00
10:00
10:45
C2 CHRYSENES/BENZANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C2 FLUORENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C2 NAPHTHALENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C3FLUORENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C3 NAPHTHALENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C4 NAPHTHALENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/L
5
UJ
3.5
UJ
8
UJ
8
UJ
8
UJ
10
UJ
8
UJ
5.9
UJ
13
UJ
CARBAZOLE
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
U
8
U
5.9
U
13
U
CHRYSENE
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
U
8
U
5.9
u
13
U
DI-N-BUTYLPHTHALATE
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
u
8
U
5.9
u
13
U
DI-N-OCTYLPHTHALATE
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
u
8
u
5.9
u
13
U
DIBENZO(A,H)ANTHRACENE
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
u
8
u
5.9
u
13
U
DIBENZOFURAN
UG/L
5
U
3.5
U
8
U
8
U
8
UJ
10
u
8
u
5.9
u
13
U
DIETHYL PHTHALATE
UG/I.
5
U
3.5
u
8
U
8
u
8
UJ
10
u
8
u
5.9
u
13
U
DIMETHYL PHTHALATE
UG/L
5
u
3.5
u
8
U
8
u
8
UJ
10
u
8
u
5.9
u
13
u
FLUORANTHENE
UG/L
5
u
0.5
J
8
u
0.76
J
8
UJ
10
u
8
u
1.2
J
13
u
FLUORENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
HEXACHLOROBENZENE (HCB)
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
HEXACHLOROBUTADIENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
. 5.9
u
13
u
HEXACHLOROETHANE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
INDENO (1,2,3-CD) PYRENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
ISOPHORONE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
N-NITROSODI-N-PROPYLAMINE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
to
u
8
u
5.9
u
13
u
N-N1TROSODIPHENYLAMINE/DIPHENYLAMINE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
NAPHTHALENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
NITROBENZENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
PENTACHLOROPHENOL
UG/L
10
u
6.9
u
16
u
16
u
16
UJ
20
u
16
u
12
u
25
u
PHENANTHRENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
PHENOL
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
5.9
u
13
u
PYRENE
UG/L
5
u
3.5
u
8
u
8
u
8
UJ
10
u
8
u
0.85
J
13
u
Data Qualifiers
J-Estimated value.
NR-Not Reported
U-Material was analyzed Tor but not detected. The number is the minimum quantitation limit.
-------
Table 5-46 (C)
Pore Water Analytical Results - Extractables
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW604
PW607
PW610
PW702
PW802
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
14:15
15:00
15:45
13:30
14:30
(3-AND/OR 4-)METHYLPHENOL
UG/L
10
u
6.7
U
6.2
U
8
U
5.8
U
1,2,4-TRICHLOROBENZENE
UG/L
10
u
6.7
U
6.2
u
8
U
5.8
U
2,3<4,6-TETRACHLOROPHENOL
UG/L
10
U
6.7
U
6.2
u
8
U
5.8
U
2,4,5-TRICHLOROPHENOL
UG/L
10
u
6.7
U
6.2
u
8
U
5.8
U
2,4,6-TRICHLOROPHENOL
UG/L
10
u
6.7
U
6.2
u
8
U
5.8
U
2,4-DICHLOROPHENOL
UG/L
10
u
6.7
U
6.2
u
8
U
5.8
U
2,4-DIMETHYLPHENOL
UG/L
10
u
6.7
U
6.2
u
8
U
5.8
U
2,4-DINITROPHENOL
UG/L
20
U
13
U
12
u
16
u
12
U
2,4-DINITROTOLUENE
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2,6-DINITROTOLUENE
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-CHLORONAPHTHALENE
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-CHLOROPHENOL
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-METHYL-4.6-DINITROPHENOL
UG/L
20
u
13
U
12
u
16
u
12
u
2-METHYLNAPHTHALENE
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-METHYLPHENOL
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-NITROANILINE
UG/L
10
u
6.7
U
6.2
u
8
u
5.8
u
2-NITROPHENOL
UG/L
10
u
6.7
u
6,2
u
8
u
5.8
u
3,3'-DICHLOROBENZIDINE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
3-NITROAN1LINE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
4-BROMOPHENYL PHENYL ETHER
UG/L
10
u
6.7
u
6.2
V
8
u
5.8
u
4-CHLORO-3-METHYLPHENOL
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
4-CHLOROANILINE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
4-CHLOROPHENYL PHENYL ETHER
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
4-N1TROANILINE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
4-NITROPHENOL
UG/L
20
u
13
u
12
u
16
u
12
u
ACENAPHTHENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
ACENAPHTHYLENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
ANTHRACENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZO(A)ANTHRACENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZO(B)FLUORANTHENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZO(GHl)PERYLENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZO(K)FLUORANTHENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZO-A-PYRENE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BENZYL BUTYL PHTHALATE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BIS(2-CIILOROETHOXY)METHANE
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BlS(2-CHLOROETHYL) ETHER
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BIS(2-CHLOROISOPROPYL) ETIIER
UG/L
10
u
6.7
u
6.2
u
8
u
5.8
u
BIS(2-ETHYLHEXYL) PHTHALATE
UG/L
10
u
16
u
6.2
u
8
u
5.8
u
CI CHRYSENES/BENZANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
8
UJ
5.8
UJ
CI FLUORANTHENES/PYRENES
UG/L
10
u;
6.7
UJ
6.2
UJ
8
UJ
5.8
UJ
CIFLUORENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
8
UJ
5.8
UJ
CI NAPHTHALENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
8
UJ
5.8
UJ
CI PHENANTHRENES/ANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
8
UJ
5.8
UJ
-------
Table 5-46 (C) - Continued
Pore Water Analytical Results - Extractabies
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW604
PW607
PW610
12/09/97
12/09/97
12/09/97
14:15
15:00
15:45
C2 CHRYSENES/BENZANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C2 FLUORENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C2NAPHTHALENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C2 PHENANTHRENES/ANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C3 CHRYSENES/BENZANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C3 FLUORENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C3 NAPHTHALENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C3 PHENANTHRENES/ANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C4 CHRYSENES/BENZANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C4NAPHTHALENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
C4 PHENANTHRENES/ANTHRACENES
UG/L
10
UJ
6.7
UJ
6.2
UJ
CARBAZOLE
UG/L
10
u
6.7
U
6.2
u
CHRYSENE
UG/L
10
u
6.7
U
6.2
u
Dl-N-BUTYLPHTHALATE
UG/L
10
u
6.7
U
6.2
u
DI-N-OCTYLPHTHALATE
UG/L
10
u
6.7
U
6.2
u
DIBENZO(A)H)ANTHRACENE
UG/L
10
u
6.7
U
6.2
u
DIBENZOFURAN
UG/L
10
u
6.7
U
6.2
u
DIETHYL PHTHALATE
UG/L
10
u
6.7
U
6.2
u
DIMETHYL PHTHALATE
UG/L
10
u
6.7
U
6.2
u
FLUORANTHENE
UG/L
10
u
6.7
U
6.2
u
FLUORENE
UG/L
10
u
6.7
U
6.2
u
HEXACHLOROBENZENE (HCB)
UG/L
10
u
6.7
U
6.2
u
HEXACHLOROBUTAD1ENE
UG/L
10
u
6.7
U
6.2
u
HEXACHLOROCYCLOPENTADIENE (HCCP)
UG/L
10
u
6.7
U
6.2
u
HEXACHLOROETHANE
UG/L
10
u
6.7
U
6.2
u
INDENO (1,2,3-CD) PYRENE
UG/L
10
u
6.7
U
6.2
u
ISOPHORONE
UG/L
10
u
6.7
U
6.2
u
N-N1TROSODI-N-PROPYLAMINE
UG/L
10
u
6.7
u
6.2
u
N-NITROSODIPHENYLAMINE/DIPIIENYLAMINE
UG/L
10
u
6.7
u
6.2
u
NAPHTHALENE
UG/L
10
u
6.7
u
6.2
u
NITROBENZENE
UG/L
10
u
6.7
u
6.2
u
PENTACHLOROPHENOL
UG/L
20
u
13
u
12
u
PHENANTHRENE
UG/L
10
u
6.7
u
6.2
u
PHENOL
UG/L
10
u
6.7
u
6.2
u
PYRENE
UG/L
10
u
6.7
u
6.2
u
Data Qualifiers
J-Estimated value.
NR-Not Reported
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
PW702 PW802
12/16/97 12/16/97
13:30 14:30
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 UJ 5.8 UJ
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
16 U 12 U
8 U 5.8 U
8 U 5.8 U
8 U 5.8 U
-------
Table 5-47 (A)
Pore Water Analytical Results - Pesticides and PCBs
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW202
PW205
PW208
12/02/97
11/25/97
11/25/97
11:00
10:00
10:45
1-HYDROXYCHLORDENE 12
UG/L
4,4'-DDD (P.F-DDD)
UG/L
0.089
U
0.067
U
0.06
U
4,4'^DDE (P.F-DDE)
UG/L
0.05
U
0.037
U
0.047
4,4'-DDT (P.f-DDT)
UG/L
0.089
u
0.067
U
0.06
U
ALDRIN
UG/L
0.036
u
0.027
U
0.024
U
ALPHA-BHC
UG/L
0.036
u
0.027
U
0.024
U
ALPHA-CHLORDANE /2
UG/L
ALPHA-CHLORDENE 12
UG/L
BETA-BHC
UG/L
0.036
u
0.027
U
0.024
U
BETA-CHLORDENE /2
UG/L
CHLORDANE (TECH. MIXTURE) /I
UG/L
0.22
u
0.17
U
0.15
U
CHLORDENE 12
UG/L
CIS-NONACHLOR 12
UG/L
DELTA-BHC
UG/L
0.036
u
0.027
U
0.024
U
DIELDR1N
UG/L
0.036
u
0.027
U
0.024
U
ENDOSULFANI (ALPHA)
UG/L
0.036
u
0.027
U
0.024
U
ENDOSULFAN H (BETA)
UG/L
0.089
u
0.067
U
0.091
U
ENDOSULFAN SULFATE
UG/L
0.089
u
0.067
U
0.06
U
ENDRIN
UG/L
0.089
u
0.067
U
0.06
U
ENDRIN KETONE
UG/L
0.89
u
0.067
U
0.06
U
GAMMA-BHC (LINDANE)
UG/L
0.036
u
0.027
U
0.024
U
GAMMA-CHLORDANE 12
UG/L
GAMMA-CHLORDENE 12
UG/L
HEPTACHLOR
UG/L
0.036
u
0.027
U
0.024
U
HEPTACHLOR EPOXIDE
UG/L
0.036
u
0.027
U
0.024
u
METHOXYCHLOR
UG/L
0.22
u
0.17
u
0.15
u
OXYCHLORDANE (OCTACHLOREPOXIDE)
12 UG/L
PCB-1016 (AROCLOR 1016)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1221 (AROCLOR 1221)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1232 (AROCLOR 1232)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1242 (AROCLOR 1242)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1248 (AROCLOR 1248)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1254 (AROCLOR 1254)
UG/L
0.44
u
0.33
u
0.3
u
PCB-1260 (AROCLOR 1260)
UG/L
0.44
u
0.33
u
0.3
u
TOXAPHENE
UG/L
3.6
u
2.7
u
2.4
u
TRANS-NONACHLOR /2
UG/L
Data Qualifiers
J-Eslimated value.
U-Material was analyzed Tor but not detected. The number is (he minimum quantitation limit.
1 .When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
PW211
PW214
PW217
PW220
PW301
PW304
PW401
[ 1/25/97
11/25/97
11/25/97
11/25/97
11/25/97
12/02/97
01/06/98
11:30
12:15
13:00
13:40
14:30
11:30
13:30
0.1 u
0.057 U
0.067
U
0.062
U
0.057
U
0.089
U
0.1
U
0.078
0.025 J
0.081
0.096
0.025
J
0.11
0.1
0.1 U
0.057 U
0.067
u
0.062
U
0.057
U
0.089
U
0.1
U
0.04 U
0.023 U
0.027
u
0.025
U
0.023
U
0.036
U
0.04
u
0.04 U
0.023 U
0.027
u
0.025
U
0.023
U
0.036
u
0.04
u
0.04 U
0.023 U
0.027
u
0.025
U
0.023
U
0.036
u
0.04
u
0.25 U
0.14 U
0.17
u
0.15
U
0.14
U
0.22
u
0.25
u
0.016
0.023
0.028
0.04 U
0 023 U
0.027
u
0.025
U
0.023
U
0.036
u
0.04
u
0.04 U
0.023 U
0.027
u
0.025
U
0.023
U
0.036
u
0.04
u
0.04 U
0.023 U
0.027
u
0.025
U
0.023
U
0.036
u
0.04
u
0.16 U
0.057 U
0.067
u
0.062
U
0.057
U
0.089
u
0.1
u
0.1 U
0.057 U
0.12
u
0.062
U
0.057
u
0.089
u
0.1
u
0.1 U
0.057 U
0.067
u
0.062
U
0.057
u
0.089
u
0.1
u
0.1 U
0.057 U
0.067
u
0.062
U
0.057
u
0.089
u
0.1
u
0.04 U
0.023 U
0.027
u
0.025
U
0.023
u
0.036
u
0.04
u
0.04 U
0.023 U
0.027
u
0.025
u
0.023
u
0.036
u
0.04
u
0.04 U
0.023 U
0.027
u
0.025
u
0.023
u
0.036
u
0.04
u
0.25 U
0.14 U
0.17
u
0.15
u
0.14
u
0.22
u
0.25
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
0.5 U
0.29 U
0.33
u
0.31
u
0.29
u
0.44
u
0.5
u
4 U
2.3 U
2.7
u
2.5
u
2.3
u
3.6
u
4
u
-------
Table 5-47 (B)
Pore Water Analytical Results - Pesticides and PCBs
Military Canal Special Study
Homestead Air Force Base
November, 19 97
1-HYDROXYCHLORDENE 12
4,4-DDD (P.F-DDD)
4,4'-DDE (P.F-DDE)
4,4'-DDT (P.P-DDT)
ALDRIN
ALPHA-BHC
ALPHA-CHLORDANE 12
ALPHA-CHLORDENE 12
BETA-BHC
BETA-CHLORDENE H
CHLORDANE (TECH. MIXTURE) /I
CHLORDENE 12
CIS-NONACHLOR 12
DELTA-BHC
DIELDRIN
ENDOSULFANI (ALPHA)
ENDOSULFANII (BETA)
ENDOSULFAN SULFATE
ENDRIN
ENDRIN KETONE
GAMMA-BHC (LINDANE)
GAMMA-CHLORDANE /2
GAMMA-C11LORDENE 12
HEPTACHLOR
HEPTACHLOR EPOXIDE
METHOXYCHLOR
OXYCHLORDANE (OCTACHLOREPOXIDE)
PCB-I016(AROCLOR I0I6)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
TOXAPHENE
TRANS-NONACHLOR 12
a
PW404
PW407
PW410
PW413
PW416
01/06/98
01/06/98
12/02/97
12/02/97
12/09/97
13:30
13:30
14:15
15:00
10:00
UG/L
UG/L
0.08
U
0.071
U
0.08
u
0.08
U
0.077
U
UG/L
0.017
J
0.015
J
0.035
J
0.063
J
0.025
J
UG/L
0.08
U
0.071
U
0.08
U
0.08
U
0.077
U
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
0.031
u
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
0.031
u
UG/L
UG/L
0.031
u
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
UG/L
UG/L
0.2
U
0.18
U
0.2
U
0.2
u
0.19
u
UG/L
UG/L
0.031
u
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
0.031
u
UG/L
0.032
U
0.029
U
0.032
U
0.032
u
0.031
u
UG/L
0.08
U
0.071
U
0.08
U
0.08
u
0.077
u
UG/L
0.08
U
0.071
u
0.08
U
0.08
u
0.077
u
UG/L
0.08
U
0.071
u
0.08
U
0.08
u
0.077
u
UG/L
0.08
U
0.071
u
0.08
U
0.08
u
0.077
u
UG/L
0.032
U
0.029
u
0.032
U
0.032
u
0.031
u
UG/L
UG/L
0.031
u
UG/L
0.032
U
0.029
u
0.032
U
0.032
u
UG/L
0.032
U
0.029
u
0.032
U
0.032
u
0.031
u
UG/L
0.2
U
0.18
u
0.2
U
0.2
u
0.19
u
UG/L
UG/L
0.4
U
0.36
u
0.4
U
0.4
u
0.38
u
UG/L
0.4
U
0.36
u
0.4
U
0.4
u
0.38
u
UG/L
0.4
U
0.36
u
0.4
U
0.4
u
0.38
u
UG/L
0.4
u
0.36
u
0.4
U
0.4
u
0.38
u
UG/L
0.4
u
0.36
u
0.4
U
0.4
u
0.38
u
UG/L
0.4
u
0.36
u
0.4
u
0.4
u
0.38
u
UG/L
0.4
u
0.36
u
0.4
u
0.4
u
0.38
u
UG/L
3.2
u
2.9
u
3.2
u
3.2
u
3.1
u
UG/L
Data Qualifiers
]-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1.When no value is reported, see chlordane constituents.
2.Constituents or metabolites of technical chlordane.
PW419
12/09/97
11:00
0.077 U
0.045
0.077 U
0.031 U
0.031 U
0.031 U
0.19 U
0.031 U
0.031 U
0.031 U
0.077 U
0.077 U
0.077 U
0.077 U
0.031 U
0.031 U
0.031 U
0.19 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
0.38 U
3.1 U
PW422
12/09/97
13:00
0.074 U
0.13
0.074 U
0.03 U
0.03 U
0.03 U
0.19 U
0.012 J
0.03 U
0.03 U
0.03 U
0.074 U
0.074 U
0.074 U
0.074 U
0.03 U
0.03 U
0.03 U
0.19 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
0.37 U
3 U
PW425
12/16/97
10:00
0.069 U
0.014 J
0.069 U
0.028 U
0.028 U
0.028 U
0.17 U
0.028 U
0.028 U
0.028 U
0.069 U
0.069 U
0.069 U
0.069 U
0.028 U
0.028 U
0.028 U
0.17 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
2.8 U
PW503
12/16/97
10:45
0.12 U
1.1
0.12 U
0.047 U
0.047 U
0.047 U
0.29 U
0.016 J
0.047 U
0.047 U
0.047 U
0.12 U
0.12 U
0.12 U
0.12 U
0.047 U
0.047 U
0.047 U
0.29 U
0.59 U
0.59 U
0.59 U
0.59 U
0.59 U
0.59 U
0.59 U
4.7 U
-------
Table 5-47 (C)
Pore Water Analytical Results - Pesticides and PCBs
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW604
PW607
PW6I0
PW702
PW802
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
14:15
15:00
15:45
13:30
14:30
1 -HYDROXYCHLORDENE 12
UG/L
4,4'-DDD (P.P-DDD)
UG/L
0.095
U
0.056
U
0.062
u
0.077
U
0.067
U
4,4'-E>DE (P.F-DDE)
UG/L
0.035
J
0.022
U
0.0068
}
0.031
u
0.027
U
4,4'-DDT (P.P-DDT)
UG/L
0.095
U
0.056
u
0.062
u
0.077
u
0.067
U
ALDRIN
UG/L
0.038
U
0.022
U
0.025
U
0.031
u
0.027
U
ALPHA-BHC
UG/L
0.038
U
0.022
U
0.025
U
0.031
u
0.027
U
ALPHA-CHLORDANE /2
UG/L
ALPHA-CHLORDENE /2
UG/L
BETA-BHC
UG/L
0.038
U
0.022
U
0.025
U
0.031
u
0.027
U
BETA-CHLORDENE 12
UG/L
CHLORDANE (TECH. MIXTURE) /I
UG/L
0.24
U
0.14
U
0.16
u
0.19
u
0.17
U
CHLORDENE 12
UG/L
CIS-NONACHLOR 12
UG/L
DELTA-BHC
UG/L
0.038
U
0.022
U
0.025
u
0.031
u
0.027
U
DIELDRIN
UG/L
0.038
U
0.022
U
0.025
u
0.031
u
0.027
U
ENDOSULFAN I (ALPHA)
UG/L
0.038
U
0.022
U
0.025
u
0.031
u
0.027
U
ENDOSULFAN II (BETA)
UG/L
0.095
U
0.056
U
0.062
u
0.077
u
0.067
U
ENDOSULFAN SULFATE
UG/L
0.095
U
0.056
U
0.062
u
0.077
u
0.067
U
ENDRIN
UG/L
0.095
U
0.056
U
0.062
u
0.077
u
0.067
U
ENDRIN KETONE
UG/L
0.095
u
0.056
u
0.062
u
0.077
u
0.067
U
GAMMA-BHC (LINDANE)
UG/L
0.038
u
0.022
U
0.025
u
0.031
u
0.027
U
GAMMA-CHLORDANE 12
UG/L
GAMMA-CHLORDENE /2
UG/L
HEPTACHLOR
UG/L
0.038
u
0.022
U
0.025
u
0.031
u
0.027
U
HEPTACHLOR EPOXIDE
UG/L
0.038
u
0.022
u
0.025
u
0.031
u
0.027
U
METHOXYCHLOR
UG/L
0.24
u
0.14
u
0.16
u
0.19
u
0.17
U
OXYCHLORDANE (OCTACHLOREPOXIDE) 12 UG/L
PCB-1016(AROCLOR 1016)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
U
PCB-1221 (AROCLOR 1221)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
U
PCB-1232 (AROCLOR 1232)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
U
PCB-1242 (AROCLOR 1242)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
U
PCB-1248 (AROCLOR 1248)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
' 0.33
u
PCB-1254 (AROCLOR 1254)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
u
PCB-1260 (AROCLOR 1260)
UG/L
0.48
u
0.28
u
0.31
u
0.38
u
0.33
u
TOXAPHENE
UG/L
3.8
u
2.2
u
2.5
u
3.1
u
2.7
u
TRANS-NONACHLOR 12 UG/L
Data Qualifiers
J-Estimated value.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
1 .When no value is reported, see chlordane constituents.
2.Constituenls or metabolites of technical chlordane.
-------
Table 5-48 (A)
Pore Water Analytical Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW202
12/02/97
11:00
ALUMINUM
ANTIMONY
ARSENIC
BARIUM
BERYLLIUM
BORON
CADMIUM
CALCIUM
CHROMIUM
COBALT
COPPER
IRON
LEAD
MAGNESIUM
MANGANESE
MOLYBDENUM
NICKEL
POTASSIUM
SELENIUM
SILVER
SODIUM
STRONTIUM
TELLURIUM
THALLIUM
TIN
TITANIUM
TOTAL MERCURY
URANIUM, TOTAL
VANADIUM
YTTRIUM
ZINC
ZIRCONIUM
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
MG/L
UG/L
UG/L
UG/L
MG/L
UG/L
MG/L
UG/L
UG/L
UG/L
MG/L
UG/L
UG/L
MG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
METAI UG/L
UG/L
UG/L
UG/L
UG/L
0.1
0.1
240
1
0.5
0.2
520
35
2.3
1
160
5
1
4300
3500
50
0.1
0.96
0.031
8.4
2
0.5
NA
U
U
NA
U
NA
U
U
U
NA
NA
NA
U
U
NA
NA
PW202
12/02/97
11:00
130
1
27
0.1
0.1
1
0.5
7.2
0.82
0.94
1
0.1
0.5
0.5
12
U
NA
U
NA
U
NA
U
U
NA
NA
NA
U
NA
NA
U
NA
NA
NA
U
U
NA
NA
NA
U
NA
PW205
01/25/98
10:00
120
0.15
PW205
11/25/97
10:00
PW208
11/25/97
10:45
44
0.1
0.1
1
0.5
10
2.3
0.7
1
0.1
28
5.2
0.5
9.7
NA
U
NA
U
NA
U
U
NA
NA
NA
U
NA
NA
U
NA
NA
NA
U
NA
NA
U
NA
0.23
5
0.1
0.21
150
2
0.5
0.1
170
9.6
1.8
1.5
48
5
1
1300
1900
50
0.1
74
5.7
0.081
6.6
1.3
10
NA
U
NA
U
NA
U
NA
NA
U
NA
NA
NA
0.77
12
0.1
0.59
130
2.7
0.5
0.091
63
7.5
5.9
3.6
27
5
2.3
570
1600
50
0.1
48
6.7
0.25
7.2
4.4
10
NA
U
NA
U
NA
NA
U
NA
NA
Note- Samples PW-205, PW-208, PW-211, PW-214, PW-217 exceeded recommended holding time for mercury.
Note: Samples PW-205^ PW-208, PW-214, PW-217 results are for acid soluble metals, method 200.1 R-4.
Data Qualifiers
NA-Not analyzed. ... ... .• .• ¦.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
PW208
11/25/97
10:45
PW211
11/25/97
11:30
230
0.71
NA
24
0.1 U
NA
0.59
NA
2.7
0.5 U
28
NA
3.9
NA
NA
5
2.2
NA
NA
1.2
NA
NA
NA
0.1 U
63
8.6
NA
6.6
NA
0.5 U
33
NA
NA
0.36
7.4
0.1
0.64
100
3
0.5
0.12
62
9.8
2.6
1.3
17
5
3.2
380
1300
50
0.1
30
5.4
0.31
6.7
1.8
10
NA
U
NA
U
NA
NA
PW214
11/25/97
12:15
U
NA
NA
NA
0.4
5.3
0.1
0.42
90
2.8
0.5
0.095
26
12
3.6
1.8
13
5
2.3
200
1200
50
0.1
38
3.9
0.17
6.8
2
10
NA
U
NA
U
NA
NA
PW214
11/25/97
12:15
U
NA
NA
PW217
11/25/97
13:00
240
0.35
NA
24
0.1 U
NA
0.4
NA
1.3
0.5 U
21
NA
3.7
NA
NA
2.8
1.7
NA
NA
1 U
NA
NA
NA
0.1 U
17
3
NA
5.5
NA
0.5 U
24
NA
NA
0.82
9.2
0.1
1-7
78
6.7
0.5
0.23
22
3.3
7.4
4
11
5
8.7
120
970
50
0.1
51
5.6
0.67
6.8
3.9
10
NA
U
NA
U
NA
NA
U
NA
NA
-------
Table 5-48 (B)
Pore Water Analytical Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW217
PW220
PW220
PW301
11/25/97
11/25/97
11/25/97
11/25/97
13:00
13:40
13:40
14:30
ALUMINUM
UG/L
350
NA
140
NA
ANTIMONY
UG/L
0.2
0.28
0.2
0.5
ARSENIC
UG/L
NA
5 U
NA
5.9
BARIUM
UG/L
17
NA
26
NA
BERYLLIUM
UG/L
0.1
U
0.1 U
0.1
U
0.1 U
BORON
UG/L
NA
NA
NA
NA
CADMIUM
UG/L
1.1
0.32
0.29
1.1
CALCIUM
MG/L
NA
80
NA
84
CHROMIUM
UG/L
2.9
1.7
1.6
2.6
COBALT
UG/L
0.5
U
0.5 U
0.5
U
0.5 U
COPPER
UG/L
46
NA
15
NA
IRON
MG/L
NA
0.087
NA
0.12
LEAD
UG/L
13
NA
3.5
NA
MAGNESIUM
MG/L
NA
30
NA
20
MANGANESE
UG/L
NA
7.2
NA
8.2
MOLYBDENUM
UG/L
3
2.1
1.4
2.4
NICKEL
UG/L
3.4
1.4
1.2
1.6
POTASSIUM
MG/L
NA
12
NA
10
SELENIUM
UG/L
NA
5 U
NA
5 U
SILVER
UG/L
1
U
5.4
1
U
2.9
SODIUM
MG/L
NA
200
NA
120
STRONTIUM
UG/L
NA
1000
NA
1100
TELLURIUM
UG/L
NA
50 U
NA
50 U
THALLIUM
UG/L
0.1
U
0.1 U
0.1
U
0.1 U
TIN
UG/L
41
18
14
3.7
TITANIUM
UG/L
2.9
3.4
3.6
3.2
TOTAL MERCURY
UG/L
NA
0.22
NA
0.41
URANIUM, TOTAL METAI UG/L
4.5
6.4
5.2
6.6
VANADIUM
UG/L
NA
1.3
NA
1.6
YTTRIUM
UG/L
0.5
U
10 U
0.5
U
0.5 U
ZINC
UG/L
61
20
20
NA
ZIRCONIUM
UG/L
NA
NA
NA
NA
Note: Samples PW-220, PW-301, PW-304, and PW-401 exceeded recommended holding time for mercury
Note: Samples PW-220, PW-301, PW-304, and PW-401 results are for acid soluble metals, method 200.1 R-4.
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
PW301
PW304
PW304
PW401
PW401
1/25/97
12/02/97
12/02/97
12/02/97
12/02/97
14:30
11:30
11:30
12:15
12:15
300
NA
220
NA
570
0.27
1.5
1.1
3.4
1.9
NA
19
NA
5 U
NA
60
NA
13
NA
24
0.1
U
0.1
U
0.1 U
0.1 U
0.1
U
NA
NA
NA.
NA
NA
0.95
t.l
1.1
2.1
1.7
NA
72
NA
81
NA
1
U
5.3
2.4
8.7
5.9
0.5
U
0.5
U
0.5 U
0.5 U
0.5
U
40
NA
50
NA
94
NA
0.26
NA
0.26
NA
10
NA
11
NA
23
NA
17
NA
18
NA
NA
5.2
NA
5.2
NA
0.91
5.4
2.8
21
10
1.1
2.4
2
3.5
4
NA
8.2
NA
7.7
NA
NA
5
U
NA
5 U
NA
1
U
8.2
2.1
25
3.6
NA
87
NA
93
NA
NA
900
NA
990
NA
NA
50
U
NA
50 U
NA
0.1
U
0.1
U
0.1 U
0.1 U
0.1
U
3.8
1.2
2.9
3.4
4.9
1.4
4
4.6
8.1
11
NA
0.4
NA
1.3
NA
4.5
11
9.2
55
41
NA
2.7
NA
11
NA
0.5
U
10
U
0.5 U
10 U
0.5
52
NA
77
NA
160
NA
NA
NA
NA
NA
-------
Table 5-48 (C)
Pore Water Analytical Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW404
PW404
PW407
PW407
PW410
PW410
PW413
PW413
PW416
PW416
12/02/97
12/02/97
12/02/97
12/02/97
12/02/97
12/02/97
12/02/97
12/02/97
12/09/97
12/09/97
13:00
13:00
13:40
13:40
14:15
14:15
15:00
15:00
10:00
10:00
ALUMINUM
UG/L
NA
120
NA
1400
NA
280
NA
620
NA
610
ANTIMONY
UG/L
0.26
0.1
U
0.86
0.43
0.91
0.27
3
3
1.3
0.44
ARSENIC
UG/L
5 U
NA
5
U
NA
5
U
NA
5
U
NA
5
U
NA
BARIUM
UG/L
NA
12
NA
18
NA
9.1
NA
12
NA
15
BERYLLIUM
UG/L
0.1 U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
BORON
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
CADMIUM
UG/L
0.6
0.42
1.7
1.2
0.35
0.31
1.7
1.7
1.9
1.3
CALCIUM
MG/L
90
NA
79
NA
84
NA
82
NA
79
NA
CHROMIUM
UG/L
3.8
1
U
5.2
5.2
2
1.1
6.7
6.7
7.1
3.1
COBALT
UG/L
0.5 U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
COPPER
UG/L
NA
17
NA
30
NA
16
NA
9.7
NA
46
IRON
MG/L
0.11
NA
0.14
NA
0.2
NA
0.15
NA
0.17
NA
LEAD
UG/L
NA
5.3
NA
11
NA
4.6
NA
NA
NA
15
MAGNESIUM
MG/L
13
NA
9.7
NA
8.1
NA
8.8
NA
17
NA
MANGANESE
UG/L
5.9
NA
5.2
NA
5.7
NA
4.7
NA
4.8
U
NA
MOLYBDENUM
UG/L
1.3
0.5
U
2.8
2.8
1.5
0.53
2.6
2.6
2.7
0.9
NICKEL
UG/L
2.1
1
U
2.1
2
2.5
1.7
3.6
3.6
2.1
1
POTASSIUM
MG/L
8.7
NA
8.2
NA
9.2
NA
8
NA
7.6
NA
SELENIUM
UG/L
5 U
NA
5
U
NA
5
U
NA
5
U
5
U
5
U
NA
SILVER
UG/L
2.9
1
U
4
1.9
2.4
1
U
6
1
U
5.8
1
U
SODIUM
MG/L
83
NA
57
NA
49
NA
40
NA
68
NA
STRONTIUM
UG/L
1100
NA
980
NA
1000
NA
1000
NA
940
NA
TELLURIUM
UG/L
50 U
NA
50
U
NA
50
U
NA
50
U
NA
50
U
NA
THALLIUM
UG/L
0.1 U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
u
0.1
U
TIN
UG/L
1
0.5
U
1.4
4.9
0.94
0.5
U
1.1
1.1
1.8
1.7
TITANIUM
UG/L
3.3
1.7
4
6.6
4.1
4.2
4
2.2
4.2
2.5
TOTAL MERCURY
UG/L
0.33
NA
0.37
NA
0.13
NA
0.53
NA
0.64
NA
URANIUM, TOTAL METAI UG/L
12
7.6
20
17
11
7.3
15
7.8
12
9.5
VANADIUM
UG/L
1.2
NA
1.4
NA
2.1
2.1
2.6
NA
1.9
NA
YTTRIUM
UG/L
0.5 U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
0.5
U
ZINC
UG/L
NA
29
NA
50
NA
26
NA
32
NA
63
ZIRCONIUM
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Note: Samples PW-404, PW-407, PW-410, PW-413, and PW-416 exceeded recommended holding time for mercury
Note: Samples PW-404, PW-407, PW-410, PW-413, and PW-416 results are for acid soluble metals, method 200.1 R-4.
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-48 (D)
Pore Water Analytical Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW419
PW419
PW422
PW422
PW425
PW425
PW503
PW503
PW601
12/09/97
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
12/16/97
12/16/97
12/09/97
11:00
11:00
13:00
13:00
10:00
10:00
10:45
10:45
13:30
ALUMINUM
UG/L
NA
120
NA
280
NA
87
NA
90
120
ANTIMONY
UG/L
1.7
0.51
0.62
0.36
0.58
0.21
0.56
0.39
0.24
ARSENIC
UG/L
5
U
NA
5
U
NA
7.3
NA
5
U
NA
NA
BARIUM
UG/L
NA
11
NA
18
NA
8.6
NA
15
12
BERYLLIUM
UG/L
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
u
0.1
U
0.1
U
0.1
U
BORON
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
CADMIUM
UG/L
2.7
0.9
0.56
0.47
0.15
0.15
0.45
0.33
0.1
U
CALCIUM
MG/L
86
NA
74
NA
77
NA
88
NA
NA
CHROMIUM
UG/L
4.4
1.8
4.8
2.7
1
U
1
U
2
1
U
1.3
COBALT
UG/L
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
COPPER
UG/L
NA
43
NA
29
NA
9.6
NA
12
3.7
IRON
MG/L
0.14
NA
0.16
NA
0.14
NA
0.3
NA
NA
LEAD
UG/L
NA
11
NA
9.3
NA
4.5
NA
6.3
0.45
MAGNESIUM
MG/L
11
NA
8.8
NA
4.9
NA
11
NA
NA
MANGANESE
UG/L
4.7
U
NA
4.7
NA
4.7
NA
11
NA
NA
MOLYBDENUM
UG/L
2.1
0.64
2.1
1
2.2
1.1
2.3
1.2
1.1
NICKEL
UG/L
2.7
1.1
2
1.3
1
U
1
U
1
U
1
U
1
U
POTASSIUM
MG/L
8.5
NA
8.1
NA
7.2
NA
7.3
NA
NA
SELENIUM
UG/L
5
U
NA
5
U
NA
5
U
NA
5
U
NA
NA
SILVER
UG/L
12
1
U
14
3.5
1
U
1
U
3.6
1
U
1
U
SODIUM
MG/L
42
NA
31
NA
21
NA
45
NA
NA
STRONTIUM
UG/L
1000
NA
860
NA
890
NA
960
NA
NA
TELLURIUM
UG/L
50
U
NA
50
U
NA
50
U
NA
50
u
NA
NA
THALLIUM
UG/L
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
u
0.1
U
0.1
U
TIN
UG/L
1.4
1
0.58
2.6
0.5
U
0.5
U
0.6
0.5
U
0.5
U
TITANIUM
UG/L
4
1.5
5.5
5.1
2.7
1.3
3
1.9
3.2
TOTAL MERCURY
UG/L
0.65
NA
0.4
NA
0.05
NA
0.19
NA
NA
URANIUM, TOTAL METAI UG/L
12
7.8
9.7
7.3
6.6
4.9
4.1
3.3
2.2
VANADIUM
UG/L
1.7
NA
3.1
NA
1.4
NA
2.1
NA
NA
YTTRIUM
UG/L
0.5
U
0.5
U
0.5
U
0.5
U
0.5
u
0.5
U
0.5
u
0.5
U
0.5
U
ZINC
UG/L
NA
75
NA
48
NA
26
NA
34
8.2
ZIRCONIUM
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
Note: Samples PW-419 and PW-422 exceeded recommended holding time for mercury
Note: Samples PW-419, PW-422, PW-425, PW-503, and PW-601 results are for acid soluble metals, method 200.1 R-4.
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-48 (E)
Pore Water Analytical Results - Metals
Military Canal Special Study
Homestead Air Force Base
November, 1997
PW604
PW604
PW607
PW607
PW610
PW610
PW702
PW702
PW802
PW802
12/09/97
12/09/97
12/09/97
12/09/97
12/09/97
12/09/97
12/16/97
12/16/97
12/16/97
12/16/97
14:15
14:15
15:00
15:00
15:45
15:45
13:30
13:30
14:30
14:30
ALUMINUM
UG/L
NA
430
NA
55
NA
99
NA
490
NA
15
ANTIMONY
UG/L
0.17
0.1
U
0.1
U
0.1
U
0.48
0.17
0.17
0.1
U
0.19
0.14
ARSENIC
UG/L
5
U
NA
5
U
NA
5
U
NA
5
U
NA
5
U
NA
BARIUM
UG/L
NA
18
NA
14
NA
9
NA
9.1
NA
12
BERYLLIUM
UG/L
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
BORON
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
CADMIUM
UG/L
0.32
0.27
0.12
0.1
U
0.19
0.15
0.13
0.1
U
1.1
0.1
U
CALCIUM
MG/L
95
NA
94
NA
90
NA
94
NA
96
NA
CHROMIUM
UG/L
4.2
2.6
2
1
U
2.5
1
U
3.7
2.4
1.5
1
U
COBALT
UG/L
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
COPPER
UG/L
NA
18
NA
4.4
NA
6.8
NA
3.2
NA
2
IRON
MG/L
0.12
NA
0.05
U
NA
0.067
NA
0.16
NA
0.05
U
NA
LEAD
UG/L
NA
3.9
NA
1.32
NA
2
NA
2.1
NA
0.55
MAGNESIUM
MG/L
28
NA
il
NA
4.2
NA
7.9
NA
4.8
NA
MANGANESE
UG/L
14
NA
9.7
NA
6.4
NA
8.5
NA
8.2
NA
MOLYBDENUM
UG/L
0.79
0.43
0.5
U
0.5
U
0.78
0.5
U
0.55
0.5
U
0.5
U
0.5
U
NICKEL
UG/L
1.8
1.1
1
U
1
U
1.9
1
U
1
U
1
U
1
U
1
U
POTASSIUM
MG/L
15
NA
2
U
NA
12
NA
6.1
NA
12
NA
SELENIUM
UG/L
5
U
NA
5
U
NA
5
U
NA
5
U
NA
5
U
NA
SILVER
UG/L
4.68
1.6
1
1
U
1.1
1
U
1
U
1
U
3.5
1
U
SODIUM
MG/L
130
NA
46
NA
20
NA
25
NA
19
NA
STRONTIUM
UG/L
1100
NA
670
NA
1000
NA
1100
NA
1100
NA
TELLURIUM
UG/L
50
U
NA
50
U
NA
50
U
NA
50
U
NA
50
U
NA
THALLIUM
UG/L
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
0.1
U
TIN
UG/L
0.81
1.5
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
TITANIUM
UG/L
6.3
8.3
2
1
U
3.2
1.2
4.2
11
1
U
1
U
TOTAL MERCURY
UG/L
0.11
NA
0.054
NA
0.11
NA
0.018
NA
0.0093
NA
URANIUM, TOTAL METAI UG/L
4.5
3.1
4.3
3.3
11
7.4
3.5
2.3
3.7
2.8
VANADIUM
UG/L
2.2
NA
1
U
NA
2.8
NA
1.7
NA
1
U
NA
YTTRIUM
UG/L
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
0.5
U
1.2
0.63
0.5
U
0.5
U
ZINC
UG/L
NA
24
NA
8.8
NA
14
NA
16
NA
12
ZIRCONIUM
UG/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Note: Samples PW-604, PW-607, and PW-610 exceeded recommended holding time for mercury
Note: Samples PW-604, PW-607, PW-610, PW-702, and PW-802 results are for acid soluble metals, method 200.1 R-4.
Data Qualifiers
NA-Not analyzed.
U-Material was analyzed for but not detected. The number is the minimum quantitation limit.
-------
Table 5-49
Sample ID
Sulfide content
(mg/L)
0.27Q mg/L std.
Cen?ri?ugi bottle blank
PW-202
PW-205
PW-205 duplicate
PW-208
PW-211
PW-214
PW-214 duplicate
PW-301
PW-304
PW-401
PW-404
PW-407
PW-410
PW-413
PW-419
PW-419 duplicate
PW-422
PW-425
PW-503A
PW-601
PW-604
PW-607
PW-610
PW-702
PW-802
PW-802 duplicate
0.270 mg/L std.
0.230
0.001
2.
0.
0.
1.
0 .
1.
1.
0.270 mg
(ending)
,570
.027
.022
.070
.064
.720
,660
0.500
0.084
1.180
0.250
0.022
0.237
0.023
.053
.048
.650
.590
.043
.019
0.256
0.065
3 .520
0.810
1.820
1.740
0.234
THE SULFIDE CONTENT OF PORE WATER SAMPLES EXTRACTED FROM SEDIMENT COLLECTED FROM
CANALS IN AND AROUND HOMESTEAD AIR FORCE BASE, FLORIDA, NOVEMBER 14-19, 1997. (DCN
# 4B-8001)
Sediments were stored at 4° C until the pore water was extracted and tested.
Extraction method: Centrifugation: sediment spun 10 minutes at 6500 rpm in a
Sorvall RC-2 superspeed centrifuge with GSA rotor to
generate a relative centrifugal force (RCF) of 5000 x g.
Analytical Method: Hach® colorimetric test #690.
Date of testing: January 15, 1998
QA/QC: Accuracy of the Hach DR/2000 was measured against a certified
standard of 0.270 mg sulfide/L before and after the test run..
Only two to three samples were extracted at a time. All,pore
water samples were analyzed within 20 minutes of extraction. A
test was also performed on a centrifuge bottle blank. Duplicate
analyses were performed on at least 10% of the test samples.
-------
Table 5-50
Sediment Toxicity Test Results
Military Canal Special Study
Homestead Air Force Base
November, 1997
Site
Hyallela.
azteca
CGxiodaphala. dubia.
Number
Pore Water
Test
(% survival)
Whole
Sediment Test
(% survival)
Adult
Survival (%)
# Young Per
Female
Control
80
96.7
90
24.4
202
100
96.7
90
13.0*
Control
83.3
90
100
24.4
205
100
90.0
100
28.3
208
100
90.0
100
28.4
211
100
83.3
100
23.7
214
96.7
70.0*
90
28.2
217
100
93.3
90
28.4
220
100
90.0
80
20.1
301
100
83.3
90
24.2
Control
100
96.7
100
24.9
304
100
90.0
20*
0.4*
Control
80
96.7
90
24.4
401
100
96.0
100
17.4*
404
100
93.3
80
27.9
Control
100
86.7
100
26.1
407
100
86.7
90
1.3*
Control
80
96.7
100
24.9
410
100
96.0
100
22.9
413
93.3
86.7
100
18.0*
-------
Table 5-50 (Continued)
Sediment Toxicity Test Results
Military Canal Special Study
Homestead Air Force Base
November, 1997
Sainple
Number
Hyalella. azteca
CexiodaphTt i a duJbia
Pore Water
Test
(% survival)
Whole
Sediment Test
(% survival
Adult
Survival (%)
# Young Per
Female
Control
100
100
100
22.7
SD-416
96.7
83.3
90
18.0
SD-419
100
83.3
90
24.3
Control
100
96.7
100
22.7
SD-422
100
- 16.7*
80
23.0
Control
93.3
96.7
100
26.1
SD-425
96.7
73. 3*
100
27.5
Control
93.3
100
96.7
26.1
SD-503A
93.3
26. 6*
80
20.1*
Control
100
96.7
100
22.7
SD-601
100
83.3
80
18.0*
Control
100
96.7
100
24.9
SD-604
100
63.3*
30*
2.3*
Control
100
100
100
22.7
SD-607
100
80.0
100
24.8
Control
100
96.7
100
22.7
SD-610
100
36.7
100
28.1
Control
93.3
96.7
100
26.7
SD-702
100
76.7*
100
26.8
Control
93.3
86.7
100
26.1
SD-802
96.7
80.0
80
21.4*
Note: Sediment controls presented here and used to calculate significant
differences were from the Ogeechee River, Ga except for C. dubia tests for samples
SD-304, SD-410, SD-413 and SD-604. Calculations for the exceptions were based on
the sand controls because two adult zooplankton were trapped in a Ogeechee River
sediment fissure in the test chamber and died by day three without producing any
offspring. Sand controls performed at least as well as did the sediment from the
Ogeechee River for all sites.
Note: An asterisk (*) after a number indicates that its value is significantly
different (p<0.05) fr6m the corresponding value for the control.
-------
Table 6-1
Sediment Contaminants Comparison - Extractables
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
Analyte
Sludge
Drying
Bed
Incinerator
Ditches
Washrack
Reservoir/Military
Canal Sediment
Phenol
X
X
ND
NA
ND
Naphthalene
X
X
ND
NA
X
2-methylnaphthalene
X
X
ND
NA
X
Acenaphthylene
X
X
ND
NA
X
Acenaphthene
X
X
ND
NA
X
Fluorene
X
X
ND
NA
X
N-nitrosodiphenylamine
ND
X
ND
NA
ND
Phenanthrene
X
X
X
NA
X
Anthracene
X
X
ND
NA
X
Carbazole
X
X
ND
NA
ND
Di-n-butyl phthalate
X
X
ND
NA
ND
Fluoranthene
X
X
X
NA
X
Pyrene
X
X
X
NA
X
Benzyl butyl phthalate
X
X
ND
NA
ND
Benzo(a)anthracene
X
X
X
NA
X
Chrysene
X
X
X
NA
X
bis(2-
ethylhexyl)phthalate
X
X
ND
NA
ND
di-n-octyl phthalate
X
X
ND
NA
ND
Benzo(b)fluoranthene
X
X
X
NA
X
Benzo(k)fluoranthene
X
X
X
NA
X
Benzo(a)pyrene
X
X
X
NA
X
Indeno( 1,2,3-c,d)pyrene
X
X
X
NA
X
Dibenzo(a,h)anthracene
X
X
NA
X
Benzo(g,h,i)perylene
X
X
X
NA
X
-------
Table 6-1 (Continued)
Sediment Contaminants Comparison - Pesticides/PCBs
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
Analyte
Sludge
Drying
Bed
Incinerator
Ditches
Washrack
Boundary Canal,
reservoir, or
Military Canal
Gamma -BHC (lindane)
NA
NA
ND
NA
X
Heptachlor
X
X
ND
NA
X
Heptachlor epoxide
X
X
ND
NA
X
Dieldrin
X
X
ND
NA
ND
p,p'-DDE
X
X
X
NA
X
p,p'-DDD
X
X
X
NA
X
p,p'-DDT
X
X
ND
NA
X
Methoxychlor
X
X
ND
NA
ND
Endrin ketone
X
X
ND
NA
ND
Endrin aldehyde
X
X
NA
NA
ND
Chlordane Constituents
X
X
X
NA
X
Toxaphene
ND
X
ND
NA
X
PCB (1260 or 1254)
X
X
X
NA
X
Silvex
NA
NA
X
NA
X
-------
Table 6-1 (Continued)
Sediment Contaminants Comparison - Metals
Military Canal Special Study
Homestead Air Force Base, Florida
November, 1997
Analyte
Sludge
Drying
Bed
Incinerator
Ditches
Washrack
Canal Sediment
Antimony
X
X
X
NA
X
Arsenic
X
X
X
NA
X
Barium
X
X
X
NA
X
Beryllium
X
X
X
NA
X
Cadmium
X
X
X
X
X
Chromium
X
X
X
X
X
Copper
X
X
X
X
X
Lead
X
X
X
X
X
Mercury
X
X
X
X
X
Nickel
X
X
X
ND
X
Silver
X
X
X
NA
X
Zinc
X
X
X
X
X
ND - Non Detect NA - Not Analyzed
-------
TABLE 6-2
CHEMICALS USED IN SOUTH DADE CANALS
1973-1995
MILITARY CANAL SPECIAL STUDY
HOMESTEAD AIR FORCE BASE
C-102
C-102N
C-103
C-103N
C-103S
Military
Canal
Surface Area (Acres)1
GO
H
CO
9.0
99.8
27 .7
11.6
5.8
(Approx.)
Chemical
Aquathol/H-191 (gals)
5477.5/67.0
1381/153.4
4723.5/47.3
811.75/29.3
109/9.4
0.0/na
Hydout/H-191 (lbs.)
0.0/na
0.0/na
1260/12.6
484/17.5
0.0/na
0.0/na
Banvel (gals.)
794/9.7
66/7.3
894.5/9.0
411/14.8
134/11.6
127/22.03
Diquat (gals.)
582.9/7.1
159/17.7
1186.9/11.9
427.25/15.4
17/1.5
3/0.5
Rodeo (gals.)
1402.3/17.1
132.25/14.7
1465.55/14.7
983/35.5
211.5/18.2
57.5/9.9
Roundup (gals.)
600/7 .3
57/6 . 3
225/2.3
112/4.0
85/7.3
33/5.7
Casaron (lbs.)
750/9.2
0.0/na
0.0/na
2845/102.7
300/25 . 9
0.0/na
Dowpon (lbs.)
7336/89.7
565/62 . 8
7300/73.1
1115/40.3
1345/115.9
390/67.2
2,4-D (gals.)
511.6/6.2
27/3.0
358.6/3.6
733/26.5
63/5.4
17/2 . 9
Silvex (gals.)
68.5/0.8
6.5/0.7
81/0.8
2/0.07
0.0/na
34.7/6.0
Copper (gals.)
1666.5/20.4
481/53.4
2940.1/29.5
1566/56.5
18/1.6
0.0/na
Diesel (gals.)
4561.5/55.8
500.1/55.6
4689.7/47.0
1529.6/55.2
567 .6/48.9
600/103.4
Inverted Oil (gals.)
1692.7/20.7
318.4/35.4
1440.3/14.4
453.2/16.4
120.4/10.4
113 .2/19.5
Note: Many more management chemicals are,given in the original records. These were selected based upon
consideration of the frequency and duration of use, and the amounts used.
Information on surface areas provided by the SFWMD, Homestead Field Station
------- |