PHYSICAL - CHEMICAL TREATMENT
OF RAW WASTEWATER
Presented by David R. Evans
Advanced Waste Treatment Project Engineer
CH2M/HILL
Corvallis, Oregon
Prepared for Environmental Protection Agency
Technology Transfer Seminar
October 31, November 1-2, 1972
Denver, Colorado
CM
r
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PHYSICAL-CHEMICAL TREATMENT
OF RAW WASTEWATER
By
Gordon Culp*
L. Gene Suhr*
David R. Evans*
INTRODUCTION
Much work, as illustrated by the referenced papers (1 through 9),
has been done recently to evaluate the feasibility of applying
physical-chemical treatment techniques, such as chemical coagula-
tion, filtration and activated carbon adsorption, directly to raw
wastewaters or primary effluents to eliminate entirely the need
for biological processes. Chemical coagulation and filtration
are used to remove the raw wastewater suspended matter, whereas
activated carbon is used to adsorb the remaining soluble organics.
Phosphorus removal normally occurs with chemical coagulation. If
nitrogen removal is also required, physical-chemical processes such
as ion exchange and break-point chlorination are adaptable to the
Rocky Mountain climatic conditions. Special sludge disposal and
recovery considerations, dissimilar to biological systems, are
included in the physical-chemical approach.
The purpose of this paper is to discuss typical design parameters
for the unit processes involved in physical-chemical treatment of
raw wastes and how the design engineer may determine the design
criteria best suited for a given wastewater. The emphasis of the
paper will be directed toward those processes particularly suited
to smaller cities and cold climates.
*
The authors are respectively; Manager, Eastern Regional Office
CH2M/HILL, Reston, Virginia; and Director and Project Manager,
Advanced Waste Treatment Group, CH2M/HILL, Engineers, Planners,
and Economists, 1600 Western Boulevard, Corvallis, Oregon.
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TREATMENT REQUIREMENTS
For purposes of providing an illustrative example, the raw waste
characteristics and effluent requirements shown in Table 1 have
been assumed. The effluent requirements should not be considered
as recommended levels for any particular location.
TABLE 1
WASTEWATER CHARACTERISTICS AND EFFLUENT
QUALITY REQUIREMENTS
INFLUENT, DESIRED EFFLUENT,
MEAN ANNUAL MEAN MONTHLY
(mg/l)	(mg/l)
BOD	180 15
COD	520 30
SUSPENDED SOLIDS	250 10
HARDNESS, AS CaCOg	170.5
PHOSPHORUS, TOTAL	11.5 1
PHOSPHORUS, ORTHO	10
NITROGEN, TOTAL	20 5
NITROGEN, AMMONIA	15
ALKALINITY AS CaCOg	220
The effluent standards cannot be met with secondary treatment
alone as chemical coagulation would be required to meet the
phosphorus standard and, at least, filtration of a secondary
effluent to meet the BOD and SS requirements. On the other hand,
the effluent standards are not so stringent as to require for
certain that physical-chemical techniques must be used in series
with biological treatment.
A design engineer faced with the above situation should conduct
the tests necessary to determine if these standards could be met
by physical-chemical treatment alone and, if so, what design
criteria should be used. The unit processes involved are proven
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to the degree that extensive, on-site pilot tests are not normally
necessary for most wastewaters and design criteria can usually be
obtained in laboratory tests. Should on-site pilot studies be
necessary, pilot equipment for liquid and solids handling studies
is available from several sources including consultant groups
and equipment manufacturers.
PRELIMINARY DATA COLLECTION
In order to proceed with the design on a rational basis, a
characterization of the raw wastewater in terms of its amenability
to physical-chemical treatment must be made. The following
description of tests on a wastewater illustrate techniques which
may be used.
The goals of these tests are to answer the following major
questions which must be known before the design can proceed:
0 What is the best coagulant?
° How much sludge is produced?
° How well does the sludge dewater?
° Is coagulant recovery practical?
° What is the particulate, colloidal, soluble, and non-
adsorbable fraction of organics in the raw wastewater?
° What is the fraction of soluble organic phosphorus
and nitrogen in the raw wastewater?
° How much carbon contact time will be required?
° What effluent quality can be expected?
Physical-chemical processes are limited in their ability to re-
move colloidal and non-adsorbable organics, and soluble organic
phosphorus and nitrogen. If these latter constituents are present
in high concentrations, various combinations of biological/
physical/chemical treatment may be required.
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CHEMICAL TREATMENT
Selection of Coagulant
There are four major classes of coagulants which may be considered
singularly or in combination:
1.	Polymers. Some investigators have reported successful
coagulation of raw sewage with polymers alone. When
used as the primary coagulant, polymers do not provide
phosphorus removal. One of the following inorganic
coagulants is required if phosphorus removal is of
concern. Polymers used in conjunction with an in-
organic coagulant are effective settling and filtration
aids.
2.	Iron Salts. Ferric chloride or ferric sulfate may be
used for both suspended solids and phosphorus removal.
Experience has shown that efficient phosphorus removal
requires the stoichiometric amount of iron (1.8 mg/1 Fe
per mg/1 of P) to be supplemented by at least 10 mg/1
of iron for hydroxide formation. Typically, 15-30 mg/1
as Fe is required to provide phosphorus reductions of
85-90 percent. When considering iron for coagulation
of raw wastes, it must be remembered that in an anaerobic
environment, as may be encountered in a downstream
carbon column, iron sulfide may be formed. This black
precipitate is obviously not desirable in the final
effluent. Depending on the iron salt, the optimum pH
for coagulation or phosphorus removal will vary between
4.5 and 8.0.
3.	Aluminum Salts. Both aluminum sulfate (alum) and sodium
aluminate have been used for coagulation of wastewaters.
Alum is generally a much more effective coagulant than
sodium aluminate. Alum doses of 200-300 mg/1 are
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typically required for 85-90 percent phosphorus removal
(22 mg/1 alum per mg/1 phosphorus). Disadvantages of
both iron and aluminum salts are (1) both form gelatinous
hydroxide floes which are difficult to dewater in many
cases; (2) no practical techniques are yet available
for recovery and reuse of the coagulant when phosphorus
removal is required; and (3) large amounts of anions
(chlorides or sulfates) are added to the wastewater.
The optimum pH will vary between 5.5 and 8.5.
4. Lime. Lime has been successfully used in several locales
for wastewater coagulation and phosphorus removal. The
amount of lime required is usually independent of the
amount of phosphorus present; rather it is a function of
the wastewater alkalinity and hardness. When the pH
reaches 9.5 to 10.5 due to the addition of lime, the
orthophosphate is converted to an insoluble form. In
some cases, additional quantities of lime may be re-
quired to form a readily settleable floe. Lime has
been recalcined and reused in some cases when used to
coagulate secondary effluent. However, recalcining
and reuse may often not be practical when it is used
to coagulate raw wastewaters due to the large amount
of inert materials present in the combined raw
sewage-chemical sludges. In any case, lime sludges
nearly always dewater more readily than those resulting
from iron or aluminum coagulation.
The choice of coagulant can usually be made rather quickly by
laboratory jar tests. The following illustrative example is based
on data collected on a raw wastewater from a community in the
midwest.
In the technique used, six one-liter samples are dosed with the
coagulants being studied while being rapidly mixed with a jar
test device. In this example, 0.5 mg/1 of an anionic polymer was
added as a settling aid. Following a 60-second rapid mix (100 rpm),
the samples are slowly mixed for about 5 minutes (30-40 rpm). They
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are then allowed to dynamically settle (5 rpm) for 30 minutes.
Samples of the supernatant are then obtained by a pipette from a
point just below the liquid surface in the jar. This is done to
avoid including any of the floating solids which are invariably
found in raw sewage. This supernatant sample is then analyzed
for turbidity and phosphorus.
Lime Coagulation. By plotting the jar test data, it was
determined that the lime dosages required to achieve a phosphorus
concentration of one mg/1 was less than that required for optimum
coagulation and suspended solids removal. One mg/1 phosphorus
was achieved at a pH of 10.5-11.0. The lime dosage required for
optimum solids removal varied from 200-400 mg/1. In general, a
somewhat higher dose of lime was required for optimum solids
removal than was required for phosphorus removal. A lime dose of
400 mg/1 as Ca(0H)2 achieved adequate solids removal for all samples
and this dose will be used in subsequent calculation of the cost of
lime coagulation.
Suspended solids analyses showed that settled supernatant con-
tained less than 5 mg/1 suspended solids at this dose and the
filtered supernatant generally contained no measurable suspended
solids. The lime and polymer dosage produced a rapidly settling
floe, as it does in most wastewaters.
Alum Coagulation. The alum dosages required to achieve a
phosphorus concentration of one mg/1 averaged 200 mg/1.
Adequate solids removal was achieved at alum doses equal to
or less than that required for phosphorus removal.
Iron Coagulation. The ferric chloride dosages required to achieve
a phosphorus concentration of one mg/1 averaged 80 mg/1. Adequate
solids removal was achieved at ferric chloride dosages less than
that required for phosphorus removal.
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Once the proper chemical dose is obtained, the test is repeated
at that dose. The supernatant sample is then analyzed for
suspended solids, COD, BOD, pH, turbidity and, if required,
organic nitrogen and ammonic nitrogen. The supernatant from
the lime jar tests should be recarbonated to pH 6.5-8.5 before
performing the above analyses.
Past experience has shown that the filtrate quality (Whatman No. 2)
obtained with filter paper will be about the same as that which
will be achieved when mixed media filtration is applied after
chemical clarification.
The ultimate choice of chemical will depend on the chemical cost,
the amount of sludge produced, and the method of sludge disposal
or recovery.
Chemical Costs
The approximate chemical costs, f.o.b. Seattle, are illustrated
in Table 2.
TABLE 2
APPROXIMATE CHEMICAL COSTS
F.O.B. SEATTLE
CHEMICAL
UNIT
UNIT
COST CHEMICAL
PER LB. DOSE
COST PER
MG
LIME
50 LB. Ca(OH)2
SACK
$0,025
400
$ 80
ALUM 100 LB. DRY ALUM $0,075
SACK
200
$120
FERRIC 350 LBS. FeClg
CHLORIDE	DRUM
$0.20
80
$130
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Chemical Process Design
Preliminary Treatment. Comminution and grit removal facilities
designed in accordance with standard sewage treatment design
practices should be provided.
Chemical Feed, Rapid Mix, and Flocculation. These functions may
all be carried out in accordance with standard practices followed
in the water treatment field for years.
Proper rapid mixing is important for efficient utilization of the
coagulating chemicals. The use of a mechanical rapid mixing
device in the basins with a total of 2 minutes detention time
at the average flow is recommended. When using lime as coagulant,
scaling of the mixer shaft will occur and may cause excessive
bearing wear if not cleaned regularly.
A mechanically mixed flocculator with 15 minutes detention is
generally adequate for wastewaters. In many cases, the floccula-
tion resulting from the large coagulant doses added to waste-
waters results in very rapid flocculation and even shorter
detention times may be feasible. Provisions should be made to
add up to one mg/1 polymer at the rapid mix or at the flocculator
inlet or outlet or split among these points.
Clarifier Sizing. The critical design parameter is the peak hourly
surface overflow rate. Gross carryover of solids can cause the
downstream filter or adsorption processes to fail due to excessive
headloss which, in turn, will result in a total failure of the
2
plant. A maximum peak hourly rate of 1,40 0 gpd/ft for conven-
tional horizontal or radial flow clarifiers is recommended when
using lime as a coagulant unless pilot tests indicate that other
2
rates should be used. A maximum average rate of 900 gpd/ft is
recommended.
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Several attempts have been made to use sludge blanket type
clarifiers on coagulated primary or secondary effluents. Difficulty
in holding a sludge blanket has been reported in many cases. Suc-
cessful operation has been achieved with these units by lowering
the overflow rate to conventional clarifier rates and eliminating
the sludge blanket.
Provision should be made for recirculation of controlled amounts
of sludge from the bottom of the clarifier to the rapid mix inlet.
The high pH of lime-treated water will form deposits of calcium
carbonate on structures and in pipelines which it contacts. Lime
sludge suction lines should be glass lined to facilitate cleaning.
Provisions must also be made for regular cleaning of all other
pipelines which carry the high pH effluent. Use of the new
polyurethane cleaning pigs should be compatible with the layout
of the pipelines. Mechanical sludge collection equipment used
in lime settling basins should be of the bottom scraper type
rather than the vacuum pickup style because of the dense sludge
to be handled.
pH Adjustment. Lime treatment of wastewaters for phosphorus
removal often raises the pH to values of 10-11. At this pH, the
water is unstable and calcium carbonate floe will precipitate
readily. This floe is very tenacious and would encrust any down-
stream filters or carbon particles to a serious degree. The
pH may be lowered by injecting C02 gas obtained from the inciner-
ator stack gases or from special generation equipment.
It is possible to reduce the pH of a treated wastewater from 11 to
7 or to any other desired value in one stage of recarbonation.
Single-stage recarbonation eliminates the need for the intermediate
settling basin which is used with two-stage systems. However,
by applying sufficient carbon dioxide in one step for the total
pH reduction, little, if any, calcium is precipitated with the
bulk of calcium remaining in solution, thus increasing the cal-
cium hardness of the finished water. Until equipment is available
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to separate raw organic sludge from the lime sludge, 2-stage re-
carbonation and lime recovery is probably not practical. The
theory of 2-stage recarbonation is discussed by Culp and Culp .
Alum or iron coagulation may also require pH adjustment. The
optimum pH for coagulation with these metal salts can vary between
pH 4.5 and 8.5. Depending on the raw waste characteristics and
the discharge standards, pH adjustment may be required both before
and after coagulation. Lime, caustic, soda ash have been used to
raise the pH. Whereas, mineral acids or carbon dioxide have been
used to lower the pH.
FILTRATION
Whether or not filtration is needed prior to activated carbon
adsorption is subject to debate. There is little question that
filtration ahead of a downflow granular carbon adsorption bed will
reduce the rate at which the pores of•the activated carbon become
plugged with inert materials. Also, the use of an efficient
filter permits downstream use of upflow, packed carbon beds which
'may be operated in the more efficient countercurrent mode dis-
cussed later. The question is whether or not the cost of provid-
ing the filtration exceeds the benefits mentioned above. Only
long-term operating data from plants using granular carbon with
and without prior filtration will answer this question. In the
interim, a conservative design will include filtration prior to
carbon adsorption. In addition to protecting carbon pores from
plugging by inerts, filtration also provides a more efficient
means of solids removal than carbon alone, resulting in a higher
effluent quality.
Filtration equipment is available which will provide simple,
reliable, and automatic operation. Carbon is not a particularly
effective filter because it acts as basically a surface type
filter and as such, is subject to all the shortcomings of other
surface filters applied to wastewaters. Any high solids loading
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will blind a surface type filter in short order. The use of dual
media or mixed, tri-media filters provides a much more efficient
filtration device which is capable of tolerating a much higher
solids loading than is a surface type filter. A discussion of
alternate filtration devices and a detailed discussion of filter
system design are discussed by Culp and Culp^1^.
In instances where an upflow expanded bed carbon contactor is
used, the filter may be located downstream of the carbon column
to remove the bacterial floe which is flushed from the carbon.
For the removal of the trace amounts of chemical floe which one
will expect from the chemical clarifier, a properly designed dual
media or mixed tri-media bed may operate at rates of 5-10 gallons
2
per minute per square foot. The use of 5 gpm/ft will provide a
conservative basis for design. Surface wash is a must when filter-
ing sewage.
The remaining question is whether the filter structure should be
of the gravity or pressure type. The pressure system offers
significant advantages in wastewater applications. In many in-
stances, the applied solids loading will be higher and more
variable than in a water treatment application. Thus, it is
desirable to have higher head available than practical with
gravity filter designs, preferably up to 20 feet of head when
2
operating at 5 gpm/ft . In many physical-chemical treatment
processes, the filtration step will be followed by a granular
carbon adsorption step. The filter effluent from the pressure
filter can pass through the downstream carbon columns without
having to be repumped, often eliminating a pumping step which
would be required with a gravity filter. All filter wash waters
must be reprocessed in sewage applications. The use of the pressure
filter will reduce the amount of wash water because of its ability
to operate to higher headlosses.
The backwashing of the filter is accomplished by reversing the
flow at a rate of 3-4 times the normal through-put rate of 5
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2
gpm/ft . Direct return of the wash waters directly to the head
of the plant would create a very substantial hydraulic surge
which may cause the upstream clarifier to fail. Therefore, the
backwash wastewater should be collected in a storage tank and
recycled to the head of the plant at a controlled rate. The
surge storage tank should be sized adequately to handle suc-
cessive backwashes from two to three filters.
It is desirable to precede the filtration step with a flow equali-
zation pond so that the filters may be operated at essentially
a constant rate. Provisions should be made for a feed of polymer
or alum directly to the filter influent as a filter aid. Filter
effluent turbidity and head loss should be monitored continuously
with high filter head loss being used to initiate an automated
backwash program. Polymers (0.1 - 1.0 mg/1) will probably be most
effective when used on waste streams coagulated with iron or
aluminum salts. Whereas alum (5-20 mg/1) will probably be the
choice when following lime coagulation.
CARBON ADSORPTION
General
There are organics (i.e., sugars) which may be readily biodegrad-
able but which are very difficult to adsorb on carbon. The amount
of these nonadsorbable materials will vary greatly from wastewater
to wastewater and their presence will be the governing factor
concerning the quality of effluent which can be achieved by
carbon adsorption. The same physical-chemical process may produce
a BOD of 10 mg/1 in one. locale and 30 mg/1 in another due to
this fact.
Carbon Evaluation
A quick method for determining the nonadsorbable fraction of
organics consists of contacting chemical treated wastewater with
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1000 mg/1 dose of a powdered carbon for one hour. Alternately,
a sample of the granular carbon under consideration may be ground
and applied to the sample. The sample is then settled and the
supernatant filtered through Whatman No. 2 filter paper prior to
analysis. The analyses should include the BOD and COD tests.
The column tests may be conducted using a granular carbon in
five 3/4-inch diameter columns in series. The columns are
sized so that cumulative contact times of 7.5, 15, 30, 45, and
60 minutes are provided at the end of the respective columns.
Four to five gallons of raw sewage are coagulated with either lime,
iron, or alum, settled, the supernatant decanted (the pH adjusted
as required), and the clarified wastewater pumped through the
columns. This quantity of sewage will provide several days of
operation in columns of this size. The tests should be continued
as long as possible to accurately determine the effects of bio-
logical activity.
The reasons for preferably conducting both the powdered carbon
and column tests are to determine if the effluent from the columns
could be lower in BOD than that achieved by adsorption alone
due to the biological growth in a column and to determine the
effects of contact time on column performance.
Figures 1 and 2 summarize the data collected from the laboratory
columns for the midwestern waste. As can be seen from the
figures, the benefits achieved by contact times greater than 30
minutes are slight. The carbon column effluent BOD values after
60 minutes contact ranged from 5 to 15 mg/1 and averaged 11.0 mg/1.
The BOD samples collected at a 30-minute contact time averaged 12.5
mg/1.
An estimate of the required carbon dosage can be made by assuming
that carbon will be withdrawn for regeneration when the carbon
loading is 0.5 pounds of COD removed per pound of carbon. This
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30
20
10 -
20 -
O
CO
DC
<
o
o
<
U
e 10
<
H
o
I-
20 -
10
DAY 1
DAY 2
DAY 3
0	20	40	60
CARBON DETENTION TIME, MIN.
30
20
10
O
CO
o
CJ
<
o
g 10
<
l-
O
20
10
0
\_
V
DAY 8
DAY 10
DAY 14
DAY 22
_L
-O,
'X-
_L
20	40	60
CARBON DETENTION TIME, MIN.
FIGURE 1
PILOT CARBON COLUMN DATA
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100
DAY 1
DAY 14
DAY 22
DAY 22
<
LU
DC
CJ
o
H
DAY 14
DAY 1
30
7.5
15
30
45
60
CARBON CONTACT TIME, MINUTES
FIGURE 2
PILOT CARBON COLUMN DATA
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loading has been achieved in several studies. An average soluble
influent COD of 86 mg/1 was achieved with lime clarification in
the four series of jar tests. The average COD achieved in the
four powdered carbon tests was 23 mg/1 and averaged 24 mg/1
after 30 minutes contact in the columns. Thus, an average
COD removal of about 62 mg/1 would be expected from these tests.
The corresponding carbon dosage is 1,0 30 pounds/mg. Carbon
dosages calculated from short-term laboratory column tests are
usually conservatively high, as biological action usually results
in greater permissible loadings in a continuous, plant scale
operation.
Process Design
Adsorption. Because of the unproven economics of recovery and
reuse of powdered carbon, the use of granular carbon is the only
current practical technique available, except for very small
systems, for removal of soluble organics from coagulated raw
wastewater. Granular carbon recovery has been demonstrated at
(11)
Pomona, California, to be practical at 0.3 mgd
With powdered carbon the grain size increases the kinetics of
adsorption such that 90% of its adsorption equilibrium is attained
in less than 10 minutes. Powdered carbon is dosed in slurry
form, after which it is separated by sedimentation following polymer
flocculation and/or filtration. Powdered carbon has the advantage
over granular in that its initial cost is about 1/3 as great.
Determination of the technical and economic feasibility must
await the result of contracts with Eimco Corp. and Infilco.
The major design decisions facing the engineer are the selection
of a contact time, carbon dosage, and the configuration of carbon
contactor to be used.
The two major alternate contactor configurations to consider are
open vessels of either an upflow or downflow type or upflow or
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EFFLUENT
MANIFOLD
EFFLUENT
RATE-OF-FLOW
CONTROL JL
VALVE -OPEN
FINAL
EFFLUENT
CARBON COLUMN
BYPASS VALVE
CLOSED
CARBON COLUMN
(TYPICAL)
INFLUENT
INFLUENT
MANIFOLD
3-WAY VALVE
X CLOSED
CARBON COLUMN
INFLUENT HEADER
VALVE-OPEN
3-WAY VALVE
INFLUENT
HEADER
WASTE
AND
DRAIN LINE
FIGURE 3
TYPICAL ARRANGEMENT FOR UPFLOW,
COUNTER CURRENT CARBON CONTACTOR
(FROM CULP & CULP)
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INFLUENT
WASTE
WASTE
BACKWASH
CARBON
COLUMN
A
CARBON
COLUMN
BYPASS
WASH WATER
SUPPLY
TO CARBON
RECLAMATION
PIPING DIAGRAM
U—00-
EFFLUENT
FILTER TO
'WASTE
COL.
COL.
FIRST
FLOW A TO B,
RENEW CARBON IN A
THEN,
FLOW B TO A,
RENEW CARBON IN B
THEN,
FLOW A TO B, AND
- CYCLE IS COMPLETE
COL.
COL.
FIGURE 4
TWO DOWNFLOW CARBON CONTACTORS IN SERIES
(FROM CULP & CULPI
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downflow counter-current pressure columns. The counter-current
approach (see Figure 3) offers a more efficient utilization of the
carbon as only the most saturated carbon is withdrawn for genera-
tion. This results from the fact that as the carbon becomes satura-
ted with organics, it becomes heavier. When the carbon column
is backwashed, the more saturated, heavier carbon migrates to the
bottom of the column where it is withdrawn for regernation.
A semi-counter-current approach can also be achieved by using
two downflow columns in series. As indicated on Figure 4, water
is first passed down through Column A, then down through Column
B. When the carbon in Column A is exhausted, the carbon in Column
B is only partially spent. At this time, all carbon in Column A
is removed for regeneration, and is replaced with fresh carbon.
Column B then becomes the lead column in the series. When the
carbon in Column B is spent, the carbon is removed for regenera-
tion and is replaced with fresh carbon. This type of operation
gives only some of the advantages of counter-current operation,
because only the carbon near the inlet of the lead bed is fully
saturated with impurities removed from the water, and some capa-
city is unused in much of the rest of the carbon sent to regenera-
tion. Also, the piping and valving is more complex and costly
than for an upflow, counter-current column. Unless one is at-
tempting to use the carbon for the dual purpose of filtration and
adsorption (which the author does not recommend for most cases),
there is no advantage to using the downflow approach while there
are the disadvantages discussed above.
The choice of contactor design is also dependent upon the method
selected for control of hydrogen sulfide .generation in the carbon
columns. The upflow, expanded bed with a downstream filter has
been used with injection of oxygen into the carbon influent for
hydrogen sulfide control. The prolific biological growth re-
sulting from this approach would result in excessive head loss
in a downflow, packed bed. Frequent backwashing of a downflow,
packed bed has been reported effective at Rocky River in con-
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trolling hydrogen sulfide. Also, breakpoint chlorination, prior
to downflow beds, although expensive, has been reported effective
at Blue Plains in controlling hydrogen sulfide. References 1
through 7 provide additional information on hydrogen sulfide genera-
tion and control.
The technology transfer manuals published by EPA and the book by
Culp and Culp^^^ present detailed carbon contactor design alter-
nates. However, there are a few other points related to contactor
design which I would like to call to your attention in addition
to the comments above.
When using steel contactors, it is imperative that the interior
be properly protected from the very corrosive effects of partially
dewatered activated carbon. Two 8-mil thick coatings of a coal
tar epoxy have proven to be effective at Tahoe over 4 years of
continuous operation. Fiberglas-polyester coatings would also be
effective, although more costly than the coal-tar epoxy coatings.
Another point to consider is the effect of the pH, of the upstream
coagulation step, on the efficiency of the carbon process. One
available process is based on a claim that use of extremely high
pH (11.8 - 12.2) in the lime coagulation process will hydrolyze
some organic materials making them more readily adsorbable.
Before one incurs the disadvantages of the high pH approach
(massive quantities of sludge plus greatly increased carbon
dioxide requirements for pH adjustment), he should carefully
evaluate the effects of pH on the specific wastewater involved.
Carbon Regeneration. As granular activated carbon adsorbs
organics from wastewater, the carbon pores eventually become
saturated and the carbon must be regenerated for reuse. The
best way to restore the adsorptive capacity of the carbon is by
means of thermal regeneration (by heating the carbon in a low-
oxygen steam atmosphere in a multiple-hearth furnace). At
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temperatures of 1,650-1,750 degrees F, the dissolved organics
are volatilized and released in gaseous form. The regenerated
carbon is cooled by water quenching. By proper treatment, carbon
can be restored to near virgin adsorptive capacity while limiting
burning and attrition losses to 5-10 percent. Regeneration
furnace off-gas odors can be controlled by after-burning, if
necessary, and particulates and soluble gases can be removed
by use of Venturi or jet impingement type scrubbers. Figure 5
illustrates a typical regeneration system.
The carbon furnace should be sized with recognition of the fact
that substantial downtime may be required for maintenance of the
furnace. An allowance of 40 percent downtime in selecting the
furnace size provides a conservative basis for furnace selection.
NITROGEN REMOVAL
Ammonia Removal by Selective Ion Exchange
A demonstration project at the Battelle Memorial Institute -
Pacific Northwest (Hanford) Laboratories, 19 69 showed that
certain zeolites, including the naturally occurring mineral
clinoptilolite, had a high selectivity for ammonium in natural
and wastewaters.
Clarifier effluent is passed downward through columns containing
clinoptilolite. When a column becomes loaded with ammonia, it
is regenerated with limewater containing sodium chloride to
speed up the rate of regeneration. The high pH of the limewater
converts the ammonium ion to ammonia gas in solution. The
ammonia laden limewater is then pumped through a packed column
through which heated air is blown to remove the ammonia.
Ammonia in the regenerant solution may also be converted to nitro-
gen gas by reaction with chlorine which is generated electrolytically
-21-

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SPENT CARBON FROM
CARBON COLUMNS
SPENT CARBON DRAIN
AND FEED TANKS
SCREW
CONVEYORS
CARBON
REGENERATION
FURNACE
MAKEUP
CARBON
CARBON
SLURRY
PUMPS
QUENCH
TANK
CARBON
SLURRY BIN
REGENERATED CARBON
DE-FINING AND
STORAGE TANKS
CARBON SLURRY
PUMPS
REGENERATED CARBON
TO CARBON COLUMNS
FIGURE 5
ILLUSTRATIVE CARBON REGENERATION SYSTEM
(FROM CULP & CULPI
-22-
W7602.6

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from the regenerant solution. This process can be carried out
with a regenerant of neutral pH so that the problem of precipita-
tion of Mg(OH)2 and CaCO^ within the bed during regeneration
is eliminated. Also, cold weather does not affect the process.
The regenerant solutions used are rich in NaCl and CaC^ which
provide the chlorine produced at the anode of the electrolysis
cell. The reactions for the destruction of ammonia by chlorine
are the same as for breakpoint chlorination.
In pilot tests of the electrolytic treatment of the regenerant at
Blue Plains, Battelle Northwest found that about 50 watt hours of
power were required to destroy one gram of ammonia nitrogen. When
related to the treatment of water containing 15 mg/1 NH^-N, the
energy consumed would be 2.9 kWh/1,000 gallons. Thus, power
costs are not prohibitive. Overall costs for a 10 mgd plant
using the electrolytic technique were estimated at 12.7 cents/
1,000 gallons by Battele Northwest.
Effluent ammonia concentrations below 1 mg/1 are easily achieved.
Figure 6 illustrates the pilot tests at South Lake Tahoe.
Ammonia Removal by Breakpoint Chlorination
When chlorine is added to water containing ammonia-nitrogen, the
ammonia reacts with the chlorine (hypochlorous acid) to form
various chloramines.
Several investigators, including the author, have found that
breakpoint chlorination requires approximately 10 mg of chlorine
per mg of NH^-N. An alkaline material such as NaOH or CafOH)^
may have to be added in order to prevent pH depression and sub-
sequent nitrogen trioxide formation. Another consideration is
that a substantial increase in effluent chlorides will result from
the addition of such large quantities of chlorine.
-23-

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OPERATING CONDITIONS
FLOW RATES
ZEOLITE GRAIN SIZE
BED VOLUME
1 bv/hr 2 6.5 bv/hr 3 9 7 bv/hr
20 x 50 MESH
3
50 FT
11) 15 mg/l, (2) 17 mg/l, (3) 17 mg/l
TAHOE TERTIARY EFFLUENT
ftVG. INFLUENT NH^N:
FEED.
A CURVE 1
0 CURVE 2
OCURVE 3
80	100
BED VOLUMES
140
160
180
FIGURE 6
AMMONIA BREAKTHROUGH
CURVES FOR A 6 FT. CLINOPTILOLITE
BED AT VARIOUS FLOW RATES
W7602.6
-24-

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Tests at Blue Plains showed that eductors do not give adequate
chlorine-wastewater mixing, resulting in localized low pH regions
in which objectionable quantities of NCl^ form. Violent, mech-
anical mixing is required to minimize NCl^ formation. The NaOH
quantity added to neutralize the acidic effects of the chlorine
addition was 0.9-1.7 pounds of NaOH/Pound of chlorine, corres-
ponding to adjusting a pH of 6 to 7.9. One run was made with
lime, which indicated about one pound of lime would be required
per pound of chlorine for a pH of 7.0.
Breakpoint chlorination may be particularly well suited to small
treatment systems with part-time staffs.
The economics of the process are not attractive when removing
the relatively large quantities of ammonia found in an un-nitrified
effluent. For example, at a chlorine cost of 3.5 cents/pound
(which is the lowest cost one could anticipate), the cost of
chlorine to remove 15 mg/1 of ammonia nitrogen (150 mg/1 of chlorine)
would be $43.80/mg. According to the Blue Plains work, about 195
mg/1 of NaOH would also be required which would, at a cost of $70/
ton, add another $57/mg to the chemical cost. Thus, without
capital and labor costs, the cost of this approach is about $100/mg
using NaOH for pH control. If lime proves satisfactory for pH con-
trol, the chemical cost would be reduced substantially to about
$60/mg at a lime cost of $25/ton.
PHYSICAL-CHEMICAL TREATMENT
OF SMALL WASTE FLOWS
General
The basic unit processes discussed earlier are directly applicable
to any size treatment plant including the less than 500,000 gal/day
package plant range. A number of manufacturers are developing
or have developed package physical-chemical wastewater treatment
plants.
-25-

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Examples of different types of small physical-chemical processes
are discussed in the following paragraphs. Some of the information
has been taken from reference 13. Mention of commercial products
does not imply endorsement by the EPA or by ourselves.
Clarification-Filtration
Johns-Manville Corporation has developed a process referred to
as the "Moving Bed Filter". Figure 7 shows a schematic of the
process. Recently Peabody Wells has been marketing the process.
Raw waste is dosed with alum and an anionic polymer and flows
into a tank which provides head for the filter operation. The
sewage filters downward through the inclined packed bed of sand
to a screened pipe and thence flows to a collector. Sewage
solids and floe collect primarily on the filter face although
some depth filtration is obtained. When the head loss exerted
by the accumulated solids becomes excessive the sand bed is
pushed upward and a cutter slices off the top layers of sand
and suspended solids. The sand-sludge mixture is collected in the
bottom of the head tank and is then pumped to a sand washer.
Clean sand is returned to a hopper and eventually to the bottom
of the sand bed. At the time of the study report (reference 13)
the feasibility of adding powdered carbon was still to be evaluated.
Without carbon treatment BOD efficiency is limited to particulate
BOD removal.
Clarification-Carbon Treatment
A process employing the clarification and granular activated
*
carbon unit in series is the Met-Pro system. This system is a
package plant utilizing an upflow solids contact clarifier ahead
*
Met-Pro Water Treatment Company of Lansdale, Pennsylvania.
-2 6-

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COAGULANT
CUTTER
CLEAN SAND
HOPPER
SAND
RECYCLE
SAND DRIVE
SYSTEM

SAND-SLUDGE
WASH WATER
FILTERED WATER
SAND WASHER
DISCHARGE
WASTE WASH WATER
FIGURE 7
SCHEMATIC FLOW DIAGRAM OF THE MOVING BED FILTER
(AFTER JOHNS-MANVILLE) (13)

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of two-stage 12x40 mesh granular activated carbon treatment.
Different chemical coagulants have been evaluated by the EPA
(reference 13). The two-stage granular carbon system consists
of a downflow packed bed followed by upflow bed. Partially spent
carbon from upflow bed is used to replace the spent carbon in the
preceding downflow bed. Completely spent carbon from the downflow
bed is discarded.
Clarification-Filtration-Carbon Treatment
Two physical-chemical systems using clarification, filtration, and
activated carbon adsorption are the package units developed by
Neptune MicroFLOC ^ and AWT Systems Inc.^ The MicroFLOC
system employs powder activated carbon whereas the AWT System
uses granular activated carbon.
In the MicroFLOC system powdered carbon and a coagulant are
introduced into the raw waste stream just prior to coagulation.
The waste stream then flows through a two stage flocculator, in-
clined settling tubes for clarification, and through a mixed
(tri-media) filter. Alum or lime may be used as the primary
coagulant. With alum, a soda ash feed system is provided for pH
control. If lime is used, pH adjustment is provided following
the tube settlers. Polymer can be fed at both the flocculation
and filtration steps.
In the AWT System's physical-chemical unit a metal salt coagulant
and an acid-alkaline control additive are added to the raw waste
before coagulation. Following coagulation, a polymer is introduced
to improve clarification. The effluent from the clarifier is
treated with a magnetic additive and fed through a magnetic filter
for further solids removal. An upflow carbon contactor with
granular activated carbon is used after filtration to remove
dissolved organics.
Neptune MicroFLOC, 1965 S.W. Airport, Corvallis, Oregon.
(2)
AWT Systems Inc., 910 Market Street, Wilmington, Delaware.
-28-

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Sludge Production
It is difficult to obtain an accurate gravimetric measurement of
sludge quantities in a laboratory test due to loss of solids
during decanting, etc. However, it is possible to estimate the
quantities of sludge from the chemistry involved and the data
collected from the jar tests.
The basic equations required for these calculations may be
simplified as follows:
1.	3P03- + 5Ca2+ + OH1- —> Ca5 OtHPO^j,
2.	Mg2+ + 20H1"	Mg(OH)2l
3.	Ca2+ + CO2-	CaCC>3
180 n0 F	A
4.	CaC0_ 		>- CaO + C0„ r (incineration)
J a	2
5.	CaO + H20 —=» Ca(0H)2
6.	Al3+ + P03~ —> AlPO^
7.	Al3+ + 30H1- —A1(0H)3^
1400°F
8.	2A1(0H)., 	=> A1„0, + 3H„0 (incineration)
3	A	c 6	&
9.	Fe3+ + P03~ —> FePO^
10.	Fe3+ + 30H1"—> Fe(0H)3l
1400°F
11.	2Fe(OH).. 	Fe~0- + 3H„0 (incineration)
-3	A	£ 6	1
12.	E Coagulant in = Z Coagulant out
-29-

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Tables 3, 4 and 5 describe the computations used to estimate the
quantities of sludge produced. The total quantities of raw and
chemical sludges produced are:
0 Lime @ 400 mg/1 [Ca(0H)2] = 6290 lbs/mg
0 Alum @ 200 mg/1 [A12(S04)3 . 14H20] = 2648 lbs/mg
0 Ferric Chloride @ 80 mg/1 [FeCl^] = 2662 lbs/mg
Sludge Disposal
Sludge disposal is perhaps the most important factor governing
the choice of chemical coagulants. Unhappily, the least is
known about this particular facet.
Alum and iron sludges can normally be added to existing anaerobic
digesters. The higher digester loadings resulting from additional
sludge production will not usually be detrimental to operation
unless an organic overloading condition exists. Release of soluble
phosphorus from the sludge during digestion is considered to be
minimal. Final disposal of the digested sludge can be on land
or by dewatering and incineration.
Alum iron and lime sludges can be disposed of directly onto land.
Depending on temperature requirements, alum and iron sludges
could need lime treatment to prevent odors.
In larger systems sludge thickening or dewatering prior to
lagooning or incineration can be considered. Here the type of
sludge becomes important. Alum and iron sludges are much harder
and expensive to thicken or dewater than are lime sludges.
-30-

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TABLE 3
ESTIMATE OF LIME SLUDGE QUANTITIES
RAW SEWAGE SUSPENDED SOLIDS
RAW SEWAGE VOLATILE SUSPENDED SOLIDS
RAW SEWAGE PO^
RAW SEWAGE TOTAL HARDNESS
RAW SEWAGE Ca2+
RAW SEWAGE Mg2+
EFFLUENT P04
EFFLUENT Ca2+
EFFLUENT Mg'
2+
250 MG/L
150 MG/L
11.5 MG/L ASP
170.5 MG/L AS CaCOg
60 MG/L
5 MG/L
0.3 MG/L AS P
80 MG/L
0
LIME DOSAGE 400 MG/L AS Ca(OH>2
OR 216 MG/L AS Ca2+
FROM EO. (1); Cag0H(P04)3 FORMED IS 1 MOLE PER 3 MOLES P
ll2- = o 365 molES P REMOVED; THEREFORE 0 365 OR
30.97	3
0.122 MOLES Ca50H(P04)3 ARE FORMED - F.W. IS 502
THEREFORE WT. IS 0.122x502 = 61 MG/L AS
Ca50H(P04)3
FROM Ea (2); Mg(OH)2 FORMED IS 1 MOLE PER MOLE Mg2+
5 = 0.206; THEREFORE 0.206x58.31 = 12 MG/L AS
24.31	Mg(OH)-
FROM Ea (12);
Ca2+ IN = Ca2+ OUT; Ca2+ IN
.2+
60+216 = 276
Ca*T CONTENT OF Ca50H(P04)3 FORMED = 5x40x0.122 = 24 MG/L
Ca2+ LOST IN EFFLUENT = 80 MG/L. THEREFORE
Ca
2+
NOT ACCOUNTED FOR = 276 - (80+24) = 172 MG/L
2+
FROM Ea (3); CaCOg FORMED IS 1 MOLE PER MOLE Ca^
THEREFORE 172
40
4.3 MOLES CaCO,
F.W. = 100
SO WT. OF CaCO, = 430 MG/L
SLUDGE SPECIES
RAW SEWAGE SOLIDS
Ca5OH(P04)3
Mg(OH)2
CaCOg
TOTALS
SLUDGE COMPOSITION
TOTAL WEIGHT
250 MG/L = 2,080 LBS./MG
61 MG/L = 510 LBS./MG
12 MG/L = 100 LBS./MG
430 MG/L = 3,600 LBS./MG
6,290 LBS./MG
ASH
832 LBS./MG
510 LBS./MG
100 LBS./MG
2,020 LBS./MG
3,462 LBS./MG
-31-

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TABLE 4
ESTIMATE OF ALUM SLUDGE QUANTITIES
RAW SEWAGE SUSPENDED SOLIDS
RAW SEWAGE VOLATILE SUSPENDED SOLIDS
RAW SEWAGE P043-
RAW SEWAGE TOTAL HARDNESS
RAW SEWAGE Ca
RAW SEWAGE Mg'
EFFLUENT P04
EFFLUENT Ca2+
EFFLUENT Mg2+
EFFLUENT Al3+
ALUM DOSAGE
2+
,2+
200 MG/L AS AI2(S04)3 14 H20 - F.W.
250 MG/L
150 MG/L
11.5 MG/L AS P
170.5 MG/L AS CaC03
60 MG/L
5 MG/L
0.3 MG/L AS P
60 MG/L
5
0
594
FROM EQ. (6); = Al P04 FORMED IS 1 MOLE PER MOLE OF P;
11-2 = 0.365 MOLES P REMOVED; THEREFORE 0.365
30.97
MOLES OF Al P04 ARE FORMED- F.W. IS 122
THEREFORE WT. IS 0.365x122 = 44 MG/L
FROM EQ. (12);
18.1 MG/L
Al3+ IN = AL3+ OUT; Al3+ IN
Al3+ CONTENT OF Al P04 = 0.365x27 = 9.9 MG/L
Al3+ NOT ACCOUNTED FOR = 18.1 - 9.9 = 8.2 MG/L
3+
FROM EQ. (7); AI(OH)3 FORMED IS 1 MOLE PER MOLE Al
THEREFORE 8.2 = 0.3T MOLES AI(OH)Q - F
27"	J
SO WT. OF AI(OH)3 IS 0.31x78 = 24 MG/L
SLUDGE SPECIES
RAW SEWAGE SOLIDS
Al P04
AI(OH)3
TOTALS
SLUDGE COMPOSITION
TOTAL WEIGHT
250 MG/L = 2,080 LBS./MG
44 MG/L = 368 LBS./MG
24 MG/L = 200 LBS./MG
2,648 LBS./MG
ASH
832 LBS./MG
368 LBS./MG
133 LBS./MG
1,333 LBS./MG
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TABLE 5
ESTIMATE OF IRON SLUDGE QUANTITIES
RAW SEWAGE SUSPENDED SOLIDS
RAW SEWAGE VOLATILE SUSPENDED SOLIDS
RAW SEWAGE PO^
RAW SEWAGE TOTAL HARDNESS
RAW SEWAGE Ca2+
RAW SEWAGE Wig2"1"
EFFLUENT P04
EFFLUENT Ca2+
EFFLUENT Mg2+
EFFLUENT Fe3+
250 MG/L
150 MG/L
11.5 MG/L AS P
170.5 MG/L AS CaC03
60 MG/L
5 MG/L
0.3 MG/L AS P
60 MG/L
5
0
FeCI3 DOSAGE = 80 MG/L
FROM EQ. (9); FeP04 FORMED IS 1 MOLE PER MOLE P;
11 2 = 0.365 MOLES P REMOVED, THEREFORE 0.365
30.97
MOLES OF FeP04 ARE FORMED - F.W. = 151
THEREFORE WT. IS 0.365x151 = 55 MG/L
FROM EQ. (12); Fe3+ IN
.3+
Fe3+ OUT; Fe3+ IN
28 MG/L
FeJT CONTENT OF FeP04 = 0.365x55.8 = 20.4 MG/L
Fe3+ NOT ACCOUNTED FOR = 28 - 20.4 = 7.6 MG/L
FROM EQ. (10); Fe(OH)3 FORMED IS 1 MOLE PER MOLE Fe
THEREFORE 7.6 = 0.136 MOLES Fe(OHU -
55.8
SO WT. OF Fe(OH)3 = 0.136x107 = 15 MG/L
3+
SLUDGE SPECIES
RAW SEWAGE SOLIDS
FePO„
Fe(OH)3
SLUDGE COMPOSITION
TOTAL WEIGHT
TOTALS
250 MG/L = 2,080 LBS./MG
55 MG/L = 460 LBS./MG
15 MG/L = 122 LBS./MG
2,662 LBS./MG
ASH
832 LBS./MG
460 LBS./MG
105 LBS./MG
1,397 LBS./MG
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The following data (Table 6), although only an educated guess,
should serve to demonstrate the magnitude of the problem.
TABLE 6
PROBABLE SLUDGE CONCENTRATIONS
CHEMICAL
COAGULANT	% SOLIDS
GRAVITY THICKENING ALUM AND IRON	2-5
LIME	10-25
DEWATERING ALUM AND IRON	10-20
LIME	20-40
Sludge incineration, particularly for larger cities could
be an integral part of physical-chemical processes. The advantages
of converting organic solids to ash and thereby reducing the
weight and volume of solids cannot be ignored. Alum, iron and
lime sludges can be incinerated. The relative amounts of water
and solids described earlier control the incinerator size. Table
7 illustrates the weight reduction achieved by incineration.
TABLE 7
PHYSICAL-CHEMICAL
SOLIDS REDUCTION BY INCINERATION
DRY WEIGHT, LBS./MG
COAGULANT	BEFORE INCIN.	AFTER INCIN.
ALUM	2,648	1,333
IRON	2,662	1,397
LIME	6,920	3,462
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Generally speaking, only lime, of the three coagulants listed,
can be recovered using current technology. Even lime recovery
may not be economically practical when used to coagulate raw
wastewater. An effective means must first be found to separate
the lime from the inert.organic raw sewage ash.
Lime recovery involves the conversion of calcium carbonate to
carbon dioxide and calcium oxide (quick lime).
When lime recovery systems are employed, recycling solids neces-
sarily appear as a part of the reclaimed coagulant feed. Again
pursuing the previous example it may be seen from Table 3 that
if recalcination for coagulant reuse is employed, each cycle of
coagulant recovery will increase the total dry solids to be
processed by the amounts shown in Table 8.
TABLE 8
THEORETICAL BUILD-UP OF INERTS IN A
RECYCLING COAGULANT RECOVERY SYSTEM
MGT. OF
INERTS/CYCLE
PARAMETER	(LBS./MG)
ASH (FROM RAW SEWAGE SOLIDS)	832
HYDROXYAPATITE	510
MAGNESIUM HYDROXIDE	100
TOTAL INERTS/CYCLE	1,442
Following this line of reasoning then, unless blowdown of inerts
from the system occurs, regardless of plant size, coagulant
recovery systems must in time approach an infinite capacity.
Purely as a coarse approximation, equation (13) can be used to
illustrate this.
-35-

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eq (13) Feed = CaCO^ + Organics + [Inerts X (C-l)]
where CaCO^ = #CaCO^/mg
Note: eq (13) usable only for > 1 cycle
Organics = #Organiqs/mg
Inerts = #Inerts/mg
and C = the number of
cycles starting with
the initial feed as No. 1
Table 9 illustrates for our example what would occur at the 5th,
10th, and 20th cycle of such a system.
TABLE 9
INCINERATOR FEED RATES THEORETICALLY
REQUIRED FOR A NON BLOW DOWN COAGULANT
RECOVERY SYSTEM

FEED LB./MG
CYCLES
(DRY SOLIDS)
1
6,290
5
11,440
10
18,640
20
33,040
Clearly such a buildup of inerts as indicated in Table 9 is un-
acceptable in the design of solids handling systems. This has
spurred research into better techniques of separating or classi-
fying chemical sludges one from another. Several techniques for
reducing the buildup of inert solids within a coagulant recovery
system are available. These include the following:
0 Direct blowdown of unprocessed sludges
0 Blowdown of dewatered chemical sludges
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0	Classification of solids content
0	Chemical treatment of unprocessed sludges
0	Indirect blowdown of recovered coagulant
0	Combinations of the above methods
Regardless of the methodology employed for blowdown of unwasted
constituents, some fraction of inert materials will be present
as a recycle in any solids handling system employing coagulant
recovery and reuse. Therefore, the design engineer must be able
to determine what this fraction is as well as its characteristics
prior to design of a proper solids handling system. This is
most easily accomplished by calculation of mass balance under
conditions when equilibrium is reached in the system. In our
example system, from Table 3, equilibrium would occur when blow-
downs of inerts are:
20 80 #/rtig organics
510 #/mg hydroxyopatite
100 #/mg magnesium hydroxide
Continuing our example, assume a coagulant recovery system employing
the following unit processes is used:
Centrifugal dewatering and classification
Recalcination
Dry blowdown of 25% of calciner output
Assuming the following test results are available, calculate the
theoretical centrifuge feed, cake output, calciner output and
blowdown of solids required and enumerate by type:
Assume	30% of Hydroxyapatite is wasted in centrate
Assume	25% of Magnesium Hydroxide is wasted in centrate
Assume	25% of Organics are wasted in centrate
Assume	10% of Calcium Carbonate is lost in centrate
-37-

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Assume 10% of Ash is wasted in centrate
Assume 25% of Calciner output is blown down.
Solution:
eq (14) Apatite to waste = 0.3x + 0.25 (0.7x)
510 = 0.3x + 0.175X
= 1075 #apatite/mg reports in centrifuge feed
eq (15) Mag. hydx to waste = 0.25x + 0.25 (0.75x)
100 = 0.25x + 0.19x
= 227 #magnesium hydroxide/mg reports in centrifuge feed
feed
eq (16) organics to waste = 20 80 #/mg
This is wasted in two forms i.e., ash and organics
organic equivalent as ash = 0 .40 (2080) = 830 #/ing
centrate wasteage = 0.25 x 830 = 208 #/mg
622 #/mg remain and are wasted as ash
ash to waste = O.lx + (0.25) (0.9x) + (0.25) (622)
622 = O.lx + 0.225x + 156
= 1440 # of actual ash/mg report in centrifuge feed
eq (17) Calcium Carbonate to waste = O.lx + (0.25) (0.9x)
X = 3600 #/mg (from Table 1)
Calcium Carbonate wasted = 3600 x 0.325
= 1170 #/mg
By use of equations 14 through 17, Tables 10, 11, and 12 may be
constructed.
The example assumes that there will be a net positive blowdown
of the inert solids itemized in Table 12. The inerts cannot
be recycled.
-38-

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TABLE 10
THEORETICAL FEED, CENTRATE AND CAKE CONTENT AT
EQUILIBRIUM IN A COAGULANT RECOVERY SYSTEM
ALL SLUDGES EXPRESSED IN LBS./MG (DRY SOLIDS)
PARAMETER
CaC03
Ca5OH(P04)3
ORGANICS
ASH
Mg(OH),
CENTRIFUGE FEED
3,600
1,075
2,080
1,440
227
CENTRATE
360
323
520
144
57
CAKE
3,240
752
1,560
1,296
170
TABLE 11
THEORETICAL CALCINER OUTPUT AT EQUILIBRIUM
IN A COAGULANT RECOVERY SYSTEM
ALL PRODUCTS EXPRESSED IN LBS./MG (DRY SOLIDS)
PARAMETER
CaO
Ca50H(P04)3
ASH
Mg(OH)2
CALCINER OUTPUT
1,820
752
1,920
170
BLOWDOWN (25%)
455
187
480
43
REMAINDER TO REUSE
1,365
565
1.440
127
TABLE 12
COMPARISON OF INERTS ACTUALLY WASTED WITH
THEORETICAL INERTS WASTAGE REQUIRED AT EQUILIBRIUM
IN A COAGULANT RECOVERY SYSTEM
INERT
Ca50H(P04>3
Mg(OH)2
ASH
SOURCE OF WASTAGE
CENTRATE BLOWDOWN
323
57
208+144
187
43
480
TOTAL
510
100
832
THEORETICAL
REQUIRED
TABLE 3
TOTAL
510
100
832
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Table 13 compares solids handling and lime requirements for
solids handling system with and without lime recovery.
The arrangement of the calculations required to determine equali-
brium values for chemical sludges in the manner illustrated pro-
vides the design engineer with a concise tabulation of the amounts
of each type of sludge under any condition he may choose to investi-
gate. This in turn allows an orderly economic evaluation to be
made. The designer may choose to evaluate several alternative
methods of solids handling ranging from no recovery to sophisticated
recovery systems and can, therefore, make a sound decision. In
addition, the designer is assured that adequate capacity is
provided for the system's needs. Weak points in the system can
then be evaluated and standby capacity or redundancy added as may
be required or deemed advisable.
TABLE 13
SOLIDS HANDLING AND LIME REQUIREMENTS WITH OR
WITHOUT LIME RECOVERY AT EQUILIBRIUM
WITH LIME	WITHOUT LIME
RECOVERY	RECOVERY
SLUDGE FROM
PRIMARY CLARIFIER	8,422	6,920
LBS./MG
SLUDGE TO BE DISPOSED
OF ASSUMING	1,442	3,462
INCINERATION LBS./MG
MAKE-UP LIME
REQUIREMENTS	1,135	2,500
LBS. CaO/MG
-40-

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SUMMARY
Relatively simple techniques for determining the efficiency of
physical-chemical treatment of a given wastewater are available
and are described. A brief discussion of design criteria for
the major unit processes is presented. The phvsical-chemical
techniques can be applied to any size waste flow including flows
of less than 1 mgd. Examples of package physical-chemical units
are included in the paper. Finally, procedures for estimating
sludge production are illustrated.
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REFERENCES
I
1.	Rizzo, J. L. and Schade, R. E., "Secondary Treatment with
Granular Activated Carbon," Water and Sewage Works, p. 307
(August 1969).
2.	Anonymous, "Carbon Makes jDebut in Secondary Treatment,"
!
Environmental Science and Technology, p. 809 (1969).
3.	Kugelman, I. J. and Cohen, J. M. , "Chemical-Physical
Processes," presented at the Advanced Waste Treatment and Water
Reuse Symposium, Cleveland, Ohio (March 1971).
4.	Weber, W. , Hopkins, C. B.:, and Bloom, R. , "Phvsiochemical
Treatment of Wastewater,'' Journal Water Pollution Control
Federation, p. 83 (1970) .
5.	Shuckrow, A. J., Bonner, W. F., Presecan, N. L., and
I
Kazmierczak, E. J., "A Pilot Study of Physical-Chemical
Treatment of the Raw Wastewater at the Westerly Plant in
Cleveland, Ohio," (Unpublished, 1971).
6.	Bishop, D. F., et al, Session on the Blue Plains Advanced
Waste Treatment Pilot Plant, AIChE Meeting, Houston, Texas
(March 1, 1971) .
7.	"The Development of a Fluidized-Bed Technique for the
Regeneration of Powdered'Activated Carbon," Federal Water
I
Quality Administration Water Pollution Control Research
Series, ORD-17020FBD03/70 (March 1970).
8.	Shuckrow, A. J., Dawson,,G. W., and Olesen, D. E., "Treatment
of Raw and Combined Sewage," Water and Sewage Works, p. 10 4
(April 1971).
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9. Shuckrow, A. J., Dawson, G. W. , and Bonner, W. F., "Pilot
Plant Evaluation of a Physical-Chemical Process for Treatment
of Raw and Combined Sewage Using Powdered Activated Carbon,"
presented at the WPCF Annual Conference, San Francisco,
California (October 1971).
10.	Culp, R. L. and Culp, G. L., "Advanced Wastewater Treatment,"
Van Nostrand Reinhold, New York (19 71).
11.	English, J. N. et. al., "Removal of Organics from Wastewater
by Activated Carbon," (Water-1970), Chemical Engineering
Symposium Series, 67, 147-153, 1970.
12.	Wilson, Evans, Culp, and Moyer, "Phase I - Engineering Design
Report, Supplemental Ammonia Stripping with Further Nitrogen
Removal by Selective Ion Exchange and Breakpoint Chlorination,"
EPA Program #17010 EEZ, April 1970.
13.	Kugelman, I. J., W. A. Schwartz, and J. M. Cohen, "Advanced
Waste Treatment Plants for Treatment of Small Waste Flows,"
presented at the Advanced Waste Treatment and Water Reuse
Symposium, South Central Region, EPA, Dallas, Texas, January
12-14, 1971.
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