United States        Office of Research and     EPA-600/R-01-056b
        Environmental Protection     Development        July 2001
        Agency          Washington, DC 20460
&EPA   Environmental
        Impacts
        of the Use of
        Orimulsion®

        Report to Congress
        on Phase 1  of the
        Orimulsion® Technology
        Assessment Program

        Volume 2: Appendices B-H

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                                  Foreword
      The  U.S.  Environmental  Protection  Agency  is  charged  by Congress with
protecting the Nation's land, air, and water resources.  Under a mandate of national
environmental lavfs, the Agency strives to formulate and implement actions leading to a
compatible balan
3e between human activities and the ability of  natural systems to
support and nurture life.  To meet this mandate, EPA's research program is providing
data and technical support for solving environmental  problems today and building a
science knowledge  base necessary to manage  our ecological  resources wisely,
understand how pollutants affect our health, and prevent or reduce environmental risks
in the future.
      The Natioral Risk Management Research  Laboratory (NRMRL) is the Agency's
center for investigation  of technological and management approaches  for preventing
and reducing risks from  pollution that threaten human health and the environment. The
focus of the Laboratory's research program is on methods  and their cost-effectiveness
for prevention and control of pollution  to air, land, water,  and subsurface resources;
protection of water quality in public water systems; remediation of contaminated sites,
sediments and  ground water; prevention  and  control of indoor air  pollution; and
restoration of ecosystems. NRMRL collaborates with  both public and  private sector
partners  to foster technologies that reduce the cost of compliance  and to anticipate
emerging problems.  NRMRL's research provides solutions to environmental problems
by: developing and promoting  technologies that protect and improve the environment;
advancing scientific and  engineering  information to  support regulatory  and  policy
decisions;  and  providing  the  technical support and  information transfer to  ensure
implementation of environmental regulations and strategies at the national, state, and
community levels.

      This  publication  has been  produced as part  of  the Laboratory's  strategic
long-term research plan.   It  is published and  made  available by  EPA's Office  of
Research and Development to assist the user community  and to link researchers with
their clients.
                                  E. Timothy Oppelt, Director
                                  National Risk Management Research Laboratory


                           EPA REVIEW NOTICE

    This report has been peer and administratively reviewed by the U.S. Environmental
    Protection Agency, and approved  for publication. Mention of trade  names or
    commercial prqducts does not constitute endorsement or recommendation for use.
                i
    This document is available to the public through the National Technical Information
    Service, Springfield, Virginia 22161.

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                                           EPA-600/R-01-056b
                                                  July 2001
     Environmental Impacts  of the
            Use  of Orimulsion®

           Report to  Congress on
Phase  1  of the Orimulsion® Technology
            Assessment Program
        Volume 2. Appendices  B-H
                         By
     C. Andrew Miller, Kevin Dreher, Randall Wentsell, and Royal J. Nadeau

               U.S. Environmental Protection Agency
            National Risk Management Research Laboratory
             Air Pollution Prevention and Control Division
                Research Triangle Park, NC 27711
       National Health and Environmental Effects Research Laboratory
                Research Triangle Park, NC 27711
            National Center for Environmental Assessment
                   Washington, DC 20460
            National Risk Management Research Laboratory
                Environmental Response Team
                     Edison, NJ 08837
               EPA Project Officer: C. Andrew Miller
            National Risk Management Research Laboratory
                Research Triangle Park, NC 27711
                      Prepared for:

               U.S. Environmental Protection Agency
               Office of Research and Development
                   Washington, DC 20460

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                                          Abstract

Orimulsion, a bitumen-in-water emulsion produced in Venezuela, was evaluated to provide a better
understanding of the potential environmental impacts associated with its use as a fuel.  A series of
pilot-scale tests were  conducted  at the  U.S.  Environmental  Protection Agency's Environmental
Research Center in Research Triangle Park, NC, to provide data on emissions of air pollutants from
the combustion of Orimulsion 100 (the original formulation), Orimulsion 400 (a new formulation
introduced in 1998), and a No. 6 (residual) fuel oil.   These results, and results  of full-scale tests
reported in the technical literature, were evaluated to determine the potential air pollutant emissions
and the ability of commercially available pollution control technologies to adequately reduce those
emissions.  Emissions of carbon monoxide (CO),  oxides  of nitrogen (NOX), sulfur dioxide (SO2),
sulfur trioxide, particulate matter (PM), and organic and metal hazardous air pollutants (HAPs) were
measured from  each  of these three  fuels to provide  a  comparison between the "new" fuel
(Orimulsion) and  a fuel that has  been commonly  used in the U.S.  (the No.  6 fuel oil).  Results
indicate that CO, NOX, and PM emissions are likely to be nearly the same as those from the No. 6 fuel
oil, that SO 2 emissions can increase if the  fuel sulfur content increases, that the particles generated by
Orimulsion  100 and 400 are  likely to be smaller in diameter than those generated by No. 6 fuel oil,
and that HAPs are also likely to be similar to those from No. 6 fuel oil.  Both the full-scale results
found in the literature and the pilot-scale results measured at EPA  indicate that conventional air
pollution control  technologies can effectively reduce  emissions to very low levels, depending upon
the type of technology used and the desired emission levels.  Because the bitumen in Orimulsion is
heavier  than water and due to the presence of a surfactant in the fuel, spills of Orimulsion are likely to
be more difficult to contain and recover than are spills of heavy fuel oil, especially in fresh water.
Additional study is needed before  adequate containment and response approaches can be developed.
Little, if any, work has been conducted by the  fuel producer or the scientific community to address
the remaining spill-related issues.

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                                          Preface

This report is the result of a request by the U.S. Congress to receive scientific information regarding
the potential environmental  impacts of the use of Orimulsion as a fuel.  In the second half of the
1990s, there was considerable interest on the part of electric utilities in using Orimulsion,  which was
promoted as a low-cost fuel that could replace heavy fuel oil or coal. There were also many concerns
raised by the  environmental community regarding the environmental impact associated  with
switching to Orimulsion.   In  1997, the U.S. Congress requested that the U.S. Environmental
Protection Agency (EPA) conduct a study  to evaluate the potential environmental impacts associated
with the use of Orimulsion. EPA's  Office  of Research  and Development provided funds to the
National Risk Management Research Laboratory (NRMRL) to conduct this study, and a team of EPA
experts in air pollution control, spill response, health effects, and environmental  assessment was
assembled to carry out the investigation.  This report was prepared by EPA staff using data generated
at EPA facilities as well as data collected from the general literature.

In 1998, Bitumenes Orinoco (Bitor), the  manufacturer of Orimulsion, changed the formulation of the
fuel.   The  original fuel, renamed Orimulsion 100, was replaced with a new formulation  named
Orimulsion 400. Compared to the amount of information on  Orimulsion  100, there is relatively little
data on the performance of Orimulsion 400. While this report provides as much data as possible on
the emissions and performance of Orimulsion 400, the bulk of the data are for the older formulation
(Orimulsion 100).   Although Orimulsion  100 is no longer produced, the results presented here are
still believed to adequately describe the basic behavior of both formulations of Orimulsion. The key
question to be addressed in this study is,  "Is Orimulsion significantly different from other fossil fuels,
and if so, how?"  The differences between Orimulsion  100  and Orimulsion 400, as indicated both
from the available data and  the information provided by the manufacturer, are substantially  smaller
than the differences between Orimulsion and other fossil fuels. The report distinguishes between the
two formulations where appropriate, but uses the  generic term "Orimulsion" where  such  distinction
is either unimportant or misleading.  The recent reformulation is significant with respect to the
surfactant used (which will affect spill toxicity) and the use of a magnesium-based additive  (which
will affect boiler tube deposition and particulate matter  emissions).   Other environmental issues
appear to be impacted only to a minor degree by the change in formulation.

The emphasis of this report is on generation and  control  of air pollutants from the combustion of
Orimulsion. Although there are other environmental issues  associated with  the use of Orimulsion,
particularly  spills of the fuel into water, EPA and NRMRL  were advised on several occasions that
questions related to air pollutant generation and  control  were the key unknowns  associated with
understanding the environmental impact  potential  of Orimulsion. The  initial step in EPA's research
activities was the convening  of a workshop to discuss environmental issues related to Orimulsion use.
This workshop, held February 8,  1998, concluded that there was a lack of information on particle size
distribution and composition and on emissions  and control of sulfur trioxide  from Orimulsion
combustion.  The  workshop also concluded that  enough  data existed to allow a comparative risk
analysis for heavy  fuel oil and Orimulsion, and therefore additional research in  that area was not
immediately required.  The workshop  noted that a lack of data existed describing the behavior, fate,
and effects of Orimulsion spills in fresh water. However, the workshop concluded that  investigations
into these areas should be the responsibility of Bitor in the event they sought to market  the  fuel to
users where spills into fresh  water were possible.  Considerable work has been conducted to quantify
behavior,  fate,  and effects  of Orimulsion in saltwater environments under the oversight of the
International Orimulsion Working Group, of which Bitor is a member  and the  major source of
funding.  Thus this  report has as  its focus the generation and control of air pollutants, although other
topics are also covered.

This focus was emphasized in the Orimulsion Technology  Assessment Plan that was prepared to
guide EPA's research  efforts. This plan was reviewed and approved, with modifying comments, by a
                                              in

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panel of technical experts, mostly from outside the federal government.  The only exception was one
member from the U.S. Coast Guard. The Plan was then reviewed by the Office of Management and
Budget (OMB), the U.S.  Department of Energy, and the Office of Science and Technology Policy.
EPA responded to comments made by each of these organizations and revised the Plan, which was
approved by OMB on April 22,  1999.

The National Risk Management Research Laboratory was the lead organization for the study, and was
chiefly responsible for preparation of Chapters 1-5 and 9-12. Robert E. Hall was the overall program
lead, and C. Andrew Miller was the lead author of these  chapters.  Kevin Dreher of the National
Health and Environmental Effects Research  Laboratory prepared Chapter 6, on toxicity testing, with
substantial  assistance from Adriana Grain.  Chapter 7, on spills, was prepared with assistance from
Royal J. Nadeau of EPA's Office of Solid Waste and Emergency Response.  Randall Wentsel of the
National Center for Environmental Assessment prepared Chapter 8, on environmental assessment.

The  conclusions  stated in this  report are scientific conclusions, and  are not intended to provide
guidance relative to regulatory requirements  that may or may not apply to the use of Orimulsion.

                                  Acknowledgments

Many people contributed to the collection of data and preparation of this  report. From EPA's Air
Pollution Prevention and Control Division, the following people provided notable input:
•  Marc Calvi for preparation and analysis of SEM samples,
•  Shirley Wasson for XRF analysis of PM samples, and
•  Paul Groff, Richard Shores, and Nancy Adams for quality assurance support.

From ARCADIS Geraghty  & Miller (under EPA contract 68-C-99-201), efforts of the following
people were critical to the completion of this project:
•  Suh Lee, project lead,
•  Charly King for sample collection and preparation,
•  Christian Elmore and Daniel Janek for SMPS operation, and
•  Dennis Tabor for analytical chemistry support.

The opportunity to observe full-scale operations at the Dalhousie and Asnaes Generating Stations was
also very useful, and we received considerable assistance from:
•  Rod Eagles and Barry Irvine of New Brunswick Power, Dalhousie, New Brunswick, Canada,
•  Kim  Jonas, Niels Groth-Andersen,  Thorkild  Meyer,  and Hans  Christensen  of SK Power,
   Kalundborg, Denmark, and
•  Morten Thellefsen Nielsen, Technical University of Denmark, Lyngby, Denmark.

Many of the reports from which full-scale data were taken were provided by Nelson Garcia Tavel of
Bitor America, Jason Miles of Bitor Europe,  and independent consultant Ken Olen.
                                             IV

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                           Nomenclature and Acronyms

APCS	air pollution control system
API	American Petroleum Institute
APPCD	Air Pollution Prevention and Control Division
ARD	Arizona road dust
ASTM  	American Society for Testing and Materials
BALF	bronchoalveolar fluid
bbl	barrels, U.S. petroleum
BTEX	benzene, toluene, ethylene, and xylenes
Btu	British thermal unit
CAA	Clean Air Act
CAAAs	Clean Air Act Amendments of 1990
CARB	California Air Resources Board
CE 	Combustion Engineering
CEM	continuous emission monitor
CO	carbon monoxide
CO2  	carbon dioxide
DAS	data acquisition system
DQI  	data quality indicator
EDX	energy dispersive  x-ray
ENEL	Italian Electricity Generating Board
EPA	Environmental Protection Agency
ESP  	electrostatic precipitator
FETC	U.S. Department of Energy's Federal Energy Technology Center
FGD	flue  gas desulfurization
FPL  	Florida Power & Light Company
GIS	geographical information  systems
HAP	hazardous air pollutant
HEPA	high efficiency particulate air
HFO	heavy fuel oil
HQ	health  quotient
IOWG	International Orimulsion Working Group
IURE  	inhalation unit risk estimate
LAPIO	low API oil
LDH	lactate dehydrogenase
LNB	low NOX burner
LOEC	lowest observable effects concentration
LOEL	lowest observed effect level
LOI  	loss  on ignition
MACS  	miniature acid-condensation system
MDL   	method detection limit
MEI	maximum exposed individual
MIR	maximum individual risk
NCEA	National  Center for Environmental Assessment
NHEERL  	National  Health and Environmental Effects Research Laboratory
NO	nitric oxide
NOEC	no observable effects concentration
NOX  	nitrogen  oxides
NRC	National  Research Council

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                   Nomenclature and Acronyms (Continued)
NRMRL	National Risk Management Research Laboratory
NSPS 	New Source Performance Standard
O2 	 oxygen
OERR	Office of Emergency and Remedial Response
OFA	overfire air
ORD	Office of Research and Development
ORI  100	Orimulsion 100
ORI 400	Orimulsion 400
OSWER  	Office of Solid Waste and Emergency Response
OTAP	Orimulsion Technology Assessment Plan
PAH	polycyclic aromatic hydrocarbon
PBS   	Package Boiler Simulator
PC  	pulverized coal
PDVSA	Petroleos de Venezuela, S.A.
PEA	performance evaluation audit
PM	particulate matter
PM2.5 	particulate matter smaller than 2.5 (am in aerodynamic diameter
PM10	particulate matter smaller than 10  (am in aerodynamic diameter
ppm	parts per million
QA	quality assurance
QAPP	quality assurance project plan
QC	quality control
ROFA 6  	residual oil fly ash (No. 6 fuel oil)
RSD	relative standard deviation
SASS 	source assessment sampling system
SCR	selective catalytic reduction
SEM	scanning  electron microscope
SMPS	scanning mobility particle  sizer
SNCR	selective noncatalytic reduction
SO2	sulfur dioxide
SO3	sulfur trioxide
SVOC	semivolatile organic compound
TCLP	toxicity characteristic leaching potential
THC	total hydrocarbon
TSA	technical  systems audit
VOC	volatile organic compound
VOST	volatile organic sampling train
WLFO	wet limestone forced oxidation
XRF	X-ray fluorescence
                                           VI

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                                       Contents

                                        Volume 1

                                                                                     Page
Abstract  	ii
Preface	iii
Acknowledgments  	iv
Nomenclature and Acronyms	 v
List of Figures  	xiii
List of Tables	xvi

Executive Summary	  ES-1
   Conclusions of the Report	  ES-1
   Recommendations of the Report	  ES-1
   Purpose and Approach	  ES-2
   Background	  ES-3
   Air Emissions	  ES-3
      Data from EPA Pilot-Scale Tests 	  ES-3
   Toxicity Testing	  ES-4
   Spills  	  ES-5
   Risk Assessment	  ES-5
   Potential Use of Orimulsion 	  ES-6
1. Introduction and Background	
    Background	
    Overview of Orimulsion and its Use
    Air Emissions	
    Spills  	
    Objective  	
    Approach	
    Report Structure
-1
-1
-2
-3
-4
-5
-5
-6
2. Properties and Characteristics of Orimulsion	 2-1
    Background	 2-1
    Properties of Emulsified Fuels  	 2-1
      Combustion Behavior	 2-1
      Impact on Boiler Efficiency	 2-2
      Fuel Handling 	 2-3
    Properties of Orimulsion	 2-3
      Fuel Composition	 2-4
      Fuel Handling 	 2-4
         Temperature 	 2-4
         Shear	 2-4
         Contamination	 2-6
    Evaluating Environmental Issues Associated With Orimulsion Combustion	 2-6
      Air Emissions	 2-7
      Solid Residues	 2-9

3. Review of Previous Orimulsion Combustion Research and Demonstration	 3-1
    Fundamental Studies	 3-1
                                          VII

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                           Contents (Continued)
                                                                                 Page

Pilot-Scale Testing  	  3-2
   Combustion Performance	  3-2
   Burner Development 	  3-4
   Trial Tests 	  3-4
   Reburning Development  	  3-6
   Air Pollution Control Equipment Evaluation  	  3-6
Full-Scale Testing and Operation  	  3-7
   Plants Currently  Operating	  3-7
     New Brunswick Power Dalhousie Generating Station	  3-8
        Dalhousie Demonstration Tests	  3-8
        Conversion to Permanent Orimulsion Operation	  3-11
        Use of Orimulsion 400	  3-12
     Kansai Electric Power Company Osaka No. 4  	  3-14
     Kashima-Kita Electric Power Company	  3-14
     SK Energy Asnaes Unit 5  	  3-14
        Orimulsion 100 Use at Asnaes	  3-14
        Orimulsion 400 Use at Asnaes	  3-18
     ENEL Brindisi Sud Units 1 and 2 and Fiume Santo Plant	  3-19
   Past Operations  	  3-20
     Florida Power & Light Company Sanford Plant	  3-20
     PowerGen Ince and Richborough  	  3-21
     Energie-Versorgung Schwaben Marbach III Power Plant	  3-23
   Planned Operations  	  3-23
   Reburning Development  	  3-24
   Engineering Studies	  3-25
     Feasibility Studies 	  3-26
     Pollution Control Equipment Analyses 	  3-27
Other Work	  3-27
   Diesel Engines	  3-27
   Gasification	  3-27
   Briquetting of Coal Fines	  3-27
   Cement Kilns	  3-28
   Desulfurization  	  3-28
Summary of Previous Work  	  3-28
   Operational Issues  	  3-28
     Fuel Handling and Atomization	  3-28
     Excess O2 	  3-28
     Boiler Efficiency	  3-28
     Boiler Fouling	  3-29
   Air Emissions	  3-29
     CO	  3-29
     NOX	  3-29
     SO2 and SO3  	  3-30
     PM  	  3-31
     Hazardous Air Pollutants and Metals	  3-31
     CO2	  3-32
   Air Pollution Control	  3-34
     NOX Control	  3-34
        Low NOX Burners	  3-34
        Reburning	  3-34
        Selective Catalytic Reduction	  3-34
                                       Vlll

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                               Contents (Continued)
                                                                                    Page

           SO2 and SO3 Control	 3-35
           PM Control	 3-35
           ESPs	 3-35
           Baghouses	 3-35
      Solid Residue Disposal	 3-36

4. EPA Pilot-Scale Experimental Approach and Equipment  	 4-1
    Approach	 4-1
    Test Equipment  	 4-1
      Package Boiler Simulator	 4-1
      Fuel Supply System	 4-2
      Instrumentation	 4-2
         Continuous Emission Monitors 	 4-3
         Data Acquisition System 	 4-4
         Dilution Sampling System	 4-5
         Scanning Mobility Particle  Sizer 	 4-6
         Scanning Electron Microscope 	 4-7
    Sampling Methods	 4-7
      EPA Methods 5 and 29  	 4-7
      EPA Methods 0010 and 0030  	 4-8
      Modified CARB Method 501	 4-8

5. EPA Pilot-Scale Test Results	 5-
    Test Conditions	 5 -
      Fuel Composition	 5-
      O2  	 5-
      Fuel Feed	 5-
    Emission Measurement Results	 5-3
      CO	 5-3
      NOX	 5-5
      SO2and SO3	 5-5
      PM	 5-7
      Organic HAPs 	 5-10
         Volatile Organic Compounds	 5-10
         Semivolatile Organic Compounds 	 5-11
      Metals  	 5-14
    Emission Factors	 5-18
    Scanning Electron Micrographs	 5-21

6. Physicochemical Properties and Acute Pulmonary Toxicity of Orimulsion Fly Ash	 6-1
    Objective  	 6-1
    Oil Fly Ash  Production and Collection	 6-1
    Reference Particle	 6-1
    Physicochemical Properties of Oil Fly Ash Samples and  Arizona Road Dust  	 6-1
    Acute Pulmonary Toxicity of Oil Fly Ash and Arizona Road Dust Samples  	 6-2
    Oil Fly Ash Health Effects Commentary	 6-5

7. Spills	 7-1
    Introduction	 7-1
    Background	 7-1
                                            IX

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                                   Contents (Continued)
                                                                                       Page

     Reported Orimulsion Spill Studies 	  7-4
       Saltwater Spills	  7-5
       Freshwater Spills  	  7-5
       Data Gaps  	  7-7

 8. Environmental Risk Assessment  	  8-1
     Comparative Ecological Risk Assessment Evaluation  	  8-1
       Introduction	  8-1
       Summary of Comparative Ecological Risk Assessment Reports  	  8-2
          Scope of Harwell Work  	  8-2
          Approach of Harwell Work 	  8-2
          Conclusions of Harwell Work	  8-2
       Scientific Evaluation of the Comparative Ecological Risk Assessment
       of Spills from No. 6 Fuel Oil and  Orimulsion 100	  8-3
          Overview of Harwell Assessment  	  8-3
          Assessment Methodologies 	  8-3
          Portability of this Assessment to Other Sites	  8-7
          Fate and Transport Methods 	  8-8
          Toxicity Test Methods	  8-8
       Suggested Improvements for the Tampa Bay Risk Assessment	  8-9
          Toxicology	  8-9
          Benthic Community	  8-10
          Modeling	  8-10
          Mitigation	  8-10
     Assessment of Risk from Air Emissions  	  8-10
     Conclusions  	  8-12

 9. Comparison of Orimulsion with  Other Fossil Fuels  	  9-1
     Fuel Properties	  9-1
       Coal	  9-1
       Fuel Oil	  9-2
       Natural Gas  	  9-3
     Fuel Use	  9-4
       Coal	  9-5
       Fuel Oil	  9-5
       Natural Gas  	  9-8
     Air Pollutant Emissions and Control	  9-8
       CO Emissions and Control	  9-8
       NOXEmissions and Control  	  9-9
       SOX Emissions and Control  	  9-11
       PM Emissions and Control	  9-13
       Hazardous Air Pollutants Emissions and Control 	  9-16
       Transition Metals Emissions and Control	  9-18
       CO2 Emissions	  9-18
       Summary of Air Pollutant Emissions	  9-19

10. Quality Assurance	  10-1

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                                Contents (Continued)
                                                                                    Page

    Data Reported in Literature	  10-1
    In-House Combustion Testing 	  10-1
       Data Quality Indicator Goals  	  10-1
       Calculation of DQI Values	  10-3
          Sampling  Goals	  10-3
          Analytical Data Quality Indicators	  10-3
            Volatile Organic Compounds 	  10-3
            Semivolatile Organic Compounds	  10-4
            Metals Analyses  	  10-9
    Audits	  10-10
       Audit Summary	  10-10
          Findings and Observations	  10-12
          EPA Performance Evaluation and Systems Audits	  10-12
            Flue Gas Flow	  10-12
            Fuel Input Flow	  10-13
            CEM Calibrations	  10-13
            Other Discrepancies  	  10-13
          ARCADIS Technical Systems Audit	  10-14
          Other Discrepancies	  10-14
    Data Limitations	  10-14
    QA Review of Sampling and Measurement Activities at Asnaes	  10-15
       Flue Gas Concentration Measurements	  10-15
       PM Sampling Program	  10-16
    Toxicity Testing	  10-17

11. Conclusions and  Recommendations  	  11-1
    Responses to Questions of the Peer Panel  	  11-1
    Further Conclusions	  11-3
       Orimulsion Properties  	  11-3
       Air Pollutant Emissions 	  11-3
       Air Pollution Control Technologies	  11-3
       Solid Waste Disposal  	  11-3
       Toxicity	  11-3
       Spills	  11-3
       Ecological Risk 	  11-3
       Potential  for  Orimulsion Use  	  11-4
       Data Reported in the Literature  	  11-4
    Recommendations  	  11-4

12. References  	  12-1

 APPENDIX A.  Conversion of English System to SI System Units	A-l

                                         Volume 2


 APPENDIX B.  Continuous Emission Monitoring Data for EPA Pilot Scale Tests  	  B-l
 APPENDIX C.  Volatile  Organic Compound Analysis Laboratory Reports  	  C-l

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APPENDIX D. Semivolatile Organic Compound Analysis Laboratory Reports	D-l
APPENDIX E. Metal Analysis Laboratory Reports	  E-l
APPENDIX F. Orimulsion Spill References Cited by the NRC, U.S. Coast Guard,
              and Environment Canada Reports	  F-l
APPENDIX G. Additional Ecological Risk Assessment Studies	G-l
APPENDIX H. Comparative Risk Methodology Synopsis of Harwell et al. (1995)  	H-l
                                          xn

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                                  List of Figures

                                       Volume 1
                                                                                     Page

 1-1.  Orinoco region of Venezuela	  1-4
 2-1.  Types of instabilities in bitumen-in-water emulsions  	  2-6

 3 -1.  Emissions of CO, NOX, and PM measured during
       pilot-scale tests of Orimulsion 100 combustion  	  3-3
 3-2.  F-jet and advanced F-jet atomizers used in Orimulsion combustion
       tests at PowerGen's Power Technology Centre	  3-5
 3-3.  Photograph of Dalhousie Generating Station, Dalhousie, New Brunswick, Canada ....  3-8
 3 -4.  Particle size distribution for PM emitted from the
       combustion of heavy fuel oil and Orimulsion 100 during
       demonstration testing at NB Power Dalhousie Generating Station	  3-10

 3-5.  Carbon in ash in PM emitted from the combustion of
       heavy fuel oil and Orimulsion 100 during demonstration testing
       at NB Power Dalhousie Generating Station	  3-11
 3-6.  CO as a function of stack O2 levels measured during
       combustion testing of heavy fuel oil and Orimulsion 100
       at the NB Power Dalhousie Generating Station	  3-12

 3-7.  Relationship between the acid dewpoint and SOj,
       emissions measured during Orimulsion  100 demonstration
       testing at the NB Power Dalhousie Generating Station  	  3-13
 3-8.  Relationship between stack and acid dewpoint
       temperature for each day during Orimulsion  100
       demonstration testing at NB Power Dalhousie Station	  3-13

 3-9.  CO, NOX, and SO2 emissions at Kansai Electric Company Osaka No. 4 plant  	  3-15
3-10.  Emissions of PM, unburned carbon, and SO3 at
       Kansai Electric Company Osaka No. 4 plant  	  3-16
3-11.  Particle size distribution for PM from the combustion of
       Orimulsion 100 measured at SK Energy Asnaes Unit 5  	  3-17
3-12.  NOX emission rates as  a function of load measured during testing
       of Orimulsion 100 at the Florida Power & Light Sanford Plant  	  3-21
3-13.  Average PM  emission rates as a function of test condition measured
       during testing of Orimulsion 100 at the Florida Power & Light Sanford Plant	  3-22
3-14.  NOX emissions measured during the reburning demonstration at Hennepin Station  . .  3-25

3-15.  NOX emissions measured during the reburning demonstration
       at Hennepin Station using  natural gas and Orimulsion 100
       as reburn fuel, as a function of % reburn fuel input	  3-26

 4-1.  Schematic of Package Boiler Simulator	  4-3

 4-2.  Schematic of fuel feed system for heavy fuel oil  	  4-4
                                              Xlll

-------
                          List of Figures (Continued)
                                                                                      Page
 4-3.  Schematic of fuel feed system for Orimulsion 100 and Orimulsion 400	  4-5
 4-4.  Schematic of continuous emission monitoring system  	  4-6
 4-5.  Schematic of high volume dilution sampling system  	  4-7
 5-1.  Average CO emissions from the three fuels tested	  5-4
 5-2.  CO vs. O2 for selected runs with Orimulsion 100, Orimulsion 400, and No. 6 fuel oil .  5-4
 5-3.  Average NO emissions from the three fuels tested  	  5-5
 5-4.  NO vs. O2 for selected runs with Orimulsion 100, Orimulsion 400, and No. 6 fuel oil .  5-6
 5-5.  Average SO2 emissions as measured by CEM from the  three fuels tested  	  5-6
 5-6.  Average PM emissions from the three fuels tested  	  5-8
 5-7.  Cascade impactor results for the three fuels tested  	  5-9
 5-8.  Scanning mobility particle sizing results for the three fuels tested	  5-10
 5-9.  Average detected concentration of volatile organic compounds	  5-13
5-10.  Average detected emission factors of volatile organic compounds 	  5-14
5-11.  Average detected concentrations of semivolatile organic compounds	  5-16
5-12.  Average detected emission factors of semivolatile organic compounds	  5-16
5-13.  Concentrations of metals measured in the flue  gases of the three fuels	  5-17
5-14.  Scanning electron micrograph of untreated blank filter  at 700x magnification	  5-22
5-15.  Scanning electron micrograph of untreated filter loaded with PM
       from No. 6 fuel oil at 700x magnification	  5-23
5-16.  Scanning electron micrograph of untreated filter loaded with PM
       from Orimulsion 100  at 700x magnification  	  5-23
5-17.  Scanning electron micrograph of untreated filter loaded with PM
       from Orimulsion 400  at 700x magnification  	  5-24
 6-1.  Particle-induced  acute lung injury	  6-4
 7-1.  Movement, spill volumes, and spill rates of heavy oils
       in U.S. domestic waters between 1991 and 1996 	  7-2
 7-2.  Spill of nonfloating oil in low-current fresh water  	  7-3
 7-3.  Spill of nonfloating oil in high-current fresh water	  7-4
 7-4.  Spill of nonfloating oil in high-current salt water	  7-5
 9-1.  Estimated recoverable reserves of coal in the U.S. by sulfur content	  9-2
 9-2.  U.S. electricity generation in 1997 by fossil fuel 	  9-4
 9-3.  U.S. utility and industrial coal consumption in 1997 by state	  9-6
 9-4.  U.S. fuel oil consumption by the commercial, industrial,
       oil company, and utility sectors in 1997 by state 	  9-7
                                               xiv

-------
                          List of Figures (Continued)

                                                                                  Page


 9-5.  U.S. natural gas consumption by the commercial,
       industrial, and utility sectors in 1997 by state	 9-10

 9-6.  Comparison of particle size distributions from the
       combustion of pulverized coal before and after an ESP	 9-15

 9-7.  Particle size distributions for  a No. 6 fuel oil and the same fuel oil
       in a 90% oil/10% water emulsion	 9-17

                                      Volume  2

 B-l.  CEM data for O2, CO, NO, and SO2 taken May 18,  1999 during
       EPA's pilot scale testing of Orimulsion 400	 B-2

 B-2.  CEM data for O2, CO, NO, and SO2 taken May 19,  1999  during
        EPA's pilot scale testing of Orimulsion 400 	 B-3
 B-3.  CEM data for O2, CO, NO, and SO2 taken May 20,  1999  during
        EPA's pilot scale testing of Orimulsion 400 	 B-4

 B-4.  CEM data for O2, CO, NO, and SO2 taken May 21,  1999  during
       EPA's pilot scale testing of Orimulsion 400	 B-5
 B-5.  CEM data for O2, CO, NO, and SO2 taken May 24,  1999  during
       EPA's pilot scale testing of Orimulsion 100	 B-6

 B-6.  CEM data for O2, CO, NO, and SO2 taken May 25,  1999  during
       EPA's pilot scale testing of Orimulsion 100	 B-7
 B-7.  CEM data for O2, CO, NO, and SO2 taken May 26,  1999  during
       EPA's pilot scale testing of Orimulsion 100	 B-8

 B-8.  CEM data for O2, CO, NO, and SO2 taken May 27,  1999  during
       EPA's pilot scale testing of Orimulsion 100	 B-9
 B-9.  CEM data for O2, CO, NO, and SO2 taken June 3, 1999 during
       EPA's pilot scale testing of No. 6 fuel oil	 B-10

B-10.  CEM data for O2, CO, NO, and SO2 taken June 4, 1999 during
       EPA's pilot scale testing of No. 6 fuel oil	 B-l 1
B-l 1.  CEM data for O2, CO, NO, and SO2 taken June 7, 1999 during
       EPA's pilot scale testing of No. 6 fuel oil	 B-12

B-12.  CEM data for O2, CO, NO, and SO2 taken June 8, 1999 during
       EPA's pilot scale testing of No. 6 fuel oil	 B-l 3
                                         xv

-------
                                    List of Tables

                                        Volume 1

                                                                                      Page
ES-1. Summary of air pollutant concentrations reported in the
      literature for Orimulsion and heavy fuel oil	 ES-4
 2-1. Typical properties of Cerro Negro bitumen	  2-3

 2-2. Typical values and ranges of Orimulsion 100 properties and constituents	  2-5
 2-3. Radioactive elements present in Orimulsion	  2-6

 2-4. Metals and radioactive elements present in Orimulsion fly ash	  2-9

 2-5. Toxicity characteristic leaching procedure (TCLP)
      results for Orimulsion 100 and coal fly ashes  	 2-10

 3 -1. Flue gas composition for pilot-scale tests using a burner from
      Dunamenti Power Station  	  3-3

 3-2. Plants that have operated or are were  operating commercially as of
      December 2000 using Orimulsion	  3-7

 3-3. Emissions measured  during Dalhousie Station Unit  1 Demonstration  	  3-9

 3-4. Stack trace metal emissions in mg/Nm3 measured at Asnaes Unit 5  	 3-17

 3-5. Trace metal concentrations in Orimulsion 100 fly ash
      in mg/kg measured at Asnaes Unit 5  	 3-18
 3-6. Trace metal concentrations in dry scrubber sludge samples
      taken during operation with coal and  Orimulsion 100 from Asnaes Unit 5  	 3-19

 3-7. Emissions of trace metal compounds  during tests of Orimulsion 400
      at ENEL Fiume Santo Plant	 3-20
 3-8. Comparison of long-term contributions to  ambient  concentration  or deposition
      of pollutants from the combustion of Orimulsion 100 at Marbach  III Power Plant  . .  . 3-24

 3-9. CO emissions measured during pilot-  and full-scale tests
      for heavy fuel oil and Orimulsion 100  	 3-29

3-10. NOX emissions measured during pilot- and full-scale tests for
      heavy fuel oil and Orimulsion	 3-30

3-11. Reported  SO3 emissions measured during pilot- and full-scale tests
      for heavy fuel oil and Orimulsion	 3-31
3-12. Reported PM emissions  measured during pilot- and  full-scale tests
      for heavy fuel oil and Orimulsion	 3-32

3-13. Reported PM size distributions measured during pilot- and
      full-scale tests for heavy fuel oil and Orimulsion	 3-33
3-14. Emissions of selected hazardous air pollutants from
      coal, heavy fuel oil, and Orimulsion  	 3-33

 4-1. Test matrix for EPA pilot-scale tests of Orimulsion air pollutant emissions  	  4-2
 5-1. Elemental analyses (as received) of the three fuels tested	  5-2

 5-2. Average O2 stack concentrations for each test run, and average of four test runs	  5-2

 5-3. Average fuel flows for each test run, and average of four test runs	  5-3
                                           xvi

-------
                             List of Tables (Continued)
                                                                                       Page
  5-4. SO2 concentrations for the three fuels tested as measured by CEM and MACS
        methods, and as calculated based on complete conversion of fuel sulfur to SO2	 5-7
  5-5. Volatile organic compounds for which samples were analyzed  	  5-11
  5-6. Semivolatile organic compounds for which samples were  analyzed	  5-12
  5-7. Semivolatile organic compounds detected in the flue gases of the three fuels  	  5-15
  5-8. Measured and calculated emission factors and percent recoveries for  12 metals	  5-19
  5-9. Results of XRF analyses of untreated filters and samples	  5-20
 5-10. XRF analyses of untreated and treated filters loaded with PM from the three fuels ....  5-21
 5-11. Emission factors for CO, NO, SO2, and PM from the three fuels tested	  5-21
  6-1  Physicochemical characterization of collected PM2 5 oil fly ash
       samples and Arizona road dust particles  	 6-2
  6-2  Biomarkers of pulmonary acute toxicity or injury	 6-3
  6-3  Relative toxicity of oil fly ash and dust exposures at the lowest
       observed effect level (LOEL) for each endpoint  	 6-3
  8-1. Summary of risk estimates from inhalation exposure to
       priority HAPs for  137  oil fired  utility boilers in the U.S	  8-12
  9-1. Ranges of trace element concentrations in coals  	 9-2
  9-2. Range of selected average trace element concentrations for U.S. coals
       from different regions of the country,  and  maximum and minimum
       concentrations from individual samples	 9-3
  9-3. Range of averages and reported typical values of trace element
       concentrations in residual fuel oils from different sources	 9-3
  9-4. CO emission  factors for coal, fuel oil, and natural gas	 9-9
  9-5. SO2 emission factors for three coal types and for No. 6 fuel oil	  9-12
  9-6. Filterable PM emission factors  for different fuels
       and different combustion system designs  	  9-13
 10-1. Data quality indicator  goals for critical measurements	  10-2
 10-2. CEM  full-range and mid-range span check results   	  10-3
 10-3. CEM  system  bias  check results   	  10-4
 10-4. VOC target analytes and method detection limits	  10-5
 10-5. VOC  surrogate recovery results	  10-6
 10-6. VOC matrix spike and matrix spike duplicate results	  10-6
 10-7. SVOC matrix spike and matrix spike duplicate results	  10-7
 10-8. SVOC pre-extraction surrogate  recovery levels	  10-8
 10-9. Pre-sampling surrogate recovery/XAD samples	   10-10
10-10. Internal laboratory QC summary	   10-11
10-11. Spiked metal sample recoveries	   10-13
                                            XVII

-------
                                     Appendix B
     Continuous Emission Monitoring Data for EPA Pilot-Scale Tests

CEM data collected from each of the 12 test runs are presented below. Figures B-l through B-12
present CO, NO, O2, and SO2  concentrations (uncorrected) for each of the four test runs conducted
for each of the three  fuels.  The top plot in each case shows O2 concentration, and the bottom plot
shows CO, NO, and SO2.  The sampling personnel attempted to collect samples when O2 and CO
fluctuations were minimal, and did not sample during periods  when there were large fluctuations in
conditions.

The plots are  presented in chronological order, with Figures B-l through B-4 showing results from
tests of Orimulsion 400, Figures B5 through B-8 showing results from  Orimulsion  100, and Figures
B-9 through B-12 showing results from No. 6 fuel oil.
                                          B-l

-------
                                       5/18/99
                                       Orimulsion 400
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Figure B-1.  CEM data forO2 (top), CO, NO, and SO2 (bottom) taken May 18, 1999 during EPA's pilot-scale testing
           of Orimulsion 400.
                                        B-2

-------
                     5/19/99
                     Orimulsion  400
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Figure B-2. CEM data for O2 (top), CO, NO, and SO2 (bottom) taken May 19, 1999 during EPA's pilot-scale testing
           of Orimulsion 400.
                                           B-3

-------
     20-
     18-

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-------
                   5/21/99
                   Orimulsion 400
Figure B-4.  CEM data for O2 (top), CO, NO, and SO2 (bottom) taken May 21, 1999 during EPA's pilot-scale testing
           of Orimulsion 400.
                                         B-5

-------

                                               5/24/99
                                               Orimulsion  100
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Figure B-5. CEM data for O2 (top), CO, NO, and SO2 (bottom) taken May 24, 1999 during EPA's pilot-scale testing
          of Orimulsion 100.
                                       B-6

-------
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Figure B-6.  CEM data for O2 (top), CO, NO, and SO2 (bottom) taken May 25, 1999 during EPA's pilot-scale testing

          of Orimulsion 100.
                                        B-7

-------
     1.0-



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          of Orimulsion 100.

-------
                Orimulsion 100
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Figure B-8. CEM data for O2 (top), CO, NO, and SO2 (bottom) taken May 27, 1999 during EPA's pilot-scale testing
           of Orimulsion 100.
                                          B-9

-------
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Figure B-9.  CEM data for O2 (top), CO, NO, and SO2 (bottom) taken June 3, 1999 during EPA's pilot-scale testing
            of No. 6 fuel oil.
                                            B-10

-------
                                          6/4/99

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            of No. 6 fuel oil.
                                           B-ll

-------
                   6/7/99

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-------
                                   APPENDIX C
         Volatile Organic Compound Analysis Laboratory Reports

Concentrations of volatile organic compounds (VOCs) were measured in EPA's Organics Support
Laboratory, located in the Environmental  Research Center in Research Triangle Park, NC. Analyses
were conducted by chemists from ARCADIS  Geraghty & Miller, the contractor for  EPA's Air
Pollution Prevention and Control Division.

The analyses were conducted to specifically determine levels of benzene, ethylene, toluene, and
xylenes  (BTEX), which were the criteria compounds for the analyses.   The  laboratory report stated
that other compounds  detected may have been outside the criteria used for BTEX, and the data
should be evaluated using the case narrative supporting  the data.

The following pages are the detailed  case narrative and laboratory reports for each of the  three
samples collected from each of the three  fuels.  Also included are the matrix spike and matrix spike
dupicate results and the results from the field blank used to evaluate laboratory contamination of the
samples.
                                           C-l

-------
                Case Narrative for Orimulsion VOST Analysis by GC/MS







       A 5-point initial calibration was performed on April 28th and 29th, 1999. Each




calibration level and the method detection limit study was performed by flash evaporation at




235°C of methanolic aliquots of standard VOC's. Each VOST pair was allowed to stand for 5




minutes (after flish evaporation) at a flow of lOmL/min, transferred to the GC/MS clamshell




heater and thermally desorbed onto the GC/MS system. In an effort to ensure proper thermal




transfer for all of the target compounds, each VOST tube pair was positioned to bias the Tenax




portion fully into the heated zone. The calibration ranged between 10 ng and 250 ng on column.




Internal standards were injected into the sidearm of the sparging vessel during each calibration




and analysis. All target analytes had a relative standard deviation less than 30 % for this initial




calibration.




        Next, a 6 point method detection limit study was performed by spiking and analyzing a




clean, VOST pair with the low level standard of 10 nanograms for each target VOC and




surrogate VOC in accordance with SW-846 methodology for determination of detection limits.




All target analytes had method detection limit values at least a factor of 2 less than the lowest




calibration (PQL) except for two brominated compounds and tetrachloroethylene which were




both below the PQL of 10 ng.  Replicated matrix spikes of a separate BTEX standard was




peformed using flash evaporation. Spike recoveries ranged from 87 % to 116 % (values not




composited into a table but submitted in the regular report format). Two composited tables




inclusive of the calibration response factor data and the method detection limit study are




attached.
                                           C-2

-------
       A mid-level standard was performed prior to daily sample analysis. Relative percent




deviations less than 30 % when compared to the average response factors formed from the initial




calibration were found for all target analytes of interest.   The 4-bromofluorobenzene peak




chosen from this standard passed method tuning criteria on each day. Prior to sample analysis,




the system's inherent background for target components was determined. Sample VOST tubes




were spiked prior to field sampling with surrogate compounds specified by the method.  Samples




were tagged on the data spreadsheets to reflect the target VOC background determined from the




most recent matrix blank (other qualifiers were also attached). Values lower than the calculated




MDL for a few compounds such as dichloromethane, toluene, 1,2-dibromoethane, m,p xylenes,




bromobenzene and the dichlorobenzenes were noticed. The field blank demonstrated that all




compounds were below the calculated detection limit except for dichloromethane (which was




directly on the detection limit of 3.7 ng). All samples had similar results with low to mid-range




values of benzene, toluene, xylenes and styrene present. Carbon disulfide and dichloromethane




were present at varying levels.  If you have any questions, please give Dennis (ext...2686) a call.




                                  Bill Preston
                                  Arcadis Geraghty & Miller Chemist
                                          C-3

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                                  Orimulsion YOST Method Detection Limit Study
        Analyte

1,1 Dichloroethene
lodomethane
Carbon Disulfide
Dichloromethane
t-1,2-DichIoroethene
1,1-Dichloroethane
c-1,2-Dichloroethane
Bromochloromethane
Chloroform
1,1,1 -Trichloroethane
Carbon Tetrachloride
1,2-Dichloroethane
Benzene
Trichloroethene
1,2-Dichloropropane
Dibromomethane
Bromodichloromethane
c- 1,3-Dichloropropene
Toluene
t-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Styrene
Bromobenzene
1,4-Dichlorobenzene
1,3-Dichlorobenzene
1,2-Dichlorobenzene
 4/28/99   4/29/99   4/29/99    4/29/99    4/29/99    4/29/99
Run#l    Run #2    Run #3   Run #4   Run #5   Run #6     StdDev  MDL(ng)
8.90
10.45
8.37
14.04
9.52
9.55
9.97
10.10
9.79
9.57
9.45
10.59
13.14
10.15
9.83
10.54
9.64
9.90
11.91
11.22
10.64
10.18
9.06
10.39
10.11
9.99
17.44
10.13
10.57
9.95
9.74
9.70
9.80
7.99
9.40
7.60
13.74
8.84
8.73
9.27
8.48
9.13
9.64
9.57
9.21
12.06
9.52
9.53
8.91
9.18
8.84
12.16
9.41
8.64
10.23
8.85
8.39
9.33
9.36
15.83
9.05
8.93
9.37
9.21
8.53
8.81
7.62
8.47
7.15
13.55
8.61
8.33
8.80
8.15
8.68
9.06
9.02
8.80
11.94
11.40
11.86
10.76
9.97
10.27
11.13
8.25
7.91
9.63
9.43
9.72
8.55
8.81
15.16
8.67
8.78
8.40
8.33
8.11
8.25
7.86
7.99
7.21
13.88
8.65
8.51
9.15
8.44
9.31
9.44
9.20
9.74
10.72
9.99
9.94
9.87
9.69
9.84
12.00
10.07
9.89
12.82
12.01
12.34
10.66
10.93
19.40
11.41
11.31
10.87
10.72
10.57
10.30
7.93
8.07
7.31
16.23
8.64
8.90
9.05
8.94
8.54
8.77
8.79
8.94
11.69
8.72
8.93
8.39
7.54
7.72
10.56
8.07
7.47
8.63
6.96
7.57
7.65
8.08
14.00
8.03
8.05
7.48
7.52
7.36
7.37
8.02
7.69
7.47
17.06
8.60
9.35
8.56
9.78
9.61
9.40
9.24
10.06
12.43
9.04
9.89
9.45
7.51
8.70
11.17
8.38
7.59
9.46
6.90
8.25
7.98
8.13
13.58
7.47
7.22
7.06
6.89
6.53
6.49
0.49
1.04
0.50
1.10
0.38
0.47
0.44
0.77
0.50
0.37
0.32
0.73
0.87
0.98
1.10
1.02
0.97
1.04
0.68
1.31
1.33
1.55
1.81
1.85
1.20
1.09
2.10
1.33
1.36.
1.32
1.24
1.28
1.18
1.6
3.5
1.7
3.7
1.3
1.6
1.5
2.6
1.7
1.2
1.1
2.4
2.9
3.3
3.7
3.4
3.3
3.5
2.3
4.4
4.5
5.2
6.1
6.2
4.0
3.7
7.1
4.5
4.6
4.4
4.2
4.3
4.0
                                                    C-4

-------
                       Response Factor Report  Volatile
Method
Title
Last Update
Response via
H:\HPCHEM\2\METHODS\V042899.M (Chemstation Integrator)
Orimulsion VOST analysis by Method 5041
Wed May 05 20:07:56 1999
Initial Calibration
Calibration Files
3      =VS34289A.D   2
4      =VS44289A.D   5

     Compound
             =VS24289A.D   1
             =VS54299A.D
=VS14289B.D
                                           Avg    %RSD
1)
2)
3)
4)
5)
6)
"7)
8)
9)
10)
11)
12)
13)
14)
15)
1 C \
16)
17)
18)
19)
20)
21)
22)
23)
24)
25)
26)
27)
28)
29)
30)
31)
32)
33)
34)
35)
36)
37)
(#)
I Pentafluorobenzene
ccc-1, 1-Dichloroethen
lodomethane
Carbon disulfide
Dichlorome thane
trans-1, 2-Dichloroeth
1, 1-Dichloroethane
cis-1 , 2-Dichloroethen
Bromochloromethane
ccc-Chloroform
1,1, 1-Trichloroethane
Carbon tetrachloride
S d4-l,2 Dichloroethane
1, 2-Dichloroethane
Benzene
I 1, 4— Dif lluorobenzene
Trichloroethene
ccc-1, 2-Oichloroprop
Dibromomethane
Bromodichloromethane
cis-1, 3-Dichloroprope
s d8 -Toluene
ccc-Toluene
trans-1, 3-Dichloropro
1, 1, 2-Trichloroethane
Tet rachloroethene
Dibromochloromethane
1, 2-Dibromoethane
I d5-Chlorobenzene
Chlorobenzene
ccc-Ethylbenzene
m,p-Xylenes
o-Xylene
Styrene
S 4-Bromofluorobenzene
Bromobenzene
d4-l, 4-Dichlorobenzen
= Out of Range

	 ID ID — — — — 	 	
0.800
0.756
1.621
0.763
0.496
0.948
0.534
0.669
0.923
0.740
0.623
0.435
0.521
1.792
0.500
0.422
0.254
0.493
0.532
1.061
1.271
0.381
0.185
0.329
0.259
0.273
0.854
0.772
1.709
0.839
0.504
1.007
0.548
0.677
1.000
0.757
0.623
0.472
0.520
1.864
0.540
0.448
0.258
0.572
0.602
1.253
1.395
0.467
0.231
0.350
0.336
0.309
0.666
0.739
1.240
1.139
0.435
0.848
0.493
0.627
0.855
0.646
0.524
0.514
0.502
0.722
0.625
1.424
0.663
0<425
0.821
0.449
0.584
0.789
0.626
0.524
0.444
0.461
2.290 1.511
T CTI"\
loIU — -
0.505 0.491
0.394
0.262
0.468
0.521
1.290
1.545
0.444
0.201
0.324
0.239
0.289
0.366
0.246
0.449
0.498
1.109
1.137
0.380
0.195
0.293
0.268
0.306
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
699
652
420
652
424
816
451
549
801
598
477
364
368
254
453
371
222
442
478
992
135
306
138
294
217
215
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
1.
0.
0.
0.
0.
0.
748
709
483
811
457
888
495
621
874
673
554
446
475
742
498
400
248
485
526
141
296
395
190
318
264
278
10.
9.
12.
24.
8.
9.
9.
8.
10.
10.
11.
12.
13.
22.
6.
8.
6.
10.
9.
11.
13.
15.
17.
7.
17.
13.
32
30
47
45
70
60
23
88
11
49
86
38
53
40
29
66
28
89
00
10
56
92
76
71
04
75

	 ISTD 	
0.814
1.484
0.444
0.404
0.565
0.477
0.309
1.074
1.892
0.591
0.548
0.813
0.705
0.443
0.867
1.523
0.489
0.438
0.658
0.547
0.337
0.782
1.411
0.448
0.416
0.588
0.537
0.323
0.
1.
0.
0.
0,
0,
0
,752
,324
,341
.357
.488
.352
.281
0.
1.
0.
0.
0.
0,
0,
,858
,527
,462
,433
,623
.524
.338
14.
14.
19.
16.
19.
24.
18.
93
25
,51
,38
,69
.41
.37

	 — 	 lol U— 	 	










        V042899.M
        Fri Jul 16 17:10:43 1999
                 Page 1
                               C-5

-------
  Method
  Title
  Last Update
  Response via
        Response Factor Report  Volatile

H:\HPCHEM\2\METHODS\V042899.M  {Chemstation Integrator)
Orimulsion VOST analysis by Method 5041
Wed May 05 20:07:56 1999
Initial Calibration
   Calibration Files
   3      =VS34289A.D
   4      =VS44289A.D

        Compound
      2
      5
=VS24289A.D
=VS54299A.D
                                   =VS14289B.D
                                           Avg
                                     %RSD
38)      If3-Dichlorobenzene
39)      l,4-Dichlorobenzene
40)      1,2-dichlorobenzene
             0.926 1.430 0.997 0.963 0.834  1.030   22.48
             0.895 1.350 0.968 0.962 0.816  0.998   20.64
             0.775 1.151 0.854 0.882 0.699  0.872   19.66
 (#)  = Out of Range
           V042899.M
        Fri Jul 16  17:10:44 1999
                                       Page 2
                              C-6

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
   Project:         Orimulsion
   Sample Name:   5181405
   Lab Sample ID:  9905029
   MS Data file:    V995299A
   Method:        5041A
                           Date Sampled:   05/18/99
                           Date Acquired:  05/24/99
                           Analyst:        Bill Preston
                           QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Sample/905181405SV 10BL04-Clamshell temp controller failed to maintain at 233°c
   and was noticed at 330°C after analysis/Benzene in blank at 2.9 ng
   Surrogates

   d4-l,2-dichloroethane(suiT)
   d8-toluene (surr)
   4-bromofluorobenzene(surr)

   Compound
                 % Recovery

                  86.1    P
                  100.4   P
                  119.7   P
                            Compound
ng
    1.1 Dichloroethene
    lodomethane
    Carbon Disulfide
    Dichloromethanc
    t-1,2-Dichlorocthcne
    1.1-Dichloroethane
    c-1 ,2-Dichloroethane
    Bromochloromethanc
    Chloroform
    1,1,1-Trichloroethane
    Carbon Tctrachloride
    1,2-Dichloroethanc
    Benzene
    Trichloroethene
    1,2-Dichloropropane
    Dibromomethane
                   ND      Bromodichloromethane
                   ND      c-13-Dichloropropcnc
                   5.9   J  Toluene
                  183.0      t-l,3-Dichloropropene
                   ND      1,1,2-Trichloroethane
                   ND      Tetrachlorocthene
                   ND      Dibtomochloromethane
                   ND      1,2-Dibrornoethane
                   ND      Chlorobenzene
                   ND      Bthylbenzene
                   ND      m,p-Xylenes
                   ND      o-Xylene
                   40.2   B Styrene
                   ND      Bromobenzene
                   ND      U-Dkhlorobenzene
                   ND      1,4-Dichlorobenzene
                            1,2-DichIorobenzene
ND
ND
19.3
ND
ND
ND
ND
ND
ND
3.9
11.9
ND
16.5
ND
ND
ND
ND
    ND = ooc detected
    Undetected in blank
E = Peak over calibration range
J = Peak bdow the calibration range
7/28/99
                        ARCADIS Geraghty Miller
                                                                                                   518H05.xls
                                                C-7

-------
   APPCD Organic Support Laboratory
   Volatile Organic Sampling Tube Report
   Project:
   Sample Name:
   Lab Sample ID:
   MS Data file:
   Method:
Orimulsion
5191058
9905030
V995309A
5041A
Date Sampled:   05/19/99
Date Acquired:  05/24/99
Analyst:        Bill Preston
QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Sample/903191058SV20BUM-CUmshdl decorber temp controller failed to maintain at 233°C
   and was noticed at 330°C after analysis/Benzene in blank at 2.9 ng
   Surrogates

   d4-1,2-dichlorocthane(«urr)
   d8-tolucne (SUIT)
   4-bromofluorobenzene(iurr)

   Compound
                  % Recovery

                   84.1    P
                   97.3    P
                   107.6   P
                            Compound
                                 ng
    1,1 Dichloroethene
    lodomethane
    Carbon Disulfidc
    Dichloromethane
    t-l,2-Dichloroethene
    1,1-Dichloroethane
    c-1,2-Dichloroethane
    Bromochloromcthane
    Chloroform
    1,1,1-Trichloroethane
    Carbon Tetrachloridc
    1,2-Dichloroethane
    Benzene
    Trichloroethene
    1,2-Dichloropropane
    Dibromomethane
                    ND      Bromodichloromethane
                    5.5    I c-l,3-Dichloropropcne
                    59.9     Toluene
                    59.9     t-l,3-Dichloropropene
                    ND       1,1,2-Trichloroethane
                    ND      Tetrachloroethene
                    ND      Dibromochloromethane
                    ND       1,2-Dibromoethane
                    ND      Chlorobenzene
                    ND      Ethylbenzene
                    ND       m,p-Xylcnes
                    ND      o-Xytene
                    102.9   B  Styrene
                    ND       Bromobenzene
                    ND      1,3-Dichlorobenzene
                    ND      1,4-Dichlorobenzene
                             1 ,2-Dichlorobenzene
                                ND
                                ND
                                28.5
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                9.5
                                ND
                                20.6
                                ND
                                ND
                                ND
                                ND
    ND = not delected    E = Peak over calibration range
    Undetected in blank   I = Pe*k I
7/28/99
                         ARCADIS Geraghty Miller


                        C-8
                                                                                                  519105il.xls

-------
       APPCD Organic Support Laboratory
       Volatile Organic Sampling Tube Report
      Project:         Orimulsion
      Sample Name:   5211256
      Lab Sample ID:  9905041
      MS Data file:    V995419A
      Method:         5041A
           Date Sampled:   05/21/99
           Date Acquired:   05/24/99
           Analyst        Bill Preston
           QC reviewer:    Dennis Tabor
      Sample Description/Narrative:

      Sample/90521 1256SV10BUM-a.msnelI temp controller failed to maintain ,t 233'c
      and was noticed at 330«C after analysis/Benzene in blank at 2.9 ng.
      Surrogates

      d4-l,2-dichloroedune(surr)
      d8-toluene (surr)
      4-bromofluorobenzene(siirr)

      Compound
% Recovery
 85.5
 32.2
 109.1
       P
       F
       P
                                                 Compound
      1,1 Dichloroethene
      lodomethane
      Carbon Disulfide
      Dichloromethane
      M.2-Dichloroethene
      1.1-Dichloroethane
      c-l^-Dichloroethane
      Bromochloromethane
      Chloroform
      1,1.1-Trichloroethane
      Carbon Tetrachloride
      U-Dfchloroethane
      Benzene
      Trichlorocthene
      1,2-Dichloropropane
      Dibromomethanc
 6.1
 72.4
 64.3
 ND
 ND
 ND
 ND
 ND
 ND
 ND
 ND
135.0
 ND
 ND
 ND
          Bromodichloromethane
          c-1.3-Dichloropropene
          Toluene
          t-l,3-Dichloropropene
          1.1.2-Trichloroethane
          Tetrachloroethene
          Dibromochloromethane
          U-Dibromoemane
          Chlorobenzene
          Ethylbenzene
          m,p-Xylenes
          o-Xylene
          Styrene
          Bromobenzene
          13-Dichlorobenzene
          1.4-Dichlorobenzene
          1,2-Dichlorobenzene
 ND
 ND
 7.1
 ND
 ND
 ND
 ND
 ND
 ND
 ND
 9.2
 ND
22.3
 ND
 ND
 ND
 ND
                    E = lt*overalib«io0iin|e
     Undetected in blank   J = Pe* below die calibwion nnje
7/28«9
                                           ARCAD1S Geraghty Miller


                                             C-9
                                                           521I256.«U

-------
   APPCD Organic Support Laboratory
   Volatile Organic Sampling Tube Report
   Project:         Orimulsion
   Sample Name:   5241337
   Lab Sample ID:  9905042
   MS Data file:    V990542A
   Method:         5041A
         Date Sampled:   05/24/99
         Date Acquired:  05/31/99
         Analyst:        Bill Preston
         QC reviewer:    Dennis Tabor
    Sample Description/Narrative:

    Sample/905241337SV1OBLO1
    Surrogates

    d4- l,2-dichlorocthane(surr)
    d8-loluene (surr)
    4-bromofluoroben2cne(surr)

    Compound
 Recovery
65.8
94.1
115.0
         Compound
    1,1 Dichloroethene
    lodomethane
    Carbon Disulfide
    Dichloromethane
    t-l,2-Dichloroethene
    1,1-Dichloroethanc
    c-1,2-Dichloroethane
    Bromochloromethane
    Chloroform
    1,1.1 -Trichlorocthanc
    Carbon Tetrachloride
    1,2-Dichlorocthane
    Benzene
    Trichloroethene
    1,2-Dichloropropanc
    Dibromomethane
 ND       Bromodichloromethane
 ND       c-13-Dichloropropene
 7.6    J  Toluene
 36.6       t-l,3-Dichloropropene
 ND       1,1.2-Trichloroethane
 ND       Tetrachloroethene
 ND       Dibromochloromethane
 ND       1,2-Dibromoethane
 ND       Chlorobenzene
 ND       Ethylbenzene
 ND       m,p-Xylenes
 ND       o-Xylenc
 20.6       Styrene
 ND       Bromobenzene
 ND       1.3-Dichlorobenzene
 ND       1,4-Dichlorobenzene
          1,2-Dichlorobenzene
ND
ND
12.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
    ND = not detected    E = Peak over calibration range
    B=detecied in blank   J = Peak below the calibration range
7/8/99
                                            ARCADIS Geraghly Miller
                                                             5241337.xls
                                              C-10

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:          Orimulsion
  Sample Name:    5251243
  Lab Sample ID:   9905051
  MS Data file:    V990551A
  Method:         5041A
                          Date Sampled:   05/25/99
                          Dale Acquired:  05/31/99
                          Analyst:        Bill Preston
                          QC reviewer:    Dennis Tabor
  Sample Description/Narrative:

  Sample/905251243S V1OBLO1
   Surrogates

   d4-1,2-dichloroethane(surr)
   d8-toluene (SUIT)
   4-bromofluorobenzene(surr)

   Compound
                % Recovery

                 100.9   P
                 71.0   P
                 119.8   P

                  ng
Compound
   1,1 Dichloroethene
   lodomethane
   Carbon Disulfidc
   Dichloromethane
   t-1,2-Dichloroethene
   1,1 -Dichloroe thane
   c-1,2-Dichloroethane
   Bromochloromethane
   Chloroform
    1,1,1-Trichloroethane
   Carbon Tetrachloride
    1,2-Dichloroethane
   Benzene
   Trichlorocthene
    1,2-Dichloropropane
    Dibromomethane
                  ND      Bromodichloromethane
                  ND      c-l,3-Dichloropropene
                  3.0   J  Toluene
                  10.7      t-l,3-Dichloropropene
                  ND      1,1,2-Trichloroethane
                  ND      Tetrachloroethene
                  ND      Dibromochloromethane
                  ND      1,2-Dibromoethane
                  ND      Chlorobenzene
                  ND      Ethylbenzene
                  ND      m,p-Xylenes
                  ND      o-Xylene
                  55.2      Styrene
                  ND      Bromobenzene
                  ND      1,3-Dichlorobenzcne
                  ND      1,4-Dichlorobenzenc
                           1,2-Dichlorobenzene
                                ND
                                ND
                                13.3
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                7.5
                                ND
                                9.3
                                ND
                                ND
                                ND
                                ND
    ND = not delected
    B=deiected in blink
E - Peak over calibration range
J = Peak below the calibration range
7/28/99
                        ARCADIS Geraghty Miller
                                                                                                   5251243-Xls
                                         C-ll

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
   Project:         Orimulsion
   Sample Name:   5261102
   Lab Sample ID:  9905057
   MS Data file:    V990557A
   Method:         5041A
                           Date Sampled:   05/26/99
                           Date Acquired:  05/31/99
                           Analyst:        Bill Preston
                           QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Sample/905261102SV10BL01
   Surrogates

   d4-1,2-dichloroethanc(surr)
   d8-toluene (SUIT)
   4-bromofluorobenzene(surr)

   Compound
                % Recovery

                  73.1    P
                  96.3    P
                  117.0   P

                   ng
Compound
    1,1 Dichloroethene
    lodomethane
    Carbon Disulfide
    Dichloromethane
    t-1,2-Dichloroethene
    1,1 -Dichloroethane
    c-1,2-Dichloroethane
    Bromochloromethane
    Chloroform
    1.1,1-Trichloroethane
    Carbon Tetrachloride
    1,2-Dichloroethane
    Benzene
    Trichloroethene
    1,2-Dichloropropanc
    Dibromomethane
                   ND       Bromodichloromethane
                   ND       c-l,3-Dichloropropene
                   5.0    J  Toluene
                   55.0      t-l,3-Dichloropropene
                   ND       1,1,2-Trichloroethane
                   ND       Tetrachloroethene
                   ND       Dibromochloromethane
                   ND       1,2-Dibromoethane
                   ND       Chlorobenzene
                   ND       Ethylbenzene
                   ND       m,p-Xylenes
                   ND      o-Xylene
                   73.6      Styrene
                   ND      Bromobenzene
                   ND      1,3-Dichlorobenzene
                   ND      1,4-Dichlorobenzene
                            1,2-Dichlorobenzenc
                                ND
                                ND
                                19.1
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                3.7
                                10.0
                                ND
                                5.4
                                ND
                                ND
                                ND
                                ND
    NDc not detected
    Undetected in blank
E = Peak over calibration range
J = Peak below the calibration range
7/8/99
                        ARCADIS Gcraghty Miller
                                                                                                    5261102.xls
                                          C-12

-------
     APPCD Organic Support Laboratory
     Volatile Organic Sampling Tube Report
     Project:
     Sample Name:
     Lab Sample ID:
     MS Data file:
     Method:
Orimulsion
6031301
9906006
V996006A
5041A
   Date Sampled:   06/04/99
   Date Acquired:  06/17/99
   Analyst:        Bill Preston
   QC reviewer:    Dennis Tabor
     Sample Description/Narrative:

     Sample/906031301S V1OBLR6
     Surrogates

     d4-1,2-dichloroethane(surr)
     d8-toluenc (SUIT)
     4-bromofluorobenzene(surr)

     Compound
                 % Recovery
                   64.7
                   90.7
                   123.9

                    ng
F
P
P
                                                Compound
     1,1 Dichloroethene
     lodomethane
     Carbon Disulfidc
     Dichloromethane
     t-1.2-Dichloroethene
     1,1-Dichloroe thane
     c-1.2-Dichloroe thane
     Bromochloromethane
     Chloroform
     1,1.1 -Trichloroethane
     Carbon Tetrachloridc
     1,2-Dichloroethane
     Benzene
     Trichloroethene
     1,2-Dichloropropane
     Dibromomcthane
                   ND      Bromodichloromethane
                   ND      c-1,3-Dichloropropene
                   28.9      Toluene
                   ND      t-1,3-Dichloropropene
                   ND      1,1,2-Trichloroethane
                   ND      Tetrachloroethene
                   ND      Dibromochloromethane
                   ND      1,2-Dibromoethane
                   ND      Chlorobenzene
                   ND      Ethylbenzene
                   ND      m,p-Xylenes
                   ND      o-Xylene
                   23.6      Styrene
                   ND      Bromobenzene
                   ND      1,3-Dichlorobenzene
                   ND      1,4-Dichlorobenzene
                            1,2-Dichlorobenzene
                                  ND
                                  ND
                                  47.9
                                  ND
                                  ND
                                  ND
                                  ND
                                  ND
                                  ND
                                  30.9
                                  113.1
                                  37.6
                                  15.3
                                  ND
                                  ND
                                  ND
                                  ND
     ND = not delected    E = Peak over calibration range
     B=dciecled in blank   J = Peak below the calibration range
7/28/99
                                           ARCADIS Oeraghiy Miller

                                             C-13
                                                                               603l301.xls

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:        Orimulsion
  Sample Name:   6041340
  Lab Sample ID:  9906015
  MS Data file:   V996015A
  Method:        5041A
                           Date Sampled:   06/04/99
                           Date Acquired:  06/17/99
                           Analyst:        Bill Preston
                           QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Sample/906041340SV10BLR6
   Surrogates

   d4-1,2-dichloroethanc(surr)
   d8-toluene (SUIT)
   4-bromofluorobcnzenc(suir)

   Compound
                 % Recovery

                  57.3    F
                  95.5    P
                  134.1   F

                   ng
Compound
   1,1 Dichlorocthcne
   lodomethane
   Carbon Disulfide
   Dichloromethane
   t-1,2-Dichloroelhcne
   1,1 -Dichloroethane
   c-1,2-Dichloroemane
   Bromochloromethane
   Chloroform
    1,1,1-Trichloroethane
   Carbon Tetrachloride
    1,2-Dichloroethane
   Benzene
   Trichloroethene
    1,2-Dichloropropane
    Dibromomethane
                   ND       Bromodichloromethanc
                   ND       c-l,3-Dichloropropcnc
                   7.2    J  Toluene
                  383.8      t-l,3-Dichloropropene
                   ND       1,1,2-Trichloroethane
                   ND       Tetrachloroelhenc
                   ND       Dibromochloromethane
                   ND       1,2-Dibromoethane
                   ND       Chlorobenzene
                   ND       Ethylbenzene
                   ND       m,p-Xylenes
                   ND       o-Xylene
                   20.0      Styrene
                   ND      Bromobenzene
                   ND      1,3-Dichlorobenzene
                   ND      1,4-Dichlorobcnzcne
                            1,2-Dichlorobenzene
                                ND
                                ND
                                13.7
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                5.2
                                23.9
                                6.4
                                10.0
                                ND
                                ND
                                ND
                                ND
    ND = not detected
    Undetected in blink
E = Peak over calibration range
J = Peak below the calibration range
7/28/99
                        ARCADIS Geraghly Miller


                      C-14
                                                                                                    604l340.xls

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:
  Sample Name:
  Lab Sample ID:
  MS Data file:
  Method:
Orimulsion
6071305
9906018
V990618A
5041A
Date Sampled:   06/07/99
Date Acquired:  06/16/99
Analyst:        Bill Preston
QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Sample/906071305SV10BLR6
   Benzene in matrix blank at 4.9 ng.

   Surrogates                        % Recovery

   d4-l,2-dichloroethane(surr)             64.5   F
   dS-toluene (surr)                     82.0   P
   4-bromofluorobenzene(surr)            157.0   F

   Compound                          ng       Compound
                                                             ng
   1,1 Dichloroethene
   lodomelhane
   Carbon Disulfidc
   Dichloromethane
   t-1,2-Dichloroethene
   1,1-Dichlorocthane
   c-1,2-Dichlorocthanc
   Bromochloromethane
   Chloroform
   1,1,1-Trichloroethane
   Carbon Tetrachloride
    1,2-Dichloroe thane
   Benzene
   Trichloroethene
    1,2-Dichloropropane
    Dibromome thane
                    ND      Bromodichloromethane
                    ND      c-l,3-Dichloropropene
                    22.3      Toluene
                    ND      t-l,3-Dichloropropene
                    ND      1,1.2-Trichloroethane
                    ND      Tetrachloroethene
                    ND      Dibromochloromcthane
                    ND      1,2-Dibromoethane
                    ND      Chlorobenzene
                    ND      Ethylbenzene
                    ND      m,p-Xylcnes
                    ND      o-Xylene
                    16.0   B Slyrene
                    ND      Bromobenzene
                    ND       1,3-Dichlorobenzene
                     ND       1,4-Dichlorobenzene
                              1,2-Dichlorobenzene
                                 ND
                                 ND
                                 25.9
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 8.2
                                 36.7
                                 9.9
                                 10.4
                                 ND
                                 ND
                                 ND
                                 ND
    ND = not detected
    Undetected in blank
  E = Peak over calibration range
  J = Peak below the calibration range
7/28/99
                          ARCAD1S Geraghty Miller
                                                                                                   607l305.xls
                                          C-15

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:         Orimulsion
  Sample Name:   4301230/FB
  Lab Sample ID:  9905001
  MS Datafile:    V995001A
  Method:         5041A
          Date Sampled:  04/30/99
          Date Acquired:  04/30/99
          Analyst:        Bill Preston
          QC reviewer:   Dennis Tabor
   Sample Description/Narrative:

   Sample/904301230SV10BLR6/Field Blank
   3.7 ng of dichloromethane was in the matrix blank
   Surrogates

   d4-1,2-dichloroethane(surr)
   d8-toluene (SUIT)
   4-bromofluorobenzene(surr)

   Compound
% Recovery

  91.6   P
  101.6   P
  120.6   P

  ng
Compound
ng
    1,1 Dichloroethene
    lodomethane
    Carbon Disulfide
    Dichloromethane
    t-1,2-Dichloroethene
    1,1-Dichloroe thane
    c-1,2-Dichloroethane
    Bromochlotomethanc
    Chloroform
    1,1,1-Trichloroethane
    Carbon Tetrachloride
    1,2-Dichloroethane
    Benzene
    Trichlorocthcne
    1,2-Dichloropropane
    Dibromomethane
  ND      Bromodichloromethanc
  ND      c-l,3-Dichloropropene
  ND      Toluene
  3.7   J,B t-l,3-Dichloropropene
  ND      1,1,2-Trichloroethane
  ND      Tetrachloroethene
  ND      Dibromochloromethane
  ND      1,2-Dibromoethane
  ND      Chlorobenzene
  ND      Ethylbenzene
  ND      m,p-Xylenes
  ND      o-Xylene
  ND      Styrene
  ND      Bromobenzene
  ND       1,3-Dichlorobenzene
  ND       1,4-Dichlorobenzene
            1,2-Dichlorobenzene
                                ND
                                ND
                                2.3
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
    ND - not detected   E = Peak over calibration range
    B=detected in blank  1 = Peak below the calibration range
7/28/99
       ARCADIS Geragluy Miller
                                                                                                    4301230.xls
                                                C-16

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:         Orimulsion
  Sample Name:   Matrix Spike
  Lab Sample ID:  9905049
  MS Data file:    V990549a
  Method:         5041A
                          Date Spiked:     05/25/99
                          Date Acquired:   05/25/99
                          Analyst:        Bill Preston
                          QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Tenax-B05689/T/C-B05695
   Matrix Spike #1 at 150 ng each B.T.E.X component
   Surrogates

   d4-1,2-dichloroethanc(surr)
   d8-loluene (surr)
   4-bromofluorobenzene(surr)

   Compound
                % Recovery

                  86.6   P
                  103.9  P
                  112.7  P

                   ng
Compound
ng
   1,1 Dichloroethene
   lodomethane
   Carbon Disulfide
   Dtchloromethane
   t-l,2-Dichloroethcne
   1,1 -Dichloroethane
   c-1,2-Dichlorocthanc
   Bromochloromethane
   Chloroform
    1,1,1 -Trichloroethane
   Carbon Tetrachloride
    1,2-Dichloroethane
    Benzene
    Trichloroethene
    1,2-Dichloropropane
    Dibromomethane
                   NS      Bromodichloromethane
                   NS      c-l,3-Dichloropropcne
                   NS      Toluene
                   NS      t-l,3-Dichloropropene
                   NS       1,1,2-Trichloroethane
                   NS      Tetrachloroethene
                   NS       Dibromochloromethane
                   NS       1,2-Dibromoethane
                   NS       Chlorobenzene
                   NS       Ethylbenzene
                   NS       m,p-Xylenes
                   NS       o-Xylene
                   135.0      Styrene
                   NS       Bromobenzene
                   NS       1,3-Dichlorobenzene
                   NS       1,4-Dichlorobenzene
                            1,2-Dichlorobenzene
                                NS
                                NS
                               1453
                                NS
                                NS
                                NS
                                NS
                                NS
                                NS
                               161.4
                               173.8
                               168.8
                                NS
                                NS
                                NS
                                NS
                                NS
    ND = not spiked
    B=detected in blank
E = Peak over calibration range
J = Peak below the calibration range
7/8/99
                        ARCAD1S Geraghty Miller
                                                                                                   orivolmsl.xls
                                                C-17

-------
  APPCD Organic Support Laboratory
  Volatile Organic Sampling Tube Report
  Project:
  Sample Name:
  Lab Sample ID:
  MS Data file:
  Method:
Orimulsion
Matrix Spike
9905050
V990550A
5041A
Date Spiked:    05/25/99
Date Acquired:  05/25/99
Analyst:        Bill Preston
QC reviewer:    Dennis Tabor
   Sample Description/Narrative:

   Tenax-B05689/T/C-B05695
   Matrix Spike #2 at 150 ng each B,T,E,X component
   Surrogates

   d4-1,2-dichloroethane(surr)
   d8-toluene (SUIT)
   4-bromofluorobenzene(surr)

   Compound
                     Recovery

                    87.5    P
                    89.4    P
                    112.5   P
                              Compound
    1,1 Dichloroethene
    lodomethane
    Carbon Disulfide
    Dichloromcthane
    t-1,2-Dichlorocthcnc
    1,1 -Dichloroethane
    c-1,2-Dichloroethane
    Bromochloromcthane
    Chloroform
    1,1,1-Trichloroethane
    Carbon Telrachloride
    1 ^-Dichloroethane
    Benzene
    Trichloroethene
    1,2-Dichloropropane
    Dibromomethane
                     NS       Bromodichloromethane
                     NS       c-l,3-Dichloropropene
                     NS       Toluene
                     NS       t-1,3-Dichloropropene
                     NS       1,1,2-Trichloroethane
                     NS       Tetrachloroethene
                     NS       Dibromochloromethane
                     NS       1,2-Dibromoethane
                     NS       Chlorobenzene
                     NS       Ethylbenzene
                     NS       m,p-Xylenes
                     NS       o-Xylene
                     130.4     Styrene
                     NS       Bromobenzene
                     NS       1,3-Dichlorobenzene
                     NS       1,4-Dichlorobcnzene
                              1,2-Dichlorobcnzene
                                 NS
                                 NS
                                139.9
                                 NS
                                 NS
                                 NS
                                 NS
                                 NS
                                 NS
                                169.0
                                172.0
                                172.9
                                 NS
                                 NS
                                 NS
                                 NS
                                 NS
    ND = not ipiked
    B=deceded in blank
  E = Peak over calibration range
  J = Peak below (he calibration range
7/8/99
                          ARCADIS Geraghty Miller
                                                                                                   orivolmsd.xls
                                           C-18

-------
                    APPENDIX D
Semivolatile Organic Compound Analysis Laboratory Reports
                         D-l

-------
      Case Narrative for Orimulsion Semivolatile Analysis by Method 8270






       A five-level calibration was performed  on June 24 -25th, 1999. Levels 1 through 4




(10,30,60, and 90 ug/mL) were analyzed on June 24th and level 5 (100 ug/mL) was analyzed on




June 25th, 1999. The relative standard deviation of the average response factors throughout the




calibration range was generally below 10 % with few exceptions.  The relative standard deviation




for 13C6-2,5-phthalic anhydride was the only constituent greater than 30 % at 37.21%.  A rigorous




method detection limit study was not performed prior to sample analysis. Past semivolatile analysis




allowed insight for establishing an arbitrary cutoff of 1 ug/mL (1 ng on column) for the instrumental




detection limit. Sample concentrations near this value were scrutinized carefully to ensure excellent




retention time matching and adequate confirmation ion ratios.




       Method 8270 daily sample analysis consisted of initially passing the DFTPP tuning criteria.




The monitoring for the presence of benzidine in the DFTPP tuning solution (which was present hi




all cases) and the monitoring for DDT lack of degradation were done daily prior to sample analysis.




After the DFTPP passed all tuning criteria, a mid-point calibration standard was analyzed.  The mid-




level standard was compared to the initial calibration curve. All constituents of interest were less




than 30 % relative deviation in all cases.




       Each sampling condition had three separate analyses: XAD, filter, and the condensate which




were analyzed bjetween July 25th and July 29th, 1999. Pre-extraction surrogates were spiked into




every sample arid pre-sampling surrogates (additional  APPCD-OSL QC) were added to the XAD




portions only. Generally, the pre-extraction and pre-sampling surrogates passed pass/fail criteria (a
                                            D-2

-------
table comprising the acceptance criteria for the pre-sampling and pre-extraction surrogates is




attached).  Replicated matrix spikes of P AHs of interest determined recovery values between 50%




and 77% when compared to the initial calibration.  This directly parallels the surrogates recovery




data.  All samples had very low to non-detectable levels for most of the PAH targets and for the




additional analyte list with a few exceptions for phthalates. If you have any questions, please give




me a call at ext...2719.








                                           Arcadis Geraghty & Miller Chemist,
                                            Bill Preston
                                             D-3

-------
                                              Sheet!
Surrogates Recovery Limits Used for the Orimulsion Study
          Description







          2-Fluorophenol






          d5-Phenol






          2,4,6-Tribromophenol







          d5-Nitrobenzene






          2-Fluorobiphenyl
Recovery limits
24-113
25-121
19-122
23-120
 30-115
                                              D-4

-------
  Method
  Title
  Last Update
  Response via
        Response Factor Report  Semi2

F:\ORIMUL~1\METHODS\S062499.M (RTE Integrator)
Orimulsion PAH Analysis by method 8270
Wed Jul 28 08:42:17 1999
Initial Calibration
Calibration Files
2 =SC26249A.D 1
4 =SC46249A.D 5
Compound
1) i
2)
3)
4) S
5)
6)
7)
8)
9) S
10) M
11)
12)
13) M
14) s
15)
16)
17)
18)
19)
20)
21)
22)
23) M
24) i
25) S
26)
27)
28)
29)
30)
31) s
32) M
33)
34) s
35)
36)
37)
38)
D4-1, 4-dichlorobenzen
n-Nitrosomethylethyla
Methyl Methanesulfona
2-Fluorophenol (surrll
n-Nitrosodiethylamine
Bis (2-chloroethyl) eth
Ethyl methanesulfonat
Aniline
D5-Phenol(surr#2)
Phenol (CCC)
2-Chlorophenol
1, 3-Dichlorobenzene
1, 4-Dichlorobenzene (C
13C6-1,2 dichlorobenz
1, 2-Dichlorobenzene
Benzyl Alcohol
Bis (2-chloroisopropyl
2-Methylphenol
n-Nitrosospyrrolidine
Acetophenone
Hexachloroethane
4 -methylphenol
N-nitrosodi-n-propyla
DS-Naphthalene (QS#2)
05-Nitrobenzene (surr#
Nitrobenzene
1-Nitrosopiperidine
Isophorone
2, 4-Dimethylphenol
Bis (2-chloroethoxy)me
13C6-2,5 dichlorophen
2, 4-Dichlorophenol (CC
1,2, 4-Trichlorobenzen
13C6-Napthalene (pre
Naphthalene
2-Nitrophenol (CCC)
2, 6-Dichlorophenol
Hexachloropropene
=SC16249A.D
=SC56259A.D
2 1
3
3
=SC36249A.D
4 5 Avg
%RSD

— — J-bl U —
0.
0.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
1,
0,
1,
0
2
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
743
801
506
610
396
460
692
698
832
378
625
653
,448
.516
.862
.650
.238
.517
.886
.687
.541
.905
.504
.516
.301
.936
.326
.474
.320
.317
.363
.122
.073
.227
.313
.235
0.757
0.889
1.625
0.622
1.567
1.593
2.127
1.873
2.004
1.538
1.681
1.778
1.273
1.624
0.886
0.742
1.374
0.558
2.054
0.746
2.889
0.983
0.559
0.570
0.343
1.053
0.359
0.532
0.288
0.340
0.399
1.020
1.158
0.236
0.331
0.243
0.
0.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
1.
0.
1.
0.
2,
0,
0
0
0
0
0
0
0
0
0
1
1
0
0
0
815
865
522
674
435
577
535
775
899
456
663
712
436
553
913
678
,311
,565
,938
.700
.611
0.817
0.827
1.446
0.671
1.358
1.488
1.594
1.662
1.797
1.382
1.632
1.647
1.391
1.491
0.815
0.653
1.175
0.533
1.736
0.668
2.275
.935 0.889
T GTH
1 O 1 U
.509 0.513
.537
.315
.977
.337
.485
.330
.329
.367
.116
.086
.243
.328
.250
0.518
0.308
0.965
0.336
0.482
0.332
0.322
0.375
1.094
1.048
0.242
0.323
0.258
0.816
0.895
1.512
0.660
1.478
1.588
1.616
1.751
1.855
1.467
1.695
1.744
1.414
1.599
0.868
0.661
1.258
0.511
1.931
0.737
2.507
0.898
0.535
0.545
0.328
1.013
0.339
0.498
0.325
0.344
0.391
1.094
1.109
0.247
0.337
0.272
0.
0.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
1.
0,
1,
0,
2
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
790
855
522
647
447
541
713
752
878
444
659
707
,392
.557
.869
.677
.271
.537
.909
.708
.565
.922
.524
.537
.319
.989
.339
.494
.319
.330
.379
.089
.095
.239
.327
.252
4.64
4.74
4.25
4.55
5.58
4.05
13.91
4.62
4.26
4.62
1.84
3.33
5.06
3.56
4.17
5.61
5.92
4.51
6.03
4.66
8.61
4.17
4.36
4.12
5.28
4.56
3.64
4.63
5.53
3.53
4.07
3.75
3.81
3.36
2.71
5.73
(#)  = Out of Range
          S062499.M
       Fri Jul 30 14:47:33 1999
Page 1
                            D-5

-------
  Method
  Title
  Last Update
  Response  via
        Response Factor Report  Semi2

F:\ORIMUL~1\METHODS\S062499.M  (RTE Integrator)
Orimulsion PAH Analysis by method 8270
Wed Jul 28 08:42:17 1999
Initial Calibration
   Calibration Files
2
4
39)
40) M
41)
42) M
43)
44) i
45)
46) s
47)
48) M
49) M
50)
51) S
52)
53)
54)
55)
56)
57)
58)
59)
60)
=SC26249A.D 1
=SC46249A.D 5
Compound
4-Chloroaniline
Hexachlorobutadiene (C
n-Nitrosodi-n-butylam
4-Chloro-3-methyl-phe
2-Methylnaphthalene
DIO-Acenaphthene (QS#3
Isosafrole
13C6-Phthalic Anhydri
1,2,4, 5-Tetrachlorobe
Hexachlorocyclopentad
2,4, 6-Trichlorophenol
2,4, 5-Trichlorophenol
2-Fluorobiphenyl (surr
2-Chloronaphthalene
1,3 Dinitrobenzene
2-Nitroaniline
3-Nitroaniline
Safrole
Acenaphthylene
1 , 4-Naphthoquinone
Dimethylphathalate
2, 6-Dinitrotoluene
61) M Acenaphthene (CCC)
62)
63)
64)
1 -Napthylamine
2-Napthylamine
4-Nitroaniline
65) M 2, 4-Dinitrophenol (SPC
66)
67)
68)
69)
Dibenzofuran
Pentachlorobenzene
2, 4-Dinitrotoluene
2,3,4, 6-Tetrachloroph
70) M 4-Nitrophenol(SPCC)
71)
72)
73)
74)
75)
76)
77) S
Fluorene
Diethyl phathalate
4-Chlorophenyl phenyl
2-Methyl-4, 6-dinitrop
5-Nitro-o-toluidine
Diphenylamine
; 2, 4, 6-Tribromophenol (
=SC16249A.D 3
=SC56259A.D
213
0.378
0.214
0.225
0.312
0.651
0.549
0.135
0.670
0.429
0.434
0.471
1.339
0.473
0.253
0.490
0.377
0.257
1.869
0.311
1.421
0.340
1.135
0.934
0.552
0.543
0.163
1.679
0.512
0.440
0.335
0.318
1.297
1.439
0.638
0.252
0.377
1.090
0.179
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
2.
0.
1.
0.
1.
0.
0.
0.
434
219
236
353
716
574
153
707
426
452
483
468
488
255
500
398
267
020
318
480
354
229
813
394
540
0.136
1.
0.
0
0
0
1
1
0
0
0
1
0
771
529
455
344
293
383
563
652
228
.414
.114
.182
0.321
0.219
0.246
0.330
=SC36249A.D
4 5 Avg
0.215
0.227
0.241
0.321
0.658 0.647
T OTT\
Ibl U
0.588 0.578
0.139
0.709
0.460
0.464
0.492
1.406
0.490
0.270
0.491
0.383
0.263
1.955
0.312
1.431
0.355
1.181
0.866
0.482
0.463
0.187
1.709
0.539
0.447
0.335
0.320
1.291
1.441
0.654
0.265
0.350
1.096
0.183
0.083
0.709
0.462
0.463
0.484
1.367
0.478
0.269
0.475
0.371
0.261
1.922
0.301
1.408
0.351
1.168
0.760
0.371
0.463
0.196
1.666
0.535
0.449
0.336
0.319
1.267
1.422
0.644
0.274
0.351
1.072
0.185
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
1.
0.
1.
0.
0.
0.
0.
1
0
0
0
0
1
248
238
236
340
677
584
236
722
465
458
489
408
481
284
502
389
269
942
276
465
365
136
833
457
518
205
746
554
487
348
333
355
1.530
0
0
0
1
0
671
293
.386
.130
.193
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
1.
0.
1.
0.
0.
0.
0.
1.
0.
0.
0.
0
1
1
0
0
0
1
0
319
223
237
331
670
575
149
704
448
454
484
398
482
266
492
384
263
942
303
441
353
170
841
451
505
178
714
534
456
339
317
318
479
652
263
376
100
.184
%RSD
28.27
4.24
3.41
4.80
4.22
2.69
37.21
2.79
4.36
2.63
1.64
3.48
1.49
4.75
2.17
2.81
1.88
2.81
5.53
2.09
2.61
3.32
7.67
16.02
7.83
15.74
2.57
2.84
4.06
1.80
4.57
3.67
4.27
1.88
9.23
7.05
2.03
2.90
(#)  = Out  of Range
          S062499.M
       Fri Jul 30 14:47:41 1999
Page 2
                            D-6

-------
                        Response Factor Report  Semi2

 Method       : F:\ORIMUL~1\METHODS\S062499.M  (RTE Integrator)
 Title        : Orimulsion PAH Analysis by method 8270
 Last Update  : Wed Jul 28 08:42:17  1999
 Response via : Initial Calibration

 Calibration Files
2
4
78)
79)
80) i
81)
82)
83)
84)
85)
86) M
87)
88)
89) s
90)
91)
92)
93) M
94)
95) i
96)
97)
98) S
99)
100)
101)
102)
103)
104)
105) i
106) M
107)
108)
109)
110) M
111)
112)
113)
114)
=SC26249A.D 1
=SC46249A.D 5
Compound
Diallate
1,3, 5-Trinitrobenzene
DIO-Phenanthrene (QS#4
4-Bromophenyl phenyl
Phenacetin
Hexachlorobenzene
4-Aminobiphenyl
Dinoseb
Pentachlorophenol (CCC
Pentachloronitrobenze
Phenanthrene
dlO-Anthracene
Anthracene
Di-n-butyl phthalate
Isodrin
Fluoranthene (CCC)
3,3' -Dimethylbenzidin
D12-Chrysene (QS#5)
Pyrene
Chlorobenzilate
D14-Terphenyl (surr#6)
p-Dimethylaminoazoben
2-Acetylaminofluorene
Benzyl butyl phthalat
3,3' -Dichlorobenzidin
Benzo (a) anthracene
Chrysene
D12-Perylene (QS#6)
di-n-Octyl phthalate (
Benzo (b) f luoranthene
7, 12-Dimethylbenz (a) a
Benzo (k) f luoranthene
Benzo (a)pyrene (CCC)
3-Methylcholanthrene
Indenod, 2, 3-cd)pyren
Dibenz (a, h) anthracene
Benzo (ghi) perylene
=SC16249A.D
=SC56259A.D
2 1
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.
1,
0,
1
0
0
0
0
0
0
1
1
1
1
0
1
1
0
1
0
1
698
325
211
453
243
516
221
136
093
,140
,025
,172
.541
.148
.172
.245
.539
.405
.922
.289
.582
.815
.382
.336
.255
.862
.206
.520
.156
.058
.520
.007
.988
.048
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
1.
1.
0.
1.
0.
1.
0.
0.
0.
0.
0,
0,
1
1
1
1
0
1
1
0
1
0
1
763
306
226
472
255
432
197
137
096
234
911
262
578
150
209
324
,661
,420
.998
.322
.545
.876
.434
.434
.338
.943
.296
.568
.235
.105
.531
.000
.972
.052
3
3
0.674
=SC36249A.D
4 5 Avg
0.656
0.328 0.335
— IblLJ —
0.233 0.232
0.457
0.264
0.526
0.250
0.135
0.098
1.193
1.054
1.223
1.533
0.142
1.181
0.454
0.264
0.464
0.258
0.135
0.098
1.166
1.047
1.199
1.494
0.140
1.172
0.256 0.257
	 loi U 	
1.612 1.585
0.424
0.974
0.292
0.651
0.831
0.427
1.423
0.416
0.974
0.276
0.651
0.809
0.412
1.401
1.346 1.345
lol 1J
1.935 1.904
1.282
0.565
1.222
1.130
0.558
1.095
1.093
1.139
1.266
0.562
1.195
1.126
0.549
1.066
1.065
1.101
0.713
0.385
0.241
0.486
0.268
0.507
0.267
0.149
0.104
1.220
1.032
1.251
1.622
0.148
1.255
0.296
1.596
0.438
0.999
0.281
0.671
0.854
0.433
1.443
1.374
2.046
1.344
0.585
1.265
1.178
0.561
1.123
1.100
1.150
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.
1.
0.
1.
0.
0,
0,
0,
0,
0
1
1
1
1
0
1
1
0
1
1
1
701
336
228
464
259
489
239
138
098
191
014
221
553
146
198
,275
,598
.420
.973
.292
.620
.837
.417
.408
.332
.938
.279
.560
.215
.119
.544
.058
.043
.098
%RSD
5.86
8.78
5.01
3.13
3.80
8.11
12.08
4.46
4.09
3.26
5.77
3.03
3.12
2.98
2.95
12.16
2.77
2.90
3.19
6.16
8.65
3.31
5.24
3.07
3.36
3.52
3.93
4.27
3.41
3.91
3.26
5.11
5.74
4.33
f)  =  Out  of  Range
         S062499.M       Fri  Jul  30  14:47:48  1999                      Page  3
                           D-7

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131F
9905026
S995026A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:

905181131SBFO- Filter

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10-Anthracene

 Compound

n-Nitrosomethylethylamine
Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane

 E = exceeded calib   ND = not detected
                     Recovery                                 % Recovery
                       59     P  D5-Nitrobenzene(surr#3)            70     P
                       71     P  2-Fluorobiphenyl(surr#4)            72     P
                       87     P  D14-Terphenyl(surr#6)              93     P

                     Recovery                                 % Recovery
                       NS        13C6-2.5 Dichlorophenol            NS
                       NS        13C6-2,5-Phthalate anhydride        NS
                       NS

                       ug        Compound                       ug

                       ND        4-Methylphenol                    ND
                       ND        N-nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                ND
                       ND        Isophorone                        ND
                       ND        2,4-Dimethylphenol                ND
                        1      J Bis(2-chloroethoxy)methane         ND
                       ND        2,4-Dichlorophenol(CCC)           ND
                       ND        1,2,4-Trichlorobenzene              ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)                ND
                       ND        2,6-Dichlorophenol                ND
                       ND        Hexachloropropene                ND
                       ND        4-Chloroaniline                    ND
                       ND        Hexachlorobutadiene(CCC)          ND
                       ND        n-Nitrosodi-n-butylamine            ND
                       ND        4-Chloro-3-methyl-phenol(CCC)      ND
                   J = Peak below the calibration range

                          D-8
                 NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131F
9905026
S995026A
8270
HRGC/LRMS
Sample Description/Narrative:

905181131SBFO- Filter

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachloijophenol
  4-Nitrophenol(SPbC)
  Fluorene
  Diethyl phathalat^

  E = exceeded calib    ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                      ug       Compound                       MS
                     ND       4-Chlorophenyl phenyl ether       ND
                     ND       2-Methyl-4,6-dinitrophenol         ND
                     ND       5-Nitro-o-toluidine                ND
                     ND       Diphenylamine                   ND
                     ND       Diallate                         ND
                     ND        1,3,5-Trinitrobenzene             ND
                     ND       4-Bromophenyl phenyl ether       ND
                     ND       Phenacetin                       ND
                     ND       Hexachlorobenzene               ND
                     ND       4-Aminobiphenyl                 ND
                     ND       Dinoseb                        ND
                      ND        Pentachlorophenol(CCC)          ND
                      ND        Pentachloronitrobenzene          ND
                      ND        Phenanthrene                    ND
                      ND        Anthracene                      ND
                      ND        Di-n-butyl phthalate               7
                      ND        Isodrin                         ND
                      ND        Fluoranthene(CCC)               ND
                      ND        3,3'-Dimethylbenzidine            ND
                      ND        Pyrene                         ND
                      ND        Chlorobenzilate                  ND
                      ND        p-Dimethylaminoazobenzene      ND
                      ND        2-Acetylaminofluorene            ND
                      ND        Benzyl butyl phthalate            ND
                      ND        3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                      ND
                   J = Peak below the calibration range

                          D-9
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131F
9905026
S995026A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/18/99
6/1/99
6/26/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
Sample Description/Narrative:

905181131SBFO- Filter

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
                     ug        Compound

                     ND       Benzo(a)pyrene(CCC)
                      7      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected
                  J = Peak below the calibration range
                NS= not spiked
                                        D-10

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131X
9905027
S995027A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:
905181131WSBXO-
Pre Extraction Surrogates
2-Ruorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(suir#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10- Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1 ,3-Dichlorobenzene
 1 ,4-Dichlorobenzene(CCC)
 1 ,2-Dichlorobenzene:
 Benzyl Alcohol    i
 Bis(2-chloroisopropyl)ether
 2-Methylphenol    '
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane
                     Recovery
                       80     P
                       66     P
                       101     P

                    iRecovery
                       86
                       87
                       100

                       Mg

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        2      J
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        8      J
                       ND
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 N-nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 Bis(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
              % Recovery
                  89     P
                  92     P
                  128     P

              % Recovery
                  92
                  142
                  Mg

                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                   9
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
 E = exceeded calib   ND = not detected
                   J = Peak below the calibration range     NS= not spiked
                                             D-ll

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131X
9905027
S995027A
8270
HRGC/LRMS
Sample Description/Narrative:

905181131WSBXO-XAD

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachlorophenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalate

 E = exceeded calib    ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                      ug       Compound                       ug
                     ND       4-Chlorophenyl phenyl ether       ND
                     ND       2-Methyl-4,6-dinitrophenol        ND
                     ND       5-Nitro-o-toluidine               ND
                     ND       Diphenylamine                  ND
                     ND       Diallate                        ND
                     ND       1,3,5-Trinitrobenzene            ND
                     ND       4-Bromophenyl phenyl ether       ND
                     ND       Phenacetin                      ND
                     ND       Hexachlorobenzene              ND
                     ND       4-Aminobiphenyl                ND
                     ND       Dinoseb                       ND
                     ND       Pentachlorophenol(CCC)         ND
                     ND       Pentachloronitrobenzene          ND
                     ND       Phenanthrene                   ND
                      ND       Anthracene                     ND
                      ND       Di-n-butyl phthalate              15
                      ND       Isodrin                        ND
                      ND       Fluoranthene(CCC)              ND
                      ND       3,3'-Dimethylbenzidine           ND
                      ND       Pyrene                        ND
                      ND       Chlorobenzilate                 ND
                      ND       p-Dimethylaminoazobenzene       ND
                      ND       2-Acetylaminofluorene            ND
                      ND       Benzyl butyl phthalate            ND
                      ND       3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                       2      J
                  J = Peak below the calibration range
                NS= not spiked
                                         D-12

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131X
9905027
S995027A
8270
HRGC/LRMS
Sample Description/Narrative:

905181131WSBXO-XAD

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/18/99
6/1/99
6/26/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                      jig        Compound

                     ND       Benzo(a)pyrene(CCC)
                      3      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib    ND = not detected      J = Peak below the calibration range      NS= not spiked
                                       D-13

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131C
9905028
S995028A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
NA
06/26/99
Bill Preston
Dennis Tabor
       1      ml
       1
 Sample Description/Narrative:

 905181131SBIO Condensate-Not spiked with pre-extraction surrogates
 Pre Extraction Surrogates
 2-Fluorophenol(surr# 1)
 D5-Phenol(suir#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1,2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
  Aniline
  Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
  Benzyl Alcohol
  B is(2-chloroisopro iy l)ether
  2-Methylphenol   :
  n-Nitrosospyrrolidijne
  Acetophenone    j
  Hexachloroethane !
                     Recovery
                       NS
                       NS
                       NS

                     i Recovery
                       NS
                       NS
                       NS

                        "g

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
 D5-Nitrobenzene(surr#3)
 2-Fluorobiphenyl(surr#4)
 D14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 N-nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 Bis(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
  1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
  Hexachloropropene
  4-Chloroaniline
  Hexachlorobutadiene(CCC)
  n-Nitrosodi-n-butylamine
  4-Chloro-3-methyl-phenol(CCC)
                Recovery
                  NS
                  NS
                  NS

               > Recovery
                  NS
                  NS
                  fig

                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                   ND
   E = exceeded calib   ND = not detected      J = Peak below the calibration range      NS= not spiked
                                            D-14

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131C
9905028
S995028A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/18/99
NA
06/26/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
Sample Description/Narrative:

905181131SBIO Condensate-Not spiked with pre-extraction surrogates
 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 l.SDinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
                      fig        Compound                      ug
                      ND        4-Chlorophenyl phenyl ether       ND
                      ND        2-Methyl-4,6-dinitrophenol        ND
                      ND        5-Nitro-o-toluidine               ND
                      ND        Diphenylamine                  ND
                      ND        Diallate                         ND
                      ND        1,3,5-Trinitrobenzene             ND
                      ND        4-Bromophenyl phenyl ether       ND
                      ND        Phenacetin                      ND
                      ND        Hexachlorobenzene               ND
                      ND        4-Aminobiphenyl                ND
                      ND        Dinoseb                        ND
                      ND        Pentachlorophenol(CCC)          ND
                      ND        Pentachloronitrobenzene          ND
                      ND        Phenanthrene                    ND
                      ND        Anthracene                     ND
                      ND        Di-n-butyl phthalate              ND
                      ND        Isodrin                         ND
                      ND        Fluoranthene(CCC)               ND
                      ND        3,3'-Dimethylbenzidine           ND
                      ND        Pyrene                         ND
                      ND       Chlorobenzilate                  ND
                      ND       p-Dimethylaminoazobenzene      ND
                      ND       2-Acetylaminofluorene            ND
                      ND       Benzyl butyl phthalate             3
                      ND       3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                      ND
                   J = Peak below the calibration range
                NS= not spiked
                                       D-15

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905181131C
9905028
S995028A
8270
HRGC/LRMS
Sample Description/Narrative:
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
905181131SBIO Condensate-Not spiked with pre-extraction surrogates

Compound                           ug       Compound
5/18/99
NA
6/26/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
B enzo(k)fluoranthene
                     ND       Benzo(a)pyrene(CCC)
                      2      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected     J = Peak below the calibration range     NS= not spiked
                                          D-16

-------
 APPCD Organic Support Laboratory
 Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016F
9905032
S995032A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/19/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
      1       ml
      1
Sample Description/Narrative:

905191016SBFO Filter

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
13C6-1.2 Dichlorobenzene
13C6-Napthalene
D10-Anthracene

Compound

n-Nitrosomethylethylamine
Methyl Methanesulfonate
n-Nitrosodiethylamine
Bis (2-chloroethyl) ether
Ethyl methanesulfonate
Aniline
Phenol(CCC)
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene(CCC)
1,2-Dichlorobenzene
Benzyl Alcohol
Bis(2-chloroisopropyl)ether
2-Methylphenol
n-Nitrosospyrrolidine
Acetophenone
Hexachloroethane

E = exceeded calib   ND = not detected
                     Recovery                                 % Recovery
                      51      P  D5-Nitrobenzene(surr#3)             58     P
                      61      P  2-Fluorobiphenyl(surr#4)             62     P
                      78      P  D14-Terphenyl(surr#6)              105     P

                     Recovery                                 % Recovery
                      NS         13C6-2.5 Dichlorophenol             NS
                      NS         13C6-2,5-Phthalate anhydride         NS
                      NS

                      ug         Compound                        ug

                      ND         4-Methylphenol                   ND
                      ND         N-nitrosodi-n-propylamine           ND
                      ND         Nitrobenzene                      ND
                      ND         1-Nitrosopiperidine                ND
                      ND         Isophorone                       ND
                      ND         2,4-Dimethylphenol                ND
                      ND         Bis(2-chloroethoxy)methane         ND
                      ND         2,4-Dichlorophenol(CCC)           ND
                      ND         1,2,4-Trichlorobenzene             ND
                      ND         Naphthalene                      ND
                      ND         2-Nitrophenol(CCC)                ND
                      ND         2,6-Dichlorophenol                ND
                      ND         Hexachloropropene                ND
                      ND         4-Chloroaniline                    ND
                      ND         Hexachlorobutadiene(CCC)          ND
                      ND         n-Nitrosodi-n-butylamine            ND
                      ND         4-Chloro-3-methyl-phenol(CCC)      ND
                   = Peak below the calibration range
                                                                 NS= not spiked
                                         D-17

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016F
9905032
S995032A
8270
HRGC/LRMS
Date Sampled:   05/19/99
Date Extracted:  06/01/99
 Sample Description/Narrative:

 905191016SBFO Filter

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzeije
  2,4-Dinitrotoluenej
  2,3,4,6-Tetrachlorjjphenol
  4-Nitrophenol(SP
-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016F
9905032
S995032A
8270
HRGC/LRMS
                          Date Sampled:
                          Date Extracted:
                          Date Acquired:
                          Analyst:
                          QC reviewer:
                          Extract Volume
                          Dilution Factor
                           5/19/99
                           6/1/99
                           6/26/99
                           Bill Preston
                           Dennis Tabor
                                                                       1 ml
                                                                       1
 Sample Description/Narrative:

 905191016SBFO Filter

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 B enzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
                     ug        Compound

                     ND       Benzo(a)pyrene(CCC)
                      2      J  3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                                                         ND
                                                         ND
                                                         ND
                                                         ND
                                                         ND
 E = exceeded calib
 ND =
= not detected
J = Peak below the calibration range
NS= not spiked
                                     D-19

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016C
9905034
S995034A
8270
HRGC/LRMS
Sample Description/Narrative:

905191016SBIO Condensate

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
13C6-1.2 Dichlorobenzene
13C6-Napthalene
D10-Anthracene
                   % Recovery
                       39     P
                       34     P
                       87     P

                   % Recovery
                       NS
                       NS
                       NS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/19/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
      1      ml
      1
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
                Recovery
                  64     P
                  67     P
                  113     P

                Recovery
                  NS
                  NS
 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane

 E = exceeded calib   ND = not detected
                       ug        Compound                        ug

                       ND        4-Methylphenol                    ND
                       ND        N-nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                 ND
                       ND        Isophorone                        ND
                       ND        2,4-Dimethylphenol                ND
                       ND        Bis(2-chloroethoxy)methane         ND
                       ND        2,4-Dichlorophenol(CCC)           ND
                       ND        1,2,4-Trichlorobenzene             ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)                ND
                       ND        2,6-Dichlorophenol                 ND
                       ND        Hexachloropropene                 ND
                       ND        4-Chloroaniline                    ND
                       ND        Hexachlorobutadiene(CCC)          ND
                       ND        n-Nitrosodi-n-butylamine            ND
                       ND        4-Chloro-3-methyl-phenol(CCC)      ND
                   J = Peak below the calibration range
                                                                  NS= not spiked
                                          D-20

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016C
9905034
S995034A
8270
HRGC/LRMS
Sample Description/Narrative:

905191016SBIO Condensate

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluenq
 2,3,4,6-Tetrachlorophenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalate

  E = exceeded calib    ND = not detected
                      MS
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                     ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/19/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
Compound                       ug
4-Chlorophenyl phenyl ether       ND
2-Methyl-4,6-dinitrophenol         ND
5-Nitro-o-toluidine               ND
Diphenylamine                  ND
Diallate                         ND
 1,3,5-Trinitrobenzene             ND
4-Bromophenyl phenyl ether       ND
Phenacetin                       ND
Hexachlorobenzene               ND
4-Aminobiphenyl                 ND
Dinoseb                        ND
Pentachlorophenol(CCC)          ND
 Pentachloronitrobenzene          ND
 Phenanthrene                    ND
 Anthracene                      ND
 Di-n-butyl phthalate              ND
 Isodrin                         ND
 Fluoranthene(CCC)               ND
 3,3'-Dimethylbenzidine            ND
 Pyrene                         ND
 Chlorobenzilate                  ND
 p-Dimethylaminoazobenzene      ND
 2-Acetylaminofluorene            ND
 Benzyl butyl phthalate            ND
 3,3'-Dichlorobenzidine            ND
 Benzo(a)anthracene              ND
                  J = Peak below the calibration range
                NS= not spiked
                                        D-21

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016C
9905034
S995034A
8270
HkGC/LRMS
Sample Description/Narrative:
905191016SBIO Condensate
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/19/99
6/1/99
6/26/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluorantherie
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
                      fig       Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   N£> = not detected
                  J = Peak below the calibration range
                NS= not spiked
                                      D-22

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
9Q5191016X
9905033
S995033A
8270
HRGC/LRMS
 Date Sampled:
 Date Extracted:
 Date Acquired:
 Analyst:
 QC reviewer:
 Extract Volume
 Dilution Factor
               05/19/99
               06/01/99
               06/26/99
               Bill Preston
               Dennis Tabor
                     1      ml
                     1
Sample Description/Narrative:

905191016SBXO XAD

Pre Extraction Surrogates
2-Fluorophenol(surr# 1)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfortate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzen*(CCC)
 1,2-Dichlorobenzeni:
 Benzyl Alcohol
 Bis(2-chloroisoprop yl)ether
 2-Methylphenol
 n-Nitrosospyrrolidir e
 Acetophenone
 Hexachloroethane
                     Recovery
                       60     P
                       61     P
                       89     P

                     i Recovery
                       66
                       67
                       86

                       ug

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        4      J
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        6
                       ND
J
  D5-Nitrobenzene(surr#3)
  2-Fluorobiphenyl(surr#4)
  D14-Terphenyl(surr#6)
  13C6-2.5 Dichlorophenol
  13C6-2,5-Phthalate anhydride
Compound

4-Methylphenol
N-nitrosodi-n-propylamine
Nitrobenzene
1 -Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol(CCC)
1,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
4-Chloro-3-methyl-phenol(CCC!)
                               Recovery
                                 68     P
                                 72     P
                                 119     P

                              ' Recovery
                                 70
                                 70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
 E = exceeded calib   ND = not detected
                    J = Peak below the calibration range
                  NS= not spiked
                                           D-23

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016X
9905033
S995033A
8270
HRGC/LRMS
Sample Description/Narrative:

905191016SBXOXAD

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopeilitadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachlorophenol
 4-Nitrophenol(SPGC)
 Fluorene
 Diethyl phathalate

 E = exceeded calib    ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/19/99
06/01/99
06/26/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                      fig       Compound                      Mg
                      ND       4-Chlorophenyl phenyl ether       ND
                      ND       2-Methyl-4,6-dinitrophenol         ND
                      ND       5-Nitro-o-toluidine                ND
                      ND       Diphenylamine                   ND
                      ND       Diallate                         ND
                      ND        1,3,5-Trinitrobenzene             ND
                      ND       4-Bromophenyl phenyl ether       ND
                      ND       Phenacetin                      ND
                      ND       Hexachlorobenzene               ND
                      ND       4-Aminobiphenyl                 ND
                      ND       Dinoseb                        ND
                      ND       Pentachlorophenol(CCC)          ND
                      ND        Pentachloronitrobenzene          ND
                      ND        Phenanthrene                    ND
                      ND        Anthracene                      ND
                      ND        Di-n-butyl phthalate               13
                      ND        Isodrin                         ND
                      ND        Fluoranthene(CCC)               ND
                      ND        3,3'-Dimethylbenzidine            ND
                      ND        Pyrene                         ND
                      ND        Chlorobenzilate                  ND
                      ND        p-Dimethylaminoazobenzene      ND
                      ND        2-Acetylaminofluorene            ND
                      ND        Benzyl butyl phthalate            ND
                      ND        3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                      ND
                   J = Peak below the calibration range
                NS= not spiked
                                         D-24

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135F
9905043
S995043A
8270
  K3C/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/21/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/ Narrative

905211135SBFO Filter

Pre Extraction Surrogates
2-Fluorophenol(surr$ 1)
D5-Phenol(surr#2)
2,4,6-Tribromophenoll(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10-Anthracene

Compound

n-Nitrosomethylethylamine
Methyl Methanesulfonate
n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene (CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 B is(2-chloroisopropy l)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane
                     Recovery                                 % Recovery
                       44     P  D5-Nitrobenzene(surr#3)            52     P
                       53     P  2-Fluorobiphenyl(surr#4)            57     P
                       80     P  D14-Terphenyl(surr#6)              101    P

                    i Recovery                                 % Recovery
                       NS        13C6-2.5 dichlorophenol            NS
                       NS        13C6-2,5-Phthalate anhydride        NS
                       NS

                       fig        Compound                       ug

                       ND        4-Methylphenol                    ND
                       ND        N-nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                ND
                       ND        Isophorone                        ND
                       ND        2,4-Dimethylphenol                ND
                       ND        Bis(2-chloroethoxy)methane         ND
                       ND        2,4-Dichlorophenol(CCC)           ND
                       ND        1,2,4-Trichlorobenzene             ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)                ND
                       ND        2,6-Dichlorophenol                ND
                       ND        Hexachloropropene                ND
                       ND        4-Chloroaniline                    ND
                       ND        Hexachlorobutadiene(CCC)          ND
                       ND        n-Nitrosodi-n-butylamine           ND
                       ND        4-Chloro-3-methyl-phenol(CCC)      ND
 E = exceeded calib   ND = not detected
                   J = Peak below the calibration range
                 NS= not spiked
                                          D-25

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135F
9905043
S995043A
8270
HRGC/LRMS
Sample Description/Narrative:

905211135SBFO Filter

Compound
2-Methylnaphthaleme
Isosafrole
1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethylphathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachlor aphenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalate
                                     Mg
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                      ND
                                      ND
                                      ND
                                      ND
                                      ND
                                      ND
                                      ND
                                      ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
                                                             05/21/99
                                                             06/04/99
                                                             06/27/99
                                                             Bill Preston
                                                             Dennis Tabor
                                                                         1 ml
                                                                         1
                               Compound
                               4-Chlorophenyl phenyl ether
                               2-Methyl-4,6-dinitrophenol
                               5-Nitro-o-toluidine
                               Diphenylamine
                               Diallate
                                1,3,5-Trinitrobenzene
                               4-Bromophenyl phenyl ether
                               Phenacetin
                                Hexachlorobenzene
                                4-Aminobiphenyl
                                Dinoseb
                                Pentachlorophenol(CCC)
                                Pentachloronitrobenzene
                                Phenanthrene
                                Anthracene
                                Di-n-butyl phthalate
                                Isodrin
                                Fluoranthene(CCC)
                                3,3'-Dimethylbenzidine
                                Pyrene
                                Chlorobenzilate
                                p-Dimethylaminoazobenzene
                                2-Acetylaminofluorene
                                Benzyl butyl phthalate
                                3,3'-Dichlorobenzidine
                                Benzo(a)anthracene
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                 6
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
  E = exceeded calib    ND = not detected      J = Peak • below the calibration range     NS= not spiked
                                          D-26

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135F
9905043
S995043A
8270
FJRGC/LRMS
Sample Description/Narrative:
905211135SBFO Filter
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/21/99
6/4/99
6/27/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)an.thracene
 Benzo(k)fluoranthene
                      fig       Compound

                     ND       Benzo(a)pyrene(CCC)
                      9      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected     J = Peak below the calibration range      NS= not spiked
                                         D-27

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135X
9905044
S995044A
8270
HRGC/LRMS
 Date Sampled:
 Date Extracted:
 Date Acquired:
 Analyst:
 QC reviewer:
 Extract Volume
 Dilution Factor
               05/21/99
               06/04/99
               06/27/99
               Bill Preston
               Dennis Tabor
                     1      ml
                     1
Sample Description/Narrative:

905211135BXO Filter

Pre Extraction Surrogates
2-Fluorophenol(surr# I)
D5-Phenol(surr#2)
2,4,6-Tribromophenoi(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
 Benzyl Alcohol
  Bis(2-chloroisoprop; rl)ether
  2-Methylphenol
  n-Nitrosospyrrolidin s
  Acetophenone
  Hexachloroethane

  E = exceeded calib   ND = not detected
                     Recovery
                       56     P  D5-Nitrobenzene(surr#3)
                       57     P  2-Fluorobiphenyl(surr#4)
                       84     P  D14-Terphenyl(surr#6)
                      Recovery
                        66
                        67
                        82

                        Mg

                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         5
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         6
                        ND
J
J
  13C6-2.5 dichlorophenol
  13C6-2,5-Phthalate anhydride
Compound

4-Methylphenol
N-nitrosodi-n-propylamine
Nitrobenzene
1 -Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol(CCC)
1,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
4-Chloro-3-methyl-phenol(CCC
                               Recovery
                                 63     P
                                 67     P
                                 115    P

                              iRecovery
                                 68
                                 57
"g

ND
ND
ND
ND
ND
ND
ND
ND
ND
 2
ND
ND
ND
ND
ND
ND
ND
                    J = Peak below the calibration range     NS= not spiked

                               D-28

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135X
9905044
S995044A
8270
HRGC/LRMS
Sample Description/Narrative:

905211135BXO Filter

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethylphathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/21/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                      fig       Compound
                      ND       4-Chlorophenyl phenyl ether
                      ND       2-Methyl-4,6-dinitrophenol
                      ND       5-Nitro-o-toluidine
                      ND       Diphenylamine
                      ND       Diallate
                      ND       1,3,5-Trinitrobenzene
                      ND       4-Bromophenyl phenyl ether
                      ND       Phenacetin
                      ND       Hexachlorobenzene
                      ND       4-Aminobiphenyl
                      ND       Dinoseb
                      ND       Pentachlorophenol(CCC)
                      ND       Pentachloronitrobenzene
                      ND       Phenanthrene
                      ND       Anthracene
                      ND       Di-n-butyl phthalate
                      ND        Isodrin
                      ND        Fluoranthene(CCC)
                      ND        3,3'-Dimethylbenzidine
                      ND        Pyrene
                      ND        Chlorobenzilate
                      ND        p-Dimethylaminoazobenzene
                      ND        2-Acetylaminofluorene
                      ND       Benzyl butyl phthalate
                      ND       3,3'-Dichlorobenzidine
                      ND       Benzo(a)anthracene
                      ND

                   J = Peak below the calibration range     NS= not spiked
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                 4
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                        D-29

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135X
9905044
S995044A
8270
HRGC/LRMS
Sample Description ^Narrative
905211135BXO Filter
 Compound

 Chrysene
 di-n-Octyl phthalate^CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/21/99
6/4/99
6/27/99
Bill Preston
Dennis Tabor
                                                                       1ml
                                                                       1
                     jig        Compound

                     ND        Benzo(a)pyrene(CCC)
                     ND        3-Methylcholanthrene
                     ND        Indeno( 1,2,3-cd)pyrene
                     ND        Dibenz(a,h)anthracene
                     ND        Benzo(ghi)perylene
                               "g

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   Nip = not detected
                  J = Peak below the calibration range
                NS= not spiked
                                        D-30

-------
APPCD Organic Support Laboratory
Semi-Volatile Ouganics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135C
9905045
S995045A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/21/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:

905211135SBIO Condensate

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1,2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidin4
 Acetophenone
 Hexachloroethane
                     Recovery                                 % Recovery
                       34     P  D5-Nitrobenzene(surr#3)             59     P
                       25     P  2-Fluorobiphenyl(surr#4)             55     P
                       79     P  D14-Terphenyl(surr#6)              112    P

                     • Recovery                                 % Recovery
                       NS        13C6-2.5 dichlorophenol             NS
                       NS        13C6-2,5-Phthalate anhydride         NS
                       NS

                       ug        Compound                       ug

                       ND        4-Methylphenol                    ND
                       ND        N-nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                 ND
                       ND        Isophorone                        ND
                       ND        2,4-Dimethylphenol                 ND
                       ND        Bis(2-chloroethoxy)methane          ND
                       ND        2,4-Dichlorophenol(CCC)            ND
                       ND        1,2,4-Trichlorobenzene              ND
                       ND        Naphthalene                       ND
                       ND        2-Nitrophenol(CCC)                ND
                       ND        2,6-Dichlorophenol                 ND
                       ND        Hexachloropropene                 ND
                       ND        4-Chloroaniline                    ND
                       ND        Hexachlorobutadiene(CCC)          ND
                       ND        n-Nitrosodi-n-butylamine            ND
                       ND        4-Chloro-3-methyl-phenol(CCC)      ND
  E = exceeded calib   ND = not detected
                    J = Peak below the calibration range
                 NS= not spiked
                                          D-31

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135C
9905045
S995045A
8270
HjlGC/LRMS
Sample Descriptioi^/Narrative:

905211135SBIO Condensate

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethylphathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(i 5PCC)
 Dibenzofuran
  Pentachlorobenzen 5
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlordphenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
         Date Sampled:
         Date Extracted:
         Date Acquired:
         Analyst:
         QC reviewer:
         Extract Volume
         Dilution Factor
05/21/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
fig        Compound
ND       4-Chlorophenyl phenyl ether
ND       2-Methyl-4,6-dinitrophenol
ND       5-Nitro-o-toluidine
ND       Diphenylamine
ND       Diallate
ND       1,3,5-Trinitrobenzene
ND       4-Bromophenyl phenyl ether
ND       Phenacetin
ND       Hexachlorobenzene
ND       4-Aminobiphenyl
ND       Dinoseb
ND       Pentachlorophenol(CCC)
ND       Pentachloronitrobenzene
ND       Phenanthrene
ND       Anthracene
ND       Di-n-butyl phthalate
ND       Isodrin
ND       Fluoranthene(CCC)
ND       3,3'-Dimethylbenzidine
ND       Pyrene
ND       Chlorobenzilate
ND       p-Dimethylaminoazobenzene
ND       2-Acetylaminofluorene
ND       Benzyl butyl phthalate
ND       3,3'-Dichlorobenzidine
ND       Benzo(a)anthracene
ND
                                                               fig
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                   J = Peak below the calibration range
                          NS= not spiked
                                        D-32

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905211135C
9905045
S995045A
8270
HRGC/LRMS
 Sample Description/Narrative:

 905211135SBIO Condensate

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/21/99
6/4/99
6/27/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                      ug        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib
  S(D = not detected      J = Peak below the calibration range     NS= not spikec
                                      D-33

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202F
9905046
S995046A
8270
I^RGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:

905241202SBFOBLO1 Filter

Pre Extraction Surrogates
2-Fluorophenol(surr# 1)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidijie
 Acetophenone
 Hexachloroethane
                     Recovery
                       51     P
                       60     P
                       78     P

                    t Recovery
                       NS
                       NS
                       NS

                       "g

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        1      J
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
 13C6-2.5 dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 N-nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 Bis(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
              % Recovery
                  59     P
                  62     P
                  106    P

              % Recovery
                  NS
                  NS
                  ug

                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
  E = exceeded calib   ND = not detected
                    J = Peak below the calibration range

                          D-34
                 NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
                Orimulsion
                905241202F
                9905046
                S995046A
                8270
                HRGC/LRMS
Sample Descriptioi i/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
 905241202SBFOBL(|)1 Filter

 Compound
 2-Methylnaphthalei^e
 Isosafrole
 1,2,4,5-Tetrachloro jenzene
 Hexachlorocyclope itadiene(SPCC)
 2,4,6-Trichlorophemol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthaleme
 l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethylphathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
  2,4-Dinitrophenol(|SPCC)
  Dibenzofuran
  Pentachlorobenzerje
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/04/99
06/27/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                                     fig        Compound                       fig
                                     ND       4-Chlorophenyl phenyl ether       ND
                                     ND       2-Methyl-4,6-dinitrophenol        ND
                                     ND       5-Nitro-o-toluidine               ND
                                     ND       Diphenylamine                  ND
                                     ND       Diallate                        ND
                                     ND       1,3,5-Trinitrobenzene            ND
                                     ND       4-Bromophenyl phenyl ether       ND
                                     ND       Phenacetin                      ND
                                     ND       Hexachlorobenzene              ND
                                     ND       4-Aminobiphenyl                ND
                                     ND       Dinoseb                        ND
                                     ND       Pentachlorophenol(CCC)          ND
                                     ND       Pentachloronitrobenzene           ND
                                     ND       Phenanthrene                    ND
                                     ND       Anthracene                      ND
                                     ND       Di-n-butyl phthalate               8
                                     ND       Isodrin                         ND
                                     ND       Fluoranthene(CCC)               ND
                                     ND       3,3'-Dimethylbenzidine            ND
                                     ND       Pyrene                         ND
                                     ND       Chlorobenzilate                  ND
                                     ND       p-Dimethylaminoazobenzene      ND
                                     ND       2-Acetylaminofluorene            ND
                                     ND       Benzyl butyl phthalate             ND
                                     ND        3,3'-Dichlorobenzidine            ND
                                     ND        Benzo(a)anthracene              ND
                                       5      J
                                  J = Peak below the calibration range
                NS= not spiked
                                        D-35

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202F
9905046
S995046A
8270
HRGC/LRMS
Sample Description/Narrative:

905241202SBFOBLO1 Filter

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/24/99
6/4/99
6/27/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     ug       Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected
                  J = Peak below the calibration range
               NS= not spiked
                                      D-36

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202X
9905047
S995047A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
      1       ml
      1
Sample Description/Narrative:

905241202SBW2BLO1-XAD

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
13C6-1.2 Dichlorobenzene
13C6-Napthalene
D10-Anthracene

Compound
n-Nitrosomethylethylamine
Methyl Methanesulfonate
n-Nitrosodiethylamine
bis (2-chloroethyl) ether
Ethyl methanesulfonate
Ethyl methanesulfonate
Aniline
Phenol(CCC)
2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene (CCC)
 1,2-Dichlorobenzene
Benzyl Alcohol
Bis(2-chloroisopropj l)ether
2-Methylphenol
n-Nitrosospyrrolidin
Acetophenone
Hexachloroethane
Recovery
54 P
59 P
78 P
Recovery
64
66
72
ug
ND
ND
ND
ND
ND
ND
ND
3 J
ND
ND
ND
ND
ND
ND
ND
ND
5 J
ND

D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D14-Terphenyl(surr#6)

13C6-2,5 dichlorophenol
13C6-2,5-Phthalate anhydride

Compound

4-methylphenol
N-nitrosodi-n-propylamine
Nitrobenzene
1 -Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol(CCC)
1 ,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
% Recovery
63
64
98
% Recovery
71
116

ug

ND
ND
ND
ND
ND
ND
ND
ND
ND
1
ND
ND
ND
ND
ND
ND

P
P
P















J






4-Chloro-3-methyl-phenol(CCC) ND
 E = exceeded calib   ND = not detected
                   J = Peak below the calibration range      NS= not spiked

                      D-37

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
               Orimulsion
               905241202X
               9905047
               S995047A
               8270
               HRGC/LRMS
Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
905241202SBW2BLO1-XAD

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophei iol(CCC)
2,4,5-Trichlorophejiol
 2-Chloronaphthalene
 l.SDinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
  Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(|SPCC)
  Dibenzofuran
  Pentachlorobenzei ie
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlon )phenol
  4-Nitrophenol(SP<:C)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                                     ug        Compound
                                     ND        4-Chlorophenyl phenyl ether
                                     ND        2-Methyl-4,6-dinitrophenol
                                     ND        5-Nitro-o-toluidine
                                     ND        Diphenylamine
                                     ND        Diallate
                                     ND        1,3,5-Trinitrobenzene
                                     ND        4-Bromophenyl phenyl ether
                                     ND        Phenacetin
                                     ND        Hexachlorobenzene
                                     ND        4-Aminobiphenyl
                                     ND        Dinoseb
                                     ND        Pentachlorophenol(CCC)
                                     ND        Pentachloronitrobenzene
                                     ND        Phenanthrene
                                     ND        Anthracene
                                     ND       Di-n-butyl phthalate
                                     ND       Isodrin
                                     ND       Fluoranthene(CCC)
                                     ND       3,3'-Dimethylbenzidine
                                     ND       Pyrene
                                     ND       Chlorobenzilate
                                     ND       p-Dimethylaminoazobenzene
                                     ND       2-Acetylaminofluorene
                                     ND       Benzyl butyl phthalate
                                     ND       3,3'-Dichlorobenzidine
                                     ND       Benzo(a)anthracene
                                     ND
                                ug
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                 9
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                  J = Peak below the calibration range
                NS= not spiked
                                        D-38

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202X
9905047
S995047A
8270
HRGC/LRMS
 Sample Description/Narrative:

 905241202SBW2BLO1-XAD

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     jig        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               "g

                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib    ND = not detected
                  J = Peak below the calibration range
                                                             NS= not spiked
                                       D-39

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202C
9905048
S995048A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/24/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
      1       ml
      1
 Sample Description/Narrative:

 905241202SBIOBLO1 Condensates

 Pre Extraction Surrogates
 2-Fluorophenol(surr# 1)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound
 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane

 E = exceeded calib   ND = not detected
Recovery
36 P
31 P
78 P
Recovery
NS
NS
NS
MS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
<
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
<
13C6-2.5 dichlorophenol
13C6-2,5-Phthalate anhydride

Compound

4-methylphenol
N-nitrosodi-n-propylamine
Nitrobenzene
1-Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
B is(2-chloroethoxy )methane
2,4-Dichlorophenol(CCC)
1 ,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
4-Chloro-3-methyl-phenol(CCC)
Jo Recovery
56 P
55 P
118 P
% Recovery
NS
NS

ug

ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                   J = Peak below the calibration range      NS= not spiked
                                         D-40

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
                Orimulsion
                905241202C
                9905048
                S995048A
                8270
                HRGC/LRMS
 Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
 905241202SBIOBLO1 Condensates

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine  I
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenoi(SPCC)
  Dibenzofuran    \
  Pentachlorobenzejne
  2,4-Dinitrotoluen i
  2,3,4,6-Tetrachlo
                 •ophenol
  4-Nitrophenol(SPJCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib    ND = not detected
         Date Sampled:
         Date Extracted:
         Date Acquired:
         Analyst:
         QC reviewer:
         Extract Volume
         Dilution Factor
05/24/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
jig        Compound
ND       4-Chlorophenyl phenyl ether
ND       2-Methyl-4,6-dinitrophenol
ND       5-Nitro-o-toluidine
ND       Diphenylamine
ND       Diallate
ND       1,3,5-Trinitrobenzene
ND       4-Bromophenyl phenyl ether
ND       Phenacetin
ND       Hexachlorobenzene
ND       4-Aminobiphenyl
ND       Dinoseb
ND       Pentachlorophenol(CCC)
ND       Pentachloronitrobenzene
ND       Phenanthrene
ND       Anthracene
ND       Di-n-butyl phthalate
ND       Isodrin
ND       Fluoranthene(CCC)
ND       3,3'-Dimethylbenzidine
ND       Pyrene
ND       Chlorobenzilate
 ND       p-Dimethylaminoazobenzene
 ND        2-Acetylaminofluorene
 ND        Benzyl butyl phthalate
 ND        3,3'-Dichlorobenzidine
 ND        Benzo(a)anthracene
 ND
                 Mg
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                                   J = Peak below the calibration range
                          NS= not spiked
                                        D-41

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905241202C
9905048
S995048A
8270
HRGC/LRMS
 Sample Description/Narrative:

 905241202SBIOBLO1 Condensates

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
                         Date Sampled:
                         Date Extracted:
                         Date Acquired:
                         Analyst:
                         QC reviewer:
                         Extract Volume
                         Dilution Factor
                          05/24/99
                          06/07/99
                          06/28/99
                          Bill Preston
                          Dennis Tabor
                                                                       1 ml
                                                                       1
                     jig        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                                                        Mg

                                                        ND
                                                        ND
                                                        ND
                                                        ND
                                                        ND
  E = exceeded calib
 jo,.
not detected
J = Peak below the calibration range
                                                             NS= not spiked1
                                      D-42

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905251144F
9905058
S9950£8A
8270
HRGC/LRMS
Sample Description/Narrative:

905251144SBFOBLO1 Filter

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound
 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane

 E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
                     Recovery
                       50     P
                       62     P
                       75     P

                    > Recovery
                       NS
                       NS
                       NS

                       "g
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
05/25/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
      1      ml
      1
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
 13C6-2.5 dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-methylphenol
 N-nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 Bis(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
                Recovery
                  59     P
                  61     P
                  106    P

               , Recovery
                  NS
                  NS
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                    J = Peak below the calibration range      NS= not spiked
                                          D-43

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
                Orimulsion
                905251144F
                9905058
                S&95058A
                8270
                HRGC/LRMS
 Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
 905251144SBFOBLO1 Filter

 Compound
 2-Methylnaphthalejne
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluenje
  2,3,4,6-Tetrachlojrophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib    ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/25/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                                     ug        Compound
                                     ND       4-Chlorophenyl phenyl ether
                                     ND       2-Methyl-4,6-dinitrophenol
                                     ND       5-Nitro-o-toluidine
                                     ND       Diphenylamine
                                     ND       Diallate
                                     ND       1,3,5-Trinitrobenzene
                                     ND       4-Bromophenyl phenyl ether
                                     ND       Phenacetin
                                     ND       Hexachlorobenzene
                                     ND       4-Aminobiphenyl
                                     ND       Dinoseb
                                     ND       Pentachlorophenol(CCC)
                                     ND       Pentachloronitrobenzene
                                     ND       Phenanthrene
                                     ND       Anthracene
                                     ND       Di-n-butyl phthalate
                                     ND        Isodrin
                                     ND        Fluoranthene(CCC)
                                      ND        3,3'-Dimethylbenzidine
                                      ND        Pyrene
                                      ND        Chlorobenzilate
                                      ND        p-Dimethylaminoazobenzene
                                      ND        2-Acetylaminofluorene
                                      ND        Benzyl butyl phthalate
                                      ND       3,3'-Dichlorobenzidine
                                      ND       Benzo(a)anthracene
                                       11
                                Mg
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                 11
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                   J = Peak below the calibration range
                 NS= not spiked
                                      D-44

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
               Orinfiulsion
               905:
               990!
               S99
    ;51144F
    1058
    >058A
8270
HRCBC/LRMS
Sample Description/Narrative:

905251144SBFOBLO1 Filter

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/25/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                                     fig       Compound

                                     ND       Benzo(a)pyrene(CCC)
                                     3      J 3-Methylcholanthrene
                                     ND       Indeno(l,2,3-cd)pyrene
                                     ND       Dibenz(a,h)anthracene
                                     ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND fc not detected
                                 J = Peak below the calibration range
                NS= not spiked
                                     D-45

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905251144X
9905059
S995059A
82170
HRGC/LRMS
 Sample Description/narrative:

 905251144SBXOBL( ll-XAD

 Pre Extraction Surrogates
 2-Fluorophenol(surr#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound
 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
  Ethyl methanesulfonate
  Aniline
  Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene (CCC)
  1,2-Dichlorobenzen<
  Benzyl Alcohol
  Bis(2-chloroisoprop Aether
  2-Methylphenol
  n-Nitrosospyrrolidine
  Acetophenone
  Hexachloroethane

  E = exceeded  calib    ND = not detected
 Date Sampled:
 Date Extracted:
 Date Acquired:
 Analyst:
 QC reviewer:
 Extract Volume
 Dilution Factor
               05/25/99
               06/04/99
               06/28/99
               Bill Preston
               Dennis Tabor
                     1       ml
                     1
                      Recovery
                        55     P  D5-Nitrobenzene(surr#3)
                        60     P  2-Fluorobiphenyl(surr#4)
                        90     P  D14-Terphenyl(surr#6)
                      Recovery
                        61
                        64
                        86

                        Mg
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         3
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                          5
                        ND
J
  13C6-2.5 Dichlorophenol
  13C6-2,5-Phthalate anhydride
Compound

4-Methylphenol
N-nitrosodi-n-propylamine
Nitrobenzene
1 -Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol(CCC)
1,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
4-Chloro-3-methyl-phenol(CCC)
                               Recovery
                                 61     P
                                 65     P
                                 114    P

                               Recovery
                                 64
                                 97
"g

ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
                     J = Peak below the calibration range

                             D-46
                   NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
               Orimulsion
               905251144X
               91)05059
               SJ95059A
Date Sampled:   05/25/99
Date Extracted:  06/04/99
               8270
               HRGC/LRMS
Sample Description/Narrative:

905251144SBXOBL01-XAD

Compound
2-Methylnaphthalene
Isosafrole
1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
2-Nitroaniline
3-Nitroaniline
Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachloijophenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalati

 E = exceeded calib    ND = not detected
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                                     fig        Compound
                                     ND        4-Chlorophenyl phenyl ether
                                     ND        2-Methyl-4,6-dinitrophenol
                                     ND        5-Nitro-o-toluidine
                                     ND        Diphenylamine
                                     ND        Diallate
                                     ND        1,3,5-Trinitrobenzene
                                     ND        4-Bromophenyl phenyl ether
                                     ND        Phenacetin
                                     ND       Hexachlorobenzene
                                     ND       4-Aminobiphenyl
                                     ND       Dinoseb
                                     ND       Pentachlorophenol(CCC)
                                     ND       Pentachloronitrobenzene
                                     ND       Phenanthrene
                                     ND       Anthracene
                                     ND       Di-n-butyl phthalate
                                     ND       Isodrin
                                     ND       Fluoranthene(CCC)
                                     ND       3,3'-Dimethylbenzidine
                                     ND       Pyrene
                                     ND       Chlorobenzilate
                                     ND       p-Dimethylaminoazobenzene
                                     ND       2-Acetylaminofluorene
                                      ND       Benzyl butyl phthalate
                                      ND        3,3'-Dichlorobenzidine
                                      ND        Benzo(a)anthracene
                                      ND

                                  J = Peak below the calibration range      NS= not spiked
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                               ND
                                 3
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                ND
                                         D-47

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905251144X
9905059
S995059A
8270
HRGC/LRMS
Sample Description/Narrative:

905251144SBXOBL01-XAD

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/25/99
06/04/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     fig       Compound

                     ND       Benzo(a)pyrene(CCC)
                      1      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected
                 J = Peak below the calibration range
               NS= not spiked
                                       D-48

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
90251144C
9905060
5995060A
iJ270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/25/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
      1       ml
      1
Sample Description/Narrative:

90251144SBIOBL01 Condensate

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10-Anthracene

 Compound

n-Nitrosomethylethylamine
Methyl Methanesulfonate
n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopro0yl)ether
 2-Methylphenol
 n-Nitrosospyrrolidi ie
 Acetophenone
 Hexachloroethane
                     Recovery
                       39     P
                       35     P
                       77     P

                     Recovery
                       NS
                       NS
                       NS

                       ug

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
Compound

4-Methylphenol
n-Nitrosodi-n-propylamine
Nitrobenzene
1 -Nitrosopiperidine
Isophorone
2,4-Dimethylphenol
Bis(2-chloroethoxy)methane
2,4-Dichlorophenol(CCC)
1,2,4-Trichlorobenzene
Naphthalene
2-Nitrophenol(CCC)
2,6-Dichlorophenol
Hexachloropropene
4-Chloroaniline
Hexachlorobutadiene(CCC)
n-Nitrosodi-n-butylamine
4-Chloro-3-methyl-phenol(CCC)
             % Recovery
                 61      P
                 59      P
                 127     P

             % Recovery
                 NS
                 NS
                 "g

                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
                 ND
 E = exceeded calib   ND = not detected
                   J = Peak below the calibration range

                           D49
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905191016X
9905033
S095033A
8270
HRGC/LRMS
 Sample Description/Narrative:

 905191016SBXOXAD

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
5/19/99
6/1/99
6/26/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                      fig       Compound

                      ND       Benzo(a)pyrene(CCC)
                      3      J 3-Methylcholanthrene
                      ND       Indeno(l,2,3-cd)pyrene
                      ND       Dibenz(a,h)anthracene
                      ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib    ND = not detected
                   J = Peak below the calibration range
                NS= not spiked
                                         D-50

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
                Orimulsion
                90251144C
                9905060
                S995060A
                8270
                HRGC/LRMS
Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
 90251144SBIOBL01) Condensate
                 |
 Compound       j
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzejie
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlor ophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
                                     MS
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
                                     ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/25/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
Compound                      MS
4-Chlorophenyl phenyl ether       ND
2-Methyl-4,6-dinitrophenol         ND
5-Nitro-o-toluidine               ND
Diphenylamine                  ND
Diallate                         ND
 1,3,5-Trinitrobenzene             ND
4-Bromophenyl phenyl ether       ND
Phenacetin                      ND
Hexachlorobenzene               ND
4-Aminobiphenyl                ND
Dinoseb                        ND
 Pentachlorophenol(CCC)          ND
 Pentachloronitrobenzene          ND
 Phenanthrene                    ND
 Anthracene                     ND
 Di-n-butyl phthalate              ND
 Isodrin                         ND
 Fluoranthene(CCC)               ND
 3,3'-Dimethylbenzidine            ND
 Pyrene                         ND
 Chlorobenzilate                  ND
 p-Dimethylaminoazobenzene      ND
 2-Acetylaminofluorene            ND
 Benzyl butyl phthalate            ND
 3,3'-Dichlorobenzidine            ND
 Benzo(a)anthracene              ND
                                  J = Peak below the calibration range
                NS= not spiked
                                           D-51

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
90251144C
9905060
S995060A
8270
HRGC/LRMS
 Sample Description/Narrative:

 90251144SBIOBL01 Condensate

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
            Date Sampled:
            Date Extracted:
            Date Acquired:
            Analyst:
            QC reviewer:
            Extract Volume
            Dilution Factor
05/25/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     pg        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno( 1,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                                           Mg

                                           ND
                                           ND
                                           ND
                                           ND
                                           ND
  E = exceeded calib
 ND = not detected
J = Peak below the calibration range
 NS= not spiked
                                       D-52

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054F
9905061
S9|95061A
8^70
H^GC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:

905261054SBFOBLul Filter

Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzend
 Benzyl Alcohol    j
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane
                     Recovery                                 % Recovery
                       49     P  D5-Nitrobenzene(surr#3)            56     P
                       62     P  2-Fluorobiphenyl(surr#4)            62     P
                       83     P  D14-Terphenyl(surr#6)              117    P

                    • Recovery                                 % Recovery
                       NS        13C6-2.5 Dichlorophenol            NS
                       NS        13C6-2,5-Phthalate anhydride        NS
                       NS

                       fig        Compound                       ug

                       ND        4-Methylphenol                    ND
                       ND        n-Nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                ND
                       ND        Isophorone                       ND
                       ND        2,4-Dimethylphenol                ND
                        2      J Bis(2-chloroethoxy)methane         ND
                       ND        2,4-Dichlorophenol(CCC)           ND
                       ND        1,2,4-Trichlorobenzene             ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)               ND
                       ND       2,6-Dichlorophenol                ND
                       ND       Hexachloropropene                ND
                       ND       4-Chloroaniline                    ND
                       ND       Hexachlorobutadiene(CCC)         ND
                       ND       n-Nitrosodi-n-butylamine           ND
                       ND       4-Chloro-3-methyl-phenol(CCC)      ND
  E = exceeded calib   ND = not detected
                   J = Peak below the calibration range
                 NS= not spiked
                                           D-53

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
               Orimulsion
               905261054F
               9905061
               S995061A
               8270
               HRGC/LRMS
Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
905261054SBFOBL01 Filter

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachlo|-ophenol
 4-Nitrophenol(SFJCC)
 Fluorene
 Diethyl phathalati

 E = exceeded calib    ND = not detected
 Date Sampled:
 Date Extracted:
 Date Acquired:
 Analyst:
 QC reviewer:
 Extract Volume
 Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                                     ug        Compound                      Hg
                                     ND        4-Chlorophenyl phenyl ether       ND
                                     ND        2-Methyl-4,6-dinitrophenol        ND
                                     ND        5-Nitro-o-toluidine               ND
                                     ND        Diphenylamine                  ND
                                     ND        Diallate                         ND
                                     ND        1,3,5-Trinitrobenzene             ND
                                     ND        4-Bromophenyl phenyl ether       ND
                                     ND        Phenacetin                      ND
                                     ND        Hexachlorobenzene              ND
                                     ND        4-Aminobiphenyl                ND
                                     ND        Dinoseb                        ND
                                     ND        Pentachlorophenol(CCC)          ND
                                     ND        Pentachloronitrobenzene          ND
                                     ND        Phenanthrene                    ND
                                     ND        Anthracene                     ND
                                     ND        Di-n-butyl phthalate               8
                                     ND        Isodrin                         ND
                                     ND       Fluoranthene(CCC)              ND
                                     ND       3,3'-Dimethylbenzidine           ND
                                     ND       Pyrene                         ND
                                     ND       Chlorobenzilate                  ND
                                     ND       p-Dimethylaminoazobenzene      ND
                                     ND       2-Acetylaminofluorene           ND
                                     ND       Benzyl butyl phthalate            ND
                                     ND       3,3'-Dichlorobenzidine           ND
                                     ND       Benzo(a)anthracene              ND
                                      3
J
                                  J = Peak below the calibration range
                 NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054F
9905Q61
S995061A
8270
HRGC/LRMS
Sample Description/Narrative:

905261054SBFOBL01 Filter

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     fig        Compound

                     ND        Benzo(a)pyrene(CCC)
                     ND        3-Methylcholanthrene
                     ND        Indeno(l,2,3-cd)pyrene
                     ND        Dibenz(a,h)anthracene
                     ND        Benzo(ghi)perylene
                              ND
                              ND
                              ND
                              ND
                              ND
 E = exceeded calib   ND = not detected
                 J = Peak below the calibration range
               NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054X
9905062
S995062A
4270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
      1       ml
      1
Sample Description/Narrative:

905261054SBXOBL01 XAD

Pre Extraction Sut rogates
2-Fluorophenol(surrw 1)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
13C6-1.2 Dichlorobenzene
13C6-Napthalene
D10-Anthracene

Compound

n-Nitrosomethylethylamine
Methyl Methanesulfonate
n-Nitrosodiethylamine
Bis (2-chloroethyl) ether
Ethyl methanesulfonate
Aniline
Phenol(CCC)
2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzenje
Benzyl Alcohol
Bis(2-chloroisoprofjyl)ether
2-Methylphenol   |
n-Nitrosospyrrolidime
Acetophenone
Hexachloroethane
                   % Recovery
                       41     P
                       53     P
                       94     P

                   % Recovery
                       46
                       55
                       75

                       Mg

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        3      J
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        5      J
                       ND
                             % Recovery
D5-Nitrobenzene(surr#3)             56     P
2-Fluorobiphenyl(surr#4)             67     P
D14-Terphenyl(surr#6)              120     P

                             % Recovery
13C6-2.5 Dichlorophenol             61
13C6-2,5-Phthalate anhydride        218
Compound                       fig

4-Methylphenol                    ND
n-Nitrosodi-n-propylamine           ND
Nitrobenzene                      ND
1-Nitrosopiperidine          .       ND
Isophorone                        ND
2,4-Dimethylphenol                 ND
Bis(2-chloroethoxy)methane         ND
2,4-Dichlorophenol(CCC)           ND
1,2,4-Trichlorobenzene              ND
Naphthalene                       ND
2-Nitrophenol(CCC)                ND
2,6-Dichlorophenol                 ND
Hexachloropropene                 ND
4-Chloroaniline                    ND
Hexachlorobutadiene(CCC)          ND
n-Nitrosodi-n-butylamine            ND
4-Chloro-3-methyl-phenol(CCC)      ND
 E = exceeded calib   ND = not detected
                   J = Peak below the calibration range      NS= not spiked

                         D-56

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
                Orimulsion
                905261054X
                9905062
                S995062A
                8270
                HRGC/LRMS
Sample Description/Narrative:
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
 905261054SBXOBL01 XAD

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate!

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                                     fig        Compound                      Mg
                                     ND        4-Chlorophenyl phenyl ether       ND
                                     ND        2-Methyl-4,6-dinitrophenol        ND
                                     ND        5-Nitro-o-toluidine               ND
                                     ND        Diphenylamine                  ND
                                     ND        Diallate                        ND
                                     ND        1,3,5-Trinitrobenzene             ND
                                     ND        4-Bromophenyl phenyl ether       ND
                                     ND        Phenacetin                      ND
                                     ND        Hexachlorobenzene              ND
                                     ND        4-Aminobiphenyl                ND
                                     ND       Dinoseb                        ND
                                     ND       Pentachlorophenol(CCC)          ND
                                     ND       Pentachloronitrobenzene          ND
                                     ND       Phenanthrene                   ND
                                     ND       Anthracene                     ND
                                     ND       Di-n-butyl phthalate               20
                                     ND       Isodrin                         ND
                                     ND       Fluoranthene(CCC)              ND
                                     ND       3,3'-Dimethylbenzidine           ND
                                     ND       Pyrene                         ND
                                     ND       Chlorobenzilate                  ND
                                     ND       p-Dimethylaminoazobenzene      ND
                                     ND       2-Acetylaminofluorene           ND
                                     ND       Benzyl butyl phthalate              1
                                     ND       3,3'-Dichlorobenzidine           ND
                                     ND       Benzo(a)anthracene              ND
                                     ND
                                  J = Peak below the calibration range

                                        D-57
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054X
9905062
S995062A
$270
HRGC/LRMS
Sample Description/Narrative:

905261054SBXOBioi XAD

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                      1 ml
                                                                      1
                     ug       Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = not detected
                  J = Peak below the calibration range
               NS= not spiked
                                     D-58

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054C
9905063
S;995063A
^270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
05/26/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description/Narrative:

 905261054SBIOBL01 Condensate

 Pre Extraction Surrogates           % Recovery
 2-Fluorophenol(surr#l)                   42     P
 D5-Phenol(surr#2)                       34     P
 2,4,6-Tribromophenol(surr#5)             77     P

 Pre Sampling Surrogates            % Recovery
 13C6-1,2 Dichlorobenzene                NS
 13C6-Napthalene                        NS
 DIO-Anthracene                        NS

 Compound                            ug

 n-Nitrosomethylethylamine               ND
 Methyl Methanesulfonate                 ND
 n-Nitrosodiethylamine                   ND
 Bis (2-chloroethyl) ether                ND
 Ethyl methanesulfonate                  ND
 Aniline                               ND
 Phenol(CCC)                          ND
 2-Chlorophenol                         ND
  1,3-Dichlorobenzene                    ND
  l,4-Dichlorobenzene(CCC)               ND
  1,2-Dichlorobenzene                    ND
 Benzyl Alcohol                         ND
 Bis(2-chloroisoprobyl)ether               ND
 2-Methylphenol  •                      ND
 n-Nitrosospyrrolid|ne                   ND
 Acetophenone   j                      ND
  Hexachloroethane                      ND
                                 D5-Nitrobenzene(surr#3)
                                 2-Fluorobiphenyl(surr#4)
                                 D 14-Terphenyl(surr#6)
                                 13C6-2.5 Dichlorophenol
                                 13C6-2,5-Phthalate anhydride
                                 Compound

                                 4-methylphenol
                                 n-Nitrosodi-n-propylamine
                                 Nitrobenzene
                                 1 -Nitrosopiperidine
                                 Isophorone
                                 2,4-Dimethylphenol
                                 Bis(2-chloroethoxy)methane
                                 2,4-Dichlorophenol(CCC)
                                 1,2,4-Trichlorobenzene
                                 Naphthalene
                                 2-Nitrophenol(CCC)
                                 2,6-Dichlorophenol
                                 Hexachloropropene
                                 4-Chloroaniline
                                 Hexachlorobutadiene(CCC)
                                 n-Nitrosodi-n-butylamine
                                 4-Chloro-3-methyl-phenol(CCC)
                                Recovery
                                  62     P
                                  60     P
                                 108     P

                                Recovery
                                 NS
                                 NS
                                  ug

                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                 ND
                                  ND
                                  ND
                                  ND
                                  ND
                                  ND
  E = exceeded calib   ND = not detected
                   J = Peak below the calibration range

                         D-59
                 NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:          Orimulsion
Sample Name:   905261054C
Lab Sample ID:  9905063
MS Data file:    S995063A
Method:         8270
                HRGC/LRMS
Sample Description/Narrative:

905261054SBIOBLJ)1 Condensate

Compound
2-Methylnaphthalene
Isosafrole
1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
2-Nitroaniline
3-Nitroaniline
Safrole
Acenaphthylene
 1,4-Naphthoquinone
Dimethyl phathalate
2,6-Dinitrotoluene
Acenaphthene(CCC)
 1-Napthylamine
2-Napthylamine
4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluene
 2,3,4,6-Tetrachlorophenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalate

 E = exceeded calib    ND = not detected
             Date Sampled:
             Date Extracted:
             Date Acquired:
             Analyst:
             QC reviewer:
             Extract Volume
             Dilution Factor
05/26/99
06/07/99
06/28/99
Bill Preston
Dennis Tabor
           1 ml
           1
    ug       Compound                       ug
   ND       4-Chlorophenyl phenyl ether       ND
   ND       2-Methyl-4,6-dinitrophenol        ND
   ND       5-Nitro-o-toluidine               ND
   ND       Diphenylamine                  ND
   ND       Diallate                        ND
   ND       1,3,5-Trinitrobenzene            ND
   ND       4-Bromophenyl phenyl ether       ND
   ND       Phenacetin                      ND
   ND       Hexachlorobenzene              ND
   ND       4-Aminobiphenyl                ND
   ND       Dinoseb                        ND
   ND       Pentachlorophenol(CCC)         ND
   ND       Pentachloronitrobenzene          ND
   ND       Phenanthrene                   ND
   ND       Anthracene                     ND
   ND       Di-n-butyl phthalate              ND
   ND       Isodrin                         ND
   ND       Fluoranthene(CCC)              ND
   ND       3,3'-Dimethylbenzidine           ND
   ND       Pyrene                         ND
   ND       Chlorobenzilate                 ND
    ND       p-Dimethylaminoazobenzene      ND
    ND       2-Acetylaminofluorene           ND
    ND       Benzyl butyl phthalate           ND
    ND       3,3'-Dichlorobenzidine           ND
    ND       Benzo(a)anthracene              ND
    ND
J = Peak below the calibration range
 NS= not spiked
                                         D-60

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
905261054C
9905063
3995063A
3270
HRGC/LRMS
Sample Description/Narrative:

905261054SBIOBL01 Condensate

Compound

Chrysene
di-n-Octyl phthalate(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
                                            05/26/99
                                            06/07/99
                                            06/28/99
                                            Bill Preston
                                            Dennis Tabor
                                                                       1 ml
                                                                       1
                     ug        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib
ND = not detected
                  J = Peak below the calibration range
               NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
Glassware Blank
9906001
S996001A
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
     NA
06/01/99
06/28/99
Bill Preston
Dennis Tabor
       1      ml
       1
 Sample Description/Narrative:

 Glassware Blank

 Pre Extraction Surrogates
 2-Fluorophenol(surr# 1)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzene(CCC)
 1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane
 E = exceeded calib   ND = not detected
                   % Recovery
                       71     P
                       80     P
                       90     P

                   % Recovery
                       NS
                       NS
                       NS

                       Mg

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
 13C6-2,5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 n-Nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 B is(2-chloroethoxy )methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
              % Recovery
                  79     P
                  76     P
                  118     P

              % Recovery
                  NS
                  NS
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                    J = Peak below the calibration range
                                             D-62
                                                                  NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
               Orimulsion
               Glassware Blank
               9906001
               S996001A
               8270
               HRGC/LRMS
Sample Description/Narrative:

Glassware Blank   :
                i
Compound                            ug
2-Methylnaphthalene                   ND
Isosafrole                            ND
1,2,4,5-Tetrachlorobenzene              ND
Hexachlorocyclopentadiene(SPCC)       ND
2,4,6-Trichlorophenol(CCC)             ND
2,4,5-Trichlorophenol                  ND
2-Chloronaphthalene                   ND
1,3 Dinitrobenzene                     ND
2-Nitroaniline                         ND
3-Nitroaniline                         ND
Safrole                              ND
Acenaphthylene                       ND
1,4-Naphthoquinone                   ND
Dimethyl phathalate                   ND
2,6-Dinitrotoluene                     ND
Acenaphthene(CCC)                   ND
1-Napthylamine                       ND
2-Napthylamine                       ND
4-Nitroaniline                         ND
2,4-Dinitrophenol(SPCC)               ND
Dibenzofuran                         ND
Pentachlorobenzene                   ND
2,4-Dinitrotoluene                     ND
2,3,4,6-Tetrachlorpphenol              ND
4-Nitrophenol(SPCC)                  ND
Fluorene                             ND
Diethyl phathalate                     ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
NA
06/01/99
06/28/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                                               Compound                      ug
                                               4-Chlorophenyl phenyl ether       ND
                                               2-Methyl-4,6-dinitrophenol        ND
                                               5-Nitro-o-toluidine               ND
                                               Diphenylamine                  ND
                                               Diallate                        ND
                                               1,3,5-Trinitrobenzene             ND
                                               4-Bromophenyl phenyl ether       ND
                                               Phenacetin                      ND
                                               Hexachlorobenzene              ND
                                               4-Aminobiphenyl                ND
                                               Dinoseb                        ND
                                               Pentachlorophenol(CCC)          ND
                                               Pentachloronitrobenzene          ND
                                               Phenanthrene                   ND
                                               Anthracene                     ND
                                               Di-n-butyl phthalate               11
                                               Isodrin                         ND
                                               Fluoranthene(CCC)              ND
                                               3,3'-Dimethylbenzidine           ND
                                               Pyrene                         ND
                                               Chlorobenzilate                 ND
                                               p-Dimethylaminoazobenzene      ND
                                               2-Acetylaminofluorene           ND
                                               Benzyl butyl phthalate            ND
                                               3,3'-Dichlorobenzidine           ND
                                               Benzo(a)anthracene              ND
 E = exceeded calib   ND = not detected      J = Peak below the calibration range     NS= not spiked

                                      D-63

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
Glassware Blank
9906001
S996001A
8270
HRGG/LRMS
Sample Description/Narrative:
 Glassware Blank
 Compound
 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
         Date Sampled:
         Date Extracted:
         Date Acquired:
         Analyst:
         QC reviewer:
         Extract Volume
         Dilution Factor
NA
06/01/99
06/28/99
Bill Preston
Dennis Tabor
                                                        1 ml
                                                        1
          Compound

ND       Benzo(a)pyrene(CCC)
ND       3-Methylcholanthrene
ND       Indeno( 1,2,3-cd)pyrene
ND       Dibenz(a,h)anthracene
ND       Benzo(ghi)perylene
                                                             Mg

                                                             ND
                                                             ND
                                                             ND
                                                             ND
                                                             ND
 E = exceeded calib   ND = ijot detected
                  J = Peak below the calibration range
                         NS= not spiked
                                              D-64

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216F
9006007
S$96007A
givo
HRGC/LRMS
Sample Description/Narrative:

906031216SBFOBLR6 Filter
                  I
Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromophenol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10-Anthracene
                     Recovery
                       42     P
                       56     P
                       85     P

                    ' Recovery
                       NS
                       NS
                       NS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
      1       ml
      1
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D14-Terphenyl(surr#6)
13C6-2.5 Dichlorophenol
13C6-2,5-Phthalate anhydride
                Recovery
                  56     P
                  68     P
                  116     P

                Recovery
                  NS
                  NS
 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenzene
 1,4-Dichlorobenzenej(CCC)
 1,2-Dichlorobenzene|
 Benzyl Alcohol
 B is(2-chloroisopropyl)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
 Acetophenone
 Hexachloroethane

 E = exceeded calib   ND = not detected
                       fig        Compound                       ug

                       ND        4-Methylphenol                    ND
                       ND        n-Nitrosodi-n-propylamine           ND
                       ND        Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                 ND
                       ND        Isophorone                        ND
                       ND        2,4-Dimethylphenol                 ND
                       ND        Bis(2-chloroethoxy)methane         ND
                       ND        2,4-Dichlorophenol(CCC)            ND
                       ND        1,2,4-Trichlorobenzene              ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)                ND
                       ND        2,6-Dichlorophenol                 ND
                       ND        Hexachloropropene                 ND
                       ND        4-Chloroaniline                    ND
                       ND        Hexachlorobutadiene(CCC)          ND
                       ND        n-Nitrosodi-n-butylamine            ND
                       ND        4-Chloro-3-methyl-phenol(CCC)      ND

                   J = Peak below the calibration range     NS= not spiked
                                             D-65

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216F
9906007
S$96007A
8l?0
HRGC/LRMS
Sample Description/Narrative:

906031216SBFOBLR6 Filter

Compound
2-Methylnaphthalene
Isosafrole
1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophenol
2-Chloronaphthalene
 l,3Dinitrobenzene
2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
 Pentachlorobenzene
 2,4-Dinitrotoluen^
 2,3,4,6-Tetrachlorophenol
 4-Nitrophenol(SP
 Fluorene
 Diethyl phathalate

 E = exceeded calib    ND = not detected
                                              Date Sampled:
                                              Date Extracted:
                                              Date Acquired:
                                              Analyst:
                                              QC reviewer:
                                              Extract Volume
                                              Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                                      ug       Compound
                                      ND       4-Chlorophenyl phenyl ether
                                      NT)       2-Methyl-4,6-dinitrophenol
                                      ND       5-Nitro-o-toluidine
                                      ND       Diphenylamine
                                      ND       Diallate
                                      ND        1,3,5-Trinitrobenzene
                                      ND       4-Bromophenyl phenyl ether
                                      ND       Phenacetin
                                      ND       Hexachlorobenzene
                                      ND       4-Aminobiphenyl
                                      ND        Dinoseb
                                      ND        Pentachlorophenol(CCC)
                                      ND        Pentachloronitrobenzene
                                      ND        Phenanthrene
                                      ND        Anthracene
                                      ND        Di-n-butyl phthalate
                                      ND        Isodrin
                                      ND        Fluoranthene(CCC)
                                      ND        3,3'-Dimethylbenzidine
                                      ND        Pyrene
                                      ND       Chlorobenzilate
                                      ND       p-Dimethylaminoazobenzene
                                      ND       2-Acetylaminofluorene
                                      ND       Benzyl butyl phthalate
                                      ND       3,3'-Dichlorobenzidine
                                      ND       Benzo(a)anthracene
                                      ND
                                                               Mg
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                                10
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                                               ND
                                   J = Peak below the calibration range

                                          D-66
                                                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216F
9906007
S996007A
8270
HRGC/LRMS
 Sample Description/Narrative:
 906031216SBFOBLR6 Filter
 Compound
 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
         Date Sampled:
         Date Extracted:
         Date Acquired:
         Analyst:
         QC reviewer:
         Extract Volume
         Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
          Compound

ND       Benzo(a)pyrene(CCC)
 2      J  3-Methylcholanthrene
ND       Indeno( 1,2,3-cd)pyrene
ND       Dibenz(a,h)anthracene
ND       Benzo(ghi)perylene
                                                             ND
                                                             ND
                                                             ND
                                                             ND
                                                             ND
  E = exceeded calib   ND = not detected     J = Peak below the calibration range     NS= not spiked
                                     D67

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216X
9906008
S996008A
8270
HRGC/LRMS
         Date Sampled:
         Date Extracted:
         Date Acquired:
         Analyst:
         QC reviewer:
         Extract Volume
         Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description/Narrative:

 906031216SBXOBtR6 - XAD

 Pre Extraction Surrogates
 2-Fluorophenol(surr#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
  n-Nitrosodiethylamine
  Bis (2-chloroethyl) ether
  Ethyl methanesulfonate
  Aniline
  Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenze|ne(CCC)
  1,2-Dichlorobenzdne
  Benzyl Alcohol
  B is(2-chloroisopr0pyl)ether
  2-Methylphenol |
  n-Nitrosospyrroli4ine
  Acetophenone  ;
  Hexachloroethane

  E = exceeded calib   ND = not detected
                   % Recovery
                        48     P
                        58     P
                        85     P

                   % Recovery
                        49
                        54
                        73
          D5-Nitrobenzene(surr#3)
          2-Fluorobiphenyl(surr#4)
          D14-Terphenyl(surr#6)
           13C6-2.5 Dichlorophenol
           13C6-2,5-Phthalate anhydride
              % Recovery
                  60     P
                  66     P
                  108    P

              % Recovery
                  58
                  185
Hg        Compound

ND        4-Methylphenol
ND        n-Nitrosodi-n-propylamine
ND        Nitrobenzene
ND        1-Nitrosopiperidine
ND        Isophorone
ND        2,4-Dimethylphenol
 4      J Bis(2-chloroethoxy)methane
ND        2,4-Dichlorophenol(CCC)
ND        1,2,4-Trichlorobenzene
ND        Naphthalene
ND        2-Nitrophenol(CCC)
ND        2,6-Dichlorophenol
ND        Hexachloropropene
ND        4-Chloroaniline
ND        Hexachlorobutadiene(CCC)
  5       J n-Nitrosodi-n-butylamine
 ND        4-Chloro-3-methyl-phenol(CCC)
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                     2
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                   ND
                                                                    ND
                     J = Peak below the calibration range

                               D-68
                           NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216X
9906008
S996008A
^270
fclRGC/LRMS
 Sample Description/Narrative:

 906031216SBXOBLR6 - XAD

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(S|>CC)
  Fluorene       j
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                      ug       Compound                       ug
                      ND       4-Chlorophenyl phenyl ether       ND
                      ND       2-Methyl-4,6-dinitrophenol        ND
                      ND       5-Nitro-o-toluidine               ND
                      ND       Diphenylamine                  ND
                      ND       Diallate                        ND
                      ND        1,3,5-Trinitrobenzene            ND
                      ND       4-Bromophenyl phenyl ether       ND
                      ND       Phenacetin                      ND
                      ND       Hexachlorobenzene              ND
                      ND       4-Aminobiphenyl                ND
                      ND       Dinoseb                       ND
                      ND       Pentachlorophenol(CCC)         ND
                      ND        Pentachloronitrobenzene         ND
                      ND        Phenanthrene                   ND
                      ND        Anthracene                      ND
                      ND        Di-n-butyl phthalate              13
                      ND        Isodrin                         ND
                      ND        Fluoranthene(CCC)               ND
                      ND        3,3'-Dimethylbenzidine            ND
                      ND        Pyrene                         ND
                      ND        Chlorobenzilate                  ND
                      ND        p-Dimethylaminoazobenzene      ND
                      ND        2-Acetylaminofluorene            ND
                      ND        Benzyl butyl phthalate            ND
                      ND       3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                       2      J
                   J = Peak below the calibration range

                          D-69
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
               Orimulsion
               906031216X
               9^06008
               S996008A
               8270
Project:
Sample Name:
Lab Sample ED:
MS Data file:
Method:
 Sample Description/Narrative:

 906031216SBXOBI[R6 - XAD

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/09/99
06/28/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                                    ug        Compound

                                    ND       Benzo(a)pyrene(CCC)
                                    ND       3-Methylcholanthrene
                                    ND       Indeno( 1,2,3-cd)pyrene
                                    ND       Dibenz(a,h)anthracene
                                    ND       Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib   ND = not detected
                                 J = Peak below the calibration range

                                       D-70
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216C
9906009
S996009B
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/07/99
06/29/99
Bill Preston
Dennis Tabor
       1      ml
       1
 Sample Description/Narrative:

 906031216SBFOBLR6-Condensate

 Pre Extraction Surrogates
 2-Fluorophenol(surr#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

  Pre Sampling Surrogates
  13C6-1.2 Dichlorobenzene
  13C6-Napthalene
  D10- Anthracene

  Compound

  n-Nitrosomethylethylamine
  Methyl Methanesulfonate
  n-Nitrosodiethylamine
  Bis (2-chloroethyl) ether
  Ethyl methanesulfonate
   Aniline
   Phenol(CCC)
   2-Chlorophenol
   1,3-Dichlorobenzene
   1,4-Dichlorobenzene(CCC)
   1,2-Dichlorobenzene
   Benzyl Alcohol
   B is(2-chloroisopippyl)ether
   2-Methylphenol j
   n-Nitrosospyrrolipine
   Acetophenone
   Hexachloroethane

    E = exceeded calib   ND = not detected
                      Recovery
                        30     P
                        25     P
                        57     P

                     !> Recovery
                        NS
                        NS
                        NS
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         ND
                         ND
                         ND
 D5-Nitrobenzene(surr#3)
 2-Fluorobiphenyl(surr#4)
 D 14-Terphenyl(surr#6)
  13C6-2.5 Dichlorophenol
  13C6-2,5-Phthalate anhydride
  Compound

  4-Methylphenol
  n-Nitrosodi-n-propylamine
  Nitrobenzene
  1 -Nitrosopiperidine
  Isophorone
  2,4-Dimethylphenol
  B is(2-chloroethoxy)methane
  2,4-Dichlorophenol(CCC)
   1,2,4-Trichlorobenzene
  Naphthalene
   2-Nitrophenol(CCC)
   2,6-Dichlorophenol
   Hexachloropropene
   4-Chloroaniline
   Hexachlorobutadiene(CCC)
   n-Nitrosodi-n-butylamine
   4-Chloro-3-methyl-phenol(CCC)
                Recovery
                  45     P
                  42     P
                  83     P

                > Recovery
                  NS
                  NS
                   "g

                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                   ND
                     J = Peak below the calibration range

                           D-71
                   NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216C
9906009
S996009B
8270
HRGC/LRMS
 Sample Description/Narrative:
                i
 906031216SBFOBLR6-Condensate

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
 Dimethyl phathalate
  2,6-Dinitrotoluene
  Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
                      Mg
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
                      ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/07/99
06/29/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
 Compound                      Mg
 4-Chlorophenyl phenyl ether       ND
 2-Methyl-4,6-dinitrophenol        ND
 5-Nitro-o-toluidine               ND
 Diphenylamine                  ND
 Diallate                         ND
 1,3,5-Trinitrobenzene             ND
 4-Bromophenyl phenyl ether       ND
 Phenacetin                      ND
 Hexachlorobenzene              ND
 4-Aminobiphenyl                ND
 Dinoseb                        ND
 Pentachlorophenol(CCC)          ND
 Pentachloronitrobenzene          ND
 Phenanthrene                    ND
 Anthracene                     ND
 Di-n-butyl phthalate              ND
 Isodrin                         ND
 Fluoranthene(CCC)              ND
 3,3'-Dimethylbenzidine           ND
 Pyrene                         ND
 Chlorobenzilate                  ND
 p-Dimethylaminoazobenzene      ND
 2-Acetylaminofluorene           ND
 Benzyl butyl phthalate            ND
 3,3'-Dichlorobenzidine            ND
 Benzo(a)anthracene              ND
                   J = Peak below the calibration range
                 NS= not spiked
                                          D-72

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906031216C
9906009
S996009B
8270
HRGC/LRMS
 Sample Description/Narrative:

 906031216SBFOBLR6-Condensate

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/03/99
06/07/99
06/29/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     fig        Compound

                     ND       Benzo(a)pyrene(CCC)
                      1      J 3-Methylcholanthrene
                     ND       Indeno( 1,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               M8

                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib  I ND = not detected
                  J = Peak below the calibration range
                NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304F
9906019
S996019B
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
                            06/04/99
                            06/09/99
                            06/29/99
                            Bill Preston
                            Dennis Tabor
                                  1       ml
                                  1
 Sample Description/Narrative:

 906041304SBFOBLR6 Filter

 Pre Extraction Surrogates
 2-Fluorophenol(surr#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
 Benzyl Alcohol
 B is(2-chloroisopropy l)ether
 2-Methylphenol
 n-Nitrosospyrrolidine
  Acetophenone
  Hexachloroethane
 Recovery
   42     P
   57     P
   75     P

. Recovery
   NS
   NS
   NS

   fig

   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
 D5-Nitrobenzene(surr#3)
 2-Fluorobiphenyl(surr#4)
 D14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 n-Nitrosodi-n-propylamine
 Nitrobenzene
 1-Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 Bis(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
                                                                 Recovery
                                                                   59      P
                                                                   65      P
                                                                   105     P

                                                                 Recovery
                                                                   NS
                                                                   NS
                                                                   Mg
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                  ND
                                                                   ND
  E = exceeded calib   ND = not detected
                    J = Peak below the calibration range
                 NS= not spiked
                                                  D-74

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304F
9906019
S996019B
8270
HRGO/LRMS
 Sample Description/Narrative:

 906041304SBFOBLR6 Filter

 Compound
 2-Methylnaphthalene  I
 Isosafrole
 1,2,4,5-Tetrachlorobenz 5ne
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
  l,3Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
  1,4-Naphthoquinone
  Dimethyl phathalate
  2,6-Dinitrotoluene
  Acenaphthene(CCC)
  1-Napthylamine
  2-Napthylamine
  4-Nitroaniline
  2,4-Dinitrophenol(SPCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/04/99
06/09/99
06/29/99
Bill Preston
Dennis Tabor
                                                                        1ml
                                                                        1
                      fig       Compound                       Mg
                     ND       4-Chlorophenyl phenyl ether       ND
                     ND       2-Methyl-4,6-dinitrophenol        ND
                     ND       5-Nitro-o-toluidine               ND
                     ND       Diphenylamine                  ND
                     ND       Diallate                        ND
                     ND        1,3,5-Trinitrobenzene            ND
                     ND       4-Bromophenyl phenyl ether       ND
                     ND       Phenacetin                      ND
                      ND       Hexachlorobenzene              ND
                      ND       4-Aminobiphenyl                ND
                      ND        Dinoseb                       ND
                      ND        Pentachlorophenol(CCC)          ND
                      ND        Pentachloronitrobenzene          ND
                      ND        Phenanthrene                    ND
                      ND        Anthracene                      ND
                      ND        Di-n-butyl phthalate              40
                      ND        Isodrin                         ND
                      ND        Fluoranthene(CCC)               ND
                      ND        3,3'-Dimethylbenzidine            ND
                      ND        Pyrene                         ND
                      ND        Chlorobenzilate                  ND
                      ND        p-Dimethylaminoazobenzene      ND
                      ND        2-Acetylaminofluorene            ND
                      ND        Benzyl butyl phthalate            ND
                      ND       3,3'-Dichlorobenzidine            ND
                      ND       Benzo(a)anthracene              ND
                        2
J
                   J = Peak below the calibration range
                 NS= not spiked
                                               D-75

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304F
9906019
S996019B
8270
HRGC/LRMS
 Sample Description/Narrative:

 906041304SBFOBLR6 Filter

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/04/99
06/09/99
06/29/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     ug        Compound

                     ND       Benzo(a)pyrene(CCC)
                      9      J 3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib    ND = not detected
                  J = Peak below the calibration range
                NS= not spiked
                                          D-76

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304X
9906020
S996020B
81270
HRGC/LRMS
 Date Sampled:
 Date Extracted:
 Date Acquired:
 Analyst:
 QC reviewer:
 Extract Volume
 Dilution Factor
               06/04/99
               06/09/99
               06/29/99
               Bill Preston
               Dennis Tabor
                     1       ml
                     1
 Sample DescriptioriVNarrative:

 906041304SBXOBLR6 XAD

 Pre Extraction Surrogates
 2-Fluorophenol(surr# 1)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
  Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzeiie
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
  Benzyl Alcohol
  B is(2-chloroisopropy l)ether
  2-Methylphenol
  n-Nitrosospyrrolidine
  Acetophenone
  Hexach loroethane

  E = exceeded calib    ND = not detected
                     Recovery
                       48     P
                       62     P
                       91     P

                     > Recovery
                       53
                       61
                       73
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         3
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                        ND
                         4
                        ND
 D5-Nitrobenzene(surr#3)
 2-Fluorobiphenyl(surr#4)
 D 14-Terphenyl(surr#6)
  13C6-2.5 Dichlorophenol
  13C6-2,5-Phthalate anhydride
J
                            % Recovery
                                 65     P
                                 71     P
                                 123     P

                            % Recovery
                                 63
                                 45
Compound                       Mg

4-Methylphenol                    ND
n-Nitrosodi-n-propylamine           ND
Nitrobenzene                      ND
1-Nitrosopiperidine                 ND
Isophorone                       ND
2,4-Dimethylphenol                ND
Bis(2-chloroethoxy)methane         ND
2,4-Dichlorophenol(CCC)           ND
1,2,4-Trichlorobenzene             ND
Naphthalene                      ND
2-Nitrophenol(CCC)                ND
2,6-Dichlorophenol                ND
Hexachloropropene                ND
4-Chloroaniline                    ND
Hexachlorobutadiene(CCC)         ND
n-Nitrosodi-n-butylamine           ND
4-Chloro-3-methyl-phenol(CCC)     ND
                    J = Peak below the calibration range

                            D-77
                  NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304X
9906020
S996020B
8270
HRGC/LRMS
Sample Description/Narrative:

906041304SBXOBtR6 XAD

Compound
2-Methylnaphthalene
Isosafrole
 1,2,4,5-Tetrachlorobenzene
Hexachlorocyclopentadiene(SPCC)
2,4,6-Trichlorophenol(CCC)
2,4,5-Trichlorophtnol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
 1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran   i
 Pentachlorobenze|ne
 2,4-Dinitrotoluenb
 2,3,4,6-Tetrachlo
 •ophenol
 4-Nitrophenol(SPCC)
 Fluorene
 Diethyl phathalatfe
            Date Sampled:  06/04/99
            Date Extracted:  06/09/99
             Date Acquired:
             Analyst:
             QC reviewer:
             Extract Volume
             Dilution Factor
06/29/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
   ug        Compound                      ug
   ND        4-Chlorophenyl phenyl ether       ND
   ND        2-Methyl-4,6-dinitrophenol        ND
   ND        5-Nitro-o-toluidine               ND
   ND        Diphenylamine                  ND
   ND        Diallate                        ND
   ND        1,3,5-Trinitrobenzene             ND
   ND        4-Bromophenyl phenyl ether       ND
   ND        Phenacetin                      ND
   ND        Hexachlorobenzene              ND
   ND        4-Aminobiphenyl                ND
   ND        Dinoseb                        ND
   ND        Pentachlorophenol(CCC)          ND
   ND        Pentachloronitrobenzene          ND
   ND       Phenanthrene                    ND
   ND       Anthracene                     ND
   ND       Di-n-butyl phthalate               5
   ND       Isodrin                         ND
   ND       Fluoranthene(CCC)              ND
   ND       3,3'-Dimethylbenzidine           ND
   ND       Pyrene                         ND
   ND       Chlorobenzilate                  ND
   ND       p-Dimethylaminoazobenzene      ND
   ND       2-Acetylaminofluorene           ND
   ND       Benzyl butyl phthalate            ND
   ND       3,3'-Dichlorobenzidine           ND
   ND       Benzo(a)anthracene              ND
   ND
  E = exceeded calib
 ND = not detected
J = Peak below the calibration range
 NS= not spiked
                                       D-78

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:        Orimulsion
Sample Name:   906041304X
Lab Sample ID:  9906020
MS Data file:   S996020B
Method:        8270
               HRGC/LRMS

Sample Description/Narrative:

906041304SBXOBLR6 XAD

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
            Date Sampled:
            Date Extracted:
            Date Acquired:
            Analyst:
            QC reviewer:
            Extract Volume
            Dilution Factor
06/04/99
06/09/99
06/29/99
Bill Preston
Dennis Tabor
           1 ml
           1
   jig       Compound

   ND       Benzo(a)pyrene(CCC)
    1       J 3-Methylcholanthrene
   ND       Indeno(l,2,3-cd)pyrene
   ND       Dibenz(a,h)anthracene
   ND       Benzo(ghi)perylene
                Mg

                ND
                ND
                ND
                ND
                ND
  E = exceeded calib   ND = not detected
J = Peak below the calibration range
 NS= not spiked
                                        D-79

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906041304C
9906021
$9960216
$270
rlRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/04/99
06/15/99
06/29/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description/Narrative:

 906041304SBIOBLR6 Condensate

 Pre Extraction Surrogates           % Recovery
 2-Fluorophenol(surir#l)                    51      P
 D5-Phenol(surr#2)                        46      P
 2,4,6-Tribromophenol(surr#5)              98      P

 Pre Sampling Surrogates            % Recovery
 13C6-1,2 Dichlorobenzene                 NS
 13C6-Napthalene                        NS
 D10-Anthracene                         NS

 Compound                             M£

 n-Nitrosomethylethylamine                ND
 Methyl Methanesulfonate                 ND
 n-Nitrosodiethylamine                    ND
 Bis (2-chloroethyl) ether                 ND
 Ethyl methanesulfonate                   ND
 Aniline                                ND
 Phenol(CCC)                           ND
 2-Chlorophenol                          ND
  1,3-Dichlorobenzene                     ND
  l,4-Dichlorobenzene(CCC)                ND
  1,2-Dichlorobenzene                     ND
  Benzyl Alcohol                          ND
  Bis(2-chloroisopropyl)ether               ND
  2-Methylphenol                         ND
  n-Nitrosospyrrolidine                    ND
  Acetophenone   \                       ND
  Hexachloroethane                       ND
                                                              % Recovery
                                 D5-Nitrobenzene(surr#3)            74     P
                                 2-Fluorobiphenyl(surr#4)            74     P
                                 D14-Terphenyl(surr#6)              131    P

                                                              % Recovery
                                 13C6-2.5 Dichlorophenol            NS
                                 13C6-2,5-Phthalate anhydride        NS
                                  Compound                        fig

                                  4-Methylphenol                   ND
                                  n-Nitrosodi-n-propylamine          ND
                                  Nitrobenzene                      ND
                                  1-Nitrosopiperidine                ND
                                  Isophorone                       ND
                                  2,4-Dimethylphenol                ND
                                  Bis(2-chloroethoxy)methane         ND
                                  2,4-Dichlorophenol(CCC)           ND
                                  1,2,4-Trichlorobenzene             ND
                                  Naphthalene                      ND
                                  2-Nitrophenol(CCC)               ND
                                  2,6-Dichlorophenol                 ND
                                  Hexachloropropene                 ND
                                  4-Chloroaniline                    ND
                                  Hexachlorobutadiene(CCC)          ND
                                  n-Nitrosodi-n-butylamine            ND
                                  4-Chloro-3-methyl-phenol(CCC)      ND
  E = exceeded calib   ND = not detected
                    J = Peak below the calibration range      NS= not spiked
                                            D-80

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
13rimulsion
J06041304C
J906021
S996021B
B270
HRGC/LRMS
 Sample Description/Narrative:

 906041304SBIOBLR6 Condensate

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichlorophenol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
  Pentachlorobenzfcne
  2,4-Dinitrotolueijie
  2,3,4,6-Tetrachl
-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
)rimulsion
 )6041304C
    321
&96021B
3270
  IGC/LRMS
 Sample Description/Narrative:

 906041304SBIOBLR6 Condensate

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/04/99
06/15/99
06/29/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                     jig        Compound

                     ND        Benzo(a)pyrene(CCC)
                      1       J  3-Methylcholanthrene
                     ND        Indeno( 1,2,3-cd)pyrene
                     ND        Dibenz(a,h)anthracene
                     ND        Benzo(ghi)perylene
                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib
 ND = not detected      J = Peak below the calibration range     NS= not spiked
                                           D-82

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Qrimulsion
906071229C
 906024
 996024B
8270
HRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/08/99
06/15/99
06/29/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description/Narrative:

 906071229BIOBLR6 Condensate/dl4-Terphenyl out of criteria
 Pre Extraction Surrogates
 2-Fluorophenol(sunf#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfanate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
 Benzyl Alcohol
 Bis(2-chloroisoproJ3yl)ether
  2-Methylphenol
  n-Nitrosospyrrolidine
  Acetophenone
  Hexachloroethane
                     Recovery                                 % Recovery
                       58     P  D5-Nitrobenzene(surr#3)            80     P
                       50     P  2-Fluorobiphenyl(surr#4)            80     P
                       105    P  D14-Terphenyl(surr#6)              138    F

                    »Recovery                                 % Recovery
                       NS       13C6-2.5 Dichlorophenol            NS
                       NS       13C6-2,5-Phthalate anhydride        NS
                       NS

                       ug       Compound                       Mg

                       ND       4-Methylphenol                   ND
                       ND       n-Nitrosodi-n-propylamine           ND
                       ND       Nitrobenzene                      ND
                       ND        1-Nitrosopiperidine                ND
                       ND       Isophorone                       ND
                       ND       2,4-Dimethylphenol                ND
                       ND       Bis(2-chloroethoxy)methane         ND
                       ND       2,4-Dichlorophenol(CCC)           ND
                       ND        1,2,4-Trichlorobenzene             ND
                       ND        Naphthalene                      ND
                       ND        2-Nitrophenol(CCC)               ND
                       ND        2,6-Dichlorophenol                ND
                       ND        Hexachloropropene                ND
                       ND        4-Chloroaniline                   ND
                       ND        Hexachlorobutadiene(CCC)         ND
                       ND        n-Nitrosodi-n-butylamine           ND
                       ND        4-Chloro-3-methyl-phenol(CCC)     ND
  E = exceeded calib   ND = not detected      J = Peak below the calibration range      NS= not spiked

                                              D-83

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
()rimulsion
<06071229C
< 1906024
 1996024B
 i270
URGC/LRMS
                i
 Sample Description/Narrative:

 906071229BIOBLB|6 Condensate/dl4-Terphenyl out of criteria
          Date Sampled:
          Date Extracted:
          Date Acquired:
          Analyst:
          QC reviewer:
          Extract Volume
          Dilution Factor
06/08/99
06/15/99
06/29/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
 Compound      j
 2-Methylnaphthal^ne
 Isosafrole
 1,2,4,5-Tetrachlorobenzene
 Hexachlorocyclopentadiene(SPCC)
 2,4,6-Trichloroph0nol(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
 2,4-Dinitrophenol(SPCC)
 Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluenie
  2,3,4,6-Tetrachlo
 rophenol
  4-Nitrophenol(S!fCC)
  Fluorene
  Diethyl phathalatje

  E = exceeded calib   ND = not delected
ug        Compound                       ug
ND       4-Chlorophenyl phenyl ether       ND
ND       2-Methyl-4,6-dinitrophenol        ND
ND       5-Nitro-o-toluidine               ND
ND       Diphenylamine                  ND
ND       Diallate                        ND
ND       1,3,5-Trinitrobenzene            ND
ND       4-Bromophenyl phenyl ether       ND
ND       Phenacetin                      ND
ND       Hexachlorobenzene              ND
ND       4-Aminobiphenyl                ND
ND       Dinoseb                        ND
ND       Pentachlorophenol(CCC)         ND
ND       Pentachloronitrobenzene          ND
ND       Phenanthrene                   ND
ND       Anthracene                     ND
ND       Di-n-butyl phthalate             ND
ND       Isodrin                        ND
ND       Fluoranthene(CCC)               ND
ND       3,3'-Dimethylbenzidine            ND
ND       Pyrene                         ND
ND       Chlorobenzilate                  ND
ND       p-Dimethylaminoazobenzene       ND
ND       2-Acetylaminofluorene            ND
ND       Benzyl butyl phthalate            ND
ND       3,3'-Dichlorobenzidine            ND
ND       Benzo(a)anthracene              ND
ND
                   J = Peak below the calibration range

                         D-84
                          NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Otganics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Ojrimulsion
906071229C
9 J06024
S596024B
8 HO
tRGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
 Sample Description/Narrative:

 906071229BIOBLR6 Condensate/dl4-Terphenyl out of criteria
 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
06/08/99
06/15/99
06/29/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
                     fig        Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               Mg

                               ND
                               ND
                               ND
                               ND
                               ND
  E = exceeded calib   |ND = not detected
                  J = Peak below the calibration range
                NS= not spiked
                                       D-85

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
906071229F
9906022
 5996022A
 !270
 WGC/LRMS
             Date Sampled:
             Date Extracted:
             Date Acquired:
             Analyst:
             QC reviewer:
             Extract Volume
             Dilution Factor
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
      1      ml
      1
Sample Description/Narrative:

906071229SBFOBtR6 Filter
                 j
Pre Extraction Surrogates
2-Fluorophenol(surr#l)
D5-Phenol(surr#2)
2,4,6-Tribromopheilol(surr#5)

Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylarnine
 Bis (2-chloroethy
 ) ether
 Ethyl methanesulfqnate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
 1,3-Dichlorobenze
-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Oripiulsion
906J071229F
99(6022
S9<>6022A
82:
0
                HPGC/LRMS
 Sample Description Narrative:

 906071229SBFOBLR6 Filter

 Compound
 2-Methylnaphthalene
 Isosafrole
 1,2,4,5-Tetrachlorob snzene
 Hexachlorocyclopen adiene(SPCC)
 2,4,6-Trichlorophen< >1(CCC)
 2,4,5-Trichlorophenol
 2-Chloronaphthalene
 1,3 Dinitrobenzene
 2-Nitroaniline
 3-Nitroaniline
 Safrole
 Acenaphthylene
 1,4-Naphthoquinone
 Dimethyl phathalate
 2,6-Dinitrotoluene
 Acenaphthene(CCC)
  1-Napthylamine
 2-Napthylamine
 4-Nitroaniline
  2,4-Dinitrophenol(S
   PCC)
  Dibenzofuran
  Pentachlorobenzene
  2,4-Dinitrotoluene
  2,3,4,6-Tetrachlorophenol
  4-Nitrophenol(SPCC)
  Fluorene         |
  Diethyl phathalate

  E = exceeded calib   ND = not detected
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                         1 ml
                                                         1
                   jig       Compound                       ug
                  ND       4-Chlorophenyl phenyl ether       ND
                  ND       2-Methyl-4,6-dmitrophenol        ND
                  ND       5-Nitro-o-toluidine               ND
                  ND       Diphenylamine                  ND
                  ND       Diallate                        ND
                  ND        1,3,5-Trinitrobenzene            ND
                  ND       4-Bromophenyl phenyl ether       ND
                  ND       Phenacetin                      ND
                  ND       Hexachlorobenzene              ND
                   ND       4-Aminobiphenyl                ND
                   ND        Dinoseb                       ND
                   ND        Pentachlorophenol(CCC)          ND
                   ND        Pentachloronitrobenzene         ND
                   ND        Phenanthrene                    ND
                   ND        Anthracene                      ND
                   ND        Di-n-butyl phthalate               6
                   ND        Isodrin                         ND
                   ND        Fluoranthene(CCC)               ND
                   ND        3,3'-Dimethylbenzidine            ND
                   ND        Pyrene                         ND
                   ND        Chlorobenzilate                  ND
                   ND        p-Dimethylaminoazobenzene      ND
                   ND        2-Acetylaminofluorene            ND
                   ND        Benzyl butyl phthalate            ND
                   ND       3,3'-Dichlorobenzidine            ND
                   ND       Benzo(a)anthracene              ND
                    2      J

                 = Peak below the calibration range     NS= not spiked
                                              D-87

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:        Orimulsion
Sample Name:  906071229F
Lab Sample ID:  9J906022
MS Data file:   S996022A
Method:        ^270
                  IGC/LRMS
 Sample Description/Narrative:

 906071229SBFOBLR6 Filter

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
            Date Sampled:
            Date Extracted:
            Date Acquired:
            Analyst:
            QC reviewer:
            Extract Volume
            Dilution Factor
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
           1 ml
           1
   jig       Compound

   ND       Benzo(a)pyrene(CCC)
   34       3-Methylcholanthrene
   ND       Indeno(l,2,3-cd)pyrene
   ND       Dibenz(a,h)anthracene
   ND       Benzo(ghi)perylene
                 Mg

                ND
                ND
                ND
                ND
                ND
  E = exceeded calib   ND = not detected
J = Peak below the calibration range
                                                              NS= not spiked
                                             D-88

-------
APPCD Organic Support Laboratory
Semi-Volatile O^ganics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
  O^imulsion
  906071229X
  9'K)6023
  S J96023A
  8170
  ERGC/LRMS
 Sample DescriptioifNarrative:
                                                Date Sampled:
                                                Date Extracted:
                                                Date Acquired:
                                                Analyst:
                                                QC reviewer:
                                                Extract Volume
                                                Dilution Factor
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
      1      ml
      1
 906071229SBXOBIJ,R6 XAD-dl4-Terphenyl out of criteria
                    I out of criteria
                                    % Recovery
                                        72     P  D5-Nitrobenzene(surr#3)
                                        85     P  2-Fluorobiphenyl(surr#4)
                    surr#5)              144     F  D14-Terphenyl(surr#6)
Sur -ogates
2,4,6-TribromopheJiol i
Pre Extraction!
2-Fluorophenol(surr *1)
D5-Phenol(surr#2)
2,4,6-Tribromophenbl(si;
 Pre Sampling Surrogates
 13C6-1.2 Dichlorobfenzene
 13C6-Napthalene
 D10-Acenapthalene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamfne
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzeffle(CCC)
  1,2-Dichlorobenzeme
  Benzyl Alcohol
  B is(2-chloroisopro i>y l)ether
  2-Methylphenol   |
  n-Nitrosospyrrolid|ne
  Acetophenone
  Hexachloroethane
                        Recovery
                          59
                          63
                          78

                          ug

                          ND
                          ND
                          ND
                          ND
                          ND
                          ND
                           5
                          ND
                          ND
                          ND
                          ND
                          ND
                          ND
                          ND
                          ND
                           6
                          ND
                                                 13C6-2.5 Dichlorophenol
                                                 13C6-2,5-Phthalate anhydride
              % Recovery
                  87     P
                  91     P
                  144    F

              % Recovery
                  64
                  29
                                                 Compound                        ug

                                                 4-Methylphenol                   ND
                                                 n-Nitrosodi-n-propylamine          ND
                                                 Nitrobenzene                     ND
                                                  1-Nitrosopiperidine                ND
                                                 Isophorone                       ND
                                                 2,4-Dimethylphenol                ND
                                               J Bis(2-chloroethoxy)methane         ND
                                                 2,4-Dichlorophenol(CCC)           ND
                                                  1,2,4-Trichlorobenzene              ND
                                                  Naphthalene                        2
                                                  2-Nitrophenol(CCC)                ND
                                                  2,6-Dichlorophenol                 ND
                                                  Hexachloropropene                 ND
                                                  4-Chloroaniline                    ND
                                                  Hexachlorobutadiene(CCC)          ND
                                                J n-Nitrosodi-n-butylamine            ND
                                                  4-Chloro-3-methyl-phenol(CCC)      ND
  E = exceeded calib   ND = not detected      J = Peak below the calibration range      NS= not spiked
                                                D-89

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:        Orimulsion
Sample Name:  906071229X
Lab Sample ID:  ^906023
MS Data file:
Method:
;996023A
5270
1RGC/LRMS
Sample Description/Narrative:
906071229SBXOB
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                                        1 ml
                                                                        1
,R6 XAD-dl4-Terphenyl out of criteria
 Compound                           Mg
 2-Methylnaphthalene                   1
 Isosafrole                            ND
 1,2,4,5-Tetrachloitobenzene             ND
 Hexachlorocyclopentadiene(SPCC)      ND
 2,4,6-Trichlorophenol(CCC)            ND
 2,4,5-Trichlorophenol                  ND
 2-Chloronaphthalene                  ND
 l,3Dinitrobenzene                    ND
 2-Nitroaniline                        ND
 3-Nitroaniline                        ND
 Safrole                              ND
 Acenaphthylene                      ND
 1,4-Naphthoquin(j>ne                  ND
 Dimethyl phathaljate                   ND
 2,6-Dinitrotoluene                    ND
 Acenaphthene(CCC)                  ND
 1-Napthylamine                      ND
 2-Napthylamine                      ND
 4-Nitroaniline                        ND
 2,4-DinitrophenoI(SPCC)              ND
 Dibenzofuran                        ND
 Pentachlorobenzene                   ND
 2,4-Dinitrotoluene                    ND
 2,3,4,6-Tetrachlorophenol              ND
 4-Nitrophenol(SPCC)                 ND
 Fluorene                            ND
 Diethyl phathalate                    ND
                               Compound                      ug
                               4-Chlorophenyl phenyl ether       ND
                               2-Methyl-4,6-dinitrophenol        ND
                               5-Nitro-o-toluidine               ND
                               Diphenylamine                  ND
                               Diallate                         ND
                               1,3,5-Trinitrobenzene             ND
                               4-Bromophenyl phenyl ether       ND
                               Phenacetin                      ND
                               Hexachlorobenzene              ND
                               4-Aminobiphenyl                ND
                               Dinoseb                        ND
                               Pentachlorophenol(CCC)          ND
                               Pentachloronitrobenzene          ND
                               Phenanthrene                    ND
                               Anthracene                     ND
                               Di-n-butyl phthalate               9
                               Isodrin                         ND
                               Fluoranthene(CCC)              ND
                               3,3'-Dimethylbenzidine           ND
                               Pyrene                         ND
                               Chlorobenzilate                  ND
                               p-Dimethylaminoazobenzene      ND
                               2-Acetylaminofluorene           ND
                               Benzyl butyl phthalate            ND
                               3,3'-Dichlorobenzidine           ND
                               Benzo(a)anthracene              ND
 E = exceeded calib    ND = not detected      J = Peak below the calibration range     NS= not spiked

                                     D-90

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
OrimUlsion
90607J1229X
9906C23
S996Q23A
8270
HRGC/LRMS
Sample Description/Narrative:
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
906071229SBXOBLR6 2 AD-dl4-Terphenyl out of criteria
 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)ahthracene
 Benzo(k)fluoranthene
06/07/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     fig        Compound

                     ND       Benzo(a)pyrene(CCC)
                      8      J  3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                               "g

                               ND
                               ND
                               ND
                               ND
                               ND
 E = exceeded calib   ND = i lot detected
                  J = Peak below the calibration range
                                           D-91
               NS= not spiked

-------
APPCD Organic Support Laboratory
Semi-Volatile Qrganics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
Matrix Spike
9906048
 •996048A
 270
^RGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
NA
06/21/99
06/30/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description/Narrative:
 Matrix Spike-100 ug of PAH components only
 Pre Extraction Surrogates
 2-Fluorophenol(surt#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophertol(surr#5)

 Pre Sampling Surrogates
 13C6-1,2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfanate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
  1,3-Dichlorobenzeme
  1,4-Dichlorobenze
-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Ojrimulsion
M atrix Spike
9906048
S')96048A
8:170
HRGC/LRMS
Sample Description/Narrative:

Matrix Spike-100 ug of PAH components only

 Compound                            MS
 2-Methylnaphthalene                  ND
 Isosafrole                            ND
 1,2,4,5-Tetrachlordbenzene             ND
 Hexachlorocyclop4ntadiene(SPCC)      ND
 2,4,6-Trichlorophehol(CCC)            ND
 2,4,5-Trichlorophenol                 ND
 2-Chloronaphthalene                  ND
 1,3 Dinitrobenzene                     ND
 2-Nitroaniline                         ND
 3-Nitroaniline                         ND
 Safrole                               ND
 Acenaphthylene                        62
 1,4-Naphthoquinotie                   ND
 Dimethyl phathalate                   ND
 2,6-Dinitrotoluene                     ND
 Acenaphthene(CCC)                    59
 1-Napthylamine                       ND
 2-Napthylamine                       ND
 4-Nitroaniline                         ND
 2,4-Dinitrophenol(SPCC)              ND
 Dibenzofuran                         ND
 Pentachlorobenzene                   ND
 2,4-Dinitrotoluen^                     ND
 2,3,4,6-Tetrachlor[)phenol               ND
 4-Nitrophenol(SPCC)                   ND
  Fluorene                              69
  Diethyl phathalate                      ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
NA
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                                          1 ml
                                                                          1
                                Compound                       ug
                                4-Chlorophenyl phenyl ether        ND
                                2-Methyl-4,6-dinitrophenol         ND
                                5-Nitro-o-toluidine                ND
                                Diphenylamine                   ND
                                Diallate                         ND
                                1,3,5-Trinitrobenzene             ND
                                4-Bromophenyl phenyl ether        ND
                                Phenacetin                       ND
                                Hexachlorobenzene               ND
                                4-Aminobiphenyl                 ND
                                Dinoseb                         ND
                                Pentachlorophenol(CCC)          ND
                                Pentachloronitrobenzene          ND
                                Phenanthrene                    72
                                Anthracene                      73
                                Di-n-butyl phthalate              10
                                Isodrin                         ND
                                Fluoranthene(CCC)               75
                                3,3'-Dimethylbenzidine            ND
                                Pyrene                         75
                                Chlorobenzilate                  ND
                                p-Dimethylaminoazobenzene      ND
                                 2-Acetylaminofluorene            ND
                                 Benzyl butyl phthalate            ND
                                 3,3'-Dichlorobenzidine            ND
                                 Benzo(a)anthracene               75
  E = exceeded calib   ND = not detected
                   J = Peak below the calibration range
                NS= not spiked
                                         D-93

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:         Oitimulsion
Sample Name:   M itrix Spike
Lab Sample ID:  9906048
MS Data file:    S9 96048A
Method:        8270
               HRGC/LRMS

Sample Description/Narrative:

Matrix Spike-100 ug Of PAH components only

Compound

Chrysene
di-n-Octyl phthalate!(CCC)
Benzo(b)fluoranthene
7,12-Dimethylbenz(a)anthracene
Benzo(k)fluoranthene
                                              Date Sampled:
                                              Date Extracted:
                                              Date Acquired:
                                              Analyst:
                                              QC reviewer:
                                              Extract Volume
                                              Dilution Factor
                                            NA
                                            06/21/99
                                            06/30/99
                                            Bill Preston
                                            Dennis Tabor
                                                       1 ml
                                                       1
                                     Ug       Compound

                                     75       Benzo(a)pyrene(CCC)
                                     ND       3-Methylcholanthrene
                                     72       Indeno( 1,2,3-cd)pyrene
                                     ND       Dibenz(a,h)anthracene
                                     76       Benzo(ghi)perylene
                                                            77
                                                            ND
                                                            73
                                                            73
                                                            73
  E = exceeded calib
jo.
                    not detected
J = Peak below the calibration range
NS= not spiked
                                          D-94

-------
APPCD Organic Support Laboratory
Semi-Volatile Qrganics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Qrimulsion
 latrix Spike Dup
  06049
  I96049A
  170
   .GC/LRMS
 Sample Descriptioi /Narrative:

 Matrix Spike Duplicate-100 ug of PAH components only
 Pre Extraction Surrogates
 2-Fluorophenol(surr#l)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(sun#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Anthracene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesutfonate
 n-Nitrosodiethylam|ine
 Bis (2-chloroethyi) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
  2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzene(CCC)
  1,2-Dichlorobenzene
  Benzyl Alcohol
  B is(2-chloroisopropy l)ether
  2-Methylphenol
  n-Nitrosospyrrolidine
  Acetophenone
  Hexachloroethane
 Recovery
  NS
  NS
  NS

> Recovery
   47
   53
   78
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
   ND
            Date Sampled:
            Date Extracted:
            Date Acquired:
            Analyst:
            QC reviewer:
            Extract Volume
            Dilution Factor
               NA
               06/21/99
               06/30/99
               Bill Preston
               Dennis Tabor
                     1       ml
                     1
D5-Nitrobenzene(surr#3)
2-Fluorobiphenyl(surr#4)
D 14-Terphenyl(surr#6)
13C6-2.5 Dichlorophenol
13C6-2,5-Phthalate anhydride
                                                              % Recovery
                                                                   NS
                                                                   NS
                                                                   NS

                                                              % Recovery
                                                                   49
                                                                   89
Compound                        MS

4-Methylphenol                   ND
n-Nitrosodi-n-propylamine          ND
Nitrobenzene                     ND
 1-Nitrosopiperidine                ND
Isophorone                       ND
2,4-Dimethylphenol                ND
Bis(2-chloroethoxy)methane         ND
2,4-Dichlorophenol(CCC)           ND
 1,2,4-Trichlorobenzene             ND
 Naphthalene                       50
 2-Nitrophenol(CCC)                ND
 2,6-Dichlorophenol                 ND
 Hexachloropropene                 ND
 4-Chloroaniline                    ND
 Hexachlorobutadiene(CCC)          ND
 n-Nitrosodi-n-butylamine            ND
 4-Chloro-3-methyl-phenol(CCC)      ND
  E = exceeded calib   ND = not detected      J = Peak below the calibration range      NS= not spiked
                                             D-95

-------
APPCD Organic Support Laboratory
Semi-Volatile Qrganics Report
Project:         0rimulsion
Sample Name:   N latrix Spike Dup
Lab Sample ID:  9906049
MS Data file:    S996049A
Method:         8270
                JfRGC/LRMS

Sample Description/Narrative:

Matrix Spike Duplicjate-100 ug of PAH components only
 Compound
 2-Methylnaphthale ne
 Isosafrole
 1,2,4,5-Tetrachlor
-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:    S<
Method:         &
                H
Oiimulsion
M
  atrix Spike Dup
9006049
  96049A
  70
  EIGC/LRMS
 Sample Description/Narrative:
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
 Matrix Spike Duplicate-100 ug of PAH components only

 Compound                           Hg        Compound
NA
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                         1 ml
                                                         1
 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethylbenz(a)anthracene
 Benzo(k)fluoranthene
                      69       Benzo(a)pyrene(CCC)
                      ND       3-Methylcholanthrene
                      67       Indeno(l,2,3-cd)pyrene
                      ND       Dibenz(a,h)anthracene
                      72       Benzo(ghi)perylene
                                                              Mg

                                                              72
                                                              ND
                                                              67
                                                              67
                                                              67
  E = exceeded calib   ND = not detected     J = Peak below the calibration range      NS= not spiked
                                      D-97

-------
APPCD Organic Support Laboratory
Semi-Volatile Organics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
Rfcsin Blank
9906050
S96050A
  ?o
  IGC/LRMS
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/21/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
      1      ml
      1
 Sample Description'Narrative:

 Resin Blank-dl4-T< rphenyl is out of criteria
 Pre Extraction Surrogates
 2-Fluorophenol(surr# 1)
 D5-Phenol(surr#2)
 2,4,6-Tribromophenol(surr#5)

 Pre Sampling Surrogates
 13C6-1.2 Dichlorobenzene
 13C6-Napthalene
 D10-Acenapthalene

 Compound

 n-Nitrosomethylethylamine
 Methyl Methanesulfonate
 n-Nitrosodiethylamine
 Bis (2-chloroethyl) ether
 Ethyl methanesulfonate
 Aniline
 Phenol(CCC)
 2-Chlorophenol
  1,3-Dichlorobenzene
  1,4-Dichlorobenzen)e(CCC)
  1,2-Dichlorobenzen e
  Benzyl Alcohol
  Bis(2-chloroisopropyl)ether
  2-Methylphenol
  n-Nitrosospyrrolidine
  Acetophenone
  Hexachloroethane

  E = exceeded calib    ND = not detected
                     Recovery
                       67     P
                       83     P
                       113    P

                     i Recovery
                       58
                       61
                       87

                       Mg

                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                       ND
                        ND
                        ND
                        ND
                        ND
 D5-Nitrobenzene(surr#3)
 2-Fluorobiphenyl(surr#4)
 D14-Terphenyl(surr#6)
 13C6-2.5 Dichlorophenol
 13C6-2,5-Phthalate anhydride
 Compound

 4-Methylphenol
 n-Nitrosodi-n-propylamine
 Nitrobenzene
 1 -Nitrosopiperidine
 Isophorone
 2,4-Dimethylphenol
 B is(2-chloroethoxy)methane
 2,4-Dichlorophenol(CCC)
 1,2,4-Trichlorobenzene
 Naphthalene
 2-Nitrophenol(CCC)
 2,6-Dichlorophenol
 Hexachloropropene
 4-Chloroaniline
 Hexachlorobutadiene(CCC)
 n-Nitrosodi-n-butylamine
 4-Chloro-3-methyl-phenol(CCC)
                Recovery
                  82     P
                  85     P
                  154    F

               i Recovery
                  59
                  101
                  Mg

                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                  ND
                    J = Peak below the calibration range
                  NS= not spiked
                                        D-98

-------
APPCD Organic Support Laboratory
Semi-Volatile Orgahics Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
Orimulsion
Resin Blank
9906050
S996CJ50A
8270
HRG^/LRMS
                     i
 Sample Description/Narrative:

 Resin Blank-dl4-Terphenjyl is out of criteria

 Compound
 2-Methylnaphthalene                  ND
 Isosafrole                            ND
 1,2,4,5-Tetrachlorobenzene             ND
 Hexachlorocyclopentadiiene(SPCC)      ND
 2,4,6-Trichlorophenol(CCC)            ND
 2,4,5-Trichlorophenol                 ND
 2-Chloronaphthalene                  ND
 1,3 Dinitrobenzene                    ND
 2-Nitroaniline                        ND
 3-Nitroaniline                        ND
 Safrole                              ND
 Acenaphthylene                      ND
 1,4-Naphthoquinone                  ND
 Dimethyl phathalate                  ND
 2,6-Dinitrotoluene                     ND
 Acenaphthene(CCC)                   ND
 1-Napthylamine                       ND
 2-Napthylamine                       ND
 4-Nitroaniline                        ND
 2,4-Dinitrophenol(SPCC)               ND
 Dibenzofuran                         ND
 Pentachlorobenzene                   ND
 2,4-Dinitrotoluene    j                 ND
 2,3,4,6-Tetrachlorophe|nol              ND
 4-Nitrophenol(SPCC)                  ND
 Fluorene                             ND
 Diethyl phathalate                     ND
Date Sampled:
Date Extracted:
Date Acquired:
Analyst:
QC reviewer:
Extract Volume
Dilution Factor
06/21/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                                         1 ml
                                                                         1
                               Compound                      Mg
                               4-Chlorophenyl phenyl ether       ND
                               2-Methyl-4,6-dinitrophenol        ND
                               5-Nitro-o-toluidine               ND
                               Diphenylamine                  ND
                               Diallate                         ND
                                1,3,5-Trinitrobenzene             ND
                               4-Bromophenyl phenyl ether       ND
                               Phenacetin                      ND
                               Hexachlorobenzene               ND
                               4-Amindbiphenyl                ND
                               Dinoseb                        ND
                                Pentachlorophenol(CCC)          ND
                                Pentachloronitrobenzene          ND
                                Phenanthrene                    ND
                                Anthracene                     ND
                                Di-n-butyl phthalate               6
                                Isodrin                         ND
                                Fluoranthene(CCC)              ND
                                3,3'-Dimethylbenzidine           ND
                                Pyrene                         ND
                                Chlorobenzilate                  ND
                                p-Dimethylaminoazobenzene      ND
                                2-Acetylaminofluorene           ND
                                Benzyl butyl phthalate            ND
                                3,3'-Dichlorobenzidine           ND
                                Benzo(a)anthracene              ND
  E = exceeded calib   ND = not detected      J = Peak below the calibration range     NS= not spiked

                                               D-99

-------
APPCD Organic Support Laboratory
Semi-Volatile Of games Report
Project:
Sample Name:
Lab Sample ID:
MS Data file:
Method:
  imulsion
     Blank
  06050
  •96050A
8270
  IGC/LRMS
 Sample Description/Narrative:

 Resin Blank-dl4-Terphenyl is out of criteria

 Compound

 Chrysene
 di-n-Octyl phthalate(CCC)
 Benzo(b)fluoranthene
 7,12-Dimethy lbenz(a)anthracene
 Benzo(k)fluoranthene
            Date Sampled:
            Date Extracted:
            Date Acquired:
            Analyst:
            QC reviewer:
            Extract Volume
            Dilution Factor
06/21/99
06/21/99
06/30/99
Bill Preston
Dennis Tabor
                                                                       1 ml
                                                                       1
                     ug       Compound

                     ND       Benzo(a)pyrene(CCC)
                     ND       3-Methylcholanthrene
                     ND       Indeno(l,2,3-cd)pyrene
                     ND       Dibenz(a,h)anthracene
                     ND       Benzo(ghi)perylene
                                            Mg

                                           ND
                                           ND
                                           ND
                                           ND
                                           ND
  E = exceeded calib
  D = not detected
J = Peak below the calibration range
 NS= not spiked
                                        D-100

-------
          APPENDIX E
Metals Analysis Laboratory Reports
               E-l

-------
   ast$isSs±
                PRISM
                LABORATORIES, INC.
Full Service Analytical & Environmental Solutions
                   !
CASE NARRATIVE
    08/11/99
                                            Main Office:
                                     449 Springbrook Road
                                         P.O. Box 240543
                                  Charlotte, NC 28224-0543
                                      Phone: 704/529-6364
                                          1/800/529-6364
                                       Fax: 704/525-0409
          CLIENT:       ARCADIS Geraghty & Miller
          PROJECT ID:   Orimulsion
          LAB GROUP ID:  8401E24
          SAMPLE ID:    AB34730 - AB34753
            MATRIX:
            NUMBER OF SOURCES:
            DATE COLLECTED:
            DATE RECEIVED.
AIR
12
06/18-7/1/99
07/2/99
          Sample Disposition:

          36 containers were received on 07/2/9911:00 in the laboratory. The samples were received in good
          condition.
: v.ii i^rowReferencei^J^eWir^Soi^boritorvlDs '.i
Sample Field TO k ^ ^
907010942 Train 1 sample 1
907010942 Train 1 sample 2
907010942 Train 1 sample 3
907010943 Train 1 sample 1
907010943 Train 1 sample 2
90701 0943 Train 1 sample 3
90603121 5SMFOBLR6
906031215SMNOBLR
906031215SMIOBLR6
906041303SMFOBLR6
90603121 5SMNOBLR
906031215SMIOBLR6
906071228SMFOBLR6
906071228SMNOBLR
906071226SMIOBLR6
905171200SMFFBL01
905171200SMNFBL01
905171200SMIFBL01
905181 131SMFOBL04
905181 131SMNOBL04
905181131SMIOBL04
905191016SMFOBL04
905191016SMNOBL04
905191016SMIOBL04
90521 1133SMFOBL04
90521 1133SMNOBL04
90521 1133SMIOBL04
IPrism Uaboratorv ID
AB34730
AB34731
AB34732
AB34733
AB34734
AB34735
AB34736
AB34737
AB34738
AB34739
AB34740
AB34741
AB34742
AB34743
AB34744
AB34745
AB34746
AB34747
                                            E-2

-------
. Cross Reference of Field IDs to Laboratory IDs
Sample Field ID
905241201SMFOBL01
905241 201 SMNOBL01
905241201SMIOBL01
905251 142SMFOBL01
905251 142SMNOBL01
905251 142SM1OBL01
905261053SMFOBL01
905261053SMNOBL01
90526 1053SMIOBL01
Prism Laboratory ID
AB34748
AB34749
AB34750
AB34751
AB34752
AB34753
Sample Analysis:

The samples! were analyzed using approved USEPA methodology.

The following test method was utilized for the analysis of the samples:
Analytes
Metals
-.^•••fiM^^'i
•' : .-••iMaito '£ .-J
EPA Method 29
Ketnoai3e«Qription
::.-.A, •:••,.., ,;/-;>>.': :;;;,-':.:;:v::;-:':,;.:;v.^.:.. / -.. . •
Determination of metals emissions from stationary sources.
Analytical Fraction 1A

Samples AB34748, AB34750, AB34752, AB34734, AB34736, AB34738, AB34744 and AB34746,
were analyzed for nickel at a 1:200 dilution due to the high concentration of nickel.

Samples AB34748, AB34750, AB34752, AB34734, AB34736, AB34738, AB34742, AB34744 and
AB34746, were analyzed for vanadium at a 1:200 dilution due to the high 'concentration of vanadium.

Zinc and antimony recoveries for sample AB34748 were outside specified limits, possible matrix
interference suspected.

Zinc recoveijy for sample AB37736 was outside specified limits, possible matrix interference suspected.

The %RSD; md matrix spike recovery for nickel and vanadium on samples AB34748and AB34746 was
not calculated because of the high dilution needed.

The reporting limit standard in position 84 exhibited carry over from the previous samples. However, the
values of the associated samples were greater than 10 times the reporting limit.
 Analytical Fraction 2A

 The matrix Spike recovery for vanadium on sample AB34749 was outside laboratory control limits
 because the spike true value was less than one fifth the sample concentration.
                                     E-3

-------
Nickel and magnesium recoveries for sample AB34747 were outside specified limits, possible matrix
interference suspected.


 If you have any questions concerning this narrative report, please call (704) 529-6364.


PRISM LABORATORIES, INC.
Helmuth M.B. Janssen
Quality Assurajnce Manager
                                     E-A

-------
Lab Report
                                                                   PRISM
                                                                          H* Swvict Anilytctl t EnntMuttMt SAUJ
   7/29/99
   Mr. Dennis Tabor
   ARCAOIS Oeraghty
   2301 Rexwoods Dr.
   Raleigh. NC 27607
& Miller
StelOO
                                     Page 5 of 24
   Customer Project Name: RN 9920100024 00001
      Customer Sample ID: M603121SFILTE
         Priam Sample ID: AB34734
             Login Group: 8401E24
Sample Cottectton Date/Time: 6/3/99
    Lab Submtttai Date/Time: 7/2/99      11:00
  The following analytioal results have been obtained for the indicated cample which was submitted to this laboratory:
TEST
PARAMETER
                              TEST
                              RESULT
   BOMB PREP. FOR METHOD 29      Completed
   BOMB PREP. FOR METHOD 29      Completed
   SAMPLE PREPARATION r-ORMETHO Completed
   ARSENIC BY METHOD 29
   ANTIMONY BYMETH0028
   BERYUIUM BY METHOD 29
   CADMIUM BY METHOD fe>
   COPPER BY METHOD 29
   CHROMIUM BY METHOD 29
   IRON BY METHOD 29
   MANGANESE BY METHOD 29
   MAGNESIUM BY METH >0 29
   ZINC BY METHOD 29
   VANADIUM BY METHOOM
   NICKEL 8Y METHOD 29

    Sample Comments:
     RN 992010.0024.00001
                                         UNITS
                             UDL
                                     METHOD
                                     REFERENCE
                             DATE/TIME
                             STARTED
                             7/7/99 Oa.-00
                             7/7/99 ie«0
Completed
9.1
20
11
7.0
63
18
3000
30
210
760
29000
MOO

ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug

2.0
2.0
2.0
2.0
2.0
2.0
20
2.0
20
2.0
400
400
Method 29
Method 29
Method 29
Method 29
Method 2B
Method 29
Method 29
Met»d29
Method 29
Meted 29
Meted 26
Method 29
Method 29
7/8/9906:00
7/12/99 08:00
7/12/9908:00
7/12/9908:00
7/12/9908:00
7/12/99 06:00
7/12/9908:00
7/12/9908:00
7/12/9908:00
7/12/99 08:00
7/12/9906:00
7/12799 08:00
7/12/9908:00
ANALYST
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
     Angela D. Overcaih. V.P. Laboratory Services
                                                E-5

-------
Lab Report
                                                               PRISM
                                                               LABORATORIES, INC.
                                                                        Fill gftminl Amtylicil-1, Friv n.ui.i
   7/29/99
   Mr. Dennis Tabor
   ARCADISGeraghtyllflller
   23Q1 Rexwoods Dr. Ste 100
   Raleigh, NC 27607
                                                        Page 6 of 24
                      Customer Project Nime: RN 992010.0024.00001
                         Customer Sample ID: MM3121S
                            Prism Sample ID: AB34735
                                 Login Group: B401E24
                    Sample CoHectkm Date/Time: 6/3/99
                       Lab Submhtal Date/Time: 7/2/99      11:00
   The following analytical
results have been obtained far the Indicated sample *fcich was submitted to this laboratory.
   TEST
   PARAMETER
   CAMPLE PREPARATION FQ* METHO
   ARSENIC BY METHOD 29
   ANTIMONY BY METHOD 26
   BERYLLIUM BY METHOD 2 3
   CADMIUM BY METHOD 29
    COPPER BY METHOD 28
    CHROMIUM BY METHOD 38
    IRON BY METHOD 29
    MANGANESE BY METHOt) 2ft
    MAGNESIUM BY METHOD 29
    NICKEL BY METHOD 29
    VANADIUM BY METHOD 39
    ZINC BY METHOD 29
     Sample Comments:
      RN 992010.0024
TEST
RESULT
Completed
Lenten
6.4
1.7
Leu then
16
3.6
400
6J5
110
630
3200
150
UNITS

US
UO
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
MDL

1.6
14
1J5
1.5
\£
1.6
16
1.6
16
1.6
1.6
1.S
METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 2B
Method 29
Method 29
Method 28
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/98 06:00
7/12/8906:00
7/12/9908:00
7/12/99 06:00
7/12J99 06:00
7/12/8008:00
7/12*908:00
7/12/9908:00
7/12/9906:00
7/12M 06:00
7/12^9 06flO
7/12*906:00
7/12*906:00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
      Angela D. Overoash. V.P. Laboratory Services
                                               E-6

-------
Lab Report
                                           PRISM
                                           UWORATOfUEl, tkO.
                                                                        KM StMM AfttyflCti» Ciwiiam
   7/29/99
   Mr. Dennis Tabor
   ARCADISGeraghty&MMer
   2301 Rexwoods Dr. Ste 100
   Raleigh. NC 27607
                                    Page 7 of 24
   Customer Project Name: RN 992010.0024.00001
     Customer Sample ID: W6041303HLTE
         Prt*m Sample ID: AB347S6
             Login Group: 8401E24
Sample CoHadion Dale/Time: 6/4/99
   Lab Submtttal Data/Time: 7/2799      11:00
   The following analytical results have been obtained for the Indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   BOMB PREP. FOR METHOD 29
   BOMB PREP. FOR METHOD 29
   SAMPLE PREPARATION FOR METHp
   ARSENIC BY METHOD 29
   ANTIMONY BY METHOD 29
   BERYLLIUM BY METHOD 29
   CADMIUM BY METHOD 2f
   COPPER BY METHOD 29
   CHROMIUM BY METHOD 29
   IRON BY METHOD 29
   MANGANESE BY METHOD 29
   MAGNESIUM BV METHOD 29
    ZINC BY METHOD 29
    VANADIUM BY METHOD 29
    NICKEL BY METHOD 29

     Sample Comments:
      RN 992010.0024.00001
TEST
RESULT
Completed
Completed
Completed
9.1
32
20
0.0
70
30
4600
42
69
1000
46000
MOO

UNITS



ug
UQ
ug
KB
ug
ug
ug
ug
ug
ug
ug
ug

MDL



24
2.0
2.0
2.0
2.0
2.0
20
2.0
20
2.0
400
400
METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 2fi
Method 29
• Method 29
Method 29
Method 29
Method 29
Method 29
MeewdZO
OATETIME
STARTED
7/7/99 1600
7/7/99 08*0
7/679908:00
7/12^908:00
7/1 2/99 08:00
7/12/99 08:00
7/12/9606:00
7/12/W 08:00
7/12/99 08:00
7/12/9908:00
T/12/99 00:00
7/12*9 08:00
7/12/9908:00
r/12/99 08:00
7/12MO 08:00

ANALYST
DHJ
DHJ
DHJ
OKI
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
OHJ
      Angela D. Overcash. V.P. Laboratory Services
                                                    E-7

-------
Lab Report
                                            PRISM
                                                                                      lA»QftATOMGC. IMC.

                                                                          Ful S*Mo* ArJiyumtK fcnvnnnwtiui Sourion
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraflhty & Miller
   2301 Rexwoods Dr. Ste 100
    Raleigh, NC 27607
                                    Page 8 of 24
  Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  MM41303
         Prism Sample ID:  AB34737
             Login Group:  8401E24
Sample Collection Date/Time:  6/4/99
    Lab SubmHtal Date/Time.  7/2/99     11:00
   The following analytical result* have been obtained for the Indicated sample which was Emitted to this laboratory:
TEST TEST
PARAMETER RESULT
ZINC BY METHOD 29 »•'
VANADIUK W METHODS* 21
NICKEL BY METHOO 29 Let* than
MAGNESIUM BY METHOD 29 Le«« than
MANGANESE BY METHOO 29 U« than
IRON BY METHOD 29 30
CHROMIUM BY METHOD 29 i-0
COPPER BY METHOD 29 3-0
CADMIUM BY METHOD 211 3.0
BERYLLIUM BY METHOD 29 L*«man
ANTIMONY BY METHOD 29 Lw.llwn
ARSENIC BY METHOO 29 Lew than
SAMPLE PREPARATION TORMfTHO Completed
UNITS
UO
ug
ug
ug
ug
UQ
ug
ug
ug
ug
ug
ug
MOt
\£
1.6
1.5
15
1.9
16
1.6
1.5
1.S
14
1.5
1.S
METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/12/99 06:00
7/12/89 08:00
7/12/990600
7/12/9908.00
7/28/99 14:47
7/12/9906:00
7/12/9906:00
7/26/99 14:47
7/26/99 14:47
7/26/09 U:47
7126m 14:47
7/26/99 14:47
7/7/9906:00
ANALYST
DHJ
DHJ
DHJ
DHJ
OKI
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
     Sample Comments:
      RN 992010.0024.00001
       Angela 0. Overcash. V.P. Laboratory Services
                                                       E-8

-------
ab Report
                                             PRISM
                                                                                             , INC.
                                                                        Ful £*rv«* And/lie* * fcnvironmtna: S«ui
76
9.6
16
3D
716

ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug

2.0
400
400
20
2.0
20
2.0
2.0
2.0
2.0
2.0
2.0
rTHO Completed

Method 29
Method 29
Method 29
Method 29
Method 29
M«thod29
Ma(hod29
Method 29
Method 29
Method 29
Mathod29
M«lhod29
Method 20
DATE/TIME
STARTED
7/7/99 16:00
7/7/99 08:00
7/12/99 08:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08 :OQ
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
r/B/08 08:00

ANALYST
DHJ
OHJ
DHJ
DHJ
OHJ
DHJ
OHJ
DHJ
OHJ
DHJ
OHJ
DHJ
DHJ
DHJ
OHJ
   Angela D. Overcash. V.P. Labors tory Services
                                                    E-9

-------
Lab Report
                                                                         PRISM
                                                                         LABORATORIES. IMC.
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwoods Dr. Ste 100
   Raleigh, NC 27607
                                                                  Page 10 of 24
                                Customer Project Name:  RN 992010.0024.00001
                                   Customer Sample ID:  906071228
                                      Prlwn Sample ID:  AB34739
                                          Login Group:  8401E24
                             Sample Collection Dale/Time:  6/7/99
                                 Lab Submittal Dateffime:  7/2/99     11:00
  The following analytic^ results have been obtained for the Indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   ZINC BY METHOD 29
   VANADIUM BY METHOD 29
   NICKEL BY METHOD 29
   MAGNESIUM BY METHOD 29
   MANGANESE BY METHOO 29
   IRON BY METHOD 29
   CHROMIUM BY METHOD 29
   COPPER BY METHOD 29
   CADMIUM BY METHOD 2J-
   BERYLLIUM BY METHOD 29
   ANTIMONY BY METHOD 29
   ARSENIC BY METHOD 29
   SAMPLE PREPARATION TOR Mf THO

    Sample Comments:
     RN 992010.0024.00001
TEST
RESULT
9.4
6.7
Less than
Lets than
Lace than
20
Less than
2.4
Less than
Less than
1.7
Less than
3 CompUWd

UNITS
og
UQ
ug
ug
UQ
ug
ug
ug
ug
ug
ug
ug


MOL
1.5
1.5
1.5
15
1.5
15
1.5
1.5
1.5
1.5
1.5
1.5

METHOD
REFERENCE
Method 29
Mathod29
Method 29
Method 2B
Method 29
Method 29
Method 2S
Method 25
Method 29
Method 29
Method 2S
Method 29
Method 26
DATE/TIME
STARTED
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/0908:00
7(12/99 14:47
7/12/99 08:00
7/12/99 08:00
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/7/9908:00

ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
/\
. OverealTi. V.P.
                          Laboratory Services
                                                  E-10

-------
Lab Report
                                                          PRISM
                                                                          Fun StMC* Arjlytietl ( fcnwonratrui Sourjoni
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geragnty & Miller
   2301 Rexwoods Or. Ste 100
   Raleigh. NC 27607
  The following analytical results r ave been obtained for the indicated sample which was submitted to this laboratory:
                                                  Page 11 of 24
                Customer Project Name: RN 992010.0024.00001
                   Customer Sample ID: 905271200FILTE
                      Prism Sample ID: AB34740
                           Login Group: 6401E24
              Sample Collection Date/Time: 5/27/99
                 Lab Submittal Date/Time: 7/2/99     11:00
  TEST
  PARAMETER
  BOMB PREP. FOR METHOD 29
  BOMB PREP. FOR METHOD 29
  ZINC BY METHOD 29
  VANADIUM BY METHOD 2fl
  NlCKEt BY METHOD 29
  MAGNESIUM BY METHOD 29
  MANGANESE BY METHOD 23
   IRON BY METHOD 25
   CHROMIUM BY METHOD 29
   COPPER BY METHOD 29
   CADMIUM BY METHOD 29
   BERYLLIUM BY METHOD 29
   ANTIMONY BY METHOD 29
   ARSENIC BY METHOD 29
   SAMPLE PREPARATION FOR METHO

    Sample Comments:
     RN 992010.0024.00001
TEST
RESULT
Completed
Completed
7.5
12
Less than
Less than
2.0
33
Leas than
2.0
6.8
Less than
Less than
Less than
> Completed
UNITS


Ufl
ug
ug
ug
ug
ug
"0
ug
UO
ug
ug
ug

MDL


2.0
2.0
2.0
20
2.0
20
2.0
2.0
2.0
2.0
2.0
2.0

METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 26
Melhod29
Method 29
Method 29
DATE/TIME
STARTED
7/7/99 16.00
7/7/99 08:00
7/12/99 08:00
7M2/99 08:00
7/12/99 08:00
7/12/99 Ofi:00
7/12/99 08:00
7/12/99 08:00
7/12/9908:00
7/12/9908:00
7/12/99 08:00
7/12/99 08.00
7/12/9006:00
7/12/9908:00
7/8/9903:00
ANALYST
OHJ
DHJ
OHJ
DHJ
DHJ
UHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
     Angela D. Overcash, V.P. La
toratory Services
                                                     E-ll

-------
ab  Report
                                             PRISM
                                            LMO*ATO*ttS.INC.
                                                                        Ful Swvic* Analytical & Environmental
 7/29/99
 Mr. Dennis Tabor
 ARCADIS Oeraghty & Miller
 2301 Rexwoods Dr. Ste 100
 Raleigh. NC 27607
                                     Page 12 of 24
  Customer Project Name: RN 992010.0024.00001
     Customer Sample ID: 905271200
         Pfi«m Sample ID: AB34741
             Login Group: 8401E24
Sample Collection Date/Time: 5/27/99
   Lab Submittal Date/Time: 7/2/99      11:00
The following analytical results have been obtained for the Indicated sample which was submitted to Ihis laboratory:
 TEST
 PARAMETER
 ZINC BY METHOD 29
 VANADIUM BY METHOD ?9
 NICKEL BY METHOD 29
 MAGNESIUM BY METHOO 29
 MANGANESE BY METHOO 29
 IRON BY METHOD 29
 CHROMIUM BY METHOD 28
 COPPER BY METHOD 29
 CADMIUM BY METHOD 29
 BERYLLIUM BY METHOD 29
 ANTIMONY  BY METHOD 29
 ARSENIC BY METHOD 26
 SAMPLE PREPARATION *OR METHO

  Sample Comments:
   RN 992010.0024.00001
TBCT
RtSULT
1*
214
Less than
23
1.6
20
Less than
7.3
2.0
L*ts than
20
Less than
D Completed
UNITS
ug
ug
ug
ug
ug
ug
ug
ug
«9
ug
Ufl
ug

MOL
1.8
1.5
1.5
15
1.6
15
1.5
1.5
1.5
1.5
1.5
1.5

METHOO
REFERENCE
Method 29
Method 20
Method 20
Method 29
Method 29
Method 28
Mathod 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 U:<7
7/12/99 08:00
7/12/99 08:00
7/12/99 14:47
7/12/99 t<:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/7/9908.00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
   Angela D- Overcast). V.P. Laboratory Services
                                                   E-12

-------
Lab Report
                                             PRISM
                                             L*BORATOWE«,|NC.
                                                                          Ful Swvioa Aiuilytisil t EtMronmtnlai VMons
   7/29/99

   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwood* Or. Ste 100
   Raleigh, NC 27607
                                     Page 13 of 24
   Customer Project Name RN 992010.0024.00001
     Customer Sample ID: 905181131FILTE
         Prism Sample ID: AB34742
              Login Group: 8401E24
Sample Collection Date/Time: 6/18/99
    Lab Submftlai Data/Time: 7/2/99      11:00
  The following analytical results have been obtained for the indicated sample which was submitted to this laboratory:
TEST
PARAMETER
"BOMB PREP. FOR METHOD »
BOMB PREP. FOR METHOD 29
ZINC BY METHOD 28
VANADIUM BY METHOD 29
NICKEL BY METHOD 29
MAGNESIUM BY METHOD 29
MANGANESE BY METHOD 29
IRON BY METHOD 29
CHROMIUM BY METHOD 29
COPPER BY METHOD 29
CADMIUM BY METHOD 29
BERYLLIUM BY METHOD 29
ANTIMONY BY METHOD 29
ARSENIC BY METHOD 29
TEST
RESULT
Completed
Compiled
Lest thin
WW9
13000
2100
20
43
12
8.5
63
24
Loss than
6.3
UNITS


Ufl
HO
Ufl
ug
ug
uo
ug
ug
ug
ug
ug
ug
MDL


2.0
400
400
20
2.0
20
2.0
2.0
2.0
2.0
2.0
2.0
SAMPLE PREPARATION FOR METHO Completed
METHOD
REFERENCE


Method 29
MfltlWlTA
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
717199 16:00
7/7/9906:00
7/12/9908:00
TflWM (W 00
7/12/99 08:00
7M2/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/6/9908:00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DH.I
    Sample Comments:
    RN 992010.0024.00001
    Angela D. Overcash, V.P. Laboratory Services
                                                     E-13

-------
Lab Report
                                             PRISM
                                                                                       l*»OlMTMIEt.lNC.

                                                                          hit Saniaf Analytic*! » tnvift.«in,tnjl S»utioits
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Oeraghly & Mille
   2301 Rexwoods Dr. Ste
   Raleigh. NC 27607
                                     Page 14 of 24
   Customer Project Name: RN 992010.0024.00001
     Customer Stmplt ID: 905181131
         Priam Sample ID: AB34743
              Login Group: 8401E24
Sample Collection DateflTme: 5/18/99
    Lab Submlttal Date/Time: 7/2/99      11:00
   The following analytical results have been obtained for the Indicated sample \«hlch was submitted to this laboratory:
   PARAMETER__
   SAMPLE'PREPARATION FOR M8THO
   ARSENIC BY METHOD 29
   ANTIMONY BY METHOD 29
   BERYLLIUM BY METHOD 29
   CADMIUM 8Y METHOD 29
   COPPER BY METHOD 29
   CHROMIUM BY METHOD 29
   IRON BY METHOD 29
   MANGANESE BY METHOD 29
   MAGNESIUM BY METHOD 29
   NICKEL BY METHOD 29
   VANADIUM BY METHOD »
   ZINC BY METHOD 29

    Sample Comments.
     RN 992010.0024.00001
TEST
RESULT
n»O Completed
LMtthtn
LMSthtn
Less than
Lettlton
4.6
Less than
26
Less than
Ussthan
Lest than
Less than
8.1

UNITS

ug
ug
ug
ug
ug
ug
ug
"9
ug
ug
ug
"0

MDL

1.5
1.6
1.5
1.5
1.5
1.S
18
1-5
15
1.5
1.6
1.S
METHOD
REFERENCE
Method 29
M«thod29
Method 29
Method 29
M«lhod29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/9908:00
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 08:00
7/12/990840
7/12/99 14:47
7/12/9008:00
7/12/9908:00
7/12/9908:00
7/12/9908:00

ANALYST
DHJ
OHJ
DHJ
OHJ
OHJ
DHJ
OHJ
OHJ
DHJ
DHJ
DHJ
DHJ
DHJ
     Angela D. Overcash, V.P. Laboratory Services
                                                     E-1A

-------
Lab Report
                                                                                    PRISM
                                                                                      lABOHATOWEt.lNC.

                                                                         F.* Sow* Antiyocti « FmrfnxtnMUl Soiuifen,
                                                                            Page 15 of 24
                                          Customer Project Name: RN 992010.0024.00001
                                             Customer Sample ID: 80'51B1016FILTE
                                                Pritm Simple ID: AB34744
                                                     Login Group: 8401E24
                                        SampledoaectionDate/lime: 5/19/99
                                           Lab Submfttal Date/Time: 7/2/99      11:00
The following analytical results have been obtained for the indicated sample which was submitted to this laboratory:
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Oeraghty & Miller
   2301 Rexwoods Or. Ste 100
         , NC
  TEST
  PARAMETER
  BOMB PREP. FOR METHOD 20
  BOMB PREP. FOR METHOD 29
  SAMPLE PREPARATION FOR METHO
  ARSENIC BY METHOD 29
  ANTIMONY BY METHOD 29
  BERYLUUM BY METHOD 29
  CADMIUM BY METHOD 20
  COPPER BY METHOD 28
  CHROMIUM BY METHOD 29
  IRON BY METHOD 29
  MANGANESE BY METHOD 29
  MAGNESIUM BY METHOD 29
  NICKEL BY METHOD 29
  VANADIUM BY METHOD 29
  ZINC BY METHOD 29

   Sample Comments
    RN 992010 0024.00001
TEST
RESULT
Completed
Completed
Completed
0.4
Last than
29
8.2
17
22
26
22
4700
15000
67000
2.0
UNITS



"9
ug
ug
ug
ug
ug
ug
ug
ug
UQ
ug
ug
MDL



2.0
2.0
2.0
2.0
2.0
2.0
20
2.0
20
400
400
2.0
METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/0908:00
7/7/99 18:00
7/8/9908:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/98 08:00
7/12/9908:00
7/12/96 08:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/9908:00
7/12/99 08:00
7M2/99 08:00
ANALYST
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
    Angela D.
                 sh. V.P. Laboratory Services
                                                     E-15

-------
_ab  Report
                                                PRISM
                                                                                           LUOIUTORIIC. INO.

                                                                              Fit doraiM Anilyictt ft Envii»-ini«nul Solution!
  7/29/99
  Mr. Dennis Tabor
  ARCADIS Oeraghty ft Miller
  2301 Rexwoods Or, Ste 100
  Raleigh, NC 27607
                                       Page 16 of 24
   Customer Project Name:  RN 992010.0024.00001
      Customer Sample ID:  «051«1016
         Prism Sample ID:  AJW4745
              Login Group:  8401E24
Sample Collection Date/Time:  6/19/99
    Lab Submittal DateH-ime:  7/2/99      11:00
  The following analytical results hav » been obtained for the indicated sample which was submitted to this laboratory.
TEST                         T -6T
PARAMETER                   RESULT      UNrr8
SAMPLE PREPARATION FOR METHO  I Completed
ARSENIC BY METHOD»           I eii than     ug
ANTIMONY BY METHOD 28         11.0         UQ
BERYLUUM BY METHOD 29         I JBM than     ug
CADMIUM BY METHOD 20          AM then     ug
COPPER BY METHOD 29           N.7         Ufl
CHROMIUM BY METHOD 29         Uttthan     ug
IRON BY METHOD 29             44         ug
MANGANESE BY METHOD 29       UwtlWi     ug
 MAGNESIUM BY METHOD 29       220        Ufl
 NICKEL BY METHOD 29           220        ug
 VANADIUM BY METHOD 29         1100        UQ
 ZINC BY METHOD 29             7.3         ug
   Sample Comments:
    RN 992010.0024.1
                                                    1.S
                                                    1.6
                                                    1.5
                                                    1.5
                                                    1.5
                                                    15
                                                    1.5
                                                    15
                                                    1.6
                                                    1.5
                                                    1.5
                METHOD
                REFERENCE
                hUtho029
                Method 29
                Method 20
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
                Method 29
DATE/TIME
STARTED
7/7/9908:00
7/12/M 14:47
7/12/9914:47
7/12/9914:47
7/12/86 14:47
7/12/B914:47
7/12/9906:00
7/12/9906:00
7/12/9914:47
7/12/9906:00
7/12/9908:00
7/12/990*00
7/12/99 06:00
ANALYST
 DHJ
 DHJ
 DHJ
 DHJ
 OHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 DHJ
 OHJ
    Angela D. Overcash. V.P. Laboratory Services
                                                           E-16

-------
Lab Report
                                            PRISM
                                                                                     LUOAATMIM. INC.

                                                                         Fun Stiwra Analytical & tnvircnnuifUiil Soluhor*
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwoods Or. Ste 100
   Raleigh, NC 27607
                                    Page 17 of 24
   Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  906211133FILTE
         Prtwn Sample ID:  AB34746
             Login Group:  8401E24
Sample Cotectton Date/Time:  5/21/9B
   Ub SubmHtal Datefllme:  7/2/99     11:00
  The following analytical results have been obtained for the Indicated sample which was submitted to this laboratory.
  TEST
  PARAMETER
  BOMB PREP. FOR METHOD 29
  BOMB PREP. FOR METHOD 29
  SAMPLE PREPARATION FOR METHO
  ARSENIC BY METHOD 29
  ANTIMONY  BY METHOD 29
  BERYLLIUM BY METHOD 29
  CADMIUM BY METHOD »l
  COPPER BY METHOD 29
  CHROMIUM BY METHOD 29
   IRON BY METHOD 2fi
   MANGANESE BY METHOD 29
   MAGNESIUM BY METHOD 29
   NICKEL BY METHOD 29
   VANADIUM BY METHOD 29
   ZINC BY METHOD 29

    Sample Comments:
    RN 992010.0024.00001
TEST
RESULT
Completed
Completed
Completed
1?
LeMthan
31
7.9
15
45
96
35
4900
16000
74000
89
UNITS



ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
Ug
ug
MDL



2.0
2.0
2.0
2.0
2.0
2.0
20
2.0
20
400
400
2.0
METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/9908:00
717190 16:00
7/6/99 06:00
7/12/990800
7M2/99 06:00
7/12/99 08.00
7/12/9906:00
7/12/9906:00
7/12/9908:00
7/12/9906:00
7/12/9908:00
7M2/99 06:00
7/12/99 08:00
7/12799 06:00
7/12/9906:00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
     Angela 0. Overcash. V.P. Laboratory Services
                                                       E-17

-------
Lab Report
                                            PRISM
                                                                                     UUKmATOftlES.tHC.

                                                                         f\M S*me* Amtyfcil & Eftyi-aniWJiSaluic.nl
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Oeraghty & Miller
   2301 Rexwoods Dr, Ste 100
   Raleigh, NC 27607
                                    Page 18 of 24
  Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  «0521«33
         Prism Sample ID:  AB34747
             Login Group:  8401E24
Sample Collection Date/Time:  5/21/99
   Lab Submittal Date/Time:  7/2/99
11:00
   The following analytical results have been obtained for the Indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   SAMPLE PREPARATION FOR METH<|
   ARSENIC BY METHOD 29        '
   ANTIMONY BY METHOD 29
   BERYLLIUM BY METHOD 29
   CADMIUM BY METHOD 29
   COPPER BY METHOD 29
   CHROMIUM BY METHOD 29
    IRON BY METHOD 29
    MANGANESE BY METHOD 29
    MAGNESIUM BY METHOD 29
    NICKEL BY METHOD 29
    VANADIUM BY METHOD 29
    ZINC BY METHOD 29

     Sample Comments:
      RN 992010.0024.00001
TEST
RESULT
Completed
Lass than
Less than
Less than
Lew than
Less than
tewuwn
27
Less than
Less than
2.0
3.2
19
UNITS

ug
ug
ug
Ufl
ug
ug
ug
ug
ug
ug
ug
ug
MDL

1.6
1.8
1.5
t.6
1.5
1.5
15
1.5
15
1.5
1.8
.••••
METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Metnod29
Method 29
Msthod29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/99 08:00
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/99 14:47
7/12/9908:00
7/12/99 08:00
7/12/99 14:47
7/12/99 08:00
7/12/99 08 :00
7/12/9908:00
7/12/9908:00
ANALYST
OHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
      Angela D. Overcash. V.P. U boratory Services
                                                      E-18

-------
Lab Report
                                            PRISM
                                            LMOHMOMEt, INC.
                                                                         FuH Sf mo* AnHytital t Environmtnw Sotuuont
   7/29/99
   Mr. Dennis Tabor
   ARCAOIS Geraghty & Miller
   2301 Rexwoods Dr. Ste 100
   Raleigh. NC 27607
                                     Page 19 of 24
   Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  9052*120lrUTE
         Prism Sample ID:  AB3474B
             Login Group:  &401E24
Sample Collection Date/Time:  6/24/99
   Lab Submittal Date/Time:  7/2/99     11:00
   The following analytical results have been obtained for the indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   BOMB PREP. FOR METHOD 29
   BOMB PREP. FOR METHOD 29
   SAMPLE PREPARATION FOR METHO
   Af ..SENIC BY METHOD 29
   ANTIMONY BY METHOD 28
   BERYLLIUM BY METHOD M
   CADMIUM BY METHOD 29
   COPPER BY METHOD 29
   CHROMIUM BY METHOD 29
   IRON BY METHOD 29
   MANGANESE BY METHOD 29
   MAGNESIUM BY METHOD 29
   NICKEL BY METHOD 26
   VANADIUM BY METHOD 29
   ZINC BY METHOD 29

     Sample Comments:
     RN 992010.0024.00001
TEST
RESULT
Completed
Completed
Completed
10
Lass than
23
6.6
17
8.2
69
19
1500
16000
60000
Less than

UNITS



ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
UQ


MOL



2.0
2.0
0.01
2.0
2.0
2.0
20
2.0
20
400
400
2.0
METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/9908:00
7/7/99 10:00
7/8/99 06:00
7/12/99 08:00
7/12/BO 08:00
7/12/99 06:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7/12/99 08:00
7(12/9908:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/9908:00

ANALYST
DHJ
OHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
      Angela D. Overcash. V.P. Laboratory Services
                                                    E-19

-------
Lab Report
                                            PRISM
                                                                                      LABORATORIES, INC


                                                                         Ful 6«viM Anilyik»l I Enwwjugnial &*,(<„
    7/29/99

    Mr. Dennis Tabor
    ARCADIS Geraghty & Miller
    2301 Rexwoods Dr. Ste 100
    Raleigh, NC 27607
                                     Page 20 of 24
  Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  905241201
         Prism Sample ID:  AB34749
             Login Group:  8401E24
Sample Collection Dale/Time:  5/24/99
   Lab Submittal Dateffime:  7/2/99     11:00
   The following analytic*! results have been obtained for the indicated sample which was submitted to this laboratory:
TEST
PARAMETER
SAMPLE PREPARATION FOR METHO
ARSENIC BY METHOD 29
ANTIMONY BY METHOD 29
BERYU.I" 'M BY METHOD 29
CADMIUM BY METHOD 2H
COPPER BY METHOD 2«
CHROMIUM BY METHOD 29
IRON BY METHOD 29
MANGANESE BY METHOD 29
MAGNESIUM BY METHOll 29
NICKEL BY METTOD 29
VANADIUM BY METHOD 29
ZINC BY METHOD 29
TEST
RESULT
Completed
Lectthan
Lest than
1.8
Let»th»n
4.6
2.4
too
2,2
3000
700
3400
11
UNITS

ug
ug
ug
ug
ug
ug
ug
ug
«9
ug
ug
ug
MOL

1.5
1-5
1.5
1.5
1.6
1.5
15
1.5
15
1.5
1-5
1.5
METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 28
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/7/9906:00
7/12/9908:00
7/129908:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
7/12/99 06.-00
7/12/99 08.00
7/12/99 0800
7/12/99 08:00
ANALYST
DHJ
OHJ
DHJ
DHJ
OHJ
DHJ
OHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
     Sample Comments:
      RN 992010.0024.00001
      Angela D. Overcash. V.P. Laboratory Services
                                                      E-20

-------
Lab Report
                                                                                   PRISM
                                                                                      uwoMToniEa, INC.

                                                                         fiM Scrvn* Analytic*! & Envjronmtntil Sohmoat
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Mller
   2301 Rexwoods Or, Sle 100
    Raleigh. NC 27607
                                                                            Page 21 of 24
                                          Customer Project Name: RN 992010.0024.00001
                                             Customer Sample ID: M525l142FILTe
                                                Prism Sample 10: AB34750
                                                     Login Group: 8401E24
                                       Sample CoBedtonDate/Tlme: 6/26/99       _
                                           Lab Submlttal DatefTlme: 7/2/99     11:00
                  lytical results hi we been obtained for the Indicated sample which
The following analy
   TEST
   PARAMETER
   BOMB PREP. FOR METHOD 29
   BOMB PREP. FOR METHOD 29
   ZINC BY METHOD 29
   VANADIUM BY METHOD 29
    NICKEL BY METHOD 29
    MAGNESIUM BY METHOD 29
    MANGANESE BY METHOD 29
    IRON BY METHOD 29
    CHROMIUM BY METHOD 20
    COPPER BY METHOD 29
    CADMIUM BY METHOD 29
     BERYU-IUM BY METHOD 29
     ANTIMONY BY METHOD 29
     ARSENIC BY METHOD 29
     SAMPLE PREPARATION FOR METHO Completed
      Sample Comments
       RN 992010.0024
                                                                  was submitted to this laboratory.
TEST
RESULT

Completed

Completed
Lett than
62000
15000
2300
*%n
20
43
8.9
Lett than
7.1
23
LMiUun
6.8
in f-MitdalBri
UNITS



m
ug
uo
"9
i M
uy
UO
ug
ug
ug
ug
ug
ug

MDL



2.0
400
400
20
2.0

20
2.0
2.0
2.0
0.01
2.0
2.0

METHOD
REFERENCE



Method 29
Method 29
Method 29
Method 29
Method »

Method 29
Method 29
Method 29
Method 29
Method 29
Method 28
Method 29
Method 29
DATE/TIME
STARTED
7/W98 16:00

7/7/8908:00
7/12»9 08:00
7/12N9 08OO
7/12/99 OCflO
7/12S9 08.00
7/12/8908:00

7/12W9 06:00
7/12^9 08.00
7/12A9 08:00
7/12»9 08.00
7/12^908:00
7f 12/99 08:00
7/12«9 08:00
7/6«SOflK)0
ANALYST
DHJ

DHJ
DHJ
DHJ
DHJ
DHJ
DHJ

DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
DHJ
DHJ
       Angela D. Overcash. V.P. Laboratory Services
                                                       E-21

-------
Lab Report
                                            PRISM
                                                                                      LABOJUTOMEI, INC.

                                                                         hM Swvc* AnslyKtl 4. Enwrornwnai Solution*
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwoods Dr. Ste 100
   Raleigh. NC 27607
                                     Page 22 of 24
   Customer Project Name:  RN 992010.0024.00001
     Customer Sample ID:  905251142
         Prism Sample ID:  AB34751
             Login Group:  S401E24
Sampte Collection Date^Tlme:  6/25/99
    Lab Submtttal DateTTIme:  7/2/99     11:00
   The following analytical result* have been obtained for the Indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   ZINC BY METHOD 29
   VANADIUM BY METHOD 29
   NICKEL BY METHOD 29
   MAGNESIUM BY METHOD 29
   MANGANESE BY METHOD 29
   IRON BY METHOD 29
   CHROMIUM BY METHOD 29
   COPPER dY METHOD 29
   CADMIUM BY METHOD 29
   BERYLLIUM BY METHOD 29
   ANTIMONY BY METHOD 29
   ARSENIC BY METHOD 29
   SAMPLE PREPARATION FOR METHO

    Sample Comments:
     RN 992010.0024.00001
TEST
RESULT
IS
14
44
27
18
42
3.0
2.9
4.0
Ue»«m>n
Le«» then
l£M ton
3 COfflDi6t0d

UNITS
Ofl
UO
ug
ug
UQ
ug
ug
ug
ug
ug
ug
ug


MDL
1.6
1*
1.5
15
1.S
15
1.6
1.8
1.5
1.6
1.5
1.5

METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
7/12/99 08:00
7/12/9908:00
7/12/99 08:00
7/12/99 08:00
-7/12/9908:00
7M2/99 08:00
7/12/99 08:00
7/12/M 08:00
7/12/9B 08:00
7/12/99 08:00
7/12/9908:00
7/12/9908:00
7/7/9908:00

ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
     Angela D. Dvercesh, V.P. Laboratory Services
                                                     E-22

-------
Lab Report
                                                                               11^^ m»oRATOme«, INC.

                                                                          Fat &m
-------
Lab Report
                                            PRISM
                                                                                     kMOAATOniEt, INC.

                                                                         Ft* S«cn* AitttytWd A Ertvuanffltr.iftl Sotufconi
   7/29/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwoods Dr. Ste 100
   Raleigh. NC 27607
                                     Page 24 of 24
   Customer Project Name: RN 992010.0024.00001
     Customer Sample ID: S05281053
         Prism Sample ID: AB34753
             Login Group: 8401E24
Sample Collection Date/Time: 6/26/99
   Lab SubmHtal Date/Time: 7/2/99     11:00
   The following analytical results have been obtained tor the Indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
   ZINC BY METHOD 29
   VANADIUM BY METHOD 29
   NICKEL BY METHOD 29
   MAGNE5IU* 3Y METHOD 29
   MANGANESE BY METHOD 2fl
   IRON BY METHOD 29
   CHROMIUM BY METHOD 29
   COPPER BY METHOD 29
   CADMIUM BY METHOD 26
   BERYLLIUM BV METHOD 29
   ANTIMONY BY METHOD 29
   ARSENIC BY METHOD 29
    SAMPLE PREPARATION FOR METHO

     Sample Comments:
     RN 992010.0024.00001
TEST
RESULT
14
3.4
1.S
20
Leiithan
22
LASS than
7.8
1.6
Lwlhan
Lett man
Lwtthan
0 Completed
UNITS
"9
ug
ug
ug
ug
ug
ug
ug
ug
ug
Ufl
ug

MDL
1.5
1.S
1.5
15
1.5
15
1.6
1.5
1.5
1.5
1.5
1.5

METHOD
REFERENCE
Method 29
Method 29
Method 29
Method 29
Method 20
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 26
DATE/TIME
STARTED
7/12/9906:00
7/12/9906:00
7/12/99 06:00
7/12799 08:00
7/12/99 06:00
7/12/99 06:00
7/12/9908:00
7/12/9906:00
7/12/99 06:00
7/12/96 06:00
7/12/99 06:00
7/12/99 06:00
7/7/9908:00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
OHJ
DHJ
OHJ
DHJ
DHJ
DHJ
      Angela D. Overcash. V.P. laboratory Services
                                                       E-24

-------
Lab  Report
                                         PRISM
                                         UBORATOWES.IHC.
                                                '
                                                                       Fut Swvioa Analytical & Envi.onm.ntal Solution)
     9/21/99
     Mr. Dennis Tabor       !
     ARCADIS Geraghty & Miller
     2301 Rexwoods Or, Ste 100
     Raleigh, NC 27607
                                    Page 2 of 7
      Customer Project 10:  Orimulsion/RN992010.0024
      Customer Sample ID:  FOBLR6K
         Prism Sample ID:  AB37197
             Login Group:  9151E7
Sample Collection Date/Time:  6/3/99
   Lab Submittal DateTTime:  7/29/99    14:30
The following analytical res
ills have been obtained for the indicated sample which was submitted to this laboratory:
TEST ! TEST
PARAMETER , RESULT UNITS MDL
LOSS ON IGNITION 16 % 1
METHOD DATE/TIME
REFERENCE STARTED
6/5/99 08:00
ANALYST
DHJ
     Sample Comments:
      Angela D. OTOrcasnTXTPTLaboratory Services
                                                  E-25

-------
Lab  Report
                                                    PRISM
                                                                                       LABOKATOMEC.INC.


                                                                          Full S«tv(o» Analytical & Environmental Solutions
      9/21/99
      Mr. Dennis Tabor        \
      ARCADIS Geraghty & Millar
      2301 Rexwoods Dr, Ste 100
      Raleigh, NC 27607
                                               Page 3 of 7
               Customer Project ID:  Orimulslon/RN992010.0024
               Customer Sample ID:  COBLRW1
                   Prism Sample ID:  AB37198
                       Login Group:  9151E7
          Sample Collection Date/Time:  6/3/99
             Lab Submittal Date/Time:  7/29/99     14:30
     The following analytical results have been obtained for the indicated sample which was submitted to this laboratory:
     "TEST
      PARAMETER  	
     LOSS ON IGNITION
TEST
RESULT

59
UNITS

%
             MDL
                     METHOD
                     REFERENCE
DATEmME
STARTED
&/5/99 08:00
ANALYST

 DHJ
       Angela D. Overcash, V.P. Laboratory Services
                                                    E-26

-------
* Report
     V
     •*^k  UBOMTOmE«.INC.
     sSBSk
Ful Swvtea Analytical t Envtanmanlal SoUkms
                                        FRISM
 9/21/99
 Mr. Dennis Tabor
 ARCADIS Geraghty & Miller
 2301 Rexwoods Or, Ste 100
 Raleigh, NC 27607


 The following analytical results hive
                                   Page 4 of 7
     Customer Project ID:  Orimulslon/RN992010.0024
     Customer Sample ID:  FOBLC4#1
         Prism Sample ID:  AB37109
             Login Group: 9151E7
Sample Collection Date/Time: 5/18/99
   Lab SubmRtal Datemme: 7/29/99     14:30
 "TEST
 PARAMETER^
 BOMB PREP. FOR METHOD 29
 ARSENIC BY METHOD 29
 ANTIMONY BY METHOD 29
 BERYLLIUM BY METHOD 29
 CADMIUM BY METHOD 29
 COPPER BY METHOD 29
 CHROMIUM BY METHOD 29
 IRON BY METHOD 29
  MANGANESE BY METHOD 29
  MAGNESIUM BY METHOD 29
  NICKEL BY METHOD 29
  VANADIUM BY METHOD 29
  ZINC BY METHOD 29

   Sample Comments:
,ve been obtained for the Indicated sample which was submitted to this laboratory.
TEST
oeeiii T
t\COUU 1
Completed
16
3.8
17
41
35

130
3300
55
8100

1600
7800
56000
UNITS


ug
ug
ug
ug
ug

ug
ug
ug
ug

ug
ug
ug
MDL


2.5
2.5
2.5
2.5
2.5
2.5

25
2.5
25
2.5

120
120
METHOD
REFERENCE


Method 29
Method 29
Method 29
Method 29
Method 29
Method 29

Method 29
Method 29
Method 29
Method 29

Method 29
Method 29
DATE/TIME
STARTED
8/20/9917:00

8/14/99 08:00
8/14/9908:00
8/14/9908:00
9/14/9908:00
8/14/9908:00
8/14/99 08:00

8/14/99 08:00
9/14/99 08:00
8/14/9906:00
8/14/9908:00

9/14/99 08:00
8/14/99 08:00
ANALYST
DHJ

DHJ
DHJ
DHJ
OHJ
DHJ
DHJ

DHJ
DHJ
DHJ
DHJ

DHJ
DHJ
    Angela D. Overcash, V.P. Laboratory Services
                                                   E-27

-------
ib Report
                                                   PRISM
                                                                                    lABORATOIIIU.INC.


                                                                        Ful Service AMlytcal I Environnwnui Solution!
   9/21/99
   Mr. Dennis Tabor
   ARCADIS Geraghty & Miller
   2301 Rexwoods Dr, Ste 100
   Raleigh, NC 27607
                                              Page 5 of 7
               Customer Project ID:  Orimul*lon/RN992010.0024
               Customer Sample ID:  FOBLC4*2
                   Prism Sample ID:  AB37200
                       Login Group:  9151E7
          Sample Collection Date/Time:  6718/99
             Lab Submtttal Datemme:  7/29/99
                                                                               14:30
   The following analytical results ^ave bean obtained for the indicated sample which was submitted to this laboratory:
   TEST
   PARAMETER
TEST
RESULT
UNITS
   LOSS ON IGNITION
    Sample Comments:
                                 12
MDL

1
                     METHOD
                     REFERENCE
DATE/TIME
STARTED

8/5/9908:00
ANALYST

  DHJ
     Angela D. Overcash, V.P. Laboratory Services
                                                       E-28

-------
b Report
                                                         PRISM
                                                        UBOIUnOMES. INC.
                                                                       Ful SMvtot Ant»ytlctl I Envlioramnlal Solutions
  9/21/99
  Mr. Dennis Tabor
  ARCADIS Geraghty & Miller
  2301 Rexwoods Dr. Ste 100
  Raleigh, NC 27607


  The following analytical results
                                                   Page 6 of 7
                    Customer Project ID:  Orimulslon/RN992010.0024
                    Customer Sample ID:  FOBLdtl
                       Prism Samole ID:  AB37201
                            Loain Group:  9151E7
               Sample Collection Date/Time:  5/24/99
                  Lab Submittal Date/Time: 7/29/99
14:30
have been obtained for the indicated sample which was submitted to Ihis laboratory.
,_	   ii - -- — .— ..-..—• —•—»•• «•- -~          -- .A.K      nA^rcfrtft.4C
TEST
PARAMFTF"
BOMB PREP. FOR METHOD 29
ARSENIC BY METHOD 29
ANTIMONY BY METHOD 29
BERYLLIUM BY METHOD 29
CADMIUM BY METHOD 29
COPPER BY METHOD 29
CHROMIUM BY METHOD 29
IRON BY METHOD 29
MANGANESE BY METHOD 29
MAGNESIUM BY METHOD 29
NICKEL BY METHOD 29
VANADIUM BY METHOD 29
ZINC BY METHOD 29
TEST
RESULT. 	
Completed
42
12
49
35
59
130
2600
90
15000
17000
79000
63000
UNITS

ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
ug
    Sample Comments:
MDL

2.5
2.5
2.5
2.5
2.5
2.5
25
2.5
25
120
120
120
METHOD
REFERENCE

Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
DATE/TIME
STARTED
6/20/9917:00
9/14/99 08:00
9/14/9908:00
9/14/9908:00
9/14/9908:00
9/14/99 08:00
9/14/9908:00
9/14/99 08:00
9/14/99 08:00
8/14/99 08:00
9/14/99 08:00
9/14/9908:00
9/14/9908:00
ANALYST
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
DHJ
      Angela D. Overcash, V.P. Laboratory Services
                                                     E-29

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ab Report                                                              V   PRISM
                                                                         FuH SwvkM Analytical 1 EnvtronnwnUI Solutions
                                                                                 Page 7 of 7
    9/21/99
            ,  _ .  ,                              Customer Project ID:  Orimutslon/RN992010.0024
    Mr. Dennis Tabor                                          •
                                                          Login Group: 9151E7

     Raleigh, NC 27607                       Sample Collection Datemme: 5/24/99

                                                Lab SubmWal Datemme: 7/29/99     14:30


    The following analytical result^ have been obtained for the indicated sample which was submitted to this laboratory.


    .	!	-rEif"       "		METHOD      DATE/TIME

    JSKlOT,	         „ WESULT     .UNITS	 J«L.	R1FERENCE__STARTED	ANALYST


    	""          	 "	~ """       '  .,           4                   8W9908^»0     OHJ
    LOSS ON IGNITION                «          %	.	
     Sample Comments:
      Angela D. Overcash, V.P. Laboratory Services
                                                     E-30

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                                    APPENDIX F
  Orimulsion Spill References Cited by the NRC, U.S. Coast Guard, and
                          Environment Canada Reports

Bitor (1999).  "Orimulsion spill response manual," PdVSA and Bitor America Corp., Boca Raton,
   FL.

Bitor America (1997).  "Orimulsion containment and recovery test carried out in Puerto La  Cruz,
   Anzoatgui State, Venezuela," Bitor America, Boca Raton, FL, October 1996.

Brown, J.W., Fuentes, H.R., Jaffe,  R., and Tsihrintzis, V.A. (1995).  "Comparative evaluation of
   physical and chemical fate processes of Orimulsion and fuel oil No. 6 in the Tampa Bay marine
   environment," Chapter 4,  Comparative Ecological Risk Assessment - Final Report, Center for
   Marine and Environmental Analysis, University of Miami, Miami, FL, June 1995.
CEDRE (1996).  "Orimulsion bitumen clean-up trials," Centre de  Documentation de Recherche et
   d'Experimentations, Brest, France, Report R.96.11.

Clement, F., Gunter, P., and Oland,  D.  (1997).  "Trials of recovery and cleanup techniques on
   bitumen derived from Orimulsion," Proceedings  of the 1995 International Oil Spill Conference,
   American Petroleum Institute, Washington, DC, pp. 89-93.

Deis, D.R., Tavel, N.G., Masciangioli, P., Villoria, C., Jones, M.A., Ortega, G.F., and Lee, G.R. (1997).
   "Orimulsion:  Research  and testing and  open water  containment  and recovery  trials,"
   Proceedings  of the  1997 International  Oil  Spill Conference, American Petroleum Institute,
   Washington, DC, pp. 459-467.

Febres,  G.A.,  Goncalves,  J.A., Masciangoli, P., and  Vilas, J. (1996).  "Fate  and behavior of
   Orimulsion spilt in sea water,"unpublished report, Comparative Oil-Orimulsion  Spill Assessment
   Program, Volume III, Florida Power and Light Company, Miami, FL.

Guenette, C., Sergy, G.,  and Fieldhouse, B. (1998).  "Removal of stranded bitumen from intertidal
   sediments using chemical agents, Phase I: Screening of chemical agents," Environment Canada
   report, Emergency Sciences  Division, Environment Canada, Edmonton, Alberta,  Canada (18 pp.).

Gunter,  P., and  Sommerville,  M. (1991).   "Orimulsion spill trials - Nelson Dock,  Liverpool,"
   NETCEN, AEA Technology/BP Research, Oxfordshire, U.K., July/August 1991.
Harper,  J.R.,  and Kory, M. (1997).   "Orimulsion  sediment interaction experiments," Report to
   Emergency Sciences Division, Environment Canada, Ottawa, Ontario, Canada (34 pp.).

Jokuty, P.,  Fieldhouse, B.,  Fingas, M., Whiticar, S., and Latour, J. (1998).  "Characterizing the
   dynamics of Orimulsion spills in salt, fresh, and  brackish  water "Proceedings of the 21st Arctic
   and Marine Oilspill Program, Technical Seminar, Environment Canada, Ottawa, Ontario, Canada,
   pp. 33-50.
Jokuty, P., Whiticar, S.,  Fingas, M., Wang, Z., Doe, K., Kyle, D.,  Lambert,  P., and Fieldhouse, B.
   (1995).   "Orimulsion: Physical  properties, chemical composition, dispersability, and toxicity,"
   Report EE-154, Environment Canada, Ottawa, Ontario, Canada.

Jokuty, P., Whiticar, S., Wang, Z., Doe, K., Fieldhouse, B., and Fingas, M. (1999).   "Orimulsion-400;
   A comparative study," Report EE-160, Environment Canada, Ottawa, Ontario, Canada.
Lorenzo, T. (1996). "Orimulsion containment and recovery  tests, October 1996, Puerto La  Cruz,
   Venezuela,"  Trip  report,  EED  Report  Series  No. 96,  Emergencies Engineering  Division,
   Environment Canada, Ottawa, Ontario, Canada.

Ostazeski, S.A., Stout, S.A.,  and Uhler, A.D. (1998). "Testing and characterization of Orimulsion 400
   - Volume I - Technical Report," Final report to Bitor America Corp., 44 pp., February 25, 1998.
Ostazeski, S.A., Macomber, S.C., Roberts, L.G., Uhler, A.D., Bitting, K.R., and Hiltabrand, R. (1997).
   "The environmental behavior  of Orimulsion  spilled  on water," Proceedings of  the  1997
                                           F-l

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    International Oil Spill Conference, American Petroleum Institute, Washington, DC, pp. 469-477.
Potter, T.L.  (1995).   "Chemistry  of fuel  oil #6  and Orimulsion,"  Chapter 14, Comparative
    Ecological  Risk Assessment - Final Report,  Center for  Marine and  Environmental Analysis,
    University of Miami, Miami, FL, June 1995.

Potter, T.L., Wu, J., Simmons, K., Kostecki, P., and Calabrese, E. (1997). "Chemical characterization
    of the water soluble fraction of Orimulsion-in-water dispersions," Department  of Food Science
    and School of Public Health, University of Massachusetts, Amherst, MA.
Sneddon,  R. (1989).  "A report on a study to determine  treatment options following  spillage of
    Orimulsion  into marine and freshwater environments," Oil Spill Service Centre, Southampton,
    UK.

Sommerville, M., Lunel,  T., Bailey, N., Oland, D.,  Miles, C., Gunter, P., and Waldhoff, T. (1997).
    "Orimulsion," Proceedings of the 1997 International Oil  Spill Conference, American Petroleum
    Institute, Washington, DC, pp. 479-487.

Wood, P.  (1996).  "Investigations into  landspills of Orimulsion,"  Report  by AEA Technology for
    Bitor Europe (18 pp.).
                                             F-2

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                                     APPENDIX G
                 Additional Ecological Risk Assessment Studies

The original risk assessment by Harwell et al. (1995) was conducted for Bitor as part of their original
permit application to the State  of Florida, and the  document was reviewed by an independent
technical panel (chosen by EPA) for this report.  The conclusions of that panel  were presented in
Chapter 8.

Following the original assessment, additional studies were  conducted that were not reviewed by the
independent panel.  The studies for the updated assessment included:

  1. Additional toxicity data on benthic organisms -  Several additional benthic species indigenous to
    Tampa Bay were tested for acute toxicity to Orimulsion and to No.  6 fuel oil.
  2. Additional toxicity data on the surfactant - Additional toxicological tests were conducted to
    evaluate the potential ecological impacts expected  from exposure to the surfactant in Orimulsion
     100 in the event of a spill, specifically focused  on chronic life-cycle tests for endocrine
    disruption effects.
  3. Additional ecorisk assessment on surfactant - Based on those new chronic life-cycle tests, a risk
    assessment was  conducted  on the ecological effects from the  surfactant associated  with
    Orimulsion 100 in the event  of a large-scale spill into Tampa Bay.
  4. Additional ecorisk assessment on shallow water and nursery areas - Similarly, based on the  new
    acute toxicity information as well as the previous toxicity data, and using a new  set of fate-and-
    transport calculations, a new comparative ecological risk assessment was conducted that focused
    on the risks to the shallow  water critical habitats  and nursery  areas  of  Tampa Bay from
    Orimulsion 100 and No. 6 fuel oil.
  5. Additional assessment of risk reductions  in Tampa Bay and elsewhere  - An assessment  was
    conducted to examine the overall ecological risk reductions from fuel spills in Tampa Bay and
    other estuarine ecosystems within the State of Florida.
  6.  Aquatic toxicity studies were conducted on Orimulsion  400.   Comparative  studies indicated a
    similar toxicity of the two formulations.

The results of these  studies were incorporated into an  updated environmental risk  assessment
conducted for Bitor. The key conclusions of that assessment are listed below:

  1. The risks to the shallow water, critical habitats of Tampa Bay were reported as being orders-of-
    magnitude lower for a major spill of Orimulsion than for a comparable spill of No. 6 fuel oil.
  2. Exposures to the surfactant of Orimulsion 100 in Tampa Bay were reported  as being many
    orders-of-magnitudes lower than the lowest observed effect level as measured through a partial
    life-cycle test using a sensitive fish species.  It was concluded that  a spill of Orimulsion 100
    would pose no risk whatsoever for endocrine disruption of biota in Tampa Bay.
  3. The updated assessment also noted that conversion from No. 6 fuel oil to  Orimulsion at the
    Manatee plant would shift electricity production in the rest of the State of Florida, resulting in
    significant reduction in the risk of spills of #6 fuel  oil in other  areas of the  State, including at the
    Biscayne National Park, Canaveral National Seashore, and other protected waters of Florida.
  4. The toxicity of Orimulsion 400 (the current formulation) is comparable to Orimulsion  100.
    Further, the reformulation of the surfactant in Orimulsion 400 removes the  concern regarding
    potential endocrine disruption.

These conclusions were cited in a document submitted in  response to comments on this report by
Bitor America (Harwell and Golder 2000).  The document was prepared by the  lead author of the
initial environmental risk assessment reviewed for this report (Harwell et al. 1995) and by an associate
of a technical firm that has conducted work in  support of Bitor's permitting efforts in the U.S.  The
submitted document provides additional detail and data, but has not been independently reviewed and
is therefore not included in its entirety as part of this  report.
                                             G-l

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References cited in the updated environmental assessment but not in the original assessment are listed
below.

Battelle (1998).  Testing and Characterization of Orimulsion-400:  Volume  I - Technical  Report,
    Battelle, Duxbury, MA.
Bergman, H., and  H.  Eckert (1990).  "Effect of monoethanolamine on  growth and biomass
    formation of rye and barley," Plant Growth Regulation 9, pp.  1-8.

Bicknell  R.J., A.E. Herbison, and J.P. Sumpter (1995). "Oestrogenic activity of an environmental
    persistent alkylphenol in the reproductive tract but not in the brain of rodents,"  J.  Steroid
    Biochem. Molec. Biol., 54(1/2), pp. 7-9.
Bjornestad, E., A.R. Pedersen,  and  S. Bowadt  (1998).   "Ecotoxicological characterization of
    Orimulsion  400:  A summary report,"  VKI Project No. 11020,  Bitor Europe  Ltd., Brentford,
    Middlesex, England, 16 pages, January  1998.

Davis, J.W., and  C.L.  Carpenter (1997).  "Environmental  assessments of the  alkanolamine,"  in
    Reviews of Environmental Contamination and Toxicology.  Volume  149.  Springer-Verlag, New
    York, N.Y.
Environmental  Health  Research and Testing (1987).   "Screening  of priority chemicals for
    reproductive hazards: Monoethanolamine,  diethanolamine and triethanolamine," report  ETOX-
    85-1002, Environmental Health Research and Testing, Cincinnati, OH.

Environment Canada  (1998).   "Orimulsion-400™  -  A  comparative study,"   prepared  by
    Emergencies Science Division, Environment Canada, Environmental Technology Centre, Ontario,
    Canada,  27 pages.
Esclapes, M.M., et al. (1998).  Unpublished data using Orimulsion-400, PDVSA-INTEVEP, Caracas,
    Venezuela.

Esclapes, M.M.,  I.  Galindo, and Y. Higuerey  (1997).   "Evaluacion  toxicologica de  nuevas
    formulaciones de Orimulsion empleando bioindicadores  acuaticos," report INT-4171,  PDVSA-
    INTEVEP, Caracas, Venezuela.
Golder Associates Geoanalysis (1999).  "Orimulsion-400 and fuel Oil #6: A comparative study of
    aquatic ecotoxicology,"   report 992210/3683 prepared for Bitor Italia  S.r.l., Rome,  Golder
    Associates Inc., Gainesville, FL.

Johnson I.C.,  G.S. Ward, and H.J. Liu (1998a).  "Acute toxicity of Orimulsion-400 and Orimulsion
    100 to two  estuarine  species," report 9937563 prepared  for Bitor  America Corporation, Golder
    Associates Inc., Gainesville, FL.
Johnson,  I.C.  G.S. Ward, and H.J. Liu (1998b).   "Acute toxicity  of Orimulsion-100 to estuarine
    species," COSAP  research under the sponsorship of the University of Miami, (In:  Ault et al.,
    1995, Chapter 10) Golder Associates Inc., Gainesville, Florida.

Johnson,  I.C., C. Metcalfe, Y. Kiparissis, G. Balch, G.S. Ward, J.Wheat, J. Liu, and T. Potter (1997).
    "Final report:  Partial life-cycle studies using  the estuarine fish sheepshead minnow to evaluate
    the potential reproductive and estrogenic  effects of Intan-100," presented at the SETAC 18th
    Annual Meeting, Special  Symposium on Endocrie Disrupters, San Francisco, California.
Knaak, J.B., H.W. Leung, W.T. Scott, J. Busch, and J. Bilsky  (1997). "Toxicology of mono-, di-, and
    triethanolamine," in Reviews of Environmental Contamination and Toxicology.  Volume  149. p.
    1, Springer-Verlag, New York, N.Y.

Liberacki, A.B., T.L. Neeper-Bradley, W.J. Breslin,  and  G.J.  Zielke (1996).  "Evaluation of the
    developmental  toxicity  of dermally applied  monoethanolamine in rats  and  rabbits,"
    Fundamental and Applied Toxicology (USA), 31(1), pp.  117-123.
Mankes,  R.F. (1986).  "Studies on the embryopathic effects of ethanolamine in Long-Evans rats:
    preferential  embryopathy in pups  contiguous with male siblings in utero," Teratog  Carcinog
                                            G-2

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   Mutagen 6, pp. 403-417.

Patty's Industrial Hygiene and Toxicology, (1982). Third Edition, Wiley and Sons, New York, NY.

Routledge, E.J., and J.P.  Sumpter (1996).  "Estrogenic  activity of surfactants and  some of their
   degradation products assessed using a recombinant yeast screen," Environ. Toxicol. Chem. 15(3),
   pp.  241-248.

Soto, A.M., H. Justicia, J.W. Wray, and C. Sonnenschein (1991).   "p-Nonylphenol: an estrogenic
   xenobiotic released from  "modified"  polystyrene," Environ. Health Perspectives, 92,  pp.  167-
    173.

Tennant, R.W., B.H. Margolin, M.D. Shelby, E. Zeiger, J.K.  Haseman,  J. Spalding, W. Caspary, M.
   Resnick, S.  Stasiewicz, B. Anderson,  and R.  Minor  (1987).    "Prediction  of chemical
   carcinogenicity in rodent from in vitro genetic toxicity assays," Science 236, pp. 933-941.
United States Coast Guard (1997).  "Micro- and meso-scale  methods for predicting the behavior of
   low-API gravity oils (LAPIO) spilled in water," 1995 Oil Pollution Grants Program, Research and
   Special Programs, U.S. Coast  Guard, Region , 1st District, Boston, MA.

Wason, S., E. Seigel, L. Sigell, M. McElwee, and W. Pratt (1991).  "Acute exposure to ethanolamine:
   Lack of serious toxicity," Veterinary and Human  Toxicology, 33(4), p. 371.
                                             G-3

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                                     APPENDIX H
     Comparative Risk Methodology Synopsis of Harwell et al. (1995)

The NCEA review of the comparative risk assessment conducted by Harwell et al. (1995) included a
synopsis of the methodology used in the assessment.  The synopsis is presented below.

1)     Meteorological and tidal conditions during  and following the hypothetical spill event were
       input to a hydrodynamical model, based on actual records for Tampa Bay during January
       1991  and August  1991.   Hydrodynamical  conditions during and following each scenario
       spill were simulated using  the NOS-based 3-D hydrodynamical model.  This model provided
       spatially  explicit projections following a hypothetical spill scenario of the current vectors
       through the Tampa bay system and the area near the mouth of the Bay.

2)     These output current  vectors were  input to a transport model to define the current field
       necessary to simulate  the transport of the No. 6 fuel  oil and Orimulsion.  Also provided as
       inputs to the Orimulsion model and the SIMAP oil spill model were parameters representing
       the characteristics of the two fuel types  as derived from chemical, physical, and weathering
       characteristics studies,  as well as from values in the literature.

3)     Transport of the spilled No. 6  fuel oil  as  an  oil slick on the surface  of Tampa Bay was
       simulated using the reparameterized SIMAP model analyses: the oil slick was modeled as a
       set of "spillets" at variable scales of resolution.

4)     A  post-processing  algorithm was  developed to generate a map of the movement of the oil
       slick over the duration of the simulation.   The map  of the movement of the oil slick was
       transferred  into the GIS facility to produce maps of the Tampa Bay region and the oil slick
       coverage for each scenario analyzed.

5)     Interception of the No.  6  fuel  oil slick  that came into contact with the  shoreline was also
       simulated using the SIMAP model.  Scientists  developed another algorithm to calculate the
       amount of mass of oil  slick intercepting each section of the shoreline.

6)     The map of the interception of the oil slick was transferred into the GIS facility to produce
       maps that superimpose the  coastal  areas contacted by the No. 6 fuel oil slick overlain onto the
       coverage of the oil slick for each scenario analyzed.

7)     The  oil slick outputs could not  be directly compared  with  the toxicological exposure-
       response  because there are  no data to  relate the amount of fuel slick present (or cumulative
       value for each cell) to ecological  effects. Consequently, exposure maps  of a No. 6 fuel oil
       slick are presented with a scalar, using  shades of brown to represent the area covered during a
       simulation by the  oil slick.  A qualitative examination of the potential effects of the oil slick
       from a spill of No. 6 fuel oil was developed, considering areal extent of the slick, the area and
       types of shoreline habitats  intercepted  by the oil slick, and historical experiences with No. 6
       fuel oil spills contacting  mangrove and seagrass ecosystems.  Note that, since Orimulsion was
       considered  not to develop  a significant oil slick, this analysis was not done for Orimulsion
       scenarios.

8)     A  reformulated and reparameterized SIMAP model was used to simulate the movement of
       dissolved and particulate fractions  entrained  into the water column following a spill of No.  6
       fuel oil.  For each cell in the SIMAP grid for each time step, each non-zero value of aromatic
       concentration was noted.  For each cell, the cumulative exposure (concentration x duration)
       was  calculated, based on the  maximum concentration seen at  any level within the  5-layer
       water column during  each time step.   Units for the cumulative exposures are ppb-hr of
       dissolved aromatics.
                                            H-l

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9)     Transport of spilled Orimulsion was simulated using the Orimulsion spill model.  This model
       simulated the 3-D movement over time throughout Tampa Bay and associated waters of the
       Orimulsion  particulates and dissolved  fraction in the water column.  The  modeled fraction
       used in the risk characterization was the total hydrocarbon content of the water column.

10)    The output files from the Orimulsion transport model were sent for post-processing.   As for
       the aromatics in No. 6 fuel oil, the cumulative exposures of Orimulsion at each cell in the grid
       were calculated.  Units for the cumulative exposures are ppm-hr of hydrocarbons.

11)    As for No. 6 fuel oil aromatics, total Orimulsion hydrocarbons were transferred to the much
       higher resolution  GIS and advanced visualization system for mapping and for calculations of
       co-occurrence.

12)    The toxicity studies on the potential effects of No. 6 fuel oil and Orimulsion on mangroves
       and seagrasses  were carefully examined.  It was concluded that  no ecologically significant
       habitat alteration  to the mangrove or seagrass plant communities of Tampa  Bay would result
       from a spill of  either No. 6 fuel oil or  Orimulsion. The focus then turned to an examination
       of water-column effects from the two fuel types and the oil slick effects  from No.  6 fuel oil.

13)    The toxicological information  provided by the  survey, the INTEVEP project  on  Orimulsion,
       and other literature reviews, plus the results  of the toxicological experiments conducted on
       seagrasses, seagrass community invertebrate inhabitants, spotted sea trout early life stages, and
       mangroves,  were examined to identify appropriate toxicological benchmarks for No. 6 fuel
       oil and Orimulsion.  The result was the selection of the spotted  sea trout  yolksac  larvae
       toxicological responses to represent the  sensitive species present in the Tampa Bay ecosystem.
       This selection represents a conservative but ecologically and societally important choice.

14)    Data for toxicity tests on spotted  sea  trout yolksac  larvae were  analyzed  to identify dose-
       response and time-dependent exposure-response relationships.  It was decided to use the 48-
       hr toxicity test for the oil-water dispersion (OWD) fraction of both Orimulsion and No. 6 fuel
       oil as most representative of conditions in Tampa Bay following a spill. In part, this decision
       derived from a detailed look at the frequency  distribution of cumulative time of exposures
       and,  in part, this decision related to the leveling off of toxicity at exposure periods exceeding
       48 hours.

15)    A series of steps  was developed to convert from dosing to  modeled conditions; for No. 6 fuel
       oil,  this  entailed  calculating from   the oil-water dispersed  fraction  stock solution
       concentrations  and nominal  concentrations through BTEX to aromatics  concentrations
       effectively  seen by  the  test organisms; for Orimulsion, it involved  going  from the
       concentration of  Orimulsion in the dosing conditions to the total hydrocarbons simulated in
       the Orimulsion  transport model.

16)    These  conversion factors were applied to toxicity  data to derive lethality rate-modeled
       fraction exposure relationships.  The concentrations  were multiplied by 50 to represent the
       associated exposure of a two-day period (comparable to 48-hr tests).

17)    Using these normalized exposure data,  LCio and LC95 values for aromatics  for No. 6 fuel oil
       and total hydrocarbons for Orimulsion were calculated using a logistic equation to fit the raw
       data.  The LC10  level was chosen on the assumption that no ecological responses would be
       ecologically significant  at  changes <10%.    The LC95  level was chosen  to  represent a
       reasonable upper  bound on the asymptotic logistic  equation.

18)    These LCio and LCgs  values were used to provide the scalars for the graphical representation
       of the  exposure levels for each scenario simulation.  By making this  scaling, the graphical
       outputs for No. 6 fuel oil and for  Orimulsion are directly comparable  in terms of effects to
       the sensitive species.  This allows direct,  visual comparative analysis of the risks from each


                                             H-2

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       fuel type for each scenario.

19)    These  simulations were completed for all 96 scenarios, and the resultant suites of graphical
       outputs were visually inspected to identify patterns with respect to the key scenario factors
       (location, seasonality, and wind/current conditions).

20)    Based  on these considerations, four individual scenarios were selected as representative of the
       types of transport and exposure regimes realized for the scenario set for each location.  These
       four  selected  scenarios were then  explored  much  more  thoroughly  for  detailed
       ecotoxicological analyses.

21)    The extensive database was  entered into the GIS facility; we have acquired more than 50
       separate environmental databases containing all relevant biological, ecological, and physical
       information from federal, state, and local agencies concerned with management of Tampa
       Bay.  This extensive, unique  database provides a unique capability to converge considerable
       distribution data with well-defined exposure regime  projects.

22)    A series of steps was developed to relate the exposure  and co-occurrence data for the spotted
       sea trout  species to  population-level  effects  and  recovery  times.  We  conducted similar
       analyses for inland silversides (i.e., the less sensitive species).

23)    A series of  steps was  developed to use the  exposure and co-occurrence information to
       calculate quantitative values  for comparing the  risks of the two fuels to selected species in
       Tampa Bay.  Three  approaches for integrating exposure and effects information into an
       estimate of risk, derived from the EPA framework for  ecological risk assessment, were used;
       single  value  comparisons (one-dimensional models of toxicant-organism interaction); joint
       distribution analysis  (comparing distributions  associated  with estimates of exposure  and
       effects); and population modeling.

24)    Expert judgment was applied to all sets of the risk assessment analyses to  develop the
       synthesis of the comparative risks to the ecological systems  of Tampa Bay from a spill of No.
       6 fuel  oil and a spill of Orimulsion.
                                             H-3

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                                 TECHNICAL REPORT DATA
                          (Please read Intiructions on the reverse before completing)
 1. REPORT NO.
  EPA-600/R-Ol-056b
                           2.
                                                     3. RECIPIENTS ACCESSION NO.
4. TITLE AND SUBTITLE
 Environmental Impacts of the Use of Orimulsion (R):
  Report to Congress on Phase 1 of the Orimulsion
  Technology Assessment Program. Volume 2
                                                      S. REPORT DATE
                                                       July 2001
                                                      6. PERFORMING ORGANIZATION CODE
                      (NRMRL-RTP). K.Dreher (NHE-
 /v8eJ (NCEA-DC). and RNadeau
 (NRMRL-ERT. Edison)
                                                     8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
  See Block 12
                                                      1O. PROGRAM ELEMENT NO.
 12. SPONSORING AGENCY
                                                     11. CONTRACT/GRANT NO.

                                                       NA (Inhouse)
                  NAME AND ADDRESS
 EPA, Office of Research and Development
 Air Pollution Prevention and Control Division
 Research Triangle Park, NC  27711
                                                     13. TYPE OF DEPORT AND PERIOD COVERED
                                                     Phase I; 8/98 - 12/99
                                                     14.SPONSORING AGENCY CODE
                                                       EPA/600/13
            _.  ,     ,   -  .	Andrew Miller, Mail Drop 65, 919/
            Volume 1 consists of the Executive Summary. Repdit, and Appendix A.
  Volume 2 contains Appendices B-H.
 6. ABSTRACT rr-i        7  :	.-	
          ine report gives results of an evaluation of Orimulsioa. a bitumen-in-
 water emulsion produced in Venezuela, to provide a better understanding of the po-
 tential environmental impacts associated with its use as a fuel. Pilot-scale tests
 were conducted at EPA's Environmental Research Center in Research Triangle Park
 in North Carolina,  to provide data on emissions of air pollutants from the combus-
 tion of Orimulsion 100 (the original formulation), Orimulsion 400 (a new formulation
 introduced in 1998). and No. 6  (residual) fuel oil. commonly used in the U. S. These
 results, and those of full-scale tests reported in the technical literature, were eval-
 uated to determine the potential air pollutant emissions and the abilit> of commer-
 cially available pollution control technologies to adequately reduce those emissions.
 Results indicate that carbon monoxide,  nitrogen oxide,  and pariculate matter  (PM)
 emissions are likely to be nearly the same as those from No. 6 fuel oil. that sulfur
 dioxide emissions can increase if the Orimulsion sulfur content is higher than  the
 fuel it replaces, that the PM generated by Orimulsion 100 and 400 is likely to be
 smaller in diameter than that generated by No. 6 fuel oil, and that hazardous air
 pollutants  are also likely to be similar to those from No. 6 fuel oil.  Conventional
 control technologies can effectively reduce emissions to very low levels.
 7.
                 DESCRIPTORS
                              KEY WORDS AND DOCUMENT ANALYSIS
                                          tUOENTIFIERS/OPEN ENDED TERMS
                                                                  c.  COSATI Field/Group
 Pollution
 Bitumens
 Emulsions
 Fuels
 Combustion
 Residual Oils
                     Emission
                     Carbon Monoxide
                     Nitrogen Oxides
                     Particles
                     Toxicity
Pollution Control
Stationary Sources
Orimulsion
Parti culate
13B    14G
11G    07B
07D
21D
21B    06T
 8. DISTRIBUTION STATEMENT

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                         21. NO. OF PAGES
                             187
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                                         H-4

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