United States
               Environmental Protection
               Agency	
National Risk Management
Research Laboratory
Research Triangle Park, NC 27711
              Research and Development
EPA/600/SR-96/026    April 1996
EPA       Project  Summary

               Evaluation of  Barriers to  the  Use of
               Radiation-Cured  and  Hot  Melt
               Coatings in  Coated and  Laminated
               Substrate  Manufacturing
               Jill B.Vitas, Geary D. McMinn, and William L. Blake, Jr.
                In support of EPA's Source Reduc-
              tion Review Project (SRRP), maximum
              achievable control technology (MACT)
              standards development, and the Pollu-
              tion Prevention Act, EPA's National Risk
              Management Laboratory  (NRMRL) is
              investigating the current industrial use
              of and barriers to the extended use of
              radiation-cured coatings in SRRP  and
              MACT categories. The report gives re-
              sults of a study to investigate and iden-
              tify the technical, educational, and eco-
              nomic barriers to  the use and imple-
              mentation of radiation-cured and  hot
              melt coatings in coated and laminated
              substrate manufacturing. Important bar-
              riers include:  capital cost, adhesive
              cost, lack of data  on physical proper-
              ties of adhesives, and aesthetics of the
              end product. The report identifies work
              areas that could help overcome techni-
              cal, educational, and economic barri-
              ers identified. Discussed opportunities
              include: (1) convening  a focus group
              to discuss identified barriers,  identify
              other barriers, and begin the process
              to overcome these barriers; (2) investi-
              gating the use of radiation-curable sys-
              tems in Europe; (3) researching  the
              marketing difficulties associated with
              non-solvent-based products; (4) inves-
              tigating state economic incentive pro-
              grams to determine if financial assis-
              tance  can  be given to manufacturing
              facilities to help encourage the testing
              of radiation-curable adhesives; and (5)
              developing a software system that will
              provide physical  property data  and
              other important information on alterna-
              tive adhesive formulations to assist fa-
              cilities in identifying alternative to their
              current solvent-based adhesives.
   This Project Summary  was devel-
 oped by EPA's National Risk Manage-
 ment Research Laboratory's Air Pollu-
 tion Prevention and Control Division,
 Research  Triangle Park,  NC,  to an-
 nounce key findings of the  research
 project that is fully documented in a
 separate report of the same  title (see
 Project Report ordering  information at
 back).

 Background
   Section 4(b) of the Pollution Prevention
 Act of 1990 requires the U.S.  Environ-
 mental  Protection Agency (EPA) to "re-
 view regulations of the Agency prior and
 subsequent to their proposal  to determine
 their effect  on source reduction." In sup-
 port of the Pollution Prevention Act, EPA
 established the  Source Reduction Review
 Project (SRRP)  to focus its  review on regu-
 lations (and anticipated regulated indus-
 tries) that will soon be mandated under
 the Clean Air Act Amendments of 1990
 (CAAA), the Clean Water Act (CWA), or
 the Resource Conservation and Recovery
 Act (RCRA). A  goal of SRRP tasks is to
 ensure  that source reduction and multi-
 media issues are considered during the
 development of upcoming  air, water, and
 hazardous waste standards.
   Maximum achievable control technology
 (MACT) standards to reduce hazardous
 air pollutants (HAPs)  from major source
 categories are regulations  under the CAA
 and a focus of SRRP. Promulgation of
 these regulations began in 1992 and will
 continue into the decade and  into the next
 century. The MACT standards offer EPA
 an excellent opportunity to use SRRP to
 incorporate pollution prevention (P2) mea-
 sures into the upcoming standards for spe-

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cific  source categories. P2 efforts offer
economic and  reduced health  and eco-
logical risk benefits  to  many  sectors  of
society that are not available through tra-
ditional pollution control methods.
  In  support of the SRRP Program, MACT
standards development, and the Pollution
Prevention Act,  EPA's National Risk Man-
agement Laboratory  (NRMRL)  is  investi-
gating P2  opportunities for product and
material substitutions that help industry to
reduce waste. The objective of this project
was  to  investigate the  current industrial
use  and  barriers  to the extended use  of
radiation-curable coatings.  Adhesive-
Coated and Laminated  Substrates (SICs
2671 and 2672—typical products  include
masking  and duct tape, adhesive labels,
and  adhesive  coated foam products-an
industry facing upcoming MACT standards,
was  selected as an industrial segment for
this  study. Thus,  when the MACT  stan-
dards are  developed,  EPA will  have a
better understanding  of coating technolo-
gies  that are feasible P2 alternatives for
this industry.

Introduction
  The report gives results  of  a study  to
investigate and  identify the technical, edu-
cational, and economic barriers to  the use
and  implementation  of radiation-curable
coatings within  the coated and  laminated
substrate  industry. The project involved
preparing  category analyses,  identifying
and  classifying barriers to  the use and
implementation  of the technology, evalu-
ating and  assessing the  environmental
impacts,  and identifying P2 and  source
reduction research opportunities within the
coated and laminated substrate industry.
Information was collected for the project
from  a review of current technical litera-
ture through cooperation with industry lead-
ers and the leading  trade organizations;
and  through  visits to  coated  and  lami-
nated substrate facilities, radiation-curable
coating and equipment suppliers,  and an
international trade show.
  Radiation-curable  processes  for the
coated and laminated  substrate industry
involve either electron beam (EB) or ultra-
violet (UV) curing mechanisms to pen-
etrate and cure the radiation-curable coat-
ing to the substrate. These two methods
of curing provide many technical, economi-
cal, and environmental  benefits to  tradi-
tional solvent-based systems including in-
creased  bonding  strength, resistance to
chemical and thermal elements, increased
throughput,  reduced cost per unit  area,
and substantially lower  environmental
emissions.  In  addition, both EB  and UV
curing  systems can use  most available
substrates, present coating application sys-
tems, and less floor space.
   The report divides the barriers to imple-
menting EB  and UV curable systems into
three categories: technical, economic, and
educational. Separate chapters examine
each of the three  barrier categories.
   Technical barriers include: the  lack of
industry knowledge of these systems since
no production line for coated and  lami-
nated substrate manufacturers is  operat-
ing in the U.S.; equipment suitability; ma-
terials availability  (coatings are manufac-
tured  and sold by few companies);  prod-
uct and adhesive  performance character-
istics  (appearance, odor, and tack differ-
ences with solvent-based products); and
health  and safety issues  (radiation as a
means of curing).
   Economic barriers provide a challenge
to implementing either an EB or UV cur-
ing system. Economic concerns  involve
the capital investment of the system, pric-
ing pressure from customers  and  com-
petitors, the  payback period of the ma-
chinery, and operating costs of the radia-
tion-curing (specifically, EB curing)  mecha-
nism.
   The primary education barriers to imple-
menting either an  EB or UV curing system
are divided  into the viewpoints of  man-
agement and  other employees. Manage-
ment  expressed concern about the cost,
performance, and productivity of  the  ra-
diation curing  technology, and other em-
ployees  expressed  concerns regarding
handling radiation curable coatings and
radiation safety.
   Hot melt adhesives, another alternative
to solvent-based  systems, are  also dis-
cussed  in this report. Hot melt adhesives
are solids that are heated to their  melting
points and applied to the substrate in their
liquid state.  Hot melt adhesives are  cur-
rently used in many applications and  pro-
vide an alternative  to the solvent-based
systems. Certain hot melt adhesives can
be  reformulated  and  used  as the  EB
system's adhesive.  Technical, economic,
and educational factors of hot melt adhe-
sives are also examined.
  The  report identifies work areas  that
could help  overcome the technical, edu-
cational, and economic barriers  identified.
Among the opportunities discussed are:
  • Convening  a focus group  of  repre-
    sentatives from industry,  trade asso-
    ciations, environmental agencies, ra-
    diation-curable coating and equipment
    suppliers,  and  other interested  par-
    ties to discuss identified barriers, iden-
    tify  others,  and begin the process to
    overcome these barriers.
  • Investigating the use  of radiation-cur-
    able systems in European markets to
    determine the problems or opportuni-
    ties they have discovered as a result
    of actual production  using  these al-
    terative adhesives.
  • Researching the marketing difficulties
    associated with  non-solvent-based
    products. A study of  specific charac-
    teristics of  a  product which improve
    its  marketability (e.g.,  aesthetics)
    would be beneficial.
  • Reviewing  state economic incentive
    programs  (EIPs) which  assist facili-
    ties in developing low-volatile organic
    compound  (VOC) surface  coatings.
    This information could be transmitted
    to coated  and  laminated  substrate
    manufacturers to assist them in meet-
    ing  requirements to receive the finan-
    cial benefits.
  • Developing a publicly available com-
    puter-based information system which
    would contain the performance char-
    acteristics of various adhesive formu-
    lations to assist coated and  laminated
    substrate manufacturers in finding al-
    ternatives to solvent-based adhesives.

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 J. Vitas, G. McMinn, and W. Blake are with TRC Environmental Corp., Chapel
  Hill, NC 27514.
 Carlos M. Nunez is the EPA Project Officer (see below).
 The complete report, entitled "Evaluation of Barriers to the Use ofRadiation-
  Cured and Hot Melt Coatings in Coated and Laminated Substrate Manufac-
  turing, " (Order No. PB96-153 564; Cost: $28.00, subject to change) will be
  available only from:
        National Technical Information Service
        5285 Port Royal Road
        Springfield, VA 22161
        Telephone: 703-487-4650
 The EPA Project Officer can be contacted at:
        Air Pollution Prevention and Control  Division
        National Risk Management Research Laboratory
        U.S. Environmental Protection Agency
        Research Triangle Park, NC 27711
United States
Environmental Protection Agency
National Risk Management Research Laboratory (G-72)
Cincinnati, OH 45268

Official Business
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         EPA
   PERMIT No. G-35
EPA/600/SR-96/026

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