&EPA
United States      Clean Air Markets Division
Environmental Protection  Office of Atmospheric Programs
Agency         (6204N)
June 2001
EPA430-R-01-005
   How to Measure the Effects of Acid
                 Deposition:

   A Framework for Ecological Assessments

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                                                   Acknowledgements

Special thanks are extended to Noreen Clancy, Paillette Middleton, and Allan Auclair at RAND Environmental Science and Policy Center for
their valuable assistance.

Front cover photos clockwise from top left: Loren Hutchinson Calvin Coolidge State Park, Plymouth, VT, NOAA Photo Gallery, trout,
VTvjsb.comMetawlee River,  VT', NOAA Photo Gallery, Cormorant.

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                                      Table of Contents
Section I.    Overview	1
               Tribal Nations Have Unique Situations	1
               Using Section 105 Funds for Assessment Purposes	2
Section II.   Assessment Process	3
               Value of Assessments	3
               Assessing the Acid Rain Program	4
Section III.  Scope of Assessment	11
               What Distinguishes Core and Ultimate Assessments?	11
               What Are Key Criteria for Determining the Scope?	13
Section IV.   Key Questions	15
Section V.   Identifying and Using Available Data  Sources	17
               CMAP	17
               Emission Databases	21
               National Air  and Deposition Monitoring Networks	21
               Ecological Monitoring	23
               General Steps for Conducting Data Quality Assurance	26
Section VI.  Identifying Appropriate Analytical Tools	27
               Air Quality	27
               Ecological Impacts	30
               General Steps for Conducting Model Quality Assurance	30
Section VII.  Integrating Information to Assess Response	33
               Limitations of Using Web Databases	35
Section VIII. Communicating  Results	37
Section IX.  Examples of State-level Ecological Assessments	39
Section X.   References	41
Appendix A. Frequently-Raised Issues and Questions	43
               Emissions, Concentration, and Deposition Analysis Considerations	43
               Ecosystem Analysis Issues	44
Appendix B. Sample Integrated Assessment	47
               Background  	47
               Results 	48
               Acid Deposition Analysis 	49
               Visibility Analysis 	53

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                                List of Tables and Figures
Table 1.  Air, Deposition, and Ecological Network Descriptions and Pollutants Monitored	18
Table 2.  Representative Models and Required Data Sources	28
Figure 1.   Ecological Assessment Process with Feedback Loops	3
Figure 2.   Electric Generating Units Affected By Phases 1  and 2 of Title IV	5
Figure 3.   National Emissions of Sulfur Dioxide	6
Figure 4.   National Emissions of Nitrogen Oxide	6
Figure 5.   Average pH of Precipitation at Monitoring Sites in 1994 (pre-Phase I of
          Title IV) and 1997 (after Phase I)	7
Figure 6.   Sulfate Deposition at Monitoring Sites in 1994 (pre-Phase I of Title IV)
           and 1997 (after Phase I)	8
Figure 7.   Various Response Times to Changes in Emissions	9
Figure 8.   Comparison of Core and Ultimate Assessments	12
Figure 9.   Assessment Strategy	12
Figure 10. Examples of Endpoints Associated with Pollutant Impacts	16
Figure 11. Sulfate Deposition at Two NADP Sites from 1978 to 1997	33
Figure 12. Relationship Between Sulfur Deposition and Precipitation at Two NADP
          Sites Over the 1978-1997 Interval	34
Figure 13. A Comparison of Ambient Air Quality, Deposition and Streamwater Data
          from 1977-1997 at Selected Sites in Pennsylvania	35

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                                           Acronyms
AIRMoN           Atmospheric Integrated Research Monitoring Network
CASTNet          Clean Air Status and Trends Network
ELS               Eastern Lake Survey
EMAP             Ecological Monitoring and Assessment Program
EPA               U.S. Environmental Protection Agency
FHM              Forest Health Monitoring Program
GIS                Geographic Information Systems maps
IMPROVE         Interagency Monitoring of Protected Visual Environments
ISEM              Intensive Site Ecosystem Monitoring
LTER              Long Term Ecological Research Program
LRM              Long Term Monitoring Project
MAGIC            Model of Acidification of Groundwater in Catchments
MAHA            Mid-Atlantic Highlands Assessment
N, NOX, NC>3       Nitrogen, Nitrogen Oxides, Nitrate
NADP/NTN        National Atmospheric Deposition Program/National Trends Network
NAMS             National Air Monitoring Stations
NAPAP            National Acid Precipitation Assessment Program
NAWQA           National Water Quality Assessment Program
NH^               Ammonium
NOAA             National Oceanic and Atmospheric Administration
NSS               National Stream Survey
NSWS             National Surface Water Survey
PAMS             Photochemical Assessment  Monitoring Stations
PM2 5 PMjQ       Particulate Matter (2.5 microns in size or less, 10 microns in size or less)
RADM             Regional Acid Deposition Model
S, SO2, SO4        Sulfur, Sulfur Dioxide, Sulfate
SENIOR            Southeastern Network for Intensive Oxidant Research
SCION             Southeastern Consortium Intermediate Oxidant Network
SLAMS            State and Local Air Monitoring Stations
SON               Spatial Ozone Network
SOS               Southern Oxidant  Study
TIME              Temporally Integrated Monitoring of Ecosystems project
USDA             U.S. Department of Agriculture
VOC               Volatile Organic Compounds
WLS               Western Lakes Survey

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                               section i.      Overview
     In an effort to reduce the adverse effects of acid
     deposition on human health and the environment,
     Congress established the Acid Deposition Control
Program, which was passed in 1990 as Title IV of the
Clean Air Act Amendments (hereafter "Title IV"). Title
IV requires reductions in annual emissions  of sulfur
dioxide (SO2)  and nitrogen oxides (NOx), the precur-
sors of acid rain, from electric utilities.

EPA hopes to facilitate the use of localized monitoring
where available in conjunction with national networks
and promote ecological assessment initiatives at  the
state and tribal nation levels in order to better under-
stand which  regions  of the  country show  signs of
improvement and if any are continuing to degrade. This
combination of local, regional and national ecosystem
assessments will improve  the decision-making  and
evaluation process regarding current air pollution con-
trol strategies.

Phase I of the Acid Rain Program achieved substantial
emission reductions,  resulting in significant environ-
mental and health benefits. As even greater emission
reductions  occur under Phase II  of the Acid Rain
Program (2000 forward), the ability to describe the eco-
logical response to these reductions becomes increas-
ingly  important.  This  type of assessment is key to
determining whether current control levels provide ade-
quate protection to human health and the environment,
and whether further pollution control steps may be nec-
essary.  Given the trans-boundary nature  of air pollu-
tion, mitigating the problem on a regional or national
scale will usually prove much more effective than con-
trolling emissions in a single state. One of  the key roles
states and tribal nations can fill is long-term monitoring
of acid deposition or water  quality and biological
parameters. States and tribal nations have a lot to gain
from measuring whether there have been improvements
in the health of their ecological resources  since imple-
mentation of Title IV (1995).

For purposes of this handbook,  an ecological assess-
ment is defined as:

    a process in which a clear understanding of
    baseline  conditions and  ensuing changes to
    ecosystems  are  monitored  and documented
    over time with the goal of establishing long-
    term environmental trends.

An ecological assessment can be "integrated" and cap-
ture the full range of processes and responses from
emissions to atmospheric transport to deposition to eco-
logical and human health impacts.  Most assessments,
however, examine just a piece  of that  larger picture.
Integrated assessments are useful to synthesize existing
knowledge, but smaller, more focused assessments are
extremely important  and valuable as well. For many
states and tribes these smaller  assessments are more
practical  and  will make up the large majority of the
analyses conducted.

This Handbook describes a process and provides gener-
al guidelines that states and tribal nations can follow in
beginning to assess ecological benefits  resulting from
the emission  reductions achieved under Title IV.
Information on basic  assessment approaches, relevant
national monitoring programs, as well as the availabili-
ty  of modeling data are discussed in the remainder of
this handbook. EPA assumes that local monitoring data
availability is known foremost by individual states and
tribal nations, so that information is not included here.
The goal of EPA's Clean Air Markets Division (former-
ly the Acid Rain Division) in developing this Handbook
is to encourage ecological assessment initiatives at the
state and tribal nation level, especially by those that are
not currently monitoring ecosystem effects  or perform-
ing ecological assessment studies. Title IV is a national
program  resulting in significant emission reductions
nationwide, so the Acid Rain Program focuses primari-
ly on national and regional monitoring programs to dis-
cern national trends.

EPA recognizes that the level  and extent  of environ-
mental protection measures are directly dictated by the
availability of resources. The resource  base of states
and tribes can vary greatly  from those  who have few
methods to pay for assessments to those  who are confi-
dent assessments  are a valuable investment for  the
future.  All states do receive grants, called  section 105
funds,  that may be used for Acid Rain assessments.
EPA can assist states in designing assessment projects

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and provide other technical assistance as needed. Tribes
also have access to EPA funds that can be used for
assessments.

While the information in this handbook focuses on the
needs of states and tribal nations it will also be of use to
university researchers, other federal scientists, foreign
researchers and  other related organizations, although
they are not explicitly addressed.
Tribal Nations Have Unique Situations

Although one handbook will  not address all needs of
states and tribes alike, this handbook attempts to pro-
vide information that may be helpful to both  groups.
EPA recognizes that tribes have treaty  and trust rela-
tionships with the U.S. government as well as relation-
ships with states. Tribes and states often have different
values and motivations  for conducting  ecological
assessments and may have unclear boundaries of man-
agement responsibility.

A tribe may have many  reasons for asserting environ-
mental decision-making authority over  its reservation.
The environmental values and ideals that a tribe holds
may differ  from those addressed by state agencies but
tribes are nevertheless often affected by decisions made
by states. The process by which a tribe makes environ-
mental decisions may also differ from the public partic-
ipation process conducted by state agencies. The reser-
vation is the home of the tribe, with historic,  cultural,
and religious significance which may not be understood
or appreciated by non-tribal agencies. This often makes
the protection of the environmental quality of the reser-
vation a high priority to tribal members.

Many tribes have not been systematically monitoring
and documenting key ecological parameters over the
past few decades to assess change.  This should not keep
these  tribes from  beginning the  assessment  process
now. In addition, tribes have their own unique ways of
establishing historical or baseline ecological informa-
tion based on their culture of oral history. Often it pro-
vides  a greater level of detail in  assessing long-term
change than documented monitoring alone. Although it
does pose  challenges to comparing the historically-
derived information to actual field measurements col-
lected in the present day, traditional ecological knowl-
edge should be considered a starting point in providing
valuable information different from what current scien-
tific knowledge can provide.  This knowledge, used in
conjunction with scientific methods is invaluable to the
understanding of ecological resources on tribal lands.
                  Using Section 105 Funds for Assessment Purposes
  States receive block grants from EPA in order to do work on air issues. These funds are called "section 105
  funds" after the section of the Clean Air Act that authorizes them. They can be used for a wide variety of pur-
  poses, one of which is assessing the impacts of emissions reduction programs. EPA encourages states with an
  interest in conducting assessments to use section 105 funds for that purpose. Some potential uses include:
     •  setting up atmospheric deposition or ecological monitoring site(s)
     •  conducting simple trends analyses on existing data sets that have not yet been "mined"
     •  integrated analyses of some combination of emissions, atmospheric transport, deposition, and ecological
        effects
     •   communicating existing assessment data or  data being collected under another program to the  public
        and/or policymakers
     •  other assessment projects relating to acid deposition
  EPA Regional and Headquarters staff can provide technical assistance to states designing and evaluating these
  assessments if requested.

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             Section II.
            Assessment Process
       The primary purpose of lowering emissions is to
       reduce the adverse effects to human health and
       the environment. Resource managers need to
determine if the environment is reaping the intended
benefits, over what timeframe, and  what additional
actions might need to be taken.  In other words, assess-
ments are  the basis for any  course-corrections or
improvements made during the now-popular adaptive
management process. In general, environmental assess-
ments can help determine how  successful  current and
past policies are in protecting natural resources and how
much further the policies may need to go. An assess-
ment uses science to answer policy-relevant questions
such as, "Are our forests healthier since we reduced
                             emissions?" or "Do we have fewer acidic lakes and
                             streams than 10 years ago?" Assessments can also be
                             useful in identifying gaps in knowledge, identifying a
                             research strategy,  prioritizing  needs,  and allocating
                             resources needed  to  achieve environmental goals
                             (Bernabo, 1993).
                             Value of Assessments

                             Assessments assist in this effort by providing the vehi-
                             cle for organizing and focusing information on environ-
                             mental policies. They are the link between the best data
    Figure 1. Ecological Assessment Process with Feedback Loops.
                                Assessment Process
     Determine
       Key
     Questions
                   New Views
Select Level of
 Assessment
 Detail Using
   Criteria
                                       Stakeholder/Reviewer Feedback
                                                ASSESSME
  Depict
 Impacts
   over
Geographic
   Area
  Perform
  Analysis
(I.e.,source/
  receptor
relationship)
                 Obtain Models
                   And Data
                                                          Synthesize
                                                           Results
                                                       COMMUNICATION
                                                         Tailor Materials
            Involve Stakeholders/Reviewers in Planning
                                Ongoing Review
                                                                     Recommendations

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and knowledge available (both monitoring and scientif-
ic experiments on mechanisms) and any actions taken
such as analyzing, interpreting, and using the informa-
tion to make decisions.  For  the purposes  of  this
Handbook, an assessment is considered an iterative pro-
cess of analyzing and synthesizing various pieces  of
information in order to evaluate and communicate their
significance for  decisionmaking.  This includes deci-
sion-making as it relates to a resource manager's devel-
opment of a research strategy, or decision-making as it
relates to  a policy-maker's evaluation  of an emission
reduction policy.

When  conducting an  assessment,  structured frame-
works, methodologies, and guidelines are usually fol-
lowed. Figure 1 shows a pictorial representation of the
assessment process. In an ideal world, these individual
assessments are repeated over time to continually eval-
uate changes and improve understanding of why the
changes are occurring. Therefore, the assessment pro-
cess (the  act of repeating individual  assessments)  is
considered an iterative one of refining our understand-
ing of environmental change as science and  societal
values evolve. An individual assessment hopefully will
not be a complete replication of a previous  assessment
but an evolution based on  greater  understanding.  The
iterative process is an important function because the
credibility of assessments  for policy  applications
requires a process of open review with wide participa-
tion to avoid  the perception or reality of policy biases.
However,  in  cases where an  iterative assessment pro-
cess is impossible, a single assessment for a given geo-
graphic area  or  ecosystem still provides a wealth  of
information.

Ecological assessments as  a  process are imperfect. It
should not be expected that the process  is easy, or even
well formulated.  It requires some willingness to exper-
iment as the  process is undertaken. Experts acknowl-
edge that  it is not known how  all the  various natural
communities  or species within ecosystems will respond
to pollution reductions. However,  acknowledging the
uncertainty does not prevent decisions from being made
on  a  daily  basis  regarding  managing  resources.
Therefore the pertinent question becomes:  "how do I
manage those resources most effectively in  the face of
uncertainty?" Assessments provide a solid  framework
from which to answer this question.

This Handbook identifies a set of ground rules that can
be helpful in establishing boundaries and providing
structure to the process. It also provides guidance on
performing the five basic  steps to  conducting  an eco-
logical assessment. Each  of these steps will  be dis-
cussed in more detail in the following sections:

Section IV:  Identify the key policy-relevant questions
            to be addressed (e.g., Is  recovery occur-
            ring in those lakes and streams known to
            have been impacted by acid deposition?
            Are fish populations healthier?).
Section V:   Collect and  synthesize  environmental
            monitoring data and information relevant
            to the policy questions (e.g., surface water
            chemistry data, tree health data).
Section VI:  Identify available and appropriate analyti-
            cal tools for collective data analysis (e.g.,
            models, statistical analyses).
Section VII: Integrate  and  assess the environmental
            monitoring data and information in a for-
            mat that addresses the policy questions.
Section VIII: Communicate the results to the policy,
            scientific, environmental, and industrial
            communities  as  well as  to the  general
            public.
Assessing the Acid Rain Program

EPA's Acid Rain Program, established under Title IV
(Acid Deposition Control) of the 1990 Clean Air Act
Amendments, calls for major reductions of sulfur diox-
ide and nitrogen oxides, the pollutants that cause  acid
rain.  The program uses market-based  incentives  to
achieve a nationwide limit on SC>2 emissions more cost
effectively  than  traditional regulatory methods.  The
Acid Rain Program requires a two-phased tightening of
restrictions on fossil fuel-fired power plants, resulting
in a permanent cap on SC>2 of 8.95 million tons nation-
wide, half the amount emitted in 1980. Phase I began in
1995, affecting roughly 440 of the larger, higher emit-
ting electric utility units in the eastern United  States.
NOX emission reductions are also phased, with Phase I
beginning in 1996. Rather than setting an absolute limit
on emissions, Title IV controls how much NOX is emit-
ted for each unit of fuel consumed (Ib/mm Btu). (Total
NOX emissions are not capped). The limits on emission
rates per unit of fuel consumed will maintain  annual
NOx  emissions 2 million  tons below what emissions
would have  been without  the  Acid Rain Program
(beginning in 2000).  Phase II for both SC>2 and NOX
began in 2000 and requires reductions in both pollutants
from more than 2000 units across the country. Figure 2
displays the geographical distribution of those  sources
affected by Title IV.

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   Figure 2: Electric Generating Units Affected By Phases 1 and 2 of Title IV.
                                                 .           	Gr-T^
                                               s^Ste, % %Sl^s*-\,?x «1K
                                                ~
                                                       «  Phase I;
                                                           Substitution/Compensating Units
                                                       s  Phase II
Phase I of Title IV has  led to greater than expected
reductions in emissions. National emissions of SO 2 and
NOX are shown in Figures 3 and 4. The even more sub-
stantial reductions that will occur during Phase II make
the ability to describe the ecological response increas-
ingly important in determining whether current control
levels provide  adequate environmental protection.

A reduction in sulfur and nitrogen oxides emitted into
the atmosphere will result in a reduction of pollutant
concentrations in the air and a reduction of acidic depo-
sition to the Earth's surface. Even so, it is important to
have realistic expectations. Atmospheric transport and
deposition  is a complex process and there  is almost
never a 1:1  or linear relationship between the  tons of
emissions reduced  and  tons  of deposition avoided.
Seasonal variability can mask  ecosystem changes due
to reductions in deposition. Only after several years of
monitoring data will it be possible to separate the  sea-
sonal variability from an overall change.

Assessments must continue long after emissions reduc-
tions take place because of the  time lag before ecologi-
cal  responses  are  seen. Even after reductions  occur,
ecosystems  may  take many years  or  even require
human intervention (such as restocking fish) before
recovering to a condition comparable those known his-
torically. Decades  of leaching valuable minerals from
soils, the removal of sensitive fish species, or changes
in ecosystem structure cannot be reversed quickly and it
can take decades or longer  to rebuild mineral stores,
reintroduce  missing links  in aquatic ecosystems, and
reach other necessary milestones to recovery.

A preliminary  interpretation of  regional monitoring
data from EPA (CASTNet) and NOAA (AIRMoN)
indicates that Title  IV  emission reductions are having a
positive effect on reducing air concentration levels of
SO2 (NAPAP,  1998).  An analysis  of wet deposition
monitoring  data (NADP) demonstrates  that Phase  I
emission reductions resulted in a decrease in the acidi-
ty of  precipitation and  sulfate deposition  in the
Midwestern and northeastern U.S. (see Figures 5 and
6). The spatial and temporal trends of these reductions
are  important components in assessing the ecosystem
effects.

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  SJOOO
A full range of ecosystem
responses are expected over
time, based on various char-
acteristics of the ecosystem.
Ecosystems  are  complex
and are constantly respond-
ing to multiple inputs  and
stressors, such as other pol-
lutants, climate,  and land-
use patterns.  These inputs
and stressors cause chemi-
cal changes within ecosys-
tems,  which  can exhibit
long lag times before mani-
festing a response. This lag
time   between  pollutant
loadings  and  ecosystem
response  underscores  the
need  for  continuous  long-
term   monitoring,  which
helps in our understanding
of what changes are occur-
ring  and when  they  are
occurring. Figure 7 displays
the timeframe  of environ-
mental  responses  to  these
reduced emissions,  which
can range from hours in the
case of changes in air con-
centrations  of  SC>2   and
decades to centuries in the
case of forest health and soil
nutrient reserves.

It  is  also  important  to
remember that within  this
assessment  process  some
relationships   are  better
understood than others. For
example,   emissions,  air
concentrations, and deposi-
tion data  are fairly  well
understood  in comparison
to the  ecosystem,  and  especially to the  biological
cell/tissue/population effects. There are some good case
studies of causal mechanisms, but the great majority of
ecological sensitivities and effects  or responses are not
well understood. The process is to then infer that the
ecosystem  or  specific  biological  organisms  will be
under less stress from the reduced pollutants  and health
will improve. It might be helpful to think of  the efforts
to determine causal relationships as a series of hypothe-
ses that are being tested and then constantly revised.
    Figure 3. National Emissions of Sulfur Dioxide (in thousand tons).
                       1970
               1990
               1995
              1997
    • Fuel combustion nTr.uisport.ilion nliulustrfeil Pro cesses mid Other j
Source: National Air Pollutant Emissions Trends Update, 1970-1997. U.S. Environmental Protection
Agency, Research Triangle Park, NC.
       Figure 4. National Emissions of Nitrogen Oxide (in thousand tons).
        19SO
1970
19SO
199S
19P7
      iFuelamibiutun • TnnqtoTtatiDn D Industrial Pn       and Other
 Source: National Air Pollutant Emissions Trends Update, 1970-1997. U.S. Environmental Protection
 Agency, Research Triangle Park, NC.

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Figure 5. Average pH of Precipitation at Monitoring Sites in 1994 (pre-Phase I of Title IV) and 2000
(post-Phase I).
         Sites not pictured:
         AK01     52
         AKD3     5.1
         PR20     5.2
         Sites not pictured:
         AK01     5.2
         AK03     5.2
         VI01      5.0
Source: National Atmospheric Deposition Program (NADP)

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Figure 6. Sulfate Deposition at Monitoring Sites in 1994 (pre-Phase I of Title IV) and 2000
(post-Phase I).
        Sites not pictured:
        AK01     1 kg/ha
        AK03     1 kg/ha
        PR20    17 kg/ha
                                                                                             Sulfate as SO/'
          Sites not pictured:
          AK01     1 kg/ha
          AK03     1 kg/ha
          VICH     6 kg/ha
      Source: National Atmospheric Deposition Program (NADP)

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 Figure 7. Various Response Times to Changes in Emissions.
Hours

Days/
Weeks

Months

Years

Decades

Centuries
Air Concentration
   Deposition
                 Aquatic(episodic)
                 Soil andPlantProcesses
                           Aquatic (chronic)
                           ForestHeilth
                                                                Soil
 Note: The time it takes for various environmental impact areas (soils, aquatic, and forest ecosystems) to
 respond to changes in emissions varies tremendously. Episodic aquatic ecosystems  may be affected in
 days/weeks, whereas forest health and soil nutrient reserves may take decades to centuries.

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              Section
Scope  of  Assessment
       This section outlines the scope of an assessment.
       The different characteristics of assessments are
       discussed in terms of the level of complexity
that can be considered. At one end is what is referred to
as a "Core Assessment," or  the simplest analysis that
can be done to provide meaningful information for the
questions being posed by the state or tribal nation. The
other  extreme  is  referred  to  as  an  "Ultimate
Assessment."  An Ultimate Assessment attempts to take
into account all of the relevant interrelated issues asso-
ciated with the questions being posed and in order to
provide a detailed quantitative analysis of the relation-
ships among issues, causes, and effects.  In this section,
we provide guidelines for determining the level of data
detail  and model sophistication that might be appropri-
ate for the Core, the Ultimate and, as is likely to be the
more typical  case, an assessment that falls somewhere
in between.
What  Distinguishes Core and Ultimate
Assessments?

The scope of an assessment is characterized in terms of
the issues of concern and the key questions asked along
with the level of detail of the analysis (e.g., data and
models) used to  address the  issues.   This Handbook
concentrates on ecological assessments related to acid
deposition. However, the same framework can be used
to design assessments  to answer all sorts of environ-
mental questions. For acid deposition, the questions
center around the effectiveness of emission reduction
strategies in improving ecosystem  environments.
Considering the relationships of ecological effects to
other impacts and multiple driving factors (such as
meteorology or climate change in  addition to emission
reductions) broadens the scope of the assessment.

A Core Assessment considers changes in key sources as
well as key ecological  receptor areas. The emphasis is
on using existing analyses and data, and non-key  but
related factors and issues are  not explicitly addressed.
Data  and modeling analysis requirements are well
focused and minimal.
                    In an Ultimate Assessment, multiple consequences of
                    emission changes throughout the region surrounding
                    the receptor sites of concern are taken into account.
                    Related issues and influences such as changes in ozone,
                    particulate matter and haze are  also explicitly consid-
                    ered.  Social, economic, and political influences may
                    also be included in the analysis. Data and modeling
                    analysis requirements are more complex since  more
                    sources, processes,  and environmental impacts  are
                    explicitly taken into account.

                    The differences between the Core  and the Ultimate
                    Assessment scope, tools, and resource requirements are
                    summarized in Figure 8. The Core is limited to quanti-
                    tative analysis of one or two  key or representative
                    impacts associated with one or two receptor areas (e.g.,
                    a lake or terrestrial ecosystem) associated with a small
                    well-defined set of sources (e.g., nearby major station-
                    ary source). The data used in the analysis are available
                    and well characterized. Similarly, models used are easy
                    to access and apply. Analyzed and fully developed ref-
                    erence tables and/or graphics  indicating source  and
                    receptor region relationships derived from the Regional
                    Acid Deposition Model, can also be used to help in the
                    assessment at the  Core level. In general, a basic Core
                    Assessment could be initiated as a screening or scoping
                    study with costs in the range of ten to fifteen thousand
                    dollars whereas the more complex assessments require
                    resources up to a hundred thousand dollars or beyond.
                    Often a scoping or Core Assessment can provide the
                    information needed to help the  decision maker decide
                    on next steps, which might include a more extensive
                    assessment.

                    Each step of the Assessment Strategy outlined in Figure
                    9 implies a range of possible questions, analyses, mod-
                    els, data and resource requirements.  Core questions
                    about key impacts and major sources (e.g., has the key
                    regional ecosystem  changed as a result  of emission
                    changes?) differ from questions  that consider a broader
                    range of factors (e.g., other economic and social factors
                    as well as emission trends) in ultimately determining
                    answers to the "why" question.  The complexity of the
                    question determine the elements  to be considered. Basic
                    ecosystem and  emissions data are  needed for  Core
                                                  11

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         Figure 8. Comparison of Core and Ultimate Assessments.
                                   Tools
Full
 Data
 Models
                            Li mited
                             Data
                             Ivtodels
                                             Ultimate
                                       Core
                                                                           Ultimate
                                                                                        Scope
            Ultimate

       $10k   Key Receptors
               Key Sources
               Key Impacts
hAjltiple Receptors
Multiple Sources
Multiple Impacts
                  Resources
                  Needed

                 A Core assessment is limited in the number of receptors, sources and impacts as
                 well as analytic tools used and resource requirements.  As you move from a Core
                 assessment toward an Ultimate assessment all of these requirements increase.
Figure 9. Assessment Strategy
  Evaluate tools and analysis:
    -Revise and modify framework
     if tools and data inadequate
     or other findings suggest new
     questions
    Models/Data:
      -acquire tools
      -proceed with first
      round analysis
    Refine Needs Based on
    Limitations:
      -Substitute data and model
      requirements with existing
      analysis results and/or
      strategies
              Formulate Key Questions
                -Has the key regional
                ecosystem changed?
                -Why?
            ASSESSMENT ELEMENTS
            Receptors and Imparts
            Sectors and Sources
            Single/Multiple Sectors
            Near Source/Long Range
            Episodes/Long Term Averages
            Other Air Quality/Climate Issues
            Other Land/Water Use Factors
            Socioeconornic  Considerations
            Regulations and Source Controls
            Policies and Management Options
         Set Up Analysis Framework:
          -Examine trends in
           ecosystems and emissions
           from sources in the region.
           •Examine issues and factors
           affecting ecosystems
               Required Elements:
                -ecosystem data
                -emissions data
                -other factors affecting
                 ecosystems
                Resource
                Constraints:
                 -agency resources
                 -ability to acquire
                  data and tools
             Set Information and
             Resource Needs:
               -Desired databases, models,
               and previous analyses for
               the area
               -Analysis time estimates
                                                    12

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Assessments while additional information is needed to
answer broader questions.

It should be kept in mind that resource constraints will
become more significant as the assessment becomes
more complex. A state or tribe may have relatively easy
access to information required for the Core Assessment,
but may have complex questions that require something
close to an Ultimate Analysis to answer. However, for
more complex analyses approaching the Ultimate, the
resource requirements  (time, expertise  and  cost)
become higher. After evaluating the questions, frame-
work and resource requirements, the assessment can be
scaled up or down to meet the needs of the tribal nation
or state within the available resources.
What are Key Criteria for Determining
the Scope?

The scope of the assessment is determined, to a large
extent, by the specific policy questions being addressed
(these questions will be discussed in detail in the fol-
lowing section). The  range  of receptors,  impacts,
sources and other factors to be considered in establish-
ing causes and effects sets the bounds for the level of
analysis required. In-depth questions dealing with mul-
tiple relationships and scales can be posed. However, if
the data and/or modeling support is not readily  avail-
able or cannot be obtained within budget, then less rig-
orous approaches must be taken, which rely on previous
      Key criteria for determining
      the  scope of an assessment
             key questions
             data quality/quantity
             model availability
             local analysis expertise
             computer constraints
             time limitations
             funding considerations
analyses or data not explicitly related to the question
being posed.

Several criteria then determine the needed and/or feasi-
ble level of detail for the assessment. The level of detail
that can actually be addressed depends on the data and
model  availability  and quality; staff,  computer and
other resource requirements and availability; assess-
ment deadlines  or  other  time constraints; and basic
funding considerations.
                                                13

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                        Section  IV.
Key  Questions
        Those conducting assessments, such as resource
        managers, should seek the input  of  relevant
        stakeholders such as  scientists, policymakers,
industries,  environmental   groups,  and  community
groups  in   formulating  the  assessment questions.
Involving stakeholders at  the outset will help to ensure
that an ecological assessment is both relevant and cred-
ible. Such inclusion will also  increase an assessment's
chance of being perceived as a useful  and successful
exercise upon its completion. The stakeholder process
is also important because  it brings to the table the soci-
etal values, preferences, and priorities, as well as scien-
tific knowledge and agency priorities. It is  also impor-
tant to keep in mind that societal values can be very dif-
ferent for different groups. For example, the value that
a tribal society places on natural resources and their
stewardship can vary greatly  from that  of  a non-tribal
society, just as such values can  drastically vary from
one  geographic  location to another.  Assessments
involving more than one community should make sure
as many voices as possible have a chance to participate
in the process.

Below is a sample list of the types of  policy-relevant
questions likely to be identified for the  purpose of
assessing ecological change  from  Title IV  emission
reductions.  It might be helpful to categorize the ques-
tions as either "feasible" or "not feasible at the present
time" based on the scope of the assessment you nar-
rowed in on in Section III.

•   Have sensitive ecosystems in  this state or tribal
    nation been identified?
•   What are the current physical, chemical, or biolog-
    ical characteristics or states of these ecosystems?
•   Have baseline measurements been established?
•   How have these characteristics changed over time
    and what are the trends in these changes?
•   How are emissions spatially  distributed in relation
    to sensitive ecosystems and/or existing ecological
    problems?
•   Does this state or tribal nation have  (or have access
    to) adequate monitoring and spatial coverage to
    detect  changes in  deposition  and  ecosystem
    effects?
•   What are the dose-response relationships of atmo-
                spheric deposition (specifically sulfur, nitrogen,
                and  base cations) on aquatic  and terrestrial
                resources?
            •   What evidence do we have of ecosystem changes
                due to increases in atmospheric deposition?
            •   What evidence do we have documenting ecosys-
                tem  recovery due to  reductions in atmospheric
                deposition or reductions in sulfur concentrations?
            •   Are  there baseline  ecological  (biological) data
                available  in order to measure a change in a certain
                sensitive ecosystem?
            •   What are the best parameters to measure ecosys-
                tem level changes (e.g., water chemistry changes,
                population changes,  etc.)?
            •   Are there uncertainties that affect the understand-
                ing of the  links and  cause/effect  relationships
                between emission decreases, deposition changes,
                and ecological effects (e.g., responses influenced
                by other  factors such as climate change, ozone,
                land-use changes and the carbon cycle)?
            •   What are  the environmental/human  health end-
                points?

            These questions can be further expressed in terms of
            particular impacts or  endpoints.  Some key endpoint
            examples are summarized in Figure  10. Endpoints for
            human health effects have been extensively studied and
            are  directly  related  to  criteria  pollutant standards.
            Endpoints associated with ecosystem and other welfare
            parameters such as visibility and materials damage also
            have been studied in detail.  Assessments of ecological
            impacts are critical to our ability to improve the state -
            of-the-science and incorporate ecological effects  into
            future policies.

            Once the relevant questions are developed, it can then
            be determined how useful current research or monitor-
            ing data will be in providing answers, and what meth-
            ods  of research and  assessment should be applied. In
            developing the key questions to  assess the impacts of
            acid deposition for a particular area, it is important to
            keep in mind  that Title IV of the  Clean  Air Act took
            effect in 1995. This date represents that point at which
            decreases in emission rates can be referenced and com-
            pared to earlier and/or later periods. Some reduction in
            emissions may even have occurred prior to 1995 as util-
                                                   15

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                   Figure 10. Examples of Endpoints Associated with Pollutant Impacts
                                             Pollutants
                                            ind
               HEALTH

               Mortality
               Chronic Bronchitis
               Hypertension
               Hospital Admissions
               Respiratory Related
               Symptoms
                                              Endpoints
VISIBILITY

Deciview Changes
(decreased visibility)

MATERIALS
Soiling Damages
ECOSYSTEMS

Agricultural
Productivity
Forest Aesthetics
Forest Health
Recreational Fishing
Biodiversity
Lake Acidification
Timber Productivity
ity companies adjusted emission levels in anticipation
of pending regulations.

The key questions are likely to differ from one state or
tribal nation to another and are apt to change over time
as new concerns  arise  and/or as new perceptions
emerge from  ongoing research into the effects of acid
deposition on ecosystems. It is likely, therefore, that the
data  required to address decision needs will vary with
location and  over time. It is also likely that,  as  our
understanding of the ecological effects of sulfate  and
nitrate  deposition improves, different data and tools
            may be needed than what were needed in 1990 or 1995.
            Where information is not available from nearby moni-
            toring sites designed to measure deposition and other
            effects of changes in pollutant emissions (e.g., ambient
            air and surface water quality), data from other monitor-
            ing programs and/or model results will need to be used.
            Data from unrelated programs should be used with the
            guidance of experts who understand the assumptions
            and other technical issues that may impact the strength
            of the assessment.
                                                   16

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  sectionv.     Identifying  and  Using  Available
                               Data  Sources
    In order to answer your policy-relevant questions,
    you need scientific data and information. This sec-
    tion outlines the data on acid deposition and its
ecological effects that are available for use by states and
tribal nations from national networks.

National air quality  and deposition monitoring net-
works are used to answer questions about trends on
national and regional scales. Using national monitoring
emissions and deposition  data will provide overall
trends, however, there are no comparable national mon-
itoring networks for surface water/soil chemistry or
ecological data designed to provide a national picture of
ecological effects. To get an idea of what is happening
with the local ecology it will most likely be necessary
to  look at  intensive  monitoring projects  on specific
ecosystems or research projects conducted by universi-
ties, state or federal  scientists, etc. A vast amount of
high-quality science was conducted in the 1980s and
early 1990s by the scientific community for the purpose
of attaining the state of science and technology on the
issue of acidic deposition. This science was sponsored
by the U.S. National Acid Precipitation  Assessment
Program (NAPAP) and fed into a NAPAP Integrated
Assessment Report (NAPAP 1991). Much of the bench-
mark science that is summarized in those reports, along
with the methods employed, should prove to be a good
foundation for most types of ecological assessments
conducted today.

Descriptions of many ongoing national air monitoring
networks and ecological monitoring networks are listed
in Table 1 with some additional detail in the paragraphs
that follow the table. This list is not  comprehensive.
Again, national coverage is the focus of those networks
cited in Table 1. States, universities, and other groups
have databases that could be accessed and of direct rel-
evance since many of them will focus on smaller spatial
scales or  specific ecosystems. It is strongly  recom-
mended that such databases be explored in  addition to
the  national datasets. For example,  if you  were con-
ducting an assessment within the state of  Minnesota
you would contact the MN Department of Natural
Resources for ecological and water databases, the MN
Pollution  Control  Agency for emissions  and water
databases, and the University of MN for ecological and
water databases.

EPA has  combined  many of its databases into the
Envirofacts  Warehouse, which can be accessed at
http: //www. epa. gov/enviro/index_i ava.html. Data  sets
are also available from monitoring networks that are no
                   NEWHC-MAP NOW AVAILABLE!!

  C-MAP is the Clean Air Mapping and Analysis Program, a website designed and maintained by
  EPA Clean Air Markets Division. This Web site is designed to take advantage of new geograph-
  ic mapping techniques to assess the environmental benefits of sulfur dioxide and nitrogen oxide
  emission reduction programs, such as the Acid Rain Program. Using a Geographic Information
  System (GIS), C-MAP allows users to view a series of national and regional maps in the "Map
  Gallery" section, and then download the data used to generate the maps in the "GIS Data
  Download" section. The maps display information showing how changes in emissions  result in
  changes in air quality indicators, acid deposition, and  sensitive ecosystems. The GIS database
  provides an extensive inventory of national/regional level emissions, environmental effects, and
  demographic data available for download, including air quality, surface water quality, acid depo-
  sition, forest health,  and sensitive ecosystem data. Many  of the datasets  described  in this
  Handbook can be accessed or linked to from C-MAP.
  See: httD;//www.eDa.gov/airmarkets/cmaD/
                                             17

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longer active (not included in Table 1). This informa-
tion can be helpful in assessing trends but locating these
data  sets may  require  a  bit  of  investigation.
Considerations for using databases to address ecologi-
cal assessment questions  and general approaches to
assuring the  quality of data, which is not part of  a
national network, also are provided.
Emissions  Databases

EPA is the primary source of emissions data for all of
the United States, at both  national and state  levels.
These  data are available  at  http://www.epa.gov/ttn/
chief. Complete documentation of emissions inventory
development  for the U.S. can be  found in the  EPA
National Air Quality and  Emissions Trends Report,
1998  (http://www.epa.gov/oar/aqtrnd98/').  That report
is  a good starting point for obtaining total emissions
data for assessments. Emissions are summarized by
pollutant,  category,  and state. Emissions associated
with a particular source  will need to be accessed from
local state agencies. Development of inventories can be
done  specially  for  a regional assessment by supple-
menting the EPA inventories with updated and source
specific information and by implementing  a variety of
emissions models. However, this is a resource intensive
process. At the very least,  any inventory  used for an
assessment, particularly  a local assessment, should be
spot-checked  to see if it  appears reasonable.

Under Title IV each regulated unit (e.g. boiler at  a
power generating facility)  is required  to  account for
every ton of emissions.  In order to ensure  compliance
each unit was required to install a continuous emission
monitoring system (CEM) to record various parameters
on  an hourly basis such as heat input  and total mass
emissions.  The data are electronically transferred to
EPA's Emissions Tracking  System (ETS) each quarter
and compared against the number of allowances held by
each unit at the end of each year.  (Allowances are allo-
cated by EPA each year  and each allowance allows the
holder to  emit one ton of  SO 2.  Allowances can be
bought and sold or banked for future use.) Emissions
data from  non-affected sources are estimated using
models  and  representative  emission measurements.
Emissions data from sources in the Acid Rain Program
can be accessed on the web  at  http://www. epa. gov/air-
markets/emissions/.

The Emissions  & Generation  Resource  Integrated
Database (E-GRID) is a comprehensive source of data
on  the  environmental characteristics of  all electric
power generated in the United States. An integration of
18  different federal  data sources, E-GRID2000 pro-
vides information  on air pollutant emissions  and
resource mix for 4600 individual power plants, more
than 2000 generating companies, states, and regions of
the power grid.  The data are expressed in terms that
allow direct comparison of the environmental attributes
of electricity generation at any level. The latest version,
E-GRID2000,  includes data from 1996 through 1998.
The new 1998 data have been reconfigured to reflect
the  industry's current structure,  including  company
mergers, power plant divestiture to non-utility compa-
nies, and grid reconfigurations through December 31,
2000. E-GRID is  accessible  through a user-friendly
data browser or by viewing Microsoft Excel spread-
sheets, both downloadable  from  the EPA Clean Air
Markets web  site at  (http://www.epa.gov/airmarkets/
e grid/index).

The EPA Office  of Enforcement and Compliance oper-
ates the American Indian Lands Environmental Support
Project  (AILESP).  AILESP  integrates  and  assesses
recent multi-media point-source releases, the potential
impacts of contaminants, and recent compliance and
enforcement histories for facilities located on and with-
in five kilometers of Tribal areas. This project uniquely
assimilates and  synthesizes disparate data sources to
create a better understanding of the nature and extent of
permitted point sources on and near Tribal areas. AILE-
SP    can   be  found  on    EPA's  website  at
http://es.epa.gov/oeca/ailesp/index.html.  Emissions at
the tribal  level  can  be deduced  from the emissions
inventories by examining the  emissions for states and
counties that overlap tribal lands. Emissions for specif-
ic sources or source categories in a particular area may
be  available  from local,  state  or tribal agencies.
Information also is readily available for counties.
National Air and Deposition Monitoring
Networks

The two pollutants controlled under Title IV are sulfur
dioxide (SC^) and nitrogen oxides (NOX) because of
their recognized contributions to adverse health and
ecosystem effects. There are many national networks
that monitor SC>2 and NOX as part of their design and are
therefore an available  source of air quality data (see
Table 1). Detailed descriptions of national monitoring
and analysis  of these  and  other key pollutants (e.g.,
those for which  standards  have been  set)  at  the
                                                   21

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metropolitan level are also  available in the  EPA
National Air Quality  and Emissions  Trends Report
1998 mentioned earlier.  In addition, both maps and
time series are available for one or more sites on a large
selection of (wet) deposition parameters at the National
Atmospheric Deposition Program:
http: //nadp. sws.uiuc.edu/.

Ambient monitoring for SO 2 and NOx has been done at
urban monitoring stations as well as some rural stations
for up to 25 years. The IMPROVE visibility network
has almost 10 years of aerosol speciation data (e.g., sul-
fates,  nitrates,  organic and   elemental carbon,  and
ammonium) for PM2.5 and PMio (particles 2.5 microns
or less  in  size and  10  microns  or less  in  size).
Precipitation chemistry in  some networks  goes back
almost two decades. All monitoring data generally are
available to the public upon  request to the network
manager responsible, but  may require persistence  in
obtaining the specific information you need.

NADP/NTN: The National Atmospheric Deposition
Program (NADP) was  established in 1978 to provide
information  on  geographical  patterns  and temporal
trends in U.S. precipitation chemistry. A major  objec-
tive of the program is to characterize geographical pat-
terns  and temporal trends  in  acid  deposition of the
United States through development and maintenance of
a deposition monitoring network called the  National
Trends Network (NTN). Long-term monitoring stations
are sponsored by cooperating  agencies  and  organiza-
tions  that volunteer personnel, equipment, analytical
costs,  and other resources and agree to  follow the
Network's standard  established  procedures.  The  net-
work currently  consists of over 200 monitoring sites
across the nation with  5 of those  stations located on
tribal lands (ME, SC, MI, MN,  NY).  NADP/NTN crite-
ria and protocols ensure uniformity in siting, sampling
methods, analytical techniques,  data handling,  and
overall network operation.

CASTNet/ AIRMoN:  The EPA Clean Air Status and
Trends Network (CASTNet) and the National Oceanic
and  Atmospheric  Administration (NOAA) Atmo-
spheric Integrated  Research and Monitoring Network
(AIRMoN) both provide information on site-specific
deposition that can be interpolated in some instances to
a regional scale. Dry deposition measurements in these
networks are a product of ambient air concentrations
and modeled deposition velocities. CASTNet measures
ambient  03,  SO2, HNOs, particulate nitrate, and sulfate
and ammonium species. CASTNet is a primary source
for data to estimate dry  acidic deposition and to provide
data on rural ozone levels. Used in conjunction with
other national monitoring networks, CASTNet  deter-
mines  the effectiveness of national emission control
programs. CASTNet data has been collected since 1987
and is available on the web at http://www.epa.gov/cast-
net.

AIRMoN brings together wet and dry deposition com-
ponents to reveal the  causes of observed trends. The
AIRMoN-wet program relies on common field equip-
ment,  a  single analytical laboratory, and centralized
quality  assurance. Daily  samples are  collected, and
samples are analyzed for nitrate, sulfate, and ammoni-
um.  The AIRMoN-dry program relies on a two-tiered
approach that infers  dry deposition from  air quality,
meteorology,  and surface observations and directly
applies eddy  flux and/or  gradient techniques.  These
methods yield average dry deposition  rates to  areas,
typically many hundred meters in radius, surrounding
observation points. Observation sites are located within
areas that are both spatially homogeneous and repre-
sentative of the larger region. Sites selected for wet
deposition measurement may not be representative sites
for dry deposition measurement.

SLAMS/NAMS:  State  or Local  Air Monitoring
Stations (SLAMS)  and  National  Air Monitoring
Stations  (NAMS)  are federally mandated air quality
monitoring networks. They are designed to measure cri-
teria pollutants  (characterizing maximum concentra-
tions, population exposure, source impacts, attainment
and non-attainment areas.  The NAMS network, a sub-
network of SLAMS, is designed to track air quality in
urban, multi-source-impacted areas with high  popu-
lation density. These surface air quality measurements
will  generally  be impacted by  local  and regional
sources.  The  current generation of  O^, NO/NOx, SO2
and  CO  instrumentation used in  these networks can
deliver virtually continuous data.

PAMS:  Photochemical   Assessment  Monitoring
Stations (PAMS) is a small and newer network designed
to improve understanding  of  ozone (O^y PAMS is
intended to provide  information  for control  strategy
development  and evaluation, emissions tracking, trend
analysis, and exposure.  It measures 03, speciated VOC,
and NOX. Speciated VOC and carbonyl compounds cur-
rently being measured have minimum sampling times
of one hour and three hours respectively. The methods
used to measure speciated hydrocarbons and carbonyls
in PAMS are  still evolving, and quality assurance pro-
cedures and  standards are still being developed. For
example, the NO 2 channel of the NOX analyzers (like all
                                                   22

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present generation commercial chemiluminescent NOX
analyzers) suffers from interference by more oxidized
forms of NOX such as HNO3 and PAN.

SOS: Like PAMS, the Southern Oxidant Study (SOS)
provides information  primarily on Q and its  precur-
sors. However, unlike the  routine monitoring of the
PAMS,  SLAMS, and  NAMS networks,  SOS provides
detailed information on interaction between regional
and urban  Q pollution in the southern United States.
SOS has included simultaneous and interacting  region-
al- and urban-scale air quality field experiments  embed-
ded in a three-tiered network of sub-networks having
different levels of spatial and temporal resolution and
instrumental and technological sophistication. The net-
work includes:

•   Spatial Ozone Network (SON)  for continuously
    monitoring surface O3 concentrations at some sites
•   Southeastern  Consortium  Intermediate Oxidant
    Network (SCION) for monitoring Q, NO, NOy,
    HNOs, CO, SO2  and speciated hydrocarbon con-
    centrations at  a smaller number of sites
•   Southeastern  Network  for  Intensive Oxidant
    Research  (SENIOR), which uses state-of-the-sci-
    ence  instrumentation  to  characterize detailed
    chemistry and chemical processes  at a variable
    number of rural sites in the region during intensive
    measurement  campaigns.
Ecological  Monitoring

The response of ecosystems to changes in emissions is
still the most elusive piece of the assessment puzzle.
Ecosystems rarely show linear changes to management
decisions, and as was mentioned earlier, the lags in eco-
logical responses resulting from emission reductions is
primarily  on the  order of decades to centuries (see
Figure 7). National ecological monitoring networks are
limited, although state-level or regional networks exist
in many parts of the country.

Therefore, one of the key roles states and tribal nations
can fill is long-term monitoring of water quality and
biological parameters.  These data are critical in the
actual documentation of recovery. Monitoring ecologi-
cal changes requires a commitment to consistent, long-
term monitoring to receive the full benefits of the net-
work. Decision-makers often have difficulty supporting
efforts with payoffs 20 years in the future, but without
good long-term monitoring data it is impossible to doc-
ument ecosystem recovery and to verify models. For
ecological  networks that have been established, it is
often a recurring battle to simply maintain the existing
network. During budget cuts networks are vulnerable
targets often resulting in the loss of monitoring stations,
the funds to analyze what data  is collected, or other
functions of the network. Such changes often compro-
mise the integrity  of  the  entire network.  This may
explain some of the variability encountered in ecologi-
cal data sets.

A partial list of parameters which could be measured to
document  changes  due  to  reductions  in deposition
include:  water chemistry changes; phytoplankton/zoo-
plankton   population    changes    or   species
presence/absence changes; fish species changes; fish
survival in formerly fishless waters; coastal eutrophica-
tion; red spruce recovery; decreases in the severity of
acidic episodes; decreases in the mercury levels in fish;
changes  in diatom  species found in the surface sedi-
ments of lakes. The National Research Council has
recently  published a book titled Ecological Indicators
for  the  Nation   (http://books.nap.edu/books/0309
068452/html/index.html). The book identifies national
level indicators needed for decision making and also
shows how the recommended methods can be useful at
regional and local scales.

Below is a brief description  of those networks refer-
enced in Table 1 including a more complete list of the
parameters measured.

Forest Health Monitoring (FHM):  Founded in 1990,
the  multi-agency FHM serves as  both the scientific
foundation and the administrative framework for col-
lecting,  managing,  assessing, and reporting forest
health information.  The  goals of the program are to
monitor, assess, and report on the  long-term  status,
changes, and trends in forest ecosystem health and sus-
tainability  in the U.S. The USDA Forest Service in
cooperation manages FHM with other program part-
ners. All measurements are taken annually (June  15-
Sept. 15) on a systematic grid of about 4,000 forested
ground plots across the nation. A quarter of the plots are
measured each year on a four-year cycle.

In addition to the ground plot measurements, detection
surveys  are  conducted.  These  include  aerial  and
ground-based  survey data on  forest insects, diseases,
and other  forest stressors collected by FHM partici-
pants, and data from other programs on factors such as
climate,  weather, air pollution, management practices,
and forest growth.
                                                   23

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A special aspect of FHM is a network of intensive site
ecosystem monitoring sites (ISEM). These are on bio-
logically representative  sites such as the  Long  Term
Ecosystem Research (LTER) sites, and are designed to
(i) correlate stressors with forest condition, (ii) improve
monitoring and evaluation  techniques, (iii) identify
causal agents, and (iv) improve the estimation of future
forest condition.

The FHM measures the following parameters:
   plant species diversity
   bioindicator plants
   lichen communities
   tree mortality
   lichen chemistry
   wildlife habitat
   tree damage
   root condition
   dendrochemistry
   branch evaluation
leaf area index
tree regeneration
vegetation structure
air pollution
tree growth
foliar chemistry
scenic beauty
tree crown condition
dendrochronology
soils
scales  into assessments  of ecological condition and
forecasts of the future risks. EMAP will develop and
demonstrate indicators to monitor the condition of eco-
logical resources, and investigate multi-tier designs that
address the acquisition and analysis of multi-scale data
including  aggregation  across  tiers  and  natural
resources. Measurements are taken annually at 12,600
sites in the eastern portion of the United States, which
include areas  of Maryland, Virginia, West Virginia,
North  Carolina  and  Pennsylvania. EPA  recently
announced the initiation of the Western Environmental
Monitoring and Assessment Program that began in the
summer of 1999 and will run for five years.

EMAP measures the following parameters:
Water:
•  discharge
•  aquatic biota
•  sediment chemistry
•  habitat
sediment load
inorganic chemistry
trace metals
Long-Term Monitoring Project (LTM): As part of the
EPA's ongoing Long-Term Monitoring project, changes
in surface water chemistry have been monitored  since
the early 1980's. Sampling occurs at 45 lakes in the
Northeast and Upper Midwest and at 12 streams main-
ly in the Mid-Atlantic region (lakes in Maine and
Vermont; Adirondack and Catskill  regions  of New
York; Michigan, Wisconsin,  and Minnesota [MI, WI,
MN monitored until 1995]; Virginia streams in the Mid
Appalachians; and streams in the Catskill Mountains,
New York). Among the factors being monitored are
acidity,  sulfate concentration and nitrate concentration.
Note that LTM data is not available via the internet but
can be obtained upon request to EPA (see Table 1).

The Temporally Integrated Monitoring of Ecosystems
(TIME) project is a related EPA program to  measure
water quality in acid-sensitive environments. Sampling
occurs at 60 lakes in the Northeast  and 60 streams  in
Mid-Atlantic region. It formed part of the Mid-Atlantic
Highlands Assessment (MAHA) to  provide a suite  of
environmental  assessment  tools.(http://www.epa.gov/
emfiulte/html/remap/three/index.html).

Environmental   Monitoring   and   Assessment
Program (EMAP): EMAP is an EPA research program
designed to develop the tools  necessary to monitor and
assess the status and trends of the nation's ecological
resources. EMAP's goal is to  develop the scientific
understanding necessary  to  translate environmental
monitoring  data from multiple  spatial and temporal
                        Marine/coastal:
                        •  salinity/freshwater flux
                        •  zooplankton
                        •  nutrients/contaminants
                        •  submerged/coastal habitats

                        Soils:
                        •  texture
                        •  toxicity
                        •  structure
                        •  strength
                        •  erodability

                        Animals
                        •  species/range/population

                        Miscellaneous
                        •  landscape pattern

                        Vegetation
                        •  growth rate
                        •  above-ground biomass
                        •  disease intensity
                               chlorophyll
                               animals
                               sediment
                               chemistry
                               mineralogy
                               climate
                               faunal biomass
                               recruitment
                               species/cover/range
                               nutrient availability
                        Long-Term   Ecological  Research  (LTER):  The
                        National Science Foundation established the LTER pro-
                        gram in 1980 to support research on long-term ecolog-
                        ical phenomena in the United States. The Network now
                        consists of 21 sites representing diverse ecosystems and
                        research emphases. A network office coordinates com-
                        munication, network publications, and planning  activi-
                                                    24

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ties. The LTER involves more than 1,100 scientists and
students investigating ecological processes operating at
long time scales (e.g., decades) and over broad spatial
scales. The LTER Network is committed to long-term
ecological research on the following core areas:

•   Pattern and control of primary production
•    Spatial and temporal distribution of populations
     selected to represent trophic structures
•   Pattern and control of organic matter accumulation
     and decomposition in surface layers and sediments
•   Patterns  of inorganic inputs and movements of
     nutrients  through soils,  groundwater and surface
     waters

LTER measurement increments vary from hourly to
annually, based on indicator  of interest.  Some of the
indicators included are listed below:
Climate:
•  meteorology

Precipitation/deposition:
•  wet deposition

Water:
•  discharge
•  organic contaminants
•  inorganic chemistry
•  trace metals
snow
dry deposition
sediment load
aquatic biota
sediment chemistry
habitat
National  Water-Quality  Assessment   Program
(NAWQA): NAWQA, which is  managed by USGS,
provides information on water resources in 60 river
basins and aquifers which together account for 60 to 70
percent of the nation's water use and population served
by public water supplies. The NAWQA goal is to iden-
tify the common environmental characteristics associat-
ed with the occurrence of key water-quality constituents
and to explain their differences. To make the program
cost effective and manageable, intensive  assessment
activities in each of the study units are conducted on a
rotational basis, with one-third of the study units being
studied intensively at any given time. For each study
unit, 3- to 5-year periods of intensive data collection
and analysis are alternated with 5- to 6-year periods of
less intensive study  and monitoring.  Coinciding  with
the study-unit  investigations are national synthesis
assessments. Generally, two to four national synthesis
topics are studied at a given time. Two issues of nation-
al priority—the occurrence of nutrients and pesticides
in rivers and ground water—were selected as the first
issues, followed by the occurrence and distribution of
volatile  organic compounds (VOCs).  Collectively,
NAWQA measures:
Water:
•  discharge
•  organic contaminants
•  inorganic chemistry
•  trace metals
sediment load
aquatic biota
sediment chemistry
habitat
Marine/coastal:
•  salinity/freshwater flux
•  zooplankton
•  nutrients/contaminants
•  submerged/coastal habitats

Soils:
•  texture
•  mineralogy
•  structure

Vegetation:
•  growth rate
•  above-ground biomass
•  nutrient availability

Animals:
•  food source/quality
•  species/range/population

Miscellaneous:
•  fire
chlorophyll
animals
sediment
chemistry
climate
faunal biomass
recruitment
species/cover/range
recruitment
Marine/coastal:
•  salinity/freshwater flux
•  nutrients/contaminants

National  Surface  Water  Survey  (NSWS):  The
National Surface Water Survey  (NSWS) sampled the
chemistry of 2,311 lakes and 433 streams nation-wide
between 1984 and 1986. The objective was to charac-
terize and classify these aquatic systems in terms of
their acidic sensitivity, chemistry, biological and bathy-
metric  features.  The  Survey was  divided  into  the
National Lake Survey and the National Stream Survey.
Closely  related studies  included the  Long-Term
Monitoring Project  (1982-present) and  the  Episodic
Response Project (1988-1990). These data are particu-
larly useful as a baseline to compare with more recent
data to  assess  whether any significant changes have
taken place since the implementation of the Acid Rain
Program.

National Lake Survey. The Eastern Lake Survey - Phase
I (ELS-I), conducted in the fall  of 1984, was the first
                                                    25

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part of a long-term effort by the U.S.  Environmental
Protection Agency National Surface Water Survey.  It
was designed to quantify the acid-base status of surface
waters in the United States in areas expected to exhibit
low buffering capacity at a single point in time. The
effort was in  support of the National Acid Precipitation
Assessment Program.  The survey involved  a  three-
month field effort in which 1,612 probability sample
lakes and 186 special interest lakes in the Northeast,
Southeast, and Upper Midwest regions of the United
States were sampled.

The Eastern Lake Survey - Phase II (ELS-II), conduct-
ed in the spring, summer and fall of 1986, focused on
the northeastern United States. ELS-II involved the re-
sampling of a subset of lakes in the northeastern United
States sampled in ELS-I to determine  chemical vari-
ability and biological status. Furthermore, within-index
period variability was examined in the  fall of 1986 to
provide insight concerning the ability to detect chemi-
cal changes over time, and the precision of the estimates
of the number of acidic lakes from Phase I.

The Western Lake Survey-Phase I (WLS-I), conducted
in the fall of 1985, involved 719 lakes in  the western
states (CA, OR, WA, Rocky Mountain states).

The parameters  measured  in Phase  I  included: alu-
minum, alkalinity, acid neutralizing capacity, calcium,
dissolved inorganic carbon, dissolved organic carbon,
chloride,  color, specific conductance, iron, potassium,
magnesium, manganese, ammonium, sodium, sulfate,
nitrate, pH, total phosphorus, silica, turbidity, water
chemistry. The parameters measured in Phase II includ-
ed: selected re-survey of chemistry survey of Phase I,
lake bathymetry, spring,  summer, and fall  seasonal
chemistry, summer chlorophyll, and summer zooplank-
ton species / abundance.

National Stream Survey. The National  Stream Survey
(NSS-I) primary goals were (1) to determine  the per-
centage, extent (number, length, and drainage area),
location, and chemical characteristics of streams in the
United States that are presently acidic, or that have low
acid  neutralizing capacity  (ANC) and  thus  might
become acidic in the future, and (2) to identify streams
representative of important classes in each region that
might be selected for more intensive study or long-term
monitoring.  The  parameters measured  included: alu-
minum, alkalinity, acid neutralizing capacity, calcium,
carbonate, color, specific conductance, dissolved inor-
ganic carbon, dissolved organic carbon, bicarbonate,
potassium,  magnesium, ammonium, sodium, nitrate,
total nitrogen, pH, total phosphorus, silica, total sus-
pended  solids,  and  turbidity.  NSS  datasets  can be
accessed    through    the   following    website:
http://www.epa.gov/emfiulte/html/otherdata/napap/nss/
index.html
General  Steps  for  Conducting
Quality Assurance  (QA)
Data
Quality assuring data is necessary in order to provide
some level of confidence that the data are representing
what is actually occurring in the environment. Use of
data that has not been formally quality-assured may be
necessary  when quality-assured data is not adequate or
when non-quality-assured data sets useful to the assess-
ment  are  available. Data  that has  not been quality-
assured should be indicated as such when  used and
treated cautiously.

Several quality checks can be applied to increase confi-
dence in the data.

•   Check with data managers for documentation and
    informal evaluation of the data base
•   Examine the data  base for prominent  anomalies
    (e.g. missing data,  negatives, spikes)
•   Seek  explanation for anomalies from data man-
    agers
•   Fill data gaps  or  omit periods without reliable
    information
•   Obtain additional formal or informal expert evalu-
    ation of the data patterns
•   Derive a rough estimate of data uncertainty (e.g.
    range of error/accuracy/reliability) for the data set

Application  of all of these steps would constitute a
thorough evaluation of the data set.

The extent to  which  a data  base  can  be  evaluated
depends on  the assessment needs and the  resources
available.  For scoping  assessments,  a detailed  evalua-
tion of the data as noted above may not be needed.
Bringing in additional expert evaluation  and develop-
ment of well-defined uncertainty bounds is less critical.
Similarly if resources are very limited, the last two steps
may not be feasible. At a minimum, it is important to
scan the data for prominent anomalies and omit them to
avoid obvious errors in  the analysis.
                                                   26

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section vi.     Identifying  Appropriate  Analytical
                                            Tools
        Relationships between emission changes, pollu-
        tant concentrations in the atmosphere, deposi-
        tion of pollutants and the impact on ecological
and other resources can be  quantified  and predicted
through the  use  of computer models and associated
databases. Models range from those that describe links
between one receptor area and one source to others that
describe the complex regional scale relationships, con-
sidering the influence of all major sources and project-
ing a wide variety of receptor impacts throughout the
region. Some models address changes over short time
periods such as episodes, others focus on longer time
periods, and some attempt to do both. Usually, models
focus on one part of the overall assessment. Emission
models develop emissions data for input into air quali-
ty models. The output of the air quality models are then
translated into impacts  using a variety of models char-
acterizing human health and ecological  welfare and
other effects.  Selection of the best model framework or
best set of models depends on the question being asked.
Resources and availability of the models also are fac-
tors.

It is important to keep  in mind the limitations of mod-
eling. Models are valuable tools that can be used to pre-
dict future scenarios or to better understand  changing
parameters,  but they cannot replace actual field mea-
surements that monitor the current status of the envi-
ronment. Models must be verified and tested against
observational data to ensure that they accurately reflect
what is measured in the "real world"  (this will be dis-
cussed in more  detail  later in  this section).  This
becomes complicated  when working with  complex
models  that rely  upon  outputs from other models.
Combining  models also multiplies the uncertainty of
the final results and can make them less reliable.

A range  of models  for drawing links between emis-
sions,  air concentrations, deposition  and  impacts are
summarized in Table 2. Input data requirements, model
outputs, capabilities and limitations, and references for
the models are included. This set is not inclusive; rather,
it provides models representative of the full range of
outputs from emissions to effects.
Air Quality

As described in the previous section, air quality data is
available from various national networks.  Similarly,
deposition data is available from large-scale networks.
Trend analysis—examining emission changes and air
quality and deposition changes over a period of time—
provides a way of exploring how impacts are  affected
by changes in emissions. When observations are  not
adequate, either because of the locations of monitors or
when the samples were collected, modeling can provide
data for the trend analysis. Air quality models are most
useful for examining future conditions. A number of
models have been evaluated by EPA and are available
on the EPA web site. These models range in  applica-
tions from individual  emissions sources  to multiple
sources and to larger regional scale analysis.

The  most comprehensive,  extensively  evaluated and
applied  acid deposition  model is the Regional Acid
Deposition Model (RADM). The model was developed
during  the 1980s and  is used in the NAPAP assess-
ments. RADM continues to be one of the primary mod-
eling systems used to characterize  and address acid
deposition and related  air quality issues in the Eastern
US. RADM is also used to predict or project the effec-
tiveness of proposed pollutant reduction legislation on
acid deposition and visibility.

One of the applications of RADM has been to develop
what are called "principle airsheds." Principle  airsheds
are  conceptual boundaries that separate areas contain-
ing sources that deposit efficiently to a particular recep-
tor region from those that do not. Airsheds are different
from watersheds, which  have actual physical bound-
aries. Any given source is in a single watershed, but a
single source can  be in  many airsheds depending on
how many receptor regions it significantly influences.
In addition, sources that are not in a particular receptor
region's airshed  can still contribute small  amounts of
deposition to that receptor.  Airsheds can be developed
for  waterbodies,  such  as  the  Chesapeake  Bay  or
Albemarle Sound, or for terrestrial ecosystems such as
the  Adirondack  region of New  York  or  Shenandoah
National Park. These airsheds do not represent the only
                                                 27

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-------
source areas for emissions that impact these receptor
regions; rather they represent the area from which emis-
sions are frequently and easily transported to the recep-
tor region.Airsheds are useful conceptual and commu-
nications tools but they must be used carefully with a
clear understanding of their underlying assumptions.

A selection of RADM results from a recent assessment
is provided in the Appendix. The results illustrate how
acid deposition, aerosol  concentrations and visibility
are expected to change as a result of reductions in emis-
sions. The results also provide information that can be
used in individual state and tribal assessments of the
impacts of proposed legislation on human health and
the well-being of ecosystems in their particular regions.
The RADM results are described in more detail in the
Appendix. Additional information on RADM-derived
regional acid deposition impacts for the Eastern US is
located  at  http://www.sph.unc.edu/ies/airpoll.htm.

For those doing assessments west of the Mississippi
River, there are two models that can be used: Models-
3/CMAQ  and REMSAD.  Until recently, air quality
models typically addressed only single pollutant issues.
Models-3/CMAQ (Community Multiscale Air Quality)
was  developed by EPA's National Exposure Research
Laboratory to address the broad scope  of  the 1990
Amendments and the complex interaction among pollu-
tants. CMAQ is  still  undergoing evaluation  but is
expected to be available shortly.

The  Models-3  framework  provides  tools to prepare
emissions and meteorological inputs, define emissions
control strategies, project future emissions inventories,
execute meteorological models, delineate a geographic
domain, select alternative atmospheric chemical reac-
tion mechanisms,  set vertical and horizontal grid reso-
lutions, and manage a series of air quality model runs.
CMAQ is applied  through  the Models-3  system.
CMAQ contains  state-of-the-science  simulations of
atmospheric transport  processes, atmospheric  chem-
istry, aerosol dynamics and chemistry, cloud chemistry
and dynamics, and deposition processes. A key aspect
of the Model-3/CMAQ system's structure is its flexibil-
ity to incorporate scientific and modeling advances, to
test alternative modeling approaches, and to link with
human and ecosystem exposure models. Models-3 is
available at http://www.epa.gov/asmdnerl/models/.

REMSAD was developed by ICF Consulting for the US
EPA. It is based on an Eulerian (grid) approach and may
be applied at scales ranging from a single metropolitan
region to a continent containing multiple urban areas. It
was designed to be capable of simulating the complex
long-range transport and deposition of atmospheric pol-
lutants to aquatic environments, and to assess the rela-
tive impacts of alternative control strategies. Although
initially developed to study the transport and removal of
airborne toxics, the interdependence of the processes
which also control the formation and removal of parti-
cles  was  recognized,  and therefore  the  model was
designed for both toxics and particulate matter applica-
tions. REMSAD is non-proprietary and can be run on a
desktop computer. More information about REMSAD
is  at http://www.epa.gov/ttn/scram/ under  "alternative
models."
Ecological  Impacts

The  endpoints of assessments—stream pH, visibility,
human health, etc.—are  often known as "receptors."
Relating changes in emissions to  resulting changes in
key receptors can be challenging, given the complexity
of the environment and the slow pace of changes in eco-
logical systems. Whereas  comparisons of emissions and
air quality should be made using  data from consistent
time periods/years; ecological impact models translate
concentration and deposition changes into future esti-
mates of ecological  changes.  Since  many  ecological
changes occur over many years, information from air
quality models has to be adapted for use in these longer-
term time frames. Make sure that the model you choose
to use can provide the correct outputs (e.g. does it pro-
vide the streamwater chemistry parameters you need?)
and that  it can be applied to the correct spatial scale.
Many ecological models  are designed for small areas,
and changes  or  additional runs may be necessary to
extrapolate to the area in  question.

MAGIC  is one of the models developed to estimate
acidification of lakes and streams  in response to sulfur
deposition  is MAGIC  (Model of  Acidification of
Groundwater in  Catchments).  It was  the  principal
model used by NAPAP to estimate future damage to
lakes and streams in the eastern United States. MAGIC
is a lumped-parameter model of intermediate complex-
ity, developed to predict the long-term effects of acidic
deposition on surface water chemistry. The model sim-
ulates soil solution chemistry and  surface water chem-
istry to predict the monthly and annual average concen-
trations of the major ions in waterbodies. At the heart of
MAGIC  is the size  of the pool of exchangeable base
cations in the soil. As the fluxes to and  from the pool
change over time due to changes in atmospheric depo -
                                                   30

-------
sition,  the chemical  equilibria between  soil and soil
solution shift to give changes in surface water chem-
istry. Although there are some uncertainties with regard
to the model, particularly concerning watershed nitro-
gen dynamics, MAGIC provides a generally accurate,
well-tested, and widely accepted tool for modeling the
response of  surface water chemistry to sulfur deposi-
tion.

PnET-BGC is an  integrated  model that  simulates the
concentrations and transport of major elements, includ-
ing nitrogen, in forest vegetation, soil, and water. The
model  was formulated by linking  two  submodels  to
allow for the simultaneous simulation of major element
cycles in forest and interconnected aquatic ecosystems.
These submodels include 1) PnET, a simple generalized
model of monthly  carbon, water, and nitrogen balances
which provides estimates of net primary productivity,
nitrogen uptake, and  water balances (Aber et al 1997;
Aber and Driscoll 1997); and 2) BGC, a new submodel
which expands PnET  to include vegetation and organic
matter  interactions of other elements (including calci-
um,  magnesium,  potassium, sodium,  silica,  sulfur,
phosphorous, aluminum, and chloride), abiotic soil pro-
cesses, solution speciation, and surface water process.
PnET-BGC uses measured and estimated data on mete-
orology and atmospheric deposition. The model is run
for several hundred model years prior to the advent of
anthropogenic deposition to allow the forest, soil, and
water to come to steady-state conditions. The model
simulates estimates of changes in atmospheric deposi-
tion from 1850 to the present day. Future scenarios of
changes in atmospheric deposition are simulated using
projections  provided  from simulations  with the
Regional Acid Deposition Model (RADM) based on
model runs of air emission control scenarios.
General  Steps for Conducting  Model
Quality Assurance

Many standard models have been documented and eval-
uated for use in various applications. Models that have
not been thoroughly tested but are considered appropri -
ate for the assessment can be evaluated using a hierar-
chy of methods. The most familiar approach is direct
comparison  with observational data. This  approach,
however, is  often not adequate for evaluating models
because the  necessary observational data may not be
available or may not be  strict enough for testing the
model for a specific application. Often the observation-
al data itself may already be earmarked for use with the
model in doing the assessment.

Several steps can be applied to gain further confidence
in the model:

•   Compare model results with observational data if
    the observational data is available.
•   Examine the extent to which models and observa-
    tions produce the  same  associations among key
    variables.
•   Check  how appropriately the model responds  to
    changes in key input parameters such as emissions.
•   Examine documentation to see how the model is
    behaving in simulating key variables compared to
    simulations of other model studies.

•   Check scientific and technical reviews if available
    to see how  well the model integrates current scien-
    tific knowledge for the current application purpos-
    es.
•   Seek expert reviews of the models.

All of these  steps performed together would constitute
a thorough  review of the model. In cases where this
level of evaluation is not needed,  as in a scoping study
or where resources are not available for an in-depth
evaluation, then a limited evaluation should be done. At
a minimum,  the model should be executed for a variety
of conditions to check how robust it is under a range of
parameter values, such as emissions, that are relevant to
the assessment questions.
                                                   31

-------

-------
 section vii      Integrating  Information  to  Assess
                                      Response
at
3
cm
        Assessing the effectiveness of the Acid
        Rain Program requires the ability to
        relate  changes  in  emissions  to
changes in deposition and to changes in sensi-
tive receptors. An assessment can focus on any
one of these steps, or it can be integrated and
look at all of them. The end-goal of the techni-
cal  analysis is to evaluate how well  current
emission control  efforts  work in reducing
human and environmental impacts and to facil-
itate and assess the potential need  for further
actions. These assessments will almost certain-
ly receive public scrutiny, and must be able to
withstand the normal processes of evaluating
financial and other costs associated with pro-
posed management actions.  In addition, it will
be important to establish the level of certainty
that can be placed on the finding. This section
illustrates possible methods of analyzing spatial
and temporal patterns and then relating these
patterns and changes to ecological  impacts
using  statistical and  other assessment tech-
niques.
Analyzing Spatial and Temporal Patterns. Changes
in  spatial  patterns, often  illustrated using  GIS
(Geographic Information System) maps and time series
trends, expressed in graphical formats, provide a useful
indicator of the effects and of the effectiveness of the
Title IV.  Ideally, pre-regulatory concentrations, emis-
sions and deposition data will be obtained and used for
comparison and quantification  of  the  magnitude of
changes.  At the national  scale there was a large
decrease in sulfur dioxide emissions during the 1970's
and early  1980's,  with additional decreases  in  the
1990s. About a 30% reduction occurred in the  eastern
U.S. between 1980 and 1995. This is due in part to the
fact that utility companies had already started to reduce
their emissions of sulfur dioxide. If the site is  located
in the eastern U.S., data may show a dramatic decrease
in SC>2 emissions in 1995, which is consistent with the
first year of compliance under  Title IV.

Trend analysis should be done over several years; year-
to-year trends are often "noise" and not reliable in the
long-term. However, a comparison of national deposi-
 Figure 11. Sulfate Deposition at Two NADP Sites from
 1978 to 1997.
    40.0
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0
    36.0 -
    32.0 -
    28'° 1
    24.0 J
    20.0 H
    16. OH
    12.0 -
     8.0
                                          ding RidgVf PA
                                        HubbaniBraaltJM
       1977   1982   1987   1992   1997
    Source: NADP website (http://nadp.sws.uiuc.edu/)
     tion maps from 1994 versus 1995 displays the expected
     drop in overall  SC>2 concentration and sulfate deposi-
     tion expected from the large reductions in sulfur diox-
     ide emissions that took place in 1995.

     This relationship is even more apparent when compar-
     ing the longer-term trend  in deposition between 1980
     and 2000. The 1994-1995 drop in total  annual sulfate
     deposition in response to Title IV regulations stands out
     in  Figure 11 above. Monitoring data  from Leading
     Ridge, PA showed an especially marked drop in 1995.
     In addition to temporal variability, there  is spatial vari-
     ability in the response as well. The response of deposi-
     tion to emissions followed a somewhat different pattern
     at Hubbard Brook, NH, but a sharp reduction after Title
     IV took effect is still apparent.

     Bivariate Relationships. Bivariate plots are often used
     to examine the  relationship between emissions (e.g.,
     SC>2 emissions on  the x-axis) and the  concentrations
     and/or total deposition  of the acid derivative sulfate
     (SO/f ) in precipitation (on the y-axis). In the example
     above, Driscoll et al. (1998a) found a linear relationship
                                                 33

-------
accounting for half of the variation (where r = 0.48 to
0.62)  at  the  Hubbard  Brook Watershed  in New
Hampshire.  This implies that cutting emissions will,
with  a 48-62%  certainty,  result in  a proportional
decrease in rain and stream concentrations of sulfate.

To further illustrate these analysis techniques, dNADP
sulfur and precipitation data was downloaded from the
NADP  website http://nadp.sws.uiuc.edu/).  The data
was  plotted using maps, time  series,  and bivariate
graphs to facilitate the analysis.

There is a known positive relation between the  annual
total precipitation  and the total deposition.  At the PA
and NH locations cited above, however, the relationship
for the 1978 to 1997 period is not a particularly strong
one, or at least highly variable as you can see (Figure
12).

The precipitation/SC>4 deposition relationship has sev-
eral implications: (i) the significantly higher precipita-
tion at the PA station in 1996 (32% increase, or a total
of 152.4 mm ppt) compared to 1995 (115.8 mm ppt) can
explain much of the increased total annual SO 4 deposi-
tion in  1996 relative to the year earlier; (ii)  the total
annual  864 deposition dropped in 1997 compared to
1996 and was  similar to that of 1995; this was consis-
   Figure 12. Relationship Between Sulfur Deposition
   and  Precipitation  at  Two NADP Sites Over the
   1978-1997 Interval.
     40.0
     36.0 -

     32.0 -

     28.0 -
  g  20.0 1
  £  16. OH
  13
  l/J
     12.0 H
      8.0
ding ttidnv, P4
                                       Hubbard Brook. NH
         38  58   78  98  118 138  158
                   Precipitation
                  (cm, annual total)

    Source: NADP website (http://nadp.sws.uiuc.edu/)
                 Essential Steps for Integrating Data

                 Define the key questions and the needs of the
                 manager/decision maker.  The  key  questions
                 identified in Section IV form the focus of the anal-
                 ysis of the scientific data and related  information.
                 The assessment is designed to support the evalua-
                 tion and decision-making processes.

                 Acquire and analyze necessary emissions,  con-
                 centration, and deposition data. This is the  vital
                 first step  in analyzing the impact of changes  in
                 emissions  in response to  Title  IV.  Establishing
                 these relationships is important since there is  gen-
                 erally  good supporting evidence  (NAPAP, 1990)
                 that reductions in emissions are reflected "down-
                 stream" (e.g.,  decreased air concentrations  and
                 deposition rates of acidic compounds).

                 Acquire    and   analyze  ecosystem  data.
                 Acquisition and analysis of ecosystem data is the
                 next, and perhaps more challenging, step. Data on
                 explicit ecosystem indicators are limited and  link-
                 ing  impacts to deposition requires integration  of
                 information on different  temporal  scales possibly
                 covering large source areas.
tent with the total precipitation in 1997 (107.2 mm
ppt) being similar to that in 1995; and (iii) the total
annual precipitation in  1994 (106.0  mm ppt) was
similar to that of 1995, discounting  the likelihood
that the 1994 -1995 drop in SO4 deposition was due
to a difference in rainfall between those years.
Integrated Analysis.  Another  common  analysis
technique involves plotting the emissions over a one
to three-decade interval simultaneously with ambi-
ent  air concentrations,  total  deposition rates, and
typically, a response such as change in water chem-
istry or soil cation base capacity. Likens et al (1996),
Driscoll et al (1993, 1995, 1998a), Lawrence et al
(1995), and Shortle et al. (1997) provide examples
of this approach.

In Figure  13, annual average levels of the ambient
air SO 2 concentration (Allegheny County, PA), the
SC>4 deposition rate (Leading Ridge, PA), and the
streamwater 864 concentration  (Young Woman's
Creek at Renovo, PA)  are plotted  simultaneously
over the 1977 to 1997 interval.

This integrated  analysis example  shows  a  direct
                                                    34

-------
     Figure 13. A Comparison  of Ambient Air Quality,
     Deposition, and Streamwater Data from 1977-1997
     at Selected Sites in Pennsylvania.
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               Year
                                          1997
   Sources:
   Ambient air SC>2- http://www.epa.gov/aqspubll/annual summarv.html
   Deposition Rate 804:
     http://nadp.sws. uiuc.edu/nadpdata/siteinfo. asp?id=PA42&net=NADP
   Streamwater 804 Concentration:
     http://wwwrvares.er.usgs.gov/wqn96cd/wqn/wq/formats/wq.fmt
Monitoring locations. The location of sample
sites and/or summary area (as in the case of the
county average used for ambient air quality)
were not spatially consistent,  e.g.,  data were
not necessarily  available for  any  one  geo-
graphical location of interest.

Years for which data is available. The select-
ed starting and ending dates limited the num-
ber of sites for which the analysis could be
done; not all  stations  selected started in our
year of choice (1997).  The data on Streamwater
values for 1996 and 1997 were not on the Web
and  were  accessed  by  calling the  USGS
database manager.

Annual averages.  The  number of samples
and/or the months of observations to represent
an annual average varied in  all cases, suggest-
ing that a robust analysis would require  con-
siderable commitment of time and access to
appropriate statistical expertise.

Locating the  correct  database.  A consider-
able fraction of the time (e.g., half to  two-
thirds) to complete  the analysis and construct
the graphs was spent in locating and accessing
the appropriate databases. Although  a large
potential choice exists, the number of suitable
databases were narrowed to a  smaller number
in practice.
comparison  between changes that occurred  along the
sequence of emission  to  air quality to deposition to
stream response. It also illustrated the relative ease of
access to websites with acid rain data, and of the limi-
tations and difficulties likely to be encountered.

Limitations of Using Web Databases

Some of the limitations and difficulty in using the Web
databases, such as those used in these analyses, are as
follows:

Changing  analysis  methods.  In the case  of  some
parameters,  the laboratory methods changed over the
two-decade  interval  so that values were not strictly
comparable, and strict continuity was lost. Contact with
the database  manager proved  valuable  /  necessary
where choices had to be made and/or where questions
arose as to the significance  of sampling or laboratory
methods changes.
                                                   Confidence intervals.  Statistical  confidence
                                           (e.g., sd, se, range) of each sample point was not explic-
                                           it  /  immediately  available,  but could  probably be
                                           obtained by accessing the original sample data.

                                           These and other analytical challenges have been dis-
                                           cussed for this kind of integration by Clow et al (1999:
                                           ftp://bqsnt.cr.usgs.gov/manilles/Clowfact3.pdf).  Their
                                           results are encouraging since they were able to observe
                                           clear responses to emissions reductions when long time
                                           series were used and where the data had been rigorous-
                                           ly  screened and appropriately transformed  to achieve
                                           methods consistency.

                                           Even with the very rudimentary analysis in the "test"
                                           illustration of Figure 13, some consistency in the depo-
                                           sition and Streamwater response to decreasing ambient
                                           SC>2 levels can be discerned. The sharp changes in 1995
                                           in  response to Title IV regulations are unambiguous in
                                           all cases. Note that the vertical scales differ between the
                                           three parameters and can influence the apparent degree
                                                    35

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of change.  To achieve simplicity of scale, the ambient
air quality was multiplied by 3,000. This has the effect
that the marked air quality response may be somewhat
exaggerated relative to the deposition and streamwater
trends. Microsoft Excel  (and other  graphics routines)
enable the user considerable flexibility in scaling final
presentations. Trend lines can be added; those shown
are second order polynomials. Correlations  and  other
statistics are easily achieved. The correlations between
air quality and deposition, for example, was r =0.65;
between air quality and streamwater response, r = 0.51.
Although  the  correlation  between deposition  and
streamwater was significant (also r = 0.51), the soils in
the watershed are likely to strongly influence the degree
of response depending on the extent to which sulfur
oxides are retained in soil and vegetation.
                                                     36

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          section VIM.    Communicating  Results
       Effective communication with key people and
       organizations is a critical element in the suc-
       cess of ecological assessments. A communica-
tion strategy is necessary to make sure the important
information gets to diverse audiences and to integrate
varied approaches and formats for effective  communi-
cation. A highly effective method for designing a com-
munication strategy is based on two steps:  (1) assess-
ing communication needs and potential responses, and
(2) developing detailed guidelines for implementing the
most effective responses.

The needs assessment and guidelines for responses are
based on  the answers to four questions:
•   WHO do the assessment managers need to  com-
    municate with?
•   WHY do the assessment managers need to  com-
    municate with them?
•   WHAT information must be communicated?
•   HOW can it be communicated most effectively?

The answers to the "who, why, and what" questions are
developed through discussions with scientists,  man-
agers, policy makers and other  key people.  Those
answers provide a starting point for developing the
"how" answers. These questions and answers provide
an analytical matrix for defining the assessment man-
agers' communication goals  and the most effective
ways to accomplish them.

The "WHO" answers enable the assessment managers
to target  the most relevant audiences instead of  dissi-
pating their resources in communication efforts that are
too broad or diffuse. In most situations where state and
tribal agencies are assessing ecological responses to
emission  reductions  achieved under the Acid  Rain
Control Program, the most important audiences will be
policy makers, such as members of state legislatures,
Congress, and the general public. However, it is impor-
tant not to overlook other key groups such as environ-
mental advocacy organizations and  industry  trade
groups.
The "WHY" answers must provide precise definitions
of the various and sometimes diverse goals of the dis-
semination effort in order to determine what informa-
tion must be communicated. For example, one goal may
be to  increase the  general public's awareness of the
broad problems involved in an environmental policy
issue,  while another may be to inform legislators about
assessment results related to a bill that is being consid-
ered.

The "WHAT" answers must propose various types and
levels of information that are needed to achieve the
goals that have been defined. For example, broad expla-
nations  of  ecological problems  and general policy
options may  be presented to the general public, while
detailed scientific conclusions related to specific provi-
sions of a particular bill may be more useful to legisla-
tors.

The "HOW" answers will provide detailed guidelines
for implementing the communication strategy.  Once the
"WHO", "WHY" and "WHAT" have been defined, the
services of an experienced communication professional
can be very  valuable in selecting the most  effective
communication media and methods to reach  precisely
targeted audiences with carefully selected information.
For example, the best ways to communicate  with the
citizens of a densely  populated eastern state  may  be
quite  different from those that will most effectively
reach  the members of a tribe scattered across a western
tribal nation.

A well-designed strategy will define the  assessment
managers' communication needs and provide a priori-
tized list of specific responses to those needs. It also
will specify the professional skills and experience need-
ed to  implement the responses effectively. It will pro-
vide managers and those who have been assigned day-
to-day responsibility for communication with the nec-
essary information and resources to organize, oversee,
and carry out communication  activities knowledgeably
and effectively.
                                                 37

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            section  ix.     Examples of State-level
                     Ecological  Assessments
Minnesota
The  Minnesota Department  of  Natural Resources
(DNR)  has  developed  tools  (e.g.,  Geographic
Information  Systems,   Ecological  Classification
Systems, environmental indicators, and biological sur-
veys) that describe and predict how resources interact
within ecosystems, and  how they respond to  human
uses. The DNR is applying these tools over large geo-
graphic areas over long time frames. One program that
has emerged from this is the Minnesota Environmental
Indicators Initiative (EII). This project will create the
framework  for an integrated, statewide network for
selecting and monitoring  environmental indicators. The
EII will provide the first statewide  network for (1)
understanding and forecasting ecosystem health status
and trends,  (2)  assessing the ability of ecological sys-
tems to provide  resource benefits,  (3) anticipating
emerging environmental  problems, and (4) monitoring
progress in maintaining and restoring ecosystems.

(http://www.dnr. state.mn.us/eii/)
Vermont
The Vermont Forest Ecosystem Monitoring (VForEM)
is a network of cooperators from government, academ -
ic and private sectors who gather and pool information
on Vermont's forest ecosystem.  Using a multi-disci-
plinary approach to understanding forest  ecosystems,
over  40 cooperators from  various disciplines work
together at two sites, Mount Mansfield  and the Lye
Brook Wilderness Area, to integrate research and mon-
itoring programs. This includes the integration of data
from multiple data sets maintained in the VForEM Data
Library, and results in a holistic view of ecosystems.
VForEM projects fall into six general categories:
   Terrestrial Flora
   Surface Water
   Geology and Soils
Terrestrial Fauna
Atmosphere
Human Impact
(http ://www.uvm. edu/~snrdept/VMC/index.html)
                          Maryland
                          In  1987,  the  Maryland  Department  of  Natural
                          Resources designed the Maryland Biological Stream
                          Survey (MBSS) to provide information on the ecologi-
                          cal consequences of acid deposition and other human-
                          related impacts. MBSS is a long-term monitoring pro-
                          gram designed to describe the current status of aquatic
                          biota, physical habitat and water quality in first, second,
                          and third order non-tidal streams. MBSS data will also
                          be used to identify probable causes of ecological degra-
                          dation, investigate relationships between human activi-
                          ties and ecological response, and identify areas in need
                          of protection or restoration. Approximately 1,000 sites
                          were sampled between 1995  and  1997.  Monitoring
                          parameters include the following:
                            pH
                            Nitrate
                            Temperature
                         Sulfate
                         Conductivity
                         Dissolved Oxygen
                          • Dissolved Organic Carbon
                          • Acid Neutralizing Capacity

                          (http://www.dnr.state.md.us/streams/acid/index.html')
Maine
Maine's Department of Environmental Protection is in
the last stages of an assessment done in collaboration
with  the  Northeast States for  Coordinated Air Use
Management (NESCAUM) and EPA's Clean Aire
Markets Division.  The assessment used the RADM
model to correlate sulfate and nitrate deposition in New
England with upwind emissions. Due to the variability
in data of one or a few deposition monitoring sites, this
assessment chose a regional analysis of sulfate and
nitrate deposition of the New England area. Total pre-
cipitation and total  deposition data sets were combined
and normalized to a mean of 1  (Shannon, 1999).
Analyses  indicate a correlation between emissions and
a drop in sulfate deposition, but there was no change in
nitrate deposition. Further analysis indicates a positive
correlation between the decrease in sulfate deposition in
New England and a change in lake chemistry in Maine.

(http: //www. state. me. us/dep)
                                                39

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                           Section X.
References
Clow, D.W and M.A. Mast. 1999. Trends in precipitation and stream-water chemistry in the northeastern United
States, water years 1984-1996. United States Geological Survey Fact Sheet 117-1999, July 1999.

Driscoll, C.T., K.M. Postek, D. Mateti, K. Sequeira, J.D. Aber, W.J. Kretser, M.J. Mitchell, and D.J. Raynal.
1998a. The response of lake water in the Adirondack region of New York to changes in acidic deposition.
Environmental Science and Policy 1: 185-198.

Driscoll, C.T., G.E. Likens, and M.R. Church 1998b. Recovery of surface waters in the northeastern U.S. from
decreases in atmospheric deposition of sulfur.  Water, Air, and Soil Pollution 105: 319-329.

Driscoll, C.T, K.M. Postek, W. Kretser, and D.J. Raynal. 1995. Long-term trends in the chemistry of precipitation
and lake water in the Adirondack region of New York, USA. Water, Air, and Soil Pollution 85: 583-588.

Driscoll, C.T., and R. Van Dreason. 1993. Seasonal and long-term temporal patterns in the chemistry of
Adirondack Lakes. Water, Air, and Soil Pollution 67: 319-344.

Heggem, D., S.A. Alexander, and J.E. Barnard 1993. Forest Health Monitoring 1992 Activities Plan. Report
EPA/620/R-93/002. U.S. Environmental Protection Agency, Office of Research and Development, Washington,
DC.

Lackey, R.T. 1997. If Ecological  Risk Assessment is the Answer, What is the Question? Human and Ecological
Risk Assessment 3(6): 921-928.

Lawrence, G.B., M.B. David, and W.C. Shortle. 1995. A new mechanism for calcium loss in forest-floor soils.
Nature 378:162-165.

Likens, G.E., C.T. Driscoll, and D.C. Buso.  1996. Long-term effects of acid rain: Response and recovery of a for-
est ecosystem. Science 272:244-246.

Middleton, P. 1997. Background Document on Air Quality Data Compatibility. Prepared for the Commission on
Environmental  Cooperation. RAND Environmental Science & Policy Center, Washington, D.C.

NAPAP. 1998. NAPAP Biennial Report to Congress: An Integrated Assessment. U.S. National Acid Precipitation
Assessment Program, Silver Spring, MD. http://www.nnic.noaa.gov/CENR/NAPAP/NAPAP_96.htm

NAPAP. 1990. Acidic Deposition: State of Science and Technology, Volumes I-IV. National Acid Precipitation
Assessment Program, Washington, DC.

National Research Council. 1999. Ecological Indicators for the Nation. National Academy Press, Washington, DC.

Shannon, J. 1999. Regional trends in wet deposition of sulfate in the United States and SC>2 emissions from 1980
through 1995. Atmospheric Environment 33(5):807-816.

Shortle, W.C. and E.A. Bondietti. 1992. Timing, magnitude, and impact of acidic deposition on sensitive forest
sites. Water, Air, and Soil Pollution 61: 253-267.


                                                  41

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Shortle, W.C., K.T. Smith, R. Minocha, G.B. Lawrence, and M.B. David. 1997. Acidic deposition, cation mobiliza-
tion, and biochemical indicators of stress in healthy red spruce. Journal of Environmental Quality 26:871-876.

Stoddard, J.L., C.T. Driscoll, J.S. Kahl, and J.H. Kellogg.  1998. Can site-specific trends be extrapolated to a
region? An acidification example for the Northeast. Ecological Applications 8(2):288-299.

Stoddard, J.L., C.T. Driscoll, J.S. Kahl, and J.H. Kellogg.  1998. A regional analysis of lake acidification trends for
the Northeastern U.S., 1982-1994. Environmental Monitoring and Assessment 51:399-413.

U.S. Environmental Protection Agency. 200. Analysis of the Acid Deposition and Ozone Control Act (S.172).
Prepared for the Senate subcommittee on Clean Air,  Wetlands, Private Property and Nuclear Safety.
http://www.epa.gov/airmarkets/articles/

U.S. Environmental Protection Agency. 1999. The Benefits and Costs of the Clean Air Act, 1990-2010. EPA
Report to Congress EPA-410-R-00-001
U.S. Environmental Protection Agency. 1998. Regulatory Impact Analysis for the NO^ SIP Call, FIP, and Section
126 Petitions, EPA, ARD, September 1998 volume 1 chapter 4. http://www.epa.gov/capi/ipm/npr.htm
                                                   42

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    Appendix A.  Frequently-Raised  Issues and
                                     Questions
This section discusses some of the questions that are
frequently raised when conducting assessments of acid
deposition. It is useful to be aware of these issue from
the beginning, so as to take them into account when
designing and conducting  the assessment as well as
communicating the results.
Emissions,     Concentration,     and
Deposition Analysis Considerations

The following notable issues, complications, and data
limitations and other constraints have implications on
how the data can be interpreted.

Only a portion of acid deposition precursors are cur-
rently being controlled. Although the largest emitting
power plants were controlled under Phase I in 1995, a
larger number of utilities did not come into compliance
until 2000 when Phase II began and controls on Phase I
sources were tightened further. However, other chemi-
cal species such as NQc are  not as aggressively con-
trolled under Title IV and still others such as ammoni-
um (NH/i) not at all. The result is that only a portion of
total acidity is being reduced by Title IV, therefore, any
analysis is unlikely to document a complete ecosystem
response.

Methods of measurement of S and N deposition are
variable, and some nitrogen deposition  data is
thought to be underestimated. The difficulty in accu-
rately measuring and  modeling deposition, particularly
of nitrogen compounds, remains a large obstacle to
accurately  quantifying actual  acidity  impacts. Wet
deposition sites are located away from local emissions
sources (e.g., major highways, chemical factories, cat-
tle, hog and chicken farms, and fertilizer applications)
in order to be as regionally representative as possible.

Evaluations of nitric acid based on ozone behavior as a
surrogate indicate that dry deposition measurements of
nitrogen may underestimate actual rates by as much as
30% during the summer, depending on the site. In addi-
tion, nitrogen deposition measurements  do not include
ammonia  and  organic nitrogen,  which may further
underestimate total nitrogen deposition loads. In addi-
tion, NADP measures NH4 somewhat inaccurately; val-
ues may be underestimated by as much as 15%.

Both of these inaccuracies tend to underestimate nitro -
gen depositon, so current nitrogen deposition estimates
can be considered conservative. Since any underestima-
tions apply universally across the entire data record,
they should not affect the trends in deposition but could
affect analyses of environmental response  (NAPAP,
1990).

Dry deposition is very condition and site specific, and
models do not currently exist that can accurately quan-
tify the variations. Therefore, some modelers make the
assumption that total deposition is twice that of wet
deposition. If wet deposition of S or N is 20 kg/ha/yr,
for example, the total deposition is estimated to be 40
kg/ha/yr. By deduction, the dry deposition component is
assumed to be 20 kg/ha/yr. Studies show, however, that
numerous factors influence the dry deposition rate and
a uniform assumption is unwarranted. For example over
the extent of  the Chesapeake  Bay, it is typically
assumed that dry deposition is uniform, but the reality
is that it is dependent on precipitation, wind, tempera-
ture, and water currents; these all vary greatly from
north to south over the length of the Bay.

Experimental work on throughfall  deposition (includ-
ing gaseous, aerosol, particulate fractions of dry depo-
sition)  under a tree canopy shows that a significant
amount of sulfur is deposited in the forest stand (e.g., a
dramatic increase in sulfur relative to samples obtained
above the canopy). There are also large differences in
deposition rates between  conifer and hardwood forest
types. Both wet and dry deposition increase as the ele-
vation increases.

There  is a significant  unknown source of sulfur at
most sites in the Northeast U.S. Driscoll et al. have
found a discrepancy in the S budget at most intensively
sampled locations in the Northeast U.S. The quantities
of output of sulfur in streamwater are larger than the
measured inputs of sulfur in precipitation, suggesting a
significant unknown S source. Three  possible sources
of the "unknown  sulfur" were  hypothesized:  sulfur
                                                43

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stored on S-absorbing sites in soils and sediments at the
time of high  S deposition are being "bled  out" or
leached; underestimates of dry S deposition; and miner-
alization  of S  from  naturally occurring  minerals.
Investigations to date indicate that the first hypothesis is
not supported by  data.  The error in dry deposition
would have to be on the order of 2-3 fold. While possi-
ble, this appears to be unlikely. Mineralization of sulfur
from naturally occurring minerals was tested using iso-
topes and papers to be the likely source. The  prepon-
derance of 150 sites sampled by EPA in 1990 show this
phenomenon.  Among  50  sites  examined  in  the
Adirondacks all  (except for a few with large wetlands)
show a sulfur surplus.

Climate  is  a major factor influencing  deposition
rates and can explain  a significant  part  of  the
observed  pattern  over the last three years. Climate,
notably the  year-to-year changes  in temperature  and
precipitation, is a significant factor affecting deposition
rates. Title IV changes alone do not explain all of the
variation in measured deposition and concentration. In
Ohio, the  total precipitation in 1995, 1996, and 1997
has been higher than the 15-year average and  this  can
explain the higher than expected S  and  N deposition
rates observed. Not only is concentration affected; total
S and N deposition is a function of the amount of rain-
fall. The total precipitation has  been going up  at many
eastern U.S. stations. Moreover, the high precipitation
levels  typical  of high elevation mountain sites  has
meant that there has been little change so far in  the total
S deposition in response to Title IV. The higher temper-
atures at many stations in the eastern U.S. is also a fac-
tor since temperature influences the oxidation rate of
SC>2 in the atmosphere. As was noted earlier SC>2 con-
centrations have come down by about 20%.

The time-scale and integration interval of the analy-
sis is very important.  Currently, recovery in response
to Title IV, as measured by increased acid neutralizing
capacity,  is not being observed  in  most lakes  and
streams (Driscoll et al. 1998a, 1998b). The exception is
New England lakes where signs of recovery are being
observed.  Soils and sediments have been sinks of S  and
N over several decades and it will be some time before
the S and N leach out. The process of replacing the lost
Ca, Mg, and cation base capacity is a geological process
on the scale of decades and centuries. There is a need to
recognize  that different ecosystems and different pro-
cesses  may respond to deposition  changes on various
time scales,  some more easily measured than others. In
addition, sublethal, but persistent  (chronic)  effects of
acidity stresses are now recognized to be as important
as the direct, lethal, short-term or acute effects.

A long integration interval (e.g., one year) needs to be
used when samples of N are being averaged from dif-
ferent  monitoring networks.  The  problem is that
although laboratory procedures are  identical, the field
monitoring procedures for N are not, so that values dif-
fer and cannot be  averaged  across multiple stations.
While S is not affected in this way, nitrate levels cannot
be simply averaged without correction factors. A long
integration time helps somewhat to  modulate any bias
of different sampling procedures.

The spatial scale is very important;  responses may
not be uniform. There is not a uniform response or uni-
form recovery  associated with  Title IV or other pro-
grams. Some parts of New England., for example, are
exhibiting signs of recovery, yet other parts of the east-
ern U.S. show no  signs of recovery or even continue to
degrade.

NADP was established to show region to region differ-
ences in the acidity of wet deposition. State or tribal
nation  scales will require much more  detail than the
NADP data are designed to provide. The appropriate
unit of ecological analysis is the watershed, again on a
much smaller scale than called for by the NADP sam-
pling design. A model developed at Pennsylvania State
University  estimates  the deposition on  a 100  meter
scale by including the National Weather Service and
other meteorological data from the National Oceanic
and Atmospheric  Administration, high resolution
topography data,  vegetation cover, etc. The result is a
highly  detailed map that shows the considerable  varia-
tion in deposition rates from one location to another. If
a relatively small  area is being studied, national moni-
toring data such as NADP may have limited utility.

Sensitivity of the ecosystem versus resolution of the
data is important.  The degree of sensitivity of ecosys-
tem parameters and processes makes a difference in the
scale of precision required in the deposition data.
Ecosystem Analysis Issues

The following notable issues, complications, and data
limitations and other  constraints have implications on
how the data can be interpreted.

Typical Ecosystem Indicators. Some ecosystem com-
ponents or  processes are  being monitored  that are
                                                    44

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directly sensitive to acidic deposition. The following
parameters, among others, are being monitored as indi-
cators of acidic deposition effects: lichen communities,
air quality bioindicators, soil base cations, acid neutral-
izing capacity, soil aluminum/calcium ratio, streamwa-
ter or lake chemistry (pH, sum of base cations, Ca, Mg,
SO/i, NOs), benthic macro-invertebrates, and fish popu-
lations.

Another source of data on indicators is a wide spectrum
of biological data collected outside the acid rain moni-
toring network but  of potential interest and  utility in
addressing certain policy questions,  such  as  data col-
lected as part  of the Long Term Ecological  Research
Program (see Table  1).

Statistical Analyses. The kinds of statistical analyses
and tests applied to  the data will depend on the nature
and complexity of the air quality-response links being
explored.  Bivariate  graphs and time series frequently
appear  in the  assessment  literature.  Shortle and
Bondietti (1992) and Likens et al (1996) are examples
of recent studies that examined the relationship between
acid deposition rates  and flux of base cations in soil,
and in streamwater,  respectively. Multivariate analyses
(e.g., factor analysis, multiple regression) are less com-
monly reported in the literature, but present an effective
option when examining  several environmental param -
eters simultaneously.

There are some problems and outstanding questions
about the methods  and the databases that may have
significant impacts on the interpretation of results.
Among those noted  in discussions with scientists are:

•   the potential impacts of repeated re-sampling
•   the importance  of the timing of (re-)measurements
•   high  spatial variation and need for comparison
     across spatial gradients
•   the difficulty in establishing true controls (e.g.,
     before or  after  acid rain impacts; or acid rain ver-
     sus non-acid rain regimes for comparison of iden-
     tical sites)
•   the need to define recovery
•   the presence of unknown manmade or  natural
     sources of sulfur and nitrogen

Ecological Models. Models offer  an opportunity  to
examine  some  kinds of deposition responses that  are
difficult to measure  or observe in the field  such as long
response times,  subtle or transient effects, and spatial
and temporal patterns that are difficult to  monitor and
map with sufficient resolution. They also offer the
opportunity  for experimentation by internal modeling
exercises using constructs  in the place of real world
data. Some models already developed and available for
analyzing acid rain effects are  enumerated in Section
VI. It will be important to determine what models are
available and which may be of use in your assessment.

Most models need specific kinds of input data, and gen-
erate specific kinds of output (e.g., ecosystem respons-
es) based on a set of assumptions about how the exter-
nal influences affect key processes  within the ecosys-
tem. Assuming a model exists that can address the pol-
icy questions, it will be important to obtain documenta-
tion of the model, and articles describing its application
to specific problems or issues.
The following key issues should also be kept in mind
when conducting an ecological assessment.

Ecological changes may be due to many factors, and
attributing the cause to  decreasing  atmospheric
deposition will require good scientific monitoring
data. There is a growing awareness that other factors
may  be playing a  role in ecosystem effects. Organic
pollutants such as trizene and atrazene, widely used in
agriculture, are suspected by some scientists to be a fac-
tor in amphibian declines in the Northeast, for example.
The skin of frogs is highly  absorbent of these chemi-
cals.

A suite of indicators is necessary to capture the full
effects of changing acidic  deposition on ecosystems.
There  is definitely a move away  from single-factor
evaluations (e.g.,  stream  water chemical quality)
toward  indicators based on a multiplicity  of interac-
tions. Several experts from different disciplines may be
involved.  Managers need a broad integration of many
component responses in order to make robust decisions.
It is true that the broader analysis is perhaps less "rig-
orous" and precise scientifically than a narrowly taken
approach on one or more parameters. However, a broad
analysis can often describe the full range of ecosystem
responses more accurately and lead to better-informed
management decisions.

How  many and what indicators  should be used?
There is no precise answer to this  question. It varies
depending on the data and resources available, and gen-
erally all desired indicators cannot be included. In dis-
cussions developing this Handbook, one scientist indi-
cated "I am not suggesting  hundreds but a selection of
6-12.  The problem is that if you put a team of review-
                                                    45

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ers in a room, there would be a range of different per-
ceptions on what the 6-12 indicators should be, and no
consensus." Ecological assessments are still an evolv-
ing process.

In developing a comprehensive  assessment, would
the aquatic  system be  a good place  to start? The
development  of an effective protocol to do  an assess-
ment is a huge and extremely difficult problem to tack-
le. A few key mechanisms can be identified; however,
this is not the whole picture.  There is the most informa-
tion available on the aquatic side, so that is usually a
good place to start. There is  a sense that aquatic scien-
tists are getting close to  agreeing on a set of indicator
species.
It is true that the data and the models for quantifying
links between deposition and stream chemistry,  and
especially those between stream chemistry and the bio-
logical responses (invertebrates,  fish) are good. These
links are much better resolved than the terrestrial  soil
chemistry-tree responses.

Given that it is possible to develop a good assessment
procedure and model for the aquatic ecosystem,  the
rhetorical question is how much confidence do you, the
manager, and the end-users need in the assessment?

Despite the fact  that these questions remain, managers
cannot wait for perfect assessment designs or complete
scientific consensus before taking action.
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  Appendix B.  Sample  Integrated  Assessment
The modeling results presented here include analysis of total annual deposition, total annual mean aerosol concen-
trations and visibility for emission scenarios related to new and existing legislation. The Regional Acid Deposition
Model (RADM) was used to model sulfur and nitrogen deposition and the Regional Particulate Model (RPM) was
used to model particulates in order to calculate visibility. The results illustrate possible acid deposition and visibili-
ty changes in the future throughout the Eastern US. Results are presented on the standard 80 by 80-kilometer
RADM gnd.

Inspection of these maps provides a way to estimate potential changes in impacts related to deposition, aerosol
concentrations and visibility within the individual grids. For example, a change in sulfate deposition within a grid
can be translated into anticipated ecosystem responses in the grid some time in the future.
Background
This analysis was requested when legislation was proposed during the 106th Congress called Senate Bill S. 172.
This legislation focuses on utility emissions because they account for about two-thirds of the total SO 2 emissions
and one-third of the NOx emissions in the United States. In addition, available control options and the costs associ-
ated with particular control scenarios are well understood (U.S. EPA 1998).


Emission inventories were developed for each scenario. EPA analyzed impacts of the full S. 172 bill and its com-
ponents on acid deposition and visibility in the Eastern U.S. in 2010. Results of the major deposition, aerosol con-
centrations and visibility parameters for the East are presented here.

Scenarios. The following three scenarios were chosen for air quality and deposition modeling:


•   1990 Base. The base case reflects emission conditions as they were in 1990. The emissions profile was derived
    from the EPA section 812 prospective study, The Benefits and Costs of the Clean Air Act, 1990-2010 which
    examines the costs and benefits for air quality legislation for the next 10 years. More detail on how this inven-
    tory was developed is available in the study itself.

•   2010 Base (S-172) or Existing Clean Air Act (Title IV) Only. The 2010 Base assumes full implementation of
    Title IV controls,  and no additional controls from other emissions reduction programs affecting electric utility
    units.

•   2010 Full (S-172) or Existing Clean Air Act (Title IV) Plus Additional S(>2 and NOx. This scenario assumes
    the same conditions as in the 2010 Base plus addition controls on SOX and NOx as outlined in S172.
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Results

The results are presented in graphical format and are grouped into acid deposition and visibility analyses.

The acid deposition analysis includes:

•   Deposition: Sulfate and nitrate deposition for the three scenarios.
•   Percent Change in Deposition: Percent changes in the base 1990 year and the two 2010 scenarios for sulfate and
    nitrate total deposition.

The visibility analysis includes:

•   Aerosol  Concentrations: Total  aerosol concentration expressed by  sum  of sulfate, nitrate  and ammonium
    aerosols for the three scenario years.
•   Percent Change in Concentrations: Percent changes in total aerosol concentration for the three scenarios.
•   Percent Change  in Visibility:  Percent  changes  in visibility calculated from the aerosol  concentrations for the
    three scenarios.

Analysis of the information is provided. Guidance on how to interpret the information and use it in an assessment
also is noted.

This air quality and deposition modeling was done using RADM, the aerosol and visibility modeling also included
a component called RPM. When this is the case, the headers include the term RPM.
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Acid Deposition Analysis

The first six maps represent the annual total deposi-
tion (wet and dry) for the three scenarios for nitrogen
and for sulfur.  The three graphs on this page depict
nitrogen deposition in 1990, in 2010 with Title IV
only,   and  in  2010 with  Title  IV and S-172.
Deposition  is expressed in  kilograms nitrogen per
hectare per year.

The highest nitrogen deposition  levels  are in the
Ohio  River Valley and areas to the east. Nitrogen
deposition would decrease from over 10 kg-N/ha/yr
in the Ohio River Valley in 1990 to 6-8 kg-N/ha/yr
in 2010 if S-172 were implemented.
Annual Oxidized Nitrogen (NOx) Deposition in
1990 (kg-N/ha/yr)
                                                           Source: Regional Acid Deposition Model (RADM)
   Annual Oxidized Nitrogen (NOx) Deposition in
   2010 with Implementation of Title IV only (kg-
   N/ha/yr)
   Source: Regional Acid Deposition Model (RADM)
 Annual Oxidized Nitrogen (NOx) Deposition in
 2010 with Implementation of Title IV and S-
 172 (kg-N/ha/yr)
 Source: Regional Acid Deposition Model (RADM)
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The following three maps show sulfur deposition in
1990, in 2010 with Title IV only, and in 2010 with
S-172. Deposition is expressed in kilograms  sulfur
per hectare per year.

As illustrated, sulfate deposition is generally highest
in the Ohio river valley and to the east of this area.
The sulfate deposition load would decrease  in those
mid-west areas of highest deposition from more than
20 kg-S/ha/yr in 1990 to 12-16 kg-S/ha/yr in 2010 if
S-172 were implemented. Title IV provides an inter-
mediate level of reduction in deposition.
Annual Total Sulfur (S) Deposition in 1990 (kg-
S/ha/yr)
                                                          Source: Regional Acid Deposition Model (RADM)
    Annual Total Sulfur (S) Deposition in 2010
    with Implementation of Title IV only (kg-
    S/ha/yr) (base)
   Source: Regional Acid Deposition Model (RADM)
Annual Total Sulfur (S) Deposition in 2010 with
Implementation of Title IV and S-172 (kg-
S/ha/yr)
     Source: Regional Acid Deposition Model (RADM)
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The following two sets of maps present the percent change in deposition.  The first set on this page is for nitrogen
deposition under 2010 conditions with Title IV only and for 2010 conditions with Title IV and S-172. Changes for
both scenarios are in comparison to the 1990 Base conditions. As illustrated in the Title IV/S172 graphic, the areas
of greatest improvement in nitrogen deposition levels are in the Ohio river valley area.  There are also significant
improvements in the south and in southern New England. Nitrate deposition shows a much greater level of improve-
ment with implementation of the full S-172 emissions reductions than with only Title IV. Environmental impacts
and/or benefits are expected to be highest in these areas of greatest reduction in deposition load.
    Percent Reduction in Annual Oxidized
    Nitrogen (NOx) Deposition between 1990
    Conditions and Implementation of Title IV
    only in 2010 (kg-N/ha/yr)
 Source: Regional Acid Deposition Model (RADM)
   Percent Reduction in Annual Oxidized
   Nitrogen (NOx) Deposition between 1990
   Conditions and  Implementation of Title IV
   and S-172 in 2010 (kg-N/ha/yr)
Source: Regional Acid Deposition Model (RADM)
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The two maps on this page present the percent change in sulfur deposition. The first is for 2010 conditions with
Title IV only and the second is for 2010 conditions with Title IV and S-172. Changes for both scenarios are in
comparison to the 1990 conditions. As illustrated in the Title IV/S172 graphic, the areas of greatest improvement
in sulfur deposition levels are in the Ohio river valley area. There are also significant improvements in the south
and in southern New England. Sulfate deposition shows a much greater level of improvement with implementation
of the full S-172 emissions reductions than with only Title IV. Environmental  impacts and/or benefits are expected
to be highest in these areas of greatest reduction in deposition load.
    Percent Reduction in Annual Total Sulfur
    Deposition Between 1990 Conditions and
    Implementation of Title IV only in 2010 (kg-
    S/ha/yr)
                                          0—5
                                          5—10
                                          10 -15
                                          15 -20
                                          20  —25
                                          25  —30
                                          >  30
  Source: Regional Acid Deposition Model (RADM)
   Percent Reduction in Annual Total Sulfur
   Deposition Between 1990 Conditions and
   Implementation of Title IV and S-172 in
   2010 (kg-S/ha/yr)
Source: Regional Acid Deposition Model (RADM)
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Fine Participate and Visibility
Analyses

The first three maps present the annual mean total
aerosol concentrations for 1990 and for the two 2010
scenarios.  The concentrations  are expressed as
micrograms per cubic meter. The totals include con-
tributions  from  sulfate,  nitrate and ammonium
aerosols. Contributions from other aerosols  are
assumed to be much lower than other components in
the East and do not need to be included in the analy -
ses.  High concentrations occur mainly in the same
regions as the high deposition levels.
 Annual Mean Total Aerosol Concentrations
 (SO4, NO3, and NH4) in 1990 (ug/m3)
                                                                                             0  —  2
                                                                                             2-4
                                                                                             4—6
                                                                                             6  —  8
                                                                                             8—10
                                                                                            10  —12
                                                                                            12  —14
                                                                                             > 14
                                                      Source: Regional Acid Deposition Model (RADM) and RPM
    Annual Mean Total Aerosol Concentrations
    (SO4, NO3, and NH4) with Implementation
    of Title IV only in 2010 (ug/m3)
    Source: Regional Acid Deposition Model (RADM) and RPM
 Annual Mean Total Aerosol Concentrations
 (SO4, NO3, and NH4) with Implementation
 of Title IV and S-172  in 2010 (ug/m3)
                                                                                           LEGEND:
                                                                                            0 — 2
                                                                                            2 — 4
                                                                                            4—8
                                                                                            6 — 8
                                                                                            8—10
                                                                                            10 -12
                                                                                            12 —14
                                                                                             >  14
Source: Regional Acid Deposition Model (RADM) and RPM
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 The next two maps show the percent reduction in total annual mean aerosol concentrations for both 2010 scenar-
ios. Improvement is greatest mainly in the regions of the highest initial concentrations.
    Percent Reduction in Aerosol
    Concentrations (SO4, NO3, and NH4)
    between 1990 Conditions and 2010
    Conditions with Title IV (ug/m3)
                                     LEGEND:
                                     % Increase
                                        0—5
                                        5—15
                                         > 15
                                     % Reduction
                                        0—5
                                        5—15
                                       15 —25
                                       25 —35
                                     i   > 35
  Source: Regional Acid Deposition Model (RADM)
  Percent Reduction in Aerosol Concentrations
  (SO4, NO3, and NH4) Between
  Implementation of Title IV only and
  Implementation of Title IV and S-172 in 2010
  (ug/m3)
Source: Regional Acid Deposition Model (RADM) and RPM
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The last two maps present the visibility changes for the two 2010 cases. In both cases, the absolute change in visi-
bility at the 90th percentile is presented. Deciview is a unit for visibility and is related to aerosol light extinction
(light scattering and absorption of sunlight by the aerosols). Total light extinction is the sum of the concentrations
of each visibility-reducing aerosol weighted by the light extinction efficiency of that aerosol. Sulfate and nitrate
aerosols have similar light extinction efficiencies.  The lower deciviews are related to better visibility and higher
ones are associated with poorer visibility.
    Annual Change in Visibility between 1990
    Conditions and Implementation of Title IV
    only in 2010 (90th percentile change in
    deciviews)
  Source: Regional Acid Deposition Model (RADM)
  Annual Change in Visibility Between 1990
  Conditions and Implementation of Title IV
  and S-172 in 2010 (90th percentile change in
  deciviews)
Source: Regional Acid Deposition Model (RADM), RPM
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