REMEDIATION SYSTEM EVALUATION
BREWSTER WELL FIELD SUPERFUND SITE
        BREWSTER, NEW YORK
 Report of the Remediation System Evaluation,
        Site Visit Conducted at the
     Brewster Well Field Superfund Site
            October 30,2001
   Final Report Submitted to Region 2
             April 8, 2002
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                                        NOTICE
Work described herein was performed by GeoTrans, Inc. (GeoTrans) and the United States Army Corps
of Engineers (USAGE) for the U.S. Environmental Protection Agency (U.S. EPA). Work conducted by
GeoTrans, including preparation of this report, was performed under Dynamac Contract No. 68-C-99-
256, Subcontract No. 91517.  Mention of trade names or commercial products does not constitute
endorsement or recommendation for use.

This document (EPA 542-R-02-008t) may be downloaded from EPA's Technology Innovation Office
website at www.epa.gov/tio or www.cluin.org/rse.

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                               EXECUTIVE SUMMARY
The Brewster Well Field, located on the northern bank of the East Branch Croton River (the "River"),
was found in  1978 to be contaminated with chlorinated volatile organic chemicals (CVOCs) including
tetrachloroethene (PCE), trichloroethene (TCE) and dichloroethene.  Alben Dry Cleaners was determined
to be a significant source of the groundwater contamination.  Source remediation— consisting of
excavation and offsite disposal of sediments, sludge, and contaminated soil from the dry well located
adjacent to the dry cleaners— was completed by 1991. Two separate air stripping systems have been
constructed and are currently operating:

               The area north of the River, associated with the Brewster Well Field, had a packed tower
               air stripper installed in 1984 to provide treatment of the Village's water supply.  The
               system continues to operate and supply water.

               The area south of the River, where the original source of the contamination was located,
               had a Ground Water Management System  (GMS) installed in 1991, and operated
               continuously since 1996, for the purpose of ground water containment and restoration.

The focus of this RSE is the GMS, which is located to south of the River.

The GMS consists of ground water extraction from four wells, above-ground treatment via air stripping,
and discharge to the East Branch of the Croton River.  The combined flow of water from the four wells  is
typically 45 to 50 gpm.

Ground water contamination with MTBE is also present on site. The source of MTBE contamination
was located at Savino's Towing, Inc.  and has been removed and the ground water concentrations for this
contaminant are below the State water quality standards. System monitoring includes sampling for
MTBE for tracking purposes only and should not affect operation of the GMS system.  It should be noted
that research on MTBE health impacts is ongoing and there is a reasonable likelihood that the MCL
might be lowered. Therefore, site managers should consider the role of the GMS if MTBE
concentrations are found to exceed the MCLs in the future.

In general, the RSE team found a well operated system.  The goal of the system, according to the ROD,  is
both containment and aquifer restoration. The RSE team believes the containment objective may not
currently be met, and although peak concentrations have declined over time, the RSE team believes that
by the current system is not optimized for aquifer restoration. With a modified system, however, aquifer
restoration is likely achievable.

The RSE team feels that a current site conceptual model should be developed, documented, and updated
on a regular basis. Furthermore, the operating system and  associated goals  should be consistent with this
conceptual model.  The following issues should be addressed by the conceptual model:

               What are the roles of the two air stripping  systems in achieving containment of the
               contaminant plume and restoration of the aquifer?  How do these two systems affect
               each other hydrogeologically? Does pumping from one system prevent the other system
               from achieving its goals?

               What is the "target capture zone" for the system south of the site?

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       •       What is the actual capture zone of the existing system, and how does it compare to the
               target capture zone?

       •       Are impacts north of the River near TH-7 being drawn to the village wells or the
               extraction system south of the River, or discharging to the River?

       •       Will the current system achieve the ROD goal of aquifer restoration at locations near
               DGC-19I, DGC-7I and TH-7 (which are impacted and appear to be distant from the
               current extraction wells)?

       •       What are  contaminant levels (and plume extent) south of the current extraction system?

       •       Why are the "hot spot" areas and overall plume extent for PCE and TCE different than
               those for cis-l,2-DCE and vinyl chloride?

       •       Does ground water south of the River discharge to the River, flow under the River, or
               both?

       •       How long will it likely take to meet the ROD objective of aquifer restoration with the
               current system?

       •       What steps could be considered to improve the likelihood of achieving aquifer
               restoration, and/or decreasing the time to aquifer restoration?

Other recommendations to improve  system effectiveness include the following:

       •       Conduct a GeoProbe investigation of shallow and intermediate ground water south of
               extraction well EW-1, followed by installation and ground water sampling of two to four
               monitor wells in that area.

       •       Define the "target capture zone".

       •       Superimpose the "target capture zone" with the capture zone interpreted from existing
               data (and  potentially, in the future,  data from additional points and/or river stage
               measurements).

       •       Refine the site conceptual model based on the results of the recommendations  above.

       •       Replace extraction wells EW-2 to EW-4 with up to three new wells located to  the east of
               extraction well EW-1.

These items might require approximately $242,500 in capital expenditures to complete,  but the annual
costs associated with them have be included in the reduced oversight costs that are discussed below.

Recommendations to reduce costs include the following:

       •       Clearly define the oversight tasks and reduce costs over time (potential savings of
               $60,000 per year).
                                               11

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       •       Switch analysis method for VOCs from EPA524.2 to EPA 8260B (potential savings of
               $15,000 per year).

       •       Reduce costs for sampling labor, equipment, and contractor travel (potential savings of
               $20,000 to $25,000).

       •       Replace third-party notification system with an autodialer (potential savings of $1,000
               per year).

These costs savings of approximately $100,000 per year can be accomplished with almost no capital
expenditure (approximately $5000).

Recommendations for technical improvement have also been suggested.

Finally, the RSE team applauds efforts to consider alternative remediation approaches (e.g., HRC)
suggested by site managers.  Until the improvements in effectiveness and costs suggested above are
made, a major investment in other technologies available at this time does not appear warranted.
Furthermore, pilot testing of alternate remedies should only be performed if scale-up costs to a full-scale
system are calculated and appear favorable in a cost-benefit analysis versus a revised extraction system.
                                               in

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                                      PREFACE
This report was prepared as part of a project conducted by the United States Environmental Protection
Agency (USEPA) Technology Innovation Office (TIO) and Office of Emergency and Remedial Response
(OERR).  The objective of this project is to conduct Remediation System Evaluations (RSEs) of pump-
and-treat systems at Superfund sites that are "Fund-lead" (i.e., financed by USEPA). RSEs are to be
conducted for up to two systems in each EPA Region with the exception of Regions 4 and 5, which
already had similar evaluations in a pilot project.

The following organizations are implementing this project.
            Organization
   Key Contact
         Contact Information
 USEPA Technology Innovation
 Office
 (USEPA TIO)
Kathy Yager
11 Technology Drive (ECA/OEME)
North Chelmsford, MA 01863
phone: 617-918-8362
fax: 617-918-8417
yager.kathleen@epa.gov
 USEPA Office of Emergency and
 Remedial Response
 (OERR)
Paul Nadeau
1200 Pennsylvania Avenue, NW
Washington, DC 20460
Mail Code 5201G
phone: 703-603-8794
fax:703-603-9112
nadeau.paul@epa.gov
 GeoTrans, Inc.
 (Contractor to USEPA TIO)
Doug Sutton
GeoTrans, Inc.
2 Paragon Way
Freehold, NJ 07728
(732) 409-0344
Fax: (732) 409-3020
dsutton@geotransinc. com
 Army Corp of Engineers:
 Hazardous, Toxic, and Radioactive
 Waste Center of Expertise
 (USAGE HTRW CX)
Dave Becker
12565 W. Center Road
Omaha, NE 68144-3869
(402)697-2655
Fax: (402) 691-2673
dave.j.becker@nwd02.usace.army.mil
                                            IV

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The project team is grateful for the help provided by the following EPA Project Liaisons.
 Region 1    Darryl Luce and Larry Brill
 Region 2    Diana Curt
 Region 3    Kathy Davies
 Region 4    Kay Wischkaemper
 Region 5    Dion Novak
Region 6     Vincent Malott
Region 7     Mary Peterson
Region 8     Armando Saenz and Richard Muza
Region 9     Herb Levine
Region 10    Bernie Zavala
They were vital in selecting the Fund-lead P&T systems to be evaluated and facilitating communication
between the project team and the Remedial Project Managers (RPM's).

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                              TABLE OF CONTENTS
EXECUTIVE SUMMARY	i

PREFACE  	iv

TABLE OF CONTENTS	vi

1.0 INTRODUCTION	  1
       1.1    PURPOSE	  1
       1.2    TEAM COMPOSITION	  2
       1.3    DOCUMENTS REVIEWED	  2
       1.4    PERSONS CONTACTED                         	  2
       1.5    SITE LOCATION, HISTORY, AND CHARACTERISTICS 	  3
             1.5.1   LOCATION AND HISTORY	  3
             1.5.2   POTENTIAL SOURCES	  3
             1.5.3   HYDROGEOLOGIC SETTING	  4
             1.5.4   DESCRIPTION OF GROUND WATER PLUME	  4

2.0  SYSTEM DESCRIPTION	  6
       2.1    SYSTEM OVERVIEW	  6
       2.2    EXTRACTION SYSTEM	  6
       2.3    TREATMENT SYSTEM	  6
       2.4    MONITORING SYSTEM  	  7

3.0  SYSTEM OBJECTIVES, PERFORMANCE AND CLOSURE  CRITERIA	  9
       3.1    CURRENT SYSTEM OBJECTIVES AND CLOSURE CRITERIA	  9
       3.2    TREATMENT PLANT OPERATION GOALS	  9
       3.3    ACTION LEVELS	  10

4.0  FINDINGS AND OBSERVATIONS FROM THE RSE SITE VISIT	  11
       4.1    FINDINGS  	  11
       4.2    SUBSURFACE PERFORMANCE AND RESPONSE 	  11
             4.2.1   WATERLEVELS 	  11
             4.2.2   CAPTURE ZONES  	  11
             4.2.3   CONTAMINANT LEVELS 	  11
       4.3    COMPONENT PERFORMANCE 	  13
             4.3.1   EXTRACTION WELLS AND PUMPS  	  13
             4.3.2   AIR STRIPPER	  13
             4.3.3   DISCHARGE LINE	  13
             4.3.4   CONTROLS	  13
       4.4    COMPONENTS OR PROCESSES THAT ACCOUNT FOR MAJORITY OF MONTHLY COSTS	  13
             4.4.1   UTILITIES	  14
             4.4.2   NON-UTILITY CONSUMABLES AND DISPOSAL COSTS 	  14
             4.4.3   LABOR	  14
             4.4.4   CHEMICAL ANALYSIS	  15
       4.5    RECURRING PROBLEMS ORISSUES	  15
       4.6    REGULATORY COMPLIANCE	  15
       4.7    TREATMENT PROCESS EXCURSIONS AND UPSETS, ACCIDENTAL CONTAMINANT/REAGENT RELEASES
              	  15
       4.8    SAFETYRECORD 	  15
                                           vi

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5.0  EFFECTIVENESS OF THE SYSTEM TO PROTECT HUMAN HEALTH AND THE ENVIRONMENT  16
       5.1     GROUND WATER 	 16
       5.2     SURFACE WATER	 16
       5.3     AIR	 16
       5.4     SOILS 	 17
       5.5     WETLANDS AND SEDIMENTS  	 17

6.0  RECOMMENDATIONS	 18
       6.1     RECOMMENDATIONS TO IMPROVE EFFECTIVENESS  	 18
              6.1.1   DEVELOP A PRELIMINARY Bur COMPREHENSIVE UPDATED CONCEPTUAL MODEL OF
                     GROUND WATER FLOW AND CONTAMINANT TRANSPORT 	 18
              6.1.2   ADDITIONAL PLUME DELINEATION SOUTH OF EW-1	 19
              6.1.3   DEFINE THE "TARGET CAPTURE ZONE"  	 20
              6.1.4   INTERPRET ACTUAL CAPTURE WITH RESPECT TO THE "TARGET CONTAINMENT ZONE" . 20
              6.1.5   DEVELOP A REVISED CONCEPTUAL MODEL	 21
              6.1.6   REPLACEEW-2 TOEW-4 WITH NEW EXTRACTION WELLS	 21
       6.2     RECOMMENDED CHANGES TO REDUCE COSTS	 22
              6.2.1   CUT MANAGEMENT EXPENSE 	 22
              6.2.2   REDUCE SAMPLING AND ANALYSIS, EQUIPMENT RENTAL, AND TRAVEL/PER DIEM COSTS
                     	 24
              6.2.3   REPLACE ELECTRONIC MONITORING SYSTEM WITH AN AUTODIALER  	 25
       6.3     MODIFICATIONS INTENDED FOR TECHNICAL IMPROVEMENT 	 25
              6.3.1   INSTALL NEW UNDERGROUND DISCHARGE LINE	 25
              6.3.2   IMPROVE TO ANNUAL O&M REPORTS	 25
              6.3.3   ENSURE VAPORS FROM ACETIC ACID WASH COMPLIES WITH OSHA STANDARDS .... 26
              6.3.4   MEASURE THE AIR FLOW THROUGH THE AIR STRIPPER	 26
       6.4     MODIFICATIONS INTENDED TO GAIN SITE CLOSE-OUT	 27
              6.4.1   CONTINUE EVALUATING ALTERNATIVE REMEDIAL OPTIONS	 27
       6.5     UNUSED EQUIPMENT 	 28
       6.6     SUGGESTED APPROACH TO IMPLEMENTATION OF RECOMMENDATIONS	 28

7.0  SUMMARY	 29
List of Tables

Table 7-1.      Cost summary table

List of Figures

Figure 1-1      Site vicinity
Figure 1-2      PCE in ground water, November 2000
Figure 1-3      cis-l,2-DCE in ground water, November 2000
Figure 2-1      Shallow ground water elevations, September 1999
Figure 2-2      Intermediate ground water elevations, September 1999
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                                 1.0 INTRODUCTION
1.1           PURPOSE

In the OSWER Directive No. 9200.0-33, Transmittal of Final FYOO - FY01 Superfund Reforms Strategy,
dated July 7,2000, the Office of Solid Waste and Emergency Response outlined a commitment to
optimize Fund-lead pump-and-treat systems. To fulfill this commitment, the US Environmental
Protection Agency (USEPA) Technology Innovation Office (TIO) and Office of Emergency and
Remedial Response (OERR), through a nationwide project, is assisting the ten EPA Regions in
evaluating their Fund-lead operating pump-and-treat systems. This nationwide project is a continuation
of a demonstration project in which the Fund-lead pump-and-treat systems in Regions 4 and 5 were
screened and two sites from each of the two Regions were evaluated. It is also part of a larger effort by
TIO to provide USEPA Regions with various means for optimization, including screening tools for
identifying sites likely to benefit from optimization and computer modeling optimization tools for pump
and treat systems.

This nationwide project identifies all Fund-lead pump-and-treat systems in EPA Regions 1 through 3 and
6 through  10, collects and reports baseline cost and performance data, and evaluates up to two sites per
Region. The site evaluations are conducted by EPA-TIO contractors, GeoTrans, Inc. and the United
States Army Corps of Engineers (USAGE), using a process called a Remediation System Evaluation
(RSE), which was developed by USAGE.  The RSE process is meant to evaluate performance and
effectiveness (as required under the NCP, i.e., and "five-year" review), identify cost savings through
changes in operation and technology, assure clear and realistic remediation goals and an exit strategy,
and verify adequate maintenance of Government owned equipment.

The Brewster Well Field Superfund Site was chosen to receive an RSE based on an initial screening of
the pump-and-treat systems managed by USEPA Region 2 as well as discussions with the Superfund
Reform  Initiative Project Liaison for that Region.  This site has high operation costs relative to the cost
of an RSE and a long projected operating life.  This report provides a brief background on the site and
current operations, a summary of the observations made during a site visit, and recommendations for
changes and additional studies. The cost impacts of the recommendations are also discussed.

A report on the overall results from the RSEs conducted for this system and other Fund-lead P&T
systems throughout the nation will also be prepared and will identify lessons learned and typical costs
savings.

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1.2
TEAM COMPOSITION
The team conducting the RSE consisted of the following individuals:

       Ed Mead, Chemical Engineer, USAGE HTRW CX
       Rob Greenwald, Hydrogeologist, GeoTrans, Inc.
       Peter Rich, Civil and Environmental Engineer, GeoTrans, Inc.
       Doug Sutton, Water Resources Engineer, GeoTrans, Inc.
1.3
DOCUMENTS REVIEWED
Author
GHR Engineering
USEPA
Ebasco
Kemron
Sevenson
Kemron
Sevenson
Sevenson
Sevenson
Army Corp of Engineers
(Handed out During RSE
Site Visit)
Date
7/1986
9/30/1986
4/20/1989
10/22/1998
3/8/2000
4/9/1999
3/21/2000
4/25/2000
7/27/2000
2001
Title
Remedial Investigation Report
Record of Decision
Final Remedial Design
Monthly Report (September 1-30, 1998)
Draft 1999 Annual Report
Monthly Report (February 1-28, 1999)
Monthly Report (February 1-29, 2000)
Draft 2000 Annual Report
Monthly Report, Partial (June 1-30, 2000)
Table of VOC Compound List
1.4
PERSONS CONTACTED
The following individuals (in addition to the RSE team) were present for the site visit:

Lisa Wong-EPA RPM
Arbor Drinkwine - USAGE Kansas City District, Project Manager
Dawn Cermak - Sevenson (Contractor to ACOE)
Lou Gasparini - Local subcontractor to Sevenson
Mike Scorca - EPA Region II Hydrogeologist
John LaPadula - EPA Region II (Observer)
Vince Pitruzello - EPA Region II (Observer)
Julia Kisser - USAGE Kansas City District (conducting 5-yr review)
Frank Bales - USAGE Kansas City District (conducting 5-yr review)
Dave Nelson - USAGE Kansas City District(conducting 5-yr review)

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1.5            SITE LOCATION, HISTORY, AND CHARACTERISTICS

1.5.1           LOCATION AND HISTORY

The Brewster Well Field (the Site) is approximately three-quarters of a mile east of the Village of
Brewster in Putnam County, New York. An illustration of the Site vicinity is presented in Figure 1-1.
The land to the north and west is largely residential while most of the land south of the site area is
occupied by commercial or light industrial facilities.

The Brewster Well Field, located on the northern bank of the East Branch Croton River (the "River"),
supplies water to approximately 2,200 people.  In 1978 the well field was found to be contaminated with
chlorinated volatile organic chemicals (CVOCs)  including tetrachloroethene (PCE), trichloroethene
(TCE) and dichloroethene (DCE). A remedial investigation  was completed in 1986, and a Record of
Decision was signed in September,  1986. The RI/FS suggested that Alben Dry Cleaners was a
significant source of the ground water contamination. Source remediation,  consisting of excavation and
offsite disposal of sediments, sludge, and contaminated soil from the dry well located adjacent to the dry
cleaners, was completed by 1991.

Two separate air stripping systems have been constructed and operated:

               The area north of the  River, associated with  the Brewster Well Field, had a packed tower
               air stripper installed in 1984 to provide treatment of the Village's water supply. The
               system continues to operate and supply water.

               The area south of the  River, where the original source  of the contamination was located,
               had a Ground Water Management System (GMS) that consists of four extraction wells
               and an air stripper.  The system was installed in 1991 and has operated continuously
               since  1996 for the purpose of ground water containment and restoration.

The focus of this RSE is the GMS, which is located to south of the River.

1.5.2           POTENTIAL SOURCES

The former Alben Cleaners, located south of the River and about 900 ft. south of Well Field No. 1, was
identified in the RI as likely being the main CVOC contaminant source.  This location is indicated on
Figure 1-1.  Other minor sources of VOCs and petroleum compounds are present in the vicinity.  The dry
well at Alben Cleaners was removed in 1990, and confirmation sampling was conducted. The working
conceptual model for the site is that the source of contamination has been removed.

Ground water contamination with MTBE is also present on site.  Savino's Towing, Inc.  was identified as
the location of the source of MTBE contamination. The source has been removed and the ground water
concentrations for this contaminant are is below the State water quality standards.  System monitoring
includes sampling for MTBE for tracking purposes only and should not affect operation of the GMS
system.  It should be noted that research on MTBE health impacts is ongoing and there is a reasonable
likelihood that the MCL might be lowered.  Therefore, site managers should consider the role of the
GMS if MTBE concentrations are found to exceed the MCLs in the future.

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1.5.3          HYDROGEOLOGIC SETTING

The subsurface hydrogeology is quite complex, as detailed in the RI report, and consists of
unconsolidated sediments overlying bedrock. During the RI, deep wells installed into the bedrock
showed no contamination. All recovery wells at the site are screened in the unconsolidated sediments.
Recharge primarily occurs through rainfall/snowmelt and through flow from surrounding areas.

As detailed in the RI, ground water flow south of the River (i.e., from the source area near Albens
Cleaners) is to the north. Under natural conditions, discharge would be to the River from both the north
and the south (i.e., the River would be a gaining stream). However, due to historic and continuing
pumping at the Village Well Field wells north of the River, the River in the vicinity of the site likely
becomes a losing river to the well field, which in turn allows passage of water beneath the River from the
south. This would explain the mechanism for historic contamination at the village wells north of the
River from a source area south of the River. The hydraulic connection of ground water north and south
of the River was demonstrated by pumping tests in the RI (pumping north of the River caused responses
south of the River), and by recovery tests by Kemron described in the September 1998 monthly report
(turning off the extraction wells south of the River caused a response north of the River).

The RI describes the ground water flow pattern south of the River as a complex interaction between the
well field (drawing ground water to the north) and the impacts of the River which cause ground water to
flow in a west/southwest direction as underflow. The RI describes a ground water divide differentiating
these two types of flow.  This complex pattern has been further complicated by the recovery wells that
have been pumping south of the River since 1996.

The River flows to the southwest and contributes to the Croton Falls Reservoir approximately 3.5 miles
downstream. Three thousand feet to the east of the Site (upstream), the River is impounded to form the
East Branch Croton Reservoir, part of New York City's Croton Watershed reservoir system.
Approximately 3,000 feet to the northeast of the site, Bog Brook, a tributary to the East Branch Croton
River, is impounded to form Bog Brook Reservoir, also owned by New York City. The degree of
connection between ground water and the East Branch Croton River is unclear. In the ROD it states that
PCE was detected at 2 to 4 ug/1 in surface water near the 1-84 overpass, which could indicate an
interchange of ground water and surface water. However, it could also have been due to potential
discharge from a culvert northeast of Alben Cleaners.  Also, the fact that the River loses water to the
Village Well Field to the north does not preclude the possibility that it still gains water (impacted by
chlorinated hydrocarbons) from the south.

1.5.4          DESCRIPTION OF GROUND WATER PLUME

Chlorinated VOCs (PCE of 166 ug/1 and TCE of 5ug/l) were found in Village Well Field samples in
August 1978, and the results were confirmed in September 1978.  Well Field No. 1 was found to have
greater impacts than Well Field No.2. At the time of the RI, the highest level of PCE seen at any well
was 5600ug/l at Well 61 (south of the River) in October 1985. In 1979, PCE of nearly 2000 ug/1 was also
detected in TH-7, north  of the River.

The 2000 Annual Report provides contour maps for the following constituents:

       PCE
       TCE
       cis-l,2-DCE
       MTBE

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The PCE and cis-l,2-DCE maps are presented in Figure 1-2 and 1-3 of this RSE report. Selected
observations from these figures include the following:

       •      Maximum concentrations of PCE are below 1000 ug/1, which is reduced from the 1979-
              1985 levels reported in the RI.

       •      Of the four extraction wells, only EW-1 is located in one of the areas with the highest
              PCE contamination onsite, while EW-2 through EW-4 are not.

       •      Impacts of PCE and cis-l,2-DCE are significant at TH-7, located north of the River.

       •      cis-l,2-DCE impacts  are significant further to the east than the PCE plume (particularly
              DGC-7I).

       •      The current remediation wells (EW-1 to EW-4) are not located  near TH-7 (north of the
              River) or DGC-7I (impacted by cis-l,2-DCE), or DGC-19 (impacted by PCE and cis-1,2-
              DCE).

       •      The extent of ground water contamination is unknown to the south (i.e., upgradient) of
              EW-1. DGC-19 is located directly between the former source and EW-1 and has
              concentrations of 79 ppb PCE and 211 ppb cis-1,2 DCE. No wells are located to the
              west of DGC-19 (south of EW-1) to delineate the extent of this contamination.

The concentrations of TCE are much lower than PCE, although the extent is similar. The cis-l-2-DCE is
a breakdown product of the PCE and/or TCE, and suggests that in-situ biodegradation is occurring at the
site.

Vinyl chloride is not mentioned in detail in the Annual Report for 1999 and 2000, other than sporadic
detections in system influent of approximately 1 to 3 ug/1. However, a data sheet with concentrations at
individual wells handed out during the RSE site visit indicates significantly elevated concentrations of
vinyl chloride at several wells (up to 277 ug/1 at DGC-19I in November 2000, and up to 121 ug/1 at well
TH-7 in November 2000). Vinyl chloride is also a degradation product of PCE/TCE, and this again
indicates that substantial biodegradation is occurring.

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                            2.0   SYSTEM DESCRIPTION
This discussion pertains to the GMS operated south of the River, which is the focus of this RSE.
2.1           SYSTEM OVERVIEW

The system has been continuously operated since 1996. It consists of ground water extraction from four
wells, above-ground treatment via air stripping, and discharge to surface water.  These components, plus
the monitoring of the system, are described in more detail below.
2.2           EXTRACTION SYSTEM

The four extraction wells (EW-1, EW-2, EW-3, and EW-4) are screened 21.5to36.5ft bgs and have 3/4
HP Gould submersible pumps. The pumps have amperage shutoffs. Discharge from the wells is currently
piped to the treatment system by a cast iron header. The cumulative extraction rate from these four wells
is approximately 45 to 50 gpm.  Flow meters are not installed on individual extraction wells; thus,
extraction rates for each of these wells cannot be determined.
2.3           TREATMENT SYSTEM

Water is pumped from the four extraction wells to the top of an air stripper. The stripper tower is a
Hydro Group 30" dia. packed tower and is filled with 25 feet of one inch Norton plastic intalox saddles.
The combined flow of water from the four wells is typically 45 to 50 gpm. The treated water is
discharged from the bottom of the air stripper to a sump with an outlet pipe that conveys the water to the
East Branch of the Croton River. The air stripper is located outside the building. Air to the air stripper is
provided by two parallel belt driven centrifugal blowers located inside the treatment building.  The air
flow-rate to the air stripper is not measured, and no estimate of the air flow-rate was available.

The processed ground water passes out of the bottom of the air stripper column into a clearwell, that
provides flow equalization and level control. The effluent from the clearwell then flows by gravity
through a buried 4-inch pipe to either the eight passive injection wells (historically inactive) or to a PVC
effluent line that discharges to an outfall to the East Branch Croton River. A gate valve that is operated
via a valve box outside the building directs flow to either the injection wells or the outfall.  A concrete
waste sump has been included within the facility to provide for multipurpose use of the system. These
uses may include storage of water generated during system start-up or draining for maintenance of the
column. A sump pump has been included to allow stored water or processed water to be recycled
through the system, discharged to the outfall, or pumped to a truck for offsite disposal. The sump pump
is used for the acid wash of the air stripper, a 24-hour processed that is completed once per quarter.

The system was originally designed such that treated water would be reinjected through a series of wells,
cross-gradient from the extraction wells.  The intended purpose was to promote flushing of the impacted
portion of the aquifer. The designed reinjection system never worked effectively due to almost
immediate clogging, so discharge was instead directed to the East Branch Croton River, approximately
150 feet from the treatment system, through an underground four-inch pipe.  The underground discharge

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line and valves are currently fouled by calcium carbonate, so discharge is currently occurring through a
temporary above-ground PVC line.
2.4           MONITORING SYSTEM

Routine inspection and sampling activities at the Brewster site consist of weekly inspections, monthly
inspections, monthly sampling, quarterly inspections and sampling, and an annual sampling event.

Weekly

Weekly inspections are performed by Mr. Lou Gasparini under subcontract to Sevenson. No sampling is
performed unless a monthly effluent sample failed for a SPDES discharge limitation parameter.

Monthly

Monthly inspections and sampling activities are performed by Sevenson personnel and Mr. Lou
Gasparini, and include:

              Effluent sampling and analysis for EPA Method 524.2 constituents plus Benzene,
              Toluene, Ethylbenzene, Xylenes, (BTEX), Methyl tert-Butyl Ether (MTBE), and Iron

        •      Depth to water measurements in monitor well DGC-7S and injection wells IW-6, IW-8,
              IW-10 and IW-12

              Pressure readings from extraction wells, total gallons extracted, and other various
              operating parameters

              Site inspection and general system inspection including inspection of air-handling system
              and air filters

Quarterly

Quarterly inspections and sampling are performed by Sevenson personnel, and have included:

              Influent and effluent sampling and analysis for EPA Method 524.2 constituents plus
              BTEX, MTBE, Iron, Calcium, Sodium, Manganese, Chloride, total and fecal coliform
              bacteria

              General site inspection

              Depth to water in 26 monitoring wells and 4 injection well  locations (not currently used
              for injection)

Beginning with the March 2001 sampling event, quarterly events will also include sampling  of ground
water at the 4 extraction wells, 8  monitor wells and 3 surface water locations.

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Annual

Annual sampling is performed by Sevenson personnel and has included all quarterly activities with the
following additions/modifications:

       •       Sample 30 monitoring wells, 2 injections wells, 3 points of the surface waters of the
               Croton River and the 4 extraction wells for EPA Method 524.2 constituents plus BTEX,
               MTBE and Iron, Calcium, Sodium, Manganese, and Chloride

       •       Depth to water in 32 monitoring wells and 4 injection wells locations (not currently used
               for injection)

Starting November 2000 sampling event, annual events will incorporate the new ground water and
surface water sampling being performed quarterly, plus sampling of 8 additional ground water
monitoring wells.  Subsequent annual sampling events will occur in December of each year.

Drafts of the annual reports for 1999 and 2000 were made available to the RSE team. It should be noted
that those annual reports do not include important data collected during the monitoring events, such as:

       •       table(s) listing water level measurements with well names, screened intervals, measuring
               elevations (i.e., tops of casings), dates, and depths to water

               table(s) listing measured concentrations at monitoring wells (a subset of those data are
               listed on some figures).

Also, the draft 2000 Annual report, does not include any presentation of water level maps from  which
flow directions can be interpreted. However, such maps were included in the draft 1999 Annual Report
for shallow water levels (see Figure  2-1) and intermediate water levels (see Figure 2-2).

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      3.0   SYSTEM OBJECTIVES, PERFORMANCE AND CLOSURE
                                       CRITERIA
This discussion pertains to the GMS operated south of the River, which is the focus of this RSE.
3.1
CURRENT SYSTEM OBJECTIVES AND CLOSURE CRITERIA
According to the ROD, the public health and environmental objectives of the Remedial Investigation and
Feasibility Study were as follows:

              provide a safe, reliable water supply, meeting EPA standards, to the Village of Brewster
              contain the plume of contamination to mitigate further contamination of public water supplies
              restore ground water quality at and in the vicinity of the Brewster Well Field to acceptable levels
              (NYS ground water standards)

Based on these objectives, the ROD calls for the following actions:

              Continued operation of the existing on-site packed column air stripping system at the Well Field
              to provide to the Village a water supply that exceeds applicable or relevant and appropriate
              standards, thereby providing a very high level of public health protection.

              Design and construction of a ground water management system, consisting of extraction wells,
              treatment of the extracted water by an additional off-Site air stripper, and reinjection of the treated
              water, to contain the plume of contamination and restore ground water quality south of the East
              Branch of the Croton River.
3.2
TREATMENT PLANT OPERATION GOALS
The Brewster GMS treatment system must meet discharge limits for eleven organic constituents, plus
iron, in order to comply with the SPDES program.  The constituents listed are
SPDES Parameters
Vinyl Chloride
Trans- 1, 2-Dichloroethene
1 , 1 -Dichloroethane
Cis- 1 ,2-Dichloroethene
Chloroform
1,1,1 -Trichloroethane
Trichloroethene
Tetrachloroethene
Chlorobenzene
1, 1,2-2-Tetrachloroethane
1,2-Dichlorobenzene
Iron, Total
SPDES Limit (ug/1)
10
10
10
10
10
10
10
10
10
10
10
4000

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Effluent is also measured monthly for benzene, toluene, ethylbenzene, xylene (Total), and MTBE. These
are not specifically contaminants of concern at the Brewster Site but are compared to Federal and State
MCLs for tracking purposes.
3.3
ACTION LEVELS
The ROD specifically refers only to Federal and State standards for ground water concentrations of TCE
(a federal standard of 5 ug/1 and a state standard of 10 ug/1 at the time of the ROD).  The state standard
has since been reduced to 5 ug/1. The current federal and state standards, as reported in the draft annual
reports, are provided in the table below.
VOCs:
Vinyl Chloride
Trans- 1, 2-Dichloroethene
1 , 1 -Dichloroethane
Cis- 1 ,2-Dichloroethene
Chloroform
1,1,1 -Trichloroethane
Trichloroethene
Tetrachloroethene
Chlorobenzene
1 , 1 ,2-2-Tetrachloroethane
1 ,2-Dichlorobenzene
Benzene
Toluene
Ethylbenzene
Xylenes, total
Methyl tert-butyl ether
Inorganics:
Iron, Total
Calcium
Manganese
Sodium
Total Chloride
Other Field Parameters:
Total Coliform Bacteria
Temperature
pH
Conductivity
Turbidity
Dissolved Oxygen
MCL (EPA)2 ug/1
2
100
7
70
1005
200
5
5
100
NA
600
5
1,000
700
10,000
4

3006
-
506
-
-

-
-
-
-
-
-
MCL (NYS)3 ug/1
2
5
5
5
1005
5
5
5
5
5
5
5
5
5
5
50

3006
NA
3006
NA
250,000

Any positive sample
-
-
-
-
-
ROD Criteria (ug/1)
_ 7
- 7
-7
7
_ 7
- 7
5
7
_ 7
- 7
-7
7
_ 7
- 7
-7
7

- 7
-7
7
_ 7
- 7


~
~
~
~
—
Notes: 1 Table based on 2000 Annual Report (Sevenson)
2 MCL = maximum contaminant level taken from National Primary Drinking Water Standards as established by
                the USEPA
        3       MCL = maximum contaminant level from 10 NYCRR Part 5, Subpart 1, Section 51
        4       Not included as part of the USEPA's Primary Drinking Water Standards.
        5       Total Trihalomethanes (chloroform, bromoform, bromodichloromethand and dibromochloromethane)
        6       If both manganese and iron are present, the total concentration of both metals should not exceed 500 ug/1
                (manganese is secondary standard).
        7       Not a ROD Parameter
                                                  10

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    4.0  FINDINGS AND OBSERVATIONS FROM THE RSE SITE VISIT
4.1           FINDINGS

The RSE team found a maintained and functional facility. The observations and recommendations given
below are not intended to imply a deficiency in the work of the designers, operators or site managers but
are offered as constructive suggestions in the best interest of the EPA and the public. These
recommendations have the benefit of several years of operating data unavailable to designers or site
managers.
4.2           SUBSURFACE PERFORMANCE AND RESPONSE

4.2.1          WATER LEVELS

According to the draft 2000 Annual Report, the following water level measurement events occurred
during 2000:

              monthly at DGC-7S and injection wells IW-6, IW-8, IW-10 and IW-12
              quarterly at total of 23 wells (does not specify which wells)
              annually (in November 2000) at total of 36 wells (does not specify which wells)

These water level measurements are not reported in the draft Annual Report, and equipotential maps
from the quarterly and/or annual events are also not provided in the annual report.  However, water level
maps were provided in the draft 1999 Annual Report based on measurements in September, 1999 (see
Figures 2-1 and 2-2). Flow patterns are discussed in Section 4.2.2.

4.2.2          CAPTURE ZONES

Figure 2-1, which pertains to the "shallow wells", appears to indicate flow to the southwest, from the
River towards the extraction wells (EW-1 to EW-4), but no water level measurements are available in the
shallow zone directly north of the extraction wells.  In the intermediate wells (Figure 2-2), however,
ground water appears to flow towards the River to the northeast, except in the immediate vicinity of the
extraction wells. In each case, the interpretation is severely limited by the number of measurement
points, and interpretation of discharge into or out of the River is also limited by lack of river stage
measurements.

During the RSE visit, the site managers indicated that capture was likely not sufficient under current
pumping conditions to prevent impacted ground water from flowing to the north, into or beneath the
River.

4.2.3          CONTAMINANT LEVELS

Based on the draft 2000 Annual Report, influent concentrations to the air stripping system for key
constituents are as follows:
                                             11

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Constituent
PCE
TCE
cis-l,2-DCE
trans- 1,2-DCE
vinyl chloride
Influent During
2000 (ug/1)
80 - 132
5-8
36-47
ND-0.7
ND-3
Discharge Limit
(ug/1)
10
10
10
10
10
Federal MCLs
(ug/1)
5
5
70
100
2
NYS MCLs
(ug/1)
5
5
5
5
2
Based on a table handed out during the RSE visit, the following concentrations were observed at the
extraction wells in November 2000 and March 2001:

PCE (ug/1)
TCE (ug/1)
cis- 1,2-DCE (ug/1)
trans- 1,2DCE (ug/1)
vinyl chloride (ug/1)
EW-1
385/793
11/22
103/195
1
3/5
EW-2
20/60
4/10
25/72
ND
ND/3
EW-3
20/21
4/4
ND/13
ND
ND/ND
EW-4
3/12
ND/2
ND/2
ND
ND/ND
Max Concentration
in Other Wells
93/158
28/54
388/448
4
277/45
Because individual flow rates at the wells cannot be monitored, it is assumed that flow rate is roughly
equal from all four wells. If that is the case, than the vast majority of mass being removed by the system
is being removed by EW-1. Minor amounts of mass are being removed by the other extraction wells.

By comparing the concentrations at the extraction wells to the maximum concentration at other wells, it
appears that the current extraction wells are not ideally located for addressing maximum concentrations
of cis-1,2-DCE and vinyl chloride in the aquifer.

The table handed out during the RSE visit also indicated concentrations at wells existing in 1985 and
1994. Peak concentrations of PCE were much higher (more than 1000 ug/1 at DGC19I and DGC-6I) in
1985 and 1994 than observed recently. The same is true for TCE (89 to 311  ug/1 at DGC-19I and DGC-
61 in 1985 and 1994). Therefore, peak concentrations have gone down over time. This may be due to any
or all of the following:

              removal of the source and dilution of the plume by hydrodynamic dispersion
              mass removed by the ground water pump-and-treat system
              in-situ biodegradation

It would be difficult, if not impossible, to quantify the contribution of these processes.
                                              12

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4.3           COMPONENT PERFORMANCE

4.3.1          EXTRACTION WELLS AND PUMPS

Only the total system flow rate is available, since there is no way to attach individual flow meters to the
wells as constructed. During the year 2000 the total flow rate averaged 37.6 gpm. This is a decrease
from previous years, which were typically 45-50 gpm (e.g., 44.7 gpm in 1999).  This has been attributed
to the scale buildup in the effluent drain line.

The extraction well vaults are prone to flooding and offer limited access for maintenance and
adjustments. The pumps have been replaced one time each over the 5 years since continuous operation
began.

4.3.2          AIR STRIPPER

The packing in the air stripper becomes fouled with calcium carbonate deposits.  To prevent plugging the
column is cleaned quarterly by shutting down the wells and re-circulating acetic acid through the column
packing for 24 hours. The acid re-circulation sump and the discharge sump are located inside the
treatment building.  After cleaning the used acid is diluted and discharges slowly to the River. The
distribution plate for the air stripper is removed and treated with a bleach solution once per year. No iron
fouling has occurred, but the air stripper at the Village Well Field across the River experiences iron
fouling. Because the air flow-rate through the air stripper was not available, it may or may not be at the
optimum rate.

4.3.3          DISCHARGE LINE

The effluent line leading from the air stripper discharge sump to the River has recently plugged with
calcium carbonate.  The Corps of Engineers Kansas City District personnel are evaluating the problem
and are considering adding a sequestering agent to the water to prevent the effluent line from plugging,
which could also eliminate the need for periodic cleaning of the air stripper packing.  They are
reportedly designing a new discharge line, and discharge is currently occurring through a temporary
above-ground PVC line.

4.3.4          CONTROLS

Currently electronic controls automatically call a third-party service if there is a problem with the system.
4.4           COMPONENTS OR PROCESSES THAT ACCOUNT FOR MAJORITY OF
              MONTHLY COSTS

In the ROD, the anticipated capital cost for the system south of the River was estimated at $164K and
O&M cost was estimated at $27K/year. The actual O&M is about $360,000 per year (based on
information provided by the USAGE project manager), which is more than 10 times what the ROD
projected.  Even if the estimated amount is adjusted for inflation, the current amount is many times
higher than that projected in the ROD.

The following cost breakdown was presented by the USAGE project manager:
                                            13

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 administration, oversight, review, QA, analysis (Army Corps)                $120,000/yr

 subcontractor project management                                          $ 12,000/yr

 reporting                                                                 $62,000/yr

 sampling analysis and labor (ground, surface, and process water)               $67,000/yr

 equipment rental                                                          $ 15,000/yr

 weekly operator checks                                                    $9,000/yr

 electric power                                                            $15,000/yr

 phone                                                                   $l,500/yr

 electronic monitoring service for emergencies                                $l,000/yr

 tower acid rinse                                                           $ 12,000/yr

 site maintenance                                                          $10,000/yr

 travel/per diem                                                           $21,000/yr

 repairs and field supplies                                                  $6,000/yr

 shipping                                                                 $6,000/yr

 miscellaneous                                                            $2,500/yr
                                                                        $360,000/yr
4.4.1           UTILITIES

As stated above, the utilities costs are predominantly electricity associated with the pumping wells and air
stripper and total approximately $15,000 per year.

4.4.2           NON-UTILITY CONSUMABLES AND DISPOSAL COSTS

The dominant costs in this category are associated with the acid wash, equipment rental, and site
maintenance.

4.4.3           LABOR

Labor is the major cost at this site. The management costs associated with the Army Corp of Engineers is
accounts for 30% to 40% of the total costs. Other labor costs are associated with  sampling, reporting, and
site visits by a local subcontractor.
                                               14

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4.4.4          CHEMICAL ANALYSIS

Based on the monitoring program summarized in Section 2.4, approximately 100 samples are collected
from the site each year. Additional samples for analysis include trip blanks, field blanks, and duplicates.
Approximately 25 such additional samples are likely analyzed per year. Given the analytical methods
used (EPA 524.2 plus BTEX compounds) this likely translates to analytical costs of approximately
$30,000 to $35,000 per year.
4.5           RECURRING PROBLEMS OR ISSUES

Originally, fouling of the air stripper required re-packing (performed in 1997 and 1998). Subsequent
procedures put in place, involving quarterly washes with acetic acid, have remedied this problem, and no
additional re-packings have been performed since 1998.  During the RSE visit the building had a strong
acid smell from a recent acetic acid wash.  This occurs because the acid re-circulation sump and the
discharge sump are located inside the treatment building.

During the RSE visit it was stated that quarterly ground water sampling events (12 wells) sometimes takes
up to 8 days to complete because of extended time for stabilization of parameters in the field. In
discussions subsequent to the RSE site visit, the USAGE project manager confirmed that this is an
anomaly characteristic of initial sampling events and does not accurately represent recent or upcoming
sampling events.
4.6           REGULATORY COMPLIANCE

Clogging in the air stripper caused exceedances of discharge standards in 1998. Subsequent procedures
put in place involving regular washes of the air stripper with acetic acid and regular washes of the air
stripper influent distributor with bleach have remedied this problem.
4.7           TREATMENT PROCESS EXCURSIONS AND UPSETS, ACCIDENTAL
              CONTAMINANT/REAGENT RELEASES

None were noted during the RSE site visit.
4.8           SAFETY RECORD

The system has an excellent safety record with no documented injuries with the exception of contact with
poison ivy.
                                           15

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      5.0  EFFECTIVENESS OF THE SYSTEM TO PROTECT HUMAN
                       HEALTH AND THE ENVIRONMENT
5.1           GROUND WATER

One goal of the system south of the River is containment. However, containment has not been sufficiently
demonstrated in the annual O&M reports, and when queried during the RSE visit, site managers stated
that the current system was likely not achieving containment.

Another goal of the system south of the River is aquifer restoration.  It appears that peak levels of PCE
and TCE have been decreasing since continuous system operation began in 1996. However, it is not clear
that those concentrations are the result of the pump and treat system.  The stable or increasing
concentrations of cis-l,2-DCE and vinyl chloride during that period indicate that in-situ biodegradation is
an important, if not the most significant, cause of those peak concentration reductions.

It appears unlikely that the current system will achieve the restoration goal.  Three of the wells are
removing water with relatively low concentrations (only EW-1 appears to be removing ground water with
high concentrations).  It is not likely that the current system will be effective at restoring the aquifer near
some of the most impacted wells, particularly those impacted significantly by cis-l,2-DCE and/or vinyl
chloride (DGC-19, DGC-7I, TH-7).
5.2           SURFACE WATER

Hydraulic containment at the southern edge of the River is likely not achieved, and some shallow ground
water impacted by VOCs likely discharges to the River from the south. Based on the volatile nature of the
contaminants and the relatively low concentrations in ground water, it is not likely that such discharge
would cause negative impacts to the surface water. The site team reports that quarterly sampling of
surface water for VOCs repeatedly show undetectable concentrations.
5.3           AIR

Vapor phase carbon is not employed at this site. Based on the low influent concentration of
approximately 100 to 200 ug/1 of total VOC's, at a rate of 50 gpm, the total mass per day removed by the
stripper and released to the atmosphere can be approximated as follows:

             200 ug/1 * 50 gpm * 3.785 L/gal * 2.21b/lE-9  ug * 1440 min/day = 0.1 Ibs/day

This is not likely to cause any negative impacts.
                                             16

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5.4           SOILS

Contaminated soil was removed as part of the source remediation. Further evaluation of soils
contamination was not addressed during the RSE.
5.5           WETLANDS AND SEDIMENTS

Wetlands and sediments were not specifically addressed during the RSE. However, to the extent that
hydraulic containment at the southern edge of the River is not achieved, and some shallow ground water
impacted by VOCs discharges to the River from the south, there is a potential for impacts to sediments in
the River and/or wetlands along the River. Also, if pumping is shifted to the east, there is a potential for
pumping to result in de-watering of some wetland areas that may not be impacted by pumping from the
current system.
                                            17

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                             6.0  RECOMMENDATIONS
Cost estimates provided herein have levels of certainty comparable to those done for CERCLA Feasibility
Studies (-307+50%), and these cost estimates have been prepared in a manner consistent with EPA
540-R-00-002, A Guide to Developing and Documenting Cost Estimates During the Feasibility Study,
July 2000.
6.1           RECOMMENDATIONS TO IMPROVE EFFECTIVENESS

As stated in Section 5.1, the current system is not entirely effective with respect to the ROD objectives,
which are containment and aquifer restoration.

The recent site documents do not include or reference a clearly stated conceptual model of ground water
flow and contaminant transport at the site. A site conceptual model should identify all key issues and/or
components of the system that must be understood to adequately assess system effectiveness and evaluate
progress towards meeting the ROD objectives.  The process should include the following steps:

       •      state a preliminary conceptual model that identifies gaps in site understanding
       •      collect information to address the gaps in site understanding
       •      refine the conceptual model based on the newly collected data

Furthermore, the site goals and associated target capture zone should be consistent with the conceptual
model. Sections 6.1.1 through 6.1.6 present recommendations to improve the site conceptual model and
the system as a whole.

6.1.1          DEVELOP A PRELIMINARY BUT COMPREHENSIVE UPDATED CONCEPTUAL MODEL OF
              GROUND WATER FLOW AND CONTAMINANT TRANSPORT

The RSE team feels a current site conceptual model should be developed and documented to ensure that
all of the site managers agree on the processes governing ground water flow and contaminant transport at
the site. This documented site conceptual model will serve a central reference to site managers as
decisions are made and progress toward or achievement of system goals are evaluated. The site
conceptual model should be derived from interpretation of historical and current site data including, but
not limited to, ground water elevations, pump test results, ground water quality, surface  water quality,
geological cross sections, and surface water elevations.  The site conceptual model  should be included in
the next annual report and revised as necessary in each subsequent annual report. The following questions,
and others, should be addressed by the conceptual model?

       •      What are the roles of the two air stripping systems in achieving containment of the
              contaminant plume and restoration of the aquifer?   How do these two systems affect
              each other hydrogeologically? Does  pumping from one system prevent the other system
              from achieving its goals?

       •      What is  the "target capture zone" for the system south of the site?
                                             18

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       •       What is the actual capture zone of the existing system, and how does it compare to the
               target capture zone?

       •       Are impacts north of the River near TH-7 being drawn to the village wells or the
               extraction system south of the River, or discharging to the River?

       •       Will the current system achieve the ROD goal of aquifer restoration at locations near
               DGC-19I, DGC-7I and TH-7 (which are  impacted and appear to be distant from the
               current extraction wells)?

       •       What are contaminant levels (and plume  extent) south of the current extraction system?

       •       Why are the "hot spot" areas and overall  plume extent for PCE and TCE different than
               those for cis-l,2-DCE and vinyl chloride?

       •       Does ground water south of the River discharge to the River, flow under the River, or
               both?

       •       How long will it likely take to meet the ROD objective of aquifer restoration with the
               current system?

       •       What steps could be considered to improve the likelihood of achieving aquifer restoration,
               and/or decreasing the time to aquifer restoration?

The site managers may have partial answers to many of these questions and may have discussed them
previously, but formulating complete answers based on data and documenting them will ensure a
conceptual model that is consistent with the data and acceptable to all site managers and associated
technical staff.  The conceptual model should also indicate any data gaps, and highlight those data gaps
that must be resolved to ensure the remedy is progressing as intended.  The goal of future data collection
should be, in part, to resolve the issues listed above.

Generating and  documenting this conceptual model should require approximately $7,500. As mentioned
previously, the associated text should be included in the next annual report.  Updates to the conceptual
model should be included in the subsequent annual reports and should cost approximately $2,500 to
develop and document (in addition to costs associated with collecting actual data that would be the bases
for the modifications).

6.1.2           ADDITIONAL PLUME DELINEATION SOUTH OF EW-1

Based on the plume maps presented in the annual reports, there are no monitoring wells south (i.e.,
upgradient) of extraction well EW-1.  DGC-19 is located  directly between the former source and EW-1
and has concentrations of 79 ppb PCE and 211 ppb cis-1,2 DCE. However, no wells are located to the
west of DGC-19 (south of EW-1) to delineate the extent of this contamination. Since EW-1 extracts water
with high concentrations of contaminants, it is important  to determine the level of impacts, and the extent,
of the plume in that direction. A prudent approach would be to perform a GeoProbe investigation of
shallow and intermediate ground water south of EW-1. Approximate cost for that investigation might be
$35,000. Based  on the results of that investigation, 2 to 4  new monitor wells might be installed (for
preliminary cost estimates in this RSE,  assume one shallow well and one intermediate well). Capital costs
for that might be $40,000, and additional monitoring costs associated with those wells might be $5,000
per year. Consideration should also be  given to delineating the plume to the northwest of TH-7. Ground


                                               19

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water in this vicinity presumably flows to the Village Well Field where it is extracted and treated.
Obtaining water levels from this location would also help in developing potentiometric surfaces and
evaluating capture provided by the Village Well Field.  A more thorough review of existing data should
help site managers determine the necessity of this additional monitoring location.

6.1.3          DEFINE THE "TARGET CAPTURE ZONE"

To assess the ability of the GMS to meet the containment objective in the ROD, the area to be contained
must be clearly established and plotted on a figure (based on recent plume maps).  Both vertical and
horizontal extent of the plume and all constituents of concern  should be considered. Because the Village
Well Field is located within the contaminant plume  (as evidenced by contamination in the extracted water)
and is pumping at approximately 200 gpm, it is infeasible for the GMS (which pumps up to 50 gpm) to
contain the entire plume.  The GMS, however, can contain a portion of the plume and thereby reduce the
migration of contamination to the Village Well Field. The target capture zone should consider these
hydrogeologic limitations and the remedy goals. Although the ROD requires containment of the area to
the south of the River, the site managers may feel the ground water contamination around TH-7 should
also  be contained. Assuming the Village Well Field air stripper continues to operate effectively,
protectiveness should be maintained in either case.

The  specific target capture zone should be clearly outlined on a current plume map and must consider all
contaminants of concern (including PCE, TCE, cis-1,2 DCE, and vinyl chloride). If concentrations
fluctuate between sampling events, a number of recent sampling events should be considered when
selecting the target capture zone.  This process should include input from the  RPM, EPA hydrogeologist,
and contractor. Previous site documents and data, including risk analyses, should be considered. The
conceptual model recommended in Section 6.1.1 and the data  from sampling points recommended  in
Section 6.1.2 should also be considered. The target capture zone should be included in the next annual
report, and the cost for document/data review, discussion,  and outlining of the target capture zone should
not exceed $10,000.

6.1.4          INTERPRET ACTUAL CAPTURE WITH RESPECT TO THE "TARGET  CONTAINMENT ZONE"

Reliable potentiometric surface maps should be developed using water level  data collected from
piezometers and monitoring wells. Water levels from both shallow and intermediate zones should be
considered.  This map, however, should not include water  levels taken from operating extraction wells
because the reduced water levels in these wells inaccurately represent the water levels in the surrounding
aquifer, thereby biasing the analysis in favor of capture. Arrows indicating ground water flow directions
and the interpreted capture zone should be provided on this map. Then, the interpreted capture zone
should be superimposed on the "target capture zone". If the actual  capture zone encompasses the target
capture zone, then adequate containment is suggested.  This capture zone analysis should confirm that
contaminated ground water is not discharging to the East Branch Croton River.

It should be noted that while this approach provides the best preliminary analysis for capture, insufficient
data set may exist. Additional data points may be needed (i.e., new piezometers, river stage
measurements, elevations of wetlands, etc.). Additional monitoring wells and piezometers may need to be
installed for clearly resolving the potentiometric surface in heterogeneous formations.  For example,
piezometer pairs can be installed in specified locations to resolve the direction of ground water flow in
that location of the aquifer.  Installing continuous water-level  recorders for river stage measurements and
for selected piezometers, for a specified time period, might add valuable information and should also be
considered.  In the process of reviewing the data and conducting the capture zone analysis, previous
                                               20

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reports should be reviewed to determine if the site wells need to be re-surveyed with respect to a common
reference point.

The capture zone analysis with the potentiometric surface should be augmented by other lines of evidence
including concentration trends in monitoring wells. Sentinel monitoring wells located downgradient of
the extraction system should show decreasing trends in contaminant concentrations over time if capture is
adequate.  Increases in concentrations, or persistent high concentrations, likely indicate a lack of capture.
For example, the relatively high concentrations in TH-7, might indicate that contamination continues to
migrate beyond the extraction system and under the River toward the Village Well Field.

Approximate flow budgets should also be considered. For example, the Village Well Field extracts
approximately four times more water than the GMS. If the two extraction systems are located in the same
formation, the Village Well Field may have a capture zone four times larger than the GMS. Data from
pump and recovery tests may yield additional information about the zones of influence of these extraction
systems, but it should be noted that a zone of influence does not necessarily correspond to the capture
zone.

Developing a ground water flow model and using particle tracking in the simulated flow fields can also be
used in evaluating capture. The  consideration of a ground water flow model should be postponed until the
preliminary capture zone analysis is complete and data gaps are identified.  Once complete, a better
understanding of the modeling needs will be better understood.  Developing a ground water flow model
may not be necessary or cost-effective at this site. As a guideline, costs for developing for this site and
properly calibrating it, if necessary, should not exceed a one time cost of $35,000, and use of the model
and recalibrating it, once developed, should not exceed $10,000 per year.

This capture zone analysis should initially focus on the interpretation of existing data. Once the analysis
is complete, significant data gaps can be identified and additional piezometers can be considered, if
necessary.  A base map for the site already exists, and potentiometric surfaces have been generated in the
past. Development of the new potentiometric surface map, identification of ground water flow  directions,
consideration of concentration trends in sentinel wells, consideration of pump test data and approximate
flow budgets, interpretation of the capture zone, comparison of the interpreted capture zone to the target
capture zone, and documentation of the entire process in the next annual report should require
approximately $15,000.  Conducting subsequent capture zones once a year and documenting them in the
annual report should cost approximately $5,000.  The cost of installing  additional monitoring points is not
included in these costs as the number of necessary points cannot be determined without conducting the
preliminary capture zone analysis and identifying the crucial data gaps.

6.1.5          DEVELOP A REVISED CONCEPTUAL MODEL

Once the items in Section 6.1.1 to 6.1.5  are complete, a revised conceptual model  should be developed
and clearly stated and/or referenced in future site documents (i.e., the annual reports). The cost of these
revisions and documentation is included in Section 6.1.1.

6.1.6          REPLACE EW-2 TO EW-4 WITH NEW EXTRACTION WELLS

As noted in the RSE report, extraction wells EW-2 to EW-4 are pumping ground water at relatively low
concentrations, while impacted areas further east (DGC-19, DGC-7I) are not located close to any
extraction wells. Based on the revised conceptual model, perhaps one to three new extraction wells
should be installed, to the east of EW-1.  Any new extraction well should include pitless adapters and
separate electrical vaults or risers at each extraction well (unlike the present wells, which have limited


                                               21

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access and poorly conceived electrical connections). Water from each extraction well should be routed to
the treatment building in individual HDPE lines. Flow from each well can then be metered at the
treatment building (unlike the present system, where individual flow rates cannot be measured). EW-1
should be retrofitted in a similar manner.  EW-2 to EW-4 should probably be decommissioned.

The specific locations of these new wells should consider containment of the plume, mass recovery, and
potential de-watering of the wetlands. Before proceeding, the appropriate target capture zone (Section
6.1.2) should be determined and a preliminary capture zone analysis of the current system should be
completed.  Updated plume maps and analysis of concentration trends in monitoring wells should also be
analyzed before proceeding. Finally, a wetlands evaluation may be required to determine the potential for
de-watering the wetlands from new extraction wells. The scope and goal of the wetlands evaluation
should be narrow and clearly defined with a specified time frame.  Prior to the evaluation, site managers
should discuss the relative priorities of containing the plume, remediating the  aquifer, and maintaining the
wetlands. Data likely exist from previous pump and recovery tests that will help determine the expected
drawdown in the wetlands due to current pumping efforts and potential future pumping  efforts.

If new wells are installed south of the river to contain the plume south of the River, the concentrations in
TH-7 and points north of the River will eventually decrease due to degradation and extraction and
treatment by the Village Well Field.  If wells are installed north of the river to contain the contamination
near TH-7,  additional costs will be required to pipe the water beneath the River, but the  contamination
would be addressed directly by the GMS.  Alternative technologies could be considered for addressing the
contamination near TH-7, but the costs of installing and operating the systems may not outweigh the
benefits, primarily because the Village Well Field and associated air stripper will continue to extract and
treat the water. Furthermore, these technologies would likely require continued operation of the GMS.

Site managers should aim to have the extraction wells relocated by the end of fiscal year 2003.  This gives
ample time to conduct the steps outlined above, including addressing the data gaps by installing new
monitoring points and collecting and interpreting additional rounds of water levels. The site managers
should layout a schedule for achieving this goal, complete with contingencies for delays that are expected.

Approximate capital costs for installing the wells, vaults, and piping might be $125,000. The total flow
rate may be the same as the current system, but the air stripper (perhaps with minor modifications) can
handle additional flow from new wells if necessary. The cost of the wetlands evaluation and other
planning should be completed for under $20,000.
6.2            RECOMMENDED CHANGES TO REDUCE COSTS

In the experience of the RSE team, an air-stripping system that pumps less than 100 gpm and treats
concentrations on the order of several hundred ppb of VOC's (i.e., requires only sporadic attention for
operation such as the weekly, monthly, quarterly O&M schedule currently employed) should cost
$200K/yr or less (compared to the $400K/yr identified for this site).  Sites vary in complexity and the
technical assistance required, but specific opportunities for cost reduction at this site are presented below.

6.2.1           CUT MANAGEMENT EXPENSE

The U.S. Army Corps Of Engineers (USAGE) costs for administration, oversight, review, QA and analysis
of about $120,000 per year represent 30 to 40 percent of the site O&M costs. From discussions with the
EPA and USAGE project managers, the RSE team understands that these oversight costs cover costs
associated with contracting and management oversight of the subcontractor in addition to technical

                                               22

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oversight. The technical oversight contributes to the interpretation in the annual reports and to other
technical evaluations associated with making site decisions. Examples of technical oversight include
evaluating alternative technologies such as the use of hydrogen-releasing compound (HRC); planning for
wetlands evaluations; planning, preparing, and proposing a ground water flow model; and considering
alternate extraction well locations. In addition, costs are included for other plans or reports including a
sampling and analysis plan and remedial action work plan.

Although lumping all of these items into a single oversight task allows the USAGE project manager to
freely allocate funds from one item to the next as necessary, this lumping of funds makes it difficult to
determine the level of effort and cost associated with the individual components.  Thus, even as individual
components are completed, the technical oversight costs could remain the same. A more specific scope
for this technical oversight task will help the EPA RPM track and evaluate the costs of each item and
reduce the costs over time as items are completed.

The RSE team does not know the level of effort or cost required within the USAGE framework for
contracting and management oversight of the subcontractor. Assuming 15% of the non-USACE costs, this
oversight could be provided for $36,000 per year.

Approximately $62,000 is budgeted for reporting, and the USAGE project manager indicated that
approximately $50,000 of it is allocated to the subcontractor for preparing the reports.  The remainder is
presumably available for technical oversight that is typically required only for the annual report.
Recommendations 6.1.1 through 6.1.6 highlight items that should be  included in the annual reports and
provide cost estimates for those items. In addition to those items, the RSE team estimates that
approximately $6,000 per year might be required for technical oversight on the annual report.

In addition to the above items, technical oversight could be provided  for evaluating new strategies or
technologies to augment or replace the current GMS.  Such evaluations should be limited in scope and
conducted every couple of years as technology options become available. A preliminary evaluation of
approximately $5,000 is likely sufficient to determine if a technology is worth pursuing further. This
preliminary evaluation should consist of contacting vendors of the technologies to determine costs for
application. Although pilot studies may be considered as a preliminary step, the costs for applying the
technology site wide  should be considered. If a site-wide application  is considered too costly, then even a
pilot test is generally not worth pursuing. Having the site conceptual model on hand and detailed annual
reports will help the site team determine the technologies worth considering and communicating site
features to vendors.  Once again, these preliminary evaluations should only occur every couple of years as
necessary and should be limited in scope rather than being a continuous, broad or general task.

Accounting for the costs of the items specified in Section 6.1 and those items included in this section,
suggested oversight costs can be summarized as follows:
Item
Management oversight
Oversight on annual reports
Evaluation of alternate technologies
Conceptual model
Target capture zone
Annual Costs for 1st Year
after RSE
$36,000
$7,500
$5,000
$7,500
$10,000
Annual Costs for Subsequent
Years after RSE
$36,000
$6,000
$5,000
$2,500
$0
                                               23

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Item
Capture zone analysis
Wetlands evaluation
Ground water flow model

Subtotal
10% contingency for a conservative estimate
Total
Annual Costs for 1st Year
after RSE
$15,000
$20,000
$0

$101,000
$10,100
-$110,000
Annual Costs for Subsequent
Years after RSE
$5,000
$0
contingent on need*

$54,500
$5,450
-$60,000
* A model may not be necessary or cost-effective for the site. Analysis of the existing data will help determine the need. See
Section 6.1.4 for guidelines on estimated costs for development, model updates, and simulations.

Thus, over the next two or three years, the oversight costs should reduce by approximately 50% from
$120,000 per year to approximately $60,000 per year.
6.2.2
REDUCE SAMPLING AND ANALYSIS, EQUIPMENT RENTAL, AND TRAVEL/PER DIEM
COSTS
The costs of the VOC analysis by EPA Method 524.2 plus BTEX and MTBE analysis are about twice that
of the commonly used EPA 8260B.  It should be straightforward to justify switching to EPA 8260B,
which is widely used at Superfund sites.  Changing analysis methods would yield a cost savings of about
$15,000 per year.  The site managers conveyed to the RSE team that the EPA Method 524.2 is used due to
a state mandate because of the potential for connecting the plant effluent to the water supply. Because
this connection may take years to occur or may never happen, Method 8260B should be used until the
connection becomes a reality.  Method 8260B should also be used for aquifer and surface water samples
as it generally is for other Superfund Sites. The detection limits for 8260B and 524.2 are the same so a
loss of information should not occur. The site managers should discuss the motivations for changing
methods with the state so that the sampling can proceed cost effectively with no sacrifice to system
effectiveness.

The costs reported for sampling and analysis ($67,000), equipment rental ($15,000), and travel/per diem
($21,000) are presumably used to conduct the monthly inspections and the quarterly and annual sampling
events. Therefore, the total cost is $103,000.

In discussions subsequent to the RSE, the USAGE project manager confirmed that 3 days were required
for the quarterly sampling events and that delays in low-flow sampling due to the stabilization of turbidity
do not continue to prolong the sampling events. At this rate, the annual event should be completed within
5 days. Thus, a total of 14 sampling days are required per year at this site. An additional 8 days are
required for the monthly checks. An additional 4 days for two staff can be assumed for mobilization and
demobilization. Based on the professional experience of the RSE team and information gathered from
RSEs at other Superfund sites, a competitive cost for labor and  equipment for sampling at is
approximately $2,000 per day. This includes two staff working 10-hour days, transportation, per diem,
and equipment rentals. For a monthly inspection (including the sampling of the effluent), assuming a
billing rate of approximately $60 per hour, a 12-hour day, transportation, per diem, and equipment, the
cost should come to under $1,200.  The approximate total costs for labor, equipment, and travel associated
with sampling and monthly inspections should therefore be consistent with those outlined in the following
table.
                                              24

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Item
Quarterly and annual sampling
Monthly inspections
Mobilization and demobilization
Subtotal
Additional contingency for a conservative estimate
Total
Calculation
$2,000/day x 14 days
$l,200/day x 8 days
$2,000/day x 4 days

10%

Cost
$28,000
$9,600
$8,000
$45,600
$4,6560
-$50,000
The sampling and monthly inspection costs should be reviewed and compared to these estimated costs.
The total current costs are approximately $103,000. Given the above costs of $50,000 plus costs for
sample analysis (currently estimated at approximately $30,000 to $35,000), savings of approximately
$20,000 to $25,000 per year could likely be expected in addition to the estimated $15,000 per year that
can be saved by changing the analytical method.
6.2.3
REPLACE ELECTRONIC MONITORING SYSTEM WITH AN AUTODIALER
Using an autodialer system with direct dialing to inform the system operator of site alarms is as effective
as the current third party electronic monitoring service. Installation of an autodialer for less than $5,000
will eliminate the $1,000 per year fees for the electronic monitoring. The cost benefit of this
recommendation should be evaluated before proceeding.
6.3
MODIFICATIONS INTENDED FOR TECHNICAL IMPROVEMENT
6.3.1
INSTALL NEW UNDERGROUND DISCHARGE LINE
A new 6-inch diameter underground HDPE discharge line with no valves should be installed from the
treatment building to the River outfall. This line would be expected to operate for at least 5 years based on
the previous discharge line. The cost of installing this line should be less than $10,000.  This line should
not require detailed design for installation.  Designing  and installing an acid wash or sequestering system
solely for protecting this line is not cost effective.  Installing a larger diameter line with minimal design
effort will solve the problem because the current quarterly acid washing of the air stripper has kept the
system operating at high efficiency. The new discharge line will probably not experience fouling
problems.  Furthermore, this line will provide extra capacity in case higher flow rates are needed for
plume capture. Any further study of alternate fouling prevention studies should be suspended at least until
the new extraction system (i.e., with new wells) is operational.
6.3.2
IMPROVE TO ANNUAL O&M REPORTS
The annual reports should include a number of items pertinent to O&M. With respect to ground water
monitoring and system performance, the following are items that should be included:
                                             25

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       •       table(s) reporting water level data, including well name, screened interval, measuring
               elevation (i.e., top of casing), date, depth to water, and ground water elevation

       •       table(s) listing measured concentrations at monitoring wells

       •       potentiometric surface maps, including interpretations of ground water flow directions
               and interpreted capture zone (superimposed on a "target capture zone")

       •       updated plume maps with the target capture zone identified and interpretation of changes
               to the plume extent and magnitude

       •       time-series plots of concentrations in extraction and monitoring wells and interpretation
               suggesting the progress of aquifer restoration, or if sentinel wells, the adequacy of plume
               capture

       •       the site conceptual model with any updates

       •       a comprehensive well information table (name, date installed, ground elevation, top of
               casing, total depth, screened interval, aquifer classification, etc.)

       •       total amount of water extracted, a time series plot of the estimated mass removed, and a
               associated interpretation with respect to the system goal of aquifer restoration

A description of the well name convention, as it pertains to the aquifer that is screened (if in fact it does
so) would also be helpful. Other information is also pertinent and should be included as necessary. For
example, including a description of recently evaluated alternative remedial strategies may be appropriate.
It should be noted that some of these items are already included in the annual reports. The costs for
reporting and technical oversight were discussed in Sections 6.1 and 6.2.

6.3.3           ENSURE VAPORS FROM ACETIC ACID WASH COMPLIES WITH OSHA STANDARDS

The acetic acid vapors in the treatment building seem strong, especially during the acid wash. Efforts
should be taken to ensure that the vapors within the building comply with OSHA standards. Compliance
will be a function of exposure which consists of both concentration and duration of exposure. The first
steps in such an analysis are to note the time that the individuals are in the treatment building following
the acid wash, to determine the concentration of the solution used, and to determine the applicable
standards, OSHA Permissible Exposure Limit (PEL) and short-term exposure limit (STEL). These steps
are not time consuming and could be accomplished for a negligible increase in annual cost.  Further
actions should be taken, if these initial steps suggest over exposure.

6.3.4           MEASURE THE AIR FLOW THROUGH THE AIR STRIPPER

Measuring the air flow with a thermal anemometer or pitot tube may provide the opportunity to optimize
the air stripper. It may be determined that the capacity of the air stripper can be improved. There is a long
run of duct from the blower to the air stripper that is ideal for sampling flow rates. The stripper operates
effectively when the packing is clean,  so the measurement is not urgent. The measurement can be
conducted during a monthly or quarterly or site visit for under $500.
                                               26

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6.4           MODIFICATIONS INTENDED TO GAIN SITE CLOSE-OUT

6.4.1          CONTINUE EVALUATING ALTERNATIVE REMEDIAL OPTIONS

The RSE team notes three categories of approaches to future remedial strategy ranging from passive to
aggressive depending on future monitoring and the results of the revised conceptual model development.
At this time, the RSE team favors the moderate approach.

Passive Approach: Switch to Monitored Natural Attenuation

This passive approach becomes valid if further conceptual model development  suggests that site-related
contamination will not adversely impact any receptors.  This might require development of a numerical
flow and transport model, to demonstrate that migration of contaminants is sufficiently slow to allow
natural degradation of the contamination before it reaches any receptors. This would require a well-
calibrated transport model (which might be a challenge given the complex hydrogeology at the site) and
reliable evidence regarding in situ degradation of site-related contaminants. The high percentage of PCE
breakdown products, especially on the east side of the plume, indicate the possibility for degradation of
chlorinated solvents. Additional data to confirm and quantify the degradation rate is being collected and
evaluated. However, it should be noted that reductive dechlorination may successfully transform PCE to
TCE, TCE to  DCE, and DCE to vinyl chloride. These daughter products are as significant or possibly
more significant hazards for human and environmental health and vinyl chloride is more effectively
degraded in aerobic conditions. Thus, complete degradation of chlorinated aliphatic compounds such as
PCE to harmless  constituents would ideally involve anaerobic conditions to transform these compounds to
vinyl chloride, and then aerobic conditions to transform vinyl chloride to harmless end products.

Moderate Approach: Continue With Modified  Pump and Treat System

Given the history of impacts at the Village Well Fields and the continuing elevated plume concentrations,
pump and treat will likely continue to be required for plume containment. The current system should be
modified as per Sections 6.1.1  to 6.1.7. The system can then be used as a containment remedy, with
improved mass removal relative to the present system (and thus increased chance of achieving aquifer
restoration south of the River). Contamination beyond an appropriate capture zone would be extracted
and treated by the Village Well Field  system or eliminated by biodegradation.

Aggressive Approach: Enhanced Biodegradation

USAGE is currently evaluating the addition of electron donors such as HRC to augment reductive
dechlorination. Enhancement of the natural attenuation may be possible, but the cost of the enhancement
should be weighed against the  potential savings, which would result if pump and treat system operation
can be terminated at an earlier  date. For the current system, predicting a close out date for the pump and
treat system is virtually impossible. However, a revised system may have a better chance or achieving site
closeout, and the HRC system  should be compared to a revised pump and treat system.

If HRC is to be considered, it should be pilot tested.  However, that pilot test should not be conducted
until the cost of a full-scale system is  approximated. That will include a clear statement of the goals of a
full-scale system, and include the area over which a full-scale system would be required. It should include
an assessment of whether or not pump and treat will still be required in addition to the HRC.  It should
also address the potential to drive degradation to a point where vinyl chloride is produced (as is currently
observed in some monitor wells), because the resulting anaerobic conditions will not be well suited for
biodegradation of vinyl chloride to harmless products.


                                              27

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The RSE team feels that the likely outcome is that a full-scale HRC system will be very expensive, subject
to a high degree of uncertainty, and may not preclude the continued operation of a pump and treat system.
The RSE team feels that moderate approach (a revised pump and treat system) is likely the most cost-
effective approach to achieving the goals stated in the ROD.
6.5           UNUSED EQUIPMENT

The RSE team did not note any unused equipment that could be potentially useful at another site.


6.6           SUGGESTED APPROACH TO IMPLEMENTATION OF
              RECOMMENDATIONS

Concentrations in ground water have been reduced over time, probably due to a combination of the pump
and treat system and natural in-situ biodegradation. The site managers for the Brewster Wellfield
Superfund Site are considering alternate remedial strategies, and the RSE team applauds this proactive site
management and encourages further consideration of remedial options.

However, the RSE team recognizes that intent of remedy as stated in the ROD (i.e., hydraulic containment
and aquifer restoration of the plume south of the River) is not likely to be met by the current system.
Therefore, we suggest a series of recommendations in Section 6.1 to improve the conceptual model of
ground water flow and contaminant transport at the site, as well as to improve the ability to monitor
containment of ground water flowing towards the River from the South. We also recommend additional
ground water monitoring in a critical area south of EW-1, and based on the revised conceptual model,
replacing some of the existing extraction wells with one to three new extraction wells located to the east
of the current wells. These recommendations could feasibly be implemented by the end of fiscal year
2003.

In terms of cost reduction, the RSE team suggests immediate implementation of the cost saving measures
in Section 6.2.  The replacement of the discharge pipe, and suggested changes to  annual O&M reports,
should also be implemented immediately.

For site closeout (Section 6.4), we agree that the rate of natural attenuation should be evaluated as a
component of the site cleanup. We feel the most effective approach towards gaining site closeout,
however, is likely to be improving the effectiveness of the pump and treat system. Until the improvements
in effectiveness and costs are made, a major investment in other technologies available at this time does
not appear warranted.  Pilot testing of alternate remedies should only be performed if scale-up costs to a
full-scale system are calculated and  appear favorable in a cost-benefit analysis versus a revised extraction
system.
                                             28

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                                      7.0   SUMMARY
The observations and recommendations given below are not intended to imply a deficiency in the work of
either the designers or operators, but are offered as constructive suggestions in the best interest of the EPA
and the public.  These recommendations obviously have the benefit of the operational data unavailable to
the original designers.

The RSE process is designed to help site operators and managers improve effectiveness, reduce operation
costs, improve technical operation, and gain site closeout. Table 7-1 summarizes the costs and cost
savings associated with each recommendation.  Both capital and annual costs are presented. Also
presented is the expected change in life-cycle costs over a 10-year period (at the request of the Site
managers) for each recommendation both with discounting (i.e., net present value) and without it.
                                               29

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                                   Table 7-1. Cost Summary Table
Recommendation
6.1.1Preliminary conceptual
model
6.1.2 Additional delineation
south of EW-l(GeoProbe, new
wells)
6.1.3 Define target containment
zone
6.1.4 Interpret capture zone
6.1.5 Revise conceptual model
6.1.6 New extraction wells
6.2. 1 Cut oversight expense
6.2.2 Reduce Sampling and
Analysis, Equipment Rental,
and Travel/Per Diem Costs
6.2.3 Replace alarm monitoring
service with autodialer
6.3. 1 Install New Underground
Discharge Line
6.3.2 Improve to Annual O&M
Reports
6.3.3 Ensure Vapors from
Acetic Acid Wash Complies
with OSHA Standards
6.3.4 Measure the Airflow
through the Air Stripper
6.4.1 Continue evaluating
alternative remedial options
Reason
Effectiveness
Effectiveness
Effectiveness
Effectiveness
Effectiveness
Effectiveness
Cost
reduction
Cost
reduction
Cost
reduction
Technical
improvement
Technical
improvement
Technical
improvement
Technical
improvement
Gain site
closeout
Estimated Change in
Capital
Costs*
$7,500
$75,000
$10,000
$15,000
$0
$125,000
($10,000)*
$0
$5,000
$10,000
included in
6.2.1
negligible
$500
included in
6.2.1
Annual
Costs
included in
6.2.1
included in
6.2.1
$0
included in
6.2.1
included in
6.2.1
$0
($60,000)
($35,000 )
to
($40,000)
($1,000)
$0
included in
6.2.1
negligible
$0
included in
6.2.1
Life-cycle
Costs**
$7,500
$75,000
$10,000
$15,000
$0
$125,000
($610,000)
($350,000)
to
($400,000)
($5,000)
$10,000
$0
negligible
$500
$0
Life-cycle
Costs ***
$7,500
$75,000
$10,000
$15,000
$0
$125,000
($496,000)
($283,500)
to
($324,000)
($3,100)
$10,000
$0
negligible
$500
$0
Costs in parentheses imply cost reductions.
* includes oversight costs and cost savings associated with the first year following the RSE
** assumes 10 years of operation with a discount rate of 0% (i.e., no discounting)
*** assumes 10 years of operation with a discount rate of 5% and no discounting in the first year
                                                  30

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FIGURES

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FIGURE 1-1.  SITE VICINITY.
                                  S&G-3
                            DGC-5
                                        S&G-4
                                         S&G-2
                                       DGC-131
                                                    S&G-1
                                                DGC-1
                                                                 DGC-151
                                FORMER LOCATION
                                ALBEN CLEANERS
                                                                            -N-
                                  ซ
                                    DGC-141
     LEGEND
ฎ   MONITOR WELL
ฉ   EXTRACTION WELL
A   INJECTION WELL (NOT USED)
o   VILLAGE WELL
                                                  0
        200
                                                          SCALE  IN FEET
400

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                                            FIGURE 1-2. PCE IN GROUNDWATER, NOVEMBER 2000.
                                                                                          S&G-3   /
                                                                                        FORMER  LOCATION
                                                                                        ALBEN  CLEANERS
                                                                                                                                     -N-
        LEGEND
        MONITOR WELL
  ฉ    EXTRACTION WELL
  A    INJECTION WELL (NOT USED)
   o    VILLAGE WELL
	  PCE CONCENTRATION CONTOUR
                                                                                            DGC-14I
                                                                                               (0)
                                                                                                                       200
                                                                                                                  SCALE IN FEET
                          400
NOTE:  From 2000 Annual Report.

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                                            FIGURE 1-3. CIS-1,2-DCE IN GROUNDWATER, NOVEMBER 2000.
                                                                                            S&G-3
                                                                                                                                        -N-
                                                                     DGC-71
                                                            iw-io
                                                              •IW-9 , IW-
                                                                     '15.8
                                                                                          FORMER LOCATION
                                                                                          ALBEN CLEANERS
                                                                            CHRYSLER
                                                                             DEA\_ER
      LEGEND

ฎ    MONITOR WELL

ฉ    EXTRACTION WELL

A    INJECTION WELL (NOT USED)

o    VILLAGE WELL

   -   CIS-1.2-DCE CONCENTRATION CONTOUR
                                                                                                                                         400
                                                                                                                     SCALE  IN  FEET
NOTE:  From 2000 Annual Report.

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                                  FIGURE 2-1. SHALLOW GROUNDWATER ELEVATIONS, SEPTEMBER 1999.
                                                                                          S&G-3
                                                                                                                          DGC-151
     o  o  •   WELL
        o ฐ  FIELD  #1
                                  DGC-2I
                                 (331.33)  \   V
                                                                                                                DGC-12IA
                                                                                                                 (332.74)
                                                                                             4DDGC-13I
                                                                                             ^(333.33)
                          DGC-9I
                      / (332.01)
                                                                             DGC-8I
                                                                             (332.02)
                                                            DGC-7I
                                                            (330.44) A
                                                                                       DGC-181
                                                                                     0(333.91)
                                    /DGC-3I
                                   / (332.96)
                                                                                        FORMER  LOCATION
                                                                                        ALBEN  CLEANERS
 r^ GAS
//STATION
                                                                                                                                      -N-
      LEGEND
      MONITOR WELL

ฉ    EXTRACTION WELL

A    INJECTION WELL (NOT USED)
o    VILLAGE WELL
      SHALLOW  GROUNDWATER
                                                                                                              (332.74)
                                                                                                                     ELEVATION
                                                                                                                     SHALLOW GROUNDWATER
                                                                                                                     ELEVATION CONTOUR
                                                                                                                        200           400
NOTE:  From 1999 Annual Report.
                                                                                                                  SCALE IN FEET

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                                  FIGURE 2-2.  INTERMEDIATE GROUNDWATER ELEVATIONS, SEPTEMBER 1999.
                                                                                         S&G-3
                                                                                   DGC-5
o o  •   WELL
   o ฐ  FIELD #1
                               ฎDGC-2I \   \
                                 (332.38)  \   \
                                                                                ,-.-' DGC-181
                                                                                    ^332.49)
                                                          BRADY V   DGC-31ฎ
                                                         STANDARD
                                                                                               S&G-4
                                                                                                           S&G-1
                                                                                                       DGC-11
                                                                                                S&G-2
                                                                                              DGC-131
                                                                    DGC-12IA
                                                                    (332.00)
                                                                                                                   i  f
                                                                                                                   i  i
                                                                                                                   i  !
                                                                                                                  I  |    DGC-151
                                                                                                                  '  /  ^
                                                                                                                 /  i
                                                                                                                    i
                                                                                                                                    -N-
                                                                                      FORMER LOCATION
                                                                                       ALBEN CLEANERS
                                                                                           DGC-141
                                                                                         flr(332.90)
                                                                            LEGEND
                                                                      ฎ    MONITOR WELL

                                                                      ฉ    EXTRACTION WELL

                                                                      A    INJECTION WELL (NOT USED)
                                                                      o    VILLAGE WELL

                                                                            INTERMEDIATE GROUNDWATER
                                                                                                               (332.74)
                                                                           ELEVATION
                                                                           INTERMEDIATE GROUNDWATER
                                                                           ELEVATION CONTOUR
NOTE:  From 1999 Annual Report.
                                                                                                                      200
                                                                                                                 SCALE  IN  FEET
                                                                                           400

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                                                             Solid Waste and
                                                             Emergency Response
                                                             (5102G)
542-R-02-008t
October 2002
vwwv.clu-in.org/rse
www.epa.gov/tio
U.S. EPA National Service Center
for Environmental Publications
P.O. Box 42419
Cincinnati, OH 45242-2419

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