U.S.  Environmental Protection Agency
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                                                                                  ET
                                Arsenic  Monitoring Technologies

100
The U.S. EPA Environmental Technology Verification
(ETV) Program's Advanced Monitoring Systems (AMS)
Center, one of six technology areas under ETV, is
operated by Battelle under a cooperative agreement with
EPA. The AMS Center has verified ten technologies for
arsenic water monitoring1 (see verification reports at
http://wvvw.epa.gov/etv/verifications/vcenterl -21 .html).

Technology Description

Arsenic is typically measured using instruments that are
bulky and expensive to operate and maintain in a folly-
equipped laboratory. Field assays, in which lower sensi-
tivities may be acceptable for purposes of sample
screening or site surveys, strive for similar detection goals
as fixed laboratory methods, are relatively inexpensive,
and can produce a large number of screening results in a
short time. The ETV-verified  arsenic monitoring
technologies are portable and designed for rapid on-site
analysis of arsenic in water. They can be categorized into
two monitoring technology classes: colorimetric and
anodic stripping voltammetry. Table 1 lists the ten
verified arsenic monitoring technologies by technology
class.

 Colorimetric

 The arsenic colorimetric test kits involve a chemical
 reaction that converts the arsenic compounds (mostly
 inorganic arsenic) present in the water into arsine gas.
 The arsine gas is exposed to  a test strip, usually paper
 impregnated with a chemical that changes color from
 white to shades of yellow or brown with increasing
 arsine  levels. The concentration of arsenic can be
 approximated using a calibrated color scale. Measure-
 ments with the colorimetric test kits are semiquantitative,
 unless the field kits are equipped with a portable
 colorimeter and/or a computer held scanner mat allows
 for a quantitative determination of arsenic by quantifying
 the color change.

 Anodic Stripping Voltammetry

 Anodic stripping voltammetry (ASV) is an analytical
 technique in which analyte concentration is derived from
 the measurement of electric current as a function of ap-
 plied potential. Analysis involves reducing the analyte of
 interest and plating the analyte  onto an electrode by
 applying a negative potential for a specific period of
 time. The deposition serves to concentrate the analyte
 from the solution onto the electrode in the metallic form.
 After deposition, the potential is scanned toward positive
 potentials and the analyte is men stripped off (i.e.,
 oxidized), brought back into  solution and measured
 quantitatively relative to known standard solutions.

                                     (Continued on page 2)
                                                                       Arsenic and Its Regulatory
                                                                        Background at a Glance

                                                                Arsenic occurs naturally in rocks, soil, wa-
                                                                ter, air, plants, and animals. It can be released
                                                                into water, including drinking water, through
                                                                natural processes such as erosion, or through
                                                                human actions, including agricultural applica-
                                                                tions (fungicides or rodenticides), mining, or
                                                                disposal of arsenic-laden consumer products
                                                                (wood preservative, paints, dyes, soaps, and
                                                                semiconductors). Studies have linked long-
                                                                term exposure to arsenic at various levels in
                                                                drinking water to cancer of the bladder, lungs,
                                                                skin, kidney, nasal passages, liver, and prostate.
                                                                Non-cancer effects of ingesting arsenic include
                                                                cardiovascular, pulmonary, immunological,
                                                                neurological, and endocrine (e.g., diabetes) ef-
                                                                fects.

                                                                In January 2001, based in part on the National
                                                                Academies of Science recommendation and to
                                                                protect consumers against the effects of long-
                                                                term chronic exposure to arsenic in drinking
                                                                water, EPA set a new drinking water standard
                                                                for arsenic at 10 parts per billion (ppb) with
                                                                compliance by all public water systems re-
                                                                quired by January 2006 (66 FR 6976).
Table 1.
Verified Arsenic Monitoring Technologies
Colorimetric Test Kits
Technology Name
Industrial Test Systems, Inc.
Quick™ II
Industrial Test Systems, Inc.
Quick™ Ultra Low II
Industrial Test Systems, Inc.
Quick™ Low Range
Industrial Test Systems, Inc.
Quick™ Low Range II
Industrial Test Systems, Inc.
Quick™
Peters Engineering AS 75
Envitop Ltd. As-Top Water
Anodic Stripping Voltammetry
(ASV)
Technology Name
Monitoring Technologies Inter-
national, Pty. Ltd. PDV 6000
with VAS Version 2.1 Software
TraceDetect Nano-Band™
Explorer
TraceDetect SafeGuard Trace
Metal Analyzer




       The ETV Program operates largely as a public-private partnership through competitive cooperative agreements with non-profit research institutes. The
      program provides objective quality-assured data on the performance of commercial-ready technologies. Verification does not imply product approval or
      effectiveness. ETV does not endorse the purchase or sale of any products and services mentioned in this document.

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Table 2. Summary of Performance for Arsenic Monitoring Technologies
Technology*
A
Unitl
A
Unit 2
B
C
Unitl
C
Unit 2
D
E
F
G
H
1
Unitl
1
Unit 2
J
Accuracy8
(% relative bias)
-21 to 7
-21 to -8
-33 to 10
-46 to -4
-51 to 31
1to64
-24 to 18
-14.5 to 239
-47 to -8
8 to 83
2 to 70
2to>310
2 to 2900
Precision8
(% relative
standard de-
viation)
3 to 20
6 to 20
16 to 24
6 to 16
3 to 15
3 to 37
Oto14
Oto3
10 to 55
Oto29
Oto24
12to>71
0 to 111
Linearity8
slope
0.808
1.005
0.88
0.77
0.91
1.29
0.92
0.83
0.79
0.88
0.80
1.28
0.55
Intercept
0.060
1.618
-1.82
1.22
0.59
-5.56
0.22
2.61
-.03
-0.45
5.12
5.70
2.97
r2
0.9936
0.9942
0.9779
0.9934
0.9955
0.988
0.9948
0.9992
0.9904
0.988
0.979
0.923
0.66
False Positive
Ratec
(%)
0
0
0
0
0
13
0
3
0
0
3
13
18
False Negative
Ratec
(%)
4
22
19
42
38
7
14
0
62
5
0
0
30
Method Detection
Limits (MDL)8
(ppb)
3.75
2.87
7
8.6
5.8
14.2
2.9
3.1
1.2
Not Calculated
Not Calculated
28
Not Calculated
A Because the ETV Program does not compare technologies, the performance results shown in this table do not identify the technologies associated with
each result and are not in the same order as the list of technologies in Table 1.
B Technical operator sample results of performance test samples only
c Technical operator sample results of performance test samples, quality control samples, and environmental samples, relative to the 10 ppb maximum contami-
nant level for arsenic in drinking water
 Verified arsenic monitoring technology- coiorimetric
                                       (Continued from page 1)
                                       Test Design and Verification Results

                                       Arsenic measurements were compared to those from a laboratory-
                                       based reference method—inductively coupled plasma mass
                                       spectrometry (ICP-MS) performed according to EPA Method 200.8.
                                       Technology performance was tested by analyzing performance test
                                       (PT) samples, quality control (QC) samples, and environmental
                                       samples for the evaluation of test parameters.  Accuracy and linearity
                                       were assessed by comparing technology results to those from the
                                       reference method. Four aliquots of PT samples and environmental
                                       samples were analyzed to assess precision. Seven aliquots of a PT
                                       sample (five times the vendor-stated detection limit) were analyzed
to assess the detection limit. Potential matrix interference effects were
assessed with PT samples of 10 ppb arsenic concentration that contained
both low levels and high levels of potentially interfering substances. Some
technologies were verified using two identical units.  Results from the two
units were statistically compared to evaluate inter-unit reproducibility.
Operator bias was assessed by statistically comparing data from two
operators (technical and non-technical). The rates of false positive and
	. false negative results
 ETV Advanced Monitoring Systems Center   were evaluated relative
                                              to the 10 ppb level of
                                              detection. Table 2
                                              provides a summary of
                                              performance data for
                                              some of the test
                                              parameters.
   Robert Fuerst, EPA, fuerst.robert@epa.gov
             Tel: (919) 541-2220
   Amy Dindal, Battelle, dindala@battelle.org
             Tel: (561)422-0113
Verified arsenic monitoring technology— ASV
References

 U.S. EPA ETV, http://www.epa.gov/etv/.
 U.S. EPA Arsenic in Drinking Water, http:7/www.epa.gov/safewater/arsenic/.
 Monitoring Arsenic in the Environment: A Review of Science and Technologies for Field Measurements and
   Sensors, http://www.epa.gov/superfund/programs/aml/tech/news/asreview.htm.
                                                                                        EPA/600/S-07/005
                                                                                           January 2007

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