September 2005 05/24/WQPC-WWF EPA/600/R-05/140 Environmental Technology Verification Report Stormwater Source Area Treatment Device Vortechnics, Inc. Vortechs® System, Model 1000 Prepared by NSF International Under a Cooperative Agreement with U.S. Environmental Protection Agency ------- Environmental Technology Verification Report Stormwater Source Area Treatment Device Vortechnics, Inc. Vortechs® System, Model 1000 Prepared for: NSF International Ann Arbor, MI 48105 Prepared by: Earth Tech Inc. Madison, Wisconsin With assistance from: United States Geologic Survey (Wisconsin Division) Wisconsin Department of Natural Resources Under a cooperative agreement with the U.S. Environmental Protection Agency Raymond Frederick, Project Officer ETV Water Quality Protection Center National Risk Management Research Laboratory Water Supply and Water Resources Division U.S. Environmental Protection Agency Edison, New Jersey September 2005 ------- THE ENVIRONMENTAL TECHNOLOGY VERIFICATION PROGRAM U.S. Environmental Protection Agency NSF International ETV Joint Verification Statement TECHNOLOGY TYPE: APPLICATION: TECHNOLOGY NAME: TEST LOCATION: COMPANY: ADDRESS: WEB SITE: EMAIL: STORMWATER TREATMENT TECHNOLOGY SUSPENDED SOLIDS AND ROADWAY POLLUTANT TREATMENT VORTECHS® SYSTEM, MODEL 1000 MILWAUKEE, WISCONSIN VORTECHNICS, INC. 200 Enterprise Drive Scarborough, Maine 04074 http://www.vortechnics.com info@vortechnics.com PHONE: (877)907-8676 FAX: (207)878-2735 NSF International (NSF), in cooperation with the U.S. Environmental Protection Agency (EPA), operates the Water Quality Protection Center (WQPC), one of six centers under the Environmental Technology Verification (ETV) Program. The WQPC recently evaluated the performance of the Vortechs® System, Model 1000 (Vortechs), manufactured by Vortechnics, Inc. (Vortechnics). The Vortechs was installed at the "Riverwalk" site in Milwaukee, Wisconsin. Earth Tech, Inc. and the United States Geologic Survey (USGS) performed the testing. The ETV Program was created to facilitate the deployment of innovative or improved environmental technologies through performance verification and dissemination of information. The ETV program's goal is to further environmental protection by accelerating the acceptance and use of improved and more cost-effective technologies. ETV seeks to achieve this goal by providing high quality, peer-reviewed data on technology performance to those involved in the design, distribution, permitting, purchase, and use of environmental technologies. ETV works in partnership with recognized standards and testing organizations; stakeholder groups, which consist of buyers, vendor organizations, and permitters; and with the full participation of individual technology developers. The program evaluates the performance of innovative technologies by developing test plans that are responsive to the needs of stakeholders, conducting field or laboratory tests (as appropriate), collecting and analyzing data, and preparing peer-reviewed reports. All evaluations are conducted in accordance with rigorous quality assurance protocols to ensure that data of known and adequate quality are generated and that the results are defensible. 05/24/WQPC-WWF The accompanying notice is an integral part of this verification statement. VS-i September 2005 ------- TECHNOLOGY DESCRIPTION The following description of the Vortechs was provided by the vendor and does not represent verified information. The Vortechs is designed to remove settable and floatable pollutants from stormwater runoff. Based on the size of the grit chamber, the Vortechs Model 1000 maximum operating flow rate is 1.6 cfs (720 gpm). Untreated stormwater enters the Vortechs through an inlet pipe that is tangential to the grit chamber. This creates a swirling motion that directs settleable solids into a pile towards the center of the grit chamber. Floating pollutants are trapped upstream of an underflow baffle. The Vortechs contains two flow controls in the last chamber of the system. The first control is designed to allow nearly-free discharge at very low flows so that very fine particles do not settle in the inlet pipe. This control begins to create a significant backwater at operating rates in excess of 5 gpm/ft2 of grit chamber surface area such that the inlet pipe becomes submerged at an operating rate of 20 gpm/ft2 of grit chamber surface area. This backwater creates a low-velocity entry into the grit chamber, which encourages stratification of pollutants in the inlet pipe. Under low flow rates, a small amount of material may settle out in the inlet pipe, but at higher flow rates, these relatively large particles will be transported into the grit chamber. Additional hydraulic capacity is provided over the top of the flow control wall so that the system does not cause upstream flooding at flow rates exceeding the maximum recommended operating rate of 100 gpm/ft2 of grit chamber surface area. The vendor claims that the Vortechs will provide a net annual removal efficiency of total suspended solids (TSS) that are typically encountered in runoff from urban environments in excess of 80%. According to the vendor's product literature, Vortechnics typically selects a system size that will provide an 80% annual TSS load reduction based on laboratory-generated performance curves for 50-(im sediment particles. VERIFICATION TESTING DESCRIPTION Methods and Procedures The test methods and procedures used during the study are described in the Final Test Plan for the Verification of Vortechs® Model 1000 Stormwater Treatment System, "Riverwalk Site," Milwaukee, Wisconsin. (March 2004). The Vortechs was installed to treat runoff collected from a 0.25-acre portion of the westbound highway surface of Interstate 794. Milwaukee receives an average annual precipitation of nearly 33 in., approximately 31% of which occurs during the summer months. Sampling was not conducted during winter months. Street sweeping occurred monthly during summer months. Verification testing consisted of collecting data during a minimum of 15 qualified events that met the following criteria: • The total rainfall depth for the event, measured at the site, was 0.2 in. (5 mm) or greater; • Flow through the treatment device was successfully measured and recorded over the duration of the runoff period; • A flow-proportional composite sample was successfully collected for both the inlet and the outlet over the duration of the runoff event; • Each composite sample was comprised of a minimum of five aliquots, including at least two aliquots on the rising limb of the runoff hydrograph, at least one aliquot near the peak, and at least two aliquots on the falling limb of the runoff hydrograph; and • There was a minimum of six hours between qualified sampling events. Automated sample monitoring and collection devices were installed and programmed to collect composite samples from the inlet and outlet during qualified flow events. In addition to the flow and analytical data, operation and maintenance (O&M) data were recorded. Samples were analyzed for: 05/24/WQPC-WWF The accompanying notice is an integral part of this verification statement. September 2005 VS-ii ------- Sediments • TSS Metals total and • total dissolved solids (TDS) • suspended sediment concentration (SSC) • particle size analysis VERIFICATION OF PERFORMANCE dissolved copper and zinc Nutrients Water Quality Parameters • total and • chemical oxygen dissolved demand (COD) phosphorus • total calcium and magnesium Verification testing of the Vortechs lasted approximately 16 months, and coincided with testing conducted by USGS and the Wisconsin Department of Natural Resources. Conditions during certain storm events prevented sampling for some parameters. However, samples were successfully taken and analyzed for all parameters for at least 15 of the 18 total storm events. In addition to the vendor's claim for sediment removal (TSS), the verification test plan included measurements for other water quality parameters. These verification factors were developed by a participating stakeholder group and technology panel, and provide ancillary performance data which is considered by many municipalities in addition to primary vendor claims when purchasing stormwater treatment technology. Environmental conditions and other factors which may have impacted TSS removal are addressed in Chapter 5 of the full report. Test Results Table 1. Rainfall Data Summary Event Number 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Date 4/30/03 5/4/03 5/9/03 5/30/03 6/8/03 6/27/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/25/04 3/28/04 4/17/04 5/12/04 5/20/04 8/3/04 8/24/04 Start Time 22:24 21:34 0:42 19:07 3:34 17:35 15:42 6:09 1:19 8:54 17:41 23:08 15:30 3:29 18:33 16:39 20:25 20:40 Rainfall Amount (in.) 1.1 0.72 0.87 0.54 0.62 0.57 0.30 0.47 0.27 0.23 0.71 0.85 0.87 0.24 0.55 0.24 1.8 0.85 Rainfall Duration (hnmin) 3:30 4:05 4:27 4:07 11:09 17:25 3:49 6:35 2:53 0:39 5:31 4:57 4:49 1:18 9:05 1:02 3:43 3:32 Runoff Volume (ft3)1 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 Peak Flow Rate (cfs) 1 0.352 0.059 0.084 0.164 0.466 0.101 0.039 2.02 0.057 0.055 0.138 0.023 0.025 0.026 0.076 1.26 2.45 1.02 1. Runoff volume and peak discharge rate measured at the inlet monitoring point. See the verification report for further details. 2. Peak flow rates exceeded the rated treatment capacity of the Vortechs unit indicating the unit may be undersized for the drainage area. 05/24/WQPC-WWF The accompanying notice is an integral part of this verification statement. VS-iii September 2005 ------- The monitoring results were evaluated using event mean concentration (EMC) and sum of loads (SOL) comparisons. The EMC evaluates treatment efficiency on a percentage basis by dividing the outlet concentration by the inlet concentration and multiplying the quotient by 100. The EMC was calculated for each analytical parameter and each individual storm event. The SOL comparison evaluates the treatment efficiency on a percentage basis by comparing the sum of the inlet and outlet loads (the parameter concentration multiplied by the precipitation volume) for all storm events. The calculation is made by subtracting from one the quotient of the total outlet load divided by the total inlet load, and multiplying by 100. SOL results can be summarized on an overall basis since the loading calculation takes into account both the concentration and volume of runoff from each event. The analytical data ranges, EMC range, and SOL reduction values are shown in Table 2. Table 2. Analytical Data, EMC Range, and SOL Reduction Results SOL SOL reduction reduction all events Inlet Outlet EMC range all events except 8 & 17 Parameter Units range range (%) (%) (%)' TSS SSC TDS Total phosphorus Dissolved phosphorus Total copper Dissolved copper Total zinc Dissolved zinc Total magnesium Total calcium COD2 mg/L mg/L mg/L mg/L as P mg/L as P Hg/L Hg/L Hg/L Hg/L mg/L mg/L mg/L 46- 50- <50- 310 820 290 0.062-0.68 0.014-0.24 21- 5.4- 100- 17- 3.7- 9.5- 27- 280 -75 920 350 -23 -48 310 28- 26- <50- 150 150 1,400 0.041-0.48 0.007-0.15 13- 120 5.4-43 84- 33- 520 330 2.3-10 9.3- 25- -43 220 -170 - 70 -90- 90 -1,100-25 -82- 52 -200 - 68 -83- 70 -250 - 52 -80- -380- -96- -120- 58 31 78 65 -170-57 18 58 -120 9.3 0 25 -10 16 -24 42 21 -15 35 61 -110 21 26 33 -12 24 -21 47 22 0 1. The SOL was recalculated excluding events 8 and 17, since the peak runoff intensity for these events exceeded the rated flow capacity of the Vortechs. Refer to the verification report for further details. 2. The outlet COD concentration for event 4 was 1,400 mg/L but considered an outlier and was not used in EMC or SOL calculations. The calculated SOL reduction for TSS, SSC, total and dissolved phosphorus, COD, and total metals improved when omitting the two events where the peak runoff intensity exceeded the rated flow capacity of the Vortechs (shown in the last column of Table 2). The high negative TDS removals were likely influenced by road salting operations. Dissolved-phase constituents, other than dissolved phosphorous, showed relatively little change when excluding events 8 and 17. The data suggest that scouring or resuspension may have occurred as a result of the high peak flow rates encountered during events 8 and 17. A particle size distribution procedure known as "sand-silt split" was conducted on samples as part of the SSC analysis. The sand-silt split procedure quantifies the percentage (by weight) of particles greater than 62.5 (im (defined as sand) and less than 62.5 (im (defined as silt). The percentage of sand in the inlet ranged from 2% to 58%, while the percentage of sand in the outlet ranged from 0% to 19%. This data was incorporated into the SOL calculation, revealing the reduction in the SSC sand fraction was 94% and the reduction in the SSC silt fraction was 21%. 05/24/WQPC-WWF The accompanying notice is an integral part of this verification statement. VS-iv September 2005 ------- System Operation The Vortechs was installed in December 2001, prior to verification, so verification of installation procedures on the system was not documented. The installed system cleaned and was inspected immediately prior to and during verification. Seven inspections of the unit were also performed during the test period. Upon completing the verification testing, the sediment chamber was cleaned out and contained sediment at depths ranging from 0 to 5.75 in., and approximately 120 Ib (dry weight) of sediment was removed from the sediment chamber. Quality Assurance/Quality Control NSF personnel completed a technical systems audit during testing to ensure that the testing was in compliance with the test plan. NSF also completed a data quality audit of at least 10% of the test data to ensure that the reported data represented the data generated during testing. In addition to QA/QC audits performed by NSF, EPA personnel conducted an audit of NSF's QA Management Program. Original signed by Original signed by Sally Gutierrez 10/3/05 Robert Ferguson 10/5/05 Sally Gutierrez Date Robert Ferguson Date Director Vice President National Risk Management Research Laboratory Water Systems Office of Research and Development NSF International United States Environmental Protection Agency NOTICE: Verifications are based on an evaluation of technology performance under specific, predetermined criteria and the appropriate quality assurance procedures. EPA and NSF make no expressed or implied warranties as to the performance of the technology and do not certify that a technology will always operate as verified. The end user is solely responsible for complying with any and all applicable federal, state, and local requirements. Mention of corporate names, trade names, or commercial products does not constitute endorsement or recommendation for use of specific products. This report is not an NSF Certification of the specific product mentioned herein. Availability of Supporting Documents Copies of the ETV Verification Protocol, Stormwater Source Area Treatment Technologies Draft 4.1, March 2002, the verification statement, and the verification report (NSF Report Number 05/24/WQPC-WWF) are available from: ETV Water Quality Protection Center Program Manager (hard copy) NSF International P.O. Box 130140 Ann Arbor, Michigan 48113-0140 NSF website: http://www.nsf.org/etv (electronic copy) EPA website: http://www.epa.gov/etv (electronic copy) Appendices are not included in the verification report, but are available from NSF upon request. 05/24/WQPC-WWF The accompanying notice is an integral part of this verification statement. September 2005 VS-v ------- Notice The U.S. Environmental Protection Agency (EPA) through its Office of Research and Development has financially supported and collaborated with NSF International (NSF) under a Cooperative Agreement. The Water Quality Protection Center (WQPC), operating under the Environmental Technology Verification (ETV) Program, supported this verification effort. This document has been peer reviewed and reviewed by NSF and EPA and recommended for public release. Mention of trade names or commercial products does not constitute endorsement or recommendation by the EPA for use. ------- Foreword The following is the final report on an Environmental Technology Verification (ETV) test performed for NSF International (NSF) and the United States Environmental Protection Agency (EPA). The verification test for the Vortechs® System, Model 1000 was conducted at a testing site in downtown Milwaukee, Wisconsin, maintained by Wisconsin Department of Transportation (WisDOT). The U.S. Environmental Protection Agency (EPA) is charged by Congress with protecting the Nation's land, air, and water resources. Under a mandate of national environmental laws, the Agency strives to formulate and implement actions leading to a compatible balance between human activities and the ability of natural systems to support and nurture life. To meet this mandate, EPA's research program is providing data and technical support for solving environmental problems today and building a science knowledge base necessary to manage our ecological resources wisely, understand how pollutants affect our health, and prevent or reduce environmental risks in the future. The National Risk Management Research Laboratory (NRMRL) is the Agency's center for investigation of technological and management approaches for preventing and reducing risks from pollution that threaten human health and the environment. The focus of the Laboratory's research program is on methods and their cost-effectiveness for prevention and control of pollution to air, land, water, and subsurface resources; protection of water quality in public water systems; remediation of contaminated sites, sediments and ground water; prevention and control of indoor air pollution; and restoration of ecosystems. NRMRL collaborates with both public and private sector partners to foster technologies that reduce the cost of compliance and to anticipate emerging problems. NRMRL's research provides solutions to environmental problems by: developing and promoting technologies that protect and improve the environment; advancing scientific and engineering information to support regulatory and policy decisions; and providing the technical support and information transfer to ensure implementation of environmental regulations and strategies at the national, state, and community levels. This publication has been produced as part of the Laboratory's strategic long-term research plan. It is published and made available by EPA's Office of Research and Development to assist the user community and to link researchers with their clients. 11 ------- Contents Verification Statement VS-i Notice i Foreword ii Contents iii Figures iv Tables iv Abbreviations and Acronyms vi Chapter 1 Introduction 1 1.1 ETV Purpose and Program Operation 1 1.2 Testing Participants and Responsibilities 1 1.2.1 U.S. Environmental Protection Agency 2 1.2.2 Verification Organization 2 1.2.3 Testing Organization 3 1.2.4 Analytical Laboratories 4 1.2.5 Vendor 4 1.3 System Owner/Operator 4 Chapter 2 Technology Description 6 2.1 Treatment System Description 6 2.2 Maintenance 7 2.3 Technology Application and Limitations 8 2.4 Performance Claim 8 Chapters Test Site Description 9 3.1 Location and Land Use 9 3.2 Contaminant Sources and Site Maintenance 11 3.3 Stormwater Conveyance System 11 3.4 Water Quality /Water Resources 11 3.5 Local Meteorological Conditions 12 Chapter 4 Sampling Procedures and Analytical Methods 13 4.1 Sampling Locations 13 4.1.1 Site 1 -Inlet 13 4.1.2 Site 2 - Treated Outlet 13 4.1.3 Other Monitoring Locations 14 4.2 Monitoring Equipment 15 4.3 Contaminant Constituents Analyzed 15 4.4 Sampling Schedule 16 4.5 Field Procedures for Sample Handling and Preservation 18 Chapter 5 Monitoring Results and Discussion 20 5.1 Monitoring Results: Performance Parameters 20 5.1.1 Concentration Efficiency Ratio 20 5.1.2 Sum of Loads 26 5.2 Particle Size Distribution 31 Chapter 6 QA/QC Results and Summary 34 6.1 Laboratory/Analytical Data QA/QC 34 6.1.1 Bias (Field Blanks) 34 6.1.2 Replicates (Precision) 35 in ------- 6.1.3 Accuracy 37 6.1.4 Representativeness 38 6.1.5 Completeness 39 6.2 Flow Measurement Calibration 39 6.2.1 Stage Measurement Corrections 39 6.2.2 Flow Calibration -InletFlume Measurements 40 6.2.3 Developing the Rating Curve 41 6.2.4 Outlet Volume Comparison 42 6.2.5 Comparison of Runoff Volumes: Rainfall Depth vs. Inlet Measurements ... 42 6.2.6 Point Velocity Correction 44 Chapter 7 Operations and Maintenance Activities 45 7.1 System Operation and Maintenance 45 7.2 Description of Post Monitoring Cleanout and Results 46 7.2.1 Background 46 Chapter 8 References 49 Glossary 50 Appendices 52 A Vortechs Design and O&M Guidelines 52 B Test Plan 52 C Event Hydrographs and Rain Distribution 52 C Analytical Data Reports with QC 52 Figures Figure 2-1. Schematic drawing of atypical Vortechs 7 Figure 3-1. Test site location 9 Figure 3-2. Drainage area detail 10 Figure 3-3. Vortechs drainage area condition 10 Figure 3-4. Reconfigured inlet to Vortechs 12 Figure 4-1. View of monitoring station 13 Figure 4-2. View of ISCO samplers 14 Figure 4-3. View of datalogger 14 Figure 4-4. View of rain gauge 15 Figure 6-1. Calculated rating curve for Vortechs inlet site 42 Tables Table 4-1. Constituent List for Water Quality Monitoring 16 Table 4-2. Summary of Events Monitored for Verification Testing 17 Table 4-3. Rainfall Summary for Monitored Events 18 Table 5-1. Monitoring Results and Efficiency Ratios for Sediment Parameters 21 Table 5-2. Monitoring Results and Efficiency Ratios for Phosphorus Parameters 23 Table 5-3. Monitoring Results and Efficiency Ratios for Metals 24 Table 5-4. Monitoring Results and Efficiency Ratios for Water Quality Parameters 25 Table 5-5. Sediment Sum of Loads Results 27 IV ------- Table 5-6. Nutrient Sum of Loads Results 28 Table 5-7. Metals Sum of Loads Results 30 Table 5-8. Water Quality Parameters Sum of Loads Results 31 Table 5-9. Particle Size Distribution Analysis Results 32 Table 5-10. Particle Size Distribution SOL Results 33 Table 6-1. Field Blank Analytical Data Summary 34 Table 6-2. Field Duplicate Sample Relative Percent Difference Data Summary 36 Table 6-3. Laboratory Duplicate Sample Relative Percent Difference Data Summary 37 Table 6-4. Laboratory MS/MSD Data Summary 38 Table 6-5. Laboratory Control Sample Data Summary 38 Table 6-6. Stage Height Corrections 40 Table 6-7. Comparison of Runoff Volumes 43 Table 7-1. Operation and Maintenance During Verification Testing 45 ------- Abbreviations and Acronyms ASTM BMP cfs COD EMC EPA ETV ft2 ft3 g gal gpm hr in. kg L Ib LOD LOQ m3 mm NRMRL mg/L min MS/MSD NSF NIST O&M QA QAPP QC RPD ssc SOL SOP Std. Dev. IDS TO TP TSS USGS VA vo American Society for Testing and Materials Best Management Practice Cubic feet per second Chemical oxygen demand Event mean concentration U.S. Environmental Protection Agency Environmental Technology Verification Square feet Cubic feet Gram Gallon Gallon per minute Hour Inch Kilogram Liters Pound Limit of detection Limit of quantification Cubic meter Millimeter National Risk Management Research Laboratory Microgram per liter (ppb) Micron (micrometer) Milligram per liter Minute Matrix spike/matrix spike duplicate NSF International, formerly known as National Sanitation Foundation National Institute of Standards and Technology Operations and maintenance Quality assurance Quality Assurance Project Plan Quality control Relative percent difference Suspended sediment concentration Sum of loads Standard operating procedure Standard deviation Total dissolved solids Testing Organization Total phosphorus Total suspended solids United States Geological Survey Visual accumulator Verification Organization (NSF) VI ------- WDNR Wisconsin Department of Natural Resources WQPC Water Quality Protection Center WisDOT Wisconsin Department of Transportation WSLH Wisconsin State Laboratory of Hygiene yd3 Cubic yard vn ------- Chapter 1 Introduction 1.1 ETV Purpose and Program Operation The U.S. Environmental Protection Agency (EPA) has created the Environmental Technology Verification (ETV) Program to facilitate the deployment of innovative or improved environmental technologies through performance verification and dissemination of information. The goal of the ETV program is to further environmental protection by substantially accelerating the acceptance and use of improved and more cost-effective technologies. ETV seeks to achieve this goal by providing high quality, peer reviewed data on technology performance to those involved in the design, distribution, permitting, purchase, and use of environmental technologies. ETV works in partnership with recognized standards and testing organizations; stakeholders groups, which consist of buyers, vendor organizations, and permitters; and with the full participation of individual technology developers. The program evaluates the performance of innovative technologies by developing test plans that are responsive to the needs of stakeholders, conducting field or laboratory (as appropriate) testing, collecting and analyzing data, and preparing peer reviewed reports. All evaluations are conducted in accordance with rigorous quality assurance protocols to ensure that data of known and adequate quality are generated and that the results are defensible. NSF International (NSF), in cooperation with the EPA, operates the Water Quality Protection Center (WQPC). The WQPC evaluated the performance of the Vortechs® System, Model 1000 (Vortechs), a stormwater treatment device designed to remove suspended solids, and other stormwater pollutants from wet weather runoff. It is important to note that verification of the equipment does not mean that the equipment is "certified" by NSF or "accepted" by EPA. Rather, it recognizes that the performance of the equipment has been determined and verified by these organizations for those conditions tested by the Testing Organization (TO). 1.2 Testing Participants and Responsibilities The ETV testing of the Vortechs was a cooperative effort among the following participants: • U.S. Environmental Protection Agency • NSF International • U.S. Geologic Survey (USGS) • Wisconsin Department of Transportation (WisDOT) • Wisconsin Department of Natural Resources (WDNR) • Wisconsin State Laboratory of Hygiene (WSLH) • USGS Sediment Laboratory • Earth Tech, Inc. • Vortechnics, Inc. (Vortechnics) ------- The following is a brief description of each ETV participant and their roles and responsibilities. 7.2.7 U.S. Environmental Protection Agency The EPA Office of Research and Development, through the Urban Watershed Branch, Water Supply and Water Resources Division, National Risk Management Research Laboratory (NRMRL), provides administrative, technical, and quality assurance guidance and oversight on all ETV Water Quality Protection Center activities. In addition, EPA provides financial support for operation of the Center and partial support for the cost of testing for this verification. The key EPA contact for this program is: Mr. Ray Frederick, ETV WQPC Project Officer (732)321-6627 email: Frederick.Ray@epamail.epa.gov U.S. EPA, NRMRL Urban Watershed Management Research Laboratory 2890 Woodbridge Avenue (MS-104) Edison, New Jersey 08837-3679 7.2.2 Verification Organization NSF is the verification organization (VO) administering the WQPC in partnership with EPA. NSF is a not-for-profit testing and certification organization dedicated to public health, safety, and protection of the environment. Founded in 1946 and located in Ann Arbor, Michigan, NSF has been instrumental in development of consensus standards for the protection of public health and the environment. NSF also provides testing and certification services to ensure that products bearing the NSF name, logo and/or mark meet those standards. NSF personnel provided technical oversight of the verification process. NSF also provided review of the test plan and this verification report. NSF's responsibilities as the VO include: • Review and comment on the test plan; • Review quality systems of all parties involved with the TO, and qualify the TO; • Oversee TO activities related to the technology evaluation and associated laboratory testing; • Conduct an on-site audit of test procedures; • Provide quality assurance/quality control (QA/QC) review and support for the TO; • Oversee the development of the verification report and verification statement; and • Coordinate with EPA to approve the verification report and verification statement. ------- Key contacts at NSF are: Mr. Thomas Stevens, P.E. Mr. Patrick Davison, Program Manager Project Coordinator (734) 769-5347 (734) 913-5719 email: stevenst@nsf.org email: davison@nsf.org NSF International 789 North Dixboro Road Ann Arbor, Michigan 48105 1.2.3 Testing Organization The TO for the verification testing was Earth Tech, Inc. of Madison, Wisconsin (Earth Tech), with assistance from USGS in Middleton, Wisconsin. USGS provided testing equipment, helped to define field procedures, conducted the field testing, coordinated with the analytical laboratories, and conducted initial data analyses. The TO provided all needed logistical support, established a communications network, and scheduled and coordinated activities of all participants. The TO was responsible for ensuring that the testing location and conditions allowed for the verification testing to meet its stated objectives. The TO prepared the test plan; oversaw the testing; and managed, evaluated, interpreted and reported on the data generated during the testing, as well as evaluated and reported on the performance of the technology. TO employees set test conditions, and measured and recorded data during the testing. The TO's Project Manager provided project oversight. The key personnel and contacts for the TO are: Earth Tech: Mr. Jim Bachhuber, P.H. (608)828-8121 email: jim_bachhuber@earthtech. com Earth Tech, Inc. 1210 Fourier Drive Madison, Wisconsin 53717 USGS: Ms. Judy Horwatich (608) 821-3874 email: jawierl@usgs.gov ------- USGS 8505 Research Way Middleton, Wisconsin 53562 1.2.4 Analytical Laboratories The WSLH, located in Madison, Wisconsin, analyzed the stormwater samples for the parameters identified in the test plan. The USGS Sediment Laboratory, located in Iowa City, Iowa, performed the suspended sediment concentration separations and particle size analyses for the first qualified event. The key analytical laboratory contacts are: Mr. George Bowman Ms. Pam Smith (608) 224-6279 (319) 358-3602 email: gtb@mail.slh.wisc.edu email: pksmith@usgs.gov WSLH USGS Sediment Laboratory 2601 Agriculture Drive Federal Building Room 269 Madison, Wisconsin 53718 400 South Clinton Street Iowa City, Iowa 52240 7.2.5 Vendor The Vortechs is designed by Vortechnics, headquartered in Scarborough, Maine and manufactured by a local pre-cast company (Wiesser Concrete in Maiden Rock, Wisconsin). Vortechnics is owned by Contech Construction Products Inc., headquartered in Middletown, Ohio. Vortechnics was responsible for providing technical support, and was available during the tests to provide technical assistance as needed. The key contact for Vortechnics is: Mr. Vaikko P. Allen II, Technical Manager (207) 885-9830, ext. 275 email: vallen@vortechnics.com Vortechnics, Inc. 200 Enterprise Drive Scarborough, Maine 04074 1.3 System Owner/Operator The Vortechs was installed in a parking lot under Interstate 794 on the east side of the Milwaukee River in downtown Milwaukee, Wisconsin. The Vortechs treated storm water collected from the decking of Interstate 794. The unit was installed in cooperation with WisDOT, the current owner/operator of the system. ------- The key contact for WisDOT is: Mr. Robert Pearson (608) 266-7980 email: robert.pearson@dot.state.wi.us Bureau of Environment Wisconsin Department of Transportation 4802 Sheboygan Avenue, Room 451 Madison, Wisconsin 53707 ------- Chapter 2 Technology Description The following technology description data was supplied by the vendor and does not represent verified information. 2.1 Treatment System Description The Vortechs is designed to remove settable and floatable pollutants from stormwater runoff. When the system is operating at its peak design capacity, the maximum operating rate is approximately 100 gpm/ft2 of surface area. The Vortechs has been tested in a laboratory at flows up to and including this maximum treatment rate and has been shown to produce positive sediment removal efficiencies throughout this range. Based on the size of the grit chamber for the Vortechs Model 1000, the maximum treatment flow rate is 1.6 cfs (720 gpm). Additional hydraulic capacity is provided over the top of the flow control wall so that the system does not cause upstream flooding at flow rates exceeding the maximum recommended operating rate of 100 gpm/ft2. The actual hydraulic capacity of on-line Vortechs Systems is typically at least as great as the 100-year peak flow rate or the drainage system conveyance capacity, whichever is less. A schematic of the Vortechs is shown in Figure 2-1 The Vortchs consists of an inlet pipe, grit chamber, baffle walls, and an outlet pipe, enclosed in a concrete vault. Untreated stormwater enters the Vortechs through an inlet pipe that is tangential to the grit chamber. This creates a swirling motion that directs settleable solids downward and towards the center of the grit chamber. Floating pollutants are trapped upstream of an underflow baffle. The Vortechs contains two flow controls in the last chamber of the system. The first control is designed to allow nearly free discharge at very low flows so that very fine particles do not settle in the inlet pipe. This control begins to create a significant backwater at operating rates in excess of 5 gpm/ft2 such that the inlet pipe becomes submerged at an operating rate of 20 gpm/ft2. This backwater creates a low-velocity entry into the grit chamber, which encourages stratification of pollutants in the inlet pipe. Under low flow rates, a small amount of material may settle out in the inlet pipe, but at higher flow rates, these particles will be transported into the grit chamber. At operating rates in excess of 20 gpm/ft2, a portion of the flow will pass through the high flow control. The flow controls were sized to create up to 3.5 ft of backwater at peak operating rates, depending on available head. This backwater effect increases the residence time in the system, thereby maximizing pollutant removal and retention. The backwater effect also increases the separation between captured floating pollutants and the bottom of the baffle wall. Both flow controls are Cipoletti shape with a flat crest and a side slope of 4:1. The Vortechs installed at the Riverwalk site in Milwaukee is designed to treat all flows up to 1.6 cfs. There is no bypass, so flows exceeding peak hydraulic capacity will pass through the system. At high flows, the inlet pipe's capacity becomes the limiting factor. ------- OH Baffle Will Into* High Flow Control Grit Chamber Low Row Control Figure 2-1. Schematic drawing of a typical Vortechs. Product Specification: • Housing - Six-inch thick concrete rectangular structure. • Dimensions - inside dimensions - length: 9 ft (2.7 m); width: 3 ft (1 m); height: 7 ft (2.1m). • Peak Treatment Capacity - 1.6 cfs (720 gpm). • Sediment Storage - 0.75 yd3 (0.57 m3). • Sediment Chamber Diameter - 3 ft (1 m). Additional equipment specifications, test site descriptions, testing requirements, sampling procedures, and analytical methods are detailed in the Final Test Plan for the Verification of Vortechs* Model 1000 Stormwater Treatment System "Riverwalk Site" Milwaukee, Wisconsin (March 22, 2004). The test plan is included in Appendix A. 2.2 Maintenance The Vortechs System should be inspected periodically and cleaned when inspection reveals the sediment depth has accumulated to within six inches of the dry-weather water level. Maintaining the Vortechs is easiest when there is no flow entering the system. Cleanout of the Vortechs with a vacuum truck is generally the most effective and convenient method of excavating pollutants from the system. ------- Accumulated sediment is typically evacuated through the manhole over the grit chamber. As water is evacuated, the water level outside of the grit chamber will drop to the same level as the crest of the lower aperture of the grit chamber. It will not drop below this level due to the fact that the bottom and sides of the grit chamber are sealed to the tank floor and walls. This "Water Lock" feature prevents water from migrating into the grit chamber, exposing the bottom of the baffle wall. Floating pollutants will decant into the grit chamber as the water level there is drawn down. This allows most floating material to be withdrawn from the same access point above the grit chamber. If maintenance is not performed as recommended, sediment may accumulate outside the grit chamber. If this is the case, it may be necessary to inspect or pump out all chambers. 2.3 Technology Application and Limitations The Vortechs is used for several project applications, including: • commercial developments such as office complexes and hotels; • industrial developments such as vehicle storage yards and material transfer stations; • retail developments such as gas stations and shopping centers; • high-density residential such as housing developments; and • urban roadways. 2.4 Performance Claim The vendor claims that the Vortechs will provide a net annual removal efficiency of total suspended solids (TSS) that are typically encountered in runoff from urban environments in excess of 80%. According to the vendor's product literature, Vortechnics typically selects a system size that will provide an 80% annual TSS load reduction based on laboratory-generated performance curves for 50-|im sediment particles. The vendor also claims that the Vortechs will capture and contain floatables in stormwater runoff, although this claim was not verified. ------- Chapter 3 Test Site Description 3.1 Location and Land Use The Vortechs is located in a municipal parking lot beneath an elevated freeway (1-794) and just east of the Milwaukee River, in downtown Milwaukee, Wisconsin. The parking lot is located just west of Water Street, between Clybourn Street and St. Paul Avenue. Figure 3-1 shows the location of the test site. Figure 3-1. Test site location. The Vortechs receives runoff from 0.25 acres of the westbound highway surface of 1-794, as shown in Figure 3-2. The interstate surface is elevated at this location so there is no other land use in the drainage area, as shown in Figure 3-3. Surface inlets on the highway, shown in Figure 3-3), collect the runoff and convey the water to the treatment device via downspouts from the deck surface to beneath the parking lot below the highway deck. The drainage area determination was based on the following information and assumptions: 1. WisDOT design plans for Interstate 794 dated 1966 (scale: 1 in. equals 20 ft) and rehabilitation plans dated 1994; 2. The assumption that resurfacing the deck did not change the basic slope or relative drainage area to each inlet; and 3. The assumption that adjacent storm drains were capable of capturing all the flow in their respective drainage areas, forming a hydrologic barrier. ------- J Drainage Area L Westbound Traffic -1-794 •i-w Figure 3-2. Drainage area detail. Storm inlet to Vortechs Figure 3-3. Vortechs drainage area condition. 10 ------- 3.2 Contaminant Sources and Site Maintenance The main pollutant sources within the drainage area are created by vehicular traffic, atmospheric deposition, and winter salt applications. The storm sewer catch basins do not have sumps. Conventional (mechanical) street sweeping is done on a monthly basis in the summer months (June through August). There are no other stormwater best management practices (BMPs) within the drainage area. 3.3 Stormwater Conveyance System The entire drainage area is served by a storm sewer collection system. Before installation of the Vortechs, the drainage area discharged storm water directly to the Milwaukee River through the system under the parking lot. The highway deck is elevated approximately 15 ft above the parking lot. Originally, the storm sewer conveyance system dropped vertically to a point below the parking lot surface, then traveled about 6.5 ft horizontally to the monitoring (flow and quality) sites, and another two feet to the Vortechs. After the initial installation of the Vortechs, the velocity meter location was frequently inundated with sediment during and after events. Vortechnics considered the 2 to 5 ft of nearly flat storm pipe leading to the grit chamber (this area is affected by backwater effect of the slot opening to the grit chamber) as part of the treatment system. As a result, sediment was settling out in this portion of the pipe. The TO and VO decided to reconfigure the storm pipe (see Figure 3-4) to avoid the interference of the sediment with the velocity meter. The reconfiguration took place prior to verification testing. 3.4 Water Quality/Water Resources Stormwater from the site is discharged directly to the Milwaukee River, just upstream of the mouth to Milwaukee Harbor, and then into Lake Michigan. The river and harbor have had a history of severe water quality impacts from various sources, including contaminated river sediments, urban non-point source runoff, rural non-point sources, combined sewer overflows, and point source discharges. The water quality in the river suffers from low dissolved oxygen, high nutrient, metals, bacteria levels, and toxic contamination. The Milwaukee River at this location is on Wisconsin's 303(d) list for dissolved oxygen, aquatic toxicity, polychlorinated biphenyls, and fish consumption advisory. Most of the urban communities within the Milwaukee River watershed, including the City of Milwaukee, are under the State of Wisconsin stormwater-permitting program (NR 216). This program meets or exceeds the requirements of EPA's Phase I stormwater regulations. 11 ------- r Enisling vertical pipe wilh cleanout will be removed and stored (or replacemenl after sampling is complete. New piping as shown would preveni backwater from Vortecrinics tank al the moniloring insert. Grade ol pipe al monitoring insert will be the same as exists for Ihe Stormwater Filler moniloring insert. < Existing Piping 8" Diameter Sch 80 Gray PVC New Piping a' Diameter Sc:;i R£ Gray PVC Existing Overpass Piaf 0 10 0 8-16 Parking lot slope .068 tt/ft Clear PVC monitoring Insert 8" Diameter SL-M eo Figure 3-4. Reconfigured inlet to Vortechs. 3.5 Local Meteorological Conditions The test plan includes summary temperature and precipitation data from the National Weather Service station from the Mitchell Field Airport in Milwaukee. The statistical rainfalls for a series of recurrence and duration precipitation events are presented in the test plan. The climate of Milwaukee, and Wisconsin in general, is typically continental with some modification by Lakes Michigan and Superior. Milwaukee experiences cold snowy winters, and warm to hot summers. Average annual precipitation is approximately 33 in., with an average annual snowfall of 50.3 in. 12 ------- Chapter 4 Sampling Procedures and Analytical Methods Descriptions of the sampling locations and methods used during verification testing are summarized in this section. Additional detail may be found in the test plan. 4.1 Sampling Locations Two locations in the test site storm sewer system were selected as sampling and monitoring sites to determine the treatment capability of the Vortechs. 4.1.1 Site 1-Inlet This sampling and monitoring site was selected to characterize the untreated stormwater from the drainage area. A velocity/stage meter and sampler suction tubing were located in the inlet pipe, upstream from the Vortechs, so that potential backwater effects of the treatment device would not affect the velocity measurements. The monitoring station and test equipment are shown in Figures 4-1,4-2, and 4-3. Figure 4-1. View of monitoring station. 4.1.2 Site 2 - Treated Outlet This sampling and monitoring site was selected to characterize the stormwater treated by the Vortechs. A velocity/stage meter and sampler suction tubing, connected to the automated sampling equipment, were located in an eight-inch diameter plastic pipe downstream from the Vortechs. 13 ------- Figure 4-2. View of ISCO samplers. Figure 4-3. View of data logger. 4.1.3 Other Monitoring Locations In addition to the two sampling and monitoring sites, a water-level recording device was installed inside the Vortechs vault. The purpose of the water level recording device was used to help verify inlet and outlet flows. A rain gauge was located adjacent to the drainage area to monitor the depth of precipitation from storm events. The data were used to characterize the events to determine if they met the requirements for a qualified storm event. The rain gauge is shown in Figure 4-4. 14 ------- Figure 4-4. View of rain gauge. 4.2 Monitoring Equipment The specific equipment used for monitoring flow, sampling water quality, and measuring rainfall for the upstream and downstream monitoring points are listed below: • Sampler: ISCO 3700 refrigerated automatic sampler; • Sample Containers: Four 10-L sample containers; • Flow Measurement: Marsh-McBirney Velocity Meter Model 270 • Stage Meter (inside Vortechs vault): Campbell Scientific Inc. SWD1; • Data Logger: Campbell Scientific, Inc. CR10X; and • Rain Gauge: Rain-O-Matic. 4.3 Contaminant Constituents Analyzed The list of constituents analyzed in the stormwater samples is shown in Table 4-1. The vendor's performance claim addresses reductions of sediments, from the runoff water. 15 ------- Table 4-1. Constituent List for Water Quality Monitoring Parameter Total dissolved solids (TDS) Total suspended solids (TSS) Total phosphorus Suspended sediment concentration (SSC) Total calcium Total copper Dissolved copper Total magnesium Dissolved zinc Total zinc Dissolved phosphorus Dissolved chloride Chemical oxygen demand (COD) Sand-silt split Five point sedigraph Sand fractionation Reporting Units mg/L mg/L mg/L as P mg/L mg/L Mg/L Mg/L mg/L Mg/L Mg/L mg/L as P mg/L mg/L NA NA NA Limit of Limit of Detection Quantification Method1 50 2 0.005 0.1 0.2 1 1 0.2 16 16 0.005 0.6 9 NA NA NA 167 7 0.016 0.5 0.7 3 3 0.7 50 50 0.016 2 28 NA NA NA SM 2540C EPA 160.2 EPA 365.1 ASTMD3977-97 EPA 200.7 SM3113B SM3113B EPA 200.7 EPA 200.7 EPA 200.7 EPA 365.1 EPA 325. 2 ASTMD1252-88(B) Fishman et al. Fishman et al. Fishman et al. 1 EPA: EPA Methods and Guidance for the Analysis of Water procedures; SM: Standard Methods for the Examination of Water and Wastewater (19th edition) procedures; ASTM: American Society of Testing and Materials procedures; Fishman et al.: Approved Inorganic and Organic Methods for the Analysis of Water and Fluvial Sediment procedures. 4.4 Sampling Schedule USGS personnel installed the monitoring equipment under a contract with the WDNR. The monitoring equipment was installed in December, 2001. During several trial events in 2002, it was discovered that the inlet velocity meter was frequently inundated with sediment from the backwater effect of the Vortechs. In January, 2003 the storm pipe was reconfigured to avoid this problem (see Figure 3-3). Verification testing began in April, 2003, and ended after the last qualified event was monitored in August, 2004. Testing was suspended during winter weather. Table 4-2 summarizes the sample collection data from the storm events. 16 ------- Table 4-2. Summary of Events Monitored for Verification Testing Inlet Sampling Point (Site 1) Outlet Sampling Point (Site 2) Event Start Number Date 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 4/30/03 5/4/03 5/9/03 5/30/03 6/8/03 6/27/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/25/04 3/28/04 4/17/04 5/12/04 5/20/04 8/3/04 8/24/04 Start Time 22:24 21:34 0:42 19:07 3:34 17:35 15:42 6:09 1:19 8:54 17:41 23:08 15:30 3:29 18:33 16:39 20:25 20:40 End Date 5/1/03 5/5/03 5/9/03 5/30/03 6/8/03 6/28/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/26/04 3/28/04 4/17/04 5/13/04 5/20/04 8/3/04 8/25/04 End No. of Start Time Aliquots Date 1:13 0:54 3:41 23:05 13:44 10:46 19:22 12:02 3:04 9:29 21:43 3:34 20:12 4:11 3:27 17:33 23:34 0:02 26 20 5 21 18 20 16 18 15 8 32 31 29 7 14 9 34 17 4/30/03 5/4/03 5/9/03 5/30/03 6/8/03 6/27/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/25/04 3/28/04 4/17/04 5/12/04 5/20/04 8/3/04 8/24/04 Start Time 22:32 21:47 1:53 19:09 3:35 17:37 15:47 11:47 1:23 8:58 17:41 23:33 15:31 3:31 18:36 16:39 20:25 20:42 End Date 5/1/03 5/5/03 5/9/03 5/30/03 6/8/03 6/28/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/26/04 3/28/04 4/17/04 5/13/04 5/20/04 8/3/04 8/24/04 End Time 0:17 7:10 4:35 22:33 5:00 10:15 17:24 11:59 3:11 9:31 21:42 3:33 18:58 4:12 3:10 17:38 23:53 23:54 No. of Aliquots 11 16 8 7 7 10 8 6 14 7 29 12 13 7 7 9 26 14 Storm events met the requirements of a "qualified event," as defined in the test plan: 1. The total rainfall depth for the event, measured at the site rain gauge, was 0.2 in. (5 mm) or greater (snow fall and snow melt events did not qualify). 2. Flow through the treatment device was successfully measured and recorded over the duration of the runoff period. 3. A flow-proportional composite sample was successfully collected for both the inlet and outlet over the duration of the runoff event. 4. Each composite sample collected was comprised of a minimum of five aliquots, including at least two aliquots on the rising limb of the runoff hydrograph, at least one aliquot near the peak, and at least two aliquots on the falling limb of the runoff hydrograph. 5. There was a minimum of six hours between qualified sampling events. Table 4-3 summarizes the storm data for the qualified events. Detailed information on each storm's runoff hydrograph and the rain depth distribution over the event period are included in Appendix B. 17 ------- Table 4-3. Rainfall Summary for Monitored Events Event Number 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Date 4/30/03 5/4/03 5/9/03 5/30/03 6/8/03 6/27/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/25/04 3/28/04 4/17/04 5/12/04 5/20/04 8/3/04 8/24/04 Rainfall Amount (inches) 1.1 0.72 0.87 0.54 0.62 0.57 0.30 0.47 0.27 0.23 0.71 0.85 0.87 0.24 0.55 0.24 1.8 0.85 Rainfall Duration (hnmin) 3:30 4:05 4:27 4:07 11:09 17:25 3:49 6:35 2:53 0:39 5:31 4:57 4:49 1:18 9:05 1:02 3:43 3:32 Runoff Volume (ft3)1 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 Peak Discharge Rate (cfs) 1 0.352 0.059 0.084 0.164 0.466 0.101 0.039 2.02 0.057 0.055 0.138 0.023 0.025 0.026 0.076 1.26 2.45 1.02 1. Runoff volume and peak discharge volume measured at the inlet monitoring point. The vendor sized the Vortechs for the Milwaukee Riverwalk site based on the peak flow rate of the 1.6 cfs), as noted in Section 2.1. The recorded peak discharge rate for events 8 and 17 exceeded both the peak flow treatment capacity of the Vortechs. Additionally, event 16 nearly exceeded the peak flow treatment capacity of the Vortechs. At these flow rates, the system was operating beyond the point at which significant sediment removal is expected. The sample collection starting times for the inlet and outlet samples, as well as the number of sample aliquots collected, varied from event to event. The inlet sampler was activated when the inlet velocity meter sensed flow in the pipe. The outlet sampler was activated when flow was detected in the outlet pipe. 4.5 Field Procedures for Sample Handling and Preservation Data gathered by the on-site data logger were accessible to USGS personnel by means of a modem and phone-line hookup. USGS personnel collected samples and performed a system inspection after storm events. 18 ------- Water samples were collected with ISCO automatic samplers programmed to collect one-liter aliquots during each sample cycle. A peristaltic pump in the sampler pumped water from the sampling location through Teflon™-lined sample tubing to the pump head where water passed through approximately three feet of silicone tubing and into one of four 10-L sample collection bottles. Samples were capped and removed from the sampler after the event by the WisDOT or USGS personnel depending upon the schedule of the staff. The samples were forwarded to USGS personnel if the WisDOT personnel collected them. The samples were then transported to the USGS field office in Madison, Wisconsin, where they were split into multiple aliquots using a 20-L Teflon™-lined churn splitter. When more than 20 L (two 10-L sample collection bottles) of sample were collected by the auto samplers, the contents of the two full sample containers would be poured into the churn, a portion of the sample in the churn would be discarded, and a proportional volume from the third or fourth sample container would be poured into the churn. The analytical laboratories provided sample bottles. Samples were preserved per method requirements and analyzed within the holding times allowed by the methods. Particle size and SSC samples were shipped to the USGS sediment laboratory in Iowa City, Iowa (after event 2, SSC samples were analyzed at WSLH). All other samples were hand-delivered to WSLH. The samples were maintained in the custody of the sample collectors, delivered directly to the laboratory, and relinquished to the laboratory sample custodian(s). Custody was maintained according to the laboratory's sample handling procedures. To establish the necessary documentation to trace sample possession from the time of collection, field forms and lab forms (see Appendix B of the test plan) were completed and accompanied each sample. 19 ------- Chapter 5 Monitoring Results and Discussion The verification testing results related to contaminant reduction are reported in two formats: 1. Efficiency ratio comparison, which evaluates the effectiveness of the system for each qualified storm event on an event mean concentration (EMC) basis. 2. Sum of loads (SOL) comparison, which evaluates the effectiveness of the system for all qualified storm events on a constituent mass (concentration times volume) basis. The test plan required that a suite of analytical parameters, including solids, metals, and nutrients be evaluated based on the vendor's performance claim. 5.1 Monitoring Results: Performance Parameters 5.1.1 Concentration Efficiency Ratio The concentration efficiency ratio reflects the treatment capability of the device using the event mean concentration (EMC) data obtained for each runoff event. The concentration efficiency ratios are calculated by: Efficiency ratio = 100 x (l-[EMCoutiet/EMCiniet]) (5-1) The inlet and outlet sample concentrations and calculated efficiency ratios are summarized by analytical parameter categories: sediments (TSS, SSC, and TDS); nutrients (total and dissolved phosphorus); metals (total and dissolved copper and zinc); and water quality parameters (COD, dissolved chloride, total calcium and total magnesium). The water quality parameters were not specified in the vendors' performance claim and were monitored for other reasons outside the scope of the ETV program. Sediments: The inlet and outlet sample concentrations and calculated efficiency ratios for sediment parameters are summarized in Table 5-1. The results show differences between inlet TSS and SSC concentrations. Comparing the inlet concentrations, SSC always exceed TSS, with the range of difference between the two parameters ranging from 6 to 90%. the TSS and SSC analytical parameters measure sediment concentrations in water; however, the TSS analytical procedure requires the analyst to draw an aliquot from the sample container, while the SSC procedure requires use of the entire contents of the sample container. If a sample contains a high concentration of settleable (generally heavy, large particle) solids, acquiring a representative aliquot from the sample container is very difficult. Therefore a disproportionate amount of the settled solids may be left in the container, and the reported TSS concentration would be considerably lower than SSC. For this data set, the TSS and SSC concentrations were relatively close. This implies that the inlet samples contained a higher proportion of finer, lighter sediment particles. 20 ------- Table 5-1. Monitoring Results and Efficiency Ratios for Sediment Parameters Event No. 1 2 3 4 5 6 7 81 9 10 11 12 13 14 15 16 171 18 Inlet (mg/L) 79 110 89 110 47 190 310 55 46 130 98 160 270 110 70 97 74 78 TSS Outlet (mg/L) 87 38 28 70 64 100 120 150 33 39 83 140 92 110 42 93 87 69 Reduction (%) -10 65 69 36 -36 47 61 -170 28 70 15 13 66 0 40 4.1 -18 12 Inlet (mg/L) 91 160 98 120 50 290 550 79 57 140 110 180 290 130 79 130 220 820 ssc Outlet (mg/L) 86 36 27 69 64 100 100 150 26 34 83 140 90 110 41 92 87 79 Reduction (%) 5.5 78 72 43 -28 66 82 -90 54 76 25 22 69 15 48 29 60 90 Inlet (mg/L) 54 100 80 88 <50 120 290 <50 82 110 56 180 160 120 80 82 <50 60 TDS Outlet (mg/L) 84 120 60 180 140 180 390 96 240 130 130 840 530 1,400 146 120 <50 150 Reduction (%) -56 -20 25 -100 ND -50 -34 ND -190 -18 -130 -370 -230 -1,100 -83 -46 ND -150 ND: Not Determined. 1. The Vortechs peak hydraulic capacity was exceeded during events 8 and 17. 21 ------- The TSS inlet concentrations ranged from 55 to 310 mg/L the outlet concentrations ranged from 28 to 150 mg/L, and the efficiency ratio ranged from -170 to 70%. The SSC inlet concentrations ranged 57 to 820 mg/L, the outlet concentrations ranged from 26 to 153 mg/L, and the efficiency ratio ranged from -90 to 90%. The highest inlet TDS concentrations were observed from events 7, 12 and 13. Events 12 and 13 occurred in March 2004, and it is possible that these results were influenced by road salting operations. This reasoning does not explain the high TDS concentrations found in event 7, which occurred in September of 2003. For all but one event, the TDS concentrations increased in the outlet samples. The vendor made no performance claim for TDS. Phosphorus: The inlet and outlet sample concentrations and calculated efficiency ratios are summarized in Table 5-2. The total phosphorus inlet concentration ranged from 0.062 mg/L to 0.68 mg/L, and the dissolved phosphorus inlet concentration ranged from 0.014 mg/L to 0.24 mg/L. Reductions in total phosphorus EMCs ranged from -82 to 52%, while reductions in dissolved phosphorus EMCs ranged from -200 to 68%. Metals: The inlet and outlet sample concentrations and calculated efficiency ratios are summarized in Table 5-3. Reductions in metal EMCs followed a similar pattern as the phosphorus results, in that the total fraction all showed higher concentrations and greater EMC reductions than the dissolved faction. The total copper inlet concentration ranged from 21 to 280 |ig/L, and the EMC reduction ranged from -83 to 70%. The total zinc inlet concentration ranged from 102 to 920 |ig/L, and the EMC reduction ranged from -80 to 58%. The dissolved copper inlet concentration ranged from less than 5 to 75 |ig/L, and the EMC reduction ranged from -250 to 52%. The dissolved zinc inlet concentration ranged from 17 to 348 |ig/L, and the EMC reduction ranged from -380 to 31%. Water quality parameters: The inlet and outlet sample concentrations and calculated efficiency ratios for water quality parameters are summarized in Table 5-4. Total magnesium inlet concentrations ranged from 3.7 to 23 mg/L, and the EMC reduction ranged from -96 to 78%. Total calcium inlet concentrations ranged from 9.5 to 48 mg/L, and the EMC reduction ranged from -120 to 65%. COD inlet concentrations ranged from 27 to 310 mg/L, and the EMC reduction ranged from -2,000 to 57%. The event with the -2,000% EMC reduction had an outlet concentration of 1,400 mg/L, which is an outlier. The other COD outlet concentrations ranged from 25 to 220 mg/L, making the 1,400 mg/L concentration an apparent outlier. 22 ------- Table 5-2. Monitoring Results and Efficiency Ratios for Phosphorus Parameters Event No. 1 2 3 4 5 6 7 81 9 10 11 12 13 14 15 16 171 18 Total Phosphorus Inlet Outlet Reduction (mg/L) (mg/L) (%) 0.062 0.23 0.086 0.17 0.098 0.35 0.68 0.11 0.13 0.18 0.14 0.13 0.18 0.16 0.13 0.15 0.098 0.23 0.079 0.12 0.041 0.12 0.13 0.27 0.48 0.2 0.15 0.12 0.17 0.14 0.089 0.17 0.12 0.14 0.11 0.14 -27 48 52 29 -33 23 29 -82 -15 33 -21 -7.7 51 -6.3 7.7 6.7 -12 39 Dissolved Phosphorus Inlet Outlet Reduction (mg/L) (mg/L) (%) 0.014 0.11 0.016 0.029 0.038 0.098 0.24 0.032 0.072 0.053 0.042 0.021 0.017 0.056 0.058 0.037 0.024 0.042 0.019 0.056 0.007 0.023 0.028 0.033 0.15 0.024 0.03 0.048 0.11 0.017 0.009 0.019 0.028 0.012 0.071 0.03 -36 49 56 21 26 66 38 25 58 9.4 -160 19 47 66 52 68 -200 29 1. The Vortechs peak hydraulic capacity was exceeded during events 8 and 17. 23 ------- Table 5-3. Monitoring Results and Efficiency Ratios for Metals Total Copper Event No. 1 2 3 4 5 6 7 81 9 10 11 12 13 14 15 16 171 18 Inlet (ng/L) 25 64 29 56 26 100 280 35 27 77 51 64 99 21 41 55 36 200 Outlet (ng/L) 34 24 13 52 33 75 120 64 33 31 51 73 43 36 39 46 28 60 Reduction -36 63 55 7.1 -27 25 57 -83 -22 60 0 -14 57 -71 4.9 16 22 70 Dissolved Copper Inlet (ng/L) 5.4 14 8.1 16 9.9 33 73 9.3 26 75 12 12 14 25 13 16 7.5 13 Outlet (ng/L) 8.8 11 5.4 19 13 32 35 10 33 32 42 16 12 43 J 19 14 7.8 10 Reduction -63 21 33 -19 -31 3.0 52 -7.5 -27 57 -250 -33 14 -72 -46 13 -4.0 23 Inlet (ng/L) 120 270 160 220 100 370 920 150 120 240 180 240 410 240 190 250 130 270 Total Zinc Outlet (ng/L) 160 130 84 170 130 250 520 270 130 100 190 280 190 310 150 170 130 170 Reduction -33 52 48 23 -30 32 43 -80 -8.3 58 -5.6 -17 54 -29 21 32 0 37 Dissolved Zinc Inlet (ng/L) 46 100 64 78 43 120 350 42 17 48 47 35 85 110 53 60 33 50 Outlet (ng/L) 68 78 48 96 62 110 330 70 81 33 170 61 59 160 70 67 38 52 Reduction -48 22 25 -23 -44 8.3 5.7 -67 -380 31 -260 -74 31 -45 -32 -12 -15 -4.0 J. Estimated concentration; USGS notes indicate possible filter contamination. 1. The Vortechs peak hydraulic capacity was exceeded during events 8 and 17. 24 ------- Table 5-4. Monitoring Results and Efficiency Ratios for Water Quality Parameters Event No. 1 2 3 4 5 6 7 81 9 10 11 12 13 14 15 16 171 18 Total Magnesium Inlet Outlet Reduction (mg/L) (mg/L) (%) 8.5 9.1 7.2 7.5 3.8 20 19 4.7 3.7 7.7 7.0 11 21 7.4 5.1 6.8 9.5 23 6.5 3 2.3 5.2 5.3 7.7 8.4 9.2 3.2 2.8 5.5 10 6.8 8 3.1 5.8 5.2 5 24 67 68 31 -39 62 56 -96 14 64 21 9.1 68 -8.1 39 15 45 78 Total Calcium Inlet Outlet Reduction (mg/L) (mg/L) (%) 20 25 20 18 9.5 48 45 10 15 20 17 29 47 20 13 16 19 48 18 14 9.3 23 21 31 33 20 19 15 17 32 24 43 12 16 12 17 10 44 54 -28 -120 35 27 -100 -27 25 0 -10 49 -120 7.7 0 37 65 Inlet (mg/L) 27 69 58 66 36 130 310 31 52 90 53 76 100 72 60 57 33 78 COD Outlet (mg/L) 39 69 25 1,4002 60 120 220 85 86 55 81 82 55 140 59 56 51 84 J Reduction (%) -44 0 57 -2,000 -67 8 29 -170 -65 39 -53 -7.9 45 -94 1.7 1.8 -55 -7.7 J: Estimated concentration, sample exceeded holding time. 1. The Vortechs peak hydraulic capacity was exceeded during events 8 and 17. 2. COD outlet concentration for event 4 is an apparent outlier and is not used in SOL calculations (Table 5-8). 25 ------- 5.1.2 Sum of Loads The sum of loads (SOL) is the sum of the percent load reduction efficiencies for all the events, and provides a measure of the overall performance efficiency for the events sampled during the monitoring period. The load reduction efficiency is calculated using the following equation: % Load Reduction Efficiency = 100x(l-(A/B)) (5-2) where: A = Sum of Outlet Load = (Outlet EMCi)(Flow Volumei) + (Outlet EMC2)(Flow Volume2) + (Outlet EMCn)(Flow Volumen) B = Sum of Inlet Load = (Inlet EMCi)(Flow Volumei) + (Outlet EMC2)(Flow Volume2) + (Outlet EMCn)( Flow Volumen) n= number of qualified sampling events Flow was monitored in the inlet and outlet, as discussed in Chapter 3. However, the TO experienced operational issues with the outlet flow monitor and data, as discussed in Chapter 6. Therefore, for the purposes of SOL calculations, the inlet flow data was used to calculate both the inlet and outlet SOL values. The SOL values are calculated using two approaches: 1. using the flow volumes and concentrations from all qualified events; and 2. using the flow volumes and concentrations from all qualified events except events 8 and 17, where the measured peak runoff intensity exceeded the rated hydraulic capacity of the Vortechs. Sediment: Table 5-5 summarizes results for the SOL calculations. When every qualified event is used in the calculations, the SOL analyses indicate a TSS reduction of 18%, an SSC reduction of 58%, and a TDS reduction of-130%. When events 8 and 17 are omitted from the calculations, the SOL analyses indicate a TSS reduction of 35%, an SSC reduction of 61%, and a TDS reduction of-130%. During event 8, there was a negative removal efficiency for both TSS and SSC, however, during event 17 there was a positive removal efficiency for SSC. The difference in TSS versus SSC is likely due to the particle size distribution in the runoff, as discussed in 5.1.1. The improvement in the TSS and SSC SOL reduction when events 8 and 17 are omitted suggest that the Vortechs is ineffective or may resuspend sediment when it encounters flows exceeding its rated hydraulic capacity. Since TSS showed a higher change than SSC in SOL reduction, it appears that higher flows allow a greater proportion of fine sediment to pass from the system. The TDS SOL reduction was -120%, however the vendor made no claims for TDS removal. Nutrients: The SOL data for nutrients are summarized in Table 5-6. When every qualified event is used in the calculations, the SOL analyses indicate a total phosphorus reduction of 9.3% and no reduction of dissolved phosphorus. When events 8 and 17 are omitted from the calculations, the SOL analyses indicate a total phosphorus reduction of 21% and a dissolved phosphorus reduction of 26%. 26 ------- Table 5-5. Sediment Sum of Loads Results TSS SSC TDS Event Runoff Volume No. (ft3) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Sum of the all events Reduction 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 loads - efficiency (%) Sum of the loads - events except 8 & 17 Reduction efficiency (%) Inlet Outlet (Ib) (Ib) 4.2 5.5 4.0 4.6 2.5 6.1 3.0 2.0 0.77 1.1 3.7 3.1 3.6 0.47 1.4 1.6 12 2.2 62 18 48 35 4.6 1.9 1.3 2.9 3.4 3.2 1.2 5.5 0.55 0.34 3.2 2.7 1.2 0.47 0.81 1.5 14 1.9 51 31 Inlet Outlet (Ib) (Ib) 4.8 7.9 4.4 5.0 2.6 9.4 5.4 2.9 0.95 1.2 4.2 3.5 3.9 0.56 1.5 2.1 34 23 120 58 80 61 4.5 1.8 1.2 2.9 3.4 3.2 0.97 5.5 0.43 0.29 3.2 2.7 1.2 0.47 0.8 1.5 14 2.2 50 31 Inlet Outlet (Ib) (Ib) 2.9 5.0 3.6 3.6 ND 3.9 2.8 0.92 1.4 0.95 2.1 3.5 2.2 0.52 1.6 1.3 ND 1.7 38 -120 37 -110 4.4 5.9 2.7 7.5 ND 5.8 3.8 3.5 4.0 1.1 5.0 16 7.1 6 2.8 1.9 ND 4.2 82 78 ND: Not determined. 27 ------- Table 5-6. Nutrient Sum of Loads Results Event No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Sum of the all events Reduction Runoff Volume (ft3) 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 loads - efficiency (%) Sum of the loads - events except 8 & 17 Reduction efficiency (%) Total Inlet (g) 1.5 5.2 1.7 3.2 2.4 5.1 3.0 1.8 0.99 0.7 2.4 1.1 1.1 0.31 1.1 1.1 7.0 2.9 43 34 phosphorus Outlet (g) 1.9 2.7 0.83 2.3 3.1 4.0 2.1 3.3 1.1 0.47 3 1.2 0.54 0.33 1.1 1.0 7.8 1.8 39 9.3 27 21 Dissolved Inlet (g) 0.34 2.5 0.32 0.55 0.91 1.4 1.1 0.53 0.55 0.21 0.73 0.18 0.1 0.11 0.51 0.27 1.7 0.53 13 10 phosphorus Outlet (g) 0.46 1.3 0.14 0.43 0.67 0.48 0.66 0.4 0.23 0.19 1.9 0.15 0.055 0.037 0.25 0.088 5.0 0.38 13 0 7.4 26 28 ------- Metals: The SOL data for metals are summarized in Table 5-7. When every qualified event is used in the calculations, the SOL analyses indicate a total copper reduction of 25%, a dissolved copper reduction of-10%, a total zinc reduction of 16%, and a dissolved zinc reduction of -24%. When events 8 and 17 are omitted from the calculations, the SOL analyses indicate a total copper reduction of 33%, a dissolved copper reduction of -12%, a total zinc reduction of 24%, and a dissolved zinc reduction of-21%. Water quality parameters: The SOL data for water quality parameters are summarized in Table 5-8. When every qualified event is used in the calculations, the SOL analyses indicate a total magnesium reduction of 42%, a total calcium reduction of 21%, and a COD reduction of-100%. When events 8 and 17 are omitted from the calculations, the SOL analyses indicate a total magnesium reduction of 47%, and a total calcium reduction of 22%, and a COD reduction of -190%. When event 4 (with an apparently outlying outlet COD concentration) is taken out of the data set, the COD reduction is -15% for all events, and 0% when events 8 and 17 are omitted from the calculations. Discussion: The calculated SOL reduction for TSS, SSC, total and dissolved phosphorus, COD, and total metals improved when omitting the two events where the peak runoff intensity exceeded the rated flow capacity of the Vortechs, while dissolved-phase constituents other than dissolved phosphorous showed relatively little change. The data suggest that scouring or resuspension may have occurred as a result of the high peak flow rates encountered during events 8 and 17. 29 ------- Table 5-7. Metals Sum of Loads Results Event No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Runoff Volume (ft3) 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 Sum of loads - all events Reduction efficiency (%) Sum of loads - events except 8 & 17 Reduction efficiency (%) Total Inlet (g) 0.6 1.4 0.59 1.1 0.62 1.5 1.2 0.58 0.20 0.30 0.89 0.56 0.61 0.041 0.36 0.40 2.6 2.5 16 13 copper Outlet (g) 0.82 0.54 0.26 0.98 0.79 1.1 0.53 1.1 0.25 0.12 0.89 0.64 0.26 0.07 0.34 0.34 2.0 0.76 12 25 8.7 33 Dissolved Inlet (g) 0.13 0.32 0.16 0.30 0.24 0.48 0.32 0.15 0.20 0.29 0.21 0.11 0.086 0.049 0.11 0.12 0.53 0.17 4.0 -10 3.3 -12 copper Outlet (g) 0.21 0.25 0.11 0.36 0.31 0.47 0.15 0.17 0.25 0.13 0.73 0.14 0.073 0.084 0.17 0.10 0.55 0.13 4.4 3.7 Total zinc Inlet (g) 2.9 6.1 3.2 4.1 2.4 5.4 4.1 2.5 0.91 0.94 3.1 2.1 2.5 0.47 1.7 1.8 9.2 3.4 57 16 45 24 Outlet (g) 3.8 2.9 1.7 3.2 3.1 3.7 2.3 4.5 0.99 0.39 3.3 2.5 1.2 0.61 1.3 1.2 9.2 2.2 48 34 Dissolved zinc Inlet (g) 1.1 2.3 1.3 1.5 1.0 1.8 1.5 0.7 0.13 0.19 0.82 0.31 0.52 0.21 0.47 0.44 2.3 0.64 17 14 Outlet (g) 1.6 1.8 0.97 1.8 1.5 1.6 1.5 1.2 0.61 0.13 3.0 0.54 0.36 0.31 0.62 0.49 2.7 0.66 21 -24 17 -21 30 ------- Table 5-8. Water Quality Parameters Sum of Loads Results Total magnesium Total calcium Event Runoff Volume No. (ft3) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Sum of loads - all events 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 Inlet (Ib) 0.45 0.45 0.32 0.31 0.2 0.65 0.18 0.17 0.062 0.066 0.27 0.21 0.28 0.032 0.099 0.11 1.5 0.64 6.0 Reduction efficiency (%) Sum of loads - events except 8 & 17 Reduction efficiency (%) 4.3 Outlet (Ib) 0.34 0.15 0.1 0.22 0.28 0.25 0.082 0.34 0.053 0.024 0.21 0.19 0.092 0.034 0.06 0.094 0.81 0.14 3.5 42 2.3 47 Inlet (Ib) 1.1 1.2 0.89 0.75 0.5 1.6 0.44 0.37 0.25 0.17 0.65 0.56 0.63 0.086 0.25 0.26 3.0 1.3 14 11 Outlet (Ib) 0.95 0.69 0.42 0.95 1.1 1.0 0.32 0.73 0.32 0.13 0.65 0.62 0.32 0.19 0.23 0.26 1.9 0.48 11 21 8.6 22 COD Inlet (Ib) 1.4 3.4 2.6 NC 1.9 4.2 3 1.1 0.87 0.77 2 1.5 1.3 0.31 1.2 0.92 5.2 2.2 34 28 Outlet (Ib) 2.1 3.4 1.1 NC 3.2 3.9 2.1 3.1 1.4 0.47 3.1 1.6 0.74 0.6 1.1 0.9 8 2.4 39 -15 28 0 NC: Not calculated; outlet COD sample for event 4 was an apparent outlier (see Table 5-4). 5.2 Particle Size Distribution Particle size distribution analysis was completed on selected events. The ability of the lab to conduct the specific analysis depended on the available sample volume, the sediment concentration, and the particle sizes in the sample. The ISCO samplers did not always collect an adequate volume of sample to conduct the full suite of particle size analyses. Two types of analyses were conducted. ------- 1. A "sand/silt split" analysis determined the percentage of sediment (by weight) larger than 62.5 |im (defined as sand) and less than 62.5 jim (defined as silt). This analysis was performed on the inlet and outlet samples of events 2, 5, 7, 8, 9, 10, 11, and 16. 2. A Visual Accumulator (VA) tube analysis (Fishman et al., 1994) defined the percentage of sediment (by weight) sized less than 1000, 500, 250, 125, and 62 |im. The analyses were conducted on the inlet samples of events 2, 7, 11, and 16. The particle size distribution results are summarized in Table 5-9. In each event where particle size analysis was conducted, the outlet samples had a higher percentage of particles in the silt category (<62.5 um) than the equivalent inlet sample. This is a result of the gravitational separation treatment mechanism of the Vortechs removing a higher percentage of the larger, heavier sediment particles. The SOL can be recalculated for SSC concentrations and "sand/silt split" data to determine the proportion of sand and silt removed during treatment. This evaluation, summarized in Table 5-10, shows that the Vortechs was highly effective in removing sand particles, and that the mass of silt particles in the inlet was nearly five times higher than the mass of sand. Particle size distribution is affected by such things as site conditions and use, maintenance (e.g. street sweeping), and weather. The data also show that the highest mass of silt in the outlet occurred during event 8, when the Vortechs encountered peak flow intensities at a rate higher than its rated flow capacity. Additionally, the Vortechs is generally more effective in removing silt particles during events with lower treatment volumes. Table 5-9. Particle Size Distribution Analysis Results Percent Less Than Particle Size (um) Event No. 2 5 7 8 9 10 11 16 Location <1000 <500 <250 <125 Inlet 100 96 83 79 Outlet Inlet Outlet Inlet 100 100 93 85 Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet 100 99 98 Outlet Inlet 98 92 86 Outlet <62.5 <31 <16 <8 <4 <2 76 95 42 98 81 74 67 55 43 28 98 74 98 64 94 83 98 98 97 100 83 97 32 ------- Table 5-10. Particle Size Distribution SOL Results SSC Cone. Sands (>62.5 urn) Fines (<62.5 urn) Event No. 2 5 7 8 9 10 11 16 Volume (ft3) 795 847 156 588 268 138 613 259 Inlet (mg/L) 160 50 550 79 57 140 110 130 Outlet (mg/L) 36 64 100 150 26 34 83 92 Inlet (%) 24 58 2 26 36 17 2 17 Outlet (%) 5 2 19 2 6 2 0 3 Inlet (%) 76 42 81 74 64 83 98 83 Outlet (%) 95 98 98 98 94 98 100 97 Sum of loads (all events) Removal efficiency (percent) Sum of loads (all events except Removal efficiency (percent) event 8) Sand SOL Inlet Ob) 1.9 1.5 1.0 0.75 0.34 0.20 0.08 0.36 6.2 5.4 Outlet (Ib) 0.09 0.07 0.02 0.11 0.03 0.01 0.00 0.04 0.36 94 0.25 95 Silt SOL Inlet (Ib) 6.0 1.1 4.3 2.1 0.61 1.0 4.1 1.7 21 19 Outlet (Ib) 1.7 3.3 0.95 5.4 0.41 0.29 3.2 1.4 17 21 11 41 33 ------- Chapter 6 QA/QC Results and Summary The Quality Assurance Project Plan (QAPP) in the test plan identified critical measurements and established several QA/QC objectives. The verification test procedures and data collection followed the QAPP. QA/QC summary results are reported in this section, and the full laboratory QA/QC results and supporting documents are presented in Appendix C. 6.1 Laboratory/Analytical Data QA/QC 6,1.1 Bias (Field Blanks) Field blanks were collected at both the inlet and outlet samplers on two separate occasions to evaluate the potential for sample contamination through the entire sampling process, including automatic sampler, sample-collection bottles, splitters, and filtering devices. "Milli-Q" reagent water was pumped through the automatic sampler, and collected samples were processed and analyzed in the same manner as event samples. The first field blank was collected on June 30, 2003 (between event 6 and 7). The second field blank was collected on May 3, 2004 (between events 14 and 15). Results for the field blanks are shown in Table 6-1. All but four analyses were below the limits of detection (LOD). Of the four analyses above the LOD; only one was greater than the LOQ. This analysis was a COD analysis conducted on the second blank test at the outlet location. Field notes and lab notes do not note any unusual circumstances or reasons for a possible contamination of this sample. These results show a good level of contaminant control in the field procedures was achieved. Table 6-1. Field Blank Analytical Data Summary Parameter Units Blank 1 (06/30/03) Inlet Outlet Blank 2 (05/03/04) Inlet Outlet LOD LOQ TDS TSS ssc Calcium, total COD Copper, total Copper, dissolved Magnesium, total Phosphorus, total Phosphorus, dissolved Zinc, total Zinc, dissolved mg/L mg/L mg/L mg/L mg/L ug/L ug/L mg/L mg/L mg/L ug/L ug/L <50 <2 <2 <0.2 <9 <1 1.7 <0.2 <0.005 <0.005 <16 <16 <50 <2 <2 <0.2 <9 <1 1.7 <0.2 <0.005 <0.005 <16 <16 <50 <2 <2 <0.2 <9 2 1.6 <0.2 <0.005 <0.005 <16 <16 <50 <2 <2 <0.2 55 1 <1 <0.2 <0.005 <0.005 <16 <16 50 2 2 0.2 9 1 1 0.2 0.005 0.005 16 16 167 7 7 0.7 28 3 3 0.7 0.016 0.016 50 50 34 ------- 6.1.2 Replicates (Precision) Precision measurements were performed by the collection and analysis of duplicate samples. The relative percent difference (RPD) recorded from the sample analyses was calculated to evaluate precision. RPD is calculated using the following formula: \X\- X2\ %RPD = - x 100% where: xi = Concentration of compound in sample x_2 = Concentration of compound in duplicate x = Mean value of xi and X2 Field precision: Field duplicates were collected to monitor the overall precision of the sample collection procedures. Duplicate inlet and outlet samples were collected during three different storm events to evaluate precision in the sampling process and analysis. The duplicate samples were processed, delivered to the laboratory, and analyzed in the same manner as the regular samples. Summaries of the field duplicate data are presented in Table 6-2. Overall, the results show good field precision. Below is a discussion on the results from selected parameters. TSS and SSC: Results were within targeted limits. Outlet samples (lower concentrations and smaller particle sizes) showed higher precision. The poorer precision for the inlet samples could be due to the sample handling and splitting procedures, or sampling handling for analysis, or a combination of factors. Tests on the sample splitting capabilities of a churn splitter showed the bias and the precision of the splits is compromised with increasing sediment concentrations and particle size. The tests identified the upper particle size limits for the churn splitter is between 250 and 500 |im (Horowitz, et al, 2001). Dissolved constituents (sediment phosphorus, and metals): These parameters consistently had very low RPD (very high precision). This supports the idea that the sample splitting operation may be the source of higher RPD in the high particulate samples. Total metals: The total copper, total magnesium, and total zinc data had RPD values exceeding the targeted limits. Similar to the paniculate sediment results, the highest RPDs occurred in the inlet samples, which had higher particulate concentrations; however, total copper had high RPDs for the outlet samples as well. The total calcium data showed higher precision. Total phosphorus: This parameter was consistently below or near the acceptable RPD value of 30%. Again, the highest discrepancies occurred at the inlet analyses, with very good duplicate agreement at the outlet samples. 35 ------- Table 6-2. Field Duplicate Sample Relative Percent Difference Data Summary 6/27/03 9/12/03 8/24/04 Parameter TDS TSS ssc COD Calcium, total Copper, total Copper, dissolved Magnesium, total Phosphorus, total Phosphorus, dissolved Zinc, total Zinc, dissolved Unit mg/L mg/L mg/L mg/L mg/L ug/L ug/L mg/L mg/L mg/L ug/L Ug/L Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Inlet Outlet Rep la 120 180 190 100 260 110 130 110 38 30 110 76 32 33 15 7.4 0.34 0.27 0.1 0.03 360 240 110 110 Rep Ib 120 180 190 100 290 100 130 120 48 31 100 75 33 32 20 7.7 0.35 0.27 0.1 0.03 370 250 120 110 RPD 0 0 0 0 11 10 0 9 23 3 10 1 3 3 29 4 3 0 0 0 3 4 9 0 Rep la 280 390 310 94 500 98 360 3 240 48 32 200 160 75 35 20 8.3 0.73 0.49 0.24 0.15 960 520 340 320 Rep Ib 290 390 i 120 550 100 310 220 45 33 280 120 73 35 19 8.4 0.68 0.48 0.24 0.15 920 520 350 330 RPD 4 0 4 10 2 15 9 9 3 33 29 3 0 5 1 7 2 0 0 4 0 3 3 Rep la 54 2 130 2 60 70 73 970 75 53 84 3 66 17 84 110 35 13 9.9 32 4.9 0.20 0.14 0.04 0.03 350 150 51 49 Rep Ib 2 150 2 78 69 820 79 78 3 3 48 17 200 60 13 10 23 5 0.23 0.14 0.04 0.03 270 170 50 52 RPD 11 14 11 6 17 5 38 0 32 0 58 53 0 1 33 2 14 0 0 0 26 13 2 6 Limit 30 30 ND ND 25 25 25 25 30 30 25 25 1 Lab error; no result reported 2 Laboratory duplicate sample QA/QC objective exceeded for this batch of samples. 3 Holding time exceeded ND not determined 36 ------- Laboratory precision: The WSLH analyzed duplicate samples from aliquots drawn from the same sample container as part of their QA/QC program. Summaries of the laboratory duplicate data are presented in Table 6-3. Table 6-3. Laboratory Duplicate Sample Relative Percent Difference Data Summary Average Maximum Minimum Std. Dev. Parameter1 Count2 TDS TSS Calcium, total Copper, total Copper, dissolved Magnesium, total Phosphorus, total Phosphorus, dissolved Zinc, total Zinc, dissolved 16 19 15 16 16 15 21 15 13 15 4.3 2.2 1.7 1.7 2.0 1.3 1.3 0.14 2.6 2.0 18 8.6 4.1 5.5 6.5 4.7 7.9 1.6 8.1 6.9 0.00 0.00 0.13 0.09 0.07 0.01 0.00 0.00 0.00 0.04 4.5 2.5 1.0 1.6 2.1 1.3 1.9 0.4 2.4 1.9 1 Laboratory precision may also be evaluated based on absolute difference between duplicate measurements when concentrations are low. For data quality objective purposes, the absolute difference may not be larger than twice the method detection limit. 2 Analyses where both samples were below detection limits were omitted from this evaluation. The data show that laboratory precision was maintained within target limits throughout the course of the verification project. The field and analytical precision data combined suggest that the solids load and larger particle sizes in the inlet samples are the likely cause of poor precision, and apart from the field sample splitting procedures for inlet samples, the verification program maintained high precision. 6.1.3 Accuracy Method accuracy was determined and monitored using a combination of matrix spike/matrix spike duplicates (MS/MSD) and laboratory control samples (known concentration in blank water). The MS/MSD data are evaluated by calculating the deviation from perfect recovery (100%), while laboratory control data are evaluated by calculating the absolute value of deviation from the laboratory control concentration. Accuracy was in control throughout the verification test. Tables 6-4 and 6-5 summarize the matrix spikes and lab control sample recovery data, respectively. 37 ------- Table 6-4. Laboratory MS/MSD Data Summary Parameter Average Maximum Minimum Std. Dev. Range Count Calcium, total Copper, total Copper, dissolved Magnesium, total Phosphorus, total Phosphorus, dissolved Zinc, total Zinc, dissolved 16 15 16 16 20 16 16 15 98 98 101 99 103 101 97 97 113 116 116 102 109 106 103 105 94 86 92 97 97 97 91 93 4.7 8.6 6.5 1.5 3.2 2.5 3.2 3.3 80-120 80-120 80-120 80-120 70-130 70-130 80-120 80-120 Table 6-5. Laboratory Control Sample Data Summary Mean Maximum Minimum Std. Dev. Parameter Count Total calcium Total copper Dissolved copper Total magnesium SSC TSS Dissolved phosphorus TDS Total phosphorus Total zinc Dissolved zinc 13 27 7 13 15 15 11 15 16 16 4 97 100 101 97 99 100 101 105 101 98 96 105 106 106 103 108 117 107 118 106 103 98 91 91 92 92 87 89 97 98 96 95 94 3.6 3.9 4.5 3.1 5.6 7.9 2.9 6.1 2.4 2.3 1.7 The balance used for solids (TSS, TDS, and total solids) analyses was calibrated routinely with weights that were NIST traceable. The laboratory maintained calibration records. The temperature of the drying oven was also monitored using a thermometer that was calibrated with a NIST traceable thermometer. 6.1.4 Representativeness The field procedures were designed to ensure that representative samples were collected of both inlet and outlet stormwater. Field duplicate samples and supervisor oversight provided assurance 38 ------- that procedures were being followed. The challenge in sampling stormwater is obtaining representative samples. The data indicated that while individual sample variability might occur, the long-term trend in the data was representative of the concentrations in the stormwater. The laboratories used standard analytical methods, with written SOPs for each method, to provide a consistent approach to all analyses. Sample handling, storage, and analytical methodology were reviewed to verify that standard procedures were being followed. The use of standard methodology, supported by proper quality control information and audits, ensured that the analytical data were representative of actual stormwater conditions. Regarding flow (velocity and stage) measurements, representativeness is achieved in three ways: 1. The meter was installed by experienced USGS field monitoring personnel familiar with the equipment, in accordance with the manufacturer's instructions; 2. The meter's individual area and velocity measurements were converted to a representation of the flow area using manufacturer's conversion procedures (see Chapter 9 of Marsh-McBirney's O&M Manual in Appendix A of the test plan); 3. The flow calculated from the velocity/stage measurements was calibrated using the procedure described in Section 6.2 To obtain representativeness of the sub-samples (aliquots) necessary to analyze the various parameters from the event sample, a churn splitter was used. As noted in Radtke, et al. (1999), the churn splitter is the industry standard for splitting water samples into sub-samples. However, inconsistencies were noted in the sub-samples, especially when the sample contained high concentrations of large-sized sediments. The even distribution of the larger particulates becomes problematic, even with the agitation action of the churn within the splitter. The issue of the potential for uneven distribution of particulates has not been fully resolved. (Horowitz, et al, 2001). 6.1.5 Completeness The flow data and analytical records for the verification study are 100% complete. There were instances of velocity "dropouts" during some events. A discussion of the calibration procedures for flow data (velocity and stage measurements), including how velocity dropouts were addressed, is provided in Section 6.2. 6.2 Flow Measurement Calibration 6.2.1 Stage Measurement Corrections Static gauge height measurements were made at the inlet pipe by constricting the pipe to a steady-state water level. An inflatable ball was used to block the pipe. Water level readings from a measuring tape inside the pipe were compared to the water surface level recorded by the 39 ------- flow meters (located within the inlet pipe,). Gauge heights were checked thirteen times during the project. A gauge height correction curve with three gauge height points—bottom, middle, and top (approximately 0.0 ft, 0.3 ft, and 0.6 ft above the invert pipe elevation)—was developed for the pipe, as shown in Table 6-6. Most of the correction factors for the inlet lowered the recorded gauge height by approximately 5%. Corrections for the outlet pipe were also small (less than ± 2%). Table 6-6. Stage Height Corrections Gauge Height: Low Gauge Height Correction Date (ft) (unitless) Gauge Height: Medium Gauge Height Correction (ft)(ft) Gauge Height: High Gauge Height Correction (ft)(ft) 2/20/03 4/11/03 4/11/03 8/20/03 8/20/03 8/25/03 8/25/03 8/26/03 8/26/03 11/4/03 11/5/03 3/9/04 3/9/04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.01 0.01 -0.002 -0.002 0.061 0.061 -0.052 -0.052 -0.003 -0.003 0.006 0.417 0.417 0.35 0.35 0.29 0.29 0.29 0.29 0.29 0.29 0.35 0.35 0.31 -0.083 -0.083 -0.03 -0.03 0.04 0.04 0.059 0.059 -0.009 -0.009 0.011 0.011 0.002 0.635 0.63 0.635 0.635 0.4 0.4 0.4 0.4 0.4 0.4 0.69 0.69 0.63 -0.017 -0.017 -0.07 -0.07 0.05 0.05 0.056 0.056 -0.004 -0.004 0.02 0.02 0.012 6.2.2 Flow Calibration — Inlet Flume Measurements Flow meters at the inlet and outlet of the Vortechs were calibrated on April 18, 2003 and November 8, 2003 using similar procedures. A 3-in. Parshall flume attached to 2.5 ft width by 8 ft length by 2 ft depth chamber was mounted in the bed of a boom truck. Hydraulics on the boom truck was used to level the flume. Water was pumped from the Milwaukee River into the chamber minimizing flow turbulence in the approach section of the flume. Four different pumping rates were used to calibrate the flow meters. A 2-in. pump generated discharge rates of approximately 0.1 and 0.15 cfs, a 4-in. pump generated discharge rate of approximately 0.4 cfs and the two pumps together generated approximately 0.55 cfs. Flow from the flume was discharged through a 6-in. corrugated pipe upstream of the installed area-velocity meters. Water level in the flume was measured and discharge for the 3-in. Parshall flume was recorded. A 10 to 20 min pumping test was run for each rate and pertinent information from the meters was recorded manually from the CR10 data logger. Several steps were needed to correct each area-velocity meter flow using raw data. First, meters outputted point velocity, which was converted to an average area velocity by applying an equation created by the manufacturer. Overall, this decreased flows by an average of 10%. Second, the area of the pipe was reduced to the portion of the flowing pipe by subtracting the 40 ------- meter and cord area; this could be as much as half of the area at depth less then 0.1 ft. Flows were then calculated by multiplying the average velocity by the effective-cross-sectional area based on the water level. Because the velocity dropouts occurred at low and high flows the velocities from the meter were used only to assist in developing the flow rating described below. 6.2. 3 Developing the Rating Curve Discharge was estimated for each meter after gage height corrections were applied, then corrected stage values and flume discharges were plotted. Using this plot, a stage vs. discharge rating was developed that tracked through the flume-recorded points at gage heights ranging from 0.08 to 0.20 ft. The following USGS rating curve for stable channels was used, which is a modified form of Manning's equation (Ratz, 1982): 2n where: Q = discharge C = discharge coefficient G = gage height of the water surface e = effective zero control S = energy slope loss n = Manning's roughness coefficient Flows were estimated using Manning's equation where flume discharge was not available. Calibration data was not available at low flows (less than 0.08 ft.) because the velocities did not register until the meter was submerged or at high flows (greater than 0.20 ft, or 0.55 cfs) because this exceeded the calibration pumping rate capabilities. Manning's roughness coefficient was adjusted to fit the USGS rating curve for low flows and Manning's roughness coefficient was adjusted to fit the calibrated rating curve and corrected meter flow. The Manning's rating curve is expressed by the following equation: Q = (\A86/n)AR2/3Sl/2 (6-3) where: 1.486 converts to English units A = cross-sectional area based on the water level R = hydraulic radius based on the water level S = energy slope loss Figure 6-1 shows the rating curve developed as a result from this process. 41 ------- 0.75 Low High Flume Calibrated Actual Flume Points High Flow Meter Points 0.10 0.05 0.00 0.00 0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 Discharge (cfs) Figure 6-1. Calculated rating curve for Vortechs inlet site. 6.2.4 Outlet Volume Comparison This Vortechs configuration did not have an external bypass mechanism, so the calculated inlet and outlet event volumes should be the same, and a comparison of the calculated inlet and outlet volumes can be used to ensure both flow monitors worked properly. However, the outlet site area velocity meter experienced frequent problems. Because of these problems, a comparison of inlet and outlet volumes was not conducted as part of the QA/QC process. 6.2.5 Comparison of Runoff Volumes: Rainfall Depth vs. Inlet Measurements A final comparison of instrument measurements was to compare the measured rainfall depth over the drainage area to the runoff volume calculated at the inlet meter. The rational method was used to convert rainfall depth to runoff volume. The rational method is expressed by the following equation: Q = CIA (6-4) where: Q = Total Flow Volume (ft3) C = Runoff Coefficient (dimensionless) / = Rainfall Depth (ft) A = Drainage Basin Area (ft2) 42 ------- This data is summarized in Table 6-7. The runoff coefficient was 1 (since the entire surface is paved) and the drainage basin area is 10,890 ft2 (0.25 acres). Table 6-7. Comparison of Runoff Volumes Event Runoff Volume (ft) Event 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Date 4/30/03 5/4/03 5/9/03 5/30/03 6/8/03 6/27/03 9/12/03 9/14/03 10/14/03 10/14/03 10/24/03 3/25/04 3/28/04 4/17/04 5/12/04 5/20/04 8/3/04 8/24/04 Based on Rainfall Depth 998 653 790 490 563 517 272 427 245 209 644 771 790 218 499 218 1,630 771 Based on Percent Inlet difference Velocity (absolute Meter value) 847 795 717 665 847 518 156 588 268 138 613 311 216 69 311 259 2,510 449 Average Median Maximum Minimum Std. Dev. 15 22 9.2 36 51 0.1 43 38 9.4 34 4.9 60 73 68 38 19 54 42 34 37 73 0.1 22 The comparison shows that calculations for seven of the eighteen events are within 25% of each other. The rest of the events showed greater differences. There are several possibilities for differences in these readings including: • Inherent accuracy of each instrument (rain gauge and velocity meter). • Accuracy of the drainage area delineation. As stated previously, the drainage area was calculated from WisDOT design drawings and maintenance update documents (see Section 3.1). It is likely that the actual contributing area for each event varies depending 43 ------- on the rain depth, intensity, and duration. Small features in the highway decking (joints, cracks, etc.) will affect the drainage characteristics. • Inlet capacity may also affect the volume of rainfall entering the storm sewer system. 6.2.6 Point Velocity Correction Equations have been developed by the flow monitoring equipment manufacturer to correct for velocity measurements recorded at a single point. A point velocity can be different than the average velocity over the entire depth of the water in the pipe. The equation for the flow equipment lowered all the measured velocities by approximately 10%. 44 ------- Chapter 7 Operations and Maintenance Activities 7.1 System Operation and Maintenance Vortechs recommends inspecting the system on a quarterly basis. The main point of the inspection is to check that the sediment and debris trapped in the grit chamber (see Figure 2-1) does accumulate any higher than to within 6 inches of the dry weather standing water elevation. The dry-weather standing water elevation was about three feet from the bottom of the grit chamber. Inspections conducted by the TO and the USGS never found the accumulation of sediment and debris in the grit chamber to reach this level. The TO followed the manufacturer's guidelines for maintenance on the Vortechs system during the verification testing. Installation of the Vortechs was completed in December 2001. In the spring of 2002 the monitoring equipment was installed and initial monitoring began. Over the summer and fall of 2002, the inlet velocity meter and area around the inlet sampling intake was frequently inundated with sediment from the backwater effects of the Vortechs. It was decided to re-configure the inlet pipe system and move the velocity meter and sampling intake line above this backwater area. This allowed for better measurements. The pipe reconfiguration was completed in January 2003. No events monitored in 2002 were used for the verification evaluation. In the spring of 2003, the system was placed into operation and adjustments to the system were completed, ETV monitoring of the system began in April 2003. Table 7-1 summarizes O&M activities undertaken by the TO and USGS once verification testing was initiated. Table 7-1. Operation and Maintenance During Verification Testing Date Activity Personnel Time/Cost 4/18/03 04/29/03 11/08/03 USGS conducted velocity meter/flow measurement calibration. Sediment in Vortechs grit chamber observed at depths ranging from less than 1 inch to 2.5 inches. General Pipe Services jet-vac and vacuumed out Vortechs grit chamber (pre-monitoring cleanout). USGS conducted velocity meter/flow measurement calibration. 2 USGS staff® 12 hours each, (most time spent on calibration work; less than 1 hour for checking Vortechs l/2 day invoice = $985.00. Landfill fee for waste = $263.13 No maintenance conducted 45 ------- Table 7-1 (cont'd) Date Activity Personnel Time/Cost 05/07/04 08/30/04 09/09/04 09/24/04 Vortechs inspection by Earth Tech; measured sediment depth in grit chamber. Sediment relatively evenly distributed throughout chamber. Depths ranged from 1 to 2 in. Floatables covered about 5 - 10% of the surface. Oil sheen also observed. USGS inspected Vortechs and measured sediment depth in grit chamber. Measured depths ranged from 1 to 5.5 in. Water in chamber cloudy; sediment very soft and organic, not much sand or gravel. Very little floatables observed. Earth Tech inspected Vortechs; measured sediment depth in grit chamber. Depths ranged from 0 to 5.75 in. Also observed oil sheen and floatables in chamber. Outlet chamber also inspected, with a very thin layer of sediment observed. Some scum and oil observed in this chamber. Post monitoring clean out of Vortechs. Clean out conducted by Earth Tech, WDNR and USGS. A complete description of the process and results is presented in Section 7.2. 2 staff @ 2 hours each. 1 staff @ 1 hour. 2 staff® 1 '72 hours each. 4 staff @ 8 hours each (time commitment to capture all sediment and debris for drying and analysis). 7.2 Description of Post Monitoring Cleanout and Results 7.2.1 Background On September 24, 2004, the Vortechs was cleaned out so that as much of the solid material as possible from the device could be dried, weighed, and characterized. The weather was sunny and clear, with temperatures in the low 70s, and there had been no rain for the previous two weeks. The general steps followed were: 1. Take sample of standing water before any disturbance to analyze for TSS of water above the settled material. 2. Measure the standing water depth and sediment depth in the Vortechs before any removal of material 46 ------- 3. Decant the standing water using a hand held sump pump to a level 0.5 ft above the settled material layer. 4. Decant the next layer of water using hand held sump pump into five-gallon containers. Obtain a water sample from each five-gallon container, composite into one container for analysis of TSS. 5. Remove sediment from grit chamber and all accessible portions of the vault and place in five-gallon containers. 6. Transport containers to USGS lab in Middleton, Wisconsin for drying and weighing. 7.2.2 Field Procedures For purposes of solids and water measurements and removal, the system is divided into the following sections (from upstream to downstream in the system): • Inlet pipe • Grit chamber (tank 1) • Oil and Flow Control Chamber (tank 2) • Outlet Chamber (tank 3) Tanks 1 and 2 are hydraulically connected and have the same water surface elevation. Tank 3 is hydraulically separated from the upper two tanks with an independent standing water elevation. Standing water TSS samples: • Grit chamber: tank 1, bottle 1 • Lower chamber: tank 3, bottle 1 Water and sediment depth measurements in grit chamber (tank 1): • Manhole rim to top of water: 5.20 ft • Manhole rim to top of sediment: 8.10 ft • Manhole rim to bottom of grit chamber: 8.40ft • Depth of water in vault: 3.20ft • Depth of sediment in grit chamber: 0.30 ft 7.2.3 Measurement Results Table 7-2 summarizes the results of the material analysis. The term "sediment" is avoided in this analysis, because much of the material consisted of leaves, trash, and larger debris. The dry weight reported includes all the debris removed. The particle size analysis was conducted only upon the material after the larger debris was sifted out. As shown in Table 7-2, approximately 82% of the sediment retained in the sediment chamber had a particle size of 125 jim or larger. 47 ------- Table 7-2: Analysis of Vortechs Cleanout Material Material Dry Percent Less Than Particle Size (urn) Sediment Source Weir Chamber (tank 3) Inlet Pipe Grit Chamber (tank 1) (1 of 2 samples) Grit Chamber (tank 1) (2 of 2 samples) Grit Chamber (tank 1) average of 2 sub- samples) Total yicigiii (lb) 15 8.1 100 120 <4000 87 88 95 89 92 91 <2000 82 83 92 85 88 86 <1000 73 76 87 69 78 78 <500 54 62 75 59 67 64 <250 37 39 40 41 41 39 <125 21 18 16 20 18 18 <63 14 11 7.2 11 9 10 <31 10 6.4 5.4 8.3 6.9 7 <16 6.9 4.6 3.8 6.3 5.1 5 <8 4.4 3.5 2.6 4.3 3.5 3 <4 3.4 2.8 2.3 3.1 2.7 3 <2 2.5 2.0 1.6 2.2 1.9 2 48 ------- Chapter 8 References 1. APHA, AWWA, and WEF. Standard Methods for the Examination of Water and Wastewater, 19thed. Washington, DC, 1995. 2. Horowitz; AJ; Hayes, T.S.; Gray; J.R.; Capel, P.D. Selected Laboratory Evaluations of the Whole-Water Sample-Splitting Capabilities of A Prototype Fourteen-Liter Teflon* Churn Splitter, U.S. Geological Survey Open-File Report 01-386, 2001. 3. Fishman, M. 1, Raese, J. W., Gerlitz, C. N., Husband, R. A., U.S. Geological Survey. Approved Inorganic and Organic Methods for the Analysis of Water and Fluvial Sediment, 1954-94, USGS OFR 94-351, 1994. 4. Huff, F. A., Angel, J. R. Rainfall Frequency Atlas of the Midwest, Midwestern Climate Center, National Oceanic and Atmospheric Administration, and Illinois State Water Survey, Illinois Department of Energy and Natural Resources. Bulletin 71, 1992. 5. NSF International and Earth Tech, Inc. Test Plan for the Verification of. Vortechs* Model 100 Stormwater Treatment System "Riverwalk Site" Milwaukee, Wisconsin. March 22, 2004. 6. NSF International. ETV Verification Protocol Stormwater Source Area Treatment Technologies. U.S. EPA Environmental Technology Verification Program; EPA/NSF Wet- weather Flow Technologies Pilot. March 2002 (v. 4.1). 7. Radtke, D.B. et al., National Field Manual for the Collection of Water-Quality Data, Raw Samples 5.1. U.S. Geological Survey Techniques of Water-Resources Investigations Book 9, Chapter A5, pp 24-26, 1999. 8. United States Environmental Protection Agency. Methods and Guidance for Analysis of Water, EPA 821-C-99-008, Office of Water, Washington, DC, 1999. 49 ------- Glossary Accuracy - a measure of the closeness of an individual measurement or the average of a number of measurements to the true value and includes random error and systematic error. Bias - the systematic or persistent distortion of a measurement process that causes errors in one direction. Comparability - a qualitative term that expresses confidence that two data sets can contribute to a common analysis and interpolation. Completeness - a quantitative term that expresses confidence that all necessary data have been included. Precision - a measure of the agreement between replicate measurements of the same property made under similar conditions. Protocol - a written document that clearly states the objectives, goals, scope and procedures for the study. A protocol shall be used for reference during Vendor participation in the verification testing program. Quality Assurance Project Plan - a written document that describes the implementation of quality assurance and quality control activities during the life cycle of the project. Residuals - the waste streams, excluding final outlet, which are retained by or discharged from the technology. Representativeness - a measure of the degree to which data accurately and precisely represent a characteristic of a population parameter at a sampling point, a process condition, or environmental condition. Wet-Weather Flows Stakeholder Advisory Group - a group of individuals consisting of any or all of the following: buyers and users of in drain removal and other technologies, developers and Vendors, consulting engineers, the finance and export communities, and permit writers and regulators. Standard Operating Procedure - a written document containing specific procedures and protocols to ensure that quality assurance requirements are maintained. Technology Panel - a group of individuals with expertise and knowledge of stormwater treatment technologies. Testing Organization - an independent organization qualified by the Verification Organization to conduct studies and testing of mercury amalgam removal technologies in accordance with protocols and Test Plans. Vendor - a business that assembles or sells treatment equipment. 50 ------- Verification - to establish evidence on the performance of in drain treatment technologies under specific conditions, following a predetermined study protocol(s) and Test Plan(s). Verification Organization - an organization qualified by EPA to verify environmental technologies and to issue Verification Statements and Verification Reports. Verification Report - a written document containing all raw and analyzed data, all QA/QC data sheets, descriptions of all collected data, a detailed description of all procedures and methods used in the verification testing, and all QA/QC results. The Test Plan(s) shall be included as part of this document. Verification Statement - a document that summarizes the Verification Report reviewed and approved and signed by EPA and NSF. Verification Test Plan - A written document prepared to describe the procedures for conducting a test or study according to the verification protocol requirements for the application of in drain treatment technology. At a minimum, the Test Plan shall include detailed instructions for sample and data collection, sample handling and preservation, precision, accuracy, goals, and quality assurance and quality control requirements relevant to the technology and application. 51 ------- Appendices A Vortechs Design and O&M Guidelines B Test Plan C Event Hydrographs and Rain Distribution C Analytical Data Reports with QC 52 ------- |