Activity 1: MercuryLQ. Test 2-3
Students are provided with the LQ. Test as a pretest. It is used just to gauge their knowledge of
Mercury.
Household Information
Activity 2: Trade-Offs Exercise 4-7
Students evaluate the pros and cons of two alternative technologies.
Mercury in the Environment
Mercury in the Environment 8
The Mercury Cycle and Bioaccumulation 10
Activity 3: Mercury in the Food Chain 12
Students reinforce their understanding of food webs while gaining a new understanding of
bioaccumulation.
Activity 4: Atmospheric Mercury 16
Students will practice critical thinking skills as they examine data.
Mercury in Our World and Community
Mercury through the Ages 25
Mercury in Medicine 27
Industrial Mercury 29
Mercury in the Twentieth Century 29
Activity 5: Mercury through the Ages 30
Students relate the unique properties of mercury to its historical uses and offer suggestions for non-
mercury alternatives
Activity 6: A Local Survey about Mercury 34
Students conduct a community survey about mercury, either using the sample provided in the
package or one that they develop. They also develop a plan for communicating the results.
Activity 7: Mercury Community Action Projects 36
Students develop and implement an action plan for their community concerning mercury.
The content in this section was adapted from "Mercury in Schools and the Community: A
National Issue." University of Wisconsin System Board of Regents, March 2002.
Region 7
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Activity 1 - Mercury I.Q.
Handout to students to test their mercury I.Q.
1. What is mercury?
a. A type of tree found in the rainforest
b. An element on the periodic table (symbol: Hg)
c. A liquid aliens like to put on their hamburgers
2. What is another common name for mercury?
a. Quicksilver
b. Space goo
c. There are no other names for mercury
3. What can mercury be found in?
a. Switches
b. Thermostats
c. Thermometers
d. All of the above
4. Which animals are most likely to have elevated mercury levels in tissues?
a. Large fish
b. Snakes
c. Birds that live in a rainforest
5. Mercury is used in:
a. Dental fillings for cavities
b. Fluorescent lamps
c. Cars
d. All of the above
6. Mercury is mined today in what countries? (Mark all that apply)
a. U.S.
b. Spain
c. Mexico
d. Russia
7. Some states or local governments have passed bans on the sales of:
a. Mercury thermostats
b. Mercury thermometers
c. Fluorescent lights
d. (a) and (b) above
8. Mercury is the only known metal that is liquid at 72 degrees: True or False
9. Mercury can be very dangerous: True or False
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Answer Sheet for activity 1
1. b
2. a
3. d
4. a
5. d
6. b
7. d
8. True
9. True
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Activity 2 - Trade-offs
Purpose
One way to reduce mercury pollution from coal burning electrical plants is to use
less electricity. Fluorescent light bulbs use much less energy than incandescent light
bulbs, but most fluorescent bulbs contain tiny amounts of mercury. What makes
sense ecologically?
Objective
Evaluate the pros and cons of two alternative technologies.
Learn how to organize data and determine the mathematical relationships needed to
solve a problem.
Coherently present the results of calculations to support a recommended choice or
alternative.
Materials
S Handout titled "Trade-Offs: Your Lights, Your Environment and your
Checkbook"
•S Trade-offs: Question sheet and Answer sheet
Procedure
• This activity can be done as homework, or as an individual or group assignment.
• Make copies and distribute "Trade-Offs: Your Lights, Your Environment and Your
Checkbook," and the "Questions" sheet to the students and ask them to prepare
answers and justifications for all questions.
Fluorescent Bulbs
(Containing mercury)
Incandescent bulb
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Trade-offs
"Trade-Offs: Your Lights, Your Environment and Your Checkbook"
Incandescent vs. Compact Fluorescent Bulbs-
Energy Use, Mercury Emissions and Cost
The largest source of mercury to the environment is coal-burning electric power
plants. There is a very small amount of mercury in the coal that is burned to produce
electricity. However, because vast amounts of coal are burned, the amount of mercury
released up the smokestacks is very significant.
One of the largest uses of the electricity produced by these power plants is for
lighting homes, buildings and streets. Can the choice of light bulbs in our homes make a
difference in terms of the amount of electricity used, the amount of mercury released
and the amount that we pay for electricity? Let's figure it out.
Compact
Incandescent Bulb Fluorescent Bulb
Energy Requirement 60 watts 15 watts
Light Output 870 lumens 925 lumens
Average Life 1,000 hours 10,000 hours
Purchase Price $1.79 for 4 bulbs $2.75 each
Cost of electricity from the power plant: $0.07 per kilowatt-hour
Pounds of mercury released per kilowatt-hour of energy used:
3.69E-08 (0.0000000369)
Keep in Mind:
1 kilowatt =1,000 watts
A lumen is a measure of brightness
A kilowatt-hour is a measure of total energy used over a period of time
1 pound = 454 grams
It takes 10 Incandescent bulbs to last as long as 1 compact fluorescent bulb
Equations to Use:
1. Efficiency = light output -r- energy requirement
2. Amount of mercury released = hours of use x energy requirement x pounds of
mercury released per kilowatt-hour of energy x 454 grams/pound of mercury -r-1000
watts/kilowatt
3. Electricity cost = Hours of use x energy requirement x cost of electricity ^-1000
watts/kilowatt
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Trade-offs
Questions
1. Which type of light bulb - incandescent or compact fluorescent - is more
efficient? Why?
2. After 10,000 hours of use, how much mercury (in grams) is released to the
environment from the use of each of these two types of light bulbs?
3. After 10,000 hours of use, what are the total costs, including purchase price and
electricity, for each type of light bulb?
4. Which type of bulb would you recommend? Why?
Optional
5. Make an educated guess as to how many light bulbs are in use in your community.
Based on this estimate, design a study to determine the differences in cost and in
mercury released if all those bulbs were either incandescent or compact fluorescent.
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Trade-offs
Answers
Which type of light bulb - incandescent or compact fluorescent - is more efficient?
Why?
Efficiency, in this
case, is measured by light output per amount of energy used. For the compact fluorescent bulb,
this is 925 lumens/15 watts = 61.67. For the incandescent bulb, this is 870 lumens/60 watts =
14.5. Thus, the fluorescent bulb is 4.25 times more efficient.
After 10,000 hours of use, how much mercury is released to the environment due to
use of each of these two types of bulbs?
The amount of mercury released from use of the compact fluorescent bulb is
10,000 hours X 15 watts X .0000000369 pounds per kilowatt-hour X 454 grams per
pound -T- 1,000 watts per kilowatt = .0025 grams.
The equation for the incandescent bulb is the same, except that 60 watts is substituted for 15
watts. Thus, the amount of mercury released is 4 times greater for the incandescent bulb, or .01
grams.
Note: A compact fluorescent bulb contains approximately 4mg (0.004g) of mercury, which is
also released to the environment if the bulb is not properly recycled.
After 10,000 hours of use, what are the total costs, including purchase price and
electricity, for each type of light bulb?
Purchase price-
Compact fluorescent - $2.75
Incandescent- $1.79/4X 10,000/1,000 = $4.48
Electricity cost-
Compact fluorescent
10,000 hours X 15wattsX$.07 per kilowatt-hour^ 1,000 watts per kilowatt = $10.50
Incandescent
10,000 hours X 60 watts X $.07 per kilowatt-hour -r-1,000 watts per kilowatt = $42.00
Total cost-
Compact fluorescent
$2.75 (purchase) + $10.50 (electricity) = $13.25
Incandescent
$4.48 (purchase) + $42.00 (electricity) = $46.48
Thus, the incandescent bulb is three and a half times more expensive.
Which type of bulb would you recommend?
Consider efficiency (compact fluorescent is 4.25 times more efficient), amount of mercury
released (4 times less for compact fluorescent if the compact fluorescent bulb is properly
recycled) and total cost (three and a half times less for compact fluorescent).
Study design to determine the differences in cost and in mercury released for the community if
all those bulbs were either incandescent or compact fluorescent.
The study design should include identification of the following steps:
• estimates of the number of bulbs used in lighting homes, streets and businesses
• assumptions about the frequency of bulb replacement
• determination of the total amount of energy used by bulbs in the community
• application of the mercury released per kilowatt factor to determine total mercury releases
• determination of purchase and electricity costs
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Mercury in the Environment
In this section, you will learn about the
behavior of mercury in the environment
and why, in addition to human health
concerns relating to direct exposure,
mercury is an important environmental
issue. Much of the material in this
lesson is from the U.S. Environmental
Protection Agency's mercury Web site.
Mercury is a silvery, liquid metal at room
temperature and is often referred to as
one of the "heavy metals." Like water,
mercury can evaporate and become
airborne. Because it is an element,
mercury does not break down into less
toxic substances. Once mercury
escapes to the environment, it circulates
in and out of the atmosphere until it
ends up in the bottoms of lakes and
oceans. Mercury can be found as the
elemental metal or in a wide variety of
organic and inorganic compounds.
Depending on its chemical form,
mercury can travel long distances
before it falls to earth with precipitation
or dust.
Bacteria and chemical reactions in lakes
and wetlands can change the mercury
into a much more toxic form known as
methylmercury. Fish become
contaminated with methylmercury by
eating food (plankton and smaller fish)
that has absorbed methylmercury.
As long as the fish continue to be
exposed to mercury, mercury continually
builds up in fish's bodies. Fish that eat
other fish become even more highly
contaminated. Thus, the largest tend to
be the most contaminated.
When people eat the contaminated fish,
the methylmercury can remain in their
bodies for a long time. If they eat fish
containing methylmercury faster than
their bodies can discharge it, the
methylmercury accumulates in their
bodies and can be toxic. Many states
have fish consumption advisories to
inform people about how many meals of
certain types of fish they can safely eat
over a period of time.
Where Does Mercury Come From?
Mercury is a naturally occurring
element. Mercury ore - cinnabar - is
mined in Spain, Algeria, Kyrgyzstan and
China. Mercury is also a byproduct of
gold and zinc mining. Mercury enters
the environment from:
• Natural sources such as
volcanoes and the weathering of
rocks;
• Our intentional uses of mercury;
• Our unintentional releases of
mercury from burning fossil fuels
and smelting metals.
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1994-95 U.S. Mercury Emissions
(in tons)
(Taken from data in the U.S. Environmental Protection Agency's Mercury Study Report to Congress, 1997.}
Mercury's Environmental Effects
Fish are the main source of food for many birds and other animals, and mercury can
seriously damage the health of these species. Loons, eagles, panthers, otters, mink,
kingfishers and ospreys eat large quantities offish. The dose of mercury that these
animals ingest through fish can affect the speed and coordination necessary to catch
their prey.
Recent research in Minnesota indicates that the following environmental effects are
occurring:
• Loons are accumulating so much mercury that it might be affecting their ability to
reproduce;
• Elevated levels of mercury have been found in mink and otters;
• Walleye reproduction might be impaired by the fish's exposure to mercury.
Similar effects are being documented for other fish and fish-eating species around the
United States and Canada. Has there always been mercury contamination, or is this a
recent problem? This is a difficult question to answer, in part because of a lack of
adequately preserved fish specimens of pre-industrial age to compare against
contemporary samples. However, several lines of evidence from recent studies on
Wisconsin lakes suggest that increased emissions to the atmosphere, and subsequent
higher deposition rates to lakes, likely translate into higher mercury levels in fish.
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The Mercury Cycle and
Bioaccumulation
There is a constant
biogeochemical cycle of
mercury. This cycle includes
• release of elemental
mercury as a gas from the
rocks and waters
(degassing);
• long-range transport of
the gases in the
atmosphere;
• wet and dry deposition
upon land and surface
water;
• absorption onto sediment
particles;
• bioaccumulation (or
biomagnification) in
terrestrial and aquatic
food chains.
Bioaccumulation means an increase in the concentration of a chemical in an organism over
time, compared to the chemical's concentration in the environment. Bioaccumulation can be
a normal and essential process for the growth of any species, but the accumulation of
unnecessary chemicals or toxins, or even the overaccumulation of essential substances can
be detrimental. All animals, including humans, daily bioaccumulate many vital nutrients,
such as vitamins A, D, and K, trace minerals, essential fats and amino acids, but
unfortunately, they can also accumulate many unnecessary substances, such as lead or
mercury. What concerns toxicologists is the bioaccumulation of necessary substances to
levels in the body that can cause harm. With substances such as lead or mercury, any
accumulation at all can be harmful. Compounds accumulate in living things any time they
are taken up and stored faster than they are broken down (metabolized) or excreted.
Understanding the dynamic process of bioaccumulation is important in protecting humans
and other organisms from the adverse effects of chemical exposure, and it has become a
critical consideration in the regulation of chemicals.
10
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Bioaccumulation varies among individual organisms as well as among species.
Large, fat, long-lived individuals or species with low rates of metabolism or excretion of a
chemical will bioaccumulate more than small, thin, short-lived organisms. Thus, an old lake trout
might bioaccumulate much more than a young bluegill in the same lake.
imir|;r: ^ Jrgamc
mercury —*• mercury
BncJn'M
Inorganic, + Organic
maicury * mercury
ftrtirni
Above is a schematic drawing of mercury cycling in an aquatic ecosystem. With the exception of
isolated cases of known point sources, the source of most mercury to most aquatic ecosystems
is deposition from the atmosphere, primarily associated with rainfall.
In the aquatic environment, mercury can be
• dissolved or suspended in the water
• trapped in the sediments
• ingested by living things (biota)
Methylmercury is the form of mercury most available and most toxic to biota (including
zooplankton, insects, fish, and humans). This form of mercury is easily taken up by biota and
bioaccumulates in their tissues. Unlike many other fish contaminants, such as PCBs, dioxin, and
DDT, mercury does not concentrate in the fat but throughout the muscle tissue. Thus, there is
no simple way to remove mercury-contaminated portions from fish that is to be eaten.
11
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Mercury in the Environment
Activity 3 - Mercury in the Food Chain
Purpose
This activity will help the students reinforce their understanding of food webs while
gaining a new understanding of bioaccumulation.
Objectives:
Students will
1) Display a graphic understanding of an aquatic food web for a specific local body
of water; and
2) Demonstrate an understanding of bioaccumulation.
Materials:
S A map of your state showing waterways (a state highway map will usually work),
paper and something to draw with
S Copies of "Example from Florida aquatic food web and mercury cycle" and
information provided in Mercury in the Environment section of this curriculum
package
S If you choose the teacher lead option you will need the following materials:
• 10 very small (1-2 oz.) cups
• (clear containers are the best, but use what you have).
• 5 small containers (4 -5 oz.)
• 3 medium containers (around 8 oz.)
• 1 clear container (large to hold around 7-8 cups)
• Glitter (3 colors) or small beads (3 colors) or something similar that is very small
and can be found in 3 distinct colors
Procedure:
1. Select a body of water or a number 3. Select either student self-discovery
of water systems in your state. or teacher lead and follow
2. Divide the class into study groups. accordingly.
Assign each group a lake, river, bay, 4. Students should share their findings.
coastal area, etc. Each group should
then create a food web for their
study site. Include as many of the
components that they can find. You
may use the Florida example on
page 14 as an idea sheet.
12
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Select one of the two options:
student self-discovery or teacher
lead
Student self-discovery: Present each
group the following scenario - the
water they are in charge of has
shown signs of mercury
contamination. As scientists they
are to demonstrate to the public
what "bioaccumulation" is and
why we have to be concerned
about it.
1. Allow them to use a variety of
materials.
2. Give each group 5 minutes for
their demonstration.
3. If you wish, you can set up a town
board to judge who did the best
job of demonstrating the issue.
Teacher lead:
You will need to gather the following
materials: (clear containers are
the best, but use what you have).
• 10 very small cups (1-2 oz.)
• 5 small containers (4 -5 oz.)
• 3 medium containers (around
8oz.)
• 1 clear container (large to
hold around 7-8 cups)
• Glitter (3 colors) or small
beads (3 colors) or something
similar that is very small and
can be found in 3 distinct
colors.
1. Fill each container to one-third full
with water.
2. Now, representing mercury, you
will put a pinch of one color of
glitter in each of the 10 very small
(1-2 oz.), another color in the 5
small containers (4 -5 oz.), and
the third color in the 3 medium
containers (8 oz.)
Using one of the food chains the
students developed, have the
students label the 10 very small ones
as the micro-organisms, the 5 small
ones as the animal that eats the
microorganisms (small fish, insects,
etc.), the medium would be the
animal that eats the small ones and
the clear container will represent a
top predator.
Now have the students help you with
the demonstration and put the food
chain and bioaccumulation into
action. First, the 10 very small
containers (they are being eaten by
the primary consumer) are poured
into the small containers. Some of
the glitter might stay in each
container as you pour. That is OK; it
represents the mercury that is
excreted by the animal (not 100
percent of the mercury
accumulates). Now the small
containers will be eaten by the
medium or secondary consumer.
And finally the medium are eaten by
the top predator (tertiary consumer).
Discuss what just happened, with
special emphasis on the glitter. How
much of the mercury was
accumulated by the top predator?
Regardless of whether you did the
student self-discovery or the teacher
lead option, now hand out the
Bioaccumlation in humans chart
on page 15 and discuss what they
have learned through the activity.
13
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OEPOSTIOV (Hgfll \ O-fcH^
•/: WTLB5W1ON •
Example from Florida aquatic food
web and mercury cycle
14
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Bioaccumlation in humans
15
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Mercury in the Environment
Activity 4 - Atmospheric Mercury
The majority of mercury entering lakes, streams, rivers, and oceans comes from the
atmosphere. It is important to understand why mercury is in the atmosphere because
once we understand the causes, we can concentrate on controlling the sources. In this
activity, students will begin to recognize patterns and make educated guesses based on
those patterns.
Objective
1. Students will demonstrate critical thinking skills.
2. Students will make educated guesses (scientific inquiry) based on patterns shown in
data.
Materials
•S Mercury Sources Fact Sheet
v' Activity 7 sheets: First, Where is Mercury?; Second, Mercury in the Air, Third,
Fish Advisories
v' Background information concerning fish advisories...
^ Optional: EPA Fact Sheet
Procedure
1. This activity is based on critical thinking and the development of the thought process;
therefore, it is crucial that the different parts are given one at a time, in the prescribed
order. The activity can be done individually, in small groups, or as a large group in a
discussion format.
2. Hand out the pages, Mercury Sources Fact Sheet (p. 17) and Where is Mercury? (p.
18). Have students review data and complete the assignment.
3. Once the first assignment is complete, hand out Mercury in the Air (p. 19). They will
need their first assignment to complete the second.
4. Once the second assignment is complete, hand out the third, Fish Advisories (pp. 20-
23). They will need the first and second to complete the third.
Optional
5. Review and discuss the EPA fact sheet (which can be found at the end of this activity
on p. 24).
16
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Clean Air Network Fact Sheet
August 1999
Mercury Sources Fact Sheet
Coal Plants are Largest Mercury Source
The majority of mercury entering lakes, streams, rivers, and oceans comes from the
atmosphere. Air deposition accounts for up to 90 percent of the mercury entering Lake
Superior, and 80 percent entering the Delaware Bay.
• 85 percent of mercury emissions come from smokestacks, primarily power
plants and municipal and medical waste incinerators.
• 33 percent of all mercury emissions come from power plants (coal- and
oil-fired), emitting 52 tons per year.
How Far does Mercury Travel in the Atmosphere?
The amount of mercury deposited around a smokestack depends on the height of the
stack, the chemical species of the mercury, and the amount of rainfall at the particular
site. Using power plants as an example, the table below shows that plants with shorter
stacks will have more local deposition than those with taller stacks, and more mercury is
deposited locally in a humid site compared to an arid site.
EPA models estimate that 7 percent to 45 percent of all mercury emitted in humid sites
deposits within a 30-mile radius, whereas 2 percent to 38 percent emitted in arid sites
deposits within 30 miles. This implies that at least 55 percent of all mercury emissions
are transported more than 30 miles from the source, and models show that mercury can
be transported across considerable distances.
The Electric Power Research Institute calculates that up to 10 percent of the mercury
released deposits within 62 miles of a power plant, and the rest is transported regionally
and globally.
Power Plant Type
Average Stack Height
(ft)
Large coal-fired power plant
Medium coal-fired power plant
Oil-fired power plant
Small coal-fired power plant
731
465
288
265
Percent of Emissions
Deposited within 30 miles
Arid Site
2
4
6
9
Humid Site
7
9
11
14
Source: US EPA, 1997, Mercury Study Report to Congress—Volume III, Tables 5-15 and 5-16. Note: The
percent deposited at each site is the sum of the percent deposited via dry deposition and wet deposition.
17
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Activity 4 - Where is Mercury?
Which state(s) do you think have the biggest problem with atmospheric mercury
(mercury that travels through the air)?
Keep in mind:
• Areas of large populations of people using electrical energy.
• General wind patterns travel from west to east.
Highlight on map where you think the biggest atmospheric mercury problem would be
and explain why.
18
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Activity 4 - Mercury in the Air
National Atmospheric Hg
Deposition
Deposition in
O 1-0-2.0
• 20-5.0
85.0-10.0
10.0-20.0
• >2D.O
iUSGS
Source: US EPA, 1998. Mercury Report
to Congress
How would you explain the pattern shown on this map?
(What are the similarities and differences?)
After reviewing this map, would you be more concerned about mercury if you lived in
New York, Texas, or California? Does this mean the other two (that you didn't pick) do
not have to worry about mercury?
19
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Activity 4 - Fish Advisories
Total Number of Fish Consumption Advisories - 2000
(Change from 1999)
NH.8<+3)
MA- 107(0)
HI. 3(41)
CT-13(0)
NJ - 49(0)
DE . 20(0)
MO . 4(0}
DC- 1(0)0
WV
AS - 1 (0) D VI - 0 (0) D
GU-0(OiQ PR-0(0)D
D AMMUMBMtRT^mMe
Q St«t*Hkl* mm only »dvi*ory inclueW m court
O Suiswide nv«r& only advisory mchxtod in caunl
D Smrandc mnra and Wtu advuory mdudad In count
• Stalmtdi couui advuory indudad m oounl
1999 Total. 2,651
Note: A lUIAMde idvitory it tuucd to w*m thr pubic of the poltnti*! l» wkteifxtid conUmvuriion 2000 Total . 2,638
o* tpfdfic ipKM in ceitwn typo of wMcrbodici. iUW *dw«3ry d«U should no( be uKd tor
{htntlnwing grognphic dotnbubon of chemol conUnwvma or NX rrukng ftttrWMt (
How does the National Atmospheric Hg Deposition map relate to this map?
(Are there similarities or patterns between the two?)
Why would a state such as New Mexico, which does not show any atmospheric mercury
deposition, have as high or higher amounts offish advisories than a state that is in the
middle of the heavy atmospheric deposition (such as West Virginia)?
20
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Background information concerning differences in fish advisories
and atmospheric deposition in New Mexico and West Virginia
The following information shows that even though West Virginia is in the area of much
higher mercury deposition, New Mexico has been able to do more extensive research
and is taking a more preventative stand than most states.
Excerpt taken from a release from the West Virginia Bureau for Public Health:
The West Virginia Bureau for Public Health (BPH) encourages anglers and consumers
to take notice of advisory notifications issued warning pregnant women, women of child
bearing age, nursing mothers and children about the health concerns of consuming fish
that may be contaminated with mercury. The warnings were issued by the United States
Environmental Protection Agency and the Food and Drug Administration.
This action is being taken based on an assessment by U. S. Environmental Protection
Agency (EPA) of data collected nationwide. The agencies in West Virginia that develop
fish consumption advisories, the Bureau for Public Health, Division of Natural
Resources and Department of Environmental Protection, agree that limited data
currently available in West Virginia support this recommendation, however, additional
fish sampling is required to determine more specifically the extent, level of
contamination and species affected by mercury.
A short summary of New Mexico's efforts:
(taken from New Mexico Environment Department)
Atmospheric deposition of mercury
With the exception of localized mineral deposits and certain industrial settings, the
greatest source of mercury to the environment is atmospheric deposition. Even though
the concentration in the atmosphere is very low, our watersheds provide large
catchments, and mercury is carried by runoff into waterways on fine particles of soil.
These particles, easily held in suspension by the force of moving water, are eventually
trapped behind dams, where they settle into the poorly oxygenated region at the bottom
of the reservoir. In the anoxic sediments and hypolimnetic waters above them, sulfate
reducing bacteria combine some of the inorganic mercury with methane, forming the
methylmercury that biomagnifies so powerfully as it is concentrated and passed from
prey to predator up the food chain.
Because mercury has been found in some fish at concentrations which could lead to
significant adverse human health effects, specific guidelines have been prepared These
guidelines allow those who fish and their families to make an informed decision as to
what fish they can safely eat. While the occasional consumer of fish from these waters
is at little risk if they are otherwise in good health, ingestion of mercury at levels found in
some fish over a long period of time could result in health problems such as kidney
disease and/or eye, respiratory tract, nervous system or brain damage.
21
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How did we first discover the problem?
Some routine spot-checking by the federal government first found the problem. We
verified it, and continued testing other lakes in New Mexico.
Have enough fish been tested to be really sure of the level of mercury
contamination?
Yes, for the lakes for which we have issued health advisories. Mercury levels are
strongly correlated with the length of the fish because longer fish are older and have
had more time to accumulate mercury. Thus only four fish of different lengths from each
species in a lake need to be tested in order to predict with great accuracy the levels of
mercury in all the fish. However, we are testing more fish than this in order to verify our
statistical models.
Where is the mercury in the fish coming from?
We don't know for sure, but we have not found any single source for it here in New
Mexico so far. Studies in other areas of the U.S. and the world have found that most of
the mercury appears to be coming from the air and then deposits in lakes and on soil.
The mercury gets into the air from industrial processes including smelters. Another
possibility is that mercury can be found naturally in different types of soils, and become
washed into lakes with soil disturbances such as overgrazing, housing developments,
road developments, etc.
Why would some lakes have a problem and others not?
The factors which affect the amount of mercury which gets into the fish are not fully
understood. However, some of them appear to be:
1. More acid lakes lead to more conversion of mercury to methylmercury, which is
taken up by the fish more easily.
2. Recently formed lakes, especially those with submerged decaying vegetation such
as trees, are more likely to convert mercury to methylmercury.
3. Smaller lakes may have the mercury more concentrated.
4. Rivers with swiftly moving water will usually have less concentrated mercury.
5. Bigger fish, and species of fish which eat other fish, get larger amounts of mercury.
State/EPA mercury screening survey
In 1995 and 1996, staff of the Surface Water Quality Bureau (SWQB) conducted a
screening survey for mercury covering over 2,000 miles of New Mexico's waterways.
Analyses were provided, free of charge, by EPA s Environmental Monitoring Systems
Laboratory (EMSL) in Cincinnati, Ohio. EMSL was able to provide a minimum detection
limit of 0.7 ng/L (0.7 parts per trillion). Using ultra-clean sample handling protocols
developed by SWQB staff, over two hundred stations were sampled before the EMSL
project lost its funding and was terminated. This study is the most comprehensive
evaluation of mercury levels in New Mexico's waters ever conducted. The Surface
Water Quality Bureau has been given the use of the analytical equipment used in the
State/EMSL mercury screening survey. This equipment now resides at the Scientific
Laboratory Division of the New Mexico Department of Health (SLD). Staff of the SLD
are currently developing a small clean room to provide a suitable laboratory
environment for the analysis of mercury at low parts per trillion levels.
22
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Survey results
The data from that study show that, with some notable exceptions, mercury levels in our
rivers and streams are very low. The average concentration of mercury in New Mexico's
waters is less than 2.5 ng/L (Range: 0.0 ng/L to 500.0 ng/L). No water sample drawn
from any major waterway in New Mexico has been found to contain mercury at a level
that could pose any degree of direct risk to humans or wildlife. While much work
remains to be done, to date it appears that in all but one instance where mercury was
found to exceed the current state chronic criterion of 12 ng/L (parts per trillion) its
occurrence can be attributed to either mining activity or storm water runoff from Los
Alamos National Laboratories (Up to >3,400 ng/L). The single exception appears to be
related to a coal seam in San Juan County.
Fish tissue mercury concentrations
Despite the extremely low concentrations of mercury in the State's waters, levels in the
tissues of certain fish, (usually large, predatory species), can still exceed the FDA action
limit of 1.0 part per million, an increase over background of six orders of magnitude. It is
this tendency of mercury to biomagnify as it is passed up the food chain that generates
concern. Fish are about ten times as tolerant of mercury than are humans. This is
possible because they have evolved an efficient strategy for sequestering mercury away
from vital organs: they store it in muscle tissue - the portion we eat.
23
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&EPA
United States
Environmental Protection
Agency
Office of Weiter
4305
EPA-S23-F-01-010
April 2001
Fact Sheet
Update: National Listing of Fish and Wildlife Advisories
Summary
The 2000 National Listing of Fiih and Wildlife Advisories is new available fay? the ii.S. Unviromrxnta! Protection Agenc, i'ER4.'.
Staffs, tribes, a no1 territories ecpoii that the number of fish consumption advisories issued in 2000 rose by IS 7, a 7% increase over
i 999. The total number of advisories in the United States increased for four major contaminants—meicury, PCS;, dioxins, and
DDT—tiyt remained (Sic same for chlordane. This is the third year in which the number of advisories issued for chlordane has
declined or remained constant. The increase in advisories generally reflects an itxrease in the >\imber of assessments performed and
the improved quality of monitoring and data collection methods. The number of acres of lakes under advisory increased from 20.4%
in i"P9°fo23sY> in 2000. a total of 63.283 lakes, while the number of river miles tinder advisory increased from 6.8% in 1999 to
9.3% in 20QQ. The suney showed inaf iOO% of the Great Lakes and their connecting waters and 71% of coastal waters of ti~
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Mercury In Our World and Community!
To gain a clear understanding of the impact of mercury on our communities and lives, it
is good to have an understanding of historical mercury uses and what is happening right
now. To do this, this section has been divided into two sections: Mercury through the
Ages, which is an excellent way to work on your students' history achievement
standards and science at the same time; and Mercury Right Here and Now. There are
things you can do today to reduce mercury pollution in our world, giving the youth a
sense of immediate success and also helping the community by reducing the possibility
of mercury poisoning.
Mercury through the Ages
You will explore the historical uses of mercury, from ancient
cultures in Egypt and China to a 1950s American car classic and
everything in between. You can contrast these historical uses with
the current uses described in previous sections of this curriculum.
The Ancients
Mercury has been known since ancient times. The chemical
symbol, Hg, is taken from the Latin, hydrargyrus, meaning "liquid
silver." Evidence shows that the Chinese were using mercury
before 2000 B.C. The ancients realized mercury was toxic and
assigned the task of mining quicksilver to slaves and prisoners. The
average life span of miners was 3 years from when they started this
hazardous work. Ancient Egyptian tombs contain vials of mercury,
demonstrating the ability to mine and refine mercury.
25
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Virtually all mercury is derived from
cinnabar, or mercury sulfide (HgS). Red
cinnabar is so rich in mercury content
that droplets of elemental mercury can
be found in samples of the ore. The ore
is heated with a reducing agent (such
as oxygen, iron, and quicklime), and
the mercury vapor is released into
vertical columns of water, where the
mercury liquefies. Mercury is quite
dense; it collects at the bottom while
most impurities float on the surface,
where they can be scraped away.
Cinnabar—mercury ore
From the Middle Ages through the Renaissance
' *
'. 6 \
•• f t
* *
I
^jgj»
Alchemist's text
During the middle ages, alchemists experimented
with various ways of turning metals and other
substances into gold. Many used mercury in their
processes and many were poisoned, although no
one knew the cause at the time.
Many of the English monarchs during this period
also dabbled in alchemy, and experts suspect that
at least some of their erratic behavior can be
explained by mercury poisoning! King Charles II,
who became king of England in 1660, was a
practicing chemist/alchemist who had his own
laboratory. He experienced personality changes
late in life and died of kidney failure, probably
from mercury poisoning.
Historians of science have studied the lives of several famous scientists of the period
and conclude that historical accounts of certain years of their lives, which correspond
with their use of mercury, exhibit strong evidence of the symptoms of mercury
poisoning.
One such notable is Sir Isaac Newton, although historians
are quick to point out that the period of suspected mercury
poisoning in his life did not occur while he was deriving the
calculus or deducing the law of gravitation. Newton also
was an alchemist who actually tasted the chemicals he
worked with. At age 49, he became emotionally disturbed
for a couple of years. In 1979, hair strands from his corpse
26
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were tested for mercury and were found to contain 75 parts per million. (Normal levels
are about 5 parts per million.)
Another scientist who worked with mercury and exhibited some erratic behaviors was
chemist and physicist Sir Michael Faraday, discoverer of electricity. He used mercury in
his electrical equipment and suffered from memory loss and a nervous breakdown.
Mercury in Medicine
Mercury has been used in a variety of medical remedies for a long time. One of its most
important uses was for treatment of syphilis. Syphilis was rather widespread among the
ruling families of Europe, and mercury was the most prominent treatment for several
centuries. Historians speculate that many of these rulers experienced mercury
poisoning. The "common man" was also subject to this disease, and the treatment was
the same—mercury. The following account illustrates how knowledge of this treatment
regime was put to good use in a recent archaeological study.
Archaeologists seeking the elusive remains of Fort Clatsop, the winter quarters of
the Lewis and Clark expedition in 1805-1806, are getting down to basics—they are
looking for the camp's privies. Researchers from the National Park Service, the
Museum of the Rockies and the University of
Washington are analyzing levels of mercury in the soil at the site, near Astoria,
Oregon. Mercury was a common Army treatment for syphilis: Meriweather Lewis
dispensed it in large doses to the men of the Corps of Discovery.
High levels of the metal in specific soil samples would indicate the site of a privy.
"With 33 men there for 106 days, we should be able to find some high
concentrations of mercury," said Cindy Orlando, Superintendent of the Fort Clatsop
National memorial. Because Army regulations at the time stipulated that privies be
located certain distances from encampments, finding signs of one would make it
easier to locate the 50-foot by 50-foot fort.
Route of the Lewis and Clark expedition
27
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Mercury was also part of a common anti-depressive medication formulation used during
the 19th century. The following article, titled "Lincoln's Little Blue Pill," appearing on
ABCNews.com on July 17, 2001, shows how users of this medication were probably
exchanging one set of symptoms (depression) for another (mercury poisoning). It also
illustrates how the effects of mercury are reversible once the exposure is eliminated.
At one point during a debate, Lincoln reached over and picked up a man by the
collar and shook him "until his teeth chattered," according to a study that appears
in the summer issue of Perspectives in Biology and Medicine. He became so
angry "his voice thrilled and his whole frame
shook," the study says. Lincoln only stopped when
someone, "fearing that he would shake Ficklin's
head off," broke his grip. The study says mercury
poisoning may explain Lincoln's behavior. "We
wondered how a man could be described as
having the patience of a saint in his 50s when only
a few years earlier he was subject to outbursts of
rage and bizarre behavior," said Dr. Norbert
Hirschhorn, a retired public health physician,
medical historian and lead author of the study.
Abraham Lincoln during a
calmer moment
The study reformulated "blue mass," a common anti-depressive medication of the 19th
century that Lincoln took. The study showed that it would have delivered a daily dose of
mercury exceeding the EPA standard by nearly 9,000 times. "Mercury poisoning
certainly would explain Lincoln's known neurological symptoms: insomnia, tremor and
rage attacks," said Dr. Robert G. Feldman, an expert on heavy metal poisoning and co-
author of the paper. "But what is even more important, because the behavioral effects of
mercury may be reversible, it also explains the composure for which he was famous
during his tenure as president."
The ingredients in "blue mass," besides mercury, included licorice root, rose water,
honey, sugar, and dead rose petals, according to the study. It was compounded with an
old-fashioned mortar and pestle and rolled to size on a 19 -century pill tile. The vapor
released by two pills in the stomach would have been 40 times the limit set by the U.S.
National Institute for Occupational Health, the researchers found. The amount of solid
mercury absorbed from two pills would have been 750 micrograms. The EPA indicates
that not more than 21 micrograms of any form of mercury per day should be safely
ingested. Someone who consumed the common dose of two to three little pills per day
would have been at serious risk for mercury poisoning, the study said. Mercury was also
used in antiseptic formulations (e.g. mercurochrome) and anti-itching compounds (e.g.
calamine lotion).
28
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Industrial Mercury
By the 1800s, mercuric nitrate was
widely used to soften fur for hats. The
resulting exposure of workers led to a
classic syndrome and the phrase "mad
as a hatter." In Danbury, Connecticut, a
center of hat making, the effects of
exposure were characterized as
"Danbury Shakes." It was not until 1941
that the use of mercuric nitrate in hat
making was banned in most states.
One of the world's best-known mercury
mines-the Almaden mine in Spain—has
been in continuous operation since 400
B.C. Mercury's discovery in California
predates the discovery of gold by
several years. The discovery of
commercial mercury ore bodies led to
the development and operation of
numerous mines from the 1840s to the
early 1960s, from which more than 220
million pounds of elemental mercury
were produced. The 1848 discovery of
gold in the Sierra Nevada created a
ready market for mercury produced by
the mines in California's coastal ranges.
Mercury forms a relatively insoluble
amalgam with gold, and miners used
this property to increase gold recovery.
An estimated 10 to 30 percent of the
mercury was lost to the environment in
this process, transported into streams
and reservoirs along with the discharged
sediments (tailings or "slickens") from
the hydraulic mining operations.
Mercury from hydraulic mining has been
transported with sediments downstream
into the San Francisco Bay/Sacramento-
San Joaquin Delta estuary, where it has
probably contributed to elevated
mercury concentrations in fish, resulting
in consumption advisories.
Mercury in the Twentieth Century
Mercury achieved widespread use
during the 1900s in industrial,
commercial, and residential applications
because of its many unique properties.
Many of these uses exist today. Other
uses have been banned or phased out;
for example, mercury in latex paints,
children's sneakers that lit up and maze
games.
One particularly interesting use of
mercury that has since been eliminated
was in cars. Up to 40 pounds of mercury
were incorporated into the road leveling
device on one model of late 1950s
Studebaker. Who knows what happened
to all that mercury and if the vintage
Studebaker owners of today are aware
of what is in their vehicles. (Other uses
of mercury in cars, such as in tilt
switches that control trunk lights, have
not yet been totally phased out.)
At lual... '1 mil xfinrtK mi' tliuf'x 5 /.... niiixl pOWGr-pei'-pOltltd iifinii/ .(nirrinni rur;
inn/ Ittri-r'x I'linii: /n;• )
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Mercury In Our World and What You Can Do!
Activity 5 - Mercury through the ages
Using the attached table on page 31, "Unique Properties of Mercury," and the
information in the preceding Mercury though the Ages section, ask the students to
complete the following activity.
For each of the following historic uses of mercury, indicate the unique properties of
mercury that form the basis for this use and, if time permits, think of or research a non-
mercury alternative to that use.
Historic use
unique property(s)
non-mercury alternative
Gold mining
Insecticides
Dental amalgam
Batteries
Road leveling
device in cars
Mercurochrorne
Electrical tilt
switches
Anti-depressive pills
Latex paints
Thermometers
Children's maze
games
30
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[Unique Properties of Mercury"
Implications
* Only metal that is liquid at
room temperature.
Holds fascination for people of all
ages. Special ceremonial uses in
several different cultures.
* Easily evaporates into the air.
A blob of mercury sitting on the table
will eventually disappear. The
mercury vapors can be extremely
dangerous to breathe.
* Very dense, yet fluid.
Just a little bit weighs a lot, yet
moves around easily. This is useful
in certain medical procedures.
Good conductor of electricity.
Used in electrical tilt switches and
other electrical devices.
* Expands or contracts uniformly
with changes in temperature.
Used in thermometers and
thermostats.
* Readily combines (amagamates)
with other metals and materials.
Dentists combine it with silver to
make amalgam, which is used to
fill cavities in teeth.
* Kills bacteria and fungi.
Previously used in pesticides, paints
and on people to kill germs!
31
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Mercury Right Here and Now
You might have already started by eliminating mercury in your school and home, or
maybe you reduced your energy consumption. Now it is time to take even greater
action. In order to take community action, you need to know where your community
stands. Have the students find out what people know or do not know about mercury by
conducting the "Local Survey about Mercury." Once the students have done this, have
them report on their findings and the implications of those findings to the full group.
Activity 6 - A Local Survey About Mercury
Objectives:
Students will: 1) design and conduct
a survey of their community on the
subject of mercury; 2) evaluate the
results of the survey and develop an
action plan to address the survey
findings.
Materials:
Sample Survey
Background:
Are residents in your community
concerned about mercury? Do any
businesses use mercury in their
operations? Does your community have
the cleanup equipment to handle a
mercury spill? Do residents in your
community know about the health
threats of mercury? Are any lakes in
your region listed in the state fish
advisory? Do anglers care?
One method of finding answers to
these questions and others is to design
a survey and conduct it in your
community. It is an interactive process
that requires preparation, involvement
and interpretation. The results can lead
students to take an active role in
tackling an environmental problem in
their community.
Several different methods can be
used to study information and opinions
about environmental issues. Here are
two different methods.
Surveys can be used to collect
information about environmental
conditions in your school and
community. They focus on information
about a specific problem in a certain
area. Example: How many mercury
thermometers do you have in your
home?
Opinionnaires measure the beliefs
or opinions of people at a specific time.
They are each person's opinion -which
might or might not be accurate or
correct.
For example:
I believe mercury is dangerous to
human health.
Strongly Agree, Agree, Neutral,
Disagree, Strongly Disagree
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Before a method is selected, it is
important that students carefully
decide the exact information that
needs to be collected, the
geographic area they want to cover,
and the target population that will be
surveyed. A combination of methods
can also be used. Accurate
collection of the information is next.
The students should prepare a data
summary sheet to record their
information.
Once the data has been
collected, students will be challenged
to interpret the information and
suggest ways to share their results
and actions that need to be taken.
A valuable book to assist you in
developing and utilizing surveys is,
"Investigating and Evaluating
Environmental Issues and Actions:
Skill Development Modules," by
Harold Hungerford and others.
Stipes Publishing Company, 10-12
Chester Street, Champaign, IL
61820
Procedure:
1. Have the students use the
sample survey or design a new
one to conduct a community
survey on the topic of mercury.
Students are encouraged to add
new questions specially targeted
at their community.
2. Students will identify a target
audience and conduct the survey.
Target audiences could include
homeowners, students, or
teachers.
3. Tabulate and analyze the results
of the survey and prepare a
report. Students should then
identify various action steps they
could take to increase the
knowledge of the target audience
on the subject of mercury.
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Sample Mercury Survey
Hello, my name is . I am a student at
School. I am doing research on mercury in our community. I would like
to ask you several questions about this topic. The survey will take about 10 minutes.
Person Responding: Male Female
Age: <20 20-40 40-60 60+
1. Do you consider mercury dangerous to human health? Yes No
2. In the last year, have you heard or read of any local or national news story that
describes an incident involving mercury? Yes No
3. Do you fish? Yes No
If yes, have you consulted the state fish advisory that describes the warnings for eating
fish from certain bodies of water? Yes No
For each of the following statements, tell me whether you strongly agree, agree,
neutral, disagree, or strongly disagree.
4. All thermometers contain mercury.
Strongly Agree Agree Neutral Disagree Strongly Disagree
5. Mercury should be stored in locked cabinets if it is used at school.
Strongly Agree Agree Neutral Disagree Strongly Disagree
6. Switches and thermostats that contain mercury should be clearly labeled.
Strongly Agree Agree Neutral Disagree Strongly Disagree
Please rate on a scale of 1 (not important) to 5 (very important) the following
statements:
7. Mercury should be banned from use in children's toys.
12345
8. Non-essential uses of mercury should be phased out in our community.
12345
9. Firefighters and emergency personnel should be trained to handle a mercury
spill.
12345
34
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Please answer True or False to the following:
T F 10. Mercury spills in schools have resulted in evacuations
and expensive cleanups.
T F 11. Several different cultures use mercury for ceremonial
or religious purposes.
T F 12. Once mercury gets into your body, it might stay there
for several weeks.
T F 13. The burning of fossil fuels such as coal releases
mercury into the air.
Please answer the following questions:
14. What would you do if you found a jar of mercury in your basement?
15. Do you read and follow the advice given in our state's Fish Consumption Advisory?
Why or Why not?
16. What are the symptoms of mercury poisoning?
17. Circle the household items that might contain mercury.
thermometers kid's maze games
mercurochrome hair shampoo
switches in old washing machines and freezers sphygmomanometers
most plastics some nasal sprays
Thank you.
35
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Mercury In Our World and Community
Now might be the time to take community action. Your class or a group of students
might wish to develop a community action plan. This activity can be done at the
beginning of the project; then you will need to revise the plan based on what the
students learned from the previous activities. Or you might wish to do the plan at the
end of your class mercury activities.
Activity 7- Mercury Community Action Projects
Objective:
Students will develop and
implement an action plan to reduce the
concerns and effects of mercury in their
community.
Materials:
Background materials in this set
of activities.
Background:
Your students will be participating
in the "real world"! Completing a
"Community Action Project" is based on
the following assumptions:
• Society must solve community
environmental issues with
participation from its young
members.
• Students need to know they can be
forces for constructive change.
• Students need the opportunity to
investigate and act upon a problem
of their choice to increase their
motivation to learn.
• The school and its community need
to be connected to show relevance
to the real world. The classroom is
part of the community and the
community is part of the classroom.
The Community Action Project will
provide the students an opportunity to
apply the knowledge they have acquired
about mercury to improve how mercury
is handled in the community. The
students will use skills in research,
investigation, problem-solving and
working in groups.
Procedure
Students can undertake this activity as a
class or in groups. They will brainstorm
a list of recommendations for their
community on mercury reduction. Based
on this list, they will choose one activity
and develop an action plan that will
include the following:
• Identify the problem to be
addressed;
• List methods to address the
problem;
• Select the best action
• Determine the resources needed to
complete the plan;
• Identify possible partners for the
program;
• Develop a time line;
• Implement the project; and
• Evaluate the project and suggest
changes for future efforts.
36
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The class or groups will then implement
their action plan.
The following are some possible
activities that the students can
develop for action plans:
Organize a community outreach
program about mercury; for example,
create a display and handout(s)
about mercury and take them to
various public venues.
Discuss mercury spill prevention and
cleanup with school janitorial staff,
local fire department and/or Hazmat
(hazardous materials) Team.
Promote a mercury or household
hazardous waste collection program
in your community.
Design and print labels for
equipment that contains mercury and
work with school janitorial staff,
nursing homes and/or others to
place these on mercury thermostats
and other equipment;
Check store inventories and work
with store owners to ensure that no
mercury-containing games (e.g.
maze games or toys) are being sold
to small children.
"Adopt" a hospital or nursing home
and work with them to minimize their
use of mercury and safely recycle
their existing mercury.
Work with your electric utility to
promote a mercury thermostat
recycling program.
Perform mercury school audits for
grade schools and middle schools in
your school district.
Determine if there are any rules
pertaining to mercury in your
community or state, and, if not, start
a campaign to establish rules.
Investigate what popular stores in
your community or state are doing
about the sale of items containing
mercury.
Other ideas from the students
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