2001 Toxics Release Inventory (TRI) Public Data Release Summary ------- Public Access to the Toxics Release Inventory (TRI) TRI Data Products Data Product Point of Access Contact Information 2001 TRI Executive Summary (reference EPA 260-S-03-001) 2001 TRI Public Data Release Report (reference EPA 260-R-03-001) 2001 State Fact Sheets (reference EPA 260-F-03-002) U.S. Environmental Protection Agency ATTN: TRI Documents MC 2844T (EPA West, 5th Floor) 1200 Pennsylvania Ave., N.W. Washington, D.C. 20460 (202) 564-9554 E-mail: tridocs@epa.gov U.S. EPA Toxics Release Inventory (TRI) Website — 2001 Data Release http://www.epa.gov/tri/tridata/tri01 2001 State Data Files in ASCII Delimited format U.S. EPA Toxics Release Inventory (TRI) Website http://www.epa.gov/tri/tridata/tri01 Chemicals in Your Community (reference EPA 550-K-99-001) U.S. EPA's National Service Center for Environmental Publications (NSCEP) (800) 490-9198 (513)489-8190 FAX: (513) 489-8695 order online: http://www.epa.gov/ncepihom TRI Online Access Online Provider of TRI Data Internet Access Address TRI Explorer provides fast and easy access to the TRI data via U.S. EPA's latest TRI tool http ://www. epa.gov/triexplorer U.S. EPA's TRI Program Homepage and 2001 data release page http ://w ww. epa. gov/tri http://www.epa.gov/tri/tridata/triO 1 U.S. EPA's Envirofacts provides access to TRI data via U.S. EPA's Envirofacts Data Warehouse Query Engine http://www.epa.gov/enviro/html/toxic_releases.html Right-to-Know Network, operated by two nonprofit organizations (OMB Watch and the Center for Public Data Access), provides free access to TRI Data http ://www.rtknet. org TOXNET® the National Library of Medicine's (NLM) Toxicology Data Network, provides free access to TRI data http://toxnet.nlm.nih.gov/ ------- EPA 260-S-03-001 July 2003 2001 Toxics Release Inventory Executive Summary U.S. Environmental Protection Agency Office of Environmental Information (281OA) Washington, D.C. 20460 Also available from: www.epa.gov/tri/tridata/tri01 ------- 2001 Toxics Release Inventory Executive Summary ------- 2001 Toxics Release Inventory Executive Summary BACKGROUND The Toxics Release Inventory (TRI) is a publicly available database that contains information on toxic chemical releases and other waste management activities reported annually by certain covered industries as well as by federal facilities. This inventory was established under the Emergency Planning and Community Right-to- Know Act of 1986 (EPCRA). In 1990 the information required to be reported to TRI was expanded by the Pollution Prevention Act. There are now nearly 650 toxic chemicals and toxic chemical categories on the list of chemicals that must be reported to EPA and the States under the EPCRA/TRI Program. A facility must report to TRI if it meets the following three criteria: • Is in the manufacturing sector or, beginning in the 1998 reporting year, is one of the following industry categories: metal mining, coal mining, electrical utilities, chemical wholesale distributors, petroleum terminals and bulk storage facilities, Resource Conservation and Recovery Act (RCRA) subtitle C hazardous waste treatment and disposal facilities, and solvent recovery services. Also, federal facilities must report to TRI regardless of their industrial classification; • Has 10 or more full-time employee equivalents, and • For all but certain persistent bioaccumulative toxic (PBT) chemicals, manufactures or processes more than 25,000 pounds or otherwise uses more than 10,000 pounds of any listed chemical during the calendar year. 'Two of the chemicals were added to the Polycyclic Aromatic Compounds category. For the 2000 reporting year, the last criterion was changed for certain PBT chemicals. TRI was expanded to include new PBT chemicals and reporting thresholds were lowered for both the newly-added PBT chemicals and certain PBT chemicals already on the TRI list. In a rule (64 FR 58666) finalized on October 29, 1999, EPA added six PBT chemicals and one PBT chemical category.1 PBT chemicals persist and bioaccumulate in the environment and they have the potential to pose greater exposure to humans and the environment over a longer period of time, making even small quantities of these chemicals of concern. Therefore, EPA established thresholds lower than the 25,000 pounds and 10,000 pounds. For those chemicals that are persistent and bioaccumulate, a threshold of 100 pounds manufactured, processed or otherwise used was established. For the subset of PBT chemicals that are highly persistent and highly bioaccumulative, a threshold of 10 pounds was established. In addition, because dioxins are highly persistent and highly bioaccumulative, but are generally produced in extremely small amounts, the threshold for dioxin and dioxin-like compounds was set at 0.1 gram. Reporting thresholds for lead and lead compounds were lowered in a separate PBT chemical rule (66 FR 4500) finalized on January 17, 2001. The lower reporting threshold and requirements for lead and lead compounds became effective for the 2001 reporting year and apply to all lead and lead compounds except for lead when it is contained in stainless steel, brass, or bronze alloys. 2001 DATA RELEASE The time period covered for the 2001 data release is the reporting year 2001. A reporting year is the 2001 Toxics Release Inventory Public Data Release ES-1 ------- 2001 Toxics Release Inventory Executive Summary same as a calendar year. The 2001 data were submitted to EPA by July 1, 2002 and are the focus of this report. The Public Data Release report is an analysis of the 2001 TRI data and trends in the data from 1988 to 2001. For the 2000 reporting year, certain PBT chemicals (see above) were added to the list of TRI chemicals. Also, in October 1999, EPA added vanadium compounds to the TRI list and changed the reporting qualifier for vanadium (already on the list of TRI chemicals) from "fume or dust" to "except when contained in an alloy." Vanadium and vanadium compounds have not been classified as PBT chemicals. For the 2001 reporting year, the thresholds for lead and lead compounds (except for lead when it is contained in stainless steel, brass, or bronze alloys) were lowered to 100 pounds. The 1998-2001 data include reporting by the manufacturing industries, metal mining, coal mining, electrical utilities, hazardous waste treatment and disposal facilities, solvent recovery facilities, chemical wholesale distributors, and petroleum bulk stations and terminals. The manufacturing sector has been reporting since 1987, federal facilities have been reporting since 1994, and the other industry sectors have been reporting since 1998. Analyses for this period also include only those chemicals reportable since 1998 with the same reporting threshold and same definition. The analysis of trends in the TRI data from 1988 to 2001 includes only the manufacturing industries and those listed chemicals that have been reportable since 1988 with the same reporting threshold and same definition. Year-to-year comparisons are based on a consistent set of chemicals and reporting industries to assure that any changes in releases or other waste management data do not simply reflect changes in reporting requirements from year to year. Thus, comparisons of 2001 data with prior years do not include persistent bioaccumulative toxic chemicals subject to the October 1999 PBT chemical rule and the January 2001 lead rule, or vanadium and Figure ES-1: Distribution of TRI On-site and Off-site Releases, 2001 Transfers Off-site to Disposal 9.4% Air Emissions 27.3% Other On-site Lan> Releases 54.0% On-site RCRA Subtitle C Landfills 2.2% Surface Water r Discharges 3.6% UIJ, Class I Wells ~~~~ 3.1% \ UIJ, Class II-V Wells 0.4% Note: On-site Releases are from Section 5 of Form R Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. UIJ = Underground injection vanadium compounds since reporting thresholds or reporting definitions for these chemicals have changed. On-site and Off-site Releases, 2001 In 2001, 24,896 facilities submitted 95,513 forms. On- and off-site releases for all TRI facilities totaled 6.16 billion pounds for 2001. (See Table ES- 1 and Figure ES-1.) On-site releases totaled 5.58 billion pounds or 91 percent of total releases on- and off-site in 2001. The largest type of on-site releases was on-site land releases, totaling 3.46 billion pounds or 56 percent of total releases on- and off-site. As shown in Table ES-1, the largest type of on-site land releases was other disposal (that is, on-site land releases other than to landfills, land treatment, and surface impoundments, and may include releases to waste piles or from spills or leaks). Other disposal totaled 2.04 billion pounds or 33 percent of total releases in 2001. On-site air emissions, the second largest type of release, were 1.68 billion pounds or 27 percent of total releases. On-site surface water discharges were 220.8 million pounds and accounted for almost 4 percent of total releases. On-site releases to ES-2 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-1: TRI On-site and Off-site Releases, 2001 Total Facilities Total Forms Form Rs Form As On-site Releases Total Air Emissions Fugitive Air Emissions Point Source Air Emissions Surface Water Discharges Underground Injection Class 1 Wells Class II-V Wells On-site Land Releases RCRA Subtitle C Landfills Other On-site Landfills Land Treatment Surface Impoundments Other Disposal Total On-site Releases Off-site Releases Storage Only* Solidification/Stabilization** Metals and Metal Category Compounds Only Wastewater Treatment (Excluding POTWs)*** Metals and Metal Category Compounds Only Transfers to POTWs**** Metals and Metal Category Compounds Only Underground Injection Landfills/Surface Impoundments Land Treatment Other Land Disposal Other Off-site Management Transfers to Waste Broker for Disposal Unknown***** Total Off-site Releases (Transfers Off-site to Disposal) Total On- and Off-site Releases Number 24,896 95,513 83,218 12,295 Pounds 1 ,679,373,058 240,558,980 1,438,814,078 220,796,115 215,424,286 193,436,563 21,987,723 3,464,680,533 138,220,131 308,599,626 14,122,290 965,279,810 2,038,458,676 5.580.273.993 Percent of Total - 100.0 87.1 12.9 Percent of Total 27.3 3.9 23.4 3.6 3.5 3.1 0.4 56.3 2.2 5.0 0.2 15.7 33.1 90.6 6,121,927 123,464,082 3,768,614 2,211,172 16,137,684 364,712,642 7,263,730 22,291,065 15,606,659 12,016,593 4,128,918 577,723,085 6,157,997,078 0.1 2.0 0.1 0.04 0.3 5.9 0.1 0.4 0.3 0.2 0.1 9.4 100.0 Note: On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. * Storage only (disposal code M10) indicates that the toxic chemical is sent off-site for storage because there is no known disposal method. Amounts reported as transferred to storage only are included as a form of disposal (off-site release). See Box 1-5. ** Beginning in reporting year 1997, transfers to solidification/stabilization of metals and metal category compounds (waste treatment code M41) are reported separately from transfers to solidification/stabilization of non-metal TRI chemicals (waste treatment code M40). Because this treatment method prepares a metal for disposal, but does not destroy it, such transfers are included as a form of disposal (off-site release). See Box 1-6. Reports under code M40 of metals and metal category compounds have been included in solidification/stabilization of metals and metal category compounds in this report. *** Beginning in reporting year 1997, transfers to wastewater treatment (excluding POTWs) of metals and metal category compounds (waste treatment code M61) are reported separately from transfers to wastewater treatment of non-metal TRI chemicals (waste treatment code M60). Because wastewater treatment does not destroy metals, such transfers are included as a form of disposal (off-site release). See Box 1-6. Transfers of metals and metal category compounds reported under code M60 have been included in transfers of metals and metal category compounds to wastewater treatment. **** Reported as discharges to POTWs in Section 6.1 of Form R. EPA considers transfers of metals and metal category compounds to POTWs as an off-site release because sewage treatment does not destroy the metal content of the waste material. ***** Unknown (disposal code M99) indicates that a facility is not aware of the type of waste management used for the toxic chemical that is sent off-site. Amounts reported as unknown transfers are treated as a form of disposal (off-site release). 2001 Toxics Release Inventory Public Data Release ES-3 ------- 2001 Toxics Release Inventory Executive Summary Table ES-2: TRI On-site and Off-site Releases by State, 2001 Total State Facilities Number Alabama 566 Alaska 32 American Samoa 2 Arizona 275 Arkansas 385 California 1,612 Colorado 231 Connecticut 385 Delaware 79 District of Columbia 8 Florida 702 Georgia 795 Guam 8 Hawaii 38 Idaho 92 Illinois 1,376 Indiana 1,101 Iowa 433 Kansas 302 Kentucky 494 -ouisiana 382 Maine 118 Maryland 211 Massachusetts 654 Michigan 939 Minnesota 505 Mississippi 356 Missouri 619 Montana 49 Nebraska 185 Nevada 103 Mew Hampshire 156 New Jersey 604 New Mexico 80 New York 775 North Carolina 914 North Dakota 47 Morthern Marianas 3 Ohio 1,725 Oklahoma 343 Oregon 307 Pennsylvania 1,436 Puerto Rico 161 Rhode Island 160 South Carolina 561 South Dakota 91 Tennessee 692 Texas 1,556 Utah 179 Vermont 47 Virgin Islands 5 Virginia 507 Washington 347 West Virginia 188 Wisconsin 931 Wyoming 44 Total 24,896 Surface Total Air Water Emissions Discharges Pounds Pounds 75,567,809 4,713,394 3,201,013 76,438 6,920 0 4,600,105 6,376 20,036,562 3,190,528 20,020,008 4,924,819 3,629,554 3,752,564 4,821,957 785,064 6,651,525 573,937 40,733 13,943 83,429,911 1,590,342 91,834,154 8,391,937 192,898 17 2,379,957 29,770 5,000,464 5,821,110 59,411,352 8,087,041 77,828,675 20,104,003 24,332,303 3,145,360 14,768,804 1,149,296 58,703,794 2,118,567 75,960,815 11,908,380 4,657,404 3,975,970 36,076,213 3,839,690 7,447,906 73,437 56,656,492 1,043,401 14,252,131 1,571,683 37,063,726 12,964,677 34,177,643 1,660,217 4,292,997 48,785 7,875,435 9,601,101 2,728,933 82,849 4,496,284 10,675 13,809,784 3,729,623 1,072,357 40,023 29,629,649 6,733,053 115,130,332 9,887,436 4,328,230 110,470 7,953 0 121,295,468 8,339,219 17,377,943 2,391,127 12,914,088 2,912,278 89,034,059 18,741,435 14,556,276 35,624 824,582 10,171 54,977,393 2,778,925 1,799,135 2,413,621 79,573,558 3,067,358 102,748,862 26,007,896 19,220,667 1,215,070 136,536 75,573 892,660 132,256 57,216,768 6,963,083 14,295,076 2,123,223 59,430,131 3,788,537 25,139,472 4,033,349 1,817,602 11,395 1,679,373,058 220,796,115 On-site Releases Underground Injection Class I Class II-V Wells Wells Pounds Pounds 0 92,912 0 20,554,878 0 0 0 0 1,492,971 93,263 0 55,902 0 0 0 0 0 0 0 0 23,796,396 709 0 0 0 0 5 2,066 0 0 327 2,172 1,074,584 140 0 0 558,721 500 0 54,425 37,112,860 0 0 0 0 56,057 0 0 2,509,470 100 0 0 11,046,901 0 0 0 0 369,092 0 0 0 785 0 0 0 6 37,389 0 1 0 0 0 0 0 0 0 31,993,954 0 4,828 0 0 0 0 0 0 0 0 0 0 0 0 704,700 0 5 77,648,758 0 0 0 0 0 0 0 0 5 0 6 14,397 0 0 0 6,145,000 0 193,436,563 21,987,723 On-site Land Releases RCRA Other On- Subtitle C site Land Landfills Releases Pounds Pounds 7,161,905 34,615,126 0 498,234,331 0 0 4,886 601,481,177 227,275 6,416,583 23,436,456 4,644,856 41,889 24,026,000 0 2,462 0 965,666 0 4,927 1,236,511 8,368,063 17,986 13,615,623 26 5,519 0 224,400 33,341,745 29,655,656 24,623,694 20,127,859 163,777 29,918,043 17,600 5,504,922 0 8,381,934 1,609 21,102,560 3,737,937 11,909,258 0 725,873 0 2,806,914 935 825,302 12,843,205 9,419,827 250 9,696,375 176,756 7,943,087 67,560 76,783,159 2,395 58,030,810 0 6,383,985 3,988,273 774,255,862 0 10,088 159,935 154,682 0 102,121,661 7,677 3,398,501 765 12,415,324 0 12,303,643 0 2 12,953,608 22,897,310 2,518,028 2,976,818 3,999,477 16,602,446 339,536 11,188,248 250 13,664 250 108 16,281 5,300,147 12,380 8,520,378 341,993 58,960,603 1,454,403 28,396,993 5,266,999 740,512,297 178 255 0 7,283 1,076 6,434,629 6,109 5,096,793 5,484 11,485,102 43,034 2,871,611 0 8,715,656 138,220,131 3,326,460,403 Total On-site Releases Pounds 122,151,146 522,066,660 6,920 606,092,545 31,457,181 53,082,041 31,450,008 5,609,483 8,191,129 59,603 118,421,931 113,859,700 198,460 2,636,198 73,818,976 112,252,445 129,089,222 33,000,185 24,859,255 81,980,954 140,629,250 9,359,246 42,778,874 8,347,581 82,472,496 25,520,439 69,195,147 112,688,579 62,744,079 23,860,521 781,056,702 4,517,047 17,854,029 103,271,430 39,768,882 137,433,858 16,742,343 7,955 197,479,559 25,268,743 36,428,289 119,303,278 14,605,814 835,111 63,072,746 13,450,214 141,943,517 236,256,913 766,215,034 212,542 1,032,199 70,615,561 21,521,207 74,723,651 32,087,466 16,689,653 5,580,273,993 Off -site Releases Transfers Off -site to Disposal Pounds 12,294,431 6,071 0 721,776 12,585,384 5,467,403 5,596,405 4,145,809 3,883,235 970 4,780,008 2,659,943 23 430,339 1,362,893 25,496,565 76,468,560 4,873,295 6,807,335 11,714,700 5,191,651 1,353,438 2,645,338 2,738,148 49,444,297 7,874,871 1,891,154 7,201,119 2,644,099 2,808,896 2,437,928 241,606 40,987,748 2,561,720 5,062,168 10,234,240 8,534,710 0 57,084,073 3,618,278 1,148,229 88,180,766 1,000,785 262,989 18,188,165 77,038 7,017,705 34,278,163 982,691 150,460 6,419 9,168,292 2,371,067 5,416,357 14,721,061 902,273 577,723,085 Total On- and Off-site Releases Pounds Rank 134,445,577 13 522,072,731 4 6,920 56 606,814,321 3 44,042,566 31 58,549,443 27 37,046,413 34 9,755,293 47 12,074,363 44 60,573 54 123,201,939 15 116,519,643 17 198,483 53 3,066,537 49 75,181,868 23 137,749,010 12 205,557,782 8 37,873,480 32 31,666,590 36 93,695,654 19 145,820,901 11 10,712,685 46 45,424,212 29 11,085,729 45 131,916,793 14 33,395,310 35 71,086,301 24 119,889,698 16 65,388,178 25 26,669,417 38 783,494,630 1 4,758,653 48 58,841,777 26 105,833,149 18 44,831,050 30 147,668,098 10 25,277,053 39 7,955 55 254,563,632 6 28,887,021 37 37,576,517 33 207,484,044 7 15,606,599 42 1,098,100 50 81,260,912 20 13,527,252 43 148,961,221 9 270,535,075 5 767,197,725 2 363,002 52 1,038,618 51 79,783,853 22 23,892,274 40 80,140,007 21 46,808,527 28 17,591,926 41 6,157,997,078 Note: On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI Facilities that reported the amount as an on-site release. ES-4 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary underground injection wells totaled 215.4 million pounds or 3.5 percent of total releases in 2001. Releases also include transfers of TRI chemicals in waste sent off-site for disposal to such sites as landfills and underground injection wells. Off-site releases (transfers off-site to disposal) were 577.7 million pounds or 9 percent of all releases in 2001. Of these off-site releases 364.7 million pounds of chemicals were sent off-site to landfills/surface impoundments and 123.5 million pounds of metals and metal category compounds were sent for solidification/stabilization. On- and Off-site Releases by State Nevada, followed by Utah, Arizona, and Alaska, were the four states with the largest total on- and off-site releases. They each reported more than 500 million pounds in total releases for 2001. (See Table ES-2.) Facilities in Nevada reported total releases of 783.5 million pounds and those in Utah reported 767.2 million pounds. Nevada and Utah each accounted for about 13 percent of all releases on- and off-site in 2001. Arizona had 606.8 million pounds of releases on- and off-site or 10 percent of the total and Alaska had 522.1 million pounds, or 8.5 percent of the total for 2001. These four states each had more than 95 percent of their total releases as other on-site releases (that is, on-site land releases to other than RCRA subtitle C landfills). Texas had the fifth largest total releases on- and off- site in 2001, with 270.5 million pounds or 4 percent of total releases. Facilities in Texas reported the largest on-site underground injection, with 77.6 million pounds or 40 percent of total on-site underground injection in 2001, all of which went to Class I wells. Texas also reported the largest surface water discharges, with 26.0 million pounds or 12 percent of all such releases in 2001. Ohio had the sixth largest total releases on- and off- site, with 254.6 million pounds or 4 percent of the total. Facilities in Ohio reported the largest air emissions, with 121.3 million pounds or 7 percent of all on-site air emissions in 2001. North Carolina facilities reported the second largest air emissions, with 115.1 million pounds or about 7 percent of total air emissions. After Ohio, Pennsylvania had the next largest total releases on- and off-site (207.5 million pounds or 3 percent of the total). Facilities in Pennsylvania reported the largest off-site releases (transfers off- site to disposal) in 2001, with 88.2 million pounds or 15 percent of total off-site releases in 2001. On- and Off-site Releases by Industry The metal mining industry reported the largest total releases on- and off-site in 2001. The 2.78 billion pounds of total releases in 2001 reported by metal mining facilities accounted for 45 percent of all releases on- and off-site in 2001. Most (over 99 percent) releases by the metal mining industry were as other on-site land releases (that is, on-site land releases to other than RCRA subtitle C landfills). The 2.76 billion pounds of other on-site land releases reported by the metal mining industry in 2001 represented 83 percent of all such releases. (See Table ES-3.) Electric utilities reported the second largest releases on- and off-site in 2001, with 1.06 billion pounds or 17 percent of total releases. Over two-thirds of releases by electric utilities were air emissions. The 717.6 million pounds of air releases from electric utilities accounted for 43 percent of all air emissions reported in 2001. Electric utilities reported 266.7 million pounds of other on-site land releases (other than to RCRA subtitle C landfills), which made it the industry sector with the second largest amount of such releases. The chemical manufacturing industry reported 582.6 million pounds of releases on- and off-site in 2001, making it the industry sector with the third largest releases. Total releases by the chemicals industry accounted for 9.5 percent of total releases from all sectors in 2001. Chemical manufacturers reported the largest amount of on-site underground injection, with 168.0 million pounds or 78 percent of all such releases. 2001 Toxics Release Inventory Public Data Release ES-5 ------- 2001 Toxics Release Inventory Executive Summary Table ES-3: TRI On-site and Off-site Releases by Industry, 2001 SIC Code Industry 10 Metal Mining 12 Coal Mining 20 Food 21 Tobacco 22 Textiles 23 Apparel 24 Lumber 25 Furniture 26 Paper 27 Printing 28 Chemicals 29 Petroleum 30 Plastics 31 Leather 32 Stone/Clay/Glass 33 Primary Metals 34 Fabricated Metals 35 Machinery 36 Electrical Equip. 37 Transportation Equip. 38 MeasureVPhoto. 39 Miscellaneous - Multiple codes 20-39 - No codes 20-39 491/493 Electric Utilities 5169 Chemical Wholesale Distributors 5171 Petroleum Bulk Terminals/Bulk Sorage 7389/4953 Hazardous Waste/Solvent Recovery Total Total Total Facilities Forms Number Number 89 658 88 348 1,688 3,611 31 67 289 671 16 41 1,006 2,499 282 632 507 3,128 231 478 3,618 20,355 542 4,299 1,822 3,909 60 149 1,027 2,800 1,941 7,445 2,959 8,089 1,143 2,881 1,831 3,883 1,348 4,872 375 749 312 683 1,317 4,869 348 887 732 6,634 475 3,335 596 4,779 223 2,762 24,896 95,513 On-site Releases Surface Total Air Water Emissions Discharges Pounds Pounds 2,854,512 427,312 768,762 760,047 56,136,054 55,154,841 2,491,746 532,888 5,740,423 175,447 343,274 5 30,478,706 19,931 7,823,922 557 157,150,488 16,536,395 19,290,560 305 227,840,792 57,577,475 48,169,295 17,091,882 77,101,109 71,092 1,207,544 124,727 31,265,083 162,077 57,612,307 44,670,397 40,447,264 1,743,317 8,279,835 18,063 12,721,139 2,936,994 66,691,884 198,256 7,166,923 1,424,454 6,764,766 36,566 66,687,839 16,511,697 3,369,277 1,065,165 717,575,860 3,519,693 1,254,310 1,856 21,164,969 11,177 974,414 23,498 1,679,373,058 220,796,115 Underground Injection Class I Class II-V Wells Wells Pounds Pounds 0 21,629,444 14,387 149,109 56,231 677 0 0 0 0 0 0 0 0 0 0 0 0 0 0 167,868,820 95,407 1,973,515 56,363 0 0 0 0 0 54,431 842,853 5 1 2,172 0 0 0 0 750 0 0 0 0 0 1,723 10 0 0 0 4 5 0 0 100 22,678,278 0 193,436,563 21,987,723 On-site Land Releases RCRA Subtitle Other On-site C Landfills Land Releases Pounds Pounds 0 2,757,118,053 0 14,414,576 254 7,553,308 0 215,914 0 295,953 0 85 4,092 394,721 0 32 31,330 16,168,805 0 4,531 1,174,731 46,748,593 41 780,800 72,149 841,059 0 8,596 37,180 3,863,435 5,736,662 177,961,804 110,340 511,183 56,873 2,394,310 19,017 681,803 45,805 727,692 301 13,009 14,102 1,865 263,125 5,360,924 3,884 8,204,785 1 ,383,707 266,699,366 5 1 ,074 26 11,215 129,266,508 15,482,910 138,220,131 3,326,460,403 Total On-site Releases Pounds 2,782,029,322 16,106,880 118,901,365 3,240,548 6,211,823 343,364 30,897,450 7,824,511 189,887,018 19,295,396 501,305,818 68,071,896 78,085,410 1,340,867 35,382,207 286,824,028 42,814,277 10,749,081 16,358,954 67,664,387 8,604,688 6,817,299 88,825,318 12,643,111 989,178,631 1,257,250 21,187,488 168,425,606 5,580,273,993 Off-site Releases Transfers Off-site to Disposal Pounds 524,935 10,830 6,161,820 322,970 749,261 57,862 518,539 184,300 5,767,146 424,007 81,278,999 3,312,421 10,450,023 1,273,813 5,078,467 271,764,651 21,204,117 4,610,570 7,575,105 12,965,556 770,558 1,616,458 15,100,990 1,120,451 73,068,649 211,020 153,163 51,446,405 577,723,085 Total Total On- and Off-site Releases Pounds 2,782,554,257 16,117,710 125,063,185 3,563,517 6,961,084 401,226 31,415,989 8,008,810 195,654,165 19,719,402 582,584,818 71,384,317 88,535,433 2,614,681 40,460,674 558,588,679 64,018,394 15,359,651 23,934,059 80,629,943 9,375,245 8,433,757 103,926,308 13,763,561 1,062,247,281 1 ,468,270 21,340,651 219,872,011 6,157,997,078 Note: On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. Facilities/forms are included in the manufacturing industry categories (SIC Codes 20-39) if they did not report a SIC code in the other industries. Forms that reported more than one 2-digit SIC code within the range 20 to 39 are assigned to the "multiple codes" category. Facilities/forms are included in the other industry categories if the facility/form has a SIC code in the other industries and no SIC code in 20-39. If the facility reported in any year prior to 1998 and the facility/form has a combination of manufacturing and other industry SIC codes, then the facility/form is included in the manufacturing industry category. If the facility reported for the first time in 1998 or later and the facility/form has a combination of manufacturing and other industry SIC codes, then the facility/form is included in the other industry category. Forms with no 2-digit SIC code are included in the "no codes 20-39" category. One facility, Phelps Dodge Miami of Claypool, AZ, that reported under SIC code 33 and SIC code 10 in 2001 and previous years has been included in SIC code 10 for the purpose of this analysis. ES-6 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-4: Top 20 Chemicals with the Largest Total Releases, 2001 CAS Number Chemical -- Copper compounds -- Zinc compounds 7647-01-0 Hydrochloric acid -- Lead compounds -- Manganese compounds -- Arsenic compounds - Nitrate compounds -- Barium compounds 67-56-1 Methanol 7664-41-7 Ammonia 7664-93-9 Sulfuric acid -- Chromium compounds -- Vanadium compounds 108-88-3 Toluene 7664-39-3 Hydrogen fluoride -- Nickel compounds 7439-96-5 Manganese 100-42-5 Styrene 1330-20-7 Xylene (mixed isomers) 110-54-3 n-Hexane Subtotal (top 20 chemicals) Total (all chemicals) On-slte Releases Surface Total Air Water Emissions Discharges Pounds Pounds 1,416,114 418,663 6,159,692 2,172,966 587,134,079 2,445 1,254,381 362,122 1,877,226 6,236,782 177,832 141,172 515,899 192,795,905 2,163,853 1,475,918 175,844,606 3,380,299 122,057,546 6,621,166 146,397,844 694 671,106 178,352 1,399,953 639,856 71,539,704 75,909 67,248,474 21,549 1,004,693 244,846 904,434 165,392 46,466,141 2,993 47,081,406 21,972 47,644,345 10,531 1,328,959,329 214,969,533 1,679,373,058 220,796,115 Underground Injection Class I Class II-V Wells Wells Pounds Pounds 176,425 717,758 537,865 9,119,066 46,398 2,172 206,138 6,026,677 11,316,486 1,165,027 65,713 1,466,028 36,865,869 1,643 15,514 1,965,433 13,377,821 80,001 22,930,936 43,301 679,045 0 2,188,916 51,250 882,575 0 264,765 365 4,400,000 0 710,080 270,609 0 0 394,001 0 80,521 550 69,663 0 95,208,731 20,909,880 193,436,563 21,987,723 On-site Land Releases RCRA Other On- Subtitle C site Land Landfills Releases Pounds Pounds 4,123,867 994,136,994 19,080,399 719,530,209 0 188,608 5,986,663 358,128,545 3,562,861 328,138,941 3,130,653 373,104,273 87,500 13,419,054 2,351,397 198,668,435 97,719 1,354,297 15,065 3,605,984 66,810 481,965 2,676,859 94,041,777 51,005 78,884,807 82,903 44,754 30,407 249,168 5,600,859 45,383,246 3,796,840 12,535,661 106,595 58,625 133,072 44,222 343 9,600 50,981,817 3,222,009,165 138,220,131 3,326,460,403 Total On-site Releases Pounds 1,000,989,821 756,600,197 587,373,702 371,964,527 352,297,323 378,085,671 243,685,870 206,640,550 194,134,743 155,273,998 147,626,358 99,808,260 81,858,196 72,008,400 71,949,598 53,214,334 17,402,327 47,028,355 47,361,743 47,734,482 4,933,038,455 5,580,273,993 Off-site Releases Transfers Off-site to Disposal Pounds 17,096,211 205,468,291 746,442 50,213,158 47,995,623 3,000,912 14,174,527 45,504,419 2,829,290 3,247,048 129,606 16,725,832 6,641,947 1,780,473 136,470 13,753,100 31,582,035 1,953,117 1,158,921 427,958 464,565,380 577,723,085 Total On- and Off-site Releases Pounds 1,018,086,032 962,068,488 588,120,144 422,177,685 400,292,945 381,086,583 257,860,397 252,144,968 196,964,033 158,521,046 147,755,964 116,534,092 88,500,143 73,788,873 72,086,068 66,967,433 48,984,362 48,981,473 48,520,664 48,162,440 5,397,603,835 6,157,997,078 Note: On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. The primary metals industry reported the fourth largest releases on- and off-site, with 558.6 million pounds or 9 percent of total releases in 2001. The primary metals industry had the largest off-site releases (transfers off-site to disposal) of any industry, with 271.8 million pounds accounting for 47 percent of all off-site releases in 2001. On- and Off-site Releases by Chemical Table ES-4 lists the 20 TRI chemicals with the largest total releases in 2001. On- and off-site releases of the top 20 TRI chemicals totaled 5.40 billion pounds, 88 percent of the total 6.16 billion pounds of all TRI chemicals released on- and off- site. Total on-site releases for these 20 TRI chemicals totaled 4.93 billion pounds, representing 88 percent of all on-site releases. Off-site releases (transfers off-site to disposal) constituted 464.6 million pounds or 80 percent of all off-site releases in 2001. Of the 5.40 billion pounds of total releases of the top 20 TRI chemicals, 3.22 billion pounds or 60 percent were as other on-site land releases (that is, on-site land releases to other than RCRA subtitle C landfills). Another 25 percent (1.33 billion pounds) were on-site air emissions. The distribution of releases for the top 20 TRI chemicals differed somewhat from that for all TRI chemicals, where 54 percent of total releases were other on-site land releases and 27 percent were on-site air emissions. Copper compounds constituted 17 percent (1.02 billion pounds) of the 6.16 billion pounds of total on- and off-site releases for all TRI chemicals in 2001. Zinc compounds accounted for the second largest releases, with 962.1 million pounds or 16 percent. Hydrochloric acid was the third-most common chemical, constituting 10 percent (588.1 million pounds). Most of the releases of copper and zinc compounds were as other on-site land releases (that is, other than RCRA subtitle C landfills) while most releases of hydrochloric acid were on-site air emissions. 2001 Toxics Release Inventory Public Data Release ES-7 ------- 2001 Toxics Release Inventory Executive Summary Table ES-5: TRI On-site and Off-site Releases, PBT Chemicals, 2001 CAS Total Number Chemical Forms Number Dioxin and dioxin-like compounds* 1,320 - Dioxin and dioxin-like compounds (in grams)* 1,320 Lead and Lead Compounds 8,561 7439-92-1 Lead 4,201 - Lead compounds 4,360 Mercury and Mercury Compounds 1,665 7439-97-6 Mercury 537 - Mercury compounds 1,128 Polycyclic Aromatic Compounds 3,813 191-24-2 Benzo(g,h,i)perylene 1,509 - Polycyclic aromatic compounds 2,304 1336-36-3 Polychlorinated biphenyls (PCBs) 137 Pesticides 130 309-00-2 Aldrin 8 57-74-9 Chlordane 20 76-44-8 Heptachlor 15 465-73-6 Isodrin 5 72-43-5 Methoxychlor 15 40487-42-1 Pendimethalin 18 8001-35-2 Toxaphene 18 1582-09-8 Trifluralin 31 Other PBTs 168 118-74-1 Hexachlorobenzene 99 29082-74-4 Octachlorostyrene 4 608-93-5 Pentachlorobenzene 17 79-94-7 Tetrabromobisphenol A 48 Total 15,794 On-site Releases Surface Total Air Water Emissions Discharges Pounds Pounds 6.37 4.08 2,887.566 1,850.869 1,633,121.66 413,419.80 378,740.71 51,297.37 1,254,380.94 362,122.44 150,462.84 1,805.15 24,698.08 341.73 125,764.77 1,463.42 1,177,581.28 17,069.76 31,455.26 685.17 1,146,126.02 16,384.58 1,359.90 2.80 6,559.55 282.29 0.31 0.00 15.49 80.00 6.04 0.00 0.35 0.00 25.19 0.00 3,573.66 195.00 42.34 6.29 2,896.17 1.00 55,273.40 463.43 1,199.39 321.61 0.00 0.12 69.10 132.70 54,004.91 9.00 3,024,365.00 433,047.31 Underground Injection Class I Class II-V Wells Wells Pounds Pounds 0.14 0.19 63.881 84.270 206,138.00 6,026,683.34 0.00 6.65 206,138.00 6,026,676.69 1,741.11 8,035.04 460.40 0.00 1,280.71 8,035.04 2.10 332.95 1.00 1.65 1.10 331.30 0.00 0.00 115.14 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.14 0.00 115.00 0.00 23.48 0.02 22.00 0.02 0.00 0.00 1.48 0.00 0.00 0.00 208,019.97 6,035,051.53 On-site Land Releases RCRA Other On- Subtitle C site Land Landfills Releases Pounds Pounds 21.97 94.39 9,963.843 42,807.558 18,610,199.14 360,809,675.39 12,623,535.98 2,681,130.01 5,986,663.17 358,128,545.38 60,008.84 4,455,980.78 19,861.63 11,899.27 40,147.21 4,444,081.51 97,094.05 71,292.51 3,716.71 4,852.90 93,377.34 66,439.62 2,265,476.30 225,685.85 15,182.57 38,277.70 0.00 0.00 3,630.30 0.00 271.69 0.00 19.00 0.00 334.69 0.00 185.00 28,832.00 3,073.89 0.00 7,668.00 9,445.70 19,006.97 203,735.50 18,586.97 4,937.60 0.00 193.00 420.00 1,929.90 0.00 196,675.00 21,066,989.83 365,804,742.12 Total On-site Releases Pounds 127.14 57,657.988 387,699,237.33 15,734,710.71 371,964,526.62 4,678,033.75 57,261.10 4,620,772.66 1,363,372.65 40,712.69 1,322,659.96 2,492,524.85 60,417.25 0.31 3,725.79 277.73 19.35 359.88 32,785.66 3,122.66 20,125.87 278,502.80 25,067.59 193.12 2,553.18 250,688.91 396,572,215.77 Off-site Releases Transfers Off-site to Disposal Pounds 200.88 91, 100.805 55,292,470.94 5,079,312.56 50,213,158.38 228,282.95 76,715.67 151,567.27 1,622,784.90 86,240.63 1,536,544.27 12,251.02 50,845.10 1.07 331.61 28.24 441.40 95.93 46,702.21 854.53 2,390.11 637,304.07 11,107.40 508.60 206.32 625,481.75 57,844,139.84 Total On- and Off -site Releases Pounds- 328.01 148,758.793 442,991,708.27 20,814,023.27 422,177,685.00 4,906,316.70 133,976.77 4,772,339.93 2,986,157.55 126,953.32 2,859,204.23 2,504,775.86 111,262.34 1.38 4,057.40 305.97 460.75 455.81 79,487.87 3,977.18 22,515.98 915,806.87 36,174.98 701.72 2,759.50 876,170.66 454,416,355.61 Note: On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI Facilities that reported the amount as an on-site release. * The chemical category dioxin and dioxin-like compounds is reported in grams. Where the category dioxin and dioxin-like compounds is shown on a table with other TRI chemicals, it is presented in pounds. The grams are converted to pounds by multiplying by 0.002205. On- and Off-site Releases of PBT Chemicals PBT chemicals accounted for 454.4 million pounds of total on- and off-site releases in 2001. (See Table ES-5.) On-site land releases, totaling 386.9 million pounds, were 85 percent of total releases of PBT chemicals in 2001. Of the on-site land releases, RCRA subtitle C landfills accounted for 21.1 million pounds, with other on-site land releases totaling 365.8 million pounds. Off-site releases (transfers off-site to disposal) were 57.8 million pounds, representing 13 percent of the total releases of PBT chemicals in 2001. On-site underground injection of PBT chemicals in 2001 was 6.2 million pounds, total air emissions were 3.0 million pounds, and surface water discharges of PBT chemicals totaled less than 440,000 pounds. Of the 454.4 million pounds of total on- and off- site releases of PBT chemicals, lead and lead compounds constituted 97 percent (443.0 million pounds) of the total in 2001. On- and off-site releases of mercury and mercury compounds totaled 4.9 million pounds, polycyclic aromatic compounds totaled 3.0 million pounds, and polychlorinated biphenyls totaled 2.5 million pounds. ES-8 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-6: Quantities of TRI Chemicals in Waste by Waste Management Activity, 2001 Waste Management Activity Recycled On-site Recycled Off-site Energy Recovery On-site Energy Recovery Off-site Treated On-site Treated Off-site Quantity Released On- and Off-site Total Production-related Waste Managed Non-production-related Waste Managed Pounds 7,558,346,576 1,970,123,256 2,646,959,925 826,420,385 6,931,390,303 626,325,057 6,176,026,135 26,735,591,638 56,889,153 Percent 28.3 7.4 9.9 3.1 25.9 2.3 23.1 100.0 Note: Data are from Section 8 of Form R for 2001. Forms for the dioxin and dioxin-like compounds category represented 8 percent (1,320 out of 15,794) of all the PBT chemicals forms for 2001. Dioxin and dioxin-like compounds are reported in grams and subject to a lower reporting threshold (0.1 grams) than the other PBT chemicals. Almost 148,759 grams of total releases of dioxin and dioxin-like compounds were reported for 2001. Over 60 percent of total releases of dioxin and dioxin-like compounds were released off-site as transfers to disposal. Of the on-site releases, almost three-quarters (74 percent) were other on-site land releases, that is on-site land releases to other than RCRA subtitle C landfills, such as other types of landfills, surface impoundments, and land treatment. More detailed information on releases of PBT chemicals, including dioxin and dioxin-like compounds, can be found in Chapter 3 of this report. Waste Management Data, 2001 A total of 26.74 billion pounds of TRI chemicals in production-related waste was reported as managed during 2001. Almost 7.56 billion pounds of toxic chemicals in production-related waste were recycled on- site in 2001, representing 28 percent of all toxic chemicals in production-related waste. (See Table ES-6.) Another 6.93 billion pounds were treated on-site, accounting for 26 percent of the toxic chemicals in production-related waste managed in 2001. Almost 6.18 million pounds (23 percent) were released on- and off-site. On-site energy recovery constituted 2.65 billion pounds or 10 percent while off-site recycling was 1.97 billion pounds or 7 percent. Off- site energy recovery and off-site treatment each accounted for 3 percent or less of the total toxic chemicals in production-related waste managed in 2001. Quantities of TRI Chemicals in Waste by State Texas, followed by Louisiana and Illinois reported the largest quantity of toxic chemicals in production-related waste managed in 2001. With more than 1.5 billion pounds each, these three states accounted for 30 percent of all toxic chemicals in production-related waste in 2001. (See Table ES-7.) Texas reported the largest amount of toxic chemicals in production-related waste, with 3.96 billion pounds or 15 percent of the total for 2001. Texas also reported the largest amount of TRI chemicals in waste treated on-site, with 1.75 billion pounds or 25 percent of all on-site treatment in 2001. Facilities in Texas also reported the largest amount of on-site energy recovery, with 875.9 million pounds or 33 percent of all TRI chemicals in waste burned for energy recovery on-site. Louisiana, with 2.3 billion pounds of toxic chemicals in production-related waste, accounted for 8 percent of the total. Facilities in Louisiana reported the second largest amounts treated on-site (1.09 billion pounds) and the second largest amounts of on-site energy recovery (316.8 million pounds). Illinois was the state with the third largest quantity of toxic chemicals in production-related waste, with 1.91 billion pounds or 7 percent of total toxic chemicals in production-related waste in 2001. 2001 Toxics Release Inventory Public Data Release ES-9 ------- 2001 Toxics Release Inventory Executive Summary Table ES-7: Quantities of TRI Chemicals in Waste by State, 2001 State Alabama Alaska American Samoa Arizona Arkansas California Colorado Connecticut Delaware District of Columbia Florida Georgia Guam Hawaii Idaho Illinois Indiana Iowa Kansas Kentucky Louisiana Maine Maryland Massachusetts Michigan Minnesota Mississippi Missouri Montana Nebraska Nevada New Hampshire New Jersey New Mexico New York North Carolina North Dakota Northern Marianas Ohio Oklahoma Oregon Pennsylvania Puerto Rico Rhode Island South Carolina South Dakota Tennessee Texas Utah Vermont Virgin Islands Virginia Washington West Virginia Wisconsin Wyoming Total Recycled On-slte Off-site Pounds Pounds 818,525,464 42,141,345 1,377,417 34,652 0 0 58,925,877 18,509,833 109,446,061 60,384,333 58,257,511 74,760,095 24,177,383 28,466,735 4,239,712 32,308,816 24,133,520 8,721,191 209 6,377 76,259,500 19,936,397 107,978,360 33,470,615 0 0 290,115 46,914 3,605,397 2,170,398 1,348,544,000 102,625,703 163,252,657 167,198,128 213,121,679 42,711,679 64,249,515 30,853,868 242,266,568 45,970,185 637,089,592 36,112,363 688,744 3,151,433 10,284,862 9,430,974 12,026,251 22,396,576 101,296,499 89,483,441 177,218,187 20,369,261 161,638,689 26,687,871 304,207,614 48,514,126 8,626,607 62,534 1,593,131 17,484,015 45,728,151 2,184,376 2,348,318 10,584,760 59,939,298 23,907,690 1,531,999 3,789,504 113,439,403 67,997,882 248,360,511 96,054,465 950 731,887 0 0 185,819,144 168,455,967 56,654,350 20,705,689 22,101,690 13,281,298 477,399,211 158,199,932 19,669,024 13,442,118 12,481,984 10,014,959 393,865,233 79,100,303 409,644 1,303,774 164,851,023 79,017,354 689,703,872 136,892,811 146,169,795 2,710,383 145,571 1,582,246 796,297 121,886 94,850,493 27,992,872 12,662,851 9,974,266 39,403,298 7,317,538 35,376,355 50,653,416 1,316,993 96,021 7,558,346,576 1,970,123,256 Energy Recovery On-slte Off-site Pounds Pounds 55,906,584 23,619,563 450,000 108,217 129 0 422,012 488,202 42,487,541 43,829,050 35,102,596 22,947,133 1,949,019 3,849,371 2,926,379 2,537,184 25,863,740 2,642,626 0 0 19,979,890 3,015,888 55,953,246 12,622,865 0 0 0 484 1,460,012 65,714 37,420,571 29,460,078 191,884,163 14,341,052 748,473 4,134,190 31,460,150 4,798,455 63,137,385 30,778,647 316,777,954 13,451,035 11,562,908 179,633 7,849,613 2,133,854 4,548,040 4,392,581 9,885,512 187,813,997 1,725,850 1,742,186 55,310,964 4,406,110 99,253,396 17,564,464 3,948,532 41,063 5,200 575,939 993,336 56,709 879,040 1,710,684 6,403,815 57,979,795 27,756,266 74,011 35,671,806 4,485,007 33,635,298 10,881,206 0 19,879 0 0 81,101,178 37,992,825 64,445,608 2,000,748 14,813,876 2,053,144 131,904,573 17,269,580 65,813 37,125,971 422,570 476,133 109,669,239 31,907,639 447,276 264,391 96,119,122 7,158,004 875,947,403 141,426,391 2,719,020 73,466 0 291,536 0 2,894 27,825,485 8,615,846 11,916,690 2,561,137 33,525,628 11,401,247 12,651,183 19,038,396 25,841 14,167 2,646,959,925 826,420,385 Treated On-slte Off-site Pounds Pounds 226,084,174 22,101,850 2,769,603 2,955 0 0 10,710,007 2,511,844 121,966,236 4,996,906 100,816,156 27,460,378 16,184,490 2,786,980 13,535,252 11,717,728 40,675,792 1,726,890 987 371 157,719,630 9,715,870 146,733,814 8,785,811 0 26 364,278 2,057 25,599,902 1,168,130 225,908,101 22,002,704 243,043,965 13,652,032 40,216,595 10,570,453 34,519,541 43,288,598 191,201,719 13,224,631 1,091,501,679 33,552,502 55,972,108 829,474 50,183,694 9,327,009 21,771,030 13,646,998 105,470,376 34,797,894 70,831,646 16,683,765 95,243,267 4,003,560 65,815,093 13,598,100 10,499,243 36,449 51,643,357 1,810,885 57,883,317 59,629 3,727,050 735,962 145,287,049 36,121,594 9,996,538 503,881 99,244,224 10,424,862 116,570,037 8,786,214 5,534,778 553,161 0 0 271,064,524 34,819,545 38,660,757 2,232,749 42,316,360 10,049,902 197,111,878 22,515,192 30,653,787 13,442,163 5,071,277 1,305,442 156,322,777 10,506,996 7,213,388 237,900 178,291,980 5,560,004 1,747,035,703 97,450,247 78,768,765 1,226,624 1,228,475 680,982 22,964,543 713 140,163,993 20,535,606 64,744,283 4,485,227 168,522,361 6,481,176 114,303,043 13,600,784 11,727,681 5,653 6,931,390,303 626,325,057 Quantity Released On- and Off-site Pounds 138,399,983 521,478,368 6,920 608,214,311 48,247,951 64,185,642 37,881,583 10,335,253 11,953,371 63,498 120,787,838 117,391,931 198,339 3,135,249 72,545,710 146,988,389 208,328,798 45,144,138 31,315,170 92,168,977 133,028,144 10,443,082 45,523,468 12,714,415 131,636,741 32,817,974 71,475,274 119,400,915 51,214,536 36,594,812 783,492,191 5,224,889 31,854,796 107,869,053 46,426,593 147,535,797 25,990,159 7,953 263,377,456 28,816,690 46,747,723 185,454,422 15,581,867 1,192,889 92,460,423 13,419,785 162,366,020 274,862,593 764,952,754 314,782 1,035,223 79,923,229 26,302,988 80,107,693 48,914,984 18,172,402 6,176,026,135 Total Production- related Waste Managed Pounds 1,326,778,962 526,221,212 7,049 699,782,085 431,358,077 383,529,510 115,295,561 77,600,324 115,717,130 71,442 407,415,013 482,936,642 198,365 3,839,097 106,615,263 1,912,949,546 1,001,700,794 356,647,207 240,485,297 678,748,112 2,261,513,268 82,827,382 134,733,474 91,495,891 660,384,461 321,388,869 418,765,736 668,353,708 74,428,965 109,707,339 890,397,708 25,210,703 361,494,038 151,521,252 377,689,778 661,823,529 32,830,814 7,953 1,042,630,639 213,516,591 151,363,993 1,189,854,789 129,980,743 30,965,255 873,832,609 23,296,158 693,363,507 3,963,319,020 996,620,807 4,243,592 24,921,556 399,907,524 132,647,442 346,758,940 294,538,161 31,358,758 26,735,591,638 Non-production- related Waste Managed Pounds 70,451 17,994 10 79,115 1,996,835 580,159 187,376 1,108,832 163,168 0 478,639 628,759 142 9 1,892,372 545,619 318,766 222,407 129,439 2,253,885 651,905 8,622 791,777 57,905 141,624 688,794 286,446 168,177 12,029,507 41,484 11,424 38,846 282,988 2,359,540 1,229,894 440,744 15,005 0 198,808 185,842 147,532 1,116,636 26,548 12,835 561,487 107,756 162,870 12,156,179 10,579,265 20,208 3,651 89,462 250,693 1,226,288 124,326 106 56,889,153 Note: Data are from Section 8 of Form R. ES-10 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-8: Quantities of TRI Chemicals in Waste by Industry, 2001 SIC Code Industry 10 Metal Mining 12 Coal Mining 20 Food 21 Tobacco 22 Textiles 23 Apparel 24 Lumber 25 Furniture 26 Paper 27 Printing 28 Chemicals 29 Petroleum 30 Plastics 31 Leather 32 Stone/Clay/Glass 33 Primary Metals 34 Fabricated Metals 35 Machinery 36 Electrical Equip. 37 Transportation Equip. 38 Measure./Photo. 39 Miscellaneous - Multiple codes 20-39 - No codes 20-39 491/493 Electric Utilities 5169 Chemical Wholesale Distributors 5171 Petroleum Bulk Terminals/Bulk Storage 7389/4953 Hazardous Waste/Solvent Recovery Total Recycled On-site Off-site Pounds Pounds 32,735,928 1,263,828 32,251 7,985 768,924,832 2,870,076 2,817 13,677 12,707,442 874,373 94,870 60,241 6,976,869 837,875 375,035 3,477,898 64,794,501 2,934,559 205,498,797 12,411,421 4,159,511,539 165,873,509 95,286,627 24,168,037 34,663,998 13,371,548 389,441 194,391 140,883,189 4,782,655 1,342,465,964 676,045,362 113,773,998 335,301,136 9,212,032 95,700,300 173,618,308 290,940,156 11,158,752 114,151,281 1,615,085 10,444,620 7,645,234 12,456,340 225,086,802 160,309,820 2,636,747 3,745,287 2,835,782 6,962,529 17,596,767 54,251 23,579,074 8,948,927 104,243,895 21,921,175 7,558,346,576 1,970,123,256 Energy Recovery On-site Off-site Pounds Pounds 0 98,030 0 0 1,182,619 156,802 0 0 4,275,378 1,974,199 0 82,786 5,484,051 5,027,675 62,251 1,783,425 174,986,780 5,624,222 548,843 3,446,972 1,357,077,773 406,079,947 282,794,445 2,622,753 23,361,474 7,495,115 577 18,862 449,089,243 1,710,176 167,015,143 3,316,752 18,296,498 11,612,043 28,694 1,600,771 9,637,045 7,649,807 2,609,230 10,935,477 269,790 1,857,568 4,021,273 1,348,756 137,286,267 21,285,530 180,654 998,403 1,645,552 682 22 15,302,011 33,089 205,550 7,073,234 314,186,073 2,646,959,925 826,420,385 Treated On-site Off-site Pounds Pounds 54,832,294 6,403 359,348 0 154,663,793 35,273,137 1,439,725 600,496 12,165,812 1,946,084 1,172,336 14,963 18,631,134 1,033,556 748,891 311,095 887,320,219 43,334,921 127,016,206 1,759,923 3,657,842,228 355,033,082 389,842,342 11,069,216 29,225,379 8,681,449 4,569,954 414,703 11,569,542 4,085,265 318,408,207 21,056,802 94,780,676 20,629,110 4,656,719 2,851,195 57,953,018 22,476,081 27,426,980 13,050,299 36,510,399 2,271,164 4,092,063 3,340,271 277,941,861 37,706,531 6,615,379 1,378,008 488,117,685 20,469 799,278 5,779,256 8,673,139 1,407,942 254,015,699 30,793,637 6,931,390,303 626,325,057 Quantity Released On- and Off-site Pounds 2,780,689,913 16,082,410 127,006,561 3,253,265 6,771,563 378,264 31,211,793 8,300,142 195,392,896 20,011,194 586,661,036 72,833,689 88,826,986 2,819,230 41,063,310 572,405,099 66,635,591 16,377,983 30,163,404 80,710,311 9,597,623 7,862,955 106,940,404 11,956,379 1,061,541,493 1,547,913 3,430,424 225,554,305 6,176,026,135 Total Production- related Waste Managed Pounds 2,869,626,395 16,481,994 1,090,077,820 5,309,980 40,714,851 1,803,460 69,202,953 15,058,736 1,374,388,098 370,693,356 10,688,079,114 878,617,109 205,625,949 8,407,158 653,183,379 3,100,713,329 661,029,051 130,427,694 592,437,820 260,042,330 62,566,249 40,766,891 966,557,214 27,510,857 1,561,124,192 41,079,498 46,278,144 957,788,017 26,735,591,638 Non-production- related Waste Managed Pounds 714,674 2,356,746 465,658 0 27,389 0 421,385 93,634 197,728 59,373 3,949,337 729,776 77,391 7,492 443,947 37,376,955 1,068,942 269,426 216,785 2,254,610 315,151 826,556 948,412 2,034,249 1,752,578 167,552 87,497 25,910 56,889,153 Note: Data are from Section 8 of Form R. Facilities/forms are included in the manufacturing industry categories (SIC Codes 20-39) if they did not report a SIC code in the other industries. Forms that reported more than one 2-digit SIC code within the range 20 to 39 are assigned to the "multiple codes" category. Facilities/forms are included in the other industry categories if the facility/form has a SIC code in the other industries and no SIC code in 20-39. If the facility reported in any year prior to 1998 and the facility/form has a combination of manufacturing and other industry SIC codes, then the facility/form is included in the manufacturing industry category. If the facility reported for the first time in 1998 or later and the facility/form has a combination of manufacturing and other industry SIC codes, then the facility/form is included in the other industry category. Forms with no 2-digit SIC code are included in the "no codes 20-39" category. One facility, Phelps Dodge Miami of Claypool, AZ, that reported under SIC code 33 and SIC code 10 in 2001 and previous years has been included in SIC code 10 for the purpose of this analysis. Facilities in Illinois reported the largest amount recycled on-site, with 1.35 billion pounds or 18 percent of total on-site recycling in 2001. Nevada facilities reported the largest quantities of TRI chemicals in waste released on- and off-site in 2001, with 783.5 million pounds or 13 percent of the total released on- and off-site. Nevada ranked ninth overall for total toxic chemicals production- related waste, with 890.4 million pounds. Quantities of TRI Chemicals in Waste by Industry The chemical manufacturing industry reported the largest quantity of toxic chemicals in production- related waste managed in 2001, with 10.69 billion pounds or 40 percent of the total reported by all industries. (See Table ES-8.) Chemical manu- facturers reported the largest amounts recycled on- site, used for energy recovery on- and off-site, and treated on- and off-site. With 4.16 billion pounds recycled on-site, the chemicals industry accounted for 55 percent of all on-site recycling in 2001. This industry also reported 3.66 billion pounds treated on-site (53 percent of total on-site treatment), 1.36 billion pounds of on-site energy recovery (51 percent of total on-site energy recovery), and 406.1 million pounds of off-site energy recovery (49 percent of total off-site energy recovery). The primary metals industry reported the second largest quantity of toxic chemicals in production- related waste managed in 2001, with 3.10 billion pounds or 12 percent of the total. Primary metals facilities reported the largest quantity of TRI chemicals in waste recycled off-site, with 676.0 2001 Toxics Release Inventory Public Data Release ES-11 ------- 2001 Toxics Release Inventory Executive Summary million pounds or 34 percent of all off-site recycling, and the second largest on-site recycling, with 1.34 billion pounds (18 percent of all on-site recycling). The metal mining industry reported the third largest quantities of toxic chemicals in production-related waste and the largest quantity released on- and off- site in 2001. With 2.87 billion pounds, metal mining facilities accounted for 11 percent of toxic chemicals in production-related waste managed by all industries in 2001. Most (97 percent) of the toxic chemicals in production-related waste managed by metal mining facilities was released on-and off-site. The 2.78 billion pounds released on- and off-site by the metal mining industry in 2001 accounted for 45 percent of all TRI chemicals in waste released on- and off-site in 2001. Electric utilities reported the fourth largest amount of toxic chemicals in production-related waste in 2001, with 1.56 billion pounds, representing 6 percent of the total managed. This industry reported the second largest amount released on- and off-site, with 1.06 billion pounds or 17 percent of the quantity released on- and off-site by all industries in 2001. Quantities of TRI Chemicals in Waste by Chemical Table ES-9 lists the 20 TRI chemicals managed in production-related waste in 2001 in the largest quantities. Production-related waste managed of the top 20 TRI chemicals totaled 19.29 billion pounds, 72 percent of all toxic chemicals in production- related waste of all TRI chemicals. On-site recycling of the top 20 TRI chemicals totaled 5.82 billion pounds, representing 77 percent all on-site recycling of all TRI chemicals in 2001. On-site treatment was 5.06 billion pounds or 73 percent of total on-site treatment for all TRI chemicals. The quantity released on- and off-site of the top 20 TRI chemicals constituted 4.44 billion pounds, representing 72 percent of the total releases on- and off-site in 2001. Of the 19.29 billion pounds of the top 20 TRI chemicals in production-related waste, 30 percent was recycled on-site, 26 percent was treated on-site and 23 percent was released on- and off-site. The TRI chemical managed in waste in the largest quantities in 2001 was methanol, with 2.33 billion pounds, accounting for 9 percent of toxic chemicals Table ES-9: Top 20 Chemicals with the Largest Total Production-related Waste, 2001 CAS Number Chemical 67-56-1 Methanol 108-88-3 Toluene 7647-01-0 Hydrochloric acid - Zinc compounds - Copper compounds 74-85-1 Ethylene 7440-50-8 Copper 110-54-3 n-Hexane - Lead compounds 98-82-8 Cumene 7664-41-7 Ammonia 115-07-1 Propylene - Nitrate compounds 7664-93-9 Sulfuric acid 107-21-1 Ethylene glycol 107-06-2 1 ,2-Dichloroethane 7782-50-5 Chlorine 1330-20-7 Xylene (mixed isomers) - Manganese compounds 7697-37-2 Nitric acid Subtotal (top 20 chemicals) Total (all chemicals) Recycled On-site Off-site Pounds Pounds 512,628,730 33,930,506 1,017,876,688 37,638,485 66,597,953 666,508 84,963,627 274,345,019 143,657,931 106,728,311 127,322,652 442 489,376,136 573,888,780 775,131,057 8,343,536 360,989,109 196,407,911 817,515,105 122,530 121,839,483 7,679,782 25,694,779 25 83,215,827 786,458 38,353,227 640,324 376,084,469 75,745,755 430,010,562 2,343,199 155,857,244 14,303 106,413,584 31,701,371 23,174,873 46,947,185 64,955,578 1,947,737 5,821,658,614 1,399,878,167 7,558,346,576 1,970,123,256 Energy Recovery On-site Off-site Pounds Pounds 396,146,801 152,279,030 182,640,178 147,740,286 3,474,181 9,721 140,775 40,538 0 12,305 469,015,809 16,270,592 0 2,128 38,584,286 24,231,336 87,740 107,720 5,041,374 1,276,359 125,788,947 139,878 282,717,411 85,357 0 71,975 6,225 34,500 4,184,282 14,351,166 34,886,848 750,931 14,646,699 50,600 92,846,853 116,238,710 3,748 0 0 3,383 1,650,212,157 473,696,514 2,646,959,925 826,420,385 Treated On-site Off-site Pounds Pounds 938,972,857 116,154,534 303,738,267 23,503,497 841,654,109 4,093,004 10,462,553 2,697,732 421,761 632,410 612,552,699 8,052,470 331,409 936,215 67,546,836 7,037,691 63,447 761,999 7,167,513 132,066 370,090,277 15,048,231 461,181,800 14,093,926 166,171,227 178,880,408 395,096,005 991,808 56,603,714 28,816,768 90,547,449 2,855,698 364,287,065 535,275 65,780,111 15,708,374 846,053 521,713 309,588,845 13,266,297 5,063,103,997 434,720,116 6,931,390,303 626,325,057 Quantity Released On- and Off-site Pounds 180,899,209 74,807,577 587,609,582 982,854,573 1,012,319,638 23,591,956 23,466,362 49,319,091 407,376,182 1,315,128 159,845,477 13,793,661 272,004,175 148,183,112 10,186,122 465,782 16,700,285 50,788,556 406,131,471 21,919,421 4,443,577,361 6,176,026,135 Total Production- related Waste Managed Pounds 2,331,011,667 1,787,944,977 1,504,105,058 1,355,504,817 1,263,772,355 1,256,806,620 1,088,001,030 970,193,833 965,794,108 832,570,075 800,432,076 797,566,959 701,130,070 583,305,201 565,972,276 561,860,469 552,091,471 479,477,559 477,625,043 411,681,261 19,286,846,925 26,735,591,638 Non-production- related Waste Managed Pounds 224,346 668,782 231,580 5,393,968 9,414,992 473,294 812,440 203,916 18,044,640 3,467 593,541 203,649 846,635 256,304 95,255 21,893 126,642 567,440 2,528,743 500,036 41,211,562 56,889,153 Note: Data are from Section 8 of Form R. ES-12 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary in production related-waste. Methanol was the chemical treated on-site in the largest amounts (939.0 million pounds or 14 percent of all on-site treatment). Toluene was managed in waste in the second largest amounts, with 1.79 billion pounds, representing 7 percent of the total for all chemicals. Toluene was recycled on-site in the largest amounts. Almost 1.02 billion pounds of toluene was recycled on-site, accounting for 13 percent of all on-site recycling in 2001. The TRI chemical with the largest quantity released on- and off-site was copper compounds with 1.01 billion pounds, accounting for 16 percent of all releases on- and off-site in 2001. Copper compounds ranked fifth for total toxic chemicals managed in production-related waste. Zinc compounds were released on- and off-site in the second largest amounts, with 982.9 million pounds, and ranked fourth for total toxic chemicals managed in production-related waste. Hydrochloric acid was released on- and off-site in the third largest amount, with 587.6 million pounds and ranked third for total toxic chemicals managed in production-related waste and second for on-site treatment. Quantities of PBT Chemicals in Waste A total of 1.28 billion pounds of PBT chemicals was reported as managed in waste during 2001. Over 546.6 million pounds of PBT chemicals in waste were recycled on-site, another 440.1 million pounds were released on- and off-site, and 259.8 million pounds were recycled off-site. (See Table ES-10.) Table ES-10: Quantities of TRI Chemicals in Waste, PBT Chemicals, 2001 CAS Number Chemical — Dioxin and dioxin-like compounds* — Dfcxin and dGxin-libe compounds (in grams)" Lead and Lead Compounds 7439-92-1 Lead - Lead compounds Mercury and Mercury Compounds 7439-97-6 Mercury - Mercury compounds Polycyclic aromatic compounds 191-24-2 Benzo(g,h,i)perylene - Polycyclic aromatic compounds 1336-36-3 Polychlorinated biphenyls (PCBs) Pesticides 309-00-2 Aldrin 57-74-9 Chlordane 76-44-8 Heptachlor 465-73-6 Isodrin 72-43-5 Methoxychlor 40487-42-1 Pendimethalin 8001-35-2 Toxaphene 1582-09-8 Trifluralin Other PBTs 118-74-1 Hexachlorobenzene 29082-74-4 Octachlorostyrene 608-93-5 Pentachlorobenzene 79-94-7 Tetrabromobisphenol A Total Recycled On-site Off-site Pounds Pounds 3.27 0.23 1,484.197 102.870 543,676,920.880 258,775,081.959 182,687,811.78 62,367,170.76 360,989,109.10 196,407,911.20 735,096.829 161,542.342 304,798.30 75,943.07 430,298.53 85,599.27 2,181,079.520 860,183.755 140,586.01 37,229.40 2,040,493.51 822,954.35 355.10 121.88 13,702.00 3.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 6,000.00 0.00 0.00 3.00 7,702.00 0.00 5,964.10 2,525.00 5,400.10 1,432.00 0.00 0.00 8.00 770.00 556.00 323.00 546,613,121.70 259,799,458.16 Energy Recovery On-site Off-site Pounds Pounds 0.03 6.09 11.524 2,760.403 96,065.614 119,025.670 8,326.00 11,306.00 87,739.61 107,719.67 77.000 1.800 77.00 1.80 0.00 0.00 10,401,981.016 178,811.785 808,168.96 3,744.11 9,593,812.06 175,067.67 400.00 54.40 1,996.00 2,649.20 0.00 306.00 244.00 0.00 45.00 334.00 0.00 0.00 569.00 1,376.00 0.00 0.00 1,138.00 7.20 0.00 626.00 370,079.64 6,551.30 369,749.64 2,132.80 0.00 0.00 330.00 1,491.00 0.00 2,927.50 10,870,599.30 307,100.24 Treated On-site Off-site Pounds Pounds 516.62 118.13 234,296.365 53,572.009 1,259,679.530 1,002,539.673 1,196,232.44 240,541.13 63,447.09 761,998.55 10,862.961 37,796.802 30.21 33,619.33 10,832.75 4,177.47 8,181,690.388 180,866.390 199,443.74 1,911.27 7,982,246.65 178,955.12 1,310,735.30 270,767.30 2,410,597.72 115,391.20 58,529.00 24.00 463,839.30 457.00 751,861.74 173.00 3,800.00 142.00 319,545.30 231.40 390,997.29 34,656.00 124,183.14 464.80 297,841.95 79,243.00 6,810,472.85 94,940.38 6,269,768.60 41,542.86 8.00 0.00 445,846.25 1,307.52 94,850.00 52,090.00 19,984,555.37 1,702,419.87 Quantity Released On- and Off-site Pounds 340.50 154,421.201 428,651,479.574 21,275,297.20 407,376,182.37 4,873,159.631 104,363.91 4,768,795.72 3,017,847.935 122,772.28 2,895,075.65 2,545,407.33 115,494.02 18.38 4,024.29 305.73 465.19 12,093.69 71,546.00 4,378.99 22,661.75 906,015.92 48,534.45 701.72 2,759.93 854,019.81 440,109,744.91 Total Production- related Waste Managed Pounds 984.86 446,648.570 1,233,580,792.900 267,786,685.31 965,794,107.59 5,818,537.365 518,833.63 5,299,703.74 25,002,460.787 1,313,855.78 23,688,605.01 4,127,841.31 2,659,833.14 58,877.38 468,564.59 752,719.47 4,407.19 333,815.39 503,199.29 130,175.13 408,074.70 8,196,549.19 6,738,560.45 709.72 452,512.70 1,004,766.31 1,279,386,999.55 Non-production- related Waste Managed Pounds 29.13 13,212.890 18,333,736.003 289,096.40 18,044,639.60 16,014.155 3,447.20 12,566.96 18,875.049 1,565.82 17,309.23 23,202.59 679.02 0.00 0.00 0.02 0.00 0.00 0.00 0.00 679.00 12,384.33 9,310.49 0.00 3,073.84 0.00 18,404,920.28 Note: Data are from Section 8 of Form R. * The chemical category dioxin and dioxin-like compounds is reported in grams. Where the category dioxin and dioxin-like compounds is shown on a table with other TRI chemicals, it is presented in pounds. The grams are converted to pounds by multiplying by 0.002205. 2001 Toxics Release Inventory Public Data Release ES-13 ------- 2001 Toxics Release Inventory Executive Summary Over 1.23 billion pounds of lead and lead compounds in production-related waste, representing 96 percent of all production-related waste of PBTs, was managed in 2001. There was 25 million pounds of polycyclic aromatic compounds in production-related waste (2 percent of the total for PBT chemicals). There was 6.7 million pounds of hexachlorobenzene, 5.8 million pounds of mercury and mercury compounds, 4.1 million pounds of polychlorinated biphenyls and 2.7 million pounds of pesticides managed in waste. Dioxin and dioxin-like compounds in production- related waste managed totaled almost 446,649 grams for 2001. Dioxin and dioxin-like compounds are reported in grams and subject to a lower reporting threshold (0.1 grams) than the other PBT chemicals. Over half (52 percent or 234,296 grams) of the dioxin and dioxin-like compounds in waste were treated on-site with most of the remaining released on- and off-site (154,421 grams). More detailed information on PBT chemicals, including dioxin and dioxin-like compounds, can be found in Chapter 3 of this report. Transfers for Further Waste Management, including Disposal A total of 4.08 billion pounds of TRI chemicals in waste was transferred off-site for further waste management, including disposal, in 2001. (See Table ES-11.) Transfers off-site to recycling total 1.95 billion pounds or 48 percent of all transfers for further waste management, including disposal. Another 840.3 million pounds, accounting for 21 percent, were transfers to energy recovery. Other off-site transfers to disposal were 664.3 million pounds or 16 percent of total transfers for further waste management in 2001. Transfers to POTWs were 339.9 million pounds or 8 percent of the total, and transfers to treatment were 279.7 million pounds or 7 percent. Projections of TRI Chemicals in Waste and Source Reduction TRI facilities expected to decrease their quantities of toxic chemicals in production-related waste managed between 2001 and 2003 by less than one percent, from 25.50 billion pounds to 25.34 billion pounds. The projected totals were 24.95 billion pounds for 2002, a decrease of just over 2 percent from 2001 to 2002 and 25.34 billion pounds for 2003, an increase of just under 2 percent from 2002 to 2003.2 (See Table ES-12.) The decrease was projected to occur within on-site recycling, off-site energy recovery, on-site treatment, and the quantity released on- and off-site. On-site recycling, with 7.01 billion pounds in 2001, was expected to decline by less than one percent by 2003. Off-site energy recovery, with 826.3 million pounds in 2001, was expected to decline by 5 percent by 2003. On- site treatment, with 6.93 billion pounds in 2001, was expected to decline by less than one percent. Table ES-11: TRI Transfers Off-site for Further Waste Management, including Disposal, 2001 Type of Transfer Transfers to Recycling Transfers to Energy Recovery Transfers to Treatment Transfers to POTWs Metals and Metal Category Compounds Only Non-metal TRI Chemicals Other Off-site Transfers* Other Off-site Transfers to Disposal** Total Transfers for Further Waste Management, including Disposal Pounds 1 ,950,840,492 840,332,852 279,686,495 339,913,774 2,211,172 337,702,602 1,781,068 664,339,613 4,076,894,294 Percent 47.9 20.6 6.9 8.3 0.1 8.3 0.04 16.3 100.0 Note: Transfers Off-site for Further Waste Management, including Disposal are from Section 6 of Form R. * Other Off-site Transfers are transfers reported without a valid waste management code. ** Does not include transfers to POTWs of metals and metal category compounds. 2 The reporting thresholds for lead and lead compounds were lowered for 2001. The amounts reported for these chemicals have been omitted from this table since facilities reporting on lead and lead compounds for the first time in 2001 may not have reported an amount for 2000 on the 2001 TRI Form R ES-14 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-12: Prior Year, Current Year and Projected Quantities of TRI Chemicals in Waste, 2000-2003 Waste Management Activity Recycled On-site Recycled Off-site Energy Recovery On-site Energy Recovery Off-site Treated On-site Treated Off-site Quantity Released On- and Off-site Total Production-related Waste Managed Waste Management Activity Recycled On-site Recycled Off-site Energy Recovery On-site Energy Recovery Off-site Treated On-site Treated Off-site Quantity Released On- and Off-site Total Production-related Waste Managed Prior Year 2000 Total Percent Pounds of Total 7,506,278,723 27.0 1,827,604,200 6.6 2,796,796,450 10.1 786,700,685 2.8 8,213,134,666 29.6 596,629,742 2.1 6,053,625,041 21.8 27,780,769,507 100.0 Change 2000-2001 Percent -6.5 -6.4 -5.4 5.0 -15.6 4.8 -5.1 -8.2 Current Year 2001 Total Percent Pounds of Total 7,014,669,655 27.5 1,711,348,174 6.7 2,646,863,860 10.4 826,301,360 3.2 6,930,130,624 27.2 625,322,518 2.5 5,747,374,655 22.5 25,502,010,846 100.0 Projected Change 2001-2002 Percent -1.6 -2.2 4.9 -5.7 -1.9 4.2 -6.6 -2.2 Projected 2002 Total Percent Pounds of Total 6,899,323,467 27.7 1,673,184,096 6.7 2,776,164,895 11.1 778,996,234 3.1 6,801,501,525 27.3 651,794,364 2.6 5,370,005,033 21.5 24,950,969,614 100.0 Projected Change 2002-2003 Percent 1.1 2.9 3.6 0.3 1.2 -0.5 1.6 1.6 Projected 2003 Total Percent Pounds of Total 6,976,781,188 27.5 1,721,512,047 6.8 2,877,192,619 11.4 781,416,547 3.1 6,880,003,751 27.2 648,521,181 2.6 5,454,490,609 21.5 25,339,917,942 100.0 Projected Change 2001-2003 Percent -0.5 0.6 8.7 -5.4 -0.7 3.7 -5.1 -0.6 Note: Does not include lead and lead compounds. Data from Section 8 of Form R for 2001. Two facilities made errors in reporting the quantity released on- and off-site. One facility reported 6,500,022,100 pounds for 2000; the correct number is 65,000 pounds. One facility reported 4,976,250,100 pounds for 2002; the correct number is 49,762 pounds. These corrections were received too late to be included in the publicly released database, but they have been included in this table. The quantity released on- and off-site was expected to decline by 5 percent, from 5.75 billion pounds to 5.45 billion pounds. The quantity released on- and off-site decreased by 5 percent from 2000 to 2001. On- and off-site releases are the least-desirable outcome under the waste management hierarchy described in Waste Management in Chapter 1 (Figure 1-2). Off-site recycling, on-site energy recovery and off- site treatment were expected to increase from 2001 to 2003. Off-site recycling was projected to increase by less than one percent, from 1.71 billion pounds in 2001 to 1.72 billion pounds in 2003. Off-site recycling decreased by 6 percent from 2000 to 2001. On-site energy recovery was projected to increase by 9 percent from 2001 to 2003, from 2.65 billion pounds to 2.88 billion pounds. On-site energy recovery decreased by 5 percent from 2000 to 2001. Off-site treatment was expected to increase by 4 percent, from 625.3 million pounds to 648.5 million pounds. Off-site treatment increased by 5 percent from 2000 to 2001. In 2001, 4,534 of the 22,359 TRI facilities submitting a Form R reported undertaking one or more source reduction activities. As noted in Waste Management in Chapter 1, source reduction—an activity that prevents the generation of waste—is preferred to waste management. These 4,534 facilities represented 20.3 percent of the TRI facilities submitting a Form R in 2001. (See Table ES-13.) Table ES-13: Facilities and Forms Reporting Source Reduction Activity by Category, 2001 Source Reduction Activity Good Operating Practices Inventory Control Spill and Leak Prevention Raw Materials Modifications Process Modifications Cleaning and Degreasing Surface Preparation and Finishing Product Modifications Any Source Reduction Activity Facilities Reporting Source Reduction Activity as Percent of TRI Facilities Reporting Form Rs* Number Percent 2,218 9.9 546 2.4 917 4.1 1,020 4.6 1,576 7.0 325 1 .5 481 2.2 392 1 .8 4,534 20.3 Forms Reporting Source Reduction Activity as Percent of TRI Forms Reporting Form Rs* Number Percent 6,474 7.8 1 ,305 1 .6 2,887 3.5 1,680 2.0 3,719 4.5 574 0.7 983 1 .2 718 0.9 18,340 22.0 Note: All source reduction activities on a form are counted in the corresponding category. Totals do not equal the sum of the above categories because facilities and forms may report more than one source reduction activity. * Source Reduction Activity reporting is only done using the Form R; Form As do not contain source reduction activity information. 2001 Toxics Release Inventory Public Data Release ES-15 ------- 2001 Toxics Release Inventory Executive Summary There were 18,340 forms with source reduction activity reported in 2001, representing 22 percent of all Form Rs in 2001. The most frequently reported source reduction activity was good operating practices (listed by 10 percent of the facilities). Process modifications came next, reported by 7 percent of facilities, followed by raw materials modifications (by 5 percent of facilities) and spill and leak prevention (by 4 percent of facilities). TRI DATA FOR 2000-2001 The data used to compare 2000 to 2001 do not include lead and lead compounds since the thresholds for reporting on lead and lead compounds were lowered for 2001 to 100 pounds. Total On-site and Off-site Releases, 2000-2001 All TRI Chemicals From 2000 to 2001, total TRI releases on- and off- site fell by 1.05 billion pounds or 15.5 percent. On- site releases decreased by 1.08 billion pounds, while off-site releases (transfers off-site to disposal) increased by 32.7 million pounds. The number of facilities and forms reporting each decreased by 4 percent. (See Table ES-14.) On-site land releases comprised the largest type of on-site release and had the largest absolute decrease of 739.1 million pounds or 19 percent from 2000 to 2001. Disposal in RCRA subtitle C landfills decreased by 83.6 million pounds or 41 percent, while other on-site land releases decreased by 655.5 million pounds or 18 percent. On-site air emissions, the second largest type of on- site release, decreased by 237.1 million pounds or 12 percent from 2000 to 2001. Point source air emissions decreased by 221.5 million pounds or 13 percent and fugitive air emissions decreased by 15.6 million pounds or 6 percent. Other types of on-site releases include underground injection and surface water discharges. Underground injection decreased by 61.2 million pounds or 23 percent and surface water discharges decreased by 46.9 million pounds or 17.5 percent. The increase in off-site releases (transfers off-site to disposal) was primarily due to the increase of 30.2 million pounds (an increase of 41 percent) of metals and metal category compounds sent for solidification/stabilization and the increase of 21.8 million pounds (7 percent) in transfers to landfills/surface impoundments. Transfers to land treatment also increased from 2000 to 2001, by 1.5 million pounds or 25.5 percent. Other types of off-site releases (transfers off-site to disposal) decreased from 2000 to 2001. Off-site underground injection decreased by 4.2 million pounds or 20.5 percent and transfers to storage decreased by 3.5 million pounds or 38 percent. PBT Chemicals On- and off-site releases of PBT chemicals decreased from 11.6 million pounds to 11.4 million pounds from 2000 to 2001, a decrease of almost 2 percent. Off-site releases decreased by 44 percent (2.0 million pounds) while on-site releases increased by 25 percent (1.8 million pounds). (See Table ES-15.) The decrease in off-site releases (transfers to disposal) of PBT chemicals was largely due to a decrease of transfers off-site to landfills/surface impoundments of 1.6 million pounds (41 percent), which included decreases of 1.4 million pounds of polycyclic aromatic compounds. On the other hand, the increase in on-site releases of PBT chemicals was due to an increase in on-site land releases of 2.2 million pounds. Such releases of mercury and mercury compounds increased by 1.2 million pounds and by 1.1 million pounds for polychlorinated biphenyls. Other types of on-site releases showed decreases, including air emissions which decreased by 355,196 pounds or 20 percent. Total releases of dioxin and dioxin-like compounds increased by 50 percent (by 49,714 grams) from 2000-2001. On-site releases increased by 30 percent (by 9,476 grams) and off-site releases increased by 67 percent (by 36,548 grams). The largest increases occurred in off-site transfers to landfills/surface ES-16 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-14: TRI On-site and Off-site Releases, 2000-2001 Total Facilities Total Forms Form Rs Form As On-site Releases Total Air Emissions Fugitive Air Emissions Point Source Air Emissions Surface Water Discharges Underground Injection Class 1 Wells Class II-V Wells On-site Land Releases RCRA Subtitle C Landfills Other On-site Land Releases Total On-site Releases Off-site Releases Storage Only* Solidification/Stabilization** Metal and Metal Category Compounds Only Wastewater Treatment (Excluding POTWs)*** Metal and Metal Category Compounds Only Transfers to POTWs**** Metal and Metal Category Compounds Only Underground Injection Landfills/Surface Impoundments Land Treatment Other Land Disposal Other Off-site Management Transfers to Waste Broker for Disposal Unknown***** Total Off-site Releases (Transfers Off-site to Disposal) Total On- and Off-site Releases 2000 Number 23,604 90,659 77,687 12,972 Pounds 1,914,847,514 255,719,707 1,659,127,808 267,240,517 270,436,755 240,690,232 29,746,523 3,824,390,738 203,224,254 3,621,166,484 6,276,915,525 2001 Number 22,615 86,952 74,710 12,242 Pounds 1,677,739,937 240,095,759 1,437,644,178 220,382,696 209,191,464 193,230,425 15,961,039 3,085,260,659 119,609,932 2,965,650,727 5,192,574,756 9,378,356 73,727,018 6,918,180 3,070,710 20,278,551 311,592,047 5,689,259 21,982,754 17,851,630 13,285,156 5,951,138 489,724,797 6,766,640,322 5,833,022 103,888,528 3,680,619 2,162,223 16,125,909 333,380,566 7,141,281 21,869,451 14,926,431 10,072,787 3,349,797 522,430,614 5,715,005,370 Change 2000-2001 Number -989 -3,707 -2,977 -730 Pounds -237,107,578 -15,623,948 -221,483,630 -46,857,821 -61,245,291 -47,459,807 -13,785,484 -739,130,080 -83,614,323 -655,515,757 -1 ,084,340,769 Percent -4.2 -4.1 -3.8 -5.6 Percent -12.4 -6.1 -13.3 -17.5 -22.6 -19.7 -46.3 -19.3 -41.1 -18.1 -17.3 -3,545,333 30,161,510 -3,237,561 -908,486 -4,152,642 21,788,519 1,452,022 -113,303 -2,925,199 -3,212,368 -2,601,340 32,705,817 -1,051,634,952 -37.8 40.9 -46.8 -29.6 -20.5 7.0 25.5 -0.5 -16.4 -24.2 -43.7 6.7 -15.5 Note: Does not include lead and lead compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. * Storage only (disposal code M10) indicates that the toxic chemical is sent off-site for storage because there is no known disposal method. Amounts reported as transferred to storage only are included as a form of disposal (off-site release). See Box 1-5. ** Beginning in reporting year 1997, transfers to solidification/stabilization of metals and metal category compounds (waste treatment code M41) are reported separately from transfers to solidification/stabilization of non-metal TRI chemicals (waste treatment code M40). Because this treatment method prepares a metal for disposal, but does not destroy it, such transfers are included as a form of disposal (off-site release). See Box 1-6. Reports under code M40 of metals and metal category compounds have been included in solidification/stabilization of metals and metal category compounds in this report. *** Beginning in reporting year 1997, transfers to wastewater treatment (excluding POTWs) of metals and metal category compounds (waste treatment code M61) are reported separately from transfers to wastewater treatment of non-metal TRI chemicals (waste treatment code M60). Because wastewater treatment does not destroy metals, such transfers are included as a form of disposal (off-site release). See Box 1-6. Transfers of metals and metal category compounds reported under code M60 have been included in transfers of metals and metal category compounds to wastewater treatment. **** Reported as discharges to POTWs in Section 6.1 of Form R. EPA considers transfers of metals and metal category compounds to POTWs as an off-site release because sewage treatment does not destroy the metal content of the waste material. ***** Unknown (disposal code M99) indicates that a facility is not aware of the type of waste management used for the toxic chemical that is sent off-site. Amounts reported as unknown transfers are treated as a form of disposal (off-site release). 2001 Toxics Release Inventory Public Data Release ES-17 ------- 2001 Toxics Release Inventory Executive Summary Table ES-15: TRI On-site and Off-site Releases, PBT Chemicals, 2000-2001 Forms On-site Releases Total Air Emissions Surface Water Discharges Underground Injection Class 1 Wells Class II-V Wells On-site Land Releases RCRA Subtitle C Landfills Other On-site Land Releases Total On-site Releases Storage Only* Solidification/Stabilization** Metals and Metal Category Compounds Only Wastewater Treatment (Excluding POTWs)*** Metals and Metal Category Compounds Only Transfers to POTWs**** Metals and Metal Category Compounds Only Underground Injection Landfills/Surface Impoundments Land Treatment Other Land Disposal Other Off-site Management Transfers to Waste Broker for Disposal Unknown***** Total Off-site Releases (Transfers Off-site to Disposal) Total On- and Off-site Releases 2000 Number 7,092 Pounds 1,746,439.21 21,437.42 11,778.46 1,996.38 9,782.09 5,300,098.18 1,709,080.04 3,591,018.14 7,079,753.28 17,119.66 415,330.48 6,850.32 413.09 0.00 3,785,264.99 881.67 115,965.59 9,368.47 80,898.95 115,370.88 4,547,464.09 11,627,217.37 2001 Number 7,233 Pounds 1,391,243.35 19,627.51 10,250.16 1,881.97 8,368.19 7,451,857.42 2,456,790.69 4,995,066.73 8,872,978.44 11,352.22 68,254.65 2,679.38 469.60 1 ,305.63 2,232,285.81 903.36 100,282.88 10,099.63 100,078.16 23,957.58 2,551,668.90 11,424,647.34 Change 2000-2001 Number 141 Pounds -355,195.86 -1,809.91 -1,528.31 -114.41 -1,413.90 2,151,759.24 747,710.65 1,404,048.59 1,793,225.16 -5,767.44 -347,075.83 -4,170.94 56.51 1 ,305.63 -1,552,979.18 21.69 -15,682.70 731.16 19,179.21 -91,413.30 -1,995,795.19 -202,570.03 Percent 2.0 Percent -20.3 -8.4 -13.0 -5.7 -14.5 40.6 43.7 39.1 25.3 -33.7 -83.6 -60.9 13.7 - -41.0 2.5 -13.5 7.8 23.7 -79.2 -43.9 -1.7 Note: Does not include lead and lead compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. * Storage only (disposal code M10) indicates that the toxic chemical is sent off-site for storage because there is no known disposal method. Amounts reported as transferred to storage only are included as a form of disposal (off-site release). See Box 1-5. ** Beginning in reporting year 1997, transfers to solidification/stabilization of metals and metal cateogry compounds (waste treatment code M41) are reported separately from transfers to solidification/stabilization of non-metal TRI chemicals (waste treatment code M40). Because this treatment method prepares a metal for disposal, but does not destroy it, such transfers are included as a form of disposal (off-site release). See Box 1-6. Reports under code M40 of metals and metal category compounds have been included in solidification/stabilization of metals and metal cateogry compounds in this report. *** Beginning in reporting year 1997, transfers to wastewater treatment (excluding POTWs) of metals and metal category compounds (waste treatment code M61) are reported separately from transfers to wastewater treatment of non-metal TRI chemicals (waste treatment code M60). Because wastewater treatment does not destroy metals, such transfers are included as a form of disposal (off-site release). See Box 1-6. Transfers of metals and metal category compounds reported under code M60 have been included in transfers of metals and metal category compounds to wastewater treatment. **** Reported as discharges to POTWs in Section 6.1 of Form R. EPA considers transfers of metals and metal category compounds to POTWs as an off-site release because sewage treatment does not destroy the metal content of the waste material. ***** Unknown (disposal code M99) indicates that a facility is not aware of the type of waste management used for the toxic chemical that is sent off-site. Amounts reported as unknown transfers are treated as a form of disposal (off-site release). impoundments (an increase of 43,614 grams or 303 percent) and on-site land releases (an increase of 14,536 grams or 38 percent). Waste Management, 2000-2001 Quantities of TRI Chemicals in Waste, 2000-2001 There was a decrease from 32.57 billion pounds in 2000 to 25.50 billion pounds in 2001 of toxic chemicals managed in waste. This represented a decrease of 22 percent or 7.07 billion pounds. (See Table ES-16.) On-site recycling, the largest type of waste management in 2001, decreased by 8 percent or 577.5 million pounds. On-site treatment, the second largest type of waste management, decreased by 5.27 billion pounds or 43 percent, from 12.20 billion pounds to 6.93 billion pounds. The quantity released on- and off-site decreased by 882.4 million pounds (13 percent) from 6.63 billion pounds to 5.75 billion pounds. On-site energy recovery decreased from 2.78 billion pounds to 2.65 billion pounds, a 5 percent decrease. Off-site recycling also decreased, from 1.93 billion pounds to 1.71 billion pounds, an 11 percent decrease. ES-18 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-16: Quantities of TRI Chemicals in Waste by Waste Management Activity, 2000-2001 Waste Management Activity Recycled On-site Recycled Off-site Energy Recovery On-site Energy Recovery Off-site Treated On-site Treated Off-site Quantity Released On- and Off-site Total Production-related Waste Managed Non-production-related Waste Managed 2000 Pounds 7,592,124,633 1,930,623,241 2,780,607,819 824,053,536 12,200,015,658 612,432,167 6,629,802,444 32,569,659,498 246,448,247 2001 Pounds 7,014,669,655 1,711,348,174 2,646,863,860 826,301,360 6,930,130,624 625,322,518 5,747,374,655 25,502,010,846 38,555,417 Change 2000-2001 Pounds -577,454,977 -219,275,067 -133,743,959 2,247,823 -5,269,885,034 12,890,350 -882,427,788 -7,067,648,652 -207,892,830 Percent -7.6 -11.4 -4.8 0.3 -43.2 2.1 -13.3 -21.7 -84.4 Note: Does not include lead and lead compounds. Data are from Section 8 of Form R of year indicated. Both off-site treatment and off-site energy recovery increased from 2000 to 2001. Off-site treatment increased by 12.9 million pounds or by 2 percent and off-site energy recovery increased by 2.2 million pounds or less than one percent. The quantity of toxic chemicals in non-production- related waste, waste due to remedial clean-up efforts or due to one-time catastrophic events, was lower in 2001 than in 2000. In 2000 it was 246.4 million pounds and in 2001 it was 38.6 million pounds. Transfers Off-site for Further Waste Management, including Disposal, 2000-2001 Transfers of toxic chemicals off-site for further waste management, including disposal, decreased by 133.9 million pounds or 3 percent from 2000 to 2001. In 2000, total transfers were 3.89 billion pounds, and in 2001 they were 3.76 billion pounds. (See Table ES-17.) The decrease in total transfers off-site for further waste management, including disposal, was primarily due to the decrease in transfers to recycling. Transfers to recycling decreased by 181.6 million pounds or 10 percent from 2000 to 2001. Transfers to POTWs was the second largest decrease of almost one million pounds or less than one percent. Other types of transfers increased from 2000 to 2001. Transfers to energy recovery represented the largest increase, of 30.1 million pounds or 4 percent. Other off-site transfers to disposal increased by 17.5 million pounds or 3 percent. TRI DATA FOR 1998-2001 The data used to compare 1998-2001 do not include the PBT chemicals or vanadium or vanadium compounds since some PBT chemicals and vanadium compounds were added to the TRI list of chemicals in 2000 and the reporting definition for vanadium changed. Also, the reporting thresholds for all PBT chemicals changed. Table ES-17: TRI Transfers Off-site for Further Waste Management, including Disposal, 2000-2001 Type of Transfer Transfers to Recycling Transfers to Energy Recovery Transfers to Treatment Transfers to POTWs Metals and metal category compounds Only Non-metal TRI Chemicals Other Off-site Transfers* Other Off-site Transfers to Disposal** Total Transfers for Further Waste Management, including Disposal 2000 Pounds 1,876,943,476 810,195,066 279,302,615 340,854,590 3,070,710 337,783,880 1,090,623 582,217,909 3,890,604,279 2001 Pounds 1,695,305,732 840,324,922 279,663,074 339,864,825 2,162,223 337,702,602 1,766,612 599,730,184 3,756,655,350 Change 2000-2001 Pounds -181,637,743 30,129,856 360,459 -989,764 -908,486 -81,278 675,988 17,512,275 -133,948,929 Percent -9.7 3.7 0.1 -0.3 -29.6 0.0 62.0 3.0 -3.4 Note: Does not include lead and lead compounds Transfers Off-site for Further Waste Management, including Disposal are from Section 6 of Form R * Other Off-site Transfers are transfers reported without a valid waste management code. ** Does not include transfers to POTWs of metals and metal category compounds. 2001 Toxics Release Inventory Public Data Release ES-19 ------- 2001 Toxics Release Inventory Executive Summary Total On-site and Off-site Releases, 1998-2001 Total on- and off-site releases of TRI chemicals decreased by 22 percent from 1998 to 2001, a net decrease of 1.58 billion pounds. On-site releases decreased by 25 percent, but off-site releases (transfers off-site to disposal) increased by 26 percent. The number of facilities and forms reporting each decreased by 7 percent. (See Table ES-18.) All types of on-site releases decreased for the four- year period 1998-2001. On-site land releases decreased by 1.11 billion pounds or 27 percent, with releases to RCRA subtitle C landfills decreasing by 73.9 million pounds or 39 percent and other on-site land releases by 1.03 billion pounds or 26 percent. On-site land releases had increased from 1998 to 1999 but then showed decreases from 1999 to 2001. (See Table ES-18 and Figure ES-2.) Air emissions decreased steadily throughout the period with an overall decrease of 23 percent (499.8 million pounds), with point source air emissions decreasing by 19.5 percent (346.8 million pounds) and fugitive air emissions decreasing by 39 percent (152.9 million pounds). Underground injection also decreased, by 19 percent (50.1 million pounds). However, underground injection increased from 1999 to 2000 with decreases in the other years. Surface water discharges decreased by 13.5 percent (34.2 million pounds) overall from 1998 to 2001 with an increase from 1998 to 1999 and decreases after that. (See Table ES-18 and Figure ES-2.) On the other hand, total off-site releases (transfers off-site to disposal) increased in all years from 1998 to 2001. The net increase in off-site releases was 106.8 million pounds or 26 percent. Transfers of metals and metal category compounds to solidification/stabilization represented the largest increase, of 61.9 million pounds or 149 percent. Transfers to landfills/surface impoundments represented the second largest increase of 51.2 million pounds (19 percent), followed by an increase in transfers off-site to underground injection of 7.8 million pounds (almost 94 percent). Other increases in off-site transfers included transfers to land treatment, which increased by 4.9 million pounds, and transfers of metals and metal category compounds to wastewater treatment facilities that are not POTWs, which increased by almost one million pounds. (See Table ES-18 and Figure ES-2.) Figure ES-2: Distribution of TRI On-site and Off-site Releases, 1998-2001 5,000 4,500 Air Emissions Surface Water Discharges Underground Injection On-site Land Releases Transfers Off-site to Disposal 11998 ]1999 D2000 D2001 Note: Does not include PBT chemicals, vanadium and vanadium compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. ES-20 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-18: TRI On-site and Off-site Releases, 1998 and 2000-2001 Total Facilities Total Forms Form Rs Form As On-site Releases Total Air Emissions Fugitive Air Emissions Point Source Air Emissions Surface Water Discharges Underground Injection Class 1 Wells Class II-V Wells On-site Land Releases RCRA Subtitle C Landfills Other On-site Land Releases Total On-site Releases Off-site Releases Storage Only* Solidification/Stabilization** Metal and Metal Category Compounds Only Wastewater Treatment (Excluding POTWs)*** Metal and Metal Category Compounds Only Transfers to POTWs**** Metal and Metal Category Compounds Only Underground Injection Landfills/Surface Impoundments Land Treatment Other Land Disposal Other Off-site Management Transfers to Waste Broker for Disposal Unknown***** Total Off-site Releases (Transfers Off-site to Disposal) Total On- and Off-site Releases 1998 Number 23,486 85,067 72,125 12,942 Pounds 2,174,480,631 392,823,028 1,781,657,602 253,953,970 258,424,539 232,355,325 26,069,214 4,104,341,065 190,559,741 3,913,781,324 6,791 ,200,204 2000 Number 22,861 83,036 70,079 12,957 Pounds 1,910,893,962 255,413,174 1,655,480,788 266,570,826 269,223,873 239,487,132 29,736,741 3,740,842,968 200,823,801 3,540,019,167 6,187,531,629 2001 Number 21,863 79,175 66,943 12,232 Pounds 1,674,701,620 239,886,238 1,434,815,383 219,722,131 208,280,132 192,332,268 15,947,864 2,997,152,316 116,655,843 2,880,496,473 5,099,856,200 8,068,030 41,657,314 2,766,507 3,551,549 8,322,674 273,598,001 2,214,102 27,181,739 18,232,677 14,583,206 3,887,947 404,063,746 7,195,263,950 9,125,572 73,011,024 6,892,748 3,059,940 20,268,451 302,912,219 5,613,484 21,097,551 16,791,321 13,109,476 5,817,637 477,699,423 6,665,231,053 5,452,214 103,588,597 3,671,352 2,151,530 16,122,953 324,796,579 7,071,250 20,904,535 13,947,438 9,916,611 3,276,626 510,899,685 5,610,755,885 Change 1998-2001 Number -1,623 -5,892 -5,182 -710 Pounds -499,779,010 -152,936,791 -346,842,219 -34,231,839 -50,144,407 -40,023,057 -10,121,350 -1,107,188,749 -73,903,898 -1,033,284,851 -1,691,344,004 Percent -6.9 -6.9 -7.2 -5.5 Percent -23.0 -38.9 -19.5 -13.5 -19.4 -17.2 -38.8 -27.0 -38.8 -26.4 -24.9 -2,615,816 61,931,283 904,845 -1,400,019 7,800,279 51,198,578 4,857,148 -6,277,204 -4,285,239 -4,666,595 -611,321 106,835,939 -1,584,508,065 -32.4 148.7 32.7 -39.4 93.7 18.7 219.4 -23.1 -23.5 -32.0 -15.7 26.4 -22.0 Note: Does not include PBT chemicals, vanadium and vanadium compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. Off-site Releases do not include transfers to disposal sent to other TRI facilities that reported the amount as an on-site release. * Storage only (disposal code M10) indicates that the toxic chemical is sent off-site for storage because there is no known disposal method. Amounts reported as transferred to storage only are included as a form of disposal (off-site release). See Box 1-5. ** Beginning in reporting year 1997, transfers to solidification/stabilization of metals and metal category compounds (waste treatment code M41) are reported separately from transfers to solidification/stabilization of non-metal TRI chemicals (waste treatment code M40). Because this treatment method prepares a metal for disposal, but does not destroy it, such transfers are included as a form of disposal (off-site release). See Box 1-6. Reports under code M40 of metals and metal category compounds have been included in solidification/stabilization of metals and metal category compounds in this report. *** Beginning in reporting year 1997, transfers to wastewater treatment (excluding POTWs) of metals and metal category compounds (waste treatment code M61) are reported separately from transfers to wastewater treatment of non-metal TRI chemicals (waste treatment code M60). Because wastewater treatment does not destroy metals, such transfers are included as a form of disposal (off-site release). See Box 1-6. Transfers of metals and metal category compounds reported under code M60 have been included in transfers of metals and metal category compounds to wastewater treatment. **** Reported as discharges to POTWs in Section 6.1 of Form R. EPA considers transfers of metals and metal category compounds to POTWs as an off-site release because sewage treatment does not destroy the metal content of the waste material. ***** Unknown (disposal code M99) indicates that a facility is not aware of the type of waste management used for the toxic chemical that is sent off-site. Amounts reported as unknown transfers are treated as a form of disposal (off-site release). 2001 Toxics Release Inventory Public Data Release ES-21 ------- 2001 Toxics Release Inventory Executive Summary Table ES-19: Quantities of TRI Chemicals in Waste by Waste Management Activity, 1998 and 2000-2001 Waste Management Activity Recycled On-site Recycled Off-site Energy Recovery On-site Energy Recovery Off-site Treated On-site Treated Off-site Quantity Released On- and Off-site Total Production-related Waste Managed Non-production-related Waste Managed 1998 Pounds 7,391,905,255 1,824,940,788 2,709,965,393 903,081 ,432 6,830,186,859 683,243,121 7,198,915,379 27,542,238,226 25,896,951 2000 Pounds 7,587,287,732 1,926,208,989 2,770,146,731 823,770,927 12,168,278,192 611,514,812 6,532,149,713 32,419,357,097 242,997,578 2001 Pounds 7,010,766,721 1,706,835,713 2,636,089,326 826,113,285 6,911,310,246 624,586,097 5,642,839,652 25,358,541,041 37,461,891 Change 1998-2001 Pounds -381,138,534 -118,105,074 -73,876,067 -76,968,147 81,123,387 -58,657,023 -1,556,075,727 -2,183,697,185 11,564,940 Percent -5.2 -6.5 -2.7 -8.5 1.2 -8.6 -21.6 -7.9 44.7 Note: Does not include PBT chemicals, vanadium and vanadium compounds. Data are from Section 8 of Form R of year indicated. Some types of off-site releases (transfers off-site to disposal) decreased from 1998 to 2001. Transfers to other land disposal decreased by 6.3 million pounds (23 percent) and transfers to waste broker for disposal decreased by 4.7 million pounds (32 percent). Waste Management Data, 1998-2001 Quantities of TRI Chemicals in Waste, 1998-2001 Overall, the quantities of TRI chemicals in waste by all TRI industries decreased by 8 percent from 1998 to 2001, a net decrease of 2.18 billion pounds. The quantity of toxic chemicals in production-related waste managed decreased from 27.54 billion pounds in 1998 to 25.36 billion pounds in 2001. However, the total quantity of toxic chemicals in production-related waste had increased from 1998 to 2000, by 4.88 billion pounds, followed by a decrease of 7.06 billion pounds from 2000 to 2001. (See Table ES-19 and Figure ES-3.) Much of the decrease from 1998 to 2001 came in the quantities released on- and off-site, which decreased by 1.56 billion pounds or 22 percent. Releases on- and off-site decreased steadily each year from 1998 to 2001. The quantities of toxic chemicals recycled, combusted for energy recovery, and treated off-site also decreased. The decrease in on-site recycling was 381.1 million pounds or 5 percent. However, on-site recycling showed decreases and increases in alternating years throughout the 1998 to 2001 Figure ES-3: Distribution of TRI Chemicals in Waste by Waste Management Activity, 1998-2001 14,000 12,000 Recycled On-site Recycled Off-site Energy Recovery Energy Recovery Treated On-site Treated Off-site Quantity Released On-site Off-site On- and Off-site 11998 Q1999 D2000 D2001 Note: Does not include PBT chemicals, vanadium and vanadium compounds. Data are from Section 8 of Form R of year indicated. ES-22 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-20: TRI Transfers Off-site for Further Waste Management, including Disposal, 1998 and 2000-2001 Type of Transfer Transfers to Recycling Transfers to Energy Recovery Transfers to Treatment Transfers to POTWs Metals and Metal Category Compounds Only Non-metal TRI Chemicals Other Off-site Transfers* Other Off-site Transfers to Disposal** Total Transfers for Further Waste Management, including Disposal 1998 Pounds 1,764,052,216 910,148,236 327,002,600 333,858,199 3,551,549 330,306,649 678,007 509,721,375 3,845,460,633 2000 Pounds 1,872,210,590 809,911,478 278,473,901 340,838,435 3,059,940 337,778,495 1,090,611 569,586,827 3,872,111,841 2001 Pounds 1,690,003,762 840,129,629 279,017,884 339,847,710 2,151,530 337,696,180 1,765,114 587,622,422 3,738,386,521 Change 1998-2001 Pounds -74,048,454 -70,018,607 -47,984,716 5,989,511 -1,400,019 7,389,531 1,087,106 77,901,047 -107,074,112 Percent -4.2 -7.7 -14.7 1.8 -39.4 2.2 160.3 15.3 -2.8 Note: Does not include PBT chemicals, vanadium and vanadium compounds. Transfers Off-site for Further Waste Management, including Disposal are from Section ( of Form R. * Other Off-site Transfers are transfers reported without a valid waste management code. ** Does not include transfers to POTWs of metals and metal category compounds. period. Off-site recycling decreased by 118.1 million pounds (6.5 percent) from 1998 to 2001, with increases from 1998 to 2000 and decreases only from 2000 to 2001. Energy recovery on- and off-site both decreased by over 70 million pounds. Off-site treatment decreased by 58.7 million pounds. (See Table ES-19 and Figure ES-3.) Only on-site treatment increased from 1998 to 2001. On-site treatment increased by 81.1 million pounds, by just over one percent, overall from 1998 to 2001, but showed decreases in the most recent period 2000 to 2001. (See Table ES-19 and Figure ES-3.) Transfers Off-site for Further Waste Management, including Disposal, 1998-2001 From 1998 to 2001, total transfers off-site for further waste management, including disposal, decreased by 3 percent or 107.1 million pounds. Such transfers decreased from 3.85 billion pounds in 1998 to 3.74 billion pounds in 2001. However, transfers off-site for further waste management, including disposal, had increased from 1998 to 2000, by 26.7 million pounds, followed by a Figure ES-4: Distribution of TRI Transfers Off-site for Further Waste Management, including Disposal, 1998-2001 Transfers to Recycling Transfers to Energy Transfers to Treatment Transfers to POTWs Recovery Other Off-site Transfers* Other Off-site Transfers to Disposal* 11998 D1999 D2000 D2001 Note: Does not include PBT chemicals, vanadium and vanadium compounds. Transfers Off-site for Further Waste Management, including Disposal are from Section 6 of Form R. * Other Off-site Transfers are transfers reported without a valid waste management code. ** Does not include transfers to POTWs of metals and metal category compounds. 2001 Toxics Release Inventory Public Data Release ES-23 ------- 2001 Toxics Release Inventory Executive Summary decrease from 2000 to 2001 of 13.4 million pounds. (See Table ES-20 and Figure ES-4.) Both transfers to recycling and transfers to energy recovery decreased by over 70 million pounds from 1998 to 2001. Transfers to recycling decreased by 74.0 million pounds or 4 percent, from 1998 to 2001, but had increased from 1998 to 1999. Transfers to energy recovery decreased by 70.0 million pounds or 8 percent from 1998 to 2001, but showed increases from 1999 to 2001. Transfers to treatment also decreased, by 48.0 million pounds or 15 percent, but showed increases in the most recent period from 2000 to 2001. (See Table ES-20 and Figure ES-4.) Transfers to POTWs of metals and metal category compounds decreased by 1.4 million pounds or 39 percent. However, transfers to POTWs of non-metal TRI chemicals increased by 7.4 million pounds or 2 percent. Other types of transfers also increased from 1998 to 2001. Other off-site transfers to disposal increased by 77.9 million pounds or 15 percent, showing increases in each year from 1998 to 2001. (See Table ES-20 and Figure ES-4.) TRI DATA FOR 1988-2001 Year-to-year comparisons of TRI data from 1988 to 2001 are based on a consistent set of chemicals and reporting industries. They do not include chemicals added or deleted since 1988; they do not include chemicals such as the PBT chemicals whose reporting threshold has changed; and they also do not include the industries that were added to TRI reporting in 1998. Total On-site and Off-site Releases, 1988-2001 For the core set of chemicals from industries that have reported consistently since 1988, total on- and off-site releases decreased by 54.5 percent between 1988 and 2001, a reduction of 1.72 billion pounds. At the same time, the number of forms submitted also declined, by 9 percent. On-site releases decreased by almost 64 percent or 1.76 billion pounds. However, off-site releases increased over this period by 12 percent or 46.7 million pounds. (See Table ES-21 and Figure ES-5.) All on-site release categories showed overall decreases from 1998 to 2001. Air emissions have Figure ES-5. Distribution of TRI On-site and Off-site Releases, 1988-2001 Transfers Off-site to Disposal On-site Land Releases Underground Injection Surface Water Discharges Total Air Emissions 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 Note: Does not include delisted chemicals, chemicals added in 1990, 1994 and 1995, aluminum oxide, ammonia, hydrochloric acid, PBT chemicals, sulfuric acid, vanadium and vanadium compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. ES-24 2001 Toxics Release Inventory Public Data Release ------- 2001 Toxics Release Inventory Executive Summary Table ES-21: Comparison of TRI On-site and Off-site Releases, 1988,1998, and 2000-2001 Total Forms Form Rs Form As On-site Releases Total Air Emissions Fugitive Air Emissions Point Source Air Emissions Surface Water Discharges Underground Injection On-site Land Releases Total On-site Releases Off-site Releases Storage Only* Solidification/Stabilization** Metals and Metal Category Compounds Only Wastewater Treatment (Excluding POTWs)*** Metals and Metal Category Compounds Only Transfers to POTWs**** Metals and Metal Category Compounds Only Underground Injection Landfills/Surface Impoundments Land Treatment Other Land Disposal Other Off-site Management Transfers to Waste Broker for Disposal Unknown***** Total Off-site Releases (Transfers Off-site to Disposal) Total On- and Off-site Releases 1988 Number 58,493 58,493 — Pounds 2,177,827,051 679,531,956 1,498,295,095 41,668,109 161,907,957 379,123,257 2,760,526,374 1998 Number 57,825 49,648 8,177 Pounds 1,017,486,824 307,023,499 710,463,324 18,510,162 114,414,728 331,404,582 1,481,816,295 2000 Number 56,385 48,047 8,338 Pounds 802,497,247 183,630,556 618,866,691 15,448,857 111,099,346 283,613,088 1,212,658,538 2001 Number 53,027 45,245 7,782 Pounds 649,457,993 156,891,800 492,566,193 14,641,632 94,949,272 236,733,698 995,782,596 13,668,594 26,620,239 4,521,656 9,373,166 8,510,253 243,616,951 2,229,844 9,200,093 37,056,902 28,335,683 10,069,918 393,203,299 3,153,729,673 5,147,870 122,645,462 2,754,133 3,260,012 10,184,718 209,442,977 524,321 13,089,809 8,698,560 12,060,273 3,344,657 391,152,792 1,872,969,088 7,777,575 132,543,685 6,666,418 3,021,489 19,290,244 224,551,703 2,167,877 7,688,229 7,233,390 11,453,376 3,990,447 426,384,432 1,639,042,971 4,858,034 156,874,378 6,776,955 2,094,688 14,968,456 232,942,848 1,696,882 4,486,807 4,769,138 8,388,361 2,085,101 439,941,648 1,435,724,244 Change 1988-2001 Number -5,466 -13,248 — Pounds -1,528,369,058 -522,640,156 -1,005,728,902 -27,026,477 -66,958,685 -142,389,559 -1,764,743,778 Percent -9.3 -22.6 - Percent -70.2 -76.9 -67.1 -64.9 -41.4 -37.6 -63.9 -8,810,560 130,254,139 2,255,299 -7,278,478 6,458,203 -10,674,103 -532,962 -4,713,286 -32,287,765 -19,947,322 -7,984,817 46,738,349 -1,718,005,429 -64.5 489.3 49.9 -111 75.9 -4.4 -23.9 -51.2 -87.1 -70.4 -79.3 11.9 -54.5 Note: Does not include delisted chemicals, chemicals added in 1990, 1994 and 1995, aluminum oxide, ammonia, hydrochloric acid, PBT chemicals, sulfuric acid, vanadium and vanadium compounds. On-site Releases are from Section 5 of Form R. Off-site Releases are from Section 6 (transfers off-site to disposal) of Form R. Off-site Releases include metals and metal category compounds transferred off-site for solidification/stabilization and for wastewater treatment, including to POTWs. For the years 1998 and after, does not include industries, other than manufacturing industries, that are required to report for 1998 and later years only. * Storage only (disposal code M10) indicates that the toxic chemical is sent off-site for storage because there is no known disposal method. Amounts reported as transferred to storage only are included as a form of disposal (off-site release). See Box 1-5. ** Beginning in reporting year 1997, transfers to solidification/stabilization of metals and metal category compounds (waste treatment code M41) are reported separately from transfers to solidification/stabilization of non-metal TRI chemicals (waste treatment code M40). Because this treatment method prepares a metal for disposal, but does not destroy it, such transfers are included as a form of disposal (off-site release). See Box 1-6. Reports under code M40 of metals and metal category compounds have been included in solidification/stabilization of metals and metal category compounds in this report. *** Beginning in reporting year 1997, transfers to wastewater treatment (excluding POTWs) of metals and metal category compounds (waste treatment code M61) are reported separately from transfers to wastewater treatment of non-metal TRI chemicals (waste treatment code M60). Because wastewater treatment does not destroy metals, such transfers are included as a form of disposal (off-site release). See Box 1-6. Transfers of metals and metal category compounds reported under code M60 have been included in transfers of metals and metal category compounds to wastewater treatment. **** Reported as discharges to POTWs in Section 6.1 of Form R. EPA considers transfers of metals and metal category compounds to POTWs as an off-site release because sewage treatment does not destroy the metal content of the waste material. ***** Unknown (disposal code M99) indicates that a facility is not aware of the type of waste management used for the toxic chemical that is sent off-site. Amounts reported as unknown transfers are treated as a form of disposal (off-site release). decreased steadily over the years 1988 to 2001, with the exception of an increase from 1997 to 1998. Overall, on-site releases decreased 70 percent or 1.53 billion pounds. Surface water discharges decreased by 65 percent or 27.0 million pounds from 1988 to 2001, however, that time period also saw increases as well as decreases. Surface water discharges have decreased since 1998. (See Table ES-21 and Figure ES-5.) On-site underground injection also had an overall decrease of 41 percent or 67.0 million pounds from 1988 to 2001, with several periods of increases within that time period. In the most recent years, underground injection increased from 1999 to 2000 with a decrease reported from 2000 to 2001. On- site land releases fell almost 38 percent or 142.4 million pounds. Increases in on-site land releases were reported from 1994 to 1997, but decreases have occurred each year from 1997 to 2001. (See Table ES-21 and Figure ES-5.) Off-site releases, with an overall increase of 12 percent from 1988 to 2001, have shown increases 2001 Toxics Release Inventory Public Data Release ES-25 ------- 2001 Toxics Release Inventory Executive Summary since 1992 with the exception of the period 1997 to 1998. The largest increases in off-site releases (transfers off-site to disposal) occurred in solidification/stabilization of metals and metal category compounds, an increase of 130.3 million pounds or over 489 percent, and in off-site underground injection, an increase of 6.5 million pounds or 76 percent. Transfers of metals and metal category compounds to wastewater treatment facilities that were not POTWs increased by 2.3 million pounds or 50 percent. (See Table ES-21 and Figure ES-5.) Other types of off-site releases (transfers to disposal) decreased. The amount of chemicals in waste sent to other off-site management decreased, by 32.3 million pounds or 87 percent. Transfers to waste brokers for disposal decreased by 19.9 million pounds or 70 percent. Disposal in landfills/surface impoundments decreased by 10.7 million pounds or 4 percent. UNDERSTANDING THE USES, SCOPE AND LIMITS OF TRI DATA While TRI provides the public, industry, and state and local governments an invaluable source of key environmental data, it has some limitations that must be considered when using the data. Although the Agency has expanded the number of industries that must report, the program does not cover all sources of releases and other waste management activities of TRI chemicals. Although TRI is successful in capturing information on a significant portion of toxic chemicals currently being used by covered industry sectors, it does not cover all toxic chemicals or all industry sectors. In addition, facilities that do not meet the TRI threshold levels (those with fewer than 10 full-time employees or those not meeting TRI reporting quantity thresholds) are not required to report. Thus, while the TRI includes 95,513 reports from 24,896 facilities for 2001, the 6.16 billion pounds of on- and off-site releases reported represent only a portion of all toxic chemical releases nationwide. In addition, while many facilities base their TRI data on monitoring data, others report estimated data to TRI as the program does not mandate release monitoring. Various estimation techniques are used when monitoring data are not available, and EPA has published estimation guidance for the regulated community. Variations between facilities can result from the use of different estimation methodologies. TRI reports reflect releases and other waste management activities of chemicals, not exposures of the public to those chemicals. Release estimates alone are not sufficient to determine exposure or to calculate potential adverse effects on human health and the environment. Although additional information is necessary to assess exposure and risk, TRI data can be used to identify areas of potential concern. TRI data, in conjunction with other information, can be used as a starting point in evaluating exposures that may result from releases and other waste management activities of toxic chemicals. The determination of potential risk depends upon many factors, including the toxicity of the chemical, the fate of the chemical after it is released, the locality of the release, and the populations that are exposed to the chemical after its release. ACCESSING THE TRI DATA The TRI data and data release reports may be accessed through the EPA's TRI home page at http://www.epa.gov/tri. The TRI home page also includes other background information on the TRI program and TRI data as well as information on applicable statutes, regulations and guidance. ES-26 2001 Toxics Release Inventory Public Data Release ------- |