United States      Prevention, Pesticides      EPA712-C-08-003
         Environmental Protection   And Toxic Substances        October 2008
         Agency        (7101)
&EPA   Fate, Transport and
         Transformation Test
         Guidelines
         OPPTS 835.3215
         Inherent
         Biodegradability-
         Concawe Test

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                            INTRODUCTION
      This guideline is one of a series of test guidelines that have been
developed by the Office of Prevention, Pesticides and Toxic Substances
(OPPTS), United States Environmental Protection Agency for use in the testing
of pesticides and toxic substances, and the development of test data to meet the
data requirements of the Agency under the Toxic Substances Control Act (TSCA)
(15 U.S.C. 2601), the Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA) (7 U.S.C. 136, et seq.), and section 408 of the Federal Food, Drug and
Cosmetic (FFDCA) (21 U.S.C. 346a).

      OPPTS developed this guideline through a process of harmonization of
the testing guidance and requirements that existed for the Office of Pollution
Prevention and Toxics (OPPT) in Title 40, Chapter I, Subchapter R of the Code
of Federal Regulations (CFR), the Office of Pesticide Programs (OPP) in
publications of the National Technical Information Service (NTIS) and in the
guidelines published  by the Organization for Economic Cooperation and
Development (OECD).

      For additional  information about OPPTS harmonized guidelines and to
access this and other guidelines, please go to http://www.epa.gov/oppts and
select "Test Methods & Guidelines" on the  left side menu.

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OPPTS 835.3215 - Inherent biodegradability - Concawe test

       (a) Scope—(1) Applicability. This guideline is intended for use in testing
pursuant to the Toxic Substances Control Act (TSCA) (15 U.S.C. 2601).

       (2) Background. This method is based on International Organization for
Standardization (ISO) 14593: Carbon dioxide (CO2)  Headspace Biodegradation
Test and provides a test for assessing  the  inherent aerobic biodegradability of
organic substances.  It is particularly useful for testing insoluble  and/or volatile
materials,  and  was  successfully  ring  tested  in  1996/97 using  a formulated
hydraulic fluid,  hexadecane, di-isotridecyl adipate and two mineral base oils.

       (b)  Purpose. (1)  This  guideline describes a  screening method for the
evaluation of inherent biodegradability of chemical substances. The test is similar
to that described in OECD 310, Ready Biodegradability—CO2 in  Sealed Vessels
(Headspace Test) (see paragraph (g)(2)  of this guideline), in that  both are based
on measurement of CO2 as inorganic carbon in either the headspace or liquid
phase. However, this test uses a mildly pre-exposed inoculum and thus meets the
definition   of  a  test  for  inherent biodegradability.  Unlike other inherent
biodegradation  tests, most notably  Zahn-Wellens/EMPA (OECD 302B) (see
paragraph (g)(3) of this guideline) and the Semi-Continuous Activated Sludge test
(OECD 302A) (see paragraph (g)(4) of this guideline), this method can be used to
test insoluble substances, since biodegradation measurements  are based on CO2
production  rather than dissolved  organic  carbon (DOC) disappearance. The
similar US  Environmental Protection  Agency Test Guideline  835.3100 (see
paragraph (g)(5)  of this  guideline) also  uses  a pre-exposed  inoculum  and
measures CO2 production, but does not include the improvements in measurement
of inorganic carbon that are in OECD 310 (see paragraph (g)(2) of this guideline)
and which solved difficulties experienced with the Sturm test (OECD 301B) and
similar methods (see paragraph (g)(2) of this guideline).

       (2) A substance yielding a positive result in this test may be classified as
inherently biodegradable, which, preferably,  should be qualified by the term "with
pre-adaptation". Because of the favorable conditions employed in this test, rapid
biodegradation in the environment of inherently biodegradable chemicals cannot
be assumed.

       (c)  General  considerations—(1) Principle  of  the  test,  (i)  The  test
substance  is incubated in a buffered,  mineral salts medium which  has  been
inoculated with a mixed population of microorganisms. In order to enhance the
biodegradative potential of the inoculum, it is pre-exposed to the test substance
using a regime based  on methods described  in US Environmental  Protection
Agency Test Guideline  835.3100 (see paragraph (g)(5) of this guideline). The test
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is performed in sealed bottles with a headspace of air that provides a reservoir of
oxygen (02) for aerobic biodegradation. CC>2 evolution from the ultimate aerobic
biodegradation of the test substance is determined by measuring the inorganic
carbon  (1C) produced in the  test bottles over that produced  in  blanks which
contain  inoculated  medium  only.  Aerobic  ultimate  biodegradation  is  the
breakdown of an  organic  chemical  by microorganisms  in the presence of  C>2,
resulting in the production of CC>2, water, mineral salts of various elements and
microbial cellular constituents (biomass). The extent of biodegradation is then
expressed as a percentage of the theoretical maximum 1C production  (ThIC),
based on the quantity of test substance (as total organic carbon) added initially.

       (ii) DOC  removal (water-soluble substances only) and/or the extent of
primary  biodegradation  of the test substance can also be measured. Primary
biodegradation is the structural change (transformation) of an organic chemical by
microorganisms resulting in the loss of a specific property.

       (2) Information  on the test substance. The organic carbon content (%
w/w) of the test substance needs to be known either from  its chemical structure or
by measurement.  For volatile  test substances, a measured or calculated Henry's
law  constant  is helpful for determining a suitable headspace-to-liquid  ratio.
Information  on the toxicity of the test substance to bacteria is useful for selecting
an  appropriate test  concentration  and for  interpreting results  showing  poor
biodegradability. As this test is usually performed only after failure to pass a test
for ready biodegradability (see paragraph (g)(6) and (g)(7) of this guideline),  the
physical and inhibitory properties may already have been ascertained.

       (3) Applicability of the method. The test is applicable to water-soluble
and insoluble test substances. Using the recommended headspace to liquid ratio of
1:2, volatile substances with a Henry's law constant of up to 50 Pa m3 mol"1 can
be tested, as the proportion of test substance in the headspace will not exceed  1%
(see paragraph (g)(8) of this guideline). A smaller headspace volume may be used
when testing more volatile substances. However, users should ensure that  the
headspace-to-liquid ratio and  the  test substance concentration are  such that
sufficient C>2 is available to allow complete aerobic biodegradation to occur (e.g.,
avoid using  both  a high  substrate concentration and  a small headspace volume).
Guidance on this can be found in paragraph (g)(9) of this guideline.

       (4) Reference substances (i)  In  order to  check the test procedure, a
reference substance of known biodegradability should be tested in parallel. For
this purpose, w-hexadecane or a  rapeseed (Canola)  oil with a low  (<2%  w/w)
erucic  acid  content,  is recommended when testing insoluble test substances.
Sodium  benzoate  is recommended when testing water-soluble test substances.
Biodegradation of these substances should reach 60% ThIC by the end of the test.
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       (ii) To demonstrate the increased biodegradative power of the test over a
ready biodegradability test, di-isotridecyl adipate (DITA) can be used as a more
difficult-to-biodegrade  reference substance.  DITA is typically biodegraded by
only about 30% ThIC after 28 days with an unexposed inoculum (e.g. in a 301B
test; see paragraph (g)(6)  of this guideline), but can be mineralized by 40-80%
ThIC in this test.  DITA  is a reference oil  (RL  130) for the  CEC  L-33-A-93
biodegradability test and details on how to obtain it can be found in the reference
in paragraph (g)(10) of this guideline.

       (5) Reproducibility—(i) Based on the CONCAWE 1996/97 ring test of
the method (see paragraph (g)(l)  of this guideline), the difference between two
single  and independent test results obtained by different operators, working in
different laboratories and on the same test substance, would exceed 38% only in
one case in 20.

       (ii) In the CONCAWE 1996/97 ring test of the  method (see paragraph
(g)(l)  of this  guideline), the results  in Table  1  were  obtained  using  the
recommended test conditions.

  Table 1. Results from  1996/97 CONCAWE ring test for two substances.
Test substance
(Both insoluble)
w-Hexadecane
Di-isotridecyl adipate (DITA)
Mean Percentage
biodegradation
(Day 56)
72
65
Coefficient of
variation
(%)
21%
21%
Number of
laboratories
10
10
For these two  insoluble test  substances,  the  variability (as the coefficient of
variation) between replicates in the same test run was <10% for laboratories that
were experienced in using the method.

       (d) Description  of  the method—(1)  Apparatus.  Normal laboratory
apparatus and the equipment  in paragraphs (d)(l)(i)  through (d)(l)(ix) of this
guideline.

       (i) pH meter;

       (ii) Analytical instruments such as for gas-liquid, high-performance liquid
or thin layer chromatography;

       (iii) Glass serum bottles, sealed with butyl rubber stoppers and crimp-on

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aluminum seals. The recommended nominal size is 125 ml, which has an actual
total volume ca. 160 ml;

       (iv) Carbon analyzer or other instrument(s) (e.g. gas chromatograph) for
measuring inorganic carbon;

       (v) Syringes of high precision for gaseous and liquid samples;

       (vi) Orbital shaker in a temperature-controlled environment;

       (vii) A supply of CO2-free air. This can be prepared by passing air through
soda lime granules or by using  an 80% N2/20% O2 gas mixture;

       (viii) Membrane filtration device of 0.20 - 0.45 jim porosity (optional);

       (ix) Organic carbon analyzer (optional).

       (2) Reagents. Use analytical grade reagents throughout.

       (3) Water. Distilled or  deionized water that contains less than or equal to
1 mg total C per L should be used. This amount of C represents at most 5% of the
initial organic carbon content  introduced by  the recommended dose of the test
substance.

       (4) Stock solutions for the mineral  salts medium (i) The stock solutions
and the mineral salts medium  are similar to those employed in ISO 14593 (see
paragraph (a)(2) of this guideline) and Organization  for Economic  Cooperation
and Development (OECD) 301 ready biodegradability tests (see paragraphs (g)(6)
and (g)(7)  of this  guideline). However, it should be noted that solution A (see
paragraph  (d)(4)(iii)(A)  of  this guideline) contains  a higher concentration  of
ammonium  chloride  to reduce the  possibility  of biodegradation  becoming
nitrogen-limited.

       (ii)  Stock solutions should be  stored under refrigeration  and discarded
after  six  months, or  earlier,  if  there  is  evidence of microbial  growth  or
precipitation.

       (iii) Prepare  the stock solutions  in  paragraphs  (d)(4)(iii)(A) through
       (A) Solution A.
       Potassium dihydrogen phosphate (KH^PO^  ....................................... 8.50g
       Dipotassium hydrogen phosphate (K^HPO^                      21.75g
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       Disodium hydrogen phosphate dihydrate (Na2HPO4-2H2O)	33.40g
       Ammonium chloride (MLjCl)	2.00g
       Dissolve in water and add water to 1 liter. The pH of this solution should
be 7.4 (± 0.2). If this is not the case, prepare a new solution.

       (B) Solution B.
       Calcium chloride dihydrate (CaCl2-2H2O)  	36.40g
       Dissolve in water and add water to 1 liter.

       (C) Solution C.
       Magnesium sulfate heptahydrate (MgSO4.7H2O)	22.50g
       Dissolve in water and add water to 1 liter.

       (D) Solution D.
       Iron (III) chloride hexahydrate (FeCl3.6H20)	0.25g
       Dissolve in water and add  water to 1  liter, then add one drop  of
concentrated HC1.

       (5) Preparation  of the mineral salts medium. Mix  10 ml of solution A
with approximately 800 ml water (see paragraph (d)(3) of this guideline),  then
add 1 ml each of solutions B, C and D, and add water to 1 liter.

       (6) Inoculum, (i) General. The test uses a composite  microbial inoculum,
derived from  soil and a wastewater treatment plant, which has been preexposed to
the test substance.  In  order to maximize the biodegradation potential of the test,
samples can be taken from locations where preexposure to the test substance or
similar materials may already have occurred (e.g. contaminated soil, industrial
biotreater).

       (ii)  Soil. Clear the soil surface of leaf litter and collect a sample to a depth
of up  to 20 cm  below  the soil  surface. Transport in  a loosely tied black
polyethylene bag. Remove stones, plant debris and invertebrates from the soil and
pass through a 2 mm mesh sieve (if the soil is too wet to sieve immediately,  then
partially air dry  the soil to facilitate sieving). If the sieved soil will not be  used
immediately,  then it can be stored at 2 to 4°C in a loosely-tied black polythene
bag for up to one month. Further guidance on collection and handling of soil
samples may be found in the reference in paragraph (g)(l 1) of this guideline.

       (iii) Activated  sludge.  Collect  activated sludge  from  a wastewater
treatment plant and keep aerated at 20 ± 1°C until use (this should be within two
days of collection).

       (iv) Preexposure procedure. (A) To 1 liter mineral salts medium, add 1 g
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prepared soil, 2 ml activated sludge and 50 mg/L yeast extract (e.g. Oxoid, Difco).
Adjust the pH (if necessary) to 7.4 ± 0.2 and dispense 100 ml aliquots into conical
flasks  of 250  to 300  ml volume. Keep the  suspension  well mixed while
dispensing. Add  4  mg/L  as  carbon of test substance to replicate flasks.  The
number of flasks needed will  depend on  the  volume of inoculum needed  to
perform the test. Close the flasks with stoppers that will allow gaseous exchange
(e.g. foam stoppers or aluminum caps) and incubate at 20 ± 1°C, with shaking or
mixing at  a rate sufficient  to keep  the  flask  contents well  mixed  and  in
suspension. Losses of a volatile test substance may occur during this procedure.

       (B)  On  or  around day 7  and day  11  of  incubation,  make up  any
evaporation losses of test medium  with  water, adjust the pH (if necessary)  to
between  7.2 and  7.6, and add 8 mg/L as carbon of test substance to each flask.
The final addition of test substance should be made at least three days before the
inoculum is used for the test.

       (C)  On the day of the test (normally day 14 of preexposure) coarse-filter
the inoculum through a number 4 grade filter paper or glass wool and keep shaken
until use. If two or three substances are being tested, the preexposed cultures for
each test substance can be pooled to give a composite inoculum. This reduces the
number of blanks needed  and  provides  a  microbial  population that has been
exposed to more than one test substance.

       (D)  The inoculum is  normally used within  one day. If problems with
invalid (i.e. too high) blank inorganic carbon production (see paragraph (f)(4)(i)
of this guideline) have been encountered,  or are thought likely to occur, then one
or both of the following treatments  designed to reduce inorganic carbon content
are recommended:

       Treatment 1: Aerate the inoculum overnight before use;

       Treatment 2: Before use, sparge the inoculum with CO2-free air for about
one hour, while maintaining  the pH at 6.5  using orthophosphoric acid. Finally,
restore the pH to its original value.

       (e) Test procedure—(1) Number of bottles,  (i) The number of bottles
needed for a test will depend on the frequency of analysis and the test duration. It
should be noted  that the  test may have to be continued beyond the 56 days
suggested in paragraph (e)(5) of this guideline.

       (ii) It is recommended that at least five bottles from each of bottle sets 1, 2
and 3 (see paragraph (e)(3)(ii) of this guideline) be analyzed at the end of the test,
to enable 95% confidence intervals to be  calculated for the mean percentage

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biodegradation value.

       (2) Inoculated medium. The inoculum is used at a concentration of 10%
v/v (e.g. add 100 ml inoculum to 900 ml mineral salts medium).

       (3)  Preparation of  bottles, (i)  Aliquots of inoculated  medium  are
dispensed into replicate bottles to give a headspace-to-liquid ratio of 1:2 (e.g. add
107 ml to 160 mi-capacity bottles). Other ratios may be used but see the warning
given in paragraph (c)(3) of this guideline.

       (ii)  Sets  of  bottles  should  be  prepared as  outlined  in  paragraphs
(e)(3)(ii)(A) through (e)(3)(ii)(E) of this guideline.

       (A) Bottle set 1:  Contains test substance (held on a glass fiber filter, if
necessary-see  paragraph  (e)(3)(iv)  of  this  guideline)   at  a  recommended
concentration of 20 mg/L as organic carbon;

       (B) Bottle set 2:  Blanks containing inoculated medium  (and a glass fiber
filter, if necessary) only;

       (C) Bottle  set 3:    Contains reference  substance  at  a  recommended
concentration of 20 mg/L as organic carbon (and a glass fiber filter, if necessary).

       (D) Bottle set 4:  Same as bottle set 1, plus 50 mg/L HgCl2 or sterilized by
some other means (e.g. by autoclaving).

       (E) Bottle set 5:  Contains the test substance plus the reference substance
at the same concentrations used in bottle sets 1 and 3.

       (iii) Water-soluble test and reference substances are added from aqueous
stock solutions.

       (iv) Insoluble test and reference substances can be added to bottles as a
measured weight absorbed  on a GF/A glass fiber filter (21  mm diameter) or by
direct injection using a microsyringe.

       (A) Use of a glass fiber filter enables an accurate weight to be dosed into
each bottle and increases bioavailability. Weighing can be facilitated by preparing
a  stock   solution  of  the  substance  in   a  suitable  volatile  solvent  (e.g.
dichloromethane) and adding the required volume dropwise to a tared filter on an
analytical balance. An attempt should be made to spread the substance over the
filter. The solvent is then allowed to evaporate until a stable weight (or nominal
test weight) is obtained.  For example, 100  ^1 of a 21.4 mg/mL as carbon stock
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solution  of test  substance added to a  filter  gives  2.14 mg  carbon as  test
substance/filter,  thus 20  mg  carbon/L when  added  to  107 ml of inoculated
medium. The measured weight of test substance on the filter should be used to
calculate the test dose (see paragraph (f)(l)(i) of this guideline).

       (B) If insoluble test or reference substance is injected into sealed bottles
using a microsyringe, the syringe should  be weighed before and after dosing to
enable an accurate test dose to be calculated.

       (v)  If the  procedure given in paragraph  (e)(3)(iv)(A) of this guideline is
used, then blank bottles (bottle set 2) should contain either a filter or a filter from
which  an equivalent volume  of solvent  has been evaporated  (removal of the
solvent should be checked by weighing).

       (vi) Volatile test substances should be injected  into sealed bottles using a
microsyringe. The syringe should be weighed before and after dosing to enable an
accurate test dose to be calculated.

       (vii) All the bottles are then sealed and time zero analyses are performed
for initial 1C concentration, DOC concentration, or other determinants.

       (4) Incubation. The bottles are incubated in the dark or diffuse light at 20
± 1°C, with shaking at a rate sufficient to keep the bottle contents well mixed and
in suspension (e.g. 150 to 200 rpm).

       (5)  Sampling. Replicate test (Bottle  set 1), blank (Bottle set 2), reference
(Bottle set  3), and inhibition control (Bottle set  5) bottles should be taken for 1C
analysis periodically, in order to obtain the biodegradation curves. Normally this
is done at least once each week. At the end of the test,  the sterile controls (Bottle
set 4)  should also be analyzed.  The test  normally  runs  until biodegradation
reaches a plateau. As a guide, users should plan for an  eight-week test. However,
the test can be continued if biodegradation is still occurring on  day 56. It is not
advisable to continue the test beyond three months.

       (6)  Inorganic carbon (1C) analysis, (i) CC>2 production in the bottles is
determined by measuring the increase in the concentration of 1C. There are  two
methods available for measuring the amount of 1C produced in the test, described
in paragraphs (e)(7) and (e)(8) of this guideline.  As the methods  can give slightly
different results, only one should be used in a given test run.

       (ii) Method A (see  paragraph (e)(7) of this guideline) is  recommended if
the liquid  medium is likely to contain  the remnants of a GF/A filter and/or
insoluble  test  substance.  This  analysis   can be   performed  using  a  gas

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chromatograph if a carbon analyzer is unavailable. It is important that the bottles
should be at or close to the test temperature of 20 ± 1°C when the headspace gas
is analyzed. Method B (see paragraph (e)(8) of this guideline) can be easier for
laboratories using carbon analyzers to measure 1C. It is important that the sodium
hydroxide solution used to convert CC>2 to carbonate is either freshly prepared or
its 1C content is  known, so that this can taken into account when calculating the
test result.

       (7) Method A:  acidification to pH <3. (i) Calibrate the 1C analyzer using
an appropriate 1C standard (e.g.  1% w/w CC>2 in N2). Inject concentrated (85%
w/v) orthophosphoric acid through the septum of each test bottle sampled to lower
the pH of the medium  to <3 (e.g. add 1  ml to  107 ml  test medium). Replace the
bottles on the shaker.  After shaking for  one  hour  at the test temperature (20 ±
1°C), remove the bottles from the shaker, withdraw aliquots (e.g. 1 ml) of gas
from the headspace  of each bottle and  inject into the 1C analyzer.  Record the
measured 1C concentration (mg carbon/L).

       (ii)  The principle of this  method  is that after acidification to pH <3  and
equilibration  at 20°C, the equilibrium constant for the distribution of CCh between
the liquid and gaseous phases in the test bottles is  1.0 (see paragraphs (g)(l),
(g)(8) and  (g)(12) of this guideline). This should be demonstrated for the  test
system at  least  once  (e.g. at the end  of the test)  as follows:  set up  bottles
containing  5  and 10 mg IC/L using a solution of anhydrous sodium carbonate
(Na2CO3) in  CO2-free water (prepared by  acidifying water to  pH  6.5 with
concentrated  orthophosphoric acid,  sparging  overnight with CCh-free air  and
raising the pH to neutrality with alkali). Ensure that  the ratio of the headspace
volume to  the liquid volume is the same as in the tests (e.g. 1:2). Acidify  and
equilibrate as described in paragraph (e)(7)(i) of this guideline, and measure the
1C concentrations of both the headspace and liquid phases. Check that the two
concentrations are the same within experimental error.

       (iii) If DOC  removal is  to be measured (water-soluble test substances
only),  take samples of  the  liquid phase  from separate (unacidified) bottles,
membrane filter and  inject into the  carbon analyzer. These bottles can be used for
other analyses as necessary.

       (8)  Method B: conversion of COi to carbonate, (i) Calibrate the 1C
analyzer  using  an   appropriate  standard-for  example, a solution  of sodium
bicarbonate (NaHCOs) in CO2-free water in the range 0 to 20 mg IC/L. Inject 7 M
sodium hydroxide (e.g. 1 ml to 107 ml of medium) through the septum of each
test bottle sampled  and shake for  one hour at the test temperature (20 ± 1°C).
Remove  the bottles from the shaker,  allow to settle,  and  withdraw, by syringe,
suitable volumes (e.g.  50 to 200 jil)  from the liquid phase in each vessel. Inject
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the samples into the 1C analyzer and record the concentration of 1C.

       (ii)  The principle of this method is that after the addition of alkali and
shaking, the concentration of 1C in the headspace is negligible.  This should be
checked for the test system at least once (e.g. at the end of the test) by using 1C
standards, adding alkali and equilibrating, and measuring the concentration of 1C in
both the headspace and liquid phases.

       (iii) If DOC removal is to be measured  (water-soluble  test substances
only),  take samples  of the liquid  phase  from  separate bottles  (no alkali),
membrane filter and inject into the  carbon analyzer. These bottles can be used for
other analyses as necessary.

       (f)  Data and reporting—(1) Calculation of results, (i) Assuming  100%
mineralization  of the test  substance to CC>2,  the theoretical  maximum 1C
production  (ThIC) in excess of that produced in the blanks equals the amount of
total organic  carbon (TOC)  from the test substance added to each bottle  at the
start of the test. For insoluble  substances, TOC  should be calculated  from the
measured  weight  of test  substance (absorbed  onto  the filter or added by
microsyringe),  and its organic carbon content.  For volatile  substances,  TOC
should be calculated from the measured weight of test substance dispensed by
microsyringe, and its organic carbon content.

       The total mass (mg) of inorganic carbon (TIC)  in each bottle is:

        TIC = (mg C in the liquid + mg C in the headspace)
            = (VL x CL) + (VH x CH)                           Equation [ 1 ]

where :
        VL = volume of liquid in the  bottle (liter);
        CL = concentration of 1C in the liquid (mg/L as carbon);
        VH = volume of the headspace (liter);
        CH = concentration of 1C in the headspace (mg/L as carbon).

       (ii)  The  calculation  of TIC  for the two analytical methods  used for
measuring 1C in this test is described in this paragraph. Percentage biodegradation
(% D) in each case is given by:


        %D = (TICt-TICh) x 100
                  TOC
where :
        TICt = mg TIC in test bottle at time t;

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        TICb = mean mg TIC in blank bottles at time t;
        TOC = mg TOC added initially to the test vessel.

Determine  total  %D  for  the test (Bottle set 1),  reference (Bottle  set  3)  and
inhibition control bottles  (Bottle  set 5), from the cumulative  amounts of TIC
produced up to each sampling time.

       (iii) If there has been a significant increase in the TIC content of the sterile
controls (Bottle  set 4) over the test period, then abiotic degradation of the test
substance has occurred.

       (2) Calculation of TIC for analytical Method A. Acidification to pH <3
and equilibration results in the equalization of the concentration of 1C in the liquid
and gaseous phases. Hence only the concentration of 1C in the gas phase needs to
be measured, as CL = CH. Therefore TIC = (VL + VH) x CH in Equation [1].

       (3)  Calculation  of TIC  for  analytical  Method B.  In this method
calculations are performed as described in Equation [1] but the negligible amount
of 1C in the gaseous phase is ignored; i.e. VH x CH in Equation [1] is set to zero.

       (4) Validity of results, (i) The test is considered as valid if:

       (A) The mean percentage biodegradation of n -hexadecane,  low erucic
acid-containing rapeseed oil (canola oil) or sodium benzoate reaches at least 60%
ThIC by the end of the test; and

       (B) The mean amount of 1C produced from the blanks at the end of the test
is no more than 15% of the organic carbon added initially as the test substance to
the test bottles.

       (C) If these criteria are not met, repeat  the test with another inoculum
and/or review procedures. For example, if high blank 1C production is a problem
then follow the procedures given in paragraph (d)(6)(iv)(D) of this guideline.

       (ii)  It can be assumed that  the test  substance is inhibitory if the mean
percentage degradation in the inhibition control bottles (Bottle set 5) is <25% by
the end of the test. In this case, the test can be repeated with a lower concentration
of test substance (e.g. 10 mg/L  as carbon). However, it should be noted that this
will  reduce the precision of the method. If lower test substance concentrations are
used, it is important that blank  1C production is as low as possible and that the
smaller amount of test substance can be dosed accurately.

       (5) Interpretation of results, (i) Biodegradation greater than 70% ThIC
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in this  test demonstrates that the test  substance is  inherently and  ultimately
biodegradable under aerobic conditions.

       (ii) Biodegradation less than or equal to 20% ThIC is an indication that the
test substance is  not inherently biodegradable under the conditions of this test.
However, this does  not rule out metabolism under different circumstances (e.g.
with a longer preexposure period and/or higher biomass-to-test substance ratio).

       (iii) Biodegradation greater than  20% ThIC is an indication that the test
substance has inherent, primary biodegradability.

       (iv) If more information  is  needed  on the potential  fate of  the  test
substance, then  further investigations such as DOC analysis  to  detect water-
soluble metabolites may be useful.

       (6) Test  report, (i)  Compile  a table of %D for each test (Bottle set 1),
reference (Bottle set 3) and inhibition control bottle (Bottle set 5) for each day
sampled. If comparable results are obtained for replicate bottles, plot  a curve of
mean %D against time. Record the amount of TIC in the blanks (Bottle set 2), and
in the sterile  controls (Bottle set 4). If determined, also record the levels  of DOC
and/or other determinants and their percentage removal.

       (ii) Determine the mean value of %D in  the plateau phase,  or use the
highest value if the biodegradation curve decreases after peaking, and  report this
as the extent  of biodegradation of the test substance. It is important to ensure that
in the latter case the highest value is not an outlier.

       (iii)  The  test  report  should include  the  information in   paragraphs
(f)(6)(iii)(A) through (f)(6)(iii)(C) of this guideline:

       (A) Test substance:

       (1) Common name, chemical  name,  CAS number, structural formula and
relevant physical-chemical properties;

       (2) Purity (impurities) of test substance.

       (B) Test conditions:

       (1) Description  of the  test  system used  (e.g.  volume of the  vessel,
headspace-to-liquid ratio, method of stirring, etc);

       (2) Application of test substance and reference substance to test system:
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test concentration used and amount of carbon dosed into each test bottle, and any
use of solvents;

       (3) Details of the inoculum used, its preexposure to the test substance and
any preconditioning (e.g. overnight aeration);

       (4) Incubation temperature;

       (5) Validation of the principle of 1C analysis;

       (6) Main  characteristics of the 1C  analyzer  employed  (and  any other
analytical methods used);

       (7) Number of replicates.

       (C) Results:

       (1) Raw data and calculated values of biodegradability in tabular form and
degradation curves;

       (2) Reasons for any rejection of the test results;

       (3) Any other facts that are relevant to the procedure followed;

       (4) Discussion of results.

       (g) References.

       (1) Battersby, N.S., D. Ciccognani, M.R. Evans, D.  King, H.A. Painter,
D.R. Peterson, and M. Starkey (CONCAWE Biodegradation Task Force) (1999).
An 'inherent' biodegradability test for oil products: description  and  results of an
international ring test. Chemosphere 38, 3219-3235.

       (2)OECD  (2006).  Ready Biodegradability-CO2   in  Sealed  Vessels
(Headspace Test), no. 310, adopted 23 March 2006, Organization for Economic
Cooperation and Development, Paris.

       (3) OECD (1992). Inherent Biodegradability: Zahn-Wellens/EMPA Test,
no. 302A, adopted  17 July 1992.  Organization for Economic  Cooperation  and
Development, Paris.

       (4) OECD (1981). Inherent Biodegradability:  Modified SCAS Test, no.
302A, adopted 12  May 1981.  Organization  for Economic Cooperation  and
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Development, Paris.

       (5) US EPA (1996). Aerobic aquatic biodegradation, Fate, Transport and
Transformation   Test  Guidelines  835.3100.  U.S.  Environmental  Protection
Agency, Washington, DC.

       (6) OECD (2007). Ready biodegradability, no. 301, adopted 17 July 1992.
Organization for Economic Cooperation and Development, Paris.

       (7) US  EPA    (1996).  Ready  biodegradability. Fate, Transport  and
Transformation   Test  Guidelines  835.3110.  U.S.  Environmental  Protection
Agency, Washington, DC..

       (8) Struijs,  J.  and J. Stoltenkamp (1990).  Headspace  determination of
evolved carbon  dioxide in a biodegradability screening test. Ecotoxicol. Environ.
Safe. 19,204-211.

       (9) Struijs, J., MJ. Stoltenkamp-Wouterse and A.L.M. Dekkers (1995). A
rationale for the appropriate amount of inoculum in ready biodegradability tests.
Biodegradation 6, 319-327.

       (10) CEC (1995). Biodegradability of two-stroke cycle outboard engine
oils in water, Method CEC L-33-A-93. Coordinating European Council for the
Development of Performance Tests for Lubricants and Engine Fuels.

       (11) Farmer, D. and R. Bartha (1972).  Preparation of soil samples for
biodegradation testing. Environ. Lett. 2,217-224.

       (12) Battersby, N.S. (1997).  The ISO CO2 headspace biodegradation test.
Chemosphere 34, 1813-1822.
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