U.S. Environmental Protection Agency Office of Research and Development June 2001 NATIONAL EXPOSURE RESEARCH LABORATORY JVTERI, £001 »^^^^^^^^^^L^_^^L^^jB ilta^^^^^- Volume 4, Issue 2 In This Issue Click On A Topic Research "MIMS" the Word Detecting Dangerous Molds COPP Exposure Behind the Wheel More Research Top Side A Tale of Success Multi-year Planning HPO Update NERL Notables Awards Open House Feedback "Doing Your Thing" Behind the Boss' Back... Task Information "MIMS" the Word Models form the cornerstone of virtually every regulatory program and policy deci- sion in the EPA. Models are used for set- ting discharge limits for point sources to waterways, for registering pesticides, for determining whether a waste should be "listed" as hazardous, and for guiding State plans that determine allowable limits for air pollution sources, just to name a few ex- amples. No one knows exactly how many models EPA uses or sanctions for use, but the number is certainly in the hundreds, and most share one characteristic: they have been developed to support a single regulatory pur- pose. The result has been that existing models tend to focus on the sources, transport, and fate of particu- lar pollutants of concern, and often on a narrow range of sources and/or media of concern. Typically, all other things (sources, pathways, media, receptors) are treated as equal, and the models reflect time and space scales peculiar to the regulatory or policy decision, whether or not there are other relevant processes occurring at other time and space scales (e.g., local versus re- gional, or daily versus seasonal averages). Inputs to the model from other media, or occurring at other scales, are usually treated as forcing functions or parameters that are not themselves influenced by the processes being simulated by the model, and the be- havior of receptors is often treated simplis- tically or ignored. Increasingly, however, a broader environmental scope must be con- sidered to understand all of the contribu- tions and interactions that might have a significant effect on policy options and deci- sions. The recent attention to Total Maximum Daily Loads (TMDLs) under section 303 of the Clean Water Act provides a good ex- ample. For all water bodies not attaining their designated use, States must determine the Total Maximum Daily Load of the pollutant(s) allowed to enter that water body (with an ad- equate margin of safety) and still allow it to attain its desig- nated use. The State then must allocate the current loads of the pollutant It's clear there is a pronounced need for a flexible, Multimedia Integrated Modeling System (MIMS) that will allow scientists to efficiently and effectively couple the kinds of models already developed for single media, single scale applications into a functioning modeling system suitable for the environmental management decisions of the next decade. ous present and anticipated fu- ture sources and devise an implementation plan for reducing pollutant inputs from the various sources to achieve the TMDLs. In the case of nitrogen, a pollutant which threatens roughly one third of the estuaries in the U.S., sources include atmospheric deposition from power plants, cars, trucks, boats, lawnmowers, fertilizer applications, and land application of fertilizer or animal manure ranging in scales from hundreds of miles distant to a few tens of meters from the receiving stream. Other sources include storm water runoff from streets, golf courses, and farms (including overflows from wastewater treatment plants and ------- Research Research Top Side NERL Notables Feedback lagooned animal wastes), septic tank drainage, soil mineraliza- tion, and even atmospheric deposition that enters the water body as groundwater. Allocating the nitrogen load among the various sources requires a model that can accurately simulate the movement of nitrogen from the atmosphere to the land and water surfaces (and vice-versa), the movement of nitro- gen from point and non-point sources to groundwater and surface water channels (with particular attention to storms), the movement of nitrogen through groundwater to the water body, and eventually the behavior of nitrogen in the estuary, in addition to quantifying the uncertainties involved. NERL began development of the Multimedia Integrated Modeling System (MIMS) three years ago, building on the success of integrating several air quality and meteorological models into the Models-3/Community Multi-scale Air Qual- ity (CMAQ) model now used by EPA's Office of Air Quality Planning and Standards, and the States to evaluate and sup- port air quality management decisions across the U.S. The project has involved two closely interacting activities: • Developing better models for air, water, soil, and recep- tor interactions and • Developing a MIMS software framework. An important early success has been the development of the Frames/3MRA Model in conjunction with the Hazardous Waste Identification Rule (HWIR). This model simulates the movement of any of a large number of potentially hazardous substances away from a waste site through air, water, and groundwater pathways, and their ultimate exposure to hu- mans and wildlife, along with the associated uncertainty. The model is user-friendly and is appropriate for use at individual sites, as opposed to regions. We are studying nitrogen in the Neuse River Basin in North Carolina, because it spans many issues that are or will be common to solving problems in a multimedia framework at multiple scales (e.g., site to region) and involves feedback among the different media and pollutants. [See Virtual Field Reference Database article.] The Neuse nitrogen issue chal- lenges us because we must work in a complex watershed and with a pollutant that originates from a myriad of sources trav- eling though all major media. [See NEXRAD article.] The MIMS framework that will be evaluated during the Neuse modeling effort is intended to provide a software in- frastructure for constructing, composing, and applying multi- scale, cross-media models, and evaluating and applying the results to the watershed management needs of the States and Tribes. The MIMS framework will allow multimedia model- ers to focus more on the science and less on the mechanics of acquiring and applying new combinations of models and data. By designing the framework with an open architecture and working with external modelers and framework develop- ers, the MIMS team is working to foster a community ap- proach to multi-disciplinary ecosystem modeling and analysis. This community approach is critical. The Models-3/ CMAQ effort, Frames/3MRA, and the Neuse projects have involved modelers working in several NERL divisions, the EPA Programs and Regions, the States, other federal agen- cies, and independent academic grantees. To promote future progress, ORD has entered into an interagency Memoran- dum of Understanding with the Nuclear Regulatory Commis- sion, Corps of Engineers, and Departments of Energy, Interior, and Agriculture to promote coordination across the federal agencies with an environmental mission. Gary Foley, NERL Director, (919) 541-2106 NERL Task #6449 Detecting Dangerous Molds Two NERL-Cincinnati scientists have developed an inno- vative way to detect potentially dangerous molds much faster and with greater accuracy. The new technology can be used to detect the mold Stachybotrys, commonly known as "black mold," and more than 50 other possibly problematic molds. •S *22 f Richard Haugland and Stephen Vesper Molds typically grow in buildings affected by water damage and have been found in homes, hospitals, schools, and office buildings. It is estimated that about 50 to 100 common in- door mold types have the potential for creating health prob- lems. Exposure to mold has been identified as a potential cause of many health problems including asthma, sinusitis, and infections. It is also believed that molds play a major role in cases of sick building syndrome and related illnesses. PageS ------- Research Research Top Side NERL Notables Feedback Drs. Stephen J. Vesper and Richard Haugland conducted their research at the NERL Microbiological and Chemical Exposure Assessment Research Division where they have developed a DNA-based system that allows rapid identifica- tion and quantification of molds in a matter of hours versus current methodologies, which require days or weeks to iden- tify molds before remedial action can be taken. With the new technology, up to 96 analyses can be run simultaneously by laboratory technicians, reducing the labor required to analyze samples while significantly increasing the accuracy and validity of the analysis. The new technology also enables scientists to make risk assessments by identifying which mold is present and in what numbers. In recognition of their work in developing the technology, the Drs. Vesper and Haugland received the prestigious Fed- eral Laboratory Consortium Award for Excellence in Tech- nology Transfer. They were in competition with researchers from all the Federal laboratories. This innovative technology is being introduced by the En- vironmental Technology Commercialization Center, head- quartered in Cleveland, one of the Agency's technology transfer centers established to assist U.S. industries in the li- censing of EPA technologies. The technology is available on a non-exclusive basis by laboratories, indoor air quality spe- cialists, or other environmental professionals. Aerotech Laboratories, Inc., a small Arizona business, is the first lic- ensee under this government patent. The preceding text was issued as an EPA press release on May 8, 2001. Additional information on molds is available at www.epa.gov/iaq/molds/ index.html. Stephen Vesper, NERE-Cmannati, (513) 569-7367 Richard Haugland, NERE-Gncmnatt, (513) 569-7135 NERE Task #6175 COPP Exposure Behind the Wheel Americans' love affair with the automobile is well known, but how is health affected by time spent behind the wheel? In July, the NERL Human Exposure and Atmospheric Sci- ences Division will conduct a study of highway patrol troop- ers to measure their exposure to emissions inside their vehicles during duty hours and to evaluate the immediate health effects of this exposure. The Car-related Occupa- tional PM and Air Toxics Exposure to Patrolmen (COPP) Study is being conducted in collaboration with the NC High- way Patrol, the University of North Carolina at Chapel Hill, and the National Health and Environmental Effects Research Laboratory. Since the average American spends 1.5 hours in a car each day, understanding the effects of exposure to emissions is an important step in assessing the associated health risks. Those whose jobs involve being on the road, such as Troopers, may spend up to 9 hours driving during each shift, resulting in a longer duration of exposure. While in their cars, people may be exposed to high concentrations of toxic air pollutants from vehicle emissions. Many of these pollutants, at certain levels, have been associated with various health problems and are regulated by the EPA. Ozone, fine particles (also known as soot), nitric oxide, nitrogen dioxide and carbon monoxide are among the air pollutants of concern from vehicle emis- sions and their reaction products. Thirteen troopers will participate in the COPP Study for 24 days. Patrol cars will be equipped with air quality monitors so that scientists can measure a variety of air pollutants from automobile emissions and conduct tests to determine lung function and heart rate variability, shown in other studies to be affected by exposure to fine particles. Health parameters for each Trooper will be measured before and after the work shift, and heart rate variability will be assessed continuously both during work and the night following their shift. Results from the COPP Study are expected early next year and will be used to improve models that predict exposure to pollutants, better determine how people are exposed to po- tentially toxic gases while in cars, and provide new informa- tion on acute health effects. The study also will improve understanding of the potential occupational risk among State Troopers from exposure to air toxics. Ron Williams, NERE-RTP, (919)541-2957 Michael'Rtedtker, NERE-RTP, (919) 541-0327 NERE Task #5676 NERL to Study Children's Exposure to Persis- tent Pollutants This past spring NERL researchers in the Human Expo- sure and Atmospheric Sciences Division launched a pilot study of Ohio preschool children to examine how they are exposed to persistent pollutants, including pesticides. These pollutants are chemical substances that persist in the environ- ment, accumulate in the food chain, and pose a risk of harm- ing human health and the environment. Preschool children are thought to have more frequent con- tact with a variety of these pollutants than older children or adults because of what they eat and drink, where they spend their time, and their activities. Children may be more sensi- tive to the toxic effects of some chemicals found in or on lawns, carpets, toys, furniture, and many other items. About 260 children between 18 months and five years of PageS ------- Research Research Top Side NERL Notables Feedback age at day care centers and individual homes will participate in the three year study which is also being conducted in North Carolina. "The study has been endorsed by the National Head Start Association, the Ohio Department of Human Services and several local child service agencies. The Agency emphasizes that additional research, beyond the pilot study, will be needed before reaching any conclusions." EPA has been directed under the Food Quality Protection Act and the Safe Drinking Water Act of 1996 to give special attention to protecting children from environmental health risks. Marsha Morgan, NERL-RTP, (919)541-2598 NERL Task #3941 Got Water? Protecting Drinking Water with Landscape-Scale Research Current philosophy is evolving toward examination of critical environmental problems over larger spatial scales and assessment of cumulative risk resulting from multiple stresses or stressors. In response to this need, a landscape-scale re- search program was initiated in 1992 by the NERL Environ- mental Sciences Division. Location and Land Cover of the Catskill/Delaware Watersheds in New York State Land Cover Types The landscape-scale assessment approach is being tested in small community-based watersheds in the southeast New York state Catskill/Delaware Watersheds, located 100 miles northwest of New York City. The six watershed basins each end in a human made reservoir. Together they supply 90% of New York City's drinking water. Currently, the City is try- ing to save tax-payers the cost of a billion dollar filtration system by protecting water quality through implementing a long-range watershed protection program. The primary goal of this study is to make a 25-year historic assessment of land- scape and water data from these watersheds. Studying the relationship between land use and water quality can help in the evaluation of the pollution trends and help develop land use strategies that would further reduce non-point pollution to streams and reservoirs. The project will produce a land cover database with satel- lite imagery from 1975, 1984,1991, and 1998. In addition to the imagery data, a set of supplemental geographic data on elevation, watershed boundaries, surface geology, aqueducts and tunnels, stream drainage, city and State owned lands, sew- age treatment plants, roads and population will be collected and produced. The project will also produce a set of land- scape metrics important to identifying surface water quality conditions and an expanded knowledge of the impacts of land cover patterns on water quality. The information will be summarized and distributed in numerous formats including EPA reports, fact sheets and journal publications. Addition- ally, the project will produce a set of metrics compiled into an easy to use format within a Geographic Information System that can be used to measure ecosystem integrity and target areas in need of maintenance or restoration in the Catskill/ Delaware Watersheds. Megan Mehaffej, NERL-Las Vegas, (702) 798-2245 NERL Task #5447 Environmental Decision Making: Crossing Boundaries In February, Mr. William Kepner, research ecologist at the NERL Environmental Sciences Division, presented The San Pedro River Case Study for Community Assessment at the Collo- quium on Community Assessment in Washington, D.C., sponsored by the ORD Office of Science and Policy. The case study illustrates how certain tools were developed and used to answer questions posed by a diverse community located within the San Pedro watershed in southeast Arizona and northeast Sonora, Mexico. Remote satellite imagery was used to examine change throughout the watershed, and a geospatial database browser was created. The data browser is available online and is currently being used by the interagency San Pedro Partnership Committee as the data source for community planning and development decisions. The study demonstrates how the creation of an interdisci- plinary, multinational, and multi-agency science consortium, which includes NERL as a founding member, has served as a platform for research coordination to facilitate environmental decision-making within the San Pedro community. The pro- gram has been a means of exchanging ideas and building con- sensus on significant environmental issues. Page 4 ------- Research Research Top Side NERL Notables Feedback More information is available online at www.epa.gov/ nerlesdl/land-sci/san-pedro.htm William Kepner, NEKL-Las Vegas, (702) 798-2193 NERL Task # 5447 Remote Sensing—Above and Beyond Las Vegas was home to Above and Beyond 2001—An EPA Re- mote Sensing Conference co-spon- sored by the NERL Environmental Sciences Divi- sion (ESD), Environmental Photographic Interpretation Center, and the EPA Region 4 GIS Information Management Branch in Spring 2001. The conference was designed to up- date attendees on the latest developments in the field of re- mote sensing as they apply to environmental issues at EPA. More than 29 speakers gave presentations on a broad range of remote sensing topics and applications to an audience of approximately 100 people from the Office of Research and Development (ORD), all ten EPA regional offices, Superfund and RCRA program offices, Regional Remote Sensing, GIS and GPS Coordinators, the National Enforcement Investiga- tions Center, the Office of Environmental Information, the Office of Enforcement and Compliance Assurance, and the All Indian Pueblo Council. Sixteen of the presenters, who were remote sensing or GIS scientists from ORD, showcased both the technical support and research and development work being performed at various ORD locations around the country. Dr. John Lyon, ESD Director, gave the keynote address. The conference underscored the continuing value of traditional remote sensing technologies for meeting EPA needs, and also demonstrated the value of the newer tech- nologies, such as high spatial resolution spaceborne systems and hyperspectral remote sensors, in performing more de- tailed site-specific to region-wide environmental assessments. Conference participants expressed interest in holding follow- on conferences every two to three years. A compilation of the conference abstracts is available upon request. Donald Garofalo, NERE-Eas Vegas [Reston, VA], (703) 6484285 NERE Task #1839 Raising Awareness of PPCPs Via the Web How the Internet can be used to further the Agency's re- search goals while providing meaningful information to the public is demonstrated by the NERL Environmental Sciences Division website "Pharmaceuticals and Personal Care Prod- ucts." The web site organizes and displays detailed technical and non-technical information effectively, including contact information for scientists involved worldwide with the envi- ronmental aspects of PPCPs, answers to frequently asked questions about PPCPs, a summary of media coverage on the topic, a slide show highlighting the multifaceted issues, and links to relevant citations, scientific conferences, and websites. By serving as an information clearinghouse, the website fo- cuses attention on the emerging issues of PPCPs. As Dr. Christian Daughton, the site's content manager and author, can attest, the website saves him time and energy in responding to numerous inquires from those interested in the topic. Many questions are repetitive and can be addressed most effectively via the web. Each person can review and digest the content at their own pace before contacting him with specific questions or comments not addressed by the site. Feedback to the site is frequent, uniformly positive, and comes from a wide range of people across the globe: faculty and teachers interested in using PPCPs to teach environmen- tal science or for research projects; students interested in learning more about the specific topic of PPCPs or about environmental science; environmental activists and lawyers interested in gaining a better understanding of the science behind environmental issues; research scientists interested in preparing grant proposals or in collaborating with us; media interested in preparing news stories; and the public. The topic of PPCPs has proven to be an effective tool for raising public awareness of the complex issues surrounding environmental science, including awareness that the actions, activities, and behaviors of individuals can directly impact the environment. This is especially important during a time when the public's overall knowledge of science has been declining. The following comments exemplify some of the e-mails received. The Chief of the Michigan Department of Envi- ronmental Quality, Surface Water Quality Division, wrote, 'The web site is outstanding. I've sent your web site address PageS ------- Research Research Top Side NERL Notables Feedback to my staff and will send it out to the rest of the States via a list server." A concerned citizen wrote, "I am really awed by the whole issue...thank you for all your work in bringing this important matter to public attention." All told, the web site immeasurably expands the number of nontechnical and technical people the Agency can reach and inform about topic. You can visit the website at www.epa.gov/ nerlesdl/chemistry/pharma/index.htm. Christian Daughton, NERL-Las Vegas, (702) 798-2207 NEKL Task #6980 Now Internet Accessible —Virtual Field Refer- ence Database for the Neuse River Basin The Neuse River Basin (NRB) Virtual Field Refer- ence Database (VFRDB) is now accessible via the Internet at: www.epa.gov/ nerlesdl/lcb/nrb/VFRDB/. Three years in the making, the VFRDB contains site characterization, field measurement, and digital imagery (camera) data for 1,390 sampling locations within the NRB. Sites include approximately 1,000 general watershed sites and 390 riparian buffer zone sampling loca- tions. The VFRDB was designed using a stratified, random approach to provide a statistically robust source of reference data to validate the results of satellite based land-cover map- ping activities, and to establish baseline conditions for future measurement efforts. The database is currently being used in support of non-point source nitrogen modeling efforts in the NRB. For detailed database description, and methods docu- mentation and application examples, see the June 2001 issue of Photogrammetric Engineering and Remote Sensing or contact Ross Lunetta to receive a reprint of the article. Ross Lanetta, NERL-RTP, (919)541-4256 NERL Task #5445 Use of NEXRAD Stage IV Data in the Multime- dia Modeling of Pollutant Transport As a leader in the environmental research community, the NERL Atmospheric Modeling Division is designing the Mul- timedia Integrated Modeling System (MIMS) to model the cycling of pollutants and nutrients between the atmosphere and the earth's surface, including water bodies and groundwa- ter. Our ability to accurately model atmospheric, hydrological and surface processes that transport chemicals is highly de- pendent on precipitation types, rates, and totals. Of special interest are precipitation extremes and subsequent flooding, which can greatly enhance the movement of such chemicals. During such events, these chemicals can enter the surface water bodies via groundwater recharge as well as overland flow. For example, the extreme flooding associated with Hur- ricane Floyd, which made landfall in North Carolina during September of 1999, transported tremendous amounts of agricultural and industrial waste and pesticides into area estu- aries and rivers. This hurricane, which made landfall shortly after an earlier hurricane (Dennis), inundated sections of eastern North Carolina with more than 20 inches of rain. During the development of MIMS, NERL is investigating the use of the National Weather Service NEXRAD (NEXt generation RADar) State IV precipitation estimates in our modeling efforts. The purpose of this research will be to evaluate the quality and identify limitations of the NEXRAD data through a comparison with ground truth data obtained from a network of ten closely spaced rain gages. The evalua- tion, which will use visualization tools and statistical analyses, will determine if the spatial resolution of NEXRAD data is adequate to capture the variability of precipitation on the watershed that is used in the surface hydrology models asso- ciated with MIMS. Brian Eder, NERL-RTP, (919) 541-3994 NERL Task #3868 Physical Modeling of Flow and Dispersion in Urban Areas Scientists at the Fluid Modeling Facility, managed by the NERL Atmospheric Modeling Division, have completed a wind-tunnel study of the flow and dispersion in idealized urban areas, in collaboration with modelers at Los Alamos National Laboratory and Lawrence Livermore National Laboratory. Three-dimensional, turbulent flow fields were measured with a pulsed-wire anemometer for both an array of two-dimensional buildings and of cubical buildings. For the cubical buildings, a point source tracer located just down- wind of the most upstream building determined the concen- tration field from measurements at various locations within the array. The goal was to develop a database for design and evaluation of 3-D fluid dynamic codes for predicting the fate of pollutants released near groups of buildings in urban ar- eas. A comprehensive report describing the experimental techniques, and containing all raw and reduced data, and se- lected features of the data has been completed and submitted to the collaborators. The report and associated data are avail- able on CD-ROM from the principal investigators. Roger Thompson, NERL-RTP, (919) 541-1895 Steven Perry, NERL-RTP, (919) 541-1896 NERL Task # 3871 Page6 ------- Research Research Top Side NERL Notables Feedback Effect of Time Splitting on the Prediction of Ozone and Particulate Concentrations Simulated by the Models-3 Community Multiscale Air Quality (CMAQ) Model The Models-3 Community Multiscale Air Quality (CMAQ) model is a multi-pollutant and multi-scale air quality model that con- tains state-of-science techniques for simulat- ing all atmospheric and land processes that affect the transport, transformation, and deposition of atmospheric pollutants at re- gional and urban scales. It is a tool for handling all the major pollutant issues in- cluding photochemical oxidants, particulate matter, acidic, and nutrient deposition in a holistic fashion. CMAQ's design incorpo- rates process modules representing different algorithms and parameterizations of physical and chemical processes. The modules follow a time-splitting numerical integration method where the effect of each science process is computed by up- dating pollutant concentrations sequentially one at a time. The final concentration at each computational time step is obtained by cycling through all the science processes in- 3-D image generated by Models-3 software volved. Unlike a model that utilizes an im- plicit numerical method where all the sci- ence processes are solved simultaneously, CMAQ's concentration predictions are af- fected by the sequence in which different science processes are called. With the cur- rent version of CMAQ, the level of science modularity is subordinated by the way the science process codes are archived in the Models-3 system. At present we are continuously testing different CMAQ configurations to study the effects of the time splitting and sequence of science pro- cess calls to establish a better model configuration that pro- duces accurate simulation results without incurring excessive computational cost. Daemon Bjun, NEKL-RTP, (919) 541-0732 Jerry Gtpson, NERL-RTP, (919) 541-4181 NERL Task #3873 Page 7 ------- |