Post-Remediation Sediment Sampling
On the Raisin River Near Monroe, Michigan
Final Results from 2OO1-2OO2 Survey:
PCB Chemistry, Caged Fished and
Bioaccumulation Results
Prepared by:
Scott Cieniawski, and
Demaree Collier
U.S. Environmental Protection Agency
Great Lakes National Program Office
Chicago, Illinois
August 2003
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EXECUTIVE SUMMARY
In 2001 and 2002 the Great Lakes National Program Office (GLNPO), in conjunction with the U.S.
Army Corps of Engineers - Detroit District and the Michigan Department of Environmental Quality
conducted an extensive survey of sediment quality conditions within the Raisin River Area of Concern
(AOC). The focus of the survey was to evaluate the levels of poly chlorinated bi-phenyls (PCB)
contamination remaining in the area of the Ford-Monroe sediment removal project completed in 1997.
The survey also collected data to evaluate the quality of sediments in the AOC outside the removal
area. The assessment focused on PCBs, the primary contaminant of concern within the AOC, but also
include analysis of other chemical constituents.
The sediment investigation included the collection of sediment cores and ponar samples for sediment
chemistry analysis, whole sediment toxicity testing, benthic community analysis, and whole sediment
bioaccumulation testing. Additionally, the agencies conducted caged fish testing at three locations
within the AOC. This report summarizes the results of the sediment chemistry, whole sediment
bioaccumulation testing, and the caged fish studies. Results of the whole sediment toxicity and benthic
community analysis will be provided in a separate report. This report details sampling locations and
methods and presents the results of the sediment assessment.
The results of the survey indicate that PCBs are still a significant problem within the AOC, from the
sediment removal project, downstream to the mouth of the river. Additionally, the whole sediment
bioaccumulation tests and caged fish testing indicate the potential for contaminant uptake into the food
web, and suggest that PCBs remaining in the sediment removal area and in downstream areas may
continue to present a human health and ecological risk.
A summary of the key findings include:
1. Elevated PCB concentrations remain in the "Sediment Removal Area" (SRA). Maximum surficial
PCB concentrations in SRA are >200 mg/kg (total Aroclors). Maximum total PCB concentration
at depth in the SRA is 550 mg/kg (average of RFS and field duplicate);
2. PCB contamination does not appear to be a problem upstream of the SRA. Surficial PCB
concentrations in sediments are all <1 mg/kg based on total aroclor analysis. Maximum PCB
concentrations in the deep sediments are all <1.3 mg/kg.
3. PCB contamination in the sediments is a problem downstream of the SRA where surficial sediment
concentrations are found up to 85 mg/kg (total of aroclors), and the deep sediments contain PCB
concentrations up to 90 mg/kg.
4. Heavy metal and PAH contamination are only a minor concern within the study area. Most levels
are present below the TEC and PEC sediment screening levels guidelines suggested by MacDonald
etal. (2002);
5. Caged fish results indicate that there is the potential for significant uptake of PCBs into the food
web in the areas adjacent to and down-steam of the SRA;
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6. PCB concentrations in caged fish are similar to those measured by MDEQ in 1991 and 1998 caged
fish studies, and significantly below the results from a 1988 caged fish study (MDEQ 2001, Figure
72);
7. Whole sediment bioaccumulation testing results indicate that there is the potential for significant
uptake of PCB s into the food-chain in the areas adjacent to and downstream of the SRA;
8. Bioaccumulation in caged-fish and whole sediment bioaccumulation testing is highest in sediment
samples collected within the SRA;
9. PCB uptake in caged-fish and whole sediment bioaccumulation testing does not appear to be a
significant problem upstream of the SRA;
10. There is not sufficient data to determine the source of PCB contamination remaining in the SRA. It
is recommended that on-going sources, sloughing of contaminated sediments from the adjacent
navigational channel, and residual contamination from the completed dredging project should all
be investigated as potential sources of the PCB contamination in the SRA.
Preliminary estimates of the volume and PCB concentration of sediments remaining in the SRA
indicate that approximately 2,600 cubic yards of sediments remain in the SRA with an average surfical
concentration of 35 mg/kg, and an average total concentration of 58 mg/kg.
The results of this investigation indicate that there is the potential for significant human health and
ecological risk from PCBs within the Raisin River AOC from the SRA downstream. Additional
ecological and human health risk assessment is necessary to quantify this risk. State, local, and federal
stakeholders need to coordinate in order to formulate a plan to address the remaining PCB
contamination in the Raisin River AOC.
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1. BACKGROUND
1.1 SITE DESCRIPTION
The Raisin River flows southeast through the southeast corner of Michigan's Lower Peninsula,
discharging into Lake Erie at Monroe Harbor near the city of Monroe, Michigan. The Area of Concern
(AOC) is defined as "the lower 2.6 miles of the River Raisin, downstream from Dam Number 6 at
Winchester Bridge in the city of Monroe, extending [downstream] one-half mile into Lake Erie, and
including Plum Creek which discharges into Lake Erie through a canal." (USEPA, 1994)
Once forested with mature hardwood stands, the AOC now consists of mostly cleared land that is
urban, suburban, and industrial in nature. Industries within the AOC include automotive, steel and
paper manufacturers. Several landfills also border the river within the AOC. Contaminants of concern
in the AOC include: polychlorinated bi-phenols (PCBs), chromium, copper, zinc, and oil and grease.
(USEPA, 1994).
In 1997 the Ford-Monroe facility, located on the banks of the Raisin River, completed an emergency
sediment removal project at the Ford Monroe contaminated sediment site under an administrative order
by the U.S. Environmental Protection Agency (USEPA) Region 5 Superfund program. The cleanup
resulted in the remediation of approximately 27,000 cubic yards of PCB-contaminated sediments
(maximum concentration 49,000 ppm) by the Ford Motor Company from a large depositional area near
an old 48-inch outfall from the Ford Monroe Stamping Plant. Remedial work also included the
removal of contaminated in-plant sewer material to eliminate the potential for on-going releases. The
remedial work at the site was completed in October 1997. (USEPA, 1998).
In 2001 the U.S. Environmental Protection Agency's Great Lakes National Program Office (GLNPO),
in conjunction with the U.S. Army Corps of Engineers Detroit District and the Michigan Department
of Environmental Quality Surface Water Quality Division, initiated a post-remediation investigation to
evaluate: (1) the levels of residual contamination left behind after completion of the Ford-Monroe
sediment removal project, (2) the recovery of the aquatic system after dredging, and (3) the level of
sediment contamination present in the AOC outside the removal area. The post-remediation
assessment focused on polychlorinated bi-phenyls (PCBs), the primary contaminant of concern at the
site, but also included analysis of other chemical constituents.
The post-remediation investigation included the collection of sediment cores and ponar samples for
sediment chemistry analysis, whole sediment toxicity testing, benthic community analysis, and whole
sediment bioaccumulation testing. Additionally, the agencies conducted caged fish testing at three
locations within the AOC. This report summarizes sampling locations and methods and presents the
results of the post-remediation assessment.
1.2. SUMMARY OF SAMPLING SURVEY
The primary objective of this survey was to collect sufficient data to ascertain the current state of the
sediment environment in the vicinity of the Raisin River, Ford Outfall, Sediment Removal Project. A
secondary objective of the survey was to collect adequate sediment data (chemistry, toxicity, tissue
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chemistry, etc.) to provide an overall summary of sediment quality conditions within the Raisin River
AOC.
The project study area and sampling locations are shown in Figure 1. This post-remediation
assessment included the following types of sampling and analysis:
1. Sediment depth survey (12 locations within the Sediment Removal Area),
2. Sediment Chemistry (18 sediment cores and 8 surficial ponar grabs from locations
upstream, downstream , and within the SRA) ,
3. Sediment Bioaccumulation Testing with Lumbriculus variegatus (8 ponar grabs
upstream, downstream , and within the SRA),
4. Caged Fish Testing (3 cage locations upstream, adjacent, and downstream of the SRA),
5. Whole Sediment Toxicity Testing using Hyalella azteca & Chironomus tentans (8
ponar grabs upstream, downstream , and within the SRA), and
6. Benthic Community Analysis specific to the family taxonomic (8 ponar grabs upstream,
downstream , and within the SRA)
This report focuses on the results of the Sediment Chemistry, Sediment Bioaccumulation, and Caged
Fish, and Sediment Depth sampling and analysis. Results of the Whole Sediment Toxicity Testing and
Benthic Community Analysis will be presented in a separate report. Methods and results for each type
of testing are summarized in Sections 3 through 6, and a summary of the conclusions and
recommendations for further evaluations and potential remedial action are provided in Section 7.
2. QAPP DEVELOPMENT
Prior to initiating sampling for this survey, GLNPO, in conjunction with the U.S. Army Corps of
Engineers (Corps) and the Michigan Department of Environmental Quality (MDEQ), prepared a
Quality Assurance Project Plan (QAPP) [USEPA, 2001], which was reviewed and signed by all major
participants in the collection and analysis of samples. The QAPP contains detailed descriptions and
standard operating procedures (SOPs) for all sampling and analysis methods. These methods are
briefly described in the following subsections.
3. SEDIMENT CHEMISTRY
Both sediment cores and surficial ponar grab samples were collected for chemical analysis. PCB
concentrations were the focus of the sediment chemistry survey, but some additional parameters were
collected for use in evaluating the results of the whole sediment toxicity testing, which is discussed
later. Sampling methods and locations and analysis methods and results are provided below.
Sediment sampling locations are shown in Figure 1.
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Figure 1. Sediment Sampler Locations
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3.1 SEDIMENT CHEMISTRY SAMPLING AND ANALYSIS METHODS
3.1.1 SEDIMENT CORE SAMPLING
Sediment cores were collected utilizing a Rossfelder Vibro-corer equipped with a polycarbonate plastic
core tube outfitted with a plastic nose cone. After measuring water depth and sediment depth the
vibro-corer and core tube assembly was driven into the sediments until refusal, or until reaching a
sediment depth of 10-feet. The vibro-corer assembly was then retrieved to the deck of the vessel and
the core tube was detached from the vibro-corer. The core tube was then laid on its side and sectioned
into intervals of 0"-6", 6"-18", 18"-54", and 54"-90" utilizing a battery-powered circular saw.
Sediment cores <90" in length were cut into fewer sections utilizing the same intervals (e.g. a 42" core
would be sectioned into 0"-6", 6"-18", and 18"-42" intervals). Where coring was unsuccessful due to
lack of sediment depth, a ponar grab sampler was used to collect a surficial sediment sample.
Sediment from each interval was then transferred into stainless steel bowls, homogenized, and placed
into appropriate sample jars. Sediment cores were analyzed for the parameters shown in Table 1.
Table 1. List of Analytical Parameters of Sediment Core Chemistry
Analyte
Moisture Content (Total Solids)
TOC
PCBs (Aroclors & Congeners11')
Oil and Grease
Analysis Method
ASTM D2937
9060/Lloyd-Kahn
EPA 8082B
EPA 9071 A
^The following 19 PCB congeners, listed by their International Union of Pure and Applied Chemistry Number (IUPAC #),
were analyzed and reported for sediment chemistry: 1, 5, 18, 31, 44, 52, 66, 87, 101, 110, 138, 141, 151, 153, 170, 180, 183,
187, 206.
The field team attempted to collect sediment cores at 20 sampling locations. Sediment coring was
successful at 13 of these locations. Ponar grab sampling was successful at an additional five (5)
proposed coring locations. One sampling location, RR01-20 was inaccessible due to low water levels,
and no sediments were present at sampling location RR01-09. Therefore, sediment samples were
collected at a total of 18 sediment coring locations.
3.1.2 SURFICIAL SEDIMENT SAMPLING (PONAR DREDGE SAMPLER)
Surficial sediment samples were collected using a ponar dredge sampler capable of collecting
approximately 2-gallons of sediment. The ponar sampler was lowered into the sediments and
automatically activated, samples were retrieved to the deck of the vessel, transferred into stainless steel
bowls, homogenized, and placed into appropriate sample jars. Sediment ponar samples were analyzed
for the wider range of chemical parameters than the sediment core samples. Analytical parameters for
the ponar samples are summarized in Table 2.
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Table 2. List of Analytical Parameters of Sediment Ponar Chemistry
Analyte
Moisture Content (Total Solids)
Grain Size without hydrometer
28-day /-/. azteca, and 1 0-day C. tentans
Whole Sediment Toxicity Tests
28-day L. variegatys Bioaccumulation Test for
Sediments
TOC
Ammonia-Nitrogen
TKN
Total Phosphorus
Metals Kit
PCBs (Sediments, L variegatus tissue)
Aroclors & Congeners'1'
PAHs
Acid Volatile Sulfide (AVS) (2)
Simultaneously Extracted (SEM) Metals w
Analysis Method
ASTM D2937
ASTM-D422
EPA/600/R-99/064, Methods 100.4 (Survival &
Length) and 100.2 (Survival & Weight)
EPA/600/R-99/064, Methods 100.3
9060/Lloyd-Kahn
E350.1
E351.2
E 365.2M
EPA 6020, 601 OA (As & Cd analyzed using
601 OB ICAP Trace procedures), 7471 A
EPA 8082B
EPA 8270C
EPA-121-R91-100
EPA6020M6010A
(1)The following 19 PCB congeners, listed by their International Union of Pure and Applied Chemistry Number (IUPAC #),
will be analyzed and reported for sediment chemistry: 1, 5, 18, 31,44, 52, 66, 87,101,110,138,141,151,153,170,180,183,
187,206.
® AVS-SEM Analysis Method can be found in the "Draft Analytical Method for Determination of Acid Volatile Sulfide in
Sediment", EPA#: 821/R-91-100 YEAR: 1991,NTIS#:PB93-155901,EPJC#: D-121
The field team collected surficial ponar dredge samples at all eight (8) of the sites targeted for surficial
sampling. Locations of the ponar samples overlap the sediment core locations and are shown in Figure
1.
3.2 SEDIMENT CHEMISTRY RESULTS
Appendix A contains the analytical results for the sediment cores and the surficial ponar samples. The
totals of the PCB congener data should be used only as a qualitative evaluation tool, since the PCB
congener data represents only a subset of the full list of PCB congeners. Additionally, several field
duplicate and field replicate samples were collected for QA/QC purposes. A comparison of the routine
field samples (RFS) and the duplicates and replicates are also provided in Appendix A for both the
sediment cores and the ponar samples.
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Visual summaries of the analytical results for total PCB Aroclors are provided in Figures 2 (surficial
concentrations) and Figure 3 (max PCB concentration at depth).
It is noted that the results for PCB levels in sample RR-01-02B represent data from a second round of
analysis. This sample was identified as an outlier data point due to the peculiar initial results (high
PCB concentrations in the 6"-18" interval, surrounded by extremely low PCB concentrations in both
the ponar sample and the 18"-54" interval). GLNPO asked the laboratories to perform a second set of
analyses on this sample using excess sample material that was originally sent to Trace Laboratories for
metals analysis. The second round of analysis was performed several weeks after the initial rounds of
analyses were completed. Only PCB aroclor analysis was performed on this second sample.
Therefore, no PCB congener data is reported for sample RR01-02B. PCB concentrations in sample
RR01-02B were much lower than the original results and were in-line with the adjacent samples.
Also, the RR01-02A sample intended for semi-volatile and PCB analysis broke in transit to the
laboratory. Therefore, no chemistry data for these parameters is provided for this sample. Important
items observed in the sediment chemistry data include:
1. Elevated PCB concentrations remain in the "Sediment Removal Area". Maximum surficial PCB
concentrations in SRA are >200 mg/kg (total Aroclors). Maximum total PCB concentration at
depth in the SRA is 550 mg/kg (average of RFS and field duplicate);
2. PCB contamination does not appear to be a problem upstream of the SRA. Surficial PCB
concentrations in sediments are all <1 mg/kg based on total aroclor analysis. Maximum PCB
concentrations in the deep sediments are all <1.3 mg/kg.
3. PCB contamination in the sediments is a problem downstream of the SRA where surficial sediment
concentrations are found up to 85 mg/kg (total of aroclors), and the deep sediments contain PCB
concentrations up to 90 mg/kg.
4. Heavy metal and PAH contamination are only a minor concern within the study area. Most levels
are present below the TEC and PEC sediment screening levels guidelines suggested by MacDonald
etal. (2002);
5. All SEM minus AVS (SEM-AVS) values in the ponar samples are less than zero, indicating that
metals contamination are not likely to contribute to toxicity to benthic organisms (cite reference).
6. PCB congener data are highly correlated to PCB aroclor data and serve as a good, qualitative
indication of the accuracy of the PCB aroclor data;
7. There is not sufficient data to determine the source of PCB contamination remaining in the SRA.
On-going sources, sloughing of contaminated sediments from the adjacent navigational channel,
and residual contamination from the completed dredging project should all be investigated as
potential sources of the PCB contamination in the SRA.
8. Results of field duplicate and field replicate analysis indicate a moderate level of variability with
some RPD calculations >50%. However, the field duplicates and replicates indicate that this PCB
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data is accurate to a factor of <3 (i.e., PCB concentrations provide in the results table are expected
to be within a factor of 3 of the true total PCB concentration present in each sample). Therefore,
this data is considered to be of sufficient quality to be used to make management decisions at this
site.
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Figure 2. Surficial PCB Concentrations (total PCB Aroclors)
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Figure 3. PCB Concentrations at Depth (total PCB Aroclors)
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J
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ft!
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4.
CAGED FISH SAMPLING
4.1 CAGED FISH SAMPLING AND ANALYSIS METHODS
Caged fish sampling and processing was performed according to MDEQ GLEAS Procedures #31 and
#62 (Procedure #31 is available at: http//www.deq.state.mi.us/documents/deq-swq-gleas-proc31.pdf,
procedure #62 is available upon request). A total of 32 young-of-the-year catfish were placed into
each of 4 fish cages (3 routine field samples and one duplicate cage). Fish cages were left in place for
a total of 28-days, and then harvested. Surviving organisms were divided into 4 replicates of
approximately equal weight, frozen, and submitted to the laboratory for whole fish processing.
Sediment samples were collected at each of the cage fish sites prior to setting each cage, and after
collection of each cage. Water samples were collected at each site prior to setting of the cages. Caged
fish sampling locations are shown in Figure 4.
The fish, water, and sediment samples were analyzed for the parameters listed in Table 3.
Table 3. List of Analytical Parameters of Caged Fish Testing
Analyte
Moisture Content/Total Solids (Sediments)
TOC (Water and Sediments)
Metals Kit (Water and Sediments)
PCBs Aroclors & Congeners0' (Sediments,
Water, Fish Tissue)
Analysis Method
ASTM D2937
9060/Lloyd-Kahn
EPA 6020, 601 OA (As & Cd analyzed using
601 OB ICAP Trace procedures), 7471 A
EPA 8082B
'-'-'The following 19 PCB congeners, listed by their International Union of Pure and Applied Chemistry Number (IUPAC #), will be
analyzed and reported for sediment chemistry: 1, 5,18, 31, 44, 52, 66, 87,101, 110, 138, 141, 151, 153, 170,180,183, 187,206.
4.2. CAGED FISH SAMPLING RESULTS
The results of the caged fish tissue analysis are summarized visually in Figure 5. Details of the
analytical results of the caged fish sampling are provided in Appendix B for the fish tissue, sediment,
and water chemistry. Table 5 summarizes the number of surviving fish in each cage at the end of the
28-day sampling event.
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Figure 4. Caged Fish Sampling Locations
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Figure 5. Summary of PCB Levels in Caged Fish Tissue
o
c
o
o
0>
3
** All Aroclors were
Less than the Detection
Limit
Near RR Bridge (Upsteam of SRA)
Adjacent to SRA
Location
River Mouth (Downstream of SRA)
Table 5. Number of Surviving Fish from Caged Fish Sampling
Location
C-1
C-2
C-2 DUP
C-3
Number of
Surviving
Fish
29
18
31
15
Important items to observe in the data include:
1. As shown in Figure 5, the caged fish results indicate that there is the potential for significant uptake
of PCB s into the food web in the areas adjacent to and down-steam of the SRA;
2. PCB uptake into caged fish are highest adjacent to the SRA;
3. PCB concentrations in caged fish are similar to those measured by MDEQ in 1991 and 1998 caged
fish studies, and significantly below the results from a 1988 caged fish study (MDEQ 2001, Figure
72);
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PCB uptake into the caged fish does not appear to be a significant problem upstream of the turning
basin; and
The RPDs between the field replicate and the routine field sample for location C-2 are shown in
Table 4 and are 12% and 0%, for total aroclors and total congeners, respectively. This indicates a
high degree of precision and representativeness in the caged fish samples. Therefore, we conclude
that the caged fish data is of sufficient quality for making screening level management decisions at
the site.
It should be noted that caged fish testing is not a direct indicator of bioaccumulation in wild fish, but
only an indication of the potential for uptake into the food web. Additional human health and
ecological risk work is required to estimate the risk from PCBs at this site.
5. WHOLE SEDIMENT BIO ACCUMULATIVE SAMPLING
5.1 BIOACCUMULATION SAMPLING AND ANALYSIS METHODS
Sediment ponar samples were collected at seven (7) locations, the eight (8) ponar sampling sites shown
in Figure 1 excluding location RR01-06P. A total of four liters of sample was collected from each of
these eight (8) locations to be utilized for performing whole sediment bioaccumulation testing.
Bioaccumulation testing was performed by AScI Corporation with Lumbriculus variegatus as specified
in Test Method 100.3 in USEPA (2000). Tissue chemistry analysis was performed by Lancaster
Laboratories. One duplicate sample and one replicate sample were collected for QA/QC purposes. L.
variegatus tissue was analyzed for the parameters listed in Table 4.
5.2 BIOACCUMULATION SAMPLING RESULTS
The results of the whole sediment bioaccumulation testing are summarized visually in Figure 6.
Details of the analytical results of the bioaccumulation testing and the QA/QC comparisons of RPD are
provided in Appendix C. Sampling locations are shown in Figure 1.
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3.5
33.0
i 2.5
| 2.0
J
81.0
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Table 6. Comparison of PCB Concentrations in Bioaccumillation Tests and Sediments
Location
1P
2P
4P
8P
12P
17P
18P
Sediment
PCB Cone.
(mg/kg)
0.2
0.2
3.9
18.0
10.0
5.4
1.4
Tissue
PCB Cone.
(mg/kg)
0.0
0.0
0.6
3.1
2.2
0.8
0.4
Once again it is noted that caged fish testing is not a direct indicator of bioaccumulation in wild fish,
but only an indication of the potential for uptake into the food web. Additional human health and
ecological risk work is required to estimate the risk from PCBs at this site.
6.
WATER DEPTH AND SEDIMENT DEPTH SURVEY
6.1 WATER DEPTH SURVEY METHODS AND RESULTS
Water Depth Measurement Method: After arriving and triple-point anchoring at each sampling
location. The field team used a weighted tape measure to estimate water depth to the nearest 1-inch.
At locations where wave action caused variability in the depth measurement, the field team members
estimated water depth by averaging between the high and low water marks on the tape measure. Water
depth was recorded on a field data log sheet.
Water depth data was collected at each sampling location and the results are provided in Appendix D.
Water surface elevation data, referenced to low water datum (LWD) are also provided in Appendix D
for each day of sampling. Given the proximity of sampling locations to open water Lake Erie, Lake
Erie water elevations are provided. Water data was collected for purposes of future data reference, and
no additional evaluation of this data was performed.
6.2 SEDIMENT DEPTH SURVEY METHODS AND RESULTS
Sediment Depth Survey Method: Sediment depth data were collected at each of the sediment core
locations within the SRA. Sampling locations are shown in Figure 1 and results are detailed in
Appendix D. This data was collected in order to provide a rough estimate of volume and average PCB
concentration of sediments remaining in the SRA.
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The sediment depth survey was conducted as follows:
After measuring water depth and recording sampling location from the differentially corrected
GPS, the field team assembled a set of 2-inch diameter, aluminum rods to use as a sediment
probing devices. Each rod is 6-feet long and the six rods can be connected in series to reach a
maximum depth of 36-feet. Each rod is marked in 1-foot increments to allow for fairly
accurate depth measurement. After assembling the rods, the field team members lowered the
rod to the sediment-water interface, noted the depth measurement, and then pushed the rod into
the sediments until refusal. The total depth of penetration by the rods represents the estimated
sediment depth. Sediment depth was then recorded on a field data log sheet to the nearest 0.25
feet.
Using the sediment depth data provided in Appendix D and the PCB chemistry data provided in
Section 3, we can obtain a rough estimate of the volume and PCB concentration of the contaminated
sediments remaining in the SRA. Appendix E contains the details of the calculations used to make the
estimate. The method described in Appendix E provides only a crude estimate of the volume and PCB
concentration of contaminated sediments remaining in the SRA. However, the accuracy of this
measurement is sufficient for providing a screening level evaluation of the conditions within the SRA.
Estimated Volume of Contaminated Sediments Remaining in SRA = 2,600 cubic yards
Average Depth of Sediment in the SRA =1.1 feet
Est. Avg. Surficial PCB Concentrations in SRA Sediments = 35 mg/kg
Est. Avg. PCB Concentration in all SRA Sediments = 58 mg/kg
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7. CONCLUSIONS AND RECOMMENDATIONS
7.1 CONCLUSIONS
The results from the caged fish, whole sediment bioaccumulation, and sediment chemistry testing and
analysis all present a similar picture and indicate that PCBs are still a potential ecological and human
health risk within the Raisin River AOC. The following are the major conclusions based on the results
of the sampling performed by GLNPO, MDEQ, and the Corps of Engineers.
1. Significant levels of PCBs (> 500 ppm) in the sediments continue to impact the AOC
downstream of the turning basin including significantly elevated concentrations (> 200 ppm)
within the SRA;
2. PCB contamination is present in both surficial sediments (top 6-inches) and deeper sediments
in the SRA and downstream areas;
3. Caged fish and whole sediment bioaccumulation testing indicate the potential for significant
bioaccumulation of PCBs in areas within and downstream of the SRA;
4. PCB contamination is not a significant problem upstream of the SRA; and
5. PAHs, heavy metals, and oil & grease are only present at moderate levels and should probably
not be considered primary contaminants of concern at this site.
7.2 RECOMMENDATIONS
Additional work is needed to evaluate the current state of the sediments within the Raisin River AOC
and to support decision-making at the site. Although, it may not be necessary to collect additional
sediment data at the site, it is necessary to evaluate all available data available for the AOC. The
authors have the following specific recommendations for further evaluation and analysis:
1. USEPA and MDEQ should undertake an extensive review of existing data to investigate the
potential source of PCB contamination remaining in the SRA. On-going sources, sloughing of
PCB-contaminated sediments from the adjacent navigational channel, and residual
contamination from the dredging project should all be investigated as potential causes of the
PCB contamination in the sediments currently in the SRA. This analysis should be performed
prior to taking additional remedial actions at the site in order to obtain the benefit of any
insights this analysis may provide.
2. USEPA and MDEQ should coordinate with other state, local, and federal stakeholders to
complete a screening level risk assessment for the sediments in the Raisin River AOC.
3. USEPA and MDEQ should coordinate with other state, local, and federal stakeholders to devise
a method of addressing the PCB contamination remaining in the Raisin River AOC. These
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efforts should focus on the area downstream of the turning basin and determining the next steps
for action in the AOC.
8. REFERENCES
MacDonald, Donald D., Ingersoll, C.G, and Berger, T.A., 2000. "Development and Evaluation of
Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems", Archives of
Environmental Contamination and Toxicology, 39:20-31
MDEQ, 2001. "Michigan Fish Contaminant Monitoring Program, 2001 Annual Report", Michigan
Department of Environmental Quality, Surface Water Quality Division, Lansing, MI.
NATO, 1988. International Toxicity Equivalency Factor (I-tef) Method of Risk Assessment for
Complex Mixtures ofDioxins and Related Compounds. North Atlantic Treaty Organization. Report
Number 176.
Persuad, D., Jaaguamagi, R., and Hayton, A., 1993. "Guidelines for the Protection and Management of
Aquatic Sediment in Ontario", Water Resources Branch, Ontario Ministry of the Environment,
Toronto, Ontario.
USEPA, 1994. A Summary of Contaminated Sediment Activities Within the United States Great Lakes
Areas of Concern, EPA-905-R94-002, USEPA-Great Lakes National Program Office, Chicago, IL,
January 1994.
USEPA, 1998. "Realizing Remediation: A Summary of Contaminated Sediment Remediation
Activities in the Great Lakes Basin", USEPA Great Lakes National Program Office, Chicago, IL,
March 1998.
USEPA, 2000. Methods for Measuring the Toxicity and Bioaccumulation of Sediment-Associated
Contaminants with Freshwater Invertebrates, Office of Research and Development, U.S.
Environmental Protection Agency, Washington, DC, EPA/600/R-99/064.
USEPA, 2001. "Quality Assurance Project Plan Raisin River Sediment Sampling in FY2002: A
Follow-Up to the 1997 Sediment Remediation Project", October 4, 2001, USEPA - Great Lakes
National Program Office, Chicago, IL.
Raisin River Near Monroe, Michigan - Final Results 2001 - 2002 - 20 -
-------
ANALYTICAL CHEMISTRY
Appendix A
SEDIMENT CORE DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
Units
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-01A
10/15/01
1405
41 53.969
-83 21.637
0
6
29,000
58.4
58.2
<600
7.7
100
0.67
25
33
20,000
28
520
<0.10
28
1.2
<0.50
100
< 0.0079
< 0.011
< 0.0079
0.12
< 0.0086
< 0.0079
0.039 J
< 0.001 7
< 0.00048
0.011
0.017
0.010
0.013
0.0089
0.0017
0.0030
0.0058
0.0024
< 0.00048
0.00086 J
0.0027
0.0011 J
0.0015 J
< 0.00048
0.0013 J
< 0.00048
0.08
0.12
RR01-01B
10/15/01
1405
41 53.969
-83 21.637
6
17
32,000
53.2
53.2
<530
9.7
150
0.86
42
44
27,000
43
720
0.13
40
1.7
<0.50
260
< 0.0071
< 0.0094
< 0.0071
0.21
< 0.0077
< 0.0071
0.044
0.0089 J
< 0.0021
0.016
0.029
0.017
0.024
0.015
0.0033 J
0.0060 J
0.0099
0.0047 J
< 0.0021
< 0.0021
0.0033 J
< 0.0021
0.0025 J
< 0.0021
0.0022 J
< 0.0021
0.11
0.25
RR01-02A
10/18/01
1545
41 54.076
-83 21.483
0
6
34,000
54.2
n/r
<540
8.1
110
0.8
32
38
20,000
34
470
0.14
30
<0.36
<0.50
120
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
RR01-02B
10/18/01
1545
41 54.076
-83 21.483
6
18
39,000
53.6
51.1
<540
5.9
110
0.81
34
47
20,000
41
520
0.19
34
1.7
<0.50
140
<0.0066
<0.0088
<0.0066
<0.0066
0.49
<0.0066
0.043
<0.72
<0.20
1.6
0.58 J
0.55 J
1.0
0.50 J
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
2.60
0.53
RR01-02C
10/18/01
1545
41 54.076
-83 21.483
18
62
84,000
55.6
54.4
<560
8.3
300
3.4
77
120
18,000
290
440
1.4
37
<0.36
2.2
530
< 0.0072
< 0.0096
< 0.0072
0.43
< 0.0072
< 0.0072
0.28
< 0.0077
< 0.0022
0.015
< 0.0022
0.017
0.025
0.017
0.0070 J
0.020
0.017
0.013
0.0062 J
0.0057 J
0.014
0.0061 J
0.014
0.0044 J
0.010
0.013
0.18
0.71
RR01-03A
10/18/01
1444
41 54.070
-83 21.352
0
6
37,000
56.4
55.5
<570
10
120
0.78
38
43
22,000
38
590
0.15
34
1.5
<0.50
120
< 0.037
< 0.049
< 0.037
0.52
< 0.040
< 0.037
0.049 J
< 0.0079
< 0.0022
0.033
0.041
0.029
0.042
0.022
0.0052 J
0.014
0.017
0.012
< 0.0022
0.0045 J
0.011
0.0053 J
0.0062 J
< 0.0022
0.0041 J
< 0.0022
0.22
0.52
RR01-03B
10/18/01
1444
41 54.070
-83 21.352
6
18
34,000
49.7
48.4
<500
9.8
150*
0.86
44
45
26,000
36
650
0.21
37
1.7
<0.50
140
< 0.032
< 0.043
< 0.032
0.32
< 0.035
< 0.032
0.063 J
< 0.0068
< 0.001 9
< 0.001 9
0.024
0.019
0.025
0.018
0.0030 J
0.0076
0.011
0.0046 J
< 0.001 9
< 0.001 9
0.0044 J
< 0.001 9
0.0029 J
< 0.001 9
0.0021 J
< 0.001 9
0.10
0.32
RR01-03C
10/18/01
1444
41 54.070
-83 21.352
18
44
36,000
48.2
48.4
<480
8.3
130*
0.89
50
58
24,000
53
580
0.23
42
0.48
<0.50
170*
< 0.032
< 0.043
< 0.032
1.3
< 0.035
< 0.032
0.12J
0.035 J
< 0.0039
0.140
0.090
0.053
0.071
0.049
0.0063 J
0.019
0.027
0.0079 J
< 0.0039
< 0.0039
0.0095 J
< 0.0039
0.0056 J
< 0.0039
0.0041 J
< 0.0039
0.45
1.30
RR01-04A
10/18/01
1408
41 54.069
-83 21.272
0
6
28,000
50.1
46.8
560
7.8
120
0.6
32
34
17,000
27
400
0.12
25
1.2
<0.50
89
<3.1
< 4.1
< 3.1
20
<3.4
< 3.1
<3.1
2.5 J
<0.19
3.0
0.48 J
0.27 J
0.80
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
<0.19
3.80
20.00
RR01-04B
10/18/01
1408
41 54.069
-83 21.272
6
18
85,000
54.8
53.9
1,500
10
560
4.1
71
100
21,000
270
340
1.3
50
1.5
1.7
670
< 0.036
< 0.048
< 0.036
1.2
< 0.039
< 0.036
0.21
0.10
< 0.00043
< 0.00043
0.016
0.013
0.024
0.0088
0.0026
0.011
0.0076
0.010
0.0034
0.0037
0.0087
0.0066
0.014
0.0039
0.0093
0.014
0.26
1.41
RR01-04C
10/18/01
1408
41 54.069
-83 21.272
18
46
41,000
39.8
43.9
830
9.3
460
2.8
47
81
17,000
200
260
0.88
31
1.2
1.3
600
< 0.0059
< 0.0078
< 0.0059
0.26
< 0.0064
< 0.0059
0.071
0.0091 J
< 0.001 8
< 0.001 8
0.0031 J
< 0.001 8
0.0035 J
< 0.001 8
< 0.001 8
0.0073
0.0028 J
0.0064
0.0030 J
0.0022 J
0.0045 J
0.0033 J
0.0082
0.0021 J
0.0056 J
0.0086
0.03
0.33
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 1 of 13
-------
ANALYTICAL CHEMISTRY
Appendix A
SEDIMENT CORE DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
Units
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-05A
10/18/01
1034
41 54.065
-83 21.275
0
4
22,000
34.5
31.1
<380
4.7
74
0.26
9.3
12
12,000
8.6
360
<0.10
18
<0.29
<0.50
36
< 0.024
< 0.032
< 0.024
0.40
< 0.026
< 0.024
< 0.024
0.028
< 0.00029
0.024
0.0037
0.0026
0.0047
0.0017
< 0.00029
0.00097 J
0.0012
0.00043 J
0.00030 J
0.00032 J
0.00067 J
< 0.00029
0.00058 J
< 0.00029
0.00044 J
< 0.00029
0.07
0.40
RR01-06A
10/19/01
0924
41 54.052
-83 21.250
0
6
19,000
44.0
42.2
<450
7.0
78
0.43
23
29
16,000
21
390
2.0
25
<0.29
<0.50
90
<1.1
< 1.5
< 1.1
8.7
< 1.2
< 1.1
<1.1
0.52 J
< 0.069
1.1
0.39
0.34
0.54
0.31
< 0.069
0.12J
0.17 J
< 0.069
< 0.069
< 0.069
< 0.069
< 0.069
< 0.069
< 0.069
< 0.069
< 0.069
2.68
8.70
RR01-06B
10/19/01
0924
41 54.052
-83 21.250
6
17
30,000
53.0
52.0
<530
7.9
120
0.74
39
44
23,000
33
490
0.26
36
< 0.41
<0.50
140
< 0.034
< 0.046
< 0.034
0.67
< 0.038
< 0.034
0.065 J
< 0.0073
< 0.0021
0.018
0.033
0.023
0.029
0.025
0.0040 J
0.0083
0.012
0.0038 J
< 0.0021
< 0.0021
0.0037 J
< 0.0021
0.0023 J
< 0.0021
< 0.0021
< 0.0021
0.15
0.67
RR01-07A
10/18/01
1010
41 54.054
-83 21.238
ponar
ponar
12,000
36.5
29.8
520
6.3
52
0.85
15
30
12,000
15
300
<0.10
19
0.95
<0.50
77
<0.94
< 1.3
<0.94
27
< 1.0
<0.94
1.6J
1.5
< 0.057
2.6
0.63
0.55
0.93
0.58
< 0.057
0.21
0.27
0.094 J
< 0.057
< 0.057
0.094 J
< 0.057
0.075 J
< 0.057
< 0.057
< 0.057
7.27
27.00
RR01-08A
10/19/01
0953
41 54.039
-83 21.236
0
6
27,000
57.4
57.4
<590
7.0
91
0.56
27
32
18,000
22
460
0.17
28
<0.38
<0.50
110
<0.39
<0.52
<0.39
7.9
<0.42
<0.39
0.68
0.11 J
< 0.023
0.38
0.46
0.34
0.47
0.46
0.057 J
0.12
0.15
0.041 J
< 0.023
< 0.023
0.041 J
< 0.023
0.030 J
< 0.023
< 0.023
< 0.023
2.38
8.58
RR01-08B
10/19/01
0953
41 54.039
-83 21.236
6
18
26,000
51.0
50.7
<510
8.3
130
2.0
40
51
24,000
220
590
0.33
40
1.8
<0.50
150
<3.3
<4.5
<3.3
46
<3.7
<3.3
<3.3
1.7
< 0.041
3.1
1.0
0.6
1.2
0.75
0.095 J
0.23
0.27
0.082 J
< 0.041
< 0.041
0.088 J
0.045 J
0.075 J
< 0.041
0.044 J
< 0.041
8.85
46.00
RR01-08C
10/19/01
0953
41 54.039
-83 21.236
18
30
40,000
49.0
48.9
<490
8.5
160
1.1
54
66
23,000 *
54
510
0.43
42
<0.34
<0.50
190
<6.5
<8.6
<6.5
300
<7.0
<6.5
24 J
75
<0.39
42
23
5.1
11
7.8
1.6
3.9
4.3
2.0
0.45 J
0.53 J
1.8
1.0J
1.8
<0.39
0.94 J
<0.39
179.30
300.00
RR01-09A
10/18/01
0942
41 54.036
-83 21.220
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
No Sample
RR01-10A
10/19/01
1034
41 54.028
-83 21.215
0
6
23,000
48.0
48.1
<480
7.2
77
0.52
22
33
17,000
20
440
<0.10
26
1.4
<0.50
100
<6.4
<8.5
<6.4
190
<6.9
<6.4
17
25
<0.39
15
11
9.1
10
16
3.3
5.6
6.7
2.5
0.50 J
<0.39
2.3
0.91 J
1.6
<0.39
0.85 J
<0.39
108.10
207.00
RR01-10B
10/19/01
1034
41 54.028
-83 21.215
6
16
32,000
51.8
53.1
700
7.8
100
0.71
34
45
20,000
32
490
0.23
34
<0.28
<0.50
130
<7.0
<9.4
<7.0
150
<7.7
<7.0
10
20
<0.43
18
4.2
6.6
14
6.1
1.3 J
2.6
3.4
1.2J
<0.43
<0.43
1.1 J
0.55 J
1.0 J
<0.43
0.55 J
<0.43
74.90
160.00
RR01-11A
10/18/01
0907
41 54.052
-83 21.202
ponar
ponar
23,000
46.4
25.5
1,200
7.4
70
0.59
23
35
12,000
32
310
0.14
22
1.0
1.1
76
< 11
< 15
< 11
93
< 12
< 11
< 11
4.9 J
<0.67
12
8.8
4.6
7.1
4.5
<0.67
1.9J
2.4
<0.67
<0.67
<0.67
<0.67
<0.67
<0.67
<0.67
<0.67
<0.67
39.40
93.00
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 2 of 13
-------
ANALYTICAL CHEMISTRY
Appendix A
SEDIMENT CORE DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
Units
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-12A
10/19/01
1359
41 54.010
-83 21.194
0
6
27,000
55.0
54.8
<550
6.7
110
0.75
30
45
19,000
31
510
0.10
35
1.6
<0.50
130
<0.37
<0.49
<0.37
12
<0.40
<0.37
0.88 J
0.26 J
< 0.022
0.76
0.75
0.57
0.85
0.71
0.093
0.24
0.27
0.082
< 0.022
< 0.022
0.091
0.036 J
0.066 J
< 0.022
0.039 J
< 0.022
4.42
12.00
RR01-12B
10/19/01
1359
41 54.010
-83 21.194
6
11
26,000
44.3
48.1
450
8.1
110
0.75
35
54
20,000
36
460
0.16
36
0.84
<0.50
140
<0.64
<0.85
<0.64
9.4
<0.69
<0.64
5.1
12
< 0.039
4.4
1.2
0.94
1.6
1.6
0.28
0.55
0.72
0.32
0.064 J
< 0.039
0.27
0.19
0.31
0.064 J
0.16
0.048 J
24.54
14.50
RR01-13A
10/18/01
0826
41 54.011
-83 21.178
ponar
ponar
7,700
19.9
18.7
800
4.6
29
0.13
12
22
8,200
15
250
<0.10
13
<0.20
<0.50
32
<1.6
<2.2
< 1.6
20
< 1.8
< 1.6
2.0 J
1.2J
< 0.098
2.3
0.54
0.48
0.84
0.61
< 0.098
0.22 J
0.25 J
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
4.77
20.00
RR01-14A
10/19/01
1500
41 53.995
-83 21.176
ponar
ponar
32,000
62.0
61.2
700
6.6
92
0.69
26
45
20,000
29
500
<0.10
31
<0.33
<0.50
120
<0.17
<0.23
<0.17
6.6
<0.19
<0.17
0.85 J
0.16J
< 0.021
0.37
0.54
0.49
0.61
0.70
0.11
0.22
0.28
0.11
< 0.021
< 0.021
0.092
0.042 J
0.071 J
< 0.021
0.043 J
< 0.021
3.52
6.60
RR01-15A
10/16/01
0820
41 53.999
-83 21.168
ponar
ponar
6,000
17.5
13.3
770
7.3
29
0.15
14
44
15,000
17
320
<0.10
22
0.56
<0.50
47
<1.5
<2.0
< 1.5
27
< 1.7
< 1.5
2.1
1.1 J
< 0.092
2.1
1.1
1.2
1.5
1.4
0.13 J
0.36
0.43
0.16J
< 0.092
< 0.092
0.13 J
< 0.092
0.12 J
< 0.092
< 0.092
< 0.092
8.09
29.10
RR01-16A
10/18/01
1654
41 53.957
-83 21.122
0
6
22,000
50.7
49.3
<510
6.3
100
0.68
37
45
19,000
38
440
0.12
46
<0.30
<0.50
130
<0.65
<0.87
<0.65
4.8
<0.71
<0.65
<0.65
0.20 J
< 0.039
0.36
0.38
0.31
0.45
0.31
0.048 J
0.14J
0.16
0.05 J
< 0.039
< 0.039
0.058 J
< 0.039
0.044 J
< 0.039
< 0.039
< 0.039
1.97
4.80
RR01-16B
10/18/01
1654
41 53.957
-83 21.122
6
18
36,000
48.5
45.3
<480
7.6
130
0.92
40
60
22,000
53
520
0.19
51
1.6
<0.50
170
<0.60
<0.80
<0.60
5.5
<0.66
<0.60
<0.60
<0.13
< 0.037
0.27
0.36
0.24
0.39
0.28
0.046 J
0.19
0.19
0.070 J
< 0.037
< 0.037
0.092 J
< 0.037
0.061 J
< 0.037
0.037 J
< 0.037
1.92
5.50
RR01-16C
10/18/01
1654
41 53.957
-83 21.122
18
36
51,000
46.5
45.9
<470
10
300
1.9
48
81
25,000
120
450
0.82
42
0.63
0.65
330
< 0.030
< 0.041
< 0.030
0.42
< 0.033
< 0.030
0.067 J
< 0.026
< 0.0074
0.026
0.026
< 0.0074
0.024 J
0.019 J
< 0.0074
0.013 J
0.010 J
< 0.0074
< 0.0074
< 0.0074
< 0.0074
< 0.0074
< 0.0074
< 0.0074
< 0.0074
0.0084 J
0.05
0.42
RR01-17A
10/19/01
0827
41 53.315
-83 21.060
0
6
26,000
52.6
52.7
<530
7.8
110
0.78
34
44
22,000
31
520
0.24
40
<0.33
<0.50
140
<1.4
< 1.9
< 1.4
14
< 1.5
< 1.4
<1.4
0.33 J
< 0.085
2.2
0.62
0.32
0.97
0.42
< 0.085
0.16J
0.15 J
< 0.085
< 0.085
< 0.085
< 0.085
< 0.085
< 0.085
< 0.085
< 0.085
< 0.085
4.53
14.00
RR01-17B
10/19/01
0827
41 53.315
-83 21.060
6
18
35,000
45.8
43.9
<460
7.0
150
2.6
46
48
20,000
62
410
0.43
39
0.44
<0.50
180
<0.29
<0.39
<0.29
3.0
<0.32
<0.29
<0.29
0.081 J
< 0.018
0.27
0.14
0.086
0.16
0.083
< 0.018
0.035 J
0.042 J
< 0.018
< 0.018
< 0.018
< 0.018
< 0.018
< 0.018
< 0.018
< 0.018
< 0.018
0.74
3.00
RR01-17C
10/19/01
0827
41 53.315
-83 21.060
18
51
61,000
45.4
43.1
630
6.3
240
3.6
54
73
23,000
120
430
0.72
45
0.80
0.65
290
< 0.0058
< 0.0077
< 0.0058
0.28
< 0.0063
< 0.0058
< 0.0058
< 0.001 2
< 0.00035
< 0.00035
0.0048
< 0.00035
0.0064
0.0045
0.0014
0.0052
0.0034
0.0038
0.0024
0.0015
0.0033
0.0024
0.0052
0.0021
0.0038
0.0067
0.06
0.28
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 3 of 13
-------
Appendix A
SEDIMENT CORE DATA
ANALYTICAL CHEMISTRY
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
Units
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-18A
10/15/01
0955
41 53.847
-83 21.065
0
6
49,000
55.6
56.4
840
9.2
140
1.6
730
360
16,000
100
300
5.1
140
1.4
0.83
410
<3.0
<4.0
<3.0
85
<3.3
<3.0
3.2 J
3.2
<0.18
4.8
2.5
2.0
4.8
0.50 J
<0.18
0.34 J
0.87
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
<0.18
18.17
85.00
RR01-18B
10/15/01
0955
41 53.847
-83 21.065
6
18
49,000
46.9
51.1
480
6.5
230
2.9
64
64
20,000
110
430
0.46
46
1.5
1.5
250
<2.7
<3.6
<2.7
92
<2.9
<2.7
3.0 J
4.7
<0.16
8.0
2.6
2.2
5.2
<0.16
<0.16
<0.16
1.3
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
24.00
92.00
RR01-18C
10/15/01
0955
41 53.847
-83 21.065
18
58
64,000
54.2
42.9
1,400
13
190
2.7
220
180
23,000
150
370
3.4
170
1.6
3.0
500
< 0.0058
< 0.0077
< 0.0058
0.33
< 0.0063
< 0.0058
0.11
0.015
< 0.00035
0.013
0.0086
0.0078
0.018
0.0045
0.0033
0.0098
0.010
0.0078
0.0050
0.0029
0.0067
0.0023
0.0071
0.0039
0.0055
0.0052
0.14
0.44
RR01-19A
10/15/01
1100
41 53.665
-83 20.684
0
6
26,000
58.6
50.5
<600
9.9
250
1.4
37
48
23,000
570
540
0.12
37
1.4
0.71
190
< 0.067
< 0.089
< 0.067
0.67
< 0.073
< 0.067
0.098 J
< 0.014
< 0.004
0.030
0.061
0.039
0.046
0.050
0.0060 J
0.014 J
0.020
0.0049 J
< 0.004
< 0.004
0.0065 J
< 0.004
< 0.004
< 0.004
< 0.004
< 0.004
0.25
0.67
RR01-19B
10/15/01
1100
41 53.665
-83 20.684
6
22
14,000
25.0
28.1
390
9.6
91
0.50
33
36
20,000
20
430
<0.10
33
1.1
<0.50
82
< 0.023
< 0.031
< 0.023
0.52
< 0.025
< 0.023
0.038 J
< 0.0097
< 0.0028
0.066
< 0.0028
0.033
0.052
0.015
< 0.0028
0.0054 J
0.013
< 0.0028
< 0.0028
< 0.0028
< 0.0028
< 0.0028
< 0.0028
< 0.0028
< 0.0028
< 0.0028
0.18
0.52
Field Dup
ofRR01-13A
RR01-21A
10/18/01
0926
41 54.011
-83 21.178
ponar
ponar
8,600
28.4
23.1
460
5.0
27
0.12
6.9
18
7,600
9.1
240
0.40
11
<0.26
1.7
26
< 1.7
<2.3
< 1.7
20
<1.9
< 1.7
1.9J
<0.36
<0.10
1.7
2.1
1.6
2.1
1.6
0.20 J
0.70
0.79
0.15J
<0.10
<0.10
0.18 J
<0.10
0.11 J
<0.10
<0.10
<0.10
10.59
20.00
Field Rep
ofRR01-05A
RR01-22A
10/18/01
1058
41 54.065
-83 21.257
0
5
21,000
36.0
32.4
<390
5.6
70
0.19
13
13
12,000
16
350
<0.10
17
<0.27
6.2
36
< 0.049
< 0.065
< 0.049
0.97
< 0.053
< 0.049
0.066 J
0.069
< 0.003
0.13
0.037
0.030
0.049
0.020
< 0.003
0.0084 J
0.013
< 0.003
< 0.003
< 0.003
0.0035 J
< 0.003
0.0034 J
< 0.003
< 0.003
< 0.003
0.35
0.97
Field Dup
ofRR01-03B
RR01-23B
10/18/01
1449
41 54.070
-83 21.352
6
18
32,000
48.4
48.8
<480
5.9
86
0.65
26
36
18,000
30
520
0.12
27
1.5
<0.50
110
< 0.0064
< 0.0086
< 0.0064
0.26
< 0.0070
< 0.0064
0.036
< 0.0068
< 0.0020
0.019
0.016
0.012
0.017
0.012
0.0022 J
0.0057 J
0.0072
0.0029 J
< 0.0020
< 0.0020
0.0027 J
< 0.0020
< 0.0020
< 0.0020
< 0.0020
< 0.0020
0.08
0.30
Field Rep
ofRR01-02A
RR01-24A
10/18/01
1602
41 54.076
-83 21.483
0
6
38,000
56.6
54.7
<570
6.9
110
0.79
35
44
20,000
41
510
0.19
33
1.6
<0.50
140
< 0.0073
< 0.0097
< 0.0073
0.27
< 0.0079
< 0.0073
0.042
< 0.0077
< 0.0022
0.021
0.031
0.026
0.035
0.024
0.0055 J
0.013
0.017
0.0066 J
< 0.0022
0.0029 J
0.0071 J
0.0026 J
0.0040 J
< 0.0022
0.0033 J
< 0.0022
0.17
0.31
Field Rep
ofRR01-02B
RR01-24B
10/18/01
1602
41 54.076
-83 21.483
6
18
49,000
49.9
35.4
<500
8.9
210
2.7
59
75
20,000
160
430
0.74
38
1.6
1.0
300
< 0.0051
< 0.0068
< 0.0051
0.28
< 0.0056
< 0.0051
0.093
< 0.0054
< 0.001 5
0.016
0.021
0.016
0.023
0.014
0.0039 J
0.012
0.012
0.009
0.0034 J
0.0042 J
0.010
0.0048 J
0.010
0.0030 J
0.0068
0.0049 J
0.15
0.37
Field Rep
ofRR01-02C
RR01-24C
10/18/01
1602
41 54.076
-83 21.483
18
46
130,000
64.5
62.4
830
10
590
5.6
100
170
21,000
620
350
2.1
43
1.8
3.3
900
< 0.0088
< 0.012
< 0.0088
0.44
< 0.0096
< 0.0088
0.30
< 0.0093
< 0.0027
0.0086 J
0.015
0.012
0.018
0.016
0.014
0.035
0.024
0.028
0.018
0.012
0.027
0.014
0.035
0.013
0.030
0.031
0.34
0.74
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 4 of 13
-------
Appendix A
SEDIMENT CORE DATA
ANALYTICAL CHEMISTRY
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
Units
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Field Dup
ofRR01-08B
RR01-25B
10/19/01
1010
41 54.039
-83 21.236
6
18
25,000
50.2
52.1
<500
7.8
120
0.74
39
45
23,000
32
590*
0.24
36
0.41
<0.50
130*
<0.69
<0.92
<0.69
26
<0.75
<0.69
1.6J
1.7
< 0.084
4.0
1.9
1.6
2.4
2.3
0.36
0.64
0.79
0.23 J
< 0.084
< 0.084
0.27 J
0.098 J
0.16 J
< 0.084
0.090 J
< 0.084
15.69
26.00
Field Dup
ofRR01-08C
RR01-25C
10/19/01
1010
41 54.039
-83 21.236
18
30
37,000
50.3
48.9
4,600
8.7
140
1.1
52
69
23,000
59
480
0.50
45
1.7
<0.50
190
<32
<43
<32
750
<35
<32
<32
77
<0.39
48
28
5.8
13
9.0
1.8
4.3
4.8
2.4
0.44 J
0.77 J
1.9
1.2J
2.0
0.40 J
1.1 J
<0.39
198.00
750.00
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 5 of 13
-------
ANALYTICAL CHEMISTRY
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOG
Total Phosphorus
TKN
Ammonia Nitrogen
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
SEM-AVS
Cadmium
Copper
Lead
Nickel
Silver
Zinc
Total SEM
Acid Volatile Sulfide (AVS)
SEM-AVS
PAHs
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1,2,3-cd)pyrene
Dibenzo(a,h)anthracene
Benzo(g,h,i)perylene
Total of PAHs (< data not used)
Appendix A
PONAR DATA
Method
GPS
GPS
Walkley-Black
6010
351.2
350.1
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
6010B
6010B
6010B
6010B
6010B
6010B
821-R-91-100
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
Units
mm/dd/yy
hhhh
dd mm.mmm
dd mm.mmm
inches
inches
mg/kg
mg/kg
mg/kg
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
umoles/g
umoles/g
umoles/g
umoles/g
umoles/g
umoles/g
umoles/g
umoles/g
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-01P
10/17/01
0937
41 53.963
-83 21.663
ponar
ponar
33,000
1,300
2,200
130
61.9
60.8
n/r
8.8
140
0.96
40
51
25000
39
630
0.16
38
1.2
<0.50
150
0.0079 J
0.48
0.12
0.30
< 0.00082
1.5
2.4
6.1
(3.7)
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
<0.89
0.0
RR01-02P
10/19/01
1729
41 54.074
-83 21.487
ponar
ponar
27,000
770
2,100
40
53.6
57.7
n/r
6.6
94
0.63
27
34
16,000
28
410
<0.10
27
1.6
<0.50
110
0.0064 J
0.39
0.11
0.24
< 0.00077
1.2
1.9
5.5
(3.6)
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
0.83
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
0.8
RR01-04P
10/20/01
0832
41 54.068
-83 21.274
ponar
ponar
31,000
840
2,000
89
54.3
56.1
n/r
6.0
86
0.59
25
32
17,000
23
360
<0.10
26
1.4
<0.50
95
0.0073 J
0.43
0.11
0.27
< 0.00073
1.3
2.1
6.3
(4.2)
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
0.0
RR01-06P
10/20/01
0916
41 54.053
-83 21.250
ponar
ponar
7,000 *
375
400
2.1 *
17.6
32.4
n/a
7.3
51
0.12
12
14
10,000
8.1
270
<0.10
17
<0.2
<0.50
43
0.0035 J
0.14
0.032
0.14 J
< 0.00048
0.42
0.6
0.6 U
0.0
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
0.38
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
0.4
RR01-08P
10/20/01
0958
41 54.038
-83 21.231
ponar
ponar
19,000*
610
440
6.7*
20.4
37.2
n/r
4.8
46
0.26
12
27
10,000
12
320
<0.10
18
<0.21
<0.50
51 *
0.0043 J
0.21
0.040
0.15 J
< 0.00051
0.50
0.8
2.5
(1.8)
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
<0.43
0.0
RR01-12P
10/19/01
1359
41 54.010
-83 21.194
ponar
ponar
24,000
990
2,200
45
56.2
58.3
n/r
7.1
110
0.79
30
45
22,000
31
540
<0.10
35
1.6
<0.50
140
0.0075 J
0.47
0.10
0.28
< 0.00077
1.4
2.3
J 5.2
(3.0)
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
<0.78
0.0
RR01-17P
10/19/01
1526
41 33.914
-83 21.064
ponar
ponar
28,000
950
2,000
46
53.9
52.5
n/r
6.7
100
0.71
31
46
20,000
34
480
<0.10
36
<0.38
<0.50
130
0.0077 J
0.48
0.12
0.33
< 0.00068
1.4
2.3
6.3
(4.0)
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
0.0
RR01-18P
10/19/01
1614
41 53.857
-83 20.984
ponar
ponar
23,000
750
2,200
34
53.2
52.1
n/r
5.9
79
0.55
29
37
15,000
31
310
<0.10
26
<0.4
<0.50
110
0.0072 J
0.53
0.13
0.30
< 0.00067
1.4
2.4
8.0
(5.6)
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
<0.73
0.0
Field Dup
ofRR01-17P
RR01-21P
10/19/01
1556
41 33.914
-83 21.064
ponar
ponar
36,000
970
850
44
54.0
54.7
n/r
7.6
110
0.75
33
41
22,000
28
490
<0.10
36
<0.29
<0.50
130
0.0080 J
0.49
0.11
0.35
< 0.00071
1.4
2.4
6.2
(3.9)
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
<0.74
0.0
Field Rep
OIRR01-04P
RR01-22P
10/20/01
0859
41 54.068
-83 21.274
ponar
ponar
27,000
1,000
2,300
53
55.9
56.8
n/r
8.2
130
0.77
33
42
22,000
32
550
<0.10
36
<0.35
<0.50
140
0.0069 J
0.43
0.10
0.27
< 0.00074
1.3
2.1
5.3
(3.2)
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
<0.77
0.0
Appendix A page 6 of 13
-------
Appendix A
PONAR DATA
Parameters
Sample ID
Date Collected
Time Collected
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18(2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,51-Tetrachlorobiphenyl)
PCB 52 (2,2',5,51-Tetrachlorobiphenyl)
PCB 66 (2,3',4,41-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,51-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,51-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,41,51-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,51-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,41,5,51-Hexachlorobiphenyl)
PCB 170 (2,2',3,31,4,41,5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,41,5,51-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,41,51,6-Heptachlorobiphenyl)
PCB 187 (2,2',3,41,5,51,6-Heptachlorobiphenyl)
PCB 206 (2,2',3,31,4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed
Total of 7 Aroclors (< detection limit assumed = 0)
Method
8082
8082
8082
8082
8082
8082
8082
jmed = 0)
Units
mm/dd/yy
hhhh
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-01P
10/17/01
0937
< 0.0084
< 0.011
< 0.0084
0.18
< 0.0092
< 0.0084
0.041 J
< 0.0018
< 0.00051
0.014
< 0.00051
0.014
0.018
0.012
0.0023
< 0.00051
0.0078
0.0033
0.00059 J
0.0011 J
0.0033
0.00090 J
0.0013 J
< 0.00051
0.0016 J
< 0.00051
0.07
0.18
RR01-02P
10/19/01
1729
< 0.0078
< 0.010
< 0.0078
0.19
< 0.0085
< 0.0078
0.027 J
0.011
< 0.00047
0.012
0.018
0.016
0.019
0.014
0.0038
0.0065
0.010
< 0.00047
0.0011 J
0.0012 J
0.0038
0.0017
0.0031
0.00073 J
0.0019
< 0.00047
0.12
0.19
RR01-04P
10/20/01
0832
<0.15
<0.20
<0.15
3.9
<0.16
<0.15
0.61 J
0.24
< 0.0091
0.66
0.26
0.27
0.37
0.15
0.029 J
0.075
0.13
0.044
< 0.0091
0.018 J
0.048
0.022 J
0.041
< 0.0091
0.031 J
< 0.0091
2.29
3.90
RR01-06P
10/20/01
0916
< 0.098
<0.13
< 0.098
4.1
<0.11
< 0.098
0.31 J
0.54
< 0.015
1.0
0.31
0.29
0.43
0.19
0.023 J
0.092
0.15
0.035 J
< 0.015
0.015 J
0.047 J
0.017 J
0.031 J
< 0.015
0.023 J
< 0.015
3.00
4.10
RR01-08P
10/20/01
0958
<0.53
<0.70
<0.53
18
<0.57
<0.53
0.95 J
0.70
< 0.032
1.1
1.1
0.94
1.1
1.1
0.13
0.32
0.39
0.10 J
< 0.032
< 0.032
0.12
0.048 J
0.065 J
< 0.032
0.043 J
< 0.032
7.00
18.00
RR01-12P
10/19/01
1359
<0.79
< 1.1
<0.79
10
<0.86
<0.79
<0.79
< 0.17
< 0.048
0.66
0.96
0.74
0.94
1.1
0.15 J
0.35
0.36
0.12 J
< 0.048
< 0.048
0.12 J
0.051 J
0.081 J
< 0.048
0.049 J
< 0.048
5.11
10.00
RR01-17P
10/19/01
1526
<0.14
<0.19
<0.14
5.4
<0.15
<0.14
0.30 J
0.16 J
< 0.017
0.84
0.30
0.22
0.39
0.26
0.034 J
0.084
0.10
0.033 J
< 0.017
< 0.017
0.045 J
0.018 J
0.029 J
< 0.017
0.020 J
< 0.017
2.19
5.40
RR01-18P
10/19/01
1614
< 0.069
< .092
< 0.069
1.4
< 0.075
< 0.069
0.18 J
0.059 J
< 0.0084
0.16
0.21
0.15
0.20
0.18
0.026 J
0.060
0.083
0.028 J
< 0.0084
< 0.0084
0.027 J
0.012 J
0.022 J
< 0.0084
0.014 J
< 0.0084
1.04
1.40
Field Dup
ofRR01-17P
RR01-21P
10/19/01
1556
<0.15
<0.19
<0.15
5.1
<0.16
<0.15
0.38 J
0.16
< 0.0088
0.72
0.32
0.25
0.39
0.31
0.045
0.11
0.14
0.047
0.011 J
< 0.0088
0.044
0.022 J
0.037
< 0.0088
0.023 J
< 0.0088
2.57
5.10
Field Rep
OIRR01-04P
RR01-22P
10/20/01
0859
<0.38
<0.51
<0.38
7.0
<0.42
<0.38
1.7 J
0.31 J
< 0.023
0.85
0.28
0.25
0.43
0.16
0.028 J
0.099
0.13
0.051 J
< 0.023
0.034 J
0.068 J
0.033 J
0.047 J
< 0.023
0.041 J
< 0.023
2.20
7.00
* Results do not meet QC acceptance criteria, see narrative
n/r - not run
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02Awasnot analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 7 of 13
-------
Appendix A
GRAIN SIZE DATA
Sample
ID No.
RR01-01P
RR01-02P
RR01-04P
RR01-06P
RR01-08P
RR01-12P
RR01-17P
RR01-18P
RR01-21P
RR01-22P
% Gravel
CRS | Fine
0.0
0.0
0.0
16.4
1.4
0.0
0.0
2.7
0.0
0.0
% Sand
7.5
26.5
21.8
62.9
84.7
8.2
12.2
64.1
15.0
19.1
% Fines
Silt | Clay
92.5
73.5
78.2
20.7
13.9
91.8
87.8
33.2
85.0
80.9
Total
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
Test Method - ASTM D-422
NOTE: RR01-06P contained 2.9% zebra mussel shells
RR01-08P contained 0.9% zebra mussel shells
RR01-18P contained 18.21 g of shells
Appendix A page 8 of 13
-------
Appendix A
ANALYTICAL CHEMISTRY
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method Units
mm/dd/yy
hhhh
GPS dd mm.mmm
GPS dd mm.mmm
inches
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
= 0)
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-02A
10/18/01
1545
41 54.076
-83 21.483
0
6
34,000
54.2
n/r
<540
8.1
110
0.8
32
38
20,000
34
470
0.14
30
<0.36
<0.50
120
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
.
F/e/d Rep
ofRR01-02A
RR01-24A
10/18/01
1602
41 54.076
-83 21.483
0
6
38,000 11%
56.6 4%
54.7
< 570 0%
6.9 16%
110 0%
0.79 1%
35 9%
44 15%
20,000 0%
41 19%
510 8%
0.19 30%
33 10%
1.6 127%
< 0.50 0%
140 15%
< 0.0073
< 0.0097
< 0.0073
0.27
< 0.0079
< 0.0073
0.042
< 0.0077
< 0.0022
0.021
0.031
0.026
0.035
0.024
0.0055 J
0.013
0.017
0.0066 J
< 0.0022
0.0029 J
0.0071 J
0.0026 J
0.0040 J
< 0.0022
0.0033 J
< 0.0022
0.17 N/A
0.31 N/A
RR01-02B
10/18/01
1545
41 54.076
-83 21.483
6
18
39,000
53.6
51.1
<540
5.9
110
0.81
34
47
20,000
41
520
0.19
34
1.7
<0.50
140
<0.009
<0.012
<0.009
0.51
<0.009
<0.009
0.12
<0.72
<0.20
1.6
0.58 J
0.55 J
1.0
0.50 J
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
2.60
0.63
Field Rep
ofRR01-02B
RR01-24B
10/18/01
1602
41 54.076
-83 21.483
6
18
49,000 23%
49.9 7%
35.4 36%
< 500 0%
8.9 41%
210 63%
2.7 108%
59 54%
75 46%
20,000 0%
160 118%
430 19%
0.74 118%
38 11%
1.6 6%
1.0 67%
300 73%
< 0.0051
< 0.0068
< 0.0051
0.28
< 0.0056
< 0.0051
0.093
< 0.0054
< 0.001 5
0.016
0.021
0.016
0.023
0.014
0.0039 J
0.012
0.012
0.009
0.0034 J
0.0042 J
0.010
0.0048 J
0.010
0.0030 J
0.0068
0.0049 J
0.15 178%
0.37 51%
RR01-02C
10/18/01
1545
41 54.076
-83 21.483
18
62
84,000
55.6
54.4
<560
8.3
300
3.4
77
120
18,000
290
440
1.4
37
<0.36
2.2
530
< 0.0072
< 0.0096
< 0.0072
0.43
< 0.0072
< 0.0072
0.28
< 0.0077
< 0.0022
0.015
< 0.0022
0.017
0.025
0.017
0.0070 J
0.020
0.017
0.013
0.0062 J
0.0057 J
0.014
0.0061 J
0.014
0.0044 J
0.010
0.013
0.18
0.71
Field Rep
ofRR01-02C
RR01-24C
10/18/01
1602
41 54.076
-83 21.483
18
46
130,000 43%
64.5 15%
62.4 14%
830 39%
10 19%
590 65%
5.6 49%
100 26%
170 34%
21,000 15%
620 73%
350 23%
2.1 40%
43 15%
1.8 133%
3.3 40%
900 52%
< 0.0088
< 0.012
< 0.0088
0.44
< 0.0096
< 0.0088
0.30
< 0.0093
< 0.0027
0.0086 J
0.015
0.012
0.018
0.016
0.014
0.035
0.024
0.028
0.018
0.012
0.027
0.014
0.035
0.013
0.030
0.031
0.34 65%
0.74 4%
RR01-03B
10/18/01
1444
41 54.070
-83 21.352
6
18
34,000
49.7
48.4
<500
9.8
150
0.86
44
45
26,000
36
650
0.21
37
1.7
<0.50
140
< 0.032
< 0.043
< 0.032
0.32
< 0.035
< 0.032
0.063 J
< 0.0068
< 0.001 9
< 0.001 9
0.024
0.019
0.025
0.018
0.0030 J
0.0076
0.011
0.0046 J
< 0.001 9
< 0.001 9
0.0044 J
< 0.001 9
0.0029 J
< 0.001 9
0.0021 J
< 0.001 9
0.10
0.32
Field Dup
ofRR01-03B
RR01-23B
10/18/01
1449
41 54.070
-83 21.352
6
18
32,000
48.4
48.8
<480
5.9
86
0.65
26
36
18,000
30
520
0.12
27
1.5
<0.50
110
< 0.0064
< 0.0086
< 0.0064
0.26
< 0.0070
< 0.0064
0.036
< 0.0068
< 0.0020
0.019
0.016
0.012
0.017
0.012
0.0022 J
0.0057 J
0.0072
0.0029 J
< 0.0020
< 0.0020
0.0027 J
< 0.0020
< 0.0020
< 0.0020
< 0.0020
< 0.0020
0.08
0.30
6%
3%
1%
0%
50%
54%
28%
51%
22%
36%
18%
22%
55%
31%
13%
0%
24%
23%
8%
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 9 of 13
-------
Appendix A
ANALYTICAL CHEMISTRY
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Oil and Grease
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',51,6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed (< detection limit assumed = 0)
Total of 7 Aroclors (< detection limit assumed = 0)
Method
GPS
GPS
Walkley-Black
D2974
EPA 160.3 modified
9071
6020
6020
6020
6020
6020
6010
6020
6010
7471
6020
6020
6010
6020
8082
8082
8082
8082
8082
8082
8082
= 0)
Units
mm/dd/yy
hhhh
dd mm.mmm
ddmm.mmm
inches
inches
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-05A
10/18/01
1034
41 54.065
-83 21.275
0
4
22,000
34.5
31.1
<380
4.7
74
0.26
9.3
12
12,000
8.6
360
<0.10
18
<0.29
<0.50
36
< 0.024
< 0.032
< 0.024
0.40
< 0.026
< 0.024
< 0.024
0.028
< 0.00029
0.024
0.0037
0.0026
0.0047
0.0017
< 0.00029
0.00097 J
0.0012
0.00043 J
0.00030 J
0.00032 J
0.00067 J
< 0.00029
0.00058 J
< 0.00029
0.00044 J
< 0.00029
0.07
0.40
Field Rep
ofRR01-05A
RR01-22A
10/18/01
1058
41 54.065
-83 21.257
0
5
21,000 5%
36.0 4%
32.4 4%
< 390 0%
5.6 17%
70 6%
0.19 31%
13 33%
13 8%
12,000 0%
16 60%
350 3%
<0.10 0%
17 6%
< 0.27 0%
6.2 170%
36 0%
< 0.049
< 0.065
< 0.049
0.97
< 0.053
< 0.049
0.066 J
0.069
< 0.003
0.13
0.037
0.030
0.049
0.020
< 0.003
0.0084 J
0.013
< 0.003
< 0.003
< 0.003
0.0035 J
< 0.003
0.0034 J
< 0.003
< 0.003
< 0.003
0.35 136%
0.97 83%
RR01-08B
10/19/01
0953
41 54.039
-83 21.236
6
18
26,000
51.0
50.7
<510
8.3
130
2.0
40
51
24,000
220
590
0.33
40
1.8
<0.50
150
<3.3
<4.5
<3.3
46
<3.7
<3.3
<3.3
1.7
< 0.041
3.1
1.0
0.6
1.2
0.75
0.095 J
0.23
0.27
0.082 J
< 0.041
< 0.041
0.088 J
0.045 J
0.075 J
< 0.041
0.044 J
< 0.041
8.85
46.00
Field Dup
ofRR01-08B
RR01-25B
10/19/01
1010
41 54.039
-83 21.236
6
18
25,000 4%
50.2 2%
52.1 3%
< 500 0%
7.8 6%
120 8%
0.74 92%
39 3%
45 13%
23,000 4%
32 149%
590 0%
0.24 32%
36 11%
0.41 126%
< 0.50 0%
130 14%
<0.69
<0.92
<0.69
26
<0.75
<0.69
1.6J
1.7
< 0.084
4.0
1.9
1.6
2.4
2.3
0.36
0.64
0.79
0.23 J
< 0.084
< 0.084
0.27 J
0.098 J
0.16 J
< 0.084
0.090 J
< 0.084
15.69 56%
26.00 56%
RR01-08C
10/19/01
0953
41 54.039
-83 21.236
18
30
40,000
49.0
48.9
<490
8.5
160
1.1
54
66
23,000
54
510
0.43
42
<0.34
<0.50
190
<6.5
<8.6
<6.5
300
<7.0
<6.5
24 J
75
<0.39
42
23
5.1
11
7.8
1.6
3.9
4.3
2.0
0.45 J
0.53 J
1.8
1.0J
1.8
<0.39
0.94 J
<0.39
179.30
300.00
Field Dup
ofRR01-08C
RR01-25C
10/19/01
1010
41 54.039
-83 21.236
18
30
37,000 8%
50.3 3%
48.9 0%
4,600 0%
8.7 2%
140 13%
1.1 0%
52 4%
69 4%
23,000 0%
59 9%
480 6%
0.50 15%
45 7%
1.7 133%
< 0.50 0%
190 0%
<32
<43
<32
750
<35
<32
<32
77
<0.39
48
28
5.8
13
9.0
1.8
4.3
4.8
2.4
0.44 J
0.77 J
1.9
1.2J
2.0
0.40 J
1.1 J
<0.39
198.00 10%
750.00 86%
RR01-13A
10/18/01
0826
41 54.011
-83 21.178
ponar
ponar
7,700
19.9
18.7
800
4.6
29
0.13
12
22
8,200
15
250
<0.10
13
<0.20
<0.50
32
<1.6
<2.2
< 1.6
20
< 1.8
< 1.6
2.0 J
1.2J
< 0.098
2.3
0.54
0.48
0.84
0.61
< 0.098
0.22 J
0.25 J
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
4.77
20.00
Field Dup
ofRR01-13A
RR01-21A
10/18/01
0926
41 54.011
-83 21.178
ponar
ponar
8,600
28.4
23.1
460
5.0
27
0.12
6.9
18
7,600
9.1
240
0.40
11
<0.26
1.7
26
<1.7
<2.3
< 1.7
20
< 1.9
< 1.7
1.9J
<0.36
<0.10
1.7
2.1
1.6
2.1
1.6
0.20 J
0.70
0.79
0.15J
<0.10
<0.10
0.18 J
<0.10
0.11 J
<0.10
<0.10
<0.10
10.59
20.00
11%
35%
21%
0%
8%
7%
8%
54%
20%
8%
49%
4%
120%
17%
0%
109%
21%
76%
0%
* Results do not meet QC acceptance criteria, see narrative
J - Estimated value. Result is above MDL, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit.
Use RR01-02P analysis as a surrogate.
Appendix A page 10 of 13
-------
Appendix A
QA/QC DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed
Total of Aroclors
Method
GPS
GPS
Walkley-Black
8082
8082
8082
8082
8082
8082
8082
Units
mm/dd/yy
hhhh
dd.ddddd
dd.ddddd
inches
inches
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-02A
10/18/01
1545
41.90127
-83.35805
0
6
34,000
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
Field Rep
01RR01-02A
RR01-24A
10/18/01
1602
41.90127
-83.35805
0
6
38,000
0.0073
0.0097
0.0073
0.27
0.0079
0.0073
0.042
0.0077
0.0022
0.021
0.031
0.026
0.035
0.024
0.0055
0.013
0.017
0.0066
0.0022
0.0029
0.0071
0.0026
0.004
0.0022
0.0033
0.0022
0.22
0.35
U
U
U
U
U
U
U
J
J
U
J
J
J
J
U
J
U
11%
RR01-02B
10/18/01
1545
41.90127
-83.35805
6
18
39,000
<0.0066
< 0.0088
<0.0066
<0.0066
0.49
<0.0066
0.043
<0.72
<0.20
1.6
0.58
0.55
1.0
0.5
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
4.23
0.53
U
U
U
U
U
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
Field Rep
01RR01-02B
RR01-24B
10/18/01
1602
41.90127
-83.35805
6
18
49,000
< 0.0090
< 0.01 20
< 0.0090
< 0.0090
0.51
< 0.0090
0.12
< 0.0054
< 0.001 5
0.016
0.021
0.016
0.023
0.014
0.0039
0.012
0.012
0.009
0.0034
0.0042
0.010
0.0048
0.010
0.003
0.0068
0.0049
0.17
0.63
U
U
U
U
U
U
U
J
J
J
J
J
J
23%
RR01-02C
10/18/01
1545
41.90127
-83.35805
18
62
84,000
< 0.0072
< 0.0096
< 0.0072
0.43
< 0.0072
< 0.0072
0.28
< 0.0077
< 0.0022
0.015
< 0.0022
0.017
0.025
0.017
0.007
0.020
0.017
0.013
0.0062
0.0057
0.014
0.0061
0.014
0.0044
0.010
0.013
0.20
0.71
Field Rep
01RR01-02C
RR01-24C
10/18/01
1602
41.90127
-83.35805
18
46
130,000
U < 0.0088
U < 0.012
U < 0.0088
0.44
U < 0.0096
U < 0.0088
0.30
U < 0.0093
U < 0.0027
0.0086
U 0.015
0.012
0.018
0.016
J 0.014
0.035
0.024
0.028
J 0.018
J 0.012
0.027
J 0.014
0.035
J 0.013
0.030
0.031
0.35
0.74
U
U
U
U
U
U
U
J
43%
RR01-03B
10/18/01
1444
41.90117
-83.35587
6
18
34,000
< 0.032
< 0.043
< 0.032
0.32
< 0.035
< 0.032
0.063
< 0.0068
< 0.001 9
< 0.001 9
0.024
0.019
0.025
0.018
0.003
0.0076
0.011
0.0046
< 0.001 9
< 0.001 9
0.0044
< 0.001 9
0.0029
< 0.001 9
0.0021
< 0.001 9
0.12
0.38
U
U
U
U
U
J
U
U
U
J
J
U
U
J
U
J
U
J
U
Field Dup
01RR01-03B
RR01-23B
10/18/01
1449
41.90117
-83.35587
6
18
32,000
< 0.0064
< 0.0086
< 0.0064
0.26
< 0.0070
< 0.0064
0.036
< 0.0068
< 0.0020
0.019
0.016
0.012
0.017
0.012
0.0022
0.0057
0.0072
0.0029
< 0.0020
< 0.0020
0.0027
< 0.0020
< 0.0020
< 0.0020
< 0.0020
< 0.0020
0.10
0.30
U
U
U
U
U
U
U
J
J
J
U
U
J
U
U
U
U
U
* Results do not meet QC acceptance criteria, see narrative
n/r - not run
J - Estimated value. Result is above method detection limit, but below limit of quanitation
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transit. Use RR01-02P analysis as a surrogate.
Appendix A page 11 of 13
-------
Appendix A
QA/QC DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed
Total of Aroclors
GPS
GPS
mm/dd/yy
hhhh
dd.ddddd
dd.ddddd
inches
inches
Walkley-Black mg/kg
8082
8082
8082
8082
8082
8082
8082
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR01-04P
10/20/01
0832
41.90113
-83.35457
ponar
ponar
31,000
<0.15
<0.20
<0.15
3.9
<0.16
<0.15
0.61
0.24
< 0.0091
0.66
0.26
0.27
0.37
0.15
0.029
0.075
0.13
0.044
< 0.0091
0.018
0.048
0.022
0.041
< 0.0091
0.031
< 0.0091
2.39
4.51
U
U
U
U
U
J
U
J
U
J
J
U
J
U
Field Rep
01RR01-04P
RR01-22P
10/20/01
0859
41.90113
-83.35457
ponar
ponar
27,000
<0.38
<0.51
<0.38
7.0
<0.42
<0.38
1.7
0.31
< 0.023
0.85
0.28
0.25
0.43
0.16
0.028
0.099
0.13
0.051
< 0.023
0.034
0.068
0.033
0.047
< 0.023
0.041
< 0.023
2.81
8.70
U
U
U
U
U
J
J
U
J
J
U
J
J
J
J
U
J
U
RR01-05A
10/18/01
1034
41.90109
-83.35429
0
4
-14% 22,000
< 0.024
< 0.032
< 0.024
0.40
< 0.026
< 0.024
< 0.024
0.028
< 0.00029
0.024
0.0037
0.0026
0.0047
0.0017
< 0.00029
0.00097
0.0012
0.00043
0.0003
0.00032
0.00067
< 0.00029
0.00058
< 0.00029
0.00044
< 0.00029
0.07
63% 0.40
U
U
U
U
U
U
U
U
J
J
J
J
J
U
J
U
J
U
Field Rep
01RR01-05A
RR01-22A
10/18/01
1058
41.90109
-83.35429
0
5
21,000
< 0.049
< 0.065
< 0.049
0.97
< 0.053
< 0.049
0.066
0.069
< 0.003
0.13
0.037
0.030
0.049
0.020
< 0.003
0.0084
0.013
< 0.003
< 0.003
< 0.003
0.0035
< 0.003
0.0034
< 0.003
< 0.003
< 0.003
0.36
1.04
U
U
U
U
U
J
U
U
J
U
U
U
J
U
J
U
U
U
RR01-08B
10/19/01
0953
41.90065
-83.35393
6
18
26,000
<3.3
<4.5
<3.3
46
<3.7
<3.3
<3.3
1.7
< 0.041
3.1
1.0
0.6
1.2
0.75
0.095
0.23
0.27
0.082
< 0.041
< 0.041
0.088
0.045
0.075
< 0.041
0.044
< 0.041
9.28
46.00
U
U
U
U
U
U
U
J
J
U
U
J
J
J
U
J
U
Field Dup
01RR01-08B
RR01-25B
10/19/01
1010
41.90065
-83.35393
6
18
25,000
<0.69
<0.92
<0.69
26
<0.75
<0.69
1.6
1.7
< 0.084
4.0
1.9
1.6
2.4
2.3
0.36
0.64
0.79
0.23
< 0.084
< 0.084
0.27
0.098
0.16
< 0.084
0.09
< 0.084
16.54
27.60
U
U
U
U
U
J
U
J
U
U
J
J
J
U
J
U
RR01-08C
10/19/01
0953
41.90065
-83.35393
18
30
-4% 40,000
<6.5
<8.6
<6.5
300
<7.0
<6.5
24
75
<0.39
42
23
5.1
11
7.8
1.6
3.9
4.3
2.0
0.45
0.53
1.8
1
1.8
<0.39
0.94
<0.39
182.22
-50% 324.00
U
U
U
U
U
U
U
U
* Results do not meet QC acceptance criteria, see narrative
n/r - not run
J - Estimated value. Result is above method detection limit, but below limit of quar
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transi
Appendix A page 12 of 13
-------
Appendix A
QA/QC DATA
Parameters
Sample ID
Date Collected
Time Collected
Latitude
Longitude
Slice Start Depth
Slice End Depth
TOC
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight) 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',S'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,41,5,51,6-Nonachlorobiphenyl)
Total of 19 Congeners Analyzed
Total of Aroclors
Method
GPS
GPS
Walkley-Black
8082
8082
8082
8082
8082
8082
8082
Units
mm/dd/yy
hhhh
dd.ddddd
dd.ddddd
inches
inches
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Field Dup
01RR01-08C
RR01-25C
10/19/01
1010
41.90065
-83.35393
18
30
37,000
<32
<43
<32
750
<35
<32
<32
77
<0.39
48
28
5.8
13
9.0
1.8
4.3
4.8
2.4
0.44
0.77
1.9
1.2
2.0
0.4
1.1
<0.39
201.91
750.00
U
U
U
U
U
U
U
U
RR01-13A
10/18/01
0826
41.90020
-83.35297
ponar
ponar
7,700
< 1.6
<2.2
< 1.6
20
< 1.8
<1.6
2
1.2
< 0.098
2.3
0.54
0.48
0.84
0.61
< 0.098
0.22
0.25
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
< 0.098
6.44
22.00
U
U
U
U
U
J
J
U
U
J
J
U
U
U
U
U
U
U
U
U
Field Dup
01RR01-13A
RR01-21A
10/18/01
0926
41.90020
-83.35297
ponar
ponar
8,600
< 1.7
<2.3
< 1.7
20
< 1.9
<1.7
1.9
<0.36
<0.10
1.7
2.1
1.6
2.1
1.6
0.2
0.70
0.79
0.15
<0.10
<0.10
0.18
<0.10
0.11
<0.10
<0.10
<0.10
11.23
21.90
U
U
U
U
U
J
U
U
J
J
U
U
J
U
J
U
U
U
11%
RR01-17P
10/19/01
1526
41.89857
-83.35107
ponar
ponar
28,000
<0.14
<0.19
<0.14
5.4
<0.15
< 0.14
0.3
0.16
< 0.017
0.84
0.30
0.22
0.39
0.26
0.034
0.084
0.10
0.033
< 0.017
< 0.017
0.045
0.018
0.029
< 0.017
0.02
< 0.017
2.53
5.70
U
U
U
U
U
J
J
U
J
U
U
J
J
J
U
J
U
Field Dup
01RR01-17P
RR01-21P
10/19/01
1556
41.89857
-83.35107
ponar
ponar
36,000
<0.15
<0.19
<0.15
5.1
<0.16
<0.15
0.38
0.16
< 0.0088
0.72
0.32
0.25
0.39
0.31
0.045
0.11
0.14
0.047
0.011
< 0.0088
0.044
0.022
0.037
< 0.0088
0.023
< 0.0088
2.63
5.48
U
U
U
U
U
J
U
J
U
J
U
J
U
25%
* Results do not meet QC acceptance criteria, see narrative
n/r - not run
J - Estimated value. Result is above method detection limit, but below limit of quar
Sample RR01-02A was not analyzed by Lancaster since the sample broke in transi
Appendix A page 13 of 13
-------
Appendix B
FISH TISSUE
FISH TISSUE
Parameters
Replicate #
Date Collected
Latitude
Longitude
Location Description
PCB Aroclors
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Total PCB Aroclors
PCB Congeners
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,51-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4l,5,5l,6-Nonachlorobiphenyl)
Total of 19 PCB Congeners
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Method
Units
NAD83 dd.mmmm
NAD83 dd.mmmm
RR02-C1 RR02-C1
Rep #1 Rep #2
8/20/02
41.8965 41.8965
-83.3482 -83.3482
Near DE Canal Near DE Canal
8082
8082
8082
8082
8082
8082
8082
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.033
< 0.033
< 0.033
< 0.033
0.580
< 0.033
< 0.033
0.580
< 0.0035
< 0.0010
< 0.0010
0.0130
0.0210
0.0280
0.0180
0.0012 J
0.0065
0.0093
< 0.0010
< 0.0010
0.0012 J
0.0043
< 0.0010
< 0.0010
< 0.0010
0.0010 J
< 0.0010
< 0.033
< 0.033
< 0.033
< 0.033
0.460
< 0.033
< 0.033
0.460
< 0.0035
< 0.0010
0.0180
0.0140
0.0240
0.0310
0.0210
0.0039
0.0076
0.0110
0.0046
< 0.0010
0.0015 J
0.0052
< 0.0010
< 0.0010
< 0.0010
0.0019 J
< 0.0010
mg/kg
0.1001
0.1403
RR02-C1
Rep #3
< 0.033
< 0.033
< 0.033
< 0.033
0.510
< 0.033
< 0.033
0.510
< 0.0035
< 0.0010
0.0190
0.0160
0.0270
0.0340
0.0240
0.0045
0.0088
0.0130
0.0054
< 0.0010
0.0018 J
0.0061
< 0.0010
0.0010 J
< 0.0010
0.0019 J
< 0.0010
0.1578
41.8965
-83.3482
RR02-C1
Rep #4
41.8965
-83.3482
Total Aroclors
Total Congeners
< 0.033
< 0.033
< 0.033
< 0.033
0.860
< 0.033
< 0.033
0.860
< 0.0035
< 0.0010
0.0170
0.0130
0.0230
0.0300
0.0200
0.0039
0.0073
0.0100
0.0045
< 0.0010
0.0015 J
0.0050
< 0.0010
< 0.0010
< 0.0010
0.0017 J
< 0.0010
0.1337
C1 AVERAGE
0.603
0.133
LOCATION AVG PCB CONC.
Near RR Bridge (Upsteam of SRA) 0.00
Adjacent to SRA 0.77
River Mouth (Downstream of SRA) 0.60
Appendix B page I of 6
-------
Appendix B
FISH TISSUE
FISH TISSUE
Parameters
Replicate #
Date Collected
Latitude
Longitude
Location Description
Method
Units
NAD83 dd.mmmm
NAD83 dd.mmmm
RR02-C2
Rep#1
8/20/02
41.9001
-83.3551
Just downstream of turn
basin
RR02-C2
Rep #2
41.9001
-83.3551
RR02-C2
Rep #3
41.9001
-83.3551
Just downstrearr
basin
Just downstream of turn
basin
RR02-C2
Rep #4
41.9001
-83.3551
Just downstream of turning
basin
PCB Aroclors
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Total PCB Aroclors
PCB Congeners
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4l,5,5l,6-Nonachlorobiphenyl)
Total of 19 PCB Congeners
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
8082
8082
8082
8082
8082
8082
8082
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.033
< 0.033
< 0.033
< 0.033
0.780
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
0.680
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
0.850
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
0.770
< 0.033
< 0.033
mg/kg
0.780
0.680
0.850
0.770
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.0035
< 0.0010
0.0190
< 0.0010
0.0210
0.0320
0.0150
< 0.0010
0.0057
0.0093
0.0034 J
< 0.0010
< 0.0010
0.0041
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.1061
< 0.0028
< 0.0008
0.0250
0.0180
0.0260
0.0360
0.0190
0.0036
0.0076
0.0120
0.0042
< 0.0008
0.0015 J
0.0049
0.0011 J
0.00097 J
< 0.0008
0.0017 J
< 0.0008
0.1563
< 0.0028
< 0.0008
0.0260
0.0190
0.0280
0.0390
0.0200
0.0039
0.0079
0.0120
0.0044
0.00083 J
0.0016 J
0.0053
< 0.0008
0.0010 J
< 0.0008
0.0017 J
< 0.0008
0.1655
Total Aroclors
Total Congeners
< 0.0028
< 0.0008
0.0320
0.0250
0.0340
0.0470
0.0250
0.0047
0.0099
0.0150
0.0060
0.0010 J
0.0021 J
0.0064
0.0011 J
0.0014 J
< 0.0008
0.0024 J
< 0.0008
0.2050
C2 AVERAGE
0.770
0.158
Appendix B page 2 of 6
-------
Appendix B
FISH TISSUE
FISH TISSUE
Parameters
Replicate #
Date Collected
Latitude
Longitude
Location Description
PCB Aroclors
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Total PCB Aroclors
PCB Congeners
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,51-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4l,5,5l,6-Nonachlorobiphenyl)
Total of 19 PCB Congeners
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Method
NAD83
NAD83
8082
8082
8082
8082
8082
8082
8082
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
Units
dd.mmmm
dd.mmmm
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR02-C2-B
Rep#1
8/20/02
41.9001
-83.3551
Just downstream of turning
basin (duplicate)
< 0.033
< 0.033
< 0.033
< 0.033
0.870
< 0.033
< 0.033
0.870
< 0.0035
< 0.0010
0.0054
< 0.0010
0.0260
0.0380
0.0160
< 0.0010
0.0067
0.0098
0.0031 J
< 0.0010
0.0012 J
0.0041
< 0.0010
< 0.0010
< 0.0010
0.0011 J
< 0.0010
0.1060
RR02-C2-B
Rep #2
41.9001
-83.3551
Just downstream of turning
basin (duplicate)
< 0.033
< 0.033
< 0.033
< 0.033
0.790
< 0.033
< 0.033
0.790
< 0.0035
< 0.0010
0.0160
0.0290
0.0360
0.0500
0.0230
0.0043
0.0096
0.0140
0.0050
< 0.0010
0.0019 J
0.0060
0.0010 J
0.0011 J
< 0.0010
0.0021 J
< 0.0010
0.1929
Total Aroclors
Total Congeners
RR02-C2-B
Rep #3
41.9001
-83.3551
Just downstream of turning
basin (duplicate)
< 0.033
< 0.033
< 0.033
< 0.033
0.650
< 0.033
< 0.033
0.650
< 0.0035
< 0.0010
0.0300
0.0230
0.0290
0.0420
0.0190
0.0033 J
0.0079
0.0110
0.0046
< 0.0010
0.0016 J
0.0051
< 0.0010
< 0.0010
< 0.0010
0.0019 J
< 0.0010
0.1716
C2-B AVERAGE
0.770
0.158
RR02-C2-B
Rep #4
41.9001
-83.3551
Just downstream of turning
basin (duplicate)
< 0.033
< 0.033
< 0.033
< 0.033
0.770
< 0.033
< 0.033
0.770
< 0.0035
< 0.0010
0.0074
0.0240
0.0310
0.0440
0.0200
0.0036
0.0080
0.0120
0.0049
< 0.0010
0.0016 J
0.0051
< 0.0010
< 0.0010
< 0.0010
0.0019 J
< 0.0010
0.1600
RPD Values
0%
0%
Appendix B page 3 of 6
-------
Appendix B
FISH TISSUE
FISH TISSUE
Parameters
Replicate #
Date Collected
Latitude
Longitude
Location Description
PCB Aroclors
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Total PCB Aroclors
PCB Congeners
PCB 1 (2-Chlorobiphenyl)
PCB 5 ( 2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,51-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4l,5,5l,6-Nonachlorobiphenyl)
Total of 19 PCB Congeners
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Method
NAD83
NAD83
Units
dd.mmmm
dd.mmmm
RR02-C3
Rep#1
8/20/02
41.9086
-83.3768
Upstream of turning basin
approaching railroad bridge
RR02-C3
Rep #2
41.9086
-83.3768
Upstream of turning basin
approaching railroad bridge
RR02-C3
Rep #3
41.9086
-83.3768
Upstream of turning basin
approaching railroad bridge
RR02-C3
RR02-Control
Rep #4
8/20/02
41.9086 N/A
-83.3768 N/A
Upstream of turning basin Negative Control
approaching railroad bridge Sample for Lab
8082
8082
8082
8082
8082
8082
8082
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0017
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
< 0.0066
mg/kg
0.000
0.000
0.000
0.000
0.000
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
8082 modified
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.0035
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.0024 J
< 0.0010
< 0.0010
0.0021 J
< 0.0010
< 0.0010
0.0025 J
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.0000
< 0.0042
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
0.0024 J
< 0.0012
< 0.0012
< 0.0012
0.0012 J
< 0.0012
0.0000
< 0.0042
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
0.0027 J
< 0.0012
< 0.0012
0.0026 J
< 0.0012
< 0.0012
< 0.0012
0.0013 J
< 0.0012
0.0000
Total Aroclors
Total Congeners
< 0.0042
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
< 0.0012
0.0027 J
< 0.0012
< 0.0012
0.0025 J
< 0.0012
< 0.0012
< 0.0012
0.0012 J
< 0.0012
0.0000
C3 AVERAGE
0.000
0.000
< 0.0035
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.0021 J
< 0.0010
< 0.0010
0.0017 J
< 0.0010
< 0.0010
0.0015 J
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.0000
Appendix B page 4 of 6
-------
U.S. Army Corps of Engineers
Raisin River Sediment Analytical Results
DACW35-01-D-0007, D.O. 3
Appendix B
SEDIMENTS
Parameters
TOC
% Moisture (Trace)
% Moisture (Lancaster)
Metals
Total Arsenic
Total Barium
Total Cadmium
Total Chromium
Total Copper
Total Iron
Total Lead
Total Manganese
Total Mercury
Total Nickel
Total Selenium
Total Silver
Total Zinc
PCB Aroclors (Dry Weight)
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
PCB Congeners (Dry Weight)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
Sample ID
Date Collected
Time Collected
Method
Walkley-Black
D2974
EPA 160.3 modified
6020
6010
6010
6010
6010
6010
6010
6010
7471
6010
7740
6010
6010
8082
8082
8082
8082
8082
8082
8082
8082 modified
any I)
any I)
any I)
Dhenyl)
ilphenyl)
ilphenyl)
ubiphenyl)
ibiphenyl)
ibiphenyl)
ubiphenyl)
orobiphenyl)
orobiphenyl)
orobiphenyl)
orobiphenyl)
achlorobiphenyl)
Units
mg/kg
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RR-02-C1
7/22/02
1900
n/r
n/r
39.4
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
< 0.0054
< 0.0054
< 0.0054
< 0.0054
0.23
< 0.0054
0.029
0.0061
< 0.00033
0.0096
0.013
0.0083
0.013
0.010
0.0019
0.0028
0.0046
0.0016
0.00037 J
< 0.00033
0.0017
0.00093 J
0.0011 J
< 0.00033
0.00071 J
< 0.00033
RR-02-C2A RR-02-C2B RR-02-C3
7/22/02
1815
20,000
40.9
37.2
4.8
63
0.42
19
22
13,000
23
280
0.15
16
< 0.20 *
<0.50
82
< 0.026
< 0.026
< 0.026
< 0.026
1.8
< 0.026
0.48
0.019 J
< 0.0016
0.081
0.097
0.061
0.088
0.076
0.018
0.033
0.045
0.015
0.0033 J
0.0059
0.015
0.0078
0.013
0.0030 J
0.0068
< 0.0016
7/22/02
1820
29,000
47.1
39.8
5.9
81
0.66
43
42
13,000
55*
300
0.79
25
<0.20
<0.50
150
<0.55
<0.55
<0.55
<0.55
7.6
<0.55
<0.55
<0.12
< 0.033
0.29
0.48
0.31
0.45
0.16
0.037 J
0.061 J
0.11 J
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
< 0.033
7/22/02
1645
22,000
42.5
41.0
4.2
60
0.39
15
15
13,000
17
330
<0.10
14
<0.20
<0.50
73
< 0.0056
< 0.0056
< 0.0056
< 0.0056
0.029
< 0.0056
0.024 J
< 0.0012
< 0.00034
0.00058 J
0.00051 J
0.00070 J
0.0010 J
0.0013
0.00083 J
< 0.00034
0.00089 J
0.00085 J
< 0.00034
< 0.00034
0.0010 J
0.00044 J
< 0.00034
< 0.00034
< 0.00034
< 0.00034
* Results do not meet QC acceptance criteria,
see narrative.
n/r - not run due to the amount of zebra mussels vs. sediment
Note: RR-02-C1 analysis results are of zebra mussels, not sediment.
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Appendix B page 5 of 6
-------
Appendix B
WATER
WATER
Sample ID
Date Collected
Time Collected
Parameters Method
TOC 415.1
Metals
Total Arsenic 6020
Total Barium 6020
Total Cadmium 6020
Total Chromium 6020
Total Copper 6020
Total Iron 6010
Total Lead 7421
Total Manganese 6020
Total Mercury 7470
Total Nickel 6010
Total Selenium 6020
Total Silver 7761
Total Zinc 6020
PCB Aroclors
Aroclor-1016 8082
Aroclor-1221 8082
Aroclor-1232 8082
Aroclor-1242 8082
Aroclor-1248 8082
Aroclor-1254 8082
Aroclor-1260 8082
PCB Congeners 8082 modified
PCB 1 (2-Chlorobiphenyl)
PCB 5 ( 2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3', 4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
Units
mg/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
RR-02-C1
7/22/02
1900
3.5
<20
< 100
<0.50
<5.0
<25
250
6.6
<20
<0.20
<25
<5.0
<0.50
< 10
< 0.097
< 0.097
< 0.097
< 0.097
< 0.097
< 0.097
< 0.097
< 0.019
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
RR-02-C2A
7/22/02
1800
4.4
<20
< 100
<0.50
<5.0
<25
950
<3.0
40
<0.20
<25
<5.0
<0.50
< 10
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
0.250 J
< 0.019
< 0.0048
< 0.0048
< 0.0048
< 0.0048
0.0065 J
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
RR-02-C2B
7/22/02
1805
4.2
<20
< 100
0.63
<5.0
<25
650
<3.0
32
<0.20
<25
<5.0
<0.50
44
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.019
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
RR-02-C3
7/22/02
1650
5.7
<20
< 100
<0.50
<5.0
<25
320
<3.0
32
<0.20
<25
<5.0
< 0.50 *
< 10
< 0.096
< 0.096
< 0.096
< 0.096
< 0.096
< 0.096
< 0.096
< 0.019
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0047
< 0.0048
< 0.0048
< 0.0048
< 0.0048
RR-02-C1 RR-02-C2ARR-02-C2B RR-02-C3
8/20/02 8/20/02 8/20/02 8/20/02
1135 1200 1200 1300
4.1
<20
< 100
<0.50
<5.0
<25
310
<3.0
30
<0.20
<25
<5.0
<0.50
< 10
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.019
< 0.0048
< 0.0048
< 0.0048
< 0.0048
0.0077 J
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0049
< 0.0049
< 0.0049
< 0.0049
4.7
<20
< 100
<0.50
<5.0
<25
1,100
<3.0
53
<0.20
<25
<5.0
<0.50
< 10
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
n/r
4.9
<20
< 100
<0.50
<5.0
<25
440
<3.0
50
<0.20
<25
<5.0
<0.50
< 10
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.019
< 0.0048
< 0.0048
0.0093 J
0.0071 J
0.013 J
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
5.5
<20
< 100
<0.50
<5.0
<25
190
<3.0
35
<0.20
<25
<5.0
<0.50
< 10
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.095
< 0.019
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0048
< 0.0049
< 0.0049
< 0.0049
< 0.0049
* Results do not meet QC acceptance criteria,
see narrative.
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Appendix B page 6 of 6
-------
Appendix C
LUMBRICULUS VARIEGATUS BIOACCUMULATION RESULTS
WHOLE SEDIMENT BIOACCUMULATION
Sample ID
Date Collected
Time Collected
Parameters Units
PCB Congeners (Method 8082 modified)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
RR01-01PA RR01-01PB RR01-01PC RR01-01PD RR01-01P E RR01-02PA RR01-02P B RR01-02PC RR01-02P D RR01-02P E
12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01
1600 1600 1600 1600 1600 1600 1600 1600 1600 1600
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
n limit,
< 0.0053
< 0.0015
< 0.0015
0.0061
0.0087
0.016
0.0048 J
< 0.0015
0.0058
0.0067
0.0052 J
< 0.0015
0.0030 J
0.0058
0.0025 J
0.0033 J
< 0.0015
0.0052 J
< 0.0015
0.0491
< 0.0053
< 0.0015
< 0.0015
0.0059
0.0081
0.014
0.0042 J
0.0025 J
0.0052 J
0.0062
0.0030 J
< 0.0015
0.0034 J
0.0035 J
0.001 7 J
< 0.0015
< 0.0015
0.0044 J
< 0.0015
0.0342
< 0.0053
< 0.0015
< 0.0015
0.0060
0.0085
0.015
0.0045 J
0.0021 J
0.0053
0.0065
0.0028 J
< 0.0015
0.0020 J
0.0032 J
0.0019 J
< 0.0015
< 0.0015
0.0039 J
< 0.0015
0.0413
< 0.0053
< 0.0015
< 0.0015
0.0053
0.0074
0.013
0.0038 J
0.0022 J
0.0044 J
0.0057
0.0028 J
< 0.0015
0.0024 J
0.0029 J
< 0.0015
< 0.0015
< 0.0015
0.0031 J
< 0.0015
0.0314
Average =
< 0.0053
< 0.0015
< 0.0015
0.0057
0.0080
0.014
0.0040 J
0.0024 J
0.0054
0.0063
0.0035 J
< 0.0015
0.0039 J
0.0042 J
0.0022 J
0.0022 J
< 0.0015
0.0045 J
< 0.0015
0.0394
0.03908
< 0.0053
< 0.0015
< 0.0015
0.0031 J
0.0061
0.010
0.0028 J
0.0019 J
0.0045 J
0.0053
0.0022 J
< 0.0015
< 0.0015
0.0028 J
< 0.0015
< 0.0015
< 0.0015
0.0027 J
< 0.0015
0.0214
< 0.0053
< 0.0015
< 0.0015
0.0031 J
0.0061
0.0098
0.0029 J
0.0020 J
0.0041 J
0.0051 J
0.0028 J
< 0.0015
0.0018 J
0.0030 J
0.001 7 J
< 0.0015
< 0.0015
0.0022 J
< 0.0015
0.0159
< 0.0053
< 0.0015
< 0.0015
0.0039 J
0.0076
0.013
0.0039 J
0.0024 J
0.0051 J
0.0066
0.0027 J
< 0.0015
0.0018 J
0.0032 J
< 0.0015
< 0.0015
< 0.0015
0.0031 J
< 0.0015
0.0272
< 0.0053
< 0.0015
< 0.0015
0.0033 J
0.0073
0.012
0.0039 J
0.0023 J
0.0058
0.0065
0.0037 J
< 0.0015
0.0024 J
0.0047 J
0.0026 J
< 0.0015
< 0.0015
0.0044 J
< 0.0015
0.0316
Average =
< 0.0053
< 0.0015
< 0.0015
0.0040 J
0.0083
0.013
0.0044 J
0.0023 J
0.0059
0.0072
0.0034 J
< 0.0015
0.0023 J
0.0038 J
0.0020 J
< 0.0015
< 0.0015
0.0042 J
< 0.0015
0.0344
0.0261
Appendix C page 1 of 5
-------
Appendix C
LUMBRICULUS VARIEGATUS BIOACCUMULATION RESULTS
WHOLE SEDIMENT BIOACCUMULATION
Sample ID
Date Collected
Time Collected
Parameters Units
PCB Congeners (Method 8082 modified)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
RR01-04PA RR01-04PB RR01-04PC RR01-04P D RR01-04P E RR01-08PA RR01-08P B RR01-08PC RR01-08P D RR01-08P E
12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01 12/19/01
1600 1600 1600 1600 1600 1600 1600 1600 1600 1600
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
n limit,
< 0.026
< 0.0075
< 0.0075
0.074
0.11
0.20
0.055
0.015 J
0.059
0.071
0.029
< 0.0075
0.019 J
0.029
0.0088 J
< 0.0075
< 0.0075
0.037
< 0.0075
0.664
< 0.026
< 0.0075
< 0.0075
0.068
0.096
0.18
0.048
0.014 J
0.055
0.069
0.024 J
< 0.0075
0.018 J
0.025 J
< 0.0075
< 0.0075
< 0.0075
0.033
< 0.0075
0.549
< 0.026
< 0.0075
< 0.0075
0.090
0.12
0.22
0.062
0.017 J
0.067
0.088
0.029
< 0.0075
0.023 J
0.035
0.0095 J
< 0.0075
< 0.0075
0.043
< 0.0075
0.754
< 0.026
< 0.0075
< 0.0075
0.078
0.10
0.20
0.052
0.016 J
0.059
0.075
0.026
< 0.0075
0.019 J
0.028
0.0087 J
< 0.0075
< 0.0075
0.037
< 0.0075
0.655
Average =
< 0.026
< 0.0075
< 0.0075
0.065
0.090
0.17
0.047
0.012 J
0.050
0.063
0.022 J
< 0.0075
0.018 J
0.023 J
0.0081 J
< 0.0075
< 0.0075
0.032
< 0.0075
0.517
0.6278
< 0.053
< 0.015
< 0.015
0.41
0.55
0.72
0.46
0.099
0.23
0.28
0.057
< 0.015
0.043 J
0.066
0.019 J
< 0.015
< 0.015
0.048 J
< 0.015
2.872
< 0.053
< 0.015
< 0.015
0.45
0.60
0.78
0.49
0.11
0.25
0.30
0.066
< 0.015
0.050 J
0.085
0.019 J
< 0.015
< 0.015
0.059
< 0.015
3.19
< 0.053
< 0.015
< 0.015
0.47
0.64
0.82
0.54
0.12
0.26
0.33
0.068
< 0.015
0.052 J
0.079
0.022 J
< 0.015
< 0.015
0.058
< 0.015
3.385
< 0.053
< 0.015
< 0.015
0.40
0.58
0.75
0.47
0.11
0.24
0.30
0.061
< 0.015
0.050 J
0.071
0.017 J
< 0.015
< 0.015
0.055
< 0.015
3.037
Average =
< 0.053
< 0.015
< 0.015
0.40
0.55
0.70
0.45
0.10
0.23
0.28
0.056
< 0.015
0.043 J
0.066
0.019 J
< 0.015
< 0.015
0.047 J
< 0.015
2.832
3.0632
Appendix C page 2 of 5
-------
Appendix C
LUMBRICULUS VARIEGATUS BIOACCUMULATION RESULTS
WHOLE SEDIMENT BIOACCUMULATION
Sample ID
Date Collected
Time Collected
Parameters Units
PCB Congeners (Method 8082 modified)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
RR01-12PA RR01-12PB RR01-12PC RR01-12P D RR01-12P E RR01-17PA RR01-17P B RR01-17PC RR01-17PD RR01-17P E
12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01
1600 1600 1600 1600 1600 1600 1600 1600 1600 1600
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
n limit,
<0.11
< 0.030
< 0.030
0.29
0.38
0.60
0.37
0.085 J
0.22
0.23
0.054 J
< 0.030
0.054 J
0.068 J
< 0.030
< 0.030
< 0.030
0.064 J
< 0.030
2.09
<0.11
< 0.030
< 0.030
0.31
0.41
0.64
0.39
0.091 J
0.23
0.24
0.057 J
< 0.030
0.056 J
0.069 J
< 0.030
< 0.030
< 0.030
0.068 J
< 0.030
2.22
<0.11
< 0.030
< 0.030
0.24
0.33
0.52
0.31
0.079 J
0.19
0.19
0.045 J
< 0.030
0.049 J
0.056 J
< 0.030
< 0.030
< 0.030
0.055 J
< 0.030
1.78
<0.11
< 0.030
< 0.030
0.34
0.45
0.70
0.43
0.12
0.25
0.26
0.065 J
< 0.030
0.079 J
0.077 J
< 0.030
< 0.030
< 0.030
0.074 J
< 0.030
2.55
Average =
<0.11
< 0.030
< 0.030
0.29
0.39
0.62
0.38
0.076 J
0.22
0.22
0.053 J
< 0.030
0.034 J
0.064 J
< 0.030
< 0.030
< 0.030
0.051 J
< 0.030
2.12
2.152
< 0.026
< 0.0075
< 0.0075
< 0.0075
0.087
0.23
0.064
0.020 J
0.039
0.06
0.024 J
< 0.0075
0.016 J
0.025 J
0.017 J
< 0.0075
< 0.0075
0.039
< 0.0075
0.515
< 0.026
< 0.0075
< 0.0075
0.21
0.099
0.26
0.075
0.020 J
0.059
0.069
0.026
< 0.0075
0.019 J
0.035
0.012 J
< 0.0075
< 0.0075
0.045
< 0.0075
0.878
< 0.026
< 0.0075
< 0.0075
0.13
0.11
0.30
0.080
0.026 J
0.083
0.088
0.040
< 0.0075
0.028
0.036
0.011 J
< 0.0075
< 0.0075
0.055
< 0.0075
0.95
< 0.026
< 0.0075
< 0.0075
0.12
0.11
0.29
0.077
0.020 J
0.080
0.079
0.029
< 0.0075
0.020 J
0.033
0.010 J
< 0.0075
< 0.0075
0.050
< 0.0075
0.868
Average =
< 0.026
< 0.0075
< 0.0075
0.19
0.12
0.31
0.089
0.023 J
0.080
0.085
0.032
< 0.0075
0.025 J
0.042
0.013 J
< 0.0075
< 0.0075
0.056
< 0.0075
1.004
0.843
Appendix C page 3 of 5
-------
Appendix C
LUMBRICULUS VARIEGATUS BIOACCUMULATION RESULTS
WHOLE SEDIMENT BIOACCUMULATION
Sample ID
Date Collected
Time Collected
Parameters Units
PCB Congeners (Method 8082 modified)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Field Rep Field Rep Field Rep Field Rep Field Rep
ofRR01-17P ofRR01-17P ofRR01-17P ofRR01-17P ofRR01-17P
RR01-18PA RR01-18PB RR01-18PC RR01-18P D RR01-18P E RR01-21PA RR01-21P B RR01-21PC RR01-21PD RR01-21P E
12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 12/27/01
1600 1600 1600 1600 1600 1600 1600 1600 1600 1600
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
n limit,
< 0.026
< 0.0075
< 0.0075
< 0.0075
0.076
0.12
0.061
0.017 J
0.039
0.057
0.018 J
< 0.0075
0.013 J
0.023 J
< 0.0075
< 0.0075
< 0.0075
0.028
< 0.0075
0.381
< 0.026
< 0.0075
< 0.0075
0.095
0.073
0.11
0.056
0.015 J
0.040
0.055
0.017 J
< 0.0075
0.013 J
0.022 J
< 0.0075
< 0.0075
< 0.0075
0.027
< 0.0075
0.456
< 0.026
< 0.0075
< 0.0075
0.067
0.070
0.11
0.054
0.014 J
0.043
0.055
0.017 J
< 0.0075
0.013 J
0.018 J
< 0.0075
< 0.0075
< 0.0075
0.026 J
< 0.0075
0.399
< 0.026
< 0.0075
< 0.0075
0.060
0.061
0.11
0.052
0.017 J
0.041
0.055
0.017 J
< 0.0075
0.017 J
0.019 J
< 0.0075
< 0.0075
< 0.0075
0.026 J
< 0.0075
0.379
Average =
< 0.026
< 0.0075
< 0.0075
0.054
0.059
0.095
0.046
0.012 J
0.037
0.047
0.014 J
< 0.0075
0.011 J
0.015 J
< 0.0075
< 0.0075
< 0.0075
0.023 J
< 0.0075
0.338
0.3906
< 0.026
< 0.0075
< 0.0075
0.11
0.096
0.27
0.076
0.021 J
0.077
0.081
0.028
< 0.0075
0.020 J
0.033
0.010 J
< 0.0075
< 0.0075
0.047
< 0.0075
0.818
< 0.026
< 0.0075
< 0.0075
0.11
0.089
0.25
0.072
0.019 J
0.071
0.074
0.026
< 0.0075
0.017 J
0.031
0.0098 J
< 0.0075
< 0.0075
0.042
< 0.0075
0.765
< 0.026
< 0.0075
< 0.0075
0.11
0.074
0.22
0.067
0.022 J
0.060
0.064
0.028
< 0.0075
0.016 J
0.025 J
0.0077 J
< 0.0075
< 0.0075
0.038
< 0.0075
0.661
< 0.026
< 0.0075
< 0.0075
0.13
0.12
0.29
0.085
0.023 J
0.082
0.086
0.031
< 0.0075
0.022 J
0.040
0.014 J
< 0.0075
< 0.0075
0.052
< 0.0075
0.916
Average =
RPD%
< 0.026
< 0.0075
< 0.0075
0.12
0.10
0.29
0.083
0.023 J
0.086
0.089
< 0.0075
< 0.0075
0.022 J
0.037
0.010 J
< 0.0075
< 0.0075
0.053
< 0.0075
0.858
0.8036
-4.8%
Appendix C page 4 of 5
-------
Appendix C
LUMBRICULUS VARIEGATUS BIOACCUMULATION RESULTS
WHOLE SEDIMENT BIOACCUMULATION
Sample ID
Date Collected
Time Collected
Parameters Units
PCB Congeners (Method 8082 modified)
PCB 1 (2-Chlorobiphenyl)
PCB 5 (2,3-Dichlorobiphenyl)
PCB 18 (2,2',5-Trichlorobiphenyl)
PCB 31 (2,4'5-Trichlorobiphenyl)
PCB 44 (2,2',3,5'-Tetrachlorobiphenyl)
PCB 52 (2,2',5,5'-Tetrachlorobiphenyl)
PCB 66 (2,3',4,4'-Tetrachlorobiphenyl)
PCB 87 (2,2',3,4,5'-Pentachlorobiphenyl)
PCB 101 (2,2',4,5,5'-Pentachlorobiphenyl)
PCB 110 (2,3,3',4',6-Pentachlorobiphenyl)
PCB 138 (2,2',3,4,4',5'-Hexachlorobiphenyl)
PCB 141 (2,2',3,4,5,5'-Hexachlorobiphenyl)
PCB 151 (2,2',3,5,5',6-Hexachlorobiphenyl)
PCB 153 (2,2',4,4',5,5'-Hexachlorobiphenyl)
PCB 170 (2,2',3,3',4,4',5-Heptachlorobiphenyl)
PCB 180 (2,2',3,4,4',5,5'-Heptachlorobiphenyl)
PCB 183 (2,2',3,4,4',5',6-Heptachlorobiphenyl)
PCB 187 (2,2',3,4',5,5',6-Heptachlorobiphenyl)
PCB 206 (2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl)
J - Estimated value. Result is above method detection limit,
but below limit of quantitation
Field Rep Field Rep Field Rep Field Rep Field Rep Control Control Control
ofRR01-4P ofRR01-4P ofRR01-4P ofRR01-4P ofRR01-4P Sample Sample Sample
RR01-22PA RR01-22PB RR01-22PC RR01-22P D RR01-22P E RR01-23PC RR01-24PC RR01-25PC
12/27/01 12/27/01 12/27/01 12/27/01 12/27/01 1/2/02 1/2/02 1/2/02
1600 1600 1600 1600 1600 1400 1400 1400
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
< 0.026
< 0.0075
< 0.0075
0.067
0.087
0.17
0.045
0.012 J
0.044
0.061
0.021 J
< 0.0075
0.023 J
0.026 J
< 0.0075
< 0.0075
< 0.0075
0.040
< 0.0075
< 0.026
< 0.0075
< 0.0075
0.077
0.10
0.20
0.052
0.014 J
0.057
0.075
0.027
< 0.0075
0.031
0.028
0.011 J
< 0.0075
< 0.0075
0.046
< 0.0075
< 0.026
< 0.0075
< 0.0075
0.080
0.10
0.20
0.052
0.013 J
0.058
0.077
0.035
< 0.0075
0.026 J
0.035
0.0095 J
< 0.0075
< 0.0075
0.049
< 0.0075
< 0.026
< 0.0075
< 0.0075
0.078
0.10
0.20
0.051
0.014 J
0.056
0.074
0.026 J
< 0.0075
0.024 J
0.026
0.0079 J
< 0.0075
< 0.0075
0.044
< 0.0075
< 0.026
< 0.0075
< 0.0075
0.081
0.11
0.20
0.053
0.018 J
0.060
0.080
0.032
< 0.0075
0.031
0.028
0.012 J
< 0.0075
< 0.0075
0.046
< 0.0075
< 0.0053
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
0.0021 J
< 0.0015
< 0.0015
0.0029 J
< 0.0015
< 0.0015
< 0.0015
0.001 7 J
< 0.0015
< 0.0053
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
0.0016 J
< 0.0015
< 0.0015
0.0018 J
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0053
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
0.001 7 J
< 0.0015
< 0.0015
0.0023 J
< 0.0015
< 0.0015
< 0.0015
< 0.0015
< 0.0015
0.514
0.693
0.686
0.629
Average =
RPD%
0.721
0.6486
3.3%
Appendix C page 5 of 5
-------
Appendix D
WATER DEPTH, SEDIMENT DEPTH, AND SURFACE WATER ELEVATION
Sample ID
RR01-01
RR01-01P
RR01-02
RR01-02P
RR01-03
RR01-04
RR01-04P
RR01-05
RR01-06
RR01-06P
RR01-07
RR01-08
RR01-08P
RR01-09
RR01-10
RR01-11
RR01-12
RR01-12P
RR01-13
RR01-14
RR01-15
RR01-16
RR01-17
RR01-17P
RR01-18
RR01-18P
RR01-19
RR01-20
RR01-21
RR01-21P
RR01-22
RR01-22P
RR01-23
RR01-24
RR01-25
Date Collected
10/15/01
10/17/01
10/18/01
10/19/01
10/18/01
10/18/01
10/20/01
10/18/01
10/19/01
10/20/01
10/18/01
10/19/01
10/20/01
10/18/01
10/19/01
10/18/01
10/19/01
10/19/01
10/18/01
10/19/01
10/16/01
10/18/01
10/19/01
10/19/01
10/15/01
10/19/01
10/15/01
10/19/01
10/18/01
10/19/01
10/18/01
10/20/01
10/18/01
10/18/01
10/19/01
Time
Collected
1405
0937
1545
1729
1444
1408
0832
1034
0924
0916
1010
0953
0958
942
1034
0907
1359
1359
0826
1500
0820
1654
0827
1526
0955
1614
1100
Inaccessible
0926
1556
1058
0859
1449
1602
1010
Latitude
dd.ddddd
41 .89948
41 .89938
41.90127
41.90123
41.90117
41.90115
41.90113
41.90109
41 .90087
41 .90088
41 .90090
41 .90065
41 .90063
41 .90061
41 .90047
41 .90042
41.90017
41.90017
41 .90020
41 .89992
41 .90000
41 .89928
41 .89858
41 .89857
41 .89744
41 .89762
41 .89442
, site above
41 .90020
41 .89857
41.90109
41.90113
41.90117
41.90127
41 .90065
Longitude
dd.ddddd
-83.361 06
-83.361 06
-83.35805
-83.35812
-83.35587
-83.35453
-83.35457
-83.35429
-83.35417
-83.35417
-83.35397
-83.35393
-83.35385
-83.35366
-83.35358
-83.35337
-83.35323
-83.35323
-83.35297
-83.35293
-83.35281
-83.35203
-83.351 00
-83.351 07
-83.351 08
-83.34973
-83.34473
water line
-83.35297
-83.351 07
-83.35429
-83.35457
-83.35587
-83.35805
-83.35393
Water
Depth
(feet)
17.4
16.7
10.5
12.5
18.6
10.5
11.2
3.6
18.9
17.0
3.8
21.0
20.8
5.4
19.4
6.5
19.8
19.8
3.4
19.7
5.3
13.3
10.2
11.8
4.1
7.7
20.4
3.4
11.8
3.6
11.2
18.6
10.5
21.0
Sediment
Depth
(feet)
4.75
0.50
2.00
0.25
2.00
0.00
1.50
0.25
1.00
0.25
0.08
0.17
4.00
4.00
Water Surface
Elevation
(ft. above
mean sea level)
569.3
568.5
569.9
569.6
569.8
569.8
570.1
570.5
570.0
569.9
570.6
570.1
569.9
570.7
570.2
570.7
569.9
569.9
570.7
569.7
572.6
569.9
569.8
569.7
568.5
569.6
568.5
N/A
570.7
569.6
570.5
570.0
569.8
569.9
570.2
Removal Zone Corner #
1
2
3
4
Latitude
dd.ddddd
41.90127
41.90111
41.89997
41.89978
Longitude
dd.ddddd
-83.35456
-83.35479
-83.35265
-83.35291
-------
Appendix E
Ca I cu I ation of Sediment Vp I umes and Average
PCB Concentrations in the Sediment Removal Area (SRA)
Sediment depth and PCB concentration data were collected at each of the sediment core
locations within the Sediment Removal Area (SRA), locations RRO1-04 through RRO1-15.
Comparison of the coordinates for each of these sampling points to the coordinates of the corners
of the SRA as provided by the U.S. Army Corp of Engineers (Baxter, 2001), confirms that these
sampling locations are within the boundaries of the SRA. The measurement are used to calculate
estimates for: average sediment depth in the SRA, estimated volume of contaminated sediments
remaining in the SRA, average surficial PCB concentration in the SRA, and volume-weighted
average PCB concentration of sediments within the SRA.
In order to simplify the calculation performed in this Appendix this report make the assumption
that each sampling location equally represents the sediment depth and PCB concentrations of
one-twelfth of the SRA. Although not exactly accurate, this simplification will provide rough
estimates suitable for making screening level decisions.
E.I AVERAGE SEDIMENT DEPTH
The average sediment depth within the SRA is calculated using the arithmetic mean of the 12
sediment depth measurements shown in Table E-1. This method of calculating average sediment
depth makes the broad assumption that each of the 12 sediment depth measurements represents
the sediment depth of one-twelfth of the area of the SRA.
Table E-l: Sediment Depth Measurements for SRA Sampling Locations
, .. Sediment Depth
Location ., .. r
(feet)
RR01-04
RR01-05
RR01-06
RR01-07
RR01-08
RR01-09
RR01-10
RR01-11
RR01-12
RR01-13
RR01-14
RR01-15
4.8
0.5
2.0
0.3
2.0
0.0
1.5
0.3
1.0
0.3
0.1
0.2
Avg Sediment Detph in SRA = 1.1 feet
-------
E.2 ESTIMATED VOLUME OF CONTAMINATED SEDIMENTS IN SRA
The area of the SRA is calculated using the four SRA corner points as given by the UTM Zone
17 coordinates provided in Table E-2.
Table E-2: UTM Coordinates for Corner Points of SRA
Point #
1
2
3
4
Easting
(meters)
304,693
304,674
304,848
304,826
Northing
(meters)
4,641,495
4,641,477
4,641,346
4,641,326
These four corner points form an irregular quadrilateral. The area of the quadrilateral are
calculated by dividing the quadrilateral into two, separate triangle as defined by points 1-2-3, and
2-3-4. In turn, the area of these triangles are calculated as follows:
1. The area of a triangle is defined as 1A * B * H, where B = length of the triangle base, and
H = height of the triangle.
2. The length of the base of each triangle is calculated using the distance between the two
sets of base points 1-3 and 2-4, respectively.
Example Calculation:
Bl.2-3
= Dis tan ce(\3) = ^(304,848- 304,693 )' + (4642346 - 4641495^ =215meters
Similarly, 62.3.4 = Distance (2,4) = 214 meters
3 . Next the normal equations for lines between points 1-3 and 2-4 are calculated using the
standard geometric methods for calculating a line between two known points. The
equations for normal lines are calculated in the form
Ix + my + n = 0
where:
Appendix E page - 2 -
-------
Equation for Line 1-3: 0.693x + 0.721y - 3557315 = 0
Equation for Line 2-4: 0.705x + 0.709y - 3507559 = 0
4. The distance from the apex to the base of each of the two triangles is then calculated
using the equation for the distance between a point and a line, and is given as:
abs [ lx; + my; + n]
Example:
HI.2-3 = abs [0.693(304,674) + 0.721(4,641,477) - 3557315] = 26.1 meters
Similarly, H2-3-4 = 29.7 meters
5. The area of each triangle can then be calculated using the equation given in Step #1:
Areai-2-3 = 2,800 square meters
Area2-3-4 = 3,200 square meters
6. Total area of the SRA is then calculated by summing the areas of the triangles:
Total Area of SRA = 6,000 square meters = 65,000 square feet
E.3 AVERAGE SURFICAL PCB CONCENTRATION
Average surficial PCB concentrations in the SRA are calculated using the PCB concentration
data provided for the uppermost core interval (0" to 6") in Table E-3. At locations where ponar
samples were collected along with cores, the PCB concentration is assumed to be the average of
the Interval A and ponar concentrations. The average concentration is the arithmetic average of
the surficial PCB concentration at each of the 12 sampling locations. For location RR01-09,
where no sediment was present, the PCB concentration was assumed to be 0 mg/kg.
The average surficial PCB concentration in the SRA is approximately 35
mg/kg.
Appendix E page - 3 -
-------
Table E-3. Surficial PCB concentrations in SRA
Sample #
RR01-04A
RR01-04P
RR01-05A
RR01-06A
RR01-06P
RR01-07A
RR01-08A
RR01-08P
RR01-09
RR01-10A
RR01-11A
RR01-12A
RR01-12P
RR01-13A
RR01-14A
RR01-15A
Start Depth
(inches)
0
ponar
0
0
ponar
ponar
0
ponar
No Sample
0
ponar
0
ponar
ponar
ponar
ponar
End Depth
(inches)
6
ponar
4
6
ponar
ponar
6
ponar
No Sample
6
ponar
6
ponar
ponar
ponar
ponar
Total
PCB
Cone.
(mg/kg)
20.00
3.90
0.40
8.70
4.10
27.00
8.58
18.00
207.00
93.00
12.00
10.00
20.00
6.60
29.10
Average
PCB
r VI*D
Cone.
of Ponar
anrl
Cll 1 U
Slice A
(mg/kg)
11.95
0.40
6.40
27.00
13.29
0.00
207.00
93.00
11.00
20.00
6.60
29.10
Average = 35 mg/kg
E.4 VOLUME-WEIGHTED PCB CONCENTRATION OF SRA SEDIMENTS
A volume weighted average PCB concentration for SRA sediment is calculated using the data
provided in Table E-4. If a sediment core and a ponar were collected at the same location only
the sediment core data is used. Volume weighted concentrations are calculated by multiplying
the PCB concentration (mg/kg) of each sample by the length (inches) of core interval it
represented. If only a ponar was collected at a given location, sediment depth is assumed to be
equal to the sediment depth measurement provided in Table E-1.
Volume-weighted average concentration is calculated by summing the "interval length *
concentration" values and dividing by the sum of the interval lengths.
Volume-weighted average PCB concentration in the SRA is
approximately 58 mg/kg.
Appendix E page - 4 -
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Table E-4. Interval Lengths and PCB Concentrations for SRA Samples
Sample #
RR01-04A
RR01-04B
RR01-04C
RR01-05A
RR01-06A
RR01-06B
RR01-07A
RR01-08A
RR01-08B
RR01-08C
RR01-09
RR01-10A
RR01-10B
RR01-11A
RR01-12A
RR01-12B
RR01-13A
RR01-14A
RR01-15A
Start Depth
(inches)
0
6
18
0
0
6
ponar
0
6
18
No Sample
0
6
ponar
0
6
ponar
ponar
ponar
End Depth
(inches)
6
18
46
4
6
17
ponar
6
18
30
No Sample
6
16
ponar
6
11
ponar
ponar
ponar
Total
PCB
Cone.
(mg/kg)
20.0
1.4
0.3
0.4
8.7
0.7
27.0
8.6
46.0
300.0
0.0
207.0
160.0
93.0
12.0
14.5
20.0
6.6
29.1
Interval
Length
(feet)
0.5
1.0
2.3
0.3
0.5
0.9
0.3
0.5
1.0
1.0
0.0
0.5
0.8
0.3
0.5
0.4
0.3
0.1
0.2
Sum
11.5
Length *
Cone
10.0
1.4
0.8
0.1
4.4
0.6
8.1
4.3
46.0
300.0
0.0
103.5
133.3
27.9
6.0
6.0
6.0
0.7
5.8
Sum
664.9
AVERAGE = 58 mg/kg
Appendix E page - 5 -
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