START2 S
Superfund Technical Assessment and nespoiisc i emu.
Reion VIII
United States
Environmental Protection Agency
Contract No. 68-W-00-U8
SAMPLING AND ANALYSIS REPORT
SUPERIOR WASTE ROCK
Superior, Mineral County, Montana
TDD No. 0203-0008
AUGUST 16.2002
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C/ OPERATING SERVICES, INC.
In association with: Tetra Tech EM, Inc.
URS Corporation
LT Environmental, Inc.
TN & Associates, Inc.
TechLaw, Inc.
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URS OPERATING SERVICES
1099 18TH STREET
SUITE 710
DENVER, COLORADO 80202-1908
TEL: (303) 296-3523
FAX: (303)291-8296
August 16, 2002
Mr. Tien Nguyen
On-Scene Coordinator
U.S. Environmental Protection Agency, Region YE
999 18th Street, Suite 500, Mail Code: 8EPR-ER
Denver, Colorado 80202
SUBJECT: START, EPA Region VIII, Contract No. 68-W-OO-l 18, TDD No. 0203-0008
Sampling and Analysis Report - Superior Waste Rock, Superior, Mineral County,
Montana
Dear Tien:
Enclosed are two copies of the final Sampling Analysis Report for the Superior Waste Rock site, Superior,
Mineral County, Montana. Sampling activities were completed June 3 through June 13, 2002. This
document is submitted for your review and approval.
If you have any questions, please call me at 303-291-8229.
Very truly yours,
URS OPERATING SERVICES, INC.
Rebecca Laramie
Environmental Engineer
attachments
cc: T. F. Staible/UOS without attachments
File/UOS
TDD No. 0203-0008
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I
URS Operating Services, Inc.
START2, EPA Region vm
Contract No. 68-W-00-118
SAMPLING AND ANALYSIS REPORT
SUPERIOR WASTE ROCK
Superior, Mineral County, Montana
Superior Waste Rock - SAR
Signature Page
Revision: 0
Date: 08/2002
Page i of iv
EPA Contract No. 68-W-00-118
TDD No. 0203-0008
Prepared By:
Rebecca Laramie
Environmental Engineer
URS Operating Services, Inc.
1099 18th Street, Suite 710
Denver, CO 80202-1908
Approved:
Tien Nguyen, On-Scene^/ooi^finator, EPA, Region VDI
Date:
Approved:
T. F. Staible-iSTART2 Program Manager, UOS
Date:
Approved:
Rebecca Laramie, Environmental Engineer, UOS
Date:
.Zee*.
This document has been prepared for the U.S. Environmental Protection Agency under Contract
No. 68-W-OO-l 18. The material contained herein is not to be disclosed to, discussed with, or made available
to any person or persons for any reason without prior express approval of a responsible officer of the U.S.
Environmental Protection Agency. In the interest of conserving natural resources, this document is printed
on recycled paper and double-sided as appropriate.
TDD No. 0203-0008
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URS Operating Services. Inc. Superior Waste Rock - SAR
START2, EPA Region Vffl Distribution List
Contract No. 68-W-OO-l 18 Revision: 0
Date: 08/2002
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DISTRIBUTION LIST
U.S. ENVIRONMENTAL PROTECTION AGENCY
Tien Nguyen (2 copies) OSC, EPA Region Vffl
URS OPERATING SERVICES, INC.
Rebecca Laramie Environmental Engineer, Region Vffl START2
File (2 copies) START2, EPA Region Vffl
TDD No. 0203-0008
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URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-00-118
Superior Waste Rock - SAR
Table of Contents
Revision: 0
Date: 08/2002
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SAMPLING AND ANALYSIS REPORT
Superior Waste Rock
Superior, Mineral County, Montana
TABLE OF CONTENTS
SIGNATURE PAGE
DISTRIBUTION LIST
TABLE OF CONTENTS
1.0 INTRODUCTION
2.0 OBJECTIVES
3.0 SITE HISTORY AND PREVIOUS WORK
4.0 SITE ACTIVITIES AND OBSERVATIONS
4.1 Sampling Activities
4.1.1 Residential Property Samples
4.1.2 Road Right of Way Samples
4.1.3 Open Space Samples
4.2 Sample Location Identification
4.2.1 Residential Samples
4.2.2 Open Space Samples
4.2.3 Right of Way Samples
4.3 Derivations from Field Sampling Plan
4.4 Analytical Parameters
4.4.1 XRF Sample Preparation
5.0 QUALITY ASSURANCE AND QUALITY CONTROL
5.1 Laboratory Quality Control
5.2 Field Quality Control
5.2.1 XRF Analysis
5.2.2 Field Quality Control Samples
6.0 ANALYTICAL DATA EVALUATION
7.0 SAMPLE RESULTS
8.0 SUMMARY
9.0 LIST OF REFERENCES
PAGE#
i
ii
iii
1
2
2
4
12
13
14
16
18
TDD No. 0203-0008
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URS Operating Services, Inc.
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Contract No. 68-W-00-118
FIGURES
Figure 1
TABLE OF CONTENTS (continued)
Superior Waste Rock - SAR
Table of Contents
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Date: 08/2002
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Sample Distribution and Elevated Concentration Values at Superior
TABLES
Table 1 Lead and Arsenic XRF Results
Table 2 Laboratory and XRF Results
Table 3 Estimated Volume of Elevated Metals Material
Table 4 TCLP Results
APPENDICES
Appendix A Photolog
Appendix B Validation Reports and Laboratory Data
Appendix C XRF Results
Appendix D Street Codes for Sample Identification
TDD No. 0203-0008
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1.0 INTRODUCTION
URS Operating Services, Inc. (UOS) has been tasked by the U.S. Environmental Protection Agency (EPA),
Region VIJJ, under Technical Direction Document (TDD) #0203-0008, to conduct environmental sampling
at Superior, Montana, as part of a Removal Assessment. The sampling was completed between June 3 and
June 13,2002. This report describes the field activities completed and the analytical results associated with
the field activities.
Soil samples were collected from 64 residential properties, 20 right-of-ways, and 10 city/county and open
space properties within and around Superior, Montana. A total of ten residential properties originally
identified for sampling were not completed because of the distance from the town of Superior, later denial
of access, or change in ownership. In addition, samples were not collected from 2 right of ways originally
identified for sampling because concrete or asphalt covered the entire right of way. Access consents were
obtained by the EPA and the Mineral County Environmental and Planning Department prior to sampling.
The Superfund Technical Assessment and Response Team 2 (START2) used a Global Positioning System
(GPS) to document sample locations and properties sampled. This information was used to produce Figure
1.
A total of 635 soil samples were collected in Superior, Montana, including 24 replicate samples and 4 rinsate
blank samples. Soil samples were analyzed on site with an X-Ray Fluorescence Spectrometer (XRF) for
metals. In addition, 26 duplicate samples were also prepared and analyzed using the XRF to determine the
quality of sample preparation. Ten percent of the total number of soil samples collected for XRF analysis
(64 samples) were sent to a commercial laboratory for Target Analyte List (TAL) metals analysis as
confirmation of field XRF results. Four soil samples were also selected and sent to a commercial laboratory
for Toxicity Characteristic Leaching Procedure (TCLP) analysis of TAL metals. Five samples were
submitted for lead and arsenic speciation and in vitro bioavailability. Confirmation sample results and TCLP
sample results were validated in accordance with the criteria contained in EPA guidance documents modified
for the analytical method used (U.S. Environmental Protection Agency (EPA) 1994a). Data validation
reports are filed with the data and describe the usability of the data for further technical interpretation.
TDD No. 0203-0008
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2.0 OBJECTIVES
The goal of the assessment is to ensure that the data generated during this project are adequate to support
removal decisions based on the human health effects associated with the possible exposure of metals to
humans in Superior, Montana. A risk assessment will be conducted to determine an acceptable level of risk
to humans and to establish an action level if a removal action is determined to be necessary.
3.0 SITE HISTORY AND PREVIOUS WORK
The Superior Waste Rock site includes areas that may be affected by tailings and waste rock from The Iron
Mountain Mine and Mill. The Iron Mountain Mine and Mill is located approximately 3.5 miles north of
Superior. The Iron Mountain Mine and Mill operated from 1909 to 1930 and again from 1947 to 1953
(Montana Department of Environmental Quality (Montana DEQ) 2001). A bulletin of unknown date cites
E. C. Earl of New York as the owner (Montana Bureau of Mines and Geology (MBMG) date unknown).
Federal Mining and Smelting Company acquired the property in 1915. The mine and mill were operated by
lessees from 1925 to 1928 when they were abandoned because of the poor market for zinc. The present
owner is ASARCO of Wallace, Idaho, that acquired the property around 1916. The mine has been abandoned
since 1954 and foundations are all that remain of the mill and other mining buildings. The mill site covers
less than one acre of property. When operating, the mill site consisted of a 200-ton mill and approximately
500 feet of tunnels (Montana Department of State Lands - Abandoned Mine Reclamation Bureau (MDSL-
AMRB) 1993). Tunnels were developed at the 200-, 400-, 700-, and 1,600-foot levels, with the main haulage
level at 1,600 feet. The mill operation processed silver, gold, lead, copper, and zinc ores (Montana DEQ
2001). The mill also accepted ore from the Dillon Mill and the Belle of the Hills Mine, which were located
upgradient of the Iron Mountain Mill site (Figure 1). It is believed that the Iron Mountain Mill used flotation
methods to separate the metals. Although the waste rock pile still exists on site, the majority of the tailings
were washed down onto the Flat Creek floodplain (MDSL-AMRB 1993). Previous UOS sampling activities
indicate that a portion of the tailings from the Iron Mountain Mill was used as fill in the town of Superior
(URS Operating Services, Inc. (UOS) 2002a).
During 1993, the Montana Department of State Lands, Abandoned Mine Reclamation Bureau (MDSL-
AMRB) conducted an abandoned mine investigation to determine the potential health and environmental
risks associated with the Iron Mountain Mine and Mill site. The Abandoned Hardrock Mine Priority Sites
Summary Report documents concentrations of arsenic, copper, mercury, lead, zinc, cadmium, manganese,
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and antimony at the mill site at more than three times the background sample concentrations(MDSL-AMRB
1993).
In 1998, reclamation activities were conducted by ASARCO, the current owner of the mill site. These
activities consisted of removing some tailings from Flat Creek and placing them on the ASARCO property
(Iron Mountain Mine) in an impoundment. The impoundment was covered with topsoil and vegetated
(ASARCO 1999). Additional tailings along Flat Creek were revegetated in place (UOS 200Ib). No
sampling data were available for Flat Creek following the removal activities. Sample results from the most
recent and complete monitoring conducted in 1997 are included in the Preliminary Assessment (PA) report
prepared by UOS (UOS 2001a).
During 2001, Region VEQ EPA conducted a PA/Site Investigation at the Iron Mountain Mill site. START2
collected approximately 44 environmental samples as part of the SI during October 2001. Eleven soil
samples were collected from the high school track and residential properties in Superior. Soil samples
collected from the high school track were compared to the background sample collected in the town of
Superior at a park. All or most of the samples had concentrations of the following analytes at least three
times above the background sample: antimony; arsenic; cadmium; calcium; copper; lead; manganese;
mercury; silver; and zinc. Specifically antimony had concentrations ranging from 34.4 parts per million
(ppm) to 1,050 ppm, arsenic ranging from 79.4 ppm to 1,690 ppm, lead ranging from 423 ppm to 8,500 ppm,
and mercury ranging from 0.32 ppm to 12.4 ppm.
The soil sample collected at 208 Main Avenue had the following analytes with at least three times the
background concentrations: antimony (1,250 ppm), arsenic (1,570 ppm), cadmium (42 ppm), copper (73.9
ppm), iron (72,000 ppm), lead (11,300 ppm), manganese (3,200 ppm), mercury (9.9 ppm), silver (76.5 ppm),
and zinc (7,620 ppm). The soil sample collected at Third and Spruce had the following analytes with three
times the background concentrations: antimony (972 ppm), arsenic (1,540 ppm), cadmium (10.8 ppm),
copper (41 ppm), iron (68,800 ppm), lead (7,930 ppm), manganese (2,570 ppm), mercury (5.7 ppm), silver
(60 ppm), and zinc (2,580 ppm). Potential targets for the surface soil pathway include the local residents
living where elevated metals were located. Potential targets for the high school track include the 383
elementary and high school students who attend school in the Superior School District. Because of these
results, the Region VIE EPA had tasked START2 to collect additional samples from the town of Superior
as part of a removal assessment.
TDD No. 0203-0008
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4.0 SITE ACTIVITIES AND OBSERVATIONS
Field operations were conducted as described below, in accordance with the EPA Region VEn Residential
Soil Lead Sampling Guidance Document, START2 Technical Standard Operating Procedures (TSOPs), the
UOS Field Samplers Guide, and the site specific Health and Safety Plan (EPA 2000; UOS 2000; UOS 1998;
UOS 2002b). Sampling activities were conducted in level D PPE.
4.1 SAMPLING ACTIVITIES
The sampling approach was judgmental and was based on the subjective selection of sampling
locations where contamination was expected to occur. Professional judgement was based upon soil
criteria such as the color, grain size, texture, and other physical characteristics. Vegetative cover was
also used to determine sample locations. The majority of the right of ways and open spaces were
sampled because persons residing in Superior suspected tailings were brought into those locations.
Samples were collected from 64 residential properties, 20 right-of-ways, and 10 city or county or
open space properties (parks, vacant lots, parking lots, etc.) within and around Superior, Montana.
Sample locations are depicted on Figure 1. At the time of sample collection, a sketch of each
property was drawn on a field form and sample location information was recorded. The soil sample
locations were also recorded with a GPS by START2 (Photo 1). Items of interest were photo
documented. Soil samples were collected in accordance with procedures described in TSOP 4.16,
"Surface and Shallow Depth Soil Sampling" (UOS 2000; EPA 2000). Sampling areas were divided
into three groups: residential properties; road right of ways; and city or county properties or open
spaces. Composite surface samples were collected between 0 and 3 inches below ground surface
(bgs) at each location. Sample collection started by using a sharp shooter or pick to remove the top
layer of soil, gravel, or organic matter (Photos 2 & 3). Soil samples were then collected using
dedicated scoops. As directed by the EPA OSC, additional samples were collected if the
concentrations of a surface sample were above 100 ppm arsenic and7or 500 ppm lead. The additional
samples were used to delineate the area of elevated metals concentrations. A minimum of one depth
sample was collected where elevated concentrations were determined. Depth samples were collected
at a depth of 9 to 12 inches below ground surface using the same method as described for the surface
samples. All additional samples were collected as grab samples, including the depth samples.
TDD No. 0203-0008
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4.1.1 Residential Property Samples
Residential property samples were collected from properties that contain a structure where
persons reside or business properties that contain areas that may be contaminated. Sample
quantities were determined by the size of the property. For a standard size lot (5,000 square
feet) or smaller, the total area was considered one sampling zone. A minimum of two
composite surface samples were collected from each zone to determine if elevated metals
concentrations exist. Additional samples were collected if children play areas were
identified, if discolored soil material was visible, or if vegetation was stressed at a specific
location. Because driveways were suspect areas, a sample was collected from the driveway
at most properties. If elevated concentrations of lead (500 ppm or greater) or arsenic (100
ppm or greater) were detected, additional samples were collected to delineate the elevated
concentrations. Large residential properties, were divided into zones that were no larger
than a standard lot. Each zone was sampled in the same manner as zones from a standard
sized lot.
4.1.2 Road Right of Way Samples
Road samples were collected from right-of-ways or alleys where elevated metals
concentrations were suspected. Discrete surface samples between 0 and 3 inches were
initially collected at 50-foot intervals on each side of the street or down the approximate
center line of alleys. Sample locations were random unless discolored material or areas with
stressed or no vegetation were observed. If elevated metals concentrations were detected
in the initial surface samples, additional grab surface samples and depth samples were
collected. These samples were used to delineate the area of elevated metals concentrations.
Visual observations were also noted to help delineate the areas of high concentrations.
4.13 Open Space Samples
Open space samples were collected from large properties that are not used for residential
purposes. This included parking lots, parks, city or county property, and vacant lots. For
ease of description, these will all be referred to in this document as open spaces. Open
space properties were divided into zones depending on the size of the original area and the
TDD No. 0203-0008
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use of the property. One composite surface sample (0 to 3 inches bgs) was collected from
each zone. If metals concentrations were elevated additional samples were collected to
delineate the area with elevated concentrations. All surface and depth samples used to
delineate areas with elevated metals concentrations were grab samples.
4.2 SAMPLE LOCATION IDENTIFICATION
Sample identifiers were written on the sample container with waterproof ink along with the date and
time of sample collection. Sketches of each property were completed on field forms at the time of
sample collection. Sample identifiers, sample locations, and sample date and time were also
documented on the field form.
4.2.1 Residential Samples
Residential samples were identified based on sample location area. Samples were designated
as follows:
The first field is the letter "S" that designates the sampling event as Superior Waste
Rock site.
The second field is the four digit house number.
The third field is two letters that represent the street on which the property is
located (Appendix D).
The fourth field is the section or zone number (most sample locations are
considered zone 1).
The fifth field is the sample depth or the composite surface sample indicator.
SI - Grab Surface sample from sample location 1.
S2 - Grab Surface sample from sample location 2.
Dl - Grab Depth sample from sample location 1.
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The last field indicates if the sample is a replicate, duplicate, or equipment blank
sample. If the last field is null, the sample is not a field quality control sample.
R - Replicate sample.
D - Duplicate sample.
B - Equipment Blank sample.
Example:
For a surface sample at the residential property at 110 Main Street.
S0110MN1S1
4.2.2 Open Space Samples
Open space samples were identified based on sample location area. All sample locations
were designated on the respective field form. Samples were designated as follows:
The first field is the letter "S" that designates the sampling event as Superior Waste
Rock site.
The second field is the four digit property address.
The third field is two letters that represent the street on which the property was
located or two letters that represented the property identification (Appendix D).
The fourth field consists of two letters that define the area sampled. Many open
space sample locations were designated by the directional location.
NW - Northwest zone on the property
CC - Center zone on the property
SW - Southwest zone on the property
If a directional location was not applicable each location was designated by a zone
(1,2,3).
The fifth field is a number defining the sample depth. Number 1 represents surface
samples collected from 0 to 3 inches and an X represents depth samples collected
from 9 inches to 12 inches. If a number was used in field four to represent the zone,
the fifth field uses SI and S2 as surface samples and Dl and D2 for depth samples.
The last field indicates if the sample was a replicate, duplicate, or equipment blank
sample. If the last field is null, the sample is not a field quality control sample.
TDD No. 0203-0008
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The last field indicates if the sample is a replicate, duplicate, or equipment blank
sample. If the last field is null, the sample is not a field quality control sample.
R - Replicate sample.
D - Duplicate sample.
B - Equipment Blank sample.
Example:
For a surface sample at the 600 block at 6th Avenue East, at 50 foot interval B on the
south side of the road.
S06006ESB1
4.3 DERIVATIONS FROM FIELD SAMPLING PLAN
The field sampling plan designated that surface samples would be grab samples collected from a
discrete location. The EPA OSC and EPA toxicologist later determined that surface composites
would be collected from residential and open space areas. Discrete sample locations were still
collected from the right of way surface locations. AH depth samples were also discrete samples as
described in the Sampling Activities Plan.
The right of ways on the 100 block of River Street and the 600 block of 4th Avenue East were not
sampled because concrete and asphalt covered the entire right of way for each location. The
following properties were originally identified for sampling, but were not addressed because of the
distance from the town of Superior, later refusal of access, or change of ownership.
202 Riverbend Road
9 Robins Nest Lane
56 Sloway West
31 Spritis Walk Lane
24 Sunnyside Lane
41 Flat Creek Road
13 Country Lane
514 T16N R27W Lower Oregon Creek
421 Diamond Road
25 Shaw Gulch Lane
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R - Replicate sample.
D - Duplicate sample.
B - Equipment Blank sample. .
Example:
For a composite surface sample collected at the Little Park open space in the
northwest zone.
S0202LPNW1
4.2.3 Right of Wav Samples
Road Right of way samples were identified based on sample location area. Samples were
designated as follows:
The first field is the letter "S" that designates the sampling event as Superior Waste
Rock site.
The second field is the four digit number representing the block.
The third field is two letters that represent the street on which the property is
located.
The fourth field represents the side of the road being sampled.
N-North
S- South
M - Middle
E - East
W - West
The fifth field is the 50 foot node designation. The node that is most east or south
is designated as node A and increases as the distance increases moving west or
north.
The sixth field is the depth or surface sample indicator. The number one was used
for the surface samples and the letter X represents a depth sample.
TDD No. 0203-0008
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4.4 ANALYTICAL PARAMETERS
Soil samples were analyzed by START2 using a Spectrace 9000ฎ Field Portable XRF. A minimum
of 10 percent of the total number of samples collected for field XRF analysis were also sent to a
commercial laboratory forTAL metals analysis as confirmation of field XRF results. Confirmation
samples were dried at less then 100ฐF and sieved with a 60-mesh or 10-mesh screen before being
sent to the commercial laboratory for TAL analysis (SW846 Method 601 OB/7471). A total of four
soil samples were selected and sent to an independent laboratory for TCLP analysis (SW846
Methods 1311/ 601 OB/7471). The samples sent for TCLP analysis represented the samples with the
higher concentrations of metals. The acceptable holding times for these samples are 28 days for
mercury and six months for all other metals. The definitive data was validated using the QA/QC
procedures associated with definitive data. Information pertaining to screening level and definitive
data can be found in the Emergency Response Program (ERP) Generic Quality Assurance Project
Plan (QAPP) (UOS 1999). Five selected samples were sent for arsenic and lead speciation to
determine bio-availability.
4.4.1 XRF Sample Preparation
XRF sample preparation followed the general guidelines set forth below and in SOP 6 from
the EPA Bioavailability Study (EPA 1994b).
The samples were collected in a seal top poly bag, homogenized, labeled with the
appropriate sample identification, and transported to the field laboratory work space
for XRF analysis.
A portion of the sample was placed in a container for drying on a griddle at
temperatures not to exceed 100ฐF, or by air drying over night. All containers had
identification tags containing a number that was cross-referenced to the sample
number and documented in the XRF sample preparation logbook.
Once the samples were dry, they were sieved using nylon lead-free sieves. A 60-
mesh sieve (250 micrometers (/*m)) was used for the residential surface samples.
All other samples were sieved using a 10-mesh sieve. Samples placed on top of the
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screen were shaken, swirled, tapped, and bumped until all the particles smaller than
the mesh had fallen through the sieve. The samples were not ground or forced
through the sieve.
The collection tray was emptied into an XRF sample cup. The drying and sieving
of additional sample material was repeated until the XRF sample cup was filled.
The sample cup was covered with 0.2-mil Mylarฎ film and tapped on a table top
to pack the sample against the window film.
Samples were analyzed as stated in Section 5.2.1, "XRF Analysis."
Non-dedicated sieves, collection trays and any other implements used were
decontaminated according to SOPs.
If the sample was dry enough to flow through the mesh sieve easily, a dry decontamination
was used. The pan was wiped with paper towel and the screen brushed with a brass brush.
If the sample did not flow through the sieve easily, a wet decontamination was used. The
screen and pan were washed with a Liquinoxฎ solution; rinsed with potable water; and
dried.
The XRF was operated as per ERT SOP 1713 and manufacturers specifications. Quality
control for the instrument are discussed in Section 5.2 of this report. Samples were analyzed
on the XRF using analysis times of 120 seconds for the source Cd-109, 30 seconds for the
source Fe-55, and 30 seconds for the source Am-241.
TDD No. 0203-0008
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5.0 QUALITY ASSURANCE AND QUALITY CONTROL
5.1 LABORATORY QUALITY CONTROL
Specific QC criteria have been developed to ensure that the Data Quality Objectives (DQOs)
established in the SAP can be achieved. Analytical methods for sample analysis have been selected
on the basis of the required detection limits, known contaminants existing in the study area, and the
range of analytes to be determined. XRF data will be evaluated as screening. Laboratory data will
be evaluated as definitive. The Draft ERP Generic QAPP, Section 10.2 "Laboratory Quality
Control," contains more specific information related to laboratory QC requirements for definitive
data (UOS 1999).
5.2 FIELD QUALITY CONTROL
5.2.1 XRF Analysis
XRF field analytical data was evaluated as screening data, with an additional ten percent of
these samples being analyzed by an independent laboratory for definitive confirmation
analysis. All XRF data generated for this project were evaluated for instrument calibration,
detection limits, energy calibration checks, blank checks, and field replicates. The field
XRF was operated per ERT SOP 1713 and per manufacturer's specifications.
High lead concentrations may mask arsenic concentrations when analyzed on an XRF. The
arsenic detection limit for the XRF is either three times the standard deviation of the XRF
standard, or one-tenth the lead result, whichever is greater.
5.2.2 Field Quality Control Samples
In addition to the samples collected to determine elevated concentrations of metals, samples
were also collected and analyzed as part of the quality control process .
A minimum of 1 per 20 soil samples collected for XRF analysis were collected in
the field as replicate samples.
TDD No. 0203-0008
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Page 13 of 49
A duplicate XRF sample was prepared in the lab for every 20 soil samples.
A minimum of 1 per 10 soil samples collected for XRF analysis was analyzed by
an independent laboratory for confirmation of XRF analytical results. The XRF
sample cup was sent to the laboratory for analysis.
Sand rinsate blanks were collected a minimum of 1 per day using decontaminated
sampling equipment and a sieve to identify potential contamination from the sample
collection and preparation implements.
6.0 ANALYTICAL DATA EVALUATION
All soil samples were analyzed with an XRF during field activities. The XRF field analytical data were
evaluated as screening data according to the START Generic Quality Assurance Project Plan (QAPP) with
an additional ten percent of these samples being analyzed by and independent laboratory (CompuChem) for
definitive confirmation analyses. All XRF data generated for this project were evaluated to ensure that
instrument calibration, detection limits, energy calibration checks, blank checks, and field replicates were
within operational control limits. The XRF was operated as per ERT SOP 1713, and per manufacturer's
specifications.
Detection limits were calculated for both the XRF instrument used and for all laboratory confirmation
samples. Detection limits were established as a value three times the standard deviation of a low National
Institute of Standards and Technology (NIST) certified standard run a minimum of seven times over a
specified period of time. In the case of arsenic, the detection limit is as stated above or one-tenth of the lead
concentration for that sample, whichever is greater.
Validation of the confirmation laboratory data was completed by TechLaw, Inc. of Lakewood, Colorado.
All data are acceptable for use as qualified in the data validation reports (Appendix A). The laboratory forms
and a Table containing the laboratory results are also in Appendix A. Qualifiers used by laboratory
validators consisted of U and J. A qualifier of U signifies that the metal was not detected at or above the
associated numerical value for that sample. A qualifier of J signifies that the associated numerical value was
estimated based on one of many reasons pertaining to laboratory quality assurance. While the value
TDD No. 0203-0008
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Contract No. 68-W-OO-118 Date: 08/2002
Page 14 of 49
associated with the J qualifier is an estimate, the presence of the metal is reliable. Please refer to the data
validation packages for specific criteria for all laboratory confirmation data.
The laboratory versus XRF metal concentration data were compared using relative percent difference (RPD).
Relative percent difference is the difference between the lab and XRF data divided by the average of the two
values. This method shows less variability for the larger concentration data because the average (divisor)
is higher and the result shows a lower RPD. At lower concentrations, a small variation between the values
shows a larger RPD because the average is lower. This method for XRF data evaluation is more specific to
whatever range of data is of most interest (usually the "action level"). RPD calculations for arsenic,
antimony, lead, and zinc are reported in Table 2. The RPD was not calculated for those results that were
qualified as U or J. An RPD value of 35 percent or less suggests an acceptable concentration variance. Only
one sample had an RPD calculated for the lead concentrations above 35 percent. Sample S0208MN1S3 had
an RPD of 41%; however, this is probably due to the high concentrations of lead (greater than 10,000 ppm)
in the sample and the variability of the XRF at this concentration.
7.0 SAMPLE RESULTS
A total of 635 soil samples were collected for XRF analysis. All XRF sample results are listed in Appendix
B. Table 1 also lists the lead and arsenic concentrations for each sample. Although ten percent of the
samples were sent to a commercial laboratory for definitive results, the discussion below only specifies XRF
results. Laboratory results are compared to the XRF results in Table 2 and discussed in the previous section.
Five right of ways had concentrations of lead above 500 ppm or arsenic above 100 ppm. Table 3 describes
each right of way with elevated metals concentrations along with sample results above the action levels.
Each area is relatively small with estimated volumes of material ranging between 0.5 cubic yards and 35
cubic yards (Photo 4). One right of way location at the Pine Street Alley had a concentration of arsenic at
110 J ppm. Although this result is above the action level, all other results are not considered elevated and
this location is not considered to have tailings material. The right of way originally identified during the
2001 sampling activities appeared to be cleaned up with a small amount of tailing material left
(approximately 1.2 cubic yards).
A total of nine residential locations had samples above the action levels stated above (Table 3). These
locations are also described in Table 3. The estimated volume of material ranges between 0.15 cubic yards
TDD No. 0203-0008
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Page 15 of 49
and 21 cubic yards for each property. Interviews with property owners indicated that the tailings material
was generally used to minimize vegetative growth, reduce dust, or fill in low spots on the property (Photo
5). The property originally identified during 2001 field activities is included on this table with additional
samples collected during the 2002 field activities. This property is owned by the United States Forest Service
and will not be included in any remedial activity completed by the EPA.
Three open space properties were determined to have elevated concentrations of metals (Table 3). The high
school track, the fairgrounds, and the city shop all have concentrations of lead above 500 ppm and the high
school track also had concentrations of arsenic above 100 ppm. The fairgrounds has an estimated volume
of 175 cubic yards of material. The high school track has an estimated volume of 3111 cubic yards. Finally,
the city shop has an estimated volume of 120 cubic yards of material with elevated metals concentration.
A total of four samples were also sent to the laboratory for TCLP analysis. The samples were selected
because of the high concentrations of lead and/or arsenic detected on the XRF. Sample results for this
analysis are listed in Table 4. All samples had concentrations of lead above the regulatory limit (5 milligrams
per liter (mg/L)). Five samples were submitted for lead and arsenic speciation and in vitro bioavailability.
Samples were selected from the high school track, the fairgrounds, the residence at 106 3rd Avenue West, the
residence at 407 Iron Mountain Heights, and the residence at 403 2nd Avenue West. These samples were also
selected because of the high concentrations of lead and/or arsenic detected on the XRF. These results were
not available at the time this report was written. The results will be included in the final Sampling Analysis
Report.
TDD No. 0203-0008
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URS Operating Services, Inc. . Superior Waste Rock - SAR
START2, EPA Region VIM Revision: 0
Contract No. 68-W-OO-118 Date: 08/2002
Page 16 of 49
8.0 SUMMARY
Sampling activities for the Superior Waste Rock site was completed between June 3 and June 13, 2002. A
total of 635 samples were collected from 64 residential properties, 20 right-of-ways, and 10 city/county and
open space properties within and around Superior, Montana. A total often residential properties originally
identified for sampling were not completed because of the distance from the town of Superior, later denial
of access, or change in ownership. In addition, samples were not collected from 2 right of ways originally
identified for sampling because concrete or asphalt covered the entire right of way.
Soil samples were analyzed on site with an X-Ray Fluorescence Spectrometer (XRF) for metals. A total of
26 duplicate samples were also prepared and analyzed using the XRF to determine the quality of sample
preparation. Ten percent of the total number of samples collected for XRF analysis (64 samples) were sent
to a commercial laboratory for Target Analyte List (TAL) metals analysis as confirmation of field XRF
results. Four soil samples were also selected and sent to a commercial laboratory for Toxicity Characteristic
Leaching Procedure (TCLP) analysis of TAL metals. Five samples were submitted for lead and arsenic
speciation and in vitro bioavailability.
Five right of ways had concentrations of lead above 500 ppm or arsenic above 100 ppm. These, right of
ways, XRF results, and a description of the area are described in Table 3. Each area is relatively small with
estimated volumes of material ranging between 0.5 cubic yards and 35 cubic yards.
Nine residential locations had samples above the action levels stated above. These locations are also
described in Table 3. The estimated volume of material ranges between 0.15 cubic yards and 21 cubic yards
for each property. Generally, the tailings material was used to minimize vegetative growth, reduce dust, or
fill in low spots on the property.
Three open space properties were determined to have elevated concentrations of metals. The high school
track, the fairgrounds, and the city shop all have concentrations of lead above 500 ppm and the high school
track also had concentrations of arsenic above 100 ppm. The fairgrounds has an estimated volume of 175
cubic yards of material. The high school track has an estimated volume of 3111 cubic yards. Finally, the
city shop has an estimated volume of 120 cubic yards of material with elevated metals concentration.
TDD No. 0203-0008
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URS Operating Services, Inc. Superior Waste Rock - SAR
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Contract No. 68-W-OO-l 18 Date: 08/2002
Page 17 of 49
A total of four samples were also sent to the laboratory for TCLP analysis. The samples were selected
because of the high concentrations of lead and/or arsenic detected on the XRF. Sample results for this
analysis are listed in Table 4. All samples had concentrations of lead above the regulatory limit (5 mg/L).
TDD No. 0203-0008
P:\Slart2\Superior Waste Rock\Rnal SARVText.wpd
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URS Operating Services, Inc. Superior Waste Rock - SAR
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Contract No. 68-W-OO-l 18 Date: 08/2002
Page 18 of 49
9.0 LIST OF REFERENCES
ASARCO. 1999. Letter from J. C. Pfahl, ASARCO, to Stephen Brown, Garlington, Lohn, and Robenson,
PLLP. April 26, 1999.
Environmental Response Team (ERT). 1995. "Spectrace 9000 Field Portable X-Ray Fluorescence
Operating Procedures." January 26, 1995.
Montana Bureau of Mines and Geology (MBMG). Date Unknown. Title unknown. Mineral County. Iron
Mountain District. Bulletin No. 30. Page 31.
Montana Department of Environmental Quality (Montana DEQ). 2001. Mining History web site.
. March 2, 2001.
Montana Department of State Lands - Abandoned Mine Reclamation Bureau (MDSL-AMRB). 1993.
Abandoned Mine Inventory, Iron Mountain Mine and Mill site. July 23, 1993.
U.S. Environmental Protection Agency (EPA). 1994a. U.S. Environmental Protection Agency CLP National
Functional Guidelines for Inorganic Data Review, EPA 540/R - 94/013 (2/94).
U.S. Environmental Protection Agency (EPA). 1994b. U.S. Environmental Protection Agency Region VIE
Unavailability Study - Phase n Investigations - Standard Operating Procedures. September 1994.
U.S. Environmental Protection Agency (EPA). 2000. Region VIJJ Superfund Program Residential Soil Lead
Sampling Guidance Document. Draft Final. April 2000.
URS Operating Services, Inc. (UOS). 1998. "Field Sampler's Guide for Sample Collection and
Documentation." February 1998.
URS Operating Services, Inc. (UOS). 1999. "Emergency Response Program (ERP) Generic Quality
Assurance Project Plan (QAPP) for the Superfund Technical Assessment and Response Team (START),
EPA Region VIO." March 11, 1999.
TDD No. 0203-0008
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Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 19 of 49
URS Operating Services, Inc. (UOS). 2000. START Standard Operating Procedures, Volume 4: Technical
Standard Operating Procedures. September 2000.
URS Operating Services, Inc. (UOS). 2001a. Preliminary Assessment. Iron Mountain Mill, Superior,
Mineral County, Montana. July 20, 2001.
URS Operating Services, Inc. (UOS). 2001b. Site visit/reconnaissance by Rebecca Laramie and Log Book
#570. March 29, 2001.
URS Operating Services, Inc. (UOS). 2002a. Analytical Results Report for Focused Site Inspection, Iron
Mountain Mill, Superior, Mineral County, Montana. January 24, 2002.
URS Operating Services, Inc. (UOS). 2002b. Site Health and Safety Plan for Superior Waste Rock. May
2002.
TDD No. 0203-0008
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O
LEGEND
Concentration
in ppm
As >= 100
and/or
Pb >= 500
As < 100
and
Pb < 500
Depth
Sample
A
A
Surface
Sample
O
MONTANA
Helena
Site of Study
URS
OPERATING SERVICES
SUPERIOR WASTE ROCK
MINERAL COUNTY, MONTANA
Figure 1: Sample Distribution and
Hot Concentration Values on Superior
August 2002
DOS - START2
TDD No. 0203-0008
Source: USGS Aerial Photo
03-12-94
Northing & Easting Units: Meters
N
200
SCALE: 1:2,500
200 400
600 Feet
659000
659250
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URS Operating Services, Inc.
START2, EPA Region Vlll
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 21 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location .' -' - r ;
100 block 1s' Street
300 block 2nd Avenue West
400 block 2nd Avenue West
500 block 2nd Avenue West 1
200 block 3rd Avenue East
r ~ - .- ..--" V ' ' '
Property Type
Right of Way
Right of Way
Right of Way
Right of Way
light of Way
^:-V:-D>K-;
S01001SWA1
S01001SWB1
S01001SWC1
S01001SWD1
S01001SWE1
S01001SWF1
S01001SWF1D
S03002WNF1
S03002WNG1
S03002WSF1
S03002WSG1
S04002WNA1
S04002WNB1
S04002WNC1
S04002WNC1R
S04002WND1
S04002WNE1
S04002WSA1
S04002WSB1
S04002WSC1
S04002WSD1
04002WSE1
05002 WNA1
05002WNB1
05002WNC1
05002 WS A 1
05002WSB1
05002WSC1
02003ENA1
02003ENB1
02003ENC1
02003END1
02003ENE1
Analysis
i^bate?.;-;
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/1 1/02
6/1 1/02
6/11/02
6/11/02
6/1 1/02
6/1 1/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/1 1/02
6/11/02
6/1 1/02
6/1 1/02
6/1 1/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/11/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
Analysis
feTfrne*
914
918
922
927
935
939
943
1446
1450
1435
1440
1521
1526
1531
1559
1540
1553
1457
1502
1506
1511
1516
1625
1629
1634
1605
1615
1620
1558
1602
1606
1610
1614
':>ฃ^;>
'/'j-si.r-.;Y-
;;*3te&:?
51 U
51 U
51 U
51 U
51 U
51 U
51 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
58 J
46 U
60 J
46 U
46 U
46 U
100 J
46 U
46 U
46 U
46 U
46 U
46 U
46 U
36 U
36 U
36 U
47 J
36 U
v,-^.*.*_ .-
66 J
22 J
42 J
25 J
42 J
180
160
99
41 J
23 U
39 J
350
50 J
33 J
23 U
48 J
23 U
27 J
68 J
23 U
770
85
23 U
23 U
160
53 J
60 J
61 J
36 J
53 J
70 J
36 U
36 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARYTexl.wpd
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URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 22 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location
200 block 3rd Avenue East
(continued)
300 block 3rd Avenue East
400 block 3"1 Avenue East
Property Type
Right of Way
Right of Way
iight of Way
.-_* "-.;;. :./'.,- ".._
^y&;^$
S02003ENF1
S02003ENG1
S02003ESA1
S02003ESB1
S02003ESC1
S02003ESD1
S02003ESE1
S02003ESF1
S02003ESG1
S02003ESG1R
S03003ENA1
S03003ENB1
S03003ENC1
S03003END1
S03003ENE1
S03003ENF1
S03003ENG1
S03003ESA1
S03003ESA1D
S03003ESB1
S03003ESC1
S03003ESD1
S03003ESE1
03003ESF1
03003ESG1
04003ENA1
04003ENB1
04003ENC1
04003END1
04003ENE1
04003ENF1
04003ENG1
04003ESA1
ft^'iwte^
6/6/02
6/6/02
6/7/02
6/7/02
6/7/02
6/7/02
6H/02
en/02
6/7/02
en/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
en/02
en/02
en/02
6/7/02
en/02
en/02
en/02
en/02
en/02
en/02
^naiyiii
-r ป ^.ฃuuw./~i
1619
1623
949
956
1001
1005
1009
1013
1017
1021
1627
1631
1635
1639
1643
1647
1652
1655
1659
1704
1708
1711
1716
835
839
843
847
851
855
859
903
907
911
gsgฃ^:^72|g:
T5ฃ3^p^fc*JSr^t'
ฅง~ซi-^4S'j;sซ
36 U
36 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
36 U
36 U
36 U
36 U
40 J
36 U
36 U
36 U
36 U
36 U
36 U
54 J
36 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U.
38 U
I1SS
36 U
40 J
170
140
58 J
24 U
44J
56 J
24 U
24 U
36 U
190
110J
75 J
36 U
51 J
36 U
220
220
270
180
44J
81 J
66 J
43 J
38 J
24 U
38 J
24 U
160
32 J
37 J
78 J
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Fmal SARYText.wpd
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URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 23 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location A*: -V-"- '""'-:
400 block 3rd Avenue East
[continued)
300 block 3rd Street
600 block alley between 4th
& 5th Avenue
Property Type
Right of Way
Right of Way
Right of Way
<
I
J
<
' '-" '' ^a - 1 *' ' ' " '
:.: y'S': 8? ::.'. '.!'
S04003ESB1
S04003ESC1
S04003ESD1
S04003ESDX
S04003ESE1
S04003ESF1
S04003ESG1
S04003ESG1D
S04003ESG1R
S03003SEA1
S03003SEB1
S03003SEC1
S03003SEC1R
S03003SED1
S03003SWA1
S03003SWB1
S03003SWC1
S03003SWD1
S06004AMA1
S06004AMB1
S06004AMC1
S06004AMD1
S06004AME1
S06004AMF1
S06004AMG1
S06004AMH1
S06004AMI1
S06004AMJ1
506004 AMK1
306004 AML1
506004 AMM1
506004 AMN1
506004 AMO1
^Analysis'
^-Date::.':;
. 6/7/02
6/7/02
6H/02
6/12/02
enm
en/02
en/02
en/02
en/02
6/1 1/02
6/11/02
6/11/02
6/1 1/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
Analysis
.',- Tiinei*
915
919
923
837
927
932
936
940
944
1638
1643
1648
1653
1658
1703
1707
1713
1717
914
919
923
931
935
938
943
947
956
959
1004
1008
1012
1016
1020
&$?&%%
w^1* >"/Vs ซ'"-.
fy+AsfK-h.
38 U
38 U
38 U
34 U
220 U
43 J
38 U
38 U
38 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
36 U
36 U
36 U
36 U
51 J
36 U
36 U
36 U
36 U
40 J
36 U
36 U
36 U
36 U
36 U
imm
68 J
43 J
24 U
23 U
2200
230
100
110
110
58 J
42 J
54 J
33 J
240
34 J
29 J
23 U
23 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
38 J
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFmal SARYText.wpd
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URS Operating Services, Inc.
START2, EPA Region VIII
ContractNo.68-W-00-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 24 of 49
TABLE 1
Lead and Arsenic XRF Results
Location
600 block alley between 4"1
& 5lh Avenue
(continued)
100 block 4th Avenue East
200 block 4lh Street
300 block 4th Street
600 block alley between 5th
& 6th Avenue
Property Type
Right of Way
Right of Way
Right of Way
Right of Way
*ightofWay
<
<
<
<
..';:riD':;;fJ-
S06004AMP1
S06004AMQ1
S06004AMQ1D
S06004AMR1
S06004AMS1
S06004AMT1
S06004AMU1
S06004AMU1R
S06004AMV1
S01004END1
S01004END1B
S02004SEA1
S02004SEB1
S02004SEC1
S02004SED1
S02004SWB1
S02004SWC1
S02004SWD1
S03004SEA1
S03004SEB1
S03004SEC1
S03004SEC1R
S03004SED1
S03004SWA1
S03004SWB1
S03004SWC1
S03004SWD1
506005 AM A 1
506005 AMB1
506005 AMC1
506005 AMD1
506005 AME1
506005 AMF1
$MJJjariB.ijฃ
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/8/02
6/8/02
6/11/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/1 1/02
6/1 1/02
6/11/02
6/1 1/02
6/12/02
6/11/02
6/11/02
6/12/02
6/12/02
6/12/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
-TMtl
1024
1028
1032
1036
1040
1044
1049
1056
1100
1135
1140
1722
1726
1731
1742
1750
1754
1758
1802
1806
1810
828
1814
1818
805
809
813
1352
1356
1401
1404
1413
1417
41J
36 U
36 U
48 J
36 U
36 U
36 U
36 U
42 J
51 U
51 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
34 U
46 U
59 J
37 J
34 U
54 J
31 J
45 J
26 J
23 U
37 J
32 J
HI
36 U
46 J
36 U
36 U
36 U
36 U
39 J
36 U
36 U
28 J
21 U
44 J
23 U
89
62 J
34 J
50 J
23 U
30 J
23 U
25 J
47 J
84
74 J
100
69 J
25 J
19 U
19 U
26 J
39 J
43 J
19 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFinal SARYText.wpd
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URS Operating Services, Inc.
START2, EPA Region VIU
Contract No. 68-W-OO-l 18
TABLE 1
Lead and Arsenic XRF Results (ppm)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 25 of 49
Location . '.,'^H, %!&*;
'h-j\;~;&
?;V-*"As^.
23 U
51J
51 J
27 J
40 J
24 J
26 J
27 J
39 J
23 U
27 J
31 J
23 U
23 U
73 J
23 U
23 U
23 U
23 U
35 J
23 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
34 J
32 J
23 U
26 J
t%2?ฃ&
S?ttSi
39 J
J9U
19 U
21 J
41 J
27 J
43 J
60 J
29 J
33 J
19 U
63 J
67
67
160
43 J
47 J
19 U
38 J
43 J
59 J
56 J
19 J
20 J
27 J
39 J
39 J
28 J
34 J
58 J
110
19 U
49 J
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Rnal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 26 of 49
TABLE I
Lead and Arsenic XRF Results (ppm)
Location
600 block 5lh Avenue East
(continued)
600 block 6th Avenue East
Property Type
Right of Way
Right of Way
v-'f-n)-;/--:--
S06005ESA1R
S06005ESB1
S06005ESC1
S06005ESD1
S06005ESE1
S06005ESF1
S06005ESG1
S06005ESH1
S06005ESI1
S06005ESJ1
S06005ESK1
S06005ESL1
S06005ESM1
S06005ESN1
S06005ESO1
S06005ESP1
S06005ESP1D
S06005ESQ1
S06005ESR1
S06005ESS1
S06006ENA1
S06006ENB1
S06006ENC1
S06006END1
S06006ENE1
S06006ENF1
S06006ENF1D
S06006ENG1
506006ENH1
506006ENI1
506006ENJ1
506006ENM1
506006ENN1
H^iJiiiฎ^
6/5/02
6/5/02
6/5/02
6/5/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
''A^^'J- *-Vx+?~'*'
Analysis
'yjWnBt^ir
t^fim&f
>A ...Wi.' j -iwy
1741
1745
1749
1753
810
814
817
822
826
830
834
838
842
846
850
854
858
902
907
910
1252
1255
1259
1304
1308
1312
1316
1320
1328
1332
1336
1340
1344
HI
39 J
23 U
28 J
49 J
36 U
36 U
36 U
36 U
47 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
23 J
29 J
23 U
36 J
23 U
26 J
32 J
23 U
23 U
29 J
23 U
23 U
23 U
HI
56 J
38 J
160
19 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
80 J
54 J
69 J
34 J
21 J
19 U
130
52 J
65
64J
92
37 J
19 U
56 J
31 J
41 J
TDD No. 0203-0008
P:\Stan2\Superior Waste RockVFinal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-00-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 27 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Lbcationf ,r. ^ /7-i,;i' -'
600 block 6th Avenue East
(continued)
100 block 7Ih Street
100 block of Cedar Street
~:- - / ' .'.- ,' - n.*i"'C
.' ; :. v. _". ' \ " -, .' tji
Property Type
Right of Way
Right of Way
Right of Way
--,"ฃ"' ^ '" ' " "
:S;ฅii>';^
S06006ENO1
S06006ESA1
S06006ESA1D
S06006ESB1
S06006ESC1
S06006ESD1
S06006ESE1
S06006ESF1
S06006ESG1
S06006ESH1
S06006ESI1
S06006ESJ1
S06006ESK1
S06006ESL1
S06006ESM1
S06006ESN1
S06006ESO1
S01007SWA1
S01007SWB1
S01007SWC1
S01007SWD1
S0100CEEA1
S0100CEEB1
S0100CEEC1
S0100CEED1
SOIOOCEEE1
S0100CEEF1
S0100CEEG1
S0100CEEG1R
S0100CEWA1
50100CEWB1
50100CEWC1
J0100CEWD1
."'.Analysis"'
'$TDa&ฃ
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/5/02
6/8/02
6/8/02
6/8/02
6/8/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
Analysi!
Q:T1me>
1348
1141
1145
1149
1153
1158
1202
1207
1211
1215
1219
1223
1227
1231
1235
1243
1247
1220
1224
1228
1232
1154
1158
1202
1207
1210
1214
1219
1105
1226
1231
1236
1355
;;-?ป. '-TT*# YA *
^j-c^H.3"
.^-iSbiฃ>
23 U
23 U
23 U
23 U
44J
23 U
23 U
23 U
29 J
23 U
23 U
33 J
23 U
40 J
23 U
23 U
23 U
51 U
51 U
51 U
54 J
38 U
38 U
38 U
38 U
38 U
43 J
38 U
39 J
38 U
38 U
38 U
38 U
-'t-V*!*?"* "}'--
^-.rfc^.V'r-i
W.-i-*;'*!--'?-'**-
V?'- -*'?ฃ '^'
^E^
-J'~.,V'-^M^" tr--
36 J
24 J
19 U
19 U
19 U
19 U
19 U
82
26 J
43 J
20 J
19 U
19 U
28 J
30 J
37 J
36 J
21 U
21 U
21 U
21 U
24 U
100
50 J
100
70 J
67 J
54 J
30 J
29 J
80
62 J
53 J
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 28 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location.
100 block of Cedar Street
(continued)
200 block of Cedar Street
300 block of Cedar Street
400 block of Illinois Avenue 1
Property Type
Right of Way
Right of Way
Right of Way
Right of Way
light of Way
I'^in^
.-KM.J ..- v/
S0100CEWE1
S0100CEWE1D
S0100CEWF1
S0100CEWG1
S0200CEEA1
S0200CEEA1B
S0200CEEB1
S0200CEEC1
S0200CEED1
S0200CEEE1
S0200CEEF1
S0200CEEG1
S0200CEWA1
S0200CEWB1
S0200CEWB1D
S0200CEWC1
S0200CEWD1
S0200CEWE1
S0200CEWF1
S0200CEWG1
S0200CEWG1R
S0300CEEE1
S0300CEEG1
S0300CEWG1
S0300FCEA1
S0300FCEB1
S0300FCEC1
S0300FCED1
50300FCWA1
50300FCWB1
50300FCWC1
50400ILEA1
50400ILEB1
r;;Aiisi|ysB^
M;D'ffite^*
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6n/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
en/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/1 1/02
6/11/02
Analysii
ฃ--iigsrsv
w33HH&.
1358
1410
1414
1419
1032
1037
1040
1045
1049
1053
1057
1101
1109
1113
1121
1125
1129
1134
1138
1142
1146
1423
1427
1150
1007
1011
15
1019
1023
1027
1031
1255
1302
38 U
38 U
43 J
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
39 J
38 U
38 U
38 U
38 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
46 U
46 U
160
190
100
82
81
24 U
65 J
70 J
110
83
53 J
270
48 J
24 U
24 U
29 J
25 J
24 U
46 J
31 J
25 J
44J
55 J
75 J
21 U
21 U
43 J
35 J
26 J
60 J
47 J
34 J
36 J
TDD No. 0203-0008
P:\Start2\Superior Waste RockVRnal SARVText.wpd
-------
I
I
I
I
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 29 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location -/t ';=,?'.-;
400 block of Illinois Avenue
(continued)
400 block of Maple Street
200 block of Main Street
Property Typie
Right of Way
Right of Way
Right of Way
i
<
<
H-> ip:;^
S0400ILEC1
S0400DLED1
S0400ILEE1
S0400ILEF1
S0400ILEG1
S0400ILEG1D
S0400ILWA1
S0400ILWB1
S0400ILWC1
S0400ILWD1
S0400ILWE1
S0400ILWF1
S0400ILWG1
S0400ILWG1R
S0400MAEA1
S0400MAEB1
S0400MAEC1
S0400MAED1
S0400MAEE1
S0400MAEF1
S0400MAWA1
S0400MAWB1
S0400MAWC1
S0400MAWD1
S0400MAWE1
S0400MAWF1
S0200MNNA1
S0200MNNB1
S0200MNNC1
S0200MNND1
50200MNNE1
30200MNNF1
50200MNNG1
"'' ป*^V- i ^ป'.'"ซ .-'
v Analysis
^)Diate?"
6/11/02
6/11/02
6/11/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/11/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/7/02
en/02
en/02
en/02
en/02
en/02
en/02
Analysis
-"$"ป&
1307
1310
1314
1319
1322
1326
1208
1213
1218
1236
1222
1227
1232
1241
1249
1252
1257
1301
1305
1325
1224
1228
1232
1236
1240
1244
1625
1629
1633
1637
1645
1649
1653
w^m
^&5^
46 U
46 U
46 U
46 U
74 J
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
36 U
36 U
36 U
36 U
41 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
38 U
38 U
38 U
38 U
38 U
41 J
38 U
?**^JVV-' ori':
1^5$^
I:^H^
29 J
30 J
49 J
55 J
70 J
56 J
23 U
23 U
23 U
23 U
23 U
23 U
27 J
38 J
36 U
36 U
54 J
70 J
73 J
110J
83 J
150
110J
80 J
62 J
36 U
130
150
42 J
53 J
59 J
290
130
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFmal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 30 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location j Property Type
200 block of Main Street
(continued)
300 block of Main Street
400 block of Main Street
(Right of Way
Right of Way
Right of Way
:W;ip^-
S0200MNNG1R
S0200MNSA1
S0200MNSB1
S0200MNSC1
S0200MNSD1
S0200MNSDX
S0200MNSE1
S0200MNSF1
S0200MNSG1
S0300MNNA1
S0300MNNB1
S0300MNNC1
S0300MNNE1
S0300MNNF1
S0300MNNF1D
S0300MNNG1
S0300MNSA1
S0300MNSB1
0300MNSC1
0300MNSD1
0300MNSF1
0300MNSG1
0300MNSG1R
0400MNNA1
0400MNNB1
0400MNNC1
0400MNND1
0400MNSA1
0400MNSA1D
0400MNSB1
0400MNSC1
0400MNSD1
.'.'Analysis;'
;;:;;'feyg
6/7/02
en/02
6/7/02
6/7/02
6/7/02
6/12/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/8/02
6/8/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6/7/02
6H/02
6/7/02
en/02
en/02
en/02
en/02
en/02
ji'r'-wvTj'7^'-''
Analysis
jjr-:a"ซฅ.!t*vS
t-USSK
1657
1435
1439
1443
1447
950
1455
1459
1504
1701
1705
1709
1713
1717
814
818
1508
1513
1516
1520
1528
1532
1537
1605
1610
1617
1622
1540
1544
1553
1558
1601
3 ij t^vr*-Jti-ปw5risSi, ~,
38 U
38 U
38 U
43 J
38 U
34 U
38 U
38 U
54 U
43 J
38 U
38 U
38 U
38 U
51 U
51 U
38U
38 U
38 U
38 U
44J
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
50 J
38 U
51 J
?,.S3iiiisRE|j
110
30 J
100
81
93
53 J
71J
61 J
540
150
90
110
200
130
100
250
28 J
24 U
24 U
24 U
31 J
110
95
24 U
24 U
41 J
24 U
24 U
24 U
24 U
41 J
69 J
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region V1I1
ContractNo.68-W-00-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 31 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location V '' '--" ^ " | Property Tyjpe
400 block alley between
Spruce & Pine Street
500 block of Pike Street
200 block Riverside Road I
West Alley
Right of Way
Right of Way
*ightofWay
!,r"r\;'ro::"-r:r-
S0400PAMA1
S0400PAMB1
S0400PAMC1
S0400PAMD1
S0400PAMD1D
S0400PAME1
S0400PAMF1
S0400PAMG1
S0400PAMG1R
S0500PDEA1
S0500PDEB1
S0500PDEC1
S0500PDED1
S0500PDEE1
S0500PDEF1
S0500PDEG1
S0500PDEH1
S0500PDEH1R
0500PDWA1
0500PDWB1
0500PDWC1
0500PDWD1
0500PDWE1
0500PDWE1D
0500PDWF1
0500PDWG1
0500PDWHI
0500PDWI1
0200RAMA1
0200RAMB1
0200RAMC1
0200RAMD1
0200RAME1
;: /Analysis,;
F^Date^i
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
' 6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
Analysis
^me^-
1329
1334
1338
1342
1346
1400
1404
1408
1412
1104
1108
1113
1116
1120
1125
1128
1132
1137
1141
1144
1149
1153
1156
1201
1204
1208
1216
1220
822
826
830
834
838
'''.-'~~'ฃ,i5!t. "*
'',-' ri''" T-<'A
'--'>fe'-..TV.-.
&$i$*
36 U
110 J
36 U
36 U
36 U
41 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
46 J
36 U
36 U
39 J
36 U
36 J
36 U
36 U
36 U
36 U
36 U
36 U
51 U
51 U
51 U
51 U
51 U
'.*!V.."sS13Sisซ;
^ฅ^ฃ
,-iVPbi^v;
65 J
230
260
74 J
71 J
160
83 J
140
190
36 U
36 U
36 U
36 U
36 U
36 U
36 U
90 J
38 J
36 U
42 J
36 U
36 U
37 J
41 J
47 J
36 U
36 U
36 U
56 J
21 U
21 U
39 J
21 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARVText.wpd
-------
URS Operating Services. Inc.
START2, EPA Region VUI
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 32 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location
200 block Riverside Road
West Alley
(continued)
800 block Riverside Road
300 block Riverside Road
400 block alley between
Spruce & Alder Street
500 block S"1 Avenue East
Property Type
Right of Way
[Right of Way
Right of Way
Right of Way
light of Way
:-'. \' ID ::>^
S0200RAMF1
S0200RAMG1
S0200RAMG1R
S0200RAMH1
S0200RAMI1
S0200RAMJ1
S0200RAMK1
S0200RAML1
S0800RVSA1
S0800RVSB1
S0800RVSCJ
S0800RVSD1
S0800RVSE1
S0800RVSF1
S0800RVSG1
S0800RVSG1R
S0300RWSA1
S0300RWSB1
S0300RWSC1
S0300RWSD1
S0300RWSF1
S0400SAMA1
S0400SAMB1
S0400SAMB1D
S0400SAMC1
S0400SAMD1
S0400SAME1
50400SAMF1
S0400SAMG1
50400SAMG1R
50500SESA1
50500SESB1
50500SESC1
;.;Apaiys5s-
J-'^TJtote-jX
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/7/02
6/8/02
6/8/02
6/8/02
Analysi!
841
846
850
854
858
902
906
910
1144
1148
1152
1156
1200
1204
1208
1216
947
951
955
959
1003
519
1523
1527
1532
1537
1540
1549
1553
1025
1322
1326
1330
51 U
51 U
51 U
73 J
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
56 J
51 U
51 U
36 U
36 U
36 U
36 U
36 U
39 J
36 U
36 U
38 U
51 U
51 U
51 U
op
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 33 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
(Location '-y-:i^ '-'-^'.^:':':
500 block 5lh Avenue East
300 block of Spruce Street
400 block of Spruce Street
403 Illinois Avenue
Property Type
Right of Way
Right of Way
Right of Way
Residential
307 Iron Mountain Heights [Residential
407 Iron Mountain Heights I
304 Maple Street F
Residential
Residential
-
H-:?V; ii> ;
S0500SESD1
S0300SPEA1
S0300SPEB1
S0300SPEC1
S0300SPED1
S0300SPEEI
S0300SPEF1
S0300SPEG1
S0300SPEG1R
S0400SPEA1
S0400SPEB1
S0400SPECI
S0400SPED1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWAI
S0400SPWB1
S0400SPWC1
S0400SPWD1
S0400SPWE1
S0400SPWF1
S0400SPWG1
S0403IL1S1
S0403IL1S2
50403IL1S3
S0307IM1S1
50407IH1D1
50407IH1S1
50304MA1S1
.0304MA1S2
I0304MA1S3
. Anittlyrsisk
^JDafe^
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/6/02
6/6/02
6/6/02
6/6/02
6/12/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/6/02
6/9/02
6/9/02
6/9/02
6/10/02
6/12/02
6/10/02
6/9/02
6/9/02
6/9/02
Anajysi
/.jinjei
1334
1035
1039
1043
1047
1055
1059
1103
1107
1356
1422
1425
1429
902
1434
1438
1442
1446
1450
1454
1458
1502
1507
1510
1628
1632
1635
1544
929
1553
1302
1306
1310
-l^
tft-Asr^i
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
36 U
36 U
400
68 J
34 U
67 U
170
150
36 U
36 U
36 U
36 U
36 U
44U
36 U
51 U
51 U
51 U
43 J
110 J
170 U
51 U
51 U
51 U
ฃฃ&&ฃ
KwM
21 U
30 J
54 J
31 J
42 J
81
64J
110
100
130
12.0
1800
300
23 U
670
270
1300
61 J
60 J
58 J
45 J
97 J
440
54 J
35 U
35 U
35 U
120
820
1700
35 U
35 U
60 J
TDD No. 0203-0008
P:\Start2\Superior Waste RockVRnal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VJIJ
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 34 of 49
TABLE 1
Lead and Arsenic XRF Results (ppmn)
Location
304 Maple Street
(continued)
306 Maple Street
307 Maple Street
311 Maple Street
69 Diamond Road
400 Diamond Road
Flat Creek & Cemetery Road
225 Flat Creek Road
617 Cedar Street
106 Cedar Street
202 Cedar Street
208 Cedar Street
61 8 6'h Avenue East
205 Alder Street
Property Type
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
: :'Vrofc;
S0304MA1S4
S0304MA1S5
S0304MA1S5R
S0306MA1S1
S0306MA1S2
S0306MA1S2D
S0307MA1S1
S0307MA1S2
S0307MA1S3
S0311MA1S1
S0311MA1S2
S0311MA1S3
S0169DI1S1
S0169DI1S2
S0400DI1S1
SOOFCCM1S1
S0225FC1S1
S0225FC1S1D
S0225FC1S2
0617CE1S1
0617CE1S2
0.106CE1S1
0106CE1S2
0106CE1S3
0202CE1S1
0202CE1S2
0208CE1S1
0208CE1S2
0208CE1S3
06186E1S1
06186E1S2
0205AL1S1
0205AL1S2
;^'Date%
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/10/02
6/10/02
6/12/02
6/10/02
6/12/02
6/12/02
6/12/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/10/02
6/10/02
6/9/02
6/9/02
, tfF.vjwrfcSL
Analysis
".fr.^^^i'iu^TV
^ffifei
1314
1318
1322
1250
1254
1258
1238
1242
1246
1226
1230
1234
1559
1549
817
1625
832
844
849
1413
1417
1402
1405
1410
1326
1334
1338
1341
1346
845
849
1159
1202
51 U
51U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
43 U
43 U
34 U
43 U
3.4 U
34 U
300
51 U
51 U
51 U
58 J
51 U
51 U
51 U
51 U
51 U
51 U
43 U
52 J
51 U
51 U
^JIK?^
ni
35 U
89 J
120
35 U
35 U
35 U
35 U
35 U
35 U
35 U
36 J
69 J
16 U
16U
43 J
23 J
55 J
130
1600
82 J
61 J
64J
62 J
35 U
71 J
35 U
66 J
49 J
59 J
16 U
16 U
35 U
35 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFinal SARYText.wpd
-------
I
I
I
I
I
I
URS Operating Services, Inc.
START2, EPA Region VHI
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 35 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
. : - -(. :."..' ,-'; .vft ''**.- >v;^V" :'-'-
Location -'..'.'ฃ' .-.>..:? >
205 Alder St. (continued)
300 Alder Street
404 Alder Street
306 Arizona Avenue
404 Arizona Avenue
615 4th Avenue East
627 4th Avenue East
639 4Ih Avenue East
801 4* Avenue East
903 4th Avenue East 1
203 5lh Street I
311 Main Street I
400 Main Street F
Property Type
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
<
Residential 5
^:;;.:.ip ;:v::
S0205AL1S3
S0300AL1S1
S0300AL1S2
S0300AL1S3
S0300AL2S1
S0404AL1S1
S0404AL1S2
S0404AL1S3
S0306AR1S1
S0306AR1S2
S0306AR1S3
S0306AR1S3R
S0306AR2S1
S0404AR1S1
S0404AR1S2
S06154E1S1
S06154E1S2
S06154E1S3
S06274E1S1
S06274E1S1D
S06274E1S2
S06394E1S1
S06394E1S2
S08014E1S1
S08014E1S2
S08014E1S3
S09034E1S1
509034E1S2
502035L1S1
502035L1S2
50311MN1S1
50311MN1S2
50400MN1S1
f. Analysis
W;/Daite^>
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
Analysis
:"T1me^
1207
1143
1147
1150
1155
1214
1219
1222
1507
1511
1516
1520
1559
1459
1503
1349
1353
1358
1423
1428
1431
1435
1439
1443
1447
1455
1548
1552
1038
1046
901
905
908
r^M^
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
43 U
43 U
43 U
45 J
43 U
^T^yS**.
n-j i -f'-j^l -^itr
35 U
35 U
35 U
35 U
36 J
35 U
35 U
78 J
35 U
35 U
180
190
35 U
35 U
35 U
44 J
37 J
41 J
35 U
41 J
35 U
35 U
35 U
35 U
35 U
35 U
35 U
35 U
25 J
16 U
36 J
16 U
16 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 36 of 49
TABLE 1
Lead and Arsenic XRF Results (ppiro)
Location
. 400 Main St. (continued)
205 Main Street
208 Main Street
500 Main Street
502 Main Street
604 Main Street
309 Montana Avenue
23 Mullan Road West
33 Mullan Road West
43 Mullan Road West
Property Type
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
106 Mullan Road East (Residential
146 Mullan Road West
3 19 Old Mullan Road
102 River Street North
205 River Street North
Residential
Residential
Residential
Residential
=.-.-. ..;.,}:.:, ;v": /
~';!r H>''->V-:
S0400MN1S2
S0205MN1S1
S0205MN1S2
S0208MN1S1
S0208MN1S2
S0208MN1S3
S0500MN1D1
S0500MN1S1
S0500MNJS2
S0502MN1S1
S0502MN1S2
S0604MN1S1
S0604MN1S2
S0604MNJS3
S0309MT1S1
S0309MT1S2
S0309MT1S3
0023MW1S1
0033MW1S1
0033MW1S2
0043MW1D1
0043MW1S1
0043MW1S2
0043MW1S3
0106ME1S1
0146MW1S1
0146MW1S2
0146MW1S3
0319OM1S1
0319OM1S2
0319OM1S3
0102RN1S1
0205RN1S1
'S'.'.patej:^1'
6/10/02
6/10/02
6/10/02
6/11/02
6/1 1/02
6/11/02
6/12/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/9/02
6/9/02
6/9/02
6/10/02
6/10/02
6/10/02
6/12/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02.
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/11/02
6/11/02
rii^fSiv-Br
Analysis
f r;2b"l*Sii-
v,;T-nner5.
913
853
857
833
838
843
954
917
925
929
933
937
941
945
1640
1652
1656
1431
1419
1346
958
1423
1350
1355
1405
1629
1642
1652
1414
1427
1444
849
813
st
Sฃฃฃ32SSSE-
43 U
43 U
43 U
46 U
81 U
1400
34 U
100 U
43 U
44J
43 U
43 U
43 U
43 U
51 U
51 U
51 U
43 U
43 U
43 U
34 U
43 U
78 U
43 U
51 J
43 U
43 U
43 U
43 U
43 U
43 U
46 U
46 U
27 J
54
31 J
53 J
820
1100
38 J
1000
32 J
16 U
30 J
24 J
17 J
17 J
35 U
35 U
35 U
40 J
67
22 J
26 J
140
780
54
24 J
29 J
21 J
16U
48 J
55
30 J
59 J
100
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 37 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location r
403 Riverside Road
209 Riverside Road
604 5lh Avenue East
612 5th Avenue East
620 5lh Avenue East
> ' ' ' " "* *'i " ' ;
Property Typฃ
Residential
Residential
Residential
Residential
Residential
628 5* Avenue East [Residential
63 15th Avenue East Residential
201 Spruce Street
Residential
esidential
213 Spruce Street
403 2nd Avenue West
107 1st Street
Residential
Residential
Residential
Residential
' ' ~, -'
:S;^'ip-;:''j:
S0403RW1S1
S0403RW1S2
S0209RW1S1
S0604SE1S1
S0604SE1S2
S0612SE1S1
S0612SE1S2
S0612SE1S3
S0620SE1S1
S0620SE1S2
S0628SE1S1
S0628SE1S2
S0631SE1S1
S0631SE1S2
S0631SE1S3
S0201SP1D1
S0201SP1S1
S0201SP1S2
S0201SP1S2D
S0201SP1S3
S0210SP1S1
S0210SP1S2
S0211SP1S1
S0211SP1S2
S0213SP1S1
S0213SP1S2
S04032W1D3
S04032W1S1
504032 W1S2
504032W1S3
504032 W1S3R
501071S1S1
501071S1S2
'- Analysis^
^Batfe;"^
6/1 1/02
6/11/02
6/1 1/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/9/02
6/9/02
6/10/02
6/12/02
6/8/02
6/8/02
6/8/02
6/8/02
6/12/02
6/12/02
6/8/02
6/8/02
6/8/02
6/8/02
6/12/02
6/10/02
6/10/02
6/10/02
6/10/02
6/8/02
6/8/02
Analysis
?Tin<:
817
828
822
837
841
824
828
832
816
820
808
812
1701
1704
804
910
1632
1636
1640
1646
853
858
1650
1655
1658
1702
825
949
953
957
1005
1506
1514
,?>,;. A^-jr
'{U*. I? M\"3*-
^$$8?
46 U
46 U
46 U
44J
43 U
43 U
43 U
50 J
43 U
43 U
43 U
43 U
51 U
51 U
43 U
46 J
51 U
51 U
51 U
180
34 U
34 U
51 U
51 U
51 U
51 U
34 U
43 U
43 U
1200
1300
51 U
51U
i,- 1::.*?>^-
*-.;<; '.;-;.- t1 --ji
-W -,i ^v> Zฃ- -,
J-rpVi&tf
,i' "!ฃ&*'*>-
33 J
120
220
29 J
42 J
51 J
20 J
130
16 U
83
44J
26 J
40 J
35 U
340
110
140
26 J
41 J
1700
53 J
39 J
60 J
170
100
89
110
20 J
62
8000
9400
45 J
68 J
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Fmal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VDI
Contract No. 68-W-00-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 38 of 49
TABLE 1
Lead and Arsenic XRF Results (ppra)
Location
202 1" Street
206 1s1 Street
211 1" Street
3102nd A venue East
405 3rd Avenue East
500 3rf Avenue East
5 10 3rd Avenue East
106 3ri Avenue West
206 31" Avenue West
305 3rd Avenue West
:va Horning Park
Jttle Park Open Space
Property Type
Residential
Residential
Residential
Residential
Residential
Residential
Residential
Residential
esidential
Residential
Open Space
pen Space
.C-. v jtflg
S02021S1S1
S02021S1S2
S02061S1D1
S02061S1S1
S02061S1S2
S02061S1S3
S02111S1S1
S02111S1S2
S03102E1S1
S04053E1S1
S04053E1S2
S05003E1S1
S05003E1S2
S05003E1S3
S05003E1S3D
S05103E1S1
S05103E1S2
S01063W1D1
S01063W1S1
S01063W1S2
S01063W1S3
S02063W1S1
02063 W1S2
03053W1S1
03053W1S2
0400EHCC1
0500EHCC1
0500EHSE1
0500EHNE1
0202LPNE1
0202LPNW1
0202LPSE1
0202LPSE1D
. -. ' - < ^y. o i.'t
^-Pai^ffi
6/1/02
6/1/02
6/1/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/12/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/10/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
"A'naiysii
ISIti
1523
1531
942
1543
1551
1559
1607
1616
1619
1623
1628
1118
1122
1126
1130
1134
1138
938
1026
1029
1034
1017
1022
1010
1013
1354
1338
1342
1346
1128
1123
1111
1115
51 U
51 U
34 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
34 U
43 U
43 U
400 U
43 U
43 U
43 U
43 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
iSl
66 J
28 J
43, J
21 J
510
100
110
40 J
59 J
27 J
43 J
35 U
42 J
35 U
35 U
52 J
47 J
29 J
50 J
26 J
4000
16 U
61
54
30 J
21 U
21 U
21 J
21 U
21 U
21 U
21 U
21 U
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFinal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 39 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
''" '-;-.-." ' '."'' '">-' ''?:''- '~>':'
Location : .'':' '
Little Park Open Space
(continued)
VFW Property
Fairgrounds
Elementary School
High School
High School Track (
;C-V- /':,;>
Property Type
Open Space
Open Space
Open Space
Open Space
Open Space
)pen Space
<
c
<
':^p,:''.ip:?-.--i:
S0202LPSW1
S0202LPTC1
SOVFWNW1
S700FGANE1
S700FGANW1
S700FGASE1
S700FGASW1
S700FGCSW1
S700FGCSWX
S700FGCWC1
S700FGCWC1D
S700FGECC1
S700FGGCC1
S700FGGCC1R
S700FGGNE1
S700FGGNW1
S700FGGSE1
S700FGGSW1
S0400EM1S1
S0400EM1S2
S0400EM1S3
S0400EM1S4
S0400EM1S5
S0400HS1S1
S0400HS1S2
S0400HS1S3
S0400HS1S4
50400HS1S5
50400HS1S6
30400HT1S1
50400HT2DC
50400HT2DCB
50400HT2S1
Anaiysis'
--'D&tigjjr
6/8/02
6/8/02
6/7/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/12/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/11/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/1 1/02
6/1 1/02
6/1 1/02
6/11/02
6/11/02
6/11/02
6/9/02
6/9/02
6/10/02
6/9/02
Anaiysis
?:Time^
1119
1131
1431
1358
1402
1411
1407
1424
934
1429
1433
1420
1446
1450
1441
1453
1437
1458
1123
1128
1134
1138
1144
1047
1052
1043
1058
1102
1119
1556
1620
1102
1604
<}.' ;.Vr-7^.;:v;
/ir-ฑV'f%\?
i- ;.: '-3$S*t
^;As^-
51 U
51 U
38 U
51U
51 U
51 U
51 U
1500
790
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
46 U
47 J
46 U
46 U
46 U
46 U
48 J
46 U
46 U
46 U
46 U
51 U
51 U
43 U
51 U
;;--?,rฃv-f^}.-~
;-, .-A-.'ji-j-;-.
ซIISs
21 U
21 U
130
22 J
21 U
36 J
21 J
7700
4000
23 J
31 J
31 J
41 J
35 J
96
34 J
110
24 J
23 U
23 U
23 U
30 J
25 J
23 U
29 J
23 U
27 J
26 J
38 J
35 U
35 U
16 U
35 U
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Fina) SAR\Te*t.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 40 of 49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location
High School Track
(continued)
Westside Field
City Shop
East of River Street and
ohnson Lane
Property Type
Open Space
Open Space
Open Space
Open Space
;^m^
S0400HT2S2
S0400HT2S3
S0400HT2S4
S0400HT3S1
S0400HT4D1
S0400HT4D2
S0400HT4D3
S0400HT4S1
S0400HT4S1D
S0800WFBE1
S0800WFBW1
S0800WFNE1
S0800WFNW1
S0800WFSE1
S0800WFSW1
S0800WFSE1D
SOCTYSH1D1
SOCTYSH1S1
SOCTYSH1S2
SOCTYSH1S3
SOCTYSH1S4
SOCTYSH1S5
S1RSOSCCS1
1RSOSNES1
1RSOSNWS1
1RSOSSES1
1RSOSSSS1
1RSOSSWS1
':V,v'Sj4'-- -.fgTi!
r-.r. BairK-
6/9/02
6/9/02
6/9/02
6/9/02
6/10/02
6/10/02
6/10/02
6/1 1/02
6/11/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/12/02
6/10/02
6/10/02
6/10/02
6/12/02
6/12/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
6/8/02
Analyst!
-'T&ฃ?
vlimejr
1608
1612
1616
1623
1050
1054
1058
1149
1200
1314
1318
1310
1305
1236
1302
1240
913
1440
1449
1452
922
917
1740
1722
1710
1719
1121
1707
MR
tffSgAsjSfl?
51 U
51 U
51 U
51 U
190 U
630
370
1700
1800
51 U
51 U
51 U
51 U
51 U
51 U
51 U
34 U
SOU
67 U
43 U
34 U
34 U
51 U
51 U
58 J
51 U
51 U
51 U
*^piป^
HSJrBJKfia:
46 J
35 J
35 U
130
1900
4400
1100
9000
9200
41 J
21 U
21 U
21 U
21 U
21 U
21 U
23 U
500
670
250
110
84
160
490
120
47 J
27 J
74
TDD No. 0203-0008
P:\Start2\Superior Waste RockXFmal SARYText.wpd
-------
I
I
I
I
I
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 41 of49
TABLE 1
Lead and Arsenic XRF Results (ppm)
Location ;.; v> ::- :^':T-;-V ,""
SW Corner of River Street
and Johnson Ave.
' 'f - ซ" ' " -".*-
'^'--:":v-^
Property Type
Open Space
:3PH. ~*M
ฃ.-*,, IK//-;
S2RSOSCCS1
S2RSOSNES1
S2RSOSNWS1
S2RSOSSES1
S2RSOSSWS1
S2RSOSSWS1B
'/rAnalysis;?;
^tisfaf:.j*!
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
6/9/02
Analysis
^Timฃ.^
1105
1053
1058
1102
1110
1114
Wf&*ฃ3.&*
t -v?,1, -r^ -, .-KX.
;a^-Ji-*.s4-^
:ฃj;^*A$?ฃ^
51 U
95 J
51 U
51U
51 U
51 U
Pi|^ฃ
:3Wi&:
150
200
82 J
82 J
35 U
35 U
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Fmal SARXText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-118
TABLE 2
Laboratory and XRF Results (ppm)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 42 of 49
Sample ID
S0200CEEA1B
S0201SP1S3
S02021S1S2
S0202CE1S1
S0205AL1S2
S02061S1S2
S02063W1S2
S0208CEIS1
S0208MN1S2
S0208MN1S3
S0209RW1S1
S02111S1S1
S0213SP1S2
S0225FC1S2
S03003ESD1
S03003SED1
S0300SPEC1
S0306AR1S3
S0311MA1S2
S0400EM1S1
Arsenic
Lab
0.41 U
190
3.7
5.7
6.6
5.7
6.5
5.4
127
2620
26.3
6.9
9.2
362
10.6
3.8
6.2
22
5.7
4.6
XRF
38 U
180
51 U
51 U
51 U
51 U
43 U
51 U
81 U
1400
46 U
51 U
51 U
300
54 J
46 U
51 U
51 U
51 U
46 U
RPD
NA
5
NA
NA
NA
NA
NA
NA
NA
61
NA
NA
NA
19
NA
NA
NA
NA
NA
NA
'Antimony .
Lab
O.J6 U
173
0.99 U
1.2
0.35 U
1.4
0.95 U
1.8
44.6
2360
5.7
2.1
2.5
63.5
2.4
1.2
0.68 U
1.5
1 U
0.4 U
XRF
51 U
560
45 U
66 U
66 U
45 U
62 U
66 U
79 J
2500
75 U
45 U
45 U
160 J
60 U
75 U
45 U
66 U
66 U
75 U
RPD
NA
106
NA
NA
NA
NA
NA
NA .
NA
6
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
' Lead
Lab
0.38
1620
31.9
54.8
14.6
523
59.7
47.1
959
16700
216
89.1
82.1
1680
48.1
209
27.1
179
31.1
11.3
XRF
24 U
1700
28 J
71 J
35 U
510
61
66 J
820
11000
220
110
89
1600
44 J
240
31 J
180
36 J
23 U
RPD
NA
4.82
NA
NA
NA
3
2
NA
16
41
2
21
8
5
NA
14
NA
1
NA
NA
i? ,'ir"'li' ".'-". -- '>''* ' -i '-- ::
. -.--:* r,vZinc:^.;r: ;ฃ'-:-- *''?
Lab
0.14 U
804
69.6
89.9
46.5
1130
99.9
121
443
6170
267
141
105
1470
79
80.2
35.3
123
67.3
34.5
.1- ;-"< ..J, ".',;ฃ.
XRF ':,--
59 U
950
130 J
200
59 J
1200
180 J
230
420
3700
330
270
200
950
83 J
120 J
100 J
130 J
170
86 J
W-- - ',^.'-
vj RPD:
NA
16.648
NA
76
NA
6
NA
62
5
50
21
63
62
43
NA
NA
NA
NA
87
NA
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
TABLE 2
Laboratory and XRF Results (ppm)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 43 of 49
Sample ID
S0400HT2DCB
S0400HT4D1
S0400HT4D2
S0400HT4D3
S0407IH1D1
S0407IM1S1
S05002WNC1
S0500MN1S1
S06004AMD1
S06005AMD1
S06005ENR1
S06005ESO1
S0612SE1S3
S06154E1S3
S0800RVSF1
SOCTYSH1S1
SOCTYSH1S2
S1RSOSNES1
S700FGCSW1
Arsenic
Lab
0.43 U
250
957
300
166
296
3.1
175
7.5
8.5
15.5
4.6
15.4
8.1
2.8
42.4
54
91.9
1910
XRF
43 U
190 U
630
370
110 J
170 U
46 U
100 U
36 U
23 U
32 J
36 U
50 J
51 U
51 U
50 U
67 U
51 U
1500
RPD
NA
NA
41
21
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
- NA
NA
NA
24
Antimony
Lab
0.24 U
136
399
67.6
63.6
84.4
0.47 U
48.6
0.74 U
0.6 U
5.3
0.38 U
4.5
1.1
0.33 U
24.1
39.3
13.6
1160
XRF
62 U
310
1000
200 J
85 J
160 J
75 U
110 J
60 U
50 U
50 U
60 U
62 U
66 U
45 U
77 J
130 J
45 U
1100
RPD
NA
78
86
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA '
NA
NA
NA
NA
NA
5
Lead
Lab
2.4
2140
5070
1120
757
1770
130
1020
15.8
27.6
101
7.6
125
38
12.3
433
689
534
9360
XRF
16 U
1900
4400
1100
820
1700
160
1000
36 U
39 J
110
36 U
130
41 J
21 U
500
670
490
7700
RPD
NA
12
14
2
8
4
21
2
NA
NA
9
NA
4
NA
NA
14
3
9
19
Zinc ;
Lab
2.7
1860
2860
348
7040
910
29.9
926
33.8
42.6
83
19.3
215
57
29.9
1010
698
1170
6790
XRF
68 U
1700
2400
410
9800
1000
72 U
760
40 J
92 J
120 J
86 J
250
130 J
44 J
1200
760
1200
4100
RPD
NA
9
17
16
33
9
NA
20
NA
NA
NA
NA
15
NA
NA
17
9
3
49
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARVText.wpd
r'ป-;.i
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
TABLE 2
Laboratory and XRF Results (ppm)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 44 of 49
..--''' '"'.. - * '
Sample ID
S700FGCSWX
S03190M1S2
S04002WNA1
S04002WSD1
S04003ESE1
S0043MW1S2
S01007SWB1
S01063W1D1
S0106CE1S3
S01071S1S1
S02003ESD1
S0200CEEG1
S0200MNSDX
S0200MNSG1
S0400HT4S1
S0400ILEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
Arsenic
Lab
918
8.6
3
153
286
58.2
2.7
4.6
6.3
4.2
5.5
32.9
9
61.8
2110
5
7.1
582
2.8
XRF
790
43 U
46 U
100 J
220 U
78 U
51 U
34 U
51 U
51 U
38 U
38 U
34 U
54 U
1700
46 U
38 U
400
34 U
RPD
15
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
22
NA
NA
37
NA
Antimony ; . ; -
Lab
289
0.91 U
0.71 U
47.5
108
27.7
[0.29]
1.1
[0.39]
[0.92]
1
10.8
2.8
23.3
1450
[0.93]
0.99
145
[0-61]
XRF
720
62 U
75 U
130 J
250
120 J
45 U
62 U
66 U
45 U
51 U
51 U
62 U
51 U
1700
75 U
51 U
280
62 U
RPD
85
NA
NA
NA
79
. NA
NA
NA
NA
NA
NA
NA
NA
NA
16
NA
NA
64
NA
Lead
Lab
4580
51
323
866
2130
706
7.8
29.1
12.4
46.3
31.1
258
47.7
587
10700
44.5
41.9
2320
9.9
XRF
4000
55
350
770
2200 .
780
21 U
29 J
35 U
45 J
24 U
270
53 J
540
9000
49 J
41 J
1800
23 U
RPD
14
8
8
12
3
10
NA
NA
NA
NA
NA
5
NA
8
17
NA
NA
25
NA
-' ',.:' ''' ^^'-Ziii^-'k-''--'-'''^^.^1
Lab
7300
67.6
84.3
828
2550
522
38.5
71.9
34.4
97.2
40.7
189
999
724
3820
44.3
66.2
2660
29.2
' XFLFrV'":.'.
6600
100 J
100 J
760
2800
560
92 J
130 J
72 J
150
100 J
170 J
980
720
3400
72 U
120 J
1700
94 U
;RPD 0
10
NA
NA
9
9
7
NA
.NA
NA
43
NA
NA
2
1
12
NA
NA
44
NA
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Final SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-00-1I8
TABLE 2
Laboratory and XRF Results (ppm)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 45 of 49
Sample ID
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWFI
S04032W1S3
S0404AL1S3
Arsenic
Lab
157
56.1
207
68.1
1540
3.6
XRF
67 U
170
150
44 U
1200
51 U
RPD
NA
101
32
NA
25
NA
Antimony
Lab
41.6
23.5
53.8
25.6
955
[0.91]
XRF
75 J
60 U
160 J
100 J
1500
66 U
RPD
NA
NA
NA
NA
44
NA
Lead
Lab
767
352
1150
468
8530
55.8
XRF
670
270
1300
440
8000
78 J
RPD
14
26
12
6
6
NA
Zinc
Lab
909
1460
1010
693
3040
85.1
XRF
820
390
1000
780
2700
130 J
RPD
10
116
1
12
12
NA
U The analyte was not detected at reported concentrations
J The associated numerical value is an estimated quantity because quality control criteria were not met
1 ] The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of compound is reliable
RPD Relative Percent Difference (%)
TDD No. 0203-0008
P:\Start2\Superior Waste RockXRnal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-00-118
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 46 of 49
Table 3
Estimated Volume of Elevated Metals Material
^ocation
Residential Properties
43 Mullan Road
106 3"1 Avenue West
201 Spruce
206 Ist Street West
208 Main Street
225 Flat Creek Road
403 2nd Avenue West
407 Iron Mountain Height
XRF Sample Results
Size/Volume Estimates
Comments ',"i\' ''.. ^.^''^:^*0*-(Z^ฃ^&ฃ&
Pb = 780 ppm
As = 78 U ppm
Sb= 120 J ppm
Pb = 4,000 ppm
As = 400 U ppm
Sb = 510ppm
Pb= 1,700 ppm
As= 180 ppm
Sb = 560 ppm
Pb = 510ppm
As = 45 U ppm
Sb = 45 U ppm
Pb = 1 1 ,000 ppm Pb = 820 ppm
As =1,400 ppm As = 81 U ppm
Sb = 2,500 ppm Sb = 79 J ppm
Pb= 1,600 ppm
As = 300 ppm
Sb= 160 J ppm
Pb = 8,000 ppm
As= 1,200 ppm
Sb= 1,500 ppm
Surface Depth
Pb = 1 ,700 ppm Pb = 820 ppm
As = 170 U ppm As=110Jppm
Sb=160Jppm Sb = 85Jppm
50'x25'x3"
11.5 cu.yds.
75' x 15' x 6"
21 cu. yds.
50'x6"x2"
0.1 5 cu.yds.
NA
NA
10'xlO'x?
75' x 15' x 6"
21 cu.yds.
30'x6'x 1.5'
10 cu.yds.
Area behind house has large rocks (waste rock) which are mixed with
the soil. Appears to be slope stabilization (slope to the Clark Fork
River). Removal of material would be difficult because of
slope/stabilization.
Driveway appears to have coarse grained tailings. Approximately 2"
of topsoil covering tailings 4"-6" thick.
Very fine, powdery tailings material under the back fence line only.
Homeowner specified tailings are 4-6" in width and approximately 2"
in depth for grass suppression under the fence.
Side yard composite sample was initially 510 ppm for lead. Return
trip did not locate any tailings. Depth sample collected was low for
lead (43 J ppm) and arsenic (34 U ppm). Side yard is 4' x 25'.
Forest Service house. Two locations on surface had high
concentrations. Depth samples and volume estimates were not
collected because the Forest Service will complete this location.
Sample was located between the house and a shed. The tailings are
covered by approximately 5" of topsoil. The depth of the tailings was
never determined. The area of tailings is at most 10' by 10' and
probably smaller.
Right of Way / Parking area in front of residence. The previous owner
placed approximately 1 pick up load of tailings in a low spot to bring
the parking area to grade.
Tailings are located on a benched area behind the house. Tailings are
covered by approximately 4" of topsoil. Visible tailings are
approximately 2" thick; however, a sample collected at 1 foot bgs
(depth results) are still elevated.
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Final SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-00-1I8
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 47 of 49
Table 3
Estimated Volume of Elevated Metals Material
x>cation
500 West Main Street
XRF Sample Results
Surface Depth
Pb = 1 ,000 ppm Pb = 38 J ppm
As = 100 U ppm As = 34 U ppm
Sb = 1 10 J ppm Sb = 62 U ppm
Size/Volume Estimates
50'xlO'x 1'
19 cu.yds.
Comments
Tailings are mixed in with the soil in the side yard. Tailings were
originally part of the driveway. Owner excavated the parking area and
placed material on the side yard. Later rototilled into the existing soil.
Tailings are not readily visible. Depth sample at 1* is clean.
City/County Properties
High School Track
Arizona Avenue
"airground
Between Pennsylvania Avenue
and Arizona Avenue
City Shop
Mullan Road West
Pb = 423 ppm - 9,000 ppm
As = 79 ppm - 1,700 ppm
Sb = 35ppm- 1,700 ppm
Surface Depth
Pb = 7,700 ppm Pb = 4,000 ppm
As = 1 ,500 ppm As = 790 ppm
Sb= 1,100 ppm Sb = 720ppm
Surface 1 Surface 2
Pb = 500 ppm Pb = 670 ppm
As = 50 U ppm As = 67 U ppm
Sb = 77 J ppm Sb = 130 J ppm
1400' x 40' x 1.5'
3,1 11 cu.yds.
25'x25'x 1.5'
150' x 50' x 6"
Total: 175 cu.yds.
8" x 250' x 15'
8"x75'x 15'
Total: 120 cu.yds.
Results are from this sampling event and last years sampling event.
The surface collected west of the track had elevated concentrations All
other samples in the vicinity of the track (and on the football field)
were below lOOppm arsenic and 500 ppm lead. Volume of track
material is based on the size of the track to a depth of 18 inches.
The fairground was split into two areas with elevated metals cone.
These include the base of the stairs leading to the corals and the coral
area. The coral area contained red material under the fence; however,
the total area was used for volume estimates.
Road base from both roads at the city shop had elevated results.
Material appeared to be 6-8" thick. A depth sample collected from the
road base had low cone.
Right of Way Locations
200 block of Main Street
400 block of 2'"1 Avenue West
400 block of 3"1 Avenue East
Pb = 540 ppm
As = 54 U ppm
Sb = 51Uppm
Surface Depth
Pb = 8,000 ppm Pb = 770 ppm
As = 1 ,200 ppm As = 100 J ppm
Sb = 1 ,500 ppm Sb = 1 30 J ppm
Pb = 2,200 ppm
As = 220 U ppm
Sb = 250 ppm
15'x5'x2"
0.5 cu.yds
25'x25'x 1.5'
35 cu.yds.
25'x5'x3"
1.2 cu.yds.
Tailings were localized and covered by approximately 4" of topsoil.
The tailings were approximately 2" thick.
Tailings were used to fill a low spot in the right of way (parking area).
Tailings were residual from fill used on right of way. Majority of the
tailings have been removed since sampling that occurred last year.
TDD No. 0203-0008
P:\Start2\Superior Waste Rock\Rnal SARVText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-l 18
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 48 of 49
Table 3
Estimated Volume of Elevated Metals Material
Location ,
400 block of Spruce Street
Pine Street Alley
XRF Sample Results '! ! .',>;
Pb = 270ppm - 1,800 ppm
As = 67 U ppm - 400 ppm
Sb = 60 U ppm - 280 ppm
Pb = 230 ppm
As = 1 10 J ppm
Sb = 60 U ppm
Total Volume Estimate:
Size/Volume Estimates
200'x5'x2"
6 cu.yds.
NA
3,530 cu.yds. in place
Comments ^\;--'>V\ '; ''(':/. i'^'x ?"s; '.ฃ*! ^?^-^ฃ^>ฃ
Tailings were visible closer to the sidewalk than the road. The tailings
appear to be a thin lense under a couple inches of clean fill.
Although the arsenic is slightly elevated, the lead concentration is low
and addition samples were not collected.
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFinal SARYText.wpd
-------
URS Operating Services, Inc.
START2, EPA Region VIII
Contract No. 68-W-OO-118
TABLE 4
TCLP Results (mg/L)
Superior Waste Rock - SAR
Revision: 0
Date: 08/2002
Page 49 of 49
Sample ID
Regulatory
S0201SP
S0208MN
S0400HT
S0700FG
Arsenic
5
[0.0391]
[0.0023]
[0.023]
[0.126]
Barium
1000
[0.367]
[0.301]
[0.471]
[0.161]
Cadmium
1
[0.0339]
[0.253]
[0.44]
[0.377]
Chromium
5
[0.006]
[0.125]
[0.003]
[0.004]
Lead
5
140
107
36.7
483
Mercury
0.2
[0.0018]
[0.0011]
0.0001 U
[0.00022]
Selenium
1
0.0095 U
0.0 109 U
0.01 24 U
0.01 19 U
V";%serO-v
5
[0.0059]
0.0005 U
0.0005 U
0.0005 U
U The analyte was not detected at reported concentrations
J The associated numerical value is an estimated quantity because quality control criteria were not met
[ ] The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of compound is reliable
TDD No. 0203-0008
P:\Start2\Superior Waste RockVFmal SARYText.wpd
-------
APPENDIX A
Photolog
-------
PHOTO 1
START2 personnel using the GPS to document sample location.
PHOTO 2
START2 personnel collecting a soil sample under the vegetative cover.
TDD No. 0203-0008
P:\Slarl2\Supcrior Waste RockVPhotoTxt.wpd
-------
PHOTO 3
START2 personnel collecting a soil sample in a residential driveway.
PHOTO 4
Tailings material in the right of way at 2"d Avenue West.
TDD No. 0203-0008
P:\Starl2\Supcrior Waste RockXPhotoTxt.wpd
-------
I
I
I
PHOTO 5
Tailings material under a fence at 201 Spruce Street.
TDD No. 0203-0008
P:\Start2\Superior Waste RockNPhotoTxt.wpd
-------
APPENDIX B
Validation Reports and Laboratory Data
-------
TABLE1A
SUPERIOR WASTE ROCK
CONFIRMATION RESULTS (PPM)
ID
S0200CEEA1B
S0201SP1S3
S02021SIS2
S0202CE1S1
S0205AL1S2
S0206IS1S2
S02063W1S2
S0208CE1S1
S0208MN1S2
S0208MN1S3
S0209RW1SI
S02H1SIS1
S0213SP1S2
S0225FC1S2
S03003ESD1
S03003SED1
S0300SPEC1
S0306AR1S3
S0311MA1S2
S0400EM1S1
S0400HT2DCB
S0400HT4D1
S0400HT4D2
S0400HT4D3
S0407IH1D1
S04071M1S1
S05002WNC1
S0500MN1S1
S06004AMD1
S06005AMD1
S06005ENRI
S06005ESO1
S0612SE1S3
Sb
0.16 U
173
0.99 U
1.2
0.35 U
1.4
0.95 U
1.8
44.6
2360
5.7
2.1
2.5
63.5
2.4
1.2
0.68 U
1.5 U
1
0.4 U
0.24 U
136
399
67.6
63.6
84.4
0.47 U
48.6
0.74 U
0.6 U
5.3
6.38 U
4.5
As
0.41 U
190
3.7
5.7
6.6
5.7
6.5
5.4
127
2620
26.3
6.9
9.2
362
10.6
3.8
6.2
22
5.7
4.6
0.43 B
250
957
300
166
296
3.1
175
7.5
8.5
15.5
4.6
15.4
Ba
0.28 U
140
115
121
106
259
72.5
136
103
48.5
176
485
129
126
98.2
101
99.9
97.5
171
113
0.25 U
149
102
116
475
413
119
103
60.2
84.1
89.1
87.3
217
Cd
0.03 U
3.3
0.42 B
0.16 U
0.03 U
2.2
0.3 B
0.18 U
2.6
30.1
1.2
o.nu
0.29 B
9.6
0.15 U
O.I2U
0.03 U
0.05 U
0.03 U
0.03 U
0.03 U
8.7
14.5
1.9
4
5.1
0.03 U
5.3
0.03 U
0.03 U
0.12 U
0.03 U
0.34 B
Ca
29.4 1
7330
1900
2850
3340
1850
6110
4040
2680
1070
12200
6920
3770
3100
5470
2860
9400
5140
3620
2620
30.1 U
7280
8510
19900
16700
7380
9490
4340
9710
18400
2610
8100
2990
CrHI
0.18 U
7.3
9.8
7.9
7.9
9.3
6.2
7.1
6.9
3.4
8.2
9.1
7
5.1
6.3
7
7.2
8.5
8.3
6.1
0.19 U
6.3
4.4
5.3
7.7
16.3
34.3
7.5
7.3
5.4
7.5
6.1
7.7
Be
0.02 U
0.34 U
0.36 B
0.41 B
0.4 B
0.33 U
, 0.24 U
0.35 U
0.33 U
0.21)
0.44 B
0.58
0.36 B
0.33 U
0.31 U
0.31 U
0.23 U
0.32 U
0.48 B
0.41 B
0.02 U
0.36 B
0.29 U
0.29 U
0.68
0.58
0.29 U
0.28 U
0.33 U
. 0.29 U
0.35 U
0.32 U
0.4 U
Co
0.06 U
3.6
3.5
4
6.1
3.7
4.3
3.6
3.5
3.6
4.7
4.4
3.7
3.5
3.3
3.9
3.5
4.2
5.6
4.5
0.06 U
4.4
3.9
3.9
3.8
5.6
4.1
3.5
4.1
4.6
3.8
4.1
5.4
Cu
0.3 B
27.3
11.9
13.7
16.6
10.8
16
12.1
14.1
85.4
18.3
25.3
18.9
20.1
10.3
14.2
10.4
13.8
17.2
14.4
0.24 B
26.3
38.9
19.5
33.1
78.7
10.2
15.9
12.4
16
14.1
12.1
19.4
Fe
56.1
11400
8860
11000
10100
8660
8800
9950
11200
63200
10900
12800
9560
18900
8370
9210
7720
10400
13200
13200
63.7
20000
32600
15100
19100
19700
7640
12200
10700
10100
12000
9110
10400
Pb
0.38
1620
31.9
54.8
14.6
523
59.7
47.1
959
16700
216
89.1
82.1
1680
48.1
209
27.1.
179
31.1
11.3
2.4
2140
5070
1120
757
1770
130
1020
15.8
27.6
101
7.6
125
Mn
1.2
364
222
370
297
297
217
350
348
1600
355
274
342
810
220
244
196
372
547
393
2.1
1470
1870
591
838
940
218
433 .
237
231
357
220
301
U - The analyte was not detected above the detection limit. The detection limit is reported. Page 1 of 2
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
UJ - The associated numerical value is an estimated quantity because quality criteria were not met. The analyte was not detected
B - The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of the compound is reliable
-------
TABLE1A
SUPERIOR WASTE ROCK
CONFIRMATION RESULTS (PPM)
ID
S06154E1S3
S0800RVSF1
SOCTYSH1S1
SOCTYSH1S2
S1RSOSNES1
S700FGCSW1
S700FGCSWX
S0319OM1S2
S04002WNA1
S04002WSD1
S04003ESEI
S0043MW1S2
S01007SWB1
S01063W1D1
S0106CE1S3
S01071SIS1
S02003ESD1
S0200CEEG1
S0200MNSDX
S0200MNSG1
S0400HT4S1
S0400ILEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWF1
S04032W1S3
S0404AL1S3
Sb
i.l
0.33 U
24.1
39.3
13.6
1160
289
0.91 U
0.71 U
47.5
108
27.7
0.29 B .
1.1
0.39 B
0.92 B
1
10.8
2.8
23.3
1450
0.93 B
0.99
145
0.61 B
41.6
23.5
53.8
25.6
955
0.91 B
As
8.1
2.8
42.4
54
91.9
1910
918
8.6
3
153
286
58.2
2.7
4.6
6.3
4.2
5.5
32.9
9
61.8
2110
5
7.1
582
2.8
157
56.1
207
68.1
1540
3.6
Ba
88.1
121
189
US
109
29.5
98.9
114
116
91.4
110
108
104
176
163
146
81.3
88.5
81.7
91.4
30.5
87.7
85.3
74
94.8
71.7
80.3
104
60.2
70.3
109
Cd
0.03 U
0.03 U
3.4
3.8
5.3
40.4
46.3
0.24 B
0.08 B
4.8
16.2
4
0.03 U
0.03 U
0.03 U
0.06 U
0.03 U
0.74
7.6
3.7
27.4
0.03 U
0.03 U
14.4
0.03 U
4.4
7.6
4.3
3.3
20.4
0.11 U
Ca
16800
4810
4750
4190
15500
2610
13200
8330
7690
2110
3450
4820
3190
2470
30100
4240
4000
4320
780
3480
1260
6930
4900.
6920
1510
5840
12500
4700
1610
3340
2340
CrHI
7.5
6.3
7.9
6.9
9.7
1.5
5.8
9
6.7
7.3
9.3
6.6
6.6
7.1
8
7.3
6.6
8.3
6.6
8.1
1.7
10.5
7.7
7.2
6.2
8.3
8.2
13.3
5.8
4.4
7.9
Be
0.3 U
0.31 U
0.42 B
0.4 U
0.37 U
0.131)
0.32 U
0.35 B
0.29 B
0.46 B
0.35 B
0.39 U
0.36 U
0.47 B
0.55
0.35 U
0.31 U
0.3 U
0.36 U
0.3 U
0.18 U
0.35 U
0.3 U
0.29 U
0.36 U
0.41 U
0.31 U
0.45 B
0.33 U
0.24 U
0.35 U
Co
4.9
4.3
3.6
4
5.1
1.1 J
3.8
4.4
3.4
4.9
4.2
4
4.8
3.9
5.6
3.6
3.5
3.8
3.3
3.7
1.7
3.5
4.1
3.5
3.4
4.6
3.6
4.6
3.4
3.4
3.6
Cu
21
9.8
32.1
28.2
32.1
102
39
34.2
26.5
32.8
42.6
19.1
9.1
9.4
26.1
14.9
9.3.
15
7.9
18.4
70.4
14.8
11.6
28.6
8.6
20.6
12.7
22.4
12.1
57.6
14.5
Fe
10100
8940
10300
11400
15200
64800
30100
10200
7950
15000
22000
11700
8980
12600
12500
9050
9090
10200
10800
12400
55500
9580
8590
27900
9240
19000
12000
17800
10900
42100
9570
Pb
38
12.3
433
689
534
9360
4580
51
323
866
2130
706
7.8
29.1
12.4
46:3
31.1
258
47.7
587
10700
44.5
41.9
2320
9.9
767
352
1150
468
8530
55.8
Mn
222
271
355
352
525
4250
2490
298
276
501
996
354
206
516
375
307
173
261
213
369
3060
192
317
1260
188
661
370
651
296
2680
311
1) - The analyte was not detected above the detection limit. The detection limit is reported. ~ Page 2 of 2
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
UJ - The associated numerical value is an estimated quantity because quality criteria were not met. The analyte was not detected
B - The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of the compound is reliable
-------
TABLE IB
SUPERIOR WASTE ROCK
CONFIRMATION RESULTS (PPM)
ID
S0200CEEA1B
S0201SP1S3
S02021S1S2
S0202CE1S1
S0205AL1S2
S02061S1S2
S02063W1S2
S0208CE1S1
S0208MN1S2
S0208MN1S3
S0209RW1S1
S02111S1S1
S0213SP1S2
S0225FC1S2
S03003ESD1
S03003SEDI
S0300SPEC1
S0306AR1S3
S0311MA1S2
S0400EM1S1
S0400HT2DCB
S0400HT4D1
S0400HT4D2
S0400HT4D3
S0407IH1D1
S0407IM1S1
Mg
17.3 U
2420
2830
2880
3430
2580
3400
2960
3290
1720
3610
3810
3130
3020
3150
3260
4070
4750
3570
3390
20.6 B
3940
4120
6840
2880
3320
Na
155 B
14.3 U
113B
128 B
102 B
14.4U
163 B
109 B
14.3 U
292 U
162 B
392
131 B
14.6U
115B
121 B
98.9 B
111B
119B
120 B
HOB
14.4U
14.3U
26.1 B
286 U
165 B
Ni
0.1 U
5.5
6
7.1
6.7
6.1
1.3
5.7
5.7
6.2
7
10.2
7
6.3
5.8
7.2
6.5
7.5
8.4
7.3
0.09 U
6.8
. 5.8
6.2
8
12.7
K
7.8 U
1220
1780
1670
1380
1200
1HO
1260
1150
749
1120
1290
1310
1290
997
1570
992
1370
1250
1190
9.1 U
1250
1050
1040
1180
1790
Se
0.21 U
0.37 B
0.3 B
0.26 B
0.49
0.48 B
0.36 B
0.46 B
0.39 B
2.3
0.53
0.59
0.4 B
0.94
0.24 B
0.23 B
0.21 U
0.36 B
0.66
0.45 B
0.21 U
1.1
.1-5
0.55 .
1.3
0.94
Ag
0.07 U
7.6
0.07 U
0.07 U
0.07 U
0.12 B
0.1 B
0.36 B
11.4
191
0.65
0.15 B
0.29 B
14.8
0.19 B
0.07 U
0.07 U
1.1
0.07 U
0.07 U
0.07 U
25.7
43.3
9.5
6.1
16.1
Th
0.32 U
0.32 U
0.33 U
0.32 U
0.32 U
0.33 U
0.33 U
0.33 U
0.32 U
2.5 J
0.33 U
0.32 U
0.33 U
0.33 U
0.32 U
0.32 U
0.32 U
0.33 U
0.32 U
0.33 U
0.32 U
0.33 U
0.32 U
0.32 U
0.32 U
0.32 U
V
0.13 U
12.2
10.6
14.5
9.8
12.3
8.6
12.9
9.8
5
10
19.8
10.8
11.1
9.2
U.I
7
8.6
17.5
10.6
0.19 U
10.5
7.8
10.2
18
26
Zn
0.14 UJ
804
69.6
89.9
46.5
1130
99.9
121
443
6170
267
141
105
1470
79
80.2
35.3
123
67.3
34.5
2.7
1860
2860
348
7040
910
U - The analyte was not detected above the detection limit, the detection limit is reported. Page 1 of 3
1 - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
UJ - The associated numerical value is an estimated quantity because quality criteria were not met. The analyte was not detected
B - The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of the compound is reliable
-------
TABLE IB
SUPERIOR WASTE ROCK
CONFIRMATION RESULTS (PPM)
ID
S05002WNCI
S0500MN1S1
S06004AMD1
S06005AMD1
S06005ENRI
S06005ESO1
S0612SE1S3
S06154E1S3
S0800RVSF1
SOCTYSH1S1
SOCTYSH1S2
S1RSOSNES1
S700FGCSW1
S700FGCSWX
S0319OM1S2
S04002WNA1
S04002WSD1
S04003ESE1
S0043MW1S2
S01007SWB1
S01063W1D1
S0106CE1S3
S01071SIS1
S02003ESD1
S0200CEEG1
S0200MNSDX
Mg
4570
2760
6150
5460
4590
4750
4220
3790
4000
3360
3500
6480
2610
6290
4430
4220
2770
4130
3240
3560
2710
9620
2990
3210
4020
2760
Na
104B
14U
119B
118 B
206
109 B
157 B
154 B
91.1 B
14.3U
14.4 U
14.3U
289 U
286 U
176 B
190 B
1590
4110
14.3 U
95.6 U
104U
128 U
119U
124 U
142 U
14.4 U
Ni
7.1
5.9
7.2
7.5
7.6
7.1
6.8
8.4
5.9
6.4
6.6
9.1
3.4
.7
7.5
6.2
7.3
9
6.5
6
6.3
8.4
5.8
5.6
7.4
5.3
K
964
966
1180
1230
1410
1080
1000
1100
1380
1730
1540
1760
522
1150
1580
1490
1230
1280
1680
1320
1780
1970 .
1800
1140
1370
1250
Se
0.21 U
0.5
0.22 U
0.21 U
0.41 B
0.32 B
0.22 U
0.27 B
0.25 B
0.5
0.33 B
0.46 B
3.1
1.6
0.3 B
0.29 B
0.37 B
0.79
0.52 U
0.5 1 U
0.53 U
0.21 U
0.42 U
0.35 U
0.45 U
0.47 U
Ag
0.07 U
8.2
0.07 U
0.07 U
0.62
0.07 U
0.86
0.07 B
0.07 U
2
5.5
2.8
79.9
42
0.05 U
0,05 U
7.6
16.5
6.5
0.28B
0.07 U
0.07 U
0.07 U
0.07 U
1.8
0.24 B
Th
0.32 U
0.32 U
0.32 U
0.32 U .
0.33 U
0.33 U
0.33 U
0.32 U
0.32 U
0.32 U
0.33 U
0.32 U
6.4
1.4J
0.22 UJ
0.21 UJ
0.21 UJ
0.21 UJ
0.32 U
0.33 U
0.32 U
0.32 U
0.32 U
0.33 U
0.32 U
0.33 U
V
6.6
8.9
7.4
7.8
8.6
8.6
9.3
9.6
9.5
11
11.6
11.9
2.5
7.8
9.8
8.8
9.4
10.8
11.8
10.1
17.7
12.7
11.3
11.7
10.2
17
Zn
29.9
926
33.8
42.6
83
19.3
215
57
29.9
1010
698
1170
6790
7300
67.6
84.3
828
2550
522
38.5
71.9
34.4
97.2
40.7
189
999
U - The analyte was not detected above the detection limit, the detection limit is reported. Page 2 of 3
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
UJ - The associated numerical value is an estimated quantity because quality criteria were not met. The analyte was not detected
B - The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of the compound is reliable
-------
TABLE IB
SUPERIOR WASTE ROCK
CONFIRMATION RESULTS (PPM)
ID
S0200MNSG1
S0400HT4S1
S0400ILEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWF1
S04032W1S3
S0404AL1S3
Mg
4100
1970
4700
4290
4420
2730
4410
5470
4970
2640
2390
2760
Na
14.2U
289 U
105 B
93.4 B
14.4U
107 B
14.3 U
14.2U
468
HU
71.5 -U
76.7 U .
Ni
8
3.5
6.9
7.1
7.6
5.6
7.8
7
9.3
5.5
5
6.5
K
1100
529
1260
1090
1220
1360
1240
1420
1810
982
851
1210
Se
0.66 U
2.6
0.67
0.34 U
1.4 U
0.32 U
0.86 U
0.49 U
0.91 U
0.52 U
2.7
0.61 U
Ag
3.5
100
0.07 U
0.07 U
18.2
0.07 U
4.2
2
9.1
2.7
81.4
0.07 U
Th
0.32 U
4.8
0.32 U
0.32 U
0.33 U
0.33 U
0.32 U
0.32 U
0.32 U
0.32 U
2.6
0.32 U
V
10.1
3.6
10.9
8.7
7.9
11.7
9.9
7.5
10.9
8.3
6.7
12.9
Zn
724
3820
44.3
66.2
2660
29.2
909
1460
1010
693
3040
85.1
U - The analyte was not detected above the detection limit, the detection limit is reported. Page 3 of 3
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit. .
UJ - The associated numerical value is an estimated quantity because quality criteria were not met. The analyte was not detected
B - The associated numerical value was detected below the CRDL, but greater than the method detection limit and is therefore an estimate. Presence of the compound is reliable
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Data Validation Report
REGION VIII
DATA VALIDATION REPORT
INORGANIC
0203-0008
Tien Nguyen
''
CompuChem-Liberty
Superior Waste Rock
Not Indicated
R2589
Review Assigned Date July 5. 2002
Bill Fear
Review Completion Date July 19. 2002
_Data Validator.
_Report Reviewer Ken Schroeder
Sampie'Number
S0407IH1D1
S0407IM1S1
S05002WNC1
S0500MN1S1
S06004AMD1*
S06005AMD1
S06005ENR1
S06005ES01*
S0612SE1S3
S06154E1S3
S0800RVSF1*
SOCTYSH1S1
SOCTYSH1S2
|5^tiri|jg|
R2589-1
R2589-2
R2589-3
R2589-4
R2589-5
R2589-6
R2589-7
R2589-8
R2589-9
R2589-10
R2589-11
R2589-12
R2589-13 .
XRFCups
Metals by SW-846 Method 6010
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Sample Number
S1RSOSNES1*
S700FGCSW1
S700FGCSWX
S0400HT2DCB
S0400HT4D1
S0400HT4D2
S0400HT4D3
i -. .
Laboratory IB--).
R2589-14
R2589-15
R2589-16
R2589-17
R2589-18
R2589-19
R2589-20
.- \. >.''-- : -~F .;>'..' ' 3~^'
/^^^;Ma'irfct;S^~$
XRFCups
^V;j^pfr^?^g|^
Metals by SW-846 Method 6010
These sample numbers were incorrectly identified on the Form Is.
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DATA QUALITY STATEMENT
( ) Data are ACCEPTABLE according to EPA Functional guidelines with no qualifiers (flags) added
by the reviewer.
() Data are UNACCEPTABLE according to EPA Functional Guidelines.
(X ) Data are acceptable with QUALIFICATIONS noted in review.
Telephone/Communication Logs Enclosed? Yes No X
TPO Attention Required? Yes X No If yes, list the items that require attention:
Matrix spike, duplicate, and serial dilution analyses were not provided with this SDG. Although no
qualification was taken, it should be noted that matrix specific effects could not be evaluated for
these analyses.
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INORGANIC DATA VALIDATION REPORT
REVIEW NARRATIVE SUMMARY
This data package was reviewed according to "USEPA Contract Laboratory Program National Functional
Guidelines for Inorganic Data Review," February 1994, and modified for the method used.
Raw data were reviewed for completeness and transcription accuracy onto the summary forms.
Approximately 10-20% of the results reported in each of the samples, calibrations, and QC analyses were
recalculated and verified. If problems were identified during the recalculation of results, a more thorough
calculation check was performed.
SDG No. R2589 consisted of 20 XRF cup samples for metals analyses by SW-846 Method 6010.
The following table lists the data qualifiers added to the sample analyses. Please see Data Qualifier
Definitions, attached to the end of this report.
II
II Sample ID
S05002WNC1, S06004AMD1,
S06005AMD1, S06005ESO1,
S0800RVSF1, S0400HT2DCB
IS05002WNC1, S0500MN1S1,
S06004AMD1, S06005AMD1,
S06005ENR1, S06005ESO1,
S0612SE1S3, S06154E1S3,
S0800RVSF1, SOCTYSH1S2,
S1RSOSNES1, S700FGCSW1,
S700FGCSWX, S0400HT4D2,
S0400HT4D3
S06005ENR1
S0400HT2DCB
S700FGCSW1
1
S700FGCSWX
- - . :^v -;J:J^V^J^'
Elements' " ;. J.\ . Qiialifiere^;'
Antimony
Beryllium
Cadmium
Barium
Calcium
Chromium
Nickel
Potassium
Vanadium
Cobalt
Thallium
U
J
%งflffi^l^ft'
Blank Contamination
ICSA solution result
greater than the IDL
and elevated iron
sample level
$$^$$$j&
vn
vni
0
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Method/SOW Number 6010/SW-846
Revision 0.0
Inorganic Deliverables Completeness Checklist
P Inorganic Cover Page
P Inorganic Analysis Data Sheets (Form I)
P Initial Calibration and Calibration Verification Results (Form II)
P Continuing Calibration Verification Results (Form II)
P CRDL Standard for ICP and AA (Form II, Part 2)
JP._ Blank Analysis Results (Form III)
P ICP Interference Check Sample Results (Form IV)
NP Spiked Sample Results (Form V)
NP Post-digest Spiked Sample Analysis (Form V, Part 2)
JNJP Duplicate Sample Results (Form VI)
P Instrument Detection Limits (Form VII) or (Form X - Quarterly)
P Laboratory Control Sample results (Form VII)
NA Standard Addition Results (Form VIII)
NP ICP Serial Dilution Results (Form IX)
NA Holding Times Summary Sheet (Form X)
P ICP Interelement Correction Factors (Form XII - Quarterly, or Form XI - Annually)
P ICP Linear Ranges (Form XII (XII) - Quarterly)
P Raw Data
_P Samples P Calibration Standards P Blanks NA Spikes
NA Duplicates P ICP QC (ICS and Serial Dilution P LCS
NA Furnace AA NA Mercury Analysis NA Cyanide Analysis
NA Percent Solids Calculations - (Solids Only)
P Sample Prep/Digestion Logs (Form XIII)
P Analysis Run Log (Form XIV)
P Chain-of-Custody
_P Sample Description
P Case Narrative
P Method References
KEY:
P = Provided in original data package, as required by the SOW
R = Provided as Resubmission
NP = Not provided in original data package or as resubmission
NR = Not required under the SOW
NA = Not applicable to this data package or analysis
R2589m Inorganic - 5
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I. DELIVERABLES
All deliverables were present.
Yes X No
Comments: None.
H. HOLDING TIMES AND PRESERVATION CRITERIA
All holding times and preservation criteria were met.
Yes X No
Comments: All samples were analyzed within required holding times. Chain-of-custody
(COC), summary forms, and raw data were evaluated. The XRF cup samples were
received outside temperature requirements. No action was taken because the
Functional Guidelines do not provide specific guidance for temperature and the
effect on the sample integrity is not known.
in. INSTRUMENT CALIBRATIONS: STANDARDS AND-BLANKS
Initial instrument calibrations were performed according to method requirements.
Yes X No
Comments: None.
The instruments were calibrated daily and each time an analysis run was performed.
Yes X No
Comments: None.
The instruments were calibrated using one blank and the appropriate number of standards.
Yes X No
Comments: None.
R2S89m Inorganic - 6
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IV. FORM 1 - SAMPLE ANALYSIS RESULTS
Sample analyses were entered correctly on Form Is.
Yes X No
Comments: Various sample results were reported from dilutions. Additionally the non-detected
j results for sodium in samples S0407IH1D1, S700FGCSW1 and S700FGCSWX
J were reported from dilutions because of negative interference.
V. FORM 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION
The initial and continuing calibration verification standards (ICV and CCV, respectively) met
method requirements.
Yes X No
Comments: None. '
The calibration verification results were within 90-110% recovery for metals, 85-115% for cyanide,
and 80-120% for mercury.
Yes X No
Comments: None.
The continuing calibration standards were run at 10% frequency.
Yes X No
Comments: None.
VI. FORM 2B - CRDL STANDARD FOR ICP AND AA
ICP Analysis: Standards (CRI) at two times the CRDL or the IDL (whichever were greater) were
analyzed at the beginning and the end of each sample run, or at a minimum of twice per eight hours,
whichever was more frequent.
Yes X No
Comments: None.
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GFAA Analysis: Standards (CRA) at two times CRDL were analyzed at the beginning of each
sample run.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
The CRI and/or the CRA were analyzed after the ICV. /
Yes X No
Comments: None.
VH. FORM 3 - BLANKS
The initial and continuing calibration blanks (ICB and CCB, respectively) met method requirements.
Yes X No
Comments: None.
The continuing calibration blanks were run at 10% frequency.
Yes X No
Comments: None.
A laboratory/preparation blank was run at the frequency of one per twenty samples, or per sample
delivery group (whichever is more frequent), and for each matrix analyzed.
Yes X No
Comments: None.
All analyzed blanks were free of contamination.
Yes No X
Comments: The following table lists the blanks with contamination that resulted in sample
qualification, elements present, affected samples, and data qualifiers:
R2589m Inorganic - 8
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Data Validation Report
te^M^PIt^Sfe^
1CB
(I CCB6
CCB5
CCB6
II
II
II
II
||
||
||
||
II
|| CCB5
II CCB7
|| PBS
CCB7
1
Antimony
Barium
Beryllium
Cadmium
Chromium
Calcium
Nickel
Potassium
Vanadium
1.6ug/L
0.7 ug/L
0.8 ug/L
0.7 ug/L
0.4 ug/L
0.5 ug/L
25.8 mg/Kg
0.7 ug/L
25.5 ug/L
0.7 ug/L
"^^:- - -:;.j;>"'"--.>:',r;;y
'SSS^SffiS
S05002WNC1
S06004AMD1
S06005AMD1
S06005ESO1
S0800RVSF1
S0400HT2DCB
S0400HT2DCB
S05002WNC1
S0500MN1S1
S06004AMD1
S06005AMDI
S06005ENR1
S06005ESO1
S0612SE1S3
S06154E1S3
S0800RVSF1
SOCTYSH1S2
S1RSOSNES1
S700FGCSW1
S700FGCSWX
S0400HT4D2
S0400HT4D3
S06005ENR1
S0400HT2DCB
S0400HT2DCB
S0400HT2DCB
S0400HT2DCB
S0400HT2DCB
^^B^iSK^S*^
Concentration Found 'in
ฃ?4;Ji^i^i;iDg/kซ)^
0.47
0.74
0.60
0.38
0.33
0.24
0.25
0.29
0.28
0.33
0.29
0.35
0.32
0.40
0.30
0.31
0.40
0.37
0.13
0.32
0.29
0.29
0.12
O.J9
30.1
0.09
9.1
0.19
s.'S^'QMdiM/SJpSrV'
^ilA^usflnentซK*
U
II
The incorrect results for antimony and selenium were reported on the Form 3 for
the ICB. The raw data value for selenium was less than the IDL rather than 2.2
as reported and the raw data value for antimony was 1.6 ug/L rather than 2.5
ug/L.
VIII. FORM 4 - ICP INTERFERENCE CHECK SAMPLE
The ICP interference check sample (ICS) was run twice per eight hour shift and/or at the beginning
and end of each sample set analysis sequence (whichever is more frequent).
Yes X
No
Comments: None.
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Percent recovery of the analytes in solution ICSAB were within the range of 80-120%.
Yes X No
Comments: None.
Sample results for aluminum, calcium, iron, and magnesium were less than the ICSA values.
Yes No X
Comments: The following sample results were qualified because the iron result was greater than
the ICSA value and the absolute value of the associated element was greater than
the IDL in the ICSA analysis:
Element
Cobalt
Thallium
IGSA Result
X'- (ซtfL).T.
-4
7
:'.v-IibL.-,-:-.!:
'-"(*&&ฃ
0.6
3.3
f- '- --'''":. ;.;": ,-f Samples Affected :/;-~; '~::'; '. I'-'' ".(',
r^^:l^^^^f^^^^
S700FGCSW1
S700FGCSWX
^Qualiffe/sHl
J I
IX. FORM 5A - MATRIX SPIKE SAMPLE ANALYSIS
A matrix spike sample was analyzed with every twenty or fewer samples of a similar matrix, or one
per sample delivery group (whichever is more frequent).
Yes
No X
Comments: A matrix spike sample was not analyzed with this SDG. Therefore, the effect of the
sample matrix on the sample preparation procedures and the measurement
methodology could not be evaluated.
The percent recoveries (%R) were calculated correctly.
% Recovery = (SSR ~ SR) X 100
SA
SSR = spiked sample result
SR = sample result
SA = spike added
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
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1 Spike recoveries were within 75-125% (an exception is granted where the sample concentration is
!j four times the spike concentration).
i Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
X. FORM SB - POST DIGEST SPIKE RECOVERY
I A post-digest spike was performed for those elements that did not meet the specified criteria (i.e.,
pre-digestion/pre-distillation spike recovery falls outside of control limits and sample result is less
. than four times the spike amount added, exception: Ag, Hg).
' Yes No NA X
I Comments: A post digestion spike was not analyzed with this SDG.
XI. FORM 6 - DUPLICATE SAMPLE ANALYSIS
Duplicate sample analysis was performed with every twenty or fewer samples of a similar matrix,
or one per sample delivery group (whichever is more frequent).
Yes No X
Comments: Duplicate sample analyses were not provided with this SDG. Therefore, precision
could not be evaluated.
The RPDs were calculated correctly.
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
For sample concentrations greater than five times the CRDL, RPDs were within ฑ20% (limits of
ฑ35% apply for soil/sediments/tailings samples).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
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For sample concentrations less than five times the CRDL, duplicate analysis results were within the
control window of ฑ CRDL (two times CRDL for soils).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
XH. GFAA QC
Duplicate injections were performed on all GFAA samples and the RSD was within ฑ 20%.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
Analytical spikes were performed on all GFAA samples and the percent recovery was 85 - ] 15%.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
MSAs were analyzed when required and the correlation coefficient was > 0.995.
Yes No NA X
Comments: None.
Xin. FORM 7 - LABORATORY CONTROL SAMPLE
The laboratory control sample (LCS) was prepared and analyzed with every twenty or fewer samples
of a similar matrix, or one per sample delivery group (whichever is more frequent).
Yes X No
Comments: None.
'All results were within control limits.
Yes X No
Comments: None.
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XIV. FORM 8 - STANDARD ADDITION RESULTS
Results from graphite furnace standard additions were entered on Form VIII as directed in the SOW.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
XV. FORM 9 - ICP QC
A serial dilution was performed for ICP analysis with every twenty or fewer samples of a similar
matrix, or one per sample delivery group, whichever is more frequent.
Yes No X
Comments: Serial dilutions were not provided with this SDG. Therefore, it could not be
determined whether or not significant physical or chemical interferences exist due
to sample matrix in ICP metals.
The serial dilution was without interference problems as defined by the method.
Yes No NA X
Comments: Serial dilutions were not provided with this SDG.
XVI. FORM 10 - QUARTERLY INSTRUMENT DETECTION LIMITS (IDL)
IDLs were provided for all elements on the target analyte list.
Yes X No
Comments: None.
XVn. FORM 11 - INTERELEMENT CORRECTION FACTORS FOR ICP
Interelement corrections for ICP were reported.
Yes X No
Comments: None.
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XVm. FORM 12 - ICP LINEAR RANGES
ICP linear ranges were reported.
Yes X No
Comments: None.
XIX. LINEAR RANGE VERIFICATION ANALYSIS
Linear Range Verification Analysis (LRA) was performed and results were within control limits of
5% of the true value.
Yes No NA X
Comments: None.
XX. FORM 13 - PREPARATION LOG
Information on the preparation of samples for analysis was reported.
Yes X No
Comments: None.
XXI. FORM 14 - ANALYSIS RUN LOG
The required information was filled out for each analysis run in the data package.
Yes X No
Comments: None.
XXII. Additional Comments or Problems/Resolutions Not Addressed Above
Yes No X
Comments: None.
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INORGANIC DATA QUALITY ASSURANCE REVIEW
Region Vffl
DATA QUALIFIER DEFINITIONS
For the purpose of Data Validation, the following code letters and associated definitions are provided for use
by the data validator to summarize the data quality. Use of additional qualifiers should be carefully
considered. Definitions for all qualifiers used should be provided with each report.
GENERAL QUALIFIERS for use with both INORGANIC and ORGANIC DATA
R - Reported value is "rejected." Resampling or reanalysis may be necessary to verify the
presence or absence of the compound.
J - The associated numerical value is an estimated quantity because the Quality Control criteria
were not met.
U J - The reported amount is estimated because Quality Control criteria were not met. Element or
compound was not detected.
N J - The analysis indicates the presence of an analyte that has been "tentatively identified" and the
associated numerical value represents its approximate concentration.
N - The analysis indicates the presence of an analyte for which there is presumptive evidence to
make a tentative identification.
U - The material was analyzed for, but was not-detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
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ACRONYMS
AA Atomic Absorption
Ag Silver
CCB Continuing Calibration Blank
CCV Continuing CaJibration Verification
CFR Code of Federal Regulations
CLP Contract Laboratory Program
CRA CRDL standard required for AA
CRDL Contract Required Detection Limit
CRI CRDL standard required for ICP
CV Cold Vapor
EPA U.S. Environmental Protection Agency
GFAA Graphite Furnace Atomic Absorption
Hg Mercury
ICB Initial Calibration Blank
ICP Inductively Coupled Plasma
ICS Interference Check Sample
ICSA Interference Check Sample (Solution A)
ICSAB Interference Check Sample (Solution AB)
ICV Initial Calibration Verification
IDL Instrument Detection Limit
LCS Laboratory Control Sample
LRA Linear Range Verification Analysis
MSA Method of Standard Additions
PDS Post Digestion Spike
QC Quality Control
RPD Relative Percent Difference
RPM RegionaJ Project Manager
RSD Percent Relative Standard Deviation
SA Spike Added
SAS Special Analytical Services
SDG Sample Delivery Group
SOW Statement of Work
SR Sample Result
SSR Spiked Sample Result
TPO Technical Project Officer
R2589m
Inorganic - 16
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SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No,:
Contract:
SAS No.:
S0407IH1D1
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: R2589-1
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese |
Nickel |
Potassium
Selenium
Silver |
7440-23-5 | Sodium |
7440-28-0 (Thallium |
7440-62-2 [Vanadium
7440-66-6 (Zinc |
Concentration
12000
166
475
63.6
0.68
4.0
16700
C
Q
M
P
1 P 1
1 P 1
1 P 1
P
1 P 1
P
7-7 | | P |
3.8 | | P |
33.1
19100
757
2880
838
8.0
1180
1.3
6.1
286 |U
0.32 |U
18.0
7040 |
P 1
P
P
P
P
P
P
P
P
P
P
P 1
1 P
Color Before: BLACK
Color After: YELLOW
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Comments:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0407IM1S1
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: R2589-2
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7 |
7440-43-9 |
7440-70-2 |
| 7440-47-3 |
7440-48-4 |
7440-50-8 |
7439-89-6 |
7439-92-1 |
7439-95-4 |
7439-96-5 |
7440-02-0 |
7440-09-7 |
7782-49-2 |
7440-22-4 |
7440-23-5 |
7440-28-0 |'
7440-62-2 [A
7440-66-6 |:
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium |
Manganese J
Nickel |
Potassium |
Selenium |
Silver |
Sodium |
Fhallium |
/anadium |
Zinc |
Concentration
13400
296
413
84.4
0.58
5.1
7380
16.3
5.6
78.7
19700
1770
3320
940
12.7
1790
0.94
16.1
165
0.32
26.0
910
C
B
U
Q
.'
M
P
P1
P
P
P
P
P
P
P
P
P
P 1
P 1
P 1
P 1
P 1
P ]4
P 1
P 1
P 1
P 1
P 1
I
I
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW84
1
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,Lab Name: COMPUCHEM
I Lab Code: LIBRTY Case No. :
Matrix (soil/water): SOIL
ILevel (low/med) : LOW
% Solids: 100.0
Contract:
. SAS No.:
S05002WNC1
SDG No.: R2589
Lab Sample ID: R2589-3
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
Analyte
Aluminum
Concentration
4170
C
Q
M
P
7440-38-2 (Arsenic
3.1
I P I
7440-39-3
7440-36-0
| 7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
| 7439-89-6
| 7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese |
Nickel |
Potassium |
Selenium
Silver |
Sodium |
Thallium |
Vanadium |
Zinc |
119 |
0.47 |B
0.29 |B
0.03 |U
9490 |
34.3 |
4.1 |
10.2 |
7640 |
130 |
4570 |
218 |
7.1 |
964 |
0.21 |U
0.07 |U
104 |B
0.32 |U
6.6 |
29.9 |
1
1
1
1
1
1
1
1
1 P
1 P
P
P
P
P
P
P
P
P 1
P
P
P
P
P
P
P
P
P
P
M
u
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0500MN1S1
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: R2589-4
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
j 7440-39-3
| 7440-36-0
7440-41-7
7440-43-9
| 7440-70-2
| 7440-47-3
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium |
7440-48-4 (Cobalt |
7440-50-8 (Copper |
( 7439-89-6 (iron |
7439-92-1 (Lead |
7439-95-4 (Magnesium (
7439-96-5 (Manganese |
7440-02-0 (Nickel |
7440-09-7 ( Potassium (
7782-49-2 (Selenium |
7440-22-4 (Silver |
7440-23-5
Sodium |
7440-28-0 (Thallium |
7440-62-2 (Vanadium (
7440-66-6
Zinc |
Concentration
5720
C
175
103
48.6
0.28 B
5.3
4340
7.5
3.5
15.9
12200
1020
2760
433
5.9
966
0.50
8.2
14.0.
U
0.32 (U
8.9
926 |
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P &
P
P 1
P
P
1 P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW8
1
1
-------
I
I
I
I
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
COMPUCHEM
LIBRTY Case No. :
Contract:
S06004/MD1
A
SASNo.: SDGNo.: R2589 . VM '///ป i-
Lab Name:
(Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
LOW
Lab Sample ID:
Date Received:
R2589-5
6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2 |
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
J Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5360
7.5
60.2
0.74
0.33
0.03
9710
1 7.3
4.1
12.4
10700
15.8
6150
237
7.2
1180
0.22 |
0.07 |l
119 p
0.32 |1
7.4 |
33.8 |
C
B
B
U
U
\J
B
J
Q
M
P
P 1
P
P
P |
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
Form I - IN
SW84.
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S06005AMD1
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: R2589-6
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
| 7440-39-3
7440-36-0
7440-41-7
| 7440-43-9
| 7440-70-2
7440-47-3
| 7440-48-4
) 7440-50-8
| 7439-89-6
| 7439-92-1
7439-95-4 |
7439-96-5 |
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel j
Potassium |
Selenium |
Silver
Sodium |
Thallium j
Vanadium
Zinc
Concentration
5020
8.5
84.1
0.60
0.29
0.03
18400
5.4
4.6
16.0
10100
27.6
5460
231
7.5
1230 |
0.21 |
0.07 |
118 |
0.32 )
7.8
42.6 |
C
B
B
u
U
u
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
1
U
n
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
-JJi
tr
Form I - IN
SWSl
-------
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
feb Name:
Lab Code:
COMPUCHEM
LIBRTY Case No. :
Contract :
S06005ENR1
SAS No.: SDG No.: R2589
fetrix (soil/water): SOIL
Level (low/med):
Solids: 100.0
Lab Sample ID: R2589-7
LOW
Date Received: 6/19/02
I
I
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4 |
7439-96-5 |
7440-02-0 |
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7110
15.5
89.1
5.3
0.35
0.12
2610
| 7.5
| 3.8
14.1
12000
101
4590
357
7.6
1410
0.41
0.62
206
0.33
8.6
83.0
C
B
B
B
U
Q
M
P
P
P 1
P
P |
P |
P
P
P
P
P
P
P
P
P
P
P^
P
P
P
P
P
4
>
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Texture: MEDIUM
Artifacts:
Comments:
1H
Form I - IN
SW846
-------
, SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No. :
Contract:
SAS No.:
SDG No.: R2589
Matrix (soil/water) : SOIL
Level (low/med) :
% Solids: 100.0
Lab Sample ID : R2589-8
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
| 7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
| 7440-43-9
| 7440-70-2
7440-47-3
7440-48-4
| 7440-50-8
( 7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
7782-49-2 (Selenium
7440-22-4 | Silver
7440-23-5 (Sodium
7440-28-0 (Thallium
7440-62-2 (Vanadium
7440-66-6 (2inc
Concentration
5370
4.6
87.3
C
0.38 B
0.32 B
0.03 U
8100
6.1
4.1 '
12.1
9110
7.6
4750
220
7.1
1080
0.32
0.07
109
0.33
8.6
19.3
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P 1
P 1
P
P
P J-
P
P
P 1
P 1
P 1
a
&
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
u
Form I - IN
SWS
-------
I
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
I
ab Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0612SE1S3
SDG No.: R2589
atrix (soil/water): SOIL
5vel (low/med):
r
i
Lab Sample ID: R2589-9
LOW
Date Received: 6/19/02
Solids: 100.0
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
| 7439-89-6
7439-92-1
| 7439-95-4 j
J 7439-96-5 j
7440-02-0 |
7440-09-7 |
| 7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
[Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7510
15.4
217
4.5
0.40
0.34
2990
7.7
5.4
19.4
10400
125
4220
301
6.8
1000
0..22 |
0.86
157 |
0.33 |
9.3
215 |
C
B
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P i
P
P
P
P
P
P
P
P
P
P
\(A
\
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Comments:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
COMPUCHEM Contract :
LIBRTY
il/water]
/med) :
100.0
Case No. : SAS No. :
: SOIL
LOW
Lab Sample ID:
Date Received:
EPA SAMPLE NO. g
S06154E1S3 ^
SDG No . :
R2589-10
R2589 1
6/19/02 1
Concentration Units (ug/L or mg/kg dry weight) : MG/KG J
1
1
1
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
7439-95-4 (Magnesium
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration C
5780
Q M
P
8.1 P
88.1 . P
1.1 P
0.30 |B p
0.03 U p
16800 P
7.5 P
4.9 P
21.0
10100
38.0
3790
222
8.4
. 1100
0.27 B
0.07 B
154 |B
0.32 |U
9.6
57.0
P
P
P
P
P
P 1
P 1
p-4
p
1 P 1
p 1
P 1
p
1
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Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE
J
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case No. :
Contract:
SOSOORjtfSFl
V
SAS No.: SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: R2589-11
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG ^
CAS No.
7429-90-5.
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3 |
7440-48-4 |
7440-50-8 |
7439-89-6 |
7439-92-1 (
7439-95-4 (
7439-96-5 |
7440-02-0 (
7440-09-7 |
7782-49-2 |
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
7440-22-4 | Silver
7440-23-5 (Sodium |
7440-28-0 | Thallium
| 7440-62-2 (Vanadium |
7440-66-6 (Zinc
Concentration
5870
2.8
121
0.33
0.31
C
B
B
0.03 |U
4810
6.3 |
4.3
9.8 |
8940 |
12.3
4000
271
5.9
1380
0.25
0.07
91.1
0.32
9.5
29.9
B
U
B
U
Q
M
P
P 1
P
P 1
P 1
P
P
P
P
P
P
P
P
P
P
P
p 4t
p
p
p
p
p
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments :
Texture: MEDIUM
Artifacts:
Form I - IN
L.O
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
SOCTYSH1S1
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: R2589-12
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): .MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
Analyte
Aluminum
Concentration
8040
Arsenic 42.2
Barium 189
7440-36-0 (Antimony 24.1
7440-41-7
7440-43-9
7440-70-2
7440-47-3 |
7440-48-4 |
| 7440-50-8 |
7439-89-6 |
7439-92-1 |
Beryllium 0.42
Cadmium 3 . 4
Calcium 4750
Chromium | 7.9
Cobalt
3.6
Copper | 32.1
Iron
10300
C
B
Lead | 433
7439-95-4 (Magnesium | 3360
7439-96-5 (Manganese
7440-02-0 J Nickel
7440-09-7 | Potassium
7782-49-2 (Selenium
7440-22-4 (Silver
7440-23-5 (Sodium
7440-28-0 (Thallium
7440-62-2 (Vanadium
7440-66-6 (Zinc
355
6.4
1730
0.50
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
1 P
1 P
P
P
P J
2.0 | P |
14.3 |U
P 1
0.32 |U | p
11.0 |
1010 |
P 1
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
24
1
Form I - IN
SW84I
-------
I
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
SOCTYSH1S2
SDG No.: R2589
I
I
I
I
I
I
trix (soil/water): SOIL
(low/med) : LOW
% Solids: 100.0
Lab Sample ID:
Date Received:
R2589-13
6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium |
Thallium
Vanadium
Zinc
Concentration
7240
54.0
118
39.3
0.40
3.8
4190
6.9
4.0
28.2
11400
689
3500
352
6.6
1540
0.33
5.5
14.4
0.33
11.6
698
C
B
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
1
(A
J*.
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-l-
INORGANIC ANALYSES DATA SHEET
EPA S.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No . :
Contract:
SAS No.:
S1R&0SNES1
'o
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: R2589-14
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
Analyte
Aluminum
Arsenic
Concentration
7540
91.9
Barium 109
7440-36-0 (Antimony 13.6
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
Beryllium 0.37
Cadmium 5 . 3
Calcium 15500
Chromium 9 . 7
Cobalt
Copper
7439-89-6 | Iron
7439-92-1 (Lead
7439-95-4 (Magnesium
7439-96-5 (Manganese
7440-02-0 . (Nickel
7440-09-7 | Potassium
7782-49-2 (Selenium
7440-22-4 | Silver
7440-23-5 ( Sodium
7440-28-0 (Thallium
7440-62-2 (Vanadium
7440-66-6 ( Zinc
5.1
32.1
15200
534
6480
525
9.1
1760
0.46
2.8
C
Q
B
B
14.3 |U
0.32 |U
11.9
1170 |
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P 1
P^
P
P
P 1
P 1
1 P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
-------
I
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
ab Code: LIBRTY Case No. :
latrix (soil/water): SOIL
*evel (low/med) : LOW _
Solids: 100.0
Contract:
SAS No.:
S700FGCSW1
SDG No.: R2589
Lab Sample ID: R2589-15
Date Received: 6/19/02
I
i
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium |
Manganese |
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
1510
1910
29.5
1160
0.13
40.4
2610
1.5
1.1
102
64800
9360
2610
4250
3.4
522
3.1
79. 9
289
6.4
2.5
6790
C
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case No. :
Matrix (soil/water): SOIL
Level (low/med) : LOW
% Solids: 100.0
Contract:
SAS No.:
S700FGCSWX
SDG No.: R2589
Lab Sample ID: R2589-16
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
Analyte
Aluminum
Concentration
4820
C
Q
M
P
7440-38-2
Arsenic
918
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6 |
7439-92-1 |
7439-95-4 |
7439-96-5 |
7440-02-0 |
7440-09-7 |
7782-49-2 j
7440-22-4 |
7440-23-5 |
7440-28-0 |
7440-62-2 j
7440-66-6 |
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
| 98.9
289
| 0.32
| 46.3
13200
| 5.8
| 3.8
| 39.0
| 30100
4580
| 6290
| 2490
7.0' |
1150 |
1.6
42.0 |
286 |
1.4 |
7.8
7300 |
1
B
U
P |
1 P 1
1 P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
P 1
I
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
_oo_
Ho
Form I - IN
SW84
-------
I
i
l!
i:
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
% Solids:
COMPUCHEM Contract :
LIBRTY Case No . : SAS No . :
.I/water) : SOIL
'med) : LOW
100.0
Lab Sample ID:
Date Received:
S0400HT2DCB
SDG No . :
R2589-17
R2589
6/19/02
Concentration Units (ug/L or mg/kg dry weight) : MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
Analyte
Aluminum
Arsenic
Barium
7440-36-0 | Antimony
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
7439-96-5 | Manganese |
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
| 7440-28-0
| 7440-62-2
. | 7440-66-6
Nickel |
Potassium
Selenium |
Silver |
Sodium |
Thallium |
Vanadium
Zinc |
Concentration C
83.8
0.43 B
0.25 |B
0.24 |B
0.02 |U
0.03 |U
30.1 |B
0.19 B
0.06 |U
0.24 B
63.7
2.4
20.6 B
2.1
0.09 B
9.1 B
0.21 |U
Q M
P 1
P 1
p | ^A,
0.07 |U
140 |B
0.32 |U
0.19 |B
2.7 |
p m
p i
p i
p m
p
p
p
p
p
p
p
p
p
p
p
p
p
p i
p i
1
U.
(4
Color Before: WHITE
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
jab Code: LIBRTY
Case No. :
Contract:
SAS No.:
latrix (soil/water) : SOIL
.level (low/med) :
fc Solids: 100.0
LOW
S0400HT4D1
Sample ID :
e Received:
SDG No . :
R2589-18
6/19/02
R2589
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
| 7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
8330
250
149
136
0.36
| 8.7
7280
6.3
4.4
26.3
20000
2140
3940
1470
6.8
1250
1.1
25.7
14.4 |
0.33 |
10.5 |
1860 |
C
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
.P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
n
-tt-
Form I - IN
SW84
-------
uos
DBS Operating Services, Inc.
Data Validation Report
REGION VIII
DATA VALIDATION REPORT
INORGANIC
0203-0008
Superior Waste Rock
Tien Nguyen
-'' ':^
CompuChem - Liberty
Not Indicated U2589
July 5. 2002
Review Assigned Date
Review Completion Date July 19. 2002
Bill Fear
_Data Validator
_Report Reviewer Ken Schroeder
;-;:^Saitiplซ^Ipi^:i:
S0319OM1S2*
S04002WNA1
S04002WSD1
S04003ESE1
^ji^o^ry^Dfi^
U2589-1
U2589-2
U2589-3
U2589-4
!งKi^igf
XRFCups
Metals by SW-846 Method 6010
Sample S0319OM1S2 was incorrectly identified as S03190M1S2 on the Fonn 1.
112589m
Inorganic -1
-------
uos
URS Operating Services, Inc.
Data Validation Report
DATA QUALITY STATEMENT
( ) Data are ACCEPTABLE according to EPA Functional guidelines with no qualifiers (flags) added
by the reviewer.
( ) Data are UNACCEPTABLE according to EPA Functional Guidelines.
( X ) Data are acceptable with QUALIFICATIONS noted in review.
Telephone/Communication Logs Enclosed? Yes,
TPO Attention Required? Yes X No_
No X
If yes, list the items that require attention:
Matrix spike, duplicate, and serial dilution analyses were not provided with this SDG. Although no
qualification was taken, it should be noted that matrix specific effects could not be evaluated for
these analyses.
U2589m
Inorganic - 2
-------
I
I
1
uos
URS Operating Services, Inc.
Data Validation Report
INORGANIC DATA VALIDATION REPORT
REVIEW NARRATIVE SUMMARY
This data package was reviewed according to "USEPA Contract Laboratory Program National Functional
Guidelines for Inorganic Data Review," February 1994, and modified for the method used.
Raw data were reviewed for completeness and transcription accuracy onto the summary forms.
Approximately 10-20% of the results reported in each of the samples, calibrations, and QC analyses were
recalculated and verified. If problems were identified during the recalculation of results, a more thorough
calculation check was performed.
SDG No. U2589 consisted of 4 XRFcup samples for metals analyses by SW-846 Method 6010.
The following table lists the data qualifiers added to the sample analyses. Please see Data Qualifier
Definitions, attached to the end of this report.
r '/j-^ ' '' \ Sample ID -' . ';: ^i^;
S0319OM1S2, S04002WNA1
All Samples
'-. : ."-. i.'"' '. ,"'' v*i"''." " '
:v.' Elements! .: ^
' ,.\\- . j- *- " ป "^j. ' . "'
Antimony
Thallium
-...V-C,.-.A. Vr-.-j i,..'.-..
' - . -v-i f- r-: *-i .' .'
- H- " :V.i 'V'^^K^tZ-^
u
UJ
'G^VReasoin to^^^^ki^
W%:&$$sJili&$j$
Blank
contamination
Negative blank
contamination
^feyiew;,,
!*}&.!&< ?&>.**.
ฃ Section j->
vn
U2589m
Inorganic - 3
-------
uos
URS Operating Services. Inc. Data Validation Report
Method/SOW Number 6010/SW-846
Revision 0.0
Inorganic Beliverables Completeness Checklist
Inorganic Cover Page
P Inorganic Analysis Data Sheets (Form I)
P Initial Calibration and Calibration Verification Results (Form II)
P Continuing Calibration Verification Results (Form II)
P CRDL Standard for ICP and AA (Form II, Part 2)
P Blank Analysis Results (Form III)
P ICP Interference Check Sample Results (Form IV)
NP Spiked Sample Results (Form V)
NP Post-digest Spiked Sample Analysis (Form V, Part 2)
NP Duplicate Sample Results (Form VI)
P Instrument Detection Limits (Form VII) or (Form X - Quarterly)
P Laboratory Control Sample results (Form VII)
NA Standard Addition Results (Form VIII)
NP ICP Serial Dilution Results (Form IX)
NA Holding Times Summary Sheet (Form X)
P ICP Interelement Correction Factors (Form XII - Quarterly, or Form XI - Annually)
P ICP Linear Ranges (Form XII (XII) - Quarterly)
P Raw Data
_P Samples P Calibration Standards P Blanks NA Spikes
NA Duplicates P ICP QC (ICS and Serial Dilution P LCS
NA Furnace AA NA Mercury Analysis NA Cyanide Analysis
NA Percent Solids Calculations - (Solids Only)
P Sample Prep/Digestion Logs (Form XIII)
P Analysis Run Log (Form XIV)
P Chain-of-Custody
P Sample Description
P Case Narrative
P Method References
KEY:
P = Provided in original data package, as required by the SOW
R = Provided as Resubmission
NP = Not provided in original data package or as resubmission
NR = Not required under the SOW
NA = Not applicable to this data package or analysis
U2589m Inorganic-4
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
b Name: COMPUCHEM
ab Code: LIBRTY Case No. :
jitrix (soil/water) : SOIL
-.evel (low/med) : LOW
Contract:
SAS No. :
Lab Sample ID:
.Date Received:
S0400HT4D2
SDG No. : R2589
R2589-19
6/19/02
Solids: 100.0
I
I
I
f
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
J Arsenic
| Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc |
Con cen tra ti on
5800
957
102
399
0.29
14.5
8510
4.4
3.9
38.9
32600
5070
4120
1870
5.8
1050
1.5
43.3
14.3 |
0.32 |
7.6 |
2860 |
C
B
U
u
Q
1
1
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P 1
P 1
P 1
(A
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
11
Form I - IN
SVV846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0400HT4D3
SDG No.: R2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: R2589-20
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
| 74.29-90-5
| 7440-38-2
| 7440-39-3
| 7440-36-0
7440-41-7
7440-43-9
7440-70-2
| 7440-47-3
| 7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4910
| 300
116
67.6
0.29
1.9
19900
5.3
3.9
19.5
15100
1120
6840
591
6.2
1040
0.55
9.5
26.1
0.32
10.2
348
C
B
- !
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
PJ
P
P
P 1
P 1
P
1
1
1
1
IU
1
1
1
K-
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW8J
-------
DOS
URS Operating Services, Inc. Data Validation Report
I. DELIVERABLES
All deliverables were present as specified in the Statement of Work.
Yes X No
Comments: None.
II. HOLDING TIMES AND PRESERVATION CRITERIA
All method holding times were met.
Yes X No
Comments: None.
All technical holding times and preservation criteria were met.
Yes X No
Comments: All samples were analyzed within required holding times. Chain-of-custody
(COC), summary forms, and raw data were evaluated. The XRF cup samples were
received outside temperature requirements. No action was taken because the
Functional Guidelines do not provide specific guidance for temperature and the
effect on the sample integrity is not known.
ID. INSTRUMENT CALIBRATIONS: STANDARDS AND BLANKS
Initial instrument calibrations were performed according to SOW requirements.
Yes X No
Comments: None.
The instruments were calibrated daily and each time an analysis run was performed.
Yes X No
Comments: None.
U2589m Inorganic - 5
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uos
URS Operating Services, Inc.
Data Validation Report
The instruments were calibrated using one blank and the appropriate number of standards.
Yes X No
Comments: None.
IV. FORM 1 - SAMPLE ANALYSIS RESULTS
Sample analyses were entered correctly on Form Is.
Yes X No
Comments: The zinc result was reported from dilution in sample S04003ESE1
V. FORM 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION
The initial and continuing calibration verification standards (ICV and CCV, respectively) met SOW
requirements.
Yes X
Comments:
No
None.
The calibration verification results were within 90-110% recovery for metals, 85-115% for cyanide,
and 80-120% for mercury.
Yes X No
Comments: None.
The continuing calibration standards were run at 10% frequency.
Yes X No
Comments: None.
U2589m
Inorganic - 6
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URS Operating Services. Inc. Data Validation Report
VI. FORM 2B - CRDL STANDARD FOR ICP AND AA
ICP Analysis: Standards (CRJ) at two times the CRDL or the IDL (whichever were greater) were
analyzed at the beginning and the end of each sample run, or at a minimum of twice per eight hours,
whichever was more frequent.
Yes X No
Comments: None.
GFAA Analysis: Standards (CRA) at two times CRDL were analyzed at the beginning of each
sample run.
Yes No NA X
Comments: None.
The CRI and/or the CRA were analyzed after the ICV.
Yes X No
Comments: None.
VH. FORM 3 - BLANKS
The initial and continuing calibration blanks (ICB and CCB, respectively) met SOW requirements.
Yes X No
Comments: None.
The continuing calibration blanks were run at 10% frequency.
Yes X No
Comments: Continuing calibration blanks were run every 10 samples.
U2589m Inorganic - 7
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uos
URS Operating Services, Inc.
Data Validation Report
A laboratory/preparation blank was run at the frequency of one per twenty samples, or per sample
delivery group (whichever is more frequent), and for each matrix analyzed.
Yes X No
Comments: None.
All analyzed blanks were free of contamination.
Yes No X
Comments: The following table lists the blanks with contamination that resulted in
qualification, elements present, affected samples, and data qualifiers:
Blank Contaminants
Blank
ID
Contaminant
Concentration
Found in
Blank
-IDL
.
Associated.
ป*/ ' f "'--" ;'"*7ซ-.1V-.^r.ฃ_^yif{|
> ' 'fnnrfiปrifmftinri'YTnimfl &p*
T-^wj*iJSiV*.v?
CCB3
Antimony
2.3ug/L
2.2
S0319OM1S2
S04002WNA1
0.91
0.71
U
CCB2
Thallium
-3.47
2.2
S0319OM1S2
S04002WNA1
S04002WSD1
S04003ESE1
0.22 U
0.21 U
0.21 U
0.21 U
UJ
The negative value for thallium was taken from the raw data as the laboratory was
having problems reporting negative results on the Form 3. No other action was
required for negative blank contamination found from the raw data as the sample
results were greater than five times the blank values.
VIII. FORM 4 - ICP INTERFERENCE CHECK SAMPLE
The ICP interference check sample (ICS)-was run twice per eight hour shift and/or at the beginning
and end of each sample set analysis sequence (whichever is more frequent).
Yes X
No
Comments: None.
U2589m
Inorganic - 8
-------
' uos
I URS Operating Services, Inc. Data Validation Report
Percent recovery of the analytes in solution ICSAB were within the range of 80-120%.
I Yes No X
(Comments: The recovery for thallium exceeded 120% in the ICSAB analysis. However no action was
required as thallium was non-detected in the samples.
I Sample results for aluminum, calcium, iron, and magnesium were less than the ICSA values.
tl Yes No X
J ~
Comments: The iron result was greater than the ICSA value in sample S04003ESE1. However
I no action was required as interference was not noted in the sample.
IX. FORM 5A - MATRIX SPIKE SAMPLE ANALYSIS
A matrix spike sample was analyzed with every twenty or fewer samples of a similar matrix, or one
per sample delivery group (whichever is more frequent).
Yes No X
Comments: A matrix spike sample was not analyzed with this SDG. Therefore, the effect of the
* sample matrix on the sample preparation procedures and the measurement
methodology could not be evaluated.
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
Spike recoveries were within 75-125% (an exception is granted where the sample concentration is
four times the spike concentration).
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
U2589m Inorganic - 9
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URS Operating Services, Inc. Data Validation Report
X. FORM SB - POST DIGEST SPIKE RECOVERY
A post-digest spike was performed for those elements that did not meet the specified criteria (i.e.,
Pre-digestion/pre-distiJlation spike recovery falls outside of control limits and sample result is less
than four times the spike amount added, exception: Ag, Hg).
Yes No Not Required X
Comments: None.
XL FORM 6 - DUPLICATE SAMPLE ANALYSIS
Duplicate sample analysis was performed with every twenty or fewer samples of a similar matrix,
or one per sample delivery group (whichever is more frequent).
Yes No X
Comments: Duplicate sample analyses were not provided with this SDG. Therefore, precision
could not be evaluated.
The RPDs were calculated correctly.
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
For sample concentrations greater than five times the CRDL, RPDs were within ฑ20% (limits of
ฑ35% apply for soil/sediments/tailings samples).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
For sample concentrations less than five times the CRDL, duplicate analysis results were within the
control window of ฑ CRDL (two times CRDL for soils).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
U2589m Inorganic-10
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I URS Operating Services, Inc. Data Validation Report
XII. GFAA QC
' Duplicate injections were performed on all GFAA samples and the RSD was within ฑ 20%.
I Yes No NA X
Comments: GFAA analyses were not performed on these samples.
I
Analytical spikes were performed on all GFAA samples and the percent recovery was 85 - 115%.
I
I
Yes No NA X
Comments: GFAA analyses were not performed on these samples.
MSAs were analyzed when required and the correlation coefficient was > 0.995.
Yes No NA X
Comments: None.
FORM 7 - LABORATORY CONTROL SAMPLE
The laboratory control sample (LCS) was prepared and analyzed with every twenty or fewer samples
of a similar matrix, or one per sample delivery group (whichever is more frequent).
Yes X No
Comments: None.
All results were within control limits.
Yes X No
Comments: All LCS results were within laboratory control limits.
XTV. FORM 8 - STANDARD ADDITION RESULTS
Results from graphite furnace standard additions were entered on Form VIII as directed in the SOW.
Yes No NA X
Comments: None.
U2589m Inorganic -11
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XV. FORM 9 - ICP QC
A serial dilution was performed for ICP analysis with every twenty or fewer samples of a similar
matrix, or one per sample delivery group, whichever is more frequent.
Yes No X
Comments: Serial dilutions were not provided with this SDG. Therefore, it could not be
determined whether or not significant physical or chemical interferences exist due
to sample matrix in ICP metals.
The serial dilution was without interference problems as defined by the method.
Yes No NA X
Comments: Serial dilutions were not provided with this SDG.
XVI. FORM 10 - QUARTERLY INSTRUMENT DETECTION LIMITS (BDL)
IDLs were provided for all elements on the target analyte list.
Yes X No
Comments: None.
Reported IDLs met SOW requirements.
Yes X No ^
/1
Comments: None. K
XVH. FORM 11 - INTERELEMENT CORRECTION FACTORS FOR ICP
Interelement corrections for ICP were reported.
Yes X No
Comments: None.
U2589m Inorganic-12
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XVm. FORM 12 - ICP LINEAR RANGES
ICP linear ranges were reported.
Yes X No
Comments: None.
XIX. LINEAR RANGE VERIFICATION ANALYSIS
Linear Range Verification Analysis (LRA) was performed and results were within control limits of
ฑ5% of the true value.
Yes No NA X
Comments: None.
XX. FORM 13 - PREPARATION LOG
Information on the preparation of samples for analysis was reported on Form XIII.
Yes X . No
Comments: None.
XXI. FORM 14 - ANALYSIS RUN LOG
A Form XIV with the required information was filled out for each analysis run in the data package.
Yes X No
Comments: None.
XXn. Additional Comments or Problems/Resolutions Not Addressed Above
Yes No X
Comments: None.
U2589m Inorganic-13
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INORGANIC DATA QUALITY ASSURANCE REVIEW
Region VIH
DATA QUALIFIER DEFINITIONS
For the purpose of Data Validation, the following code letters and associated definitions are provided for use
by the data validator to summarize the data quality. Use of additional qualifiers should be carefully
considered. Definitions for all qualifiers used should be provided with each report.
GENERAL QUALIFIERS for use with both INORGANIC and ORGANIC DATA
R - Reported value is "rejected." Resampling or reanalysis may be necessary to verify the
presence or absence of the compound.
J - The associated numerical value is an estimated quantity because the Quality Control criteria
were not met.
UJ - The reported quantitation limit is estimated because Quality Control criteria were not met.
Element or compound was not detected.
N J - Estimated value of a tentatively identified compound. (Identified with a CAS number.)
ORGANICS analysis only.
U - The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
U2589m Inorganic -14
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Data Validation Report
ACRONYMS
AA Atomic Absorption
Ag Silver
CCB Continuing Calibration Blank
CCV Continuing Calibration Verification
CFR Code of Federal Regulations
CLP Contract Laboratory Program
CRA CRDL standard required for AA
CRDL Contract Required Detection Limit
CRI . CRDL standard required for ICP
CV Cold Vapor
EPA U.S. Environmental Protection Agency
GFAA Graphite Furnace Atomic Absorption
Hg Mercury
ICB Initial Calibration Blank
ICP Inductively Coupled Plasma
ICS Interference Check Sample
ICSA Interference Check Sample (Solution A)
ICSAB Interference Check Sample (Solution AB)
ICV Initial Calibration Verification
IDL Instrument Detection Limit
LCS Laboratory Control Sample
LRA Linear Range Verification Analysis
MSA Method of Standard Additions
PDS Post Digestion Spike
QC Quality Control
RPD Relative Percent Difference
RPM Regional Project Manager
RSD Percent Relative Standard Deviation
SA Spike Added
SAS Special Analytical Services
SDG Sample Delivery Group
SOW Statement of Work
SR Sample Result
SSR Spiked Sample Result
TPO Technical Project Officer
U2589m
Inorganic-15
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SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
y>
V*
tf3
I
Lab Name: COMPUCHEM
งab Code : LIBRTY Case No . :
I
Matrix (soil/water) : SOIL
level (low/med) : LOW
Contract :
SAS No. :
Lab Sample ID:
Date Received:
EPA SAMPLB'WoT 1
S0319/JM1S2
o
SDG No. :
U2589-1
U2589
6/19/02
% Solids: 100.0
I
I
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6300
8.6
114
0.91
0.35
0.24
8330
9.0
4.4
34.2
10200
51.0
4430
298
7.5
1580
0.30
0.05
176
0.22
9.6
67.6
C
B
B
B
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U
LC
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
-J-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code : LIBRTY Case No . :
Contract :
S04002WNA1
SAS No.: SDG No.: U2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: U2589-2
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
| Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4990
3.0
116
0.71
0.29
0.08
7690
6.7
3.4
26.5
7950
323
4220
276
6.2
1490
0.29
0.05
190
0.21
8.8
84.3
C
B
B
B
B
U
B '
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ab Name: COMPUCHEM
Lab Code: LIBRTY
Case No . :
Contract:
SAS No.:
Jatrix (soil/water): SOIL
Level (low/med) : LOW
Solids: 100.0
S04002WSD1
Sample ID :
e Received:
SDG No . :
U2589-3
6/19/02
U2589
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
| 7439-96-5
| 7440-02-0
| 7440-09-7
7782-49-2
[ 7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7220
153
91.4
47.5
0.46
4.8
2110
7.3
4.9
32.8
15000
866
2770
501
7.3
1230
0.37
7.6
1590
0.21
9.4
828
C
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
"if
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
jab Code: LIBRTY Case No. :
Contract:
S04003ESE1
SAS No.: SDG No.: U2589
totrix (soil/water): SOIL
^evel (low/med): LOW
% Solids: 100.0
Lab Sample ID: U2589-4
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5 |
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
| Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6840
286
110
108
0.35
16.2
3450
9.3
4.2
42.6
22000
2130
4130
996
9.0
1280
0.79
16.5
4110
0.21
10.8
2550
C
B
u
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
0
0
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Tex ture: MEDIUM
Artifacts:
Form I - IN
S\V84ซ
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Data Validation Report
REGION Vm
DATA VALIDATION REPORT
INORGANIC
0203-0008
Tien Nguyen
Cpiitracto*:Laboratory ;
CompuChem - Liberty
d*r\orir\v \H7ocrfA 17/tsvL-
Superior Waste Rock
> ;C6ntract$Jioi;-'-'
Not Indicated
T2589
Review Assigned Date July 5. 2002
Review Completion Date July 19.2002
Data Validator Lisa Tvson
Report Reviewer Bill Fear
! Sample Niiinber
S0201SP1S3
S02021S1S2
S0202CE1S1
S0205AL1S2
S02061S1S2
S02063W1S2
S0208CE1S1
S0200CEEA1B
S0208MN1S2
S0208MN1S3
S0209RW1S1
S02111S1S1
S0213SP1S2
&.'M*ti6ij*ifiw1if:-tf
T2589-1
T2589-2
T2589-3
T2589-4
T2589-5
T2589-6
T2589-7
T2589-8
T2589-9
T2589-10
T2589-11
T2589-12
T2589-13
XRFCups
Metals by SW-846 Method 6010
T2589m
Inorganic - 1
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Data Validation Report
Sample Number
S0225FC1S2
S03003ESD1
S03003SED1
S0300SPEC1
S0306AR1S3
S0311MA1S2
S0400EM1S1
Laboratory ID
T2589-14
T2589-15
T2589-16
T2589-17
T2589-18
T2589-19
T25 89-20
V ";;V7;lV^tra^:^^
XRF Cups
Metals by SW-846 Method 6010
T2589m
Inorganic - 2
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DATA QUALITY STATEMENT
( ) Data are ACCEPTABLE according to EPA Functional guidelines with no qualifiers (flags) added
by the reviewer.
() Data are UNACCEPTABLE according to EPA Functional Guidelines.
(X ) Data are acceptable with QUALIFICATIONS noted in review.
Telephone/Communication Logs Enclosed? Yes No X
TPO Attention Required? Yes X No If yes, list the items that require attention:
Matrix spike, duplicate, and serial dilution analyses were not provided with this SDG. Although no
qualification was taken, it should be noted that matrix specific effects could not be evaluated for
these analyses.
T2589m Inorganic - 3
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Data Validation Report
INORGANIC DATA VALIDATION REPORT
REVIEW NARRATIVE SUMMARY
This data package was reviewed according to "USEPA Contract Laboratory Program National Functional
Guidelines for Inorganic Data Review," February 1994, and modified for the method used.
Raw data were reviewed for completeness and transcription accuracy onto the summary forms.
Approximately 10-20% of the results reported in each of the samples, calibrations, and QC analyses were
recalculated and verified. If problems were identified during the.recalculation of results, a more thorough
calculation check was performed.
SDG No. T2589 consisted of 20 XRF cup samples for metals analyses by SW-846 Method 6010.
The. following table lists the data qualifiers added to the sample analyses. Please see Data Qualifier
Definitions, attached to the end of this report.
Ir^'%;- : .Sample ID? ._ , , .,,:'.
S0200CEEA1B
S02021S1S2, S0205AL1S2,
S02063W1S2, S0300SPEC1,
S03 1 1 MA 1 S2, S0400EM 1 S 1
S0201SP1S3.S02061S1S2,
S02063W1S2, S0208CE1S1,
S0208MN1S2, S0208MN1S3,
S0225FC1S2, S03003ESD1,
S03003SED1, S0300SPEC1,
S0306AR1S3
S0202CE1S1.S0208CE1S1,
S02111S1S1.S03003ESD1,
S03003SED1.S0306AR1S3
S0200CEEA1B
S0208MN1S3
Elements; .^
Calcium
Zinc
Antimony
Beryllium
Cadmium
Barium
Chromium
Magnesium
Nickel
Potassium
Vanadium
Thallium
J/UJ
U
J
?&ij^^i^^^^^^Sง
Negative Blank
Contamination
Blank Contamination
ICSA solution result
greater than the IDL
and elevated iron
sample level
VII
VIII
T2589m
Inorganic - 4
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Method/SOW Number 6010/SW-846
Revision 0.0
Inorganic Deliverables Completeness Checklist
P Inorganic Cover Page
P Inorganic Analysis Data Sheets
P Initial Calibration and Calibration Verification Results
P Continuing Calibration Verification Results
P CRDL Standard for ICP and AA
P Blank Analysis Results
P ICP Interference Check Sample Results
NP Spiked Sample Results
P Post-digest Spiked Sample Analysis
NP Duplicate Sample Results
P Instrument Detection Limits
P Laboratory Control Sample results
NA Standard Addition Results
NP ICP Serial Dilution Results
NA Holding Times Summary Sheet
P ICP Interelement Correction Factors
P ICP Linear Ranges
R Raw Data
R Samples P Calibration Standards R Blanks NA Spikes
NA Duplicates R ICP QC (ICS and Serial Dilution) P LCS
NA Furnace AA NA Mercury Analysis NA Cyanide Analysis
NA Percent Solids Calculations - Solids Only
P Sample Prep/Digestion Logs (Form XIII)
P Analysis Run Log (Form XIV)
P Chain-of-Custody
P Sample Description
P Case Narrative
P Method References
KEY:
P = Provided in original data package, as required by the SOW
R = Provided as Resubmission
NP = Not provided in original data package or as resubmission
NR = Not required under the SOW
NA = Not applicable to this data package or analysis
T2589m Inorganic - 5
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I. DELIVERABLES
All deliverables were present.
Yes No X
Comments: Raw data information was not provided for the 06/24/02 analytical run. This
information was located and reviewed in another SDG associated with this project.
n. HOLDING TIMES AND PRESERVATION CRITERIA
All holding times and preservation criteria were met.
Yes X No
Comments: All samples were analyzed within required holding times. Chain-of-custody
(COC), summary forms, and raw data were evaluated. The XRF cup samples were
received outside temperature requirements. No action was taken because the
Functional Guidelines do not provide specific guidance for temperature and the
effect on the sample integrity is not known.
ffl. INSTRUMENT CALIBRATIONS: STANDARDS ANB BLANKS
Initial instrument calibrations were performed according to method requirements.
Yes X No
Comments: None.
The instruments were calibrated daily and each time an analysis run was performed.
Yes X No
Comments: None.
The instruments were calibrated using one blank and the appropriate number of standards.
Yes X No
Comments: None.
T2589m Inorganic - 6
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W. FORM 1 - SAMPLE ANALYSIS RESULTS
Sample analyses were entered correctly on Form Is.
Yes X No
Comments: None.
V. FORM 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION
The initial and continuing calibration verification standards (ICV and CCV, respectively) met
I method requirements.
I
Yes X No
Comments: None.
i
The calibration verification results were within 90-110% recovery for metals, 85-115% for cyanide,
and 80-120% for mercury.
* Yes X No
Comments: None.
I The continuing calibration standards were run at 10% frequency.
Yes X No
I Comments: None.
I VI. FORM 2B - CRDL STANDARD FOR ICP AND AA
IICP Analysis: Standards (CRI) at two times the CRDL or the IDL (whichever were greater) were
analyzed at the beginning and the end of each sample run, or at a minimum of twice per eight hours,
whichever was more frequent.
I Yes X No
I Comments: None.
I
T2589m Inorganic - 7
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GFAA Analysis: Standards (CRA) at two times CRDL were analyzed at the beginning of each
sample run.
Yes _ No _ NA X
Comments: Samples were not analyzed by GFAA.
The CRI and/or the CRA were analyzed after the ICV.
Yes X No _
Comments: None.
FORM 3 - BLANKS
The initial and continuing calibration blanks (ICB and CCB, respectively) met method requirements.
Yes X No _
Comments: None.
The continuing calibration blanks were run at 10% frequency.
Yes X No _
Comments: None.
A laboratory/preparation blank was run at the frequency of one per twenty samples, or per sample
delivery group (whichever is more frequent), and for each matrix analyzed.
Yes X No _
Comments: None.
All analyzed blanks were free of contamination.
Yes _ No X
Comments: The following table lists the blanks with contamination that resulted in sample
qualification, elements present, affected samples, and data qualifiers:
T2589m Inorganic - 8
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Blank Contaminants
Blank DX
PB
CCB
ICB
CCB
CCB
CCB
CCB
CCB
CCB
CCB
' Contaminant.:
Potassium
Antimony
Calcium
Zinc
Barium
Beryllium
Cadmium
Chromium
Magnesium
Nickel
Vanadium
Concentration Found ln;;
1.677
0.2
0.22
-6.17
-0.47
0.09
0.07
0.04
0.06
3.94
0.12
0.1
:: Associated Samples ' .
S0200CEEA1B
S02021S1S2
S0205AL1S2
S02063W1S2
S0300SPEC1
S0311MA1S2
S0400EM1S1
S0200CEEA1B
S0200CEEA1B
S0200CEEA1B
S0201SP1S3
S02061S1S2
S02063WIS2
S0208CE1S1
S0208MNIS2
S0208MN1S3
S0225FC1S2
S03003ESD1
S03003SED1
S0300SPEC1
S0306AR1S3
S0202CE1S1
S0208CE1S1
S02111S1S1
S03003ESD1
S03003SED1
S0306AR1S3
S0200CEEA1B
S0200CEEA1B
S0200CEEA1B
S0200CEEA1B
U ;; -^/'. tfซ I;..-. ; -"/; "* ^j'-'i; -7C
4 ? .Coricehtratlbn Founil li&
~y** l-ft?'- ^ *'*'"/ :''* ""/t^*?\"55*-*SP"
^ ,3.'.i;.' Sample (itig/lcgy.y^t-^--
7.8
0.99
0.35
0.95
0.68
1.0
0.40
29.4
0.14 U
0.28
0.34
0.33
0.24
0.35
0.33
0.20
0.33
0.31
0.31
0.23
0.32
0.16
0.18
0.17
0.15
0.12
0.05
0.18
17.3
0.10
0.13
U
J
UJ
U
The incorrect results for antimony and selenium were reported on the Form 3 for the
ICB. The raw data value for selenium was less than the IDL rather than 2.2 as
reported and the raw data value for antimony was 1.6 ug/L rather than 2.5 ug/L.
T2589m
Inorganic - 9
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FORM 4 - ICP INTERFERENCE CHECK SAMPLE
The ICP interference check sample (ICS) was run twice per eight hour shift and/or at the beginning
and end of each sample set analysis sequence (whichever is more frequent).
Yes X
Comments:
No
None.
Percent recovery of the analytes in solution ICSAB were within the range of 80-120%.
Yes X No
Comments: None. .
Sample results for aluminum, calcium, iron, and magnesium were less than the ICSA values.
Yes No X
Comments: The following sample results were qualified because the iron result was greater than
the ICSA value and the absolute value of the associated element was greater than
the IDL in the ICSA analysis:
.;:; Element
ir";; ~_: "_ . -.--:.. ~: . '
-.':
Thallium
1GS A Result
fiip/I1' \ ' ' ' '
V ._ ir1-. ../--.' -
7
; : npti
( IIP/I 'I '""!
. .V & ../-.
3.3
._:; : :: .";;._"', .'.-.: SampBes;. Affected: jv ;:;. ;:.:';; }^/.L
.. -t . : .'r -' :. .: .'.'':.:'.' .f '.'"'' l. ' - ._.': ..! ' T :/: .;.. .=' .: .. .. . .1' ' '
-. - . ..:.-..:-.-:,: :.:-.;.:::.. - ' ~ ' ':. ; .
S0208MN1S3
tiQijiiiMKrif
| !::! ,.i.i| :.'.,'. '][;'. i ; . , ' ;: ; : >
-..:,.'. .- .. .'.: .:!/.:
J
IX. FORM 5A - MATRIX SPIKE SAMPLE ANALYSIS
A matrix spike sample was analyzed with every twenty or fewer samples of a similar matrix, or one
per sample delivery group (whichever is more frequent).
Yes No X
Comments: A matrix spike sample was not analyzed with this SDG. Therefore, the effect of the
sample matrix on the sample preparation procedures and the measurement
methodology could not be evaluated.
0
T2589m
Inorganic- 10
1
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uos
URS Operating Services, Inc. Data Validation Report
The percent recoveries (%R) were calculated correctly.
% Recovery = ^SSR " SR) X 100 SSR = spiked sample result
SA SR = sample result
SA = spike added
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
Spike recoveries were within 75-125% (an exception is granted where the sample concentration is
four times the spike concentration).
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
X. FORM SB - POST DIGEST SPIKE RECOVERY
A post-digest spike was performed for those elements that did not meet the specified criteria (i.e.,
pre-digestion/pre-distillation spike recovery falls outside of control limits and sample result is less
than four times the spike amount added, exception: Ag, Hg).
Yes No NA X
Comments: A post digestion spike was not analyzed with this SDG.
XI. FORM 6 - DUPLICATE SAMPLE ANALYSIS
Duplicate sample analysis was performed with every twenty or fewer samples of a similar matrix,
or one per sample delivery group (whichever is more frequent).
Yes No X
Comments: Duplicate sample analyses were not provided with this SDG. Therefore, precision
could not be evaluated.
The RPDs were calculated correctly.
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
T2589m Inorganic - 11
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uos
URS Operating Services, Inc. _ Data Validation Report
: -
For sample concentrations greater than five times the CRDL, RPDs were within ฑ20% (limits of
ฑ35% apply for soil/sediments/tailings samples).
Yes _ No _ NA X
Comments: Duplicate sample analyses were not provided with this SDG.
For sample concentrations less than five times the CRDL, duplicate analysis results were within the
control window of ฑ CRDL (two times CRDL for soils).
Yes _ No _ NA X
Comments: Duplicate sample analyses were not provided with this SDG.
XH. GFAA QC
Duplicate injections were performed on all GFAA samples and the RSD was within ฑ 20%.
Yes _ No _ NA X
Comments: Samples were not analyzed by GFAA.
Analytical spikes were performed on all GFAA samples and the percent recovery was 85 - 115%.
Yes _ No _ NA X
Comments: Samples were not analyzed by GFAA.
MSAs were analyzed when required and the correlation coefficient was > 0.995.
Yes _ No _ NA X
Comments: None.
FORM 7 - LABORATORY CONTROL SAMPLE
The laboratory control sample (LCS) was prepared and analyzed with every twenty or fewer samples
of a similar matrix, or one per sample delivery group (whichever is more frequent).
Yes X No _
Comments: None.
T2S89m Inorganic - 12 *
I
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_ uos
I URS Operating Services, Inc. Data Validation Report
w
1
1
1
1
1
1
1
All results were within control limits.
Yes X No
Comments: None.
XIV. FORM 8 -STANDARD ADDITION RESULTS
Results from graphite furnace standard additions were entered on Form VIII as directed in the SOW.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
XV. FORM9-ICPQC
A serial dilution was performed for 1CP analysis with every twenty or fewer samples of a
matrix, or one per sample delivery group, whichever is more frequent.
Yes No X
Comments: Serial dilutions were not provided with this SDG. Therefore, it could
similar
not be
determined whether or not significant physical or chemical interferences exist due
to sample matrix in ICP metals.
The serial dilution was without interference problems as defined by the method.
Yes No NA X
Comments: Serial dilutions were not provided with this SDG.
XVI. FORM 10 - QUARTERLY INSTRUMENT DETECTION LIMITS (IDL)
IDLs were provided for all elements on the target analyte list.
Yes X No
Comments: None.
T2589m Inorganic- 13
-------
uos
(JRS Operating Services, Inc. Data Validation Report
XVn. FORM 11 - INTERELEMENT CORRECTION FACTORS FOR HCP
Interelement corrections for ICP were reported.
Yes X No
Comments: None.
XVm. FORM 12 - ICP LINEAR RANGES
ICP linear ranges were reported.
Yes X No
Comments: None.
XIX. LINEAR RANGE VERIFICATION ANALYSIS
Linear Range Verification Analysis (LRA) was performed and results were within control limits of
5% of the true value.
Yes No NA X
Comments: None.
XX. FORM 13 - PREPARATION LOG
Information on the preparation of samples for analysis was reported.
Yes X No
Comments: None.
XXI. FORM 14 - ANALYSIS RUN LOG
The required information was filled out for each analysis run in the data package.
Yes X No
Comments: None.
T2589m Inorganic - 14
-------
uos
jj URS Operating Services, Inc. Data Validation Report
XXII. Additional Comments or Problems/Resolutions Not Addressed Above
I
I
Yes No X
Comments: None.
T2589m Inorganic - 15
-------
uos
URS Operating Services, Inc. Data Validation Report
INORGANIC DATA QUALITY ASSURANCE REVIEW
Region Vm
DATA QUALIFIER DEFINITIONS
For the purpose of Data Validation, the following code letters and associated definitions are provided for use
by the data validator to summarize the data quality. Use of additional qualifiers should be carefully
considered. Definitions for all qualifiers used should be provided with each report.
GENERAL QUALIFIERS for use with both INORGANIC amd ORGANIC DATA
R - Reported value is "rejected." Resampling or reanalysis may be necessary to verify the
presence or absence of the compound.
J - The associated numerical value is an estimated quantity because the Quality Control criteria
were not met.
U J - The reported amount is estimated because Quality Control criteria were not met. Element or
compound was not detected.
N J - The analysis indicates the presence of an analyte that has been "tentatively identified" and the
associated numerical value represents its approximate concentration.
N - The analysis indicates the presence of an analyte for which there is presumptive evidence to
make a tentative identification.
U - The material was analyzed for, but was not-detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
T2589m Inorganic-16
1
-------
I
I
I
I
I
I
I
uos
URS Operating Services, Inc.
Data Validation Report
ACRONYMS
AA Atomic Absorption
Ag Silver
CCB Continuing Calibration Blank
CCV Continuing Calibration Verification
CFR Code of Federal Regulations
CLP Contract Laboratory Program
CRA CRDL standard required for AA
CRDL Contract Required Detection Limit
CRI CRDL standard required for ICP
CV Cold Vapor
EPA U.S. Environmental Protection Agency
GFAA Graphite Furnace Atomic Absorption
Hg Mercury
ICB Initial Calibration Blank
ICP Inductively Coupled Plasma
ICS Interference Check Sample
ICSA Interference Check Sample (Solution A)
ICSAB Interference Check Sample (Solution AB)
ICV Initial Calibration Verification
IDL Instrument Detection Limit
LCS Laboratory Control Sample
LRA Linear Range Verification Analysis
MSA Method of Standard Additions
PDS Post Digestion Spike
QC Quality Control
RPD Relative Percent Difference
RPM Regional Project Manager
RSD Percent Relative Standard Deviation
SA Spike Added
SAS Special Analytical Services
SDG Sample Delivery Group
SOW Statement of Work
SR Sample Result
SSR Spiked Sample Result
TPO Technical Project Officer
T2589m
Inorganic- 17
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
1
jab Name: COMPUCHEM
lab Code : LIBRTY Case No . :
Contract:
S0201SP1S3
SAS No.: SDG No.: T2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: T2589-1
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5.
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6 |
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7230
190
140
173
0.34
3.3
7330
7.3
3.6
27.3
11400
1620
2420
364
5.5
1220
0.37
7.6
14.3
0.32
12.2
804
C
B
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SXV846
-------
SW846-METALS
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
jab Name: COMPUCHEM
Lab Code: LIBRTY Case No. :
latrix (soil/water) : SOIL
Level (low/med): LOW
% Solids: 100.0
Contract:
SAS No.:
S02021S1S2
SDG No.: T2589
Lab Sample ID: T2589-2
Date Received: 6/19/02
Concentration Units (ug/L or ing/kg dry weight) : MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4 |
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6960
3.7
115
0.99
0.36
0.42
1900
9.8
3.5
11.9
8860
31.9
2830
222
6.0
1780
0.30
0.07
113
0.33
10.6
69.6
C
B
B
B
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
44-
Fora I - IN
SW84ซ
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0202CE1S1
SDG No.: T2589
Matrix (soil/water): SOIL
Level (low/med) : LOW
k
Lab Sample ID: T2589-3
Date Received: 6/19/02
Solids: 100.0
Concentration Units (ug/L or mg/kg dry weight): MG/KG
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
9360
5.7
121
1.2
0.41
0.16
2850
7.9
4.0
13.7
11000
54.8
2880
370
7.1
1670
0.26
0.07 |
128 |
0.32 |
14.5 |
89.8
C
B
*
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0205AL1S2
SDG No.: T2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: 12589-4
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0 |
7440-62-2
7440-66-6 |
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6850
6.6
106
0.35
0.40
0.03
3340
7.9
6.1
16.6
10100
14.6
3430
297
6.7
1380
0.49
0.07
102
0.32
9.8
46.5
C
B
B
U
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S02061S1S2
SDG No.: T2589
Platrix (soil/water) : SOIL
rvel (low/med) : LOW
Solids: 100.0
Lab Sample ID: T2589-5
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6650
5.7
259
1.4
0.33
2.2
1850
9.3
3.7
10.8
8660
523
2580
297
6.1
1200
0.48
0.12
14.4
0.33
12.3
1130
C
B
B
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture: FINE
Artifacts:
4-4
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ab Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S02063W1S2
SDG No.: T2589
atrix (soil/water): SOIL
evel (low/med):
Solids: 100.0
Lab Sample ID: T2589-6
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4670
6.5
72.5
0.95
0.24
0.30
6110
6.2
4.3
16.0
8800
59.7
3400
217
7.3
1110
0.36
0.10
163
0.33
8.6
99.9
C
B
B
B
i
B
B
B
u
Q
,
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
^X-
J
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
x/r
o l
Texture: FINE
Artifacts:
Form I - IN
S\V84ซ
-------
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
1
Lab Name :
Lab Code :
COMPUCHEM
LIBRTY Case No . :
Contract :
hif A SAMPLE NO .
S0208CE1S1
SASNo.: SDGNo.: T2589
Matrix (soil/water): SOIL
level (low/med) :
% Solids: 100.0
Lab Sample ID: T2589-7
I
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6 |
Analyte
Aluminum
| Arsenic
| Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
8300
5.4
136
1.8
0.35
0.18
4040
7.1
3.6
12.1
9.950
47.1
2960
350
5.7
1260
0.46
0.36
109
0.33
12.9
121
C
B
B
B
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Texture:
Artifacts:
FINE
Comments:
ifr
Form I - IN
SW846
-------
SW846-IN i L. i ALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ab Name: COMPUCHEM
,ab Code: LIBRTY Case No. :
atrix (soil/water): SOIL
ซvel (low/med): LOW
; Solids: 100.0
Contract:
SAS No.:
S0200CEEA1B
SDG No.: T2589
Lab Sample ID: T2589-8
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concen tr a ti on
123
0.41
0.28
0.16
0.02
0.03
29.4
0.18
0.06
0,30
56.1
0.38
17.3
1.2
0.10
7.8
0.21
0.07
155
0.32
0.13
0.14
C
IU
B
IU
U
U
B
IB
U
B
B
B
B
u
u
B
"
B
U
Q
*
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
CT
Color Before: WHITE
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW84I
-------
I
I
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0208MN1S2
rrix (soil/water) : SOIL
el (low/med):
Solids: 100.0
I
I
I
I
I
LOW
Lab Sample ID:
Date Received:
SDG No.: T2589
T2589-9
6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
| 7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6790
127
103
44.6
0.33
2.6
2680
6.9
3.5
14.1
11200
959
3290
348
5.7
1150
0.39
11.4
14.3
0.32
9.8
443
C
B
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0208MN1S3
SDG No.: T2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: T2589-10
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MS/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0 |
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
3080
2620
48.5
2360
0.20
30.1
1070
3.4
3.6
85.4
63200
16700
1720
1600
6.2
749
2.3
191
292
2.5
5.0
6170
C
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
\J
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
I
I
I
t
r
i
i
\
i
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
!Name : COMPUCHEM
Code : LIBRTY Case No . :
Contract:
S0209RW1S1
SAS No. : SDG No. : T2589
ix (soil/water): SOIL
1 (low/med) :
lids: 100.0
LOW
Lab Sample ID: T2589-11
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
| Arsenic
Barium
| Antimony
| Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6000
26.3
176
5.7
0.44
1.2
12200
8.2
4.7
18.3
10900
216
3610
355
7.0
1120
0.53
0.65
162
0.33
10.0
267
C
B
B
u
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
jab Name: COMPUCHEM
Lab Code: LIBRTY Case No. :
Jatrix (soil/water) : SOIL
Level (low/med) : LOW
% Solids: 100.0
Contract:
SAS No.:
S02111S1S1
SDG No.: T2589
Lab Sample ID: T2589-12
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2 |
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
11400
6.9
485
2.1
0.58
0.17
6920
9.1
4.4
25.3
12800
89.1
3810
274
10.2
1290
0.59
0.15
392
0.32
19.8
141
C
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
(Jl
Texture: FINE
Artifacts :
Form I - IN
SW84
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
.]
b Name: COMPUCHEM
to Code: LIBRTY Case No.:
Contract:
S0213SP1S2
SAS No . : SDG No . : T2589
itrix (soil/water): SOIL
Ivel (low/med) :
Solids: 100.0
LOW
Lab Sample ID: T2589-13
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
| Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration'
7460
9.2
129
2.5
0.36
0.29
3770
7.0
3.7
18.9
9560
82.1
3130
342
7.0
1310
0.40
0.29
131 |
0.33
10.8
105
C
B
B
B
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
*/
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Jab Name: COMPUCHEM
Lab Code: LIBRTY Case No. :
latrix (soil/water) : SOIL
L,evel (low/med) : LOW
% Solids: 100.0
Contract :
SAS No. :
Lab Sample ID:
Date Received:
S0225FC1S2
SDG No . :
T2589-14
T2589
6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5 |
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concen tra ti on
8920
362
126
63.5
0.33
9.6
3100
5.1
3.5
20.1
18900
1680
3020
810
6.3
1290
0.94
14.8
14.6
0.33 |
11.1
1470 |
C
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Comments:
Form I - IN
SW84
-------
I
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
I
ฑ> Name: COMPUCHEM
ง3 Code : LIBRTY Case No . :
|trix (soil/water) : SOIL
I/el (low/med) : LOW
Solids: 100.0
Contract :
SAS No. :
Lab Sample ID :
Date Received:
S03003ESD1
SD6 No . :
T2589-15
T2589
6/19/02
I
I
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5460
10.6
98.2
2.4
0.31
0.15
5470
6.3
3.3
10.3
8370
48.1
3150
220
5.8
997
0.24
0.19
115
0.32
9.2
79.0
C
B
B
I,
B
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
> Name: COMPUCHEM
Code: LIBRTY
Case No.:
Contract:
SAS No.:
S03003SED1
SDG No.: T2589
nix (soil/water): SOIL
rel (low/med):
Solids: 100.0
Lab Sample ID: T2589-16
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
| Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6830
3.8
101
1.2
0.31
0.12
2860
7.0
3.9
14.2
9210
209
3260
244
7.2
1570
0.23
0.07
121
0.32
11.1
80.2
C
B
B
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ปb Name: COMPUCHEM
m Code: LIBRTY Case No. :
itrix (soil/water): SOIL
mel (low/med) :
Solids: 100.0
Contract:
SAS No. :
S0300SPEC1
SDG No.: T2589
LOW
Lab Sample ID: T2589-17
Date Received: 6/19/02
I
I
I
I
I
I
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
| Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concen tra ti on
4110
6.2
99.9
0 . 68
0.23
0.03
9400
7.2
3.5
10.4
7720
27.1
4070
196
6.5
992
0.21
0.07 |
98.9
0.32
7.0
35.3 !
C
B
B
"
U
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: MEDIUM
Artifacts:
QET
Form I - IN
SW846
-------
SW846-METALS
-1-
EVORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
b Name: COMPUCHEM
ปb Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0306AR1S3
SDG No. : T2589
itrix (soil/water): SOIL
svel (low/med) :
Solids: 100.0
Lab Sample ID: T2589-18
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
.7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4 |
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6450
22.0
97.5
1.5
0.32
0.05
5140
8.5
4.2
13.8
10400
179
4750
372
7.5
1370
0.36
1.1
111
0.33
8.6
123
C
B
B
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0311MA1S2
SDG No.: T2589
ttrix (soil/water): SOIL
(vel (low/med): LOW
Solids: 100.0
Lab Sample ID:
Date Received:
T2589-19
6/19/02
Concentration Units (ug/L or zng/kg dry weight): MG/KG
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4 |
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0 |
7440-62-2
7440-66-6 1
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concen tra ti on
13300
5.7
171
1.0
0.48
0.03
3620
8.3
5.6
17.2
13200
31.1
3570
547
8.4
1250
0.66
0.07
119
0.32
17.5
67.3
C
B
u
u
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
J
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ib Name: COMPUCHEM
ab Code: LIBRTY
Case No.:
Contract:
SAS No. :
S0400EM1S1
SDG No.: T2589
atrix (soil/water): SOIL
3vel (low/med):
Solids: 100.0
Lab Sample ID: T2589-20
LOW
Date Received: 6/19/02
Concentration Units (ug/L or rag/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
'Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
10900
4.6
113
0.40
0.41
0.03
2620
6.1
4.5
14.4
13200
11.3
3390
393
7.3
1190
0.45
0.07
120 |
0.33
10.6
34.5
C
B
B
U
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW84
-------
I
I
I
uos
URS Operating Services, Inc.
Data Validation Report
REGION VIII
DATA VALIDATION REPORT
INORGANIC
riil^l^iWf^
0203-0008
^'^^:f^^i^^t^0^i^^'^
Tien Nguyen
'.' - ^Contractor Laboratory " '; -v
CompuChem-Liberty
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Superior Waste Rock
^;.Ci,ntraSivp;-:3i
Not Indicated
'^'s^m^
S2589
^"'^"'-'Opc^bleilJiiiit^S^i''^^ ;-.
j :.:'' '...';y:jv:.i;;?i'.''Vi-vi ,'.- ''^N;/;^
: Labbratory DJPOmegion ;.
Review Assigned Date July 5. 2002
Data Validator Bill Fear
Review Completion Date July 19. 2002
.Report Reviewer Ken Schroeder
Sample Number
. Laboratory ID
Matrix
Analysis
S0400HT4S1
S0400ILEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWF1
S04032W1S3
S0404ALIS3
S0043MW1S2
S01007SWB1
S2589-1
XRFCups
Metals by SW-846 Method 6010
S2589-2
S2589-3
S2589-4
S2589-5
S2589-6
S2589-7
S2589-8
S2589-9
S2589-10
S2589-11
S2589-12
S2589-13
S2589m
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Sample lumber
.':' Labbratory-JDli '
aSftSBSi&jftgjI
^JZ^?M>iiฃ*f23ฃM.%
S01063W1D1
S0106CE1S3
S01071S1S1
S02003ESD1
S0200CEEG1
S0200MNSDX
S0200MNSG1
S2589-14
XRFCups
Metals by SW-846 Method 6010
S2589-15
S2589-16
S2589-17
S2589-18
S2589-19
S2589-20
S2589TO
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DATA QUALITY STATEMENT
() Data are ACCEPTABLE according to EPA Functional guidelines with no qualifiers (flags) added
by the reviewer.
() Data are UNACCEPTABLE according to EPA Functional Guidelines.
(X ) Data are acceptable with QUALIFICATIONS noted in review.
Telephone/Communication Logs Enclosed? Yes No X
TPO Attention Required? Yes X No If yes, list the items that require attention:
Matrix spike, duplicate, and serial dilution analyses were not provided with this SDG. Although no
qualification was taken, it should be noted that matrix specific effects could not be evaluated for
these analyses.
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INORGANIC DATA VALIDATION REPORT
REVIEW NARRATIVE SUMMARY
This data package was reviewed according to "USEPA Contract Laboratory Program National Functional
Guidelines for Inorganic Data Review," February 1994, and modified for the method used.
Raw data were reviewed for completeness and transcription accuracy onto the summary forms.
Approximately 10-20% of the results reported in each of the samples, calibrations, and QC analyses were
recalculated and verified. If problems were identified during the recalculation of results, a more thorough
calculation check was performed.
SDG No. S2589 consisted of 20 XRF cup samples for metals analyses by SW-846 Method 6010.
The following table lists the data qualifiers added to the sample analyses. Please see Data Qualifier
Definitions, attached to the end of this report.
1; Sample ID
S04032W1S3
S0400HT4S1, S0400ILEE1,
S0400MNSC1, S0400SPEC1,
S0400SPEDX, S0400SPEE1,
S0400SPEF1, S0400SPWF1,
S04032W1S3, S0404AL1S3,
S0043MW1S2, S01007SWB1,
S01071S1S1, S02003ESD1,
S0200CEEG1, S0200MNSDX,
S0200MNSG1
S0404AL1S3, S01071S1S1
S0400ILEE1, S0400MNSC1,
S0400SPEC1, S0400SPEDX,
IS0400SPEE1, S0400SPEFJ,
S0400SPEG1, S0400SPWF1,
S0404AL1S3, S0043MW1S2,
S01007SWB1, S01063W1D1,
S01071S1S1.S02003ESD1,
S0200CEEG1, S0200MNSDX,
S0200MNSG1
S0404AL1S3, S01007SWB1,
S01063W1D1, S0106CE1S3,
S01071S1S1,S02003ESD1,
S0200CEEG1
Elements
Sodium
Beryllium
Cadmium
Selenium
Sodium
/j:Q"SliHeirei's:C;
71. 5 U
mg/Kg
U
L,.:, J-^i'^-Syr^i^^M
^^ma^m^m
. :.: -* ..^r:.-.-ซV.-^BSซ-.S.5>,iซ':Ji:.*;
;r ' .QyaJjfiiifio&iEnB
Result not adjusted
for dilution (5x)
Blank Contamination
:5>;;:V;,i-:;SS^.:^:^
'^as^a*^
rv
vn
1
S2S89m
Inorganic - 4
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Method/SOW Number 6010/SW-846
Revision 0.0
Inorganic Deliversbles Completeness Checklist
P Inorganic Cover Page
P Inorganic Analysis Data Sheets (Form I)
P Initial Calibration and Calibration Verification Results (Form II)
P Continuing Calibration Verification Results (Form II)
P CRDL Standard for ICP and AA (Form H, Part 2)
P Blank Analysis Results (Form ffl)
P ICP Interference Check Sample Results (Form IV)
NP Spiked Sample Results (Form V)
NP Post-digest Spiked Sample Analysis (Form V, Part 2)
NP Duplicate Sample Results (Form VI)
P Instrument Detection Limits (Form VH) or (Form X - Quarterly)
P Laboratory Control Sample results (Form VII)
NA Standard Addition Results (Form VIS).
NP ICP Serial Dilution Results (Form DC)
NA Holding Times Summary Sheet (Form X)
P ICP Interelement Correction Factors (Form XII - Quarterly, or Form XI - Annually)
P ICP Linear Ranges (Form XII (XU) - Quarterly)
P Raw Data
P Samples P Calibration Standards P Blanks _NA Spikes
NA Duplicates P ICP QC (ICS and Serial Dilution P LCS
NA Furnace AA NA Mercury Analysis NA Cyanide Analysis
NA Percent Solids Calculations - (Solids Only)
P Sample Prep/Digestion Logs (Form XIII)
P Analysis Run Log (Form XTV)
P Chain-of-Custody
P Sample Description
P Case Narrative
P Method References
KEY:
P = Provided in original data package, as required by the SOW
R = Provided as Resubmission
NP = Not provided in original data package or as resubmission
MR = Not required under the SOW
NA = Not applicable to this data package or analysis
S2589m Inorganic - 5
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I. DELIVERABLE^
All deliverables were present.
Yes X No
Comments: None.
II. HOLDING TIMES AND PRESERVATION CRITERIA
All holding times and preservation criteria were met.
Yes X No
Comments: All samples were analyzed within required holding times. Chain-of-custody
(COC), summary forms, and raw data were evaluated. The XRF cup samples were
received outside temperature requirements. No action was taken because the
Functional Guidelines do not provide specific guidance for temperature and the
effect on the sample integrity is not known.
III. INSTRUMENT CALIBRATIONS: STANDARDS AND!
Initial instrument calibrations were performed according to method requirements.
Yes X No
Comments: None.
The instruments were calibrated daily and each time an analysis run was performed.
Yes X No
Comments: None.
The instruments were calibrated using one blank and the appropriate number of standards.
Yes X No
Comments: None.
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IV. FORM 1 - SAMPLE ANALYSIS RESULTS
Sample analyses were entered correctly on Form Is.
Yes No X
Comments: Various sample results were reported from dilutions. Additionally the non-detected
results for sodium in samples S0400HT4S1 and S04032W1S3 were reported from
dilutions because of negative interference. However, the laboratory did not correct
the sodium result in sample S04032W1S3 to reflect the five times dilution. The
result should be 71.5 U mg/Kg rather than 14.3 U mg/Kg.
V. FORM 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION
The initial and continuing calibration verification standards (ICV and CCV, respectively) met
method requirements.
Yes X No
Comments: None.
The calibration verification results were within 90-110% recovery for metals, 85-115% for cyanide,
and 80-120% for mercury.
Yes X No
Comments: None.
The continuing calibration standards were run at 10% frequency.
Yes X No
Comments: None.
VI. FORM 2B - CRDL STANDARD FOR ICP AND AA
ICP Analysis: Standards (CRT) at two times the CRDL or the IDL (whichever were greater) were
analyzed at the beginning and the end of each sample run, or at a minimum of twice per eight hours,
whichever was more frequent.
Yes X No
Comments: None.
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GFAA Analysis: Standards (CRA) at two times CRDL were analyzed at the beginning of each
sample run.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
The CRI and/or the CRA were analyzed after the ICV.
Yes X No
Comments: None.
VII. FORM 3 - BLANKS
The initial and continuing calibration blanks (ICB and CCB, respectively) met method requirements.
Yes X No
Comments: None.
The continuing calibration blanks were run at 10% frequency.
Yes X No
Comments: None.
A laboratory/preparation blank was run at the frequency of one per twenty samples, or per sample
delivery group (whichever is more frequent), and for each matrix analyzed.
Yes X No
Comments: None.
All analyzed blanks were free of contamination.
Yes No X
Comments: The following table lists the blanks with contamination that resulted hi sample
qualification, elements present, affected samples, and data qualifiers:
Blank Contaminants
S2589m Inorganic - 8
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Data Validation Report
teili*^
CCBII
CCB12
II
II
II
II
II
CCB12
ICB
CCB12
Beryllium
Cadmium
Selenium
Sodium
1 1
. ts-.E.-xMf.-wtr,.: iV'.fyjLi^--.-'--><,A'v!
S ^2^A^i1Hfe^ฃi
: *:ewicenMปiiซiV:J^-IDJsV$.
i j-: vV.'-j-t- "' --*- .-fcvv. JlsViff --w.-'-^s;.
-. ?, ^DdtoBIantep^ingpg
0.9 ug/L
0.8 ug/L
3.3 ug/L
293.4 ug/L
0.2
0.3
2.2
145.8
^Ss^i^ls
^x^&fP
S0400HT4S1
S04001LEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPWF1
S04032W1S3
S0404AL1S3
S0043MW1S2
S01007SWB1
S01071S1S1
S02003ESD1
S0200CEEG1
S0200MNSDX
S0200MNSGI
S0404AL1S3
S01071SIS1
S04001LEE1
S0400MNSC1
S0400SPEC1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWF1
S0404AL1S3
S0043MW1S2
S01007SWB1
S01063W1D1
S01071S1S1
S02003ESDI
S0200CEEG1
S0200MNSDX
S0200MNSG1
S0404AL1S3
S01007SWB1
S01063W1D1
S0106CE1S3
S01071S1S1
S02003ESD1
S0200CEEG1
Ipbui^ia^il
0.18
0.35
0.30
0.29
0.36
0.41
0.31
0.33
0.24
0.35
0.39
0.36
0.35
0.31
0.30
0.36
0.30
0.11
0.06
0.67
0.34
1.4
0.32
0.86
0.49
0.91
0.52
0.61
0.52
0.51
0.53
0.42
0.35
0.45
0.47
0.66
76.7
95.6
104
128
119
124
142
fe^^-ASJostiBent^sSs1'
Ss.VsV^1ls',-ซ's.BV.ป-i.,rs?t
U
The negative values for the blanks were taken from the raw data as the
laboratory was having problems reporting negative results on the Form 3. No
action was required for negative blank contamination found from the raw data as
the sample results were greater than five times the blank values.
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VIII. FORM 4 - ICP INTERFERENCE CHECK SAMPLE
The ICP interference check sample (ICS) was run twice per eight hour shift and/or at the beginning
and end of each sample set analysis sequence (whichever is more frequent).'
Yes X No
Comments: None.
Percent recovery of the analytes in solution ICSAB were within the range of 80-120%.
Yes X No
Comments: None.
Sample results for aluminum, calcium, iron, and magnesium were less than the ICSA values.
Yes No X
Comments: The iron results were greater than the ICSA value in samples S0400HT4S1,
S0400SPEC1, and S04032W1S3. However no action was required as interference
was not noted in these samples.
IX. FORM 5A - MATRIX SPIKE SAMPLE ANALYSIS
A matrix spike sample was analyzed with every twenty or fewer samples of a similar matrix, or one
per sample delivery group (whichever is more frequent).
Yes No X
Comments: A matrix spike sample was not analyzed with this SDG. Therefore, the effect of the
sample matrix on the sample preparation procedures and the measurement
methodology could not be evaluated.
The percent recoveries (%R) were calculated correctly.
% Recovery = ^SSR ~ SR* X 100 SSR = spiked sample result
*" SR = sample result
SA = spike added
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
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Spike recoveries were within 75-125% (an exception is granted where the sample concentration is
four times the spike concentration).
Yes No NA X
Comments: A matrix spike sample was not analyzed with this SDG.
X. FORM SB - POST DIGEST SPIKE RECOVERY
A post-digest spike was performed for those elements that did not meet the specified criteria (i.e.,
pre-digestion/pre-distillation spike recovery falls outside of control limits and sample result is less
than four times the spike amount added, exception: Ag, Hg).
Yes No; NA X
Comments: A post digestion spike was not analyzed with this SDG.
XI. FORM 6 - DUPLICATE SAMPLE ANALYSIS
Duplicate sample analysis was performed with every twenty or fewer samples of a similar matrix,
or one per sample delivery group (whichever is more frequent).
Yes No_JL_
Comments: Duplicate sample analyses were not provided with this SDG. Therefore, precision
could not be evaluated.
The RPDs were calculated correctly.
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
For sample concentrations greater than five times the CRDL, RPDs were within ฑ20% (limits of
ฑ35% apply for soil/sediments/tailings samples).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
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For sample concentrations less than five times the CRDL, duplicate analysis results were within the
control window of ฑ CRDL (two times CRDL for soils).
Yes No NA X
Comments: Duplicate sample analyses were not provided with this SDG.
XII. GFAA QC
Duplicate injections were performed on all GFAA samples and the RSD was within ฑ 20%.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
Analytical spikes were performed on all GFAA samples and the percent recovery was 85 - 115%.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
MS As were analyzed when required and the correlation coefficient was > 0.995.
Yes No NA X
Comments: None.
XIII. FORM 7 - LABORATORY CONTROL SAMPLE
The laboratory control sample (LCS) was prepared and analyzed with every twenty or fewer samples
of a similar matrix, or one per sample delivery group (whichever is more frequent).
Yes X No
Comments: None.
All results were within control limits.
Yes X No
Comments: None.
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XIV. FORM 8 - STANDARD ADDITION RESULTS
Results from graphite furnace standard additions were entered on Form VIII as directed in the SOW.
Yes No NA X
Comments: Samples were not analyzed by GFAA.
XV. FORM9-ICPQC
A serial dilution was performed for ICP analysis with every twenty or fewer samples of a similar
matrix, or one per sample delivery group, whichever is more frequent.
Yes No X
Comments: Serial dilutions were not provided with this SDG. Therefore, it could not be
determined whether or not significant physical or chemical interferences exist due
to sample matrix in ICP metals.
The serial dilution was without interference problems as defined by the method.
Yes No NA X
Comments: Serial dilutions were not provided with this SDG.
XVI. FORM 10 - QUARTERLY INSTRUMENT DETECTION LIMITS (IDL)
EDLs were provided for all elements on the target analyte list.
Yes X No
Comments: None.
XVII. FORM 11 - INTERELEMENT CORRECTION FACTORS FOR ICP
Interelement corrections for ICP were reported.
Yes X No
Comments: None.
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XVIII. FORM 12 - 1CP LINEAR RANGES
ICP linear ranges were reported.
Yes X No
Comments: None.
XIX. LINEAR RANGE VERIFICATION ANALYSIS
Linear Range Verification Analysis (LRA) was performed and results were within control limits of
5% of the true value.
Yes No NA X
Comments: None.
XX. FORM 13 - PREPARATION LOG
Information on the preparation of samples for analysis was reported.
Yes X No
Comments: None.
XXI. FORM 14 - ANALYSIS RUN LOG
The required information was filled out for each analysis run in the data package.
Yes X No
Comments: None.
XXII. Additional Comments or Problems/Resolutions Nod Addressed Above
Yes No X
Comments: None.
S2589m Inorganic -14
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INORGANIC DATA QUALITY ASSURANCE REVIEW
Region VIII
DATA QUALIFIER DEFINITIONS
For the purpose of Data Validation, the following code letters and associated definitions are provided for use
by the data validator to summarize the data quality. Use of additional qualifiers should be carefully
considered. Definitions for all qualifiers used should be provided with each report.
GENERAL QUALIFIERS for use with both INORGANIC and ORGANIC DATA
R - Reported value is "rejected." Resampling or reanalysis may be necessary to verify the
presence or absence of the compound.
J - The associated numerical value is an estimated quantity because the Quality Control criteria
were not met.
U J - The reported amount is estimated because Quality Control criteria were not met. Element or
compound was not detected.
N J - The analysis indicates the presence of an analyte that has been "tentatively identified" and the
associated numerical value represents its approximate concentration.
N - The analysis indicates the presence of an analyte for which there is presumptive evidence to
make a tentative identification.
U - The material was analyzed for, but was not-detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
S2589m
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ACRONYMS
AA Atomic Absorption
Ag Silver
CCB Continuing Calibration Blank
CCV Continuing Calibration Verification
CFR Code of Federal Regulations
CLP Contract Laboratory Program
CRA CRDL standard required for AA
CRDL Contract Required Detection Limit
CRI CRDL standard required for ICP
CV Cold Vapor
EPA U.S. Environmental Protection Agency
GFAA Graphite Furnace Atomic Absorption
Hg Mercury
ICB Initial Calibration Blank
ICP Inductively Coupled Plasma
ICS Interference Check Sample
ICSA Interference Check Sample (Solution A)
ICSAB Interference Check Sample (Solution AB)
ICV Initial Calibration Verification
IDL Instrument Detection Limit
LCS Laboratory Control Sample
LRA Linear Range Verification Analysis
MSA Method of Standard Additions
PDS Post Digestion Spike
QC Quality Control
RPD Relative Percent Difference
RPM Regional Project Manager
RSD Percent Relative Standard Deviation
SA Spike Added
SAS Special Analytical Services
SDG Sample Delivery Group
SOW Statement of Work
SR Sample Result
SSR Spiked Sample Result
TPO Technical Project Officer
S2589m
Inorganic - 16
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1
-1-
INORGAN1C ANALYSES DATA SHEET
EPA SAMPLE NO.
lLab Name: COMPUCHEM
Lab Code : LIBRTY Case No . :
|Matrix (soil/water) : SOIL
Level (low/med) : LOW
1% Solids: 100.0
Contract:
SAS No . :
Lab Sample ID:
Date Received:
S01007SWB1
SDG No . :
S2589-13
S2589
6/19/02
Concentration Units (ug/L or mg/kg dry weight) : MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5760
2.7
104
0.29.
0.36
0.03
3190
6.6
4.8
9.1
8980
7.8
3560
206
6.0
1320
0.51
0.28
95.6
0.33
10.1
38.5
C
B
B
"
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
(A
-------
3 W O1O-1V1H, 1 /\J_,ป
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code : LIBRTY Case No . :
Contract:
S01063W1D1
SAS No.: SDG No.: S2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: S2589-14
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
1 Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
12800
4.6
176
1.1
0.47
0.03
2470
7.1
3.9
9.4
12600
29.1
2710
516
6.3
1780
0.53
0.07
104
0.32
17.7
71.9
C
B
u
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
1
Form I - IN
SW846
-------
SWS46-ME1ALS
-1-
INORGAMC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
,ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0106CE1S3
SDG No.: S2589
iatrix (soil/water): SOIL
.evel (low/med) :
4 Solids: 100.0
Lab Sample ID: S2589-15
I
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
9370
6.3
163
0.39
0.55
0.03
30100
8.0
5.6
26.1
12500
12.4
9620
375
8.4
1970
0.21 |
0.07 |
128 |
0.32 |
12.7 |
34.4 |
C
B
U
U
U
B
U
0
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S01071S1S1
SDG No.: S2589
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 100.0
Lab Sample ID: S2589-16
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
| Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6910
4.2
146
0.92
0.35
0.06
4240
7.3
3.6
14.9
9050
46.3
2990
307
5.8
1800
0.42
0.07
119
0.32
11.3
97.2
C
B
B
B
B
u
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
TTT
Form I - IN
SW846
1
-------
I
SW84()-JVlJb.lAJLS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Jab Name: COMPUCHEM
Lab Code: LIBRTY
trix (soil/water):
Level (low/med): LOW
% Solids: 100.0
Case No.:
SOIL
Contract:
SAS No.:
S02003ESD1
SDG No.: S2589
Lab Sample ID:
Date Received:
S2589-17
6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
| 7440-39-3
7440-36-0
7440-41-7
| 7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4 |
7439-96-5
7440-02-0
7440-09-7 |
7782-49-2 |
7440-22-4 |
7440-23-5
7440-28-0 |
7440-62-2 |
7440-66-6 |
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5710
5.5
81.3
1.0
0.31
0.03
4000
6.6
3.5
9.3
9090
31.1
3210
173
5.6
1140
0.35
0.07
124
0.33
11.7
40.7
C
B
"
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0200CEEG1
SDG No.: S2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: 52589-18
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5610
32.9
88.5
10.8
0.30
0.74
4320
8.3
3.8
15.0
10200
258
4020
261
7.4
1370
0.45
1.8
142
0.32
10.2
189
C
B
B
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
CA
^\
a
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
*
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
'Lab Name: COMPUCHEM
.Lab Code: LIBRTY Case No. :
Matrix (soil/water) : SOIL
.Level (low/med) : LOW
Contract :
SAS No . :
Lab Sample ID:
Date Received:
S0200MNSDX
SDG No . :
82589-19
S2589
6/19/02
f% Solids: 100.0
Concentration Units (ug/L or mg/kg dry weight): MG/KG
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7290
9.0
81.7
2.8
0.36
7.6
780
6.6
3.3
7.9
10800
47.7
2760
213.
5.3
1250
0.47
0.24
14.4 |
0.33 |
17.0
999 |
C
B
B
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U
(A
Texture: FINE
Artifacts:
Comments :
Form I - IN
SW846
-------
-1-
ESORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0200MNSG1
SDG No.: 82589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
LOW
Lab Sample ID: S2589-20
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5 |
7440-28-0 |
7440-62-2
7440-66-6 |
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5630
61.8
91.4
23.3
0.30
3.7
3480
8.1
3.7
18.4
12400
587
4100
369
8.0
1100
0.66
3.5
14.2
0.32
10.1
724
C
B
U
u
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
M
tA
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW846I
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
;ab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0400HT4S1
SDG No.: S2589
latrix (soil/water) : SOIL
level (low/med) : LOW
Lab Sample ID: S2589-1
S Solids: 100.0
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight) : MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6 |
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
2400
2110
30.5
1450
0.18
27.4
1260
1.7
1.7
70.4
55500
10700
1970
3060
3.5
529
2.6
100
289
4.8
3.6
3820
C
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: ORANGE
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
,oV
Form I - IN
SW846
-------
SW846-ME1AJLS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ib Name: COMPUCHEM
ab Code: LIBRTY
Case No. :
Contract:
SAS No.:
S0400ILEE1
SDG No.: S2589
atrix (soil/water): SOIL
avel (low/med):
Solids: 100.0
Lab Sample ID: S2589-2
LOW
Date Received: 6/19/02
Concentration Units {ug/L or mg/kg dry weight) : MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concen t ra ti on
5970
5.0
87.8
0.93
0.35
0.03
6930
10.5
3.5
14.8
9580
44.5
4700
192
6.9
1260
0.67
0.07 j
105 |
0.32 |
10.9 j
44.3 |
C
IB
B
u
u
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
U.
~~~
m
s
(A
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
33:
Form I - IN
SW84(
-------
1
S\VS46-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
1
4ab Name: COMPUCHEM
tCode : LIBRTY Case No . :
rix (soil/water) : SOIL
ievel (low/med) : LOW
i
Contract :
SAS No . :
Lab Sample ID:
Date Received:
SDG No . :
S2589-3
6/19/02
S0400MNSC1
S2589
I
Solids: 100.0
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4780
7.1
85.3
0.99
0.30
0.03
4900
7.7
4.1
11.6
8590
41.9
4290
217
7.1
1090
0.34
0.07
93.4
0.32
8.7
66.2
C
B
"
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P .
P
P
P
P
P
P
P
(A
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments :
Texture: FINE
Artifacts:
20
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0400SPEC1
SDG No.: S2589
Matrix (soil/water): SOIL
Level (low/med):
% Solids: 100.0
Lab Sample ID: S2589-4
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-.28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4710
582
74.0
145
0.29
14.4
6920
7.2
3.5
28.6
27900
2320
4420
1260
7.6
1220
1.4
18.2
14.4
. 0.33 |
7.9 |
2660 |
C
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
(X
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
..ah Name: COMPUCHEM
-,ab Code : LIBRTY Case No . :
Matrix (soil/water) : SOIL
Level (low/med) : LOW
\ Solids: 100.0
Contract :
SAS No . :
Lab Sample ID :
Date Received:
S0400SPEDX
SDG No . :
S2589-5
S2589
6/19/02
I
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4 |
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7420
2.8
94.8
0.61
0.36
0.03
1510
6.2
3.4
8.6
9240
9.9
2730
188
5.6
1360
0.32
0.07
107
0.33
11.7
29.2
C
B
B
U
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
-------
-1-
EVORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Jab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0400SPEE1
SDG No.: S2589
latrix (soil/water): SOIL
jevel (low/med) :
* Solids: 100.0
Lab Sample ID: S2589-6
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
6050
157
71.7
41.6
0.41
4.4
5840
8.3
4.6
20.6
19000
767
4410
661
7.8
1240
0.86
4.2
14.3
0.32
9.9
909
C
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
i\
LA
Color Before: BROWN
Color After: YELLOW
Comments:
Clarity Before:
Clarity After:
.Texture: FINE
Artifacts:
1
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
Lab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0400SPEF1
SDG No.: S2589
latrix (soil/water) : SOIL
L.evel (low/med) :
i Solids: 100.0
Lab Sample ID: S2589-7
LOW
Date Received: 6/19/02
Concentration Units
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
,ab Name: COMPUCHEM
,ab Code: LIBRTY Case No.:
Contract:
S0400SPEG1
SASNo.: SDG.No.: S2589
latrix (soil/water) : SOIL
.evel (low/med) :
i Solids: 100.0
LOW
Lab Sample ID: S2589-8
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
7439-95-4 (Magnesium
7439-96-5
7440-02-0
Manganese
Nickel
7440-09-7 | Potassium
7782-49-2
7440-22-4
Selenium
Silver
7440-23-5 | Sodium
7440-28-0 | Thallium
7440-62-2
7440-66-6
Vanadium
Zinc
Concentration
7870
.207
104
53.8
0.45
4.3
4700
13.3
4.6
22.4
17800
1150
4970
651
9.3
1810
0.91
9.1
468
0.32
10.9
1010
C
B
U
Q
.
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
lab Name: COMPUCHEM
Lab Code : LIBRTY Case No . :
htrix (soil/water) : SOIL
-
Level (low/med) : LOW
1 Solids: 100.0
Contract:
SAS No . :
Lab Sample ID:
Date Received:
S0400SPWF1
SD6 No . :
S2589-9
S2589
6/19/02
I
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
5250
68.1
60.2
25.6
0.33
3.3
1610
5.8
3.4
12.1
10900
468
2640
296
5.5
982
0.52
2.7
14.0 |
0.32 |
8.3 |
693 |
C
B
U
u
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
u
^olor Before: BROWN
iolor After: YELLOW
Clarity Before:
Clarity After:
Comments:
Texture: FINE
Artifacts:
Fora I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
Jab Code: LIBRTY
Case No.:
Contract:
SAS No.:
S04032W1S3
SD6 No.: S2589
latrix (soil/water) : SOIL
jevel (low/med) :
& Solids: 100.0
Lab Sample ID: 52589-10
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
4010
1540
70.3
955
0.24
20.4
3340
4.4
3.4
57.6
42100
8530
2390
2680
5.0
851
2.7
81.4
14.3
2.6
6.7
3040
C
B
".
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Color Before: BROWN
Color After: YELLOW
Comments :
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
Form I - IN
SW846
-------
SW846-METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
Code : LIBRTY
Case No.:
Contract:
SAS No.:
S0404AL1S3
SDGNo.: S2589
[
I
I
I
I
rix (soil/water): SOIL
el (low/med):
'olids: 100.0
Lab Sample ID: S2589-11
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7180
3.6
109
0.91
0.35
0.11
2340
7.9
3.6
14.5
9570
55.8
2760
311
6.5
1210
0.61
0.07
76.7 |
0.32 |
12.9 I
85.1 |
C
B
B
B
U
B
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
K
lor Before: BROWN
:olor After: YELLOW
!omments:
Clarity Before:
Clarity After:
Texture: FINE
Artifacts:
ฃ0
Form I - IN
SW846
-------
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ab Name: COMPUCHEM
ab Code: LIBRTY
Case No.:
Contract!
SAS No.:
S0043MW1S2
SDG No.: S2589
atrix (soil/water): SOIL
=vel (low/med):
Solids: 100.0
LOW
Lab Sample ID: 52589-12
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No.
7429-90-5
7440-38-2
7440-39-3
7440-36-0
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7782-49-2
7440-22-4 |
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Analyte
Aluminum
Arsenic
Barium
| Antimony
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Concentration
7810
58.2
108
27.7
0.39
4.0
4820
6.6
4.0
19.1
11700
706
3240
354
6.5
1680
0.52
6.5
14.3 |
0.32 |
11.6 |
522 |
C
B
U
U
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P 1
P
-------
uos
URS Operating Services, Inc.
Data Validation Report
REGION
DATA VALIDATION REPORT
INORGANIC
$y^ >S ;8:Mj*N^:r A <;:';;:W
0203-0008
W lV';'^G^R^pS^i^^^^->^
Tien Nguyen
t r
Contractor Laboratory
CompuChem - Liberty
ฃte?v>^,^.&i .'-'.t^'^-.--^-^
^^:f-r^:-.Site^am^:^lj^
Superior Waste Rock
Contract No.>
Not Indicated
'..jj.'i-^
SDG*Nb.^
Q2589
^- *^X* ^ ** ^f$^'f**r&*'~'$&^!fฃi
Yabqratpr^-QFOmeiifni
Review Assigned
Review Completk
:;/SainRle:^
S0400HT
S0208MN
S0700FG
S0201SP
Date Julv 5. 2002 Data Validator Bill Fear
>nDate Julv 19. 2002 Report Reviewer Ken Schroeder
$&^$j$ti&3
Q2589-1
Q2589-2
Q2589-3
Q2589-4
Ip^ifli
Soil/Sediment
TCLP - Metals
02589m
Inorganic -1
-------
uos
URS Operating Services, Inc. Data Validation Report
DATA QUALITY STATEMENT
( ) Data are ACCEPTABLE according to EPA Functional guidelines with no qualifiers (flags) added
by the reviewer.
( ) Data are UNACCEPTABLE according to EPA Functional Guidelines.
( X ) Data are acceptable with QUALIFICATIONS noted in review.
Telephone/Communication Logs Enclosed? Yes No X
TPO Attention Required? Yes No X If yes, list the items that require attention:
i
02589m Inorganic - 2
-------
uos
URS Operating Services, Inc.
Data Validation Report
INORGANIC DATA VALIDATION REPORT
REVIEW NARRATIVE SUMMARY
This data package was reviewed according to "USEPA Contract Laboratory Program National Functional
Guidelines for Inorganic Data Review," February 1994, and modified for the method used.
Raw data were reviewed for completeness and transcription accuracy onto the summary forms.
Approximately 10-20% of the results reported in each of the samples, calibrations, and QC analyses were
recalculated and verified. If problems were identified during the recalculation of results, a more thorough
calculation check was performed.
The data package, TDD No. 0203-0008, SDG No. Q2589, consisted of 4 soil samples for TCLP metals.
The following table lists the data qualifiers added to the sample analyses. Please see Data Qualifier
Definitions, attached to the end of this report.
All samples
Selenium
U
Blank contamination
VII
Q2589m
Inorganic 3
-------
uos
URS Operating Services, Inc. Data Validation Report
Method/SQW Number 6010. 1311. 7470/SW-846
Revision 0.0
Inorganic Deliverables Completeness Checklist
P Inorganic Cover Page
P Inorganic Analysis Data Sheets (Form I)
P Initial Calibration and Calibration Verification Results (Form II)
P Continuing Calibration Verification Results (Form II)
P CRDL Standard for ICP and AA (Form II, Part 2)
P Blank Analysis Results (Form III)
P ICP Interference Check Sample Results (Form IV)
P Spiked Sample Results (Form V)
P Post-digest Spiked Sample Analysis (Form V, Part 2)
P Duplicate Sample Results (Form VI)
P Instrument Detection Limits (Form VII) or (Form X - Quarterly)
P Laboratory Control Sample results (Form VII)
NA Standard Addition Results (Form VIII)
P ICP Serial Dilution Results (Form IX)
NA Holding Times Summary Sheet (Form X)
P ICP Interelement Correction Factors (Form XII - Quarterly, or Form XI - Annually)
P ICP Linear Ranges (Form XII (XII) - Quarterly)
P Raw Data
_P Samples P Calibration Standards P Blanks P Spikes
P Duplicates P ICP QC (ICS and Serial Dilution P LCS
NA Furnace AA P Mercury Analysis NA Cyanide Analysis
NA Percent Solids Calculations - (Solids Only)
P Sample Prep/Digestion Logs (Form XIII)
P Analysis Run Log (Form XIV)
P Chain-of-Custody
P Sample Description
P Case Narrative
P Method References
KEY:
P = Provided in original data package, as required by the SOW
R = Provided as Resubmission
NP = Not provided in original data package or as resubmission
NR = Not required under the SOW
NA = Not applicable to this data package or analysis
Q2589m ' Inorganic - 4
-------
DOS
URS Operating Services, Inc. Data Validation Report
I. DELIVERABLES
All deliverables were present as specified in the Statement of Work.
Yes X No
Comments: None.
n. HOLDING TIMES AND PRESERVATION CRITERIA
All method holding times were met.
Yes X No
Comments: None.
All technical holding times and preservation criteria were met.
YesX No
Comments: All samples were analyzed within required holding times. The samples were
received by the laboratory with cooler temperature of 22ฐC. No action was taken
because the Functional Guidelines do not provide specific guidance for temperature
and the effect on the sample integrity is not known. No other shipping or receiving
problems were noted.
DI. INSTRUMENT CALIBRATIONS: STANDARDS AND BLANKS
Initial instrument calibrations were performed according to SOW requirements.
Yes X No
Comments: None.
The instruments were calibrated daily and each time an analysis run was performed.
Yes X No
Comments: None.
02589m Inorganic - 5
-------
UOS I
URS Operating Services, Inc. Data Validation Report
The instruments were calibrated using one blank and the appropriate number of standards. ^
/
Yes X No |
Comments: The calibration correlation coefficient for mercury was greater than 0.995.
IV. FORM 1 - SAMPLE ANALYSIS RESULTS
Sample analyses were entered correctly on Form Is. el
Yes X No I
Comments: The lead results were reported from dilutions in samples S0208MN, S0700FG, and
S0201SP. El
V. FORM 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION Q
The initial and continuing calibration verification standards (ICV and CCV, respectively) met SOW
requirements. m
Yes X No
Comments: None. ffi
The calibration verification results were within 90-110% recovery for metals, 85-115% for cyanide, rlj
and 80-120% for mercury.
Yes X No Q
Comments: None.
The continuing calibration standards were run at 10% frequency.
Yes X No . ' 1
Comments: None. m
02589m Inorganic - 6
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URS Operating Services. Inc. Data Validation Report
VI. FORM 2B - CRDL STANDARD FOR ICP AND AA
ICP Analysis: Standards (CRI) at two times the CRDL or the IDL (whichever were greater) were
analyzed at the beginning and the end of each sample run, or at a minimum of twice per eight hours,
whichever was more frequent.
Yes X No
Comments: None.
GFAA Analysis: Standards (CRA) at two times CRDL were analyzed at the beginning of each
sample run.
Yes No NA X
Comments: None.
The CRI and/or the CRA were analyzed after the ICV.
Yes X No
Comments: None.
VH. FORM 3 - BLANKS
The initial and continuing calibration blanks (ICB and CCB, respectively) met SOW requirements.
Yes X No
Comments: None.
The continuing calibration blanks were run at 10% frequency.
Yes X No
Comments: Continuing calibration blanks were run every 10 samples.
Q2589m Inorganic - 7
-------
uos
DPS Operating Services, Inc.
Data Validation Report
A laboratory/preparation blank was run at the frequency of one per twenty samples, or per sample
delivery group (whichever is more frequent), and for each matrix analyzed.
Yes X No
Comments: None.
All analyzed blanks were free of contamination.
Yes No X
Comments:
The following table lists the blanks with contamination that resulted in
qualification, elements present, affected samples, and data qualifiers:
Blank Contaminants
Blank
ID
Leachate
Blank
Contaminant
Selenium .
Concentration
Found in Blank
9.2ug/L
IDL
(ug/L)
2.1
T
Associated
Samples^,
S0400HT
S0208MN
S0700FG
S0201SP
~ ~ *^-&k
Concentration IFonndK J
V- inSample^B^
t ^ (ug/L) *">&
12.4
10.9
11.9
9.5
U
Vin. FORM 4 - ICP INTERFERENCE CHECK SAMPLE
The ICP interference check sample (ICS) was run twice per eight hour shift and/or at the beginning
and end of each sample set analysis sequence (whichever is more frequent).
Yes X
Comments:
No
None.
Percent recovery of the analytes in solution ICSAB were within the range of 80-120%.
Yes X No
Comments: None.
02589m
Inorganic-8
-------
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URS Operating Services. Inc. Data Validation Report
Sample results for aluminum, calcium, iron, and magnesium were less than the ICSA values.
Yes X No
Comments: None.
IX. FORM 5A - MATRIX SPIKE SAMPLE ANALYSIS
A matrix spike sample was analyzed with every twenty or fewer samples of a similar matrix, or one
per sample delivery group (whichever is more frequent).
Yes X No
Comments: None.
The percent recoveries (%R) were calculated correctly.
% Recovery = (SSR ~ SR) X 100 SSR = spiked sample result
SA SR = sample result
SA = spike added
Yes X No;
Comments: None.
Spike recoveries were within the range of 75-125% (an exception is granted where the sample
concentration is four times the spike concentration).
Yes X No
Comments: None.
X. FORM SB - POST DIGEST SPIKE RECOVERY
A post-digest spike was performed for those elements that did not meet the specified criteria (i.e.,
Pre-digestion/pre-distillation spike recovery falls outside of control limits and sample result is less
than four times the spike amount added, exception: Ag, Hg).
Yes No Not Required X
Comments: None.
02589m Inorganic - 9
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URS Operating Services. Inc. _ Data Validation Report
XI. FORM 6 - DUPLICATE SAMPLE ANALYSIS
Duplicate sample analysis was performed with every twenty or fewer samples of a similar matrix,
or one per sample delivery group (whichever is more frequent).
Yes X No _
Comments: None.
The RPDs were calculated correctly.
D)
D)/2 D = duplicate
RPD = (S "D) X 100 S = sample
Yes X No _
Comments: None.
For sample concentrations greater than five times the CRDL, RPDs were within ฑ20% (limits of
ฑ35% apply for soil/sediments/tailings samples).
Yes X No _ NA _
Comments: None.
For sample concentrations less than five times the CRDL, duplicate analysis results were within the
control window of ฑ CRDL (two times CRDL for soils).
Yes X No
Comments: None.
GFAAQC
Duplicate injections were performed on all GFAA samples and the RSD was within ฑ 20%.
Yes No NA X
Comments: GFAA analyses were not performed on these samples.
02589m Inorganic-10
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URS Operating Services, Inc. _ Data Validation Report
Analytical spikes were performed on all GFAA samples and the percent recovery was 85 - 115%.
Yes _ No _ NA X
Comments: GFAA analyses were not performed on these samples.
MSAs were analyzed when required and the correlation coefficient was > 0.995.
Yes _ No_ NA X
Comments: None.
FORM 7 - LABORATORY CONTROL SAMPLE
The laboratory control sample (LCS) was prepared and analyzed with every twenty or fewer samples
of a similar matrix, or one per sample delivery group (whichever is more frequent).
Yes X No _
Comments: None.
AH results were within control limits.
Yes X No _
Comments: All LCS results were within 80-120%.
XTV. FORM 8 - STANDARD ADDITION RESULTS
Results from graphite furnace standard additions were entered on Form VIII as directed in the SOW.
Yes _ No _ NA X
Comments: None.
XV. FORM 9 - ICP QC
A serial dilution was performed for ICP analysts with every twenty or fewer samples of a similar
matrix, or one per sample delivery group, whichever is more frequent.
Yes X No _
Comments: None.
02589m Inorganic - 1 1
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URS Operating Services, Inc. Data Validation Report
The serial dilution was without interference problems as defined by the SOW.
Yes X No
Comments: All serial dilution %Ds were less than 10% or the original sample result was less
than 50* the IDL.
XVI. FORM 10 - QUARTERLY INSTRUMENT DETECTION LIMITS (IDL)
IDLs were provided for all elements on the target analyte list.
Yes X No
Comments: None.
Reported IDLs met SOW requirements.
Yes X No
Comments: None.
XVII. FORM 11 - INTERELEMENT CORRECTION FACTORS FOR ICP
Interelement corrections for ICP were reported.
Yes X No
Comments: None.
XVm. FORM 12-ICP LINEAR RANGES
ICP linear ranges were reported.
Yes X No
Comments: None.
02589m Inorganic-12
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URS Operating Services, Inc. Data Validation Report
XIX. LINEAR RANGE VERIFICATION ANALYSIS
Linear Range Verification Analysis (LRA) was performed and results were within control limits of
ฑ 5% of the true value.
Yes No NA X
Comments: None.
XX. FORM 13 - PREPARATION LOG
Information on the preparation of samples for analysis was reported on Form XIII.
Yes X No
Comments: None.
XXI. FORM 14 - ANALYSIS RUN LOG
A Form XIV with the required information was filled out for each analysis run in the data package.
Yes X No
Comments: None.
XXII. Additional Comments or Problems/Resolutions Not Addressed Above
Yes No_X_
Comments: None.
0.2589m Inorganic-13
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URS Operating Services, Inc. Data Validation Report
INORGANIC DATA QUALITY ASSURANCE REVIEW
Region Vm
DATA QUALIFDZR DEFINITIONS
For the purpose of Data Validation, the following code letters and associated definitions are provided for use
by the data validator to summarize the data quality. Use of additional qualifiers should be carefully
considered. Definitions for all qualifiers used should be provided with each report.
GENERAL QUALIFIERS for use with both INORGANIC and ORGANIC DATA
R - Reported value is "rejected." Resampling or reanalysis may be necessary to verify the
presence or absence of the compound.
J - The associated numerical value is an estimated quantity because the Quality Control criteria
were not met.
U J - The reported quantisation limit is estimated because Quality Control criteria were not met.
Element or compound was not detected.
N J - Estimated value of a tentatively identified compound. (Identified with a CAS number.)
ORGANICS analysis only.
U - The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
02589m Inorganic-14
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URS Operating Services, Inc.
Data Validation Report
ACRONYMS
AA Atomic Absorption
Ag Silver
CCB Continuing Calibration Blank
CCV Continuing Calibration Verification
CFR Code of Federal Regulations
CLP Contract Laboratory Program
CRA CRDL standard required for AA
CRDL Contract Required Detection Limit
CRI CRDL standard required for ICP
CV ' Cold Vapor
EPA U.S. Environmental Protection Agency
GFAA Graphite Furnace Atomic Absorption
Hg Mercury
ICB Initial Calibration Blank
ICP Inductively Coupled Plasma
ICS Interference Check Sample
ICSA Interference Check Sample (Solution A)
ICSAB Interference Check Sample (Solution AB)
ICV Initial Calibration Verification
IDL Instrument Detection Limit
LCS Laboratory Control Sample
LRA Linear Range Verification Analysis
MSA Method of Standard Additions
PDS Post Digestion Spike
QC Quality Control
RPD Relative Percent Difference
RPM . Regional Project Manager
RSD Percent Relative Standard Deviation
SA Spike Added
SAS Special Analytical Services
SDG Sample Delivery Group
SOW Statement of Work
SR Sample Result
SSR Spiked Sample Result
TPO Technical Project Officer
02589m
Inorganic-15
-------
SW846 METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: COMPUCHEM
ab Code : LIBRTY
Case No . :
Contract:
SAS No.:
S0400HT
SDG No.: Q2589
atrix (soil/water): WATER
,evel (low/med) :
-------
SW846 METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
ab Name: COMPUCHEM
ab Code: LIBRTY Case No. :
atrix (soil/water) : WATER
Contract:
SAS No . :
Lab Sample ID:
SDG No . :
Q2589-2
S0208MN
Q2589
evel (low/med):
, Solids: 0.0
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No.
7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7439-97-6 \
7782-49-2
7440-22-4
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
Concentration
2.3
301
253
125 |
107000 |
1.1 I
10.9 |
0.50 |
C
B
B
B
B
B
B
U
Q
..
M
P
P
P
P
P
CV
P
P
Color Before: COLORLESS
Clarity Before: CLEAR
Color After: COLORLESS
Clarity After: CLEAR
Texture:
Artifacts:
Comments:
Form I - IN
SW84
I
-------
SW846 METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
1
ab Name: COMPUCHEM
fb Code : LIBRTY Case No . :
1
atrix (soil/water) : WATER
Contract :
SAS No. :
Lab Sample ID:
S0700FG
SD6 No . :
Q2589-3
Q2589
ivel (low/med) : LOW
, Solids: 0.0
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No.
7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7439-97-6 |
| 7782-49-2 |
7440-22-4
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
Concentration
126
161
377
4.0
48300
0.22 |
11.9 |
0.50 |
C
B
B
B
B
B
B
U
Q
M
P
P
P
P
P
cv
P 1
P
Color Before: COLORLESS
Clarity Before: CLEAR
Color After: COLORLESS
Clarity After: CLEAR
Texture:
Artifacts:
Comments:
13.
Form I - IN
SW846
-------
SW846 METALS
-1-
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
i> Name: COMPUCHEM
ib Code: LIBRTY
Case No.:
Contract:
SAS No.:
S0201SP
SDG No.: Q2589
itrix (soil/water): WATER
svel (low/med) :
Solids: 0.0
Lab Sample ID: Q2589-4
LOW
Date Received: 6/19/02
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No.
7440-38-2
7440-39-3
7440-43-9 |
7440-47-3 |
7439-92-1 |
7439-97-6 |
7782-49-2 |
7440-22-4 |
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
Concentration
39.1
367
33.9
6.0
140000
1.8
9.5
5.9
C
B
B
B
B
B
B
B
Q
M
P
P
P
P
P
CV
P
P
Color Before: COLORLESS
Clarity Before: CLEAR
Color After: COLORLESS
Clarity After: CLEAR
Texture:
Artifacts:
Comments:
Form I - IN
S\V8
-------
APPENDIX C
XRF Results
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0023MW1S1 6/10/2002
S0033MW1S1 6/10/2002
S0033MW1S2 6/10/2002
S0043MW1D1 6/12/2002
S0043MW1SI 6/10/2002
S0043MWIS2 6/10/2002
S0043MW1S3 6/10/2002
SOOFCCM1S1 6/10/2002
SOI001SWA1 6/8/2002
S01001SWB1 6/8/2002
S01001SWC1 6/8/2002
S01001SWD1 6/8/2002
SO 100 IS WEI 6/8/2002
S01001SWF1 6/8/2002
S01001SWF1D 6/8/2002
S01004END1 6/8/2002
S01004END1B 6/8/2002
S01007SWA1 6/8/2002
S01007SWB1 6/8/2002
S01007SWC1 6/8/2002
S01007SWD1 6/8/2002
S0100CEEA1 6/7/2002
S0100CEEB1 6/7/2002
S0100CEEC1 6/7/2002
S0100CEED1 6/7/2002
S0100CEEE1 6/7/2002
S0100CEEF1 6/7/2002
S0100CEEG1 6/7/2002
S0100CEEG1R 6/7/2002
S0100CEWA1 6/7/2002
S0100CEWB1 6/7/2002
S0100CEWC1 6/7/2002
S0100CEWD1 6/7/2002
SOIOOCEWE1 6/7/2002
S0100CEWE1D 6/7/2002
1 1 - The. anal vtp wac tint
TIME
1431
1419
1346
958
1423
1350
1355
1625
914
918
922
927
935
939
943
1135
1140
1220
1224
1228
1232
1154
1158
1202
1207
1210
1214
1219
1105
1226
1231
1236
1355
1358
1410
^MMHM
Sb
62 U
62 U
62 U
62 U
62 U
120 J
62 U
62 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
As
43 U
43 U
43 U
. 34 U
43 U
78 U
43 U
43 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51U
51 U
51 U
5IU
51 U
54 J
38 U
38 U
38 U
38U
38 U
431
38 U
39 J
38 U
38 U
38 U
38 U
38 U
38 U
Ba
380
410
470
470
430
440
460
360
420
480
450
440
460
410
370
510
82 U
430
400
450
350
440 J
380 J
430 J
430 J
480
320 J
320 J
340 J
440 J
380 J
380 J
440
410 J
350 J
Cd
150 U
150 U
150U
170 U
150 U
150 U
150 U
150 U
130 U
130 U
130U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
140 J
130 U
130 U
130 U
130 U
130 U
130 U
130 U
Ca
17000
11000
28000
6600 J
16000
15000
30000
39000
13000
20000
15000
8400 J
8900 J
18000
16000
13000
2900 U
13000
II 000
9500 J
15000
11000
9800
11000
15000
11000
14000
12000
12000
8900
10000
14000
11000
10000
8800
CrHI
720 J
510J
710J
610J
550 J
360 U
760 J
710J
490 U
490 U
490 U
780 J
490 U
830 J
790 J
640J
490 U
620 J
680 J
690 J
590 J
370 U
440J
370 U
460 J
370 U
480 J
690 J
700 J
550 J
430 J
660 J
560 J
640 J
670 J
CrLO
500 U
500 U
500 U
670 U
500 U
500 U
500 U
500 U
610U
610U
610U
610U
6IOU
610U
610 U
610 U
.610U
610 U
610U
610U
6IOU
460 U
460 U
460 U
460U
460U
460 U
520 J
460 U
460 U
460 U
460 U
460 U
460 U
460 U
Co
330 U
330 U
330 U
510U
330 U
350 J
330 U
330 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
Cu
sou
sou
sou
120 U
51]
SOU
SOU
SOU
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
100U
100U
100U
100 U
100U
100U
100U
100U
100U
100U
100U
100U
100 U
100U
Fe
18000
18000
21000
13000
22000
18000
17000
16000
15000
16000
16000
16000
16000
18000
18000
18000
I400U
16000
. 17000
13000
15000
15000
17000
17000
17000
17000
18000
16000
16000
16000
16000
18000
16000
20000
19000
Pb
40 J
67
22 J
26 J
140
780
54
23 J
66J
22 J
42 J
25 J
42 J
180
160
28 J
21 U
21 U
21 U
21 U
21 U
24 U
100
50 J
100
70 J
67 J
54J
30 J
29 J
80
62 J
53 J
160
190
Mn
510 U
510U
510U
330 U
570 J
510U
5IOU
510U
440U
440 U
440U
440U
440U
440U
470 J
440U
440 U
440 U
440U
460 J
440 U
400U
400 U
400 U
400 U
460 J
400 U
400 U
400 U
400U
400U
400 U
400U
530 J
490 J
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 1 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE TIME
Sb
S0100CEWFI 6/7/2002 1414 51 U
S0100CEWG1 6/7/2002 1419 51 U
SOI02RN1S1 6/11/2002 849 75 U
S01063W1D1 6/12/2002 938 62 U
S01063W1S1 6/10/2002 1026 62 U
S01063W1S2 6/10/2002 1029 62 U
S01063W1S3 6/10/2002 1034 510
S0106CE1S1 6/9/2002 1402 66 U
S0106CE1S2 6/9/2002 1405 66 U
S0106CE1S3 6/9/2002 1410
S0106ME1S1 6/10/2002 1405
S0107IS1S1 6/8/2002 1506
S01071S1S2 6/8/2002 1514
SOU6MW1S1 6/10/2002 1629
S0146MW1S2 6/10/2002 1642
S0146MW1S3 6/10/2002 1652
S0169DI1S1 6/10/2002 1559
S0169DMS2 6/10/2002 1549
S02003ENA1 6/6/2002 1558
S02003ENBI 6/6/2002 1602
S02003ENCI 6/6/2002 1606
S02003END1 6/6/2002 1610
S02003ENE1 6/6/2002 1614
S02003ENF1 6/6/2002 1619
S02003ENOI . 6/6/2002 1623
S02003ESA1 6/7/2002 949
S02003ESB1 6/7/2002 956
S02003ESC1 6/7/2002 1001
S02003ESD1 6/7/2002 1005
S02003ESE1 6/7/2002 1009
S02003ESF1 6/7/2002 1013
S02003ESG1 6/7/2002 1017
S02003ESG1R 6/7/2002 1021
S02004SEA1 6711/2002 1722
S02004SEB1 6/11/2002 1726
66 U
62 U
45 U
45 U
62 U
62 U
62 U
62 U
62 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
75 U
75 U
J - The associated numerical value is
As
431
38 U
46 U
34 U
43 U
43 U
400 U
51 U
58 J
51 U
51J
51 U
51 U
43 U
43 U
43 U
43 U
43 U
36 U
36 U
36 U
47 J
36 U
36 U
36 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
46 U
46 U
detection limit.
Ba
2901
370 J
450
470
350
320
350
490
420
360
620
450
450
320
310
240
370
430
470
420 J
400 J
480
440
420 J
440
350 J
380 J
450
520
390 J
410 J
420 J
390 J
500
450
Cd Ca
130 U 12000
130U 8900
180 U 21000
170U 9500
150 U 8900 J
150 U 8900 J
150 U 13000
210 U 13000
210 U 14000
21 OU 47000
150U 4500 J
130 U 13000
130U 9400 J
150U 28000
150 U 12000
150 U 12000
150 U 13000
150 U 8200 J
180U 22000
180 U 18000
180U 20000
180 U . 13000
180 U 6900 J
180U 5400 J
I SOU 8500
130U 9700
130U 15000
130 U 15000
130U 15000
130U 9200
130U 9200
130U 7300 J
130U 8800
180U 23000
180 U 11000
CrHI
610 J
560 J
640 J
630 J
1IOOJ
590 J
560 J
680 J
720 J
470 J
450 J
510J
550 J
510J
570J
830 J
680 J
460 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
650 J
650 J
370 U
400 J
730 J
440 J
500 J
700 J
590J
440 J
ป-^ ^^
CrLO
460 U
460 U
920 U
670 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
610U
610U
500 U
500 U
500 U
500 U
500 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
460 U
460 U
460 U
460U
460 U
460 U
460 U
460 U
920 U
920 U
MMi^^^M^iH
Co
320 U
450 J
580 U
510U
330 U
330 U
330 U
540 U
540 U
540 U
350 J
630 U
630 U
330 U
330 U
330 U
370 J
330 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
320 U
320 U
320 U
320 U
320 U
350 J
320 U
320 U
580 U
580 U
Cu
100 U
100U
55 U
120 U
SOU
SOU
SOU
41 U
41 U
41 U
SOU
76 U
76 U
SOU
SOU
SOU
SOU
SOU
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
55 U
55 U
Fe
20000
21000
15000
20000
17000
19000
30000
18000
17000
19000
20000
15000
16000
19000
19000
21000
17000
18000
17000
16000
15000
15000
15000
14000
15000
19000
16000
16000
16000
18000
18000
14000
15000
15000
17000
Pb
100
82
59 J
29 J
50 J
26 J
4000
64 J
62 J
35 U
24 J
45 J
68 J
29 J
21 J
16 U
16 U
16U
36 J
53]
70 J
36 U
36 U
36 U
40 J
170
140
58 J
24 U
44J
56 J
24 U
24 U
44]
23 U
The detection limit is reported.
an estimated quantity between the detection limit and the quantitation
limit.
Mn
400 U
720 J
420 U
710J
510U
510U
1200J
640 U
640 U
640U
510U
440U
440 U
510U
510 U
550 J
800 J
840 J
400 U
400U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
420 U
420 U
Page 2 of 19
-------
B
TABLE 1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S02004SECI 6/11/2002
S02004SED1 6/11/2002
S02004SWB1 6/11/2002
S02004SWC1 6/11/2002
S02004SWD1 6/11/2002
S0200CEEA1 6/7/2002
S0200CEEA1B 6/7/2002
S0200CEEB1 6/7/2002
S0200CEEC1 6/7/2002
S0200CEEDI 6/7/2002
S0200CEEE1 6/7/2002
S0200CEEF1 6/7/2002
S0200CEEG1 6/7/2002
S0200CEWA1 6/7/2002
S0200CEWB1 6/7/2002
S0200CEWB 1 D 6/7/2002
S0200CEWC1 6/7/2002
S0200CEWD1 6/7/2002
S0200CEWE1 6/7/2002
S0200CEWF1 6/7/2002
S0200CEWG1 6/7/2002
S0200CEWG1R 6/7/2002
S0200MNNA1 6/7/2002
S0200MNNB1 6/7/2002
S0200MNNC1 6/7/2002
S0200MNND1 6/7/2002
S0200MNNE1 6/7/2002
S0200MNNF1 6/7/2002
S0200MNNG1 6/7/2002
S0200MNNG1 R 6/7/2002
S0200MNSA1 6/7/2002
S0200MNSB1 6/7/2002
S0200MNSC1 6/7/2002
S0200MNSD1 6/7/2002
S0200MNSDX 6/1 2/2002
TIME
M^M^MMB
1731
1742
1750
1754
1758
1032
1037
1040
1045
1049
1053
1057
1101
1109
1113
1121
1125
1129
1134
1138
1142
1146
1625
1629
1633
1637
1645
1649
1653
1657
1435
1439
1443
1447
950
Sb
MM^B^^^
75 U
75 U
75 U
75 U
75 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51U
51 U
51 U
51 U
51 U
51 U
61 J
51 U
51 U
51U .
51 U
51 U
51 U
62 U
As
^^^^^^^^MM
46 U
46 U
46 U
46 U
46 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
39 J
38 U
38 U
38 U
38 U
38 U
38 U
41 J
38 U
38 U
38 U
38 U
43 J
38 U
34 U
Ba
340
390
390
420
480
370 J
130 U
540
390 J
390 J
440 J
410J
300 J
480
360 J
420 J
510
440J
490
450
510
530
350 J
310J
410J
3601
440
360 J
390 J
430 J
430 J
340 J
360 J
390 J
430
Cd
180 U
180 U
180 U
180 U
180 U
130 U
130 U
130 U
130 U
130 U
130U
130U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
180 J
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
170 U
Ca
25000
14000
9700 J
10000
13000
10000
2300 U
8200
13000
12000
9400
10000
11000
12000
17000
17000
14000
10000
7500
9300
13000
14000
9600
11000
8700
7400 J
5100J
8300
7400 J
7700
16000
11000
11000
12000
6800 J
CrHI
720 J
720 J
480 J
690 J
630 J
570 J
380 J
710J
370 U
660 J
630 J
490 J
630 J
370 U
550 J
420 J
5101
370 J
380 J
660 J
480 J
370 U
530 J
510J
540 J
660 J
780 J
630 J
640 J
370 U
370 U
740 J
6901
750 J
440 U
ปซ ป ซB_^_
CrLO
920 U
920 U
920 U
920 U
920 U
460 U
460 U
460 U
460 U
460U
460 U
460 U
460 U
460 U
460 U
460U
460U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
550 J
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
670 U
MB^^^HMM
Co
M^^^MM^M
580 U
580 U
580 U
580 U
580 U
320 J
320 U
320 U
320 U
320 U
320 U
320 U
410J
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 J
320 U
320 U
320 U
410J
330 J
490 J
340 J
320 U
320 U
320 U
320 U
320 U
320 U
510U
^M^^^^
Cu
^WM^^^HM
55 U
55 U
55 U
55 U
55 U
100 U
100U
100U
100U
100 U
100U
100U
100U
100U
IOOU
100U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
120 U
-^^ ^
Fe
i^ ป_-_
20000
19000
16000
17000
17000
17000
1600 U
13000
16000
16000
15000
15000
15000
17000
15000
15000
15000
16000
18000
14000
17000
19000
21000
19000
16000
15000
22000
18000
17000
17000
17000
19000
17000
16000
16000
Ph
r u
M^^^HMHM
89
62 J
34 J
50 J
23 U
81
24 U
65 J
70 J
110
83
53 J
270
48 J
24 U
24 U
29 J
25 J
24 U
46 J
31 J
25J
130
150
42 J
53 J
59 J
290
130
110
30 J
100
81
93
53 J
Mn
ivi n
^M^^^^^MM
420 U
420 U
420 U
420 U
420 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400U
400U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400U
400 U
400 U
620 J
400U
400 U
470 J
400U
400 U
400U
420 J
330 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 3 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0200MNSE1 6/7/2002
S0200MNSF1 6/7/2002
S0200MNSGI 6/7/2002
S0200RAMA1 6/8/2002
S0200RAMB1 6/8/2002
S0200RAMC1 6/8/2002
S0200RAMD1 6/8/2002
S0200RAME1 6/8/2002
S0200RAMF1 6/8/2002
S0200RAMG1 6/8/2002
S0200R AMG 1 R 6/8/2002
S0200RAMH1 6/8/2002
S0200RAMI1 6/8/2002
S0200RAMJ1 6/8/2002
S0200RAMK1 6/8/2002
S0200RAML1 6/8/2002
S0201SP1DI 6/12/2002
S0201SPIS1 6/8/2002
S0201SP1S2 6/8/2002
S0201SP1S2D 6/8/2002
S0201SP1S3 6/8/2002
S02021S1SI 6/8/2002
S02021S1S2 6/8/2002
S0202CE1S1 6/9/2002
S0202CE1S2 6/9/2002
S0202LPNE1 6/8/2002
S0202LPNWI 6/8/2002
S0202LPSE1 6/8/2002
S0202LPSE1D 6/8/2002
S0202LPSW1 6/8/2002
S0202LPTC1 6/8/2002
S02035L1S1 6/10/2002
S02035L1S2 6/10/2002
S0205ALIS1 6/9/2002
S0205AL1S2 6/9/2002
TIME
1455
1459
1504
822
826
830
834
838
841
846
850
854
858
902
906
910
910
1632
1636
1640
1646
1523
1531
1326
1334
1128
1123
1111
1115
1119
1131
1038
1046
1159
1202
Sb
51 U
51 U
51 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
62 U
45 U
45 U
45 U
560
45 U
45 U
66 U
66 U
45 U
45 U
45 U
45 U
45 U
45 U
62 U
62 U
66 U
66 U
As
38 U
38 U
54 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
73 J
51 U
51 U
51 U
51 U
46 J
5IU
51 U
51 U
180
51 U
51 U
51U
51 U
51 U
51 U
51 U
51U
51 U
51 U
43 U
43 U
51U
51 U
Ba
460
430 J
310J
410
420
430
540
450
460
460
390
420
440
480
330
410
360
420
390
410
420
350
360
430
370
360
330
380
390
370
380
370
360
390
390
Cd
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
210U
210U
130 U
130 U
130 U
130U
130 U
130 U
150 U
150 U
210U
210 U
Ca
13000
14000
13000
21000
23000
22000
12000
23000
21000
11000
13000
14000
15000
9000 J
8700 J
6500 J
5800 J
19000
11000
12000
20000
11000
9500 J
12000
13000
7900 J
8500 J
6400 J
7700 J
6700 J
4200 J
13000
15000
11000
9500
CrHI
410J
620 J
660 J
600 J
490 U
910 J
610J
490 U
490 U
560 J
730 J
490 U
490 U
630 J
490 U
600 J
480 J
540 J
490 U
590 J
6IOJ
670 J
620 J
560 J
620 J
780 J
490 U
490 U
490 U
790 J
490 U
640 J
650 J
700 J
630 J
CrLO
460 U
500 J
460 U
610U
610U
610 U
610U
610U
610U
6IOU
610U
610 U
610U
610U
610U
610 U
670 U
6IOU
610U
610U
610U
610U
610 U
500 U
500 U
610U
610 U
610U
610 U
610 U
6IOU
500 U
500 U
500 U
500 U
Co
350 J
320 U
320 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
510U
630 U
630 U
630 U
630 U
630 U
630 U
540 U
540 U
630 U
630 U
630 U
630 U
630 U
630 U
330 U
330 U
540 U
540 U
Cu
100 U
100U
100U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
120 U
76 U
76 U
76 U
76 U
76 U
76 U
41 U
41 U
76 U
76 U
76 U
76 U
76 U
76 U
SOU
SOU
41 U
41 U
Fe
16000
15000
17000
17000
17000
17000
12000
20000
18000
20000
20000
22000
18000
18000
17000
20000
23000
20000
17000
17000
22000
18000
16000
20000
19000
16000
16000
15000
15000
16000
18000
15000
15000
16000
18000
Pb
71 J
61 J
540
56 J
21 U
21 U
39 J
21 U
32 J
63 J
51 J
21 U
100
130
110
80
110
140
26 J
41 J
1700
66 J
28 J
71 J
35 U
21 U
21 U
21 U
21 U
21 U
21 U
25J
16U
35 U
35 U
Mn
400 U
400 U
400 U
440U
440U
440U
440U
440 U
440U
440U
440U
440U
440 U
440 U
500 J
440U
5IOJ
820 J
440 U
440 U
440 U
440U
440 U
640 U
770 J
440U
560 J
440 U
440U
440 U
440 U
510 U
510U
640 U
640U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 4 of 19
-------
TABLE 1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0205AL1S3
S0205MN1S1
S0205MNIS2
S0205RN1S1
S02061S1D1
S02061SISI
S02061S1S2
S02061S1S3
S02063WISI
S02063W1S2
S0208CE1S1
S0208CE1S2
S0208CE1S3
S0208MN1S1
S0208MN1S2
S0208MN1S3
S0209RWIS1
S0210SP1S1
S0210SP1S2
S02111S1S1
S02111S1S2
S02I1SP1SI
S0211SP1S2
S0213SP1S1
S02I3SP1S2
S0225FC1S1
S0225FC1S1D
S0225FCIS2
S03002WNF1
S03002WNGI
S03002WSF1
S03002WSG1
S03003ENAI
S03003ENBI
S03003ENC1
II - The analv<
DATE
6/9/2002
6/10/2002
6/10/2002
6/1 1/2002
6/12/2002
6/8/2002
6/8/2002
6/8/2002
6/10/2002
6/10/2002
6/9/2002
6/9/2002
6/9/2002
6/1 1/2002
6/1 1/2002
6/11/2002
6/11/2002
6/12/2002
6/12/2002
6/8/2002
6/8/2002
6/8/2002
6/8/2002
6/8/2002
6/8/2002
6/12/2002
6/12/2002
6/12/2002
6/1 1/2002
6/1 1/2002
6/11/2002
6/1 1/2002
6/6/2002
6/6/2002
6/6/2002
t(* u/ac not
TIME
1207
853
857
813
942
1543
1551
1559
1017
1022
1338
1341
1346
833
838
843
822
853
858
1607
1616
1650
1655
1658
1702
832
844
849
1446
1450
1435
1440
1627
1631
1635
dt*tt*f*tt>A
Sb
66 U
62 U
62 U
75 U
62 U
45 U
45 U
45 U
62 U
62 U
66 U
66 U
66 U
75 U
79 J
2500
75 U
62 U
62 U
45 U
45 U
45 U
45 U
45 U
45 U
62 U
62 U
160 J
75 U
75 U
75 U
75 U
60U
60 U
60U
oltmtA *lปA J
As
5111
43 U
43 U
46 U
34 U
51 U
51 U
51 U
43 U
43 U
51 U
51 U
51U
46 U
81 U
1400
46 U
34 U
34 U
51 U
51 U
51 U
51 U
5IU
51 U
34 U
34 U
300
46 U
46 U
46 U
46 U
36 U
36 U
36 U
Ba
- i
420
350
300
320
510
450
540
410
380
350
400
370
410
460
410
310
380
390
380
580
330
400
520
410
370
340
440
320 J
440
320
430
390
3701
410J
450
t TlkA J-i_-
Cd
^M^H^HMM
210 U
150 U
150 U
180 U
170 U
130 J
130 U
130 U
150 U
150 U
2IOU
210 U
210U
180 U
180 U
180 U
180 U
170 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
170 U
nou
170 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
Ca
14000
13000
9000 J
10000
11000
7300 J
11000
46000
9000 J
16000
14000
13000
14000
8100 J
10000
5100J
26000
11000
12000
17000
9400 J
15000
13000
19000
13000
21000
22000
10000
13000
15000
25000
27000
15000
10000
10000
CrHI
630 J
720 J
520 J
820 J
680 J
6IOJ
580 J
610J
630 J
530 J
660 J
650 J
460 U
710J
570 J
470 J
740 J
460 J
800 J
650 J
700J
490 U
570 J
620 J
590 J
940 J
680J
760 J
430 J
530 J
730 J
580 J
720 U
720 U
720 U
CrLO
500 U
500 U
500 U
920 U
670 U
610U
610U
610U
500 U
500 U
500 U
500 U
500 U
920 U
920 U
920 U
920 U
670 U
670 U
610U
610U
6IOU
610 U
610U
610 U
670 U
670 U
670 U
920 U
920 U
920 U
920 U
840 U
840 U
840 U
Co
540 U
340 J
330 U
580 U
510U
630 U
630 U
630 U
330 U
470 J
540 U
540 U
540 U
580 U
580 U
580 U
580 U
510U
510U
630 U
630 U
630 U
630 U
630 U
630 U
510U
510U
510U
580 U
580 U
580 U
580 U
530 U
530 U
530 U
Cu
41 U
SOU
SOU
55 U
120 U
76 U
76 U
76 U
SOU
SOU
41 U
41 U
41 U
55 U
55 U
55 U
55 U
120 U
120 U
76 U
76 U
76 U
76 U
76 U
76 U
120 U
120U
120 U
55 U
55 U
55 U
55 U
100 U
100U
100U
Fe
17000
19000
16000
20000
16000
17000
17000
19000
13000
16000
18000
18000
17000
16000
19000
49000
22000
15000
16000
28000
nooo
18000
26000
16000
18000
16000
17000
24000
17000
17000
20000
23000
18000
16000
17000
Pb
35 U
54
31 J
100
43 J
21 J
510
100
16U
61
66 J
49 J
59 J
53 J
820
11000
220
53 j
39 J
110
40 J
60 J
170
100
89
55 J
130
1600
99
4IJ
23 U
39 J
36 U
190
110J
Mn
640 U
510 U
5IOU
420 U
330 U
440U
700 J
440U
510U
680 J
640U
640 U
640 U
420 U
420 U
I100J
420 U
330 U
720 J
470 J
440U
440 U
440U
440U
440U
330 U
330 U
840 J
430 J
420 U
420 U
420 U
520 J
400 U
400 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 5 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S03003END1
S03003ENE1
S03003ENF1
S03003ENG1
S03003ESA1
S03003ESA1D
S03003ESBI
S03003ESC1
S03003ESDI
S03003ESEI
S03003ESFI
S03003ESGI
S03003SEA1
S03003SEB1
S03003SEC1
S03003SEC1R
S03003SEDI
S03003SWA1
S03003SWB1
S03003SWC1
S03003SWD1
S03004SEAI
S03004SEB1
S03004SEC1
S03004SECIR
S03004SEDI
S03004SWA1
S03004SWB1
S03004SWC1
S03004SWDI
S0300AL1S1
S0300AL1S2
S0300AL1S3
S0300AL2S1
S0300CEEE1
DATE
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/7/2002
6/7/2002
6/11/2002
6/1 1/2002
6/11/2002
6/1 1/2002
6/1 1/2002
6/1 1/2002
6/11/2002
6/1 1/2002
6/1 1/2002
6/11/2002
6/11/2002
6/1 1/2002
6/12/2002
6/1 1/2002
6/1 1/2002
6/12/2002
6/12/2002
6/12/2002
6/9/2002
6/9/2002
6/9/2002
6/9/2002
6/7/2002
TIME
1639
1643
1647
1652
1655
1659
1704
1708
1711
1716
835
839
1638
1643
1648
1653
1658
1703
1707
1713
1717
1802
1806
1810
828
1814
1818
805
809
813
1143
1147
1150
1155
1423
Sb
60 U
60 U
60 U
60 U
60 U
60 U
60U
60 U
60 U
60 U
51 U
51 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
62 U
75 U
75 U
62 U
62 U
62 U
66 U
66 U
66 U
66 U
51 U
As
36 U
40 J
36 U
36 U
36 U
36 U
36 U
36 U
.54 J
36 U
38 U
38 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
34 U
46 U
59 J
37 J
34 U
54 J
51 U
51 U
51U
51 U
38 U
Ba
320 J
430 J
410 J
410J
270 J
330 J
330 J
400 J
480
470
470
550
380
370
410
400
450
300
440
420
380
390
450
380
340
230 J
260
420
380
290 J
430
390
400
380
390 J
Cd
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
130 U
130 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
170 U
180 U
180 U
170 U
170 U
170 U
210U
210U
21011
210 U
130 U
Ca
9800
9100
9800
9600
11000
12000
13000
12000
13000
17000
17000
9800
14000
20000
14000
12000
10000
18000
11000
8800 J
39000
14000
6400 J
14000
11000
68000.
21000
20000
14000
9800
12000
11000
11000
12000
15000
CrHI
820 J
720 U
720 U
720 U
840 J
9IOJ
720 U
720 U
720 U
720 U
390 J
480 J
840
690 J
670 J
490 J
500 J
550 J
690 J
530 J
630 J
680 J
440 J
820 J
530 J
620 J
690 J
600 J
440 U
870 J
730 J
670 J
630 J
550 J
470 J
CrLO
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
460 U
460 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
670 U
920 U
920 U
670 U
670 U
670 U
500 U
500 U
500 U
520 J
460 U
Co
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
320 U
320 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
510U .
580 U
580 U
510U
510U
510U
540 U
540 U
540 U
540 U
320 U
Cu
100U
100U
100 U
100U
IOOU
100U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
120 U
55 U
55 U
120 U
120U
120 U
41 U
41 U
41 U
41 U
IOOU
Fe
16000
16000
17000
16000
19000
19000
18000
20000
15000
16000
18000
17000
18000
19000
17000
17000
18000
18000
18000
17000
19000
17000
17000
18000
17000
19000
19000
14000
17000
16000
18000
18000
18000
20000
15000
Pb
ซ ^^^ i
75 J
36 U
51 J
36 U
220
220
270
180
44J
81 J
66 J
43 J
58 J
42 J
541
33 J
240
34 J
29 J
23 U
23 U
30 J
23 U
25 J
47 J
84
74 J
100
69 J
25 J
35 U
35 U
35 U
36 J
44J
Mn
^mmm^^^^^^m
400 U
400U
400U
400 U
400U
400 U
510J
400 U
400 U
400 U
460J
550 J
420 U
740 J
420 U
420 U
480 J
420 U
420 U
420 U
520]
420 U
460 J
460 J
490 J
420 U
420 U
330 U
570 J
330 U
930 J
640 U
640 U
640 U
400 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 6 of 19
-------
TABLE 1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0300CEEG1 6/7/2002
S0300CEWG1 6/7/2002
S0300FCEA1 6/8/2002
S0300FCEB1 6/8/2002
S0300FCEC1 6/8/2002
S0300FCEDI 6/8/2002
S0300PCWA1 6/8/2002
S0300FCWB1 6/8/2002
S0300FCWCI 6/8/2002
S0300MNNA1 6/7/2002
S0300MNNB1 6/7/2002
S0300MNNC1 6/7/2002
S0300MNNE1 6/7/2002
S0300MNNF1 6/7/2002
S0300MNNF1D 6/8/2002
S0300MNNG1 6/8/2002
S0300MNSAI 6/7/2002
S0300MNSB1 6/7/2002
S0300MNSC1 6/7/2002
S0300MNSD1 6/7/2002
S0300MNSFI 6/7/2002
S0300MNSG1 6/7/2002
S0300MNSG1R 6/7/2002
S0300RWSAI 6/8/2002
S0300RWSBI 6/8/2002
S0300RWSC1 6/8/2002
S0300RWSDI' 6/8/2002
S0300RWSF1 6/8/2002
S0300SPEA1 6/8/2002
S0300SPEB1 6/8/2002
S0300SPEC1 6/8/2002
S0300SPED1 6/8/2002
S0300SPEE1 6/8/2002
S0300SPEF! 6/8/2002
S0300SPEG1 6/8/2002
1 1 - Thp analvtp u/ac nnt
TIME
1427
1150
1007
1011
15
1019
1023
1027
1031
1701
1705
1709
1713
1717
814
818
1508
1513
1516
1520
1528
1532
1537
947
951
955
959
1003
1035
1039
1043
1047
1055
1059
1103
/40t Ait AS! n
Sb
51 U
51 U
45 U
45 U
45 U
66 J
47 J
45 U
45 U
51 U
51 U
51 U
51 U
51 U
45 U
50 J
51 U
51 U
51 U
53 J
51 U
51 U
51 U
45 U
553
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
As
^^^^^^^1
38 U
38 U
51 U
51 U
51U
51 U
51 U
51U
51 U
43 J
38 U
38 U
38 U
38 U
51 U
51 U
38 U
38 U
38 U
38 U
44J
38 U
38 U
51 U
51 U
56 J
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
Ba
360 J
450
380
410
420
500
520
350
420
360 J
4301
390 J
300 J
340 J
330
360
510
530
490
1600
340 J
360 J
390J
300
380
490
400
450
490
450
510
440
500
440
410
'.* TL._ ซl,.*^.
Cd
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
Ca
M^^^^^^H^^^^
8200
11000
85000
2900 U
25000
23000
34000
33000
28000
9500
9000
8600
10000
13000
12000
9700
12000
12000
11000
5600 J
5500 J
8900
7800
15000
6900 J
11000
6100 J
7500 J
12000
12000
19000
13000
11000
9500 J
9400 J
. _
CrHI
890 J
490 J
620 J
490U
490 U
670 J
490 U
710J
490 U
630 J
680 J
600 J
610J
820 J
600 J
580 J
910J
750 J
540 J
800 J
490 J
550 J
460 J
560 J
860 J
600 J
510J
580 J
640 J
490 U
490 U
560 J
500 J
640 J
530 J
CrLO
460 U
460 U
610U
610U
610 U
610U
610U
610 U
610U
460 U
460 U
460 U
460 U
590 J
610 U
6IOU
460 U
460 U
460 U
460 U
460 U
460 U
460 U
6IOU
610 U
610 U
610 U
610U
610U
610 U
610 U
610 U
610U
610U
610U
Co
320 U
320 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
410 J
320 U
360 J
320 U
320 U
630 U
630 U
320 U
320 U
320 U
320 U
320 U
390 J
320 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
Cu
100 U
100U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
100 U
100 U
100U
100U
100U
76 U
76 If
100U
100 U
IOOU
100 U
IOOU
IOOU
IOOU
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
Fe
16000
16000
18000
11000
17000
16000
16000
20000
17000
16000
17000
17000
18000
16000
16000
18000
21000
16000
17000
23000
15000
17000
17000
18000
21000
19000
17000
15000
16000
16000
16000
15000
16000
18000
18000
Pb
55 J
75 J
21 U
21 U
43 J
35 J
26 J
60 J
47 J
150
90
110
200
130
100
250
28 J
24 U
24 U
24 U
31 J
110
95
44J
26 J
21 U
49 J
34 J
30 J
54 J
31J
42 J
81
64J
110
Mn
400 U
400 U
440 U
440U
440 U
440U
440U
440U
440 U
400 U
400 U
430 J
510J
470 J
440 (j
590 J
520 J
400 U
400 U
660 J
400 U
400 U
400 U
440 U
440U
440 U
440U
440 U
440U
440 U
440U
440 U
440 U
440 U
510J
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 7 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0300SPEG1R 6/8/2002
S0304MA1S1 6/9/2002
S0304MA1S2 6/9/2002
S0304MA1S3 6/9/2002
S0304MA1S4 6/9/2002
S0304MA1S5 6/9/2002
S0304MA1S5R 6/9/2002
S03053W1SI 6/10/2002
S03053W1S2 6/10/2002
S0306AR1S1 6/9/2002
S0306AR1S2 6/9/2002
S0306AR1S3 6/9/2002
S0306AR1S3R 6/9/2002
S0306AR2S1 6/9/2002
S0306MA1S1 6/9/2002
S0306MA1S2 6/9/2002
S0306MAIS2D 6/9/2002
S0307IM1S1 6/10/2002
S0307MA1S1 6/9/2002
S0307MA1S2 6/9/2002
S0307MA1S3 6/9/2002
S0309MT1S1 6/9/2002
S0309MT1S2 6/9/2002
S0309MT1S3 6/9/2002
S03102E1S1 6/8/2002
S03I1MA1S1 6/9/2002
S0311MA1S2 6/9/2002
S0311MA1S3 6/9/2002
S0311MN1S1 6/10/2002
S0311MN1S2 6/10/2002
S0319OM1S1 6/10/2002
S0319OM1S2 6/10/2002
S0319OM1S3 6/10/2002
S04002WNA1 6/11/2002
S04002WNB1 6/11/2002
U - Thp analvtp was nnt
TIME
1107
1302
1306
1310
1314
1318
1322
1010
1013
1507
1511
1516
1520
1559
1250
1254
1258
1544
1238
1242
1246
1640
1652
1656
1619
1226
1230
1234
901
905
1414
1427
1444
1521
1526
Hซปtprtfw4 4
Sb
45 U
66 U
66 U
66 U
66 U
66 U
66 U
62 U
62 U
66 U
66 U
66 U
66 U
66 U
66 U
66 U
66 U
62 U
66 U
66 U
66 U
66 U
66 U
66 U
45 U
66 U
66 U
66 U
62 U
62 U
62 U
62 U
62 U
75 U
75 U
. . ~
Vt/MfA tit a f\t
As
51 U
51U
51 U
5IU
51 U
51 U
51U
43 U
43 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
43 J
51 U
51 U
51 U
51U
51U
51 U
51U
51U
51 U
s'iu
43 U
45 J
43 U
43 U
43 U
46 U
46 U
Ba
390
330
370
360
480
390
380
420
390
400
340
300
390
360
370
370
380
440
300
300
390
380
380
350
430
560
350
320
370
380
420
460
480
450
230 J
Cd
130 U
210U
210U
210U
210U
210 U
210U
150 U
150 U
210U
210U
210 U
210U
210 U
210 U
210 U
210 U
150 U
210U
210 U
210U
210U
210U
2IOU
130 U
210 U
210U
210 U
150 U
150 U
150 U
150 U
150 U
180 U
180 U
Ca
8600 J
15000
12000
14000
10000
15000
14000
9100J
16000
11000
8900
9800
11000
9300
16000
11000
11000
24000
16000
16000
14000
11000
10000
17000
11000
11000
14000
18000
11000
9000 J
18000
18000
14000
17000
13000
CrHI
580 J
9IOJ
680 J
480 J
730 J
690 J
730 J
670 J
600 J
460 U
800 J
590 J
640J
6901
690 J
460 J
570 J
900 J
780 J
590 J
560 J
680 J
570 J
720 J
580 J
8IOJ
670 J
890 J
510J
450 J
380 J
690 J
590 J
490 J
950
CrLO
610 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 y
500 U
500 U
500 U
500 U
610U
. 500 U
500 U
- 500 U
500 U
500 U
500 U
500 U
500 U
920 U
920 U
Co
630 U
540 U
540 U
540 U
540 U
540 U
540 U
330 U
350 J
540 U
540 U
540 U
540 U
540 U
.540U
540 U
540 U
330 U
540 U
540 U
540 U
540 U
540 U
540 U
630 U
540 U
540 U
540 U
330 U
330 U
330 U
330 U
330 U
580 U
580 U
-
Cu
76 U
41 U
41 U
41 U
41 U
41 U
41 U
SOU
SOU
41 U
41 U
41 U
41 U
41 U
41 U
41 U
41 U
SOU
41 U
41 U
41 U
41 U
41 U
41 U
76 U
41 U
41 U
41 U
SOU
SOU
SOU
SOU
SOU
55 U
55U
=
Fe
17000
24000
20000
20000
21000
20000
19000
17000
21000
21000
18000
17000
18000
19000
21000
22000
23000
23000
21000
22000
19000
20000
18000
19000
17000
20000
22000
22000
18000
17000
18000
18000
16000
15000
21000
Pb
100
35 U
35 U
60 J
35 U
89 J
120
54
30 J
35 U
35 U
180
190
35 U
35 U
35 U
35 U
120
35 U
35 U
35 U
35 U
35 U
35 U'
59 J
35 U
36 J
69 J
36 J
16U
48 J
55
30 J
350
50 J
Mn
440 U
640U
640U
640U
640U
640U
640U
510U
510U
640 U
640 U
640 U
640U
640 U
800 J
740 J
730 J
1200J
820 J
660 J
640 U
640 U
640 U
640U
650 J
640 U
1100J
640 U
510U
510 U
510J
510U
510U
420 U
420 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 8 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S04002WNC1 6/11/2002
S04002WNCIRS/1 1/2002
S04002WND1 6/11/2002
S04002WNE1 6/11/2002
S04002WSA1 6/11/2002
S04002WSB1 6/11/2002
S04002WSC1 6/11/2002
S04002WSD1 6/11/2002
S04002WSE1 6/11/2002
S04003ENA1 6/7/2002
S04003ENB1 6/7/2002
S04003ENC1 6/7/2002
S04003END1 6/7/2002
S04003ENE1 6/7/2002
S04003ENF1 6/7/2002
S04003ENG1 6/7/2002
S04003ESA1 6/7/2002
S04003ESB1 6/7/2002
S04003ESC1 6A7/2002
S04003ESD1 6/7/2002
S04003ESDX 6/12/2002
S04003ESEI 6/7/2002
S04003ESF1 6/7/2002
S04003ESG1 6/7/2002
S04003ESG1D 6/7/2002
S04003ESG1R 6/7/2002
S0400DI1S1 6/12/2002
S0400EHCC1 6/8/2002
S0400EM1S1 6/11/2002
S0400EM1S2 6/11/2002
S0400EM1S3 6/11/2002
S0400EM1S4 6/11/2002
S0400EM1S5 6/11/2002
S0400HS1S1 6/11/2002
S0400HS1S2 6/11/2002
TIME
1531
1559
1540
1553
1457
1502
1506
1511
1516
843
847
851
855
859
903
907
911
915
919
923
837
927
932
936
940
944
817
1354
1123
1128
1134
1138
1144
1047
1052
Sb
75 U
75 U
75 U
75 U
75 U
75 U
75 U
130 J
75 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51U
51 U
51 U
51 U
62 U
250
51 U
51U
51 U
51 U
62 U
45 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
As
46 U
58 J
46 U
60 J
46 U
46 U
46 U
100J
46 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
38 U
34 U
220 U
43 J
38 U
38 U
38 U
34 U
51 U
46 U
47 J
46 U
46 U
46 U
46 U
48 J
Ba
430
400
390
430
370
430
440
360
400
580
510
550
500
360 J
460
400 J
380 J
430]
490
530
390
340 J
450
390 J
450
380 J
440
410
360
370
370
240
470
350
290
Cd
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
130 U
130 U
130 U
130 U
130 U
130U
130 U
130 U
130 U
130 U
130 U
170 U
130 U
130 U
130U
130 U
130 U
170 U
130 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
Ca
8500 J
53000
9400 J
47000
35000
12000
9500 J
6600 J
11000
9700
7300 J
17000
17000
11000
7500 J
8800
9400
11000
17000
24000
7200 J
11000
15000
12000
9600
11000
15000
7000 J
8000 J
12000
21000
9200 J
12000
11000
14000
CrHI
750 J
480 J
540 J
670 J
530 J
550 J
530 J
900
650 J
590 J
460 J
470 J
570 J
820 J
370 U
800 J
840 J
630 J
680 J
480J
580 J
600 J
370 U
670 J
660 J
570 J
440 U
580 J
680 J
530 J
560 J
650 J
510)
620 J
430 J
CrLO
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
670 U
460 U
460 U
460 U
460 U
460 U
670 U
610U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
Co
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
320 U
350 J
510U
460 J
320 U
320 U
320 U
390 J
510U
630 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
Cu
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
120 U
100U
100U
100U
100 U
100U
120 U
76 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
Fe
16000
16000
16000
17000
18000
21000
19000
21000
17000
14000
13000
17000
16000
16000
13000
14000
19000
16000
18000
16000
18000
26000
15000
17000
15000
15000
15000
15000
22000
21000
18000
22000
23000
19000
19000
Pb
33 J
23 U
48 J
23 U
27 J
68 J
23 U
770
85
38 J
24 U
38 J
24 U
160
32 J
37 J
78 J
68]
43 J
24 U
23 U
2200
230
100
110
110
43]
21 U
23 U
23U
23 U
30 J
25 J
23 U
29 J
Mn
420 U
420 U
420 U
420 U
690 J
420 U
420 U
600 J
420 U
400U
400 U
400 U
400 U
430 J
400 U
400 U
400 U
400 U
400 U
400 U
330 U
840]
400 U
400 U
400 U
400 U
350 J
440U
420 U
570 J
420 U
490 J
420 U
420 U
420 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 9 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE TIME
S0400HS1S3 6/11/2002
S0400HS1S4 6/11/2002
S0400HS1S5 6/11/2002
S0400HS1S6 6/11/2002
S0400HT1S1 6/9/2002
S0400HT2DC 6/9/2002
S0400HT2DCB6/10/2002
S0400HT2S1 6/9/2002
S0400HT2S2 6/9/2002
S0400HT2S3 6/9/2002
S0400HT2S4 6/9/2002
S0400HT3S1 6/9/2002
S0400HT4D1 6/10/2002
S0400HT4D2 6/10/2002
S0400HT4D3 6/10/2002
S0400HT4S1 6/11/2002
S0400HT4S1D 6/1 1/2002
S0400ILEA1 6/11/2002
S0400ILEB1 6/11/2002
S0400ILEC1 6/1 1/2002
S0400ILED1 6/11/2002
S0400ILEEI 6/1 1/2002
S0400ILEF1 6/11/2002
S0400ILEG1 6/11/2002
S0400ILEG1D 6/11/2002
S0400ILWA1 6/1 1/2002
S0400ILWB1 6/11/2002
S0400ILWC1 6/11/2002
S0400ILWD1 6/11/2002
S0400ILWE1 6/1 1/2002
S0400ILWF1 6/1 1/2002
S0400ILWG1 6/11/2002
S0400ILWG1R 6/1 1/2002
S0400MAEA1 6/6/2002
S0400MAEB1 6/6/2002
1043
1058
1102
1119
1556
1620
1102
1604
1608
1612
1616
1623
1050
1054
1058
1149
1200
1255
1302
1307
1310
1314
1319
1322
1326
1208
1213
1218
1236
1222
1227
1232
1241
1249
1252
Sb
75 U
75 U
75 U
75 U
66U
66 U
62 U
66 U
66 U
66 U
66 U
66U
310
1000
200 i
1700
1800
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
60 U
60 U
As
46 U
46 U
46 U
46 U
51 U
51 U
43 U
51 U
51 U
51 U
51 U
51 U
190 U
630
370
1700
1800
46 U
46 U
46 U
46 U
46 U
46 U
74 J
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
46 U
36 U
36 U
Ba
430
420
400
400
330
410
53 U
320
350
330
350
400
370
340
380
230 J
220 J
400
380
400
410
340
360
430
380
410
410
410
280
440
370
440
430
440
440
Cd
I80U
I80U
180 U
180 U
210U
210U
150 U
210U
210U
210U
210 U
210U
150 U
150 U
150 U
180 U
180 U
180 U
180 U
I80U
180U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
220 J
180 U
180 U
180 U
180 U
180 U
Ca
8500 J
7800 J
21000
7500 J
18000
18000
2900 U
7500
10000
9900
15000
13000
15000
14000
25000
3100 J
3700 J
11000
9500 J
13000
20000
13000
9900 J
16000
15000
13000
12000
18000
13000
18000
23000
18000
15000
18000
23000
CrHI
780 J
560 J
720 J
610J
620 J
550 J
360 U
460 U
780 J
460 U
460 U
460 U
720 J
520 J .
500 J
390 J
440 J
460 J
500 J
580 J
760 J
730 J
390J
750 J
730 J
580 J
340 J
450 J
980
310J
710J
590 J
480 J
720 U
720 U
CrLO
920 U
920 U
920 U
920 U
500 U
500 U
500 U
500 U
500 U
500 U
5001)
500 U
500 U
500 U
500 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
920 U
840 U
840 U
Co
580 U
580 U
580 U
580 U
540 U
540 U
330 U
540 U
540 U
540 U
540 U
540 U
330 U
330 U
330 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
580 U
530 U
530U
Cu
55 U
55 U
55 U
55 U
41 U
41 U
SOU
41 U
41 U
41 U
41 U
41 U
SOU
SOU
SOU
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
55 U
IOOU
100 U
Fe
16000
16000
18000
19000
14000
17000
1600 U
15000
17000
16000
13000
19000
26000
37000
22000
51000
53000
17000
16000
16000
16000
16000
18000
15000
14000
20000
18000
17000
24000
18000
22000
17000
16000
17000
18000
Pb
23 U
27 J
26 J
38 J
35 U
35 U
16U
35 U
46 J
35 J
35 U
130
1900
4400
1100
9000
9200
34 J
36]
29 J
30 J
49 J
55 J
70 J
56 J
23 U
23 U
23 U
23 U
23 U
23 U
27 J
38 J
36 U
36 U
Mn
420 U
420 U
420 U
560 J
640 U
640 U
510 U
640U
640 U
640 U
640 U
640 U
I500J
2100
1000 J
2700
3000
420 U
420 U
420 U
420 U
420 U
610 J
420 U
420 U
520 J
480 J
420 U
420 U
420 U
420 U
420 U
420 U
400 U
400 U
U - The analyte was not detected above the detection limit. The detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 10 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0400MAEC1 6/6/2002
S0400MAED1 6/6/2002
S0400MAEE1 6/6/2002
S0400MAEF1 6/6/2002
S0400MAWA1 6/6/2002
S0400MAWB1 6/6/2002
S0400MAWC1 6/6/2002
S0400MAWD1 6/6/2002
S0400MAWE1 6/6/2002
S0400MAWF1 6/6/2002
S0400MNIS1 6/10/2002
S0400MN1S2 6/10/2002
S0400MNNA1 6/7/2002
S0400MNNB1 6/7/2002
S0400MNNC1 6/7/2002
S0400MNNDI 6/7/2002
S0400MNSA1 6/7/2002
S0400MNSA ID 6/7/2002
S0400MNSB1 6/7/2002
S0400MNSC1 6/7/2002
S0400MNSD1 6/7/2002
S0400PAMAI 6/6/2002
S0400PAMB1 6/6/2002
S0400PAMC1 6/6/2002
S0400PAMD1 6/6/2002
S0400PAMD1D 6/6/2002
S0400PAME1 6/6/2002
S0400PAMF1 6/6/2002
S0400PAMG1 6/6/2002
S0400PAMG1R 6/6/2002
S0400SAMA1 6/6/2002
S0400SAMB1 6/6/2002
S0400SAMB1D 6/6/2002
S0400SAMC1 6/6/2002
S0400SAMD1 6/6/2002
11 - Thp. analvtp vuac nnt
TIME
1257
1301
1305
1325
1224
1228
1232
1236
1240
1244
908
913
1605
1610
1617
1622
1540
1544
1553
1558
1601
1329
1334
1338
1342
1346
1400
1404
1408
1412
519
1523
1527
1532
1537
sfafA/*ff>rl o
Sb
60 U
60 U
60 U
60 U
60U
60 U
60 U
60 U
60 U
60 U
62 U
62 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
60 U
60 U
60 U
60 U
60 U
60 U
60U
60 U
60U
60 U
60 U
60 U
60U
60U
Krtvrik fit A A.
As
MMWMMM^M^
36 U
36 U
41 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
43 U
43 U
38 U
38 U
38 U
38 U
38 U
38 U
50 J
38 U
51J
36 U
110J
36 U
36 U
36 U
41 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
Ba
^^^^^M
400 J
450
300 J
310J
440
460
510
4IOJ
370 J
450
390
410
440
450
450
520
450
470
480
320J
410J
480
520
460
640
570
440
460
430 J
430 J
530
450
440
500
520
* Tlป rl*.t~.
Cd
^^M^
180 U
180 U
180 U
180 U
180 U
I80U
180 U
180 U
200 J
180 U
150 U
150 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
Ca
17000
1 1000
9400
8500
9100
12000
6800 J
8000
23000
21000
9700
14000
7100 J
6900 J
9200
6700 J
10000
12000
7700
9800
9200
10000
10000
10000
16000
15000
15000
11000
15000
16000
11000
14000
14000
14000
11000
_ . _ j
CrHI
720 U
720 U
720 U
950 J
720 U
720 U
720 U
900 J
830 J
720 U
810]
570 J
670 J
650 J
560 J
430 J
500 J
440 J
370 U
430 J
560 J
720 U
720 U
720 U
720 U
850 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
CrLO
^MMMM^H^M^M
840 U
840 U
840U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
500 U
500 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
460 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840U
Co
^ซซ^ซป
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
330 U
330 U
320 U
320 U
320 J
320 U
320 U
320 U
320 U
320 U
320 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U '.
530 U
530 U
530 U
530 U
530 U
530 i)
Cu
100 U
100U
100U
100U
100U
100U
100U
100 U
100 U
100 U
sou
sou
100U
100 U
100U
100U
100U
100 U
100U
100U
100U
100U
100U
100 U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
Fe
14000
16000
19000
19000
17000
18000
13000
20000
18000
18000
15000
16000
15000
15000
15000
13000
16000
16000
14000
14000
15000
15000
15000
17000
18000
19000
18000
19000
17000
16000
17000
18000
17000
16000
14000
Pb
54J
70 J
73 J
110]
83 J
150
no;
80 J
62 J
36 U
16 U
27 J
24 U
24 U
41 J
24 U
24 U
24 U
24 U
41 J
69 J
65 J
230
260
74 J
71 J
160
83 J
140
190
36 U
42 J
39 J
36 U
36 U
Mn
400U
400U
400U
430 J
580 J
400 U
400 U
400U
400 U
400 U
S10U
510U
400 U
400U
400U
400 U
400U
400 U
400 U
400 U
400 U
530 J
410 J
400 U
400 U
400U
400 U
400 U
400 U
400 U
400 U
400 U
400U
400 U
400 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page If ofI9
-------
TABLE 1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0400SAME1
S0400SAMF1
S0400SAMGI
S0400SAMG1R
S0400SPEA1
S0400SPEB1
S0400SPECI
S0400SPED1
S0400SPEDX
S0400SPEE1
S0400SPEF1
S0400SPEG1
S0400SPWA1
S0400SPWBI
S0400SPWC1
S0400SPWDI
S0400SPWEI
S0400SPWF1
S0400SPWG1
S04032W1D3
S04032W1SI
S04032W1S2
S04032W1S3
DATE TIME
6/6/2002
6/6/2002
6/6/2002
6/7/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/12/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/6/2002
6/12/2002
6/10/2002
6/10/2002
6/10/2002
S04032W1S3R 6/10/2002
S04031L1SI
S0403IL1S2
S0403IL1S3
S0403RW1S1
S0403RWIS2
S0404AL1S1
S0404AL1S2
S0404ALIS3
S0404AR1S1
S0404AR1S2
S04053E1S1
6/9/2002
6/9/2002
6/9/2002
6/1 1/2002
6/11/2002
6/9/2002
6/9/2002
6/9/2002
6/9/2002
6/9/2002
6/8/2002
1540
1549
1553
1025
1356
1422
1425
1429
902
1434
1438
1442
1446
1450
1454
1458
1502
1507
1510
825
949
953
957
1005
1628
1632
1635
817
828
1214
1219
1222
1459
1503
1623
Sb
60 U
60 U
60 U
51 U
60 U
60 U
280
85 J
62 U
75 J
60 U
160 J
60 U
60'U
60 U
60 U
60 U
100 J
60 U
62 U
62 U
62 U
1500
1800
66 U
66 U
66 U
75 U
75 U
66 U
66 U
66 U
66 U
66 U
45 U
As
39 J
36 U
36 U
38 U
36 U
36 U
400
68 J
34 U
67 U
170
150
36 U
36 U
36 U
36 U
36 U
44 U
36 U
34 U
43 U
43 U
1200
1300
51U
51 U
51U
46 U
46 U
51 U
51U
51U
51,U
51U
51 U
Ba
470
4IOJ
390 J
430 J
450
400 J
380 J
480
450
410 J
420 J
450
390 J
390 J
450
430 J
450
480
410J
510
390
450
290
280
320
350
370
370
460
380
340
470
420
390
460
Cd
180 U
180 U
180 U
130 U
180 U
180 U
180 U
180 U
170 U
180 U
180 U
180 U
180U
180 U
180 U
180 U
180 U
180 U
180 U
170 U
150 U
150 U
150 U
150 U
210U
210U
210U
180 U
180 U
210U
210U
210U
2IOU
210U
130 U
Ca
15000
10000
15000
17000
14000
12000
IIOOO
13000
7900
IIOOO
20000
10000
8800
IIOOO
11000
15000
7500
7200
11000
11000
12000
UOOO
7600 J
7300 J
14000
" 1 4000
33000
10000
14000
18000
12000
12000
10000
10000
19000
CrHI
720 U
720 U
720 U
6IOJ
720 U
720 U
720 U
720 U
440 U
720 U
720 U
840 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
520 J
760 J
620 J
740 J
590 J
520 J
590 J
530 J
580 J
760 J
970 J
590 J
520 J
810J
660 J
490 U
CrLO
840 U
840 U
840 U
460 U
840 U
840 U
840 U
840 U
670 U '
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
670 U
500 U
500 J
. 500 U
500 U
500 U
500 U
500 U
920 U
920 U
500 U
500 U
500 U
500 U
500 U
610U
Co
530 U
.530U
530 U
320 U
530 U
530 U
530 U
530 U
510U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
510U
360 J
330 U
420 J
510J
540 U
540 U
540 U
580 U
580 U
540 U
540 U
540 U
540 U
540 U
630 U
Cu
IOOU
100U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
120 U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
120 U
sou
sou
sou
sou
41 U
41 U
41 U
55 U
55 U
41 U
41 U
41 U
41 U
41 U
76 U
Fe
18000
18000
14000
14000
16000
15000
24000
21000
15000
20000
17000
26000
18000
16000
15000
15000
13000
15000
19000
17000
18000
16000
45000
49000
18000
18000
18000
16000
17000
22000
16000
16000
16000
16000
18000
Pb
36 U
51 J
36 U
29 J
130
120
1800
300
23 U
670
270
1300
61 J
60 J
58 J
45 J
97 J
440
54.J
110
20 J
62
8000
9400
35 U
35 U
35 U
33 J
120
35 U
35 U
78 J
35 U
35 U
27 J
Mn
400U
400 U
400U
400 U
400 U
430 J
760 J
400 U
330 U
600 J
400 U
600 J
400 U
400 U
510J
400 U
400 U
400 U
400 U
580 J
530 J
510 U
3600
2900
640 U
640 U
640 U
420 U
420 U
1200 J
640 U
640 U
640U
640U
440U
U - The analyte was not detected above the detection limit. The detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 12 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9QOQ XRF DATA (PPM)
ID DATE
S04053E1S2 6/8/2002
S0407IH1D1 6/12/2002
S0407IM1S1 6/10/2002
S05002WNA1 6/11/2002
S05002WNB1 6/11/2002
S05002WNC1 6/11/2002
S05002WSA1 6/11/2002
S05002WSB1 6/11/2002
S05002WSC1 6/11/2002
S05003E1S1 6/9/2002
S05003E1S2 6/9/2002
S05003E1S3 6/9/2002
S05003EIS3D 6/9/2002
S0500EHCC1 6/8/2002
S0500EHNE1 6/8/2002
S0500EHSE1 6/8/2002
S0500MN1D1 6/12/2002
S0500MN1S1 6/10/2002
S0500MN1S2 6/10/2002
S0500PDEA1 6/6/2002
S0500PDEB1 6/6/2002
S0500PDEC1 6/6/2002
S0500PDED1 6/6/2002
S0500PDEE1 6/6/2002
S0500PDEF1 6/6/2002
S0500PDEG1 6/6/2002
S0500PDEH1 6/6/2002
S0500PDEH1R 6/6/2002
S0500PDWA1 6/6/2002
S0500PDWB1 6/6/2002
S0500PDWC1 6/6/2002
S0500PDWD1 6/6/2002
S0500PDWE1 6/6/2002
S0500PDWE1D 6/6/2002
S0500PDWF1 6/6/2002
TIME
1628
929
1553
1625
1629
1634
1605
1615
1620
1118
1122
1126
1130
1338
1346
1342
954
917
925
1104
1108
1113
1116
1120
1125
1128
1132
1137
1141
1144
1149
1153
1156
1201
1204
Sb
^ซ
45 U
85 J
160 J
75 U
75 U
75 U
75 U
75 U
75 U
66 U
66 U
66 U
66U
45 U
45 U
45 U
62 U
HOJ
62 U
60 U
60 U
60 U
60 U
60U
60 U
60 U
60 U
60 U
60 U
60U
60 U
60 U
60 U
60 U
60U
As
i^BMB^^MH
51 U
110J
170 U
46 U
46 U
46 U
46 U
46 U
46 U
51 U
51 U
51 U
51U
51U
51U
5IU
34 U
\OOVJ
43 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
46 J
36 U
36 U
39 J
36 U
36 J
36 U
36 U
36 U
Ba
ป
400
320
430
440
400
490
400
440
410
480
440
440
400
460
340
380
430
360
440
330 J
360)
360 J
320 J
400J
360 J
400 J
400 J
340 J
390 J
310J
290 J
400 J
310J
320 J
330 J
Cd
^^MW^tM
130 U
170 U
150J
180 U
180 U
180 U
180 U
180 U
180 U
210U
210U
210U
210U
130 U
130 U
130 U
170 U
150 U
150 U
180 U
180 U
180 U
180 U
180 U
I80U
180 U
180 U
180 U
180 U
180 U
I80U
180 U
180 U
180 U
180 U
Ca
12000
37000
19000
31000
24000
17000
14000
15000
12000
13000
14000
14000
12000
7000 J
60001
8100J
9900
15000
13000
8200
8600
9400
34000
9100
8100
9300
8400
7500
9400
16000
14000
9400
10000
11000
1 1000
CrHI
5001
990 J
690 J
600 J
850
500 J
710J
610 J
670 J
460 U
820 J
860 J
840 J
520 J
490 U
490 U
490 J
550 J
560 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
740 J
720 U
720 U
720 U
740 J
720 U
720 U
720 U
720 U
CrLO
610 U
670 U
500 U
920 U
920 U
920 U
920 U
920 U
920 U
500 U
500 U
500 U
500 U
610U
610U
610U
670 U
500 U
500 U
840 U
840 U
840 U
840 U
840 U
840 U
840U
840 U
840 U
840U
840 U
840 U
840 U
840 U
840 U
840 U
Co
630 U
510U
330 U
580 U
580 U
580 U
580 U
580 U
580 U
540 U
540 U
540 U
540 U
630 U
630 U
630 U
510U
330 U
330 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
Cu
76 U
120 U
88 J
55 U
55 U
55 U
55 U
55 U
55 U
41 U
41 U
41 U
41 U
76 U
76 U
76 U
120 U
SOU
SOU
100U
100U
100 U
100 U
100U
100U
100 U
100U
100 U.
100 U
100U
100U
IOOU
100U
IOOU
IOOU
Fe
17000
30000
28000
19000
18000
17000
21000
17000
18000
17000
20000
19000
19000
16000
8700
15000
15000
20000
17000
17000
16000
16000
13000
16000
15000
16000
19000
17000
14000
18000
17000
17000
16000
17000
18000
Pb
43 J
820
1700
23 U
23 U
160
53 J
60 J
61 J
35 U
42 J
35 U
35 U
21 U
21 U
21 J
38 J
1000
32 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
90)
38J
36 U
42 J
36 U
36 U
37 J
41 J
47 J
Mn
440U
870 J
1300J
420 U
420 U
420 U
420 U
430 J
420 U
640U
640U
640U
640U
440 U
440 U
440 U
330 U
650)
510U
420)
590)
400 U
400 U
400U
400 U
400 U
400 U
420 J
400 U
400 U
400 U
400U
400 U
400U
400 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 13 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S0500PDWG1 6/6/2002
S0500PDWH1 6/6/2002
S0500PDWI1 6/6/2002
S0500SESAI 6/8/2002
S0500SESB1 6/8/2002
S0500SESCI 6/8/2002
S0500SESD1 6/8/2002
S0502MNIS1 6/10/2002
S0502MN1S2 6/10/2002
S05103E1SI 6/9/2002
S05103E1S2 6/9/2002
S06004AMA1 6/6/2002
S06004AMB1 6/6/2002
S06004AMC1 6/6/2002
S06004AMDI 6/6/2002
S06004AME1 6/6/2002
S06004AMFI 6/6/2002
S06004AMG1 6/6/2002
S06004AMH1 6/6/2002
S06004AMI1 6/6/2002
S06004AMJ1 6/6/2002
S06004AMK1 6/6/2002
S06004AML1 6/6/2002
S06004AMM1 6/6/2002
S06004AMN1 6/6/2002
S06004AMOI 6/6/2002
S06004AMP1 6/6/2002
S06004AMQ1 6/6/2002
S06004AMQ1D 6/6/2002
S06004AMR1 6/6/2002
S06004AMS1 6/6/2002
S06004AMT1 6/6/2002
S06004AMU1 6/6/2002
S06004AMU1R 6/6/2002
S06004AMV1 6/6/2002
TIME
1208
1216
1220
1322
1326
1330
1334
929
933
1134
1138
914
919
923
931
93.5
938
943
947
956
959
1004
1008
1012
1016
1020
1024
1028
1032
1036
1040
1044
1049
1056
1100
Sb
60U
60 U
60 U
45 U
45 U
45 U
45 U
62 U
62 U
66 U
66 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
As
W^M^^M
36 U
36 U
36 U
51 U
51 U
51 U
51 U
44 J
43 U
51 U
5IU
36 U
36 U
36 U
36 U
51J
36 U
36 U
36 U
36 U
40 J
36 U
36 U
36 U
36 U
36 U
41 J
36 U
36 U
48 J
36 U
36 U
36 U
36 U
42 J
Ba
350 J
330 J
360 J
420
370
450
440
420
420
420
320
390 J
400J
390 J
430 J
490
430 J
420 J
470
370 J
400 J
430 J
460
420 J
440
490
420 J
480
470
460
460
390 J
430 J
390 J
410 J
Cd
180 U
180 U
180 U
130 U
130 U
130 U
130 U
150 U
150U
210U
210U
180 U
180 U
180 U
I80U
180 U
180 U
180U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
180 U
Ca
11000
12000
11000
8300 J
10000
7300 J
8900 J
13000
9600 J
22000
14000
16000
29000
22000
17000
12000
23000
22000
21000
20000
21000
15000
17000
16000
18000
18000
16000
25000
25000
22000
22000
18000
21000
20000
14000
CrHI
720 U
720 U
720 U
490 U
610J
490 U
610J
440 J
560 J
730 J
900 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 J
720 U
720 U
720 U
720 U
740 J
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
CrLO
840 U
840 U
840 U
6IOU
610U
6IOU
610 U
500 U
500 U
500 U
500 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
Co
530 U
530 U
530 U
630 U
630 U
630 U
630 U
330 U
330 U
540 U
540 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530U
530 U
530 U
530U
Cu
100 U
100U
100 U
76 U
76 U
76 U
76 U
SOU
SOU
41 U
41 U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100 U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100U
100 U
Fe
16000
17000
15000
13000
15000
16000
15000
17000
16000
20000
20000
16000
19000
18000
17000
19000
18000
17000
18000
16000
17000
16000
18000
17000
17000
16000
16000
17000
16000
17000
15000
16000
16000
15000
1SOOO
Pb
36 U
36 U
36 U
21 U
48 J
21 U
21 U
16 U
30 J
52 J
47 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
38 J
36 U
46 J
36 U
36 U
36 U
36 U
39 J
36 U
36 U
Mn
490 J
400 U
400 U
440U
440 U
440 U
440 U
510U
510 U
640 U
640 U
400 U
400 U
400 U
400 U
400 U
400 U
400U
400 U
410J
400 U
400 U
400 U
400 U
400 U
400 U
400 U
530 J
440 J
400 U
400 U
400 U
400 U
400 U
400 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 14 of 19
must
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S06005AMAI
S06005AMBI
S06005AMC1
S06005AMD1
S06005AME1
S06005AMF1
S06005AMG1
S06005AMH1
S06005AMH1R
S06005AMII
S0600SAMJI
S06005AMK1
S06005AML1
S06005AML1D
S06005AMM1
S06005AMN1
S06005AMO1
S06005ENA1
S06005ENB1
S06005ENC1
S0600SENDI
S06005ENE1
S0600SENE1R
S06005ENF1
S06005ENGI
S06005ENH1
S06005ENI1
S06005ENJ1
S06005ENK1
S06005ENL1
S06005ENM1
S06005ENN1
S06005ENO1
S06005ENP1
S06005ENP1D
DATE
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
TIME
1352
1356
1401
1404
1413
1417
1421
1527
1531
1535
1539
1543
1547
1552
1556
1600
1604
1608
1613
1617
1621
1629
1633
1637
1641
1645
1649
1653
1657
1701
1705
1710
1713
1717
1721
Sb
SOU
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
>^ M*^M
As
^^^^^^M
31J
45 J
26 J
23 U
37 J
32 J
23 U
51J
51 J
27 J
40 J
24 J
26 J
27 J
39 J
23 U
27 J
31 J
23 U.
23 U
73 J
23 U
23 U
23 U
23 U
35 J
23 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
Ba
410
420
420
440
390
370
420
410
400
500
400
440
410
380
460
410
320
430
450
570
440
450
480
510
430
380
. 410
410
400
460
460
450
430
380
320 .
Cd
140 U
140U
140 U
140U
140U
140 U
I40U
140 U
140 U
140U
140U
140U
140U
140U
140 U
200 J
140 U
140 U
140 U
140U
140 U
140 U
140 U
140U
140 U
140 U
140 U
140 U
140U
140 U
140U
140 U
140 U
140U
140 U
Ca
33000
45000
29000
28000
40000
78000
22000
40000
55000
20000
74000
26000
28000
27000
21000
28000
71000
45000
33000
9800
17000
11000
10000
8100
16000
14000
17000
18000
10000
15000
11000
14000
22000
9900
8900
CrHI
470 J
590 J
730 J
530 J
690 J
540 J
370 J
410 J
630 J
630 J
490 J
440J
370 J
830 J
760 J
600 J
500 J
600 J
590 J
6SOJ
630 J
580 J
470 J
350 J
560 J
440 J
600 J
600 J
660 J
560 J
540 J
500 J
750 J
5301
730 J
CrLO
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
Co
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
Cu
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
Fe
14000
15000
19000
15000
18000
18000
15000
16000
17000
16000
18000
18000
17000
18000
18000
17000
17000
20000
19000
17000
19000
15000
15000
14000
17000
14000
16000
19000
15000
15000
18000
16000
17000
18000
17000
Pb
19 U
19U
26 J
39 J
43 J
19 U
39 J
19U
19U
21 J
41 J
27 J
43 J
60 J
29 J
33 J
19 U
63 J
67
67
160
43 J
47 J
19 U
38 J
43 J
59 J
56 J
19J
20 J
27 J
39 J
39 J
28 J
34 J
Mn
360 U
360 U
360 U
360 U
530 J
360 U
380 J
360 U
360 U
360 U
360 U
360 U
370 J
360 U
360 U
360 U
360 J
360 U
4IOJ
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
360 U
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 15 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE TIME
S06005ENQ1 6/5/2002 1725
S06005ENRI 6/5/2002 1729
S06005ENS1 6/5/2002 1733
S06005ESA1 6/5/2002 1737
S06005ESA1R 6/5/2002 1741
S06005ESB1 6/5/2002 1745
S06005ESC1 6/5/2002 1749
S06005ESD1 6/5/2002 1753
S06005ESE1 6/6/2002 810
S06005ESF1 6/6/2002 814
S06005ESG1 6/6/2002 817
S06005ESH1 6/6/2002 822
S06005ESM 6/6/2002 826
S06005ESJ1 6/6/2002 830
S06005ESK1 6/6/2002 834
S06005ESL1 6/6/2002 838
S06005ESM1 6/6/2002 842
S06005ESN1 6/6/2002 846
S06005ESO1 6/6/2002 850
S06005ESP1 6/6/2002 854
S06005ESP1D 6/6/2002 858
S06005ESQ1 6/6/2002 902
S06005ESRI 6/6/2002 907
S06005ESS1 6/6/2002 910
S06006ENA1 6/5/2002 1252
S06006ENB1 6/5/2002 1255
S06006ENC1 6/5/2002 1259
S06006END1 6/5/2002 1304
S06006ENE1 6/5/2002 1308
S06006ENF1 6/5/2002 1312
S06006ENF1D 6/5/2002 1316
S06006ENG1 6/5/2002 1320
S06006ENH1 6/5/2002 1328
S06006ENI1 6/5/2002 1332
S06006ENJ1 6/5/2002 1336
Sb
sou
sou
sou
sou
sou
sou
sou
sou
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
60 U
SOU
SOU
SOU
SOU
SOU
SOU
sou
sou
sou
sou
sou
As
34 J
32 J
23 U
26 J
39 J
23 U
28 J
49 J
36 U
36 U
36 U
36 U
47 J
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
23 J
29 J
23 U
36J
23 U
26 J
32 J
23 U
23 U
29 J
23 U
above the detection limit.
Ba
440
350
420
470
380
470
470
510
500
460
530
540
460
390 J
440 J
490
460
470
510
410 J
430 J
390 J
440
490
480
750
950
350
360
370
360
300
310
340
390
Cd Ca
I40U 20000
140U 7700
140 U 15000
140 U 10000
I40U 8900
140 U 14000
140 U 14000
140U 20000
180U 10000
180U 13000
180U 30000
180U 12000
I SOU 26000
180 U 15000
180 U 17000
180U 17000
180U 28000
180U 10000
180 U 14000
180U 14000
180U 16000
180U 13000
180 U 11000
180 U 16000
140U 12000
I40U 9900
140 U 15000
140U 17000
140 U 18000
140 U 15000
140 U 15000
140 U 22000
140 U 15000
140 U 11000
I40U 8200
CrHI
i^^^^^^^^^^^B
740 J
370 J
500 J
460 J
750 J
460 J
390 J
640]
720 U
720 U
720 U
720 U
720 U
810J
720 U
720U
720 U
720 U
720 U
720 U
720 U
720 U
720 U
750]
310U
730J
610J
580J
560 J
520J
720J
370J
420J
830J
740J
CrLO
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
840 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
Co
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
530 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
SOO U
Cu
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
100U
100U
100U
100U
100 U
100U
100U
100 U
100U
100U
100U
100U
IOOU
100 U
IOOU
100_U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89.U
89 U
89 U
Fe
17000
19000
16000
19000
19000
17000
18000
20000
14000
16000
20000
13000
19000
14000
16000
17000
20000
15000
18000
14000
15000
17000
15000
21000
17000
20000
21000
15000
15000
16000
16000
18000
15000
15000
16000
Pb
58]
110
19 U
49]
56]
38]
160
19U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
36 U
80]
54 J
69]
34]
21 J
19U
130
52]
65
64]
92
37 J
19 U
56]
The detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation
limit.
Mn
360 U
400]
360 U
390]
360 U
360 U
360 U
360 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
400 U
620]
360 U
360 U
360 U
360 U
440]
360 U
360 U
360 U
440]
610]
360 U
Page 16 of 19
-------
TABLE 1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S06006ENM1
S06006ENN1
S06006ENOI
S06006ESA1
S06006ESA1D
S06006ESB1
S06006ESCI
S06006ESD1
S06006ESE1
S06006ESFI
S06006ESG1
S06006ESHI
S06006ES11
S06006ESJ1
S06006ESKI
S06006ESL1
S06006ESMI
S06006ESN1
S06006ESO1
S06045EISI
S06045E1S2
S0604MNJS1
S0604MN1S2
S0604MNIS3
S06125E1S1
S06125EIS2
S06125E1S3
S06154E1S1
S06154E1S2
S06I54E1S3
S06174E1S1
S06174E1S2
S06I86E1S1
S06186E1S2
S06205E1S1
DATE
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/5/2002
6/10/2002
6/10/2002
6/10/2002
6/10/2002
6/10/2002
6/10/2002
6/10/2002
6/10/2002
6/9/2002
6/9/2002
6/9/2002
6/9/2002
6/9/2002
6/10/2002
6/10/2002
6/10/2002
TIME
1340
1344
1348
1141
1145
1149
1153
1158
1202
1207
1211
1215
1219
1223
1227
1231
1235
1243
1247
837
841
937
941
945
824
828
832
1349
1353
1358
1413
1417
845
849
816
Sb
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
sou
62 U
62 U
62 U
62 U
62 U
62 U
62 U
62 U
66 U
66 U
66 U
66 U
66 U
62 U
62 U
62 U
As
23 U
23 U
23 U
23 U
23 U
23 U
44 J
23 U
23 U
23 U
29 J
23 U
23 U
33 J
23 U
40 J
23 U
23 U
23 U
44J
43 U
43 U
43 U
43 U
43 U
43 U
50 J
51 U
51 U
51 U
5IU
51 U
43 U
52 J
43 U
^MBMMMH
Ba
^^^^^M^M
380
250
350
490
530
480
500
570
430
320
330
390
370
370
380
310
380
340
250
360
350
420
450
460
410
370
480
340
350
300
340
350
390
430
340
i^HMMVM^BM
Cd
140 U
140U
140 U
140 U
140 U
140U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140U
140 U
140 U
140 U
140 U
I50U
150 U
150 U
150 U
I50U
150 U
150 U
150 U
210U
210U
210 U
210U
210 U
150 U
150U
150 U
Ca
9400
14000
7700
9700
10000
8700
8500
8900
7900
14000
10000
7700
9400
8900
6300 J
10000
8500
8800
20000
14000
12000
7300 J
8400 J
9200 J
13000
9200 J
8300 J
13000
12000
34000
11000
8400
10000
8900 J
8700 J
CrHI
360 J
650 J
660 J
620 J
780 J
410J
440J
500 J
530 J
450 J
700 J
470 J
4101
470 J
640 J
630 J
560 J
730 J
750 J
650 J
570 J
4303
520 J
560 J
660 J
690 J
400 J
470 J
730 J
610J
490 J
800 J
560 J
680 J
790 J
CrLO
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
800 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
Co
500 U
500 U
500 U
500 U
500 U
500 U
SOOU
500 U
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
SOOU
330 U
330 U
330 U
330 U
330 U
330 U
330 U
330 U
540 U
540 U
540 U
540 U
540 U
330 U
380 J
330 U
Cu
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
89 U
SOU
SOU
SOU
SOU
SOU
SOU
SOU
SOU
41 U
41 U
41 U
41 13
41 U
SOU
SOU
SOU
Fe
16000
17000
17000
14000
14000
16000
15000
16000
15000
15000
15000
15000
16000
15000
15000
15000
16000
15000
18000
16000
18000
15000
15000
14000
18000
18000
19000
20000
18000
19000
19000
18000
17000
16000
17000
Pb
31J
41 J
36 J
24 J
19 U
19U
19U
19 U
19 U
82
26 J
43 J
20 J
19U
19 U
28 J
30 J
37 J
36 J
29 J
42 J
24 J
17 J
17 J
5U
20 J
130
44]
37 J
41 J
82 J
61 J
16. U
16U
16 U
Mn
380 J
360 U
360 U
560 J
360 U
no i
**JV J
360 U
460 J
360 U
360 U
360 U
920 i
570 J
630 J
360 U
360 U
360 U
360 U
360 U
5IOU
510U
510 U
510U
510U
510 U
510U
600 J
640U
640 U
640 U
640 U
640 U
670 J
510U
510 U
r- _-
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 17 of 19
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE
S06205E1S2 6/10/2002
S06274E1SI 6/9/2002
S06274E1S1D 6/9/2002
S06274E1S2 6/9/2002
S06285E1S1 6/10/2002
S06285E1S2 6/10/2002
S06315E1S1 6/9/2002
S06315E1S2 6/9/2002
S063I5E1S3 6/10/2002
S06394E1S1 6/9/2002
S06394E1S2 6/9/2002
S0800RVSA1 6/8/2002
S0800RVSB1 6/8/2002
S0800RVSC1 6/8/2002
S0800RVSD1 6/8/2002
S0800RVSE1 6/8/2002
S0800RVSF1 6/8/2002
S0800RVSG1 6/8/2002
S0800RVSG1R 6/8/2002
S0800WFBE1 6/8/2002
S0800WFBW1 6/8/2002
S0800WFNE1 6/8/2002
S0800WFNW1 6/8/2002
S0800WFSE1 6/8/2002
S0800WFSE1D 6/8/2002
S0800WFSW1 6/8/2002
S08014E1S1 6/9/2002
S08014E1S2 6/9/2002
S08014E1S3 6/9/2002
S09034E1S1 6/9/2002
S09034E1S2 6/9/2002
SOCTYSH1D1 6/12/2002
SOCTYSH1S1 6/10/2002
SOCTYSH1S2 6/10/2002
SOCTYSH1S3 6/10/2002
TIME
820
1423
1428
1431
808
812
1701
1704
804
1435
1439
1144
1148
1152
1156
1200
1204
1208
1216
1314
1318
1310
1305
1236
1240
1302
1443
1447
1455
1548
1552
913
1440
1449
1452
Sb
62 U
66 U
66 U
66 U
62 U
62 U
66 U
66 U
62 U
66 U
66 U
45 U
45 U
45 U
52 J
45 U
45 U
45 U
45 U
45 U
45 U
48 J
45 U
45 U
45 U
45 U
66 U '
66 U
66 U
66 U
66 U
62 U
77 J
130J
62 U
As
43 U
51 U
51 U
51 U
43 U
43 U
51 U
51 U
43 U
51U
5IU
51 U
5IU
SIU
5IU
51U
51 U
51 U
51 U
51 U
51U
51U
51 U
51U
SIU
51 U
51 U
51 U
51 U
SIU
SIU
34 U
SOU
67 U
43 U
Ba
310
330
340
340
310
300
350
360
310
360
390
460
380
310
410
510
430
450
430
540
520
480
550
420
390
450
380
' 380
350
310
360
390
490
430
650
Cd
150U
210U
210U
210U
I50U
150 U
210U
210U
150 U
210U
210U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
210U
210U
210 U
210U
210U
170 U
150 U
150 U
150 U
Ca
22000
13000
15000
15000
13000
14000
10000
9100
13000
13000
13000
12000
10000
17000
12000
9500 J
12000
21000
21000
18000
17000
5800 J
9800
7500 J
7300 J
. 7500 J
9600
21000
10000
15000
14000
9000
16000
13000
17000
~ซ^^^"^^ปซ
CrHI
590 J
650 J
460 J
610J
6IOJ
580 J
700 J
670 J
620 J
500 J
640 J
490 U
890 J
500 J
500 J
490 U
550 J
490 U
940 J
490 U
490 U
580 J
490 U
590 J
550J
490 U
490 J
600 J
460 U
690 J
1000 J
710J
610J
590 J
540 J
CrLO
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
500 U
610U
610U
610 U
6IOU
6IOU
610U
610U
610 U
610U
610U
610U
610 U
610U
610 U
6IOU
500 U
500 U
500 U
500 U
500 U
670 U
700 J
500 U
500 U
Co
330 U
540 U
540 U
540 U
330 U
330 U
540 U
540 U
330 U
540 U
540 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
540 U
540 U
540 U
540 U
540 U
510U
330 U
330 U
330 U
Cu
sou
41 U
41 U
41 U
SOU
SOU
41 U
41 U
SOU
41 U
41 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
41 U
41 U
41 U
41 U
41 U
120 U
SOU
SOU
55 J
Fe
17000
18000
20000
19000
21000
19000
17000
17000
17000
21000
21000
14000
15000
17000
15000
14000
16000
16000
16000
16000
16000
12000
13000
14000
14000
13000
18000
15000
17000
21000
23000
19000
19000
20000
28000
Pb
83
35 U
41 j
35 U
44J
26 J
40 J
35 U
340
35 U
35 U
21 U
21 U
21 U
22 J
21 U
21 U
21 U
21 U
41 J
21 U
21 U
21 U
21 U
21 U
21 U
35 U
35 U
35 U
35 U
35 U
23 U
500
670
250
Mn
510U
640 U
640U
930 J
510J
510U
650 J
640 U
510U
640 U
640 U
440 U
440 U
620 J
440U
1000 J
440 U
440 U
440 U
440U
440 U
440 U
830 J
440U
440 U
440U
640 U
640 U
640U
640 U
640 U
330 U
570 J
510U
2100
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 18 of 19
B5S3FI
-------
TABLE1A
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID DATE TIME
SOCTYSH1S4 6/12/2002
SOCTYSHIS5 6/12/2002
SOVFWNW1 6/7/2002
S1RSOSCCS1 6/8/2002
S1RSOSNESI 6/8/2002
S1RSOSNWS1 6/8/2002
S1RSOSSES1 6/8/2002
SlRSOSSSSl 6/8/2002
S1RSOSSWS1 6/8/2002
S2RSOSCCS1 6/9/2002
S2RSOSNES1 6/9/2002
S2RSOSNWS1 6/9/2002
S2RSOSSES1 6/9/2002
S2RSOSSWS1 6/9/2002
S2RSOSSWS IB 6/9/2002
S700FGANE1 6/8/2002
S700FGANW1 6/8/2002
S700FGASE1 6/8/2002
S700FGASWI 6/8/2002
S700FGCSW1 6/8/2002
S700FGCSWX 6/1 2/2002
S700FGCWCI 6/8/2002
S700FGCWC 1 D 6/8/2002
S700FGECC1 6/8/2002
S700PGGCC1 6/8/2002
S700FGGCC1R 6/8/2002
S700FGGNE1 6/8/2002
S700FGGNW1 6/8/2002
S700FGGSE1 6/8/2002
S700FGGSWI 6/8/2002
922
917
1431
1714
1722
1710
1719
1727
1707
1105
1053
1058
1102
1110
1114
1358
1402
1411
1407
1424
934
1429
1433
1420
1446
1450
1441
1453
1437
1458
Sb
62 U
62 U
51 U
45 U
45 U
45 U
45 U
45 U
45 U
66 U
66 U
66 U
66 U
66 U
66 U
45 U
45 U
45 U
45 U
1100
720
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
45 U
As
34 U
34 U
. 38 U
51 U
51 U
58 J
51 U
51 U
51U
51 U
95 J
51U
51 U
51 U
51 U
51 U
51 U
51 U
51 U
1500
790
51 U
51 U
5IU
51 U
51 U
51 U
51 U
51 U
51 U
Ba
440
390
480
390
350
370
380
340
370
470
360'
470
400
400
65 U
450
500
470
460
1801
350
450
440
420
360
380
330
470
320
250 J
Cd
170 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
210 U
2IOU
210 U
210 U
210 U
210 U
130 U
130 U
130 U
130 U
130 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
Ca
23000
12000
7500
46000
27000
39000
32000
26000
40000
32000
46000
28000
21000
29000
1500 U
6700 J
5900 J
6900 J
6400 J
4800 J
20000
21000
20000
11000
24000
20000
13000
11000
HOOO
46000
CrHI
520 J
440 U
450 J
790 J
570 J
880 J
690 J
6801
490 U
460 U
890 J
460 J
480 J
670 J
460 U
490 U
490 U
490 U
640 J
620 J
860 J
490 U
580 J
490 U
610J
490 U
710J
490 U
500]
730 J
CrLO
670 U
670 U
460 U
610U
610U
610 U
610U
610 U
610U
500 U
500 U
500 U
500 U
500 U
500 U
610 U
6101)
610 U
610U
610 U
670 U
610 U
610U
610 U
610U
610U
610 U
610 U
610 U
610 U
Co
510U
510U
320 U
630 U
630 U
630 U
630 U
630 U
630 U
540 U
540 U
540 U
540 U
540 U
540 U
630 U
630 U
630 U
630 U
630 U
510U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
630 U
Cu
120 U
120 U
100U
76 U
76 U
76 U
76 U
76 U
76 U
41 U
41 U
41 U
41 U
41 U
41 U
76U
76 U
76 U
76 U
76 U
120U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
76 U
Fe
16000
16000
16000
18000
23000
17000
20000
17000
18000
21000
19000
19000
20000
20000
2200 U
14000
14000
14000
13000
52000
38000
20000
21000
19000
19000
19000
24000
16000
22000
22000
Pb
110
84
130
160
490
120
47 J
27 J
74
150
200
82 J
82 J
35 U
35 U
22 J
21 U
36 J
21 J
7700
4000
23 J
31 J
31 J
41 J
35 J
96
34 J
110
24.J
Mn
330 U
330 U
400 U
440U
500J
440 U
440U
440U
440 U
640 U
640 U
640 U
640U
640 U
640U
440U
440 U
440 U
440 U
3900
3200
470 J
440U
440 U
440 U
440U
700 J
440U
600 J
440 U
U - The analyte was not detected above the detection limit. The detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 19 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0023MW1S1
S0033MW1S1
S0033MW1S2
S0043MWIDI
S0043MW1S1
S0043MW1S2
S0043MW1S3
SOOFCCM1S1
S01001SWA1
S01001SWB1
SOI001SWC1
SOI001SWD1
SOI001SWEI
S01001SWF1
S01001SWFID
SOI004END1
S01004END1B
S01007SWA1
S01007SWB1
S01007SWC1
SOI007SWD1
S0100CEEA1
S0100CEEB1
S0100CEEC1
S0100CEED1
S0100CEEE1
S0100CEEF1
S0100CEEG1
S0100CEEG1R
S0100CEWA1
S0100CEWB1
S0100CEWCI
S0100CEWD1
SOIOOCEWE1
S0100CEWE1D
Hg
54 U
54 U
54 U
75 U
54 U
54 U
54 U
54 U
19U
20 J
22 J
19 U
19 U
19U
I9U
19 U
19U
19U
32 J
19 U
19U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
Mo
5.5 U
5.5 U
5.5 U
6.7 U
5.5 U
5.5 U
5.5 U
5.5 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7:9 u
7.9 U
7.9 U
Ni
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
160U
160 U
160 U
160 U
160 U
160U
160 U
160 U
160 U
160 U
160U
160 U
160 U
160U
K
24000
21000
30000
25000
26000
29000
33000
25000
26000
28000
28000
22000
24000
25000
23000
29000
4200 U
22000
29000
25000
26000
28000
24000
30000
25000
25000
23000
22000
23000
26000
24000
22000
20000
25000
21000
Rb
81 J
88 J
110
77
83 J
100
100
92 J
96
120
110
99
110
98
91
110
15 U
93
100
89
88
89
86
97
97
94
91
83 J
85 J
110
110
87
68 J
98
100
Se
20 U
20 U
20 U
18U
20 U
20 U
20 U
20 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
Ag
86 U
110J
86 U
120 U
95 J
86 U
86 U
86 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130U
Sr
190
200
180
280
240
220
ISO
160
140
110
130
210
210
ISO
140
120
32 U
210
210
250
210
140
180
120
180
210
190
170
180
170
130
210
220
180
150
Th
8.5 U
8.5 U
11 J
I4J
9.4 J
8.5 U
8.5 U
8.5 U
14 U
14U
14 U
I4U
14U
14 U
14U
14 U
14U
14 U
14 U
14 U
14U
8.8 U
8-8 U
8.8 U
8.8 U
9J
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
I3J
8.8 U
8.8 U
8.8 U
Sn
160 U
160 U
160 U
59 U
160 U
160 U
160 U
160 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
Ti
2400
2200 J
2900
2200 J
1800 J
2200 J
2500
1700J
2300 J
2200 J
1600J
1900J
2000 J
1700 J
2400 J
1700J
1000 U
1700J
1800 J
1700 J
1700J
1900J
1300J
2300 J
2400 J
1700J
2300 J
1900J
1400 J
1600 J
1400 J
2000 J
1400 J
2200 J
2100 J
U
16J
10 U
10 U
15J
10U
10 U
10 U
12;
9.9 U
11 J
17J
9.9 U
9.9 U
9.9 U
10J
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
19U
19U
19U
19 U
19U
19U
I9U
19U
19U
19 U
19U
19U
I9U
19U
Zn
110J
150 J
130J
94 U
480
560
75 J
88 J
110J
53 J
59 J
54 J
68 J
500
470
160
41 U
47 J
92 J
79 J
41 U
66 J
200
99 J
190 J
230
210
140 J
120 J
100 J
99 J
79 J
130 J
240
260
Zr
260
260
250
210
260
240
280
230
250
230
230
270
300
250
240
290
17J
240
260
190
210
250
230
220
260
230
210
210
230
250
230
230
230
220
210
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Pagel of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0100CEWF1
S0100CEWG1
S0102RNIS1
S01063W1D1
SOI063W1S1
S01063W1S2
S01063W1S3
S0106CE1S1
SOI06CEIS2
S0106CEIS3
S0106ME1S1
S01071S1S1
S01071S1S2
S0146MWIS1
S0146MW1S2
S0146MWIS3
S0169DIIS1
S0169DIIS2
S02003ENA1
S02003ENB1
S02003ENC1
S02003END1
S02003ENEI
S02003ENF1
S02003ENG1
S02003ESAI
S02003ESBI
S02003ESCI
S02003ESDI
S02003ESE1
S02003ESF1
S02003ESG1
S02003ESG1R
S02004SEA1
S02004SEB1
Hg
58 U
58 U
78 U
75 U
54 U
54 U
54 U
44U
44U
44U
54 U
19 U
19U
54 U
54 U
54 U
54 U
54 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
78 U
78 U
Mo
7.9 U
7.9 U
7.1 U
6.7 U
5.5 U
5.5 U
5.5 U
5.3 U
5.3 U
5.3 U
5.5 U
5.4 U
5.4 U
5.5 U
5.5 U
5.5 U
5.5 U
5.5 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.1 U
7.1 U
Ni
^^^^^^VM
160U
160 U
59 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
87 U
87 U
170 U
170 U
170 U
170 U
170 U
130 U
130 U
130 U
130U
130 U
130 U
130 U
160U
160U
160U
160U
I60U
160U
160 U
160U
59 U
59 U
K
"^ ซ^ซ
20000
27000
27000
25000
22000
21000
25000
22000
22000
29000
32000
26000
28000
26000
23000
20000
22000
26000
29000
25000
25000
27000
23000
25000
23000
24000
20000
25000
26000
23000
24000
24000
21000
32000
27000
Rh
M\JJ
74 J
100
94
90
89 J
80 J
92 J
85
87
100
120
91
96
100
93 J
85 J
93 J
88 J
110
92 J
98
100
100
84J
97
99
82 J
100
95
110
110
93
84]
94
99
Go
OK
27 U
27 U
24 U
I8U
20 U
20 U
20 U
23 U
23 U
23 U
20 U
24 U
24 U
20 U
20 U
20 U
20 U
20 U
22 U
22 U
22 U
22 U
22 U
22U
22 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
24U
24 U
A n
Ag
130 U
130 U
130 U
120 U
86 U
86 U
96 J
110U
IIOU
110U
100J
150 U
150 U
86 U
86 U
86 U
86 U
91 J
77 J
73 U
78 J
73 U
73 U
73 U
73 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
'130U
O__
or
15Q
150
180
230
190
180
150
250
240
110
75 J
250
260
120
150
170
240
240
150
140
150
240
190
210
200
180
260
200
230
130
120
230
240
180
220
Th
^^^^M^^^H
8.8 U
8.8 U
11U
12U
8.5 U
8.5 U
8.5 U
11U
I2J
16J
12J
15J
14 U
9.5 J
8.5 U
9.1 J
10J
8.5 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
.8.8U
8.8 U
9.2 J
8.8 U
8.8 U
8.8 U
I2J
13 J
IIU
I1J
Sn
88 U
88 U
75 U
59 U
160 U
160 U
160 U
63 U
63 U
63 U
160U
140 U
140 U
160 U
160 U
160 U
160 U
160 U
110U
110U
110U
110U
110U
IIOU
110U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
75 U
75 U
Ti
2100J
2400 J
2100J
2200 J
2100 J
2200 J
2200 J
2200 J
2IOOJ
2000 J
2000 J
2400 J
2300 J
2400
2700
2800
2000 J
2400
2300 J
2300 J
1700 J
1900 J
1800J
1700 J
1500J
2400 J
1900 J
2100 J
2000 J
1900 J
1900J
1300 J
1600 J
2200 J
2600 J
U
19 U
19U
12U
11J
16J
10U
10U
8.8 U
9.6 J
8.8 U
10 U
9.9 U
9.9 U
14J
10U
12J
10U
10U
19J
15U
15U
15U
15U
15U
15U
19U
19 U
19U
19U
19 U
I9J
19U
19 U
12U
16J
Zn
240
190 J
100 J
130J
130 J
77 J
3100
ISO
210
72 J
160 J
150
110J
99 J
120 J
88 J
68 U
1IOJ
71 J
110
120
55 J
74 J
94
83 J
240
190 J
150 J
100 J
85 /
100J
110J
110J
80 J
100J
Zr
220
230
250
450
290
270
270
290
240
210
290
200
250
220
260
230
240
280
220
240
260
210
210
200
200
220
200
190
220
260
260
210
210
240
360
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 2 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S02004SEC1
S02004SED1
S02004SWB1
S02004SWC1
S02004SWD1
S0200CEEA1
S0200CEEAIB
S0200CEEB1
S0200CEECI
S0200CEED1
S0200CEEEI
S0200CEEFI
S0200CEEO1
S0200CEWA1
S0200CEWBI
S0200CEWB1D
S0200CEWCI
S0200CEWD1
S0200CEWE1
S0200CEWF1
S0200CEWG1
S0200CEWG1R
S0200MNNAI
S0200MNNBI
S0200MNNC1
S0200MNND1
S0200MNNEI
S0200MNNF1
S0200MNNG1
S0200MNNGIR
S0200MNSA1
S0200MNSB1
S0200MNSC1
S0200MNSDI
S0200MNSDX
Hg
78 U
78 U
78 U
78 U
78 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U .
' 58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
75 U
Mo
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
6.7 U
Ni
59 U
59 U
59 U
59 U
59 U
160 U
I60U
I60U
160 U
160U
160U
160U
160 U
160 U
160 U
160 U
160 U
160U
160 U
160 U
160 U
160 U
160 U
160 U
160 U
160U
160U
160 U
160 U
160 U
160U
160 U
160 U
160 U
170 U
K
27000
31000
26000
29000
34000
22000
3500 U
26000
22000
24000
23000
21000
20000
29000
22000
26000
26000
28000
27000
23000
30000
30000
28000
23000
24000
21000
31000
22000
23000
26000
25000
24000
23000
27000
26000
Rb
100
120
100
95
98
91
26 U
97
100
96
91
83 J
88
92
85 J
96
93
110
93
87
110
80 J
110
87
88
90
150
100
95
95
92
86
93
100
87
Se
24 U
24 U
24 U
24 U
24 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
. 27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
18 U
Ag
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
120U
Sr
130
190
210
190
170
170
22 U
230
170
210
200
ISO
140
210
110
130
130
160
190
230
180
190
100
180
210
220
110
200
210
210
160
190
130
130
250
Th
11U
11U
11U
11U
11U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
IN
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
12J
11 J
12J
11 J
12J
8.8 U
11 J
8.8 U
1IJ
8.8 U
11 J
8.8 U
8.8 U
8.8 U
I2U
Sn
75 U
75 U
75 U
75 U
83 J
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88U
59 U
Ti
2400 J
2000 J
1900 J
2000 J
2300 J
1500J
780 U
2200 J
1400J
1900J
1500J
1800J
I400J
2100 J
1200J
I800J
1700 J
1700J
2200 J
1700 J
2400 J
2100 J
1800J
1900J
1600J
2100J
2000 J
1700 J
2000 J
1500 J
2300 J
2000 J
1900J
1500J
2000 J
U
I2U
13J
12U
12U
12U
19 U
19U
19 U
19U
I9U
19U
I9U
19U
20 J
19U
19U
19U
19U
19U
19 U
19U
19U
21 J
19U
19U
19 U
19U
19U
19U
19U
19U
19U
I9U
19 U
21 J
Zn
250
130 J
110J
140 J
72 U
100 J
59 U
67 J
110J
110J
95 J
69 J
170 J
67 J
81 J
97 J
76 J
64 J
62 J
623
59 U
89 J
190 J
210
.130J
76 J
130 J
400
180 J
230
1IOJ
170 J
130 J
180 J
980
Zr
*~^^mm
230
240
250
250
240
190
21 U
190
220
210
230
260
190
250
220
240
210
240
190
220
270
280
220
240
230
230
270
250
280
240
270
250
230
240
330
J -.The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 3 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRA CE 9000 XRF DATA (PPM)
ID
S0200MNSEI
S0200MNSF1
S0200MNSGI
S0200RAMA1
S0200RAMB1
S0200RAMC1
S0200RAMD1
S0200RAME1
S0200RAMF1
S0200RAMGI
S0200RAMG1R
S0200RAMH1
S0200RAMI1
S0200RAMJ1
S0200RAMK1
S0200RAML1
S0201SP1D1
S0201SP1S1
S0201SP1S2
S0201SPIS2D
S0201SP1S3
S02021S1SI
S02021S1S2
S0202CE1S1
S0202CE1S2
S0202LPNE1
S0202LPNW1
S0202LPSE1
S0202LPSEID
S0202LPSW1
S0202LPTC1
S02035L1S1
S02035L1S2
S0205ALISI
S0205AL1S2
U - The analvte w
Hg
58 U
58 U
58 U
22 J
19 U
19 U
19 U
19U
19U
19 U
19 U
19 U
19 U
19U
19 U
19U
75 U
19U
19 U
19 U
19U
19U
19U
44U
44U
19U
19U
19U
19 U
19U
19U
54 U
54 U
44U
44U
as not deter
Mo
7.9 U
7.9 U
7.9 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
6.7 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.3 U
5.3 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.5 U
5.51)
5.3 U
5.3 U
:ted ahnvp th
Ni
160 U
160 U
160 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
170 U
170 U
170 U
P rfptprtirm t
K
28000
26000
22000
25000
24000
27000
26000
27000
25000
26000
25000
27000
28000
22000
24000
28000
25000
22000
24000
1 22000
20000
23000
26000
25000
19000
21000
21000
24000
21000
23000
27000
23000
24000
21000
27000
imit thp dptp
Hh
110
96
82 J
100
100
98
82
97
100
110
120
110
100
100
86
120
83
90
97
100
68
94
87
86
94
77
85
92
98
98
97
100
78 J
95
no
CA
ae
^^^Mi^
27 U
27 U
27 U
24 U
24 U
24 U
24U
24 U
24 U
24U
24U
24 U
24 U
24U
24 U
24 U
18U
24 U
24 U
24 U
24 U
24 U
24 U
23 U
23 U
24 U
24 U
24 U
24 U
24 U
24 U
20 U
20 U
23 U
23 U
Ag
130 U
130 U
130 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
120 U
150 U
150 U
150 U
150 U
150 U
150 U
110U
110U
150 U
150 U
150 U
150 U
150 U
150 U
86 U
86 U
I10U
HOU
Sr
130
150
190
130
240
140
260
140
130
130
120
84 J
150
170
93 J
110
230 .
250
240
240
200
210
240
210
250
210
200
210
210
200
110
150
180
200
210
Th
8.8 U
8.8 U
8.8 U
14 U
15J
14 U
14U
14J
14 U
14 U
14U
14 U
14 U
14 U
14U
14U
19 J
14 U
14U
14 U
14 U
14 U
14U
11U
nu
14 U
HU
14U
14U
14 U
14U
8.5 U
8.5 U
11U
UU
Sn
88 U
88 U
88 U
140 U
140 U
140U
HOU
HOU
HOU
140 U
HOU
HOU
140U
140 U
HOU
HOU
59 U
HOU
HOU
140 U
HOU
140 U
140U
63 U
63 U
HOU
HOU
HOU
140 U
HOU
140 U
160 U
160U
63 U
63 U
Ti
2100 J
2200 J
1400 J
1900 J
2100J
1700J
1500J
2500 J
2000 J
2400 J
1900 J
2300 J
1600J
2100J
1600J
2000 J
2300 J
2900 J
1800J
2300 J
2600 J
2300 J
1700 J
2900 J
2700 J
2100 J
18001
1500J
1800J
2300 J
2100 J
2200 J
2600
1700J
1600 J
U
19 U
19 U
19U
9.9 U
9.9 U
21 J
9.9 U
9.9 U
9.9 U
12J
9.9 U
17 J
9.9 U
9.9 U
HJ
I5J
12J
9.9 U
11 J
9.9 U
15J
18J
15 J
12J
8.8 U
13J
9.9 U
9.9 U
9.9 U
9.9 U
9.9 U
10U
10 U
8.8 U
8.8 U
Zn
69 J
140 J
720
64J
120 J
57 J
56 J
41 U
79 J
150
140
77 J
170
250
280
160
1300
320
85 J
140
950
150
1303
200
UOJ
97 J
UOJ
94 J
120 J
120 J
64J
68 U
68 U
160 ,
59 J
Zr
240
270
210
270
270
220
180
210
200
220
220
240
210
250
240
250
420
260
220
250
290
280
330
270
250
240
230
240
270
240
210
340
300
310
260
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 4 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0205AL1S3
S020SMN1S1
S0205MN1S2
S020SRN1S1
S02061SID1
S02061S1SI
S0206ISIS2
S0206IS1S3
S02063WIS1
S02063W1S2
S0208CE1S1
S0208CE1S2
S0208CE1S3
S0208MNIS1
S0208MNIS2
S0208MNIS3
S0209RW1SI
S0210SP1SI
S0210SP1S2
S021I1S1S1
S02111S1S2
S0211SPIS1
S0211SP1S2
S02I3SP1S1
S0213SP1S2
S0225FC1S1
S0225FC1S1D
S0225FC1S2
S03002WNF1
S03002WNG1
S03002WSFI
S03002WSG1
S03003ENA1
S03003ENBI
S03003ENCI
Hg
44U
54 U
54 U
78 U
75 U
19 U
19U
19 U
54 U
54 U
44U
44U
44U
78 U
78 U
78 U
78 U
75 U
75 U
19 U
19U
19 U
19 U
19U
19U
75 U
75 U
75 U
78 U
78 U
78 U
78 U
- 37 U
37 U
37 U
Mo
5.3 U
5.5 U
5.5 U
7.1 U
6.7 U
5.4 U
5.4 U
5.4 U
5.5 U
5.5 U
5.3 U
5.3 U
5.3 U
7.1 U
7.1 U
7.1 U
8J
6.7 U
6.7 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
6.7 U
6.7 U
6.7 U
7.1U
7.1U
7.1 U
7.1 U
9.4 U
9.4 U
9.4 U
Ni
170 U
170 U
170 U
59 U
170 U
87 U
87 U
87 U
170 U
170 U
170 U
170 U
170 U
59 U
59 U
59 U
59 U
170 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
170 U
170 U
59 U
59 U
59 U
59 U
130 U
130 U
130 U
K
25000
25000
23000
28000
22000
28000
25000
23000
21000
24000
21000
20000
23000
25000
26000
26000
27000
23000
22000
21000
24000
24000
29000
25000
25000
27000
27000
22000
29000
27000
28000
27000
28000
26000
26000
Rb
86
95 J
90 J
100
92
100
90
89
93 J
86 J
82
93
91
97
95
88
96
89
77
71
110
100
100
88
86
100
110
78
94
100
95
98
100
110
99
Se
23 U
20 U
20 U
24 U
18U
24 U
24 U
24 U
20 U
20 U
23 U
23 U
23 U
24 U
24 U
24 U
24 U
18U
18U
24 U
24 U
24 U
24 U
24 U
24 U
18U
18 U
18U
24 U
24 U
24 U
24 U
22 U
22 U
22 U
Ag
110U
86 U
86 U
130 U
120 U
150 U
I50U
150 U
86 U
100 J
110U
110U
110U
130 U
130 U
130 U
130 U
120 U
120 U
150 U
150 U
150 U
150 U
150 U
150 U
120 U
120 J
120 U
130 U
130 U
130 U
130 U
73 U
73 U
73 U
Sr
200
170
210
100J
260
100J
230
210
270
180
230
240
250
250
220
140
230
240
230
400
210
180
120
140
220
130
130
170
220
170
150
190
120
190
210
Th
11U
8.5 U
8.5 U
I1U
12U
14U
14U
14U
9.IJ
8.5 U
1IU
11U
15J
111!
I3J
11 U
111!
12U
12J
14U
14 U
14 U
14 U
14U
14 U
12U
12U
12U
11U
11U
11 U
11 U
9.8 U
9.8 U
9.8 U
Sn
63 U
160 U
160 U
75 U
59 U
140 U
140 U
140 U
160 U
160 U
63 U
63 U
63 U
75 U
75 U
75 U
. 75 U
59 U
59 U
140 U
140 U
140 U
140 U
1401)
140 U
59 U
59 U
59 U
75 U
75 U
75 U
75 U
110 U
I10U
110U
Ti
2500 J
2500
2500
2600 J
I900J
1800 J
2300 J
2600 J
1500 J
1700J
2500 J
1700 J
2100]
1900 J
2400 J
1800J
2800 J
2200 J
2000 J
3500
2200 J
2700 J
2800 J
2500 J
2200 J
2000 J
2400 J
2100 J
1900 J
1600J
2100 J
2500 J
1600 J
1900J
1800J
U
13J
10 U
14J
16J
8.2 J
13J
9.9 U
17J
10U
10 U
8.8 U
9.2 J
9.9 J
12U
12U
12U
12U
7.3 U
15J
I6J
9.9 U
9.9 U
9.9 U
14]
9.9 U
7.8 J
10J
15J
12 U
12U
12U
12U
18J
15U
15U
Zn
110J
73 J
140 J
310
150 J
130 J
1200
360
68 U
180 J
230
150
200
140 J
420
3700
330
1IOJ
150 J
270
120 J
140J
250
59]
200
110]
190 J
950
110J
140 J
72 J
90 J
88 J
160
160
Zr
280
280
270
250
290
280
330
310
250
220
270
250
220
270
260
220
370
210
220
370
270
250
210
290
250
250
260
260
290
190
310
250
200
210
220
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 5 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S03003END1
S03003ENE1
S03003ENFI
S03003ENG1
S03003ESA1
S03003ESA1D
S03003ESB1
S03003ESC1
S03003ESD1
S03003ESE1
S03003ESFI
S03003ESG1
S03003SEA1
S03003SEB1
S03003SECI
S03003SECIR
S03003SEDI
S03003SWAI
S03003SWBI
S03003SWC1
S03003SWD1
S03004SEA1
S03004SEB1
S03004SEC1
S03004SEC1R
S03004SED1
S03004SWA1
S03004SWBI
S03004SWC1
S03004SWD1
S0300AL1S1
S0300ALIS2
S03QOAL1S3
S0300AL2S1
S0300CEEEI
^^^n
IT. Thp analvto u
Hg
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
42 J
58 U
58 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
75 U
78 U
78 U
75 U
75 U
75 U
44 U
44U
44U
44U
58 U
Mo
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
7.9 U
7.9 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
6.7 U
7.1 U
7.1 U
6.7 U
6.7 U
6.7 U
5.3 U
5.3 U
5.3 U
5.3 U
7.9 U
Ni
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
160U
160U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
170 U
59 U
59 U
170 U
170 U
170 U
170U
170 U
170 U
170 U
160U
K
22000
22000
22000
25000
23000
26000
20000
26000
25000
26000
31000
25000
28000
26000
24000
26000
26000
26000
30000
24000
27000
27000
30000
30000
26000
24000
27000
27000
26000
24000
22000
22000
23000
23000
23000
Rb
91 J
85 J
98
95 J
80 J
110
86 J
100
95 J
98
100
91
78
100
76
99
78
100
100
81
110
110
120
98
94
95
94
98
93
89
90
85
90
94
95
SP
22 U
22 U
22 U
22 U
. 22 U
22 U
22 U
22 U
22 U
22 U
27 U
27 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
18U
24 U
24 U
18U
18 U
18U
23 U
23 U
23 U
23 U
27 U
M^^^H^H^^H
An
Ag
73 U
87 J
73 U
73 U
73 U
73 U
73 U
73 U
110)
73 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
120 U
130 U
130 U
120 U
120 U
120 U
nou
110U
nou
nou
130 U
0_
ar
200
240
210
200
140
160
180
170
250
150
160
230
170
140
230
220
210
190
200
240
130
180
200
150
140
130
170
210
220
ISO
250
220
230
200
150
In
9.8 U
9.8 U
9.8 U
9.8 U
12J
9.8 U
9.8 U
9.8 U
9.8 U
10J
14J
8.8 U
12J
11U
11U
11U
11U
11 U
11 U
11 U
11U
11 U
I4J
11U
12U
11U
111)
12U
12U
12U
11 J
UU
12J
111)
8.8 U
Sn
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
88 U
88 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
86 J
59 U
75 U
75 U
59 U
59 U
59 U
63 U
63 U
63 U
63 U
88 U
Ti
1700J
1300J
1600J
2200 J
1800J
2000 J
1900 J
2200 J
\900J
1900 J
2500 J
2000 J
2000 J
1700 J
2000 J
2300 J
2400 J
2100J
2400 J
2500 J
2300 J
2300 J
2000 J
2100 J
1800 J
2500 J
2600 J
1600 J
1600 J
2500 J
2400 J
2600 J
2500 J
3000 J
1600J
U
15 U
15U
15U
15U
15 U
15U
15 U
15 U
18J
15 U
19 U
19U
12U
20 J
12U
12U
I4J
12U
15J
12U
12U
12U
20 J
12U
7.3 U
12U
12U
7.3 U
11 J
15J
8.8 U
19J
15J
IIJ
19U
Zn
130x
76 J
no
77 J
240
250
300
280
83 J
130
87 J
110J
110J
87 J
120 J
83 J
120 J
88 J
140 J
72 U
92 J
110J
99 J
160 J
150 J
110J
180J
130 J
94 U
140J
93 J
90 J
120 J
150
110J
Zr
210
220
220
240
200
230
220
200
210
240
290
240
270
220
280
240
270
260
280
280
250
260
230
230
200
200
230
260
250
230
240
250
260
260
240
J - The associated numerical.value is an estimated quantity between the detection limit and the quantitation limit.
Page 6 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0300CEEG1
S0300CEWG1
S0300FCEA1
S0300FCEB1
S0300FCECI
S0300FCED1
S0300FCWAI
S0300PCWBI
S0300FCWCI
S0300MNNA1
S0300MNNB1
S0300MNNC1
S0300MNNE1
S0300MNNFI
S0300MNNFID
S0300MNNGI
S0300MNSA1
S0300MNSBI
S0300MNSC1
S0300MNSD1
S0300MNSF1
S0300MNSG1
S0300MNSG1R
S0300RWSA1
S0300RWSB1
S0300RWSC1
S0300RWSD1
S0300RWSF1
S0300SPEAI
S0300SPEB1
S0300SPEC1
S0300SPED1
S0300SPEEI
S0300SPEFI
S0300SPEG1
Hg
58 U
58 U
I9U
19U
19 U
19U
24 J
19U
19 U
58 U
58 U
58 U
58 U
58 U
19U
19 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
19 U
19U
19U
19U
19U
19 U
19J
19U
19U
19U
19U
I9U
Mo
7.9 U
7.9 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
5.4 U
5.4 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4U
5.4 U
5.4 U
5.4 U
5.4 U
Ni
160 U
160 U
87 U
87 U
88 J
87 U
87 U
87 U
87 U
160 U
I60U
160 U
160U
160 U
87 U
87 U
160U
160 U
160U
160U
160 U
160 U
160 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
K
24000
21000
25000
32000
26000
32000
25000
24000
25000
22000
24000
23000
23000
23000
24000
26000
26000
27000
22000
32000
23000
24000
23000
24000
26000
30000
26000
24000
26000
29000
26000
25000
22000
23000
26000
Rb
no
96
110
120
15 U
no
100
92
96
93
100
110
100
95
92
92
96
99
95
130
89
88
74 J
88
no
140
85
110
93
100
89
100
97
94
91
Se
27 U
27 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
27 U
27 U
27 U
27 U
27 U
24 U
24 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
Ag
130 U
130 U
150 U
150 U
150 U
150 U
160 J
150 U
150 U
130 U
130 U
130 U
130 U
130 U
150 U
150 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
150 U
150 U
150 U
150 U
150 U
150U
150 U
150 U
150 U
150 U
150 U
I50U
Sr
200
210
85 J
33 J
130
150
120
120
130
170
230
220
180
220
210
200
220
210
180
86
130
210
210
no
180
120
190
230
130
1101
130
ISO
190
180
190
Th
8.8 U
8.8 U
14U
14U
14U
14 U
I4U
14U
14U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
14 U
14 U
8.8 U
9.9 J
8.8 U
16 J
8.8 U .
8.8 U
11 J
14 U
14U
14U
14 U
14 U
14 U
UU
14 U
14 U
14U
14 U
14U
Sn
88 U
88 U
140 U
140 U
140 U
I40U
140 U
140 U
140 U
88 U
88 U
88 U
88 U
88 U
140 U
140 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
140 U
140 U
140 U
140 U
140 U
140 U
140U
140 U
140 U
140 U
140 U
140 U
Ti
2000 J
2000 J
3300 J
1800J
1900J
2100 J
2000 J
2200 J
2200 J
2100 J
2300 J
I900J
1700J
2000 J
2200 J
1900 J
2900
2200 J
2000 J
2100 J
1600J
1700J
1800 J
1800J
1600 J
2700 J
2000 J
1900J
1300J
1400 J
1900 J
1400J
1200J
1700J
2100J
U
19U
19 U
11 J
21 J
15J
13J
10J
13J
9.9 U
19 U
I9U
22 J
19U
19U
9.9 U
12 J
19U
19U
19 U
23 J
19U
I9U
19 U
15J
9.9 U
13J
11 J
9.9 U
9.9 U
9.9 U
12J
12J
9.9 U
12J
12J
Zn
73 J
130]
49 J
41 U
73 J
120 J
66 J
130 J
140
220
150 J
150 J
270
210
180
320
130 J
62 J
130 J
100 J
no;
160 J
140 J
120 J
78 J
89 J
130 J
69 J
I10J
87 J
100 J
55 J
70 J
120 J
130 J
Zr
220
310
250
320
250
230
240
240
230
220
270
230
250
210
250
210
350
200
230
240
220
240
220
240
290
260
310
200
240
240
240
240
210
220
210
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 7 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0300SPEG1R
S0304MA1S1
S0304MA1S2
S0304MA1S3
S0304MA1S4
S0304MA1S5
S0304MA1S5R
S03053W1S1
S03053W1S2
S0306ARIS1
S0306AR1S2
S0306ARIS3
S0306AR1S3R
S0306AR2SI
S0306MA1S1
S0306MAIS2
S0306MA1S2D
S03071M1S1
S0307MA1S1
S0307MA1S2
S0307MA1S3
S0309MT1SI
S0309MT1S2
S0309MT1S3
S03102E1SI
S03IIMAISI
S03I1MA1S2
S031IMA1S3
S0311MN1SI
S03IIMN1S2
S0319OM1S1
S0319OM1S2
S0319OM1S3
S04002WNA1
S04002WNB1
Hg
19 VJ
44U
44 U
44U
44U
44U
44U
54 U
54 U
44U
44U
44U
44U
44U
44U
44U
44U
54 U
44U
44U
44U
44 U
44U
44U
19 U
44U
44U
44U
54 U
54 U
54 U
54 U
54 U
78 U
78 U
Mo
5.4 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.5 U
5.5 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.5 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.4 U
5.3 U
5.3 U
5.3 U
5.5 U
5.5 U
5.5 U
5.5 U
5.5 U
7.1 U
7.1 U
Ni
^ป~"^ป
87 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
87 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
59 U
59 U
^^^^^^IM
K
^^^^MMMM^n
27000
17000
22000
21000
27000
26000
26000
26000
33000
22000
25000
28000
30000
22000
21000
21000
23000
20000
17000
18000
23000
22000
23000
27000
28000
31000
20000
19000
23000
24000
27000
29000
25000
28000
24000
Rb
98
72
84
110
no
100
98
100
110
95
84
100
110
87
92
86
100
86 J
74
79
80
86
100
88
97 .
150
82
86
96 J
82J
100
110
95 J
82
80
Se
kjc
24 U
23 U
23 U
23 U
23 U
23 U
23 U
20 U
20 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
23 U
20 U
23 U
23 U
23 U
23 U
23 U
23 U
24 U
23 U
23 U
23 U
20 U
20 U
20 U
20 U
20 U
24 U
24 U
Ao
AB
150 U
110U
HOU
110U
110U
110U
HOU
86 U
I50J
110U
MOU
110U
110U
MOU
110U
HOU
110U
86 U
HOU
HOU
110U
110U
IIOU
HOU
150 U
IIOU
nou
IIOU
86 U
86 U
86 U
110J
86 U
130 U
130 U
c_
ar
190
210
200
200
HO
170
170
250
ISO
220
210
100 J
100J
210
200
200
200
250
190
220
220
220
210
180
190
79 J
180
200
260
260
200
170
240
210
140
Tlป
In
14U
11U
11U
11U
11U
11 U
11U
8.5 U
117
11U
11U
17 J
11U
11U
11U
1IU
I2J
8.5 U
HU
HU
12J
1IU
11U
HU
14 U
II U
11U
11 U
8.5 U
9.6 J
IOJ
8.5 U
8.5 U
11U
1IU
Sn
140U
63 U
63 U
63 U
63 U
63 U
64J
160 U
160 U
63 U
63 U
63 U
63 U
63 U
63 U
63 U
63 U
160 U
63 U
63 U
63 U
63 U
63 U
63 U
140 U
63 U
63 U
63 U
160 U
160 U
160 U
160 U
160 U
75 U
75 U
Ti
1800 J
3500 J
2200 J
2400 J
2400 J
2600 J
2400 J
1900J
2400
2700 J
2100 J
2400 J
2500 J
2100J
2900 J
2600 1
3000 J
2600
2500 J
2500 J
3000 J
2500 J
2600 J
2600 J
2200 J
2200 J
2400 J
3100 J
I900J
2000 J
1900 J
2600
2300
1900 J
2100J
U
9.9 U
8.8 U
18J
12J
11 J
8.8 U
8.8 U
10U
13J
8.8 J
8.8 U
IOJ
15J
15J
16J
I4J
11 J
10 U
8.8 U
8.8 U
16J
11 J
8.8 U
13J
9.9 U
11 J
in
8.8 U
12 J
10U
10 U
10 U
10 U
12U
12U
Zn
120 J
150
87 J
170
71 J
130 J
200
140 J
99J
57 J
81 J
130 J
190
84 J
88 J
120 J
150
380
160
180
88 J
79 J
110J
130 J
150
IOOJ
170
210
93 J
88 J
160 J
IOOJ
83 J
IOOJ
170 J
Zr
190
420
280
270
290
280
260
240
250
360
260
260
310
320
300
330
280
300
230
280
300
300
250
280
300
260
300
270
270
270
270
310
220
210
280
r
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 8 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S04002WNC1
S04002WNC1R
S04002WNDI
S04002WNE1
S04002WSA1
S04002WSB1
S04002WSCI
S04002WSD1
S04002WSE1
S04003ENA1
S04003ENB1
S04003ENC1
S04003END1
S04003ENE1
S04003ENF1
S04003ENG1
S04003ESA1
S04003ESB1
S04003ESC1
S04003ESD1
S04003ESDX
S04003ESE1
S04003ESF1
S04003ESG1
S04003ESG1D
S04003ESG1R
S0400DI1S1
S0400EHCC1
S0400EMISI
S0400EMIS2
S0400EM1S3
S0400EM1S4
S0400EMJS5
S0400HS1SI
S0400HSIS2
Hg
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
75 U
58 U
58 U
58 U
58 U
58 U
75 U
I9U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
Mo
7.1 U
7.1 U
7.1 U
7.1U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
6.7 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
6.7 U
5.4 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1U
Ni
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
160 U
160 U
160U
160U
160 U
160U
160 U
160 U
160 U
160 U
160U
170 U
160 U
160U
160 U
160 U
160 U
170 U
87 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
K
28000
26000
27000
29000
27000
26000
25000
27000
25000
27000
25000
28000
26000
23000
23000
21000
27000
24000
30000
27000
22000
25000
23000
23000
24000
22000
28000
20000
26000
23000
26000
20000
27000
24000
19000
Rb
IX U
89
100
96
100
100
87
84
100
88
96
90
100
110
100
96
86
110
91
110
no
81
98
100
91
90
95
92
86
93
93
90
78
91
87
79
Cp
oc
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
18U
27 U
27 U
27 U
27 U
27 U
18U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
An
A8
130 U
130 U
130 U
130 U
130 U
180J
130 U
140 J
140J
150 J
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
120 U
130 U
130 U .
130 U
130 U
130 U
120 U
150 U
130 U
130 U
130 U
130 U
130 U
130 U
I30U
o_
ar
220
I10J
210
140
120
230
220
140
220
240
200
200
210
200
240
160
140
220
150
140
250
140
240
200
230
230
200
180
140
160
85 J
160
230
200
160
rซm
Th
11U
11 J
11U
121
11U
I3J
19J
Ml)
I1U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
12U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
12U
14U
11 U
11U
11U
111)
11U
11U
11U
Sn
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
59 U
88 U
88 U
88 U
88 U
88 U
59 U
140 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
Ti
2200 J
2300 J
2100 J
2600J
1800J
1800J
3200
2400 J
2000 J
1800]
I800J
2100 J
2400 J
1900J
1800 J
1200 J
2000 J
2000J
2700
1700 J
2700 J
1800J
1500 J
2100 J
1600J
1700]
2100 J
1400 J
2200 J
2700 J
I800J
2900 J
3000J
2200J
2600J
U
12U
12U
I2U
12U
12U
17J
12U
12U
12U
I9U
19U
191)
19U
19 U
19U
191)
I9U
I9U
19U
\9U
9.8 J
19U
19U
19 U
19 U
19U
U J
9.9 U
12U
12U
12U
12U
20 J
12U
13J
Zn
81]
97 J
100 J
72 U
96 J
IOOJ
81 J
760
130 J
59]
59 U
77 J
59 U
170 J
74]
110]
180]
IOOJ
150 J
110]
94 U
2800
220
230
190 J
210
97 J
91 J
86]
90 J
72 U
140 J
80]
130J
150 J
Zr
200
280
220
280
240
280
270
290
250
ISO
190
200
250
210
210
200
230
210
220
250
.270
170
190
220
200
220
220
220
270
250
270
240
360
280
250
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 9 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0400HS1S3
S0400HSIS4
S0400HS1S5
S0400HS1S6
S0400HT1S1
S0400HT2DC
S0400HT2DCB
S0400HT2S1
S0400HT2S2
S0400HT2S3
S0400HT2S4
S0400HT3S1
S0400HT4D1
S0400HT4D2
S0400HT4D3
S0400HT4SI
S0400HT4S1D
S04001LEAI
S0400ILEB1
S04001LEC1
S0400ILEDI
S0400ILEE1
S0400ILEF1
S0400ILEG1
S0400ILEGID
S0400ILWA1
S0400ILWB1
S04001LWCI
S0400ILWD1
S0400ILWE1
S0400ILWFI
S04001LWG1
S0400ILWG1R
S0400MAEA1
S0400MAEB1
Hg
78 U
78 U
78 U
78 U
44U
44U
54 U
44U
44U
44U
44U
44U
54 U
54 U
54 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
78 U
37 U
37 U
Mo
7.1 U
7.1 U
7.1 U
7.1 U
5.3 U
5.3 U
5.5 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.5 U
5.5 U
5.5 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
9.4 U
9.4 U
Ni
59 U
59 U
59 U
59 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
nou
170 U
170 U
170 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
59 U
130 U
130 U
K
24000
26000
25000
24000
23000
20000
3100U
22000
22000
23000
22000
28000
24000
27000
25000
32000
31000
32000
29000
28000
27000
27000
28000
28000
25000
29000
26000
26000
32000
31000
35000
. 34000
30000
23000
26000
Rb
84
87
100
98
67
85
29 U
88
100
91
84
90
97 J
69 J
100
74
99
110
100
85
83
98
86
98
86
95
99
94
130
110
130
110
110
96 J
100
ป_-___^
Se
LJV
24 U
24 U
24 U
24 U
23 U
23 U
20 U
23 U
23 U
23 U
23 U
23 U
20 U
20 U
20 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24U
24 U
22 U
22 U
ซ _^
Ao
Ag
130 U
nou
130 U
130 U
nou
nou
86 U
nou
nou
nou
nou
nou
86 U
140 J
86 U
I50J
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
160 J
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
73 U
73 U
c_
or
230
180
210
160
130
210
36 U
170
190
200
150
200
140
91 J
140
82 J
78 J
140
140
150
130
150
170
130
130
130
170
140
110J
140
110J
130
130
160
170
Vim
i n
nu
nu
nu
16J
nu
nu
8.5 U
nu
nu
nu
n u
nu
8.5 U
8.5 U
23 J
nu
21 J
nu
nu
17J
nu
nu
n u
nu
11 U
nu
nu
12J
11U
n j
nu
13J
nu
9.8 U
9.8 U
ซ
Sn
75 U
75 U
75 U
75 U
63 U
63 U
160 U
63 U
63 U
63 U
63 U
63 U
160 U
160 U
160 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
75 U
nou
nou
Ti
1700J
2000 J
1900]
2600 J
1900 J
2300 J
690 U
2500 J
1900 J
1700 J
18007
2400 J
2200 J
1800J
2000 J
I900J
2000 J
1900J
2000 J
1800 J
1800 J
2200 J
2900 /
1900 J
2000 J
2200 J
2800 J
2IOOJ
2600 J
2600 J
2400 J
2100)
2200 J
2200 J
2100J
U
12U
12 U
12U
12U
15J
11 J
10 U
8.8 U
8.8 U
14J
8.8 U
8.8 U
IOU
21 J
IOU
16J
12U
15J
12U
18J
I2U
12U
I7/
12U
12U
17 J
12U
14J
15J
I2U
12U
12 U
12U
15 U
15 U
Zn
97 J
79 J
86 J
72 U
62 J
96 J
68 U
78J
81 J
50 J
56 J
110]
1700
2400
410
3400
3300
91 J
72 U
86]
72 U
72 U
IOOJ
72 U
89]
120]
72 U
72 U
180 J
91 J
150]
MOJ
88]
79]
120
Zr
200
290
280
240
290
260
27 J
290
310
320
320
310
220
220
170
170
170
290
240
270
250
210
260
260
240
250
230
300
220
310
260
270
270
210
190
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 10 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0400MAEC1
S0400MAED1
S0400MAEE1
S0400MAEF1
SIMOOM AWA1
S0400MAWB1
S0400MAWC1
S0400MAWD1
S0400MAWEI
S0400MAWFI
S0400MN1S1
S0400MN1S2
S0400MNNA1
S0400MNNB1
S0400MNNC1
S0400MNNDI
S0400MNSAI
S0400MNSAID
S0400MNSBI
S0400MNSC1
S0400MNSD1
S0400PAMAI
S0400PAMB1
S0400PAMC1
S0400PAMDI
S0400PAMD1D
S0400PAME1
S0400PAMF1
S0400PAMG1
S0400PAMGIR
S0400SAMAI
S0400SAMBI
S0400SAMB1D
S0400SAMCI
S0400SAMDI
I 1' ' I I *" i'i '! .1 ,
f I ปTซI__ 1. -ป_
Hg
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
54 U
54 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
58 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
Mo
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
5.5 U
5.5 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
7.9 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
Ni
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
nou
170 U
160U
160U
160 U
160U
160U
160 U
160 U
160U
160 U
130U'
130 U
130U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130U
130 U
130 U
K
25000
30000
26000
30000
30000
31000
22000
23000
26000
24000
27000
24000
23000
22000
25000
24000
24000
25000
25000
24000
23000
20000
25000
26000
27000
28000
26000
27000
27000
26000
29000
26000
27000
30000
28000
Rb
90 J
95 J
110
100
100
110
93 J
99
110
99
an
82 J
92
78 J
90
94
99
110
94
91
95
90J
86 J
96 J
110
120
110
110
93 J
95 J
29 U.
100
120
93 J
100
- -
Se
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
20 U
20 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
27 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
AR
87 J
73 U
91 J
73 U
98 J
130 J
73 U
73 U
92 J
73 U
86 U
86 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
73 U
73 U
73 U
73 U
73 U
84 J
73 U
73 U
90 J
73 U
73 U
73 U
73 U
73 U
Sr
130
210
120
no
140
130
250
160
120
190
270
250
230
230
240
270
190
210
270
140
200
240
230
210
150
160
160
140
170
170
180
160
180
200
170
-
Th
in
9.8 U
9.8 U
9.8 U
9.8 U
11J
9.8 U
9.8 J
9.8 U
9.8 U
8.5 U
9.2 J
8.8 U
9.5 J
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
8.8 U
9.8 U
9.8 U
9.8 U
13J
9.8 U
11J
9.8 U
9.8 U
9.8 U
18J
9.8 U
9.8 U
14J
9.8 U
1
Sn
110U
110U
MOD
1IOU
110U
110U
110U
UOU
IIOU
nou
160 U
160 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
88 U
nou
nou
nou
nou
nou
nou
nou
nou
nou
120 J
nou
nou
nou
nou
Ti
1700J
2100 J
1600 J
2300 J
2200 J
2100 J
2200 J
2600
2100 J
1700J
1700J
1600]
1800 J
1600 J
2200 J
1500J
1800J
2IOOJ
1400 J
1900J
1500J
1800)
2000 J
2400 J
2000 J
1800J
1900J
2100 J
2200 J
2100 J
2700
1900J
2100 J
2000 J
1700J
U
15 U
15 U
15 U
15U
15 U
15 U
15 U
15 U
15 U
15 U
10 U
11 J
19 U
19 U
19 U
19U
19 U
19U
19U
19 U
19U
15U
15 U
15 U
I5U
15U
15 U
16J
15U
15 U
15 U
16J
15U
17J
15 U
Zn
77 J
100
160
150
140
230
120
140
82 J
70 J
87 J
170 J
74 J
98 J
95 J
59 U
93 J
72 J
60 J
120 J
I50J
140
390
370
170
140
210
170
190
200
69 J
95
87 J
no
88 J
Zr
250
180
210
230
250
270
190
230
200
250
250
260
190
220
200
220
210
240
210
210
240
200
200
210
220
240
230
240
240
220
330
230
230
270
260
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 11 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
^ ^-
S0400SAME1
S0400SAMFI
S0400SAMG1
S0400SAMG1R
S0400SPEA1
S0400SPEBI
S0400SPEC1
S0400SPEDI
S0400SPEDX
S0400SPEE1
S0400SPEFI
S0400SPEG1
S0400SPWA1
S0400SPWBI
S0400SPWC1
S0400SPWD1
S0400SPWEI
S0400SPWF1
S0400SPWG1
S04032W1D3
S04032W1S1
S04032W1S2
S04032W1S3
S04032W1S3R
S0403IL1S1
S04031LIS2
S0403ILIS3
S0403RW1S1
S0403RWIS2
S0404AL1SI
S0404ALIS2
S0404ALIS3
S0404AR1S1
S0404AR1S2
S04053EIS1
Hg
37 U
37 U
37 U
58U
37 U
37 U
37 U
37 U
75 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
75 U
54 U
54 U
54 U
54 U
44U
44U
44U
78 U
78 U
44U
44U
44U
44U
44U
25 J
Mo
9.4 U
9.4 U
9.4 U
7.9 U
9.4 U
9.4 U
9.4 U
9.4 U
6.7 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
6.7 U
5.5 U
5.5 U
5.5 U
5.5 U
5.3 U
5.3 U
5.3 U
7.1 U
7.1 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.4 U
Ni
130 U
130 U
130 U
160 U
130 U
130 U
130 U
130 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
59 U
59 U
170 U
170 U
170 U
170 U
170 U
87 U
K
27000
25000
20000
24000
29000
24000
25000
27000
23000
22000
25000
35000
21000
23000
26000
24000
25000
26000
27000
24000
23000
25000
24000
24000
25000
21000
23000
23000
23000
18000
22000
25000
23000
24000
28000
Rb
^MMMW^^H
97 J
100
87 J
91
110
84J
861
140
89
97
94 J
120
90 J
80 J
92 J
100
84 J
100
110
87
100
99
53 J
741
87
91
83
84
93
89
95
95
87
94
100
Se
22 U
22 U
22 U
27 U
22 U
22 U
22 U
22 U
18U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
18U
20 U
20 U
20 U
20 U
23 U
23 U
23 U
24 U
24 U
23 U
23 U
23 U
23 U
23 U
24 U
Ag
91 J
73 U
73 U
130 U
73 U
73 U
73 U
73 U
120 U
73 U
86 J
73 U
73 U
73 U
78 J
73 U
73 U
96 J
73 U
I40J
86 U
UOJ
250 J
2801
IIOU
IIOU
IIOU
130 U
130 U
IIOU
IIOU
IIOU
IIOU
IIOU
150 U
Sr
200
120
150
190
160
210
120
140
260
150
110
150
200
210
220
110
210
230
90
250
220
230
UOJ
UOJ
170
180
160
220
240
210
180
260
250
240
130
Th
9.8 U
9.8 U
9.8 U
8.8 U
13J
9.8 U
9.8 U
9.8 U
13 J
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
13J
9.8 U
9.8 U
9.8 U
IOJ
12U
8.5 U
8.5 U
8.5 U
8.5 U
IIU
IIU
IIU
15 J
UU
IIU
UU
IIU
UU
UU
14 U
Sn
IIOU
IIOU
IIOU
88 U
IIOU
IIOU
UOU
IIOU
59 U
UOU
UOU
UOU
UOU
UOU
UOU
UOU
UOU
UOU
UOU
59 U
160 U
160 U
160 U
160 U
63 U
63 U
63 U
75 U
75 U
63 U
63 U
63 U
63 U
63 U
140 U
Ti
2100 J
1900 J
1300 J
1800 J
2300 J
2000 J
12001
1900 J
1800 J
1800J
19001
2600
1900 J
1900 J
1700 J
1800 J
1700 J
1800 J
1900 J
2600 J
2400
2300
1700J
1700 J
2200 J
2000 J
2500 J
2200 J
2500 J
2900 J i
2100 J
I700J
2000 J
1700 J
2400 J
U
15 U
1SU
18J
19 U
15 U
15 U
15U
15 U
7.3 U
15 U
15 U
191
161
16J
15 U
15 U
15U
15 U
15 U
12J
12J
10U
16J
10 U
8.8 U
131
8.8 U
12U
12U
I1J
8.8 U
8.8 U
15J
10)
12J
Zn
621
140
100
1001
140
170
1700
320
94 U
820
390
1000
120
120
130
110
560
780
150
140 J
120 J
120 J
2700
2900
81 J
581
UOJ
89 J
2201
180
UOJ
130J
IOOJ
1001
821
Zr
260
220
220
210
230
250
220
250
210
270
230
250
220
230
220
230
210
230
220
270
270
240
220
190
270
250
250
320
310
230
290
220
250
220
280
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 12 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S04053E1S2
S0407IH1D1
S0407IM1S1
S05002WNA1
S05002WNB1
S05002WNC1
S05002WSA1
S05002WSB1
S05002WSC1
S05003E1S1
S05003E1S2
S05003E1S3
S05003E1S3D
S0500EHCC1
S0500EHNEI
S0500EHSE1
S0500MNID!
S0500MN1SI
S0500MNIS2
S0500PDEA1
S0500PDEBI
S0500PDECI
S0500PDED1
S0500PDEE1
S0500PDEF1
S0500PDEG1
S0500PDEHI
S0500PDEH1R
S0500PDWA1
S0500PDWB1
S0500PDWC1
S0500PDWD1
S0500PDWE1
S0500PDWE1D
S0500PDWF1
I 1 _ TT*ซป ortolir+A UK
Hg
19U
75 U
54 U
78 U
78 U
78 U
78 U
78 U
78 U
44U
44U
44U
44U
19J
I9U
19U
75 U
54 U
54 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U.
37 U
37 U
=^==
Mo
5.4 U
6.7 U
5.5 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
5.3 U
5.3 U
5.3 U
5.3 U
5.4 U
5.4 U
5.4 U
6.7 U
5.5 U
5.5 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
===^=
-ซ
Ni
87 U
170 U
170 U
59 U
59 U
59 U
59 U
59 U
59 U
170 U
170 U
170 U
170 U
87 U
87 U
87 U
170 U
170 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
K
22000
12000
20000
29000
30000
34000
32000
29000
33000
30000
22000
25000
23000
22000
28000
18000
23000
24000
21000
24000
17000
20000
21000
19000 .
20000
23000
26000
23000
20000
23000
22000
24000
22000
21000
20000
Rb
83
59 J
75 J
110
110
110
120
110
120
87
86
81
84
83
72
81
93
79 J
80 J
94 J
82 J
79 J
93 J
98
76 J
84 J
90 J
87 J
91 J
100
95 J
89 J
86 J
86 J
91 J
SP
oc
24 U
18U
20 U
24 U
24 U
24 U
24 U
24 U
24 U
23 U
23 U
23 U
23 U
24 U
24 U
24 U
18U
20 U
20 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U .
22 U
22 U
22 U
22 U
Ao
A8
150 U
120 U
86 U
130 U
130 U
130 U
130 J
130 U
130 U
110U
110U
1IOU
110U
150 U
150 U
150 U
120 U
86 U
89 J
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
73 U
: - - ^=
C
or
220
630
240
130
120
160
140
140
150
180
260
290
290
210
110
170
280
240
260
200
200
200
110
190
170
130
no
160
200
140
150
200
190
170
180
ปfiป
Th
14U
12 U
8.5 U
11U
11U
11U
11U
11U
II U
18J
1IU
11U
11U
14 U
14 U
14 U
12U
IN
11 J
9.8 U
9.8 U
15J
9.8 U
13J
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
ft
Sn
140 U
59 U
160 U
75 U
75 U
75 U
75 U
75 U
75 U
63 U
63 U
63 U
63 U
140 U
140 U
140U
59 U
160 U
160 U
I10U
IIOU
110U
110U
IIOU
110U
IIOU
nou
IIOU
IIOU
nou
IIOU
IIOU
IIOU
nou
nou
Ti
2200 J
28001
4400
3000 J
2000 J
2100 J
2200 J
1900J
2500 J
2300 J
2500 J
2600 J
2400 J
I500J
1000U
1500J
2100 Jl
2300
2200 }
2500
I900J
1500 J
I500J
1800 J
1800 J
I500J
I800J
1900J
I600J
1800 J
2400
2200 J
1700 J
1700 J
1700 J
" '^- - -
U
9.9 U
7.3 U
10U
I2U
13J
12U
12U
12U
12U
14J
8.8 U
8.8 U
8.8 U
9.9 U
11 J
19J
10J
10U
19J
15U
15 U
15 U
15U
15 U
15 U
15 U
15U
15U
15 U
15 U
15U
15 U
15U
15U
15 U.
Zn
170
9800
1000
79 J
72 U
72 U
150 J
94 J
98 J
93 J
110J
110J
87 J
55 J
44J
67 J
94 J
760
160 J
87 J
120
54 J
100
92
33 J
69 J
99
87 J
110
150
82 J
91
100
no
140
Zr
250
240
300
250
260
240
230
230
250
260
260
250
260
210
140
180
220
210
250
270
220
200
220
220
220
220
210
220
200
190
170
260
190
200
190
. --- ---ปปปซ &.!.ปป VIIN* vปs*isf%*viuu lllllll 13 IQLnJIL^U.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 13 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S0500PDWG1
S0500PDWH1
S0500PDV/11
S0500SESA1
S0500SESB1
S0500SESC1
S0500SESD1
S0502MN1S1
S0502MN1S2
S05103E1S1
S05I03EIS2
S06004AMAI
S06004AMB1
S06004AMC1
S06004AMDI
S06004AME1
S06004AMF1
S06004AMG1
S06004AMH1
S06004AMII
S06004AMJ1
S06004AMK1
S06004AMLI
S06004AMM1
S06004AMN1
S06004AMO1
S06004AMPI
S06004AMQI
S06004AMQ1D
S06004AMR1
S06004AMSI
S06004AMT1
S06004AMU1
S06004AMU1R
S06004AMV1
U - The analyte w
Ho
"8
37 U
37 U
37 U
19 U
19 U
32 J
I9U
54 U
54 U
44U
44U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
as not detec
It/In
1V1O
9.4 U
9.4 U
9.4 VJ
5.4 U
5.4 U
5.4 U
5.4 U
5.5 U
5.5 U
5.3 U
5.3 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
:ted above th
NTS
Nl
ป ^ป
130 U
130 U
130 U
87 U
87 U
87 U
87 U
170 U
170 U
170 U
170 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
e detection li
K
22000
21000
23000
24000
26000
23000
21000
25000
22000
29000
20000
26000
27000
25000
27000
28000
28000
27000
26000
26000
27000
25000
26000
27000
25000
30000
24000
27000
28000
28000
24000
21000
25000
23000
22000
mit the Hptp
Rb
95 J
92 J
94 J
89
100
90
94
82 J
87 J
99
73
110
130
120
no
160
110
110
110
120
130
120
120
120
120
110
100
130
120
120
120
110
98
110
92 J
ft inn limit i
Se
22 U
22 U
22 U
24 U
24 U
24 U
24 U
20 U
20 U
23 U
23 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
- 22 U
22 U
22 U
22 U
22 U
22 U
22 U
C rปnnrtas4
Ag
73 U
73 U
73 U
150 U
150 U
150 U
150 U
86 U
99 J
110U
IIOU
73 U
73 U
97 J
73 U
110J
77 J
140J
73 U
73 U
73 U
73 U
73 U
73 U
88 J
73 U
91 J
73 U
73 U
73 U
73 U
73 U
73 U
73 U
96J
Sr
^^^^^M
180
180
180
190
150
230
220
230
260
180
260
150
130
120
120
110
130
140
110
120
120
130
120
110
120
140
150
150
140
140
110
130
130
120
no
MMMMMHM^M
Th
^^ ปซ
I4J
9.8 U
18 J
14 U
14 U
14 U
14 U
8.5 U
8.5 U
11U
II U
9.8 U
9.8 U
9.8 U
13J
15J
16J
IOJ
9.8 U
9.8 U
I5J
13J
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
14J
9.8 U
9.8 U
9.8 U
9.8 U
9.9 J
Sn
^^MMMMM
110U
IIOU
nou
140 U
140U
140 U
140 U
160 U
160 U
63 U
63 U
IIOU
IIOU
IIOU
IIOU
IIOU
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
nou
HOU
Ti
2000 J
2000 J
2200 J
1600J
1500 J
2000 J
1500J
2200 J
2000 J
2500 J
2500 J
2000 J
2300 J
1600J
2200 J
1900J
2200 J
1800 J
1700 J
2100 J
2200 J
1500 J
2100 J
1800 J
1600J
2000 J
1700 J
2700
2100 J
2700
2000 J
1900 J
1700 J
2000 J
1500 J
U
15 U
15 U
15U
9.9 U
I4J
18J
9.9 U
10 U
13J
8.8 U
8.8 U
15U
15 U
15U
15 U
15 U
15U
15U
19 J
15 U
15 U
I8J
15U
15 U
15 U
15U
22 J
15 U
15U
15 U
15 U
15 U
15 U
15 U
15U
Zn
80 J
83 J
64)
67 J
97 J
62 J
85 J
110J
130 J
110J
160
89 J
64 J
62 J
40 J
96
120
76 J
120
110
83 J
79 J
93
52 J
89 J
43 J
100
100
85 J
71 J
120
140
86 J
100
831
Zr
200
190
210
190
200
250
250
300
240
280
230
210
260
230
220
250
230
240
220
200
240
230
240
250
230
230
230
260
250
260
220
210
310
220
220
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 14 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S06005AMA1
S06005AMBI
S06005AMCI
S06005AMD1
S06005AME1
S06005AMF1
S06005AMG1
S06005AMH1
S0600SAMH1R
S06005AMII
S06005AMJ1
S06005AMK1
S06005AML1
S06005AML1D
S06005AMM1
S06005AMNI
S06005AMO1
S06005ENA1
S06005ENB1
S06005ENCI
S06005END1
S06005ENE1
S06005ENE1R
S06005ENFI
S06005ENG1
S06005ENH1
S06005ENI1
S06005ENJI
S06005ENK1
S06005ENL1
S06005ENM1
S06005ENNI
S06005ENOI
S06005ENPI
S06005ENP1D
Hg
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
Mo
7. ID
7.1 U
7.1 U
7.1U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.5 J
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1 U
7.1U
7.1U
7.1 U
7.1 U
7.1 U
7.1 U
7.1U
7.1 U
7.1 U
7.1 U
Ni
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
. 93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
K
26000
21000
27000
26000
23000
23000
22000
25000
26000
25000
23000
25000
23000
24000
25000
26000
22000
28000
29000
29000
27000
24000
23000
22000
26000
24000
27000
24000
23000
26000
28000
23000
23000
24000
24000
Rb
94
100
110
110
100
96
83
110
97
99
86
86
110
110
100
94
99
110
120
100
110
94
87
98
81
95
91
98
90
110
110
98
95
98
76
Se
21 U
21 U
21 U
21 U
21 U'
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
Ag
120 J
100 U
IOOU
100 U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
110J
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU
1IOJ
IOOU
IOOU
IOOU
IOOU
Sr
no
180
130
190
120
110
180
140
130
220
100
130
160
150
120
130
97
140
120
120
140
230
200
220
170
160
140
170
130
150
120
ISO
110
130
110
Th
HU
I4U
14 U
UU
14 U
16J
14 U
17J
14U
I4U
14U
I4U
14U
14U
16J
14 U
14U
14 U
14 U
14 U
14 U
14U
14U
14 U
14 U
14 U
14 U
14U
14U
14 U
14U
14 U
14U
14U
I4U
Sn
99U
99 U
99 U
99 U
99 U
99U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
Ti
1600 J
1600 J
I900J
1500]
1900 J
2800
17001
1500J
2100 J
2000 J
2500
2500
2100J
2400
1800J
2300 J
2100J
2600
1500 J
2200 J
1800 J
2100 J
2100]
1600J
1500J
1800 J
2000 J
2000 J
1800J
1900 J
2200 J
1600J
I900J
2000 J
I800J
U
13 U
14J
I3U
13 U
13U
13 U
13U
13U
13 U
13J
16J
13U
13U
13 U
13U
16J
13U
17J
13U
13U
19J
13U
13U
13U
15J
13U
13U
15J
13U
13U
13 U
13 U
13U
13 U
13U
Zn
57 U
72 J
120J
92 J
63 J
IIOJ
57 U
64J
100 J
76 J
110J
95 J
120 J
83 J
140 J
140 J
57 U
120 J
95 J
59 J
220
83 J
120 J
73 J
63 J
83 J
120 J
120J
100 J
65 J
57 U
IOOJ
100 J
69 J
59 J
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Zr
MM^H
220
160
240
230
220
210
190
190
220
220
210
240
220
250
220
250
210
220
220
240
230
200
190
170
220
220
230
240
240
210
240
180
230
230
240
Page 15 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
^^^^^^^^PB^M^B
ID
S06005ENQ1
S06005ENR1
S06005ENS1
S06005ESAI
S06005ESA1R
S06005ESB1
S0600SESC1
S06005ESD1
S06005ESE1
S06005ESFI
S06005ESG1
S06005ESH1
S06005ES11
S06005ESJ1
S06005ESK1
S06005ESL1
S06005ESM1
S06005ESN1
S06005ESO1
S06005ESP1
S06005ESP1D
S06005ESQ1
S06005ESR1
S06005ESS1
S06006ENAI
S06006ENBI
S06006ENC1
S06006END1
S06006ENEI
S06006ENFI
S06006ENF1D
S06006ENGI
S06006ENH1
S06006ENI1
S06006ENJI
1 1 - TViA analvto u
Hg
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
37 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
tftc nnt t\ote*f
Mo
7. U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
9.4 U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
7. U
WMMHH*ซ^H
Ni
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
130 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
K
22000
25000
23000
30000
25000
25000
24000
28000
23000
24000
31000
26000
29000
25000
26000
28000
28000
24000
26000
23000
24000
28000
30000
33000
27000
36000
35000
21000
21000
24000
22000
23000
22000
20000
24000
Rb
92
92
92
120
110
100
120
130
93 J
96 J
130
100
100
90 J
no
110
100
95 J
100
80 J
91 J
99
99
120
99
130
120
93
85
89
85
95
86
86
110
Se
IJC
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
22 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
Ao
A8
IOOU
100U
IOOU
IOOU
IOOU
IOOU
toou
110J
73 U
I20J
73 U
97 J
94 J
73 U
140J
79 J
73 U
96 J
73 U
120 J
73 U
73 U
73 U
73 U
IOOU
IOOU
IOOU
IOOU
IOOU
IOOU "
IOOU
IOOU
IOOU
IOOU
IOOU
c-
3r
180
110
170
170
160
150
150
120
230
210
130
240
160
ISO
no
200
130
190
190
210
200
140
170
160
150
150
120
230
180
190
190
140
220
200
170
Tl*
In
14U
14U
I4U
14 U
14 U
14 U
14U
14 U
9.8 U
9.8 U
9.8 U
12J
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
9.8 U
10J
11 J
9.8 U
9.8 U
9.8 U
14 U
14 U
14 U
14U
14 U
14 U
14 U
14 U
I4U
14 U
14 U
ฃ
Sn
99 U
99 U
99U
99 U
99 U
99U
99 U
99 U
I10U
IIOU
110U
I10U
110U
1IOU
UOU
IIOU
110U
UOU
110U
IIOU
UOU
uou
UOU
UOU
99 U
99 U
99 U
99 U
99U
99 U
99 U
99 U
99 U
99 U
99 U
^a^mmm
Ti
1600J
2200 J
2200 J
2300 J
1700 J
1900J
1600 J
2600
2200 J
I400J
2400
I800J
2200 1
1400 J
1900 J
I800J
2700
1500 J
2100 J
2000 J
1600 J
2400 J
2100 J
2400
2100J
2600
1700J
1300J
1700 J
2100 J
1500 J
1700J
1800 J
2300 J
1400 J
U
14J
13U
13U
13 U
13U
13U
I3U
13U
15 U
15 U
15 U
15 U
15U
15 U
15 U
I5U
19J
15 U
20 J
15 U
I5U
19)
15U
15 U
13U
I5J
18J
13U
13U
I3U
13 U
13U
13U
13 U
13 U
Zn
75 J
120 J
62 J
110J
91 J
120 J
210
65 J
65 J
78 J
43 J
58 J
51J
110
85 J
41 J
51 J
100
86 J
45 J
59 J
140
110
100
91 J
100J
92 J
140J
100J
110J
99 J
140 J
110J
100 J
75 J
Zr
210
230
240
210
200
180
190
190
190
240
210
160
200
190
220
220
200
260
200
240
220
240
220
240
280
250
250
180
220
190
180
190
180
ISO
180
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 16 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S06006ENM1
S06006ENN1
S06006ENO1
S06006ESA1
S06006ESAID
S06006ESB1
S06006ESCI
S06006ESDI
S06006ESE1
S06006ESF1
S06006ESG1
S06006ESH1
S06006ESI1
S06006ESJI
S06006ESK1
S06006ESLI
S06006ESM1
S06006ESNI
S06006ESO1
S06045E1S1
S06045E1S2
S0604MN1S1
S0604MN1S2
S0604MNIS3
S06125E1S1
S06125EIS2
S06125E1S3
S06154E1SI
S06154EIS2
S06154E1S3
S06I74E1S1
S06I74EIS2
S06I86EISI
S06186EIS2
S06205EIS1
II - Thp analvtp ปi
Hg
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
65 U
54 U
54 U
54 U
54 U
54 U
54 U
54 U
54 U
44U
44U
44U
44 U
44U
54 U
54 U
54 U
QC nf\t rfot^ri
M
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
5.i
5.!
5.:
5.'.
5.'.
5.!
5.i
5.!
5.:
5.:
5.:
5.:
. s.:
5.!
5.!
s.;
- ' " "_
fart ซli
(o
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
iU
;u
>u
iU
iU
iU
)U
iU
(U
(U
III
ID
tu
iU
iU
iU
tftirA tV*
Ni
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
93 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
1
K
23000
20000
23000
26000
25000
23000
26000
27000
22000
20000
21000
21000
23000
22000
22000
20000
21000
22000
22000
24000
22000
25000
24000
24000
27000
24000
26000
20000
23000
23000
25000
22000
20000
21000
23000
Rb
91
75
83
94
99
95
no
100
97
70
92
86
100
77
83
95
84
88
80
85 J
88 J
95 J
96 J
86 J
90 J
90 J
100
77
75
99
94
84
77 J
85 J
88 J
Se
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
21 U
20 U
20 U
20 U
20 U
20 U
20 U
20 U
20 U
23 U
23 U
23 U
23 U
23 U
20 U
20 U
20 U
AR
100U
100 U
100U
100 U
100 U
100 U
100 U
100 U
100 U
100 U
100U
100 U
100 U
100U
IOOU
100 U
IOOU
IOOU
IOOU
86 J
86 U
86 U
86 U
86 U
86 U
86 U
86 U
I10U
110U
110U
110U
110U
86 U
120 J
86 U
*MMHM^M
Sr
^^^MMM^^
220
160
ISO
250
260
260
240
260
240
210
230
230
220
210
180
190
190
210
150
210
200
240
240
250
260
220
150
180
200
170
170
210
210
240
210
Th
14 U
14U
!4U
14 U
I4U
14 U
14 U
14 U
14 U
I4U
14U
I4U
14 U
14U
14U
14U
14U
14 U
14U
8.5 U
8.5 U
8.5 U
8.5 U
8.5 U
12 J
8.5 U
8.5 U
11U
I1U
11U
I5J
11U
18J
8.5 U
9.5 J
Sn
99 U
99 U
99 U
99 U
99U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99 U
99U
99 U
99 U
160 U
160 U
160 U
160 U
160 U
160 U
160 U
160 U
63 U
63 U
63 U
63 U
63 U
160 U
160 U
160 U
Ti
1700J
2100J
I500J
1700 J
1500J
1900 J
2200 J
2000 J
1800 J
1700 J
1900J
1700J
2000 J
1900 J
1600J
1800J
1600J
1900J
1800J
1900J
2300 J
1900 J
2200 J
2300
2200 J
2200 J
2000 J
2800 J
1900 J
2400 J
2300 J
2700 J
2600
2000 J
2200 J
U
13U
13U
15 J
13 U
13U
13 U
13U
14J
13U
13U
13U
13U
13 U
13U
13 U
13U
14J
13U
13J
10U
14 J
13J
11 J
10U
16J
10U
10U
13J
16J
9.8 J
10J
8.8 U
10U
I2J
13J
Zn
120 J
150 J
110J
79 J
120 J
83 J
84 J
57 U
57 U
140 J
66 J
130 J
99 J
58 J
68 J
140 J
1101
120 J
150 J
99 J
120 J
68 U
68 U
76 J
150J
68 U
250
84 J
100J
130J
120 J
I30J
120 J
77 J
100J
Zr
190
220
230
210
190
190
230
240
200
200
ISO
160
200
180
220
180
230
230
210
260
240
240
220
260
240
250
290
270
240
240
280
230
310
290
240
= ' . '=3
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 17 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
S06205E1S2
S06274E1S1
S06274E1S1D
S06274E1S2
S06285EISI
S06285E1S2
S06315EIS1
S06315E1S2
S06315E1S3
S06394E1S1
S06394E1S2
S0800RVSA1
S0800RVSBJ
S0800RVSC1
S0800RVSD1
S0800RVSE1
S0800RVSFI
S0800RVSGI
S0800RVSG1R
S0800WFBE1
S0800WFBWI
S0800WFNEI
S0800WFNWI
S0800WFSE1
S0800WFSEID
S0800WFSW1
S08014E1S1
S08014E1S2
S080I4EIS3
S09034E1S1
S09034E1S2
SOCTYSH1D1
SOCTYSH1SI
SOCTYSHIS2
SOCTYSH1S3
1 1 - Thp analvt** u;
Hg
54 U
44U
44 U
44U
54 U
54 U
44U
44U
54 U
44U
44U
19 U
19 U
19U
19U
19 U
19 U
19U
19U
39 J
19 U
19 U
19 U
19 U
19 U
19 U
44U
44U
44U
44U
44U
75 U
54 U
54 U
54 U
Mo
5.5 U
5.3 U
5.3 U
5.3 U
5.5 U
5.5 U
5.3 U
5.3 U
5.5 U
5.3 U
5.3 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
6.7 U
5.5 U
5.5 U
5.5 U
nmi^aai
Ni
170 U
170 U
nou
nou
170 U
)70U
170 U
170 U
170 U
170 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
170 U
170 U
170 U
170 U
170 U
170 U
170U
170 U
K
25000
22000
22000
18000
18000
21000
21000
23000
26000
19000
20000
27000
22000
26000
22000
24000
23000
24000
25000
29000
30000
28000
25000
23000
23000
25000
24000
22000
21000
23000
25000
25000
24000
30000
25000
Rh
110
88
96
93
92 J
94 J
88
76
82 J
76
97
100
84
85
92
88
90
92
100
83
89
100
110
110
88
87
94
82
89
90
94
100
98
91 J
89 J
Co
20 U
23 U
23 U
23 U
20 U
20 U
23 U
23 U
20 U
23 U
23 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
23 U
23 U
23 U
23 U
23 U
18U
20 U
20 U
20 U
A A
A8
86 U
110U
nou
IIOU
86 U
86 U
IIOU
1IOU
86 U
IIOU
IIOU
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
IIOU
IIOU
IIOU
IIOU
IIOU
12tfU
86 U
86 U
110J
Sr
190
170
180
190
190
200
220
210
170
200
200
230
190
130
210
250
200
160
170
220
170
270
260
210
230
230
220
210
210
290
260
200
240
190
290
Th
8.5 U
1IU
11U
11U
8.5 U
8.5 U
11 U
I8J
8.5 U
11U
11U
14U
14 U
14 U
14 U
14U
14U
14U
14 U
14 U
14U
I4U
14 U
14U
14U
14U
11U
II U
11 U
11U
nu
12U
8.5 U
8.5 U
8.5 U
Sn
160 U
63 U
63 U
63 U
160 U
160 U
63 U
63 U
160 U
63 U
63 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140U
140 U
140 U
63 U
63 U
63 U
63 U
63 U
65 J
160 U
160 U
160 U
Ti
1800J
2400 J
2000 J
2200 J
2000 J
2500
I700J
2IOOJ
2200 J
3100J
1900 J
1500 J
l'400J
2000 J
1600J
1600J
2IOOJ
1900 J
1900 J
2300 J
2400 J
2100 J
I500J
1500;
2100J
1900 J
2200 J
2200 J
2500 J
2700 J
3100;
2400 J
2900
2200 J
1700 J
U
10U
I3J
8.8 U
8.8 U
10 U
12J
I6J
8.8 U
10U
11 J
8.8 U
9.9 U
12J
9.9 U
9.9 U
9.9 U
12J
10J
9.9 U
14J
14]
9.9U
9.9 U
9.9 U
9.9 U
9.9 J
8.8 U
16i
9.8 J
8.8 U
8.8 U
7.3 U
10U
10 U
IOU
Zn
100J
78 J
130 J
150
140 J
HO;
97 J
72 J
200 J
140 J
I30J
62/
94;
79;
110J
74;
44 J
79)
78;
94;
91 J
69;
43;
743
69;
73;
100;
97;
98;
100J
no;
94 U
1200
760
620
Zr
250
290
250
250
270
240
260
300
220
280
270
250
200
210
210
220
250
230
250
230
230
190
190
250
220
260
280
270
260
220
240
300
270
300
210
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 18 of 19
-------
TABLE IB
SUPERIOR WASTE ROCK
SPECTRACE 9000 XRF DATA (PPM)
ID
SOCTYSH1S4
SOCTYSHIS5
SOVFWNW1
S1RSOSCCS1
S1RSOSNES1
S1RSOSNWS1
SIRSOSSES1
SIRSOSSSSI
SIRSOSSWS1
S2RSOSCCS1
S2RSOSNES1
S2RSOSNWSI
S2RSOSSES1
S2RSOSSWS1
S2RSOSSWS1B
S700FGANE1
S700FGANW1
S700FGASE1
S700FGASW1
S700FGCSW1
S700FGCSWX
S700FGCWC1
S700FGCWC1D
S700FGECCI
S700FGGCC1
S700FGGCC1R
S700FGGNE1
S700FGGNW1
S700FGGSEI
S700FGGSW1
Hg
75 U
75 U
58 U
19U
I9U
19 U
19 U
23 J
19U
44 U
44U
44U
44U
44U
44 U
19 U
19U
19U
19 U
19U
75 U
19U
19 U
I9U
19 U
19 U
19U
19U
25 J
19U
Mo
6.7 U
6.7 U
7.9 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 LT
5.4 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.3 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
6.7 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
5.4 U
Ni
170 U
170 U
160U
87 U
87 U
87 U
87 U
87 U
87 U
170 U
170 U
170 U
170 U
170 U
170 U
87 U
87 U
87 U
87 U
87 U
170 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
87 U
K
24000
26000
25000
27000
27000
28000
27000
28000
27000
29000
24000
28000
28000
25000
4800 U
25000
27000
26000
27000
24000
31000
29000
27000
31000
26000
27000
27000
26000
25000
23000
Rb
81
98
90
94
110
96
96
110
98
110
120
92
110
92
15U
81
84
100
94
81
100
110
100
130
110
90
110
92
120
98
Se
18 U
18U
27 U
24 U
24 U
24 U
24 U
24 U
24 U
23 U
23 U
23 U
23 U
23 U
23 U
24 U
24 U
24 U
24 U
24 U
18U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
24 U
Ag
120 U
120 U
130 U
150 U
150 U
150 U
150 U
150 U
150 U
120 J
110U
110U
110U
110U
1IOU
150 U
150 U
150 U
150 U
150 U
120 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
150 U
Sr
230
180
240
160
130
150
170
87 J
140
160
120
140
150
120
32 U
210
210
210
190
65 J
100
150
150
140
140
140
120
240
130
140
Th
12U
12U
13J
14U
14U
I4U
14U
14 U
14 U
11U
11U
11 U
11 U
13J
11 U
14 U
14U
14 U
14 U
14U
12U
14 U
UU
14 U
14U
14 U
14U
14 U
14U
14U
Sn
59 U
59 U
88 U
I40U
140 U
140 U
140 U
140 U
140U
63 U
63 U
63 U
63 U
63 U
63 U
I40U
140 U
140U
140 U
140 U
59 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
140 U
Ti
1900 J
1800J
1900J
2000 J
2600 J
2400 J
1900 J
2400 1
2100 J
2000 J
2400 J
2400 J
2500 J
3100 J
1400 U
1200/
1200 J
2100J
1600J
1500 J
1700J
2500 J
27001
2200 J
2100J
1900J
1900 J
2200 J
2000 J
2600 J
U
121
7.3 U
19 U
12J
IOJ
9.9 U
IOJ
I5J
9.9 U
8.8 U
8.8 U
16J
8.8 U
8.8 U
8.8 U
9.9 U
16)
9.9 U
9.9 U
9.9 U
7.3 U
13J
21 J
15J
15J
9.9 U
9.9 U
15J
13J
9.9 U
Zn
2001
100 J
250
370
1200
310
110J
77 J
130 J
330
460
100 J
170
74 J
43 U
69 /
41 J
57 J
731
4100
6600
110J
120 J
120J
180
120 J
160
130 J
140
220
Zr
240
250
240
210
230
240
230
260
280
240
200
270
270
260
22 U
150
170
140
170
140
200
270
230
270
180
180
200
260
210
180
U - The analyte was not detected above the detection limit, the detection limit is reported.
J - The associated numerical value is an estimated quantity between the detection limit and the quantitation limit.
Page 19 of 19
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APPENDIX D
Street Codes for Sample Identification
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T-StreeLCode
7/24/2002
i ./'^-: ' /:-: '-: ' :>::: "-*& ''- Street x ;:# ?ฃ-^>^U.;,v~ ;:7: v~
1ST STREET
2ND AVENUE EAST
2ND AVENUE WEST
3RD AVENUE EAST
3RD AVENUE WEST
3RD STREET
4TH AVENUE EAST
4TH AVENUE WEST
4TH STREET
5TH AVENUE EAST
5TH AVENUE EAST
5TH STREET WEST
6TH AVENUE EAST
7TH STREET
ALDER STREET
ALLEY BETWEEN 4TH & 5TH AVENUE
ALLEY BETWEEN 5TH & 6TH AVENUE
ALLEY BETWEEN ALDER & SPRUCE
ALLEY BETWEEN PINE & SPRUCE
ARIZONA AVENUE
CALIFORNIA AVENUE
CEDAR STREET
CEMETARY ROAD
CITY SHOP
COUNTRY LANE
DIAMOND ROAD
ELEMENTARY SCHOOL
EVA HORNING PARK
FAIRGROUNDS
FLAT CREEK ROAD
HIGH SCHOOL
HIGH SCHOOL TRACK
ILLfNOfS AVENUE
IRON MOUNTAIN HIGHT
IRON MOUNTAIN ROAD
LITTLE PARK
MAIN STREET WEST
MAPLE STREET
MONTANA AVENUE
MULLAN ROAD EAST
MULLAN ROAD WEST
DLAD MULLAN ROAD
PIKE STREET
=ปVER STREET
RIVER STREET NORTH
RIVERBEND ROAD
^todel^
1S
2E
2W
3E
3W
3S
4E
4W
4S
5E
5E
Fl
6E
7S
AL
4A
5A
SA
PA
AR
CA
CE
CM
SP
CO
Dl
EM
EH
FG
FC
HS
HT
.
H
M
P
MN
MA
MT
ME
\/IW
DM
D
I
N
B
Pagel
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T-Street Code
7/24/2002
v^-.^-^ie^ew^^viV-!.:--. Street . :' ':.'""." ^^^SPIili
RIVERSIDE ROAD
RIVERSIDE ROAD ALLEY
RIVERSIDE ROAD WEST
RIVERSTREET/JOHNSON LANE OPENSPACE
ROBINS NEST LANE
SHAW GULCH LANE
SLOW AY WEST
SOUTHSIDE ROAD
SPRITIS WALK LANE
SPRUCE STREET
SUNNYSIDE LANE
WESTFIELD PARK
$&$&&$$%&
RV
RA
RW
OS
RL
SG
SW
SO
SL
SP
SU
WF
Page 2
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