Estimating Emissions Associated with
   Portable Fuel Containers (PFCs)
United States
Environmental Protection
Agency

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                     Estimating Emissions Associated with
                         Portable Fuel Containers (PFCs)
                                    Assessment and Standards Division
                                   Office of Transportation and Air Quality
                                   U.S. Environmental Protection Agency
                                              NOTICE

                  This report does not necessarily represent final EPA decisions or positions. It is
                  intended to present technical analysis of issues using data which are currently
                  available. The purpose in the release of such reports is to facilitate the exchange of
                  technical information and to inform the public of technical developments which may
                  form the basis for a final EPA decision, position, or regulatory action.
v>EPA
United States                                               EPA420-R-07-001
Environmental Protection                                          February 2007
Agency

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1.0    INTRODUCTION

Portable fuel containers (PFCs, or gas cans) are consumer products used to refuel a wide variety
of gasoline-powered equipment. California has established an emissions control program for gas
cans which began in 2001. Since then, some other states have adopted the California
requirements. Last year, California adopted a revised program.

EPA is planning to propose standards to control VOCs as an ozone precursor and also to
minimize exposure to VOC-based toxics such as benzene and toluene. Gasoline is highly
volatile and evaporates easily from containers that are not sealed or closed properly. Although
an individual gas can is a relatively modest emission source, the cumulative VOC emissions
from estimated population of 80 million gas cans are quite significant. Left uncontrolled, the
evaporative emissions  from a gas can are up to 60 times the VOC of a new Tier 2 vehicle
evaporative control system. Gas can emissions are primarily of three types: evaporative
emissions from unsealed or open containers; permeation emissions from gasoline passing
through the walls of the plastic containers; and evaporative emissions from gasoline spillage
during use.

This report proposes an approach to estimating the VOC inventory associated with PFCs used
for gasoline. (This analyses does not consider PFCs used for either kerosene or diesel fuel.)

In 1999, California's Air Resources Board (ARB) proposed a methodology to estimate annual
emissions from portable fuel containers (PFCs) within California.[1,2] Their approach involved
first distinguishing and characterizing the various mechanisms (i.e., sources) of emissions of
hydrocarbons (HCs) and then estimating the frequency of occurrence and emission rates
associated with each of those sources.

For most of those  sources, the daily emission rates also depend upon these four factors:

  •    Composition of the PFC (plastic versus metal),
  •    Whether the PFC was stored open or closed (i.e., a PFC is considered "open" if its vent
       and or spout is  uncapped),
  •    Average size/capacity of the PFC, and
  •    Frequency the PFC was refilled.

ARB found (based upon analysis of their survey data) that those four factors were themselves
dependent upon whether the PFC was used for residential or commercial use. The ARB survey
results are given in the following table.

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                                       Table 1
                          Distribution of PFCs by Usage Type

Residential
Usage
Commercial
Usage
Plastic
Closed
53%
33%
Plastic
Open
23%
39%
Metal
Closed
13%
18%
Metal
Open
11%
10%
ARB also determined that the average PFC in residential usage had a capacity of 2.34 gallons
and was refilled 6.4 times annually; the average PFC in commercial usage had a capacity of 3.4
gallons and was refilled 352 times annually.  Combining those survey results leads to the
estimates that each PFC in a residential unit represents, on average, 14.9 gallons of gasoline
annually, and each PFC in commercial unit represents 1,206.9 gallons of gasoline annually.

The analysis also provided ARB with an estimate of the number of PFCs per each residential
unit (1.8 per household) and per each commercial unit (6.9 per business).  Census data (of the
number of households and the number of businesses within California) were then used by ARB
to estimate the total number of PFCs within California.

The Ozone Transport Commission (through its contractor Pechan) modified ARB's methodology
to apply to Northeastern states. [3]  The New Jersey Department of Environmental Protection
then continued that approach to estimating emissions from PFCs in the state of New Jersey.[4]
2.0    EPA APPROACH

In this report, EPA proposes to modify ARB's proposed methodology in two ways. The first of
those modifications was how the number of PFCs (and the number of gallons of associated
gasoline) was estimated, and the second were revisions to those sources of emissions of HC
emissions.

2.1    Estimating Number of PFCs

Rather than assuming that the numbers of PFCs per household and per business were consistent
across the entire country, EPA used its non-road emissions model (NONROAD2005*) to
estimate the seasonal (nonroad) consumption of gasoline by source category classification (SCC)
code for each state plus the District of Columbia. Each SCC code has a unique usage
(commercial versus residential), a unique ratio of the percent of fuel dispensed from PFCs
(versus from fuel pumps), and a unique spillage rate (grams  per gallon). The spillage (from
PFCs) in the NONROAD2005 model is assumed to be a constant 17 grams for each refueling
event. Since the fuel tank capacity varies for different pieces of equipment, the spillage rate (in
terms of grams per gallon of dispensed gasoline) also varies greatly. (See Appendix A.)  Thus,
   The previous  draft version of this report (EPA420-D-06-003) was based on
   estimates from the draft  NONROAD2004  model.

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by combining those two outputs of NONROAD2005, EPA was able to estimate (by state) the
total quantity of gasoline supplied from PFCs as well as the total spillage (from using the PFCs
to refuel the individual pieces of equipment) for residential usage and for commercial usage.  For
example, running the NONROAD2005 model for calendar year 2005 produced the following
estimates (obtained by summing the individual state-by-state estimates):

                                         Table 2
         Estimate of Gallons of Gasoline Dispensed Nationwide by PFCs in 2005
Season
Winter 2005
Spring 2005
Summer 2005
Autumn 2005
Annual 2005
Residential
Usage (gallons)
107,369,000
281,789,000
456,122,000
281,374,000
1,126,653,000
Commercial
Usage (gallons)
303,321,000
553,932,000
742,357,000
551,282,000
2,150,892,000
Spillage at
Equipment (tons)
10,170
17,891
24,377
17,824
70,262
Using ARB's survey-based estimates of the total annual gallons of gasoline represented by each
PFC (14.9 gallons for PFCs in residential usage and 1,206.9 gallons for PFCs in commercial
usage), EPA estimated the number of PFCs in use. This method produced an estimate of
76,284,000 PFCs in use nationally which is close to industry estimates of 80.5 million PFCs.*
The fact that some PFCs are only used seasonally would increase that calculated number of
PFCs, bringing it even closer to that industry estimate. This suggests that this approach produces
estimates that are reasonable on an annual basis. To apply this approach to seasonal estimates,
we first had to distribute the estimated 6.4 annual refills (for the residential PFCs) on a seasonal
basis. Distributing those refills proportional to the gasoline used (Table 2) led to an estimated
average 0.6 refills each winter. Rounding that up to an even 1.0 and distributing the remaining
refills proportional to the remaining gasoline produced the values in Table 3. The seasonal
distribution of the refills of PFCs in  commercial usage (also given below in Table 3) was
estimated to be proportional to the distribution of the refills of PFCs in residential usage.
     The US Consumer Products Safety Commission estimated 80.5 million PFCs in use nationwide, and
     about 20 million additional PFCs are sold annually.[5] Assuming a slow growth rate in the national
     population of PFCs (e.g., the one percent rate estimated from the NONROAD model and illustrated
     in Figure 1), the average useful life of a PFC would have to be between four and five years.  That
     estimate of useful life is consistent with the estimates given in that memorandum (i.e., 3-5 years for
     plastic PFCs and 25 years for metal PFCs).

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                                        Table 3
                       Number of Refills for Each RFC by Season
Season
Winter
Spring
Summer
Autumn
Annual
Residential Usage
1.0000
1.4755
2.4000
1.4755
6.3510
Commercial Usage
55.4023
81.7468
132.9655
81.7468
351.8614
This distribution of refills predicts (for calendar year 2005) that approximately 47 million PFCs
would be in use during the three winter months and approximately 82 million would be in use
during each of the remaining nine months. EPA proposes to use this seasonal rate of refilling the
PFCs to estimate the season emissions associated with PFC usage.

2.2    Revising  Sources of HC Emissions

The second modification to ARB's proposed methodology was a revision to those sources of
emissions of HC emissions, by:

  -    including the emissions produced by displacing the vapor within the PFC and within the
       equipment when each is filled,
  -    including the spillage occurring when the PFC is filled at the pump, and
       adjusting the estimates of evaporation/diurnal  and permeation emissions to account for
       the fuel RVP and the ambient temperature (using the same approach used by EPA in its
       NONROAD2005 model [6]).

This modification  produced the following list of seven sources:
  •    Emissions  associated with filling the gas can (PFC)  at the gas pump
        (1)   Displacement of the vapor within the can
        (2)   Spillage of gasoline while filling the can
  •    Emissions  associated with transporting the gas can to the piece of nonroad equipment
        (3)   Spillage of gasoline during transport
  •    Emissions  associated with using the gas can to refuel the piece of nonroad equipment
       (These emissions are already accounted for in EPA's NONROAD model.)
        (4)   Displacement of the vapor within the nonroad equipment
        (5)   Spillage of gasoline while filling the nonroad equipment
  •    Emissions  (adjusted for changes in ambient temperature) associated with storage of the
       gasoline in the PFCs
        (6)   Emissions due to evaporation (i.e., diurnal emissions)
        (7)   Emissions due to permeation

Since (as noted above) the spillage and vapor displacement associated with using the PFCs to
refuel the pieces of nonroad equipment (i.e., items 4 and 5 in the above list) are already included

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in the estimates of EPA's NONROAD model; care should, therefore, be taken to avoid double
counting them in inventory estimates.

2.2.1  HC Emissions from Vapor Displacement

Each gallon of gasoline pumped into each PFC or poured into each piece of nonroad equipment
displaces the same volume of vapor. In EPA's NONROAD model (for equipment fueled using
PFCs),  the mass of that displaced vapor is a function of the ambient temperature (in degrees
Fahrenheit) and the Reid Vapor Pressure (RVP) of the fuel, specifically the mass of HC in the
vapor (in grams) displaced by each gallon of gasoline is given by the following formula:

                   exp(-1.2798 + 0.0203* Temperature + 0.1315*RVP)

Where  (ambient) temperature is in degrees Fahrenheit (between 40 and 95° F), and fuel RVP is
in pounds per square inch  (psi).  For ambient temperatures under 40° F, the temperature is
rounded up to 40° F in the formula. Similarly, for ambient temperatures over 95° F, the
temperature is rounded down to 95° F.

Since (as noted in Section 2.2) the vapor displaced from the individual non-road equipment is
already being estimated by EPA's NONROAD model, care must be taken not to double count
this quantity in inventory estimates.

2.2.2  HC Emissions from Spillage at Pump

In EPA's MOBILE6 model, spillage at the pump is estimated at 0.3128 grams per gallon
pumped into each on-road vehicle. EPA proposes to use this same estimate of spillage for each
gallon pumped into each PFC.

2.2.3  HC Emissions from Spillage During Transport

ARE determined that the spillage of gasoline during transport was dependent upon whether the
PFC was opened or closed. Specifically, ARB set the transport spillage at 23.0 grams/refill for
closed PFCs and at 32.5 grams/refill for opened PFCs. EPA proposes to use those same ARB
estimates in combination with ARB's survey estimates that, for residential usage, the average
PFC has a capacity of 2.34 gallons and, for commercial usage, the average PFC has a capacity of
3.43 gallons. Combining these ARB estimates leads to the following results:

                                      Table 3
                         Transport Spillage (grams / gallon)
              Residential
                Usage
             Commercial
                Usage
                                Closed PFCs
9.829
6.706
Open PFCs

  13.889
   9.475

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2.2.4  HC Emissions from Spillage During Refueling Non-Road Equipment
As described (in Section 2.1), EPA used its non-road emissions model (NONROAD2005) to
estimate the spillage (per gallon) for each piece of non-road equipment that is fueled using a
PFC.  Since this spillage for the individual non-road equipment is already being estimated by
EPA's NONROAD model, care must be taken not to double count this quantity in inventory
estimates.  If control measures such as automatic fuel shut-offs are used, this could reduce the
spillage rate to below what is currently assumed in the NONROAD model.

2.2.5   HC Emissions Due to Permeation

For closed PFCs, ARE estimated the daily permeation rates at 1.6 grams/gallon for plastic
containers and at 0.06 grams/gallon for metal containers.[2]  These estimates were based on
testing PFCs with an average fill level to be 49 percent. EPA modified ARB's permeation rate
for closed metal containers by assuming a rate of zero because fuel does not permeate through
metal. (For open PFCs, the quantity of evaporative emissions far exceeds the permeation; thus,
ARB simply used a combined value. See Section 2.2.6.)  Based on ARB's survey results that the
capacity of the typical PFC in residential use is 2.3 gallons and that the capacity of the typical
PFC in commercial use is 3.4 gallons, assuming  (as ARB did) the average fill level to be 49
percent, we estimated the average daily permeation for each type of container.  Those estimates
are given in Table 4.

                                       Table 4
                         Daily Permeation  (grams / container)
              Residential
                Usage
              Commercial
                Usage
                             Closed Plastic PFCs     Closed Metal* PFCs
1.80016
2.63870
             *  Although ARB estimated permeation from metal cans to be 0.06
               grams per gallon, EPA believes that a permeation rate (through a
               metal container) is more likely to be zero.

Testing has shown that the permeation rate is the same whether the PFC is completely filled with
liquid gasoline or with saturated vapor. Thus, the total permeation emission is a function of the
total number of PFCs (in use) rather than of the total amount of gasoline.

EPA has assumed (in its recent rule makings) that emissions due to permeation are a function of
ambient temperature, doubling approximately every 10 to 12 degrees Celsius (18 to 22 degrees
Fahrenheit). We developed an exponential temperature adjustment factor which when applied
(multiplicatively) to those permeation values allow modeling at various ambient temperatures.
The formula for that  adjustment factor is:

                          exp(0.0327 * (Temperature - 85.53))

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The temperature adjustment factors were calculated separately for each state and for each day of
the year and were then averaged to produce estimates for each state for each season of the year
(see Section 2.3).

2.2.6  HC Emissions Due to Evaporation/Diurnal

Diurnal (or evaporative) emissions result from fuel expansion and vapor production due to rising
temperatures during the day. ARB performed 24-hour diurnal testing (with temperatures cycling
between 65° and 105° F) on PFCs using a fuel with an RVP of 7.0 psi. For closed PFCs, ARB
estimated the average daily emissions (permeation plus diurnal) for plastic containers at 2.95
grams/gallon and for metal containers at 0.50 grams/gallon.[2] (As before, the average fill level
of the containers was 49 percent.)

Subtracting the estimated daily permeation rates (Section 2.2.5) produced these estimates of
daily diurnal emissions:

  •    Closed, plastic PFCs:  1.38 grams per gallon per day
  •    Closed, metal PFCs:   0.50 grams per gallon per day

For "open" containers (regardless of material or capacity), a single rate was calculated [2]:

  •    Open PFCs:         21.8 grams per day (per container)

Assuming an average daily fill level of 49 percent, we estimated daily diurnal emissions for each
in-use (closed) PFC to be:

                                        Table 5
                      Daily Diurnal Emissions  (grams /  container)

Residential
Usage
Commercial
Usage
Closed Plastic PFCs
1.6
2.3
Closed Metal* PFCs
0.6
0.8
EPA applied an adjustment factor to those values to estimate the diurnal emissions resulting
from daily temperature cycles different than the 65° to 105° F cycle test used to develop these
rates as well as from gasoline with different RVPs.  These temperature/RVP adjustment factors
were calculated separately for each state and for each day of the year and were then averaged to
produce estimates for each state for each season of the year (see Section 2.3). (Estimates of
future RVPs include the effects of the renewable fuel standards; see Section 3.3.)

2.3    Determining Ambient Temperatures

As noted in the previous section, the estimates of emissions (except for spillage) are dependent
upon the temperature of the fuel which is assumed to track the "ambient" temperature.  A
common approach to determining ambient temperatures is simply to use the outdoor

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temperatures which are readily available. However, some recent testing .[7] suggests that the
mean temperatures in garages (in which PFCs may be stored) can exceed the (mean) outdoor
daily temperatures by an average of 10 degrees Fahrenheit.* The differences between outdoor
and "ambient" temperatures are influenced by factors such as:

  •    Is a vehicle or a piece of (non-road) equipment with a hot engine stored in that enclosure?
  •    Where in that enclosure are the PFCs stored (i.e., on a cool floor, on a shelf, near a hot
       engine)?
  •    How frequently is the door of the enclosure opened (allowing an exchange of air with the
       outdoors)?  Similarly, is there a vent (or open window) in the enclosure?
  •    Is the enclosure shielded either from direct sunlight or from the cooling effects of wind?
       Similarly, is the enclosure insulated?

Further study would be necessary to precisely quantify the differences between outdoor
temperatures and the corresponding "typical" PFC storage temperatures.  The more the storage
(or ambient) temperature exceeds the outdoor temperature, the higher will be the estimated
inventory of VOC emissions from PFCs. EPA believes that half the difference observed in that
recent study (i.e., 5 degrees Fahrenheit) would be a reasonable estimate of that temperature
difference.

Therefore, EPA proposes (for the purpose of estimating PFC inventories) to estimate the daily
PFC storage temperatures by simply  adding 5 degrees Fahrenheit to the average (local) daily
temperatures. These adjusted temperatures will be used in these analyses.
3.0    RESULTS

3.1    Estimates of HC Emissions (Calendar Year 2005)

Using the NONROAD2005 model for calendar year 2005, we estimated (for each state for each
season, and for each SCC code) both the total gasoline dispensed by PFC and the total spillage
occurring when the PFCs were used to fuel the individual pieces of equipment.  Summarizing
those results nationwide (50 states plus the District of Columbia), we obtain the seasonal
estimates in Table 2 of Section 2.1.

By the 2005 calendar year, California had already implemented rules which would require the
PFCs to be designed in such a way as to reduce (probably eliminate) the likelihood of a PFC
being left in the "open" condition. Additionally, California's ARB  predicts that those changes
will also reduce both the spillage (occurring when refueling the equipment) by 60 percent as well
as the permeation rate (for the closed plastic PFCs) by 50 percent.  Our estimates for the 2005
calendar year assume that those rules have been in place long enough for all of the older PFCs to
be replaced by PFCs that meet the California requirements (see footnote on Page 3). (Note that
by eliminating the possibility that PFCs can be accidentally  left in the "open" condition, not only
     In a soon to be published report, two researchers from the Department of Environmental Health Sciences at
     the University of Michigan report that a study of at 15 residential garages in Michigan found that the
     temperatures in those garages averaged about five degrees Celsius warmer than outside air.

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are evaporative plus permeation emissions reduced but also spillage during transport is also
reduced.)

Using ARB's estimates of PFC distribution, we can use the estimates from Section 2.1 to
estimate PFC usages and then the associated PFC emissions. These estimates of the annual
inventory of HC emissions resulting from PFCs are summarized in Appendix B-2 on a state by
state basis.  A breakdown of nationwide annual emissions (in tons) for calendar year 2005 is
given in the Table 6. Fourteen (14) additional states plus the District of Columbia are planning
to adopt the California PFC requirements.  By 2010, we anticipate that all of the PFCs in those
states will also be compliant with the California rules.  We are incorporating that assumption into
our estimates for calendar years beyond 2005.

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                                        Table 6
             Breakdown of Annual (2005) Nationwide PFC Emissions (tons)



Residential Usage:
Permeation + Diurnal
Filling PFCs
- Spillage
- Vapor Displacement
Transport Spillage
Fueling Non-Road
Equipment*
- Spillage
- Vapor Displacement
Commercial Usaqe:
Permeation + Diurnal
Filling PFCs:
- Spillage
- Vapor Displacement
Transport Spillage
Fueling Non-Road
Equipment*
- Spillage
- Vapor Displacement
TOTALS
TOTALS Excluding Overlap*

Plastic
Closed

34,311

223
2,532
7,011

13,560
2,532

882

321
3,577
6,872

19,481
3,577
94,877
54,968

Plastic
Open

102,033

81
927
3,576

5,008
927

3,982

244
2,799
7,384

15,155
2,799
144,913
121,025
- PFC Tvnp
Metal
Closed

7,353

46
532
1,455

2,813
532

196

115
1,316
2,462

6,979
1,316
25,115
13,249

Metal
Open

48,798

39
443
1,710

2,395
443

1,021

62
718
1,893

3,886
718
62,127
54,685


Total

192,495

388
4,434
13,752

23,776
4,434

6,080

742
8,410
18,610

45,500
8,410
327,031
243,926
 * The NONROAD model (and hence local inventories) includes estimates of vapor displacement and
   spillage associated with refueling non-road equipment.  However, those NONROAD estimates do
   not exactly match the values in the above table since they do not take into account the California
   control measures.

From the preceding table, EPA estimates that the nationwide HC inventory resulting from PFCs
in 2005 to be 327,000 tons per year which is 244,000 tons above what is already being estimated
by EPA's NONROAD2005 model.
                                          10

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3.1.1   Sensitivity of Estimated VOC Emissions to Ratio of Open PFCs

These analyses are based on the distribution of PFCs found by ARB in their surveys. As shown
in Table 1, ARB estimated that 49 percent of the PFCs in commercial use and 34 percent of the
PFCs in residential use were stored in the open position. As the ratio of open PFCs changes, so
do the estimated total emissions.  In fact, redesigning the PFCs to make it difficult for them to be
stored in the open position is one strategy used to reduce VOC  emissions. For example, as the
ratio of all PFCs being open varies between 30 and 40 percent,  the estimated total VOC
emissions vary by plus or minus seven percent.
3.2    Estimates of HC Emissions (Calendar Year 1990)

Using EPA's NONROAD model, we repeated the preceding approach and obtained estimates of
gasoline consumed by non-road equipment (by state for each SCC code) for calendar year 1990
(instead of for 2005).  Assuming the same distribution of PFCs (i.e., open versus closed, plastic
versus metal), we obtained a national inventory of HC emissions from PFCs as 299,000 tons
(which is 222,000 tons above what is already being estimated by EPA's NONROAD2005 model
for 1990).

This suggests that the national inventory of HC emissions from PFCs increased by about nine
percent during the 15 years from 1990 to 2005. That growth rate in HC emissions appears small
because it is being offset by the effect of California adopting its PFC requirements. As
illustrated in Figure 1  (in the following section), without the effect of California (and later, 14
other states plus DC), the annual growth rate would be slightly over one percent.

3.3    Estimating Annual PFC  Emissions into the  Future

As noted in Section 3.1, EPA estimated the HC inventory resulting from PFCs for calendar year
2005 to be 327,000 tons per year. A substantial portion of those emissions are due to the fact
that many of the PFCs are left open by the users.  If the PFCs were redesigned so that neither the
vent nor the spout could be left "open" while being transported or stored, the resulting 2005
national inventory would decrease.  Additionally, if the PFCs were redesigned to  decrease
spillage by 50 percent, the reduction in HC emissions would be much greater.

Twelve states plus the District of Columbia (California, Connecticut, Delaware, Maine,
Maryland, New Hampshire, New Jersey, New York, Ohio, Pennsylvania, Texas, Virginia, and
Washington DC) already have or will implement controls on the design of PFCs that will reduce
HC emissions.  Additionally, three other states (Massachusetts, Rhode Island,  and Vermont) are
also planning to adopt the California PFC programs which are expected to reduce (for the
modified containers) spillage (while fueling the equipment) and permeation (each reduced by 50
percent) and reduce evaporation by  designing the PFCs so that they are not easily left open.

Additionally, California (alone among those 15 states) has adopted more stringent emission
standards that will require each PFC to emit (permeation plus evaporation) no more than 0.3
grams of VOC per day for each gallon of capacity. This requirement will be effective July 1,
                                         11

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2007. Assuming that gas cans have a typical life of about five years on average, the "new"
versions of the PFCs should replace virtually all of the earlier versions by 2013.

Assuming that those 15 states plus DC will have fully implemented their own controls and using
this methodology, we estimate that that the total annual nationwide HC emissions associated
with PFCs for 2015 would be 330,000 tons (which includes the "double counted" emissions from
the NONROAD2005).

Additionally, the renewable fuel standards (RFS) are expected to affect the RVP of the local
fuels which in turn would affect the estimates of evaporative emissions and vapor displacement.
These estimates of future RVP levels are incorporated in the estimates of VOC emissions for
future years.

Using this methodology repeatedly, we can obtain estimates of annual PFC emissions for two
basic scenarios, namely a base case (in which no PFC controls are implemented) and a case in
which 15 states plus DC implement California type requirements. Those two scenarios are
plotted in the following graph in which the base scenario is represented by  a dotted (black) line
and the 15-state control scenario (California beginning in 1999) is represented by a solid (blue)
line. The annual growth in the base scenario (about 1.2 percent annually) is being driven by the
increasing estimates of PFC related fuel consumption from the NONROAD model. [8]

                                       Figure 1
                         Comparison of PFC Control Scenarios
         Annual Nationwide VOC Emissions (Tons) from PFCs by Calendar Year
    500,000
    400,000
    300,000
    200,000
    100,000
                               ~ Base
                              — State Programs
          1990
2000
   2010
Calendar Year
2020
2030
                                          12

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4.0    REFERENCES

 1.     "Proposed Refueling Emission Inventory," by the California Air Resources Board,
       October 1998.

 2.     "Notice of Public Meeting to Consider the Approval of California's Portable Gasoline-
       Container Emissions Inventory" (Mail-Out MSC 99-25).

 3.     "Control Measure Development Support Analysis of Ozone Transport Commission
       Model Rules," prepared for Ozone Transport Commission (OTC) by E.H. Pechan &
       Associates, Inc., March 2001.

 4.     "Estimated VOC Emission Reductions and Economic Impact Analysis for Proposed
       Portable Fuel Containers Rule," by the State of New Jersey Department of Environmental
       Protection,  July 2003.

 5 .     "Market Information — Gasoline Cans," Memorandum from Terrance R. Karels (US
       Consumer Products Safety Commission) to Suzanne Barone,  January 3, 2003.

 6.     "Nonroad Evaporative Emission Rates," US EPA Number EPA420-R-05-020 (NR-007c),
       December 2005.  (Posted at: http://www.epa.gov/otaq/nonrdmdl.htm#techrept)

 7.     S. Batterman et al., "Concentrations and Emissions of Gasoline and Other Vapors from
       Residential Vehicle Garages," accepted for publication (November 1, 2005) in
       Atmospheric Environment. (Available online at: http://www.sciencedirect.com)

 8.     "Calculation of Age Distributions in the Nonroad Model — Growth and Scrappage," US
       EPA Number EPA420-R-05-018 (NR-007c), December 2005. (Posted at:
       http ://www. epa.gov/otaq/nonrdmdl. htm#techrept)
                                         13

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                Appendix A-1

Commercial  (Non-Road) Equipment Fueled Using PFCs
   By Source Category Classification (SCC)  Codes


Classification
Commercial
Equipment






Industrial Equipment





Lawn and Garden
Equipment















Logging Equipment
Recreational
Equipment


SCC
2260006005
2260006010
2260006015
2265006005
2265006010
2265006015
2265006025
2265006030
2260003030
2260003040
2265003010
2265003030
2265003040
2265003050
2260004016
2260004021
2260004026
2260004031
2260004071
226500401 1
2265004016
2265004026
2265004031
2265004036
2265004041
2265004046
2265004051
2265004056
2265004066
2265004071
2265004076
2260007005
2265001060



Equipment
Generator Sets
Pumps
Air Compressors
Generator Sets
Pumps
Air Compressors
Welders
Pressure Washers
Sweepers/Scrubbers
Other General Industrial Eqp
Aerial Lifts
Sweepers/Scrubbers
Other General Industrial Eqp
Other Material Handling Eqp
Rotary Tillers < 6 HP
Chain Saws < 6 HP
Trimmers/Edgers/Brush Cutter
Leafblowers/Vacuums
Commercial Turf Equipment
Lawn mowers
Rotary Tillers < 6 HP
Trimmers/Edgers/Brush Cutter
Leafblowers/Vacuums
Snowblowers
Rear Engine Riding Mowers
Front Mowers
Shredders < 6 HP
Lawn & Garden Tractors
Chippers/Stump Grinders
Commercial Turf Equipment
Other Lawn & Garden Eqp.
Chain Saws > 6 HP
Specialty Vehicles/Carts


2 vs4
Stroke
2
2
2
4
4
4
4
4
2
2
4
4
4
4
2
2
2
2
2
4
4
4
4
4
4
4
4
4
4
4
4
2
4

% of Fuel
From
PFCs
100%
98.459%
100%
52.297%
76.737%
57.208%
10.290%
77.253%
100%
100%
1 .587%
18.803%
63.058%
0.156%
100%
100%
1 00%
1 00%
100%
100%
100%
1 00%
1 00%
100%
100%
100%
1 00%
100%
1 00%
100%
100%
100%
0.021%


Spillage
(gr/gal)
21.250
21.250
15.455
7.275
12.798
8.437
11.333
12.448
26.123
16.308
5.862
4.375
6.741
11.111
56.667
122.324
85.000
24.286
6.800
42.500
56.667
85.000
24.286
24.286
6.954
6.987
54.839
6.526
1.478
3.290
5.141
62.408
4.722

                       14

-------
                     Appendix A-2

               Residential  (Non-Road) Equipment
By Source Category Classification (SCC) Codes Fueled Using PFCs
Classification
Lawn and Garden
Equipment






Pleasure Craft
Recreational
Equipment
SCC
2260004015
2260004020
2260004025
2260004030
2265004010
2265004015
2265004025
2265004030
2265004035
2265004040
2265004055
2265004075
2282005010
2282010005
2260001010
2260001030
2265001010
Equipment
Rotary Tillers < 6 HP
Chain Saws < 6 HP
Trimmers/Edgers/Brush Cutter
Leafblowers/Vacuums
Lawn mowers
Rotary Tillers < 6 HP
Trimmers/Edgers/Brush Cutter
Leafblowers/Vacuums
Snowblowers
Rear Engine Riding Mowers
Lawn & Garden Tractors
Other Lawn & Garden Eqp.
Outboard
Inboard/Sterndrive
Motorcycles: Off-Road
ATVs
Motorcycles: Off-Road
2 vs4
Stroke
2
2
2
2
4
4
4
4
4
4
4
4
2
4
2
2
4
% of Fuel
From
PFCs
100%
100%
1 00%
1 00%
100%
100%
1 00%
1 00%
100%
100%
100%
100%
5.001%
0.003%
100%
1 00%
100%
Spillage
(gr/gal)
56.667
201.422
85.000
24.286
42.500
56.667
85.000
24.286
24.286
6.953
6.526
5.155
5.963
7.194
6.538
6.538
6.538
                             15

-------
         Appendix B-1

RFC Emissions (Tons / Year) by Source
             (for 1990)
State

AL
AK
AZ
AR
CA
CO
CT
DE
DC
FL
GA
HI
ID
IL
IN
IA
KS
KY
LA
ME
MD
MA
Ml
MN
MS
MO
MT
NE
NV
NH
NJ
NM
NY
Refilling PFC
Vapor
Displacemen
t
224.8
24.8
279.1
105.7
1,532.1
202.7
123.2
36.6
7.6
933.1
390.9
58.1
50.6
405.1
241.4
99.6
93.5
129.1
168.9
40.7
226.0
199.0
316.9
181.4
97.0
212.6
26.4
55.0
123.4
44.1
332.9
58.0
517.1
at Pump
Spillage
15.0
1.9
22.9
8.5
133.9
18.9
12.0
3.1
0.7
72.5
32.4
4.0
4.9
36.3
19.8
8.3
8.5
11.1
12.1
4.3
21.1
19.1
29.6
15.5
7.4
19.0
2.6
5.2
10.6
4.5
30.0
5.2
47.5
Spillage
During
Transpor
t
447.1
60.1
647.9
262.7
3,760.8
536.5
342.7
89.1
25.0
2,055.5
930.8
112.9
146.3
1,058.5
578.2
248.5
247.9
340.2
370.7
130.7
597.8
556.1
886.3
463.1
230.6
560.9
81.9
154.0
295.8
131.0
857.4
155.6
1,414.3
Refueling E<
Vapor
Displacement

224.8
24.8
279.1
105.7
1,532.1
202.7
123.2
36.6
7.6
933.1
390.9
58.1
50.6
405.1
241.4
99.6
93.5
129.1
168.9
40.7
226.0
199.0
316.9
181.4
97.0
212.6
26.4
55.0
123.4
44.1
332.9
58.0
517.1
^uipment
Spillage
1,010.8
103.2
1,630.1
533.4
9,284.9
1,319.4
837.2
217.9
56.6
5,050.7
2,234.7
285.3
316.0
2,458.1
1,353.8
541.9
567.2
727.8
771.4
297.7
1,520.6
1,322.3
1,966.1
992.3
476.0
1,271.6
160.5
336.4
759.6
299.6
2,041.2
358.7
3,095.2
Permeation
Plus
Evaporation
4,286.7
776.6
3,936.1
2,813.4
19,682.1
2,137.2
1,422.5
514.9
235.1
14,664.5
5,918.5
1,208.2
780.1
5,764.9
3,914.8
1,886.4
1,457.6
2,914.7
5,178.9
620.4
2,528.1
2,561.3
5,253.7
3,281.1
2,997.4
3,427.2
506.1
911.4
1,362.6
572.4
4,049.9
1,050.8
8,473.6
               16

-------
   Appendix B-1  (Continued)

RFC Emissions (Tons / Year) by Source
            (for 1990)
State

NC
ND
OH
OK
OR
PA
Rl
SC
SD
TN
TX
UT
VT
VA
WA
WV
Wl
WY
50-
State
Refilling PFC
Vapor
Displacemen
t
407.9
17.2
507.3
139.6
133.8
419.5
28.3
207.8
20.9
237.0
875.0
70.8
18.7
309.8
225.6
65.4
166.3
14.8
11,403.3
at Pump
Spillage
31.5
1.8
41.1
12.1
12.8
38.5
2.7
15.1
2.0
18.6
67.6
6.7
1.9
27.6
20.5
5.4
16.4
1.5
972.1
Spillage
During
Transpor
t
911.8
54.1
1,188.5
352.5
373.6
1,132.0
80.8
438.3
62.1
553.4
1,954.5
201.4
57.6
786.6
595.1
170.6
488.5
48.1
28,226.3
Refueling E<
Vapor
Displacement

407.9
17.2
507.3
139.6
133.8
419.5
28.3
207.8
20.9
237.0
875.0
70.8
18.7
309.8
225.6
65.4
166.3
14.8
11,403.3
^uipment
Spillage
2,179.0
103.9
2,843.0
824.4
864.5
2,644.5
188.9
1,066.9
124.8
1,245.3
4,645.6
418.4
127.6
1,986.7
1,399.7
345.8
1,089.3
92.7
66,389.1
Permeation
Plus
Evaporation
6,950.0
302.1
7,500.9
2,322.6
1,889.7
6,498.5
422.5
3,981.0
398.1
4,944.1
15,730.9
1,208.1
296.3
3,853.6
3,174.0
1,700.5
2,512.5
265.7
181,040.0
               17

-------
         Appendix B-2

RFC Emissions (Tons / Year) by Source
            (for 2005)
State

AL
AK
AZ
AR
CA
CO
CT
DE
DC
FL
GA
HI
ID
IL
IN
IA
KS
KY
LA
ME
MD
MA
Ml
MN
MS
MO
MT
NE
NV
NH
NJ
NM
NY
Refilling PFC
Vapor
Displacemen
t
224.8
29.7
333.8
124.9
1,637.4
234.0
129.2
38.0
9.0
1,078.4
452.6
67.5
59.2
432.0
277.8
116.5
108.8
146.2
199.4
45.5
254.0
209.1
371.2
212.2
115.1
245.4
31.3
64.3
141.5
47.3
346.5
67.9
562.4
at Pump
Spillage
17.5
2.2
26.4
10.1
154.9
21.8
13.8
3.6
0.9
83.6
37.6
4.6
5.7
42.3
23.0
9.7
9.9
13.1
14.2
5.1
24.3
22.2
34.6
18.2
8.8
22.2
3.1
6.1
12.1
5.2
34.8
6.1
55.6
Spillage
During
Transpor
t
527.1
72.4
751.8
312.6
3,703.0
623.4
399.5
103.7
30.4
2,386.6
1,084.7
131.6
172.6
1,239.6
677.6
293.1
290.8
404.0
440.6
154.8
694.1
651.0
1,046.1
546.2
275.4
659.1
97.7
181.5
341.9
153.8
998.2
183.5
1,667.5
Refueling E<
Vapor
Displacement

224.8
29.7
333.8
124.9
1,637.4
234.0
129.2
38.0
9.0
1,078.4
452.6
67.5
59.2
432.0
277.8
116.5
108.8
146.2
199.4
45.5
254.0
209.1
371.2
212.2
115.1
245.4
31.3
64.3
141.5
47.3
346.5
67.9
562.4
^uipment
Spillage
1,069.0
109.1
1,723.4
564.2
8,870.9
1,395.9
885.9
230.3
59.9
5,340.5
2,363.2
302.9
334.4
2,600.8
1,432.1
573.4
600.3
770.0
815.9
315.0
1,608.9
1,399.0
2,079.8
1,049.9
503.5
1,345.2
169.8
355.9
803.0
317.0
2,160.2
379.5
3,275.4
Permeation
Plus
Evaporation
5,292.6
955.2
5,161.0
3,471.7
6,767.7
2,630.5
1,424.3
510.7
273.6
18,167.2
7,296.1
1,511.5
962.5
5,933.4
4,713.6
2,318.4
1,792.6
3,313.9
6,404.7
691.7
2,960.0
2,576.5
6,476.4
4,031.7
3,706.5
4,125.5
625.4
1,120.9
1,668.5
598.1
4,020.0
1,295.2
8,968.4
               18

-------
   Appendix B-2 (Continued)

RFC Emissions (Tons / Year) by Source
            (for 2005)
State

NC
ND
OH
OK
OR
PA
Rl
SC
SD
TN
TX
UT
VT
VA
WA
WV
Wl
WY
50-
State
Refilling PFC
Vapor
Displacemen
t
472.9
20.2
588.1
162.3
154.8
472.9
30.2
241.0
24.7
276.8
1,002.5
82.9
22.0
351.2
246.4
77.6
186.7
17.6
12,843.7
at Pump
Spillage
36.6
2.1
47.7
14.0
14.9
44.9
3.2
17.6
2.4
21.8
78.4
7.9
2.2
31.9
23.8
6.5
19.1
1.8
1,130.1
Spillage
During
Transpor
t
1,064.7
64.4
1,388.0
413.0
437.9
1,329.5
95.0
512.0
73.8
651.5
2,282.0
237.8
68.3
914.9
696.7
203.9
576.0
57.3
32,362.5
Refueling E<
Vapor
Displacement

472.9
20.2
588.1
162.3
154.8
472.9
30.2
241.0
24.7
276.8
1,002.5
82.9
22.0
351.2
246.4
77.6
186.7
17.6
12,843.7
^uipment
Spillage
2,303.8
109.9
3,007.6
871.7
914.8
2,798.4
199.9
1,128.1
132.1
1,316.9
4,912.3
442.7
135.1
2,101.4
1,481.0
365.9
1,152.4
98.1
69,276.1
Permeation
Plus
Evaporation
8,546.9
371.4
9,236.1
2,860.6
2,319.1
7,495.4
433.6
4,898.7
489.8
6,086.9
18,891.1
1,486.5
365.5
4,566.5
3,493.7
2,103.5
2,836.2
327.7
198,575.1
               19

-------
                                Appendix  C-1

               Response to Peer Review Comments from Sam Wells

This report was formally peer reviewed by two peer reviewers (Sam Wells and Sandeep Kishan).
In this appendix, comments from Sam Wells are reproduced in plain text, and EPA's responses
to those comments are interspersed in indented italics. Comments from the other peer reviewer
appear in the following appendix (Appendix C-2).

Peer Review of 'Estimating emissions associated with portable fuel containers (PFCs)'

Sam Wells
January 16, 2006


Introduction

Comments are offered on draft documentation of calculation used in 'Estimating emissions
associated with portable fuel containers (PFCs).  In general, the document is clear and concise,
making improvements upon previous work done by California Air Resources Board (ARB) and
others. Further, the proposed methodology is more complete, as it includes all possible modes of
hydrocarbon emissions from the gas pump to the non-road fuel tank, as opposed to ARB's single
focus upon the PFC.

Similar to other peer review comments I have submitted recently, the introduction appears
perhaps a little too concise and brief, with the first sentence mentioning an ARB study- without
an overview of the problem and why estimating PFC emissions are important to understand.
Also, the types of hydrocarbon emissions are grouped into seven (7) categories, but only six (6)
are discussed.  These are not fatal flaws but a little editing would make the document much more
readable.

       Two paragraphs have been added to the introduction to explain the importance of
       estimating emissions from PFCs.

Surveys

Realizing that the EPA is constrained as to obtaining consumer survey information, one could
make a case that the ARB survey was (a) a small, (b) old, and (c) perhaps geographically biased
towards northern and southern California and perhaps not representative the US.  These are
important considerations because the ARB survey findings indicated a very high incidence of
PFC stored in the "open" condition:

   •   Residential open - 34% (random survey = 1,500, response = 26%)
   •   Commercial open - 49% (nonrandom survey = 161, response = 94%)
                                         20

-------
These high frequencies have a disproportional impact on hydrocarbon emissions because these
PFC are freely vented to the atmosphere; thus small changes in the proportions could cause large
changes to the emissions inventory.

Therefore, I would recommend a future survey on a national basis to update these statistics and
the 1991 Outdoor Power Equipment Institute study used to provide NEVES and NONROAD
spillage and vapor displacement at the gasoline pump.  The EPA should consider funding such a
study if it considers regulation of PFC in the future or analysis of SIP credits; it is understood
that the current methodology used the "best current science."

       The reviewer is  correct that while this survey is the  "best current science, " it is
       very limited.  A  survey of a larger number of businesses and households over a
       larger geographic area (i.e.,  more than just one state) might produce somewhat
       different  inventory estimates.  However,  we performed several  supplemental
       analyses  in which we made relatively  large changes to the survey  ratios in
       Table 1,  and we found that the total estimated VOC inventory changed by less
       than 13 percent.  Therefore, EPA does not believe that such an undertaking would
       result in a significantly different estimate of the overall VOC inventory.


EPA Approach

Although the ARB survey had its limitations, the EPA application to seasonally and
geographically allocate PFC is considered to be good.  It was also beneficial to have estimates of
approximately 80 million PFC in the US so as to validate the estimates. A brief analysis of
residential and commercial landscaping equipment found in NONROAD appears to bolster this
contention, since those are the leading contributors in terms of PFC (indeed one could almost
call PFC the "lawnmower and weed whacker gas can inventory").

Revising Sources of HC Emissions

As mentioned previously,  this section includes seven hydrocarbon sources but only six are
mentioned. For document clarity perhaps vapor displacement at the pump should follow the
exact list as enumerated. Section 2.2.1 seems confusing because it related to both "each gallon
of gasoline pumped into each PFC or poured into each piece of nonroad equipment..." This
seems to assume that the displacement of a PFC and the gas tank on an engine are exactly the
same, which seems awkward at best, and the caveat to not double-count emissions raises even
more questions.  Please  clarify this double-counting issue as it is mentioned again in latter text.

       The goal of the analyses  in this report was to estimate all of the VOC emissions
       associated with  the use of PFCs.  When a PFC is filled at the gas pump, vapor
       (containing VOC) is displaced into the atmosphere.  Then, when that same PFC is
       used to refuel a piece of equipment, the vapor in the fuel tank of the piece of
       equipment is displaced. Thus, when one gallon of gasoline is pumped into a PFC,
       it displaces 231 cubic inches of vapor from the PFC, and a second 231 cubic
       inches (again) of vapor when it is pour from the PFC into the equipment. Thus,
       there are two vapor displacements occurring.  However, EPA 's NONROAD2004
       model already  includes that  second  vapor displacement in its estimates.
                                          21

-------
       Therefore, if an estimate of all VOC emissions associated with PFCs is needed,
       then both displacements need to be counted.  However, if an inventory of VOC
       emissions is being calculated and if that inventory already includes the estimates
      from the NONROAD2004 model, then that second vapor displacement should not
       be double counted.

Results

The ARB rule also adopted in similar form by other states is purported to reduce spillage (from
gas can to fuel tank) by up to 60 percent. This claim may be exaggerated or have unknown
effects because by the ARB's own admission there were some difficulties: 1

       Shortly after implementing the PFC regulations, consumers began to express complaints
       regarding spillage from the new PFCs.  Specifically, ARB staff received complaints
       expressing dissatisfaction with the design and functionality of the PFC's "spill-proof
       spouts. ARB staff researched these complaints and learned that while the regulations
       have been successful in reducing emissions from evaporation and permeation, emissions
       from spillage continued to occur. This is a direct result of the spout design.

Please verify the reductions if possible or state that "good engineering judgment" was used to
develop these reduction estimates, as the previous SIP reductions appear to be somewhat
tenuous.

       The reviewer  is correct that California's  original  approach  was not only
       unpopular with the consumers, but it was also not effective in controlling spillage.
       California reduced its estimates of spillage reduction down  to zero (i.e., their
       design change had no effect on spillage).  However, California has since revised
       its approach to spillage control, and they now believe that the current approach
       will reduce spillage by 60 percent. Since California's current approach is similar
       to the one that EPA plans to propose in its new (proposed)  rule,  EPA 's belief
       (based on its own "good engineering judgment") is that the design will reduce
       spillage by 50 to 60 percent.

Growth, Useful Life, and Scrappage

Sections 2.2, 3.1, and 3.3 rely on some rather "shaky" assumptions regarding growth, useful life,
and scrappage of PFC over time. One of the assumptions is that after four to five years, all the
plastic PFC will be replaced by new containers, some in areas having the ARB regulations.
These assumptions are based on NONROAD and an estimate that 20 million PFC (of 80 million)
are purchased each year. The question as to whether these old, "scrapped" PFC are indeed sent
to a hazardous or municipal solid waste landfill^ is an interesting one that can lead to some
conjecture - that perhaps not as many PFC are truly scrapped but are still emitting hydrocarbons
(diurnal and evaporative).  It could be that as families and businesses purchase new equipment,
1   ARB,  2005,   'Staff report:   Initial  statement  of reasons for proposed
amendments to  the portable  fuel container regulations,'  July 29, 2005
2   Most  Subtitle D landfills  will not  accept hazardous  materials  including
gasoline  and oil, including any red/orange container  (including medical
wastes)
                                          22

-------
many PFC could simply be added to the inventory.  This again would be subject to another
survey, which was recommended in previous sections, yet may be based in some logic.

   •   A cursory review of gas can exchange programs in various states and local regions
       indicated numbers in the thousands, not millions
   •   As families acquire more equipment, such as 2-stroke chain saws and personal
       watercraft, 1 more gas cans may be needed
   •   As landscaping companies^ expand, more PFC are required for additional crew trucks

In light of such perceived issues, one might recommend a statement saying that there is
considerable uncertainty as to the PFC scrappage rates, since one would think they would be
similar to the NONROAD scrappage curves but we simply do not have any hard data.

       The reviewer makes two distinct comments concerning scrappage of PFCs. The
       question as to whether the  disposal of PFCs is itself an environmental problem is
       beyond the scope of this study.  Those PFCs would be disposed of regardless of
      governmental actions to modify future PFCs.  Also, programs dealing with the
       disposal of those PFCs would not be under the control of EPA 's Office of Air.

      As to the estimates of the scrappage rate, EPA agrees with the reviewer that this
       estimated rate is subject to considerable uncertainty.  However, if we accept the
       estimate of the PFC manufacturers that there are approximately 80 million PFCs
       in use (in the USA), that this number is slowly rising, and that approximately 20
       million new PFCs are sold each year; then (as stated in the footnote on page 3)
       mathematically we must conclude that the typical PFC has to be replaced every
       three to five years.    Therefore, EPA will  continue  to use  this estimate  of
       scrappage rate.


Conclusion

The PFC document is very well presented; I have made a few minor suggestions. However, it
may be prudent to consider the level of uncertainty amongst the variables when documenting
emission inventory tools and resulting inventories. The math itself may be perfect and executed
with a high degree of precision, but accuracy may suffer as  a result of extrapolating large-scale
inferences from very small surveys. This appears to be the case with PFC. Since documents
such as this are often used as guidance or models for states,  locals, and consultants as boilerplate
to conduct emission inventories, perhaps a few sentences regarding use of special local surveys
would be a good idea.
1   Note  that personal watercraft are not  included  in  the list  of covered
equipment in Appendix A, but  are extensively used  in the expanding rental
market
2   This  may be counter-balanced by an  increase in  diesel mowers  and diesel
PFC are assumed to have zero  hydrocarbon emissions
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                                Appendix C-2

          Response to Peer Review Comments from  Michael Hutcheson

This report was formally peer reviewed by two peer reviewers (Sam Wells and Michael
Hutcheson).  In this appendix, comments from Michael Hutcheson are reproduced in plain text,
and EPA's responses to those comments are interspersed in indented italics.  Comments from the
other peer reviewer appear in the preceding appendix (Appendix C-l).


                      Peer Review Comments on the Draft Report
        "Estimating Emissions Associated with Portable Fuel Containers (PFCs)"
This document details comments from the peer review of the draft US EPA report on evaporative
emissions related to portable fuel container use in the following document:

          "Estimating Emissions Associated with Portable Fuel Containers (PFCs)"
                               dated November 18, 2005.

Comments are provided in general for the overall report and for each subject area including
population estimates, sources of emissions, ambient temperatures and results.

General Comments
In general the reviewer found the report confusing in some very important areas. The most
obvious of which is there is no stated purpose for the report. It appears that the estimates are
being made because ARB did some similar estimates and now is controlling PFC emissions. If
this is a guide for states to estimate PFC emissions or alternatively use these emission estimates
then that purpose should be stated. If these estimates are the basis of federal rule making, then
that purpose should be included.  The description of the CARB methodology should not be the
introduction but should be included in an analysis of existing data and methodologies.  The
introduction should start with a determination of purpose, history, etc.

       Two paragraphs have been added to the introduction to explain the importance of
       estimating emissions from PFCs.

The most confusing aspect is the allegiance of the report to its CARB counterpart to the point
that it the CARB estimates get confused with the EPA estimates. It is abundantly clear in
Section 2.2 as well as other sections that changes have been made to the CARB methodology.
Because of these changes, it would be more clear to the reader if sections described EPA's
methodology with reference to CARB data when used instead of reference to CARB's data and
methodology then EPA's changes to the methodology and data used. It is recommended that all
sections which begin with "ARB determined..." be reworded so that the reader is aware that
"EPA estimates ... based on the information from...".  It appears to the reviewer that the EPA
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attributes more weight to the CARB method than is due because of the numerous basic
adjustments EPA has made to the methodology to fit other states.

       The reviewer is  correct that EPA 's analysis relies greatly upon ARE's original,
       groundbreaking analysis.  EPA 's goals were slightly different from ARE's, thus,
       requiring some  modifications  to  ARB's  approach.   (ARE seems  primarily
       concerned with controlling the VOC emissions from PFCs as a means  to control
       ozone during the summer months. EPA similarly plans to use these estimates for
       control of summertime ozone on a nationwide basis.  However,  EPA  is also
       interested in the control  of  those VOCs  on an annual basis as a  means of
       controlling certain  toxic chemicals contained in the VOCs)  In this report, we
      found only one use  of the phrase "ARE determined ..." (Section 2.2.3), and in
       that instance EPA used exactly what ARE had determined (unmodified).

Population Estimates
The use of the NONROAD model for PFC estimates is an excellent integration of the
NONROAD model into these estimates.  It appears based on the comparison of the EPA estimate
of 76.284 million units to the industry estimate of 80.5 million units that the methodology is a
fair estimate. However, the reviewer fails to see how seasonal non-use of containers increases
the estimate of the number of containers when it is based on the total fuel consumed divided by
the average fuel consumed per container.  Furthermore, it is unclear why EPA revises the
seasonal estimates of fuel consumed when they are based on seasonal fuel consumption.
Revising the estimated number of winter refills upward from 0.6 to 1.0 creates a winter bias and
possibly underestimating emissions.

       The reviewer makes two distinct comments concerning the estimate of the number
       of PFCs First, the  estimate of 76.284 million PFCs in use was based on EPA 's
       estimate (from the NONROAD2004 model) of the number of gallons of gasoline
       being dispensed by PFCs However, if some PFCs are out of use for one or more
       seasons, then the total number of PFCs would be the sum of those in use plus the
       number of those not in use. Hence, assuming that some PFCs are used only part
       of the year would increase the total (estimated) number of PFCs.

       As to EPA 's decision to round up the number of refills during winter from 0.6 up
       to 1.0, EPA reasoned that PFCs  used for only one  season (i.e., winter) would be
       refilled at the beginning of that  season,  thus insuring at least one refill.  PFCs
       used for two or more season would likely require more than a single refill during
       the year; thus, suggesting (but not requiring) a refill during the winter.  PFCs not
       used during the winter would not be averaged in to determine the number of
       refills.  Thus, EPA  believes that  assuming (for only those residential PFCs used
       during the winter) that a refill rate of 1.0 was more reasonable than 0.6. Also,
       note that using  the 0.6 rate and distributing the remaining 0.4 refills over the
       remaining nine months results in an increase of VOCs during the summer months
       of only four percent.

It is also unclear to the reader if the seasonal estimates are nationwide or state by state. Because
the state by state description is lacking, it is assumed the state by state analysis was not
performed. It seems to the reviewer that  a state by state analysis of fuel consumption is
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appropriate because warmer states would have substantially higher summer consumption and
lower winter consumption than colder climates. This is because colder climates would have
additional snow and cold weather nonroad units to maintain. Therefore the reviewer
recommends that the seasonal fuel consumption estimates be made on a state by state basis.

       EPA used its NONROAD2004 model to estimate fuel consumption related to
       PFCs.  These fuel consumption estimates were made for each season and for each
       state.   Thus,  this component of EPA 's approach already  met  the reviewers
       suggestion.  A statement has been added to  the text  to the  effect that  the fuel
       consumption estimates (from Table 2) were calculated by adding the individual
       state-by-state estimates.

Sources of Emissions
The reviewer recommends that EPA eliminate the discussion of the changes to the CARB
methodology and limit the discussion to EPA's methodology and data sources. The description
of changes to methods only confuses the findings in the report as discussed above. Additional
discussion of individual sources of emissions are discussed below.

Vapor Displacement
The reviewer can not tell from the discussion of vapor displacement if EPA conducted separate
daily analyses for each state based on daily average temperatures or if the estimates made by
NONROAD for filling equipment are simply assumed equal to the vapor displacement during
filling of the PFC. Based on the  amount of transport spillage, permeation and diurnal emissions
and equipment refueling spillage, vapor displacement during filling of PFC's must be greater
than vapor displacement during fueling of non-road equipment.

       The reviewer is correct that because of gasoline lost to permeation, evaporation,
       and transport spillage the vapor displacement at  the time the PFC is filled is
       greater than the vapor  displacement when  the PFC is then used to fill the
       equipment.  However, that spillage estimates matches the  estimates from the
       NONROAD2004 model which are already included in the inventory.  Also, that
       difference is not only tiny compared to the total VOC emitted,  it is not affected by
       EPA 'sproposed rules.  Therefore, EPA will retain its current spillage estimate.

Spillage at the Pump
EPA errs by using the Mobile6 model spillage estimates as the basis for estimating spillage on  a
per gallon basis for one basic reason. Simply put, on-road vehicles have much larger tank
capacities than PFCs.  Testing by URS Corporation for Missouri refueling regulations shows that
spillage during refueling is independent of the amount of gasoline dispensed and is only
dependent on the number of fills. In other words, spillage is caused at the fuel pump by the act  of
removing the nozzle from the tank regardless of the amount of gasoline dispensed. On average,
each nozzle will spill approximately 1.5 grams of fuel  per refill, even if 1,000 gallons were
dispensed each time. Based on the average capacity of a container for residential  use, EPA
estimates less than 1 gram of spillage per refill and for commercial containers EPA estimates
approximately  1 gram of spillage per refill. Therefore on a per gallon  of fuel dispensed basis, the
reviewer believes the Mobile6 model underestimates spillage during refilling of PFC.
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       The reviewer is likely correct that EPA is underestimating the spillage occurring
       when the PFC is filled at the pump.  However, since that underestimation is small
       relative to the total VOC emitted and is not affected by EPA 's proposed rule, EPA
       will continue to use the estimates based on its MOBILE model.

Spillage during Transport
The reviewer believes the EPA methodology for estimating emissions from spillage during PFC
transport are incorrect and the CARB data underlying these estimates are incorrectly based.
Transport spillage should be directly proportional to number of gallons as well as distance
transported.  Commercial usage of portable fuel containers is necessary only to transport
gasoline to a piece of equipment where transport of the equipment to a central refueling location
is infeasible. Typically, these uses are predominantly related to transport of the container
between operational locations as in a commercial landscaping business. Because of the large
number of miles these containers must be transported in comparison to residential PFC usage, it
is beyond belief that spillage during transport for an open commercial PFC transported 50 miles
per refill would be less on a per gallon basis than for a residential closed PFC transported less
than 5 miles from the pump to the residence. For this reason, the reviewer recommends that
additional  consideration of the transport spillage estimates be made.

       The reviewer does not  disagree that the  estimates  EPA proposes  to  use to
       estimate spillage during transport are  "the best available " estimates; rather, he
       only suggests that those estimates might not be  "good enough. " EPA agrees with
       the reviewer that those estimates (from Table 3) could be improved. However, we
       do  not agree that those estimates  are too far from reality to be useful. As we  can
       see in Table 6, the current estimate of spillage during transport is actually less
       than six percent of the estimated total VOCs.  Therefore, even if we were to
       double the estimated spillage during transport,  we would be increasing the total
       inventory of VOCs from PFCs  by lest than six percent.  Since EPA believes that
       the assumptions underlying Table 3 are directionally correct  (i.e., spillage from
       open PFCs is greater than from closed PFCs) and since the sensitivity of the total
       inventory to the assumed spillage  rate is small, EPA will retain this approach.

Spillage during Refueling Non-road Equipment
The reviewer believes the NONROAD  estimates of spillage are appropriate for this analysis.

Permeation
The reviewer agrees the CARB estimates of permeation rates are appropriate to use, however, it
is not clear in this document if the CARB estimates are on a per gallon of fuel or per gallon of
capacity basis.  It appears that EPA has based their estimates assuming the CARB testing is
based on a per gallon of gasoline basis, however this is not immediately clear. If additional
testing has shown the permeation rate is independent of fill level, as stated, then any additional
testing relied upon should be referenced in this document and any analysis of permeation rate
included for comparison.

       EPA has used these factors to adjust both permeation and diurnal/evaporative
       emissions to reflect changes both in ambient temperatures and (for evaporation/
       diurnal emissions) infuelRVP.  Most recently these adjustment factors were used
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       in EPA 's NONROAD2005 model. We added a reference to EPA technical report
       NR-007c which documents these factors.

EPA does not clearly identify whether the permeation temperature adjustment factor is used for
these estimates or just previous rule makings.  It is presumed that the estimates tabulated in the
results section include temperature adjustment for permeation.  The reviewer agrees with the
temperature adjustment of permeation, however, it is not clear at what temperature the CARB
testing data was completed.  Since this would influence the adjustment factor, this data should be
provided in this report.

       As noted  in Section  2.2.6,  the ARE testing was performed (in a  variable
       temperature, diurnal SHED) with ambient temperatures cycling over a 40 degree
       Fahrenheit range (65° to 105° F).

Evaporation/Diurnal
EPA does not explain or identify the method used to determine the adjustment factor for diurnal
emissions.  These emissions are closely related to permeation emissions in closed containers as
illustrated by the CARB data but it is not clear if the same temperature adjustment factor is
appropriate. EPA needs to identify this adjustment factor for diurnal emissions and explain its
development.

       As previously noted, EPA  used  the same temperature adjustment factor that it
       used in its NONROAD2005 model.

Ambient Temperatures
The EPA makes a statement regarding temperature testing in PFC storage areas (garages) but
does not reference this testing. Any testing identified by EPA in this report should be adequately
referenced.

       Information and reference material regarding that testing program  have  been
       added.

The reviewer agrees with the EPA's method of adjusting ambient temperature for residential
units but believes that the 10 degree average increase based on testing is more appropriate than
the 5 degree increase used because it is based on testing. However, for commercial units which
are assumed to get almost daily refills, it is more appropriate to rely on true daily temperatures
than to make this correction as storage in a garage can not be presumed. Therefore separate
adjustments to temperature should be made for residential and commercial PFC emission
estimate calculations.
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