PB92-113117 Evaluation of Pilot ESP Performance with Elevated Loadings from Sorbent Injection Processes (U.S.) Environmental Protection Agency, Research Triangle Park, NC 4 Sep 91 J ------- PB92-113117 EPA/600/D-91/244 EVALUATION OF PILOT ESP PERFORMANCE WITH ELEVATED LOADINGS FROM SORBENT INJECTION PROCESSES Charles B. Sedman, Richard E. Valentine, and Norman Plaks U.S. Environmental Protection Agency Air and Enerqy Engineering Research Laboratory Research Triangle Park, NC 27711 ABSTRACT Measurements were made of calcium silicate sorbent (ADVACATE) injected into a duct to simulate injection into the duct upstream of an electrostatic precipitator (ESP). The concentration of ADVACATE sorbent submicron particles (particles S 1 Jim} and projected ESP emissions tended to peak and began to decrease when the overall particulate matter addition rate to the gas stream exceeded 12 g/Nm . The submicron fly ash, subjected to the same duct injection, increased linearly with increased injection rates from 3 to 24 g/Nm3, A possible explanation is in-duct agglomeration of fines by the coarse particles, similar to observations reported on cyclone performance evaluations. The duct, flue gas, and sorbent characteristics which affect agglomeration tendencies probably play a major role in the observations presented. The majority of the ADVACATE material settled out of the gas stream. Measurements of the gas-suspended residual particulate matter were used to model expected ESP performance. The results of the modeling are encouraging, and suggest that collection of reacted ADVACATE sorbent in an ESP is manageable. Future work will focus on identifying the process parameters that will ensure reliable and reproducible control in an ESP subjected to elevated sorbent loadings. ------- EVALUATION OF PILOT ESP PERFORMANCE WITH ELEVATED LOADINGS FROM SORBENT INJECTION PROCESSES INTRODUCTION As an integral part of EPA* s program to commercialize the ADV&CATE process for sulfur dioxide (802) removal, recent research has focused on the effect of elevated in-duct dust loadings Idue to advanced calcium silicate {ADVACATE) sorbent] on electrostatic precipitator (ESP) operation. A brief explanation of the ADVACATE process reveals the many parameters that may affect sorbent properties and ESP operation [1J. Figure 1 illustrates the ADVACATE Moist Dust Injection (MDI) process as proposed for the Shawnee 10 MW_ facility of TVA. In this scheme ADVACATE sorbent is prepared from the ESP first section dust capture where recycled dust is split into several fractions: (1) approximately one-third is slurried in a continuous stirred tank reactor (CSTR) with lime at elevated temperature to promote the production of high surface area calcium silicates,* (2) approximately two-thirds is directed to a mixer where it is blended with product slurry to form a high-moisture, free-flowing powder suitable for duct injection; and (3) the remainder is added to the bottoms from the remaining ESP sections and is handled/disposed of as a solid waste. ADVACATE sorbent is then injected into a flue gas at 150 °C and within half a second has simultaneously flash dried from the initial 40 to 50% moisture to about 5%, cooled the flue gas to about 65 °C, and removed a majority of the S02 and other acid gases present. This research effort currently focuses on: • ESP performance of ADVACATE vs. fly ash and fly ash/lime mixture under comparable conditions. • ESP performance of ADVACATE at elevated grain loadings. § Effect of sorbent surface moisture on ESP performance. • Effect of SO£ absorption upon ESP performance. § Effect of flue gas temperature and moisture upon ESP performance. § Effect of ADVACATE process parameters (e.g., degree of grinding, reaction tin" , storage, and mixing parameters} upon ESP performance. The program being developed to answer these questions has resulted in substantial renovation of EPA pilot facilities and purchase of new process equipment. Operatic.i ~»f these facilities in an integrated fashion will likely not commence -intil mid-1992. In the interim, a shorter-term program has been implemented in an attemot to determine which areas or parameters have a major impact on ESP pert: -1- nee. The remainder of this paper is devoted to results of this interim program, interpreting the results, and projecting incremental emissions increases due to ADVACATE sorbent injection on a commercial scale ESP application. ------- EPA currently operates a. 3400 ro^/h dry flue gas cleaning pilot plant which consists of a gas-fired heater, spray dryer, numerous dry sorbent injection/sampling ports, and three particulate matter collectors—pulse-jet and reverse-air fabric filters and a four-section ESP. It is planned to install ADVACATE sorbent preparation facilities and modify recycle dust capabilities to allow an integrated 0.7 MWe ADVACATE system to operate continuously by mid-1992. % In the interim, a second four-section ESP has been modified to examine the impact of ADVACATE sorbent upon ESP operation, and ADVACATE sorbent has been prepared in batches for short-term ESP operations. This ESP has previously been described in reports and technical papers and is briefly described herein [2J. It is a four-section unit that can be operated in a large number of configurations with regard to corona wires, wire-to-wire spacing, type of electrode, and type of energization. The ESP, which had been well characterized, had predictable performance that could be related to larger- scale ESPs. Table 1 contains the relevant parameters for all ESP operations data reported herein. The ESP was modified externally to allow high dust load operation as shown in Figure 2. As originally operated, particulate matter was aspirated into the ESP using modified sand blast guns. The maximum inlet grain loading with this arrangement was about 4.5 g/tn , which was insufficient for testing ADVACATE. To the existing 1700 m3/h facility, a sorbent injection system was added, including a blower, solids metering and feeding, and a 15 m long 10 cm l.D. duct. The added system was designed to deliver 340 nrYh of ambient air, resulting in a gas velocity of 15 m/s. This stream entered the ESP, in which the nominal flow velocity was 1.5 m/s, at the centerline, approximately 3 m upstream of the first ESP section. The entering stream first encountered a gas disperser cone followed by a coarse egg-crate set of flow straightening vanes. Considerable effort was made to ensure a flat profile, both vertical and horizontal, for gas velocity and temperature entering the first ESP section. Table 2 shows the velocity and temperature data through the ESP with the main blower and adjunct duct blower both in operation with no dust injection. Comparative tests were made with fly ash injected through the aspirators and the high velocity duct. With the sections energized, the performance, with aspirator injection, was similar to the historical data for the ESP. The same loading of fly ash injected through the duct gave performance that differed from historical data for the ESP, and from normal ESP operation. A possible reason for the aberrant ESP performance might be the propelling of particles down the centerline of the ESP by the high velocity stream. In view of the unusual ESP performance, the test program was altered to: {1} measure particle size distribution of dust exiting the ESP with all fields off, (2) measure total particle mass concurrent with particle size, and (3) model expected ESP performance based on these data. The remainder of this paper details results of this work. PARTICLE SIZE MEASUREMENTS An initial series of tests were run varying the ADVACATE injection rate from 150 to 1000 g/min {equivalent to approximately 3.9 to 26.3 g/Nm3 inlet ESP loading) to determine relative ESP effects. Sorbent was first prepared by slurrying pre-ground fly ash from the Meredosia Station of Central Illinois Public Service with Mississippi calcium hydroxide for 3 hours at 88 °C, then mixing the slurry with recycle ADVACATE solids for a product having 40-45% moisture content. The solids were then injected into the duct by a screw feeder under negative pressure at rates corresponding to 17.8 to 117.8 g/Nm^ in the duct with 1000 ppmv SC^. The partially reacted solids then entered the ESP and were diluted from 303.5 to 1370.9 Nnrvh by addition of heated air from the ESP blower, resulting in ESP loadings (not including added ------- sulfites and sulfates but deleting moisture evaporated) of 3.94 to 26.26 g/Nm . -{Although not measured directly, the maximum impact of SC^ absorption on the calculated ESP loading would be an 18% increase over the figures in Table 3, Column 2.) A series of measurements were made as shown in Table 3 where mass and particle size measurements were made simultaneously on the ESP outlet with the ESP turned off. The particle size measurements are in terms of the geometric mass mean diameter (GMMD) and the geometric standard deviation (GSD), The results in Table 3 show a definite trend in decreasing particle size scatter or a normalizing of particle size with increasing particle concentration. Further, a decided drop in particle size diameter is evident when the feed rate increased from "750 to 1000 g/mirv, concurrent with a decrease in effective ESP loading from 4.41 to 2,40 g/Nm3. Another way of looking at the data is to focus only on the submicron fraction of dust particles. The term submicron fraction denotes that portion of the particulate matter £ 1.0 jun. From the outlet loading and particle size data, the submicron fraction was calculated (Table 4), and shows that the submicron fraction, too, tended to decrease as loading increased. A second series of tests were conducted to determine the effect of using fresh sorbent instead of stored sorbent. For these tests Clinch River fly ash was slurried with lime and cycled through a Union Process 15-S attritor or vertical mill for 30 min. The slurry was then reacted for 2 h at 90 °C and mixed with spent ADVACATE sorbent to yield a 47% moisture solid, which was then fed immediately into the 15 m duct ESP entry. Results are shown in Tables 5 and 6. The contrast between results for old vs. fresh sorbent is significant. Table 5 shows that fresh sorbent is considerably larger in size, with substantially more scatter in particle size, as indicated by the larger standard deviations. The fresh sorbent particles also tended to grow with increased duct loading, and the ESP outlet loadings were generally much lower than for old sorbent, indicative of more settling out of sorbent in the ESP due to gravity. Table 6 shows that the submicron particle loading is only half that of old sorbent (shown in Table 4). The overall trends, however, in decreased fines as injection rate increases are consistent in both cases. An abbreviated test series of four runs were made with ADVACATE injection at a point 2 m upstream of the ESP inlet. The ESP outlet loadings in Table 7 are similar to those of the long duct runs, but fines contents are lower, by 50 to 70%. These runs were made at relatively low feed rates and cannot be compared to the higher rates where duct conditions tended to suppress fines. As shown in Table 7, the particle size distributions of fresh and old sorbent were dramatically different; however, the submicron loadings were similar, again lending credence to the fines content's being a function of handling rather than preparation. Long duct runs were made with fly ash as shown in Table 8. The mass particle loading and submicron particle loading both increased linearly with injection rate; with submicron loading, an order of magnitude higher than for ADVACATE (see Tables 4 and 6) at lower rates and two orders of magnitude higher at the highest rate, corresponding to about 25 g/Nm3 (11 gr/SCF). Figure 3 compares submicron particles entering the ESP as a function of injection rate for the ADVACATE tests and fly ash only. ESP MODELING With the ESP deenergized, particle size measurements and loadings were ------- measured in the sample port in the vertical outlet duct of the pilot ESP. This location was used because measurements taken in the relatively small cross section area are believed to be more representative than those made in the ESP casing itself. Particle size was measured with MRI 1 impactors. Particulate loading was measured using a modified EPA Method 5. It was assumed that the particulate matter in the vertical outlet duct, with the ESP deenergized, is the only particulate matter of concern to the ESP. From Table 5, the majority of the particulate matter introduced into the ESP falls out prior to reaching the vertical duct. The assumption was that the particles that settle out would do so regardless of whether or not the ESP was operating, and do not have to be included in the ESP performance computations. The ESP model used for the computer simulation is the new ESPVI Version 4.0, which is in its final stage of development by Research Triangle Institute and EPA. ESPVI Version 4.0 can compute V-I values for various electrode shapes, and then use the computed electrical conditions to predict ESP performance. Included among the attributes of this model is the ability to determine the effects of space charge on the ESP, and especially on the corona current. Determining the effects of space charge is essential when analyzing ESPs operating with high grain loads. ESPs of two sizes were modeled to illustrate a range of sizes that might be encountered in application of the ADVACATE process. The geometries for the two ESPs are given in Table 9. Also given are the gas conditions for baseline (149 °C> and ADVACATE (65 °C) operation. The final data presented in Table 9 are the non-ideal conditions (sneakage and rapping reentrainment) that were used for the modeling. The baseline was modeled assuming a fly ash particle size distribution defined by a GMMD of 15 jun and a GSD of 3. The emissions computed by the model, for the two ESPs, were placed on Figure 4, and connected by a line. Because there are only two points connected the line by necessity was straight, which is not meant to imply that there is a linear relationship between SCA and emissions. For the remaining plots the emissions for the two ESPs were modeled separately for fly ash and various ADVACATE solids loadings at 65 °C. Appropriate corrections were made to the SCA in going from 149 In 65 °C. The plots that represent the fly ash plus ADVACATE were obtained by summing the separate emissions for fly ash and ADVACATE. It should be noted that obtaining an emission for a composite substance such as fly ash plus ADVACATE, by summing separately computed emissions, is not a rigorous approach. The ESP electrical conditions are affected by the space charge, which, in turn, is established by the particle loading and size distribution J3]. Thus the electrical conditions for the individual particulate materials would not be the same as they would be for their sum. This tends to introduce a slight error in the emissions. However, for the particle concentrations for which the modeling is being done, the error is not significant. A further point noted is that the SCA increases when cooling from 149 to 65 "C. Therefore an SCA value on the baseline plot line is not equivalent to the SCA for the plot lines. The Fly Ash Plus ADVACATE Low plot on Figure 4 represents modeled ESP emissions for pilot data from the 1000 g/min injection rate test {Table 3), assuming that the particulate matter of concern to the ESP does not increase with increasing ADVACATE feed rate. This assumption is based on extrapolation of data in Figure 3 to approximately 80 g/Nm feed rates, discussed previously. The Fly Ash Plus ADVACATE High plot assumes that the particulate matter of concern to the ESP, contrary to the experimental findings, increases linearly with additional ADVACATE feed, or increases three-fold as feed rate is increased from 26 to 80 g/Nm5. The Fly Ash Plus ADVACATE No Duct plot is for ADVACATE injection directly into the ESP (no ------- duct residence time for agglomeration to occur) and is a worst-case approach. This assumption is magnified by the limited "no-duct" data at low ADVACATE injection rates, since the 6.57 g/Nm3 injection rate data were multiplied by 12 to approximate the expected commercial rate of approximately 80 g/Nm . For all the modeling simulations presented in Figure 4, the particle size distribution measured and repeated in Tables 3-1 was used. DISCUSSION OF RESULTS The obvious conclusions from the data are that (1) ADVACATE material generates less fines per unit mass than fly ash alone, and (2) some phenomenon is suppressing ADVACATE fines as the feed rate is increased. Since the ADVACATE material is prepared by solids' blending with slurry, the sorbent itself has only very coarse agglomerates, typically hundreds of micrometers in diameter. The questions are (I) do the agglomerates generate fines during flash .rying, and (2) what is the effect of preparation, handling, duct gc:..i *ry, and flue gas conditions on generated fines? Although the present work does not subject the sorbent to exact field conditions, an attempt has been made to bound the expected emissions created by drying and handling. Our current conclusion is that the small {10 cm) duct and ESP configuration is host to a new phenomenon which apparently mitigates the majority of fines from in-duct drying, mechanical forces, and perhaps fines inherent in the flue gas. This phenomenon has been previously observed in mechanical collector performance, Muschelknautz (4), Mothes and Loffler (5), and Hoffman, et al. 16] have reported the apparent improvement in cyclone performance with increased dust loading. Muschelknautz introduced the critical loading concept which proposes that a moving gas stream contains sufficient turbulent energy to support only a critical load of dust, and that any amount of dust exceeding this critical value will spontaneously fall out of the gas stream unclassified, or without respect to particle size, Mothes and Loffler explained the same observation as due to sweeping of the smaller particles to the cyclone wall by larger particles. Hoffman, et al, noted that the efficiency improvement of cyclones also increased with decreasing gas velocity; hence, their conclusions were that (1) the improvements were unrelated to the cyclone parameters, and (2) results were consistent with agglomeration at the cyclone inlet but an additional sweeping effect in the cyclone may explain the difference between model predictions and actual observations based on agglomeration alone. Considering the large quantities of ADVACATE material that will be injected into the gas stream, the modelling projections are encouraging. ESP operation is extremely sensitive to changes in inlet loading and particle size distribution 13] . Small changes to the particle size distribution of ADVACATE, again considering the large quantities being injected, provide a very high potential for profound changes in ESP performance. Variation in ADVACATE particle characteristics, from batch to batch, has been observed. An important component of future work on ADVACATE will be to determine the effects of improvements in S02 capture and modifications to the process on proper ESP operation. We cannot overemphasize the limited nature of data presented in Tables 3-8, however. Duct dimensions, gas velocities, moisture, and a host of other variables must be examined in future work before the practical significance of these observations is known. However, the conditions reported suggest a marked improvement in expected ESP performance at high inlet loadings that can be explained only by the sequestering and removal of Al VACATE fines in the duct and ESP transition section. Planned work in 1992 will expand these observations to higher and lower loadings, gas velocities, temperatures, moisture, and duct dimensions. In ------- addition to the question of general applicability, specific questions to be resolved are: (1) Will increased sorbent loading continue to show improved sequestering of fines? Is the upper limit strictly one of economics? (2) Will the increased sorbent load remove furnace-borne aerosols similarly to sorbent fines? Can overall {fly ash + sorbent) emissions be reduced to levels lower than for fly ash alone? (3) Will the current projection trends of ESP performance continue to hold? Will process development modifications of ADVACATE affect ESP performance? (4) Can ESP performance be improved by simple recycle of coarse ash from the first section's ESP bottoms? What will be the effects on SO2 capture? (5) How important is addition of hygroscopic materials (such as ADVACATE sorbent) in the above observations? (6) What process parameters are important in producing consistent ADVACATE material? CONCLUSIONS The large quantities of sorbent injected into the ESP by the ADVACATE process provide a potential for ESP problems. However it appears that addition of increasing loadings of hygroscopic sorbent material such as calcium silicates (ADVACATE sorbent) tends to suppress any fines generated by injection, drying, or mechanical process on the sorbent. The phenomenon is best explained by in-duct agglomeration of fines into larger particles. The measured quantity and size distribution of the ADVACATE particles that remain suspended in the gas stream, and would consequently be of importance to ESP operation, were modeled to provide a prediction of ESP performance. The results of the modeling were encouraging and suggest that particulate matter control for an ADVACATE retrofitted process is manageable. ------- REFERENCES Hall, B.W., Singer, C., Jozewicz, W.f Sedman, C.B., and Maxwell, M.A., Current status of ADVACATE process for flue gas desulfuri^^tion, presented at the 1991 AWMA Annual Meeting, Vancouver, B.C., Canada, June 20, 1991. Lawless, P.A., Daniel, B.E., and Ramsey, G.H., Characterization of the EPA/IERL-RTP pilot-scale precipitator, EPA-600/7-79-052 (NTIS PB 292820), February 1979. Plaks, N., The effects on electrostatic precipitation of changes in grain loading, size distribution, resistivity, and temperaturer presented at the Ninth Particulate Symposium, Williamsburg, VA, October 15-18, 1991. Muschelknautz, E., Die berechnung von zyklonabscheiden fur gase, Chemie-Ing-Techn, jT4 No.5, 1970. Mothes, H. and Loffler, F., "Motion and deposition of particles in cyclones," Ger. Chetn. Eng., 8., (1985). Hoffman, A.C.r Arends, H., and Sie, H., An experimental investigation elucidating the nature of the effects of solids loading on cyclone performance, Filtration and Separation, pp. 188-193, May-June 1991. ------- TO M/XEfl TO MIXER STACK DISPOSAL Figure 1. ADVACATE/MDI Process ------- N _J X I LU o S H2O O O O so Hf o SAMPLE PORTS \ JO. L4- o o o XL TO SCRUBBER MEZZANINE / SAMPLE PORTS FIELD 1 GAS BURNERS O O O FIELD 2 XL O O O FIELDS O O o FIELD 4 O O O od '77 Figure 2. EPA ESP Facility, Research Triangle Park, NC ------- CO E 0 O _j LU 0 DC Q_ O CC O 2 CO CO 0.35 0.3 0.25 0.2 0.15 0.1 0.05 n " > _ ; - »,•"* i A i ,•' - * .* ^ .• ^ _^ ' 4 e- _^fl- a". "O -i , , "rtJ 10 20 INJECTION RATE, g/Nm3 ADVACATE, fresh - ADVACATE, old • FLY ASH 30 Figure 3. Submicron Particle Mass Vs. Injection Rate ------- ^ s CO" o CO CO Ul 1UU 90 80 70 60 50 40 30 20 10 n ~" V \ \ \ \ \ \ \ \ \ \ \ \ \ '-•-,.. \ " "^^^•^•••...^ i t i "7*^* i , 20 40 60 SCA, m /m /s 60 FLY ASH FLY ASH+ADVACATE LOW FLY ASH+ADVACATE HIGH FLY ASH+ADV NO DUCT 100 Figure 4. Projected ESP Performance-ADVAGATE Process Impact ------- Table 1 PILOT ESP DESCRIPTION No. of Fields Plates per Field Plate Spacing, cm Effective Plate Area, m2 Hires per Field Hire Diameter, cm Hire Spacing, cm SCA , m2/m3/s At 23 cm plate spacing, 1.5 m/s gas velocity 4 2 22.9 1.5 5 0,32 22.9 28 Table 2 PILOT ESP GAS VELOCITY AND TEMPERATURE PROFILE AFTER MODIFICATION Top T, °C v, m/s Middle T, °C v, m/s Bottom T, °C v, m/s 154.4 1.64 154.4 1.89 153.5 1.12 Between Fields 1 & 2 151.7 1.48 148.3 1.74 152.8 1.26 Between Fields 263 149.4 1.61 150.6 1.74 149.4 1.35 Between Fields 3 & 4 148.9 1.65 147.8 1.61 147.8 1.20 ESP Outlet 147,8 1.28 148.9 1.93 137.8 1.28 13 ------- Table 3 PARTICLE SIZE ANALYSES WITH ESP OFF Outlet Duct Feed ESP Inlet, q/Nm-3 ESP Outlet, Rate, q/min Calculated Measured ESP Off, q/NmJ 150 3.94 3.69 2.04 500 13.13 8.94 3.80 750 19.70 12.14 4,41 1000 26.26 14.83 2.40 Table 4 Particle Size GMMD, Urn GSD 21.8 4.00 22.3 3.67 20.0 3.31 13.4 3,03 SUBMICRON PARTICLE BEHAVIOR VS. ADVACATE INJECTION RATE Outlet ADVACATE Injection Particle Loading Rate, a/min ESP Off, a/NmJ 150 2.04 500 3.80 750 4.41 1000 2.40 Table 5 FRESH SORBENT PARTICLE SIZE Duct Feed ESP Inlet, ESP Outlet, Rate, a/min Calculated, q/Nnr ESP Off, q/NmJ 150 3.94 0.878 300 7.88 1.060 750 19.70 0.534 1000 26.26 0.355 Submicron Particle Loading ESP Off, q/Nm3 0.0233 0.0315 0.0297 0.0240 Outlet Particle Size GMMD, urn GSD 65.6 6.77 63.1 6.10 81.4 12.15 112.3 15.35 14 ------- Table 6 SDBMICRON PARTICLE LOADING WITH FRESH SORBENT ADVACATE Injection Rate, q/min 150 300 750 1000 Outlet Particle Loading ESP Off,Q/Nmj 0,878 1.060 0.534 0.355 Submicron Particle Loading ESP Off. g/Nm3 0.014 0,013 0.021 0.012 Table 7 SHORT DUCT INJECTION OF ADVACATE AT 250 q/min ESP Outlet Particle Size, Particle Loading Sorbent Fresh Old GMMD, Urn 54.5 52.3 100.7 134.6 GSD 5.54 5.80 6.32 7.33 ESP Off, q/Nm-» 0.463 0.318 0.426 0.338 Submicron Particle Loading ESP Off, 0.0057 0.0053 0.0046 0.0039 Table 8 SUBMICRON PARTICLE BEHAVIOR VS. FLY ASH INJECTION RATE Fly Ash Injection Rate g/ndn Outlet Particle 75 (3.28) 150 (6.57) 300 (13.13) 550 (24.07) Outlet Particle Size Submicron Particle Loading o/NmJ 1.607 3.147 6.883 8.445 GMMD, ton 8.43 10.23 13.23 9.81 GSD 2.79 3.34 3.91 3.69 ESP Off, a/Nm3 0.0306 0.0881 0.2065 0.3378 15 ------- Table 9 ESP MODELED Small Large ESPGeometry Sections 3 5 Section Length, m 2.29 2."74 Height, m 9.14 9.14 Section Area, mz 2070 2484 Plate Spacing, m 0.229 0.229 Hire Spacing, m 0.229 0.229 Hire Diameter, mm 2.8 2.8 Wires per Lane 10 10 Lanes per Section 50 50 Gas Conditions High Temperature Case Temperature, °C 149 149 Volumetric Flow, actual nr/s 159.3 159.3 Velocity, m/s 1.52 1.52 SCA, mVm3/s 39.0 78.0 Low Temperature Case Temperature, °C 65 65 Volumetric Flow, actual m3/s 129.8 129.8 Velocity,,m/s 1.24 1.24 SCA, mVnrVs 47.9 95.8 Non-ideal Conditions [same for all) Sneakage 0.05 Rapping Fraction 0.06 Velocity Standard Deviation 0.15 16 ------- AEERL-P-855 TECHNICAL REPORT DATA (Pleatc read liulmctions on the rtrcttt before tomplel' 1. RE'ORT NO. EPA/600/D-91/Z44 PB92-113117 4. TITLE AND SUBTITLE Evaluation of Pilot ESP Performance with Elevated Loadings from Sorbent Injection Processes S. REPORT DATE G. PERFORMING ORGANIZATION CODE 1, AUTHORtSl Charles B. Sedman. Richard E. Valentine, and Norman Plaks 13. PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORGANIZATION NAME AND ADDRESS 1O, PROGRAM ELEMENT NO. See Block 12 11. CONTRACT/GRANT NO. NA (Inhouse) J2. SPONSORING AGENCY NAME A«D ADDRESS EPA, Office of Research and Development Air and Energy Engineering Research Laboratory Research Triangle Park. North Carolina 27711 13. TYPE OF REPORT AND PERIOD COVERED Published paper; 4~9/91 14, SPONSORING AGENCY CODE EPA/600/13 is.SUPPLEMENTARY NOTES AEERL project officer is Charles B. Sedman, Mail Drop 4, 919/ 541-7700. Presented at 9th Symposium on Participate Control, Williamsburg, VA, 10/15-19/91. 16.ABSTRACT^pj^g paper gives results of an evaluation of pilot electrostatic pi-ecipitalor (ESP) performance with elevated loadings from the advanced silicate (ADVACATE) sorbent injection process. Measurements were made of a calcium silicate sorbent injected into a duct upstream of an ESP. The concentration of ADVACATE sorbent submicron particles (=/< 1 micrometer) and projected ESP emissions tended to peak and began to decrease when the overall particulate matter addition rale to the gas stream approached and then exceeded 12 g/Nm3. The submicron fly ash, subjected to the same duct injection, increased linearly with increased injection rates from 3 to 24 g/Nm3. A possible explanation is in-duct agglomeration of fines by the coarse particles, similar to observations reported on cyclone performance evaluations. The duct, flue gas, and sorbent characteristics that affect agglomeration tendencies probably play a major role in the observations presented. Most of the ADVACATE material settled out of the gas stream. Measurements of the gas-suspended residual particulate matter were used to model expected ^SP performance. The encouraging results of the modeling suggest that collection of reacted ADVACATE sorbent in a ESP is manageable, c: 17. KEY WORDS AUO DOCUMENT ANALYSIS DESCRIPTORS b.lDENtlFIERS/OPEN ENDED TERMS Pollution Sulfur Dioxide Sorbents Calcium Silicates Flue Gases Particles Mathematical Models Electrostatic Precipi- tators Pollution Control Stationary Sources Sorbenl Injection ADVACATE Particulate c. COSATI Fkld/Gioup 13 B 07 B 11G 21B 14G 12 A 13J 19 DISIt IBUTtON SI A1LMFNT St 10 Public- is SC CORtTV CLARE f/ftl( I P.Cl.iSSl 71 NO Ol w ?O SLCumi V CLASS nrl- .--".sifiPif ------- |