PB92-113117
Evaluation of Pilot ESP Performance with Elevated
Loadings from Sorbent Injection Processes
(U.S.) Environmental Protection Agency, Research Triangle Park, NC
4 Sep 91
                                                                      J

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                                                         PB92-113117


                                                       EPA/600/D-91/244
                  EVALUATION OF PILOT ESP PERFORMANCE WITH
             ELEVATED LOADINGS FROM SORBENT INJECTION PROCESSES

                             Charles B. Sedman,

                            Richard E.  Valentine,

                                     and

                                Norman Plaks

                    U.S. Environmental Protection Agency
               Air and Enerqy Engineering Research Laboratory
                      Research Triangle Park,  NC  27711
ABSTRACT
Measurements were made of calcium silicate sorbent (ADVACATE)  injected into
a duct to simulate injection into the duct upstream of an electrostatic
precipitator (ESP).  The concentration of ADVACATE sorbent submicron
particles (particles S 1 Jim} and projected ESP emissions tended to peak and
began to decrease when the overall particulate matter addition rate to the
gas stream exceeded 12 g/Nm .  The submicron fly ash, subjected to the same
duct injection, increased linearly with increased injection rates from 3 to
24 g/Nm3,  A possible explanation is in-duct agglomeration of fines by the
coarse particles, similar to observations reported on cyclone performance
evaluations.  The duct, flue gas, and sorbent characteristics which affect
agglomeration tendencies probably play a major role in the observations
presented. The majority of the ADVACATE material settled out of the gas
stream. Measurements of the gas-suspended residual particulate matter were
used to model expected ESP performance.  The results of the modeling are
encouraging, and suggest that collection of reacted ADVACATE sorbent in an
ESP is manageable.  Future work will focus on identifying the process
parameters that will ensure reliable and reproducible control in an ESP
subjected to elevated sorbent loadings.

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                  EVALUATION OF  PILOT  ESP PERFORMANCE WITH
             ELEVATED  LOADINGS FROM SORBENT  INJECTION PROCESSES


INTRODUCTION

As an integral part of EPA* s program to commercialize the ADV&CATE process
for sulfur dioxide  (802)  removal,  recent research has focused on the effect
of elevated in-duct dust  loadings  Idue to advanced calcium silicate
{ADVACATE) sorbent] on electrostatic precipitator (ESP) operation.  A brief
explanation of the ADVACATE process reveals  the many parameters that may
affect sorbent properties and ESP  operation  [1J.

Figure 1 illustrates the  ADVACATE  Moist Dust Injection  (MDI) process as
proposed for the Shawnee  10 MW_  facility of  TVA.  In this scheme ADVACATE
sorbent is prepared from  the ESP first section dust capture where recycled
dust is split into several  fractions:  (1) approximately one-third is
slurried in a continuous  stirred tank  reactor  (CSTR) with lime at elevated
temperature to promote the  production  of high surface area calcium
silicates,* (2) approximately two-thirds is directed to  a mixer where it is
blended with product slurry to form a  high-moisture, free-flowing powder
suitable for duct injection;  and (3) the remainder is added to the bottoms
from the remaining ESP sections  and is handled/disposed of as a solid waste.

ADVACATE sorbent is then  injected  into a flue gas at 150 °C  and within half
a second has simultaneously flash  dried from the initial 40 to 50% moisture
to about 5%, cooled the flue gas to about 65 °C, and removed a majority of
the S02 and other acid gases present.

This research effort currently focuses on:

     •     ESP performance  of ADVACATE vs.  fly ash and fly ash/lime
           mixture under  comparable conditions.

     •     ESP performance of ADVACATE at elevated grain loadings.

     §     Effect of sorbent  surface moisture on ESP performance.

     •     Effect of SO£  absorption upon ESP performance.

     §     Effect of flue gas temperature and moisture upon ESP
           performance.

     §     Effect of ADVACATE process parameters (e.g.,  degree of
           grinding, reaction tin"  , storage,  and mixing parameters}
           upon ESP performance.

The program being developed  to answer  these questions has resulted in
substantial renovation of EPA pilot facilities and purchase of new process
equipment.  Operatic.i  ~»f  these facilities in an integrated fashion will
likely not commence -intil mid-1992.  In the  interim,  a shorter-term program
has been implemented in an attemot to determine which areas or parameters
have a major impact on ESP pert:  -1- nee.  The remainder of this paper is
devoted to results of  this  interim program,   interpreting the results,  and
projecting incremental emissions increases due to ADVACATE sorbent injection
on a commercial scale  ESP application.

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EPA currently operates a. 3400 ro^/h dry flue gas cleaning pilot plant which
consists of a gas-fired heater, spray dryer, numerous dry sorbent
injection/sampling ports, and three particulate matter collectors—pulse-jet
and reverse-air fabric filters and a four-section ESP.  It is planned to
install ADVACATE sorbent preparation facilities and modify recycle dust
capabilities to allow an integrated 0.7 MWe ADVACATE system to operate
continuously by mid-1992.
           %

In the interim, a second four-section ESP has been modified to examine the
impact of ADVACATE sorbent upon ESP operation, and ADVACATE sorbent has been
prepared in batches for short-term ESP operations.  This ESP has previously
been described in reports and technical papers and is briefly described
herein [2J.  It is a four-section unit that can be operated in a large
number of configurations with regard to corona wires, wire-to-wire spacing,
type of electrode, and type of energization.  The ESP, which had been well
characterized, had predictable performance that could be related to larger-
scale ESPs.  Table 1 contains the relevant parameters for all ESP operations
data reported herein.

The ESP was modified externally to allow high dust load operation as shown
in Figure 2.  As originally operated, particulate matter was aspirated into
the ESP using modified sand blast guns.  The maximum inlet grain loading
with this arrangement was about 4.5 g/tn , which was insufficient for testing
ADVACATE.  To the existing 1700 m3/h facility, a sorbent injection system
was added, including a blower, solids metering and feeding,  and a 15 m long
10 cm l.D. duct.  The added system was designed to deliver 340 nrYh of
ambient air, resulting in a gas velocity of 15 m/s.  This stream entered the
ESP, in which the nominal flow velocity was 1.5 m/s,  at the centerline,
approximately 3 m upstream of the first ESP section.   The entering stream
first encountered a gas disperser cone followed by a coarse egg-crate set of
flow straightening vanes.  Considerable effort was made to ensure a flat
profile,  both vertical and horizontal, for gas velocity and temperature
entering the first ESP section.  Table 2 shows the velocity and temperature
data through the ESP with the main blower and adjunct duct blower both in
operation with no dust injection.

Comparative tests were made with fly ash injected through the aspirators and
the high velocity duct.  With the sections energized, the performance,  with
aspirator injection, was similar to the historical data for the ESP.  The
same loading of fly ash injected through the duct gave performance that
differed from historical data for the ESP, and from normal ESP operation.  A
possible reason for the aberrant ESP performance might be the propelling of
particles down the centerline of the ESP by the high velocity stream.

In view of the unusual ESP performance, the test program was altered to:
{1} measure particle size distribution of dust exiting the ESP with all
fields off, (2) measure total particle mass concurrent with particle size,
and (3)  model expected ESP performance based on these data.   The remainder
of this paper details results of this work.


PARTICLE SIZE MEASUREMENTS

An initial series of tests were run varying the ADVACATE injection rate from
150 to 1000 g/min {equivalent to approximately 3.9 to 26.3 g/Nm3 inlet  ESP
loading)  to determine relative ESP effects.  Sorbent  was first prepared by
slurrying pre-ground fly ash from the Meredosia Station of Central Illinois
Public Service with Mississippi calcium hydroxide for 3 hours at 88 °C,  then
mixing the slurry with recycle ADVACATE solids for a  product having 40-45%
moisture content.  The solids were then injected into the duct by a screw
feeder under negative pressure at rates corresponding to 17.8 to 117.8  g/Nm^
in the duct with 1000 ppmv SC^.  The partially reacted solids then entered
the ESP and were diluted from 303.5 to 1370.9 Nnrvh by addition of heated
air from the ESP blower,  resulting in ESP loadings (not including added

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sulfites and sulfates but deleting moisture evaporated) of 3.94  to 26.26
g/Nm .  -{Although not measured directly, the maximum impact of SC^
absorption on the calculated ESP loading would be an 18% increase over the
figures in Table 3, Column 2.)

A series of measurements were made as shown in Table 3 where mass and
particle size measurements were made simultaneously on the ESP outlet with
the ESP turned off.  The particle size measurements are in terms of the
geometric mass mean diameter  (GMMD) and the geometric standard deviation
(GSD),  The results in Table 3 show a definite trend in decreasing particle
size scatter or a normalizing of particle size with increasing particle
concentration.  Further, a decided drop in particle size diameter is evident
when the feed rate increased from "750 to 1000 g/mirv, concurrent with a
decrease in effective ESP loading from 4.41 to 2,40 g/Nm3.

Another way of looking at the data is to focus only on the submicron
fraction of dust particles.  The term submicron fraction denotes that
portion of the particulate matter £ 1.0 jun.  From the outlet loading and
particle size data, the submicron fraction was calculated (Table 4), and
shows that the submicron fraction, too, tended to decrease as loading
increased.

A second series of tests were conducted to determine the effect of using
fresh sorbent instead of stored sorbent.  For these tests Clinch River fly
ash was slurried with lime and cycled through a Union Process 15-S attritor
or vertical mill for 30 min.  The slurry was then reacted for 2 h at 90 °C
and mixed with spent ADVACATE sorbent to yield a 47% moisture solid, which
was then fed immediately into the 15 m duct ESP entry.  Results are shown in
Tables 5 and 6.

The contrast between results for old vs. fresh sorbent is significant.
Table 5 shows that fresh sorbent is considerably larger in size, with
substantially more scatter in particle size, as indicated by the larger
standard deviations.  The fresh sorbent particles also tended to grow with
increased duct loading, and the ESP outlet loadings were generally much
lower than for old sorbent, indicative of more settling out of sorbent in
the ESP due to gravity.  Table 6 shows that the submicron particle loading
is only half that of old sorbent (shown in Table 4).

The overall trends, however, in decreased fines as injection rate increases
are consistent in both cases.

An abbreviated test series of four runs were made with ADVACATE injection at
a point 2 m upstream of the ESP inlet.  The ESP outlet loadings in Table 7
are similar to those of the long duct runs, but fines contents are lower,  by
50 to 70%.  These runs were made at relatively low feed rates and cannot be
compared to the higher rates where duct conditions tended to suppress fines.
As shown in Table 7, the particle size distributions of fresh and old
sorbent were dramatically different; however,  the submicron loadings were
similar, again lending credence to the fines content's being a function of
handling rather than preparation.

Long duct runs were made with fly ash as shown in Table 8.  The mass
particle loading and submicron particle loading both increased linearly with
injection rate; with submicron loading, an order of magnitude higher than
for ADVACATE (see Tables 4 and 6) at lower rates and two orders of magnitude
higher at the highest rate, corresponding to about 25 g/Nm3 (11 gr/SCF).
Figure 3 compares submicron particles entering the ESP as a function of
injection rate for the ADVACATE tests and fly ash only.


ESP MODELING

With the ESP deenergized, particle size measurements and loadings were

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measured in the sample port in the vertical outlet duct of the pilot ESP.
This location was used because measurements taken in the relatively small
cross section area are believed to be more representative than those made in
the ESP casing itself.  Particle size was measured with MRI 1 impactors.
Particulate loading was measured using a modified EPA Method 5.

It was assumed that the particulate matter in the vertical outlet duct, with
the ESP deenergized, is the only particulate matter of concern to the ESP.
From Table 5, the majority of the particulate matter introduced into the ESP
falls out prior to reaching the vertical duct.  The assumption was that the
particles that settle out would do so regardless of whether or not the ESP
was operating, and do not have to be included in the ESP performance
computations.

The ESP model used for the computer simulation is the new ESPVI Version 4.0,
which is in its final stage of development by Research Triangle Institute
and EPA.  ESPVI Version 4.0 can compute V-I values for various electrode
shapes, and then use the computed electrical conditions to predict ESP
performance.  Included among the attributes of this model is the ability to
determine the effects of space charge on the ESP, and especially on the
corona current.  Determining the effects of space charge is essential when
analyzing ESPs operating with high grain loads.

ESPs of two sizes were modeled to illustrate a range of sizes that might be
encountered in application of the ADVACATE process.  The geometries for the
two ESPs are given in Table 9.  Also given are the gas conditions for
baseline (149 °C> and ADVACATE  (65 °C) operation.  The final data presented
in Table 9 are the non-ideal conditions (sneakage and rapping reentrainment)
that were used for the modeling.

The baseline was modeled assuming a fly ash particle size distribution
defined by a GMMD of 15 jun and a GSD of 3.  The emissions computed by the
model, for the two ESPs, were placed on Figure 4, and connected by a line.
Because there are only two points connected the line by necessity was
straight, which is not meant to imply that there is a linear relationship
between SCA and emissions.

For the remaining plots the emissions for the two ESPs were modeled
separately for fly ash and various ADVACATE solids loadings at 65 °C.
Appropriate corrections were made to the SCA in going from 149 In 65 °C.
The plots that represent the fly ash plus ADVACATE were obtained by summing
the separate emissions for fly ash and ADVACATE.  It should be noted that
obtaining an emission for a composite substance such as fly ash plus
ADVACATE, by summing separately computed emissions, is not a rigorous
approach.  The ESP electrical conditions are affected by the space charge,
which, in turn, is established by the particle loading and size distribution
J3].  Thus the electrical conditions for the individual particulate
materials would not be the same as they would be for their sum.  This tends
to introduce a slight error in the emissions.  However, for the particle
concentrations for which the modeling is being done, the error is not
significant.  A further point noted is that the SCA increases when cooling
from 149 to 65 "C.  Therefore an SCA value on the baseline plot line is not
equivalent to the SCA for the plot lines.

The Fly Ash Plus ADVACATE Low plot on Figure 4 represents modeled ESP
emissions for pilot data from the 1000 g/min injection rate test {Table 3),
assuming that the particulate matter of concern to the ESP does not increase
with increasing ADVACATE feed rate.  This assumption is based on
extrapolation of data in Figure 3 to approximately 80 g/Nm  feed rates,
discussed previously.  The Fly Ash Plus ADVACATE High plot assumes that the
particulate matter of concern to the ESP,  contrary to the experimental
findings, increases linearly with additional ADVACATE feed, or increases
three-fold as feed rate is increased from 26 to 80 g/Nm5.  The Fly Ash Plus
ADVACATE No Duct plot is for ADVACATE injection directly into the ESP  (no

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duct residence time for agglomeration to occur) and is a worst-case
approach.  This assumption  is magnified by the limited "no-duct" data at low
ADVACATE injection rates, since  the  6.57 g/Nm3 injection rate data were
multiplied by 12 to approximate  the  expected commercial rate of
approximately 80 g/Nm  .   For all the modeling simulations presented in
Figure 4, the particle size distribution measured and repeated in Tables 3-1
was used.


DISCUSSION OF RESULTS

The obvious conclusions from the data are that  (1) ADVACATE material
generates less fines per  unit mass than fly ash alone, and  (2) some
phenomenon is suppressing ADVACATE fines as the feed rate is increased.
Since the ADVACATE material is prepared by solids' blending with slurry, the
sorbent itself has only very coarse  agglomerates, typically hundreds of
micrometers in diameter.  The questions are  (I) do the agglomerates generate
fines during flash  .rying,  and  (2) what is the effect of preparation,
handling, duct gc:..i *ry,  and flue gas conditions on generated fines?
Although the present work does not subject the sorbent to exact field
conditions, an attempt has  been  made to bound the expected emissions created
by drying and handling.   Our current conclusion is that the small {10 cm)
duct and ESP configuration  is host to a new phenomenon which apparently
mitigates the majority of fines  from in-duct drying, mechanical forces, and
perhaps fines inherent in the flue gas.

This phenomenon has been  previously  observed in mechanical collector
performance,  Muschelknautz (4),  Mothes and Loffler (5), and Hoffman, et al.
16] have reported the apparent improvement in cyclone performance with
increased dust loading.   Muschelknautz introduced the critical loading
concept which proposes that a moving gas stream contains sufficient
turbulent energy to support only a critical load of dust, and that any
amount of dust exceeding  this critical value will spontaneously fall out of
the gas stream unclassified, or  without respect to particle size,  Mothes
and Loffler explained the same observation as due to sweeping of the smaller
particles to the cyclone  wall by larger particles.  Hoffman, et al, noted
that the efficiency improvement  of cyclones also increased with decreasing
gas velocity; hence, their  conclusions were that  (1) the improvements were
unrelated to the cyclone  parameters, and (2) results were consistent with
agglomeration at the cyclone inlet but an additional sweeping effect in the
cyclone may explain the difference between model predictions and actual
observations based on agglomeration  alone.

Considering the large quantities of  ADVACATE material that will be injected
into the gas stream, the  modelling projections are encouraging.  ESP
operation is extremely sensitive to  changes in inlet loading and particle
size distribution 13] .  Small changes to the particle size distribution of
ADVACATE, again considering the  large quantities being injected,  provide a
very high potential for profound changes in ESP performance.  Variation in
ADVACATE particle characteristics, from batch to batch,  has been observed.
An important component of future work on ADVACATE will be to determine the
effects of improvements in  S02 capture and modifications to the process on
proper ESP operation.

We cannot overemphasize the limited  nature of data presented in Tables 3-8,
however.  Duct dimensions,  gas velocities,  moisture, and a host of other
variables must be examined  in future work before the practical significance
of these observations is  known.   However, the conditions reported suggest a
marked improvement in expected ESP performance at high inlet loadings that
can be explained only by  the sequestering and removal of Al VACATE fines in
the duct and ESP transition section.

Planned work in 1992 will expand these observations to higher and lower
loadings, gas velocities,  temperatures,  moisture,  and duct dimensions.  In

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addition to the question of general applicability, specific questions to be
resolved are:

      (1)   Will increased sorbent loading continue to show improved
           sequestering of fines?  Is the upper limit strictly one of
           economics?

      (2)   Will the increased sorbent load remove furnace-borne aerosols
           similarly to sorbent fines?  Can overall {fly ash + sorbent)
           emissions be reduced to levels lower than for fly ash alone?

      (3)   Will the current projection trends of ESP performance
           continue to hold?  Will process development modifications
           of ADVACATE affect ESP performance?

      (4)   Can ESP performance be improved by simple recycle of coarse ash
           from the first section's ESP bottoms?  What will be the effects
           on SO2 capture?

      (5)   How important is addition of hygroscopic materials (such as
           ADVACATE sorbent) in the above observations?

      (6)   What process parameters are important in producing consistent
           ADVACATE material?


CONCLUSIONS

The large quantities of sorbent injected into the ESP by the ADVACATE
process provide a potential for ESP problems.  However it appears that
addition of increasing loadings of hygroscopic sorbent material such as
calcium silicates (ADVACATE sorbent) tends to suppress any fines generated
by injection, drying, or mechanical process on the sorbent.  The phenomenon
is best explained by in-duct agglomeration of fines into larger particles.

The measured quantity and size distribution of the ADVACATE particles that
remain suspended in the gas stream, and would consequently be of importance
to ESP operation, were modeled to provide a prediction of ESP performance.
The results of the modeling were encouraging and suggest that particulate
matter control for an ADVACATE retrofitted process is manageable.

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REFERENCES
      Hall,  B.W.,  Singer,  C.,  Jozewicz,  W.f  Sedman,  C.B.,  and Maxwell, M.A.,
      Current  status of ADVACATE process for flue gas desulfuri^^tion,
      presented at the 1991 AWMA Annual  Meeting,  Vancouver,  B.C.,  Canada,
      June  20,  1991.

      Lawless,  P.A., Daniel, B.E., and Ramsey,  G.H., Characterization of the
      EPA/IERL-RTP pilot-scale precipitator, EPA-600/7-79-052 (NTIS PB
      292820),  February 1979.

      Plaks, N., The effects on electrostatic precipitation of changes
      in  grain loading,  size distribution,  resistivity,  and
      temperaturer presented at the Ninth Particulate Symposium,
      Williamsburg,  VA,  October 15-18,  1991.

      Muschelknautz, E.,  Die berechnung  von zyklonabscheiden fur  gase,
      Chemie-Ing-Techn,  jT4 No.5, 1970.

      Mothes,  H. and Loffler,  F.,  "Motion and deposition of particles in
      cyclones," Ger.  Chetn. Eng.,  8., (1985).

      Hoffman,  A.C.r Arends, H., and Sie, H., An  experimental investigation
      elucidating  the nature of the effects of solids loading on  cyclone
      performance, Filtration and Separation, pp. 188-193,  May-June 1991.

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TO M/XEfl    TO MIXER
                                                STACK
                                               DISPOSAL
     Figure 1. ADVACATE/MDI Process

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               Figure 2. EPA ESP Facility, Research Triangle Park, NC

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          10             20
         INJECTION RATE, g/Nm3
                                                 ADVACATE, fresh
                                               - ADVACATE, old
                                               • FLY ASH
30
Figure 3. Submicron Particle Mass Vs. Injection Rate

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80

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                                              	FLY ASH+ADV NO DUCT
100
Figure 4. Projected ESP Performance-ADVAGATE Process Impact

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                                   Table 1

                            PILOT ESP DESCRIPTION
                No. of Fields
                Plates per  Field
                Plate Spacing,  cm
                Effective Plate Area, m2
                Hires per Field
                Hire Diameter,  cm
                Hire Spacing,  cm
                SCA , m2/m3/s

             At 23 cm plate spacing, 1.5 m/s gas velocity
                                             4
                                             2
                                            22.9
                                             1.5
                                             5
                                            0,32
                                            22.9
                                            28
                                   Table  2

      PILOT  ESP  GAS  VELOCITY AND TEMPERATURE  PROFILE AFTER MODIFICATION
Top

  T, °C
  v, m/s

Middle

  T, °C
  v, m/s

Bottom
  T,  °C
  v,  m/s
154.4
  1.64
154.4
  1.89
 153.5
   1.12
                           Between
                           Fields
                            1 & 2
151.7
  1.48
148.3
  1.74
 152.8
   1.26
                        Between
                        Fields
                         263
149.4
  1.61
150.6
  1.74
 149.4
   1.35
                          Between
                          Fields
                           3 &  4
148.9
  1.65
147.8
  1.61
 147.8
   1.20
                             ESP
                            Outlet
147,8
  1.28
148.9
  1.93
 137.8
   1.28
                                   13

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              Table 3



PARTICLE SIZE ANALYSES WITH ESP OFF
                                         Outlet
Duct Feed ESP Inlet, q/Nm-3 ESP Outlet,
Rate, q/min Calculated Measured ESP Off, q/NmJ
150 3.94 3.69 2.04
500 13.13 8.94 3.80
750 19.70 12.14 4,41
1000 26.26 14.83 2.40
Table 4
Particle Size
GMMD, Urn GSD
21.8 4.00
22.3 3.67
20.0 3.31
13.4 3,03

SUBMICRON PARTICLE BEHAVIOR VS. ADVACATE INJECTION RATE
Outlet
ADVACATE Injection Particle Loading
Rate, a/min ESP Off, a/NmJ
150 2.04
500 3.80
750 4.41
1000 2.40
Table 5
FRESH SORBENT PARTICLE SIZE
Duct Feed ESP Inlet, ESP Outlet,
Rate, a/min Calculated, q/Nnr ESP Off, q/NmJ
150 3.94 0.878
300 7.88 1.060
750 19.70 0.534
1000 26.26 0.355
Submicron
Particle Loading
ESP Off, q/Nm3
0.0233
0.0315
0.0297
0.0240


Outlet
Particle Size
GMMD, urn GSD
65.6 6.77
63.1 6.10
81.4 12.15
112.3 15.35
             14

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                                   Table 6

                SDBMICRON PARTICLE LOADING WITH FRESH SORBENT
ADVACATE Injection
   Rate, q/min

      150

      300

      750

     1000
             Outlet
         Particle Loading
          ESP Off,Q/Nmj

               0,878

               1.060

               0.534

               0.355
                     Submicron
                   Particle Loading
                    ESP Off. g/Nm3

                         0.014

                         0,013

                         0.021

                         0.012
                                   Table 7

                SHORT DUCT INJECTION OF ADVACATE AT 250 q/min
                 ESP Outlet
              Particle Size,
                 Particle Loading
Sorbent
Fresh
Old
GMMD, Urn
54.5
52.3
100.7
134.6
GSD
5.54
5.80
6.32
7.33
ESP Off, q/Nm-»
0.463
0.318
0.426
0.338
                     Submicron
                   Particle Loading
                    ESP Off,

                       0.0057
                       0.0053

                       0.0046
                       0.0039
                                   Table 8

           SUBMICRON PARTICLE BEHAVIOR VS. FLY ASH INJECTION RATE
   Fly Ash
Injection Rate
 g/ndn
Outlet Particle
  75   (3.28)

 150   (6.57)

 300  (13.13)

 550  (24.07)
   Outlet
Particle Size
  Submicron
Particle Loading
o/NmJ
1.607
3.147
6.883
8.445
GMMD, ton
8.43
10.23
13.23
9.81
GSD
2.79
3.34
3.91
3.69
ESP Off, a/Nm3
0.0306
0.0881
0.2065
0.3378
                                15

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                                   Table 9

                                 ESP MODELED

                                        Small                      Large
ESPGeometry
Sections                              3                       5
Section Length, m                     2.29                    2."74
Height, m                             9.14                    9.14
Section Area, mz                   2070                    2484
Plate Spacing, m                      0.229                   0.229
Hire Spacing, m                       0.229                   0.229
Hire Diameter, mm                     2.8                     2.8
Wires per Lane                       10                      10
Lanes per Section                    50                      50

Gas Conditions

High Temperature Case

Temperature, °C                     149                     149
Volumetric Flow, actual nr/s        159.3                   159.3
Velocity, m/s                         1.52                    1.52
SCA, mVm3/s                         39.0                    78.0

Low Temperature Case

Temperature,  °C                     65                      65
Volumetric Flow, actual m3/s        129.8                   129.8
Velocity,,m/s                         1.24                    1.24
SCA, mVnrVs                         47.9                    95.8

Non-ideal Conditions
[same for all)

Sneakage                              0.05
Rapping Fraction                      0.06
Velocity Standard Deviation           0.15
                                 16

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 AEERL-P-855
       TECHNICAL REPORT DATA
(Pleatc read liulmctions on the rtrcttt before tomplel'
1. RE'ORT NO.
 EPA/600/D-91/Z44
                                                             PB92-113117
4. TITLE AND SUBTITLE
 Evaluation of Pilot ESP Performance with Elevated
 Loadings from Sorbent Injection Processes
                                                       S. REPORT DATE
                             G. PERFORMING ORGANIZATION CODE
1, AUTHORtSl
 Charles B. Sedman.  Richard E.  Valentine, and
 Norman Plaks
                                                       13. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
                                                       1O, PROGRAM ELEMENT NO.
 See Block 12
                             11. CONTRACT/GRANT NO.

                              NA (Inhouse)
J2. SPONSORING AGENCY NAME A«D ADDRESS
 EPA, Office of Research and Development
  Air and  Energy Engineering  Research Laboratory
  Research Triangle Park.  North Carolina  27711
                             13. TYPE OF REPORT AND PERIOD COVERED
                              Published paper; 4~9/91
                             14, SPONSORING AGENCY CODE
                              EPA/600/13
is.SUPPLEMENTARY NOTES AEERL project officer is Charles B. Sedman, Mail Drop 4,  919/
 541-7700. Presented at 9th Symposium on Participate Control, Williamsburg,  VA,
 10/15-19/91.
16.ABSTRACT^pj^g paper gives results of an evaluation of pilot electrostatic pi-ecipitalor
 (ESP) performance with elevated loadings from the advanced silicate (ADVACATE)
 sorbent injection process.  Measurements were made of a calcium silicate sorbent
 injected into a duct upstream of an ESP.  The concentration of ADVACATE sorbent
 submicron particles (=/<  1 micrometer)  and projected ESP emissions tended to peak
 and began to decrease when the overall particulate matter addition rale to the gas
 stream approached and then exceeded 12 g/Nm3. The submicron fly  ash, subjected
 to the same duct injection, increased linearly with increased injection rates from 3
 to 24 g/Nm3. A possible explanation is in-duct agglomeration of fines by the coarse
 particles, similar to observations reported on cyclone performance evaluations.
 The duct, flue gas, and sorbent characteristics that  affect agglomeration tendencies
 probably play a  major role in the observations presented. Most of the ADVACATE
 material settled out of the gas stream.  Measurements of the gas-suspended residual
 particulate matter were used to model expected ^SP performance. The encouraging
 results of the modeling suggest that collection of reacted ADVACATE sorbent in a
 ESP is manageable, c:
17.
                             KEY WORDS AUO DOCUMENT ANALYSIS
                DESCRIPTORS
                                           b.lDENtlFIERS/OPEN ENDED TERMS
 Pollution
 Sulfur Dioxide
 Sorbents
 Calcium Silicates
 Flue Gases
 Particles
 Mathematical Models
Electrostatic Precipi-
  tators
                 Pollution Control
                 Stationary Sources
                 Sorbenl Injection
                 ADVACATE
                 Particulate
                                         c.  COSATI Fkld/Gioup
13 B
07 B
11G

21B
14G
12 A
13J
19 DISIt IBUTtON SI A1LMFNT
      St 10 Public-
                 is SC CORtTV CLARE f/ftl(

                 I P.Cl.iSSl
                                                                    71 NO Ol
       w
                                           ?O SLCumi V CLASS
                                            nrl- .--".sifiPif

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