Sistes                   EPA-600/7-86-038
                  Protection
                                    October 1986
vvEFy\     Research  and
            Development
            ASPHALT!C CONCRETE INDUSTRY

            PARTICULATE EMISSIONS:

            SOURCE CATEGORY REPORT
            Prepared for
            Office of Air Quality Planning and Standards
            Prepared by

            Air and Energy Engineering Research
            Laboratory
            Research Triangle Park NC 27711

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               of the Off»ce of         and Development. U.S. Environmental
Protectors Agency,          grouped into           Trtest nine broad cate-
gories were            to facilitate further                 application of en-
vironmental technology. Elimination  of traditional  iroujjing     consciously
planned to                 transfer     a maximum interface in
The nine

    1, Environmental Health       Research

    2. Environmental Protection

    3,

    4. Environmental Monitoring

    5. Socioeeonormic Environmental

    S. Scientilic and Technical                    fSTAR)

    7,            Energy~Environment          aocf Development

    8. "Special"

    i,              Reports

This      has              to the 1NT6RAGENCV ENERGY-ENVIftONMENT
RESEARCH AMD  DEVELOPMENT series.        in mis                the
effort funded       the 17-ageney        Energy/Environ merit
Development Program. These             to EPA's mission to       the
health     welfare from ad«rs« effects o* poJluitnts          with       sys-
      The     of the Program is 10        the      development of domestic
energy sypplies m an environmentaiEy-compatibte manner by providing the nec-
essary                  and control tecrinology.                    enaly-
sea of the tranipod of ene^gy-feiated poHutants- and the^r       and
                   of,                 ol, control lechnologits for
        and integrated            of a          of energy-related environ-
mental
                        EPA
Thts      has     rtviewtU by the           Federal Agencies.
lor publication. Appnjvif       not signify that the contents necessarily reflect
the views tncJ policies of the Government, nor      mention of             or
commercial products  constitute indorsement or recommendation for
              is                            me National Technicii informa-
tion Service, Springfield, Virginia 22161.

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                                           EPA- 600/7- 86-038
                                           October 1986
     ASPHALTIC CONCRETE INDUSTRY

         P ARTICULATE EMISSIONS:

       SOURCE CATEGORY REPORT
                       by

                 John S. Klnsey
           Midwest Research Institute
              425 Yolker Boulevard
          Kansas City, Missouri 64110
           EPA Contract No. 68-02-3158
           Technical Directive No.  18
       EPA  Project Officer:  Dale L.  Harmon
  Air and Energy Engineering Research Laboratory
Office of Environmental Engineering and Technology
   Research Triangle Park, North Carolina 27711
                  Prepared for:

       U.S.  Environmental Protection Agency
        Office  of  Research and Development
             Washington, D.C. 20460

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                                 PREFACE
     This report was prepared by Midwest Research  Institute  (HRI)  for  the
Environmental Protection Agency's (EPA's) Air and  Energy  Engineering
Research Laboratory under EPA Contract No. 68-02-3158,  Technical Directive
No. 18.      Dale Harmon was the Project Officer for this study.   The  work
was performed 1n MRI's Air Quality Assessment Section    ( Chatten Cowherd,
Head).  The report was authored by     John Kinsey.       Gregory Muleski
was responsible for the computer software used in  the study,  and     Julia
Poythress was involved in data compilation and analysis.
                                   11

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                                 CONTENTS
Preface	   ii
Figures.  .....  	   iv
Tables	   vi

1.0       Introduction 	 ..... 	    1

2.0       Industry Description 	  .    2

               2.1  Raw material	    2
               2.2  Process description	    5
               2.3  Control technology 	   19

3.0       Data Review and Emission Factor Development. .......   24

               3.1  Literature search and screening. ........   24
               3.2  Emission data quality rating system	   25
               3.3  Particle size determination	   26
               3.4  Review of specific data sets	   32
               3.5  Development of candidate emission factors. ...   51

4,0       Chemical  Characterization	   89

5.0     -..Proposed AP-42 Section	  .   go

Appendices

     A.   Reference 1 and Supporting Data	A-l
     B.   Reference 3	  B-l
     C.   Reference 8 and Supporting Data .... 	 .....  C-l
     D.   Reference 12	0-1
     E.   Reference 23.	  E-l
     F.   Reference 26.	F-l
     G.   Reference 27	G-l
     H.   Complete Listings of JSKPRG, JSKRAW, and JSKLOG ......  H-l
     I.   Description of TI-59 Program to Compute Log-Normal Particle
           Size Distribution	  I-l
     J.   Computer Printouts and Hand Calculations	J-l
     K.   Emission Calculations for Drum-Mix Asphalt Plants .....  K-l
                                     111

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                                  FIGURES

Number                                                                Page

 2-1      General process flow diagram for batch-mix asphalt
            paving plants ... 	     8

 2-2      Effect of drum gas velocity on the production capacity
            for rotary dryers ............ 	     9

 2-3      Effect of drum gas velocity on dust carryout for rotary
            dryers	    10

 2-4      General process flow diagram for continuous-mix asphalt
            paving plants	    12

 2-5      General process flow diagram for drum-mix asphalt
            paving plants	    14
 3-1      Example output of "JSKPRG"	    53

 3-2      Example output of "JSKRAW"		    54

 3-3      Example output of "JSKLOG"	    55

 3-4     'Size-specific emission factors for conventional asphalt
            plants	_._	_!_•••    81

 3-5      Particle size distribution and size-specific emission
            factors for drum-mix asphaltic concrete plants. ....    82

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                                  TABLES
Number

 2-1
 2-2
 2-3
 2-4
 2-5

 3-1
 3-2
 3-3
 3-4
 3-5
 3-6

 3-7

 3-8

 3-9
 3-10

 3-11
 3-12

 3-13

 3-14

 3-15
 3-16

 3-17

 3-18

 3-19

 3-20

 3-21
                                              of Process .
                                              the Asphalt
Specifications for Asphalt Cements .....
Specifications for Emulsified Asphalts .  .  .
Composition of Asphalt Paving Mixtures .  .  .
Distribution of Asphalt Paving Plants by Type
Primary and Secondary Control Devices Used in
  Concrete Industry	,	
Equations Used for Particle Size Conversions 	
Guide to Particle Size Measurement 	
Summary of Particle Size Data - Reference 1. ......
                    Size Data for Test No.  C-393 .  .  .  .
                    Size Data for Test No.  C-426 .  .  .  .
                    Size Data for Uncontrolled Emissions
Summary of Particle
Summary of Particle
Summary of Particle
  Reference 3, .  .  	
Summary of Particle Size Data for the Dust Exiting the
  Primary Collector - Reference 3	
Summary of Particle Size Data for Sloan Construction
  Company. ............. 	
Summary of Particle Size Data for Harrison, Inc	
Summary of Particle Size Data for Test C-537 -
  Reference 12	
Summary of Particle Size Data for Reference 26 	
           Particle Size Test Data Collected at the
           Inlet -  Reference 27	
           Particle Size Test Data Collected at the Bag-
                 Reference 27	
                 Concentrations (Condensables Testing) -
Summary of
  Baghouse
Summary of
  house Outlet -
Particulate Mass
  Reference 27 ... 	 .........
Comparison of Computer Programs	
Calculated Particle Size Distributions and Controlled
  Emission Factors for Reference 1 - Scrubber Inlet. .  .
Calculated Particle Size Distributions and Controlled
  Emission Factors for Reference 1 - Scrubber Outlet .  .
Calculated Particle Size Distribution and Controlled
  Emission Factors for Reference 1 - Test No. C-393. .  .
Calculated Particle Size Distribution and Controlled
  Emission Factors for Reference 1 - Test No. C-426. .  .
Stoke1s Diameter versus Settling Velocity for Particles
  of Varying Density - Reference 3 	
Calculated Particle Size Distributions and Uncontrolled
  Emission Factors for Reference 3 - Dryer Exhaust . ,  .
Page

  3
  4
  6
 18

 20
 29
 31
 33
 35
 36

 38

 40

 43
 43

 45
 46

 48

 49

 50
 51

 57

 58

 59

 60

 61

 62

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                            TABLES (continued)
Number                                                                Page

 3-22     Calculated Particle Size Distributions arid Controlled
            Emission Factors for Reference 3 - Outlet of Primary
            Collectors	-.	   63
 3-23     Calculated Particle Size Distributions and Factors for
            Reference 8 - Sloan	   64
 3-24     Calculated Particle Size Distributions and Emission
            Factors for Reference 8 - Harrison	   65
 3-25     Calculated Particle Size Distributions and Emission
            Factors for Reference 12 - Test No. C-537	   66
 3-26     Calculated Particle Size Distribution and Associated
            Controlled Emission Factors for Reference 26 -
            Baghouse Outlet	   67
 3-27     Calculated Emission Factors for Reference 27 - Baghouse
            Inlet	   68
 3-28     Calculated Emission Factors for Reference 27 - Baghouse
            Outlet	   69
 3-29     Emission Factors for Condensable Organics * Reference 27  .   70
 3-30     Candidate Particulate Emission Factors for Uncontrolled
            Conventional Asphalt Plants. 	 ....   73
 3-31     Candidate Emission Factors for Cyclone Oust Collectors in
            Conventional Asphalt Plants	   74
 3-32     Candidate Particulate Emission Factors for Conventional
            Asphalt Plants Controlled by Multiple Centrifugal
            Scrubbers	  .   75
 3-33     Candidate Particulate Emission Factors for Conventional
            Asphalt Plants Controlled by Gravity Spray Towers. ...   76
 3-34   "Candidate Particulate Emission Factors for Conventional
         	Asphalt Plants Controlled^by a Baghouse Collector. . .  .   77
 3-35     Candidate Particulate Emission Factors for Drum-Mix
            Asphalt Plants Controlled by a Baghouse Collector. ...   78
 3-36     Summary of Candidate Emission Factors for Conventional
            Asphalt Plants	   80
 3-37     Range of Source Operating Characteristics Applicable to
            the Candidate Emission Factors	  .   84
 4-1      Chemical Composition of the Particulate Emissions from an
            Asphalt Batch Plant Controlled by  a Baghouse Collector.    89

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                             1.0  INTRODUCTION
     The U.S.  Environmental Protection Agency (EPA) is in the process of re-
viewing the pertinent technical criteria and data bases to determine whether
the establishment of a revised National Ambient Air Quality Standard (NAAQS)
for particulate matter based on particle size is warranted.   Upon adoption of
such a standard, the Clean Air Act requires that each state develop and sub-
mit revisions to their State Implementation Plan (SIP) which outline how they
will attain and maintain the standard.  These revisions to the SIP would ne-
cessitate the collection  and  use of information related to size-selective
participate emissions from new and existing sources.  Thus, a need exists to
initiate development of an emission factor data base to meet such objectives.

     Since 1972 the document entitled "Compilation of Air Pollutant Emission
Factors" (AP-42) has  been published by the EPA.  This document contains a
compendium  of  emission  factor reports for the  most significant emission
source categories.  Supplements  to  AP-42 have been published both for new
source categories and for updating existing emission factors as more infor-
mation about sources and the control of emissions has become available.  Up
to this  point,  however, little information has  been provided  in AP-42  with
regard to particle size characteristics of particulate emissions.

     To address the requirement for size-specific emission factors, the EPA
is currently conducting research to characterize the emissions of fine par-
ticles in the inhalable particulate (IP) size range for a variety of indus-
trial sources.   The purpose of this research is to develop emission factors
to be used if revisions to the National Ambient Air Quality Standard for par-
ticulate matter are made to address fine particles.  As part of this program.
Midwest Research Institute (MRI) has prepared this report which reviews the
existing emission data base for  asphalt  concrete*  plants based on  particle
size and provides a revised AP-42 Section (8.1) for that industry category.
Included in the revised Section 8.1 are the available size-specific emission
factors for asphalt concrete plants presented according to the type of pro-
cess and control technology used.

     This report is organized by section as follows:

     Section 2.0 - Industry Description
     Section 3.0 - Data Review and Emission Factor Development
     Section 4.0 - Chemical Characterization
     Section 5.0 - Proposed AP-42 Section
     Section 6.0 - References
   The term "asphalt concrete" is used everywhere in this report except for
     the proposed AP-42 section where "asphaltic concrete" has been substi-
     tuted.  Asphalt concrete is the term most commonly accepted by experts
     working in the industry.

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                         2.0  INDUSTRY DESCRIPTION
     Asphalt paving  (concrete)  consists  of a mixture of well graded, high
quality aggregate  and  liquid  asphalt cement which  is heated and mixed  in
measured quantities to produce bituminous pavement materials.1  Hot mix as-
phalt paving can  be  manufactured by any of the following basic processes:
batch-mix, continuous-mix, and drum-mix.

     In this section,  the raw material used in the formulation of asphalt
concrete is described, along with the basic processes available for its pro-
duction and the technology  employed  by the  industry to control particulate
emissions.

2.1  RAW MATERIAL

2.1.1  Asphalt Cement

     Asphalt is a  dark brown  to black thermoplastic cementitious material
composed principally of bitumens which come either from naturally occurring
deposits  or  is derived from  crude  petroleum.   Chemically,  asphalt  is  a
hydrocarbon consisting of asphaltenes (small particles surrounded by a resin
coating), resins,  and oils.   The asphaltenes contribute to body,  the resins
furnish the adhesive and ductile properties, and the oil  influences the vis-
cosity and flow characteristics of the asphalt.2

     Asphalt cement is a highly viscous material available in many standard
grades,3  Originally,  penetration tests^were  used to specify grades of"
asphalt cement.  More  recently,  viscosity is becoming the standard  char-
acteristic to specify grades.3  Specifications for asphalt cement are based
on a range of viscosity at a reference temperature of 60°C (14G°F).  A min-
imum viscosity at 135°C (275°F) is also specified.  These temperatures were
chosen because 6Q°C (14Q°F) approximates the maximum temperature of asphalt
pavement  surfaces  in the United States while  135°C (275°F)  approximates
mixing and laydown temperatures  for  hot mix asphalt pavements.  Specifica-
tions for the various grades of asphalt cement are presented in Table 2-1.3

     In some areas,  emulsified asphalts are used  for the production  of  hot
mix paving.  Emulsified asphalts are dispersions of colloidal size globules
of asphalt in water (or visa versa) that are prepared using high speed mixers
or colloid mills.   Small quantities of surface active agents or emulsifiers
are added to the asphalt to aid dispersion.  Anionic and cationic emulsified
asphalts are two commercially available asphalt emulsions.1  Specifications
for the various grades  of emulsified asphalts  are presented  in Table  2-2.3

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TABLE 2-1,   SPECIFICATIONS FOR ASPHALT CEMENTS3


Characteristics

Penetration, 77°FS 100 g, 5 sec.
Viscosity at 275°F
Saybolt Furol , SSF
Kinematic, Centistokes
Flash point (Cleveland Open Cup), °F
Thin film oven test
Penetration after test, 77°F
100 g, 5 sec. , % of original
Ductility:
At 77°F, cm
At 60°F, cm
Solubility in carbon tetrachloride, %
General requirements


J«l *
AASHTO
test
method

T49

-
—
T 48
T 179

T 49

T 51

T 44C



h
ASTM Industrial
test and
method special

D 5 40-50

E 102 120+
D 445 240+
D 92 450+
-

0 5 52+

0 113 100+
-
D 4C 99.5+
The asphalt shall be
shall be uniform in
to 350°F.



60-70

100+
200+
450+
_

50+

100+
-
99.5+
prepared by
character

Grades


85-100

85+
170+
450+
_

45+

100+
-
99.5+

Paving

120-150 200-300

70+ 50+
140+ 100+
425+ 350+
_ _

42+ 37+

60+
60+
99.5+ 99.5+
the refining of petroleum. It
and shal

1 not foam when heated


. American Association of State Highway
American Society of Testing & Material
Transportation Organizations.
s.
Except that carbon tetrachloride is used instead


of carbon disulfide as solvent.

Method

No. 1 in AASHTO Method
d T 44 or Procedure No. 1 in ASTM Method D 4,

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TABLE 2-2.   SPECIFICATIONS FOR EMULSIFIED ASPHALTS3



Characteristics
Tests on Emulsion
Fural viscosity at 77°F, sec.
Fural viscosity at 122°F, sec.
Residue from distallation, %
Settlement, 5 days, %

Demulsibility:
35 ml of 0.02 N CaCl2, %
50 ml of 0.10 N CaCl2, %
Sieve test (retained on No. 20), %
Cement mixing test, %
Tests on Residue
Penetration, 77°F, 100 g, 5 sec.
Solubility in carbon tetrachloride ,e %
Ductility, 77°F, cm.
AASHTOa ASTMb
test test Rapid
method method RS-1

20-100
-
57-62
3-
T 59 D 244

60+
-
0.10-
—

T 49, D 5 . 100-200
T 44° D 4° 97. 5+
T 51 D 113 40+
Medium Slow
settling settling settling
RS-2 MS-2 SS-1

100+ 20-100
75-400
62-69 62-69 57-62
3- 3- 3-


50+
30-
0.10- 0.10- 0.10-
2.0-

100-200 100-200 100-200°
97.5+ 97.5+ 97.5+
40+ 40+ 40+

k American Association of State Highway Transporation Organizations.
American Society of Testing & Materials
,
For some special uses, such as dilute Emulsified Asphalt fog seal coats,
by preferable. In such cases, the Penetration of Residue at 77°F shal
d designated as SS-lh.

Except that carbon tetrachloride is used instead of carbon disulfide as

a lower penetration residue may
1 be 40-90 and the grade shall be

solvent, Method No. 1 in AASHO
e Method T 44 or Procedure No. 1 in ASTM Method D 4.
This solvent is being reevaluated for replacement due to its toxic and carcinogenic properties.

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2.1.2  Aggregate

     Asphalt pavement mixtures are produced by combining mineral aggregates
and  asphalt  cement.   Aggregates  constitute  over 92% of  the total mix-
ture.2  Aside from the amount and grade of asphalt used, mix characteristics
are determined by the relative amounts and types of aggregate used.

     Aggregate is generally  sized in three groups:   coarse -aggregate (ma-
terial > 2.36 mm), fine aggregate (material passing < 2.36 mm), and mineral
filler (material < 74 urn).1  Coarse aggregate can consist of crushed stone,
limestone, gravel, slag from steel mills, glass, oyster shells, and material
such as decomposed granite (or other fractured material),  or highly angular
material with a pitted or rough surface.   Fine aggregate consists of natural
sand, crushed limestone, slag, or gravel  or any mixture of these materials.
Mineral filler or mineral dust consists of crushed rock, limestone, hydrated
lime, portland cement, fly ash, or other nonplastic mineral matter which is
either added to the mix or is indigenous to the aggregate itself.  A minimum
of 70%  of  this  material must pass through a  74-pm sieve.1   All  aggregate
should be  free  of clay and silt.  Table 2-3 lists the composition for the
various types of  asphalt paving  mixtures  specified by the American Society
of Testing and Materials (ASTM) Designation 3515.1

     Generally, a single natural  source  cannot  provide  the  required grada-
tion; thus,  the mechanical  combination of two or more aggregates is often
necessary.  Aggregates may also be blended because of limited supplies, for
economic reasons,  and to control  particulate emissions.   Blending techniques
include trial  and error, mathematical,  and  graphical  blending methods.4

     State transportation departments  are  usually responsible  for  specify-
ing  the percentage of each aggregate size  in  a  given mix.   State and local
specifications .for aggregate  properties  which are required  for a sound mix
take into account variations in locally available supplies.4'5  In practice,
the plant operator develops a job-mix formula to produce the particular grade
of paving  material  necessary to  meet customer specifications based on the
characteristics of the available aggregate.

2.2  PROCESS DESCRIPTION

2.2.1  Batch-Mix Process

     Crushed and  screened raw aggregate  is stockpiled near  the  plant where
the moisture content will stabilize between 3 and 5% moisture by weight for
the  total  aggregate  blend  (fine  aggregate contains the highest amount of
moisture).6  The aggregate is transferred by front-end loader from the stor-
age piles and placed  in the appropriate hoppers of the cold feed unit.   The
material  is  metered  from the hoppers  onto a  moving  belt  and conveyed by
bucket elevator or belt conveyor into a direct-fired rotary dryer fueled by
gas  or oil, or lately by coal or coal/oil slurries.

     The dryer is a revolving cylinder usually ranging from 0.9 to 3.5 m (3
to 12 ft)  in diameter and from 4.5 to 12 m (15 to 40 ft) long,  in which ag-
gregate is  dried  and  heated  by an  oil, gas,  or  combination  oil-gas burner.

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              TABLE  2-3,   COMPOSITION  OF  ASPHALT PAVING MIXTURES
                                     Asphalt Concrete                   §*«*      A
                                                                     Asphalt     Asphalt

  Sieve Size                  ^'* Designation and Nominal Maximum Size of Aggregate
1 Vi in, I in. Yi in. '/i in.
(2A) (3A> (4A) (5A>
(37.5mm) (25.0mm) (19.0mm) (12.5 mm)
-Urn, No. 4 No. 16
(6A) (7A) (8A)
(9.5mm) (4.7$ mm) (1,18 mm)
                      Grading of Total Aggregate (Coarse Plus Fine, Plus Filler if Required)
                   Amounts Finer Than Each Laboratory Sieve (Square Opening), weigh! percent
2V* in. (63 mm)
2 in. (50 mm)
1 V* in. (37.5 mm)
1 in. (25.0 mm)
fc in. {19.0 mm)
Vi in. (12.5 mm)
H in. (9.5 mm)
No. 4 (4.75 mm)
No, 8' (2.36 mm)
No. 16 (1.18 mm)
No. 30 (600 urn)
No. 50 (300 urn)
No. IOO(150Mm)
No. 200* (75 pm)
100
90 to 100
60 to 80

20 to 55
10 to 40
. . «

2 to 16
. . .
Oto5
100
90 to 100
60 lo 80

25 to 60
15 to 45
. * .

3 to 18

I to 7
100
90 to 100
60 to 80
35 to 65
20 to 50


3 to 20

2 to 8
100
90 to 100

45 to 70
25 to 55
. . .

5 to 20

2 to 9
100
90 to 100
60 to 80
35 to 65
. » .

6 to 25

2 to 10

100
80 to 100
65 to 100
40 to 80
20 to 65
7 to 40
3 to 20
2 to 10
...
. . .
100
95 to 100
85 to 100
70 to 95
45 to 75
20 to 40
9 to 20
                               Asphalt Cement, weight percent of Toial Mixture*'
                  3'/ito8   4to8Vj   410 9     4Wio9W   5 to 10   7 to 12     8V* to 12

                           Suggested Coarse Aggregate Sizes
4 ind 67

5 and 7
or 57
67or68 7or78 8
or • . .~ 	
6 and 8
   aln considering the total grading characteristics of an asphalt paving mixture the amount
passing the No. 8 (2.36 mm) sieve is a significant and. convenient field control point between
fine  and  coarse aggregate. Gradings approaching the maximum amount permitted to pass the
No. 8 (2.36-mm) sieve win result in pavement surfaces having comparatively fine texture, while
gradings  approaching  the minimum amount passing the  No. 8 (2.36-mm) sieve will result  in
surfaces with comparatively coarse texture.
   ^The  material passing the No. 200 (75-jUm) sieve may  consist of fine particles  of the
aggregates or mineral  filler, or both. It shall be free from organic matter and clay particles and
have a plasticity index not greater than 4 when tested in accordance with Method 0423 and
Method D424.
   cThe  quantity of  asphalt cement is given in terms of weight percent of the  total mixture.
The  wide difference  in the specific  gravity  of various  aggregates, as well as a considerable
difference in absorption, results in a comparatively wide range in the limiting amount of asphalt
cement specified. The amount of asphalt required for a given mixture should be determined by
appropriate laboratory testing  or on the basis of past experience with similar mixtures, or by a
combination of both.
 	             Used  by  permission of  the  Asphalt  Institute.

*U.S.A.  Standard sieve designation is 38,1 mm,

                                           6

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The cylinder  is  equipped with  longitudinal troughs  or  channels called
"flights" that lift the  aggregate and drop it  in  veils  through the  hot
gases.   The slope  of  the cylinder, its rotation speed,  diameter,  length,
and the  arrangement and  number of flights  control the length  of time re-
quired for the aggregate to pass through the dryer (residence time).  The
dryer performs two functions; it vaporizes and removes the moisture, and it
heats the aggregate to mixing temperature.

     The most commonly used oil  burner in dryers atomizes the fuel  oil with
low pressure air.  There are also medium and high pressure gas burners,
combination oil and gas  burners,  and liquid petroleum gas  (LPG} burners.

     As  it leaves  the dryer, the  material drops onto  a bucket  elevator and
is transferred to a set of vibrating screens where it is  classified by size
into four or more grades.  The classified aggregate then  drops into four or
more large bins.   The  bins  provide a substantial  amount  of surge capacity
for the dryer system.   The operator controls the aggregate size distribution
by opening one of  the bins  and allowing the classified aggregate to  be de-
posited into a weigh hopper until the desired amount of material is obtained.
The doors of  this  bin are  then closed, another bin  is opened,  and  so on.
After all the  material  is weighed out, the mixture is dropped into a pug-
mill mixer and mixed (usually dry) for about 15  sec.   The action of the two-
shafted pugmill is similar to that of an egg beater except that the paddles
are mounted on horizontal shafts instead of vertically.   The asphalt cement
is pumped from a heated  storage tank  (or  tanks) into  the pugmill and  thor-
oughly mixed with  the aggregate for 25 to 60 sec to  form asphalt concrete.
The hot  mix  is  then  deposited in a truck and hauled away to the job site.
A flow diagram of the batch-mix process is shown in Figure 2-1.s

     As with most facilities in the mineral  products industry, asphalt batch
plants have two major categories of particulate  emissions:   those which are
vented to the atmosphere through  some type  of stack,  vent,  or  pipe  (ducted
sources) and those which are emitted directly from the source to the ambient
air (fugitive sources) without the aid of such equipment.  Ducted emissions
are usually captured  and transported by an industrial ventilation  system
with one or more fans or air movers and emitted  to the atmosphere through a
stack.   Fugitive sources, on the other hand, can either be process fugitives,
which are emissions associated with some form of physical or chemical change
in the material being processed,  or open  dust sources where no  such  change
occurs.

     The most  significant source of ducted emissions  from  asphalt batch
plants is the  rotary  dryer.  The amount  of aggregate dust  carried  out of
the dryer by  the  moving gas stream depends upon a number of  factors,  in-
cluding the gas velocity in the drum, the particle size distribution of the
aggregate, and the specific gravity and aerodynamic  characteristics  of the
particles.  The most  significant of these factors  is the gas  velocity in
the dryer.6   Figures  2-2 and 2-3 show the  effect  of increasing dryer gas
velocity upon production capacity and dust carryout as determined by a study
conducted by  the  Sarber-Greene  Company.6'7   It  should be noted that a 50%
increase in gas velocity will allow about a 30% increase  in production while
causing  a 150%  increase  in dust carryout.  Of course the increase in drum
velocity also  results  in higher air volumes drawn through  the dryer which
subsequently increases the  amount of oxygen available for combuston.

-------
00
            UGINP

            y—* Mule* fatal

            (o) OwiW (irinlm

            (ff) hecM fuBill.. Enlntam

            foq Of.n Dmi
Fine Aggregate
Storage Pile
       Coarie* Aggregate
       Storage Pile
                                      Feeders
                              Figure 2-1.   General process  flow diagram  for  batch-mix
                                                asphalt  paving plants."

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1
0

e
u
u
D
0.

a

c
u

•o
o
    100
    90
    80
     70
    60
     50
.     40
                   Used by permission of Barber-Greene Company.
     30
     20
     10
                   29.1
             10    20    30   40    50    60    70    80    90


                        Drum Gas Velocity, % Increase


             600     700     800    900       1000      1100


                           Drum  Gas Velocity,  FPM
                                                                 100






                                                                  1200
    Figure  2-2.   Effect of drum gas  velocity on the production capacity

                   for rotary dryers.^

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          Used by permission of Barber- Greene Company
   0     10     20    30     40    50    60     70
                     Drum Gas Velocity, % Increase
    600        700      JOO       900     1000
                        Drum Gas Velocity, FPM
80    90    100

 1100    1200
Figure 2-3.  Effect of drum gas velocity  on  dust  carryout for rotary
               dryers,'
                                 10

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In general, if the Stoke's settling velocity of an aggregate particle is of
the same order of magnitude as the gas velocity through the dryer, the par-
ticle will probably  be  entrained in the gas  stream  and swept out of the
dryer,s

     The major source of  process fugitives in asphalt  batch plants  comes
from enclosures over the hot-side conveying, classifying, and mixing equip-
ment which are vented into the primary collection  equipment along with the
dryer gas.  These  vents  and  enclosures are commonly called the  "fugitive
air" or "scavenger"  system.   The scavenger system may or may not have its
own separate air mover-depending on the particular facility.

     The particulate emissions captured  and transported by the  scavenger
system consist mostly of aggregate dust but may also contain a fine aerosol
of condensed liquid particles.  This liquid aerosol is created by condensa-
tion of the organic  vapors volatilized from the asphalt  cement in the pug-
mill.8  The amount of liquid  aerosol produced depends to a large extent  on
the temperature of the asphaltic cement and aggregate entering the pugmill.

     There are also  a  number of open dust sources associated with asphalt
batch plants.   These include the fugitive dust generated by vehicular traf-
fic on paved and unpaved roads, the dust created by the storage and handling
of the aggregate material, and similar operations.  The  number and type  of
fugitive emission  sources which  are  associated with a particular plant de-
pend on whether the  equipment is  portable  or  stationary, whether it  is lo-
cated adjacent to a gravel pit or quarry, and the inherent aggregate moisture.

     To illustrate the various sources of  particulate emissions  associated
with asphalt batch plants,  the type and location  of  each  emission point
throughout the process flow are shown in Figure 2-1.

2.2.2  Continuous-Mix Process  •

     The continuous-mix process is generally similar to that of batch plants
with the exception that slight modifications have been made to the hot-side
conveying equipment.   In a continuous plant, the classified aggregate drops
from the  vibrating screens into  a set of small bins.  The purpose of these
bins is to  collect and  meter the classified aggregate to the mixer;  thus,
they  do  not provide a  large  amount  of surge  capacity.   From the hot bins,
the aggregate is metered through feeder conveyors to a second bucket elevator
and into the mixer.  Hot asphalt is metered into the inlet end of the mixer,
and the mix is conveyed through the unit by the action of the rotating pad-
dles.  Retention time is  controlled (and some surge capacity provided) by
an adjustable  dam  at the end of  the  mixer trough.  The asphalt concrete
flows out of the mixer into a surge hopper for loading into trucks.

     In some plants,  surge  capacity is provided by a set of separate hot
mix storage bins.   These bins, which may be either heated or nonheated, are
often sealed from  contact with the ambient air to prevent oxidation.  If
storage bins are  used,  the mix  is conveyed from the mixer to the storage
bins and trucks are  loaded from the bins.  A flow diagram of the continuous-
mix process is shown in Figure 2-4.


                                     11

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                       tmlniw felril


                       OucM fxlubn

                       fioc.n FujHIW. Inlulom


                       OfMiiOutl tnlnlon
              Fine Aggregate
              Storage Pile
                              Cold Aggregate Blra
                             Exhaust la
                             Atmosphere
UJ
     	.,  	 Draff For* ( Location
    I  t	  ^7—v Dependent Upon
    ^~*t         Type of Secondary)
       Primary Dull
                         Feeders —^
Coarse Aggregate
Storage Pile
        • Elevators
Heater  ^Asphalt    lruck
         Storage
            Figure 2-4.   General  process  flow diagram for continuous-mix
                              asphalt paving plants.

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     The participate emissions from continuous-mix asphalt plants are gen-
erated in the  same  manner  as for batch plants, except that an additional
hot-side conveyor is used  which  would tend to increase the amount of dust
collected by the  scavenger system.   Otherwise, there  are  no  substantial
differences in  the  mechanisms  which produce  the  emissions.   The various
sources of  particulate  emissions associated  with continuous-mix asphalt
plants are identified in Figure 2-4.6

2.2.3  Drum-Mix Process

     The third  type of process utilized for the production of asphalt pav-
ing mixtures is the  drum-mix process.   This  process is relatively new to
the industry and  is  becoming increasingly more popular due  to  its lower
capital and operating costs and its simplified production  process.   The
most significant difference between the drum-mix process and the others de-
scribed above  is  that the  aggregate is dried, mixed, and combined with the
asphalt cement  inside a single unit (rotary drum  mixer) thus eliminating a
substantial amount of mechanical  equipment.9

     During normal  operation,  proportioned aggregate  from the  cold  feed
bins is transported by belt conveyor to either a vibrating screen where the
larger material is  rejected or directly to the drum mixer.   The already
combined aggregate is then introduced into the uphill  end of the rotating
drum mixer where it passes  through the hot gases and is heated to a tempera-
ture of 300°F  to  remove moisture.  The aggregate  is tumbled by the flights
as it  travels  the length  of the drum in parallel  flow with the combustion
gases from the burner.   This is opposite to the batch process where a counter-
flow arrangement  is  used.   Asphalt cement from a heated  storage tank is
introduced from the  opposite end of the drum where  it is mixed with the
heated aggregate to produce hot mix asphalt paving.  The point at which the
asphalt cement is  injected  varies from plant to plant but is generally more
than halfway down the  length of the drum.  The asphalt is protected from
coming into direct  contact with  the burner flame not only by distance but
also by the dense curtain  of falling aggregate.   In a few cases, a metal
barrier (flame  shield)  is  installed in the drum to provide additional pro-
tection for the asphalt cement.  The hot mix (120 to 140°C)10 is discharged
from the drum  mixer  and transported by inclined  belt  conveyor to storage
silos  for  eventual  loading into  trucks and transport  to the job site.  A
diagram of the drum-mix process is shown in Figure 2-5.

     Inside the drum mixer  four basic processes  occur.   These are bulk
moisture removal;  asphalt  injection  with  partial  coating; foaming (which
completes the coating process); and rapid temperature rise of the mix.10'11
Upon entering  the dryer, the aggregate is directly exposed to radiant heat
which  vaporizes most  of the moisture in the  aggregate.  As the  aggregate
continues down  the  length  of the drum, out of contact with the  flame, it
reaches the asphalt  injection  point.  At this point, the  liquid  asphalt  is
injected by a  shielded  pipe.  In some plants,  chemical  additives  (e.g.,
liquid silicon  added  at the refinery or by the distributor) are injected
along  with  the asphalt  to   improve the distribution  of the spray and its
adhesion to the aggregate  surface.9'10  After asphalt injection, the ag-
gregate attains a temperature high enough to  vaporize the remaining moisture
                                     13

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 Fine Aggregate
 Storage Pile
Coarse Aggregate
Stcuaga Pile
                                                                                                  ©
                   Aggregate Feed flim

                       (
                                                                                                    Truck load-Out
    Figure  2-5.   General  process flow diagram for drum-mix asphalt  paving plants.

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in the pores  of  the rock.   As this water vapor reaches the  surface,  it
escapes by foaming  through  the asphalt coating, which  is  thought to in-
crease its uniformity  of  film thickness.   Near the  discharge end of the
drum, sufficient heat  is  absorbed in  the aggregate itself to increase the
mix temperature,  since the bulk of the moisture has already been vaporized.
The total  residence time ranges from 3 to 5 min.10'11

     As with  the other two  processes  used for  the production of asphalt
concrete,  the  major ducted source of  particulate  emissions is the  drum
mixer itself, but emissions are significantly  lower  than in  batch and  con-
tinuous plants.  This  overall  reduction in emissions  is due  to the coating
of the finer  particles with the asphalt  cement.   The emissions  from the
drum mixer consist  of  a gas stream containing a substantial  amount of  par-
ticulate matter and lesser  amounts of gaseous organic compounds of various
species.9   The particulate  generally  consists  of fine aggregate particles
entrained  in the flowing gas stream during the drying process.  The organic
compounds, on the other hand,  are a result of the heating and mixing of the
asphalt cement inside the drum, which  volatilizes certain components of the
asphalt.   Once the volatile organic compounds have sufficiently cooled, they
condense to form a fine liquid aerosol or "blue smoke," the quantity of which
depends on the type of asphalt cement and temperature.9'10   Filaments of
asphalt cement can also be produced through a similar process.

     A number of measures  have been introduced in the newer plants to re-
duce or eliminate blue smoke,  including the  installation of  flame shields,
rearrangement of the  flights  inside the  drum,  adjustments  in the asphalt
injection  point, and  other  design changes.9'10  These modifications have
resulted  in  significant improvements in  the elimination of blue smoke.

     The process fugitive emissions from  the hot-side screens, bins, ele-
vators, and pugmill  normally associated with batch and continuous-mix plants
have been  eliminated in the drum-mix process.  There may be, however, a cer-
tain amount of  fugitive  liquid aerosol produced during the  transport  and
handling of the hot mix from  the  drum mixer  to  the storage  silo if an  open
conveyor is used.   Otherwise,  the remaining open dust sources are similar
to those  found  in  batch or continuous plants.   The location of each emis-
sion point throughout the drum-mix process is shown on Figure 2-5.

2.2.4  Recycle Processes

     In recent years, a new practice has been initiated in the asphalt con-
crete industry.  This practice involves the recycling of old asphalt paving.
Recycling significantly reduces the amount of new (virgin) rock and asphalt
cement needed to repave an existing road base.   The various recycling tech-
niques include both cold and hot methods.   Since this report addresses only
hot-mix asphalt processes,  discussion will  be  limited to  recycling  at a
central plant.

     For recycling, old  asphalt  pavement is broken up at the job site and
removed from the road base.   This material is then transported to the plant,
crushed, and  screened  to  the  appropriate size for further processing.   It
                                     15

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is then heated and mixed with superheated new or virgin aggregate (if appli-
cable) to which the proper amount of new asphalt cement is added to produce
an adequate grade of hot asphalt paving suitable for laying.

     There are basically three methods which can be used for heating of re-
cycled asphalt paving (RAP) prior to the addition of the asphalt cement.10*12
These methods  are  direct  flame  heating,  indirect  flame  heating,  and super-
heated aggregate.  Each is discussed in the following subsections.

2.2,4.1  Direct Flame Heating--
     Direct flame  heating is  typically performed  with a drum mixer  wherein
all materials  are  simultaneously mixed in the  revolving  drum.   The first
experimental attempts at  recycling used a standard drum-mix plant and in-
troduced the recycled paving and virgin aggregate concurrently at the burner
end of the drum.  Numerous problems with excessive blue smoke emissions led
to several  modifications  to  the process, including  the addition of heat
shields and the use of split feeds.12

     Heat dispersion is a method used for recycling.   A heat shield i.is  in-
stalled around the burner and additional cooling air is provided to reduce
the hot gases  to a temperature  below  about  430 to  650°C  (800 to 1200°F),
thus decreasing  the amount of blue smoke.12   However, the  heat shield also
accounts for a higher gas velocity and turbulence due to the restriction in
the free flow of the burner gas.13  This type of equipment can successfully
recycle a  mixture  of  up to approximately 70% recycled asphalt concrete.12

     The concept of a drum within a drum has also been successfully utilized
for recycling .  This process ii based on a small diameter  drum
being inserted into a conventional drum-mix unit.   Virgin aggregate is intro-
duced into  the inner  drum where it is superheated to approximately 150 to
260°C (300  .to  500°F).12  Reclaimed material  is introduced into  the outer
drum through a second charging chute.  The reclaimed material and the heated
virgin aggregate meet  at the discharge point of the inner drum where heat
transfer-occurs.—This  type  of-equipment-can successfully recycle mixtures
containing  up to about 50 to 60% recycled bituminous materials.12

     Split  feed  drum  mixers  were first utilized for recycling in 1976 and
are now the process used  most often.  New'aggregate  't±s  introduced'
at the  flame  end of the drum where it is superheated to 150 to 260°C (300
to 500°F).12   At about the midpoint of  the  drum  the recycled bituminous
material is  introduced  by a split  feed  arrangement and heated by the hot
gases as well  as by heat  transfer from  the  superheated virgin aggregate.
This type  of  equipment can successfully recycle mixtures containing up to
about 60 to 70% recycled bituminous material.1^

     The last type of direct flame method involves the use of a  slinger con-
veyor to throw recycled asphalt into the  center  of the drum mixer from the
discharge end.  This arrangement is sold as a kit for the retrofit  of exist-
ing plants.  In this process, the RAP material  enters the drum along an arc
landing in  the appropriate area of the asphalt  injection  point.   A  slinger
conveyor should  be capable of recycling  mixtures  containing about the same
amount of RAP  (i.e., 50 to 70%)  as  the other direct  flame methods mentioned
above.12

                                     16

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2.2.4.2  Indirect Flame Heating-
     Indirect  flame  heating has been performed  with special drum mixers
equipped with  heat  exchanger tubes-   These tubes prevent the
virgin aggregate/recycled paving mixture from coming  into direct  contact with
the flame and the associated high temperatures.   These plants are capable  of
processing up to 100% recycled bituminous material  but account  for lower pro-
duction for similarly sized dryers.12

2.2.4.3  Superheated Aggregate—
     Superheated aggregate can also be utilized  to  heat recycled  bituminous
material.   As noted above, two of the direct flame  methods also make use of
this concept to  a certain extent to partially heat the recycled  material.

      In standard  batch or continuous mix plants recycled  paving  can be  in-
 troduced  either  into the pugmill or at the discharge end  of the  dryer,  at
 which point the  temperature of the material is raised by  heat transfer  from
 the virgin aggregate.  The proper amount of new asphalt cement is  then  added
 to the virgin  aggregate/recycled paving mixture to produce high  grade
 asphalt concrete.  The percentage of recycled pavement is  ususally below 30%.

     Tandem drum mixers can also be utilized for  heating  of the recycle mate-
rial.   The first drum or aggregate dryer is used  to superheat the virgin ag-
gregate,  and a second drum or dryer is provided either to heat only recycled
paving material or to mix and heat  a combination of virgin and recycled  paving
material.12   It is possible to use the exhaust gas  from the first dryer as a
heat source for the second unit.  The recycling  technique utilizing  super-
heated aggregate  is  limited to  about  50% recycled bituminous  material.

     There are a number of process-related variables affecting the generation
of emissions  from asphalt recycling processes.  These include the method of
heating the RAP, the percentage of RAP versus virgin material used, and the
introduction  of chemical  additives to the mix.  The exact nature  of how each
variable  affects the quantity of emissions produced or how recycle emissions
compare with  plants  utilizing  100% virgin aggregate is  not yet known.

2.2.5  Industry Distribution

     There were approximately 4,500 asphalt concrete plants operating  in the
United States during 1981 which produced 264 million metric tons  (290  million
short tons)  of hot mix paving.13  Of the various  processes described above,
batch-mix  plants are currently the most common.    However, most of the  plants
being sold as either new installations or as replacements to  existing  equip-
ment are of the  drum-mix type.   To illustrate the  distribution of asphalt
paving plants by type of process, Table 2-4 presents data on  the  percentage
of plants  by process,  production capacity, and those equipped for recycling
for calendar years 1979 and 1980.13  Comparing the  information contained in
Table 2-4  with that presented in a  1977  EPA study,2 it was determined  that
the percentage of drum-mix facilities has increased from  2.6% to  15% of the
total plant population over a 5-year period (1975 to 1980).   Due  to the sig-
nificant economic savings  associated with the drum mix process,  it is ex-
pected that the  trend  toward an increased usage  of this  type of  equipment
should continue in the future.

                                      17

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                 TABLE 2-4.  DISTRIBUTION, OF ASPHALT PAVING PLANTS BY TYPE OF PROCESS1

Percentage of


< 150
Type of process 1979
Batch mix 21%
Drum mix 2%
£ Continuous mix 3%

h
tons/hr
1980
20%
2%
3%


asphalt plants
by production
capacity



Percentage of
plants equipped
150-300 tons/hr
1970
505
&
1980
49%
7% 8%
2%
2%
300-400
1979
8%
3%
1%
tons/hr
1980
8%
4%
1%
> 400
1979
1%
1%
1%
tons/hr
1980
1%
1%
1%
for
1979
2%
2%
-
recycling
1980
4%
4%
—
:c
Per reference No. 13.  No data available on the number of uncontrolled facilities.
No data available for plants < 150 ton/hr production capacity.

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2.3  CONTROL TECHNOLOGY

2.3.1  Ductedand Process Fugitive Emissions

     Particulate matter  from  the  dryer (or drum mixer)  and  the  scavenger
system is removed  from  the gas stream prior  to being discharged into  the
atmosphere by one  or  more air pollution control devices.  In  the case of
batch and continuous  mix plants,  two dust collectors are usually arranged
in series.   The  primary  collector is a low efficiency device which essen-
tially removes the  larger particles, with a secondary collector being em-
ployed to complete  final  cleanup  of the stack gas  to the required degree
(Figures 2-1, 2-4,  and 2-5).

     Almost every plant  has  at least a primary dust collector which was
originally used  to  prevent dust nuisance,  protect the air handling equip-
ment downstream  from  the dryer,  and for product recovery.   Such equipment
proved to be economically attractive as the aggregate it recovered could be
recycled.  Generally,  the primary collector cannot meet current particulate
emission regulations but does considerably reduce the load on the secondary
collector.

     Secondary collectors are used to achieve final  control  of emissions to
the atmosphere in  batch  and continuous plants.   These collectors are more
efficient than primary collectors  and are able to remove particles in the
smaller  size ranges.  Material  recovered  from the secondary collector may
be recycled (baghouse) or discarded (scrubber) depending on economic feasi-
bility.   Secondary  collectors  may  be further subdivided into wet and  dry
types.

     It  is currently  standard practice in drum-mix plants to utilize only
one high efficiency collector for gas cleaning purposes though primary col-
lectors  are  on the  rise  (Figure 2-5).  In those cases where a baghouse is
used and the aggregate contains only a small percentage of < 200 mesh (74
material, primary collectors  are of  little  use since the rate at which  the
dust cake builds up on the filter bags is  not sufficient to enhance particle
collection between  cleaning cycles.  In addition,  drum-mix plants generally
have a lower overall  mass loading which allows a smaller capacity control
system to be used.9'10'11

     Particulate control  technology for asphalt  concrete  plants can  be
classified into  the following categories:   gravity settling or  expansion
chambers (knock-out boxes);  centrifugal collectors  (cyclones); wet scrub-
bers; and fabric filters (baghouses).

     For batch and  continuous mix plants,   settling  chambers and cyclones
(single  or multiple)  are typically employed as primary collectors, and wet
scrubbers and baghouses  are  used  for secondary control.   The types of wet
scrubbers utilized  in such facilities include gravity  spray towers, wet
fans, and  centrifugal (cyclonic), orifice  plate, and  venturi  scrubbers.
For drum-mix plants,  venturi  scrubbers and baghouses are the predominant
control  technology.   A  number of good references are available  which  dej
scribe the theory and operation of the control devices listed above,2'14 16
                                     19

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     The type of device or combination of devices installed on a particular
plant depends on the process and whether it is classified as a new facility
required to meet applicable New Source Performance Standards (0.04 gr/dscf)
or whether only state and  local regulations apply.  Table 2-5 presents the
overall distribution of  primary and secondary control devices used in the
asphalt concrete  industry  as  published in a  1977  EPA report.2   From  this
table it was determined that a dry centrifugal collector (cyclone) followed
by a baghouse (fabric filter) is the most common type of air pollution sys-
tem utilized at the time which the subject report was published.  Such a
distribution may or may not be the case at present, since the percentage of
drum-mix facilities which have generally no primary collector, has increased
significantly since 1975,2*13
         TABLE 2-5.  PRIMARY AND SECONDARY CONTROL DEVICES USED IN
                       THE ASPHALT CONCRETE INDUSTRY2
Type of control equipment
Percent of industry5
Primary collectors
  Settling or expansion chambers
  Single cyclone dust collectors
  Multiple cyclone dust collectors
  Other
          4
         58
         35
          3
Secondary collectors
  Gravity spray tower
  Cyclone scrubber
  Venturi scrubber
  Orifice scrubber
  Baghouse (fabric filter)
  Other
          8
         24
         16
          8
         40
          3
   An  accelerating  trend from gravity  spray  towers  and cyclone  scrubbers
   towards venturi  scrubbers  and baghouses has been  observed  since  1975.
   A survey  conducted  in 1983 of a  limited  number of plants showed that
   wet collectors were  used in 52.2% of the facilities and fabric filters
   in  47.8%  of  the  plant population  surveyed.   A  heavy  bias towards  scrub-
   bers was  observed in the Central and  Southern regions  of the country.
                                     20

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2.3.2  Open Dust Sources

     As stated previously, there are a number of open dust sources associ-
ated with asphalt concrete plants,  including vehicular traffic on paved and
unpaved roads, conveyor transfer points,  aggregate storage piles; and batch
load-in operations.  There are many alternative methods which could poten-
tially be employed to control  emissions from such sources.  Wet suppression
is sometimes used for the control  of fugitive dust from open dust sources in
asphalt plants.17  Other more sophisticated measures such as enclosed silos,
conveyors, etc.,  and capture and collection systems are also used to control
emissions  from open dust sources but are  generally not common in these
facilities.17

     In general, wet suppression  involves  the application of water  or a
water solution with a chemical additive (surfactant, foaming agent, or chem-
ical binder)  to  the dust-producing surface to prevent the finer particles
from becoming airborne as a result of some  type of  mechanical disturbance.
Although it  is the  exception  rather than the rule,  water  may be applied to
unpaved roads in  the plant area by a tanker truck.   In arid areas such as
the southwestern United  States where the mineral aggregate moisture is be-
low 2%, spray nozzles are sometimes installed to wet the material before it
is conveyed from one belt to another.17  Enclosures at transfer points also
may be used in conjunction with or in place of wet suppression.   Watering of
storage piles can be used if dust emissions from wind erosion and materials
handling (i.e.,  load-in, load-out)  become a problem.

     In actual practice, the  use of water  during the transfer and  handling
of the aggregate  material  is  generally avoided wherever  possible  because
whatever additional moisture  that  is  added to the  material prior  to  pro-
cessing must eventually be removed by the dryer in order to meet mix speci-
fications.  An overall  control  strategy  for a facility generally consists
of at  least  watering of unpaved roads, with additional  measures being em-
ployed on a case-by-case basis.  The specific controls used at a particular
plant depends on  individual requirements imposed by the applicable regula-
tory agency.
                                     21

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                         REFERENCES FOR SECTION 2
 1.   A  Brief Introduction  to  Asphalt and__Spme of Its Uses,  Manual  Series
     No.  5  (MS-5),  Seventh Edition,  The  Asphalt Institute, College Park,
     MQ,  1977.

 2.   Z.  S.   Khan,  and T. W.  Hughes,  Source Assessment:   Asphalt Hot Mix,
     EPA-6QQ/2-77-lQ7n,  U.S.  Environmental  Protection  Agency, Research
     Triangle Park,  NC,  December 1977.

 3.   The__Asphalt Handbook,  Manual  Series No. 4, The  Asphalt  Institute,
     College Park,  MD,  March  1960.

 4.   Asphalt Plant  Manual,  Manual  Series  No.  3 (MS-3), The Asphalt Institute,
     College Park,  MD,  March  1979.

 5.   Model  Construction Specifications for Asphalt Concrete and Other Platrt-
     Mix  Types,  Specification Series No.  1 (SS-1),  Fifth Edition,  The Asphalt
     Institute,  College Park, MD,  November 1975.

 6.   J.  A.  Crim, and W.  D,  Snowden, Asphaltic Concrete PlantsAtmospheric
     Emissions Study,  EPA-APTD-Q936, U.S. Environmental Protection Agency,
     Research Triangle  Park,  NC, November 1971.

 7.   Dryer  Principals,  Sales  Manual, p.  9205, Barber-Greene Company, Aurora,
     IL,  November 1960.

 8.   T.  D.  Sear!, et al..  Asphalt Hot-Mix Emission Study, Research Report
     75-1 (RR 75-1), The  Asphalt  Institute, College Park, MD, March 1975.

 9.   J.  i.  Kinsey,  "An  Evaluation of Control Systems and Mass Emission Rates
     from Dryer-Drum Hot Asphalt Plants," JAPCA, 26(12):1163-1165, December
  	1976.-   .._   _	_	._.  ~~"~T"    _.   .._.    ._   _____

10.   T.   W.   Beggs,  Emission of Volatile  Organic Compounds  from Drum-Mix
     Asphalt Plants. EPA-600/2-81-026, U.S. Environmental  Protection Agency,
     Cincinnati, OH, February 1981.

11.   JACA  Corporation,  Preliminary Eva!uation ofAir PollutionAspects of
     the Drum-Mix Process. EPA-340/1-77-004,  U.S.  Environmental Protection
     Agency, Washington, D.C., March 1976.

12.   Interim Guidelines for Recycling PavementMaterials,   Texas  A&M  Uni-
     versity, College Station, TX, July 1978.

13.   Written communication from Fred Kloiber, Fred Kloiber  and Associates,
     College Park,  MD,  to John  Kinsey, Midwest  Research Institute,  Kansas
     City,  MO, May 3, 1982.

14.   Control Techniques for  ParticulateEmissions  from  Stationary Sources -
     VglumeI.  EPA-450/3-81-005a,  U.S.   Environmental  Protection  Agency,
     Research Triangle Park, NC, September 1982.

                                     22

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15.   Control Techniques for Particulate Emissions from Stationary Sources_-_
     Volume II. EPA-450/3-81-005b,  U.S.  Environmental Protection Agency,
     Research Triangle Park, NC,  September 1982.

16.   S.   Calvert,  et  al. ,  Wet Srubber System Study. Volume I:  Scrubber
     Handbook,   EPA-R2~72-118a,   U.S.  Environmental  Protection Agency,
     Research Triangle Park, NC,  August 1972.

17.   Written communication from Fred Kloiber,  Fred Kloiber Associates, Col-
     lege Park, MD,  to John Kinsey, Midwest Research Institute, Kansas City,
     MO,  January 16, 1984.
                                     23

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             3.0  DATA REVIEW AND EMISSION FACTOR DEVELOPMENT
3.1  LITERATURE SEARCH AND SCREENING

     The first  step  of this investigation was an  extensive search of the
available literature  relating to the  participate emissions associated with
asphalt concrete plants.  This search included data collected under the cur-
rent inhalable  participate  characterization program,  information contained
in the  computerized  Fine  Particle Emission Inventory  System (FPEIS), back-
ground documents for Section 8.1 of AP-42 located in the files of the EPA's
Office of Air  Quality Planning  and Standards  (QAQPS),  and other reliable
sources  including  MRI's  own  library.   The search was  thorough but  not
exhaustive.   It  is  expected that certain additional  information may also
exist, but limitations in funding precluded further searching.

     Some 27 reference documents  were collected and reviewed.1 27  At the
end of this section, each document is listed in chronological  order with an
indication as to whether the document contains particle size data.

     To reduce the large amount of literature collected to a final  group of
references pertinent  to  this report, the following general criteria were
used:

     1.   The information contained in the report must characterize the emis-
       — sions by particle size.   Documents were eliminated from considera-
          tion if only total mass emissions were determined.   (This included
   	   most_of  the original  data base utilized to_derive _the existing
          emission factors  in Table 8.1-3 and Table 8.1-5 of AP-42.)

     2.   Source testing  must be a  part  of the referenced study.  Some  re-
          ports  reiterate information from  previous studies and thus were
          not considered.

     3.   The document must constitute the  original  source of  test data.
          For example,  a technical  paper was not included if the original
          study was already contained in a previous document.   If the exact
          source of  the  data could  not  be  determined,  the document was
          eliminated.

     A  final set of reference materials was compiled after a thorough re-
view of  the  pertinent reports,  documents, and  information according to  the
three criteria stated  above.  This set of documents was further analyzed to
derive candidate emission factors according to particle size.
                                     24

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3.2  EMISSION DATA QUALITY RATING SYSTEM

     As part of MRI's analysis of the available data, the final set of eight
reference documents (References 1, 3, 8, 10, 12, 23, 26, and 27) were eval-
uated as  to  the  quantity  and  quality of the  information contained  in  them.
The following data were always excluded from consideration.28

     1.    Test series  averages  reported in units that  cannot be converted
          to the selected reporting units.

     2.    Test series representing incompatible test methods.

     3.    Test series  of  controlled  emissions  for which the  control device
          is not specified.

     4.    Test series in which the source process is not clearly identified
          and described.

     5.    Test series  in  which  it is not clear whether the emissions mea-
          sured were controlled or uncontrolled.

     If there was  no reason to  exclude  a particular data set,  each was  as-
signed a  rating  as to  its quality.   The rating system  used was  that speci-
fied by the  OAQPS for the preparation of AP-42 Sections.28  The data were
rated as follows:

     A -  Multiple tests  performed on the same source using sound methodol-
          ogy .and  reported in enough detail for adequate validation.  These
          tests  do not necessarily have to  conform  to  the methodology spe-
          cified  in  the IP protocol  documents, although such methods were
          certainly used  as a guide.

     8 -  Tests  that  are  performed by  a generally  sound methodology but
          lack enough detail for adequate validation.

     C -  Tests  that are  based on an untested or new  methodology  or  that
          lack a significant amount of background data.

     D -  Tests  that are  based on a generally unacceptable method but may
          provide  an order-of-magnitude value  for the source.

     The  following criteria were used to evaluate  source test  reports for
sound methodology  and adequate detail:

     1.   Source operation.  The manner  in which the source was operated  is
          well documented in  the report.  The source was operating within
          typical  parameters during the test.

     2.   Sampling procedures.  The sampling procedures  conformed  to  a gen-
          erally  accepted methodology.   If  actual procedures deviated from
          accepted methods, the deviations  are well documented.  When this
          occurred, an  evaluation was  made of how  such  alternative proce-
          dures  could  influence the test results,

                                     25

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     3.    Sampling and process data.   Adequate  sampling and process data
          are documented in the report.  Many variations can occur without
          warning during testing and sometimes without being noticed.   Such
          variations can induce wide deviations in sampling results.   If a
          large spread between test results cannot be explained by informa-
          tion contained in the test report, the data are suspect and were
          given a lower rating.

     4.    Analysts and cajculations.   The test reports contain original raw
          data sheets.The nomenclature  and equations used were compared
          to those specified by EPA (if any) to establish equivalency.   The
          depth of review of the calculations was  dictated by the reviewer's
          confidence in the ability  and conscientiousness of the tester,
          which in turn was based on factors such  as consistency of results
          and completeness  of other areas of the test report.

3.3  PARTICLE SIZE DETERMINATION

     There is no one method which is universally accepted for the determina-
tion of particle  size.  A  number of different techniques can be  used which
measure the size of particles according to their basic physical  properties.
Since there is no "standard" method(s) of particle size analysis, a certain
degree of  subjective evaluation was used to  determine  if a test  series was
performed using sound methodology.   The following is a brief explanation of
how particle size is defined and the various methods available for particle
size measurement.

3.3.1  Particle Size Definitions

     Examination of particles with the aid of an optical or electron micro-
scope involves the physical measurement of a linear dimension of a particle.
The measured "particle size" is related to the particle perimeter or to the
particle projected area diameter.   Particle size measurement in this manner
does^not account for variation in^particle~density or^shape.29

     All  laws  describing the  properties of aerosols can be expressed most
simply for  particles  of spherical  shape.   To accommodate nonspherical  par-
ticles it is customary to define a "coefficient of sphericity" which is the
ratio of the surface area of a sphere with the same volume as the given par~
tide to the surface area of the particle.29  An estimate of particle volume
can be obtained from microscopic sizing, and by assuming a density, one can
obtain an estimate of particle weight.

     Because of large variations in particle density and the aggregated na-
ture of atmospheric particles, it is useful to define other quantities as a
measure of  particle size based  on  their aerodynamic  behavior.  The  Stoke's
diameter  is  defined as the diameter of  a  sphere  having the same settling
velocity  as  the  particle  and a density equal to that of the bulk material
from which the particle was formed, or30:
                                     26

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                             is vs n

                    °s = \/ g e C(DS)   ^r Re < 0.5                  (1)
where:
        D  = Stoke1s diameter (cm)

        V  = terminal settling velocity of a particle in free fall (cm/sec)

         H = viscosity of the fluid (gm/on-sec)

         g = gravitational constant (980.665 cm/sec2)

         & - density of the particle (gra/cm3)

     C(DS) - Cunningham's slip correction factor for spherical particles
             of diameter D  (dimensionless)

                                                                      (2)
                         A = a + p exp(-y DS/2A)                      (3)


     a  = empirical  constant (dimensionless) =.1.23 - 1.246
     P  = empirical  constant (dimensionless) = 0.41 - 0.45
     Y  = empirical  constant (dimensionless) = 0.88 - 1.08
     A.  = mean free  path of the fluid at stated conditions (cm)
        = X0 (q/n0)  (T/T0)°'5 (pQ/p)                                  (4)

     A  = mean free  path at reference conditions (cm)
     H  = gas viscosity at stated conditions (gm/em*sec)

          gas viscosity at reference conditions (gm/cm«sec)
     T  = absolute temperature (°K)
     T  = reference temperature = 296.16°K
     P  = absolute pressure (kPa)
     p  _ reference pressyre = 101.3 kPa
     Re = Reynold's number (dimensionless)


     For particles greater than a  few microns in diameter, a less rigorous
form of  Equation 1 can  be used with reasonable accuracy according to the
rel ationship: 31 )32
                                     27

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                                    - e')g
                                               Re < 0.05
                                                                      (5)
where:
      i  9» DS» and n
                         as defined above; and
      ' = density of air at the appropriate temperature and pressure
            (gm/cm3)
     Since dispersion and condensation aerosols are usually formed from many
materials of different densities, it is more useful to define another param-
eter called the aerodynamic diameter, which is the diameter of a sphere havin
the same falling velocity as the particle and a density equal to 1 g/cm3.29'3
The classical  aerodynamic  diameter differs from the Stoke's diameter only
by virtue  of  difference'in density, assumed  equal  to  unity, and  the  slip
correction factor,  which,  by  convention,  is  calculated for  the aerodynamic
equivalent diameter.  From Equation I:30
                                       gC(DAe)
                                                                      (6)
where  0.  = "classical" aerodynamic equivalent diameter (cm), with n»
        'Ae
                  g, C as previously defined in Equation 1.
     Equations required for interconversion between Stoke1s and aerodynamic
diameters are presented in Table 3-1.30

3.3.2  Particle Size Measurement
     As
certain
inertia!
characteristics.
either  directly
        stated previously  above,  particle size is determined by measuring
        physical properties of the particulate being analyzed,  such as its
        ,  light  scattering,  sedimentation,  diffusional,  and electrical
                  The  size distribution of an aerosol  can  be determined
                at  the source (i.e., stack or vent) or indirectly by the
collection of a bulk sample of the material for subsequent analysis in the
laboratory.  In either case,  the  instrument(s) utilized to make  such a de-
termination can be  manual  or  automated depending on the  individual tech-
nique.

     The five basic methods for the direct measurement of particle size are:

     1.   Aerodynamic separators (cascade impactors, cyclones, elutriators,
          etc.)

     2.   Light-scattering optical particle counters
                                     28

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        TABLE 3-1.   EQUATIONS USED FOR PARTICLE SIZE CONVERSIONS30
Diameter definition
(given)
Stoke1
s diameter

Stoke 's
diameter (D )
1.0
Conversion equation

Classical aerodynamic
equivalent diameter (D. )
"pC(
n - n
°Ae °s CTD
Ds)1 W
Ae}.
Classical
aerodynamic
diameter (0A ) D-D.
Ae s Ae
" C(DAe) "
. PC(Ds) -
j./t
1.0
   Notation:   D   = Stoke's diameter (um)
              D.  = Classical  aerodynamic equivalent diameter (pm)
              p   = Particle density (g/cm3)
              C(D ), C(D/. ), = Slip correction factors (dimension!ess)—
                                 see Equations 2, 3, and 4,

     3.    Electrical mobility analyzers
     4.    Condensation nuclei  counters
     5.    Diffusion batteries
All of the above are extractive methods, with the exception of certain aero-
dynamic separators.
     Indirect methods  for  the  determination of  particle  size include:
     1.   Sieving (wet, dry, sonic)
     2.   Sedimentation
     3.   Centrifugation (inertia! separation)
     4.   Microscopy (optical and electron)
     5.   Others (acoustic,  thermal, spectrothermal emission)
                                     29

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     Table 3-2 provides a guide as to the various methods for the determina-
tion of particle  size  based on certain physical properties of the particu-
late and  notes  the size range in which  each is generally applicable.33

     In most  respects  instruments that fractionate  an aerosol on the basis
of the aerodynamic properties of its components probably give the best prac-
tical assessment  of size.  Once flow conditions have been selected for the
device, the terminal settling velocities of the particles collected in each
stage or part of the instrument can be determined, even though particle spe-
cific gravity and shape factor are unknown.30  Unless the particle shapes
are extremely irregular,  the  details of precise geometric form can be by-
passed and  the  likelihood of the particle's  capture by  a dust-collecting
system can still be determined.  Because the correct assessment of particle
size properties  is  essential  for the development of appropriate emission
factors, an assessment by  aerodynamic techniques was emphasized  in review-
ing and rating the individual data sets for sound methodology.

     Examples of  aerodynamic  particle  sizing instruments are centrifuges,
cyclones, cascade  impactors,  and  elutriators.  Each of  these instruments
employs the unique  relationship between a particle's diameter and mobility
in gas or air to collect and classify the particles by size.   For pollution
studies, cyclones  and  impactors  (primarily  the  latter) are more  useful be-
cause they  are  rugged  and compact enough for j_n  situ sampling.   j[n situ
sampling is preferred  because the measured size distribution may be dis-
torted if a probe is used for sample extraction.  In the following two sub-
sections, methods of using impactors and cyclones are discussed.

3.3.2.1  Cascade  Impactors—
     Cascade  impactors  used  for the  determination of particle size in pro-
cess streams consist of a series of plates or stages containing either small
holes or  slits  with the size of the openings decreasing from one plate to
the  next;-.  In each  stage  of  an impactor, the  gas  stream  passes through the
orifice or  slit to form a jet that is directed toward an impaction plate.
For each--stage-there-fs a characteristic particle^diameter that-has a 50%
probability of  impaction.  This characteristic  diameter  is called the cut-
point (Den) of  the stage.   Typically, commercial instruments have six to
eight impaction  stages with  a back-up filter to  collect those  particles
which are  either too  small to be collected by the  last stage or which are
reentrained off  the various  impaction surfaces  by the moving gas stream.34

     The particle collection  efficiency of  a particular  impactor jet-plate
combination is determined by properties of the aerosol such as the particle
shape and  density,  but the viscosity of the  gas, and by the design of the
impactor stage.   There is also a slight dependence on the type of collec-
tion surface  used (glass  fiber,  grease, metal,  etc.).   Reentrainment, or
particle bounce,  is a  significant problem with cascade impactors especially
in  the  case of  high particulate  loadings.   This  problem can ba  partially
solved by  using a preseparation device ahead  of the impactor to  reduce the
overall loading of coarse particles.
                                     30

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  TABLE 3-2.   GUIDE TO PARTICLE SIZE MEASUREMENT33
                                      Diameter of
                                     applicability
          Method                          (urn)
Optical
  Light imaging                      0.5+
  Electron imaging                   0.001-15
  Light scanning                     1+
  Electron scanning                  0.1+
  Direct photography                 5+
  Laser holography                   3+

Sieving                              2+

Light scattering
  Right angle                        0.5+
  Forward                            0.3-10
  Polarization                       0.3-3
  With condensation                  0.01-0.1
  Laser scan                         5+

Electrical
  Current alteration                 0.5+
  Ion counting, unit charge          0.01-0.1
  Ion counting, corona charging      0.015-1.2

Impaction                            0.5+

Centrifugation                       0.1+

Diffusion battery    ,                0.001-0.5

Acoustical
  Orifice passage                    15+
  Sinusoidal vibration               1+

Thermal                              0.1-1

Spectrothermal emission              0.1+
                         31

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3.3.2.2  Cyclone Separators--
     TraditionaHy, cyclones have  been  used as a preseparator ahead of a
cascade impactor to remove the larger particles.  These cyclones are of the
standard reverse-flow design whereby the aerosol sample enters the cyclone
through a tangential inlet and forms a vortex flow pattern.   Particles move
outward toward  the  cyclone wall  with a velocity that is determined by the
geometry and  flow  rate  in the cyclone and by their size.   Large particles
reach the wall and are collected.

     A series of  cyclones with progressively decreasing cut-points can be
used also  instead  of  impactors to  obtain particle size distributions.  The
advantages are  that larger samples are acquired, particle bounce is not a
problem, and  no substrates are required.   Also, longer sampling times are
possible with cyclones,  which  can be an advantage at very dusty streams,
but a  disadvantage  at relatively clean streams.  One such series cyclone
system was developed by an EPA contractor specifically for the IP program.38

3.4  REVIEW OF SPECIFIC DATA SETS

     The following  is  a discussion of the data contained in each of eight
primary reference  documents.   The  documents  are presented according to the
Reference  number  indicated at  the end of this  section  and  their date of
publication.

3.4.1  Reference 1  (I960)

     Reference lisa technical  paper published in the Journal of the Air
Pollution Control Association, which presents the results of 25 tests con-
ducted by personnel of the Los Angeles County Air Pollution Control District
beginning  in  1949.   Included in  this document are emissions data for batch
and continuous mix  asphalt plants controlled by either a multiple centrifugal
scrubber or a baffled spray tower.  In five of these tests,  a particle size
distribution was  obtained at both the inlet and outlet  of  the scrubber.
The~information"contained  in Reference 1 was^later repubtished in the first
(1967) edition of the Air  Pollution Engineering Manual (EPA document AP-40).
The data were again included in a  second edition of  the  same document in
1973.  A summary of the five tests which contain particle size data is shown
in Table 3-3,  and a copy  of the  paper  itself  is contained in Appendix A.

     There were a number of deficiencies noted in  the  data contained in
Reference  1.   The main problem was that a test method was not specified for
either  total  mass emissions or particle size.   In addition, data were not
available  on  the operation of the process,  the raw material used, or the
exact  configuration of  the plants tested.  As  far as could be determined,
only one set  of samples was collected during each test included in Refer-
ence 1.

     The data published by Los Angeles County have been cited repeatedly in
numerous reports on the emissions from asphalt  concrete plants.   An attempt
was therefore  made to supplement the information contained in Reference 1
by both written and verbal communication  with  personnel of the  South  Coast
Air Quality  Management  District (SCAQMD) (formerly the Los Angeles County


                                     32

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                                  TABLE  3-3.   SUMMARY OF PARTICLE DATA  - REFERENCE la



                                                         Data Rating:   D
'•
Test
series
No.
C-393
C-369
C-372A
C-372B
C-422(l>
a c
Fro.e:
Inlet dust
loading.
(Ib/hrf
4,260
352
76
121
-
Tables I and
Outlet dust
loading.
(Ib/hr)
26.9
24.4
10.0
19.2
26.6
II. p. 31 of

Type of
scrubber
T
C
C
c
c
Ingel, et at.
Production
rate .
(tons/hr>a
92.3
113.0
158.0
142.9
198.0
, "Control of

Inlet
0-10 Jin
13.0
76.4
78.0
91.0
80.48
Asphaltic

particle
10-20 ua
71.1
6.3
18.0
9.0
18. 6«
Concrete

size (X weight)6
20-44 [in > 44 (in
9.6 6.3
2.8 14,5
2.0 2.0
0 0
l.O9 O8
Plants In Los Angeles

Outlet
0-10 |.m
99.3
79.9
83.0
82.0
73.2
County," J.

particle
10-20 (in
0
3.8
5.0
3.0
5.1

size (%
20-44 i
0
2.0
1.0
2.0
4.5

weight)6
in > 44 [ta
0.7
14. 3f
11. Of
13. Of
17.2
Air Pol Hit. Control Assoc. ,
   1011}:29-33, Feb.  1960 (Appendix A).  .



b  1 Ib/hr = 0,454 kg/hr.



   C = multiple centrifugal spray scrubber; T = baffled spray-tower.



   Assumed to be short  tons (2,000 Ib) per hour of asphalt paving produced.  1 short ton/hr = 0.907 metric  tons/hr = 0.907 (10)° gm/hr.



   SLoke's diameter.



   Microscopic examination Indicated agglomerated particles.



"  Data  not used for emission factor development.

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Air Pollution Control  District)  to obtain copies of the original  reports
for the subject tests,36  Only in two cases (Nos. C-393 and C-426) was this
effort successful.37'38   Upon reviewing the two  reports supplied by the
SCAQMD, it was concluded that there was still insufficient information con-
tained in the documents from which to ascertain the exact equipment and pro-
cedure used  to  determine  the total mass emissions from each plant and the
particle size distribution.  Tables 3-4 and 3-5 summarize the data obtained
from Tests C-393 and C-426,  respectively, with copies  of the original test
reports included in Appendix A.

     To fill  in the gaps  in  the  available information, a telephone conver-
sation was held with Mr. William Krenz, Manager of Source Testing and Moni-
toring for the  SCAQMD.39   It was learned from Mr. Krenz that the sampling
apparatus used by Los Angeles County during that time period to measure the
total mass emissions from a process was similar to the standard EPA Method 5
sampling train with the exception  that the  filter was  installed downstream
of the wet irapingers.   According to his best recollection,  the particle size
distribution was obtained by introducing a sample of dried particulate mat-
ter caught in the impingers of the sampling train into a commercially avail-
able instrument called a  "Micromerograph."   The  Micromerograph consists  of
a sample feeder and  deagglomerator installed atop a gravity sedimentation
column at the bottom  of which is an electronic torsion balance.   This in-
strument measures  the size  distribution  of the  sample according  to  the
Stoke's settling velocity of the particles.  Both the sampling train and
the Micromerograph are described in a source test manual published by the
Los Angeles  County Air Pollution Control District (APCD).40  A technical
paper describing the  Micromerograph and its operation has  also  been in-
cluded in Appendix A.41

     The information  obtained from Reference 1 and that subsequently ob-
tained from  the SCAQMD is somewhat sketchy.  It would also be expected that
the method used to determine the particle size distribution may not provide
data that are entirely representative of the actual emissions from the pro-
cess-since the finer particle'" fraction wou1thbe~ collected on the "filter and
not in the impinger train.  The  size distribution could also be affected by
agglomeration of the  particles during preparation of  the  sample  prior  to
analysis.  Based on  these factors and  taking  into consideration  the time
period during which the data were collected, a data quality rating of D was
assigned to  the information contained  in Reference 1.

3.4.2  Reference 3 (1967)

     Reference 3 is a technical  paper published  in the English version of
Staub-Reinhalt, Luft outlining the results of a major research program con-
ducted in West Germany of the emissions from asphalt concrete plants.  Some
35 individual tests were  conducted at 10 different facilities during the
sampling program.   These  data were then compared  against 83 additional tests
at 27 other  facilities as performed by other investigators.  During  the pro-
gram, measurements were made of  the total dust loading in the dryer exhaust
as well  as  at the discharge of  the primary and secondary dust collectors.
In every  case but  one, the control  system generally  consisted of  multiple,
large  diameter  cyclones  arranged  in  parallel  followed by a single,  low


                                      34

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    TABLE 3-4.   SUMMARY OF PARTICLE SIZE DATA FOR
                  TEST NO.  C-39337

                Data Rating:   D

Particle size range
(umsr
0-10
10-20
20-44
> 44
Percent
Inlet to
scrubber
13.0
71.1
9.6
6.3
by weight
Outlet from
scrubber
99.3
-
-
0.7

   Stoke1s diameter.

   Data taken from page 5 of Reference 1 (Appendix A).

c  Baffle plate scrubber.  Inlet to scrubber = outlet
   from a single large diameter cyclone collector.

   Outlet data not used for emission factor development.
                           35

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 TABLE 3-5.   SUMMARY OF PARTICLE SIZE DATA FOR TEST NO.  C-42638

                        Data Rating:   0
      iize
  200 mesh (74 jjm) deter-
mined by sieve analysis was also assumed to be Stoke1s diameter.
Data taken from page 9 of Reference 1 (Appendix A).  Data for par-
ticles > 60 umS not input to SPLIN2 program (see Section 3.5.2).

Inlet to multiple centrifugal scrubber.  Includes combined effluent
from cyclone and vent line.

Scavenger control system vent line.  Includes hot side elevator,
screens, bins, and weigh hopper.

Data not input to SPLIN2 program (see Section 3.5.2).
                                 36

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energy wet  scrubber.  The particle size distribution was  determined  on  the
uncontrolled emissions from the dryer and at the exit of the primary collec-
tor.  Exactly how such samples were obtained is not specified in the document.
A copy of Reference 3 is provided in Appendix 8.

     As far as can be determined, the particle size data included in Refer-
ence 3 was obtained by taking a dry sample of the dust caught in the sample
train and analyzing  it  utilizing a Gonell air elutriator according to VDI
Directive 2031,  "Fineness Determination  of Technical  Dusts."  The Gonell
elutriator consists of a long brass tube with a conical  base.42  The sample
is placed in the inlet cone with an upward stream of air  blown through  the
column at varying velocities  to  achieve separation.  The  theory  is that as
the air moves vertically upward it carries with it particles whose gravita-
tional settling velocity is  less than the velocity of the carrier gas.  The
amount of material remaining  in  the instrument  is weighed and the test  re-
peated to complete the  particle size analysis.   A summary of the particle
size distribution of  the  uncontrolled emissions from the plants tested is
shown in Table 3-6,  and  Table 3-7 provides the  size  distribution of the
dust exiting the primary collector.

     Although the data contained in  Reference 3 were derived from plants
located in  West  Germany, it is  felt that  these  data can also be  considered
as characteristic of U.S.  facilities as well.   This opinion is based on the
fact that in many cases the, Germans utilize plant equipment which is manu-
factured in the  United  States.43  In addition, the type  of aggregate and
asphalt cement  used  is  also  reasonably similar  to  that which is avail-
able in this country.43   For  the above reasons, the data included in Ref-
erence 3 were included in the development of candidate emission factors for
conventional asphalt plants.

     The emissions  data  in  Reference 3 are of  fairly good quality  even
though there are significant  gaps  in the sampling protocol  used.  As with
the data contained in Reference 1,  the size distribution of the particulate
was determined indirectly through the use of a laboratory instrument, which
can cause a certain degree of bias in the test results.   Due to the lack of
sufficient  documentation on the exact methods used to collect and analyze
the samples and detailed information on the process operating parameters of
the plants  tested, it is  difficult to ascertain the representativeness of
the results obtained.  For these reasons,  a rating of C was assigned to the
data included in Reference 3.

3.4.3  Reference 8 (1971)

     Reference 8  presents the results of  a study conducted by an EPA con-
tractor, of the atmospheric  emissions from batch and continuous mix asphalt
concrete plants.   In this study, original  source tests were conducted of the
total mass emissions from five individual  plants using both EPA Method 5 and
a sampling train developed by the Los Angeles County APCD.40  An industrial
survey was also conducted as part of the study to obtain whatever data were
available from  other sources on both mass  emissions  and particle size.
                                      37

-------
CO
                      TABLE  3-6.   SUMMARY OF PARTICLE  SIZE  DATA FOR UNCONTROLLED EMISSIONS - REFERENCE 3(




                                                          Data Rating:  C
i I
Dust in the drum
exhaust gases
1.

1.1






1.2
1.3
2.



2.1


For washed raw
material In
manufacture of
Fine asphaltic
concrete 0/8





Binder 0/18
Base 0/35
For half-
washed raw ma-
terial in the
manufacture of
Fine asphaltic
concrete 0/8

Plant
10 No.


A4
01

112
A
I2d
ft
13d
02




Cl

C2
Raw dust
concen-
tration
Raw naterial (g/«» STP)


Moraine * Rhine sand
Basalt + natural
sand
Basalt + line +
natural sand
Basalt + lime +
blast furnace slag
Line + Rhine sand
Basalt + natural sand




Basalt * moraine +
Rhine sand



28.6
33.4

26,2

39.1

29.3
29.9




69.9

69.5
Waste
gases per
metric
ton (a*h
STP/MT)


330
630

470

540

SOO
630




520

520
Uncon-
trolled
ealsslgn
factor
(kfl/HT)


9.
21,

12.

21.

14.
18.




36.

36.


4
0

3

1

7
8




3

1
particle
Particle
density
(B/CB»)


2.4
2.6

2,6

2.9

2,7
2,9




2.5

2.5
< 0.2
cm/sec


10.5
7.0

8.7

10.8

13.7
15.1




6.9

7.6
< 0.4
cm/ sec


16.7
13.1

17,0

14.0

29,1
25.0




13.8

16.9
Raw dust in the drus waste gases
size distribution by settling velocity intervals
(wetqht proportion in %)
< 0.8
cm/ sec


23.2
18.2

23.4

17.2

40.9
41.1




22.0

24.9
< 1.6
cm/ sec


28.6
22.6

27.6

25.1

49.2
58.1




29.6

31,7
< 3.2
cm/sec


34.3
26.7

33.4

34.5

58.1
65.4




37.2

37,4
< 6.4
cm/ sec


39.7
28.8

36.2

38.5

64.7
67.0




45.9

42,6
< 12.8
cm/sec


46.0
32.0

45.9

47.2

70.2
69.1




54.7

50.9
< 25.6
en/sec


57.1
38.2

59.1

64.1

80.9
73.3




74.1

58.9

	 > 	 2576
cm/sec


42.9
61.8

40.9

35.9

19.1
26. 7




25.9

41,1
                                                             (continued)

-------
                                                                  TABLE  3-6.    (concluded)
10


Dust in the drura
exhaust oases
3. for unwashed
raw material
in the nanu"
facture of
3.1 fine asptialtic
concrete 0/B




3.2 Binder 0/12
3,3 Base 0/30
Base 0/35


Plant
10 No,




B3

04
F3
G2
K4
Cl
Bl
F2



Raw Material




Blast furnace slag *
Rhine sand
Basalt
LI ae stone
Li lies tone
Linestone
Diabase * line
Gravel
Rhine gravel
Raw dust
concen-
tration
(fl/n' SIP)




133.5

116.5
119.1
117,0
111.2
103.2
53.1
52.0
Uait«
gases per
•elHc
ton {»*.
sip/tnr




350

640
310
260
460
270
300
280
Uncon-
trolled
eaisstgn
factor
(kft/H?)




46.7

74.6
36.9
30.4
51.2
27.9
15.9
14.6
particle
Partict*
dens 1 ty
(g/c«>)




2.6

2. a
2.4
2.5
2.7
2.S
2.5
2.5

< 0.2
cm/ tec




4.2

15.9
11.0
8.3
1.5
5.9
3.6
16. 5

< 0.4
ca/sec




7.7

26.8
19.8
20.1
2.1
16. S
S.I
24.0
Raw dust in the dri» waste gases
siie distribution by settling velocity intervals
(
< 0.8
CB/sec




12.5

41.5
27.7
37.0
2.9
29.1
7.0
32. S
weight proportion in X)
< 1.6
CB/sec




18. 3

53.8
35.5
50.2
3.8
3S.1
8.9
41.S
< 3.2
CB/SCC




25.4

61.5
43.2
59.6
4.6
43.8
10.9
45.6
< 6,4
CB/sec




32.7

67.6
48.9
66,7
6.3
53.9
12.8
48.5
< 12. B
CB/sec




41.4

72.0
57.6
72.1
10.5
66.0
16.3
53.0
< 25.6
en/sec




56.7

80.6
66.9
82.5
16.3
81.9
23.7
60.4
> 25.6
CB/sec




43.3

19.4
33.1
17.5
63. 7
18.1
76.3
39.6
          Data taken  froa Tables 3 and 8, pgs. 12 and 20 at Reference 3 (Appendix B).  Assumed to be dryer exhaust only.   Minor differences in raw dust concentration
          noted between Tables 3 and 8 for Plant ID's B3, C2,  and D4.

       b  Assumed  to  be metric tons (NT) of asphalt concrete produced.  1 MT 3 1.1 short tons a 2,200 Ib = 10° g*.

       c  Calculated  from data In two previous columns.   For example:  28.6 jf X 3JO g| x |-||^ •  = 9.4 kg/Hi


          Same tests  as J2 and J3 shown In original reference  dacunent.

-------
TABLE 3-7.  SUMMARY  OF PARTICLE SIZE DATA FOR THE DUST  EXITING THE PRIMARY COLLECTOR -
REFERENCE 3a
Data Rating: C
•







Total mss

1.


1.1


1.2
1.3
2.


2.1
Oust in the driu
waste gases
For washed raw mate-
rial in the manu-
facture of
Fine asphalttc con-
crete 0/8


Binder 0/1B
Base 0/35
For half-washed raw
material In the Manu-
facture of
Fine asphaltic
concrete 0/8
Plant
10 No.



A4
Dl
H2
12°
n9
D2



Cl
C2
cone. Total gas
exiting volumetric
collector flow rate .
Raw eater lal (g/m1) (101 aVlir)



Moraine * Rhine sand
Basalt + natural sand
Basalt + lloe +
natural sand
Basalt + UM + blast
furnace slag
Line + Rhine sand
Basalt + natural sand



Basalt * moraine »
Rhine sand



0.673 17.0
3.23 48.6
1.70 21.2
0'.B2 27.5
2.12 26.4
4.90 46.2



2.39 44.3
2.72 45,3
Production
rate
(HT/hr)c



25
60
35
40
40
60



60
60
Emission
factor.
(kg/Ml)0



0.458
2.62
1.03
0.56
1.40
3.77



1.77
2.05
Proportion of dust
Intervals (Stoke
0-10



23.2
18.2
2S.4
17.2
40.9
41.1



22.0
24.9
\m 10-20 |IB



11.1
8.5
10.0
17.3
17.2
24.3



15,2
12.5
In particle
's diameter]
20-40 un >



11.7
5.3
12.5
12.7
12.1
3.7



17. S
13.5
|tze
40 UB



54.0
68.0
54.1
52.8
29.8
30.9



45.3
45.3
No. of
cyclone.
eleaents



4
2
IB
20
20
2



6
6
                                       (continued)

-------
                                                        TABLE 3-7.   (concluded)
Oust in the drum
waste gases
Total mass
cone. ' Total gas
exiting volumetric Production Emission
Plant collector flow rate . rate factor.
ID (to. Raw material (g/B*) (10» •Vhr) (MT/hr) (kg/MT)
Proportion of dust in particle size
intervals (Stoke* s diameter)
0-10 urn 10*20 n»
20-40 |tn :
» 40 |in
No. of
cyclone,
elements
3. For unwashed raw mate-
rial in the manufacture
of
3.1 Fine asphaltfc
concrete 0/fl




3.2 Binder 0/12
3. 3 Base 0/30
Base 0/3S
*T 8 Multiple cyclone dust
significant figures.
At actual temperature
c Assumed to be metric
Calculated from data
* Density assumed equal
" C«fttrt Tik1~ 1 ^ 1A *

83 Blast furnace
Rhine sand
D4 Basalt
F3 Limestone
G2 Limestone
K4 Limestone

slag + 2.
12.
6.
10.
3.
Gl Diabase + line 8.
Bl Gravel 0.
F2 Rhine gravel
collectors. Data taken
and pressure.

27
9
10
3
08
3
916
3.12
from Table 3, p. 12, and

tons (HT) of asphalt concrete produced.
in three previous columns
to 2.6 B/cm».

For example:



1 HT s 1.
0.673 J



34. i
44.5
27.0
26.3
43.0
30.8
34.4
25.6
Table 9

1 short
1 x 17.0



64
55
70
90
75
80
70
70
, p. 22 of the

ton s 2,200 Ib
(ioj» g x 5r



1.22
10.4
2.35
3. OB
1.77
3.20
0.449
1.14
Reference 3

= 108 gm.
Iffi j, J k9
HT * 1.000 g



12.5
41.5
27.7
37.0
2.9
29.1
7.0
32.5
(Appendix B).


' °-45a $



12.9
20.0
15.5
22.6
1.7
14.7
3.9
13.1

16.0
10.5
14.4
12.5
5.9
22.2
5.4
7.4
Calculations rounded











58.6
28.0
42.4
27.9
89.5
34.0
83.7
47.0
to three






21 * 12*1
2
6
4
6
21 * 12h
6






Same  tests as J2 and J3 shown In original reference document.
Two sets of cyclones In series.

-------
     Four particle  size  distribution curves are presented  in  Reference  8
with two of these curves representing plants with centrifugal scrubbers and
the remaining  data  representing plants with spray towers.   There  is  no in-
formation contained in the report on either the plants tested or the methods
used to  determine  the particle size distributions,   A copy of Reference 8
is provided in Appendix C.

     To augment the particle size information contained in Reference 8, the
EPA contractor who  performed the  study was  contracted  to  extract  the orig-
inal data used to  prepare the four particle size distribution curves men-
tioned above  from  the project files.44  From this  effort,  three  separate
test reports  were  supplied to  MRI consisting of  data collected by CMI Sys-
tems of  Chattanooga,  Tennessee.   Two of these tests were determined to be
suitable for the development candidate emission factors.45'46  Summaries of
these data  are shown in Tables 3-8  and  3-9, respectively,  with copies of
the original reports provided  in Appendix C.

     The two  CMI documents mentioned above  provide  the results of particle
size tests conducted at two batch-mix asphalt plants controlled by a single
cyclone  dust  collector,  followed  by a wet  scrubber.   One of these plants
was equipped  with  a spray tower (Sloan)  and the  other  a centrifugal  scrub-
ber (Harrison).  Samples were  collected both downstream of the cyclone (in-
let to the  scrubber) and from the  exhaust  stack (outlet  of the scrubber)
utilizing an  Andersen nine-stage, in-stack cascade  intpactor.  This equip-
ment is not fully described in the test reports themselves but is explained
in  some  detail  in  the third document received  from the EPA contractor,47
As  far as  could be determined, two  sets of samples were  collected at the
Sloan plant  and  one set at the Harrison facility.   The sampling  duration
for all particle size tests was 5 min.

     The tests  conducted by  CMI Systems were generally based  on  accepted
methodology but  do  lack documentation on process operation,  type of raw
material utilized,  and  certain key  information with regard to the collec-
tion -and analysis-of--the samples.—In addition, the small  number—of--test
runs and their short duration would  somewhat decrease the  overall repre-
sentativeness  of the data over the  entire  range of process operating con-
ditions.   Due  to these  considerations,  a rating of B  was assigned to the
information  contained in Reference 8 and the  supplementary test reports
supplied by the EPA contractor.

3.4.4  Reference 10 (1972)

     Reference 10  is  a  report of a  source  test  conducted by Glen Ode 11,
Consulting  Engineer,  of an  uncontrolled Shearer process  drum-mix asphalt
plant owned  by Page Paving Company.   This plant  is  unusual  in  that the as-
phalt cement  is  added to the  aggregate  before  it  enters the drum mixer.
The total mass emissions  from  the process were determined utilizing a modi-
fied version  of EPA Method 5  with  the filter installed downstream of the
third impinger.  This modification  was made to  reduce  plugging of the fil-
ter with asphaltic material, which occurred  in the  normal configuration.   A
crude determination  of  particle size was made by microscopically  examining
a  sample of the particulate collected on one  of the  filters  (Run 1).  A
                                     42

-------
TABLE 3-8.   SUMMARY OF PARTICLE SIZE DATA FOR SLOAN CONSTRUCTION COMPANY44
                             Data Rating;  B
Particle size
                     Inlet to scrubber
             Percent by
               weight
                       Emission rate
                          (Ib/hr)
                                               Outlet from scrubber
                            Percent by
                              weight
                         Emission rate
                            (Ib/hr)
30 and larger
  9.2
  5.5
  3.3
  2.0
  1.0
  0.3
  0
    30
    9.2
    5.5
    3.3
     ,0
     .0
2.
I.
1 - 0.3
 Total
27.7
19.0
14.8
13.3
12,2
 9.5
 2.3
 0.7
596
409
318
286
262
204
 50
 15
54.8
 9.2
 8,3
 4.7
 4.4
 4.9
 8.0
 5.7
                                   2,135
                                                          181.0
   Aerodynamic diameter.

   Downstream of a cyclone collector.   Data taken from page 8 of test re-
   port (Appendix C).

   Outlet of a spray tower.   Data taken from page 8 of test report (Appen-
   dix C).
      TABLE 3-9.   SUMMARY OF PARTICLE SIZE DATA FOR HARRISON, INC.45
                             Data Rating:   8
Particle size
(umA)
30 and larger
5.5-30
2.0-5.5
Smaller than 2.
Total
Inlet to
Percent by
weight
23.1
26.9
35.1
0 14.9
100
scrubber
Emission rate
(Ib/hr)
396.2
461.3
602.0
255.5
1,715.0
Outlet
Percent by
weight
3.0
2.2
6.8
88.0
IoT~
from scrubber
Emission rate
(Ib/hr)
1.9
1.4
4.3
55.4
SO

Aerodynamic
diameter.


£* «. £ 4i «. -. 4* w.-*
   port (Appendix C).

   Outlet of a centrifugal scrubber.  Data taken from page 6 of test report
   (Appendix C).
                                      43

-------
 log-normal  distribution was constructed from this particle size data using
 a  number of somewhat questionable  assumptions.

     The information contained in Reference  10  is  well  documented and  in-
 cludes  adequate detail  for evaluation.   The method  used  to determine parti-
 cle size is, however, inappropriate for any type of quantitative analysis.
 For this reason, Reference 10 was not used in the development of candidate
 emission factors,  and no copy of  such  is included in this document.

 3.4.5   Reference 12 (1973)

     Reference  12 is the 1973 version  of the  Air Pollution Engineering  Manual
 published by the Los Angeles  County  APCD.   This  document contains  one addi-
 tional  data set  (Test  No.  C-537)  which was  not  included in  Reference  1.
 This data set provides a characterization of the emissions from a 6,000-lb
 capacity asphalt batch plant  equipped  with a  low efficiency cyclone, a  mul-
 ticyclone (multiple small  diameter  cyclones),  and  a multiple centrifugal
 scrubber.   The  particle  size  distribution was  obtained  for the dryer ex-
 haust,  the vent  line  from the scavenger system, downstream of the primary
 cyclone, and at the inlet  to the scrubber.  A summary of the data for Test
 No.  C-537 contained in Reference  12  is provided  in  Table 3-10 with applica-
 ble sections of the document  included  in Appendix D.

     Since the  particle  size data contained  in Reference 12 is of the same
 vintage as that  described  previously  for Reference 1,  an identical  rating
 of D was assigned to it.

 3.4.6   Reference 23 (1976)

      Reference  23 is a report of  source tests conducted  by an EPA  contractor
 to measure the  emissions from an  experimental drum-mix  plant  processing re-
 cycled  asphalt  pavement.   Particulate  emissions  from the plant were con-
 trolled by a venturi  scrubber and associated inertia!  separator for mist
-elimination.—Concurrent-tests were conducted at both the inlet and outlet
 of the  scrubber  using  EPA Method 5  or a modified version of  EPA Method 8.

     Three separate operating conditions were tested.   The first operating
 scenario (one test) consisted  of  the  introduction  of the recycle  material
 at the  midpoint  of the drum  mixer.   During the  second  operating condition
 (three  tests) recycle material was introduced at the burner end of the  drum
 along  with the  virgin aggregate.   The  final operating condition (three  tests)
 consisted of injection  of  the recycle material  at  the  burner end  but with
 the inclination of the drum increased from 2  to 2.98 degrees.   ParticTe siz-
 ing was performed  during the second and third conditions using an Andersen
 9-stage cascade impactor and  a standard EPA Method  5 sampling train.

      The only data in Reference 23 which  are applicable  to current  process
 technology for  the recycling of  asphalt pavement are that obtained during
 the first operating condition (see Section 2.2.4).   Since no determination
 of particle size was  conducted during this  test, only  the data for total
 mass would be  of value in this analysis.  Due to the fact that the plant
 was experimental in  nature and only one  test was  actually conducted for
                                      44

-------
                    TABLE 3-10.   SUMMARY OF PARTICLE SIZE DATA FOR TEST C-537 - REFERENCE 1226

                                              .Data Rating:   Da
Ul
                                                               Inlet to
Particle sige
range (urn)
0-5
5-10
10-20
20-50
> 50
Vent line
(wt %)
18.8
27.6
40.4
12.1
1.1
Dryer exhaust
(wt%)
9.2
12.3
22.7
49.3
6.5
primary ,
cyclone
(wt %)
6.2
9.4
13.8
22.9
47.7
Inlet to
multi clone
(wt %)
19.3
31.9
31.6
15.1
2.1
Inlet to
scrubber
(wt %)
57.0
34.0
8.8f
0.2r
Nil

              Assumed identical  to Reference 1.

              Stoke's diameter.

              Includes only particles <  200 mesh (74 |jm).   Data taken from Table 94,  p.  328 of
              reference document.

              Combined effluent  of dryer exhaust and vent line.   Data taken from Table 96, p.  333 of
              reference document.

              Data taken from Table 96,  p.  333 of reference document (Appendix D).

              Percentage of particles 20-50 |jmS in diameter are reported in Table 96  (Appendix D)
              as  9.2%.   This is  obviously a typographical  error since the total calculates out to be
              109%.   Appropriate correction has been made in the analysis for particles in this size
              range.

-------
total mass, the  information  contained in Reference 23 was not used in the
development of candidate emission factors.  Although the data are generally
unsatisfactory, the test  results  may be somewhat useful in estimating the
emissions from this type  of  facility.  Therefore, a copy of the test data
for Reference 23 has been included in this report as Appendix E.

3.4.7  Reference 26 (1978)

     Reference 26 is a  study of the  fine  particle emissions  from a  variety
of sources in  the South Coast Air Basin (Los Angeles),  conducted by a con-
tractor to the California Air Resources Board (CARB).   One test included in
this study was of the emissions from an asphalt batch plant controlled by a
cyclone collector followed by a baghouse.  Only one test  run was performed
during the sampling program with concurrent measurements  made at the inlet
and outlet of the baghouse collector.

     The size  distribution of  the particulate was determined at each sam-
pling location using either  of two sampling trains equipped with a series
of three individual  cyclones  having nominal cut-points of 10, 3, and 1 umA,
respectively.   For inlet  testing,  a standard EPA Method 5 (Joy) train was
adapted for the program by installing  the three cyclones  and a  backup fil-
ter  in the oven  section of the impinger  box.  For testing at the outlet,
the  Source Assessment Sampling  System (SASS) was used.   The data obtained
from the CARB study were entered into the EADS system from which a printout
was  obtained.  A summary  of the data contained in Reference  26  is provided
in Table 3-11 with a copy of the pertinent sections of the draft report in-
cluded in Appendix F.   Upon checking with the contractor it was learned that
the test data for run 29S were not changed in the final  report from that in-
cluded in the draft shown in  Appendix F.48


       TABLE 3-11.   SUMMARY OF PARTICLE SIZE DATA FOR REFERENCE 26a

     		         	Data-Rating:  B         	


      Test    Sampling.     Percent of particles in stated size range0
       No.     location     >  10 umA    10-3 yinA    3-1 un,A    < 1 umA


       29S     Outlet         60           6          4          30


      k  From page 4-165 of Reference 26 (Appendix F).
         Location relative to baghouse collector.
         Aerodynamic diameter.


     From the  analysis  of Reference  26  it was determined  that the particle
size measurements were  made  using sound  methodology, and it does contain
adequate information for  validation.   The only significant  problem found
                                     46

-------
with the data was  that the cyclone train at the inlet to the baghouse be-
came overloaded with material, which could  significantly  affect  the  valid-
ity of the  test  results.   This fact was learned from a review of the test
report itself rather than from the EADS printout.  For this reason, the data
collected at the inlet of the baghouse were not  used  in the development of
candidate emission  factors.   Since  only one test run was conducted at the
outlet of the baghouse, a rating of B was assigned to the data.

3.4.8  Reference 27 (1982)

     Reference 27 is a report of the tests conducted by MRI,  under the IP
program,  of a drum-mix asphalt plant controlled by a baghouse collector.
The drum mixer was  equipped to process recycled  asphalt paving utilizing  a
split feed arrangement.   Particulate matter contained in the exhaust stream
was sampled at both the inlet and outlet of the  baghouse  with measurements
also made of  the  condensation aerosol  which would theoretically be formed
upon release into the atmosphere (condensable organics).

     The general sampling protocol  used in  this study was that  developed
for the  IP  program.35  At the inlet, the total uncontrolled emissions  from
the process were determined from a six-point traverse utilizing EPA Method 5.
The particle size  distribution  was  obtained from samples collected  by an
Andersen High Capacity Stack Sampler equipped with a Sierra  Instruments
15-umA preseparator.  Four  particle size tests were  conducted at  each of
the four sampling quadrants for a total of 16 test runs.

     At the outlet from the baghouse, the total mass emissions from the plant
were determined utilizing proposed EPA Method 17, with two tests being con-
ducted at each of  four sampling  quadrants.   The  particle  size distribution
was likewise obtained using an Andersen Mark III cascade  impactor and Sierra
Instruments  15 jjniA preseparator utilizing  an identical  test  protocol.
     Condensable organics testing was also performed during the study utiliz-
ing the Dilution Stack Sampling System (DSSS) developed by Southern Research
Institute.49  This system extracts a small slipstream of gas from the stack
which, after removing particles > 2.5 pmA in diameter, is mixed in a dilution
chamber with cool, dry ambient air.  A standard  high-volume air sampler  is
installed at the  discharge  end of the chamber which  collects a combination
of the fine parti cul ate (< 2.5 urn) extracted from the stack and any new par-
ti cul ate matter formed by condensation.   The loadings obtained from the DSSS
are then compared to  those  measured  by a  second  sampling train without the
dilution chamber  to  determine the amount of condensable organics  formed.
Three separate tests were conducted at the outlet of the baghouse collector
during the sampling program.

     Tables 3-12 through 3-14 provide a summary of the results of this study
with a copy of  applicable portions of the document  included in Appendix  G.
Since the tests  in  Reference 27 were conducted  according  to the  protocol
developed for the IP program and are well documented, a rating of A was as-
signed to the data.
                                     47

-------
                 TABLE 3-12.
*»
QQ
SUMMARY OF PARTICLE SIZE TEST DAI A COLLECTED AT THE BAGHOUSE  INLET

  REFERENCE 27a



                   Data Rating:  A

15-|im Cyclone




Test Run No.
No

I







3



4


( source- run-quad]
I-l-l(B)
1-1-2
I~l-3
1-1-4
I-2-l(C)b
1-2-2(8)
1-2-3
1-2-4
1-3-1
1-3-2
1-3-3
1-3-4
1-4-1
1-4-2
1-4-3
1-4-4


Hass
(n>g)
4,775.2
6,088.7
6,345,5
10,607.6
212.91
5,881.3
4,157.7
9,068.9
5,718.0
6,113,0
3,086.1
10,346.7
2,149.4
3,242,0
7,794.4
9,585.9


060 size
(t«i)
14.8
1S.5
15,1
15.2
14.5
15.6
15.4
15.0
15.7
15.5
15.4
15,2
15.5
15.4
15.4
15.5
Cum. %
less
than
stated
size
30.2
25.0
19.2
17.6
26.7
25.7
22.9
22.9
22,3
23.5
33.5
19.8
35.8
27.8
20,2
21.4


: Stage 1


Hass Dso size
(ing) (n»)
95.2 11.4
125.0 11.8
68,5 11.5
179.5 11.6
45.6 11.2
127.0 11.7
60.4 11.7
406.6 11.5
364.8 11.7
81.6 11.7
62.2 11.6
170.5 11.6
48.4 11.7
78.4 11.7
89,3 11.6
178.5 11.7

Cum. X
less
than
stated
size
28.8
23.5
18.3
16.2
25.1
24.1
21.7
19.5
17.4
22.5
32.1
18.5
34,4
26,00
19,3
20.0



Hass
(nig)
617.5
566.6
399.4
750.9
221.8
621.1
362.7
767,3
200.5
505.7
393.8
888.7
301.8
348.8
550.6
873.4
Stage 2


Oso size
(H»)
6.3
6.7
6.5
6.5
6.2
6.6
6.6
6.4
6.6
6.6
6.5
6.5
6.61
6.6
6.6
6.6

Cum. X
less
than
stated
size
19.7
16.5
13.3
10.4
17.5
16.2
15.0
12.9
14.7
16.2
23.6
11.6
25.4
18.2
13.6
12.8



Hass
(BB)
1,091.0
1,143.3
906.8
977.9
446.3
1,061.0
746.8
1,038.8
975.1
997.5
937,4
1,062.2
671.9
642.8
874.2
785.0
Cyclone


D50 size
(|»)
1.9
1.9
1.9
1.9
i.a
2.0
1.9
1.9
2.0
2,0
1.9
1.9
2.0
1.9
1.9
2.0

Cum. %
less
than
stated
size
3.8
2.4
1.7
2.8
2.1
2.8
1.2
4.1
1.4
3.7
3.4
3,4
5.3
3.9
4.7
6.4




Filter
Mass
(ng)
258.0
198.0
134.3
356.5
60.8
222.6
62.4
481.7
104.1
294,8
169.4
435.3
177.1
175.2
456.6
777.3
060 size
(l»)
< 1.9
< 1.9
< 1.9
< 1.9
< 1.8
< 2.0
< 1.9
< 1.9
< 2.0
< 2.0
< 1.9
< 1.9
< 2.0
< 1.9
< 1.9
< 2.0

a
b
Reproduced from Table 4.4, p.


49 of Reference 27

	 . „. » 	 i
(Appendix G).
„ 	 * 	
it 	 . * 	










-------
TABLE 3-13.
SUMMARY OF PARTICLE SIZE TEST DATA COLLECTED AT THE BAGHOUSE OUTLET
  REFERENCE 27a

                   Data Rating:   A
15-m Cyclone


Test
No.

j



2






Test
No.

.
"


-




Run No. Mass
(source- run-quad) (mg)
0-1-lfB) 37.96
0-1-2° 84.91
0-1-3° 39.29
0-1-4 72.37
0-2-1 21.93
0-2-2 49.78
0-2-3 61.54
0-2-4 71.68




Run No. Mass
(source- run-quad) (ng)
0-1- MB) 8.45
0-1-2* 5.43
0-1-3" 2.97
0-1-4 0.00
0-2-1 5.68
0-2-2 7,91
0-2-3 7.04
0-2-4 8.35
Reproduced from Table 4.5,


D60 size
(M»)
14.9
14.7
14.9
14.8
15.2
15.0
14.6
15.4
Stage 4



Oso size
(no)
2.7
2.6
2.7
2.7
2.7
2.7
2.6
2.8
Cum. X
less
than
stated
size
42,1
21.0
26.0
31.6
56.7
35.7
32.8
37.0

CUB. X
less
than
stated
size
12.9
6.8
10.2
12.7
21.0
13.6
8.9
9.0
p. 50 of Reference
Stage 0


Mass Dso
(ng) (
0.41
0.51
0.00
0.61
1.60
0.67
3.52
7.79




Mass 0
(80 size
(MB)
6.2
6.1
6.1
6.2
6.3
6.2
6.0
6.3
Stage 7



OBO size
(Wl>
0.59
0.58
0.58
0.59
0.60
0.59
0.57
0.61


Cum. X
less
than
stated
size
33.9
16.0
21.1
28,1
41,2
29.4
21.6
22.1

Cum. X
less
than
stated
size
0.56
0.29
0.24
0.20
2.8
0,26
0.14
0,63




Mass
(s>s)
5,30
4.44
2.82
16.29
4.56
4.33
4.58
6.57




Mass
(ng)
' 0.37
0,31
0,13
0.21
1.40
0.20
0,13
0.72

Stage 3


D50 size
(MS)
4.2
4.1
4.2
4.2
4.3
4.2
4.1
4.3

Filter


Oso size
(MS)
< 0.59
< 0.58
< 0.58
< 0.59
< 0.60
< 0.59
< 0.57
< 0.61


CUB. X
less
than
stated
size
25.8
11.9
15.8
12.7
32.2
23.8
16.6
16.3
















-------
      TABLE 3-14.  PARTICIPATE  MASS CONCENTRATIONS (CONDENSABLES  TESTING) -  REFERENCE 27a
                                                Data Rating:   A

Cyclone X
> 15 u
Run No.
1 IP
1 SDSS
2 IP
2 SOSS
3 IP
3 SDSS
4 IP
4 SDSS
Average IP
Average SDSS
mg/dscra
5. 78
19.03
18.76
14.92
36.74
25.61
9.70
14.47
17.75
18.51
gr/dscfc
0.00252
0. 00831
0. 00819
0.00652
0.16
0.112
0.00424
0.00632
0.00775
o.ooaoa
Cyclone III
2.5-15 WB
mg/dscra
1.57
2.80
0.94
2.01
4.36
5.52
2.14
2.13
2.21
3.11
gr/dscfc
0.000686
0.00122
0.00041
0. 000878
0.0019
0.00241
0.000935
0.00093
0.000983
0. 00136
Filter Filter plus wash
< 2.5 pa < 2.5 (in condensable* % Total emissions
ng/«Jsc« gr/dscfc mg/dscn
1.59 0.000694
-
1.49 0.000651
15.78
1.66 0.000725
19.79
2.42 0.00106
27.81
1.79 0.000782
21.13
gr/dscf Condensable* Rg/dscra
8.94
-
21.19
0.00689 43.7 32.71
42.76
0.00864 36. 6 50.92
14.26
0.0121 57.2 44.41
21.79
0.00923 45.3 42.68
gr/dscfc
0.0039
-
0.0093
0.0143
0.0187
0.0223
0.0062
0.0194
0.0095
0.0187
   Reproduced from Table 5.4, p,  81 of Reference 27 (Appendix G), . Tests conducted during the processing of ~ SOX recycled asphalt
   paving.
   Nil If grans per dry standard cubic meter.
e  Grains per dry standard cubic foot.

-------
     3.5  DEVELOPMENT OF CANDIDATE EMISSION FACTORS

     3.5.1  Data Analysis Methodology

          The information contained in Tables 3-3 through 3-11 was reduced to  a
     common format using a family of computer programs developed especially  for
     this purpose (as shown  in  Table 3-15).   These programs are fundamentally
     BASIC translations of the FORTRAN program SPLIN2 developed by Southern  Re-
     search  Institute.50  The  particular version  translated  is  one that MRI
     earlier modified to operate  utilizing as few as three data points.   Addi-
     tional changes were made to  produce emission factors as functions of the
     aerodynamic particle diameter.
                    TABLE 3-15.   COMPARISON OF COMPUTER PROGRAMS
    Fitted size               JSKPRG                 JSKRAW              JSKLOG
    distribution              Spline                 Spline            Log-normal


Input requirements:
  particle size data   Cumulative mass         Largest particle     Completed log-
                         fractions;  particle     diameter; incre-     normal size
                         density                 mental mass frac-    distribution
                                                 tions; particle
                                                 density

  process data         Process and emis-       Process and ends-    Process and emis-
                         sion rates               sion rates           sion rates
                             - or -                   - or -
                         emission factor         emission factor
Output:                 	—	  Size-specific emission factors
                                         (English and metric units)
                                     for selected aerodynamic particle
                                                 diameters
                                          51

-------
     As mentioned above, SPLIN2 is the central portion of the program which
uses the  so-called  "spline"  fits.   Spline fits  result  in cumulative  mass
size distributions very similar to those which would be drawn using a French
curve and fully logarithmic graph paper.  In effect, the logarithm of cumu-
lative mass is plotted as a function of the logarithm of the particle size,
and  a  smooth curve with a continuous,  nonnegative derivative  is  drawn.

     The process by which this smooth cumulative distribution is constructed
involves passing an interpolation parabola through three measured data points
at a time.  The parabola is then used to  interpolate additional  points  be-
tween measured values.  When  the set of  interpolated points  are added  to
the original set of data,  a more satisfactory fit is obtained than would be
the case using only the measured data.

     The primary addition to the spline fitting procedure is the determina-
tion of size-specific emission factors once the size distribution is obtained
by a spline fit.   The user is prompted to input process and emission rate
data.  The  program determines  a total  particulate  emission  factor by:
                                 ETP =  -f-                           (?)


where:  Eyp = total particulate emission factor (Ib/ton)

        e-j-p = total particulate emission rate (Ib/hr)

          R = process weight rate (tons of asphalt paving produced/hr)

Emission factors for each size range are then obtained by multiplying ETP by
the mass-fraction  associated with that range.  The programs automatically
convert the  size-specific emission  factors  obtained from English  units
(Tb"/ton")~tb the appropriate metric units "(kg/metric ton),~whTcfT'is tabulated
as a  part  of the output  format  (1  kg/metric  ton =  1  kg/106  g  =  1  kg/Mg).

     As an additional function, each program has the capability of convert-
ing from Stoke1s diameter to aerodynamic diameter  using the appropriate
density correction  (Table 3-1).   For data reduction purposes,  a  density of
2.4 g/cm3 was assumed unless otherwise specified in the reference document.

     Some of  the programs also require that a largest particle diameter be
provided to  complete the  size distribution.    A  maximum size of  74  urn
(Stoke1s diameter)  was  assumed unless other data were available (see Sec-
tion 3.5.2).   This value was selected due to the apparent correlation of the
amount of material < 200 mesh contained in the aggregate with the total mass
emissions from the process.51  It was likewise assumed that particle sizing
by dry  sieving  generated  data  by Stoke's rather than  physical  diameter.  A
complete listing of each  program is provided in  Appendix H with  sample
outputs shown in Figures 3-1 to 3-3.
                                     52

-------
                SPLIN2  PROGRAM  -   02/22/82 VI
 TEST  IBS  EXAMPLE  OUTPUT  OF  "JSKPRG"
INPUT DAT At
                 PROCESS WEIGHT RATE  =  100   TONS PROD*/HR
                 TOTAL PARTICIPATE EMISSION  RATE = 100  LB/HR
                 PARTICLE DENSITY = 2.44  G/CC
MEASURED SIZE DISTRIBUTION

CUT< URi)        CUM.  % < CUT

                    15
10
20
30
50
                   25
                   34
                   50
OUTPUT DATA!
               TP EMISSION FACTOR  =  1  LB/T  (   ,5  KG/MT )
CUT ( unA)

  .625
 1
 1.25
 2,5
 5
 10
 15
 20
             CUM* 7. < CUT

              1,78801
              2.3787
              2.73215
              4.25364
              6.74744
              10.9053
              14,567
              17.9582
£ND OF TEST SERIES
    EMISSION FACTOR
 (LB/T)       tKG/MT)
,0173801
,023787
,0273215
.0425364
.0674744
,109053
t14567
.179582
S.94Q06E-Q3
,0118935
.0136607
.0212682
.0337372
.0545267
.0728348
,0897908
               Figure 3-1.  Example output of "JSKPRS."
                                53

-------
                 SPLIN2 PROGRAM - 02/22/82 VI

TEST  ID:  EXAHPLE  OUTPUT  OF  "JSKRAU"

INPUT DATA!
     PROCESS WEIGHT  RATE = 100  TONS PROD. /HR
     TOTAL PARTICULATE  EMISSION RATE = 100 LB/HR
     PARTICLE DENSITY = 2,44 G/CC
MEASURED PARTICLE SIZE  DISTRIBUTION

CUT (u»)    RAW % < CUT     CUM*  7. < CUT

                                  15
 10
 20
 30
 50
 74
  15
  10
  9
  16
  50
                                  25
                                  34
                                  50
                                  100
OUTPUT DATA:     TP EMISSION  FACTOR =  i  LB/T  c   ,5  KG/MT)
CUT < uroA)
CUM, % < CUT
                                  EMISSION FACTOR
                              < LB/T )         (KG/MT )
,425
1
1,25
2,5
5
10
15-
20
1*78804
2.37873
2,73218
4,23366
6,74745
10,9053
14,567
17,9581
,0178804
,0237873
,0273218
.0425366
,0674745
.109053
.14567
,179581
END OF TEST SERIES
          Figure 3-2.  Example output of "JSKRAW."
                                              8.94021E-03
                                              .0118937
                                              ,0136609
                                              .0212683
                                              ,0337373
                                              ,0545267
                                              ,0728348
                                              ,0897907
                           54

-------
                      SPLIN2  PROGRAM  -   02/22/82 VI
      TEST IBJ  EXAMPLE OUTPUT OF "JSKLOG"
      INPUT DATA;
                 PROCESS WEIGHT RATE  =  100   TONS PRQO./HR
                 TOTAL PARTICULATE  EMISSION RATE = 100  LB/BR
                 PARTICLE DENSITY = 2.44  G/CC
      MEASURED SIZE DISTRIBUTION

      CUT(utii)        CUM. % < CUT

                         15
10
20
30
50
                         34
                         50
      OUTPUT DATA:
               TP EMISSION FACTOR  =
         LB/T  (   .5  KG/MT)
             CUM. % < CUT
   EMISSION FACTOR
(LB/T)       (KG/MT)
      CUT < uaA)

       .625
       1
       1,25
       13
       20
THIS DATA SET WAS FIT TO A LOG-NORMAL SIZE  DISTRIBUTION
1,788
2,379
2,732
4,254
6,747
10.9
14,57
17,96
.01788
.02379
,02732
.04254
,06747
,109
,1457
,1796
8.94E-03
,011895
.01366
,02127
.033735
.0545
,07285
,0893
                 Figure-3-3.  Example output of "JSKL06."
                                  55

-------
     Since the spline fit routine was originally designed for a cascade inr
pactor data reduction system, its application to noninertial particle  siz-
ing methods may  not  always be entirely appropriate.  Often a  large scale
extrapolation (i.e.,  order of magnitude) of the data will result in a nega-
tive  slope  of the cumulative size distribution curve.   In  such cases,
JSKIQG was  used  in  its  place.  In JSKIOG,  the  data input to the program
have already  been fitted  to a standard  log-normal  distribution  utilizing a
separate program written  for  the Texas Instruments Model 59 (TI-59) pro-
grammable calculator.  This program was used whenever a  spline  fit was  de-
termined not  suitable to  represent  adequately the distribution in the
smaller particle size ranges.   A complete description and listing of  the
TI-59 program used to compute the necessary log-normal  distributions  are
provided in Appendix I.

3.5.2  Results of Data Analysis

     Each of  the specific data  sets described above were processed through
the appropriate computer  program  to  obtain both the particle size distri-
bution and  size-specific  emission factors  for selected particle diameters.
Copies of the individual computer printouts have been included  in Appendix J,
with the results of the computer analyses summarized in Tables  3-16 through
3-29.  Any calculations needed to convert the raw data to the proper format
for input to  the computer were  conducted manually, and copies  of such  cal-
culations are also  included  in Appendix J.  In the case of Reference  27,
the test results were already analyzed by the spline routine as part of the
study and thus, no further data reduction  was necessary.  The  tabular  data
presented in the test report were simply reproduced in Tables 3-27 and 3-28.

     A number of notations should be made  regarding the  particle size  data
shown in Tables 3-16  through  3-29.   First, only data for particles larger
than 2.5 urn (aerodynamic diameter) have been reported even though the spline
equation-was asked to predict values below that size range.   This particular
lower cut off was selected since the last  measured data  point  was,  in  most
cases,-5 or 10 urn.— Extrapolating the size distribution below 2.5 nm-without
the benefit of  actual  data is  questionable and cannot be considered good
engineering practice.  In  addition, the size-specific emission  factors cal-
culated  from  the test  data  have also  been reported  in  each  table even
though  they were not actually  used  in  the development of the  candidate
emission factors for the process.  These values have been included only for
the sake of comparison.

     In  the case  of  test  No.  426 (Reference 1), only selected  portions of
the raw  particle  size data were used as input to the SPLIN2 program.   The
data  for >  60 umS and for 3  and 4 uraS were intentionally deleted from the
computer analysis.   Only  data for particles < 60  umS were used since  the
remainder of  the distribution was derived  from  a  sieve analysis of the
coarse particles which  does  not yield  test  results which are  based on a
true  Stoke's  diameter.   For  3 and 4 umS particles, the  data were deleted
since they were generally  so  closely spaced that the spline fit routine may
not have yielded  physically  valid results.  It is felt that the above de-
letions did not introduce  any significant bias in the output from the SPLIN2
program  since the entire size distribution was essentially  log-normal.


                                     56

-------
            TABLE 3-16.   CALCULATED PARTICLE SIZE DISTRIBUTIONS AND CONTROLLED
                           EMISSION FACTORS FOR REFERENCE 1 -  SCRUBBER INLET3

                                     Data Rating:   D

Cumulative mass % equal to
or less than stated size
Test .
ID No.
2.5
umA
5.0
umA
10.0
umA
15.0 20.0
umA umA
Cumulative emission
or less than stated
2.5
umA
5.0
pmA
10.0
umA
15.0
umA
factor
size
20.
equal to
(kg/Mg)a

Total mass
0 emission
factor
C-369     49.5   60.6   70,8   75.9   79.0   0.771  0.943   1.10   1.18   1.23       1.56

C-372A    19.2   37.7   62.1   76.6   85.7   0.0461 0.0907 0.149  0.184  0.206      0.241

C-372B    46.4   64.3   81.7   90.2   95.0   0.196  0.272   0.346  0.382  0.402      0.423
a  From computer printouts included in Appendix J,  pages  J-3,  5,  and 7.

   Measured at inlet to a multiple centrifugal  scrubber.   Test C-422(l)  not included  due
   to lack of size-specific test data.

c  Aerodynamic diameter.

   Kilograms of particulate matter per 106 g (Mg) of asphalt concrete produced.

-------
                             TABLE 3-17.
CALCULATED PARTICLE SIZE DISTRIBUTIONS AND CONTROLLED
  EMISSION FACTORS FOR REFERENCE I - SCRUBBER OUTLET3
            Data Rating:  Q
Ul
00

Cumulative mass % equal to
or less than stated size
Test .
ID No.
C-369
C-372A
C-372B
C-422(l)
2.5
umA
62.9
57.1
69.5
56.4
5.0
umA
70.3
68,3
74.9
63.1
10.0
umA
76.6
78.0
79.5
69.5
15.0
umA
79.6
82.6
81.8
72.9
20.0
HtnA
81.5
85.2
83.2
75.1
Cumulative emission factor equal to
or less than stated size (kg/Mg)
2.5
umA
0.
0.
0.
0.
0679
0181
0467
0379
5.0 10.0
umA umA
0.0758 0.0827
0.0216 0.0247
0.0503 0.0534
0.0424 0.0467
15.0
umA
0.0860
0.0261
0.0549
0.0490
20.0
umA
0.0879
0.0270
0.0559
0.0505
Total mass
emission
factor
0.108
0.0316
0.0672
0.0672
''
                    From computer printouts included in Appendix J,  pages J-4,  6,  8,  and 9.
                    Emissions to atmosphere from a multiple centrifugal  scrubber.
                    Aerodynamic diameter.
                    Kilograms of particulate matter per 106 g (Mg) of asphalt concrete produced.

-------
TABLE 3-18,   CALCULATED PARTICLE SIZE DISTRIBUTION AND CONTROLLED EMISSION
               FACTORS FOR REFERENCE 1 - TEST NO. C-3933

                             Data Rating:   D
Particlehsize
   (MmA)D
   Cumulative mass
    % equal  to or
less than stated size
Total mass emission factor
Cumlative emission
factor equal to or
 less than stated
  size (kg/Mg)c
2.5
5.0
10.0
15.0
20.0
1.12 (10)
0.0449
2.8
13.9
30.8
2.59 (10)
0.0104
0.646
3.21
7.11
                                 23.1
   From computer printout included in Appendix J, page J-13.  Measured at
   the inlet of a baffle-plate scrubber.   Outlet data eliminated from
   analysis.

   Aerodynamic diameter.

c  Kilograms of particulate matter per 10s g (Mg) of asphalt concrete
   produced.
                                     59

-------
                 TABLE 3-19.   CALCULATED PARTICLE SIZE DISTRIBUTION AND CONTROLLED EMISSION
                                FACTORS FOR; REFERENCE 1 -  TEST NO.  C-426a
                                              Data Rating:   D
                                                             Cumulative emission factor equal  to or
                     Cumulative mass  % equal  to or      	less than stated s 1 ze (kg/Mg)	
                        less  than stated size                                                    Total  mass
    Measurement   2.5      5.0     10.0    1510    20.0    2.5       5.0    10.0    15.0    20.0    emission
     location      pmA      [jmA      |jmA     (.imA .    jJinA    pmA       jjmA     pmA     pmA     jjmA     factor


    Cyclone        0.803   4.56   13.7    20.4    25.2   0.148     0.839   2.53    3.76    4.64     18.41
      inlet

os   Cyclone  H      0.833   2.93    6.92     9.96   12.6   0.0600    0.211   0.500   0.717   0.908     7.20
0     outlet*1                               |
                                           I
    Vent           1.63     8.87   26.0    38-4    47.7   0.00896    0.488   1.43    2.11    2.62      5.49
      line6


    a  From  computer printouts included  in Appendix J,  pages J-10 through J-12.

       Aerodynamic diameter.

    c  Kilograms  of particulate matter per 106 g  (Mg) of asphalt  concrete produced.

       Inlet to multiple  centrifugal  scrubber.   Includes effluent from cyclone and vent line.
    g
       Effluent from scavenger system.

-------
  TABLE 3-20.  STOKE'S DIAMETER VERSUS SETTLING VELOCITY FOR
                 PARTICLES OF VARYING DENSITY - REFERENCE 3a

Settling
velocity.
(cm/sec)
0.2
0.4
0.8
1.6
3.2
6.4
12.8
25.6
Stoke 's
2.4
g/cm3
5.3
7.5
10.6
15.0
21.2
30.0
42.4
60.0
diameter for particles of
2.5
g/cm3
5.2
7.4
10.4
14.7
20.8
29,4
41.6
58.8
2.6
g/cm3
5.1
7.2
10.2
14.4
20.4
28.8
40.8
57.7
2.7
g/cm3
5.0
7.1
10.0
14.1
20.0
28.3
40.0
56,6
specified density0
2.8
g/cm3
4.9
6.9
9.8
13.9
19.6
27.7
39.2
55.4
2.9
g/cm3
4.8
6.8
9.6
13.6
19.2
27.2
38.4
54.3

   From calculations included in Appendix J, pages J-15 through
   19.
   Assumes dry air at 20°C and 760 mm Hg.
c  Calculated from Eq.  (5) with n. = 1814 (10)"  g/cm• sec;
  "g = 980.665 cm/sec2; p1 = 1.2046 (10)"  g/cm3; and p = to the
   values shown in each column.
                                61

-------
TABLE 3-21.   CALCULATED PARTICLE SIZE DISTRIBUTIONS AND UNCONTROLLED
               EMISSION FACTORS FOR REFERENCE 3 - DRYER EXHAUST
                           Data Rating:   C

:' Cumulative emission factor equal to
less than stated size (kg/Mg)
Cumulative mass % equal, to
or less





than stated size
Plant
ID
A4
01
H2
12

13
D2
a, Cl
10 C2
B3
D4
F3
G2
Gl
Bl
F2
2.5
umA
0,774
0.0803
0.0576
3.03

0.0502
2.68
0.138
0.0259
0.197
1.25
0.219
0.0633
6.72(10)
0.956
2.96
5.0
umA
4.29
1.67
1.78
6.86

2.34
7.39
1.81
1.24
1.40
6.33
3.07
3 1.54
0.647
2.13
8.76
10.0
|jmA
13.9
10.4
13.3
12.6

22.0
20.2
10.4
12.4
6.02
21.8
15.8
14.0
11.0
4.38
20.5
15.
0 20.0
pniA umA
21.
16.
21.
16.

38.
36.
19.
6 26.3
9 20.9
9 25.7
1 21.5

0 45.7
7 52.2
7 26.3
22.8 28.8
11.
37.
25.
1 15.6
7 48.9
6 32.1
32.3 44.9
25.
6.
30.
9 32.5
47 8.06
1 38.0
2.5
umA
0.0728
0.0169 3
7.08(10)"
0.639
_3
7.38(10)
0.503
0.0500 3
9.34(10)"
0.0919
0.933
0.0807
0.0192 3
1.88(10)
0.152
0.432
5.0
(juiA
0.403
0.351
0.219
1.45

0.344
1.39
0.656
0.448
0.655
4.72
1.13
0.469
0.180
0.338
1.28
10.0
umA
1.31
2.18
1.63
2.66

3.23
3.80
3.78
4.49
2.81
16.2
5.84
4.25
3.08
0.696
2.99
15.0
umA
2.02
3.55
2.69
3.40

5.59
6.90
7.16
8.24
5.19
28.1
9.46
9.82
7.23
1.03
4.40
20.0
umA
2.47
4.38
3.16
4.53

6.72
9.81
9.55
10.4
7.30
36.5
11.8
13.6
9.06
1.28
5.54
or
Total
mass
emission
factor
9.4
21.0
12.3
21.1

14.7
18.8
36.3
36.1
46.7
74.6
36.9
30.4
27.9
15.9
14.6

From computer printouts on paqes
of
Appendix J.
Uncontrol
J-20
. 22. 24.
led emissions from the
26, 28, 30 3?
dryer only.
34, 36

, 38, 40

4?

44, 46,

and 48

Aerodynamic diameter.
C un

A.JS 	 . 1 _ i. _


nfi _ /»a_\
_ ^ 	 	 »_ _ 1 i, 	 	






-------
TABLE 3-22.   CALCULATED PARTICLE SIZE DISTRIBUTIONS AND CONTROLLED EMISSION FACTORS FOR
               REFERENCE 3 - OUTLET OF PRIMARY COLLECTORS

                                   Data Rating:   C


Cumulative emission factor equal to or
less than stated size (kg/Mg)
Cumulative mass % equal,
than stated size
Plant 2.5
ID
A4
Dl
H2
12
13
02
Cl
C2
B3
D4
F3
G2
K4
Gl
Bl
F2
pmA
5,00
2,38
7,45
0.397
7.13
1,55
2,68
5.31
0,622
4.48
3.85
d 2'48
U
9.74
1.74
5.14
5.0
jjfliA
9.60
6.02
11.8
2.23
15,7
7.40
6.60
10.4
2.29
12.5
9.16
8.63
-
14.6
3.02
12.0
10.0
pmA
16.7
12.4
17.9
8.52
29.2
23.5
14.1
18.5
6.74
27.6
18.6
22.5
-
22.0
5.04
23.1
to or less
15.0
pmA
22.1
17.3
22.5
15.6
39.1
38.2
20.7
24.7
11.5
39.3
26.2
34.6
-
27.9
6,67
31.1
20.0
umA
26.5
21.0
26.2
22.2
46.4
49.6
26.3
29.7
16.0
48.1
32.3
44.2
-
33.0
8.07
36.8
2.5
umA
0.0229
0.0624
0.0767
0.00222
0.0998
0,0583
0.0474
0.109
0.00759
0.465
0.0905
0.0764
-
0.312
0.00782
0. 0586
5.0
umA
0.0440
0.158
0.121
0.0125
0.219
0.279
0.117
0.213
0.0279
1.30
0.215
0.266
-
0.468
0.0136
0.136
10.0
MfliA
0.0767
0.325
0.184
0.0477
0.409
0.886
0.250
0.379
0.0823
2.87
0.437
0.694
-
0.703
0.0226
0.263
15.0
(jmA
0.101
0.453
0.231
0.0876
0.547
1.44
0.366
0.506
0.140
4.09
0.616
1.07
-
0.892
0.0299
0.354
Total
mass
20.0 emission
umA
0.121
0.549
0.270
0.125
0.650
1.87
0.465
0.609
0.195
5.00
0.760
1.36
-
1,06
0.0362
0.420
factor
0.458
2.62
1.03 '
0.560
1.40
3.77
1.77
2.05
1.22
10.4
2.35
3.08
-
3.20
0.449
1.14

a

b
c
d
From computer
of Appendix J
printouts
on oaves
J-21.
23. 25.
Emissions from dryer controlled
27, 29, 31,
by multipl
33, 35
. 37 39
e cyclone dust
, 41, 43
. 45. 47.
and 49
collectors.
Aerodynamic diameter.
Kilograms of
I") -* 4- -, »n4- j*J A H A
particulate matter
fr ***

per 106

g (Hg)

of asphalt

concrete produced.






-------
     TABLE 3-23,   CALCULATED PARTICLE SIZE DISTRIBUTIONS AND
                    FACTORS FOR REFERENCE 8 - SLOAN3

                        Data Rating:   B
            Cumulative
           mass % equal
            to or less
Cumulative emission factors equal to
      or less than stated size
Particle
size
umA
2.5
5.0
10.0
15.0
20.0
Total mass
than stated size
Washer
inletc
17.6
35.6
54.7
61.7
65.9
emission
Washer
exhaust
20.5
26.6
36.5
38.9
40.6
factor
Washer
lb/tond
1.67
3.38
5.19
5.86
6.25
9.49
in!etc
kg/Mgd
0.834
1.69
2.59
2.93
3.13
4.74
Washer
lb/tond
0.165
0.214
0.294
0.313
0.327
0.804
exhaust
kg/Mgd
0.0825
0.107
0.147
0.156
0.163
0.402

From computer printouts on pages J-51 and J-52 of Appendix J.   Based
on test data from Sloan Construction Company.   Emissions controlled
by a spray tower scrubber.

Aerodynamic diameter.
Exit from a single cyclone collector.

Pounds of particulate matter per short ton (assumed) of asphalt
concrete produced or kilograms of particulate matter per 106 g
(Mg) of asphalt concrete produced.
                                 64

-------
           TABLE 3-24.   CALCULATED PARTICLE SIZE DISTRIBUTIONS AND
                          EMISSION FACTORS FOR REFERENCE 8 - HARRISON'

                             Data Rating:  B
                  Cumulative
                 mass % equal
                  to or less
Cumulative emission factors equal to
      or less than stated size
Particle
size
umA
2.5
5.0
10.0
15.0
20.0
than stated size
Pre-wash
entrance
20.7
45.5
62.6
68.1
71.7
Washer
exhaust
89.8
94.3
95.8
96.2
96.5
Pre-wash
lb/tond
1.97
4.34
5.97
6.48
6.83
entrance1"
kg/Mge
0.986
2.17
2.98
3.24
3.41
Washer exhaust
lb/tond
0.314
0.330
0.335
0.337
0.338
kg/Mge
0.157
0.165
0.168
0.168
0.169
Total mass emission factor
9.53
4.76
0.350
0.175
   From computer printouts on pages J-53 and J-54 of Appendix J.   Based on
   test data from Harrison, Inc.   Emissions controlled by a centrifugal
   scrubber.

   Aerodynamic diameter.

   Measured at exit from a single cyclone collector.

   Pounds of particulate matter per short ton (assumed) of asphalt
   concrete produced.

   Kilograms of particulate matter per 10s g (Mg) of asphalt concrete
   produced.
                                     65

-------
Ch
                           TABLE 3-25.  CALCULATED PARTICLE SIZE DISTRIBUTIONS AND EMISSION
                                          FACTORS .FOR REFERENCE 12 - TEST NO. C-5373

                                                    Data Rating:  D

Cumulative mass % equal to or
than stated size
Test Measurement 2,5 5.0
No. location jjrnA umA
C-537 Inlet to 0.726 2.94
primary
cyclone
C-537 Inlet to . 1.33 7.93
multiclone
C-537 Inlet to 11.7 34.6
scrubber
10.0
umA
8.91

28.9
70.3

15.0
umA
14.9

48.9
89.1

less
20.0
umA
20.0 0.

63.2 0.
95.6 0.

Cumulative emission factor equal to or
stated size (kg/Mg)
2.5 5.0 10.0 15.0 20.0
umA umA umA umA umA
115 0.464 1.41 2.35 3.16

0584 0.350 1.27 2.16 2.79
0400 0.118 0.240 0.305 0.327

less than
Total
particulate
15.8

4.41
0.342


a From computer printouts on Pages J-56
Aerodynamic diameter.
Includes drier exhaust and vent line.
d
, 57,



and 58



of Appendix



J.







      Outlet from a multiple cyclone collector.

      Kilograms of particulate matter per 106 g (Hg) of asphalt concrete produced.

-------
TABLE 3-26.   CALCULATED PARTICLE SIZE DISTRIBU-
                TION AND ASSOCIATED CONTROLLED
                EMISSION FACTORS FOR REFERENCE
                26 - BAGHOUSE OUTLET3

               Data Rating:  B



Particle
s1zeb
(MmA)
2.5
5.0
10.0
15.0
20.0
Cumulative
mass % equal to
or less than
stated size
33.2
35.8
40.4
46.8
53.9
Cumulative
emission
factor
( kg/Mg)
0.00412
0.00443
0.0050
0.0058
0,00668
Total mass emission factor            0.0124
   From computer printouts on page J-61 of
   Appendix J.  Inlet test data not processed.

   Aerodynamic diameter.

c  Kilograms of particulate matter per 10s g
   (Mg) of asphalt concrete produced.
                        67

-------
                            TABLE  3-27.    CALCULATED  EMISSIONS  FACTORS  FOR  REFERENCE  27  -  BAGHOUSE  INLETC

                                                                i         Data Rating:   A
Test      Run No.
 Ho.   (source-run-quad)
                                      Matching
                                      ia*f  run
 Total  Bass
emission  rate
   (Jb/h)
            Production
              r«tec
             (ton/h)
           Total uss   .
          •Isslon factor
            (ID/ton)
                                                                                                         Size-specific  eaiision factors
                  < 2.5
                                                                                                                                        <  15 pa
             (llj/ton)   (kg/Kg)   {Ib/ton)  (kg/Mg)  {Ib/ton}  (kg/Hg)
00
                       I-l-l(fl)
                       1-1-2
                       -1-3
                       -1-4

                       -2-1(8)*
                       -2-2(8)
                       -2-3
                       -2-4

                       -3-1
                       -3-2
                       .-3-3
                       -3-4

                       -4-lb
                       -4-2.
                       -4-3*
                       -4-4b
                           -7
                           -KC)
                           -2
                           -KC)

                           one
                           -2
                           -7
                           -5

                           -8
                           -7
                           -8
                           -7

                          None
                          1-6(8)
                          None
                          None
7,480
8,190
6,930
8.190
6,930
7.480
7,180

5,840
7,480
5,840
7,480
5,720
22S
217
162
217
162
225
195

215
225
215
225
205
 33.3
 37,7
 42. B
 37.7

(30.9)
 42.8
 33.3
 36.8

 27.2
 33.3
 27.2
 33.1

(30.9)
 27.9
(30.9)
(30.9)
                                               2.1
                                               1.6
                                               1.4
                                               1,5

                                               1.3
                                               1.9
                                               0.8
                                               2.0

                                               0.75
                                               1.8
                                               1.6
                                               1.5

                                               2.5
                                               1.6
                                               1.9
                                               2.2
1.1
0.80
0.70
0.75

0.65
0.95
0.4
1.0

0.38
0.90
0.80
0.75

1.3
0.80
0.95
1.1
 9.1
 8.3
 7.S
 5.6

 7.4
 9.5
 6.8
 6.6

 4.5
 7.1
 8.3
 5.7

10.0
 6.8
 5.6
 5.6
4.6
4.2
3,8
2.8

3.7
4.8
3.4
3.3

2.3
3.6
4.2
2.9

5.0
3.4
2.8
2.8
10.2
 9.4
 8.3
 6.7

 8.5
10.9
 7.6
 8.5

 5.8
 7.8
 9.1
 6.6

11.0
 7.7
 6.3
 6.6
S.I
4.7
4.2
3.4

4.3
5.5
3.8
4.3

2.3
3.9
4.6
3.3

5.5
3.9
3.2
3.3
                    Total average
                                       Non-
                                      Batching
                                      •ass runs

                                       1-3
                                       1-4
                                      5,620
                                      3,850

                                      6.350
               223
               237

               210
             25.2
             16.3

             30.9
                                                                                                1.7
                                                                                                         0.85
                                                                                                                    7.2
                                                                                                                            3.6
                                                                                                                                      8.2
                                                                                                                                              4.1
                 Results of SPLIN2 analysis  reproduced from Table 4.6, p. 51 of the  lest report (Appendix 6).  Orusralx process.  Does not Include any
                 tests conducted during the  processing of recycled asphalt paving.

                 Ha  paired Mass run for this particle sizing run,  :Used the average  total nass emission factor of all elghtaass runs (30.9 Ib/ton) to
                 calculate site-specific emission factors.

                 Average plant production  rate during Bass  test run.  Tons (2,000 Ib) of asphalt concrete produced per hour.

                 Pounds of participate Batter per short ton of asphalt concrete produced or kilograms of participate Matter per 10*/g (Hg) of asphalt
                 concrete produced.

-------
                  TABLE  3-28.    CALCULATED  EMISSION FACTORS FOR REFERENCE  27  - BAGHOUSE  OUTLET*
                                                            Data Rating:   A
Total MISS Production
Test
No.











* Results
b
Run Ho.
source- run- quad
0-1-UB)
0-1-2^
0-l-3d
0-1-4
Average
0-2-1 '
0-2-2
Q-2-3
0-2-4
Average
Total average
of SPUN2 analysis

Mission rate
(Ib/h)
11.5
12.7
16.6
9,6
12.6
9.6
7,3
24.7
10.0
12.9
12.8
reproduced fron
A I
rate .
(ton/l»r
164
226
216
237
211
174
216
195
178
191
201
Table 4.7,

Total »ass Ratio of total MSI
emission factor cone, to particle
(Ib/ton) size train cone.
0.07
0.066
0.077
0.041
0. 061 0. 59
0,055
0.034
0.127
0.056
0.068 0.65
0.065
p. S2 of the test report (Appendix G).

Size specific emission factors'*
< 2
(Ib/ton)
O.OOB
0.004
0.007
0.004
0.006
0.011
0.004
0.011
0.004
0.008
0.007
drum nix

.5 H*
(ko/ng)
0.004
0.002
0.004
D.002
0.003
0.006
0.002
0.006
0.002
0.004
0.004
process.

< 10
(Ib/ton)
0.028
0.011
0.019
0.013
0.018
0.028
0.012
0.035
0.016
0.023
0.021


V*
(kg/Mfl)
0.014
0.006
0.010
0.007
0.009
0.014
0.006
0.018
0.006
0.012
0.011


< 15
{ Ib/ton)
0.03
0.012
0.021
0.013
0.019
0.031
0.012
0,044
0.021
0.027
0,023


yn
(kg/Ma)
0.0 IS
0.006
0.011
0.007
0.01D
0.016
0.006
0.022
0.011
0.014
0.012


c Founds of parttcutate natter per short ton of asphalt concrete produced or kilograos of participate natter per 10* g (Hg) of asphalt concrete produced.
  Test conducted during the processing of - 30X recycled asphalt paving.

-------
                               TABLE  3-29.    EMISSION FACTORS FOR CONDENSABLE  ORGANICS -  REFERENCE  27a

Run No,c Date
1
1
2
2
3
3
4
4
SDSS wmi
suss 10/8/ai
SDSS 10/9/fll
SDSS 10/9/Bl
Ratio of total
stack flow rate
to sampler
flow rate
62,200
71,500
70,300
85,400
71,100
81,500
80,200
84,800
uaia nanny, n

,
Average . Total mass
Total emissions production rate enission factor
 15
(Ib/ton)
0.0016
0.0069
0.0055
0.013
0.0087
0.0045
0.0066
U*
(kfl/Ha)
0.0008
0.0035
0.0028
0.0065
0.0044
0.0023
0.0033
2.5-15
(Ib/ton)
0.00043
0.00035
0.00075
0.0016
0.0019
0.00098
0.00098
MB
< kg/Mg)
0.00022
0.00018
0.00038
0.00080
0.00095
0.00049
0.00049

factor
< 2.5
(Ib/ton)
0.00044
0.00055
0.0057
0.00060
0.0066
0.0011
0.013


l«
(kfl/H8)
0.00022
0.00028
0.0029
0.0003
0.0033
0.00055
0.0065

2  a  Reproduced from Table 5.5, p. 82 of Reference 27 (Appendix G).  Dria-alx process with split feed.  All tests conducted during the processing of ~ 3OX
       recycled asphalt paving.

       Average production rate for test period except for Run 2 where the daily average was used to calculate the enission  factor.  Short tons of asphalt
       concrete produced per hour.

    c  IP  - Sampling train consisting of a dual cyclone plus standard back-up filter.
       SDSS * Sampling train consisting of a dual cyclone followed by an atoospherfc dilution chamber and back-up filter.

-------
     Another notation which should be made  is  in  regard  to  the  information
derived from Reference 3.   In  this  case, the  particle  size data for the
uncontrolled emissions from the dryer were expressed in terms of their set-
tling velocity  rather than  particle  size.  Calculations were,  therefore,
made to convert the data from the applicable settling velocity to Stoke1s
diameter using  Equation  5.  A  summary  of such a determination is provided
in  Table  3-20   with  the  calculations  themselves included in  Appendix J.

3,5.3  Development of Candidate Emission Factors and AP-42 Background

     The ideal   situation would be to average a large number of A-rated data
sets to  obtain a single-valued emission  factor which would  represent a
broad cross section  of  the  asphalt paving  industry.  As outlined in the
above discussion, such data were  not available  for this  particulate  study.
In the case of  batch and continuous plants,  there were no A-rated data con-
tained in  the  information collected  and only three 8-rated data sets con-
sisting of a total  of four  individual test  runs at three different facili-
ties.  For drum-mix  plants, only one A-rated test at a single facility is
included in the entire data  base.   This lack of high quality data makes the
development of  appropriate  size-specific  emission factors for asphalt con-
crete plants very difficult.

     According  to the OAQPS guidelines,  A-  and 8-rated data should not be
combined with C- or D-rated  data to develop  emission factors for a particu-
lar  source.  However, in the case of conventional plants it was found nec-
essary to  combine a  small amount  of 8-rated data with a  substantial  C- and
D-rated data base  in order  to improve the overall quality of the emission
factors.   This  was  deemed appropriate  since the total number of B-rated
tests was so low that the inclusion of the C- and D-data would significantly
enhance the overall  applicability of the emission factor to a larger number
of facilities utilizing a greater diversity  of raw material.

     To derive  each  emission  factor,  the information contained in Tables
3-16 through  3-29  was tabulated  according  to  the  type  of process  and
control equipment,  and  the arithmetic mean and standard deviation  were
calculated wherever  possible for  each particle  size  increment.  The  arith-
metic mean was  calculated from the data  in each  column  according to the
relationship:

                                  •t    n
                                          x,                          (8)
where:    x = arithmetic mean

          n = number of measurements
         x. - individual measurements
                                     71

-------
The standard deviation was calculated according to the relationship:
                                  n-1
                                            1/2
                                                                      (9)
where:
a - standard deviation with x.
and n as defined in Equation (8)
     The geometric mean  and standard deviation were also calculated, with
the standard  geometric  deviation being indicative of the overall variance
in the data. The geometric mean was calculated from the data in each column
according to the relationship:
                              exp  -
                              n
                              E
                             1=1
    In
xi
(10)
where:    x  = geometric mean with x. and n as defined in Equation (8)

The standard geometric deviation was calculated according to the relationship:

                                                     1/2
                    or  * exp
" n
E
.1=1
In x.

- In x
n-1
2"

                                                            (11)
where: "   0*.= standard geometric deviation with x- ~and n~as defined-in   —
           9     Equation (8)                     1

     Rather than  utilizing  the  emission  factors  actually  derived  from  each
study, the  candidate  emission factor for each size increment was obtained
by applying the  particle size distribution from  the  various data sets to
the existing  AP-42  emission factor (if  any).  This  approach  was used to
take advantage of the significant data  base  which  already  exists for  the
total mass  emissions  from asphalt concrete plants.   It was felt  that  this
was superior  to  utilizing emission factors based on  limited data of some-
times marginal quality and  would  produce emission factors much  more  repre-
sentative of the total industry.  The results of this analysis are shown in
Tables 3-30 through 3-35.

     Since  both  the batch and  continuous  process use similar mechanical
equipment (and thus would have similar  emissions),  data  for these plants
were combined  under the  generic category of  "conventional asphalt plants,"
and emission factors were calculated for each type of control  equipment for
which data were available.
                                     72

-------
                 TABLE  3-30,
—I
U)
CANDIDATE  PARTICIPATE EMISSION  FACTORS FOR UNCONTROLLED  CONVENTIONAL
  ASPHALT  PLANTS

                     EirVjssltmFactor Rating:   Da


Reference
No.
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
12

Test
ID
No.
C-4266
A4
Dl
H2
12
13
02
Cl
C2
B3
04
F3
G2
Gl
Bl
F2 ,
C-537'

Summary data
K
table No.
3-19
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-21
3-25

Data
qua) i ty
rating
0
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
D
Arithmetic Mean (x)
Geometric
Standard
Mean (xg)
Deviation
Std. Geometric Dev.
3 See Section 3.5.
b T .,
-3 n» 1 . t.J— *l 1

(o)
(ofl)
4 for rationale.





_ , ,t» 2 «t^ *,§»
Cumulative


less than
2.5
umA
0.803
0.774
0.0803
0.0576
3.03
0.0502
2. 68
0.138
0.0259
0.197
1.25
0.219
0. 0633
0. 00672
0.956
2.96
0.726
0.825
0.269
1.06
6.13


5.0
|inA
4.56
4.29
1.67
1.78
6.86
2.34
7.39
1.81
1.24
1.40
6.33
3.07
1.54
0.647
2.13
8.76
2.94
3,46
2.71
2.48
2.07

J -i_ & _
mass equal to

or

stated size <%)*•
10.0 15.0
|inA (i«A
13.7 20.4
13.9 21.6
10.4 16.9
13.3 21.9
12.6 16.1
22.0 38.0
20.2 36.7
10.4 19.7
12.4 22.8
i.02 11.1
21.8 37.7
15.0 25.6
14.0 32.3
11.0 25.9
4.38 6.47
20. 5 30. 1
8.91 14.9
13.6 23.4
12.6 21.4
5.17 9.23
1.54 1.59


20.0
|inA
25.2
26.3
20.9
25.7
21.5
45.7
52. 2
26.3
28.8
15.6
48.9
32.1
44.9
32.5
8.06
38.0
20.0
30.1
27.5
12.3
1.59


Cumulative particulate emission ,,
factor less than stated size
2.5
(jraA
0.181
0. 174
0.0181
0.013
0,682
0.0113
0.603
0.0311
0.00583
0.0443
0.281
0.0493
0.0142
0.00151
0.215
0.666
0.163
0.185
0. 0604
0.238
6.13


5.0
|imA
1.03
0.965
0.376
0.401
1.54
0.527
1.66
0.407
0.279
0.315
1.42
0.691
0.347
0.146
0.479
1.97
0.662
0.777
0.610
0.556
2.07


10.0
|inA
3.08
3.13
2.34
2.99
2. 84
4.95
4.55
2.34
2.79
1.35
4.91
3.56
3.15
2.48
0.986
4.61
2.00
3.06
2.83
1.17
1.55


15.0
lioA
4.59
4.86
3.80
4.93
3.62
8.55
8.26
4.43
5.13
2.50
8.48
5.76
7.27
5.83
1.46
6.77
3.35
5.27
4.82
2.08
1.59


(kg/Ma)"
20.0
jimA
5.67
5.92
4.70
5.78
4.84
10.3
11.8
5.92
6.48
3,51
11.0
7.22
10.1
7.31
1.81
8.55
4.50
6.79
6.20
2.77
1.60


Total mass
emission factor
(kg/Ha)
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5
22.5






      Aerodynamic diameter.

      Based on a total mass  emission factor of 22.5 kg/Mg per Table 8.1-3 of AP-42.   Results of calculations rounded to three significant figures,

      Includes dryer emissions only.

      Includes emissions from dryer and scavenger system (vent line).

-------
            TABLE  3-31.
CANDIDATE EMISSION FACTORS  FOR CYCLONE DUST COLLECTORS  IN CONVENTIONAL
  ASPHALT PLANTS
                                                  Emission  Factor Rating:   Da

Test c . .
Reference ID Sunraary data
Ho. Mo. table No.
1 C-426*
1 C-393T
3 A4
3 Ul
3 H2
3 12
3 13
3 02
3 Cl
3 C2
3 B3
3 D4
3 F3
3 G2
3 Gi
3 Bl
3 F2 ,
8 Harrison
8 Sloan!
12 C-5371
Arithmetic Mean (it)
Geometric Hean (xg)
Standard Deviation (a)
Std. Geometric Oev. (og)
3-19
3-18
3-22
3-22
3-22
3-22
3-22
3-22
3-22
3-22
3-22
3-22
3-22
3-22 ,
3-22
3-22
3-22
3-24
3-23
3-25




Data
Cumulative: mass equal to or
j £
less than stated size (X)
quality 2.5 5.0
rating iimA jJtoA
0
0
C
C
C
C
C
C
C
C
c
c
c
c
c
c
c
B
B
D




0.833 2.93
0.0112 0.0449
5.00 9.60
2.38 6.02
7.45 11.8
0.397 2.23
7.13 15.7J
1.55 7.40
2.68 £.60
5.31 10.4
0.622 2.29
4.48 12.5
3.85 9.16
2.48 8.63
9.74 14.6
1.74 3.02
5.14 12. 0|
20.7 45.5
17.6 35.6
1.33 7.93
5.02 11.2
2.44 6.60
5.51 11.0
5.15 4.12
|imA
6.92
2.80
16.7
12.4
17.9
8.52
29.2
23.5
14.1
18.5
6.74
27.6
18.6
22.5
22.0
5.04
23.1
62.6
54.7
28.9
21.1
16.5
15.2
2.16
15.0
9.96
13.9
22.1
17.3
22. S
15.6
33.1
38.2
20.7
24.7
11.5
39.3
26.2
34.6
27.9
6.67
31.1
68.1
61.7
48.9
29.0
24.7
16.6
1.83
20.0
(iraA
12.6
30.8
26.5
21.0
26.2
22.2
46.4
49.6
26.3
29.7
16.0
48.1
32,3
44.2
33.0
8.07
36.8
71.7
65.9
63.2
35.5
31.1
17.7
1.75
Cumulative particulate emission factor
equal to or less than stated size (kg/Mg)
2.5
0.00708 7
9.52(10)"
0.0425
0.0202
0.0633
0.00337
0.0606
0.0132
0.0228
0.0451
0.00529
0.0381
0.0327
0.0211
0.0828
0.0148
0.0437
0.176
0.150
0.113
0.0478
0.0185
0.0488
13.0
5.0
umA
0.0249 4
3.82(10)"
0.0816
0. 0512
0.100
0.0190
0.133
0.0629
0.0561
0. 0884
0.0195
0.106
0.0779
0.0734
0.124
0.0257
0.102
0.387
0.303
0.674
0.125
0. 0629
0.159
4.58
10.0
|imA
0.0588
0.0238
0.142
0.105
0.152
0.0724
0.247
0.200
0.120
0.157
0.0573
0.235
0.158
0.191
0.187
0. 0428
0.196
0.532
0.465
0.246
0.179
0.140
0.129
2.16
15.0
0.0847
0.118
0.188
0.147
0.191
0.133
0.332
0.325
0.176
0.210
0.0978
0.334
0,223
0.294
0.231
0. 0567
0.264
0.579
0.524
0.416
0.247
0.210
0.141
1.83
20.0 e
0.107
0.262
0.225
0.178
0.223
0.188
0.394
0.422
0.224
0.252
0.136
0.409
0.275
0.376
0.281
0.0686
0.313
0.609
0.560
0.537
0.302
0.264
0.150
1.75
Total mass
mission factor
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85





See Section 3.5.4 for rationale.                     j
                                                 |

Table  included in this report from which the  raw data was taken.


Aerodynamic diameter.                              :


Based  on a total mass emission factor of 0.85 kg/Mg per Table 8.1-3 of AP-42.  Results of calculations  rounded to three significant  figures.


Includes exhaust from a single cyclone and the scavenger system (vent line).


Single cyclone collector.

-------
Ul
                    TABLE  3-32.   CANDIDATE  PARTICIPATE EMISSION FACTORS FOR  CONVENTIONAL ASPHALT PALNTS
                                     CONTROLLED BY MULTIPLE CENTRIFUGAL  SCRUBBERS

                                                    Emission  Factor Rating:  D
Cumulative
Test Data
Reference ID quality
No. No. rating
1 C-369 0
1 C-372A 0
1 C-372B 0
1 C-422{1) 0
8 Harrison B
Arithmetic Mean (x)
Geometric Mean (xg)
Standard Deviation (a)
Std. Geometric Oev. (ag)
iess than
Summary data
table No.
3-17
3-17
3-17
3-17
3-24
-

-

2.5
MO*
62.9
57.1
69.5
56.4
89.8
67.1
66.1
13.7
1.21
5.0
(""A
70.3
68.3
74.9
63.1
94.3
74.2
73.5
12.0
1.16
mass equal to
Stated
10.0
'**
76.6
78.0
79.5
69.5
95. 8
79.9
79.4
9.69
1.12
OC
Cumulative part icul ate emission
factor equal to or less, than
size (X)"
15.0 20.0
ufflA
79.6
82.6
81. B
72.9
96.2
82.6
82.3
8.50
1.11
!«A
81.5
85.2
83.2
75.1
96.5
84.3
84.0
7.80
1.09
2.5
uoA
0.022
0.020
0.024
0.020
0.031
0.023
0.023
0.005
1.20
stated
5.0
(imA
0.025
0.024
0.026
0.022
0.033
0.026
0.026
0.004
1.16
size (kg/Ha)"
10.0
|imA
0.027
0.027
0.028
0.024
0.034
0,028
0.028
0.004
1.13
15.0
|ifflA
0.028
0.029
0.029
0.026
0.034
0.029
0,029
0.003
1.10
20.0
|unA
0.029
0.030
0.029
0.026
0.034
0.030
0.030
0.003
1.10
Total nass
emission factor
(lcg/«9)
0.035
0.035
0.035
0.035
0.035
0.035

-

         Aerodynamic diameter.

         Based on a total nass emission factor of 0,035 Kg/Mg per Table 8.1*3 of AP-42 for nultlpte centrifugal scrubbers.  Results of calculations
         rounded to two significant figures.

         Table included In this report from which the raw data was obtained.

-------
    TABLE 3-33.   CANDIDATE PARTICULATE EMISSION FACTORS FOR CONVENTIONAL
                   ASPHALT PLANTS CONTROLLED BY GRAVITY SPRAY TOWERSa

                       Emission Factor Rating:   0
                                                    Cumlative emission
                         Cumulative mass            factor equal to or
Particle, size             % equal  to or              less than stated
   (uraA)              less than stated size           size (kg/Mg)
2.5
5.0
10.0
15.0
20.0
Total mass emission factor
20.5
26,6
36.5
38.9
40.6
_
0.041
0.053
0.073
0.078
0.081
0.20

a  Based on data contained in Reference 8 for Sloan Construction Company
   (see Table 3-23).   Data Rating:   B.

   Aerodynamic diameter.^     	           __     _     _.

c  Based on a total mass emission factor of 0.20 kg/Mg per Table 8.1-3 of
   AP-42 for spray towers.  Results of calculations rounded to two sig-
   nificant figures.
                                    76

-------
    TABLE 3-34.  CANDIDATE PARTICULATE EMISSION FACTORS FOR CONVENTIONAL
                   ASPHALT PLANTS CONTROLLED BY A BAGHOUSE COLLECTOR9

                       Emission Factor Rating:  D
                                                    Cumlative emission
                         Cumulative mass            factor equal to or
Particle^size             % equal to or              less than stated
   (untA)              less than stated size           size (kg/Mg)
2.5
5.0
10.0
15.0
20.0
Total mass emission factor
33.2
35.8
40.4
46.8
53.9
-
0.003
0.004
0.004
0,005
0,005
0.01

a  Based on data contained in Reference 26 (see Table 3-26).  Data Rating;  8.

   Aerodynamic diameter.

   Based on a total mass emission factor of 0^01 kg/Mg per Table 8.1-3 of
   AP-42 for baghouses.   Results of calculations rounded to one significant
   figure.
                                    77

-------
       TABLE 3-35.   CANDIDATE PARTICULATE EMISSION FACTORS FOR DRUM-MIX ASPHALT
                      PUNTS CONTROLLED BY A BAGHOUSE COLLECTOR3

                             Emission Factor Rating:  D

Cumulative mass
or less 1
Parti cle.size stated siz«
(umA)D

2.5

10.0

15,0

Total mass
Condensabl
Uncontrolled

5.5

23

27

emission factor
e organics^
annai +n Cumulative participate emission factors
.jjquai to equgl t(j Qp 1@ss th&n stated s1ze

-------
A summary of  the  size-specific emission factors  for  conventional  asphalt
plants is shown  in  Table 3-36 and graphically  in Figure  3-4  by  drawing  a
smooth curve through the various data points.

     In the case  of drum-mix plants, there  is  no applicable factor pub-
lished in AP-42  for the total mass  emissions from plants controlled by  a
baghouse collector.   To  calculate  the various size-specific emission fac-
tors contained  in Table 3-35, the overall collection efficiency for the
baghouse as determined  during the  testing program (99.8%) was applied to
the uncontrolled  emission factor (2.45  kg/Mg) published in AP^42 to obtain
a controlled  emission  factor for total  particulate (0.0049 kg/Mg).   The
percentage of the total  mass  in each particle size increment  (<  2.5, < 10,
and < 15 umA, respectively)  was  then used to calculate each  of  the size-
specific emission factors using the total  mass  emissions as determined
above.   The results  of  such a determination are  also shown graphically  in
Figure 3-5.   Copies of appropriate calculations are contained in Appendix K.

     Table 3-35 also contains an  emission factor  for condensable organics
as determined from Reference 27.   This factor is  based on data taken directly
from the report with no further manipulations.   Since the data base used to
derive the total mass emission factor for drum-mix plants theoretically  in-
cludes only measurements of the particulate matter contained in the exhaust
of the drum mixer at stack temperature and pressure,  it was deemed inappro-
priate to use the published factor for any determination  of condensable  or-
ganics.

3.5.4  Emission Factor Quality Rating

     The quality  of the average emission factors  contained in Tables 3-30
through 3-35 was  rated utilizing the following general criteria:28

     «  ~-A - Excellent:  Developed  only from A-rated test data  taken  from
          many randomly  chosen facilities  in the  industry population.  The
          source  category* is specific enough to  minimize variability within
          the source category population.

          B - Above average:  Developed  only from A-rated test data from a
          reasonable number  of  facilities.   Although no  specific  bias is
          evident,  it is not clear  if the facilities tested represent  a
          random  sample  of  the industries.   As  in the A-rating,  the source
          category  is specific  enough to minimize  variability within  the
          source  category population.

          C - Average:    Developed only from A- and B-rated test  data from a
          reasonable number  of  facilities.   Although no  specific  bias is
          evident,  it is not clear  if the facilities tested represent  a
          random  sample  of  the industry.  As in  the  A-rating, the source
          category  is specific  enough to minimize variability within  the
          source  category population.
    Source category:   A category  in  the emission factor table  for  which
   an  emission factor has been calculated  (generally a single process).

                                     79

-------
                TABLE 3-36.   SUMMARY OF  CANDIDATE EMISSION FACTORS FOR  CONVENTIONAL ASPHALT PLANTS
                                                  Emission Factor Rating:D
emulative Bass equal to or less than stated
Particle
size Cyclone f
(umA) Uncontrolled collectors
2.S uraA
5.0 ufflA
10.0 umA
15.0 |imA
20.0 itraA
0.825
3.46
13.6
23.4
30.1
5.02
11.2
21.1
29.0
35.5
slze'(%)
Multiple Gravity
centrifugal spray, Baghouse .
scrubbers8 towers collector
67.1 20.5
74.2 26.6
79.9 36.5
82.6 38.9
84.3 40.6
33.2
35.8
40.4
46.8
53.9
Total mass eaission factor
Cumulative
Uncontrol led
kg/Hg TbTton
0.185 0.370
0.777 1-55
3.06 6.12
5.27 10.5
6.79 13.6
22.5 45.0
particulate emission factor equal
Cyclone
collectors
kg/Mg Ib/ton
0.048 0.096
0.13 0.26
0. 18 0. 36
0.25 0.50
0.30 0.60
0.85 1.7
Multiple
centr 1 f ugal
scrubbers
kg/Mg
0.023
0.026
0.028
0.029
0.030
0.035
Ib/ton
0.046
0.052
0.056
0.058
0.060
0.070
to or less than stated size
Gravity
'spray towers
ka/Mg
0.041
0.053
0.073
0.078
0.081
0.20
Ib/ton
0.082
0.11
0.15
0.16
0.16
0.40
Baghouse,
collector
kg/Mg Ib/ton
0.003 0.006
0.004 0.008
0.004 0.008
0.005 0.01
0.005 0.01
0.01 0.02

a Aerodynamic
Rounded to
c Rounded to
d Rounded tc
From Table
frnm Tahla
diameter.

three significant figures
two significant
one significant
3-30.

figures.
figure.





, Unit weight of partlculatt natter per unit weight of
Unit weight of partlculate natter per
Unit weight of partlculate natter per





asphalt concrete

produced.
unit weight of asphalt concrete produced.
unit of weight of


asphalt concrete


produced.



1 ton
1 ton =
1 ton



= 2,000

Ib.


2,000 Ib.
= 2,000


Ib.





8 From Table 3-32.
h From Table 3-33.
  From Table 3-34.

-------
   10.0
 -*  1.0
 •u
 o
 o
 u
 e
    0.!
0.01
   0.001
       0.1
                      TTT
                                 I   I  I I  111
             1. Boghoujea

             2. Centrifugal Scrubbers

             3. Spray Towers

             4. C/cionai

             5. Uncontrol led
                                     I   I I  II
1
                                                                    10.0
                                                                    1.0
                                                                    O.I
                                                                        "3
                                                                         e
                                                                     c
                                                                     o
                                                                     u
                                                                    0,01
                       1.0                 10.0

                   Aerodynamic Particle Dicmef*r (^i
                O.OOt

             100.0
Figure 3-4.   Size-specific emission factors  for conventional

                  asphalt plants.
                                   81

-------
     "a
     o
     3
     u5
     J
     e
     i-
     o

     o

ro.o






0.0




1.0
0.1
0.
.* 1 till l~FF~
-
-
-
-
^
-



W
-

mm


_ U m Uncoitfrollad
„ C - Saghous*
* tii iTLi4n-iLnL
i I 11(111
- X*
X ~~~*




^
C S^ '
*—/ ''
/ /
* — u /
//



/
I 1 1 I * " I t
I i 1 1 1 I I U,
«*•* "*





^-»
p "^







*~*
-
1 1.0 10.0 10C
1 .U
1
o.i 7
N
I/I
1
*/*
c
a
"Z,
J
e
0.01 J
3
•ff
2
u
o
e
w
"I
0.001 "J
3
u
0.0001
.0
                        Aerodynamic Portiela Diameter
Figure 3-5.   Particle size distribution and size-specific emission
                factors for drum-mix asphalt plants.
                                  82

-------
          D - Below average:   The emission  factor was developed only from
          A- and B-rated  test  data  from a small number of facilities, and
          there is reason to suspect that these facilities do not represent
          a random sample  of  the industry.   There also may be evidence of
          variability within the  source  category population.  Limitations
          on the use  of  the  emission factor are footnoted in the emission
          factor table.

          E _- Poor:  The emission factor was developed  from  C- and  0-rated
          test data,  and  there  is reason to suspect  that the facilities
          tested do not  represent a random sample of the industry.   There
          also may be evidence  of variability within the source category
          population.   Limitations  on  the  use  of these factors are always
          footnoted.
The use of  the  above criteria is somewhat subjective depending to a large
extent on the individual reviewer.

     In the case of both uncontrolled conventional plants and those equipped
with cyclones,   it  was  found necessary, in some instances, to apply lower
quality (i.e., C-  and 0-rated) particle size data  to  a B-rated emission
factor.  Because of this  large difference in data quality, it became dif-
ficult to ascertain what the overall rating of  the  resultant  emission  fac-
tor should be.  Theoretically,  a B emission factor has been calculated from
only A-rated  data  sets  which should not be combined with  C or D particle
size data.  For  this  reason, a certain  amount of  good engineering  judgment
was employed  to  rate  the quality of the various emission factors obtained.
Even though the particle size data were sometimes only marginally acceptable,
they were applied to a high quality emission factor.  It would be expected,
therefore, that  something better than an order-of-magnitude estimate would
be provided by such a procedure.   For this reason, it was determined that a
minimum of D would be the most appropriate rating for the resulting emission
factors where large differences in data quality existed.

     Because the overall quality of the emission factors determined in this
study is generally low, it is helpful  to define the range of process operat-
ing parameters and  raw material  characteristics to which  the factors  are
most applicable.  Table 3-37 provides information extracted from each  ref-
erence document relative to the number of facilities tested compared to the
total plant population  in the United States, the  number of tests conducted
at each plant, the range of production rates tested, and the range of mineral
filter (% < 200  mesh) content  in the aggregate used in each  study.  From
the available data, no good correlation could be derived which relates emis-
sions to mineral filler content even though it is expected that such a rela-
tionship does actually exist.  The information contained in Table 3-37 should
give at  least a  general idea of what the process  operating conditions  were
during testing and  thus,  where the above  emission  factors can be  applied
with at least a marginal degree of confidence.
                                     83

-------
                           TABLE 3-37.  RANGE OF SOURCE OPERATING CHARACTERISTICS APPLICABLE
                                          TO THE CANDIDATE EMISSION FACTORS
                                             No. of
             Reference    No. and type    particle size
                                          Percent
                                          of total
                                         population
                              Range of
                             production
                               rates
                             Range of
                          mineral filler
                          content in wet
                No.     of plants tested  tests/plant3   by process type  tested (TPH)   aggregate (% wt)c
00
-P-
 \       6-conventional
 3      10-conventional
 8       2-conventional
12       1-conventional
26       1-conventional
27       1-drum-mix
  1
1 to 3
1 to 2
  1
  1
 16
0.16
0.26
0.06
0.03
0.03
0.2%
 92 - 198
 28 - 147
180 - 225
   173
   170
138 - 372
1.6 - 2.9
  2 - 10
    N/A
    1.6
    N/A
1.5 - 5.4
                Either controlled or uncontrolled tests - not total number of runs.
                TPH - tons (2,000 Ib) of asphalt concrete produced per hour.
                N/A - not available.

-------
                         REFERENCES FOR SECTION 3


 *1.   R.  M.  Ingels,  et al. ,  "Control  of Asphaltic  Concrete Plants  in
      Los Angeles County." JAPCA,  10(l);29-33, February 1960.

 *2.   Resources  Research,  Inc.,  Gujjje_for Air Pollution Control Hot-Mix
      Asphalt Plants,  Information  Series 17,  National  Asphalt  Pavement
      Association, Riverdale,  MD,  1965.

 *3.   P,  Wiemer,  "Dust Removal  from the Waste Gases of Preparation Plants
      for Bituminous Road-Building Material,"  Staub-Reinhalt, Luft, 27{7):
      9-22, July 1967.

 *4.   H.  E. Friedrich, "Air Pollution  Control  Practices at Hot-Mix Asphalt
      Paving Batch Plants," JAPCA. 19(21):924-928, December 1969,

  5.   Environmental  Pollution  Control  at Hot-Mix Asphalt Plants, Information
      Series 27, National  Asphalt  Pavement Association, Riverdale, MD, 1970,

 *6.   A.  E. Vandegrift,  et al..  Particulate Pollutant System Study. Volume III:
      Handbook of Emission Properties,  EPA Contract No. CPA-22-69-104, Midwest
      Research Institute,  Kansas City,  MO,  May 1971.

 *7.   L.  J. Shannon,  et al.,  Pajti^ulate Pollutant System Study, Volume II:
      Fine Particle Emissions.  EPA Contract No. CPA-22-69-104,  Midwest Re-
      search Institute,  Kansas  City, MO,  August 1971.

 *8.   J.  A. Crira  and W. D. Snowden, Asphaltic  Concrete Plants Atmospheric
      Emissions Study,  EPA-APTD-0936,  U.S.  Environmental  Protection Agency,
      Research Trfangle Park,  NC,  November 1971.

 *9.   Background Information  for the Establishmentof National  Standards of
      Performance for New Sources, Asphalt Batch Plants,  Draft  Report, EPA
      Contract  No.  CPA-70-142,  Task 2,  Environmental  Engineering,  Inc. ,
      Gainesville, FL,  March  1971.

*1Q,   G.  F. Odell, Particulate  Emissions from a Orum Mixer Portable Asphalt
      Plant Near Estacada, Oregon,  F,  Glen Ode11,  Consulting  Engineer,
      Portland, OR,  1972.

*11.   L.  C. Hardison,  and C,  A,  Greathouse, AirPollution Control Technology
      and Costs in Nine Selected Areas,  EPA-APTD-1555,  U.S.  Environmental
      Protection Agency,  Durham^ NC7 September 1972.

*12.   J.  A. Danielson,  and R.  S. Brown, "Hot-Mix Asphalt Paving Batch Plants,"
      Chapter 7, Air Pollution Engineering Manual, EPA-AP-40, U.S. Environ-
      mental Protection  Agency, Research  Triangle  Park, NC,  May 1973.
                                     85

-------
 13.   L.  L  taster. Atmospheric Emissions from the Asphalt Industry, EPA-650/
      2-73-046, U.S.  Environmental  Protection  Agency,  Washington, D.C.,
      December 1973.

 14.   BackgroundInformation of Proposed New Source Performance Standards:
      Asphalt Concrete Plants Petroleum Refineries, Storage Vessels. Second-
      ary Lead Smelters and Ref1ner_i_es^Br_ass._pr Bronze Ingot Production
   -  Plants. Iron and Steel Plants, and Sewage TreatmentPlants; Volume I,
      Main Text, APTC-1352a, U.S.  Environmental Protection Agency, Research
      Triangle Park, NC, June 1973.

*15.   J.  D. McCain, Evaluation of Centrifield  Scrubber. EPA-650/2-74-129z,
      U.S.  Environmental ProtectTonAgency, Research Triangle Park, NC, 1975.

*16.   T.  D. Searl,  etal.,  Asphalt  Hot-Mix Emission Study, Research Report
      75-1 (RR  75-1),  The Asphalt Institute, College Park, MD, March 1975.

*17.   J.  Robert,  et a!., Air Pollution  Emissions  and Control Technology,
      Asphalt Paving Industry.  EPS  3-AP-74-2,  Combustion  Sources  Division,
      Air Pollution Control  Directorate, Ottawa, Ontario,  Canada, April 1975.

*18.   R.  G. Lock,  Dust Control in Portable Asphalt Plants.  The  University
      of Calgary,  Department of Chemical  Engineering,  Calgary,  Alberta,
      Canada, September 1975.

 19.   G.  B.  Frame, Emission Survey for  Huron  Construction Company, Ltd.,
      Chatham, Ontario. Beck Consultants,  Ltd.,  Toronto,  Ontario, Canada,
      October 1975.

 20.   G.  B. Frame,  Emission Survey  for Warren  Bitulithic  Division, Ashland
      Oil Company, Ltd., Oownsview,Ontario,  Beak Consultants, Ltd., Toronto,
      Ontario, Canada, October 1975.

 217  JACA Corporation, Preliminary Evaluation of-the Drum-Mix-Process, EPA-
      340/1-77-004, U.S. Environmental Protection Agency,  Washington,  D.C. ,
      March 1976.

 22.   A.  J.  Chandler,  and G. B.  Frame, EmissionSurvey for Huron Construction
      Company, Ltd., Chatham, Ontario, Beak Consultants, Ltd., Mississauga,
      Ontario, Canada, September 1976.

*23.   E.  W,  Stewart,  and W. Smith, Source Sampling Report,  Experimental
      Asphalt Concrete Recycling Plant in Iowa. EPA Contract No.  68-01-3172,
      Entropy Environmentalists, Inc., Research Triangle  Park, NC, October
      1976.

 24.   A.  J.  Chandler,  Emission Survey for Huron Construction Companyt  Ltd.t
      Chatham, Ontajrki7 BeakConsultants, Ltd.. Mississauga, Ontario,  Canada,
      September 1977.

*25.   1.  S. Khan,  and T.  W. Hughes,  Source Assessment:   Asphalt  Hot Mix,
      EPA-600/2-77-107n, U.S. Environmental Protection  Agency, Cincinnati,
      OH, December 1977.

                                     86

-------
*26.
 28.



 29.



 30.



 31.


 32.


 33.


 34.
 35.
 36.
 37.
 38.
H.  J.  Taback,  et al.,  Fine Particle Emissions from Stationary and
Miscellaneous Sources in the South Coast Air Basin,  KVB  5806-783,
KVB, Inc., Tustin, CA, February 1979.
      T.  J.  Walker, et,
      Emissions from a
                 al., Characterization of Inhalable Particulate Matter
                 Drum-Mix Asphalt Plant, EPA Contract No. 68-02-3158,
                    8, Midwest  Research Institute, Kansas City, MO,
Technical Directive
February 1983.

Technical Procedures for Developing AP-42 EmissionFactors and Prepar-
ing AP-42Sections, U.S.  Environmental Protection Agency,  Research
Triangle Park, NC, April 1980.

S. Calvert, et al., Wet ScrubberSystems  Study,  Volume  I:   Scrubber
Handbook,  EPA-R2-72-118a,  U.S.  Environmental  Protection  Agency,
Research Triangle Park, NC, August 1972.

J. B. Galeski, Particle Size Definitions for ParticulateData Analysis,
EPA-600/7-77-129, U.S.  Environmental  Protection Agency, Washington,
D.C., November 1977.

J. P. Sheehy, et  al..  Handbook of Air Pollution,  999-AP-44,  U.S.  De-
partment of Health, Education, and Welfare, Durham, NC, 1968.

H. L Green,  and  W.  R. Lane, ParticuJate^CJpuds:  Dusts, Smokes and
Mists. E.F.N.  Spon, Ltd., London, 1964.

R. Dennis,  Handbook on Aeroso1s,  TID-26608, Energy Research and De-
velopment Admirn strati oni, Washington, D.C., September 1978.

W. 8.  Smith, et  al. ,  Technical Manual:  A Survey of Equipment and
Methods for Particulate Sampling in Industrial Process Streams,  EPA-
600/7-78-043,  U.S. Environmental Protection Agency, Research Triang1e
Park, NC, March 1978.

R. R. Wilson,  and W. B. Smith, Procedures Manual  for Inhalable Particu-
late Sampler Operation, EPA Contract  No. 68-02-3118, Southern Research
Institute, Birmingham, AL, November 1979.

Written communication from John S. Kinsey, Midwest Research Institute,
Kansas City, MO,  and William Krenz, South Coast Air Quality Management
District, El Monte, CA, May 4, 1982.

H. E. McMahon, and W.  C. Rogers,  Test Conducted at Griffith Company,
1601 Alameda Street,Wilmington, California, on July 23, 1957
      Division Report No.  C-393, County of Los Angeles Air Pollution
      District, Los Angeles, CA, September 1957.
                                                               Research
                                                               Control
R. M.  Burl in,  and H.  W. Linnard, Test Conducted at GHffith Company
Hot Asphalt Paving Batch Plant, 1380E. Arrow Highway, Irwindale,
Cal i forma, on February 7_f 1958,  Research  Division Report No.  C-426,
                       Air Pollution Control  District,  Los  Angeles,
      County of
      CA, March
           Los  Angeles
          1958.
                                     87

-------
39.  Telephone communication between William Krenz, South Coast Air Quality
     Management District,  El Monte,  CA,  and John Kinsey,  Midwest  Research
     Institute, Kansas City, MO, June 1, 1982.

40.  H. Devorkin, et al., Air Pol1_utip_n^_Sgurce Testing Manual, Los Angeles
     County Air Pollution Control District, Los  Angeles, CA, December 1972.

41.  F. S,  Eadie,  and R.  E, Payne,  "The Micromerograph A New  Instrument
     for Particle Size Distribution Analysis," British Chemical Enaineering,
     October 1956.

42.  E. Q. Laws, et al., "Classification of Methods for Determining Particle
     Size," Analyst, 88:156-187, March 1963.

43.  Written communication from Fred Kloiber, Fred Kloiber Associates, Col-
     lege Part, MD, to John Kinsey, Midwest Research Institute, Kansas City,
     MO, January 16, 1984.

44.  Telephone  communication  between Wesley  Snowden,  ASA  Consultants,
     Bellevue, WA,  and  John Kinsey, Midwest Research  Institute,  Kansas
     City, MO, May 1982.

45.  W. N.  Smith,  and J.  Campbell, Air  Pol 1 ution Test, December 1, 1970,
     Sloan Construction Company, Liberty, South  Carolina.  CMI  Systems,
     Chattanooga, TN, December 1970.

46.  Source Test Data for Harrison, Inc., Haryville, Tennessee, CMI Systems,
     Chattanooga, TN, May 1971.

47.  W. N. Smith, and G. Catlett, Air Pollution  Test, Minot Paving Company.
     Mi not. North Dakota. CMI Systems, Chattanooga, TN, June 1971.

48.  Telephone  communication between Hal Taback, KVB, Inc.,  Irvine,  CA,
     and^John Kinsey,^Midwest"Research"Institute, Kansas City, MO, -February-
     1983.

49.  A. D. Williamson, Procedures Manual for Operation of theDilution Stack
     Sampling System. EPA Contract No. 68-02-3118, Southern Research Institute,
     Birmingham, AL, October 1980.

50.  J. W.  Johnson,  et  aj., A  Computer-Based Cascade  Impactor  Data  Reduc-
     tion System.  EPA-60Q/7-78-042,  U.S. Environmental Protection Agency,
     Washington, D.C., March 1978.

51.  Dryer Principals. Sales Manual, p.  9205, Barber-Greene Company, Aurora,
     IL, November 1960.
  Indicates those documents found in the original  literature search which
  contain particle size data (see page 27).
                                    88

-------
                       4.0  CHEMICAL CHARACTERIZATION
     The  only data  available which chemically  characterize  the participate
emissions  from asphalt concrete plants  are those  included in  Reference 26
as described in  Section 3.0  of this  report.   A compilation  of these data
for the emissions from  the baghouse collector  is shown in Table 4-1 (Appen-
dix E, Table 4-59).   No such data were  collected far  the plant tested under
the IP program (Reference  27).
                   TABLE  4-1.  CHEMICAL  COMPOSITION  OF THE
                                  PARTICIPATE EMISSIONS FROM
                                  AN ASPHALT BATCH  PLANT
                                  CONTROLLED BY A BAGHOUSE
                                  COLLECTOR25
Type of element
or compound
WT % OF CUT
mf ANALYSIS
Arsenic
Barium
Calcium
Chromium
Iron
Potassium
Silver
(Sulfur)
Titanium
TOTAL3
Sulfates, H20 sol13 .
(sulfur, from S04 )
Nitrate (H20 sol}6
TOTAL ANALYZED
BALANCE

Percent
cyclone
62.1

t
t
2,4/0.3
t
3.S/0.5
1.5/0.5
t
(< 8)
t
8
2
(t)
t
10
90
100%
by weight
Filter
3.57

-
-
10/3
-
1/0.1
-
-
(< 4}
t
11



11
89
100*
                     t = Detected 1n concentration of < 1%.

                     ( } - Not included in total—sulfur and sulfates
                          are accounted for in sulfur XRF analysis.

                     a Analyzed by x-ray fluorescence.

                       Analyzed by wet chemistry.

                       Calculated from sulfates  (sylfurssylfate/3) to
                         compare with sulfur from XRF.

                                       89

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               5.0  PROPOSED AP-42 SECTION
     The proposed  revision  to  Section  8.1 of AP-42  is pre-
sented  in  the following pages.   It should  be  noted that  the
terms  "asphaltic cement"  and  "asphaltic  concrete" are used
in  this section  in  place  of  "asphalt  cement" and "asphalt
concrete"  as   is more  common  in  the  industry.    This  was
done  to be   consistent  with  the  current  version  of   Sec-
tion  8.1  of  AP-42.   Such  terminology has  not  been   used
elsewhere in this report.
                            90

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8.1  ASPHALTIC CONCRETE PLANTS

8.1.1  General1'2

     Asphaltic concrete paving is a mixture of well graded, high quality ag-
gregate and liquid asphaltic cement which is heated and mixed in measured quan
tities to produce  bituminous  pavement material.   Aggregate constitutes over
92 percent by  weight  of the total mixture.  Aside from the amount and grade
of asphalt used, mix  characteristics  are determined by the relative amounts
and types of aggregate used.  A certain percentage of fine aggregate (% < 74 p
in physical diameter)  is required for the production of good quality asphaltic
concrete.

     Hot mix asphalt paving can be manufactured by batch mix, continuous mix
or drum mix process.   Of these various processes, batch mix plants are cur-
rently predominant.  However, most  new installations or replacements to ex-
isting equipment are of the drum mix  type.  In 1980, 78 percent of  the total
plants were of  the conventional  batch type, with 7 percent being continuous
mix facilities and 15  percent drum mix plants.  Any of these plants can be
either permanent installations or portable.

     Conventional  Plants -  Conventional plants produce  finished asphaltic
concrete through  either batch (Figure  8.1-1) or  continuous (Figure 8.1-2)
mixing operations,  fiaw aggregate is  normally stockpiled near the plant at a
location where  the bulk moisture content will stabilize  to between 3 and
5 weight percent.

     As processing for either type of  operation  begins,  the aggregate is
hauled from the storage piles and is placed in the appropriate hoppers of the
cold feed unit.  The material is  metered from the hoppers onto a conveyor belt
and is transported into a gas or oil  fired  rotary dryer.  Because a substan-
tial portion of the heat is transferred by radiation, dryers are equipped with
flights designed to tumble the aggregate to promote drying.

     As it leaves  the  dryer,  the hot material drops into a bucket  elevator
and is transferred to  a set of vibrating screens and classified into as many
as four different  grades  (sizes).   The classified material then enters the
mixing operation.

     In a batch plant,  the classified  aggregate drops into four large bins
according to size.  The operator controls1  the aggregate size distribution by
opening various bins over a weigh hopper until the desired mix and weight are
obtained.  This material is dropped into a pug mill  (mixer) and is  mixed dry
for about 15 seconds.   The asphalt, a solid at ambient temperature, is pumped
from a heated  storage  tank,  weighed and injected into the mixer.   Then the
hot mix is dropped into a truck and is hauled to the job site.

     In a continuous plant,  the  dried and classified aggregate drops into a
set of small bins  which collect the aggregate and meter it through a set of
feeder conveyors  to another bucket elevator  and  into  the mixer.   Asphalt
is metered through the inlet end of the mixer, and retention time is
                         Mineral Products Industry                   8.1-1

                                     91

-------
 I

 fO
H
en
en
n

i
H

O
                    UCfNP



                    „ — < U
                      O^., IKnl liHulo*
               Coarse Aggregate

               Storage Pile
Aggregdle

  Pile
                                            Feeders  C
                                 Figure  8.1-1.   General process  flow diagram  for batch mix

                                                    asphalt  paving plants.

-------
 X
 H-
 P
 re
o
a.
ft
u
p
(X
en
rt
                                       UGINO
                                       >>_* f irfnlBt folrti
Op,
                                 Fine Aggregate
                                 Storage Pile
      Cold Aggregate Bins
                                                                 Exhaust lo
                                                                 Atmosphere
                                   u
   .  	 Draft Fan ( Location
   /T__r Dependent Upon
         Type of Secondary)
Primary Dust
Collector
                                                                               4®
                                            Feedari
                   Coarse Aggregate
                   Storage Pile
                                                      Conveyor
                                                                      Aspha 1 1
                                                                      Storage
                                                                                                                           Tlucl<
00
*~*
 I
                                 Figure 8.1-2.   General process  flow  diagram for continuous  mix
                                                       asphalt  paving plants.

-------
controlled by an  adjustable dam at the opposite end.  The hot mix flows out
of the mixer into a surge hopper, from which trucks are loaded.

     Drum Mix Plants  - The  drum mix process" simplifies  the  conventional pro-
cess by using proportioning feed controls in place of hot aggregate storage
bins, vibrating  screens  and the mixer.   Aggregate is introduced near the
burner end of the revolving drum mixer,  and the asphalt  is  injected midway
along the drum.   A variable flow asphalt pump is linked electronically to the
aggregate belt scales to control mix specifications.   The  hot mix is dis-
charged from the revolving drum mixer into surge bins or storage silos.  Fig-
ure 8.1-3 is a diagram of the drum mix process.

     Drum mix plants  generally  use parallel  flow design for hot  burner gases
and aggregate flow.   Parallel flow has  the advantage of giving the mixture a
longer time  to coat and  to  collect dust in the  mix,  thereby reducing partic-
ulate emissions.   The amount of particulate  generated  within the dryer in
this process is usually lower than that generated within conventional dryers,
but because asphalt is heated to high temperatures for a long period of time,
organic emissions  (gaseous  and  liquid aerosol) are  greater than in conven-
tional plants.

     Recycle Processes - In recent years, recycling of old asphalt paving has
been initiated in the asphaltic concrete industry.  Recycling significantly
reduces the amount of new (virgin) rock and  asphaltic cement needed to repave
an existing road.  The various recycling techniques include both cold and hot
methods, with the hot processing conducted at a central plant.

     In recycling, old asphalt pavement is broken up at a job site and is re-
moved from  the  road base.  This material is then  transported to the plant,
crushed and  screened  to  the appropriate  size for  further processing.   The
paving material  is then  heated  and mixed with new  aggregate (if  applicable),
to which  the proper amount of  new asphaltic cement is added  to produce  a
grade of hot^asphalt paving~~suitable for laying."   "~

     There are three  methods which can  be used to  heat  recycled  asphalt pav-
ing before  the  addition  of the  asphaltic cement:  direct flame heating, in-
direct flame heating, and superheated aggregate.

     Direct  flame  heating is typically performed with a drum mixer, wherein
all materials are simultaneously mixed  in the revolving drum.  The  first  ex-
perimental attempts at recycling used a standard drum mix plant and introduced
the recycled  paving and  virgin  aggregate concurrently  at the burner end  of
the drum.   Continuing problems  with excessive  blue  smoke emissions led to
several process  modifications,  such  as the  addition of heat  shields and the
use of split feeds.

     One method  of recycling involves  a  drum mixer with a heat dispersion
shield.  The heat  shield  is installed around the burner, and  additional cool-
ing air  is  provided to  reduce  the hot  gases to a temperature below 430 to
650°C  (800  to 12QO°F), thus decreasing  the  amount of blue smoke.   Although
now considered obsolete,  a drum  within  a  drum design has also been successfully
8.1-4                          EMISSION FACTORS

                                      94

-------
 H-
 O
 a
T)
H
O
e
n
I
01
Fine Aggregate

Srorage Pi 10
                        Coarse Aggregate

                        Storage Pile
                  Aggregate Feed Bins

                       (   V
                                                                                                                                Exhaust

                                                                                                                                Slack
                                                                            Heated Asphalt Storage Tank
                                                                                                                                Truck Load-out
oo
    Figure 8.1-3.   General process flow diagram for  drum  mix  asphalt

                                  paving plants.
 i
Ln

-------
used for recycling.   Reclaimed  material is introduced  into  the outer drum
through a  separate  charging chute while virgin material  is  introduced  into
the inner drum.

     Split feed drum mixers were first used for recycling in 1976 and are now
the most popular  design.   At about the midpoint  of the drum, the recycled
bituminous material  is  introduced by a split feed arrangement and is heated
by both the hot gases and heat transfer from the superheated virgin aggregate.
Another type of direct flame method involves the use of a slinger conveyor to
throw recycled material into  the  center of the drum mixer from  the discharge
end.  In this  process,  the recycled material enters the  drum along an  arc,
landing approximately at the asphalt injection point.

     Indirect  flame  heating  has  been performed  with special  drum mixers
equipped with  heat  exchanger  tubes.   These tubes  prevent the  mixture of
virgin aggregate and recycled paving from  coming into direct contact with the
flame and  the  associated  high temperatures.  Superheated aggregate can also
be used to heat recycled bituminous material.

     In conventional plants,  recycled paving can be introduced either  into
the pug mill  or  at  the discharge end of the dryer,  after which the tempera-
ture of the material is raised by heat from the virgin aggregate.  The proper
amount of  new  asphaltic cement  is  then  added to the virgin aggregate/recycle
paving mixture to produce high grade asphaltic concrete.

     Tandem drum  mixers  can also be used  to heat the recycle material.  The
first drum or  aggregate dryer is  used to  superheat  the  virgin aggregate,  and
a second drum or dryer either heats recycled paving  only or mixes and heats a
combination of virgin and  recycled material.  Sufficient  heat remains  in  the
exhaust gas from the first  dryer to heat the second  unit also.

8.1.2  Emissions and Controls

     Emission points at  batch,  continuous and drum mix asphalt plants  dis-
cussed below refer to Figures 8.1-1, 8.1-2 and 8.1-3, respectively.

     Conventional Plants -  As with most facilities  in  the mineral products
industry,  conventional asphaltic concrete  plants have two major categories of
emissions,  those  which are vented  to  the atmosphere through some type of
stack, vent  or pipe (ducted  sources),  and those  which are not confined to
ducts and  vents  but are emitted directly  from the  source to the ambient air
(fugitive  sources).   Ducted emissions are usually  collected and transported
by  an  industrial  ventilation system with  one or  more fans or  air movers,
eventually to  be emitted  to the  atmosphere  through some type  of stack.
Fugitive emissions  result  from process sources, which consist of a combina-
tion  of  gaseous pollutants and  particulate matter, or open dust  sources.

     The most  significant  source of ducted emissions  from conventional as-
phaltic concrete  plants  is the rotary  dryer.  The  amount of aggregate  dust
carried out  of the  dryer by  the  moving gas stream  depends upon a  number  of
factors, including the gas  velocity in  the drum,  the particle size distribution
 8.1-6                          EMISSION  FACTORS
                                       96

-------
of the aggregate, and the specific gravity and aerodynamic characteristics of
the particles.  Dryer emissioas also contain  the fuel combustion products of
the burner.

     There may also be some ducted emissioas  from the heated asphalt storage
tanks.  These may consist of combustion products from the tank heater.

     The major source of process  fugitives in asphalt plants is enclosures
over  the  hot side  conveying,  classifying and mixing equipment  which  are
vented into the primary dust collector along with the dryer gas.   These vents
and enclosures are  commonly called a "fugitive air" or  "scavenger" system.
The scavenger system may or may not have its own separate air mover device,
depending on the particular facility.  The emissions captured and transported
by the  scavenger system  are mostly aggregate  dust, but they may also contain
gaseous volatile  organic compounds (VOC) and a  fine aerosol of condensed
liquid particles.  This  liquid aerosol is created by the condensation of gas
into particles during cooling of  organic vapors volatilized from the asphal-
tic cement in the pug mill.  The amount of liquid aerosol produced depends to
a  large extent on  the  temperature of the asphaltic cement  and  aggregate
entering the pug mill.   Organic vapor and its  associated aerosol  are  also
emitted directly to the atmosphere as process fugitives during truck loadout,
from the bed  of  the truck itself during transport to the job site, and from
the asphalt  storage tank,  which also may contain small amounts of polycyclic
compounds.

     The choice  of  applicable  control equipment for the drier exhaust and
vent  line  ranges from dry mechanical  collectors to scrubbers and fabric col-
lectors.  Attempts  to apply electrostatic precipitators  have met with little
success.  Practically all plants  use primary dust collection equipment like
large diameter cyclones,  skimmers or settling chambers.   These chambers are
often used as  classifiers to return collected material  to the hot elevator
and to  combine it with the drier aggregate.  Because of high pollutant levels,
the primary  collector  effluent  is ducted to  a  secondary collection device.
Table 8.1-1  presents  total particulate  emission  factors for conventional
asphaltic  concrete  plants, with the factors  based  on  the type of control
technology employed.  Size specific emission factors for conventional asphalt
plants, also based on the control of technology used, are shown in Table 8.1-2
and Figure 8.1-4.  Interpolations of size data other than those shown in Fig-
ure 8.1-4 can be made from the curves provided.

     There are also a  number of  open  dust  sources  associated with conven-
tional  asphalt  plants.   These include vehicle  traffic  generating fugitive
dust  on paved  and  unpaved roads, handling aggregate material, and similar
operations.  The number and type of fugitive emission sources associated with
a  particular plant  depend on whether  the equipment  is portable or  stationary
and whether  it is  located adjacent to  a gravel pit or quarry.  Fugitive dust
may range  from 0.1  micrometers  to more than  300 micrometers in diameter.  On
the average,  5 percent  of cold aggregate feed  is  less  than 74 micrometers
(minus  200 mesh).   Dust that may escape collection  before primary control
generally  consists  of  particulate having 50  to 70 percent of the total mass
being  less than  74 micrometers.   Uncontrolled particulate emission factors
for various  types  of  fugitive  sources in conventional  asphaltic  concrete
plants  can be found in Section 11.2.3 of this document.

                         Mineral Products Industry                   8.1-7
                                      97

-------
           TABLE 8.1-1.  EMISSION FACTORS FOR TOTAL PARTICIPATE
               FROM CONVENTIONAL ASPHALTIC CONCRETE PLANTS3
                 Type of control                Emission factor
                                               kg/Mg      Ib/ton
b c
Uncontrolled *
Precleaner
High efficiency cyclone
Spray tower
Baffle spray tower
Multiple centrifugal scrubber
Orifice scrubber
Venturi scrubber
Baghouse
22.5
7.5
0.85
0.20
0.15
0.035
0.02
0.02
0.01
45-0
15.0
1.7
0.4
0.3
0.07
0.04
0.04
0.02

           References 1-2, 5-10, 14-16.  Expressed in terms of
           emissions per unit weight of asphaltic concrete pro-
           duced.  Includes both, batch mix and continuous mix
          .processes.
           Almost all plants have at least a precleaner follow-
           ing the rotary drier.
           Reference 16.  These factors differ from those given -
           in Table 8.1-6 because they are for uncontrolled
           .emissions and are from an earlier survey.
           Keference 15.  Range of values = 0.004 - 0.0690 kg/Mg.
           Average from a properly designed, installed, operated
           and maintained scrubber, based on a study to develop
           New Source Performance Standards.
          References 14-15.  Range of values = 0.013 - 0.0690
          fkg/Mg.
           References 14-15.  Emissions from a properly de-
           signed, installed, operated and maintained bag-
           house, based on a study to develop New Source Per-
           formance Standards.  Range of values = 0.008 - 0.018
           kg/Mg.
8.1-8                        EMISSION FACTORS
                                    98

-------
                  TABLE 8.1-2.   SUMMARY OF SIZE SPECIFIC  EMISSION FACTORS  FOR CONVENTIONAL ASPHALT PLANTS3


                                                  EMISSION  FACTOR RATING:  D

Cumulative
emulative
Particle
«l2cb
(ittA) Uncontrolled
2
H-
P 2,5 |i«A 0.83
(D
Q 5.0 (laA 3.5
10.0 l«iA 14
0 15.0 M"A 23
^ 20.0 M">* 30
rt
CO Total mags emission factor
M 	 ' 	
D. "Reference 23, Table 1-36.
fj Aerodynamic diaaeter.

Cyclone
paniculate eminion factor i atated (ize
•«<* $ stated lite (X)
Multiple
centrifugal
col lectori «c rubbers

S.O

11
21
29
36


Rounded



67

74
80
83
84


to two significant


Gravity
spray Bagbouac Uncontrolled
towers collector kg/Kg

21

21
3J
39
41


figures.



33

36
40
47
54






0,19

0,78
3.1
5.3
6.8

23



Ib/ton

0.37

1,6
6.1
11
14

4S



Cyclone
collector!
kg/Mg

o.os"1

0,13
o.ia
0.25
0.30

0.85



)b/lon

0.104

0.26
0,36
O.SO
0.60

1.7



Multiple
centrifugal
•crubbera
fcg/Hg

0.023

0,026
0.028
0.029
0.030

0.035



Ib/ton

0.046

O.OS2
0.056
O.OS8
0.060

0.070

Gravity
•pray lowers
kg/Kg

0,041

0.053
0.073
0.018
0.081

0.20



Ib/ton

0.082

0,11
0.15
0.16
0.16

0.40



collector
kg/Hg

0.003

0.004
0. 004
0.005
0.005

0.01



Ib/too

0.006

0.008
0.008
0,010
0.010

0.02



       Rounded to one significant figure.
00
I
IO

-------
               10.0
            —
            !
             VI
             I
             o
             o
             OJ
             s
             3
             u
0,1
                0.01
               0.00
                         1. Soghoum
                         2. Centrifugal Scrubb«rt
                         3. Spray Towars
                         4. Cyclonei
                         S._Uficoflfroll«
-------
     Drum Mix Plants -  As  with the other two asphaltic concrete production
processes, the most significant ducted source of particulate emissions is the
drum mixer itself.  Emissions from the drum mixer consist of a gas stream with
a substantial amount of particulate matter and  lesser amounts of gaseous VOC
of various species.  The solid particulate generally consists of fine aggre-
gate particles entrained in the flowing gas stream during the drying process.
The organic compounds,  on  the other hand, result from heating and mixing of
asphalt cement inside  the  drum,  which volatilizes certain components of the
asphalt.  Once the  VOC have sufficiently cooled, some condense to form the
fine liquid aerosol  (particulate)  or  "blue smoke" plume typical of drum mix
asphalt plants.

     A number of process modifications have been introduced in the newer plants
to reduce or eliminate the blue smoke problem, including installation of flame
shields, rearrangement  of  the flights inside the drum, adjustments  in  the
asphalt injection point, and other design changes.  Such modifications result
in significant improvements in the elimination of blue smoke.

     Emissions from the drum mix recycle process are similar to emissions from
regular drum mix plants, except that there are more volatile organics because
of the  direct flame volatilization of petroleum derivatives  contained in the
old asphalt paving.  Control  of liquid organic  emissions in  the drum mix re-
cycle process is through some type of process modification, as described above.

     Table 8.1-3 provides total particulate emission factors for ducted  emis-
sions in drum mix asphaltic concrete plants,  with available size specific emis-
sion factors shown in Table 8.1-4 and Figure 8.1-5.

            TABLE 8.1-3.  TOTAL PARTICULATE EMISSION FACTORS FOR
                     DRUM MIX ASPHALTIC CONCRETE PLANTS3

                         EMISSION FACTOR RATING:  B
                     Type of control         Emission factor
                                             kg/Mg    Ib/ton
Uncontrolled
Cyclone or mul tic lone ,
Low energy wet scrubber
Venturi scrubber
2.45
0.34
0.04
0.02
4.9
0.67
0.07
0.04

            3.
             Reference 11.  Expressed in terms of emissions per
             unit weight of asphaltic concrete produced.  These
             factors differ from those for conventional asphaltic
             concrete plants because the aggregate contacts and
             is coated with asphalt early in the drum mix pro-
            .cess.
             Either stack sprays, with water droplets injected
             into the exit stack, or a dynamic scrubber with a
             wet fan.
                          Mineral Products Industry                   8.1-11
                                    101

-------
    TABLE 8.1-4.  PARTICLE SIZE DISTRIBUTION AND SIZE SPECIFIC EMISSION FACTORS FOR
              DRUM MIX ASPHALT PLANTS CONTROLLED BY A BAGHOUSE COLLECTOR3

                              EMISSION FACTOR RATING:  D

Cumulative particulate emission factors
Cumulative mass i stated $ stated size
size (%) jd

b £
(MtnA) Uncontrolled Controlled kg/Mg Ib/ton 10 J kg/M$»
2.5 5.5 11 0.14 0.27 0.53
10.0 23 32 0.57 1.1 1.6
15,0 27 35 0.65 1.3 1.7
Total mass
emission
factor 2.5 4.9 4.9
Condensable
organics^ 3-9

10"3 Ib/ton
1.1
3.2
3.5


9.8
7.7

^Reference 23, Table 3-35.  Rounded to two significant figures.
 Aerodynamic diameter.
 Expressed in terms of emissions per unit weight of asphaltic concrete produced.  Not
 .generally applicable to recycle processes.
 Based on an uncontrolled emission factor of 2.45 kg/Mg (see Table 8.1-3).
 Reference~23.  Calculated using an "overall" collection efficiency of 99.8% for a
 baghouse applied to an uncontrolled emission factor of 2.45 kg/Mg.
 Includes data from two out of eight tests where ~ 30% recycled asphalt paving was
 processed using a split feed process.
 Determined at outlet of a baghouse collector while plant was operating with ~ 30%
 recycled asphalt paving.  Factors are applicable only to a direct flame heating
 process with a split feed.
    8.1-12
EMISSION FACTORS

     102

-------
100.0
s
-Q
1
VI
* 10.0
i
«
>
jj
3
U
1.0
0.1
0
	 1 	 1 — 1 1 i| IT





.
-
M

U = Uneontroi lad
C = flaghowe
	 1 	 1 — ; i i m
/—



C /''

* — u /


//
/^
1 I 1 ! 1 I 1 I
	 1 	 1 — r-TTTTC
-
r*^*

'



,-— "*


I L < 1 1 i 11
.1 1.0 10,0 lOf
°'' 1
N
•a
u
s.
ist
VI
0.01 2
u
a
1
J
".2
J
3
0.001 U
0.0001
3.0
           Aerodynamic Particle Diameter
Figure 8.1-5.  Particle size distribution and size
     specific emission factors for drum mix
            asphaltic  concrete plants.
             Mineral Products  Industry

                        103
8.1-13

-------
Interpolations of the data shown in Figure 8.1-5 to particle sizes other thaa
those indicated can be made from the curves provided.

     Process fugitive emissions normally associated with batch and continuous
plants from the  hot side screens, bins, elevators  and pug mill have been
eliminated in  the drum mix process.  There may  be,  however, a  certain amount
of fugitive VOC  and liquid aerosol produced  from  transport and handling of
hot mix from the drum mixer to the storage silo, if an open conveyor is used,
and also from the beds of trucks.  The open dust sources associated with drum
mix plants are similar to those of batch or continuous plants, with regard to
truck traffic and aggregate handling operations.

8.1.3  Representative Facility

     Factors  for various materials  emitted  from  the  stack of a  typical
asphaltic concrete plant are given in Table 8.1-5, and the characteristics of
such a plant  are shown in Table  8.1-6.  With  the exception of  aldehydes, the
materials listed in Table 8.1-6  are  also emitted from  the  mixer, but in con-
centrations 5  to 100 fold smaller than stack gas  concentrations,  and they
last only during the discharge of the mixer.

     Reference 16 reports mixer emissions of SO , NO , and VOC as "less than"
values, so  it is possible they may  not be present at all.  Particulates,
carbon monoxide, polycyclics, trace metals and hydrogen sulfide were observed
at concentrations that were  small relative to stack amounts.   Emissions from
the mixer are thus best treated as fugitive.

     All emission factors  for  the typical  facility are for controlled opera-
tion and are  based  either  on average industry practice shown by survey  or on
results of actual testing in a selected typical, plant.

     An industrial  survey16  showed that over  66 percent  of operating hot mix
asphalt plants use  fuel-oil  for^combustion.   Possible-sulfur oxide emissions—
from the stack were calculated, assuming that all sulfur  in the fuel oil is
oxidized to SO .  The amount of sulfur oxides actually released through the
stack may be  attenuated  by water scrubbers, or  even by the aggregate itself,
if limestone  is being dried.  Number 2 fuel oil has an average sulfur content
of 0.22 weight percent.

     Emission factors for nitrogen oxides, nonmethane volatile organics, car-
bon monoxide,  polycyclic organic material, and aldehydes were determined by
sampling stack gas at the representative asphalt hot mix plant.
8.1-14                           EMISSION  FACTORS
                                      104

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 TABLE 8,1-5.  EMISSION FACTORS FOR SELECTED GASEOUS POLLUTANTS
       FROM A CONVENTIONAL ASPHALTIC CONCRETE PLANT STACK3

Material emitted
Sulfur oxides (as S02)d'e
Nitrogen oxides (as H02)
Volatile organic compounds
Carbon monoxide
Polycyclic organic material
Aldehydes
Formaldehyde
2-Methylpropanal
( is obutyr aldehyde)
1-Butanal
(n-butyr aldehyde)
3-Methylbutanal
(isovaleraldehyde)
Emission
Factor
Rating
C
D
D
D
D
D
D

D

D

D
Emission
g/Mg
146S
18
14
19
0.013
10
0.075

0.65

1.2

8.0
c
factor
Ib/ton
0 . 292S
0,036
0.028
0.038
0.000026
0.02
0.00015

0.0013

0.0024

0.016

.Reference 16.
 Particulates, carbon monoxide, polycyclics, trace metals and
 hydrogen sulfide were observed in the mixer emissions at con~
 centrations that were small relative to stack concentrations.
^Expressed as g/Mg and Ib/ton of asphaltic concrete produced.
"Mean source test results of a 400 plant survey.
 Reference 21.  S - % sulfur in fuel.  S02 may be attenuated
r5Q% by adsorption on alkaline aggregate.
 Based on limited test data from the single asphaltic concrete
 plant described in Table 8.1-6.
                    Mineral Products Industry
                                105
8.1-15

-------
              TABLE  8.1-6.  CHARACTERISTICS  OF A  REPRESENTATIVE
               ASPHALTIC  CONCRETE  PLANT SELECTED  FOR SAMPLING**
               Parameter                        Plant sampled


           Plaat  type                       Conventional,  permanent,
                                             batch plant
           Production  rate,
            Mg/hr  (toos/hr)                160.3 ± 16% (177 ±  16%)
           Mixer  capacity,
            Mg  (tons)                        3.6 (4.0)
           Primary  collector                Cyclone
           Secondary collector              Wet  scrubber  (venturi)
           Fuel                             Oil
           Release  agent                    Fuel oil
           Stack  height, m  (ft)              15.85 (52)


           Reference  16, Table  16.


 References for  Section 8.1

  1.   Asphaltic^oncrete Plants  Atmospheric Emissions Study,  EPA Contract No.
      68-02-0076, Valentine,  Fisher,  and Toinlinson, Seattle, WA,  November 1971.

	2.   Guide for  Air pollution Controlof Hot Mix AsphaltPlants,   Information
      Series 17,  National Asphalt Pavement Association,  Riverdale,  MD,  1965.

  3.   R.  M. Ingels, et al., "Control of Asphaltic Concrete Batching Plants in
      Los Angeles  County", Journal  of the Air^Pollution  Control  Association,
      10(1):29-33,  January  1960.

  4.   H.  E. Friedrich, "Air  Pollution Control Practices  and Criteria for Hot
      Mix Asphalt Paving Batch Plants", Journal  of the Air Pollution Control
      Association,  ^£(12):924-928, December 1969,

  5.   Air Pollution Engineering  Manual, AP-40, U. S. Environmental Protection
      Agency,  Research Triangle  Park, NC, 1973.  Out of Print.

  6.   G.  L. Allen,  et  al.,  "Control  of Metallurgical and  Mineral  Dust and Fumes
      in Los Angeles County,  California", Information Circular 7627, U.  S.  De-
      partment of Interior, Washington, DC, April 1952.
 8.1-16                          EMISSION FACTORS
                                        106

-------
 7.   P.  A.  Kenline,  Unpublished  report  on control  of  air .pollutants  from chem-
     ical process  industries,  U.  S.  Environmental  Protection Agency,  Cincinnati,
     OH, May 1959.

 8.   Private communication on particulate pollutant study between G. Bailee,
     Midwest Research Institute,  Kansas City,  MO,  and U.  S.  Environmental Pro-
     tection Agency, Research  Triangle  Park, NC, June 1970.

 9.   J.  A.  Danielson, Unpublished test  data from asphalt  batching plants, Los
     Angeles Comity  Air Pollution Control District, Presented at  Air Pollution
     Control Institute, University of  Southern California,  Los Angeles,  CA,
     November 1966.

10.   M.  E.  Fogel,  et al., Comprehensive Economic Study of Air PollutionCon-
     trol Costs  for  Selected Industries and SelectedRegions,  R-OU-455,  U.  S.
     Environmental  Protection  Agency, Research Triangle  Park,  NC, February
     1970.

11.   Preliminary Evaluation of Air Pollution Aspects  of the  Drum  Mix Process,
     EPA-340/1-77-004, U.  S. Environmental Protection Agency,  Research Triangle
     Park,  NC, March 1976.

12.   R.  ¥.  Beaty and B.  M.  Bunnell,  "The Manufacture  of Asphalt Concrete Mix-
     tures  in the Dryer Drum", Presented at the Annual Meeting of the Canadian
     Technical Asphalt Association,  Quebec City, Quebec,  November 19-21,  1973.

13.   J-  S. Kinsey, "An Evaluation of Control Systems and Mass Emission Rates
     from Dryer  Drum Hot Asphalt  Plants", Journal  of  the_  Air Pollution Control
     Association,  26(12):1163-1165,  December 1976.

14.   Background  Information for ProposedNew Source Performance Standards,
     APTD-1352A  and  B, U.  S. Environmental Protection Agency,  Research Triangle
     Park,  NC, June  1973.

15.   Background  Information for NewSource PerformanceStandards, EPA 450/2-74-
     003, U. S.  Environmental Protection Agency,  Research Triangle Park, NC,
     February 1974.

16.   Z.  S.  Kahn  and  T. W.  Hughes, SourceAssessment:   Asphalt Paving Hot Mix,
     EPA-600/2-77-107n, U.  S.  Environmental Protection Agency, Cincinnati,  OH,
     December 1977.

17.   V.  P.  Puzinauskas and L.  W.  Corbett, Report on Emissions from Asphalt Hot
     Mixes,  RR-75-1A,  The  Asphalt Institute, College Park,  MD,  May 1975.

18.   Evaluation  of Fugitive Dust  from Mining,  EPA Contract  No.  68-02-1321,
     PEDCo Environmental, Inc.,  Cincinnati, OH, June  1976.

19.   J.  A.  Peters  and P. K. Chalekode,  "Assessment of Open Sources",  Presented
     at the  Third National Conference on Energy and  the Environment, College
     Corner, OH, October 1, 1975.
                          Mineral Products Industry                   8.1-17
                                      107

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20.  Illustration of Dryer Drum Hot Mix Asphalt Plant,  Pacific Environmental
     Services, Inc., Santa Monica,  CA,  1978.

21.  Herman H. Farsten,  "Applications  of  Fabric Filters to Asphalt Plants",
     Presented at the 71st Annual Meeting of the Air Pollution Control Asso-
     ciation, Houston,  TX, June 1978,

22.  Emission of Volatile Organic Compounds from Drum Mix AsphaltPlants,  EPA-
     6QQ/2-81-G26, U. S.  Environmental Protection Agency,  Washington,  DC,
     February 1981.

23.  J. S. Kinsey, Asphaitic Concrete  Industry - Source Category Report, EPA
     Contract No. 68-02-3999,  Midwest  Research Institute, Kansas City,  MO,
     September 1985.
                                EMISSION FACTORS
                                      108

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          APPENDIX A
REFERENCE 1 AND SUPPORTING DATA
              A-l

-------
Control  of ASPHALTIC  CONCRETE PLANTS
in  Los  Angeles  County*
                                                                         Used  by  permission of  JAPCA.
                                                  RAY M. INGELS, Air Pollution Engineer, NORMAN R. SHAFFER
                                              Inrermedfeta Air  Pollution Engineer and JOHN A. DAN1ELSON Senior
                                                Air Pollution Engineer, Los Angeles County Air Pollution  Control District
Introduction
  The phenomenal growth of population
in Southern California during the last
tiro  decades has resulted in large de-
mands for asphaltic concrete.   To meet
these demands, in Los Angeles County
alone, 48 asphaitic concrete plants have
been built which produce an average of
14,000 tons per day.
  Prior   to  the installation  of  well-
designed air pollution control equip-
ment, dust  losses from asphaitic con-
crete plants were nearly 25 tons per day.
In 1949, the Air Pollution Control Dis-
trict of  Los Angeles County adopted a
rule which limited the discharge of dust
from each of these plants to 40 pounds
per hour.1  To meet this prohibition, it
became necessary to" install dust collec-
tion equipment capable of high collec-
tion  efficiencies. "This   was  accom-
plished  by the use of centrifugal or im-
pingement type scrubbers which pro-
Tided collection  efficiencies,  in  most
cases, of 90 percent or greater.  The de-
sign  of  these  control devices has  im-
proved  over the years, and as described
later in this paper, total emissions have
decreased substantially in spite  of in-
creased production.

 Description of Basic Equipment
   Generally, an asphaitic concrete plant
consists of a rotary dryer, screening and
classifying  equipment,  an  aggregate
 weighing system, a mixer, storage bins
 and  conveying equipment.  Sand and
 aggregate are  charged from bins into a
 rotary  dryer.  The dried aggregate at
 the lower end of the dryer is mechani-
 cally conveyed by a bucket elevator to
 the screening  equipment where it is
 classified and dumped into storage bios.
   * Preheated at the 52nd Annual Meeting
 of APCA,  Statler  Hotel,  Jima 21-2S,
 1950, Los Angeles, Calif.

 hbnntry I960 / Voium* 10, Numb.r 1
Weighed quantities of the sized prod-
acts are then dropped into the mixer
along with asphalt where the batch is
mixed and dumped into awaiting trucks
for  transportation to the paving site.
The combustion gases and fine dust
from  the rotary  drier are exhausted
through a precieaner which is usually a
single cyclone,  but twin or multiple
cyclones and other devices are also used.
The precieaner catch is then discharged
back into the bucket elevator where it
continues in process with the "lain bulk
of the dried aggregate.  The air outlet
of the precieaner is vented to air pollu-
tion control equipment.
Air Pollution Control Equipment

  In Los Angeles County two principal
types of control equipment have evolved
from many types etaployed  over the
years—the  multiple  centrifugal" "type
spray chamber  and  the baffled  type
spray tower.*Of these two types, the
multiple centrifugal type spray chamber
(Fig. 1) has proved to be the  more effi-
cient.  It consists of two or more inter-
nally fluted cylindrical spray  chambers
in which the dust-laden gases are "ad-
mitted tangentially  at high velocities.
Each of these chambers is identical in
size and has dimensions approximately
    Rg. I. Typieol muillpla centrifugal ryp« ioray diamb«rurviitg on aiphalhc eanerel* plan*.


               A-2

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          RS» 2. -Typical baffled fyp« »pray low« itrring an cnphaitfe concrete plane.
          saamt IMUI oust uuamo —
Rg. 3.  Reiationinip between urvbbw M«r dint
loading  and  tcnibbw  collection
30
Rf, 4,  Effect of  lOvboer  »afer-gai ratio
on stack cfnisiioni at average aggregate dn«i
ret* in ihe dryer feed,

              A-3
                                            6 ft diam x IS ft long.   Usually five to
                                            10  spray  nozzles  are  located evenly
                                            spaced  within each  chamber.   Water
                                            rates  to the nozzles are usually in  the
                                            range of 70 to 250 gpm at 50 to 100 psi
                                            and the water generally Is not recireu-
                                            tated.   In the baffled type spray tower
                                            (Fig,  2),  there have  been many vari-
                                            ations in designs,  but fundamentally,
                                            each  consists  of a chamber  which is
                                            baffled to force the gases to travel in an
                                            S-sfaaped pattern, encouraging impinge-
                                            ment  of the dust  particles against  the
                                            sides  of  the chamber and the  baffles.
                                            Water spray  nozzles  are  located  be-
                                            tween  the  baffles  and water • rates
                                            through  the spray heads usually vary
                                            between 100 to 300 gpm at 50 to 100 paL
                                              In addition to venting the dryer, the
                                            dust collection system also  ventilates
                                            several other dust sources which include;
                                            (1) the lower end of the dryer where the
                                            stationary burner  box attaches to the
                                            rotary dryer;  (2) the aggregate screen-
                                            ing  and classifying system;  (3)  the
                                            bucket elevator; (4) the aggregate stor-
                                            age  bins; and  (5) the weigh hopper.
                                              Asphaltic concrete plants vary in size
                                            with the majority capable of producing
                                            100  to 150 tons per hour.  However, in
                                            the last two or three years, several plants
                                            have  been  installed  in Los  Angeles
                                            County  which  are classified as  6000-
                                            pound plants, capable of producing 200
                                            to 250 tons per hour.
                                             The major source of  dust originates
                                            from the rotary dryer.   Very little work
                                            has been done in the study of dust emis-
                                           sions  from  rotary  dryers.  Friedman
                                           and  Marshall1 obtained  data  showing
                                           that dryer dust emissions, expressed  aa
                                           percent of feed, increase with air maqg
                                           velocity, increase with increasing rate of
                                           rotation,  are  independent  of  dryer
                                           slope, and decrease with increasing feed
                                           rate.   The  absolute amount  of drver
                                                                                      OU*Mftf¥ OP HNii I
                                                                                                      B MlMI IM QIVT* RIO — kA"* X
fte. J.  Effect of aggregate Hne< rate an track
•flihtian* at average wafer-gai ratio.


       Journal of the Air Peifurfon AiKxiatlan

-------
                         TabN I—T«s* Pqtq from Atphglttc Concrete Plants Controlled by Scrubbers
UJ
a
HI
Inlet Dust Emission, lines Kate,* Ratio,
TV* Loading, Lb/Hr, Lb/Hr XW', Gal/1000 set,
;""::;- 940 20.7 9.55 8.62
•~£r 427 3S.6 4,46 3.34
••bfi 4iio 37.1 8.3S 6.38
••«A 2170 47.0 14.00 6.31

m$ 	 32UJ 	 2O 	 Ol 	 ITS!
*CiHS 1640 2lJ S\22 li^ifl
• H — 31.0 8.8S 20.40
UiitAto lab. — 33-5 7.52 11.01
<'"t79 3850 30.3 8.50 5.92
C-SH" 308 13.6 2.51 11.11

C-234 372 21.2 2.53 5.70
C-428 2820 25.5 10.20 7,75
C-U7 560 39.9 3.05 2.94
&425 485 32.9 2.89 4.26
OuUtdelab. — £5.5 6.59 6.60
C485 212 17.5 4.89 4.56
C433 266 11.0 5.96 8.12
£422Ci) — 28.6 7.14 4,90
tSitSJ — 37.0 3.34 3.02
C-118 3400 30.8. 9.35 8.90
Totals 667,4 146.93
Avtrages 29.7 5.9
Type Type Effluent
of of Production, Volume,
Log xi Scrubber* Fuel Tons/Hi sefin
0.82 C Oa 183.9 23,100
0.60 C Oil 96.9 19,800
0.81 C Oil 174.0 26,200
0.83 C Oil 209.1 25,700
1.04 C OU 142.9
1 05 C >ft* 158.0 	

1~Q8 T Otl 92.3 19.500;
— 09 	 T 	 da no rjm
1.29 T Oil 137.8 18,700
1.31 T Oil 184.2 17,000
1.04 T Oil 144. ft 23,700
0.77 C Gaa 191.3 28,300
1.05 C Oil 114.6 24,300
0.86 T Gas 124.4 15,900
0.78 T Gaa 42.0 17,200
0.89 C' OU 182.0 22,000
0.47 C Oil 138.9 24,600
0.63 C OU 131.4 18,000
0.82 C CM 131.7 18,200
0.68 C Oil 174.3 20,000
0.91 C Gaa 114.5 19,600
n RO C Oil WR 0 21.000
0.48 C Oil 152.0 22,200
0.95 T Oil 116.5
21.33
0.85
17,100


       * Quantity of finea (minus 200 mesh) in dryer feed.
       1 C •• Multiple centrifugal type spray chamber.  T — Baffled tower scrubber.
     dust, in weight per unit time, increases
     with feed rate.  Dust emissions depend
     to a large extent on the particle size dis-
     tribution of the dryer feed.  While the
     dust from  the  rotary  dryer  is  un-
     doubtedly the greatest source, the dust
     collected from the vibrating screens, the
     backet elevator, the bins and the weigh
     hopper is also considerable in quantity.
     In one plant, 2000 Ib/hr of particu-
     late matter containing 39.7 percent of
     0 to 10 micron material was produced by
     these secondary sources."

     Study of Stock Test Dale      	
        In the process of granting  permits to
     operate, many stack  tests  were con-
     ducted by the District  to insure that
     each plant was operating in compliance
     with air pollution laws.  Aa these data
     became available, a study was made to
determine which variables were most
jognifiamt in affecting emissions to the
atmosphere.  A  preliminary  observa-
tion disclosed that the  water scrubber
efficiency varied with the scrubber inlet
dust loading as shown in Fig. 3.  Higher
dust collection efficiencies were obtained
at  the  higher  inlet  dust   loadings.
Plants with less effective cyclone pre-
nlpnning had, on the average, larger par-
ticles entering the water scrubber, and
consequently better scrubber collection
efficiencies  were  obtained.   In  fact,
scrubber efficiency  was so dependent
upon the degreeTof precleaning^that the
effect of other  variables  on collection
efficiency was completely masked in the
available  data.  However,  the  frac-
tional collection efficiency of particles
larger than  10  microns  in  diameter
proved to  be  99.7 percent.  Conse-
 quently,  the variables  and  operating
 conditions  which  affect  the amount
 and collection efficiency of the 0 to 10
 micron fraction should be refiected in
 the absolute stack emissions.  This was
 found to be the case.  The magnitude
 of the stack emissions were found to de-
 pend mainly upon the scrubber water-
 gas ratio, the type of fuel used in the
 rotary dryer, the type of scrubber, and
 the quantity of minus 200-mesh material
 (minus  74 microns) processed in the
 dryer.4   It would be expected that the
 particle size  distribution of the  minus
~2QO-mesh"~fraetion  of ""the dryer-feed-
 would have a large effect on stack losses,
 but sufficient data were  not available
 to investigate it.
   Twenty-five source testa of asphaltic
 concrete plants were  available  (from
 some  US testa which have  been  per-
                      Tabl* II—Collection Efficiency Data far Scrubber* Serving AsphalHc Concrata Plants
1
CO
UJ
09
1 —
a
UJ
ZD
h-
Dwrt
Particle
Size,
Microns
0-10
10-20
20-44
44+
Dust
Furtiek
Size,
Microns
0-10
10-20
1-44
44+
. 	 Test
Inlet,
%
13.0
n.i
9.6
6.3

Report Series,
Outlet,
%
99,3
0.0
0.0
0.7
	 r— 	 XC31

91.0
9,0
0.0
0.0
C-333 	
JtlSiCIGQC^f
%
95.2
100.0 '
100.0
99.3
Outlet,
82.0
3.0
2.0
13.0-
• 	 Teat
Inlet,
%
76.4
6.3
2.8
14.5
Report Series,
Outlet,
%
79.9
3.8
2.0
14,3"
Efficiency,
85,7
99.4
C469 	 .
SfflciftEcy,
%
92.8
98.0
95.0
93.1
Inlet,
80.4
18.6
1.0
0.0
— — Teat Report Series,
Inlet, Outlet,
78.0 S3,0
18.0 5.0
2.0 1.0
2.0 11.0*
Outlet,
73,2
5.1
4.5
17.2
C-372A — .
Efficiency,
85.0
96,2
93.3
26.5
Efficiency,
—
        * Microscopic examination indicated that toe outlet mm plea wen agglomerated.
      February I960 / Vdum«.10,
               A-4
                                   31

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    •Dr-
 I  JL
 i
                                                                         -J40
                                                        on. HBO omi
                J_
_L
J	I
J_
I	I
                                                   J_
                                                                   I
                                                                       I
                                                                           29 ~
                 *    i   ifl   11   i*  i*       a    3   «   »   i   to  u  M  it
                   QUANTITY Of NNEt (MNUS 200 MSH} IN MYO TOO — Itf/H* X 19"'

                tdktfon curYoj for muitfpl* e«ntttfugal icrabfawi Mrring ojphclHe caner*t» plontt.
 fanned since 1949} which bad sufficient
 data to attempt to correlate the major
 variables affecting stack losses.  Aggre-
 gate feed rates, screen size  analyses,
 scrubber water and gas rates, as well as
 particuiate matter emissions to the at-
 mosphere were obtained during each of
 these tests.  The data are tabulated in
 Tables I and II.  Ths aggregate dryers
 were fired with PS 300 or heavier oik
 during 19 of the tests and natural pa
 fired during six.  Seventeen  of these
 teats were performed  on  multiple cen-
 trifugal type scrubbers with-spirai baffles
 and tangential  entrances.  The other
 eight  tests were performed on simple
 baffled tower scrubbers.  A curvilinear
 multiple  correlation  was  required to
 represent the data satisfactorily.  Eze-
 lael's* graphical procedure of successive
 approximations  was   used  to it  the
 curves (see  Appendix for correlation
 methods).
                      Hroct of Variables on Scrubber
                      Emissions

                        The effect of scrubber water-gas ratio
                      on stack emissions is shown in Fig. 4,
                      for multiple centrifugal type scrubbers
                      and baffled  tower scrubbers, with  the
                      aggregate fines rate (the  minus 200-
                      mesh  fraction)  held constant  at  the
                      average.  Low  scrubber water-gas  ra-
                      tios are more  than  proportionately
                      less effective than higher ratios.  Pos-
                      sibly, the water rate waa insufficient for
                      good spray coverage for ratios in  the
                      lower ranges.
                        The effect of aggregate fines rate on
                      stack emissions at constant water-gas
                      ratio is  shown  in Fig.  5 for multiple
                      centrifugal type scrubbers  and baffled
                      tower  scrubbers.  Stack emissions  in-
                      crease linearly with an  increase in the
                      amount  of  minus 200-mesh material
                      processed.
 w
 M
 ^
                                                          on. HMO ova
       J	I
                                           t   I    I
                                                                            §
                                                                          "I
    0    !    *   4   »   19   12   I*  14        gJ   J   4  ~j"

                 OU*NHTY OP NN€S (MINUS 200 M«K> IN 0»VW fttO —OS/Hi X 10"*

Hfl. 7.  Enrisikm pradictign e«r»«» fof  baffled Iaw«- icruober. iwvinQ aipheitie conertt* planrt.
32

   Stack emissions were 5.1 Ib/hr higher
 when the  dryer  waa oil fired, rather
 than gas  fired.  The difference is be*
 lieved  to  represent  paniculate  mat-
 ter in or formed by the fuel oil, rather
 than additional dust from the dryer and
 mixer.   It has  been similarly observed
 that burning heavy  fuel oils  in other
 kinds of combustion equipment results
 in higher emissions of particukte  mat-
 ter.  For  example, glass  furnaces dis-
 charge  significantly  more  particukte
 matter when fired by PS  300 or heavier
 fuel oils than when natural gas or  light
 fuel oils are used.*
   As expected, centrifugal type water
 scrubbers were more effective than sim-
 ple baffled tower water scrubbers.  The
 difference  averaged 5.0  Ib/hr at  con-
 stant aggregate fines rate and constant
 water-gas  ratio.
   The data, even when corrected for the
 variables studied, tend to scatter rather
 badly.   However, the results do repre-
 sent average trends of plants operating
 in the  Los Angeles area.  Curves are
 presented in Fig. 6 and 7 from which the
 most likely stack emissions can be pre-
 dicted for  oil and gas  fired plants with
 either multiple centrifugal  or  baffled
 tower scrubbers. These cunts present
 emissions for various scrubber water-gas
 ratios and  aggregate fines rates.
   During the course of conducting  sev-
 eral particle size analyses of scrubber in-
 let and outlet dust, an unusual obser-
 vation waa made.   In all of these tests
 as shown in Table II, the fractional col-
 lection  efficiency of  the  444-  micron
 material was less than for the 10-20 and
 the  20-44 micron  fractions, which of
 course is opposite to what would  nor-
 mally  be expected.  However,  micro-
 scopic examination  of the samples indi-
 cated that the particles in the scrubber
 outlet were agglomerated.   Apparently,
 the fine particles agglomerate writhin the
 scrubber, but part  of the resulting ag-
 glomerates escape to  the  atmosphere.
 This  potentially recoverable material
 constitutes  five  to 10 percent  of  the
 scrubber  emissions.  However,  these
 emissions are minor and even perfect col-
 lection of this material would not reduce
 total emissions over 3.5 Ib/hr.
 Survey of Dust Emissions in  Las
 Angeles County
   In order to evaluate the effect of the
 control program  on dust emissions from
 the aaphaltic concrete  industry, it  was
 necessary to acquire  information  con-
 cerning  the number of plants in oper-
 ation, emissions of dust to  the atmos-
 phere,  amount  of  aspludtic concrete
 produced, and volume 01 air handled.
  To obtain the data on production,
 number of plants, types of controls and
 operating schedules, a questionnaire waa
 devised and sent to each company oper-
ating an jisphaitic concrete plant".  The
data obtained from this survey indicated
 that in  IS5T there  were  19 companies

       Journal or tt»» Air Pollution Aiwa'ofion

-------
(tj>rraCinn  4S  plants  in  Los Angeles
County.  These plants produced a total
of 14.000 tons per day.  The data also
indicated  tliat asphaltic concrete was
produced over a 13-hr day with a maxi-
mum hourly output of 1200 tons.
  To augment the data obtained from
this  survey aod to make comparisons
ivith data'obtauied from previous sur-
veys, the analytical  test data in  the
District's  files on  asphaltio  concrete
plants   were  studied.    From   these
studies, average yearly dust emissions
to the  atmosphere  were determined.
During the early stages of the develop-
ment of the  control  program, many
stack tests disclosed emissions of dust
in excess of the weight per hour allowed.
As the design of control equipment im-
proved, violations became less frequent.
During recent years, excessive emissions
conld be traced to either poor experi-
mental  scrubber  designs,  or more  fre-
quently to poor maintenance. It was
observed that even well-designed scrub*
bers would emit  excessive  dust  if  a
sound  maintenance  program was  not
being enforced.
  Figure 8 illustrates the effect of the
increasing efficiency of the control equip*
meat from 1948 to 1958.  Prior to the
development  of  the  control program,
little or no control devices were installed
and  an average of five pounds of dust
were emitted  per ton of asphaltic con-
crete produced.  As  the control pro-
gram progressed  and the efficiency of
control  equipment was increased, dust
emissions were reduced until today only
0.15 pound is emitted per ton of asphal-
tic concrete produced.  The major re-
duction of dust was  accomplished be-
tween   1948   and -1950.  During this
period,  an  average reduction of  150
Ib/hr per•- plant  was achieved.  -From
1950 to  the  present  time, an average
reduction of 12 lb/hr per plant has been
accomplished  due to  improvements in
controls and  better maintenance pro-
pains.  '
  The increased efficiency of the control
equipment  was   accomplished   even
though the  average  volume of gasea
handled per plant has increased  from
13,000 standard cubic feet per minute
in 1951  to 21,000 standard  cubic  feet
per minute in  1958.   Figure 9 illustrates
this  increase in volume.  A reduction in
volume between  1048 and 1951  is be-
lieved  to be  partially  due  to conser-
vation of ps volume to  allow smaller
control  devices to be  installed.  Subse-
quent  to 1951, better control of dust
emissions from sources other than the
dryer required an increase in gas volume.
.Moreover, plants have increased in size
in recent years.
  The data.obtained  from surveys con-
ducted periodically on the asphaltic con-
crete industry show that production has
increased since 194S from an  average of
10,000 tons per day to more than 14.000
 tons per day in  1957 (Fig. 10), an in-
 crease of 40 percent.  During the same
 period, dust emissions decreased from
 25 tons per day to I ton per day, a de-
 crease of 96 per cent overall.

 Conclusion*

   In conclusion, it. is emphasized that
 the  variables  studied  only  represent
 average trends  of asphaltic  concrete
 plants  in Los Angeles  County.  With
 this point in mind, it can be concluded
 that;
   1. Multiple   centrifugal   scrubbers
 have proved to be more efficient than
 baffled towers.
   2. Scrubber water-gas ratio is equally
 important in both  types of scrubbers.
 The best utilization of water is achieved
 up to a ratio of six  gallons  per 1,000
 standard cubic feet of gas.  Above this
 ratio, efficiency still increases within the
 bounds studied, but at a lesser rate.
   3. Scrubber stack emissions increase
 linearly with an increase in the amount
 of minus 200-mesh material charged to
 the dryer.
   4. The hummg of PS 300 or heavier
 fuel oils rather than natural gas results
 in higher stack emissions.  Under con-
 stant conditions, an increase of approxi-
 mately five pounds per hour was  ob-
 served.  Although  the  available data
 are not conclusive, it appears that dust
 emissions  are  significantly  decreased
 when PS 200 oil is substituted for PS
 300 oiL
   Through the use of  scrubbers, dust
 emissions from asphaltic concrete plants
 have been  reduced from a total of 25
 tons per day to 1 ton per day.   If this
 is related to the increase in production
 over the 10-year period then the control
 program is responsible for a net removal
-of 34 tons per day of dust from the Los
 Angeles County atmosphere.

             REFERENCES
 1. Rule 54- Rules and Regulations of the
   Los Ansjelea County Air Pollution Con-
   trol District.   In essence,  this rale
   limits tha amount of  dust and fumes
   discharged to  the atmosphere in any
   one hour from any source baaed upon
   the  process weight.  For example,  u*
   100 tons per hour of sand and aggregate
   are charged to the dryer of tut aaptulltic
   concrete  plant, the process weight  la
   then 200,000 lb/hr.  The rule states
   that for process weights of 60,000 lb/Kr
   or more, the minimum weight of dust
   and fumes discharged to the atmosphere
   shall not exceed 40 lb/hr.
 2. 3. J. Friedman  and W. R. .Marshall,
   Jr., "Studies in Rotary Drying," CAem.
   Eng. Prog., 45:3, p. 482 (August, 1049).
 3. Los Angeles Countv Air Pollution Con-
   trol District, Teat fteport Series C-428,
   unpublished reports.
 4. R.  M.  Ifljels and G. 3.  Richards, Los
   Angeles County Air Pollution Control
   District,  unpublished report.
 5. M.  Ezekiel,  Methods of  Correlation
   Analyiai,  2nd Edition,  p.  ±M. John
   Wiley and Sons. New York (1041).
 tt. Los Angeles County Air Pollution Con-
   trol District, Teat Report 8«rie» C-372,
   unpublished report.
    8.  Redwafa" of dvxt «mi«kxu from «»
phattfe concrete plant! In lot Angela County
dudng Hi* period 1948 to 1953.
 I
 I   «
 8  m
 s
Fig. 9.  Aipholtie  concrete  plant average
Kruab,w *{Ry*n« •xoluai* in lot Anfleiet Cosirty
during  Hie period 1948 to 1938.
                            i*s»     1,1*
Fig. 10.  Avoreq* daily  production  and fetal
4
-------
i"  No.
C-W
6 ^
 O
Z.O
 1,0
2.0
                                                                                                             0.1
                                                                                                          /7Z.

-------
            South Coast
            AIR QUALITY MANAGEMENT L
HEADQUARTERS,
ANAHEIM OFFICE,
CARSON OFFICE.
COUTON OFFICE,
»130 C, FUAIR OR., *I- MONTK. CA »I731

Kid E. 9A 1.1. HO., ANAHEIM. CA taiOS . (714) 1*1-7200

»SO OOVUIN ft... SFACE €, CAR3ON, CA *074« . (SUl 51.--

Z2»50 COOUCV OM.. COUTON, CA 11324 . I7I4| tlflttO
%3&$g^%-'*!& W v -~- V--* -,: *-
t£*-?*&z>&&~'ri. ri>' '
-------
HR
                    JM COHISOL DISTRICT - COOHTT Off "6
                  ..^I EEDRG STSESI - IDS AHCSISS £,, CAIZFOHitli
                           TEST GOUDUCTED
                          GRIFF3SH ' COHPAHI
                         l£01 1IJMSDA SflSET
                                  , CIAXTFOBNIL
                                1EBD2E
                                CiT TEE
                       1METSES OF THE DISGHABGS
                     FROM A MUSE SCEQaBSa SEH7IB5
                      JLH02 ASIHJCEE ELAaT DHEBIG
                              on.
H. I. McMfflON
W. C. EOGESS
                                  BI
                                         HE FOLUJTICK EiGBEEE
                                   AIR K3LEOHOH EIGINSSR
                  BESEA1CH DIfTSION 1SB3ET  HO. G-393
                                 A-9

-------
  From
Elevates?
                                                                    Outlet
                           a - Baffin
                               yy&ya
                                                                 3 - Spray
                                                                     Nozalea
                                                              Wat
                                                               Station
                                                                                 t
  DUST QOHI&OL B2UZFHBIIT
nor AaHiAiff1 Mfoimia HAIW
     ORXEVHI! GOMPAlff
                                                                             Vfcter
                                                                                    fo
                                                                         I
£
a
                                                                                                              a
                                                                                                                      ;i.»
                                                                                                                      a
                                                                                                                      a
                                                                                                                      o

                                                                                                                      q
                                                                                                                      v-

                                                                                                                      !*-*

-------
             AIB POLLUTIof"CONTROL  DISTRICT -  COUNTY (    LOS ANGELES
                               SUMMARY  SHEET
                                                                   Page
                                                                             .of.
     of
Location  of
               Griff ith
                                                           .Test
                 1601
                              St.a wnm',Tigton, Cal±g
23, 195?
                                    NO
                                                  voa   ¥ater scrubber
Collection Equipment    Yea    T.
Specific Equipment Tasted.  ¥ater scrobbiag tcwer  serving hot asphalt.plant
Length of Process Cj>gi»                         T\mm Cycle R«*g>"
Total  Process- Weight           	;	P.W./hr.  I81t>560	
Sample- Statton	         • •  .   "       Inlet	;	
Time of Test        Begin	;	1;15 P> H.	31:CO A, ff.
                    End	
         Elapsed  Ttm»  (Test)
 Gas Volume SCFM {Standard Conditions)
 Material Coi lee-ted
     Srains/SCF at 1251 C02-
     Loss per hour In pounds.
 Allowable- Loss Lbs. per hour
 Percent Moisture In Gases
 Orsat  Analysis iDry Basis)
          Percent:  C02
                    Q2
                    CO
          N2(8y dlff.
Coribtistibles — percent
                                                           1:31 P. H.
         1:31 P.  M.
                                                             16
           53 si
                                                        20900
                                                                            1950Q
                                                            Particolate Matter
                                                           23.8
                                                         Ii260
                                                                               26,9
as. I s 1
3.2
2.6
15.9 17.0
1 0.0
80.9
2.6
- percent
O.C
80 JL
7.1
99 Ji
Approved By.
                                                         Cand.  fly
                                       Data Co«p. 
-------
         HE FOfflT" M COIHROI DIST2ICT - CCTUTt OlT JS  I11GSE2S
Test Mo. C-393                                          Page 5
                                                        Jxily 23, 1957
                   Particle Size Analyses of Samples
                           Sediaseataticn Method)
0-lOp*
                                                        Outlet
Wt. gns.
0.3286
1*7977
0.21*16
0.1593
2.5272
Ws. %
13.0
71.1
9-6
6.3
100.0
Wt » gins »
0.3535
- •
-
0.0029
c.3561t
¥t. a^
99.3
-
-
0.7
100.0
                  (THESE DATA USED  IN TABLE 3-4)
                                A-12

-------
SIEVE ANALYSES  OP AGGREGATE
Percent of Sample by Weight
SIEVE
SIZE
+ 10
Mesh
- 10
+100
Hash
-100
+200
Me ah
-200
l-bsh
TOTAL
CONVENOR
No. 1
12sl5 PH
80 Ji

16.H



1.6
1.6

100.0
No. 2
12$3lj PM
60.3

33.3



3.5
2.9

100.0
Ho»J
IslS PM
83.6

12.9



1,6
1.9

100.0
Mof l^
2s05 PM
72 .a

22.5



2,lj
2.3

100.0
HOT BINS
No. 1
12s30 PM
22.7

66.2



6.0
5.1

100.0
No, 1
IsOO PM
10.9

70.0



8,0
11.1

100.0
No, 2
12i30 PM
95.5

U.1



0.1
0.3

100.0
No. 2
ItOO PM
93,7

5.8



0.2
0.3

300.0
*?°t ?
12 1 30 PM
98 .I|

1.0



0.2
o.h

100.0
No« ?
s
liOO PM
98.0

1.2



0.1
0.7

100.0
Ho. k
12i30 PM
99.7

0,1



0,0
0.2

100,0
No, 1^
liOO PM
99.5

0.2



0.1
0.2

100.0
                                                                                   o

                                                                                   B
                                                                                   o
                                                                                   i
                                                                                    IE.

                                                                                    fa
                                                                             M
                                                                             ui

-------
                A!8 POWhiON CONTROL DISTRICT - LOS ANCEIES COUNTY

                                                                 Page 7

                           Statement of Proea*»  Weight

                                     GOPr                 .My 23', 1957

Firm w«—>  Griffith Comacy _
         -
                                                                       2t08 PH
^A ----    1601 H.
Tina of' complete-operating cycle- in m-t™rt:»a— ._ . _l]	60 3BJn»_
(see 2 J. Rules & Regulations)
Raw material charged during
tills- time          -  •          Material	It. is. lbs.
          id                   MatMrtal                Wt-ia


                                                       W1-. 1-n Thm.
          do                   Material _ It. in Ibs,

Solid fuel charged in pounds   Material              •**- in Ibs.


Total pounds
F.W.* Tqtal potinda y 6Qa           t  SO 9 Iba.
        Total minutes
   -P.W. for- lat-.prftoeding cycle  UTm3^
   P.W. for 2nd preceding cycle    g
   P.W. for 3rd preceding cycle    *:
                                      J. ^
                    RULES AND REGULATIONS OF
                THE AXB POlfflTlCIN CONTSQL DISIHICT

     HEG01AT10H I.  GENERAL SSOVISIONS    RJILS 2. DEF]2HTIONS

  j. Procewi weight per hour.  "Process weight" is the total weight
of all materials,  including aolid fuels,  introduced into any apec-
ifio process, which process may cause any discharge into the atmos-
phere.  The "process weight per hour* will be derived by diriding
the total process  weight by the number of hours in one complete
operation from  the beginning of any given process to the completion
thereof, excluding any time during which the equipment" is idle.

                                     A-14
 74J4070S3

-------
                       ^.
             AIH POLLUTION^.  JNTBQL  DISTHICT  -  COUNTY (   LOS ANGELES
                                                        (L
   MO.
                                                                             23, 1351
                     SUMMARY  OF  CALCULATIONS
AME OF  f i R M    Griffith GoEpany
ESC
1.
2.
3.
S.
6.
7.
10.
II.
12,
3.
•filPTiON OF FO,J1PMFNT TF^TFH ^ater scrobbing tower serving the
*i3n v* a
Phase of Process Cycle Covered by Test,- 	 ..— ..

Sampling Station 1 fir at i on

Av». Gas Vel. at Sampling Station (Ft/Sec),
FUi* Gas Vn'M"ie (SCFM) ....

Sampling RateT at Mater (CFM)
E lapsed Time- of Test (Minutes)
Mfttsr Vacuum - Average ("Hg) 	 .__ 	 	 	 __
Meter T*?™p»r»tyre - Average (OF) 	
Volume of Gas Sampled, Meter Conditions (CF)
Water Vapor Condensate (ce), 	 ,r-
Water Vapor Volume, Meter Conditions (CF)
Total Sampled Voiumfl, Meter Conditions (CF)
flnrrerted Sample Volume - (S(!P)., 	 	
Material Collerterf
Weight (3m. ) a. Wfaataaa thi-ribls
|j Water residtte
c. 	 ., 	
Total Weight (gm. )

Concentration grains/SCF S 12$ C(>2 	
Calculated Loss (Lbs. per hour) „



Inlst


20900
8 inn
0.96
US
7.6
88
15 -Wt
30
2.0
17 Ji
12.3
Partictilate
0.059
IS .8879

1S.5U7
23^

Ii260
bot asphalt



Otifclst


19500
15 If.ldi
0.50
53
2.2
79
26J4S
35
1*8
28.3
25.3
Matter
0.006
0.2576

0»261i
0.161

26.9
                             COLLECTOR  EFFICIENCY
                               (If Collector Installed)
16.
17.
18.
15,
Total material  to collector (Ibs.  per hour).
Total loss to atmosphere (Lbs. per hour)	
Tota! material  collected (Lbs. per hour)	
Percent efficiency_	,	
                                                           U260
                                                           If2?.!.
                                                             29_Ji.
                                         A-15
                                           TEST  CONO.  BY   HEc - RT -X-15.

-------
         AH "f VOIIOK CONTROL DISTRICT - COOR-lf' TF IDS AHSSIES
             SbufS SAX FSDEO SSaEEf - LOS MGEDaa 13, CUZFQRMIA
                                 TSST

                             CQHDUC7SD IT

                     GC2-3Pilir HOT jKjpHATfl1 PATUB BS3JCH HAHf

                        1380 BA3Z iSSCi EIGBW2J
                                  cn

                                    7,  1558
                 DOST ICSS,. F1KTICIE SIZE DISfRISOEOS

                AHD GCEI2CTICM EFFTDUSCT GF

               - .cc«samKc--3icssiffi!s OF

                    EOS ISPESIff PATHS 1SICH
                                  BT

R* M» EQBIEf                            ISTEBlEDIJeffiE AXE FCEUJTIGN SIGUEES

H» tC» I3IKMRB                           AIR POECDTIQI i
                                      HSPCRT MO.
                     ISSUED	a
                                 A-16

-------


                                        (
                                                        ,

             5EE2IC BLICSiH C?
              AiS  PlTSsG BSHH Hil-S
                                              Wash Hs±ss» ta
                        Statics f fx>-/
-•*  j(  y/"--\,--i*^>A>* »^»^^.Vi^^t'>^/«^-wv»7\;-"^r*'
   "  *~
                                                               /

                                                            f}
                                                     ,,         — ™_      —•»••
                                                    /    ! ^ j ,. » t -*•-"" *~ Sta;
                                                                x
                                                                        •jj.-*
                                                                        ^^«»^>
                                                                    St-aca
                                                                    :Cc? So,,
                                                                    lasd 2
                                                                    H js. H=s
                        A-17

-------
                A1RV. .illfflON CONT7JOL DISTRICT - LOS A;(  ,LES  COUNTY
                           Statement of Proeoss Weight    Page 7

                                      (CQEI)      Date   Febrmsy 7, 1958

Firm Mama  Griffith. Co,	      Time  Cycle
                                                 Started	
Address' •   1380 tew %f.	
Time of complete operating cycle la
 (see 2 j. Rules & Regulations}

Raw material charged during
this time                      Material __i_MS _ Wt. in Ibs,
          do                   Material
          do'            '       Material __2_££	Wt.in Ibs. __JlIi£.

          do                   Material    ^   	It, in Ibs.
Solid fuel charged in pounds   Material _     _ Wt.ia Ibs.
                                                                      280
Total pounds                             .                            ggCO Ibs.
      T^tal jptmdajtJ^Qa _ j_^Q, a Iba./hr.   182 TEH
        Total minutes
   P.W. "for 1st' preceding~cycle
   P.W- for 2nd. preceding cycle
   ?.W. for 3rd preceding cycle
                                            Plant Foresaa.
                    ROTES AND HEC30LAHONS  OF
                THE AIS POUimON CONTSOL  DISTRICT

     HEGOLAHOT I.  GENERAL PROVISIONS    RULE 2.  DEFINITIONS

  j. Process weight per hour,   "Process weight" is the  total weight
of all materials,  including solid fuels, introduced into any spec-
ific process, which process may cause  any  discharge into the atmos-
phere.  The "process weight per hour"  will be derived by dividing
the total process  weight by the number of  hours in one  complete
operation from the beginning of any  given  process  to the completion
thereof, excluding any time during which the equipment  is idle,


                                       A-18
 76 S 407 C 3-52

-------
AIR POLl£ ION CONTROL DISTHICT - Caf T OF LOS ANGELES




              SUMMARY  SHEET
"IIM of Ft rm GriUTfitli CoEtosrjT"
i^atr^r, ^ QHnt l?flO B. Arrow Higtafay, Irmadale, Calif.
T-=* N« C-ii26
n=* a Febrttarr 7» 195-3
fniiaf +!,?,, equipment Ye« I N« Typ* Cyclone and water scrabber
5p^»-ifj*. pq,, | pmo «* Tasted Oyclsne and water s crabber

Total Process Weight , ., J P.W. /hr. 	 ,
Cyclone ¥eafc
T!m» of Test Beqfn . . 	 12sC5 1:33_
End 2sO? 2:07
^^SSJIHQ^^^LjJCP*
s£ji2uiipujEi!sff ^'Tjfiisi fflrf y^ _ ot? *s/i
Sa« Vnlym, 5CPU. f^t^n^afH C^n«1 f t f 1M > IJ^OOO, 	 2800
Material Col 1 acted ,. 	 Dost
^M M J3^ O
'rntfn^/SCF 3i.fc yj-.o
G«»|i1.f/5r,P ^* 12* CO,,.,.. 	 .,. 	
Losfl p^r hou1" i« pflMnd*? 6,700 2000

Percent Moisture In Gases 17 »6 —
Orsat Analysts (Dry Basis) 	 „ . ..'

Q2 .., 	
r-n
N2< By d I f f . )
Stack Gas feaperatirra, °F (Jar.) 200 21$
Stack Gas Telocity, ft/sec. (Av») ii9»7 70.2
Collection Efficiency: Cyclone - 91%
Sibber- 99% Tfs< c<
A-19
Aoorot1*^ Pv - - - - - -- , 	 	 Dttl? Camp, and Ch*t


36IuQOO
Scarabbeir Stack
Inlet Cutlet
12:05 12:C5
1:20 1:20
60 60
28,000 22,000

10.9 0.135

2*620-. 25.5
bo
16.6 10.5





1U7 119
143.2 lli.3
,«^_ fly
•had fiy ERG - EL

-------
         UR POpHTZCH CORBQL DISTRICT - COOMIT/T? LOS JMGSLBS
Teat Ho.  C-U26
Page 9
Pebrnary 7»  1953
                       Particle Size Distribution,
Weight %
£es3 ttaii
10 rcmgh
(1651 micrana)
u£t ^BiBtSuOLf
I ^W** IHfl Jf*Tp'WM:W. I
100 mesh
• I it 7 f||^ /»«j^|«|«p|«^| i
200 mesh,

SDnrtcmiti
. -t,.--.,
30. nicreas
20 microns
13 nicrcns
5"^
1^ micrtffls
,3 Illiilt: OnZ"^'^'"^ ?
2 ICiCffOHS
1 micron
SAHPIS STATTOW-
Drier Feed
29.2
9.4
2.8






Bin HP. 1 '
92.7
31.8
8.4






Bia Ho. 2
6.3
0.6
0.5
0.5






Cyclone
Inlet
200.0
98.0
83.0
57.8
56.6
53.5
itf-7
1(0.8
32.1
27.8
21.1
10 .1
7.2
U.3
1.5
0
Cyclone
Outlet
200.0
98.5
81*0
54.0
51.1
liU-6
33.8
25.4
17-8
14.3
10.3
5.4
U.4
3.0
1.3
0
Teat
Line
200.0
98.9
95.7
89.2
88.0
85.8
81.6
TluO
60.7
52.7
39.7
19*3
14.3
8.5
3.0
0
                       (THESE DATA  USED IN TABLE 3-5)

                                   A-20
                                                                  ED3 - EL

-------


                                                                                 ,
@
                                             «w*TfT»*
                                             SHA .\Utiii2.
           301
           20,.
           101
               -»«J
                                 22..G
                        2*9 2a9
                                      6.T,
                                    8.7
                                                                                    Sysisze
           30{
  fe
  «3j
   I
20}


«1
                                                        10.5
                                                                  J3?i
           30-
           204
              5-0

                                               A-21

-------
            AIR POLLlf  ON CONTROL DISTRICT  - COU^ -' OF LOS ANGELES
TEST »»     -                                                 JMC£___.OF _ PA-



                                                               February 7. 19
                   SUMMARY  OF  CALCULATIONS
NAME
DESC
1.
2.
3.
1.
6.
7.
,*•»
**
—•«/
10.
11.
12.
1.5.
16.
17.
18.
19.
r np PIBM , Griff Itli Connanr _
•flfPTiQN op pQy | PMFNT TF.STEO- J2Pffi,,,ll!,t^




aaohaltle concrate batch, plant
CoH fired) tdlth 12* dia, cyclone and triple-tiibe centrifugal wet scicbber.
Phase of Process Cycle Covered by Test-


-------
 APPENDIX B
REFERENCE 3
    B-l

-------
                                                          J»lf,
                         Used by  permission of  Staub-Reinhalt,  Luft.

(IDC S2S.5U.h» tiyg^fff^tiaifl knowledge in so gxzfisiive
and complex a sphere.  .Maay individual experiences ire
contradictory and tome concluiioaa do not apply to
tioas elsewhere.   Finally,  (iie possibilities and limits o! dust
removal are nee assessed correctly, even today.
 1,300.  A representative cross section through all these plants
 according to statistical principles was sot possible for various
 reasons.  Consequently,  die glafits to be investigated wete
 selected by locality,  raw material, size and differing levels of
 equipment, to that the measurements wen sure to provide an
 extensive view of practical working conditions.  Maximum
 drum load was agreed upon witjj {be operators for the purpose
 of this  investigation,  and test days wets adapted to include
 whatever were regarded  as the most Interesting mixtures.
Investigating the waste gases of drying drams

   In 1S63,  the two Trade Associations of operators of such
equipment (the "Sundetfachabteilung Scrassenaau" In the
"Hiiiptverbaad der deutschen Sauindustrle,* and the "Sundes-
jrbeitsgemeinicSaft der Vereintguag der Tew- and Asphalt-
makadam herstetlenden Fumea'1 initiated research to resolve
these basic problems.  The project was offered to the "Haupt-
abteiluag  ivirme- nod Ktaftwicnchai't des Ttl v SJieinlind,'
This large-icale protect was intended to ex am inc. unprejudiced
by, and independent of,  all hitherto known data, ihe expected
dust content in the drum vaste gases, their dependence on
starting material and the manufactured mixture, the specific   •
properties of these dim? and, finally', dust removal, as prac-
ticed id Tar. - The problem of dram utilization, the resulting
waste-gas quantities and conditions, etc., were included.
The measurements were carried out in 1964 according to a
standardized program.  In  1963, the results were used to pre-
pare the draft for VDI Directive 2233 -Emission limits,  pre-
paration and mixing plants for bituminous road building ma-
terials."  The final version will appear this year.
   The number  of such preparation plants operated in West
Germany by these associations is estimated at some 1.700 to
 Test results

    Tie results of these first systematicaUy planned and  •
 Implemented series investigation,  a total of 35 individual
 studies it 10 plants, are  represented.in Tables 1 to 3,  They
-provide a clear  view of the dusts leaving the drums with the-
 waste gases, being subsequently almost completely retained
 in the dust collectors of the first and second itage, a small
 residue being flaiily emitted into the free air.
    These series  investigations having been completed, it was
 of Interest to compare their results with data obtained tram
.numerous other  studies in similar plants. They ire values
 obtained at many places in emission measurements performed
 at the behest of the authorities.  Table 4 shows the results of
 83 such studies in 27 plants.  These measurements were made
 available to the authoc by various institutes..  The many
 blank fields in  this  table  (Table 4) which was cam piled
 according to the same scheme as Table 3. emphasize the
 incompleteness  c;' our knowledge,  a situation which is quite
 inevitable when evaluation is based on conventional emission
 data which,  though numerous, carry too little information.
 The series investigation has the further advantage of noting the
 occasionally high dust content in the raw gas.
                                                          9
                                                        B-2

-------
 TA8L£t.  Drum sizes of  the  plants and existing lust collectors

Cornec.
Mo.

1-3
S
1
8

10
11
14
13
14
ia
18
IT
18
19
20
21
22
23
24
25
26
27
23
23..
30"
31
32
33—33
riant
No.
and test
No.
A1-A3
32
3
1
Cl
2
01
4
2
3
13
1
2
Fl
3
2
4
G2
I
HI
2
3
4
11
2
3
4
K4
K1-K3

Mixture tnaao/actund

Fine asph. concr, 0/3
Fine asph, coser. 0/3
* * * *
Base 0/30

Fine asph. coocr. 0/8
Fine Asph, concr. 0/3
• « • -
Base 0/33
* *
Binder 0/12
Sase 0/23
* »
Fine asph. concr. 0/8
Base 0/33
* *
Fine asph. concr. 0/8
Binder 0/12
Fine asph. concr, 0/8
Base 0/2S
•• * * m
Fine asph. concr. 0/8
Siader 0/18
* *
Fine atph. concr. 0/S
Bass 0/33
Drum dimensions
Dlam.
(at)
1.S

1.8


2.0

1.23


2.0 .


w

2,0

1.8


«

2.1
Length
(m» -
S

%


8

8


8


IS

13

9


f

6.1
Raced
(*/ hr>
30/40

go/so


80/80

80/80


80/80


73/100

90/120

37,3/30


43/60

103/130
Dust collector
1st stage

4 cyclones. 7000
21 cyclones, 41 0«

*12 cyclones. 600 «

8 cyclones. 1,320 «

2 cyclones, 1420 *


Surface cooler


8 cyclones, l.QQOd

4 cyclones, 1. 190 «

18 cyclones


20 cyclones

8 cyclones; 990 $
2nd stage

Wet scrubber
None



Wet scrubber

Wet scrubber


Fabric filter


Wet scrubber

Wet scrubber

Wet scrubber


Wet scrubber

w« scrubber
Dust generation in die drams

   Wbett enumerating the factors which if feet 4uu contest in
tie wute gases of the drum, the sequence U quite immaterial.
for all practical purposes,  these factors act simultaneously and
U Is not immediately clear which are the more important
ones, it is, however, certain cnat content increase* wieh the
quantity of finely granulated raw material entering the drum.
TMs quantity Is determined by  its percentage in the starting
material and In the mixture turned out, as well as by the ex-
tent of production. Furthermore, the type of rocks which
crack vSea heated, ire easily ground down by the motion of
Che drum tad tend to farm a great deal of dust.  Finally,  the
excess air wits which drums are operated plays a role.  The
quantity of waste gas is not only dependent on the material
load of the drum, but also cm die CDj content the equipment
tus bees id ins ted to.
   There is na uniformity is the terminology concerning rocks
and their granulations, raw material and the finished product.
The operators refer to the finished product as hates, binder.
and fine concrete, respectively,  ta the 'Technical Specifica-
tions and Directives for the Construction of Sicuminous Road
Covers,"  the so-called TV bit 3/64'  Issued by the federal
Miaistiy ol Transport. Road Building Division, the following
ire distinguished:
                                                          10

                                                          B-3

-------
Uft
                                               m.1 SvHf, tMf
TABLES.  The granulation components of  rocks in the mixtaca manufactured during (he test
(balance up co 1001* U made up  by  filler  tad  binder)
'Uni

A


•


C


0




£



Typaaf racdt
A1.M
Meate eUeptogf, VMM
tBffHKIlliy*
SUMMWi
A 1.3
Slut fura»c« iUg chtppurgi. wasted
« * « * •
ttiMMBd.
91,$
SUM tea. il*g chlppiap. aswiibwl
* * * scvK8flift£ii
(thiivmoil
U,
Gnvtt
C1.J
Batatt. awaited
* •
Mama*. MdHtd

01.4
fault cfiippwgi, «ul»4
" Krttaings * U*aimnl
nii«
0X4
BauU chippingi
... * «
# «
* icrtenu ji * 12% oa. >aa4
«J
iualc chippiajj. iun a9*
2/9 » 28*
0.09/3 - 38*
0/0.09 * t*
8«« 0/33
12/33" 43*

0.09/1 * Ji*
8Un!*t 0/12
1/12 • 20*
3/6 « 17*
J/8 • ig*
0.09/2 • 27*
* - 10*
UwO/U
• 12/29 - 31*
8/13 • iy%
J/i - Jt*
9/2 »13*
a/a
Plaai
f






H




-t



K


Typ« o/ rod
Fi.8
Umcuon* thippiogi
* *
ri,*
Kline gr»v«i
Gl
Unotoiw cMppiafi. vul»ti
* • «
* lct««aiiigi,i»nwi»h«J
°i
DUb«M etU^ioji, wu&Ml
UmcKOM * *
* (cmoiagi. unvuiied
m.a
Siult ettlpshnjj. wute4 '
UIBOUM KnttUnp. v«ilM4
Nctwal land
H 3.4
Li23€f£OQtt dlippiQSS
* *
Odemtrnd
U.S
fault cWppio^i. wutwd
Umcscnom iciMaiagi. wu&«d

£3.*
Limcitona cMppingj, wuheU
» * »
RUM land
K 4
Umtaaas chippin^i
* *
Uraenaew lemniogi
K 1.2,3.
LUncauuia ttreenln^i
C'lauticum component
Fln« uptutt coocr. 0/8
5/8 * 30* •
«/S%30*
0/3 * 39*
8«MO/33
5/i»l»
FlM UpiUlt COBQ. 0/8
3 /a * 43*
l/S« -
9/3*48*
SlodCfO/U '
a/12 * is*
3/8 « 11*
2/3 « U*
0/3 .40*

J/8 iTT*
J/8 «2i*
0/2 » «Kb
0/t»J3*
SaMO/23
ia/25«30*
S/I2 % 20*
3/8 *20*
0/3 130*
nac uphali concr. 0/8
$/a > zs*
2/5 *ZO*
0/2 • 24*

Binder Q/ 18
12/18 *30*
«/12 * 20*
Z/S*1S*
0/3 >30*
ftam uptuU coocf. 0/8
a/8 « is*
2/3 *23* •
0/7 »H3*
S4MO/3&
19/^ft * -*-^g-
1/12 • as*
3/8 * 8%
fl.03/2 • 18*
                                             11
                                           B-4

-------
            TABLES.  Reiuln of ictlei  la veulg«i lont  35  uudlei at  10 pliou with iiaadardlzed meaiuriag program,  identical
            Innrumcnu anil pciionncl.  Plant  and raw  material according to Tablet  1  and 8.
w
    M
o
J5
u
1
1
1
4
1
1
1
I
14
II
11
11
14
II
II
It
II
II
10
11
11
11
14
11
11
»
M
10
11
11
14
N
0
36
§
ta
9
0
1
a!
At
„ j
i
i
•i
i
1,

„ t\
I

Dl
i
}
I
11
1
1
ri
i

1
HI
1

HI
4
Jl
i
1
4
,t
1
1
fr-
1
U
£
I
11
w
10
M
14
'f

W
W

M
u

to
to
M
M
10
la
10
TO
•o
ft-

11
11
	 41 	
41
40
10
40
1%
111
114
111
Upui. of the dull collector
O >-<
•u
iii
144
111
Hi
J»t
,.111




Ml
iii

-Jl.*
11*1
i >6M
1011
' 111
If 1.
Ill
I'1
III

_Jf 11,
till
till
—It-It—
ilif
J01
}H
in
»»•!
Dull c
I/m"
14.1
14.0
164
111
HI -

411
\\\

no
111- -
—111—
ttl
tsi
Ml
lit
' Hi

lit
111
111

lit
101
111
144
Jii~_
PI
III
114
111
111
III
onient
gAn'STP
lit
14.1
21.1
11.1
lilt
111!
--HI




Pi
f llf
in „
»i
Ml
111
114
III
II (L
411
ma
|6|-1

114
lit
iii
in
lit
Ml
111
III
, 111,1
111!
1(0.1
1161
Duit collector In itige (dry)
dowaiirei m of the collector
b
11
ill
114
ill
Mi
in
Hi

_4li_
IM



'1
11
—'lOO
IM
ua
"4
114 '
Iii .
m ,,

ii
i?
11
w
M
M
|l
II
	 1J1__
111
111
»•
d
112
ill
116 •
Hi
141
144

44]
ill

!H
ill

• 411
Cooler!
luit- lad
>UC. lit
in
Hfl.

ill
ill
. m 	

11.1
_UJ_
in
114
11 (
111 	
114
fit
41.1
411
411
Duit c
8/IH*
eiti
Olll
1.011
i.it
i >i
ODI

111
3.11

111
t| 1
4M
1.11
410
410
14.4
-
an
241
10. 1
il

in
111
IM
Oil
	 SJi_
ill •
l.il
TCP
ill
414
441
onient
g^i^STI
IM4
1114
1411
Mil
2.11
111
1.411
400
411
411
111
1.11
161
MO
101
411
111
114
111
lit
lit
441
111
1 U
1011
IM
1M
411
l.tl
111
Hi
Efficiency «, %
MS
110
114
US
111
11.4
IU
11,1
111
111
DO
»•
111
U.I
Ml
II.I
Ml
111
M4
•1.4
111
114
M4
11.1
Ml
111
Ml
Ml
. 144
Ml
Collector 2nd itaga (wet)
dowmu.of the collector
Waste-gat quan-
tity, l&m*fls
in
in
HI
ut
in
DuttC
g/BI1
tIM
lilt
6111
Olll
Olll
ooteni
«.iii
t!4l
• IM
1.041
Efficiency , , % '
41.*
411
111
414
IIS
noaeBtiilfig
in
IM
414
411
41.1
410
411 '
411
411
ill
in
in
111
114
111
101
100
Ml
111
ll.t
ill
110
141
41.1
111
41.1
11.1
Olll
a in
Olll
tut
A 101
Olll
6 Ml
tan
6611
am
6114
am
Olll
Oil]
114
OHO
0114
0411
0111
0114
01 JO
am
ana
6011
0011
a DM
atM
am
•.in
6161
Olll
6011
Oil!
0.1 M
0*44
• 101
t.ll
I.M
•114
ftlll
OMI
0110
0114
• HI
OMI
ftlll
OOJJ
owo
ftIM
0611
111
112
Ml
Ml
HI
til
Ml
III
111
Ml
440
111
114
III
M.I
Ml
MO
•1.1
III
110
111
IM
114
Ml
Ml
116

j
1
K
•1.1
in
Ml
til
111
•1*
114
111
Ml
Ml
114
114
lit
lie

Ml
Ml
Ml
114
Ml
111
Ml
111
•11
11.1
110
lit
Ml
III
M.I
Ml
Ml
Ml
Upmeam of the iticl
i
s,
1
101
101
101
161
161
141
III
111
II
M
4t
11
41
41
11
II
II
11
It
11
U
It
M
M
M
41
11
14
11
41
41
fl
11
II
fc*
§
ff
-
11
II
11
10
11
10
1.0
10
I.I
M
01
I.I
11
21
1.1
11
41
41
4.4
11
11
11
1*
11
11
1.1
14
II
11
1.)
101
101
Waite-gM quan-
tity. 10* re* STJVte
14
11
ii
ii
14
11-1
111
212
111
II.I
HI
111
116
110
311
111
141
111
111
111
11.1
lit
141
III
111
III
HI
III
261
•144
211
111
»4
                                                                                                                           a
                                                                                                                           f
                                 (These Data Used  in Tables 3-6  and 3-7)

-------
                                                                      y, Ulf
1.  asphalt binder
2.  coarse upoaltie concrete
3.  flue atfhaltie concrete,  low chipping* content (20—35*
    chipping!)   '
4.  fine asphaltie concrete,  high chipping! content (35 —«S*
    cMppiags)
5.  sand asphalt.
   The following raw materials am processed!
S and;      i. s,, mineral substances which pan die 2 mm-
             mesh screes and an retained by the 0,09 nun
             screest*
Chippings: Le..  crushed rock,  sizes 2— 29mm.
Fillet:      Le..  mineral substances which pan die 0.09 mm
              mesh screen*
   IB these investigations the fine concrete had a particle
smeaire of 0/8 mm,  the binder 0/12  — 0/13 mm,  anil the
bates 0/2S—0/3Smm.  Toes* moat will be retained below.
Effect of me processed rock and la granulation

   The fine particle component of (tie rock mixture to be dried.
as id jutted far the prescribed particle structure of a gives mix-
ture,  can be taken from die data of Table 2.   If these values
are correlated with toe dim-content figures la Table 3, U Is
jeen that tee resulting Table 3 shows only a minor increase  af
dust content with rising fine panicle component.  This becomes
understandable,  when noting that the raw material as
mentioned  Ln Table S ii washed.
   The range of fine particles with a lower limit at zero cannot
be assessed with certainty,  since neither the proportion of the
near-ten particles, nor their actual proximity to tero are
known. However, if we separate the so-called filler,  i. e..
the proportion between zero and 0.09 mm from the fiae range
0 — 2 ram (achieved by washing the land), the granulation  of
the residue can once again be clearly defined.  Measurements
show  that this granulation doesjiot apparently have a greater
thare in dost formation than other coarser paniculate*.  It   '  ' ~
makes no difference whether the material-mixture rua through
the dram is for the base,  the binder, or the fine asphaitie
concrete; dait content remains approximately equal if only
washed material is used.
•   As can be seen from further evaluations, die assumed in-
fluence of rock type and of the granulations processed are of
secondary importance,  compared to the question as to whether
the raw material Is free of the smallest particles of the filler
size,  through having beea fed either after washing, or else with-
out addition of filler, whether the latter procedure cormltutes a
genuine alternative to washing remains to be proved.  Toe
measured values for du« content ia drum waste gases,  which
in Table  3 itiil appear as a eon/using jumble,  assume a clearly
discernible order when separated according to whether washed
or unwashed raw material wax used (Table i).  The first
column corresponds to the data from Table S.  in the third
column,  which represents unwashed material,  a remarkable
difference appears.  The dust contents are all much higher and
increase in ascending order, i.e., from "base* via "binder"
to 'fine concrete,"   Compared to these values, the dust con-
tent for washed material is almost insignificant.  High dust-
content values are therefore apparently associated with ihe we
of unwashed raw material.  A horizontal comparison of values
ia Table 8, with two measured values for half-washed material
la the fine-concrete column U very interesting.  The trend
toward dust Increase with rising fines is clearly recognizable.
   if the high dust content of unwashed raw material is due to
the finest, pulverulent particles,  an identical or at least
similar situation should logically  occur, whea a certain quan-
tity of filler is added to washed raw material.  This was in-
vestigated In the test series 01 and 04.  The raw material of
the high chippings content fine concrete had die following
composition:
1.  basalt chipping*, washed
2.  basalt chippings. washed
3.  basalt chippings * IS* natural
    sand, unwished
    natural sand,  unwashed
    filler
  ' In test Dl.  the last two materials, jointly constituting 2S*.
were only added to the mixture downstream of the drum,   in
test 04 they were present  In the mixture from the beginning.
If, for die sake of simplicity, we term them finest components,
the following can be stated; dust  content of drum waste gases
when manufacturing fine concrete with partially washed raw
material was
       . without finest component      33.4g/nrlSTP,
        with finest component        US .3 g/m5 STP.
   la fact, this relation attains the same order of magnitude
as that rewittag for washed aad unwashed starting material.
If the filler is added to the dram, the dust content of the drum
waste gases cart thus be compared with that arising  for un-
washed naiting material.
   Measured values related to the type of rock used appear in
Table ?.  The following materials were used for the compari-
son}"          .    '           -            	
4.
5.
                                        3/8 ram
                                        2/S mm
  0,8/2 mm  :  20*
0.09/O.Smm ;  IS*
 0/0.09 mm  :   1*
                          a   'it    a
                        Mix manufacture
Figure 1.  Waste-gas quantity of the drying drums as a function
of rout production
                                                          13
                                                      B-6

-------
          TABU 4. Results  of cmliiion measuiemeniii 83 itudiei In 2? ioitalliiloni, carried out at ibe bebcti of ilic tuperviiory
          autliaililei by  various iniiUuict with  dtffeiing meaiurlng Iniirimicoii
OS

-4
o*
i*
36
38
39
40
41
42
43
44
45
46
~47
48
49
60
61
62
63
64
Ts
66
67
66
69
60
"it
62
61
64
65
£6
67
0
3
i
o
a
m
Kit
2
KM!
2
KN1
2
KOI
2
KM
2
KQ1
Kflt
2
KS1
2
KI1
2
KU1
2
KV1
2
KWI
2
KXt
2
KYI
2
3
4
KWL1
2
KWMt
2
Mixture
manufac tmed
Bate 0/35 gravel
p n M
Bate 0/35 gravel
Date Q/a$ baialt
*t m o
Base 0/35 gravel
W » M
Base 0/25
Fine aipli. carter , 0/B
Has* 0/3S gravel
date 0/35 gravel
Base 0/35 gravel
Oate 0/35 gravel
	 — 	 T-J 	 J- 	 * 	 	
Bad: 0/115 gravel
Fitifi ji|>li. cmicr. 0/H
Base 0/35 gravel
Qase 0/35 gravel
F. aipti. toner. 0/8 giv
UHC fl/;iA gruvul
Oiu«ki 0/25 gravel
Fiife aiph. concr, 0/d
• - (moraine)
Bate 0/35 gravel
**
*
fi
30
32
20
20
16
16
63
66
30(60%)
10(50%)
67
36
40
4S
46
46
60
43
41
10
66
34
34
80
90
28
30
30
30
40
40
60
60
Upstream of the
dud collector
Watte -gas quant iliy.
10*0]* SI? /te
10.4
110
103
0,7
20
2.2
167
166
261
246

122
12.1
140
141
12.6
134
11.9
119
12.2
11.9
MS
149
286
303
11.2
102
166
170

Di
con
m
e
DO

6.21
66S

207
196
235
12.8

4.49
8.97
144
too
1013
14.70






IS!
lent
06

6.78
264

37.9
3&1
28.2
16.7
293
12
9.6S
27.4
18.9
1493
21.46






| Temperature, C
• —


—


246


	

*
i
i
U









6.6
4.7





Dun callecicx lit stage
downiu.of ilw collector
j Temperature, C
140
136

299
250
229
220


170
172
246
238
170
163
200
191

as
92
184
170
83
110.
66
90

V
S.5
~f <~>
16.9
16.7
134
133
4.2
4,2
28.7
27.7
303
303

19.6
19,3
266
266
203
21.4
22.0
21.7
16.2
14.7
198
20.3
49.1
600
162
16.1
196
226

Uu
cant
t
1.35
1.22
0.933
0809
0.7S4
0.903
187
1,77
413
362

091
1.127
2.36
1.13
0.694
0.793

622
0.447




tl ,
eat
M
2.0S
1.84
1065
1 182
1.661
1.731
3.43
3.16
6.70
437
316
1.266
1JOS
447
2,11
0.676
1.168

0.278
0662





Efficiency , , $'

82.1
84.4

91,0
81.0
lij
72.4
890
824
81.1
83.7
86.7
841
84.1






Dust collector 2nd Mage
dowotu. of the collector
Waiie-gaj quantity.
IcPrnVto
136
14,2
D
can
0094
0.118
USI
tent
6
0.116
0.142
*
r
s
§
84.1
91.8
nonexliiing
Qoniixiiiiug
22.4
22.1
03«fl
0.234
0.462
0.307
none Kisiing
83.0
89.4

378 1 0.164| 0.243 1 91.8
Doncilsitng
nw.enis.iHg
IBS
19.6
166
164
0.281
0.440
0605
0686
0.416
0643
0.613
0096
627
44.6

.W.M:«iHi»,,5
16.3
386
388

16.4
16.4
21.6
21.6
O.OS7
0058
0194
0.199
0.262
0.131
0083
0.112
0.160
0,126
0.062
0.106
0070
0.072
0.2SB
0.268
0.314
0,161
0.101
0.132
0.210
0.180
0.076
0.128


	
1st aad 2nd uage. %



SB 7
890

99.1


86*






Upttieam of the
slack •
Wane-gas temperature.
C
61
69
77
87
2SS
260
B7
i4
63
60
86
170
172
246
236
129
124
74
66
6S
66
66
66
63
88
48
61
42
48
106
110
66
66
«,*
I
. §
u
U
4.2
3.8


6.6
6.1
O.B
1.2
2.1



6.1
4,4
06
O.4
1.9
2.2
43
4.8
20
3.6
2.6
2.6
68
6.9
38
3.6
1
11.1
11.7


169
16.8
26.1
24.6
266

14.0
141
126
134
12.3
12.4
~12~F
11.9
14.4
MB
29.1
29.1

11.0
11.0
179
179
                                                                                                                          	    i
                                                                                                                                  V
                                                                                                                                  I

-------
o
89
70
71
72
73
74
75
76
77
70
79
BO
at
62
63
B4
85
86
87
~ii
89
BO
at
92
S3
84
• 98
96
97
98
89
100
101
102
10)
104
IDS
106
107
108
109
110
lit
112
113
114
116
116
117
tie
HUH
2
HMM1
2
3
HMN1
1
HMOt
2
3
4
HNLI
2
3
4
6
6
7
a
HNMl
a
2
4
HNNt
2
3
Silt
2
3
4
&
6
SlMl
2
3
4
&
6
7
SlMl
2
3
4
6
fit
2
3
4
6
6
fine aiph. concr. 0/8
Binder 0/15
' o/ia
Mixture 0/8
Fine aiph. conci, 0/6
Fine aspE, concr, 0/2
Dindci D/2S
fine asph. concr. 0/8
MM M m
•* H Ml Ml
Hinder 0/15
•* H
Fine gravel 0/3
Binder O/ 18
fine, gravel 0/3
Bate 3/2S
«* «
Fine atph.concf. 0/B
« » « «
Base 0/2S
•» w
Fine asph.conct. 0/2
*•
Hinder 0/2 diabase
Fine aiph.conci. 0/8
diabase
Bate 0/3 i llnrniane
• <• •
K *• M
Base 0/35 gravel *
• « "
" 0/28 "
Fine atph, conci. 0/8
w * mm
Dindet 0/12
Date 0/3S
" 12/25
40
40
28
3S
as
61(60%)
120
42
40
43
44
47
63
72
48
48
78
65
£8
60
60
80
60
10
to
to
40.6
4l.ft
42.S
45
40
43
BS
92
73
93
107
94
88
76
75
76
68
88
66
65
66
60
80
65
13.1
11.8
8.1
8.1
8.8
635
103
20.7
200
200


III
11.8
118
110
IIS
118
176
17.6
17.1
18.8
183
18.3
18.2



24.4
27.7
187.0
163.0


86.6


Cold proc.
M
M





102.4
98.8
966
66.4
1020
1460
876
BBS
61 6
640
76.0
64.0
612




126
118
122
122
	
243
237
237
2S4
236
137
ia>
187
196
188
214
200
204







81
6.1
6.1
6.4
67
6.2
4.1
4.0
3.7
32
36
37
34
4.9
4.7
4.2
31
1,6



82
aa
112
102
tot
il
84
73





70
80
80
116
160
60
18.7
16.7
17.4
17.1
17.1
67.1
262
27.1
26.6
26.0
286
257
193
26.6






7.41
2.86
68
106
14.44
1.34
1.88
2.04
26.6
20.4
3.62
18.2
M3
18.6






1068
4.60
14.9
19.8
26.0
1.68



6.1
62
6.1
6.3
6.8
6.0
6.6
61
6.0
6.0




•3.7
80.4
•6.7
883


03.8
•2.9
834
810
94.1
94.3
91.0
832
80.7
91.7


aonexlulng
346
28.8
263
24.6
214
20.8
21.7
20.6
23.9
244
242
24.6
26.0
64
8.4
3.2



31.6
31.7
31.8
31.8
32.2
31.3
0.492
0.304
0.663
0.624
0.746
063
2.01
2.73
1.68
018
0207
0.616
0.204
0.279
0223
0.663



0.301
0.416
0296
05H
0376
0140
0.664
0413
0.914
0890
too 1

0.222
0269
0770
0260
0.330
0.260
0.910
20
2.8
2.3
1.7
26
3,4
0.3&S
0.3S9
0381
0353
0361
0.346
0.320
0.124
0137
0.096
0187
0.183
0.3&9
0.484
0.3S6
0.612
0.462
0.160
*y
pedal
80.7
60.7
A8.2
81.3


384
16.2
2S.O
39.8
12.8
13.0
838
83.1
04.2
83.7







96.1
94.3
26.0
94.6
84,8
950
996
99,6
994
99,4
996
996
996
990
99.2
788
988
99,1

117
168
3t8
239
220
70
49
84
101
tie
tio
31
33
33
29
• 63
89
67
7i
47
42
102
126
122
123
130
117
116
60
60
60
66
68
60
6fl
82
65
64
fil
60
62
60
62
62
66
40
1.6
40
7.2
4.2
3.4
1.6
6.8
3.8
6.0
6.4
4.6
llo 3
**
*«
**
*i
M
36
**
Ml
1 102
M




13.1
11.6
6.1
9.1
aa
63.6
29.4
t94
184
173
169
191
20.3
188
192
19.3
rse
162
203
19.0
19.4
19.6
196
4.6
4.6
2.3
24.6
24.6
24.6
23.7
24.7
24.8
21.8
218
216
209
20.8
20.8
208
193
20.7
20.7
21.6
21.6
266
26.8
266
266
26.9
27.2
                                                                                                                                                          a
                                                                                                                                                          f

-------
                                            %t Mf. IMT

TABLES. Effect  of th« particle components 0—2mm as dust content
Mixture manufactured
Classification (mm)
Particle sizes
< 2 mm taw material 05>)
Dust content
far washed raw material
(g/rfSTP)
Floe itphal
low chipp, COM.
(J/8
64 to S3
394
tic concrete
high cbipp. coat.
a/a
48 to 30
to 28.2
Binder
0/12 to 0/11
40 to 30
29,3 n 22.4
Base
0/25 to Q/3S
30 to 19
29.9 to 23.3
TABLES.  Measured dust content la the drum waits gas«s  for washed aad unwashed raw

Oust content
Measured values from —

fine asphaltic concrete
Binder

8as*



to

0/8
0/12
0/18
0/29
0/30
0/35
Washed
4
Mia.
28.2
—
22.4
—
—
23.3
l/nfST?}
Max.
39 J.
—
29.3
—
—
29.9
Half-washed
•(g/ra'STP)
Mia. Max.
69.3 69.9
— —
— , —
— —
_ • —
— —
Unwashed
(g/ar1 STPJ
Mia. Max.
117.0 W3.0
89.S 103.2
— —
72.4 93.7
53a T
43.1 52.0
TABLE 7.  Effect of rock type oa dust content

Flue Hfhaitic concrete 0/8
low caipplngj content
Fine atpoaltie concrete 0/8
low caippingj content
floe asphalric concrete 0/8
Ugb chippingj content
Ftoe upnaitlc concrete 0/8
high chipping! content
Pine asphaltic concrete 0/8
high chipping! content
Binder 0/13
Base 0/3S
Raw material, washed
Proportion
0— 2mm
*
•34
34
35
SZ
49
30
21
*
32
32
32
32
IS
20
29
23
24
24
30
21
Type of rock
(In proportion of dust content)
Moraine, icreeoiap
Bftii^n iand
Blast ftuoace slag, screenings
Raise sand
Moraine, screenings
Rhine land
LifnestQQC icreeaiafft
Natural sand
limestone, screening!
Blast furnace slag, screening!
Rhine land
Basalt, screenings, with V* natural
tand
Oust content
g/irr*STP
28 J to 28.S
23,3 to 31.7
3S.9
20.2 to 26.4
32.3 to 39 J.
22.4 to 29 J
233 to 29.9
                                        16
                                        B-9

-------
                                                          1M.ZI MB.T Mf. 1H7
   Basalt, blast furnace slag, llmeaone. motaiae, natural
find. limestone.
   To ettrntoate Interference by tecondary effect], washed ttw
material was once again used as a basa.  Despite wide!'/ differ-
ing proportloni of the fine-granulate range from 0 — 2 ram la
toe tfaitlfif  material, tile measured dust contests scarcely
deviate.  Tais means not only that.  In this respect, cite dif-
ferences between the rock types themselves ace snail, but aisa
that,  in the absolute T*HT*.  meir additional effect on dust
generation Is quite Insignificant,  Tills could also be ,
flflBattoa of tiie identical suitability of thes« rocte.
Tne material load of thi drain

   Toe dram dimensions of tin ten plants studied In the pro—
gnn ate known,  as Ls taelr 5*erforrnancc during meaiuremeot.  .
Ttie fEteil capacities In  Talite 1 are based oil  40(i
Figure 4.  Particle size distribution of dust la tee manufacture
of bases 0/30 — 0/35 mm
                                                           17
                                                     B-10

-------
                                                      loft VM.2T N*.;
                                                                      r. 1HT
The waste gu laid of the dnun

   It is alto Important to relate the measured quantities of
waste gases la the dram to (he quantity of material processed.
If gaa quantities are plotted *i. production, we obtain Figure l,
which ihowi a considerable scattering of measured values.  A
mean relation Is indicated by the two limiting lines, and may
by useful for rough calculations.  However, cite question re-
mains of whether a cause  for the considerable scattering can
be seen  from  the measured results.  The CO| content
which was also measured, and which could, conceivably ssrra
as a measure [of Che  material load/waste gas relation], was
found to differ, greatly.
   The drying process in the drams Is sustained by combustion,
Excess air Is calculated  from the measured CO, content and the
theoretical  km** value which, for the commonly used tight
reel ail EL, can be set as approximately 16*1. Upon calculation,
excess air It found shockingly high. However, It man be regarded
solelyui connection with the specific working process, namely
drying and heating of the material for subsequent bituminixaiion,
   Ere eg air simultaneously serves for cooling and for protec-
tion against as impermisiibly high heating of the material.
Nevertheless, In average installations,  excess air quantities
can sometimes reach ten times the values of somo very good
modem units,  of which one was also included is the tesr pro-
gram.
   If the waste-gas quantity it divided by the quantities of the
manufactured mix, the effect of the varying CO, cuuteiu is illus-
trated quite clearly (Figure 2%  The specific w«te-g»j quantities
were: in low-efficiency units (1% CO,), about 600 nr'STt'/th;
in average units (3% CO]), 900 —400 m: STP/th, and in the
best units (10% COj), about 200 of STP/th, Differences in
the quantity of waste gases are thus not only due to differing
production volumes,   but mainly to the mode of operation of
the drum.  This realization is significant for conclusions to be
drawn later.
   Figure 1 can be complemented by lines for which CQj con-
tent  ii  the parameter.  These then indicate the waste-gas
quantities for which,  in the individual case,  waste-gas ducts,
dust  collectors, suction fan and stack would have to be cal-
culated (Figure 3).
Panicle sizes of dusts

   The dust samples collected during measurement were sub-
sequently analyzed  for particle lize using Gonell classifiers.
In accordance with  VDC Directive 2031 'Fineness Determina-
tion of Technical Oust." the dusts were classified according to
their sealing  velocities  in steps from 0.2 to 33.Scm/see.
Specific weight (density or apparent density) was determined
by the pyknometric  method.  This permits conversion of the
settling velocity to  particle size by means of the aforemen-
tioned directive.
   The results of air classification  are given in Table 3.  Scat-
tering is great,  and  it is not easy to tell the significant from
                                          > 12 era/see
                         1   "S
                       Settling velocity
                            diameter for 7 »2.8g/cms > 40ji
          o
Figure S,  Particle- size distribution of dust in the manufacture
of binders 0/12—0/18 mm

the nonsignificant values.  The uncertainties am created by
the fact that the values of the dust samples at the dram outlet
must partly be formed from the perceatual summation of
separated dost and clean -3 as dust of the first collector stage.
As is known, tfag
                 aking of a pBBrgs
                                         average sample
ttatn a great aaantirv of separated dust Is difficult.
   Plotting the particle lines produces a confusing multitude of"
curves.  However, since these are residue curves (for defini-
tion see  VBI 2031}.  the extremely high curves can be neglected
as less Important for subsequent dost removal. The problem
is not how coarse, but how fine the dusc is.  The residue
corves for fine dast,  however, tie lower.
   As shown la Figures 4,  S,  and S, the particulates of the
other dusts are practically all in a range which,  for an apparent
density of 2,$g/cm*. can be given  approximately as follows;
Residue
                   > 10(1: 53 to 78%
                   > 20pt 33 to 63%
                   > 40fis 28 to $4%
Passage
                   > 10|i; 43 to 22%
                   > 200: S3 to 33%
                   > 40|i: 72 to 48%
   la case, of mese large intervals, usually quite adequate in
practice,  the numerical data apply  both to the dust  during the
manufacture of bases and binders, and to fine concrete. '
With the latter,  this  is not quite true for washed starting ma-
terial, the dusts from which contain less fine conponents, ts
is evident from figure S.
Dust removal

   The dust content of drum waste gases is occasionally so
great that the waste-gas flow is held to be comparable to
pneumatic dust conveying and dust removal  to separators used
with such conveyers.  Such comparisons do not apply to our
measured values, showing maximum dust  contents of
l60g/m*$TP.  Average dust emission of the drams for
                                                               B-ll

-------
                               >*   'V   > 12 on/iee
             (l      ,   Settling velocity	
           MV    *at irucie  diameter tor 7=2.6 g/eirr* > 4Qu
           a
 Figure i.  Particle tixe dUiriburioa a/ dust downstream of the
 dram in the manufacture of One? wphalttc concrete 0/8 mm
31 measurements at 10 instillations is 23 kf of dun per ton of
miMd material,  i. a,. 2.31k  The lowest value was  Q.9<% and
(he highest, 7.5%.
   While,  in the  past, planet wens exclusively equipped with
centrifugal collectors, modem plants ire provided almost only
with two-flag* dust removal,  Cyclonei serve as preseparators
In the first stage, the second stage being frequently a wet
scrubber,  fabric at bulk layer  filters  being also used increasingly,
ix axe sometimes special electrostatic precipitaton.
   Of the 10 units in the test program.  3 were equipped with
two-stage dry-wet collectors.  Toe number and dimensions at
available cyclones can be seen In Table 1.  One installation
had only a fabric Alter with preliminary surface coaler, and
one was only equipped with a  relatively large number of
medium-size cyclones.  The e/Ticieaciei meaiured at die pi an u
ace gives in Table 3, separately  for  each stage, and altogether
for the entire dust removal unit.  Re/erring to the 10 plants
investigated, the following can be concluded:

1,  Cyclonei  of  the  first stage
vol. IT tta.f Mr, Oil
3. loth stages together
No, of plants
1
1
Z
1
2
I
3 cyclones + wet scrubbers
1 fabric filter
' " 1 with cyclones only


Efficiency (°k)
(temporary)
99.9
> 99.5
> 9S.O
> 98.3
> 98.0
> 97 ,3
-> 99.3
> 97.0
No. of plants
4
2
3
1 (without cyclone)
2, Wet scrubbeti of the
No. of plants
1
2
1
2
1
t
2 (without wet scrubber)


Efficiency {<%)
(temporary)
> 99
> 90
> as
—
second stage
Efficiency (%
(temporary)
> 98
> 98
> 90
> as
» TO
> so
_
19
B-12
   As eaa be wen. dust removal la alt 10 plants was quite
satisfactory.  However, jt should be noted thai; jftq test pro-
gfann did aqt |peludei thejerv went a tana.  The differences
between very good and merely good dust removal become
oaly obvious and, la fact, tuikiag. when clean gas dust con-
tent after ifie second stage is examined (In Table 3).  An
efficiency for the entire installation of less than 991k oa longer
appears so exemplary. However,  this is already in anticipa-
tion of the recommendations of the recent Emission Directive
VOI 2213 for new piano reported elsewhere.
   Tn« reliability of cyclone collectors u generally recognized.
Although their efficiency has a natural limit when the particles
become coo small, it is quite sufficient for many practical
tasks.  Cyclones must have specific dimensions and be sub-
jected to (he correct load.   The manufacturers guarantee
graded efficiencies for their cyclones, often formulated as
follows  for known dttsts is known stausioass
Panicle sizes (jij
Iffieieaey
      Ota 10
     1Q to 20
     20 to 40
    above 40
     70
     n
     98
     99
                                                                   Apart from uncertainty for the lowest particle sizes,  the
                                                                validity of these data was repeatedly confirmed in'innumerable
                                                                acceptance tests.  If these data are assumed as given also in
                                                                this case — &e*high density of dust particles according to
                                                                VOI 2031 of in  average 2.Sg/cmJ favors such an assumption —
                                                                they can be used to establish evaluation factors to assess the
                                                                efficiency of these collectors.
                                                                   In T*Mf t[ the to|jil efficiencies.  a« aenially measured  at
                                                                the cyclones, are related ro the theoretically  aossijale bv
                                                                m^frqi of the particle analyses ia Table 8.  It is seen that in
                                                                11 of 17 analyzed investigations the calculated values were,
                                                                at times exceeded in practice.  Also, the effect of particle
                                                                size in the individual stages on the final result is clear.  The
                                                                average of the theoretically possible  total efficiency  is 91.2?*,
                                                                the lowest value is 36% and the highest. 97.7%.  Among mea-
                                                                sured values the average^!* 91.4f»:  (ha lowest. 11.3f« and the

-------
           TAULE8, Panicle inilyili of the duic lampiei In the ten program
Ob


Duit la the drum wane gaiet



1. For washed raw mateiial
In the manufacture of
1,1 Fine asphalltc
canciete 0/8
™**>i^*fc*fc **/ B


1.2 Binder 0/18
1.3 Bate 0/3S
2. For half-waihed raw
material in the manufac-
ture of
2,1 Fine aiphaltlc
concrete 0/8
3. Pot unwashed law material
In the manufacture of
3.1 Fine asphalltc
concrete 0/8



3,2 Binder 0/12
3,3 Bate 0/30
Base 0/35


0*
z
1
E


A4
Dl
H2
12
13
D2



Cl
C2


B3
D4
F3
G2
K4
Gl
Bl
F2
,

Raw material





Moraine «Rhlne sand
Wan feimee-ilAB « Shine i»ml
Basalt* natural sand
Baialt t lime « natural land
Basalt tlline + blast futnaceilag
Lime t Rhine sand
Basalt * natural sand



Basalt * moraine + Rhine land



Blast furnace slag •» Rhine sand
Basalt
Limestone
Limestone
Limestone
Diabase t lime
Gravel
Rhine gravel
1 I U
"1 1^
8 II I •-
0
u
§
I"

a-s.
CO


28.6
33.4
26,2
39.1
29.3
29.9



69.9
89.5


133.5
116.5
119.1
Ico, I
1 f

i* 1

11

M
i
2ir
1W
1C
A




1

B.Ol
fl.l 1
15.2 1
111.0 f 4,4 1
111. 2 II 3. 9 1
103,2 I S.I 1
i.
<* 21
s t>
S"e


330
630
410
S40
500
630



520
520


350
640
310
260
460
210
53,1 I 3.3 U 300
52,0 f 4.4 1 280


"B
u
to
*,
1
u
a


2.4
C.4
2.6
2.6
2.9
2.7
2.9



2.5
2.5


2.6
2.8
2.4
2.5
2.1
2.5
2.S
2.S

Raw gai dust in the drum waue gases
Panicle size dltitibutlon by settling velocity Intervals
Weight proportion In %, itttling velocities in cm/sec


<0.2


10.5
l-fft
7.0
8.7
io.a
13,7
15.1



8.9
1.8


4.2
15.9
11.0
8.3
1.5
5.9
3,8
16.5
<0.4


16.1
lit n
13.1
11.0
14.0
29.1
25,0



13.8
16.9


1.1
26.6
19.8
20.1
2.1
16.5
i.l
24.0

-------
                                                      loft Voi.2t NO.T July. MM
bigness, tt.4%.  Mean and maximum of the manured total
efficiency just about equal the mean and maximum of the
theoretically possible,
   Wet scrubbers as a second stage are widely used because of
their applicability also fas fine dusts la die clean gu of the
cycioaes, and because of their simple design and operation.
Particle size i* leas decisive to attainable efficiency th^n the'
weoiblllry of die dun and the degree of probability with which
toe particles can be brought into contact wita water.  The
simplicity of design can easily disguise these true difficulties.
   TBB§ sot *U wet secaeben can be regarded as truly efficient,
a It eat enough co spray water through nowies into a dust-
y 40
Weignt %
45 co 22
20 to 13
1 WU
28 to 54
    Deviations were only observed towards the coarser range. -
 The density of the durt panicles according to VOI 2031 was,
 ia  the average, about S.Sg/cm1,
    Given toe capacities of modern cyclone collectors U can be
 expected that some 35 — 92<$ of the dust of this composition
                                                           21
                                                          B-14

-------
                                                                       My. l»Tt
     TABLE 9,  Comparison of  (be measured  efficiencies of cyclones,  installed as  preseparators  at the
     lime of the  tests,  with the efficiencies  theoretically attainable  according  to  the guarantees
     of the  manufacturers
 I
N"\
 LLl
Plant
No.
A4
3
01
HZ
J2
J3
i2
C1
2
•a
04
. F3
"_
_.X4
JL1
it
n
Dua
panic
(
0 to
iOu
*
212
2X4
ii.2
.,fU
17.2
*aa
41.1
2ZO
24J
US
41 .5
27.7
37.0
"j
^AL
,-7-o
A4
t propci
•le-tize
• «2.3
10 to
20ji
*
11 1
S.S
3.S
10.0
17.3
1Z2
244
112
1XS
1U
20.0
1S.S
22.6
1.7
14.7
19J
13.1
rtioa la
totem
g/cm1)
20 to
40«
*
1L7
14.7^
u
,_!*-s .
1Z7
12.1
17
17.8
13.5
ISO
10,5
14.4
12.3
*r*_
211
__**.
13
iii
>40
|I
*
S40
S3.1
48-0
S*.i
S2.I
29.8
~~S£S~
413
4&4
Sfl.8
2S.O
*!.*
27.9
_!aS_
;*3
33.7
4TiT^
Total
efficiency
eyelont;.!''
measured
*
95.4
33-3
•7.1
91.3
97.2
90J
77.3
S4J
9X3

87.0
S2.1
^SJ
38.1
St9 ^
97.2
90.3
c
0 to
10|i
*
70*



Jraded
guarani
Rianuf<
10 to
20u
*
95%


efficies
eed by
icoirer
20 to
40u
*
98%


cy
>40
(J
%
39%


Toi
0 to
100
*
1SJ
i&a
12.7
ia.4
ira
28,8
2SJ
114
17.4
48
ra.o
134
25.8
2.0
2O4
4J
22.7
Mefflt
accor
8^
10 to
20fi
*
ma
u
8.1
JJ
16.3
1«J
211
14,4
11.3
12-2
19.O
14.7
21 J
1.8
t4J>
i7
txs
:ieacy c
iiag to
lorantet
20 to
40U
^fc
itj
14.4
U
113
12,4
11.3
18
17J
133
tSJ
1&3
14.1
12.3
9J
21. S
U
73
lalculat
tbese
a
>40
II
«b
S3J
sxi
€7,4
S3.S
S2.4
29.8
30.6
444
«a.s
58.0
27.7
41.9
27.i
88.5
33.8
810
4&S
ed
Totai
*
31.3
31.1
9X4
it.7
1X3
88.4
S8.1
91.3
SI -2
14.7
S8.0
sat
wa
97,7
89.8
M.3
89.0
Oeviai
(mtu
guira
*
*xs
*1a
*X9
•4.1
•IS
*it
*2J
*1.0
*2JJ
• 04
»1J
aon-tn *fc
lured —
meed)
-8-3
-0.4
-13

-U
-U
-ZJ
 Q
 LLJ
 in
CD
 HI
     will be retained In tile first stage.  Efficiency icrmnes wita
     Ificreuifla coarsfi compaaeau up to a possible 93%.. Siace,
     furrhennore. the  dasa ire relatively heavy ind toe guaranteed
     4«U of the manufacturer mostly refer co densities of ouiy
     Zg/era3. given tbe bigh dust contents, the higher efficiencies
     are certainly attainable.
       18 good wet sentbben.  racii as am frequemly used as a
     second ttage.  residual dust from'ine fine stage.Gt separated with
     .efficiencies of 93—96%,  in special cases even up co 9t —9*9%.
       Fabric or bulk  layer /Liters used, instead of wet scrubbers can
     attain efficiencies above 99%, when properly secured against
     unsuitable waste gas conditional
       The present ticiacion with regard to dust removal in prepara-
     tion plants is thus largely clear.  A detailed investigation of
     the processes of dust generation,  though beyond  the framework
     of this article, would bo of great interest for the further deve-
     lopment of preparation plants,  concerning problems of dust
     load and its removal.
       for particles of about 10 and 200 the settling velocities ate
     only 0.8 and 3.2 cm/sec.  Even coarser particles of 40|i settle
     only at some 12Jem/sec. Being stirred up by tipping pro-
     cesses in the drums, such panic lea are easily emitted with {he
     gases.  The drag  of waste  gases Is still to great that 53 — 70«i,
     and sometimes even up to 90% of ail dust panicles in the
     waste gases are larger than 40u. •
       Given the tendency rewards economical maximum  per-
     formance, Uie future will  ttardly bring large; drums for (he
     same, capacities.  Consequently, dusts capable of being air-
     borne will continue to leave the drams, unless watte gas quan-
     tities can be greatly reduced.  This is possible.  Even if  spe-
     cific dust content is to remain equal (In  test series K of the
programs this was the case. In spice of 10% CO,),  a reduction
of excess air to the Unit of the possible could lead to further
improvement of dust removal.  The smaller waste gas quan-
tities could permit the use of specifically more expensive
types of collectors at the same cost.  It is possible chat deve-
lopment will move in this direction,  and that ao teasoos for
controversy will remain also concerning the very last residues
of dust  in waste gases emitted by the stacks.
Bibliography

1.   Waiter, E. Causes of the Oust Situation at Mixing
     Plants for Bituminous Road Building Materials and Measures
     for Improvement, — Scrassenbau. S7th year of puni.. No. 5,
     pp.297-305. 1986.
2.   W a 11 e r, S. The Dust Situation at Mixing Plants for
     Bituminous Road Building Materials in the German
     Federal Republic, — Staub-aeinhalt. Luft,  Vol, 26,  No. 11,
     pp.34 -41.   1966 [English ganilartnnl.
Summary

  /Cost in waste gas from preparation plants for. road building
depends on many chanctuisric factors.  This ii-7sh"d for the
dust it the drying drum outlet and also for clean gas dust at the
chimney inlet.  The crude gas dust is naturally influenced by
the properties of raw material, whilst clean gas dust is also
influenced by the dust removal method used. These problems
ate discussed on the basis of a wide range of numerical data.
                                                              22
                                                            B-I5

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           APPENDIX C
REFERENCE 8 AND SUPPORTING DATA
               C-l

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          .ASPHALTIC CONCRETE PLANTS
         A1MDSIHEHIC EMISSIONS STUDY

           EPA COOT1ACT #68-02-0076
                 Prepared for

       E8VHONMEHTAL i IOTECTIQH AGENCY
            OIHCE OF AIR PSDGRAMS
Research Triangle Park,. North Carolina  27711
                 Prepared by

        VALENTINE, FISHER & TOHLIH50K
             Consul ting Engineers
            .  520 Lloyd Building
          Seattle, Washington  98101
                (206) 623-0717
                   Authors

                  J.A. Crim
               Grim Engineering
             Seattle, Washington

                 tf.D. Snow den
        Valentine, fisher & Tomlinson
              November 1,  1971
                      C-2

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                            IftO
9
CO
                              *M    *« f i  •»  *J  i   i

-------
MM
               fl».l IM    WJ   M

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                                                                                                                                              «J   *t (.1  Ml     Ml
9
en

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9
01

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           CONSULTANTS
           AIR, WATER, ENERGY, HYGIENE & MANAGEMENT
May 14,  1982
Midwest Research. Institute
425 Volker Blvd.
Kansas City, MO  64110

Attni  Mr» John Kinsey


Dear John,
   Ret  Original Particle Size Data from  EPA Asphaltic Concrete Plants
Emissions

The original '• field data  to the subject report is enclosed.  May I provide any
clarification?  Ifiank you for having us help you on your study.
Yours truly,
&Ca0Sjpm      ^
 ^^^^^^^
Wesley 0. Snowden, P.E.
Enclosures
                                                     7
                                   C-7
           180S - 136th Place N.E. Suite 104, Seilevue. WA 98005, (206) 641-5130

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                ENVIRONMENTAL PROTECTION AGENCY .
              AIR POLLUTION CONTROL OFFICE  (APCQ)

        ASFHALT BATCHI2IG PLANT EMISSION DATA COMPILATION
                   PART I - PLANT INFORMATION

DATA IDENTIFICATION   Sloan Constrtjotloir Co.	
FLAhT GEOGRAPHICAL LOCATION   Libertv.  S^C^.
TZPE. OF EAB MATESIAL PROCESSED Crushed granite and sand aggregate

PtAST CAPACITY   TO. ftOOff' Barber-Greene
ILAST PRODUCTION BATE (DURING EVALUATION)   225 tons/hr
TYPE OF CONTROL SYSTEH CyQlpj^e^ a^oV vet washer

AIR fLOW SATE (cfm)  37.900       t   510   *F &
                                                Static  across  the fan
LOCATION OF SAMPLING POiO:  (NOTE OBSTRUCTIONS) 	
J[>  Washer inlet2.  Richaust. g-fcaelr at  washer
            "  sq. duct         6  foot dian  - 2 ports  at 15 foot
        EQUIPMENT DESCRIPTION    downstream from stack  Inlet	
      See attached sheet
     PRESSURE DROP 	
     BRAND- AND SIZE OF CONTROL EQUIPMENT 	
     .WATER USAGE, ETC,  	
PARTTCLS SIZE DISTRIBUTION  (WEIGHT OR COUNT)   See attached renort
AVAILABLE COST TNFORHATION   Mot available
     PURCHASE COST
     OPERATING COST*
     HADJTENANCE COST

EVAPORATION LOSSES
COMMENTS:                   "  '

The system  described was replaced in the  early part of 1971
with a DP-710 Dynamic  Precipitator System furnished by CMI
Systemsf Chattanooga,  Tennessee.
                                             .
                                                     M^26 1971
                                                YAIE-ITIHE. FiSHEH 3 TQMUH

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                ENVIRONMENTAL PROTF.CTION AGENCY
               AIR POLLUTION CONTROL OFFICE  (APCQ)

         ASPHALT BATCHING PLANT EMISSION DATA COMPILATION
                   PART II - SAMPLE INFORMATION
DATA Identlficacion (Pore, Etc.)
TYPE OF STACK GAS SAMPLING TRAIN  Anderson  - See attaf!hgd

DRY. GAS VOLUME' RECORDED ON GAS METER (FT3)  'f1",'  m=	:	3

PRESSURE OF METER (laches Hg)	
AVERAGE- TEMPERATURE- OF DRY GAS METER (*R) 	_^_	

VOLUME OF H^G COLLECTED IN TRAIN (ml)     -   '  \ ;':  1 J   :    --,

VOLUME OF WATER VAPOR PASSING: THROUGH DRY GAS METER  (FT3  § METER
     TEMPE1ATU1E AND PRESSURE)
* MOISTUEZ IS STACK GAS (%}      11?°  F.D.B./1150 F.M.B.

MDLECDLAR WEIGHT OF DRY STACK GAS"' (LS/LB HOLE) 	
     2C02
     202
     ICO ~
STACK.'PRESSURE AT SAMPLING PORT (Inches Hg)
STACK GAS TEMPERATURE ("R) AND PITOT TUBE READING  ("HzO) S EACH
     TRAVERSE POINT :^'    — f ;• J/.^-'-  -"   '  * -  ].-m .  ^ ' * "

                                4  -3, "ST   W-2    j 3 Q & __;	 #17   '.^^_ S
^3  /. *•;•    &   .-3 "  j   ^8  •'..-'j _ &  3. J:T   ff!3    •. ". C & 	 #18
                      g9   ~ J  &•  *,  ;."    114    . :• /  & .	 *19   l ^ t   &
                          '."O  &   -  -0    #15    / • ',-^  & 	
TYPE PITOT TUBE USED W/ COEFFICIENT  Stvt?e      WITH     ).82

AREA OF STACK @ PORT (FT2)    28.1	.'«  .'^ -c^

SAMPLING TIME (MIN.) 	5	
TOTAL PARTICULATE (LESS BLANKS ON CLEAN-UP MATERIALS)

     FILTER FINAL WT. (rag) 	- TARE  (og) 	
     TYPE OF FILTER
     ACETONE RINSE OF PROBE £. PREFILTER  (tag)
     ETHER AND CHLOROFORM EXTRACTION ON
          BUBBLERS & IHPINGER WATER (mg)	
          120 EVAPORATION FROM IMPINGERS AND  BUBBLERS
     ACETONE RINSE OF GLASSWARE (mg) 	
     TOTAL PARTICULATE (rag)   OQ. ^ on  all plates

COMMENTS:
                                  C-9

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              Air f olltition Test
              December I,  1970
         Sloan Construction Company
          Liberty,  South Carolina
Date Performed;  December 1. 1970
                 Report by:  w. Konnan  Smith,  P.  E.


              Test Conducted By:

                 Norman Smith

                 Jim Campbell

                 C-10

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                                             A DIVISION OF Oil COIIIKJKATION
                                                  P.O. iox 6249 * 1617 W.
                                                     Cftattanooga. Tenntsa
                                                              (61S)
X.   INTROPPCTIOgr
         purpose  of the air pollution tests was  to determine
the emission rates and particle size distribution at the hot
mix asphalt plant owned by Sloan Construction  Company, Liberty,
South Carolina.   A study of the present equipment and the equip-
ment necessary to conform to the State of  South  Carolina Air •
Pollution codes were, additional primary objectives.

     By taking test samples at the air washer  entrance and
exit.,, the performance of the air washer could  be evalutated.

     She Anderson Stack Sampler was used as a  fractionating
device to determine the particulate distribution as well as
emission rate.
                                  C-E

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HI.   TEST PROCEDURE

       Each of-the test locations were tested according to the
  following -procedure:

       1.  The average velocity of the gas stream was determined
           using a special Pitot tube and an inclined manometer
           to traverse the duct.  The flow rate of the gas stream
         *  was then calculated using the average velocity and the
           caross-section area of the duct.  Test points were
           located as recommended by Bulletin WP—50, Joy Man-
           ufacturing Company.  The correction factor of 0.82
           as determined for previous calibration tests was used.
         '. The temperature of the gas stream was taken periodically
           to- use in calculating density.

       2.  IV reference station was selected to use as the point
           at which the sample was to be taken.  The reference
           station velocity pressure was taken and the velocity
         .  calculated.  In order to obtain an isokinetic sample
           the velocity into the sampling nozzle must be the
           same as the gas stream at the point of the sample.
           Using the known area of the sampler nozzle and the
           desired velocity,  the required sampler flow rate
           was calculated.

       3.  The sampling apparatus consisted of a probe to insert
           into the gas stream with a nozzle on the probe of
           arknown size,  an Andersen stack sampler, a vaccum pump,
           and a flow meter to measure the__total. air _flow_ through
           tbe^samplerv               '

       •*.  The samples were taken for periods that varied depending
           on the loading.  Two samples were taken at each location.
           The sampler was heated while the sample was being taken
           to prevent condensation of water vapor on the sample
           plates.  After allowing the plates to cool to room
           temperature the gross and the tare weight of each plate
           was recorded.   The flow rate through the sampler
           which was determined from previous calculations and
           recorded.

      • 5.  Velocity traverse calculations were made as outlined by
           Bulletin WP-50, Joy Manufacturing Company.
                                    C-12

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SOMMARY OF DATA
1.  Location. - Air Washer Exhaust "Stack

    Emission Rate ............. ......._..,........., .181 #/hr
    Grains per cubic foot ( Std. Cond. ) . ....... . ..... 0. 695
                                 ^-
    Dry Bulb Temp		,.	115° F
    Wet Bulb Temp..		115° F
    Mr 'Flow at Duct Cond.	...................32,600 ACFM
    Mar Flow at STD Cond	30,400 SCFM
    No. of Samples	......2


J»  location. -'Entrance to Air Washer,

    Emission Rate.	2135 f/hr
    Grains per cubic foot (Std. Cond)....	..8.2 Gr/c.f.
    Miorogromc pn~ Qubi.j. HAL-.' [C'uiiU Camel]	.10i7 -i 1QP
    Dry Bulb Temperature		. 210<=- F
    Wet Bulb Temperature.	.»210° F
    Air Flow At Duct Cond	37,900 ACFM
    Air Flow At STD. Cond	30,400 SCFM
    No. of Samples	2
                             O13

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3»  Fan Data:
        Clarage Size 141XL
        Motor • 100 H.P.
        Motor RPM - 1760
        Motor Full Load AMPS - 116
        Motor Operating Loan AMPS - 90
        Fat* EFK - 650
        Operating Static Pressure Across Fan  - 9.0 in. W. C,
                              014

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 ZZ7
      7 /
               J
                                 8
(THESE DATA REPRODUCED  IN TABLE 3-8)
              C-15

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Control Equip. Descrip,
Single cyclone
   2.

50 foot
Horizontal
Air Washer
Pressure Drop
                                 - 4 in. ¥.C.
                      3 - 5 in. W.C.
iranit & Size of Equip,
Esstee - 9 foot
Diameter
7 foot
Diameter x
50 feet long
Water Usage
                               None
                       150 -  200 GPM
                                 C-16

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II.   EQUIPMENT

      1.  Special Pitofc Tube
      2v  Dryer Inclined Manometer
      3.  Andersen Stack. Sainpler
      4.  Dry and1 Wet Bulb Thermometer
      5.  Vacuum Pump and Sampling Train
      £_  Storbal Precisian Balance
          (Accurate to i/10,OQQ gram)

      CWHER*S EQUIPMENT TESTED
      1.  Barher-Greetie Batch. Plant
      2.  Cyclone Dust Collector
      3.  'Clarage 141XL, Exhaust Fan
      4-.  HorizcmtaL Air. Washer
                          C-17

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                   EHVI10KMENTAL PROTECTION AGENCY
                 MR POLLUTIOM CONTROL OFFICE  (APCO)

            ASPHALT SATCHHK; PLANT EMISSION DATA COMPILATION
                      PAST I - PLAHT IHFORMAT1QN

   DATA IBENTIFlCATiaS   Harbison.  Inc.	.	.
         GEOGRAPHICAL LOCATION   Marwille. Tennessee

        OF HAW MAIESIAL BI0CESSEB Limestone and  sand
   FLAHT, CAPACITY   6.000 lb. batch
   PLANT F80DUCTIQH SATE (DDSIHff EVALUATION)  180  tons per hour

   TIPS OF COSTEOL SYSTEH. Prv cvc^onej |>re-washer and cent,  washer

   AIR. 1LQW BATE (cfm)    TI.SOO      f    70   *7 &     ' _
   LOCATIOS OF SAMPLING PORT (HOTE OBSTRUCIIOHS)  Two ports  at  QQQ in a  six
   foot  diameter  exh^yst stack  app*ro?clrnatelv- 20 fi»<>t  dotim^ifr^am f?-nm
   •tiae stack inlet.
I. CONTHOL EQUTPHEXT DESCRIPTIOS  Centrifugal  sprav washer - vertical

        PHESSTJRE B10P   1 in. W.C. _
        SSASD AMD SIZE OF CONTROL EQUIPHEXT Slm^ijiity - TO  foot rt-iameter-
        HAIIR aSAGE,, ETC.  150 - 200 GPM _ ; _
   See attached sheet  for items  2 and 5.
   FABUCLE SIZE DISTSIBUTIOK OreiGHT OE COllNT} See  attached  chart
   AVAILABLE COST ISH3RMAIIOK
        PtJRClASE COST
        OfESATBIG COST"
        MAIKTENAMCE COST

   WAPORATIOS LOSSES
   COMMENTS:

   This  system when  tested was emitting 6j lbs/hr which was over the
   Tennessee code.   The contractor has now installed a CMI  Systems
   DP-71Q  which is a Dynamic Precipitator System.   I will be glad
   to furnish the test information to you as  soon as it is  complete.
                                   O18

-------
                              PROTECTION ACQJCY
                   POLLUTION CONTROL OFFICE  (AFCQ)

         ASPHALT HATCHING PLAJfT EMSSIOK DATA COMPILATION
                   ?ABX II - SAMPLE ISFOBIlAllQSJ
3AXA Id«QClficaciott (Pore, Etc.)
XffE OF STACK GAS SAMPLING TRAIN   _An_derson
                             i""i
BBX GAS VOLUME 5ECOROED OS GAS 'METER (FT3)     ^ , 5 '.* 7_-'; '_ "

RESSOTEE OF KETEE (laches
ATOSAGE TSff'EEAlUSE OF OR! CAS METES (*B)

       OF I20 COIiECTEB DT TSAZK (ml)
       OF WATER 7APOR. PASSING W10IICS DE? GAS MEISR  (FT3 i METER  I  < .. V :    j
                 AHD PSESSUSE) 	^1*_*    2"
  MOISTtffiE Dt STACK CAS (Z)
0.B. Temp *  112°F    V.I.  Temp  « 112<»P
MOLECULAR UEICMT OF DRT STACK CAS (LS/L3 HOLE}

     JC02 _
     202 _ _
    • 3SCO ___
STACK PRESSURE AT SAMPLING PORT (laches Ig) t	

STACK. GAS TEHPlSATtUffi (1)' AOT PITOT TOTE READING  ("BlQ)  @
     TJSAVERSE POIHT;
12 ^
^•j &>
17 J -JZ &
#12 5 . ? J i
fl? &
13 1,l£" & #8 2_'}~)'^ & 113 & #18 4
#4 ;
15 S:
UPS
. ~.3 &
j"l- &
PITQT TOTE
OF STACK f
19 -• - ,' 3 &
110 3 i'i &
US'ED W/ COEFFICIENT
PORT err2) lar?' so
ii4 &
#15 &
S Time WITH
. ft.
IIS &
#20 i
.81
/ * » i **r' ' '
SJIHPLIMC TIME (MIN.)   ? ainutes
TOTAL PARXIOILATE (LESS BLANKS ON CLEAH-UP
            FISAL WT. (mg) _ - TAtE  (mg)
     TYPE OF FlLfEE  _
     ACETONE RINSE OF PROBE & PREFILTER  (rag)
     ETHER AND CHLOROFORM EXTRACTION OS
          BUBBLERS & IHPIKGER WATER
              EVAPORATION FROM IHPIHGEKS AMD 8U3SLERS
     ACETONE RINSE OF GLASSWARE («g) 	t
     TOTAL PARJICULATE (»G) 	
                                C-19

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                                     ESTIMATED EMISSION RATES
                                                                           Harrison,  Inc.
                                                                           Alcoa,  Tenn.
                                    !!>!££. II, f/Hr, stftito Pun
                                     to Collecting System
                                         efficient
Co wet collector
             B  Diameter X
           approx
                                         Material  to dryer
                                                ZOO weah
                                                                                                        collected
                                         collected
Dryer Discharge
  \60  TPII to plant

Mute I
  I,  Emission rotes may vary from those
      shown. However these valyea are an
      estimate based on actual reaulte
      and with material which weights
      100 lbi./cu. ft.
  2.  Exhnuat fan for draft not ahown

-------
2.   Control Equipment Description:  Pre-washer
        Pressure drop                5 in. ¥.C.
        Brand and size of equipment  Simplicity - 7 foot
        Water usage                  30 • 50 GPM	
3.   Control Equipment Description:   Cyclone
        Pressure drop                4-5 in.  V.C-.	
        Brand and size of equipnent  Simplicity - 9  foot dlam.
        Water usage                  None	
                             021

-------
        N,.  IKC.  - MAHYVIT.LK,  TENN.
 PIUS-VASII ENTRANCE.
VASHEIl EXHAUST
MJCHOK SIKE % #/tm % ,f/Hll
30 & larger
5.5 to 30
2.0 to 5.5
Smaller lhaa


^0 23.1 : 396.2
.V -2(5.9 • ;• ' 461.3
; > . 35.1 "* r 602.0
2.0 1A.9 ,' . 255.5
1715.0
OVERALL EFF. =1715 -
3.0
2.2
6.8
83.0

6j s 1652
1.9
1.4
'i.3
55. i»
63-0
» 96. 355
EFF.
                                             9&.9%
                                             99.73
                                             99.3S
                                             78.355
                1715	1715
(THESE  DATA  REPRODUCED  IN TABLE 3-9)
               C-22

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 APPENDIX D
REFERENCE 12
      D-l

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     AIR  POLLUTION
ENGINEERING  MANUAL
          SECOND EDITION

         Compiled and Edited
               by
          John A, Daniilson


   AIR  POLLUTION CONTROL DISTRICT
      COUNTY OF  LOS ANGELES
    ENVIRONMENTAL PROTECTION AGENCY
      Office of Air and Water Programs
 Office of Air Quality Planning and Standards
     Research Triangle Park, N.C.  27711

             May 1973
             D-2

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                                              CHAPTER 7
                                   MECHANICAL  EQUlPMENf
        HOT-MIX ASPHALT  PAVING
              BATCH  PLANTS

INTRODUCTION
Hot-mix asphalt paving consists  of  a combina-
tion of aggregates* uniformly mixed and coated
with asphalt cement.   An asphalt batch plant  is
used to heat, mix, and combine the aggregate and
asphalt in the proper proportions to give the de-
sired paving mix.  After the material is mixed,  it
is transported to the paving site  and spread as a
loosely compacted layer with a uniformly smooth
surface.  While still hot, the material is compacted
and densified by heavy motor -driven rollers to pro-
duce a smooth, well-compacted course.

Asphalt paving mixes maybe produced from a wide
range of aggregate combinations, each having par-
ticular characteristics  and suited to specific de-
sign and construction uses.  Aside from the amount
and  grade of asphalt cement used, the principal
characteristics of the mix are determined by the
relative amounts of:

Coarse aggregate (retained on No, S-rnesh sieve),

fine aggregate (passing No. 3-mesh sieve), and

mineral dust (passing No.  200-mesh sieve).

The aggregate composition may vary from a coarse -
texturedmixhaving a predominance of coarse ag-
gregate to a fine-textured mix having a predomi-
nance  of  fine aggregate.  The  Asphalt Institute
{1957)elassifieS'hot-mi3S asphalt paving  according
to the relative amounts  of coarse aggregate, fine
aggregate,  and mineral  dust.   The general limits
for each mixtype are shown in Table 91.   The com-
positions  used within each mix type are shown ia
Tables 92 and 93.


Row MoUriaU Used

Aggregates of all sizes up to 2-1/2  inches are ussd
in hot-mix asphalt paving.  The coarse aggregates
usually consist of crushed stone, crushed  slag,
crushed gravel,  or combinations  thereof,  or of
material  such as decomposed granite  naturally
occurring  in a fractured condition, or of a highly
t$ t ctrm -jtea u aescriae cne solii mineral  lo.i
  °* -isenalc saving sucn 4* tana- particlos -ind
  vel
caojcity*"'* °* -isenalc saving
jf stone. y«"*vel. and so farcn.
                                             angular natural aggregate with a pitted or rough
                                             surface texture.  The fine aggregates usually con-
                                             sist of natural sand and may contain added materi-
                                             als such as  crushed stone, slag, or gravel.   All
                                             aggregates must be free from coatings of clay, silt,
                                             or other objectionable matter and should not con-
                                             tain clay particles  or other fine materials.  The
                                             aggregate  must also meet  tests for soundness
                                             {ASTM  designation  C88) and wearability  (ASTM
                                             designation C131),

                                             Mineralfiller is used in some types of  paving.  It
                                             usually consists of finely ground particles of crushed
                                             rock, limestone, hydrated lirne,  Portland  cement,
                                             or  other nonplastic  mineral matter. A minimum
                                             of 65 percent of this material must pass a 200-mesh
                                             sieve.  Another name for mineral filler  is mineral
                                             dust.
                                             Asphalt cement is used in amounts of 3 to  12 per-
                                             cent by •weight and is made from refined petroleum.
                                             It is a  solid at ambient temperature but is  usually
                                             used as a liquid  at 275°  to 325 T.  One property
                                             measurement used in  selecting an asphalt  cement
                                             is the "penetration" as  determined by ASTM Method
                                             DS. The most common penetration grades  used in
                                             asphalt paving are 60  to 70,  85 to 100, and 120 to
                                             ISO, The'grade  used depends upon Che type of ag-
                                             gregate,  the paving use, and the climatic condi-
                                             tions.
                                             Basic Equipment

                                             A typical hot-mix asphalt paving batch plant usu-
                                             ally consists of an oil- or gas-fired rotary drier,
                                            ^a screening  and classifying system, <,veigh boxes
                                             for asphalt cement  and -aggregate, a mixer, and
                                             the accessary conveying equipment consisting of
                                             bucket elevators and belt conveyors,   Eauipment
                                             for the storage of sand, gravel,  asphalt cement,
                                             and fuel oil  is provided in  most plants.  Heaters
                                             for the asphalt cement and  fuel oil tanks are also
                                             used.
Plant Operation

Plants vary in size.  The majority in Los Angeles
Countyproduce 4, 000-pound batches and ha%*e pro-
duction  rates of 100 to ISO tons of asphalt paving
mix per hour.  Same ot the newer plants area, 000 -
pound batch size and are capable of producing 150
to 250 tons oer hour.
                                                 D-3

-------
 326
                                 MECHANICAL EQUIPMENT
                    Table 91.  CLASSIFICATION OF HOT-MIX ASPHALT PAVING
                                     (The Asphalt Institute, 1937)
       Paving HUN
                        M;t \imimi *iv.»'
                          .iliSl'i-jliili-
                        normally iu»v•• j ^g-'f.

* " A
K;A
, •
>^'.
-'H^

'.Y*3
j . ACCRKC;
$
*ik
'i'f'-'t

%
GRf"<*a^.ci ,
AND "*5_
^ LEVEL^i
OASE. V^\ ING
Y5/.* MIX Si
HINDER, K^Js
AND
LEVELINC

No- 4 loot
- ' . \
V*
A TK PKOP
THIS ARK
r NOKMAI
KCOMMEN
— KOI? PA
o\
\*\ CO.^H'
*
\
•5
I
oirrrONH


I
DKD •
Vt'MENT — •

niUCTlON

. -\
*" \
"ion
U
y
35
HO «
5
«i
X
f.o 5
H
U
50 5
U
H
40 •<
O
-"1
" I
.9
0
        zone - Dxiat contents in this region should
mil he used without  a substantial background 01" ex-
perience with such mixes and/or suitable justifica-
tion by laboratory design tests.  	   	   	
Intermediate zone - Dust contents in this region
jometimes usud in surface and leveling mixes as. /
well as in base and binder mixes.         >.\,ii»»i!r
                                                        0         3         10
                                                        % MINERAL DUST {PASSING MO. ZOO SIEVE)
Figure  i21 is a Clow diagram of a typical plant.
Aggregate is  usually conveyed from the storage
bins to the rotary drier by means of a belt con-
veyor and bucket elevator.  The drier is usually
either oil- or gas-Cired and heats  the aggregate to
temperatures ranging from 250*   to 350°F,  The
dried aggregate  is conveyed by a bucket elevator
to the  screening equipment where it is classified
and d\imped into elevated storage bins.  Selected
amounts o£ the proper size  aggregate are dropped
from the storage bins to the weigh hopper.  The
weighed aggregate is then dropped into the  mixer
along %vith hot asphalt cement.  The batch is  mixed
and then dumped into waiting trucks for transporta-
tion to the paving site. Mineral filler can be added
directly to the weigh hopper by means of an  auxil-
iary bucket elevator and  screw conveyor.
                                                 Fine dust in the  combustion gases from the rotary
                                                 drier is partially  recovered  ut a precleaner and
                                                 discharged continuously into the hot dried aggre-
                                                 gate leaving the drier.

                                                 THE AIR  POLLUTION PROBLEM
                                                 The largest source of dust  emissions is the rotary
                                                 drier.  Other sources are the hot aggregate bucket
                                                 elevator, the vibrating screens,  the hot aggregate
                                                 bins, the aggregate weigh hopper, and the mixer.
                                                 Rotary  drien emissions up to 6,700  pounds per
                                                 hour  have been  measured,  as shawm, in Table 94.
                                                 In one  plant, 2., 000 pounds  of dust per hour was
                                                 collected from the discharge of the secondary dust
                                                 sources, that is, the vibrating screens, hot aggre-
                                                 gate bins,  the  aggregate  weigh hopper, and the
                                                 mixer.
                                                 D-4

-------
                            Hot-Mix Asphalt Paving Batch Plants
T>Z1
Table 92.  COMPILATION OF SUGGESTED MIX COMPOSITIONS (The Asphalt Institute,  1957)

Hyp*
Mia



s





••






tla



. !tb

11 c


IH a

I

| (100 tl)


til b i
IV a. 1 i
[V b
IV c
V »
V b4
V! a
VI If
VII a»
Vtll »








100
100 TO tu 100* -45
j 100 T5
100

7f ro 100 1 ou
too i so
100 SO In IOO! 7fl
so ta ina : ' 60

100 ! 35
! 100 i m to 100)




I 100 ! 85
100

too


40

u looi :o
o "*
0 100
iU
n
a Mi 1*
o lOfll l«
o "01 «0
a JO
to too
1. 4

tu »»i « in ifl '.

0 401 '
i> 41)
0 »«
a *5
a 7*
1 *
ill
in
n
o 70! IS
4S to 65
t*
0* iu HOI «o
; 63 to 30) *O
to 100 I
, •»« to iOOi
i


*M«T bf> «*wl fur b*ii> wh»r» nwr»,- iMn>|iMc » tioi ron
too

Ii ta 100
too
6*
u iO '
,i ifl

0 1* 10 n ii
0 !* 10
£» *O - 1 *
t> «0 13
0*1} 1 <»
«> 4< »7 o »4 i«
u 6* , 17 o *£ , i<
u '•)« *0 »i TO • H
** t»> HO '. 47 u ft It . 10
SO to <»* . 70 o .N<> . M
o* to 100 i M« ii •>* 1 TO
u • *
NH. "iii N<». looixii. inn
!u <> 4
i in


h „ u,

U i" 1 i i

to
40
i »

IN
+01 IH
60
'«

i*
•0
XI
•»«(40
comically av.ti|j*JtU>.
4 tu Ii
(> Ih: i n Ii

•t
n iJ -j

u HI
7
IH
i, who
u If
u in
it 413
t1
in
10
„ 7* '.jo
u if.
,. 16

u iO
„ in

u i'
•1 i*
0
n
,
^
4
4
(J
s
I
,,
;
0 4
A.ph.lt.
4. n » i-O
4. 0
u 4 4.H
II 4
i, *)
ii 4 1 I.f)

n in
! (»
J. *
n ID i t, *

n 1(»
ii in
II 1 J
.. H
4 :u 14

4. O
4. n
•». <
4. <
»,, 0

<« 5,0
o 1,0
o ti.Q
<» o.O


o T, 0
.) T.I)


11 H i
,| 4 i
<» I 1 . 0


Table 93.  COMPILATION OF SUGGESTED MIX COMPOSITIONS (The Asphalt Institute, 1957)
Mix
«rp»
i-I/i in.
1-1 /i in.
1 in.
1/4 in.
l/i in.
Ml in.
Mo. 4
,H«. H
M». Id
«n. (0 | Mo. *»
j
N«. ion |N». woj A'^'"-
1 ! ' ._
u«
tt 4
Illb
UI c
:i( it
IV c







IOA


100
ion
JOO
70 lit 110
1(1 II
too
T* «u 100
VO lu 100
70 la 100

7» lu ItMl
T* lu 100


45 u 7*
it) n 40
« lu iO
(* u iiO [J 11 »«l * in iO
SO u H«
1* « «*
so 11 M* ;n u 'fi
44 u 70
ttU ii .41]
ill In \*>
in iu t*
10 o ^oiin tu «
H «i d» 1* lu *(1






I i 0 tu 4 i i, J '.a o. 0
• j i) lu 4 | S. 0 ta 6. 0
10 lo ii ' b tu Ee 4 En Ii E i tu * ; *, 0 ta 6. 0
J i» in " i tu li i tu t i '> i" t i i. a in o. o
« In iO ' 1 lu Ii i In N • <> lu » ! i, H lu 6. t>
1" lu IO | 1 * n> i « J i«. 1 * 1 i» n» ' 1 i. ^ t« T. <)
l^vrlinii
:u b
V !>»
vi b*





i
loo !TS ti. ioa
100 U* la 100
100
01) 10 <*

^ In ;*
iO to l»
n« 10 MOI'iO lu ft*
*« 111 ieiiM j»* iu !fo

it ui ~i
47 lu h*
10 tu ii ! * in Is { 4 tu Ii ; i lu 1 ' i.'J tu B. 3
i«i to 411 IH 1,1 SO M» l«i ifl ! t lu HJ '. 11 lu 7. *
to t,. «* ' in ui 4u n> tu ii j » :n « c -t. ' iu 3, 5
«&«.-
! 3
tt d
U c
Jtlt
III 1!
IV (i
100


JS to JO i 0 u I*
I 100 70 a 100
100 • TO lit EDO SO n -tO
' iflO


100 ! 7« la tOO
100 'HO ta 100
7* u 100
bO ., 11
TO u ••*

i^ !<* bO
i 0 lu *
l=i in '*
i^ tu *l] '• 10 tit 10
' in in
* in in
4* ii, 70 . SO t«i »(l|iO In l«
1(1 li> n« i <() tu ^dlill to t«
IS u. 7% 4< tu -,i





j i j u t., t ! i.n ;.. 4. s
t : tl in 4 1 t. ft tu IT. n
1 i ;i ;u 1 t, i) i., R. i>
» tu io , ; iu ii' i »i * '' •» "" 4 '.i> in >i, •>
* 

                                                                                     STACK
                                                                                     ;AU —f
vv
                    £010 JGGREGiTE
                    3UCSEI ElifiTOS
                                              HOT
                                              9UCXET I
                Figure 221.  Flow diafram of 3 typical hot-mix asphalt paving batch plant.

                                           D-5

-------
323
MECHANICAL EQUIPMENT
             Table 94.  DUST AND FUME DISCHARGE FROM ASPHALT BATCH PLAMTS
              Test No.
            C-426
                                                        Drier
                                                       21,000
                                                           130
                                                        6,700
                                                            37.2
                                                           C-537
              Batch plant data
                Mixer capacity,  Ib
                Process weight,  Ib/hr
                Drier fuel
                Type oi mix
                Aggre gate feed, to dries, -wt %
                 + 10 mesh
                 -10 to -MOO rnesfa
                 -100 to -f-200 mesh
                 -200 mesh
             6,000
          364,000
           PS 3 00
           street,  su
                                                           6,000
                                                         346,000
                                                      Oil,  PS3QQ
                                                      Highway,  surface

                                                              68, I
                                                              28.9
                                                                1.4
                                                                1.6
                                                O
                                                !—)
                                                 I
                                                r»n
                                                 ui
                                                 _i
                                                 03
                                                      a
                                                      ID
Dust and fume data
 Gas volume, scfm
 Gas temperature, *F
 Dust loading,  Ib/hr
 Duat loading,  grains/sc£
 Sieve analysis of dust,  wt%
   *100 mesh
   -100 to 4-200 mesh
   -200 mesh
 Particle size  oi -iOO mesh
    0 to  5 (A, wt %
    5 to 10 (A, wt %
   I 0 to 20 n, wt %
   20 to 50 p., wt %
    > SO fi, wt %
Vent line
 2,800
   213
 2,000
    81.
                                                                     13.3
                                                                    27.6
                                                                    40,4
                                                                     12. 1
                                                                      1. 1
  Drier
22,050
   430
 4,720
    24.98

    13.9
    32.2
    48.9

     9.2
                                                                                 12.3
                                           49.3
                                            6.5
                                                                                            UJ
                                                                                            OT
                                                                                            UJ
              aVemt line  serves hot elevator,  screens,  bin,  weigh hopper,  and miser.
 Drier dust emissions increase with air maas ve-
 locity,  increasing rate of rotation,and feed rate,
-hue  are independent of-.drier-siope~-(Friedmaa~and
 Marshall, 1949).  Particle size distribution of the
 drier feed  has an. appreciable effect  on the dis-
 charge  of dust.  Tests show that about 55 percent
 of the  minus 200-mesh fraction, in the drier feed
 can  be  lost in  processing.   The dust emissions
 from the  secondary sources vary with  the amount
 o£ fine material in the feed and the mechanical  con-
 dition of the equipment.  Table 94 and  Figure 222
 give results gf source tests of two typical plants.
 Particle size of the dust emissions and of the ag-
 gregate feed to the drier are also show*.
 HOOOtNG AND VfNTILATlON REQUIREMENTS

 Dust pickup must be provided at all the sources of
 dust discharge.   Total  ventilation  requirements
 vary according to the size of the  plant.  For  a
 6, OOQ-pound-per-batch plant, 22,000 scfm is typ-
 ical, of which  18,000 to 19,000 scfm is allotted
 for  use in  controlling the drier emissions.  The
 topendof the drier must be closely hooded to pro-
 vide for exhaust of the products of combustion and
 entrained dust.  A ring-type hood located between
 the  stationary portion of the burner housing and
 the drier provides satisfactory pickup at the  lower
                end of the drier.  An indraft velocity of 200 ipm
                should be provided at the annular opening between
                the"circurnfeTeace^oi the~drier"an«i*the ring-type
                hood.

                The secondarydust sources, that is, the elevator,
                vibrating screens, hot aggregate Dins, weigh hop-
                per, and mixer, are all totally enclosed, and hence,
                no separate hooding is required.   Dust collection
                is  provided oy connecting this equipment through
                branch ducting to the main exhaust system.  Ap-
                proximately 3,000 to 3,500 scfm will adequately
                ventilate these secondary sources.


                AIR POLLUTION CONTROL EQUIPMENT

                Primary dust collection equipment usually consists
                of  a cyclone.   Twin or multiple cyclones are also
                used.  The catch oi the primary dust collector
                is returned to the hot bucket elevator where  it con-
                tinues on with the main bulk of the drier aggregate.
                The air discharge from the p-" nary dust collector
                is  ducted to the final dust collection system.

                Two principal types of final control  equipment have
                evolved from  the many  types employed over ch«
                years:  The multiple centrifugal-type spray cham-
                ber (Figure 223) and the baffled-type aurav tower
                                                D-6

-------
                                Hot-Mix Asphalt Paving Batch Plants
TEST C-4ZB
m 	
vat UMS ISM ^-'"f /" J—.M. 	 ii.
2.009 IB/nr ,
F«0» DRHR —
• 	 w
8. TOO IS.-IK EFFICIENCT
\
SITUfW TB HOT EUmOR
""i. ill iB/nr
j = 30. IS
muifii
CENTS IFUS*l
SCRTJ88ER
EFFICIENCT
s 99, IS






f


f




TEST C-SJT
FM
«»T MHI 	 ii« ih,hf ^— 1 	
?«] (6/iif
FBOH 08fH " f—


— t hCLOHI
t. 72o"iWlir 	 " k|iiiciyCT
\
BfiTMH TD HOT IIO4TOR
EFFICIEHW \ /
«7» W
wanni
CENTHIFUGAL
SCRU8BER
EFFICIfJICT
* n.j«
1 407 iD/hr
S.K* ii/hr



_Li
b
TCR MB MO
t,49S ts/hr
OUT OUST
TO moment
33.9 ID, Mr



'




*

"*•



RATER MO MUD
34. 5 m/ftr
flHT OUST
               Figure 222. Test data an air padutian control equipment serving tva hct-mix
               paving plants (vent line serves screens, hot SHIS,  weigh hopper, and miner).

      223.  Typical multiple centrifugal-type scrubber
servings 4,QQB-pound-aatcrt-eapctty tiot-wix asphalt
javing plant.
(Figure 224).  The multiple centrifugal-type spray
chamber has proved the more efficient.  It consists
of two or more internally fluted., cylindrical spray
chambers  in  which the dust-Laden gases are ad-
mitted tangentially athigh velocities.  These cham-
bers are each about the same size, that is, 6 feet
in diameter by  15 feet in length, if two chambers
are used,  and 6  feet in diameter by 9 or 12 feet in
length if  three  chambers are used.   Usually 7 to
12 spraynozzles are evenly spaced within each
chamber.   The total  water rate to the nozzles is
usually about 70  to 250 gpm at 50 to 100 psi.  In
th* baffled -type spray tower,  there have been many
variations and  designs,  but  fundamentally,  each
consists of a chamber that is baffled to force the
gases to travel in a sinuous path,  which encoura'ges
impingement of the dust particles  against the sides
of the chamber and the baffles.  Water spray nox-
zles are located amonsj the baffles,  and the %vater
rate through the spray nozzles is usually between
100 to 300 gpm  at 50 to' 100 psi.

In both types  of scrubber the water may be either
fresh  or  recirculated.   Settling pits or concrete
tanks  of  sufficient  capacity  to allow most of the
collected dust  to settle out  of the water  are re-
                                                   D-7

-------
330
MECHANICAL EQUIPMENT
  Fiprt 224.  Typical baff jad-type spray tower serving
  a 4,(KM-paur«J4atcfi-cajiaeity hot-nix asphalt paving
  plant (Griffith Company, ViInington, Calif,).
                                                       The  effect of aggregate fines  feed rats on stack
                                                       emissions at constant water-gas ratio (an average
                                                       value for teat considered) is shown in Figure 225
                                                       for multiple centrifugal-type scrubbers and baffled
                                                       tower scrubbers.  Stack emissions increase lin-
                                                       early with an increase in the amount of minus 200-
                                                       mesh material  processed.  '.These losses  can be
                                                       greatly reduced by using a clean or -washed sarid,
                                                       The  required fines content o£ the hot-mix asphalt
                                                       paving is then  obtained  by  adding mineral filler
                                                       directly to the plaat weigh hopper by means o£ aa
                                                       auxiliary bucket elevator and screw conveyor.

                                                       Most asphalt paving batch plants burn natural gas.
                                                       When gas is not  available, and if permitted  by law,
                                                       a heavy fuel oil (U, S. Grade No. 6 or heavier) is
                                                       usually substituted.  Dust emissions to the atmo-
                                                       sphere  from plants with air pollution control de-
                                                       vices were found to be about 3, 1 pounds  per hour
                                                       greater when the drier was fired with oil than they
                                                       were when  the  drier was fired with natural gas.
                                                       The difference is believed to represent particuU.ce
                                                       matter  residing in,  or  formed by,  She  fuel oil,
                                                       rather than additional dust from the drier.   Simi-
                                                       larly, the burning of heavy fuel oils in other kinds
                                                       oCcombustion equipment results in greater emis-
                                                       sions of particulate matter.

                                                       The amount of water E«d to the  scrubber is  a very
                                                       important consideration.  The spray noazles should
 quired with a "system  using recirculated water.
 The  scrubber  patch is usually hauled away and
-discarded.—It is usually unsuitable for use as min-
 eral filler in the paving mix because it contains
 organic matter and clay particles.  The recircu-
 lated water may become acidic and corroaive, de-
 pending upon the amount of sulfur in the drier fuel,
 and must then be treated with chemicals to protect
 the scrubber  and stack from corrosion.   Caustic
 soda and lirne have been used successfully for this
 purpose.


 VortahUs Afftefing Serttbb«r Enmjions

 Inarecentsrudy (Ingels et al. , I960), many source
 testa (see Table 95) on asphalt paving plants in Los
 Angeles  County were used to correlate the major
 variables affecting stack losses.  Significant var-
 iables include the aggregate  fines  feed rate (the
 minus 200-mesh  fraction),  the type of fuel fired
 inthedrier, the scrubber's water-gas ratio,* and
 the type of scrubber used.  Other,  less important
 variables were also revealed in the study.
 The »4C«r-gas ratio is aeMneo Ji ;ne ioc»l qu*nc
 Sf»ra?«a in gallon* oer I.JOO scf of ('flume g«.
                    ID
                               _
                            2,008     4 030     S.JOO     MM     19 '
                             OF FlHCS (JINKS SO «$H) Id 88TES FKB. IB "'
                    figure 225. Effect of iggrepte  fines fwd  rate on
                    stack emissions at averate later-eas ratio  (tnesis
                    et ai..  1980).
                                                   D-8

-------
                                 Hot-Mix Asphalt Paving Batch Plants
                                            331
 Table 95,  TEST DATA FROM HOT-MIX ASPHALT PAVING PLANTS CONTROLLED BY SCRUBBERS
Test No.
C-3S7
C-32
C-379
C-355
C-372B
C-372A
C-369
C-393
C-J54
C-JSS
C-173
I
C-379
C-3J?
2
C-234
C-426
C-417
C-425
3
C-385
C-433
C -422(1)
€-42,1(1}
C-413
Averages!
Scrubber
inlet dust
Loading,
Ib/hr
940
427
4, HO
2, 170
12!
76
352
4,260
.»
1,640
--.
._
3,350
30S
..
372
2.620
560
485
~
212
266
-_
-_
3,400

Stack
emission,
Ih/hr
20.7
35,6
37. I
47.0
19.2
10.0
24.4
"26.9
2T.3
2S.3
31.0
33.5
30.3
13.6
21.1
21.2
25.5
39.9
32.9
25. 5
17,5
11.0
26.6
37.0
30.3
26,?
Aggregate
fines rate,
Ib/hr
9, 550
4,460
8.350
14,000
2,290
2.840
4.750
4,050
6,370
5.220
3,350
7, S20
6. 500
2. SIO
3.730
2,530
10,200
3,050
2,990
6,590
4,890
5,960
7. 140
3.340
9, 350
5.900
Water-gas
ratio,
gal/ I, 000 scf
6.62
3.94
6.38
6.81
10.99
11. 11
5.41
12.01
6. 10
19.40
20.40
11.01
5.92
11. 11
7.28
5.70
7.75
2,94
4.26
6.60
4. 56
3. 12
4.90
3.02
S.90

Overall
scrubber
efficiency,
wt %
97.3
91.6
99, 1
97.8
84.2
36.3
93.0
99. 3
«...
98.7
--
—
99.2
9S.5
--
94.1
99.0
92. S
93.2
--
91. 7
95. S
..
._
99. I
94.9
Type
of
scrubber
C
C
C
C
(•*
C
C
T
T
T
T
T
C
C
T
T
C
C
C
C
C
C
C
C
T

Type
of
drier
fuel
Oil
Oil
Oil
Oil
Production
rate,
tons/hr
183.9
96.9
F
Gas
effluent
vulunip,
*cfm
23, !00
1 '',100
174.0 -6, 200
209. 1 45, 700
Oil 142. 9 ! 13, 200
Gas
Oil
Oil
Oil
Oil
Oil
Oil
Gas
Oil
Gas
Gas
Oil
Oil
Oil
Gas
158.0 13,100
m.o 16,100
92.3 19,500
113.4
137.8
7, 720
13.700
134. 2 i 17,000
144.6
191. 3
114. 6
124. 4
42.0
132.0
138. 9
131. 4
131. 7
Oil ! 174. 3
Gas
Oil
Oil
Oil

I 14. i
198. 0
1*2.0
1 16. i

23.700
2S. JOO
24. 300
15,900
17.200
22,000
24,600
13,000
13.200
20,000
19,600
il. 000
22,200
17, 100

 *Quantity of finei (minus 200 mesh) in dryer feed.
  ~~  - Multiple centrifugal-type spray chamber.
     3 Baffled Cower scrubber.
be located so a:1- to cover the moving gas stream
adequately with fine spray.  Sufficient water should
be used to cool the gases below the dew point.  One
typical scrubber tested had an inlet gas at 200 °F
with 16.3 percent water vapor content by volume,
and an outlet gas  at  131T with 16.3  percent water
vapor and saturated.   The temperature at the gas
outlet of efficient scrubbers rarely exceeds 140'F,
and the gas is usually saturated with water vapor.

Figure 226 shows the effect of the scrubber's water -
gas ratio on dust  emissions  with the aggregate fines
feed rate held constant (as average value for the
test  considered).   Efficient scrubbers use water
at rates of 6 to 10 gallons per 1,000 standard cubic
feet of gas.  The  efficiency falls off rapidly at water
rates less than 6 gallons per 1,000 scf of gas.  At
rates of more than 10  gallons per 1,000 set of gas,
the efficiency still increases, but at a  lesser rate.

Curves are presented in Figures 227 and 223 from
which  probable  stack emissions  can be predicted
for oil-  and gas-f1-ed plants with either multiple
centrifugal or baiiied tower scrubbers.   These
curves present  emissions  for various scrubbers'
water-ga's ratios and aggregate fines  rates.  Emis-
sion predictions from  these curves are accurate
onlyfor plants of the type and desiyn already dis-
cussed.
The operation of  the rotary drier is also an im-
portant variable. Oust emissions increase with ar.
increase of air mass velocity through the drier,
Obviously then, care should be taken to operate the
drier without a great amount of excess air.   This
care effects fuel economy and reduces dust emis-
sions from the drier.

The firing rate of the drier is determined by the
amount of moisture in the aggregate and by the re-
quired hot aggregate temperature.   The greater
the aggregate moisture content,  the  greater the
firing rate and the resulting dust emissions to the
atmosphere. In some plants, the increase in mois-
ture content of the flue gases may increase the ef-
ficiency  of  the  scrubber sufficiently to offset the
increase in  dust emissions from the drier.

Scrubber efficiencies  also  vary according to the
degree of precleaning  done  fay the  primary dust
collector.  Tests (suchas those presented  in Table
95) have shown  that overall efficiency of the  pre-
                                                D-9

-------
332
MECHAOTCA.L EQUIPME?>TT
                                                            SO
        1    4   8    9   10    12    14   16    !J   20
            SC&UIBEB MTIR-eAS S*TI8. jll/I.QOD at
         226, Effect of  scrutator,!* vatcr-gas-ratta-on
   stacfc emissions at average aggrepte  fines  feed rate
   in the drier feed {Ingels et al., I36Q).
cleaner and final collector varies only slightly with
large variations in orecieaner  efficiency.  Plants
with less effective cyclone precleaning had, on the
average, larger particles entering the scrubber,
and  consequently,  show greater scrubber collec-
tion efficiencies.   The  principal  advantage of an
efficient precleaner is that the  valuable fines col-
lected can be discharged directly to the hot elevator
£or use in the paving mix.  Furthermore, leas dust
is discharged to the scrubber, where more trouble-
some dust disposal problems are encountered.


ColUetton Effici«nd«s Attoin«d

Collection efficiencies of cyclonic-type precleanera
vary from approximately  70  to  90 percent OR an
overall weight basis.  Scrubber efficiencies vary-
ing from 35 to nearly 100 percent have been found.
Overall  collection efficiencies usually vary between
95 and 100 percent.
                                                  D-10
                     0	.	-	
                      0        i. ODD       M30       (2.000      13,'M
                       (KJMfflTT OF FINES (MINUS 200 ffiSH) Iff OHTQ FEED. itLlr
                 Figure 227.  Emission prsflictiort  curves  for multiple cantrifuffl!
                 ssrubtiers serving aspnaltic concrete plants (Ingels at al..  i960?

-------
                                  Hot-Mix Asphalt Paving Batch Plants
                                                                           333
                                                    =  40
   10
              4. QUO
           	       10
,000       12.300      18,000       a         4.000
(HJAMTIH OF FINIS (MINUS 200 M6SH) IN DRYfft Fltfl. IS/hr
                                                                             3,000
IZ.QOO
16,300
                Figure 22S, Emission prediction curves  for baffled  tower scrutoers serving asphaltic
                concrete plants ([ngsls et al.,  1980).
Collection efficiencies  of  a, simple cyclone and a.
multiple cyclone  for  various particle sizes are
shown in Table 96.  Multiple cyclones achieve high
efficiencies for particle sizes down to 3 microns,
whereas single cyclones  are very inefficient. Cor
particle sizes below20 microns.  The particle size
data from this table are plotted on log-probability
paper in Figure 229.   TTiis figure  also shows the
particle size distribution  of the scrubber outlet.
Other data on this installation have already been
presented  in Figure 222, test C-537.
                              Fuiurt  Tr»nds in  Air Pollution Control  Equipment

                             The air pollution control equipment discussed in
                             this  section  has  been adequate in Che  past  for
                             controlling dust emissions  from'hoc-mix aspnalt-
                             paving batch plants in Los Angeles  County,   How-
                             ever, new regulations on dust emissions, adopted
                             in January 19?2, now require that more efficient
                             devices than wet collectors be used as final col-
                             lectors.   The batch plants are  now  converting
                             from scrubbers  to baghouses.
                 Table 96,  COLLECTION EFFICIENCY DATA FOR A CYCLONE AND
                    A MULTIPLE CYCLONE SERVING A HOT-MIX PAVING PLANT
Dust
particle
size, ji

0 to 5
5 to 10
10 to 20
20 to 50
10+
Dust loading
ib/hr
Test C-S37
cyclone
Inlet,
%
6.2
9.4
13. S
22. 9
47. 7
5, 463
Outlet,
%
19. 3
31.9
31.6
15, 1
2. 1
Efficiency,
%
13. 3
5.4
36. 1
31.6
98.3
1, 325 | 72. 1%
Test C-537*
multiple cyclone
Inlet,
%
19.3
31.9
31.6
15. 1
2. I
1,325
Outlet,
%
37. 0
34.0
3.3
9.2

113. 3
Efficiency,
m
t"
77. 1
91. 7
97.3
no_ a
100. 0
91. '!«•>
                See Table 94, test C-337 for plant operating data.

                                                 D-ll
                                                                        o
                                                                        1—I
                                                                         I

                                                                         LU
                                                                        ' _J
                                                                         BQ
                                                                                                  Q
                                                                                                  LLJ
                                                                                                  <
                                                                                                  I—
                                                                                                  <

-------
334
                                  MECHANICAL EQUIPMENT
   o.ai
                                  10    20   JO  40  SO  3Q  70   10    30   95
                                  ?I8CIHT LESS TMN GtVIN MUTJCtE Sill, flierwi
                 Figure 229. Plot of particle size of oust at the inlet and outlet of a cyclone and
                 multiple cyclone front test C-53T.
      CONCRETE-BATCHING  PLANTS

Concrete-batching plants store, convey, measure,
and discharge fche ingredients tor making concrete
to mixing or transportation equipment.  One type
is used to charge  sand, aggregate,  cement, and
water to transit-mix trucks, which mix the  batch
«n route to the site  where the concrete is  to be
poured; this operation is known as  "wet batching. "
Another  type is used to charge the sand,  aggre-
gate,  and cement to flat bed trucks, which trans-
port the batch to paving machines where water is
added and  mixing takes place; this  operation  is
known as "dry batching."  A  third type employs
the use of a central mix plant, from which wet con-
crete is delivered to the  pouring site in open dump
trucks.

WET-CONCRfTE-BATCHING  PUNTS
to a typical wet-concrete -batching plant, sand and
           are elevated by belt conveyor or ciain
shell crane, or bucket elevator to overhead storage
bins. Cement from bottom-discharge hopper trucks
is conveyed to an elevated storage silo.  Sand and
aggregates  for a batch are weighed  by successive
additions from the overhead bias to a weigh hopper.
Cement is deliveredhy a screw conveyor from the
silo to a separate weigh hopper,  The weighed ag-
gregates and cement are dropped into a gathering
hopper  and flow into  the receiving hopper to the
transit-mix truck.'  At the same time,  the required
amount o£water is injected int" the flowiiig stream
ot solids.   Details  and varik-«.iQtis of this generalN
procedure will be discussed later.
TSi* Air Pollution
Dust, the air contaminant from wet-concrete-batch-
ing, results from the material used.  Sand and ag-
gregates for concrete  piodiiction came directly
from a rock and gravel plant where they are washed,
to remove silt and clay-like minerals.  They thus
                                               B-12

-------
                        APPENDIX E
                       BEFEREUGE 23




(not used in the development candidate emission factors)
                             £-1

-------
      NTRQPY
      IMVIRONMENTAUSTS, INC •            A
                                                           IN
                  SOURCE SAMPLING REPORT
               EXPERIMENTAL ASPHALT CONCRETE
                  RECYCLING PLANT IN IOWA
                        68-01-3172
                      OCTOBER  1976

P. Q. Sax 1S2S1, Research Triangle Park, Ncrsh Carolina 277G9
                   Phone S1S-7S1-355Q
                           E-2

-------
                        INTRODUCTION

    The asphalt concrete industry and state transportation
agencies are looking at the feasibility of recycling old
asphalt pavement in modified drum-mix drier plants.  One such
experimental plant located in Kosuth County, Iowa, has concerned
the Iowa Department of Environmental Quality, due to previous
observation of excessive visible emissions from a similarly operated
plant.  EPA Region VII was requested by the Iowa DEQ for technical
assistance to determine if the plant was complying with the
state- air pollution regulations.
    As part of its continuing study of new asphalt concrete
technology trends and their impact on the Federal New Source
Performance Standards, the Division of Stationary Source
Enforcement of EPA agreed to provide assistance to the Iowa
DEQ.  "••
    Source sampling was performed at the Everds Brothers, Lie.
asphalt recycling plant located near Titonka, Iowa, on two
separate occasions, under three different plant operating con-
ditions.
    Briefly, the first two conditions involved changes in the
location of the recycled material injection.  Only one set of
simultaneous particulate tests at the inlet and outlet of the
wet scrubber control equipment was made on September 29, 1976,
because of problems encountered with the conveyor equipment used
to introduce the recycled material midway in the drier.  Three
sets of simultaneous inlet-outlet particulate tests and one set
of particle sizing tests were made on September 30 and October
                            1-3

-------
1, 1976 (after process changes were made to feed all of the
recycled asphalt material into the drier at the elevated end,
along with the virgin material).  In addition to the par-
ticulate tests, air samples "before and after the scrubber were
taken for a hydrocarbon analysis.
    The last condition constituted a change in the type and
rate of production of asphalt mix produced and an increase in
the rotary drier's angle of elevation.  The asphalt mix was
changed from 66% recycled/34% gravel at a production rate of
18S to 204 tons per hour to 701 recycled/301 limestone at 245
to 2SO tons per hour, while the drier slope was increased from
2° to 2,98°  Three particulate tests were run at the separator
outlet on October 6, 1976;  three venturi-scrubber inlet
particulate tests were performed on October 7, 1976 along with
a set of inlet-outlet particle sizing tests.
    During all the testing, water samples were taken at the
scrubber water pump inlet and at the separator water discharge
for a water analysis.
    Present during the testing were Ronald Kolpa of the Iowa
Department of Environmental Quality and Robert Farnhan and Lee
3inz from Barber-Greene Company, the manufacturers of the plan-
facility.
    The measurements made for stack gas flow rates and partial
emissions were made according to the Iowa Department of Eaviroi
mental Quality's recommendations and generally followed the U.>
Environmental Protection Agency's requirements.  Due to the
sampling problem of plugging filters encountered during the ?re^
vious tests, a modified Method 3 sampling train was used in an
                        E-4

-------
attempt to alleviate the problem.
    Following sections of this report treat the summary of
results, a brief descrition of the process and its operation,
and the sampling and.analytical procedures used.
                       E-5

-------
                      SUMMARY OF  RESULTS

     The results  of the particulate testing program  are
summarized  and presented below in  Table 1.  The values used in
computing the  averages presented below were reasonably consists
considering the nature o£ the  process and the control equipment.
                            Table 1
             AVERAGE PARTICULATE CONCENTRATIONS
                          grains/dscf
                Venturi Inlet
"Seoaratar Cutlet
uperaciiig
Conditions*
#
1
2
3
EPA S
Only
2.04
S.35
CNA
ImDingers
2,35
S.-S4
20.67
Test
Set #
1
2-4
1-3
EPA S
Only.
0.22
0.43
DMA
EPA S *
IntDingers
0.31
0.57
0.88
Corresponl
Table ?'s|
2-3
4-3
a-?
*  See "Process Description and Operation" for details

     Table.s  2-7_,,. as no-ted above, -are summations" of t"h~e~
individual  test results from  the  particuiate testing.   Since
a modified  Method 3 sampling  train was used in making  the inlet-
outlet tests during the third operating  condition,  no* ""EPA
5"results are available - a Method 8 train eliminates  the filter
between  the  probe and the water-filled impingers.   For this
reason,  only "EPA * Ispinger" results are presented  in Tables
6 and 7, and in Table 1, under condition  3.  Flow rate  dctermina-
cion.s 1*01'  clio .scrubber outlet stuck appear to be  higher than real
hnr.ovt *JU (:!ui c;i i cu I .'i rcni vnn r.u r i - ncruhiH: c iuiot. f* I DW  r:»i-<:.   Tlic,
hiuluM' ViiSiio 1 r. |i I'lihiili I / 'I i >f  ('= nnn • \>n t'n ( I « I  l'|(»w  in  Hi"  -.1 m-r.
                           E-6

-------
(most probably tangential).   Generally, the results would be lower
than real due to sampling over isokinetically; however, due to
the extremely small particle sizes as acted below, there  probably
was a negligible effect.
    Results of the particle sizing tests on conditions two and
three are given in Tables 8-11; no particle sizings were made
under the first operating condition of the plant.  During the
second and third conditions, the aerodynamic diameter of 301
of the particles was less than the following sizes - second con-
dition:  inlet, S.5 microns; outlet, 0.43 microns; third condition
inlet, 991 greater than 10 microns; outlet,7.1 microns.
     Analysis for gaseous hydrocarbons on the air samples taken fr
the venturi inlet and scrubber outlet during condition two results
in values for the .inlet only.  The.outlet bag samples  developed
a leak during shipment, resulting  in dilutions and  lower  figures.
By -assuming the amount  of carbon monoxide to be  constant  from
the venturi inlet to the  scrubber  outlet, the total hydrocarbon
content  reported at the outlet was  recalculated  and found  to be
approximately the same  as at  the inlet.  The  inlet data  was
reported as follows:  total hydrocarbons, 468 parts per  million;
methane,  18 parts per million; carbon  monoxide,  2065  parts  per
million.  On the total  hydrocarbon measurement,  an apparently
very  heavy hydrocarbon  was  present  since the relative decay of
a portion of the total  was  very  slow.   If heated lines were used
to bring the sample from  the  stack directly  into the  instrument,
the total hydrocarbon results  might  have been much higher.

-------
     Analysis of the water samples resulted in the values
reported in Table 12.  Because the analytical method used
in determining the dissolved solids is designed for concen-
trations lower than those found, the results for the dissolved
solids are questionable.
     No visible emissions data was taken because of the nature
of the steam dissipation in the plume.  In general, however,
the opacity was noted to be approximately 2S-3QS.
                          E-8

-------
 APPENDIX F
REFERENCE 26
     F-l

-------
                              UJ. DEPARTMENT OF COMMERCE
                              Haticnii Technical information Service

                              PS-293 923
Fine Particle Emissions from Stationary
and Miscellaneous Sources in the
South  Coast Air Basin. Final Report

KVB, Inc, Tustin, CA
California State Mr Resources Board, Sacramento


Feb 79
                      F-2

-------
TABLE 4-1,
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i   t
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512
4sa
14
99.5
|38
9,1
122
7?
99
9tt
ua
119

BU
103
91

124


i

54.2
22.1
61.7
26.4
36
3.4 i
?.S|»
20.2
2.6

11.2
S.S
17.0

10.0


W|»
ClClOM

630.8
79.. 5
256. J
36.8
26B.P
36.7
-
3.4 *
5. On*
14.6
2.7

a.4
3.6
26. 5

126.2


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143.6
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149.|
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126.9
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277.'
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124.4
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146.7


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160.5
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20.9
390.9
139,1
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nTa
1014.4
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24.1
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63
41. 6
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-------
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476
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411
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247
247
5248

5966


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6.17
8. 11

2.1
2.1
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202.5
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272
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8716

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0.0896
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1.128
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1.210
1.149
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1.071
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1.J6

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0.0998
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0.042
O.O77
0.549
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0.0431
0.0184

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l&fo*%_


SsP-
44.5
6.0
7.1
^1:?-
60.9
4.0
11.7
1213.7
10.4
ifl-j
11.9
148.2
11.4
..Bl.l
22.7


24. B
55.4
3.9
4.2
IB. 2
4.S
13.0
19.9
1.5
S.I


11?, 1
57.2
eu^.s
61,3
P"!!

W.fc
39.9
152.3
43.0
JU60.1
1999.7
173.5
1113.8

109.1
135. 6
JB54.0
201.2
2217.4

252.4
1070.:
UI

-------
                                                        TABU2 j-\  (coot»4.)
I   ^
*-"  i-l
*-  s
   U)
   m
   o
   a\
   03


27S
27J
31S
31J
17S
IW
19S
194

30S
304
30 |5
39S
39J

40S
4IS
rt~«
MCtfl

9HOO
91400
m.40^
»5,40,
10948
1690|
46B8
1979

4179
4206
4384
*546
6703

16216
11399
f»«ft

Air
All
Air
Air
20,9
20.9
Air
Air

Air
Air
Air
Air
Air

3.9
0.9
€»

—
—
--
—
..
—
—
—

__
--
—
—
-.1


10.7
Ttt-

193
«9
240
240
240
5*
193
195

192.3
120
70
240
120

240
240
CKHIMlUfl
?»••

4000
4000
27SO
2750
8736
B736
2000
2000

2080
2080
2000
2000
20UO

B736
8400

«t/0SC7 1 t/J"if
OMCAH1C t
0.00171
0.0032S
Q. 00241
0.002U2
0.0237
0.610S
O.002ttC
0.7154
5,9
5.1
6.9
7-8
CHE
9.74
389
a. i
12.2
Ib/lw
OM/PH
2.«
2.56
5.0
S.7
HICAU
2.33
88,7
o.u
12.16
ID/mM(U
• usp:
HIV
HA
MA
m

—
—
_.
HOOD PMOCeSSIIIG
O.O022
0.0168
0.931
O. 00311
0.366
0.1
0.6
16. 5
0.2
21
0. 070
0.601
35. OS
0.3
20.0
PCfKOLUIH
a. 00424
0.055
2.6
>2.33
O.S9
14.84
HA
HA
NA
—
--

O.0062
—
*• c*n at f«rtl
'^OJi

n

s
&
10
IS
4
98.6

Q
37
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60
99

4.S
62
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S
IH
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'3
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1
3
P.2

3
4
_.
11
0.3

2
5
l-tp

5
15
3
8
0.5
0
1
0

3
12
__
9
0.3

1.5
5

< III

19

to
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«»*
Af
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1.2

86
36
—
20
0.7

91
52
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tw

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Mane
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97 $
97. &
99. |
99.1

96.3

M 98.4
« «»•«
99.0


Hot Test






pmit
tnlat
Exit
Inlet

Bayhouso
En It
laQhouae It
at, Cycloi
tjsli
:yclona
Inlot
Cyclone
Outlet
Cycloii;
Inlet '


ed


-------
 4.2.12 ' Asphaltic_Cencrete  Batch Plants,
 A.    •   Process  Description (Ref.  4-20  & 4-21)—
         Plants produce  finished asphaltic concrete through either batch or
 continuous  aggregate  mixing operations.   Different applications of asphaltic
 concrete require different  aggregate size distributions,  so that the raw
 aggregates  are crushed  and  screened  at  the quarries.   The coarse aggregate
 usually consists of crushed stone  and gravel,  but waste materials,  such as
 slag from steel  mills or  crushed glass,  can be used as raw material.
         As  processing1 for either type of operation (batch or continuous)
 begins,  the aggregate is  hauled from the storage piles and placed in the
 appropriate hoppers of  the  cold-feed unit.  The material  is tnetered from the
 hoppers  onto a conveyor belt and is  transported into  a gas or oil-fired rotary
 dryer.
         As  it leaves  the  dryer,  the  hot  material drops into a bucket elevator
 and is  transferred  to a set of  vibrating screens where it is classified by
 size into as many as  four different  grades.  At this  point it enters the
'mixing  operation.
         In  a batch  plant, which was  the  type tested in this program, the
 classified  aggregate  drops  into one  of the four large bins.   After all  the
 material is weighed out,  the sized aggregates  are dropped into a mixer  and
 mixed dry for about 30  seconds.  The asphalt,  which is a  solid at ambient
 temperatures, is  pumped from heated  storage  tanks,  weighed,  and then injected
 into the mixer.   The  hot, mixed batch is then  dropped into a truck  and  haulec
 to  the  job  site.  Figure  4-48   illustrates  a  batch plant similar to the one
 tested and  indicates  the  location  of particulate sources  in the operation,
 There are many sources  of fugitive particulate emissions  as shown in the
 sketch.   In this  program  the ducted  emissions  controlle _  by a baghouse.were
 characterized,. as were  .the  partially controlled emissions entering the
 baghouse.
                                       4-160                     K7B 5306-783
                                        F-15

-------

                                                          atation
                                                          SASS train
                                Sampling  station
                                Joy train

                            Primary dust
                               collector
                               cyclone
                                                                        Exhaust to
                                                                        atmosphere
   Coarse
  aggregate
storage pile
    fine
  aggregate
storage pile
  Feeders
                                                                  Weigh hopper
                                                                  mixer
           Conveyor
 Figure 4-48,   Batch hot-mix asphalt plant.   "P" denotes particulate emission points.

                                                                            KVB 5806-783

-------
B.      Participate Test Set-up—
        Two trains were used simultaneously to  sample  the  inlet and outlet
of the baghouse.  The inlet station was located on the vertical duct
approximately 12  ft ahead of the bend entering  the haghouse.  The  velocity
profile of the inlet duct was taken through the three  3" diameter  ports
provided.  The velocity profile in the inlet and exit  ducts of the baghouse
are listed in Table 4-58-
        The outlet sample station was located on the horizontal section of
the duct about, eight ft upstream of the fan.  In the interest of the safety
of the crew, the  velocities were not taken through the vertical port.  There-
fore Velocity Points 10 through 15 were obtained by swinging the pitot tube.
A 7/16"' nozzle was used at Velocity Point #3 on the outlet duct and a 5/16"
nozzle was used at Point #3 of the inlet duct.
C.
Partictilate Test Results—
        The results of the two tests (Test 29S and 29J) discussed in this
section are listed in Table  4-1.    Elemental composition, sulfate, nitrate,
and carbon analysis were determined for all fractions of parciculate catches
which contained weights in excess of 100 Big,  The details for these procedures
are discussed in Section 3.2.2.  Due to the very heavy loading on the inlet
side of the baghouse, the cyclones aad filter in the small sampling train had
filled to total capacity and caused a pressure drop during sampling which
resulted in stopping the sampling.
D.
Discussion of Test Results—
    1,  Efficiency, of the, baqhouse-~qsing the solid satch data (i.e. without
the impinger catch)  from both sampling trains for the inlet and exit, the
baghouse efficiency was calculated to be 99.95%.  Using the total catch,
the efficiency would, be 99.92%.
    2.  Partiele_ slate distribution—Figure  4-49  is a plot of particle size
(Uffl)  vs accumulated weight percent, the latter plotted on 3 probability scala
as explained in Section 3.2.3 B.  Two sets of curves are presented, one
including the iaspinger catch, the other ignoring it.  Considering the large
amount of material collected upstream of the filter, it would seem that the
                                       4-1.62
                                                                IC7B 5SQ6-783
                             F-17

-------
TABLE  4^38.,   VELOCITY PBOFILE—ASPHALT  BATCH  PLAMT (TEST 29)
r
/

1 4 1 U
***JLia*««J_
niae 	 ~P"« — .,.1-,
jrt»" w**i«' ^^D ' li
S«"
2 fr ID
P- 1 s *
M?:ir ~ /«
1- poet
}"M« IS* - ^ ( 2* *»«P
Inl«t to a*9botts«
rw«*mun> iso*r
SMU.C FT»»«UT«l -4.J- IQ
itstance from Velocity Velocity
ad of Port Point * ft/sec
8" 1 30.2
20" 2. 30.2
32" 3 34.1
44" 4 37.2
8" " 5 31.9
~~ 20" '~ ., S. ""36^7
32" 7 38.2
44" 8 41. 8
8" 9 37.2
20" 10 34.1
32" 11 28.9
44" 12 28.3
Average: 34.1 ft/sec
75337 scf
^~ 	 *^
toopJU l>ouit ^ ^^. m
1/16' na«i«X -X^k X
f\^\ \ "
l/\ in \
\\ j(y< KJS * IB
r yore. i >< " / J
r M* N^^^ N. 14 / /
Outl«t of u^nou**
T«p«t»t.ux«i 160*7
StBCle l»r»»»ur«: -ll*M.O
Distance from Velocity velocity
Ead of fort Point t ft/sec
5" 1 53.8
9-3/8" 2 76.3
14-5/8" 3 35.3
22-3/8" 4 85.3
33" R ' 95.4
43-5/8" ~*~ 	 V ""95.4"
51-3/8" 6 85.3
56-5/8" 7 85.3
61" 8 81.0
37" 10 95,4
35" 11 ai.O
34" 12 89. S
34" 13 85. 3
•35" 14 73.9
37" IS 68.8
Average? 84.6 ft/sec
75354 scf
                          F-18
                                                         KVB 3806-783

-------
0.01   0,1  0,5 1  2    5   10  20 30 40506070  80   iO   95   98  99  99.3   99.39
                   WEIGHT, PESCEOT LESS THAN STATED SI2E
          Joy Mfg. Sampling Train with Impinger

          Joy Mfg. Sampling Train Without  Inspinger

          SASS Train With Impinfer

          SASS Train Without laipinger


        Figure  4-49.   Particle size distribution for asphaltic concrete
                       batch plant  (Test 29)
                                4-164
                                                                 KVB 5306-"S3
                                F-19

-------
 effects  of pseudo  particulates would be insignificant.   Therefore, the
Stinger catch, was believed to be properly included in the measurements of
 the suspended particulates  froa  asphaltic concrete plants.  As a result of
 the filling of the cyclones in the Joy train,  a particle size distribution
 curve could not be made.  It is  estimated from visual examinations that
 »he mean particle  size  for  the inlet is greater than lOOyn.  The breakdown
 cf the particle size  distribution for the baghouse outlet including the
         is as follows:
Controlled
Test 29S
0. 00 776
1.56
4.34
0.02
0.1
Uncontrolled
Test 29J
11.485
2079.9
5777. S
34
45
                                                                                  LU
                                                                                  to
                                        Percent of Particles
                        Greater than lOya     10-3van     3-lura     Less  than lym    f£
test 29S	60	6	4	30	
                                                                                  U
ae -mean particle size for the baghouse outlet is approximately SOya.             p:
                     f                                                            >—'
Although the baghouse has a high efficiency  some of the coarser particles
still penetrate, no doubt due to small leaks in and around the bags.
   3.  Chemicalcomposition of particulates—Table 4-59 lists  the  results
from the chemical analysis of the particulate fraction for the tests dis-
jsssed in this section.  Although silicon is not detected with XRF (sae
Action 3.2.2 B) , it  is. clear that silicon is the most abundant element in
these samples.  The unanalyzed portion of Table 4-59   is primarily SiO.  and
other compounds*- of silicon,
   4.  Enissicns and emission factors—Eg" gg jQ"g and  emission factors^ can —    • —
ie listed with several different units.  The following lists some of these
missions and-factors for these tests:
        Dnits
        gr/OSCF
        T/yr
        Ib/hr
        Us/ton produced
        li/ton produced (Ref.  4-22)
                                       4~163                     KVB 5306-733
                                         F-20

-------
TABLE 4-59.     CHEMICAL COMPOSITION OF PAKTICULATE SAMPLES
       IN  PERCENT FOR ASPHALT BATCH PLANTS  (TEST  29)
SAMPLE f
WT. PERCENT OF CUT
XRF ANALYSIS
Arsenic
Barium
Calcium
Chromium
Iron
Potassium
Silver
(Sulfur)
Titanium
TOTAL1
Sulla tes, H_0 sol2
(Sulfur, from SO4") "
Nitrate EH.,0 sol)2
lOym
Cyclone
29S-25
62.1

t
t
2.4/0.3
t
3.6/O.S
1.5/O.S
t
(<8)
t
8
2
It }
t
lOyn
Filter Cyclone
29S-5S 29J-2S
3.57 54.3


t
10/3 1.9/0
t
1/0.1 4.3/0
1.5/0

(<4) (<33
t t
11 8





.3

.5
.2





             2
 Total Carbon
    (Volatile Carbon)
    (Carbonates)3
• TOTAL ANALYZED
 BALANCE
                                    10
                                    90
                                   100%
11
39
100%
(t )
 8
92
100%
        d*t«et*4 in oooe«ntr»tian of <1%
        Analyzed fey x-ray fluor»»c«nee— Saetion 3.2,2 t
        «naly«5d by w*t eh*mi«try— Section 3.2.2 A
        «n*ly**d by Oe»MOqs»phy carton &nalyt«r— S«ct:±oft 3.2.2 A
2
3
4

5

( }
        ealeuiatml fsraa «ul£*tai  {iulfiit-««alf«a!/3>  co eoatp«r« with
        from XBF
        tor
                  stewn »« X/t, X i« % Of tfca «iea»nt pr«i«a«  and If is th«
        not inelaiad In tacai— aoifae *nd «ulfate* ar« mccomtad for in sulfur
        «T «nalyii» «nd volmtil*  esxbon uwl cKtoonat* ara «ceoun*od for In
        totii c*rbon
                                   4-166
                                  F-21
                                                                 KVB  5305-TS3

-------
 APPENDIX G
REFERENCE 27
       G-l

-------
          CHARACTERIZATION OF INHALABLE PARTICULATE MATTER EMISSIONS
                         FROM A DRUM-MIX ASPHALT PLANT
                                      by

                               Thomas M. "Walker
                                George R. Cobb
                                Hack D. Hansen
                                John S. Kinsey
                                   VOLUME  I

                                 FINAL REPORT
              Contract No. 68-02-3138, Technical Directive No.  8
                          HRI Project No.  4S91-L(84).

                               February  16,  1983
                                       For

                 Industrial Environmental Research, Laboratory
                        Environmental Protection Agency
                            Cincinnati,  Ohio  45268

                             Attn;   Mark Stutsraan
MIDWEST RESEARCH INSTITUTE  425 VOLKER BOULEVARD, KANSAS CITY, MISSOURI 64110 • 8t6 753-7600

                                       G-2

-------
and is deposited in a hopper located beneath  the  collector.  The  collected
dust is returned to the drum from the hopper using a. positive flow pneumatic
system.

2,2  FIGCESS OPERATION

     As an  integral part  of the field sampling program, data on the oper-
ation of the plant were obtained which characterized the various parameters
affecting the generation  of emissions.   Such data included the plant pro-
duction rate, the  raw material  throughput,  the asphalt  content  of the mix,
the ratio of  recycle  material  to total aggregate, and  the temperature  of
the hot mix and the effluent gas from the drum mixer.  This information was
collected in  the  form of  hard copy printouts from the computerized system
controlling plant  operation.   The printouts  were obtained approximately
every 30 m-in throughout each sampling period.   A summary of the process op-
erating data  collected  dtiring  the program  is presented in Table  2.2, and
photocopies of the original printouts are provided in Appendix S.

     During the period when testing was being conducted at the Bowen plant,
a number of different types of asphalt paving were  produced depending  on
individual customer requirements.  Each type of nix is designated according
to its job mix number, as  shown in Table 2.2.  The job mix number specifies
the type and  quantity of  aggregate and asphalt cement required to produce
a particular grade of asphalt paving.  In the process, the proper amount of
material from each of the cold feed bins (including the recycle feed bin)
is provided  to  supply aggregate  of the appropriate gradation.   Hot  asphalt
cement is also  metered  to the process according to the job mix specifica-
tions.  Allowances have been made in the job mix formula to account for
the asphalt content  of  the old asphalt concrete when recycled material is
used.

     Table 2,3 provides a summary of the job nix specifications available
for each type of paving produced by  the Bowen plant as a  function  of  the
aggregate gradation and asphalt content.
                                    7
                                   G~3

-------
TABLE  2:2.  SIjMMiRY OF PROCESS  OPESATI2TG DATA, AT SOFTEN .CONSTRUCTION COUP ANT
Baca
10/7/81



io/a/8ie
10/9/11













10/16/81

io/w/81












10/20/81










10/21/81






fiM
CM
13:30
14:00
1*8 32,
13:00
-
08:30
09: IS
10: CO
10:30
11:00
tl:30
12:00
12:30
13:00
13:30
14:00
14s30
13:00
12:30
10:30
11:03
08:00
08*30
09:00
09:30
10:00
10:30
11:00
12; 00
12:30
13:00
13:30
14:00
14:30
08:00
38:30
09:00
10:00
10:30
11:00
11:30
12:00
12:30
13:00
13:23
08:30
09: 13
09:45
10:15
11:13
12:00
12:30
Saw malarial . Secycl* uts-
throuttrout (tons/h) rial/ toe* I
Tatti Arpoait frotiaction jits Aapdalt content Job Biz afgrtfiu
a(jTej»« ce*«at {wiu/h) of "ti (vt. 2) So. (•)
362
316
314
322
-
309
309
311
316
304
312
306
300
322
174
249
243
233
-
237
262
255
«
274
27S
233
•-..243
226
213
233-
250
171
22S
21S
223
222
216
212
214
263
278
298
304
243
211
230
245
239
190
195
113
185
10.3
11. 1
11.2
10.9
-
10.9
10.3
t.S
8.s
J.I
8.8
9.1
$.0
10.4
11.4
9.2
S.8
8.3
7.2
13.7
8.9
8.?
-
8.7
8.6
!.i
S.6
5.3
9,4
3,3 	
3.2
8.3
7.o
11.7
7.9
7.7
11. i
7.1
6.6
8.6
».3
10.2
10.9
8.1
8.7
7.9
12.3
12. 4
9.3
9.8
10.3
10. 1
372
327
323
333
290
320
320
330
323
313
321
313
308
332
283
238
234
244
-
271
271
274
.
283
284
281
234
263
222
- -261
268
ISO
236
230
231
230
227
219
221
272
288
308
314
233
220
138
238
231
200
20S
193
195
4.56
4.64
4.64
4.61
-
4.33
4.7!
3.38
3.94
-
3.93
4.10
3.78
3.77
3.03
$.40
S.01
4.97
3.77
S.03
4.4$
4.41
.
4.37
4.49
4.33
4.37
4.33
4.20
— . - - 4, 63
4,33
4.54
5.17
4,95
4.53
4.6i
4.95
4.4J
4,6$
4.37
4.61
4.53
4.61
4.37
4.33
4.61
4.97
4.39
4.73
4.31
4.98
3.14
a
s
8
8
8
t
S
9
3
S
8
9
9
8
I
8
a
8
3
S
8
8
8
8
8
$
a
3
5
_j 	 	
a
3
a
s
s
$
5
3
5
3
8
S
8
S
a
8
6
0
6
0
k
4
28.2
30.4
29.0
30.7
-
30.4
29.4
29,9
29.4
29.3
30.8
30.4
28.3
29.8
3S.1
30.3
29.3
28.1
-
0
30.9
31.3
.
32.1
32.7
31.2
27.3
30.9
a
31.2
31.5
2.3
33.1
0
30.0
29.7
0
31.1
29.0
31.6
30.2
30.5
31. &
29.3
17.3
29.1
0
9
0
0
0
0
lot, oix
txie leaf.
CT)
320
293
292
303
-
304
307
287
308
305
307
301
306
296
298
297
291
311
288
301
239
293
.
298
297
298
Z60-
318
318
	 303-
307
299
302
311
312
317
307
307
316
306
316
293
293
314
307
236
197
296
302
313
314
314
Orftr its
axis. ifoa.
err
338
330
334
342
345
359
236
363
361
331
362
356
339
334
340
363
331
356
337
335
379
139
_
133
363
362
379
264
343
• 342 	
332
337
361
341
361
363
34e
34i
338
349
365
332
331
367
331
343
321
331
345
343
33S
335
                                     (continued)
                                         8
                                       G-4

-------
                                         TABLE  2.2.   (concluded)
Oat*
10/22/81









10/26/81











10/27/81







10/30/81










11/6/81




TIM
(B)
97:45
08<3Q
09:00
09:30
10:00
10:30
11:00
11:30
12:30
13:30
09:30
10:00
10:30
11:00
11:30
12:00
12:30
13:00
13:20
14:00
14:30
13:00
08:00
08:30
09:00
09:30
10:30
11:00
14:00
14:30
08:00
08 -.30
09:00
10:00
10:30
11:00
11:30
12:00
12:30
13:00
13:30
10:00
10:30
11:00
11:30
12:00
Saw >»i
EJsromirouc
Total
atirttaU
146
161
160
147
160
163
189
ISO
190
194
137
132
134
163
136
191
180
212
215
234
238
192
206
107
199
209
183
203
134
131
- 193
136
189
183
136
186
188
167
163
160
143
264
268
263
261
248
iMM/hr
Aspiult Production r»t«
cement (tra*/h)
7,9
9.0
8.8
8.1
8.8
8.8
10.3
9.9
10.3
10.4
8.1
7.9
8.1
8.4
8.0
10.0
9.8
11.0
11.7
12.2
12.9
12.4
10.9
11.1
11. 0
10.8
9.6
10.7
7.0
6.9
10.0
9.9
9. a
9.9
9.9
10.0
9.9
a. 7
a. 7
8.7
7.1
8.4
3.3
8.8
8.7
8.0
134
170
169
135
169
172
199
190
200
204
163
160
162
171
164
201
190
223
217
246
231
284
217
218
210
220
195
214
141
138
203
196
199
198
196
196
198
176
172
169
151
272
277
274
170
236
Recycle «•<*-
Aapbalt content Job six »jjref»e«
of adx (•*. 1} »o. (i)
3.18
S.14
5.14
5.14
3.14
5.10
4.94
5.14
S.10
5.10
S.03
5.03
4.93
4.99
4.99
$.07
5.03
4.99
4.39
4.99
$.03
5.19
4.99
5.03
4.99
4.93
5.19
4.83
4.93
4.93
5.81
4.98
3.01
4.98
4.93
4.S5
4, as
4.83
5.01
4.98
5.06
4.21
4,45
4.43
4.42
4.43
4
4
4
4
4
4
4
4
4
4
5
3
5
5
5
5
S
5
5
3
5
5
5
5
S
• 5
5
$
5
5
3
5
S
5
5
5
3
5
S
5
2
10
10
10
IS
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 "
0
0
0
0
0
0
0
0
0
0
0
0
9
0
0
0
0
0
0
0
0
3
0
0
0
29.9
20.2
29.8
29.9
30.6
lot ai*
•sic top.
323
326
313
333
331
32S
315
324
320
323
327
318
315
317
322
309
334
324
332
307
323
329
339
340
335
329
341
332
127
344
337
330
316
333
323
313
333
342
330
323
332
308
303
309
310
312
3ryer gaa
340
343
334
345
341
333
333
35?
329
333
333
336
348
336
3*3
330
332
353
363
337
337
374
373
362
366
363
371
338
339
346
341
343
331
348
235
361
339
331
347
333
342
367
372
378
360
334
*  fatal iggrtifica a virgin uttcial * rtcyelad Mpiu.lt p*7eaett.
   Me»»ured 
-------
                                         TABLE 2.3.  JOB HIX SPECIFICATIONS
o


Coarne aggregate
Jab mix Na. (% > 8 mesh)*
4 36.5
5 47.8
6 47.8
8C 45.8
Aggregate gradation
Fine aggregate Mineral filler
(% < 8 mesh) (.% < 200 meah)a
63.5 3.6
52.2 3.4
52.2 4.0
54.2 5.9

Asphalt content .
of mix (% weiglit)
5.2
5.0
4.9
4.9
9 Not Available
10C 54.6
45,4 5.7
5.1

           lY-rt:ent  of total aggregate.




           Percent  of total mix.




           Includes recycled asphalt paving.

-------
     It should be noted  that  the mineral  filler content shown la Table 2.4
is that percent of the total aggregate (or recycle) below 200 mesh which is
indigenous to the material  itself  aad  should aot be misinterpreted  as  sup-
plementary mineral filler added to the aggregate.

     la addition to collecting process data, samples of both the virgin ag-
gregate and the  recycled asphalt concrete being used as raw material were
collected.  These samples were taken front the appropriate belt conveyor just
prior to being transferred into the drum mixer.  The samples were stored in
polyethylene bottles  in  the field  for  transport back to the  laboratory for
analysis.   These  samples were then analyzed gravimetrically for surface
moisture.   The virgin material dried in a- laboratory oven at 110°C for 24 h;
and the recycle-  material at HO°C for 1.5  h.   The raw  data  sheets  of  the
moisture analyses are  contained  in Appendix C.  The aggregate and recycle
samples were then graded according to size  by dry sieving using standard
MSHTO test methods.   Since MRI's  nest of sieves does not contain a tfo. 8
screen, which is the  cutoff between coarse  and fine aggregate, the  percent
in each of  these ranges  was obtained through a linear regression analysis
of the entire aggregate  size  distribution.   Again,  it should .be  noted  that
the mineral filler content  is  that which  is  indigenous  to the material  it-
self and not added to the mix.  The results of  the  raw material analyses are
provided-in Table 2.4.  The raw data of the dry sieve and moisture analyses
are provided in Appendix D.   Also contained in  this appendix are the graphs
plotted to  determine  the cut point, between  coarse aad fine aggregate.

     Included in  the data collected during  the sampling program was  an
analysis of the asphalt cement used by Bowen in their process.  This cement.
was a standard 60-70 paving asphalt manufactured by the Amoco Oil Company at
their refinery in Sugar Creek, Missouri.   An analysis of the asphalt cement
is contained  in Table 2.5.   This  information was supplied by Amoco Oil
Company.
                                    11
                                    G-7

-------
                                              TABLE 2.4.  SU1WARY OP RAH MATERIAL ANALYSES
Q
i
GO
Date
collected
10/7/tl

10/9/81



10/19/81

10/20/ftl



JO/21/81
IO/22/BI

10/26/81

IO/27/S1

10/30/8!
11/6/81

a
Tyiie of r
Ti«e "VlriTT"
00 aggregate
SoBI Run II X

SoHl Hun 13 X

15:30 x

13:30 X

OSilS X

13:30 X

09:00 X
08:30 X
12:00 X
1I;OU X
13:15 X
08:40 X
I4i20 X
08:50 X
IOsI5 X


aw iMterljll
Recycle! Coarse friction*
paving (J > a Hush)
44.3
X ?2.l
JJ.6
X 8). 3
£9.0
X 61.1
61.5
x n.i
65.2
X ?5.2
51.?
X 79.1
49. 5
24.4
28.3
41.0
49.1
53.3
57.3
59. a
72.1
X 66.8
~ . — -.—^ 	 .. 	 __..__
Fine fracUuu8
(1 < 8 «oal,)
55.1
27.3
22.4
12.?
31,0
38.9
38.5
25.3
34. a
24. B
42.3
20.9
50.5
75. 6
71.7
5'J.O
50. 9
46.7
42.7
40.2
27.9
31.2

Hlner.l filler*
(X < 200 «esh)
5.4
0.1
1.4
0.1
2.2
0.8
4.2
0.2
2.7
0.2
3.5
0.7
3.1
2.3
2.9
4.5
3.9
2.5
2.2
1.5
4.1
O.I

Surface auiature
(«t. t)
2.1
0.9
1.4
0.9
1.3
0.8
2.5
I.S
2.5
1.7
2.4
1.5
2.5
4.0
5.4
4.9
3.1
3.1
3.1
2.3
2.0
3.2

                         J'crccut of laid! material.

-------
             TABLE 2.5.  ANALYSIS OF ASPHALT CEMENT

Parameter
fenetratioa (at 77 °F)
Flash, point
Ductility (at 77 °F)
Solubility
Specific gravity
Specification
0.6-0.7 mm
450°F
100 on
99%
-
Test results
0.62 ran
615°F
150* cm
99.96%
1.035

Source:  Amoco Oil Company.
                             13
                             G-9

-------
3.3  SAMPLING FROC22UBIS

     The preliminary  inlet, and outlet test data taken prior to performing
the actual emission tests at the asphalt plant are contained in Appendix F.
The preliminary inlet data contain an attempted Hethod 17 run using 43 sam-
pling points (traversing 24 points per port).  However, only two points were
sampled because of  the  high  loading.  The  testing  strategy  decided upon  is
discussed in more detail in Section 3.3.2.  Also contained in Appendix F are
toe dry molecular weight determinations used in the final calculations,  The
dry molecular weight of the stack gas was determined daily at the  inlet and
outlet of the baghouse.

3.3.1  Pretest Prepargtipqa

3.3.1.1 "larticulate Hass—

     3-3,1.1.1  ETA Method 5 train—Four-inch diaaeter Type A/E (Gelman Sci-
ences, Inc.) glass  fiber  filters were used .for  particulate  collection sub-
strates in  the EPA  Method 5  train used  at  the baghouse  inlet.   The filters
were placed in numbered 4-3/4 in. diameter by 3/16 in. deap aluminum weighing
pans.  The filters and weighing pans were then placed, in a constant humidity
and temperature room for 24 h» after which each filter and its corresponding
numbered weighing pan were weighed on a Mettler Model AK 160 electronic bal-
ance to the nearest 0.1 mg.  The filters and weighing pans were again, equili-
brated for 6 h and weighed.  This procedure was repeated until two consecutive
weighings agreed within 1.0 rag.  The Method 5 filter tare weights  are  found
in Appendix G.  After completion of weighings, the filters were placed in
plastic petri dishes for transport to the test site.

                                   23
                                  G-10

-------
     Two-hundred and  fifty milliliter  capacity glass  beakers  were used for
recovery of mass  train samples.  The beakers were first washed ia Alconox
detergent and  the  rinsed with tap water.  After the beakers were numbered
with a  lead pencil on the etched surface  of the beaker,  they were rinsed
with distilled water.  The beakers were then heated in an oven to 500°F for
1 h to burn off any organic material present.  The beakers were transferred
using beaker tongs to an equilibration, room and equilibrated for 24 h.  The
beakers were then  weighed on a Mettler Model AK 160 electronic balance to
the nearest 0.1 ing.   The beakers were equilibrated  for  6 h and then  re-
weigned.  This procedure was repeated until two consecutive weighings  agreed
within 1.0 mg.   Tare weights for 250 ml beakers are presented ia Appendix G.
After completion of  weighing,  the beakers were placed in sterile plastic
Whirl-Pak containers and put into their original box for shipping.

     3.3-1.1.2  SPA Method 17 train—Gelman  type A/E 47-tam diameter glass
fiber filters  were used  for particulata collection  substrates  in the  EPA
Method 17 train used  at  the baghouse outlet  location.   The filters were
placed in numbered 57-ona .diameter aluminum weighing pans.  The equilibration
and weighing procedures  used on these  filters  were identical  to the proce-
dures used for the EPA Method 5 filters.  Method 17 filter tare weights are
presented" ..in Appendix  G.  Plastic petri dishes were used as shipping  con-
tainers .

     One-hundred and  fifty milliliter  capacity glass  beakers  were used far
recovery of EPA Hethod 17 samples.  The beakers were cleaned, equilibrated,
and weighed according to the procedures described above for the EPA Jletaad 5
beakers.  Tare weights for  the  ISO-mi  beakers  are presented in Appendix G.
These beakers  were transported  in sterile plastic  Wuirl-Pak containers.

3.3.1.2  Particle Size—

     3.3.1.2.1    Andersen high capacity stack sanroler_with 15_-ua preseg-
arator—The entire Andersen HCSS iarpactor and  15-ym preseparator systea and
nozzles were washed ia detergent and rinsed with, tap water, distilled  water,
and acetone.  The  acceleration and vent tubes were cleaned with a high pres-
sure air stream.
                                   24
                                  G-ll

-------
     A 1-1/2 in. diameter by 4-3/4 in. long aluminum tube was used as a con-
tainer for each, glass  fiber thimble  filter.   The  aluminum  tube  also  served
as a weighing container.  The thimble filter  and aluminum tube were prepared
for field use as follows:

          Aluminum tubes were numbered with an engraver.

          Aluminum tubes and lids were washed in Alconox detergent.

     *    Aluminum tubes  and  lids were first rinsed  with  tap water,  then
          with deionized, distilled water.

          Aluminum tubes  and  lids were heated in an oven to  500°F for 1  h
          to remove any potential organic contaminants.  After heating, the
          aluminum tubes were handled only with beaker tongs.  The aluminum
          lids were handled with latex surgical  gloves  since they were  not
          weighed.

          The aluminum tubes and  lids were removed from the oven  and allowed
          to cool.

          "A thimble filter was placed in each container.
          The thimble  filter and aluminum tube  were  placed in a constant
          humidity  room for  24  h  at ambient  temper a cure and pressure.

          The aluminum  tube  and  thimble filter were weighed to the nearest
          0.1 gag on a Mettier Model AK  160 electronic balance.   The aluminum
          tube lid was not desiccated or weighed.

          The  aluminum tube and thimble  filter were  desiccated for  6  tu

          The aluminum  tube  and  thimble filter were weighed a second time.
                                    25
                                   G-12

-------
     '    Weighings were  repeated  until  two consecutive weighings  agreed
          within. 1.0 mg,

     *    The lid was placed on the aluminum tube.

     *    Aluminum tubes were wrapped in aluminum foil and placed in plastic
          Whirl-Paks for shipment.

     Aluminum weighing  pans  57  am  in, diameter and 20 mm deep were used in
recovering samples  from the  first  four impactor  stages.  Each weighing pan
was numbered with  a metal engraver.  The aluminum weighing pans were  then
desiccated and weighed  according  to 'the procedures  used for the aluminum
tubes and thimble filters.  The aluminum weighing pans were placed in  100 mm
diameter by 20 mm  deep  plastic  petri dishes used as shipping containers.
Thimble filter and  aluminum  weighing pan tare weights can be found in Ap-
pendix G.

     3.3.1.2.2    Andersen Mark III lapactor with15-ym preseoarator—Ten
3-in. aluminum foil squares  were  cut to serve as holders  for each  filter
set.  The aluminum  foil squares were folded in half, labeled, and the ap-
propriate . glass  fiber filter substrate (Andersen 2000) placed iaside.   the
equilibration and weighing procedures used were as follows:

          The,filter  sets were  equilibrated in  a constant humidity room
          for 24 h.

          The filter and  its aluminum foil holder were weighed  on  a  Cahn
          Instruments Model  27  eleetrobalance  to the  nearest   0.01 tug.

          The filter sets were equilibrated for another 6 h.

          The filters were weighed a second tine.
                                   26
                                   G-13

-------
          The equilibrmtioa and weighing procedures were repeated until two
          consecutive weighings agreed within. 0.05 ng.

     *    Each, complete  filter  set was placed in  a  glassine  envelope  for
          shipping.

     Andersen Hark III  impactor substrate  tare weights  are  found in  Appen-
dix 6.

3.3.2  Testing Strategy

     The Southern Research Institute "Procedure Manual for Inhalable Particu-
late Sampler Operation," Hovember 30» 1979, prepared for H&  (SoRI-EAS-79-761,
4181-37), was used to  determine most of  the  sampling criteria for both the
particle sizing  and mass tests.  Four  individual  sampling points were  used
rather than  a  standard traverse of the duct, except for the  inlet.   Also,
the criterion for isokinetic sampling was expanded to ± 20% rather than the
standard ± 10%.

3.3.2.1  Baghouse Inlet—
     According to the  procedures  manual cited above, the recommended sam-
pling points for circular and square or rectangular ducts can be determined
using Figure 3.7.  However, due to the duct configuration and the extremely
high loading at  the  inlet, it was decided to deviate from the recommended
sampling points for the  total mass tests.  Instead of sampling at one point
during a run, it was decided to traverse six points.  A traverse o£  the duct
was necessary to obtain  total mass data that would be unbiased by stratifica-
tion.  Six points were chosen because of the short sampling time dictated by
the high loading of the  inlet.  The particle sizing tests were conducted us-
ing normal inhalable particulate testing procedures.  (Refer  to Figure 3.2.)

3.3.2.2  Baghouse Outlet—
     The testing strategy used  in testing the outlet employed normal inhal-
able particulate testing procedures for both particle sizing 'and total mass
tests.
                                   G-14

-------
          r
         b/4
      __!___

Figure 3.7.   Rscomoended sampling points.

Source:   Southern Heseareh Inscicuta,
           "Procedure Manual for Irthaiabla
           Particuiate Sampler Operacior.,1'
           prepared for EPA, Soveuifaer  30,
           1979.  (SoRI-SAS-79-75i, iiSl-37)
                 G-15

-------
                                SECTION 4.0

                            SUMMARY OF BESUITS
     Results of  the  testing program at the Bo wen Con.stnict.ioa Company as-
phalt plant  are  summarized in this section.  The tabular and graphic pre-
sentations that  follow were derived from  reduction  of the  raw  field data
found in Appendix  I  and the laboratory and analytical data  found in Appen-
dix 5.  The raw data were  combined and  reduced by a  computer program devel-
oped by MRI  to produce the printouts  found in Appendix J.   The  information
contained in these computer printouts was used in the  construction of the
graphs and tables  in this  section.

     Only data that have met specific acceptance criteria are summarized  in
this section.  These criteria,  as  obtained from "Procedures Manual for  In-
halable Particulate  Sampler Operation," prepared by Southern Research In-
stitute for EJA, are:

     1.  Each total  mass and particle  sizing run must be within ± 20%  of
isokinetic.

     2.  The particulate  grain  Loading from  the total mass train  (EPA
Method 5 or  Method 17) and the  corresponding  particle size  train (Andersen
HCSS or Andersen Hark III with 15 M^  preseparator)  must be within ± 50%.

     The data that has net  this criteria is in Table 4.1.   Two total mass and
four particle sizing tests  consisting of four runs per  test (one  run per  quad-
rant on particle sizing) were conducted at the baghouse  inlet test site.  Two
total mass and two particle  sizing tests consisting  of  four runs  each (one run
per quadrant) were conducted at the baghouse  outlet  test site.
                                  G-16

-------
                       TABLE 4.1. SUIttAKY OF UACUOUSE INLET  AND OUTLET ACCEPfANCE  CRITERIA RESULTS
	 	 ™- 	 ~. - — — 	 .^»~.~,... 	 — 	 „, „_ — . .. n _
Yiiul Him Ho.
Ho. soitt't:i:~ruu-iju«t| Test date
itilel I'iirtlcle




2


3

a
i
•^ 4
-1-1(10
-1-2
- 1-3
-1-4
-2- lit)
-2-3
-2-4
-3-1
-3-2
-3-3
-3-4

-4-1
-4-2
-4-3
-4-4

(iutltl I'jillclt.
O-l-t(tt)
, 0-1-2
0-1-3
II- 1-4
0-2-1
, 0-2-2
0-2-3
0-2-4

a
Sizing Train
10/26/81
10/21/81
10/22/81
10/21/81
ii/o6/8i
10/22/81
10/26/81
IO/22/fll
10/27/Bi
10/26/81
10/27/81
10/26/81

10/30/81
10/27/BI
10/30/8 1
10/30/81

Sizing train
10/21/81
iu/1'j/ei
IO/20/B1
10/22/81
10/30/81
10/22/81
10/27/81
10/26/B1


I'itrl liul j| e
% loading
iBoklitetlc gr/ilscf*

94,9
93,2
95.1
101.6
89.7
96.0
99.1
III. 2
90.9
95.4
09.9
98.8

110,1
111.2
93.6
109. S


120.1
117.7
104.4
114.3
105,8
101.2
100. B
92, S



15.1
21.2
17.5
33.6
6.6
IB. 6
12.7
26.1
16. »
18. «
10,4
32.5

7.6
10.1
17.5
22.1


O.U298
0.0310
O.OIBB
0.0467
d.UV.H
0 , 040!)
0.0419

... »..,_. . . _.„ .
_k % fcuw Him Ma.

1-1 U-)
21.9 22
1-2

J-3
16.0 II
1-4

1-5
19.7 9
1-6(8)


I-J
14.3 20
1-8
* = 18.0

0-1-1
0-1-2
0 .0316 S 0-1-3
-------
 To further scrutinize the particle sizing data an average grain loading was
 determined for the 16  inlet  runs and the 3 outlet runs.  This average was
 compared to the average grain loading of each  test.   If the average varied
 by more than 50%,  runs within that test would be compared to the grain load-
 ing found in the corresponding mass run.  If these values disagreed by less
 than 50%, the deviation probably indicated a high degree of stratification
 and all data were retained.

 4.1  rSIAlAELE PMTICUIATE (II) EMISSION FACTORS

      The IP emission factors  for a typical source were calculated for 15.0,
 10.0, and 2.5 pa particles as follows:

      A total mass emission factor,  indicating the amount of particulata mat-
 ter released into the atmosphere per unit of asphalt  concrete produced,  in
 pounds per ton was  calculated for each run of each mass test.  The total
 mass emission factor (Ib/ton) was derived by dividing the total mass emission
 rate (Ib/hr)  calculated from  the mass train data, by the production rate (tons/
 hr).  Froduction data for the plant was provided by the Bowen Construction
 Company as described in Section 1.   The calculation for a single run was based
 on the assumption that the average stack velocity during the run was the same
 as the velocity measured at the sampling point of the quadrant being sampled.
—In.-addition—the  individual^ emission"f actors £of "each~~run~ we re "calculated   "
 based on  the plant production  rate during the  period  when the samples were
 collected with no adjustment being made for other variations  in process
 operating conditions.  The IP  emission factors  were  calculated using the
 total mass emission  factor derived from the Method 5  and  Method 17 data
 rather than a  factor which could have been calculated from the total mass
 collected by the particle sizing device.

      The  total mass  collected during a run in the particle sizing device,
 and the mass collected on each individual stage was entered into a computer
 program along with the criteria  to determine the actual D50 of  each stage.
                                  G-18

-------
The Dgo of a stage is the particle" diameter at which the stage achieves 50%
efficiency; one half of the particles of that diameter are captured and one
half are not.  The computer printouts of the particle sizing tests in Appen-
dix J indicate cumulative percent greater  than  the  stated Dso, whereas  the
graphs and tables indicate Dso as cumulative percent less than stated size,
The cumulative percent less than stated size vs. the stated size (Dgo) were
then plotted  for each, of the  four runs that constitute a test.  Mote:   The
cumulative percent less  than  stated size is determined by subtracting the
numbers found in the row labeled "cum.% with filter" from 100.

     To determine  exactly what percentage of the total mass was less than
2.5, 10, and 15 microns, the cumulative percent greater than stated size and
DSQ fxom the  abovementioned  computer printouts were entered into a spline
equation.  A program for handling 'impactor data using a spline fit has been
developed by  J. E. Johnson et al. ("A Computer  Eased Cascade Impactor Data
Reduction Systen," EIA-60Q/7-78-042, March 1978).   An improvement to this
program has recently been completed by MRI and was used in this study to de-
termine emission factors. .  IP emission factors were calculated by multiply-
ing the percentage of the total mass derived by the spline equation for the
desired Dgo hy the total mass emission factor (Ib/ton).   The particle diameter
upper limit was set  at  50.0 (jmA for  the  calculations using  the spline fit.

4.2  CALCULATION PROCEDURES FOR THE IHLET AMD CUTLET OF THE BAGEQUSE

     Due to the extremely high loading at the inlet, a deviation from normal
IP protocol was  used to calculate these emissions.  The outlet emissions
were calculated using  the  normal IP methods discussed earlier.  The total
mass runs were matched  with  the particle  size  runs as shown  in Table 4.2
and 4.3.

     All total mass  samples  taken at the inlet were collected using a six
point traverse instead of being collected from one point at the center of a
quadrant.  Because of this, the mass and particle sizing runs  could  not be
matched quadrant by  quadrant.  Total mass runs were matched with particle
sizing runs according to time and day (see Appendix A).  The last 2 days of
                                   G-19

-------
 TABI£ 4.2.  BAGHOtJSE OUTLET TOTAL MASS
               AND FARTICLE SIZING
               COORDINATION
Particle sizing nm       Total atass  run
Q-l-l(B)                0-1-1
0-1-2 (recycle)         0-1-2  (recycle)
0-1-3 (recycle)         0-1-3(B)  (recycle)
0-1-4                   0-1-4  (recycle)

0-2-1 (recycle)         0-2-1
0-2-2                   0-2-2(B)
0-2-3    .               0-2-3
0-2-4                   0-2-4(C)
                G-20

-------
TABLE 4.3.  BAGHOaSE DUET TOTAI MASS
              AND PARTICLE SIZING
              COORDINATION
Particle sizing run
None
Kone
1-1-4
1-1-2
1-1-3
1-2-2(8)
1-2-4
1-2-3
1-3-2
I-l-l(B)
1-3-4
1-3-1
1-3-3
1-4-2
1-4-1
1-4.3
1-4-4
I-2-1CC) (recycle)
Total mass run
1-3 (recycle)
1-4 (recycle)
I-KC)
1-2
1-5
1-7
1-8
1-6 (B)
None
              G-21

-------
testing no total mass runs were conducted.  The average total mass emission.
factor (lb/ton)» calculated from all eight of the inlet mass runs  (Table 4.3)
was applied to the particle sizing runs conducted on that day,

4.3  DATA PRESENTATION I01MAT

     Stannary tables  for  both the baghouse inlet and outlet test locations
are presented as follows:

     Tables 4.4 and  4.5  present impactor particle  size  run sampling data
including mass (mg) , D50 values, and the cumulative percent less than stated
size for each stage of the impactar.

     Tables 4,6 and  4.7  present the total mass  emission factors  (Ib/ton)
and the IS emission factors for 2.5-, 10.Q-, and lS-(Jm particles.  An aver-
age ratio of the grain loading determined from the particle sizing train to
the grain loading determined from the mass train, is presented  in table 4.7.
This ratio was not included in the data for the inlet (Table 4.6) due to the
six-point traverse (instead of quadrant sampling) used to obtain the  sample.

     The .computer  results  of the modified IPA Method  5  and Method  17 train
field data containing the calculated grain loading and the emission  rate in
pounds per hour, are presented in Appendix J.  If emission factors for both
the inlet and the outlet are summarized in Table 4.8.

     The data  results  are  also  presented  in  graphic form for both  the bag-
house  inlet  and outlet  test locations,  These  graphs  are presented  as
follows;

     Figures 4.1, 4.2, 4.3,  4.4,  4.5, and 4.6 present the results of each
individual test, which consisted of four  separate  runs  (one per quadrant).
The data presented  include particle size (Egg)  versus  cumulative  percent
less  than  stated size and emission  factors  for 2.5, 10.0,  and 1S.O urn.
                                  G-22

-------
                              TABLE 4.4.   PARTICLE SIZE  RUN  TEST SAMPLING DATA, BAGIIOUSE INLET
to
La
	 " ' 	 "' " 	 	 	 - 	 - -- 	 ' 	
15-|H» Cyclone Stage I
T«jst Him Ho.
Haaa
D«o «1«
Nu. Bourn.1-! iu|-qua
95.2
125,0
68.5
179.5
45.6
127,0
60.4
406.6
364.8
81.0
6Z.2
170. S
48.4
78.4
69.3
178.5
(|*>
11.4
11.8
11.5
ll.fi
11. 2
11.7
11.7
11.5
11.7
11.7
11.6
11.6
11.7
11.7
11.6
11.7
Cuw. I
less
than
stated
size
28.8
23.5
18.3
16.2
25.1
24.1
21.7
19.5
17.4
22.5
32,1
18.5
34.4
26.00
19.3
20.0
MM*
(«8)
617.5
566.6
399.4
750.9
221.8
621.1
362.7
767.3
200. S
505.7
393.8
888.7
301.8
348.8
550.6
873.4
Stage 2

(|*»>
6.3
6.7
6.5
6.5
6.2
6.6
6.6
6.4
6.6
6.6
6.5
6.5
6.61
6.6
6.6
6.6

Cum. 1
le«i
tbun
uiza
19.7
16.5
13.3
10.4
17.5
16.2
15. ft
12.9
14.7
16.2
23.6
11.6
25.4
18.2
13.6
12.8

Ham
(.8)
1,091.0
1,143.3
906.8
977.9
446.3
1,061.0
746.8
1,038.8
975.1
997.5
937.4
1,062.2
671.9
642.8
874.2
785. 0
Cyclone

(fa)
1.9
1.9
1.9
1.9
1.8
2.0
1.9
1.9
2.0
2.0
1.9
1.9
2.0
1.9
1.9
2.0

Ciua. %
less
lltun
Bize
3.8
2.4
1.7
2.8
2.1
2.8
1.2
4.1
1.4
3.7
3.4
3.4
5.3
3.9
4.7
6.4


	 fl!i£f__ 	
Hans Dga size
(ttg)
258.0
198.0
134.3
356.5
60.8
222.6
62.4
481.7
104.1
2U4.8
159.4
435.3
177.1
175.2
4S6.6
777.3
(M
< 1.9
< 1.9
< 1.9
< 1.9
< 1.8
< 2.0
< 1.9
< 1.9
< 2.0
< 2.0
< 1.9
< 1.9
< 2.0
< 1.9
< 1.9
< 2.0
                                             (Data Reproduced In Table 3-12)

-------
                                TABLE 4.5.  PARTICLE  SIZE TEST  SAMPLING DATA,  BAGHOUSE OUTLET
CJ
IS-IH Cyclone Stage t) Stage 1


let I Hun Hi.
Ha. source- riili-i|uail
0- -HU)
0- -2
0- -3
0- -4
0- -1
2 0- -2
n-2-3
0-2-4




Test KUII No,
tlo. nutirce-run-<|uail
O-I-I(H)
. W-l-2
0-1-3
tt-l-4
CJ-2-1
ti-'i-'l
0-2-3
0-2-4
Cum. %
lew
tli an
: CtlM. %
teas
tliau
Haas D60 ilze slater! HJES |IBU uize utated Mas* D6O s|ze
(wg) (|>») site (og) (|liu) lit lie (ma) (|ttn)
37.96 14.9 42.1 0.41
84.91 14.? 21.0 0.51
39.29 14.9 26.0 0.00
72.3} 14.6 31.6 0.61
21.93 15.2 56,7 1.60
49.78 15.0 3S.7 0.67
61.54 14.6 32.8 3.52
71.68 IS. 4 37,0 7.79
Stage 4
Cu». X
ictm
til Ml
14. I 41. 5 i.34 9.1
14.4 20.5 0.89 9.0
14.6 26.0 0.63 9.1
14.7 31.1 0.73 9.2
14.9 53.1 1.88 9.3
14.7 34.9 0.8S 9.2
14.3 28.9 1.98 8.9
15,0 30.1 3.38 9.4
Stage 5 Stage 6
Ciui. f
letta
Mian
Mann Bs<) *tze alultJ Milan II60 clze tl«li:4 HiiBK 05U size
<»«) (}l») alii: (ing)
B.45 2.7 12.9 5.71
5.43 2.6 6.8 4,74
2.97 2.7 10.2 3.26
0.00 2.7 12.7 12.4
5.68 2.7 21.0 5.09
7.91 2.7 13.6 6.63
7.04 2.6 ».» 5.0'J
8.35 2.8 9.0 6,07

(|ou) ilxe dog) (|u)
.3 4.2 2,07 0.80
.3 2.4 1.71 0.78
.3 4.1 1.81 0.79
.3 1.0 0.00 41,81
.3 II. 0 2.60 U.8I
.3 5.1 2.95 0.80
.3 3.3 2,45 (1.78
.4 3.7 2.51 0.82
Cum. %
lens
ill an
atatetl
size
3'J.S
19.7
24.8
30.4
49.8
33.8
26.8
27.2


Hans 1
Ug)
3.65
3.94
1.95
2.36
4.33
3.36
4.77
5.75
§i»8S 2 • Stage 3


J&o »1
(H8)
6.2
6.1
6.1
6.2
6.3
6.2
6.0
6.3












Cum- 1
leSI
Iban
• tateil
• izc
33.9
16.0
21.1
28.1
41.2
29.4
21.6
22.1


Has*
(«gl
5.30
4.44
2,82
16.29
4.56
4.33
4.58
6.57
Cum. I
til Hll
Dm lize ctuteil
(|Jg) size
4.2 25.8
4.1 11.9
4.2 15.8
4.2 12.7
4.3 32.2
4.2 23.8
4.1 16.6
4.3 16.3
Stage 7
CMS. X
lean
than
stated
size
l.i
0.82
0.64
1.0
5. a
1.3
0.64
1.4



hast!
(-1)
0.33
0.57
0.21
0.88
1.54
0.77
0.46
0.91



0&0



nize
(V8>
0,
0.
0.
0.
59
58
SB
59
11.60
0.
0.
o.
59
57
61
Cum. 1
leu
than
•tated
• ize
0.56
0.29
0.24
0.20
2. a
0.26
0.14
0.63



Has*
(»8)
0.37
0.31
0. 13
0.21
1.40
0.20
0.13
0.72
Filter


l>60 alzu
(l'8>
< 0.59
< 0.58
< 0.58
< 0.59
< 0.60
< 0.59
t 0.57
< 0.61

                                                 (Data Reproduced In Table 3-13)

-------
TABLE 4.6.   BAGHOUSE  INLET  HUSSION  FACTORS  HASE0  ON  TOTAL MASS  AND  IHPACTOR  SIZE DISTRIBUTION
        Nu ,

Titlill Btiitcti
Kim No. Hu idling «;iiiittsii»u rule*
tircu-rtiu-iniitij w.iiti run llt/li
I-I-I(U) 1-7 7.48U
1-1-2 !-!(«:) B.I'JO
1-1-3 1-2 6.U30
1-1-4 l-l(tf) B.i'jo

1-2-1(8)* NuiM
1-2-2(11) 1-2 fe,!»au
1-2-3 1-7 ?,4BO
1-2-4 i-S 7.1*0

1-3-1 1-8 5,840
1-3-2 1-7 7.4BO
1-3-3 l-fl 5.B4U
1-3-4 1-7 7,480

i-4-l* Huuc
1-4-2 1-6(11) 5,720
I -4-3 Nunc
1-4-4* NUMO

Ntiit-
tt*i I citing
tout** runs
i-tl 5.620
1-4 a. 115(1
"' ^"^ 6'J5°

Product fun
i alt:
luil/li
225
217
162
217

-
162
225
195

215
225
215
225

_
205
-
-




223
237
210
- - , .
Tola! mat. a
utttlus ion faclor ^
Ib/luu (1
33.3
37.7
42.6
37.7
Avg, 37.9 Aug.
(30.9)
42. a
33.3
36.8
Avg. 40.0 Avg.
27.2
33.3
27.2
33.3
Avg. 30.3 Avg.
(30. !J)
27.9
(30.9)
(30.9)
Avg. 30.2 Avu.



;»5,2
16.3
(30.'J)C

IP CMll
2.5 |ta <
l>/luu) (]
2.1
1.6
1.4
1.5
1.65 Avg.
1.3
1.9
o.a
2.0
1.5 Av|.
0.75
i.a
1.6
1.5
1.4 Avg.
Z.i
1.6
1.9
2.2
2.1 Avg.





1.7

is ion
10 |im
lt>/ ton
9.1
8.3
7-5
5.6
J.6
7.4
9.5
6. a
6.6
7.6
4.5
7.1
i.3
5.7
6.4
10.0
6. a
5.6
5.6
7.0





7.2


< 15 |M
) (Ul/lUli)
10.2
9.4
a. 3
6.7
Avg. B.7
B.5
10.9
7.6
a. 5
Avg. 8.9
5. a
7. a
9.1
6.6
Avu . ?.3
11.0
7.7
6.3
6.6
AWJJ. 7.9





a. 2
      IM.:;  A (.uliiuiu
                              "Hall.. »l lutdl M,,bb i:uur. lu
       ilut: lu ||ii> littV«!li»iiig ui UK: w.j^i i»iti> i.ilhur lluii .juj.lrjul
   Nu jMirutl injt.1. inn |i<4  llii^ |i.u(icli! uiiing run.  UiiuJ ilm .ivti\.
^  m:i&a ruiiti (30.9 ll>/lun) It, t.il.nl.Ui: 11- i:wj^i,iuii (ailuii
t  Avt:i-aK>i |ilaul |>ru>lufl iuii i.ilu ilm jag t».its, leal inn.
   Tlliti iivurilgl.' WJS i|.:ilu.:.l Ililui I la:  ulgltl w.lktt IllltH ill D'allli! 4.3.
                                                                            cowt," It. uul liitli.JeJ oil Ibla tulili: due
                                                                           wpl i»g.
                                                                            lulal wjs-i. uwistiiuu tai:lor ut dl
                                            (Data Reproduced  In  Table  3-27)

-------
           TAUUi 4.7.   llAGHOUSIi: OUTLET EMISSION  FALTOUS BASED ON TOTAL MASS ANI> IMPACTOR SIZE  DISTRIBUTION


Tut. l
«u.

1




2





Hull Ha.
Total
MSB PrOduC)
ton Total mu»»
emiuttluu rule ralti emiimioii fuctor
nuurce-ruii-<|liail (ll»/li) (luu/l
0-1-KB)
0-1-2
0-1-3
0-1-4
Average
0-2-1
0-2-2
0-2-3
0-2-4
Avur-ue
Tumi uverage
II
|2
16
9
12
9

24
10
12
12
,5 164
.1 226
6 216
.6 21}
.6 211
6 1*4
3 . 216
7 195
0 118
9 191
6 201
) ClMtot)
o.ai
0.056
O.OJ)
0.041
0.061
0.055
Q.U34
0.121
0.056
0.06B
0.065
Httllu of itari-icle
IP c.
UllCK Iflllll Id lutlll < 2.S |W
••MB train cant:. (Ib/tou)
0
0
a
0
0 VJ 0
0
0
0
0
0.65 , 0
0
.008
.004
,00}
.004
.006
.011
.004
.011
.004
.OOB
.00}
ilcnloii fuel
< 10 |W
(Ib/iou)
0.02U
0.011
0.019
0.011
0.018
0.028
0.012
0.035
0.016
0.023
0.021
can

< IS |M
(II.
a
a
o
a
0
0
0
0
0
0
0
/iwii
.03
.012
.021
.011
.019
.031
.012
.044
.021
.021
.023
a
to
            Average |iUni |>ra
-------
     The data for  particle size (Dgo) versus cumulative percent  less  Chan
stated size data have been plotted for each of the  four separate  rims.   The
average of the results from the four runs have also been presented  as  a  line.
This line was generated  from  the  results  of  the  spline fit of the selected
particle diameters (2.5, 10,0, and 15.0 JJJB) •

     The calculated  emission,  factors foe 2.5, 10.0,  and  15.0 \m are pre-
sented both as an. average of the faux runs and as a range  of  values for  the
four runs.  The average of the four runs is presented  as a line,  whereas the
range of values is presented  as a vertical line  at  the selected diameters.

     Figures 4.7 and  4.3  present  the average of the  results  of all tests
conducted at each  testing  location.  There were  four  particle sizing testa
of four runs per test conducted at the ialet location  and  two particle siz-
ing tests of four runs per test conducted at the outlet location.
   .  The avenge particle  size (Dgg) versus  cumulative  percent less than
stated  size  for all teats is  presented  graphically.  The plot  was  con-
structed by averaging all test data generated by the spline  fit  for  the  se-
lected diameters of  2,5,  10.0, and 15.0 yaa.  The ranges of  the  individual
test averages are also presented at the selected diameters .

     The average emission  factor for all  tests  is  also represented by  a
line.  The line was constructed by averaging the average of  individual test
results at  the  selected diameters of 2.5,  10.0,  and 15,0  jjoi.   The ranges
of the  individual  test averages are presented  at  the  selected diameters.
                                  G-27

-------
                                SECTION 5.0

                       CONDINSABLES TESTIHG RIStHTS
     This section  summarizes  tests for condensable emissions  conducted by
Southern. Research Institute (SoRI) at Bowen Construction Company.  The tests
were conducted during the week of October 5 to  10, 1981.  The  IF condensable
testing was  performed using the EPA Stack Dilution Sampling System  (SBSS)
according to IS protocol.  Both the sampling equipment and  the protocol used
are described  in  this section,  followed by a  presentation of test data and
a brief discussion of the- teat, results.

5.1  DESCRIPTION OF OISTRTIMENT AND TEST PROCESSES

5.1.1  Design of Stack Dilution Saaoling System (SPSS)

     A diagram  of the najor components  of  the SDSS  is shown in Figure 5.1.
In  operation,  gases  from_the process stream_are  drawn_,througli_the If Dual
Cyclone Sampler in which particles with an aerodynamic diameter greater than
IS  M» and  those in the range 2.5  to 15 M» are  removed in  two  stages.  The
stack gas  containing  the  fine particle  fraction (<  2.5  Mm) and condensable
vapors passes  through the heated  probe  and flexible sample line and is in-
troduced axially  into the bottom  of the cylindrical  dilution  chamber.  At
this point  the stack gases are mixed with cool, dry dilution air to form a
Simulatad plume which flows upward through the  dilution chamber.   A  standard
20  x 25  cm  hi-vol filter is  installed  at the discharge end of the chamber
which collects  the fine particulate including any aew particulate  formed  by
condensation.   The diluted  stream  is exhausted  by a  1-hp  blower or optionally
by  a standard hi-vol  blower.  Stack gas flow  rate is  measured  by  an  orifice
                                   G-28

-------
                                  Ill VOL IMPACTOR
                                  AND/OR FILTER
                    PROCESS STREAM
o
to
vD
                                    SAMPLING
                                    CYCLONE
               }.(Cli\
                          /

                                                                          EXHAUST BLOWER
                                                                    .DILUTION
                                                                     CHAMBER
                                                                         1=
                                                 TOULTRAFINE
                                                 PARTICLE SIZING
                                                 SYSTEM (OPTIONAL)
                                                                                    DILUTION AIR
                                                                                    "EATER
                                                                                                          DILUTION AIR
                                                                                                          BLOWER
          TO HEATERS, BLOWERS
          TEMPERATURE SENSORS
                                                                                    ICE BATH
                                                                  TO ORIFICE
                                                                  PRESSURE TAPS
                                                                      ©
                                            MAIN CONTROL
                                 FLOW, PRESSURE
                                 MONITORS
Figure  5,1,
                                                       uf stack  dlludun  Baubling system.

-------
at the base of the dilution chamber.  Dilution and exhaust flow are measured
by orifices in the inlet and outlet lines, respectively,

     Ambient dilution  air  is  drawn through a blower and forced through aa
ice bath condenser.  In this condenser the air is cooled to 5 to 8°C (41 to
46°T), depending  on  the flow and  ambient  temperature.   Hare  significantly,
the dilution, aiz  humidity  is reduced  to about Q.57% by volume,  correspond-
ing to saturated air at the ice point.  After the condenser, the air is re-
heated as  required to  reach 21,1°C (7Qa?)  at the  dilution chamber inlet,
filtered through a HEPA-type absolute filter, and introduced into the dilu-
tion chamber,  the dilution air eaters a single tangential inlet at the
base of the dilution chamber and passes through  a set of flow straightening
screens into the annular region surrounding the  sample  gas inlet.  The ratio
of the areas of the  two inlets  is such that for  sample gas  at  room temper-
ature the  velocities of the sample and dilution  streams are  equal.   Sample
gas at stack temperature will be injected at a higher velocity proportional
to the thermal  expansion  of the  heated gas  stream.   This was judged the
best simulation of a buoyant plume  injected into stagnant air.

5.2  SPECIFICATIONS

     The geometric and flow specifications were  set by  several constraints.
The sample  flow rate was set by  the  flow requirements of the If cyclone-
sampler.  Ideally,  to  approximate the conditions  found  in actual plumes,
the dilution  ratio  should be high (approaching  103 to 104) and the mixing
times  long  (tens  of seconds).   The actual dilution conditions represent a
compromise  dictated by limitations on the size of a  portable  field  iascm-
mcat.  Geometric and flow specifications  are given in Table 3.1.

     Since  the  effect  of varying dilution air  temperature and humidity can-
not be easily predicted for  all typical process  streams, standard conditions
of 0.57%  moisture by volume at  21.1°C (corresponding to  about 24% relative
humidity  at 70°f) were chosen.  This  relatively  dry dilution air should not
be subject  to water condensation for normal stack samples, yet  is  more
realistic than  totally dry  air.
                                   C-30

-------
          TABLE 5.1.  SPECIFICATIONS FOR DILUTION SAMPLING SYSTEM
Geometric
     *  Active length, of dilution chamber:              48 in. (122 cm)
     *  Diameter of dilutioa chamber:                   8.4 ia.  (21.3 cm)
     *  Diameter of sample inlet tube:                  1.68 in. (4,27 cm)
     •  Active dilution volume:                         1,54 ft3 (43,600 on3)

Flow
     *  Sample flow (determined by inhalable
          particulata cyclone train):                   0.6 ftVmia
                                                          (~ 17  liters/mia)
     •  Sample velocity:                                0.86 ft/sec
                                                        .,  (~ 27  cm/sec)
                                                          at 302°F (15Q°C)-
     •  Dilution airflow:                               15 ft3/min
                                                          (425 liters/min)
     *  Dilution air velocity:                          0.66 ft/sec
                                                          (20 cm/sec)
     •  Dilution ratio:                                 - 25:1 (up to 40:1
                                                          possible)
     «  Residence time:                                 6.2 sec
Gasconditions
     •  Sample gas:  T < 250°C; particles > 2.5 Mm removed by cyclones
     •  Dilution air:  1 = 21.1*C; relative humidity 24%, filtered ambient
          air

Sample collection
     *  Particulate collected on glass fiber filter
     *  Optional impactor gives cuts at 0.5, 1.0, 2.0, and 4.0 pm
     *  Optional extraction of diluted stream for sizing by optical counter,
          electrical mobility analyzer, condensation nuclei counter, etc.
                                    G-31

-------
5.3  OPERATING PROCEDURE

     The in-stack  IP  dual cyclone train is the intended precutter  for the
SDSS.  This device is  fully  described in. the  "Procedures  Manual for Inhal-
able Partieulate Sampler  Operation"  cited earlier.   The flow rate of stack
gas entering the dilution system is determined by the necessity  to  obtain a
DSo of IS pm (50%  collection efficiency at 15 MO) for the initial IP  cyclone
(SB1-X).  This  flow rate, which varies with  temperature,  can be determined
from the experimental  calibration data for the cyclone train.   Nominally,
23 1,/raia (0.8 fta/min) is required for standard air  at  1SO°C  (30QaF).  Over
the entire operating  temperature  range of the sampler,  Cyclone SHI-HI ob-
tains 50% collection efficiency at 2.5 + 0.5  M° foe  the flow  rate determined
by cyclone SRI-X.  Particulate with aerodynamic diameter smaller than 2.5 pm
(the fine particulate  fraction) passes into the SDSS and provides the nuclei
for the accumulation of condensable material  in the  dilution/cooling  process,

     Since the  fine fraction of the in-stack  particulate  is  collected along
with the condensable emissions, a second dual cyclone IP train with a stan-
dard in-stack  filter  is used to measure  simultaneously the in-stack parti-
culate without  condensation effects.  The setup and  operating procedures for
both cyclone  trains are essentially identical and are described in full in
the SoRI procedures manual.  In brief, the stack gas temperature,' velocity,
and "composition" are measured, and" the  gas~~vUscosity~ calculated".  Using~cali-
bration data  for  Cyclone  X of the dual cyclone IB sampler,  a flow  rate is
selected to obtain a D50 of  IS urn for  this device.   Nozzles  are  selected for
isokinetic sampling, and the sampling  trains, after  warmup,  are  inserted at
different points in the stack that are demonstrated  not to have  dramatically
different loadings due to stratification  of emissions.  The  protocol  for the
SDSS calls  for sampling at a minimum of  two  points in a duct rather than a
minimum of  four as specified for the  dual cyclone train.  In either  case,
sampling points are chosen at the centroids of quadrants of  the  duct.  When
the minimum two-point  measurements are taken, as they were in this  test, the
dual cyclone train is  used to sample at one point while the  SDSS is used at
the other,  la.  alternate  runs, the sampling trains are  switched, especially
if stratification  is noted.
                                   G-32

-------
     After sampling,  the  cyclones  ace  unloaded and tile cyclone catches ace
collected according  to  the procedures  manual  for  the dual cyclone train.
The probe,  heated hose,  and  sample gas inlet  assembly of the SDSS are
washed with  a suitable sol-rent, usually acetone.  The  rinses  are  evaporated
to dryness and the residue weighed as in EPA lefereace  Method  5.   The  probe
wash, weights are included with the SDSS filter  in  calculating  the  fine par-
ticulate plus condensable emissions fraction.

5.4  TEST CONDITIONS

     The sampling  crew  from SoRI arrived on-sita  with  the SDSS on Monday,
October 5, and began setup.   Due to delays in  obtaining electrical power,
the first run  could not be made until Wednesday,  October 7,  A second run
was performed  on Thursday, October 8;  in order to  make up. for the  lost run
on Tuesday,  two runs were made on Friday, October  9.

     All samples were taken from the outlet of the baghouse  with the plant
utilizing recycled  paving material.  A cross-section of the  stack  is shown
in Figure 5.2.  Samples were  taken at  points  2 and 4 of Figure 5.2.  These
points lie 105 on (41.0 in.) from the entrance  of  each  port along  the  diam-
eter of the stack; in other words,  at the centroids of  the quadrants of the
stack cross  section which lie away from the  baghouse.  Stack velocities
were measured  at  quadrant centroid points  1  to 4   and averaged to select
sampling aozzle sizes.   Gas  composition (dry basis) was measured  by Orsat
and determined to be  15% 02, 3% C02, and 82% Jf2, respectively.  Stack  mois-
ture as determined  at the end of all IP runs  varied  from 14  to 19% by  vol-
ume.  Obviously, this figure will vary with production  rate and the moisture
content of the aggregate, but it was  roughly constant except for Run 4.
Other relevant variables are presented in Table 5.2.

     To provide  a  "clean"  substrate  for  any future chemical analysis,.
Zefluor Teflon membrane  filters (GHIA, Inc.),  2-ym  pore size, were used
for all SDSS runs.   For  the in-stack backup filters  on the conventional  IP
train, preweighed  4?-mm glass fiber filters  were  employed.   "So pressure
                                   G-33

-------
     East Port
                    •6" ID Ports-

                 Outlet Cross Section
                         West Port
Figure 5.2.
Cross section of baghouse ouclec stack.
 .Quadratics nuebered  as  for cemdeosables
  testing.
                        G-34

-------
   TAULE 5.2.   RUN CONDITIONS FOK  TNIIAI.AULB  PAK'tTCULATE AND STACK DILUTION SAMPLING SYSTEM
                   TESTS AT  IIOWEH CONSTRUCTION COMPANY
him Slack
time temperature
Hun No. Start tine Date («iu) (»C)
! suss I2i4° ""»• I0/l/81 isa IM
2 IL 1 '»«!>•". 10/S/SI ^J 154
5foss .,3..... ,..,.., £
4 suss 2:0a p*"* I0'9 8I !oa l49
Actual Uteri per »lnute.
Actual cubic feet per Minute.
Dry Blaiulard cubic melect.
Dry utJuJurJ cubic feet.
*
Stick Sample Sample
•tolaturc (low rate voliuoe .
volume (1) ala («cfB) iiscn"~ (dacf)
. 20.12 (0.732) 1,765 (62.3)
17.91 (0.635) 1,559 (55.0)
,„ „ 21.39 (0.155) 1.6SI (59.4)
8 17.61 (0.622) 1.315 (48.6)
,, , 21.38 (0.155) 2.104 (74.3)
10 '' 18.66 (0.659) 1.104 (60.2)
. . 18.73 (0.661) i.155 (40.0)
11.10 (0.625) 1.112 (39.3)





Average Eat tinted total
•tack velocity . stack flow .
•/*ec (h/aec) a*/-!"1 («cf»)
18.4 (60.2) 1,290 45,4(10
21.5 (10.5) 1.500 53,100
21.7 (11,2) 1,520 53,100
21.4 (70.3) 1,500 53,000





 '
  et |>er accoitil.

Actual cubic meter* per

Actual cubic feet |>er •iniilc.

-------
drop problems  were acted with either  filter.   The SOSS filter from Run 1
was dropped  after the run and was  contaminated thus voiding the results.
All other  filters,  including one  blank filter of each type,  were kept pro-
tected in covered containers.

5,3  RESULTS

     The weights  of  the  cyclone  and  filter catches  are  presented  in
Table 5.3.  The cyclone catches were weighed after  desiccation on a  Cahn  27
balance at Soli.   All filter weights  represent the results of  replicate
weighings  in the  controlled humidity  weighing  room at'MRI.  The variation
of all  replicate  weighings was insignificant  except for the  loaded  SDSS
Teflon filters.  The  filters  from Runs 2 to 4 showed a  steady  loss of weight
with tine, as shown in Figure 5-3.   A blank SDSS filter which was  taken to
the test site and returned for weighing showed  no  such  variation.  For  rea-
sons discussed below, this loss was interpreted as  evaporation of condensed
organic compounds collected on the filter of the diluted stream.  Ho similar
weight  loss  was  noted on  Che  glass  filters used for the in-stack cyclone
train.  The  variations in the weights of  these filters were  within the
0.2-mg reliability of the Hettler AKlfiO balance used and were  not nonotonic
with time.  Chrer the  3- or 4-day weighing period,  the glass  filters  were  as
likely to ..gain weight as to lose weight between reweighings.   Thus,  we  con-
cluded  that  the  systematic weight lass was real and unique to the_f.ilter
samples taken with the SDSS.  Therefore, the weights reported  for these fil-
ters in Table 5.3 are not averages,  but  rather the individual weights as
measured 1 day after  sampling.  The  rationale  for  this  decision  is discussed
below.

     Inspection of the data  in Table 3.3  reveals that the two parallel cy-
clone trains collected roughly comparable  amounts  of dust for the runs in
this teat.   For  all pairs of  cyclone catches except those  in Run 1,  the
deviation  from the mean is less than  30%.   In Run  1,  the SDSS  cyclone X was
significantly  higher  than the standard IB  train with a deviation of 43%
above the mean, but this is still within reasonable limits for simultaneous
                                   G-36

-------
                TABLE 5.3.  RAW WEIGHTS   FROH  TN1IALADI.E  PAHTCULATE STACK DILUTION SAMPLING SYSTEH
                              TESTS AT UOWEN CONSTRUCTION COHPANY
o




Run No.
1 IP
2 IP
2 SDSS
3 IP
3 SDSS
4 IP
4 SDSS

15 \isa D80
cyclone
SRI X
10.21
31.53
20.51
77.31
43.63
11.20
16.09

2 5 ym i)
cyclone
SRI HI
2.77
1.58
2.77
9.17
9.40
2.47
2.37

Uncorrected
filter
wt.
2.8
2.5
14.69
3.5
25.21
2.8
24.64
8%
Corrected
filter Total weight
wt. Wash collected
15.78
35.61
15.87 5.4 43.37
89.98
27.23 6.0 84.24
16.47
26.61 4.0 47.1

Corrected
total
wt.


44.55

86.26

49.07

            .  Ail weights in Diilligratus.
              Filter from SDSS Rim 1 was contaminated.

-------
        30
        26
     I
        20
                   i—i—r
                                                                      i         i         r
Q
u>
OQ
§
O  IB
     DC
        10
                                                                                              TT-
                                                                                   O  RUN 2
                                                                                   O  RUN 3
                                                                                   A  RUN 4
                                                                                   •  BLANK
                  10
                       20
                                     30
                                                   GO

                                                TIME, lir
60
                                                                          70
80
00
                Figure 5.3.  Variation of partleuluta  muss  on filter from stuck dilution sampling
                               uystuiu with time after
                                     100

-------
single-point samples.   In.  contrast,  the SUSS  filter  catches  were factors
of 6 to 9 higher than the in-stack filters even before the probe washes were
included.  This extra mass, coupled.with the steady weight loss of the SDSS
filters, indicates that the diluted flue gas contained a substantial amount
of condensable material with  enough volatility to  reevaporate at  room  tem-
perature.  The most  likely candidate species  appear to be lower molecular
weight aliphatic hydrocarbons from the asphalt, mix,  but  analyses of the
material would be necessary to confirm this speculation.

     The evaporation  of the SDSS  filter  samples results in some difficulty
in assigning a unique loading to the  filters.  Obviously,  the weights  of
the filters immediately after sampling would  give  best  lower  bounds  to  the
samples, but there were technical problems in  obtaining these  data.  First,
it is aot always desirable to take an appropriate balance-to the  field site.
Second, it is customary to equilibrate filters for several hours  ia  a  con-
stant humidity atmosphere or  a desiccator before weighing to avoid artifacts
due to adsorbed  moisture.   In this test,  prompt weighings  were available
only for lun 4.  However, for all three runs weighings were in the vicinity
of 24 h  after sampling.  Since  this was  the earliest  period after sampling
for which accurate weights could be reported  for  all runs, and since  the
filters should have  equilibrated with the weighing room atmosphere by the
end of the day, these weights were chosen  for  Table 5-3.

     To  obtain  a more  realistic  comparison of the weight losses  of the
three SDSS filters, all sample weights were normalized to the  1-day weights.
These normalized data are  presented in Figure 5.4.  It is noteworthy that
the relative weights  of the  three samples  lie along  the  same curve.   Ex-
trapolating this curve, it is estimated that the filter catches immediately
after sampling are  5 to 10%  higher than the 24-h value and that  up to 20%
of this mass is lost  after 4  days.  To calculate mass concentrations at  the
time of  emission,  the 1-day weights  given in  Table 5.3  should be  Increased
by approximately 8%.
                                   G-39

-------
       1.2
       1.0
       0.8
    > 0.6
    P
r>   UJ
O   DC
      0.4
       0.2
              P
                  i         r
                  10
             Figure 5.4.
20
          i        r
30
                   i         r
                                                                               O RUN 2
                                                                               D RUN 3
                                                                               A RUN 4
                  i	i         i         i
                                      I	__l
60
70
80
80
                   10        EO
                          TIME, Jir
Relative variation of participate iaass on SDSS filter with  time  after
  sampling.  All data for each  run are normulized with respect to  muss
  measured 1 day (21 tu  26  li) after sampling.
100

-------
     The mass coucen.trati.oiis calculated from the test data  are presented in
Table 5.4.  Concentrations have been calculated from the data in Tables  5.2
and 5.3.  The fine particle plus condensable fraction has been corrected by
the 8% fraction mentioned earlier, and the concentration of particles  formed
by condensation  alone  has been calculated by subtracting the fine  particu-
late concentration measured by the standard IS train from the corresponding
fraction from the  SDSS data.  This value,  divided by  the  total  emissions
concentration measured  in  the SDSS, is tabulated  as percent condensable.
As can be  seen,  on the average 45% of  the particulate  measured  in  the SDSS
at this source was formed by condensation.

     The total mass  concentrations in Table 5.4 are listed in taetric and
English units and  have been converted to  emissions factors in pounds per
hour using the stack volume flow listed in Table 5.2.  This number is  based
on a four-point velocity average rather than a full pitot traverse,

     Table 5.5 presents  the  IB emission factors that were  calculated  from
the condensables testing data.  The IF emission  factors  were determined by
first calculating  a total mass emission  factor  (pounds/ton).   The total
mass emission factor was calculated by multiplying the ratio of the stack
flow rate  to  the sampler flow  rate  by the total weight collected in  the
sampler and converting to pounds per hour.   Pounds  of  emissions  per  ton of
product were  calculated by multiplying the average production rate  (tons
per hour)  during the test period by the  total  emissions  (pounds  per  hour).
In order to  calculate  emission factors  for  >1S,  2.5  to 15, and  <2,5 M01
(pounds per ton),  the  ratio of the individual stage weight  (Table 5.3)  to
the total weight collected was multiplied by the total oass emission  factor
(pounds per ton).

     One final word of caution:  The condensable emission  factors  measured
in the SDSS must not be equated with volatile organic carbon measurements
made with  other  sampling trains.   It  has  been demonstrated that the SDSS
does not  retain  all the oore volatile hydrocarbons that fall in the vola-
tility range  corresponding  to the TCO fraction  Level  1  organic  analysis.
These more volatile hydrocarbons  will not be  retained by the SDSS filter,
                                   G-41

-------
                       TABLE 5.4,   PAMTICUI.ATE MASS COHCENTRATlOtlS (COHDENSABLES TESTING)
?
*»
Cyclone X
> IS |l
Run Ho.
1 If
1 SUSS
2 IF
2 ems
3 If
3 SUSS
4 IF
4 sosa
Average IF
Average SOSB
Cyclone III , Filter Filter pl'io wash
2.5-15 tim • < 2.5 l*a < 2.S |M coiidcimalilet X total ealgglons
mS/d»cmm tt/Ancf" »«/d*cO gr/d.el ai/dic. tr/Jacf -i/d.**
5.7*
19.03
18.76
14.92
36.74
2s. 61
9.70
14.17
17.75
IB. SI
0.00253
0.00831
O.OOBI9
0.00652
0.16
0.112
0,00424
0.00632
0,00775
o.ooeoa
1.57
2.80
0.94
2.01
4.36
5.52
2.14
2.13
2.25
3.11
0.000686 1.59 0.000694
0.00122
i
0.00041 1.49 0.000651
0.000878 IS. 78
0.0(119 I,fi6 0.000725
0.00241 19-79
0.000935 2.42 0.00106
0.00093 27.81
0,000903 1.19 0. 00(1782
0.00)36 21.13
tr/dicl Condensable* «•/
-------
                                      TABLE  5.5,   EMISSION FACTORS  
* SUSS

Total B*K*
eujiikiou fjictor
(Ib/lou)
0.00247
-
0.012
0.0155
0.0172
0. 00655
0.0202
-0.0081
-0.016



If euiMsloii factor
> IS t»
X Comlciiyable (Ib/laii)
0.0016
-
43 -1 2:SSS
35*6 0.0087
0.0045
31 "* 0.0066
-45.5 -0.0065
-0.0069
2.5-15 ilis
(ib/tou)
0.00043
-
0,00035
0.00075
0.0016
0.0019
o.oou'ja
O.OOOM
-0. 00004
-0.0012
< 2-5 |£»
(Ib/tou)
0.00044
-
0.00055
0.0057
0.00060
0.0066
0.0011
0.013
-0. 00067
-0.0084
	 . ,
         Average |irudui:tioii rate for tent period except t'ur Him 2 wliurc tlic daily nverage wa* utcj to calculate the eaUaion
                                                    (Data Reproduced  in Table 3-29)

-------
as they will not remain la the condensed particulate in the actual plume of
a stack.  To obtain values o£ total organic emission, a sampling train such
as the  Source  Assessment, Sampling System is recommended.  The present re-
sults are  representative  of the particulate emissions as they would exist
in the  near-stack  ambient environment, after  emission,  including  that  frac-
tion of the volatile emissions found in the condensed phase.
                                  G-44

-------
                  APPENDIX H
COMPLETE LISTINGS OF JSKFRG. JSKRAW, AMD JSKLOG
                      H-l

-------
:2  REH	PROGRAM "J8KPRG"	
10  CLEAR 4000
12 REH	CLEAR  REGISTERS FOR NEW RUN	
15 OG=LOG( lO)U2=OtXX=OlXD=0tX2=OtYP=OtST=0;NZ=QtXM=OtLX=OtSi=GtYL=QtYM=OtDM=Ot
=0 IL2=0IL3=OIL4=QIL5=Q
16 Ld=OJKl=OIK2=OtK3=OiK4=OlK5=OtK6=OSJY=OIJ9=OJIT=0;iJ=0;iH=OtIl=0
17 K2=On3=OlTL=OtKS=OtBfti=Ot3A=OtIQ=OtIX=OtI2=QtJX=OtIA=Otie=OtIB=Q
20 DIM XN< iO)tYO< 10 >»X< 53 >»A< 16 )»B< 4 >»CO< 50»3 )»Yl< 53 >?XD< 15)>XQ< 10>50)>YO( 10*50
Y2< iO)»ID*<  50 )» JX<50 )yJY(50)»GG< 10»5Q)»JGK 10)f JU( 10 )
30 PRINT"PROGRAM SPLIN2 FROM FORTRAN ORIGINAL 02/22/82 VI"
31  LPRINT TAB<6H " "tLPRINT "  "tLPRINT "  "tLPRINT "                       SPLIN!
PROGRAM -   02/22/82 Ml"tLPRINT" "tLPRINT "  "
39 REM 	 NUMBER OF  DATA SETS AND REQUESTED OUTPUT 	—
40 INPUT-ENTER * OF DATA SETS"iQW
45 PRINT"ENTER DSO'S  IN INCREASING SIZE"
50 INPUT"ENTER NUMBER OF POINTS"»NF
52 REM 	 INPUT  PRODUCTION*  EMISSION DATA 	
55 FOR QV»1 TO QU
58 INPUT"SI£T  ID»"1ID'* CUM LOADING FOR EACH POINT* JQGK I»QV >»YGK I»QV >:X8< I f GW >=JW< R
*QQ< I»«M)INEXT I
80 PRINT"SET *"rQV'.NEXT QM
81 INPUT-ENTER * OF DSO'S TO BE DETERMINED FOR ALL SETS"iLA
82 FOR 1 = 1  TO LAJINPUT-ENTER AERODYNAMIC D50"iXD»" TONS PROIU/HR" ILPRINT  TAB< 24 )? "TOTi
 PARTICULATE EHISSION RATE =")JY( QM)»"  LB/HR"SLPRINT TAB<24 )»"PARTICLE DENSITY
»Jtt< QV)J" G/CC"
85 LPRINT "  "tLPRINT  TAB<6)I"MEASURED SIZE DISTRIBUTION"tLPRINT  "  "
86 LPRINT TAB<6-)» "CUT(um)        CUM,  % < CUT" tLPRINT "  "
88 FOR 1 = 1  TO NF'tLPRINT TAB(6)J QQJNEXT It'LPRINT"  "ILPRIi
89 HN=8'.RR=NN',N=4*,R=N
90 NP=<(NF-2 )*N)+NN+1
91 aE=JY(Qrv')/JX"$ LPRINT"  "tLPRINT " " tLPRINTTAB< 41 )»"EMISSION FACTOR"
93 LPRINT TAB<6)i"CUT  (umA)      CUM. % < CUT      C LB/T )       < KG/MT )" tLPRINT
93 «EM 	 SPLINE  FIT  OF MEASURED SIZE DISTRIBUTION -
96 REM 	 BASIC TRANSLATION OF "SPLIN2" Ml 02/22/82
100 N2=NF-2
110 FOR 1=1 TO N2
120 JJ=N-1
130 IF N2-KO THEN 150
140 00=N+2
150 H=< 1-1 )*N+1
160 X< M )=LOG< KN( I ) )/OG
170 YKM)=LOGCYO< I) )/OG
1BO XI=< LOG< XN< I + l ) )/OG-LOG< XN< I ) )/QG >/R
190 FOR 11=1 TO 3
200 HM=I-1-HI
210 B< 11 )=LUG( Y0< MM ) )/QG                H_5
220 K=3*
260 NEXT atNEXT  II

-------
280 (JQSUB 5000
290 FOR j=l  TO  2
300 8L=B< 2 )+2*B« 3 )$LGG< XN< I+J-1 ) )/QG
310 IF SL>=0 THEN 350
320 B< 2)=/QG+J*XI
390 Yl< K >=B<  i )+B< 2 )*XC K )+B< 3 )*X< K )C2
400 NEXT J5 NEXT I
410 FOR 1=1  TO  3
420 K=3*< 1-1)
430 FOR J=l  TO  3
440 K*i+=0 THEN  600
530 FOR 1=1  TO  3tA< I)»I:NEXT i
540 A< 4 )=X< 1 )-( X< N+l )-X< 1 ) )
550 AC 7 )=M4>C2
560 FOR  1 = 1  TO  2tK=s3*i:FOR  4=2  TO 3
570 M=H-«J-2)*W>:A*X< I )Ct J-2)
690 NEXT a
700 B( 2)=COINEXT J
730 B( 3 )=Y1< 1+2 )
740 FOR J»l  TO  3tL«l+< J-1)*3:A
-------
930 GOSUB 7000
¥35 N3--NN+2
940 FOR  1=1 TO N3
950 J=M-ItX=X<
960 If XCJKZS THEN  1000
970 Yl< J >=LOG< Y0( NF ) )/OG
980 GOTO 1100
iOOO H;EM
1010 YKJ )=B( I )
1020 FOR K=2  TO  4
i030 Y11 --I >=YU .3 >+B< K >*X< J >C < K-1 > IMEXT  K
1040 YK J >=LOG< Yi< J ) )/OG
iiOO NEXT I
illO IIsNP-NN-2
1120 XN=NP-1
1130 GOTO 630
1140 I5=NP-i
1160 FOR 1 = 1  TO  LA
1180 i:ti=LQGX(J>  THEN 1300
1220 XS=d-i
1230 J=MP
1300 N£XT J
1310 IF  XS<1  THEN  I5=1
1320 YB»CO< ISf 1 )+CO< IS»2)*D1+CO( IS>3
1330 BY»iOCYB
1340 LPRINT TABC6HXBaO THEN  5150
5120 BA-W I..I)
Si30 XK=I2
5150 NOT 12
5160 IF  ABS(BA)-TL>0 THEN 5200
5170 KS=i
5180 -J 2=3: GOTO 5393
5 2 00  11 = J2f 3*( .] 2-2 )
3210  rr=IH-J2
5220 FOR K2=J2 TO  3
5230  i;i=IH-3iI3=Ii-fIT
5240 SA=A< li )
5250 A-; II )=
-------
S3 40
3350
3360
3370
3380
3390
5392
5393
3398
3400
5410
5430
5440
5450
3460
5470
5480
5490
5500
7OOO
7005
70X0
7020
7030
7040
7050
7060
7070
7080
7090
7100
7120
7 130
7140
7145
7150
7160
7170
7130
7190
7200
7210
7230
7260
7300
7310
7320
7330
7350
7400
IZ=IG+IX
:r.T=-J2-IX
FOR JXsJY  TO  3
XX=3*< JX-i HIX
,n=xx+rr
A< XX )*A< XX )-< AC 12 >#A< JZ ) UNEXT JX
B< IX)=B#BC 1C)
IA=IA-3
IOIC-11NEXT  K2tNEXT J2
RETURN
REH ROUTrNE OSCFIT
PRINT " 7000" » TIME*.
NZ-NZ+i
LisXD-XXtL2s-Li:L3=Ll*LUL4=l.2#L2
L5»L3*LilLA=L4*L2
K1=YL/L3
K2=-2*YL/L5
K3=YH/L4
K4=-2*YH/L6
K5=DH/L3
BU)=K2+K4tK5
»< 3 )=< K14-K3-( 2*XX+XD )*< K2+K5 )-< 2#XIH-XX >*t K4 ) )
B< 2 )=< ( K2+K5 )*< C XX*XX )+2*XD*XX )-K K4 )*< ( XD*XE )+2*XB*XX ) )
B< 2)aB<2)-2*Kl*XX-2*K3*XD
B< 1 )=( Kl*( XX*XX )+K3*( XD*XD )-XD#< XX*XX )*< K2+K5 ) )-i XK*XD )*XX*( K4 )
X2=XB-S1
FOR  12=1  TO  100
X2=X2fSl
IF X2>XX  THEN  7250
YP»3#B<4 )#< X2*X2)+2*B( 3 )*X2+B< 2 )
     W4=OtlF
     NEXT 12
     IF  U4=i
     IF  NZ=1
     XX
     IF
        YP<0 THEN  XX=XX-ST t 12=100 tW4=l

        THEN U 4=0 1 GOTO 7030
        THEN 7400
    XX+STtST=ST/10
    ABS
-------
ii REH ---------- PROGRAM "JSKRAU" ----------------
3 CLS
10 CLEAR 4000
13 OG=LOG( 10>:i2»o:xX=0:XB»OJX2=Q:YP*OiST=OiNZ=0:XM=QlLX=0:Sl=QJYL=0:YM=QiDM=0;i
=OlL2~OtL3=OSL4=QlL5=Q
16 L6=OiKi=OtK2=OtK3=OJK4=OJK5=OtK6=0;.JY=OJ.J9=OtIT=OUJ=OtIH=OJIi=0
17 K2=o { 0=0 :TL=O : KS=O rsft=o : SA=O t IQ=O i ix=6 : 12=0 MX=O ; I A=O i ic=o t IB=O
20 DIM XM< iO)iYO< 10 )»X< 33 )» A< 16 )»B( 4 )iCQ< 50 > 3 )» Yl( 53>rXD< 15 ) » XCK 10»5Q )r YQ< 10, 50 1
Y2< 10 )»ID1K50)» JX<50 >»JY<50)»QCK 10»5Q)»JGK 10)»JW( 10 )
30 PRINT'PRQGRAM SPLIN2 FROM  FORTRAN ORIGINAL 02/22/82 VI"
31 LPRINT  " "ILPRINT  "  "i LPRINT TAB< 22 )» "SPLIN2 PROGRAM  -  02/22/82 Vl"tLPRINT  "

40 INPUPENTER * OF DATA SETS"»QW
45 PRIMT"EWTER B50' S  IN INCREASING SIZE"
46 PRIN^'The last entry inputted MUST be the  largest  psrliele diemeter   using t
e density  entered"
SO INP'Uf" ENTER NUHBER OF POINTS" JNF
35 FOR UV*1 TO UV
58 INPUT" SET ID=" ? IC$( tW )t INPUT  "PROCESS yGT.  RAT E< tons  P3VinS/hr )=" MXC QM )tINPt
 " TP EMISSION RATE < Ib/hr )=» MY( QM )
59 INPUT "ENTER  PARTICLE DENSITY ( S/ec > =" > JQ( QV ) 5 JW( QM )=SQR( JQ( QV ) )
60 POR 1=1 TO NF
70 INPUfENTER QSO» RAW LOADING FOR EACH POINT" »QQ< I»QV )»YQ( I »QV ) tXQ< 1 jQU >=JU< Q1,
80 PR1NT"SET *"»QMtNEXT QM
81 INPUT" ENTER  %  OF 050' S TO BE DETERMINED FOR  ALL  SETS"»LA
82 FOR  1=1 TO LAtINPUT"£NTER AERODYNAMIC B50" i XD< I )tNEXT  I
S3 FOR  «V*1 TO  UUIFOR  1 = 1 TO NF UN( I )=XQ< I >QV ) tY2( I )=YQ< I»QV )JNEXT I
84 PRINT  TIHEttLPRINT  TAB<6)»"TEST IDt  " i ID$< QM )t LPRINT  "  " ILPRINT TAB(6)I"INPU
 DATAt       PROCESS WEIGHT RATE ="»JX» "EMISSION FACTOR"
93 LPRINT TAB<6)f»CUT  < U8iA )    CUM, % < CUT     (LB/T)         ( KG/HT )" JLPRINT" '
100 N2=NF-2
110 FOR 1 = 1 TO  N2
120 JJ-N-1
130 XF N2-KO  THEN 150
140 JJaN+2
150 M-(I-1 )«N+1
X 60 X< H )=LOG< XN< I } )/QG
1 70 Y it M }=l,OG< Y0< I ) )/OG
ISO XI=< LUG( XN< 1 + 1 ) )/OQ~LOG( XN< I ) )/OG )/R
190 FOR 11 = 1 TO 3
200 Mrt=I~l-HI
210 E« II >*LOG< Y0< MM ) )/OG
220 K = 3*< 11-1 )
230 FOR J = l  TO  3
240 M3=I-1+J
250 A< K+J )=i LOQ( XH< H3  ) )/OG )C( II-U     H~6
260 NEXT  JtHEXT II
270 KS=0
280 GOSU0 3000
290 FOR .J = l  TO  2

-------
310 IF SL>=0 THEN  330
320 B< 2)=< LOG< ¥0< 1 + 1 )/YOC I ) »/QG/< LOGC XNC 1+1 >/XN< I ) )/QG KB( 1 )=LOG< Y0( I ) VOG-BC 2 >*
LOGtXNC I))/OG
330 £K 3)=OtJ=2
'350 NEXT  a
360 FOR J = l TO JJ
370 K=KKJ
"380 X< K)s»LUG< XNC I 5 >/OG+J*XI
390 Yl< K >=&< 1 )+B< 2 )*X< K )+B< 3 )#X< K )C2
400 NEXT  J I NEXT  I
410 FOR i = i TO 3
420 K«'i»< X-l)
430 FOR 4 = 1 TO 3
440 M=1-K J-i)#N
450 A*NIB< I >*Yl(M>iNEXT I
490 KS=0
500 QOSUP 5000
SiO SL=B< 2 H2«E<3 )#X< 1 )
520 IF SL>=0 THEN  600
330 FOR 1 = 1 TO 3JA< D=itNEXT I
340 A( 4 )«X< 1)-( X< N+l )-X< 1))
550 A< 7)-A< 4)C2
560 FOR 1 = 1 TO 2iK*3*ItFDR  J=2  TO 3
570 «=!+(( J -2) *M)IM KtJ )=X( H )C It NEXT  JJNEXT I
580 B< 1 )=Y1<1 )
590 FOR  1=2 TO 3tH=l+( t 1-2 )*N )SBC I )=Y1( H KNEXT I
5c/5 KS=O;GOSUB sooo
6OO FOR 1 = 1 TO 3
6 i 0 C<>( 111 )=B< 151 NEXT 1
615 11=1
620 1N=NP-N«-1
630 FOR l = U TO IN
640 JJ=i:BU)=0
6SO FOR J»2 TQ 3
660 K-I-I
670 IF 1*1 THEN K=I
680 B( 1 )=£« 1 )-f (.J-l )« C0< K> J ) )#X< I )C ( J-2 )
690 NEXT  ,j
700 B< 2)»COC< J-l >:NEXT'J
730 B< 3>sYKI+2 )
740 FOR  0 = 1 TO 3JL=1-K J-l )#3JIFJ*1THEMA( L )=OELSEA( L )=( J-l >*X< I )C< J-2 )
745 NEXT  J
730 FOR J = l TO 3:K=J-1IKK=3*K:A/OG
820 XI»08/RR
830 «=< HF-2 )*N+1
840 XD=tUOJ( XN< NF-1 ) )/OGiXH=LOG( XM( NF ) )/OG
850 NL=NP-NN
860 YL = 10tYl
-------
¥40 FOR  1 = 1  TO  N3
950 0««tX JXt J )=X( H >+I*XI
¥60 IF X(JXZS  THEN  1000
¥70 Yl< 0)=LOGO'Q/QG
V80 QOTQ 1100
1000 REM
1010 Yi(0 >=1C 1 )
1020 FOR K*2 TO 4
1030 Yl( 0 )=ri< J H-B< K )#X< J )C ( K-l ) tNEXT
1040 Yi< •) )-LOG< Yi( J 3 )/OG
1100 NEXT  1
iliO II=NP-NN-2
13.20 XN=NP-i
1130 UOTO  630
1140 I5=NP-1
iidO FOR 1=1 TO LA
1 .ISO ttl*LOU( XD< I 5 )/OG
1190 X3=NP-1
1200 FOR J = l TO NP
1210 IF  D1>X(J) THEN 1300
1220 IS=J-1
1230 .Jt=NP
1300 NEXT  J
1310 IF  IbXl THEN  IS=1
1320 YD=CO< ISrl )+CO< ISf2)*DH-CO< IS*;
1330 DY=HOCYB
1340 LPRINT  TAB<6)»XD< I )»TAB< 20 )5BY»TAB< 36 )>DY*JE/100ITAB< 50 )»0.005*DY«JE
1350 NEXT I
1360 LPRIMT11 "tLPRINT"  " I NEXT QV
1362 LPRIHT  rAB<6)5"END OF TEST SERIES"
1365 PRINT TIMEf
1370 PRINT  "END OF RUN"; END
3000 RE« ROUTIWE SIMQ
5010 TL=0
5O20 t\S=0
3030 09=-3
5040 FOR 02=1  T.Q 3
5O50 OY=02-H
5060 09=09+341
5080  IT=09-J2
5090  FOR  12=02 TO 3
sioo  i.j=rr+i2
Si 10  IF ABS( BA )-ABS< A( 1J))>=0 THEN 5150
5120 BA=W U)
5i30  iH=I2
5150  NEXT  12
5i60  IF ABS(BA)-TL>0 THEN 5200
5170 KS=1
5i80  02=31 QOTO 5395
5200  I1-J2+3K J2-2 )
5210  IT=IM-02                   '  '
5220  FOR  K2=,J2 TO 3
5230  Xl=Ii+3:i3--Il + IT
5240  SA=A< II }
5250  Adi )=A< 13)
5260  A(I3)«SA
3270  Adi )=M 11 )/BAiNEXT K2
5280 SA=Bf Ih)
52VO  E« IH )=»<: J2)
5300  BU'2)aSA/BA                       H-8
5310  IF .J2=3 THEN 5395
5320  Itt=3*( 02-1 )
5330  FOR  JX=.JY TO 3
3340  IZ

-------
5360  FOR  JX=JY  TO  3
3370  XXs3Hr-< A< IZ )*A( JZ »: NEXT JX
5392 BUX)«BUX)-B<02)*A< IZ>{NEXT IX
5395 NEXT -J2
5398  IF KS=1 THEN  5500
5400 NY=3-i
S410  IT-3*3
S420 FOR .;«2=1 TO NY
5430  Xft=IT-J2
5440  IB=3-J2
3430  IC=3
5460  FOR  K2=l TO J2
5470  &aB>=8«: IB)-A< IA )*B( 1C )
5480  IA=IA-3
5490  IOIC-UNEXT  K21NEXT J2
5500 RETURM
7000  H'EM  ROUTINE OSCFIT
7005 PRINT VOOOHfTIHEtJ
7010 W2=0*,ST=,lJXX=XrtlLX=XM-XD
7020 81=U/9?!G8=0
7O30  NZ-NZ-H
7040  Li=XB-XXtL2=-LltL3=Li5ScLllL4=L2#L2
7050 L5-L3*Llf,LA=L4*L2
7060  K1=YL/L3
7070  K2=-2*YL/L5
7080  K3»YH/L4
7090  K'4=-2¥YH/L6
7 100  K5=»J1/L3
7120  B<4)=K2+K4+K5
7 130  B(3 )=< Kl+K3-< 2*XX+XB )*< K2+K5 )-( 2*XD+XX )**< K4 ))
7140 B< 2 )=< < K2+K5 W ( XX*XX )+2*XB*XX )f < K4 )#( < XD*XD H2*XB*XX ) )
7145 B< 2)»B<2)-2»K1*XX-2*K3*XD
7150 B< 1 )«< Kl«< XX*XX H-K3W XE'STXIi )-XH*( XX*XX )*< K2+K5 ) )-< XDXXD )*XX*:( K4 )
7160 X2=XD-S1
7170  FOR  I2=i!Q 100
7180  X2=X2+S1
7190  IF X2>XX THEM 7250
7200  YP=3#B< 4 )#( X2*X2 )+2*P( 3 )*X2-i-B< 2 )
7210 y4=0?!F YP<0  THEN XX=XX-ST5I2=iOOlU4~l
7250 MEXT 12
7260  IF W4=l THEN  W4»OSGOTO 7030
7300  XF NZ=1 THEN  7400
7310  XX=XX+STtST=ST/iO
7320  IF ABS
-------
2 REM
3 REM       Pro sir am " JSKLOG" f 10/04/82
4 REM For use in  the  asphalt category report
5 REM in those cases  that 3 los-normal size ciistri-
6 REM bution is used  to characterize data.


10 CLE1AR 4000

=OtL2~OtL3~QtL4=OtL5=0

17 R2=0t 13-0 tTL=OtKS=QtBA=OtSA=OtIQ=QtIX=0; 12=0 tJX=OtIA=Q;iC=OJIB==0
20 »IN  XN( 10)rYO< 10 )»X< S3)fA( 16)»B<4)»CO< 5Qi3 )»Yl( 53 >»XD( 15 }»XQ( 10.50 )»YQ< 10»50)
Y2( 10 )»IB*< 5Q)»JX<50)fJY<50>fM( 10f50 )».JQ( 1Q)»4W( 10)
30 PRINT-PROGRAM  SPL1N2 FROM FORTRAN ORIGINAL  02/22/32  Ml"
31 LPRINT TAB(TAB<36)}DY*.JE/iOO»TAB<50)JO,005*DY*JEtNEXT Q%
V5  LPRINT "THIS DATA SET yAS FIT TO A LOG-NORMAL SIZE DISTRIBUTION" t EN£<
                                        H-10

-------
              APPENDIX I
DESCRIPTION OF TI-59 PROGRAM TO COMPUTE
 LOG-NOIMAL PARTICLE SIZE DISTRIBUTION
               1-1

-------
     Particle size data fitting a log-normal  distribution  yields  a, straight
line when plotted on log-probability graph  paper.   To  graphically determine
the mass fraction of particles smaller  than 15  \jt,m. in diameter,  the data
points would have to be plotted.  Then,  the best-fit Line  would be drawn
through the data points and the I?  fraction determined.  Such a graphical
approach is time consuming and requires  a subjective judgment in  drawing
the best-fit line through the data  points.

     Aa analytical technique utilizing  the  TI-59  programmable calculator
was developed as part of chis study.  The program transforms  both coordi-
nates into a linear format, as shouts in Figure  o»  and  then performs a stan-
dard linear regression analysis to  find the slope  and  intercept of the least
squares line fit to the data*  The  ordinate is  linearized  by  taking the log-
arithm of the aerodynamic particle  diameter*  The  abscissa or the probabil-
ity function is represented by the  integral
                                       C2/2
                                              dt
This* integral can not be solved explicitly,  but  can  be  approximated by

0 < F < 0.5  x • -t +   CQ -t- elt + c2t2      + e(F)j
                      1 4- d^t 4- d2tz 4- d3tj

0.5 < F < 1.0  x = t -   C° * Clt ^ °2t       + c(P),
                       1 4- d^t 4- d2t2 4- d3t3
The constants needed for  the probability function approximation are  given
in Table A-l.	       __      	      ..._ .      	       	,


                                                                  167
        TABLE A-l.  CONSTANTS USED IN THE LOG N01MAL DATA ANALYSIS—

h
Q
O
0
» 0.31938153
» -0.356563782
- 1.781477937
» -1.821255978
= 1.330274429
^0
C2
r
« 2*
= 0.
- 0.
» 0.
515517
802853
010328
2316419
d
d
d
C
3 "
I.
0.
0.
432788
1892 S9
0013 08
           :)| < 7.5 x 10"3                         |t(F)| < 4.5 x  10
-4
                                     1-2

-------
     Once the data points are transformed co  linear coordinates,  the stan-
dard linear regression function of  the TI-59  is  used to determine the slope
and intercept of the least squares  line  fie  through the data points.   The
mass median diameter is the anti-log of  the  y-intercept, as  shown in  Fig-
ure 6, and the geometric standard deviation  is the anti-log  of the slope.
the linear correlation coefficient  is also calculated*

     To find the nass fraction of particles  smaller than IS  urn,  the log of
15 (y -coordinate) is entered and the corresponding value of  the  x-coordinate
is computed using the least squares line previously determined.   This pro-
gram can be modified very easily if the  mass  fraction for another particle
cut size is desired.  The computed  x -coordinate  value is then converted
back to a mass fraction using Che following  formulas:
                         ""J      *S      /      Cf
x < 0  F - f (x)[bLt -I- b2e  4- b3e  +• b4e  + bjt ] 4- « 0  F = I - f (x)[blt 4- b2t  +• b3t  -f- b4t  4- b3t] 4 e
-------
Tm e
PROGRAMMER
                                    .PAGEJ	OF A     Ti Ftogrammable  ,J^
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-------
TITLE
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-------
im g
PROGRAMMER
                                   .PAGE_J	OF.

                                   _DATE o.-">!
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-------
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                                                         TEXAS INSTRUMENTS
                                         1-7

-------
               APPENDIX J
COMPUTER PRINTOUTS AND HAND CALCULATIONS
 (Included  In  Tables  3-16  through 3-26)
                  J-l

-------
       REFERENCE 1 DATA
(Ftom Tables  3-3,  3-4,  and 3-5)
              J-2

-------
TEST
INPUT DAT AI
                SPLIN2 PROGRAM - 02/22/32 Ml

             COUNTY  SUMMARY  TABLE  TEST C-369 SCRUBBER INLET

                  PROCESS WEIGHT RATE =113  TONS PROD, /HR
                  TOTAL PART'ICULATE EMISSION RATE = 352 LB/HR
                  PARTICLE DENSITY * 2.4  C/CC

         PARTXQ.E SIZE DISTRIBUTION

CUT 
CUT < u»A)
 15
CUM. '/. < CUT

  2S.6371
  35.2163
  38.5441
  49.4708
  60,3947
  70.8298
  73,9369
  79.0119
                                 EMISSION FACTOR
                              < LB/T )         (KG/HT)
                               .392744
                               1.097
                               1.20067
                               1.34104
                               1.88735
                               2.20633
                               2.36547
                               2,46123
.446372
.548502
.600333
.770318
.943776
1.10319
1.13273
1.23063
    OK TEST SERIES
                                  3-3

-------
                SPLIN2  PROGRAM  -  02/22/32 VI

TEE'L IB I   LA COUNTY  SUHMARY TABLE TEST  C-369  SCRUBBER  OUTLET
XKPili" DATftt
     PROCESS WEIGHT RATE  =113   TONS PROD,  /HR
     TOTAL PARTICIPATE  EMISSION 'RATE = 24,4 LB/HR
     PARTICLE DENSITY =2,4   G/CC
CUT (urn.)


 20

 74


OUTPUT CATAI
         BARTXCI.E SIZE DISTRIBUTION

            RAW 7. < CUT     CUM. % <  CUT
               79,9
               3.8
               2
               14.3
                    79.9
                    83.7
                    13.7
                    100
                TP EMISSION FACTOR =   ,213929   LB/T  <   ,107965  KG/HT)
CUT <
CUH. % < CUT
                                 EMISSION  FACTOR
                              C LB/T )        < KG/MT >
..A23
i
i,25
2.5
S
i<< . .
is
20
44,9872
52,4434
55,0381
62.9364
70,2577
76,3667
79,6239
81.4592
.101459
,113241
.113843
,135898
.151707
.16533
.171931
.175894
.0307295
.0566205
.0594217
.067949
.0758534
.082665
,0859636
,0879471
END .Or' TEST SERIES
                                 J-4

-------
                3PI.IN2  PROGRAM  - 02/22/82 VI

TEST mi  LA COUNTY  SUMMARY TABLE  TEST  C-372A  SCRUBBER INLET
IHI*\J f & AT A*.
     PROCESS WEIGHT RATE  a  138   TONS PROD,  /HR
     TOTAL PARTICULATE EMISSION  RATE = 76 LB/HR
     PARTICLE DENSITY = 2.4   5/CC
HCABIWSD PARTICLE SIZE DISTRIBUTION

CUT (um)    RAW '/. < CUT     CUM. % <  CUT
                                 78
                                 96
                                 98
                                 100
i<>
2u
44
74
78 ,
18 .
2
2
&ATAI
   TP EMISSION FACTOR
                                       .431013   LB/T  (   .240504  KG/MT )
CUT (umA)
CUM. Y. < CUT
                          EMISSION FACTOR
                       
-------
                3PLJCN2  PROGRAM  -  02/22/32 VI

TEST X»l.  LA COUNTY  SUMMARY TABLE  TEST  C-372A  SCRUBBER  OUTLET

XN»»ur DATA:       PROCESS WEIGHT  RATE  =  iss   TONS  PROD,  /HR
                  TOTAL PARTICULARS EMISSION  RATE  =  10 LB/HR
                  PARTICLE DENSITY = 2,4   G/CC

tis£A;iLi«£r< PARTICLE SIZE  DISTRIBUTION

CUT (urn)    RAM % <  CUT    CUM*  % < CUT
 44
 74
               83
                 33
                 33
                 39
                 100
OUT PUT BAT Ai
TP EMISSION FACTOR -  ,0632911  LB/T  (   ,0316456   KG/MT)
CUT < u»A)

 20
CUM. V. < CUT

  34.8733
  42,0797
  45»6662
  37,1342
  63,3063
  78*0367
  32.60O4
  83.1924
                 EMISSION FACTOR
              
-------
                3PLIN2 PftQGRftH - 02/22/82 VI

TEST X&i  LA COUNTY  SUMMARY TABLE   TEST C-372B SCRUBBER INLET

XHr'iJ? riATAl       PROCESS  WEIGHT RATE a 142.9  TONS PROD. /HR
                  TOTAL PARTICULATE  EMISSION RATE a 121 LB/HR
                  PARTICLE DENSITY = 2.4  G/CC
         PARTICLE SIZE DISTRIBUTION

CUT     RAM % < CUT      CUM,  % < CUT
.to
20
44
74
 9
*.0i
*.0i
                                 90.9818
                                 99,93
                                 99.99
                                 100
     r BATAI    TP E?iis3iQN FACTOR  »  ,344744  LB/T  c   ,422373  KG/«T>
CUT < urn A )
 .623
 '.'0
 •>•* w
            CUH. % < CUT
                    EMISSION FACTOR
                 LB/T >         (KG/MT)
ia.496a
26.2783
30 '.6033
46»37o9
64 » 3333
81,7232
90,2349
95.0498
.156621
,222512
,259177
,392695
. 544736
,692005
.76406
.804331
.0733103
.111256
.129533
.196347
.272393
.346003
.33203
.402415
    OF TEST SERIES
*  Model will not accept zero values.
                                  J-7

-------
                 3PLIN2 PROGRAM  - 02/22/32 VI

TEST IB I  LA COUNTY  3UMNARY TABLE   TEST  C-372B  SCRUBBER OUTLET
ItoVrUf ft AT A i
                  PROCESS WEIGHT RATE »  142.9   TONS  PROD.  XHR
                  TOTAL PARTICULARS EMISSION RATE -  If.2 LB/HR
                  PARTICLE DENSITY =2,4  G/CC
         PARTICLE SIZE BX3TRIBUTIQN

cur     RAy •/. < CUT     CUM,  % <  CUT
                                  82
                                  85
                                  87
                                  100
iu
20
44
74
82
3
2
13
OUTPUT DATA I
                TP EMISSION FACTOR
                          .13436   LB/T   <   ,0471799   KC/MT)
CU?
     uraA )
CUH* 7.
CUT
  EMISSION FACTOR
LB/T 5        ( KG/MT )
.623
;i.
:U25
2.S
',1
iu
_i5 . 	
20
37.3976
61 .6263
63.6338
69.5435
74.9027
79.2144
• ai-W-912
83.1956
.0771192
.0823412
.0355043
.0934334
.100639
. 10633S
	 .109894-
.111731
.0335596
.0414206
.0427524
.0467192
.0503195
.0534176
..—..0549472,
.0558907
 IIWO (Vf TEST SERIES
                                  J-8

-------
                SPLIN2 PROGRAM  - 02/22/82 VI

TEST XJ>i  LA COUNTY  SUMMARY TABLE  TEST  C-422< 1)  SCRUBBER  OUTLET
XHr-Uf &ATAI
  PROCESS WEIGHT RATE - 198  TONS PROD,  /HR
  TOTAL PARTICIPATE EMISSION RATE =26.6 LB/HR
  PARTICLE DENSITY =2.4  G/CC
         PARTICLE SIZE DISTRIBUTION

r.ur"    RAW y. < CUT     CUM. % <  CUT

 iu            73.2              73.2
 .20            3.1               73»3
 44,            4.5               32*3
 74  ...         17.2              100
flUfPUf DATA!
TP EMISSION FACTOR =   ,134343  LB/T   C   .0671717   KG/MT)
GUf < umA
CUH. 7.
      CUT
   EMISSION FACTOR
< LB/T )        
-------
                 3PLIM2  PROGRAM  -   02/22/82 VI
TEST ID',  i960 LOS ANGELES COUNTY  TEST*C-426  VENT  LINE
INPUT DATAI
                   PROCESS  WEIGHT RATE * 132  TONS PRQB./HR
                   TOTAL  PARTICIPATE EMISSION RATE = 2000  LB/HR
                   PARTICLE DENSITY  = 2,4   S/CC
MEASURED SIZE DISTRIBUTION
CUTCusn)
               CUM.  %  <  CUT
 10
 15
 20
 30
 40
 50
 60
                   19.3
                   39.7
                   52.7
                   60.7
                   74
                   81.6
                   85.8
                   88
OUTPUT DATA:    TP EMISSION FACTOR =   10.939   LB/T  <   5.49451   KG/MT)
CUT (uis.A>

 .625
 1
 1.25
•2.5
 13
 20
CUM. X < CUT

 9.34642E-03
 .0701322
                                   EMISSION  FACTOR
                                
-------
                  SPLIN2 PROGRAM -  02/22/82 VI


 TEST IDS  i960 LOS  ANGLES  COUNTY   TESTiC-426  CYCLONE OUTLET

 INPUT DATA:       PROCESS  WEIGHT  RATE = tS2  TOMS PRGD./HR
                   TOTAL  PARTICULATE EMISSION RATE = 2620  LB/HR
                   PARTICLE DENSITY =2.4   G/CC

* MEASURED SIZE DISTRIBUTION

 CUTCunO        CUM.  7.  <  CUT
  10
  15
  20
  30
  40
  50
  60
                    5.4
                    10.3
                    14.3
                    17.8
                    23.4
                    33,8
                    44 .6
                    51.1
 OUTPUT OATAt
                  TP  EMISSION FACTOR =  14.3956  LB/T  <   7. If 78   KG/MT)
CUT CumA)
CUM.
                        CUT
.625
1
1.25
'2.5
5
10
15
20
.0221413
.0894864
.163537
.833455
2.9282
6.92055
9.95612
12.6159
 END OF TEST SERIES

* Particles > 60 pmS and 3-4
  of text) ..
                                     EMISSION FACTOR
                                  (LB/T)        (KG/MT)
                                3»18737E-03
                                 .0128821
                                 .0235494
                                 .119981
                                 .421532
                                 .996256
                                1,43324
                                1.81613
                                               1.59368E-03
                                               6.44105E-03
                                               .0117747
                                               .0599904
                                               .210766
                                               .498128
                                               .716622
                                               .908065
                            not used as  Input to model  (see Section 3.5.2
                                  J-ll

-------
                  SPLIN2 PROGRAM -  02/22/82
 TEST ID:  I960  LOS  ANGELES  COUNTY  TEST*C-426  CYCLONE INLET
 INPUT  DATA:
    PROCESS WEIGHT RATE =  132   TONS  PROO./HR
    TOTAL PARTICIPATE EMISSION  RATE  =  6700   LB/HR
    PARTICLE DENSITY =2.4   G/CC
* HEASURED SIZE  DISTRIBUTION
 CUT(un»)
  10
  IS
  20
  30
  40
  50
  60
 CUM, % < CUT

     1.5
     10,1
     21,1
     27*8
     32,1
     40.8
     47.7
     53.5
     56.6
  OUTPUT DATA',
  TP EMISSION FACTOR  =   36.3132  LB/T  <   18.4066  KG/MT)
 CUT  (umA)

   ,625
   i
  •1.25
   Z..5	_
   5
   10
   15
   20
CUM. % < CUT

 4.02547E-03
 .03184
 .07707
 .....80332-	
 4,55354
 13.7273
 20,4088
 2S.2256
  END  OF  TEST  SERIES
    EMISSION
 (LB/T)

1.4819E-03
,0117213
.0283719
..295728
1,67315
5.05344
7,51313
9,28636
FACTOR
  60 fmS and 3-4 pmS not used as input to model (see Section 3.5.2
  of text) .
                                   J-12

-------
                 SPLIN2 PROGRAM -  02/22/32 VI
 TEST IDt  i960 LOS ANGELES COUNTY  TEST*C-393  SCRUBBER INLET
 INPUT DATA:
    PROCESS UEIGHT RATE =92.3  TONS PRQB./HR
    TOTAL PARTICIPATE EMISSION RATE = 4260  LB/HR
    PARTICLE DENSITY = 2.4   C/CC
 MEASURED SIZE DISTRIBUTION

 CUTCuni)        CUM, % < CUT
  10
  20
  44
  74
     13
     84*1
     93.7
     100
 OUTPUT DATA:    TP EMISSION FACTOR =  46*1533  LB/T  <   23.0/6?  KG/MT>
 CUT CumA)

  ,625
  i
  5
  10
  15
  20
CUH» 7. < CUT
 2»16E-09
 4E-08
 1.12E-04
 .0449
 2»8
 13.9
 30.8
    EMISSION
 (LB/T }

1.02E-12
9.96923E-10
1.84615E-08
5*16923E-05 '
.0207231
1.29231
6.41538
14.2154
DATA SET WAS  FIT TO A LOG-NORMAL  SIZE DISTRIBUTION
FACTOR
 (KC/MT)

 5.1E-13
 4.98462E-10
 9.23077E-09
 2.58462E-05
 .0103615
 .646154
 3.20769
 7.10769
                                  J-13

-------
    REFERENCE 3 DAfA




(Froa Tables 3-6 and 3-7)
          J-14

-------
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IO.L,
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42-4-
60.0
•
                 J-15

-------

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        = 0-2.
                0.7-
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40.6

-------
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-------
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               J-18

-------
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-------
                SPLIN2 PROGRAM -  02/22/82
PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST ID I   GERMAN STUDY  PLANT ID NO. A4  CYCLONE INLET
INPUT DATA*
    PROCESS  WEIGHT  RATE -  0  TONS PRQB./HR
    TOTAL PARTICULATE  EMISSION  RATE  = 0   LB/HR
    PARTICLE DENSITY = 2.4  G/CC
HEASUREII SIZE DISTRIBUTION

CUT76074E~04
 3.33E-03
 7.69273E-03
 .0727647
 .402899
 1.30589
 2.02467
 2.46845
 END  OF  TEST  SERIES
                                 J-20

-------
                SPLIN2 PROGRAM - 02/22/82
PROCESS DATA NOT AVAILABLE* EMISSION FACTOR DIRECTLY INPUT
TEST lOt   GERMAN STUDY  PLANT ID NO, A4  CYCLONE OUTLET
INPUT DAT At
     PROCESS UEIGHT RATE = 0  TONS PROD,  /HR
     TOTAL PARTICULATE EMISSION RATE = 0  LB/'HR
     PARTICLE DENSITY =2,6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT zu
 5
 10
 15
 20
CUM, 7. < CUT

  1,01021
  1.81471
  2,35923
  4,99792
  9,60428
  16.7416
  22,1483
  26,4721
   EMISSION FACTOR

-------
                SPLIN2 PROGRAM -  02/22/32 Ml
PROCESS DATA NOT AVAILABLE? EHISSION FACTOR DIRECTLY  INPUT
TEST IB!   GERMAN STUBY  PLANT ID NO, 01  CYCLONE INLET
INPUT DATAJ
   PROCESS WEIGHT RATE = 0  TONS PRGD./HR
   TOTAL PARTICULATE EMISSION RATE = 0  LB/HR
   PARTICLE DENSITY = 2,6  C/CC
MEASURED SIZE DISTRIBUTION
CUT< urn)

 5*1
 7v2
 .10.2
 14.4
 20.4
 28*8
 40.8
 57.7
 74
CUM
CUT
    7
    13.1
    18.2
    22.8
    26.7
    28*8
    32
    38*2
    100
OUTPUT DATA:
 TP EMISSION FACTOR =  42  LB/T  (  21  KG/MT )
CUT (umA )

 ,623
 1
 1.25	

 5
 10
 15
 20
              CUH.  '/» <  CUT

               4.90417E-06
               2.26465E-04
               1.14969E-03.
               ,0303031
               1.67117
               10.362
               16*3908
               20.8641
                    EMISSION FACTOR
                 
                2.05975E-06
                9.51154E-05
                4.3287E-0.4
                .0337273
                .70139
                4,35205
                7.09415
                8,76291
                      1.02988E-06
                      4.75577E-05
                      2.4U35E-04-
                      .0168637
                      .350943
                      2,17602
                      3,54708
                      4,38146
 END  OF TEST SERIES
                                 J-22

-------
                SPLIN2 PROGRAM - 02/22/82  VI
PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY  INPUT
TEST iDt   GERMAN STUDY  PLANT ID NO, Di'  CYCLONE OUTLET
INPUT DATA:
     PROCESS WEIGHT RATE =  0   TONS  PROD*  /HR
     TOTAL PARTICULATE EMISSION  RATE =  0  LB/HR
     PARTICLE DENSITY =2,6 C/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW % < CUT     CUM, 7. < CUT
 10
 20
 40
 74
  18.2
  8.5
  5.3
  68
   13*2
   26.7
   32
   100
OUTPUT DATA:    TP EHISSIQN FACTOR =  5.24  LB/T  c  2,62  KG/MTJ
CUT < umA )
 »625
 1,25
 2,5
 10
 15
 20
CUM. % < CUT

  .203426
  .512838
  ,770132
  2,3319
  6.0183?
  12.4233
  17.2S45
  20.9505
   EMISSION FACTOR
tLB/T )        ( KC/MT )
 .0106595
 .0263753
 .0403549
 .124811
 ,315364
 ,650982
 .905708
 1,09781
5.32977E-0;
,0134377
.0201775
.0624057
.157682
.325491
. 452854
.548904
END OF TEST  SERIES
                                J-23

-------
                SPLIN2 PROGRAM -  02/22/32 VI
PROCESS DATA NOT AVAILABLE* EMISSION FACTOR DIRECTLY INPUT
TEST ID*.   GERMAN STUDY  PLANT ID NO. H2  CYCLONE INLET
INPUT DATAJ
    PROCESS UEIGHT RATE = 0  TONS PROD./HR
    TOTAL PARTICIPATE EMISSION RATE = 0  LB/HR
    PARTICLE DENSITY =2.6  G/CC
MEASURED SIZE DISTRIBUTION
CUT(urn )

 5.1
 7.2
 10.2
 14.4
 20.4
 28»8
 40.8
 57.7
 74
 CUM* % < CUT

     8.7
     17
     23.4
     27.6
     33*4
     36.2
     45.9
     59.1
     100
OUTPUT DATA:
  TP EMISSION FACTOR =  24.6  LB/T  (  12.3  KG/MT)
CUT < uiftA )
 1
 1.25
 2.5
 5
 10
 15
 20
CUM. 7. < CUT

 8.47661E-07
 6.96892E-05
 .0575943
 1.78027
 13.2326
 21*8806
 25*7017
  -  EMISSION  FACTOR
 < LB/T )        (KG/MT)
2.08525E-07
1.71435E-05
TT10635E=04
.0141682
.437947
3.26751
5.38262
6.32261
1.04262E-07
8»57177E-06
5.53175E-05"
7.08409E-03
.218974
1.63376
2.69131
3.16131
END OF TEST SERIES
                                 J-24

-------
                SPLIN2 PROGRAM - 02/22/32 Ml

PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY  INPUT
TEST IDt  GERMAN STUBY  PLANT ID NO. H2  CYCLONE OUTLET
 INPUT DATAt
      PROCESS  WEIGHT  RATE =  0  TONS PROD.  /HR
      TOTAL PARTICIPATE EMISSION  RATE  = 0  LB/HR
      PARTICLE DENSITY =2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT 
-------
                SPLIH2 PROGRAM -  02/22/82 Ml
PROCESS DATA MOT AVAILABLE* EMISSION FACTOR DIRECTLY INPUT
TEST 101  GERMAN STUDY  PLANT ID NO. 12  CYCLONE INLET
INPUT D
     PROCESS WEIGHT RATE » 0  TONS PRQB,/HR
     TOTAL PARTICIPATE EHISSION RATE a 0  LB/HR
     PARTICLE DENSITY * 2,9  G/CC
MEASURED SIZE DISTRIBUTION

CUTCutn)        CUM. X < CUT
  4,8
  6.3
  9,6
  13.6
  19,2
  27,2
  38.4
  54.3
  74
      10,8
      14
      17.2
      25.1
      34.5
      38*5
      47,2
      64,1
      100
OUTPUT BATAt    TP EMISSION FACTOR =  42,2  L3/T  (  2J.I  KG/WTJ
CUT 
-------
                SPLIN2 PROGRAM - 02/22/82 Mi
PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST ID?   GERMAN STUDY  PLANT ID NO* 12  CYCLONE OUTLET
INPUT DATA:
     PROCESS WEIGHT RATE = 0   TONS  PROD,  /HR
     TOTAL PARTICULATE EMISSION RATE =  0  LB/HR
     PARTICLE DENSITY =2.6 G/CC
HEASUREH PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW % < CUT.     CUM, % < CUT
 10
 20
 40
 74
  17*2
  17*3
  12.7
  52,3
   17.2
   34,5
   47.2
   100
OUTPUT DATAJ
   TP EMISSION FACTOR
        1.12  LB/T
                                                     .56  KG/HT )
CUT < umA )
 .625
 2,5
 5
 10
 15
 20
CUM* % < CUT

  3.99466E-03
  .0225395
  .0481914
  .396545
  2,2256
  8.51994
  15*6471
  22.2464
   EMISSION FACTOR
( LB/T )  .      (KG/MT )
 4.47402E-05
 2.52442E-04
 5.39744E-04
 4.4413E-03
 .0249268
 .0954234
 .175247
 ,249159
2.23701E-05
1.26221E-04
2.69872E-04
2.22065E-03
.0124634
.0477117
.0876236
.12453
END OF  TEST  SERIES
                                J-27

-------
                SPLIN2 PROGRAM -  02/22/82
PROCESS PftTA NOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST IB I  GERMAN STUBY  PLANT IB KG. 13  CYCLONE IMLET
INPUT QftTAt
   PROCESS WEIGHT RATE - 0  TONS PROB./HR
   TOTAL PARTICULATE EMISSION RATE = 0  LB/HR
   PARTICLE DENSITY =2.7  G/CC
MEASURES SIZE DISTRIBUTION
    UB. )
  5
  7,1
  10
  14.1
  20
  28.3
  40
  56.6
  74
CUM, "L < CUT

    13.7
    29,1
    40.9
    49.2
    58*1
    64.7
    70.2
    30.9
    100
OUTPUT BATAS    TP EMISSION FACTOR =  29,4  LB/T  (   14,7  KC/MT)
CUT (unA)    .CUM. % < CUT
                    EMISSION FACTOR
                 (LB/T)       (KG/MT)
.425
1 '
— 	 	 l-*25" 	
-i. *%*
5
10
15
20
.1»90208E-07
2.68464E-05
--2.17566E-04- "
,0502156
2.33869
21.9781
38,0358
45.6821
5.5921E-08
7.892S4E-06
6.39644E-05
.0147634
,687574
6.46156
11.1325
13.4306
2.79605E-08
3.94642E-06
3.19822E-05
7.3817E-03
,343787
3.23078
5.59126
6.71528
END OF TEST SERIES
                                        J-28

-------
                SPLIN2 PROGRAM - 02/22/32 VI
PROCESS DATA NOT AVAILABLE? EMISSION FACTOR  DIRECTLY  INPUT
TEST ID:  GERMAN STUDY  PLANT ID NO. 13  CYCLONE OUTLET
 INPUT DATA:
      PROCESS WEIGHT  RATE = 0  TONS PROD,  /HR
      TOTAL PARTICULATE  EMISSION  RATE  = 0  LB/HR
      PARTICLE DENSITY =2,6  G/CC
MEASURED- PARTICLE SIZE DISTRIBUTION

CUT (UA)    RAW % < CUT     CUH» 7. < CUT
 10
 20
 40
 74
  40.9
  17.2
  12.1
  29.8
   40.9
   58*1
   70.2
   100
OUTPUT DATAt     TP EMISSION FACTOR =  2,3  LB/T  <  1.4  KG/MT)
CUT < umA )
 .625
 1
 1,25
 2.5
 5
 10
 15
 20
CUM. X < CUT

  .910363
  1,9668
  2.76234
  7.12934
  15•6506
  29.2229
  39.0639
  46.4114
   EMISSION FACTOR
( LB/T )        < KG/MT )
 .0254902
 ,0550703
 .0773456
 .199622
 ,438218
 .818241
 1.09379
 1.29952
.0127451
.0275352
.0386728
,0998108
.219109
.409121
,546895
.64976
END OF TEST SERIES
                                J-29

-------
                SPLIN2  PROGRAM -  02/22/82  Mi
PROCESS DATA NOT AVAILABLE! EMISSION  FACTOR  DIRECTLY  INPUT
TEST ID:  GERMAN STUOY  PLANT ID NO*  02  CYCLONE  INLET
INPUT DATA:
    PROCESS yEIGHT RATE = 0  TONS PROEU/HR
    TOTAL PARTICIPATE EHISSION RATE = 0  LB/HR
    PARTICLE DENSITY = 2.9  G/CC
MEASURED SIZE DISTRIBUTION
CUT
-------
                SPLIN2 PROGRAM - 02/22/S2 Ml
 PROCESS DATA NOT AVAILABLE; EMISSION  FACTOR  DIRECTLY  INPUT
 TEST ID:  GERMAN STUDY  PLANT ID NO.  02  CYCLONE OUTLET
 INPUT DAT At
   PROCESS WEIGHT RATE  =  0   TONS PROD*  /HR
   TOTAL PARTICIPATE EMISSION RATE = 0  LB/HR
   PARTICLE DENSITY = 2,6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT     RAW 7. < CUT     CUM* % < CUT
 10
 20
 40
 74
41*1
24,3
3.7
30,9
                                41.1
                                65*4
                                69*1
                                100
OUTPUT OATA:
 TP EMISSION FACTOR =  7.54  LB/T   (  3*77   KG/MT)
CUT (
 ,625
1  *>*
1 t •£«
2,5
5
10
15
20
CUM. 7. < CUT

  .0197552
  .104072
  .214452
  1..54576
  7*39811
  23.5107
  38.2438
  49.6107
                  EMISSION FACTOR
               
-------
                 SPLIN2 PROGRAM -  02/22/32 VI
 PROCESS BATA  NOT  AVAILABLE!  EMISSION  FACTOR DIRECTLY INPUT
 TEST IZU GERMAN  STUBY   PUNT  10 MO*  Cl   CYCLONE IMLET
 INPUT DATA:
     PROCESS WEIGHT  RATE  =  0   TONS PRQB./HR
     TOTAL  PARTICULATE  EMISSION  RATE = 0   LB/HR
     PARTICLE DENSITY = 2,5   G/CC
 MEASURES SIZE  DISTRIBUTION
 CUT< urn )
 CUH, I  <  CUT
  5.2
  7,4
  10,4
  14,7-
  20,8
  2?, 4
  41.6
  53.S.
  74
      6.9
      13,8
      22
      29 .6
      37,2
      45,9-
      54,7
      74, t-
      100
 OUTPUT  DATA;    TP EMISSION  FACTOR -  72.6   LB/T  c   34,3  KG/MTJ
CUT
  .425
 2,5
 5
 10
 15
 20
CUH. % < CUT

••6.75344E-05
 l'.29393E-03
 .13771?
 U8074
 10.4073
 19,7365
 2A.2973
ENB OF  TEST SERIES
    EMISSION FACTOR
 (LB/T)       
-------
                SPLIN2 PROGRAM - 02/22/32
PROCESS DATA NOT AVAILABLEI EMISSION FACTOR  DIRECTLY  INPUT
TEST ID:  GERMAN STUBY  PLANT ID NO. Cl  CYCLONE OUTLET
INPUT DATA;
     PROCESS WEIGHT RATE  *  0   TONS PROD,  /HR
     TOTAL PARTICULATE EMISSION  RATE  =  0  LB/HR
     PARTICLE DENSITY =2*6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT     RAW % < CUT     CUM. 7. < CUT
 10
 20
 40
 74
  22
  15,2
  17.5
  45.3
           37.2
           54,7
           100
OUTPUT DATA:
   TP EMISSION FACTOR «  3.54   LB/T   (   1.77
                                                            KG/MT )
CUT (
,625
1
1,25
2,5
5
10
15
20
CUM. %

  ,290619
  .656995
  .946186
  2.67886
  6.59549
  14.121
  20*6603
  26.291
           EMISSION FACTOR
CUT     (LB/T)        ( KG/MT )
                               ,0102879
                               .0232576
                               ,033495
                               .0948318
                               »23348
                               ,499884
                               ,731376
                               .930703
                       5.14396E-0;
                       .0116288
                       .0167475
                       ,0474159
                       .11674
                       .249942
                       .365683
                       .465351
    OF TEST SERIES
                                J-33

-------
                SPLIN2 PROGRAM -
                    02/22/82
PROCESS DATA NOT AVAILABLE! EMISSION FACTOR DIRECTLY INPUT
TEST ID:  GERMAN STUDY  PLANT ID NO, C2  CYCLONE INLET

INPUT DATAS       PROCESS WEIGHT RATE - 0  TONS PRQB,/HR
                  TOTAL PARTICIPATE EMISSION RATE ~ 0  LB/HR
                  PARTICLE DENSITY = 2.5  G/CC

MEASURED SHE DISTRIBUTION
CUT(uift)

  5,2
  7,4
  10,4
  14,7
  20,8
  29,4
  41,6
  58,3
  74
 CUM, 2 < CUT

     7,6
     16,9
     24.9
     31,7
     37,4
     42,6
     56.9
     58,9
     100
OUTPUT  D3TA',
  TP EMISSION FACTOR =  72.2  LB/T  (   36,1  KG/MT!
CUT (unA)
  ,625
 2t-3
 5
 10
 15
CUM, % < CUT

 1.04337E-07
 l,41687E-05
 1.13451E-04
 ,0238845
 1,23919
 12.4481
 22,3192
 23.8498
    EMISSION FACTOR
 (LB/T)       < KG/MT)
7.53311E-08
1.02298E-05
8.19113E-05
,0186886
,394697
8,98751
16,4754
20,3295
3.76655E-08
5,11489E-06
4.09557E-05
9.34432E-03
,447348
4,49374
8,23772
10,4148
END OF  TEST  SERIES
                                        J-34

-------
                SPLIN2 PROGRAM - 02/22/82 VI

PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST int  GERMAN STUDY  PLANT ID NO* C2  CYCLONE OUTLET
INPUT DATA:
     PROCESS WEIGHT RATE =  0   TONS  PROD*  /HR
     TOTAL PARTICIPATE EMISSION  RATE  -  0  LB/HR
     PARTICLE DENSITY = 2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAM % < CUT     CUM. % < CUT
 10
 20
 40
 74
  24,9
  12,5
  13,5
  45.3
  25.8836
  38 * 8773
  52.9106
  100
OUTPUT DATA:     TP EMISSION FACTOR =  4.1  LB/T  c  2»os  KG/MT>
CUT < urnA )
CUM. 7. < CUT
  EMISSION FACTOR
LB/T )        ( KG/MT )
,625
1
1,25
2.5
5
10
15
2.0
1.03112
1.S791
2,45924
5,31454
10.4065
18.4638
24.6679
--- 29,6832
.0422761
.0770431
. 100829
.217896
.426667
,757015
1,01138
1.21701
,021138
,0385216
.0504144
. 108948
.213334
. 378507
,505692
,608506
END OF TEST SERIES
                                 J-35

-------
                 SPLIN2 PROGRAM  -  02/22/82
PROCESS BftTA MOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST 10:  GERMAN STUDY  PLANT  ID NO. BS  CYCLONE  INLET
INPUT DATA:
PROCESS HEIGHT RATE = 0  TONS PROD./HR
TOTAL PART1CULATE EHISSION RATE = 0  LB/HR
PARTICLE DENSITY » 2.6  G/CC
HEASUREB SIZE BISTRIBUTIQH

CUTCum)        CUM. I <  CUT
 54
 7.2
 10,2
 14.4
 20,4
 28.3
 40,8
 57,7
 74
 4.2
 7.7
 12,5
 18.3
 25,4.
 32.7
 41,4
 56.7
 100
OUTPUT  BftTAJ    TP EMISSION  FACTOR =  93,4   LB/T   (   46,7  KG/MT)
CUT
 1  '
 1,25
 2.5
 10
 15
 .CUM. % < CUT

  -8.4312E-04
  6.72639E-03
—,0166124
   ,196869
   1,4032
  6.01537
   11.1082
   15.6364
                 EHISSIQN FACTOR
              (LB/T)       (KG/HT)
             7.87474E-04
             6»23245E-03
            "7015316
             .133875
             1,31059
             5.61335
             10,3751
             14.6044-
3.93737S-04
3.14123E-03
7.7530"IE-0~3~
.0919377
,655294
2,30913
5,18753
7.30213
    OF TEST SERIES
                                        J-36

-------
                SPLIN2 PROGRAH - 02/22/32 VI
PROCESS HATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST IB:   GERMAN STUBY  PLANT IB HO. B3  CYCLONE OUTLET
INPUT BATA:
                 PROCESS WEIGHT RATE = 0  TONS PROD, /HR
                 TOTAL PARTICULATE EMISSION RATE = 0 LB/HR
                 PARTICLE DENSITY = 2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW % < CUT     CUM, % < CUT

               12.5
10
20
40
74
               12.9
               16
               58.6
   12.5
   25.4
   41.4
   100
OUTPUT DATA:
               TP EMISSION FACTOR *  2.44  LB/T  (   1.22  KG/MT)
CUT 

 ,625
 t
 1.25
 2.5
 5
 10
 15
 20
            CUM.  % < CUT

              .0237498
              .0793193
              .13571
              .622023
              2.28689
              6.74413
              11.4626
              15.9533
   EMISSION FACTOR
< LB/T )        < KG/MT)
 5.79495E-04
 1.93539E-03
 3.31132E-03
 .0151774
 .0558001
 .164557
 .279687
 .389261
2.89748E-04
9.67696E-04
1.65566E-03
7.58863E-03
.0279
.0822784
.139843
.19463
END OF TEST  SERIES
                                 J-37

-------
                SPLIN2 PRQGRAH -  02/22/32 VI
PROCESS DATA NOT AVAILABLE; EMISSION FACTOR DIRECTLY INPUT
TEST IDt  SERHAM STUDY  PLANT ID HO, B4  CYCLONE INLET
INPUT DMA:
    PROCESS WEIGHT RATE * 0  TOMS PRQD./HR
    TOTAL PARTICUUTE EMISSION RATE = 0  LB/HR
    PARTICLE DENSITY a 2,3  G/CC
MEASURED SIZE SISTRIBUTIQN
CUT(um)

 4,9
 6,9
 9,3
 13,9
 19,6
 27,7
 39,2
 55,4
 74
 CUH» I < CUT

     15,9
     26,8
     41,5
     53.8
     61,5
     67,6
     72
     80,6
     100
OUTPUT DATA;    TP EMISSION FACTOR =  149,2  LB/T  <   74.6  KC/MT>
CUT (unA)

  ,625
 1
 1,25  	
 2,5
 3
 10
 15
 20
EHB OF TEST SERIES
CUM, X < CUT
   EMISSION FACTOR
(LB/T)       ( KG/HT)
-,015282
.0809016
, 167706
1.25014
6,33009
21.7722
37,7312
48.886
,0228008
,120705
	 ,250218
1,86521
9,4445
32.4841
56,2949
72.9378
.0114004
,0603526
1 1*51 rtQ
. ii.JJ.UT •
,932606
4,72225
16,2421
28.1474
36,4689
                                         J-38

-------
                SPLIN2 PROGRAM - 02/22/82 VI
PROCESS DATA HOT AVAILABLE! EMISSION FACTOR DIRECTLY INPUT
TEST IB;   GERMAN STUDY  PLANT ID NO* B4  CYCLONE OUTLET
INPUT DATA;
PROCESS WEIGHT RATE = 0  TONS PROD* /HE
TOTAL PARTICULATE EMISSION RATE = 0 LB/HR
PARTICLE DENSITY = 2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT 
CUT

 .625
 1
 1,23
 2.5
 5
 10
 15
 20
             CUH.  % < CUT

               ,282783
               ,80161
               1,26568
               4,47531
               12,5012
               27.5872
               39.295
               48.0945
               EMISSION FACTOR
            < LB/T )        ( KG/MT )
             ,0588189
             , 166735
             ,263261
             .930364
                2.600
                  25
             5,73815
             8.17336
             10,0036
 ,0294094
 .0833675
 ,131631
 .465432
 1,30012
2.86907
4,08668
5,00182
END OF TEST  SERIES
                               J-39

-------
                SPLIM2  PRQGRAil -  02/22/82 VI
PROCESS BATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY 1MPUT
TEST tat  GERMAM STUBY  PLANT IB MO, F3  CYCLONE IMLET
INPUT DATA!
     PROCESS WEIGHT RATE  s  0   TONS PRQD,/HR
     TOTAL PARTICULATE  EMISSION  RATE  =  0   LB/HR
     PARTICLE DENSITY =2,4 G/CC
 MEASURED SIZE DISTRIBUTION
 CUT(uin)

  5,3
  7,5
  10,6
  15
  21,2
  30
  42.4
  40
  74
  CUM, 2 < CUT

      11
      19,8
      27,7
      35,5
      43.2
      48.9
      57,6
      id,9
      100
 OUTPUT  BATAJ    TP EMISSION FACTOR =  73,8  LB/T  (  36,9  KG/MT)
CUT UotA)
 1
 1-25
 2,5
 5
 10
 15
 CUM.  % <  CUT

 -5.50136E-05
  U43158E-03
-5.72483E-03
  ,218311
  3,0718
  15,8391
  25,6354
 ,32,1089
    EMISSION FACTOR
 (LB/T)       {KG/MT)
4.06E-05
1.05651E-03
4;22492E-03
,161483
2,26699
11,6893
18,9189
23.6963
2.03E-OS
5.2S253E-04
.0807414
1,13349
5,34463
9,45946
11,8482
ENB OF  TEST SERIES
                                         J-40

-------
                SPLIN2  PROGRAM  -  02/22/32 Mi

 PROCESS DATA NOT  AVAILABLE, EMISSION FACTOR DIRECTLY INPUT
 TEST  IB!  GERMAN  STUBY  PLANT ID  NO.  F3   CYCLONE OUTLET
 INPUT DATA!
      PROCESS  yEIGHT  RATE = 0  TOMS PROD* /HR
      TOTAL PARTICIPATE  EHISSION  RATE  = 0 LB/HR
      PARTICLE DENSITY =  2.6  G/CC
MEASURES PARTICLE SIZE DISTRIBUTION

CUT (un)    RAW % < CUT     CUM, % <  CUT
 10
 20
 40
 74
  27,7
  15.5
  14,4 '
  42,4
   27,7
   43.2
   57.6
   100
OUTPUT DATA:
   TP EMISSION FACTOR  »   4,7  LB/'T  <   2.35  KG/MT )
CUT (unA)
 i.;
 5
 10
 15
 20
CUM, % < CUT
   EMISSION FACTOR
< LB/T )        < KG/MT )
,426108
.964353
1 . 38577
3.85301
9,15894
18.6134
26.2079
32.3403
,0200271
.0453248
•0651313
.131092
,43047
,374832
1.23177
1.52
.0100135
,0226624
.0325657
,0905458
.215235
.437416
.615885
.759998
END OF TEST SERIES
                                J-41

-------
                SPLIN2 PROGRAM -  02/22/82 Ul
PROCESS DATA NOT AVAILABLE! EMISSION FACTOR DIRECTLY  INPUT
TEST ID*.   GERMAN STUDY  PLANT ID NO. G2  CYCLONE INLET
INPUT DATA:
    PROCESS WEIGHT RATE » 0  TONS PROD./HR
    TOTAL PARTICULATE EMISSION RATE = 0  LB/HR
    PARTICLE DENSITY =2.5  G/CC
MEASURED SIZE DISTRIBUTION

CUT
-------
                SPLIN2 PROGRAM - 02/22/82 Ml

PROCESS DATA NOT AVAILABLE? EMISSION FACTOR DIRECTLY  INPUT
TEST ID:  GERMAN STUCY  PLANT ID NO, G2  CYCLONE OUTLET
INPUT DATA:
     PROCESS WEIGHT RATE =  0   TONS  PROD,  /HR
     TOTAL PARTICIPATE EMISSION RATE = 0  LB/HR
     PARTICLE DENSITY = 2,6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW X < CUT     CUM. 7, < CUT
 10
 20
 40
 74
  37
  22,6
  12.5
  27*9
   37
   59.6
   72.1
   100
OUTPUT DATA:
   TP EMISSION FACTOR =  6.16  LB/T   <  3,08   KG/MT)
CUT ( urnA )
CUM. % < CUT
,625
i
1,25
2,5
,5
10
15
20
.0868022
.307537
.533432
2.43041
8.62957
22.5476
34 , 6296
44.2443
   EMISSION FACTOR
< LB/T )        (KG/MT)
                               5.34702E-03
                               .0189443
                               .0329826
                               ,152793
                               .531582
                               1,38893
                               2.13318
                               2.72545
                                 2.67351E-03
                                 9.47215E-03
                                 .0164913  •
                                 .0763967
                                 .265791
                                 .694466
                                 1,06659
                                 1,36273
END OF TEST SERIES
                                 J-43

-------
                SPLIN2 PROGRAM -  02/22/82 Ml
PROCESS DATA NOT AVAILABLE; EMISSION FACTOR DIRECTLY  INPUT
TEST I0t   GERMAN STUDY  PLANT ID NO, Gl  CYCLONE INLET
INPUT DATA:
     PROCESS  yglGHT  RATE = 0  TONS PRQD./HR
     TOTAL PARTICULATE  EMISSION  RATE  = 0  LB/HR
     PARTICLE DENSITY = 2.5  G/CC
MEASURED SIZE DISTRIBUTION

CUT(uffi)        CUM, % < CUT
 5.2
 7.4
 10.4
 14.7
 20.8
 29.4
 41.6
 38,8
 74
      3.9
      16»5
      29.1
      35.1
      43.8
      53*9
      66
      81.9
      100
OUTPUT DATA:
   TP EMISSION FACTOR =  55,8  LB/T  (   27.9  KG/MT)
CUT C umA )
 .625
 t.23
 2,3
 10
 15
 20
 CUM.  %  <  CUT

  4.0479E-09
  1.12921E-06
  1.238S9E-OS
—A-.7.2062E-03-
  .646657
  11.0338
  25.9301
  32.4878
     EMISSION FACTOR
  ( LB/T )       (KG/MT )
 2.25S73E-09
 6.30101E-07
 6.91134E-06
-3»7501-1-E-03
 .360834
 6.15684
 14.469
 18.1282
1.12936E-09
3.1505E-07
3.45567E-06
1.87305E-03
.180417
3.07842
7.2345
9,06411
END OF TEST SERIES
                                 J-44

-------
                SPLIN2 PROGRAM - 02/22/82 VI
PROCESS DATA NOT AVAILABLE! EMISSION FACTOR DIRECTLY INPUT
TEST IDt  GERMAN STUDY  PLANT ID NO. Gl  CYCLONE OUTLET
INPUT DATA:
   PROCESS WEIGHT RATE  =  0  TONS PROD*  /HR
   TOTAL PARTICULATE EMISSION  RATE  =  0  LB/HR
   PARTICLE DENSITY = 2.6  G/CC
HEASUREB PARTICLE SIZE DISTRIBUTION

CUT 
-------
                SPLIN2 PROGRAM -  02/22/32 VI
PROCESS DATA NOT AVAILABLE! EMISSION FACTOR DIRECTLY INPUT
TEST IDJ   GERMAN STUDY  PLANT ID NO. Bl  CYCLONE INLET
INPUT DATA;
    PROCESS WEIGHT RATE = 0  TONS PROO./HR
    TOTAL PARTICULATE EMISSION RATE = 0  LB/HR
    PARTICLE DENSITY = 2.5  G/CC
HEA3UREB SIZE DISTRIBUTION

CUT(im)        CUM. % < CUT
 5*2
 7.4
 10.4
 14.7
 20.8
 29.4
 41*6
 58.8
 74
     3.6
     5.1
     7
     8.9
     10.9
     12.8
     16.3
     23.7
     100
OUTPUT DATA:    TP EMISSION FACTOR =  31.3  LB/T  <  15.9  KG/MT)
CUT (

 .625
 1.
 1.23
-2T5
 5
 10
 15
 20
CUM. 7. < CUT

 ,152491
 .294359
 .397183
 .956238
 2.12832
 4.37859
 6.47235
 8.06365
     EMISSION FACTOR
 ( LB/T )        (KG/MT )
 .0484921
 .0936062
 .126304
-.3041	
 .676805
 1.39239
 2.05S21
 2.56424
.024246
.0468031
.0631522
VI5205
.338402
.696196
1.0291
1.28212
END OF TEST SERIES
                                 J-46

-------
                SPLIN2 PROGRAM - 02/22/32 VI
PROCESS DATA NOT AVAILABLE* EMISSION FACTOR DIRECTLY INPUT
TEST in:   GERMAN STUBY  PLANT ID NO. Bl  CYCLONE OUTLET
INPUT DATA:
     PROCESS WEIGHT RATE = 0  TONS PROD, /HR
     TOTAL PARTICULATE EMISSION RATE = 0 LB/HR
     PARTICLE DENSITY =2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (um)    RAW % < CUT     CUM» % < CUT
 10
 20
 40
 74
  7
  3.9
  5.4
  83.7
   7
   10.9
   16.3
   100
OUTPUT DATA:
   TP EMISSION FACTOR =  .898  LB/T  (  ..449   KS/MT )
CUT < urnA )
 .623
 1
 5
 10
 15
 20
CUM, 7. < CUT

  .51156
  .789009
  .962941
  1.74073
  3.02207
  5.03358
  6.6685
  8.0676
   EMISSION FACTOR
.< LB/T )        < KG/HT )
 4.S9381E-03
 7.08531E-03
 8.64721E-03
 .0156319
 .0271382
 .0452464
 .0598831
 .0724471
2.29691E-03
3.54265E-03
4.3236E-03
7.8I395E-03
.0135691
.0226232
.0299416
.0362235
END OF TEST SERIES
                                 J-47

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                SPLIN2 PROGRAM -  02/22/82 Ml
PROCESS DATA NOT AVAILABLE? EMISSION FACTOR  DIRECTLY  INPUT
TEST ID:   GERMAN STUDY  PLANT ID NO. F2  CYCLONE INLET
INPUT DATAt
    PROCESS yEIGHT RATE = 0  TONS PROD./HR
    TOTAL PARTICULATE EMISSION RATE * 0  LB/HR
    PARTICLE DENSITY =2,5  G/CC
MEASURED SIZE DISTRIBUTION

     m)        CUM. X < CUT
     16.5
     24
     32.5
     41.5
     45.6
     48.5
     53'
     60.4
     100 •
 5.2
 7.4
 10.4
 14.7
 20.8
 29.4
 41.6
 58*3
 74
OUTPUT DATA:
  TP EMISSION FACTOR =  29.2  LB/T  (  14.6  KG/MT)
CUT < umA )

 .623
 1
 1. ""•"
  10
  15
  20
CUM. % <

 .165785
 .48994
 ,7SS83
 2.96063
 8.76495
 20.4681
 30.1277
 37.9535
                       CUT
    EMISSION FACTOR
 (LB/T )       
-------
                SPLIN2 PROGRAM - 02/22/82 Ml
PROCESS DATA NOT. AVAILABLE? EMISSION FACTOR DIRECTLY INPUT
TEST IDt   GERMAN STUBY  PLANT ID NO* F2  CYCLONE OUTLET
INPUT DATAJ
                 PROCESS WEIGHT RATE - 0  TONS PROD. /HR
                 TOTAL PARTICULAR EHISSION RATE = 0 LB/HR
                 PARTICLE DENSITY - 2.6 G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW % < CUT     CUM. % < CUT
 10
 20
 40
 74
              32.5
              13.1
              7.4
              47
                    32. S
                    45.6
                    33
                    100
OUTPUT DATA*.     TP EMISSION FACTOR =  2.28 , LB/T  (  1.14  KG/MT )
CUT < uniA )
.625
1
1
  .25
 5
 10
 15
 20
CUM. 7. < CUT

  .538796
  1.25917
  1.82789
  5.13696
  11.9589
  23.0623
  31.0338
  36.8422
                                EMISSION FACTOR
                             
-------
    SEFER1NCE 8 DATA
(From fables  3-8 and 3-9)
          J-50

-------
                 SPLIN2  PROGRAM - 02/22/32 Ml

TEST ID l  SLOftii 1971  WASHER IMLET
INPUT
                  PROCESS UEIGHT RATE * 225  TONS  PROD*  /HR
                  TOTAL PARTICULATE EMISSION RATE  -  2135  LB/Hft
                  PARTICLE DENSITY • 1 G/CC
HEASUStl; PARTICLE SIZE DISTRIBUTION

CUT (ur«)    RAU 2 < CUT     CUH, 7. < CUT
 i
 1
 t,
 3,3
 5,5
 9.2
 30
 120
               2.3
               9,5
               12,2
               13.3
               14.8
               19
               27,7
   .703518
   3.01508
   12*5628
   24,8241
   38.191
   33.0653
   72.1408
   100
OUTPUT
                TP EMISSION FACTOR *  9.48889  LB/T   (   4,74444   KG/HT
 CUT
 i.23
 2.5
 iu
  13
 20
             CUB, 2 < CUT

               1.46364
               3,13023
              "4.99144
               17.5865
               35.5683
               54.6757
               61.7131
               65,3706
   EMISSION FACTOR
(LB/T)        < KG/HT)
 .138883
 .297029
 ,473632
 1.66876
 3.37504
 5.13312
 5.85589
 6.25039
,0694414
.148514
,236816
.834381
1,68752
2,59406
2.92795
3.12319
 EKD  Of  TEST SERIES
                                          J-51

-------
                 SPLIK2 PROGRAM - 02/22/82 Ml

TEST ID I  SLQAw  1971   WASHER EXHAUST

INPUT  DATAI
PROCESS UEIGHT RATE = 225  TONS PROD. /HR
TOTAL PARTICIPATE EMISSION RATE » 181 LB/HR
PARTICLE SENSITY = 1 G/CC
HEASUREfc PARTICLE SHE DISTRIBUTION

CUT 
-------
                SPLIH2 PROGRAM - 02/22/82 Ml

TEST Ifil  HARRISON 1971  PRE-UASH ENTRANCE

IftfUT DATA1.       PROCESS UEIGHT RATE * 180  TONS PROD. /HR
                  TOTAL PARTICULATE EMISSION RATE « 1715 LB/HR
                  PARTICLE DENSITY = 1 6/CC

MEASURED PARTICLE SIZE DISTRIBUTION

CUT (UK)    RAH I < CUT     CUM, % < CUT
 5.5
 30
 120
  14,9
  35.1
  26.9
  23.1
   14,9
   50
   76,9
   100
OUTPUT DATA I
   TP EMISSION FACTOR =  9.52778  LB/T  (   4.76389  KG/MT)
CUT

  .625
  i
  i,25
  2.5
  5
  10
  15
CUM. % < CUT

  1.S3489
  4.3074
  6.66173
  20.6907
  45.5494
  62.6il6
  68,0623
  71.673
   EMISSION FACTOR
ILB/T)         (KG/MT 5
 ,146241
 .4104
 ,634714
 1.97136
 4»33985
 5.9655
 6,48482
 6,32932
.0731205
,2052
.317357
.98568
2.16992
2,98275
3.24241
3.41466
ENB OF  TEST SERIES
                                         J-53

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                SM.IN2 PRQSRAtt - 02/22/82 VI

TEST ID l  KARR1SOK 1971   UASHER EXHAUST

iNf'UT DATs I       PROCESS UEISHT RATE =  ISO  TOMS PROD,  /HR
                  TOTAL  PARTICULATE EMISSION RATE * 63 LB/HR
                  PARTICLE DENSITY = 1 5/CC

HEASUREU PARTICLE SIZE DISTRIBUTION

CUT     RAU I < CUT      CUM, 2 < CUT
 5,5
 30
 120
               6.3
               2.2
               3
94.8
97
100
OUTPUT DATA I    TP EMISSION FACTOR *  »33  LB/T  <   .173  KG/WT)
CUT (u;,A)    CUH.  'L < CUT
                                 EMISSION FACTOR
                              (LB/T)        (KG/HT)
>i25
*i
4.
i.25
2,5
5
10
13
20"
7S.375
Si .4615
33.7061
39.3065
94.2514
95.831
-96.1975
96.4902
.247312
.285115
.292971
.314323
.32988
.335408
.336698
.337716
.133656
.142558
.146486
,157161
,16494
.167704
.168349
.168858
END OF TEST SERIES
                                        J-54

-------
REFERENCE 12 DATA
(From Table 3-10)
        J-55

-------
                SPLIN2 PROGRAM -  02/22/32 Ml

TEST IBS  TABLE 94 AP-40  C-537   INLET TO  PRIMARY  CYCLONE

INPUT DATA!       PROCESS WEIGHT  RATE  -  173   TONS  PROD,,  /HR
                  TOTAL PARTICULATE EMISSION  RATE  -  5463 LB/HR
                  PARTICLE DENSITY = 2.4   G/CC

MEASURED PARTICLE SIZE DISTRIBUTION

CUT < urn)    RAy X < CUT     CUM.  % < CUT
 5
 10
 20
 50
 74
  6.2
  9,4
  13.8
  22,9
  47.7
  6*2
  15.6
  29.4
  52.3
  100
OUTPUT DATAI    TP EMISSION FACTOR =  31,578   LB/T  <   15.789   KG/MT)
CUT ( umA)
  ,625
  1
  1,25
  2,5
  5
  10
  15
  20
CUM. % < CUT

  ,0186489
  .0734769
  , 134485
  ,726412
  2.93389
  8.90582
  14.3743
  19,9991
  EMISSION FACTOR
LB/T )        (KG/MT )
5,38895E-03
,0232025
.0424676
,229387
,928044
2,81228
4,69702
6.31533
2.94447E-03
.0116013
.0212338
.114693
.464022
1.40614
2.34851
3,15766
    "OF" TEST" SERIES"
                                 J-56

-------
                SPLIN2 PROGRAM - 02/22/82  Ml

TEST IDS  TABLE 94 AP-40  C-537  INLET TO  SCRUBBER
INPUT DATA:
     PROCESS WEIGHT RATE  =  173   TONS  PROD.  /HR
     TOTAL PARTICIPATE EMISSION  RATE  =  118.3  LB/HR
     PARTICLE BEMSITY =2.4  G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT (urn)    RAW % < CUT     CUM. '/. < CUT
 5
 10
 20
 50
 74
  34
  8.8
  .2
   57
   91
   99.8
   100
   100
OUTPUT DATA?    TP EMISSION FACTOR -   .633815  LB/T  <   .341903   KG/MT)
CUT (
 ,625
 1.23
 2.5
 3
 10
 15
 20
CUM. 7. < CUT

  .432684
  1,56537
  2,71332
  11.6883
  34.5881
  70.3109
  89.0992
  95,5844
   EMISSION FACTOR

-------
                SPLIN2 PROGRAM - 02/22/82 Ml
TEST IDt  TABLE 94 AP-40   INLET TO MULTICLQNE
INPUT DATA:
     PROCESS yEIGHT RATE = 173  TONS PROC. /HR
     TOTAL PARTICULATE EMISSION RATE = 1525 LB/HR
     PARTICLE DENSITY =2.4  G/CC
MEASURED PARTICLE SIZE DISTRIBUTION

CUT ( un)    RAW % < CUT     CUM. % < CUT
 10
 20
 50
 74
  19.3
  31.9
  31.6
  15.1
  2.1
   19.3
   51.2
   82.8
   97.9
   100
OUTPUT DATAt
   TP EMISSION FACTOR -  8.31503  LB/T  (  4.40752  KG/MT>
CUT ( umA)
  .625
 2.5
 10
 15
 20
CUM, % < CUT

  8.3S504E-03
  ,0582523
  .135014
  1.32526
  7.92999
  28.9263
  48*894
  63.2283
   EMISSION FACTOR
( LB/T )        < KG/MT )
 7.39144E-04
 5.13496E-03
 .0119015
 .116822
 .699031
 2.54986
 4.3102
 5i5736
3.69572E-04
2.56748E-03
5.95076E-03
.0584111
.349516
1*27493
2.1551
2.7868
t£NB OF TEST SERIES
                                 J-58

-------
REFERENCE 26 DATA
(From Table 3-11)
       J-59

-------
               MIDWEST RESEARCH INSTITUTE
                    rlOJICT OIVflOPMENT SKETCH
                                        S    0 uilet

pffOJECT NO IV iflL-oH DRAWN >V T 	 APPB . pAff , J ,

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-------
                SPLIN2  PROGRAH  -  02/22/82

TEST ID;  KVB 5806-783  TEST 29S  OUTLET
INPUT BATAt
   PROCESS  WEIGHT  RATE = 175  TONS PROD, /HR
   TOTAL PARTICULATE  EMISSION RATE - 4.34 LB/HR
   PARTICLE DENSITY = 1 G/CC
MEASURES PARTICLE SIZE DISTRIBUTION

CUT 
-------
                    APPENDIX K
EMISSIONS CALCULATIONS FOR DRQM-MIX ASPHALT PLANTS
         (Results  Included  in Table 3-35)
                        K-l

-------
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-------
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K-5

-------
TECHNICAL REPORT DATA
(Please read fan/actions on the reverse before completing)
1. REPORT NO. 2.
EPA-600/7-86-Q38
4. TITLE AND SUBTITLE
Asphaltic Concrete Industry Particulate Emissions:
Source Category Report
7. AUTMOfHS)
John S. Kinsey
i. PERFORMING ORGANIZATION NAME AND ADDRESS
Midwest Research Institute
425 Volker Boulevard
Kansas City, Missouri 64110
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air and Energy Engineering Research Laboratory
Research Triangle Park, NC 27711
3. RECIPIENT'S ACCESSION- NO.
8. REPORT DATE
October 1986
6, PERFORMING ORGANIZATION
8. PERFORMING ORGANIZATION
CODE
REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3158, Task 18
13. TYPE OF REPORT AND PERIO
Task Final; 3/82 - 1C
°/i?6R6D
14, SPONSORING AGENCY CODE
EPA/600/13
is. SUPPLEMENTARY NOTES AEERL project officer is Dale L. Harmon, Mail Drop 61,
2429.
919/541-
16. ABSTRACT -j^g repOrt describes the development of particulate emission factors
based on cutoff size for inhalable particles for the asphaltic concrete industry. After
review of available information characterizing particulate emissions from asphalt
concrete plants, .the data were summarized and  rated in terms of reliability. Size
specific emission factors were developed from these data for each of the three pro-
cesses used in the manufacture of asphalt concrete. A detailed process description
is presented, with emphasis on factors affecting the generation  of emissions.  A  re-
placement for Section 8.1 (Asphalt  Concrete Plants) of AP-42 was prepared, con-
taining the  size specific emission factors developed by the program.
17. KIY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Pollution
Bituminous Concretes
Asphalt Plants
Dust
Emission
13. DISTRIBUTION STATEMENT
Release to Public
b. IDENTIFIERS/OPEN ENDED TIHMS
Pollution Control
Stationary Sources
Asphalt Concrete Plants
Particulate
Emission Factors
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page}
Unclassified
c. COSATI Pit:l
-------
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    Office of Research and Development
  Canter for Environmental Research Information
          Cincinnati, Ohio 45268

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                                     tear off; and return to the above address.
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                                    Publication  No. EPA-eoo/7-86-038

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