United States
     Environmental Protection
     Agency
        RESEARCH PROJECT
National Risk Management Research Laboratory
      Water Supply and Water Resources Division
          Water Quality Management Branch
NOBLE GAS TEMPERATURE PROXY FOR CLIMATE CHANGE
                                                              IMPACT STATEMENT
                                                 Noble gases in groundwater appear to  offer a practical
                                                 approach for quantitatively  determining past surface air
                                                 temperatures over recharge  areas for any watershed. The
                                                 noble gas temperature (NGT) proxy should then permit a
                                                 paleothermometry of a region over time. This terrestrial
                                                 proxy when coupled with groundwater age dating offers a
                                                 timeline  of climate changes. Such  a history of  regional
                                                 climate changes can thus aid  our understanding of the
                                                 resultant intensification  of  the water cycle. Therefore,
                                                 forecasting changes in  runoff and shifts in  recharge
                                                 patterns  can  be improved to  model water quality and
                                                 stream flow modifications. These nascent applications are
                                                 occurring  on the  Olympic Peninsula,  Washington, in
                                                 support of the reestablishment of healthy anadromous
                                                 fisheries.
BACKGROUND:
The NGT proxy is introduced for the Olympic Mountains region as a quantitative assessment of past mean
recharge air temperatures. Continental climate archives are stored in aquifers that are ubiquitous and can be
integrated into  regional syntheses of  past climate  environments. Aquifers may  smooth out  short-term
meteorological fluctuations but often preserve long term climate change information. In order to retrieve
earlier surface air temperatures at recharge areas in watersheds, noble gases (He, Ne, Ar, Kr,  and Xe) are
measured in groundwater. Fundamentally, the solubility of noble gases is temperature dependent, and thus,
the temperature at which recharged water last equilibrated with the atmosphere can be calculated from
noble gas concentrations. The advantageous spatial relationship of noble gas and mean air temperature at the
recharge location is  maintained and  is  not impacted  by recharge  altitude,  seasonal distribution  of
precipitation, and vapor source area.
DESCRIPTION:
The Olympic Peninsula offers a prognostic study area for climate change in the Pacific Northwest. The National
Risk Management Research Laboratory of the U.S. Environmental Protection Agency's (EPA) Office of Research
and Development is leading an interdisciplinary team of hydrologists and chemists from several organizations.
Experimental sampling techniques and new analytical tools have  been developed to test the application of
noble gas paleothermometry for climate change investigations. Collaborative  field activities with the  U.S.
National  Park  Service  (USNPS),  the  U.S.  Forest Service  (USFS),  Peninsula Community College,  and  the
Washington State Department of Natural Resources (DNR) are guiding sampling of ubiquitous springs in the
      National Risk Management Research Laboratory
      Water Supply and Water Resources Division

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Olympic massif. Shared rare gas mass spectrometry, stable isotope analyses, and radioisotope assays are being
conducted with Ohio State University, the U.S. Department of Energy's (DOE) Oak Ridge National Laboratory
(ORNL), and  Purdue University.  Collaborative modeling  with  Environment Canada-Climate  Centre, Miami
(Ohio) University, and the University of Washington is centered on scaling general circulation models to adapt
regional data sources obtained through this project. Assessment of climate change  model forecasts, as they
relate to shifting recharge and  runoff patterns with effects on anadromous fisheries,  would be integrated into
EPA's Region  10 activities.
RESEARCH PARTNERS:
Collaborators:  USNPS;  USFS; Washington State DNR; Environment Canada-Climate Centre; Ohio State University;
DOE/ORNL; Purdue University;  Miami (Ohio) University; Peninsula Community College,  University of Washington,
EPA/Region 10

EXPECTED  OUTCOMES AND IMPACTS:
A timeline of past surface air temperature changes in the watersheds of the Olympic Peninsula will be utilized
to forecast trends for recharge and runoff modeling in support of anadromous fisheries.

OUTPUTS:
Expected outputs consist of journal articles and conference proceedings.

RESOURCES:
Sidle WC and Cvetic V (2009). Holocene noble gas paleothermometry from springs in the Olympic Mountains,
Washington.  Presentation at the 2009 Geological Society of America Annual  Meeting in Portland, Oregon.
http://www.geosociety.org/meetings/2009/
National Risk Management Research Laboratory: http://www.epa.gov/nrmrl/

CONTACTS:
William Sidle, Principal Investigator - (513) 569-7212 or sidle.william@epa.gov
Steven Doub, Media Relations - (513) 569-7503 ordoub.steven@epa.gov
Michelle Latham, Communications - (513) 569-7601 or latham.michelle@epa.gov


      National Risk Management Research Laboratory
      Water Supply and Water Resources Division
www.epa.gov/nrmrl     EPA/600/F-09/024
                    October 2009

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