United States
          Environmental Protection Agency
                                                    Office of Solid Waste and
                                                    Emergency Response (51 02G)
 EPA542-F-09-004
 December 2009
Green Remediation Best Management Practices:
Site  Investigation
Office of Superfund Remediation and Technology Innovation
                                                                                        Quick Reference Fact Sheet
  The U.S. Environmental Protection Agency (EPA) Principles for
  Greener Cleanups outlines the Agency's policy for evaluating
  and minimizing the environmental "footprint" of activities
  undertaken when cleaning up a contaminated site.1 Use of
  the best management practices (BMPs) recommended in
  EPA's series of green remediation fact sheets can help project
  managers and other stakeholders apply the  principles on a
  routine basis, while maintaining the cleanup objectives,
  ensuring protectiveness of a remedy, and improving its
  environmental outcome.2
  Overview
The  need for site investigation  is  common  to cleanups
under any regulatory program. An investigation can occur
at all  points  in  the  cleanup  process,  from  initial  site
assessment   through   waste  site  closeout.   A   site
investigation generally is undertaken to:
• Confirm   the   presence  or   absence   of  specific
  contaminants
• Delineate  the   nature  and  extent of  environmental
  contamination
• Identify contaminant sources
• Provide the data necessary to assess  potential risk to
  human health and/or the environment
• Gather  the data needed  to determine if  a remedial
  action should be taken
• Understand site characteristics  impacting  the remedy
  design, construction, or operation and closeout, and
• Evaluate performance of a  remedial action.
Site  investigations typically involve sampling  of soil and
groundwater  using various drilling and  well installation
technologies   and  analysis  of  samples    at  offsite
laboratories.  Investigations also may  include sampling of
sediment, surface water, soil  gas, or indoor air; searching
for  underground   storage  tanks  (USTs)  or  other buried
objects;  or  evaluating  demolition  material   containing
asbestos, lead-based paint, or other toxic products.
  Planning for Site Investigation
Consideration of green remediation options early during
the project design  phase will  help reduce cumulative
environmental footprints  of a  cleanup.  Effective planning
will include identification  of investigative decision points in
context  of a site's  unique  contamination  scenario  and
logistics,  while  accounting  for potential  remedies  and
anticipated site reuse.
                                                          At each decision point, strategies and methods can be
                                                          evaluated to determine which are likely to best address the
                                                          core elements of a green cleanup:
                                                            Reducing total energy use and
                                                            increasing renewable energy
Materials
& Waste
                                               Energy
                                                                                                      Core
                                                                                             Land &  Elements
                                                                                           Ecosystems
                                                                                                     Water
              •
• Reducing air pollutants and
  greenhouse gas (GHG)
  emissions
• Reducing water use and
  negative impacts on water resources
• Improving materials management and waste reduction
  efforts, and
• Enhancing  land management and ecosystems
  protection.
A  green site  investigation relies on  information  gained
from  a thorough  preliminary assessment that identifies
target   areas  and  site  conditions  through  minimally
intrusive techniques.  Use of innovative field analytics and
direct  sensing  tools  can  reduce  the  environmental
footprint  of  follow-on   characterization  or   cleanup
activities, particularly  by limiting mobilizations in  the field
and  increasing  the  density  of analytical  data.  More
targeted remedial  actions and "surgical" removal actions
also can  be  achieved through  use of  high  resolution
sampling tools during site  investigations.
Initial BMPs for a site investigation include:
• Evaluating  feasibility of  using a mobile laboratory, field
  analytical methods, or direct sensing tools
• Scheduling activities for appropriate seasons to reduce
  delays caused  by weather conditions and fuel needed
  for heating or cooling
• Identifying  local sources of energy efficient  machinery
  and vehicles and alternative fuels
• Establishing electronic networks for data transfers  and
  deliverables,   team   decisions,    and    document
  preparation, and selecting electronic  products on the
  basis of comparisons available in the Electronic Product
  Environmental Assessment Tool (EPEATฎ)
• Selecting  facilities   with  green  policies, for  worker
  accommodations and periodic meetings
• Reducing  travel  through  increased  teleconferencing,
  compressed work  hours, and  flexible work locations,
  and
• Identifying  options   for  integrating  renewable  energy
  resources,   including   those  extending   throughout
  cleanup activities.

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                                Portable electricity
                                generators equipped
                                with photovoltaic
                                panels and batteries
                                can be used to power
                                investigative equipment
                                such as chilling or
                                heating units.
Procurement  of   goods   and  services   offers   other
opportunities for conserving natural  resources:
• Incorporate green  specifications  into  solicitations and
  contracts,  with   respect  to   environmentally  preferred
  purchasing  of materials,  awards to  contractors  with
  green  policies and procedures (such as routine  use of
  water  efficient   and  Energy Starฎ  equipment)  and
  periodic  reporting of resource reductions
• Select   service   providers,   product  suppliers,   and
  analytical  laboratories   from  the   local  area  and
  coordinate service  and  delivery  schedules,  to reduce
  fuel consumption and associated air emissions, and
• Specify laboratory  analytical  methods  generating less
  waste and solvents, such as solid phase micro  extraction
  (SPME),   pressurized    fluid  extraction,   microwave
  extraction,  and   supercritical   fluid   extraction,   if
  comparable accuracies  can  be achieved; for example,
  SPME  provides  a single-step  process  that can reduce
  sample  preparation time  by  as  much  as  70%  while
  using little or no solvents.

Collection  of representative data during the first round of
field activities reduces the  need  for subsequent  sampling.
Development of a  well conceived site  sampling plan can
help assure that  collected  data truly represent a  site.
Systematic  planning,  a  critical  component of  optimized
strategies for investigating  hazardous waste sites, involves
identifying   key  decisions  to   be   made,  developing   a
conceptual site model (CSM) to support decision making,
and   evaluating   decision    uncertainty   along    with
approaches for actively managing  that uncertainty. The
CSM combines analytical  data with historical  information
to  identify  data  gaps  and   allows   for  refinement  as
additional  data become available.

Collecting  information dynamically  and  in real  time and
adjusting  the work according to  the field  findings  will
minimize   mobilizations.  Dynamic  work  strategies  that
employ data visualization, dynamic sampling  programs,
and quality controls to minimize uncertainties reduce the
need for repeated mobilizations and additional  sampling.
Use of the Triad  approach can help project  managers
integrate systematic planning, dynamic working strategies,
and deployment of these real-time measurement tools. 3
                                                             Energy Use & Renewable Energy
Fewer  field  mobilizations can  result  in significant savings
of fossil fuel and minimized emission of GHG and  other
air  pollutants.  Real-time   field   measurements   can
immediately  provide  data to  help  determine the  next
course of action during a single sampling event. Real-time
data collection technologies include:

• Direct  sensing  technology  such  as  the   membrane
  interface probe, laser-induced  fluorescence (LIE) sensor,
  and  cone penetrometer testing (CPT)
• X-ray fluorescence analyzers for metals
• Soil gas surveys for volatile organic compounds (VOCs)
• Portable   gas  chromatography/mass spectrometry  for
  fuel-related  compounds  and  VOCs   in  soil   and
  groundwater
                  for analyzing  soil  and  groundwater
                   such     as    petroleum,     metals,
                  biphenyls,  pesticides,  explosives,  and
Field  test  kits
contaminants
polychlorinated
inorganics, and
Geophysical  surveys  for  locating  USTs,  buried  steel
drums, and boundaries of disposal areas.
  Profile: McGuire Air Force Base, C-l7Hangar Site,
          New Hanover, NJ
  * Used a Triad decision making approach to complete
    characterization ofVOC contamination of soil and
    groundwater ahead of schedule, consequently reducing
    the fuel consumption, land disturbance, and dust
    generation associated  with additional sampling days
  • Used investigative tools such as CPT and fuel fluorescence
    detectors to generate over 4,500 analytical results in real
    time, which expedited decision making in the field and
    avoided  fuel use associated with transporting samples to
    an offsite laboratory
  * Determined through real-time measurements that  natural
    attenuation of halogenated VOCs was occurring,  and
    avoided  excess land disturbance and fuel consumption by
    incorporating monitored natural attenuation into the
    remedy
  * Precisely identified a smear zone of Stoddard solvent,
    allowing it  to be surgically excavated with minimal land
    disturbance and fuel consumption
Recommended BMPs  for selecting  other  equipment and
processes  that minimize fuel and  energy consumption
include:
• Limiting  the  number of vehicles  deployed  onsite, and
  renting electric, hybrid, or hydrogen fuel cell vehicles
• Instituting  idle  reduction   plans,  such  as  machinery
  shutdown after three minutes of non-use
• Compressing shipments to offsite  laboratories whenever
  feasible
• Using  in situ  data  loggers  wherever  appropriate  to
  monitor water levels and water quality parameters

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  Using  solar-powered  telemetry  systems  to  remotely
  transmit logging data directly to project offices
  Using rechargeable  batteries for handheld data loggers
  and other field instruments
  Using  direct-push technology  (DPT)  for  well  drilling,
  which is 50-60% more time efficient than rotary drill rigs
  and  avoids drill cuttings that require  assessment and
  disposal of investigation-derived waste (IDW)
  Segregating   soil  and  groundwater  collected   from
  different   areas;  in   many states,  media  analytically
  determined  to be clean  can be deposited onsite  rather
  than transported for  offsite disposal, and
  Disposing IDW at the nearest permitted facility.
  Air Pollutants & GHG Emissions
Air emissions  from  mobile  sources  can  be  reduced
through use of various new technologies. Diesel emission
control filters, for example, can reduce particulate matter
emissions  by  as   much   as  89%  and  nitrogen  oxide
emissions by as much as 80%. Switching from low-sulfur
to ultralow-sulfur  fuels  will reduce emissions  of  sulfur
dioxide  (an  acid   rain-causing  air  pollutant)  and  also
allows use  of emission control systems that would  be
damaged by fuels with a higher sulfur content.  Ultralow-
sulfur diesel  has become  the standard  in most states; it
contains  no more  than 15  ppm  sulfur (S), in comparison
to the 500 ppm S in low-sulfur diesel.
Any  technology that  reduces  duration  of drilling  and
groundwater  pumping  or  purging  helps  reduce  the
cumulative  amounts of pollutants  released to the  air.
Examples include  sonic drilling and passive  (diffusion-
based) sampling devices.


Deployment of diesel-powered machinery, vehicles,
and equipment over six months of investigations cou
emit nearly 32,000 pounds of CO2/ based on a
consumption of more than 1,400 gallons of diesel.4
d

Relative Diesel Consumption of
Common Investigative Activities over Six Months
(gallons)
Transportation, operation, and support for a rotary
drilling rig for four weeks
Groundwater sampling with a submersible pump
driven by a 2.5-hp gasoline-powered generator
Deployment of a truck-mounted DPT rig for
subsurface sampling
Operation of utility trucks for equipment
maintenance, groundwater and soil sampling, and
Periodic truck delivery of small equipment and
supplies and disposal of nonhazardous waste
IDW transfer to a disposal facility by way of tractor
trailer
293
45
400
300
260
125
Total disssl consumed: 1,423 gallons
 Water Use & Impacts on Water Resources
Green remediation strategies help reduce consumption of
fresh  water,  reclaim  or  reuse  uncontaminated  water,
minimize  potential for  waterborne  contamination,  and
minimize introduction of toxic processing materials during
a site investigation. Recommended best practices include:
• Using waterless drilling techniques such as DPT
• Exploring  options for reusing operational  graywater and
  capturing  rainwater for tasks such as irrigation or dust
  control
• Returning  unused clean  water to  surface water bodies
  rather than discharging it to a public sewer system
• Using low-flow sampling equipment wherever possible
  during  monitoring,  to  minimize  purge  volumes  and
  energy consumption while producing  little IDW
                                Use of passive diffusion
                                hag samplers reduces
                                or eliminates purge
                                water associated with
                                well sampling; multiple
                                vertically-placed
                                samplers can provide a
                                vertical profile of
                                groundwater samples at
                                one-foot intervals.
• Steam-cleaning  or  using  phosphate-free  detergents
  instead  of organic solvents or acids to decontaminate
  sampling equipment
• Containing decontamination fluids and preventing their
  entrance into storm drains or the ground surface
• Treating  potentially contaminated purge water through
  use  of  appropriate  treatment   techniques  such  as
  activated  carbon filtration  prior  to  discharge to  storm
  drains or waterways
• Using   closed-loop   cleaning   systems   relying   on
  graywater to wash non-sampling  related machinery and
  equipment
• Using  biodegradable  hydraulic  fluids  on  hydraulic
  equipment such  as drill rigs
• Selecting  groundwater monitoring  equipment made of
  noncorrosive  material,   to  avoid   potential    cross-
  contamination and equipment replacement, and
• Quickly  restoring  any vegetated  areas  disrupted  by
  equipment or vehicles, to control stormwater runoff and
  avoid soil transport to surface water bodies.
Integrating the needs of remedial and monitoring phases
during  design  of  sampling  wells  will   help  reduce
subsurface drilling throughout the life of a cleanup. Well
designs also can accommodate a site's  potential cleanup
remedy(s) and  reuse goals,  in ways that meet the  site's
future demand  for water while preserving any portions of
the property targeted for specific use.

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  Materials Management & Waste Reduction
  Land Management & Ecosystem Protection
Site  investigation  procedures typically involve use of an
assortment  of  manufactured products  such  as  personal
protective  equipment   (PPE),  sample   containers,  and
routine  business materials.  Green purchasing  considers
product lifecycles and gives preference to:

• Products with recycled and biobased  contents such  as
  agricultural  or  forestry waste  instead  of petroleum-
  based  ingredients
• Products,  packing material, and  disposable equipment
  with reuse or recycling potential, and
• Products  manufactured  through   processes   involving
  nontoxic chemical alternatives.

IDW  generation   and   management   account  for   a
significant portion  of the environmental footprints  of site
investigation. IDW includes drill cuttings, well purge water,
spent carbon from filtration equipment, reagents used with
environmental  field  test  kits,  contaminated PPE,  and
solutions for  decontaminating  non-disposable  PPE  and
equipment.

Reducing the volume of generated  IDW will decrease the
need for related containers such  as plastic disposal bags
and   55-gallon storage drums,   and  for treatment  or
disposal   of  IDW  in   an   appropriate  hazardous  or
nonhazardous  waste  facility.  Recommended  BMPs  to
reduce the volume of routine waste or IDW and  decrease
materials consumption include:

• Recycling  cardboard boxes and beverage bottles
• Reducing  use of single-use plastic bags
• Reducing  the number of sampling days
• Using  onsite analysis and  other real-time measurement
  technologies  to  reduce  needs  for  sample  packing
  materials
• Selecting  test kits that generate less waste,  such  as soil
  samplers with reusable handles  for coring syringes, and
• Segregating  drill  cuttings  by  appropriately stockpiling
  next to a borehole and awaiting analytical results; under
  many cleanup programs, clean soil may be distributed
  near boreholes or backfilled into a boring.
  Explore Web-based calculators, software models, and other
  Footprint Assessment \oo\s accessible on Green Remediation
  Focus (http://www.cluin.org/greenremediation), such as the:
  • CICA Compliance Summary Tool, to  evaluate construction
    impacts on land, ecosystems, and water
  • Energy & Materials Flow & Cost Tracker (EMFACT™), to
    track materials, energy use, wastes, and costs
  • Greenhouse Gas Protocol, to quantify and manage GHG
    emissions
    MotorMaster + , to select energy efficient motors, and
    Water Evaluation and Planning System (WEAP), to conduct
    integrated water resource planning
Site  investigation  activities  can   disturb  a  significant
amount  of  land  in  order to gather the  necessary data.
Project managers should  consider  technologies  resulting
in limited subsurface intrusion and minimal land impacts:

• Ground   penetrating   radar   or  other   geophysical
  methods  can  identify  subsurface anomalies  such  as
  USTs and buried drums without disturbing land.
• DPT for soil and groundwater sampling do  not result in
  drill cuttings or excess soil waste and  related IDW.
• A  wide range  of  direct sensing  tools such as the LIE
  sensor  are   now   available   to develop  a   nearly
  continuous vertical  profile  of  some  volatile and  semi-
  volatile contaminants in  the subsurface,  both above and
  below  the water table.
• Soil gas surveys are minimally invasive and  can  provide
  relatively rapid and  cost-effective  information about the
  presence, composition, and distribution  of contaminants
  in  the vadose zone and water table.
          A Sampling of Success Measures for
                    Site Investigation
   Reduced fuel consumption and GHG emissions through
   integrated planning of field activities
   Increased use of solar energy-driven auxiliary equipment
   and small devices
   Reduced generation of wastewater from well drilling and
   sampling
   Reduced subsurface and ecosystem disturbance through
   more use of advanced sampling  technologies and
   visualizing techniques
   Fewer soil and groundwater samples needing offsite
   laboratory analysis
 References [Web accessed: 2009, December 30]
1 U.S. EPA; Principles for Greener Cleanups; August 27, 2009;
 http://www.epa.gov/oswer/greencleanups

 U.S. EPA; Green Remediation: Incorporating Sustainable
 Environmental Practices into Remediation of Contaminated
 Sites; EPA 542-R-08-002, April 2008;
 http://www.cluin.org/greenremediation

3Interstate Technology & Regulatory Council;  Technical and
 Regulatory Guidance for the Triad Approach: A New Paradigm
 for Environmental Project Management;  December 2003;
 http://www.triadcentral.org/

4U.S. EPA; Emission Facts: Average Carbon Dioxide Emissions
 Resulting from Gasoline and Diesel Fuel; EPA420-F-05-001
            Visit Green Remediation Focus online:
         http://www.cluin.org/greenremediation
                                                                            For more information, contact:
                                                                  Carlos Pachon, OSWER/OSRTI (pachon.carlos@epa.gov)
                                                                          U.S. Environmental Protection Agency

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