EPA/600/R-07/005
February 2007
Source Sampling Fine Particulate Matter
Institutional Oil-Fired Boiler
Prepared by:
Joan T. Bursey and Dave-Paul Dayton
Eastern Research Group, Inc.
1600 Perimeter Park Drive
Morrisville, NC 27560
Contract No. 68-D-00-264
EPA Work Assignment Manager:
Lee L. Beck
Air Pollution Prevention and Control Division (E-343-02)
National Risk Management and Research Laboratory
Research Triangle Park, NC 27711
Prepared for:
U.S. Environmental Protection Agency
Office of Research and Development
Washington, DC 20460
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Table of Contents
Acknowledgments ix
Section 1 Introduction 1
Description of Testing and Testing Objectives 3
Organization of Report 6
Section 2 Conclusions 8
Section 3 Methods and Materials 13
Description of the Testing Program 13
Description of Testing Equipment 15
Dilution Sampling System 15
Dilution Sampling System Control Instrumentation 19
Sample Collection Arrays 21
Process Description/Site Operation 21
Description of the Oil-Fired Boiler Tested at North Carolina A&T
(Greensboro, NC) 24
Pre-Test Surveys 26
Section 4 Experimental Procedures 32
Preparation for Test Setup 32
Application of EPA Methods 1-4 33
Traverse Point Determination Using EPA Method 1 33
Volumetric Flow Rate Determination Using EPA Method 2 34
Pitot Tube Calibration 35
Calculation of Average Flue Gas Velocity 35
Determination of Volumetric Flow Rate for Stack Gas 36
Nozzle Size Determination 39
Measurement of O2 and CO2 Concentrations 39
Stationary Gas Distribution (as Percent Volume) 40
Dry Molecular Weight of Flue Gas 40
Wet Molecular Weight of Flue Gas 41
Determination of Average Moisture Using EPA Method 4 41
Volume of Dry Gas Sampled at Standard Conditions (dscf) 42
Volume of Water Vapor at Standard Conditions (dscf) 43
Calculation of Moisture /Water Content (as % Volume) 44
Calculation of Dry Mole Fraction of Flue Gas 44
Setup of the Dilution Sampling System 45
Pre-Test Leak Check 53
Orifice Flow Check 57
Determination of Test Duration 57
Canister/Veriflow Blanks 57
ii
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Table of Contents (Continued)
Determination of Flow Rates 58
Sample Collection Arrays: Campaign #1 59
Sample Collection Arrays: Campaign #2 63
Measurement of O2 and CO2 Process Concentrations 65
Operation of the Dilution Sampling System and Sample
Collection Arrays 65
Laboratory Experimental Methodology 90
PM-2.5 Mass 90
Elemental Analysis 90
Water-Soluble Inorganic Ions 91
Elemental Carbon/Organic Carbon 91
Organic Compounds 92
Carbonyl Compounds 93
Canister Analyses: Air Toxics and Speciated Nonmethane
Organic Compounds 95
Particle Size Distribution Data 96
Section 5 Results and Discussion 102
PM Mass, Elemental/Organic Carbon, Major Inorganic Ions, and Major Elements ... 102
General Equation for Uncertainty 106
Uncertainty in PM Mass Emission Factor Estimation 107
Uncertainty in PM-2.5 Organic Carbon Concentration 107
Uncertainty in Gas-Phase Semivolatile Organic Species Emission Factors ... 109
Uncertainty in Particle-Phase Semivolatile Organic Species Emission
Factors 109
Uncertainty in PM-2.5 Elemental and Ion Concentrations 110
Speciated Gas- and Particle-Phase Organic Compounds 110
Gas-Phase Carbonyl Compounds 131
Gas-Phase Air Toxics Whole Air Samples 137
Gas-Phase Speciated Nonmethane Organic Compounds 138
Particle Size Distribution Data 149
Section 6 Quality Assurance/Quality Control 158
Carbonyl Compound Analysis 169
Concurrent Air Toxics/Speciated Nonmethane Organic Compound (SNMOC)
Analysis 169
PM Mass Measurements, Elemental Analysis, Water-Soluble Ion Analysis,
and GC/MS Analysis 170
Section 7 References 171
Appendices
in
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Table of Contents (Continued)
A Table of Unit Conversions
B Example Calculations NMOC, SNMOC, and Carbonyl Emission Factors
C Method Detection Limits
D EPA Method Operating Procedures
ERG Standard Operating Procedures
E Chain of Custody Forms
F Sample Logs for Both Campaigns
G Data Tables for Individual NMOC Samples Campaign #1 Only
H Supporting Data for Air Toxics Analysis
I Supporting Data for Carbonyl Analysis
J Individual PM-2.5 Mass Measurements Both Campaigns
K Example Calculations: PM-2.5 Emission Factors Both Campaigns
L Individual PM-2.5 EC/OC Measurements Both Campaigns
M Individual PM-2.5 Elemental Measurements Both Campaigns
N Individual PM-2.5 Inorganic Ion Measurements Both Campaigns
O Individual or Composited Particle-Phase Semivolatile Organic Compounds
Quartz Filters
P Individual Gas-Phase (PUF) Semivolatile Organic Compounds
IV
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List of Figures
3-1 Diagram of the dilution sampler and dilution air conditioning system 17
3-2 Instrumentation for control and analysis of the dilution sampler 20
3-3 Schematic Diagram of Test Boiler Exhaust to Stack Connection 23
3-4 Diagram of the sampling port 27
3-5 Sampling port with cap plate 29
3-6 Ground level access to the test facility 30
3-7 Testing area, ground level 31
4-1 Dilution sampling system elevated on mobile lift for access to the sampling port 46
4-2 Dilution system sampling probe installed in 6 in. i.d. flanged port 47
4-3 Dilution system control module positioned at the sampling location 48
4-4 TSI particle sizer positioned at the sampling location (January 16, 2001) for
Campaign #1 49
4-5 ELPI particle size positioned at the sampling location (July 7, 2002) for
Campaign #2 50
4-6 Dilution system with all sample collection arrays and instruments attached for
Campaign #1 51
4-7 Dilution system sampling module, together with sample collection arrays, for
Campaign #2 52
4-8 Sample recovery area 54
4-9 Sample recovery area 55
4-10 Teflon filter being removed from the holder in preparation for packaging for
transport to the laboratory 56
4-11 Schematic diagram of sample collection arrays used in field test (January 16-18, 2001)
for Campaign #1 60
4-11A Schematic diagram of sample collection arrays used in field test (January 16-18, 2001)
for Campaign #1, showing denuders used on only one test day 61
4-12 Schematic diagram of sample collection arrays used in field test (January 9-11, 2002)
for Campaign #2 64
4-13 Blower flow, Test 1 - Day 1, January 16, 2001, Campaign #1 73
4-14 Dilution flow, Test 1 - Day 1, January 16, 2001, Campaign #1 73
4-15 Venturi flow, Test 1 - Day 1, January 16, 2001, Campaign #1 74
4-16 Blower flow, Test 2 - Day 2, January 17, 2001, Campaign #1 74
4-17 Dilution flow, Test 2 - Day 2, January 17, 2001, Campaign #1 75
4-18 Venturi flow, Test 2 - Day 2, January 17, 2001, Campaign #1 75
4-19 Blower flow, Test 3 - Day 3, January 18, 2001, Campaign #1 76
4-20 Dilution flow, Test 3 - Day 3, January 18, 2001, Campaign #1 76
4-21 Venturi flow, Test 3 - Day 3, January 18, 2001, Campaign #1 77
4-22 Blower flow, Test 1 - Day 1, July 9, 2002, Campaign #2 84
4-23 Dilution flow, Test 1 - Day 1, July 9, 2002, Campaign #2 84
4-24 Venturi flow, Test 1 - Day 1, July 9, 2002, Campaign #2 85
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List of Figures (Continued)
4-25 Blower flow, Test 2 - Day 2, July 10, 2002, Campaign #2 85
4-26 Dilution flow, Test 2 - Day 2, July 10, 2002, Campaign #2 86
4-27 Venturi flow, Test 2 - Day 2, July 10, 2002, Campaign #2 86
4-28 Blower flow, Test 3 - Day 3, July 11, 2002, Campaign #2 87
4-29 Dilution flow, Test 3 - Day 3, July 11, 2002, Campaign #2 87
4-30 Venturi flow, Test 3 - Day 3, July 11, 2002, Campaign #2 88
5-1 Graphical presentation of particle size data, SMPS (January 16, 2001) 152
5-2 Graphical presentation of particle size data, SMPS (January 17, 2001) 152
5-3 Graphical presentation of particle size data, SMPS (January 18, 2001) 153
5-4 ELPI Mass Concentration by Stage (July 9, 2002) 156
5-5 ELPI Mass Concentration by Stage (July 10, 2002) 156
5-6 ELPI Mass Concentration by Stage (July 11, 2002) 157
5-7 ELPI Mass Concentration by Stage (Three-Day Average) 157
6-1 ERG chain of custody form 168
VI
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List of Tables
2-1 Results Summary for Industrial Scale Oil-Fired Boiler
3-1 Sampling Medium Used for Collection of Samples, Analysis Performed, Analytical
Method, and Responsible Laboratory 14
3-2 Analysis of the #2 Distillate Oil Used to Fuel the Institutional Boiler 22
3-3 Fuel Use Data for Testing Days: #2 Distillate Oil 24
4-1 EPA Method 1—Traverse Point Location for Institutional Boiler Exhaust
(A Rectangular Duct) 34
4-2 Campaign-Specific Flue Gas Velocity for Each Traverse Point 36
4-3 Carbon-Based Calculation of Flue Gas Flow Rates 37
4-4 Moisture Recovery for Method 4 42
4-5 Blank Values for Veriflows and Canisters (Campaign #1) 58
4-6 Run Time Summary Information, Test Run #1, Campaign #1 67
4-7 Run Time Summary Information, Test Run #2, Campaign #1 69
4-8 Run Time Summary Information, Test Run #3, Campaign #1 71
4-9 Run Time Summary Information, Test Run #1, Campaign #2 78
4-10 Run Time Summary Information, Test Run #2, Campaign #2 80
4-11 Run Time Summary Information, Test Run #3, Campaign #2 82
4-12 Carbonyl Compounds Analyzed by High Performance Liquid Chromatography 94
4-13 Air Toxics Compounds Determined by Analytical Method TO-15 97
4-14 Speciated Nonmethane Organic Compounds Determined According to the
Procedures of EPA Research Operating Procedure "Research Protocol Method for
Analysis of C2-C12 Hydrocarbons in Ambient Air by Gas Chromatography with
Cryogenic Concentration" 99
5-1 Summary of Oil-Fired Institutional Boiler Results 103
5-2 Gas Phase Semivolatiles: Emission Factors from an Institutional Oil-Fired Boiler
(Campaign #2, July 2002) Ill
5-3 Particle-Phase Semivolatiles from an Institutional Oil-Fired Boiler: Mass Fractions
(Campaign #2, July 2002) 118
5-4 Particle-Phase Semivolatiles from an Institutional Oil-Fired Boiler: Emission Factors
(Campaign #2, July 2002) 125
5-5A Carbonyl Compounds Analyzed by High Performance Liquid Chromatography
(Campaign #1, January 16, 2001) 132
5-5B Carbonyl Compounds Analyzed by High Performance Liquid Chromatography
(Campaign #1, January 17, 2001) 134
5-5C Carbonyl Compounds Analyzed by High Performance Liquid Chromatography
(Campaign #1, January 18, 2001) 135
5-6 Total Mass of Carbonyl Compounds for Each Campaign #1 Test Day 137
5-7 Air Toxics Compounds (Campaign #1) 138
5-8A SNMOC (Campaign #1, January 16, 2001) 139
vii
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List of Tables (Continued)
5-8B SNMOC (Campaign #1, January 17, 2001) 142
5-8C SNMOC (Campaign #1, January 18, 2001) 145
5-9 Total Mass of Nonmethane Organic Compounds for Each
Campaign #1 Test Day 148
5-10 Particle Size Diameter Measurements, TSI SMPS
(Campaign #1, January 16-18, 2001) 150
5-11 Gravimetric Data, ELPI (Campaign #2, July 9-11, 2002) PM-2.5 Mass
Concentration by Size 155
6-1 Sample Collection Equipment: Quality Criteria 159
6-2 Carbonyl Analysis: Quality Criteria 160
6-3 Air Toxics and SNMOC Analysis: Quality Criteria 162
6-4 PM Mass Measurements: Quality Criteria 163
6-5 Elemental Analysis: Quality Criteria 164
6-6 Water-Soluble Ion Analysis: Quality Criteria 164
6-7 Semivolatile Organic Compounds Analysis: Quality Criteria 165
Vlll
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Acknowledgments
Dave-Paul Dayton, Mark Owens, and Robert Martz of Eastern Research Group, Inc.
(ERG) were responsible for conducting sampling at the test site and for preparing collected
samples for transport to the analytical laboratories. Amy Frame, Donna Tedder, Laura
VanEnwyck, Tina Agnew, and Randy Bower of ERG were responsible for the carbonyl and
volatile organic compound analyses. Joan Bursey of ERG provided data analysis and sections of
the report pertaining to the ERG work on the project. Manieta Roman of ERG prepared the
typewritten manuscript.
Michael Hays, Kara Linna, and Jimmy Pau of the EPA were responsible for the analysis
of organic compounds, elements, and ionic species. Yuanji Dong, John Lee, David Proffitt, and
Tomasz Balicki of ARCADIS, Geraghty & Miller, Inc., provided technical support in preparing
the dilution sampling system and sampling substrates, in performing the elemental/organic
carbon analyses, and in extracting organic compounds from the various sampling substrates.
N. Dean Smith was the EPA Project Officer responsible for field testing efforts. Lee L. Beck
was the EPA Project Officer responsible for the Final Report.
IX
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Section 1
Introduction
In July 1997, the U.S. Environmental Protection Agency (EPA) promulgated new
National Ambient Air Quality Standards (NAAQS) for ambient particulate matter of
aerodynamic diameter 2.5 |im or less (PM-2.5). Implementation of the new standards has been
delayed to allow EPA time to better understand the factors underlying the observed correlation
between ambient fine PM and adverse human health effects and to better evaluate risk
management options.
States are required under the federal consolidated emission reporting rule (CERR) to
report emissions information to U.S. EPA for inventory and planning purposes, including PM25
and ammonia. The purpose of the CERR is to simplify reporting, offer options for data
collection and exchange, and unify reporting dates for various categories of criteria pollutant
emission inventories. This rule consolidates the emission inventory reporting requirements
found in various parts of the Clean Air Act (CAA). Consolidation of reporting requirements
enables state and local agencies to better explain to program managers and the public the
necessity for a consistent inventory program, increases the efficiency of the emission inventory
program, and provide more consistent and uniform data. One concern with this reporting
requirement is there are no reliable emission factors to use for estimating PM2 5 or NH3. Sources
should be able to provide more accurate emission estimates than are currently available in
emission inventories or AP-42. This is especially concerning to Title V sources that are required
to certify the emissions estimate.
Fine particles can be directly emitted from sources or, like ozone, can be formed in the
atmosphere from precursor gases. The most common source of directly emitted PM25 is
incomplete combustion of fuels containing carbon (fossil or biomass), which produces
carbonaceous particles consisting of a variety of organic substances and black carbon (soot), as
well as gaseous carbon monoxide, VOCs and NOX. Certain high energy industrial processes also
emit primary PM25. Examples of direct PM25 sources include diesel and gasoline vehicles, open
1
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burning, residential wood burning, forest fires, power generation, and industrial metals
production and processing. The major gaseous precursors of secondary PM25 include SO2, NOX,
certain VOCs and NH3. Secondary formation of PM25 involves complex chemical and physical
processes. The major sources of secondary PM25 forming gases (SO2, NOX, certain VOCs, NH3)
include nearly every source category of air pollutants. Major SO2 sources in the U.S. include
coal-fired power plants and industrial boilers and smelters. EPA required states upwind of PM2 5
nonattainment areas to control and reduce emissions of sulfur dioxide (SO2) or nitrogen oxides
(NOX). Measurement of the primary PM25 content and the chemicals that participate in
secondary fine particulate formation is important in PM control and attainment of NAAQS.
Consequently, EPA has concluded that small contributions of pollution transport to downwind
nonattainment areas should be considered significant from an air quality standpoint because
these contributions could prevent or delay downwind areas from achieving the health-based
standards.
In 1999, a national network of ambient monitoring stations was started under the overall
guidance of the EPA's Office of Air Quality Planning and Standards (OAQPS) to assist the
States in determining regulatory nonattainment areas and to develop State Implementation Plans
(SIPs) to bring those areas into compliance with the law for PM-2.5 regulations. One component
of the monitoring network was seven supersites: i.e., urban airsheds in which intensive
coordinated PM-related research was carried out to better understand the atmospheric formation,
composition, and sources of fine PM.
To further support development of better emission factors and an understanding of the
formation of fine particulate after emissions leave stationary sources, the Emissions
Characterization and Prevention Branch (ECPB) of the Air Pollution Prevention and Control
Division (APPCD) implemented research to characterize PM-2.5 emissions from specific source
categories. This research focuses on updating and improving source emission rates and profiles
for PM-2.5 with the aim of improving the quality of data used for dispersion and receptor
modeling and of providing quality emissions data for risk management strategies.
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This program has concentrated its PM source sampling efforts on the sources and types
of PM-2.5 where data are most needed, with a primary focus on the collection of fine particles
emitted by combustion sources, both stationary and mobile. To ensure that the collected PM is
representative of the PM collected by ambient monitors downstream of the source, PM samples
were collected using a dilution sampling method to simulate the processes of cooling and
condensation that occur when material leaves a stack as hot exhaust gas and to provide a means
to comply with the requirements of the Consolidated Emissions Reporting Rule.
The mission of the ECPB of the APPCD is to characterize source emissions and develop
and evaluate ways to prevent those emissions. Source characterizations as defined here include
the measurement of PM mass emission rates, source PM profiles (PM chemical composition and
associated chemical mass emission rates), and emission rates of ambient aerosol precursors such
as SOX, NOX, and NH3.
PM mass emission rates are used in emission inventories and as inputs to atmospheric
dispersion models that yield estimates of ambient PM concentrations from considerations of
atmospheric transport and transformation of emitted particles. Source characterization data are
used in receptor models which enable apportionment of ambient concentrations of PM to the
various sources that emitted the particles and in atmospheric dispersion models that compute the
formation of secondary organic aerosols. Source types for testing in this program were selected
on the basis of the quantity of fine PM emitted by the source as determined from existing
emission inventories and on the basis of the quality of existing PM-2.5 source profiles for each
source type. This report presents the results of testing one source type so selected, an
institutional scale oil-fired boiler (SCC 1-02-005-01)1.
Description of Testing and Testing Objectives
This test report describes the measurement and characterization of fine particulate matter
(fine PM) emissions and volatile organic compound (VOC) emissions from an institutional scale
#2 distillate oil-fired boiler with a rated capacity of 60,000 Ibs/h (18.7 MW, 67.3 GJ/h)1. This
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category of boilers was responsible for an estimated 1245.4 kJ (ca. 45.6%) of distillate oil
consumption in the U.S. in 19902. The boiler tested in this study was one of three boilers in a
university power plant that provided space and water heating to a number of buildings on the
university campus. Sampling was conducted in the exhaust duct of one boiler prior to the point
at which all three boiler exhausts were combined into a single exhaust stream to the power plant
stack. The boiler employed low-NOx burners for control of NOX emissions, but no devices for
control of particulate matter were utilized.
The report presents results of the test efforts in two ways:
As mass emission factors (i.e., mass of emitted species per unit mass of fuel
consumed), and
Mass fraction composition of the particle and gas phase emissions.
Mass emission factors are useful for emission inventories and for atmospheric dispersion models
that yield estimates of ambient pollutant concentrations via considerations of atmospheric
transport and transformation of emitted species. Compositional data are used in source-receptor
models to enable the apportionment of ambient air pollutants to the responsible pollutant
sources.
Source-receptor models such as the Chemical Mass Balance (CMB) model require as
input both the chemical composition of the ambient air samples and the composition of the
emissions of all major sources contributing to the ambient pollutants. The oil-fired boiler
emission tests described here are among a number of such tests of significant emission sources
aimed at updating and improving the quality of source emission profiles in EPA's source profile
database (SPECIATE), which is available for use by state and local environmental agencies and
others for source-receptor modeling.
Sampling the hot stack gas emissions in the present study involved withdrawing a known
amount of sample from the exhaust duct of the boiler and cooling and diluting the sample stream
4
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with cleaned ambient air to near ambient conditions prior to collecting the particle- and gas-
phase emissions. A custom-fabricated dilution sampler following the design by Hildemann et
al.3 was used. This sampler was constructed entirely of electropolished stainless steel and
contained no rubbers, greases, or oils to ensure no introduction of organic contaminants in the
samples. Ambient air used to dilute the stack gas was pre-cleaned by means of a HEPA filter, a
large bed of activated carbon (carbonaceous material contained in a 30-gallon drum), and a
Teflon membrane filter prior to mixing with the stack gas. By sampling in this way, the particle
emissions are deemed to be more representative of the material as it exists in the ambient air
downwind of the source.
The boiler was tested in two separate campaigns. An initial test series (i.e., campaign #1)
was conducted in January 2001. The primary objective of the first campaign effort was to
chemically characterize the fine PM emissions (i.e., PM-2.5, particles equal to or less than 2.5
|im aerodynamic diameter) and to develop emission factors for EPA's SPECIATE data base.
Many past efforts have focused on the coarse fraction of emitted PM (PM-10) or only the
filterable portion of emitted PM. Condensible PM, which can form when a hot exhaust stream is
diluted and cooled with ambient air, has not often been characterized in previous work. Also,
earlier chemical characterization studies of PM were often limited to the elemental composition
of the material with the nature of the organic content of carbonaceous PM unidentified.
This initial test series included a trial run to determine an appropriate test duration and to
ensure all systems were operating properly. The trial run was followed by three replicate
sampling runs, one run on each of three successive days. Samples of gas phase organic
compound emissions were collected concurrently with the fine PM samples in test campaign #1,
and results of these gaseous emissions determinations are also reported here for completeness.
A second test series (i.e., campaign #2) was conducted in July 2002 in collaboration with
the EPA's OAQPS, Emissions Monitoring and Analysis Division (EMAD). The second
campaign had a dual purpose:
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To provide referee comparative data to EMAD to help in the development of a
more compact and portable dilution sampler suitable for routine regulatory
compliance stack gas sampling and for source emissions profiling; and
To compare the PM2.5 results of the two test campaigns conducted at winter and
summer boiler operating conditions, respectively.
A prototype of the EMAD sampler design was operated concurrently with the Hildemann-
designed sampler so that results of the two devices could be compared under the same boiler
operating conditions.
Some of the experimental design matrix was changed for the second campaign to focus
effort on measurements that provided comparison between the Hildemann designed sampler and
the EMAD prototype sampler. Measurements focused on contributions to PM2.5 and its
formation. Semivolatile organic compound sampling and analysis was added to assess a fuller
range of condensible organic compounds. Organic and elemental carbon as well as inorganic
components contributing to particulate formation were included in both campaigns enabling
consistent PM2.5 comparisons between campaigns and between the sampling trains.
This report presents only the results derived from the Hildemann-designed dilution
sampler for the two test campaigns. The EMAD sampling system and procedure can be found at
http://www.epa.gov/ttn/emc/ctm.html in conditional test method CTM-039.
Organization of Report
This report is organized into five additional sections plus references and appendices.
Section 2 provides the conclusions derived from the study results, and Section 3 describes the
process operation and the test site. Section 4 outlines the experimental procedures used in the
research, and Section 5 presents and discusses the study results. Section 6 presents the quality
control/quality assurance procedures used in the research to ensure generation of high quality
data. Section 7 presents the references cited in this report.
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Section 2
Conclusions
Salient results from both the winter 2001 and summer 2002 test campaigns (campaign #1
and campaign #2, respectively) at the institutional-scale oil-fired boiler are summarized in
Table 2-1. Complete tabulated results with associated uncertainties are provided in Section 5 of
this report, along with the combustion parameters data (i.e., O2, CO, H2O, fuel consumption).
Table 2-1. Results Summary for Industrial Scale Oil-Fired Boiler
Campaign #1 Campaign #2
Test Date
Emission Factors (mg/kg fuel):
PM-2.5 mass3
Particle mass semivolatile organic species
Gas-phase semivolatile organic species
Nonmethane volatile organic compounds
Speciated
Total
Gas-phase carbonyls
Speciated
Total
PM Composition (wt.%):
Elemental carbon (EC)
Organic carbon (OC)
Sulfate
Ammonium
Sulfur
Silicon
1/16/01
26.9
NS
NS
3.0
2.4
0.25
.27
1.8
NQ
58.0
NQ
5.2
NQ
1/17/01
32.1
NS
NS
18.7
18.0
0.30
0.30
10.5
0.5
56.9
NQ
3.4
NQ
1/18/01
39.8
NS
NS
32.7
35.3
0.50
0.55
34.0
NQ
45.5
NQ
8.3
NQ
7/9/02
40.4
1.0
89.5
NS
NS
NS
NS
5.8
43.3
6.8
2.0
2.7
0.89
7/10/02
42.7
0.66
75.4
NS
NS
NS
NS
3.1
45.7
10.7
2.6
3.7
0.75
7/11/02
178.0
7.9
123.1
NS
NS
NS
NS
1.6
63.1
3.5
0.46
1.3
0.24
NQ = below quantitation limit; NS = not sampled
a Filterable only.
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The filterable PM-2.5 mass emission factor was fairly consistent throughout both test
campaigns with the exception of one day during campaign #2 (7/11/02) for which the emission
factor was nearly five times higher than the average of the other five test days. Excluding the
single day of markedly higher emissions, the average PM-2.5 mass emission factor was 36.4 mg
per kg of fuel (0.81 |ig/kJ) with a range of 26.9 to 42.7 mg/kg (0.60 - 0.96 |ig/kJ). The single
day of substantially higher PM-2.5 emissions gave an emission factor of 178.0 mg per kg of fuel
(3.99 |ag/kJ). No unusual event on that day was identified to explain the higher PM-2.5
emissions for that test. However, during both campaign #1 and campaign #2 the boiler was
operated at very low load where combustion conditions are difficult to maintain. Under such
conditions, erratic behavior in boiler operation and emissions may occur.
A PM-2.5 emission factor for industrial-scale distillate oil-fired boilers with no PM
emission controls has been estimated by the EPA as 283 - 313 mg/kg of fuel with fuel sulfur
contents ranging from 0.05 - 0.09 wt %, respectively.4 It should be noted that these EPA
estimates do not consider the condensible portion of fine PM. From this study, the average
PM-2.5 emission factor for campaign #1 when the fuel contained 0.09% sulfur was 32.9 mg/kg,
nearly an order of magnitude less than the estimated EPA value. The average PM-2.5 emission
factor for campaign #2 when the fuel contained 0.05% sulfur was 41.6 mg/kg (excluding the
single high emission day) or 87.0 mg/kg with all three test results averaged. These values are 6.8
and 3.3 times less than the current EPA estimated emission factor, respectively.
The PM-2.5 mass emission factor was fairly consistent for both test campaigns, whereas
the composition of the PM-2.5 was very different for the two campaigns. Sulfate comprised 45.5
to 58.0% by mass of the PM-2.5 emitted during campaign #1 but accounted for only 3.5 to
10.8% of the PM-2.5 mass during campaign #2. Conversely, there was much more carbon in the
PM-2.5 emitted during campaign #2, most of which was organic carbon (43.3 to 63.1% of the
PM-2.5 mass). The organic carbon (OC) content of the fine PM was highest for Test Day #3 of
campaign #2 (7/11/02), for which the PM-2.5 emission factor was also the highest of all tests.
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Most of the speciated and quantified OC associated with the fine PM was made up of the
C16 through C31 w-alkanes (63.8 wt % of the speciated PM organics). w-Tetracosane (C24) was
the single most prominent w-alkane with the other C16 - C31 species in a near-Gaussian
distribution by carbon number around C24. Benzene di- and tri-carboxylic acids comprised the
second largest category of organic constituents found in the fine PM (21.4 wt % of the quantified
species). Polynuclear aromatic hydrocarbons (PAHs) and w-alkanoic acids made up most of the
remaining 14.8% of the quantified and speciated particle-phase organic compounds. The
benzene di- and tri-carboxylic acids and chrysene were the only semivolatile organic species
confined to the particle phase. All of the other semivolatile species were found in both the gas
and particle phases with the predominant amounts in the gas phase. The only two elements in
the PM found at levels above method quantitation limits were silicon and sulfur.
Two factors may have contributed to this marked difference in PM composition. The
sulfur content of the fuel oil was 1.8 times higher during the campaign #1 tests than during the
campaign #2 tests (0.09 vs 0.05 wt %, respectively). This factor could have contributed to a
higher sulfate content during the campaign #1 tests. During the campaign #2 tests, the fuel feed
rate averaged 37.6% lower than for the campaign #1 tests, and the excess oxygen levels were
much higher (campaign #2 = 15.7 to 20.5%; campaign #1 = 7.6 to 9.2% excess oxygen). During
campaign #1, the boiler was fired at 37 - 42% of its rated capacity; during campaign #2, the
boiler was fired at only 25% capacity. A lower combustion efficiency associated with the low
combustion load during the summertime is likely responsible for the PM emissions being
enriched in OC.
A quantitative analysis of individual organic compounds associated with the organic
carbon content of the fine PM was not possible for the campaign #1 owing to breakthrough of
the organic species in the PM sampling arrays during the tests. For the campaign #1 tests, XAD-
coated annular denuders were used in front of pre-fired quartz filters in an attempt to minimize
adsorption of gas-phase organic species on the quartz filters and a consequent positive artifact in
the PM mass and PM organic carbon content. Polyurethane foam (PUF) plugs were employed
behind the quartz filters to collect any particle-phase semivolatiles that were air stripped from
-------
the filters during sampling. Sampling durations were long (i.e., 10 hours per test) in an attempt
to gather sufficient fine PM for analysis of particle-phase organics. However, the lengthy
sampling periods resulted in exceeding the capacity of the denuders and PUF plugs. Therefore,
an unknown quantity of organic compounds passed through the arrays and could not be
accounted for.
During the campaign #2 test, the denuders were omitted from the sample collection
arrays, and an attempt was made to correct for the positive Organic Carbon (OC) artifact in the
PM collected on the quartz filters by subtracting from each of these filters the amount of OC
collected on a quartz filter placed behind a Teflon membrane filter. This correction was based
on the presumption that the Teflon filter collected particle-phase organic compounds and the
backup quartz filter behind the Teflon filter collected adsorbed gas-phase organics equivalent to
those adsorbed on the undenuded primary quartz filter. Even with this substantial correction, the
PM collected during the summer campaign contained much more OC than the PM collected
during the winter campaign.
Gas-phase organic nonmethane volatile organic compounds (NMOC) and carbonyl
compound emissions were measured only during the campaign #1 tests, when the boiler was
operating at more typical load conditions. For the campaign #1 tests, total NMOC (speciated +
unspeciated) and PM-2.5 mass emission factors increased with increasing fuel consumption rates
(2.42, 17.96, and 35.30 mg/kg for successive test days), but total gas-phase carbonyl compound
emission factors exhibited the opposite trend.
A Scanning Mobility Particle Sizer (SMPS) operated on all three test days during the
campaign #1 tests and collected data on particle size distribution in the range below 2.5 |im (the
range monitored was 10 nm to 392 nm), with one complete scan over the entire range every three
minutes. Both the particle size distribution and particle number count observed on Day 1
(January 16, 2001) differed with respect to the other two test days. The number of counts
observed in each channel was approximately four orders of magnitude lower on Day 1 than on
the other two test days. The SMPS instrumental operating parameters appeared to be normal,
10
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and there was no obvious indication of instrumental malfunction. On the second and third test
days, the number counts and distribution profiles were similar to the distributions centered at 46
nm and 50 nm, respectively.
During campaign #2, particle size data were collected using an Electrical Low Pressure
Impactor (ELPI). The particle size distribution suggests bimodal behavior. Note that the SMPS
gives an electrical mobility diameter and the ELPI gives an aerodynamic diameter, so the two
values should not necessarily agree.
Results of this study indicate that the fine PM composition emitted from an institutional-
scale oil-fired boiler can be markedly different depending on the combustion load and the
characteristics of the fuel. Therefore, to the extent possible, source-receptor modeling should
consider these conditions when selecting profiles and fitting species for source apportionment
modeling. In this study, the boiler tested produced a wide variation in particle size and
composition dependent on the fuel combustion and fuel composition. Industrial-scale boilers
used to generate process steam and utility boilers used to generate power may be less susceptible
to changing demand and therefore emit a fine PM with a more consistent composition.
11
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Section 3
Methods and Materials
Description of the Testing Program
Two field tests (campaign #1, January 16-18, 2001; and campaign #2, July 7-9, 2002)
were conducted at an institutional-scale boiler fired with #2 distillate oil and located on the
campus of North Carolina A&T University in Greensboro, NC. Quality control procedures were
implemented to obtain source emissions measurements of high and known quality. To simulate
the behavior of fine particles as they enter the ambient atmosphere from an emissions source,
dilution sampling was performed to cool, dilute, and collect gaseous and fine particulate
emissions from the institutional-scale oil-fired boiler. Gaseous and fine particulate material
collected during the sampling was also characterized. ERG coordinated all field test activities;
laboratory testing activities were divided between EPA and ERG according to the scheme shown
in Table 3-1.
The objectives of the testing activities were to evaluate the sampling equipment and to
characterize the fine particulate emissions from an institutional oil-fired boiler. ERG performed
source sampling to collect artifact-free, size-resolved particulate matter in a quantity and form
sufficient to identify and quantify trace elements and organic compounds and to distinguish gas-
phase and particle-phase organic compounds. Total particulate matter mass in the diluted and
cooled emissions gas was size resolved at the PM-10 and PM-2.5 cut points with the PM-2.5
fraction further continuously resolved down to 30 nm diameter using a particle size analyzer.
Fine particle emission profiles can be used in molecular marker-based source apportionment
models, which have been shown to be powerful tools to study the source contributions to
atmospheric fine particulate matter.
12
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Table 3-1. Sampling Medium Used for Collection of Samples, Analysis Performed,
Analytical Method, and Responsible Laboratory
Sampling Medium
Teflon Filter
Teflon Filter
Teflon Filter
Quartz Filter
Analysis
PM-2.5 mass
Elemental Analysis
Inorganic Ions
Elemental Carbon/
Method
Gravimetric (GRAY)
X-ray fluorescence (XRF)
Ion Chromatography (1C)
Thermal-Optical Evolution (TOE)
Laboratory
EPA
EPA
EPA
EPA
Quartz filter
XAD-4 denuder
PUF
DNPH-impregnated
silica gel tubes3
SUMMA canisters3
Particle Size
Analyzer
Organic Carbon
Organic species
Carbonyl compounds
Air Toxics
Speciated Nonmethane
Organic Compounds
Particle Sizes
Gas Chromatography/ Mass EPA
Spectrometry (GC/MS)
High Performance Liquid ERG
Chromatography (HPLC)
Method TO-11A
GC/MS ERG
Method TO-15
ERG Concurrent Analysis
Scanning Mobility Particle Sizer ERG
(SMPS)
Electrical Low Pressure Impactor
(ELPI)
aDNPH tubes and SUMMA canisters were used for campaign #1 only.
To assist in the characterization of the stationary source and to obtain chemical
composition data representative of particle emissions after cooling and mixing with the
atmosphere, ERG performed the following activities at the test site:
Performed preliminary measurements using EPA Methods 1-4 to evaluate source
operating conditions and parameters;
Installed the pre-cleaned dilution sampling system, sample collection trains, and
ancillary equipment at the field site without introduction of contaminants;
Calibrated flow meters before and after sampling, monitoring and adjusting gas
flows (as necessary) throughout the tests;
13
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Acquired process data for the test periods, including temperatures, pressures,
flows, fuel consumption, etc.;
Determined the type of combustion fuel and rate of consumption during the
source testing;
Collected six sets of stationary source samples (three per test campaign) as
prescribed in the Site-Specific Test Plans, including field blanks (one per test
campaign); and
Recovered the dilution sampling unit and sample collection trains for analysis for
specific parameters and return of the dilution sampling unit to EPA.
For Test campaign #1, ERG transported the dilution sampling system to the test site to
collect integrated samples, performed whole air analysis of SUMMA-polished stainless steel
canisters and gas-phase carbonyl compounds collected on silica gel cartridges impregnated with
2,4-dinitrophenylhydrazine (DNPH), and evaluated particle size distribution data. EPA was
responsible for pre-test cleaning of the dilution system, for analysis of semivolatile organic
compounds from XAD-4 denuders and polyurethane foam (PUF) modules resulting from the test
efforts and for characterization of the particulate-phase emissions and mass loading on quartz
and Teflon filters. For Test campaign #2, ERG transported the dilution sampling system to the
test site to collect integrated samples and evaluated particle size distribution data. EPA was
responsible for pre-test cleaning of the dilution system, for analysis of semivolatile organic
compounds from polyurethane foam (PUF) modules resulting from the test efforts and for
characterization of the parti culate-phase emissions and mass loading on quartz and Teflon filters.
Description of Test Equipment
Dilution Sampling System
The dilution sampling system used in the source test was based on the original design by
Dr. L. M. Hildemann3, modified to incorporate more secure closure fittings and electronic
controls. Automatic flow control and data acquisition capabilities were added to the dilution
14
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sampler to improve the ease of operation of the unit. A touchscreen interface connected to the
main controller was used to monitor current conditions and allow setpoints to be entered into the
system readily. A laptop computer was used for continuous monitoring of operating parameters
and logging of the sampler operation.
The dilution sampling system dilutes hot exhaust emissions with clean air to simulate
atmospheric mixing and particle formation. Control of residence time, temperature, and pressure
allows condensible organic compounds to adsorb to fine particles as they might in ambient air.
The sampler is also designed and fabricated to minimize any contamination of samples,
especially organic compound contamination, and to minimize particle losses to the sampler
walls.
Figure 3-1 shows a schematic diagram of the dilution sampling system and dilution air
cleaning and conditioning system. As shown, the dilution air cleaning system provides high
efficiency particulate arresting (HEPA) and activated carbon-filtered air for dilution of source
emissions. Acid gases (if present) will not be completely removed by the dilution air cleaning
system, but the presence of acid gases can be monitored in the dilution tunnel immediately
downstream of the dilution air inlet. The dilution air cleaning system can be modified to add a
heater, cooler, and dehumidifier as needed. Cleaned dilution air enters the main body of the
sampler downstream of the dilution air orifice meter. The key zones of the dilution sampling
system and their function are discussed below.
Sample Inlet Zone—
Stack Emissions Inlet: designed to allow source exhaust gas to be sampled
through an inlet cyclone separator to remove particles with nominal aerodynamic
diameters > 10 |im. The PM-10 cyclone prevents large particles from entering the
sampler to plug or damage the equipment. Three ports are dedicated to sampling
of the dilution air before it mixes with the source gas.
Heated Inlet Line: 3/4" heated stainless steel sampling probe draws source gas
through a venturi meter into the main body of the sampler. Sample flow rate can
be adjusted from 15-50 Lpm (typically 30 Lpm).
15
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Turbulent Mixing Chamber
10jjm
CYCLONE
HEATED INLET LINE
STACK
EMISSIONS INLET
LOWER J
-^""^
V
COOLING
UNIT
HE PA
FILTER
ACTIVATED
CARBON
BED
DILUTION AIR
INLET
Figure 3-1. Diagram of the dilution sampler and dilution air conditioning system.
-------
Venturi Meter—
Constructed of low carbon, very highly corrosion-resistant stainless steel;
equipped for temperature and pressure measurement. Wrapped with heating coils
and insulated to maintain the same isothermal temperature as the inlet cyclone
and inlet line.
Turbulent Mixing Chamber—
Consists of an entrance zone, U-bend, and exit zone.
Inside diameter: 6 in., yielding a Reynolds number of-10,000 at a flow rate of
lOOOLpm.
Dilution air enters the mixing chamber in the direction parallel to the flow.
Hot source emission gas enters the chamber perpendicular to the dilution airflow,
4.5 in. downstream of the dilution air inlet.
The combined flow travels 38 in. before entering the U-bend.
After the residence chamber transfer line, the mixing chamber continues for
18 in., then expands to an in-line high-volume sampler filter holder. Collected
particulate has not experienced time to equilibrate with the gas phase at the
diluted condition.
Sample and instrumentation ports are installed on the turbulent mixing chamber at
various locations.
Residence Time Chamber—
The inlet line to the residence time chamber expands from a 2 in. line (sized to
provide a quasi-isokinetic transfer of sample gas from the turbulent mixing
chamber to the residence time chamber at a flow rate of-100 Lpm) within the
mixing chamber to a 7 in. line at the wall of the residence chamber.
The flow rate is controlled by the total sample withdrawal from the bottom of the
residence time chamber and provides a 60-sec residence time in the chamber.
Twelve ports are installed at the base of the residence time chamber:
Nine ports for sample withdrawal;
Three ports for instrumentation.
Sample Collection Zone—
Samples collected from the sample ports at the base of the residence time
chamber have experienced adequate residence time for the semivolatile organic
compounds to re-partition between the gas phase and the particle phase.
17
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Since it is very difficult to maintain both isokinetic sampling and a fixed cyclone size cut during
most stack sampling operations, the inlet cyclone may be operated to provide a rough PM-10 cut
while maintaining near-isokinetic sampling. The rough inlet size cut has minimal impact on
sampling operations since the dilution sampling system is mainly used to collect fine particulate
matter from combustion sources and the critical fine particle size cut is made at the end of the
residence time chamber. Typically, the calculated total time the sample spends in the dilution
sampling system ranges from 58-75 sec: 2-3 sec for the turbulent mixing chamber and 56-72 sec
for the residence chamber.
Dilution Sampling System Control Instrumentation
Instrumentation for control and analysis of the dilution sampling system is shown in
Figure 3-2. Differential pressure measurements made across the venturi and orifice meters are
used to determine the dilution airflow rate, the sample gas flow rate, and the exhaust gas flow
rate. Since flow equations used for determination of the flow across venturi and orifice meters
correct for flowing temperature and pressure, the flowing temperature and pressure of the venturi
and orifice meters must be recorded during sampling operations. Thermocouples for monitoring
temperature are placed at each flow meter as well as at the inlet PM-10 cyclone, at various points
on the sample inlet line, at the inlet to the mixing chamber U-bend, and at the outlet of the
residence time chamber. An electronic relative humidity probe is used to determine the relative
humidity of the sample gas. The dilution sampling system is equipped with automated data
logging capabilities to better monitor source testing operations and to minimize manpower
requirements during sampling operations. Dilution sampler flows and temperatures are
monitored and controlled automatically at set points established by the operator using a QSI
Corporation QTERM-K65 electronic touch-screen interface. The dilution sampling system was
operated by three testing staff members during the test at the institutional oil-fired boiler facility.
In operation, the source sample flow, the dilution airflow, and the total airflow (not
including the sample collection arrays) were each measured by separate flow meters and
pressure
18
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Key:
TE = Temperature Indicator
PT = Pressure Indicator
RH = Relative Humidity Indicator
D
PM 10
Cyclone
(TE-103
PT-101 (TE-104
Dilution Air
Blower
HEPA Filter Carbon Bed
PT-1021
Exhaust
Blower
Residence
Time
Chamber
Figure 3-2. Instrumentation for control and analysis of the dilution sampler.
-------
transducers. A venturi measured the source sample flow and orifices were used for the dilution
and total flows. A ring compressor was used to push the dilution air through a HEPA filter, a
carbon adsorber, and a final filter into the turbulent mixing chamber. The compressor motor
was modulated by a variable frequency drive to match the desired dilution flow based on a set
point entry. A separate blower (connected to a speed controller adjusted to achieve the desired
sample flow based on a set point entry) at the end of the sampler pulled the source sample flow
through the venturi. Flow through this blower consisted of the dilution airflow plus the source
sample flow not including the flow exiting through the sample collection arrays.
The main controller modulated the power used to heat the sample probe (32 in. long, one
heated zone). The controller switched solid-state relays on and off as needed to maintain the
probe temperature entered by the operator.
Sample Collection Arrays
Virtually any ambient sampling equipment (including filters, denuders, PUF cartridges,
DNPH-impregnated sampling cartridges, SUMMA-polished canisters, cyclones, particle size
distribution measurement instrumentation) can be employed with the dilution sampling system.
The exact number and type of sample collection arrays is uniquely configured for each testing
episode.
Process Description/Site Operation!
With the concurrence of the EPA work assignment manager, an institutional oil-fired
boiler located at North Carolina A&T University in Greensboro, NC, that was used to heat
multiple dormitories was selected as the test site. The boiler, constructed by the Nebraska Boiler
Company, was permitted for operation with either #2 distillate oil or #6 residual oil. For the
duration of both tests (January 16-18, 2001, and July 7-9, 2002), the fuel used during testing was
#2 distillate oil.
20
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The watertube boiler tested was one of four boilers used to supply space and water
heating for several university buildings. The test boiler flue gas was connected through a
common duct with the other three boilers to a common exhaust fan and stack as shown in
Figure 3-3. The test boiler had a rated capacity of 67.3 GJ/h, was capable of utilizing either #2
distillate oil, #6 residual oil, or natural gas as fuel, and was equipped with a burner designed to
reduce NOX emissions by reducing the peak flame temperature at the flame base. Low NOX
operation of the burner was accomplished by staging the combustion process with specially
designed fuel nozzle injectors and an air recirculator. There were no control devices for control
of particulate matter emissions from the boiler. Emissions sampling was conducted at a
sampling port located in the exhaust gas duct from the boiler prior to the junction of that duct
with exhaust ducts from the other two boilers. Exhaust gases from all boilers were fed together
to a single stack from the university power plant.
The analysis of the #2 distillate oil used as fuel for the North Carolina A&T boiler is
shown in Table 3-2 for both test campaigns; slight differences in the analyzed values were
observed.
Table 3-2. Analysis of the #2 Distillate Oil Used to Fuel the Institutional Boiler
Component
sulfur
heat value
ash
carbon
hydrogen
nitrogen
oxygen
chlorine
Campaign #1
January 16-18, 2001
0.09%
19,374 BTU per pound
<0.01%
85.93%
13.66%
0.03%
0.26%
Not Determined
Campaign #2
July 7-9, 2002
0.05%
19, 193 BTU per pound
<0.01%
86.53%
12.75%
0.02%
0.65%
303.8ppm
21
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Building Roof
Isolation Plate Common Exhaust Duct
Boiler
(Not
operating)
Boiler
(Not in
Use)
Boiler
(Not in
Use)
Test
Point
Location
Exhaust Stack
Figure 3-3. Schematic Diagram of Test Boiler Exhaust to Stack Connection
22
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The fuel use for both test campaigns by test days is summarized in Table 3-3.
Table 3-3. Fuel Use Data for Testing Days: #2 Distillate Oil
Campaign # Test #
1
1 2
3
1
2 2
3
Test Date
1/16/01
1/17/01
1/18/01
7/09/02
7/10/02
7/11/02
Test Duration
(min)
600.33
600.50
600.17
600.60
600.67
600.00
Fuel Use
(gal/min)
3.428
3.615
4.134
2.314
2.331
2.333
Total Fuel
(gal)
2058
2171
2481
1390
1400
1400
Both test campaigns were scheduled to minimize disruption to the normal operation of the test
facility and to enable as much simultaneous data collection important to all parties as possible.
ERG scheduled the sampling test at the chosen facility and obtained permission and cooperation
of the site/institution/management.
Description of the Oil-Fired Boiler Tested at North Carolina A&T (Greensboro, NC)
The burner tested at North Carolina A&T (Greensboro, NC) was manufactured by Forney
Corporation and assembled on a 60,000 Ibs/hr Nebraska D-type water tube boiler. The
NOXMISER Low NOX burner is designed to reduce NOX emissions by reducing the peak flame
temperature at the flame base. The formation of NOX during the combustion process was:
• Exponentially proportional to peak flame temperature;
• Proportional to time duration at peak flame temperature; and
• Proportional to the square root of the number of oxygen molecules available at the
primary zone where the peak temperature occurs.
Low NOX operation is accomplished by staging the combustion process with specially designed
fuel nozzle injectors and an air recirculator. This mode of operation results in lower peak flame
23
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temperature yet stable flame with minimum flue gas recirculation and low carbon monoxide
emissions.
The combustion air forced draft fan, a direct-drive high performance airfoil fan designed
for a speed of 3500 rpm, is sized to provide all the required combustion air and flue gas for
recirculation. The combustion air forced draft fan is equipped with a 100% width inlet cone.
The airflow control damper is located between the windbox and forced draft fan; the damper
assembly is linked to the burner jack shaft.
The burner wind box, designed to provide equal air distribution into the air register,
contains the zone divider and the primary and secondary air slide damper assembly. The air
slide damper assembly provides a manual adjustment to the distribution of the total air between
the primary and secondary air zones.
A flame safeguard system, designed to provide proper burner sequencing for safe burner
operation, sequences the burner from purge, low fire ignition of the pilot, and main flame
automatically. The flame safeguard system monitors main flame, limit switches, and boiler
operating interlocks applicable to boiler operation, and interfaces with fuel shutoff valves and oil
pumps.
The burner consists of the subassemblies listed below:
• Basic Burner
- The basic burner is completely assembled with fuel and air control devices
with necessary control linkages and levers. Electrical components are pre-
wired, using Sealtite conduit, to a junction box. Oil and atomizing air
piping trains are a part of the basic burner.
• A burner refractory throat tile seal-welded to the boiler furnace plate, with plastic
refractory packed between the burner refractory throat and the furnace wall;
• Burner positioned to the boiler front plate with support to center the burner with
the refractory throat inside diameter;
24
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• Flame safeguard system, in its own enclosure, with a conduit and wiring to the
forced draft fan motor and separate conduits and wiring to junction box #1
(located at the burner) and junction box #2 (located at the gas train assembly), as
well as the boiler limit switches. House power was connected to the flame
safeguard enclosure fuse block;
• Gas train assembly with gas vent lines installed per applicable codes, piped to the
designated safe and nonhazardous location;
• Piping connecting the fuel gas train outlets to the burner flow control valve inlet,
with fuel oil and atomizing medium supplied to the burner on a combination fuel-
firing boiler; and
• A stack gas fuel inlet nozzle located approximately five stack diameters
downstream of the boiler smoke box outlet, with a fuel gas recirculation line
running from the stack inlet nozzle to the flue gas recirculation fan inlet.
Proper burner setup is essential for safe operation and optimum burner performance; the burner
was started up by an authorized service engineer.
Pre-Test Surveys
A thorough survey of the test site was performed prior to each test campaign. The
purpose of the surveys was to determine that the test equipment would fit in the test location, to
identify and gain access to the utilities needed to operate the dilution system and its ancillary
equipment, to arrange for installation of a sample collection port (installation for campaign #1 -
the same port was used for campaign #2), to arrange for installation of power for operation of the
dilution sampling system (installation for campaign #1 only) and to evaluate the means for
positioning the sampler at the desired location. The same sampling location and port were
utilized in both campaigns. A schematic diagram of the sampling port is shown in Figure 3-3; a
photograph of the port, as installed, with cap plate, is shown in Figure 3-4. The relationship of
the sampling port relative to the boiler and the exhaust ductwork is discussed in Section 4.
A new power panel and feeder to provide power to two quad outlets and a 50-amp, 2-pole
circuit, including a breaker in the existing main panel, was also installed prior to campaign #1.
ERG conducted pre-test site surveillance and site preparation to ensure readiness of the site for
25
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to
Front View
Port Center
54"
i
Floor Level
v
Side View
Port installed at mark
with center 5 4" above
floor.
Figure 3-4. Diagram of the sampling port.
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the start of the scheduled sampling activities. The pre-test survey considered access to utilities
and personnel, as well as legal and safety requirements. ERG obtained source data such as
exhaust gas flow rate and velocity, exhaust gas temperature and water vapor content, and
approximate particulate matter concentration, parameters useful for estimating appropriate
dilution ratios and duration of sample collection.
The sampling port was positioned to allow the dilution sampling unit to sit on a sturdy
hydraulic lift cart, which could be rolled into place and raised to allow the probe access to the
sampling port. The cart sat on the floor of the boiler room, with its wheels firmly anchored.
Access to the test facility was attained by a ground-level door that was sufficiently wide to
accommodate the dilution sampling unit. The two modules (dilution air supply/control module
and sampler module) were positioned at the sampling location, (Figure 3-5), by rolling the units
through the ground-level door at the test facility (Figure 3-6); testing occurred at ground level
inside the facility (Figure 3-7), with the dilution system elevated to allow access to the sampling
port.
27
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to
-------
to
Figure 3-6. Ground level access to the test facility.
-------
Figure 3-7. Testing area, ground level.
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Section 4
Experimental Procedures
To sample undiluted hot exhaust gas streams, the EPA/ECPB dilution sampling system
(schematic diagram in Figure 3-1), sample collection arrays, sample substrates, and a dilution air
cleaning system were used by ERG. To minimize introduction of contaminants, EPA pre-
cleaned and pre-assembled the dilution sampler and sample collection arrays in a clean
environment prior to transport to the test site. The sampler and dilution air cleaning system were
assembled on separate portable aluminum frames equipped with wheels and tie-down lugs for
transport to and from the site. ERG maintained the sampler and sample collection arrays in a
contaminant-free condition prior to collection of institutional oil-fired boiler samples and field
blanks.
A sampler blank test was run prior to transporting the sampler to the test site for each
campaign to ensure that the system had been cleaned properly and was leak free. The blank test
was run in the laboratory by completely assembling the sampling system, including the sample
collection arrays connected to the residence chamber and all instrumentation. The blank test was
conducted for a time period consistent with the expected duration of the source tests (10 hours).
Following the blank test, the sampler was shut down in reverse order from startup, and all
substrates were unloaded, preserved as appropriate, and analyzed to verify the absence of
contamination in the dilution sampling system.
Preparation for Test Setup
Prior to deployment of the dilution sampling system at the test site and initiation of
sampling with the dilution sampling system and associated sample collection arrays, EPA
Methods 1-45"8 were used to establish key experimental parameters for the test conditions.
Application of EPA Methods 1-4
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Traverse Point Determination Using EPA Method 1
EPA Method I5, "Sample and Velocity Traverses for Stationary Sources," was used to
establish the number and location of sampling traverse points necessary for isokinetic and flow
sampling. These parameters are based upon how much duct distance separates the sampling
ports from the closest downstream and upstream flow disturbances.
The selected sample collection location did not meet the minimum requirements of EPA
Method 1 for length of straight run or for orientation of the port with respect to the plane of
bends in the ductwork. However, this location was the only position on the duct work with
sufficient space for physical location of the sampling system. The duct work was rectangular.
The inside stack dimensions were length, 48 in.; width, 22 in. The port was located 3 ft.
downstream from the exit of the boiler breech area and 20 ft. upstream of the common exhaust
duct. Traverse point locations are shown in Table 4-1. A table of metric unit conversions is
shown in Appendix A. Sampling at the test site was performed at the point determined by
Method 1 to represent the average velocity in the oil-fired boiler exhaust stack (Figure 3-4).
The absolute pressure of the flue gas (in inches of mercury) was calculated according to
the following equation:
Pg
PS = Pbar + (4-1)
13.6
Where:
PS = absolute gas pressure, inches of mercury
Pbar = barometric pressure, inches of mercury
P = gauge pressure, inches of water (static pressure)
32
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Table 4-1. EPA Method 1—Traverse Point Location for Institutional Boiler Exhaust
(A Rectangular Duct)
Fraction of Inside Stack
Traverse Point
Number
1
2
3
4
5
6
7
8
9
10
Dimension Length
(%)
2.6
8.2
14.6
27.6
34.2
65.8
77.4
85.4
91.8
97.4
Inside Stack Wall
(in.)
1.250
3.875
7.000
13.250
16.375
31.500
37.250
41.000
44.125
46.750
from Outside Sampling Port3
(in.)
8.250
10.875
14.000
20.125
23.375
38.500
44.125
48.000
51.125
53.750
a The thickness of the stack wall plus the port flange was 7.0 in.
The value 13.6 represents the specific gravity of mercury (1 inch of mercury = 13.6 inches of
water). For the stack tested, the absolute gas pressure under these conditions was 29.68 inches
of mercury.
Volumetric Flow Rate Determination Using EPA Method 2
Volumetric flow rate was measured according to EPA Method 26, "Velocity — S-Type
Pitot". A Type K thermocouple and S-type pitot tube were used to measure flue gas temperature
and velocity, respectively. All of the isokinetically sampled methods that were used
incorporated EPA Method 2.
Pitot Tube Calibration
The EPA has specified guidelines concerning the construction and geometry of an
acceptable Type-S pitot tube. If the specified design and construction guidelines are met, a pitot
tube coefficient of 0.84 is used. Information pertaining to the design and construction of the
33
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Type-S pitottube is presented in detail in Section 3.1.1 ofQuality Assurance Handbookfor Air
Pollution Measurement Systems. Volume III. Stationary Source Specific Methods.9 Only
Type-S pitot tubes meeting the required EPA specifications were used. Pitot tubes were
inspected and documented as meeting EPA specifications prior to field sampling.
Calculation of Average Flue Gas Velocity
The average flue gas velocity for each traverse point is calculated using the following
equation:
Where:
V
APavg
460
Vs = KP * C
I APavg* (460 + Ts)
Ps * Ms
(4-2)
average flue gas velocity, ft/sec
Pitot constant (85.49)
Pitot coefficient (dimensionless), typically 0.84 for Type S
average flue gas velocity head, inches of water
zero degrees Fahrenheit expressed as degrees Rankine
flue gas temperature, degrees Fahrenheit
absolute stack pressure (barometric pressure at measurement site plus
stack static pressure), in. Hg
wet molecular weight, pounds per pound-mole
The flue gas velocity calculated for each traverse point and the average velocity are shown in
Table 4-2.
34
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Table 4-2. Campaign-Specific Flue Gas Velocity for Each Traverse Point
Traverse Point
(As Calculated in Table 4-1)
1
2
3
4
5
6
7
8
9
10
Average Velocity
Campaign #1
Velocity, ft/min
0.0
0.0
0.0
0.0
423.3
598.0
792.4
732.3
0.0
0.0
(4-point x) 636.51
Campaign #2
Velocity, ft/min
293.9
339.1
321.0
340.0
366.7
390.3
423.4
298.4
230.7
230.7
(10-point x) 323.42
For campaign #1, the point of average velocity has the closest relationship to traverse point #6.
For campaign #2, the point of average velocity has the closest relationship to traverse point #3.
Determination of Volumetric Flow Rate for Stack Gas
Because stack gas flow rate velocity could be measured at only four often traverse points
for the testing performed for campaign #1 (whereas stack flow could be measured at all ten
traverse points for campaign #2), stack volumetric flow rates could not be determined on the
same basis in both test campaigns. Stack gas flow rates were therefore calculated for both
campaigns on the basis of carbon content of fuel feed, as shown in Table 4-3. The values shown
in Table 4-3 for flue gas flow rate were used in subsequent calculations for emission factors.
35
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Table 4-3. Carbon-Based Calculation of Flue Gas Flow Rates
Volume occupied by 1 mole of gas at 273.16 K and 1 atm (29.92 " Hg) [Standard Temperature and Pressure]
PV = nRT V = nRT/P
V= [(1 mol) * (0.082056 L atmK'1 mol'1) * (273.16 K)]/l atm
Molar volume at 273 K, 1 atm
V= 22.4144 L/g-mol
1 ft3 = 28.317 L
Therefore, 22.4144 L/mol = 791.55 ft3/kg-mol, and corrected to the test conditions 849.66 ftYkg-mol.
Parameter
Fuel volumetric flow rate (gal/min)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Carbon in fuel (wt %)
Carbon feed rate (kg/min)
Carbon feed rate (kmol/min)
CO2 in flue gas (vol %, wet)
CO in flue gas (vol %, wet)
Ideal gas conversion (0 °C, 1 atm) (scf/kmol)
Gaseous carbon in flue gas (kmol/scf)
Organic carbon on quartz filter (|ig/cm2)
Elemental carbon on quartz filter (|ig/cm2)
Total carbon on filter" (|ig)
Dayl
3.43
3.19
10.9417
85.93
9.4022
0.7829
16.20
0.03
849.66
0.000191
0.31
0.59
12.105
Sampling Campaign #1
Day 2 Day 3
3.62
3.19
11.5478
85.93
9.9230
0.8623
15.67
0.03
849.66
0.000184
2.39
2.51
65.905
4.14
3.19
13.2066
85.93
11.3484
0.9449
15.47
0.03
849.66
0.000182
2.37
10.31
170.546
Dayl
2.32
3.19
7.4008
86.53
6.404
0.5337
10.70
0.03
849.66
0.000126
20.337
1.47
293.304
Sampling Campaign #2
Day 2 Day 3
2.33
3.19
7.4327
86.53
6.4315
0.5360
10.40
0.03
849.66
0.000123
20.267
0.66
281.468
2.33
3.19
7.4327
86.53
6.4315
0.5360
9.90
0.03
849.66
0.000123
66.04
1.47
908.010
-------
Table 4-3. (Continued)
Parameter
Sample flow (sLpm)
Test ran time (min)
PM concentration at filter (kmol/scf)
Dilution ratio
PM carbon in flue gas (kmol/scf)
Total carbon in flue gas (kmol/scf)
Flue gas flow rate by carbon content (scfm)
Flue gas flow rate by pilot (scfm)
Difference in flow measurements
Sampling Campaign #1 Sampling Campaign #2
Day 1 Day 2 Day 3 Day 1 Day 2 Day 3
8.255
600.33
5.785 x 10'11
46.81
2.695 x 10-9
0.000191
4065
4666
-1.3%
8.242
600.50
3.139X10'10
48.67
1.528 xlO'8
0.000184
4159
8.489 8.239 8.195 8.251
600.17 600.60 600.67 600.00
7.891 xlO'11 1.397 x 10'9 1.348 x 10'9 4.323 x 10'10
45.91 44.31 44.37 44.95
3.623 xlO'9 6.191 x 10'8 5.980 x 10'8 1.943 x 10'8
0.000182 0.000126 0.000123 0.000117
4827 3935 4066 4270
2371
39.7%
Tilter area on which paniculate matter was collected was 13.45 cm2.
-------
No structural changes to the ductwork were made between the two test campaigns. The
percent load at which the boiler was operated was different for the two campaigns. During the
campaign #2 tests, the fuel feed rate averaged 37.6% lower than the campaign #1 tests, and the
excess oxygen levels were much higher (campaign #2 = 15.7 to 20.5%; campaign #1 = 7.6 to
9.2% excess oxygen). During campaign #1, the boiler was fired at 37 - 42% of its rated
capacity; during campaign #2, the boiler was fired at only 25% capacity. The differences in load
resulted in different stack velocities for the two campaigns (see Section 4, Table 4-2). As the
point at which the sampling port used for these tests had to be installed (due to physical
constraints) was very close to the breech area exit of the boiler, the upstream and downstream
distances specified in EPA Method 1 could not be attained (see Section 3). Consequently, the
stack gas at the different velocities behaved differently in the duct work resulting in a different
flow profile. As the point of average velocity was determined using EPA Methods 1-4 for both
tests, representativeness and comparability are considered to be appropriate.
Nozzle Size Determination
It is desirable to sample at or near isokinetic velocities at the probe inlet nozzle. The
nozzle size is based on the required sample flow rate. Prior to using an Excel macro to perform
nozzle size calculations according to the procedures of EPA Method 58 (U.S. EPA, 1989d) the
velocity in the stack (feet per minute) must be determined from the pitot traverses prior to the
start of the test run. The additional input required by the macro is sampling rate in liters/minute.
At the average velocity calculated using the four-point average for campaign #1, the
recommended nozzle size was 0.552 in. At the average velocity calculated using the 10-point
average for campaign #2, the recommended nozzle size was 0.505 in.
Measurement of O2 and CO2 Concentrations
The O2 and CO2 concentrations were determined by use of a Fyrite bulb during the
traverse.
Stationary Gas Distribution (as Percent Volume)
38
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The following values were measured for the stationary gases:
Campaign #1 Campaign #2
Measured O2 vol % (wet) 6.0 8.1
Measured CO2 vol % (wet) 15.0 11.0
(Provided) CO vol % (wet) 0.03 0.03
The percentage of nitrogen (N2) was calculated according to the following equation:
N2 vol %= 100 - (O2 vol % + CO2 vol % + CO vol %)
= 100-(6.0 + 15.0 + 0.03)
= 78.97 (campaign #1) (4-3)
= 100-(8.1 +11.0 +0.03)
= 80.87 (campaign #2)
Dry Molecular Weight of Flue Gas
The dry molecular weight of the flue gas (Md) was calculated according to the following
equation:
Md = (CO2 vol % * 0.44) + (O2vol % * 0.32) + [(CO vol % + N2 vol %) * 0.28 ]
= (15.0*0.44)+ (6.0* 0.32)+[(0.03 + 78.97) * 0.28]
= 6.60+ 1.92+ 22.12 (4-4)
= 30.64 Ib/lb-mole (campaign #1)
= 30.08 Ib/lb-mole (campaign #2)
Where:
Md = molecular weight of flue gas, dry basis (Ib/lb-mole)
CO2 vol % = percent CO2 by volume, dry basis
39
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O2 vol %
CO vol %
N2 vol %
0.44
0.32
0.28
percent O2 by volume, dry basis
percent CO by volume, dry basis
percent N2 by volume, dry basis
molecular weight of CO2, divided by 100
molecular weight of O2, divided by 100
molecular weight of N2 or CO, divided by 100.
Wet Molecular Weight of Flue Gas
The wet molecular weight of the flue gas (Ms) was calculated according to the following
equation:
Ms = (Md * Mfd) + (0.18 * H2O vol %)
= 29.25 wet Ib/lb-mole (campaign #1) (4-5)
= 28.65 wet Ib/lb-mole (campaign #2)
Where:
Ms = wet molecular weight of flue gas, wet Ib/lb-mole
Md = molecular weight of flue gas, dry basis (Ib/lb-mole)
Mfd = dry mole fraction of effluent gas, calculated as [1 - H2O vol % /100]
0.18 = molecular weight of H2O, divided by 100
%H2O = percent H2O, by volume.
Determination of Average Moisture Using EPA Method 4
EPA Method 47, "Moisture Content", was used to determine the average moisture content
of the stack gas. A gas sample was extracted from the source, moisture was removed from the
sample stream, and the moisture content was determined gravimetrically. Before sampling, the
initial weight of the impingers was recorded. When sampling was completed, the final weights
of the impingers were recorded and the weight gain was calculated. The weight gain and the
volume of gas sampled were used to calculate the average moisture content (percent) of the stack
gas. The calculations were performed by computer. Method 4 was incorporated into the
techniques that were used for all of the manual sampling methods used during the test.
40
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The measurements shown in Table 4-4 were made on January 15, 2001, for campaign #1
and on July 7, 2002, for campaign #2, using Method 4 to determine moisture recovery.
Table 4-4. Moisture Recovery for Method 4
Measured on January 15, 2001, for Campaign #1
Impinger Impinger
Number Solution
1 Water
2 Water
3 Empty
4 Silica Gel
Impinger Impinger
Number Solution
1 Water
2 Water
3 Empty
4 Silica Gel
Impinger Impinger Tip Final Initial Weight
Contents (g) Configuration (g) (g) Gain (g)
100
100
0
300
Measured on
Weight of
Impinger
Contents (g
100
100
0
300
S&G 702.3 625.1
S&G 672.0 642.1
S&G 597.2 590.0
S&G 749.1 748.3
Total Weight Gain (g)
July 7, 2002, for Campaign #2
Impinger Weight
Impinger Tip Final Initial
) Configuration (g) (g)
S&G 674.5 607.6
S&G 609.0 575.9
S&G 492.7 484.8
S&G 732.3 720.3
Total Weight Gain (g)
77.2
29.9
7.2
3.8
118.1
Weight
Gain (g)
66.9
33.1
7.9
12.0
119.9
Volume of Dry Gas Sampled at Standard Conditions (dscf)
The volume of dry gas sampled under standard conditions was calculated using the
following equation:
V
v
m(std)
v * V
i v
P +
rbar t-
AH
13.6
(4-6)
41
-------
Where:
Vm(std) = volume of dry gas sampled at standard conditions, dry standard cubic feet
(dscf)
Y = dry gas meter calibration factor (0.98)
Vm = volume of gas metered, cubic feet, dry
Pbar = barometric pressure at measurement site, inches of mercury
AH = Sampling rate, measured as differential pressure at the meter orifice, inches
of water
Tm = dry gas meter temperature, degrees Fahrenheit
The constant 17.64 was used for conversion to standard conditions (68°F + 460°R)/29.92 in. Hg;
460 is zero degrees Fahrenheit in degrees Rankine. Using measured values from the field data
sheet, the volume of dry gas sampled at standard conditions (Vm(std)) was calculated to be 43.011
dscf for campaign #1, 42.034 dscf for campaign #2.
Volume of Water Vapor at Standard Conditions (dscf)
The volume of water vapor under standard conditions was calculated using the following
equation:
Vw(std) = 0.04707 * Vlc (4-7)
Where:
Vw(std) = volume of water vapor at standard conditions, dry standard cubic feet (dscf)
Vlc = volume of liquid catch, grams
The constant 0.04707 is the standard cubic feet per gram (or milliliter) of water at standard
conditions. Using the total weight gain for water determined using Method 4 (Table 4-4 above),
the volume of water vapor at standard conditions is calculated to be 5.559 scf for campaign #1,
5.644 scf for campaign #2.
42
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Calculation of Moisture/Water Content (as % Volume)
The moisture content of the gaseous stack emissions is calculated using the following
equation:
H2Ovol%= 100 * - — - (4-8)
Vw(std) + vm(std)
Using values measured using EPA Method 4 and values calculated previously, the moisture
content was calculated to be 10.993 percent volume for campaign #1 and 1 1.838 percent volume
for campaign #2.
Calculation of Dry Mole Fraction of Flue Gas
The dry mole fraction of flue gas is calculated using the following equation:
H2Ovol%
M - 1 -
M" !
fd
100
Where:
Mfd = dry mole fraction of effluent gas.
Using the percent moisture determined above, the dry mole fraction of effluent gas is calculated
as 0.8901 for campaign #1 and 0.8816 for campaign #2.
43
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Setup of the Dilution Sampling System
The site location was a boiler room at the NC A&T facility, with the 6-inch flanged
sampling port installed in the exhaust duct work to allow the dilution sampling unit to sit on a
sturdy hydraulic lift cart, which could be rolled into place and raised to allow the probe of the
dilution sampling system (Figure 3-2) access to the sampling port. The dilution system control
module, the sampling module, and all ancillary equipment were delivered to the test site by truck.
The two modules (dilution air supply/control module and sampling module) were positioned at
the sampling location by rolling the units through a ground-level door, then elevating the
sampling module to the appropriate height for access to the sampling port using the sturdy
hydraulic lift to raise and lower the sampling assembly. A power panel and feeder to provide
power to two quad outlets and a 50-amp, 2-pole circuit, including a breaker in the existing main
panel, had also been installed by the facility prior to campaign #1.
The location provided convenient access to the stack and sampling port, as shown in
Figure 3-4, and sufficient space for the equipment and personnel for both testing campaigns. The
dilution air system module positioned at the sampling location in the boiler room is shown during
testing operations in Figure 4-1. Figure 4-2 shows the sampling probe installed in the 6-in. ID.
flanged port used for sampling. The dilution air supply/control module (Figure 4-3) was located
in the boiler room, approximately 12 feet from the sampling module and around the corner of the
boiler. A TSI SMPS (Figure 4-4), with associated laptop computer, was also connected to the
sampling module (visible behind the TSI display in Figure 4-4), together with the sample
collection arrays for campaign #1. An Electrical Low Pressure Impactor (ELPI) (Figure 4-5),
with an associated laptop computer, was connected to the sampling module together with the
sample collection arrays for campaign #2. The dilution system sampling module, together with
other sample collection arrays and instruments attached, is shown in Figure 4-6 for campaign #1.
The dilution system sampling module, together with other sample collection arrays and
instruments attached, is shown in Figure 4-7 for campaign #2.
44
-------
I
Figure 4-1. Dilution sampling system elevated on mobile lift for access to the sampling port.
-------
Figure 4-2. Dilution system sampling probe installed in 6 in. I.D. flanged port.
-------
Figure 4-3. Dilution system control module positioned at the sampling location.
-------
oo
Figure 4-4. TSI particle sizer positioned at the sampling location (January 16, 2001) for Campaign #1.
-------
VO
Figure 4-5. ELPI particle sizer positioned at the sampling location (July 7, 2002) for Campaign #2.
-------
Figure 4-6. Dilution system with all sample collection arrays and instruments attached for Campaign #1.
-------
Figure 4-7. Dilution system sampling module, together with sample collection arrays, for Campaign #2.
-------
Figures 4-8 and 4-9 present the recovery area used during both testing campaigns.
Figure 4-9 shows the analyst recovering a PUF sampling module. Figure 4-10 shows the removal
of a filter from a sample collection array prior to packaging for transport to the laboratory.
Pre-Test Leak Check
To perform a pre-test leak check on the assembled dilution system in the field, the inlet
end of the probe was plugged with a Swagelok fitting. Solvent-cleaned solid plates were inserted
in place of the orifice plates at the orifice meter run flanges and sealed off using gaskets on each
side. A new preweighed quartz 8-in. x 10-in. filter was inserted into the filter holder and
carefully sealed in place using screw fittings. A vacuum pump was attached to the residence
chamber and a Magnehelic gauge was attached to an available port. The valve between the pump
and the chamber was opened and the vacuum was monitored as the system was evacuated. As the
reading passed 27 in., the valve between the pump and the chamber was closed. The leak rate
was timed between 25 to 20 in. H2O and again from 20 to 15 in. H2O, and the two times were
averaged. Using the recorded data, the leakage rate in cubic feet/minute was calculated according
to Equation 4-10.
AP
leakage rate = ~~ x V x CF
L\ -L
(4-10)
Where:
leakage rate
AP
AT
V
CF
rate of leakage (ft3/min)
change in pressure (in. H2O)
time increment (sec)
volume of the evacuated dilution sampler (15.3 ft3)
unit conversion factors
- 60 sec/min
1 atm/406.8 in. H,O
52
-------
Figure 4-8. Sample recovery area.
-------
Figure 4-9. Sample recovery area.
-------
Figure 4-10. Teflon filter being removed from the holder in preparation for packaging for transport to the
laboratory.
-------
The criteria for an acceptable leak are <0.1 cfm, or > 1 min 53 sec, equivalent to a pressure
increase of 5 in. H2O. For campaign #1, an average time of 1 min 58 sec was required for a 5-in.
pressure change to occur (resulting leak rate: 0.100 cfm). For campaign #2, an average time of
1 min 59 sec was required for a 5-in. pressure change to occur (resulting leak rate: 0.095 cfm).
These leak rates both met the acceptance criteria.
Orifice Flow Check
Critical orifice flows on the sampling pumps were checked without sample collection
arrays in place using a rotameter to verify that the channels on sample collection array pumps
were at the specified flow rate of 16.7 L/min. Rotameters were calibrated with an NIST-traceable
electronic bubble flow meter.
Determination of Test Duration
To maximize the collection of particulate material, the decision was made to extend the
run time for the longest duration (-10 hours) allowed by the facility.
Canister/Veriflow Blanks
Canisters and Veriflows were utilized only for campaign #1. Prior to deployment in the
field, SUMMA-polished canisters and Veriflow canister filling units were cleaned, and blank
analysis was performed in the laboratory. All units met the cleanliness criterion of < 10 parts per
billion carbon (ppbC, Table 4-5).
56
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Table 4-5. Blank Values for Veriflows and Canisters (Campaign #1)
Unit Blank Value, ppbC
Veriflows
Unit #4 18 (Source)
Unit #3 15 (Dilution Air)
ERG-3 (Ambient)
Canisters
3950
3953
4031
4040
3965
1404
4028
4039
4024
5000
0.0
0.0
0.7
1.1
4.4
1.4
1.03
1.0
1.0
0.0
0.0
1.5
3.7
Determination of Flow Rates
A Visual Basic macro was written to process raw data files of flow rate information and
convert this information to actual flow based on temperature, pressure, and calibration data. For
venturi flows, the macro converted the differential pressure into a reported flow rate. The square
root of the differential pressure was then multiplied by a previously determined calibration factor
based on the flowing temperature, and the resulting value was converted to standard liters per
minute (sLpm) using ideal gas law relationships (1 atm, 70°F).
Calibration data for the venturi were generated by placing a dry gas meter at the inlet to
the sample probe. The flows reported by the data acquisition system were corrected to actual
conditions (aLpm) and compared to those produced by the dry gas meter corrected to the venturi
conditions. An Excel macro automatically selected a correct calibration value to be applied based
on the flowing temperature.
57
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Since the actual venturi flow was dependent upon the operating conditions, the setpoint
value displayed and entered on the viewing screens needed to be adjusted to achieve the desired
flow. Information to be entered included desired flow, flowing temperature, flowing pressure,
and barometric pressure; the Excel macro automatically selected the correct value to be applied
based on the flowing temperature.
Sample Collection Arrays: Campaign #1
Prior to actual testing (Test Run #1, January 16, 2001; Test Run #2, January 17, 2001;
Test Run #3, January 18, 2001), sample collection arrays were attached to various ports on the
dilution sampling system, as shown in Figure 4-11. Up to ten sampling ports were available,
attached to either the dilution chamber (designated Ports #D1, #D2, and #D3) or the residence
chamber (designated Ports #R2, #R3, #R4, #R5, #R6, #R8, and #R10); the available sampling
ports are shown in Figure 3-1. The following sample collection arrays were used on all three test
days for campaign #1; the sample collection arrays with two denuders in series were used only on
the first test day (Figure 4-11 A):
• Dilution Chamber Sample Collection for Campaign #1
— Dilution Chamber Collection Array Dl
Collection array Dl collects gas phase semivolatile organic compounds,
particle-bound organic materials, and metals. The array consists of a
cyclone separator to remove particulate matter with aerodynamic diameter
greater than 2.5 |im. The gas stream is split into two legs. Leg 1 contains a
quartz filter followed by two PUF units in series. The other leg of
array Dl consists of a Teflon filter.
- Dilution Chamber Array D2
Collection array D2 collects gas-phase carbonyl compounds using a pair of
carbonyl collection cartridges in series in a pump.
- Dilution Chamber Array D3
Collection array D3 collects fine particulate matter and gas-phase organic
compounds. This array consists of a single filter unit followed by a
SUMMA canister.
58
-------
Dilution chamber
Port#D1 Port#D2
Port #D3
SUMMA
I Canister
Total Sample
Substrates
QF
TF-0.5
TF
PUF
Denuder* 6
2
4
7
2
5
14
SUMMA
DNPH
*Denuders collected
one test day only.
Residence chamber
Port #R2 Port #R3
Cyclone
Port #R4
SUMMA
I Canister
Total Field Blank
Substrates
QF
TF
PUF
DNPH
1
1
1
1
Port #R5
Port #R6
Port #R8
Port#R10
Cyclone
Figure 4-11. Schematic diagram of sample collection arrays used in field test
(January 16-18, 2001) for Campaign #1.
59
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Dilution chamber
Port #1 Port #2
Port #3
Residence chamber
Port #2 Port # 3
Cyclone
SUMMA
I Canister
Port #4
SUMMA
I Canister
Total Sample
Substrates
QF 7
TF-0.5 2
TF 5
PUF 14
Denuder* 6
SUMMA 2
DNPH 4
*Denuders collected
one test day only.
Total Field Blank
Substrates
QF
TF
PUF
DNPH
1
1
1
1
Port #5
Cyclone
Port #6
Port #8
Port #10
Cyclone
Figure 4-11 A. Schematic diagram of sample collection arrays used in field test
(January 16-18, 2001) for Campaign #1, showing denuders used on only one test day.
60
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Residence Chamber Collection Arrays for Campaign #1
- Residence Chamber Collection Array R2
Collection array R2 collects fine particulate matter. The array consists of a
2.5-|im cyclone followed by two identical legs containing Teflon filters.
- Residence Chamber Collection Array R3
Collection array R3 collects fine particulate matter and gas-phase carbonyl
compounds. This array consists of a pair of carbonyl collection cartridges
in series and a pump.
- Residence Chamber Collection Array R4
Collection array R4 collects fine particulate matter and gas-phase organic
compounds. This array consists of a single filter unit followed by a
SUMMA canister.
- Residence Chamber Collection Array R5
Collection array R5 collects fine particulates. The array consists of a
2.5-|im cyclone followed by two identical legs containing Teflon filters.
- Residence Chamber Collection Arrays R6, R8, and RIO
Collection arrays R6, R8, and RIO collect fine particulate matter on quartz
filters for total carbon and elemental carbon analysis. These sampling
arrays consist of a 2.5-|im cyclone followed by two identical legs each
containing a quartz filer followed by two PUF plugs in series. On one test
day, two XAD-4-coated denuders in series will be used with each array to
collect semivolatile organic compounds.
In addition to the sample collection arrays, a TSI continuous particle size analyzer was
used on the residence chamber. The scanning mobility particle sizer (SMPS) includes a TSI
Model 3081 Electrostatic Classifier in tandem with a TSI Model 3025A Ultrafine Condensation
Particle Counter. This device scanned the range of 9-421 nanometers (nm) in a scan cycle of
approximately 3 minutes, with data collected continuously onto a laptop computer with real-time
data display and saving. The SMPS was connected to the residence chamber at port #R7 to
continuously monitor particle size distribution.
61
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Sample Collection Arrays: Campaign #2
Prior to actual testing (Test Run #1, July 9, 2002; Test Run #2, July 10, 2002; and Test
Run #3, July 11, 2002), sample collection arrays were attached to various ports on the dilution
sampling system, as shown in Figure 4-12. Up to ten sampling ports were available, attached to
either the dilution chamber (designated port #D1) or the residence chamber (designated ports
#R2, 3, 4, 5, 6, 8, and 10); the available sampling ports are shown in Figure 4-12, the schematic
diagram of the dilution sampling system. The following sample collection arrays were used on all
three test days for campaign #2:
• Dilution Chamber Sample Collection for Campaign #2
Dilution Chamber Collection Array Dl
Collection array Dl collects gas phase semivolatile organic compounds,
particle-bound organic materials (both organic and inorganic). The array
consists of a cyclone separator to remove particulate matter with
aerodynamic diameter greater than 2.5 |im. The gas stream is split into two
legs. Leg one contains a quartz filter followed by two PUF units in series.
The other leg of array Dl consists of a Teflon filter.
• Residence Chamber Collection Arrays for Campaign #2
Residence Chamber Collection Arrays R6, R8 and RIO
Collection arrays R6, R8 and RIO collects fine particulate matter and
semivolatile organic compounds for analysis of elemental carbon/organic
carbon (EC/OC) and speciated organic compounds. The array consists of a
2.5-|im cyclone followed by two identical legs containing quartz filters and
four PUF plugs in series (two PUF modules containing two PUF plugs each
on each leg).
62
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Sampling Arrays - Oil Boiler Tests (HC A&T. 62002)
Dilution chamber
Port#D1
I
rn PUF
n
El " [=5 ^
"j c-xcfcr*
V
Total Sample
Substrates
QF 11
TF 5
PUF 26
Residence chamber
Port#R6 Port#R10 Port#R8
Port#R2
V
Port#R4
B8F
H11
V
Figure 4-12. Schematic diagram of sample collection arrays used in field test (July 9-11,
2002) for Campaign #2.
63
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Residence Chamber Collection Arrays R2 andR4
Collection arrays R2 and R4 collected PM-2.5 on Teflon filters for
determination of mass, elements and inorganic ions. The Teflon filters are
followed by quartz filters to determine any semivolatile organic
compounds stripped from the Teflon filters during sampling.
In addition to the sample collection arrays, an ELPI was connected to the residence
chamber at port R3 to continuously monitor particle size distribution.
Measurement of 02 and C02 Process Concentrations
For campaign #1, measurements of O2 were made using the certified facility O2 analyzer
every 15 min for the duration of each test day to determine average O2 concentrations during test
conditions. For campaign #2, measurement of O2 and CO2 were made using Fyritebulbs every 30
min across the duration of the tests to determine average O2 and CO2 concentrations during
testing.
Operation of the Dilution Sampling System and Sample Collection Arrays
To prepare the dilution sampling system for a full test run, sampling probe temperature
setpoints were set equal to or slightly above the measured stack temperature. The system was
equilibrated at temperature. Sample collection arrays were loaded with appropriate media, and
flow/leak checks were performed with each sample collection array to ensure that the entire
system would be leak-free in operation. Sampler flows were set just before initiation of the test to
prevent heat loss from the heated probe. The blower and the ring compressor were started to
achieve a slightly positive pressure, then the blower flow was adjusted to cause the stack gas to
flow into the dilution sampling system after the probe was inserted in the stack. Sample
collection array pumps were started, and for campaign #1 valves for the SUMMA canisters were
opened to initiate canister air sample collection. The sampling process was carefully monitored
by the sampling team based on pressure change in the canister to ensure that filters were not
overloaded in the course of sampling. Start time and other pertinent data were recorded. At the
end of the predetermined sampling interval, the sampling process was stopped by stopping the
64
-------
pumps for the sample collection arrays and closing the valves on the SUMMA canisters. The
probe was withdrawn from the stack, the blower and ring compressor were turned off, and heaters
were turned off and allowed to cool. Each sampling array was leak-checked at the end of the
sampling period, and ending flow rates were documented. Experimental parameters for tests #1,
#2, and #3 of campaign #1 are shown in Tables 4-6 through 4-8; blower flow, dilution flow, and
venturi flow for tests #1, #2, and #3 of campaign #1 are shown graphically in Figures 4-13
through 4-21. Experimental parameters for tests #1, #2, and #3 of campaign #2 are shown in
Tables 4-9 through 4-11; blower flow, dilution flow, and venturi flow for tests #1, #2, and #3 of
campaign #2 are shown graphically in Figures 4-22 through 4-30.
At the end of the sampling period, the pumps on the dilution system were turned off, and
recovery of the dilution sampling system consisted of removing the sample collection arrays and
turning off the particle size analyzer. Sample collection arrays were then carried to the recovery
area and disassembled, the parts were carefully labeled, and the components were carefully
packaged for transport to the laboratories.
The sample collection arrays were removed sequentially at the cyclone connection. Each
individual collection array was removed and the ends of the assembly were covered with
aluminum foil. As each sample collection array was removed from the sampling system, the
sampling aperture was covered to avoid introduction of any contaminants into the dilution
sampler. The ends of the sample collection array were capped and the array placed in a secure
container for transport to the sample recovery area.
65
-------
Table 4-6. Run Time Summary Information, Test Run #1, Campaign #1
Test Run #1 (January 16,2001)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
Sample Flow Rates
Actual Flow
aLpm
17.22
17.07
16.92
16.62
17.22
9:25:09 a.m.
7:25:29 p.m.
600.33 min
29.68 in. Hg
0.390
Average
30.47 aLpm
18.53 sLpm
-0.92 in. WC
205.53 °C
876.58 aLpm
847.89 sLpm
-1.37 in. WC
25.23 °C
918.41 aLpm
839.02 sLpm
-17.59 in. WC
28.20 °C
46.81
189.98 °C
198.11 °C
198.14°C
Corrected Flow
sLpm Notes
16.96 PM 2.5 sample on dilution air: start
16.81 PM 2 . 5 sample on dilution air: end
PM 2.5 sample on residence chamber port
16.66 10: start
PM 2.5 sample on residence chamber port
16.36 10: end
PM 2.5 sample on residence chamber port
16.96 8: start
Average Flow
sLpm
16.88
16.51
16.96
66
-------
Table 4-6. (Continued)
Sample Flow Rates
Actual Flow
aLpm
17.22
16.92
16.62
17.22
17.22
17.22
17.22
0.90
1.05
1.47
1.47
Canisters
#4024, Dilution
#4039, Source
#5000, Ambient"
#1404, Blank
Corrected Flow
sLpm
16.96
16.66
16.36
16.96
16.96
16.96
16.96
0.89
1.03
1.45
1.45
Start Pressure
29.0 in. Hg
29.0 in. Hg
29.0 in. Hg
29.0 in. Hg
Notes
PM 2. 5 sample on residence chamber port 8:
end
PM 2.5 sample on residence chamber port
6: start
PM 2.5 sample on residence chamber port
6: end
PM 2.5 sample on residence chamber port
4: start
PM 2.5 sample on residence chamber port
4: end
PM 2.5 sample on residence chamber port
2: start
PM 2.5 sample on residence chamber port
2: end
DNPH sample on residence chamber port 3 :
start
DNPH sample on residence chamber port 3 :
end
DNPH sample on dilution air port
3: start
DNPH sample on dilution air port
3: end
End Pressure
5.0 in. Hg
8.0 in. Hg
0.0 in. Hg
29.0 in. Hg
Average Flow
sLpm
16.51
16.96
16.96
0.96
1.45
a The ambient sample was collected on the first test day of campaign # 1 at the inlet of the charcoal scrubber
subsystem of the EPA Dilution Sampling System. The data from the analysis of the ambient canister sample were
reported but no correction of the monitoring data for ambient levels was performed. The ambient information was
supplied to provide an indicator of the performance of the dilution sampling system scrubber efficiency in
removing the ambient background from the air used for sample dilution at the test site.
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
67
-------
Table 4-7. Run Time Summary Information, Test Run #2, Campaign #1
Test Run #2 (January 17,2001)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
Sample Flow Rates
Actual Flow
aLpm
17.40
17.25
7:50:00 a.m.
5:50:30 p.m.
600.50 min
29.83 in. Hg
0.390 in.
Average
29.37 aLpm
17.88 sLpm
-0.96 in. WC
207.51 °C
870.64 aLpm
848.35 sLpm
-1.34 in. WC
24.57 °C
877.00 aLpm
833.41 sLpm
-13.30 in. WC
27.67 °C
48.67
194.54 °C
207.63 °C
209.57 °C
Corrected Flow Average Flow
sLpm Notes sLpm
17.39 PM 2.5 sample on dilution air: start 17.3 1
17.24 PM 2.5 sample on dilution air: end
16.49
16.49
17.10
PM 2.5 sample on residence chamber port
16.48 10: start
PM 2.5 sample on residence chamber port
16.48 10: end
PM 2.5 sample on residence chamber port
17.08 8: start
16.48
17.08
68
-------
Table 4-7. (Continued)
Sample Flow Rates
Actual Flow
aLpm
17.10
16.49
16.49
17.10
17.10
17.25
17.10
0.99
0.93
0.93
0.93
Canisters
#4031, Dilution
#4040, Source
Corrected Flow
sLpm
17.08
16.48
16.48
17.08
17.08
17.24
17.08
0.99
0.93
0.93
0.93
Start Pressure
29.0 in. Hg
29.0 in. Hg
Notes
PM 2.5 sample on residence chamber port
8:end
PM 2.5 sample on residence chamber port
6: start
PM 2.5 sample on residence chamber port
6: end
PM 2.5 sample on residence chamber port
4: start
PM 2.5 sample on residence chamber port
4: end
PM 2.5 sample on residence chamber port
2: start
PM 2.5 sample on residence chamber port
2: end
DNPH sample on residence chamber port 3 :
start
DNPH sample on residence chamber port 3 :
end
DNPH sample on dilution air port
3: start
DNPH sample on dilution air port
3: end
End Pressure
5.0 in. Hg
4.0 in. Hg
Average Flow
sLpm
16.48
17.08
17.16
0.96
0.93
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
69
-------
Table 4-8. Run Time Summary Information, Test Run #3, Campaign #1
Test Run #3 (January 18,2001)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
Sample Flow Rates
Actual Flow
aLpm
17.36
17.36
16.60
16.60
17.20
7:35:06 a.m.
5:35:16 p.m.
600.17min
29.74 in. Hg
0.390 in.
Average
3 1.26 aLpm
19.02 sLpm
-0.99 in. WC
206.60 °C
875.34 aLpm
850.66 sLpm
-1.39 in. WC
24.44 °C
885.81 aLpm
836.70 sLpm
-14.68 in. WC
27.44 °C
45.91
196.98 °C
203.77 °C
206.10°C
Corrected Flow
sLpm Notes
17. 13 PM 2.5 sample on dilution air: start
17. 13 PM 2.5 sample on dilution air: end
PM 2.5 sample on residence chamber port
16.38 10: start
PM 2.5 sample on residence chamber port
16.38 10: end
PM 2.5 sample on residence chamber port
16.98 8: start
Average Flow
sLpm
17.13
16.38
16.98
17.20
16.98
PM 2.5 sample on residence chamber port
6: start
16.98
70
-------
Table 4-8. (Continued)
Actual Flow
aLpm
17.20
17.20
17.20
17.20
17.20
1.14
1.14
1.18
1.18
Canisters
#3953, Dilution
#3950, Source
Corrected Flow
sLpm
16.98
16.98
16.98
16.98
16.98
1.12
1.12
1.17
1.17
Start Pressure
29.0 in. Hg
29.0 in. Hg
Notes
PM 2.5 sample on residence chamber port
6: end
PM 2.5 sample on residence chamber port
4: start
PM 2.5 sample on residence chamber port
4: end
PM 2.5 sample on residence chamber port
2: start
PM 2.5 sample on residence chamber port
2: end
DNPH sample on residence chamber port
3: start
DNPH sample on residence chamber port 3 :
end
DNPH sample on dilution air port
3: start
DNPH sample on dilution air port
3: end
End Pressure
5.0 in. Hg
3.0 in. Hg
Average Flow
sLpm
16.98
16.98
1.12
1.17
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
71
-------
BlowerFlow 1/16/01
5500 .
3500 -
7:OC
-SflO _
|
:
SB
:QO 8:00:00 9:00:00
I
+. ALHM
H SLPM
|
10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:00:00 19:00:00
b— ,
20:00:00 21:0
Time
Figure 4-13. Blower flow, Test 1—Day 1, January 16, 2001, Campaign #1.
Dilution Flow 1/16/01
I0 10:00:00 I 1 CIO ::iu liijocici i;i:ii:i:iij I4i:n:ii:in 15 on Lid 1t. iMjijij 17 00 DO 1.:: OLI iy:i lji:i:iu.:i ^u no CIO 21:00:00
oci ";i
Figure 4-14. Dilution flow, Test 1—Day 1, January 16, 2001, Campaign #1.
72
-------
VenturiFlow
- Liu Ci-J rt.uo Ijui •- I.IL, LIU IL.'.LUL lluiliivi
19:00:00 20:00:00 21:00:00
Figure 4-15. Venturi flow, Test 1—Day 1, January 16, 2001, Campaign #1.
B lower Flow 1/17/01
Figure 4-16. Blower flow, Test 2—Day 2, January 17, 2001, Campaign #1.
73
-------
Dilution Flow 1,1701
Figure 4-17. Dilution flow, Test 2—Day 2, January 17, 2001 Campaign #1.
venturlFlon 1/17(01
Figure 4-18. Venturi flow, Test 2—Day 2, January 17, 2001, Campaign #1.
74
-------
B lowerF low 1/18/01
Figure 4-19. Blower flow, Test 3—Day 3, January 18, 2001, Campaign #1.
Dilution Flow 1'18'01
Figure 4-20. Dilution flow, Test 3—Day 3, January 18, 2001, Campaign #1.
75
-------
VenturiFlow 1.18/01
Tim.
Figure 4-21. Venturi flow, Test 3—Day 3, January 18, 2001, Campaign #1.
76
-------
Table 4-9. Run Time Summary Information, Test Run #1, Campaign #2
Test Run #1 (July 9,2002)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
Actual Corrected
Flow Flow
sLpm aLpm
16.43 17.78
16.43 17.78
16.43 17.78
16.43 17.78
16.58 17.93
16.58 17.93
16.43 17.78
16.43 17.78
8:01:08 a.m.
6:01:44 p.m.
600.60 min
28.79 inches Hg
0.505 inches
Average
30.03 aLpm
18.85 sLpm
-0.77 inches WC
176.89 °C
908.65 aLpm
816.28 sLpm
- 1.42 inches WC
38.82 °C
789. 12 aLpm
680.59 sLpm
-16.54 inches WC
41.37 °C
44.33
171.45 °C
176.73 °C
176.48 °C
Notes
PM 2.5 sample on dilution air-start
PM 2.5 sample on dilution air-end
PM 2.5 sample on residence chamber port 10-start
PM 2.5 sample on residence chamber port 10-end
PM 2.5 sample on residence chamber port 8-start
PM 2.5 sample on residence chamber port 8-end
PM 2.5 sample on residence chamber port 6-start
PM 2.5 sample on residence chamber port 6-end
Average
Flow
sLpm
16.43
16.43
16.58
16.43
77
-------
Table 4-9. (Continued)
Actual
Flow
sLpm
8.91
9.16
16.29
16.14
16.58
16.43
Corrected
Flow
aLpm
9.64
9.91
17.62
17.46
17.93
17.78
Notes
PM 2.5 sample on residence chamber port 5-start
PM 2.5 sample on residence chamber port 5-end
PM 2.5 sample on residence chamber port 4-start
PM 2.5 sample on residence chamber port 4-end
PM 2.5 sample on residence chamber port 2-start
PM 2.5 sample on residence chamber port 2-end
Average
Flow
sLpm
9.04
16.22
16.51
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
78
-------
Table 4-10. Run Time Summary Information, Test Run #2, Campaign #2
Test Run #2 (July 10,2002)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
Sample Flow Rates
Actual Corrected
Flow Flow
sLpm aLpm
16.51 18.00
16.37 17.85
16.37 17.85
16.37 17.85
16.37 17.85
16.37 17.85
7:06:05 a.m.
5:06:45 p.m.
600.67 min
28.67 inches Hg
0.505 inches
Average
30.00 aLpm
18.79 sLpm
-0.80 inches WC
176.03 °C
91 1.02 aLpm
814.43 sLpm
- 1.42 inches WC
39.00 °C
783.42 aLpm
673.14 sLpm
-16.32 inches WC
41.45 °C
44.37
171.71 °C
177.13°C
176.68 °C
Notes
PM 2.5 sample on dilution air-start
PM 2.5 sample on dilution air-end
PM 2.5 sample on residence chamber port 10-start
PM 2.5 sample on residence chamber port 10-end
PM 2.5 sample on residence chamber port 8-start
PM 2.5 sample on residence chamber port 8-end
Average
Flow
sLpm
16.44
16.37
16.37
79
-------
Table 4-10. (Continued)
Sample Flow Rates
Actual
Flow
sLpm
16.37
9.12
9.25
16.22
16.08
16.37
16.37
Corrected
Flow
aLpm
17.85
9.95
10.08
17.69
17.53
17.85
17.85
Notes
PM 2.5 sample on residence chamber port 6-end
PM 2.5 sample on residence chamber port 5-start
PM 2.5 sample on residence chamber port 5-end
PM 2.5 sample on residence chamber port 4-start
PM 2.5 sample on residence chamber port 4-end
PM 2.5 sample on residence chamber port 2-start
PM 2.5 sample on residence chamber port 2-end
Average
Flow
sLpm
9.19
16.15
16.37
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
80
-------
Table 4-11. Run Time Summary Information, Test Run #3, Campaign #2
Test Run #3 (July 11,2002)
Start Time
End Time
Run Time
Barometric Pressure
Nozzle Size
Parameter
7:17:03a.m
5:17:03 p.m.
600.00 min
28.64 inches Hg
0.505 inches
Average
Venturi Flow
PT-101
TE-104
Dilution Flow
PT-102
TE-108
Blower Flow
PT-103
TE-105
Dilution Ratio
TE-101
TE-102
TE-103
30.02 aLpm
18.78 sLpm
-0.98 inches WC
176.12°C
900.09 aLpm
824.70 sLpm
-1.45 inches WC
31.22°C
774.50 aLpm
681.74 sLpm
-16.20 inches WC
33.61 °C
44.95
169.72 °C
177.18°C
176.86 °C
81
-------
Table 4-11. (Continued)
Sample Flow Rates
Actual
Flow
sLpm
16.41
16.41
16.55
16.41
16.55
16.41
16.70
16.41
9.27
9.02
16.12
16.12
16.55
16.55
Corrected
Flow
aLpm
17.80
17.80
17.96
17.80
17.96
17.80
18.11
17.80
10.06
9.79
17.49
17.49
17.96
17.96
Notes
PM 2.5 sample on dilution air-start
PM 2.5 sample on dilution air-end
PM 2.5 sample on residence chamber port 10-start
PM 2.5 sample on residence chamber port 10-End
PM 2.5 sample on residence chamber port 8-start
PM 2.5 sample on residence chamber port 8-end
PM 2.5 sample on residence chamber port 6-start
PM 2.5 sample on residence chamber port 6-end
PM 2.5 sample on residence chamber port 5-start
PM 2.5 sample on residence chamber port 5-end
PM 2.5 sample on residence chamber port 4-start
PM 2.5 sample on residence chamber port 4-end
PM 2.5 sample on residence chamber port 2-start
PM 2.5 sample on residence chamber port 2-end
Average
Flow
sLpm
16.41
16.48
16.48
16.56
9.15
16.12
16.55
PT = pressure transducer
TE = thermocouple
aLpm = actual liters per minute
sLpm = standard liters per minute
WC = water column
82
-------
Blower Flow 7/9/2002
10X1
CL 600
-200
1:00 7:00:00 8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:00:00 19:C3:00
Time
Figure 4-22. Blower flow, Test 1-Day 1, July 9, 2002, Campaign #2.
Dilution Flow 7/9/2002
1400
1200
1000
800
E 600
400
200
:00 9:00:00 10:00:0 11:00:0 12:00:0 13:00:0 14:00:0 15:00:0 16:00:0 17:00:0 18:03:0 19:10:0
0000000001
Time
Figure 4-23. Dilution flow, Test 1-Day 1, July 9, 2002, Campaign #2.
83
-------
Venturi Flow 7/9/2002
eOQOO 7:00:00 8:0000 9:00:00 10:00:0011:00:001200:0013:000014:00:0015:00:0016:00:0017:00:0018:00:0019:00:00
Time
Figure 4-24. Venturi flow, Test 1-Day 1, July 9, 2002, Campaign #2.
Blower Flow 7/10/2002
ea
m
•
,
:
r
?
):00 7:00:00 8:00:00 900:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:0
100
Figure 4-25. Blower flow, Test 2-Day 2, July 10, 2002, Campaign #2.
84
-------
Dilution Flow 7/10/2002
8UU-
6:OC
-9nn -
T
c
I"
I
1: 00 f
I
I
I
I
I
I
58:00 8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:OCTOO 18:0
3:00
Time
Figure 4-26. Dilution flow, Test 2-Day 2, July 10, 2002, Campaign #2.
Venturi Flow 7/10/2002
20
6:00:00 7:00:00 8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:00:00
Time
Figure 4-27. Venturi flow, Test 2-Day 2, July 10, 2002, Campaign #2.
85
-------
Blower Flow 7/11/2002
600
400
200
7:OC
_onn
i
i
):00 8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:0
0:00
Time
Figure 4-28. Blower flow, Test 3-Day 3, July 11, 2002, Campaign #2.
Dilution Flow 7/11/2002
800 -
7:OC
-9nn -
i
m
8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:(J
F 18:0
0:00
Figure 4-29. Dilution flow, Test 3-Day 3, July 11, 2002, Campaign #2.
86
-------
Venturi Flow 7/11/2002
7:00:00 8:00:00 9:00:00 10:00:00 11:00:00 12:00:00 13:00:00 14:00:00 15:00:00 16:00:00 17:00:00 18:00:00
Time
Figure 4-30. Venturi flow, Test 3-Day 3, July 11, 2002, Campaign #2.
87
-------
In the sample recovery area, the sample collection arrays were disassembled into the
following components:
Polyurethane foam (PUF) modules were disassembled from the sample collection
array as a module. Both ends of the PUF sampling module were capped, the
module placed in a sealable plastic bag, the bag appropriately labeled, and chain of
custody documentation initiated.
Filters were positioned in specific filter holder assemblies as part of several of the
sample collection arrays. In the sample recovery area, the filter holder assemblies
were disassembled, and the filter was removed with Teflon tipped tweezers and
placed in a pre-numbered custom filter container with a locking lid. The
appropriate label was affixed to the filter container and chain of custody
documentation initiated. The filter holder assembly was re-assembled without the
filter, placed in a plastic bag, and labeled.
Denuders were disassembled, the ends of the sorbent tube closed with Teflon caps
and sealed with Teflon tape, the sealed denuder tubes placed in a plastic bag,
labeled, and chain of custody documentation initiated.
Carbonyl sampling tube assemblies were disassembled. The ends of the individual
tubes were sealed with plastic caps, and the sealed tubes placed in an aluminum
foil packet, labeled to preserve the front/back order from the sample collection
array, placed in a plastic bag, labeled, and chain of custody documentation
initiated.
Canister sampling was terminated by closing the valve on the canister at the end of
the sampling period. The canister with closed valve was disconnected from the
dilution system and capped; chain of custody documentation was generated.
At a later time, extraction of the denuders was performed on-site. The denuders were
rinsed with a mixture of methylene chloride: acetone: hexane in a volume ratio of 2:3:5. The
solvent mixture was added to the denuder and the denuder tube was capped and shaken (four
times). An internal standard was added to the first extraction. The rinses were combined in a pre-
cleaned glass jar for paired denuders, the jar was labeled, sealed with Teflon tape, chain of
custody documentation was initiated for the extract, and the jar was stored over ice. After
extraction, the denuders and caps were dried using high-purity nitrogen and capped until ready for
re-use.
-------
Denuders, PUF modules, and filters were all bagged and stored on site in a chest freezer.
Canisters and carbonyl tubes were transported to the ERG laboratory for analysis; the filters, PUF
modules, and denuder extracts were transported to the EPA laboratory for analysis.
Chain of custody documentation for both test campaigns is supplied in Appendix E; field
sample logs are presented in Appendix F.
Laboratory Experimental Methodology
The analytical methodology used in EPA and ERG laboratories to perform the analyses is
summarized in Table 3-1.
Components of the sample collection arrays, filters, DNPH-impregnated silica gel tubes
used to sample carbonyl compounds, and canisters used to sample volatile organic compounds
were returned for analysis to EPA and ERG laboratories, respectively; the analyses described in
the following sections were performed.
PM-2.5 Mass
Teflon membrane (Gelman Teflo) filters of 2-|im pore diameter were used to collect fine
PM samples for mass determinations. Filters before and after sample collection were maintained
at 20-23 °C and a relative humidity of 30-40% for a minimum of 24 hours prior to weighing on a
micro-balance. Sample mass was determined by the difference in weight of a filter before and
after sample collection.
Elemental Analysis
Individual elements above atomic number 9 (fluorine) were measured using a Philips 2404
wavelength-dispersive X-ray fluorescence (XRF) spectrometer running the UniQuant program.
This program gives qualitative and quantitative information on the elements present on a Teflon
membrane filter. The filter to be analyzed was covered with a 0.4-|im thick Prolene film, which
was attached using glue. The glue was on only the outer rim of the filter and did not interfere
89
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with the analysis. Only elements which gave amounts greater than one standard error above the
detection limit were reported.
Water-Soluble Inorganic Ions
Teflon filter samples were analyzed for major inorganic anions and cations using a Dionex
DX-120 ion chromatograph equipped with a 25-|iL sample loop and a conductivity detector.
Major ions determined were chloride, nitrate, sulfate, calcium, magnesium, potassium, and
ammonium. Prior to extraction the filters were wetted with ethanol (350-500 |j,L). Two
sequential extractions with HPLC grade water were performed using mild sonication of the filters
followed by filtration of the extracts. The two extracts were combined for analysis.
Anions were separated using an Ion Pac AS 14 (4 x 250 mm) column with an alkyl
quaternary ammonium stationary phase and a carbonate-bicarbonate mobile phase. Cations were
separated using an Ion Pac CS12 (4 x 250 mm) column with an 8-|im poly(ethylvinylbenzene-
divinylbenzene) macroporous substrate resin functionalized with a relatively weak carboxylic
acid stationary phase and a sulfuric acid mobile phase. Ion concentrations were determined from
four-point calibration curves using an external standard method. All samples were extracted and
analyzed in duplicate or triplicate.
Elemental Carbon/Organic Carbon
Elemental carbon (EC) and organic carbon (OC) content of PM samples collected on pre-
fired quartz filters was determined by NIOSH Method 504010 using a Sunset Laboratory
instrument with a 30-m, 0.32-mm ID. Rtx - SMS (Crossbond 5% diphenyl - 95% dimethyl
polysilorane) capillary column, with a 1 |im film thickness. In this method, a 1.0- x 1.5-cm punch
of the quartz filter sample is placed in the instrument, and organic and carbonate carbon are
evolved in a helium atmosphere as the temperature is raised to 850 °C. Evolved carbon is
catalytically oxidized to CO2 in a bed of granular MnO2, then reduced to methane in a methanator.
Methane is subsequently quantified by a flame ionization detector (FID). In a second stage, the
sample oven temperature is reduced, an oxygen-helium mixture is introduced, and the
temperature is increased to 940 °C. With the introduction of oxygen, pyrolytically generated
90
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carbon is oxidized and an increase in the transmittance of a laser light beam through the filter
occurs. The point at which the filter transmittance reaches its initial value is defined as the split
between OC and EC. Carbon evolved prior to the split is considered OC (including carbonate),
and carbon volatilized after the split is considered elemental (EC). Elemental carbon evolved is
similarly oxidized to CO2 and subsequently reduced to methane to be measured by the FID.
Organic Compounds
Individual organic compounds present in the fine PM collected on pre-fired quartz filters
were determined by extracting the filters with hexane (two extractions) followed with a 2:1
mixture of benzene and isopropanol (three extractions). Prior to extraction, the filters were
composited as necessary to achieve a total of approximately 0.5 mg of OC and spiked with a
mixture of isotropically labeled (deuterated) internal recovery standards. These standards were
selected to represent the range of expected solubilities, stabilities, chromatographic retention
times, and volatilities of organic compounds present in the samples. All extracts from the five
extraction steps were combined and concentrated using an automated nitrogen blowdown
apparatus.
An aliquot of the combined extract was derivatized with diazomethane to yield methyl
esters of any fatty acids which might be present. After the methylation reaction was complete, the
methylated extract aliquot was reconcentrated by nitrogen blowdown. A separate portion of the
methylated extract was derivatized a second time using Sylon BFT reagent to convert compounds
such as levoglucosan and cholesterol to their trimethylsilyl (TMS) derivatives. Both
derivatizations were performed in order to allow the compounds to be separated and eluted from a
gas chromatograph column. Since the TMS derivatives are somewhat unstable over time, the
silylation was carried out just prior to analysis.
Gas chromatography coupled with a mass spectrometer detector (GC/MS) was used to
identify and quantify the individual organic compounds present in the extracts. A Hewlett-
Packard 6890 GC equipped with an HP 5973 mass spectrometer detector was used. A SMS
column (30-m, 0.25-mm diameter, 0.25-|im film thickness) was employed along with an injector
temperature of 65 °C and a GC/MS interface temperature of 300 °C. The initial GC oven
91
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temperature was set at 65 °C with an initial hold time of 10 min. The oven temperature was then
ramped upward at 10 °C/min to 300 °C and held at the upper temperature for an additional 41.5
minutes. Helium was used as the carrier gas (1 mL/min), and the GC was operated in the
split/splitless mode.
Positive identification of target compounds was obtained by comparing mass spectra of
the analytes with those obtained from over 100 authentic compound standards. Iso- and anteiso-
alkanes were identified using secondary standards derived from paraffin candle wax. Additional
compounds were identified as "probable" based on a comparison of the GC retention times and
mass spectra with commercially available spectral libraries. Quantification of the individual
compounds involved referencing each compound against one or more of the deuterated internal
standards spiked into the sample to correct for losses of the analytes which may have occurred in
the compositing, extracting, concentrating, and derivatizing steps. An extensive set of standards
of target compounds at known concentrations which also included the deuterated internal
standard compounds was used to establish 3-point or 5-point calibration curves from which the
concentrations of the analytes were determined.
Carbonyl Compounds
Carbonyl compounds were sampled and analyzed in campaign #1 only. Sep-Pak
chromatographic-grade silica gel cartridges impregnated with DNPH were used in series for
carbonyl sample collection; the tubes were used in series to check for compound breakthrough.
Following sample collection in the field, the cartridges and accompanying chain of custody
documentation were transported to the ERG laboratory, where they were logged into the
laboratory sample tracking system. The cartridges were extracted and analyzed for the
compounds listed in Table 4-12 using a modified version of EPA Compendium Method
TO-11A11, "Determination of Formaldehyde in Ambient Air Using Adsorbent Cartridge Followed
by High Performance Liquid Chromatography (HPLC)". The analytical instrument was a Varian
5000 High Performance Liquid Chromatograph (HPLC) with a multiwavelength detector
operated at 360 nanometers (nm). The HPLC was configured with a 25-cm, 4.6-mm ID., CIS
silica
92
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Table 4-12. Carbonyl Compounds Analyzed by High Performance Liquid Chromatography
Compound CAS No.
Formaldehyde 50-00-0
Acetaldehyde 75-07-0
Acetone 67-64-1
Propionaldehyde 123-38-6
Crotonaldehyde 4170-30-3
Butyraldehyde 123-72-8
Benzaldehyde 100-52-7
Isovalderaldehyde 590-86-3
Valeraldehyde 110-62-3
o-Tolualdehyde 529-20-4
/w-Tolualdehyde 620-23-5
^-Tolualdehyde 104-87-0
Hexaldehyde 66-25-1
2,5-Dimethylbenzaldehyde 5779-94-2
Diacetyl 432-03-8
Methacrolein 78-85-3
2-Butanone 78-93-3
Glyoxal 107-22-2
Acetophenone 98-86-2
Methylglyoxal 78-98-8
Octanal 124-13-0
Nonanal 124-19-6
analytical column with a 5-micron particle size. Twenty-five (25) |j,L aliquots were injected into
the HPLC with an automatic sample injector.
The chromatography data acquisition system was used to retrieve data from the HPLC;
data were processed and peak identifications were made using retention times and relative
retention times determined by analysis of analytical standards. After peak identifications were
made, the concentration of each target analyte was determined using individual response factors
for the carbonyl compounds.
Daily calibration checks were performed to ensure that the analytical procedures were in
control. Daily quality control checks were performed after every ten samples on the days that
93
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samples were analyzed, with compound responses within ±15% relative to the responses from the
current calibration curve. Compound retention time drifts were also measured from the analysis
of the quality control check sample and tracked to ensure that the HPLC was operating within
acceptable parameters.
As part of the daily quality control check, if the analysis of the daily quality control
sample was not acceptable, a second injection of the quality control standard was performed. If
the second quality control check did not meet acceptance criteria or if more than one daily quality
control check did not meet acceptance criteria, a new calibration curve (at five concentration
levels) was analyzed. All samples analyzed with the unacceptable quality control checks would
be re-analyzed.
An acetonitrile system blank was analyzed after the daily calibration check and before
sample analysis. The system was considered in control if target analyte concentrations were less
than the current method detection limits.
Canister Analyses: Air Toxics and Speciated Nonmethane Organic Compounds
Canister sampling and analysis were performed for campaign #1 only. The combined
analysis12'13 for air toxics and speciated nonmethane organic compounds was performed on a gas
chromatograph(GC)/flame ionization detector(FID)/mass selective detector (MSD), using a
Hewlett-Packard 5971 MSD and a Hewlett-Packard 5890 Series II GC with a 60-m by 0.32-mm
i.d. and a 1 |im film thickness J&W DB-1 capillary column followed by a 2:1 splitter to send the
larger portion of the column effluent to the MSD and the smaller fraction to the FID. The
chromatograph oven containing the DB-1 capillary column was cooled to -50 °C with liquid
nitrogen at the beginning of the sample injection. This temperature was held for five minutes and
then increased at the rate of 15 °C per minute up to 0 °C. The oven temperature was then ramped
at 6 °C/minute to 150 °C, then ramped at 20 °C/minute to 225 °C and held for 8 min. The gas
eluting from the DB-1 capillary column passed through the 2:1 fixed splitter to divide the flow
between the MSD and the FID.
94
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The air toxics analysis was performed according to the procedures of EPA Compendium
Method TO-15, "Determination of Volatile Organic Compounds (VOCs) in Air Collected in
Specially-Prepared Canister and Analyzed by Gas Chromatography/Mass Spectrometry
(GC/MS)" for the compounds shown in Table 4-13. The analysis of SNMOC was performed
according to the procedures of "Technical Assistance Document for Sampling and Analysis of
Ozone Precursors13 " for the compounds shown in Table 4-14. Detection limits for air toxics and
for the speciated nonmethane organic compounds are shown in Appendix C. Method detection
limits were determined according to the Federal Register procedure.14
Particle Size Distribution Data
The SMPS was operated and collected data during both test days. Data were reduced
using the TSI software package.
95
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Table 4-13. Air Toxics Compounds Determined by Analytical Method TO-15
Compound
CAS No.
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromometnane
Chloroethane
Acetonitrile
Acetone
Trichlorofluoromethane
Acrylonitrile
1,1 -Dichloroethene
Methylene chloride
Trichlorotrifluoroethane
/ra«5-l,2-Dichloroethylene
1,1 -Dichloroethane
Methyl fer/-butyl ether
Methyl ethyl ketone
Chloroprene
cis-1,3 -Dichloroethy lene
Bromochloromethane
Chloroform
Ethyl tert-butyl ether
1,2-Dichloroethane
1,1,1 -Trichloroethane
Benzene
Carbon tetrachloride
ter/-Amyl methyl ether
1,2-Dichloropropane
Ethyl acrylate
Bromodichloromethane
Trichloroethylene
Methyl methacrylate
c/5-l,2-Dichloropropene
74-86-2
115-07-1
75-71-8
74-87-3
1320-37-2
75-01-4
106-99-0
74-83-9
75-00-3
75-05-8
67-64-1
75-69-4
107-13-1
75-35-4
75-09-2
26523-64-8
56-60-5
75-34-3
1634-04-1
78-93-3
126-99-8
156-59-2
74-97-5
67-66-3
637-92-3
107-06-2
71-55-6
71-43-2
56-23-5
994-05-8
78-87-5
140-88-5
75-27-4
79-01-6
80-62-6
10061-01-5
96
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Table 4-13. (Continued)
Compound
CAS No.
Methyl isobutyl ketone
/ra«5-l,2-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
w-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m-, p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
/w-Dichlorobenzene
Chloromethylbenzene
/>-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-1,3 -butadiene
108-10-1
10061-02-6
79-00-5
108-88-3
124-48-1
106-93-4
111-65-9
127-18-4
108-90-7
100-41-4
108-38-3/106-42-3
75-25-2
100-42-5
79-34-5
95-47-6
108-67-8
95-63-6
541-73-1
100-44-7
106-46-7
95-50-1
120-82-1
87-68-3
97
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Table 4-14. Speciated Nonmethane Organic Compounds Determined According to the
Procedures of EPA Research Operating Procedure "Research Protocol Method for Analysis
of C2-C12 Hydrocarbons in Ambient Air by Gas Chromatography with Cryogenic
Concentration"
Compound
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1 -butene
1,3 -Butadiene
w-Butane
/ra«s-2-Butene
c/s-2-Butene
3 -Methyl- 1 -butene
Isopentane
1-Pentene
2-Methyl-l-butene
w-Pentane
Isoprene
/ra«5-2-Pentene
c/s-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3 -Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl-l-pentene
1-Hexene
2-Ethyl-l-butene
w-Hexane
/r
-------
Table 4-14. (Continued)
Compound
CAS No.
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3 -Dimethylpentane
3 -Methy Ihexane
1-Heptene
2,2,4-Trimethylpentane
w-Heptane
Methylcyclohexane
2,2,3-Trimethylpentane
2,3,4-Trimethylpentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethylbenzene
m-, p-Xylene
Styrene
o-Xylene
1-Nonene
w-Nonane
Isopropylbenzene
a-Pinene
w-Propylbenzene
/w-Ethyltoluene
/>-Ethyltoluene
1,3,5-Trimethylbenzene
o-Ethyltoluene
p-Pinene
1,2,4-Trimethylbenzene
1-Decene
w-Decane
1,2,3 -Trimethy Ibenzene
/M-Diethylbenzene
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
Table 4-14. (Continued)
99
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Compound CAS No.
^-Diethylbenzene 105-05-5
1-Undecene 821-95-4
w-Undecane 1120-21-4
1-Dodecene 112-41-4
w-Dodecane 112-40-3
1-Tridecene 2437-56-1
w-Tridecane 629-50-5
100
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Section 5
Results and Discussion
Analyses for each campaign were performed in either the EPA or ERG laboratories as
shown in Table 3-1, using the analytical procedures described in Section 4. Results of these
analyses are discussed in this section.
PM Mass, Elemental/Organic Carbon, Major Inorganic Ions, and Major Elements
Emissions of PM mass, elemental/organic carbon (EC/OC), major elements, and major
inorganic ions as components of the fine particulate matter are reported in Table 5-1 both as
weight percent and as mass fraction of measured PM-2.5 mass. Results reported in Table 5-1
show the following:
The PM-2.5 mass emission factor was fairly consistent throughout both test
campaigns with the exception of one day during campaign #2 (7/11/02) for which
the emission factor was nearly 5 times higher than the average of the other 5 test
days. Excluding the single day of markedly higher emissions, the average PM-2.5
mass emission factor was 36.4 mg per kg of fuel (0.81 |ig/kJ) with a range of 26.9
to 42.7 mg/kg (0.60 - 0.96 |ig/kJ). The single day of substantially higher PM-2.5
emissions gave an emission factor of 178.0 mg per kg of fuel (3.99 |ig/kJ). No
unusual event on that day was identified to explain the higher PM-2.5 emissions
for that test. However, during campaign #2 (which occurred in July) the boiler
was operated at very low load where combustion conditions are difficult to
maintain. Under such conditions, erratic behavior in boiler operation and
emissions may occur.
Although the PM-2.5 mass emission factor was fairly consistent for both test
campaigns, the composition of the PM-2.5 was very different for the two
campaigns. Sulfate comprised 45.5 to 58.0% by mass of the PM-2.5 emitted
during campaign #1, but accounted for only 3.5 to 10.8% of the PM-2.5 mass
during campaign #2.
101
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Table 5-1. Summary of Oil-Fired Institutional Boiler Results
Campaign #1 (1/01)
Campaign #2 (7/02)
o
to
Parameter
Fuel Feed Rate (kg/min)
Fuel Carborf
(wt %)
Fuel Sulfur1
(wt %)
Flue Gas Composition
Flue Gas O2 (volume %, wet)
Flue Gas CO2 (volume %, wet)
Flue Gas CO (volume %, wet)
Flue Gas O2 (volume %, dry)
Flue Gas CO2 (volume %, dry)
Flue Gas CO (volume %, dry)
Flue Gas N2 (volume %, dry)
Excess Air (%)
Test #1
10.94
85.93
0.09
4.8
16.2
0.03
5.4
18.2
0.034
76.4
36.1
Test #2
11.55
85.93
0.09
5.3
15.7
0.03
6.0
17.6
0.034
76.4
41.4
Test #3
13.21
85.93
0.09
5.5
15.5
0.03
6.2
17.4
0.034
76.4
43.6
Test #1
7.40
86.53
0.05
8.1
11.0
0.0
10.2
12.1
0.0
77.6
97.6
Test #2
7.43
86.53
0.05
9.0
10.7
0.03
10.1
11.8
0.034
78.1
94.4
Test #3
7.43
86.53
0.05
8.9
10.4
0.03
9.1
11.2
0.034
79.7
74.8
PM-2.5 Emission Factor
(mg/kg fuel)
26.86 ±3.44
32.09 ±1.89
39.77 ±0.:
40.36 ±1.27
42.67 ±2.51
178.02 ±2.51
-------
Table 5-1. (Continued)
Mean PM-2.5 Emission Factor (mg/kg fuel) 32.91 ± 5.93
Mean PM-2.5 Emission Factor (mg/kg fuel) 87.02 ± 67.3
PM-2.5 Composition (wt %)
Elemental Carbon 1.8 10.5 34.0
Mean Elemental Carbon 15.4 ± 16.6 wt %
Organic Carbon 0 0.5 0
Mean Organic Carbon 0.17 ± 0.29 wt %
Sulfate 58.0 ±6.1 56.9 ± 5.3 45.5 ± 4.2
MeanSulfate 53.5±7.4wt%
Ammonium NQ NQ NQ
Mean Ammonium NQ
Sulfur 5.2 ±2.2 3.4 ±0.2 8.3 ±6.0
Mean Sulfur 5.6 ±3.6
Silicon NQ NQ NQ
Mean Silicon NQ
PM-2.5 Composition (mass fraction)
5.8 ±1.4 3.1 ±0.7 1.6 ±0.2
Mean Elemental Carbon 4.0 ± 2.2 wt %
43.3 ±5.9 45.7 ±12.0 63.1 ±4.3
Mean Organic Carbon 50.7 ± 10.1 wt %
6.8 ±0.2 10.7 ±0.1 3.5 ±0.0
Mean Sulfate wt %
2.0 ±0.2 2.6 ±0.1 0.46 ±0.0
Mean Ammonium l 7 ± 1 0 wt %
2.7 ±0.2 3.7 ±0.1 1.3 ±0.1
Mean Sulfur 2.6 ± 1.1 wt %
0.89 ±0.10 0.75 ±0.10 0.24 ± 0.00
Mean Silicon 0.63 ± 0.31 wt %
Elemental Carbon 0.018 0.105
Mean Elemental Carbon 0.15 ± 0.17 mass fraction
Organic Carbon 0 0.005
Mean Organic Carbon 0.0017 ± 0.0029 mass fraction
0.34
0.066 0.038 0.017
Mean Elemental Carbon 0.040 ± 0.025 mass fraction
0.433 0.452 0.631
Mean Organic Carbon 0.505 ± 0.109
-------
Table 5-1. (Continued)
PM-2.5 Composition (mass fraction)
Sulfate 0.58 ±0.061 0.569 ±0.053 0.455 ±0.042
Mean Sulfate 0.535 ± 0.069 mass fraction
Ammonium NQ NQ NQ
Mean Ammonium NQ
Sulfur 0.052 ±0.022 0.034 ± 0.002 0.083 ± 0.063
Mean Sulfur 0.056 ± 0.025 mass fraction
Silicon NQ NQ NQ
Mean Silicon NQ
0.068 ±0.002 0.107 ±0.001 0.035 ± 0.000
Mean Sulfate 0.070 ± 0.036 mass fraction
0.02 ±0.002 0.026 ±0.001 0.046 ± 0.000
Mean Ammonium 0.017 ± 0.011 mass fraction
0.027 ±0.002 0.037 ±0.001 0.013 ±0.001
Mean Sulfur 0.026 ± 0.012 mass fraction
0.0089 ±0.0010 0.0075 ± 0.0000 0.0024 ± 0.0000
Mean Silicon 0.0063 ± 0.0034 mass fraction
a Fuel was sampled one time per campaign and the results applied to all the test runs in each of the two campaigns.
NQ = Below quantitation limit.
-------
• Conversely, there was much more carbon in the PM-2.5 emitted during campaign
#2, most of which was organic carbon (43.3 to 63.1% of the PM-2.5 mass). The
organic carbon (OC) content of the fine PM was highest for Test Day #3 of
campaign #2 (7/11/02), for which the PM-2.5 emission factor was also the highest
of all tests.
• Two factors may have contributed to the marked difference in PM composition.
The sulfur content of the fuel oil was 1.8 times higher during the campaign #1 test
series than during the campaign #2 tests (0.09 vs 0.05 wt %, respectively). This
factor could have contributed to a higher sulfate content in the campaign #1 tests.
In the campaign #2 tests, the fuel feed rate averaged 37.6% lower than in the
campaign #1 tests and the excess oxygen levels were much higher (campaign #2 =
15.7 to 20.5%; campaign #1 = 7.6 to 9.2% excess oxygen). During the campaign
#1 tests, the boiler was fired at 37 - 42% of its rated capacity, while during the
campaign #2 tests, the boiler was fired at only 25% capacity. A lower combustion
efficiency associated with the low combustion load during the summertime is
likely responsible for the PM emissions being enriched in organic carbon.
Supporting data for Table 5-1 are found in the following appendices:
• Appendix J, Data Tables for Individual PM-2.5 Mass Measurements, Both
Campaigns;
Appendix K, Data Tables for PM-2.5 Mass Emission Factors, Both Campaigns;
Appendix L, Data Tables for Individual PM-2.5 EC/OC Samples, Both
Campaigns;
• Appendix M, Data Tables for Individual PM-2.5 Elemental Samples, Both
Campaigns; and
Appendix N, Data Tables for Individual PM-2.5 Inorganic Ion Samples, Both
Campaigns.
General Equation for Uncertainty
If a result, R, is calculated from a set of measurements, xl5 x2, ..., xn, it can be expressed
as:
R= R(x},x2,...xJ (5-1)
105
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The uncertainty in the calculated result, WR, is given as:
WR =
dR
dR
•w, +...+
(5-2)
where wl3 w2, and w3 are the uncertainties in each of the respective measurements.
Uncertainty in PM Mass Emission Factor Estimation
The three-day average emission factor, Ea, is calculated by:
E =
} + E2 + E3
3
(5-3)
where El3 E2, and E3 are the emission factors for Day-1, Day-2, and Day-3, respectively. Thus,
the uncertainty in ER can be obtained as:
Wu =
w,
^'
8F
l/J-'n
+
-w, I + I -w3
(5-4)
where wl3 w2, w3 are the uncertainties in PM emission factors for Day-1, Day-2, and Day-3,
respectively. In this report the values for uncertainties wl3 w2, and w3 are taken to be the standard
deviations (Sl3 S2, and S3) for the daily emission factor averages.
Uncertainty in PM-2.5 Organic Carbon Concentration
The OC concentration in PM-2.5 is given by:
106
-------
cf-ch- c,
OC = — x 100%
(5-5)
where Cf, Cb, and Cd represent the daily average OC concentrations on the primary (front) quartz
filters (QF), backup QFs, and dilution chamber QF, and CP represents the daily average PM
concentrations on the Teflon filters (TF). These concentrations are obtained by dividing the
sample mass by the volume of flow in the sampling array. The uncertainty in the day-average OC
concentration in the PM is then derived as:
WR =
dC
o/^>
oL
(5-6)
'KV.
[UJ
'W*12+
,cj +
( c - c - c V
1 u/ u* u^ 1
c2 Wp
\ *— p J
where wf, wb, and wp represent the uncertainties in day-average OC concentrations in the front
QF, backup QF, and day-average PM concentration. These uncertainties are taken to be the
standard deviations (Sf, Sb, and Sp) of the respective daily averages. There was no standard
deviation associated with the OC concentration for the dilution air sample because of only one QF
and one TF was used to sample the dilution air each day.
The uncertainty for the three-day average of OC concentration is calculated using the
same equation as for three-day average PM emission factor.
Uncertainty in Gas-Pnase SemiVo/afi/e Organic Species Emission Factors
Uncertainties of three-day averages of emission factors for gas-phase semivolatile organic
species analyzed on the PUF samples were calculated using an equation in the same form as that
for the three-day average PM emission factor (Equation 4).
107
-------
Uncertainty in Particle-Phase Semivolatile Organic Species Emission Factors
Since the QF samples were composited for each day of the first two days, the average and
standard deviation of the first two days was first calculated. The three-day average is then given
by:
E1+2 + E3
(5-7)
where E1+2 is the average emission factor for the first two days. The uncertainty for the three-day
average is calculated as:
1+2
dE,
(5-8)
I '
.3Wj+2;
where w1+2 and w3 are the standard deviations for the first two days and for the third day,
respectively.
108
-------
Uncertainty in PM-2.5 Elemental and Ion Concentrations
Element and inorganic ion concentrations in the PM-2.5 for each test day are reported as
averages of replicate samples taken on each test day. Uncertainties reported for these averages
represent the standard deviation of the replicate sample analyses.
Speciated Gas- and Particle-Phase Organic Compounds
Semivolatile organic compounds were not determined during campaign #1 because the
gas-phase semivolatiles exceeded the collection capacity of the XAD-coated denuders and the
PUF plugs. Sampling for ten hours in an attempt to maximize collection of PM for organic
compound analysis resulted in overloading the denuders and PUF plugs so that an undetermined
quantity of gas-phase material was allowed to escape collection and analysis.
For campaign #2, fine PM samples collected on quartz filters and gas-phase semivolatile
organic compounds collected on PUF plugs and organic denuders were extracted from the
collection media with a solvent system consisting of benzene :hexane:isopropanol (for filter
samples) or dichloromethane:hexane:acetone (for PUFs and denuders) followed by GC/MS
analysis of the extracts. Table 5-2 lists those organic compounds which were positively identified
above detection limits and above the amounts found in the cleaned dilution air in the fine PM, all
of which are relatively high molecular weight hydrocarbons. Compositing the quartz filters was
necessary in order to achieve even the results reported; the compositing scheme for the quartz
filters is presented in the Sample log in Appendix F. All PUF plug pairs were analyzed
individually; none were composited. Emission factors for the gas-phase semivolatiles from the
oil-fired industrial boiler are shown in Table 5-2, together with the calculated uncertainty.
Particle-phase semivolatiles expressed as mass fractions are shown in Table 5-3, and as emission
factors, in Table 5-4.
Most of the speciated and quantified organic carbon associated with the fine PM was
made up of the C16 through C31 w-alkanes (63.8 wt.% of the speciated PM organics). n-
Tetracosane (C24) was the single most prominent w-alkane with the other C16-C31 species in a near-
Gaussian distribution by carbon number around C24. Benzene di- and tri-carboxylic acids
109
-------
comprised the second largest category of organic constituents found in the fine PM (21.4 wt % of
the quantified species). Polynucleararomatic hydrocarbons (PAHs) and w-alkanoic acids made up
most of the remaining 14.8% of the quantified and speciated particle phase organic compounds.
The benzene di- and tri-carboxylic acids and chrysene were the only semivolatile organic species
confined to the particle-phase. All of the other semivolatile species were found in both the gas
and particle phases with the predominant amounts in the gas phase. The only two elements in the
PM which were found at levels above method quantitation limits were silicon and sulfur.
Supporting data for the semivolatile organic compounds are found in the following
appendices:
Appendix O, Data Tables for Individual or Composited Particle-Phase (Quartz
Filter) Semivolatile Organic Compound Samples; and
Appendix P, Data Tables for Individual Gas-Phase (PUF) Semivolatile Organic
Compound Samples.
110
-------
Table 5-2. Gas Phase Semivolatiles: Emission Factors from an Institutional Oil-Fired Boiler
(Campaign #2, July 2002)
Compound
dimethyl phthalate
diethyl phthalate
naphthalene
2-methylnaphthalene
1 -methy Inaphthalene
2,7-dimethylnaphthalene
1 ,3 -dimethy Inaphthalene
2,6-dimethy Inaphthalene
additional dimethylnaphthalenes
acenaphthylene
acenaphthene
fluorene
1 -methy Ifluorene
additional methy Ifluorenes (peak 1)
additional methylfluorenes (peak 2)
phenanthrene
additional dimethylphenanthrenes
anthracene
methylanthracene - peak 1
methylanthracene - peak 2
methylanthracene - peak 3
methylanthracene - peak 4
octylcyclohexane
norpristane
decylcyclohexane
pristane
phytane
tridecylcyclohexane
Emission Factor
(mg/kg fuel)
0.000
0.076
0.667
3.688
2.526
3.499
2.561
3.715
2.559
0.047
0.066
0.516
0.857
0.960
0.274
1.258
0.127
0.127
1.188
1.702
0.843
0.672
0.043
3.219
0.338
2.986
2.163
0.040
Uncertainty
(mg/kg fuel)
0.000
0.031
0.167
0.846
0.530
0.514
0.580
0.576
0.466
0.013
0.086
0.114
0.281
0.326
0.096
0.263
0.061
0.253
0.473
0.431
0.222
0.156
0.036
1.593
0.050
1.204
1.314
0.070
111
-------
Table 5-2. (Continued)
Emission Factor Uncertainty
Compound (mg/kg fuel) (mg/kg fuel)
dibutyl phthalate 0.140 0.070
butyl benzyl phthalate 0.078 0.078
6/X2-ethylhexyl) phthalate 0.063 0.034
dioctyl phthalate 0.074 ND
fluoranthene 0.065 0.041
pyrene 0.058 0.041
chrysene 0.002 0.002
benzo [a] anthracene ND ND
benzo[k]fluoranthene ND ND
benzo[b]fluoranthene
benzo [a]pyrene
nonadecylcyclohexane 0.002 0.003
squalane
indeno[l,2,3-cd]pyrene
dibenzo[a,h]anthracene
benzo[ghi]perylene
coronene
cholestane - peak 1
cholestane - peak 2
cholestane - peak 3
cholestane - peak 4
ABB-2OR-24S-methylcholestane
ABB-2OR-ethylcholestane
17A(H)-22,29,30-/ra(norhopane)
17(B)-21 A(H)-norhopane
17B(H)-21B(H)-hopane
17B(H)-21 A(H)-hopane
17A(H)-21B(H)-hopane
112
-------
Table 5-2. (Continued)
Compound
w-decane (w-CIO)
w-undecane (w-Cll)
w-dodecane («-C12)
n-tridecane (w-C13)
9H-fluoren-9-one
w-tetradecane (w-C14)
n-pentadecane (»-C15)
w-hexadecane (w-C16)
w-heptadecane (w-C17)
1-octadecene
w-octadecane (w-C18)
2-methylnonadecane
3 -methy Inonadecane
w-nonadecane (w-C19)
w-eicosane («-C20)
w-heneicosane (w-C21)
w-docosane (w-C22)
w-tricosane (w-C23)
/5o-docosane (C22)
awte/5o-docosane (C22)
pyrene
anthraquinone
naphthalic anhydride
methylfluoranthene
retene
cyclopenta[c,d]acepyrene
benzanthraquinone
1 -methy Ichrysene
Emission Factor
(mg/kg fuel)
0.014
0.855
0.686
0.127
2.405
6.089
8.948
7.787
0.002
4.242
0.000
0.000
3.331
2.965
2.424
2.034
1.959
0.080
Uncertainty
(mg/kg fuel)
0.011
0.130
0.054
0.028
0.539
1.963
2.201
2.854
0.003
2.384
0.000
0.000
2.032
1.603
1.084
0.689
0.504
0.010
113
-------
Table 5-2. (Continued)
Emission Factor Uncertainty
Compound (mg/kg fuel) (mg/kg fuel)
w-tetracosane (w-C24 0.926 0.231
/5o-tricosane (C23)
anteiso-tricosane (C23)
n-pentacosane (w-C25) 0.501 0.178
/5o-tetracosane (C24)
awtewo-tetracosane (C24)
n-hexacosane (w-C26) 0.405 0.154
/5o-pentacosane (C25)
awtewo-pentacosane (C25)
n-heptacosane («-C27) 0.506 0.228
/5o-hexacosane (C26)
awfe/'so-hexacosane (C26)
/5o-heptacosane (C27)
awte/5o-heptacosane (C27)
/5o-octacosane (C28)
awtewo-octacosane (C28)
w-octacosane (w-C28) 0.609 0.303
w-nonacosane (w-C29) 0.483 0.238
/5o-nonacosane (C29)
awfe/'so-nonacosane (C29)
squalene 0.273 0.382
indeno [ 1,2,3 -cd]fluoranthene
dibenzo [a,e]pyrene
w-triacontane (w-C30) 1.641 0.823
w-hentriacontane(w-C31) 1.317 0.806
/5o-triacontane (C30)
awte/5o-triacontane (C30)
/5-o-hentriacontane (C31)
114
-------
Table 5-2. (Continued)
Emission Factor Uncertainty
Compound (mg/kg fuel) (mg/kg fuel)
awte/5o-hentriacontane (C31)
/'so-dotriacontane (C32)
awtewo-dotriacontane (C32)
n-dotriacontane («-C32) 0.693 0.249
w-tritriacontaine («-C33) 0.438 0.212
w-tetratriacontaine (w-C34) 0.522 0.263
/5o-tritriacontane (C33)
awte/5o-tritriacontane (C33)
w-pentatriacontane («-C35)
n-hexatracontane (w-C36) 0.649 0.223
w-tetracontane (w-C40) 0.145 0.099
hexanoic acid 0.482 0.097
succinic acid 0.040 0.007
octanoic acid 0.522 0.096
glutaricacid 0.012 0.009
nonanoic acid 0.884 0.272
adipic acid 0.002 0.004
decanoicacid 0.412 0.061
undecanoic acid 0.544 0.148
pimelic acid
suberic acid
dodecanoic acid 0.366 0.127
azelaic acid 0.036 0.062
tridecanoic acid
pinonic acid
phthalic acid
1,4-benzenedicarboxylic acid
1,3-benzenedicarboxylic acid
115
-------
Table 5-2. (Continued)
Compound
Emission Factor
(mg/kg fuel)
Uncertainty
(mg/kg fuel)
1,2-benzenedicarboxylic acid, 4-methyl
1,2,4-benzenetricarboxylic acid
benzenetetracarboxylic acid
abietic acid
pimaric acid
sandaracopimaric acid
isopimaric acid
dehydroabietic acid
sebacic acid
tetradecanoic acid
pentadecanoic acid
palmitoleic acid
hexadecanoic acid
heptadecanoic acid
linoleic acid
oleic acid
linolenic acid
octadecanoic acid
nonadecanoic acid
eicosanoic acid
docosanoic acid
tricosanoic acid
tetracosanoic acid
pentacosanoic acid
hexacosanoic acid
heptacosanoic acid
octacosanoic acid
nonacosanoic acid
0.366
0.239
0.151
0.985
0.068
0.030
0.070
0.000
0.525
0.021
0.021
0.054
0.251
0.169
0.238
0.636
0.035
0.018
0.103
0.000
0.226
0.008
0.011
0.027
116
-------
Table 5-2. (Continued)
Emission Factor Uncertainty
Compound (mg/kg fuel) (mg/kg fuel)
triacontanoic acid
Total 96.03 27.76
117
-------
Table 5-3. Particle-Phase Semivolatiles from an Institutional Oil-Fired Boiler: Mass
Fractions (Campaign #2, July 2002)
Compound
additional dimethylnaphthalenes
acenaphthylene
acenaphthene
fluorene
1 -methy Ifluorene
additional methyIfluorenes (peak 1)
additional methy Ifluorenes (peak 2)
phenanthrene
additional dimethylphenanthrenes
anthracene
methylanthracene - peak 1
methylanthracene - peak 2
methylanthracene - peak 3
methylanthracene - peak 4
octylcyclohexane
norpristane
decylcyclohexane
pristane
Summer Campaign
Average
Mass Fraction
0.00385
0.01509
0.01376
0.03651
0.04635
0.02841
0.02411
Uncertainty
dimethyl phthalate
diethyl phthalate
naphthalene
2-methy Inaphthalene
1 -methy Inaphthalene
2,7-dimethy Inaphthalene
1 ,3 -dimethy Inaphthalene
2,6-dimethy Inaphthalene
ND
0.00234
ND
0.00128
0.00064
0.00146
0.00290
0.00140
ND
0.00082
ND
0.00082
0.00036
0.00094
0.00162
0.00088
0.00069
0.00190
0.00112
0.00498
0.00635
0.00354
0.00339
0.00702
0.00132
118
-------
Table 5-3. (Continued)
Compound
Average
Mass Fraction
Uncertainty
phytane
tridecylcyclohexane
dibutyl phthalate
butyl benzyl phthalate
6/X2-ethylhexyl) phthalate
dioctyl phthalate
fluoranthene
pyrene
chrysene
benzo [a] anthracene
benzo[k]fluoranthene
benzo[b]fluoranthene
benzo [a]pyrene
nonadecylcyclohexane
squalane
indeno[l,2,3-cd]pyrene
dibenzo[a,h]anthracene
benzo [ghijperylene
coronene
cholestane - peak 1
cholestane - peak 2
cholestane - peak 3
cholestane - peak 4
ABB-2OR-24S-methylcholestane
ABB-2OR-ethylcholestane
17A(H)-22,29,30-/r/Xnorhopane)
17(B)-21 A(H)-norhopane
0.02373
0.01745
0.00848
0.01038
0.04065
0.00191
0.03512
0.00881
0.00490
0.00187
0.00876
0.00887
0.03904
0.00130
0.00358
0.00095
119
-------
Table 5-3. (Continued)
Compound
Average
Mass Fraction
Uncertainty
17B(H)-21B(H)-hopane
17B(H)-21A(H)-hopane
17A(H)-2 lB(H)-hopane
n-decane (w-CIO)
w-undecane (w-Cll)
w-dodecane («-C12)
n-tridecane (w-C13)
9H-fluoren-9-one
w-tetradecane (w-C14)
n-pentadecane (»-C15)
w-hexadecane (w-C16)
w-heptadecane (w-C17)
1-octadecene
w-octadecane (w-C18)
2-methylnonadecane
3 -methy Inonadecane
w-nonadecane (w-C19)
w-eicosane (n-C20)
w-heneicosane (w-C21)
n-docosane (w-C22)
w-tricosane (w-C23)
/5o-docosane (C23)
awte/5o-docosane (C23)
pyrene
anthraquinone
naphthalic anhydride
methy Ifluoranthene
0.00052
0.00069
0.00004
0.00436
0.01469
0.02085
0.05049
0.15462
0.16568
0.20432
0.25152
0.00066
0.00138
0.00008
0.00124
0.00412
0.00564
0.00901
0.04156
0.04720
0.04845
0.03866
0.08036
0.00869
120
-------
Table 5-3. (Continued)
Compound
Average
Mass Fraction
Uncertainty
benzanthraquinone
1 -methy Ichry sene
w-tetracosane («-C24
/5o-tricosane (C24)
anteiso-tiicosane (C24)
w-pentacosane («-C25)
/5o-tetracosane (C25)
awte/5o-tetracosane (C25)
w-hexacosane (w-C26)
/5o-pentacosane (C26)
awte/5o-pentacosane (C26)
w-heptacosane (n-C27)
/5o-hexacosane (C27)
awte/5o-hexacosane (C27)
/5o-heptacosane (C28)
awtewo-heptacosane (C28)
/5o-octacosane (C29)
awte/5o-octacosane (C29)
w-octacosane (w-C28)
n-nonacosane (w-C29)
/5o-nonacosane (C30)
awtewo-nonacosane (C30)
squalene
indeno [ 1,2,3 -cd]fluoranthene
dibenzo [a,e]pyrene
n-triacontane («-C30)
w-hentriacontane (w-C31)
0.41407
0.22033
0.18047
0.13140
0.10031
0.06173
0.09177
0.00135
0.00142
0.03666
0.01569
0.01074
0.00846
0.00794
0.00555
0.03406
0.00097
0.00160
121
-------
Table 5-3. (Continued)
Compound
/'so-triacontane (C31)
awfe/'so-triacontane (C31)
/5o-hentriacontane (C32)
awfe/so-hentriacontane (C32)
/5o-dotriacontane (C33)
awtewo-dotriacontane (C33)
n-dotriacontane (w-C32)
w-tritriacontaine (w-C33)
w-tetratriacontaine (w-C34)
/5o-tritriacontane (C34)
awte/5o-tritriacontane (C34)
w-pentatriacontane («-C35)
n-hexatracontane (w-C36)
w-tetracontane (w-C40)
hexanoic acid
succinic acid
octanoic acid
glutaric acid
nonanoic acid
adipic acid
decanoic acid
undecanoic acid
pimelic acid
suberic acid
dodecanoic acid
azelaic acid
tridecanoic acid
pinonic acid
Average
Mass Fraction
0.00041
0.00064
0.00093
0.00351
0.01805
0.00416
0.01289
0.00578
0.00943
0.00422
0.00803
0.00798
0.00859
0.00674
0.00437
0.01795
Uncertainty
(%)
0.00064
0.00036
0.00043
0.00054
0.00188
0.00051
0.00355
0.00027
0.00520
0.00213
0.00439
0.00083
0.00158
0.00389
0.00093
0.02539
122
-------
Table 5-3. (Continued)
Compound
Average
Mass Fraction
Uncertainty
phthalic acid
1,4-benzenedicarboxylic acid
1,3-benzenedicarboxylic acid
1,2-benzenedicarboxylic acid, 4-methyl
1,2,4-benzenetricarboxylic acid
benzenetetracarboxylic acid
abietic acid
pimaric acid
sandaracopimaric acid
isopimaric acid
dehydroabietic acid
sebacic acid
tetradecanoic acid
pentadecanoic acid
palmitoleic acid
hexadecanoic acid
heptadecanoic acid
linoleic acid
oleic acid
linolenic acid
octadecanoic acid
nonadecanoic acid
eicosanoic acid
docosanoic acid
tricosanoic acid
tetracosanoic acid
pentacosanoic acid
hexacosanoic acid
0.00079
0.04304
0.07511
0.43862
0.11274
0.08921
0.00331
0.00311
0.00267
0.00112
0.00223
0.00351
0.02279
0.01355
0.00879
0.01823
0.13150
0.01520
0.01516
0.00550
0.00743
0.01804
0.05328
0.00328
0.00417
0.00071
0.01976
0.00076
0.00073
0.00203
123
-------
Table 5-3. (Continued)
Compound
Average
Mass Fraction
Uncertainty
heptacosanoic acid
octacosanoic acid
nonacosanoic acid
triacontanoic acid
Total
3.56
0.34
124
-------
Table 5-4. Particle-Phase Semivolatiles from an Institutional Oil-Fired Boiler: Emission
Factors (Campaign #2, July 2002)
Compound
Emission Factor
(jig/kg fuel)
Uncertainty
(jig/kg fuel)
dimethyl phthalate
diethyl phthalate
naphthalene
2-methylnaphthalene
1 -methy Inaphthalene
2,7-dimethylnaphthalene
1,3 -dimethy Inaphthalene
2,6-dimethy Inaphthalene
additional dimethylnaphthalenes
acenaphthylene
acenaphthene
fluorene
1-methy Ifluorene
additional methylfluorenes (peak 1)
additional methylfluorenes (peak 2)
phenanthrene
additional dimethylphenanthrenes
anthracene
methylanthracene - peak 1
methylanthracene - peak 2
methylanthracene - peak 3
methylanthracene - peak 4
octylcyclohexane
norpristane
decylcyclohexane
pristane
phytane
3.10
0.69
0.36
0.79
1.57
0.76
4.34
14.69
16.01
41.41
52.29
32.39
27.32
7.82
26.02
0.90
0.52
0.61
1.08
0.57
0.81
1.81
1.25
5.21
5.99
3.75
3.60
1.39
4.69
125
-------
Table 5-4. (Continued)
Emission Factor Uncertainty
Compound (ng/kg fuel) (ng/kg fuel)
tridecylcyclohexane 9.66
dibutyl phthalate 13.42 9.71
butyl benzyl phthalate 15.83 9.59
6/X2-ethylhexyl) phthalate 30.13 35.33
dioctyl phthalate
fluoranthene 1.89 1.64
pyrene 37.83 4.26
chrysene 7.90 0.39
benzo [a] anthracene
benzo[k]fluoranthene
benzo[b]fluoranthene
benzo [a]pyrene
nonadecylcyclohexane
squalane
indeno[l,2,3-cd]pyrene
dibenzo[a,h]anthracene
benzo[ghi]perylene
coronene
cholestane - peak 1
cholestane - peak 2
cholestane - peak 3
cholestane - peak 4
ABB-2OR-24S-methylcholestane
ABB-2OR-ethylcholestane
17A(H)-22,29,30-/r/Xnorhopane)
17(B)-21 A(H)-norhopane
17B(H)-21B(H)-hopane
17B(H)-21A(H)-hopane
126
-------
Table 5-4. (Continued)
Compound
17A(H)-2 lB(H)-hopane
w-decane (w-CIO)
w-undecane (w-Cll)
n-dodecane (»-C12)
w-tridecane (w-C13)
9H-fluoren-9-one
n-tetradecane (n-C14)
w-pentadecane («-C15)
w-hexadecane (w-C16)
n-heptadecane (n-C17)
1-octadecene
w-octadecane (w-C18)
2-methylnonadecane
3 -methy Inonadecane
w-nonadecane (w-C19)
w-eicosane (w-C20)
w-heneicosane (w-C21)
w-docosane (n-C22)
w-tricosane (w-C23)
/5o-docosane (C23)
awfe/'so-docosane (C23)
pyrene
anthraquinone
naphthalic anhydride
methy Ifluoranthene
retene
cyclopenta[c,d]acepyrene
benzanthraquinone
Emission Factor
(jig/kg fuel)
0.27
1.09
0.07
4.28
15.52
21.94
46.48
168.23
182.46
225.50
283.78
72.43
Uncertainty
(jig/kg fuel)
0.47
1.89
0.11
1.47
4.84
6.64
9.19
50.85
58.66
55.96
41.33
11.82
127
-------
Table 5-4. (Continued)
Compound
Emission Factor
(Hg/kg fuel)
Uncertainty
(Hg/kg fuel)
1-methylchrysene
w-tetracosane (»-C24
/5o-tricosane (C24)
anteiso-tricosane (C24)
w-pentacosane (»-C25)
/5o-tetracosane (C25)
awte/5o-tetracosane (C25)
w-hexacosane (w-C26)
/5o-pentacosane (C26)
awte/5o-pentacosane (C26)
w-heptacosane (w-C27)
/5o-hexacosane (C27)
awte/5o-hexacosane (C27)
/5o-heptacosane (C28)
awte/5o-heptacosane (C28)
/5o-octacosane (C29)
awte/5o-octacosane (C29)
w-octacosane (w-C28)
w-nonacosane (w-C29)
/5o-nonacosane (C30)
awfe/'so-nonacosane (C30)
squalene
indeno [ 1,2,3 -cd]fluoranthene
dibenzo [a,e]pyrene
w-triacontane («-C30)
n-hentriacontane (w-C31)
/5o-triacontane (C31)
awfe/'so-triacontane (C31)
403.25
209.06
160.30
105.60
81.32
41.14
73.59
1.58
1.56
40.02
16.78
11.33
40.25
1.15
1.90
128
-------
Table 5-4. (Continued)
Compound
/'so-hentriacontane (C32)
awfe/'so-hentriacontane (C32)
/5o-dotriacontane (C33)
awte/5o-dotriacontane (C33)
w-dotriacontane (w-C32)
w-tritriacontaine (w-C33)
n-tetratriacontaine (w-C34)
/'so-tritriacontane (C34)
awtewo-tritriacontane (C34)
n-pentatriacontane («-C35)
w-hexatracontane (w-C36)
w-tetracontane (n-C40)
hexanoic acid
succinic acid
octanoic acid
glutaric acid
nonanoic acid
adipic acid
decanoic acid
undecanoic acid
pimelic acid
suberic acid
dodecanoic acid
azelaic acid
tridecanoic acid
pinonic acid
phthalic acid
1,4-benzenedicarboxylic acid
Emission Factor
(jig/kg fuel)
0.65
0.36
0.51
4.16
21.42
4.94
15.30
6.86
11.19
5.01
9.53
7.60
8.47
8.00
2.42
21.30
0.94
36.74
Uncertainty
(jig/kg fuel)
0.76
0.63
2.12
0.58
4.19
0.23
6.16
2.53
5.20
0.32
1.65
4.61
30.13
1.33
0.22
129
-------
Table 5-4. (Continued)
Compound
Emission Factor
(Hg/kg fuel)
Uncertainty
(Hg/kg fuel)
1,3-benzenedicarboxylic acid
1,2-benzenedicarboxylic acid, 4-methyl
1,2,4-benzenetricarboxylic acid
benzenetetracarboxylic acid
abietic acid
pimaric acid
sandaracopimaric acid
isopimaric acid
dehydroabietic acid
sebacic acid
tetradecanoic acid
pentadecanoic acid
palmitoleic acid
hexadecanoic acid
heptadecanoic acid
linoleic acid
oleic acid
linolenic acid
octadecanoic acid
nonadecanoic acid
eicosanoic acid
docosanoic acid
tricosanoic acid
tetracosanoic acid
pentacosanoic acid
hexacosanoic acid
heptacosanoic acid
octacosanoic acid
64.33
437.83
115.71
10.43
21.64
156.06
18.04
17.99
6.53
101.47
3.93
2.81
3.16
2.12
23.28
15.47
8.81
21.40
63.02
3.84
4.91
0.81
23.19
0.89
0.60
2.40
130
-------
Table 5-4. (Continued)
Compound
Emission Factor
(Hg/kg fuel)
Uncertainty
(Hg/kg fuel)
nonacosanoic acid
triacontanoic acid
Total
3058.78
481.44
Gas-Phase Carbonyl Compounds
Analytical results for the carbonyl field samples for each of the three test days of
campaign #1 are shown in Table 5-5 (A, B, C). The DNPH-impregnated silica gel tubes were
sampled as pairs (in series), using the back tube of each pair as a check for breakthrough. Final
values are reported as the difference between the sum of the paired tubes sampling the residence
chamber and the sum of the paired tubes sampling the Dilution Air. At the bottom of each table,
the entry reported as "Total Speciated" is the total mass (front tube plus back tube) of the sum of
the specifically identified compounds; the final value represents the difference between the
131
-------
Table 5-5A. Carbonyl Compounds Analyzed by High Performance Liquid
Chromatography (Campaign #1, January 16, 2001)
Compound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/M-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenz-
aldehyde
diacetyl
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Total Speciated
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779.94-2
431-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
Residence
Chamber Pair
(Jig)
0.6150
0.3575
0.3585
ND
ND
0.0560
0.0450
0.0090
ND
ND
ND
ND
0.0560
ND
ND
ND
0.0720
0.2730
0.0060
0.0880
0.0140
0.2100
Dilution
Air
(^g)
0.0745
0.1980
0.2260
ND
ND
0.0470
0.0200
ND
0.0015
0.0120
0.0015
ND
0.0560
ND
ND
ND
0.0640
0.1990
ND
0.0700
0.0250
0.2430
2.1600
Residence
Chamber
Minus
Dilution Air
fog)
0.5405 ± 0.06
0.1595 ±0.00b
0.1325 ±0.01
ND
ND
0.0090 ± 0.00
0.0250 ± 0.00
0.0090 ±0.00
ND
ND
ND
ND
ND
ND
ND
ND
0.0080 ± 0.00
0.0740 ± 0.00
0.0060
0.0180 ±0.00
ND
ND
1.2375
% Total3
34.06 ±3.75
10.05 ±0.11
8.35 ±0.35
ND
ND
0.57 ±0.03
1.58 ±0.05
0.57 ±0.08
ND
ND
ND
ND
ND
ND
ND
ND
0.50 ±0.04
4.66 ±0.13
0.38 ±0.02
1.13±0.14
ND
ND
0.9225
132
-------
Table 5-5A. (Continued)
Compound CAS No.
Total Unspeciated
Total Speciated + Unspeciated
Mass emission rate of Speciated Carbonyls
Mass emission rate of Total Carbonyls (Speciated
(1/16/01)
Residence
Chamber Dilution
Pair Air
1.5375 0.8730
3.6975 2.1105
+ Unspeciated)
Residence
Chamber
Minus
Dilution Air
Gig)
0.6645
1.5870
0.84 mg/kg
fuel
1.42 mg/kg
fuel
ND = Not Detected
"Percent of each compound expressed as a percentage of Total Speciated + Unspeciated Carbonyl Compounds.
bCalculated value for analytical uncertainty is less than 0.01.
133
-------
Table 5-5B. Carbonyl Compounds Analyzed by High Performance Liquid
Chromatography (Campaign #1, January 17, 2001)
Compound CAS No.
formaldehyde 50-00-0
acetaldehyde 75-07-0
acetone 67-64-1
propionaldehyde 123-38-6
crotonaldehyde 4170-30-0
butyraldehyde 123-72-8
benzaldehyde 100-52-7
isovaleraldehyde 590-86-3
valeraldehyde 110-62-3
o-tolualdehyde 529-20-4
w-tolualdehyde 620-23-5
^-tolualdehyde 104-87-0
hexaldehyde 66-25-1
2,5-dimethylbenz- 5779-94-2
aldehyde
diacetyl 431-03-8
methacrolein 78-85-3
2-butanone 78-93-3
glyoxal 107-22-2
acetophenone 98-86-2
methylglyoxal 78-98-8
octanal 124-13-0
nonanal 124-19-6
Total Speciated
Total Unspeciated
Total Speciated + Unspeciated
Residence
Chamber
Pair
dig)
0.2870
0.2385
0.4085
ND
ND
0.0645
0.0330
ND
0.0045
ND
ND
ND
0.0585
ND
ND
ND
0.0640
0.2370
ND
0.0840
0.0220
0.1550
Dilution
Air
(ng)
0.0890
0.1790
0.2380
0.0005
ND
0.0485
0.0150
ND
0.0015
0.0120
0.0015
ND
0.0450
ND
ND
ND
0.0560
0.1720
ND
0.0590
0.0070
0.1430
1.6565
1.0515
2.7080
Residence
Chamber Minus
Dilution Air
(ng)
0.1980 ±0.02
0.0595 ± 0.00b
0.1705 ±0.007
ND
ND
0.0160 ±0.00
0.0180 ±0.00
ND
0.0045 ± 0.00
ND
ND
ND
0.0135 ±0.00
ND
ND
ND
0.0080 ± 0.00
0.0650 ± 0.00
ND
0.0250 ± 0.00
0.0150 ±0.00
0.0120 ±0.00
1.0520
0.730
1.7825
Mass emission rate of Speciated Carbonyls
Mass emission rate of Total Carbonyls
(Speciated +
Unspeciated)
% Total3
21. 39 ±2.36
6.429 ± 0.07
18.42 ±0.78
ND
ND
1.73 ±0.10
1.94 ±0.06
ND
0.49 ±0.05
ND
ND
ND
1.46 ±0.14
ND
ND
ND
0.86 ±0.07
7.02 ±0.19
ND
2.70 ±0.33
1.62 ±0.00
1.30 ±0.10
0.6045
0.3210
0.9255
0.56 mg/kgfuel
0.86mg/kgfuel
ND = Not Detected
Tercent of each compound expressed as a percentage of Total Speciated + Unspeciated Carbonyl Compounds.
bCalculated value for analytical uncertainty is less than 0.01.
134
-------
Table 5-5C. Carbonyl Compounds Analyzed by High Performance Liquid
Chromatography (Campaign #1, January 18, 2001)
Residence
Chamber Minus
Compound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/M-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenz-
aldehyde
diacetyl
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
Residence
Chamber
Pair
Oig)
0.2155
0.2885
0.2230
ND
ND
0.0865
0.0130
ND
ND
ND
ND
ND
0.0515
ND
ND
0.0630
0.2890
ND
0.0700
0.0060
0.1120
Dilution
Air
(^g)
0.1140
0.2390
0.1910
0.0005
ND
0.0590
0.0200
ND
ND
ND
ND
ND
0.0545
ND
ND
0.0590
0.2100
ND
0.0650
0.0090
0.1320
Dilution Air
(± Analytical
Uncertainty
(^g)
0.1015 ±0.01
0.0495 ± 0.00b
0.0320 ±0.00
ND
ND
0.0275 ± 0.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0040 ± 0.00
0.0790 ± 0.00
ND
0.0050 ± 0.00
ND
ND
% Total3
(± Analytical
Uncertainty
14.43 ±1.59
7.04 ± 0.08
4.55 ±0.19
ND
ND
3. 91 ±0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.57 ±0.05
11.23 ±0.31
ND
0.71 ±0.09
ND
ND
135
-------
Table 5-5C. (Continued)
Compound CAS No.
Total Speciated
Total Unspeciated
Total Speciated + Unspeciated
Mass emission rate of Speciated Carbonyls
Mass emission rate of Total Carbonyls (Speciated
Residence
Chamber
Pair
(ng)
1.4180
1.4795
2.8975
+ Unspeciated)
Dilution
Air
(ng)
1.1540
1.0400
2.1940
Residence
Chamber
Minus
Dilution Air
(± Analytical
Uncertainty
(ng)
0.2640
0.4395
0.7035
0.23 mg/kg fuel
0.56 mg/kg fuel
a Percent of each compound expressed as a percentage of Total Speciated + Unspeciated Carbonyl Compounds.
b Calculated value for analytical uncertainty is less than 0.01.
residence chamber air and dilution air. At the bottom of each table, the entry reported as "Total
Unspeciated" is the total mass (front plus back tube) of the compounds characterized as carbonyl
compounds but not identified as a specific compound because no analytical standard was
available; the final value represents the difference between residence chamber air and dilution air.
The entry reported as "Total Speciated + Unspeciated" includes the total mass (front tube plus
back tube) of specifically identified carbonyl compounds as well as unspeciated carbonyl
compounds; the final value represents the difference between residence chamber air and dilution
air.
Supporting data showing results for each individual carbonyl sampling tube (blanks, front and
back tubes) are included in Appendix I.
The total mass of the carbonyl compounds (Speciated, Unspeciated, and (Speciated +
Unspeciated) for each test day is summarized in Table 5-6. The speciated carbonyl compounds
decrease with each successive test day, as do the total (Speciated + Unspeciated) carbonyl
compounds. The unspeciated carbonyl compounds decrease from Day #1 to Day #2, but increase
from Day #2 to Day #3. This behavior says that one or more unidentified carbonyl compounds
increase in concentration from Day #2 to Day #3, while the speciated (i.e., identified) carbonyl
136
-------
compounds decrease in concentration. Fuel consumption increases over the three test days as
both
137
-------
Table 5-6. Total Mass of Carbonyl Compounds for Each Campaign #1 Test Day
Test Day
January 16,2001
Emission Rate
January 17, 2001
Emission Rate
January 18, 2001
Emission Rate
Fuel
Consumption
(kg)
6,569
6,934
7,926
Speciated Unspeciated
0.9225 ng 0.6645 \ig
0.84 mg/kg fuel
0.6045 ng 0.3210 \ig
0.56 mg/kg fuel
0.2640 ng 0.4395 \ig
0.23 mg/kg fuel
Speciated +
Unspeciated
1.5870 ng
1.42 mg/kg fuel
0.9255 ng
0.86 mg/kg fuel
0.7035 ng
0.56 mg/kg fuel
speciated and total (Speciated + Unspeciated) carbonyl compounds are decreasing. Emission
rates also show a decline over the three test days, even with increased consumption of fuel.
Gas-Phase Air Toxics Whole Air Samples
Air toxics values were determined only for campaign #1. Analytical results for the air
toxics canister samples are shown in Table 5-7. The ERG concurrent analysis produces analytical
results for both air toxics and nonmethane organic compound ozone precursors; the NMOC
results are presented separately. Table 5-7 shows only the air toxics compounds that were
observed, with the ambient sample analytical data included for reference. By comparison with
the ambient air sample, the concentrations of the air toxics compounds are seen to be very low,
with most of the compounds on the air toxics target list not observed in the field samples at
measurable levels. No consistent trends for the three test days are evident for these compounds.
Samples labeled "Dilution Air (DA)" reflect the dilution air entering the sample dilution system;
this dilution air has not been exposed to the stationary source matrix. The second canister for
each test day is labeled "Residence Chamber Air" and reflects the diluted stationary source matrix
at the end of the residence chamber (RC).
Supporting data for the air toxics analysis are shown in Appendix H.
138
-------
Table 5-7. Air Toxics Compounds (Campaign #1)
Compounds
acetylene
propylene
dichlorodifluoromethane
chloromethane
dichlorotetrafluoroethane
1,3 -butadiene
trichlorofluoromethane
methylene chloride
trichlorotrifluoroethane
methyl tert-butyl ether
methyl ethyl ketone
benzene
carbon tetrachloride
toluene
w-octane
styrene
o-xylene
1 , 3 ,5 -trimethy Ibenzene
1,2,4-trimethylbenzene
/>-dichlorobenzene
1 ,2,4-trichlorobenzene
CAS No.
74-86-2
115-07-1
75-71-8
74-87-3
1320-37-2
106-99-0
75-69-4
75-09-2
26253-64-8
1634-04-1
78-93-3
71-43-2
56-23-5
108-88-3
111-65-9
100-42-5
95-47-6
108-67-8
95-63-6
106-46-7
120-82-1
Ambient
1.52
2.20
2.45
0.98
0.13
0.16
1.56
0.42
0.65
0.15
12.31
1.29
0.53
2.11
0.22
0.11
0.86
0.31
0.88
0.10
0.28
RC-DA
1/16/01
Hg/m3
ND
0.08
ND
ND
ND
ND
0.05
0.11
ND
ND
ND
0.19
ND
0.08
0.18
ND
ND
0.03
0.18
ND
ND
RC-DA
1/17/01
1.27
0.07
ND
ND
ND
ND
ND
1.00
ND
ND
ND
0.33
0.05
0.05
ND
ND
0.04
0.13
0.33
ND
ND
RC-DA
1/18/01
ND
ND
ND
0.12
ND
ND
ND
0.16
ND
ND
ND
0.05
ND
0.05
ND
ND
ND
0.15
0.11
ND
ND
ND = Not Detected
Gas-Phase Speciated Nonmethane Organic Compounds
Nonmethane organic compounds were determined only for campaign #1. Analysis of
whole air samples of dilution air and residence chamber air using ERG's concurrent analysis
generated analytical data for speciated nonmethane organic compounds (SNMOC), shown in
Tables 5-8 (A, B, C). Analytical results are calculated as the difference between the weight of the
compound collected from the residence chamber minus the weight of the compound collected
from the dilution air, expressed as micrograms (|J-g). The weight percent of total SNMOC
(Speciated + Unspeciated) is also calculated. Mass emission rates of speciated SNMOC and total
(Speciated + Unspeciated) nonmethane organic compounds are also shown in Table 5-9.
Supporting data for the NMOC analysis are found in Appendix G. Samples labeled "Dilution
Air" reflect the dilution air entering the sample dilution system; this dilution air has not been
exposed to the stationary source matrix. The second canister for each test day is labeled
"Residence Chamber Air" and reflects the diluted stationary source matrix at the end of the
residence chamber. The general profiles of the collected concentrations of analytes do not
139
-------
Table 5-8A. SNMOC (Campaign #1, January 16, 2001)
Compound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
n-butane
/raws-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl-l-butene
w-pentane
isoprene
/raws-2-pentene
c/s-2-pentene
2-methyl-2-butene
2,2-dimethylbutane
cyclopentene
4-methyl-l-pentene
cyclopentane
2,3 -dimethylbutane
2-methylpentane
3-methylpentane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
Residence Chamber
minus Dilution Air ([j,g)
652.00 ±13.02
9.34 ±12.01
136.89 ±10.90
8. 14 ±6.90
18751.70 ±12.24
ND
511.43 ±6.23
48.81 ±4.00
31.20 ±5.90
275.28 ± 11.24
1.45 ±7.23
6.65 ±10.79
ND
191.81 ±16.13
21.81 ±9.01
ND
71.29 ±11.24
ND
11.63 ±9.12
22.03 ± 13.46
ND
38.63 ± 16.46
6.42 ±15.57
ND
26.90 ±7.68
ND
54.24 ± 8.79
80.69 ± 16.80
%Total
2.65 ±0.05
0.04 ± 0.05
0.56 ±0.04
0.03 ±0.03
76.36 ±0.05
ND
2.08 ±0.03
0.20 ± 0.02
0.13 ±0.02
1.12 ±0.05
0.01 ±0.03
0.03 ±0.04
ND
0.78 ±0.07
0.09 ±0.04
ND
0.29 ±0.05
ND
0.05 ± 0.04
0.09 ±0.05
ND
0.16 ±0.07
0.03 ± 0.06
ND
0.11 ±0.03
ND
0.22 ± 0.04
0.33 ±0.07
140
-------
Table 5-8A. (Continued)
Compound
2-methyl-l-pentene
1-hexene
2-ethyl-l-butene
n-hexane
/raws-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3 -dimethylpentane
3 -methy Ihexane
1-heptene
2,2,4-trimethylpentane
w-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3 ,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
w-octane
ethylbenzene
7w-xylene//>-xylene
styrene
o-xylene
CAS No.
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
Residence Chamber
minus Dilution Air ([j,g)
ND
17.72 ± 17.01
ND
843.46 ±12.90
ND
ND
153.95 ±10.68
11.74 ±13. 35
137.35 ±8.45
ND
88.42 ± 2.22
2.00 ±11. 12
ND
ND
38.75 ± 11.24
32.77 ±5.67
27.56 ±10.79
ND
37.63 ±7.79
54.04 ±4.45
ND
1.22 ±4.23
ND
14.52 ±2.22
ND
ND
ND
14.30 ±3.00
%Total
ND
0.07 ± 0.07
ND
3.43 ±0.05
ND
ND
0.63 ± 0.04
0.05 ±0.05
0.56 ±0.03
ND
0.36 ±0.01
0.01 ±0.05
ND
ND
0.16 ±0.05
0.13 ±0.02
0.11 ±0.04
ND
0.15 ±0.03
0.22 ± 0.02
ND
0.00a±0.02
ND
0.06 ±0.01
ND
ND
ND
0.06 ±0.01
141
-------
Table 5-8A. (Continued)
Compound CAS No.
1-nonene 124-11-8
n-nonane 111 -84-2
isopropylbenzene 98-82-8
a-pinene 80-56-8
n-propylbenzene 103-65-1
/w-ethyltoluene 620-14-4
^-ethyltoluene 622-96-8
1,3,5-trimethylbenzene 108-67-8
o-ethyltoluene 611-14-3
p-pinene 127-91-3
1,2,4-trimethylbenzene 95-63-6
1-decene 872-05-9
w-decane 124-18-5
1,2,3-trimethylbenzene 526-73-8
/w-diethylbenzene 141-93-5
^-diethylbenzene 105-05-5
1-undecene 821-95-4
n-undecane 1120-21-4
1-dodecene 112-41-4
w-dodecane 112-40-3
1-tridecene 2437-56-1
w-tridecane 629-50-5
Total Speciated SNMOC
Total Unspeciated SNMOC
Total Speciated + Unspeciated SNMOC
Residence Chamber
minus Dilution Air (jig)
21.70 ±2.34
18.27 ±2.34
ND
ND
11.40 ±2.22
90.09 ±5. 12
58.88 ±5.90
51.48 ±3.23
61. 11 ±3.45
ND
100.52 ±3.23
ND
ND
58.88 ±2.67
16.94 ±1.45
ND
ND
140.43 ±2.11
ND
ND
ND
ND
Mass Emission Rate of Speciated Nonmethane Organic Compounds
Mass Emission Rate of Total (Speciated
Compounds
+ Unspeciated) Nonmethane Organic
%Total
0.09 ±0.01
0.07 ±0.01
ND
ND
0.05 ±0.01
0.37 ±0.02
0.24 ± 0.02
0.21 ±0.01
0.25 ±0.01
ND
0.41 ±0.01
ND
ND
0.24 ±0.01
0.07 ±0.01
ND
ND
0.57 ±0.01
ND
ND
ND
ND
23.40 ng/m3
2.36 ng/m3
25.76 ng/m3
0.25 mg/kg fuel
0.27 mg/kg fuel
"Calculated value less than 0.00.
142
-------
Table 5-8B. SNMOC (Campaign #1, January 17, 2001
Compound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/1 -butene
1,3 -butadiene
n-butane
/raws-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl-l-butene
w-pentane
isoprene
/raws-2-pentene
c/s-2-pentene
2-methyl-2-butene
2,2-dimethylbutane
cyclopentene
4-methyl-l-pentene
cyclopentane
2,3 -dimethylbutane
2-methylpentane
3-methylpentane
2-methyl-l-pentene
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
Residence Chamber
Minus Dilution Air ([j,g)
1773.89 ±12.56
1335.54 ±11.60
1974.33 ± 10.52
154.47 ±6.66
2894.27 ± 11.81
ND
39.96 ±6.01
131. 87 ±3.87
ND
82.53 ± 10.84
42.90 ±6.98
48.21 ±10.41
ND
106.50 ±15.57
37.38 ±8.70
ND
64.35 ± 10.84
1.40 ±1.29
26.97 ± 8.80
63.60 ±12.99
ND
126.88 ±15. 89
47.78 ±15.03
ND
37.49 ±7.41
54.59 ±18.36
99.80 ± 8.48
106.18 ± 16.21
ND
% Total
10.80 ±0.08
8. 12 ±0.07
12.02 ± 0.06
0.94 ±0.04
17.62 ± 0.07
ND
0.24 ± 0.04
0.80 ±0.02
ND
0.50 ±0.07
0.26 ± 0.04
0.29 ±0.06
ND
0.65 ±0.09
0.23 ±0.05
ND
0.39 ±0.07
0.01 ±0.01
0.16 ±0.05
0.39 ±0.08
ND
0.77 ±0.10
0.29 ±0.09
ND
0.23 ±0.05
0.33±0.11
0.61 ±0.05
0.65 ±0.10
ND
143
-------
Table 5-8B. (Continued)
Compound
1-hexene
2-ethyl-l-butene
w-hexane
/ra«5-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3 -dimethylpentane
3 -methy Ihexane
1-heptene
2,2,4-trimethylpentane
w-heptane
methylcyclohexane
2,2,3-trimethylpentane
2,3 ,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
n-octane
ethylbenzene
/w-xylene//>-xylene
styrene
o-xylene
1-nonene
CAS No.
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
Residence Chamber
Minus Dilution Air ([j,g)
84. 16 ±16.42
ND
451. 16 ±12.45
ND
ND
148.22 ±10.31
63.71 ±12.88
157.55 ±8.16
ND
42.47 ±2.15
85. 16 ±10.74
16.79 ±9.02
ND
58.72 ±10.84
84.19 ±5.48
32.50 ±10.41
ND
42.69 ±7.52
61.08 ±4.29
32.18 ±4.19
47.89 ±4.08
ND
226.36 ±2. 15
32.82 ±2.90
40.38 ±4.51
53.31 ±7.41
43.63 ±2.90
ND
% Total
0.51 ±0.10
ND
2.75 ±0.08
ND
ND
0.90 ±0.06
0.39 ±0.08
0.96 ±0.05
ND
0.26 ±0.01
0.52 ±0.07
0.10 ±0.05
ND
0.36 ±0.07
0.51 ±0.03
0.20 ± 0.06
ND
0.26 ±0.05
0.37 ±0.03
0.20 ±0.03
0.29 ±0.02
ND
1.38 ±0.01
0.20 ± 0.02
0.25 ± 0.03
0.32 ±0.05
0.27 ± 0.02
ND
144
-------
Table 5-8B. (Continued)
Compound
w-nonane
isopropylbenzene
a-pinene
n-propylbenzene
/w-ethyltoluene
/>-ethyltoluene
1 ,3 ,5-trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
w-decane
1,2,3 -trimethylbenzene
/w-diethylbenzene
/>-diethylbenzene
1-undecene
w-undecane
1-dodecene
w-dodecane
1-tridecene
w-tridecane
Total Speciated SNMOC
Total Unspeciated SNMOC
CAS No.
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence Chamber
Minus Dilution Air (jig)
100.12 ±2.55
37.39 ±4.29
ND
26.76 ±2. 15
74.33 ±4.94
43.01 ±5.69
126.13 ±3. 11
95. 13 ±3. 33
114.44 ±2.25
174.56 ±3. 11
ND
66.13 ±2.36
78.99 ±2.58
78.03 ± 1.40
67.62 ± 1.61
ND
150.48 ±2.04
93.63 ±4.51
3950.78 ±4.62
ND
93.63 ±4.62
Total Speciated + Unspeciated SNMOC
Mass Emission Rate of Speciated Nonmethane Organic Compounds
Mass Emission Rate of Total
Compounds
(Speciated
+ Unspeciated) Nonmethane Organic
% Total
0.61 ±0.01
0.23 ±0.03
ND
0.16 ±0.01
0.45 ±0.03
0.26 ±0.03
0.77 ± 0.02
0.58 ±0.02
0.70 ±0.01
1.06 ±0.02
ND
0.40 ±0.01
0.48 ±0.02
0.48 ±0.01
0.41 ±0.01
ND
0.92 ±0.01
0.57 ±0.03
24.05 ±0.03
ND
0.57 ±0.03
29.48 ug/m3
ND
29.48 ug/m3
0.30 ug/kg fuel
0.30* ug/kg fuel
* More Unspeciated NMOC was found in dilution air than in residence chamber samples. Unspeciated analysis was determined invalid and not
used in this calculation due to an unidentified contaminant.
145
-------
Table 5-8C. SNMOC (Campaign #1, January 18, 2001)
Compound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
n-butane
/raws-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl-l-butene
w-pentane
isoprene
/raws-2-pentene
c/s-2-pentene
2-methyl-2-butene
2,2-dimethylbutane
cyclopentene
4-methyl-l-pentene
cyclopentane
2,3 -dimethylbutane
2-methylpentane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
Residence Chamber
Minus Dilution Air ([j,g)
418.90 ±13. 35
222.76 ± 12.32
ND
268.93 ± 7.07
23162.61 ±12.55
ND
ND
48.57 ±4.11
ND
ND
1.14 ±7.42
ND
ND
ND
11.24 ±9.24
ND
1.83 ±11.52
ND
6.13 ±9.36
ND
ND
12.38 ±16.89
16.57 ±15.97
ND
6.13 ±7.87
7.27 ±19.51
612.16 ±9.01
% Total
1.37 ±0.04
0.73 ± 0.04
ND
0.88 ±0.02
75.68 ±0.04
ND
ND
0.16 ±0.01
ND
ND
0.00a±0.02
ND
ND
ND
0.04 ±0.03
ND
0.01 ±0.04
ND
0.02 ± 0.03
ND
ND
0.04 ± 0.06
0.05 ± 0.05
ND
0.02 ±0.03
0.02 ± 0.06
2.00 ±0.03
146
-------
Table 5-8C. (Continued)
Compound
3-methylpentane
2-methyl-l-pentene
1-hexene
2-ethyl-l-butene
n-hexane
trans-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3 -dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
w-heptane
methylcyclohexane
2,2,3-trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
w-octane
ethylbenzene
7w-xylene//>-xylene
CAS No.
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
Residence Chamber
Minus Dilution Air (jig)
33.48 ±17.22
ND
2. 17 ±17.46
ND
362.46 ± 13.23
ND
ND
75.13 ±10.95
1.14 ±13.69
33.03 ±8.67
1.48 ±19.40
0.91 ±2.28
ND
ND
41.76 ±9.47
6.70 ± 11.52
22.13 ±5.82
11.47 ±11.07
ND
1.14 ±7.99
ND
ND
ND
ND
43.81 ±2.28
ND
ND
% Total
0.11 ±0.06
ND
0.01 ±0.06
ND
1.18 ±0.04
ND
ND
0.25 ± 0.04
0.00 ± 0.04
0.11 ±0.03
0.00 ± 0.06
0.00 ±0.01
ND
ND
0.13 ±0.03
0.02 ± 0.04
0.07 ± 0.02
0.04 ± 0.04
ND
0.00 ±0.03
ND
ND
ND
ND
0.14 ±0.01
ND
ND
147
-------
Table 5-8C. (Continued)
Compound
styrene
o-xylene
1-nonene
w-nonane
isopropylbenzene
a-pinene
w-propylbenzene
/w-ethyltoluene
/>-ethyltoluene
1 ,3 ,5-trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
n-decane
1 ,2,3 -trimethylbenzene
/w-diethylbenzene
/>-diethylbenzene
1-undecene
w-undecane
1-dodecene
w-dodecane
1-tridecene
w-tridecane
Total Speciated SNMOC
Total Unspeciated SNMOC
Total Speciated + Unspeciated
CAS No.
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
SNMOC
Residence Chamber
Minus Dilution Air (jig)
58.44 ±7.87
12.26 ±3.08
0.91 ±2.40
32.69 ±2.40
1.03 ±4.56
ND
ND
ND
1.14 ±6.04
42.44 ±3.31
21.68 ±3.54
104.39 ±2.40
44.27 ±3.31
ND
56.19 ±2.51
ND
52.19 ±1.48
36.54 ±1.71
ND
11.16 ±2.11
78.29 ±4.79
2067.01 ±4.90
ND
93. 95 ±4.90
Mass Emission Rate of Speciated Nonmethane Organic Compounds
Mass Emission Rate of Total (Speciated + Unspeciated)
Compounds
Nonmethane Organic
% Total
0.19 ±0.03
0.04 ±0.01
0.00 ±0.01
O.lliO.Ol
0.00 ±0.01
ND
ND
ND
0.00 ± 0.02
0.14 ±0.01
0.07 ±0.01
0.34 ±0.01
0.14 ±0.01
ND
0.18 ±0.01
ND
0.17 ±0.00
0.12 ±0.01
ND
0.23 ±0.01
0.26 ± 0.02
6.75 ±0.02
ND
0.31 ±0.02
48.28 ng/m3
4.41 ng/m3
52.69 ng/m3
0.50 mg/kg fuel
0.55 mg/kg fuel
"Calculated value less than 0.00.
148
-------
Table 5-9. Total Mass of Nonmethane Organic Compounds for Each Campaign #1
Test Day
January 16, 2001
Emission Rate
January 17,2001
Emission Rate
January 18,2001
Emission Rate
Mass of Fuel
Consumed (kg) Speciated Unspeciated
6,569 1617 mg 163 mg
0.25 mg/kg fuel
6,934 2085 mg Oa
0.23 mg/kg fuel
7,926 3961 mg 361 mg
0.50 mg/kg fuel
Speciated +
Unspeciated
1780 mg
0.27 mg/kg fuel
2085 mg
0.28 mg/kg fuel
4322 mg
0.55 mg/kg fuel
"Weight of unspeciated NMOC in dilution air was higher than the weight of unspeciated NMOC in the residence
chamber air for January 17, 2001.
parallel the results for the carbonyl compounds. Weight % for each analyte was calculated by
dividing the value of that analyte by the total speciated plus unspeciated NMOC value. The
analytical uncertainty was calculated using the standard deviation of the replicate determinations
performed in the determination of the method detection limits. Both the "Total" and "Speciated"
NMOC values are calculated on the basis of subtraction of analyte in the dilution air (DA) from
the analyte collected in the residence chamber (RC) air. Because the EPA dilution sampling
system was operated at a dilution factor of approximately 40 for both campaign #1 and campaign
#2, dilution air in 40-fold excess is present in the final sample. In some instances, when the sum
of the speciated (or unspeciated) analytes in the dilution air is subtracted from the sum of the
speciated (or unspeciated) analytes from the residence chamber, a negative value is obtained. The
total value is obtained by adding the sum of the values for the residence chamber minus dilution
air for speciated analytes to the sum of unspeciated analytes for the residence chamber minus
dilution air. If the (RC-DA) difference is negative, the value for Total NMOC is less than the
value for speciated NMOC (as in data from January 16, 2001 and January 17, 2001). Complete
NMOC calculations are shown in Appendix G for each day; NMOC emission factor calculations
are shown in Appendix B. Note that on January 16, 2001, the mass of analyte in total combustion
air for speciated NMOC is 0.025004 |ig; for speciated and unspeciated NMOC the value is
0.020531 |ig. The total emission factor is therefore less than the speciated emission factor.
149
-------
The mass of total speciated NMOC results and the total speciated plus unspeciated results
have been used to calculate the mass emission rates for SNMOC as well as speciated plus
unspeciated NMOC (Table 5-9). Samples taken from the residence chamber were corrected for
the SNMOC observed in the dilution air to determine the total SNMOC collected. These values
were used to calculate a mass emission rate for SNMOC and speciated plus unspeciated NMOC
for each test day. The supporting calculations are shown in Appendix G.
The profile of the concentrations for the SNMOC differs from the profile of the
concentrations for the carbonyl compounds. Both speciated and total carbonyl compounds show
a decreasing trend over the three test days, while the concentration of the unspeciated carbonyl
compounds increases on the third test day. For all SNMOC (speciated, unspeciated, and
speciated plus unspeciated), concentrations drop on the second test day and reach their highest
level on the third test day. During these compound concentration changes, fuel consumption is
increasing on each test day, as shown in Table 5-9.
Particle Size Distribution Data
The SMPS system was operated on all three test days of campaign #1, collecting data on
particle size distribution in the range below 2.5 |im (the range monitored was 10 nm to 392 nm),
with one complete scan over the entire range every three minutes. The analytical data are
presented in Table 5-10 and are presented graphically as a plot of midpoint diameter of the
particles vs counts (an indirect version of number of particles in each size range) or as midpoint
diameter in nanometers vs number of particles (Figures 5-1 through 5-3).
150
-------
Table 5-10. Particle Size Diameter Measurements, TSI SMPS (Campaign #1,
January 16-18, 2001)
Particle Size Range (10-392 nm)
Channel Range (32 - 83)
Channels per decade: 32
Weighted by number
Units: Counts
Average Values for All Scans
Channel Sample Time Counts Counts Counts
Midpoint Diameter (nm) (1/16/01) (1/17/01) (1/18/01)
1
2
o
J
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
10.3663
11.1397
11.9709
12.8640
13.8237
14.8551
15.9634
17.1544
18.4342
19.8096
21.2875
22.8757
24.5824
26.4165
28.3874
30.5053
32.7812
35.2269
37.8552
40.6794
43.7144
101.6
75.2
80.3
110.8
80.9
74.1
60.4
505
448.8
271.7
259.1
248.2
324.9
492.6
650.5
689.8
498.1
362
337.5
337.7
341.7
96083.3
156779.5
245424.3
355450.4
484897.1
647382.2
841926
1047940
1247522
1420894
1547679
1593648
1541539
1401504
1188134
924710.5
654602
411559.7
227993.9
109850.2
45115.7
117694.3
201348.7
314480.1
466870.4
659765.6
885842.2
1155580
1451086
1743655
2000971
2221012
2358421
2391306
2292371
2066818
1748867
1364195
978867
638168.4
372354.5
193396.2
151
-------
Table 5-10. (Continued)
Channel Sample Time
Midpoint Diameter (nm)
22
23
24
25
26
27
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
46.9759
50.4087
54.2469
58.2942
62.6434
67.317
83.5363
89.7687
96.4662
103.663
111.397
119.709
128.64
138.237
148.551
159.634
171.544
184.342
198.096
212.875
228.757
245.824
264.165
283.874
305.053
327.812
352.269
378.552
Counts
(1/16/01)
338.1
279
290.8
250
250.8
216.1
210.7
199.5
232.2
206.1
185.4
219.8
167.1
169.2
154.8
164.5
162.6
127.4
146.3
131.3
121.1
130.8
148.5
101.6
94.6
107.2
91.5
109.9
Counts
(1/17/01)
16148
5514.5
2282.8
2159.4
1231
1053.1
822.6
2625.5
2181.4
1297
1258.3
952.2
884.4
914.1
785.7
724.8
668.5
649.4
614
761.2
592.7
3130.4
2964.6
765.9
501.2
454.4
458.9
452.7
Counts
(1/18/01)
89624.2
40419.2
21423.4
16296.9
15712.8
15653.5
17714.2
18073.2
18423.3
18337.5
18547.1
18312.1
17837.9
17157.6
16610.4
15352.5
14226.8
12581.4
11571.9
10084.2
8847.7
7273.6
6256.8
5033.7
4185.9
3394.8
2734.5
2189.1
152
-------
1-16-01
800 i
700 -
600 -
500 -
to
c 400
o
o
300
200 -
100 -
10 13 16 20 25 31 38 47 58 72 90 111 138 172 213 264 328
Midpoint Diameter, namometers
Figure 5-1. Graphical presentation of particle size data, SMPS (January 16, 2001).
1-17-01
1800000 -,
1600000
i^nnnnn
-lonnnnn
1000000
800000
onnnnn
n -
n
n
n
n
L._
10 13 16 20 25
31 38 47 58 72 90 111 138 172 213 264 328
Midpoint Diameter, namometers
Figure 5-2. Graphical presentation of particle size data, SMPS (January 17, 2001).
153
-------
The profile observed on Day 1 (January 16, 2001) appears to be an outlier with respect to
1-18-01
o
o
3000000 -,
9c>nnnnn
onnnnnn -
i^nnnnn -
mnnnnn -
Cflflflflfl
n -
i
1
n
J
J
n
n
n
n
u U n n n
10 13 16 20 25 31 38 47 58 72 90 111 138 172 213 264 328
Midpoint Diameter, namometers
Figure 5-3. Graphical presentation of particle size data, SMPS (January 18, 2001).
the other two test days: the shape of the plot is very different from the plots obtained on the other
two days, and the number of counts observed in each channel is approximately four orders of
magnitude lower on Day 1 than on the other two test days. The SMPS instrumental operating
parameters appeared to be normal and there was no obvious indication of instrumental
malfunction. There is not an obvious explanation for the outstandingly low signal level on Day 1.
On Day 2 (January 17, 2001) and Day 3 (January 18, 2001), the shapes of the profiles appear to
be qualitatively similar. However, the signal maximum on Day 2 is observed at approximately
1.6 x 106 counts, at a midpoint diameter of 23 nm. On Day 3, the signal maximum occurs at
approximately 2.4 x 106 counts (50% higher than the signal level on Day 2), at a slightly larger
midpoint diameter (approximately 25 nm).
154
-------
During campaign #2, particle size data were collected using an Electrical Low Pressure
Impactor (ELPI). The particle size distribution was bimodal. The greatest amount of mass was
found on the second stage, but it is not clear where the peak of the actual mode is located, given
the data collected. ELPI data are shown in Table 5-11 and graphically in Figures 5-4, 5-5, and
5-6. The three-day average is shown graphically in Figure 5-7. Note that the SMPS gives an
electrical mobility diameter and the ELPI gives an aerodynamic diameter, so the two values
should not necessarily agree.
155
-------
Table 5-11. Gravimetric Data, ELPI (Campaign #2, July 9-11, 2002) PM-2.5 Mass
Concentration by Size
Stage
1
2
3
7
8
9
10
11
12
13
Total Mass
D50
(nm)
30.0
61.0
105.0
645.0
1000.0
1630.0
2480.0
4020.0
6760.0
10260.0
Concentration
Di
(nm)
42.78
80.03
132.82
803.12
1276.71
2010.57
3157.47
5212.98
8328.12
(mg/m3)
Stage Mass Concentration (mg/m3)
7/9/02 7/10/02 7/11/02 Mean
0.0061
0.0064
0.0040
0.0007
0.0003
0.0036
0.0023
0.0017
0.0017
0.0000
0.0331
0.0028
0.0042
0.0017
0.0010
0.0007
0.0014
0.0000
0.0007
0.0012
0.0007
0.0170
0.0172
0.0316
0.0120
0.0005
0.0007
0.0010
0.0002
0.0000
0.0002
0.0002
0.0741
0.0087
0.0140
0.0059
0.0008
0.0006
0.0020
0.0008
0.0008
0.0010
0.0003
0.0414
156
-------
Stage mass concentration (Test 7/9/02)
0.007 -,
Onnfi
^2 n nnc:
B)
5 n nn/i
•43
Ł
fi n nm
o
o
(A
(A
n n nrto
Onm
n nnn -
1 2 3 4 5 6 7 8 9 10 11 12 13
Stage No.
Figure 5-4. ELPI Mass Concentration by Stage (July 9, 2002)
Stage mass concentration (Test 7/10/02)
0.005 -
n nr\A
co"
"^ n nn^
E
c
IE
c
8
n nnn -
1 2 3 4 5 6 7 8 9 10 11 12 13
Stage No.
Figure 5-5. ELPI Mass Concentration by Stage (July 10, 2002)
157
-------
Stage mass concentration (Test 7/11/02)
Mass concentration (mg/m3)
0
0
0
o
0
0
o
n
035 -
rnn -
005
nnn -
] 1 1 ] , i
1234567
Stage No.
9 10 11 12 13
Figure 5-6. ELPI Mass Concentration by Stage (July 11, 2002)
Stage mass concentration (Three-Day Average)
0.016 --
u.uit -
CO
^)
c
o
Ł n nna
c
01
u
c
§ 0 006
t/>
in
to
n nnn -
1 ,
1 2 3 4 5 6 7 8 9 10 11 12 13
Stage No.
Figure 5-7. ELPI Mass Concentration by Stage (Three-Day Average)
158
-------
Section 6
Quality Assurance/Quality Control
A detailed description of the objectives and activities of the institutional oil-fired boiler
tests is presented in Sections 3 and 4 of this report. Separate quality assurance project plans for
the source sampling and PM-2.5 sample analyses were developed for each of the two testing
campaigns (i.e., QTRAX numbers 9905115 and 9900216) and were approved by EPA/NRMRL.
The testing that was conducted adhered to the specifications of these two QAPPS. QA
procedures for the analyses of gaseous nonmethane organic compounds and air toxics were
followed as prescribed by EPA Compendium Method TO-1512. Analyses of the gaseous carbonyl
compounds adhered to the QA procedures of EPA Compendium Method TO-11 A11.
A summary of the quality control measures, acceptance criteria, and whether these criteria
were achieved is provided in Tables 6-1 through 6-7 for source sampling activities, concurrent
speciated NMOC/air toxics analyses, carbonyl analyses, PM mass measurement, PM elemental
analysis, PM inorganic ion analysis, and semivolatile organic compound analysis, respectively.
Sampling and analytical procedures for critical measurements are presented in Section 4.
In field sampling with the dilution sampling system, the following quality control procedures
were implemented:
• A leak check of the dilution sampling system was performed before field testing
was initiated;
• Pitot tubes and meter boxes were calibrated;
• The analytical balance(s) were calibrated;
• Flow control collection devices for the canisters were calibrated using a primary
flow standard;
• Multipart forms recording field conditions and observations were used for
canisters and carbonyl samples; and
• Strict chain of custody documentation for all field samples was maintained.
159
-------
Table 6-1. Sample Collection Equipment: Quality Criteria
Equipment
Effect
Acceptance
Criteria
Criteria
Achieved ?
Orifice meters (volumetric gas flow
calibration)
Venturi meters (volumetric gas flow
calibration)
Flow transmitter (Heise gauge with
differential pressure)
Analytical Balances
Thermocouples
Relative humidity probes
Sampling equipment leak check and
calibration (before each sampling
run)
Sampling equipment field blanks
Ensures the accuracy of flow
measurements for sample collection
Ensures the accuracy of flow
measurements for sample collection
Ensures the accuracy of flow
measurements for sample collection
Ensures control of bias for all project
weighing
Ensures sampler temperature control
Ensures the accuracy of moisture
measurements in the residence chamber
Ensures accurate measurement of sample
volume
Ensures absence of contamination in
sampling system
±1%
± 1% of
reading
±0.5% of
range
Calibrated
with Class S
weights
±1.5°C
±2%
relative
humidity
1%
< 5.0% of
sample
values
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
160
-------
Table 6-2. Carbonyl Analysis: Quality Criteria
Parameter
HPLC Column
Efficiency
Linearity Check
Quality Control
Check
Analyze SSQC
Analyze 5-point
calibration curve and
SSQC in triplicate
Frequency
At setup and one per sample
batch
At setup or when calibration
check does not meet
acceptance criteria
Acceptance Criteria
Resolution between acetone and
propionaldehyde > 1.0
Column efficiency > 500 plates
Correlation coefficient >0.999,
relative error for each level against
calibration curve ± 20% or less
Corrective Action
Eliminate dead volume,
backflush, or replace
column; repeat analysis
Check integration, re-
integrate or re-calibrate
Criteria
Achieved ?
Yes
Retention time
Calibration
Check
Analyze calibration
midpoint
Analyze midpoint
standard
Once per 10 samples
Once per 10 samples
Relative Error
Intercept acceptance should be
< 10,000 area counts/compound;
correlates to 0.06 mg/mL
Acetaldehyde, Benzaldehyde,
Hexaldehyde within retention time
window established by determining
3 a or ±2% of the mean calibration
and midpoint standards, whichever
is greater
85-115% recovery
Check integration, re-
integrate or re-calibrate
Check system for plug,
regulate column
temperature, check
gradient and solvents
Check integration, re-
calibrate or re-prepare
standard, re-analyze
samples not bracketed
by acceptable standard
Yes
Yes
Yes
Yes
Yes
Calibration
Accuracy
SSQC
Once after calibration in
triplicate
Analyze 0.1 |_ig/mL Once after calibration in
standard triplicate
85-115% recovery
±25% difference
Check integration; re-
calibrate or re-prepare
standard, re-analyze
samples not bracketed
by acceptable standard
Yes
-------
Table 6-2. (Continued)
Parameter
System Blank
Duplicate
Analyses
Replicate
Analyses
MS/MSD
Quality Control
Check
Analyze acetonitrile
Duplicate Samples
Replicate injections
Analyze MS/MSD
Frequency
Bracket sample batch, one at
beginning and one at end
As collected
Duplicate samples only
One MS/MSD per 20
samples
Acceptance Criteria
Measured concentration
<5xMDL
± 20% difference
< 10% RPD for concentrations
greater than 1.0 [ig/mL
80-120% recovery for all
compounds
Corrective Action
Locate contamination
and document levels of
contamination in file
Check integration;
check instrument
function; re-analyze
duplicate samples
Check integration,
check instrument
function, re-analyze
duplicate samples
Check calibration,
check extraction
procedures
Criteria
Achieved ?
Yes
Yes
Yes
Yes
>-? HPLC = High Performance Liquid Chromatography
to SSQC = Second Source Quality Control
MDL = Method Detection Limit
RPD = Relative Percent Difference
MS/MSD = Method Spike/Method Spike Duplicate
-------
Table 6-3. Air Toxics and SNMOC Analysis: Quality Criteria
Quality Control Check
Frequency
Acceptance Criteria
Corrective Action
Criteria
Achieved ?
Air Toxics Analysis
BFB Instrument Tune Check Daily prior to calibration check
Five-point calibration
bracketing the expected sample
concentration
Calibration check using mid-
point of calibration range
System Blank
LCS
Replicate Analysis
Samples
SNMOC Analysis
System Blank Analysis
Following any major change,
repair, or maintenance if daily
quality control check is not
acceptable. Calibration is valid
for six weeks if calibration
check criteria are met.
Daily
Daily following tune check and
calibration check
Daily
All duplicate field samples
All samples
Daily, following calibration
check
Evaluation criteria in data system
software; consistent with Method TO-15
RSD of response factors < 30%
RRTs for target peaks ± 0.06 units from
mean RRT
Response factor < 30% bias from
calibration curve average response factor
0.2 ppbv/analyte or MDL, whichever is
greater
IS area response ±40% and ±0.33 min of
most recent calibration check
Recovery limits
70% - 130%
IS RT ±0.33 min of most recent
calibration
<30% RPD for compounds >5xMDL
IS RT ±0.33 min of most recent
calibration
20 ppbC total
Retime mass spectrometer;
clean ion source and
quadrupoles
Repeat individual sample
analysis; repeat linearity
check; prepare new
calibration standards and
repeat analysis
Repeat calibration check;
repeat calibration curve
Repeat analysis with new
blank; check system for
leaks, contamination; re-
analyze blank.
Repeat analysis; repeat
calibration curve.
Repeat sample analysis
Repeat analysis
Repeat analysis; check
system for leaks; clean
system with wet air
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
-------
Table 6-3. (Continued)
Quality Control Check
Frequency
Acceptance Criteria
Corrective Action
Criteria
Achieved ?
Multiple point calibration
(minimum 5); propane
bracketing the expected sample
concentration range
Calibration check: midpoint of
calibration curve spanning the
carbon range (C2-C10)
Replicate analysis
Prior to analysis and monthly
Daily
All duplicate field samples
Correlation coefficient
(r2) >0.995
Response for selected hydrocarbons
spanning the carbon range within ±30%
difference of calibration curve slope
Total NMOC within ±30% RSD
Repeat individual sample
analysis; repeat linearity
check; prepare new
calibration standards and
repeat
Repeat calibration check;
repeat calibration curve.
Repeat sample analysis
Yes
Yes
Yes
BFB = 1,4-Bromofluorobenzene
RSD = Relative Standard Deviation
RRT = Relative Retention Time
MDL = Method Detection Limit14
IS = Internal Standard
LCS = Laboratory Control Standard
RPD = Relative Percent Difference
Table 6-4. PM Mass Measurements:
Parameter Quality Control
_ Check
Quality Criteria
Frequency
Acceptance Criteria
Corrective Action
Criteria
Achieved ?
Deposition on Filter Analyze Laboratory
during Conditioning Filter Blank
Laboratory Stability Analyze Laboratory
Control Filter
Balance Stability
Analyze Standard
Weights
Bracket sample batch, one at
beginning and one at end
Bracket sample batch, one at
beginning and one at end
Bracket sample batch, one at
beginning and one at end
Mass within
±15 mg of previous
weight
Mass within
±15 mg of previous
weight
Mass within
±3 mg of previous weight
Adjust mass for deposition
Adjust mass to account for
laboratory difference
Perform internal calibration of
balance, perform external
calibration of balance
Yes
Yes
Yes
-------
Table 6-5. Elemental Analysis: Quality Criteria
Parameter
Performance
Evaluation check
Quality Control
Check
Freauencv
Analyze Monitor Once per month
Sanmle
Table 6-6. Water-Soluble Ion Analysis
Quality Control
Parameter Check
Linearity Check
System Dead
Volume
Analyze 4-point
calibration curve
Analyze water
: Quality Criteria
Freauencv
At setup or when
calibration check
does not meet
acceptance criteria
Bracket sample
batch, one at
Corrective
Acceotance Criteria Action
< 2% change in each element from previous Recalibrate
measurement
Accentance Criteria Corrective Action
Correlation coefficient Recalibrate
>0.999
Within 5% of previous Check system temperature, eluent, and
analysis columns
Criteria
Achieved ?
Yes
Criteria
Achieved ?
Yes
Retention Time
Calibration check
System Blank
Analyze standard
Analyze one
standard
Analyze HPLC
grade water
Duplicate analyses Duplicate Samples
beginning and one
at end
At setup
Once every 4-10
samples
Bracket sample
batch, one at
beginning and one
at end
As collected
Each ion within ± 5% of
standard retention time
85-115% recovery
No quantifiable ions
Check system temperature and eluent
Recalibrate or re-prepare standard, re-
analyze sample not bracketed by
acceptable standard
Re-analyze
Yes
Yes
Yes
Yes
Yes
165
-------
Table 6-6. (Continued)
Parameter
Replicate Analyses
Quality Control
Check
Replicate Injections
Freauencv
Each sample
Accentance Criteria
< 10%RPDfor
concentrations greater than
1 Ome/L
Corrective Action
Check instrument function, re-analyze
samples
Criteria
Achieved ?
Yes
HPLC = High Performance Liquid Chromatography
RPD = Relative Percent Difference
Table 6-7. Semivolatile Organic Compounds Analysis: Quality Criteria
Quality Control Check
Frequency
Acceptance Criteria
Corrective Action
Criteria
Achieved ?
Oi
Oi
Mass spectrometer instrument
tune check (FC-43)
Five-point calibration
bracketing the expected
concentration range
Calibration check using
midpoint of calibration range
System Blank
Retention time check
Daily prior to calibration check
Following maintenance or repair
of either gas chromatograph or
mass spectrometer or when daily
quality control check is not
acceptable
Daily
As needed after system
maintenance or repair
Daily
Mass assignments m/z = 69, 219, 502
(± 0.2)
Peak widths = 0.59-0.65
Relative mass abundances = 100 %
(69); >30 % (219); > 1% (502).
Correlation coefficient of either
quadratic or linear regression > 0.999
Compounds in a representative
organic compound suite > 80% are ±
15% of individually certified values.
Values > 20% are not accepted.
Potential analytes < detection limit
values
Verify that select compounds are
within ±2% of established retention
time window
Retune mass spectrometer;
clean ion source
Check integration, re-
integrate or recalibrate
Repeat analysis, repeat
calibration curve
Repeat analysis; check
system integrity. Reanalyze
blank
Check inlet and column
flows and the various
GC/MS temperature zones
Yes
Yes
Yes
Yes
Yes
-------
Field sampling equipment quality control requirements that were met in the course of preparing
for the field test and execution of testing activities are summarized in Table 6-1.
For this testing program:
No performance evaluation audits were performed for any of the analytical
procedures for the NCA&T field tests. During the development phases of the EPA
dilution sampling system and the associated analytical procedures, PE audits were
conducted, but not on a test-specific basis.
• Collocated sample collection was not feasible as EPA owns only one dilution
sampling system.
Duplicate or replicate sample collection arrays for the measurement of particulate
matter were collected on each of the three test runs for each campaign (see Figure
4-11). However, comparison of individual samples was not achievable because of
the need to composite samples to aggregate sufficient quantities of material to
perform analytical procedures. There were not sufficient sample collection ports
or physical space on the EPA Dilution Sampling System to accommodate duplicate
collection of air toxics or carbonyl samples.
The primary function of testing with the dilution sampling system was collection
of PM for determination of mass collected. There is no commercial source of PM
standards spiked on filters and there is presently no accepted procedure for the
preparation of spiked PM filters.
• TO-15 samples were collected for informational purposes only and the TO-15
results were not used in any calculations of emission factors. A field blank was
collected for the TO-15 samples for campaign #1 as presented in the sample chain
of custody (COC) forms (see Appendix E). TO-15 sampling/analysis was not
performed for campaign #2. Data for the field blanks are presented in Appendix H
[Supporting Data for Air Toxics Analysis]; field blanks for TO-15 are erroneously
labeled as "Laboratory Blanks". These samples are clearly identified.
• A field blank was collected for the TO-11A samples for campaign #1 as
presented in the sample chain of custody (COC) forms (see Appendix E). TO-11A
sampling/analysis was not performed for campaign #2. Data for the field blanks
are presented in Appendix I [Supporting Data for Carbonyl Analysis]; field blanks
for TO-11A are erroneously labeled as "Laboratory Blanks". These samples are
clearly identified.
The inability to conduct robust sampling QC affects the ability to calculate analytical
uncertainties associated with the analysis of individual samples. As a result, uncertainties
associated with individual emission factors for individual test days were calculated by the EPA
167
-------
Work Assignment Manager and reported. It is recommended that procedures for conducting
robust sampling QC be developed for future field testing.
Strict chain of custody procedures were followed in collecting and transporting samples
and sampling media to and from the field sampling location. Sample substrates (filters, denuders,
PUF canister, DNPH cartridges) were prepared in advance in accordance with the number and
types of samples designated in the sampling matrix of the approved field test plan. Clean
SUMMA collection canisters and DNPH cartridges used to collect carbonyl compounds were
prepared and supplied by ERG. The PUF, XAD-4, denuder, and PM-2.5 sampling substrates
were prepared and supplied by EPA. Chain of custody forms (Figure 6-1) were initiated when the
sampling media were prepared each sample substrate was assigned a unique identification number
by the laboratory supplying the substrates. Copies of the chain of custody forms are included in
Appendix E.
Sample identification numbers include a code to track:
Source type;
• Test date;
Sampler type;
Substrate type;
• Sampler chamber (i.e., dilution chamber or residence chamber);
Sampler port;
• Lane/leg;
• Position; and
• Holder number.
For samples to be analyzed in the EPA laboratories, whole sampling arrays were
assembled by EPA, assigned a unique tracking number and used for sample collection. Sample
collection arrays were recovered in the field as a complete unit and transferred to the EPA
laboratory for disassembly and analysis.
168
-------
EASTERN RESEARCH GROUP. INC.
Chain of Custody Record
Page.
of
PROJECT
SITE
COLLECTED BY (Signature)
FIELD SAMPLE I.D.
SAMPLE MATRIX
REMARKS:
RECEIVED BY:
DATE/TIME
DATE
TIME
RELINQUISHED BY:
AIMERS
9Ł
o o
^ r ^
DATE
ANALYSES
TIME
RECEIVED BY:
SAM ID NO.
REMARKS (For lab use only)
DATE
TIME
RELINQUISHED DATE TIME
BY:
RELINQUISHED DATE TIME
BY:
LAB USE ONLY
RECEIVED FOR LABORATORY BY:
DATE
TIME
AIRBILL NO.
OPENED BY
DATE
TIME
TEMP°C
SEAL*
CONDITION
REMARKS:
Figure 6-1. ERG chain of custody form.
-------
After collection, samples were transported to the analysis laboratories by ERG, with
careful documentation of sample collection and chain of custody records for the samples being
transported. Samples were stored in a secure area until they were transported to the laboratories
performing analyses.
Carbonyl Compound Analysis
Quality control criteria for the carbonyl analysis performed by ERG are shown in
Table 6-2. Supporting analytical calibration and quality control data are a part of the project file
at ERG.
Concurrent Air Toxics/Speciated Nonmethane Organic Compound (SNMOC)
Analysis
The analytical system performing the concurrent analysis is calibrated monthly and
blanked daily prior to sample analysis. A quality control standard is analyzed daily prior to
sample analysis to ensure the validity of the current monthly response factor. Following the daily
quality control standard analysis and prior to the sample analysis, cleaned, dried air from the
canister cleaning system is humidified and then analyzed to determine the level of organic
compounds present in the analytical system. Upon achieving acceptable system blank results —
less than or equal to 20 ppbC — sample analysis begins. Ten percent of the total number of
samples received are analyzed in replicate to determine the precision of analysis for the program.
After the chromatography has been reviewed, the sample canister is returned to the canister
cleaning laboratory to be prepared for subsequent sample collection episodes or sent to another
laboratory for further analysis. Quality control procedures for the air toxics and SNMOC
analyses are summarized in Table 6-3; supporting analytical calibration and quality control data
are a part of the project file at ERG.
170
-------
PM Mass Measurements, Elemental Analysis, Water-Soluble Ion Analysis, and
GC/MS Analysis
Quality control criteria for EPA analyses (PM mass, elemental analyses, ion
chromatography analysis, and GC/MS analysis are summarized in Tables 6-4 through 6-7;
supporting data are included in the project file in the EPA laboratory.
Sample collection completeness was 100% (i.e., all planned samples were collected for
both campaign #1 and campaign #2). Most of the solvent extracts of the XAD-coated annular
denuders, quartz filters, and PUF plugs from campaign #1 were subjected to analysis for
semivolatile organic compounds. However, these results are not reported due to the observation
that breakthrough of the sampling substrates had occurred, thus rendering reliable quantitative
measurements impossible. For campaign #2, 99% of the samples were analyzed. Of the samples
not analyzed, two were quartz which were archived and two were PUF extracts which were
misplaced at the EPA laboratory.
171
-------
Section 7
References
1. Alternative Control Techniques Document - Industrial/Commercial/Institutional (ICI)
Boilers, U.S. EPA, Office of Air Quality Planning and Standards, EPA-453/R-94-022, March
1994.
2. Emission Factor Documentation for AP-42 Section 1.3, Fuel Oil Combustion, U.S. EPA,
Office of Air Quality Planning and Standards, April 1993.
3. Hildemann, L. M., G. R. Cass, and G. R. Markowski, A Dilution Stack Sampler for Collection
of Organic Aerosol Emissions: Design, Characterization and Field Tests, Aerosol Science and
Technology, 10, 193-204, 1989.
4. Compilation of Air Pollutant Emission Factors, AP-42, Fifth Edition, Volume 1: Stationary
Point and Area Sources, U. S. EPA, Office of Air Quality Planning and Standards, 1996.
5. U.S. Government Printing Office, EPA Method 1, Sample and Velocity Traverses for
Stationary Sources, in Code of Federal Regulations, Title 40, Part 60, Appendix A, pp. 181-
206, Washington, DC, 1989a.
6. U.S. Government Printing Office, EPA Method 2, Velocity -S-Type Pilot, in Code of Federal
Regulations, Title 40, Part 60, Appendix A, pp. 214-253, Washington, DC, 1989b.
7. U.S. Government Printing Office, EPA Method 4, Moisture Content, in Code of Federal
Regulations, Title 40, Part 60, Appendix A, pp. 347-371, Washington, DC, 1989c.
8. U.S. Government Printing Office, EPA Method 5, Determination of Paniculate Matter
Emissions from Stationary Sources, in Code of Federal Regulations, Title 40, Part 60,
Appendix A, pp. 371-443, Washington, DC, 1989d.
9. von Lehmden, D. J., W. G. De Wees, and C. Nelson. Quality Assurance Handbook for Air
Pollution Measurement Systems. Volume III. Stationary Source Specific Methods. U.S.
Environmental Protection Agency, Environmental Monitoring and Support Laboratory,
Research Triangle Park, NC, EPA/600/4-77/027b (NTIS PB80-112303), May 1979.
10. NIOSH Method 5040, Elemental Carbon (DieselPaniculate). National Institute for
Occupational Safety and Health (NIOSH) Manual of Analytical Methods (NMAM®), 4th
Edition, Department of Health and Human Services (NIOSH) Publication 94-113 (August,
1994).
11. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient
Air, Second Edition, Compendium method TO-11A, "Determination of Formaldehyde in
Ambient Air Using Adsorbent Cartridge Followed by High Performance liquid
Chromatography (HPLC)," EPA/625/R-96/010b, January, 1999.
172
-------
12. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient
Air, Second Edition, Compendium Method TO-15, "Determination of Volatile Organic
Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas
Chromatography/Mass Spectrometry," EPA/625/R-96/010b, January, 1999.
13. U. S. EPA. Technical Assistance Document for Sampling and Analysis of Ozone Precursors,
U.S. Environmental Protection Agency, National Exposure Research Laboratory, Office of
Research and Development, Research Triangle Park, NC, EPA-600/R-98-161, September
1998. No NTIS number available. Document is available from Ambient Monitoring
Technology Information Center (AMTIC) Bulletin Board.
(http://www.epa.gov/ttnamtil/files/ambient/pams/newtad.pdf)
14. Federal Register. Volume 49, Number 209, Appendix B to Part 136—Definition and
Procedure for the Determination of the Method Detection Limit—Revision 1.11, pp. 198-199,
October 26, 1984.
15. Quality Assurance Project Plan; Source Sampling for Fine Particulate Matter, QTRAX No.
99051, Revision No. 2, April 2000, EPA National Risk Management Research Laboratory,
Air Pollution Prevention & Control Division.
16. Quality Assurance Project Plan; Chemical Analysis of Fine Parti culate Matter, QTRAX No.
99002, Revision No. 3, December 2000, EPA National Risk Management Research
laboratory, Air Pollution Prevention & Control Division.
173
-------
EPA/600/R-07/005
February 2007
Source Sampling Fine Particulate Matter
Institutional Oil-Fired Boiler
Appendix A
Table of Unit Conversions
Appendix B
Example CalculationsNMOC, SNMOC, and Carbonyl Emission Factors
Appendix C
Method Detection Limits
Appendix D
EPA Method Operating ProceduresERG Standard Operating Procedures
-------
Appendix A
Table of Unit Conversions
-------
Multiply
atmospheres
atmospheres
atmospheres
atmospheres
atmospheres
Btu
Btu
centimeters
cm/sec
cm/sec
cm/sec
cm/sec
cm3
cm3
ft3
fWmin
in.3
m3
ft
ft
ft of water
grams
inches
inches of water
kg
km
km
kilowatts
Unit Conversion Table
By
101.3
29.92
760
33.94
14.70
1054
2.982 x ID'4
0.3937
1.969
0.03281
0.036
0.6
3.53x ID'2
io-3
0.02832
0.4720
16.39
35.31
12
0.3048
0.8826
0.03527
2.540
0.07355
2.20462
3280.84
0.6214
56.92
To Obtain
kilopascals
inches of mercury
mm of mercury
feet of water
lb/in.2(psi)
joules
kilowatt-hours
inches
ft/min
ft/sec
km/hr
m/min
ft3
liters
m3
liters per second
cm3
ft3
in.
m
in. mercury
ounces
cm
inches of mercury
Ib
ft
miles
Btu per min. (Continued)
A-l
-------
Multiply
liters
liters
liters
liters per minute
m
m
m3
miles
miles
ounces
pounds
pounds per square inch
cm2
ft2
ft2
temperature (°C + 273)
temperature (°C + 17.8)
temperature (°F + 460)
temperature (°F-32)
watts
watts
By
0.03531
61.02
io-3
5.855x ID'4
3.28084
39.37
0.02832
5280
1.6093
28.35
453.6
703.1
0.1550
929.0
0.09290
1
1.8
1
5/9
0.05692
44.26
To Obtain
ft3
in.3
m3
ft3 per second
ft
in.
ft3
feet
km
grams
grams
kg/m2
in.2
cm2
m2
absolute temperature (K)
temperature (°F)
temperature (°Rankine)
temperature (°C)
Btu per min.
foot-pounds per min.
A-2
-------
Appendix B
Example Calculations
NMOC, SNMOC, and Carbonyl Emission Factors
-------
Table B-l. Calculation of Mass Emission Rates for Speciated NMOC (1/16/01)
Test
Analyte
Date
Entry Date
Greensboro A&T
Speciated NMOC
1/16/01
9/17/01
Speciated NMOC
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
Total Volume of Air Sampled
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of SNMOC in Diluted Sample
Mass Flow Rate of SNMOC in Undiluted Sample
Total Mass of Speciated SNMOC in Sampled Air
Speciated SNMOC in Total Combustion Air
Mass Emission Rate of Speciated SNMOC
0.025004
6,568.63
4065
600.33
18.53
847.89
0.007
Units
kg
scfm
min
slpm
slpm
1pm
69102783
11124.115
509013.8
46.75769
0.0059501
0.2782111
3094.8522
19225161
246.20
0.246
liters
liters
liters
• g/liter
• g/liter
•g
•g
•g/kg
mg/kg
Calculation of Mass of Speciated NMOC Collected
Testl 1/16/01
Volume Canister = flow rate into canister * test duration
Test duration 600.33 min
Flow rate, dilution air canister 0.008 1pm
Flow rate, residence chamber canister 0.007 1pm
Mass Speciated SNMOC Collected = [Speciated SNMOC Cone. ]*Volume Canister
SNMOC RC = 145.55 • g/m3 = 145.55 ng/L = 0.14555 • g/L 0.6116462
SNMOC DA = 122.15'g/m3 = 122.15 ng/L = 0.12215 • g/L 0.5866425
Mass Speciated NMOC Collected
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
145.55 • g/m3
122.15« g/m3
23.40 • g/m3
0.0250037
Volume
4.80264
4.20231
liters
liters
B-l
-------
Table B-2. Calculation of Mass Emission Rates for Speciated NMOC (1/17/01)
Date
Entry Date
1/17/01
9/17/01
Speciated NMOC
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
Total Volume of Combustion Air
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of SNMOC in Diluted Sample
Mass Flow Rate of SNMOC in Undiluted Sample
Total Mass of Speciated SNMOC in Sampled Air
Speciated SNMOC in Total Combustion Air
Mass Emission Rate of Speciated SNMOC
0.176128
6,934.45
4159.00
600.5
17.88
848.35
0.008333
70720752.38
10736.94
509434.175
48.44686801
0.035197678
1.705217245
18308.81525
120594246.5
300.68
0.30
Units
kg
scfm
min
slpm
slpm
1pm
liters
liters
liters
• g/liter
• g/liter
•g/kg
mg/kg
Calculation of Mass of Speciated NMOC Collected
Test 2 1/17/01
Volume Canister = flow rate into canister * test duration
Test duration 600.5 min
Flow rate, dilution air canister 0.007833 1pm
Flow rate, residence chamber canister 0.008333 1pm
Mass Speciated SNMOC Collected = [Speciated SNMOC Cone. ]*Volume Canister
SNMOC RC = 124.77 • g/m3 = 124.77 ng/L = 0.12477 • g/L 0.6243449
SNMOC DA = 95.29 • g/m3 = 95.29 ng/L = 0.09529 • g/L 0.448217145
Mass Speciated NMOC Collected
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
0.176127755
124.77 • g/m3
95.29 • g/m3
29.48 • g/m3
Volume
4.7037165
5.0039665
liters
liters
B-2
-------
Table B-3. Calculation of Mass Emission Rates for Speciated NMOC (1/18/01)
Date
Entry Date
1/18/01
9/17/01
Speciated NMOC
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.334446 • g
Mass Fuel Consumed 7,926.21 kg
Combustion Air Flow Rate (Average) 4827 scfm
RunTime 600.17 min
Venturi Flow Rate (Average) 19.01 slpm
Dilution Air Flow Rate (Average) 850.66 slpm
Flow Rate at Sample Collection Unit 0.008667 1pm
Calculations
Total Volume of Combustion Air 82034497 liters
Volume of Combustion Air Sampled 11409.232 liters
Volume of Dilution Air 510540.61 liters
Dilution Ratio 45.748027
Mass Flow Rate of SNMOC in Diluted Sample 0.0642958 • g/liter
Mass Flow Rate of SNMOC in Undiluted Sample 2.9414082 • g/liter
Total Mass of Speciated SNMOC in Sampled Air 33559.208 •§
Speciated SNMOC in Total Combustion Air 241296944 • g
Mass Emission Rate of Speciated SNMOC 499.7 • g/kg
0.50 mg/kg
Calculation of Mass of Speciated NMOC Collected
Test3 1/18/01
Volume Canister = flow rate into canister * test duration
Test duration 600.17 min
Flow rate, dilution air canister 0.008 1pm
Flow rate, residence chamber canister 0.008667 1pm
Mass Speciated SNMOC Collected = [Speciated SNMOC Cone. ]*Volume Canister
SNMOC RC = 256.39 «g/m3 = 256.39 ng/L = 0.25639 • g/L 1.333657 «g
SNMOC DA = 208. Il'g/m3 = 208. llng/L = 0.20811 • g/L 0.999211 «g
Volume
4.80136
5.2016734
liters
liters
Mass Speciated NMOC Collected
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
0.334446
256.39
208.11
48.28
•g/m3
•g/m3
•g/m3
B-3
-------
Table B-4. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) NMOC (1/16/01)
Test
Analyte
Date
Entry Date
Greensboro A&T
Total
NMOC
1/16/01
9/17/01
Total (Speciated + Unspeciated) NMOC
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
Total Volume of Air Sampled
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of NMOC in Diluted Sample
Mass Flow Rate of NMOC in Undiluted Sample
Total Mass of Total NMOC in Sampled Air
Total NMOC in Total Combustion Air
Mass Emission Rate of Total NMOC
Units
0.020531
6,569
4065
600.33
18.53
847.89
0.007
•g
kg
scfm
min
slpm
slpm
1pm
7E+07
11124.1
509014
46.7577
0.00489
0.22844
2541.21
1.6E+07
271.0
0.27
liters
liters
liters
• g/liter
• g/liter
•g
•g
•g/kg
mg/kg
Calculation of Mass of Total NMOC Collected
Testl 1/16/01
Volume Canister = flow rate into canister * test duration
Test duration 600.33 min
Flow rate, dilution air canister 0.008 1pm
Flow rate, residence chamber canister 0.007 1pm
Mass Total NMOC Collected = [Total NMOC Cone. ]*Volume Canister
NMOC RC = 171.88 • g/m3 = 171.88 ng/L = 0.17188 • g/L 0.72229
NMOC DA = 146.12ug/m3= 146.12 ng/L = 0.14612 ug/L 0.70176
Mass Total NMOC Collected
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
0.02053
171.88'g/m3
146.12'g/m3
25.76 • g/m3
Volume
4.80264
4.20231
liters
liters
B-4
-------
Table B-5. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) NMOC (1/17/01)
Test
Analyte
Date
Entry Date
Dean Smith #2 (Greensboro A&T)
Total NMOC
1/17/01
9/17/01
Total (Speciated + Unspeciated) NMOC
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
Total Volume of Combustion Air
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of NMOC in Diluted Sample
Mass Flow Rate of NMOC in Undiluted Sample
Total Mass of Total NMOC in Sampled Air
Total NMOC in Total Combustion Air
Mass Emission Rate of Total NMOC
Units
0.168868
6,934
4159.00
600.5
17.88
848.35
0.008333
•g
kg
scfm
min
slpm
slpm
1pm
70720752.4
10736.94
509434.18
48.446868
0.0337468
1.6349282
17554.125
11562349
279.23
0.28
liters
liters
liters
• g/liter
• g/liter
•g/kg
mg/kg
Calculation of Mass of Total NMOC Collected
Test 2 1/17/01
Volume Canister = flow rate into canister * test duration
Test duration 600.5
Flow rate, dilution air canister 0.007833
Flow rate, residence chamber canister 0.008333
Mass Total NMOC Collected = [Total NMOC Cone. ] * Volume Canister
NMOC RC = 133.49 ug/m3 = 133.49 ng/L = 0.13349 • g/L
NMOCDA=106.11ug/m3= 106.11 ng/L = 0.10611 • g/L
Mass Total NMOC Collected
Volume
min
1pm 4.7037165
1pm 5.0039665
liters
liters
0.6679795
0.4991114
0.1688681
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
124.77 • g/m3
95.29 • g/m3
29.48 • g/m3
B-5
-------
Table B-6. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) NMOC
(1/18/01)
Date
Entry Date
1/18/01
9/17/01
Total (Speciated + Unspeciated) NMOC
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
0.36074
7,926
4827
600.17
19.01
850.66
0.008667
Units
kg
scfm
min
slpm
slpm
1pm
Total Volume of Combustion Air
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of NMOC in Diluted Sample
Mass Flow Rate of NMOC in Undiluted Sample
Total Mass of Total NMOC in Sampled Air
Total NMOC in Total Combustion Air
Mass Emission Rate of Total NMOC
82034497.5
11409.2317
510540.612
45.7480274
0.06935076
3.17266044
36197.6181
260267605
545.33
0.55
liters
liters
liters
• g/liter
• g/liter
•g
•g
•g/kg
mg/kg
Calculation of Mass of Total NMOC Collected
Test3 1/18/01
Volume Canister = flow rate into canister * test duration
Test duration
Flow rate, dilution air canister
Flow rate, residence chamber canister
Mass Total NMOC Collected = [Total NMOC Cone. ]*Volume
Canister
NMOC RC = 269.18 • g/m3 = 269.18 ng/L = 0.26918 • g/L
NMOC DA = 216.491' g/m3 = 216.49 ng/L = 0.21649 • g/L
Mass Total NMOC Collected
Residence Chamber
Dilution Air
Residence Chamber - Dilution Air
600.17
0.008
0.008667
1.40018644
1.03944643
0.36074002
269.18« g/m3
216.49'g/m3
52.69 • g/m3
Volume
min
1pm 4.80136 liters
1pm 5.2016734 liters
B-6
-------
Table B-7. Calculation of Mass Emission Rates for Speciated Carbonyl Compounds (1/16/01)
Test Greensboro A&T
Analyte Speciated Carbonyls
Date 1/16/01
Entry Date 9/17/01
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.9815 • g
Mass Fuel Consumed 6,569 kg
Combustion Air Flow Rate (Average) 4065 scfm
RunTime 600.33 min
Venturi Flow Rate (Average) 18.53 slpm
Dilution Air Flow Rate (Average) 847.89 slpm
Flow Rate at Sample Collection Unit 0.9601 1pm
Calculations
Total Volume of Air Sampled 69659855 liters
Volume of Combustion Air Sampled 11124.11 liters
Volume of Dilution Air 509013.8 liters
Dilution Ratio 46.75769
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.001703 • g/liter
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.079623 • g/liter
Total Mass of Speciated Carbonyls in Sampled Air 885.7319 • g
Total Speciated Carbonyls in Total Combustion Air 5546505 • g
Mass Emission Rate of Total Speciated Carbonyls 844.3929 • g/kg
0.844393 mg/kg
B-7
-------
Table B-8. Calculation of Mass Emission Rates for Speciated Carbonyl Compounds (1/17/01)
Date 1/17/01
Entry Date 9/17/01
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.6050 • g
Mass Fuel Consumed 6,934 kg
Combustion Air Flow Rate (Average) 4159 scfm
Run Time 600.5 min
Venturi Flow Rate (Average) 17.88 slpm
Dilution Air Flow Rate (Average) 848.35 slpm
Flow Rate at Sample Collection Unit 0.9592 1pm
Calculations
Total Volume of Combustion Air 76162118 liters
Volume of Combustion Air Sampled 10736.94 liters
Volume of Dilution Air 509434.2 liters
Dilution Ratio 48.44687
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.00105 • g/liter
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.050886 • g/liter
Total Mass of Speciated Carbonyls in Sampled Air 546.3607 «g
Total Speciated Carbonyls in Total Combustion Air 3875591 • g
Mass Emission Rate of Total Speciated Carbonyls 558.8891 • g/kg
0.558889 mg/kg
B-8
-------
Table B-9. Calculation of Mass Emission Rates for Speciated Carbonyl Compounds (1/18/01)
Date 1/18/01
Entry Date 9/17/01
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.2985 • g
Mass Fuel Consumed 7,926 kg
Combustion Air Flow Rate (Average) 4827 scfm
RunTime 600.17 min
Venturi Flow Rate (Average) 19.01 slpm
Dilution Air Flow Rate (Average) 850.66 slpm
Flow Rate at Sample Collection Unit 1.1209 1pm
Calculations
Total Volume of Combustion Air 88185640 liters
Volume of Combustion Air Sampled 11409.23 liters
Volume of Dilution Air 510540.6 liters
Dilution Ratio 45.74803
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.000444 • g/liter
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.020299 • g/liter
Total Mass of Speciated Carbonyls in Sampled Air 231.5965 «g
Total Speciated Carbonyls in Total Combustion Air 1790084 • g
Mass Emission Rate of Total Speciated Carbonyls 225.843 8 • g/kg
0.225844 mg/kg
B-9
-------
Table B-10. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) Carbonyl
Compounds (1/16/01)
Date 1/16/01
Entry Date 9/17/01
Parameters Required Units
Mass of Analyte in Total Combustion Air 1.6460 • g
Mass Fuel Consumed 6,569 kg
Combustion Air Flow Rate (Average) 4065 scfm
RunTime 600.33 min
Venturi Flow Rate (Average) 18.53 slpm
Dilution Air Flow Rate (Average) 847.89 slpm
Flow Rate at Sample Collection Unit 0.9601 1pm
Calculations
Total Volume of Air Sampled 69659855 liters
Volume of Combustion Air Sampled 11124.11 liters
Volume of Dilution Air 509013.8 liters
Dilution Ratio 46.75769
Mass Flow Rate of Total Carbonyls in Diluted Sample 0.002856 • g/liter
Mass Flow Rate of Total Carbonyls in Undiluted Sample 0.133529 • g/liter
Total Mass of Total Carbonyls in Sampled Air 1485.395 • g
Total Carbonyls in Total Combustion Air 9301627 • g
Mass Emission Rate of Total Carbonyls 1416.068 *g/kg
1.416068 mg/kg
B-10
-------
Table B-ll. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) Carbonyl
Compounds (1/17/01)
Date 1/17/01
Entry Date 9/17/01
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.9260 • g
Mass Fuel Consumed 6,934 kg
Combustion Air Flow Rate (Average) 4159 scfm
Run Time 600.5 min
Venturi Flow Rate (Average) 17.88 slpm
Dilution Air Flow Rate (Average) 848.35 slpm
Flow Rate at Sample Collection Unit 0.9592 1pm
Calculations
Total Volume of Combustion Air 76162118 liters
Volume of Combustion Air Sampled 10736.94 liters
Volume of Dilution Air 509434.2 liters
Dilution Ratio 48.44687
Mass Flow Rate of Total Carbonyls in Diluted Sample 0.001608 • g/liter
Mass Flow Rate of Total Carbonyls in Undiluted Sample 0.077885 • g/liter
Total Mass of Total Carbonyls in Sampled Air 836.2479 • g
Total Carbonyls in Total Combustion Air 5931896 • g
Mass Emission Rate of Total Carbonyls 855.4237 • g/kg
0.855424 mg/kg
B-ll
-------
Table B-12. Calculation of Mass Emission Rates for Total (Speciated + Unspeciated) Carbonyl Compounds
(1/18/01)
Date
Entry Date
1/18/01
9/17/01
Parameters Required
Mass of Analyte in Total Combustion Air
Mass Fuel Consumed
Combustion Air Flow Rate (Average)
Run Time
Venturi Flow Rate (Average)
Dilution Air Flow Rate (Average)
Flow Rate at Sample Collection Unit
Calculations
Total Volume of Combustion Air
Volume of Combustion Air Sampled
Volume of Dilution Air
Dilution Ratio
Mass Flow Rate of Total Carbonyls in Diluted Sample
Mass Flow Rate of Total Carbonyls in Undiluted Sample
Total Mass of Total Carbonyls in Sampled Air
Total Carbonyls in Total Combustion Air
Mass Emission Rate of Total Carbonyls
Units
0.7380
7,926
4827
600.17
19.01
850.66
1.1209
•g
kg
scfm
min
slpm
slpm
1pm
88185640
11409.23
510540.6
45.74803
0.001097
0.050187
572.5903
4425735
558.3675
0.558368
liters
liters
liters
• g/liter
• g/liter
•g/kg
mg/kg
B-12
-------
Appendix C
Method Detection Limits
-------
Table C-l. Carbonyl Compounds Analyzed by High Performance Liquid Chromatography: Method
Detection Limits
Method Detection Limits
Compound
Formaldehyde
Acetaldehyde
Acetone
Propionaldehyde
Crotonaldehyde
Butyraldehyde
Benzaldehyde
Isovalderaldehyde
Valeraldehyde
o-Tolualdehyde
/w-Tolualdehyde
/>-Tolualdehyde
Hexaldehyde
2,5-Dimethylbenzaldehyde
Diacetyl
Methacrolein
2-Butanone
Glyoxal
Acetophenone
Methylglyoxal
Octanal
Nonanal
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-3
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779.94-2
432-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
(jig)
0.0838
0.0916
0.0428
0.0934
0.1283
0.0956
0.0959
0.1076
0.1758
0.1439
0.1439
0.1439
0.1377
0.1337*
0.0154*
0.0125*
0.0125*
0.0412*
0.0250*
0.0244*
0.0100*
0.0182*
*Estimated value.
C-l
-------
Table C-2. Detection Limits (ppbv) for Air Toxics Compounds (Analytical Method EPA Compendium
Method TO-15)
Compound
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3 -Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acetone
Trichlorofluoromethane
Acrylonitrile
1 , 1 -Dichloroethene
Methylene chloride
Trichlorotrifluoroethane
/ra«5-l,2-Dichloroethylene
1 , 1 -Dichloroethane
Methyl ter/-butyl ether
Methyl ethyl ketone
Chloroprene
cis- 1 ,3 -Dichloroethylene
Bromochloromethane
Chloroform
Ethyl ter/-butyl ether
1 ,2-Dichloroethane
1,1,1 -Trichloroethane
Benzene
Carbon tetrachloride
fer/-Amyl methyl ether
1 ,2-Dichloropropane
Ethyl acrylate
Bromodichloromethane
Trichloroethylene
Methyl methacrylate
CAS No.
74-86-2
115-07-1
75-71-8
74-87-3
1320-37-2
75-01-4
106-99-0
74-83-9
75-00-3
75-05-8
67-64-1
75-69-4
107-13-1
75-35-4
75-09-2
26523-64-8
56-60-5
75-34-3
1634-04-1
78-93-3
126-99-8
156-59-2
74-97-5
67-66-3
637-92-3
107-06-2
71-55-6
71-43-2
56-23-5
994-05-8
78-87-5
140-88-5
75-27-4
79-01-6
80-62-6
Method Detection Limit
(ppbv)
0.07
0.03
0.04
0.06
0.03
0.07
0.05
0.04
0.06
0.21
0.15
0.06
0.06
0.04
0.02
0.02
0.05
0.03
0.03
0.03
0.03
0.04
0.04
0.04
0.05
0.08
0.06
0.06
0.09
0.06
0.09
0.04
0.05
0.06
0.06
C-2
-------
Table C-2. (Continued)
Compound
cis- 1 ,2-Dichloropropene
Methyl isobutyl ketone
trans- 1 ,2-Dichloropropene
1 , 1 ,2-Trichloroethane
Toluene
Dibromochloromethane
1 ,2-Dibromoethane
w-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m-, p-Xylene
Bromoform
Styrene
1 , 1 ,2,2-Tetrachloroethane
o-Xylene
1 ,3 ,5-Trimethylbenzene
1 ,2,4-Trimethylbenzene
/w-Dichlorobenzene
Chloromethylbenzene
/>-Dichlorobenzene
o-Dichlorobenzene
1 ,2,4-Trichlorobenzene
Hexachloro- 1 , 3 -butadiene
CAS No.
10061-01-5
108-10-1
10061-02-6
79-00-5
108-88-3
124-48-1
106-93-4
111-65-9
127-18-4
108-90-7
100-41-4
108-38-3/106-42-3
75-25-2
100-42-5
79-34-5
95-47-6
108-67-8
95-63-6
541-73-1
100-44-7
106-46-7
95-50-1
120-82-1
87-68-3
Method Detection Limit
(ppbv)
0.03
0.07
0.03
0.03
0.10
0.04
0.05
0.09
0.10
0.04
0.10
0.08
0.12
0.11
0.05
0.03
0.08
0.09
0.09
0.18
0.08
0.10
0.09
0.11
C-2
-------
Table C-3. Detection Limits (ng/m3) for Speciated Nonmethane Organic Compounds (EPA Research
Operating Procedure, Research Protocol Method for Analysis ofC2-C12 Hydrocarbons in Ambient Air by Gas
Chromatography with Cryogenic Concentration)
Method Detection Limits
Compound CAS No. (|ig/m3)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/ 1 -butene
1,3 -Butadiene
w-Butane
/raws-2-Butene
cis-2 -Butene
3 -Methyl- 1 -butene
Isopentane
1-Pentene
2-Methyl- 1 -butene
w-Pentane
Isoprene
/ra«s-2 -Pentene
c/s-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl- 1 -pentene
Cyclopentane
2,3 -Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl- 1 -pentene
1-Hexene
2-Ethy 1-1 -butene
w-Hexane
/raws-2-Hexene
c/s-2-Hexene
74-85-1
74-86-2
74-84-0
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
0.50
0.47
0.54
0.44
0.46
0.42
0.43
0.21
0.40
0.43
0.42
0.42
0.32
0.33
0.32
0.45
0.33
0.31
0.33
0.33
0.32
0.46
0.31
0.45
0.32
0.46
0.46
0.46
0.46
0.46
0.45
0.46
0.46
0.46 (Continued)
C-4
-------
Table C-3. (Continued)
Compound
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3 -Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Trimethylpentane
w-Heptane
Methylcyclohexane
2,2,3 -Trimethylpentane
2,3 ,4-Trimethylpentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
w-Octane
Ethylbenzene
m-, />-Xylene
Styrene
o-Xylene
1-Nonene
w-Nonane
Isopropylbenzene
a-Pinene
w-Propylbenzene
/w-Ethyltoluene
/>-Ethyltoluene
1 ,3 ,5-Trimethylbenzene
o-Ethyltoluene
p-Pinene
1 ,2,4-Trimethylbenzene
1-Decene
w-Decane
CAS No.
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
Method Detection Limits
(Hg/m3)
0.45
0.35
0.42
0.45
0.40
0.40
0.40
0.39
0.51
0.40
0.39
0.51
0.51
0.37
0.51
0.51
0.50
0.51
0.52
0.47
0.46
0.47
0.40
0.41
0.38
0.39
0.38
0.38
0.38
0.38
0.38
0.39
0.38
0.33
0.33 (Continued)
C-5
-------
Table C-3. (Continued)
Method Detection Limits
Compound CAS No. (Hg/m3)
1,2,3-Trimethylbenzene 526-73-8 0.38
ffj-Diethylbenzene 141-93-5 0.32
^-Diethylbenzene 105-05-5 0.32
1-Undecene 821-95-4 0.49
w-Undecane 1120-21-4 0.50
1-Dodecene 112-41-4 0.49
w-Dodecane 112-40-3 0.50
1-Tridecene 2437-56-1 0.49
w-Tridecane 629-50-5 0.50
C-6
-------
Appendix D
EPA Method Operating Procedures
ERG Standard Operating Procedures
-------
Table D-l. List of EPA Method Operating Procedures
EPA Lab Method No. Method Title
2501 Preparation of Clean Substrates, Glassware, and Other
Materials
2502 Purification of Benzene Solvent
2503 Mass Measurements of Blank and Exposed Sampling
Substrates
2504 Solvent Extraction of Samples and Extract Concentration
2505 Diazomethane Preparation and Extract Methylation
2506 Silylation of Methylated Extracts
2507 GC/MS Calibration and Analysis of Extracts
2508 Denuder Coating, Cleanup, and Extraction
2509 PUF Cleanup and Extraction
NIOSH Method 5040 Elemental/Organic Carbon Analysis
D-l
-------
Table D-2. List of ERG Standard Operating Procedures
SOP
No.
Dept
SOP Title
Rev
Issue Date
All
Prep
VOC
3B VOC
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
GC/MS
MS/VOC
GC/MS
GC/MS
All
All
All
All
Prep
VOC
Prep
Prep
GC
All
All
All
20
All
Documentation of Field Recovery Activities
Gravimetric Determination for Paniculate Emissions
Measurements
Field Procedure for Collecting Ambient Air Toxics and
Carbonyl Compounds Samples using the ERG:AT/C
Sampling System
Field Procedure for Collecting Ambient Air Toxics and
Carbonyl Compounds Samples using the ERG:AT/C
Sampling System
SOP for Preventive Maintenance in the Gas
Chromatography/Mass Spectrometry Laboratory
SOP for the Concurrent GC/FID/MS Analysis of Canister Air
Toxic Samples
SOP for the Analysis of Tenax® Tubes According to EPA
Method TO-I/TO-17
SOP for the Preparation of Review Packages for Mass
Spectrometry Data Sets
Procedure for Preparation of Standard Operating Procedures
SOP for the Operation of the Documentation System
SOP for the Determination of Method Detection Limits in the
GC/MS Air Toxics Laboratory
SOP for Sample Storage and Checkout from
Freezers/Refrigerators at the Laboratory
SOP for Basic Training Requirements for Sample Preparation
Laboratory Personnel
Field Procedure for Collecting Ambient Air Hexavalent
Chromium Samples Using the ERG:CR6 Sampling System
SOP for Sample Preparation Quality Control
SOP for Documentation Procedures for the Sample
Preparation Laboratory
SOP for the Varian 9000 Series High Performance Liquid
Chromatography (HPLC)
SOP for Developing, Documenting, and Evaluating the
Accuracy of Spreadsheet Data
Maintaining and Recording Data Records
SOP for Transferring, Storing, and Using Confidential
Business Information (CBI)
SOP for Conducting a Laboratory Systems Audit
0
0
2/26/98
2/26/98
4/18/01
0
0
0
0
1
1
0
0
0
0
0
0
1
0
0
0
10/12/99
5/8/03
2/24/00
10/12/99
11/1/01
9/22/99
6/17/99
9/22/99
7/13/99
10/19/03
6/17/99
7/13/99
9/28/99
111191
2/26/98
1/16/98
3/3/98
D-2
-------
Table D-2. List of ERG Standard Operating Procedures
SOP
XT Dept SOP Title
No.
21
22
23
24
24
25
26
27
28
29
30
31
32
33
34
34
35
36
37
38
39
40
voc
Prep
All
GC
Chrom Lab
GC
All
GC
GC/MS
Prep
VOC
All
All
All
All
GC/MS,
GC, Prep,
VOC
All
All
All
All
All
Prep
Field Procedure for Collecting Ambient Air Toxics Canister
Samples Using the ERG: AT Sampling System
SOP for the Preparation of Standards in the ERG Organic
Preparatory Laboratory
SOP for the Use of Significant Figures and Rounding Off
Numbers When Reporting Data
SOP for Preparing Aldehyde Derivatizing Reagents and
Extracting Derivatized Samples
SOP for Preparing, Extracting, and Analyzing DNPH
Carbonyl Cartridges
SOP for the Operation of the Rainin High Performance Liquid
Chromatography System
SOP for Documentation: Labeling of Samples and Standards
Prepared in the Laboratory
SOP for the Operation of a Gas Chromatograph
SOP for Quality Assurance/Quality Control in Gas
Chromatography /Mass Spectrometry
SOP for Concentration of Sample Extracts Using the
Kuderna-Danish Concentrates
SOP for Canister Sampling System Certification Procedures
SOP for Cleaning Glassware and Syringes for Organic
Analysis
Statistical Manual Standard Operating Procedure
SOP for Solid and Hazardous Waste Disposal
Analytical Chemistry Training at PPK Laboratory
SOP for Analytical Chemistry Training in the ERG
Laboratory
SOP for Quality Assurance/Quality Control
SOP for Laboratory Security
SOP for Chemical Inventory
SOP for Personal Protective Equipment Program
SOP for Maintaining Laboratory Notebooks
SOP for Chemical Storage Facilities
Rev
0
0
0
0
1
0
0
0
0
0
0
0
1
0
0
0
1
1
1
0
0
0
Issue Date
9/16/03
2/2/00
11/5/98
9/28/99
5/8/03
9/28/99
10/12/99
7/13/99
2/23/00
10/4/99
10/4/99
1/24/01
4/18/01
2/2/00
Not Dated
9/22/99
4/18/01
2/15/01
2/23/00
2/2/00
-------
Table D-2. List of ERG Standard Operating Procedures
kJVJi
No.
41
42
43
44
45
46
47
47B
48
49
50
51
52
53
54
54
55
56
57
58
59
60
61
Dept
Optical
GC
GC/MS
GC/MS,
voc
Prep
VOC
VOC
VOC
GC/MS,
Prep
Prep
Prep
Prep
Prep
Prep
Transfill
Chrom
Lab, LIMS
GC/MS,
CCL
All
All
Transfill
GC
VOC
VOC
SOP Title
SOP for Tracer Gas Release and Integrated Bag Sampling for
Analysis by FTIR Spectroscopy
SOP for the Dionex-300 Ion Chromato graph
SOP for the Analysis of Semivolatile Organic Compounds in
Gaseous Emissions using the SemiVOST Method
SOP for Method 8270C - GC/MS Analysis of Semivolatile
Organics
SOP for Sample Log-in at the ERG Chemistry Laboratory
Field Procedure for Collecting Speciated and/or Total
Nonmethane Organic Compounds Ambient Air Samples
Using the ERG:S/NMOC Sampling System
Field Procedure for Collecting Ambient Carbonyl Compounds
Samples Using the ERG:C Sampling System
Field Procedure for Collecting Ambient Carbonyl Compounds
Samples Using the ERG:C Sampling System
SOP for Cleaning XAD-2® and Polyurethane Foam Cartridges
with Quality Control Measures to Assure Cleanliness
SOP for the Extraction and Analysis of PAH's from XAD-27
Traps
SOP for Separatory Funnel Liquid-Liquid Extraction by EPA
SW-846 Method 3 5 IOC
SOP for Continuous Liquid-Liquid Extraction by EPA S W-
846 Method 3520C
SOP for Acid-Base Partition Cleanup by EPA SW-846
Method 3650B
SOP for Soxhlet Extraction by EPA SW-846 Method 3540C
SOP for Preparation, Evaluation, and Shipping of
Performance Evaluation Samples for Method 24
Sample Extraction and Preparation for Energetic Organic
Material
SOP for Maintenance of NANOpure-A Deionized Water
System
SOP for Daily Maintenance of Cold Storage Units
SOP for Project Peer Review
SOP for Preparing Method 25 Audit Samples Using the
Transfill System
SOP for High Performance Liquid Chromatography
SOP for PDFID Sample Analysis
SOP for Standard Preparation Using Dynamic Flow Dilution
D-4
Rev
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
Issue Date
6/20/00
5/5/00
1/24/01
5/15/03
2/24/00
4/18/01
4/18/01
10/9/02
2/24/00
7/13/99
7/13/99
8/18/99
9/23/99
01/04
10/12/99
9/22/99
8/18/99
4/24/98
5/5/00
7/8/99
-------
Table D-2. List of ERG Standard Operating Procedures
SOP
No.
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
Dept
voc
GC
Transfill
VOC, Prep,
GC,MS
Transfill
VOC
All
Transfill
Transfill
GC/MS,
VOC
Optical
GC
Prep
Prep
Prep
GC/MS
GC/MS
GC/MS
GC/MS
Prep
SOP Title
System
SOP for UATMP and NMOC Canister Cleaning
SOP for the Analysis of Ambient Air for Hexavalent
Chromium by 1C
SOP for Shipping Method 6, 7, 8, and 26 Audit Samples
SOP for the ERG Sample Database
Cylinder Recycling
SOP for Producing Standard Mixtures of Organic Compounds
in Air by Liquid Injection
SOP for Refrigerator and Freezer Temperature Monitoring
SOP for Shipping Method 23 Audit Samples
SOP for Storing and Shipping Method 13A, 13B, and 29
Audit Samples
SOP for Documentation Requirements for the GC/MS
Laboratory and for GC/MS Systems in the VOC Laboratory
SOP for Stack Sampling Using FTIR Spectroscopy
SOP for the BCD Wipe Test
SOP for the Preparation of Spiked Sorbent Samples Using
Liquid Spiking into Tenax-GC* Tubes
SOP for the Preparation of Spiked Sorbent Samples Using
Liquid Spiking onto XAD-2®
SOP for the Preparation of Spiked Sorbent Samples Using
Flash Evaporation Spiking onto XAD-2®
SOP for Method 624
SOP for Method 625
SOP for Method 1624C
SOP for Method 1625C
SOP for the Preparation of Spiked Method 8 Samples as
Rev
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
Issue Date
7/8/99
5/8/03
10/31/01
7/8/99
5/5/00
6/20/00
2/29/00
9/23/99
9/23/99
8/18/99
3/31/03
Stationary Source Audit Materials
D-5
-------
EPA/600/R-07/005
February 2007
Source Sampling Fine Particulate Matter
Institutional Oil-Fired Boiler
Appendix E Chain of Custody Forms
-------
Appendix E
Chain of Custody Forms
-------
Campaign 1
Chain of Custody Forms
-------
Chain of Custody Record
Page ' of '
PROJECT
OIL
SITE
COLLECTED BY (Signature)
FIELD SAMPLE I.D. SAMPLE MATRIX
DATE/TIME
TAINERS
O. OF C
ANALYSES
\L
or
REMARKS
SAM ID NO.
(For lab use only)
• (1801
7P
v/
IB! <$H|
I/
C
H Ai
oo
613
6 A< L
I/
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P 12. tl oo
REMARKS:
*
RELINQUISHED BY:
DATE
TIME
RECEIVED BY:
DATE
TIME
RELINQUISHED BY:
DATE
TIME
RECEIVED BY:
DATE
TIME
RELINQUISHED BY:
PATE
TIME
LAB USE ONLY
RECEIVED FOR LABORATORY BY:
REMARKS:
DATE
TIME
AIRBILL NO.
OPENED BY
DATE
TIME
TEMP'C
SEAL #
CONDITION
-------
Chain of Custody Record
Page
- M
PROJECT
6
OIL
SITE
COLLECTED BY (Signature)
FIELD SAMPLE I.D. SAMPLE MATRIX
DATE/TIME
AINERS
CO
ANALYSES
0V
!L
IL
REMARKS
SAM ID NO.
(For lab use only)
B
1 (00 1
8l
I/
C
6 Bi
o/o8o/
H
V
REMARKS:
RELINjISHED BY:
DATE
TIME
RECEIVED BY:
DATE TIME
RELINQUISHED BY:
DATE TIME
RECEIVED BY:
DATE TIME
9
RELINQUISHED BY:
DATE
TIME
LAB USE ONLY
RECEIVED FOR LABORATORY BY:
REMARKS:
DATE
TIME
AIRBILL NO.
OPENED BY
DATE
TIME
TEMP"C
SEAL*
CONDITION
-------
Chain of Custody Record
Page.
„
PROJECT
SITE
COLLECTED BY (Signature)
FIELD SAMPLE I.D.
&ct /4
SAMPLE MATRIX
DATEATIME
CONTAINERS
NO.
ANALYSES
BY
REMARKS
SAM ID NO.
(For lab use only)
h to A. A
01
A
to k-i A
6
A.
W
01 C
+f
-------
EASTERN RESEARCH CROUP. INC.
PROJECT
sm! ŁfeNJ*BoŁo, NJC
COLLECTED BY (Signature)
FIELD SAMPLE I.D.
SAMPLE MATRIX
DATE/TIME
tl
\
^
1 fa
HzT?
REMARKS:
RECEIVED BY:
DATE
TIME
RELINQUISHED BY:
Chain of Custody Record
OF CONTAINERS
ANALYSES
0/
DATE
TIME
RECEIVED BY:
LAB USE ONLY
RECEIVED FOR LABORATORY BY:
DATE
TIME
AIRBILL NO.
OPENED BY
REMARKS:
V
I/
DATE
TIME
REMARKS
RELINQUISHED BY:
-M
RELINQUISHED BY:
DATE
TIME
TEMP°C
SEAL#
Page.
SAM ID NO.
(For lab use only)
DATE
DATE
TIME
TIME
CONDITION
-------
,1.6
CLEAN SUBSTRATES
Date Substrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
1/11/01
Rob Martz
Yuanji Dong
Total
Denuder
Quartz Filter
KOHQF
Teflo-washed
Teflo
Zeflo
PUF
50
t
-------
11*8
CLEAN SUBSTRATES
Date Substrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
1/11/01
Rob Martz
Yuanji Dong
Total
Denuder 6
Quartz Filter 32
KOHQF
Teflo-washed
Teflo
Zeflo
PUF
24
S3
4?
ft
?e
40
<&
x>
r?
't
1
"L
0
Y
*>
2
?>t
(
Type
Denuder
Denuder
Denuder
Denuder
Denuder
Denuder
QF r - - - *•
QF > ,
KjCn-»»f |Ł. #*f^l 1 •>
QF
QŁ>-* •*•*&* f
OF*-* «'.'-:
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
Clean Substrate ID
D071 000-1 01 3-6
D071 000-1 069-6
D071 800-995-2
D071 800-1 063-2
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EPA/600/R-07/005
February 2007
Source Sampling Fine Particulate Matter
Institutional Oil-Fired Boiler
Appendix F through Appendix K
-------
Appendix F
Sample Logs for Both Campaigns
-------
Table F-l. Campaign #1 Sample Log Summary
Test Date
1/16/01
1/17/01
1/18/01
Type of Test: Oil-fired boiler
Combustion:
Fuel Type
Fuel Mass, kg
Flue Gas Rate, scfm
Flue Gas, O2 %
CO2%
CO ppm
THC ppm
Sampling:
Sampling Time, min
Venturi Flow, slpm
Dilution Flow, slpm
Dilution Ratio
Emission:
8x10" Filter PM Mass, g
Mass/Flow, i-ig/L
PM2.5 Mass/Flow, jig/L
Mass/Fuel, g/kg
PM2.5 OC/Flow, ng/L
OC/Fuel, mg/kg
OC/TC, %
OC/PM, %
#2 Oil
6565.0
4290
6.0
15.0
0.03
600.33
18.53
847.89
46.81
no tare
0.0542
0.0282
0.0008
0.0004
34.4
1.6
Oil-fired boiler
#2 Oil
6925.5
4363
6.0
15.0
0.03
600.5
17.88
848.35
48.67
0.0209
0.0402
0.0604
0.0315
0.0065
0.0034
48.8
10.8
Oil-fired boiler
#2 Oil
7914.4
4658
6.0
15.0
0.03
600.17
19.01
850.66
45.91
0.03
0.0611
0.0783
0.0359
0.0063
0.0029
18.7
8.0
F-l
-------
Table F-2. Oil-Fired Institutional Boiler, Campaign #1, January 16, 2001
Test ID:
Sample
Log
Test Location:
Fuel Type: No. 2 Oil
IB011601H Oil fired industrial
boiler
Time, min: 600.33
Fuel Mass, kg: 6565
2058 gals 3.19 kg/gal
Heating
Value: 19374
Btu/lb
Dilution Ratio: 46.81
46.81
Port
Chamber # Position
RT 2 Al
Bl
3 Ml
M2
4 Al
Bl
5 M2
6 Ml
Substrate
TF
TF
DNPH
DNPH
TF
TF
SUMMA
D
Stack Flow, cfm: 4290
Holder PM
# Substrate ID mg
585 T041700H- 0.243
IB011601Hr2Al
614 T041700I- 0.267
IB011601Hr2Bl
610 T041700J- 0.267
IB011601Hr4Al
613 T062700F- 0.326
IB011601Hr4Bl
1063 D071800-1063-2-
IB011601Hr6Ml
No. of OC EC TC Flow PM OC Extraction Filter
punch ug/cm2 ug/cm2 mg SLPM ug/L ug/L Split
8.479 0.0477
8.479 0.0525
0.960
0.960
8.479 0.0525
8.479 0.0640
16.511 1/16/01
M2 D 995 D071800-995-2-
IB011601Hr6M2
16.511
1/16/01
F-2
-------
Table F-2. (Continued)
Port Holder
Chamber # Position Substrate # Substrate ID
PM No. of OC EC TC Flow PM OC Extraction Filter
mg punch ug/cm2 ug/cm2 mg SLPM ug/L ug/L Split
A3
A4
A5
B3
B4
B5
7 Ml
8 Ml
M2
A3
A4
A5
B3
B4
QF
PUF
PUF
QF
PUF
PUF
SMPS
D
D
QF
PUF
PUF
QF
PUF
642
L
L
481
I
I
1049
1261
622
B
B
640
H
Q010801B-
IB011601Hr6A3 **
P100400C-
IB011601Hr6A4
P100400F-
IB011601Hr6A5
Q010801C-
IB011601Hr6B3**
P100600B-
IB011601Hr6B4
P100600D-
IB011601Hr6B5
D071000-1049-6-
IB011601Hr8Ml
D010901-1261-1-
IB011601Hr8M2
Q010801D-
IB011601Hr8A3 **
P121200E-
IB011601Hr8A4
P121800N-
IB011601Hr8A5
Q010801E-
IB011601Hr8B3
P010801B-
IB011601Hr8B4
1 0.31 0.59 0.01 8.255
2
8.255
8.255
8.255
8.255
8.255
16.958
16.958
0 8.479
8.479
8.479
0 8.479
8.479
0.00 1/31/01**
084
1/31/01
1/31/01
**
1/31/01
1/31/01
1/16/01
1/16/01
**
2/7/01
1/31/01
**
2/7/01
1
1
1
1
F-2
-------
Table F-2. (Continued)
Port Holder PM No. of OC EC TC Flow PM OC Extraction Filter
Chamber # Position Substrate # Substrate ID mg punch ug/cm2 ug/cm2 mg SLPM ug/L ug/L Split
B5
10 Ml
M2
A3
A4
A5
B3
B4
B5
Dilution 1 Al
PUF
D
D
QF
PUF
PUF
QF
PUF
PUF
QF
H P010800D-
IB011601Hr8B5
1013 D071000-1013-6-
IB011601HrlOM
1 *
1259 D010901-1259-1-
IB011601HrlOM
2*
564 Q010801F-
IB011601HrlOA3
**
A P080900M-
IB011601HrlOA4
A P080900N-
IB011601HrlOA5
618 Q010801G-
IB011601HrlOB3
**
G P121200I-
IB011601HrlOB4
G P121200J-
IB011601HrlOB5
Average
Standard
Deviation
Relative Standard
Deviation, %
633 Q010801A-
IB011601HdlAl
8.479 1/31/01
16.511
16.511 1/16/01
0 8.255 1/16/01 1
8.255 **
8.255 2/7/01
0 8.255 2/7/01 1
8.255 2/7/01
8.255 2/7/01
0.05
42
0.00
69
12.8
2
1 3.09 0.25 0.04 8.442 0.00 5/18/01 1
5 820
F-4
-------
Table F-2. (Continued)
Port Holder
Chamber # Position Substrate #
Substrate ID
PM No. of OC EC TC Flow PM OC Extraction Filter
mg punch ug/cm2 ug/cm2 mg SLPM ug/L ug/L Split
A2 PUF
A3 PUF
Bl TF
2 Al DNPH
Bl DNPH
2 M2 SUMMA
Field Blank QF
TF
PUF
PUF
J P092700A-
IB011601HdlA2
J P092700B-
IB011601HdlA3
641 T041700G-
moneoiHdiBi o.oo
3
Q010901F-
IB011601HFB
T070700D-
IB011601HFB 0.00
7
IB011601H-P-
FB1
IB011601H-P-
FB2
8.442 3/1/01
8.442 3/7/01
8.442
1.447
1.447
3/2/01
3/2/01
* Composite of 6 denuders:
IBO11601HR6M1 ,-R6M2,-R8M 1 ,-R8M2,-Rl OM1, and-Rl OM2 with
40uLx6ofStd.#l
** Composite of 6 QF samples:IB011601HR6A3,-R6B3,-R8A3,-
R8B3, -R10A3, and R10B3
F-5
-------
Table F-2. (Continued)
Extracted Internal
Mass mg OC mg #1
240
0.240 0.004 125
125
125
0.268 0.004
125
125
0.276 0.004
125
125
0.276 0.004
125
125
0.268 0.004
125
125
0.268 0.004
125
125
0.0371 125
125
250
125
125
Std. jiL
#2
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
250
125
125
Filtration
1/29/01*
1/29/01*
1/31/01
2/1/01
2/1/01
**
2/5/01
2/5/01
1/29/01*
1/29/01*
**
2/15/01
2/6/01
**
2/12/01
2/6/01
1/29/01*
1/29/01*
**
2/9/01
2/9/01
**
2/9/01
2/9/01
5/18/01
3/8/01
3/16/01
3/16/01
Concentration, ^iL
Extract Derivat.
240 120
composite with R6M1
240 115
225 100
220 100
composite with R6A3
240 110
260 130
composite with R6M1
composite with R6M1
composite with R6A3
260 130
250 115
composite with R6A3
220 110
255 120
composite with R6M1
composite with R6M1
composite with R6A3
255 125
245 115
composite with R6A3
265 135
250 130
270 160
260 130
240 120
220 100
240 115
Neutral
110
115
110
110
115
115
115
125
100
120
120
115
120
105
100
120
110
110
115
F-6
-------
Figure F-2. (Continued)
Test ID: IB011601H
Institutional Boiler
Type of Test: stack
Test Location:
Fuel Type:
No2 Oil
Dilution Ratio: 46.81
Port
Chamber
Composite
RT
# Position
2 Al
Bl
3 Ml
M2
4 Al
Bl
5 M2
6 A4
A5
B4
B5
7 Ml
8 A4
Substrate
D
QF
TF
TF
DNPH
DNPH
TF
TF
SUMMA
PUF
PUF
PUF
PUF
SMPS
PUF
Time, min 600.33
Fuel Mass, kg: 6565
Air Rate, cfm: 4290
Extracted,
Holder mg
#
585
614
610
613
L
L
I
I
B
Substrate ID PM
IB011601H-
R6M1/2+R8M1/2+R10M1/2
IB011601H-
R6A3/B3+R8A3/B3+R10A3/
B3 1.596
T041700H-IB011601Hr2Al 0.239
T041700I-IB011601Hr2Bl 0.265
T041700J-IB011601Hr4Al 0.266
T062700F-IB011601Hr4Bl 0.326
P100400C-IB01 1601Hr6A4
P100400F-IB011601Hr6A5
P100600B-IB01 1601Hr6B4
P100600D-IB01 1601Hr6B5
P121200E-IB01 1601Hr8A4
Heating Value: 19374 Btu/lb
Internal Std.
|j,L Concentration
OC #1 #2
240
0.025 125 125
125 125
125 125
125 125
125 125
125 125
Extract uL
240
240
225
220
240
260
260
Derivat.
UL
120
115
100
100
110
130
130
F-7
-------
Table F-2. (Continued)
Port
Chamber # Position Substrate
A5
B4
B5
10 A4
A5
B4
B5
Dilution 1 Al
A2
A3
Bl
2 Al
Bl
2 M2
Field Blank
PUF
PUF
PUF
PUF
PUF
PUF
PUF
QF
PUF
PUF
TF
DNPH
DNPH
SUMMA
QF
TF
PUF
PUF
Extracted, Internal Std.
Holder mg p.L Concentration
# Substrate ID PM OC #1 #2 Extract uL
B
H
H
A
A
G
G
633
J
J
641
P121800N-IB011601Hr8A5
P010801B-IB01 1601Hr8B4
P010800D-IB011601Hr8B5
P080900M-
IB011601HrlOA4
P080900N-IB01 1601HrlOA5
P121200I-IB01 1601HrlOB4
P121200J-IB01 1601HrlOB5
Average
Standard Deviation
Relative Standard Deviation,
Q010801A-IB011601HdlAl
P092700A-IB01 1601HdlA2
P092700B-IB01 1601HdlA3
T041700G-IB011601HdlBl -0.008
Q010901F-IB011601HFB
T070700D-IB011601HFB -0.007
IB011601H-P-FB1
IB011601H-P-FB2
125
125
125
125
125
125
125
125
125
250
125
125
125
125
125
125
125
125
125
250
250
220
255
255
245
265
250
270
260
240
Derivat.
UL
115
110
120
125
115
135
130
160
130
120
F-8
-------
Table F-2. (Continued)
Methylation Silylation GC/MS 1C XRF
Date Vol. uL Date File ID File ID Extract mL Job No.
2/15/01 130
3/27/01 139
2/15/01 127
F-9
-------
Table F-3. Oil-Fired Institutional Boiler, Campaign #1, January 17, 2001
Sample Log Test ID: IB011701H
Test Location:
Fuel Type:
Dilution Ratio:
Port
Chamber #
RT 2
3
4
5
6
7
8
No. 2
Oil
48.67
Position
Al
Bl
Ml
M2
Al
Bl
M2
Al
A2
A3
Bl
B2
B3
Ml
Al
A2
A3
Bl
B2
Substrate
TF
TF
DNPH
DNPH
TF
TF
SUMMA
QF
PUF
PUF
QF
PUF
PUF
SMPS
QF
PUF
PUF
QF
PUF
Holder
#
585
614
610
613
642
L
L
481
I
I
622
B
B
640
H
Time, min: 600.5
Fuel Mass, kg: 6925.5
Stack Flow, cfm: 4363
PM
Substrate ID mg
T070700C-IB011701Hr2Al 0.303
T070700E-IB011701Hr2Bl 0.304
T062900D-IB011701Hr4Al 0.298
T062900F-IB011701Hr4Bl 0.337
Q010901A-IB011701Hr6Al *
P092600F-IB01 1701Hr6A2
P092700E-IB01 1701Hr6A3
Q010901B-IB011701Hr6Bl *
P092600E-IB01 1701Hr6B2
P092600A-IBO 1 1 70 1 Hr6B3
Q010901I-IB011701Hr8Al *
P010801E-IB011701Hr8A2
P010801F-IB011701Hr8A3
Q010901H-IB011701Hr8Bl *
P100400A-IB011701Hr8B2
2171 gals 3.19
No. of OC EC TC
punch ug/cm2 ug/cm2 mg
1 2.39 2.51 0.066
F-10
-------
Table F-3. (Continued)
Port
Chamber # Position
B3
10 Al
A2
A3
Bl
B2
B3
Dilution 1 Al
A2
A3
Bl
2 Al
Bl
2 M2
Substrate
PUF
QF
PUF
PUF
QF
PUF
PUF
QF
PUF
PUF
TF
DNPH
DNPH
SUMMA
Holder
#
H
564
A
A
618
D
D
633
J
J
641
PM
Substrate ID mg
P100400D-IB01 1701Hr8B3
Q010901E-IB011701HrlOAl *
P010801A-IB01 1701HrlOA2
P100600C-IB01 1701HrlOA3
Q010901K-IB011701HrlOBl *
P121800P-IB011701HrlOB2
P121200K-IB01 1701HrlOB3
Average
Standard Deviation
Relative Standard Deviation, %
Q010801K-IB011701HdlAl **
P121200F-IB011701HdlA2
P121200G-IB011701HdlA3
T070700F-IB011701HdlBl -0.007
No. of OC EC TC
punch ug/cm2 ug/cm2 mg
1 2.39 0.20 0.035
* Composited with residence chamber QF samples from January 18. 2001
** Composited with dilution air QF sample from January 18, 2001
F-ll
-------
Table F-3. (Continued)
8x10" Filter Catch, g: 0.0209
kg/gal
Heating Value: 19374
Btu/lb
Flow PM OC Extraction Filter Extracted Internal Std. \iL Filtration Concentration, u,L
SLPM ug/L ug/L Split Mass mg OC mg #1 #2 Extract Derivat. Neutral
8
8
0
0
8
8
8
8
8
8
8
8
8
8
8
8
8
8
.580 0.0588
.580 0.0590
.959
.959
.542 0.0581
.542 0.0657
.242
.242
.242
.242
.242
.242
.542
.542
.542
.542
.542
.542
0.00649 1
2/22/01
2/22/01
* 1
2/22/01
2/22/01
* 1
2/22/01
3/7/01
* 1
3/9/01
3/9/01
0.267 0.029
125
125
0.299 0.032
125
125
0.310 0.033
125
250
0.310 0.033
125
125
125
125
125
125
125
250
125
125
composite,
3/9/01
4/24/01
composite,
3/13/01
3/13/01
composite,
3/13/01
3/13/01
composite,
3/12/01
4/24/01
refer to
215
250
refer to
260
245
refer to
260
260
refer to
230
240
Page 2 of
110
165
Page 2 of
135
125
Page 2 of
135
140
Page 2 of
105
120
11/17
95
105
11/17
115
110
11/17
100
110
11/17
115
110
F-12
-------
Table F-3. (Continued)
Flow PM OC Extraction Filter Extracted Internal Std. \iL
SLPM us/L U2/L Split Massms OC ms #1 #2
8
8
8
8
8
8
.242
.242
.242
.242
.242
.242
0.0604
0.0036
5.88
* 1 0.299 0.032
3/7/01 250
2/22/01 125
* 1 0.299 0.032
3/2/01 125
3/12/01 125
250
125
125
125
Filtration Concentration, u.L
Extract Derivat.
composite,
4/24/01
3/9/01
composite,
3/15/01
3/15/01
refer to
250
220
refer to
205
260
Page 2 of
140
100
Page 2 of
100
140
Neutral
11/17
100
110
11/17
95
110
.656
.656
.656
0.00618
3/1/01
3/7/01
0.029 composite, refer to Page 2 of 11/17
125 125 3/16/01 255 140 105
250 250 3/7/01 230 110 110
F-13
-------
Table F-3. (Continued)
Test ID: IB011701H
Test Location: NC A&T Greensboro
Fuel Type: No2 Oil
Dilution Ratio: 48.67
Port Holder
Chamber # Position Substrate #
Composite
RT
Composite
Dilution
RT
ID:
6
8
10
6
8
10
ID:
1
1
2
3
IB011701&011801-RT-QF
Al
Bl
Al
Bl
Al
Bl
Al
Bl
Al
Bl
Al
Bl
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
QF
642
481
622
640
564
618
642
481
622
640
564
618
IB011701&011801-DL-QF
Al
Al
Al
Bl
Ml
M2
QF
QF
TF
TF
DNPH
DNPH
633
633
585
614
Type of Test: Oil fired Institutional Boiler
Time, min: 600.5
Fuel Mass, kg: 6925.5
Stack Flow, cfm: 4363
Extracted, mg Internal Std. u.L
Substrate ID PM OC #1 #2
4.105 0.377 125 125
Q010901A-IB011701Hr6Al
Q010901B-IB011701Hr6Bl
Q010901I-IB011701Hr8Al
Q010901H-IB011701Hr8Bl
Q010901E-IB011701HrlOAl
Q010901K-IB011701HrlOBl
Q010801I-IB011801Hr6Al
Q010801J-IB011801Hr6Bl
Q010801L-IB011801Hr8Al
Q010801M-IB011801Hr8Bl
Q010801N-IB011801HrlOAl
Q010801O-IB011801HrlOBl
0.058 125 125
Q010801K-IB011701HdlAl
Q010801H-IB011801HdlAl
T070700C-IB011701Hr2Al
T070700E-IB011701Hr2Bl
F-14
-------
Table F-3. (Continued)
Port Holder
Chamber # Position Substrate #
Substrate ID
Extracted, mg
PM OC
Internal Std. \iL
#1 #2
4 Al
Bl
5 M2
6 A2
A3
B2
B3
7 Ml
8 A2
A3
B2
B3
10 A2
A3
B2
B3
Dilution 1 A2
A3
Bl
2 Al
Bl
2 M2
TF
TF
SUMMA
PUF
PUF
PUF
PUF
SMPS
PUF
PUF
PUF
PUF
PUF
PUF
PUF
PUF
PUF
PUF
TF
DNPH
DNPH
SUMMA
610
613
L
L
I
I
B
B
H
H
A
A
D
D
J
J
641
T062900D-IBO 1 1 70 !Hr4A 1
T062900F-IB011701Hr4Bl
P092600F-IB01 1701Hr6A2
P092700E-IB01 1701Hr6A3
P092600E-IB01 1701Hr6B2
P092600A-IB01 1701Hr6B3
P010801E-IB011701Hr8A2
P010801F-IB011701Hr8A3
P100400A-IB011701Hr8B2
P100400D-IB011701Hr8B3
P010801A-IB011701HrlOA2
P100600C-IB01 1701HrlOA3
P121800P-IB011701HrlOB2
P121200K-IB011701HrlOB3
P121200F-IB011701HdlA2
P121200G-IB011701HdlA3
T070700F-IB011701HdlBl
125
125
125
125
125
250
125
125
250
125
125
125
125
250
125
125
125
125
125
250
125
125
250
125
125
125
125
250
F-15
-------
Table F-3. (Continued)
8x10" Filter Catch, g: 0.0209
Heating Value: 19374 Btu/lb
Extract, \iL
Total
245
240
215
250
260
245
260
260
230
240
250
220
205
260
255
230
Derivat.
125
120
110
165
135
125
135
140
105
120
140
100
100
140
140
110
Methylation Silylation GC/MS 1C XRF
Neutral Date Vol. uL Date File ID File ID Extract mL Job No.
110
110
95
105
115
110
100
110
115
110
100
110
95
110
105
110
F-16
-------
Table F-4. Oil-Fired Institutional Boiler, Campaign #1, January 18, 2001
Sample Log Test ID: IB011801H
Test Location: NC A&T Greensboro
Fuel Type: No. 2 Oil
Dilution Ratio: 45.91
Port Holder
Chamber # Position Substrate #
RT 2 Al
Bl
3 Ml
M2
4 Al
Bl
5 M2
6 Al
A2
A3
Bl
B2
B3
7 Ml
8 Al
A2
A3
Bl
B2
TF
TF
DNPH
DNPH
TF
TF
SUMMA
QF
PUF
PUF
QF
PUF
PUF
SMPS
QF
PUF
PUF
QF
PUF
585
614
610
613
642
L
L
481
I
I
622
B
B
640
H
Time, min: 600.17
Fuel Mass, kg: 7914.4 2481 gals 3.19
Stack Flow, cfm: 4658
PM No. of OC EC TC
Substrate ID mg punch ug/cm2 ug/cm2 mg
T062900C-IB011801Hr2Al 0.398
T062900E-IB011801Hr2Bl 0.402
T062900A-IB011801Hr4Al 0.387
T062900B-IB011801Hr4Bl 0.408
Q010801I-IB011801Hr6Al * 1 2.37 10.31 0.171
P121200A-IB011801Hr6A2
P121200B-IB011801Hr6A3
Q010801J-IB011801Hr6Bl *
P010901C-IB011801Hr6B2
P010901E-IB011801Hr6B3
Q010801L-IB011801Hr8Al *
P100400B-IB011801Hr8A2
P100400E-IB011801Hr8A3
Q010801M-IB011801Hr8Bl *
P100600A-IB011801Hr8B2
F-17
-------
Table F-4. (Continued)
Port
Chamber # Position
B3
10 Al
A2
A3
Bl
A2
A3
Dilution 1 Al
A2
A3
Bl
2 Al
Bl
2 M2
Substrate
PUF
QF
PUF
PUF
QF
PUF
PUF
QF
PUF
PUF
TF
DNPH
DNPH
SUMMA
Holder
#
H
564
A
A
618
C
C
633
J
J
641
Substrate ID
P100600E-IB011801Hr8B3
Q010801N-IB011801HrlOAl
P010901A-IB011801HrlOA2
P010901B-IB011801HrlOA3
Q010801O-IB011801HrlOBl *
P121200C-IB011801HrlOB2
P121200D-IB011801HrlOB3
Average
Standard Deviation
Relative Standard Deviation, %
Q010801H-IB011801HdlAl **
P092600B-IBO 1 1 80 IHd 1 A2
P092600D-IB01 1801HdlA3
T070500A-IB011801HdlBl
PM No. of OC EC TC
mg punch ug/cm2 ug/cm2 mg
1 2.46 0.18 0.036
-0.007
* Composited with residence chamber QF samples from January 17, 2001
** Composited with dilution air QF sample from January 17, 2001
F-18
-------
Table F-4. (Continued)
8x10" Filter Catch, g: 0.0319
kg/gal
Heating Value: 19374 Btu/lb
Flow
SLPM
8.489
8.489
1.121
1.121
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.489
8.191
PM OC Extraction Filter
[ig/L u,g/L Split
0.0781
0.0789
0.0760
0.0801
0.00626 1
3/1/01
3/9/01
* 1
3/1/01
3/1/01
* 1
3/1/01
3/2/01
* 1
3/9/01
3/7/01
* 1
Extracted Internal
Mass mg OC #1
mg
0.356 0.028
125
250
0.399 0.032
125
125
0.399 0.032
125
125
0.399 0.032
125
250
0.385 0.031
Std. \iL
#2
125
250
125
125
125
125
125
250
Filtration Concentration, \iL
Extract Derivat.
composite, refer to
4/25/01 250
3/9/01 250
composite, refer to
3/19/01 250
3/19/01 260
composite, refer to
3/15/01 220
3/15/01 260
composite, refer to
3/12/01 270
3/9/01 200
composite, refer to
Page 2 of
130
130
Page 2 of
130
135
Page 2 of
105
140
Page 2 of
140
90
Page 2 of
Neutral
11/17
110
110
11/17
110
115
11/17
105
110
11/17
120
100
11/17
F-19
-------
Table F-4. (Continued)
Flow PM OC
SLPM [ig/L p,g/L
8.191
8.191
8.191
8.191
8.191
0.0783
0.0017
2.22
8.564 0.00644
8.564
8.564
8.564 0.00000
1.168
1.168
Extraction
3/12/01
3/2/01
*
3/2/01
3/9/01
3/12/01
3/12/01
Filter Extracted Internal
Split Massing OC #1
mg
125
125
1 0.385 0.031
125
125
1 0.030
125
125
Std. p.!
#2
125
125
125
125
125
125
-/ Filtration Concentration, jiL
Extract Derivat.
3/16/01 200
3/16/01 250
composite, refer to
4/25/01 210
4/25/01 245
composite, refer to
4/25/01 270
3/12/01 240
90
130
Page 2 of
100
125
Page 2 of
145
115
Neutral
100
110
11/17
100
115
11/17
115
115
F-20
-------
Table F-4. (Continued)
Test ID:
Test Location:
Fuel Type:
Dilution Ratio:
Port
Chamber #
RT 2
3
4
5
6
7
8
10
IB011801H
NC A&T Greensboro
No. 2
Oil
45.91
Positio
n
Al
Bl
Ml
M2
Al
Bl
M2
A2
A3
B2
B3
Ml
A2
A3
B2
B3
A2
A3
A2
A3
Substrate
TF
TF
DNPH
DNPH
TF
TF
SUMMA
PUF
PUF
PUF
PUF
SMPS
PUF
PUF
PUF
PUF
PUF
PUF
PUF
PUF
Holder
#
585
614
610
613
L
L
I
I
B
B
H
H
A
A
C
C
Type of Test: Oil fired Institutional Boiler
Time, min 600.17
Fuel Mass, kg: 0
Air Rate, SLPM: 4658
PM OC Internal Std. [iL
Substrate ID mg mg #1 #2
T062900C-IB011801Hr2Al 0.398
T062900E-IB011801Hr2Bl 0.402
T062900A-IB011801Hr4Al 0.387
T062900B-IB011801Hr4Bl 0.408
P121200A-IB011801Hr6A2
P121200B-IB011801Hr6A3
P010901C-IB011801Hr6B2
P010901E-IB011801Hr6B3
P100400B-IB011801Hr8A2
P100400E-IB011801Hr8A3
P100600A-IB011801Hr8B2
P100600E-IB011801Hr8B3
P010901A-IB011801HrlOA2
P010901B-IB011801HrlOA3
P121200C-IB011801HrlOB2
P121200D-IB011801HrlOB3
F-21
-------
Table F-4. (Continued)
Chamber
Port Holder
# Position Substrate #
Substrate ID
PM OC Internal Std. u.L
mg mg #1 #2
Dilution
Blank
A2
A3
Bl
Al
Bl
M2
PUF
PUF
TF
DNPH
DNPH
SUMMA
PUF
J
J
641
Average
Standard Deviation
Relative Standard Deviation, %
P092600B-IB011801HdlA2
P092600D-IB011801HdlA3
T070500A-IB011801HdlBl
-0.007
P080200B-IB080900HBLNK
F-22
-------
Table F-5. Oil-Fired Institutional Boiler, Campaign #2, July 9, 2002
Sample Log Test ID: IB070902H
Venturi, std. m3:
Test Location:
Fuel Type: No. 2 Oil
Port
Chamber # Position
RT 2 Al
A2
Bl
B2
4 Al
A2
Bl
B2
5 Al
A2
A3
Bl
B2
B3
B4
6 Al
A2
A3
Time, min 600.6 Dilution, std. m3:
Dilution Ratio:
Holder PM No. of QC EC ocx Flow
Substrate # Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2 SLPM
TF
QF
TF
QF
TF
QF
TF
QF
D
D
TF
D
D
TF
NF
QF
PUF
PUF
564
564
613
613
633
633
641
641
73G10
F16
1185
79G14
F18
1246
1246
618
F
F
1007993 0.292
Q060602K-IB070902HR2A2 1 10.28 0.22 0.39
*
1007994 0.284
Q060602L-IB070902HR2B2
*
1007995 0.278
Q060602M- 1 10.47 0.1 0.24
IB070902HR4A2 *
1008951 0.266
Q060602N-IB070902HR4B2
*
73G10
F16
1008952 0.120
79G14
F18
1008953 0.156
NF-1
Q060602A-IB070902HR6A1 1 20.42 1.77 3.23
**
P01 1702A-IB070902HR6A2
P01 1702B-IB070902HR6A3
8.251
8.251
8.251
8.251
8.106
8.106
8.106
8.106
4.518
4.518
4.518
4.518
4.518
4.518
4.518
8.215
8.215
8.215
F-23
-------
Table F-5. (Continued)
Port
Chamber # Position
A4
A5
Bl
B2
B3
B4
B5
8 Al
A2
A3
A4
A5
Bl
B2
B3
B4
B5
Substrate
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
PUF
PUF
Holder
#
G
G
642
H
H
I
I
585
B
B
C
C
481
D
D
E
E
PM No. of OC EC OCX
Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2
P01 1702C-IB070902HR6A4
P01 1702D-IB070902HR6A5
Q060602B-IB070902HR6B 1
**
P01 1702E-IB070902HR6B2
P01 1702F-IB070902HR6B3
P01 1502A-IB070902HR6B4
P01 1502B-IB070902HR6B5
Q060602C-IB070902HR8A1 1 21.04 1.3 3.12
#
P01 1502C-IB070902HR8A2
P01 1502D-IB070902HR8A3
P01 1502E-IB070902HR8A4
P01 1502F-IB070902HR8A5
Q060602D-IB070902HR8B 1
#
P012202A-IB070902HR8B2
P012202B-IB070902HR8B3
P012202C-IB070902HR8B4
P012202D-IB070902HR8B5
Flow
SLPM
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.288
8.288
8.288
8.288
8.288
8.288
8.288
8.288
8.288
8.288
F-24
-------
Table F-5. (Continued)
Port
Chamber # Position
Sample Log, July 9, continued
10 Al
A2
A3
A4
A5
Bl
B2
B3
B4
B5
Dilution 1 Al
A2
A3
Bl
Substrate
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
TF
Holder
#
610
J
J
K
K
622
L
L
M
M
640
A
A
614
PM No. of OC EC OCX
Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2
Q060602E- 1 19.55 1.34 3.04
IB070902HR10A1 **
P012202E-
IB070902HR10A2
P012202F-
IB070902HR10A3
P012202G-
IB070902HR10A4
P012302A-
IB070902HR10A5
Q060602F-
IB070902HR10B1 **
P012302B-
IB070902HR10B2
P012302C-
IB070902HR10B3
P012302D-
IB070902HR10B4
P012302E-
IB070902HR10B5
Q060602G- 1 0.90 0.11 0.00
IB070902HD1A1
P012302F-IB070902HD1A2
P012302G-IB070902HD1A3
1007992 0.003
Flow
SLPM
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
8.215
F-25
-------
Table F-5. (Continued)
Port
Chamber # Position
Field Blank
Substrate
QF
TF
NF
PUF
PUF
Holder PM No. of OC EC OCX
# Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2
Q060702C-IB070902H-FB
1008954 0.006
NF-2
P020 1 02T-IB070902H-FB 1
P020802A-IB070902H-FB2
Flow
SLPM
* Composited with residence chamber port 2, A2
** Composited with residence chamber port 6, Al
# archived
F-26
-------
Table F-5. (Continued)
11.32 Fuel Mass, kg:
490.26 Air Flow, scfm:
44.31 8x10" Filter Catch, g:
PM OC Extraction Fliter Extracted, mg
ms/L ms/L Split Mass OC
0.000059
1 0.123
0.000057
1 0.138
0.000057
1 0.126
0.000055
1 0.141
0.000044
0.000057
1 0.251 0.245
9/3/02
9/3/02
9/3/02
9/3/02
1 0.281 0.275
9/3/02
9/3/02
9/3/02
9/3/02
1 0.253 0.252
8/30/02
4445.0
4551
0.051
Internal Std. uL Filtration
#1 #2
composite
composite with R2A2
composite with R2A2
composite with R2A2
composite
125 125 9/6/02
125 125 9/6/02
125 125 9/6/02
125 125 9/6/02
composite with R6A1
125 125 9/9/02
125 125 9/9/02
125 125 9/9/02
125 125 9/9/02
Archive
125 125 9/5/02
8x10" blank: 0.0011
Concentration, uL
Extract Derivat.
250
270
280
240
260
270
190
230
270
140
140
140
120
130
140
100
120
140
Neutral
120
130
140
120
130
130
90
120
130
F-27
-------
Table F-5. (Continued)
PM OC Extraction Fliter
mg/L mg/L Split
8/30/02
8/30/02
8/30/02
1
8/30/02
8/30/02
8/30/02
8/30/02
1
8/28/02
8/28/02
8/28/02
8/28/02
1
8/28/02
8/28/02
8/28/02
8/28/02
1
9/10/02
9/10/02
0.000001
9/13/02
9/13/02
Extracted, mg Internal
Mass OC #1
125
125
125
0.284 0.283 Archive
125
125
125
125
Std. uL
#2
125
125
125
125
125
125
125
0.251 0.235 composite with
125
125
125
125
125
125
125
125
0.281 0.263 composite with
125
125
125
125
0.003 0.011
125
125
125
125
125
125
125
125
125
125
125
125
Filtration
9/5/02
9/5/02
9/5/02
8/30/02
8/30/02
8/30/02
8/30/02
R6A1
8/29/02
8/29/02
8/29/02
8/29/02
R6A1
9/5/02
9/5/02
9/5/02
9/5/02
9/11/02
9/11/02
9/23/02
9/23/02
Concentration, uL
Extract Derivat. Neutral
250
250
250
240
270
260
260
260
280
260
250
250
220
220
220
260
260
250
220
130
130
130
120
140
130
130
130
140
130
130
130
120
120
120
130
130
130
110
120
120
120
120
130
130
130
130
140
130
120
120
100
100
100
130
130
120
110
F-28
-------
Table F-5. (Continued)
Test ID:
Location:
Fuel Type:
Substrate
TF
QF
PUF
IB070902H
NC A&T Greensboro
No2 Oil
Substrate ID
1007993
1007994
1007995
1008951
1008952
1008953
1007992
1008954
Q060602K-IB070902HR2A2
Q060602L-IB070902HR2B2
Q060602M-IB070902HR4A2
Q060602N-IB070902HR4B2
Q060602A-IB070902HR6A1
Q060602B-IB070902HR6B 1
Q060602E-IB070902HR1 OA 1
Q060602F-IB070902HR1 OB 1
Q060602C-IB070902HR8 A 1
Q060602D-IB070902HR8B 1
Q060602G-IB070902HD 1 A 1
Q060702C-IB070902H-FB
PO 1 1 702A-IB070902HR6A2
Type of Test:
Time, min
Chamber Port
RT
RT
RT
RT
RT
RT
DL
Field
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
Field
RT
#
2
2
4
4
5
5
1
Blank
2
2
4
4
6
6
10
10
8
8
1
Blank
6
Oil fired Institutional Boiler Venturi, std. m3: 11.32
600.6 Dilution, std. m3: 490.26
Position
Al
Bl
Al
Bl
A3
B3
Bl
A2
B2
A2
B2
Al
Bl
Al
Bl
Al
Bl
Al
A2
Holder
#
564
613
633
641
1185
1246
614
564
613
633
641
618
642
610
622
585
481
640
F
Dilution Ratio: 44.31
No. of punch Composite ID Extracted , mg
Mass OC
0.292
0.284
0.278
0.266
0.12
0.156
0.003
0.006
2 IB070902HR2&R4 0.528
2 IB070902H 1.064 1.017
R6&R10
1 IB070902HD1 0.003 0.011
F-29
-------
Table F-5. (Continued)
Substrate Substrate ID
P01 1702B-IB070902HR6A3
P01 1702C-IB070902HR6A4
PO 1 1 702D-IB070902HR6A5
P01 1702E-IB070902HR6B2
P011702F-IB070902HR6B3
P01 1502A-IB070902HR6B4
P01 1502B-IB070902HR6B5
P01 1502C-IB070902HR8A2
P01 1502D-IB070902HR8A3
P01 1502E-IB070902HR8A4
P01 1502F-IB070902HR8A5
P012202A-IB070902HR8B2
P012202B-IB070902HR8B3
P012202C-IB070902HR8B4
P012202D-IB070902HR8B5
P012202E-IB070902HR10A2
P012202F-IB070902HR10A3
P012202G-IB070902HR10A4
P012302A-IB070902HR10A5
P012302B-IB070902HR10B2
P012302C-IB070902HR10B3
P012302D-IB070902HR10B4
P012302E-IB070902HR10B5
P012302F-IB070902HD1A2
P012302G-IB070902HD1A3
P020 1 02T-IB070902H-FB 1
P020802A-IB070902H-FB2
Chamber Port
#
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
DL
Field
Field
6
6
6
6
6
6
6
8
8
8
8
8
8
8
8
10
10
10
10
10
10
10
10
1
1
Blank
Blank
Position
A3
A4
A5
B2
B3
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
Holder No. of punch Composite ID Extracted , mg
# Mass OC
F
G
G
H
H
I
I
B
B
C
C
D
D
E
E
J
J
K
K
L
L
M
M
A
A
F-30
-------
Table F-5. (Continued)
Fuel Mass, kg: 4445.0
Air Flow, scfm: 4551
Internal
#1
150
150
100
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
Std. uL
#2
150
150
100
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
8x10" Filter Catch, g: 0.051 8x10" blank: 0.0011
Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
Total Derivat. Neutral
250
270
280
240
260
270
190
230
270
250
250
250
240
270
260
260
260
280
260
250
140
140
140
120
130
140
100
120
140
130
130
130
120
140
130
130
130
140
130
130
120
130
140
120
130
130
90
120
130
120
120
120
120
130
130
130
130
140
130
120
F-31
-------
Table F-5. (Continued)
Internal Std. uL Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
#1 #2 Total Derivat. Neutral
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
250
220
220
220
260
260
250
220
130
120
120
120
130
130
130
110
120
100
100
100
130
130
120
110
F-32
-------
Table F-6. Oil-Fired Institutional Boiler, Campaign #2, July 9, 2002
ELPI Stage Mass
Test ID: IB070902H
Test Location:
Type of Test: Industrial Boiler
Fuel Type: No. 2 Oil
Sampling Location: Residence chamber - Port #7
ELPI flow, SLPM:
ELPI Dilution Ratio:
ELPI Unit No.:
ELPI Flow Data
Sampling start
Sampling end
Sampling time, min
Sampler
DR
Gravimetric Analysis
9.61
1
292
8:01:08
18:01:44
600.6
1
F-33
-------
Table F-6. (Continued)
Stage
1
2
3
4
5
6
7
8
9
10
11
12
13
BLANK
Substrate ID
A062 1 02M-IB070902H-ELPI 1
A062 1 02L-IB070902H-ELPI2
A062 1 02K-IB070902H-ELPI3
A062 1 02J-IB070902H-ELPI4
A062 1 02I-IB070902H-ELPI5
A062 1 02H-IB070902H-ELPI6
A062 1 02G-IB070902H-ELPI7
A062 1 02F-IB070902H-ELPI8
A062 1 02E-IB070902H-ELPI9
A062 1 02F-IB070902H-ELPI 1 0
A062 1 02C-IB070902H-ELPI 1 1
A062 1 02B-IB070902H-ELPI 12
A062 1 02A-IB070902H-ELPI 1 3
A062 1 02N-IB070902H-ELPI-FB
PM, mg
0.037
0.039
0.025
0.021
0.009
0.012
0.006
0.004
0.023
0.015
0.012
0.012
-0.006
0.002
Net PM mg
0.035
0.037
0.023
0.019
0.007
0.01
0.004
0.002
0.021
0.013
0.01
0.01
0
Mass Cone TDS
me/m3
0.0061
0.0064
0.0040
0.0033
0.0012
0.0017
0.0007
0.0003
0.0036
0.0023
0.0017
0.0017
0.0000
F-34
-------
Table F-7. Oil-Fired Institutional Boiler - Campaign #2, July 10, 2002
Sample Log Test IB071002H
ID:
Venturi, std. m3:
Test Location:
Fuel Type: No2 Oil
Port
Chamber # Position
RT 2 Al
A2
Bl
B2
4 Al
A2
Bl
B2
5 Al
A2
A3
Bl
B2
B3
B4
6 Al
A2
A3
A4
A5
Bl
B2
B3
Substrate
TF
QF
TF
QF
TF
QF
TF
QF
D
D
TF
D
D
TF
NF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
Time, min 600.67 Dilution, std. m3:
Dilution Ratio:
Holder PM No. of OC EC OCX Flow
# Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2 SLPM
564
564
613
613
633
633
641
641
1185
1246
1246
618
642
1008958 0.3
Q060702A-IB071002HR2A2 * 1 10.57 0.18 0.32
1008959 0.302
Q060702B-IB071002HR2B2 *
1008956 0.267
Q060602Y-IB071002HR4A2 * 1 8.68 0.12 0.20
1008957 0.27
Q060602Z-IB071002HR4B2 *
72G16
F17
1008960 0.135
75G13
F15
1008961 0.138
NF-3
Q060602V-IB071002HR6A1 * 1 20.58 1.03 4.07
P020 1 02 J-IB07 1 002HR6A2
P020 1 02K-IB07 1 002HR6A3
P020 1 02L-IB07 1 002HR6A4
P020 1 02M-IB07 1 002HR6A5
Q060602W-IB071002HR6B1 **
P020 1 02N-IB07 1 002HR6B2
P020 1 02O-IB07 1 002HR6B3
8.183
8.183
8.183
8.183
8.075
8.075
8.075
8.075
4.593
4.593
4.593
4.593
4.593
4.593
4.593
8.219
8.219
8.219
8.219
8.219
8.219
8.219
8.219
F-35
-------
Table F-7.
Chamber
Sample Log,
Dilution 1
(Continued)
Port
# Position
B4
B5
8 Al
A2
A3
A4
A5
Bl
B2
B3
Substrate
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
Holder PM No. of OC EC OCX
# Substrate ID mg punch ug/cm2 ug/cm2 ug/cm2
P020 1 02P-IB07 1 002HR6B4
P020 1 02Q-IB07 1 002HR6B5
585 Q060602T-IB071002HR8A1 # 1 21.35 0.86 4.33
P020 1 02B-IB07 1 002HR8A2
P020 1 02C-IB07 1 002HR8A3
P020 1 02D-IB07 1 002HR8 A4
P020 1 02E-IB07 1 002HR8 A5
481 Q060602U-IB071002HR8B1#
P020 1 02F-IB07 1 002HR8B2
P020 1 02G-IB07 1 002HR8B3
Flow
SLPM
8.219
8.219
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
July 10, continued
B4
B5
10 Al
A2
A3
A4
A5
Bl
B2
B3
B4
B5
Al
A2
A3
Bl
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
TF
P020 1 02H-IB07 1 002HR8B4
P020 1 02I-IB07 1 002HR8B5
610 Q060602R-IB071002HR10A1 ** 1 18.87 0.8 3.65
P012902B-IB071002HR10A2
PO 1 2902C-IB07 1 002HR1 OA3
P012902D-IB071002HR10A4
PO 1 2902E-IB07 1 002HR1 OA5
622 Q060602S-IB071002HR10B1 **
P012902F-IB071002HR10B2
PO 12902G-IB07 1 002HR1 OB3
PO 1 2902H-IB07 1 002HR1 OB4
P020102A-IB071002HR10B5
640 Q060602X-IB071002HD1A1 1 0.88 0.08 0.00
P020102R-IB071002HD1A2
P020102S-IB071002HD1A3
614 1008955 0.002
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.183
8.219
8.219
8.219
8.219
* Composite with residence chamber port 2, A2
** Composite with residence chamber port 6, Al
F-36
-------
Table F-7. (Continued)
11.29 Fuel Mass, kg: 4464.6
489.2 Air Flow, scfm: 4574.5
44.37 8x10" Filter Catch, g: 0.0463 8x10" blank: 0.0011
PM OC Extrac- Filter Extracted, mg Internal Std. uL Filtration Concentration, uL
ms/L ms/L tion Split Mass OC #1 #2 Extract Derivat. Neutral
0.000061
0.000061
0.000055
0.000056
0.000049
0.000050
9/16/02
9/16/02
9/16/02
9/16/02
9/23/02
9/23/02
9/23/02
9/23/02
1 0.127
1 0.142
1 0.104
1 0.117
1 0.257 0.247
125
125
125
125
1 0.288 0.277
125
125
125
125
composite
composite with R2A2
composite with R2A2
composite with R2A2
composite
125 9/19/02 290
125 9/19/02 260
125 9/19/02 260
125 9/19/02 260
composite with R6A1
125 9/24/02 230
125 9/24/02 230
125 9/24/02 230
125 9/24/02 250
150 150
130 130
130 130
130 130
120 110
120 110
120 110
130 120
1 0.256 0.256 archive
9/30/02
9/30/02
9/30/02
9/30/02
125
125
125
125
125
125
125
125
F-37
-------
Table F-7. (Continued)
PM OC Extrac- Fliter Extracted, mg
mg/L mg/L tion Split Mass OC
1 0.287 0.287
9/16/02
9/16/02
9/16/02
9/16/02
1 0.256 0.226
9/30/02
9/30/02
9/30/02
9/30/02
1 0.287 0.254
9/30/02
9/30/02
9/30/02
9/30/02
1 0.002 0.011
9/10/02
9/10/02
Internal Std. uL
#1 #2
archive
125 125
125 125
125 125
125 125
composite with
125 125
125 125
125 125
125 125
composite with
125 125
125 125
125 125
125 125
125 125
125 125
Filtration
9/20/02
9/20/02
9/20/02
9/19/02
R6A1
R6A1
9/1 1/02
9/1 1/02
Concentration
Extract
260
260
250
260
230
250
, uL
Derivat.
130
130
130
130
120
130
Neutral
130
130
120
130
110
120
F-38
-------
Table F-7. (Continued)
Test ID: IB071002H Type of Test:
Location: NC A&T Greensboro Time, min
Fuel Type: No. 2 Oil
Substrate Substrate ID Chamber Port
#
TF 1008958
1008959
1008956
1008957
1008960
1008961
1008955
QF Q060702A-IB071002HR2A2
Q060702B-IB071002HR2B2
Q060602Y-IB071002HR4A2
Q060602Z-IB071002HR4B2
Q060602V-IB07 1 002HR6A 1
Q060602W-IB07 1 002HR6B 1
Q060602R-IB07 1 002HR1 OA 1
Q060602S-IB07 1 002HR1 OB 1
Q060602T-IB07 1 002HR8 A 1
Q060602U-IB071002HR8B1
Q060602X-IB07 1 002HD 1 A 1
PUF P020102J-IB071002HR6A2
P020 1 02K-IB07 1002HR6A3
P020 1 02L-IB07 1 002HR6A4
P020 1 02M-IB07 1 002HR6A5
P020 1 02N-IB07 1 002HR6B2
P020 1 02O-IB07 1 002HR6B3
RT
RT
RT
RT
RT
RT
DL
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
RT
RT
RT
RT
RT
RT
2
2
4
4
5
5
1
2
2
4
4
6
6
10
10
8
8
1
6
6
6
6
6
6
Oil fired
Boiler
600.67
Position
Al
Bl
Al
Bl
A3
B3
Bl
A2
B2
A2
B2
Al
Bl
Al
Bl
Al
Bl
Al
A2
A3
A4
A5
B2
B3
Institutional Venturi, std. m3: 11.29
Dilution, std. m3: 489.2
Dilution Ratio: 44.37
Holder No. of Composite ID Extracted , mg
# punch Mass OC
564
613
633
641
1185
1246
614
564 2 IB071002HR2&R4 0.490
613
633
641
618 2 IB071002HR6&R10 1.087 1.004
642
610
622
585 1
481
640 1 IB071002HD1 0.002 0.011
F-39
-------
Table F-7. (Continued)
Substrate Substrate ID Chamber Port Position Holder No. of Composite ID Extracted, mg
J # punch Mass PC
P020 1 02P-IB07 1 002HR6B4
P020 1 02Q-IB07 1 002HR6B5
P020 1 02B-IB07 1 002HR8A2
P020 1 02C-IB07 1 002HR8A3
P020 1 02D-IB07 1 002HR8 A4
P020 1 02E-IB07 1 002HR8 A5
P020 1 02F-IB07 1 002HR8B2
P020 1 02G-IB07 1 002HR8B3
P020 1 02H-IB07 1 002HR8B4
P020 1 02I-IB07 1 002HR8B5
PO 1 2902B-IB07 1 002HR1 OA2
PO 1 2902C-IB07 1 002HR1 OA3
PO 1 2902D-IB07 1 002HR1 OA4
P012902E-IB071002HR10A5
PO 1 2902F-IB07 1 002HR1 OB2
PO 12902G-IB07 1 002HR1 OB3
PO 1 2902H-IB07 1 002HR1 OB4
P020 1 02A-IB07 1 002HR1 OB5
P020102R-IB071002HD1A2
P020102S-IB071002HD1A3
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
DL
6
6
8
8
8
8
8
8
8
8
10
10
10
10
10
10
10
10
1
1
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
F-40
-------
Table F-7. (Continued)
Fuel Mass, kg: 4464.6
Air Flow, scfm: 4574.5
8x10" Filter Catch, g: 0.0463
8x10" blank: 0.0011
Internal
#1
150
150
100
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
Std. uL
#2
150
150
100
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
Total Derivat. Neutral
290
260
260
260
230
230
230
250
260
260
250
260
150
130
130
130
120
120
120
130
130
130
130
130
150
130
130
130
110
110
110
120
130
130
120
130
F-41
-------
Table F-7. (Continued)
Internal Std. uL Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
#1 #2 Total Derivat. Neutral
125 125
125 125
125 125
125 125 230 120 110
125 125 250 130 120
F-42
-------
Figure F-8. Oil-Fired Institutional Boiler, Campaign #2, July 10, 2002
ELPI Stage Mass
Test ID: IB071002H
Test Location:
Type of Test: Industrial Boiler
Fuel Type: No. 2 Oil
Sampling Location: Residence chamber
ELPI flow, SLPM: 9.61
ELPI Dilution Ratio: 1
ELPI Unit No.: 292
ELPI Flow Data
Sampling start 7:06:05
Sampling end 17:06:45
Sampling time, min 600.7
Sampler
DR
Gravimetric Analysis
Staee Substrate ID
1 A062402A-IB071002H-ELPI1
2 A062102Z-IB071002H-ELPI2
3 A062102Y-IB071002H-ELPI3
4 A062102X-IB071002H-ELPI4
5 A062102W-IB071002H-ELPI5
6 A062102V-IB071002H-ELPI6
7 A062102U-IB071002H-ELPI7
8 A062102T-IB071002H-ELPI8
9 A062102S-IB071002H-ELPI9
10 A062102R-IB071002H-ELPI10
11 A062102Q-IB071002H-ELPI11
12 A062102P-IB071002H-ELPI12
13 A062102O-IB071002H-ELPI13
- Port #7
PM. me
0.018
0.026
0.012
0.009
0.005
0.007
0.008
0.006
0.010
0.002
0.006
0.009
0.006
Net PM me
0.016
0.024
0.010
0.007
0.003
0.005
0.006
0.004
0.008
0.000
0.004
0.007
0.004
Mass Cone me/m3 TDS
0.0028
0.0042
0.0017
0.0012
0.0005
0.0009
0.0010
0.0007
0.0014
0.0000
0.0007
0.0012
0.0007
F-43
-------
Table F-9. Oil-Fired Institutional Boiler, Campaign #2, July 11, 2002
Test Location:
Fuel Type: No. 2 Oil
Port
Chamber # Position
RT 2 Al
A2
Bl
B2
4 Al
A2
Bl
B2
5 Al
A2
A3
Bl
B2
B3
B4
6 Al
A2
A3
A4
A5
Bl
B2
B3
Substrate
TF
QF
TF
QF
TF
QF
TF
QF
D
D
TF
D
D
TF
NF
QF
PUF
PUF
PUF
PUF
QF
PUF
PUF
Holder
#
564
564
613
613
633
633
641
641
1185
1246
1246
618
642
Time, min 600
PM No. of OC
Substrate ID mg punch ug/cm2
1008967 1.176
Q060702P-IB071102HR2A2* 1 12.64
1008968 1.15
Q060702Q-IB071102HR2B2 *
1008965 1.082
Q060702N-IB071102HR4A2* 1 12.64
1008966 1.064
Q060702O-IB071102HR4B2 *
95G17
F13
1008962 0.361
83G18
F14
1008963 0.357
NF-4
Q060702K-IB071102HR6A1 1 67.37
P062502K-IB071 102HR6A2
P062502L-IB071 102HR6A3
P062502M-IB071 102HR6A4
P062502N-IB071 102HR6A5
Q060702L-IB071 102HR6B1
P062502O-IB071 102HR6B2
P062 1 02A-IB07 1 1 02HR6B3
Dilution, std.
m3:
Dilution Ratio:
EC OCX Flow
ug/cm2 ug/cm2 SLPM
8.276
0.03 0.10 8.276
8.276
8.276
8.058
0.09 0.00 8.058
8.058
8.058
4.573
4.573
4.573
4.573
4.573
4.573
4.573
1.59 9.19 8.276
8.276
8.276
8.276
8.276
8.276
8.276
8.276
494.82
44.95
PM
mg/L
0.000237
0.000232
0.000224
0.000220
0.000132
0.000130
F-44
-------
Table F-9. (Continued)
Port
Chamber # Position
Sample Log,
Dilution 1
B4
B5
8 Al
A2
A3
A4
A5
Bl
B2
B3
Holder
Substrate #
PUF
PUF
QF 585
PUF
PUF
PUF
PUF
QF 481
PUF
PUF
Substrate ID
P062102B-IB071102HR6B4
P062102C-IB071102HR6B5
Q060702I-IB071 102HR8A1
P062502C-IB071 102HR8A2
P062502D-IB071 102HR8A3
P062502E-IB071 102HR8A4
P062502F-IB071 102HR8A5
Q060702J-IB07 1 1 02HR8B 1
P062502G-IB071 102HR8B2
P062502H-IB071 102HR8B3
PM No. of OC EC OCX Flow PM
mg punch ug/cm2 ug/cm2 ug/cm2 SLPM mg/L
8.276
8.276
1 67.54 1.38 9.64 8.239
8.239
8.239
8.239
8.239
8.239
8.239
8.239
July 11, continued
B4
B5
10 Al
A2
A3
A4
A5
Bl
B2
B3
B4
B5
Al
A2
PUF
PUF
QF 610
PUF
PUF
PUF
PUF
QF 622
PUF
PUF
PUF
PUF
QF 640
PUF
P062502I-IB071102HR8B4
P062502J-IB071 102HR8B5
Q060702G-IB071102HR10A1
P04 1 202G-IB07 1 1 02HR1 OA2
P04 1 202H-IB07 1 1 02HR1 OA3
P04 1 202I-IB07 1 1 02HR1 OA4
P04 1 202 J-IB07 1 1 02HR1 OA5
Q060702H-IB071102HR10B1
P04 1 202K-IB07 1 1 02HR1 OB2
P041202L-IB071 102HR10B3
P062502A-IB071 102HR10B4
P062502B-IB07 1 1 02HR1 OB5
Q060702M-IB07 1 102HD 1 A 1
P062102D-IB071102HD1A2
8.239
8.239
1 63.21 1.43 9.68 8.239
8.239
8.239
8.239
8.239
8.239
8.239
8.239
8.239
8.239
1 0.51 0.05 0.00 8.203
8.203
* Composited with residence chamber port 2, A2
F-45
-------
Table F-2. (Continued)
OC Extrac-
mg/L tion
Fuel Mass, kg: 4459.7
Air Flow, scfm: 4282.3
8x10" Filter Catch, g: 0.123
Fliter Extracted, mg Internal
Split Mass OC #1
Std. uL
#2
8x10" blank: 0.0011
Filtra- Concentration, uL
tion Extract Derivat.
Neutral
1 0.152 composite
1 0.170 composite with R2A2
1 0.152 composite with R2A2
1 0.170 composite with R2A2
1
9/25/02
9/25/02
9/25/02
9/25/02
9/25/02
9/25/02
9/25/02
9/25/02
9/23/02
9/23/02
9/23/02
9/23/02
9/13/02
9/13/02
9/13/02
1 1.010 0.808
125
125
125
125
1 1.132 0.906
125
125
125
125
1 1.006 0.810
125
125
125
125
1 1.127 0.908 archive
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
9/26/02
9/26/02
9/26/02
9/26/02
9/30/02
9/30/02
9/30/02
9/30/02
9/25/02
9/25/02
9/25/02
9/25/02
9/16/02
9/16/02
9/16/02
200
230
240
240
230
200
210
230
290
250
220
260
250
260
250
100
120
120
120
120
100
110
120
150
130
110
130
130
130
130
100
110
120
120
110
100
100
110
140
120
110
130
120
130
120
F-46
-------
Table F-9. (Continued)
OC Extrac-
mg/L tion
9/13/02
9/1 1/02
9/1 1/02
9/1 1/02
9/1 1/02
9/10/02
9/10/02
9/10/02
9/10/02
9/13/02
9/13/02
Filter Extracted, mg Internal
Split Mass OC #1
125
1 1.006 0.759
125
125
125
125
1 1.127 0.850 archive
125
125
125
125
1 0.005 0.006
125
125
Std. uL
#2
125
125
125
125
125
125
125
125
125
125
125
Filtra-
tion
9/16/02
9/13/02
9/13/02
9/13/02
9/13/02
9/24/02
9/24/02
9/24/02
9/24/02
9/23/02
9/23/02
Concentration, uL
Extract Derivat.
260
250
230
210
220
240
240
260
240
220
250
130
130
120
110
110
120
120
130
120
110
130
Neutral
130
120
110
100
110
120
120
130
120
110
120
F-47
-------
Table F-9. (Continued)
Test ID:
Location:
Fuel Type:
Substrate
TF
QF
PUF
IB071102H
NC A&T Greensboro
No. 2 Oil
Substrate ID
1008967
1008968
1008965
1008966
1008962
1008963
1008964
Q060702P-IB071 102HR2A2
Q060702Q-IB071 102HR2B2
Q060702N-IB071 102HR4A2
Q060702O-IB071 102HR4B2
Q060702K-IB071 102HR6A1
Q060702L-IB07 1 1 02HR6B 1
Q060702I-IB071 102HR8A1
Q060702 J-IB07 1 1 02HR8B 1
Q060702G-IB071102HR10A1
Q060702H-IB071 102HR10B1
Q060702M-IB071 102HD1A1
P062502K-IB071 102HR6A2
P062502L-IB071 102HR6A3
P062502M-IB071 102HR6A4
P062502N-IB071 102HR6A5
Type of Test
Time, min
Chamber
RT
RT
RT
RT
RT
RT
DL
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
RT
RT
RT
RT
•
Port
#
2
2
4
4
5
5
1
2
2
4
4
6
6
8
8
10
10
1
6
6
6
6
Oil fired
600
Position
Al
Bl
Al
Bl
A3
B3
Bl
A2
B2
A2
B2
Al
Bl
Al
Bl
Al
Bl
Al
A2
A3
A4
A5
Institutional Boiler
Holder No. of
# punch
564
613
633
641
1185
1246
614
564 2
613
633
641
618 1
642
585 1
481
610 1
622
640 1
Venturi, std. m3:
Dilution, std. m3:
Dilution Ratio:
Composite Extracted
ID Mass
IB071102HR2&R4
.010
.132
.006
.127
.006
.127
0.005
11.27
494.82
44.95
,mg
OC
0.643
0.808
0.906
0.810
0.908
0.759
0.850
0.006
F-48
-------
Table F-9. (Continued)
Substrate Substrate ID
P062502O-IB071 102HR6B2
P062102A-IB071 102HR6B3
P062102B-IB071 102HR6B4
P062102C-IB071 102HR6B5
P062502C-m071 102HR8A2
P062502D-IB071 102HR8A3
P062502E-m071 102HR8A4
P062502F-IB071 102HR8A5
P062502G-m071 102HR8B2
P062502H-m071 102HR8B3
P062502I-IB071 102HR8B4
P062502J-IB071 102HR8B5
P041202G-IB071 102HR10A2
P041202H-IB071 102HR10A3
P041202I-IB071 102HR10A4
P041202J-m071 102HR10A5
P041202K-IB071 102HR10B2
P041202L-m071 102HR10B3
P062502A-IB071 102HR10B4
P062502B-IB071 102HR10B5
P062102D-IB071 102HD1 A2
P062102E-IB071 102HD1 A3
Chamber
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
RT
DL
DL
Port
#
6
6
6
6
8
8
8
8
8
8
8
8
10
10
10
10
10
10
10
10
1
1
Position Holder No. of Composite Extracted , mg
# punch ID Mass OC
B2
B3
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
A4
A5
B2
B3
B4
B5
A2
A3
F-49
-------
Table F-9. (Continued)
Fuel Mass, kg: 4459.7
Air Flow, scfm: 4282.3
Internal
#1
150
150
150
150
150
150
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
8x10" Filter Catch, g: 0.1230 8x10" blank: 0.0011
Std. uL Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
#2 Total Derivat. Neutral
150
150
150
150
150
150
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
200
230
240
240
230
200
210
230
290
250
220
260
250
260
250
260
250
230
100
120
120
120
120
100
110
120
150
130
110
130
130
130
130
130
130
120
100
110
120
120
110
100
100
110
140
120
110
130
120
130
120
130
120
110
F-50
-------
Table F-9. (Continued)
Internal Std. uL Concentrated Extract, uL Methylation Silylation GC/MS 1C XRF
#1 #2 Total Derivat. Neutral
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
125
210
220
240
240
260
240
220
250
110
110
120
120
130
120
110
130
100
110
120
120
130
120
110
120
F-51
-------
Table F-10. Oil-Fired Institutional Boiler, Campaign #2,
July 11, 2002. ELPI Stage Mass
Test ID:
IB071102
H
Test Location: NC A&T Greensboro
Type of Test: Institutional Boiler
Fuel Type: No. 2 Oil
Sampling Location: Residence chamber - Port #7
ELPI flow, SLPM: 9.61
ELPI Dilution Ratio: 1
ELPI Unit No.: 292
ELPI Flow Data
Sampling start 7:17:03
Sampling end 17:17:03
Sampling time, min 600.0
Sampler 1
DR
Gravimetric Analysis
Stage Substrate ID
1 A062402N-IB07 1 1 02H-ELPI 1
2 A062402M-IB07 1 1 02H-ELPI2
3 A062402L-IB071102H-ELPI3
4 A062402O-IB07 1 1 02H-ELPI4
5 A062402J-IB07 1 1 02H-ELPI5
6 A062402I-IB07 1 1 02H-ELPI6
7 A062402H-IB07 1 1 02H-ELPI7
8 A062402G-IB07 1 1 02H-ELPI8
9 A062402F-IB071102H-ELPI9
1 0 A062402E-IB07 1 1 02H-ELPI 1 0
1 1 A062402D-IB07 1 1 02H-ELPI 1 1
12 A062402C-IB071102H-ELPI12
1 3 A062402B-IB07 1 1 02H-ELPI 1 3
PM, mg
0.101
0.184
0.071
0.033
0.026
0.008
0.005
0.006
0.008
0.003
-0.059
0.003
0.003
NetPM
me
0.099
0.182
0.069
0.031
0.024
0.006
0.003
0.004
0.006
0.001
-0.061
0.001
0.001
Mass Cone TDS
me/m3
0.0172
0.0316
0.0120
0.0054
0.0042
0.0010
0.0005
0.0007
0.0010
0.0002
0.0000
0.0002
0.0002
F-52
-------
Appendix G
Data Tables for Individual NMOC Samples
Campaign #1 Only
-------
Table G-l. Greensboro A&T Field Test: January 16-18, 2001
SNMOC. Laboratory and Field (Ambient) Blank.
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l -butene
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methvlhexane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
Laboratory
Blank
1/16/01
ue/m3
0.49
0.35
0.94
0.21
1.26
0
0.27
0.10
0
0.68
0
0
0
0.50
0
0
0.22
0
0
0
0
0
0.25
0
0.12
0.17
0.35
0.15
0
0
0
0.23
0
0
0.11
0
0.31
0.21
0
0
0
Ambient
1/16/01
ue/m3
2.84
2.14
13.70
2.86
288.06
0
8.71
0.61
0.22
7.88
0.30
0.32
0.07
10.53
0.26
0.23
2.37
0.29
0.38
0.28
0.43
2.92
0.38
0
0.31
0.51
1.10
0.90
0
0.43
0
1.24
0
0
0.72
0.27
1.69
0.86
0.34
0.33
0.56
G-l
-------
Table G-l. (Continued)
Conioound
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
m-xylene//>-xylene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
cc-pinene
«-propylbenzene
w-ethyltoluene
/>-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
w-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
CAS No.
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Laboratory
Blank
1/16/01
Lie/m3
0
0.16
0
0
0
0
0.48
0
0
0
0
0.14
0.27
0.11
0.11
0.22
0
0
0.18
0
0
0
0.08
0
0.13
0.15
0
0.10
0
0
0
0
0.15
0.11
0.31
0
0
9.62
5.08
14.70
Ambient
1/16/01
ue/m3
0.18
1.28
0.47
0.45
0.58
0.48
2.75
1.69
0.27
0.10
0.59
0.71
1.72
0.53
0.82
0.22
0.41
0.14
0.13
0.28
0.66
0.42
0.43
0.72
0.25
1.05
0
2.80
0.20
0.21
0.15
0.08
0.66
0.26
4.50
0
0.13
381.36
28.08
409.44
Total NMOC with unknowns in //g/m is an estimate based on propane only.
G-2
-------
Table G-2A. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
Residence
Chamber
1/16/01
V=4.2L
ue/ni3
4.1600
2.6700
22.8300
4.8500
65.4000
0.0000
1.5900
0.2700
0.0600
1.4100
0.1300
0.1400
0.0000
0.7700
0.1300
0.0000
0.4600
0.0000
0.1300
0.1500
0.0000
0.2700
0.1200
0.0000
0.1300
Residence
Chamber
1/16/01
us
0.0175
0.0112
0.0959
0.0204
0.2747
0.0000
0.0067
0.0011
0.0003
0.0059
0.0005
0.0006
0.0000
0.0032
0.0005
0.0000
0.0019
0.0000
0.0005
0.0006
0.0000
0.0011
0.0005
0.0000
0.0005
Dilution
Air
1/16/01
V=4.8L
ue/m3
2.9700
2.7100
23.0600
4.9400
29.9900
0.0000
0.6200
0.1800
0.0000
0.9000
0.1300
0.1300
0.0000
0.4100
0.0900
0.1100
0.3300
0.1500
0.1100
0.1100
0.0800
0.2000
0.1100
0.0000
0.0800
Dilution
Air
1/16/01
us
0.0143
0.0130
0.1107
0.0237
0.1440
0.0000
0.0030
0.0009
0.0000
0.0043
0.0006
0.0006
0.0000
0.0020
0.0004
0.0005
0.0016
0.0007
0.0005
0.0005
0.0004
0.0010
0.0005
0.0000
0.0004
SNMOC
RC-DA
1/16/01
us
0.0032
-0.0018
-0.0148
-0.0033
0.1307
0.0000
0.0037
0.0003
0.0003
0.0016
-0.0001
0.0000
0.0000
0.0013
0.0001
-0.0005
0.0003
-0.0007
0.0000
0.0001
-0.0004
0.0002
0.0000
0.0000
0.0002
No Negs+
SNMOC
RC-DA
1/16/01
us
0.0032
0.0000
0.0000
0.0000
0.1307
0.0000
0.0037
0.0003
0.0003
0.0016
0.0000
0.0000
0.0000
0.0013
0.0001
0.0000
0.0003
0.0000
0.0000
0.0001
0.0000
0.0002
0.0000
0.0000
0.0002
G-3
-------
Table G-2A. (Continued)
Comoound
2,3-dimethylbutane
2-methylpentane
3 -methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l-butene
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
CAS No.
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
Residence
Chamber
1/16/01
V=4.2L
ue/ni3
0.2600
0.3000
0.3900
0.0000
0.2200
0.0000
2.6100
0.0000
0.0000
0.5700
0.1400
0.4500
0.2000
0.1700
0.1800
0.1000
0.0000
0.2800
0.2000
0.1900
0.0000
0.1800
0.7400
0.1000
0.1100
0.0000
0.3900
Residence
Chamber
1/16/01
us
0.0011
0.0013
0.0016
0.0000
0.0009
0.0000
0.0110
0.0000
0.0000
0.0024
0.0006
0.0019
0.0008
0.0007
0.0008
0.0004
0.0000
0.0012
0.0008
0.0008
0.0000
0.0008
0.0031
0.0004
0.0005
0.0000
0.0016
Dilution
Air
1/16/01
V=4.8L
ue/m3
0.3400
0.2000
0.2400
0.0000
0.1900
0.0000
1.0100
0.0000
0.2600
0.2800
0.1200
0.1900
9.9800
0.0000
0.1800
0.1400
0.0000
0.2100
0.1400
0.1400
0.0000
0.1100
0.6500
0.1200
0.1100
0.0000
0.3700
Dilution
Air
1/16/01
us
0.0016
0.0010
0.0012
0.0000
0.0009
0.0000
0.0048
0.0000
0.0012
0.0013
0.0006
0.0009
0.0479
0.0000
0.0009
0.0007
0.0000
0.0010
0.0007
0.0007
0.0000
0.0005
0.0031
0.0006
0.0005
0.0000
0.0018
SNMOC
RC-DA
1/16/01
us
-0.0005
0.0003
0.0005
0.0000
0.0000
0.0000
0.0061
0.0000
-0.0012
0.0011
0.0000
0.0010
-0.0471
0.0007
-0.0001
-0.0003
0.0000
0.0002
0.0002
0.0001
0.0000
0.0002
0.0000
-0.0002
-0.0001
0.0000
-0.0001
No Negs+
SNMOC
RC-DA
1/16/01
us
0.0000
0.0003
0.0005
0.0000
0.0000
0.0000
0.0061
0.0000
0.0000
0.0011
0.0000
0.0010
0.0000
0.0007
0.0000
0.0000
0.0000
0.0002
0.0002
0.0001
0.0000
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
G-4
-------
Table G-2A. (Continued)
Comoound
ethylbenzene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
ra-ethyltoluene
/>-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
m-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
100-41-4
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence
Chamber
1/16/01
V=4.2L
ue/ni3
0.2200
0.3700
0.3700
0.1200
0.2700
0.0800
0.0000
0.1100
0.3200
0.2600
0.5100
0.4600
0.1200
0.8000
0.0000
5.9200
0.2600
0.1500
0.0000
0.0000
2.1000
0.1300
18.9100
0.0000
0.1200
Residence
Chamber
1/16/01
us
0.0009
0.0016
0.0016
0.0005
0.0011
0.0003
0.0000
0.0005
0.0013
0.0011
0.0021
0.0019
0.0005
0.0034
0.0000
0.0249
0.0011
0.0006
0.0000
0.0000
0.0088
0.0005
0.0794
0.0000
0.0005
Dilution
Air
1/16/01
V=4.8L
ue/m3
0.2300
0.6200
0.3500
0.0800
0.2400
0.1000
0.0600
0.0900
0.1500
0.1500
0.4200
0.3500
0.3600
0.6200
0.0000
6.8100
0.1500
0.1200
0.0700
0.0000
1.8700
0.2700
25.8600
0.0000
0.2100
Dilution
Air
1/16/01
us
0.0011
0.0030
0.0017
0.0004
0.0012
0.0005
0.0003
0.0004
0.0007
0.0007
0.0020
0.0017
0.0017
0.0030
0.0000
0.0327
0.0007
0.0006
0.0003
0.0000
0.0090
0.0013
0.1241
0.0000
0.0010
SNMOC
RC-DA
1/16/01
us
-0.0002
-0.0014
-0.0001
0.0001
0.0000
-0.0001
-0.0003
0.0000
0.0006
0.0004
0.0001
0.0003
-0.0012
0.0004
0.0000
-0.0078
0.0004
0.0001
-0.0003
0.0000
-0.0002
-0.0008
-0.0447
0.0000
-0.0005
No Negs+
SNMOC
RC-DA
1/16/01
us
0.0000
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0006
0.0004
0.0001
0.0003
0.0000
0.0004
0.0000
0.0000
0.0004
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
G-5
-------
Table G-2A. (Continued)
Comoound CAS No.
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
Residence
Chamber
1/16/01
V=4.2L
ue/ni3
145.5500
26.3300
171.8800
Residence
Chamber
1/16/01
us
0.6113
0.1106
0.7219
Dilution
Air
1/16/01
V=4.8L
ue/m3
122.1500
23.9700
146.1200
Dilution
Air
1/16/01
us
0.5863
0.1151
0.7014
SNMOC
RC-DA
1/16/01
us
0.0250
-0.0045
0.0205
No Negs+
SNMOC
RC-DA
1/16/01
us
0.1546
0.0000
0.1546
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
+A11 negative values obtained in subtracting DA from RC have been changed to 0 for subsequent calculations.
G-6
-------
Table G-2B. Greensboro A&T Field Test
January 16-18, 2001
Sample Concentrations by Test Day
Comoound CAS No.
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
Residence
Chamber
1/17/01
V=5L
ue/ni3
7.6900
7.1000
33.9500
3.0000
43.2400
0.0000
0.4000
0.4200
0.0000
0.5700
0.2000
0.2200
0.0000
0.4300
0.1600
0.0000
0.3000
0.1300
0.1400
0.2300
0.0000
0.4300
0.1800
0.0000
0.1700
0.3400
0.2800
0.4000
Residence
Chamber
1/17/01
us
0.0385
0.0355
0.1698
0.0150
0.2162
0.0000
0.0020
0.0021
0.0000
0.0029
0.0010
0.0011
0.0000
0.0022
0.0008
0.0000
0.0015
0.0007
0.0007
0.0012
0.0000
0.0022
0.0009
0.0000
0.0009
0.0017
0.0014
0.0020
Dilution
Air
1/17/01
V=4.7L
ue/m3
4.3700
4.6300
30.7900
2.7600
38.4700
0.0000
0.3300
0.1700
0.0000
0.4200
0.1200
0.1300
0.0000
0.2300
0.0900
0.0000
0.1800
0.1300
0.0900
0.1100
0.0000
0.1900
0.0900
0.0000
0.1000
0.2400
0.0900
0.2000
Dilution
Air
1/17/01
ue
0.0205
0.0218
0.1447
0.0130
0.1808
0.0000
0.0016
0.0008
0.0000
0.0020
0.0006
0.0006
0.0000
0.0011
0.0004
0.0000
0.0008
0.0006
0.0004
0.0005
0.0000
0.0009
0.0004
0.0000
0.0005
0.0011
0.0004
0.0009
SNMOC
RC-DA
1/17/01
us
0.0179
0.0137
0.0250
0.0020
0.0354
0.0000
0.0004
0.0013
0.0000
0.0009
0.0004
0.0005
0.0000
0.0011
0.0004
0.0000
0.0007
0.0000
0.0003
0.0006
0.0000
0.0013
0.0005
0.0000
0.0004
0.0006
0.0010
0.0011
No Negs*
SNMOC
RC-DA
1/17/01
us
0.0179
0.0137
0.0250
0.0020
0.0354
0.0000
0.0004
0.0013
0.0000
0.0009
0.0004
0.0005
0.0000
0.0011
0.0004
0.0000
0.0007
0.0000
0.0003
0.0006
0.0000
0.0013
0.0005
0.0000
0.0004
0.0006
0.0010
0.0011
G-7
-------
Table G-2B. (Continued)
Comoound
2-methyl- 1 -pentene
1-hexene
2-ethyl-l-butene
«-hexane
fra«s-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
m-xylene//>-xylene
styrene
o-xylene
CAS No.
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
Residence
Chamber
1/17/01
V=5L
ue/m3
0
0
0
1
0
0
0
0
.0000
.3400
.0000
.6900
.0000
.0000
.5200
.2400
0.4400
0
0
0
0
0.
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
.1900
.1600
.3400
.1400
.0000
.2500
.2500
.1800
.0000
.1800
.4700
.1500
.1900
.0000
.6800
.2100
.4400
.2200
.2700
Residence
Chamber
1/17/01
us
0.0000
0.0017
0.0000
0.0085
0.0000
0.0000
0.0026
0.0012
0.0022
0.0010
0.0008
0.0017
0.0007
0.0000
0.0013
0.0013
0.0009
0.0000
0.0009
0.0024
0.0008
0.0010
0.0000
0.0034
0.0011
0.0022
0.0011
0.0014
Dilution
Air
1/17/01
V=4.7L
ue/m3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0000
.1800
.0000
.8400
.0000
.0000
.2400
.1200
.1400
.3300
.0800
.1800
.1100
.0000
.1400
.0900
.1200
.0000
.1000
.3600
.0900
.1000
.0000
.2500
.1500
.3700
.1200
.1900
Dilution
Air
1/17/01
us
0
0.
0
0.
0.
0.
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
.0000
.0008
.0000
.0039
.0000
.0000
.0011
.0006
.0007
.0016
.0004
.0008
.0005
.0000
.0007
.0004
.0006
.0000
.0005
.0017
.0004
.0005
.0000
.0012
.0007
.0017
.0006
.0009
SNMOC
RC-DA
1/17/01
us
0.
0.
0.
0.
0.
0.
0.
0.
0.
-0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0000
0009
0000
0045
0000
0000
0015
0006
0015
.0006
0004
0009
0002
0000
0006
0008
0003
0000
0004
0007
0003
0005
0000
0022
0003
0005
0005
0005
No Negs+
SNMOC
RC-DA
1/17/01
us
0.0000
0.0009
0.0000
0.0045
0.0000
0.0000
0.0015
0.0006
0.0015
0.0000
0.0004
0.0009
0.0002
0.0000
0.0006
0.0008
0.0003
0.0000
0.0004
0.0007
0.0003
0.0005
0.0000
0.0022
0.0003
0.0005
0.0005
0.0005
G-8
-------
Table G-2B. (Continued)
Comoound
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
/>-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
m-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
Total speciated
Total unspeciated
CAS No.
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Total soeciated + unsoeciated*
Residence
Chamber
1/17/01
V=5L
ue/m3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12
0
0
124
8
133
.0000
.3100
.1600
.0000
.1200
.2800
.2100
.3600
.3200
.2200
.6000
.0000
.9400
.2400
.1500
.1300
.0000
.7300
.1800
.1100
.0000
.1800
.7700
.7200
.4900
Residence
Chamber
1/17/01
us
0.0000
0.0016
0.0008
0.0000
0.0006
0.0014
0.0011
0.0018
0.0016
0.0011
0.0030
0.0000
0.0047
0.0012
0.0008
0.0007
0.0000
0.0037
0.0009
0.0606
0.0000
0.0009
0.6239
0.0436
0.6675
Dilution
Air
1/17/01
V=4.7L
ue/m3
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
95
10
0000
1200
0900
0000
0700
1400
1300
1200
1400
0000
2700
0000
8300
0900
0000
0000
0000
4500
0000
6100
0000
0000
.2900
.8200
106.1100
Dilution
Air
1/17/01
us
0.
0.
0
0.
0
0
0
0
0
0.
0
0
0
0
0
0
0
0
0
0
0
0
.0000
.0006
.0004
.0000
.0003
.0007
.0006
.0006
.0007
.0000
.0013
.0000
.0039
.0004
.0000
.0000
.0000
.0021
.0000
.0217
.0000
.0000
0.4479
0
.0509
0.4987
SNMOC
RC-DA
1/17/01
us
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
-0
0.
0000
0010
0004
0000
0003
0007
0004
0012
0009
0011
0017
0000
0008
0008
0008
0007
0000
0015
0009
0389
0000
0009
1760
.0073
1687
No Negs+
SNMOC
RC-DA
1/17/01
us
0.0000
0.0010
0.0004
0.0000
0.0003
0.0007
0.0004
0.0012
0.0009
0.0011
0.0017
0.0000
0.0008
0.0008
0.0008
0.0007
0.0000
0.0015
0.0009
0.0389
0.0000
0.0009
0.1766
0.0000
0.1766
Total NMOC with unknowns in ug/m3 is an estimate based on propane only.
+A11 negative values obtained in subtracting DA from RC have been changed to 0 for subsequent calculations.
G-9
-------
Table G-2C. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2-butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
Residence
Chamber
1/18/01
V=5.2L
ue/m3
5.8400
4.3100
25.2600
4.3300
198.1800
0.0000
0.3100
0.2300
0.0000
0.4000
0.1000
0.1200
0.0000
0.2200
0.0900
0.0000
0.1600
0.0000
0.0900
0.1100
0.0000
0.1900
0.1100
0.0000
0.0900
0.1900
1.3000
Residence
Chamber
1/18/01
us
0.0304
0.0224
0.1314
0.0225
1.0305
0.0000
0.0016
0.0012
0.0000
0.0021
0.0005
0.0006
0.0000
0.0011
0.0005
0.0000
0.0008
0.0000
0.0005
0.0006
0.0000
0.0010
0.0006
0.0000
0.0005
0.0010
0.0068
Dilution
Air
1/18/01
V=4.8L
ue/ni3
5.1500
3.9700
26.6700
3.9000
157.2400
0.0000
0.3300
0.1400
0.0000
0.4200
0.1000
0.1400
0.0000
0.2500
0.0700
0.0000
0.1600
0.1400
0.0800
0.1200
0.0000
0.1700
0.0800
0.0000
0.0800
0.1800
0.1300
Dilution
Air
1/18/01
us
0.0247
0.0191
0.1280
0.0187
0.7548
0.0000
0.0016
0.0007
0.0000
0.0020
0.0005
0.0007
0.0000
0.0012
0.0003
0.0000
0.0008
0.0007
0.0004
0.0006
0.0000
0.0008
0.0004
0.0000
0.0004
0.0009
0.0006
SNMOC
RC-DA
1/18/01
us
0.0056
0.0034
0.0033
0.0038
0.2758
0.0000
0.0000
0.0005
0.0000
0.0001
0.0000
0.0000
0.0000
-0.0001
0.0001
0.0000
0.0001
-0.0007
0.0001
0.0000
0.0000
0.0002
0.0002
0.0000
0.0001
0.0001
0.0061
No Negs+
SNMOC
RC-DA
1/18/01
us
0.0056
0.0034
0.0033
0.0038
0.2758
0.0000
0.0000
0.0005
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0001
0.0000
0.0001
0.0000
0.0000
0.0002
0.0002
0.0000
0.0001
0.0001
0.0061
G-10
-------
Table G-2C. (Continued)
Comoound
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l-butene
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
w-xylene//>-xylene
styrene
CAS No.
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
Residence
Chamber
1/18/01
V=5.2L
ug/m3
0.2500
0.0000
0.1900
0.0000
1.3400
0.0000
0.0000
0.3200
0.1000
0.2100
0.1300
0.0800
0.1500
0.0600
0.0800
0.1400
0.1500
0.1100
0.0000
0.1000
0.2700
0.0700
0.0800
0.0000
0.2600
0.1100
0.2500
0.2000
Residence
Chamber
1/18/01
us
0.0013
0.0000
0.0010
0.0000
0.0070
0.0000
0.0000
0.0017
0.0005
0.0011
0.0007
0.0004
0.0008
0.0003
0.0004
0.0007
0.0008
0.0006
0.0000
0.0005
0.0014
0.0004
0.0004
0.0000
0.0014
0.0006
0.0013
0.0010
Dilution
Air
1/18/01
V=4.8L
ue/m3
0.1900
0.0000
0.1900
0.0000
0.6600
0.0000
0.0000
0.1800
0.1000
0.1500
0.1300
0.0800
0.1600
0.0700
0.0000
0.1300
0.1100
0.0900
0.0000
0.1000
0.3100
0.0900
0.1000
0.0000
0.1800
0.1300
0.3000
0.0900
Dilution
Air
1/18/01
us
0.0009
0.0000
0.0009
0.0000
0.0032
0.0000
0.0000
0.0009
0.0005
0.0007
0.0006
0.0004
0.0008
0.0003
0.0000
0.0006
0.0005
0.0004
0.0000
0.0005
0.0015
0.0004
0.0005
0.0000
0.0009
0.0006
0.0014
0.0004
SNMOC
RC-DA
1/18/01
us
0.0004
0.0000
0.0001
0.0000
0.0038
0.0000
0.0000
0.0008
0.0000
0.0004
0.0001
0.0000
0.0000
0.0000
0.0004
0.0001
0.0003
0.0001
0.0000
0.0000
-0.0001
-0.0001
-0.0001
0.0000
0.0005
-0.0001
-0.0001
0.0006
No Negs+
SNMOC
RC-DA
1/18/01
us
0.0004
0.0000
0.0001
0.0000
0.0038
0.0000
0.0000
0.0008
0.0000
0.0004
0.0001
0.0000
0.0000
0.0000
0.0004
0.0001
0.0003
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0005
0.0000
0.0000
0.0006
G-ll
-------
Table G-2C. (Continued)
Comoound
o-xylene
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
ra-ethyltoluene
/•-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
ra-diethylbenzene
/•-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence
Chamber
1/18/01
V=5.2L
ug/m3
0.1800
0.0800
0.1800
0.0900
0.0000
0.0700
0.1100
0.1000
0.1400
0.1100
0.2000
0.3000
0.0000
0.4500
0.0800
0.1000
0.0700
0.0000
0.4200
0.1500
7.1000
0.0000
0.1800
Residence
Chamber
1/18/01
us
0.0009
0.0004
0.0009
0.0005
0.0000
0.0004
0.0006
0.0005
0.0007
0.0006
0.0010
0.0016
0.0000
0.0023
0.0004
0.0005
0.0004
0.0000
0.0022
0.0008
0.0369
0.0000
0.0009
Dilution
Air
1/18/01
V=4.8L
ue/m3
0.1600
0.0800
0.1200
0.0900
0.0000
0.0800
0.1300
0.1000
0.0600
0.0700
0.0000
0.2200
0.0000
0.3500
0.0900
0.0000
0.0000
0.0000
0.2900
0.0000
3.2100
0.0000
0.0000
Dilution
Air
1/18/01
us
0.0008
0.0004
0.0006
0.0004
0.0000
0.0004
0.0006
0.0005
0.0003
0.0003
0.0000
0.0011
0.0000
0.0017
0.0004
0.0000
0.0000
0.0000
0.0014
0.0000
0.0154
0.0000
0.0000
SNMOC
RC-DA
1/18/01
us
0.0002
0.0000
0.0004
0.0000
0.0000
0.0000
-0.0001
0.0000
0.0004
0.0002
0.0010
0.0005
0.0000
0.0007
0.0000
0.0005
0.0004
0.0000
0.0008
0.0008
0.0215
0.0000
0.0009
No Negs+
SNMOC
RC-DA
1/18/01
us
0.0002
0.0000
0.0004
0.0000
0.0000
0.0000
0.0000
0.0000
0.0004
0.0002
0.0010
0.0005
0.0000
0.0007
0.0000
0.0005
0.0004
0.0000
0.0008
0.0008
0.0215
0.0000
0.0009
G-12
-------
Table G-2. (Continued)
Comoound CAS No.
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
Residence
Chamber
1/18/01
V=5.2L
ue/m3
256.3900
12.7900
269.1800
Residence
Chamber
1/18/01
us
1.3332
0.0665
1.3997
Dilution
Air
1/18/01
V=4.8L
ue/m3
208.1100
8.3800
216.4900
Dilution
Air
1/18/01
us
0.9989
0.0402
1.0392
SNMOC
RC-DA
1/18/01
us
0.3343
0.0263
0.3606
No Negs+
SNMOC
RC-DA
1/18/01
us
0.3356
0.0263
0.3619
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
+A11 negative values obtained in subtracting DA from RC have been changed to 0 for subsequent calculations.
G-13
-------
Table G-3. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day: Summary
All negative values from the RC-DA subtraction have been replaced by
SNMOC SNMOC
RC-DA RC-DA
1/16/01 1/17/01
Comoound CAS No. Lie Lie
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l -butene
«-hexane
fra«5-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
0.0032
0.0000
0.0000
0.0000
0.1307
0.0000
0.0037
0.0003
0.0003
0.0016
0.0000
0.0000
0.0000
0.0013
0.0001
0.0000
0.0003
0.0000
0.0000
0.0001
0.0000
0.0002
0.0000
0.0000
0.0002
0.0000
0.0003
0.0005
0.0000
0.0000
0.0000
0.0061
0.0000
0.0000
0.0011
0.0000
0.0010
0.0000
0.0007
0.0000
0.0000
0.0000
0.0179
0.0137
0.0250
0.0020
0.0354
0.0000
0.0004
0.0013
0.0000
0.0009
0.0004
0.0005
0.0000
0.0011
0.0004
0.0000
0.0007
0.0000
0.0003
0.0006
0.0000
0.0013
0.0005
0.0000
0.0004
0.0006
0.0010
0.0011
0.0000
0.0009
0.0000
0.0045
0.0000
0.0000
0.0015
0.0006
0.0015
0.0000
0.0004
0.0009
0.0002
0.0000
"0.0000".
No Negs
SNMOC
RC-DA
1/18/01
us
0.0056
0.0034
0.0033
0.0038
0.2758
0.0000
0.0000
0.0005
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0001
0.0000
0.0001
0.0000
0.0000
0.0002
0.0002
0.0000
0.0001
0.0001
0.0061
0.0004
0.0000
0.0001
0.0000
0.0038
0.0000
0.0000
0.0008
0.0000
0.0004
0.0001
0.0000
0.0000
0.0000
0.0004
G-14
-------
Table G-3. (Continued)
Comoound
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
w-xylene//>-xylene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
cc-pinene
«-propylbenzene
w-ethyltoluene
/>-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
w-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
SNMOC
RC-DA
1/16/01
us
0.0002
0.0002
0.0001
0.0000
0.0002
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0001
0.0000
0.0000
0.0000
0.0000
0.0006
0.0004
0.0001
0.0003
0.0000
0.0004
0.0000
0.0000
0.0004
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.1546
0.0000
0.1546
SNMOC
RC-DA
1/17/01
us
0.0006
0.0008
0.0003
0.0000
0.0004
0.0007
0.0003
0.0005
0.0000
0.0022
0.0003
0.0005
0.0005
0.0005
0.0000
0.0010
0.0004
0.0000
0.0003
0.0007
0.0004
0.0012
0.0009
0.0011
0.0017
0.0000
0.0008
0.0008
0.0008
0.0007
0.0000
0.0015
0.0009
0.0389
0.0000
0.0009
0.1766
0.0000
0.1766
No Negs
SNMOC
RC-DA
1/18/01
us
0.0001
0.0003
0.0001
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0005
0.0000
0.0000
0.0006
0.0002
0.0000
0.0004
0.0000
0.0000
0.0000
0.0000
0.0000
0.0004
0.0002
0.0010
0.0005
0.0000
0.0007
0.0000
0.0005
0.0004
0.0000
0.0008
0.0008
0.0215
0.0000
0.0009
0.3356
0.0263
0.3619
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
G-15
-------
Table G-4A. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day
All negative values resulting from the subtraction RC-DA have been replaced by "0.0000".
Residence Dilution
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
Chamber Air
1/16/01 Total 1/16/01
V=4.2L Collected V=4.8L
ue/m3 tie ue/m3
4.1600
2.6700
22.8300
4.8500
65.4000
0.0000
1.5900
0.2700
0.0600
1.4100
0.1300
0.1400
0.0000
0.7700
0.1300
0.0000
0.4600
0.0000
0.1300
0.1500
0.0000
0.2700
0.1200
0.0000
0.1300
0.2600
0.3000
2163.7737
1388.7682
11874.7487
2522.6689
34017.0199
0.0000
827.0193
140.4372
31.2083
733.3945
67.6179
72.8193
0.0000
400.5062
67.6179
0.0000
239.2634
0.0000
67.6179
78.0207
0.0000
140.4372
62.4166
0.0000
67.6179
135.2359
156.0414
2.9700
2.7100
23.0600
4.9400
29.9900
0.0000
0.6200
0.1800
0.0000
0.9000
0.1300
0.1300
0.0000
0.4100
0.0900
0.1100
0.3300
0.1500
0.1100
0.1100
0.0800
0.2000
0.1100
0.0000
0.0800
0.3400
0.2000
Total
Collected
U2
1511.7710
1379.4274
11737.8583
2514.5282
15265.3240
0.0000
315.5886
91.6225
0.0000
458.1124
66.1718
66.1718
0.0000
208.6957
45.8112
55.9915
167.9746
76.3521
55.9915
55.9915
40.7211
101.8028
55.9915
0.0000
40.7211
173.0647
101.8028
1/16/01
RC-DA
us
652.0027
9.3408
136.8904
8.1407
18751.6959
0.0000
511.4307
48.8148
31.2083
275.2820
1.4461
6.6475
0.0000
191.8105
21.8067
-55.9915
71.2889
-76.3521
11.6264
22.0292
-40.7211
38.6345
6.4250
0.0000
26.8968
-37.8288
54.2386
No Negs
1/16/01
RC-DA
us
652.0027
9.3408
136.8904
8.1407
18751.7000
0.0000
511.4307
48.8148
31.2083
275.2820
1.4461
6.6475
0.0000
191.8105
21.8067
0.0000
71.2889
0.0000
11.6264
22.0292
0.0000
38.6345
6.4250
0.0000
26.8968
0.0000
54.2386
G-16
-------
Table G-4A. (Continued)
Comoound CAS No.
3-methylpentane 96-14-0
2-methyl-l-pentene 763-29-1
1-hexene 592-41-6
2-ethyl-l-butene 760-21-4
«-hexane 110-54-3
trans '-2-hexene 4050-45-7
c/s-2-hexene 7688-21-3
methylcyclopentane 96-37-7
2,4-dimethylpentane 108-08-7
benzene 71-43-2
cyclohexane 110-82-7
2-methylhexane 591-76-4
2,3-dimethylpentane 565-59-3
3-methylhexane 589-34-4
1-heptene 592-76-7
2,2,4-trimethylpentane 540-84-1
«-heptane 142-82-5
methylcyclohexane 108-87-2
2,2,3 -trimethylpentane 564-02-3
2,3,4-trimethylpentane 565-75-3
toluene 108-88-3
2-methylheptane 592-27-8
3-methylheptane 589-81-1
1-octene 111-66-0
«-octane 111-65-9
ethylbenzene 100-41-4
w-xylene/p-xylene 108-38-3/106-42-3
styrene 100-42-5
o-xylene 95-47-6
Residence Dilution
Chamber Air
1/16/01 Total 1/16/01
V=4.2L Collected V=4.8L
ue/m3 Lie ue/m3
0.3900
0.0000
0.2200
0.0000
2.6100
0.0000
0.0000
0.5700
0.1400
0.4500
0.2000
0.1700
0.1800
0.1000
0.0000
0.2800
0.2000
0.1900
0.0000
0.1800
0.7400
0.1000
0.1100
0.0000
0.3900
0.2200
0.5000
0.3700
0.3700
202.8538
0.0000
114.4303
0.0000
1357.5600
0.0000
0.0000
296.4786
72.8193
234.0621
104.0276
88.4234
93.6248
52.0138
0.0000
145.6386
104.0276
98.8262
0.0000
93.6248
384.9021
52.0138
57.2152
0.0000
202.8538
114.4303
260.0690
192.4510
192.4510
0.2400
0.0000
0.1900
0.0000
1.0100
0.0000
0.2600
0.2800
0.1200
0.1900
9.9800
0.0000
0.1800
0.1400
0.0000
0.2100
0.1400
0.1400
0.0000
0.1100
0.6500
0.1200
0.1100
0.0000
0.3700
0.2300
0.5800
0.6200
0.3500
Total
Collected
us
122.1633
0.0000
96.7126
0.0000
514.1039
0.0000
132.3436
142.5239
61.0817
96.7126
5079.9578
0.0000
91.6225
71.2619
0.0000
106.8929
71.2619
71.2619
0.0000
55.9915
330.8590
61.0817
55.9915
0.0000
188.3351
117.0732
295.2280
315.5886
178.1548
1/16/01
RC-DA
us
80.6905
0.0000
17.7177
0.0000
843.4560
0.0000
-132.3436
153.9547
11.7377
137.3494
-4975.9302
88.4234
2.0023
-19.2481
0.0000
38.7457
32.7657
27.5643
0.0000
37.6333
54.0431
-9.0679
1.2237
0.0000
14.5187
-2.6428
-35.1590
-123.1375
14.2962
No Negs
1/16/01
RC-DA
us
80.6905
0.0000
17.7177
0.0000
843.4560
0.0000
0.0000
153.9547
11.7377
137.3494
0.0000
88.4235
2.0023
0.0000
0.0000
38.7457
32.7657
27.5643
0.0000
37.6333
54.0431
0.0000
1.2237
0.0000
14.5187
0.0000
0.0000
0.0000
14.2962
G-17
-------
Table G-4C. (Continued)
Comoound
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
/>-ethyltoluene
1,3,5-trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
ra-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence
Chamber
1/16/01 Total
V=4.2L Collected
ug/m3 Lie
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
2.
0.
18
0.
0.
1200
2700
0800
0000
1100
3200
2600
5100
4600
1200
8000
0000
9200
2600
1500
0000
0000
1000
1300
.9100
0000
1200
62.4166
140.4372
41.6110
0.0000
57.2152
166.4441
135.2359
265.2703
239.2634
62.4166
416.1103
0.0000
3079.2165
135.2359
78.0207
0.0000
0.0000
1092.2896
67.6179
9835.8080
0.0000
62.4166
Dilution
Air
1/16/01
V=4.8L
ue/ni3
0.
0.
0.
0.
0.
0.
0.
0800
2400
1000
0600
0900
1500
1500
0.4200
0.
0.
0.
0.
6.
0.
0.
0.
0.
1.
0.
25
0.
0.
3500
3600
6200
0000
8100
1500
1200
0700
0000
8700
2700
.8600
0000
2100
Total
Collected
us
40.7211
122.1633
50.9014
30.5408
45.8112
76.3521
76.3521
213.7858
178.1548
183.2450
315.5886
0.0000
3466.3840
76.3521
61.0817
35.6310
0.0000
951.8558
137.4337
13163.0970
0.0000
106.8929
1/16/01
RC-DA
us
21.6954
18.2739
-9.2903
-30.5408
11.4039
90.0921
58.8838
51.4845
61.1086
-120.8284
100.5218
0.0000
-387.1675
58.8838
16.9390
-35.6310
0.0000
140.4338
-69.8158
-3327.2889
0.0000
-44.4763
No Negs
1/16/01
RC-DA
us
21
18
0.
0.
11
90
58
51
61
0.
.6955
.2739
0000
0000
.4039
.0921
.8838
.4845
.1086
0000
100.5218
0.
0.
58
0000
0000
.8838
16.9390
0.
0.
0000
0000
140.4338
0.
0.
0.
0.
0000
0000
0000
0000
G-18
-------
Table G-4C. (Continued)
Comoound CAS No.
Total speciated
Total unspeciated
Total speciated + unspeciated*
Residence Dilution
Chamber Air
1/16/01 Total 1/16/01
V=4.2L Collected V=4.8L
ue/m3 Lie ue/m3
145.5500 75706.0741 122.1500
26.3300 13695.2314 23.9700
171.8800 89401.3054 146.1200
Total 1/16/01
Collected RC-DA
us us
62176.0361 13530.0379
12201.0609 1494.1705
74377.0970 15024.2085
No Negs
1/16/01
RC-DA
us
23063.5037
1494.1705
24557.6742
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
16-Jan
Venturi Flow (Average) 18.53 sLpm
Dilution Flow (Average) 847.89 sLpm
Run Time 600.33 min
Volume Combustion Air 11124.115 L
Volume Dilution Air 509013.8 L
Residence Chamber 520137.92 L
RC-DA 11124.115 L
G-19
-------
Table G-4B. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day
All negative values
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
tmns-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
resulting from the RC-DA subtraction have been replaced by "0.0000."
Residence Dilution
Chamber Air
1/17/01 1/17/01 1/17/01
V=5L Total V=4.7L Total RC-DA
CAS No. ue/m3 tie ue/ni3 tie ue
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
7.6900
7.1000
33.9500
3.0000
43.2400
0.0000
0.4000
0.4200
0.0000
0.5700
0.2000
0.2200
0.0000
0.4300
0.1600
0.0000
0.3000
0.1300
0.1400
0.2300
0.0000
0.4300
0.1800
0.0000
0.1700
0.3400
0.2800
4000.1159
3693.2149
17659.8094
1560.5133
22492.1990
0.0000
208.0684
218.4719
0.0000
296.4975
104.0342
114.4376
0.0000
223.6736
83.2274
0.0000
156.0513
67.6222
72.8240
119.6394
0.0000
223.6736
93.6308
0.0000
88.4291
176.8582
145.6479
4.3700
4.6300
30.7900
2.7600
38.4700
0.0000
0.3300
0.1700
0.0000
0.4200
0.1200
0.1300
0.0000
0.2300
0.0900
0.0000
0.1800
0.1300
0.0900
0.1100
0.0000
0.1900
0.0900
0.0000
0.1000
0.2400
0.0900
2226.2273
2358.6802
15685.4782
1406.0383
19597.9327
0.0000
168.1133
86.6038
0.0000
213.9624
61.1321
66.2264
0.0000
117.1699
45.8491
0.0000
91.6982
66.2264
45.8491
56.0378
0.0000
96.7925
45.8491
0.0000
50.9434
122.2642
45.8491
1773.8885
1334.5347
1974.3311
154.4750
2894.2663
0.0000
39.9552
131.8681
0.0000
82.5352
42.9021
48.2112
0.0000
106.5037
37.3783
0.0000
64.3532
1.3958
26.9749
63.6016
0.0000
126.8811
47.7817
0.0000
37.4857
54.5940
99.7988
No Negs
1/17/01
RC-DA
us
1773.8885
1334.5347
1974.3311
154.4750
2894.2663
0.0000
39.9552
131.8681
0.0000
82.5352
42.9021
48.2110
0.0000
106.5032
37.3783
0.0000
64.3532
1.3958
26.9749
63.6016
0.0000
126.8811
47.7817
0.0000
37.4857
54.5940
99.7988
G-20
-------
Table G-4B. (Continued)
Comoound
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l-butene
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
w-xylene//>-xylene
styrene
o-xylene
Residence
Chamber
1/17/01
V=5L
CAS No. iie/m3
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
0.4000
0.0000
0.3400
0.0000
1.6900
0.0000
0.0000
0.5200
0.2400
0.4400
0.1900
0.1600
0.3400
0.1400
0.0000
0.2500
0.2500
0.1800
0.0000
0.1800
0.4700
0.1500
0.1900
0.0000
0.6800
0.2100
0.4400
0.2200
0.2700
Total
112
208.0684
0.0000
176.8582
0.0000
879.0892
0.0000
0.0000
270.4890
124.8411
228.8753
98.8325
83.2274
176.8582
72.8240
0.0000
130.0428
130.0428
93.6308
0.0000
93.6308
244.4804
78.0257
98.8325
0.0000
353.7164
109.2359
228.8753
114.4376
140.4462
Dilution
Air
1/17/01
V=4.7L
mi/in3
0.2000
0.0000
0.1800
0.0000
0.8400
0.0000
0.0000
0.2400
0.1200
0.1400
0.3300
0.0800
0.1800
0.1100
0.0000
0.1400
0.0900
0.1200
0.0000
0.1000
0.3600
0.0900
0.1000
0.0000
0.2500
0.1500
0.3700
0.1200
0.1900
Total
us
101.8868
0.0000
91.6982
0.0000
427.9247
0.0000
0.0000
122.2642
61.1321
71.3208
168.1133
40.7547
91.6982
56.0378
0.0000
71.3208
45.8491
61.1321
0.0000
50.9434
183.3963
45.8491
50.9434
0.0000
127.3585
76.4151
188.4906
61.1321
96.7925
1/17/01
RC-DA
us
106.1816
0.0000
85.1600
0.0000
451.1645
0.0000
0.0000
148.2248
63.7090
157.5545
-69.2808
42.4726
85.1600
16.7862
0.0000
58.7220
84.1937
32.4987
0.0000
42.6874
61.0841
32.1766
47.8891
0.0000
226.3578
32.8208
40.3846
53.3055
43.6537
No Negs
1/17/01
RC-DA
us
106.1816
0.0000
84.1600
0.0000
451.1645
0.0000
0.0000
148.2248
63.7090
157.5545
0.0000
42.4726
85.1600
16.7862
0.0000
58.7220
84.1937
32.4987
0.0000
42.6874
61.0841
32.1766
47.8891
0.0000
226.3578
32.8208
40.3846
53.3055
43.6537
G-21
-------
Table G-4B. (Continued)
Comoound
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
/•-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
ra-diethylbenzene
/•-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence
Chamber
1/17/01
V=5L
ug/m3
0.0000
0.3100
0.1600
0.0000
0.1200
0.2800
0.2100
0.3600
0.3200
0.2200
0.6000
0.0000
0.9400
0.2400
0.1500
0.1300
0.0000
0.7300
0.1800
12.1100
0.0000
0.1800
Total
112
0.0000
161.2530
83.2274
0.0000
62.4205
145.6479
109.2359
187.2616
166.4548
114.4376
312.1027
0.0000
488.9608
124.8411
78.0257
67.6222
0.0000
379.7249
93.6308
6299.2722
0.0000
93.6308
Dilution
Air
1/17/01
V=4.7L
mi/in3
0.0000
0.1200
0.0900
0.0000
0.0700
0.1400
0.1300
0.1200
0.1400
0.0000
0.2700
0.0000
0.8300
0.0900
0.0000
0.0000
0.0000
0.4500
0.0000
4.6100
0.0000
0.0000
Total
us
0.0000
61.1321
45.8491
0.0000
35.6604
71.3208
66.2264
61.1321
71.3208
0.0000
137.5472
0.0000
422.8304
45.8491
0.0000
0.0000
0.0000
229.2454
0.0000
2348.4915
0.0000
0.0000
1/17/01
RC-DA
us
0.0000
100.1209
37.3783
0.0000
26.7601
74.3271
43.0095
126.1295
95.1340
114.4376
174.5554
0.0000
66.1305
78.9920
78.0257
67.6222
0.0000
150.4795
93.6308
3950.7807
0.0000
93.6308
No Negs
1/17/01
RC-DA
us
0.0000
100.1209
37.3783
0.0000
26.7601
74.3271
43.0095
126.1295
95.1340
114.4376
174.5554
0.0000
66.1305
78.9920
78.0257
67.6222
0.0000
150.4795
93.6308
3950.7807
0.0000
93.6308
G-22
-------
Table G-4B. (Continued)
Comoound CAS No.
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
Residence
Chamber
1/17/01
V=5L
ug/m3
124.7700
8.7200
133.4900
Total
112
64901.7500
4535.8921
69437.6421
Dilution
Air
1/17/01
V=4.7L
mi/in3
95.2900
10.8200
106.1100
Total
us
48543.9825
5512.0778
54056.0603
1/17/01
RC-DA
us
16357.7675
-976.1857
15381.5818
No Negs
1/17/01
RC-DA
us
16426.0475
0.0000
16426.0475
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
17-Jan
Venturi Flow (Average) 17.88
Dilution Flow (Average) 848.35
Run Time 600.5
Volume Combustion Air 1073 6.94
Volume Dilution Air 509434.175
Residence Chamber 520171.115
sLpm
sLpm
min
L
L
L
G-23
-------
Table G-4C. Greensboro A&T Field Test, January 16-18, 2001
Sample Concentrations by Test Day
All negative values
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
tmns-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
resulting from the RC-DA subtraction have been replaced by "0.0000".
Residence Dilution
Chamber Air
1/18/01 RC 1/18/01 DA RC-DA
V=5.2L Total V=4.8L Total 1/18/01
CAS No. ue/m3 tie ue/m3 tie Total tie
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
5.8400
4.3100
25.2600
4.3300
198.1800
0.0000
0.3100
0.2300
0.0000
0.4000
0.1000
0.1200
0.0000
0.2200
0.0900
0.0000
0.1600
0.0000
0.0900
0.1100
0.0000
0.1900
0.1100
0.0000
0.0900
0.1900
1.3000
3048.1870
2249.6038
13184.4527
2260.0428
103440.0173
0.0000
161.8044
120.0485
0.0000
208.7799
52.1950
62.6340
0.0000
114.8290
46.9755
0.0000
83.5120
0.0000
46.9755
57.4145
0.0000
99.1705
57.4145
0.0000
46.9755
99.1705
678.5348
5.1500
3.9700
26.6700
3.9000
157.2400
0.0000
0.3300
0.1400
0.0000
0.4200
0.1000
0.1400
0.0000
0.2500
0.0700
0.0000
0.1600
0.1400
0.0800
0.1200
0.0000
0.1700
0.0800
0.0000
0.0800
0.1800
0.1300
2629.2842
2026.8462
13616.1181
1991.1084
80277.4058
0.0000
168.4784
71.4757
0.0000
214.4271
51.0541
71.4757
0.0000
127.6352
35.7378
0.0000
81.6865
71.4757
40.8432
61.2649
0.0000
86.7919
40.8432
0.0000
40.8432
91.8973
66.3703
418.9029
222.7575
-431.6654
268.9344
23162.6115
0.0000
-6.6740
48.5728
0.0000
-5.6471
1.1409
-8.8417
0.0000
-12.8062
11.2376
0.0000
1.8255
-71.4757
6.1322
-3.8504
0.0000
12.3786
16.5712
0.0000
6.1322
7.2732
612.1645
No Negs
RC-DA
1/18/01
Total lie
418.9029
222.7575
0.0000
268.9344
23162.6100
0.0000
0.0000
48.5728
0.0000
0.0000
1.1409
0.0000
0.0000
0.0000
11.2376
0.0000
1.8255
0.0000
6.1322
0.0000
0.0000
12.3786
16.5712
0.0000
6.1322
7.2732
612.1645
G-24
-------
Table G-4C. (Continued)
Comoound
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l-butene
«-hexane
trans-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
w-xylene//>-xylene
styrene
o-xylene
Residence
Chamber
1/18/01
V=5.2L
CAS No. ue/m3
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.2500
.0000
.1900
.0000
.3400
.0000
.0000
.3200
.1000
.2100
.1300
.0800
.1500
.0600
.0800
.1400
.1500
.1100
.0000
.1000
.2700
.0700
.0800
.0000
.2600
.1100
.2500
.2000
.1800
RC
Total
112
130.4875
0.0000
99.1705
0.0000
699.4128
0.0000
0.0000
167.0239
52.1950
109.6095
67.8535
41.7560
78.2925
31.3170
41.7560
73.0730
78.2925
57.4145
0.0000
52.1950
140.9265
36.5365
41.7560
0.0000
135.7070
57.4145
130.4875
104.3900
93.9510
Dilution
Air
1/18/01
V=4.8L
ue/m3
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0.
0.
0
0
0.
0.
0.
0.
0.
0
0.
0.
0.
.1900
.0000
.1900
.0000
.6600
.0000
.0000
.1800
.1000
.1500
.1300
.0800
.1600
.0700
.0000
.1300
.1100
.0900
.0000
.1000
.3100
.0900
.1000
.0000
.1800
.1300
.3000
.0900
.1600
DA
Total
us
97
0.
97
0.
.0027
0000
.0027
0000
336.9568
0.
0.
91
51
76
66
40
81
35
0.
66
56
45
0.
51
0000
0000
.8973
.0541
.5811
.3703
.8432
.6865
.7378
0000
.3703
.1595
.9487
0000
.0541
158.2676
45
51
0.
91
66
.9487
.0541
0000
.8973
.3703
153.1622
45
81
.9487
.6865
RC-DA
1/18/01
Total Lie
33.4847
0.0000
2.1678
0.0000
362.4560
0.0000
0.0000
75.1266
1.1409
33.0284
1.4832
0.9127
-3.3940
-4.4209
41.7560
6.7027
22.1330
11.4658
0.0000
1.1409
-17.3411
-9.4122
-9.2981
0.0000
43.8096
-8.9558
-22.6747
58.4413
12.2645
No Negs
RC-DA
1/18/01
Total lie
33
0.
2.
0.
.4847
0000
1678
0000
362.4560
0.
0.
75
1.
33
1.
0.
0.
0.
41
6.
22
11
0.
1.
0.
0.
0.
0.
43
0.
0.
58
12
0000
0000
.1266
1409
.0284
4832
9127
0000
0000
.7560
7027
.1330
.4658
0000
1409
0000
0000
0000
0000
.8097
0000
0000
.4413
.2645
G-25
-------
Table G-4C. (Continued)
Comoound
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
/>-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
m-diethylbenzene
/>-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Residence
Chamber
1/18/01
V=5.2L
ug/m3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
0
0
.0800
.1800
.0900
.0000
.0700
.1100
.1000
.1400
.1100
.2000
.3000
.0000
.4500
.0800
.1000
.0700
.0000
.4200
.1500
.1000
.0000
.1800
RC
Total
112
41.7560
93.9510
46.9755
0.0000
36.5365
57.4145
52.1950
73.0730
57.4145
104.3900
156.5849
0.0000
234.8774
41.7560
52.1950
36.5365
0.0000
219.2189
78.2925
3705.8438
0.0000
93.9510
Dilution
Air
1/18/01
V=4.8L
ue/m3
0.
0.
0.
0.
0.
0.
0.
0
0
0.
0
0.
0.
0
0
0
0.
0.
0.
3.
0.
0.
.0800
.1200
.0900
.0000
.0800
.1300
.1000
.0600
.0700
.0000
.2200
.0000
.3500
.0900
.0000
.0000
.0000
.2900
.0000
.2100
.0000
.0000
DA
Total
us
40.8432
61.2649
45.9487
0.0000
40.8432
66.3703
51.0541
30.6324
35.7378
0.0000
112.3189
0.0000
178.6892
45.9487
0.0000
0.0000
0.0000
148.0568
0.0000
1638.8354
0.0000
0.0000
RC-DA
1/18/01
Total Lie
0.
32
1.
0.
-4
-8
1.
42
21
9127
.6861
0268
0000
.3068
.9558
1409
.4405
.6766
104.3900
44
0.
56
-4
52
.2660
0000
.1882
.1927
.1950
36.5365
0.
71
78
0000
.1622
.2925
2067.0084
0.
0000
93.9510
No Negs
RC-DA
1/18/01
Total lie
0.
32
1.
0.
0.
0.
1.
42
21
9127
.6861
0268
0000
0000
0000
1409
.4405
.6766
104.3900
44
0.
56
0.
52
.2660
0000
.1882
0000
.1950
36.5365
0.
71
78
0000
.1622
.2925
2067.0080
0.
93
0000
.9510
G-26
-------
Table G-4C. (Continued)
Total
Total
Total
Comoound
speciated
unspeciated
soeciated +
CAS No.
unsoeciated*
Residence
Chamber
1/18/01
V=5.2L
ug/m3
256.3900
12.7900
269.1800
RC
Total
112
133822.7169
6675.7383
140498.4552
Dilution
Air
1/18/01
V=4.8L
ue/m3
208.1100
8.3800
216.4900
DA
Total
us
106248.6068
4278.3303
110526.9371
RC-DA
1/18/01
Total Lie
27574.1102
2397.4080
29971.5181
No Negs
RC-DA
1/18/01
Total lie
28208.0208
2397.4080
30605.4288
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
18-Jan
Venturi Flow (Average) 19.01
Dilution Flow (Average) 850.66
RunTime 600.17
Volume Combustion Air 11409.2317
Volume Dilution Air 510540.6122
Residence Chamber 521949.8439
sLpm
sLpm
min
L
L
L
G-27
-------
Table G-5A. SPECIATE Format
SNMOC Values for 1/16,1/17,1/18
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
tmns-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l -butene
CAS No.
4-84-0
74-86-2
74-85-1
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
1/16/01
RC-DA Uncertainty
U2 US.
652.0027
9.3408
136.8904
8.1407
18751.7000
0.0000
511.4307
48.8148
31.2083
275.2820
1.4461
6.6475
0.0000
191.8105
21.8067
0.0000
71.2889
0.0000
11.6264
22.0292
0.0000
38.6345
6.4250
0.0000
26.8968
0.0000
54.2386
80.6905
0.0000
17.7177
0.0000
13.0152
12.0140
10.9016
6.8970
12.2365
6.2295
4.0047
5.8958
11.2354
7.2307
10.7904
16.1300
9.0105
9.0105
11.2354
1.3349
9.1218
13.4602
13.0152
16.4637
15.5738
16.0187
7.6756
19.0222
8.7881
16.7974
16.7974
17.0199
16.6862
Percent
Total
2.6550
0.0380
0.5574
0.0331
76.3578
0.0000
2.0826
0.1988
0.1271
1.1210
0.0059
0.0271
0.0000
0.7811
0.0888
0.0000
0.2903
0.0000
0.0473
0.0897
0.0000
0.1573
0.0262
0.0000
0.1095
0.0000
0.2209
0.3286
0.0000
0.0721
0.0000
Uncertainty
as % Total
0.0530
0.0489
0.0444
0.0281
0.0498
0.0254
0.0163
0.0240
0.0458
0.0294
0.0439
0.0657
0.0367
0.0458
0.0371
0.0548
0.0670
0.0634
0.0313
0.0358
0.0684
0.0693
G-28
-------
Table G-5A. (Continued)
Comoound
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
w-xylene//>-xylene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
p-ethyltoluene
CAS No.
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
1/16/01
RC-DA Uncertainty
us us
843.4560
0.0000
0.0000
153.9547
11.7377
137.3494
0.0000
88.4235
2.0023
0.0000
0.0000
38.7457
32.7657
27.5643
0.0000
37.6333
54.0431
0.0000
1.2237
0.0000
14.5187
0.0000
0.0000
0.0000
14.2962
21.6955
18.2739
0.0000
0.0000
11.4039
90.0921
58.8838
12.9040
12.9040
12.9040
10.6792
13.3489
8.4543
18.9110
2.2248
11.1241
9.3443
9.2330
11.2354
5.6733
10.7904
11.2354
7.7869
4.4496
4.3384
4.2272
4.1159
2.2248
3.0035
4.6721
7.6756
3.0035
2.3361
2.3361
4.4496
2.3361
2.2248
5.1171
5.8958
Percent
Total
3.4346
0.0000
0.0000
0.6269
0.0478
0.5593
0.0000
0.3601
0.0082
0.0000
0.0000
0.1578
0.1334
0.1122
0.0000
0.1532
0.2201
0.0000
0.0050
0.0000
0.0591
0.0000
0.0000
0.0000
0.0582
0.0883
0.0744
0.0000
0.0000
0.0464
0.3669
0.2398
Uncertainty
as % Total
0.0525
0.0435
0.0544
0.0344
0.0091
0.0453
0.0458
0.0231
0.0439
0.0317
0.0181
0.0172
0.0091
0.0122
0.0095
0.0095
0.0091
0.0208
0.0240
G-29
-------
Table G-5A. (Continued)
Comoound
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
w-diethylbenzene
/•-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Total speciated
Total unspeciated
Total speciated + unspeciated*
1/16/01
RC-DA Uncertainty
us us
51.4845
61.1086
0.0000
100.5218
0.0000
0.0000
58.8838
16.9390
0.0000
0.0000
140.4338
0.0000
0.0000
0.0000
0.0000
23063.5037
1494.1705
24557.6742
3.2260
3.4485
2.3361
3.2260
2.4473
2.4473
2.6698
1.4461
1.6686
2.1136
2.1136
4.6721
4.7834
4.6721
4.7834
Percent
Total
0.2096
0.2488
0.0000
0.4093
0.0000
0.0000
0.2398
0.0690
0.0000
0.0000
0.5719
0.0000
0.0000
0.0000
0.0000
Uncertainty
as % Total
0.0131
0.0140
0.0131
0.0109
0.0059
0.0086
Total NMOC with unknowns in //g/m is an estimate based on propane only.
G-30
-------
Table G-5B. SPECIATE Format
SNMOC Values for 1/16,1/17,1/18
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
trans -2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l -butene
CAS No.
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
1/17/01
RC-DA
US
1773.8885
1334.5347
1974.3311
154.4750
2894.2663
0.0000
39.9552
131.8681
0.0000
82.5352
42.9021
48.2110
0.0000
106.5032
37.3783
0.0000
64.3532
1.3958
26.9749
63.6016
0.0000
126.8811
47.7817
0.0000
37.4857
54.5940
99.7988
106.1816
0.0000
84.1600
0.0000
Uncertainty
us
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
10.7992
8.1245
12.0195
0.9404
17.6200
0.0000
0.2432
0.8028
0.0000
0.5025
0.2612
0.2935
0.0000
0.6484
0.2276
0.0000
0.3918
0.0085
0.1642
0.3872
0.0000
0.7724
0.2909
0.0000
0.2282
0.3324
0.6076
0.6464
0.0000
0.5124
0.0000
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
G-31
-------
Table G-5B. (Continued)
Comoound
«-hexane
trans -2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
«-xylene//>-xylene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
CAS No.
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
1/17/01
RC-DA
US
451.1645
0.0000
0.0000
148.2248
63.7090
157.5545
0.0000
42.4726
85.1600
16.7862
0.0000
58.7220
84.1937
32.4987
0.0000
42.6874
61.0841
32.1766
47.8891
0.0000
226.3578
32.8208
40.3846
53.3055
43.6537
0.0000
100.1209
37.3783
0.0000
26.7601
74.3271
Uncertainty
us
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
2.7466
0.0000
0.0000
0.9024
0.3879
0.9592
0.0000
0.2586
0.5184
0.1022
0.0000
0.3575
0.5126
0.1978
0.0000
0.2599
0.3719
0.1959
0.2915
0.0000
1.3780
0.1998
0.2459
0.3245
0.2658
0.0000
0.6095
0.2276
0.0000
0.1629
0.4525
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
G-32
-------
Table G-5B. (Continued)
Comoound
/•-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
ra-diethylbenzene
/•-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
1/17/01
RC-DA
US
43.0095
126.1295
95.1340
114.4376
174.5554
0.0000
66.1305
78.9920
78.0257
67.6222
0.0000
150.4795
93.6308
3950.7807
0.0000
93.6308
16426.0475
0.0000
16426.0475
Uncertainty
us
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
0.2618
0.7679
0.5792
0.6967
1.0627
0.0000
0.4026
0.4809
0.4750
0.4117
0.0000
0.9161
0.5700
24.0519
0.0000
0.5700
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
G-33
-------
Table G-5C. SPECIATE Format
SNMOC Values for 1/16,1/17,1/18
Comoound
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/ 1 -butene
1,3 -butadiene
«-butane
tmns-2-butene
c/s-2-butene
3 -methyl- 1 -butene
isopentane
1-pentene
2-methyl- 1 -butene
«-pentane
isoprene
fra«s-2-pentene
c/s-2-pentene
2-methyl-2 -butene
2,2-dimethylbutane
cyclopentene
4-methyl- 1 -pentene
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
2-methyl- 1 -pentene
1-hexene
2-ethyl-l -butene
CAS No.
4-84-0
74-86-2
74-85-1
115-07-01
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
1/18/01
RC-DA
U2
418.9029
222.7575
0.0000
268.9344
23162.6100
0.0000
0.0000
48.5728
0.0000
0.0000
1.1409
0.0000
0.0000
0.0000
11.2376
0.0000
1.8255
0.0000
6.1322
0.0000
0.0000
12.3786
16.5712
0.0000
6.1322
7.2732
612.1645
33.4847
0.0000
2.1678
0.0000
Uncertainty
us.
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
1.3687
0.7278
0.0000
0.8787
75.6814
0.0000
0.0000
0.1587
0.0000
0.0000
0.0037
0.0000
0.0000
0.0000
0.0367
0.0000
0.0060
0.0000
0.0200
0.0000
0.0000
0.0404
0.0541
0.0000
0.0200
0.0238
2.0002
0.1094
0.0000
0.0071
0.0000
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
G-34
-------
Table G-5C. (Continued)
Comoound
«-hexane
fra«s-2-hexene
c/s-2-hexene
methylcyclopentane
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3-dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
«-heptane
methylcyclohexane
2,2,3 -trimethylpentane
2,3,4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
«-octane
ethylbenzene
m-xylene//>-xylene
styrene
o-xylene
1-nonene
«-nonane
isopropylbenzene
a-pinene
«-propylbenzene
w-ethyltoluene
CAS No.
110-54-3
4050-45-7
7688-21-3
96-37-7
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
1/18/01
RC-DA
US
362.4560
0.0000
0.0000
75.1266
1.1409
33.0284
1.4832
0.9127
0.0000
0.0000
41.7560
6.7027
22.1330
11.4658
0.0000
1.1409
0.0000
0.0000
0.0000
0.0000
43.8097
0.0000
0.0000
58.4413
12.2645
0.9127
32.6861
1.0268
0.0000
0.0000
0.0000
Uncertainty
us
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
1.1843
0.0000
0.0000
0.2455
0.0037
0.1079
0.0048
0.0030
0.0000
0.0000
0.1364
0.0219
0.0723
0.0375
0.0000
0.0037
0.0000
0.0000
0.0000
0.0000
0.1431
0.0000
0.0000
0.1910
0.0401
0.0030
0.1068
0.0034
0.0000
0.0000
0.0000
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
G-35
-------
Table G-5C. (Continued)
Comoound
/•-ethyltoluene
1 , 3 ,5 -trimethylbenzene
o-ethyltoluene
p-pinene
1 ,2,4-trimethylbenzene
1-decene
«-decane
1 ,2,3 -trimethylbenzene
ra-diethylbenzene
/•-diethylbenzene
1-undecene
«-undecane
1-dodecene
«-dodecane
1-tridecene
«-tridecane
CAS No.
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
Total speciated
Total unspeciated
Total soeciated + unsoeciated*
1/18/01
RC-DA
US
1.1409
42.4405
21.6766
104.3900
44.2660
0.0000
56.1882
0.0000
52.1950
36.5365
0.0000
71.1622
78.2925
2067.0080
0.0000
93.9510
29208.0208
2397.4080
30605.4288
Uncertainty
us
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Percent
Total
0.0037
0.1387
0.0708
0.3411
0.1446
0.0000
0.1836
0.0000
0.1705
0.1194
0.0000
0.2325
0.2558
6.7537
0.0000
0.3070
Uncertainty
as % Total
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Total NMOC with unknowns in //g/m3 is an estimate based on propane only.
G-36
-------
Appendix H
Supporting Data for Air Toxics Analysis
-------
Table H-l. Greensboro A&T Field Test, January 16-18, 2001
Air Toxics
Laboratory Blank and Field (Ambient) Blank (1/16/01)
Compounds
acetylene
propylene
dichlorodifluoromethane
chloromethane
di chl orotetrafluoroethane
vinyl chloride
1,3 -butadiene
bromomethane
chloroethane
acetonitrile
acetone
tri chl or ofluorom ethane
acrylonitrile
1 , 1 -dichloroethene
methylene chloride
tri chl orotrifluoroethane
fr*
-------
Table H-l. (Continued)
ConiDOimds
cis- 1 ,2-dichloropropene
methyl isobutyl ketone
trans- 1 ,2-dichloropropene
1 , 1 ,2-trichloroethane
toluene
dibromochloromethane
1 ,2-dibromoethane
w-octane
tetrachl oroethy 1 ene
chlorobenzene
ethylbenzene
TO-, />-xylene
bromoform
styrene
1 , 1 ,2,2-tetrachloroethane
o-xylene
1,3,5 -trimethy Ib enzene
1 ,2,4-trimethylbenzene
TO-di chlorobenzene
chl oromethy Ib enzene
p-di chl orob enzene
o-di chl orob enzene
1 ,2,4-tri chlorobenzene
hexachloro- 1 .3 -butadiene
CAS No.
10061-01-5
108-10-1
10061-02-6
79-00-5
108-88-3
124-48-1
106-93-4
111-65-9
127-18-4
108-90-7
100-41-4
108-38-3/106-42-3
75-25-2
100-42-5
79-34-5
95-47-6
108-67-8
95-63-6
541-73-1
100-44-7
106-46-7
95-50-1
120-82-1
87-68-3
Laboratory
Blank
U2/m3
0
0
0
0
0.42
0
0
0
0
0
0.10
0.57
0
0
0
0.08
0
0
0
0
0
0
0
0
Ambient
Air
1/16/01
U2/m3
0
0
0
0
2.11
0
0
0.22
0
0
0.60
3.37
0
0.11
0
0.86
0.31
0.88
0
0
0.10
0
0.28
0
H-2
-------
Table H-2. A&T Air Toxics
Residence Chamber, Dilution,
Difference
1/16/01, 1/17/01, 1/18/01
Comoounds
acetylene
propylene
di chl orodifluoromethane
chloromethane
di chl orotetrafluoroethane
vinyl chloride
1,3 -butadiene
bromomethane
chloroethane
acetonitrile
acetone
tri chl or ofluorom ethane
acrylonitrile
1,1-dichloroethene
methylene chloride
tri chl orotrifluoroethane
trans- 1 ,2-dichloroethylene
1 , 1 -di chloroethane
methyl fert-butyl ether
methyl ethyl ketone
chloroprene
Residence
Chamber
1/16/01
CAS No. ue/m3
74-86-2
115-07-1
75-71-8
74-87-3
1320-37-2
75-01-4
106-99-0
74-83-9
75-00-3
75-05-8
67-64-1
75-69-4
107-13-1
75-35-4
75-09-2
26523-64-8
56-60-5
75-34-3
1634-04-1
78-93-3
126-99-8
1.77
3.90
3.71
0.90
0
0
0
0
0
0
0
0.31
0
0
1.91
0
0
0
0
0.90
0
Dilution
Air
1/16/01
ue/m3
1.82
3.82
4.02
0.99
0
0
0
0
0
0
0
0.26
0
0
1.80
0.21
0
0
0.22
8.36
0
Air
Toxics
RC-DA
1/16/01
ue/m3
-0.05
0.08
-0.31
-0.09
0
0
0
0
0
0
0
0.05
0
0
0.11
-0.21
0
0
-0.22
-7.46
0
Ambient
1/16/01
ug/m3
1.52
2.20
2.45
0.98
0.13
0
0.16
0
0
0
0
1.56
0
0
0.42
0.65
0
0
0.15
12.31
0
Residence
Chamber
1/17/01
ug/m3
4.15
2.21
3.96
0.77
0
0
0
0
0
0
0
0
0
0
2.84
0
0
0
0
0.83
0
Dilution
Air
1/17/01
ue/m3
2.88
2.14
4.18
0.82
0
0
0
0
0
0
0
0.13
0
0
1.84
0
0
0
0.11
5.38
0
Air Toxics
RC-DA
1/17/01
ue/m3
1.27
0.07
-0.22
-0.05
0
0
0
0
0
0
0
-0.13
0
0
1
0
0
0
-0.11
-4.55
0
Residence
Chamber
1/18/01
ue/m3
2.52
3.01
4.69
0.92
0
0
0
0
0
0
0
0
0
0
2.88
0
0
0
0
0.35
0
Dilution
Air
1/18/01
ue/m3
2.53
3.01
4.78
0.80
0
0
0
0
0
0
0
0
0
0
2.72
0
0
0
0
4.27
0
-------
Table H-2. (Continued)
Comoounds
cis- 1 ,3 -dichloroethylene
bromochloromethane
chloroform
ethyl tert-butyl ether
1 ,2-dichloroethane
1,1,1 -trichloroethane
benzene
carbon tetrachloride
tert-amyl methyl ether
1 ,2-dichloropropane
ethyl acrylate
bromodichloromethane
trichloroethylene
methyl methacrylate
cis- 1 ,2-dichloropropene
methyl isobutyl ketone
trans- 1 ,2-dichloropropene
1 , 1 ,2-trichloroethane
toluene
dibromochloromethane
1 ,2-dibromoethane
«-octane
tetrachloroethylene
chlorobenzene
ethylbenzene
m-, />-xylene
bromoform
styrene
CAS No.
156-59-2
74-97-5
67-66-3
637-92-3
107-06-2
71-55-6
71-43-2
56-23-5
994-05-8
78-87-5
140-88-5
75-27-4
79-01-6
80-62-6
10061-01-5
108-10-1
10061-02-6
79-00-5
108-88-3
124-48-1
106-93-4
111-65-9
127-18-4
108-90-7
100-41-4
108-38-37
106-42-3
75-25-2
100-42-5
1/16/01
ue/m3
0
0
0
0
0
0
0.41
0
0
0
0
0
0
0
0
0.24
0
0
0.60
0
0
0.18
0
0
0.23
1.09
0
0
1/16/01
ue/m3
0
0
0
0.30
0
0
0.22
0
0.48
0
0
0
0
0
0
1.70
0
0
0.52
0
0
0
0
0
0.21
1.21
0
0.27
1/16/01
ue/m3
0
0
0
-0.3
0
0
0.19
0
-0.48
0
0
0
0
0
0
-1.46
0
0
0.08
0
0
0.18
0
0
0.02
-0.12
0
-0.27
1/16/01
ue/m3
0
0
0
0
0
0
1.29
0.53
0
0
0
0
0
0
0
0
0
0
2.11
0
0
0.22
0
0
0.60
3.37
0
0.11
1/17/01
Lie/m3
0
0
0
0
0
0
0.48
0
0
0
0
0
0
0
0
0
0
0
0.42
0
0
0
0
0
0.15
0.71
0
0
1/17/01
ue/m3
0
0
0
0
0
0
0.15
0
0
0
0
0
0
0
0
0
0
0
0.37
0
0
0.15
0
0
0.13
0.75
0
0
1/17/01
ue/m3
0
0
0
0
0
0
0.33
0
0
0
0
0
0
0
0
0
0
0
0.05
0
0
-0.15
0
0
0.02
-0.04
0
0
1/18/01
u,g/m3
0
0
0
0
0
0
0.22
0
0
0
0
0
0
0
0
0
0
0
0.30
0
0
0
0
0
0.04
0.43
0
0
1/18/01
ue/m3
0
0
0
0
0
0
0.17
0
0
0
0
0
0
0
0
0
0
0
0.25
0
0
0
0
0
0.11
0.65
0
0
H-4
-------
Table H-2. (Continued)
Comoounds
1 , 1 ,2,2-tetrachloroethane
o-xylene
1 , 3 ,5 -trimethylbenzene
1 ,2,4-trimethylbenzene
w-dichlorobenzene
chloromethylbenzene
/>-dichlorobenzene
o-dichlorobenzene
1 ,2,4-trichlorobenzene
hexachloro- 1 .3 -butadiene
CAS No.
79-34-5
95-47-6
108-67-8
95-63-6
541-73-1
100-44-7
106-46-7
95-50-1
120-82-1
87-68-3
1/16/01
ue/m3
0
0.21
0.33
0.81
0
0
0
0
0
0
1/16/01
ue/m3
0
0.25
0.30
0.63
0
0
0.12
0
0.44
0.34
1/16/01
ue/m3
0
-0.04
0.03
0.18
0
0
-0.12
0
-0.44
-0.34
1/16/01
ue/m3
0
0.86
0.31
0.88
0
0
0.10
0
0.28
0
1/17/01
Lie/m3
0
0.14
0.27
0.57
0
0
0
0
0
0
1/17/01
ue/m3
0
0.10
0.14
0.24
0
0
0
0
0
0
1/17/01
ue/m3
0
0.04
0.13
0.33
0
0
0
0
0
0
1/18/01
u,g/m3
0
0.17
0.15
0.29
0
0
0
0
0
0
1/18/01
ue/m3
0
0.17
0
0.18
0
0
0
0
0
0
H-5
-------
Table H-3. Greensboro A&T Air Toxics
Air Toxics for Each Day (Residence Chamber - Dilution Air) Compared to Ambient
Comoounds
acetylene
propylene
dichlorodifluoromethane
chloromethane
dichlorotetrafluoroethane
vinyl chloride
1,3 -butadiene
bromomethane
chloroethane
acetonitrile
acetone
trichlorofluoromethane
acrylonitrile
1 , 1 -dichloroethene
methylene chloride
trichlorotrifluoroethane
trans- 1 ,2-dichloroethylene
1 , 1 -dichloroethane
methyl fert-butyl ether
methyl ethyl ketone
chloroprene
cis- 1 ,3 -dichloroethylene
bromochloromethane
chloroform
erthyl tert-butyl ether
1 ,2-dichloroethane
1,1,1 -trichloroethane
benzene
carbon tetrachloride
tert-amyl methyl ether
1 ,2-dichloropropane
ethyl acrylate
bromodichloromethane
trichloroethylene
methyl methacrylate
cis- 1 ,2-dichloropropene
methyl isobutyl ketone
trans- 1 ,2-dichloropropene
1 , 1 ,2-trichloroethane
toluene
CAS No.
74-86-2
115-07-1
75-71-8
74-87-3
1320-37-2
75-01-4
106-99-0
74-83-9
75-00-3
75-05-8
67-64-1
75-69-4
107-13-1
75-35-4
75-09-2
26523-64-8
56-60-5
75-34-3
1634-04-1
78-93-3
126-99-8
156-59-2
74-97-5
67-66-3
637-92-3
107-06-2
71-55-6
71-43-2
56-23-5
994-05-8
78-87-5
140-88-5
75-27-4
79-01-6
80-62-6
10061-01-5
108-10-1
10061-02-6
79-00-5
108-88-3
Ambient
1/16/01
ue/m3
1.52
2.20
2.45
0.98
0.13
0
0.16
0
0
0
0
1.56
0
0
0.42
0.65
0
0
0.15
12.31
0
0
0
0
0
0
0
1.29
0.53
0
0
0
0
0
0
0
0
0
0
2.11
Air Toxics
RC-DA
1/16/01
ue/m3
-0.05
0.08
-0.31
-0.09
0
0
0
0
0
0
0
0.05
0
0
0.11
-0.21
0
0
-0.22
-7.46
0
0
0
0
-0.30
0
0
0.19
0
-0.48
0
0
0
0
0
0
-1.46
0
0
0.08
Air Toxics
RC-DA
1/17/01
ue/m3
1.27
0.07
-0.22
-0.05
0
0
0
0
0
0
0
-0.13
0
0
1.00
0
0
0
-0.11
-4.55
0
0
0
0
0
0
0
0.33
0
0
0
0
0
0
0
0
0
0
0
0.05
Air Toxics
RC-DA
1/18/01
ue/m3
-0.01
0
-0.09
0.12
0
0
0
0
0
0
0
0
0
0
0.16
0
0
0
0
-3.92
0
0
0
0
0
0
0
0.05
0
0
0
0
0
0
0
0
0
0
0
0.05
H-f
-------
Table H-3. (Continued)
Comoounds
dibromochloromethane
1 ,2-dibromoethane
«-octane
tetrachloroethylene
chlorobenzene
ethylbenzene
m-, />-xylene
bromoform
styrene
1 , 1 ,2,2-tetrachloroethane
o-xylene
1 , 3 ,5 -trimethylbenzene
1 ,2,4-trimethylbenzene
w-dichlorobenzene
chloromethylbenzene
/>-dichlorobenzene
o-dichlorobenzene
1 ,2,4-trichlorobenzene
hexachloro- 1 .3 -butadiene
CAS No.
124-48-1
106-93-4
111-65-9
127-18-4
108-90-7
100-41-4
108-38-3/106-42-3
75-25-2
100-42-5
79-34-5
95-47-6
108-67-8
95-63-6
541-73-1
100-44-7
106-46-7
95-50-1
120-82-1
87-68-3
1/16/01
ue/m3
0
0
0.22
0
0
0.60
3.37
0
0.11
0
0.86
0.31
0.88
0
0
0.10
0
0.28
0
1/16/01
ue/m3
0
0
0.18
0
0
0.02
-0.12
0
-0.27
0
-0.04
0.03
0.18
0
0
-0.12
0
-0.44
-0.34
1/17/01
ue/m3
0
0
-0.15
0
0
0.02
-0.04
0
0
0
0.04
0.13
0.33
0
0
0
0
0
0
1/18/01
ue/m3
0
0
0
0
0
-0.07
-0.22
0
0
0
0
0.15
0.11
0
0
0
0
0
0
H-7
-------
Appendix I
Supporting Data for Carbonyl Analysis
-------
Table 1-1. Greensboro A&T Carbonyl Compounds
Laboratory (Method) and Field Blanks
Compound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenzaldehyde
diacetyl
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
Total fsoeciated + unsoeciated")
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
Method
Blank
Uff
0.0695
0.0800
0.0735
0
0
0.0075
0.0085
0
0
0
0
0
0.0235
0
0
0
0.0230
0.1000
0
0.0310
0.0050
0.0610
0.4825
0.4960
0.9785
Field
Blank
llff
0.0135
0.0760
0.0865
0
0
0.0140
0.0025
0
0
0
0
0
0.0215
0
0
0
0.0230
0.1050
0
0.0320
0.0050
0.0360
0.4150
0.3380
0.7530
1-1
-------
Table I-2A. Greensboro A&T Carbonyl Compounds
Individual Tube Results
Field Samples (1/16/01)
"No Negs" means that negative values generated from RC-DA have been replaced by "0.0000".
Site ID
Field ID
Characterization
A&T A&T Dilution A&T A&T Residence Carbonyls
Air Chamber
HD2A1H1 HD2A2H2 Paired HR3A1H1T1 HR3A2H2T1 Paired RC-DA
Tl Tl Tubes Tubes
DA, DA, 1/16/01 RC, FRONT RC, REAR 1/16/01 1/16/01 No Negs
FRONT BACK
Sampling Date
Analysis Date
Data File
Comoound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenzaldehyde
diacetyl
methacrolein
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-85-3
1/16/01
1/31/01
F1A%008
US.
0.0580
0.0835
0.1240
0
0
0.0250
0.0175
0
0.0015
0.0120
0.0015
0
0.0270
0
0
0
1/16/01
1/31/01
F1A%009
US.
0.0165
0.1145
0.1020
0
0
0.0220
0.0025
0
0
0
0
0
0.0290
0
0
0
us.
0.0745
0.1980
0.2260
0.0000
0.0000
0.0470
0.0200
0.0000
0.0015
0.0120
0.0015
0.0000
0.0560
0.0000
0.0000
0.0000
1/16/01
1/31/01
F1A%010
UQ
0.4955
0.2720
0.2535
0
0
0.0430
0.0450
0
0
0
0
0
0.0370
0
0
0
1/16/01
1/31/01
F1A%006
IIQ
0.1195
0.0855
0.1050
0.0000
0.0000
0.0130
0.0000
0.0090
0.0000
0.0000
0.0000
0.0000
0.0190
0.0000
0.0000
0.0000
IIQ
0.6150
0.3575
0.3585
0.0000
0.0000
0.0560
0.0450
0.0090
0.0000
0.0000
0.0000
0.0000
0.0560
0.0000
0.0000
0.0000
IIQ
0.5405
0.1595
0.1325
0.0000
0.0000
0.0090
0.0250
0.0090
-0.0015
-0.0120
-0.0015
0.0000
0.0000
0.0000
0.0000
0.0000
Carbonyls
RC-DA
1/16/01
UQ
0.5405
0.1595
0.1325
0.0000
0.0000
0.0090
0.0250
0.0090
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1-2
-------
Table I-2A. (Continued)
Compound CAS No. us, US, US, US US US US US-
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
Total fsoeciated +
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
unsoeciated)
0.0360
0.1040
0
0.0280
0.0160
0.1820
0.7160
0.4165
1.1325
0.0280
0.0950
0
0.0420
0.0090
0.0610
0.5215
0.4565
0.9780
0.0640
0.1990
0.0000
0.0700
0.0250
0.2430
1.2375
0.8730
2.1105
0.
0.
0.
0.
0.
0.
1.
1.
2.
0440
2730
0060
0590
0140
1580
.7000
0690
7690
0.
0.
0.
0
0.
0.
0
0
0.
.0280
.0000
.0000
.0290
.0000
.0520
.4600
.4685
.9285
0.0720
0.2730
0.0060
0.0880
0.0140
0.2100
2.1600
1.5375
3.6975
0.0080
0.0740
0.0060
0.0180
-0.0110
-0.0330
0.9225
0.6645
1.5870
0.0080
0.0740
0.0060
0.0180
0.0000
0.0000
0.9815
0.6645
1.6460
-------
Table I-2B. Greensboro A&T Carbonyl Compounds
Individual Tube Results
Field Samples (1/17/01)
"No Negs" means that negative values generated from RC-DA have been replaced by "0.0000".
Site ID
Field ID
Characterization
Sampling Date
Analysis Date
Data File
A&T A&T Dilution A&T A&T Residence Carbonyls No
Air Chamber Negs
HD2A1H1T2 HD2A2H2T2 Paired HR3A1H1T2 HR3A2H2T2 Paired Tubes RC-DA Carbonyls
Tubes RC-DA
DA, FRONT DA, BACK 1/17/01 RC, FRONT RC, REAR 1/17/01 1/17/01 1/17/01
1/17/01 1/17/01 1/17/01 1/17/01
1/31/01 1/31/01 1/31/01 1/31/01
F1A%014 F1A%012 F1A%013 F1A%011
Compound
CAS No.
ug/m
ug/m
ug/m3
ug/m3
ug/m3
ug/m3
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenzaldehyde
diacetyl
methacrolein
2-butanone
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779.94.2
431-03-8
78-85-3
78-93-3
0.0350
0.0900
0.1470
0.0005
0
0.0280
0.014
0
0
0.0000
0
0
0.0240
0
0
0
0.0310
0.0540
0.0890
0.0910
0
0
0.0205
0.0010
0
0
0
0
0
0.0210
0
0
0
0.0250
0.0890
0.1790
0.2380
0.0005
0.0000
0.0485
0.0150
0.0000
0.0000
0.0000
0.0000
0.0000
0.0450
0.0000
0.0000
0.0000
0.0560
0.2480
0.1780
0.3160
0.0000
0.0000
0.0395
0.0210
0.0000
0.0045
0.0000
0.0000
0.0000
0.0345
0.0000
0.0000
0.0000
0.0370
0.0390
0.0605
0.0925
0.0000
0.0000
0.0250
0.0120
0.0000
0.0000
0.0000
0.0000
0.0000
0.0240
0.0000
0.0000
0.0000
0.0270
0.2870
0.2385
0.4085
0.0000
0.0000
0.0645
0.0330
0.0000
0.0045
0.0000
0.0000
0.0000
0.0585
0.0000
0.0000
0.0000
0.0640
0.1980
0.0595
0.1705
-0.0005
0.0000
0.0160
0.0180
0.0000
0.0045
0.0000
0.0000
0.0000
0.0135
0.0000
0.0000
0.0000
0.0080
0.1980
0.0595
0.1705
0.0000
0.0000
0.0160
0.0180
0.0000
0.0045
0.0000
0.0000
0.0000
0.0135
0.0000
0.0000
0.0000
0.0080
1-4
-------
Table I-2B. (Continued)
Compound CAS No. u,g/m3 ug/m3 u,g/m3 ug/m3 ug/m3 ug/m3 iig/m3 iig/m3
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
Total (speciated +
unsoeciated)
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
0.0960
0
0.0300
0.0070
0.0930
0.5955
0.4355
1.0310
0.0760
0
0.0290
0.0000
0.0500
0.4565
0.2950
0.7515
0.1720
0.0000
0.0590
0.0070
0.1430
1.0520
0.7305
1.7825
0.1470
0.0000
0.0540
0.0120
0.1010
1.1925
0.7260
1.9185
0.0900
0.0000
0.0300
0.0100
0.0540
0.4640
0.3255
0.7895
0.2370
0.0000
0.0840
0.0220
0.1550
1.6565
1.0515
2.7080
0.0650
0.0000
0.0250
0.0150
0.0120
0.6045
0.3210
0.9255
0.0650
0.0000
0.0250
0.0150
0.0120
0.6050
0.3210
0.9260
1-5
-------
Table I-2C. Greensboro A&T Carbonyl Compounds
Individual Tube Results
Field Samples
(1/18/01)
"No Negs" means that negative values generated from RC-DA have been replaced by "0.0000".
Site ID
Field ID
Characterization
Sampling Date
Analysis Date
Data File
Comoound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5 -dimethylbenzaldehyde
diacetyl
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
A&T
HD2A1H2T3
DA, FRONT
1/18/01
2/1/01
F1A%020
ue/m3
0.1025
0.1530
0.0895
0
0
0.0375
0.0105
0
0
0.0000
0
0
0.0330
0
0
A&T
HD2A2H2T3
DA, BACK
1/18/01
2/1/01
F1A%017
ue/m3
0.0115
0.0860
0.1015
0.0005
0
0.0215
0.0095
0
0
0
0
0
0.0215
0
0
Dilution
Air
Paired
Tubes
1/18/01
ue/m3
0.1140
0.2390
0.1910
0.0005
0.0000
0.0590
0.0200
0.0000
0.0000
0.0000
0.0000
0.0000
0.0545
0.0000
0.0000
A&T
HR3A1H1T3
RC, FRONT
1/18/01
2/1/01
F1A%018
ue/m3
0.1970
0.2110
0.1230
0.0000
0.0000
0.0460
0.0100
0.0000
0.0000
0.0000
0.0000
0.0000
0.0270
0.0000
0.0000
A&T
HR3A2H2T3
RC, REAR
1/18/01
2/1/01
F1A%019
ue/m3
0.0185
0.0775
0.1000
0.0000
0.0000
0.0405
0.0030
0.0000
0.0000
0.0000
0.0000
0.0000
0.0245
0.0000
0.0000
Residence
Chamber
Paired
Tubes
1/18/01
ue/m3
0.2155
0.2885
0.2230
0.0000
0.0000
0.0865
0.0130
0.0000
0.0000
0.0000
0.0000
0.0000
0.0515
0.0000
0.0000
Carbonyls
RC-DA
1/18/01
ue/m3
0.1015
0.0495
0.0320
-0.0005
0.0000
0.0275
-0.0070
0.0000
0.0000
0.0000
0.0000
0.0000
-0.0030
0.0000
0.0000
No
Negs
Carbonyls
RC-DA
1/18/01
ue/m3
0.1015
0.0495
0.0320
0.0000
0.0000
0.0275
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1-6
-------
Table I-2C. (Continued)
Compound
CAS No.
ug/m3
ug/m3
ug/m3
ug/m3
ug/m3
ug/m3
ug/m3
ug/m3
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
Total (speciated +
unsoeciated")
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
0
0.0330
0.1030
0
0.0360
0.0090
0.0780
0.6850
0.7620
1.4470
0.0010
0.0260
0.1070
0
0.0290
0.0000
0.0540
0.4690
0.2780
0.7470
0.0010
0.0590
0.2100
0.0000
0.0650
0.0090
0.1320
1.1540
1.0400
2.1940
0.0000
0.0290
0.1540
0.0000
0.0360
0.0060
0.0690
0.9080
1.0645
1.9725
0.0000
0.0340
0.1350
0.0000
0.0340
0.0000
0.0430
0.5100
0.4150
0.9250
0.0000
0.0630
0.2890
0.0000
0.0700
0.0060
0.1120
1.4180
1.4795
2.8975
-0.0010
0.0040
0.0790
0.0000
0.0050
-0.0030
-0.0200
0.2640
0.4395
0.7035
0.0000
0.0040
0.0790
0.0000
0.0050
0.0000
0.0000
0.2985
0.4395
0.7380
1-7
-------
Table I-3A. Greensboro A&T Carbonyls (1/16/01): Uncertainty
Comnound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenzaldehyde
diacetyl
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
Total fsoeciated + unsoeciated)
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
RC-DA
1/16/01
U2 Uncertainty ± % Total Uncertainty ±
0.5405
0.1595
0.1325
0.0000
0.0000
0.0090
0.0250
0.0090
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0080
0.0740
0.0060
0.0180
0.0000
0.0000
0.9815
0.6645
1.6460
0.0596
0.0018
0.0056
0.0000
0.0000
0.0005
0.0008
0.0012
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0007
0.0020
0.0003
0.0022
0.0000
0.0000
32.8372
9.6902
8.0498
0.0000
0.0000
0.5468
1.5188
0.5468
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.4860
4.4957
0.3645
1.0936
0.0000
0.0000
3.6187
0.1105
0.3405
0.0000
0.0000
0.0319
0.0465
0.0727
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0395
0.1227
0.0174
0.1343
0.0000
0.0000
-------
Table I-3B. Greensboro A&T Carbonyls (1/17/01): Uncertainty
Compound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
«7-tolualdehyde
/>-tolualdehyde
hexaldehyde
2, 5 -dimethylbenzaldehy de
diacetyl
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
Total fsoeciated + unsoeciated)
RC-DA
1/17/01
UŁ
0.1980
0.0595
0.1705
0.0000
0.0000
0.0160
0.0180
0.0000
0.0045
0.0000
0.0000
0.0000
0.0135
0.0000
0.0000
0.0000
0.0080
0.0650
0.0000
0.0250
0.0150
0.0120
0.6050
0.3210
0.9260
Uncertainty ±
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
% Total
21.3823
6.4255
18.4125
0.0000
0.0000
1.7279
1.9438
0.0000
0.4860
0.0000
0.0000
0.0000
1.4579
0.0000
0.0000
0.0000
0.8639
7.0194
0.0000
2.6998
1.6199
1.2959
Uncertainty ±
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1-9
-------
Table I-3C. Greensboro A&T Carbonyls (1/17/01): Uncertainty
Comnound
formaldehyde
acetaldehyde
acetone
propionaldehyde
crotonaldehyde
butyraldehyde
benzaldehyde
isovaleraldehyde
valeraldehyde
o-tolualdehyde
/w-tolualdehyde
/>-tolualdehyde
hexaldehyde
2,5-dimethylbenzaldehyde
diacetyl
methacrolein
2-butanone
glyoxal
acetophenone
methylglyoxal
octanal
nonanal
Sum, speciated
Sum, unspeciated
CAS No.
50-00-0
75-07-0
67-64-1
123-38-6
4170-30-0
123-72-8
100-52-7
590-86-3
110-62-3
529-20-4
620-23-5
104-87-0
66-25-1
5779-94-2
431-03-8
78-85-3
78-93-3
107-22-2
98-86-2
78-98-8
124-13-0
124-19-6
Total fsoeciated + unsoeciated")
RC-DA
1/18/01
us Uncertainty ± % Total Uncertainty ±
0.1015
0.0495
0.0320
0.0000
0.0000
0.0275
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0040
0.0790
0.0000
0.0050
0.0000
0.0000
0.2985
0.4395
0.7380
0.0112
0.0006
0.0014
0.0000
0.0000
0.0016
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0003
0.0022
0.0000
0.0006
0.0000
0.0000
13.7534
6.7073
4.3360
0.0000
0.0000
3.7263
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.5420
10.7046
0.0000
0.6775
0.0000
0.0000
1.5156
0.0765
0.1834
0.0000
0.0000
0.2176
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0441
0.2922
0.0000
0.0832
0.0000
0.0000
Analytical
Uncertainty %
11.02
1.14
4.23
0.66
2.48
5.84
3.06
13.30
9.58
0
1.3
5.61
9.3
0
0
5.84
8.13
2.73
4.76
12.28
0
8.06
1-10
-------
Appendix J
Individual PM-2.5 Mass Measurements
Both Campaigns
-------
Table J-l. Oil-Fired Industrial Boiler, Campaign #1, January 2001
PM-2.5 Mass Samples - Gravimetric
Test ID: IB11601H
T041700H-IB011601HR2A1
T041700I-IB011601HR2B1
T041700J-IB011601HR4A1
T062700F-IB011601HR4B1
T041700G-IB011601HD1B1
T070700D-IB011601HFB
Test ID: IB011701H
T070700C-IB01 1701HR2A1
T070700E-IBO 1 1 70 1HR2B 1
T062900D-IB011701HR4A1
T062900F-IB011701HR4B1
T070700F-IB010701HD1B1
Test ID: IB011801H
T062900C-IBO 1180 1HR2A 1
T062900E-IBO 1180 1HR2B 1
T062900A-IB011801HR4A1
T062900B-IBO 1180 1HR4B 1
T070500A-IB011801HD1B1
Test ID: BT011401H
T063000A-BT01 1401HR8A1
Initial wt.fe)
0.17062
0.17135
0.16779
0.170875
0.16645
0.167936
0.163246
0.167177
0.166534
0.167457
0.162163
0.167193
0.168819
0.166356
0.158869
0.167729
0.16798
Final wt.fe)
0.170859
0.171615
0.168056
0.171201
0.166442
0.16793
0.163549
0.167481
0.166832
0.167794
0.162156
0.167591
0.169221
0.166743
0.159277
0.167725
0.167991
Net wt.fe) Net wt. (me)
0.000239
0.000265
0.000266
0.000326
-8E-06
-7E-06
0.000303
0.000304
0.000298
0.000337
-7E-06
0.000398
0.000402
0.000387
0.000408
-4E-06
0.000011
0.239
0.265
0.266
0.326
-0.008
-0.007
0.303
0.304
0.298
0.337
-0.007
0.398
0.402
0.387
0.408
-0.004
0.011
J-2
-------
Table J-2. ELPI Data, Campaign #2
Filter ID
A062102A
A062102B
A062102C
A062102D
A062102E
A062102F
A062102G
A062102H
A062102I
A062102J
A062102K
A062102L
A062102M
A062102N
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
IB070902H
ELPI 13
ELPI 12
ELPI 1 1
ELPI 10
ELPI 9
ELPI 8
ELPI 7
ELPI 6
ELPI 5
ELPI 4
ELPI 3
ELPI 2
ELPI1
ELPI FB
Tare
Mass
me
49.403
49.332
49.223
49.176
49.307
49.350
49.665
49.558
49.374
49.410
49.552
49.285
49.258
49.496
Final
Mass
me
49.397
49.344
49.235
49.191
49.330
49.354
49.671
49.570
49.383
49.431
49.577
49.324
49.295
49.498
PM
Mass
me
-0.006
0.012
0.012
0.015
0.023
0.004
0.006
0.012
0.009
0.021
0.025
0.039
0.037
0.002
Tare Mass
me
torn 49.403
49.332
49.223
49.176
49.307
49.350
49.665
49.558
49.374
49.410
49.552
49.285
49.258
49.496
Final
Mass
me
49.396
49.340
49.231
49.187
49.327
49.353
49.670
49.568
49.382
49.429
49.572
49.324
49.293
49499
PM
Mass
me
-0.007
0.008
0.008
0.011
0.020
0.003
0.005
0.010
0.008
0.019
0.020
0.039
0.035
0.003
Jul- 9-
02
13
12
11
10
9
8
7
6
5
4
3
2
1
FB
Series 1
-0.006
0.012
0.012
0.015
0.023
0.004
0.006
0.012
0.009
0.021
0.025
0.039
0.037
0.002
Series 2
-0.007
0.008
0.008
0.011
0.02
0.003
0.005
0.01
0.008
0.019
0.02
0.039
0.035
0.003
J-J
-------
o n^ -,
o D4
o o^
u.uo
w
tn
re
En o?
S
Q.
n m
U.U I
n
u
-0.01
-^^V
ill
|l| 12 11 10
i i i I
9876
ELPI stag«
1
i
5
B
4
1
3
1
2
1
1
rl
i
FB
nSeriesI
• Senes2
Figure J-l. July 9, 2002 - ELPI Data
J-4
-------
Table J-3. ELPI Data - July 10, 2002
Tare Mass
Filter ID
A062102P
A062102Q
A062102R
A062102S
A062102T
A062102U
A062102V
A062102W
A062102X
A062102Y
A062102Z
A062402A
Jul-10-02
13
12
11
10
9
8
7
6
5
4
3
2
1
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
IB071002H
Series 1
0.006
0.009
0.006
0.002
0.01
0.006
0.008
0.007
0.005
0.009
0.012
0.026
0.018
ELPI 12
ELPI 1 1
ELPI 10
ELPI 9
ELPI 8
ELPI 7
ELPI 6
ELPI 5
ELPI 4
ELPI 3
ELPI 2
ELPI 1
Series 2
0.005
0.01
0.007
0.004
0.01
0.002
0.002
0.005
0.003
0.004
0.008
0.023
0.036
49
49
49
49
49
49
49
49
49
49
49
49
me
.460
.179
.359
.727
.604
.333
.517
.078
.068
.315
.472
.415
Final
Mass
me
49.
49.
49.
49.
49.
49.
49.
49.
49.
49.
49.
469
185
361
737
610
341
524
083
077
327
498
49.433
PM
Mass
me
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
009
006
002
010
006
008
007
005
009
012
026
018
49.460
49.179
49.359
49.727
49.604
49.333
49.517
49.078
49.068
49.315
49.472
49.415
Tare Mass
me
49.470
49.186
49.363
49.737
49.606
49.335
49.522
49.081
49.072
49.323
49.495
49.451
Final Mass
me
0.010
0.007
0.004
0.010
0.002
0.002
0.005
0.003
0.004
0.008
0.023
0.036
J-5
-------
0 040 -,
0 035
— . 0 030
O)
E o 095
w 0 020
re
E o 015
o_ n mn
"• \j.\j \ \j
0.005
0 000
July 10, 2002
rr
13
In
Illrl
i
12 11 10
hri
n n
Ll
i i i i
9876
ELPI stage
1
5
t
4
i
3 2 1
D series 1
• series 2
Figure J-2. ELPI Data - July 10, 2002
J-6
-------
Table J-4. ELPI Data - July 11, 2002
Tare Mass
Filter ID
A062402C
A062402D
A062402E
A062402F
A062402G
A062402H
A062402I
A062402J
A062402K
A062402L
A062402M
A062402N
A062402O
Jul-11-02
13
12
11
10
9
8
7
6
5
4
3
2
1
me
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
IB071102H
Series 1
0.003
0.003
-0.059
0.003
0.008
0.006
0.005
0.008
0.026
0.033
0.071
0.184
0.101
ELPI 12
ELPI 1 1
ELPI 10
ELPI 9
ELPI 8
ELPI 7
ELPI 6
ELPI 5
ELPI 3
ELPI 2
ELPI1
ELPI 4
Series 2
0.003
0.004
-0.06
0.001
0.007
0.005
0.004
0.007
0.025
0.03
0.068
0.181
0.101
49
49
49
.155
.342
.416
49.631
49
49
49
49
49
49
49
49
49
.454
.493
.197
.672
.421
.114
.504
.769
.468
Final Mass
me
49
49
49
.158
.283
.419
49.639
49
49
49
49
49
49
49
49
.460
.498
.205
.698
.185
.688
.870
.501
PM Mass
me
0.003
-0.059
0.003
0.008
0.006
0.005
0.008
0.026
0.071
0.184
0.101
0.033
Tare Mass
me
49
don't know what happened here - 49.342
double checked my numbers
49
49
.155
.416
.631
49.454
49.493
49
49
not used 49.421
49
49
49
49
.197
.672
.114
.504
.769
.468
Final Mass
me
49.159
49.282
49.417
49.638
49.459
49.497
49.204
49.697
49.182
49.685
49.870
49.498
0.003
0.004
-0.060
0.001
0.007
0.005
0.004
0.007
0.025
0.068
0.181
0.101
0.030
J-7
-------
-- 0.100
tfl
-------
Table J-5. Oil-Fired Industrial Boiler, Campaign #2,
July 2002
PM-2.5 Mass Samples - Gravimetric
Teflon filter ID
IB070902HD1B1
IB070902HR2A1
IB070902HR2B1
IB070902HR4A1
IB070902HR4B1
IB070902HR5A3
IB070902HR5B3
IB070902 - FB
IB071002HD1B1
IB071002HR4A1
IB071002HR4B1
IB071002HR2A1
IB071002HR2B1
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3
IB071102HRD1B1
IB071102HR4A1
IB071102HR4B1
IB071102HR2A1
IB071102HR2B1
PM mass
0.003
0.292
0.284
0.278
0.266
0.120
0.156
0.006
0.002
0.267
0.270
0.300
0.302
0.135
0.138
0.361
0.357
0.005
1.082
1.064
1.176
1.150
J-9
-------
Appendix K
Example Calculations: PM-2.5 Emission Factors
Both Campaigns
-------
Table K-l. Oil-Fired Industrial Boiler, Campaign #1, January 16, 2001
PM-2.5 Mass Emission Factors
Test
01/16/2001 (individual filters)
Notes
1 Sampling time (min)
2 TF sample
3 PM mass on filter (mg)
4 Array flow (SLPM)
5 PM cone @ filter (mg/L)
6b PM mass on dilution chamber filter (mg)
6c Array flow (SLPM)
6d PM cone @ dilution air (mg/L)
6e Net PM mass cone after dilution (mg/L)
7 Probe flow (SLPM)
8 Probe flow (m3)
9 Dilution air (SLPM)
10 Dilution air (m3)
11 Dilution ratio
12 PM cone @ stack (mg/L)
13 Stack flow (SCFM)
14 Stack flow (SLPM)
15 PM emission rate from stack (mg/min)
16 Fuel type
17 Fuel volumetric feed (gal/min)
18 Fuel density (Ib/gal)
79 Fuel density (kg/gal)
20 Fuel mass feed rate (kg/min)
27 Fuel mass feed rate (Ib/min)
22 Fuel heating value (Btu/lb)
600.3
T041700H T0417001 T041700J T062700F
0.243 0.267 0.267 0.326
8.479 8.479 8.479 8.479
0.000048 0.000052 0.000052 0.000064
0.000
8.442
0.000000
0.000048 0.000052 0.000052 0.000064
18.54
11.13
847.89
508.99
46.75
0.0022 0.0025 0.0025 0.0030
4065
115120.8
259.0 284.6 284.6 347.5
#2 Oil
3.43
7.034
3.19
10.94
24.1
19374
(6b) I (6c)
(6a) - (6d)
(7)x(7)/1000
(9)x(7)/1000
(6e) x (77)
(13) x (16) x 528/(460+(74)) x ((15)129.92)
(77) x 28.32
(72) x (14)
(20) x 2.205
K-l
-------
Table K-l. (Continued)
23
24
25
26
27
Test
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
Emission factor (|ig/kJ)
Ave. Emission factor (mg/kg)
Ave. Emission factor (ug/kJ)
01/16/2001 (individual filters) Notes
467517.0
23.67 26.01 26.01
0.53 0.58 0.58
26.86
0.60
(21}
31.75 (75) x 1000
0.70 (19} x 1000x0.948
x(22)
x 0.948 / (23)
1(30)
K-2
-------
Table K-2. Oil-Fired Industrial Boiler, Campaign #1, January 17, 2001
PM-2.5 Mass Emission Factors
Test
01/17/2001 (individual filters)
Notes
1 Sampling time (min)
2 TF sample
3 PM mass on filter (mg)
4 Array flow (SLPM)
5 PM cone @ filter (mg/L)
6b PM mass on dilution chamber filter (mg)
6c Array flow (SLPM)
6d PM cone @ dilution air (mg/L)
6e Net PM mass cone after dilution (mg/L)
7 Probe flow (SLPM)
8 Probe flow (m3)
9 Dilution air (SLPM)
10 Dilution air (m3)
11 Dilution ratio
12 PM cone @ stack (mg/L)
13 Stack flow (SCFM)
14 Stack flow (SLPM)
15 PM emission rate from stack (mg/min)
16 Fuel type
17 Fuel volumetric feed (gal/min)
18 Fuel density (Ib/gal)
19 Fuel density (kg/gal)
20 Fuel mass feed rate (kg/min)
21 Fuel mass feed rate (Ib/min)
600.5
T070700C T070700E T062900D T062900E
0.303 0.304 0.298 0.337
8.580 8.580 8.542 8.542
0.000059 0.000059 0.000058 0.000066
0.000
8.656
0.000000
0.000059 0.00059 0.000058 0.000066
17.88
10.74
848.35
509.43
48.45
0.0028 0.0029 0.0028 0.0032
4159
117782.9
360.8 362.0 356.4 403.1
#2 Oil
3.62
7.034
3.19
11.5
25.5
(6b) I (6c)
(6a) - (6d)
(7)x(7)/1000
(9) x (7) II 000
(13} x 28. 32
(12)* (14)
(20) x 2.205
K-3
-------
Table K-2. (Continued)
Test
01/17/2001 (individual filters)
Notes
22 Fuel heating value (Btu/lb)
23 Fuel heat feed rate (Btu/min)
24 Emission factor (mg/kg)
25 Emission factor (|ig/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (iig/kJ)
19374
493318.2
31.24
0.69
32.09
0.71
(27) x (22)
31.35 30.86 34.90 (15) / (20)
0.70 0.68 0.77 (75) x 1000 x 0.948 / (23)
K-4
-------
Table K-3. Oil-Fired Industrial Boiler, Campaign #1,
January 18, 2001
PM-2.5 Mass Emission Factors
Test
01/18/2001 (individual filters)
Notes
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (SLPM)
PM cone @ filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (SLPM)
PM cone @ dilution air (mg/L)
Net PM mass cone after dilution (mg/L)
Probe flow (SLPM)
Probe flow (m3)
Dilution air (SLPM)
Dilution air (m3)
Dilution ratio
PM cone @ stack (mg/L)
Stack flow (SCFM)
Stack flow (SLPM)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (Ib/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (Ib/min)
Fuel heating value (Btu/lb)
600.1
T062900C T062900E T062900A
0.398 0.402 0.387 0.408
8.489 8.489 8.489 8.489
0.000078 0.000079 0.000076 0.000080
0.000
8.564
0.000000
0.000078 0.000079 0.000076 0.000080
19.01
11.41
850.66
510.48
45.75
0.0036 0.0036 0.0035 0.0037
4827
136700
524.3 529.6 509.8 537.5
#2 Oil
4.14
7.034
3.19
13.2
29.1
19374
T062900B
(6b) 1 (6c)
(6d) - (6d)
(7)x(7)/1000
(9)x(7)/1000
((8) + (10)) 1(8)
(6e)*(ll)
(13) x (16) x 528/(460+(74)) x ((15)129.92)
(1 7) x 28.32
(12)* (14)
(17)x(19)
(20) x 2.205
K-5
-------
Table K-3. (Continued)
Test
01/18/2001 (individual filters)
Notes
23
24
25
26
27
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
Emission factor (|ig/kJ)
Ave. Emission factor (mg/kg)
Ave. Emission factor (ug/kJ)
564181.6
39
0.
39
0.
.70
88
.77
88
40.10
0.89
38
0.
.60
86
40
0.
.70
90
(27) x
(15) /
(7 5) x 1000 x
(22)
(20)
0.948
/(23)
K-6
-------
Table K-4. Oil-Fired Industrial Boiler - Campaign #2 (July 9, 2002) -Undenuded PM-2.5 Mass Emission Factors
Test
07/09/2002 (individual filters)
Notes
1 Sampling time (min)
2 TF sample
3 PM mass on filter (mg)
4 Array flow (SLPM)
5 PM cone @ filter (mg/L)
6b PM mass on dilution chamber filter (mg)
6c Array flow (SLPM)
6d PM cone @ dilution air (mg/L)
6e Net PM mass cone after dilution (mg/L)
7 Probe flow (SLPM)
8 Probe flow (m3)
9 Dilution air (SLPM)
10 Dilution air (m3)
11 Dilution ratio
12 PM cone @ stack (mg/L)
13 Stack flow (SCFM)
14 Stack flow (SLPM)
15 PM emission rate from stack (mg/min)
16 Fuel type
17 Fuel volumetric feed (gal/min)
18 Fuel density (Ib/gal)
19 Fuel density (kg/gal)
20 Fuel mass feed rate (kg/min)
21 Fuel mass feed rate (Ib/min)
22 Fuel heating value (Btu/lb)
600.6
1007993 1007994 1007995 1008951
0.292 0.284 0.278 0.266
8.251 8.251 8.106 8.106
0.000059 0.000057 0.000057 0.000055
0.003
8.215
0.0000006
0.000058 0.000057 0.000056 0.000054
18.85
11.32
816.28
490.26
44.30
0.0026 0.0025 0.0025 0.0024
3935
11439
308.9 300.4 299.3 286.2
#2 Oil
2.32
7.034
3.19
7.4
16.3
19193
(6b) I (6c)
(6a) - (6d)
(7)x(7)/1000
(9)x(7)/1000
(13) x (16) x 528/(460+(7Ą)) x ((75)/29.92)
(7 7) x 28.32
(72)x(70
(20) x 2.205
K-7
-------
Table K-4. (Continued)
Test
07/09/2002 (individual filters)
Notes
23
24
25
26
27
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
Emission factor (ug/kJ)
Ave. Emission factor (mg/kg)
Ave. Emission factor (ug/kJ)
313267.1
41
0.
40
0.
.73
93
.35
90
40.58
0.91
40
0.
.43
91
38
0.
.67
87
(27) x
(15) /
(7J)xlOOOx
(22)
(20)
0.948
/(23)
K-8
-------
Table K-5. Oil-Fired Industrial Boiler - Campaign #2 (July 10, 2002) - Undenuded - PM-2.5 Mass Emission Factors
Test
07/10/2002 (individual filters)
Notes
1 Sampling time (min)
2 TF sample
3 PM mass on filter (mg)
4 Array flow (SLPM)
5 PM cone @ filter (mg/L)
6b PM mass on dilution chamber filter (mg)
6c Array flow (SLPM)
6d PM cone @ dilution air (mg/L)
6e Net PM mass cone after dilution (mg/L)
7 Probe flow (SLPM)
8 Probe flow (m3)
9 Dilution air (SLPM)
10 Dilution air (m3)
11 Dilution ratio
12 PM cone @ stack (mg/L)
13 Stack flow (SCFM)
14 Stack flow (SLPM)
15 PM emission rate from stack (mg/min)
16 Fuel type
17 Fuel volumetric feed (gal/min)
18 Fuel density (Ib/gal)
79 Fuel density (kg/gal)
20 Fuel mass feed rate (kg/min)
27 Fuel mass feed rate (Ib/min)
22 Fuel heating value (Btu/lb)
23 Fuel heat feed rate (Btu/min)
600.67
1008958 1008959 1008956 1008957
0.3 0.302 0.267 0.27
8.183 8.183 8.075 8.075
0.000061 0.000061 0.000055 0.000056
0.002
8.203
0.0000004
0.000061 0.000061 0.000055 0.000055
18.79
11.29
814.43
489.20
44.34
0.0027 0.0027 0.0024 0.0025
4066
115149
332.1 334.4 299.3 302.7
#2 Oil
2.33
7.034
3.19
7.4
16.4
19193
314556.1
(6b) I (6c)
(6d) - (6d)
(7)x(7)/1000
(9)x(7)/1000
(13) x (16) x 528/(460+(74)) x ((7J)/29.92)
(7 7) x 28.32
(20) x 2.205
(21) x (22)
K-9
-------
Table K-5. (Continued)
Test
07/10/2002 (individual filters)
Notes
24 Emission factor (mg/kg)
25 Emission factor (ug/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (ug/kJ)
44.68
1.00
42.67
0.96
44.98
1.01
40.27
0.90
40.73
0.91
(75) x 1000x0.9487(23)
K-10
-------
Table K-6. Oil-Fired Industrial Boiler - Campaign #2 (July 11, 2002) -Undenuded PM-2.5 Mass Emission Factors
Test
07/11/2002 (individual filters)
Notes
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (SLPM)
PM cone @ filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (SLPM)
PM cone @ dilution air (mg/L)
Net PM mass cone after dilution (mg/L)
Probe flow (SLPM)
Probe flow (m3)
Dilution air (SLPM)
Dilution air (m3)
Dilution ratio
PM cone @ stack (mg/L)
Stack flow (SCFM)
Stack flow (SLPM)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (Ib/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (Ib/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
600
1008967
1.176
8.276
0.000237
0.005
8.203
0.0000010
0.000236
18.78
11.27
824.70
494.82
44.91
0.0106
4270
120926
1374.2
#2 Oil
2.33
7.034
3.19
7.43
16.4
19193
314556.1
184.88
1008968 1008965 1008966
1.15 1.082 1.064
8.276 8.058 8.058
0.000232 0.000224 0.000220
(6b) / (6c)
0.000231 0.000223 0.000219 (6a) - (6d)
(7)x(7)/1000
(9)x(7)/1000
((8) + (10)) 1(8)
0.0104 0.0100 0.0098 (<5e)x(77)
(13) x (16) x 528/(460+(74)) x ((15)129.92)
(1 7) x 28.32
1343.7 1298.2 1276.5 (72)x(74)
(17)x(19)
(20) x 2.205
(27)x(22)
180.78 174.66 171.74 (15)/(20)
K-ll
-------
Table K-6. (Continued)
Test
07/11/2002 (individual filters)
Notes
25 Emission factor (ug/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (ug/kJ)
4.14
178.02
3.99
4.05
3.91
3.85
(75) x 1000x0.9487(23)
K-12
-------
Table K-7. Oil-Fired Industrial Boiler - Campaign #2 (July 9, 2002) - Denuded - PM-2.5 Mass Emission Factors
Test
07/09/2002 (individual filters)
Notes
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (SLPM)
PM cone @ filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (SLPM)
PM cone @ dilution air (mg/L)
Net PM mass cone after dilution (mg/L)
Probe flow (SLPM)
Probe flow (m3)
Dilution air (SLPM)
Dilution air (m3)
Dilution ratio
PM cone @ stack (mg/L)
Stack flow (SCFM)
Stack flow (SLPM)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (Ib/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (Ib/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
600.6
1008952
0.12
4.518
0.000044
0.003
8.215
0.0000006
0.000044
18.85
11.32
816.28
490.26
44.30
0.0019
4065
115121
231.0
#2 Oil
2.32
7.034
3.19
7.4
16.3
19193
313267.1
31.21
1008953
0.156
4.518
0.000057
(6b) / (6c)
0.000057 (6a) - (6d)
(7)x(7)/1000
(9)x(7)/1000
((8) + (10)) 1(8)
0.0025 (<5e)x(77)
(13) x (16) x 528/(460+(7Ą)) x ((75)/29.92)
(7 7) x 28.32
301.3 (12)* (14)
(17)x(19)
(20) x 2.205
(21)* (22)
40.71 (15)1(20)
K-13
-------
Table K-7. (Continued)
Test
07/09/2002 (individual filters)
Notes
25 Emission factor (ug/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (ug/kJ)
0.70
35.96
0.81
0.91
(75) x 1000x0.9487(23)
K-14
-------
Table K-8. Oil-Fired Industrial Boiler - Campaign #2 (July 10, 2002) - Denuded - PM-2.5 Mass Emission Factors
Test
07/10/2002 (individual filters)
Notes
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (SLPM)
PM cone @ filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (SLPM)
PM cone @ dilution air (mg/L)
Net PM mass cone after dilution (mg/L)
Probe flow (SLPM)
Probe flow (m3)
Dilution air (SLPM)
Dilution air (m3)
Dilution ratio
PM cone @ stack (mg/L)
Stack flow (SCFM)
Stack flow (SLPM)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (Ib/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (Ib/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Emission factor (mg/kg)
600.67
1008960
0.135
4.593
0.000049
0.002
8.203
0.0000004
0.000049
18.79
11.29
814.43
489.20
44.34
0.0022
4066
115149
265.8
#2 Oil
2.33
7.034
3.19
7.4
16.4
19193
314556.1
35.77
1008961
0.138
4.593
0.000050
(6b) / (6c)
0.000050 (6a) - (6d)
(7)x(7)/1000
(9)x(7)/1000
((8) + (10))/(8)
0.0022 (<5e)x(77)
(13) x (16) x 528/(460+(74)) x ((15)129.92)
(7 7) x 28.32
271.8 (12)* (14)
(17)x(19)
(20) x 2.205
(27)x(22)
36.57 (15)1(20)
K-15
-------
Table K-8. (Continued)
Test
07/10/2002 (individual filters)
Notes
25 Emission factor (ug/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (ug/kJ)
0.80
36.17
0.81
0.82
(75) x 1000x0.9487(23)
K-16
-------
Table K-9. Oil-Fired Industrial Boiler - Campaign #2 (July 11, 2002) - Denuded- PM-2.5 Mass Emission Factors
Test
07/11/2002 (individual
filters)
Notes
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (SLPM)
PM cone @ filter (mg/L)
PM mass on dilution chamber filter
(mg)
Array flow (SLPM)
PM cone @ dilution air (mg/L)
Net PM mass cone after dilution
(mg/L)
Probe flow (SLPM)
Probe flow (m3)
Dilution air (SLPM)
Dilution air (m3)
Dilution ratio
PM cone @ stack (mg/L)
Stack flow (SCFM)
Stack flow (SLPM)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (Ib/gal)
Fuel density (kg/gal)
600
1008962
0.361
4.573
0.000132
0.005
8.203
0.0000010
0.000131
18.78
11.27
824.70
494.82
44.91
0.0059
4270
120926
760.8
#2 Oil
2.33
7.034
3.19
1008963
0.357
4.573
0.000130
(6b) 1 (6c)
0.000129 (6a) - (6d)
(7)x(7)/1000
(9} x (7) 11 000
((8} + (10)) 1(8)
0.0058 (6e) x (77)
(73) x (16) x 528/(460+(7Ą)) x ((75)/29.92)
(77) x 28. 32
752.3 (12) x (14)
K-17
-------
Table K-9. (Continued)
Test
07/11/2002 (individual filters)
Notes
20 Fuel mass feed rate (kg/min)
21 Fuel mass feed rate (Ib/min)
22 Fuel heating value (Btu/lb)
23 Fuel heat feed rate (Btu/min)
24 Emission factor (mg/kg)
25 Emission factor (ug/kJ)
26 Ave. Emission factor (mg/kg)
27 Ave. Emission factor (ug/kJ)
7.4
16.4
19193
314556.1
102.36
2.29
101.78
2.28
101.21
2.27
(20) x 2.205
(27) x (22)
(IS) I (20)
(15) x 1000x0.9487(23)
K-18
-------
EPA/600/R-07/005
February 2007
Source Sampling Fine Particulate Matter
Institutional Oil-Fired Boiler
Appendix L through Appendix P
-------
Appendix L
Individual PM-2.5 EC/OC Measurements
Both Campaigns
-------
Table L-l. Oil-Fired Institutional Boiler. Organic/Elemental Carbon Content of PM-2.5
Both Campaigns
Campaign
Test Day
Test time (min)
OC concentration after dilution (|J.g/L)
EC concentration after dilution (|J.g/L)
PM-2.5 mass emission factor (mg/kg)
OC mass emission factor (mg/kg)
EC mass emission factor (mg/kg)
OC/PM-2.5 (%)
EC/PM-2.5 (%)
(OC + EQ/PM-2.5 (%)
Campaign
1/16/01
600.33
-0.00736
0.00094
30.18
-4.10
0.52
-13.8
1.8
1.8
#1
1/17/01
600.5
0.00031
0.00630
36.06
0.19
3.76
0.5
10.5
11.1
1/18/01
600.17
-0.00018
0.02675
44.68
-0.10
15.27
-0.2
34.0
34.0
Campaign
7/9/02
600.6
0.002453
0.000300
45.46
42.58
2.98
43.3
6.6
49.9
#2
7/10/02
600.67
0.002397
0.000218
48.06
43.98
1.85
45.2
3.8
49.0
7/11/02
600.0
0.001394
0.000137
200.51
157.20
3.40
63.1
1.7
64.8
L-l
-------
OOPM
80.0
60.0
^ 40.0
Q.
O
O
20.0
0.0
Figure L-l. OC as Percentage of PM
L-2
-------
EC/PM (%
50.0
40.0
— 30.0
20.0
10.0
0.0
o
HI
•
Figure L-2. EC as Percentage of PM
L-3
-------
Table L-2. Organic and Inorganic Carbons for NC A&T Boiler Campaign #1
(1/16/01 - 1/18/01)
Test
Date
Sampling Time (min)
OC on filter (i-ig/cm2)
EC on filter (i^g/cm2)
Array flow (sLpm)
OC concentration at filter (i-ig/L)
EC concentration at filter (i-ig/L)
OC on dilution chamber filter (i^g/cm2)
EC on dilution chamber filter (i^g/cm2)
Array flow (sLpm)
OC concentration at dilution air (i-ig/L)
EC concentration at dilution air (i-ig/L)
Net OC concentration after dilution (i-ig/L)
Net EC concentration after dilution (i-ig/L)
Probe flow (sLpm)
Dilution air (sLpm)
Dilution ratio
OC concentration at the stack (i-ig/L)
EC concentration at the stack (i-ig/L)
Stack flow (serin)
Stack flow (sLpm)
OC emission rate from stack (mg/min)
EC emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Dayl
1/16/01
600.33
0.31
0.59
8.255
0.000841
0.001601
3.09
0.25
8.442
0.008201
0.000636
-0.007359
0.000938
18.54
847.887
46.75
-0.3440
0.0438
4065
115121
-39.9
5.09
No. 2 Oil
3.43
Day 2
1/17/01
600.5
2.39
2.51
8.242
0.006495
0.006821
2.39
0.20
8.656
0.006184
0.000518
0.000310
0.006303
17.88
848.349
48.45
0.0150
0.3054
4159
117783
1.91
38.68
No. 2 Oil
3.62
Day 3
1/18/01
600.17
2.37
10.31
8.489
0.006257
0.027217
2.46
0.18
8.564
0.006437
0.000471
-0.000181
0.026746
19.01
850.660
45.75
-0.0083
1.2236
4827
136701
-1.21
179.48
No. 2 Oil
4.14
L-4
-------
Table L-2. (Continued)
Date
1/16/01
1/17/01
1/18/01
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
OC mass emission factor (mg/kg)
EC mass emission factor (mg/kg)
PM concentration at stack (mg/LO
OC/PM (%)
EC/PM (%)
3.19
10.94
-3.65
0.46
0.0025
-13.8
1.8
3.19
11.55
0.16
3.35
0.0029
0.5
10.5
3.19
13.20
-0.09
13.59
0.0036
-0.2
34.0
L-5
-------
Table L-3. Organic and Inorganic Carbons for NC A&T Boiler Campaign #2
(7/9/02-7/11/02)
Test
Date
Sampling Time (min)
Quartz Filter Sample
OC on filter (|_ig/cm2)
EC on filter (|_ig/cm2)
Array flow (sLpm)
OC concentration at filter (|ig/L)
EC concentration at filter (|ig/L)
Average OC concentration at filter (|ig/L)
Average OC concentration at filter -
corrected (|J.g/L)
Average EC concentration at filter (|ig/L)
OC on dilution chamber filter (|_ig/cm2)
EC on dilution chamber filter (|_ig/cm2)
Array flow (sLpm)
OC concentration at dilution air (|ig/L)
EC concentration at dilution air (|ig/L)
Dayl
7/9/02
600.6
1 2 3
20.42 21.04 19.55
1.77 1.30 1.34
8.215 8.288 8.215
0.05567 0.05685 0.05329
0.00483 0.00351 0.00365
0.055271
0.026871
0.003997
0.90
0.11
8.215
0.002453
0.000300
Day 2
7/10/02
600.67
1 2 3
20.58 21.35 18.87
1.03 0.86 0.80
8.219 8.183 8.183
0.05607 0.05842 0.05164
0.00281 0.00235 0.00219
0.055375
0.028875
0.002449
0.88
0.08
8.219
0.002397
0.000218
Day 3
7/11/02
600.0
1 2
67.37 67.54
1.59 1.38
8.276 8.239
0.18248 0.18376
0.00431 0.00375
0.179408
0.144708
0.003984
0.51
0.05
8.203
0.001394
0.000137
3
63.21
1.43
8.239
0.17198
0.00389
L-6
-------
Table L-3. (Continued)
Test
Date
Net OC concentration after dilution (|ig/L)
Net EC concentration after dilution (|ig/L)
Probe flow (sLpm)
Dilution air (sLpm)
Dilution ratio
OC concentration at the stack (|ig/L)
EC concentration at the stack (|ig/L)
Stack flow (scfm)
Stack flow (sLpm)
OC emission rate from stack (mg/min)
EC emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
OC mass emission factor (mg/kg)
EC mass emission factor (mg/kg)
PM concentration at stack (mg/L)
Dayl
7/9/02
0.024417
0.003697
18.85
816.280
44.30
1.0818
0.1638
4065
115121
129.3
19.58
No. 2 Oil
2.32
3.19
7.40
17.48
2.65
0.0025
Day 2
7/10/02
0.026477
0.002232
18.79
814.430
44.34
1.1741
0.0990
4159
117783
145.0
12.22
No. 2 Oil
2.33
3.19
7.43
19.51
1.64
0.0026
Day 3
7/11/02
0.143315
0.003847
18.78
824.700
44.91
6.4368
0.1728
4827
136701
835.1
22.42
No. 2 Oil
2.33
3.19
7.43
112.36
3.02
0.0102
L-7
-------
Table L-3. (Continued)
OC/PM (%)
EC/PM (%)
Test
Date
Dayl
7/9/02
43.3
6.6
Day 2
7/10/02
45.2
3.8
Day 3
7/11/02
63.1
1.7
Note: OC collected on quartz filter was corrected for gas-phase OC adsorption by subtracting OC found on quartz filter behind a
Teflon filter
L-8
-------
Table L-4. Campaign #2 July 9, 2002, Organic/Elemental Carbon Samples
NIOSH 5040 Method
ID IB070902H
D1B1 D1A1 R2A1 R2B1 R4A1 R4B1 R6A1
R8A1 R10A1
Time min 600.6
dilu.PM mg 0.003
Flowslpm 8.215025
dilu.PM ug/L 0.001
res.PM mg
Flow slpm
res. PM ug/L
ave.res.PM ug/L
dilu.OC ug/cm2
dilu.EC ug/cm2
dilu.OC ug
dilu.EC ug
Flow slpm
dilu.OC ug/L
dilu.EC ug/L
0.292 0.284 0.278 0.266
8.251 8.251 8.106 8.106
0.058 0.057 0.056 0.054
0.056
0.9
0.11
12.11
1.48
8.215
0.002
0.000
Test data
PM on filter DIB 1
Flow for DIB 1
dilu.PM ug/L = dilu. PM mg
*1000/(DlBl.Flow slpm * Time min)
PM on each res.filter
Flow for each res.filter
res. PM ug/L = res.PM mg*1000 /(Flow slpm
* Time min) - dilu.PM ug/L]
Average of res.PM ug/L
OC reading
EC reading
dilu.OC ug = dilu.OC ug/cm2 * 13.45 where
13.45 cm2 is total aera of QF
dilu.EC ug = dilu.EC ug/cm2 * 13.45
Flow for D1A1
dilu.OC ug/L = dilu.OC ug / (DIAl.Flow
slpm * Time min)
dilu.EC ug/L = dilu.EC ug / (DIAl.Flow slpm
* Time min)
OC ug/cm2
EC ug/cm2
Flow slpm
OCug
ECug
20.42 21.04 19.55
1.77 1.3 1.34
8.215 8.288 8.215
274.649 282.988 262.9475
23.81 17.49 18.02
OC reading
EC reading
Flows for R4A1 and R10A1
OC ug = OC ug/cm2 * 13.45
EC ug = EC ug/cm2 * 13.45
L-9
-------
Table L-4. (Continued)
D1B1
D1A1 R2A1 R2B1 R4A1 R4B1 R6A1 R8A1 R10A1
OCug/L
ECug/L
OC/PM wt%
EC/PM wt%
0.025 0.026
0.005
44.0
8.0
43.2
6.6
0.003
45.9
5.7
0.022 OC ug/L = OC ug / (Flow slpm * Time min) -
dilu.OC ug/L - correction for OC on backup
filter
0.003 EC ug/L = EC ug / (Flow slpm * Time min) -
dilu.EC ug/L
39.6 OC/PM wt% = OC ug/L / ave.res.PM ug/L
*100
5.9 EC/PM wt% = EC ug/L / ave.res.PM
ug/L*100
ave wt % OC
Ave wt% EC
L-10
-------
Table L-5. Oil-Fired Institutional Boiler, Campaign #2, July 10, 2002 Organic/Elemental Carbon Samples -
NIOSH 5040 Method
ID IB07100
2H
D1B1 D1A1 R2A1 R2B1 R4A1 R4B1
R6A1
R8A1
R10A1
Time min 600.67
dilu.PM mg 0.002
Flowslpm 8.219
dilu.PM ug/L 0.000
res.PM mg
Flow slpm
res. PM ug/L
ave.res.PMug/L
dilu.OC ug/cm2
dilu.EC ug/cm2
dilu.OC ug
dilu.EC ug
Flow slpm
dilu.OC ug/L
dilu.EC ug/L
OC ug/cm2
EC ug/cm2
Flow slpm
OCug
0.300 0.302 0.267 0.270
8.183 8.183 8.075 8.075
0.061 0.061 0.055 0.055
0.058
0.88
0.08
11.84
1.08
8.219
0.002
0.000
20.58 21.35 18.87
1.03 0.86 0.8
8.219 8.183 8.183
276.801 287.1575 253.8015
Test data
PM on filter DIB 1
Flow for DIB 1
dilu.PM ug/L = dilu. PM mg * 1000/(DlBl.Flow
slpm * Time min)
PM on each res.filter
Flow for each res.filter
res. PM ug/L = res.PM mg* 1000 /(Flow slpm * Time
min) - dilu.PM ug/L]
Average of res.PM ug/L
OC reading
EC reading
dilu.OC ug = dilu.OC ug/cm2 * 13.45 where 13.45
cm2 is total aera of QF
dilu.EC ug = dilu.EC ug/cm2 * 13.45
Flow for D1A1
dilu.OC ug/L = dilu.OC ug / (DIAl.Flow slpm *
Time min)
dilu.EC ug/L = dilu.EC ug / (DIAl.Flow slpm *
Time min)
OC reading
EC reading
Flows for R4A1 and R10A1
OC ug = OC ug/cm2 * 13.45
L-ll
-------
Table L-5. (Continued)
ID IB07100
2H
D1B1 D1A1 R2A1 R2B1 R4A1 R4B1 R6A1 R8A1 R10A1
ECug 13.85 11.57 10.76 EC ug = ECug/cm2 * 13.45
OCug/L 0.027 0.030 0.023 OC ug/L = OC ug / (Flow slpm * Time min) - dilu.OC
ug/L
EC ug/L 0.003 0.002 0.002 EC ug/L = EC ug / (Flow slpm * Time min) - dilu.EC ug/L
OC/PMwt% 46.9 51.0 39.3 OC/PM wt% = OC ug/L / ave.res.PM ug/L * 100
EC/PMwt% 4.5 3.7 3.4 EC/PMwt% = EC ug/L/ave.res.PM ug/L* 100
45.7 avewt%OC
19 Ave wt% EC
L-12
-------
Table L-6. Oil-Fired Institutional Boiler, Campaign #2, Julyll, 2002 Organic/Elemental Carbon Samples -
NIOSH 5040 Method
ID IB071102H
D1B1 D1A1 R2A1 R2B1 R4A1 46B1 R6A1 R8A1 R10A1
Time min 600 Test data
dilu.PM mg 0.005 PM on filter DIB 1
Flow slpm 8.203 Flow for D1B1
dilu.PM ug/L 0.001 dilu.PM ug/L = dilu. PM mg *1000/(DlBl.Flow slpm *
Time min)
res.PM mg 1.176 1.150 1.082 1.064 PM on each res.filter
Flow slpm 8.276 8.276 8.058 8.058 Flow for each res.filter
res. PM ug/L 0.236 0.231 0.223 0.219 res. PM ug/L = res.PM mg* 1000/(Flow slpm * Time min)
-dilu.PM ug/L]
ave.res.PMug/L 0.227 Average of res.PM ug/L
dilu.OC ug/cm2 0.51 OC reading
dilu.EC ug/cm2 0.05 EC reading
dilu.OC ug 6.86 dilu.OC ug = dilu.OC ug/cm2 * 13.45 where 13.45 cm2 is
total aera of QF
dilu.EC ug 0.67 dilu.EC ug = dilu.EC ug/cm2 * 13.45
Flow slpm 8.203 Flow for D1A1
dilu.OC ug/L 0.001 dilu.OC ug/L = dilu.OC ug / (DIAl.Flow slpm * Time
min)
dilu.EC ug/L 0.000 dilu.EC ug/L = dilu.EC ug / (DIAl.Flow slpm * Time
min)
OCug/cm2 67.37 67.54 63.21 OC reading
ECug/cm2 1.59 1.38 1.43 EC reading
Flow slpm 8.276 8.239 8.239 Flows for R4A1 and RIGA 1
OCug 906.1265 908.413 850.1745 OC ug = OC ug/cm2 * 13.45
L-13
-------
Table L-6. (Continued)
ID IB071102H
D1B1 D1A1 R2A1 R2B1 R4A1 46B1
R6A1
R8A1 R10A1
ECug
OC ug/L
EC ug/L
OC/PM wt%
EC/PM wt%
21.39 18.56 19.23 ECug = ECug/cm2 * 13.45
0.146 0.148 0.136 OC ug/L = OC ug / (Flow slpm * Time min) - dilu.OC
ug/L
0.004 0.004 0.004 EC ug/L = EC ug / (Flow slpm * Time min) - dilu.EC ug/L
64.5 65.0 59.8 OC/PM wt% = OC ug/L/ave.res.PM ug/L * 100
1.8 1.6 1.7 EC/PM wt% = EC ug/L/ave.res.PMug/L* 100
ave wt % OC
Ave wt% EC
L-14
-------
Appendix M
Individual PM-2.5 Elemental Measurements
Both Campaigns
-------
Table M-l. Campaign #1 Elemental Analysis
WXDRF Data
Oil-Fired Institutional Boiler, Campaign #1, January 2001
Elemental Analysis Samples - XRF
T041700G
Element moneoi
HD1B1
S (wt%PM mass) ND
mg on filter
PM mass (mg)
sample flow rate
DR
Time (min)
stack flow (cfm)
stack flow (SLPM)
fuel mass (kg)
emission factor fme/kel
T041700H
IB011601
HR2A1
6.72
0.016
0.243
8.479
46.81
600.33
4065
115121
6565
1.67
T041701 IB01
1601
HR2B1
3.62
0.010
0.267
8.479
46.81
600.33
4065
115121
6565
0.99
T070700F T070700C
IB011701 IB011701HR
HD1B1 2A1
<3e 3.27
0.010
0.303
8.58
48.67
600.5
4159
117783
6925.5
1.00
T070700E
IB011701
HR2B1
3.61
0.011
0.304
8.58
48.67
600.5
4159
117783
6925.5
1.11
T070500A
IB011801
HD1B1
0.01
0.000
0.001
8.564
45.91
600.17
4827
136701
7914.4
0.00
T062900C
IB011801
HR2A1
4.09
0.016
0.398
8.489
45.91
600.17
4827
136701
7914.4
1.47
T062900E
IB011801
HR2B1
12.53
0.050
0.402
8.489
45.91
600.17
4827
136701
7914.4
4.54
All elements above atomic number 9 were analyzed.
Sulfur was the only element found in an amount at least one standard error above detection limit
M-l
-------
Table M-2. Campaign #1 Elemental Analysis
ED and WD Data
T041700G T041700H T041701
IB011601H IB011601 IB011601
D1B1 HR2A1 HR2B1
Element WD ED WD ED WD ED
T070700F T070700C
IB011701 IB011701
HD1B1 HR2A1
WD ED WD ED
T070700E
IB011701
HR2B1
WD ED
T070500A
IB011801
HD1B1
WD ED
T062900C
IB011801
HR2A1
WD ED
T062900E
IB011801
HR2B1
WD ED
S
Ca
Ti
Fe
Ce
ND
6.72
20.13
0.05
0.03
0.05
5.62
18.97 <3e
0.06
5.27
17.44
0.04
5.61
18.60
0.04
0.03
0.03
0.01
4.09
14.56
0.03
0.02
0.07
12.53
14.79
0.02
0.02
0.05
M-2
-------
Table M-3. Campaign #1 Elemental Analyses
WD Second, Third Runs
Element
Mg
Si
S
Sx
Cl
Ar
Ca
Cr
Mn
Fe
Ni
Cu
Sr
Zr
Nb
Mo
Px
P
V
Hg
Pu
Ga
Ir
Ba
Na
Re
T082101E
A
32.4
94.8
24.5
18.8
79.8
46.5
30.1
655.9
48.1
984.9
38.8
27.2
6.13
3.59
4.11
3.09
7.37
11.1
16.2
8.59
5.11
9.08
6.56
13.5
25.4
5.06
Blank 2
B
27
92.3
28.7
19.8
64.3
38.2
28
636.7
40
944
36.3
16.1
5.62
6.15
5.13
4.63
8.42
11.6
15.7
6.07
7.15
10.1
10.1
12.5
24
7.08
T082101F
A
31
76.2
15.7
13.6
37.3
40.8
20.2
614.4
45.1
964.7
40.9
18.6
6.13
4.61
3.08
5.66
12.1
7.37
15.7
6.07
2.04
12.1
4.54
17.6
17.4
4.55
Blank 3
B
28.6
81.3
13.6
15.7
32.7
45.5
32.2
625
34.9
963.2
39.8
25.7
7.15
4.61
7.19
2.06
8.95
8.95
14.1
5.56
5.62
6.56
10.6
13.5
13.9
8.6
T082101G
A
31
93.5
17.8
15.1
28
39.3
21.3
638.7
42.5
942.5
44.4
19.6
6.13
3.59
4.62
1.54
2.63
12.6
12.1
7.58
2.55
8.57
6.05
11.9
16
7.58
Blank 4
B
24.4
84.1
16.7
15.1
28.5
36.7
19.7
618.4
44.6
917.7
47.9
18.1
6.64
6.66
4.62
4.63
10
10
13.1
5.06
5.11
9.08
8.07
12.5
15.7
8.09
T082101D
Blank 1
A
26.5
84.7
14.1
18.3
40.4
34.6
16.6
644.8
38.5
935.9
33.3
24.7
4.6
7.17
2.05
4.11
5.26
9.47
13.6
6.07
5.11
7.57
6.56
9.86
17
4.55
T041700F
Blank D
A
33
76.6
32.4
31.3
39.9
35.1
24.4
621.5
38.5
956.1
38.8
23.7
3.06
2.05
5.13
3.6
8.42
6.32
12.6
8.09
4.6
7.06
10.6
15
17
8.6
ave.
29.24
85.44
20.44
18.46
43.86
39.59
24.06
631.93
41.53
951.13
40.03
21.71
5.68
4.80
4.49
3.67
7.89
9.68
14.14
6.64
4.66
8.77
7.89
13.30
18.30
6.76
ave A
30.78
85.16
20.9
19.42
45.08
39.26
22.52
635.06
42.54
956.82
39.24
22.76
5.21
4.202
3.798
3.6
7.156
9.372
14.04
7.28
3.882
8.876
6.862
13.572
18.56
6.068
aveB
26.67
85.90
19.67
16.87
41.83
40.13
26.63
626.70
39.83
941.63
41.33
19.97
6.47
5.81
5.65
3.77
9.12
10.18
14.30
5.56
5.96
8.58
9.59
12.83
17.87
7.92
These are the data from the oil-fired boiler samples. I ran these filters two extra times with only an Al
rather than the plastic I have used in the past and that I used for the first analysis of these samples
on the other sheet. Filters where the data do not appear twice broke during, or prior to analysis.
Blanks - intensities
mask
M-3
-------
Table M-4. Campaign #1 Elemental Analyses
WD Second and Third Runs
T041700G T041700H T041701 T070700F T070700C T070700E T070500A T062900C T062900E
Element IB011601HD1B1 IB011601HR2A1 IB011601HR2B1 IB011701HD1B1 IB011701HR2A1 IB011701HR2B1 IB011801HD1B1 IB011801HR2A1 IB011801HR2B1
A C A ABCABCABCABCABC
Mg 0.03
Si 0.06
Sx NA 6.72 4.59 3.62 NA 3.27 2.5 2.3 3.6 2.59 2.37 0.01 0.01 0.02 4.09 3.01 2.85 12.53 11.09 9.73
M-4
-------
Table M-5. Campaign #2 Elemental Analysis
Oil-Fired Institutional Burner
Element
Na
Mg
Al
Si
P
P/PO4-3
S
s/so4-2
Cl
Ar
K
Ca
Ti
V
Cr
Mn
Fe
Blank 1
Peak
12.2
28.2
106.7
44.4
6.18
7.73
14.8
11.7
29.9
66.9
18
16.5
19.8
16.4
589
47
846.6
Blank 2
intensity
15.3
30.1
78.5
5934
10.3
5.67
16.9
13.8
33.4
64.4
18.5
17.5
24.3
10.8
585.4
35.7
867
Blank3
intensity
14.3
32
261.9
52.2
4.64
9.28
12.3
10.7
41.5
67.9
23.6
18
30.2
16.4
542.9
43.4
813
Blank 4
intensity
14
44
560.7
47.6
7.22
6.18
12.3
14.3
34.4
67.4
19
18.5
21.3
13.3
550.1
63.8
817.5
Blank 41)
intensity
13.9
27.7
151.4
67.5
6.23
5.19
24.1
20.5
38.5
63.7
16
21.9
23.2
14.4
559.9
44.4
861.5
Blank 5
intensity
16.8
35.8
311.3
53.2
6.18
5.15
18.9
26.6
39.5
65.9
18.5
23.5
20.3
14.9
515.8
58.2
854.7
Blank 5b
intensity
16.9
33.9
287.5
69.1
9.35
8.31
22.6
25.6
40.5
71.2
20
20.9
17.8
13.8
542
60.7
848.8
dilution
intensity
13.4
30.7
17.4
70
4.68
10.9
17.4
12.8
52.6
72.7
25
40.3
36.1
26.2
604.4
52.5
927.1
Mean
14.60
32.80
221.93
57.93
6.85
7.30
17.41
17.00
38.79
67.51
19.83
22.14
24.13
15.78
561.9
50.71
854.53
Standard
deviation
1.6
5.3
172.9
10.1
2.0
2.1
4.4
6.3
6.9
3.1
3.0
7.7
6.1
4.6
29.6
9.7
35.2
RSD
11.2
16.1
77.9
17.4
29.8
28.9
25.1
37.3
17.7
4.6
15.2
34.9
25.4
29.0
5.3
19.2
4.1
M-5
-------
Table M-5. (Continued)
Element
Ni
Cu
Zn
Ga
Br
Sr
Mo
Rh
Cd
Blank 1
Peak
31.4
18.7
7.07
6.55
7.08
5.58
3.05
1.52
4.06
Blank 2
intensity
41.1
21.8
9.6
7.55
5.06
6.09
2.03
2.03
2.54
Blank3
intensity
o o
JJ
217.2
18.7
8.56
4.55
5.07
5.59
2.54
5.07
Blank 4
intensity
36.5
329.1
15.2
13.6
4.55
6.6
3.56
3.55
5.58
Blank 41)
intensity
41.5
19.1
10.6
8.56
6.57
6.56
2.54
2.03
3.55
Blank 5
intensity
42.6
22.3
11.6
6.04
5.06
4.57
4.57
1.52
1.01
Blank 5b
intensity
48.6
17.2
12.1
9.06
8.59
4.06
5.08
1.52
5.58
dilution
intensity
46.1
28.8
15.1
10.1
8.09
8.62
1.52
3.55
2.54
Mean
40.10
84.28
12.50
8.75
6.19
5.89
3.49
2.28
3.74
Standard
deviation
6.1
120.4
3.7
2.4
1.6
1.4
1.5
0.9
1.6
%
RSD
15.1
142.9
29.5
27.0
26.1
24.3
42.2
37.6
44.0
Note: values in shaded cells are outliers.
M-6
-------
Table M-5. (Continued)
Element
Na
Mg
Al
Si
P
P/PO;3
S
s/so4-2
Cl
Ar
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Blank 1
Peak
12.2
28.2
106.7
44.4
6.18
7.73
14.8
11.7
29.9
66.9
18
16.5
19.8
16.4
589
47
846.6
31.4
Blank 2
intensity
15.3
30.1
59.4
10.3
5.67
16.9
13.8
33.4
64.4
18.5
17.5
24.3
10.8
585.4
35.7
867
41.1
Blank3
intensity
14.3
32
261.9
52.2
4.64
9.28
12.3
10.7
41.5
67.9
23.6
18
30.2
16.4
542.9
43.4
813
33
Blank 4
intensity
14
44
47.6
7.22
6.18
12.3
14.3
34.4
67.4
19
18.5
21.3
13.3
550.1
63.8
817.5
36.5
Blank 41)
intensity
13.9
27.7
151.4
67.5
6.23
5.19
24.1
20.5
38.5
63.7
16
21.9
23.2
14.4
559.9
44.4
861.5
41.5
Blank 5
intensity
16.8
35.8
311.3
53.2
6.18
5.15
18.9
26.6
39.5
65.9
18.5
23.5
20.3
14.9
515.8
58.2
854.7
42.6
Blank 5b
intensity
16.9
33.9
287.5
69.1
9.35
8.31
22.6
25.6
40.5
71.2
20
20.9
17.8
13.8
542
60.7
848.8
48.6
dilution
intensity
13.4
30.7
70
4.68
10.9
17.4
12.8
52.6
72.7
25
604.4
52.5
927.1
46.1
Mean
14.60
32.80
223.76
57.93
6.85
7.30
17.41
17.00
38.79
67.51
19.83
19.54
22.41
14.29
561.9
50.71
854.53
40.10
Standard
deviation
1.6
5.3
89.6
10.1
2.0
2.1
4.4
6.3
6.9
3.1
3.0
2.6
4.1
1.9
29.6
9.7
35.2
6.1
%RSD
11.2
16.1
40.0
17.4
29.8
28.9
25.1
37.3
17.7
4.6
15.2
13.2
18.1
13.6
5.3
19.2
4.1
15.1
M-7
-------
Table M-5. (Continued)
Element
Cu
Zn
Ga
Br
Sr
Mo
Rh
Cd
Blank 1
Peak
18.7
7.07
6.55
7.08
5.58
3.05
1.52
4.06
Blank 2
intensity
21.8
9.6
7.55
5.06
6.09
2.03
2.03
2.54
Blank3
intensity
18.7
8.56
4.55
5.07
5.59
2.54
5.07
Blank 4
intensity
15.2
13.6
4.55
6.6
3.56
3.55
5.58
Blank 4b
intensity
19.1
10.6
8.56
6.57
6.56
2.54
2.03
3.55
Blank 5
intensity
22.3
11.6
6.04
5.06
4.57
4.57
1.52
Blank 5b
intensity
17.2
12.1
9.06
8.59
4.06
5.08
1.52
5.58
dilution
intensity
28.8
15.1
10.1
8.09
8.62
1.52
3.55
2.54
Mean
21.32
12.50
8.75
6.19
5.89
3.49
2.28
4.13
Standard
deviation
4.1
3.7
2.4
1.6
1.4
1.5
0.9
1.3
%RSD
19.4
29.5
27.0
26.1
24.3
42.2
37.6
32.0
Note: Shaded areas indicate outliers.
M-8
-------
Table M-6. Campaign #2 Elemental, wt% results
NC A&T, Test #2
July, 2002
IB070902HR2A1
Units
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
EDXRF WDXRF
ng/cm2 wt% wt%
193.8 0.893338 0.85
25.6
5
12.4
532.5 2.454606 2.55
43.2
9.2 0.04208
2.1
21.9 0.10095
2.3
1.4
0.9
18.9 0.09
2.4
2.7
1.2
20.6
3.4
M-9
-------
Table M-6. (Continued)
IB070902HR2B1
Units
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
EDXRF WDXRF
ng/cm2 wt% wt%
230.3 1.09 0.934
28.4
5.9
13
638.5 3.03 2.86
50.4
7.4 0.04
2
29.9 0.14 0.292
2.7
2.4
0.9
18.1 0.09
2.4
3.4
1.3
64 0.30
6.4
M-10
-------
Table M-6. (Continued)
IB071002HR2A1
Units
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
EDXRF WDXRF
ng/cm2 wt% wt%
163.5 0.73 0.716
24.7
11.5
13.6
868.4 3.90 3.62
66.8
1.9
1.9
3.5 0.02
1.7
0.4
0.9
7.5
1.7
6.6 0.03
1.4
0.1
2.3
M-ll
-------
Table M-6. (Continued)
Units
IB071002HR2B1
EDXRF WDXRF
ng/cm2 wt% wt%
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
194.5 0.87 0.777
25.8
-18.2
12.9
931.7 4.15 3.81
71.2
-0.9
1.8
5.4 0.02
1.7
10 0.04
1.3
36.6 0.16
3.7
6.9 0.03
1.5
4.1
2.5
M-12
-------
Table M-6. (Continued)
Units
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
IB071102HR2A1
DXRF
ng/cm2 wt%
255.6 0.29
33.9
4.1
15.2
1271.5 1.46
100.2
7 0.01
1.9
5.7 0.01
1.7
9.2 0.01
1.2
41.2 0.05
3.9
5.9 0.01
1.4
00.5
2.3
WDXRF
wt%
0.242
1.36
M-13
-------
Table M-6. (Continued)
IB071102HR2B1
Units
Si
Si
P
P
S
s
K
K
Ca
Ca
Cr
Cr
Fe
Fe
Cu
Cu
Zn
Zn
CONC
UNC
CON
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
CONC
UNC
EDXRF WDXRF
ng/cm2 wt% wt%
181.2 0.21 0.244
28.5
20.2
14.3
1180.8 1.38 1.28
93.3
-0.1
1.7
5.1
1.7 0.01
-0.4
0.9
10.4
1.9
6 0.01
1.4
2.1 0.01
2.2
M-14
-------
Table M-7. OAQPS Samples
Background Corrected
1008978 1008981 1008984 OAQPS 071102 Port 2 Position 1
Na 0.085
Si 0.118 0.0223
S 0.528 0.877 0.583
M-15
-------
Table M-8. Campaign #2 Elemental Comparison
Oil-Fired Institutional Boiler
Campaign #2, July 2002
XRF (Both Energy and Wavelength Dispersive)
Element
EDXRF
wt%
IB070902HR2A1
WDXRF
wt%
% diff
EDXRF
wt%
IB070902HR2B1
WDXRF
wt%
% diff
Si
S
K
Ca
Cr
Fe
Cu
Zn
0.893338
2.454606
0.042408
0.10095
0.09
0.85
2.55
4.9
-3.9
1.09
3.03
0.04
0.14
0.09
0.30
0.934
2.86
0.292
14.4
5.5
M-16
-------
Table M-8. (Continued)
Element
EDXRF
wt%
IB071001HR2A1
WDXRF
wt%
% diff
EDXRF
wt%
IB071002HR2B1
WDXRF
wt%
% diff
Si
S
K
Ca
Cr
Fe
Cu
Zn
0.73
3.90
0.02
0.716
3.62
2.4
7.1
0.03
0.87
4.15
0.02
0.04
0.16
0.03
0.777
3.81
10.4
8.2
M-17
-------
Table M-8. (Continued)
Element
EDXRF
wt%
IB071102HR2A1
WDXRF
wt%
% diff
EDXRF
wt%
IB071102HR2B1
WDXRF
wt%
% diff
Si
S
K
Ca
Cr
Fe
Cu
Zn
0.29
1.46
0.01
0.01
0.01
0.05
0.01
0.242
1.36
17.3
6.5
0.21
1.38
0.01
0.01
0.01
0.244
1.28
-15.0
7.4
M-18
-------
Appendix N
Individual PM-2.5 Inorganic Ion Measurements
Both Campaigns
-------
Table N-l. Oil-Fired Institutional Boiler, Campaign #1, January 2001
Inorganic Ion Samples Analyzed by Ion Chromatography
T041700J
IB011601Hr4Al
T062900D IB011701Hr4Al
T062901A IB011801Hr4Al
sulfate
ave
std dev
RSD
mg/kg
1.72
1.67
1.69
1.69
0.03
0.02
wt%
PM mass
63.50
61.39
62.07
62.32
1.07
0.02
sulfate
ave
std dev
RSD
T062700F
mg/kg
18.28
18.42
18.30
18.33
0.08
0.00
T062900F
wt%
PM mass
60.44
60.91
60.50
60.62
0.25
0.00
IB011701Hr4Bl
sulfate
ave
std dev
RSD
T062900B
mg/kg
17.13
16.88
16.69
16.90
0.22
0.01
wt%
PM mass
49.17
48.48
47.93
48.53
0.62
0.01
IB011801Hr4Bl
IB011601Hr4Bl
sulfate
ave
std dev
RSD
mg/kg
1.79
1.79
1.78
1.79
0.01
0.01
wt%
PM mass
53.65
53.83
53.50
53.66
0.17
0.01
sulfate
ave
std dev
RSD
mg/kg
18.20
18.13
18.14
18.15
0.04
0.00
wt%
PM mass
53.20
53.00
53.03
53.08
0.11
0.00
sulfate
ave
std dev
RSD
mg/kg
15.42
15.72
15.73
15.62
0.18
0.01
wt%
PM mass
41.99
42.82
42.84
42.55
0.49
0.01
N-l
-------
Table N-2. Ions, Campaign #2
Raw ppm Filter Samples
A&T Oil Boiler Test 2 July 2002
for K, NH4, Cl, NO3
ND - < 0.3ppm
NQ - < 0.45ppm
for Mg, Ca, SO4 (later eluting ions)
ND - < O.Sppm
NQ - < 0.60ppm
sample ID
PMmass K(a) NH4 (a) NH4 (b) NH4 (c) NH4 (d) NH4 (ave) std dev
mg mg/L mg/L
%RSD
1007995
1008951
1008952
1008953
1008954
1008956
1008957
1008960
1008961
1008962
1008963
IB070902HR4A1
IB070902HR4B1
IB070902HR5A3
IB070902HR5B3
IB070902 -FB
IB071002HR4A1
IB071002HR4B1
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3
0.278
0.266
0.12
0.156
0.006
0.267
0.27
0.135
0.138
0.361
0.357
NQ
NQ
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.53 0.53 0.53 0.53 0.00
0.56 0.57 0.57 0.57 0.01
ND
ND
ND
0.66 0.68 0.67 0.68 0.67 0.01
0.71 0.71 0.72 0.71 0.01
NQ
NQ
NQ
0.52 0.52 0.52 0.52 0.00
0.00
1.75
1.49
1.41
0.00
N-2
-------
Table N-2. (Continued)
sample ID
PM mass K (a)
mg mg/L
NH4 (a) NH4
(b)
NH4(c) NH4(d) NH4 (ave) std dev
mg/L
%RSD
1008965
1008966
1008976
1008977
1008979
1008980
1008982
1008983
IB071102HR4A1
IB071102HR4B1
070902 P6, PI*
070902 P5, PI*
071002 P5, PI*
071002 P6, PI*
071102 P5, PI*
071102 P6. PI*
1.082
1.064
0.046
0.041
0.024
0.024
0.047
0.053
ND
ND
ND
ND
ND
ND
ND
ND
0.52 0.53 0.53 0.53 0.01
0.47 0.47 0.47 0.47 0.47 0.00
ND
ND
ND
ND
ND
ND
1.89
0.00
* OAQPS samples: date, port, position
N-3
-------
Table N-3. Campaign #2 Ions
Raw ppm Filter Samples
1007995
1008951
1008952
1008953
1008954
1008956
1008957
1008960
1008961
1008962
1008963
1008965
Sample ID mg ion wt% PM
on filter Mass
IB070902HR4A1 0.005 1.91
IB070902HR4B1 0.006 2.13
IB070902HR5A3
IB070902HR5B3
IB070902 -FB
IB071002HR4A1 0.007 2.52
IB071002HR4B1 0.007 2.64
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3 0.005 1.46
IB071102HR4A1 0.005 0.49
Mg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ca(a) Ca(b) Ca (c) Ca std dev
(ave)
H12/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
N-4
-------
Table N-3. (Continued)
Sample ID
mg ion
on filter
wt% PM
Mass
Mg
Ca(a) Ca(b) Ca (c) Ca (ave) std dev
mg/L
1008966 IB071102HR4B1 0.005 0.44
1008976 070902 P6, PI*
1008977 070902 P5, PI*
1008979 071002 P5, PI*
1008980 071002 P6, PI*
1008982 071102 P5, PI*
1008983 071102 P6. PI*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
N-5
-------
Table N-4. Campaign #2 Ions
Raw ppm Filter Samples
Sample ID %RSD mgion wt% PM Cl (a) Cl (b) Cl (c) Cl (d) Cl (ave) std dev %RSD
on filter Mass ms/L
1007995
1008951
1008952
1008953
1008954
1008956
1008957
1008960
1008961
1008962
1008963
1008965
1008966
1008976
IB070902HR4A1
IB070902HR4B1
IB070902HR5A3
IB070902HR5B3
IB070902 -FB
IB071002HR4A1
IB071002HR4B1
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3
IB071102HR4A1
IB071102HR4B1
070902 P6, PI*
ND
NQ
NQ
ND
ND
NQ
NQ
NQ
NQ
ND
ND
NQ
NQ
ND
N-6
-------
Table N-4. (Continued)
Sample ID
%RSD mg ion wt% PM
on filter Mass
Cl (a) Cl(b) Cl(c)
Cl(d) Cl(ave) std dev %RSD
mg/L
1008977
1008979
1008980
1008982
1008983
070902 P5, PI*
071002 P5, PI*
071002 P6, PI*
071102 P5, PI*
071102 P6. PI*
ND
ND
ND
ND
ND
N-7
-------
Table N-5. Campaign #2 Ions
Raw ppm Filter Samples
Sample ID
mg ion wt% PM SO4 (a) SO4 (b) SO4 (c) SO4 (d) SO4 (e) SO4 (f) SO4 (ave) std dev %RSD
on filter Mass mg/L
1007995
1008951
1008952
1008953
1008954
1008956
1008957
1008960
1008961
1008962
1008963
1008965
1008966
1008976
1008977
IB070902HR4A1
IB070902HR4B1
IB070902HR5A3
IB070902HR5B3
IB070902 -FB
IB071002HR4A1
IB071002HR4B1
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3
IB071102HR4A1
IB071102HR4B1
070902 P6, PI*
070902 P5, PI*
1.86
1.86
0.91
0.8
ND
2.88
2.87
1.31
1.23
1.9
1.97
3.74
3.73
ND
ND
1.86
1.85
0.95
0.81
2.89
2.9
1.28
1.2
1.9
1.98
3.7
3.68
1.87
1.84
0.93 0.92 0.92
0.8
2.88
2.89 2.89
1.26 1.25
1.21 1.21
1.87
1.97
3.69
3.76 3.72 3.73
1.86
1.85
0.93
0.80
2.88
2.89
1.28
1.21
1.89
1.97
3.71
3.72
0.01
0.01
0.02
0.01
0.01
0.01
0.03
0.01
0.02
0.01
0.03
0.03
0.54
0.54
2.15
1.25
0.35
0.35
2.34
0.83
1.06
0.51
0.81
0.81
N-8
-------
Table N-5. (Continued)
Sample ID
mg ion wt% PM SO4 (a) SO4 (b) SO4 (c) SO4 (d) SO4 (e) SO4 (f) SO4 (ave) std dev %RSD
on filter Mass mg/L
1008979 071002 P5, PI*
1008980 071002 P6, PI*
1008982 071102 P5, PI*
1008983 071102 P6. PI*
ND
ND
NQ
NO
N-9
-------
Table N-6. Campaign #2 Ions
Raw ppm Filter Samples
1007995
1008951
1008952
1008953
1008954
1008956
1008957
1008960
1008961
1008962
1008963
1008965
1008966
1008976
1008977
1008979
1008980
1008982
1008983
IB070902HR4A1
IB070902HR4B1
IB070902HR5A3
IB070902HR5B3
IB070902 -FB
IB071002HR4A1
IB071002HR4B1
IB071002HR5A3
IB071002HR5B3
IB071102HR5A3
IB071102HR5B3
IB071102HR4A1
IB071102HR4B1
070902 P6, PI*
070902 P5, PI*
071002 P5, PI*
071002 P6, PI*
071102 P5, PI*
071102 P6. PI*
mg ion wt% PM
on filter Mass
0.02 6.70
0.02 6.95
0.01 7.72
0.01 5.15
0.03 10.80
0.03 10.69
0.01 9.44
0.01 8.79
0.02 5.24
0.02 5.53
0.04 3.43
0.04 3.50
NO3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
N-10
-------
Table N-7. Campaign #2 Ions
Wt% Filter Samples
Oil-Fired Institutional Boiler, Campaign #2, July 2002
Inorganic Ion Samples - Ion
Chromatography
Teflon Filter ID
Wt. %,
PM-2.5 mass
Wt. %,
PM-2.5 mass
NH4
K
Mg
Ca
Cl
N03
S04
NH4
K
Mg
Ca
Cl
N03
S04
IB070902
HR4A1
1.91
NQ
ND
ND
ND
ND
6.70
IB071102
HR4B1
0.44
ND
ND
ND
NQ
ND
3.5
IB070902
HR4B1
2.13
NQ
ND
ND
NQ
ND
6.95
070902 P6,
PI*
ND
ND
ND
ND
ND
ND
ND
HIB07090
2R5A3
ND
ND
ND
ND
NQ
ND
7.72
070902
P5.P1*
ND
ND
ND
ND
ND
ND
ND
IB070902
HR5B3
ND
ND
ND
ND
ND
ND
5.15
071002
P5.P1*
ND
ND
ND
ND
ND
ND
ND
IB070902 -
FB
ND
ND
ND
ND
ND
ND
ND
0701002
P6.P1*
ND
ND
ND
ND
ND
ND
ND
IB071002
HR4A1
2.52
ND
ND
ND
NQ
ND
10.80
071102
P5.P1*
ND
ND
ND
ND
ND
ND
NO
IB071002
HR4B1
2.64
ND
ND
ND
NQ
ND
10.69
071102
P6.P1*
ND
ND
ND
ND
ND
ND
NO
IB071002
HR5A3
NQ
ND
ND
ND
NQ
ND
9.44
IB071002
HR5B3
NQ
ND
ND
ND
NQ
ND
8.79
IB071102
HR5A3
NQ
ND
ND
ND
ND
ND
5.24
IB071102
HR4A1
0.49
ND
ND
ND
NQ
ND
3.43
N-ll
-------
Appendix O
Individual or Composited Particle-Phase Semivolatile
Organic Compounds
Quartz Filters
-------
Table O-l. Quartz Filter Species Emission Factors (jig/kg)
Test Date
Sampling Array
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
7/9/02
Compo-
site
0.000
0.000
0.000
0.000
0.000
0.000
7/10/02
Compo-
site
0.000
1.186
1.067
1.305
2.846
1.305
First Two-Day
Avg.
0.000
0.593
0.534
0.652
1.423
0.652
SD
0.000
0.839
0.755
0.923
2.013
0.923
7/11/02
6A
12.981
0.000
0.000
0.000
0.000
0.000
Summer
Campaign
6B
5.440
5.384
0.000
6.363
11.258
5.874
Port
Avs
9.210
2.692
0.000
3.182
5.629
2.937
PortSD
5.333
3.807
0.000
4.499
7.961
4.153
8A
6.630
0.000
0.000
0.000
0.000
0.000
10A
12.016
0.000
0.000
0.000
0.000
0.000
Day
Avs
8.324
2.019
0.000
2.386
4.222
2.203
DaySD
2.921
2.578
0.000
3.046
5.389
2.812
Average
4.16
1.31
0.27
1.52
2.82
1.43
Uncertainty
1.46
1.36
0.38
1.59
2.88
1.48
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1-Methylfluorene 0.000
Add'l Methylfluorenes -
Peakl
Add'l Methylfluorenes -
Peak 2
Phenanthrene 4.370
Add'l 0.000
Dimethylphenanthrenes
Anthracene
Methylanthracene-Peak 1 0.000
Methylanthracene-Peak 2 0.000
Methylanthracene-Peak 3 0.000
Methylanthracene-Peak 4 0.000
0.000 0.000 0.000 15.692 15.792 15.742 0.071 12.167 11.136 13.709 2.413
2.413 3.392 1.384 41.642 44.818 43.230 2.245
0.000 0.000 0.000 52.862 51.885 52.374 0.691
0.000 0.000 0.000 136.519 147.333 141.926 7.647
0.000 0.000 0.000 165.773 189.428 177.600 16.727
0.000 0.000 0.000 107.265 113.069 110.167 4.105
0.000 0.000 0.000 91.355 97.406 94.380 4.279
36.040 32.574 39.165 5.822
45.861 45.879 49.000 3.619
118.386 112.378 130.006 17.205
145.583 147.431 165.011 21.918
90.123 91.242 101.150 12.154
76.791 74.747 85.831 11.714
6.85
21.28
24.50
65.00
82.51
50.58
42.92
1.21
2.99
1.81
8.60
10.96
6.08
5.86
O-l
-------
Table O-l. (Continued)
Test Date 7/9/02
7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/5-2-Ethylhexyl phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Compo-
site
0.000
0.000
28.981
0.000
0.000
0.000
0.000
4.936
3.565
Compo-
site
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.795
2.846
Avg. SD
0.000 0.000
0.000 0.000
14.491 20.493
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
3.865 1.513
3.206 0.508
6A 6B Port Port SD 8A
Avg
26.407 29.664 28.036 2.302 22.458
84.523 103.719 94.121 13.574 72.153
0.000 0.000 0.000 0.000 0.000
114.25 0.000 57.13 80.79 57.04
94.86 5.28 50.07 63.34 74.88
117.68 307.68 212.68 134.35 24.74
7.698 10.279 8.989 1.825 7.999
117.02 116.50 116.76 0.37 108.79
17.963 18.600 18.282 0.451 17.598
10A Day Day SD
Avg
19.862 25.005 4.612 12.50
67.922 84.479 17.217 42.24
0.000 0.000 0.000 7.25
6.64 30.202 31.157 15.10
17.54 36.941 31.574 18.47
33.78 144.720 138.898 72.36
0.000 6.817 4.639 3.41
91.76 108.449 11.725 56.16
15.980 17.615 1.167 10.41
2.31
8.61
10.25
15.58
15.79
69.45
2.32
5.91
0.64
O-2
-------
Table O-l. (Continued)
Test Date 7/9/02
7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Compo- Compo-
site site
Avg.
SD
6A
6B
Port
Avg
PortSD
8A
10A
Day
Avg
DaySD
Cholestane 3
Cholestane 4
ABB-20R-24S-
Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-
Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (»-C15)
w-Hexadecane (w-C16)
w-Heptadecane («-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
«-Nonadecane (
0.000
0.000
0.000
0.000
1.472
1.353
2.392
0.000
0.000 0.000 0.000 0.000 4.895 2.447
0.000 0.000 0.000 19.688 0.000 9.844
0.000 0.000 0.000 1.172 0.000 0.586
3.461 0.000 0.000 1.836 2.343
13.922 0.000 0.000 2.461 4.922
0.829 0.000 0.000 0.147 0.293
0.000 0.736 1.041 14.529 15.361 14.945 0.589 12.692 6.435 12.358 4.119
0.000 0.676 0.956 57.699 61.950 59.824 3.006 45.016 30.813 49.401 14.501
0.000 1.196 1.692 71.762 86.245 79.004 10.241 70.249 40.990 69.122 19.862
25.813 12.906 18.252 127.824 156.747 142.285 20.452 111.329 87.279 124.410 31.172
0.92
1.23
0.07
6.55
25.04
35.16
68.66
1.17
2.46
0.15
2.12
7.27
9.97
18.06
O-3
-------
Table O-l. (Continued)
Test Date 7/9/02
7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Compo-
site
Compo- Avg. SD 6A 6B Port Port SD 8A 10A Day Day SD
site Avg Avg
w-Eicosane («-C20)
w-Heneicosane (»-C21)
w-Docosane («-C22)
w-Tricosane («-C23)
iso-Docosane (C22)
anteiso-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/5o-Tricosane (C23)
awfe/'so-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
anfe/'so-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awfe/so-Pentacosane (C25)
Heptacosane (n-C2T)
6.039
0.052
0.000
0.000
0.000 3.020 4.270 569.687654.213611.950 59.768 558.810325.202537.544146.844 270.28 73.45
0.000 0.026 0.037 636.080 717.080 676.580 57.276 618.526 346.896 589.771 166.892 294.90 83.45
0.000 0.000 0.000 768.500880.251824.375 79.020 711.113494.037727.444170.774 363.72 85.39
0.000 0.000 0.000 911.8451028.04969.945 82.165 861.527722.575895.523134.372 447.76 67.19
44.047
16.361 30.204 19.577 183.821 155.820 169.820 19.799 184.046 116.766 156.613 28.957 93.41 17.48
197.708 0.000 98.854 139.801 1089.89 1165.28 1127.59 53.311 1020.58 887.937 1050.3 124.418 574.60 93.57
124.145 0.000 62.073 87.784 539.209 564.095 551.652 17.597 506.291 451.151 518.297 51.194 290.18 50.81
98.582 34.575 66.57845.260379.427384.986382.206 3.931 346.740314.264357.049 33.418 211.81 28.13
70.696 57.189 63.943 9.551 229.879 207.882 218.881 15.554 174.055 173.824 193.660 25.947 128.80 13.82
O-4
-------
Table O-l. (Continued)
Test Date 7/9/02
7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Compo- Compo-
site site
Avg.
SD
6A
6B
Port
Avg
PortSD
8A
10A
Day
Avg
DaySD
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/'so-Heptacosane (C27)
awte/50-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 54.140
Nonacosane (w-C29) 38.386
/5o-Nonacosane (C29)
anteiso-Nonacosane (C29)
Squalene 0.000
Indeno[l,2,3-c,d]-
fluoranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30) 0.000
w-Hentriacontane (w-C31) 0.000
/5o-Triacontane (C30)
anfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane
(C31)
/5o-Dotriacontane (C32)
awfe/'so-Dotriacontane (C32)
Dotriacontane (w-C32) 0.000 0.000
Tritriacontane (C33) 0.000 1.067
44.078 49.109 7.115 194.474 149.095 171.784 32.087 143.594 121.819 146.573 25.051 97.84 13.02
44.594 41.490 4.390 71.306 46.235 58.771 17.728 34.585 27.919 41.878 16.233 41.68 8.41
0.000 0.000 0.000 0.000 644.616 322.308 455.813 87.239 252.802 326.741 120.761 163.37 60.38
0.134 0.067 0.095 12.656 4.293 8.475 5.914 3.386 1.928 4.521 3.437 2.29 1.72
0.000 0.000 0.000 15.804 6.248 11.026 6.757 2.981 0.000 5.064 5.703 2.53 2.85
0.000
0.534
0.000
0.755
8.961
0.000
0.000
0.000
4.480
0.000
6.336
0.000
1.398
0.000
0.000
0.000
1.470
0.000
2.292
0.000
0.73
0.27
1.15
0.38
O-5
-------
Table O-l. (Continued)
Test Date 7/9/02 7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awfe/'so-Tritriacontane (C34)
Pentatriacontane (C35)
Hexatriacontane (n-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1 ,4-Benzenedicarboxylic
acid
Compo-
site
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.428
0.985
0.000
3.999
0.000
0.000
18.620
Compo-
site
1.542
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.483
3.535
0.000
3.264
0.000
0.000
18.995
Avg.
0.771
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.456
2.260
0.000
3.631
0.000
0.000
18.808
SD
1.090
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.453
1.803
0.000
0.520
0.000
0.000
0.265
6A
0.000
11.160
59.774
16.034
54.785
20.082
46.646
20.395
39.607
17.192
24.378
33.786
0.000
127.82
5.622
73.065
6B Port PortSD 8A
Avg
0.000 0.000 0.000 0.000
11.160
59.774
16.034
54.785
20.082
46.646
20.395
39.607
17.192
24.378
33.786
0.000
127.82
5.622
73.065
10A
0.000
13.823
68.754
13.587
37.020
21.049
20.522
9.676
17.544
18.569
17.398
14.233
0.000
0.000
0.000
72.133
Day
Avg
0.000
12.492
64.264
14.811
45.902
20.565
33.584
15.035
28.575
17.881
20.888
24.010
0.000
63.912
2.811
72.599
DaySD
0.000
1.883
6.350
1.730
12.562
0.684
18.473
7.580
15.601
0.973
4.936
13.826
0.000
90.385
3.975
0.659
0.39
6.25
32.13
7.41
22.95
10.28
16.79
7.52
14.29
10.17
11.57
12.00
1.82
31.96
1.41
45.70
0.55
0.94
3.17
0.87
6.28
0.34
9.24
3.79
7.80
0.87
2.63
6.91
0.26
45.19
1.99
0.36
O-6
-------
Table O-l. (Continued)
Test Date 7/9/02 7/10/02 First Two-Day 7/11/02
Summer Uncertainty
Campaign
Average
Sampling Array
Compound
Compo- Compo- Avg. SD 6A 6B Port Port SD
site site Avg
8A 10A Day Day SD
Avg
1,3-Benzenedicarboxylic 36.816
acid
1,2-Benzenedicarboxylic 0.000
acid, 4-methyl
1,2,4-Benzenetricarboxylic 216.929
acid
Benzenetetracarboxylic acid 47.440
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
28.219 32.518 6.079 123.48
0.000 0.000 0.000 0.000
0.000 108.46 153.392 1047.2
4
0.000 23.720 33.545 266.88
123.48
0.000
1047.2
266.88
132.46 127.97 6.348
0.000 0.000 0.000
80.24
1145.9 1096.5 69.840 602.51
332.49 299.69 46.397 161.70
4.39
84.27
28.63
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
0.000
0.000
0.000
0.000
0.000
0.000
11.556
0.000
2.288
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.778
0.000
1.144
0.000
0.000
0.000
0.000
0.000
0.000
8.171
0.000
1.618
49.970
110.316
601.87
62.264
64.393
17.880
342.032
13.675
7.418
49.970
110.316
601.87
62.264
64.393
17.880
342.032
13.675
7.418
12.587
19.520
334.51
45.958
43.565
21.309
243.658
9.885
4.889
31.278
64.918
468.19
54.111
53.979
19.594
292.845
11.780
6.153
26.434
64.203
189.051
11.530
14.728
2.424
69.561
2.680
1.788
15.64
32.46
234.09
27.06
26.99
9.80
149.31
5.89
3.65
13.22
32.10
94.53
5.77
7.36
1.21
35.02
1.34
1.21
O-7
-------
Table O-l. (Continued)
Test Date 7/9/02 7/10/02 First Two-Day 7/11/02
Sampling Array
Compound
Summer Uncertainty
Campaign
Average
Compo- Compo- Avg. SD 6A 6B Port Port SD 8A 10A Day Day SD
site site Avg Avg
4.396 9.490 7.204 4.75
3.60
Tricosanoic acid
Tetracosanoic acid 0.000 0.000 0.000 0.000 14.584 14.584
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1020.93 298.61 659.77 510.75 10381.0 8219.1 9300.0 1528.7 6411.4 7859.0 7947.4 1193.1 4303.58 648.92
O-8
-------
Table O-2. Quartz Filter Species in PM%
Test Date 7/9/02 7/10/02
First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg)) 40.36
PM emission factor uncertainty 1.27
(mg/kg)
Compound in PM (%)
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene-Peak 1
Methy lanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.01083
0.00000
0.00000
0.00000
0.00000
0.00000
42.67 41.52
2.51 1.63
in PM (%) Avg. in PM (%)
0.00000
0.00278
0.00250
0.00306
0.00667
0.00306
0.00000
0.00566
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00143
0.00129
0.00157
0.00343
0.00157
0.00000
0.00817
0.00000
0.00000
0.00000
0.00000
0.00000
Uncertainty (%)
0.00000
0.00075
0.00071
0.00079
0.00116
0.00079
0.00000
0.00179
0.00000
0.00000
0.00000
0.00000
0.00000
178.02
5.94
in PM (%)
0.00468
0.00113
0.00000
0.00134
0.00237
0.00124
0.00770
0.02200
0.02752
0.07303
0.09269
0.05682
0.04821
Uncertainty (%)
0.00165
0.00145
0.00171
0.00303
0.00158
0.00138
0.00335
0.00223
0.00997
0.01269
0.00709
0.00677
0.00234
0.00128
0.00064
0.00146
0.00290
0.00140
0.00385
0.01509
0.01376
0.03651
0.04635
0.02841
0.02411
0.00082
0.00082
0.00036
0.00094
0.00162
0.00088
0.00069
0.00190
0.00112
0.00498
0.00635
0.00354
0.00339
O-9
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg))
PM emission factor uncertainty
(mg/kg)
Compound
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
te-(2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo [a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
40.36
1.27
in PM (%)
0.00000
0.00000
0.07181
0.00000
0.00000
0.00000
0.00000
0.01223
0.00883
42.67
2.51
in PM (%)
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00655
0.00667
41.52
1.63
Avg. in PM (%) Uncertainty (%)
0.00000 0.00000
0.00000 0.00000
0.03490 0.00374
0.00000 0.00000
0.00000 0.00000
0.00000 0.00000
0.00000 0.00000
0.00931 0.00191
0.00772 0.00174
178.02
5.94
in PM (%) Uncertainty (%)
0.01405 0.00263 0.00702
0.04745 0.00980 0.02373
0.00000 0.00000 0.01745
0.01697 0.01751 0.00848
0.02075 0.01775 0.01038
0.08129 0.07807 0.04065
0.00383 0.00261 0.00191
0.06092 0.00689 0.03512
0.00989 0.00073 0.00881
0.00132
0.00490
0.00187
0.00876
0.00887
0.03904
0.00130
0.00358
0.00095
O-10
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
PM emission factor (mg/kg)) 40.36
PM emission factor uncertainty 1.27
(mg/kg)
Compound in PM (%)
42.67
2.51
41.52
1.63
7/11/02
178.02
5.94
Summer Uncertainty
Campaign (%)
Average
inPM(%) Avg. inPM(%) Uncertainty (%) inPM(%) Uncertainty (%)
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (n-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (n-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane («-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (n-C20)
0.00000
0.00000
0.00000
0.00365
0.00335
0.00593
0.00000
0.01496
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.06049
0.00000
0.00000
0.00000
0.00000
0.00177
0.00163
0.00288
0.03109
0.00727
0.00000
0.00000
0.00000
0.00084
0.00080
0.00107
0.00352
0.00169
0.00103
0.00138
0.00008
0.00694
0.02775
0.03883
0.06989
0.30196
0.00132
0.00277
0.00016
0.00233
0.00820
0.01123
0.01766
0.08310
0.00052
0.00069
0.00004
0.00436
0.01469
0.02085
0.05049
0.15462
0.00066
0.00138
0.00008
0.00124
0.00412
0.00564
0.00901
0.04156
O-ll
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg))
PM emission factor uncertainty
(mg/kg)
Compound
w-Heneicosane («-C21)
w-Docosane («-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awfe/so-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/'so-Tricosane (C23)
anteiso-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
w-Hexacosane («-C25)
/5o-Pentacosane (C25)
anfe/'so-Pentacosane (C26)
Heptacosane (w-C27)
40.36
1.27
in PM (%)
0.00013
0.00000
0.00000
0.10914
0.48986
0.30759
0.24426
0.17516
42.67
2.51
in PM (%)
0.00000
0.00000
0.00000
0.03834
0.00000
0.00000
0.08103
0.13403
41.52
1.63
Avg. in PM (%) Uncertainty (%)
0.00006 0.00016
0.00000 0.00000
0.00000 0.00000
0.07275 0.00537
0.23812 0.01025
0.14952 0.00796
0.16037 0.00802
0.15402 0.00779
178.02
5.94
in PM (%) Uncertainty (%)
0.33129 0.09440 0.16568
0.40863 0.09689 0.20432
0.50305 0.07733 0.25152
0.08798 0.01653 0.08036
0.59002 0.07261 0.41407
0.29115 0.03035 0.22033
0.20057 0.01993 0.18047
0.10879 0.01502 0.13140
0.04720
0.04845
0.03866
0.00869
0.03666
0.01569
0.01074
0.00846
O-12
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg)) 40.36
PM emission factor uncertainty 1.27
(mg/kg)
Compound in PM (%)
/5o-Hexacosane (C26)
anfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/50-Octacosane (C28)
Octacosane (w-C28) 0.13414
Nonacosane (w-C29) 0.09511
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene 0.00000
Indeno[ 1 ,2,3 -c,d]fluoranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30) 0.00000
w-Hentriacontane (n-C31) 0.00000
/5o-Triacontane (C30)
awtewo-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/5o-Dotriacontane (C32)
Dotriacontane (w-C32) 0.00000
Tritriacontane (C33) 0.00000
Tetratriacontane (C34)
42.67 41.52 178.02
2.51 1.63 5.94
inPM(%) Avg. inPM(%) Uncertainty (%) inPM(%) Uncertainty (%)
0.10330 0.11829 0.00682 0.08234 0.01434 0.10031
0.10451 0.09994 0.00627 0.02352 0.00915 0.06173
0.00000 0.00000 0.00000 0.18354 0.06811 0.09177
0.00032 0.00016 0.00025 0.00254 0.00193 0.00135
0.00000 0.00000 0.00000 0.00284 0.00321 0.00142
0.00000 0.00000 0.00000 0.00083 0.00129 0.00041
0.00250 0.00129 0.00071 0.00000 0.00000 0.00064
0.00794
0.00555
0.03406
0.00097
0.00160
0.00064
0.00036
O-13
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg)) 40.36
PM emission factor uncertainty 1.27
(mg/kg)
Compound in PM (%)
/5o-Tritriacontane (C33)
anfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00354
0.00244
0.00000
0.00991
0.00000
0.00000
0.04614
0.09122
42.67 41.52
2.51 1.63
in PM (%) Avg. in PM (%)
0.00361
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00816
0.00828
0.00000
0.00765
0.00000
0.00000
0.04452
0.06613
0.00186
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00591
0.00544
0.00000
0.00875
0.00000
0.00000
0.04530
0.07833
Uncertainty (%)
0.00086
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00153
0.00146
0.00000
0.00186
0.00000
0.00000
0.00422
0.00555
178.02
5.94
in PM (%)
0.00000
0.00702
0.03610
0.00832
0.02578
0.01155
0.01887
0.00845
0.01605
0.01004
0.01173
0.01349
0.00000
0.03590
0.00158
0.04078
0.07188
Uncertainty (%)
0.00000
0.00108
0.00376
0.00101
0.00711
0.00054
0.01040
0.00427
0.00878
0.00064
0.00280
0.00778
0.00000
0.05079
0.00223
0.00141
0.00430
0.00093
0.00351
0.01805
0.00416
0.01289
0.00578
0.00943
0.00422
0.00803
0.00798
0.00859
0.00674
0.00437
0.01795
0.00079
0.04304
0.07511
0.00043
0.00054
0.00188
0.00051
0.00355
0.00027
0.00520
0.00213
0.00439
0.00083
0.00158
0.00389
0.00093
0.02539
0.00112
0.00223
0.00351
O-14
-------
Table O-2. (Continued)
Test Date
7/9/02
7/10/02 First Two-Day
7/11/02
Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg)) 40.36
PM emission factor uncertainty 1.27
(mg/kg)
Compound in PM (%)
1,2-Benzenedicarboxylic acid, 4-
methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
0.53748
0.11754
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.02863
0.00000
0.00567
0.00000
42.67 41.52
2.51 1.63
in PM (%) Avg. in PM (%)
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.26127
0.05714
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.01392
0.00000
0.00276
0.00000
Uncertainty (%)
0.01079
0.00481
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00235
0.00000
0.00104
0.00000
178.02
5.94
in PM (%)
0.61597
0.16834
0.01757
0.03647
0.26300
0.03040
0.03032
0.01101
0.16450
0.00662
0.00346
0.00533
Uncertainty (%)
0.04429
0.02666
0.01486
0.03609
0.10656
0.00656
0.00833
0.00141
0.03946
0.00152
0.00101
0.00405
0.43862
0.11274
0.00879
0.01823
0.13150
0.01520
0.01516
0.00550
0.08921
0.00331
0.00311
0.00267
0.02279
0.01355
0.00743
0.01804
0.05328
0.00328
0.00417
0.00071
0.01976
0.00076
0.00073
0.00203
O-15
-------
Table O-2. (Continued)
Test Date 7/9/02 7/10/02 First Two-Day 7/11/02 Summer Uncertainty
Campaign (%)
Average
PM emission factor (mg/kg)) 40.36 42.67 41.52 178.02
PM emission factor uncertainty 1.27 2.51 1.63 5.94
(mg/kg)
Compound inPM(%) inPM(%) Avg. inPM(%) Uncertainty (%) inPM(%) Uncertainty (%)
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 2.53 0.70 1.59 0.03 5.53 0.69 3.56 0.34
O-16
-------
Table O-3. Campaign #2 Particle-Phase Semivolatiles (July 9, 2002)
Test Date
Substrate
Sample ID
Sampling Position
Number of filters
Punches after OC/EC analysis
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7- Dimethylnaphthalene
1,3- Dimethylnaphthalene
2,6- Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
7/9/02
QF
IB070902HR6&10
Front
4
2
32.860
600.6
44.30
111439
7.40
300
ng/uL ng ng/L us/kg
0.35 110.98 0.00562 4.03
0.38 120.50 0.00611 4.37
IB070902HR2&R4
Backup
4
2
32.716
600.6
44.30
111439
7.40
300
ng/uL ng
0.33 104.64
0.09 28.54
IB070902HD1A1
Dilution
1
1
8.215
600.6
44.30
111439
7.40
300
ng/L ng/uL ng ng/L ug/kg
0.00533 0.81 272.36 0.05520 39.51
0.00145
O-17
-------
Table O-3. (Continued)
Compound
ng/uL ng
ng/L ug/kg
ng/uL
ng
ng/L
ng/uL
ng
ng/L ug/kg
Methylanthracene-Peak 1
Methylanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butylbenzyl phthalate
bis (2- Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
0.21
66.59
0.00339
2.52
3.15
4.40
0.62
0.31
799.07 0.04049
998.84 0.05061
1395.21 0.07069
28.98
36.23
50.60
2.55
3.37
7.88
808.59
1068.60
2498.69
0.04115
0.05438
0.12717
5.15 1731.69 0.35097 251.22
12.26 4122.43 0.83552 598.06
1.90 638.88 0.12949 92.68
196.60
98.30
0.00996
0.00498
7.13
3.57
0.19 60.25 0.00307
O-18
-------
Table O-3. (Continued)
Compound
ng/uL ng
ng/L ug/kg
ng/uL
ng
ng/L
ng/uL
ng
ng/L ug/kg
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
n-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
n-Tetradecane (w-C14)
n-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
0.58
0.66
0.66
1.68
3.38
4.25
8.49
16.94
183.91 0.00932 6.67
209.28 0.01060 7.59
209.28 0.01060
7.59
532.72 0.02699 19.32
1071.77 0.05431 38.87
1347.64 0.06828 48.88
2692.11 0.13641 97.64
5371.54 0.27217 194.82
0.66
0.32
0.45
0.54
0.45
209.28
101.47
142.69
171.23
142.69
0.01065
0.00516
0.00726
0.00871
0.00726
0.22
73.98 0.01499 10.73
1.82
2.42
3.34
7.97
15.27
577.11
767.36
1059.09
2527.23
4842.00
0.02937
0.03905
0.05390
0.12862
0.24643
0.10
0.21
0.27
0.42
33.63 0.00682 4.88
70.61 0.01431 10.24
90.79 0.01840 13.17
141.23 0.02862 20.49
O-19
-------
Table O-3. (Continued)
Compound
ng/uL ng ng/L ug/kg ng/uL ng ng/L ng/uL ng ng/L ug/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]-
acepyrene
Benzanthraquinone
1-Methylchrysene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/5o-Tricosane (C23)
anteiso-Tricosane (C23)
n-Pentacosane (»-C25)
/5o-Tetracosane (C24)
awfe/'so-Tetracosane (C24)
w-Hexacosane (n-C26)
/5o-Pentacosane (C25)
anfe/'so-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awte/5o-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awtewo-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C30)
anteiso-Nonacosane (C30)
Squalene
3.83 1214.46 0.06154 44.05
43.27 13720.59 0.69521 497.63 22.29 7067.99 0.35971 0.87 292.54 0.05929 42.44
25.81 8184.15 0.41469 296.83 13.26 4204.64 0.21399 0.40 134.50 0.02726 19.51
21.11 6693.82 0.33917 242.78 9.02 2860.17 0.14556 0.82 275.73 0.05588 40.00
15.46 4902.25 0.24839 177.80 5.64 1788.40 0.09102 0.86 289.18 0.05861 41.95
14.66 4648.57 0.23554 168.60
6.11 1937.43 0.09817 70.27
5.39 1709.13 0.08698
2.76 875.17 0.04454
1.07 359.79 0.07292 52.20
0.34 107.81 0.00549 2.39 803.64 0.16288 116.59
O-20
-------
Table O-3. (Continued)
Compound
Indeno-[l,2,3-c,d]fhioranthene
Dibenzo[a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awtewo-Triacontane (C30)
iso-Hentriacontane (C31)
awfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
anfe/'so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
anfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
ns/uL
1.13
1.08
0.97
0.63
2.43
0.60
0.56
1.96
0.81
1.00
2.15
0.31
0.51
1.85
ns
358.31
342.46
307.58
198.18
768.95
190.26
178.36
622.29
257.64
317.09
681.75
99.09
162.51
586.62
ns/L
0.01816
0.01735
0.01558
0.01004
0.03896
0.00964
0.00904
0.03153
0.01305
0.01607
0.03454
0.00502
0.00823
0.02972
U2/k2
13.00
12.42
11.16
7.19
27.89
6.90
6.47
22.57
9.34
11.50
24.73
3.59
5.89
21.28
ns/uL
0.98
1.35
1.32
0.22
0.22
0.99
1.15
0.90
0.39
1.88
0.59
1.18
2.16
0.19
0.43
1.86
ns
310.75
428.07
418.56
69.76
69.76
313.13
364.66
285.38
122.87
594.55
186.29
372.58
685.71
59.45
134.76
590.58
ns/L
0.01582
0.02179
0.02130
0.00355
0.00355
0.01594
0.01856
0.01452
0.00625
0.03026
0.00948
0.01896
0.03490
0.00303
0.00686
0.03006
ns/uL
0.17
0.22
0.52
2.40
0.23
0.43
1.94
0.75
0.81
1.34
1.15
ns
57.16
73.98
174.85
807.00
75.66
142.91
651.48
252.19
273.20
449.73
386.69
ns/L
0.01159
0.01499
0.03544
0.16356
0.01533
0.02896
0.13204
0.05111
0.05537
0.09115
0.07837
U2/k2
8.29
10.73
25.37
117.08
10.98
20.73
94.51
36.59
39.63
65.25
56.10
O-21
-------
Table O-3. (Continued)
Compound
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-methyl
1,2,-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
ns/uL
0.88
2.64
0.93
2.96
5.76
0.75
18.86
4.13
2.25
4.76
3.59
34.86
2.86
0.99
2.73
22.49
0.55
0.44
0.44
ns
277.46
836.33
293.31
939.39
1827.24
237.82
5981.15
1308.01
713.46
1510.15
1137.57
11054.63
907.68
313.13
864.08
7130.61
174.40
138.73
138.73
ns/L
0.01406
0.04238
0.01486
0.04760
0.09259
0.01205
0.30306
0.06628
0.03615
0.07652
0.05764
0.56013
0.04599
0.01587
0.04378
0.36130
0.00884
0.00703
0.00703
U2/k2
10.06
30.33
10.64
34.07
66.27
8.63
216.93
47.44
25.88
54.77
41.26
400.94
32.92
11.36
31.34
258.62
6.33
5.03
5.03
ns/uL
0.53
12.40
1.64
1.34
2.55
1.89
1.94
4.33
28.44
1.90
1.21
10.25
0.20
0.24
0.24
ns
166.47
3931.94
519.24
424.11
808.59
598.51
614.37
1371.42
9017.31
602.48
384.47
3250.20
63.42
75.31
75.31
ns/L
0.00847
0.20011
0.02643
0.02158
0.04115
0.03046
0.03127
0.06980
0.45892
0.03066
0.01957
0.16541
0.00323
0.00383
0.00383
ns/uL
121.14
3.41
1.08
1.79
0.93
7.18
0.39
0.41
0.63
2.64
0.14
0.25
ns
40732.48
1147.45
361.47
601.05
311.03
2412.59
130.30
138.70
210.16
886.86
46.23
84.06
ns/L
8.25556
0.23256
0.07326
0.12182
0.06304
0.48898
0.02641
0.02811
0.04259
0.17975
0.00937
0.01704
U2/k2
5909.25
166.47
52.44
87.20
45.12
350.01
18.90
20.12
30.49
128.66
6.71
12.20
O-22
-------
Table O-3. (Continued)
Compound ng/uL ng ng/L ug/kg ng/uL ng ng/L ng/uL ng ng/L ug/kg
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 307.46 97494.0 4.94 3535.98 191.43 60699.4 3.09 177.66 59738.2 12.11 8666.50
O-23
-------
Table O-4. Campaign #2 Particle-Phase Semivolatiles (July 10, 2002)
Test Date
Substrate
Sample ID
Sampling Position
Number of filters
Punches after OC/EC analysis
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 , 3 -Dimethy Inaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
7/10/02
QF
IB071002HR6&10
Residence - Front filter
4
2
32.805
600.67
44.34
115149
7.43
300
ng/uL ng ng/L
0.20 63.42 0.00322
0.10 31.71 0.00161
0.09 28.54 0.00145
0.11 34.88 0.00177
0.24 76.10 0.00386
0.11 34.88 0.00177
0.34 107.81 0.00547
IB071002HR2&R4 IB071002HD1A1
Residence - Backup filter Dilution - Front filter
4 1
2 1
32.516 8.219
600.67 600.67
44.34 44.34
115149 115149
7.43 7.43
290 300
us/kg ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
2.37 0.20 61.30 0.00314 2.31 0.28 94.15 0.01907 14.05
1.19
1.07
1.30
2.85
1.30
4.03 0.14 42.91 0.00220 1.62
O-24
-------
Table O-4. (Continued)
Compound ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
Methylanthracene-Peak 1
Methylanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate 3.30 1046.40 0.05310 39.14 0.48 147.13 0.00753 5.55 4.67 1570.29 0.31806 234.42
Butylbenzyl phthalate 4.36 1382.52 0.07016 51.71 0.69 211.50 0.01083 7.98 5.49 1846.01 0.37390 275.58
bis (2-Ethylhexyl) phthalate 3.82 1211.29 0.06147 45.31 4.26 1305.79 0.06685 49.27 0.97 326.16 0.06606 48.69
Dioctyl phthalate
Fluoranthene
Pyrene 0.46 145.86 0.00740 5.46 0.23 70.50 0.00361 2.66
Chrysene 0.24 76.10 0.00386 2.85
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [bjfluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
O-25
-------
Table O-4. (Continued)
Compound
ng/uL
ng
ng/L ug/kg ng/uL
ng
ng/L ug/kg
ng/uL
ng
ng/L ug/kg
Cholestane 4
ABB -20R-24 S-Methy Icholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14) 0.10
n-Pentadecane («-C15)
w-Hexadecane (w-C16) 0.23
w-Heptadecane (w-C17) 0.53
1-Octadecene
w-Octadecane (w-C18) 0.41
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19) 4.02
w-Eicosane (w-C20) 2.59
w-Heneicosane (w-C21) 3.41
w-Docosane (w-C22) 8.22
n-Tricosane (w-C23) 15.00
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene
31.71 0.00161
1.19
72.93 0.00370 2.73
168.06 0.00853 6.29
130.01 0.00660 4.86
1274.71 0.06469 47.68
821.27 0.04168 30.72
1081.28 0.05487 40.44
2606.50 0.13228 97.49
4756.39 0.24138 177.90
0.08 24.52 0.00126 0.93
0.62 190.04 0.00973 7.17
0.11 33.72 0.00173 1.27
0.31 95.02 0.00487 3.59
0.61 186.98 0.00957 7.06
0.55 168.59 0.00863 6.36
1.63 499.63 0.02558 18.85
2.74 839.87 0.04300 31.69
3.77 1155.59 0.05917 43.61
8.38 2568.66 0.13151 96.93
16.85 5164.91 0.26444 194.90
0.04
0.05
0.07
0.41
0.06
0.08
0.13
0.17
0.30
13.45 0.00272 2.01
16.81 0.00341 2.51
23.54 0.00477 3.51
137.86 0.02792 20.58
20.18 0.00409 3.01
26.90 0.00545 4.02
43.71 0.00885 6.53
57.16 0.01158 8.53
100.88 0.02043 15.06
O-26
-------
Table O-4. (Continued)
Compound
ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1-Methylchrysene
Benzo[a]pyrene
w-Tetracosane («-C24)
/5o-Tricosane (C23)
awtewo-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
n-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awtewo-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C287
awtewo-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (n-C28)
Nonacosane (n-C29)
/5o-Nonacosane (C29)
anteiso-Nonacosane (C29)
Squalene
Indeno [ 1,2,3 -c,d1fluoranthene
3.33 1055.92 0.05359 39.49 2.00 613.05 0.03139 23.13
0.49 150.20 0.00769 5.67
28.27 8964.20 0.45492 335.29 30.85 9456.22 0.48415 356.83 0.59 198.39 0.04018 29.62
18.19 5767.91 0.29271 215.74 16.93 5189.43 0.26569 195.82 0.52 174.85 0.03542 26.10
14.58 4623.21 0.23462 172.92 9.14 2801.62 0.14344 105.72 0.65 218.56 0.04427 32.63
10.41 3300.93 0.16752 123.46 3.56 1091.22 0.05587 41.18 0.50 168.13 0.03405 25.10
9.44 2993.35 0.15191 111.96
3.76 1192.27 0.06051 44.59
2.18 668.22 0.03421 25.22 0.85 285.81 0.05789 42.67
2.08 659.55 0.03347 24.67 5.54 1698.14 0.08694 64.08 0.11 36.99 0.00749 5.52
O-27
-------
Table O-4. (Continued)
Compound
Dibenzo[a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
anfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/'so-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awte/50-Dotriacontane (C32)
Dotriacontane (w-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (n-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
0
1.
1.
0
0
0.
2.
ns/uL
.89
.00
.01
.09
.13
.13
.39
0.18
0.
0.
1
0.
.64
.45
.20
.54
1.65
0
0
1.
0.
.54
.71
.43
.78
ns
282.21
317.09
320.26
28.54
41.22
39.64
757.06
55.49
202.15
142.69
380.51
170.44
523.20
170.44
225.93
451.86
245.75
ns/L
0.01432
0.01609
0.01625
0.00145
0.00209
0.00201
0.03842
0.00282
0.01026
0.00724
0.01931
0.00865
0.02655
0.00865
0.01147
0.02293
0.01247
U2/k2
10.56
11.86
11.98
1.07
1.54
1.48
28.32
2.08
7.56
5.34
14.23
6.37
19.57
6.37
8.45
16.90
9.19
ns/uL
0.25
0.28
0.53
1.05
2.85
0.91
0.54
1.50
0.68
1.11
2.63
0.25
0.43
2.25
0.51
ns
76.63
85.83
162.46
321.85
873.59
279.70
164.76
459.78
206.90
341.01
804.62
76.63
130.27
689.68
157.09
ns/L
0.00392
0.00439
0.00832
0.01648
0.04473
0.01432
0.00844
0.02354
0.01059
0.01746
0.04120
0.00392
0.00667
0.03531
0.00804
U2/k2
2.89
3.24
6.13
12.15
32.97
10.55
6.22
17.35
7.81
12.87
30.36
2.89
4.92
26.03
5.93
ns/uL
0.15
0.20
0.53
1.54
0.10
0.14
0.46
0.34
0.30
0.44
0.38
ns ns/L us/ks
50.44 0.01022 7.53
67.25 0.01362 10.04
178.21 0.03610 26.60
516.98 0.10471 77.18
33.63 0.00681 5.02
46.23 0.00936 6.90
155.52 0.03150 23.22
113.48 0.02299 16.94
100.88 0.02043 15.06
147.11 0.02980 21.96
126.09 0.02554 18.82
O-28
-------
Table O-4. (Continued)
Compound
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-
methyl
1,2,4- Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
ns/uL
1.23
0.48
2.65
5.01
0.34
19.75
5.05
3.95
6.49
4.86
45.20
3.15
0.68
3.40
ns
388.44
150.62
840.29
1589.43
107.02
6262.57
1601.32
1252.51
2057.14
1541.86
14332.5
7
998.84
214.04
1078.11
ns/L
0.01971
0.00764
0.04264
0.08066
0.00543
0.31781
0.08126
0.06356
0.10440
0.07825
0.72735
0.05069
0.01086
0.05471
U2/k2
14.53
5.63
31.43
59.45
4.00
234.24
59.89
46.85
76.94
57.67
536.08
37.36
8.01
40.32
ns/uL
2.26
1.08
2.70
2.26
0.84
3.89
6.89
4.66
48.96
3.04
0.81
2.21
ns
693.51
329.51
827.61
693.51
256.71
1191.61
2111.17
1429.16
15008.11
931.06
249.05
678.18
ns/L
0.03551
0.01687
0.04237
0.03551
0.01314
0.06101
0.10809
0.07317
0.76840
0.04767
0.01275
0.03472
U2/k2
26.17
12.43
31.23
26.17
9.69
44.97
79.67
53.93
566.33
35.13
9.40
25.59
ns/uL
77.05
8.41
3.79
1.29
2.19
1.99
8.96
0.38
0.33
1.05
ns
25908.06
2828.70
1273.55
432.92
735.55
668.30
3013.64
126.09
109.28
353.06
ns/L
5.24758
0.57294
0.25795
0.08769
0.14898
0.13536
0.61040
0.02554
0.02213
0.07151
U2/k2
3867.62
422.28
190.12
64.63
109.80
99.77
449.88
18.82
16.31
52.71
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
21.83 6920.54 0.35121 258.85 15.74
0.58 182.33 0.00925 6.82 0.34
0.48 150.62 0.00764 5.63 0.44
0.79 249.71 0.01267 9.34 0.64
4823.90 0.24698 182.03 2.41
103.45 0.00530 3.90 0.09
134.10 0.00687 5.06 0.08
195.41 0.01000 7.37 0.21
811.20 0.16431 121.10
29.42 0.00596 4.39
25.22 0.00511 3.76
71.45 0.01447 10.67
O-29
-------
Table O-4. (Continued)
Compound ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 277.56 88012.15 4.47 3291.92 224.85 68921.61 3.53 2600.77 128.72 43282.10 8.77 6461.26
O-30
-------
Table O-5. Campaign #2 Particle-Phase Semivolatiles (July 11, 2002)
Test Date: July 11,2002
Substrate: Quartz Filter
Sample ID
Sampling Position
Number of filters
Punches after OC/EC analysis
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow Opm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
IB071102HR6A1
Residence - Front filter
1
1
8.276
600
44.91
120926
7.43
290
ns/uL ns ns/L
0.29 94.26 0.01898
IB071102HR6B1
Residence - Front filter
1
0
8.276
600
44.91
120926
7.43
310
us/ks ns/uL ns
14.88 0.15 46.50
0.11 34.10
0.13 40.30
0.23 71.30
0.12 37.20
ns/L us/ks
0.00936 7.34
0.00687 5.38
0.00812 6.36
0.01436 11.26
0.00749 5.87
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l DimethyIphenanthrenes
Anthracene
0.37
0.93
1.03
120.27 0.02422 18.99
302.29 0.06088 47.73
334.79 0.06743 52.86
0.39
1.04
1.06
120.90 0.02435 19.09
322.40 0.06493 50.91
328.60 0.06618 51.88
O-31
-------
Table O-5. (Continued)
Compound
Methylanthracene-Peak 1
Methylanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butylbenzyl phthalate
bis (2-Ethylhexyl) phthalate
Dioctylphthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo[a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
ns/uL
2.66
3.23
2.09
1.78
0.69
1.81
2.85
2.27
2.85
0.15
2.28
0.35
ns
864.61
1049.88
679.34
578.57
224.28
588.33
926.37
737.84
926.37
48.76
741.10
113.76
ns/L
0.17413
0.21144
0.13681
0.11652
0.04517
0.11849
0.18657
0.14860
0.18657
0.00982
0.14925
0.02291
U2/k2
136.52
165.77
107.26
91.35
35.41
92.89
146.27
116.50
146.27
7.70
117.02
17.96
ns/uL
3.01
3.87
2.31
1.99
0.79
2.29
0.61
0.55
6.87
0.21
2.38
0.38
ns
933.10
1199.70
716.10
616.90
244.90
709.90
189.10
170.50
2129.70
65.10
737.80
117.80
ns/L
0.18792
0.24161
0.14422
0.12424
0.04932
0.14297
0.03808
0.03434
0.42891
0.01311
0.14859
0.02372
U2/k2
147.33
189.43
113.07
97.41
38.67
112.09
29.86
26.92
336.27
10.28
116.50
18.60
O-32
-------
Table O-5. (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (n-CIT)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methylnonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
0.10
0.48
0.14
0.68
1.92
2.97
5.34
19.85
20.51
24.05
24.65
156.02
45.51
221.03
624.08
965.37
1735.72
6452.08
6666.60
7817.25
8012.28
0.03142
0.00916
0.04451
0.12569
0.19442
0.34956
1.29941
1.34262
1.57435
1.61363
24.63
7.19
34.90
98.54
152.43
274.06
1018.76
1052.63
1234.31
1265.11
0.12
0.73
2.10
3.41
6.19
22.54
23.16
27.50
28.22
31.00
37.20
226.30
651.00
1057.10
1918.90
6987.40
7179.60
8525.00
8748.20
0.00624
0.00749
0.04558
0.13111
0.21289
0.38646
1.40722
1.44593
1.71689
1.76184
4.89
5.87
35.73
102.79
166.91
302.99
1103.28
1133.63
1346.06
1381.31
O-33
-------
Table O-5. (Continued)
Compound
ng/uL
ng ng/L ug/kg
ng/uL
ng
ng/L ug/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane («-C24)
/5o-Tricosane (C24)
awte/5o-Tricosane (C24)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
anfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
anteiso-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d1fluoranthene
4.37
25.55
11.78
8.17
5.14
4.68
1.90
1.56
1420.43 0.28607 224.28
8304.81 1.67254 1311.30
3828.99 0.77114 604.58
2655.59 0.53482 419.31
1670.71 0.33647 263.80
1521.20 0.30636 240.19
617.58 0.12438 97.51
507.07 0.10212 80.06
4.01
28.33
12.86
8.68
4.94
3.98
1.48
15.44
1243.10 0.25035 196.28
8782.30
1.76871 1386.69
3986.60 0.80288 629.47
2690.80 0.54191 424.87
1531.40 0.30842 241.80
1233.80 0.24848 194.81
458.80 0.09240 72.44
4786.40 0.96395 755.75
O-34
-------
Table O-5. (Continued)
Compound
/'so-Triacontane (C30)
anfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/50-Dotriacontane (C32)
Dotriacontane (w-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (n-C36)
Tetracontane (C40)
ng/uL
ng
ng/L
ug/kg
ng/uL
0.75
243.78 0.04910
0.56
ng
173.60
ng/L
0.03496
ug/kg
Dibenzo [a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
0.43
0.52
139.77
169.02
0.02815
0.03404
22.07
26.69
0.28
0.35
86.80
108.50
0.01748
0.02185
13.71
17.13
27.41
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
0.38
2.66
0.58
1.23
1.43
1.30
1.04
2.16
0.39
0.48
1.86
121.89
865.42
186.90
398.18
463.18
422.55
337.23
702.90
125.95
154.39
605.39
0.02455
0.17429
0.03764
0.08019
0.09328
0.08510
0.06792
0.14156
0.02537
0.03109
0.12192
19.25
136.65
29.51
62.87
73.14
66.72
53.25
110.99
19.89
24.38
95.59
0.55
2.91
0.54
1.19
1.29
1.25
0.83
2.48
0.40
0.55
2.14
170.50
902.88
166.63
368.13
399.13
387.50
255.75
767.25
124.00
170.50
662.63
0.03434
0.18183
0.03356
0.07414
0.08038
0.07804
0.05151
0.15452
0.02497
0.03434
0.13345
26.92
142.56
26.31
58.13
63.02
61.18
40.38
121.15
19.58
26.92
104.63
O-35
-------
Table O-5. (Continued)
Compound
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-
methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
ns/uL
3.03
1.20
1.58
2.65
1.06
20.70
5.20
2.80
5.95
2.24
22.99
1.98
1.93
0.91
9.48
0.34
0.21
0.54
ns
983.25
390.05
511.94
861.36
345.36
6728.36
1690.22
910.12
1934.00
727.28
7471.90
641.96
625.71
296.60
3079.77
109.70
69.07
174.71
ns/L
0.19802
0.07855
0.10310
0.17347
0.06955
1.35505
0.34040
0.18329
0.38950
0.14647
1.50480
0.12929
0.12601
0.05973
0.62025
0.02209
0.01391
0.03519
U2/k2
155.25
61.59
80.83
136.01
54.53
1062.38
266.88
143.70
305.37
114.83
1179.78
101.36
98.80
46.83
486.28
17.32
10.91
27.59
ns/uL
0.85
1.90
3.34
0.81
21.13
4.78
5.04
8.95
6.89
33.64
2.70
2.05
3.65
11.20
0.55
0.39
1.44
ns
263.50
589.00
1034.63
251.88
6548.75
1480.25
1561.63
2774.50
2135.13
10427.63
837.00
635.50
1131.50
3472.00
170.50
120.13
445.63
ns/L
0.05307
0.11862
0.20837
0.05073
1.31888
0.29811
0.31450
0.55877
0.43000
2.10007
0.16857
0.12799
0.22788
0.69924
0.03434
0.02419
0.08975
U2/k2
41.61
93.00
163.36
39.77
1034.02
233.73
246.57
438.08
337.13
1646.48
132.16
100.34
178.66
548.22
26.92
18.97
70.36
O-36
-------
Table O-5. (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total
289.32
94041.06 18.94
14848.72
346.87
107529.7
21.66
16978.52
O-37
-------
Table O-6. Campaign #2 Particle-Phase Semivolatiles (July 11, 2002)
Test Date: July 11,2002
Substrate: Quartz Filter
IB071102HR8A1
Residence - Front filter
Sample ID
Sampling Position
Number of Filters
Punches after OC/EC analysis
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (nL)
Compound
1
1
8.239
600
44.91
120926
7.43
300
ng/uL
ng
ng/L
ug/kg
IB071102HR10A1
Residence - Front filter
1
1
8.239
600
44.91
120926
7.43
290
ng/uL ng ng/L
ug/kg
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1-Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
0.16
53.80
0.01088
0.27
87.76
0.01775
13.92
0.29
97.51
0.01973
15.46
0.28
91.01
0.01841
14.43
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
0.79
0.86
265.64
289.18
0.05373
0.05850
42.13
45.86
0.75
0.89
243.78
289.29
0.04931
0.05852
38.66
45.88
O-38
-------
Table O-6. (Continued)
Compound
Methylanthracene-Peak 1
Methylanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutylphthalate
Butylbenzylphthalate
Bis-2-Ethylhexylphthalate
Dioctylphthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
ns/uL
2.22
2.73
1.69
1.44
0.59
1.51
1.67
1.81
1.00
0.15
2.04
0.33
ns
746.48
917.96
568.26
484.20
198.39
507.74
561.54
608.61
336.25
50.44
685.95
110.96
ns/L
0.15100
0.18569
0.11495
0.09795
0.04013
0.10271
0.11359
0.12311
0.06802
0.01020
0.13876
0.02245
U2/k2
118.39
145.58
90.12
76.79
31.46
80.52
89.06
96.52
53.33
8.00
108.79
17.60
ns/uL ns
2.18 708.59
2.86 929.62
1.77 575.32
1.45 471.31
0.56 182.02
1.48 481.06
0.75 243.78
0.76 247.03
1.21 393.30
1.78 578.57
0.31 100.76
ns/L
0.14334
0.18805
0.11638
0.09534
0.03682
0.09731
0.04931
0.04997
0.07956
0.11704
0.02038
U2/k2
112.38
147.43
91.24
74.75
28.87
76.29
38.66
39.18
62.37
91.76
15.98
O-39
-------
Table O-6. (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
n-Decane (n-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
n-Tetradecane (w-C14)
n-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (n-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
n-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
0.11
0.62
1.61
2.83
4.83
18.90
19.41
22.07
22.78
36.99
208.48
541.36
951.59
1624.09
6355.13
6526.61
7421.04
7659.78
0.00748
0.04217
0.10951
0.19249
0.32853
1.28554
1.32023
1.50115
1.54945
5.87
33.06
85.86
150.92
257.57
1007.88
1035.08
1176.93
1214.79
0.09
0.52
1.39
2.36
4.53
15.02
14.81
18.62
20.87
29.25
169.02
451.81
767.10
1472.44
4882.13
4813.87
6052.28
6783.62
0.00592
0.03419
0.09139
0.15517
0.29785
0.98757
0.97377
1.22428
1.37222
4.64
26.81
71.65
121.66
233.52
774.27
763.45
959.85
1075.84
O-40
-------
Table O-6. (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/so-Tricosane (C23)
awtewo-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
n-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awtewo-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awfe/so-Hexacosane (C26)
/5o-Heptacosane (C27)
awtewo-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (n-C28)
Nonacosane (n-C29)
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d1fluoranthene
4.21
23.29
10.72
7.25
.90
3.55
1.14
5.72
1415.61 0.28636 224.51
7831.26 1.58414 1241.99
3604.60 0.72915 571.67
2437.81 0.49313 386.62
1311.38 0.26527 207.98
1193.69
383.33
0.24146
0.07754
189.31
60.79
1250.85 0.25303 198.38
3.05
3.25
1.05
991.38 0.20054
21.52 6994.90 1.41495
10.02 3256.92 0.65882
6.87 2233.04 0.45171
4.03 1309.92 0.26497
1056.39
341.29
0.21369
0.06904
7.06 2294.79 0.46420
157.23
1109.34
516.53
354.14
207.74
167.54
54.13
363.94
O-41
-------
Table O-6. (Continued)
Compound
/'so-Triacontane (C30)
awfe/so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/5o-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
0.58
195.03
0.03945
30.93
0.57
185.27
0.03748
ug/kg
Dibenzo [a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
0.24
0.26
80.70
87.43
0.01632
0.01768
12.80
13.87
0.22
0.20
71.51
65.01
0.01447
0.01315
11.34
10.31
29.38
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
0.56
2.85
0.50
1.06
1.05
1.00
0.74
1.51
0.48
0.43
1.30
189.14
958.31
168.13
357.27
353.06
336.25
247.98
508.58
159.72
142.91
437.13
0.03826
0.19385
0.03401
0.07227
0.07142
0.06802
0.05016
0.10288
0.03231
0.02891
0.08842
30.00
151.98
26.66
56.66
55.99
53.33
39.33
80.66
25.33
22.66
69.33
0.43
2.83
0.53
0.88
1.44
0.79
0.83
1.73
0.41
0.34
1.48
138.14
918.24
170.65
284.41
467.25
255.97
268.16
560.70
134.08
109.70
479.44
0.02794
0.18575
0.03452
0.05753
0.09452
0.05178
0.05424
0.11342
0.02712
0.02219
0.09698
21.91
145.63
27.06
45.11
74.10
40.60
42.53
88.92
21.26
17.40
76.04
O-42
-------
Table O-6. (Continued)
Compound
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
ns/uL
1.63
0.86
1.61
2.74
0.73
19.98
5.64
2.04
4.08
1.25
16.74
1.58
7.31
0.25
0.13
0.28
ns
546.41
290.02
542.20
920.48
243.78
6716.59
1895.61
685.11
1370.22
420.31
5627.98
529.59
2458.83
84.06
42.03
92.47
ns/L
0.11053
0.05867
0.10968
0.18620
0.04931
1.35866
0.38345
0.13859
0.27717
0.08502
1.13845
0.10713
0.49738
0.01700
0.00850
0.01870
U2/k2
86.66
45.99
85.99
145.98
38.66
1065.21
300.63
108.65
217.31
66.66
892.56
83.99
389.95
13.33
6.67
14.66
ns/uL
0.33
0.80
1.55
2.81
0.71
22.53
6.45
2.06
4.16
2.09
17.70
1.65
1.51
0.98
7.53
0.26
0.16
0.34
ns
105.64
260.03
503.81
914.18
231.59
7321.56
2096.52
670.40
1352.99
678.52
5753.24
536.32
491.63
316.92
2445.94
85.32
52.82
109.70
ns/L
0.02137
0.05260
0.10191
0.18492
0.04685
1.48103
0.42409
0.13561
0.27369
0.13725
1.16379
0.10849
0.09945
0.06411
0.49477
0.01726
0.01068
0.02219
U2/k2
16.75
41.24
79.90
144.98
36.73
1161.15
332.49
106.32
214.57
107.61
912.42
85.06
77.97
50.26
387.91
13.53
8.38
17.40
O-43
-------
Table O-6. (Continued)
Compound ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 249.59 83923.80 16.98 13309.75 238.61 77559.00 15.69 12300.34
O-44
-------
Table O-7. Campaign #2 Particle-Phase Semivolatiles (July 11, 2002)
Test Date: July 11,2002
Substrate: Quartz Filter
IB071102HR2&R4
Residence - Backup filter
Sample ID
Sampling Position
Number of Filters
Punches after OC/EC Analysis
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue Gas Flow (1pm)
Fuel (kg/min)
Volume
Compound
4
2
32.668
600
44.91
120926
7.43
300
ng/uL
ng
ng/L
ug/kg
IB071002HD1A1
Dilution - Front filter
1
1
8.203
600
44.91
120926
7.43
270
ng/uL ng ng/L
ug/kg
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
0.15 47.56 0.00243
1.90
0.26 82.44 0.00421
0.48 152.20 0.00777
3.30
6.09
O-45
-------
Table O-7 (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Methylanthracene-Peak 1
Methylanthracene-Peak 2
Methylanthracene-Peak 3
Methylanthracene-Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutylphthalate
Butylbenzylphthalate
Bis-2-Ethylhexylphthalate
Dioctylphthalate
Fluoranthene
Pyrene
Chrysene
Benzo [a] anthracene
Benzo [k]fluoranthene
Benzo [bjfluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
1.52
3.89
0.71
0.66
2.50
0.32
0.11
1.19
0.12
481.98
1233.49
225.14
209.28
792.73
101.47
34.88
377.34
38.05
0.02459
0.06293
0.01149
0.01068
0.04044
0.00518
0.00178
0.01925
0.00194
19.28
49.34
9.01
8.37
31.71
4.06
1.40
15.09
1.52
0.58 175.52 0.03566 27.96
0.42 127.10 0.02582 20.25
0.28 84.74 0.01722 13.50
O-46
-------
Table O-7 (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
n-Tridecane (n-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (»-C15)
w-Hexadecane (w-C16)
n-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
n-Nonadecane (n-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (n-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
ante/5o-Docosane (C22)
Pyrene
0.39
0.17
1.15
3.22
6.36
11.53
35.14
32.31
36.08
26.75
123.67
53.91
364.66
1021.04
2016.71
3656.07
11142.62
10245.25
11440.69
8482.22
0.00631
0.00275
0.01860
0.05209
0.10289
0.18653
0.56848
0.52270
0.58369
0.43275
4.95
2.16 0.08
14.59 0.12
40.84
80.67
146.24
445.70 0.07
409.80 0.14
457.62 0.17
339.28 0.29
24.21 0.00492 3.86
36.32 0.00738 5.78
21.18 0.00430 3.37
42.37 0.00861 6.75
51.45 0.01045 8.20
87.76 0.01783 13.98
O-47
-------
Table O-7 (Continued)
Compound
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
ug/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1-Methylchrysene
Benzo[a]pyrene
w-Tetracosane («-C24)
/5o-Tricosane (C23)
anteiso-Tricosane (C23)
w-Pentacosane (n-C25)
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24)
w-Hexacosane (n-C26)
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (n-C27)
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awtewo-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (n-C29)
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene
Indeno [ 1,2,3 -c,d1fluoranthene
3.19 1011.52 0.05161 40.46
15.67 4968.84 0.25350 198.75
3.71 1176.41 0.06002 47.06
1.51 478.81 0.02443 19.15
0.85 269.53 0.01375 10.78
1.21 383.68 0.01957 15.35
0.66 209.28 0.01068 8.37
6.71 2127.69 0.10855 85.11
0.47
0.38
0.43
0.48
0.63
0.37
0.54
142.23 0.02890 22.66
115.00 0.02337
18.32
130.13 0.02644 20.73
145.26 0.02951
23.14
190.65
111.97
0.03874
0.02275
163.42 0.03320
30.37
17.84
26.03
O-48
-------
Table O-7 (Continued)
Compound
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
anfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane (n-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
ng/uL
ng
ng/L
ug/kg
ng/uL
ng
ng/L
0.58
0.04
183.91
12.68
0.00938
0.00065
7.36
0.51
0.46
139.21
0.02828
ug/kg
Dibenzo[a,e]pyrene
n-Triacontane (w-C30)
w-Hentriacontane (w-C31)
0.21
0.25
66.59
79.27
0.00340
0.00404
2.66
3.17
0.14
0.16
42.37
48.42
0.00861
0.00984
6.75
7.71
22.18
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
0.64
1.50
1.06
0.64
2.19
0.78
1.69
4.49
0.21
3.88
202.15
475.64
336.91
202.15
693.64
245.75
535.09
1422.95
67.38
1228.73
0.01031
0.02427
0.01719
0.01031
0.03539
0.01254
0.02730
0.07260
0.00344
0.06269
8.09
19.03
13.48
8.09
27.75
9.83
21.40
56.92
2.70
49.15
1.20
0.53
0.21
0.24
0.30
0.26
363.15
158.88
64.31
71.87
90.79
79.44
0.07378
0.03228
0.01307
0.01460
0.01845
0.01614
57.85
25.31
10.24
11.45
14.46
12.65
O-49
-------
Table O-7 (Continued)
Compound
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
ns/uL
2.16
4.41
0.61
0.99
4.89
1.20
6.01
9.25
8.59
35.11
2.51
2.71
1.48
7.76
0.29
0.28
0.55
ns
685.71
1399.17
194.22
313.13
1549.79
380.51
1906.52
2933.10
2723.03
11133.90
796.69
860.11
467.71
2461.43
91.16
87.20
174.40
ns/L
0.03498
0.07138
0.00991
0.01598
0.07907
0.01941
0.09727
0.14964
0.13892
0.56803
0.04065
0.04388
0.02386
0.12558
0.00465
0.00445
0.00890
U2/k2
27.43
55.97
7.77
12.52
61.99
15.22
76.26
117.32
108.92
445.35
31.87
34.40
18.71
98.46
3.65
3.49
6.98
ns/uL ns ns/L us/ks
0.36 109.70 0.02229 17.47
1.61 487.98 0.09915 77.73
0.36 109.70 0.02229 17.47
2.75 832.22 0.16909 132.57
0.15 45.39 0.00922 7.23
0.21 64.31 0.01307 10.24
0.95 287.49 0.05841 45.80
0.13 37.83 0.00769 6.03
O-50
-------
Table O-7 (Continued)
Compound ng/uL ng ng/L ug/kg ng/uL ng ng/L ug/kg
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 305.46 96859.82 4.94 3874.32 15.47 4682.37 0.95 745.88
O-51
-------
Appendix P
Individual Gas-Phase (PUF) Semivolatile Organic Compounds
-------
Table P-l. PUF Species Emission Factors (mg/kg)
Test Date
Sampling Array 6A 6B 8A
Compound
July 9, 2002
8B 10A 10B
Day Avg SD
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo [a]anthracene
B enzo [k] fluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[ 1 ,2,3 -cd]pyrene
0.000
0.107
0.593
2.918
1.979
3.708
3.272
4.086
3.217
0.053
0.000
0.581
1.558
1.132
0.354
1.552
0.098
0.000
0.000
3.892
1.139
0.839
0.000
3.587
0.356
3.837
2.224
0.000
0.151
0.000
0.223
0.062
0.104
0.000
0.000
0.000
0.055
0.401
2.334
1.533
2.842
2.234
3.008
2.100
0.075
0.000
0.606
0.874
1.037
0.228
1.363
0.125
0.000
1.561
1.777
0.972
0.792
0.000
1.828
0.290
2.353
1.682
0.000
0.107
0.077
0.000
0.042
0.125
0.008
0.000
0.000
0.000
0.401
1.836
1.247
2.493
1.880
2.563
1.799
0.026
0.000
0.587
0.164
0.734
0.704
1.032
0.137
0.000
1.133
1.370
0.728
0.573
0.000
1.663
0.343
1.811
1.262
0.000
0.050
0.174
0.006
0.074
0.137
0.000
0.004
0.000
0.000
0.018
0.490
2.200
1.473
2.860
2.147
2.907
2.067
0.061
0.000
0.612
0.742
1.074
0.428
1.392
0.135
0.000
1.542
1.791
0.968
0.793
0.000
1.968
0.314
2.468
1.908
0.000
0.062
0.084
0.000
0.074
0.080
0.090
0.004
0.000
0.000
0.032
0.077
0.319
0.202
0.377
0.235
0.306
0.254
0.031
0.000
0.028
0.524
0.360
0.247
0.376
0.009
0.000
0.400
0.428
0.237
0.220
0.000
0.394
0.027
0.721
0.784
0.000
0.041
0.087
0.018
0.050
0.078
0.004
0.000
P-l
-------
Table P-l. (Continued)
Test Date
Sampling Array
Compound
6A
6B
8A
July 9, 2002
8B 10A 10B
Day Avg SD
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (n-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane («-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
ante/5o-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
0.000
0.660
0.319
0.000
0.941
3.395
8.528
7.715
0.000
4.813
0.000
0.000
3.251
3.346
2.823
2.511
3.126
0.005
0.246
0.231
0.391
0.816
2.524
6.001
4.998
0.000
3.537
0.000
0.000
2.618
2.526
2.456
2.171
2.345
0.069 0.067
0.000
0.190
0.222
0.285
0.709
2.078
4.944
3.919
0.000
3.299
0.000
0.000
2.846
2.241
2.131
2.165
1.978
0.002
0.242
0.228
0.376
0.828
2.542
6.005
5.418
0.000
3.904
0.000
0.000
3.219
2.793
2.687
2.531
2.434
0.003
0.050
0.005
0.084
0.125
0.474
1.062
1.748
0.000
0.851
0.000
0.000
0.852
0.566
0.701
0.629
0.5.6
0.065
0.071
0.008
P-2
-------
Table P-l. (Continued)
Test Date July 9,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compound
1 -Methy Ichry sene
Benzo[a]pyrene 1.376 0.985 0.882 1.081 0.261
w-Tetracosane (w-C24)
/'so-Tricosane (C23)
ante/5-o-Tricosane (C23) 0.798 0.484 0.592 0.625 0.160
w-Pentacosane (w-C25)
/5o-Tetracosane (C24)
awte/50-Tetracosane (C24) 0.567 0.340 0.417 0.441 0.115
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/50-Pentacosane (C25) 0.434 0.256 0.370 0.353 0.090
Heptacosane (n-C27)
/5o-Hexacosane (C26)
awte/50-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/50-Heptacosane (C27)
/5o-Octacosane (C28)
awte/50-Octacosane (C28) 0.598 0.307 0.320 0.408 0.164
Octacosane (w-C28) 0.528 0.229 0.282 0.346 0.160
Nonacosane (w-C29)
/5o-Nonacosane (C29)
awtewo-Nonacosane (C29) 0.000 0.000 0.000 0.000 0.000
Squalene
Indeno[l,2,3-c,d]fluoranthene
Dibenzo[a,e]pyrene 2.909 1.167 1.226 1.767 0.989
w-Triacontane (w-C30) 1.239 1.066 1.100 1.135 0.092
w-Hentriacontane (n-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/50-Dotriacontane (C32) 1.370 0.557 0.572 0.833 0.465
Dotriacontane (w-C32) 0.837 0.320 0.301 0.486 0.304
Tritriacontane (C33) 1.127 0.444 0.402 0.658 0.407
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35) 1.193 0.650 0.667 0.837 0.309
Hexatriacontane (w-C36) 0.000 0.000 0.000 0.000 0.000
Tetracontane (C40) 0.472 0.268 0.130 0.290 0.172
0.000 0.000 0.000 0.000 0.000
P-3
-------
Table P-l. (Continued)
Test Date
Sampling Array
Compound
6A
6B
8A
July 9, 2002
8B 10A 10B
Day Avg SD
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
0.433
0.022
0.528
0.000
0.350
0.372
0.249
0.324
0.355
0.000
0.450
0.000
0.284
0.209
0.147
0.000
0.110
0.000
0.310
0.000
0.300
0.640
0.620
0.000
0.298
0.007
0.428
0.000
0.311
0.408
0.340
0.108
0.171
0.013
0.113
0.000
0.035
0.218
0.251
0.187
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.816
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.272
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.471
0.000
0.000
0.000
P-4
-------
Table P-l. (Continued)
Test Date July 9,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compound
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid 101.26 83.22 93.27 80.30 89.51 9.60
P-5
-------
Table P-2. PUF Species Emission Factors (mg/kg)
Test Date July 10, 2002
Sampling Array 6A 6B 8A 8B 10A 10B
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
0.000
0.000
0.542
2.431
1.638
3.246
2.326
3.149
2.304
0.083
0.000
0.642
1.187
1.451
0.353
1.782
0.144
0.000
1.933
2.226
1.202
1.014
0.000
2.413
0.311
3.240
2.780
0.000
0.028
0.000
0.034
0.062
0.144
0.000
0.000
0.000
0.055
0.527
2.334
1.533
2.842
2.234
3.008
2.100
0.075
0.000
0.606
0.874
1.037
0.228
1.363
0.125
0.000
1.561
1.777
0.972
0.792
0.000
1.828
0.290
2.353
1.682
0.000
0.107
0.077
0.000
0.042
0.125
0.008
0.000
0.000
0.000
0.401
1.836
1.247
2.493
1.880
2.563
1.799
0.026
0.000
0.587
0.164
0.734
0.704
1.032
0.137
0.000
1.133
1.370
0.728
0.573
0.000
1.663
0.343
1.811
1.262
0.000
0.050
0.174
0.006
0.074
0.137
0.000
0.004
0.000
Day Avg
0.000
0.018
0.490
2.200
1.473
2.860
2.147
2.907
2.067
0.061
0.000
0.612
0.742
1.074
0.428
1.392
0.135
0.000
1.542
1.791
0.968
0.793
0.000
1.968
0.314
2.468
1.908
0.000
0.062
0.084
0.000
0.074
0.080
0.090
0.004
0.000
SD
0.000
0.032
0.077
0.319
0.202
0.377
0.235
0.306
0.254
0.031
0.000
0.028
0.524
0.360
0.247
0.376
0.009
0.000
0.400
0.428
0.237
0.220
0.000
0.394
0.027
0.721
0.784
0.000
0.041
0.087
0.018
0.050
0.078
0.004
0.000
P-6
-------
Table P-2. (Continued)
Test Date
Sampling Array
Compound
6A
6B
8A
July 10, 2002
8B 10A
10B Day Avg SD
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (n-C14)
n-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
n-Nonadecane (n-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methy Ifluoranthene
Retene
0.000
0.289
0.232
0.451
0.959
3.025
7.069
7.338
0.000
4.877
0.000
0.000
4.194
3.433
3.474
3.257
2.979
0.005
0.246
0.231
0.391
0.816
2.524
6.001
4.998
0.000
3.537
0.000
0.000
2.618
2.526
2.456
2.171
2.345
0.080
0.067
0.000
0.190
0.222
0.285
0.709
2.078
4.944
3.919
0.000
3.299
0.000
0.000
2.846
2.421
2.131
2.165
1.978
0.002
0.242
0.228
0.376
0.828
2.542
6.005
5.418
0.000
3.904
0.000
0.000
3.219
2.793
2.687
2.531
2.434
0.003
0.050
0.005
0.084
0.125
0.474
1.062
1.748
0.000
0.851
0.000
0.000
0.852
0.556
0.701
0.629
0.506
0.065
0.071 0.008
P-7
-------
Table P-2. (Continued)
Test Date July 10,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compound
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene 1.376 0.985 0.882 1.081 0.261
n-Tetracosane (w-C24)
/'so-Tricosane (C23)
awtewo-Tricosane (C23) 0.798 0.484 0.592 0.625 0.160
w-Pentacosane (w-C25)
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24) 0.567 0.340 0.417 0.441 0.115
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/50-Pentacosane (C25) 0.434 0.256 0.370 0.353 0.090
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awte/5o-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/50-Octacosane (C28) 0.598 0.307 0.320 0.408 0.164
Octacosane (w-C28) 0.528 0.229 0.282 0.346 0.160
Nonacosane (n-C29)
/5o-Nonacosane (C29)
awtewo-Nonacosane (C29) 0.000 0.000 0.000 0.000 0.000
Squalene
Indeno[l,2,3-c,d]fhioranthene
Dibenzo[a,e]pyrene 2.909 1.167 1.226 1.767 0.989
n-Triacontane (n-C30) 1.239 1.066 1.100 1.135 0.092
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awtewo-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32) 1.370 0.557 0.572 0.833 0.465
Dotriacontane (w-C32) 0.837 0.320 0.301 0.486 0.304
Tritriacontane (C33) 1.127 0.444 0.402 0.658 0.407
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awfe/'so-Tritriacontane (C33)
Pentatriacontane (C35) 1.193 0.650 0.667 0.837 0.309
P-8
-------
Table P-2. (Continued)
Test Date
Sampling Array
Compound
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
6A
6B
July 10, 2002
8A 8B 10A
10B Day Avg SD
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
0.000
0.472
0.433
0.022
0.528
0.000
0.350
0.372
0.249
0.324
0.000
0.268
0.355
0.000
0.450
0.000
0.284
0.209
0.147
0.000
0.000
0.13
0.11
0.00
0.31
0.00
0.30
0.64
0.62
0.00
0.000
0.290
0.298
0.007
0.428
0.000
0.311
0.408
0.340
0.108
0.000
0.172
0.171
0.013
0.113
0.000
0.035
0.218
0.251
0.187
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.816
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.272
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.471
0.000
0.000
0.000
P-9
-------
Table P-2. (Continued)
Test Date July 10,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compound
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid 94.05 70.00 62.23 75.43 16.59
Triacontanoic acid
P-10
-------
Table P-3. PUF Species Emission Factors (mg/kg)
Test Date
Sampling Array
Comnounds
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[ 1 ,2,3 -cd]pyrene
6A
0.000
0.066
1.369
8.123
5.471
4.974
1.849
5.489
3.575
0.015
0.326
0.093
0.000
0.000
0.000
1.167
0.000
0.009
0.000
0.000
0.000
0.000
0.206
2.155
0.348
1.220
0.035
0.363
0.085
0.000
0.000
0.227
0.000
0.000
0.000
6B
0.000
0.000
0.483
3.483
2.606
2.507
1.526
2.801
1.202
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.679
0.265
0.734
0.010
0.000
0.013
0.000
0.121
0.000
0.000
0.000
0.000
July 7, 2002
8A 8B 10A
0.000
0.106
1.273
7.401
5.107
5.132
4.623
5.746
3.512
0.047
0.000
0.541
1.092
1.489
0.223
1.047
0.303
0.000
1.303
1.564
0.957
0.612
0.163
10.104
0.385
7.057
6.709
0.000
0.314
0.000
0.000
0.113
0.000
0.000
0.000
10B Day Avg
0.0000
0.057
1.042
6.335
4.395
4.204
2.666
4.679
2.763
0.021
0.109
0.212
0.364
0.496
0.074
0.738
0.101
0.003
0.434
0.521
0.319
0.204
0.123
4.646
0.333
3.004
2.251
0.121
0.137
0.000
0.040
0.114
0.000
0.000
0.000
SD
0.000
0.054
0.486
2.497
1.560
1.472
1.702
1.631
1.352
0.024
0.188
0.289
0.631
0.860
0.129
0.642
0.175
0.005
0.753
0.903
0.552
0.353
0.109
4.732
0.062
3.519
3.860
0.209
0.157
0.000
0.070
0.114
0.000
0.000
0.000
p-11
-------
Table P-3. (Continued)
Test Date July 7,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compounds
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO) 0.000 0.049 0.059 0.036 0.031
w-Undecane (w-Cll) 1.749 1.936 1.520 1.735 0.208
w-Dodecane (w-C12) 1.515 1.411 1.719 1.549 0.156
n-Tridecane (w-C13) 0.008 0.004 0.000 0.004 0.004
9H-Fluoren-9-one 4.531 4.707 7.401 5.546 1.608
n-Tetradecane (w-C14) 7.417 11.786 19.018 12.740 5.859
w-Pentadecane (w-C15) 6.328 15.242 18.816 13.462 6.432
w-Hexadecane (w-C16) 1.357 13.431 17.409 10.732 8.360
w-Heptadecane (w-C17) 0.014 0.000 0.000 0.005 0.008
1-Octadecene 0.015 0.031 12.294 4.113 7.085
n-Octadecane (w-C18) 0.000 0.000 0.000 0.000 0.000
2-Methylnonadecane 0.000 0.000 0.000 0.000 0.000
3-Methylnonadecane 0.000 0.000 10.452 3.484 6.034
w-Nonadecane (w-C19) 0.000 0.000 8.271 2.757 4.775
n-Eicosane (w-C20) 0.021 0.029 5.518 1.856 3.172
w-Heneicosane (w-C21) 0.000 0.052 3.402 1.151 1.949
w-Docosane (w-C22) 0.162 0.144 2.494 0.933 1.352
w-Tricosane (w-C23)
/5o-Docosane (C22)
awtewo-Docosane (C22) 0.077 0.081 0.129 0.096 0.029
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
P-12
-------
Table P-3. (Continued)
Test Date July 7,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compounds
1-Methylchrysene 0.242 0.405 1.094 0.580 0.452
Benzo[a]pyrene
1-Methylchrysene 0.242 0.405 1.094 0.580 0.452
Benzo[a]pyrene
w-Tetracosane (w-C24)
/5o-Tricosane (C23) 0.000 0.211 0.694 0.302 0.356
awtewo-Tricosane (C23)
w-Pentacosane (w-C25)
/5o-Tetracosane (C24) 0.000 0.168 0.429 0.199 0.216
awte/5o-Tetracosane (C24)
n-Hexacosane (w-C26)
wo-Pentacosane (C25) 0.120 0.378 1.072 0.524 0.492
awte/5o-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awtewo-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5-o-Octacosane (C28) 0.297 0.425 1.712 0.811 0.783
awtewo-Octacosane (C28) 0.000 0.379 1.131 0.503 0.576
Octacosane (w-C28)
Nonacosane (w-C29)
wo-Nonacosane (C29) 0.000 0.074 0.789 0.288 0.436
awte/5o-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d]fluoranthene 0.714 1.054 4.367 2.045 2.018
Dibenzo[a,e]pyrene 0.000 1.042 4.252 1.765 2.216
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/50-Hentriacontane (C31)
awte/5o-Hentriacontane (C31)
/5o-Dotriacontane (C32) 0.413 0.547 1.384 0.781 0.526
awte/5-o-Dotriacontane (C32) 0.188 0.336 1.140 0.555 0.512
Dotriacontane (n-C32) 0.168 0.406 1.364 0.646 0.633
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33) 0.047 0.527 1.133 0.569 0.544
Pentatriacontane (C35) 0.000 0.507 0.474 0.327 0.284
Hexatriacontane («-C36) 0.686 0.751 0.940 0.792 0.132
P-13
-------
Table P-3. (Continued)
Test Date
Sampling Array
Comnounds
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
6A
0.078
0.655
0.024
1.401
0.018
0.475
0.709
0.414
0.000
6B
0.079
0.667
0.047
0.949
0.000
0.491
0.644
0.406
0.000
8A
0.049
0.971
0.000
2.503
0.000
0.784
1.338
0.906
0.000
July 7, 2002
8B 10A 10B DayAvg
0.069
0.764
0.024
1.618
0.006
0.583
0.897
0.575
0.000
SD
0.017
0.179
0.024
0.799
0.011
0.174
0.383
0.286
0.000
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
0.686
0.400
0.024
2.259
0.144
0.133
0.068
0.000
1.359
0.055
0.054
0.126
0.644
0.449
0.058
1.493
0.145
0.028
0.000
0.000
0.703
0.037
0.034
0.092
1.968
1.301
1.276
5.115
0.325
0.090
0.564
0.000
1.566
0.086
0.096
0.246
1.099
0.717
0.453
2.956
0.205
0.083
0.211
0.000
1.209
0.060
0.061
0.155
0.752
0.506
0.713
1.909
0.104
0.053
0.308
0.000
0.451
0.025
0.032
0.081
P-14
-------
Table P-3. (Continued)
Test Date July 11,2002
Sampling Array 6A 6B 8A 8B 10A 10B DayAvg SD
Compounds
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid 72.32 80.51 216.58 123.14 81.03
P-15
-------
Table P-4. Semivolatile Organic Compounds, Uncertainty
Compounds Campaign #2 Average Uncertainty
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [k]fluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
0.000
0.076
0.667
3.688
2.526
3.499
2.561
3.715
2.559
0.047
0.066
0.516
0.857
0.960
0.274
1.258
0.127
0.127
1.188
1.702
0.843
0.672
0.043
3.219
0.338
2.986
2.163
0.040
0.140
0.078
0.063
0.074
0.065
0.058
0.002
0.002
0.000
0.031
0.167
0.846
0.530
0.514
0.580
0.576
0.466
0.013
0.086
0.114
0.281
0.326
0.096
0.263
0.061
0.253
0.473
0.431
0.222
0.156
0.036
1.593
0.050
1.204
1.314
0.070
0.070
0.078
0.034
0.041
0.041
0.002
0.003
P-16
-------
Table P-4. (Continued)
Compounds
Campaign #2 Average
Uncertainty
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
n-Decane (w-CIO)
w-Undecane (w-Cll)
n-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
n-Hexadecane (w-C16)
w-Heptadecane (n-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methy Ifluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichrysene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/5o-Tricosane (C23)
anteiso-Tricosane (C23)
«-Pentacosane («-C25)
0.014
0.855
0.686
0.127
2.405
6.089
8.948
7.787
0.002
4.242
0.000
0.000
3.331
2.965
2.424
2.034
1.959
0.080
0.926
0.501
0.011
0.130
0.054
0.028
0.539
1.963
2.201
2.854
0.003
2.384
0.000
0.000
2.032
1.603
1.084
0.689
0.504
0.010
0.231
0.178
P-17
-------
Table P-4. (Continued)
Compounds Campaign #2 Average Uncertainty
w-Hexacosane («-C26)
wo-Pentacosane (C25) 0.506 0.228
awfe/so-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awtewo-Heptacosane (C27)
/5o-Octacosane (C28) 0.609 0.303
awtewo-Octacosane (C28) 0.483 0.238
Octacosane (w-C28)
Nonacosane (w-C29)
/5-o-Nonacosane (C29) 0.273 0.382
awfe/so-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d]fluoranthene 1.641 0.823
Dibenzo[a,e]pyrene 1.317 0.806
w-Triacontane (w-C30)
n-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C31)
wo-Dotriacontane (C32) 0.693 0.249
awte/50-Dotriacontane (C32) 0.438 0.212
Dotriacontane (w-C32) 0.522 0.263
Tritriacontane (C33)
Tetratriacontane (C34)
/5-o-Tritriacontane (C33)
awte/50-Tritriacontane (C33) 0.649 0.223
Pentatriacontane (C35) 0.145 0.099
Hexatriacontane (w-C36) 0.482 0.097
Tetracontane (C40) 0.040 0.007
0.522 0.096
Hexanoicacid 0.012 0.009
Succinic acid 0.884 0.272
Octanoic acid 0.002 0.004
Glutaricacid 0.412 0.061
NonanoicAcid 0.544 0.148
Adipic acid
Decanoic acid
Undecanoic acid 0.366 0.127
Pimelic acid 0.036 0.062
Suberic acid
P-18
-------
Table P-4. (Continued)
Compounds Campaign #2 Average Uncertainty
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid 0.366 0.251
Dehydroabietic acid 0.239 0.169
Sebacicacid 0.151 0.238
Tetradecanoic acid 0.985 0.636
Pentadecanoic acid 0.068 0.035
Palmitoleic acid 0.030 0.018
Hexadecanoic acid 0.070 0.103
Heptadecanoic acid 0.000 0.000
Linoleic acid 0.525 0.226
Oleic acid
Linolenic acid 0.021 0.008
Octadecanoic acid 0.021 0.011
Nonoadecanoic acid
Eicosanoic aicd 0.054 0.027
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid 96.03 27.76
P-19
-------
Table P-5. PUF Species Emission Factors (mg/kg)
Test Date
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (|iL)
Comnound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
July 9, 2002
P011702A
6A
First
8.215
600.6
44.3
119569.9
7.4
250
na/uL
4.06
4.2
18.33
12.41
16.83
29.88
30.41
28.79
1.46
16.03
42.96
31.2
9.76
42.03
2.88
107.3
31.4
23.12
19.98
2.44
31.19
44.82
1.94
5.47
2.88
P011702B
6A
Second
270
ng/uL
4.07
18.34
12.62
30.62
22.47
28.87
25.8
0.5
30.39
5.7
42.2
13.94
0.6
P011702C
6A
Third
280
na/uL
4.84
21.38
14.01
30.42
21.71
29.18
22.21
0.21
28.96
23.99
1.29
0.97
0.72
1.69
P011702D
6A
Fourth
240
na/uL
4.61
19.71
13.41
19.04
12.23
19.14
7.47
0.17
14.23
1.27
2.71
3.92
1.73
1.38
ms/ks.
0.107
0.593
2.918
1.979
3.708
3.272
4.086
3.217
0.053
0.581
1.558
1.132
0.354
1.552
0.098
3.892
1.139
0.839
3.587
0.356
3.837
2.224
0.151
0.058
0.223
0.104
P-20
-------
Table P-5. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
n-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methylnonadecane
w-Nonadecane (w-C19)
n-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene
8.25
1.9
116.55
91.24
7.7
2.14
15.64
1.24
6
2.43
1.4
0.32
3.58
2.12
0.16
0.18
0.66
0.319
5.59
16.32
33
78.51
6.32
21.35
60.74
85.15
6.81
24.05
70.88
38.21
7.56
29.66
62.22
1.38
0.941
3.395
8.528
7.715
4.813
.251
94.78
76.48
63.52
71.36
1.13
1.45
1.46
3.69
0.63
2.29
4.88
10.73
1.02
1.68
5.2
3.346
2.823
2.511
3.126
1.9
0.069
P-21
-------
Table P-5. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 25.45 2.89 10.93 4.22 1.283
/'so-Tricosane (C23)
awfe/so-Tricosane (C23)
w-Pentacosane (w-C25) 17.57 4.21 13.37 5.6 1.103
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24)
w-Hexacosane (w-C26) 15.47 5.55 14.6 6.62 1.141
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27) 16.11 6.28 15.94 7.06 1.319
/5o-Hexacosane (C26)
awfe/so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 13.11 6.76 14.31 6.04 1.217
Nonacosane (n-C29) 12.1 5.07 13.03 5.36 1.143
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene 4.03 1.17 1.31 5.87 -0.571
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30) 27.19 11.02 30.6 11.93 2.45
w-Hentriacontane (w-C31) 25.8 10.55 27.44 11.45 2.322
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane (w-C32) 8.89 5.51 10.09 5.09 0.827
Tritriacontane (C33) 5.98 2.89 7.58 2.49 0.599
Tetratriacontane (C34) 5.03 3.69 8.69 2.09 0.612
/5o-Tritriacontane (C33)
aMte/so-Tritriacontane (C33)
P-22
-------
Table P-5. (Continued)
Comnound
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
na/uL
5.21
6.16
0.99
18.76
0
18.61
10.28
11.63
ng/uL
5.57
1.99
4.73
0.2
0.78
0
1.96
0.66
1.1
na/uL
8.73
4.07
3.63
0.2
1.28
0
2.96
0.86
1.19
ne/uL
3.48
0.93
0.23
0.29
0.08
1.01
0.51
0.96
ms/ks.
0.883
0.243
0.476
0.06
0.72
0.003
0.743
0.411
0.369
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
6.66
0.54
0.59
0.47
0.211
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
6.79
6.23
29.9
5.28
0.24
0.66
0.68
0.76
4.99
0.31
1.43
0.09
0.73
1.03
0.56
5.68
0.3
0.5
0.33
1.61
0.1
1.13
1.85
1.67
9.48
0.47
0.36
0.88
0.16
2.07
0.13
0.15
-0.124
-0.115
-0.687
-0.544
-0.042
0.001
-0.357
-0.037
-0.228
0.003
-0.007
P-23
-------
Table P-5. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Tetracosanoic acid 0.38 0.14 0.14 0.32 0.008
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1525 536.29 572.56 336.23 98.55
P-24
-------
Table P-6. Gas-Phase Semivolatiles, Campaign #2, July 9, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (Lpm)
Sampling Time (min)
Dilution Ratio
Flue Gas Flow (Lpm)
Fuel (kg/min)
Volume diL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
July 9, 2002
PUF
P011702A
6A
First
8.215
600.6
44.30
119569.9
7.40
250
ng/uL
4.06
4.20
18.33
12.41
16.83
29.88
30.41
28.79
1.46
16.03
42.96
31.20
9.76
42.03
2.88
107.30
31.40
23.12
19.98
2.44
31.19
44.82
1.94
5.47
P011702B
6A
Second
270
ng/uL
4.07
18.34
12.62
30.62
22.47
28.87
25.80
0.50
30.39
5.70
42.20
13.94
0.60
P011702C
6A
Third
280
ng/uL
4.84
21.38
14.01
30.42
21.71
29.18
22.21
0.21
28.96
23.99
1.29
0.97
0.72
1.69
P011702D
6A
Fourth
240
ng/uL
4.61
19.71
13.41
19.04
12.23
19.14
7.47
0.17
14.23
1.27
2.71
3.92
1.73
1.38
mg/kg
0.107
0.593
2.918
1.979
3.708
3.272
4.086
3.217
0.053
0.581
1.558
1.132
0.354
1.552
0.098
3.892
1.139
0.839
3.587
0.356
3.837
2.224
0.151
0.058
0.223
P-25
-------
Table P-6. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Fluoranthene
Pyrene 2.88 0.104
Chrysene
Benzo [a]anthracene
B enzo [k] fluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[ 1,2,3 -cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (n-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
8.25
1.90
5.59
16.32
33.00
78.51
116.55
91.24
94.78
76.48
63.52
71.36
7.70
2.14
6.32
21.35
60.74
85.15
15.64
1.24
1.13
1.45
1.46
3.69
6.00
2.43
6.81
24.05
70.88
38.21
1.40
0.32
0.63
2.29
4.88
10.73
3.58
2.12
7.56
29.66
62.22
1.38
0.16
0.18
1.02
1.68
5.20
0.660
0.319
0.941
3.395
8.528
7.715
4.813
3.251
3.346
2.823
2.511
3.126
P-26
-------
Table P-6. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
/5o-Docosane (C22)
awtewo-Docosane (C22)
Pyrene 1.90 0.069
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 25.45 2.89 10.93 4.22 1.283
/'so-Tricosane (C23)
anfe/'so-Tricosane (C23)
w-Pentacosane (w-C25) 17.57 4.21 13.37 5.60 1.103
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
w-Hexacosane (w-C26) 15.47 5.55 14.60 6.62 1.141
/5o-Pentacosane (C25)
awfe/'so-Pentacosane (C25)
Heptacosane (n-C27) 16.11 6.28 15.94 7.06 1.319
/5o-Hexacosane (C26)
anfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/50-Heptacosane (C27)
/5o-Octacosane (C28)
awte/50-Octacosane (C28)
Octacosane (w-C28) 13.11 6.76 14.31 6.04 1.217
Nonacosane (w-C29) 12.10 5.07 13.03 5.36 1.143
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene 4.03 1.17 1.31 5.87 -0.571
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30) 27.19 11.02 30.60 11.93 2.450
w-Hentriacontane (w-C31) 25.80 10.55 27.44 11.45 2.322
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
a«fe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/5o-Dotriacontane (C32)
Dotriacontane («-C32) 8.89 5.51 10.09 5.09 0.827
P-27
-------
Table P-6. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
5.98
5.03
5.21
6.16
0.99
18.76
0.00
18.61
10.28
11.63
2.89
3.69
5.57
1.99
4.73
0.20
0.78
0.00
1.96
0.66
1.10
7.58
8.69
8.73
4.07
3.63
0.20
1.28
0.00
2.96
0.86
1.19
2.49
2.09
3.48
0.93
0.23
0.29
0.08
1.01
0.51
0.96
0.599
0.612
0.883
0.243
0.476
0.060
0.720
0.003
0.743
0.411
0.369
Pimelic acid
Suberic acid
Dodecanoic acid 6.66 0.54 0.59 0.47 0.211
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
6.79
6.23
29.90
0.66
0.68
0.76
4.99
0.31
0.73
1.03
0.56
5.68
0.30
0.50
0.33
1.13
1.85
1.67
9.48
0.47
0.36
0.88
0.16
-0.124
-0.115
-0.687
-0.544
-0.042
0.001
-0.357
-0.037
P-28
-------
Table P-6. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Octadecanoic acid 5.28 1.43 1.61 2.07 -0.228
Nonoadecanoic acid
Eicosanoic aicd 0.24 0.09 0.10 0.13 0.003
Docosanoic acid 0.15 -0.007
Tricosanoic acid
Tetracosanoic acid 0.38 0.14 0.14 0.32 0.008
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1525.0 536.29 572.56 336.23 98.55
P-29
-------
Table P-7. Campaign #2 Gas-Phase Semivolatiles, July 9, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (Lpm)
Sampling Time (min)
Dilution Ratio
Flue Gas Flow (Lpm)
Fuel (kg/min)
Volume (jiL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
July 9, 2002
PUF
P011702E
6B
First
8.215
600.6
44.30
111439
7.40
260
ns/uL
3.83
3.53
17.21
11.14
22.84
25.24
27.82
25.62
1.52
15.52
31.15
29.75
5.61
38.26
3.16
P011702F
6B
Second
270
ns/uL
3.68
19.44
13.01
30.51
23.82
31.58
25.85
1.04
0.18
P011502A
6B
Third
190
ns/uL
3.63
18.78
12.77
24.62
18.36
25.02
17.05
0.13
P011502B
6B
Fourth
230
ns/uL
4.71
23.16
15.00
18.87
12.57
21.52
7.37
0.26
ms/ks
0.104
0.459
2.681
1.780
3.365
2.811
3.694
2.695
0.057
0.626
1.175
1.122
0.212
1.456
0.113
P-30
-------
Table P-7. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
39.97 0.20
43.25
52.91
25.62
22.28
0.76
30.11 24.72 14.48
2.61 4.28
24.48 40.43 20.21 3.50
41.00 16.35 0.51
1.45 0.97 1.43 7.89
0.99 3.64
3.03 2.00 0.57 1.56
0.56
0.17
0.38 0.20
1.515
1.631
1.996
0.966
0.840
0.025
2.344
0.216
3.165
2.201
0.347
0.047
0.168
0.021
0.006
0.020
P-31
-------
Table P-7. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
n-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (n-C14)
w-Pentadecane («-C15)
n-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
n-Tricosane (w-C23)
/5o-Docosane (C22)
awte/50-Docosane (C22)
1.32
1.71
6.24
16.39
34.00
75.79
113.85
89.86
93.19
76.44
64.39
65.89
0.24
6.39
2.09
6.84
21.52
56.75
78.83
24.19
0.65
0.30
0.79
0.87
2.26
0.20
3.42
2.05
6.65
21.66
51.24
30.41
0.43
0.19
0.27
0.80
0.72
2.11
2.44
2.14
8.15
29.79
53.33
2.35
0.27
0.27
0.28
1.03
1.13
3.21
0.015
0.167
0.268
0.909
3.010
6.604
6.795
5.174
3.303
3.382
2.834
2.413
2.515
P-32
-------
Table P-7. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Pyrene 2.05 0.077
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane («-C24) 23.45 2.38 1.76 2.81 0.776
/5o-Tricosane (C23)
anteiso-Tricosane (C23)
n-Pentacosane (n-C25) 13.68 3.77 2.19 0.287
/5o-Tetracosane (C24)
awfe/'so-Tetracosane (C24)
w-Hexacosane («-C26) 10.61 4.80 2.45 4.93 0.360
/5o-Pentacosane (C25)
awfe/'so-Pentacosane (C25)
Heptacosane (w-C27) 10.37 5.14 2.44 5.63 0.443
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awtewo-Octacosane (C28)
Octacosane (w-C28) 8.60 4.23 2.32 4.81 0.399
Nonacosane (w-C29) 7.70 3.75 2.26 4.72 0.447
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene L32 L46 2.06 2.09 -0.787
P-33
-------
Table P-7. (Continued)
Compound
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/so-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awfe/'so-Dotriacontane (C32)
Dotriacontane (w-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
ns/uL
15.64
14.75
5.49
2.96
1.44
2.59
0.79
12.48
16.00
8.16
9.69
5.36
ns/uL
8.16
7.64
4.08
1.72
1.72
3.18
1.59
0.31
0.66
2.11
0.59
1.40
0.69
ns/uL
6.12
6.17
4.00
1.81
2.12
3.87
1.43
0.95
0.20
0.58
0.14
2.05
0.58
1.38
0.68
ns/uL
10.66
10.21
4.89
2.57
2.36
3.68
0.50
0.15
0.23
0.00
1.88
0.75
1.84
0.91
ms/ks
0.808
0.826
0.342
0.189
0.119
0.354
0.039
0.091
0.052
0.468
0.004
0.641
0.331
0.342
0.187
P-34
-------
Table P-7. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
5.51 0.80
4.36 0.90
0.58
20.24 5.94
0.26
0.54
0.74 0.55
6.46 3.68
0.10
0.18
0.98
1.05
0.74
7.48
0.30
0.44
0.65
5.76
0.13
0.11
0.18
1.26
1.34
1.08
12.78
0.48
0.43
0.64
13.33
0.16
0.14
0.18
-0.157
-0.200
-0.719
-0.756
-0.048
0.016
-0.313
0.379
-0.005
-0.004
-0.010
P-35
-------
Table P-7. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1369.0 514.16 358.76 337.08 80.23
P-36
-------
Table P-8. Campaign #2 Gas-Phase Semivolatiles, July 9, 2002
Sampling Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (Lpm)
Sampling Time (min)
Dilution Ratio
Flue Gas Flow (Lpm)
Fuel (kg/min)
Volume (jiL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
P012202E
10A
First
8.215
600.6
44.30
111439
7.40
260
ns/uL
3.97
2.87
14.35
9.85
24.92
24.34
25.86
24.17
1.44
17.39
39.78
32.78
8.26
40.75
5.53
55.24
July 9, 2002
PUF
P012202F P012202G
10A
Second
280
ns/uL
0.23
3.35
15.47
10.78
25.31
18.65
24.51
20.63
1.20
10A
Third
260
ns/uL
3.41
16.29
11.32
26.33
18.56
25.43
17.75
P012302A
10A
Fourth
250
ns/uL
0.82
3.30
15.45
10.91
16.13
10.46
16.97
6.97
0.18
ms/ks
0.148
0.417
2.324
1.630
3.546
2.755
3.546
2.672
0.054
0.705
1.500
1.236
0.312
1.537
0.202
0.000
2.084
P-37
-------
Table P-8. (Continued)
Compound ns/uL
Methy lanthracene -Peak4 30.18
Octylcyclohexane
Norpristane 18.37
Decylcyclohexane 3.03
Pristane 30.65
Phytane 50.75
Tridecylcyclohexane
Dibutyl phthalate 1.79
Butyl benzyl phthalate 3.80
bis(2 -Ethylhexyl) phthalate 2.28
Dioctyl phthalate
Fluoranthene
Pyrene 5.53
Chrysene
Benzo [a] anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijpery lene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
ns/uL ns/uL ns/uL ms/ks
1.138
24.32 27.82 16.40 3.325
4.83 4.25 1.91 0.540
35.12 26.14 6.99 3.806
13.23 1.63 2.513
0.75 0.87 6.50 0.318
1.10 1.62 9.08 0.476
0.69 0.95 2.77 0.158
0.209
P-38
-------
Table P-8. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
n-Decane (n-CIO)
n-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
n-Pentadecane («-C15)
w-Hexadecane (w-C16)
w-Heptadecane (n-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
n-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
3.98
2.52
5.32
15.54
36.41
82.67
102.49
95.71
96.52
76.19
72.76
59.08
2.27
1.71
1.71
5.51
17.38
48.22
67.22
24.38
0.80
0.33
0.63
0.69
2.14
2.89
1.88
5.94
20.35
67.61
46.41
1.20
0.17
0.33
0.68
0.75
3.44
15.30
1.89
6.13
26.14
60.78
5.59
0.17
0.12
0.35
0.66
0.41
3.33
0.575
0.298
0.821
2.965
7.993
7.734
4.819
3.527
3.518
2.812
2.709
2.342
0.086
P-39
-------
Table P-8. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 26.16 1.72 2.91 23.76 1.684
/so-Tricosane (C23)
awfe/so-Tricosane (C23)
w-Pentacosane (w-C25) 14.99 2.70 4.17 3.20 0.512
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
w-Hexacosane (w-C26) 12.48 3.48 5.26 5.03 0.532
/5o-Pentacosane (C25)
awtewo-Pentacosane (C25)
Heptacosane (w-C27) 12.41 3.72 5.74 3.15 0.545
/5o-Hexacosane (C26)
awte/5o-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/50-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 10.32 5.17 5.44 2.67 0.586
Nonacosane (w-C29) 9.65 3.26 5.31 2.60 0.581
/5o-Nonacosane (C29)
awtewo-Nonacosane (C29)
Squalene 4.69 3.26 0.99 1.12 -0.633
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
n-Triacontane («-C30) 21.05 7.51 11.81 7.32 1.184
«-Hentriacontane («-C31) 18.83 6.62 10.72 6.02 1.061
P-40
-------
Table P-8. (Continued)
Compound
/'so-Triacontane (C30)
awfe/so-Triacontane (C30)
/5o-Hentriacontane (C31)
awtewo-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awte/5o-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awte/5o-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
ns/uL
6.79
3.35
2.92
3.25
3.74
0.53
11.19
13.75
7.60
9.05
4.95
ns/uL
3.26
1.06
1.30
1.95
4.91
0.41
0.74
1.21
0.45
0.86
0.43
ns/uL
5.22
2.31
2.19
3.33
0.85
2.49
0.49
1.69
0.55
1.10
0.54
ns/uL ms/ks
4.70 0.457
1.92 0.200
2.66 0.202
4.30 0.483
1.32 0.080
1.31 0.370
0.037
0.36 0.431
1.14 0.509
0.49 0.303
0.85 0.271
0.41 0.148
P-41
-------
Table P-8. (Continued)
Compound ns/uL
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid 5.59
Pentadecanoic acid 5.05
Palmitoleic acid
Hexadecanoic acid 23.64
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid 4.75
Nonoadecanoic acid
Eicosanoic aicd 0.25
Docosanoic acid 0.16
Tricosanoic acid
Tetracosanoic acid 0.44
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
ns/uL ns/uL ns/uL ms/ks
0.79 0.69 0.60 -0.174
1.18 0.79 0.88 -0.174
1.41 0.74 0.56 -0.692
6.45 4.90 5.63 -0.842
0.31 0.28 0.30 -0.049
0.43 0.36 -0.001
0.78 0.43 0.20 -0.346
3.64 2.63 2.80 -0.085
0.11 0.10 0.000
0.11 -0.001
0.21 0.16 0.10 0.007
P-42
-------
Table P-8. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Nonacosanoic acid
Triacontanoic acid
Total 1462.7 440.33 418.18 331.11 88.15
P-43
-------
Table P-9. Campaign #2 Gas-Phase Semivolatiles, July 9, 2002
Test Date July 9, 2002
Substrate PUF
Sample ID
Port and Array
Sampling Position
Sampling Flow (Lpm)
Sampling Time (min)
Dilution Ratio
Flue Gas Flow (Lpm)
Fuel (kg/min)
Volume (|iL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methy Inaphthalene
1 -Methy Inaphthalene
2,7-Dimethy Inaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene - Peak 1
P012302B
10B
First
8.215
600.6
44.30
111439
7.40
250
ns/uL
5.92
3.19
14.28
9.08
23.40
23.57
25.48
25.28
1.66
9.78
27.15
44.91
48.25
10.92
55.50
4.56
72.56
P012302C
10B
Second
220
ns/uL
3.46
15.77
9.72
28.66
27.17
27.95
27.17
0.51
0.27
0.32
P012302D
10B
Third
220
ns/uL
0.79
3.54
17.92
12.45
26.55
18.21
17.01
25.36
0.22
P012302E
10B
Fourth
220
ns/uL
1.72
4.63
19.36
13.04
15.62
10.86
17.46
6.59
0.28
ms/ks
0.254
0.411
2.191
1.451
3.109
2.650
2.916
2.804
0.076
0.355
0.985
1.629
1.750
0.396
2.031
0.169
2.632
P012302F
DA
First
8.215
600.6
44.30
119569.9
7.40
260
ns/uL
0.00
1.61
0.41
0.00
0.00
0.17
P012302G
DA
Second
260
ns/uL ms/ks
1.07 0.040
0.39 0.075
0.12 0.020
0.05 0.002
0.17 0.006
0.00 0.006
P-44
-------
Table P-9. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Methylanthracene - Peak 2 80.06 2.904
Methylanthracene - Peak 3 45.15 1.638
Methylanthracene - Peak 4 34.72 1.259
Octylcyclohexane
Norpristane 20.46 30.26 25.44 12.48 2.918
Decylcyclohexane 6.31 3.34 1.34 0.351
Pristane 34.39 41.53 15.13 3.02 3.136 0.00 0.42 0.016
Phytane 58.36 8.21 2.379
Tridecylcyclohexane
Dibutyl phthalate 1.95 0.74 0.71 0.069 0.00 1.28 0.048
Butyl benzyl phthalate 2.62 1.06 0.027 1.15 1.56 0.102
6/X2-Ethylhexyl) phthalate 2.19 1.11 0.79 0.048 0.84 1.61 0.092
Dioctyl phthalate 1.70 0.064
Fluoranthene
Pyrene
Chrysene 0.17 0.006
Benzo [a] anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
P-45
-------
Table P-9. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane («-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
Anthraquinone
13.12
1.71
3.97
13.04
33.08
97.90
109.31
87.28
89.63
69.53
57.57
55.64
1.86
9.51
1.88
5.18
16.73
52.30
77.55
4.09
0.53
0.59
0.73
0.77
2.71
4.97
1.83
6.42
23.67
69.34
18.29
0.31
0.27
0.44
0.74
0.69
2.66
10.18
1.93
7.08
26.65
43.79
1.84
0.35
0.22
0.35
0.65
0.55
2.86
0.954
0.236
0.691
2.570
6.386
6.600
4.027
3.072
3.133
2.453
2.045
2.057
0.067
5.39
0.62
0.48
1.23
0.88
1.89
2.99
3.93
2.87
1.86
4.11
2.80
0.16
0.69
0.65
1.25
0.93
0.47
0.36
0.35
0.75
0.98
1.82
0.309
0.006
0.049
0.043
0.094
0.068
0.089
0.126
0.161
0.137
0.107
0.224
P-46
-------
Table P-9. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 21.89 2.99 2.00 3.55 0.722 6.00 3.12 0.344
/5o-Tricosane (C23)
anfe/'so-Tricosane (C23)
w-Pentacosane (w-C25) 12.61 4.54 2.62 4.77 0.401 7.52 4.06 0.437
/5o-Tetracosane (C24)
awfe/'so-Tetracosane (C24)
w-Hexacosane (w-C26) 8.71 5.57 2.81 4.61 0.270 8.12 4.09 0.461
/5o-Pentacosane (C25)
anfe/'so-Pentacosane (C25)
Heptacosane (w-C27) 7.37 6.13 2.22 4.12 0.261 7.25 3.48 0.405
/5o-Hexacosane (C26)
awte/50-Hexacosane (C26)
/5o-Heptacosane (C27)
antewo-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 5.31 6.71 1.41 2.72 0.223 6.18 2.18 0.315
Nonacosane (w-C29) 4.64 4.67 1.14 2.50 0.223 3.83 1.75 0.210
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene 2.77 17.57 2.37 2.12 -0.216 11.73 15.32 1.020
Indeno [ 1,2,3 -c,d]fluoranthene
Dibenzo [a,e]pyrene
P-47
-------
Table P-9. (Continued)
Compound
w-Triacontane (w-C30)
w-Hentriacontane (n-C31)
/5o-Triacontane (C30)
awte/50-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/50-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awfe/'so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
ns/uL
4.62
1.85
1.83
3.14
4.54
0.49
9.48
12.93
7.88
10.20
5.70
ns/uL
10.22
8.88
5.29
2.53
3.02
5.85
2.19
4.75
0.36
1.36
0.70
1.60
0.85
ns/uL
2.07
1.81
1.26
0.29
7.75
0.79
2.41
0.35
4.38
1.08
1.50
0.74
ns/uL
6.71
6.27
4.98
2.29
3.10
4.74
2.24
0.26
0.36
1.36
0.83
1.08
0.53
ms/ks ns/uL
-0.019 11.27
0.001 9.29
0.237 5.45
0.104 2.35
0.121 2.99
0.452 4.93
0.070
0.523
0.051
0.391
0.011
0.531
0.328
0.325
0.183
ns/uL
5.32
5.04
2.47
0.99
0.73
2.96
1.39
4.35
1.08
4.71
2.43
ms/ks
0.626
0.541
0.299
0.126
0.140
0.112
0.052
0.164
0.041
0.178
0.091
P-48
-------
Table P-9. (Continued)
Compound
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
ns/uL ns/uL ns/uL ns/uL ms/ks ns/uL
6.31 2.50 1.05 0.94 -0.093
5.85 3.44 1.24 1.29 -0.071
6.58 2.90 0.83 0.86 -0.413
24.99 14.71 6.49 5.86 -0.614
0.66 0.31 0.30 -0.042
0.61 0.44 0.40 0.015
2.55 0.68 0.61 -0.279
5.13 2.63 2.24 1.40 -0.227
0.24 0.21 0.11 0.11 0.005
0.19 0.18 0.11 0.004
0.38 0.46 0.23 0.16 0.013
ns/uL
12.33
12.55
21.15
63.21
2.19
0.84
10.64
1.14
16.24
0.46
0.31
0.74
ms/ks
0.465
0.473
0.798
2.384
0.083
0.032
0.401
0.043
0.612
0.017
0.012
0.028
P-49
-------
Table P-9. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Heptacosanoic acid
Octacosanoic acid 0.19 0.007
Nonacosanoic acid
Triacontanoic acid
Total 1494.8 528.37 348.18 276.59 78.33 225.32 12.80
P-50
-------
7/9/02
1500
• Port 6A
•Port6B
•PortlOA
Port 10B
PUF Position
Figure P-l. Campaign #2 Gas Phase Semivolatiles, July 9, 2002: PUF Position
P-51
-------
Table P-10. Campaign #2 Gas-Phase Semivolatiles, July 9, 2002
Test Date
Substrate
Sample ID P020102J P020102K
Port and Array 6A 6A
Sampling Position First Second
Sampling Flow (1pm) 8.219
Sampling Time (min) 600.67
Dilution Ratio 44.34
Flue gas flow (Ipni) 115149
Fuel (kg/min) 7.43
Volume (uL) 290 260
Compound
July 10,2002
PUF
P020102L
6A 6A
Third Fourth
P020102M
260
260
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methy Inaphthalene
1 -Methy Inaphthalene
2,7-Dimethy Inaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
3.13
13.52
9.13
22.18
17.19
21.26
19.58
1.25
14.84
27.13
33.52
8.15
40.90
3.32
3.35
15.38
10.59
27.64
20.05
25.15
22.67
0.74
0.24
0.51
3.69
16.01
10.74
23.30
15.40
22.87
12.10
0.14
0.23
0.24
3.86
16.22
10.70
7.96
5.31
9.41
2.74
0.17
0.542
2.431
1.638
3.246
2.326
3.149
2.304
0.083
0.642
1.187
1.451
0.353
1.782
0.144
P-52
-------
Table P-10. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Anthracene
Methylanthracene - Peak 1 44.64 1.933
Methylanthracene - Peak 2 51.42 2.226
Methylanthracene - Peak 3 27.77 1.202
Methylanthracene - Peak 4 23.42 1.014
Octylcyclohexane
Norpristane 16.41 23.07 16.45 4.35 2.413
Decylcyclohexane 5.01 2.54 0.45 0.311
Pristane 32.31 37.36 9.41 1.07 3.240
Phytane 58.00 7.48 2.780
Tridecylcyclohexane
Dibutyl phthalate 0.79 0.86 0.52 0.028
Butyl benzyl phthalate 0.57 0.45
6/X2-Ethylhexyl) phthalate 1.84 1.25 0.92 0.034
Dioctyl phthalate
Fluoranthene 1.44 0.062
Pyrene 3.32 0.144
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
P-53
-------
Table P-10. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (n-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
2.13
1.63
10.41
6.70
17.23
41.17
96.09
104.51
97.55
5.81
1.63
5.45
16.81
50.42
73.21
9.31
0.39
1.56
1.14
6.17
18.93
56.95
8.75
0.48
0.39
0.91
1.58
6.71
23.85
30.80
1.05
0.74
0.54
0.289
0.232
0.451
0.959
3.025
7.069
7.338
4.877
4.194
P-54
-------
Table P-10. (Continued)
Compound
w-Eicosane («-C20)
w-Heneicosane («-C21)
w-Docosane (w-C22)
w-Tricosane («-C23)
/5o-Docosane (C22)
awte/50-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/5o-Tricosane (C23)
anfe/'so-Tricosane (C23)
w-Pentacosane (w-C25)
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awte/50-Hexacosane (C26)
ns/uL ns/uL ns/uL ns/uL ms/ks
80.54 0.51 0.52 3.433
79.47 1.04 1.46 1.29 3.474
69.99 1.93 2.77 2.32 3.257
60.44 3.31 4.70 4.24 2.979
1.85 0.080
25.03 2.98 4.82 3.48 1.376
10.15 3.89 5.83 3.81 0.798
5.87 3.89 5.61 4.30 0.567
4.15 3.05 5.00 4.34 0.434
P-55
-------
Table P-10. (Continued)
Compound
ng/uL
ng/uL ng/uL
ng/uL
mg/kg
/'so-Heptacosane (C27)
antewo-Heptacosane (C27)
/'so-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C29)
anfe/'so-Nonacosane (C29)
Squalene
Indeno[ 1,2,3 -c,d]fluoranthene
Dibenzo [a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/50-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awte/5o-Dotriacontane (C32)
Dotriacontane (w-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
5.84
6.38
3.60
13.38
8.44
10.41
9.84
5.96
2.76
6.98
7.63
3.74
4.78
5.70
4.35
3.96
5.24
36.46 11.81 13.31
10.90 12.96
7.90
4.55
5.69
6.68
3.73
4.74
22.49
21.36
10.78
6.43
7.61
70 o
.38
0.598
0.528
-1.893
2.909
1.239
1.370
0.837
1.127
1.193
P-56
-------
Table P-10. (Continued)
Compound
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
ns/uL
4.73
0.58
9.91
0.54
11.80
0.00
7.69
9.79
5.43
ns/uL
5.68
0.21
0.55
0.30
1.06
0.61
0.88
0.44
ns/uL
1.16
0.19
1.26
0.00
0.78
1.44
1.24
8.34
ns/uL
0.56
0.64
0.41
1.41
1.21
ms/ks
0.472
-0.031
0.433
0.022
0.528
-0.009
0.350
0.372
0.249
0.324
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
11.71
1.06
1.11
-0.892
P-57
-------
Table P-10. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total
7.55
5.69
30.03
1.99
4.44
0.14
0.11
0.30
1417.3
2.06
2.80
7.73
0.40
0.46
1.20
2.49
0.13
0.13
0.30
471.38
2.01
2.99
8.13
0.38
0.48
1.31
2.40
0.11
0.23
359.32
5.89
7.48
20.54
0.89
0.63
3.76
4.43
0.19
0.16
0.39
299.53
-0.662
-2.252
-3.411
-0.142
-0.025
-1.364
-0.857
-0.044
-0.036
-0.066
82.37
P-58
-------
Table P-ll. Campaign #2 Gas-Phase Semivolatiles, July 10, 2002
Test Date July 10, 2002
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1-Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
PUF
P020102N
6B
First
8.219
600.67
44.34
115149
7.43
230
ns/uL
1.44
3.61
15.76
10.86
23.54
22.99
26.30
23.94
1.49
17.64
25.46
30.19
6.64
39.53
3.64
45.46
P020102O
6B
Second
230
ns/uL
3.51
15.08
9.86
26.58
19.89
25.51
23.16
0.70
0.06
P020102P
6B
Third
230
ns/uL
0.25
4.50
18.92
12.11
24.31
17.51
25.82
12.60
0.08
6B
Fourth
250
ns/uL
0.47
3.88
16.81
10.87
7.68
4.29
9.19
1.34
0.20
P020102Q
ms/ks
0.055
0.527
2.334
1.533
2.842
2.234
3.008
2.100
0.075
0.606
0.874
1.037
0.228
1.363
0.125
1.561
P-59
-------
Table P-ll. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
51.76
28.31
23.08
14.47
2.28
26.23
46.25
1.26
1.23
3.64
0.23
20.45
4.03
36.16
3.35
0.86
18.31
2.13
5.88
0.89
0.66
2.76
2.06
1.777
0.972
0.792
1.828
0.290
2.353
1.682
0.107
0.077
-0.086
0.042
0.125
0.008
P-60
-------
Table P-ll. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (n-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
n-Eicosane («-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
Anthraquinone
4.37
1.87
11.40
6.10
17.64
36.76
79.53
100.74
77.47
74.74
71.66
60.40
62.51
1.94
3.36
1.80
5.59
15.41
42.57
63.38
2.61
0.18
0.42
0.90
1.29
2.88
0.15
1.55
1.72
6.57
18.91
59.34
2.56
0.26
0.14
0.41
0.96
1.34
2.76
1.38
1.43
6.20
20.72
35.27
1.26
0.93
0.73
0.69
1.20
1.40
3.17
0.005
0.246
0.231
0.391
0.816
2.524
6.001
4.998
3.537
2.618
2.526
2.456
2.171
2.345
0.067
P-61
-------
Table P-ll. (Continued)
Compound ns/uL
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
n-Tetracosane («-C24) 25.41
/5o-Tricosane (C23)
awfe/'so-Tricosane (C23)
w-Pentacosane («-C25) 9.64
/5o-Tetracosane (C24)
awfe/so-Tetracosane (C24)
w-Hexacosane (w-C26) 4.92
/5o-Pentacosane (C25)
awfe/'so-Pentacosane (C25)
Heptacosane (w-C27) 3.22
/5o-Hexacosane (C26)
awtewo-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 2.88
Nonacosane (w-C29) 2.59
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene 4.97
Indeno[l,2,3-c,d]fluoranthene
Dibenzo [a,e]pyrene
ns/uL ns/uL ns/uL ms/ks
2.87 2.24 2.19 0.985
3.67 2.95 2.45 0.484
4.48 3.36 3.34 0.340
4.57 3.22 2.80 0.256
5.65 3.00 2.99 0.307
3.98 2.78 2.68 0.229
6.47 3.92 3.50 -2.203
P-62
-------
Table P-ll. (Continued)
Compound
w-Triacontane (w-C30)
n-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awtewo-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awfe/so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awfe/so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
ns/uL
9.44
9.08
5.11
2.40
3.36
4.71
4.46
0.59
10.60
12.90
8.18
10.13
5.65
ns/uL
15.79
13.96
6.40
3.84
3.71
4.99
3.25
0.23
0.74
0.41
0.81
0.40
ns/uL
10.80
10.44
5.25
2.67
3.00
4.06
0.68
0.23
0.95
0.39
0.63
0.30
ns/uL
11.99
11.60
5.68
3.03
3.30
4.75
0.18
1.25
0.76
0.23
0.73
ms/ks
1.167
1.066
0.557
0.320
0.444
0.650
0.268
-0.037
0.355
0.450
-0.009
0.284
0.209
0.147
0.000
P-63
-------
Table P-ll. (Continued)
Compound ns/uL
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid 8.48
Pentadecanoic acid 7.83
Palmitoleic acid
Hexadecanoic acid 29.64
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid 4.64
Nonoadecanoic acid
Eicosanoic aicd 0.21
Docosanoic acid 0.18
Tricosanoic acid
Tetracosanoic acid 0.44
Pentacosanoic acid
Hexacosanoic acid
ns/uL ns/uL ns/uL ms/ks
1.64 0.76 1.54 -1.164
3.14 1.63 2.43 -0.853
4.40 2.04 3.60 -2.658
12.41 6.73 11.50 -4.020
0.64 0.31 0.45 -0.243
0.45 -0.070
2.08 0.79 1.50 -1.453
3.94 2.71 4.58 -0.852
0.20 0.11 0.11 -0.044
0.20 0.13 -0.035
0.55 0.26 0.21 -0.064
P-64
-------
Table P-ll. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total
1296.0
445.45
316.30
223.94
56.21
P-65
-------
Table P-12. Campaign #2 Gas-Phase Semivolatiles, July 10, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
P012902B
10A
First
8.183
600.67
44.34
115149
7.43
ng/uL
July 10,2002
PUF
P012902 P012902D
C
10A 10A
Second Third
P012902E
10A
Fourth
ng/uL
ns/uL
ns/uL
ms/ks
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1-Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l DimethyIphenanthrenes
Anthracene
P-66
-------
Table P-12. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
P-67
-------
Table P-12. (Continued)
Compound
ng/uL
ng/uL ng/uL
ng/uL
mg/kg
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
n-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (n-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
n-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methylnonadecane
n-Nonadecane (n-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene
P-68
-------
Table P-12. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/'so-Tricosane (C23)
awte/5o-Tricosane (C23)
w-Pentacosane (w-C25)
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24)
w-Hexacosane (n-C26)
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awtewo-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (n-C29)
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d]fluoranthene
P-69
-------
Table P-12. (Continued)
Compound
ng/uL
ng/uL ng/uL
ng/uL
mg/kg
Dibenzo [a,e]pyrene
n-Triacontane («-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane (w-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
1.99
2.68
8.95
8.99
24.70
21.30
4.49
0.49
4.54
3.91
4.80
0.19
3.05
2.63
0.76
0.20
0.31
0.21
1.39
0.69
0.20
0.71
-0.020
-0.064
-0.024
-0.013
-0.097
-0.052
-0.196
-0.098
P-70
-------
Table P-12. (Continued)
Compound
ng/uL
ng/uL ng/uL
ng/uL
mg/kg
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
4.66
4.79
2.35
22.20
1.33
12.53
0.23
0.09
0.15
3.86
5.24
6.53
34.10
0.69
0.59
2.14
14.21
0.19
0.26
0.81
1.40
1.48
12.65
0.40
0.54
0.83
3.25
0.16
7.63
9.45
12.50
32.53
1.59
0.85
5.14
6.11
0.41
0.36
1.00
-1.595
-1.375
-3.013
-6.124
-0.292
-0.085
-1.607
-1.410
-0.066
-0.052
-0.115
P-71
-------
Table P-12. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 116.9 81.23 32.18 82.04 -16.30
P-72
-------
Table P-13. Campaign #2 Gas-Phase Semivolatiles, July 10, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
July 10, 2002
PUF
P012902F P012902G P012902H
10B 10B 10B
First Second Third
8.183
600.67
44.34
115149
7.43
250 230 250
ns/uL ns/uL ns/uL
2.52 2.83 2.91
11.02 12.73 12.74
7.63 8.75 8.71
16.94 23.66 20.62
14.96 17.31 14.89
17.32 22.47 21.30
16.40 20.41 11.29
0.70
15.65
4.38
19.57
18.77
27.27 0.11 0.11
3.65
30.22
P020102A
10B
Fourth
250
ns/uL
0.53
3.11
13.57
8.88
7.17
4.39
9.07
1.52
0.23
ms/ks
0.000
0.401
1.836
1.247
2.493
1.880
2.563
1.799
0.026
0.587
0.164
0.734
0.704
1.032
0.137
1.133
P-73
-------
Table P-13. (Continued)
Compound
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ns/uL
36.56
19.43
15.29
10.60
16.55
29.53
1.24
2.16
1.69
3.65
0.12
ns/uL ns/uL ns/uL ms/ks
1.370
0.728
0.573
18.98 15.82 0.47 1.663
4.27 2.04 3.17 0.343
28.84 5.65 1.811
4.48 0.56 1.262
0.73 0.92 0.050
0.44 2.05 0.174
0.56 0.53 0.88 0.006
1.97 0.074
0.137
0.004
0.13 0.13 0.009
P-74
-------
Table P-13. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (n-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
n-Eicosane («-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (n-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
Anthraquinone
2.69
1.29
7.59
5.50
12.46
24.33
54.73
84.42
77.19
66.22
57.33
55.94
50.18
1.73
3.01
1.82
5.07
13.52
34.23
51.71
4.68
0.19
0.23
0.84
1.14
1.85
1.57
1.58
4.72
14.27
48.87
2.76
0.25
0.21
0.26
0.84
0.89
1.51
1.35
1.58
5.16
17.17
29.24
0.65
0.52
0.47
0.39
0.93
1.07
2.39
0.190
0.222
0.285
0.709
2.078
4.944
3.919
3.299
2.846
2.421
2.131
2.165
1.978
0.065
P-75
-------
Table P-13. (Continued)
Compound
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
n-Tetracosane («-C24)
/5o-Tricosane (C23)
awfe/'so-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awfe/so-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awfe/'so-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
awtewo-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene
Indeno[ 1 ,2,3 -c,d]fluoranthene
Dibenzo [a,e]pyrene
ns/uL ns/uL ns/uL ns/uL ms/ks
20.70 2.12 1.61 3.15 0.882
12.07 2.30 1.73 4.30 0.592
8.91 2.28 1.84 4.22 0.417
8.59 1.97 1.52 3.99 0.370
7.53 1.82 1.71 2.97 0.320
6.93 1.75 1.65 2.47 0.282
5.09 3.49 1.37 6.39 -2.259
P-76
-------
Table P-13. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
w-Triacontane («-C30)
n-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awtewo-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awfe/so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awfe/so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
21.15
19.66
7.32
7.38
9.58
8.12
7.34
4.14
3.45
.90
4.66
2.24
2.51
4.47
5.41
2.51
3.25
5.75
9.05
8.53
4.37
1.97
2.40
4.03
1.226
1.100
0.572
0.301
0.402
0.667
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
1.08
3.49
7.93
7.29
15.98
13.78
1.66
0.78
0.49
1.71
1.48
1.38
0.84
0.50
1.83
1.58
0.129
0.106
1.28 0.306
1.11 0.298
2.98 0.642
2.56 0.624
P-77
-------
Table P-13. (Continued)
Compound
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
ns/uL ns/uL ns/uL ns/uL ms/ks
8.76 1.06 0.68 3.94 -1.057
7.05 1.50 0.80 5.94 -0.807
4.43 1.41 0.78 6.53 -2.525
30.16 9.20 7.95 51.14 -2.461
2.41 0.28 0.21 1.08 -0.144
0.40 0.63 -0.048
0.59 2.55 -1.491
17.74 8.38 9.38 24.58 0.816
0.30 0.23 -0.046
0.21 0.13 -0.040
0.36 0.14 0.51 -0.077
P-78
-------
Table P-13. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1095.8 357.92 267.78 281.48 51.29
P-79
-------
Table P-14. Campaign #2 Gas-Phase Semivolatiles,
Test Date
Substrate
Sample ID P012902F P012902
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
10B
First
8.183
600.67
44.34
115149
7.43
250
ng/uL
2.52
11.02
7.63
16.94
14.96
17.32
16.40
0.70
15.65
4.38
19.57
18.77
27.27
3.65
G
10B
Second
230
ng/uL
2.83
12.73
8.75
23.66
17.31
22.47
20.41
0.11
July 10, 2002
July 10, 2002
PUF
P012902H P020102A
10B
Third
250
ng/uL
2.91
12.74
8.71
20.62
14.89
21.30
11.29
0.11
10B
Fourth
250
ng/uL
0.53
3.11
13.57
8.88
7.17
4.39
9.07
1.52
0.23
mg/kg
0.000
0.401
1.836
1.247
2.493
1.880
2.563
1.799
0.026
0.587
0.164
0.734
0.704
1.032
0.137
P020102 P020102S
R
DA DA
First Second
8.219
600.67
44.34
123537.5
7.43
230 250
ng/uL ng/uL
0.37 0.20
0.26 0.21
0.06
0.13 0.06
mg/kg
0.020
0.017
0.002
0.007
P-80
-------
Table P-14. (Continued)
Compound
Methylanthracene - Peak 1
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
Phytane
Tridecylcyclohexane
Dibutyl phthalate
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1 ,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
ns/uL
30.22
36.56
19.43
15.29
10.60
16.55
29.53
1.24
2.16
1.69
3.65
0.12
ns/uL ns/uL ns/uL ms/ks
1.133
1.370
0.728
0.573
18.98 15.82 0.47 1.663
4.27 2.04 3.17 0.343
28.84 5.65 1.811
4.48 0.56 1.262
0.73 0.92 0.050
0.44 2.05 0.174
0.56 0.53 0.88 0.006
1.97 0.074
0.137
0.004
ns/uL ns/uL ms/ks
0.23 0.21 0.016
0.61 0.021
0.86 0.71 0.056
1.72 1.89 0.130
P-81
-------
Table P-14. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Cholestane4 0.13 0.13 0.009
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
w-Heptadecane (n-CIT)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
2.69
1.29
7.59
5.50
12.46
24.33
54.73
84.42
77.19
66.22
57.33
55.94
50.18
1.73
3.01
1.82
5.07
13.52
34.23
51.71
4.68
0.19
0.23
0.84
1.14
1.85
1.57
1.58
4.72
14.27
48.87
2.76
0.25
0.21
0.26
0.84
0.89
1.51
1.35
1.58
5.16
17.17
29.24
0.65
0.52
0.47
0.39
0.93
1.07
2.39
0.190
0.222
0.285
0.709
2.078
4.944
3.919
3.299
2.846
2.421
2.131
2.165
1.978
0.065
1.86
0.23
0.68
0.57
1.23
0.81
1.36
2.11
2.74
2.52
1.35
1.62
0.51
0.38
0.92
0.43
0.24
0.20
0.72
1.21
1.79
0.124
0.008
0.042
0.034
0.077
0.044
0.056
0.080
0.094
0.113
0.045
0.113
P-82
-------
Table P-14. (Continued)
Compound
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane («-C24)
/'so-Tricosane (C23)
awte/5o-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awte/50-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/50-Pentacosane (C25)
Heptacosane (w-C27)
/5o-Hexacosane (C26)
anfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/50-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene
Indeno [ 1 ,2,3 -c,d]fluoranthene
ns/uL nsJuL ns/uL nsJuL ms/ks nsJuL nsJuL ms/ks
20.70 2.12 1.61 3.15 0.882 1.53 2.48 0.145
12.07 2.30 1.73 4.30 0.592 1.49 3.08 0.166
8.91 2.28 1.84 4.22 0.417 2.17 3.97 0.223
8.59 1.97 1.52 3.99 0.370 2.12 4.13 0.227
7.53 1.82 1.71 2.97 0.320 1.85 3.66 0.200
6.93 1.75 1.65 2.47 0.282 1.77 3.53 0.193
5.09 3.49 1.37 6.39 -2.259 38.98 40.81 2.861
P-83
-------
Table P-14. (Continued)
Compound
Dibenzo [a,e]pyrene
w-Triacontane (w-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
anfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/'so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
ns/uL
21.15
19.66
7.34
4.14
3.45
3.90
1.08
3.49
7.93
7.29
15.98
13.78
ns/uL ns/uL
7.32 9.58
7.38 8.12
4.66 5.41
2.24 2.51
2.51 3.25
4.47 5.75
1.66 1.38
0.78 0.84
0.49 0.50
1.71 1.83
1.48 1.58
ns/uL
9.05
8.53
4.37
1.97
2.40
4.03
1.28
1.11
2.98
2.56
ms/ks
1.226
1.100
0.572
0.301
0.402
0.667
0.129
0.106
0.306
0.298
0.642
0.624
ns/uL
5.07
5.06
2.45
1.00
0.74
0.58
1.06
0.43
1.60
0.86
2.85
1.43
ns/uL
9.20
9.17
3.92
1.74
0.74
0.26
0.34
1.14
0.24
0.61
2.64
1.33
ms/ks
0.517
0.516
0.230
0.099
0.025
0.020
0.064
0.024
0.013
0.097
0.009
0.052
0.196
0.098
P-84
-------
Table P-14. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
8.76
7.05
4.43
30.16
2.41
17.74
0.30
0.21
0.36
1.06
1.50
1.41
9.20
0.28
0.40
0.59
8.38
0.14
0.68
0.80
0.78
7.95
0.21
9.38
3.94
5.94
6.53
51.14
1.08
0.63
2.55
24.58
0.23
0.13
0.51
-1.057
-0.807
-2.525
-2.461
-0.144
-0.048
-1.491
0.816
-0.046
-0.040
-0.077
20.59
17.01
36.66
76.34
3.49
1.11
19.19
16.88
0.71
0.50
1.01
23.80
21.20
47.01
93.85
4.63
1.26
25.41
22.26
0.28
1.11
0.94
2.14
1.595
1.375
3.013
6.124
0.292
0.085
1.607
1.410
0.010
0.066
0.052
0.115
P-85
-------
Table P-14. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 1095.8 357.92 267.78 281.48 51.29 286.16 348.23 22.82
P-86
-------
7/10/02
1500
O)
f, 1000
u
ra
o
'i/i
.2 500
LU
2 3
PDF Position
Figure P-2. Campaign #2 Gas-Phase Semivolatiles, July 10, 2002: PUF Position
P-87
-------
Table P-15. Campaign #2 Gas-Phase Semivolatiles, July 11, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow Opm)
Sampling Time (min)
Dilution Ratio
Flue gas flow OPm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methy Inaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
July 11, 2002
P062502K
6A
First
8.276
600.0
44.91
120926
7.43
200
ns/uL
0.07
10.06
65.25
44.72
66.00
75.08
70.00
0.48
10.33
2.96
36.72
0.28
P062502L
6A
Second
230
ns/uL
7.54
53.41
37.82
71.06
46.14
73.38
36.21
0.49
PUF
P062502M
6A
Third
240
ns/uL
1.87
10.14
62.05
43.47
8.15
4.58
11.97
1.30
0.36
P062502N
6A
Fourth
240
ns/uL ms/ks
-0.003
2.78 0.066
11.07 1.369
46.74 8.123
27.40 5.471
4.974
1.849
5.489
3.575
0.015
0.326
0.093
1.167
0.009
-------
Table P-15. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane 5.44 0.206
Norpristane 59.35 2.155
Decylcyclohexane 9.58 0.348
Pristane 33.60 1.220
Phytane 0.96 0.035
Tridecylcyclohexanell.48 0.363
Dibutyl phthalate 2.38 2.74 0.085
Butyl benzyl phthalate
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene7.20 0.227
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
P-89
-------
Table P-15. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (»-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
anfe/'so-Docosane (C22)
Pyrene
Anthraquinone
13.08 16.34
8.97 9.53
32.24
96.55
140.64
37.48
0.35
1.41
2.02
3.15
2.44
12.07 11.52
10.34 13.04
0.12 0.10
41.19 48.49
105.96
34.12 1.20
0.58 0.97
0.37
0.32 0.56
1.50
4.95
1.749
1.515
0.008
4.531
7.417
6.328
1.357
0.014
0.015
0.021
-0.015
0.162
0.077
P-90
-------
Table P-15. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 6.79 2.51 1.82 0.242
/5o-Tricosane (C23)
awfe/'so-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
anfe/'so-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27) 1.58 2.21 5.15 0.120
/5o-Hexacosane (C26)
awte/5o-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
ante/5o-Octacosane (C28)
Octacosane (w-C28) 1.88 2.45 6.12 2.24 0.297
Nonacosane (w-C29) 1.80 2.51 -0.037
/5o-Nonacosane (C29)
awte/50-Nonacosane (C29)
Squalene 17.16 7.67 11.13 14.44 -0.001
Indeno[l,2,3-c,d]fluoranthene
Dibenzo [a,e]pyrene
P-91
-------
Table P-15. (Continued)
Compound
w-Triacontane («-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awte/5o-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/50-Hentriacontane (C31)
/5o-Dotriacontane (C32)
anfe/'so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
anfe/'so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
ns/uL
7.25
7.58
5.06
2.58
2.75
4.46
18.18
1.19
17.59
0.54
21.15
12.08
15.15
9.36
ns/uL
9.85
10.94
6.23
3.12
3.28
5.00
1.70
0.50
0.95
6.11
1.35
3.69
1.88
ns/uL
18.14
7.80
4.42
4.12
1.08
0.48
1.24
0.19
7.93
1.20
3.39
1.71
ns/uL
12.29
6.76
3.33
4.38
6.04
1.20
0.44
1.34
9.00
0.49
1.50
4.78
2.45
ms/ks
0.714
-0.345
0.413
0.188
0.168
0.047
0.686
0.078
0.655
0.024
1.401
0.018
0.475
0.709
0.414
P-92
-------
Table P-15. (Continued)
Compound
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid!6.61
Pentadecanoic acidlO.53
Palmitoleic acid
Hexadecanoic acid47.23
Heptadecanoic acid3.50
Linoleic acidl.05
Oleic acid
Linolenic acid
Octadecanoic acid!6.36
Nonoadecanoic acid
Eicosanoic aicdO.85
Docosanoic acidO.81
Tricosanoic acid
Tetracosanoic acidl.91
Pentacosanoic acid
Hexacosanoic acid
ns/uL ns/uL ns/uL ns/uL ms/ks
6.01 8.31 15.61 0.686
5.48 7.63 12.71 0.400
11.14 14.81 22.23 0.024
27.81 36.89 58.08 2.259
1.34 1.68 2.81 0.144
1.39 2.31 2.23 0.133
5.46 8.80 11.40 0.068
12.99 14.31 21.05 1.359
0.46 0.64 1.00 0.055
0.44 0.64 0.88 0.054
0.94 1.45 2.25 0.126
P-93
-------
Table P-15. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 678.1 917.03 532.39 389.34 71.92
P-94
-------
Table P-16. Campaign #2 Gas-Phase Semivolatiles, July 11, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1-Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
July
11,2002
PUF
P062502O P062102A
6B 6B
First Second
8.276
600.0
44.91
120926
7.43
230 200
ns/uL ns/uL
7.30
53.35
40.22
68.43
41.89
70.87
36.09
0.30
P062102B
6B
Third
210
ns/uL
0.71
8.40
54.23
40.30
10.43
6.12
16.99
1.88
0.23
P062102C
6B
Fourth
230
ns/uL ms/ks
-0.087
0.483
3.483
2.606
2.507
1.526
2.801
1.202
-0.007
P-95
-------
Table P-16. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Methylanthracene - Peak 2
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane 50.87 2.20 1.679
Decylcyclohexane 8.38 0.265
Pristane 22.97 0.26 0.734
Phytane 0.32 0.010
Tridecylcyclohexane
Dibutyl phthalate 2.24 1.42 0.013
Butyl benzyl phthalate
6/X2-Ethylhexyl) phthalate 2.25 1.51 0.121
Dioctyl phthalate
Fluoranthene
Pyrene
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo[a,h]anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
P-96
-------
Table P-16. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
w-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane («-C15)
w-Hexadecane (n-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methylnonadecane
w-Nonadecane (w-C19)
n-Eicosane (w-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
Anthraquinone
0.38
43.43 4.83
12.02 7.79
20.52 34.10
61.87 92.71
277.07 124.93
351.06 21.44
0.47
0.38
1.08
1.38
2.99
2.24
0.52
4.57
8.48
0.05
35.01
94.31
38.17
0.59
0.42
0.32
1.18
1.21
2.32
0.54
5.67
12.33
0.06
48.54
98.81
2.41
1.32
0.94
0.67
1.19
1.56
3.12
0.049
1.936
1.411
0.004
4.707
11.786
15.242
13.431
0.031
0.000
0.029
0.052
0.144
0.081
P-97
-------
Table P-16. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
n-Tetracosane («-C24) 6.47 3.16 2.34 3.46 0.405
/5o-Tricosane (C23)
awfe/'so-Tricosane (C23)
w-Pentacosane (w-C25) 4.50 2.97 4.39 0.211
/5o-Tetracosane (C24)
awfe/so-Tetracosane (C24)
w-Hexacosane (w-C26) 5.79 3.73 0.168
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27) 2.86 5.90 3.13 5.22 0.378
/5o-Hexacosane (C26)
awtewo-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 3.50 5.29 3.58 4.97 0.425
Nonacosane (w-C29) 2.97 5.61 3.36 4.61 0.379
/5o-Nonacosane (C29)
awte/5o-Nonacosane (C29)
Squalene 8.72 4.36 21.40 19.28 0.074
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
P-98
-------
Table P-16. (Continued)
Compound
w-Triacontane (w-C30)
n-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awtewo-Triacontane (C30)
/5o-Hentriacontane (C31)
awte/5o-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awfe/so-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/'so-Tritriacontane (C33)
awfe/so-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
ns/uL
11.10
12.70
7.82
3.98
5.30
7.21
4.42
17.04
1.53
17.78
0.46
24.54
12.71
16.46
10.54
ns/uL
20.06
18.47
8.59
5.60
6.21
8.03
4.37
3.51
0.44
0.56
0.45
2.24
0.90
2.08
1.06
ns/uL
14.91
13.84
8.14
5.08
7.00
9.86
6.30
0.81
0.28
0.48
0.28
1.44
0.75
2.55
1.28
ns/uL
15.11
14.31
6.78
4.05
3.99
5.20
0.84
0.36
0.55
0.20
1.93
0.93
3.00
1.50
ms/ks
1.054
1.042
0.547
0.336
0.406
0.527
0.507
0.751
0.079
0.667
0.047
0.949
0.491
0.644
0.406
P-99
-------
Table P-16. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid, 4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
16.36
8.90
37.64
3.45
15.01
0.65
0.51
1.14
3.45
4.20
7.88
20.61
0.94
1.19
4.24
8.30
0.36
0.36
0.86
11.81
12.68
22.58
45.38
2.44
1.93
11.06
11.86
0.75
0.65
1.74
14.13
13.06
23.26
49.90
2.61
1.35
10.73
12.98
0.78
0.75
2.03
0.644
0.449
0.058
1.493
0.145
0.028
-0.006
0.703
0.037
0.034
0.092
P-100
-------
Table P-16. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 867.53 568.18 409.39
P-101
-------
Table P-17. Campaign #2 Gas-Phase Semivolatiles, July 11, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
2,7-Dimethylnaphthalene
1 ,3 -Dimethylnaphthalene
2,6-Dimethylnaphthalene
Add'l Dimethylnaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethylphenanthrenes
Anthracene
Methylanthracene - Peak 1
P062502C
8A
First
8.239
600.0
44.91
120926
7.43
290
ns/uL
3.39
21.18
14.85
37.73
45.91
42.88
40.99
1.02
11.77
23.92
32.38
4.85
21.30
6.58
28.34
July 11, 2002
PUF
P062502D P062502E
8A 8A
Second Third
250 220
ns/uL ns/uL
1.95
9.29 9.35
60.27 54.90
41.28 39.22
66.74 21.52
52.14 12.72
70.02 28.59
37.10 4.48
1.57 0.30
P062502F
8A
Fourth
260
ns/uL ms/ks
3.59 0.106
10.88 1.273
51.45 7.401
34.41 5.107
5.132
4.623
5.746
3.512
0.047
0.541
1.092
1.489
0.223
0.46 1.047
0.303
1.303
P-102
-------
Table P-17. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Methylanthracene - Peak 2 34.00 1.564
Methylanthracene - Peak 3 20.80 0.957
Methylanthracene - Peak 4 13.31 0.612
Octylcyclohexane 4.66 0.163
Norpristane 170.11 51.13 7.25 10.104
Decylcyclohexane 9.71 0.385
Pristane 132.06 24.00 0.91 7.057
Phytane 143.99 1.59 0.67 6.709
Tridecylcyclohexane
Dibutyl phthalate 3.26 2.71 4.24 0.314
Butyl benzyl phthalate 2.21
bis(2 -Ethylhexyl) phthalate
Dioctyl phthalate
Fluoranthene 2.36 0.12 0.113
Pyrene
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno[l,2,3-cd]pyrene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
P-103
-------
Table P-17. (Continued)
Compound
ng/uL
ng/uL
ng/uL
ng/uL
mg/kg
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
17A(H)-22,29,30-Trisnorhopane
17B(H)-21 A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (w-CIO)
w-Undecane (w-Cll)
w-Dodecane (w-C12)
n-Tridecane (w-C13)
9H-Fluoren-9-one
w-Tetradecane (n-C14)
w-Pentadecane («-C15)
w-Hexadecane (w-C16)
n-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
n-Nonadecane (n-C19)
n-Eicosane («-C20)
w-Heneicosane (w-C21)
w-Docosane (w-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
awte/5o-Docosane (C22)
Pyrene
0.42
11.68
7.75
56.43
151.06
241.57
360.68
266.33
221.68
179.84
116.84
67.74
40.75
2.81
0.58
9.25
9.84
37.84
105.55
139.05
21.26
0.86
6.33
2.75
3.87
7.66
0.47
9.33
9.63
36.54
94.26
62.28
0.66
0.77
0.25
2.22
4.41
9.16
10.71
15.43
50.17
114.02
3.35
0.44
0.37
1.05
1.10
1.62
3.32
0.059
1.520
1.719
7.401
19.018
18.816
17.409
12.294
10.452
8.271
5.518
3.402
2.494
0.129
P-104
-------
Table P-17. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane (w-C24) 13.40 5.35 9.62 1.51 1.094
/'so-Tricosane (C23)
anteiso-Tricosane (C23)
w-Pentacosane (w-C25) 9.13 13.27 0.694
/5o-Tetracosane (C24)
awtewo-Tetracosane (C24)
w-Hexacosane (n-C26) 16.26 0.429
/5o-Pentacosane (C25)
awte/5o-Pentacosane (C25)
Heptacosane (w-C27) 12.16 13.35 6.12 1.072
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awtewo-Octacosane (C28)
Octacosane (w-C28) 21.02 6.74 12.21 5.35 1.712
Nonacosane (n-C29) 11.29 5.14 11.42 4.72 1.131
/5o-Nonacosane (C29)
awfe/'so-Nonacosane (C29)
Squalene 27.20 15.87 18.78 0.789
Indeno[l,2,3-c,d]fluoranthene
P-105
-------
Table P-17. (Continued)
Compound
Dibenzo [a,e]pyrene
n-Triacontane («-C30)
w-Hentriacontane (w-C31)
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/5o-Hentriacontane (C31)
awfe/so-Hentriacontane (C3 1)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
ns/uL
47.34
43.63
15.28
13.50
17.75
14.37
10.31
15.88
0.76
17.83
24.38
12.34
17.71
11.79
ns/uL
21.18
25.22
8.66
5.50
4.99
6.64
3.83
0.31
2.49
21.74
4.01
10.93
6.19
ns/uL
43.92
40.90
12.30
9.54
8.14
7.95
1.84
0.24
1.16
8.63
1.21
2.88
1.45
ns/uL
20.46
19.40
10.51
6.52
10.33
10.57
0.73
0.14
1.09
8.48
1.78
4.91
4.24
ms/ks
4.367
4.252
1.384
1.140
1.364
1.133
0.474
0.940
0.049
0.971
2.503
0.784
1.338
0.906
P-106
-------
Table P-17. (Continued)
Compound
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
ns/uL ns/uL ns/uL ns/uL ms/ks
25.05 25.98 8.13 11.30 1.968
16.73 16.76 7.73 12.10 1.301
38.70 18.15 21.63 1.276
61.88 71.11 36.36 49.05 5.115
4.73 3.39 1.76 2.35 0.325
2.34 1.91 1.30 0.090
18.00 8.99 10.50 0.564
16.65 20.63 12.35 12.63 1.566
0.91 1.11 0.63 0.70 0.086
1.00 1.13 0.61 0.70 0.096
2.45 2.73 1.66 1.83 0.246
P-107
-------
Table P-17. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total 3069.0 1110.57 749.64 568.52 216.58
P-108
-------
Table P-18. Campaign #2 Gas-Phase Semivolatiles, July 11, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (1pm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methy Inaphthalene
1 -Methy Inaphthalene
2,7-Dimethy Inaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methy Ifluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
July 11, 2002
P041202G
10A
First
8.239
600.0
44.91
120926
7.43
250
ns/uL
6.02
41.96
30.79
66.19
71.96
70.00
44.15
73.81
52.67
PUF
P041202H
10A
Second
230
ns/uL
4.15
64.99
48.80
84.06
51.26
89.00
55.55
0.30
P041202I
10A
Third
210
ns/uL
0.74
7.14
47.84
36.42
19.14
11.59
25.68
5.13
0.49
P041202J
10A
Fourth
220
ns/uL ms/ks
P-109
-------
Table P-18. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Methylanthracene - Peak 3 32.86
Methylanthracene - Peak 4 28.53
Octylcyclohexane 4.83
Norpristane 60.53 8.00
Decylcyclohexane 12.69 0.70
Pristane 42.95 0.67
Phytane 3.10
Tridecylcyclohexane
Dibutyl phthalate 7.48 3.18
Butyl benzyl phthalate 3.78 6.93 7.04
6/X2-Ethylhexyl) phthalate 2.49 2.36 4.89
Dioctyl phthalate 0.58
Fluoranthene
Pyrene 5.41
Chrysene
B enzo [a] anthracene
Benzo[k]fluoranthene
Benzo[b]fluoranthene
Benzo[a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [1,2,3 -cd]py rene
Dibenzo [a,h]anthracene
Benzo[ghi]perylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB -20R-Ethy Icholestane
P-110
-------
Table P-18. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
n-Decane (n-CIO)
n-Undecane (w-Cll) 0.36 0.42
w-Dodecane (w-C12) 5.23 9.11 3.51
w-Tridecane (w-C13) 9.95 9.98 13.33
9H-Fluoren-9-one 0.12
w-Tetradecane (w-C14) 60.14 39.15 30.12
n-Pentadecane (w-C15) 141.38 94.41 79.90
w-Hexadecane (w-C16) 247.27 136.88 55.68
w-Heptadecane (n-C17) 627.27 69.32 0.72
1-Octadecene
w-Octadecane (w-C18) 284.83 2.80 0.37
2-Methylnonadecane 4.94
3-Methylnonadecane 1.45
w-Nonadecane (w-C19) 252.99 0.36 0.44
w-Eicosane (w-C20) 175.82 1.71
w-Heneicosane (w-C21) 121.70 1.00 6.48
n-Docosane (w-C22) 67.92 1.15 13.45
w-Tricosane (w-C23) 35.70 1.66 24.65
/5o-Docosane (C22)
awfe/'so-Docosane (C22)
Pyrene 2.37
Anthraquinone
Naphthalic anhydride
Methylfluoranthene
Retene
P-lll
-------
Table P-18. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methylchry sene
Benzo[a]pyrene
w-Tetracosane («-C24) 6.21 1.66 21.62
/5o-Tricosane (C23)
awfe/so-Tricosane (C23)
n-Pentacosane (n-C25) 2.45 1.73 26.33
/5o-Tetracosane (C24)
awfe/'so-Tetracosane (C24)
w-Hexacosane (w-C26) 2.07 28.43
/5o-Pentacosane (C25)
awfe/'so-Pentacosane (C25)
Heptacosane (w-C27) 1.54 2.01 31.44
/5o-Hexacosane (C26)
awte/5o-Hexacosane (C26)
/5o-Heptacosane (C27)
awte/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28) 1.33 3.01 28.55
Nonacosane (w-C29) 1.57 25.20
/5o-Nonacosane (C29)
awtewo-Nonacosane (C29)
Squalene 16.19 14.78 25.22
Indeno[l,2,3-c,d]fhioranthene
Dibenzo [a,e]pyrene
n-Triacontane (w-C30) 4.40 7.78 64.78
n-Hentriacontane (w-C31) 5.35 8.15 60.11
/5o-Triacontane (C30)
aMte/so-Triacontane (C30)
P-112
-------
Table P-18. (Continued)
Compound
ng/uL
ng/uL ng/uL
ng/uL mg/kg
/5o-Hentriacontane (C31)
awfe/so-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awtewo-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
1,3-Benzenedicarboxylic acid
2.49
1.16
7.21
1.04
13.53
0.51
16.01
11.08
14.09
8.49
4.91
2.39
2.89
4.93
2.68
1.35
13.25
10.40
6.90
5.28
2.19
0.33
0.76
0.18
2.78
1.41
2.69
0.36
0.36
0.78
0.23
4.11
0.86
2.13
6.16
3.23
P-113
-------
Table P-18. (Continued)
Compound
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total
ns/uL
15.36
11.56
11.34
45.50
3.04
10.85
17.20
0.70
0.50
1.16
2795.4
ns/uL
8.49
9.48
15.28
37.96
1.81
2.29
8.28
12.16
0.59
0.53
1.43
1075.72
ns/uL ns/uL ms/ks
23.29
19.81
38.13
79.68
3.96
3.24
21.65
23.51
1.38
1.25
0.00
3.28
999.43
P-114
-------
Table P-19. Campaign #2 Gas-Phase Semivolatiles, July 11, 2002
Test Date
Substrate
Sample ID
Port and Array
Sampling Position
Sampling Flow (1pm)
Sampling Time (min)
Dilution Ratio
Flue gas flow (lpm)
Fuel (kg/min)
Volume (uL)
Compound
Dimethyl phthalate
Diethyl phthalate
Naphthalene
2-Methy Inaphthalene
1 -Methy Inaphthalene
2,7-Dimethy Inaphthalene
1 ,3 -Dimethy Inaphthalene
2,6-Dimethy Inaphthalene
Add'l Dimethy Inaphthalenes
Acenaphthylene
Acenaphthene
Fluorene
1 -Methylfluorene
Add'l Methylfluorene - Peak 1
Add'l Methylfluorene - Peak 2
Phenanthrene
Add'l Dimethy Iphenanthrenes
Anthracene
Methylanthracene - Peak 1
Methylanthracene - Peak 2
July 11, 2002
PUF
10B 10B 10B 10B
First Second Third Fourth
8.239
600.0
44.91
120926
7.43
240 240 260 240
ns/uL ns/uL ns/uL ns/uL ms/kj
3.23 3.97
3.06 6.18 8.74 8.98
20.90 46.17 56.58 48.09
16.03 35.29 41.57 30.08
50.86 73.58 15.97
49.01 56.12 9.56
47.84 72.85 23.23
46.03 41.10 3.02
18.17
6.98
37.22
39.93
30.84 0.63 0.49 0.63
49.79
55.90
P062102D
DA
First
8.203
600.0
44.91
129745.2
7.43
220
E ns/uL
0.15
1.87
0.34
0.22
0.38
P062102E
DA
Second
250
ns/uL ms/ks
0.005
1.12 0.110
0.35 0.026
0.008
0.28 0.024
P-115
-------
Table P-19. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
Methylanthracene - Peak 3
Methylanthracene - Peak 4
Octylcyclohexane
Norpristane
Decylcyclohexane
Pristane
33.90
25.98
126.37
24.02
113.16
4.04
58.18
10.39
31.60
5.05
Phytane
Tridecylcyclohexane
Dibutyl phthalate 5.17 7.70 3.81 3.24 1.44 1.37 0.105
Butyl benzyl phthalate 4.08 6.39 1.60 1.44 1.92 0.076
6/X2-Ethylhexyl) phthalate 2.36 2.55 2.84
Dioctyl phthalate
Fluoranthene
Pyrene 0.90
Chrysene
Benzo[a]anthracene
Benzo [kjfluoranthene
Benzo [b]fluoranthene
Benzo [a]pyrene
Nonadecylcyclohexane
Squalane
Indeno [ 1,2,3 -cd]pyrene
Dibenzo [a,h] anthracene
Benzo [ghijperylene
Coronene
Cholestane 1
Cholestane 2
Cholestane 3
Cholestane 4
ABB-20R-24S-Methylcholestane
ABB-20R-Ethylcholestane
P-116
-------
Table P-19. (Continued)
Compound ng/uL ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
17A(H)-22,29,30-Trisnorhopane
17B(H)-21A(H)-Norhopane
17B(H)-21B(H)-Hopane
17B(H)-21A(H)-Hopane
17A(H)-21B(H)-Hopane
w-Decane (n-CIO)
w-Undecane (n-Cll)
w-Dodecane (w-C12)
w-Tridecane (n-C13)
9H-Fluoren-9-one
w-Tetradecane (w-C14)
w-Pentadecane (w-C15)
w-Hexadecane (w-C16)
w-Heptadecane (w-C17)
1-Octadecene
w-Octadecane (w-C18)
2-Methylnonadecane
3 -Methy Inonadecane
w-Nonadecane (w-C19)
w-Eicosane (n-C20)
w-Heneicosane (w-C21)
w-Docosane (n-C22)
w-Tricosane (w-C23)
/5o-Docosane (C22)
anfe/'so-Docosane (C22)
Pyrene
Anthraquinone
Naphthalic anhydride
5.440
10.020
34.320
104.570
189.780
270.790
237.460
207.050
162.000
103.680
59.760
26.270
2.500
6.110
8.320
32.730
107.920
163.300
34.260
0.390
0.830
1.220
3.770
9.74
10.99
39.73
116.75
60.22
0.70
0.30
1.85
1.22
2.18
4.09
15.89
12.14
47.04
128.19
3.76
0.60
0.26
1.12
1.38
3.34
2.42
0.60
1.62
1.82
1.03
0.34
0.93
1.45
1.25
1.94
1.66
0.44
1.20
1.37
0.68
0.49
0.35
0.92
1.11
1.82
0.151
0.039
0.105
0.118
0.063
0.031
0.047
0.087
0.088
0.140
P-117
-------
Table P-19. (Continued)
Compound
Methylfluoranthene
Retene
Cyclopenta[c,d]acepyrene
Benzanthraquinone
1 -Methy Ichry sene
Benzo[a]pyrene
w-Tetracosane (w-C24)
/'so-Tricosane (C23)
anteiso-Tricosane (C23)
w-Pentacosane («-C25)
/5o-Tetracosane (C24)
awte/5o-Tetracosane (C24)
w-Hexacosane (w-C26)
/5o-Pentacosane (C25)
anfe/'so-Pentacosane (C25)
Heptacosane (n-C27)
/5o-Hexacosane (C26)
awfe/'so-Hexacosane (C26)
/5o-Heptacosane (C27)
ante/5o-Heptacosane (C27)
/5o-Octacosane (C28)
awte/5o-Octacosane (C28)
Octacosane (w-C28)
Nonacosane (w-C29)
/5o-Nonacosane (C29)
antewo-Nonacosane (C29)
Squalene
Indeno[l,2,3-c,d]fluoranthene
Dibenzo [a,e]pyrene
w-Triacontane («-C30)
w-Hentriacontane (w-C31)
ns/uL ns/uL ns/uL ns/uL ms/ks ns/uL ns/uL ms/ks
7.080 1.410 3.14 1.41 1.58 1.94 0.133
4.150 2.42 2.61 0.189
3.950 3.47 0.138
2.770 2.180 2.59 2.49 2.96 0.205
2.480 3.750 3.10 1.81 1.90 2.56 0.169
2.200 2.690 2.95 2.56 1.99 2.90 0.185
17.930 9.750 35.08 40.24 24.02 23.81 1.790
6.690 19.290 10.74 13.25 10.76 16.30 1.026
6.050 16.570 11.23 13.12 10.58 15.33 0.981
P-118
-------
Table P-19. (Continued)
Compound
ng/uL
ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
/5o-Triacontane (C30)
awfe/'so-Triacontane (C30)
/'so-Hentriacontane (C31)
awte/50-Hentriacontane (C31)
/5o-Dotriacontane (C32)
awtewo-Dotriacontane (C32)
Dotriacontane («-C32)
Tritriacontane (C33)
Tetratriacontane (C34)
/5o-Tritriacontane (C33)
awte/5o-Tritriacontane (C33)
Pentatriacontane (C35)
Hexatriacontane (w-C36)
Tetracontane (C40)
3.480
0.980
1.600
2.720
10.810
6.890
10.050
6.84
3.38
4.44
8.41
5.02
7.51
9.250 6.12
5.87
2.98
3.35
5.45
8.01 0.525
4.93 0.301
6.09 0.360
7.87
0.504
Hexanoic acid
Succinic acid
Octanoic acid
Glutaric acid
Nonanoic Acid
Adipic acid
Decanoic acid
Undecanoic acid
Pimelic acid
Suberic acid
Dodecanoic acid
Azelaic acid
Tridecanoic acid
Pinonic acid
Phthalic acid
1,4-Benzenedicarboxylic acid
0.48
0.20
0.51
2.01
0.84
2.91
1.46
0.49
0.14
0.36
1.50
0.00
0.71
2.79
1.40
0.036
0.012
0.032
0.130
0.000
0.058
0.213
0.107
P-119
-------
Table P-19. (Continued)
Compound
ng/uL
ng/uL ng/uL ng/uL mg/kg ng/uL ng/uL mg/kg
1,3-Benzenedicarboxylic acid
1,2-Benzenedicarboxylic acid,
4-methyl
1,2,4-Benzenetricarboxylic acid
Benzenetetracarboxylic acid
Abietic acid
Pimaric acid
Sandaracopimaric acid
Isopimaric acid
Dehydroabietic acid
Sebacic acid
Tetradecanoic acid
Pentadecanoic acid
Palmitoleic acid
Hexadecanoic acid
Heptadecanoic acid
Linoleic acid
Oleic acid
Linolenic acid
Octadecanoic acid
Nonoadecanoic acid
Eicosanoic aicd
Docosanoic acid
Tricosanoic acid
Tetracosanoic acid
Pentacosanoic acid
Hexacosanoic acid
Heptacosanoic acid
Octacosanoic acid
Nonacosanoic acid
Triacontanoic acid
Total
11.05
10.18
20.60
44.48
2.06
2.00
10.68
14.48
13.69
26.66
57.31
2.84
1.33
13.10
0.964
0.902
1.784
3.841
0.185
0.123
0.896
11.20
0.55
0.45
1.01
14.48
0.79
0.74
1.83
0.969
0.051
0.045
0.108
213.85
268.47 18.19
P-120
-------
7/11/02
3500
3000
O) 2500
E,
g" 2000
+-
o
re
Li.
c 1500
.0
'35
w
I 1000
500
Figure P-3. Gas-Phase Semivolatiles, July 11, 2002: PUF Position
P-121
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