dEPA
United States
Environmental
Protection Agency
Our Nation's Air
STATUS AND TRENDS THROUGH 2008
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Printed on 100% recycled/recyclable process chlorine-free paper with 100% post-consumer fiber using vegetable-oil-based ink.
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STATUS AND TRENDS THROUGH 2008
Contract No. EP-D-05-004
Work Assignment No. 5-07
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina
EPA-454/R-09-002
February 2010
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Highlight
Air Pollution
Six Common Pollutants
Ozone
Particle Pollution
Lead
N02/ CO, and S02
Toxic Air Pollutants
Atmospheric Deposition
Visibility in Scenic Areas
Climate Change and Air Quality
International Transport of Air Pollution
Appendix
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Improving air quality and taking action on climate
change are priorities for the EPA. This summary report
presents EPA's most recent evaluation of our nation's air
quality status and takes a closer look at the relationship
between air quality and climate change.
LEVELS OF SIX COMMON POLLUTANTS
CONTINUE TO DECLINE
• Cleaner cars, industries, and consumer products have
contributed to cleaner air for much of the U. S.
• Since 1990, nationwide air quality has improved
significantly for the six common air pollutants.
These six pollutants are ground-level ozone, particle
pollution (PM25 and PM10), lead, nitrogen dioxide
(NO2), carbon monoxide (CO), and sulfur dioxide
(SO2). Nationally, air pollution was lower in 2008
than in 1990 for:
— 8-hour ozone, by 14 percent
- annual PM2 5 (since 2000), by 19 percent
- PM10,by31 percent
- Lead, by 78 percent
- NO2, by 35 percent
- 8-hour CO, by 68 percent
— annual SO2, by 59 percent
• Despite clean air progress, approximately 127
million people lived in counties that exceeded any
national ambient air quality standard (NAAQS) in
2008, as shown in Figure 1. Ground-level ozone and
particle pollution still present challenges in many
areas of the country.
• Nationally, for the period from 2001 to 2008, annual
PM2 5 concentrations were 17 percent lower in 2008
compared to 2001. 24-hour PM25 concentrations
were 19 percent lower in 2008 compared to 2001.
• Ozone levels did not improve in much of the East
until 2002, after which there was a significant
decline. 8-hour ozone concentrations were
10 percent lower in 2008 than in 2001. This decline
is largely due to reductions in oxides of nitrogen
(NO ) emissions required by EPA's rule to reduce
ozone in the East, the NOx State Implementation
Plan (SIP) Call. EPA tracks progress toward
meeting these reductions through its NOx Budget
Trading Program.
LEVELS OF MANY TOXIC AIR
POLLUTANTS HAVE DECLINED
• Toxic air pollutants such as benzene, 1,3-butadiene,
styrene, xylenes, and toluene decreased by
5 percent or more per year between 2000 and
2005 at more than half of ambient monitoring
sites. Other key contributors to cancer risk, such
as carbon tetrachloride, tetrachloroethylene, and
1,4-dichlorobenzene, declined at most sites.
• Total emissions of toxic air pollutants have decreased
by approximately 40 percent between 1990 and
Ozone (8-hour)
PM2 5 (annual and/or 24-hour) —
Lead —
NO2 -
CO -
SO2 (annual and/or 24-hour) —
One or more NAAQS —
119.5
36.9
14.9
4.8
0.0
0.0
0.2
126.8
\ I I I I I I I
20 40 60 80 100 120 140 160
Millions of People
Figure 1. Number of
people (in millions)
living in counties
with air quality
concentrations above
the level of the primary
(health-based) National
Ambient Air Quality
Standards (NAAQS) in
2008.
Note: Projected population
data for 2008 (U.S. Census
Bureau, 2008).
180
Our Nation's Air
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Highlights
2005. Control programs for mobile sources and
facilities such as chemical plants, dry cleaners, coke
ovens, and incinerators are primarily responsible for
these reductions.
ACID RAIN AND HAZE ARE DECLINING
• EPA's NOx SIP Call and Acid Rain Program have
contributed to significant improvements in air
quality and environmental health. The required
reductions in SO2 and NOx have led to significant
decreases in atmospheric deposition, which have
contributed to improved water quality in lakes
and streams. For example, between 1989-1991
and 2006-2008, wet sulfate deposition decreased
more than 30 percent and wet nitrate deposition
decreased more than 30 percent in parts of the East.
• Between 1998 and 2007, visibility in scenic areas
improved throughout the country. Eight areas—
Mt. Rainier National Park, WA; Great Gulf
Wilderness, NH; Snoqualmie Pass, WA; Olympia,
WA; Columbia Gorge, WA; Starkey, OR; Presque
Isle, ME, and Bridgton, ME—showed notable
improvement on days with the worst visibility.
CLIMATE CHANGE AND
INTERNATIONAL TRANSPORT:
IMPROVING OUR UNDERSTANDING
• In 2007, the U.N. Intergovernmental Panel on
Climate Change (IPCC) concluded that climate
change is happening now, as evident from
observations of increases in global average air and
ocean temperatures, widespread snow melt, and
rising average sea levels.
• Research is continuing to improve our
understanding of the effects of air pollution
on climate. For example, tropospheric ozone
(a greenhouse gas) has a warming effect on climate.
Black carbon particle pollution has warming
effects, while aerosols containing sulfates and
organic carbon tend to have cooling effects. Also,
research is continuing to investigate the effects of
climate change on future air pollution levels.
• Ongoing studies continue to improve our
understanding about air pollution movement
between countries and continents.
MORE IMPROVEMENTS ANTICIPATED
• EPA expects air quality to continue to improve as
recent regulations are fully implemented and states
work to meet current and recently revised national
air quality standards. Key regulations include the
Locomotive Engines and Marine Compression-
Ignition Engines Rule, the Tier II Vehicle and
Gasoline Sulfur Rule, the Heavy-Duty Highway
Diesel Rule, the Clean Air Non-Road Diesel Rule,
and the Mobile Source Air Toxics Rule.
SOURCES-TO-EFFECTS CONTINUUM
EMISSIONS
MONITORING
DOSAGE
HEALTH EFFECTS &
ENVIRONMENTAL
IMPACTS
Because air pollution harms human health and damages the environment, EPA tracks pollutant emissions. Air pollutants are
emitted from a variety of sources including stationary fuel combustion, industrial processes, highway vehicles, and non-road
sources. These pollutants react in and are transported through the atmosphere. EPA; other federal agencies; and state, local,
and tribal agencies monitor air quality at locations throughout the U.S. Data collected through ambient monitoring are used
in models to estimate population and environmental exposures. Personal health monitoring is conducted via specia studies
to better understand actual dosage of pollutants. EPA uses monitoring data, population exposure estimates, and persona
dosage data to better understand health effects of air pollutants. Ambient monitoring data and models are also used to
estimate environmental exposures to air pollutants.
2
Our Nation's Air
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AIR POLLUTION
I
HEALTH, ENVIRONMENTAL, AND
CLIMATE IMPACTS
Air pollution can affect our health in many ways.
Numerous scientific studies have linked air pollution to
a variety of health problems including: (1) aggravation
of respiratory and cardiovascular disease; (2) decreased
lung function; (3) increased frequency and severity of
respiratory symptoms such as difficulty breathing and
coughing; (4) increased susceptibility to respiratory
infections; (5) effects on the nervous system, including
the brain, such as IQJoss and impacts on learning,
memory, and behavior; (6) cancer; and (7) premature
death. Some sensitive individuals appear to be at
greater risk for air pollution-related health effects, for
example, those with pre-existing heart and lung diseases
(e.g., heart failure/ischemic heart disease, asthma,
emphysema, and chronic bronchitis), diabetics, older
adults, and children. In 2008, approximately 127 million
people lived in counties that exceeded national air
quality standards.
Air pollution also damages our environment. Ozone
can damage vegetation, adversely impacting the growth
of plants and trees. These impacts can reduce the ability
of plants to uptake CO2 from the atmosphere and
indirectly affect entire ecosystems. Visibility is reduced
by particles in the air that scatter and absorb light.
Typical visual range in the eastern U.S. is 15 to 30 miles,
approximately one-third of what it would be without
man-made air pollution. In the West, the typical visual
range is about 60 to 90 miles, or about one-half of the
visual range under natural conditions.
Pollution in the form of acids and acid-forming
compounds (such as sulfur dioxide [SOJ and oxides of
nitrogen [NO ]) can deposit from the atmosphere to
the Earth's surface. This acid deposition can be either
dry or wet. Wet deposition is more commonly known
as acid rain. Acid rain can occur anywhere and, in some
areas, rain can be 100 times more acidic than natural
precipitation. Acid deposition can be a very serious
regional problem, particularly in areas downwind from
high SO2~ and NOx-emitting sources (e.g., coal burning
power plants, smelters, and factories). Acid deposition
can have many harmful ecological effects in both land
and water systems. While acid deposition can damage
tree foliage directly, it more commonly stresses trees by
changing the chemical and physical characteristics of
the soil. In lakes, acid deposition can kill fish and other
aquatic life.
Air pollution can also impact the Earth's climate.
Different types of pollutants affect the climate in
different ways, depending on their specific properties
and the amount of time they stay in the atmosphere.
Any pollutant that affects the Earth's energy balance
is known as a "climate forcer." Some climate forcers
absorb energy and lead to climate warming, while
others reflect the sun's rays and prevent that energy
from reaching the Earth's surface, leading to climate
cooling. Climate forcers can either be gases or aerosols
(solid or liquid droplets suspended in the air) and
include many traditional air pollutants, such as ozone
and different types of particle pollution.
Greenhouse gas (GHG): A gas that traps heat in
the atmosphere. The principal greenhouse gases
affected by human activities are: carbon dioxide
(CO2), methane (CHJ, nitrous oxide (N2O), ozone,
and fluorinated gases (hydrofluorocarbons [MFCs],
perfluorocarbons [PFCs], and sulfur hexafluoride [SFJ).
Climate forcing pollutant: Any pollutant that affects
the Earth's energy balance, including GHGs and
aerosols. These pollutants are also called "radiative
forcers." Some climate forcers absorb energy and warm
the atmosphere (positive radiative forcing), while others
coo it by reflecting sunlight back into space (negative
radiative forcing).
Under normal conditions, most of the solar radiation
reaching the Earth's surface is radiated back toward
space. However, atmospheric greenhouse gases—like
CO2, CH4, and ozone—can trap this energy and
prevent the heat from escaping, somewhat like the glass
panels of a greenhouse. Greenhouse gases (GHGs)
are necessary to life as we know it because they keep
the planet's surface warmer than it would otherwise
be. However, as the concentrations of these gases
continue to increase in the atmosphere, largely due to
the burning of fossil fuels like coal and oil, the Earth's
Our Nation's Air
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Air Pollution
Health, Environmental, and Climate Effects of Air Pollution
Pollutant
Ozone (OJ
Health Effects
Decreases ung function and causes respiratory
symptoms, such as coughing and shortness of breath;
aggravates asthma and other lung diseases leading
to increased medication use, hospital admissions,
emergency department (ED) visits, and premature
mortality.
Environmental and Climate Effects
Damages vegetation by visibly injuring leaves, reducing
photosynthesis, impairing reproduction and growth, and
decreasing crop yields. Ozone damage to plants may alter
ecosystem structure, reduce biodiversity, and decrease plant
uptake of CO Ozone is a so a greenhouse gas that contributes
to the warming of the atmosphere.
Particulate
Matter (PM)
Short-term exposures can aggravate heart or lung
diseases leading to symptoms, increased medication
use, hospital admissions, ED visits, and premature
mortality; long-term exposures can lead to the
development of heart or lung disease and premature
mortality.
Impairs visibility, adversely affects ecosystem processes, and
damages and/or soils structures and property. Variable climate
impacts depending on partic e type. Most particles are reflective
and lead to net cooling, while some (especially black carbon)
absorb energy and lead to warming. Other impacts include
changing the timing and location of traditional rainfall patterns.
Lead (Pb)
Damages the developing nervous system, resulting
in IQ loss and impacts on learning, memory, and
behavior in children. Cardiovascular and renal effects
in adults and early effects related to anemia.
Harms plants and wildlife, accumulates in soils, and adversely
impacts both terrestrial and aquatic systems.
Oxides of
Sulfur (SO
Aggravate asthma, leading to wheezing, chest
tightness and shortness of breath, increased
medication use, hospital admissions, and ED visits;
very high levels can cause respiratory symptoms in
people without lung disease.
Contributes to the acidification of soil and surface water
and mercury methylation in wetland areas. Causes injury to
vegetation and local species losses in aquatic and terrrestrial
systems. Contributes to partic e formation with associated
environmental effects. Sulfate particles contribute to the cooling
of the atmosphere.
Oxides of
Nitrogen
(NO)
Aggravate lung diseases leading to respiratory
symptoms, hospita admissions, and ED visits; increase
susceptibility to respiratory infection.
Contributes to the acidification and nutrient enrichment
(eutrophication, nitrogen saturation) of soi and surface water.
Leads to biodiversity losses. Impacts levels of ozone, partic es,
and methane with associated environmental and climate effects.
Carbon
Monoxide
(CO)
Reduces the amount of oxygen reaching the body's
organs and tissues; aggravates heart disease,
resulting in chest pain and other symptoms leading to
hospital admissions and ED visits.
Contributes to the formation of CO2 and ozone, greenhouse
gases that warm the atmosphere.
Ammonia
(NHJ
Contributes to particle formation with associated
health effects.
Contributes to eutrophication of surface water and nitrate
contamination of ground water. Contributes to the formation of
nitrate and sulfate partic es with associated environmental and
climate effects.
Volatile
Organic
Compounds
(VOCs)
Some are toxic air pollutants that cause cancer and
other serious health problems. Contribute to ozone
formation with associated health effects.
Contributes to ozone formation with associated environmental
and climate effects. Contributes to the formation of CO and
ozone, greenhouse gases that warm the atmosphere.
Mercury
(Hg)
Causes liver, kidney, and brain damage and
neurological and developmental damage.
Deposits into rivers, lakes, and oceans where it accumulates in
fish, resulting in exposure to humans and wildlife.
Other Toxic
Air Pollutants
Cause cancer; immune system damage; and
neurological, reproductive, developmenta ,
respiratory, and other health problems. Some toxic air
pollutants contribute to ozone and particle pollution
with associated health effects.
Harmful to wildlife and livestock. Some toxic air pollutants
accumulate in the food chain. Some toxic air pollutants contribute
to ozone and partic e pollution with associated environmental
and climate effects.
Our Nation's Air
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temperature is climbing above past levels. Such changes
in temperature, along with changes in precipitation and
other weather conditions due to climate change, may
lead to even higher air pollution levels.
In addition to GHGs, other pollutants contribute
to climate change. Black carbon (BC), a component
of particle pollution, directly absorbs incoming
and reflected solar radiation and reduces reflection
of sunlight off of snow and ice. In these ways, BC
contributes to increased absorption of energy at the
Earth's surface and warming of the atmosphere.
Recent studies suggest that BC may be having a
significant impact on the Earth's climate. Other types
of particles—particularly sulfates, nitrates, and some
types of directly emitted organic carbon—are largely
reflective and therefore have a net cooling impact on
the atmosphere. Particles can also have important
indirect effects on climate through impacts on clouds
and precipitation.
The longer a pollutant stays in the atmosphere, the
longer the effect associated with that pollutant will
persist. Some climate forcing pollutants stay in the
atmosphere for decades or centuries after they are
emitted, meaning today's emissions will affect the
climate far into the future. These pollutants, like
CO2, tend to accumulate in the atmosphere so their
net warming impact continues over time. Other
climate forcers, such as ozone and BC, remain in the
atmosphere for shorter periods of time so reducing
emissions of these pollutants may have beneficial
impacts on climate in the near term. These short-lived
climate forcers originate from a variety of sources,
including the burning of fossil fuels and biomass,
wildfires, and industrial processes. Short-lived climate
forcing pollutants and their chemical precursors can be
transported long distances and may produce particularly
harmful warming effects in sensitive regions such as the
Arctic.
SOURCES OF AIR POLLUTION
Air pollution consists of gas and particle contaminants
that are present in the atmosphere. Gaseous pollutants
include SO2, NOx , ozone, carbon monoxide (CO),
volatile organic compounds (VOCs), certain toxic air
pollutants, and some gaseous forms of metals. Particle
pollution (PM2 5 and PM10) includes a mixture of
compounds. The majority of these compounds can be
grouped into five categories: sulfate, nitrate, elemental
(black) carbon, organic carbon, and crustal material.
Some pollutants are released directly into the
atmosphere. These include gases, such as SO2, and
some particles, such as crustal material and elemental
carbon. Other pollutants are formed in the air.
Ground-level ozone forms when emissions of NO
X
and VOCs react in the presence of sunlight. Similarly,
some particles are formed from other directly emitted
pollutants. For example, particle sulfates result from
SO2 and ammonia (NH3) gases reacting in the
EMISSIONS INCLUDED IN THIS REPORT
PM emissions include directly emitted partic es only. This report
does not include gaseous emissions that condense in coo er
air (i.e., condensibles) that form particles or emissions from fires
and resuspended dust. Note that the emissions do not include
secondarily formed pollutants resulting from other directly
emitted pollutants.
SO NO , VOCs, CO, and lead emissions originate from
human activity sources only.
NH3 emissions primarily result from animal livestock operations
and are estimated using population data (e.g., cattle, pigs,
poultry) and management practices.
2008 emissions from industry were derived from the 2005
emissions inventory, except for SO and NO emissions, which
were derived from measured data from electric utilities.
Highway vehicle emissions were based on emissions
measurements from vehicle testing programs.
Emissions data were compiled using the best methods and
measurements available at the time.
Our Nation's Air
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Air Pollution
atmosphere. Weather plays an important role in the
formation of secondarily formed air pollutants, as
discussed later in the Ozone and Particle Pollution
sections.
EPA tracks direct emissions of air pollutants and
emissions that contribute to the formation of key
pollutants, also known as precursor emissions.
Emissions data are compiled from many different
organizations, including industry and state, tribal, and
local agencies. Some emissions data are based on actual
measurements while others are estimates.
Generally, emissions come from large stationary fuel
combustion sources (such as electric utilities and
industrial boilers), industrial and other processes
(such as metal smelters, petroleum refineries, cement
kilns, manufacturing facilities, and solvent utilization),
and mobile sources including highway vehicles and
non-road sources (such as recreational and construction
equipment, marine vessels, aircraft, and locomotives).
Sources emit different combinations of pollutants.
For example, electric utilities release SO2, NOx , and
particles.
Figure 2 shows the distribution of national total
emissions estimates by source category for specific
pollutants in 2008. Electric utilities contribute about
70 percent of national SO2 emissions. Agricultural
operations (other processes) contribute over 80 percent
of national NH3 emissions. Almost 50 percent of the
national VOC emissions originate from solvent use
(other processes) and highway vehicles. Highway
vehicles and non-road mobile sources together
contribute approximately 80 percent of national CO
emissions. Pollutant levels differ across regions of the
country and within local areas, depending on the size
and type of sources present.
Fossil fuel combustion is the primary source
contributing to CO2 emissions (not shown in Figure 2).
In 2007 (the most recent year for which data are
available), fossil fuel combustion contributed almost
94 percent of total CO2 emissions (source: http://
epa.gov/climatechange/emissions/usinventoryreport.
html). Major sources of fossil fuel combustion include
electricity generation, transportation (including
personal and heavy-duty vehicles), industrial processes,
residential, and commercial. Electricity generation
contributed approximately 42 percent of CO2 emissions
from fossil fuel combustion while transportation
contributed approximately 33 percent.
Primary sources of CH4 emissions (not shown) include
livestock, landfills, and natural gas systems (including
wells, processing facilities, and distribution pipelines).
In 2007, these sources contributed about 64 percent
of total U.S. CH4 emissions. Other contributing
sources include coal mining (10 percent) and manure
management (8 percent).
Direct PM
Direct PM
"c
ra
"o
Q.
Percent of Emissions
Source Category
Stationary Industrial and Highway Non-Road
Fuel Combustion Other Processes Vehicles Mobile
Figure 2. Distribution of national total emissions estimates by source category for specific pollutants, 2008.
Our Nation's Air
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TRACKING POLLUTANT
EMISSIONS
Since 1990, national annual
air pollutant emissions have
declined, with the greatest
percentage drop in lead
emissions. NH3 shows the
smallest percentage drop (six
percent), while direct PM2 5
emissions have declined by
over one-half, PM10, NOx , and
VOC emissions have declined
by over one-third, and SO2 and
CO emissions have declined by
almost one-half, as shown in
Table 1.
Table 1. Change in annual national emissions
per source category (1990 vs. 2008) (thousand tons).
Source Category PM,, PMln NH, SO, NO VOC CO Lead
+43
Percent Change
(1990 vs. 2008)
,346
-58% -39%
-446
+ 153
-439
+474
-442
-50% -36% -35% -53% -79%
The combined emissions of the
six common pollutants and their precursors (PM25 and PM10, SO2, NOx , VOCs, CO, and lead) dropped 41 percent
on average since 1990, as shown in Figure 3. This progress has occurred while the U.S. economy continued to grow,
Americans drove more miles, and population and energy use increased. These emissions reductions were achieved
through regulations and voluntary partnerships between federal, state, local, and tribal governments; academia;
industrial groups; and environmental organizations. There was a notable reduction in vehicle miles traveled and
energy consumed from 2007 to 2008. Factors likely contributing to this reduction include the nationwide spike in
gasoline prices during 2008 and the economic recession that began in 2008. Figure 3 also shows total CO2 emissions
increasing by about 20 percent from 1990 to 2007 (http://epa.gov/climatechange/emissions/usinventoryreport.html).
Domestic Product
Aggregate Emissions
(Six Common Pollutants)
r
95 96 97 98 99 00 01 02 03 04 05 06 07 08
Figure 3. Comparison of growth measures and emissions, 1990-2008.
Note: CO emissions estimates are from 1990 to 2007.
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SIX COMMON
ANTS
To protect public health and the environment, EPA has
established, and regularly reviews, national air quality
standards for six common air pollutants also known
as "criteria" pollutants: ground-level ozone, particle
pollution (PM25 and PM10), lead, nitrogen dioxide
(NO ), carbon monoxide (CO), and sulfur dioxide
(S02).
TRENDS IN NATIONAL AIR QUALITY
CONCENTRATIONS
Monitors across the country measure air quality.
Monitored levels of the six common pollutants show
improvement since the Clean Air Act was amended
in 1990. Figure 4 shows national trends between 1990
and 2008 in the common pollutants relative to their air
quality standards. Most pollutants show a steady decline
throughout the time period. Lead declined in the
1990s because all lead was removed from automotive
gasoline and stationary source control programs were
implemented to lower concentrations in areas above
the national standard (year-to-year fluctuations in lead
concentrations are influenced by emissions changes
due to operating schedules or other industrial facility
activities, such as plant closings, on measurements
at nearby monitors). The trend for lead shown in
Figure 4 is relative to the decision announced by EPA
on October 15,2008, to strengthen the standard to
0.15 |ig/m3 (maximum three-month average) from
1.5 |ig/m3 (maximum quarterly average). Ozone and
PM2 5 trends are shown relative to standards that were
revised in 2008 and 2006, respectively. These trends
are not smooth and show year-to-year influences of
weather conditions that contribute to the formation,
dispersion, and removal of these pollutants from the
air. Ozone was generally level in the 1990s and showed
a notable decline after 2002, mostly due to oxides of
nitrogen (NO ) emissions reductions in the East.
Many areas still have air quality problems caused by
one or more pollutants. Ozone and particle pollution
continue to present air quality challenges throughout
much of the U.S., with many individual monitors
measuring concentrations above, or close to, national
air quality standards.
400%
200%
Ozone, 547 monitors (4lh maximum 8-hour average)
PM25l 682 monitors (98"1 percentile)
PM25, 682 monitors (annual average)
PM10, 325 monitors (2nd maximum 24-hour average)
Lead, 64 monitors (maximum 3-month average)
NO2, 151 monitors (annual average)
CO, 206 monitors (2nd maximum 8-hour average)
SO2, 266 monitors (annual average)
-100%
90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07 08
Figure 4. Comparison of national levels of the six common pollutants to the most recent national ambient air
quality standards, 1990-2008. National levels are averages across all monitors with complete data for the time
period.
Note: Air quality data for PM25 start in 1999.Trends from 2001 though 2008 (using the larger number of monitors operating since 2001) are
the focus of graphics in the following sections.
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ENVIRONMENTAL JUSTICE
Integrating environmental justice into our programs
and regulatory process is one of EPA's top
priorities. We're working to ensure that people of
all races, cultures, and incomes are treated fairly
and benefit equally from EPA's actions to protect
public health and the environment. The agency
recognizes that improving environmental health
at the local level will bring economic and socia
benefits to the entire community.
To get an accurate picture of local air quality
and sources of emissions that are of major
concern, some communities have performed local
assessments. Understanding the risks at the local
level enables communities to target problem areas
and tailor emissions reduction strategies that will
improve air quality. EPA has been working in partnership with the West Oakland Toxic Reduction Collaborative to identify
and address sources of pollution that are harming public health. West Oakland, CA, is a low-income community of 25,000
people, approximately 90 percent of whom are people of color. West Oakland is impacted by emissions from traffic and
the transport of goods and produce. The efforts of the Collaborative, EPA Region 9, and a host of community organizations
have resulted in a commitment from the Port of Oakland to reduce risk from port-related diesel pollutants by 85 percent by
2020 and to support cleanup of the fleet of 2,000 heavy duty trucks serving the Port. Community partners include the local
health department, labor unions, the West Oakland Commerce Association, environmental advocacy organizations, the
University of San Francisco, elected officials, and many other organizations.
The Collaborative's accomplishments include setting up a "truck information center" to facilitate compliance by more than
2,000 truckers with new state truck standards. At least two industrial recyclers are working with the Collaborative's Land
Use work group to relocate their operations out of residentia areas into industrial areas in order to reduce toxics exposure
while retaining businesses in the community. Dozens of households have been trained on indoor air quality and assessment
and control by way of the Healthy Homes work group. The Health Impacts Assessment (HIA) work group piloted two
applications on an HIA methodology; one at a senior center, which resulted in mitigation measures. The Alternative Fuels
work group facilitated the piloting of a dozen applications of alternative fuels including biodiese and compressed natural
gas.
One of the resources used by the Collaborative is the Community Action for a Renewed Environment grant program, which
offers communities an innovative way to address risks from multiple sources of toxic air pollutants. EPA offers other kinds
of support to help inform and empower citizens to make local decisions concerning the health of their communities. For
example, EPA maintains the Air Toxics Community Assessment and Risk Reduction Projects database to inform communities
about past community-level air toxics assessments and lessons learned (http://www.epa.gov/ttn/atw/urban/mainwks.
html). EPA has also engaged many communities in its Collision Repair Campaign (CRC), a voluntary program that reduces
and eliminates harmful air toxics from collision repair and/or auto body shops across the nation. These sources affect many
environmental justice communities. The CRC has trained over 750 people, representing close to 500 repair shops. EPA
estimates that the CRC has reduced volatile organic compound emissions by 31 tons and particle emissions by 40 tons in
2008.
Through efforts like these, EPA can build on the progress we've made so far, accelerate environmenta improvements, and
ensure communities that are behind catch up - and continue to keep pace.
Our Nation's Air
9
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Six Common Pollutants
AIR QUALITY IN NONATTAINMENT
AREAS
Under the Clean Air Act, EPA and state, local, and
tribal air quality planning agencies work together to
identify areas of the U.S. that do not meet the EPA's
National Ambient Air Quality Standards (NAAQS).
These areas, known as nonattainment areas, must
develop plans to reduce air pollution. Each year, EPA
tracks air quality progress in nonattainment areas
by reviewing changes in measured concentrations
with respect to the standards. Table 2 identifies the
nonattainment areas throughout the U.S. and shows
how many of these areas were above or below one or
more of the standards as of 2008.
Over time, air quality has improved in nonattainment
areas for all six common pollutants. All of the
areas designated as nonattainment for CO, SO2,
and NO2 showed air quality levels below their
respective standards as of December 2008. Only two
nonattainment areas were above the original standard
for lead (1.5 |ig/m3)—Herculaneum and Dent
Township, MO. For ozone, annual PM2 5, and PM10,
a number of areas were still exceeding the standards:
31,21, and 18 areas, respectively. Furthermore, 31
new areas were designated as nonattainment with
the revised 24-hour PM25 standard in October 2009.
Figure 5 shows trends for average concentrations of
particle pollution and ozone in those nonattainment
areas. Although many areas were still above the
standard in 2008, there have been improvements in the
Pollutant
Standard
Year Number of
NAAQS Nonattainment
Established Areas
Number of These
Nonattainment Areas
Still Above NAAQS
Levels in 2008
Ozone (8-hour)
Annual PM0 c
2.D
24-hour PM25
24-hour PMlo
Lead (max
quarterly)
Annual NO2
CO (8-hour)
Annual SO
1997
1997
2006
1987
1978
1985
1985
1987
113
39
31
87
13
1
43
54
31
21
31
18
2
0
0
0
Table 2. Status of original nonattainment areas
for one or more standards as of 2008.
Notes: Designations for the recently revised standard
for lead (2008) are to be determined and therefore are
not included in this table. Depending on the form of the
standard, this table and the graphic below compare data from
one, two, or three years with the level of the standard. For
information about air quality standards, visit http://www.epa.
gov/air/criteria.html. For information about air trends design
values, visit http://www.epa.gov/air/airtrends/values.html.
The current status of all designated nonattainment areas
can be found at the EPA Green Book website (http://www.
epa.gov/oar/oaqps/greenbk/). Nonattainment area maps
for 8-hour ozone (based on the 1997 ozone standard) and
PM25 (based on the 1997 PM25 standard) can be generated
from information on the GIS download area of the website
(http://www.epa.gov/oar/oaqps/greenbk/gis_download.
html).
Figure 5. Air quality trends in nonattainment
areas above the NAAQS in 2008.
E 0.098-
o ^ 0.090-
J= CD
OD g 0.082-
0 0.075-
21
_ E
5 O)
19-
17-
15
50-
45-
40
35
750-
550
350-
150-
31 areas
21 areas
31 areas
18 areas
i o
Our Nation's Air
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concentration levels in the nonattainment areas. For
example, between 2000 and 2008, ozone areas showed a
7 percent improvement, and annual PM2 5 areas showed
an 11 percent improvement.
Despite these improvements, many areas still have work
to do. It is important to note that EPA periodically
reviews the standards, and their scientific basis, and
revises the standards as appropriate to protect public
health and the environment. This means that although
areas may be making progress in reducing air pollution,
over time they may need to implement additional
control measures to meet new air quality standards. In
addition, some areas that met previous standards may
now need to implement controls to meet new, more
protective standards.
NATIONAL AMBIENT AIR QUALITY STANDARDS (NAAQS)
common air
ir pollutants:
The Clean Air Act requires EPA to set two types of NAAQS for the six
1. Primary standards protect public health with an adequate margin of safety, including the health of at-risk populations
such as asthmatics, children, and older adults.
2. Secondary standards protect public welfare from adverse effects, including visibility impairment and known or
anticipated effects on the environment (e.g., vegetation, soils, water, and wildlife).
The Clean Air Act requires periodic review of the standards and the science upon which they are based. The standards as
of October 2009 are shown below, along with the date the most recent review was completed.
Pollutant Primary Standard(s) Secondary Standard(s) ltd
Ozone1
PM25
PM,0
Lead
NO2
CO
S02
0.075 ppm (8-hour)
15 ug/m3 (annual)
35 ug/m3 (24-hour)
150 ug/m3 (24-hour)
0.15 ug/m3 (3-month)
0.053 ppm (annual)
9 ppm (8-hour)
35 ppm (1-hour)
0.03 ppm (annual)
0.14 ppm (24-hour)
Same as primary
Same as primary
Same as primary
Same as primary
Same as primary
None; no evidence of
adverse welfare effects at
current ambient levels
0.5 ppm (3-hour)
2008
2006
2006
2008
1996
1994
1996
1 On September 16, 2009, EPA announced that it is reconsidering the current levels of the ozone primary and secondary standards.
Units of measure are parts per million (ppm) or micrograms per cubic meter (ug/m3) of air. For more information about the
standards, visit http://www.epa.gov/air/criteria.html.
Our Nation's Air
1 1
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Six Common Pollutants
PROCESS FOR REVIEWING AIR QUALITY STANDARDS
HUMAN HAIR
50-70 urn
(microns) in diameter
CPM2.5
Combustion particles, organic
compounds, metals, etc.
< 2.5 (im (microns) in diameter
Before new standards are established, EPA compiles and evaluates the latest scientific knowledge to assess the health
and welfare effects associated with each pollutant. Based on this scientific assessment, EPA staff prepare risk and policy
assessments regarding the potential need to revise the standards to ensure that they protect public health with an adequate
margin of safety and that they protect the environment and public welfare from known or anticipated adverse effects. These
assessments undergo rigorous review by the scientific community, industry, public interest groups, the genera public, and an
independent review board of external experts known as the Clean Air Scientific Advisory Committee (CASAC) before any
decisions are made by the EPA Administrator.
The history of EPA's nationa ambient air quality standards for particulate matter provides an excellent example of how this
iterative review process leads to
changes to the standards over
time. EPA first established air
quality standards for particulate
matter (PM) in 1971. These
standards limited the amount of
Total Suspended Particulate (TSP)
in ambient air. They were not
significantly revised until 1987,
when EPA changed the standard to
focus on inhalable particles smaller
than, or equal to, 10 microns in
diameter (PMJ. In 1997, EPA
established new standards for fine
partic es smaller than 2.5 microns
in diameter (PM25). This decision
was based on new evidence
linking these smaller particles to
serious health problems including
premature death, aggravation of
respiratory and cardiovascular
disease, and increased respiratory symptoms. At that time, EPA also retained the standards for PM10 to ensure continued
protection against the effects of exposure to coarse particles. In 2006, based on the latest scientific information, EPA
revised the 24-hour standard for PM25 while retaining the annua PM25 standard set in 1997 Furthermore, EPA retained the
24-hour standard for PM10 but revoked the annual PM10 standard because available evidence no longer suggested a link
between long-term exposures to ambient concentrations of coarse particles and adverse health effects.
Dust, pollen, mold, etc.
<10 Jim (microns) in diameter
90 nm (microns) in diameter
FINE BEACH SAND
Image courtesy ot the U.S. EPA
1 2
Our Nation's Air
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TRENDS IN "UNHEALTHY'
QUALITY DAYS
AIR
The Air Quality Index (AQI) relates daily air
pollution concentrations for ozone, particle pollution,
NO2, CO, and SO2 to health concerns for sensitive
groups and for the general public. A value of 100
generally corresponds to the national air quality
standard for each pollutant. Values below 100
are considered satisfactory. Values above 100 are
considered unhealthy—first for certain sensitive
groups of people, then for everyone as the AQI values
increase.
Figure 6 shows the number of days on which the
AQI was above 100 for selected metropolitan
areas from 2001-2008. All areas experienced fewer
unhealthy days in 2008 compared to 2001. However,
Cleveland, Sacramento, San Diego, Dallas, and San
Francisco experienced more unhealthy days in 2008
than in 2007. All of the increases in unhealthy days
are due to ozone and/or particle pollution. Weather
ERA'S AIR QUALITY INDEX (AQI)
Air Quality Index Levels of Health Concern
{AQI) Values
0 to 50 Good
51-100 Moderate
101 -150 Unhealthy for Sensitive Groups
AIR QUALITY INDEX
http://www.airnow.gov
conditions, as well as emissions, contribute to ozone
and particle pollution formation. Many areas in the
Midwest and eastern U. S. experienced fewer unhealthy
days in 2008 compared to 2007, mostly due to weather
conditions less conducive to ozone formation in these
areas in 2008.
10 Rttsburgh O , ,
New York
^ Columbus
ndianapolis •
m U-^m
8P Cincinnati
11
MLK
Baltimore
24
• • 31 __-
-•..- >• Washington
Charlotte ^fl
• - 30
*14 I • •/
• Atlanta J
2001 2002 2003 2004 2005 2006 2007 2008
5
Figure 6. Number of days on which AQI values were greater than 100 during 2001-2008 in selected cities.
Our Nation's Air
1 3
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Ozone is a molecule composed of three oxygen atoms.
It is formed throughout the lower part of the Earth's
atmosphere through a series of chemical reactions
involving sunlight and ozone precursors such as volatile
organic compounds (VOCs) and oxides of nitrogen
(NOx). Carbon monoxide (CO) and methane (CH4)
also contribute to ozone formation. These precursors are
emitted from a variety of man-made sources including
industrial facilities, power plants, landfills, and motor
vehicles. Precursor emissions from natural sources such
as lightning, soil, and trees also contribute to ozone
formation. Ozone at ground level is associated with
adverse health and welfare effects, and EPA has set
national standards and designed control programs
to protect against this "bad" ozone (see Figure 7).
Additionally, ozone occurring throughout the
tropospheric (lower) region of the Earth's atmosphere
acts as a greenhouse gas (GHG), trapping heat from
the sun and warming the Earth's surface. Ozone that
occurs higher up in the stratospheric region of the
atmosphere is generally natural in origin and forms
a protective layer that shields life on Earth from the
sun's harmful rays. EPA works to protect this "good"
ozone in the upper atmosphere through regulations on
ozone-depleting substances like chlorofluorocarbons
(CFCs).
rotective Ozone Layer
6 miles
Smog (Bad Ozone)
Figure 7. Ozone occurs both in the Earth's upper atmosphere (stratosphere) and at ground level (troposphere).
Most of the adverse health and environmental effects of ozone are associated with ozone in the troposphere,
while ozone in the stratosphere actually protects the Earth from harmful solar radiation.
1 4
Our Nation's Ai
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TRENDS IN GROUND-LEVEL OZONE
CONCENTRATIONS
Nationally, ground-level ozone concentrations were
10 percent lower in 2008 than in 2001, as shown in
Figure 8. The trend showed a notable decline after
2002. Though concentrations in 2008 were among the
lowest since 2002, many areas measured concentrations
above the 2008 national air quality standard for
ozone (0.075 ppm). When comparing two three-year
periods (2001-2003 and 2006-2008), 97 percent of
the sites show a decline or little change in ozone
concentrations, as shown in Figure 9. Sites that showed
the greatest improvement were in or near the following
metropolitan areas: Anderson, IN; Chambersburg, PA;
Chicago, IL; Cleveland, OH; Houston, TX; Michigan
City, IN; Milwaukee, WI; New York, NY; Racine, WI;
Watertown, NY; and parts of Los Angeles, CA.
However, other parts of Los Angeles showed a notable
increase in ground-level ozone concentrations. Ozone
trends can vary locally, as shown by the presence of
increases and decreases at nearby sites.
Twenty-three sites showed an increase of greater than
0.005 ppm. Of the 23 sites that showed an increase,
12 sites measured concentrations above the 2008 ozone
standard in the 2006-2008 time period.1 These sites
are located in or near the following metropolitan areas:
Atlanta, GA; Baton Rouge, LA; Birmingham, AL;
Denver, CO; El Centre, CA; Los Angeles, CA; San
Diego, CA; and Seattle, WA.
0.12
E
Q.
Figure 8. National 8-hour ozone air
quality trend, 2001-2008 (average of
annual fourth highest daily maximum
8-hour concentrations in ppm).
« 0.08 -
g
'75 0.06-
| 0.04
o
0 0.02 H
Average 1050 sites
90 percent of sites are below this line.
I
Current National Standard (revised 2008)
10 percent of sites are below this line.
01 02 03 04 05 06 07
2001 to 2008: 10% decrease
08
Figure 9. Change in ozone
concentrations in ppm, 2001-2003 vs.
2006-2008 (three-year average of annual
fourth highest daily maximum 8-hour
concentrations).
Change in Concentration (ppm)
O Increase of 0.006 to 0.020 (23 Sites)
o Little Change +- 0.005 (385 Sites)
O Decrease of 0.006 to 0.020 (478 Sites)
O Decrease of more than 0.020 (13 Sites)
Puerto Rico
1 On September 16,2009, EPA announced it
would reconsider the 2008 ozone NAAQS, which
included primary and secondary standards of
0.075 ppm (8-hour average). EPA will propose any
revisions to the standards by December 2009 and
issue a final decision by August 2010.
Our Nation's Air
15
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Ozone
Figure 10 shows a snapshot of ozone concentrations in
2008. The highest ozone concentrations were located
in California. Note that the high concentration shown
in Wyoming occurred at one site due to an unusual
combination of local emission and atmospheric
conditions on a winter day. Thirty-two percent of all
sites were above 0.075 ppm, the level of the 2008
standard.
WEATHER INFLUENCES OZONE
In addition to emissions, weather plays an important
role in the formation of ozone. A large number of hot,
dry days can lead to higher ozone levels in any given
year, even if ozone-forming emissions do not increase.
To better evaluate the progress and effectiveness of
emissions reduction programs, EPA uses a statistical
model to estimate the influence of atypical weather on
ozone formation.
Concentration Range (ppm)
• 0.029 - 0.059 (89 Sites)
O 0.060 - 0.075 (722 Sites)
O 0.076 - 0.095 (336 Sites)
• 0.096-0.120(41 Sites)
Puerto Rico
Alaska
Figure 10. Ozone concentrations in ppm, 2008 (fourth highest daily maximum 8-hour concentration).
1 6
Our Nation's Air
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Figure 11 shows ozone trends for 2001 through 2008,
averaged across selected sites before and after adjusting
for weather. Across these selected sites, observed ozone
levels show a decrease of approximately eight percent
between 2001 and 2008, compared with a larger
decrease of approximately 11 percent after removing
the influence of weather variations. By examining the
data separately for California vs. the eastern U.S., it is
clear that the majority of the ozone improvement, after
adjusting for weather, occured in the East (on the order
of 15 percent).
The largest changes in both observed and
weather-adjusted ozone in the East occurred during the
period of 2002 to 2004 and was especially noticeable
between 2003 and 2004 for the weather-adjusted trend.
This relatively abrupt change in ozone levels coincides
with the large NOx emission reductions brought about
by implementation of the NOx SIP Call rule, which
began in 2003 and was fully implemented in 2004. This
significant improvement in ozone continues into 2008,
i.e., weather-adjusted levels in 2008 are the lowest over
the eight-year period. In 2007, weather conditions
contributed to higher than average ozone formation
in the East, as shown by the large difference between
adjusted and observed ozone. In contrast, 2008 showed
a small difference between adjusted and observed ozone
indicating that weather variation had less of an impact
on ozone formation.
0.075
I 0.070:
a.
c 0.065:
o
| 0.060-
c
§ 0.055
o
o 0.050:
c
g 0.045:
0.040
National Trend
157 Sites
2001 to 2008: 8% decrease (observed)
2001 to 2008: 11% decrease (adjusted)
01
02
03
04
05
06
07
08
Monitoring Sites
A Rural (CASTNET)
• Urban (AQS)
n ri7R
U.U i O
f 0.070-
s
c 0.065-
o
| 0.060-
c
| 0.055-
o 0.050-
c
£ 0.045-
o n^o
U.U'+U
0
California Trend
r~
2001 to 2008: 1%
2001 to 2008: 3%
1 02 03
•.
" ~- -*'"
increase (observed)
increase (adjusted)
04 05 06
10 Sites
^ <
07 0
— «• — Observed trend
O.C
| 0.070:
Q.
T 0.065-
o
| 0.060:
c
I 0.055:
o :
% 0.050:
N 0.045:
0.040
Eastern U.S. Trend
80 Sites
2001 to 2008: 9% decrease (observed)
2001 to 2008: 15% decrease (adjusted)
01 02 03
Adjusted trend
04
05
06
07
08
Figure 11. Trends in average summertime daily maximum 8-hour ozone concentrations in ppm (May-September),
before and after adjusting for weather nationally, in California, and in eastern states, and the location of rural and urban
monitoring sites used in the averages.
Notes: Urban areas are represented by multiple monitoring sites. Rural areas are represented by a single monitoring site. For more information about the Air Quality
System (AQS), visit http://www.epa.gov/ttn/airs/airsaqs. For more information about the Clean Air Status and Trends Network (CASTNET), visit http://www.epa.
gov/castnet/.
Our Nation's Air
1 7
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o
zone
OZONE'S EFFECTS ON CLIMATE
The Intergovernmental Panel on Climate
Change (IPCC) indicates that tropospheric
ozone is the third most important GHG after
carbon dioxide (CO2) and methane (CH4) in
terms of global average climate forcing, as shown
in Figure 12.
At any given location, the local ozone
concentrations are the sum of three separate
components: (1) ozone produced by local
emissions and meteorology, (2) transported
ozone produced elsewhere in the region, and
(3) ozone transported on hemispheric scales
(global background levels of ozone) (Dentener,
2004). The time scales and mechanisms for
ozone formation, transport, and destruction vary
across these three contributors. Local formation
typically occurs on the scale of hours, whereas
regional and hemispheric transport can occur
over days and weeks, respectively. Traditionally,
most efforts to improve ozone air quality have
been aimed at reducing the local and regional
1.6
LO fj?
§1
CM §
— o
'o •<-
o o
CU 0)
:g CD
CD O.
CD O „ „
QL O 0.4
1.2
0.8-
Carbon Dioxide Methane Tropospheric Ozone
Greenhouse Gas
Figure 12. Net radiative forcing (Watts per m2) associated with
the three most important GHGs, based on concentrations in 2005
compared to pre-industrial levels. As these GHGs increased,
absorption of radiation by these gases and consequent warming
of the atmosphere also increased. (Source: National Academy of
Sciences, 2005)
UNDERSTANDING THE CONTRIBUTION OF TROPOSPHERIC OZONE TO CLIMATE CHANGE
Ozone
greenhouse gases
(including ozone)
Sunlight heats
land and oceans
Heat radiates from
land and oceans
11) Sunlight absorbed by ozone warms ffie air.
(2) Sunlight absorbed by land and oceans warms ffie Earth's surface.
(3) Energy radiates from land and oceans to space.
(4) Most energy radiated from land and oceans is absorbed by greenhouse gases,
including ozone, which warm the air and re-radiate energy in all directions.
As solar energy passes
through the Earth's
atmosphere, some of it
is absorbed or scattered
by water vapor, aerosols,
clouds, and gases like ozone.
Tropospheric ozone warms
the atmosphere partly by
absorbing this direct and
reflected energy from the
sun (yellow in figure). Most
of the atmospheric warming
from tropospheric ozone
comes from absorption of
infrared energy radiated
back toward space from the
Earth's surface. The tendency
for ozone to absorb reflected
energy and "trap" heat is
especially significant over
surfaces such as ice and snow,
which normally reflect a arge
percentage of incoming so ar
radiation back to space.
1 8
Our Nation's Air
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Radiative forcing: The change in the energy balance
between incoming soar radiation and exiting infrared
radiation, typically measured in watts per square meter
(W/m2). Positive radiative forcing tends to warm the
surface of the Earth while negative forcing generally
leads to cooling.
contributions via controls of local VOC emissions
and local/regional NOx emissions. These efforts have
resulted in significant improvements in ground-level
ozone concentrations over the U.S. in recent years. It
should be noted that global background levels of ozone
are very important for climate considerations because
ozone formed from emissions in U.S. urban areas and
regions represents only a fraction of the overall global
ozone and its resulting impacts on warming. Global
ozone background levels are determined by global
emissions of CH4, CO, NOx, and VOCs, as well as
natural processes like lightning and transport from
the stratosphere. Numerous field studies have shown
that these global background ozone concentrations
can approach 40 ppb (Jacob, 2007) and have been
increasing in recent years (Parrish, 2009).
CONTROL STRATEGIES
Current U. S. ozone reduction strategies have tended
to focus on reducing peak concentrations rather than
background levels and have also focused more on
NO reductions than on reductions of other ozone
X
precursors in most locations. While such strategies
have been successful in reducing ground-level ozone
concentrations for the purpose of meeting the
National Ambient Air Quality Standards (NAAQS)
and protecting public health, it may be necessary to
re-evaluate these control programs for their impact on
climate.
Reducing the emissions of ozone precursors will
generally decrease ozone production and cool the
atmosphere. In some cases, however, reducing one
precursor by itself may not be sufficient. Reductions in
NOx alone, for example, increase the lifetime of CH4,
which has a warming influence on the atmosphere.
To be most beneficial for climate and air quality,
ozone reduction strategies involving NOx should also
target reductions in CH4, VOCs, and/or CO, which
contribute substantially to global background levels of
ozone (Quinn, 2008).
Our Nation's Air
1 9
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Particle pollution refers to two classes of particles—
fine and coarse. These classes are based in part on
long-established information about differences in
sources, properties, and atmospheric behavior. EPA has
set national standards to protect against the health and
welfare effects associated with exposures to fine and
coarse particles. Fine particles are generally considered
to be less than or equal to 2.5 micrometers (|im) in
aerodynamic diameter, or PM2 5. Coarse particles
are those between 2.5 and 10 |im in diameter. PM10
(particles generally less than or equal to 10 |im in
diameter) is the indicator used for the coarse particle
standard.
TRENDS IN PM25 CONCENTRATIONS
There are two national air quality standards for
PM25: an annual standard (15 |ig/m3) and a 24-hour
standard (35 u.g/m3). Nationally, annual and 24-hour
PM25 concentrations declined by 17 and 19 percent,
respectively, between 2001 and 2008, as shown in
Figure 13.
Annual
Figure 13. National PM2 s air quality
trends, 2001-2008 (annual average
concentration and 98th percentile of
24-hour concentration in ug/m3).
20
18
o
O
90 percent of sites are below this line. 766 sites
Current National Standard
10 percent of sites are below this line.
01 02 03 04 05 06 07 08
2001 to 2008: 17% decrease
q> 35--
24-hour |
O
O
50
45-
40 :
35
30-
25 :
20 :
15:
10:
5:
0
01
90 percent of sites are below this line.
766 sites
Current National Stanc
10 percent of sites are below this line.
02 03 04 05 06 07
2001 to 2008: 19% decrease
08
20
Our Nation's Ai
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For each monitoring location, the maps in
Figure 14 show whether annual and 24-hour PM25
concentrations increased, decreased, or stayed about
the same since the beginning of the decade. When
comparing two three-year periods, 2001-2003 and
2006-2008, almost all of the sites show a decline or
little change in PM2 5 concentrations. Sixteen sites in
California, Illinois, Indiana, Michigan, Ohio, Utah, and
West Virginia showed the greatest decreases in annual
PM25 concentrations. Four of the 565 sites showed
an increase in annual PM2 5 concentrations greater
than 1 |ig/m3. These sites were located in Montana,
Arizona, and Wisconsin. Of the four sites that showed
an increase in annual PM2 5 concentrations, none were
above the level of the annual PM2 5 standard for the
most recent three-year period of data (2006-2008). Five
sites in California, Montana, Oregon, Pennsylvania,
and Utah showed decreases greater than 15 |ig/m3 in
24-hour PM25 concentrations. Nineteen sites showed
an increase in 24-hour PM25 concentrations greater
than 3 |ig/m3. Of the 19 sites that showed an increase
for the most recent three-year period of data, seven
measured concentrations above the level of the 24-hour
PM2 5 standard. These sites are located in or near the
following metropolitan areas: Virginia Beach, VA;
Butte-Silver Bow, MT; Nogales, AZ; Seattle, WA;
Albany, GA; Redding, CA; and Chico, CA (note:
Virginia Beach was above the standard due to the
effects of a wildfire in North Carolina). Due to the
influence of local sources, it is possible for sites in the
same general area to show opposite trends, as in the
case of the Denver area for the 24-hour standard.
Annual
Change in Concentration (jjg/m3)
O Increase of 1.1 to 3.4 (4 Sites)
o Little Change +-1 (234 Sites)
O Decrease of 1.1 to 3 (311 Sites)
® Decrease of more than 3 (16 Sites)
Puerto Rico
Figure 14. Change in PM2S
concentrations in ug/ni3, 2001-2003 vs.
2006-2008 (3-year average of annual
average and 98th percentile of 24-hour
concentrations).
24-hour
Change in Concentration (|jg/m3)
O Increaseof 3.1-21.6 (19 Sites)
o Little Change +- 3 (206 Sites)
O Decrease of 3.1 -11 (329 Sites)
O Decrease of 11.1 -15 (6 Sites)
0 Decrease of more than 15 (5 Sites)
Puerto Rico
Our Nation's Air
2 1
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Particle Pollution
In 2008, the highest annual average PM25
concentrations were in California, Arizona, and
Hawaii, as shown in Figure 15. The highest 24-hour
PM2 5 concentrations were in California and Virginia.
Wildfires played a role in both state's PM2 5 levels.
Some sites showed high 24-hour PM25 concentrations
but low annual PM concentrations, and vice versa.
Sites that show high 24-hour concentrations but low
or moderate annual concentrations exhibit substantial
variability from season to season. For example, sites
in the Northwest generally show low concentrations
in warm months but are prone to much higher
concentrations in the winter. Factors that contribute to
the higher levels in the winter are extensive woodstove
use coupled with prevalent cold temperature inversions
that trap pollution near the ground. Nationally, more
sites exceeded the level of the 24-hour PM25 standard
than the annual PM2 5 standard, as indicated by yellow
and red dots on the maps below. Of the 18 sites
that exceeded the annual standard and 55 sites that
exceeded the 24-hour standard, 14 sites exceeded both.
1 • I +•
V L 9! ^^.
^J^r~-*. •
Annual
Concentration Range (|jg/m3)
• 4.3-12.0 (610 Sites)
O 12.1 -15.0(221 Sites)
O 15.1 - 18.0 (13 Sites)
• 18.1 - 23.5 (5 Sites)
Puerto Rico
Figure 15. Annual average and 24-hour
(98th percentile of 24-hour concentrations)
PM2S concentrations in ug/m3,2008.
24-hour
Concentration Range (ijg/m3)
• 8-15(51 Sites)
O 16-35 (743 Sites)
O 36-55 (43 Sites)
• 56-97 (12 Sites)
Puerto Rico
22
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WEATHER INFLUENCES PM25
In addition to emissions, weather plays an important
role in the formation of PM25. Figure 16 shows trends
in PM25 from 2001 through 2008, before and after
adjusting for weather. PM2 5 levels are monitored
throughout the year, and separate graphs are shown
for the warm and cool months. These separate graphs
are shown due to the seasonal variability of the
components that make up PM25, as described in
the next section. After adjusting for weather, PM2 5
concentrations have decreased by approximately
17 percent in both the warm and cool seasons between
2001 and 2008.
^^_
E
qi
c
o
'•5
"£
0
o
c
0
o
J
n
10 -
16-
-
t
14-
-
12-
-in
Annual Trend
l^
"*" ^-«^ ^
**0^
2001 to 2008: 18%
2001 to 2008: 17%
82 Sites
^
•" X
~~** >* «L
*• " x
•x
decrease (observed)
decrease (adjusted)
01
02
03
04
05
06
07
08
Monitoring Sites
• Urban (AQS)
1 U
E"
1 16-
C
O
"CD
-g 14 -«
o
o
°» 12-
s1
0.
m -
Cool Months Trend 82 Sites
k
^ -
* *""~~-*-""""x
x __ *.
2001 to 2008: 20% decrease (observed) " "- <
2001 to 2008: 17% decrease (adjusted)
1 O ~
E
1 16-
c
0
^5
•g 14-
o
c
o
"«, 12-
i .>
LL
-in
Warm Months Trend 82 Sites
-^ "^ ^^ **^ \
X X* x.
^ •- _ __ ' x^ ^
X
X
1
2001 to 2008: 17% decrease (observed)
2001 to 2008: 17% decrease (adjusted)
01 02 03 04 05 06 07 08
— ••• — Observed trend
01 02 03
Adjusted trend
04
05
06
07
08
Figure 16. Trends in annual, cool-month (October—April) and warm-month (May—September) average PM2 s concentrations
in ug/m3 (before and after adjusting for weather), and the location of urban monitoring sites used in the average.
Our Nation's Air
23
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Particle Pollution
PM25 COMPOSITION
The chemical composition of PM25 is characterized in
terms of five major components that generally comprise
the mass of PM2 5: sulfate, nitrate, organic carbon
(OC), elemental carbon (also called black carbon, BC),
and crustal material.
Figure 17 shows regional differences in the composition
of PM25 nationwide. On average, sulfate is the largest
component by mass in the eastern U. S. Generally, the
largest sources of sulfate in the eastern U. S. are electric
utilities and industrial boilers. OC is the next largest
component in the East. The primary sources of OC
are highway vehicles, non-road mobile, waste burning,
wildfires, and vegetation. Next is nitrate; the largest
sources of nitrate originate from highway vehicles,
non-road mobile, electric utilities, and industrial
boilers. Elemental carbon is a small component of the
overall PM25 composition (typically 5-10 percent in
U.S. cities). Elemental carbon is directly emitted from
incomplete combustion processes such as fossil fuel and
biomass burning. Crustal material is typically a small
fraction of PM2 5 mass, although two cities show higher
than average values (Birmingham, AL and Detroit,
MI). Crustal material comes from suspended soil and
metallurgical operations.
In the West, OC is generally the largest estimated
component of PM2 5 by mass. Fireplaces and
woodstoves are important contributors to OC in the
West. On an annual average basis, nitrate, sulfate,
or crustal material can also represent substantial
components of PM2 5 for the western U. S. The
composition varies from city to city and may vary by
geography. For example, in southern California and
port cities in the Northwest, emissions from marine
vessels also likely contribute a significant portion of
PM25 sulfate.
Riverside
V.
v
Angeles
SulfateM Nitrated Elemental Carbon
Organic Carbon •Crustal
Figure 17. Four-season average of PM2S composition for 15 U.S. cities.
24
Our Nation's Air
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The maps in Figure 18 reveal somewhat different
patterns between seasons. While sulfate is a major
component in the eastern U. S. in the spring, fall, and
(particularly) summer, the sulfate contribution during
winter is offset by larger amounts of nitrate in the
Midwest and OC in the Southeast. Nitrate is lower
in the spring and fall, particularly in the southeastern
cities and is essentially zero during the summer in
the eastern U. S. Crustal material is a substantial
summertime component in Houston, TX, and is
generally low elsewhere in the East during all seasons.
In the West, wintertime OC and elemental carbon are
generally the largest components of PM2 5, followed by
nitrate. Nitrate can represent a larger percentage in the
spring and fall. Crustal material represents a relatively
high percentage year-round in arid Phoenix, AZ and
Denver, CO.
It is important to note that although studies have
begun to focus on how different constituents of
particulate matter (PM) may affect health outcomes,
at this point there is no conclusive evidence that
any component is "harmless"—studies continue to
link numerous components to health effects and
the evidence does not support excluding any PM
component or source from regulation. Thus, though
different ambient mixtures of PM maybe observed
in different geographical areas and during different
seasons, EPA continues to regulate PM2 5 and PM10
by mass and most control strategies are designed to
reduce mass rather than individual components from
particular sources.
Summer (Jun.-Aug.)
Max. Min.
Sulfate™Nitrate™Elemental Carbon Total Mass /^ Q
Organic Carbon =»Crustal (ug/m3) v-'
24 6
Los
Angeles
Figure 18. PM s composition by season for 15 U.S. cities.
Our Nation's Air
25
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Particle Pollution
PARTICLES' EFFECTS ON CLIMATE
Particles have both direct and indirect effects on
climate. The direct effects come from particles'
ability to absorb and scatter light. The different
types of particles have different impacts on
climate: some warm (positive forcing); others cool
(negative forcing). The net effect for all particles in
the atmosphere is cooling, as scattering generally
dominates (National Academy of Sciences, 2005),
though effects can vary dramatically by region.
Particles also have important indirect effects
on climate. For example, different particles can
increase or decrease the reflectivity of clouds,
leading to cooling or warming effects. Particles
also influence cloud lifetime and precipitation, and
may affect droughts, rainfall, and stream flows.
However, there remains relatively high scientific
uncertainty about these indirect effects (National
Academy of Sciences, 2005).
As shown in Figure 19, the direct effects of
particles on climate are significant even when
compared to carbon dioxide (CO ), the most
important greenhouse gas. However, the direction
of the climate impact from particles (warming vs.
Carbon
Dioxide
§|
CM §
o) m
"o T~
o o
^~ -Q
CD tU
1 s.
T3 E
(0 O
c o
1 -
0.5 -
-0.5 -
Black
Carbon
Organic
Carbon Sulfates
Figure 19. Net radiative forcing (Watts per m2) associated with
the presence of different pollutants in the atmosphere, based on
concentrations in 2005 compared to pre-industrial levels. (Source:
Black carbon data [IPCC, 2007]. Carbon dioxide, organic carbon,
sulfates data [National Academy of Sciences, 2005].)
cooling) varies by particle type and location of emission, which
makes designing control strategies more challenging. Sources
emitting BC also emit OC and may emit NOx and SO2, all of
which form particles that tend to have a cooling effect. Thus,
while the health benefits of reducing all types of emissions
RETROFITTING DIESEL ENGINES
From the farm to the interstate highway to the neighborhood grocery store,
diesel engines are found in every corner of society. Despite EPA's stringent
diesel engine and fuel standards, which, for new engines, are being phased
in over the next decade, 20 million engines already in use continue to emit
relatively large amounts of oxides of nitrogen (NOX) and fine particulate matter
(PM25). Both of these pollutants contribute to serious health conditions, such as
asthma, and worsen heart and lung disease. In addition, diese engines emit
black carbon and carbon dioxide, which contribute to global climate change.
Fortunately, a variety of cost-effective technologies can dramatically reduce
harmful emissions, save fuel, and help our nation meet its c ean air and
sustainability goals. In 2000, to address the concerns of both new and existing
diesel engines, EPA created the National Clean Diesel Campaign (NCDC), a
partnership program that incorporates traditional regulatory approaches and
innovative non-regulatory approaches to achieve results.
In 2008, for the first time, Congress appropriated funding under the Energy
Policy Act of 2005 to reduce emissions from diesel engines in the nation's
existing fleet. In the first year of the program, the EPA's NCDC distributed $49.2
million to initiate diese emission reduction projects and programs across the country. In addition, the American Recovery
and Reinvestment Act of 2009 provided $300 million in new funding for national and state programs to support the
implementation of verified and certified diese emissions reduction technologies.
As a result of this funding and NCDC projects across the country, hundreds of thousands of tons of pollutants and air toxics
will be reduced over the lifetime of the program.
26
Our Nation's Air
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contributing to ambient PM are
relatively clear, the net climate impact
of PM emissions reduction strategies
will depend on the relative amounts
of each of these components reduced
from controlled sources.
TRENDS IN PM
CONCENTRATIONS
Nationally, 24-hour PM10
concentrations declined by 19 percent
between 2001 and 2008, as shown in
Figure 20.
c
o
03
O
O
O
160
140
120-
100-
80
60
40
20
0
Current National Standard 781 sites
90 percent of sites are below this line.
10 percent of sites are below this line.
01 02 03 04 05 06 07
2001 to 2008: 19% decrease
08
Figure 20. National PM10 air quality trend, 2001-2008
(second maximum 24-hour concentration in ug/m3).
UNDERSTANDING LINKAGES BETWEEN BLACK CARBON AND CLIMATE
Black carbon (BC) is emitted directly as a result of
incomplete combustion of fuels, generally from man-made
sources. Many BC partices are too small to be visible.
One-half to two-thirds of BC emissions in the U.S. come
from the burning of fossil fuels, while the remainder comes
from biomass burning. Unless specifically controlled, diesel
engines are major producers of BC.
BC emissions are a component of fine particle pollution,
which causes adverse health effects. BC emissions a so
lead to climate warming by absorbing incoming and
reflected sunlight in the atmosphere (direct effects) and
by darkening clouds, snow, and ice, thereby reducing
the reflection of light back into space (indirect effects).
Other effects may include changes in precipitation and
cloud patterns. The total climate impact of BC currently (l) •
in the atmosphere has been estimated to be anywhere
from 10 percent to more than 60 percent as large as the
climate impact from carbon dioxide (CO2). These effects
may be concentrated in regions such as the Arctic and
the Himalayas, where glaciers provide critical fresh water
reservoirs for nearly 1.3 billion people.
Reflecting Particles
Black Carbon (BC)
Snow
Actions taken to reduce emissions of BC could produce
almost immediate benefits for climate: while CO remains
in the atmosphere for decades to centuries, freshly emitted
BC is in the atmosphere for a very short time. Reducing BC
today may reduce climate forcing in the near term.
(]) Sunlight absorbed by BC particles warms the air.
(2) Other types of particles scatter or reflect light and
cool the atmosphere.
(3) Sunlight absorbed by BC and some other
particles on snow speeds up melting and results in less
sunlight reflected.
Considerable uncertainty remains regarding the levels of BC emissions from various sources, the transport of these
emissions around the globe, and the net impacts of BC and co-emitted pollutants such as organic carbon on the Earth's
energy balance and global climate patterns.
Our Nation's Air
27
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Particle Pollution
When comparing two 3-year periods, 2001-2003 and
2006-2008, most sites showed a decline or little change
in PM1(|, as shown in Figure 21. Twenty-seven sites
located in the Southwest, South Carolina, Missouri,
Wyoming, and Montana showed a decline greater
than 50 |ig/m3. Ninety-one sites showed an increase
of greater than 10 |ig/m3 over the trend period. Five
of these sites (Houston, TX; Albany, GA; Phoenix,
AZ; Butte-Silver Bow, MT; and Trinity County, CA)
showed large increases of 50 |ig/m3 or more.
Figure 22 shows that in 2008, the highest PM10
concentrations were located in California, Arizona, and
New Mexico. Within these areas some sites showed a
decline greater than 50 |ig/m3. Highest concentrations
are largely located in dry and/or industrial areas with a
high number of coarse particle sources.
Change in Concentration (|jg/m3)
O Increase of 10.1 to 105 (91 Sites)
o Little Change +- 10 (310 Sites)
O Decrease of 10.1 to 30 (108 Sites)
• Decrease of 30.1 to 50 (25 Sites)
0 Decrease of more than 50 (27 Sites)
Figure 21. Change in PM10
concentrations in ug/ni3, 2001-2003
vs. 2006-2008 (3-year average
of second maximum 24-hour
concentrations).
.
Puerto Rico
Alaska
Figure 22. PM10 concentrations
in ug/m3, 2008 (second maximum
24-hour concentration).
Note: 2563 (|ig/m3) is from a site located in
the Mono Basin nonattainment area where the
major source of PM10 is from a dry lake bed
(Mono Lake).
Concentration Range (\iglm )
• 2 - 54 (439 Sites)
O 55-154 (366 Sites)
O 155-255(21 Sites)
• 256-2563 (14 Sites)
Puerto Rico
Alaska
2 8
Our Nation's Air
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COOKSTOVE POLLUTION THREATENS PUBLIC HEALTH AND CLIMATE
An unvenfed, traditional stove in Ethiopia produces high indoor smoke levels for
a woman and young child. (Credit: John Mitchell, U.S. EPA)
Roughly half of the world's population-
especially in Asia, Africa, and parts of
Latin America-uses wood, dung, coa
or other solid fuels for cooking and
heating. This leads to extraordinarily
high indoor concentrations of fine
partice pollution, carbon monoxide,
and other toxic pollutants. The World
Health Organization estimates
that indoor stove use leads to an
estimated 1.5 million premature
deaths each year, mostly among
women and young children, making
it the fourth most serious health risk
factor in poor developing countries
after undernourishment, unsafe sex,
and unsafe water, sanitation, and
hygiene. Fuel wood collection also
limits economic and educationa
opportunities for women and children
and can put substantia pressure on
local forests and ecosystems.
Use of c ean and efficient cookstoves and fuels would significantly improve public health and could also provide important
climate benefits. It is estimated that an improved cookstove typically reduces carbon dioxide-equivalent emissions by 1 to
4 tons per year—almost as much as taking a typical U.S. car off the road. Crude, traditional cookstoves account for about a
quarter of global black carbon emissions, which contribute to regional and globa warming, though the net climate impact
also depends on co-emissions
of other (primarily reflecting)
partices.
In 2002, the EPA and
13 partners launched the
Partnership for Clean Indoor
Air (PCIA) to help households
adopt cean cooking and
heating practices to improve
health, livelihood, and
quality of life. Today, PCIA
has over 310 active partner
organizations working in
over 115 countries around
the world (http://www.
PCIAonline.org). Already,
key PCIA partners have
reported helping 2.4 million
households adopt clean
cooking and heating
practices, reducing harmful
exposures for more than
1 8 million people.
An improved plancha stove with a chimney in Guatemala significantly lowers indoor
smoke levels. (Credit: Richard Grinnell, HELPS International, http://www.helpsintl.org)
Our Nation's Air
29
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LEAD
TRENDS IN LEAD
CONCENTRATIONS
Concentrations of lead decreased 48 percent
between 2001 and 2008, as shown in
Figure 23. Average concentrations are shown
for 24 sites near large stationary sources
and 101 sites that are not near stationary
industrial sources. The typical average
concentration near a stationary source (e.g.,
metals processors, battery manufacturers,
and mining operations) is approximately
eight times the typical concentration at a
site that is not near a stationary industrial
source. There are significant year-to-year
changes in lead concentrations at sites near
stationary sources; these reflect changes
in emissions due to changes in operating
schedules and plant closings. For example,
lead concentrations declined between
2001 and 2002, mostly due to lower lead
concentrations at sites in Herculaneum,
MO.
Figure 24 shows lead concentrations in
2008. Of the 110 sites shown, 23 sites in 12
counties exceeded the 2008 lead standard
(0.15 |ig/m3). These sites are located in
Alabama, Florida, Illinois, Indiana,
Minnesota, Missouri, Ohio, Pennsylvania,
Tennessee, and Texas. All of these sites are
located near stationary lead sources. New
requirements for monitoring near additional
stationary lead sources will be implemented
in 2010. Approximately 250 new locations
will be monitoring lead concentrations.
— National Avg. (125 Sites)
^— Source Oriented Avg. (24 Sites)
Non-Source Oriented Avg. (101 Sites)
01 02 03 04 05 06 07
2001 to 2008: 48% decrease
Figure 23. National lead air quality trend, 2001-2008 (maximum
3-month average in ug/m3).
Note: 90 percent of sites are shown in the orange area.
08
Concentration Range (jjg/m3)
• 0.00 - 0.07 (79 Sites)
O 0.08-0.15 (8 Sites)
• 0.16-2.89 (23 Sites)
Figure 24. Lead concentrations
in ug/m3, 2008 (maximum
3-month averages).
Note: The number of sites in Figure 24 (110) differs from the number of sites in Figure 23 (125)
due to differences in the requirements for lead data to be considered complete for each figure.
Puerto Rico
EPA STRENGTHENS THE NATIONAL AMBIENT AIR QUALITY STANDARD FOR LEAD
On October 15, 2008, EPA strengthened the National Ambient Air Quality Standard for lead. The level for the previous lead
standard was 1.5 pg/m3, not to be exceeded as an average for a calendar quarter, based on an indicator of lead in total
suspended particles (TSP). The new standard, also in terms of lead in TSP, has a level of 0.15 pg/m3, not to be exceeded as
an average for any three-month period within three years.
In conjunction with the revision of the lead standard, EPA also modified the lead air quality monitoring rules. Ambient lead
monitoring is now required near lead emissions sources emitting one or more tons per year, and also in urban areas with a
population equal to or greater than half a million people. Monitoring sites are required to sample every sixth day.
30
Our Nation's Air
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TRENDS IN NO2/ CO, AND SO2
CONCENTRATIONS
Nationally, concentrations of nitrogen dioxide
(NO2) decreased 27 percent between 2001
and 2008, as shown in Figure 25. In 2008,
NO2 concentrations were the lowest of the
eight-year period. All recorded concentrations
were well below the level of the annual
standard (0.053 ppm).
Nationally, concentrations of 8-hour carbon
monoxide (CO) decreased 41 percent between
2001 and 2008, as shown in Figure 26. In
2008, CO concentrations were the lowest
0.06
0.05-
0.04-
323 sites
Current National Standard
90 percent of sites are below this line.
01
02
03 04 05 06 07
2001 to 2008: 27% decrease
Q_
_Q.
C
O
2
O
O
10
9
8-
7-
4-
3:
2-
1 -
332 sites
Current National Standard
90 percent of sites are below this line.
10 percent of sites are below this line.
01 02 03 04 05 06
2001 to 2008: 41% decrease
07
08
Figure 26. National CO air quality trend,
2001-2008 (second maximum 8-hour average in ppm).
10 percent of sites are below this line.
Figure 25. National NO2 air quality trend,
2001-2008 (annual average in ppm).
in the past eight years. All concentrations
were below the 8-hour standard (9 ppm) and
1-hour standard (35 ppm).
Nationally, concentrations of sulfur dioxide
(SO2) decreased 30 percent between 2001 and
2008, as shown in Figure 27. In 2008, annual
SO2 concentrations were the lowest of the
eight-year period. One site in Hawaii showed
concentrations above the level of the annual
standard (0.03 ppm) and two sites in Hawaii
showed concentrations above the level of the
24-hour standard (0.14 ppm). These high
measurements were caused by emissions from
a nearby volcano.
Downward trends in NO2, CO, and SO2
are the result of various national emissions
control programs. Even though concentrations
of these pollutants are low with respect to
national standards, EPA continues to track
these gaseous pollutants because of their
contribution to other air pollutants (e.g., ozone
and PM2 5) and reduced visibility. Additionally,
national ambient air quality standards for these
pollutants are under review.
u.uoa
Om
gO.025-
o 0.02-
cn
•g 0.015-
OJ
£ 0.01-
O
° 0.005-
•
415 sites
Current National Standard
90 percent of sites are below this line.
Average
10 percent of sites are below this line.
I
1
01
02
03
04
05
06
07
08
2001 to 2008: 30% decrease
Figure 27. National SO2 air quality trend, 2001-2008 (annual average in ppm).
Our Nation's Air
3 1
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TOXIC AIR POLLUTANTS
tf!
TRENDS IN TOXIC AIR POLLUTANT
CONCENTRATIONS
Under the Clean Air Act, EPA regulates 187 toxic
air pollutants. Toxicity levels, or the potential for
adverse effects on human health, vary from pollutant to
pollutant. For example, a few pounds of a relatively toxic
pollutant may have a greater health effect than several
tons of emissions of a less toxic pollutant. Toxicity levels
can vary by orders of magnitude between pollutants.
EPA recommends a set of benchmark toxicity levels for
estimating the effects of exposure to individual toxic air
pollutants. For more information, visit http://www.epa.
gov/ttn/atw/toxsource/tablel.pdf.
Because ambient monitoring data are so limited
for toxic air pollutants, EPA frequently relies on
ambient modeling studies to better define trends
in toxic air pollutants. One such modeling study,
the National-Scale Air Toxic Assessment (NATA),
is a nationwide study of ambient levels, inhalation
exposures, and health risks associated with emissions of
180 toxic air pollutants (a subset of the Clean Air Act's
list of 187 toxic air pollutants and diesel particulate
matter). NATA examines individual pollutant effects
as well as cumulative effects of many air pollutants on
human health.
Figure 28 shows the estimated lifetime cancer risk
across the continental U. S. by county based on 2002
NATA model estimates. The national average cancer
risk level in 2002 is 36 in a million. Many urban areas
as well as transportation corridors show a risk above
the national average. From a national perspective,
benzene is the most significant toxic air pollutant for
which cancer risk could be estimated, contributing
over 30 percent of the average individual cancer
risk identified in the 2002 assessment. Though not
included in the figure, exposure to diesel exhaust is
also widespread. EPA has not adopted specific risk
estimates for diesel exhaust but has concluded that
diesel exhaust is a likely human carcinogen and ranks
with the other substances that the national-scale
assessment suggests pose the greatest relative risk to
human health.
Median Risk Level
0-25 in a Million
26-50 in a Million
51 -75 in a Million
^•76 -100 in a Million
^•> 100 in a Million
Figure 28. Estimated
county-level cancer
risk from the 2002
National-Scale Air
Toxics Assessment
(NATA2002). Darker
colors show greater
cancer risk associated
with toxic air pollutants.
Puerto Rico
Alaska
32
Our Nation's Air
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Figure 29 shows the trends in ambient monitoring
levels for some of the important toxic air pollutants
identified by NATA. When the median percent change
per year (marked by an x for each pollutant shown)
is below zero, the majority of sites in the U.S. show
a decrease in concentrations. Ambient monitoring
data show that for some of the toxic air pollutants of
greatest widespread concern to public health (shown in
yellow), 1,3-butadiene, benzene, tetrachloroethylene,
and 1,4-dichlorobenzene, concentration levels are
declining at most sites. Concentrations of volatile
organic compounds (VOCs) such as 1,3-butadiene,
benzene, styrene, xylenes, and toluene decreased by
approximately 5 percent or more per year at more
than half of all monitoring sites. Concentrations of
carbonyls such as formaldehyde, acetaldehyde, and
propionaldehyde were equally likely to have increased
or decreased (another carbonyl of interest, acrolein, was
not reliably measured in 2000 so no trend is shown
for it). Chlorinated VOCs such as tetrachloroethylene,
dichloromethane, and methyl chloroform decreased at
more than half of all monitoring sites, but decreases
among these species were much less consistent from
site to site than among the other VOCs shown. Lead
particles decreased in concentration at most monitoring
sites; trends in other metals are less reliable due to the
small number of sampling sites available for analysis.
In 2003, in an effort to improve accuracy and
geographic coverage of monitoring, EPA, working with
its state and local partners, launched the National Air
Toxics Trends Station (NATTS) program, a national
monitoring network for toxic air pollutants. The
principal objective of the NATTS network is to provide
long-term monitoring data across representative areas
of the country for NATA priority pollutants (e.g.,
benzene, formaldehyde, 1,3-butadiene, acrolein, and
hexavalent chromium) in order to establish overall
trends. The initial 23 sites were established between
2003 and 2005; two sites were added in 2007 and
two more in 2008 for a total of 27 NATTS sites. In
addition, the list of pollutants monitored was expanded
to include polycyclic aromatic hydrocarbons (PAHs), of
which naphthalene is the most prevalent. In addition
to the NATTS program, about 300 monitoring
sites—operated by state, local, and tribal agencies—
are currently collecting data to help track toxic air
pollutants levels across the country.
Figure 29. Distribution of changes in ambient concentrations
at U. S. toxic air pollutant monitoring sites, 2000-2005
(percent change in annual average concentrations).
(Source: McCarthy M.C., Hafner H.R., Chinkin L.R., and
Charrier J.G. [2007] Temporal variability of selected air toxics
in the United States.dtmos. Environ. 41 [34], 7180-7194)
Notes: 10th and 90th percentiles are excluded if fewer than 10 monitoring
sites were available for analyses. For chloroform and nickel, the 90th percentile
percent changes per year are cut off at 30. TSP = total suspended participate.
1,4-Dichlorobenzene
Carbon Tetrachloride
Chloroform
Chloromethane
Dichloromethane
Methyl Chloroform
Tetrachloroethylene
Trich loroethy lene
1,3-Butadiene
2,2,4-Trimethylpentane
Benzene
Ethylbenzene
Isopropylbenzene
M-P-Xylenes
N-Hexane
O-Xylene
Styrene
Toluene
Acetaldehyde
Formaldehyde
Propionaldehyde
Lead (TSP)
Manganese (TSP)
Nickel (TSP)
VOCs
Carbonyls
Metals
X
-30 -20 -10 0 10 20 30
Percentage Change per Year
Median Percentage
Change/Year
lOth^H X 90th
Percentile Percentile
Our Nation's Air
33
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Pollution in the form of acids and acid-forming
compounds such as oxides of sulfur (SO ) and oxides of
nitrogen (NO ) can deposit from the atmosphere to the
Earth's surface. Figure 30 illustrates how this deposition
can occur through rain or snow (wet deposition), clouds
or fog (occult deposition), and gases and particles
(dry deposition). Nitrogen and sulfur interactions in
the environment are highly complex: while both are
essential nutrients for growth and productivity, excess
amounts of either nitrogen or sulfur can impair the
structure and function of ecosystems.
Some of the most serious impacts of excess nitrogen
and sulfur are acidification and nutrient enrichment—
an increase in nutrients available in the ecosystem.
This process is known as eutrophication in aquatic
ecosystems. Eutrophication involves excessive plant
growth and decay, which can lead to a lack of oxygen,
impairment of water quality, and damage to fish and
animal populations. Acidification causes a cascade
of effects in terrestrial and aquatic ecosystems such
as slower plant growth, injury or death of forest
vegetation, and localized extinction of fish and other
aquatic species. In some ecosystems, excess sulfur also
contributes to increased mercury methylation—the
transformation of mercury emissions into a highly toxic
form of mercury associated with a range of adverse
effects in humans and animals. Sources of mercury
emissions include coal combustion, municipal and
medical waste incineration, and mining of metals
for industry. More information about EPA's mercury
program can be found at http://www.epa.gov/mercury.
Wet Deposition/Acid Rain
Figure 30. Nitrogen (N) and sulfur cycling and interactions in the environment.
34
Our Nation's Ai
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TRENDS IN ATMOSPHERIC DEPOSITION
In recent decades, acid deposition in the U.S. has
declined significantly. Between 1989-1991 and
2006-2008, wet sulfate deposition decreased over
30 percent in the Northeast and Midwest, as shown in
Figure 31. In addition, wet nitrate deposition decreased
by about 30 percent in the Mid-Atlantic and Northeast
and 20 percent in the Midwest. These reductions have
led to the improvement of water quality in lakes and
streams.
Most of these improvements are due to reductions
in SO2 and NOx emissions from electric utilities and
industrial boilers. The Acid Rain Program and the NOx
SIP Call in the East have led to significant reductions
in SO2 and NOx
emissions.
• SO2 emissions from Acid Rain Program sources
have been reduced by more than 8 million tons
from 1990 levels, or about 52 percent. Compared
to 1980 levels, SO2 emissions from power plants
have dropped by almost 10 million tons, or about
56 percent. In 2008, annual SO2 emissions fell by
over 1,300,000 tons from 2007 levels.
• NOx emissions from sources subject to the NOX
SIP Call program have been reduced by about
4 million tons from 1990 levels so that emissions
in 2008 were less than half the level anticipated
without the Acid Rain and NO SIP Call
X
programs.
Despite significant progress, acid deposition remains
a challenge for many areas of the country. Deposition
WetSO4, 1989-1991
Wet S04, 2006-2008
Wet NO,, 1989-1991
Wet NO, ,2006-2008
Figure 31. Three-year average deposition of sulfate (wet SO/) and nitrate (wet NO3 ) in 1989-1991 and 2006-2008 in kg/ha.
Dots show monitoring locations. (Data source: National Atmospheric Deposition Program, http://nadp.sws.uiuc.edu)
Our Nation's Air
35
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Atmospheric Deposition
of both nitrogen and sulfur is generally higher in the
eastern U. S. than in the West. Fossil fuel combustion
and nitrogen fertilizer use contribute to relatively
high rates of nitrogen deposition in the East, with the
Midwest and Northeast generally experiencing the
highest levels of deposition. In the East, deposition
exceeding 18 kg sulfur per hectare per year occurs near
some SO2 sources, with high deposition particularly
notable along the Ohio River Valley extending across
Pennsylvania.
EPA is currently conducting a joint review of the
NOx and SOx secondary standards and looking at the
relationship between acid deposition and ecological
effects such as acidification and eutrophication. This
review, which is scheduled to be completed in 2012,
will address residual acid deposition in the U.S. Because
NO , SO , and their associated transformation
X ' X '
products are linked in terms of both atmospheric
chemistry and environmental effects, a joint assessment
of the scientific information, associated risks, and
standards is essential to ensuring appropriate
environmental protection.
DEPOSITION OF AIR POLLUTANTS TO THE CHESAPEAKE BAY
The Chesapeake Bay's airshed is an area containing air
pollutant emission sources that contribute 75 percent of
nitrogen deposited into the Bay and its watershed. Defined in
this manner, the Chesapeake Bay airshed is about 570,000
square miles, or seven times the size of the watershed.
Nitrogen and chemical contaminants from air pollution,
such as mercury and polychlorinated biphenyls (PCBs),
contribute to poor water quality in the region. Air pollution
is generated by a variety of sources including power plants,
industrial facilities, farming operations, and highway vehices
and non-road engines. About 34 percent of the amount of
nitrogen added to the Bay and its watershed on a yearly basis
(loading) comes from atmospheric deposition.
National air quality control programs for both stationary and
mobile sources, including the Clean Air Interstate Rule, the
Tier-2 Light Duty Vehicle Rule, the Non-Road Engine Rule,
the Heavy-Duty Diesel Engine Rule, and the Locomotive/
:
,
Atmospheric Deposition
to Watershed:
Agricultural Sources
6%
Atmospheric Deposition
to Tidal Waters:
All Sources
7%
Manure:
Agricultural Land
17%
Chemical Fertilizer:
Agricultural Land
15%
Atmospheric Deposition to
Watershed: Mobile, Utilities,
& Industrial Sources
20%
Atmospheric Deposition
to Watershed:
Natural Sources
1%
Municipal &
Industrial
Wastewater
20%
Septic Systems
4%
Chemical Fertilizer:
Developed Land
10%
Sources of nitrogen loading to the Bay
Chesapeake Bay airshed
Marine Engine Rule, are reducing nitrogen emissions
and, therefore, nitrogen deposition onto the Bay
and watershed. Data from 30 long-term monitoring
sites within the Chesapeake watershed (National
Atmospheric Deposition Program and Atmospheric
Integrated Research Monitoring Network) show
a decrease of about 30 percent in nitrate and
ammonium deposition from 1985 to 2005.
EPA estimates that by 2020, nitrogen deposition to the
Chesapeake Bay will decline 46 percent from 1985
levels.
3 6
Our Nation's Air
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VISIBILITY IN SCENIC AREAS
TRENDS IN VISIBILITY
EPA and the National Park
Service monitor visibility trends
in 155 of the 156 national parks
and wilderness areas, where clear
views are an important value for
visitors (i.e., Class I areas). States
are required to adopt progress
goals every ten years for improving
visibility, or visual range, from
baseline conditions (represented
by the five-year average conditions
between 2000 and 2004). The
ultimate goal is to achieve natural
background conditions, or
conditions which existed before
manmade pollution, by 2064. The
Regional Haze Rule, published in
1999, requires states to identify the
most effective means of preserving
conditions in Class I areas when
visibility is at its best—based on the
20 percent best or cleanest visibility
days monitored—and to gradually
improve visibility when it is most
impaired—based on the 20 percent
worst visibility days monitored.
Long-term trends indicate that
visibility is improving. Figure 32
shows this progress. A number
of Class I areas show improving
visibility or decreasing haze
(indicated by the downward
pointing arrows) for the worst
visibility days: Mt. Rainier
National Park, WA; Great Gulf
Wilderness, NH; Snoqualmie Pass,
WA; Olympia, WA; Columbia
Gorge, WA; Starkey OR; Presque
Isle, ME; and Bridgton, ME.
Only Hawaii Volcanoes National
Park shows increasing haze. Most
locations also show improving
visibility (decreasing haze) for the
best visibility days. Considerable
20% Worst Days
Trends in Visibility
T^ Increasing Haze
Possible Increasing Haze
c No Trend
Possible Decreasing Haze
Decreasing Haze
Figure 32. Trends in visibility on the 20 percent worst and best visibility
days, 1998-2007. (Source: National Park Service/Air Resources Division,
http://www.nature.nps.gov/air/)
Note: Visibility trends using a haze index for the annual average for the 20 percent best and worst
visibility days are based on aerosol measurements collected at Interagency Monitoring of Protected
Visual Environments (IMPROVE) monitoring sites. The haze index is measured in deciviews (dv),
a visibility metric based on the light extinction coefficient that expresses incremental changes in
perceived visibility. Sites having at least six years of complete data were used to compute the change in
dv per year over the trend period and its statistical significance.
Our Nation's Air
3 7
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Visibility in Scenic Areas
additional progress is needed to achieve natural
visibility. Implementation of the Regional Haze Rule
and other planned regulatory programs will reduce
emissions of visibility impairing pollutants and ensure
that the improvement in visibility continues.
States determine whether they are meeting their
visibility goals by comparing visibility conditions from
one five-year average to another (e.g., 2000-2004
to 2013-2017). The glide path to natural visibility
conditions in 2064 for the Shenandoah National Park
is shown in Figure 33 and demonstrates the minimum
rate of progress or improvement in visibility that
should occur over time to meet the goal of natural
conditions. In 2007, states were required to submit
plans demonstrating how they would achieve natural
visibility conditions by 2064. EPA requires monitoring
to verify that progress is being made to improve
visibility in the Class I areas.
35
0
Glide path
—Q— 5-year rolling average
2018 Target
25.1 dv
2064 Natural Background
11.4 dv
i (M •
CD CO O CN ^ CD CO i
CO CO O) CD CT> O) i
CD O5 O) O) O~> O) O) i
'OOOOOOOOO
ICMCNICMCNCNICMCSICMCM
CM •* CD '
CO CO CO i
O O O '
CM C\l CM i
i CM '
CM '
Figure 33. Glide path to natural conditions in 2064 for Shenandoah (deciviews) compared to
2000-2004 baseline conditions. (Source: Visibility Improvement State and Tribal Association of
the Southeast—VISTAS)
Notes: A change of one deciview (dv) is a change in visibility that is discernable. The figure shows a five-year rolling average
for the 20 percent worst visibility days.
• I
3 8
Our Nation's Air
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CLIMATE CHANGE AND AIR QUALITY
. \
CLIMATE AND AIR QUALITY
Climate and air quality are closely coupled. As discussed
in previous sections of this report, conventional
pollutants, such as ozone and particle pollution, not
only affect public health but also contribute to climate
change. Ozone is a significant greenhouse gas (GHG)
and particles can influence the climate by scattering,
reflecting, and/or absorbing incoming solar radiation
and interacting with various cloud processes (see
Ozone and Particle Pollution sections). Climate and
meteorology directly influence ambient concentrations
of particles and ozone, in part by affecting emissions of
precursors from natural sources such as plants and trees.
Thus, though climate and air quality are often treated
as separate issues, there are important interactions that
need to be considered and addressed.
Ozone and black carbon (BC) both affect public
health and climate. Their impacts differ from those of
long-lived GHGs because ozone and particle pollution
generally stay in the atmosphere for only a few days
or weeks. Therefore, these short-lived pollutants may
not travel as far and tend to be unevenly distributed
in the atmosphere. Long-lived GHGs like carbon
dioxide (CO2) persist in the atmosphere over decades
to centuries and eventually become fairly evenly
distributed throughout the Earth's atmosphere. Because
they persist, long-lived GHGs will continue to exert
influence over climate, meteorology, and air pollution
levels far into the future.
Because ozone and BC have short atmospheric
lifetimes, reducing these emissions has a strong,
immediate climate benefit. While controlling
long-lived GHGs is essential for addressing climate
effects in the long term, controlling short-lived climate
pollutants may be a good strategy to reduce the rate of
climate change in the near-term. Reducing short-lived
climate pollutants can supplement programs to reduce
the long-lived climate pollutants.
Given the links between climate and air quality, the
National Academy of Sciences (NAS) recommended in
its 2004 report, Air Quality Management in the United
States, that air pollution and climate change policies be
developed through an integrated approach. A number
of strategies being discussed for climate—energy
efficiency, renewable energy, and reducing the number
of vehicle miles traveled—will provide reductions
in emissions that contribute to multiple air quality
concerns such as ozone and particle pollution, toxic
air pollutants, atmospheric deposition, and visibility.
These kinds of approaches are "win-win,"providing
improvements to air quality while also reducing the
adverse risks and impacts associated with climate
change.
Our Nation's Ai
39
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Climate Change and Air Qjua 1 ity
RECENT TRENDS IN GREENHOUSE GAS
EMISSIONS AND CLIMATE
EPA, in collaboration with other government agencies,
tracks both changes in climate and changes in GHG
emissions. Figure 34 shows the trends in domestic
GHG emissions over time.Total U.S. emissions
increased 17 percent from 1990 to 2007. Primary
contributors to this increase include an increased
consumption of fossil fuels to generate electricity and
a significant decrease (14 percent) in hydropower
generation (electric power generated using water
power) used to meet this demand.
A number of EPA scientists participate on the
Intergovernmental Panel on Climate Change
(IPCC), an international scientific body that provides
information about the causes of climate change and
its potential effects on the environment. In a series of
comprehensive reports completed in 2007, the IPCC
concluded that "warming of the climate system is
unequivocal, as is now evident from observations of
increases in global average air and ocean temperatures,
widespread melting of snow and ice, and rising global
average sea level." Global mean surface temperatures
have been rising and the IPCC reported that since the
mid 20th century, most of the observed increase is very
likely due to the observed increase in human-made
GHG concentrations.
CLIMATE'S EFFECTS ON AIR QUALITY
Due to climate change, the IPCC predicted "declining
air quality in cities."In summarizing the impact of
climate change on ozone and particle pollution, the
IPCC concluded that "future climate change may cause
significant air quality degradation by changing the
dispersion rate of pollutants; the chemical environment
for ozone and particle pollution generation; and the
strength of emissions from the biosphere, fires, and
dust." Though a great deal of uncertainty remains
regarding the expected future impacts of climate
change on air quality, recent research suggests that such
effects may be very significant, particularly on a local or
regional scale.
Ground-level ozone is influenced by shifts in the
weather, such as the periodic occurrence of heat waves.
Changes in the weather that might result from climate
change, such as warmer temperatures and more or less
frequent episodes of stagnant air, therefore also have
the potential to affect ground-level ozone. The potential
impact of climate change on particle pollution is less
well understood, but recent studies have begun to look
at this relationship.
A 2009 report by EPA (EPA Assessment, 2009)
investigates the potential impacts of climate change
on both ozone and particle pollution (while holding
emissions constant). With regard to ozone, the
MFCs, PFCs, &SF6
Nitrous Oxide
Methane
Carbon Dioxide
LU
O
ra
8000 -i
6000
4000
2000 -
Figure 34. Domestic greenhouse gas
emissions in teragrams of carbon dioxide
equivalents (Tg CO2 eq), 1990-2007.
(Source: http://epa.gov/climatechange/
emissions/usinventoryreport.html)
Notes: A teragram is equal to 1 million metric tons.
Emissions in the figure include fluorocarbons (HFCs,
PFCs) and sulfur hexafluoride (SF6).
90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07
40
Our Nation's Air
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assessment indicates climate change (between the
present and 2050) has the potential to:
• Produce significant increases in summertime average
ground-level ozone concentrations in many regions
by 2 to 8 parts per billion, as shown in Figure 35
• Exacerbate peak ozone concentrations on days
where weather is already conducive to high ozone
concentrations
• Lengthen the ozone season
• Increase emissions of ozone precursors from natural
sources
In general, while this type of modeling study cannot
precisely predict what the future will hold, it does
demonstrate the potential for global climate change to
exacerbate ground-level ozone pollution across the U. S.
The findings of this study indicate that, where climate
change-induced increases in ground-level ozone do
occur, damaging effects on ecosystems, agriculture,
and health may be pronounced, due to increases in
average pollutant concentrations and the frequency of
extreme pollution events. Further studies are needed to
understand how changes in future emissions patterns
will affect climate and air quality interactions.
For particle pollution, the results from EPA's
assessment are less definitive. The report indicates that
future climate conditions may be associated with a
range of impacts—both increases and decreases—in
particle concentrations in different regions and may
also affect different components of particle pollution
differently. Specifically, the study's limited findings
show:
• Globally, particle pollution generally decreases
as a result of simulated climate change (with
manmade emissions held constant), due to increased
atmospheric humidity and/or increased precipitation
• Regionally, simulated climate change produces both
increases and decreases in particle pollution (on the
order of a few percent) in 2050, depending on the
region of the U.S., with the largest increases in the
Midwest and Northeast
• The responses of the individual components of
particle pollution (e.g., sulfate, nitrate, ammonium,
BC, organic carbon) to climate change are highly
variable, depending on the properties and transport
characteristics of each component
• Particle pollution is expected to be influenced by
meteorological factors such as precipitation, clouds,
and temperature, all of which are affected by climate
change
Change in
Concentration (ppb)
Change of-1.5 to 1.5
I Increase of 1.6 to 4.5
I Increase of 4.6 to 7.5
• Increase of 7.6 to 11.5
Figure 35. Increases in
average summertime ozone
concentrations in the eastern
U.S., due to climate change,
are predicted for 2050. (Source:
Figure 33 from EPA Assessment,
2009. 2050s-minus-present
differences in simulated summer
mean maximum daily average
8-hour ozone concentrations;
reproduced from Figure 2 in
Hogrefeetal.,2004.)
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41
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Climate Change and Air Qjua 1 ity
IMPACTS OF SHORT-LIVED POLLUTANTS ON THE ARCTIC CLIMATE
Arctic temperatures have increased at almost twice the global average rate over the past 100 years (IPCC, 2007).
Warming in the Arctic has been accompanied by an earlier onset of spring melt. During the 2007 melt season, Arctic
sea ice dropped to the lowest levels observed since satellite measurements began in 1979, resulting in the first recorded
complete opening of the Northwest Passage. As sea ice shrinks, less sunlight is reflected from the Earth's surface, leading to
further warming.
Reducing emissions of carbon dioxide (CO2) globally is essential to long-term global (and Arctic) climate stabilization, but
will not significantly change the rate of warming in the Arctic over the next few decades due to the long lifetime of CO2
in the atmosphere. However, reducing emissions of short-lived pollutants may impact Arctic climate on a more immediate
timescale. Several short-lived pollutants, including black carbon (BC) and ozone, are contributing to the accelerated rates
of warming.
BC emissions lead to climate warming by absorbing incoming and reflected sunlight in the atmosphere. BC deposited on
ice increases the rate of warming and melting of the ice. Due to these effects, and because BC in the atmosphere causes
more warming when it is present over reflective surfaces such as ice, BC has impacts in the Arctic and over other snow and
ice covered areas. Ground-level ozone has also been shown to play an important roe in seasonal Arctic warming trends
(Shindell et al., 2006). Warming due to ground-level ozone is at a maximum during spring when transport of ozone is
efficient, sunlight is abundant, and substantial ozone precursors have built up over the winter.
Median Extent 1979-2000
2007 Ice Shelf Extent
2005 Ice Shelf Extent
North Pole
This image compares trie average sea ice extent from September 2007 to September 2005; trie red line indicates the long-term
median from 1979 to 2000. (Dafa source: Courtesy of file National Snow and Ice Data Center, Boulder, CO; http://nsidc.org/
news/press/2007_seaiceminim urn/20071001 _pressrelease.htmlj
42
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INTERNATIONAL TRANSPORT OF AIR
POLLUTION
TRANSPORT OF AIR POLLUTION
AFFECTS THE U.S.
While domestic sources of emissions are the primary
cause of air pollution in our country, the U.S. is both
an importer and exporter of air pollution. Air pollution
flows across boundaries—not only between the U.S.
and our closest neighbors, Canada and Mexico, but also
between North America, Europe, and Asia and, to some
extent, between North America, Africa, and Central
and South America. International flow of air pollutants
into the U.S. contributes to observed concentrations
of ozone and fine particles and deposition of mercury,
persistent organic pollutants (POPs), and acid
deposition.
The impact that international transport of air pollution
has on our ability to attain air quality standards or other
environmental objectives in the U.S. has yet to be fully
characterized (except in areas that are immediately
adjacent to cities or sources in Mexico or Canada).
Estimates based on the available evidence are highly
uncertain but suggest that the current contributions of
international transport to observed concentrations and
deposition are small but are of the same magnitude
as the air quality improvements expected from recent
national emissions control programs. Figure 36
illustrates one estimate of the "footprint" of North
American, European, and Asian emissions with
respect to ammonium sulfate, a significant man-made
component of fine particle pollution. Increased
emissions of particle pollution, mercury, and ozone
precursors associated with economic growth in
developing countries may increase background levels of
these pollutants in the U.S.
For ozone and particle pollution, increased background
levels of these pollutants could potentially create
difficulties for local and regional areas to achieve
the National Ambient Air Quality Standards and
long-term visibility improvement goals. Transported
ozone and fine particles also contribute to radiative
forcing and global and regional climate change.
For mercury and POPs, international flows contribute
to deposition and eventual human and ecosystem
chemical exposures. In some locations, especially in
Alaska, international sources are the dominant source
of ambient air contamination.
Ammonium Sulfate Surface Cone
From European Pollution
180 120W
Figure 36. Annual average surface ammonium sulfate concentrations in the Northern Hemisphere in 2001 from NASA's
GOCART (Goddard Chemistry Aerosol Radiation and Transport) model (top left panel) and the amount from major
source regions of Asia (second panel), Europe (third panel), and North America (last panel). Color scales are concentrations
in ug/m3 and the contour lines show the percentage contributions to the total ammonium sulfate in 10,30,50, and 80
percent intervals. (Source: Chin et al., 2007, Atmospheric Chemistry and Physics, 7:5501-5517)
Our Nation's Air
43
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International Transport of Air Pollution
EFFORTS TO BETTER UNDERSTAND
TRANSPORT OF AIR POLLUTION
EPA and other agencies are working via treaties
and international cooperative efforts to address the
international transport of air pollution. In 2008, EPA
worked with the International Maritime Organization
to adopt new emission standards for ocean-going
vessels, a major source of air pollution in some coastal
regions (see ship traffic patterns in Figure 37). In 2009,
the National Academy of Sciences (NAS) completed
a study funded by EPA, the National Oceanic and
Atmospheric Administration (NOAA), the National
Aeronautics and Space Administration (NASA), and
the National Science Foundation (NSF), about the
significance of international transport on air quality,
deposition, and radiative forcing. This study, entitled
"Global Sources of Local Pollution," will contribute to
a 2010 assessment, co-led by EPA, of intercontinental
transport in the northern hemisphere by the
international Task Force on Hemispheric Transport of
Air Pollution under the Convention on Long-Range
Transboundary Air Pollution (LRTAP). The NAS
study will also help inform U.S. participants on (1)
negotiations on a global treaty to address mercury
pollution that will be convened by the United Nations
Environment Programme in 2010 and (2) ongoing
negotiations under the global Stockholm Convention
on Persistent Organic Pollutants, to which nine new
toxic substances were added in 2008.
EPA continues to work bilaterally with air quality
management authorities in Canada, Mexico, and other
key countries, such as China and India, to help them
address sources of air pollution, which ultimately helps
to reduce the transport of air pollution into the U.S.
0 9501,900 3,800
5,700 7,600
Nautical Miles
Ship Traffic Pattern I I Low G^| High
I Very Low I I Medium ^H Very High
Derived from 1983-2002 ICOADS.
Figure 37. Marine shipping activity derived from the International
Comprehensive Ocean-Atmosphere Data Set (ICOADS).
44
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APPENDIX '
TERMINOLOGY
AQI Air Quality Index
AQS Air Quality System
BC black carbon
CASTNET Clean Air Status and Trends Network
CFCs chlorofluorocarbons
CH4 methane
CO carbon monoxide
CO2 carbon dioxide
dv deciviews
EC elemental carbon
EPA U. S. Environmental Protection Agency
GHG greenhouse gas
HFCs hydrofluorocarbons
ICOADS International Comprehensive
Ocean-Atmosphere Data Set
IMPROVE Interagency Monitoring of Protected
Visual Environments
IPCC Intergovernmental Panel on Climate
Change
LRTAP Long-Range Transboundary Air
Pollution
N Nitrogen
NAAQS National Ambient Air Quality
Standards
NAS National Academy of Sciences
NASA National Aeronautics and Space
Administration
NATA National-Scale Air Toxic Assessment
NATTS National Air Toxics Trends Stations
NEI National Emissions Inventory
NH3 ammonia
NOAA National Oceanic and Atmospheric
Administration
NO
NO
X
N02
NSF
03
oc
PAHs
ppb
ppm
PFCs
PM
POPs
ppm
SF6
SIP
SO
x
so2
|im
|ig/m3
VOCs
nitric oxide
oxides of nitrogen
nitrogen dioxide
National Science Foundation
ground-level ozone
organic carbon
polycyclic aromatic hydrocarbons
parts per billion
parts per million
perfluorinated compounds
particulate matter (particle pollution)
particulate matter (fine) 2.5 |im or less
in size
particulate matter 10 |im or less in size
persistent organic pollutants
parts per million
sulfur hexafluoride
state implementation plan
oxides of sulfur
sulfur dioxide
micrometers (microns)
micrograms per cubic meter
volatile organic compounds
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45
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Web Sites
WEB SITES
Atmospheric Deposition
Acid Rain Program: http://www.epa.gov/airmarkets/progsregs/arp/index.html
Acid Rain Program 2006 Progress Report: http://www.epa.gov/airmarket/progress/arp06.html
National Atmospheric Deposition Program: http://nadp.sws.uiuc.edu/
Background/General Information
Air Quality Index: http://www.airnow.gov
Air Quality System: http://www.epa.gov/ttn/airs/airsaqs/
Air Quality System Detailed Data: http://www.epa.gov/ttn/airs/airsaqs/detaildata
Clean Air Research Program: http://www.epa.gov/airscience
EPA-Funded Particulate Matter Research Centers:
http://cfpub.epa.gov/ncer_abstracts/index.cfm/fuseaction/outlinks.centers#19
Framework for Assessing the Public Health Impacts of Risk Management Decisions:
http://www.epa.gov/ORD/npd/hhrp/files/hhrp-framework.pdf
Health and Ecological Effects: http://www.epa.gov/air/urbanair/
HELPS International: http://www.helpsintl.org
Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air): http://depts.washington.edu/mesaair/
National Ambient Air Quality Standards: http://www.epa.gov/air/criteria.html
National Center for Environmental Assessment: http://cfpub.epa.gov/ncea/
National Particle Components Toxicity (NPACT) Initiative: http://www.healtheffects.org/Pubs/NPACT.pdf
Office of Air and Radiation: http://www.epa.gov/air/
Office of Air Quality Planning and Standards: http://www.epa.gov/air/oaqps/
Office of Atmospheric Programs: http://www.epa.gov/air/oap.html
Office of Transportation and Air Quality: http://www.epa.gov/otaq/
Climate Change
Climate change: http://www.epa.gov/climatechange/
U.S. Climate Change Science Program: http://www.climatescience.gov
Emissions and trends in greenhouse gases:
http://www.epa.gov/climatechange/emissions/usinventoryreport.html
Green Car Congress: http://www.greencarcongress.com/2008/06/us-vehicle-mile.html
Intergovernmental Panel on Climate Change: http://www.ipcc.ch
Traffic Volume Trends: http://www.fhwa.dot.gov/ohim/tvtw/tvtpage.cfm
Emissions and Control Programs
Emissions: http://www.epa.gov/air/emissions/
NOx Budget Trading Program/NOx SIP Call: http://www.epa.gov/airmarkets/progsregs/nox/sip.html
46 Our Nation's Air
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Toxic Air Pollutants
2002 National-Scale Air Toxics Assessment: http://www.epa.gov/ttn/atw/nata2002/
Measurements and Trends
Air Quality Trends: http://www.epa.gov/airtrends/
Air Trends Design Values: http://www.epa.gov/air/airtrends/values.html
Clean Air Status and Trends Network (CASTNET): http://www.epa.gov/castnet/
EPA Monitoring Network: http://www.epa.gov/ttn/amtic/
Local air quality trends: http://www.epa.gov/airtrends/where.html
National Air Monitoring Strategy Information: http://www.epa.gov/ttn/amtic/monstratdoc.html
National Core Monitoring Network: http://www.epa.gov/ttn/amtic/ncore/index.html
Trends in ozone adjusted for weather conditions: http://www.epa.gov/airtrends/weather.html
Visibility
National Park Service: http://www.nature.nps.gov/air/
Regional Haze Program: http://www.epa.gov/visibility
Visibility Information Exchange Web System (VIEWS): http://vista.cira.colostate.edu/views/
International Transport
International Maritime Organization: http://www.imo.org
FAAs Aviation Climate Change Research Initiative (ACCRI):
http://www.faa.gov/abou t/office_org/headquarters_offices/aep/aviation_climate/
Task Force on Hemispheric Transport of Air Pollution: http://www.htap.org
Our Nation's Air 47
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Reference s
REFERENCES
Highlights
U.S. Census Bureau, Population Division, Annual Estimates of the Resident Population by Selected Age Groups
and Sex for Counties: April 1, 2000 to July 1, 2008, available on the Internet at http://www.census.gov/popest/
counties/asrh/CC-EST2008-agesex.html.
Ozone
National Academy of Sciences, National Research Council, Radiative Forcing of Climate Change: Expanding the
Concept and Addressing Uncertainties, National Academies Press, Washington, D.C. October, 2005.
Dentener, et. al., The Impact of Air Pollutant and Methane Emission Controls on Tropospheric Ozone and Radiative
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Jacob, Daniel et al., Transboundary Influences on U.S. Background Ozone, presented at the American Geophysical
Union Fall Meeting, San Francisco, CA, December 14,2007.
Parrish, David et al., Air Quality Implications of Ozone in Air Entering the West Coast of North America, presented
at the Task Force on Measurements and Modeling - Task Force on Hemispheric Transport of Air Pollution
Joint Workshop on Regional-Global and Air Quality-Climate Linkages, Paris, France, June 17,2009.
Quinn, et. al., Short-lived Pollutants in the Arctic: Their Climate Impact and Possible Mitigation Strategies,
Atmospheric Chemistry and Physics, 8, pg. 1723-1735 (2008).
Particle Pollution
Intergovernmental Panel on Climate Change, Summary for Policymakers. In: Climate Change 2007:
Impacts, Adaptation and Vulnerability. Contribution of Working Group II to the Fourth Assessment Report of the
Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge, United Kingdom and New
York, NY, USA, 2007.
National Academy of Sciences, Radiative Forcing of Climate Change: Expanding the Concept and Addressing
Uncertainties, October 2005.
Climate Change and Air Quality
National Academy of Sciences, National Research Council, Air Quality Management in the United States,
National Academies Press, Washington, D.C., 2004.
U.S. Environmental Protection Agency, Assessment of the Impacts of Global Change on Regional U.S. Air Quality:
A Synthesis of Climate Change Impacts on Ground-level Ozone, Office of Research and Development, National
Center for Environmental Assessment, EPA/600/R-07/094F, April, 2009.
Shindell, el. al., Role of Tropospheric Ozone Increases in 20th-century Climate Change, Journal of Geophysical
Research, Geophysical Research Union, Vol. Ill, D08302,2006.
International Transport of Air Pollution
National Academy of Sciences, National Research Council, Global Sources of Local Pollution: An Assessment of
Long-Range Transport of Key Air Pollutants to and from the United States, National Academies Press, Washington,
D.C. November, 2009.
48 Our Nation's Air
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METHODOLOGY USED IN THIS REPORT
1. In Figure 3 of this report, the trend line in "Aggregate Emissions" is derived by 1) determining the percentage
change in emissions for each pollutant from 1990 to a later year (e.g., 2005) then 2) determining the average
percentage change from among all pollutant emissions for that time period. In previous reports, this trend line
was based on the percentage change in the yearly sum of the emissions from all individual pollutants. The earlier
approach allowed carbon monoxide changes to dominate the overall trend line because emissions of carbon
monoxide are about 10 times those of any other pollutant. The new approach results in an indicator that is more
balanced among the pollutants.
2. In this report, figures and statistics involving air concentrations of all common pollutants are based on the
inclusion of all valid measured concentrations even if these measured concentrations were affected by natural or other
exceptional events. In previous reports, air concentrations that EPA had determined were affected by such events—
and could therefore be excluded for regulatory purposes—were excluded from the figures and statistics. The new
approach uses indicators that are more reflective of the air quality to which people have been exposed.
Our Nation's Air 49
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