EPA/600/R-10/091 September 2010 United States Environmental Protection Agency Field Screening Equipment Information Document Companion to Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM) - Revision 5.0 Office of Research and Development National Homeland Security Research Center ------- ------- Field Screening Equipment Information Document Companion to Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM) - Revision 5.0 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Office of Research and Development, National Homeland Security Research Center, Cincinnati, OH 45268 Office of Research and Development National Homeland Security Research Center, Threat and Consequence Assessment Division ------- SAM Companion - Field Screening Equipment Document Acknowledgements This document was developed by the U.S. Environmental Protection Agency's (EPA) National Homeland Security Research Center (NHSRC) within EPA's Office of Research and Development as a companion to NHSRC's Standardized Methods for Environmental Restoration Following Homeland Security Events (SAM). We wish to acknowledge the external peer reviews conducted by Matthew Arduino of the U.S. Centers for Disease Control and Prevention, Larry Burchfield of the Radiochemistry Society, Jordan Peccia of Yale University, and Fred Lee of G. Fred Lee & Associates, whose thoughtful comments contributed greatly to the quality of the information. The document was prepared by Computer Sciences Corporation (CSC) under EPA Contract No. EP-W-06-046. Disclaimer Mention of trade names or commercial products in this document does not constitute endorsement or recommendation for use. Questions concerning this document or its application should be addressed to: Romy Lee National Homeland Security Research Center Office of Research and Development (NG16) U.S. Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, OH 45268 (513)569-7016 lee.romy@epa.gov September 2010 ------- SAM Companion - Field Screening Equipment Document Foreword Following the events of September 11, 2001, EPA's mission was expanded to account for critical needs related to homeland security. Presidential Directives identified EPA as the primary federal agency responsible for the country's water supplies and for decontamination following a chemical, biological, and/or radiological (CBR) attack. To provide scientific and technical support to help EPA meet this expanded role, EPA's National Homeland Security Research Center (NHSRC) was established. The NHSRC research program is focused on conducting research and delivering products that improve the capability of the Agency to carry out its homeland security responsibilities. One specific focus area of NHSRC's research is to support the Environmental Response Laboratory Network (ERLN), a nationwide association of federal, state, local, and commercial environmental laboratories, established by EPA. The ERLN can be deployed in response to a large-scale environmental disaster by providing consistent analytical capabilities, capacities, and quality data in a systematic, coordinated manner. Toward this end, NHSRC has worked with experts from across EPA and other federal agencies to develop a compendium of analytical methods to be used in support of remediation following national homeland security related incidents. For specific analytes that have been determined to be of concern during a homeland security related event, analytical methods have been chosen to measure levels of contamination in different environmental matrices. The results of these efforts have been published in EPA's Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM), available at http://www.epa.gov/sam. In identifying and selecting appropriate analytical methods to be used in such instances, a need became apparent to provide information regarding the capabilities of field equipment that is currently in use and could be applied for screening environmental samples and conditions prior to laboratory analysis. The information in this document addresses this need, in part, by providing information regarding the capabilities of field screening equipment that is currently in use, for detecting chemical and radiochemical analytes listed in SAM. Updates will be provided as new information is developed regarding field screening equipment and related capabilities. NHSRC has made this publication available to assist in preparing for and recovering from disasters involving chemical, radiochemical, and biological contamination; it specifically represents an important next step in supporting the ERLN. We value your comments as we move toward the development of an efficient process to manage environmental samples and move EPA one step closer to achieving its homeland security mission and its overall mission of protecting human health and the environment while supporting sustainable solutions. Gregory D. Sayles, Ph.D., Acting Director National Homeland Security Research Center iii September 2010 ------- SAM Companion - Field Screening Equipment Document Table of Contents ACKNOWLEDGEMENTS ii TABLE OF CONTENTS IV LIST OF TABLES iv ACRONYMS AND ABBREVIATIONS v 1.0 BACKGROUND 1 2.0 SCOPE AND APPLICATION 1 3.0 EQUIPMENT 2 3.1 Field Screening Equipment for SAM Chemistry Analytes 2 3.2 Field Screening Equipment for SAM Radiochemistry Analytes 5 4.0 REFERENCE S 7 List of Tables Table 1a: Field Screening Equipment - Use in Detecting Chemistry Analytes Listed in SAM Table 1b: Field Screening Equipment - Use in Detecting Radiochemistry Analytes Listed in SAM Table 2a: SAM Chemistry Analytes - Detection using Field Screening Equipment Table 2b: SAM Radiochemistry Analytes - Detection using Field Screening Equipment iv September 2010 ------- SAM Companion - Field Screening Equipment Document Acronyms and Abbreviations a Alpha (3 Beta y Gamma BZ Quinuclidinyl benzilate ฐC Degrees centigrade CAS RN Chemical Abstracts Service Registry Number CDS Civil Defense Simultest (Kit) cfm Cubic feet per minute cm Centimeter cm2 Square centimeter cpm Counts per minute CSC Computer Sciences Corporation ED Ethyldichloroarsine EPA U.S. Environmental Protection Agency eV Electron volt FID Flame ionization detector FPS Flame photometric spectrometry G-agent Nerve agent GA Tabun GB Sarin GD Soman GE 1-Methylethyl ester ethyl-phosphonofluoridic acid GF Cyclohexyl sarin H-agent Mustard/blister agent HD Mustard, sulfur/mustard gas hr Hour FIN-1 Mustard, nitrogen [bis(2-chloroethyl) ethylamine] FIN-2 Mustard, nitrogen [2,2'-dichloro-N-methyldiethylamine N,N-bis(2-chloroethyl) methylamine] FIN-3 Mustard, nitrogen [tris(2-chloroethyl) amine] IMS Ion mobility spectrophotometry IR Infrared KeV Kiloelectron volt L Liter L-l Lewisite 1 L-2 Lewisite 2 L-3 Lewisite 3 LCD Liquid crystal display LEL Lower explosive limit m3 Cubic meter MARLAP Multi-Agency Radiological Laboratory Analytical Protocols Manual MCA Multi channel analyzer (ig Microgram \\L Microliter (im Micrometer (iR Microroentgens mg Milligram mR Milliroentgens September 2010 ------- SAM Companion - Field Screening Equipment Document mrem Millirem MeV Megaelectron volt min Minute mSv Millisievert mV Millivolt MVA Mercury vapor analyzer ng Nanogram NHSRC National Homeland Security Research Center nSv Nanosievert OSC On-scene coordinator PC Personal computer PID Photoionization detector ppb Parts per billion ppm Parts per million R Roentgen R-33 S-[2-(diethylamino)ethyl O-2 -methylpropyl ester (Russian VX) rem Roentgen equivalent in man SAM Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events SPM Single point monitor TEA Triethanolamine TIC Toxic industrial chemical V-agent Nerve agent VE Phosphonothioic acid, ethyl-, S-(2-(diethylamino)ethyl) O-ethyl ester VG Phosphonothioic acid, S-(2-(diethylamino)ethyl) O,O-diethyl ester VM Phosphonothioic acid, methyl-, S-(2-(diethylamino)ethyl) O-ethyl ester VOC Volatile organic compound VX O-ethyl-S-(2-diisopropylaminoethyl) methyl phosphonothiolate Z Density value of composite composition VI September 2010 ------- SAM Companion - Field Screening Equipment Document Field Screening Equipment Information Document [Companion to Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM)] September 2010 1.0 Background The U.S. Environmental Protection Agency (EPA) National Homeland Security Research Center (NHSRC) worked with experts from across EPA and its sister agencies since 2003 to develop a compendium of analytical methods to be used when responding to national homeland security related incidents. Analytical methods have been selected for chemical, radiochemical, pathogen, and biotoxin analytes of concern for the types of environmental sample matrices that are anticipated in such incidents. The results of these efforts have been published in several revisions of EPA's Standard Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM), available at http://www.epa.gov/sam. NHSRC periodically reviews and updates the SAM document to address the needs of homeland security, reflect improvements in analytical methods and new technologies, and incorporate changes in target analytes. During development of SAM, EPA recognized the need for a companion document to identify the capabilities of field equipment currently in use or being considered by EPA, to screen sites for the presence of the SAM analytes. This document is intended to address this need, in part, by providing information regarding the capabilities of field equipment currently being used or considered by EPA on-scene coordinators (OSC), for detecting chemical and radiochemical analytes listed in SAM. The document corresponds to Revision 5.0 of SAM and EPA's OSC equipment list as of September 1, 2009. As with SAM, NHSRC plans to update the information in this document periodically, to reflect changes to the analytes listed in SAM or to the equipment being used or considered by EPA OSCs. 2.0 Scope and Application This document is intended to provide a general overview of information regarding field screening equipment that is currently in use by EPA, in terms of equipment capabilities for addressing the target chemical and radionuclide analytes and the environmental matrices included in SAM. The information in this document is intended for use by decision makers in preparing for and developing field screening site assessment activities. Detailed procedure(s) and/or instruction(s) regarding the use of specific equipment, as well as information regarding the relative toxicity, health risks, and environmental risks of the analytes, are outside the scope of this document. Users should refer to the appropriate instrument manufacturer, SAM, and/or other references listed in Section 4.0 and Tables la and Ib for further information on these topics. NOTE: Information regarding the equipment listed in this document is provided in terms of equipment capabilities to address the analytes and sample types listed in SAM. Assumptions regarding whether analytes are of concern (i.e., will persist) in a particular sample type are based on how the analytes are listed in SAM. Analytes that are listed in this document as not a concern in a particular sample type reflect SAM workgroup decisions regarding analyte persistence. September 2010 ------- SAM Companion - Field Screening Equipment Document There are four tables provided in this document. Information is compiled into two tables for each of two analyte categories (chemical and radiochemical) with emphasis on equipment capabilities (Tables la and Ib) and with emphasis on the analytes of concern (Tables 2a and 2b): Tables la and Ib: Provide information regarding the screening equipment that can be used to indicate the presence/absence of chemical (Table la) and radiochemical (Table Ib) analytes listed in SAM. The information is sorted first by field screening equipment, followed by: (1) SAM analytes that can be detected by the equipment, (2) Chemical Abstracts Service Registry Number (CAS RN) of the analytes, and (3) environmental media that can be screened by the equipment for detection of the analytes. Table la: Field Screening Equipment - Use in Detecting Chemistry Analytes Listed in SAM Table Ib: Field Screening Equipment - Use in Detecting Radiochemistry Analytes Listed in SAM Tables 2a and 2b: Provide information similar to the information provided in Tables la and Ib, but sort the information by SAM analyte, followed by (1) analyte CAS RNs, (2) field screening equipment that can be used to provide an indication of the presence/absence of the analyte, and (3) the type of environmental media that can be screened by the equipment. Table 2a: SAM Chemistry Analytes - Detection using Field Screening Equipment Table 2b: SAM Radiochemistry Analytes - Detection using Field Screening Equipment 3.0 Equipment The information provided in this document corresponds to field screening equipment currently in use or being considered by EPA OSCs. This equipment is listed below, along with brief descriptions. Additional equipment information is provided in Tables la, Ib, 2a, and 2b. Where available, equipment performance information is provided throughout this document; this information, however, may not reflect specific project or site conditions. Prior to use, each piece of screening equipment should be evaluated for its ability to address site- or incident-specific goals. NOTE: Analyte presence/absence determinations are highly dependent on equipment detection capabilities for the specific target analyte(s) or analyte class. Where available, equipment detection levels or ranges are included in Tables la and Ib. Site- or project- specific detection levels and plans will be needed to support site- or project-specific decision making, and will depend on the intended use of the field equipment. 3.1 Field Screening Equipment for SAM Chemistry Analytes AP2C Chemical Agent Monitor (Page la-1) - Portable, hand-held instrument that uses flame photometric spectrometry (FPS) to identify specific classes of nerve or mustard agent vapor in air. Responds to nerve and mustard agent vapors, including GA, GB, GD, GF, VX, and HD, through a series of lighted bars, with minimum detection limits of approximately 0.2 milligrams per cubic meter (mg/m3) for G-agents and 0.9 mg/m3 for H- agents. September 2010 ------- SAM Companion - Field Screening Equipment Document AP4C Chemical Agent Monitor (Page la-2) - Portable, hand-held instrument used to detect chemical agents in the form of vapor, aerosols, and dust. Responds to nerve, blister, and blood agent vapors, including GA, GB, GD, GF, lewisite, VX, and HD. The AP4C has extended capacity (compared to AP2C) to detect chemical warfare agents and toxic inorganic compounds in a simultaneous mode. There is no limitation in number of gases detected simultaneously by the AP4C. Detection time is within two seconds. APD2000ฎ Chemical Agent Monitor (Page la-3) - Portable, hand-held instrument that uses ion mobility spectrometry (IMS) to identify the specific class of nerve agent or blister agent in air. Responds to nerve and blister agent vapors (GA, GB, GD, VX, HD, HN, and lewisite) through a relative number between 1 and 100, with minimum detection limits of approximately 0.025 mg/m3 for G-agents and 0.2 mg/m3 for H-agents. Draeger Civil Defense Simultest (CDS) Kit with Detection Tube Kits I and V (Page la-4) - Provides rapid identification of chemical agents using chemical reagents in calibrated detector tube sets. The Draeger CDS Kit includes both CDS Detection Tube Kits I and V, which are each designed to detect up to five separate chemical agents simultaneously in five minutes. Using both kits, a total of eight different chemical agents can be detected, with each detector tube having a sensitivity specific to one chemical. Compounds and minimum detection levels include the following: hydrocyanic acid (at 1 parts per million [ppm]); phosgene (at 0.2 ppm); lewisite (as organic arsenic compounds at 3 mg/m3 and as arsine at 0.1 ppm); N-mustard (as organic based nitrogen compounds at 1 mg/m3); S-mustard (as thioether at 1 mg/m3); nerve agents (as phosphoric acid esters at 0.025 ppm); cyanogen chloride (at 0.25 ppm); and chlorine (at 0.2 ppm). For additional detection capabilities, refer to full vendor listing of compatible detection tubes (i.e., Kits II, III, IV, etc.). Draeger MultiWarn (Page la-5) - Portable, hand-held, microprocessor-controlled instrument designed for monitoring up to four atmospheric gas hazards simultaneously. Combines electrochemical, catalytic oxidation, and infrared (IR) sensing technology to monitor for two different toxic gases (over 25 different toxic gas sensors are available), combustible gases (0 - 100% of lower explosive limit [LEL]), and oxygen levels (0 - 25%), using a membrane pump with a flow of 0.6 liters/minute that can draw gases from distances greater than 100 feet. Currently available toxic sensors include ammonia (0 - 300 ppm), nitric oxide (0 - 100 ppm), phosphine (0 - 10 ppm), hydrogen cyanide (0 - 50 ppm), chlorine (0 - 20 ppm), and nitric oxide (0 - 50 ppm). Draeger MultiWarn II (Page la-5) - Portable, hand-held, microprocessor-controlled instrument similar to Draeger MultiWarn with additional capabilities, including: (1) remote sampling pump is standard equipment and (2) optional internal datalogger. Draeger Polytron 7000 Series Detectors (Page la-6) - Single platform gas detector for toxic and oxygen gas measurement applications that can detect over 100 different gases. Modular design allows upgrading to higher specifications levels. Communication interfaces can be selected for different central control systems and software options. This instrument also can be equipped with a relay module. HazCat Chemical Identification System (Page la-7) - Chemical identification system used to identify hazardous characteristics (corrosive, water reactive, toxic, oxidizer, sulfide, flammable, and/or organic halide) and other properties of unknown materials. By September 2010 ------- SAM Companion - Field Screening Equipment Document using simple field chemistry tests and following the HazCat charts, an unknown material can be segregated by hazard class and possibly identified. The HazCat kit uses gas detection tubes and is designed for rapid, on-site identification or categorization of many spilled or abandoned materials. Three HazCat kits are available: (1) KT1209, which is a basic kit without pump or detection tubes; (2) KT1206, which includes Draeger pump and detection tubes, and (3) KT1204, which includes Gastec pump and detection tubes. Kits KT1206 and KT1204 include ammonia, hydrogen cyanide, and phenol gas detection tubes. For additional detection capabilities, refer to full vendor listing of compatible detection tubes. Jeromeฎ 431/431 Mercury Vapor Analyzer (MVA) (Page la-8) - Portable, hand-held, microprocessor-controlled instrument using gold film technology to monitor for mercury vapor in air at levels from 0.003 to 0.999 mg/m3. M256A1 Chemical Agent Detector Kit (Page la-9) - Chemical agent detector kit that can detect chemical agents in vapor form, including nerve agents (G and V), blood agents, blister agents (H, HD, and CX), and lewisite. The kit gives qualitative results only, with detection limits ranging from ug/m3 levels for nerve agents to mg/m3 levels for blister and blood agents. M8 Paper (VGH ABC-M8 Chemical Agent Detector Paper) (Page la-10) - Detects nerve agents (G and V) and blister agents (H) in liquid form only. M8 paper is similar to litmus (i.e., pH) paper; the difference is that M8 paper is designed specifically to react to nerve agents and blister agents in liquid form. The paper gives qualitative results only; detection limits are unspecified. M9 Chemical Agent Detector Paper (Page la-11) - Reacts more rapidly than M8 paper and detects nerve agents (G and V) and blister agents (H) in liquid form only. Use with 100 microliter [\\L\ droplets of liquid, or larger; will not respond to chemical agents when wet. Chemical agent vapors also are not detected. The paper gives qualitative results only; detection limits are unspecified. MDA Scientific Single Point Monitor (SPM) (Page la-12) - Used for long-term monitoring of airborne concentrations of a known organic or inorganic gas for up to 30 days per Chemcassetteฎ tape. Chemcassettesฎ use a dry reagent impregnated into a paper tape to collect and analyze air samples; when exposed to a target gas, a chemical reaction occurs resulting in a color change in direct proportion to the concentration of gas present. The instrument monitors the color intensity change and determines the gas concentration by comparison to a known, pre-programmed gas response. Detects a wide variety of compounds, with detection limits (generally in the parts per billion [ppb] range) and sample times depending on the compound. Available tapes include aliphatic amines, ammonia, diisocyanates, hydrides, hydrogen cyanide, hydrogen sulfide, chlorine dioxide, phosgene, hydrogen fluoride, sulfuric acid, and phosphine. MIE DataRAM (Page la-12) - Portable, hand-held, microprocessor-controlled instrument that measures the concentration of airborne particulate matter (aerosolized liquid or solid), as well as mean particle size. With appropriate particle discriminators, it provides measurements correlated with 10, 2.5, and 1.0 \\m (PMi0, PM2s, PMi 0), and respirable fractions, air temperature, and humidity. Covers a measurement range of 0.001 - 400 mg/m3. Uses a high-sensitivity nephelometric monitor with a light-scattering September 2010 ------- SAM Companion - Field Screening Equipment Document sensing configuration optimized to measure airborne dust, smoke, fumes, and mist in industrial and ambient environments. MultiRAE Plus Multigas Monitor and Photoionization Detector (PIP) (Page la-13) - Portable, hand-held, multi-gas monitor for continuous monitoring of toxic gases, oxygen, and combustible gases. Monitors organic vapors with a built-in PID (10.6 eV lamp standard), combustible gases/LEL with a catalytic bead sensor, oxygen concentration with an electrochemical sensor, and inorganic toxic compounds with up to two electrochemical sensors (numerous sensors are available). Examples of detection levels and currently installed sensors include the following: oxygen (0 - 30%); combustible gas (0 - 100% LEL); carbon monoxide (0 - 500 ppm); and hydrogen sulfide (0 - 100 ppm). In PID mode, the MultiRAE does not distinguish one type of chemical from another, but indicates the total concentration of all photoionizable compounds in the range of 0 to 2,000 ppm. RA-915+MVA (Page la-14) - Portable, hand-held, atomic absorption spectrometer that can monitor for mercury vapor in air at levels from 2 nanograms per cubic meter (ng/m3) to 50 micrograms per cubic meter (|ig/m3). TVA1000B Combined PID/Flame lonization Detector (FID) Detector (Page la-15) - Portable, hand-held vapor analyzer that uses both a FID and PID. This instrument can detect total organic and some inorganic vapors in air down to ppm levels, but does not differentiate between compounds. 3.2 Field Screening Equipment for SAM Radiochemistry Analytes Ludlum Radiological Survey Meters - Ludlum rate meters with accompanying probes measure alpha, beta, and gamma radiation. The following Ludlum meters are included in this document: - Ludlum Model 192 MicroR Radiation Meter (Page lb-1) - Used as a low-level gamma radiation surveying instrument. The detector used in the instrument is an internal 2-inch by 1-inch sodium-iodide scintillation counter. The detection range is 0 to 5,000 microroentgens per hour ((iR/hr). - Ludlum Model 2241-3 Survey Meter with Model 44-9, 43-90 or 44-2 Probe (Page Ib- 2) - The Model 2241-3 is a sealer/rate meter that can use different probes: the Model 44-9 probe detects alpha/beta/gamma contamination; the Model 43-90 probe is used for measuring alpha contamination; and the 44-2 probe is used to determine the presence of gamma-emitting contamination. The Model 2241-3 also has a sealer function to count radioactive disintegrations for a pre-selected time. - Ludlum Model 15 Survey Meter (Page lb-2) - Used as a neutron counter by attaching the neutron probe beneath the instrument in a shielded chamber. The survey meter measures radiation in counts per minute (cpm) and has an effective operating range of 0 to 500,000 cpm. It is used predominantly as a neutron detection device; however, the auxiliary external Model 44-7 Geiger-Mueller probe will measure beta and gamma radiation. - Ludlum Model 3030 Alpha/Beta Counter (Page lb-3) - Dual-channel counter for simultaneous alpha and beta radiation measurement of samples up to 2 inches in diameter and 0.4 inches thick. This instrument is primarily used for determining removable levels of radioactive contamination on wipes and airborne concentrations September 2010 ------- SAM Companion - Field Screening Equipment Document collected on filters. The user-defined count times enable detection ranges from 0 to 999,999 cpm, with user-defined alarm levels. RADeCo Model H810AC High Volume Air (Page lb-4) - Used for air sample collection coupled to the Ludlum Model 3030 alpha/beta counter. Typical maximum flow rates vary from 2.7 cubic feet per minute (cfm) to 11.8 cfin, depending on the cartridge and filter combination. Microprocessor-based unit does not use rotameter or mechanical time meter, increasing accuracy. Thermo-Eberline RO20E Ion Chamber (Page lb-3) - Provides real-time monitoring of beta, gamma, and x-ray radiation with a portable ion chamber, which is vented to atmospheric pressure and specifically designed to have flat energy response into the x-ray region. The detector is compensated over the operational temperature range for output accuracy within 10%. The range of operation is 1 millirem per hour (mrem/hr) to 50 roentgen equivalent in man (rems) per hour. These instruments are usually used as a secondary survey device if high radiation fields have been indicated by a more sensitive survey instrument such as the Ludlum Model 192 MicroR Radiation Meter. Berkeley Nucleonics SAM 940 Gamma Spectrometer (Page lb-5) - Portable gamma and neutron radiation detector that identifies multiple radionuclides simultaneously. Identifies the radionuclide, category of the radionuclide (medical, industrial, or Special Nuclear Material), and calculates the isotope-specific dose rates, all within one second. Contains a 2-inch by 2-inch external sodium-iodide detector for greater sensitivity. Ludlum Model 239-IF Floor Monitor with 2350-1 Data Logger. 43-37-582 Gas Proportional Detector Coupled to Ludlum 2380-1 Data Logger (Page lb-6) - Used for surface sample collection and detection of alpha, beta, and gamma emitters. Monitors floor contamination using a gas proportional detector (recommended gas P-10 [10% methane, 90% argon]). Flow meter is adjustable from 0 to 100 cubic centimeters per minute (cc/min) and has a threshold of 2 to 4 millivolts (mVs). Typical efficiencies are -17% (alpha), ~ 25% (beta), and ~ <1% (gamma). Gamma Tracer and Base Station (Page lb-7) - Uses Geiger-Miiller tubes for detection of gamma emitters and integrates and stores up to 12,800 data points as time correlated dose rates (time cycles are user selectable). Provides real-time monitoring from either single or multiple units. Data from each unit can be downloaded into a local network using an embedded device serving as an IR transceiver. September 2010 ------- SAM Companion - Field Screening Equipment Document 4.0 References The following resources were used to prepare this document. Additional equipment vendor and manufacturer sources used for commercial product information are provided in Tables la and Ib. Arnold, F. October 2006. "Measuring New Fumigants with Drager-Tubesฎ." Ninth International Working Conference on Stored Product Protection, New Chemicals and Food Residues. Sao Paulo, Brazil. Davis, G.L. December 2008. "CBRNE - Chemical Detection Equipment." eMedicine. eMedicine, Inc. Omaha Neb. Department of Homeland Security. January 2007. "Guide for the Selection of Chemical Detection Equipment for Emergency First Responders," 3rd Ed. pp. C-7, C-l 1, C-l 13, and C- 235. Department of Homeland Security. Washington, D.C. https://www.rkb.us/contentdetail.cfm?content_id=97670 (accessed September 22, 2009) Fatah, A.A., Barrett, J.A., Arcilesi, R.D., Ewing, K.J., Lattin, C.H., and Helinski, M.S. June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders, v II." U.S. Department of Justice, National Institute of Justice. Washington, D.C. http://www.ncjrs.gov/pdffilesl/nij/184450.pdf (accessed September 22, 2009) Kovacs, T. 2006. "Developed Physical Detection-Possibilities of Chemical Agents." Acta Polytechnica Hungarica, 3(2): 133-141. National Research Council, Commission on Life Sciences, Committee on R&D Needs for Improving Civilian Medical Response to Chemical and Biological Terrorism Incidents. 1999. "Chemical and Biological Terrorism, Research and Development to Improve Civilian Medical Response." National Academy Press. Washington, D.C. Longworth, T.L., Barnhouse, J.L., and Ong, K.Y. February 1999. "Testing of Commercially Available Detectors Against Chemical Warfare Agents: Summary Report." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, Md. http://www.chem-bio.com/resource/1999/dp detectors summary.pdf (accessed September 22, 2009) Longworth, T.L. and Ong, K.Y. May 2001. "Domestic Preparedness Program: Testing of Detectors Against Chemical Warfare Agents - Summary Report, UC AP2C Portable Chemical Contamination Control Monitor Collective Unit." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, MD. http://www.ecbc .army.mil/downloads/reports/ECBC_uc_ap2c .pdf (accessed September 22, 2009) Multi-Agency Radiological Laboratory Analytical Protocols Manual (MARLAP). July 2004. U.S. EPA. http://www.epa.gov/rpdwebOO/docs/marlap/402-b-04-001b-17-final.pdf (accessed September 22, 2009) Ong, K.Y., Longworth, T.L., and Barnhouse, J.L. August 2000. "Domestic Preparedness Program: Testing of APD2000 Chemical Warfare Agent Detector Against Chemical Warfare Agents Summary Report." Soldier and Biological Chemical Command, AMSSB-RRT, September 2010 ------- SAM Companion - Field Screening Equipment Document Aberdeen Proving Ground, Md. http://www.chem- bio.com/resource/2000/apd2000_detector.pdf (accessed September 22, 2009) Rostker, B. July 1998. "Case Narrative Czech and French Reports of Possible Chemical Agent Detections, Tab D, Czech and French Detection Equipment." Gulflink, U.S. Department of Defense, Force Health Protection and Readiness, Department of Defense. University of British Columbia, School of Environmental Health (SOEH), the SOEH Laboratory. Equipment. Vancouver, BC, Canada. http://www.cher.ubc.ca/SOEHLab/equipment.htm#GasVapour (accessed September 22, 2009) U.S. Army Soldier and Biological Chemical Command. October 2001. "M256A1 Chemical Agent Detector." Soldier and Biological Chemical Command. Aberdeen Proving Ground, Md. http://www.edgewood.army.mil/ps/download/ECBC_m256al.pdf (accessed September 22, 2009) U.S. Army Soldier and Biological Chemical Command. October 2001. "M8 Chemical Agent Detector Paper." Soldier and Biological Chemical Command. Aberdeen Proving Ground, Md. http://www.ecbc.army.mil/ps/download/ECBC_m8.pdf (accessed September 22, 2009) U.S. EPA. August 2001. "Measuring Elemental and Total Mercury Emissions." Environmental Technology Verification Program. http://epa.gOv/etv/pubs/0l_vs_lumex_cem.pdf (accessed September 22, 2009) U.S. EPA. June 2009. Radiation Protection. http://www.epa.gov/rpdwebOO/(accessed September 22, 2009) U.S. EPA. "Technology Performance Summary: Proengin AP4C Handheld Detector for Toxic Industrial Chemicals." http://www.epa.gov/nhsrc/news/newsl03108b.html (accessed September 22, 2009) U.S. EPA. August 2009. "Technology Performance Summary: Smiths Detection APD 2000ฎ Handheld Detector for Chemical Warfare Agents." http://www.epa.gov/nhsrc/news/newsl03108c.html (accessed September 22, 2009) U.S. Nuclear Regulatory Commission (formerly, Atomic Energy Commission). June 1974. Regulatory Guide 1.86, Termination of Operating Licenses for Nuclear Reactors, Table 1. http://www.nrc.gov/reading-rm/doc-collections/reg-guides/power-reactors/active/01-086/01- 086.pdf (accessed September 22, 2009) September 2010 ------- Table 1a: Field Screening Equipment - Use in Detecting Chemistry Analytes Listed in SAM Equipment detection levels, ranges, and units are cited as provided by the manufacturer and/or reference cited. Equipment (Testing Information) SAM Analyte(s) CASRN Media AP2C Chemical Agent Monitor Proengin Inc. 140 South University Drive, Suite F Plantation, FL 33324 http://vwvw.proengin.com 1) Kovacs, T: 2006. "Developed Physical Detection-Possibilities of Chemical Agents. "Acta Polytechnica Hungarica, 3(2): 133-141. Matrix: Air Analytes: 5-10 ppm (as G- and V-agents) 2) Fatah, A.A., Barrett, J.A., Arcilesi, R.D., Ewing, K.J., Lattin, C.H., and Helinski, M.S. June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders, v II." U.S. Department of Justice, National Institute of Justice. Washington, D.C. Matrix: Air Analytes: GA(13.3 ug/m3, rj.002 ppm); GB (11.5 ug/m3, 0.002 ppm); GD (7.45 ug/m3, 0.001 ppm); VX(656 ug/m3, 0.06 ppm); HD (6.51 ug/m3, 0.001 ppm) Other: Sulfur- and phosphorus-containing compounds may act as interferents 3) Rostker, B. Gulflink. July 1998. "Case Narrative Czech and French Reports of Possible Chemical Agent Detections, Tab D, Czech and French Detection Equipment." Gulflink, Department of Defense, Force Health Protection and Readiness, Department of Defense. Matrix: Air Analytes: GA (100 ug/m3); GB (100 ug/m3); GD (100 ug/m3); GF (100 ug/m3); HD (400 ug/m3); VX(150ug/m3) 4) Longworth, T.L. and Ong, K.Y. May 2001. "Domestic Preparedness Program: Testing of Detectors Against Chemical Warfare Agents - Summary Report, UC AP2C Portable Chemical Contamination Control Monitor Collective Unit." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, MD. Matrix: Air Analytes: GA (30 ug/m3, 0.004 ppm); GB (20.0 ug/m3, 0.003 ppm); HD (930 ug/m3, 0.142 ppm) Cyclohexyl sarin (GF) 329-99-7 1-Methylethyl ester ethylphosphonofluoridic acid (GE) 1189-87-3 Mustard, sulfur/ Mustard gas (HD) 505-60-2 R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] 159939-87-4 Sarin (GB) 107-44-8 Soman (GD) 96-64-0 Tabun (GA) 77-81-6 VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] 21738-25-0 VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] 78-53-5 VM [phosphonothioic acid, methyl-, S- (2-(diethylamino)ethyl) O-ethyl ester] 21770-86-5 VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] 50782-69-9 Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1a -1 September 2010 ------- Equipment (Testing Information) AP4C Chemical Agent Monitor Proengin Inc. 140 South University Drive, Suite F Plantation, FL 33324 http://vwvw.proengin.com 1 ) U.S. EPA. Technology Performance Summary: Proengin AP4C Handheld Detector for Toxic Industrial Chemicals. Matrix: Air Analvtes: Arsine (<1 mg/m3, 0.3 pprn); hydrogen cyanide (<18.7 mg/m3, 17 pprn); cyanogen chloride (<1 mg/m3, 0.4 ppm); hydrogen sulfide (<57.4 mg/m3, 41 ppm) SAM Analyte(s) Ammonia Arsine BZ (Quinuclidinyl benzilate) Carbon disulfide Cyanogen chloride Cyclohexyl sarin (GF) Hydrogen cyanide Hydrogen sulfide 1-Methylethyl ester ethylphosphonofluoridic acid (GE) Mustard, sulfur/ Mustard gas (HD) Phosphorus trichloride R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] Sarin (GB) Soman (GD) Sulfur dioxide Tabun (GA) VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] VM [phosphonothioic acid, methyl-, S- (2-(diethylamino)ethyl) O-ethyl ester] VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] CASRN 7664-41-7 7784-42-1 6581-06-2 75-15-0 506-77-4 329-99-7 74-90-8 7783-06-4 1189-87-3 505-60-2 7719-12-2 159939-87-4 107-44-8 96-64-0 7446-09-5 77-81-6 21738-25-0 78-53-5 21770-86-5 50782-69-9 Media Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1a - 2 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media APD 2000ฎ Chemical Agent Monitor Smiths Detection 1601 North Kent Street #200 Arlington, VA 22209 http://vwvw.smithsdetection.com 1) U.S. EPA. August 2009. Technology Performance Summary: Smiths Detection APD 2000ฎ Handheld Detector for Chemical Warfare Agents. Matrix: Air Analvtes: GB (>0.015 ppm); HD (<0.09 ppm) 2) Ong, K.Y., Longworth, T.L., and Barnhouse, J.L. August 2000. "Domestic Preparedness Program: Testing of APD2000 Chemical Warfare Agent Detector Against Chemical Warfare Agents Summary Report." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, MD Matrix: Air Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 Mustard, sulfur/ Mustard gas (HD) 505-60-2 Sarin (GB) 107-44-8 Soman (GD) 96-64-0 Tabun (GA) 77-81-6 Analvtes: HD (220 ug/m 0.004-0.006 ppm) 0.033 ppm); GA (27.0 ug/m3, 0.004 ppm); GB (21.0- 37.0 ug/m3 VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] 50782-69-9 Air Air Air Air Air Air Air Air Draeger Civil Defense Simutest (CDS) Kit with Detection Tube Kits I and V Draeger Safety Inc. 101 Technology Drive Pittsburg, PA 15275-1057 http://www.draeger.com 1) Civil Defense Kit Illustrated Accessory Guide http://www.skcgulfcoast.com/drager/Drager_CDS_Kit_Accessory_Guide.pdf (accessed August 26, 2009) Other: Complete CDS Kit includes 5 sets of tubes from Kit I and Kit V. Kits I and V can be used to replenish CDS kit. For additional detection capabilities, refer to full vendor listing of compatible detection tubes (i.e., Kits II, III, IV, etc.). 2) Civil Defense Simultest Kit http://www.afcintl.com/pdf/CDSKit.pdf (accessed August 26, 2009) Matrix: Air Analvtes: Chlorine (0.2 - 30 ppm); cyanogen chloride (0.25 - 30 ppm); HD (1 mg/m3 as thioethers) hydrogen cyanide (2-150 ppm); lewisite (3 mg/m3 as arsenic); nitrogen mustards (1 mg/m3 as basic nitrogen compounds); phosgene (0.25 - 15 ppm); G- and V-agents (0.05 ppm of phosphoric acid esters) Ammonia 7664-41-7 Arsine 7784-42-1 Chlorine 7782-50-5 Chloropicrin 76-06-2 Cyanogen chloride 506-77-4 Dichlorvos 62-73-7 Hydrogen cyanide 74-90-8 Hydrogen sulfide 7783-06-4 Lewisite 1 (L-1)[2- chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 1-Methylethyl ester ethylphosphonofluoridic acid (GE) 1189-87-3 Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] 538-07-8 Mustard, nitrogen (HN-2) [2,2'-dichloro- N-methyldiethylamine N,N-bis(2- chloroethyl)methylamine] 51-75-2 Air Air Air Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1a - 3 September 2010 ------- Equipment (Testing Information) Draeger Civil Defense Simutest (CDS) Kit with Detection Tube Kits 1 and V (cont.) 3) Arnold, F. October 2006. "Measuring New Fumigants with Drager-Tubesฎ." Ninth International Working Conference on Stored Product Protection, New Chemicals and Food Residues. Sao Paulo, Brazil. Matrix: Air Analytes: Chloropicrin (0.1 - 2 ppm); phosphine (0.01 - 1 and 0.1-4 ppm) 4) Department of Homeland Security. January 2007. "Guide for the Selection of Chemical Detection Equipment for Emergency First Responders," 3rd Ed. p. C-7. Department of Homeland Security. Washington, D.C. Matrix: Air Analytes: Arsine (0.1 ppm); chlorine (0.2 ppm); cyanogen chloride (0.25 ppmv); HD (1 mg/m3); hydrogen cyanide (1 ppm); lewisite (3 mg/m3); nitrogen mustard (1 mg/m3); phosgene (0.2 ppm); G- and V-agents (0.025 ppm as dichlorovos) Draeger MultiWarn Draeger Safety Inc. 101 Technology Drive Pittsburg, PA 15275-1 057 http://www.draeger.com 1) Fatah, A.A., Barrett, J.A., Arcilesi, R.D., Ewing, K.J., Lattin, C.H., and Helinski, M.S. June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders vll"US Department of Justice National Institute of Justice. Washington, D.C. Matrix: Air A i i+ A /n onn \ /n -in \ ki /n on \ fi /n on ppm), hydrogen cyanide (0 - 50 ppm), hydrogen sulfide (0-100 ppm), methylamine (0-100 ppm), phosgene (0-3 ppm), sulfur dioxide (0 - 2000 ppm), phosphine (0-10 ppm), ethylene SAM Analyte(s) Mustard, nitrogen (HN-3) [tris(2- chloroethyl)amine] Mustard, sulfur/ Mustard gas (HD) Phosgene Phosphine R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] Sarin (GB) Soman (GD) Sulfur dioxide Tabun (GA) VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] VM [phosphonothioic acid, methyl-, S- (2-(diethylamino)ethyl) O-ethyl ester] VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] Ammonia Arsine Chlorine Ethylene oxide Formaldehyde Hydrogen cyanide Hydrogen sulfide Methylamine Phosgene __ . . . Phosphine CASRN 555-77-1 505-60-2 75-44-5 7803-51-2 159939-87-4 107-44-8 96-64-0 7446-09-5 77-81-6 21738-25-0 78-53-5 21770-86-5 50782-69-9 7664-41-7 7784-42-1 7782-50-5 75-21-8 50-00-0 74-90-8 7783-06-4 74-89-5 75-44-5 7803-51-2 Media Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1a - 4 September 2010 ------- Equipment (Testing Information) Draeger MultiWarn II Draeger Safety Inc. Pittsburg PA 15275-1 057 http://vwvw.draeger.com 1) Draeger MultiWarn II Brochure http://www.skcgulfcoast.com/drager/Drager_Multiwarn_Brochure.pdf (accessed August 25, 2009) Analytes' Acrylonitril6 (0 200 ppm)' ammonia (0 300 ppm)' arsin6 (0 10 ppmY chlorin6 (0 20 ppm); ethylene oxide (0 - 200 ppm); formaldehyde (0 - 200 ppm); hydrogen cyanide (0 - 50 ppm); hydrogen sulfide (0 - 1000 ppm); methylamine (0-100 ppm); phosphine (0 - 1000 ppm); Draeger Polytron 7000 Series Detectors Draeger Safety Inc. 101 Technology Drive Pittsburg, PA 15275-1 057 http://www.draeger.com 1 ) Drager 2008 List of Detectable Gases and Vapors http://www.draeger.com/media/10/01/10/10011004/gas list br 9046375 en. pdf (accessed August 25, 2009) Matrix: Air Analvtes: Acrvlonitrile (20 - 1 00 ppm); allvl alcohol (20 - 200 ppm); ammonia (50 - 1 000 ppm); 100 ppm); hydrogen chloride (3-100 ppm); hydrogen cyanide (10-50 ppm); hydrogen fluoride (100 ppm); phosgene (0.1 - 1 ppm); phosphine (0.3 -20 ppm); phosphorus trichloride (3- 30 ppm); propylene oxide (20 - 200 ppm); sulfur dioxide (5 - 1 00 ppm); sulfur trioxide (30 ppm); TEA (100 ppm) SAM Analyte(s) Acrylonitrile Ammonia Arsine Chlorine Ethylene oxide Formaldehyde Hydrogen cyanide Hydrogen sulfide Methylamine Phosphine Propylene oxide Sulfur dioxide Acrylonitrile Allyl alcohol Ammonia Arsine Boron trifluoride Chlorine 2-Chloroethanol 1,2 Dichloroethane Ethylene oxide Hydrogen bromide Hydrogen chloride Hydrogen cyanide Hydrogen fluoride Hydrogen sulfide Methyl hydrazine Methylamine Phosgene Phosphine Phosphorus trichloride Propylene oxide Sulfur dioxide Sulfur trioxide Triethanolamine (TEA) (degradation product of HN-3) CASRN 107-13-1 7664-41-7 7784-42-1 7782-50-5 75-21-8 50-00-0 74-90-8 7783-06-4 74-89-5 7803-51-2 75-56-9 7446-09-5 107-13-1 107-18-6 7664-41-7 7784-42-1 7637-07-2 7782-50-5 107-07-3 107-06-2 75-21-8 10035-10-6 7647-01-0 74-90-8 7664-39-3 7783-06-4 60-34-4 74-89-5 75-44-5 7803-51-2 7719-12-2 75-56-9 7446-09-5 7446-11-9 102-71-6 Media Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1a - 5 September 2010 ------- Equipment (Testing Information) Draeger Warning Stations/Unit Sensor Bias Station HazCat Chemical Identification System Haztech Systems, Inc. P.O. Box 929 3919 Bootjack Lane Mariposa, CA 95338 http://vwvw.hazcat.com/ 1) Hazcat Industrial Chemical Identification Systems User Guide http://www.hazcat.com/ (accessed August 25, 2009) Matrix: Air Analytes: Kits KT1204 and KT1206 come with ammonia, hydrogen cyanide, and phenol gas detection tubes (many other tubes available) Other: Three kits: 1) KT1209 basic kit without pump or detection tubes, 2) KT1206 with Draeger pump and detection tubes, and 3) KT1204 with Gastec pump and detection tubes 2) Department of Homeland Security. January 2007. "Guide for the Selection of Chemical Detection Eguipment for Emergency First Responders," 3rd Ed. p. C-1 1 . Department of Homeland Security. Washington, D.C. Analvtes: GA (<0.5 ppm): GB (<0.13): HD (<40 mg): HN (<40 mg): VX (0.25 ppm) SAM Analyte(s) TBD Ammonia Ethyldichloroarsine (ED) Hydrogen cyanide Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] Mustard, nitrogen (HN-2) [2,2'-dichloro- N-methyldiethylamine N,N-bis(2- chloroethyl)methylamine] Mustard, nitrogen (HN-3) [tris(2- chloroethyl)amine] Mustard, sulfur/ Mustard gas (HD) Phenol Sarin (GB) Tabun (GA) VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] CASRN TBD 7664-41-7 598-14-1 74-90-8 541-25-3 40334-69-8 40334-70-1 538-07-8 51-75-2 555-77-1 505-60-2 108-95-2 107-44-8 77-81-6 50782-69-9 Media TBD Air Water Air Solid Air Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Air Water Air Solid Water Air Solid Water Air Solid Chemistry Field Screening Eguipment Table 1a - 6 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media Jeromeฎ 411/431 Mercury Vapor Analyzer (MVA) Arizona Instrument 3375 North Delaware Street Chandler, AZ 85225 vwwv.azic.com 1) University of British Columbia, School of Environmental Health Laboratory. Equipment. Matrix: Air Mercury, Total 7439-97-6 Analytes: Hg (0.001 - 0.999 mg/m ) 2) Jeromeฎ 431-X Mercury Vapor Analyzer Manual http://www.equipcoservices.com/pdf/jerome431.pdf (accessed August 25, 2009) Matrix: Air Analytes: Hg (0.003 - 0.999 mg/m3 Other: 431 model Mercuric chloride (analyze for total mercury) 7487-94-7 3) Jeromeฎ 411 Mercury Vapor Analyzer Manual http://vwvw.equipcoservices.com/pdf/manuals/jerome411 .pdf (accessed August 25, 2009) Matrix: Air Analytes: Hg (0.003 - 1.999 mg/m3) Other: 411 model Methoxyethylmercuric acetate (analyze for total mercury) 151-38-2 Air Air Air M256A1 - Chemical Agent Detector Kit Anachemia Canada Inc. 255 Norman Lachine, Quebec, Canada HSR 1A3 1) Fatah, A.A., Barrett, J.A., Arcilesi, R.D., Ewing, K.J., Lattin, C.H., and Helinski, M.S. June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders, v II." U.S. Department of Justice, National Institute of Justice. Washington, D.C. Matrix: Air, liquid Analytes: Cyanogen chloride (7870 ug/m3, 3.13 ppm); GB: (4.58 ug/m3, 0.0008 ppm); GD: (14.9 ug/m3, 0.002 ppm); HD (2020 ug/m3, 0.31 ppm); hydrogen cyanide 7880 ug/m3, 7.13 ppm); lewisite (8480 ug/m3, 1 ppm); VX: (21.9 ug/m3, 0.002 ppm) Cyanogen chloride 506-77-4 Hydrogen cyanide 74-90-8 Lewisite 1 (L-1)[2- chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 1-Methylethyl ester ethylphosphonofluoridic acid (GE) 1189-87-3 Mustard, sulfur/ Mustard gas (HD) 505-60-2 R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] 159939-87-4 Water Air Air Water Air Water Air Water Air Water Air Water Air Water Air Chemistry Field Screening Equipment Table 1a - 7 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media M256A1 - Chemical Agent Detector Kit (cont.) 2) National Research Council, Commission on Life Sciences, Committee on R&D Needs for Improving Civilian Medical Response to Chemical and Biological Terrorism Incidents. 1999. "Chemical and Biological Terrorism, Research and Development to Improve Civilian Medical Response." National Academy Press. Washington, D.C. Analytes: Cyanogen chloride (3000 |jg/m3, 25 minutes); HD (20.0 ug/m3); lewisite (2000 ug/m3); G- and V-agents (5.0 ug/m3, 15 minutes) 3) Davis, G.L. December 2008. "CBRNE - Chemical Detection Equipment." eMedicine Matrix: Air Analvtes: Hydrogen cyanide (1100 ug/m3); HD (20.0 ug/m3); Q- and V-agents (5.0 ug/m3) Other: Prone to false-positive results; has not been demonstrated to produce false-negative results in real situations. Sarin (GB) 107-44-8 Water Air Soman (GD) 96-64-0 Water Air VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] 21738-25-0 Water Air VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] 78-53-5 Water Air VM [phosphonothioic acid, methyl-, S-(2-(diethylamino)ethyl) O-ethyl ester] 21770-86-5 Water Air VX [O-ethyl-S-(2- diisopropylaminoethyl)methyl- phosphonothiolate] 50782-69-9 Water Air M8 Paper (VGH ABC-M8) Chemical Agent Detector Paper Truetech, Inc. 680 Elton Street Riverhead, NY 11301 (631)727-8600 1) Longworth, T.L., Barnhouse, J.L., and Ong, K.Y. February 1999. "Testing of Commercially Available Detectors Against Chemical Warfare Agents: Summary Report." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, MD. Other: M8 paper is used to detect the presence of liquid V, G, and H chemical agents via direct contact of the paper with a suspected liquid. It cannot be used to detect agents in water or as aerosolized and does not detect vapors. 2) U.S. Army Soldier and Biological Chemical Command. October 2001. "M8 Chemical Agent Detector Paper." Soldier and Biological Chemical Command. Aberdeen Proving Ground, MD. Matrix: Non-aqueous Liquid Analvtes: GA, GB, GD, GF, HD, and lewisite Cyclohexyl sarin (GF) 329-99-7 Non-aqueous Liquid Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Non-aqueous Liquid Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Non-aqueous Liquid Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 Non-aqueous Liquid Lewisite oxide (degradation product of lewisite) 1306-02-1 Non-aqueous Liquid Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] 538-07-8 Non-aqueous Liquid Mustard, nitrogen (HN-2) [2,2'-dichloro- N-methyl diethylamine N,N-bis(2- chloroethyl)methylamine] 51-75-2 Non-aqueous Liquid Mustard, nitrogen (HN-3) [tris(2- chloroethyl)amine] 555-77-1 Non-aqueous Liquid Mustard, sulfur/ Mustard gas (HD) 505-60-2 Non-aqueous Liquid R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] 159939-87-4 Non-aqueous Liquid Sarin (GB) 107-44-8 Non-aqueous Liquid Chemistry Field Screening Equipment Table 1a - 8 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media M8 Paper (VGH ABC-M8) Chemical Agent Detector Paper (cont.) Soman (GD) 96-64-0 Non-aqueous Liquid Tabun (GA) 77-81-6 Non-aqueous Liquid VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] 21738-25-0 Non-aqueous Liquid VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] 78-53-5 Non-aqueous Liquid VM [phosphonothioic acid, methyl-, S-(2-(diethylamino)ethyl) O-ethyl ester] 21770-86-5 Non-aqueous Liquid VX [O-ethyl-S-(2- diisopropylaminoethyl) methyl phosphonothiolate] 50782-69-9 Non-aqueous Liquid M9 Chemical Agent Detector Paper Truetech, Inc. 680 Elton Street Riverhead, NY 11301 (631)727-8600 1) M9 Detection Paper Product Information http://vwvw.aramsco.com/eserv/eclipse.ecl?PROCID=WEBPROC.WOE.AUTH&AUTOLOG&SEA RCH=.6511 (accessed August 28, 2009) Other: M9 paper is used to detect the presence of liquid V, G, and H chemical agents via direct contact of the paper with a suspected liquid. Does not detect vapors. Can be purchased with or without adhesive backing in either a roll or booklet of sheets. 2) Chemical Agent Liquid Detector Paper - M-9 http://firstrespondernetwork.com/items/products/detection/detection-paper~kits/m9-c9-paper- 091402-detail.htm (accessed August 29, 2009) Other: Can quickly determine the presence of G, V, or H agents in liquid Cyclohexyl sarin (GF) 329-99-7 Non-aqueous Liquid Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Non-aqueous Liquid Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Non-aqueous Liquid Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 Non-aqueous Liquid Lewisite oxide (degradation product of lewisite) 1306-02-1 Non-aqueous Liquid Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] 538-07-8 Non-aqueous Liquid Mustard, nitrogen (HN-2) [2,2'-dichloro- N-methyl diethylamine N,N-bis(2- chloroethyl)methylamine] 51-75-2 Non-aqueous Liquid Mustard, nitrogen (HN-3) [tris(2- chloroethyl)amine] 555-77-1 Non-aqueous Liquid Mustard, sulfur/ Mustard gas (HD) 505-60-2 Non-aqueous Liquid R-33 (VR) [methylphosphonothioic acid, S-[2-(diethylamino)ethyl O-2- methylpropyl ester] 159939-87-4 Non-aqueous Liquid Sarin (GB) 107-44-8 Non-aqueous Liquid Soman (GD) 96-64-0 Non-aqueous Liquid Tabun (GA) 77-81-6 Non-aqueous Liquid Chemistry Field Screening Equipment Table 1a - 9 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media M9 Chemical Agent Detector Paper (cont.) VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] 21738-25-0 Non-aqueous Liquid VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] 78-53-5 Non-aqueous Liquid VM [phosphonothioic acid, methyl-, S-(2-(diethylamino)ethyl) O-ethyl ester] 21770-86-5 Non-aqueous Liquid VX [O-ethyl-S-(2- diisopropylaminoethyl) methyl phosphonothiolate] 50782-69-9 Non-aqueous Liquid MDA Scientific Single Point Monitor (SPM) with Data Recorder Honeywell Analytics Inc. 400 Sawgrass Corporate Parkway, Suite 100 Sunrise, FL 33325 www.honeywell.com 1) Honeywell MDA Scientific SPM http://www.equipcoservices.com/pdf/mdaspm.pdf (accessed August 28, 2009) Matrix: Air Analvtes: Ammonia (2.6 - 75.0 ppm); arsine (15 - 150 ppb); chlorine (0.05- 1.5 ppm); phosphine (32 - 900 ppb); hydrogen bromide (0.3 - 9.0 ppm); hydrogen chloride (0.5 - 15 ppm); hydrogen cyanide (1.1 - 30 ppm); hydrogen fluoride (0.6 - 9.0 ppm); hydrogen sulfide (1.1 - 30 ppm); Other: Gas sensitivity to ppb levels Ammonia 7664-41-7 Arsine 7784-42-1 Chlorine 7782-50-5 Hydrogen bromide 10035-10-6 Hydrogen chloride 7647-01-0 Hydrogen cyanide 74-90-8 Hydrogen sulfide 7783-06-4 Phosphine 7803-51-2 Sulfur dioxide 7446-09-5 Air Air Air Air Air Air Air Air Air MIE DataRam Thermo Electron Corporation Environmental Instruments 27 Forge Parkway Franklin, MA 02038 www.thermo.com/ih 1) Argus Hazco MIE Personal DataRAM Aerosol Monitor http://argus-hazco.com/air-section/air-monitoring/mie-personal-dataram.htm (accessed August 27, 2009) Matrix: Air Analvtes: Asbestos particulates (0.001 - 399 mg/m3) Other: Particle size range: 0.1 - 10 urn Asbestos 1332-21-4 Air Chemistry Field Screening Equipment Table 1a -10 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media MIE DataRam (cont.) 2) Personal DataRan Series Product Overview http://vwvw.thermo.com/eThermo/CMA/PDFs/Product/productPDF_18492.pdf (accessed August 27, 2009) Matrix: Air Analvtes: Asbestos particulates (0.001 -400 mg/m3) Other: Flow Rate Range: 1-10 L/min (external pump required) Asbestos 1332-21-4 3) University of British Columbia, School of Environmental Health Laboratory. Equipment Matrix: Air Other: Particle size range: 0.1 - 10 urn Air MultiRAE Plus Multigas Monitor and Photoionization Detector (PID) RAE Systems 3775 North First Street San Jose, CA95134 www.raesystems.com 1) Department of Homeland Security. January 2007. "Guide for the Selection of Chemical Detection Equipment for Emergency First Responders," 3rd Ed. p. C-113. Department of Homeland Security. Washington, D.C. Matrix: Air Ammonia 7664-41-7 Arsine 7784-42-1 Carbon disulfide 75-15-0 Chlorine 7782-50-5 Cyclohexyl sarin (GF) 329-99-7 Hydrogen cyanide 74-90-8 Analvtes: Ammonia (1 - 50 ppm); arsine (0.2 - 2000 ppm); chlorine (0.1 - 50 ppm); GA (0.7 mg/m3, 0.1 ppm); GB (1.7 mg/m3, 0.3 ppm); GD (2.2 mg/m3, 0.3 ppm); GF (2 mg/m3, 0.3 ppm); HD (1.3 mg/m3, 0.2 ppm); HN-1 (1.4 mg/m3, 0.2 ppm); hydrogen cyanide (1.1-110 mg/m3, 100 ppm); hydrogen sulfide (1-100 ppm); L-1 (1.7 mg/m3, 0.2 ppm); phosphine (0.1-5 ppm); sulfur dioxide (0.1 -20 ppm) 2) Fatah, A.A., Barrett, J.A., Arcilesi, R.D., Ewing, K.J., Lattin, C.H., and Helinski, M.S. June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders, v II." U.S. Department of Justice, National Institute of Justice. Washington, D.C. Matrix: Air Hydrogen sulfide 7783-06-4 Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) 541-25-3 Lewisite 2 (L-2) [bis(2-chlorovinyl)- chloroarsine] (analyze for total arsenic) 40334-69-8 Lewisite 3 (L-3) [tris(2-chlorovinyl)- arsine] (analyze for total arsenic) 40334-70-1 Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] 538-07-8 Analvtes: Ammonia (0 - 50 ppm); chlorine (0-10 ppm); hydrogen cyanide (0-100 ppm); hydrogen sulfide (0-100 ppm); phosphine (0 - 50 ppm); sulfur dioxide (0-100 ppm) Mustard, sulfur/ Mustard gas (HD) 505-60-2 Air Air Air Air Air Air Air Air Air Air Air Air Chemistry Field Screening Equipment Table 1 a -11 September 2010 ------- Equipment (Testing Information) SAM Analyte(s) CASRN Media MultiRAE Plus Multigas Monitor and Photoionization Detector (PID) (cont.) 3) MultiRAE Plus One-to-Five Gas Monitor with VOC Detection http://www.raesystems.com/~raedocs/Data_Sheets/MultiRAE_Plus.pdf (accessed August 28, 2009) Matrix: Air Analvtes: Chlorine (0-10 ppm); phosphine (0-5 ppm); and sulfur dioxide (0 - 20 ppm) at 0.1 ppm resolution. Ammonia (0 - 50 ppm); hydrogen cyanide (0-100 ppm); hydrogen sulfide (0 - 100 ppm); and VOCs (0-200 ppm) at 1.0 ppm resolution Phosphine 7803-51-2 Sarin (GB) 107-44-8 Soman (GD) 96-64-0 Sulfur dioxide 7446-09-5 Tabun (GA) 77-81-6 Air Air Air Air Air RA-915+ Mercury Vapor Analyzer (MVA) OhioLumex Co. 9263 Ravenna Rd, Unit A-3 Twinsburg, OH 44087 vwwv.ohiolumex.com 1) Portable Zeeman Mercury Analyzer http://www.ohiolumex.com/download/Ra915_flyer.pdf (accessed August 26, 2009) Matrix: Air, water or solid Analvtes: Hg (2.0 ng/m3[air], 0.5 ng/L [water], 0.5 ug/kg [solid]) Other: Measuring range 0.00001 - 0.1 mg/m3 (air) Mercury, Total 7439-97-6 Mercuric chloride (analyze for total mercury) 7487-94-7 2) U.S. EPA. August 2001 . "Measuring Elemental and Total Mercury Emissions. " Environmental Technology Verification Program. Matrix: Water Other: Relative accuracy 58.2% for total mercury (levels: 7-8 ug/m3); 50.2% for elemental Methoxyethylmercuric acetate (analyze for total mercury) 151-38-2 mercury (levels: 6-7 ug/m3); and 99% for oxidized mercury (levels: 1-1.5 ug/m3) Water Air Solid Water Air Solid Water Air Solid TVA1000B Combined PID/FID Detector Thermo Electron Corporation Environmental Instruments 27 Forge Parkway Franklin, MA 02038 www.thermo.com/ih 1) Thermo Scientific TVA1OOOB Toxic Vapor Analyzer http://www.thermo.com/eThermo/CMA/PDFs/Product/productPDF_5619.pdf (accessed August 28, 2009) Matrix: Air Other: PID Dynamic range (0.5 - 2000 ppm); FID dynamic range (0.5 - 50000 ppm); PID linear range (0.5 - 500 ppm); FID linear range (0.5 - 10000 ppm) Allyl alcohol 107-18-6 Ammonia 7664-41-7 Carbon disulfide 75-15-0 Air Air Air Chemistry Field Screening Equipment Table 1a -12 September 2010 ------- Equipment (Testing Information) TVA1000B Combined PID/FID Detector (cont.) 2) Longworth, T.L., Barnhouse, J.L., and Ong, K.Y. February 1999. "Testing of Commercially Available Detectors Against Chemical Warfare Agents: Summary Report." Soldier and Biological Chemical Command, AMSSB-RRT, Aberdeen Proving Ground, MD. Matrix. Air Analvtes: HD (1.9 mg/m3, 0.29 ppm); GA (4.1 mg/m3, 0.61 ppm); GB (26 mg/m3, 4.46 ppm) 3) Feld Environmental Instruments http://vwvw.equipcoservices.com/rentals/air-monitoring/flame-ionization-detectors.html (accessed August 28, 2009) Matrix: Air Other: PID Dynamic ranqe (0.5 - 2000 ppm); FID dynamic ranqe (0.5 - 50000 ppm); PID linear range (0.5 - 500 ppm); FID linear range (0.5 - 10000 ppm) 4) Fatah A A Barrett JA Arcilesi RD Ewing KJ Lattin CH and Helinski MS June 2000. "Guide for the Selection of Chemical Agent and Toxic Industrial Material Detection Equipment for Emergency First Responders, v II." U.S. Department of Justice, National Institute of Justice. Washington, D.C. Matrix: Air Analvtes: GA (0.61 ppm); HD (0.29 ppm) 5) Department of Homeland Security. January 2007. "Guide for the Selection of Chemical Detection Equipment for Emergency First Responders," 3rd Ed. p. C-235. Department of Homeland Security. Washington, D.C. Analvtes: Allyl alcohol (10 ppm, PID & FID); ammonia (10 ppm, PID only); carbon disulfide (10 ppm, PID only); ethylene oxide (10 ppm, PID & FID); formaldehyde (10 ppm, PID & FID) SAM Analyte(s) Ethylene oxide Formaldehyde Mustard, sulfur/ Mustard gas (HD) Sarin (GB) Tabun (GA) CASRN 75-21-8 50-00-0 505-60-2 107-44-8 77-81-6 Media Air Air Air Air Air Chemistry Field Screening Equipment Table 1a -13 September 2010 ------- Chemistry Field Screening Equipment Table 1a -14 September 2010 ------- Table 1b: Field Screening Equipment - Use in Detecting Radiochemistry Analytes Listed in SAM 5.0 The following assumptions/nuclear physics variables should be considered when assessing data from each instrument: It is assumed that standard health physics and radiation protection protocols are used consistently when comparing measurements. For example, all comparative radiation dose measurements are made at the same distance from the source term (at contact, one foot, etc.), all contamination measurements are consistent as to source to detector configuration, and the efficiency of the detector is well known to perform comparative readings from one detector system to another. It is assumed, for gamma spectroscopy measurements for comparative results, that the source configuration characteristics are well known to take into consideration the Z (density value of composite composition) of matrix, the Z of the container, expected homogeneity of the radioisotope in the sample matrix, and sample volume for self-absorption and gamma attenuation coefficients. For example, Am-241 measurements at the surface of an open steel container will give higher values because there is no steel to attenuate the low energy gamma vs. measuring the same container from the side through the steel. Minimum Detectable Activities, count rates, and/or dose rates are well established for each instrument prior to field utilization and re-evaluated to ambient backgrounds, in the field, to assess the instrument's capability to produce acceptable and usable data. If field measurements cannot determine presence/absence of a contaminant and samples have to be taken for laboratory analysis, ensure sample size is of sufficient quantity to enable the laboratory to meet presence/absence criteria (contact laboratory for sample size requirements prior to sampling). Equipment Ludlum Model 192 MicroR Radiation Meter Gamma Dose Rate Meter Ludlum Measurements, Inc. 501 Oak Street Sweetwater, TX 79556 http://www.ludlums.com/ Matrix: Water, Air, Soil/Sediment, Wipe Analvtes: Gamma emitters (not analyte specific) Other: 4 Ranges Micro-processor based Total counting range from 0 - 5,000 uR/hr Indicated use is for low level (uR) gamma survey Detector is 2" x 1" Nal Tl scintillator Sensitivity is typically 700 cpm/uR/hr (Cs-137 gamma ) Energy response is energy dependent Multipliers are x1, x10, x100, xlOOO Linearity reading is within ฑ10% of true value Alarm is dual action and can be set at desired point Analyte(s) y NOTE: Gamma photons from all gamma emitter isotopes present are measured without isotopic identification. CASRN NA Media Water NOTE: Measurements should always be at the surface of the liquid. Never immerse the detector in the liquid. Air Soil / Sediment Wipe Radiochemistry Field Screening Equipment 1b -1 September 2010 ------- Equipment Ludlum Model 2241-3 Survey Meter with: Model 44-9 probe for alpha/beta/gamma Model 43-90 probe for alpha Model 44-2 probe for gamma Ludlum Measurements, Inc. 501 Oak Street Sweetwater, TX 79556 http://www.ludlums.com/ Matrix: Water, Air, Soil/Sediment, Wipe Analytes: Alpha, beta, and gamma emitters (not analyte specific) Other: 6 Decade LCD Sealer with backlight Logarithmic and linear rate meter with total counting range of 0 - 500,000 cpm Audio divide Single channel analyzer Compatible detectors are the G-M, proportional, scintillation Connectors are Series "C" (others available) Audio is a built-in unimorph speaker with volume control Audio divide is a thumb switch for 1, 10, or 100 events-per-click Meter dial is 0 - 500 cpm; 50 - 500k cpm logarithmic scale (others available) Multipliers are x1, x10, x100, xlOOO, and Log for logarithmic scale Linearity reading is within ฑ10% of true value with detector connected Digital display is a 6 digit LCD display with 0.5" (1.3 cm) digits Digital ratemeter is a digital display of count rate Sealer will allow for gross counting with range of 0 - 999999 counts when selector switch is in Sealer position (controlled by count and hold buttons) Timer has selectable divisions of 0.1, 0.5, 1, 2, 5, 10 minutes or continuous NOTE: Concurrent use of sealer and digital ratemeter Ludlum Model 15 Survey Meter Ludlum Measurements, Inc. 501 Oak Street Sweetwater, TX 79556 http://www.ludlums.com/ Matrix: Water, Air, Soil/Sediment, Wipe Analvtes: Alpha, beta, and gamma emitters (not analyte specific) Other: End window G-M detector for alpha, beta, and gamma He-3 proportional detector with moderator for neutrons 4 ranges Total counting range of 0 - 500,000 cpm Indicated useis for fast and thermal neutron, alpha, beta-gamma survey Detectors are controlled bv selector switch Analyte(s) a, p, and y NOTE: Apha, beta, and gamma photons from all isotopes present are measured without isotopic identification. a, p, andy NOTE: Apha, beta, and gamma photons from all isotopes present are measured without isotopic identification. CASRN NA NA Media Water NOTE: Measurements should always be at the surface of the liquid. Never immerse the detector in the liquid. Gross alpha measurements of liquids are impractical. Air Soil /Sediment Wipe Water NOTE: Measurements should always be at the surface of the liquid. Never immerse the detector in the liquid. Gross alpha measurements of liquids are impractical. Air Radiochemistry Field Screening Equipment 1b - 2 September 2010 ------- Equipment Ludlum Model 15 Survey Meter (cont.) Neutron: Model 42-14H He-3 proportional detector with 3" (7.6 cm) diameter cadmium lined moderator for fast neutrons (remove detector from moderator for thermal neutrons) Energy response: Count response is not linear throughout energy spectrum (0.025 -12MeV) Sensitivity: Typically 60 cpm/mrem/hr (Am/Be fast neutrons) Alpha/beta/gamma: Model 44-7 thin end window G-M detector (others available) Window: 1.7 ฑ 0.3 mg/cm2 mica Window area: Active = 6.4 cm2; open = 5.2 cm2 Efficiency (4ir geometry) is typically 2% C-14; 10% Sr-90/Y-90; 7% Pu-239 Sensitivity is typically 2100 cpm/mR/hr (Cs-137 gamma) Meter dial: 0 - 500 cpm, 0 - 2.5 kV, battery test (others available) Multipliers: x1, x10, x100, xlOOO Thermo-Eberline RO20E Ion Chamber Thermo Eberline (Thermo Fisher Scientific) 27 Forge Parkway Franklin, MA 02038 www.thermo.com Matrix: Water, Air, Soil/Sediment, Wipe Analytes: Gamma emitters (not analyte specific) Other Indicated use is for gamma or X-ray exposure rate Detector is an air filled ionization chamber vented to atmosphere Range selections are 0 - 5, 0 - 50, 0 - 500 mR/hr/ 0 - 5, 0 - 50 R/h Ludlum Model 3030 Alpha/Beta Counter Ludlum Measurements, Inc. 501 Oak Street Sweetwater, TX 79556 http://www.ludlums.com/ Matrix: Water, Air, Soil/Sediment, Wipe Analvtes: Alpha and beta emitters (not analyte specific) Other: Dual Alpha/Beta Sealer Maximum sample size is 2" xO.4" Indicated use is for simultaneous alpha/beta sample counting Detector is ZnS(Ag) adhered to plastic scintillation material Tube is a 2" (5.1cm) diameter magnetically shielded photomultiplier Analyte(s) a, p, and Y NOTE: Apha, beta, and gamma photons from all isotopes present are measured without isotopic identification. y NOTE: Gamma photons from all gamma emitter isotopes present are measured without isotopic identification. o,p NOTE: Apha, beta, and gamma photons from all isotopes present are measured without isotopic identification. CASRN NA NA Media Soil /Sediment Wipe Water NOTE: Measurements should always be at the surface of the liquid. Never immerse the detector in the liquid. Air Soil / Sediment Wipe Water NOTE: Measurements of liquids can be made with this instrument only if the liquid is taken to dryness in an appropriate counting planchet prior to counting. Air Radiochemistry Field Screening Equipment 1b - 3 September 2010 ------- Equipment Ludlum Model 3030 Alpha/Beta Counter (cont.) Window is a 0.4 mg/cm2 aluminized mylar Active/open area is 20.3 cm2 Sample holder is brass housing with chrome-plated brass sample tray capable of holding 1" or 2" diameter samples Efficiency (4pi geometry) is as follows: Alpha 37% Th-230; 39% U-238; 37% Pu- 239; Beta 8% C-14; 27% Tc-99; 29% Cs-137; 26% Sr-90/Y-90 Cross talk: Alpha to beta 10% or less; beta to alpha 1% or less Background is as follows: Alpha - 3 cpm or less; beta/gamma - typically 50 cpm or less (10 uR/hr field ), 80 cpm or less (25 uR/hr field) Sealers are 2 each, 6 digit LCD displays with backlights providing a range of 0 - 999999 counts (started by count button) Count timer is adjustable from 0. 1 to 30 minutes (PC setting is user-defined via PC software) High voltage is adjustable from 200 to 2500 volts; beta threshold - 4 mV; alpha - 120mV Beta window is 50mV RADeCo Model H810AC High Volume Air (Sample Collection) 509 Norwich Avenue Raftville, CT 06380 http://www.radecoinc.com/ Matrix: Air Analvtes: NA Other: LCD displays total elapsed time, flow rate, and total volume Microprocessor based unit does not use rotometer or mechanical time meter, increasing accuracy Battery-backed data memory stores data if power cut off Tripod and carrying belt available Typical maximum flow rates vary from 2.7 cfm to 11.8 cfm, dependent upon cartridge and filter combination Analyte(s) NA CASRN NA NA Media Soil /Sediment Wipe Air NOTE: Air sample collection only; see Ludlum Model 3030 alpha/beta counter. Radiochemistry Field Screening Equipment 1b - 4 September 2010 ------- Equipment Berkeley Nucleonics SAM 940 Gamma Spectrometer Berkeley Nucleonics Corporation 29 Kerner Boulevard San Rafael, CA 94901 http://www.berkeleynucleonics.com/ Matrix: Water, Air, Soil/Sediment, Wipe Analvtes: Am-241, Cs-137, Co-60, Eu-154, 1-125, 1-131, lr-192, Mo-99, Ra-226, Ru- 103, U-235, U-238 Other: Detection of these analytes requires use by an experienced operator Operated primarily in Dose Rate (default mode). In any of its modes, an alarm (sample acquisition) can be stored, reviewed and qualitatively analyzed in a multi- channel analyzer. Each stored alarm can be printed or downloaded. Four different modes of operation: - Dose rate, the default mode - Sigma - Spectra Manual Functions include nuclide identification, spectrum analysis, dose rate (rem/Sv) calculation, total dose display, source finding Energy range is 1 8 KeV - 3 MeV Basic SAM 940 unit consists of: - Spectrometer electronics (controller) -A rechargeable battery pack (installed in the left side of the instrument) Operates at temperature range of -20 to 50ฐC; automatic stabilization Internal gamma detector (if present) is a 2" x 2" Nal detector; models with 6 Lil (SAM Defender GN) or LaBr (SAM Resolver) detectors available Optional, detachable detectors: - 2" x 2" or 3" x 3" Nal, with or without neutron detector - LaBr detector Analyte(s) y Americium-241 Cesium-137 Cobalt-60 Europium-154 lodine-125 lodine-131 CASRN NA 14596-10-2 10045-97-3 10198-40-0 15585-10-1 8052-26-4 10043-66-0 Media Water Air Soil /Sediment Wipe Water Air Soil / Sediment Wipe Water Air Soil /Sediment Wipe Water Air Soil /Sediment Wipe Water Air Soil /Sediment Wipe Water Air Soil /Sediment Wipe Water Air Soil /Sediment Wipe Radiochemistry Field Screening Equipment 1b - 5 September 2010 ------- Equipment Berkeley Nucleonics SAM 940 Gamma Spectrometer (cont.) Analyte(s) lridium-192 Molybdenum-99 Radium-226 Ruthenium-103 Ruthenium-106 Selenium-75 Uranium-235 Uranium-238 CASRN 14694-69-0 14119-15-4 13982-63-3 13968-53-1 13967-48-1 14265-71-5 15117-96-1 7440-61-1 Media Water Air Soil /Sediment Wipe Water Air Soil /Sediment Wipe Water Air Wipe Soil / Sediment Water Air Wipe Soil / Sediment Water Air Wipe Soil / Sediment Water Air Wipe Soil / Sediment Water Air Wipe Soil / Sediment Water Air Wipe Soil / Sediment Radiochemistry Field Screening Equipment 1b - 6 September 2010 ------- Equipment Ludlum Model 239-1 F Floor Monitor with 2350-1 Data Logger, 43-37-582 Gas Proportional Detector Coupled to Ludlum 2380-1 Data Logger Ludlum Measurements, Inc. 501 Oak Street Sweetwater, TX 79556 http://www.ludlums.com/ Matrix: Floor contamination monitor (possible adaptation for smooth, flat soil/sediment surfaces) Analytes: Alpha, beta, and gamma emitters Ludlum Model 239-1 F Floor Monitor with 2350-1 Data Logger, 43-37-582 Gas Proportional Detector Coupled to Ludlum 2380-1 Data Logger (cont.) Other: Floor monitor detects alpha, beta, and gamma Detector is gas proportional Recommended counting gas is P-10 (10% methane, 90% argon) Gas consumption is typically 50 cc/min; for gas recharge, will operate on static charge for 2 hours Typically used with Matheson size 2 or Linde Q bottle size Window is 0.8 mg/cm2 aluminized mylar (window thicknesses of 0.4, 3.9, or 7.9 mg/cm2 are available) Active area is 584 cm2 Open area is 425 cm2 Efficiency (4pi) is 17% Pu-239; 25% Sr-90/Y-90; <1% gamma Flow meter is adjustable from 0 to 100 cc/min Detector operating voltage is typically: - 1000 - 1200 volts for alpha - 1600 - 1800 volts for beta and gamma Threshold is typically 2 - 4 mV Gamma Tracer and Base Station Saphymo GmbH (formerly Genitron Instruments) Heerstrasse 149 D-60488 Frankfurt a. M., Germany http://www.genitron.de/ Matrix: Air Analvtes: NA Other: Detector is a 2X Geiger-Muller-tube at center of casing, parallel to longitudinal axis Sensitivity is 2 x 150 impulses in 10 minutes at 100 nSv/h Measuring range is 10 nSv/h - 10 mSv/h (measures dose rate) 1-sigma-error is ฑ 3% (at 100 nSv/h with 60-min measuring cycle Calibration error is ฑ 6% calibrated with Cs-137 Calibration radiation is 662 KeV (Cs-137) Analyte(s) a, p, and Y a, p, and Y y CASRN NA NA NA Media Floor contamination monitor (possible adaptation for smooth, flat soil/sediment surfaces) Floor contamination monitor (possible adaptation for smooth, flat soil/sediment surfaces) Air Radiochemistry Field Screening Equipment 1b - 7 September 2010 ------- Radiochemistry Field Screening Equipment 1 b - 8 September 2010 ------- Table 2a: SAM Chemistry Analytes - Detection using Field Screening Equipment Equipment detection levels, ranges, and units are cited as provided by the manufacturer and/or reference cited. Analytes listed as "not a concern" reflect their listing in Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events (SAM). Analyte(s) Acephate Acrylamide Acrylonitrile Aldicarb (Temik) Aldicarb sulfone Aldicarb sulfoxide Allyl alcohol 4-Aminopyridine Ammonia CASRN 30560-19-1 79-06-1 107-13-1 116-06-3 1646-88-4 1646-87-3 107-18-6 504-24-5 7664-41-7 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - - - - - - - Draeger MultiWarn II Draeger Polytron 7000 series - - - - - - - - - - - Draeger Polytron 7000 series TVA1000B - - Comments Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeaer MultiWarn II: 0 - 200 ppm Draeqer Polvtron 7000 series: 20-100 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeaer Polvtron 7000 series: 20 - 200 ppm TVA1000B: 10ppmPID&FID Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - AP4C Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series HazCat Chemical Identification System MDA Scientific SPM MultiRAE Plus TVA1000B Collect sample for laboratory analysis Collect sample for laboratory analysis AP4C: Not available Draeqer Civil Defense Kit: 1740 - 6.97 x 104 uq/m3 (2.5 - 100 ppm); 3480 - 4.88 x 105 ug/m3 Draeqer MultiWarn: 0-2.09x 105 uq/m3 Draeqer MultiWarn II: 0 - 300 ppm Draeqer Polvtron 7000 series: 50 - 1000 ppm HazCat Chemical Identification System: Not available MDA Scientific SPM: 2.6 - 75 ppm MultiRAE Plus: 1 -50 ppm TVA1000B: 10 ppm PID only Not a concern SAM Chemistry Analytes Table 2a -1 September 2010 ------- Analyte(s) Ammonium metavanadate (analyze for total vanadium) Arsenic, total Arsenic trioxide (analyze for total arsenic) Arsine Asbestos Boron trifluoride Brodifacoum Bromadiolone BZ (Quinuclidinyl benzilate) Calcium arsenate (analyze as total arsenic) Carbofuran (Furadan) Carfentanil CASRN 7803-55-6 7440-38-2 1327-53-3 7784-42-1 1332-21-4 7637-07-2 56073-10-0 28772-56-7 6581-06-2 7778-44-1 1563-66-2 59708-52-0 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - - - - - - - - - - AP4C Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series MDA Scientific SPM MultiRAE Plus - Comments Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis AP4C: <1 ma/m3(0.3 ppm) Draeaer Civil Defense Kit: 0.1 ppm Draeaer MultiWarn: 0 - 3. 1 9 x 1 04 ua/m3 Draeqer MultiWarn II: 0-10 ppm Draeqer Polvtron 7000 series: 0.3 - 20 ppm MDA Scientific SPM: 50-150 ppb MultiRAE Plus: 0.2 - 2000 ppm Collect sample for laboratory analysis Not a concern MIE DataRam - Particulate detection range 0.001 - 400 mg/m3; particle size range 0.1 - 10 urn; flow rate 1-10 L/min Collect sample for laboratory analysis Not a concern Draeger Polytron 7000 series |3 - 20 ppm Not a concern [Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - AP4C - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis AP4C: Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a - 2 September 2010 ------- Analyte(s) Carbon disulfide Chlorfenvinphos Chlorine 2-Chloroethanol 3-Chloro-1 ,2-propanediol Chloropicrin Chlorosarin Chlorosoman 2-Chlorovinylarsonous acid (CVAA) (degradation product of lewisite) Chlorpyrifos Chlorpyrifos oxon Crimidine CASRN 75-15-0 470-90-6 7782-50-5 107-07-3 96-24-2 76-06-2 1445-76-7 7040-57-5 85090-33-1 2921-88-2 5598-15-2 535-89-7 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - AP4C MultiRAE Plus TVA1000B - - - - - Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series MDA Scientific SPM MultiRAE Plus Not a concern - Draeger Polytron 7000 series - - - - - Draeger Civil Defense Kit - - - - - - - - - - - - - - - - - Comments Collect sample for laboratory analysis AP4C: Not available MultiRAE Plus: 0.1 - 2000 ppm TVA1000B: 10 ppm PID only Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeaer Civil Defense Kit: 58.0 - 8.70 x 104 ua/m3 Draeaer MultiWarn: 0 - 5.80 x 104 ua/m3 Draeaer MultiWarn II: 0-20 ppm Draeaer Polvtron 7000 series: 1 - 50 ppm MDA Scientific SPM: 0.05 - 1.5 ppm MultiRAE Plus: 0.1-50 ppm: 0-10 ppm Collect sample for laboratory analysis 30- 100 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis 6720-1. 34 x104ug/m3(1 -2 ppm) Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a - 3 September 2010 ------- Analyte(s) Cyanide, Amenable to chlorination Cyanide, Total Cyanogen chloride Cyclohexyl sarin (GF) 1,2-Dichloroethane (degradation product of HD) Dichlorvos Dicrotophos Diesel Range Organics Diisopropyl methylphosphonate (DIMP) (degradation product of GB) Dimethylphosphite Dimethylphosphoramidic acid (degradation product of GA) CASRN NA 57-12-5 506-77-4 329-99-7 107-06-2 62-73-7 141-66-2 NA 1445-75-6 868-85-9 33876-51-6 Media Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - Comments Collect sample for laboratory analysis Not a concern - - - - M256A1 Kit AP4C Draeger Civil Defense Kit M256A1 Kit - - AP2C AP4C Draeger Civil Defense Kit MultiRAE Plus M8 Paper M9 Paper - - Draeger Polytron 7000 series - - Draeger Civil Defense Kit - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis 3000 ug/m3 in 25 min; 7870 ug/m3 (3.13 ppm) AP4C: <1 ma/m3 (0.4 ppm) Draeaer Civil Defense Kit: 0.25 ppm M256A1: 3000 ua/m3 in 25 min: 7870 ua/m3 (3.13 ppm) Collect sample for laboratory analysis Collect sample for laboratory analysis AP2C: 100 ua/m3 in 2 seconds AP4C: Not available Draeaer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) MultiRAE Plus: 2 ma/m3 (0.3 ppm) M8: Not available M9: Not available Collect sample for laboratory analysis Collect sample for laboratory analysis 30 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - - - - - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a - 4 September 2010 ------- Analyte(s) Diphacinone Disulfoton Disulfoton sulfoxide 1,4-Dithiane (degradation product of HD) EA2192 [Diisopropylaminoethyl methylthiolophosphonate] (hydrolysis product of VX) Ethyl methylphosphonic acid (EMPA) (degradation product of VX) Ethyldichloroarsine (ED) N-Ethyldiethanolamine (EDEA) (degradation product of HN-1) Ethylene oxide Fenamiphos Fentanyl Fluoride Fluoroacetamide CASRN 82-66-6 298-04-4 2497-07-6 505-29-3 73207-98-4 1832-53-7 598-14-1 139-87-7 75-21-8 22224-92-6 437-38-7 16984-48-8 640-19-7 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - Comments Collect sample for laboratory analysis Not a concern - - - - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - - - - - - - - - - - - - Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series TVA1000B - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeqer MultiWarn: 0 - 3.60 x 105 uq/m3 Draeqer MultiWarn II: 0 - 200 ppm Draeqer Polvtron 7000 series: 20 - 200 ppm TVA1000B: 10ppmPID&FID Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern Not a concern - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a - 5 September 2010 ------- Analyte(s) Fluoroacetic acid and fluoroacetate salts (analyze forfluoroacetate ion) 2-Fluoroethanol Formaldehyde Gasoline Range Organics Hexahydro-1 ,3,5-trinitro-1 ,3,5-triazine (RDX) Hexamethylenetriperoxidediamine (HMTD) Hydrogen bromide Hydrogen chloride Hydrogen cyanide CASRN NA 371-62-0 50-00-0 NA 121-82-4 283-66-9 10035-10-6 7647-01-0 74-90-8 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - - - - - - - Draeger MultiWarn Draeger MultiWarn II TVA1000B - - Comments Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeqer MultiWarn: 0 - 2.46 x 1 05 ua/m3 Draeaer MultiWarn II: 0 - 200 ppm TVA1000B: 10ppmPID&FID Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - Collect sample for laboratory analysis Not a concern Draeger Polytron 7000 series MDA Scientific SPM Draeaer Polvtron 7000 series: 3-100 ppm MDA Scientific SPM: 0.3 - 9.0 ppm Not a concern Not a concern Draeger Polytron 7000 series MDA Scientific SPM Draeaer Polvtron 7000 series: 3-100 ppm MDA Scientific SPM: 0.5-15 ppm Not a concern Not a concern AP4C Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series HazCat Chemical Identification System M256A1 Kit MDA Scientific SPM MultiRAE Plus AP4C: <18.7ma/m3(17ppm) Draeaer Civil Defense Kit: 1 ppm Draeaer MultiWarn: 0 - 5.53 x 104 ua/m3 Draeaer MultiWarn II: 0-50 ppm Draeaer Polvtron 7000 series: 10-50 ppm HazCat Chemical Identification System: Not available M256A1 Kit: 1100 ua/m3: 7880 ua/m3 (7.13 ppm): prone to false-positive results; has not been demonstrated to produce false-negative results in real situations MDA Scientific SPM: 1.1 -30 ppm MultiRAE Plus: 1.1 - 110 ma/m3 (0- 100 ppm) Not a concern SAM Chemistry Analytes Table 2a - 6 September 2010 ------- Analyte(s) Hydrogen fluoride Hydrogen sulfide Isopropyl methylphosphonic acid (IMPA) (degradation product of GB) Kerosene Lewisite 1 (L-1) [2-chlorovinyldichloroarsine] (analyze for total arsenic) CASRN 7664-39-3 7783-06-4 1832-54-8 64742-81-0 541-25-3 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Equipment Not a concern Draeger Polytron 7000 series MDA Scientific SPM Comments Draeqer Polvtron 7000 series: 3-30 ppm MDA Scientific SPM: 0.6 - 9.0 ppm Not a concern Not a concern AP4C Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series MDA Scientific SPM MultiRAE Plus Not a concern - - - - AP4C: <57.4 ma/m3 (41 ppm) Draeaer Civil Defense Kit: 878 - 8.36 x 104 ua/m3 (0.63 - 60 ppm); 6970 - 8.36 x 1 05 ug/m3 (5 - 600 ppm) Draeqer MultiWarn: 0- 1.39x 105 uq/m3 Draeqer MultiWarn II: 0 - 1000 ppm Draeqer Polvtron 7000 series: 10 - 1000 ppm MDA Scientific SPM: 1.1 -30 ppm MultiRAE Plus: 1 -100 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - HazCat Chemical Identification System M256A1 Kit APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit MultiRAE Plus M8 Paper M9 Paper HazCat Chemical Identification System M256A1 Kit MultiRAE Plus Collect sample for laboratory analysis HazCat Chemical Identification System: Not available M256A1 Kit: 2000 uq/m3; 8480 uq/m3 (1 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations APD2000ฎ: 200 ppb Draeqer Civil Defense Kit: 3 mq/m3 HazCat Chemical Identification System: Not available M256A1 Kit: 2000 uq/m3; 8480 uq/m3 (1 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.7 mq/m3 (0.2 ppm) M8: Not available M9: Not available HazCat Chemical Identification System: Not available M256A1 Kit: Prone to false-positive results, but has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.7 mq/m3 (0.2 ppm) SAM Chemistry Analytes Table 2a - 7 September 2010 ------- Analyte(s) Lewisite 2 (L-2) [bis(2-chlorovinyl)-chloroarsine] (analyze for total arsenic) Lewisite 3 (L-3) [tris(2-chlorovinyl)-arsine] (analyze for total arsenic) Lewisite oxide (degradation product of Lewisite) Mercuric chloride (analyze for total mercury) CASRN 40334-69-8 40334-70-1 1306-02-1 7487-94-7 Media Water Air Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Water Air Solid Equipment HazCat Chemical Identification System M256A1 Kit APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit MultiRAE Plus M8 Paper M9 Paper - HazCat Chemical Identification System M256A1 Kit APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit MultiRAE Plus M8 Paper M9 Paper HazCat Chemical Identification System - - M8 Paper M9 Paper - RA-915+MVA Comments HazCat Chemical Identification System: Not available M256A1 Kit: Prone to false-positive results, but has not been demonstrated to produce false-negative results in real situations APD2000ฎ: 200 ppb Draeaer Civil Defense Kit: 3 ma/m3 HazCat Chemical Identification System: Not available M256A1 Kit: Prone to false-positive results: has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.7 ma/m3 (0.2 ppm) M8: Not available M9: Not available Collect sample for laboratory analysis HazCat Chemical Identification System: Not available M256A1 Kit: Prone to false-positive results, but has not been demonstrated to produce false-negative results in real situations APD2000ฎ: 200 ppb Draeqer Civil Defense Kit: 3 mq/m3 HazCat Chemical Identification System: Not available M256A1 Kit: Prone to false-positive results, but has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.7 mq/m3 (0.2 ppm) M8: Not available M9: Not available Not available Collect sample for laboratory analysis Collect sample for laboratory analysis M8: Not available M9: Not available Collect sample for laboratory analysis Not available Not a concern RA-915+MVA Not available SAM Chemistry Analytes Table 2a - 8 September 2010 ------- Analyte(s) Mercury, total Methamidophos Methomyl Methoxyethylmercuric acetate (analyze for total mercury) Methyl acrylonitrile Methyl fluoroacetate (analyze forfluoroacetate ion) Methyl hydrazine Methyl isocyanate Methyl paraoxon Methyl parathion Methylamine N-Methyldiethanolamine (MDEA) (degradation product of HN-2) CASRN 7439-97-6 10265-92-6 16752-77-5 151-38-2 126-98-7 453-18-9 60-34-4 624-83-9 950-35-6 298-00-0 74-89-5 105-59-9 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment RA-915+ MVA Jeromeฎ 41 1/431 MVA RA-915+MVA RA-915+MVA - - - - - - RA-915+MVA Jeromeฎ 41 1/431 MVA RA-915+MVA RA-915+MVA - - - - - - - Draeger Polytron 7000 series - Comments 0.5 ng/m3; relative accuracy 50.2 - 58.2% Jeromeฎ 41 1/431 MVA: Detection ranae of 1.00- 999 ug/m3 RA-915+ MVA: 2.0 nq/m3; relative accuracy 50.2 - 58.2% 0.5 ng/m3; relative accuracy 50.2 - 58.2% Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not available Jeromeฎ 41 1/431 MVA: Not available RA-915+ MVA: Not available Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis 1-3 ppm Collect sample for laboratory analysis Not a concern - [Collect sample for laboratory analysis Not a concern - - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series Draeaer MultiWarn: 0 - 1 .27 x 1 05 ua/m3 Draeaer MultiWarn II: 0-100 ppm Draeaer Polvtron 7000 series: 100 ppm Not a concern - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a - 9 September 2010 ------- Analyte(s) 1-Methylethyl ester ethylphosphonofluoridic acid (GE) Methylphosphonic acid (MPA) (degradation product of VX, GB, & GD) Mevinphos Monocrotophos Mustard, nitrogen (HN-1) [bis(2- chloroethyl)ethylamine] Mustard, nitrogen (HN-2) [2,2'-dichloro-N-methyl diethylamine N,N-bis(2-chloroethyl)methylamine] CASRN 1 1 89-87-3 993-13-5 7786-34-7 6923-22-4 538-07-8 51-75-2 Media Water Air Non-aqueous Liquid Solid Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Equipment M256A1 Kit AP2C AP4C Draeger Civil Defense Kit M256A1 Kit M8 Paper M9 Paper - - - - - - - - - - HazCat Chemical Identification System Draeger Civil Defense Kit HazCat Chemical Identification System MultiRAE Plus M8 Paper M9 Paper HazCat Chemical Identification System HazCat Chemical Identification System Draeger Civil Defense Kit HazCat Chemical Identification System M8 Paper M9 Paper HazCat Chemical Identification System Comments 5.00 ug/m3 in 15 minutes AP2C: 5-10 ppm AP4C: Not available Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.00 uq/m3in 15 minutes M8: Not available M9: Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis <40 mg Draeqer Civil Defense Kit: 1 mq/m3 HazCat Chemical Identification System: <40 mq MultiRAE Plus: 1.4 mq/m3 (0.2 ppm) M8: Not available M9: Not available <40 mg <40 mg Draeqer Civil Defense Kit: 1 mq/m3 HazCat Chemical Identification System: <40 mq M8: Not available M9: Not available <40 mg SAM Chemistry Analytes Table 2a -10 September 2010 ------- Analyte(s) Mustard, nitrogen (HN-3) [tris(2-chloroethyl) amine] Mustard, sulfur / Mustard gas (HD) Nicotine compounds (analyze as nicotine) Octahydro-1 ,3,5,7-tetranitro-1 ,3,5,7-tetrazocine (HMX) Organophosphate pesticides, NOS CASRN 555-77-1 505-60-2 54-11-5 2691-41-0 NA Media Water Air Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Water Air Solid Water Air Solid Water Air Solid Equipment HazCat Chemical Identification System Draeger Civil Defense Kit HazCat Chemical Identification System M8 Paper M9 Paper HazCat Chemical Identification System HazCat Chemical Identification System M256A1 Kit AP2C AP4C APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit MultiRAE Plus TVA1000B M8 Paper M9 Paper HazCat Chemical Identification System - Comments <40 mg Draeaer Civil Defense Kit: 1 ma/m3 HazCat Chemical Identification System: <40 ma M8: Not available M9: Not available <40 mg HazCat Chemical Identification System: <40 mq M256A1 Kit: 20.0 uq/m3; 2020 uq/m3 (0.31 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations AP2C: 930 uq/m3 (0.142 ppm) in 4- 11 seconds; 6.51 ug/m3 (0.001 ppm) in 2 seconds; sulfur- and phosphorus-containing compounds may act as interferents AP4C: Not available APD2000ฎ: 220 uq/m3 (0.033 ppm) Draeqer Civil Defense Kit: 1 mq/m3 HazCat Chemical Identification System: <40 mq M256A1 Kit: 20.0 uq/m3; 2020 uq/m3 (0.31 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.3 mq/m3 (0.2 ppm) TVA1000B: 1900 uq/m3 (0.29 ppm) M8: Not available M9: Not available <40 mg Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a -11 September 2010 ------- Analyte(s) Osmium tetroxide (analyze for total osmium) Oxamyl Paraquat Paraoxon Parathion Pentaerythritol tetranitrate (PETN) Phencyclidine Phenol Phorate Phorate sulfone Phorate sulfoxide Phosgene Phosphamidon CASRN 20816-12-0 23135-22-0 4685-14-7 311-45-5 56-38-2 78-11-5 77-10-1 108-95-2 298-02-2 2588-04-7 2588-03-6 75-44-5 13171-21-6 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment - - - - - - - Comments Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern Not a concern - - - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - - - - HazCat Chemical Identification System - - - - - - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern Draeger Civil Defense Kit Draeger MultiWarn Draeger Polytron 7000 series Draeqer Civil Defense Kit: 0. 1 00 - 1 .01 x 1 05 uq/m3 Draeqer MultiWarn: 0 - 1 .21 x 1 04 uq/m3 Draeqer Polvtron 7000 series: 0.1 - 1 ppm Not a concern - - - Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a -12 September 2010 ------- Analyte(s) Phosphine Phosphorus trichloride Pinacolyl methyl phosphonic acid (PMPA) (degradation product of GD) Propylene oxide R-33 (VR) [methylphosphonothioic acid, S-[2- (diethylamino)ethyl O-2-methylpropyl ester] Sarin (GB) CASRN 7803-51-2 7719-12-2 616-52-4 75-56-9 159939-87-4 107-44-8 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Equipment Not a concern Draeger Civil Defense Kit Draeger MultiWarn Draeger MultiWarn II Draeger Polytron 7000 series MDA Scientific SPM MultiRAE Plus Comments Draeqer Civil Defense Kit: 13.9 - 1390 uq/m3 Draeqer MultiWarn: 0- 1.39x 104 uq/m3 Draeqer MultiWarn II: 0 - 1000 ppm Draeqer Polvtron 7000 series: 0.3 - 20 ppm MDA Scientific SPM: 32 - 900 ppb MultiRAE Plus: 0.1-5 ppm; 0-50 ppm Not a concern Not a concern AP4C Draeger Polytron 7000 series Not a concern - - - - Draeger MultiWarn II Draeger Polytron 7000 series - M256A1 Kit AP2C AP4C Draeger Civil Defense Kit M256A1 Kit M8 Paper M9 Paper - HazCat Chemical Identification System M256A1 Kit AP2C AP4C APD2000ฎ Draeger Civil Defense Kit AP4C: Not available Draeqer Polvtron 7000 series: 3-30 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Draeqer MultiWarn II: 0 - 200 ppm Draeqer Polvtron 7000 series: 20 - 200 ppm Collect sample for laboratory analysis 5.00 uq/rn3 in 15 minutes AP2C: 5-10 ppm AP4C: Not available Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.00 ug/m3 in 15 minutes M8: Not available M9: Not available Collect sample for laboratory analysis HazCat Chemical Identification System: <0.13 ppm M256A1 Kit: 5.00 uq/m3; 4.58 uq/m3 (0.0008 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations AP2C: 20.0 uq/m3 (0.003 ppm) in 6 - 73 seconds; 11.5 ug/m3 (0.002 ppm) in 2 seconds; 100 ug/m3 in 2 seconds; sulfur- and phosphorus-containing compounds may act as interferents AP4C: Not available APD2000ฎ: 21.0 uq/m3 (0.004 ppm) Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) SAM Chemistry Analytes Table 2a -13 September 2010 ------- Analyte(s) Sarin (GB) (cont.) Semivolatile Organic Compounds, NOS Sodium arsenite (analyze for total arsenic) Sodium azide (analyze as azide ion) Soman (GD) Strychnine CASRN 107-44-8 NA 7784-46-5 26628-22-8 96-64-0 57-24-9 Media Air Non-aqueous Liquid Solid Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Solid Equipment HazCat Chemical Identification System M256A1 Kit MultiRAE Plus TVA1000B M8 Paper M9 Paper HazCat Chemical Identification System - - - - - - - - - M256A1 Kit AP2C AP4C APD2000ฎ Draeger Civil Defense Kit M256A1 Kit MultiRAE Plus M8 Paper M9 Paper - - Comments HazCat Chemical Identification System: <0.13 ppm M256A1 Kit: 5.00 uq/m3; 4.58 uq/m3 (0.0008 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 1.7 mq/m3 (0.3 ppm) TVA1000B: 26 mg/m3 (4.46 ppm) M8: Not available M9: Not available <0.13 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis 5.00 ug/m3; 14.9 ug/m3 (0.002 ppm); prone to false- positive results; has not been demonstrated to produce false-negative results in real situations AP2C: 7.45 - 100 uq/m3; sulfur- and phosphorus- containing compounds may act as interferents AP4C: Not available APD2000ฎ: 15ppb Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.00 uq/m3; 14.9 uq/m3 (0.002 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations MultiRAE Plus: 2.2 mq/m3 (0.3 ppm) M8: Not available M9: Not available Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern [Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a -14 September 2010 ------- Analyte(s) Sulfur dioxide Sulfur trioxide Tabun (GA) Tetraethyl pyrophosphate Tetramethylenedisulfotetramine Thallium sulfate (analyze for total thallium) Thiodiglycol (TDG) (degradation product of HD) CASRN 7446-09-5 7446-11-g 77-81-6 107-49-3 80-12-6 7446-18-6 111-48-8 Media Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Equipment Not a concern AP4C Draeger Civil Defense Kit Draeger MultiWarn II Draeger Polytron 7000 series MultiRAE Plus Comments AP4C: Not available Draeqer Civil Defense Kit: 1310 - 6.55 x 104 uq/m3 (0.5-25 ppm) Draeqer MultiWarn II: 0-50 ppm Draeqer Polvtron 7000 series: 5-100 ppm MultiRAE Plus: 0.1 -20 ppm; 0- 100 ppm; 0-20 ppm Not a concern Not a concern Draeger Polytron 7000 series |30 ppm Not a concern HazCat Chemical Identification System M256A1 Kit AP2C AP4C APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit MultiRAE Plus TVA1000B M8 Paper M9 Paper HazCat Chemical Identification System - - - - - - - - - - - - HazCat Chemical Identification System: <0.5 ppm M256A1 Kit: 5.0 uq/m3 in 15 minutes AP2C: 13.3 - 100 uq/m3; sulfur- and phosphorus- containing compounds may act as interferents AP4C: Not available APD2000ฎ: 27.0 uq/m3 (0.004 ppm) Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) HazCat Chemical Identification System: <0.5 ppm M256A1 Kit: 5.0 uq/m3 in 15 minutes MultiRAE Plus: 0.7 mq/m3 (0.1 ppm) TVA1000B: 4.10 mg/m3 (0.61 ppm) M8: Not available M9: Not available <0.5 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a -15 September 2010 ------- Analyte(s) Thiofanox 1 ,4-Thioxane (degradation product of HD) Titanium tetrachloride (analyze for total titanium) Triethanolamine (TEA) (degradation product of HN-3) Trimethyl phosphite 1 ,3,5-Trinitrobenzene (1,3,5-TNB) 2,4,6-Trinitrotoluene (2,4,6-TNT) Vanadium pentoxide (analyze for total vanadium) VE [phosphonothioic acid, ethyl-, S-(2- (diethylamino)ethyl) O-ethyl ester] VG [phosphonothioic acid, S-(2- (diethylamino)ethyl) O,O-diethyl ester] CASRN 39196-18-4 15980-15-1 7550-45-0 102-71-6 121-45-9 99-35-4 118-96-7 1314-62-1 21738-25-0 78-53-5 Media Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Solid Water Air Non-aqueous Liquid Solid Water Air Equipment - - - - Comments Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - Collect sample for laboratory analysis Not a concern Not a concern - - Draeger Polytron 7000 series - - - - - Collect sample for laboratory analysis Collect sample for laboratory analysis 100 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - Collect sample for laboratory analysis Collect sample for laboratory analysis Not a concern - - - - M256A1 Kit AP2C AP4C Draeger Civil Defense Kit M256A1 Kit M8 Paper M9 Paper - M256A1 Kit AP2C AP4C Draeger Civil Defense Kit M256A1 Kit Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis 5.0 ug/m in 15 minutes AP2C: Nerve qases (G-aqents/V-aqents) 10-5 ppm AP4C: Not available Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.0 uq/m3 in 15 minutes M8: Not available M9: Not available Collect sample for laboratory analysis 5.0 ug/m in 15 minutes AP2C: Nerve qases (G-aqents/V-aqents) 10-5 ppm AP4C: Not available Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.0 uq/m3 in 15 minutes SAM Chemistry Analytes Table 2a -16 September 2010 ------- Analyte(s) VG [phosphonothioic acid, S-(2 (diethylamino)ethyl) O,O-diethyl ester] (cont.) VM [phosphonothioic acid, methyl-, S-(2-(diethylamino)ethyl) O-ethyl ester] VX [O-ethyl-S-(2-diisopropylaminoethyl) methyl phosphonothiolate] White phosphorus CASRN 78-53-5 21770-86-5 50782-69-9 12185-10-3 Media Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Water Air Non-aqueous Liquid Solid Water Air Solid Equipment M8 Paper M9 Paper - M256A1 Kit AP2C AP4C Draeger Civil Defense Kit M256A1 Kit M8 Paper M9 Paper - HazCat Chemical Identification System M256A1 Kit AP2C AP4C APD2000ฎ Draeger Civil Defense Kit HazCat Chemical Identification System M256A1 Kit M8 Paper M9 Paper HazCat Chemical Identification System - - - Comments M8: Not available M9: Not available Collect sample for laboratory analysis 5.0 ug/m in 15 minutes AP2C: Nerve qases (G-aqents/V-aqents) 10-5 ppm AP4C: Not available Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) M256A1 Kit: 5.0 uq/m3 in 15 minutes M8: Not available M9: Not available Collect sample for laboratory analysis HazCat Chemical Identification System: 0.25 ppm M256A1 Kit: 5.00 uq/m3; 21.9 uq/m3 (0.002 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations AP2C: 656 uq/m3 (0.06 ppm) in 2 seconds; 150 ug/m3 in 2 seconds; sulfur- and phosphorus- containing compounds may act as interferents AP4C: Not available APD2000ฎ: 4 ppb Draeqer Civil Defense Kit: 0.025 ppm (G and V- agents as dichlorovos); 0.05 ppm (G- and V-agents as phosphoric acid esters) HazCat Chemical Identification System: 0.25 ppm M256A1 Kit: 5.00 uq/m3; 21.9 uq/m3 (0.002 ppm); prone to false-positive results; has not been demonstrated to produce false-negative results in real situations M8: Not available M9: Not available 0.25 ppm Collect sample for laboratory analysis Collect sample for laboratory analysis Collect sample for laboratory analysis SAM Chemistry Analytes Table 2a -17 September 2010 ------- SAM Chemistry Analytes Table 2a -18 September 2010 ------- Table 2b: SAM Radiochemistry Analytes - Detection using Field Screening Equipment The following assumptions/nuclear physics variables should be considered when assessing data from each instrument: It is assumed that standard health physics and radiation protection protocols are used consistently when comparing measurements. For example, all comparative radiation dose measurements are made at the same distance from the source term (at contact, one foot, etc.), all contamination measurements are consistent as to source to detector configuration, and the efficiency of the detector is well known to perform comparative readings from one detector system to another. It is assumed, for gamma spectroscopy measurements for comparative results, that the source configuration characteristics are well known to take into consideration the Z (density value of composite composition) of matrix, the Z of the container, expected homogeneity of the radioisotope in the sample matrix, and sample volume for self-absorption and gamma attenuation coefficients. For example, Am-241 measurements at the surface of an open steel container will give higher values because there is no steel to attenuate the low energy gamma vs. measuring the same container from the side through the steel. Minimum Detectable Activities, count rates, and/or dose rates are well established for each instrument prior to field utilization and re-evaluated to ambient backgrounds, in the field, to assess the instrument's capability to produce acceptable and usable data. If field measurements cannot determine presence/absence of a contaminant and samples have to be taken for laboratory analysis, ensure sample size is of sufficient quantity to enable the laboratory to meet presence/absence criteria (contact laboratory for sample size requirements prior to sampling). Analyte(s) Gross Alpha NOTE: All alpha particles present are measured without isotopic identification. Gross Beta NOTE: All beta-gamma particles present are measured without isotopic identification. Decay Products / Radiations a P CASRN NA NA Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment NOTE: Water samples cannot be directly read for gross alpha; samples may be dried and analyzed using the Ludlum Model 3030 Alpha/Beta Counter. Ludlum Model 3030 Alpha/Beta Counter with RADeCo Model H810AC Ludlum Model 15 Survey Meter Ludlum Model 2241-3 Survey Meter Ludlum Model 3030 Alpha/Beta Counter Ludlum Model 15 Survey Meter Ludlum Model 2241-3 Survey Meter Ludlum Model 2241-3 with Model 44-9 or 43-90 probe Ludlum Model 3030 Alpha/Beta Counter Ludlum Model 15 Survey Meter NOTE: These detectors should not be immersed. Measurements should be taken at the water surface. Ludlum Model 2241-3 Survey Meter with Model 44-9 probe Ludlum Model 15 Survey Meter Ludlum Model 3030 Alpha/Beta Counter Ludlum Model 3030 Alpha/Beta Counter with RADeCo Model H810AC Ludlum Model 15 Survey Meter Ludlum Model 2241-3 Survey Meter Ludlum Model 3030 Alpha/Beta Counter Ludlum Model 15 Survey Meter Ludlum Model 2241-3 Survey Meter Ludlum Model 2241-3 w/ Model 44-9 probe Ludlum Model 15 Survey Meter Ludlum Model 3030 Alpha/Beta Counter SAM Radiochemistry Analytes Table 2b -1 September 2010 ------- Analyte(s) Gamma NOTE: Except for the Berkeley Nucleonics SAM 940, which can identify specific isotopes, all equipment listed will detect gamma photons from all gamma emitter isotopes present without isotopic identification. Americium-241 Californium-252 Decay Products / Radiations Y a,y a,y CASRN NA 14596-10-2 13981-17-4 Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment NOTE: These detectors should not be immersed. Measurements should be taken at the water surface. Ludlum Model 192 MicroR Radiation Meter Ludlum Model 2241-3 w/ Model 44-9 or 44-2 probe Ludlum Model 15 Survey Meter Thermo-Eberline RO-20E Ion Chamber Berkeley Nucleonics SAM 940 Ludlum Model 192 MicroR Radiation Meter Ludlum Model 2241-3 w/ Model 44-9 or 44-2 probe Ludlum Model 15 Survey Meter Thermo-Eberline RO-20E Ion Chamber Berkeley Nucleonics SAM 940 Gamma Tracer and Base Station Berkeley Nucleonics SAM 940 Ludlum Model 192 MicroR Radiation Meter Ludlum Model 2241-3 Survey Meter Thermo-Eberline RO-20E Ion Chamber Ludlum Model 192 MicroR Radiation Meter Ludlum Model 2241-3 w/ Model 44-9 or 44-2 probe Ludlum Model 15 Survey Meter Thermo-Eberline RO-20E Ion Chamber Berkeley Nucleonics SAM 940 Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. SAM Radiochemistry Analytes Table 2b - 2 September 2010 ------- Analyte(s) Cesium-137 Cobalt-60 Curium-244 Europium-154 lodine-125 lodine-131 Decay Products / Radiations P,Y P,Y a,Y P,Y Y P,Y CASRN 10045-97-3 10198-40-0 13981-15-2 15585-10-1 8052-26-4 10043-66-0 Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy SAM Radiochemistry Analytes Table 2b - 3 September 2010 ------- Analyte(s) lridium-192 Molybdenum-99 Plutonium-238 Plutonium-239 Decay Products / Radiations P,Y Y a,y a,y CASRN 14694-69-0 14119-15-4 13981-16-3 15117-48-3 Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma Spectroscopy. Collect sample for laboratory analysis. SAM Radiochemistry Analytes Table 2b - 4 September 2010 ------- Analyte(s) Polonium-210 Radium-226 Ruthenium-103 Ruthenium-106 Selenium-75 Decay Products / Radiations a,Y a,Y P,Y P,Y Y CASRN 13981-52-7 13982-63-3 13968-53-1 13967-48-1 14265-71-5 Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy U-235 is an interferent. Field equipment screening will likely require a long counting time to address low gamma yield fraction. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy U-235 is an interferent. Field equipment screening will likely require a long counting time to address low gamma yield fraction. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy U-235 is an interferent. Field equipment screening will likely require a long counting time to address low gamma yield fraction. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy U-235 is an interferent. Field equipment screening will likely require a long counting time to address low gamma yield fraction. Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy Berkeley Nucleonics SAM 940 - Gamma Spectroscopy SAM Radiochemistry Analytes Table 2b - 5 September 2010 ------- Analyte(s) Strontium-90 Technetium-99 Tritium (Hydrogen-3) Uranium-234 Decay Products / Radiations P P P a CASRN 10098-97-2 14133-76-7 10028-17-8 13966-29-5 Media Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Water Air Filters Wipe Soil /Sediment Equipment Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Not Applicable Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. Field equipment is not available to determine presence/absence of this isotope. Collect sample for laboratory analysis. SAM Radiochemistry Analytes Table 2b - 6 September 2010 ------- Analyte(s) Decay Products / Radiations CASRN Media Equipment Uranium-235 15117-96-1 Water Berkeley Nucleonics SAM 940 - Gamma Spectroscopy may be used to determine presence/absence of this isotope at 185.7 keV. However, if Ra-226 is also supected to be present at 186.2 keV in the gamma spectrum, then collect sample for laboratory analysis by alpha spectroscopy. Air Filters Berkeley Nucleonics SAM 940 - Gamma Spectroscopy may be used to determine presence/absence of this isotope at 185.7 keV. However, if Ra-226 is also supected to be present at 186.2 keV in the gamma spectrum, then collect sample for laboratory analysis by alpha spectroscopy. Wipe Berkeley Nucleonics SAM 940 - Gamma Spectroscopy may be used to determine presence/absence of this isotope at 185.7 keV. However, if Ra-226 is also supected to be present at 186.2 keV in the gamma spectrum, then collect sample for laboratory analysis by alpha spectroscopy. Soil /Sediment Berkeley Nucleonics SAM 940 - Gamma Spectroscopy may be used to determine presence/absence of this isotope at 185.7 keV. However, if Ra-226 is also supected to be present at 186.2 keV in the gamma spectrum, then collect sample for laboratory analysis by alpha spectroscopy. Uranium-238 7440-61-1 Water Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. However, U-238 progeny (Pa-234m) may be used as a surrogate if it is assumed to be in secular equilibrium with U-238. In this case, Berkeley Nucleonics SAM 940 should be used. Air Filters Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. However, U-238 progeny (Pa-234m) may be used as a surrogate if it is assumed to be in secular equilibrium with U-238. In this case, Berkeley Nucleonics SAM 940 should be used. Wipe Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. However, U-238 progeny (Pa-234m) may be used as a surrogate if it is assumed to be in secular equilibrium with U-238. In this case, Berkeley Nucleonics SAM 940 should be used. Soil /Sediment Field equipment is not available to determine presence/absence of this isotope due to low gamma yield fraction for gamma spectroscopy. Collect sample for laboratory analysis. However, U-238 progeny (Pa-234m) may be used as a surrogate if it is assumed to be in secular equilibrium with U-238. In this case, Berkeley Nucleonics SAM 940 should be used. SAM Radiochemistry Analytes Table 2b - 7 September 2010 ------- United States Environmental Protection Agency PRESORTED STANDARD POSTAGE & FEES PAID EPA PERMIT NO. 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