Analytical Methods Recommended for Drinking Water Monitoring of Secondary Contaminants Analysis for the following contaminants may be conducted in accordance with the methods in the following table, or their equivalent as determined by EPA. Methods for copper, fluoride, and pH are listed in 40 CFR 141.23 and methods for the remaining contaminants are in 40 CFR 143.4. Additional methods are » listed in Appendix A to Subpart C of Part 141. The recommended monitoring for these contaminants is specified in 40 CFR 143.4. The CFR is the legal reference for approved methods and takes precedent over this table. The table should accurately reflect the analytical methods information published in 40 CFR 141.23, 143.4, and Appendix A to Subpart C of Part 141. If you find discrepancies, please notify The Safe Drinking Water Hotline (800-426-4791) so that EPA can correct the table. Contaminant. Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). . . . Aluminum EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination May 1994 of Metals in Environmental Samples Supplement 1 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA 200.8 Rev 5.4 In Methods for the Determination May 1994 of Metals in Environmental Samples Supplement 1 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA Standard Methods Standard Methods 200. 9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/1 1 1 PB95-125472 of Metals in Environmental Samples Supplement 1 3 1 1 1 D Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 1 D Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition http: //www.nemi. go v Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 1 of 28 ------- Contaminant EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Aluminum Standard 3 Methods Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly withoul contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R- 94/173) available through EPA Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). HID Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition Standard 3 1 1 3 B Standard Methods for the 1 992 Methods Examination of Water and Wastewater, 18th Edition Standard 3 1 1 3 B Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 3113B Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 3120 B Standard Methods for the 1992 Methods Examination of Water and Wastewater, 18th Edition Standard 3120 B Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 3120 B Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard 3120B Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 3111D-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval Source of Method digestion, and other recommended procedures are 's digital publications National Environmental Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http: //www. standardmethods. ore/ year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 2 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Aluminum Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Chloride ASTM D4327-03 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D4327-97 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D5 1 2-04 B Annual Book of ASTM Standards, International Vol. 11.01 ASTM D5 12-89 B Annual Book of ASTM Standards, International (Reapproved Vol. 11.01 1999) http://www.astm.org http://www.astm.org http://www.astm.org http://www.astm.org EPA 300.0 Rev 2.1 In Methods for the Determination August 1993 EPA/600/R-93/100 PB94-120821 of Inorganic Substances in Environmental Samples http: //www.nemi. go v EPA 300.1 Rev 1.0 In Methods for the Determination August2000 EPA 815-R-00-014 PB2000-106981 of Organic and Inorganic Compounds in Drinking Water, Volume 1 http://www.epa.gov/safewater/methods/sourcalt.html Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 3 of 28 ------- Contaminant Method Organization Number Reference Title Chloride Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-C1- D Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-C1- D Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition EPA Publication Publication Order Date Number Number 1992 1995 1998 2005 1992 1995 1998 2005 1992 1995 Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 4 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Chloride Standard 4500-C1- D Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-C1- D Standard Methods for the Examination of Water and Wastewater, 2 1 st Edition 2005 Standard Methods Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-C1- B-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-C1- D-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Waters Method Test Method for Determination of Corporation D6508, Dissolved Inorganic Anions in Revision 2 Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 5 of 28 ------- Contaminant EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Color Standard 2120B Standard Methods for the 1992 Methods Examination of Water and Wastewater, 18th Edition Standard 2120 B Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 2120 B Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard 2120 B Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 2120B-01 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval Source of Method Standard Methods Standard Methods Standard Methods Standard Methods http: //www. standardmethods. ore/ year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). ASTM D1688-02A Annual Book of ASTM Standards, International Vol. 11.01 http://www.astm.org ASTM D1688-02C Annual Book of ASTM Standards, International Vol. 11.01 http://www.astm.org ASTM D1688-90A Annual Book of ASTM Standards, International Vol. 11.01 ASTM International (ASTM) ASTM D1688-90C Annual Book of ASTM Standards, International Vol. 11.01 ASTM International (ASTM) Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 6 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). ASTM D1688-95A Annual Book of ASTM Standards, International Vol. 11.01 http://www.astm.org ASTM D1688-95C Annual Book of ASTM Standards, International Vol. 11.01 http://www.astm.org EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA 200.9 Rev 2.2 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v Standard 3111B Methods Standard Methods for the Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard 3111B Methods Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard 3111 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 7 of 28 ------- Contaminant EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Copper Standard 3 Methods Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly withoul contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R- 94/173) available through EPA Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). 1 1 3 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition Standard 3 1 1 3 B Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 3 1 1 3 B Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 3120 B Standard Methods for the 1992 Methods Examination of Water and Wastewater, 18th Edition Standard 3120 B Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 3120 B Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard 3120B Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 3111B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval Source of Method digestion, and other recommended procedures are 's digital publications National Environmental Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http: //www. standardmethods. ore/ year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 8 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Fluoride ASTM D 1 1 79-04 B Annual Book of ASTM Standards, International Vol. 11.01 ASTM Dl 179-93 B Annual Book of ASTM Standards, International Vol. 11.01 ASTM Dl 179-99 B Annual Book of ASTM Standards, International Vol. 11.01 ASTM D4327-03 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D4327-97 Annual Book of ASTM Standards, International Vol. 11.01 Bran + Luebbe 129-71W Fluoride in Water and Wastewater December 1972 Bran + Luebbe 3 80-75 WE Fluoride in Water and Wastewater February 1976 http://www.astm.org ASTM International (ASTM) http://www.astm.org http://www.astm.org http://www.astm.org Bran+Luebbe Bran+Luebbe Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 9 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Fluoride EPA 300.0 Rev 2.1 In Methods for the Determination August 1993 EPA/600/R-93/100 PB94-120821 of Inorganic Substances in Environmental Samples http: //www.nemi. go v EPA 300.1 Rev 1.0 In Methods for the Determination August2000 EPA 815-R-00-014 PB2000-106981 of Organic and Inorganic Compounds in Drinking Water, Volume 1 http://www.epa.gov/safewater/methods/sourcalt.html Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 4 1 1 0 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 41 10 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 41 10 B Standard Methods for the 1998 Examination of Water and Wastewater, 20th Edition 41 10 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 4500-F- B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 4500-F- B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 4500-F- B Standard Methods for the 1998 Examination of Water and Wastewater, 20th Edition 4500-F- B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 10 of 28 ------- Contaminant Method Organization Number Reference Title Fluoride Standard 4500-F- C Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-F- C Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4500-F- C Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4500-F- C Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-F- D Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-F- D Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4500-F- D Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4500-F- D Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-F- E Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-F- E Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition EPA Publication Publication Order Date Number Number 1992 1995 1998 2005 1992 1995 1998 2005 1992 1995 Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 11 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Fluoride Standard 4500-F- E Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-F- E Standard Methods for the Examination of Water and Wastewater, 2 1 st Edition 2005 Standard Methods Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-F- B-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-F- C-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-F- D-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 12 of 28 ------- Contaminant Method Organization Number Fluoride Standard 4500-F- E-97 Methods Online Reference Title Date Online version of Standard Methods for the Examination of Water and Wastewater. Approval EPA Publication Number Publication Order Number Source of Method http: //www. standardmethods. ore/ year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Waters Method Corporation D6508, Revision 2 Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation Foaming Agent Standard 5540 C Methods Standard Methods for the Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard 5540 C Methods Standard Methods for the 1 996 Examination of Water and Wastewater, 19th Edition Supplement Standard Methods Standard 5540 C Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 5540 C Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 5540 C-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 13 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Iron Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/1 1 1 PB95-125472 of Metals in Environmental Samples Supplement 1 3 1 1 1 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 1 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3 1 1 1 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 3 1 1 3 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 3 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3 1 1 3 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition http: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 14 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Iron Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard 3120B Methods Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3113B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 15 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Manganese Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/1 1 1 PB95-125472 of Metals in Environmental Samples Supplement 1 3 1 1 1 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 1 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3 1 1 1 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 3 1 1 3 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 3 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition http: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 16 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Manganese Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard 3120B Methods Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120B Methods Standard Methods for the Examination of Water and Wastewater, 2 1 st Edition 2005 Standard Methods Standard 3111B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3113B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 17 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Manganese Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Odor Standard 2150 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard Methods 2150 B Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard Methods 2150 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 2150 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 2150B-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ fiJL ASTM D1293-8 International Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 18 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method pH ASTM D1293-95 International Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) ASTM D1293-99 International Annual Book of ASTM Standards, Vol. 11.01 http://www.astm.org EPA 150.1 In Methods for Chemical Analysis March 1983 of Water and Wastes EPA/600/4-79/020 PB84-128677 http: //www.nemi. go v EPA 150.2 In Methods for Chemical Analysis March 1983 of Water and Wastes EPA/600/4-79/020 PB84-128677 http: //www.nemi. go v Standard 4500-H+ B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 2 1 st Edition 2005 Standard Methods Standard 4500-H+ B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 19 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Silver Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/1 1 1 PB95-125472 of Metals in Environmental Samples Supplement 1 3 1 1 1 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 1 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3 1 1 1 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 3 1 1 3 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 3 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition http: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 20 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Silver Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard 3120B Methods Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120B Methods Standard Methods for the Examination of Water and Wastewater, 2 1 st Edition 2005 Standard Methods Standard 3111B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 3113B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 21 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Silver Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ U.S. 1-3720-85 In Methods for Determination of 1989 Geological Inorganic Substances in Water and Survey Fluvial Sediments, USGS Series: Techniques of Water-Resource Investigation Report; edited by Fishman, MJ. & Friedman, L.C. Sulfate ASTM D4327-03 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D4327-97 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D516-02 Annual Book of ASTM Standards, International Vol. 11.01 ASTM D516-90 Annual Book of ASTM Standards, International Vol. 11.01 05-A1 http://infotrek.er.usgs.gov/pubs/ http://www.astm.org http://www.astm.org http://www.astm.org ASTM International (ASTM) EPA 300.0 Rev 2.1 In Methods for the Determination August 1993 EPA/600/R-93/100 PB94-120821 of Inorganic Substances in Environmental Samples http://www.nemi.gov EPA 300.1 Rev 1.0 In Methods for the Determination August2000 EPA 815-R-00-014 PB2000-106981 of Organic and Inorganic Compounds in Drinking Water, Volume 1 http://www.epa.gov/safewater/methods/sourcalt.html Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 22 of 28 ------- Contaminant Method Organization Number Reference Title Sulfate EPA 375 .2 Rev 2.0 In Methods for the Determination of Inorganic Substances in Environmental Samples Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4 1 1 0 B Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-SO42- C Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition Standard 4500-SO42- C Standard Methods for the Methods Examination of Water and Wastewater, 19th Edition Standard 4500-SO42- C Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition Standard 4500-SO42- C Standard Methods for the Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-SO42- D Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition EPA Publication Publication Order Date Number Number August 1993 EPA/600/R-93/100 PB94-120821 1992 1995 1998 2005 1992 1995 1998 2005 1992 Source of Method http: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 23 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Publication Order Number Number Source of Method Sulfate Standard 4500-SO42- D Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 4500-SO42- D Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard 4500-SO42- D Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-SO42- E Standard Methods for the 1992 Methods Examination of Water and Wastewater, 18th Edition Standard 4500-SO42- E Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 4500-SO42- E Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard 4500-SO42- E Standard Methods for the 2005 Methods Examination of Water and Wastewater, 2 1 st Edition Standard 4500-SO42- F Standard Methods for the 1992 Methods Examination of Water and Wastewater, 18th Edition Standard 4500-SO42- F Standard Methods for the 1995 Methods Examination of Water and Wastewater, 19th Edition Standard 4500-SO42- F Standard Methods for the 1998 Methods Examination of Water and Wastewater, 20th Edition Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 24 of 28 ------- Contaminant Method Organization Number Reference Sulfate Title Standard 4500-SO42- F Standard Methods for the Methods Examination of Water and EPA Publication Date Number 2005 Publication Order Number Source of Method Standard Methods Wastewater, 21 st Edition Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-SO42- C- Online version of Standard Methods 97 Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-SO42- D- Online version of Standard Methods 97 Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Standard 4500-SO42- E- Online version of Standard Methods 97 Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 25 of 28 ------- Contaminant Method Organization Number Sulfate Standard 4500-SO42- F- Methods 97 Online Reference Title Date Online version of Standard Methods for the Examination of Water and Wastewater. Approval EPA Publication Number Publication Order Number Source of Method http: //www. standardmethods. ore/ year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Waters Method Corporation D6508, Revision 2 Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation TDS Standard 2540 C Standard Methods for the Methods Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online 2540 C Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 2540 C Standard Methods for the 1998 Examination of Water and Wastewater, 20th Edition 2540 C Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 2540 C-97 Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard Methods Standard Methods Standard Methods http: //www. standardmethods. org/ Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 26 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Zinc Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http: //www.nemi. go v EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 8 Rev 5.4 In Methods for the Determination May 1994 EPA/600/R-94/1 1 1 PB95-125472 of Metals in Environmental Samples Supplement 1 3 1 1 1 B Standard Methods for the 1 992 Examination of Water and Wastewater, 18th Edition 3 1 1 1 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3 1 1 1 B Standard Methods for the 2005 Examination of Water and Wastewater, 2 1 st Edition 3120 B Standard Methods for the 1992 Examination of Water and Wastewater, 18th Edition 3120 B Standard Methods for the 1995 Examination of Water and Wastewater, 19th Edition 3120 B Standard Methods for the 1998 Examination of Water and Wastewater, 20th Edition http: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 27 of 28 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Zinc Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. ore/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http: //www. standardmethods. org/ Contact information for methods that are not available on the Internet are summarized in the report titled "Sources of Approved Analytical Methods for National Drinking Water Regulations." Revised June 2008 Recommended Methods for Secondary Drinking Water Contaminants Page 28 of 28 ------- |