EPA-452/F-03-012
                              Air Pollution Control Technology
                                                  Fact Sheet
Name of Technology: Impingement-Plate/Tray-Tower Scrubber

This type of technology is a part of the group of air pollution controls collectively referred to as "wet scrubbers."
When used to control inorganic gases, they may also be referred to as "acid gas scrubbers." When used to
specifically control sulfur dioxide (SO2), the term flue-gas desulfurization (FGD) may also be used.

Type of Technology: Removal of air pollutants by inertial or diffusional impaction, reaction with a sorbent
or reagent slurry, or absorption into liquid solvent.

Applicable Pollutants:

Primarily particulate matter (PM), including particulate matter less than or equal to 10 micrometers (|j,m) in
aerodynamic diameter (PM10), particulate matter less than or equal to 2.5 • m in aerodynamic diameter (PM2 5),
and hazardous air pollutants (HAP) in particulate form (PMHAP); and inorganic fumes, vapors, and gases (e.g.,
chromic acid, hydrogen sulfide, ammonia, chlorides, fluorides, and SO2). These types of scrubbers may also
occasionally be used to control volatile organic compounds (VOC). Hydrophilic VOC may be controlled with
and aqueous fluid, and hydrophobic VOC may be controlled with an amphiphilic block copolymer in the water.
However, since very little data exist forthis application, VOC data are not presented. When using absorption
as the primary  control technique, the spent solvent  must  be easily regenerated or disposed of in an
environmentally acceptable manner (EPA, 1991).

Achievable Emission Limits/Reductions:

PM:  Impingement-plate tower collection efficiencies range from 50 to 99 percent, depending  upon the
application. This type of scrubber relies almost exclusively on inertial impaction for PM collection. Therefore,
collection efficiency decreases as particle size decreases. Short residence times will also lower scrubber
efficiency for small particles.  Collection efficiencies for small particles (< 1 |j,m in aerodynamic diameter) are
low for these scrubbers, hence, they are not recommended for fine PM control (EPA, 1998).

Inorganic Gases:  Control device vendors estimate that removal efficiencies  range from 95 to 99 percent
(EPA, 1993). For SO2 control, removal efficiencies vary from 80 to greater than 99 percent, depending upon
the type of reagent used and the plate towerdesign. Most current applications have an SO2 removal efficiency
greater than 90 percent (Sondreal, 1993; Soud, et al., 1993).

Applicable Source Type: Point

Typical Industrial Applications:

The suitability of gas absorption as a pollution control method is generally dependent on the following factors:
1) availability of suitable solvent; 2) required removal efficiency; 3) pollutant concentration in the inlet vapor;
4) capacity required for handling waste gas; and, 5)  recovery value of the pollutant(s) or the disposal cost of
the unrecoverable solvent (EPA, 1996).

Impingement plate scrubbers are typically used in the food and agriculture industry, and at gray iron foundries
(EPA, 1998).


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FGD is used to control SO2 emissions from coal and oil combustion from electric utilities and industrial
sources. Impingement scrubbers are one wet scrubber configuration used to bring exhaust gases into contact
with a sorbent designed to remove the SO2. On occasion, wet scrubbers have been applied to SO2 emissions
from processes in the primary nonferrous  metals industries (e.g., copper, lead, and aluminum), but sulfuric
acid or elemental sulfur plants are more popular control devices for controlling the high SO2 concentrations
associated with these processes (Soud, et al., 1993).

When absorption is used for VOC control,  packed towers are usually more cost effective than impingement-
plate towers.  However, in certain cases, the impingement-plate design is preferred over packed-tower
columns when either internal cooling is desired, or where low liquid flow  rates would inadequately wet the
packing (EPA, 1992).

Emission Stream Characteristics:

       a.     Air Flow: Typical gas flow rates for a single impingement-plate scrubber unit are 0.47 to 35
              standard cubic meters per second (sm3/sec) (1,000 to 75,000 standard cubic feet per minute
              (scfm))(EPA, 1998).

       b.     Temperature:  Inlet gas temperature is limited to 4 to 370-C  (40 to 700-F) for PM control.
              For gaseous pollutant control, the gas temperature ranges between 4 to 38-C (40 to 100-F).
              In general, the higher the gas temperature, the lower the absorption rate, and vice-versa.
              Highertemperatures can lead to loss of scrubbing liquid orsolvent through evaporation (EPA,
              1996;Avallone, 1996).

       c.     Pollutant Loading:  Impingement-plate scrubbers are easy to clean and maintain and are
              not subject to fouling as packed-bed wet scrubbers are, hence they are more suited to PM
              control and there are no practical limits to inlet PM concentrations (EPA, 1998).

       d.     Other Considerations:  For organic vapor HAP control, low outlet concentrations will
              typically be required, leading to impractically tall absorption towers, long contact times, and
              high liquid-gas ratios that may not be cost-effective. Wet scrubbers will generally be effective
              for HAP control when they are used in combination with other control devices such  as
              incinerators or carbon adsorbers (EPA, 1991).

Emission Stream Pretreatment Requirements:

For gas absorption applications, precoolers (e.g., spray chambers)  may  be needed to reduce the inlet air
temperature to acceptable levels to avoid solvent evaporation or reduced absorption rates (EPA, 1996).

Cost Information:

The  following  are cost  ranges (expressed  in 2002 dollars) for  impingement-plate wet scrubbers of
conventional design under typical operating conditions, developed using EPA cost-estimating spreadsheets
(EPA, 1996) and  referenced  to the volumetric flow rate of the waste stream treated.  For purposes of
calculating  the example cost effectiveness, the pollutant  is assumed to be PM at an inlet loading of
approximately 7 grams per standard cubic meter (g/sm3), or 3 grains per standard cubic foot (gr/scf).  The cost
estimates do not include costs for post-treatment or disposal of used solvent or waste.  Actual costs can be
substantially higher than in the ranges shown for applications which require expensive materials, solvents,
ortreatment methods. As a rule, smaller units controlling a low concentration waste stream will be much more
expensive (per unit volumetric flow rate) than a large unit cleaning a high  pollutant load flow.
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       a.      Capital Cost: $8,500 to $23,000 per sm3/sec ($4 to $11  per scfm)

       b.      O & M Cost: $6,500 to $93,000 per srrrVsec ($3.10 to $44 per scfm), annually

       c.      Annualized Cost: $11,000 to $150,000 per sm3/sec ($5.10 to $71 per scfm), annually

       d.      Cost Effectiveness:  $104 to $1,400 per metric ton ($94 to $1,300 per short ton),
               annualized cost per ton per year of pollutant controlled

Theory of Operation:

PM Control:

An impingement-plate scrubber is a vertical chamber with plates mounted horizontally inside a hollow shell.
Impingement-plate scrubbers operate as countercurrent PM collection devices. The scrubbing liquid flows
down the tower while the gas stream flows upward. Contact between the liquid and the particle-laden gas
occurs on the plates.  The plates are equipped with openings that allow the gas to pass through.  Some plates
are perforated or slotted, while more complex plates have valve-like openings (EPA, 1998).

The simplest impingement-plate scrubber is the sieve plate, which has round perforations. In this type of
scrubber, the scrubbing liquid flows overthe plates and the gas flows up through the holes. The gas velocity
prevents the liquid from flowing down through the perforations.  Gas-liquid-particle contact is achieved within
the froth generated by the gas passing through the liquid layer. Complex plates, such as bubble cap or baffle
plates, introduce an additional means of collecting PM. The bubble caps and baffles placed above the plate
perforations  force the gas to turn before escaping the layer  of liquid.  While the gas  turns  to avoid  the
obstacles, most PM cannot and is collected by impaction on the caps or baffles.  Bubble caps and the like also
prevent liquid from flowing down the perforations if the gas flow is reduced (EPA, 1998).

In all types of impingement-plate scrubbers, the scrubbing liquid flows across each plate and down the inside
of the tower onto the plate below.  After the bottom plate, the liquid and collected PM flow out of the bottom
of the tower.  Impingement-plate scrubbers are usually designed to provide operator access to each tray,
making them relatively easy to clean and maintain.  Consequently, impingement-plate scrubbers are more
suitable for PM collection than packed-bed scrubbers. Particles greater than 1  |j,m in aerodynamic diameter
can be collected effectively by impingement-plate scrubbers, but many  particles <1 |j,m  in aerodynamic
diameter will penetrate these devices (EPA, 1998).

Inorganic Gases Control:

Water is the most common solvent used to remove inorganic contaminants, though as caustic for is used for
acid-gas absorption (EPA, 1996).  Amphiphilic block copolymers can be used to absorb  hydrophobic VOC.
When used as part of an FGD system, an impingement-plate scrubber promotes contact between the flue
gas and the sorbent slurry in a vertical column with transversely mounted perforated trays. The SO2-laden
gas enters at the bottom of the column and travels upward through the perforations in the trays; the reagent
slurry is fed at the top and flows over the plates toward the bottom.  In most cases the sorbent is an alkaline
slurry, commonly limestone, slaked lime, or a mixture of slaked lime and alkaline fly ash, though many other
sorbent processes  exist. Absorption of SO2 is accomplished by countercurrent contact  between the gas
reagent slurry.  The sulfur oxides react with the sorbent, forming a wet mixture of calcium sulfite and sulfate
(EPA, 1981;Soud,  etal., 1993).
Advantages: Advantages of impingement plate scrubbers include (Cooper, 1994):

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        1.      Can handle flammable and explosive dusts with little risk;
        2.      Provides gas absorption and dust collection in a single unit;
        3.      Can handle mists;
        4.      Collection efficiency can be varied;
        5.      Provides cooling for hot gases;
        6.      Corrosive gases and dusts can be neutralized; and
        7.      Improves gas-slurry contact for SO2 removal.

Disadvantages: Disadvantages of impingement plate scrubbers include (AWMA, 1992, Cooper, 1994):

        1.      Effluent liquid can create water pollution problems;
        2.      Waste product collected wet;
        3.      High potential for corrosion problems;
        4.      Protection against freezing required;
        5.      Off-gas may require reheating to avoid visible (steam) plume;
        6.      Collected PM may be contaminated, and may not be recyclable; and
        7.      Disposal of waste sludge may be very expensive.

Other Considerations:

For PM applications, wet scrubbers generate waste in the form of a slurry. This creates the need for both
wastewater treatment and solid waste disposal. Initially, the slurry is treated to separate the solid waste from
the water. The treated water can then be reused or discharged. Once the water is removed, the remaining
waste will be in the form of a solid  or sludge.  If the solid waste is inert and nontoxic, it can generally be
landfilled.  Hazardous wastes will have more stringent procedures for disposal. In some cases, the solid
waste may have value and can be sold or recycled (EPA, 1998).

For gas absorption, the water or other solvent must be treated to remove the captured pollutant from the
solution. The effluent from the column may be recycled into the system and used again.  This is usually the
case if the solvent is costly (e.g., hydrocarbon oils, caustic solutions). Initially, the recycle stream may go to
a waste treatment system to remove the pollutants  or the reaction product.  Make-up solvent may then be
added before the liquid stream reenters the column  (EPA, 1996).

For FGD applications, the slurry combines with the SO2-laden waste gas to form a waste slurry in the bottom
of the scrubber. The sludge is removed from the scrubber and, depending upon the reagent or sorbent used
to react with the SO2, the waste reacted sludge is disposed of,  recycled or regenerated, or, in some cases,
a salable product. For slurries which produce calcium sulfate and sulfite, oxidizing the waste sludge results
in gypsum.  Gypsum is a preferred product because it can be marketed and also  because of its superior
dewatering characteristics.  Most scrubbers are operated without the oxidizing step and the waste sludge must
be dewatered and disposed of properly. Some slurries can be regenerated and used again, but few such
systems are in use due to high energy costs associated with the regeneration of the reagent (Sondreal,  1993;
Soud, et al., 1993; Merrick, 1989).

Configuring a control device that  optimizes control  of more than one pollutant often does not achieve the
highest control possible for any of the pollutants controlled alone. For this reason, waste gas flows  which
contain  multiple pollutants  (e.g., PM and SO2, or PM and inorganic gases) are generally  controlled with
multiple control devices, occasionally more than one type of wet scrubber (EC/R, 1996).
References:


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Avallone, 1996. "Marks' Standard Handbook for Mechanical Engineers," edited by Eugene Avallone and
Theodore Baumeister, 10th Edition, McGraw-Hill, New York, NY, 1996.

AWMA, 1992. Air& Waste Management Association, Air Pollution Engineering Manual, Van Nostrand
Reinhold, New York.

Cooper, 1994.  David Cooper and F. Alley, Air Pollution Control: A Design Approach, 2nd Edition,
Waveland Press, Prospect Heights, IL, 1994.

EC/R, 1996. EC/R, Inc., "Evaluation of Fine Particulate Matter Control Technology:  Final Draft," prepared
for U.S. EPA, Integrated Policy and Strategies Group, Durham, NC, September, 1996.

EPA, 1981. U.S. EPA, Office of Air Quality Planning and Standards, "Control Technologies for Sulfur
Oxide Emission from Stationary Sources," Second Edition,  Research Triangle Park,  NC, April, 1981.

EPA, 1991. U.S. EPA, Office of Research  and Development, "Control Technologies for Hazardous Air
Pollutants," EPA/625/6-91/014, Washington, D.C., June.

EPA, 1992. U.S. EPA, Office of Air Quality Planning and Standards, "Control Technologies for Volatile
Organic Compound Emissions from Stationary Sources," EPA 453/R-92-018, Research Triangle Park,
NC, December, 1992

EPA, 1993. U.S. EPA, Office of Air Quality Planning and Standards, "Chromium Emissions from
Chromium Electroplating and Chromic Acid Anodizing Operations - Background Information for Proposed
Standards," EPA-453/R-93-030a, Research Triangle Park,  NC, July 1993.

EPA, 1996. U.S. EPA, Office of Air Quality Planning and Standards, "OAQPS Control Cost Manual," Fifth
Edition, EPA 453/B-96-001, Research Triangle Park, NC February.

EPA, 1998. U.S. EPA, Office of Air Quality Planning and Standards, "Stationary Source Control
Techniques Document for Fine Particulate  Matter," EPA-452/R-97-001, Research Triangle Park, NC,
October.

Merrick, 1989.  David Merrick and Jan Vernon, "Review of Flue Gas Desulphurization Systems,"
Chemistry and Industry, February 6 , 1989.

Sondreal, 1993. Everett A. Sondreal, "Clean Utilization of Low-Rank Coals for Low-Cost Power
Generation," from "Clean and Efficient Use of Coal: The New Era for Low-Rank Coal," Organization for
Economic Co-Operation and Development/International Energy Agency, Paris, France,  1993.

Soud, et al., 1993. Hermine N. Soud, Mitsuru Takeshita, and Irene M. Smith, "FGC Systems and
Installations for Coal-Fired Plants" from "Desulfurization 3," Institution of Chemical Engineers,
Warwickshire, UK, 1993.
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