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-------
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Appendix D - 2
Stack Testing Field Data Sheets and Calibration Sheets
-------
EnvtronmeL
Technology &
PARTICIPATE FILuD DATA
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-------
LABORATORY DATA SHEET
PARTICULATE & WATER COLLECTED
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-------
Environmc
Technology &
Engineering Corp.
PARTICULATE F, _D DATA
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Environis'-tal
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Enviromnei
Technology 4
Engineering Corp.
PARTICULATE Fll D DATA
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LABORATORY DATA SHEET
PARTICULATE & WATER COLLECTED
JOB NAME
JOB NO.
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-------
LABORATORY DATA SHEET
PARTICULATE & WATER COLLECTED
JOB NAME
JOB NO.
RUN NO.
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DATE OF TEST °\ '
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NOTES:
-------
Environmi i
Technology &
Engineering Corp.
PARTICULATE Fu.LD DATA
m AMT
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Environme' "
Technoiow &
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PARTICIPATE F LD DATA
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LOCAT10M _
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STACX NO. .
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Environmer/
Technolo^ j.
Engineering Corp.
PARTICIPATE F LD DATA
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PARTIGULATE & WATER COLLECTED
JOB NAME
JOB NO.
DATE OF TEST
TEST ENGINEER
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JOB NAME
JOB NO.
RUN NO.
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-------
Environment
Technology *
Engineering Corp.
PART1CULATE FIL^J DATA
PVAWT
DATE
S"
LOCAT10M _
OPERATOR.
STACX HO. .
RUM NO.
AMBIENT TEMPERATURE
BAROMETRIC PRESSURE .
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-------
Environmei.
Technology
Engineering Corp.
PARTICULATE FIL^D DATA
AMBIENT TEMPERATURE
BAROMETRIC PRESSURE
ASSUMED MOISTURE.
PROBE LENGTH, ,
PROCESS TOCHT RATE
ORSAT RESULTS
LEAK CHECK-
MOZH-E WAJ«ETER. ;«.
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-------
EnvironmeL
Technology 4
Engineering Corp.
PARTICULATE FIL..D DATA
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LOCATION .
OPERATOR.
STACX NO.
AMBIENT TEMPERATURE
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LABORATORY DATA SHEET
PARTICULATE & WATER COLLECTED
JOB NAME
JOB NO.
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-------
LABORATORY DATA SHEET
PARTICULATE & WATER COLLECTED
JOB NAME
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JOB NAME
JOB NO.
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-------
Enviromm
Technology 4
Engineering Corp.
PART1CULATE Fi_LD DATA
DATE
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Environm<
technology 4
Engineering Corp.
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Environmei
Technology &
Engineering Corp.
PART1CULATE FlLi_D DATA
PT.AMT
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/£> ^
ie>1
>&%
!&<%
/£>*?
ffo
»&
H O
II )
m
ID
1l ~L
nt.
>} 3
)i J
l/ 3
)} V
> / c
MPERATURE
S METER
OUTLET
/£•/
y^z_
/s> >
/£> /
f&1~
ro~$
yo ^
I&1
)o°\
/£> *?
// c>
//c>
ft O
n }
ni
in
)) i__
HI.
n ~t>
" 3
LL3
»il
'f L!
SAMPLE BOX
TEMPERATURE
-F
2-3S"
•7^/sr
2, So
LST&
Z^T
Zsro
isrsr
Z-So
^SO
Z'/T
iio
~L*J &
TEMPERATURE
OF GAS
LEAVING
CONDENSER OR
LAST IMPINGER
F
V^
l/5"
yr
^5"
V«r
V^
V^"
•/sr
ijtr
^0
^o
So
PUMP
VACUUM
;.. H,
*• T_
-------
LABORATORY DATA SHEET
PARTIGULATE & WATER COLLECTED
JOB NAME
JOB NO.
DATE OF TEST /?>/
TEST ENGINEER
RUN NO.
Sample Box
' $
STACK
Filter
Wash Bottle
Beaker No.
WATER COLLECTED
Impinger No.
Final Wt. g Initial Wt. g Collected grams
7/7
/O
O
TOTAL
PARTICULATE COLLECTED
Filter
Washings
WATER COLLECTED
PARTICULATE COLLECTED
Final Wt. g Jare. Wt. g . Collected grams
ECTED
GRAMS
GRAMS
NOTES:
-------
JOB NAME
JOB NO.
RUN NO.
Sample Box
LABORATORY DATA SHEET
PARTICIPATE & WATER COLLECTED
STACK
Filter
>/f
DATE OF TEST /t>
I
TEST ENGINEER /<7/f/
Wash Bottle 0 • >
Beaker No.
WATER COLLECTED
Impin^er No.
Final Wt
Initial Wt. g Collected grams
TOTAL
PARTICULATE COLLECTED
Filter
Washings
Final Wt. g Tap-e-WtV
Collected grams
WATER COLLECTED
GRAMS
PARTICIPATE COLLECTED
NOTES;
GRAMS
-------
JOB NAME
JOB NO.
RUN NO.
Sample Box
LABORATORY DATA SHEET
PARTIGULATE & WATER COLLECTED
DATE OF TEST A? / "V ^'_'
TEST ENGINEER //J^/
STACK
Filter & O fl €^'-1
Wash Bottle
Beaker No.
WATER COLLECTED
Impinger No.
Final Wt. g Initial Wt. g Collected grams
//
too
0
111
TOTAL
PARTICULATE COLLECTED
Filter
Washings
WATER COLLECTED
PARTICULATE COLLECTED
NOTES:
Final Wt. g Tare Wt. g Collected grams
ECTED
GRAMS
TOTAL
GRAMS
-------
STACK TESTING CALIBRATION DATA
The probe tips, pitot tubes, dry gas meters, and sample box orifices used in the test efforts
were calibrated prior to the testing in accordance with the procedures outlined in the
Maintenance, Calibration, and Operation of Isokinetic Source-Sampling Equipment as
published by the US EPA as well as the applicable sections of EPA Methods 1 -4 and 29.
The values obtained were:
Test
Condition
3
4
5
6
7
10
11
12
13
14
18
19
20
21
22
23
24
25
27
28
Test
Date
10/31/05
11/3/05
11/2/05
11/1/05
11/09/05
2/1/06
1/12/06
1/11/06
2/2/06
11/7/05
2/206
9/27/05
9/28/05
9/29/05
9/30/05
10/18/05
11/15/05
11/10/05
11/16/05
10/17/05
10/19/05
Control
Box ID
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
2
2
2
2
2
Orifice Coeff.
(AH@)
0,725
0.725
0.725
0.725
0.725
0.730
0.722
0.722
0.730
0.725
0.730
0.725
0.725
0.725
0.725
1.007
0.725
0.725
0.725
0.725
0.725
Dry Gas Meter
Coeff. (y)
1.003
1.003
1.003
1.003
1.003
1.009
1.006
1.006
1.009
1.003
1.009
1.003
1.003
1.003
1.003
1.006
1.003
1.003
1.003
1.003
1.003
Control Box
Calib. Date
9/25/05
9/25/05
9/25/05
9/25/05
9/25/05
1/31/06
11/29/05
11/29/05
1/31/06
9/25/05
1/31/06
9/25/05
9/25/05
9/25/05
9/25/05
10/11/05
9/25/05
9/25/05
9/25/05
9/25/05
9/25/05
Probe Tip
Diameters
0.308 in.
0.308 in.
0.308 in.
0.308 in.
0.248 in.,
0.308 in.
0.248 in.
0.248 in.
0.248 in.
0.248 in.
0.308 in.
0.248 in.
0.248 in.,
0.370 in.
0.308 in.
0.308 in.
0.308 in.
0.187 in.
0.187 in.
0.308 in.
0.187 in.
0.308 in.
0.308 in.
The flow measurements were made with standard pitot tubes which were carefully
inspected every 60 days (at the dates of control box calibrations listed in the above table).
The pitot tubes and associated tubing were also inspected throughout each day of test
efforts to avoid plugging of orifices or holes in the tubing. For all of the test efforts, the two
pitot tubes used had coefficients (Cp) of 0.99.
The dry gas meters installed in the control boxes were temperature compensating meters;
therefore, only a slight temperature correction need be made to the volume of gas sampled.
The correction factors for the meters could best be described by the equation:
Y = Y (as listed above) + [(TM - 70) x 0.00012]
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant
: £&&
Time:
Run #
Location:
M3/min
Operators:
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer:_
Pre-Test Leak Check Q
M3/mrn x 35.315 = « Flf/min -
Critical Orifice Vacuum ^i^ ..in. Hg
Post-Test Leak Check O M3/min
M3/min x 35.315 = __0 Ft3/min
Critical Orifice Vacuum &.)*<£ in. Hg
M
Page 1
-------
• VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Run #
Time: //
I oration:
/If,
Operators:_
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer:_
rV
Pre-Test Leak Check
M3/mrnx35.315 =
Critical Orifice Vacuum.
M3/min
FtVmin -
Jn. Hg
Post-Test Leak Check 0 M3/min
M3/min x 35.315 = C _ Ft^/min
Critical Orifice Vacua m
in. Hg
Traverse
Cyclonic
Ap
(AP
5min
) avg
min. + sec.
sample time
running tirrie
gas meter
reading (L)
gas meter
temp.
vacuum (in.hg)
n
V'.
-77,7
y/
.* //
IT" //.
0, e
5" -
^ 0*3
77.3
0.-7CS5D
37 "
19. L
0.
7
0
* a3
II
7%c(
c>
fei
6 #3,3
71-.
of. /f
07
Til
!t> 7O7f
$-.3-7
7/
71
tot.
Page 1
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
: A*B
Time:
/ 30
Run*
Location:
Operators:_
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer: &-J.
Pre-Test Leak Check O M3/min
M3/mrn x 35.315 = _^_=_Ft3/min •
Critical Orifice Vacuum Alr O in. Hg
Post-Test Leak Check O M3/min
M3/min x 35.315 = Q?^ Ft3/min
Critical Orifice Vacuum
in. Hg
Traverse
Cyclonic
Ap
Smln
) avg
min. + sec.
sample time
running tirri'e
min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
O
O.
a
1 ', //
0, G>7O g
s //
37*
0,^
'$ t i
/ ? y j
71,
0,
/3
.<"
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEt I
Plant:
Date:
Run#
Time:
Location:
Operators: i
Beginning Stack Temp.: •—•'
Ending Stack Temp.: •—•
Average Stack Temp.: '-"~
Barometer:
Pre-Test Leak Check PS M3/min
M3/min x 35.315 = O FtfVmin •
Critical Orifice Vacuum 3.Q, ti in. Hg
Post-Test Leak Check M3/min
M3/min x 35.315 =
Critical Orifice Vacuum .- in. Hg
.Fp/min
Traverse
Point #
Cyclonic
Flow Angle
Ap
&p~
(Ep) avg
min. + sec.
sample time
"
running time
min.
<3
1
a
3
v
5"
6-
gas meter
reading (L)
^«5JT7^
5~77
tf/7
&*fQ
&fa
&S3
70^
gas meter
temp.
i?^, i
53t,"7
$"**O
fJ.I
ZT»7
r^-c!
TV-^"
critical orifice
vacuum (in.hg)
ao,#
310 -b
a a o
SLCJ* O
•3LO, 0
ao-o
3jcy, 0
tot.
tot
>D M3
Page 1
-------
stack" test'cafe "sheet
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
loU
Plant: /
Run#
Time: ID'* 13.
Location :
Operators:_j2lJ
Beginning Stack Temp.:.
Ending Stack Temp.:
Pre-Test Leak Check O M3/min
M3/min x 35.315 = O FtVmin -
Average Stack Temp.:
Barometer: ^X^/ (e>
Critical Orifice Vacuum,.
Post-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum_
in. Hg
M3/rnin
_Ft3/min
in. Hg
Traverse
Cyclonic
Ap
avg
min. + sec.
sample time
running time
gas meter
reading (L)
gas meter
temp.
vacuum (in.hg)
o
, o
#30
y*
M&/y
13
f II
-7*1.1
Ifo
y
/3
v/a
£1-7
1±
.a/
777
017
SrSit
O,
3-L
O
11
/3k
3L
ff?
tot.
Page 1
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Time:
Location :
Operators: o ~2^it'-*-
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer:
Run #
Pre-Test Leak Check
M3/min x 35.315 =
Critical Orifice Vacuum_
Post-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum,
_M3/min
— Ft^/min -
in. Hg
M3/rnin
_FtJ/min
in. Hg
Traverse
Point #
Cyclonic
Flow Angle
Ap
avg
min. + sec.
sample time
running time
min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
©
SrV.
&.
LCf
y
5- >i
704
7
. 3/
/3
5^. 3/
_1_
lo
V6. J 7
I,
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
Time:
Run*
Location :
Operators: T5~2- t
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer:
Pre-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum
_M3/min
FtVmin -
Jn. Hg
Post-Test Leak Check O. M3/min
M3/min x 35.315 = Q . FtrVmin
Critical Orifice Vacuum
in. Hg
Traverse
Point #
Cyclonic
Flow Angle
Ap
(AP"
'•fAp x 5min
(Ep) avg
min. + sec.
sample time
running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
&_
A!±L
S-/, 1
3
/ 3
4-
5-
S-/7
5" /
L
rt_
3"
"G~
707
3
/.
5-
3 I
7
1*07
70
/s-
tc?
o.
0.97 */
_u_
0* f/X
C)
5-l-SS
tot
Page 1
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
PSant: •"•"•
Date:
Run#
lime:
Location: *~
Operators:
Beginning Stack Temp.:
Ending Stack Temp,:
Average Stack Temp.: '~~~
Barometer:
Pre-Test Leak Check ifS M3/min
M3/min x 35.315 = O FtrVmin -
Critical Orifice Vacuum QO, f) in. Hg
Post-Test Leak Check M /min
M3/rnin x 35.315 =
Critical Orifice Vacuum .• in. Hg
.Ft^/min
Traverse
Point #
Cyclonic
Haw Angle
Ap
'
6F
'•f AD x Smln
(Ep) avg
min. + sec.
sample time
-
running time
min.
&
i
3
$-
6
gas meter
reading (L)
6CGf7J'
5-77
(c^'O
^^3,
^SJ
7c/£^
gas meter
temp.
f £..- V
5"3r X
o"3.-O
jf 7,3
5*3.7
5~y< oi
'f*7*g~~
critical orifice
vacuum (in.hg)
So, &
3LO .
si a o
3LCJ* O
'•*^ f*\ ^Y-
&{-\* * \~^
'^^i.X t Vj?
=SL(V, O
ot
>b M3
agel
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
/iS^ /7«Xtj
Date: la/ 3LVc>^ T\rc\e.\ 7
Plant:
Run #
1 ocation:
Operators:.
Beginning Stack Temp.: & V.
Ending Stack Temp.:.
M3/min
Pre-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum 3^1,0 in. Hg
Ft^/min
Average Stack Temp.:
Barometer: tsJLit y*
Post-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum
M3/min
Ft3/min
in. Hg
Traverse
Point #
Cyclonic
Flow Angle
Ap
Ap"x 5min
(pp) avg
min. + sec.
sample time
running time
min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
o
'•/7
5"' ^"
5.3-3
5' /V"
3
0.3-1
¥70
. SL
S" 37
a a . o
5"
5-
X7 /t,
5s 1 3-3
_/*_
3.3L
7
*/ $r
37
, d
5-
ya/
1.7.7
t/
7*7, /
1L
/7
3-3 t
o
O.//
7
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=2.70
77/3
f ffo"
77.JT
77,
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7
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li
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S7
Stl.sr
^
.-3.o2.7M3
Page 1
-------
slack test 'caic." sheet'
VELOCTTY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant: .Arli*-f-«*j
Date: iafaafas' Time: LL
Run#
Location:_
_A'i sl-nln
^
Operators:J
Beginning Stack Temp.: Z
Ending Stack Temp.:
Pre-Test Leak Check
M3/min x 35.315 =
Critical Orifice Vacuum_
O M3/min
_Ft3/min-
_in. Hg
Average Stack Temp.:
Barometer: 3.cf,S"Y
Post-Test Leak Check O M3/min
M3/min x 35.315 = & Ft^/min
' Critical Orifice Vacuum
in. Hg
Traverse
Point #
Cyclonic
Flow Angle
Ap
avg
min. + sec.
sample time
running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
&
5 ' ' 5"
3T
WO
^ d
•IT,
-33L
IT 31
3-7* //;••<
&*~ f /_&
76,1*
-&L
76 ^
7
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f /y
V, 93
7S-X
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«. 1 60-6
(3. //
•£.3/7
ray
O
71,$-
7^/3
37
73.-S-
/y, o
* 77
-c
707
7
C'e/7
5-
o.
31
7V,
10
\l
O
^L
¥.913
Ft* 3*3"
M
Page 1
-------
"stack" test' calc.'sfieet"
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:_
Date:
ssryc-^
Time:
Run #
3
Location:
yfr
Operators: D"
Wt
Pre-Test Leak Check C7 M3/min
M3/mi;n x 35.315 = & FtVmin -
Beginning Stack Temp.:_
Ending Stack Temp.:
Average Stack Temp.:
Barometer:
Critical Orifice Vacuum
in. Hg
Post-Test Leak Check M /min
M3/min x 35.315 =
Critical Orifice Vacuum in. Hg
_Ft3/min
Traverse
Point #
Cyclonic
Flow Angle
Ap
(Ep) avg
min. + sec.
sample time
running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
&
75.
s l
5- /•/'<
_7JL
3
1ST
72. i
17
7V.
0,
7
d./r
73".
F
_£1/1
Id
» 36 C>
7*1
_£/_
/-a
Ov
C*
5& 73- 1
3.3/7
13
M-
,18:73
', 77
_L
27
^^3_
73, i
7
0, y 7
,y/£-3
3.37
5"
-r
V?
r //
/3.I
71,
JT3
,r-
ot.
ot. /,
MJ
Page 1
-------
VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
Run #
Time:
Location: —
Operators: i
Beginning Stack Temp.: »—
Ending Stack Temp.: •—•
Pre-Test Leak Check (fS M3/min
M3/min x 35.315 = O FtVmin -
Critical Orifice Vacuum 3.O, cJ in. Hg
Average Stack Temp.: '~~
Barometer:
Post-Test Leak Check_
M3/min x 35.315 =
Critical Orifice Vacuum
_M3/min
FtfVmin
Jn. Hg
Traverse
Point #
Cyclonic
Flow Angle
Ap
fAp
(Ep) avg
min. + sec.
Sample time
-
mnning tirrie
min.
O
1
a
7
1
f
6
gas meter
reading (L)
GccffS
5~77
6!^
6*0
&(&.
&S3
70^
gas meter
temp.
$"^,y
53*7
o"3,C)
JT?,3
£^*7
r¥,
QO, O
3LCJ* O
'2.C, O-
"SU>-- O
, C)
tot
ot
Page 1
-------
Appendix E
Laboratory QA/QC Data for Stack Testing Samples
-------
NI STACK TEST PROJECT P1
A When Samples received in house, they are logged in.
IDs double checked by QA Coordinator when delivered to lab.
Three samples per test run are received... 1) front half- or probe rinse
2) filter
3) back half- or impringer
D The Filter part of the sample run:
1) these are large filter pads delivered in petrie dishes
2) they are digested according to Method 29, sec 8.3.1.2.
3) 4 rnls HF, and 6 rnls cone HN03 are the acids used.
4) As long as the filter < 1 g, digestion is complete, in that the final solution is clear and colorless.
Even though the procedure says to use 0.5 g sections; the chance of contamination is
increased, and reagent use would double, conflicting with our pollution prevention
philosophy.
5) When the microwave digestions are completed, the digestion solution is quantitatively transferred
to a 4-oz bottle and capped.
6) A LRB and LFB is also included with this prep batch
E The Probe rinse part of the sample run:
1) these are dellivered in quart glass jars.
2) they are digested according to Method 29, sec 8.3.3.
3) the initial total volume of the sample is measured and recorded.
4) the pH is checked with paper to insure it is < 2.0, and this is recorded.
5) Since the sample is to be analyzed for nickel only, the total volume is used.
The sample is "quantitatively" transferred to an appropriate sized beaker.
6) Reduce volume to about 20 mis, by evaporating on a hot plate.
this may take a couple of days, and sample must be protected from contamination,
by covering the beakers overnight.
7) The 20 rnls is then quantitatively transferred to a microwave vessel.
8) 4 rnls HF, and 6 rnls cone HN03 are added to each vessel and the samples are then microwaved.
9) A LRB and LFB is also included with this prep batch.
10) The digestate is then added to the corresponding "filter digestate" for the analytical fraction.
The digestion sample is expected to be clear and colorless to be complete.
F This analytical fraction corresponds to "analytical fraction 1A":
1) includes the filter pad and the probe rinse.
2) When the digested solutions are combined, the final volume is adjusted to a convenient level
with Dl water, (usually 100 mis)
3) This sample is now ready for analysis by Flame AA.
G The impinger samples corresponds to "analytical fraction 2A":
1) dellivered in quart glass jars.
2) digested according to Method 29, sec 8.3.4. And 8.3.4.2
3) the initial total volume of the sample is measured and recorded.
4) the pH is checked with paper to insure it is < 2.0, and this is recorded.
5) Since the sample is to be analyzed for nickel only, the total volume is used.
The sample is "quantitatively" transferred to an appropriate sized beaker.
6) Reduce volume to about 20 mis, by evaporating on a hot plate.
this may take a couple of days, and sample must be protected from contamination,
by covering the beakers overnight.
7) The 20 rnls is then quantitatively transferred to a microwave vessel.
NI STACK TEST PROJECT P2
3/29/2006LK
1 OF12
S/LAB/CoWkSht/2005 METHOD 29-2
-------
8) 10 rnls of 3% H2O2, and 10 rnls 50% HN03 are added to each vessel and the samples
are then microwaved.
9) A LRB and LFB is also included with this prep batch.
10) quantitatively transfer the digested sample to a labeled 4-oz bottle.
For uniformity, the volume is adjusted to 50 rnls using a 50-ml class A graduate.
The digestion sample is expected to be clear and colorless to be complete.
11) This sample is now ready for analysis by Flame AA.
I The Microwave program is as follows:
RAMP: 20 min
power = 1000 watts
temp = 170degC
HOLD: 10 min
power = 700 watts
temp= 170degC
VENT: 10 min
The applications specialists at MILESTONE, determined that since the Microwave Digestion Unit
has the capacity to monitor and control temperature, the program was set up a bit different than
that stated in the Method 29.
J Volumes were determined with Class A graduated cylinders, from 25 to 250-ml sizes.
Because of the large volumes involved, measuring was to 0.2 rnls with the 25-ml only. The other
two were 0.5. at best.
K All pHs were checked and recorded as <2.0.
L "QUANTITATIVELY" means that the containers used to transfer or hold the sample were carefully
rinsed with Dl, and those "rinses" were added to the sample base.
M Procedure for Method 306A
N For the calculation we are not concerned with volumes; just the actual mg of Nl present.
The initial volume of sample, and evaporating it down, is of no consequence.
If a portion of the initial volume was used, this would be taken into account.
The analytical fraction volume is used to adjust the mg/L Reading to just "MG".
3/29/2006LK
2 OF 12
S/LAB/CoWkShU2005 METHOD 29-2
-------
PROJECT # 080033: METHOD 29 FOR NICKEL
date: 11/01/05
1 Method Detection Limit for Flame AA of Nickel: 0.075 mg/L
This MDL is calculated as per 40CFR Part 136, Appendix B.
2 Detection for Impinger sample: 0.004 mg Ni
0.075 mg/L X "AF 2A" mis X "Initial Sample Volume" mis / "SF 2A" mis X 1 L / 1000 mis
FINAL MLS MLS OF ORIGINAL CONVERSION TO
MDL (AF2A) SAMPLE MLS USED "MG NI"
0.075 50 300 300 0.001 0.0038
Although the actual mis of "original sample" varied, the volume used is that which will yield the
highest value for the MDL.
2 Detection for filter & probe rinse sample: 0.007 mg Ni
0.075 mg/L X "AF 1A" mis X "Sample Volume" mis / "SF 1" mis X 1 L / 1000 mis
FINAL MLS MLS OF ORIGINAL CONVERSION TO
MDL (AF1A) SAMPLE MLS USED "MG NI"
0.075 100 ° 100 0.001 0.0075
3 Detection for TOTAL RUN sample: 0.011 mg Ni
= Impinger + filter & probe rinse
-------
Nl STACK TEST PROJECT
H The BLANK Sample batch
1) dellivered in quart glass jars.
2) digested according to Method 306A, sec 11.3.1.1
3) the initial total volume of the sample is measured and recorded.
4) the pH is checked with paper to insure it is < 2.0, and this is recorded.
5) Since the sample is to be analyzed for nickel only, the total volume is used.
The sample is "quantitatively" transferred to an appropriate sized beaker.
6) Reduce volume to aboutlOO mis, by evaporating on a hot plate.
When the volume is about 100 mis, add 10 mis cone HNO3.
Reflux the sample to near dryness
Add another 5 mis cone. HNO3, and complete the digestion
Quantitatively transfer the solution to a 50 ml volumetric flask.
Add 0.5 mis cone HNO3, and dilute to volume, (do not add Ca(NO3)2-this is nc
7) These solutions are now ready for Flame AA analysis.
-------
PROJECT # 2005110202: METHOD 29 FOR NICKEL
1 2 3456789 10
11
12
12
SA#
2
3
1
39
4
38
6
7
5
9
10
8
12
13
11
15
16
14
18
19
17
21
22
20
24
25
23
27
28
26
30
31
29
33
34
32
36
37
35
SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger (
filter
probe rinse
RUN ID
Cond. 3: RUN
#1
BLANK
Cond. 3: RUN
#2
Cond. 3: RUN
#3
Cond. 6: RUN
#1
Cond. 6: RUN
#2
Cond. 6: RUN
#3
Cond. 5: RUN
#1
Cond. 5: RUN
#2
Cond. 5: RUN
#3
Cond. 4: RUN
#1
Cond. 4: RUN
#2
Cond. 4: RUN
#3
MDL^
PH
<2.0
<2.0
<20
<2.0
<20
<2.0
< 20
<2.0
< 20
<2.0
<20
<2.0
<20
<2.0
<20
<2.0
<20
<2.0
< 20
<2.0
<2 0
< 2 0
<20
<2.0
< 2.0
< 2 0
•k ^
Sample
Fraction
SF = SFA)
336
1 filter
100.0
300
1 filter
99.0
334
1 filter
98.0
344
1 filter
98.0
331
1 filter
97.0
334
1 filter
98.0
335
1 filter
97.0
325
1 filter
96.0
328
1 filter
97.0
223
1 filter
98.0
334
1 filter
97 0
325
1 filter
97.0
324
1 filter
96 0
••< ',soa
1 filter *
100,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
NA
20
X 20-
i NA-
,-, &
REAGENTS
FOR DIG.
HNO3 + H2O2
HF + HN03
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HN03
W03 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 +• H20
HF + HNO3
HF + HNO3
HNO3 + H20
HF + HNO3
HF + HNO3
HF + HN03
HF + HNO3
WO3 -f\H20
-fcj^KNpS
-»HF,-+~HNO3
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.42
93.12
8,3.1 2
Analytical
Fraction
AF = AFA)
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
•MBMMBHM^BH
50
100
50
100
50
100
. '. ri50 ,
• MO'Q
Nl mg/L
Ca1 or Ca2 )
< 0.074
0.447
0.078
0.106
< 0.074
0.285
0.087
0.274
0.087
4.306
< 0.074
10.394
0.100
16.344
< 0.074
4.878
< 0.074
6.664
< 0.074
3.829
0.090
0.895
0.106
0.483
< 0 074
0.249
0.075 ;
0.075 »
MG Nl
IN INITIAL
SAMPLE
0.004
0.045
0.004
0.011
0.004
0.029
0.004
0.027
0.004
0.431
0.004
1.039
0.005
1.634
0.004
0.488
0.004
0.666
0.004
0.383
0.005
0.090
0.005
0.048
0.004
0.025
0.004
0.008
-K
TOTAL MG
PER RUN
.048
.015
0.032
.032
.435
1.043
.639
0.492
0.670
0.387
0.094
.054
0.029
- (hull
1 0 Samples that read
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
^5100 AA
1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
(For Specific instrument settings, see current copy of method.)
Date:
1/9/2006
Analyst: LK
(Mg/L)
IDL= 0.027
MDL= 0.075
RL = 0.10
LDR = 0.10 to 8.0
3
CALIBRA
Cal Curve:
Corr. Coef:
TION:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.237
0.517
1.019
2.069
4.966
0.9998
% Rec.
94.7
103.3 '
101.9
103.5
99.3
4
STANDARD TRACEABILITY
QC STANDARD
CCV CRA AAT
QCS LFM
Standard Name, Company, & Lot #
CPI QC-21 41M044
CPIQC-21 41M044
CPI05F011
(> 0.995 i
•5 <%AMPI F ANAI YTI^AL RUN
MAT-
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M'9
M29
SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
202-1+3
SPK
202-4+38
CCB
202-14+16
202-17+19
202-23+25
202-26+28
202-32+34
CCB
CCV
LFB
DUP
DSER OIL
202-6
202-1 2
CCV
202-18
202-24
202-36
STD CONC
5.00
2.00
0.05
0.25
1.00
0.50
1.00
2/10
1.00
READING
Mg/L
4.981
2.043
-0.024
0.077
0.230
-0.015
0.431
1.431
0.096
-0.008
8.861
1.637
5.913
3.860
0.449
0.036
0.488
1.033
0.057
0.191
-0.024
0.032
-.091
0.052
0.028
0.078
BLK
0.056
-0.018
-0.018
-0.001
-0.015
-0.015
-0.030
0.006
-0.027
-0.011
-0.037
-0.008
-0.001
-0.006
0.003
-0.007
-0.036
-0.021
0.031
-0.035
-0.021
0.036
0.016
-0.020
0.027
-0.047
-0.035
0.059
-0.055
0.009
-0.039
-0.048
-0.048
-0.005
0.017
0.003
RESULT
4.981
2.043
-0.024
0.021
0.092
0.248
0.231
-0.014
1.623
0.447
0.434
1.425
0.282
0.106
0.285
0.274
0.029
4.974
8.862
1.039
13.115
1.634
5.949
0.666
3.829
0.895
0.483
0.249
0.057
0.433
0.472
0.010
1.053
0.051
0.030
1.114
0.216
0.238
,-OTJ7oN.
t -0.082 }
•^887"
0.087
0.029
1.082
0.052
0.100
0.048
0.033
0.051
0.090
0.106
0.074
-0.027
0.271
DILI
To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1~0
10.0
10.0
1.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
to
1.0
DIL2
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
To
QC
RESULTS
102
-0.024
42
9?
108
2.8
1.0
99
0.010
106
0,029
-0027
Mg/L
0.285
10.394
4.878
6664
0.895
0.249
IERUH ONCE
0.051
0.078
0087
0.052
0.048
0.051
Ktn
mq/L
0.285
10.394
4.878
6.664
0.895
0.249
!
0.074
0.078
0.087
0.074
0.074
0.074
— I
ICP
95-105%R )
95-1 05%R )
< MDL )
70-130%R )
70-1 30%R }
90-11 0%R)
90-11 0%R)
< MDL )
80-120%R )
«10RPD, IFSA»20XMDL)
80-120%R )
<10%DIFF)
< MDL )
90-11 0%R)
(< MDL )
{90-110%R )
; 90-1 1 0%R }
(< MDL j
(80-120%R)
(<10 RPD, IF SA > 2QX MDL)
(80-120%R)
(<10%DIFF)
< <10%DIFF)
{< MDL i
( 90-11 0%R)
(< MDL )
( 90-11 0%R)
-------
Method Name: NI
Method Description: Nickel
Date: 01/09/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 15
Sample Info File: Untitled
Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 70
Results Data Set:
Element: Ni Seq. No.: 1
Sample ID; Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 2
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 3
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
AS :
BlnkCorr
Signal
0.074
0.075
0.075
0.075
0.000
0.46
AS !
BlnkCorr
Signal
0.008
0.004
0.009
0.007
0.003
40.94
AS
BlnkCorr
Signal
0.039
0.005
0.266
0.103
0.142
137.20
Loc. :
Peak
Area
0.074
0.075
0.075
Loc. :
Peak
Area
0.083
0.078
0.083
Loc. :
Peak
Area
0.121
0.087
"0.347
Date: 01/09/2006
Bkgnd Time
Area
0.000 08:35:00
0.000 08:35:02
0.000 08:35:04
Date: 01/09/2006
Bkgnd Time
Area
-0.009 08:36:44
-0.005 08:36:46
-0.009 08:36:48
Date: 01/09/2006
Bkgnd Time
Area
-0.044 08:36:57
-0.013 08:36:59
-0.275 08:37:01
Page 1
-------
Element: Ni Seq. No,: 4
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 5
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 6
Sample ID: Calib Blank
Repl SampleConc StndConc,
$ mcf/L mg/L ^
1 / ,'
2
3
Mean :
SD : I
%RSD:
Auto-zero performed.-'
Element: Ni Seq. \ No.: 7
Sample ID: CAL STD \
Repl SampleConc StndConc
# mg/L mg/L
1 \
2 \
3 \
Mean :
SD : \
%RSD :
AS LOG. :
BlnkCorr Peak
Signal Area
-0.106 0.079
-0.097 0.088
-0.100 0.085
-0.101
0.005
4.53
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 0.081
0.005 0.088
0.007 0.091
0.003
0.005
189.79
,AS"~~Eoc7 ": • -.; —
'*"' BlnkCorr Peak
/ Signal Area
0.000 0.087
-0.001 0.086
-0.003 0.084
-0.001
0.002
151.73
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 0.090
0.005 0.091
0.003 0.089 „
0.004 /
0.001 X
24.43 /
Date: 01/09/2006
Bkgnd Time
Area
-0.005 08:38:11
-0.014 08:38:14
-0.011 08:38:17
Date: 01/09/2006
-W- -/
\ \ \ '
Bkgnd Time \ A V \
Area kj J \ \01
-0.006 08:41:11 1^ , \ \J^
-0.014 08:41:13 \ K>
-0.016 08:41:15 Yfi-
^n
/
y
Date: 01/09/2006
Bkgnd Time
Area \
-0.01'B 08:41:35
-0.011 08:41:37
-0.009\ 08:41:39
|
I
•
i
i
Date: /01/09/2006
Bkgnd Time
Area
-d.005 08:42:24
/-0.005 08:42:26
/ -0.004 08:42:28 r- /
VfP
\ ^
\ \J
Standard number 1 applied'X.JO.25]
Correlation Coefficient: ~
Slope: 0.0162
Page 2
-------
Element: Ni Seq. No.: 36
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
i
o
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 37
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 38
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No^,: 39
Sample ID: "SAL-SID ^ \, v>
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1 applied.
Correlation Coefficient: 0
AS I
BlnkCorr
Signal
0.003
-0.001
-0.003
0.000
0.003
2081.21
AS :
BlnkCorr
Signal
-0.004
-0.003
-0.005
-0.004
0.001
20.40
AS :
BlnkCorr
Signal
-0.001
0.001
-0.001
0.000
0.001
187.21
AS
i- \~
-------
Element: Ni Seq. No.: 40
Sample ID: CAL STD
Repl SampleConc StndConc
# mg/L mg/L
-1
3
Mean:
SD :
%RSD:
Standard number 1 applied. [
Correlation Coefficient: 0.
Element: Ni Seq. No.: 41
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
i
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 42
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
9
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 43
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
9
3
Mean:
SD :
%RSD:
Standard number 4 applied.
AS Loc. :
BlnkCorr Peak
Signal Area
0.009 0.088
0.009 0.088
0.009 0.088
0.009
0.000
3.40
;o.25]
9998
AS Loc. :
BlnkCorr Peak
Signal Area
0.018 0,097
0.021 0.100
0.020 0.099
0.020
0.001
6.26
[0.50]
.9998
AS Loc. :
BlnkCorr Peak
Signal Area
0.039 0.118
0.038 0.117
0.039 0.118
0.039
0.000
1.06
[1.00]
.9998
AS Loc. :
BlnkCorr Peak
Signal Area
0.078 0.157
0.079 0.158
0.078 0.157
0.078
0.000
0.56
[2.00]
Date: 01/09/2006
Bkgnd Time
Area
0.000 09:47:11
0.000 09:47:13
0.000 09:47:15
Slope: 0.0377
Date: 01/09/2006
Bkgnd Time
Area
0.001 09:47:29
-0.002 09:47:31
0.000 09:47:33
Slope: 0.0377
Date: 01/09/2006
Bkgnd Time
Area
0.000 09:48:03
0.001 09:48:05
0.000 09:48:07
Slope: 0.0377
Date: 01/09/2006
Bkgnd Time
Area
0.001 09:48:25
0.001 09:48:27
0.001 09:48:30
Correlation Coefficient: 0.9997
Slope: 0.0377
Page 11
-------
Element: Ni Seq. No,: 44
AS Loc
Date: 01/09/2006
Repl
#
1
J.
3
Mean:
SD :
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
0.188
0.188
0.189
0.188
0.001
Peak
Area
0.267
0.267
0.267
Bkgnd
Area
0.001
0.002
0.001
Time
09:48:47
09:48:49
09:48:51
0.27
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9998
Slope: 0.0378
Ni
0.20
Concentration
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.009
0.020
0.039
0.078
0.188
Correlation Coefficient: 0.99978
Entered
Calculated
Concentration Concentration Standard
(mg/L)
0.25
0,50
l.QO
2.00
5.00
Slope:
(mg/L)
0.000
0.2368
0.5167
1.019
2.069
4.966
0.03784
Deviation
0.0009
0.0003
0.0012
0.0004
0.0004
0.0005
%RSD
187.2082
3. 3956
6.2608
1.0583
0.5556
0.2662
0
Page 12
-------
Element
Sample
: Ni Seq.
ID: ccv
No.: 45
Repl SampleConc StndConc
# mg/L mg/L
l -^ nn? 5.002
j-
9
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
i
2
3
Mean:
SD :
%RSD:
4. 997
4.944
4.981
0.0317
0.64
: Ni Seq.
ID: qcs
SampleConc
mg/L
2. 020
2. 036
2.072
2.043
0.0267
1.31
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0. 0143
0. 0124
-0.0698
-0.0239
0.0419
175.3
4.997
4.944
4.981
0.0317
0.64
No.: 46
StndConc
mg/L
2.020
2.036
2.072
2.043
0.0267
1.31
No.: 47
StndConc
mg/L
-0.0143
0.0124
-0.0698
-0.0239
0.0419
175.3
AS Loc. :
BlnkCorr
Signal
0.189
0.189
0.187
0.188
0.001
0.64
Peak
Area
0.268
0.268
0.266
AS Loc. :
BlnkCorr
Signal
0.076
0.077
0.078
0.077
0.001
1.31
AS
BlnkCorr
Signal
-0.001
0.000
-0.003
-0.001
0.002
175.28
Peak
Area
0.155
0.156
0.157
Loc. :
Peak
Area
0.078
0.079
0.076
Date: 01/09/2006
Bkgnd
Area
0.001
0.001
0.001
Time
09:49:39
09:49:41
09:49:43
/
j
Date: 01/09/2006
Bkgnd
Area
0.001
0.001
0.001
Date:
Bkgnd
Area
-0.001
-0.003
0.001
Time
09:50:05
09:50:07
09:50:10
/
01/09/2006
Time
09:50:29
09:50:31
09:50:33
-J
Page 13
-------
Element: Ni Seq.
Sample ID: Sample
No.: 48
AS Loc.
Repl SampleConc StndConc
# mg/L mg/L
1 0.0009 0.0009
Auto-zero performed.
BlnkCorr
Signal
0.000
Peak
Area
0.079
Date: 01/09/2006
Bkgnd Time
Area
-0.002 09:50:39
Element: Ni Seq. No.: 49
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0500
0.0695
0.1486
0.0560
0.1000
178.5
StndConc
mg/L
-0.0500
0.0695
0.1486
0.0560
0.1000
178.5
BlnkCorr
Signal
-0.002
0.003
0.006
0.002
0.004
178.50
Peak
Area
0.077
0.082
0.085
Bkgnd
Area
. 0.000
-0.005
-0.008
Ti
09:
09:
09:
me
50
50
50
:47
:49
:51
/
__!_—-
Element: Ni Seq. No.: 50
AS Loc.
Date: 01/09/2006
Repl
#
9
.£.
3
Mean:
SD :
SampleConc
mg/L
0. 0583
-0.0034
0.1755
0.0768
0.0909
StndConc
mg/L
0.0583
-0.0034
0.1755
0.0768
0.0909
BlnkCorr
Signal
0.002
0.000
0.007
0.003
0.003
Peak
Area
0.081
0.079
0.086
Bkgnd
Area
-0.002
0.001
-0.006
Time
09:51:
09:51:
09:51:
08
11
13
/
%RSD:
118.3
118.3
118.26
No,: 51
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0028
-0
-0
-0
0
.0157
.0071
.0067
.0093
139.5
StndConc
mg/L
0.0028
-0
-0
-0
0
.0157
.0071
.0067
.0093
139.5
BlnkCorr
Signal
0.000
-0.
0.
0.
0.
139
001
000
000
000
.48
Peak Bkgnd Time
Area Area
0.079 -0.002 09:51:28
0.078 -0.001 09:51:31
0.079 -0.001 09:51:33
v/
No.: 52
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 1333
0.1612
0.0901
0.1282
0.0358
27.92
StndConc
mg/L
0.1333
0.1612
0.0901
0.1282
0.0358
27.92
BlnkCorr
Signal
0.005
0.006
0.003
0.005
0.001
27.92
Peak
Area
0.084
0.085
0.082
Bkgnd
Area
-0.002
-0.003
-0.001
Time
09:53:
09
09
:53:
:53:
39
41
43
Page 14
-------
Element: Ni Seq. No.: 53
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0336 0.0336
2 0.0624 0.0624
3 0.0113 0.0113
Mean: 0.0358 0.0358
SD : 0.0256 0.0256
%RSD: 71.61 71.61
Element: Ni Seq. No.: 54
Sample ID: era 0.25
Repl SampleConc StndConc
# mg/L mg/L
1 0.1925 0.1925
2 0.2165 0.2165
3 0.2287 0.2287
Mean: 0.2126 0.2126
SD : 0.0184- 0.0184
%RSD: 8.67 8.67
Element: Ni Seq. No.: 55
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0011 -0.0011
2 -0.0281 -0.0281
3 -0.0246 -0.0246
Mean: -0.0179 -0.0179
SD : 0.0147 0.0147
%RSD: 82.07 82. (T7
Element: Ni Seq. No.: 56
Sample ID: era 0.25
Repl SampleConc StndConc
# mg/L mg/L
1 0.2321 0.2321
2 0.2285 0.2285
3 0.2294 0.2294
Mean: 0.2300 0.230,0
SD : 0.0018 0.0018
%RSD: 0.80 0.80
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.080
0.002 0.081
0.000 0.079
0.001
0.001
71.61
AS Loc. :
BlnkCorr Peak
Signal Area
0.007 0.086
0.008 0.087
0.009 0.088
0.008
0.001
8.67
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.001 0.078
-0.001
0.001
82.07
AS Loc. :
BlnkCorr Peak
Signal Area
0.009 0.088
0.009 0.088
0.009 0.088
0.009
0.000
0.80
Date: 01/09/2006
Bkgnd Time (\ \ I
> \ li
Area .1 /•- V^^~
-0.004 09:54:42 4#^ ,
-0.005 09:54:45 f _, O • ( JT
-0.002 09:54:47 j^
./
Date: 01/09/2006
Bkgnd Time . \ -s
Area , jJ) [J^^
0.001 09:55:20 A U ffl^
0.000 09:55:22 tt f^
0.000 09:55:24 '• ^ Y1^^
^0 ^ \
J \
Date: 01/09/2006
1
Bkgnd Time /
Area -,
-0.001 09:56:18 ^ ,
0.000 09:56:20 \, \ L
0.000 09:56:22 y^ -fy^ w
J
Date: 01/09/2006 I
1
Bkgnd Time /
Area /
0.000 09:56:47 j/_
0.000 09:56:49
0.000 09:56:52
n i~^
& i
Page 15
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0392
2 -0.0343
3 -0.0201
Mean: -0.0312
SD : 0.0099
%RSD: 31.73
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0159
2 0.0509
3 -0.0378
Mean: -0.0009
SD : 0.0462
%RSD: 4903
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0-081
2 -0.0325
3 -0.0051
Mean: -0.0153
SD : 0.0150
%RSD: 98.46
Element : Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1. 621
2 1,607
3 1.596
Mean: 1.608
SD : 0.0124
%RSD: 0.77
No. : 57
StndConc
mg/L
-0.0392
-0.0343
-0.0201
-0.0312
0.0099
31.73
, No.: 58
StndConc
mg/L
-0.0159
0.0509
-0.0378
-0.0009
0.0462
4903
. No. : 59
StndConc
mg/L
-0.0081
-0.0325
-0.0051
-0.0153
0.0150
98.46
. No. : 60
StndConc
mg/L
1.621
1.607
1.596
1.608
0.0124
0.77
AS I
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
31.73
AS ]
BlnkCorr
Signal
-0.001
0.002
-0.001
0.000
0.002
4902.95
AS :
BlnkCorr
Signal
0.000
-0.001
0.000
-0.001
0.001
98.46
AS
BlnkCorr
Signal
0.061
0.061
0.060
0.061
0.000
0.77
,oc. :
Peak
Area
0.078
0.078
0.078
joe. :
Peak
Area
0,078
0.081
0.078
LOG, :
Peak
Area
0.079
0.078
0.079
Loc. :
Peak
Area
0.140
0.140
0.139
Date: 01/09/2006
Bkgnd Time
Area
0.000 09:57:40
0.000 09:57:42
-0.001 09:57:45
___
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:03:38
-0.004 10:03:40
0.000 10:03:42
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:06:42
0.000 10:06:44
-0.001 10:06:47
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:08:30
0.000 10:08:32
0.000 10:08:35
Page 16
-------
Element: Ni Seq. No.: 61
Sample ID: 202-1+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.4422 0.4422
2 0.4224 0.4224
3 0.4290 0.4290
Mean: 0.4312 0.4312
SD : 0.0101 0.0101
%RSD: 2.34 2.34
Element: Ni Seq. No.: 62
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0223 -0.0223
2 -0.0304 -0.0304
3 -0.0357 -0.0357
Mean: -0.0295 -0.0295
SD : 0.0068 0.0068
%RSD: 22.97 22.97
Element: Ni Seq. No.: 63
Sample ID: d202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.4099 0.4099
2 0.4021 0.4021
3 0.4023 0.4023
Mean: 0.4047 0.4047
SD : 0.0044 0.0044
%RSD: 1.10 1.10
Element: Ni Seq, No.: 64
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0228 -0.0228
2 0.0470 0.0470
3 -0.0051 -0.0051
Mean: 0.0064 0.0064
SD : 0.0363 0.0363
%RSD: 570.5 570.5
AS Lo
BlnkCorr
Signal
0.017
0.016
0.016
0.016
0.000
2.34
c. :
Peak
Area
0.096
0.095
0.095
AS LOG. :
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
22.97
Peak
Area
0.078
0.078
0.078
AS Loc. :
BliikCorr
Signal
0.016
0.015
0.015
0.015
0.000
1.10
Peak
Area
0.095
0.094
0.094
AS Loc. :
BlnkCorr
Signal
-0.001
0.002
0.000
0.000
0.001
570.46
Peak
Area
0.078
0.081
0.079
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:09:14
0.001 10:09:17
0.000 10:09:19
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:09:59
0.000 10:10:01
0.000 10:10:03
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:10:29
0.001 10:10:31
0.001 10:10:33
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:10:50
-0.003 10:10:52
-0.001 10:10:54
Page 17
-------
Element: Ni Seq. No.: 65
Sample ID: s202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 1.419 1.419
2 1.419 1.419
3 1.455 1.455
Mean: 1-431 1.431
SD : 0.0204 0.0204
%RSD: 1-43 1.43
Element: Ni Seq. No.: 66
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0081 -0.0081
2 -0.0226 -0.0226
3 -0.0498 -0.0498
Mean: -0.0269 -0.0269
SD : 0.0212 0.0212
%RSD: 78.83 78.83
Element: Ni Seq. No.: 67
Sample ID: ser202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.2490 0.2490
2 0.2584 0.2584
3 0.2584 0.2584
Mean: 0.2553 0.2553
SD : 0.0054 0.0054
%RSD: 2.12 2.12
Element: Ni Seq. No.: 68
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0092 -0.0092
2 -0.0237 -0.0237
3 0.0002 0.0002
Mean: -0.0109 -0.0109
SD : 0.0120 0.0120
%RSD: 110.3 110.3
AS Loc. :
BlnkCorr Peak
Signal Area
0.054 0.133
0.054 0.133
0.055 0.134
0.054
0.001
1.43
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.002 0.077
-0.001
0.001
78.83
AS Loc. : - —
BlnkCorr Peak
Signal Area
0.009 0.088
0.010 0.089
0.010 0.089
0.010
0.000
2.12
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
0.000 0.079
0.000
0.000
110.30
Date: 01/09/2006
• '
Bkgnd Time
Area
0.001 10:11:14
0.001 10:11:16
0.000 10:11:18
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:11:34
0.000 10:11:36
0.000 10:11:38
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:12:34
0.000 10:12:36
0.000 10:12:39
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:12:52
0.000 10:12:54
-0.002 10:12:56
Page 18
-------
Element: Ni Seq. No.: 69
Sample ID: 202-4+38
Repl SampleConc StndConc
# mg/L mg/L
1 0.1234 0.1234
2 0.0758 0.0758
3 0.0873 0.0873
Mean: 0.0955 0.0955
SD : 0.0248 0.0248
%RSD: 25.98 25.98
Element: Ni Seq. No.: 70
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0460 -0.0460
2 -0.0325 -0.0325
3 -0.0285 -0.0285
Mean: -0.0356 -0.0356
SD : 0.0092 0.0092
%RSD: 25.69 25.69
Element: Ni Seq. No.: 71
Sample ID: 202-5+7
Repl SampleConc StndConc
ft mg/L mg/L
1 0.2487 0.2487
2 0.2356 0.2356
3 0.2635 0.2635
Mean: 0.2493 0.2493
SD : 0.0140 0.0140
%RSD: 5.61 5.61
Element: Ni Seq. No.: 72
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0355 -0.0355
2 -0.0216 -0.0216
3 -0.0513 -0.0513
Mean: -0.0361 -0.0361
SD : 0.0149 0.0149
%RSD: 41.13 41.13
AS Lo
BlnkCorr
Signal
0.005
0.003
0.003
0.004
0.001
25.98
c. :
Peak
Area
0.084
0.082
0.082
AS Loc. :
BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
25.69
Peak
Area
0.077
0.078
0.078
AS Loc. :
BlnkCorr
Signal
0.009
0.009
0.010
0.009
0.001
5.61
Peak
Area
0.088
0.088
0.089
AS Loc. :
BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
41.13
Peak
Area
0.078
0.078
0.077
Date: 01/09/2006
Bkgnd Time
Area
-0.004 10:13:28
-0.002 10:13:30
-0.002 10:13:32
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:13:47
0.000 10:13:49
-0.001 10:13:51
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:14:14
0.000 10:14:16
0.000 10:14:18
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:14:32
0.000 10:14:34
0.001 10:14:37
Page 19
-------
Element: Ni Seq.
Sample ID: 202-8+10
Repl SampleConc
# mg/L
I 0.2427
2 0.2428
3 0.2280
Mean: 0.2378
SD : 0.0085
%RSD: 3.58
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0368
2 -0.0027
3 -0.0435
Mean: -0.0031
SD : 0.0401
%RSD: 1285
Element: Ni Seq.
No.: 73
StndConc
mg/L
0.2427
0.2428
0.2280
0.2378
0.0085
3.58
No.: 74
StndConc
mg/L
0.0368
-0.0027
-0.0435
-0.0031
0.0401
1285
, No.: 75
AS 1
BlnkCorr
Signal
0.009
0.009
0.009
0.009
0.000
3.58
JOG. :
Peak
Area
0.088
0.088
0.088
AS Loc. :
BlnkCorr
Signal
0.001
0.000
-0.002
0.000
0.002
1284.97
Peak
Area
0.080
0.079
0-077
AS Loc. :
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:14:59
0.001 10:15:02
0.001 10:15:04
Date: 01/09/2006
Bkgnd Time
Area
-0.003 10:15:20
-0.001 10:15:23
0.000 10:15:25
Date: 01/09/2006
Sample ID: 202-11+13
Repl SampleConc
# mg/L
1 4.321
2 4.294
3 4.295
Mean: 4.303
SD : 0.0153
%RSD: 0.35
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0251
2 -0.0573
3 -0.0277
Mean: -0.0367
SD : 0.0179
%RSD: 48.65
StndConc
mg/L
4.321
4.294
4.295
4.303
0.0153
0.35
. No.: 76
StndConc
mg/L
-0.0251
-0.0573
-0.0277
-0.0367
0.0179
48.65
BlnkCorr
Signal
0.163
0.162
0.163
0.163
0.001
0.35
AS
BlnkCorr
Signal
-0.001
-0.002
-0.001
-0.001
0.001
48.65
Peak
Area
0.243
0.241
0.242
Loc. :
Peak
Area
0.078
0.077
0.078
Bkgnd Time
Area
0.001 10:15:44
0.001 10:15:46
0.001 10:15:48
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:16:08
0.001 10:16:10
0.000 10:16:12
Page 20
-------
No.: 77
AS LOG.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0435
0.0037
0.0164
-0.0078
0.0316
405.9
StndConc
mg/L
-0.0435
0.0037
0.0164
-0.0078
0.0316
405.9
BlnkCorr
Signal
-0.002
0.000
0.001
0.000
0.001
405.92
Peak
Area
0.077
0.079
0.080
Bkgnd
Area
0.000
-0.002
-0.003
Time
10:16:20
10:16:22
10:16:24
Element: Ni Seq. No.: 78
AS LOG.
Date: 01/09/2006
Repl
# :
i
9
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4 . 959
4.957
4.981
4.966
0.0134
0.27
StndConc
mg/L
4.959
4.957
4.981
4.966
0.0134
0.27
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.188 0.267 0.001 10:16:49
0.188 0.267 0.001 10:16:51
0.188 0.268 0.002 10:16:53
0.188
0.001
0.27
Element: Ni Seq. No.: 79
AS LOG.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0201
0.
0.
-0.
0.
0152
0035
0005
0180
3822
StndConc
mg/L
-0.0201
0
0
-0
0
.0152
.0035
.0005
.0180
3822
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.078 -0.001 10:17:12
0.
0.
0.
0.
3821
001 0.080 -0.002 10:17:14
000 0.079 -0.001 10:17:16
000
001
.57
Element: Ni Seq. No.: 80
AS Loc.
Date: 01/09/2006
Repl
#
i
-L
Sample
9
£*
S ample
^
O
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
8 . 833
absorbance
8. 899
absorbance
8.851
absorbance
8.861
0.0340
0.38
absorbance
StndConc
mg/L
8.833
is
is
is
is
greater
8.899
greater
8.851
greater
8.861
0.0340
0.38
greater
BlnkCorr
Signal
0.334
than
0.
than
0.
than
0.
0.
0
that
337
that
335
that
335
001
.38
than that
Peak
Area
0.413
of
0.
of
0.
of
of
the
416
the
414
the
the
Bkgnd
Area
0.002
Time
10:17:
highest standard.
0.001 10:17:
highest standard.
0.001 10:17:
highest
highest
34
36
38
standard.
standard.
Page 21
-------
No.: 81
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0336
-0.0242
0.0387
-0.0064
0.0393
617.8
StndConc
mg/L
-0.0336
-0.0242
0.0387
-0.0064
0.0393
617.8
BlnkCorr
Signal
-0.001
-0.001
0.001
0.000
0.001
617.84
Peak
Area
0.078
0.078
0.080
Bkgnd
Area
0.000
0.000
-0.003
Time
10:18:00
10:18:02
10:18:04
Element: Ni Seq. No.: 82
AS Loc.
Date: 01/09/2006
Repl
#
"I
2
3
Mean:
SD :
%RSD:
SampleConc
rng/L
1. 026
1.032
1.041
1.033
0.0076
0.74
StndConc
mg/L
1.026
1.032
1.041
1.033
0.0076
0.74
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.039 0.118 0.001 10:19:09
0.039 0.118 0.001 10:19:11
0.039 0.118 0.000 10:19:14
0.039
0.000
0.74
Element: Ni Seq. No.: 83
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0408
-0. 0721
-0.0507
-0.0546
0.0160
29.31
StndConc
mg/L
-0.0408
-0.0721
-0.0507
-0.0546
0.0160
29.31
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.002 0.077 0.000 10:19:30
-0.003 0.076 0.001 10:19:32
-0.002 0.077 0.000 10:19:34
-0.002
0.001
29.31
Element: Ni Seq. No.: 84
Sample ID: 202-17+19
AS Loc,
Date: 01/09/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
rng/L
13.09
absorbance
13.10
absorbance
13.06
absorbance
13.08
0.0230
0.18
absorbance
StndConc
mg/L
13.09
is greater
13.10
is greater
13.06
is greater
13.08
0.0230
0.18
is greater
BlnkCorr
Signal
0.495
than that
0.496
than that
0.494
than that
0.495
O.OOl
0.18
than that
Peak Bkgnd Time
Area Area
0.574 0.001 10:19:59
of the highest standard.
0.575 0.001 10:20:01
of the highest standard.
0.573 0.001 10:20:04
of the highest standard.
of the highest standard.
Page 22
-------
Element: Ni Seq. No.: 85
AS Loc.
Date: 01/09/2006
sampj-ts
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0163
0.0532
-0.0292
0.0026
0.0443
1709
StndConc
mg/L
-0.0163
0.0532
-0.0292
0.0026
0.0443
1709
BlnkCorr
Signal
-0.001
0.002
-0.001
0.000
0.002
1708.94
Peak
Area
0.078
0.081
0.078
Bkgnd
Area
-0.001
-0.003
0.000
Time
10:20:19
10:20:21
10:20:23
===-==================
Element: Ni Seq. Mo.: 86
Sample ID: 202-17+19 xlO
AS Loc.
Date: 01/09/2006
nc BlnkCorr
Signal
7 0.062
6 0.063
8 0.061
7 0.062
6 0.001
6 1.5-6
Peak
Area
0.141
0.142
0.140
Bkgnd
Area
0.001
0.000
0.001
Time
10:21:17
10:21:20
10:21:22
Element: Ni Seq. No,: 87
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0551
-0.0445
-0.0306
-0.0067
0.0540
810.8
StndConc
mg/L
0.0551
-0.0445
-0.0306
-0.0067
0.0540
810.8
BlnkCorr
Signal
0.002
-0.002
-0.001
0.000
0.002
810.76
Peak
Area
0.081
0.077
0.07B
Bkgnd
Area
-0.003
0.000
0.000
Time
10:21:42
10:21:45
10:21:47
Element: Ni Seq. No.: 88
AS Loc.
Date: 01/09/2006
tJ dlllp U- ^
Repl
# :
1
J.
O
£.
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4 . 886
4 . 831
4.897
4.871
0.0352
0.72
StndConc
mg/L
4.886
4.831
4.897
4.871
0.0352
0.72
BlnkCorr Peak
Signal Area
0.185 0.264
0.183 0.262
0.185 0.264
0.184
0.001
0.72
Bkgnd Time
Area
0.001 10:22:10
0.001 10:22:12
0.001 10:22:14
Page 23
-------
Element: Ni Seq. No.: 89
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0493
-0.0133
-0.0438
-0.0355
0.0194
54.78
StndConc
mg/L
-0.0493
-0.0133
-0.0438
-0.0355
0.0194
54.78
BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.001
0.001
54.78
Peak
Area
0.077
0.079
0.077
Bkgnd
Area
0.000
-0.001
0.001
Time
10:22:30
10:22:32
10:22:35
======
Element: Ni Seq. No.: 90
Sample ID: 202-23+25
AS Loc.
Date: 01/09/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.940
absorbance
5.925
absorbance
5.875
absorbance
5.913
0.0342
0.58
absorbance
StndConc
mg/L
5.940
is greater
5.925
is greater
5.875
is greater
5.913
0.0342
0.58
is greater
BlnkCorr
Signal
0.225
than that
0.224
than that
0.222
than that
0.224
0.001
0.58
than that
Peak Bkgnd Time
Area Area
0.304 0.001 10:23:00
of the highest standard.
0.303 0.002 10:23:02
of the highest standard.
0.301 0.001 10:23:04
of the highest standard.
of the highest standard.
Element: Ni Seq. No.: 91
AS Loc.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0631
0. 0004
-0.0012
-0.0213
0.0362
169.7
StndConc
mg/L
-0.0631
0.0004
-0.0012
-0.0213
0.0362
169.7
BlnkCorr
Signal
-0.002
0.000
0.000
-0.001
0.001
169.66
Peak
Area
0.077
0.079
0.079
Bkgnd
Area
0.001
-0.001
-0.002
Time
10:23:35
10:23:37
10:23:39
Element: Ni Seq. No.: 92
AS Loc.
Date: 01/09/2006
Repl
ft
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.6306
0.
0.
0.
0.
6471
6575
6451
0135
2.10
StndConc
mg/L
0.6306
0.
0.
0.
0.
6471
6575
6451
0135
2.10
BlnkCorr Peak
Signal Area
0.024 0.103
0
0
0
0
.024 0.104
.025 0.104
.024
.001
2.10
Bkgnd Time
Area
0.001 10:24:34
0.001 10:24:37
0.001 10:24:39
Page 24
-------
Element: Mi Seq. No.: 93
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0060 0.0060
2 0.0629 0.0629
3 0.0230 0.0230
Mean: 0.0306 0.0306
SD : 0.0292 0.0292
%RSD: 95.37 95.37
Element: Ni Seq. No.: 94
Sample ID: 202-26+28
Repl SampleConc StndConc
# mg/L mg/L
1 3 834 3.834
2 3.872 3.872
3 3.874 3.874
Mean: 3.860 3.860
SD : 0.0225 0.0225
%RSD: 0.58 0.58
Element: Ni Seq. No.: 95
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
I 0.0034 0.0034
2 0 0606 0.0606
3 0.0362 0.0362
Mean: 0.0334 0.0334
SD : 0.0287 0:0287
%RSD: 86.03 86.03
Element: Ni Seq. No.: 96
Sample ID: 202-29+31
Repl SampleConc StndConc
# mg/L mg/L
1 0.9253 0.9253
2 0.9260 0.9260
3 0.9332 0.9332
Mean: 0.9282 0.9282
SD : 0.0044 0.0044
%RSD: 0.47 0.47
AS LOG. :
BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.001 0.080
0.001
0.001
95.37
AS Loc. :
BlnkCorr Peak
Signal Area
0.145 0.224
0.147 0.226
0.147 0.226
0.146
0.001
0.58
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.001 0.080
0.001
0.001
86.03
AS Loc. :
BlnkCorr Peak
Signal Area
0.035 0.114
0.035 0.114
0.035 0.114
0.035
0.000
0.47
Date: 01/09/2006
Bkgnd Time
Area
-0.002 10:25:18
-0.004 10:25:20
-0.002 10:25:22
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:25:50
0.001 10:25:53
0.000 10:25:55
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:26:11
-0.004 10:26:13
-0.003 10:26:15
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:26:38
0.000 10:26:40
0.000 10:26:42
Page 25
-------
Element: Ni Seq. No.: 97
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0491 -0.0491
2 -0.0371 -0.0371
3 -0.0171 -0.0171
Mean: -0.0345 -0.0345
SD : 0.0162 0.0162
%RSD: 46.89 46.89
Element: Ni Seq. No.: 98
Sample ID: 202-32+34
Repl SampleConc StndConc
# mg/L mg/L
1 0.4242 0.4242
2 0.4207 0.4207
3 0.5014 0.5014
Mean: 0.4488 0.4488
SD : 0.0456 0.0456
%RSD: 10.17 10.17
Element: Ni Seq. No.: 99
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.1494 0.1494
2 0.0253 0.0253
3 0.0136 0.0136
Mean: 0.0627 0.0627
SD : 0.0752 0.0752
%RSD: 119.9 119.9
Element: Ni Seq. No.: 100
Sample ID: 202-35+37
Repl SampleConc StndConc
# mg/L mg/L
1 0.2780 0.2780
2 0.3551 0.3551
3 0.3012 0.3012
Mean: 0.3114 0.3114
SD : 0.0395 0.0395
%RSD: 12.70 12.70
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.077
-0.001 0.078
-0.001 0.078
-0.001
0.001
46.89
AS Loc. :
BlnkCorr Peak
Signal Area
0.016 0.095
0.016 0.095
0.019 0.098
0.017
0.002
10.17
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 0.085
0.001 0.080
0.001 0.080
0.002
0.003
119.90
AS Loc. :
BlnkCorr Peak
Signal Area
0.011 0.090
0.013 0.092
0.011 0.090
0.012
0.001
12.70
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:26:59
0.000 10:27:01
-0.001 10:27:03
Date: 01/09/2006
„ , •-—• •
Bkgnd Time
Area
0.000 10:27:42
0.000 10:27:44
-0.002 10:27:46
Date: 01/09/2006
Bkgnd Time
Area
-0.007 10:28:01
-0.002 10:28:03
-0.001 10:28:05
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:28:26
-0.002 10:28:28
0.000 10:28:30
Page 26
-------
Element: Ni Seq. No.: 101
AS Loc.
Date: 01/09/2006
samp-Lt;
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0387
0.0108
-0.0341
-0.0207
0.0273
132.2
StndConc
mg/L
-0.0387
0.0108
-0.0341
-0.0207
0.0273
132.2
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
132.22
Peak
Area
0.078
0.079
0.078
Bkgnd
Area
0.000
-0.002
0.000
T:
10
10
10
ime
:28:45
:28:47
:28:49
-======
No.: 102
AS Loc.
Repl
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0133
0.0193
0.0762
0.0362
0.0347
95.83
StndConc
mg/L
0.0133
0.0193
0.0762
0.0362
0.0347
95.83
BlnkCorr
Signal
0.001
0.001
0.003
0.001
0.001
95.83
Peak
Area
0.080
0.080
0.082
Bkgnd
Area
-0.003
-0.002
-0.005
Time
10:40:03
10:40:05
10:40:07
Element: Ni Se.cf.''" No. : 103
AS Loc.:
Date: 01/09/2006
Repl SampleConc
# mg/L I
i n.4fi?5
2
3
Mean:
SD :
%RSD:
0.
n.
0.
0.
4109
47,31
46'88
005f
:====—:==
StndConc BlnkCorr Peak
mg/L Signal \ Area
0.4625 0.018 I 0.097
0
0
0
0
x--^..
.4709
.4731
.4688
.0056
1.19 ,
0
0
0
0,
.018 / 0.097
. 018/ 0.097
. 018
v'OOO
1. 19
Bkgnd Time
Area
0.001 10:41:52
0.001 10:41:54
0.001 10:41:56
\ t— .0 t~{j^ -
! p i/3
Element: Ni Seq. No.: 104
AS Loc.
Date: 01/09/2006
Repl
#
I
J-
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 0009
0. 0194
0.0267
0.0157
0.0133
84.93
StndConc
mg/L
0.0009
0.0194
0.0267
0.0157
0.0133
84.93
BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.001
84.93
Peak
Area
0.079
0.080
0.080
Bkgnd
Area
-0.002
-0.002
-0.002
Time
10:42:27
10:42:29
10:42:31
Page 27
-------
Element: Ni Seq.
Sample ID: ccv
No.: 105
Repl SampleConc StndConc
# mg/L mg/L
1 0.4758 0.4758
2 0.4903 0.4903
3 0.4981 0.4981
Mean: 0.4881
SD : 0.0113
%RSD: 2.32
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0097
2 -0.0285
3 -0.0239
Mean: -0.0207
3D : 0.0098
%RSD: 47.22
Element: Ni Seq.
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0140
2 -0.0012
3 -0.0157
Mean: -0.0103
SD : 0.0079
%RSD: 76.69
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0249
2 -0.0042
3 -0.0300
Mean: -0.0197
SD : 0.0137
%RSD: 69.22
0.4881
0.0113
2.32
No.: 106
StndConc
mg/L
-0.0097
-0.0285
-0.0239
-0.0207
0.0098
47.22
. No. : 107
StndConc
mg/L
-0.0140
-0.0012
-0.0157
-0.0103
0.0079
76.69
. No. : 108
StndConc
mg/L
-0.0249
-0.0042
-0.0300
-0.0197
0.0137
69.22
AS LOG. :
BlnkCorr
Signal
0.018
0.019
0.019
0.018
0.000
2.32
Peak
Area
0.097
0.098
0.098
AS Loc.:
BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
47.22
Peak
Area
0.079
0.078
0.078
AS Loc. :
BlnkCorr
Signal
-0.001
0.000
-0.001
0.000
0.000
76.69
AS
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
69.22
Peak
Area
0.078
0.079
0.078
Loc. :
Peak
Area
0.078
0.079
0.078
Date: 01/09/2006
Bkgnd Time / ;f/^-""
Area <-"'" '
0.001 10:42:53
0.000 10:42:55
0.000 10:42:57
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:43:14
0.000 10:43:16
0.000 10:43:18
Date: 01/09/2006
Bkgnd Time
Area
0.00-0 10:43:36
0.000 10:43:38
0.000 10:43:40
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:43:57
-0.002 10:43:59
-0.001 10:44:01
Page 28
-------
Element: Ni Seq.
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.016
2 1.047
3 1.035
Mean: 1.033
SD : 0.0158
%RSD: 1-53
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0700
2 -0.0536
3 0.0657
Mean: 0.0274
SD : 0.0701
%RSD: 256.0
Element: Ni Seq
Sample ID: 202-2
Repl SampleConc
# mg/L
1 0,1189
2 0.0636
3 0.0521
Mean: 0.0782
SD : 0.0357
%RSD: 45.66
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0048
2 0.0442
3 0.0417
Mean: 0.0270
SD : 0.0276
%RSD: 102.0
No.: 109
StndConc
mg/L
1.016
1.047
1.035
1.033
0.0158
1.53
No.: 110
StndConc
mg/L
0.0700
-0.0536
0.0657
0.0274
0.0701
256.0
. No. : 111
StndConc
mg/L
0.1189
0.0636
0.0521
0.0782
0.0357
45.66
. No. ; 112
StndConc
mg/L
-0.0048
0.0442
0.0417
0.0270
0.0276
102.0
AS Loc. :
BlnkCorr Peak
Signal Area
0.038 0.117
0.040 0.119
0.039 0.118
0.039
0.001
1.53
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.082
-0.002 0.077
0.002 0.082
0.001
0.003
256.01
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.084
0.002 0.081
0.002 0.081
0.003
0.001
45.66
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.002 0.081
0.001
0.001
101.99
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:44:23
0.000 10:44:25
0.000 10:44:27
Date: 01/09/2006
Bkgnd Time
Area
-0.004 10:44:40
0,000 10:44:43
-0.004 10:44:45
Date: 01/09/2006
Bkgnd Time
Area
-0.003 10:45:02
-0.001 10:45:04
0.000 10:45:06
Date: 01/09/2006
Bkgnd Time
Area
-0,001 10:45:21
-0.003 10:45:23
-0.003 10:45:25
Page 29
-------
Element: Ni Seq,
Sample ID: d202-2
Repl SampleConc
# mg/L
1 0.0331
2 0.0689
3 0.0696
Mean: 0.0572
SD : 0.0209
%RSD: 36.57
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0069
2 -0.0216
3 -0.0606
Mean: -0.0297
SD : 0.0278
%RSD: 93.53
Element: Ni Seq
Sample ID: s202-2
Repl SampleConc
# mg/L
1 1.089
2 1.078
3 1.086
Mean: 1.084
SD : 0.0055
%RSD: 0.50
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0447
2 -0.0233
3 -0.0316
Mean: -0.0332
SD : 0.0108
%RSD: 32.45
. No. : 113
StndConc
mg/L
0.0331
0.0689
0.0696
0.0572
0.0209
36.57
. No. : 114
StndConc
mg/L
-0.0069
-0.0216
-0.0606
-0.0297
0.0278
93.53
. No.: 115
StndConc
mg/L
1.089
1.078
1.086
1.084
0.0055
0.50
. No. : 116
StndConc
mg/L
-0.0447
-0.0233
-0.0316
-0.0332
0.0108
32.45
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.080
0.003 0.082
0.003 0.082
0.002
0.001
36.57
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.002 0.077
-0.001
0.001
93.53
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.120
0.041 0.120
0.041 0.120
0.041
0.000
0.50
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.077
-0.001 0.078
-0.001 0.078
-0.001
0.000
32.45
Date: 01/09/2006 .
Bkgnd Time
Area
0.000 10:46:14
-0.001 10:46:16
-0.001 10:46:18
Date: 01/09/2006
Bkgnd Time
Area
-0.002 10:46:34
-0.001 10:46:36
0.001 10:46:38
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:47:04
0.000 10:47:06
0.000 10:47:08
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:48:19
-0.001 10:48:21
0.000 10:48:23
Page 30
-------
Element: Ni Seq. No.: Ill
Sample ID: ser202-2
Repl SampleConc StndConc
# mg/L mg/L
1 0.1896 0.1896
2 0.1695 0.1695
3 0.1889 0.1889
Mean: 0.1827 0.1827
SD : 0.0114 0.0114
%RSD: 6.26 6.26
Element: Ni Seq. No.: 118
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0764 -0.0764
2 0.0027 0.0027
3 -0.0675 -0.0675
Mean: -0.0471 -0.0471
SD : 0.0433 0.0433
%RSD: 91.96 91.96
Element: Ni Seq. No.: 119
Sample ID: dser202-2
Repl SampleConc StndConc
# mg/L mg/L
1 0.1939 0.1939
2 0.1817 0.1817
3 0.1974 0.1974
Mean: 0.1910 0.1910
SD : 0.0083 0.0083
%RSD: 4.32 4.32
Element: Ni Seq. No.: 120
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0122 -0.0122
2 -0.0507 -0.0507
3 -0.0589 -0.0589
Mean: -0.0406 -0.0406
SD : 0.0249 0.0249
%RSD: 61.41 61.41
AS L
BlnkCorr
Signal
0.007
0.006
0.007
0.007
0.000
6.26
AS I
BlnkCorr
Signal
-0.003
0.000
-0.003
-0.002
0.002
91.96
AS !
BlnkCorr
Signal
0.007
0.007
0.007
0.007
0.000
4.32
AS
BlnkCorr
Signal
0.000
-0.002
-0.002
-0.002
q.ooi
61.41
ioc. :
Peak
Area
0.086
0.085
0.086
JOG. :
Peak
Area
0.076
0.079
0.076
LOG. :
Peak
Area
0.086
0.086
0.086
Loc. :
Peak
Area
0.079
0.077
0.077
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:49:21
0.000 10:49:23
-0.001 10:49:25
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:49:41
-0.002 10:49:43
0.000 10:49:45
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:50:10
0.000 10:50:12
0.000 10:50:14
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:50:35
0.000 10:50:37
0.000 10:50:39
Page 31
-------
Element: Ni Seq. No.: 121
AS Loc.
Date: 01/09/2006
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
-0.0237
-0.0375
-0.0451
-0.0354
0.0108
30.62
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 202-39
SampleConc
mg/L
0.0152
0.0617
0.0497
0.0422
0.0241
57.20
StndConc
mg/L
-0.0237
-0.0375
-0.0451
-0.0354
0.0108
30.62
. No. : 122
StndConc
mg/L
0.0152
0.0617
0.0497
0.0422
0.0241
57.20
BlnkCorr
Signal
-0.0.01
-0.001
-0.002
-0.001
0.000
30.62
AS
BlnkCorr
Signal
0.001
0.002
0.002
0.002
0.001
57.20
Peak
Area
0.078
0.078
0.077
Loc. :
Peak
Area
0.080
0.08-1
0.081
Bkgnd
Area
-0.001
0.000
0.000
Time
10:53:
10:53:
10:53:
11
13
15
Date: 01/09/2006
Bkgnd
Area
0.000
-0.001
-0.001
Time
10:53
10:53
10:53
:33
:36
:38
, m/nn/onnc
Element: Ni Seq. No.: 123
AS Loc.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCD
SampleConc
mg/L
-0.0226
-0.0108
-0.0375
-0.0236
0.0134
56.60
StndConc
mg/L
-0.0226
-0.0108
-0.0375
-0.0236
0.0134
56.60
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
56.60
Peak
Area
0.078
0.079
0.078
Bkgnd
Area
-0.001
-0.001
0.000
Time
10:53:52
10:53:54
10:53:56
— ==============================
Element: Ni Seq. No*: 124
AS Loc.
sampj-e
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0396
0.0440
0.0728
0.0521
0.0180
34.61
StndConc
mg/L
0.0396
0.0440
0.0728
0.0521
0.0180
34.61
BlnkCorr
Signal
0.001
0.002
0.003
0.002
0.001
34.61
Peak
Area
0.081
0.081
0.082
Bkgnd
Area
0.001
0.000
0.000
Time
10:54:13
10:54:15
10:54:17
Page 32
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0444
2 -0.0433
3 -0.0253
Mean: -0.0376
SD : 0.0107
%RSD: 28.50
Element: Ni Seq,
Sample ID: 202-9
Repl SampleConc
# mg/L
1 0.0592
2 0.0543
3 0.0355
Mean: 0.0497
SD : 0.0125
%RSD: 25.15
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0627
2 -0.0403
3 -0.0626
Mean: -0.0552
SD : 0.0129
%RSD: 23.38
Element : Ni Seq
Sample ID: 202-12
Repl SampleConc
# mg/L
1 0.0108
2 0.0578
3 0.0272
Mean: 0.0319
SD : 0.0239
%RSD: 74.72
No.: 125
StndConc
mg/L
-0.0444
-0.0433
-0.0253
-0.0376
0.0107
28.50
. No. : 126
StndConc
mg/L
0.0592
0.0543
0.0355
0.0497
0.0125
25.15
. No. : 127
StndConc
mg/L
-0.0627
-0.0403
-0.0626
-0.0552
0.0129
23.38
. No.: 128
StndConc
mg/L
0-0108
0.0578
0.0272
0.0319
0.0239
74.72
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.077
-0.002 0.077
-0.001 0.078
-0.001
0.000
28.50
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.081
0.002 0.081
0.001 0.080
0.002
0.000
25.15
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.077
-0.002 a. 077
-0.002 0.077
-0.002
0.000
23.38
AS Loc. :
BlnkCorr" Peak
Signal Area
0.000 0,079
0.002 0.081
0.001 0.080
0.001
0.001
74.72
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:54:31
0.000 10:54:33
-0.001 10:54:36
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:54:51
0.000 10:54:53
0.000 10:54:56
Date: 01/09/2006
Bkgnd Time
Area
0.000 10:55:11
-0.001 10:55:14
0.000 10:55:16
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:55:43
-0.001 10:55:45
0.000 10:55:47
Page 33
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0756
2 -0.0567
3 -0.0891
Mean: -0.0738
SD : 0.0162
%RSD: 22.01
Element: Hi Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0574
2 -0.0944
3 -0.0627
Mean: -0.0715
SD : 0.0200
%RSD: 27.93
Element : Ni Seq
Sample ID: Sample
. No. : 129
StndConc
mg/L
-0.0756
-0.0567
-0.0891
-0.0738
0.0162
22.01
.No.: 130
StndConc
mg/L
-0.0574
-0.0-944
-0.0627
-0.0715
0.0200
27.93
. No. : 131
AS :
BlnkCorr
Signal
-0.003
-0,002
-0.003
-0.003
0.001
22.01
AS
BlnkCorr
Signal
-0.002
-0.004
-0.002
-0.003
0.001
27.93
AS
Loc. :
Peak
Area
0.076
0.077
0.076
Loc. :
Peak
Area
0.077
0.075
0.077
Loc. :
Date: 01/09/2006
Bkgnd Time
Area
0.001 10:56:02
0.000 10:56:04
0.001 10:56:06
Date: 01/09/2006
Bkgnd Time
Area
-0.001 10:58:09
0.001 10:58:11
0.000 10:58:13
Date: 01/09/2006
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0749 -0.0749
Aufco-zero performed.
BlnkCorr Peak
Signal Area
-0.003 0.076
Bkgnd Time
Area
0.000 10:58:58
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0368
0.0016
-0.0244
-0.0199
0.0196
98.59
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0042
0.0226
0.0005
0.0091
0.0118
129.6
.No.: 132
StndConc
mg/L
-0.0368
0.0016
-0.0244
-0.0199
0.0196
98.59
. No.: 133
StndConc
mg/L
0.0042
0.0226
0.0005
0.0091
0.0118
129.6
AS Loc. :
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
98.59
AS
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
129.55
Peak
Area
0.075
0.076
0.075
Loc. :
Peak
Area
0.076
0.077
0.076
Date: 01/09/2006
Bkgnd
Area
0.001
0.000
0.001
Date:
Bkgnd
Area
0.000
-0.001
0.000
Time
10:59:
10:59:
10:59:
05
07
10
01/09/2006
Time
11: 03:
11:03:
11:03:
17
19
21
Page 34
-------
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 1.085
2 1.112
3 1-077
Mean: 1.091
SD : 0.0185
%RSD: 1-70
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2860
2 0.2812
3 0.3049
Mean: 0.2907
SD : 0.0125
%RSD: 4.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
ft mg/L
1 0.0382
2 -0.0004
3 0.0352
Mean: 0.0243
SD : 0.0214
%RSD: 88.08
Element: Ni \ Seq
Sample ID: ccv\
Repl SampleConcX
# mg/L
1 0.2361
2 0.2298
3 0.2255
Mean: 0.2305
SD : 0.0053
%RSD: 2.32 /
No.: 134
StndConc
mg/L
1.085
1.112
1.077
1.091
0.0185
1.70
. No. : 135
StndConc
mg/L
0.2860
0.2812
0.3049
0.2907
0.0125
4.31
. No.: 136
StndConc
mg/L
0.0382
-0.0004
0.0352
0.0243
0.0214
88.08
.No.: 137
.StndCoofc-
rag/L /
0\2361
0/2298
/. 225.5^
/0.2305\
/ 0.0053 >
2.32
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.117
0.042 0.118
0.041 0.117
0.041
0.001
1.70
AS Loc. :
BlnkCorr Peak
Signal Area
0.011 0.087
0.011 0.087
0.012 0.088
0.011
0.000
4.31
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.078
0.000 0.076
0.001 0.078
0.001
0.001
88.08
- AS Loc. :
/
BlnkCorr Peak
Signal Area
0.009 0.085
0.009 0.085
0.009 0.085
0.009 ,-, \
v 0.000 \ \ ^
\ 2.32 \v\ \
\ 'xN
Date: 01/09/2006
Bkgnd Time
Area
0.000 11:03:45
0.000 11:03:47
0.001 11:03:50
Date: 01/09/2006
Bkgnd Time
Area
0.000 11:04:12
0.000 11:04:14
-0.001 11:04:16
Date: 01/09/2006
Bkgnd Time
Area
-0.002 11:04:29
0.000 11:04:31
-0.002 11:04:33
Date: 01/09/2006
Bkgnd Time
Area » /
0.000 / 11:04:50 ^J\ /
I „-„,-_ V \ /
0.000 0-1:^4:52 ^/ v/
0.000 li,:>0V:55 K° A
wo >.|
G\ -j ^
*vV\ \ \/
{\ \ /• ^
\) \s -J i
A A' ^
VJ ^r\
Page 35
-------
Element: Ni Seq. No.: 138
AS Loc.
Date: 01/09/2006
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: ID: ccfo
SampleConc
mg/L
-0.0163
-0.0424
-0.0603
-0.0396
0.0221
55.83
StndConc
mg/L
-0.0163
-0.0424
-0.0603
-0.0396
0.0221
55.83
===========
BlnkCorr
Signal
-0.001
-0.002
-0.002
-0.002
0.001
55.83
Peak
Area
0.076
0.075
0.074
Bkgnd
Area
-0.001
0.000
0.001
Time
11:05:11
11:05:13
11:05:15
Element: Ni Seq. No.: 139
AS Loc,:
£>aiup-i-<=
Repl
#
1
2
3
Mean:
SD :
%RSD:
=
SampleConc
mg/L
0.0145
-0.0011
0.0247
0.0127
0.0130
102.1
StndConc
mg/L
0.0145
-0.0011
0.0247
0.0127
0.0130
102.1
BlnkCorr
Signal
0.001
0.000
0.001
0.000
0.000
102.10
—
Peak
Area
0.077
0.076
0.077
Bkgnd
Area
0.. 001
0.001
0.001
Time
11:05:31
11:05:33
11:05:36
No.: 140
AS Loc.
Date: 01/09/2006
OdlUJJ-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0,0180
-0.0700
-0.0546
-0.0475
0.0267
56.14
StndConc
mg/L
-0.0180
-0.0700
-0.0546
-0.0475
0,0267
56.14
BlnkCorr
Signal
-0.001
-0.003
-0.002
-0.002
0.001
56.14
•
Peak
Area
0.076
0.074
0.074
Bkgnd
Area
-0.001
0.001
0.000
Time
11:05:50
11:05:52
11:05:54
No.: 141
AS Loc.
Date: 01/09/2006
Repl
#
]_
•)
£u
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 0412
0. 0686
0.0468
0.0522
0.0145
27.71
StndConc
mg/L
0.0412
0.0686
0.0468
0.0522
0.0145
27.71
BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
27.71
Peak Bkgnd Time
Area Area
0.078 -0.001 11:06:10
0.079 -0.001 11:06:12
0.078 0.000 11:06:14
Page 36
-------
Element: Ni Seq. No.: 142
AS LOG,
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0601
-0.0373
-0.0472
-0.0482
0.0114
23.72
StndConc
mg/L
-0.0601
-0.0373
-0.0472
-0.0482
0.0114
23.72
BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.002
0.000
23.72
Peak
Area
0.074
0.075
0.074
Bkgnd
Area
0.000
0.000
0.000
Time
11:06:28
11:06:30
11:06:33
Element: Ni Seq. No.: 143
AS LOG.
Date: 01/09/2006
Repl
#
i
r>
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0. 0?1 9.
o
0.
-0.
0.
0196
0000
0005
0204
3851
StndConc
mg/L
-0.0212
0
0
-0
0
.0196
.0000
.0005
.0204
3851
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.075 0.001 11:06:47
0.
0.
0.
0.
3850
001 0.077 0.000 11:06:49
OQO 0.076 0.001 11:06:51
000
001
.97
Element: Ni Seq. No.: 144
AS LOG.
Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0534
-0. 0746
-0.0421
-0.0567
0.0165
29.13
StndConc
mg/L
-0.0534
-0.0746
-0.0421
-0.0567
0.0165
29.13
BlnkCorr Peak Bkgnd Time
Signal Area Area
-o!o02 0.074 0.000 11:07:07
-0.003 0.073 0.001 11:07:09
-0.002 0.075 0.000 11:07:11
-0.002
0.001
29.13
Element: Ni Seq.
Sample ID: Sample
No.: 145
AS Loc.
Date: 01/09/2006
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0196 -0.0196
Auto-zero performed.
BlnkCorr Peak
Signal Area
-0.001 0.075
Bkgnd Time
Area
-0.001 11:07:15
Element: Ni Seq. No.: 146
Sample ID: ccb
AS Loc.
Date: 01/09/2006
„ J- _ -,
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0253
0.0546
-0.0451
-0.0052
0.0528
StndConc
mg/L
-0.0253
0.0546
-0.0451
-0.0052
0.0528
BlnkCorr
Signal
-0.001
0.002
-0.002
0.000
0.002
Peak
Area
0.074
0.078
0.074
Bkgnd
Area
0.000
-0.003
0.001
Time
11:07:22
11:07:24
11:07:27
%RSD:
1006
1006 1006.49
Page 37
-------
Element: Ni Seq,
Sample ID: 202-24
Repl SampleConc
# mg/L
1 0.0279
2 0.0186
3 0.0371
Mean: 0.0279
SD : 0.0093
%RSD: 33.30
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0788
2 -0.0244
3 -0.0044
Mean: 0.0167
SD : 0.0547
%RSD: 328.4
Element: Ni Seq
Sample ID: 202-27
Repl SampleConc
# mg/L
1 0.0580
2 0.0942
3 0.0520
Mean: 0.0680
SD : 0.0229
%RSD: 33.58
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0437
2 -0.0562
3 -0.0341
Mean: -0.0447
SD : 0.0111
%RSD: 24.81
, No. : 147
StndConc
mg/L
0.0279
0.0186
0.0371
0.0279
0.0093
33.30
. No.: 148
StndConc
mg/L
0.0788
-0.0244
-0.0044
0.0167
0.0547
328.4
. No.: 149
StndConc
mg/L
0.0580
0.0942
0.0520
0.0680
0.0229
33.58
, No. : 150
StndConc
mg/L
-0.0437
-0.0562
-0.0341
-0.0447
0.0111
24.81
AS LOG. :
BlnkCorr Peak
Signal Area
0.001 0.076
0.001 0.076
0.001 0.077
0.001
0.000
33.30
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.078
-0.001 0.075
0.000 0.075
0.001
0.002
328.36
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.078
0.004 0.079
0.002 0.077
0.003
0.001
33.58
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.074
-0.002 0.073
-0.001 0.074
-0.002
0.000
24.81
Date: 01/09/2006
Bkgnd Time
Area
0.001 11:07:46
0.001 11:07:48
0.000 11:07:51
Date: 01/09/2006
Bkgnd Time
Area
-0.004 11:08:05
0.000 11:08:08
-0.001 11:08:10
Date: 01/09/2006
Bkgnd Time
Area
0.001 11:08:27
0.000 11:08:29
0.001 11:08:31
Date: 01/09/2006
Bkgnd Time
Area
0.001 11:08:46
0.001 11:08:49
0.001 11:08:51
Page 38
-------
Element: Ni Seq
Sample ID: 202-30
Repl SampleConc
# mg/L
1 0.0290
2 0.0638
3 0.0424
Mean: 0.0451
SD : 0.0176
%RSD: 38.96
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0277
2 -0.0357
3 -0.0507
Mean: -0.0381
SD : 0.0117
%RSD: 30.66
Element : Ni Seq
Sample ID: 202-33
Repl SampleConc
# mg/L
1 0.0608
2 0.0483
3 0.0933
Mean: 0.0675
SD : 0.0233
%RSD: 34.48
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0012
2 0.0049
3 0.0034
Mean: 0.0032
SD : 0.0019
%RSD: 58.53
. No.: 151
StndConc
mg/L
0.0290
0.0638
0.0424
0.0451
0.0176
38.96
.No.: 152
StndConc
mg/L
-0.0277
-0.0357
-0.0507
-0.0381
0.0117
30.66
. No. : 153
StndConc
mg/L
0.0608
0.0483
0.0933
0,0675
0.0233
34.48
. No.: 154
StndConc
mg/L
0.0012
0.0049
0.0034
0.0032
0.0019
58.53
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.077
0.002 0.078
0.002 0.077
0.002
0.001
38.96
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.074
-0.001 0.074
-0.002 0.074
-0.001
0.000
30.66
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.078
0.002 0.077
0.004 0.079
0.003
0.001
34.48
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.075
0.000 0.076
0.000 0.076
0.000
0.000
58.53
Date:
Bkgnd
Area
0.001
-0.001
0.000
Date:
Bkgnd
Area
0.001
0.001
0.001
Date:
Bkgnd
Area
-0.001
-0.001
-0.002
Date:
Bkgnd
Area
-0.001
-0.001
-0.001
01/09/2006
Time
11:09:08
11:09:10
11:09:12
01/09/2006
Time
11:09:29
11:09:31
11:09:33
01/09/2006
Time
11:09:48
11:09:51
11:09:53
01/09/2006
Time
11:1-0:08
11:10:10
11:10:12
Page 39
-------
Element: Ni Seq
Sample ID: 202-36
Repl SampleConc
# mg/L
1 0.1020
2 0.0831
3 0.0475
Mean: 0.0775
SD : 0.0276
%RSD: 35.65
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0581
2 0.0104
3 -0.0048
Mean: 0.0213
SD : 0.0328
%RSD: 154.4
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 0.0124
3 -0.0270
Mean: -0.0053
SD : 0.0200
%RSD: 377.6
Element: Ni Seq
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2641
2 0.2662
3 0.2665
Mean: 0.2656
SD : 0.0013
%RSD: 0.50
. No. : 155
StndConc
mg/L
0.1020
0.0831
0.0475
0.0775
0.0276
35.65
. No.: 156
StndConc
mg/L
0.0581
0.0104
-0.0048
0.0213
0.0328
154.4
. No.: 157
StndConc
mg/L
-0.0012
0.0124
-0.0270
-0.0053
0.0200
377.6
. No.: 158
StndConc
mg/L
0.2641
0.2662
0.2665
0.2656
0.0013
0.50
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 0.079
0.003 0.079
0.002 0.077
0.003
0.001
35.65
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.078
0.000 0.076
0.000 0.075
0.001
0.001
154.37
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.075
0.000 0.076
-0.001 0.074
0.000
0.001
377.55
AS Loc. :
BlnkCorr Peak
Signal Area
0.010 0.085
0.010 0.086
0.010 0.086
0.010
0.000
0.50
Date: 01/09/2006
Bkgnd Time
Area
-0.002 11:10:29
-0.002 11:10:31
0.000 11:10:33
Date: 01/09/2006
Bkgnd Time
Area
-0.003 11:10:46
-0.001 11:10:48
0.000 11:10:51
Date: 01/09/2006
Bkgnd Time
Area
0.000 11:10:58
-0.001 11:11:00
0.000 11:11:03
Date: 01/09/2006
Bkgnd Time
Area
0.000 11:11:23
0.000 11:11:25
0.000 11:11:27
Page 40
-------
IE i
k
p
RE
Prep Method : (check on!y one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301 OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
P
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3C
GFAA: EPA 200.9
GFAA: SW-846 301 5A (NoHC
OTHER:
M
Set #
I
20A "*" '"^ -5
L) MICROWAVE
OTHER:
MATRIX
1
7
£
4
5
6
7
8
9
10
11
1?
DRINH
Set
InifJ
'.
CINC
(check only one per page)
5 WATER
Set
date
4
,,T
4
Set
time
r
p HI
m/»-
Lab#
^ P^
//£) ^D^L
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Smp#
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(mis)
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(mis)
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Start Date:
febO
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S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
METALS PREP FORM
Set#
, Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: .
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:_____
MATRIX: (check only one per page)
DRINKING WATER
S\QA FORMS \FM-0411R02 \LK
Page 1 of 1
-------
MFTALS PREP FORM
Set#
Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: _
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:____
MATRIX: (check only one per page)
DRINKING WATER
AQUEOUS
OTHER:_
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
PROJECT # 2006020074: METHOD 29 FOR NICKEL
8
10
11
12
SA#
8
15
9
16
o
10
17
11
18
12
19
C
13
20
14
21
7
SAMPLE
DESCRPTION
impinger
filter
impinger
filter
impinger
filter
impinger
filter
impinger
filter
impinger
filter
impinger
filter
im$n,ger 'f
- filtejfs *V
RUN ID
BLANK
Cond. 10-1
Cond. 10-2
Cond. 10-3
Cond. 13-1
Cond. 14-4
Cond. 14-5
;; ^lyiou
PH
<20
<20
<2.0
<20
<2.0
<20
<20
< 20
<2.0
< 20
<2.0
<2,0
<2.0
<2.0
; ^ „
X \i
Sample
Fraction
(SF - SFA)
302
1 filter
100.0
300
1 filter
99.0
309
1 filter
100.0
316
1 filter
98.0
306
1 filter
97.0
313
1 filter
99.0
310
1 filter
100.0
"v300
'}- f filter
100X0 -
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
MA
^2.
\ .. 100
Nl mg/L
( Ca1 or Ca2 )
0.136
< 0.074
1.401
0.217
0.595
0.558
1.213
0.358
0.075
IN INITIAL
SAMPLE
0.004
0.014
0.004
0.140
0.004
0.022
0.060
0.056
0.005
0.121
0.036
,,.0.004
' 0^008
TOTAL MG
PER RUN
0.017
0.144
0.026
0.063
0.060
0.126
0.040
;;O.Q11
10 Samples that read
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
'5100 AA
1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
Date:
Analyst:
2/10/2006
LK
(For Specific instrument settings, see current copy of method.)
(Mg/L)
IDL= 0.027
MDL= 0.075
RL= 0.10
LDR = 0.10 to 8.0
3
CALIBRATION:
Cal Curve:
Corr. Coef:
Cone
0.25
050
1 00
200
5.00
xxxxxxxxx
Abs
0.009
0.020
0.035
0.078
0.184
Result
0.245
0.537
0.956
2.097
4.964
0.9995
% Rec.
97,8
107.4
95.6
104.9
99.3
4 STANDARD TRACEABILITY
QC STANDARD
Calibration
Standard Name, Company, & Lot #
CPIQC-21 Lot # 05H062
CCV, CRA, AAT
CPIQC-21 Lot#05H062
QCS, LFM
( > 0.995)
CPl QC-19 Lot#05FO11
s SAMPLE ANALYTICAL RUN
MAT-RIX
121
-191
121
121
121
121
M29
M29
M29
9
M29
M29
SAMPLE
QCS
STD
CCB
CRA
CRA
LRB
LFB
218-1
218-2
218-3
218-4
218-5
CCB
CCV
LRB
LFB
072-1
072-2
072-3
072-4
072-5
CCB
CCV
LRB
LFB
"074-8
SPK
DUP
SER OIL
CCB
CCV
074-9
074-1 0
074-11
074-12
074-13
074-14
CCB
STD CONC
5.00
2.00
10.00
0.05
0.10
2.00
0.25
2.00
1.00
1.00
1.0
1.0
2/10
0.50
READING
Mg/L
4969
2 129
9.083
-0.004
0051
0.098
0.030
1.980
2.201
0.284
0061
0.676
0.144
0.001
0.249
0056
2.117
0.063
0262
0.086
2 357
0.179
-0.024
0 949
0023
1 076
0.058
1.113
1.030
0.226
-0019
0.510
0033
0058
0.031
0069
0.101
0.075
0.010
BLK
-0.007
-0004
-0.004
-0.006
-0 006
0.009
-0006
-0.005
0 006
-0.008
0.011
0.001
0 009
0004
0.010
-0.001
0007
-0.003
-0.001
-0.018
-0.024
-0006
-0.005
0.005
-0018
-0 008
-0.020
0.004
-0.019
-0013
-0024
-0 008
-0.011
0 003
0.001
-0 005
RESULT
4.969
2.129
9.083
0.003
0.055
0.102
0 036
1 986
2.192
0 290
0 066
0.671
0.151
-0 009
0.247
0.048
2.113
0.054
0.264
0.080
2360
0.180
-0 006
0.973
0.029
1.081
0053
1.131
1.038
0.246
-0.023
0 529
0.046
0.082
0039
0080
0 097
0 074
0.015
DILI
1.0
'.0
• .0
1.0
1.0
1.0
1.0
1.0
• .0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
DIL2
1.0
1.0
• .0
1.0
1.0
1.0
1.0
' .0
1.0
1.0
1.0
1.0
1.0
• .0
1.0
1.0
'.0
'.0
1.0
1.0
QC
RESULTS
99
106
91
0.003
109
102
0.036
99
-0.009
99
0.048
106
-0.006
97
0.029
108
108
8.5
8.8
-0.023
106
0.015
Mg/L
2.192
0.290
0.066
0.671
0.151
0.054
0.264
0.080
2.360
0.180
0.053
0.046
0.082
0.039
0.080
0.097
0.074
mq/L
2.192
0.290
0.074
0.671
0.151
0.074
0.264
0.080
2.360
0.180
A J
<(Mo
0.074
0.082
0.074
0.080
0.097
0.074
ICP
^TI_
/,o MJ
— ^
95-105%R)
95-105%R)
90-110%R)
20XMDL)
(<10%DIFF)
(
-------
QA/QC WORK SHEET for NICKEL P2
FLAA METHOD SOP MET-040
Date:
Analyst:
2/10/2006
LK
M29
M29
M29
M29
M29
3 IUU Hh
ccv
LRB
LFB
*074-1+15
SPK
DUP
SER OIL
CCB
CCV
CCV
074-2+16
074-3+17
074-4+18
074-5+19
074-6+20
074-7+21
CCB
CCV
1
2.00
0.50
1.0
1.0
0.25
0.10
2.00
2085
0.025
0 592
0.122
1.185
1.170
0236
-0.028
0.233
0.089
1.394
0.234
0.613
0.559
1 209
0.355
0.002
2078
0.010
0.001
0.019
-0.013
0.001
-0008
-0.011
0.006
-0028
-0 009
-0.007
0.017
0.018
0.001
-0004
-0003
0002
0002
2.075
0.024
0.574
0.136
1.184
1.178
0.247
-0.034
0.261
0 098
1.401
0.217
0595
0558
1.213
0358
0.000
2076
1.0
1.0
1.0
• .0
1.0
• .0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
104
0.024
115
105
0.5
4.4
-0.034
104
98
0.000
104
0.136
1.401
0.217
0.595
1.213
0.358
0.136
1.401
0.217
0.595
0.558
1.213
0.358
90-110%R)
20XMDL)
<10%DIFF)
(< MDL)
(90-110%R)
(90-110%R)
(< MDL)
( 90-110%R )
-------
Method Name: NI
Method Description: Nickel
Date: 02/10/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni Seq. No.: 24
Sample ID: Calib Blank
Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 71
Results Data Set:
AS Loc.
Date: 02/10/2006
Repl SampleConc StndCo
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
. ====:
nc BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.096
0.001 0.098
0 000
\J , \J \J \J
0.001
745.34
Bkgnd Time
Area
0.007 10:15:47
0.007 10:15:49
0.007 10:15:51
Element: Ni Seq. No.: 25
Sample ID: Calib Blank
AS Loc.
SampleConc StndConc
mg/L mg/L
Repl
#
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 26
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
576.54
==—===— ===:==:—=—=====
Bkgnd Time
Area
0.007 10:15:57
0.007 10:15:59
0.007 10:16:01
AS Loc.
Date: 02/10/2006
OCUU^J-^
Repl
#
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
0.001
0.001
0.001
n nm
U . U \J J-
0.000
48.75
Peak
Area
0.098
0.098
0.098
Bkgnd
Area
0.007
0.007
0.006
Time
10:20
10:21
10:21
:59
:02
:04
Auto-zero performed.
Page 8
-------
Element: Ni Seq. No.: 27
AS Loc.
Date: 02/10/2006
Sample
Repl
ft
1
2
3
Mean:
SD :
ID: CAL STU
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.009
0.009
0.009
0 . 009
0. 000
*-. •-! /"\
Peak
Area
0.107
0.107
0.107
Bkgnd
Area
0.007
0.007
0.007
Time
10:21:53
10:21:55
10:21:57
O J\>-> LJ m
Standard number 1 applied. [0.25]
Correlation Coefficient:
0.9997
Slope: 0.0376
Element: Ni Seq. No.: 28
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
AS Loc. :
BlnkCorr
Signal
0.019
0. 020
0.021
n 090
0.001
3.10
Peak
Area
0.117
0.118
0.119
Date: 02/10/2006
Bkgnd
Area
0.007
0.007
0.006
Time
10:22:14
10:22:17
10:22:19
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9998
Slope: 0.0376
Element: Ni Seq. No.: 29
Sample ID: cal std 3
AS Loc.
Date: 02/10/2006
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9998
BlnkCorr
Signal
0.035
0.035
0.036
0.035
0.000
0.64
Peak
Area
0.133
0.133
0.134
Bkgnd
Area
0.007
0.007
0.007
Time
10:22:47
10:22:49
10:22:51
Slope: 0.0376
Element: Ni Seq. No.: 30
AS Loc.
Date: 02/10/2006
Sample iu: ca_L s L.U
Repl SampleConc
# mg/L
3
Mean:
SD :
%RSD:
i
StndConc
mg/L
Standard number 4 applied.
Correlation Coefficient: 0
BlnkCorr
Signal
0.078
0.078
0.077
0.078
0.000
0.52
[2.00]
.9997
Peak
Area
0.176
0.175
0.175
Bkgnd
Area
0.006
0.007
0.007
Slope:
Time
10:23:09
10:23:11
10:23:13
0.0376
Page 9
-------
Element: Ni Seq. No.:
31
AS Loc.
Date: 02/10/2006
O CULL^ J-<^ -l- J-' • •—".-•- —
Repl SampleConc
# mg/L
O
Z.
3
Mean:
SD :
%RSD:
StndConc
mg/L
Standard number 5 applied.
Correlation Coefficient: 0
BlnkCorr
Signal
0.185
0.183
0.184
0.184
0.001
0.39
[5.00]
.9995
Peak
Area
0.283
0.281
0.282
Bkgnd
Area
0.007
0.007
0.007
Slope:
Time
10:23:31
10:23:33
10:23:35
0.0371
Ni
0)
o
re
•s
o
0.20
0.15
0.10
0.05
Concentration
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.009
0.020
0.035
0.078
0.184
Correlation Coefficient: 0.99953
Entered
Concentration
(mg/L)
0.25
0.50
1.00
2.00
5.00
Slope: 0.
Calculated
Concentration
(mg/L)
0.000
0.2445
0.5372
0.9560
2.097
4.964
03705
Standard
Deviation
0.0004
0.0003
0.0006
0.0002
0.0004
0.0007
%RSD
48.7522
3.6976
3.0989
0.6443
0.5235
0.3890
Page 10
-------
No.: 32
AS LOG.
Date: 02/10/2006
Repl
#
1
o
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4 . 946
4 .976
4.987
4.969
0. 0213
0.43
StndConc
mg/L
4.946
4.976
4.987
4.969
0.0213
0.43
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.183 0.281 0.007 10:23:53
0 184 0.282 0.006 10:23:55
0.185 0.283 0.007 10:23:58
0.184
0.001
0.43
Element: Ni Seq. No.: 33
AS LOG.
Date: 02/10/2006
Repl
#
-\_
9
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2 . 127
2 . 138
2.121
2.129
0.0083
0.39
StndConc
mg/L
2.127
2.138
2.121
2.129
0.0083
0.39
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.079 0.177 0.007 10:24:17
0.079 0.177 0.007 10:24:19
0.079 0.177 0.007 10:24:21
0.079
0.000
0.39
Element: Ni Seq. No.: 34
AS LOG.:
Date: 02/10/2006
Repl
#
i
j-
S amp 1 e
2
Sample
3
Sample
Mean :
SD :
%RSD :
Sample
SampleConc
mg/L
9. 081
absorbance
9.065
absorbance
9. 104
absorbance
9.083
0.0195
0.21
absorbance
StndConc
mg/L
9.081
is greater
9.065
is greater
9.104
is greater
9.083
0.0195
0.21
is greater
BlnkCorr
Signal
0.336
than
0.
than
0.
than
0.
0.
0
than
that
336
that
337
that
337
001
.21
that
Peak
Area
0.434
of
0.
of
0.
of
of
the
434
the
435
the
the
Bkgnd
Area
0.007
Time
10:24:
highest standard.
0.007 10:24:
highest standard.
0.007 10:24:
highest
highest
46
48
50
standard.
standard.
Element: Ni Seq. No.: 35
Sample ID: ccb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0093
0.0052
-0.0161
-0.0067
0.0109
161.3
StndConc
mg/L
-0.0093
0.0052
-0.0161
-0.0067
0.0109
161.3
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
161.34
Peak
Area
0.098
0.098
0.097
Bkgnd
Area
0.007
0.006
0.007
Time
10:25:22
10:25:24
10:25:27
Page 11
-------
Elemen
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
t: Ni Seq
ID: -era^CTCf
SampleConc
mg/L
-0.0132
0.0144
-0.0120
-0. 0036
0.0156
431.9
. No.-: 36
3" ££^D
StndConc
mg/L
-0.0132
0.0144
-0.0120
-0.0036
0.0156
431.9
AS Lc
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.001
431.92
)c. :
Peak
Area
0.097
0.098
0.098
Udue; u.
Bkgnd
Area
0.007
0.006
0.007
£,/ J_ W / £* ^ *~> -+s
Time
10:25:37
10:25:39
10:25:42
Element: Ni Seq. No.: 37
Sample ID: cra-0.05
AS Loc.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
0.0510
0.0508
0.0667
0.0562
0.0091
16.23
StndConc
mg/L
0.0510
0.0508
0.0667
0.0562
0.0091
16.23
BlnkCorr
Signal
0. 002
0.002
0.002
0.002
0. 000
16.23
BlnkCorr Peak
Signal Area
0.002 0.100
0.002 0.100
0.002 0.100
0.002
0.000
16.23
Bkgnd Time
Area
0.006 10:26:01
0.007 10:26:03
0.006 10:26:05
Element
Sample
Repl
1
2
3
Mean:
SD :
%RSD:
—
: Ni Seq
ID: era- 0.1
SampleConc
mg/L
0.0996
0 . 0801
0.1147
0.0981
0.0174
17.70
. No. : 38
StndConc
mg/L
0.0996
0.1147
0.0981
0.0174
17.70
AS
BlnkCorr
Signal
0.004
fl 003
0.004
0.004
0.001
17.70
Loc. :
Peak
Area
0.102
0 101
0.102
Date:
Bkgnd
Area
0.007
0.008
0.007
02/10/2006
Time
10:26:21
10:26:23
10:26:25
No.: 39
AS Loc.
Date: 02/10/2006
O cUU£J -L C
Repl
#
1
2
3
Mean:
SD :
%RSD:
j_ *_j , \~-\^*^
SampleConc
mg/L
0.0014
-0.0093
-0.0098
-0.0059
0.0063
107.0
StndConc
mg/L
0.0014
-0.0093
-0.0098
-0.0059
0.0063
107.0
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
107.03
Peak
Area
0.098
0.098
0.098
Bkgnd
Area
0.006
0.007
0.006
T
10
10
10
ime
:26:
:26:
:26:
44
47
49
Page 12
-------
Element: Ni Seq. No.: 40
AS LOG.
Date: 02/10/2006
sampj-e
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0239
0.0371
0.0285
0.0298
0.0067
22.44
StndConc
mg/L
0.0239
0.0371
0.0285
0.0298
0.0067
22.44
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
22.44
Peak
Area
0.099
0.099
0.099
Bkgnd
Area
0.007
0.006
0.007
Time
10:27:23
10:27:25
10:27:27
===============
Element: Ni Seq. No.: 41
AS LOG.
•DdUlJJ-Lc;
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.988
1.962
1.990
1.980
0.0153
0.77
StndConc
mg/L
1.988
1.962
1.990
1.980
0.0153
0.77
BlnkCorr
Signal
0.074
0.073
0.074
0.073
0.001
0.77
Peak
Area
0.172
0.171
0.172
Bkgnd
Area
0.007
0.007
0.007
Time
10:27:
10:28:
10:28:
59
01
03
=:—===:===:= =====:::==::::::
Element: Ni Seq. No.: 42
Sample ID: ccb
AS Loc.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0176
0.0160
-0.0058
0.0093
0.0131
141.4
StndConc
mg/L
0.0176
0.0160
-0.0058
0.0093
0.0131
141.4
BlnkCorr
Signal
0.001
0.001
0.000
0.000
0.000
141.42
Peak
Area
0.099
0.099
0.098
Bkgnd Time
Area
0.006 10:28:26
0.006 10:28:28
0.007 10:28:30
No.: 43
AS Loc.
Date: 02/10/2006
hJcu.LL£^-i- ^-
Repl
#
i
J-
0
£*
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2 . 192
2 . 213
2.199
2.201
0.0111
0.50
StndConc
mg/L
2.192
2.213
2.199
2.201
0.0111
0.50
BlnkCorr Peak
Signal Area
0.081 0.179
0.082 0.180
0.081 0.179
0.082
0.000
0.50
Bkgnd Time
Area
0.006 10:28:47
0.007 10:28:49
0.007 10:28:52
Page 13
-------
Element: Ni Seq. No.: 44
AS LOG.
Date: 02/10/2006
Repl
#
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0. 0107
-0.0087
0.0010
-0.0061
0.0063
102.3
StndConc
mg/L
-0.0107
-0.0087
0.0010
-0.0061
0.0063
102.3
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.000 0.098 0.007 10:29:21
0 000 0.098 0.007 10:29:23
0.000 0.098 0.007 10:29:26
0.000
0.000
102.32
No.: 45
AS LOG.
Date: 02/10/2006
Repl
#
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.7790
0.
0.
0.
0.
2898
2819
2836
0056
1.98
StndConc
mg/L
0.2790
0
0
0
0
.2898
.2819
.2836
.0056
1.98
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.010 0.108 0.007 10:29:45
0
0
0
0
Oil 0.109 0.007 10:29:4/
.010 0.108 0.007 10:29:49
.011
.000
1.98
Element: Ni Seq. No.: 46
AS LOG.
Date: 02/10/2006
Repl
#
1
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0042
n nn4 Q
-0.0055
-0.0049
0.0006
13.01
StndConc
mg/L
-0.0042
0 0049
-0.0055
-0.0049
0.0006
13.01
BlnkCorr
Signal
0.000
0. 000
0.000
0.000
0.000
13.01
Peak
Area
0.098
0.098
0.098
Bkgnd
Area
0.007
0.007
0.007
Time
10:30:
10:30:
10:30:
10
12
14
Element: Ni Seq. No.: 47
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0812
0. 0508
0.0508
0.0609
0.0175
28.73
StndConc
mg/L
0.0812
0.0508
0.0508
0.0609
0.0175
28.73
BlnkCorr Peak
Signal Area
0.003 0.101
0.002 0.100
0.002 0.100
0.002
0.001
28.73
Bkgnd Time
Area
0.006 10:30:34
0.007 10:30:36
0.007 10:30:39
Page 14
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0025
3 0.0052
Mean: 0.0057
SD : 0.0035
%RSD: 61.08
Element: Ni Seq.
Sample ID: 218-4
Repl SampleConc
# mg/L
1 0.6766
2 0.6721
3 0.6801
Mean: 0.6763
SD : 0.0040
%RSD: 0.59
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0073
o n m 1 1
3 -0.0044
Mean: -0.0076
SD : 0.0033
%RSD: 44.18
Element: Ni Seq
Sample ID: 218-5
Repl SampleConc
# mg/L
1 0.1360
2 0.1481
3 0.1467
Mean: 0.1436
SD : 0.0066
%RSD: 4.60
No. : 48
StndConc
mg/L
0.0025
0.0093
0.0052
0.0057
0.0035
61.08
No.: 49
StndConc
mg/L
0.6766
0.6721
0.6801
0.6763
0.0040
0.59
. No. : 50
StndConc
mg/L
-0.0073
-0 0111
-0.0044
-0.0076
0.0033
44.18
. No. : 51
StndConc
mg/L
0.1360
0.1481
0.1467
0.1436
0.0066
4.60
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
61.08
AS Loc. :
BlnkCorr Peak
Signal Area
0.025 0.123
0.025 0.123
0.025 0.123
0.025
0.000
0.59
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
44.18
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.103
0.005 0.103
0.005 0.103
0.005
0.000
4.60
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:30:58
0.006 10:31:00
0.007 10:31:02
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:31:19
0.007 10:31:22
0.007 10:31:24
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:31:46
0.007 10:31:48
0.007 10:31:51
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:32:10
0.006 10:32:12
0.006 10:32:14
Page 15
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0095
2 0.0095
3 0.0131
Mean: 0.0107
SD : 0.0021
%RSD: 19.46
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0035
2 0.0037
3 -0.0035
Mean: 0.0013
SD : 0.0041
%RSD: 325.9
Element: Ni Seq
Sample ID: ccv-0.2!
Repl SampleConc
# mg/L
1 0.2678
2 0.2337
3 0.2443
Mean: 0.2486
SD : 0.0175
%RSD: 7.02
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0202
2 -0.0019
3 0.0081
Mean: 0.0088
SD : 0.0110
%RSD: 125.5
No.: 52
StndConc
mg/L
0.0095
0.0095
0.0131
0.0107
0.0021
19.46
No.: 53
StndConc
mg/L
0.0035
0.0037
-0.0035
0.0013
0.0041
325.9
. No. : 54
StndConc
mg/L
0.2678
0.2443
0.2486
0.0175
7.02
. No.: 55
StndConc
mg/L
0.0202
-0.0019
0.0081
0.0088
0.0110
125.5
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
19.46
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
325.87
AS Loc. :
BlnkCorr Peak
Signal Area
0.010 0.108
0 009 0 107
0.009 0.107
0.009
0.001
7.02
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.099
0.000 0.098
0.000 0.098
0.000
0.000
125.54
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:32:39
0.007 10:32:41
0.006 10:32:44
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:32:54
0.007 10:32:56
0.007 10:32:59
Date: 02/10/2006
Bkgnd Time
Area
0.006 10:33:22
0.007 10:33:25
0.007 10:33:27
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:33:57
0.007 10:33:59
0.007 10:34:01
Page 16
-------
Appendix E - 2
Laboratory QA/QC Data for Stack Testing Samples
-------
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 0.0582
2 0.0577
3 0.0534
Mean: 0.0564
SD : 0.0027
BRSD: 4.73
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0055
2 0.0156
3 -0.0094
Mean: 0.0039
SD : 0.0126
%RSD: 322.8
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 2.127
2 2.101
3 2.122
Mean: 2.117
SD : 0.0136
%RSD: 0.64
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0115
2 0.0158
3 0.0025
Mean: 0.0099
SD : 0.0068
%RSD: 68.64
. No. : 56
StndConc
mg/L
0.0582
0.0577
0.0534
0.0564
0.0027
4.73
. No. : 57
StndConc
mg/L
0.0055
0.0156
-0.0094
0.0039
0.0126
322.8
. No. : 58
StndConc
mg/L
2 .127
2 .101
2 .122
2 .117
0.0136
0.64
. No. : 59
StndConc
mg/L
0.0115
0.0158
0.0025
0.0099
0.0068
68.64
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
4 .73
AS
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
322.78
AS
BlnkCorr
Signal
0.079
0.078
0.079
0.078
0.001
0.64
AS
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
68.64
Loc. :
: Peak
Area
0.100
0.100
0.100
Loc. :
Peak
Area
0.098
0.099
0.098
Loc. :
Peak
Area
0.177
0.176
0.177
Loc. :
Peak
Area
0.098
0.099
0.098
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:34:20
0.007 10:34:23
0.007 10:34:25
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:34:43
0.006 10:34:45
0.007 10:34:47
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:35:00
0.007 10:35:02
0.007 10:35:05
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:35:19
0.006 10:35:22
0.007 10:35:24
-------
Element: Ni Seq
Sample ID: 072-1
Repl
#
1
2
3
Mean:
3D :
%RSD:
SampleConc
mg/L
0.0622
0.0656
0.0624
0.0634
0.0019
3.04
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0017
-0.0028
0.0007
-0.0013
0.0018
138.8
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 072-2
SampleConc
mg/L
0.2678
0.2550
0.2640
0.2623
0.0066
2 .51
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0005
0.0140
0.0050
0.0065
0.0069
106.1
. No. : 60
StndConc
mg/L
0.0622
0.0656
0.0624
0.0634
0.0019
3.04
. No. : 61
StndConc
mg/L
-0.0017
-0.0028
0.0007
-0.0013
0.0018
138.8
. No. : 62
StndConc
mg/L
0.2678
0.2550
0.2640
0.2623
0.0066
2 .51
. No. : 63
StndConc
mg/L
0.0005
0.0140
0.0050
0.0065
0.0069
106.1
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
3.04
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
138.75
Loc. :
Peak
Area
0.100
0.100
0.100
Loc. :
Peak
Area
0.098
0 .098
0.098
AS LOG. :
BlnkCorr
Signal
0.010
0.009
0.010
0.010
0.000
2.51
Peak
Area
0 .108
0.107
0.108
AS Loc. :
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
106.08
Peak
Area
0.098
0.098
0.098
Date:
Bkgnd
Area
0.007
0.007
0 .007
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
02/10/2006
Time
10:35:
10:35:
10:35:
48
51
53
02/10/2006
Time
10:36:
10:36:
10:36:
12
14
16
02/10/2006
Time
10:36:
10:36:
10:36:
34
36
38
Date: 02/10/2006
Bkgnd
Area
0.007
0.006
0.007
Time
10:36:
10:37:
10:37:
58
01
03
Page 18
-------
Element: Ni Seq.
Sample ID: 072-3
Repl SampleConc
# mg/L
1 0.0833
2 0.0761
3 0.0990
Mean: 0.0862
SD : 0.0117
%RSD: 13.60
Element: Ni Seq.
Sample ID : ccb
Repl SampleConc
# mg/L
1 -0.0010
2 -0.0071
3 -0.0004
Mean: -0.0028
SD : 0.0037
%RSD: 131.2
Element: Ni Seq.
Sample ID: 072-4
Repl SampleConc
ft mg/L
1 2.339
2 2.365
3 2.369
Mean: 2.357
SD : 0.0163
%RSD: 0.69
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0066
2 -0.0051
3 0.0099
Mean: -0.0006
SD : 0.0091
%RSD: 1512
No. : 64
StndConc
mg/L
0.0833
0.0761
0.0990
0.0862
0.0117
13 .60
No. : 65
StndConc
mg/L
-0.0010
-0.0071
-0.0004
-0.0028
0.0037
131.2
No . : 66
StndConc
mg/L
2.339
2 .365
2.369
2 .357
0.0163
0.69
No. : 67
StndConc
mg/L
-0.0066
-0.0051
0.0099
-0.0006
0.0091
1512
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.101
0 . 003 0 .101
0.004 0.102
0.003
0.000
13 .60
AS Loc. :
BlnkCorr Peak
Signal Area
0 . 000 0 .098
0.000 0.098
0.000 0.098
0 .000
0.000
131.18
AS Loc. :
BlnkCorr Peak
Signal Area
0.087 0.185
0.088 0.186
0.088 0.186
0.087
0.001
0.69
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
1511.65
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:37:21
0.007 10:37:23
0.006 10:37:25
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:37:44
0.007 10:37:47
0.007 10:37:49
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:38:07
0.007 10:38:09
0.007 10:38:11
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:38:32
0.007 10.-.38.-34
0.006 10:38:36
Page 19
-------
Element: Ni Seq.
Sample ID: 072-5
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1799
0.1817
0.1761
0.1792
0.0029
1.59
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID : ccb
SampleConc
mg/L
-0.0199
-0.0268
-0.0069
-0.0179
0.0101
56.43
: Ni Seq .
ID: ccb
SampleConc
mg/L
-0.0177
-0.0264
-0.0264
-0.0235
0.0050
21.26
: Ni Seq.
ID: ccv-1
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.9524
0.9413
0.9532
0.9490
0.0067
0.70
. No . : 68
StndConc
mg/L
0.1799
0.1817
0.1761
0.1792
0.0029
1.59
No. : 69
StndConc
mg/L
-0.0199
-0.0268
-0.0069
-0.0179
0.0101
56.43
No.: 70
StndConc
mg/L
-0.0177
-0.0264
-0.0264
-0.0235
0.0050
21.26
No. : 71
StndConc
mg/L
0.9524
0.9413
0.9532
0.9490
0.0067
0.70
AS
Loc. :
BlnkCorr Peak
Signal
0.007
0.007
0.007
0.007
0.000
1.59
AS
BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.000
56.43
AS
BlnkCorr
Signal
-0.001
-0.001
-0 .001
-0.001
0.000
21.26
AS
BlnkCorr
Signal
0.035
0.035
0.035
0.035
0.000
0.70
Area
0 .105
0.105
0.104
Loc. :
Peak
Area
0.097
0.097
0.098
Loc. :
Peak
Area
0.097
0.097
0.097
Loc. :
Peak
Area
0.133
0 .133
0.133
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0 .007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
02/10/2006
Time
10:38:
10:38:
10:38:
51
53
55
02/10/2006
Time
10:39:
10:39:
10:39:
18
21
23
02/10/2006
Time
10:39:
10:39:
10:39:
45
47
49
02/10/2006
Time
10:41:
10:41:
10:41:
17
19
21
Page 20
-------
Element: Ni Seq. No.: 72
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0007 0.0007
2 -0.0042 -0.0042
3 -0.0136 -0.0136
Mean: -0.0057 -0.0057
SD : 0.0072 0.0072
%RSD: 126.8 126.8
Element: Ni Seq. No.: 73
Sample ID: Irb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0070 0.0070
2 0.0279 0.0279
3 0.0335 0.0335
Mean: 0.0228 0.0228
SD : 0.0140 0.0140
%RSD: 61.34 61.34
Element: Ni Seq. No.: 74
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0051 -0.0051
2 -0.0022 -0.0022
3 -0.0067 -0.0067
Mean: -0.0047 -0.0047
SD : 0.0023 0.0023
%RSD: 48.70 48.70
Element: Ni Seq. No.: 75
Sample ID: Ifb
Repl SampleConc StndConc
# mg/L mg/L
1 1.071 1.071
2 1.079 1.079
3 1 . 077 1 . 077
Mean: 1.076 1.076
SD : 0.0041 0.0041
%RSD: 0.38 0.38
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
-0.001 0.097
0.000
0.000
126.80
AS Loc, :
BlnkCorr Peak
Signal Area
0. 000 0 . 098
0.001 0.099
0.001 0.099
0.001
0.001
61.34
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
48.70
AS Loc. :
BlnkCorr Peak
Signal Area
0.040 0.138
0.040 0.138
0.040 0.138
0.040
0.000
0.38
Date: 02/10/2006
Bkgnd Time
Area
0.006 10:42:59
0.007 10:43:01
0.007 10:43:04
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:43:18
0.007 10:43:20
0.006 10:43:22
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:43:37
0.007 10:43:39
0.007 10:43:41
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:43:55
0.007 10:43:57
0.007 10:43:59
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
BRSD:
:: Ni Seq
ID: ccb
SampleConc
mg/L
0.0138
-0 .0013
0.0028
0.0051
0.0078
153.2
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
i
2
3
Mean:
SD :
%RSD:
ID: 074-8
SampleConc
mg/L
0.0568
0.0573
0.0595
0.0579
0.0014
2.48
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0387
-0.0199
-0.0255
-0.0280
0.0096
34 .37
: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0129
-0.0342
-0.0313
-0.0175
0.0264
150.8
. No. : 76
StndConc
mg/L
0.0138
-0.0013
0.0028
0.0051
0.0078
153.2
. No. : 77
StndConc
mg/L
0.0568
0.0573
0.0595
0.0579
0.0014
2.48
. No.: 78
StndConc
mg/L
-0.0387
-0.0199
-0.0255
-0.0280
0.0096
34.37
. No. : 79
StndConc
mg/L
0.0129
-0.0342
-0.0313
-0.0175
0.0264
150.8
AS
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
153.21
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
2 .48
Loc. :
Peak
Area
0.098
0.098
0.098
Loc. :
Peak
Area
0.100
0 .100
0.100
AS Loc. :
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
34.37
Peak
Area
0.097
0.097
0.097
AS Loc. :
BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.001
150.81
Peak
Area
0.098
0 .097
0.097
Date: 02/10/2006
Bkgnd Time
Area
0.006 10:44:20
0.006 10:44:22
0.007 10:44:24
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:44:40
0.007 10:44:42
0.007 10:44:45
Date: 02/10/2006
Bkgnd Time
Area
0.007 10:52:21
0.007 10:52:23
0.007 10:52:25
Date: 02/10/2006
Bkgnd Time
Area
0.005 10:52:34
0.007 10:52:36
0.007 10:52:38
Page 22
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: Ifm
SampleConc
mg/L
1.115
1.109
1.116
1.113
0.0039
0.35
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID: ccb
SampleConc
mg/L
0.0045
-0.0253
-0.0035
-0.0081
0.0154
189.9
: Ni Seq
ID: dup Ifm
SampleConc
mg/L
1.025
1.024
1.040
1.030
0.0088
0.86
: Ni Seq.
ID: ccb
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
-0.0091
-0.0304
-0.0197
-0.0197
0.0106
53.96
. No. : 80
StndConc
mg/L
1.115
1.109
1.116
1.113
0.0039
0.35
. No. : 81
StndConc
mg/L
0.0045
-0.0253
-0.0035
-0.0081
0.0154
189.9
. No. : 82
StndConc
mg/L
1.025
1.024
1.040
1.030
0.0088
0.86
. No. : 83
StndConc
mg/L
-0.0091
-0.0304
-0.0197
-0.0197
0.0106
53.96
AS
BlnkCorr
Signal
0.041
0.041
0.041
0.041
0.000
0.35
AS
BlnkCorr
Signal
0.000
-0.001
0.000
0.000
0.001
189.87
AS
BlnkCorr
Signal
0.038
0.038
0.039
0.038
0.000
0.86
Loc. :
Peak
Area
0.139
0.139
0.139
Loc. :
Peak
Area
0.098
0.097
0.098
Loc. :
Peak
Area
0.136
0.136
0.136
AS Loc. :
BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
53.96
Peak
Area
0.098
0.097
0.097
Date:
Bkgnd
Area
0.007
0.007
02/10/2006
Time
10:52:
10:52:
0.007 10:53:
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.006
Date :
Bkgnd
Area
0.006
0.007
0.007
55
58
00
02/10/2006
Time
10:53:
10:53:
10:53:
13
15
17
02/10/2006
Time
10:53:
10:53:
10:53:
36
38
40
02/10/2006
Time
10:53:
10:53:
10:53:
54
56
58
-------
Element: Ni Seq
Sample ID: ser
Repl SarapleConc
# mg/L
1 0 , ZZ^d
2 0 i ZXSX
3 0.2360
Mean: 0.2262
SE1 : 0.0105
%RSD: 4.65
Element: Ni Seq
Sample ID: ccb
Repl SarapleConc
# mg/L
1 -0.0118
Z 0,0198
3 0.0037
Mean: 0,0039
Se ; 0-0158
%RSD: 403.9
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
•L -0.0205
Z -0.0187
3 -0 , Oil 9
Mean: -0.0190
se : 0,0013
% ~ s e> 6 ,8S
Element: Ni Seq
Sample e : ccv-0.5
Repl SampleConc
# mg/L
1 0.5081
2 0.5158
3 0.5046
Mean: 0.5095
SE1 : 0.0057
%RSD: 1.13
. No. : 84
StndConc
mg/L
0.2274
0.2151
0.2360
0.2262
0.0105
4.65
. No. : 85
StndConc
mg/L
-0,0118
0,0198
0.0037
0.0039
0.0158
403.9
. No. : 86
StndConc
mg/L
-o,ozos
-0.0187
-0.0179
-0. OT90
0.0013
6 ,8S
. No. : 87
StndConc
mg/L
0.5081
0,5158
0.5046
0.5095
0.0057
1.13
AS Loc. :
BlnkCorr Peak
Signal Area
0,008 0.106
0,008 0,106
0,009 0.107
0,008
0,000
4.65
AS Loc. :
BlnkCorr Peak
Signal Area
0,000 0,098
0,OOT 0,099
0,000 0,098
0,000
0.001
403.87
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.097
-0,001, 0.097
-0,001 0,091
- 0 , 001,
0.000
6,85
AS Loc. :
BlnkCorr Peak
Signal Area
0.019 0.117
0,OT9 0,117
0.019 0.117
0,0 19
0.000
1.13
Date: 02/10/2006
Bkgnd Time
Area
0,006 10:54:13
0,001 10:54:15
0,001 10:54:17
Date: 02/10/2006
Bkgnd Time
Area
0,001 10:57:50
0.006 10:57:52
0,001 10:57:55
Date: 02/10/2006
Bkgnd Time
Area
0,001 10:53:02
0.007 10:58:05
0,001 10:58:07
Date: 02/10/2006
Bkgnd Time
Area
0,001 10:58:32
0,001 10:58:34
0,001 10:58:36
-------
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0177
2 -0.0051
3 -0.0158
Mean: -0.0129
SD : 0.0068
%RSD: 52.77
Element : Ni Seq
Sample ID: 074-9
Repl SampleConc
# mg/L
1 0.0411
2 0.0310
3 0.0268
Mean: 0.0330
SD : 0.0073
%RSD: 22.24
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0197
2 -0.0183
3 -0.0333
Mean: -0.0238
SD : 0.0083
%RSD: 34.77
Element: Ni Seq.
Sample ID: 074-10
Repl SampleConc
# mg/L
1 0.0582
2 0.0570
3 0.0584
Mean: 0.0579
SD : 0.0008
%RSD: 1.36
. No. : 88
StndConc
mg/L
-0. 0177
-0.0051
-0.0158
-0.0129
0.0068
52.77
. No. : 89
StndConc
mg/L
0.0411
0.0310
0.0268
0.0330
0.0073
22.24
. No. : 90
StndConc
mg/L
-0.0197
-0.0183
-0.0333
-0.0238
0.0083
34 .77
No. : 91
StndConc
mg/L
0.0582
0.0570
0.0584
0.0579
0.0008
1.36
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.097
0.000 0.098
-0.001 0.097
0.000
0.000
52.77
AS Loc. :
BlnkCorr Peak
Signal Area
0 . 002 0 . 099
0.001 0.099
0.001 0.099
0.001
0.000
22.24
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.097
-0.001 0.097
-0.001 0.097
-0.001
0.000
34 .77
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.100
0.002 0.100
0.002 0.100
0.002
0.000
1.36
Date :
Bkgnd
Area
0.007
0.006
0.007
Date :
Bkgnd
Area
0.007
0.007
0.007
Date :
Bkgnd
Area
0.007
0.007
0.007
Date : '
Bkgnd
Area
0.007
0.007
0.007
02/10/2006
Time
10:58:57
10:59:00
10:59:02
02/10/2006
Time
10:59:23
10:59:25
10:59:27
02/10/2006
Time
10:59:47
10:59:49
10:59:51
02/10/2006
Time
11:00:09
11:00:11
11:00:13
-------
Element: Ni Seq. No.: 92
Sample ID: ccb
AS Loc.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0099
-0.0170
-0.0170
-0.0081
0.0155
192.6
StndConc
mg/L
0.0099
-0.0170
-0.0170
-0.0081
0.0155
192.6
BlnkCorr
Signal
0.
-0.
-0.
0.
0.
192
000
001
001
000
001
.59
Peak
Area
0.
0.
0.
.098
.097
.097
Bkgnd
Time
Area
0
0.
0.
.006
.007
.007
11
11
11
:00:
:00:
:00:
34
36
38
Element: Ni Seq. No.: 93
Sample ID: 074-11
AS Loc.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0227
0.0342
0.0364
0.0311
0.0074
23.71
StndConc
mg/L
0.0227
0.0342
0.0364
0.0311
0.0074
23.71
BlnkCorr Peak
Signal Area
0.001 0.099
0.001 0.099
0.001 0.099
0.001
0.000
23.71
Bkgnd Time
Area
0.007 11:00:54
0.007 11:00:57
0.007 11:00:59
Element: Ni Seq. No.: 94
Sample ID: ccb
AS Loc.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0455
.0259
.0419
.0378
.0105
27.72
St
ndConc
mg/L
-0
-0
-0
-0
0
.0455
.0259
.0419
.0378
.0105
27.72
BlnkCorr
Signal
-0.
-0.
-0.
-0.
0.
27
002
001
002
001
000
.72
Peak Bkgnd Time
Area Area
0.096 0.007 11:01:16
0.097 0.007 11:01:18
0.096 0.007 11:01:20
Element: Ni Seq. No.: 95
Sample ID: Sample
AS Loc.
Date: 02/10/2006
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 -0.0309 -0.0309 -0.001 0.097
Auto-zero performed.
Bkgnd Time
Area
0.007 11:01:45
Element: Ni Seq. No.: 96
Sample ID: ccb
AS Loc.
Date: 02/10/2006
~~
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0173
-0.0009
-0.0153
-0.0112
0.0090
80.11
StndConc
mg/L
-0.0173
-0.0009
-0.0153
-0.0112
0.0090
80.11
BlnkCorr
Signal
-o,
0.
-0.
0.
0.
80
001
000
001
000
000
.11
Peak
Area
0.
0.
0.
.096
.097
.096
Bkgnd
Time
Area
0.
0.
0.
.007
.007
.007
11:
11:
11:
02:
02:
02:
07
09
11
-------
Element : Ni Seq
Sample ID: 074-12
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0670
0.0644
0.0754
0.0690
0.0058
8.36
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0000
0.0061
0.0042
0.0034
0.0031
91.31
: Ni Seq.
ID: 074-13
SampleConc
mg/L
0.0958
0.1032
0.1032
0.1008
0.0043
4 .24
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0152
0.0029
0.0152
0.0010
0.0153
1584
. No. : 97
StndConc
mg/L
0.0670
0.0644
0.0754
0.0690
0.0058
8.36
. No.: 98
StndConc
mg/L
0.0000
0.0061
0.0042
0.0034
0.0031
91.31
. No. : 99
StndConc
mg/L
0.0958
0.1032
0.1032
0.1008
0.0043
4.24
No. : 100
StndConc
ing/L
-0.0152
0.0029
0.0152
0.0010
0.0153
1584
AS
BlnkCorr
Signal
0.002
0.002
0.003
0.003
0.000
8.36
AS
BlnkCorr
S ignal
0.000
0.000
0.000
0.000
0.000
91.31
AS
BlnkCorr
Signal
0.004
0.004
0.004
0.004
0.000
4.24
Loc . :
Peak
Area
0.099
0.099
0.100
Loc. :
Peak
Area
0.097
0.097
0.097
Loc. :
Peak
Area
0.100
0.101
0.101
AS Loc. :
BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
1584.50
Peak
Area
0.096
0.097
0.097
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
02/10/2006
Time
11:02:
11:02:
11:02:
36
38
41
02/10/2006
Time
0.007 11:03:
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
11:03:
11:03:
07
09
11
02/10/2006
Time
11:03:
11:03:
11:03:
26
28
30
02/10/2006
Time
11:03:
11:03:
11:03:
50
52
54
-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 074-14
SampleConc
mg/L
0.0729
0.0662
0.0861
0.0751
0.0101
13 .46
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0011
-0.0042
-0.0126
-0.0052
0.0069
132 .3
: Ni Seq.
ID: ccb
SampleConc
mg/L
-0.0061
-0.0022
0.0381
0.0099
0.0245
246 .4
: Ni Seq.
ID: ccv-2
SampleConc
mg/L
2 .106
2.062
2.087
2.085
0.0216
1.04
. No. : 101
StndConc
mg/L
0.0729
0.0662
0.0861
0.0751
0.0101
13.46
. No. : 102
StndConc
mg/L
0.0011
-0.0042
-0.0126
-0.0052
0.0069
132 .3
. No. : 103
StndConc
mg/L
-0.0061
-0.0022
0.0381
0.0099
0.0245
246 .4
. No. : 104
StndConc
mg/L
2.106
2.062
2.087
2.085
0.0216
1.04
AS
BlnkCorr
Signal
0.003
0.002
0.003
0.003
0.000
13 .46
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
132.25
Loc . :
Peak
Area
0.100
0.099
0.100
Loc. :
Peak
Area
0.097
0.097
0.096
AS Loc. :
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
246 .45
Peak
Area
0.097
0.097
0.098
AS Loc. :
BlnkCorr
Signal
0.078
0.076
0.077
0 . 077
0.001
1.04
Peak
Area
0.175
0.173
0.174
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.006
02/10/2006
Time
11:04:
11:04:
11:04:
25
27
29
02/10/2006
Time
11:04:
11:05:
11:05:
58
00
02
02/10/2006
Time
11:05:
11:05:
11:05:
35
37
40
Date: 02/10/2006
Bkgnd
Area
0.007
0.007
0.007
Time
11:06:
11:06:
11:06:
46
48
50
Page 28
-------
Elemeni
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
;: Ni Seq
ID: ccb
SampleConc
mg/L
0.0038
0.0002
-0.0004
0.0012
0.0023
187.5
;: Ni Seq.
ID: Irb
SampleConc
mg/L
0.0309
0.0150
0.0301
0.0253
0.0090
35.41
:: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0067
0.0220
0.0269
0.0185
0.0106
56.93
: Ni Seq.
ID: Ifb
SampleConc
mg/L
0.5973
0.5800
0.5991
0.5921
0.0106
1.78
. No. : 105
StndConc
mg/L
0.0038
0.0002
-0.0004
0.0012
0.0023
187.5
. No.: 106
StndConc
mg/L
0.0309
0.0150
0.0301
0.0253
0.0090
35.41
No.: 107
StndConc
mg/L
0.0067
0.0220
0.0269
0.0185
0.0106
56.93
No. : 108
StndConc
mg/L
0.5973
0.5800
0.5991
0.5921
0.0106
1.78
AS
BlnkCori
Signal
0.000
0.000
0.000
0.000
0.000
187.55
AS
BlnkCorz
Signal
0.001
0.001
0.001
0.001
0.000
35.41
AS
BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
56.93
AS
BlnkCorr
Signal
0.022
0.021
0.022
0.022
0.000
1.78
Loc. :
: Peak
Area
0.097
0.097
0.097
Loc. :
: Peak
Area
0.098
0.097
0.098
Loc. :
Peak
Area
0.097
0.098
0.098
Loc. :
Peak
Area
0.119
0.118
0.119
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:07:28
0.007 11:07:30
0.007 11:07:33
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:07:56
0.007 11:07:58
0.007 11:08:00
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:08:41
0.007 11:08:44
0.006 11:08:46
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:09:03
0.007 11:09:05
0.007 11:09:07
-------
Element: Ni Seq. No.: 109
Sample ID: ccb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD ;
%RSD:
SampleConc
rag/It
0.0202
0.0101
0.0181
0.0161
0.0053
33.00
: StndConc
mg/L
0.0202
0.0101
0.0181
0.0161
0.0053
33.00
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
33
001 0.098
000 0.097
001 0.097
001
000
.00
Bkgnd Time
Area
0.006 11:09:23
0.006 11:09:25
0.006 11:09:27
Element: Ni Seq. No.: 110
Sample ID: Ifb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
.6011
.6002
.5978
.5997
.0017
0.28
StndConc
mg/L
0
0
0
0
0
.6011
.6002
.5978
.5997
.0017
0.28
BlnkCorr
Signal
0.022
0.022
0.022
0.022
0.000
0.28
Peak
Area
0.
0.
0.
.119
.119
.119
Bkgnd
Time
Area
0.
0.
0.
.006
.006
.006
11
11
11
:09:
:09:
:09:
46
48
50
Element: Ni Seq. No.: Ill
Sample ID: ccb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0070
.0253
.0079
.0134
.0103
76.58
StndConc
mg/L
-0
-0
-0
-0
0
.0070
.0253
.0079
.0134
.0103
76.58
BlnkCorr Peak
Signal Area
0.
-0.
0.
0.
0.
76
000 0.097
001 0.096
000 0.097
000
000
.58
Bkgnd Time
Area
0 . 007 11: 10: 18
0.007 11:10:20
0.007 11:10:22
Element: Ni Seq. No.: 112
Sample ID: 074-1+15
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1152
0.1366
0 .1144
0.1221
0.0126
10.33
StndConc
mg/L
0
0
0
0
0
.1152
.1366
.1144
.1221
.0126
10.33
BlnkCorr
Signal
0.
0.
0.
0.
0.
10
004
005
004
005
000
.33
Peak
Area
0.
0.
0.
101
102
101
Bkgnd
Time
Area
0
0.
0.
.007
.006
.007
11:1
11:1
11:1
0:45
0:47
0:49
Page 30
-------
Element: Ni Seq. No.: 113
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0051 0.0051
2 -0.0013 -0.0013
3 0.0002 0.0002
Mean: 0.0013 0.0013
SD : 0.0033 0.0033
%RSD: 250.1 250.1
Element: Ni Seq. No.: 114
Sample ID: Ifm
Repl SampleConc StndConc
# mg/L mg/L
1 1.179 1.179
2 1.189 1.189
3 1.188 1.188
Mean: 1.185 1.185
SD : 0.0054 0.0054
%RSD: 0.46 0.46
Element: Ni Seq. No.: 115
Sample ID : ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0022 -0.0022
2 -0.0061 -0.0061
3 -0.0144 -0.0144
Mean: -0.0076 -0.0076
SD : 0.0063 0.0063
%RSD: 82.62 82.62
Element: Ni Seq. No.: 116
Sample ID: Ifm dup
Repl SampleConc StndConc
# mg/L mg/L
1 1.173 1.173
2 1.173 1.173
3 1.165 1.165
Mean: 1.170 1.170
SD : 0.0044 0.0044
%RSD: 0.38 0.38
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
250.08
AS
BlnkCorr
Signal
0.044
0. 044
0.044
0. 044
0.000
0.46
AS
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
82.62
AS
BlnkCorr
Signal
0.043
0.043
0.043
0.043
0.000
0.38
Loc. :
Peak
Area
0.097
0.097
0.097
Loc. :
Peak
Area
0.141
0 . 141
0.141
Loc. :
Peak
Area
0.097
0.097
0.096
Loc. :
Peak
Area
0.140
0.140
0.140
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:11:23
0.007 11:11:25
0.006 11:11:27
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:11:40
0.006 11:11:43
0.006 11:11:45
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:12:30
0.007 11:12:32
0.007 11:12:34
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:12:57
0.007 11:12:59
0.007 11:13:01
-------
Element : Ni Seq
Sample
Rep I
#
1
2
3
Mean:
SD ;
%RSD:
ID: ccb
SampleConc
mg/L
-0.0170
-0.0193
0.0040
-0.0108
0.0128
119.0
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ser
SampleConc
mg/L
0.2375
0.2289
0.2428
0.2364
0.0070
2.97
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0097
0.0227
-0. 0144
0.0060
0.0189
313.6
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0323
-0.0242
-0.0285
-0.0283
0.0041
14.34
.No.: 117
StndConc
mg/L
-0.0170
-0.0193
0.0040
-0.0108
0.0128
119.0
. No. : 118
StndConc
mg/L
0.2375
0.2289
0.2428
0.2364
0.0070
2.97
No. : 119
StndConc
mg/L
0.0097
0.0227
-0.0144
0.0060
0.0189
313.6
No. : 120
StndConc
mg/L
-0.0323
-0.0242
-0.0285
-0.0283
0.0041
14 . 34
AS
BlnkCorr
S ignal
-0.001
-0.001
0.000
0.000
0.000
119.03
AS
BlnkCorr
S ignal
0.009
0.008
0.009
0.009
0.000
2.97
AS
BlnkCorr
S ignal
0.000
0.001
-0.001
0.000
0.001
313.63
Loc. :
Peak
Area
0.096
0.096
0.097
Loc. :
Peak
Area
0.106
0.105
0.106
Loc. :
Peak
Area
0.097
0.098
0.096
AS Loc. :
BlnkCorr
S ignal
-0.001
-0.001
-0.001
-0.001
0.000
14 .34
Peak
Area
0.096
0.096
0.096
Date:
Bkgnd
Area
0.007
0.007
0.006
Date:
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.006
0.006
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
02/10/2006
Time
11:13:
11:13:
11:13:
33
35
38
02/10/2006
Time
11:13:
11:13:
11:13:
53
55
57
02/10/2006
Time
11:14:
11:14:
11:14:
11
14
16
02/10/2006
Time
11:14:
11:14:
11:14:
51
53
55
-------
Element: Ni Seq. No. : 121
Sample ID: ccv-0.25
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.2328
0.2453
0.2199
0.2327
0 . 0127
5.47
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID: ccb
SampleConc
mg/L
-0.0256
-0.0292
-0.0179
-0.0242
0.0058
23.96
: Ni Seq.
ID: ccv-0.1
SampleConc
mg/L
0.0996
0.0917
0.0904
0.0939
0.0050
5.31
: Ni Seq.
ID : ccb
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
-0.0415
-0.0305
-0.0226
-0.0315
0.0095
30.19
StndConc
mg/L
0.2328
0.2453
0.2199
0.2327
0.0127
5.47
. No. : 122
StndConc
mg/L
-0.0256
-0.0292
-0.0179
-0.0242
0.0058
23.96
No. : 123
StndConc
mg/L
0.0996
0.0917
0.0904
0.0939
0.0050
5.31
No. : 124
StndConc
mg/L
-0.0415
-0.0305
-0.0226
-0.0315
0.0095
30.19
AS
BlnkCorr
S ignal
0.009
0.009
0.008
0.009
0.000
5.47
AS
BlnkCorr
S ignal
-0.001
-0.001
-0.001
-0.001
0.000
23.96
AS
BlnkCorr
S ignal
0.004
0.003
0.003
0.003
0.000
5.31
Loc. :
Peak
Area
0.105
0.106
0.105
Loc. :
Peak
Area
0.096
0.096
0.096
Loc. :
Peak
Area
0.101
0.100
0.100
AS Loc. :
BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
30.19
Peak
Area
0.095
0.096
0.096
Date:
Bkgnd
Area
0.006
0.006
0.007
Date :
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.006
0.007
0.007
Date:
Bkgnd
Area
0.007
0.007
0.007
02/10/2006
Time
11:15:
11:15:
11:15:
15
17
19
02/10/2006
Time
11:15:
11:15:
11:15:
37
39
41
02/10/2006
Time
11:15:
11:15:
11:16:
57
59
01
02/10/2006
Time
11:16:
11:16:
11:16:
15
17
20
-------
Element: Ni Seq. No.: 125
Sample ID : ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0285 -0.0285
2 -0.0227 -0.0227
3 -0.0395 -0.0395
Mean: -0.0303 -0.0303
SD : 0.0085 0.0085
%RSD: 28.18 28.18
Element: Ni Seq. No. : 126
Sample ID: Sample
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0197 -0.0197
Auto- zero performed.
Element: Ni Seq. No. : 127
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0123 -0.0123
2 -0.0020 -0.0020
3 0.0058 0.0058
Mean: -0.0028 -0.0028
SD : 0.0091 0.0091
%RSD: 320.2 320.2
Element: Ni Seq. No. : 128
Sample ID: Sample
Repl SampleConc StndConc
# mg/L mg/L
1 0.0072 0.0072
Auto- zero performed.
Element: Ni Seq. No.: 129
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0106 -0.0106
2 -0.0090 -0.0090
3 -0.0123 -0.0123
Mean: -0.0106 -0.0106
SD : 0.0016 0.0016
%RSD: 15.25 15.25
AS LOG. :
BlnkCorr Peak
Signal Area
-0.001 0.096
-0.001 0.096
-0.001 0.095
-0.001
0.000
28.18
AS Loc. :
BlnkCorr Peak
S ignal Area
-0.001 0.096
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
320.19
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.096
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
15.25
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:28
0.007 11:16:30
0.007 11:16:32
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:36
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:44
0.007 11:16:46
0.007 11:16:48
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:52
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:58
0.007 11:17:00
0.007 11:17:02
-------
Element : Ni Seq
Sample ID: ccv-0.1
Repl SampleConc
# mg/L
1 0.1067
2 0.1085
3 0.0893
Mean: 0.1015
SD : 0.0106
%RSD: 10.41
Element : Ni Seq
Sample ID : ccb
Repl SampleConc
# mg/L
1 -0.0125
2 -0.0038
3 -0.0056
Mean: -0.0073
SD : 0.0046
%RSD: 62.79
Element: Ni Seq.
Sample ID: 074-2+K
Repl SampleConc
# mg/L
1 1.411
2 1.386
3 1.397
Mean: 1.398
SD : 0.0126
%RSD: 0.90
Element: Ni Seq.
Sample ID : ccb
Repl SampleConc
# mg/L
1 0.0063
2 0.0179
3 0.0265
Mean: 0.0169
SD : 0.0101
%RSD: 59.99
. No.: 130 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.1067 0.004 0.100
0.1085 0.004 0.100
0.0893 0.003 0.100
0.1015 0.004
0.0106 0.000
10.41 10.41
. No. : 131 AS Loc. :
StndConc 'BlnkCorr Peak
mg/L Signal Area
-0.0125 0.000 0.096
-0.0038 0.000 0.096
-0.0056 0.000 0.096
-0.0073 0.000
0.0046 0.000
62.79 62.79
. No. : 132 AS Loc. :
StndConc BlnkCorr Peak
mg/L Signal Area
1.411 0.052 0.149
1.386 0.051 0.148
1.397 0.052 0.148
1.398 0.052
0.0126 0.000
0.90 0.90
. No. : 133 AS Loc. :
StndConc BlnkCorr Peak
mg/L Signal Area
0.0063 0.000 0.097
0.0179 0.001 0.097
0.0265 0.001 0.097
0.0169 0.001
0.0101 0.000
59.99 59.99
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:17:20
0.007 11:17:23
0.007 11:17:25
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:17:39
0.007 11:17:41
0.007 11:17:43
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:17:58
0.007 11:18:01
0.006 11:18:03
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:19:08
0.007 11:19:10
0.006 11:19:12
-------
Element: Ni Seq. No.: 134
Sample ID: 074-3+17
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.2393
0.2307
0.2307
0.2336
0.0050
2.14
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0 . 0217
0.0168
0.0141
0.0175
0.0038
21.94
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
0.2393
0.2307
0.2307
0.2336
0.0050
2.14
. No. : 135
StndConc
mg/L
0.0217
0.0168
0.0141
0.0175
0.0038
21.94
No. : 136
AS
BlnkCorr
S ignal
0.009
0.009
0.009
0.009
0.000
2.14
AS
BlnkCorr
S ignal
0.001
0.001
0.001
0.001
0.000
21.94
Loc. :
Peak
Area
0.105
0.105
0.105
Loc. :
Peak
Area
0.097
0.097
0.097
AS Loc. :
Date:
Bkgnd
Area
02/10/2006
Time
0.007 11:19:
0.007
11:19:
0.007 11:19:
Date:
Bkgnd
Area
0.006
0.007
0.007
Date:
33
35
37
02/10/2006
Time
11:19:
11:19:
11:19:
53
55
57
02/10/2006
ID: 074-4+18
SampleConc
mg/L
0.6003
0.5994
0.6388
0.6129
0.0225
3.67
: Ni Seq.
ID : ccb
SampleConc
mg/L
0.0188
-0.0108
-0.0038
0.0014
0.0155
1118
StndConc
mg/L
0.6003
0.5994
0.6388
0.6129
0.0225
3.67
No. : 137
StndConc
mg/L
0.0188
-0.0108
-0.0038
0.0014
0.0155
1118
BlnkCorr
Signal
0.022
0.022
0.024
0.023
0.001
3.67
Peak
Area
0.119
0.119
0.120
AS Loc. :
BlnkCorr
S ignal
0.001
0.000
0.000
0.000
0.001
1117 .51
Peak
Area
0.097
0.096
0.096
Bkgnd
Area
0.007
0.007
0.005
Date:
Bkgnd
Area
0.006
0.007
0.007
Time
11:20:
11:20:
11:20:
13
15
18
02/10/2006
Time
11:20:
11:20:
11:20:
47
49
51
Page 36
-------
Element: Ni Seq. No.: 138
Sample ID: 074-5+19
Repl SampleConc StndConc
# mg/L mg/L
1 0.5594 0.5594
2 0.5527 0.5527
3 0.5651 0.5651
Mean: 0.5591 0.5591
SD : 0.0062 0.0062
%RSD: 1.11 1.11
Element: Ni Seq. No.: 139
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0054 -0.0054
2 -0.0042 -0.0042
3 -0.0020 -0.0020
Mean: -0.0039 -0.0039
SD : 0.0017 0.0017
%RSD: 45.04 45.04
Element: Ni Seq. No.: 140
Sample ID: 074-6+20
Repl SampleConc StndConc
# mg/L mg/L
1 1.212 1.212
2 1.220 1.220
3 1.196 1.196
Mean: 1.209 1.209
SD : 0.0124 0.0124
%RSD: 1.03 1.03
Element: Ni Seq. No.: 141
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0087 -0.0087
2 0.0005 0.0005
3 -0.0013 -0.0013
Mean: -0.0031 -0.0031
SD : 0.0049 0.0049
%RSD: 155.9 155.9
AS Loc. :
BlnkCorr Peak
Signal Area
0.021 0.117
0.020 0.117
0.021 0.117
0.021
0.000
1.11
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
45.04
AS Loc. :
BlnkCorr Peak
Signal Area
0.045 0.141
0.045 0.142
0.044 0.141
0.045
0.000
1.03
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
155.91
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:22:07
0.006 11:22:09
0.007 11:22:12
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:22:29
0.007 11:22:31
0.007 11:22:33
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:22:49
0.007 11:22:51
0.007 11:22:53
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:23:06
0.006 11:23:09
0.007 11:23:11
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
;: Ni Seq.
ID: 074-7+21
SampleConc
mg/L
0.3496
0.3574
0.3588
0.3553
0.0050
1.39
:: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0081
0.0040
-0.0058
0.0021
0.0071
338.8
: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0070
-0.0108
0.0103
0.0022
0.0114
525.0
: Ni Seq.
ID: ccv-2
SampleConc
mg/L
2.072
2.062
2.100
2.078
0.0199
0.96
No. : 142
StndConc
mg/L
0.3496
0.3574
0.3588
0.3553
0.0050
1.39
No. : 143
StndConc
mg/L
0.0081
0.0040
-0.0058
0.0021
0.0071
338.8
No.: 144
StndConc
mg/L
0.0070
-0.0108
0.0103
0.0022
0.0114
525.0
No. : 145
StndConc
mg/L
2.072
2.062
2.100
2.078
0.0199
0.96
AS
BlnkCorr
Signal
0.013
0.013
0.013
0.013
0.000
1.39
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
338.80
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
525.00
AS
BlnkCorr
Signal
0.077
0.076
0.078
0.077
0.001
0.96
Loc. :
Peak
Area
0.109
0.110
0.110
Loc. :
Peak
Area
0.097
0.097
0.096
Loc. :
Peak
Area
0.097
0.096
0.097
Loc. :
Peak
Area
0.173
0.173
0.174
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:23:27
0.006 11:23:29
0.006 11:23:31
Date: 02/10/2006
Bkgnd Time
Area
0.006 11:23:48
0.006 11:23:50
0.006 11:23:53
Date: 02/10/2006
Bkgnd Time
Area
0.005 11:25:05
0.006 11:25:07
0.006 11:25:09
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:25:22
0.007 11:25:24
0.006 11:25:26
-------
Element: Ni Seq. No. : 146
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
tng/L
-0
-0
-0
-0
0
.0170
,0283
.0148
.0200
.0073
36.29
StndConc
mg/L
-0
-0
-0
-0
0
.0170
.0283
.0148
.0200
.0073
36.29
AS LOG. :
BlnkCorr Peak
Signal Area
-0.
-0.
-0.
-0.
0.
36
001 0.096
001 0.095
001 0.096
001
000
.29
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:25:42
0.007 11:25:44
0.007 11:25:47
-------
1
tM
P rep Method : (check onJy one per page)
ICP/FLAA: -SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
iCP/FLAA: SW-846 3005A
ICP/FLAA: S W-846 301 5A MICROWAVE
GFAA: SM3030E
\
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) M ICROWAVE
OTHF.R:
OTHER-
MATRIX: (check only one per page)
DRINKING WATER
1
2
3
4
5
6
7
8
9
10
14
12
Set
Init'l
iM-
y
Set
date
Its
Set
time
S1J/&
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S\QA FORMS \FM-041 \R02\LK
Page 1 of 1
-------
Prep Method: (check only one Per
ICP/FLAA: SM3030 F, EPA 200.7'82
1CP/FLAA: EPA2QO's, SW-8463010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-8463005A
ICP/FLAA: SW-8463015A MICROWAVE
OTHER: -
GFAA: SM 3030 E -^
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER: :
MATRIX: (check only one per page)
DRINK
1
?
a
4
5
6
7
8
9
10
11
12
Set
Inifl
^
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Set
date
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Page 1 of 1
-------
PROJECT # 2006010214: METHOD 29 FOR NICKEL
8
9
10
11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19
SAMPLE
DESCRPTION
impinger
fitter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger , !>
"filter ; ,
prob&riflse '
RUN ID
Cond. 12:
RUN»1
Cond. 12:
RUN #2
Cond. 12:
RUN«3
BLANK
Cond. 11:
RUN #1
Cond. 11:
RUN 82
Cond. 11:
RUN #3
' MDL
PH
<2.0
<2.Q
<2,0
<2,0
<2.0
<2.0
<2,0
< 2-0
<2.Q
<2.0
<2.Q
<2.0
<2.0
<2.0
, ,
Sample
Fraction
(SF = SF*}
308
1 filter
98.0
316
1 filter
99.0
309
1 filter
98.0
304
1 filter
100.0
312
1 filter
96.0
312
1 filter
99.0
314
1 filter
980
,, 300\ ,
, 1, Wt^r ,
100,0
EVAP.
TO
20
NA
20
20 j
NA
20
20
Nft
20
20
NA
20
20
NA
20
20
NA
20
20
NA
70
'• A
/ S4"
20
REAGENTS
FOR DIG.
HN03 + H202
HF + HNO3
HF * HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 * H202
HF + HNO3
HF + HN03
HNO3 t- H2O2
HF » HNO3
HF + HNO3
HNO3 + H2O2
HF + HN03
HF * HNO3
HNO3 + H2O2
HF * HNO3
HF * MNO3
HNO3 + H2O2
HF + HN03
hF +• HN03
HN03 + H20?.'
HF + HN03 •
'HF*HN05
MICRO-
Dig. BY
8.3.4.2
8.3.12
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8,3.1.2
8.3.1.2
8.3.4.2
8.3.1,2
8.3.1.2
8.3.4 2
8.3.1.2
8.3.1-2
8.3.4.2
8.3.1 .2
8.3.1.2
8,3.4.2
831 2
83 1 2
83,1.2
83l"a'
, 03.13 .
Analytical
Fraction
(AF = AF4
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50-
, w s
Nf mg/L
( Ca1 or Ca2 )
< 0.074
1.792
< 0.074
4.409
< 0.074
1.949
< 0.074
0.170
0.083
1.845
< 0.074
0.522
0.104
0.306
, 0.D75> ,
. •" 3'$^ •
MG NI
IN INITIAL
SAMPLE
0.004
0.179
0.004
0.441
0.004
0.195
0.004
0.017
0.004
0.185
0.004
0.052
0.005
0.031
0,004*
O'.'oos;
TOTAL MG
PER RUN
0.183
0.445
0.199
0.021
0.189
0.056
0.036
0,011
10 Samples that read
-------
PROJECT # 2005110324: METHOD 29 FOR NICKEL
8
10
11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19
SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filler
probe rinse
impinger
filter
probe rinse
impinger
filter
orobe rinse
impinge^ '•>.
filter •' •'
• probe'rinse" •
RUN ID
Cond. 23:
TEST#1
Cond. 23:
TEST #2
Cond. 23:
TEST #3
BLANK
Cond. 25:
TEST #1
Cond. 25:
TESTS2
Cond. 25:
TEST S3
. MDE •'
C
PH
<2.0
<2.0
<2.0
<2.0
<2.0
<2.Q
•=2.0
<2.0
<2.0
<2.0
<2.0
<2,0
<2,0
<2.0
Sample
Fraction
(SF = SFA)
314
1 filter
97.0
318
1 filter
95.0
320
1 filter
96.0
302
1 filter
100.0
303
1 filter
96.0
299
1 filter
95.0
308
1 filter
98.0
300.;.,
« filter,. '
- '100.0.-:
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
23
";20 ';-
-''NA';
.20 i',;
REAGENTS
FOR DIG.
HNO3 + H2O2
HF * HN03
HF t HN03
HNO3 + H2O2
HF * HNO3
HF + HNO3
HNO3 * H2O2
HF + HN03
HF * HN03
HNO3 + H2O2
HF * HN03
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HN03 * H2O2
HF + HNO3
HF + HNO3
HNO3 * H2O2
HF + HNO3
HF + HNO3
HSl03*H20a
$ff f |JW3'?
-' Hf-1-HNOS '
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1,2
8.3. 1-2
8.3.4 2
8.3.1.2
8.3.1.2
6.3.4.2
8.3.1-2
8.3.1.2
8,3.4.2
8.3.1-2
8.31 2
""-a-,3.4.2
8.3:1,2
. 8,ii.?*
Analytical
Fraction
(AF = AFA)
50
100
50
100
50
100
50
100
50
100
50
100
50
100
• ^m , **
•/io6\/
N! mg/L
( Ca1 or C32 )
0.297
0.617
0.101
0.557
0.083
0.769
< 0.074
0.157
< 0.074
0.258
0.099
0.308
< 0.074
0.326
.-\ 0.075
-,0,075 V
MG Nl
IN INITIAL
SAMPLE
0.015
0.062
, 0.005
0.056
0.004
0.077
^ 0.004
0.016
\ 0.004
0.026
0.005
0.031
0.004
0.033
OJ004
0.008-
TOTAL MG
PER RUN
0.077
0.061
0.081
0.019
0.030
0.036
0.036
0,011
1 ° Samples that read
-------
QA/QC WORK SHEET for NICKEL
F" AA METHOD SOP MET-040
5100 AA
1 CURRENT COPY OF METHOD AVAILABLE IN WIN LAB.
2 INSTRUMENT SET-UP:
(For Specific Instrument settings, see current copy of method.)
Date:_
Analyst: _
2/2/2006
LK
(Mg/L)
IDL= 0.027
MDL- 0.075
RL a 0.10
LDRs 0.10 to s.o
3 CALIBRATION:
Cal Curve:
Corr. Coef:
Cone
0.25
O.SO .
7.00
2.00
5.00
xxx»«xxx
Abs
0.009
0019
0.036
0.077
0.182
Result
0.248
0.511
0.974
2.097
4.963
0.9996
% Rec.
993
102.2
97.4
104.9
99.3
4 STANDARD TRACEABILITY
QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM
Standard Name, Company, & Lot #
CPIQC-21Lot#05H062
CP1 QC-21 Lot* 05H062
CPIQC-19Lot#05F011
* 0.995)
s SAMPLE ANALYTICAL RUN
MAT-R1X
M29
M29
*'nf*
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
LFB
203-1 1
203-10+12
203-23
203-22+24
CCB
CCV
\jj-yo&rt ^2-
W^ SPK
DUP
SER DIL
324-4+6
324-7+9
324-10+12
CCB
CCV
324-13+15
324-16+18
r 324-19+21
214-1+3
214-4+6
CCB
CCV
214-7+9
214-10+12
214-13+15 v/
214-J6+1S
214-19+21
CCB
CCV
LRB
LFB
'324-2
STD CONG
5.00
2.00
0.05
0.10
1.00
0.25
I-I+3
1.0
1.0
2/10
0.50
1.00
2.00
1.00
READING
Mg/L
4.936
2.085
-0.013
0.032
0.068
0-004
1.107
0.074
0.122
0.091
2.176
0.020
0.270
0.644
1.622
1.604
0.340
0.559
0.781
0.157
0.004
0.516
0.247
0.277
0.308
1.786
4.415
-0.026
0.952
1.925
0.157
1.836
0.530
0.305
0.004
2.090
0.068
1.073
0.294
BLK
-0.013
-0.020
-0.020
0,006
0.009
-0.002
0.015
0.005
0.033
0.020
0.027
0.019
0.019
0.026
0.002
0.012
0.000
-0.019
0.004
-0.01 1
-0.031
-0.018
-0.006
0.006
-0.030
-0.026
-0.024
-0,013
-0.009
0.009
-0.001
0.006
0,004
0.007
-0.026
-0.003
RESULT
4.936
2.085
-0.013
0.045
0.089
0.025
1,101
0.065
0.124
0,076
2.171
-0.014
0.251
0.617
1.603
1.585
0.315
0.557
0.769
0.157
0,023
0.512
0,258
0,308
0.326
1.792
4,409
0.004
0.978
1.949
0,170
1.845
0.522
0,306
-0.002
2,086
0.060
1.099
0.297
DILI
1.0
1.0
1.0
1.0
1.0
1.0
1,0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
DIL 2
1.0
t.o
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC
RESULTS
99
104
-0.013
89
89
0.025
110
-0.014
100
99
11
1.9
0,023
102
0.004
98
-O.D02
104
0.060
115
Mg/L
0.065
0.124
0.076
2.171
0,617
0,557
0,769
0.157
0.258
0.308
0,326
1,792
4,409
1.949
0.170
1.845
0.522
0.306
0.297
REPT
mg/L
I
0.074
0.124
0.076
2.171
0.617
O.SS7
0.769
0.157
0.256
0.308
0.326
1.792
4.409
1.949
0.170
1.845
0.522
0.306
0.297
ICP
<«4 H
.ss.^3*/
(95-105%R)
(95-105%R)
(< MDL j
( 70-130%R }
(70-130%R)
(-= MOL )
( 80-12Q%R J
m
(< MDL)
(90-110%R)
( 80-120%R)
(<10 RPD, IF SA :• 20X MDL)
(< MDL 1
(90-110%R j
(
-------
QA/QC WORK SHEET for NICKEL p2
F'JVA METHOD SOP MET-040
5100 AA
Date:_
Analyst: _
2/2/2006
LK
5 SAMPLE ANALYTICAL RUN
MAT-RSX
M29
M29
M29
M29
M29
M29
M29
NI29
M29
M28
j
M29
M29
SAMPLE
SPK
DUP
SER OIL
GCB
ccv
324-5
324-8
324-11
324-14
DUP
CCB
CCV
324-17
324-20
214-2
214-5
214-8
CCB
CCV
214-11
DUP
214-14
214-17
214-20
CCB
CCV
STD CONG
1.0
1.0
2(10
0.25
2.00
0.50
0.25
READING
Mg/L
1.246
1.188
0.229
-0.014
0.229
0.087
0.090
0.068
0,072
0.065
-0.009
2.072
0.081
0.057
0.077
0.049
0.060
-0.045
0.471
0.022
0.104
0.049
0.034
0.066
0.009
0.233
BLK
-0.017
0.005
-0.003
0.005
-0.014
-0.014
0.007
0.003
-0.003
-0.039
0.016
-0.009
-0.018
-0.009
0.007
-0.017
0.005
-0.004
-0.045
-0.050
-0.004
-0,035
-0.024
-0.039
0.011
0.009
RESULT
1.263
1.183
0.232
-0.019
0.243
0.101
0.083
0.065
0.074
0.104
-0,025
2.081
0.099
0.066
0,071
0.066
0.056
-0.041
0,516
0.072
0.108
0.083
0.058
0.104
-0.002
0.224
DILI
1.0
1,0
1.0
1.0
1.0
1.0
1,0
1.0
1,0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
OIL 2
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1,0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC
RESULTS
97
6.6
8,3
-0.019
97
33.2
-0.025
104
1.4
-0.041
103
4Q.8
158
-0,002
90
Mg/L
0.101
0,083
0.065
0.074
0.099
0.066
0.071
0.066
0.056
0.072
0.083
0.058
0.104
REPT
mq/L
0.101
0.083
0.074
0.074
0.099
0.074
0.074
0.074
0.074
0.074
0,083
O.Q74
0.104
ICP
( 80-120%R )
(<10RPD, 1FSA>20XMDL)
(< MDL )
(SO-HOWR)
(<10RPD. IFSA: 20XMDL)
(< MDL }
{90-1105'oR )
MDL)
j 90-110%R)
(<10RPD, IF SA>20XMDL)
MOL)
( 90-1KW4R }
-------
Method Name: NI
Method Description: Nickel
Date: 02/02/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni Seq. No.: 265
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seg. No.: 266
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
~Mea n :
;D :
%RSD:
Auto- zero performed.
Element: Ni Seq. No. : 267
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
2
3
Mean:
SD :
%RSD:
Eiement: N i
hi^^ '"
Calibration Equation: Zero Intercept:
S lit Width: 0.20 nm
Energy : 7 1
Results Data Set:
AS LOG. :
BlnkCorr Peak
S ignal Area
-0.011 0.096
-0.011 0.096
-0.011 0.095
-0.011
0.000
1.39
AS LOG. :
BlnkCorr Peak
S ignal Area
0.000 0.096
0.001 0.096
0.001 0.097
0.001
0.001
61.54
AS LOG. :
BlnkCorr Peak
S ignal Area
-0.001 0.096
-0.001 0.096
-0.001 0.096
-0.001
0.000
14.29
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:18:41
0.006 10:18:43
0.006 10:18:45
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:18:53
0.006 10:18:55
0.005 10:18:57
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:19:01
0.006 10:19:03
0.006 10:19:05
1 ^
Linear
Auto-zero performed
Page 72
-------
Element: Ni Seq. No.: 268 AS Lo~. :
Sample ID: CAL STD
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.009 0.105
2 0.009 0.105
3 0.009 0.105
Mean: 0.009
SD : 0.000
BRSD: 2.79
Standard number 1 applied. [0.25]
Correlation Coefficient: 0.9985
Element: Ni Seq. No.: 269 AS Loc. :
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.018 0.114
2 0.019 0.115
3 0.019 0.115
Mean: 0 . 019
SD : 0.000
BRSD: 1.99
Standard number 2 applied. [0.50]
Correlation Coefficient : 0.9988
Element: Ni Seq. No.: 270 AS Loc.:
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.036 0.131
2 0.036 0.132
3 0.036 0.131
Mean: 0 . 036
SD : 0.000
%RSD: 0.44
Standard number 3 applied. [1.00]
Correlation Coefficient : 0.9992
Element: Ni Seq. No.: 271 AS Loc.:
Sample ID: cal std 4
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.077 0.172
2 0.076 0.172
3 0.078 0.174
Mean: 0 . 077
SD : 0.001
%RSD: 1.58
Standard number 4 applied. [2.00]
Correlation Coefficient : 0.9996
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:19:28
0.005 10:19:30
0.006 10:19:33
Slope: 0.0371
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:19:58
0.006 10:20:00
0.006 10:20:02
Slope: 0.0370
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:20:22
0.006 10:20:24
0.006 10:20:26
Slope: 0.0368
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:20:46
0.006 10:20:49
0.005 10:20:51
Slope: 0.0367
Page 73
-------
Element: Ni Seq. No.: 272
Sample ID: cal std 5
A5 Loc.
Date: 02/02/2006
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
«nc StndConc BlnkCorr Peak
mg/L Signal Area
0.182 0.278
0.183 0.279
0.181 0.277
0.182
0.001
0.50
• 5 applied. [5.00]
fficient: 0.9996
Bkgnd Time
Area
0.005 10:21:14
0.005 10:21:16
0.005 10:21:18
Slope: 0.0367
Ni
(B
•e
o
0.20
Q.1S
0.10
0.05
Concentration
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.009
0.019
0.036
0.077
0.182
Entered Calculated
icentration C
(mg/L)
0.25
0.50
1.00
2.00
5.00
:entratic
(mg/L)
0.000
0.2482
0.5112
0 . 9742
2.097
4.963
>n Standard
Deviat ion
0.0001
0.0003
0.0004
0.0002
0.0012
0.0009
%RSD
14.2878
2.7920
1.9883
0.4437
1.5791
0.4990
Correlation Coefficient: 0.99961 Slope:
0.03669
-------
Element: Ni Seq. No.: 273 AS
Sample ID: ccv-5
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 4.904 4.904 0.180
2 4.946 4.946 0.181
3 4.959 4.959 0.182
Mean: 4.936 4.936 0.181
SD : 0.0291 0.0291 0.001
%RSD: 0.59 0.59 0.59
Element: Ni Seq. No. : 274 AS
Sample ID: gcs-2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 2.092 2.092 0.077
2 2.073 2.073 0.076
3 2.091 2.091 0.077
Mean: 2.085 2.085 0.077
SD : 0.0109 0.0109 0.000
%RSD: 0.52 0.52 0.52
Element: Ni Seq. No.: 275 AS
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0067 -0.0067 0.000
2 -0.0213 -0.0213 -0.001
3 -0.0116 -0.0116 0.000
Mean: -0.0132 -0.0132 0.000
SD : 0.0074 0.0074 0.000
%RSD: 56.26 56.26 56.26
Element: Ni Seq. No.: 276 AS :
Sample ID: era- 0.05
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0464 0.0464 0.002
2 0.0112 0.0112 0.000
3 0.0371 0.0371 0.001
Mean; 0.0315 0.0315 0.001
SD : 0.0182 0.0182 0.001
%RSD: 57.81 57.81 57.81
Loc . :
Peak
Area
0.276
0.277
0.278
Loc. :
Peak
Area
0.172
0.172
0.172
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.097
0.096
0.097
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:21:32
0.005 10:21:34
0.005 10:21:36
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:22:04
0.007 10:22:06
0.006 10:22:08
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:24:48
0.006 10:24:50
0.006 10:24:52
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:25:22
0.007 10:25:24
0.006 10:25:26
Page 75
-------
Element: Ni Seq. No.: 277 AS
Sample ID: era- 0. 1
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0639 0.0639 0.002
2 0.0732 0.0732 0.003
3 0.0677 0.0677 0.002
Mean: 0.0682 0.0682 0.003
SD : 0.0047 0.0047 0.000
%RSD: 6.85 6.85 6.85
Element: Ni Seq. No.: 278 AS
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0193 -0.0193 -0.001
2 -0.0328 -0.0328 -0.001
3 -0.0091 -0.0091 0.000
Mean: -0.0204 -0.0204 -0.001
SD : 0.0119 0.0119 0.000
%RSD: 58.39 58.39 58.39
Element: Ni Seq. No.: 279 AS
Sample ID: Irb f+pr
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0026 0.0026 0.000
2 -0.0029 -0.0029 0.000
3 0.0128 0.0128 0.000
Mean: 0,0042 0.0042 0.000
SD : 0.0080 0.0000 0.000
%RSD: 189.8 189.8 189.78
Element: Ni Seq. No.: 280 AS :
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0092 0.0092 0.000
2 0.0001 0.0001 0.000
3 0.0084 0.0084 0.000
Mean: 0.0059 0.0059 0.000
SD : 0.0051 0.0051 0.000
%RSD: 85.93 85.93 85.93
Loc. :
Peak
Area
0.098
0.098
0.098
Loc. :
Peak
Area
0.095
0.094
0.095
Loc. :
Peak
Area
0.096
0.096
0.096
Loc. :
Peak
Area
0,096
0.096
0.096
Date: 02/02/2006
Bkgnd Time
Area
0.007 10:25:50
0.007 10:25:52
0.007 10:25:54
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:26:16
0.007 10:26:18
0.006 10:26:20
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:26:55
0.007 10:26:57
0.007 10:26:59
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:27:47
0.006 10:27:49
0.006 10:27:51
Page 76
-------
Element: Ni Seq. No.: 281
Sample ID: Ifb f+pr
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.063
1.093
1.107
1.088
0.0225
2.07
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0096
-0.0503
-0.0373
-0.0324
0.0208
64.12
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 203-11
SampleConc
mg/L
0.0640
0.0774
0.0792
0.0735
0.0083
11.23
Element: Ni Seq,
Sample
Repl
#
1
2
o
J
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0103
0.0088
-0.0045
-0.0020
0.0098
489.3
StndConc
mg/L
1.063
1.093
1.107
1.088
0.0225
2.07
.No.: 282
StndConc
mg/L
-0.0096
-0.0503
-0.0373
-0.0324
0.0208
64.12
. No . : 283
StndConc
mg/L
0.0640
0.0774
0.0792
0.0735
0.0083
11.23
. No. : 284
StndConc
mg/L
-0.0103
0.0088
-0.0045
-0.0020
0.0098
489.3
AS
BlnkCorr
Signal
0.039
0.040
0.041
0.040
0.001
2.07
AS
BlnkCorr
Signal
0.000
-0.002
-0.001
-0.001
0.001
64.12
AS
BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
11.23
Loc. :
Peak
Area
0.135
0.136
0.136
Loc. :
Peak
Area
0.095
0.094
0.094
Loc* :
Peak
Area
0.098
0.098
0.099
AS Loc. :
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
489.25
Peak
Area
0.095
0.096
0.095
Date:
Bkgnd
Area
0.007
0.006
0.006
Date:
Bkgnd
Area
0.006
0.008
0.007
Date:
Bkgnd
Area
0.006
0,005
0.005
Date:
Bkgnd
Area
0.006
0.005
0.006
02/02/2006
Time
10:29:10
10:29:12
10:29:14
02/02/2006
Time
10:31:33
10:31:36
10:31:38
02/02/2006
Time
10:32:05
10:32:07
10:32:09
02/02/2006
Time
10:32:26
10:32:28
10:32:30
-------
Element: Ni Seq
. No.: 285
AS
LOG. :
Date: 02/02/2006
Sample ID: 203-10+12
Repl SampleConc
# mg/L
1 0.1169
2 0.1113
3 0.1382
Mean: 0.1221
SD : 0.0142
%RSD: 11.65
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0295
2 -0.0191
3 -0.0291
Mean: -0.0259
SD : 0,0059
%RSD: 22.78
StndConc
mg/L
0.1169
0.1113
0.1382
0.1221
0.0142
11.65
No.: 286
StndConc
mg/L
-0.0295
-0.0191
-0.0291
-0.0259
0.0059
22.78
Element: Ni Seq. No.: 287
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0534
2 -0.0420
3 -0.0626
Mean: -0.0527
SD : 0.0103
%RSD: 19.58
Element: Ni Seq.
Sample ID: Sample
StndConc
mg/L
-0.0534
-0.0420
-0.0626
-0.0527
0,0103
19.58
No.: 288
BlnkCorr Peak
Signal
0.004
0.004
0.005
0.004
0.001
11.65
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
22.78
AS
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
19.58
AS
Area
0.100
0.100
0.101
LOG. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.094
0.094
0.093
Loc. :
Bkgnd Time
Area
0.006 10:32:50
0.006 10:32:52
0.005 10:32:54
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:33:13
0.006 10:33:15
0.006 10:.33:17
Date: 02/02/2006
Bkgnd Time
Area
0.007 10:33:35
0.007 10:33:37
0.007 10:33:39
Date: 02/02/2006
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0344 -0.0344
Auto-zero performed.
BlnkCorr Peak
Signal Area
-0.001 0.094
Bkgnd Time
Area
0.006 10:33:44
Element: Ni Seq. No.: 289
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0002
0.0341
0.0109
0.0151
0.0173
115.0
StndConc
ing/L
0.0002
0.0341
0.0109
0.0151
0.0173
115.0
AS Loc. :
BlnkCorr
Signal
o.ooo
0.001
0.000
0.001
0.001
114.98
Peak
Area
0.094
0.096
0.095
Date: 02/02/2006
Bkgnd
Area
0.006
0.005
0.006
Time
10:33:50
10:33:53
10:33:55
Page 78
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD !
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
: : Ni Seq
ID: 203-23
SampleConc
mg/L
0.0973
0.0826
0.0926
0.0908
0.0075
8.30
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0026
-0.0080
0.0259
0.0051
0.0182
356.6
. No. : 290
StndConc
mg/L
0.0973
0.0826
0.0926
0.0908
0.0075
8.30
. No.: 291
StndConc
mg/L
-0.0026
-0.0080
0.0259
0.0051
0.0182
356.6
: Ni Seq. No. : 292
ID: 203-22+24
SampleConc
mg/L
2.168
2.173
2.187
2.176
0.0097
0.45
: Ni Seq.
ID: ccb
Repl SampleConc
# mg/L
1 0.0355
2
3
Mean:
SD :
%RSD:
0.0153
0.0492
0.0334
0.0171
51.14
StndConc
mg/L
2.168
2.173
2.187
2.176
0.0097
0.45
No.: 293
StndConc
mg/L
0.0355
0.0153
0.0492
0.0334
0.0171
51.14
AS
LOG, :
BlnkCorr Peak
Signal Area
0.004 0.098
0.003
0.003
0.003
0.000
8.30
AS
0.097
0.098
Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.000
0.001
0.000
0.001
356.64
AS
BlnkCorr
Signal
0.080
0.080
0.080
0.080
0.000
0.45
AS
BlnkCorr
Signal
0.001
0.001
0.002
0.001
0.001
51.14
0.094
0.095
Loc. :
Peak
Area
0.174
0.174
0.175
Loc. :
Peak
Area
0.096
0.095
0.096
Dare:
02/02/2006
Bkgnd Time
Area
0.006 10:34:
0.007
0.006
Date:
Bkgnd
Area
0.006
0.007
0.005
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.005
0.006
0.005
10:34:
10:34:
12
14
17
02/02/2006
Time
10:34:
10:34:
10:34:
34
36
38
02/02/2006
Time
10:34:
10:34:
10:35:
56
58
00
mui—im~ij—mm^j^ — — — ^^ ^ ^^^_^_,^_^ ^_^_^_^_^_^
02/02/2006
Time
10:35:
10:35:
10:35:
49
51
54
Page 79
-------
Element: Ni Seq. No.: 294
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0149 0.0149
2 0.0288 0.0288
3 0.0155 0.0155
Mean: 0.0197 0.0197
SD : 0.0078 0.0078
%RSD: 39.73 39.73
Element: Ni Seq. No.: 295
Sample ID: ccv-0.25
Repl SampleConc StndConc
# mg/L mg/L
1 0,2672 0.2672
2 0.2671 0.2671
3 0.2767 0.2767
Mean: 0.2703 0.2703
SD : 0.0055 0.0055
%RSD: 2.04 2.04
Element: Ni Seq. No.: 296
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0215 0.0215
2 0.0465 0.0405
3 0.0193 0.0193
Mean: 0.0271 0.0271
SD : 0.0116 0.0116
%RSD: 42.91 42.91
Element: Ni Seq. No.: 297
Sample ID: *324-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.6406 0.6406
2 0.6395 0.6395
3 0.6519 0.6519
Mean: 0.6440 0.6440
SD : 0.0069 0.0069
%RSD: 1.07 1.07
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
39.73
AS
BlnkCorr
Signal
0.010
0.010
0.010
0.010
0.000
2.04
AS :
BlnkCorr
Signal
0.001
0. 001
0.001
0.001
0.000
42.91
AS :
BlnkCorr
Signal
0.024
0.023
0.024
0.024
0.000
1.07
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.104
0.104
0.105
Loc. :
Peak
Area
0.095
0.096
0.095
Loc. :
Peak
Area
0.118
0.118
0.118
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:36:00
0.006 10:36:03
0.006 10:36:05
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:36:29
0.005 10:36:32
0.005 10:36:34
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:36:53
0.005 10:36:56
0.005 10:36:58
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:37:30
0.006 10:37:32
0.006 10:37:34
Page 80
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0221
0.0175
0.0168
0.0188
0.0029
15.26
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 298
StndConc
mg/L
0.0221
0.0175
0.0168
0.0188
0.0029
15.26
. No. : 299
AS
BlnkCorr
S ignal
0.001
0.001
0.001
0.001
0.000
15.26
AS
Loc . :
Peak
Area
0.095
0.095
0.095
Loc. :
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
02/02/2006
Time
10:37:
10:37:
10:37:
53
55
57
02/02/2006
ID: S324-1+3
SampleConc
mg/L
1.596
1.621
1.650
1.622
0.0270
1.66
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0230
0,0171
0.0171
0.0191
0.0034
17.65
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
1.596
1.621
1.650
1.622
0.0270
1.66
. No.: 300
StndConc
mg/L
0.0230
0.0171
0.0171
0.0191
0.0034
17.65
. No. : 301
BlnkCorr
S ignal
0.059
0.059
0.061
0.060
0.001
1.66
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.65
Peak
Area
0.153
0.154
0.155
Loc. :
Peak
Area
0.095
0.095
0.095
AS Loc. :
Bkgnd
Area
0.006
0.006
Time
10:38:
10:38:
0.006 10:38:
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
18
20
23
02/02/2006
Time
10:38:
10:38:
10:38:
39
41
43
02/02/2006
ID: sd324-l+3
SampleConc
mg/L
1.596
1.613
1.602
1.604
0.0087
0.54
StndConc
mg/L
1.596
1.613
1.602
1,604
0.0087
0.54
BlnkCorr
Signal
0.059
0.059
0.059
0.059
0.000
0.54
Peak
Area
0.153
0.154
0.153
Bkgnd
Area
0.006
0.006
0.006
Time
10:39:
10:39:
10:39:
05
07
09
Page 81
-------
Element : Ni Seq
Sanple ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0408
0.0202
0.0162
0.0258
0.0132
51.25
. No.: 302
StndConc
mg/L
0.0408
0.0202
0.0162
0.0258
0.0132
51.25
Element: Ni Seq. No.: 303
Sample ID: ser324-l+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.3389
0.3537
0.3287
0.3404
0.0126
StndConc
mg/L
0.3389
0.3537
0.3287
0.3404
0.0126
3.69 3.69
Element: Ni Seq. No.: 304
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0217
0.0115
-0.0268
0.0021
0.0256
1202
: Ni Seq.
ID: 324-4+6
SampleConc
mg/L
0.5527
0.5795
0.5451
0.5591
0.0181
3.24
Stndeonc
mg/L
0.0217
0.0115
-0.0268
0.0021
0.0256
1202
No.: 305
StndConc
mg/L
0.5527
0.5795
0.5451
0.5591
0.0181
3.24
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
51.25
AS
BlnkCorr
Signal
0.012
0.013
0.012
0.012
0.000
Loc . :
Peak
Area
0.096
0.095
0.095
Loc. :
Peak
Area
0.107
0.107
0.106
Date:
Bkgnd
Area
0.005
0.006
0.007
Date:
Bkgnd
Area
0.007
0.006
0.007
02/02/2036
Time
10:39:
10:39:
10:39:
23
25
21
02/02/2006
Time
10:40:
10:40:
10:40:
00
02
04
3.69
AS Loc. :
BlnkCorr
Signal
0.001
0.000
-0.001
0.000
0.001
1202.00
Peak
Area
0.095
0.095
0.093
AS Loc. :
BlnkCorr
Signal
0.020
0.021
0.020
0.021
0.001
3.24
Peak
Area
0.115
0.116
0.114
Date:
Bkgnd
Area
0.006
0.006
0.008
02/02/2006
Time
10:40:
10:40:
10:40:
17
19
21
Date: 02/02/2006
Bkgnd
Area
0.006
0.006
0.006
Time
10:41:
10:41:
10:41:
12
14
16
Page 82
-------
Element: Ni Seq. No. : 306
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0071 -0.0071
2 0.0268 0.0268
3 0.0159 0.0159
Mean: 0.0118 0.0118
SD : 0.0173 0.0173
%RSD: 146.0 146.0
Element: Ni Seq. No.: 307
Sample ID: 324-7+9
Repl SampleConc StndConc
# mg/L mg/L
1 0.7695 0.7695
2 0.8041 0.8041
3 0.7678 0.7678
Mean: 0.7805 0.7805
SD : 0.0205 0.0205
%RSD: 2.62 2.62
Element: Ni Seq. No.: 308
Sample ID: ccb
Repl SampleConc StndConc
# rng/L mg/L
1 0.0288 0.0288
2 -0.0042 -0.0042
3 -0.0235 -0.0235
Mean: 0.0004 0.0004
SD : 0.0265 0.0265
%RSD: 7256 7256
Element: Ni Seq. No.: 309
Sample ID: 324-10+12
Repl SampleConc StndConc
# mg/L mg/L
1 0.1553 0.1553
2 0.1373 0.1373
3 0.1785 0.1785
Mean: 0.1570 0.1570
SD : 0.0207 0.0207
%RSD: 13.15 13.15
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.001 0.095
0.001 0.095
0.000
0.001
146.05
AS Loc. :
BlnkCorr Peak
Signal Area
0.028 0.123
0.030 0.124
0.028 0.123
0.029
0.001
2.62
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.095
0.000 0.094
-0.001 0.094
0.000
0.001
7256.20
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 0.100
0.005 0.099
0.007 0.101
0.006
0.001
13.15
Date: 02/02/2006
Bkgnd Time
Area
0.007 10:41:38
0.006 10:41:41
0.006 10:41:43
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:42:02
0.006 10:42:04
0.007 10:42:06
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:42:31
0.006 10:42:33
0.007 10:42:35
Date: 02/02/2006
Bkgnd Time
Area
0.007 10:43:07
0.007 10:43:09
0.006 10:43:11
Page 83
-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0217
-0.0237
-0.0106
-0.0187
0.0071
37.90
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0016
-0.0078
0.0182
0.0040
0.0132
329.0
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD;
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-0.5
SampleConc
mg/L
0.5241
0.5166
0.5084
0.5164
0.0078
1.52
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0080
-0.0295
0.0036
-0.0113
0.0168
148.9
. No. : 310
StndConc
mg/L
-0.0217
-0.0237
-0.0106
-0.0187
0.0071
37.90
. No. : 311
StndConc
mg/L
0.0016
-0.0078
0.0182
0.0040
0.0132
329.0
. No. : 312
StndConc
mg/L
0.5241
0.5166
0.5084
0.5164
0.0078
1.52
No. : 313
StndConc
mg/L
-0.0080
-0.0295
0.0036
-0.0113
0.0168
148.9
AS
BlnkCorr
S ignal
-0.001
-0.001
0.000
-0.001
0.000
37.90
AS
BlnkCorr
Signal
0.000
0.000
0.001
0,000
0.000
329.00
Loc. :
Peak
Area
0.094
0.094
0.094
Loc. :
Peak
Area
0.094
0.094
0.095
AS LOG. :
BlnkCorr
Signal
0.019
0.019
0.019
0.019
0.000
1.52
Peak
Area
0.114
0.113
0.113
AS Loc. :
BlnkCorr
Signal
0.000
-0.001
0.000
0.000
0.001
148.91
Peak
Area
0.094
0.093
0.095
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.005
0.006
0.005
02/02/2006
Time
10:44:
10:44:
10:44:
00
02
04
02/02/2006
Time
10:44:
10:44:
10:44:
11
13
15
Date: 02/02/2006
Bkgnd
Area
0.006
0.006
0.006
Time
10:44:
10:44:
10:44:
36
38
40
Date: 02/02/2006
Bkgnd
Area
0.006
0.007
0.005
Time
10:45:
10:45:
10:45:
02
04
06
Page 84
-------
Element: Mi Seq.
. No. : 314
AS LOG. ;
Date: 02/02/2006
Sample ID: 324-13+15
Repl SampleConc
# mg/L
1 0.2248
2 0.2505
3 0.2649
Mean: 0.2467
SD : 0.0203
%RSD: 8.23
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0270
2 -0.0443
3 -0.0366
Mean: -0.0360
SD : 0.0087
%RSD: 24.12
Element : Ni Seq .
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0071
2 -0.0421
3 -0.0430
Mean: -0.0307
SD : 0.0205
%RSD: 66.59
Element: Ni Seq.
StndConc
mg/L
0.2248
0.2505
0.2649
0.2467
0.0203
8.23
No.: 315
StndConc
mg/L
-0.0270
-0.0443
-0.0366
-0.0360
0.0087
24.12
No.: 316
StndConc
mg/L
-0.0071
-0.0421
-0.0430
-0.0307
0.0205
66.59
No. : 317
BlnkCorr Peak
Signal Area
0.008 0.103
0.009 0.104
0.010 0.104
0.009
0.001
8.23
AS LOG. :
BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.001 0.093
-0.001
0.000
24.12
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
-0.002 0.093
-0.002 0.093
-0.001
0.001
66.59
AS LOG.:
Bkgnd Time
Area
0.007 10:45:23
0.006 10:45:25
0.006 10:45:27
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:45:43
0.007 10:45:45
0.007 10:45:47
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:46:02
0.006 10:46:04
0.007 10:46:07
Date: 02/02/2006
Sample ID: 324-16+18
Repl SampleConc
# mg/L
1 0.2713
2 0.2871
3 0.2736
Mean: 0.2773
SD : 0.0086
%RSD: 3.08
StndConc
mg/L
0.2713
0.2871
0.2736
0.2773
0.0086
3.08
BlnkCorr Peak
Signal Area
0.010 0.104
0.011 0.105
0.010 0.104
0.010
0.000
3.08
Bkgnd Time
Area
0.006 10:46:26
0.006 10:46:28
0.006 10:46:30
Page 85
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0392
2 -0.0459
3 -0.0290
Mean: -0.0380
SD : 0.0085
%RSD: 22.44
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0077
2 -0.0066
3 -0.0401
Mean: -0.0181
SD : 0.0191
%RSD: 105.2
Element : Ni Seq
. No. : 318
StndConc
mg/L
-0.0392
-0.0459
-0.0290
-0.0380
0.0085
22.44
. No. : 319
StndConc
mg/L
-0.0077
-0.0066
-0.0401
-0.0181
0.0191
105.2
. No.: 320
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.001 0.093
-0.001
0.000
22.44
AS Loc. :
BlnkCorr Peak
Signal Area
0,000 0.094
0.000 0.094
-0.001 0.093
-0.001
0.001
105.25
AS Loc. :
Date: 02/02/2055
Bkgnd Time
Area
0.007 10:46:51
0.007 10:46:53
0.006 10:46:55
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:47:04
0.005 10:47:07
0.007 10:47:09
Date: 02/02/2006
Sample ID: 324-19+21
Repl SampleConc
# mg/L
1 0.3012
2 0.2984
3 0.3245
Mean: 0.3080
SD : 0.0143
StndConc
mg/L
0.3012
0.2984
0.3245
0.3080
0.0143
%RSD: 4.65 4.65
Element: Ni Seq. No.: 321
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0073
2 -0.0031
3 -0.0075
Mean: -0.0060
SD : 0.0025
%RSD: 41.56
StndConc
mg/L
-0.0073
-0.0031
-0.0075
-0.0060
0.0025
41.56
BlnkCorr Peak
Signal Area
0.011 0.105
0.011 0.105
0.012 0.106
0.011
0.001
4.65
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.094
0.000 0.094
0.000
0.000
41.56
Bkgnd Time
Area
0.006 10:47:28
0.006 10:47:30
0.005 10:47:32
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:47:57
0.006 10:47:59
0.006 10:48:01
Page 86
-------
Element: Ni Seq
Sample ID: 214-1+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.791
1.772
1.795
1.786
0.0123
0.69
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD ;
%RSD:
ID : ccb
SampleConc
mg/L
0.0077
-0.0015
0.0111
0.0058
0.0065
112.6
Element : Ni Seq .
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ft
1
2
3
Mean:
SD :
%RSD,-
ID: 214-4+6
SampleConc
mg/L
4.352
4.461
4.431
4.415
0.0564
1.28
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0255
-0.0334
-0.0319
-0.0303
0.0042
13.78
. No.: 322
StndConc
mg/L
1.791
1.772
1.795
1.786
0.0123
0.69
. No.: 323
StndConc
mg/L
0.0077
-0.0015
0.0111
0.0058
0.0065
112.6
No.: 324
StndConc
mg/L
4.352
4.461
4.431
4.415
0.0564
1.28
No. : 325
StndConc
mg/L
-0.0255
-0.0334
-0.0319
-0.0303
0.0042
13.78
AS
BlnkCorr
Signal
0.066
0.065
0.066
0.066
0.000
0.69
AS
Loc . :
Peak
Area
0.160
0.159
0.160
Loc. :
BlnkCorr Peak
S ignal
0.000
0.000
0.000
0.000
0.000
112.55
AS
BlnkCorr
S ignal
0.160
0.164
0.163
0.162
0.002
1.28
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
13.78
Area
0.095
0.094
0.095
Loc. :
Peak
Area
0.254
0.258
0.257
Loc. :
Peak
Area
0.093
0.093
0.093
Date:
Bkgnd
Area
0.005
02/02/2006
Time
10:48:
0.006 10:48:
0.005
Date:
Bkgnd
Area
0.005
0.005
0.005
Date:
Bkgnd
Area
0.006
0.005
0.005
10:48:
18
20
22
02/02/2006
Time
10:48:
10:48:
10:48:
46
48
51
02/02/2006
Time
10:49:
10:49:
10:49:
08
10
12
Date: 02/02/2006
Bkqnd
Area
0.006
0.006
0.006
Time
10:50:
10:50:
10:50:
11
13
16
Page 87
-------
Element : Ni Seq
Sanple
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0098
-0.0332
-0.0363
-0.0264
0.0144
54.67
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-1.0
SampleConc
mg/L
0.9410
0.9500
0.9644
0.9518
0.0118
1.24
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
BRSD:
ID: ccb
SampleConc
mg/L
-0.0465
-0.0275
0.0033
-0.0236
0.0251
106.5
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 214-7+9
SampleConc
mg/L
1.910
1.915
1.949
1.925
0.0209
1.09
. No. : 326
StndConc
mg/L
-0.0098
-0.0332
-0.0363
-0.0264
0.0144
54.67
. No. : 327
StndConc
mg/L
0.9410
0.9500
0.9644
0.9518
0.0118
1.24
No.: 328
StndConc
mg/L
-0.0465
-0.0275
0.0033
-0.0236
0.0251
106.5
No.: 329
StndConc
mg/L
1.910
1.915
1.949
1.925
0.0209
1.09
AS
Loc , :
BlnkCorr Peak
Signal
0.000
-0.001
-0.001
-0.001
0.001
54.67
AS
BlnkCorr
Signal
0.035
0.035
0.035
0.035
0.000
1.24
AS
BlnkCorr
Signal
-0.002
-0.001
0.000
-0.001
0.001
106.53
Area
0.094
0.093
0.093
Loc. :
Peak
Area
0.129
0.129
0.130
Loc. :
Peak
Area
0.093
0.093
0.095
AS Loc. :
BlnkCorr
Signal
0.070
0.070
0.072
0.071
0.001
1.09
Peak
Area
0.164
0.165
0.166
Date:
Bkgnd
Area
0.006
0.007
0.006
Date:
Bkgnd
Area
0.007
0.006
0.005
Date:
Bkgnd
Area
0.003
0.006
0.005
02/02/2006
Time
10:50:
10:50:
10:50:
23
26
28
02/02/2006
Time
10:51:
10:51:
10:51:
02
04
06
02/02/2006
Time
10:51:
10:51:
10:51:
45
47
49
Date: 02/02/2006
Bkgnd
Area
0.006
0.007
0.006
Time
10:52:
10:52:
10:52:
33
35
37
Page 88
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0126
-0.0235
-0.0042
-0.0134
0.0097
72.15
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 33G
StndConc
mg/L
-0.0126
-0.0235
-0.0042
-0.0134
0.0097
72.15
. No.: 331
AS
BlnkCorr
S ignal
0.000
-0.001
0.000
0.000
0.000
72.15
AS
Loc , :
Peak
Area
0.094
0.094
0.094
Loc, :
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
02/02/2006
Time
10:53:
10:53:
10:53:
32
34
37
02/02/2006
ID: 214-10+12
SampleConc
mg/L
0.1683
0,1424
0.1591
0.1566
0.0131
8.39
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
BRSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0100
-0.0257
-0.0100
-0.0086
0.0179
209.0
: Ni Seq.
StndConc
mg/L
0.1683
0.1424
0.1591
0.1566
0.0131
8.39
. No. : 332
StndConc
mg/L
0.0100
-0.0257
-0.0100
-0.0086
0.0179
209.0
No.: 333
BlnkCorr
S ignal
0.006
0.005
0.006
0.006
0.000
8.39
Peak
Area
0.101
0.100
0.100
AS Loc. :
BlnkCorr
S ignal
0.000
-0.001
0.000
0.000
0.001
209.03
Peak
Area
0.095
0.093
0.094
Bkgnd
Area
0.006
Time
10:53:
0.006 10:54:
0.006
Date:
Bkgnd
Area
0.005
0.007
0.006
10:54:
59
01
03
02/02/2006
Time
10:54:
10:54:
10:54:
50
52
54
AS Loc. : Date:
02/02/2006
ID: 214-13+15
SampleConc
mg/L
1.819
1.861
1.B28
1.836
0.0223
1.21
StndConc
mg/L
1.819
1.861
1.828
1.836
0.0223
1.21
BlnkCorr
Signal
0.067
0.068
0.067
0.067
0.001
1.21
Peak
Area
0.161
0.163
0.161
Bkgnd
Area
0.007
0.007
0.007
Time
10:55:
10:55:
10:55:
13
15
17
Page 89
-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID: ccb
SampleConc
mg/L
0.0122
0.0020
0.0113
0.0085
0.0056
66.41
: Ni Seq.
. No. : 334
StndConc
mg/L
0.0122
0.0020
0.0113
0.0085
0.0056
66.41
. No. : 335
AS
Loc. :
BlnkCorr Peak
Signal
0.000
0.000
0.000
0.000
0.000
66.41
AS
Area
0.095
0.094
0.095
Loc. :
Date:
Bkgnd
Area
02/02/2006
Time
0.006 10:55:
0.006
0.006
Date:
10:55:
10:55:
—
37
39
41
02/02/2006
ID: 214-16+18
SampleConc
mg/L
0.5226
0.5389
0.5288
0.5301
0.0082
1.54
: Ni Seq.
ID: ccb
SampleConc
mg/L
-0.0049
-0.0080
0.0115
-0.0005
0.0105
2156
: Ni Seq.
StndConc
mg/L
0.5226
0.5389
0.5288
0.5301
0.0082
1.54
. No. : 336
StndConc
mg/L
-0.0049
-0.0080
0.0115
-0.0005
0.0105
2156
No. : 337
BlnkCori
S ignal
0.019
0.020
0.019
0.019
0.000
1.54
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
2156.28
AS
Peak
Area
0.114
0.114
0.114
Loc. :
Peak
Area
0.094
0.094
0.095
Loc. :
Bkgnd
Area
0.007
0.007
0.007
Date:
Bkgnd
Area
0.006
0.006
0.006
Time
10:55:
10:56:
10:56:
59
01
03
02/02/2006
Time
10:56:
10:56:
10:56:
18
20
22
Date: 02/02/2006
ID: 214-19+21
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.2877
0.3106
0.3176
0.3053
0.0156
5.13
StndConc
mg/L
0.2877
0.3106
0.3176
0.3053
0.0156
5.13
BlnkCorr
Signal
0.011
0.011
0.012
0.011
0.001
5.13
Peak
Area
0.105
0.106
0.106
Bkgnd
Area
0.007
0.006
0.006
Time
10:56:
10:56:
10:56:
39
41
43
Page 90
-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0088
-0.0064
0.0140
0.0055
0.0106
193.8
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0091
-0.0069
0.0268
0.0036
0.0201
561.5
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-2
SampleConc
mg/L
2.099
2.063
2 .109
2.090
0. 0244
1.17
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0060
0.0073
0.0082
0.0072
0.0011
15.32
. No. : 338
StndConc
mg/L
0.0088
-0.0064
0.0140
0.0055
0.0106
193.8
. No. : 339
StndConc
mg/L
-0.0091
-0.0069
0.0268
0.0036
0.0201
561.5
. No. : 340
StndConc
mg/L
2.099
2.063
2.109
2.090
0.0244
1.17
. No. : 341
StndConc
mg/L
0.0060
0.0073
0.0082
0.0072
0.0011
15.32
AS
BlnkCorr
S ignal
0.000
0.000
0.001
0.000
0.000
193.76
AS
BlnkCorr
S ignal
0.000
0.000
0.001
0.000
0.001
561.54
Loc. :
Peak
Area
0.095
0.094
0.095
Loc. :
Peak
Area
0.094
0.094
0.095
AS LOG. :
BlnkCorr
Signal
0 .077
0.076
0.077
0.077
0.001
1.17
Peak
Area
0.171
0.170
0.172
AS Loc. :
BlnkCorr
S ignal
0.000
0.000
0.000
0.000
0.000
15.32
Peak
Area
0.095
0.095
0.095
Date:
Bkgnd
Area
02/02/2006
Time
0.006 10:57
0.006
10:57
0.006 10:57
Date:
Bkgnd
Area
0.006
0.006
0.005
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.005
0.006
0.006
—
:25
:28
:30
02/02/2006
Time
10:57
10:57
10:57
—
:42
:45
:47
02/02/2006
Time
10:58
10:58
10:58
:01
:03
:05
02/02/2006
Time
10:58
10:58
10:58
:28
:30
:32
-------
Element : Ni Seq
Sample ID: Irb i
Repl SampleConc
# mg/L
1 0.0698
2 0.0656
3 0.0673
Mean: 0 . 0676
SD : 0.0021
%RSD: 3.13
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0414
2 0.0082
3 -0.0436
Mean: -0.0256
SD : 0.0293
%RSD: 114.5
Element: Ni Seq.
Sample ID: Ifb i
Repl SampleConc
# mg/L
1 1.086
2 1.079
3 1.056
Mean: 1.073
SD : 0.0159
%RSD: 1.48
Element : Ni Seq .
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0128
2 0.0038
3 -0.0002
Mean: -0.0030
SD : 0.0087
%RSD: 284.9
. No. : 342
StndConc
mg/L
0.0698
0.0656
0.0673
0.0676
0.0021
3.13
. No. : 343
StndConc
mg/L
-0.0414
0.0082
-0.0436
-0.0256
0.0293
114.5
. No. : 344
StndConc
mg/L
1.086
1.079
1.056
1.073
0.0159
1.48
No.: 345
StndConc
mg/L
-0.0128
0.0038
-0.0002
-0.0030
0.0087
264.9
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.097
0.002 0.097
0.002 0.097
0.002
0.000
3.13
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 0.093
0.000 0.095
-0.002 0.093
-0.001
0.001
114.45
AS Loc. :
BlnkCorr Peak
Signal Area
0.040 0.134
0.040 0.134
0.039 0.133
0.039
0.001
1.48
AS Loc. I
BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.094
0.000
0.000
284.88
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:58:52
0.006 10:58:54
0.006 10:58:56
Date: 02/02/2006
Bkgnd Time
Area
0.007 10:59:14
0.006 10:59:16
0.007 10:59:18
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:59:39
0.006 10:59:41
0.006 10:59:43
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:00:01
0.005 11:00:03
0.006 11:00:05
Page 92
-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 324-2
SampleConc
mg/L
0.2935
0.3163
0.2716
0.2938
0.0223
7.60
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0206
-0.0301
-0.0002
-0.0170
0.0153
90.12
Element: Ni Seq.
Sample ID: s324-2
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.238
1.270
1.231
1.246
0.0207
1.66
: Ni Seq.
ID : ccb
SampleConc
mg/L
0.0080
-0.0097
0.0179
0.0054
0.0139
257.9
. No. : 346
StndConc
mg/L
0.2935
0.3163
0.2716
0.2938
0.0223
7.60
. No. : 347
StndConc
mg/L
-0.0206
-0.0301
-0.0002
-0.0170
0.0153
90.12
No. : 348
StndConc
mg/L
1.238
1.270
1.231
1.246
0.0207
1.66
No. : 349
StndConc
mg/L
0.0080
-0.0097
0.0179
0.0054
0.0139
257.9
AS
BlnkCorr
Signal
0.011
0.012
0.010
0.011
0.001
7.60
AS
BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.001
90.12
Loc. :
Peak
Area
0.105
0.106
0.104
Loc. :
Peak
Area
0.094
0.093
0.094
AS Loc. :
BlnkCorr
Signal
0.045
0.047
0.045
0.046
0.001
1.66
Peak
Area
0.140
0 . 141
0.140
AS Loc. :
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
257.91
Peak
Area
0.095
0.094
0.095
Date:
Bkgnd
Area
0.006
02/02/2006
Time
11:00:
0.005 11:00:
0.006
Date:
Bkgnd
Area
0.006
0.006
0.005
Date:
Bkgnd
Area
0.006
0.005
0.007
11:00:
24
27
29
02/02/2006
Time
11:01:
11:01:
11:01:
15
17
19
02/02/2006
Time
11:01:
11:01:
11:01:
44
46
48
Date: 02/02/2006
Bkgnd
Area
0.005
0.005
0.005
Time
11:02:
11:02:
11:02:
05
07
09
Page 93
-------
Element: Ni Seq. No. : 350 AS
Sample ID: sd324-2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.185 1.185 0.043
2 1.183 1.183 0.043
3 1.196 1.196 0.044
Mean: 1.188 1.188 0.044
SD ; 0.0070 0.0070 0.000
%RSD: 0.59 0.59 0.59
Element: Ni Seq. No.: 351 AS
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0002 -0.0002 0.000
2 -0.0097 -0.0097 0.000
3 0.0013 0.0013 0.000
Mean: -0.0029 -0.0029 0.000
SD : 0.0059 0.0059 0.000
%RSD: 207.9 207.9 207.95
Element: Ni Seq. No.: 352 AS
Sample ID: ser324-2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.2275 0.2275 0.008
0.2461 0.2461 0.009
3 0.2124 0.2124 0.008
Mean: 0.2287 0.2287 0.008
SD : 0.0169 0.0169 0.001
%RSD: 7.39 7.39 7.39
Element: Ni Seq. No.: 353 AS
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0086 -0.0086 0.000
2 -0.0199 -0.0199 -0.001
3 -0.0128 -0.0128 0.000
Mean: -0.0137 -0.0137 -0.001
SD : 0.0057 0.0057 0.000
%RSD: 41.60 41.60 41.60
LOG. :
Peak
Area
0.138
0.138
0.138
LOG. :
Peak
Area
0.094
0.094
0.094
LOG. :
Peak
Area
0.103
0.103
0.102
Loc. :
Peak
Area
0.094
0.094
0.094
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:02:29
0.005 11:02:31
0.005 11:02:33
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:02:55
0.006 11:02:57
0.005 11:02:59
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:03:24
0.005 11:03:27
0.006 11:03:29
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:03:47
0.005 11:03:50
0.005 11:03:52
Page 94
-------
Element : Ni Seq
Sample ID : ccb
Repl SampleConc
# mg/L
1 -0.0022
2 0.0122
3 0.0060
Mean: 0.0053
SD : 0.0072
%RSD: 135.1
Element : Ni Seq
Sample ID: ccv-0.2E
Repl SampleConc
# mg/L
1 0.2277
2 0.2319
3 0.2260
Mean: 0.2285
SD : 0.0030
%RSD: 1.32
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0026
2 -0.0195
3 -0.0197
Mean: -0.0139
SD : 0.0098
%RSD: 70.72
Element: Ni Seq.
Sample ID: 324-5
Repl SampleConc
# mg/L
1 0.0842
2 0.1008
3 0.0755
Mean: 0.0868
SD : 0.0129
%RSD: 14.82
. No. : 354
StndConc
mg/L
-0.0022
0.0122
0.0060
0.0053
0.0072
135.1
. No.: 355
5
StndConc
mg/L
0.2277
0.2319
0.2260
0.2285
0.0030
1.32
. No. : 356
StndConc
mg/L
-0.0026
-0.0195
-0.0197
-0.0139
0.0098
70.72
. No. : 357
StndConc
mg/L
0.0842
0.1008
0.0755
0.0868
0.0129
14.82
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.095
0.000
0.000
135.09
AS Loc. :
BlnkCorr Peak
Signal Area
0.008 0.103
0.009 0.103
0.008 0.103
0.008
0.000
1.32
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
-0.001 0.094
-0.001 0.094
-0.001
0.000
70.72
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.097
0.004 0.098
0.003 0.097
0.003
0.000
14.82
Date:
Bkgnd
Area
0.005
0.005
0.005
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.005
0.006
0.005
Date:
Bkgnd
Area
0.006
0.005
0.005
02/02/2006
Time
11:04:31
11:04:33
11:04:35
02/02/2006
Time
11:04:52
11:04:54
11:04:56
02/02/2006
Time
11:05:12
11:05:14
11:05:16
02/02/2006
Time
11:05:33
11:05:35
11:05:37
Page 95
-------
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0095
2 0.0100
3 0.0000
Mean: 0.0065
SD : 0.0056
%RSD: 86.70
Element : Ni Seq
Sample ID: 324-8
Repl SampleConc
# mg/L
1 0.0915
2 0.0842
3 0.0932
Mean: 0.0896
SD : 0.0048
%RSD: 5.31
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# »g/L
1 -0.0005
O f~\ /** f~\ i—i r-r
- : £ -0 . 0077
3 0.0175
Mean: 0.0031
SD : 0.0130
%RSD: 418.5
Element : Ni Seq .
Sample ID: 324-11
Repl SampleConc
# mg/L
1 0.0766
2 0.0620
3 0.0647
Mean: 0.0678
SD : 0.0078
%RSD: 11.44
. No. : 358
StndConc
mg/L
0.0095
0.0100
0.0000
0.0065
0.0056
86.70
. No. : 359
StndConc
mg/L
0.0915
0.0842
0.0932
0.0896
0.0048
5.31
. No. : 360
StndConc
mg/L
-0.0005
_ _ _
-0 . 0077
0.0175
0.0031
0.0130
418.5
. No. : 361
StndConc
mg/L
0.0766
0.0620
0.0647
0.0678
0.0078
11.44
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
86.70
AS
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
5.31
AS
BlnkCorr
Signal
0.000
0 . 000
0.001
0.000
0.000
418 .47
AS :
BlnkCorr
Signal
0.003
0.002
0.002
0.002
0.000
11.44
LOG. :
Peak
Area
0.095
0.095
0.094
Loc. :
Peak
Area
0.098
0.097
0.098
Loc. :
Peak
Area
0.094
0 . 094
0.095
Loc. :
Peak
Area
0.097
0.097
0.097
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:05:58
0.005 11:06:00
0.005 11:06:03
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:06:22
0.006 11:06:24
0.006 11:06:26
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:06:52
r~\ r\ f~\ .*- 1 "1 /~l /"" ET ./!
0 . 006 1J- : Uo ; o4
0.005 11:06:56
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:07:10
0.005 11:07:13
0.005 11:07:15
Page 96
-------
Element : Ni Seq . No . : 362
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0182 -0.0182
2 -0.0605 -0.0605
3 -0.0383 -0.0383
Mean: -0.0390 -0.0390
SD : 0.0212 0.0212
%RSD: 54.23 54.23
Element: Ni Seq. No.: 363
Sample ID: 324-14
Repl SampleConc StndConc
# mg/L mg/L
1 0.0609 0.0609
2 0.0751 0.0751
3 0.0591 0.0591
Mean: 0.0650 0.0650
SD : 0.0088 0.0088
BRSD: 13.51 13.51
Element: Ni Seq. No.: 364
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0027 -0.0027
2 0.0071 0.0071
3 -0.0122 -0.0122
Mean: -0.0026 -0.0026
SD : 0.0097 0.0097
%RSD: 369.8 369.8
Element: Ni Seq. No.: 365
Sample ID: dup 324-14
Repl SampleConc StndConc
# mg/L mg/L
1 0.0746 0.0746
2 0.0711 0.0711
3 0.0696 0.0696
Mean: 0.0718 0.0718
SD : 0.0025 0.0025
%RSD: 3.52 3.52
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.094
-0.002 0.092
-0.001 0.093
-0.001
0.001
54.23
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.097
0.003 0.097
0.002 0.097
0.002
0.000
13.51
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.094
0.000
0.000
369.79
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.097
0.003 0.097
0.003 0.097
0.003
0.000
3.52
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:07:29
0.008 11:07:31
0.007 11:07:33
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:07:49
0.005 11:07:51
0.006 11:07:53
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:08:05
0.005 11:08:07
0.006 11:08:10
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:08:27
0.005 11:08:29
0.006 11:08:31
-------
Appendix E - 3
Laboratory QA/QC Data for Stack Testing Samples
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0184
2 0.0153
3 0.0148
Mean: 0.0162
SD : 0.0020
%RSD: 12.16
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0151
2 -0.0018
3 -0.0086
Mean: -0.0085
SD : 0.0067
%RSD: 78.22
Element: Ni Seq.
Sample ID: ccv-2
Repl SampleConc
# mg/L
1 2.056
2 2.089
3 2.071
Mean: 2.072
SD : 0.0169
%RSD: 0.82
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0109
2 -0.0421
3 -0.0002
Mean: -0.0177
SD : 0.0218
%RSD: 122.7
No. : 366 AS ]
StndConc BlnkCorr
mg/L Signal
0.0184 0.001
0.0153 0.001
0.0148 0.001
0.0162 0.001
0.0020 0.000
12.16 12.16
No. : 367 AS '.
StndConc BlnkCorr
mg/L Signal
-0.0151 -0.001
-0.0018 0.000
-0.0086 0.000
-0.0085 0.000
0.0067 0.000
78.22 78.22
No. : 368 AS
StndConc BlnkCorr
mg/L Signal
2.056 0.075
2.089 0.077
2.071 0.076
2.072 0.076
0.0169 0.001
0.82 0.82
No. : 369 AS
StndConc BlnkCorr
mg/L Signal
-0.0109 0.000
-0.0421 -0.002
-0.0002 0.000
-0.0177 -0.001
0.0218 0.001
122.7 122.73
L,oc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.094
0.094
0.094
Loc. :
Peak
Area
0.170
0.171
0.170
Loc. :
Peak
Area
0.094
0.093
0.094
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:08:45
0.005 11:08:47
0.005 11:08:49
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:16:25
0.005 11:16:27
0.005 11:16:30
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:16:45
0.005 11:16:48
0.005 11:16:50
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:18:32
0.006 11:18:35
0.005 11:18:37
Page 98
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: 324-17
SampleConc
mg/L
0.0671
0.1088
0.0665
0.0808
0.0243
30.02
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0162
0.0117
-0.0215
-0.0087
0.0178
205.1
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: 324-20
SampleConc
mg/L
0.0558
0.0667
0.0483
0.0569
0.0093
16.26
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0170
0.0133
-0.0108
0.0065
0.0151
231.6
, No.: 370
StndConc
mg/L
0.0671
0.1088
0.0665
0.0808
0.0243
30.02
. No. : 371
StndConc
mg/L
-0.0162
0.0117
-0.0215
-0.0087
0.0178
205.1
. No. : 372
StndConc
mg/L
0.0558
0.0667
0.0483
0.0569
0.0093
16.26
. No.: 373
StndConc
mg/L
0.0170
0.0133
-0.0108
0.0065
0.0151
231.6
AS Loc. :
BlnkCorr
Signal
0.002
0.004
0.002
0.003
0.001
30.02
Peak
Area
0.097
0.098
0.097
AS Loc. :
BlnkCorr
Signal
-0.001
0.000
-0.001
0.000
0.001
205.15
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
16.26
AS
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.001
231.56
Peak
Area
0.094
0.095
0.094
Loc. :
Peak
Area
0.096
0.097
0.096
Loc. :
Peak
Area
0.095
0.095
0.094
Date: 02/02/2006
Bkgnd
Area
0.006
0.004
0.006
Time
11:18:50
11:18:52
11:18:54
Date: 02/02/2006
Bkgnd
Area
0.006
0.005
0.006
Date:
Bkgnd
Area
0.005
0.006
0.006
Date:
Bkgnd
Area
0.005
0.005
0.005
Time
11:19:23
11:19:26
11:19:28
02/02/2006
Time
11:19:50
11:19:52
11:19:55
02/02/2006
Time
11:20:15
11:20:17
11:20:19
Page 99
-------
Element: Ni Seq
Sample ID: 214-2
Repl SampleConc
# mg/L
1 0.0944
2 0.0740
3 0.0636
Mean: 0.0774
SD : 0.0157
%RSD: 20.26
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0175
2 -0.0277
3 -0.0071
Mean: -0.0174
SD : 0.0103
%RSD: 59.06
Element: Ni Seq
Sample ID: 214-5
Repl SampleConc
# mg/L
1 0.0350
2 0.0607
3 0.0507
Mean: 0.0488
SD : 0.0130
%RSD: 26.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0007
2 0.0168
3 -0.0026
Mean: 0.0045
SD : 0.0107
%RSD: 237.3
. No.: 374
StndConc
mg/L
0.0944
0.0740
0.0636
0.0774
0.0157
20.26
. No. : 375
StndConc
mg/L
-0.0175
-0.0277
-0.0071
-0.0174
0.0103
59.06
. No. : 376
StndConc
mg/L
0.0350
0.0607
0.0507
0.0488
0.0130
26.55
. No. : 377
StndConc
mg/L
-0.0007
0.0168
-0.0026
0.0045
0.0107
237.3
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.098
0.003 0.097
0.002 0.097
0.003
0.001
20.26
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.094
-0.001 0.093
0.000 0.094
-0.001
0.000
59.06
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.002 0.096
0.002
0.000
26.55
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.094
0.001 0.095
0.000 0.094
0.000
0.000
237.27
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:20:45
0.005 11:20:48
0.006 11:20:50
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:21:08
0.006 11:21:10
0.005 11:21:12
Date: 02/02/2006
Bkgnd Time
Area
0.007 11:21:24
0.006 11:21:26
0.006 11:21:28
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:21:42
0.004 11:21:44
0.005 11:21:46
Page 100
-------
Element: Ni Seq
Sample ID: 214-8
Repl SampleConc
# mg/L
1 0.0496
2 0.0645
3 0.0667
Mean: 0.0603
SD : 0.0093
%RSD: 15.47
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0166
2 0.0035
3 0.0007
Mean: -0.0041
SD : 0.0109
%RSD: 263.2
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0357
2 -0.0454
3 -0.0529
Mean: -0.0447
SD : 0.0086
%RSD: 19.24
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.4736
2 0.4539
3 0.4856
Mean: 0.4711
SD : 0.0160
%RSD: 3.40
. No. : 378
StndConc
mg/L
0.0496
0.0645
0.0667
0.0603
0.0093
15.47
. No. : 379
StndConc
mg/L
-0.0166
0.0035
0.0007
-0.0041
0.0109
263.2
. No. : 380
StndConc
mg/L
-0.0357
-0.0454
-0.0529
-0.0447
0.0086
19.24
. No. : 381
StndConc
mg/L
0.4736
0.4539
0.4856
0.4711
0.0160
3.40
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.096
0.002 0.097
0.002 0.097
0.002
0.000
15.47
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.094
0.000 0.095
0.000 0.094
0.000
0.000
263.17
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.002 0.092
-0.002
0.000
19.24
AS Loc. :
BlnkCorr Peak
Signal Area
0.017 0.112
0.017 0.111
0.018 0.112
0.017
0.001
3.40
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:22:02
0.006 11:22:04
0.006 11:22:06
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:22:21
0.005 11:22:23
0.005 11:22:25
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:22:52
0.006 11:22:54
0.006 11:22:56
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:23:12
0.007 11:23:15
0.005 11:23:17
Page 101
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0689
2 -0.0290
3 -0.0518
Mean: -0.0499
SD : 0.0200
%RSD: 40.15
Element: Ni Seq
Sample ID: 214-11
Repl SampleConc
# mg/L
1 0.0427
2 -0.0027
3 0.0252
Mean: 0.0217
SD : 0.0229
%RSD: 105.5
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0250
2 -0.0233
3 -0.0556
Mean: -0.0346
SD : 0.0182
%RSD: 52.47
Element: Ni Seq
Sample ID: 214-14
Repl SampleConc
# mg/L
1 0.0527
2 0.0811
3 0.0117
Mean: 0.0485
SD : 0.0349
%RSD: 72.01
. No.: 382
StndConc
mg/L
-0.0689
-0.0290
-0.0518
-0.0499
0.0200
40.15
. No. : 383
StndConc
mg/L
0.0427
-0.0027
0.0252
0.0217
0.0229
105.5
. No. : 384
StndConc
mg/L
-0.0250
-0.0233
-0.0556
-0.0346
0.0182
52.47
. No.: 385
StndConc
mg/L
0.0527
0.0811
0.0117
0.0485
0.0349
72.01
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 0.092
-0.001 0.093
-0.002 0.092
-0.002
0,001
40.15
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.096
0.000 0.094
0.001 0.095
0.001
0.001
105.53
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.093
-0.001 0.094
-0.002 0.092
-0.001
0.001
52.47
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.096
0.003 0.097
0.000 0.095
0.002
0.001
72.01
Date: 02/02/2006
Bkgnd Time
Area
0.007 11:23:35
0.005 11:23:37
0.006 11:23:39
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:23:50
0.007 11:23:53
0.006 11:23:55
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:24:12
0.005 11:24:14
0.006 11:24:16
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:24:32
0.004 11:24:34
0.007 11:24:36
Page 102
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0221
2 -0.0341
3 -0.0146
Mean: -0.0236
3D : 0.0098
%RSD: 41.74
Element: Ni Seq
Sample ID: 214-17
Repl SampleConc
# mg/L
1 0.0279
2 0.0335
3 0.0403
Mean: 0.0339
SD : 0.0062
%RSD: 18.30
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0292
2 -0.0518
3 -0.0345
Mean: -0.0385
SD : 0.0118
%RSD: 30.74
Element: Ni Seq
Sample ID: 214-20
Repl SampleConc
# mg/L
1 0.0434
2 0.0731
3 0.0804
Mean: 0.0656
SD : 0.0196
%RSD: 29.87
. No. : 386
StndConc
mg/L
-0.0221
-0.0341
-0.0146
-0.0236
0.0098
41.74
. No.: 387
StndConc
mg/L
0.0279
0.0335
0.0403
0.0339
0.0062
18.30
. No. : 388
StndConc
mg/L
-0.0292
-0.0518
-0.0345
-0.0385
0.0118
30.74
. No.: 389
StndConc
mg/L
0.0434
0.0731
0.0804
0.0656
0.0196
29.87
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
41.74
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
18.30
AS
BlnkCorr
Signal
-0.001
-0.002
-0.001
-0.001
0.000
30.74
AS
BlnkCorr
Signal
0.002
0.003
0.003
0.002
0.001
29.87
Loc. :
Peak
Area
0.094
0.093
0.094
Loc. :
Peak
Area
0.095
0.096
0.096
Loc. :
Peak
Area
0.093
0.092
0.093
Loc. :
Peak
Area
0.096
0.097
0.097
Date: 02/02/2006
Bkgnd Time
Area
0.005 11:24:48
0.006 11:24:50
0.006 11:24:52
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:25:10
0.006 11:25:12
0.006 11:25:14
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:25:26
0.006 11:25:28
0.006 11:25:30
Date: 02/02/2006
Bkgnd Time
Area
0.006 11:25:43
0.005 11:25:45
0.005 11:25:48
Page 103
-------
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0388
-0.0224
-0.0520
-0.0377
0.0148
39.21
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0237
-0.0707
-0.0569
-0.0504
0.0242
47.92
Element: Ni Seq
Sample
Repl
#
1
ID: Sample
SampleConc
mg/L
-0.0350
. No. : 390
StndConc
mg/L
-0.0388
-0.0224
-0.0520
-0.0377
0.0148
39.21
. No. : 391
StndConc
mg/L
-0.0237
-0.0707
-0.0569
-0.0504
0.0242
47.92
. No. : 392
StndConc
mg/L
-0.0350
AS
BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
39.21
AS
BlnkCorr
Signal
-0.001
-0.003
-0.002
-0.002
0.001
47.92
AS
BlnkCorr
Signal
-0.001
Loc. :
Peak
Area
0.093
0.094
0.092
Loc. :
Peak
Area
0.094
0.092
0.092
Loc. :
Peak
Area
0.093
Date:
Bkgnd
Area
02/02/2006
Time
0.006 11:26:
0.005
0.007
Date :
Bkgnd
Area
0.005
0.007
0.006
Date:
Bkgnd
Area
0.006
11:26:
11:26:
01
03
05
02/02/2006
Time
11:26:
11:26:
11:26:
14
16
18
02/02/2006
Time
11:26:
22
Auto- zero performed.
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0053
-0.0071
-0.0106
-0.0041
0.0083
201.8
. No. : 393
StndConc
mg/L
0.0053
-0.0071
-0.0106
-0.0041
0.0083
201.8
: Ni Seq. No. : 394
AS Loc. :
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
201.80
Peak
Area
0.093
0.093
0.093
AS Loc. :
Date:
Bkgnd
Area
0.006
0.006
0.006
02/02/2006
Time
11:26:
11:26:
11:26:
29
31
34
Date: 02/02/2006
ID: 214-11 dup
SampleConc
mg/L
0.1052
0.1077
0.0995
0.1042
0.0042
4.03
StndConc
mg/L
0.1052
0.1077
0.0995
0.1042
0.0042
4.03
BlnkCorr
Signal
0.004
0.004
0.004
0.004
0.000
4.03
Peak
Area
0.097
0.097
0.097
Bkgnd
Area
0.005
0.005
0.005
Time
11:26:
11:26:
11:26:
51
53
56
Page 104
-------
Element: Ni Seq. No.: 395
Sample ID: ccb
AS LOG.
Date: 02/02/2006
Repl J
# r
1
2
3
Mean:
SD :
%RSD:
3ampleConc
ag/L
0.0224
0.0073
0.0044
0.0114
0.0097
85.26
StndConc
mg/L
0.0224
0.0073
0.0044
0.0114
0.0097
85.26
BlnkCorr Peak
Signal Area
0.001 0.094
0.000 0.093
0.000 0.093
0.000
0.000
85.26
Bkgnd Time
Area
0.005 11:27:11
0.006 11:27:13
0.006 11:27:15
Element: Ni Seq. No.: 396
Sample ID: ccb
AS Loc.
Date: 02/02/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0029
0.0277
-0.0031
0.0092
0.0163
178.0
StndConc
mg/L
0.0029
0.0277
-0.0031
0.0092
0.0163
178.0
BlnkCorr Peak
Signal Area
0.000 0.093
0.001 0.094
0.000 0.093
0.000
0.001
177.97
Bkgnd Time
Area
0.005 11:27:35
0.005 11:27:38
0.006 11:27:40
Element: Ni Seq. No.: 397
Sample ID: ccv-0.25
AS Loc.
Date: 02/02/2006
Repl
#
1
2
~ 3
Mean:
SD :
%RSD:
Samp
mg/I
0.
0.
0.
0.
0.
>leConc
i
2425
2233
2335
2331
0096
4.11
St
mg
0
0
0
0
0
ndConc
/L
.2425
.2233
.2335
.2331
.0096
4.11
BlnkCorr
Signal
0.009
0.008
0.009
0.009
0.000
4.11
Pe
Ar
0.
0.
0.
ak
ea
102
101
102
Bk
Ar
0
0
0
gnd
ea
.006
.006
.006
Time
11:28
11:28
11:28
:01
:03
:05
Page 105
-------
Prep Method," (check only one per page) - -
ICP/FLAA: SM 3030 E^PA 200.7 '82
1CP/FLM: EPA 2pd!s, SW-846 3010A
ICP/FLAA: EPX200.7r4.4
|CP/FLAA;ydW-846 3005A
ICP/FLA#C SW-846 3015A MICROWAVE
OTHE
GFAA:
GFAA: SPA 200's, SW-846 3020A
EPA 200.9
SW-846 3015A (NoHCL) MICROWAVE
OTH ER: ; _
MATRIX; (check only one per page)
DRINKING WATER
1
2
3
4
5
6
7
8
9
10
11
12
Set
Inifl
L^
Set
date
^
Set
time
$
Lab#
/lo&f
&* / #*s ^ /Z-/
y / &/ &£~j ^f
Smp#
. ._ »
-3
L?
^
/(x
/^
/•?
^
_^
/^
^
/^
/<"
i^
p-i
AQUEOUS
Company
LFB
LRB
USS3«P
LFM
.>
OTHER:
Aliquot
(mis)
I^IL
\
/
/ 7, fa
\
/
Final
(mis)
Mcr
Vsl#
€>
Z
^
4
^
2.
*
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Prep M©fhod: • (check only one per page)
ICP/FLAA: SM 3Q3Qtf~EPA 200.7 '82
ICP/FLAA: EPA 3do's, SW-846 301OA
ICP/FLAA: EBA 2O0.7 r4.4
!CP/FLAAySW-846 3005A
ICP/FLAX: SW-846 3015A MICROWAVE
OTHE
GFAA:
GFAA:yPA 200's, SW-846 3020A
GFAA! EPA 200.9
SW-846 3015A (NoHCL) MICROWAVE
HER: :
IVIATRIX: (check only one per page)
DRINKING WATER I lAQUEOUS
OTHER:
Set
Init'I
Set
date
Set
time
Company
Aliquot
(mis)
Final
(mis)
Mcr
Vslf
LFB
3.
\0
it
^ ..'),
IS.-
o
/ i-
o
o
lo
a
D
/3
4
0
/3
n
J
7
4
8
•£2.
7
ii.
)0
10
11
Us
12
ii
O
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
sp\
LOT#
A~fl£>ka.
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 UK
Page 1 of 1
-------
Self |
Prep Method: (check only one per page) - -
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: ; .
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: -EPA 200.9
FAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER: :
MATRIX: {check only one per page)
DRINKING WATER AQUEOUS
OTHER:
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
Cfa)
*
LOT*
£>.5"H OL^a.
Analyst: _
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
PROJECT # 2005110201: METHOD 306A FOR NICKEL
Samples that read ,,
PH
<2.0
<2.0
<2.0
<2.0
»k42:0 * -
Sample
Fraction
385.0
371.0
390.0
322.0
/^",
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
. - HNOSt
Analytical
Fraction
50.0
50.0
50.0
50.0
':, 50.0xj/;;
7
Nl mg/L
0.612
0.400
0.547
'V~ j,0.0f4
0.075
8
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.031
0.020
0.027
j
-------
QA/QC WORK SHEET for NICKEL
F' AA METHOD SOP MET-040
5100 AA
1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
Date: 1/5/2006
Analyst: LK
(For Specific instrument settings, see current copy of method.)
3 CALIBRATION:
(Mg/U
IDL= 0.027
MDL= 0.075
RL = 0.10
LDR = 0.10 to 8.0
4 STANDARD TRACEABILITY
Cai Curve:
Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.226
0.488
1.022
2.072
4.968
0.9998
% Rec.
90.5
97.6
102.2
103.6
99.4
QC STANDARD
Calibration
CCV CRA, AAT
QCS, LFM
Standard Name, Company, & Lot #
CPI QC-21 41M044
CPI QC-21 41M044
CPI 05F011
ff SAMPI ,,F ANALYTICAL RUN
MAT-
RIX
306
121
121
121
121
121
121
121
SAMPLE
CCV
QCS
CCV
CCB
CRA
CRA
CRA
LRB
201-3
CCV
LRB
LFB
SPK
SER OIL
325-2
325-3
034-1
034-2
034-3
CCV
STD CONC
5.00
2.00
10.00
0.05
0.10
0.25
0.50
0.80
1.00
2/10
2.00
READING
Mg/L
4.975
2.080
9.137
-0.051
0.025
0.082
0.229
-0.023
1.067
0.617
1.509
0.336
0.547
0.051
0.584
-0.030
0.762
0.036
0.045
1.033
0.226
0.271
-0.014
0.054
0.083
0.158
0.155
-0.020
2.173
0.004
BLK
-0.061
-0.004
-0.028
-0.021
-0.043
-0.006
0.009
0.043
-0.001
0.000
0.036
0.036
0.031
-0.005
-0.001
0.009
0.029
0.005
0.006
0.008
0.029
0.032
0.008
0.010
0.005
0.000
RESULT
4.975
2.080
9.137
0.010
0.028
0.110
0.250
0.020
1 073
0.612
0.576
1.500
0.293
0.547
0.015
0.548
-0.062
0.766
0038
0.036
1.004
0.221
0.265
-0.023
0.024
0.150
0.146
-0.025
2.173
0004
D1L1
1 0
1.0
1.0
-To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
OIL 2
1 0
1.0
1.0
~0
.0
1.0
1.0
1.0
-To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC
RESULTS
100
104
91
0.010
57
110
100
0.020
107
110
-0.062
96
10.0
109
0004
Mg/L
0.015
0.038
0.265 /
-0.023 /
0.024 /
0.146\
-0.025X
\
REP'T
mg/L
0.074
0.074
> \
0.265
0.074
0.074
0.146
0.074
,
ICP
— .- C'tS 2~-
, 9^ '1
0.064
V
0.288 N
, -0.002
\ 0.049
i 0.176
j 0.001 /
95-1 05%R 5
95-105%R)
90-1 10%R)
< MDL }
70-1 30%R)
70-130%R )
70-1 30%R)
< MDL )
80-1 20%R)
<10 RPD, IF SA > 20X MDL)
80-1 20%R)
<10%DIFF)
(< MDL )
(90-110%R)
(< MDL )
! W1-120%R)
(«10 RPD, IF SA > 20X MDL)
! »">-120%R)
(<10%DIFF)
y*-
/
( 90-11 0%R )
(< MDL )
-------
Method Name: NI
Method Description: Nickel
Date: 01/05/2006 ,
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 15
Sample Info File: Untitled
Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 70
Results Data Set:
Element: Ni Seq. No.: 1
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
Repl
#
i
-L
0
C*
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
-0.056
-0.056
-0.056
-0.056
0.000
0.14
Peak
Area
-0.056
-0.056
-0.056
Bkgnd
Area
0.143
0.143
0.143
Time
11:29:20
11:29:22
11:29:24
Auto-zero performed.
Element: Ni Seq. No.: 2
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
Repl
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
-0.069
-0.076
0.083
-0.020
0.090
439.78
Peak
Area
-0.124
-0.131
0.028
Bkgnd
Area
0.200
0.208
0.050
Time
11:36:48
11:36:50
11:36:52
Auto-zero performed.
Element: Ni Seq. No.: 3
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
0.155
0.155
0.155
0.155
0.000
0.03
Peak
Area
0.079
0.079
0.079
Bkgnd
Area
0.000
0.000
0.000
Time
11:36:55
11:36:58
11:37:00
Auto- zero performed.
Page 1
-------
Element: Ni Seq. No.: 4
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
SampleConc
mg/L
Repl
#
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed
StndConc
mg/L
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
769.44
Peak
Area
0.079
0.078
0.079
Bkgnd
Area
0.000
0.000
0.000
Time
11:37:05
11:37:09
11:37:11
Element: Ni Seq. No.: 5
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
Repl
SampleConc StndConc
mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
446.30
Peak
Area
0.079
0.078
0.078
Bkgnd
Area
0.000
0.000
0.000
Time
11:37:16
11:37:18
11:37:20
Element: Ni Seq. No.: 6
Sample ID: CAL STD
AS Loc.
Date: 01/05/2006
.BlnkCorr
Signal
-0.160
-0.161
-0.162
-0.161
0.001
0.67
Peak
Area
-0.081
-0.083
-0.084
Bkgnd
Area
0.168
0.170
0.171
Time
13,: 37: 55
11:37:57
11:38:00
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
Nfcalibration because standard abs.' and cone, values are not in the same order.
Standard number 1 not applied. []
Element: Ni Seq. No.: 7
Sample ID: Calib Blank
AS Loc.
Date: 01/05/2006
SampleConc
mg/L
Repl
#
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
StndConc
mg/L
BlnkCorr
Signal
-0.172
-0.172
-0.172
-0.172
0.000
0.04
Peak
Area
-0.093
-0.093
-0.093
Bkgnd
Area
0.170
0.170
0.169
Time
11:38:17
11:38:19
11:38:21
Page 2
-------
=== _ _____ 01/05/2006
Element: Ni Seq. No.: 8 AS LOG..
Sample ID: Calib Blank
Bkgnd Time
Area
0.169 11:38:30
0.169 11:38:32
0.170 11:38:34
Repl
#
I
0
3
Mean
SD
%RSD
SampleConc StndConc
mg/L mg/L
.
.
.
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
91.65
Peak
Area
-0.093
-0.093
-0.094
Auto-zero performed.
AS Loo.: — Date: 01/05/2006
Sample ID: CAL STD ____________________________
Repl slmpleconc StndConc BlnkCorr Peak Bkgnd Time
* -" -"1 SJ?SS -o"B5 "?172 .1:33:50
J 0.009 -0.085 0.172 11:38:52
3 0.009 -0.085 0.172 11:38:54
Mean:
SD : 0.000
%RSD: 1.45
Standard number 1 applied. [0,25] en ^~. n n^4Q
Correlation Coefficient: 1.0000 Slope. 0.0349
T No.: 10 AS Loc.: — Date: 01/05/2006
Sample ID: cal std 2 _____________________________
Repl SampleConc StndConc BlnkCorr Peak Bkgnd Time
_
i 0,019 -0.075 0.172 11:39:30
3 0.019 -0.075 0.172 11:39:32
Mean: 0.019
SD : °-000
%RSD: °'23
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9957 Slope: 0.0371
M Seq. No.: 11 AS Loc.:— Date: 01/05/2006
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr Peak Bkgnd Time
, _/L »9/L Signal _A».< Area^ ^^
, 0.039 -0.054 0.173 11:40:03
3 0.039 -0.054 0.173 11:40:05
Mean: 0.039
SD : °-°00
%RSD: O-30
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9981 Slope: 0.0388
Page 3
-------
Element: Ni Seq. No.: i:
Sample ID: cal std 4
Repl SampleConc StndCon>
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient:
— , =
2 AS LOG. :
c BlnkCorr Peak
Signal Area
0.080 -0.013
0.080 -0.014
0.079 -0.014
0 080
0. 000
0.58
[2.00]
0.9995
Date: ui/uo/^uuu
Bkgnd Time
Area
0.173 11:40:32
0.173 11:40:35
0.173 11:40:37
Slope: 0.0396
t-v j_ . ni/nc:/Of\n£
Element: Ni Seq. No.: 13 AS Loc.
Sample ID: cal std 5
Repl
#
1
2
3
Mean
SD
%RSD.
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9998
Date:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
0.190
0.193
0.191
0.191
0.002
0.82
Peak
Area
0.097
0.100
0.097
Bkgnd
Area
0.175
0.175
0.175
Time
11:41:03
11:41:05
11:41:07
Slope: 0.0385
o>
u
(0
0.20
0.15
0.10
0.05
Concentration
Page 4
-------
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0,000
0.009
0.019
0.039
0.080
0.191
Entered Calculated
Concentration Concentration
(mg/L) (mg/L)
0.000
Correlation Coefficient: 0.99976
0.25
0.50
1.00
2.00
5.00
Slope:
0.2263
0.4880
.022
,072
.968
0.03850
Standard
Deviation
0.0001
0.0001
0.0000
0.0001
0.0005
0.0016
%RSD
91.6515
1.4487
0.2288
0.2985
0.5762
0.8188
Element: Ni Seq. No.: 14
AS Loc.
Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4.993
4.941
4.991
4.975
0.0293
0.59
StndConc
mg/L
4.993
4.941
4.991
4/975
0.0293
0.59
BlnkCorr
Signal
0.192
0.190
0.192
0.192
0.001
0.59
Peak
Area
0.099
0.097
0.099
Bkgnd
Area
0.175
0.175
0.174
Time
11:41:21
11:41:23
11:41:25
No.: 15
AS Loc.
Date: 01/05/2006
Repl
#
i
-L
0
<£.
3
Mean:
.SD :
%RSD:
SampleConc
mg/L
2.084
2. 074
2.083
2.080
0.0057
0.27
StndConc
mg/L
2.084
2.074
2.083
2.080
0.0057
0.27
BlnkCorr
Signal
0.080
0
0
0
0
.080
.080
.080
.000
0.27
Peak
Area
-0.013
-0.
-0.
014
013
Bkgnd
Area
0.173
0.
0.
173
174
Time
11:41:
11:
11:
41:
41:
47
49
51
No.: 16
AS Loc.:
Date: 01/05/2006
Repl
#
1
JL
Sample
o
£*
Sample
Q
O
Sample
Mean:
SD :
arjqn •
O i\KJ LJ .
Sample
SampleConc
mg/L
9 . 064
absorbance
9. 159
absorbance
9. 187
absorbance
9.137
0.0644
0.71
absorbance
S
m
is
is
is
is
tndConc
g/L
9.064
greater
9.159
greater
9.187
greater
9.137
0.0644
0.71
greater
Blnk'
Sig:
0.
than
0.
than
0.
than
0.
0.
0
than
Corr
rial
349
that
353
that
354
that
352
002
.71
that
Pe
Ar
0.
of
0.
of
0.
of
of
ak
ea
256
the
259
the
260
the
the
Bkgnd
Area
0.17
highest
0.17
highest
0.17
highest
highest
6
st
6
st
7
st
st
Time
11:42:
andard.
11:42:
andard.
11:42:
andard.
:andard.
13
15
17
Page 5
-------
No.: 17
AS LOG.
Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0624
-0.0536
-0.0673
-0.0611
0.0070
11.39
===========— ~
StndConc
mg/L
-0.0624
-0.0536
-0.0673
-0.0611
0.0070
11.39
BlnkCorr
Signal
-0.002
-0.002
-0.003
-0.002
0. 000
11.39
Peak
Area
-0.096
-0.095
-0.096
Bkgnd
Area
0.171
0.171
0.172
Time
11:43:44
11:43:46
11:43:48
_
No.: 18
AS Loc.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ecu
SampleConc
mg/L
-0.0525
-0.0570
-0.0445
-0.0514
0.0063
12.33
StndConc
mg/L
-0.0525
-0.0570
-0.0445
-0.0514
0.0063
12.33
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0. 000
12.33
Peak
Area
-0.095
-0.096
-0.095
Bkgnd
Area
0.171
0.171
0.170
Ti
11:
11:
11:
me
45:
45:
45:
51
53
55
Element: Ni Seq.
Sample ID: Sample
No.: 19
Repl
SampleConc StndConc
mg/L mg/L
1 -0.0485 -0.0485
Auto-zero performed.
AS Loc.:
BlnkCorr Peak
Signal Area
-0.002 -0.095
Date: 01/05/2006
Bkgnd Time
Area
0.170 11:46:00
Element: Ni Seq. No.: 20
AS Loc.
Date: 01/05/2006
sample .
Repl i
# '1
1
2
3
Mean :
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
ng/L
-0.0030
-0.0078
0.0000
-0.0036
0.0039
109.9
: Ni Seq
ID: 0.05 pp
SampleConc
mg/L
0.0273
0.0198
0.0271
0.0247
0.0043
17.24
StndConc
mg/L
-0.0030
-0.0078
0.0000
-0.0036
0.0039
109.9
. No. : 21
m
StndConc
mg/L
0.0273
0.0198
0.0271
0.0247
0.0043
17.24
BlnkCorr
Signal
0.000
.0 . 000
0.000
0.000
0.000
109.95
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.24
Peak
Area
-0.095
-0.096
-0.095
Loc. :
Peak
Area
-0.094
-0.095
-0.094
Bkgnd
Area
0.171
0.171
0.171
Date:
Bkgnd
Area
0.172
0.172
0.172
Time
11:46:12
11:46:14
11:46:16
01/05/2006
, , — '
Time
11:46:43
11:46:45
11:46:47
Page 6
-------
Element: Ni Seq. No.: 22
AS LOG.
Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
T?1 ornf^n
ID: ccb
SampleConc
mg/L
-0.0356
-0.0158
-0.0321
-0.0279
0.0106
37.97
t- ; Ni Sec
StndConc
mg/L
-0.0356
-0.0158
-0.0321
-0.0279
0.0106
37.97
r. No. : 23
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
37,97
AS
Peak
Area
-0.097
-0.096
-0.097
LOG. :
Bkgnd
Area
0.171
0.171
0.171
Date:
Time
11:47
11:47
11:47
:05
:07
:09
01/05/2006
Sample ID: 0.10 ppm
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0813
0.0829
0.0829
0.0823
0.0009
1.10
StndConc
mg/L
0.0813
0.0829
0.0829
0.0823
0.0009
1.10
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
1.10
Peak
Area
-0.092
-0.092
-0.092
Bkgnd
Area
0.171
0.171
0.171
Time
11:47:35
11:47:38
11:47:40
Element: Ni Seq. No.: 24
AS Loc.
Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0186
-0.0233
-0.0207
-0.0208
0.0023
11.27
StndConc
mg/L
-0.0186
-0. 0233
-0.0207
-0.0208
0.0023
11.27
BlnkCorr Peak
Signal Area
-0.001 -0.096
Ofini — n OQ 6
»UUJ- \j •
-------
Element: Ni Seq. No.: 26
Sample ID: ccb
AS LOG.
Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0408
-0.0439
-0.0443
-0.0430
0.0019
4.45
StndConc
mg/L
-0.0408
-0.0439
-0.0443
-0.0430
0.0019
4.45
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
4.45
Peak
Area
-0.097
-0.097
-0.097
Bkgnd
Area
0.169
0.169
0.169
Time
11:50:50
11:50:52
11:50:54
Element: Ni Seq. No.: 27
AS LOG.
Date: 01/05/2006
aampxe
Repl
#
1
2
3
Mean:
SD :
%RSD:
j.u . -LJ-J-I
SampleConc
mg/L
-0.0273
-0.0226
-0.0198
-0.0232
0.0038
16.26
StndConc
mg/L
-0.0273
-0.0226
-0.0198
-0.0232
0.0038
16.26
BlnkCorr
Signal
-0.001
-0,001
-0.001
-0.001
0.000
16.26
Peak
Area
-0.096
-0.096
-0.096
Bkgnd
Area
0.170
0.170
0.169
Ti:
11:
11:
11:
-1 /AC
me
51:
51:
51:
/or
41
44
46
lAC
Element: Ni Seq. No.: 28
AS Loc.
Ddmp-LC:
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0.0071
-0.0078
-0.0021
-0.0057
0.0031
55.13
StndConc
mg/L
-0.0071
-0 . 0078
-0.0021
-0.0057
0.0031
55.13
BlnkCorr Peak
Signal Area
0.000 -0.096
On nn — n OQfi
. U U U \j * \J ^ \J
0.000 -0.095
0.000
0.000
55.13
Bkgnd Time
Area
0.167 11:52:23
0.167 11:52:25
0.167 11:52:27
No.: 29
AS Loc.
Date: 01/05/2006
Repl
# :
1
-L
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1 . 073
1.073
1.054
1.067
0.0110
1.03
StndConc
mg/L
1.073
1.073
1.054
1.067
0.0110
1.03
BlnkCorr Peak
Signal Area
0.041 -0.054
0.041 -0.054
0.041 -0.055
0.041
0.000
1.03
Bkgnd Time
Area
0.169 11:52:49
0.170 11:52:51
0.170 11:52:53
Page 8
-------
30
AS LOG.
Date: 01/05/2006
Repl SampleConc
# mg/L
1 -0.0330
2 -0.0349
3 -0.0403
Mean: -0.0361
SD : 0.0038
%RSD: 10.49
Element : Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 -0.0466
StndConc
mg/L
-0.0330
-0.0349
-0.0403
-0.0361
0.0038
10.49
. No. : 31
StndConc
mg/L
-0.0466
BlnkCorr Peak
Signal Area
-0.001 -0.097
-0.001 -0.097
-0.002 -0.097
-0.001
0.000
10.49
AS LOG. :
BlnkCorr Peak
Signal Area
-0.002 -0.097
Bkgnd Time
Area
0.168 11:53:11
0.169 11:53:13
0.168 11:53:15
Date: 01/05/2006
Bkgnd Time
Area
0.169 11:53:21
Auto-zero performed.
Element: Ni Seq. No.: 32
AS Loc.
Date: 01/05/2006
Repl
1
7
i£<
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0019
0. 0080
0.0068
0.0043
0.0054
126.0
StndConc
mg/L
-0.0019
0.0080
0.0068
0.0043
0.0054
126.0
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
126.02
Peak
Area
-0.097
-0.097
-0.097
Bkgnd
Area
0.169
0.169
0.168
Time
11:53:
11:53:
11:~"
53:
29
31
33
No.: 33
AS Loc.
Date: 01/05/2006
Repl SampleConc StndConc BlnkCorr Peak Bkgnd Time
& mcr/L mq/L Signal Area Area
? 0 ,106 I 6106 0024 -0.074 0.172 11:54:02
7
3
Mean:
SD :
%RSD:
0.
0.
0.
0.
6184
6210
6167
0054
0.88
0.
0.
0.
0.
6184
6210
6167
0054
0.88
0
0
0
0
.024 -0.073 0.172 11:54:04
.024 -0.073 0.171 11:54:06
.024
.000
0.88
Element: Ni Seq. No.: 34
AS Loc.
Date: 01/05/2006
Repl
#
]_
2
3
Mean:
3D :
%RSD:
SampleConc
mg/L
0. 0512
0.0382
0.0533
0.0476
0.0082
17.21
StndConc
mg/L
0.0512
0.0382
0.0533
0.0476
0.0082
17.21
BlnkCorr Peak
Signal Area
0.002 -0.095
0.001 -0.096
0.002 -0.095
0.002
0.000
17.21
Bkgnd Time
Area
0.166 11:56:01
0.167 11:56:03
0.166 11:56:05
Page 9
-------
Element: Ni Seq.
Sample ID: d201-l
Repl SampleConc
# mg/L
1 0.6243
2 0.6255
3 0.6219
Mean: 0.6239
SD : 0.0019
%RSD: 0.30
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0109
2 0.0099
3 0.0075
Mean: 0.0094
SD : 0.0018
%RSD: 18.89
Element: Ni Seq.
Sample ID: $201-1
Repl SampleConc
# mg/L
1 1.497
3 1.513
Mean: 1.509
SD : 0.0107
%RSD: 0.71
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0422
2 0.0453
3 0.0412
Mean: 0.0429
SD : 0.0022
%RSD: 5.06
No.: 35
StndConc
mg/L
0.6243
0.6255
0.6219
0.6239
0.0019
0.30
No.: 36
StndConc
mg/L
0.0109
0.0099
0.0075
0.0094
0.0018
18.89
. NO. : 37
StndConc
mg/L
1.497
1 R 1 *7
1.513
1.509
0.0107
0.71
. No. : 38
StndConc
mg/L
0.0422
0.0453
0.0412
0.0429
0.0022
5.06
AS LOG. :
BlnkCorr Peak
Signal Area
0.024 -0.073
0.024 -0.073
0.024 -0.073
0.024
0.000
0.30
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
18.89
AS Loc. :
BlnkCorr Peak
Signal Area
0.058 -0.039
0 Q5Q _Q 039
0.058 -0.039
0.058
0.000
0.71
AS Loc. :
BlnkCorr Peak
Signal Area
0. 002 . -0.095
0.002 -0.095
0.-002 -0.096
0.002
0.000
5.06
Date: 01/05/2006
Bkgnd Time
Area
0.170 11:56:34
0.171 11:56:36
0.171 11:56:38
Date: 01/05/2006
Bkgnd Time
Area
0.167 11:58:31
0.167 11:58:34
0.167 11:58:36
Date: 01/05/2006
Bkgnd Time
Area
0.170 11:58:55
0.170 11:58:57
0.169 11:58:59
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:00:03
0.167 12:00:05
0.167 12:00:07
Page 10
-------
Element: Ni Seq. No.: 39
Sample ID: ser201-l
AS LOG.
Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.3399
0.3356
0.3309
0.3355
0.0045
1.35
StndConc
mg/L
0.3399
0.3356
0.3309
0.3355
0.0045
1.35
BlnkCorr
Signal
0.013
0.013
0.013
0.013
0.000
1.35
Peak
Area
-0.084
-0.084
-0.084
Bkgnd
Area
0.169
0.168
0.169
Time
12:00:54
12:00:56
12:00:58
Element: Ni Seq. No.: 40
AS Loc.
Date: 01/05/2006
OdXllp-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0031
0.0035
-0.0017
-0.0005
0.0035
751.2
StndConc
mg/L
-0.0031
0.0035
-0.0017
-0.0005
0.0035
751.2
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
751.25
Peak
Area
-0.097
-0.097
-0.097
Bkgnd
Area
0.168
0.168
0.168
Time
12:02:05
12:02:07
12:02:09
- >- ======
No.: 41
AS Loc.
Date: 01/05/2006
Repl
# :
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.4000
n "3 Q Q1
0.3999
0.3999
0.0002
0.04
StndConc
mg/L
0.4000
0 -5QQ7
0.3999
0.3999
0.0002
.0.04
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.015 -0.082 0.171 12:02:30
0.015 -0.082 0.171 12:02:32
0.015 -0.082 0.171 12:02:34
0.015
0.000
0.04
Element: Ni Seq. No.: 42
AS Loc.
Date: 01/05/2006
Repl
#
i
J,
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0-0023 0.0023 0.000
0
-0
0
0
.0017
.0040
.0000
.0035
9.632E+14
0.
-0.
0.
0.
0017
0040
0000
0035
9.632E+14
0
0
0
0
.000
.000
.000
.000
Peak
Area
-0.097
-0.
-0.
962646678436614
097
097
.50
Bkgnd Time
Area
0.169 12:02:56
0.169 12:02:58
0.169 12:03:01
Page 11
-------
Element: Ni Seq.
Sample ID: 201-3
Repl SampleConc
# mg/L
1 0.5461
2 0,5548
3 0.5406
Mean: 0.5472
SD : 0.0072
%RSD: 1.31
Element: Ni Seq,
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0109
2 0.0361
3 0.0606
Mean: 0.0359
SD : 0.0248
%RSD: 69.20
Element: Ni Seq
Sample ID: 201-4
Repl SampleConc
# mg/L
1 0.0582
2 0.0493
3 0.0462
Mean: 0.0512
SD : 0,0062
%RSD: 12.13
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0361
2 0.0340
3 0.0375
Mean: 0.0359
SD : 0.0017
%RSD: 4.87
No.: 43
StndConc
mg/L
0.5461
0.5548
0.5406
0.5472
0.0072
1.31
. No. : 44
StndConc
mg/L
0.0109
0.0361
0.0606
0.0359
0.0248
69.20
. No. : 45
StndConc
mg/L
0.0582
0.0493
0.0462
0.0512
0.0062
12.13
.No.: 46
StndConc
mg/L
0.0361
0.0340
0.0375
0.0359
0.0017
4.87
AS Loc. :
BlnkCorr Peak
Signal Area
0.021 -0.076
0.021 -0.076
0.021 -0.076
0.021
0.000
1.31
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.001 -0.096
0.002 -0.095
0.001
0.001
69.20
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.095
0.002 -0.095
0.002 -0.095
0.002
0.000
12.13
AS Loc.:
BlnkCorr Peak
Signal Area
0,001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
4.87
Date: 01/05/2006
Bkgnd Time
Area
0.171 12:03:20
0.171 12:03:22
0.171 12:03:24
Date: 01/05/2006
Bkgnd Time
Area
0.168 12:03:43
0.167 12:03:45
0.166 12:03:47
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:04:07
0.169 12:04:09
0.170 12:04:11
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:04:25
0.167 12:04:28
0.167 12:04:30
Page 12
-------
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.5743
2 0.5901
3 0.5878
Mean: 0.5841
SD : 0.0085
%RSD: 1-46
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0549
2 0.0212
3 0.0181
Mean: 0.0314
SD : 0.0204
%RSD: 65.06
Element : Mi Seq
Sample ID: Irb af
Repl SampleConc
# mg/L
1 -0.0327
o -o 0?76
3 -0.0307
Mean: -0.0303
SD : 0.0025
%RSD: 8.38
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0033
2 -0.0096
3 -0.0007
Mean: -0.0045
SD : 0.0046
%RSD: 100.8
No.: 47
StndConc
mg/L
0.5743
0.5901
0.5878
0.5841
0.0085
1.46
. No . : 48
StndConc
mg/L
0.0549
0.0212
0.0181
0.0314
0.0204
65.06
. No.: 49
StndConc
mg/L
-0.0327
-0.0276
-0.0307
-0.0303
0.0025
8.38
. No.: 50
StndConc
mg/L
-0.0033
-0.0096
-0.0007
-0.0045
0,0046
100.8
AS Loc. :
BlnkCorr Peak
Signal Area
0.022 -0.075
0.023 -0.074
0.023 -0.074
0.022
0.000
1.46
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.095
0.001 -0.096
0.001 -0.096
0.001
0.001
65.06
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.098
-0.001 -0.098
-0.001 -0.098
-0.001
0.000
8.38
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
100.81
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:04:54
0.167 12:04:56
0.167 12:04:58
Date: 01/05/2006
Bkgnd Time
Area
0.165 12:05:30
0.167 12:05:32
0.167 12:05:34
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:06:14
0.170 12:06:16
0.170 12:06:18
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:06:40
0.169 12:06:42
0.169 12:06:44
Page 13
-------
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 0.7627
2 0.7591
3 0.7634
Mean: 0.7618
SD : 0.0023
%RSD: 0.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 -0.0033
3 0.0002
Mean: -0.0014
SD : 0.0017
%RSD: 120.8
Element: Ni Seq
Sample ID: 325-1
Repl SampleConc
# mg/L
1 0.0351
9 0. D38Q
• 3 0.0346
Mean: 0.0362
SD : 0.0024
%RSD: 6.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0118
2 0.0047
3 0.0101
Mean: 0.0089
SD : 0.0037
%RSD: 41.92
. No. : 51
StndConc
mg/L
0.7627
0.7591
0.7634
0.7618
0.0023
0.31
. No. : 52
StndConc
mg/L
-0.0012
-0.0033
0.0002
-0.0014
0.0017
120.8
. No. : 53
StndConc
mg/L
0.0351
0. 0389
0.0346
0.0362
0.0024
6.55
. No.: 54
StndConc
mg/L
0.0118
0.0047
0.0101
0.0089
0.0037
41.92
AS :
BlnkCorr
Signal
0.029
0.029
0.029
0.029
0.000
0.31
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
120.80
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
6.55
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
41.92
Loc. :
Peak
Area
-0.068
-0.068
-0.068
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Loc. :
Peak
Area
-0.096
-0.096
-0.096
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Date: 01/05/2006
Bkgnd
Area
0.171
0.171
0.171
Date:
Bkgnd
Area
0.168
0.168
0.168
Date:
Bkgnd
Area
0.171
0.171
0.171
Date:
Bkgnd
Area
0.169
0.169
0.169
Time
12: 07: 10
12:07:13
12:07:15
01/05/2006
Time
12:07:55
12:07:57
12:07:59
01/05/2006
Time
12:08:17
12:08:19
12:08:21
01/05/2006
Time
12:08:37
12:08:39
12:08:41
Page 14
-------
Element: Mi Seq
Sample ID: d325-l
Repl SampleConc
# mg/L
1 0.0386
2 0.0519
3 0.0455
Mean: 0.0453
SD : 0.0067
%RSD: 14.75
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0281
2 0.0316
3 0.0278
Mean: 0.0292
SD : 0.0021
%RSD: 7.24
Element: Hi Seq.
Sample ID: s325-l
Repl SampleConc
# mg/L
1 1.033
2 1.041
3 1.025
Mean: 1.033
SD : 0.0081
%RSD: 0.78
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0054
2 0.0047
3 O.OQ63
Mean: 0.0054
SD : 0.0008
%RSD: 14.39
. No. : 55
StndConc
mg/L
0.0386
0.0519
0.0455
0.0453
0.0067
14.75
. No. : 56
StndConc
mg/L
0.0281
0.0316
0.0278
0.0292
0.0021
7.24
. No. : 57
StndConc
mg/L
1.033
1.041
1.025
1.033
0.0081
0.78
No.: 58
StndConc
mg/L
0.0054
0.0047
0.0063
0.0054
0.0008
14.39
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.096
0.002 -0.095
0.002 -0.095
0.002
0.000
14.75
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
7.24
AS Loc.:
BlnkCorr Peak
Signal Area
0.040 -0.057
0.040 -0.057
0.039 -0.058
0.040
0.000
0.78
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
14.39
Date: 01/05/2006
Bkgnd Time
Area
0.171 12:08:57
0.171 12:08:59
0.172 12:09:01
Date: 01/05/2006
Bkgnd Time
Area
0.168 12:09:38
0.168 12:09:40
0.168 12:09:42
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:10:53
0.170 12tlO:56
0.170 12:10:58
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:12:25
0.169 12:12:27
0.169 12:12:30
Page 15
-------
Element: Ni Seq.
Sample ID: ser325-l
Repl SampleConc
tt mg/L
1 0.2262
2 0.2286
3 0.2296
Mean: 0.2281
SD : 0.0018
%RSD: 0.78
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0069
2 0.0033
3 0.0078
Mean: 0.0060
SD : 0.0024
%RSD: 39.80
Element: Ni Seq.
Sample ID: 325-2
Repl SampleConc
# mg/L
1 0.2673
2 0.2708
: . 3 0.2734
! Mean: 0.2705
SD : 0.0031
%RSD: 1.13
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0111
2 0.0080
3 0.0054
Mean: 0.0082
SD : 0.0029
%RSD: 35.15
No . : 59
StndConc
mg/L
0.2262
0.2286
0.2296
0.2281
0.0018
0.78
No.: 60
StndConc
mg/L
0.0069
0.0033
0.0078
0.0060
0.0024
39.80
No.: €1
StndConc
mg/L
0.2673
0.2708
0.2734
0.2705
0.0031
1.13
No.: 62
StndConc
mg/L
0.0111
0.0080
0.0054
0.0082
0.0029
35.15
AS
BlnkCorr
Signal
0.009
0.009
0.009
0.009
0.000
0.78
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
39.80
AS
BlnkCorr
Signal
0.010
0.010
0.011
0.010
0.000
1.13
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
35.15
Loc. i
Peak
Area
-0.088
-0.088
-0.088
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Loc. :
Peak
Area
-0.087
-0.087
-0.087
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:12:51
0.169 12:12:54
0.169 12:12:56
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:13:50
0.169 12:13:52
0.169 12:13:54
Date: 01/05/2006
Bkgnd Time
Area
0.171 12:14:08
0.171 12:14:10
0.171 12:14:12
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:14:53
0.169 12:14:56
0.168 12:14:58
Page 16
-------
Element: Ni Seq
Sample ID: 325-3
Repl SampleConc
# mg/L
1 -0.0162
2 -0.0134
3 -0.0134
Mean: -0.0143
SD : 0.0016
%RSD: 11.22
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0281
2 0.0311
3 0.0288
Mean: 0.0294
SD : 0.0015
%RSD: 5.26
Element: Ni Seq
Sample ID: 325-4
Repl SampleConc
# mg/L
1 0.0566
2 0.05.00
3 0.0540
Mean: 0.0536
SD : 0.0033
%RSD: 6.21
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0301
2 0.0262
3 0.0396
Mean: 0.0320
SD : 0.0069
%RSD: 21.55
. No.: 63
StndConc
mg/L
-0.0162
-0.0134
-0.0134
-0.0143
0.0016
11.22
. No.: 64
StndConc
mg/L
0.0281
0.0311
0.0288
0.0294
0.0015
5.26
. No. : 65
StndConc
mg/L
0.0566
0.0500
0.0540
0.0536
0.0033
6.21
. No.: 66
StndConc
mg/L
0.0301
0.0262
0.0396
0.0320
0.0069
21.55
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.098
-0.001 -0.098
-0.001 -0.098
-0.001
0.000
11.22
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
5.26
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.095
0.002 -0.095
0.002 -0.095
0.002
0.000
6.21
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.002 -0.096
0.001
0.000
21.55
Date: 01/05/2006
Bkgnd Time
Area
0.171 12:15:13
0.171 12:15:15
0.171 12:15:17
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:15:41
0.167 12:15:44
0.167 12:15:46
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:16:07
0.170 12:16:09
0.170 12:16:11
Date: 01/05/2006
Bkgnd Time
Area
0.168 12:16:29
0.167 12:16:32
0.167 12:16:34
Page 17
-------
Element: Ni Seq
Sample ID: 325-5
Repl SampleConc
# mg/L
1 0.0832
2 0.0862
3 0.0794
Mean: 0.0829
SD : 0.0034
%RSD: 4.10
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0104
2 0.0061
3 0.0075
Mean: 0.0080
SD : 0.0022
%RSD: 27.75
Element: Ni Seq
Sample ID: 034-1
Repl SampleConc
# mg/L
1 0.1549
2 0.1577
3 0.1624
Mean: 0.1584
SD : 0.0038
%RSD: 2.38
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0099
2 0.0061
3 0.0127
Mean: 0.0096
SD : 0.0033
%RSD: 34.69
. No . : 67
StndConc
mg/L
0.0832
0.0862
0.0794
0.0829
0.0034
4.10
. No. : 68
StndConc
mg/L
0.0104
0.0061
0.0075
0.0080
0.0022
27.75
. No.: 69
StndConc
mg/L
0.1549
0.1577
0.1624
0.1584
0.0038
2.38
. No.: 70
StndConc
mg/L
O.OQ99
0.0061
0.0127
0.0096
0.0033
34.69
AS LOG. :
BlnkCorr Peak
Signal Area
0.003 -0.094
0.003 -0.094
0.003 -0.094
0.003
0.000
4.10
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
27.75
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 -0.091
0.006 -0.091
0.006 -0.091
0.006
0.000
2.38
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
34.69
Date: 01/05/2006
Bkgnd Time
Area
0.169 12:16:51
0.169 12:16:53
0.169 12:16:55
Date: 01/05/2006
Bkgnd Time
Area
0.168 12:17:17
0.168 12:17:19
0.168 12:17:21
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:17:53
0.170 12:17:56
0.170 12:17:58
Date: 01/05/2006
Bkgnd Time
Area
0.168 12:18:17
0.168 12:18:20
0.167 12:18:22
Page 18
-------
Element: Ni Seq
Sample ID: 034-2
Repl SampleConc
# mg/L
1 0.1518
2 0.1539
3 0.1603
Mean: 0.1553
SD : 0.0044
%RSD: 2.86
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0122
2 0.0061
3 -0.0026
Mean: 0.0052
SD : 0.0074
%RSD: 142.4
Element : Ni Seq
Sample ID: 034-3
Repl SampleConc
# mg/L
1 -0.0182
2 -0.0141
3 -0.0268
Mean: -0.0197
SD : 0.0065
%RSD: 32.83
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 -0.0023
3 0.0026
Mean: -0.0003
SD : 0.0026
%RSD: 884.5
. No. : 71
StndConc
mg/L
0.1518
0.1539
0.1603
0.1553
0.0044
2.86
. No.: 72
StndConc
mg/L
0.0122
0.0061
-0.0026
0.0052
0.0074
142.4
. No. : 73
StndConc
mg/L
-0.0182
-Q.0141
-0.0268
-0.0197
0.0065
32.83
. No.: 74
StndConc
mg/L
-0.0012
-0.0023
0.0026
-0.0003
0.0026
884.5
AS
BlnkCorr
Signal
0.006
0.006
0.006
0.006
0.000
2.86
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0,000
142.40
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
32.83
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
884.53
Loc. :
Peak
Area
-0.091
-0.091
-0.091
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Loc. :
Peak
Area
-0.098
-0.098
-0.09-8
Loc. :
Peak
Area
-0.097
-0.097
-0.097
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:18:41
0.170 12:18:44
0.170 12:18:46
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:19:08
0.167 12:19:11
0.167 12:19:13
Date: 01/05/2006
Bkgnd Time
Area
0.170 12:19:28
0.169 12:19:30
0.170 12:19:32-
Date: 01/05/2006
Bkgnd Time
Area
0.167 12:19:51
0.167 12:19:53
0.167 12:19:55
Page 19
-------
Element: Ni Seq.
Sample ID: ccv
No.: 75
AS LOG.
Date: 01/05/2006
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.165
2.182
2.172
2.173
0.0088
0.41
StndConc
mg/L
2.165
2.182
2.172
2.173
0.0088
0.41
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.083 -0.014 0.169 12:20:13
0.084 -0.013 0.169 12:20:15
0.084 -0.013 0.168 12:20:17
0.084
0.000
0.41
Element: Ni Seq.
Sample ID: ccb
No.: 76
AS Lo c.
Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
-0
0
0
.0082
.0024
.0002
.0035
.0043
122.8
StndConc
mg/L
0
0
-0
0
0
.0082
.0024
.0002
.0035
.0043
122.8
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
122.78
Peak
Area
-0.
-0.
-0.
097
097
097
Bkgnd
Time
Area
0.
0.
0.
166
167
167
12
12
12
:20:34
:20:36
:20:38
Page 20
-------
if351
p.
Set*
Prep Method: {check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:
MATRIX: (check only one per page)
DRINKING WATER
1
2
3
4
5
6
7
8
9
10
11
12
Set
Inif
u
Set
date
iltf
Set
time
II *f
^
^
t----^£-"
£~^. J, ' L^f
Lab#
4^ e>v U
llDluDl
Smp#
'fit*&
/
£
3
*^j
AQUEOUS
Company
LFB
LRB
&
4=R«**» lit
y^ tft>
^
&
OTHER:
' \
Aliquot
(mis)
Final
(mis)
5/0
\
1
K
'&^ '^^s
'
Mcr
Vsl#
/
(
"
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
ri>\
" i
LOT#
&T&£* \ \
Analyst:
Start Date:
S\QA FORMS XFM-041 \R02 \LK
Page 1 of 1
-------
PROJECT #2005100014: METHOD
1 2 34567
29 FOR NICKEL
8 9 10
11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19
23
24
22
26
27
25
29
30
28
32
33
31
35
36
34
38
39
37
SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
"s,'jm{3in§ei't ' *
filter- ",'
probe rinse
RUN ID
BLANK
»1
Cond. 18: Tes
#2
Cond. 18: Tes
#3
#1
#2
#3
#1
Cond. 20: Test
#2
#3
#1
#2
#3
' ^ * > r% ^--^
;'-'M0L' -•"
PH
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
•£•:*
Sample
Fraction
(SF = SFA)
296
1 filter
97.5
305
1 filter
100.0
311
1 filter
99.0
334
1 filter
97.0
315
1 filter
101.0
320
1 filter
100.0
313
1 filter
98.0
301
1 filter
96.0
301
1 filter
100.0
297
1 filter
100.0
'299
1 filter
98.0
303
1 filter
97.0
298
1 filter
99.0
^a
'M mer^
100.0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
2Q >
NA '
20
REAGENTS
FOR DIG.
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HN03
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HN03
HN03 + H2O2
HF + HN03
HF + HN03
HNO3 + H2O2
HF + HN03
HF + HN03
HN03 + H2O2
HF + HN03
HF + HNO3
HNO3 + H2O2
HF + HN03
HF + HN03
HNO3,*|i?'p|-
HF -tTHNO^
HF t HN03
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
';S^:2 ,
aB 2 :
8312
Analytical
Fraction
(AF = AFA)
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
'SOI - '
100
Nl mg/L
( Ca1 or Ca2 )
< 0.074
< 0.074
0.109
0.224
< 0.074
< 0.074
0.245
0.380
0.378
0.829
0.229
0.210
< 0.074
3.580
0.172
0.205
0.080
< 0.074
0,100
0.312
0.170
0.299
0.083
< 0.074
0.127
< 0.074
V-0,075
0.075
MGNI
IN INITIAL
SAMPLE
0.004
0.007
0.005
0.022
0.004
0.007
0.012
0.038
0.019
0.083
0.011
0.021
0.004
0.358
0.009
0.021
0.004
0.007
0.005
0.031
0.009
0.030
0.004
0.007
0.006
0.007
0.004
0.008
TOTAL MG
PER RUN
< 0.011
0.028
< 0.011
0.050
0.102
0.032
0.362
0.029
0.011
0.036
0.038
0.012
0.014
0.011
10 Samples that read
-------
PROJECT # 2005100306: METHOD 306A FOR NICKEL
8
SA#
1
2
3
4
5
*
SAMPLE DESCRPTION
Condition 29; Run 1
Condition 29; Run 2
Condition 29; Run 3
Field Blank 0.1 NHN03
Field Blank 5% HNO3 &
10% H202
' MDL
PH
<2.0
<2.0
<2.0
<2.0
<2.0
"<2:0
Sample
Fraction
355.0
356.0
378.0
332.0
288.0
288:0
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
HNO3
, HNCX=r \*
Analytical
Fraction
50.0
50.0
50.0
50.0
50.0
,'V"* '50.0*' '
\» < -
Nl mg/L
15.9
6.51
7.83
^ ': '" A074 ' : :
0.222
" 0.075^
TOTAL WIG Nl
(OR IN INITIAL SAMPLE)
0.795
0.326
0.392
" -y<'». '•'•'•" -^
:•: ••• 0,0.04 v • ••'•""*
0.011
0.004
Samples that read MDL,.so'that'these affected samples should result as*"< DL"
#8 Is the amount of Nl in the 50 ml aliquot, or the 355 ml original sample, whichever you prefer,
because they are the MG value will not change. (The volumes have been negated in the calculation.)
11/7/05LK
S/ LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 306
XI USEPA/ NICEM/ PROJECT 21 Analytical data/ METHOD 306-2
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
•"E5100 AA
i CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
Date:
Analyst:
11/8/2005
LK
(For Specific instrument settings, see current copy of method.)
(Mg/L)
IDL= 0.027
MDL= 0.075
RL s/aitb
LDR =0:16 to 8.0
3 CALIBRATION:
4 STANDARD TRACEABILITY
Cal Curve:
Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.287
0.568
1.161
2.151
4.885
0.9977
% Rec.
114.8
113.6
116.1
107.6
97.7
QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM
Standard Name, Company, & Lot #
CPI QC-21 41M044
CPI QC-21 41M044
CPI05F011
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
SAMPLE
CCV
QCS
CCB
CRA
014-1+3
014-1+3
SPK
DUP
SERDIL
014-25+27
014-31+33
014-31+33
014-31+33
014-31+33
014-2
SPK
DUP
SER OIL
306-1
306-1
306-1
306-1
306-1
CCV
CCB
STD CONG
5.00
2.00
0.10
0.75
2/10
1.00
2110
5.00
READING
Mg/L
4.875
2.014
-0.005
0.098
-0.138
-0.130 -
0.612
0.532
0.121
-0.117
-0.245
-0.171
-0.104
-0.120
0.081
1.048
0.999
0.312
29.570
11.960
5.818
3.046
1.688
4.766
0.056
BLK
-0.005
0.044
0.100
-0.100
0.009
-0.055
0.025
-0.072
-0.033
-0.062
0.073
-0.045
0.026
0.015
-0.014
0.075
0.025
0.121
0.008
0.101
0.056
RESULT
4.875
2.019
-0.005
0.054
-0.239
-0.030
0.603
0.588
0.096
-0.045
-0.212
-0.109
-0.177
-0.075
0.055
1.033
1.013
0.237
29.570
11.936
5.697
3.038
1.587
4.710
0.056
DILI
1.0
2.0
1.0
1.0
1.0
1.0
1.0
2.0
2.0
4.0
1.0
1.0
1.0
1.0
1.0
10.0
25.0
50.0
100.0
DIL2
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC
RESULTS
98
101
-0.005
54
112
2.6
20.2
111
2.0
14.6
94
0.056
Mg/L
-0239
-0.059 /
REP'T
mg/L
r™*^
<0,150 )
v^ ,^f'ff
ICP
(Apparently, cannot expect much better)
-0.045
I -0.212
-0.218
-0.354
-0.301
0.055
<0.100
<0.300
<0.100
£. , o '? 5*
(Apparently, cannot expect much better)
29.570
119.355
142.423
151.900
158.670
159
(80-120%R)
(«--10 RPD, IF SA > 20X MDL)
(<10%DIFF7?)
80-120%R)
<10RPD, IFSA>20XMDL)
<10%DIFF??}
90-110%R)
< MDL)
-------
Element: Ni Seq. No.: 142
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 143
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 144
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 145
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.132
0.000 -0.133
0.000
0.001
110.91
AS Loc. :
BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.005 -0.137
-0.004 -0.137
-0.004
0.000
2.03
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.136
0.001 -0.135
0.001 -0.136
0.001
0.000
26.84
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.135
0.001 -0.135
0.001 -0.135
0.001
0.000
11.87
Date: 11/08/2005
Bkgnd Time
Area
0.162 07:54:36
0.162 07:54:38
0.163 07:54:40
Date: 11/08/2005
Bkgnd Time
Area
0.166 07:55:17
0.167 07:55:20
0.167 07:55:22
Date: 11/08/2005
Bkgnd Time
Area
0.165 08:12:50
0.165 08:12:52
0.165 08:12:54
Date: 11/08/2005
Bkgnd Time
Area
0.163 08:19:40
0.163 08:19:42
0.163 08:19:44
Page 37
-------
Element: Ni Seq. No.: 146 AS LOG.:
Sample ID: Calib Blank
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.000 -0.135
2 0.000 -0.135
3 0.000 -0.135
Mean: 0.000
SD : 0.000
%RSD: 444.45
Auto-zero performed.
Element: Ni Seq. No.: 147 AS LOG.:
Sample ID: CAL STD
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.009 -0.126
2 0.010 -0.125
3 0.009 -0.126
Mean: 0.009
SD : 0.000
%RSD: 4.29
Standard number 1 applied. [0.25]
Correlation Coefficient: 0.9983
Element: Ni Seq. No.: 148 AS LOG.:
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.019 -0.116
2 0.018 -0.116
3 0.019 -0.116
Mean: 0.019
SD : 0.000
%RSD: 0.51
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9986
Element: Ni Seq. No.: 149 AS LOG.:
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.037 -0.098
2 0.038 -0.097
3 0.038 -0.097
Mean: 0.038
SD : 0.001
%RSD: 1.72
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9987
Date: 11/08/2005
Bkgnd Time
Area
0.162 08:20:03
0.162 08:20:05
0.162 08:20:07
Date: 11/08/2005
Bkgnd Time
Area
0.162 08:20:28
0.162 08:20:30
0.161 08:20:32
Slope: 0.0352
Date: 11/08/2005
Bkgnd Time
Area
0.161 08:20:46
0.161 08:20:48
0.161 08:20:50
Slope: 0.0351
Date: 11/08/2005
Bkgnd Time
Area
0.160 08:21:02
0.159 08:21:04
0.159 08:21:06
Slope: 0.0351
Page 38
-------
Element: Ni Seq. No.: 150
Sample ID: cal std 4
AS LOG.
Date: 11/08/2005
Repl SampleConc StndCon
# mg/L mg/L
1
2
3
Mean :
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient:
c BlnkCorr Peak
Signal Area
0.070 -0.065
0.070 -0.065
0.070 -0.065
0.070
0.000
0.64
[2.00]
0.9996
Bkgnd
Area
0.159
0.160
0.160
Slope:
Time
08:21:25
08:21:27
08:21:29
0.0347
Element: Ni Seq. No.: 151
Sample ID: cal std 5
AS Loc.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.159
0.159
0.159
0.159
0.000
0.11
Peak
Area
0.024
0.024
0.025
Bkgnd
Area
0.161
0.161
0.161
Time
08:21:44
08:21:47
08:21:49
The calibration curve may not be linear.
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9977
Slope: 0.0326
Ni
0)
u
o
U)
.0
0.20
0.15
0.10
0.05
Concentration
Page 39
-------
Calibration data for Ni
Entered Calculated
Mean Signal Concentration Concentration Standard
Standard ID (Absorbance) (mg/L) (mg/L) Deviation %RSD
Calib Blank 0.000 0.000 0.0002 444.4487
CAL STD 0.009 0.25 0.2870 0.0004 4.2884
cal std 2
cal std 3
cal std 4
cal std 5
Correlation Coefficient
0.019
0.038
0.070
0.159
: 0.99773
0.50
1.00
2.00
5.00
Slope:
0.5682 0.0001 0.5070
1.161 0.0007 1.7235
2.151 0.0004 0.6363
4.885 0.0002 0.1080
0.03261
Element : Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 4.857
2 4.888
3 4.879
Mean: 4.875
SD : 0.0158
%RSD: 0.32
Element: Ni Seq
Sample ID: QCS
Repl SampleConc
# mg/L
1 2.015
2 2.016
3 2.010
Mean: 2.014
SD : 0.0033
%RSD: 0.16
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0025
2 0.0019
3 -0.0194
Mean: -0.0050
SD : 0.0125
%RSD: 250.4
. No.: 152
StndConc
mg/L
4.857
4.888
4.879
4.875
0.0158
0.32
. No.: 153
StndConc
mg/L
2.015
2.016
2.010
2.014
0.0033
0.16
. No. : 154
StndConc
mg/L
0.0025
0.0019
-0.0194
-0.0050
0.0125
250.4
AS
BlnkCorr
Signal
0.158
0.159
0.159
0.159
0.001
0.32
AS
BlnkCorr
Signal
0.066
0.066
0.066
0.066
0.000
0.16
Loc. :
Peak
Area
0.023
0.024
0.024
Loc. :
Peak
Area
-0.069
-0.069
-0.069
AS LOG. :
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
250.39
Peak
Area
-0.135
-0.135
-0.136
Date: 11/08/2005
Bkgnd Time
Area
0.161 08:22:02
0.161 08:22:04
0.160 08:22:06
Date: 11/08/2005
Bkgnd Time
Area
0.163 08:22:19
0.163 08:22:21
0.163 08:22:23
Date: 11/08/2005
Bkgnd Time
Area
0.162 08:22:39
0.162 08:22:41
0.162 08:22:43
Page 40
-------
Element: Ni Seq
Sample ID: CRA-0.1
Repl SampleConc
# mg/L
1 0.0936
2 0.1051
3 0.0958
Mean: 0.0982
SD : 0.0061
%RSD: 6.20
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0382
2 0.0384
3 0.0548
Mean: 0.0438
SD : 0.0095
%RSD: 21.75
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 -0.1622
2 -0.1306
3 -0.1218
Mean: -0.1382
SD : 0.0212
%RSD: 15.38
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0960
2 0.1061
3 0.0989
Mean: 0.1004
SD : 0.0052
%RSD: 5.16
. No. : 155
StndConc
mg/L
0.0936
0.1051
0.0958
0.0982
0.0061
6.20
. No. : 156
StndConc
mg/L
0.0382
0.0384
0.0548
0.0438
0.0095
21.75
. No. : 157
StndConc
mg/L
-0.1622
-0.1306
-0.1218
-0.1382
0.0212
15.38
. No. : 158
StndConc
mg/L
0.0960
0.1061
0.0989
0.1004
0.0052
5.16
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.132
0.003 -0.132
0.003 -0.132
0.003
0.000
6.20
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.134
0.001 -0.134
0.002 -0.133
0.001
0.000
21.75
AS Loc. :
BlnkCorr Peak
Signal Area
-0.005 -0.140
-0.004 -0.139
-0.004 -0.139
-0.005
0.001
15.38
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.132
0.003 -0.131
0.003 -0.132
0.003
0.000
5.16
Date: 11/08/2005
Bkgnd Time
Area
0.162 08:23:10
0.161 08:23:13
0.161 08:23:15
Date: 11/08/2005
Bkgnd Time
Area
0.161 08:23:32
0.161 08:23:34
0.161 08:23:36
Date: 11/08/2005
Bkgnd Time
Area
0.182 08:24:09
0.181 08:24:12
0.181 08:24:14
Date: 11/08/2005
Bkgnd Time
Area
0.159 08:24:30
0.159 08:24:32
0.159 08:24:34
Page 41
-------
Element: Ni Seq. No.: 159
Sample ID: CCB
AS LOG.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0983
0.1120
0.1223
0.1109
0.0120
10.86
StndConc
mg/L
0.0983
0.1120
0.1223
0.1109
0.0120
10.86
BlnkCorr Peak
Signal Area
0.003 -0.132
0.004 -0.131
0.004 -0.131
0.004
0.000
10.86
Bkgnd Time
Area
0.158 08:27:22
0.158 08:27:24
0.158 08:27:26
Element: Ni Seq. No.: 160
Sample ID: Sample
AS LOG.
Date: 11/08/2005
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.1004 0.1004 0.003 -0.132
Auto-zero performed.
Bkgnd Time
Area
0.158 08:27:29
Element: Ni Seq. No.: 161
Sample ID: CCB
AS Loc.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0244
0.0047
0.0111
0.0134
0.0100
74.99
: Nor- --.-.., Seq.
ID: 014-1+a,..
SampleConc
mg/L
-0.1064
-0.1345
-0.1479
-0.1296
0.0211
16.32
StndConc
mg/L
0.0244
0.0047
0.0111
0.0134
0.0100
74.99
No.: 162
X2
X
StndConc
mg/L\
-0.1064
-0.1345
-0.1479\
-0.1296 \
0.0211 '
16.32
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
74.99
AS
BlnkCorr
Signal
-0.003
-0.004
-0.005
-0.004
s 0.001
\ 16.32
\
Peak
Area
-0.131
-0.132
-0.131
Loc. :
Peak
Area
-0.135
-0.136
-0.136
Bkgnd
Area
0.159
0.159
0.158
Date:
Bkgnd
Area
0.170
0.171
0.171
Time
08:27:37
08:27:39
08:27:41
11/08/2005
Time
08:28:09
08:28:11
08:28:13
Element: Ni Seq. No.: 163
Sample ID: CCB
AS Loc.
Date: 11/08/2005
Repl
. #
,1
2
\
Mean:
SD K.
%RSD:
SampleConc
mg/L
-0.
-0.
-0.
-0.
0.
0958
1025
1017
1000
0037
3.69
StndConc /BlnkCorr
mg/L
-0.
-0.
-0.
-0.
0.
0958
1025
1017 .
100 O/
0037
3. -6 9
/ Signal
/ -0.003
/ -0.003
•' -0.003
-0.003
0.000
3.69
Peak
Area
-0
-0
-0
.135
.135
.135
Bkgnd
Time
Area
0.
0.
0.
161
161
161
08
08
08
:28:49
:28:51
:28:53
Page 42
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: 014-1+3
SampleConc
mg/L
0.6075
0.6089
0.6208
0.6124
0.0073
1.19
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0160
0.0096
0.0016
0.0091
0.0072
79.12
: Ni Seq
ID: 014-1+3
SampleConc
mg/L
0.5500
0.5316
0.5154
0.5323
0.0173
3.26
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0515
-0.0562
-0.0584
-0.0554
0.0036
6.43
. No.: 164
X2 SPK
StndConc
mg/L
0.6075
0.6089
0.6208
0.6124
0.0073
1.19
. No. : 165
StndConc
mg/L
0.0160
0.0096
0.0016
0.0091
0.0072
79.12
. No.: 166
X2 SD
StndConc
mg/L
0.5500
0.5316
0.5154
0.5323
0.0173
3.26
. No.: 167
StndConc
mg/L
-0.0515
-0.0562
-0.0584
-0.0554
0.0036
6.43
AS
BlnkCorr
Signal
0.020
0.020
0.020
0.020
0.000
1.19
AS
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
79.12
AS
BlnkCorr
Signal
0.018
0.017
0.017
0.017
0.001
3.26
AS
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
6.43
LOG. :
/f^>
Peak
Area
-0.112
-0.112
-0.111
LOG. :
Peak
Area
-0.131
-0.131
-0.132
LOG. :
Peak
Area
-0.114
-0.114
-0.115
LOG. :
Peak
Area
-0.133
-0.133
-0.134
Date: 11/08/2005
uA •^V/'H- //*>
Bkgnd Time
Area
0.170 08:30:39
0.170 08:30:42
0.170 08:30:44
Date: 11/08/2005
Bkgnd Time
Area
0.158 08:31:00
0.158 08:31:02
0.158 08:31:04
Date: 11/08/2005
Bkgnd Time
Area
0.173 08:31:59
0.173 08:32:01
0.172 08:32:04
Date: 11/08/2005
Bkgnd Time
Area
0.160 08:32:24
0.160 08:32:26
0.160 08:32:28
Page 43
-------
Element: Ni Seq
Sample ID: 014-1+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1159
0.1103
0.1368
0.1210
0.0140
11.53
Element: Ni Seq
Sample ID: 014-1+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1571
0.1952
0.2223
0.1915
0.0328
17.11
Element: Ni Seq
Sample ID: CCB
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0246
0.0260
0.0236
0.0247
0.0012
5.00
. No.: 168
SER
StndConc
mg/L
0.1159
0.1103
0.1368
0.1210
0.0140
11.53
. No.: 169
SER
StndConc
mg/L
0.1571
0.1952
0.2223
0.1915
0.0328
17.11
. No. : 170
StndConc
mg/L
0.0246
0.0260
0.0236
0.0247
0.0012
5.00
Element: Ni Seq. No.: 171
Sample ID: 014-25+27
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.1021
-0.1148
-0.1325
-0.1165
0.0152
13.09
StndConc
mg/L
-0.1021
-0.1148
-0.1325
-0.1165
0.0152
13.09
AS
Loc . :
BlnkCorr Peak
Signal Area
0.004 -0.128
0.004
0.004
0.004
0.000
11.53
AS
BlnkCorr
Signal
0.005
0.006
0.007
0.006
0.001
17.11
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
5.00
-0.128
-0.127
Loc. :
Peak
Area
-0.127
-0.125
-0.124
Loc. :
Peak
Area
-0.131
-0.131
-0.131
AS LOG. :
BlnkCorr
Signal
-0.003
-0.004
-0.004
-0.004
0.000
13.09
.Peak
Area
-0.135
-0.135
-0.136
Date:
Bkgnd
Area
0.162
0.163
0.162
Date:
Bkgnd
Area
0.160
0.160
0.159
Date:
Bkgnd
Area
0.157
0.157
0.158
11/08/2005
Time
08:33:
08:33:
08:33:
02
05
07
11/08/2005
Time
08:33:
08:33:
08:33:
31
34
36
11/08/2005
Time
08:33:
08:33:
08:33:
54
56
59
Date: 11/08/2005
Bkgnd
Area
0.179
0.179
0.179
Time
08:34:
08:34:
08:34:
35
37
39
Page 44
-------
Element: Ni Seq. No.: 172
Sample ID: CCB
AS LOG.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2 ,•"
3/
Me.an :
SD :
%RSD:
Element
Sample
Rep\l
# \ /
1 \ /
2 A
'Mean :
jgfo :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0724
-0.0595
-0.0826
-0.0715
0.0116
16.24
: Ni Seq
StndConc
mg/L
-0.0724
-0.0595
-0.0826
-0.0715
0.0116
16.24
. No. : 173
BlnkCorr
Signal
-0.002
-0.002
-0.003
-0.002
0.000
16.24
_S
/ AS
Peak
Area
-0.134
-0.134
-0.134
Loc. :
Bkgnd Time
Area
0.161 08:34:54
0.160 08:34:56
0.160 08:34:58
Date: 11/08/2005
ID: 014-31+33 /
SampleConc
mg/L --.
-0.2463
-0.2430
-0.2453
-0.2449 /
0.0017 /
0.69/
: Ni / Seq
ID:/CCB
/
Ej.ampleConc/
mg/L
-0.0502 /
-0.0314/
-0.0168
,.-0.0,328
0"."0168
51.08
: Ni Seq
StndCq.nc
mg/L/
-0.^463
-0, 2430
/0.2453
/-0.2449
0.0017
0.69
j No. : 174
StndConc
mg/L
-0.0502
-0.0314
-0.0168
-0.0328
0.0168
51.08
. No. : 175
BlnkCorr
Signal
-0.008
-0.008
-0.008
-0.008
0.000
0.69
AS
BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.001
51.08
AS
Peak
Area
-0.140
-0.140
-0.140
Loc. :
Peak
Area
-0.133
-0.133
-0.132
Loc. :
Bkgnd Time
Area
0.186 08:35:31
0.186 08:35:34
0.186 08:35:36
Date: 11/08/2005
Bkgnd Time
Area
0.160 08:35:48
0.160 08:35:51
0.159 08:35:53
Date: 11/08/2005
ID: 014-31+33 X2
SampleConc
mg/L
-0.1678
-0.1850
-0.1593
-0.1707
0.0131
7.66
StndConc
mg/L
-0.1678
-0.1850
-0.1593
-0.1707
0.0131
7.66
BlnkCorr
Signal
-0.005
-0.006
-0.005
-0.006
0.000
7.66
Peak
Area
-0.137
-0.138
-0.137
Bkgnd Time
Area \^
0.175 08:38:2A
0.175 08:38:23\
0.176 08:38:26 \
Page 45
-------
Element
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0769
-0.0449
-0.0636
-0.0618
0.0161
26.00
: Ni Seq
. No. : 176
StndConc
mg/L
-0.0769
-0.0449
-0.0636
-0.0618
0.0161
26.00
. No.: 177
AS
BlnkCorr
Signal
-0.003
-0.001
-0.002
-0.002
0.001
26.00
AS
Loc.
: Date: 11/08/2005 \ .
Peak
Area
-0
-0
-0
Loc.
.134
.133
.134
Bkgnd
Area
0.160
0.160
0.160
Time
08:38:
08:38:
08:38:
\ 1 V S '
ho, i/^
43 / / f\r
46 /
48 / /
/
/
^/
: Date: 11/08/2005
rs.
ID: 014-31+33 2 M .J\ '
1 1 r,-A-!J¥>
SampleConc
mg/L
-0.0972
-0.1185
-0.0970
-0.1043
0.0124
11.87
: Ni Seq
ID: CCB
SampleConc
mg/L
0.1019
0.0765
0.0392
0.0725
0.0316
43.52
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0500
0.0556
0.0474
0.0510
0.0042
8.21
StndConc
mg/L
-0.0972
-0.1185
-0.0970
-0.1043
0.0124
11.87
.No.: 178
StndConc
mg/L
0.1019
0.0765
0.0392
0.0725
0.0316
43.52
. No.: 179
StndConc
mg/L
0.0500
0.0556
0.0474
0.0510
0.0042
8.21
BlnkCorr
Signal
-0.003
-0.004
-0.003
-0.003
0.000
11.87
AS
BlnkCorr
Signal
0.003
0.002
0. 001
0.002
0.001
43.52
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
8.21
Peak
~-?c
-0
-0
-0
Loc.
se^
.135-x
.136
.135
:
Peak
Area
-0
-0
-0
Loc.
.128
.129
.130
Bkgnd
Area
0.172
\0.172
""5^172
\
\
\
1
Date : 1
__J
Bkgnd /
Area /
0.15B
0.156
0./56
X
Time
08:39:
08:39:
08:39:
\
36
38
40 ,
\
\ JLLS -
jl/08/2005 \ (^7 n
1
Time
08:39:
08:40:
08: 40:
i\A _/ ^ .4 1
\ ^ \ fy /
V i \¥
59 \\f
01 rp
03 v
: Date: 11/08/2005
Peak
Area
-0
-0
-0
.130
.130
.130
Bkgnd
Area
0.156
0.157
0.157
Time
08:40:
08:40:
08:40:
18
20
23
Page 46
-------
Element: Ni Seq
. No. : 180
AS Loc. :
Date: 11/08/2005
Sample ID: 014-31+33 X4
Repl SampleConc
# mg/L
1 -0.1290
2 -0.1157
3 -0.1181
Mean: -0.1209
SD : 0.0071
%RSD: 5.87
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0509
2 -0.0330
3 -0.0507
Mean: -0.0448
SD : 0.0102
%RSD: 22.84
Element: Ni Seq
Sample ID: 014-2
Repl SampleConc
# mg/L
1 0.0806
2 0.0822
3 0.0785
Mean: 0.0805
SD : 0.0018
%RSD: 2.30
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0049
2 0.0234
3 0.0498
Mean: 0.0260
SD : 0.0226
%RSD: 86.67
StndConc
mg/L
-0.1290
-0.1157
-0.1181
-0.1209
0.0071
5.87
. No.: 181
StndConc
mg/L
-0.0509
-0.0330
-0.0507
-0.0448
0.0102
22.84
. No.: 182
StndConc
mg/L
0.0806
0.0822
0.0785
0.0805
0.0018
2.30
. No. : 183
StndConc
mg/L
0.0049
0.0234
0.0498
0.0260
0.0226
86.67
BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.004 -0.135
-0.004 -0.136
-0.004
0.000
5.87
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 -0.133
-0.001 -0.133
-0.002 -0.133
-0.001
0.000
22.84
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.129
0.003 -0.129
0.003 -0.129
0.003
0.000
2.30
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.131
0.001 -0.131
0.002 -0.130
0.001
0.001
86.67
Bkgnd Time
Area
0.169 08:41:32
0.168 08:41:34
0.168 08:41:36
Date: 11/08/2005
Bkgnd Time
Area
0.159 08:41:55
0.159 08:41:57
0.159 08:41:59
Date: 11/08/2005
Bkgnd Time
Area
0.160 08:42:29
0.160 08:42:31
0.160 08:42:34
Date: 11/08/2005
Bkgnd Time
Area
0.158 08:42:55
0.157 08:42:57
0.157 08:43:00
Page 47
-------
Element: Ni Seq
Sample ID: 014-2 S
Repl SampleConc
# mg/L
1 0.9949
2 1.005
3 0.9961
Mean: 0.9986
SD : 0.0054
%RSD: 0.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0117
2 0.0016
3 -0.0326
Mean: -0.0142
SD : 0.0173
%RSD: 121.4
Element: Ni Seq
Sample ID: 014-2 s:
Repl SampleConc
# mg/L
1 1.057
2 1.044
3 1.043
Mean: 1.048
SD : 0.0080
%RSD: 0.76
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0287
2 0.0121
3 0.0035
Mean: 0.0148
SD : 0.0128
%RSD: 86.84
. No. : 184
StndConc
mg/L
0.9949
1.005
0.9961
0.9986
0.0054
0.54
. No. : 185
StndConc
mg/L
-0.0117
0.0016
-0.0326
-0.0142
0.0173
121.4
. No. : 186
D
StndConc
mg/L
1.057
1.044
1.043
1.048
0.0080
0.76
. No. : 187
StndConc
mg/L
0.0287
0.0121
0.0035
0.0148
0.0128
86.84
AS LOG. :
BlnkCorr Peak
Signal Area
0.032 -0.099
0.033 -0.099
0.032 -0.099
0.033
0.000
0.54
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.132
0.000 -0.132
-0.001 -0.133
0.000
0.001
121.41
AS Loc. :
BlnkCorr Peak
Signal Area
0.034 -0.097
0.034 -0.098
0.034 -0.098
0.034
0.000
0.76
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.131
0.000 -0.131
0.000 -0.132
0.000
0.000
86.84
Date: 11/08/2005
Bkgnd Time
Area
0.162 08:44:53
0.162 08:44:55
0.162 08:44:57
Date: 11/08/2005
Bkgnd Time
Area
0.159 08:45:09
0.160 08:45:11
0.160 08:45:13
Date: 11/08/2005
Bkgnd Time
Area
0.161 08:45:35
0.161 08:45:37
0.161 08:45:39
Date: 11/08/2005
Bkgnd Time
Area
0.159 08:45:57
0.159 08:45:59
0.159 08:46:02
Page 48
-------
Element: Ni Seq. No.: 188
Sample ID: 014-2 SER
AS LOG.:
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.
3187
3136
3029
3117
0081
2.58
StndConc
mg/L
0.
0.
0.
0.
0.
3187
3136
3029
3117
0081
2.58
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
2
010 -0.121
010 -0.121
010 -0.122
010
000
.58
Bkgnd Time
Area
0.156 08:46:59
0.157 08:47:02
0.156 08:47:04
Element: Ni Seq. No.: 189
Sample ID: CCB
AS LOG.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.
0742
0781
0722
0749
0030
4.04
StndConc
mg/L
0.
0.
0.
0.
0.
0742
0781
0722
0749
0030
4.04
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.
0.
0.
0.
0.
4
002 -0.129 0.157 08:47:18
003 -0.129 0.156 08:47:20
002 -0.129 0.157 08:47:22
002
000
.04
Element: Ni Seq. No.: 190
Sample ID: 306-1
AS Loc.
Date: 11/08/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
29.56
absorbance
29.58
absorbance
29.58
absorbance
29.57
0.0111
0.04
absorbance
StndConc
mg/L
is
is
is
is
29.56
greater
29.58
greater
29.58
greater
29.57
0.0111
0.04
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
964
that
965
that
965
that
964
000
.04
that
Peak
Area
0.
of
0.
of
0.
of
of
832
the
833
the
833
the
the
Bkgnd
Area
0.177
highest
Time
08:48:
30
standard.
0.177
highest
08:48:
32
standard.
0.177
highest
highest
08:48:
34
standard.
standard.
Element: Ni Seq. No.: 191
Sample ID: 306-1 X10
AS Loc.
Date: 11/08/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
11.93
absorbance
12.02
absorbance
11.94
absorbance
11.96
0.0531
0.44
absorbance
StndConc
mg/L
11.93
is
is
is
is
greater
12.02
greater
11.94
greater
11.96
0.0531
0.44
greater
BlnkCorr
Signal
0.389
than
0.
than
0.
than
0.
0.
0
than
that
392
that
389
that
390
002
.44
that
Peak
Area
0.257
of
0.
of
0.
of
of
the
260
the
258
the
the
Bkgnd
Area
0.164
Time
08:55:
highest standard.
0.164 08:55:
highest standard.
0.164 08:55:
highest
highest
00
02
04
standard.
standard.
Page 49
-------
Element: Ni Seq. No.: 192
Sample ID: CCB
AS LOG.
Date: 11/08/2005
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0254
0.0119
0.0361
0.0245
0.0121
49.56
StndConc
mg/L
0.0254
0.0119
0.0361
0.0245
0.0121
49.56
BlnkCorr Peak
Signal Area
0.001 -0.131
0.000 -0.131
0.001 -0.130
0.001
0.000
49.56
Bkgnd Time
Area
0.157 08:56:26
0.158 08:56:28
0.158 08:56:30
Element: Ni Seq. No.:
Sample ID: 306-1 X25
193
AS LOG.
Date: 11/08/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.781
absorbance
5.852
absorbance
5.823
absorbance
5.818
0.0357
0.61
absorbance
StndConc
mg/L
5.781
is greater
5.852
is greater
5.823
is greater
5.818
0.0357
0.61
is greater
BlnkCorr
Signal
0.189
than that
0.191
than that
0.190
than that
0.190
0.001
0.61
than that
Peak Bkgnd Time
Area Area
0.057 0.160 08:56:48
of the highest standard.
0.059 0.159 08:56:50
of the highest standard.
0.058 0.159 08:56:52
of the highest standard.
of the highest standard.
Element: Ni Seq. No.: 194
Sample ID: CCB
AS LOG.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1366
0.1337
0.0929
0.1211
0.0244
20.18
StndConc
mg/L
0.1366
0.1337
0.0929
0.1211
0.0244
20.18
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.004 -0.127 0.154 08:57:06
0.004 -0.127 0.153 08:57:08
0.003 -0.129 0.155 08:57:10
0.004
0.001
20.18
Element: Ni Seq. No.
Sample ID: 306-1 X50
195
AS LOG.
Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.035
3.055
3.049
3.046
0.0104
0.34
StndConc
mg/L
3.035
3.055
3.049
3.046
0.0104
0.34
BlnkCorr Peak
Signal Area
0.099 -0.033
0.100 -0.032
0.099 -0.032
0.099
0.000
0.34
Bkgnd Time
Area
0.160 08:58:18
0.159 08:58:20
0.160 08:58:22
Page 50
-------
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0006
2 0.0160
3 0.0074
Mean: 0.0080
SD : 0.0077
%RSD: 96.38
Element : Ni Seq
. No. : 196
StndConc
mg/L
0.0006
0.0160
0.0074
0.0080
0.0077
96.38
. No. : 197
AS
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
96.38
AS
LOG. :
Peak
Area
-0.132
-0.131
-0.131
LOG. :
Date: 11/08/2005
Bkgnd Time
Area
0.159 08:58:35
0.159 08:58:37
0.158 08:58:39
Date: 11/08/2005
Sample ID: 306-1 X100
Repl SampleConc
# mg/L
1 1.687
2 1.676
3 1.701
Mean: 1.688
SD : 0.0123
%RSD: 0.73
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.1130
2 0.1169
3 0.0740
Mean: 0.1013
SD : 0.0237
%RSD: 23.40
Element: Ni Seq
Sample ko: CCV
Repl SampleConc/
# mg/L\ /
1 2 . uSfj
2 2.8^2^
3 2./33\
Mean: 2/311 \
SD : 0/4776
%RSD: /20. 67
StndConc
mg/L
1.687
1.676
1.701
1.688
0.0123
0.73
. No. : 198
StndConc
mg/L
0.1130
0.1169
0.0740
0.1013
0.0237
23.40
. No. : 199
s
/-
StndConc
mg/L
2.036
2.862
2.033
2.311
\fl.4776
20.67
BlnkCorr
Signal
0.055
0.055
0.055
0.055
0.000
0.73
Peak
Area
-0.077
-0.077
-0.076
AS LOG. :
BlnkCorr
Signal
0.004
0.004
0.002
0.003
0.001
23.40
Peak
Area
-0.128
-0.128
-0.129
ex AS LOG. : — -
V) tury1
BlnkCorr
Signal
0.066
0.093
0.066
0.075
0.016
20.67
WT 3
MPeak
Area
-0.065
-0.038
-0.065
Bkgnd Time
Area
0.157 09:00:56
0.157 09:00:58
0.157 09:01:00
Date: 11/08/2005
Bkgnd Time
Area
0.155 09:01:13
0.155 09:01:15
0.155 09:01:17
Date: 11/08/2005
CiA-j-vA-litLX
Bkgnd Time
Area
0.160 09:02:00
0.133 09:02:02
0.160 09:02:04
"
Page 51
-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -1.265
2 0.0057
3 0.0287
Mean: -0.4100
SD : 0.7401
%RSD: 180.5
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0267
2 0.0281
3 0.0090
Mean: 0.0213
SD : 0.0106
%RSD: 49.96
Element: Ni ,/'Seq
Sample ID: CCV
Repl SampleConc
# >g/L
1 / 4.763
2 / 4.753
3 / 4.782
Meap.: 4 . 766
SD / : 0.0145
%R$D: 0.30
Element: Ni Seq,
Sample ID: CCB
Repl SampleConc
# 1 mg/L
11 0.0533
2 \ 0.0708
3 \ 0.0429
Mean\: 0.0556
SD \ 0.0141
%RSD:\ 25.32
. No. : 200
StndConc
mg/L
-1.265
0.0057
0.0287
-0.4100
0.7401
180.5
. No. : 201
StndConc
mg/L
0.0267
0.0281
0.0090
0.0213
0.0106
49.96
. No. : 202
StndConc
mg/L
4.763
4.753
4.782
4.766
0.0145
0.30
. No. : 203
StndConc
mg/L
0.0533
0.0708
0.0429
0.0556
0.0141
25.32
AS
BlnkCon
Signal
-0.041
0.000
0.001
-0.013
0.024
180.50
AS
BlnkCon
Signal
0.001
0.001
0.000
0.001
0.000
49.96
'" -
AS
BlnkCorr
Signal
0.155
0.155
0.156
0.155
0.000
0.30
AS
BlnkCorr
Signal
0.002
0.002 ,
0.00 1/
0.002
0.-000
,x25 . 32
Loc. :
: Peak
Area
-0.173
-0.131
-0.131
Loc. :
: Peak
Area
-0.131
-0.131
-0.131
Loc. : ~~-==" — --•
Peak
Area
0.024
0.023
0.024
/
Loc. : / —
/
E*eak
/Area
/-0.130
/ -0.129
-0.130
Date: 11/08/2005
Bkgnd Time
Area
0.172 09:02:21
0.158 09:02:23
0.159 09:02:25
Date: 11/08/2005
Bkgnd Time
Area
0.158 09:02:42
0.158 09:02:44
0.158 09:02:46
.- Date: 11/08/2005
BJcgnd Time
Area
/ 0.160 09:03:03
/ 0.160 09:03:05
' 0.160 09:03:07
Date: 11/08/2005
Bkgnd Time
Area
0.157 09:03:24
0.156 09:03:26
0.156 09:03:29
Page 52
-------
METALS PREP FORM
Set*
Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER \ \ \ lAQUEOU
OTHER:
Set
Inifl
Set
date
Set
time
Lab#
Smp#
Company
Aliquot
(mis)
Final
(mis)
Mcr
Vsl#
LFB
LRB
I rrnfl ni IP
LI IV! LJ\Jl
5
10
11
1?
\
GSTDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
/'pl
LOT*
&S^o\\
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
QA/QC WORK SHEET for NICKE
FLAA METHOD SOP MET-040 A
PE5100AA ^1A
Date:
11/7/2005
Analyst: LK
* CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
INSTRUMENT SET-UP:
(For Specific instrument settings, see current copy of method.)
3 CALIBRATION:
(Mcj/U
IDL= 0.027
MDL= 0.075
RL = 0.10
LDR = 0.10 to 8.0
4 STANDARD TRACEABILITY
Cal Curve:
Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.324
0.601
1.102
2.144
4.897
0.9981
% Rec.
129.6
120.2
110.2
107.2
97.9
QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM
Standard Name, Company, &Lot#
CPIQC-21 41M044
CPIQC-21 41M044
CPI41M044
(> 0.995
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
LFB
014-1+3
SPK
DUP
SER DIL
CCB
CCV
014-4+6
014-7+9
014-10+12
014-13+15
014-16+18
014-19+21
CCB
CCV
014-22+24
014-25+27
014-28+30
014-31+33
014-34+36
014-37+39
CCB
CCV
LRB
LFB
014-2
SPK
DUP
SER DIL
CCB
CCV
STD CONG
500
200
0.25
0.10
3.50
3 5
3/10
1.00
050
'
t
\g/T
\?)/
wr
— T
200
200
4.0
5/10
5 00
READING
Mg/L
4 958
2.125
0.050
0323
0.178
0.043
3 337
-0.162
3.418
3469
1 082
0.010
0.921
0.241
-0.066
0.398
0.772,
0.247
3.526
-0.054
^ 0.465
i 0.133
*&> -0.168
0.272^
~X-0 168 )
-0.057
-0.124
0.015
2004
0080
1.876
0018
4.178
4239
2.494
-0075
4693
BLK
0.050
0.050
0039
0.090
0018
0.017
0013
0.104
-0.014
0.111
-0.049
-0.049
0.017
-0.045
0018
-0.058
0.038
-0 054
0.029
0029
-0.072
0.028
-0.040
0.011
-0.037
-0.077
-0062
-0.062
0026
0.026
0.012
-0.047
-0085
-0.074
-0.074
0 033
RESULT
4.909
2.076
0.050
0.284
0.088
0.025
3320
-0.175
3.314
3.483
0.971
0059
0969
0.224
-0.021
0.380
0.829
0.210
3.580
-0.083
0.436
0.205
-0.196
0.312
-0.180
-0019
-0046
0.077
2.066
0.054
1.850
0.007
4.225
4.324
2.568
-0.001
4.660
D1L1
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
DIL 2
1.0
10
10
10
10
10
1.0
1.0
10
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
QC RESULTS
98
' • 104
•0.050
114
88
0.025
95
100
5.0
24
0.010
97
-0.054
^ -87
0.015
103
0.054
93
105
2.3
' |1 0
(•0,075
93
Wlg/L
• -0.175
.,-- . O J aj
0.224
-0.021
0.380
0.829
0.210
3.580
REP'T
mg/L
^
. lS~a
0.224
<0.100
0.380
0.829
0.210
3.580
See explanation below
0.205
j. -Q/M. -;
0.312
-0.180 ,-
-0.019
-0.046
0.007
0.20§
<^foo
0.312
*/5
- , 3t> /
, CJ> -5
;95-105%R)
(95-105%R)
{< MDL )
(70-130%R)
(70-130%R)
(« MDL )
(80-120%R)
{< MDL )
(90-110%R)
iff.
(< MDL )
(90-110%R)
MDL )
(80-120%R)
(80-120%R )
(<10RPD, IFSA>
(<10%DIFF)
{< MDL)
(90-110%R)
The CCV at 0.50 ppm was low for indicated limits which is from SM 3111B. The previous CCV and following CCV were within limits. The limits for EPA is +/- 20%, for which
this would be acceptable. In view of these observations, the CCV being out of limits appears to be an isolated occurrance and does not reflect on the degradation of the
curve Therefore no corrective action was taken at this point. -.?=—•*>.
-""•"' "*
RERUN:
Due to failed SER \
Due to failed SER (see^p?)
-------
QA/QC WORK SHEET for NICKEL p2
FLAA METHOD SOP MET-040
PE5100 AA
i CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
'NSTRUMENT SET-UP:
(For Specific instrument settings, see current copy of method.)
Date:
Analyst:
11/7/2005
LK
(Mg/U
IDL= 0.027
MDL= 0.075
RL = 0.10
LDR = 0.10 to 8.0
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
SAMPLE
014-5
014-8
014-11
014-14
014-17
014-20
CCB
CCV
014-23
014-26
014-29
014-32
014-35
014-38
CCB
CCV
LRB
LFB
306-1
SPK
DUP
SERDIL
306-1
306-1
CCB
CCV
306-2
306-3
306-3
306-4
306-5
CCB
CCV
STD CONC
025
1.00
1.00
1.5
5/10
0.50
10.00
READING
Mg/L
0.061
0.028
0.183
0.349
0.185
-0034
0.045
0.198
0.136
0.119
0.069
0.127
0.069
0.143
-0.041
1.006
-0018
0.894
28.900
27.710
27.870
16.270
11.630
5.725
-0.030
0.494
6.587
24.450
3 069
-0.012
0.145
-0.076
10.090
BLK
-0.048
0.046
-0.062
-0.029
-0.044
0.019
0.019
-0.050
-0.036
0039
-0.031
-0.044
-0.014
0.015
0.051
0.051
-0.013
0.061
-0.096
0.146
0.008
-0.008
0.078
-0.030
0.062
-0.022
0.075
0.022
-0064
0.086
-0.076
RESULT
0.109
-0.018
0.245
0.378
0.229
-0.053
0.026
0.248
0.172
0.080
0.100
0.170
0.083
0.127
-0.092
0.955
-0.004
0.832
2ff396"\
f/27.5651
j 27.862 /
[ 16.278'
V1-1T552
5.755
-0.092
0.515
6.513
24.428
3.133
-0.098
0.222
-0.076
10.090
DILI
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0 .-"
1.0
10.0
25.0
1.0
1.0
25.0
1.0
1.0
DIL2
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
14 '
j.oK-u
T^WI.O
I 1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC RESULTS
0.045
99
-0.041
95
-0.004
f\ 83
w
Vs" 88
\ 1.1
''>, 18,1
-0.030
103
~M?M-:
101
Mg/L
0.109
-0.018
0.245
0.378
0.229
-0.053
0.172
0.080
0.100
0.170
0.083
0.127
28.996
115.516
143.875
6.513
24.428
78.335
-0.098
0.222
REPT
mg/L
0.109
<0.100
0.245
0.378
0.229
<0.100
0.172
<0.100
0.100
0.170
<0.100
0.127
J*f
6.51
78.335
<0.100
0.222
ICP
/ 5 j x-
So close, and last CCB, so accepted)
(< MOL)
(90-110%R')
'< MDL)
;90-110%R)
.< MDL)
; 80-120%R j
80-120%R }
'<10RPD, IFSAs
<10%D1FF)
MDL.)
{ 90-110%R)
-------
Method-Name: NI
Method Description: Nickel
Date: 11/07/2005
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 64
Results Data Set:
Element: Ni Seq. No.: 1
Sample ID: Calib Blank
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
-0.139
-0.138
-0.138
-0.138
0.000
0.14
Peak
Area
-0.139
-0.138
-0.138
Bkgnd
Area
0.167
0.166
0.166
Time
14:41:59
14:42:01
14:42:03
Auto-zero performed.
Element: Ni Seq. No.: 2
Sample ID: Calib Blank
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.001
0.000
0.001
0.001
0. 000
39.86
Peak
Area
-0.138
-0.138
-0.138
Bkgnd
Area
0.166
0.166
0.165
Time
14:42:
14:42:
14:42:
08
10
12
Auto-zero performed.
Element: Ni Seq. No.: 3
Sample ID: CAL STD
AS Loc.
Date: 11/07/2005
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1
StndConc
mg/L
applied.
Correlation Coefficient: 1
BlnkCorr
Signal
0.011
0.012
0.011
0.011
0.000
2.32
[0.25]
.0000
Peak
Area
-0.127
-0.126
-0.126
Bkgnd
Area
0.164
0.165
0.164
Slope:
Time
14:42:53
14:42:55
14:42:58
0.0456
Page 1
-------
Element: Ni Seq. No . : 4
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 5
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 6
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 7
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient: 0
AS LOG. :
BlnkCorr Peak
Signal Area
0.019 -0.119
0.019 -0.119
0.020 -0.118
0.019
0.000
1.94
[0.50]
.9717
AS Loc. :
BlnkCorr Peak
Signal Area
0.021 -0.117
0.021 -0.117
0.021 -0.117
0.021
0.000
0.83
[0.50]
.9952
AS Loc. :
BlnkCorr Peak
Signal Area
0.040, -0.098
0.039 -0.099
0.038 -0.100
0.039
0.001
2.58
[1.00]
.9948
AS Loc. :
BlnkCorr Peak
Signal Area
0.075 -0.063
0.076 -0.062
0.076 -0.062
0.075
0.001
0.94
[2.00]
.9983
Date: 11/07/2005
Bkgnd Time
Area
0.166 14:43:31
0.166 14:43:33
0.166 14:43:35
Slope: 0.0399
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:44:27
0.164 14:44:29
0.164 14:44:32
Slope: 0.0430
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:44:51
0.166 14:44:53
0.166 14:44:55
Slope: 0.0398
Date: 11/07/2005
Bkgnd Time
Area
0.166 14:45:13
0.166 14:45:15
0.166 14:45:17
Slope: 0.0383
Page 2
-------
Element: Ni Seq. No.:
Sample ID: cal std 5
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.171
0.173
0.173
0.172
0.001
0.77
Peak
Area
0.033
0.036
0.035
Bkgnd
Area
0.167
0.168
0.168
Time
14:45:42
14:45:44
14:45:46
The calibration curve may not be linear.
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9981
Slope: 0.0352
Mi
0.20
Concentration
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.011
0.021
0.039
0.075
0.172
Correlation Coefficient: 0.99808
Entered
Calculated
Concentration Concentration Standard
(mg/L)
0.25
0.50
1.00
2.00
5.00
Slope:
(mg/L)
0.000
0.3241
0.6010
1.102
2.144
4.897
0.03518
Deviation
0.0003
0.0003
0.0002
0.0010
0.0007
0.0013
%RSD
39.8601
2.3187
0.8347
2.5761
0.9419 '
0.7710
Page 3
-------
Element: Ni Seq.
Sample ID: CCV
Repl SampleConc
# mg/L
1 5.024
2 4.946
3 4.904
Mean: 4.958
SD : 0.0609
%RSD: 1.23
Element: Ni Seq.
Sample ID: QCS
Repl SampleConc
# mg/L
I 2.113
2 2.123
3 2.140
Mean: 2.125
SD : 0.0133
%RSD: 0.63
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0549
2 0.0540
3 0.0395
Mean: 0.0495
SD : 0.0086
%RSD: 17.44
Element: Ni • Seq.
Sample ID: CCV-0.25
Repl SampleConc
# mg/L
1 0.3323
2 0.3154
3 0.3213
Mean: 0.3230
SD : 0.0086
%RSD: 2.66
No. : 9
StndConc
mg/L
5.024
4.946
4.904
4.958
0.0609
1.23
No. : 10
StndConc
mg/L
2.113
2.123
2.140
2.125
0.0133
0.63
No.: 11
StndConc
mg/L
0.0549
0.0540
0.0395
0.0495
0.0086
17.44
No. : 12
StndConc
mg/L
0.3323
0.3154
0.3213
0.3230
0.0086
2.66
AS LOG. :
BlnkCorr Peak
Signal Area
0.177 0.039
0.174 0.036
0.173 0.035
0.174
0.002
1.23
AS Loc. :
BlnkCorr Peak
Signal Area
0.074 -0.063
0.075 -0.063
0.075 -0.063
0.075
0.000
0.63
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.136
0.002 -0.136
0.001 -0.136
0.002
0.000
17.44
AS Loc. :
BlnkCorr Peak
Signal Area
0.012 -0.126
0.011 -0.127
0.011 -0.126
0.011
0.000
2.66
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:46:00
0.165 14:46:02
0.165 14:46:04
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:46:24
0.164 14:46:26
0.165 14:46:29
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:46:51
0.164 14:46:53
0.165 14:46:55
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:47:14
0.165 14:47:16
0.164 14:47:18
Page 4
-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0433
2 0.0283
3 0.0458
Mean: 0.0392
SD : 0.0095
%RSD: 24.17
Element: Ni Seq
Sample ID: CRA-0.1
Repl SampleConc
# mg/L
1 0.1648
2 0.1816
3 0.1869
Mean: 0.1778
SD : 0.0115
%RSD: 6.47
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0821
2 0.0848
3 0.1040
Mean: 0.0903
SD : 0.0119
%RSD: 13.21
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 0.0477
. No. : 13
StndConc
mg/L
0.0433
0.0283
0.0458
0.0392
0.0095
24.17
. No. : 14
StndConc
mg/L
0.1648
0.1816
0.1869
0.1778
0.0115
6.47
. No. : 15
StndConc
mg/L
0.0821
0.0848
0.1040
0.0903
0.0119
13.21
. No.: 16
StndConc
mg/L
0.0477
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.136
0.001 -0.137
0.002 -0.136
0.001
0.000
24.17
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 -0.132
0.006 -0.131
0.007 -0.131
0.006
0.000
6.47
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.135
0.003 -0.135
0.004 -0.134
0.003
0.000
13.21
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.136
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:47:32
0.165 14:47:34
0.165 14:47:36
Date: 11/07/2005
Bkgnd Time
Area
0.163 14:47:58
0.163 14:48:00
0.162 14:48:02
Date: 11/07/2005
Bkgnd Time
Area
0.163 14:48:14
0.163 14:48:16
0.163 14:48:18
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:48:37
Auto-zero performed.
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0023
2 -0.0196
3 -0.0019
Mean: -0.0079
SD : 0.0101
%RSD: 127.5
. No. : 17
StndConc
mg/L
-0.0023
-0.0196
-0.0019
-0.0079
0.0101
127.5
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.136
-0.001 -0.137
0.000 -0.136
0.000
0.000
127.50
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:48:52
0.165 14:48:54
0.165 14:48:56
Page 5
-------
Element: Ni Seq
Sample ID: LRB
Repl SampleConc
# mg/L
1 0.0414
2 0.0342
3 0.0534
Mean: 0.0430
SD : 0.0097
%RSD: 22.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0017
2 0.0110
3 0.0443
Mean: 0.0179
SD : 0.0238
%RSD: 132.9
Element: Ni Seq
Sample ID: LFB
Repl SampleConc
# mg/L
1 3.326
2 3.343
3 3.340
Mean: 3.337
SD : 0.0091
%RSD: 0.27
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 - 0.0154
2 0.0272
3 0.0097
Mean: 0.0174
SD : 0.0089
%RSD: 51.18
. No. : 18
StndConc
mg/L
0.0414
0.0342
0.0534
0.0430
0.0097
22.54
. No. : 19
StndConc
mg/L
-0.0017
0.0110
0.0443
0.0179
0.0238
132.9
. No. : 20
StndConc
mg/L
3.326
3.343
3.340
3.337
0.0091
0.27
. No. : 21
StndConc
mg/L
0.0154
0.0272
0.0097
0.0174
0.0089
51.18
AS
BlnkCorr
Signal
0.001
0.001
0.002
0.002
0.000
22.54
AS
BlnkCorr
Signal
0.000
0.000
0.002
0.001
0.001
132.93
AS
BlnkCorr
Signal
0.117
0.118
0.118
0.117
0.000
0.27
AS
BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
51.18
Loc. :
Peak
Area
-0.135
-0.135
-0.134
Loc. :
Peak
Area
-0.136
-0.136
-0.135
Loc. :
Peak
Area
-0.019
-0.018
-0.019
Loc . :
Peak
Area
-0.136
-0.135
-0.136
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:49:09
0.166 14:49:11
0.166 14:49:13
Date: 11/07/2005
Bkgnd Time
Area
0.165 14:49:32
0.165 14:49:35
0.163 14:49:37
Date: 11/07/2005
Bkgnd Time
Area
0.166 14:49:52
0.165 14:49:54
0.165 14:49:56
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:50:16
0.164 14:50:18
0.164 14:50:20
Page 6
-------
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 -0.1686
2 -0.1597
3 -0.1589
Mean: -0.1624
SD : 0.0054
%RSD: 3.32
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0108
2 0.0139
3 0.0131
Mean: 0.0126
SD : 0.0016
%RSD: 12.55
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 3.407
2 3.437
3 3.410
Mean: 3.418
SD : 0.0166
%RSD: 0.48
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.1036
2 0.1021
3 0.1076
Mean: 0.1044
SD : 0.0028
%RSD: 2.73
. No. : 22
StndConc
mg/L
-0.1686
-0.1597
-0.1589
-0.1624
0.0054
3.32
. No. : 23
StndConc
mg/L
0.0108
0.0139
0.0131
0.0126
0.0016
12.55
. No.: 24
SPK
StndConc
mg/L
3.407
3.437
3.410
3.418
0.0166
0.48
. No.: 25
StndConc
mg/L
0.1036
0.1021
0.1076
0.1044
0.0028
2.73
AS :
BlnkCorr
Signal
-0.006
-0.006
-0.006
-0.006
0.000
3.32
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
12.55
AS
,3 / 10
Peak
Area
-0.016
-0.015
-0.016
Loc. :
Peak
Area
-0.132
-0.133
-0.132
Date: 11/07/2005
Bkgnd Time
Area
0.188 14:50:39
0.188 14:50:41
0.188 14:50:43
Date: 11/07/2005
Bkgnd Time
Area
0.164 14:51:01
0.164 14:51:03
0.164 14:51:05
Date: 11/07/2005
Bkgnd Time
Area
0.186 14:53:06
0.186 14:53:08
0.185 14:53:10
Date: 11/07/2005
Bkgnd Time
Area
0.161 14:53:40
0.161 14:53:42
0.161 14:53:44
Page 7
-------
Element: Ni Seq. No.: 26
SampleXlD: 014-1+3 SD
SafhpleConc
mg/E
10\35
absorb
-10.47
absorbXnc
1JK41
abao'rbance
/10.41
"" 0.0629
0.60
absorbance
is greater
is greater
AS LOG.
Date: 11/07/2005
BlnkCorr
Signal
0.364
than that
9.368
than that
0.366
than that
0.366
0.002
0.60
than that
Peak Bkgn| Time
Area Area
0.228 0.190 14:54:16
of the highest standard.
0.232 0.190 14:54:18
of the highest standard.
0.230 0.191 14:54:21
of the highest standard.
of the highest standard.
Element: Ni Seq. No.:
Sample ID: SD RE-SET
27
AS LOG.
Date: 11/07/2005
Repl
tt
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.471
3.497
3.439
3.469
0.0287
0.83
StndConc
mg/L
3.471
3.497
3.439
3.469
0.0287
0.83
BlnkCorr Peak
Signal Area
0.122 -0.014
0.123 -0.013
0.121 -0.015
0.122
0.001
0.83
Bkgnd Time
Area
0.183 14:55:21
0.183 14:55:23
0.183 14:55:25
Element: Ni Seq. No.: 28
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0065
-0.0413
0.0070
-0.0136
0.0249
.183.7
StndConc
mg/L
-0.0065
-0.0413
0.0070
-0.0136
0.0249
183.7
BlnkCorr Peak
Signal Area
0.000 -0.136
-0.001 -0.138
0.000 -0.136
0.000
0.001
183.72
Bkgnd Time
Area
0.164 14:55:41
0.165 14:55:43
0.164 14:55:45
Element: Ni Seq. No.: 29
Sample ID: 014-1+3SER
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.175
1.021
1.050
1.082
0.0822
7.60
StndConc
mg/L
1.175
1.021
1.050
1.082
0.0822
7.60
BlnkCorr
Signal
0.
0.
0.
0.
0.
7
041
036
037
038
003
.60
Peak
Area
-0.
-0.
-0.
095
100
099
Bkgnd
Time
Area
0
0
0
.171
.176
.175
14
14
14
:57:
:57:
:57:
13
15
17
Page 8
-------
Element: Ni Seq.
Sample ID: CCB
No.: 30
AS LOG.:
Date: 11/07/2005
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0
0
0
0
0
.1131
.1209
.0989
.1110
.0112
10.08
StndConc
mg/L
0
0
0
0
0
.1131
.1209
.0989
.1110
.0112
10.08
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
10
004 -0.132
004 -0.132
003 -0.133
004
000
.08
Bkgnd Time
Area
0.162 14:57:56
0.161 14:57:58
0.162 14:58:01
Element: Ni Seq. No.: 31
Sample ID: Sample
AS LOG.:
Date: 11/07/2005
Repl SampleConc StndConc
# mg/L mg/L
1 0.0797 0.0797
Auto-zero performed.
BlnkCorr Peak
Signal Area
0.003 -0.133
Bkgnd Time
Area
0.162 14:59:25
Element: Ni Seq. No.
Sample ID: CCB
32
AS LOG.:
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0247
0.0190
-0.0125
0.0104
0.0201
193.1
StndConc
mg/L
0.0247
0.0190
-0.0125
0.0104
0.0201
193.1
BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.133
0.000 -0.134
0.000
0.001
193.12
Bkgnd Time
Area
0.162 14:59:31
0.162 14:59:34
0.162 14:59:36
Element: Ni Seq. No.: 33
Sample ID: CCV
AS LOG.:
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Samp
mg/L
0.
0.
0.
0.
0.
leConc
9477
9422
8717
9205
0424
4.61
Stn
mg/
0.
0.
0.
0.
0.
.dConc
L
9477
9422
8717
9205
0424
4.61
Blnk
Sig
0.
0.
0.
0.
0.
4
Corr Peak
nal Area
033 -0.100
033 -0.100
031 -0.103
032
001
.61
Bkgnd Time
Area
0.166 14:59:50
0.167 14:59:52
0.169 14:59:54
Element: Ni Seq.
Sample ID: CCB
No.: 34
AS LOG.:
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0603
.0416
.0449
.0489
.0100
20.35
StndConc
mg/L
-0
-0
-0
-0
0
.0603
.0416
.0449
.0489
.0100
20.35
BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.002
0.000
20.35
Peak
Area
-0.
-0.
-0.
135
135
135
Bkgnd
Time
Area
0.
0.
0.
164
164
164
15:
15:
15:
00:09
00:11
00:14
Page 9
-------
Element: Ni Seq.
Sample ID: 014-4+6
Repl SampleConc
# mg/L
1 0.2426
2 0.2456
3 0.2346
Mean: 0.2409
SD : 0.0057
%RSD: 2.36
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0070
2 0.0215
3 0.0221
Mean: 0.0169
SD : 0.0085
%RSD: 50.49
Element: Ni Seq.
Sample ID: 014-7+9
Repl SampleConc
# mg/L
1 -0.0728
2 -0.0462
3 -0.0791
Mean: -0.0660
SD : 0.0175
%RSD: 26.44
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0502
2 -0.0378
3 -0.0466
Mean: -0.0449
SD : 0.0064
%RSD: 14.16
No.: 35
StndConc
mg/L
0.2426
0.2456
0.2346
0.2409
0.0057
2.36
No.: 36
StndConc
mg/L
0.0070
0.0215
0.0221
0.0169
0.0085
50.49
No.: 37
StndConc
mg/L
-0.0728
-0.0462
-0. 0791
-0.0660
0.0175
26.44
No. : 38
StndConc
mg/L
-0.0502
-0.0378
-0.0466
-0.0449
0.0064
14.16
AS LOG. :
BlnkCorr Peak
Signal Area
0.009 -0.125
0.009 -0.125
0.008 -0.125
0.008
0.000
2.36
AS LOG. :
BlnkCorr Peak
Signal Area
0.000 -0.133
0.001 -0.133
0.001 -0.133
0.001
0.000
50.49
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.003 -0.136
-0.002
0.001
26.44
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.135
-0.002 -0.135
-0.002
0.000
14.16
Date: 11/07/2005
Bkgnd Time
Area
0.188 15:00:36
0.188 15:00:38
0.188 15:00:40
Date: 11/07/2005
Bkgnd Time
Area
0.163 15:00:55
0.162 15:00:57
0.163 15:00:59
Date: 11/07/2005
Bkgnd Time
Area
0.186 15:01:17
0.186 15:01:19
0.186 15:01:21
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:01:31
0.165 15:01:34
0.165 15:01:36
Page 10
-------
Element: Ni Seq
. No. : 39
AS LOG. :
Date: 11/07/2005
Sample ID: 014-10+12
Repl SampleConc
# mg/L
1 0.3958
2 0.4095
3 0.3897
Mean: 0.3984
SD : 0.0101
%RSD: 2.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0245
2 0.0040
3 0.0260
Mean: 0.0182
SD : 0.0123
%RSD: 67.72
Element: Ni Seq
StndConc
mg/L
0.3958
0.4095
0.3897
0.3984
0.0101
2.54
. No. : 40
StndConc
mg/L
0.0245
0.0040
0.0260
0.0182
0.0123
67.72
. No.: 41
BlnkCorr Peak
Signal Area
0.014 -0.119
0.014 -0.119
0.014 -0.120
0.014
0.000
2.54
AS LOG. :
BlnkCorr Peak
Signal Area
0.001 -0.132
0.000 -0.133
0.001 -0.132
0.001
0.000
67.72
AS LOG. :
Bkgnd Time
Area
0.186 15:02:03
0.185 15:02:05
0.185 15:02:07
Date: 11/07/2005
Bkgnd Time
Area
0.162 15:02:19
0.162 15:02:21
0.162 15:02:23
Date: 11/07/2005
Sample ID: 014-13+15
Repl SampleConc
# mg/L
1 0.7715
2 0.7641
3 0.7791
Mean: 0.7715
SD : 0.0075
%RSD: 0.97
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0760
2 -0.0504
3 -0.0460
Mean: -0.0575
SD : 0.0162
%RSD: 28.23
StndConc
mg/L
0.7715
0.7641
0.7791
0.7715
0.0075
0.97
. No. : 42
StndConc
mg/L
-0.0760
-0.0504
-0.0460
-0.0575
0.0162
28.23
BlnkCorr Peak
Signal Area
0.027 -0.106
0.027 -0.106
0.027 -0.106
0.027
0.000
0.97
AS LOG. :
BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.002 -0.135
-0.002
0.001
28.23
Bkgnd Time
Area
0.189 15:02:44
0.189 15:02:46
0.190 15:02:48
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:03:02
0.165 15:03:05
0.165 15:03:07
Page 11
-------
Element : Ni Seq
. No. : 43
AS
LOG. :
Date: 11/07/2005
Sample ID: 014-16+18
Repl SampleConc
# mg/L
1 0.2519
2 0.2513
3 0.2384
Mean: 0.2472
SD : 0.0076
%RSD: 3.09
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0272
2 0.0500
3 0.0352
Mean: 0.0375
SD : 0.0116
%RSD: 30.91
Element : Ni Seq
StndConc
mg/L
0.2519
0.2513
0.2384
0.2472
0.0076
3.09
. No. : 44
StndConc
mg/L
0.0272
0.0500
0.0352
0.0375
0.0116
30.91
. No. : 45
BlnkCorr
Signal
0.009
0.009
0.008
0.009
. 0.000
3.09
AS
BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
30.91
AS
Peak
Area
-0.124
-0.124
-0.125
Loc. :
Peak
Area
-0.132
-0.132
-0.132
Loc. :
Bkgnd Time
Area
0.188 15:03:32
0.188 15:03:35
0.189 15:03:37
Date: 11/07/2005
Bkgnd Time
Area
0.162 15:03:54
0.162 15:03:56
0.162 15:03:58
Date: 11/07/2005
Sample ID: 014-19+21
Repl SampleConc
# mg/L
1 3.520
2 3.569
3 3.488
Mean: 3.526
SD : 0.0409
%RSD: 1.16
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0612
2 -0.0538
3 -0.0454
Mean: -0.0535
SD : 0.0079
%RSD: 14.76
StndConc
mg/L
3.520
3.569
3.488
3.526
0.0409
1.16
. No. : 46
StndConc
mg/L
-0.0612
-0.0538
-0.0454
-0.0535
0.0079
14.76
BlnkCorr
Signal
0.124
0.126
0.123
0.124
0.001
1.16
AS
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
14.76
Peak
Area
-0.009
-0.008
-0.011
Loc. :
Peak
Area
-0.135
-0.135
-0.135
Bkgnd Time
Area
0.190 15:04:22
0.191 15:04:24
0.190 15:04:27
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:04:41
0.164 15:04:43
0.164 15:04:45
Page 12
-------
Element: Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.4529
2 0.4721
3 0.4709
Mean: 0.4653
SD : 0.0108
%RSD: 2.32
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0200
2 0.0430
3 0.0241
Mean: 0.0290
SD : 0.0123
%RSD: 42.22
Element: Ni Seq
. No. : 47
StndConc
mg/L
0.4529
0.4721
0.4709
0.4653
0.0108
2.32
. No. : 48
StndConc
mg/L
0.0200
0.0430
0.0241
0.0290
0.0123
42.22
. No. : 49
AS
BlnkCorr
Signal
0.016
0.017
0.017
0.016
0.000
2.32
AS
BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
42.22
AS
Loc. :
Peak
Area
-0.117
-0.117
-0.117
Loc. :
Peak
Area
-0.133
-0.132
-0.132
Loc. :
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:05:05
0.165 15:05:07
0.164 15:05:09
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:05:25
0.162 15:05:27
0.161 15:05:29
Date: 11/07/2005
Sample ID: 014-22+24
Repl SampleConc
# mg/L
1 0.1449
2 0.1479
3 0.1068
Mean: 0.1332
SD : 0.0229
%RSD: 17.18
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0688
2 -0.0789
3 -0.0688
Mean: -0.0722
SD : 0.0058
%RSD: 8.06
StndConc
mg/L
0.1449
0.1479
0.1068
0.1332
0.0229
17.18
. No. : 50
StndConc
mg/L
-0.0688
-0.0789
-0.0688
-0.0722
0.0058
8.06
BlnkCorr
Signal
0.005
0.005
0.004
0.005
0.001
17.18
AS
BlnkCorr
Signal
-0.002
-0.003
-0.002
-0.003
0.000
8.06
Peak
Area
-0.128
-0.128
-0.130
Loc. :
Peak
Area
-0.136
-0.136
-0.136
Bkgnd Time
Area
0.190 15:05:45
0.190 15:05:47
0.191 15:05:49
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:06:04
0.166 15:06:07
0.165 15:06:09
Page 13
-------
Element: Ni Seq.
No . : 51
AS LOG. :
Date: 11/07/2005
Sample ID: 014-25+27
Repl SampleConc
# mg/L
1 -0.1614
2 -0.1827
3 -0.1612
Mean: -0.1684
SD : 0.0123
%RSD: 7.33
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0308
2 0.0253
3 0.0264
Mean: 0.0275
SD : 0.0029
%RSD: 10.58
Element: Ni Seq.
StndConc
mg/L
-0.1614
-0.1827
-0.1612
-0.1684
0.0123
7.33
No. : 52
StndConc
mg/L
0.0308
0.0253
0.0264
0.0275
0.0029
10.58
No. : 53
BlnkCorr Peak
Signal Area
-0.006 -0.139
-0.006 -0.140
-0.006 -0.139
-0.006
0.000
7.33
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.132
0.001 -0.132
0.001
0.000
10.58
AS Loc. :
Bkgnd Time
Area
0.186 15:06:26
0.187 15:06:28
0.187 15:06:30
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:06:47
0.161 15:06:49
0.162 15:06:51
Date: 11/07/2005
Sample ID: 014-28+30
Repl SampleConc
# mg/L
1 0.2789
2 0.2498
3 0.2873
Mean: 0.2720
SD : 0.0197
%RSD: 7.23
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0433
2 -0.0335
3 -0.0441
Mean: -0.0403
SD : 0.0059
%RSD: 14.74
StndConc
mg/L
0.2789
0.2498
0.2873
0.2720
0.0197
7.23
No.: 54
StndConc
mg/L
-0.0433
-0.0335
-0.0441
-0.0403
0.0059
14.74
BlnkCorr Peak
Signal Area
0.010 -0.123
0.009 -0.125
0.010 -0.123
0.010
0.001
7.23
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.134
-0.002 -0.135
-0.001
0.000
14.74
Bkgnd Time
Area
0.189 15:07:14
0.190 15:07:16
0.190 15:07:18
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:07:35
0.165 15:07:37
0.165 15:07:39
Page 14
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
. No.: 55
AS
LOG. :
Date:
11/07/2005
ID: 014-31+33
SampleConc
mg/L
-0.1722
-0.1656
-0.1673
-0.1684
0.0035
2.05
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0352
0.0508
0.0186
0.0114
0.0434
380.6
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
-0.1722
-0.1656
-0.1673
-0.1684
0.0035
2.05
. No. : 56
StndConc
mg/L
-0.0352
0.0508
0.0186
0.0114
0.0434
380.6
. No. : 57
BlnkCorr
Signal
-0.006
-0.006
-0.006
-0.006
0.000
2.05
AS
BlnkCorr
Signal
-0.001
0.002
0.001
0.000
0.002
380.64
AS
Peak
Area
-0.139
-0.139
-0.139
Loc. :
Peak
Area
-0.135
-0.132
-0.133
Loc. :
Bkgnd
Area
0.190
0.191
0.192
Date:
Bkgnd
Area
0.164
0.162
0.161
Date:
Time
15: 07:
15:07:
15:08:
57
59
01
11/07/2005
Time
15:08:
15:08:
15:08:
14
16
18
11/07/2005
ID: 014-34+36
SampleConc
mg/L
-0.0567
-0.0580
-0.0551
-0.0566
0.0014
2.52
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCB
SampleConc
mg/L
-0.0251
-0.0335
-0.0536
-0.0374
0.0147
39.21
StndConc
mg/L
-0.0567
-0.0580
-0.0551
-0.0566
0.0014
2.52
. No. : 58
StndConc
mg/L
-0.0251
-0.0335
-0.0536
-0.0374
0.0147
39.21
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
2.52
AS
BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
39.21
Peak
Area
-0.135
-0.135
-0.135
Loc. :
Peak
Area
-0.134
-0.134
-0.135
Bkgnd
Area
0.186
0.186
0.187
Date:
Bkgnd
Area
0.164
0.165
0.165
Time
15:08:
15:08:
15:08:
33
36
38
11/07/2005
Time
15:08:
15:08:
15:08:
54
56
58
Page 15
-------
Element: Ni Seq. No.:
Sample ID: 014-37+39
59
AS LOG.:
Date: 11/07/2005
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.1196
.1373
.1137
.1235
.0123
9.93
StndConc
mg/L
-0.
-0.
-0.
-0.
0.
1196
1373
1137
1235
0123
9.93
BlnkCorr Peak
Signal Area
-0
-0
-0
-0
0
.004 -0.138
.005 -0.138
.004 -0.137
.004
.000
9.93
Bkgnd Time
Area
0.189 15:09:13
0.189 15:09:15
0.189 15:09:17
Element: Ni Seq.
Sample ID: CCB
No.: 60
AS LOG.:
Date: 11/07/2005
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0.0715
-0.0823
-0.0776
-0.0771
0.0054
7.04
StndConc
mg/L
-0.0715
-0.0823
-0.0776
-0.0771
0.0054
7.04
BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.003 -0.136
-0.003 -0.136
-0.003
0.000
7.04
Bkgnd Time
Area
0.165 15:09:33
0.166 15:09:36
0.166 15:09:38
Element: Ni Seq. No.: 61
Sample ID: Sample
AS LOG.
Date: 11/07/2005
Repl SampleConc StndConc
# mg/L mg/L
1 0.0217 0.0217
Auto-zero performed.
BlnkCorr Peak
Signal Area
0.001 -0.133
Bkgnd Time
Area
0.161 15:09:50
Element: Ni Seq. No.: 62
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleCo
mg/L
-0.0013
0.0207
0.0243
0.0146
0.0139
95.32
nc StndConc
mg/L
-0.0013
0.0207
0.0243
0.0146
0.0139
95.32
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.000 -0.133 0.162 15:10:00
0.001 -0.132 0.162 15:10:02
0.001 -0.132 0.162 15:10:04
0.001
0.000
95.32
Element: Ni Seq.
Sample ID: CCV
No.: 63
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.019
2.012
1.981
2.004
0.0201
1.00
StndConc
mg/L
2.019
2.012
1.981
2.004
0.0201
1.00
BlnkCorr
Signal
0
0
0
0
0
.071
.071
.070
.070
.001
1.00
Peak
Area
-0.
-0.
-0.
062
062
063
Bkgnd
Time
Area
0.
0.
0.
165
165
166
15:
15:
15:
10
10
10
:18
:20
:22
Page 16
-------
Appendix E - 4
Laboratory QA/QC Data for Stack Testing Samples
-------
Element
Sample
: Ni Seq,
ID: CCB
Repl SampleConc
# mg/L
1 -0.0909
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
-0. 0401
-0.0555
-0.0622
0.0260
41.86
: Ni Seq
ID: I LRB
SampleConc
mg/L
1.860
1.878
1.891
1.876
0.0153
0.82
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCB
SampleConc
mg/L
0.0137
0.0388
0.0247
0.0257
0.0126
48.89
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: I LFB
SampleConc
mg/L
0.1021
0.0962
0.0405
0.0796
0.0340
42.70
. No.: 64
StndConc
mg/L
-0.0909
-0.0401
-0.0555
-0.0622
0.0260
41.86
. No. : 65
StndConc
mg/L
1.860
1.878
1.891
1.876
0.0153
0.82
. No.: 66
StndConc
mg/L
0.0137
0.0388
0.0247
0.0257
0.0126
48.89
. No. : 67
StndConc
mg/L
0.1021
0.0962
0.0405
0.0796
0.0340
42.70
AS LOG. :
BlnkCorr
Signal
-0.003
-0.001
-0.002
-0.002
0.001
41.86
Peak
Area
-0.136
-0.134
-0.134
AS Loc. :
BlnkCorr
Signal
0.065
0.066
0.067
0.066
0.001
0.82
Peak
Area
-0.067
-0.066
-0.066
AS Loc. :
BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
48.89
AS
BlnkCorr
Signal
0.004
0.003
0.001
0.003
0.001
42.70
Peak
Area
-0.132
-0.131
-0.132
Loc. :
Peak
Area
-0.129
-0.129
-0.131
Date: 11/07/2005
Bkgnd
Area
0.165
0.165
0.164
Time
15:10:33
15:10:35
15:10:37
Date: 11/07/2005
Bkgnd
Area
0.168
0.168
0.167
Date:
Bkgnd
Area
0.162
0.161
0.162
Date:
Bkgnd
Area
0.165
Time
15:11:01
15:11:03
15:11:05
11/07/2005
Time
15:11:18
15:11:20
15:11:22
11/07/2005
Time
15:11:40
0.166 15:11:42
0.167
15:11:45
Page 17
-------
Element: Ni Seq. No.: 68
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
-0.0658
-0.0394
-0.0432
-0.0494
0.0143
28.90
StndConc
mg/L
-0.0658
-0.0394
-0.0432
-0.0494
0.0143
28.90
BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.134
-0.002 -0.134
-0.002
0.001
28.90
Bkgnd Time
Area
0.164 15:11:59
0.164 15:12:01
0.165 15:12:03
Element: Ni
Sample ID: I
Seq. No.: 69
014-2
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0110
0.0314
0.0120
0.0181
0.0115
63.34
StndConc
mg/L
0.0110
0.0314
0.0120
0.0181
0.0115
63.34
BlnkCorr Peak
Signal Area
0.000 -0.132
0.001 -0.131
0.000 -0.132
0.001
0.000
63.34
Bkgnd Time
Area
0.167 15:12:21
0.167 15:12:23
0.168 15:12:25
Element: Ni Seq.
Sample ID: CCB
No.: 70
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0270
0.0129
-0.0053
0.0115
0.0162
140.5
StndConc
mg/L
0.0270
0.0129
-0.0053
0.0115
0.0162
140.5
BlnkCorr Peak
Signal Area
0.001 -0.132
0.000 -0.132
0.000 -0.133
0.000
0.001
140.50
Bkgnd Time
Area
0.162 15:12:48
0.162 15:12:50
0.162 15:12:52
Element: Ni Seq.
Sample ID: 014-2 S
No. : 71
Date: 11/07/2005
BlnkCorr
Signal
0.253
than that
0.253
than that
0.253
than that
0.253
0.000
0.14
than that
Peak
Area
0.120
of the
0.120
of the
0.121
of the
Bkgnd Time
Area
0.167 15:14:04
highest standard.
0.166 15:14:06
highest standard.
0.166 15:14:08
highest standard.
of the highest standard.
Page 18
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: 014-2 S
SampleConc
mg/L
4.198
4.177
4.159
4.178
0.0196
0.47
: Ni Seq.
ID: CCB
SampleConc
mg/L
-0.0373
-0.0555
-0.0489
-0.0472
0.0092
19.56
: Ni Seq.
ID: 014-2 SD
SampleConc /
mg/L /
-0.0888/
-0.0080''
0.00/17
-0.0317
0/0497
/156.8
: Ni Seq.
ID: 014-2 SD
SampleConc
mg/L
4.240
4.225
4.251
4.239
0.0129
0.30
No.: 72
StndConc
mg/L
4.198
4.177
4.159
4.178
0.0196
0.47
No. : 73
StndConc
mg/L
-0.0373
-0.0555
-0.0489
-0.0472
0.0092
19.56
No. : 74
/ L
StndConc
mg/L
-0.0888
-0.0080
0.0017
-0.0317
0.0497
156.8
No.: 75
StndConc
mg/L
4.240
4.225
4.251
4.239
0.0129
0.30
AS
BlnkCorr
Signal
0.148
0.147
0.146
0.147
0.001
0.47
AS
BlnkCorr
Signal
-0.001
-0.002
-0.002
-0.002
0.000
19.56
•, AS
lA
BlnkCorr
Signal
-0.003
0.000
0.000
-0.001
0.002
156.81
AS
BlnkCorr
Signal
0.149
0.149
0.150
0.149
0.000
0.30
Loc. :
Peak
Area
0.015
0.014
0.014
Loc. :
Peak
Area
-0.134
-0.134
-0.134
Loc. :
Peak
Area
-0.136
-0.133
-0.132
Loc. :
Peak
Area
0.017
0.016
0.017
Date:
Bkgnd
Area
0.168
0.169
0.169
Date:
Bkgnd
Area
0.164
0.164
0.164
Date:
Bkgnd
Area
0.165
0.163
0.161
Date:
Bkgnd
Area
0.165
0.165
0.165
11/07/2005
Time
15:14:
15:14:
15:14:
29
31
33
11/07/2005
Time
15:15:
15:15:
15:15:
00
02
05
11/07/2005
Time
15:15:
15:15:
15:15:
13
16
18
11/07/2005
Time
15:15:
15:15:
15:15:
33
35
37
Page 19
-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.1029
2 -0.0865
3 -0.0652
Mean: -0.0849
SD : 0.0189
%RSD: 22.24
Element: Ni Seq.
Sample ID: 014-2 SI
Repl SampleConc
# mg/L
1 2 . 493
2 2 . 469
3 2.521
Mean: 2.494
SD : 0.0256
%RSD: 1.03
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0857
2 -0.0614
3 -0.0745
Mean: -0.0739
SD : 0.0122
%RSD: 16.48
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0797
2 -0.0751
3 -0.0700
Mean: -0.0749
SD : 0.0049
%RSD: 6.48
No . : 76
StndConc
mg/L
-0.1029
-0.0865
-0.0652
-0.0849
0.0189
22.24
. No. : 77
3R
StndConc
mg/L
2.493
2.469
2.521
2.494
0.0256
1.03
. No. : 78
StndConc
mg/L
-0.0857
-0.0614
-0.0745
-0.0739
0.0122
16.48
. No. : 79
StndConc
mg/L
-0.0797
-0.0751
-0.0700
-0.0749
0.0049
6.48
AS LOG. :
BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.003 -0.136
-0.002 -0.135
-0.003
0.001
22.24
AS Loc. :
BlnkCorr Peak
Signal Area
0.088 -0.045
0.087 -0.046
0.089 -0.044
0.088
0.001
1.03
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.003 -0.135
-0.003
0.000
16.48
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.003 -0.135
-0.002 -0.135
-0.003
0.000
6.48
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:16:38
0.165 15:16:40
0.165 15:16:43
Date: 11/07/2005
Bkgnd Time
Area
0.163 15:17:00
0.163 15:17:02
0.164 15:17:04
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:17:55
0.166 15:17:57
0.165 15:17:59
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:18:46
0.166 15:18:48
0.165 15:18:50
Page 20
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCV
SampleConc
mg/L
4.699
4.681
4.700
4.693
0.0103
0.22
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0392
0.0342
0.0255
0.0330
0.0069
21.03
: Ni Seq
ID: 014-5
SampleConc
mg/L
0.0892
0.0570
0.0376
0.0613
0.0260
42.46
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0635
-0.0458
-0.0338
-0.0477
0.0149
31.27
. No. : 80
StndConc
mg/L
4.699
4.681
4.700
4.693
0.0103
0.22
. No. : 81
StndConc
mg/L
0.0392
0.0342
0.0255
0.0330
0.0069
21.03
. No. : 82
StndConc
mg/L
0.0892
0.0570
0.0376
0.0613
0.0260
42.46
. No. : 83
StndConc
mg/L
-0.0635
-0.0458
-0.0338
-0.0477
0.0149
31.27
AS :
BlnkCorr
Signal
0.165
0.165
0.165
0.165
0.000
0.22
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
21.03
AS
BlnkCorr
Signal
0.003
0.002
0.001
0.002
0.001
42.46
AS
BlnkCorr
Signal
-0.002
-0.002
-0.001
-0.002
0.001
31.27
LOG. :
Peak
Area
0.033
0.032
0.033
LOG. :
Peak
Area
-0.131
-0.131
-0.132
LOG. :
Peak
Area
-0.129
-0.131
-0.131
LOG. :
Peak
Area
-0.135
-0.134
-0.134
Date: :
Bkgnd
Area
0.167
0.168
0.168
Date:
Bkgnd
Area
0.161
0.161
0.161
Date:
Bkgnd
Area
0.164
0.165
0.165
Date:
Bkgnd
Area
0.165
0.165
0.165
11/07/2005
Time
15:19:13
15:19:15
15:19:17
11/07/2005
Time
15:19:32
15:19:34
15:19:36
11/07/2005
Time
15:20:02
15:20:04
15:20:06
11/07/2005
Time
15:20:16
15:20:18
15:20:20
Page 21
-------
Element: Ni Seq
Sample ID: 014-8
Repl SampleConc
# mg/L
1 0.0468
2 0.0270
3 0.0108
Mean: 0.0282
SD : 0.0180
%RSD: 63.82
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0565
2 0.0451
3 0.0365
Mean: 0.0460
SD : 0.0100
%RSD: 21.77
Element: Ni Seq
Sample ID: 014-11
Repl SampleConc
# mg/L
1 0.1795
2 0.1981
3 0.1713
Mean: 0.1830
SD : 0.0137
%RSD: 7.51
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0734
2 -0.0470
3 -0.0650
Mean: -0.0618
SD : 0.0135
%RSD: 21.86
. No. : 84
StndConc
mg/L
0.0468
0.0270
0.0108
0.0282
0.0180
63.82
. No.: 85
StndConc
mg/L
0.0565
0.0451
0.0365
0.0460
0.0100
21.77
. No . : 86
StndConc
mg/L
0.1795
0.1981
0.1713
0.1830
0.0137
7.51
. No. : 87
StndConc
mg/L
-0.0734
-0.0470
-0.0650
-0.0618
0.0135
21.86
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.131
0.001 -0.132
0.000 -0.132
0.001
0.001
63.82
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.131
0.001 -0.131
0.002
0.000
21.77
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 -0.126
0.007 -0.126
0.006 -0.127
0.006
0.000
7.51
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.134
-0.002 -0.135
-0.002
0.000
21.86
Date: 11/07/2005
Bkgnd Time
Area
0.166 15:20:41
0.166 15:20:43
0.166 15:20:45
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:20:58
0.161 15:21:01
0.161 15:21:03
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:21:19
0.166 15:21:22
0.166 15:21:24
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:21:35
0.165 15:21:37
0.165 15:21:39
Page 22
-------
Element: Ni Seq
Sample ID: 014-14
Repl SampleConc
# mg/L
1 0.3378
2 0.3445
3 0.3650
Mean: 0.3491
SD : 0.0142
%RSD: 4.06
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
I -0.0776
2 -0.0563
3 0.0473
Mean: -0.0288
SD : 0.0668
%RSD: 231.7
Element: Ni Seq
Sample ID: 014-17
Repl SampleConc
# mg/L
1 0.1774
2 0.2074
3 0.1690
Mean: 0.1846
SD : 0.0202
%RSD: 10.94
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0156
2 -0.0352
3 -0.0812
Mean: -0.0440
SD : 0.0337
%RSD: 76.56
. No.: 88
StndConc
mg/L
0.3378
0.3445
0.3650
0.3491
0.0142
4.06
. No. : 89
StndConc
mg/L
-0.0776
-0.0563
0.0473
-0.0288
0.0668
231.7
. No. : 90
StndConc
mg/L
0.1774
0.2074
0.1690
0.1846
0.0202
10.94
. No.: 91
StndConc
mg/L
-0.0156
-0.0352
-0.0812
-0.0440
0.0337
76.56
AS Loc. :
BlnkCorr Peak
Signal Area
0.012 -0.121
0.012 -0.120
0.013 -0.120
0.012
0.000
4.06
AS Loc. :
BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.135
0.002 -0.131
-0.001
0.002
231.74
AS Loc. :
BlnkCorr Peak
Signal Area
0.006 -0.126
0.007 -0.125
0.006 -0.127
0.006
0.001
10.94
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.001 -0.134
-0.003 -0.135
-0.002
0.001
76.56
Date: 11/07/2005
Bkgnd Time
Area
0.166 15:21:53
0.167 15:21:55
0.167 15:21:57
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:22:11
0.165 15:22:13
0.162 15:22:15
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:22:33
0.164 15:22:35
0.164 15:22:37
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:22:50
0.164 15:22:53
0.165 15:22:55
Page 23
-------
Element: Ni Seq.
Sample ID: 014-20
Repl SampleConc
# mg/L
1 -0.0354
2 -0.0403
3 -0.0264
Mean: -0.0340
SD : 0.0070
%RSD: 20.67
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0544
2 0 . 0494
3 0.0612
Mean: 0.0188
SD : 0.0636
%RSD: 339.1
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0502
2 0.0401
3 0.0439
Mean: 0.0447
SD : 0.0051
%RSD: 11.37
Element: Ni Seq.
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.1977
2 0.2030
3 0.1928
Mean: 0.1978
SD : 0.0051
%RSD: 2.60
No.: 92
StndConc
mg/L
-0.0354
-0.0403
-0.0264
-0.0340
0.0070
20.67
No.: 93
StndConc
mg/L
-0.0544
0.0494
0.0612
0.0188
0.0636
339.1
No.: 94
StndConc
mg/L
0.0502
0.0401
0.0439
0.0447
0.0051
11.37
. No. : 95
StndConc
mg/L
0.1977
0.2030
0.1928
0.1978
0.0051
2.60
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.134
-0.001 -0.134
-0.001 -0.133
-0.001
0.000
20.67
AS Loc. :
BlnkCorr Peak
Signal Area
-0.002 -0.134
0.002 -0.131
0.002 -0.130
0.001
0.002
339.09
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.131
0.001 -0.131
0.002 -0.131
0.002
0.000
11.37
AS Loc. :
BlnkCorr Peak
Signal Area
0.007 -0.126
0.007 -0.125
0.007 -0.126
0.007
0.000
2.60
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:23:09
0.166 15:23:11
0.166 15:23:14
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:23:31
0.162 15:23:34
0.162 15:23:36
Date: 11/07/2005
Bkgnd Time
Area
0.162 15:23:46
0.162 15:23:48
0.162 15:23:50
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:24:23
0.165 15:24:26
0.165 15:24:28
Page 24
-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0768
2 -0.0709
3 -0.0030
Mean: -0.0503
SD : 0.0410
%RSD: 81.57
Element: Ni Seq
Sample ID: 014-23
Repl SampleConc
# mg/L
1 0.1498
2 0.1394
3 0.1192
Mean: 0.1361
SD : 0.0156
%RSD: 11.43
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0489
2 -0.0384
3 -0.0211
Mean: -0.0361
SD : 0.0140
%RSD: 38.81
Element: Ni Seq
Sample ID: 014-26
Repl SampleConc
# mg/L
1 0.1247
2 0.1160
3 0.1160
Mean: 0.1189
SD : 0.0050
%RSD: 4.25
. No. : 96
StndConc
mg/L
-0.0768
-0.0709
-0.0030
-0.0503
0.0410
81.57
. No. : 97
StndConc
mg/L
0.1498
0.1394
0.1192
0.1361
0.0156
11.43
. No. : 98
StndConc
mg/L
-0.0489
-0.0384
-0.0211
-0.0361
0.0140
38.81
. No. : 99
StndConc
mg/L
0.1247
0.1160
0.1160
0.1189
0.0050
4.25
AS LOG. :
BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.135
0.000 -0.133
-0.002
0.001
81.57
AS LOG. :
BlnkCorr Peak
Signal Area
0.005 -0.127
0.005 -0.128
0.004 -0.128
0.005
0.001
11.43
AS LOG. :
BlnkCorr Peak
Signal Area
-0.002 -0.134
-0.001 -0.134
-0.001 -0.133
-0.001
0.000
38.81
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 -0.128
0.004 -0.128
0.004 -0.128
0.004
0.000
4.25
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:24:44
0.165 15:24:46
0.163 15:24:48
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:25:11
0.165 15:25:13
0.165 15:25:15
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:25:41
0.164 15:25:43
0.164 15:25:46
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:26:31
0.165 15:26:33
0.164 15:26:35
Page 25
-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
ft mg/L
1 0.0388
2 0.0382
3 0.0407
Mean: 0.0392
3D : 0.0013
%RSD: 3.30
Element: Ni Seq.
Sample ID: 014-29
Repl SampleConc
ft mg/L
1 0.0734
2 0.0475
3 0.0856
Mean: 0.0688
SD : 0.0194
%RSD: 28.21
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
ft mg/L
1 -0.0407
2 -0.0106
3 -0.0424
Mean: -0.0312
SD : 0.0179
%RSD: 57.16
Element: Ni Seq.
Sample ID: 014-32
Repl SampleConc
ft mg/L
1 0.1148
2 0.1278
3 0.1373
Mean: 0.1266
SD : 0.0113
%RSD: 8.89
No. : 100
StndConc
mg/L
0.0388
0.0382
0.0407
0.0392
0.0013
3.30
No.: 101
StndConc
mg/L
0.0734
0.0475
0.0856
0.0688
0.0194
28.21
No.: 102
StndConc
mg/L
-0.0407
-0.0106
-0.0424
-0.0312
0.0179
57.16
No.: 103
StndConc
mg/L
0.1148
0.1278
0.1373
0.1266
0.0113
8.89
AS LOG. :
BlnkCorr Peak
Signal Area
0.001 -0.131
0.001 -0.131
0.001 -0.131
0.001
0.000
3.30
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.130
0.002 -0.131
0.003 -0.130
0.002
0.001
28.21
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.134
0.000 -0.133
-0.001 -0.134
-0.001
0.001
57.16
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 -0.129
0.004 -0.128
0.005 -0.128
0.004
0.000
8.89
Date: 11/07/2005
Bkgnd Time
Area
0.162 15:27:51
0.162 15:27:53
0.162 15:27:55
Date: 11/07/2005
Bkgnd Time
Area
0.167 15:28:14
0.168 15:28:16
0.168 15:28:18
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:28:35
0.164 15:28:37
0.164 15:28:39
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:29:26
0.165 15:29:29
0.165 15:29:31
Page 26
-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0719
2 -0.0338
3 -0.0251
Mean: -0.0436
SD : 0.0249
%RSD: 57.03
Element: Ni Seq.
Sample ID: 014-35
Repl SampleConc
# mg/L
1 0.0622
2 0.0694
3 0.0749
Mean: 0.0688
SD : 0.0064
%RSD: 9.28
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0548
2 -0.0452
3 0.0568
Mean: -0.0144
SD : 0.0619
%RSD: 430.1
Element: Ni Seq.
Sample ID: 014-38
Repl SampleConc
# mg/L
1 0.1420
2 0.1298
3 0.1555
Mean: 0.1425
SD : 0.0128
%RSD: 9.01
No.: 104
StndConc
mg/L
-0.0719
-0.0338
-0.0251
-0.0436
0.0249
57.03
No.: 105
StndConc
mg/L
0.0622
0.0694
0.0749
0.0688
0.0064
9.28
No. : 106
StndConc
mg/L
-0.0548
-0.0452
0.0568
-0.0144
0.0619
430.1
No.: 107
StndConc
mg/L
0.1420
0.1298
0.1555
0.1425
0.0128
9.01
AS LOG. :
BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.001 -0.134
-0.001 -0.133
-0.002
0.001
57.03
AS LOG. :
BlnkCorr Peak
Signal Area
0.002 -0.130
0.002 -0.130
0.003 -0.130
0.002
0.000
9.28
AS LOG. :
BlnkCorr Peak
Signal Area
-0.002 -0.134
-0.002 -0.134
0.002 -0.131
-0.001
0.002
430.09
AS LOG. :
BlnkCorr Peak
Signal Area
0.005 -0.128
0.005 -0.128
0.005 -0.127
0.005
0.000
9.01
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:29:45
0.165 15:29:47
0.165 15:29:49
Date: 11/07/2005
Bkgnd Time
Area
0.166 15:30:08
0.166 15:30:10
0.166 15:30:12
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:30:23
0.166 15:30:25
0.162 15:30:28
Date: 11/07/2005
Bkgnd Time
Area
0.163 15:30:43
0.163 15:30:45
0.163 15:30:47
Page 27
-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0059
2 0.0234
3 0.0160
Mean: 0.0151
SD : 0.0088
%RSD: 58.21
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
If mg/L
1 -0.0183
2 -0.0532
3 -0.0515
Mean: -0.0410
SD : 0.0197
%RSD: 48.10
Element: Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.9857
2 0.9861
3 1.046
Mean: 1.006
SD : 0.0346
%RSD: 3.44
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0574
2 0.0521
3 0.0441
Mean: 0.0512
SD : 0.0067
%RSD: 13.08
. No. : 108
StndConc
mg/L
0.0059
0.0234
0.0160
0.0151
0.0088
58.21
. No. : 109
StndConc
mg/L
-0.0183
-0.0532
-0.0515
-0.0410
0.0197
48.10
. No. : 110
StndConc
mg/L
0.9857
0.9861
1.046
1.006
0.0346
3.44
. No. : 111
StndConc
mg/L
0.0574
0.0521
0.0441
0.0512
0.0067
13.08
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.132
0.001 -0.132
0.001 -0.132
0.001
0.000
58.21
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.002 -0.134
-0.002 -0.134
-0.001
0.001
48.10
AS Loc. :
BlnkCorr Peak
Signal Area
0.035 -0.098
0.035 -0.098
0.037 -0.096
0.035
0.001
3.44
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.131
0.002 -0.131
0.002
0.000
13.08
Date: 11/07/2005
Bkgnd Time
Area
0.162 15:30:59
0.162 15:31:02
0.163 15:31:04
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:31:16
0.165 15:31:18
0.165 15:31:20
Date: 11/07/2005
Bkgnd Time
Area
0.166 15:31:52
0.166 15:31:54
0.163 15:31:56
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:32:11
0.161 15:32:14
0.162 15:32:16
Page 28
-------
Element: Ni Seq
Sample ID: B-LRB
Repl SampleConc
# mg/L
1 0.0027
2 -0.0093
3 -0.0462
Mean: -0.0176
SD : 0.0255
%RSD: 144.5
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0175
2 -0.0048
3 -0.0173
Mean: -0.0132
SD : 0.0073
%RSD: 55.38
Element: Ni Seq
Sample ID: B-LFB
Repl SampleConc
# mg/L
1 0.9021
2 0.9004
3 0.8781
Mean: 0.8935
SD : 0.0134
%RSD: 1.50
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0549
2 0.0614
3 0.0671
Mean: 0.0612
SD : 0.0061
%RSD: 9.95
. No. : 112
StndConc
mg/L
0.0027
-0.0093
-0.0462
-0.0176
0.0255
144.5
. No. : 113
StndConc
mg/L
-0.0175
-0.0048
-0.0173
-0.0132
0.0073
55.38
. No. : 114
StndConc
mg/L
0.9021
0.9004
0.8781
0.8935
0.0134
1.50
. No. : 115
StndConc
mg/L
0.0549
0.0614
0.0671
0.0612
0.0061
9.95
AS LOG. :
BlnkCorr Peak
Signal Area
0.000 -0.132
0.000 -0.133
-0.002 -0.134
-0.001
0.001
144.55
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 -0.133
0.000 -0.133
-0.001 -0.133
0.000
0.000
55.38
AS Loc. :
BlnkCorr Peak
Signal Area
0.032 -0.101
0.032 -0.101
0.031 -0.102
0.031
0.000
1.50
AS Loc.:
BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.130
0.002 -0.130
0.002
0.000
9.95
Date: 11/07/2005
Bkgnd Time
Area
0.165 15:32:30
0.166 15:32:32
0.166 15:32:34
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:32:55
0.164 15:32:57
0.164 15:32:59
Date: 11/07/2005
Bkgnd Time
Area
0.167 15:33:11
0.167 15:33:13
0.168 15:33:15
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:33:32
0.161 15:33:34
0.161 15:33:37
Page 29
-------
Element: Ni Seq
Sample ID: 306-1
No.: 116
AS LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean :
SD :
%RSD:
Sample
SampleConc
mg/L
28.91
absorbance
28.88
absorbance
28.93
absorbance
28.91
0.0244
0.08
absorbance
StndConc
mg/L
28.91
is greater
28.88
is greater
28.93
is greater
28.91
0.0244
0.08
is greater
BlnkCorr
Signal
1.
than
1.
than
1.
than
1.
0.
0
than
017
that
016
that
018
that
017
001
.08
that
Peak
Area
0.
of
0.
of
0.
of
of
885
the
884
the
885
the
the
Bkgnd
Area
0.182
highest
Time
15:34:
standard.
0.182
highest
15:34:
standard.
0.182
highest
highest
15:34:
13
15
17
standard.
standard.
Element: Ni Seq.
Sample ID: CCB
No.: 117
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleCon
mg/L
-0.0257
-0.1198
-0.1413
-0.0956
0.0615
64.33
c StndConc
mg/L
-0.0257
-0.1198
-0.1413
-0.0956
0.0615
64.33
BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.004 -0.137
-0.005 -0.138
-0.003
0.002
64.33
Bkgnd Time
Area
0.166 15:35:25
0.168 15:35:27
0.170 15:35:30
Element: Ni Seq.
Sample ID: 306-1 S
No.: 118
AS Loc.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
27.67
absorbance
27.74
absorbance
27.70
absorbance
27.71
0.0319
0.12
absorbance
StndConc
mg/L
is
is
is
is
27.67
greater
27.74
greater
27.70
greater
27.71
0.0319
0.12
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
974
that
976
that
975
that
975
001
.12
that
Peak
Area
0.
of
0.
of
0.
of
of
841
the
843
the
842
the
the
Bkgnd
Area
0.181
highest
Time
15:35:
standard.
0.181
highest
15:35:
standard.
0.181
highest
highest
15:35:
45
48
50
standard.
standard.
Element: Ni Seq. No.: 119
Sample ID: CCB
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.
1546
1441
1378
1455
0085
5.81
StndConc
mg/L
0.
0.
0.
0.
0.
1546
1441
1378
1455
0085
5.81
BlnkCorr
Signal
0.005
0.005
0.005
0.005
0.000
5.81
Peak
Area
-0.
-0.
-0.
127
127
128
Bkgnd
Time
Area
0.
0.
0.
162
162
162
15:
15:
15:
36:12
36:14
36:16
Page 30
-------
Element: Ni Seq. No.
Sample ID: 306-1 SD
120
AS Loc.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
27.91
absorbance
27.82
absorbance
27.88
absorbance
27.87
0.0433
0.16
absorbance
StndConc
mg/L
27.91
is greater
27.82
is greater
27.88
is greater
27.87
0.0433
0.16
is greater
BlnkCorr
Signal
0.982
than that
0.979
than that
0.981
than that
0.980
0.002
0.16
than that
Peak Bkgnd Time
Area Area
0.849 0.179 15:36:32
of the highest standard.
0.846 0.179 15:36:34
of the highest standard.
0.848 0.180 15:36:36
of the highest standard.
of the highest standard.
Element: Ni Seq. No.: 121
Sample ID: CCB
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
0.
0.
0.
0.
0.
StndConc
mg/L
0025
0061
0167
0084
0074
0.
0.
0.
0.
0.
0025
0061
0167
0084
0074
BlnkCorr
Signal
0.
0.
0.
0.
0.
000
000
001
000
000
Peak
Area
-0.
-0.
-0.
132
132
132
Bkgnd
Area
0
0
0
.166
.166
.166
Time
15:37:17
15:37:19
15:37:21
%RSD:
87.95
87.95
87.95
Element: Ni Seq. No.: 122
Sample ID: 306-1 SER
AS Loc.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
16.24
absorbance
16.28
absorbance
16.29
absorbance
16.27
0.0272
0.17
absorbance
S
m
is
is
is
is
tndConc
g/L
16.24
greater
16.28
greater
16.29
greater
16.27
0.0272
0.17
greater
Blnk
Sig
0.
than
0.
than
0.
than
0.
0.
0
than
Corr
nal
571
that
573
that
573
that
572
001
.17
that
Pe
Ar
0.
of
0.
of
0.
of
of
ak
ea
439
the
440
the
440
the
the
Bkgnd
Area
0.17
highest
0.17
highest
0.17
highest
highest
0
st
1
st
1
st
st
Time
15:37:
andard.
15:38:
andard.
15:38:
andard.
andard.
59
01
03
Element: Ni Seq. No.: 123
Sample ID: CCB
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
0.0215
-0.0321
-0.0131
-0.0079
0.0272
StndConc
mg/L
0.0215
-0.0321
-0.0131
-0.0079
0.0272
BlnkCorr
Signal
0.001
-0.001
0.000
0.000
0.001
Peak
Area
-0.132
-0.134
-0.133
Bkgnd
Area
0.165
0.165
0.165
Time
15:38
15:38
15:38
:22
:24
:26
%RSD:
343.1
343.1
343.14
Page 31
-------
Element: Ni Seq. No.:
Sample ID: 306-1 X10
124
AS LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
3D :
%RSD:
Sample
SampleConc
mg/L
11.65
absorbance
11.61
absorbance
11.63
absorbance
11.63
0.0227
0.20
absorbance
StndConc
mg/L
11.65
is greater
11.61
is greater
11.63
is greater
11.63
0.0227
0.20
is greater
BlnkCorr
Signal
0.410
than that
0.408
than that
0.409
than that
0.409
0.001
0.20
than that
Peak Bkgnd Time
Area Area
0.277 0.166 15:39:05
of the highest standard.
0.276 0.167 15:39:08
of the highest standard.
0.277 0.168 15:39:10
of the highest standard.
of the highest standard.
Element: Ni Seq.
Sample ID: CCB
No.: 125
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
.0823
.0703
.0825
.0784
.0070
8.89
StndConc
mg/L
0.
0.
0.
0.
0.
0823
0703
0825
0784
0070
8.89
BlnkCorr Peak
Signal Area
0
0
0
0
0
.003 -0.130
.002 -0.130
.003 -0.130
.003
.000
8.89
Bkgnd Time
Area
0.161 15:40:11
0.161 15:40:13
0.161 15:40:15
Element: Ni Seq. No.: 126
Sample ID: 306-1 X25
AS LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.726
absorbance
5.741
absorbance
5.708
absorbance
5.725
0.0165
0.29
absorbance
StndConc
mg/L
is
is
is
is
5.726
greater
5.741
greater
5.708
greater
5.725
0.0165
0.29
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
201
that
202
that
201
that
201
001
.29
that
Peak
Area
0.
of
0.
of
0.
of
of
069
the
069
the
068
the
the
Bkgnd
Area
0.166
highest
Time
15:40:
37
standard.
0.166
highest
15:40:
39
standard.
0.167
highest
highest
15:40:
41
standard.
standard.
Element: Ni Seq. No.: 127
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0570
.0257
.0072
.0300
.0252
84.01
StndConc
mg/L
-0
-0
-0
-0
0
.0570
.0257
.0072
.0300
.0252
84.01
BlnkCorr
Signal
-0.002
-0.001
0.000
-0.001
0.001
84.01
Peak
Area
-0.
-0.
-0.
135
133
133
Bkgnd
Time
Area
0
0
0
.165
.164
.164
15:40:
15:40:
15:40:
55
57
59
Page 32
-------
Element: Ni Seq.
Sample ID: CCB
No.: 128
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0635
0.0660
0.0576
0.0624
0.0043
6.89
StndConc
mg/L
0.0635
0.0660
0.0576
0.0624
0.0043
6.89
BlnkCorr Peak
Signal Area
0.002 -0.130
0.002 -0.130
0.002 -0.131
0.002
0.000
6.89
Bkgnd Time
Area
0.161 15:41:39
0.161 15:41:41
0.161 15:41:43
Element: Ni Seq. No.: 129
Sample ID: CCV
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
.5086
.4838
.4892
.4939
.0130
2.63
StndConc
mg/L
0.
0.
0.
0.
0.
5086
4838
4892
4939
0130
2.63
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
2
018 -0.115
017 -0.116
017 -0.115
017
000
.63
Bkgnd Time
Area
0.163 15:42:01
0.164 15:42:03
0.164 15:42:05
Element: Ni Seq. No.: 130
Sample ID: CCB
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0150
-0.0110
-0.0386
-0.0215
0.0149
69.14
StndConc
mg/L
-0.0150
-0.0110
-0.0386
-0.0215
0.0149
69.14
BlnkCorr Peak
Signal Area
-0.001 -0.133
0.000 -0.133
-0.001 -0.134
-0.001
0.001
69.14
Bkgnd Time
Area
0.164 15:42:22
0.163 15:42:24
0.164 15:42:26
Element: Ni Seq. No.: 131
Sample ID: 306-2
AS Loc.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.557
absorbance
6.589
absorbance
6.615
absorbance
6.587
0.0288
0.44
absorbance
StndConc
mg/L
6.557
is greater
6.589
is greater
6.615
is greater
6.587
0.0288
0.44
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
231
that
232
that
233
that
232
001
.44
that
Peak
Area
0
of
0
of
0
of
of
.098
the
.099
the
.100
the
the
Bkgnd
Area
0.171
highest
Time
15:42:
39
standard.
0.171
highest
15:42:
42
standard.
0.171
highest
highest
15:42:
44
standard.
standard.
Page 33
-------
Element: Mi Seq. No.: 132
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0793
0.0751
0.0692
0.0745
0.0051
6.79
StndConc
mg/L
0.0793
0.0751
0.0692
0.0745
0.0051
6.79
BlnkCorr Peak
Signal Area
0.003 -0.130
0.003 -0.130
0.002 -0.130
0.003
0.000
6.79
Bkgnd Time
Area
0.161 15:42:56
0.162 15:42:58
0.161 15:43:00
Element: Ni Seq. No.: 133
Sample ID: 306-3
AS LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
24.44
absorbance
24.47
absorbance
24.45
absorbance
24.45
0.0189
0.08
absorbance
StndConc
mg/L
is
is
is
is
24.44
greater
24.47
greater
24.45
greater
24.45
0.0189
0.08
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
860
that
861
that
860
that
860
001
.08
that
Peak
Area
0
of
0
of
0
of
of
.727
the
.728
the
.728
the
the
Bkgnd
Area
0.176
highest
Time
15:43:
18
standard.
0.176
highest
15:43:
20
standard.
0.176
highest
highest
15:43:
22
standard.
standard.
Element: Ni Seq. No.: 134
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0384
0.0240
0.0046
0.0223
0.0170
76.12
StndConc
mg/L
0.0384
0.0240
0.0046
0.0223
0.0170
76.12
BlnkCorr Peak
Signal Area
0.001 -0.131
0.001 -0.132
0.000 -0.132
0.001
0.001
76.12
Bkgnd Time
Area
0.164 15:43:43
0.164 15:43:45
0.165 15:43:48
Element: Ni Seq. No.: 135
Sample ID: 306-3 X25
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.083
3.065
3.059
3.069
0. 0124
0.40
StndConc
mg/L
3.083
3.065
3.059
3.069
0.0124
0.40
BlnkCorr Peak
Signal Area
0.108 -0.024
0.108 -0.025
0.108 -0.025
0.108
0.000
0.40
Bkgnd Time
Area
0.164 15:44:42
0.165 15:44:45
0.165 15:44:47
Page 34
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.1093
-0.0679
-0.0162
-0.0644
0.0467
72.42
: Ni Seq
ID: 306-4
SampleConc
mg/L
0.0127
-0.0183
-0.0289
-0.0115
0.0216
188.6
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0835
0.0926
0.0821
0.0861
0.0057
6.61
: Ni Seq
ID: 306-5
SampleConc
mg/L
0.1306
0.1487
0.1567
0.1453
0.0133
9.18
. No. : 136
StndConc
mg/L
-0.1093
-0.0679
-0.0162
-0.0644
0.0467
72.42
. No. : 137
StndConc
mg/L
0.0127
-0.0183
-0.0289
-0.0115
0.0216
188.6
. No. : 138
StndConc
mg/L
0.0835
0.0926
0.0821
0.0861
0.0057
6.61
. No. : 139
StndConc
mg/L
0.1306
0.1487
0.1567
0.1453
0.0133
9.18
AS Loc. :
BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.002 -0.135
-0.001 -0.133
-0.002
0.002
72.42
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 -0.132
-0.001 -0.133
-0.001 -0.134
0.000
0.001
188.57
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 -0.130
0.003 -0.129
0.003 -0.130
0.003
0.000
6.61
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 -0.128
0.005 -0.127
0.006 -0.127
0.005
0.000
9.18
Date: 11/07/2005
Bkgnd Time
Area
0.168 15:44:59
0.166 15:45:01
0.165 15:45:04
Date: 11/07/2005
Bkgnd Time
Area
0.167 15:45:18
0.167 15:45:21
0.168 15:45:23
Date: 11/07/2005
Bkgnd Time
Area
0.161 15:45:38
0.161 15:45:40
0.161 15:45:42
Date: 11/07/2005
Bkgnd Time
Area
0.164 15:45:57
0.165 15:46:00
0.165 15:46:02
Page 35
-------
Element: Ni Seq. No.: 140
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0432
.0378
.1481
.0764
. 0622
81.43
StndConc
mg/L
-0
-0
-0
— 0
0
.0432
.0378
.1481
.0764
.0622
81.43
BlnkCorr
Signal
-0.002
-0.001
-0.005
-0.003
0.002
81.43
Peak
Area
-0.
-0.
-0.
134
134
138
Bkgnd
Time
Area
0.
0.
0.
165
165
169
15:46:
15:46:
15:46:
12
14
16
Element: Ni Seq. No.: 141
Sample ID: CCV
AS LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
10.04
absorbance
10.00
absorbance
10.22
absorbance
10.09
0.1181
1.17
absorbance
StndConc
mg/L
10.04
is greater
10.00
is greater
10.22
is greater
10.09
0.1181
1.17
is greater
BlnkCorr
Signal
0.353
than that
0.352
than that
0.360
than that
0.355
0.004
1.17
than that
Peak Bkgnd Time
Area Area
0.221 0.169 15:46:38
of the highest standard.
0.219 0.169 15:46:40
of the highest standard.
0.227 0.170 15:46:42
of the highest standard.
of the highest standard.
Page 36
-------
Set*
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S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
PROJECT #
1 2
2005110203:
345
METHOD 29 FOR NICKEL
6789 10
11
12
SA#
2
3
1
5
6
8
9
7
11
12
10
14
15
17
18
16
20
21
19
23
24
26
27
29
30
32
33
SAMPLE
DESCRPT1ON
impinger
filter
probe rinse
impinger
filter
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
impinger
filter
impinger
filter
impinger
filter
impinger
'filte'K\ •
RUN ID
Cond. 14:
TEST #1
Cond. 14:
TEST #2
Cond. 14:
TEST #3
BLANK
Cond. 7: TEST
#1
Cond. 7: TEST
#2
Cond. 7: TEST
#3
BLANK
Cond. 24:
TESTS1
Cond. 24:
TEST #2
Cond. 24:
RUN #3
/' MDL -/
PH
<2.0
<2.0
<20
<20
<20
<2.0
<20
<2.0
<20
<20
<2.0
<20
<2.0
<2.0
< 20
<20
<20
<20
<20
< 2 C
<20
Sample
Fraction
(SF = SFA)
313
1 filter
92.0
315
1 filter
94 0
312
1 filter
97.0
298
1 filter
98.0
296
1 filter
97 0
296
1 filter
98.0
297
1 filter
96.0
299
1 filter
298
1 filter
99.0
300
1 filter
100.0
1 filter
97 0
3ti0
;- 1 filter
- 180,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
•~ ;NA",
^20- =
REAGENTS
FOR DIG.
HNO3 -v H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HF + HNO3
HF + HNO3
HN03 * H202
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HN03
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF +• HNO3
HF + HNO3
HF + HNO3
HF + HNO3
HF + HNO3
HF + HN03
HF + HNO3
•'H|!*HN03
HJi& HN03
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
' 8.3,15
8,3.12-
Analytical
Fraction
(AF = AF.O
50
100
50
100
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
- 50V
£:t100>
\ «
Nl mg/L
( Ca1 or Ca2 )
0.135
0.265
0.101
0.319
0.111
0.256
0.080
0.159
0.101
2.434
2.763
< 0.074
-6.164
0.084
0.183
0.095
1.472
2.277
< 0.074
2.123
' , 0.075" *
,/' 0.075
MGNI
IN INITIAL
SAMPLE
0.007
0.027
0.005
0.032
0.026
0.004
0.016
0.005
0.243
0.276
0.004
0.616
0.004
0.018
0.147
0.228
0.004
0.212
* 0.004
'* -o;oos
^ o ;; -
TOTAL MG
PER RUN
0.033
0.037
0.031
0.020
0.248
0.280
0.620
0.023
0.152
0.232
0.216
o;on
10 Samples that read
-------
PROJECT # 2005120032: METHOD 306A FOR NICKEL
8
SA#
1
2
3
4
*
SAMPLE DESCRPTION
12/01/2005 -CONDITION
#26 - RUN #1
12/01/2005 -CONDITION
#26 - RUN #2
12/01/2005 - CONDITION
#26 - RUN #3
12/01/2005 -BLANK
'\WZfc;>~J
PH
<2.0
<2.0
<2.0
<2.0
" ~^2^"
Sample
Fraction
397.0
395.0
388.0
360.0
- "<;
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
~ ' ' KiiJOS
Analytical
Fraction
50.0
50.0
50.0
50.0
-x; 50.o ,;;
Nl mg/L
1.324
2.388
2.139
0.101
~'sr 0.075 "'.,
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.066
0.119
0.107
0.005
0,004
Samples that read
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
r 5100 AA
1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
Date: _
Analyst:
2/1/2006
LK
(For Specific instrument settings, see current copy of method.)
(Mfl/L)
tDL- 0.027
MDL= 0.075
RL = 0.10
LDR = 0.10 to 8.0
3
CALIBRATION:
Cal Curve:
Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Abs
0.012
0.022
0.041
0.079
0.182
Result
0.315
0.592
1.111
2.121
4.908
0.9984
% Rec.
126.0
118.4
111.1
106.1
98.2
4 STANDARD TRACEABILITY
QC STANDARD
Standard Name, Company, & Lot #
Calibration
CPIQC-21 Lot#05H062
CCV. CRA, AAT
CPIQC-21 Lot#05H062
QCS, LFM
CPIQC-19Lot#05F011
> 0.935)
s SAMPLE ANALYTICAL RUN
MAT-RIX
M2^
20XMDL)
<10%DIFF)
20XMDL)
(<10%DIFF)
(< MDL )
(90-110%R)
^
2/^
(< MDL )
( 90-11 0%R)
-------
QA/QC WORK SHEET for NICKEL P2
FKAA METHOD SOP MET-040
5100 AA
Date:
Analyst:
2/1/2006
LK
* QAMPI F ANALYTICAL RUN
MAT-RIX
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
WI29
SAMPLE
203-31+33
LRB
LFB
CCB
CCV
*203-2
SPK
DUP
SER DiL
203-5
203-8
CCB
CCV
203-1 1
203-14
203-17
203-20
CCB
CCV
203-23
203-26
DUP
703 29
203-32
CCB
CCV
STD CONC
1 00
050
1.0
1.0
025
050
1.00
READING
Mg/L
0.219
0.112
1.084
0024
0542
0 153
1.119
1.094
0.281
0 133
0.128
0019
0.281
0.118
0 122
0073
0069
0004
0490
0069
0.093
0.100
0083
0071
0003
0.940
BLK
0.035
0.035
0022
0.010
0024
0018
0.025
0035
-0.004
0032
0.017
0035
0019
0039
0.021
0.007
0000
-0.004
0004
-0.015
-0 002
-0.011
-0.001
0004
0010
0003
RESULT
0 183
0.077
1.062
0.014
0518
0.135
1.094
1 059
0.285
0.101
0.111
-0.016
0.262
0.080
0.101
0067
0069
0009
0485
0.084
0.095
0.112
0.084
0.066
-0.007
0937
DILI
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
DIL 2
1.0
1.0
• .0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
-.0
1.0
1.0
1.0
-.0
QC
RESULTS
0.077
106
0.014
104
96
3.3
30.4
-0.016
105
0.009
97
16.3
-0.007
94
Mg/L
0.183
0.135
0.101
0.111
0.080
0.101
0.067
0.069
0.084
0.095
0.084
0.066
REPT
mq/L
0.183
0.135
0.101
0.111
0.080
0.101
0.074
0.074
0.084
0.095
0.084
0.074
!££
o . c "I V
Q. *&!>
, i>TJ
a£> / L> 5;
20XMDL)
<10%DIFF)
;< MDL }
90-110%R)
(< MDL)
(90-110%R)
;< MDL )
( 90-110%R)
-------
Method Name: NI
Method Description: Nickel
Date: 02/01/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 71
Results Data Set:
Element: Ni Seq. No.: 115
AS Loc.
Date: 02/01/2006
Repl
#
i
j.
0
£,
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
232.33
Peak
Area
0.097
0.097
0.098
Bkgnd
Area
0.006
0.006
0.006
Time
15:02:30
15:02:32
15:02:34
Auto-zero performed.
Element: Ni Seq. No.: 116
Sample ID: Calib Blank
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L
BlnkCorr
Signal
-0.001
0.000
0.000
0.000
0.001
347.18
Peak
Area
0.096
0.098
0.098
Bkgnd
Area
0.007
0.006
0.006
Time
15:02:39
15:02:41
15:02:43
Auto- zero performed.
Element: Ni Seq. No.: 117
Sample ID: CAL STD
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.012
0.012
0.012
0.012
0.000
1.65
Peak
Area
0.109
0.109
0.109
Bkgnd
Area
0.005
0.005
0.005
Time
15:03:16
15:03:18
15:03:20
Standard number 1 applied. [0.25]
Correlation Coefficient: 0.9991
Slope: 0.0358
Page 32
-------
Element; Ni Seq. No.: 118 AS :
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
I 0.022
2 0.023
3 0.022
Mean: 0.022
SD : 0.000
%RSD: 2.16
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9987
Element: Ni Seq. No.: 119 AS
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.041
2 0.042
3 0.041
Mean: 0.041
SD : 0.001
%RSD: 1-44
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9982
Element: Ni Seq. No.: 120 AS
Sample ID: cal std 4
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.079
2 0.078
3 0.079
Mean: 0.079
SD : 0.001
%RSD: 1-09
Standard number 4 applied. [2.00]
Correlation Coefficient: 0.9973
Element: Ni Seq. No.: 121 AS
Sample ID: cal std 5
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.182
2 0.182
3 0.183
Mean: 0.182
SD : 0.001
%RSD: 0.41
Loc. :
Peak
Area
0.119
0.120
0.119
Loc. :
Peak
Area
0.138
0.139
0.139
Loc. :
Peak
Area
0.176
0.175
0.177
Loc. :
: Peak
Area
0.279
0.279
0.280
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:03:35
0.004 15:03:37
0.005 15:03:39
Slope: 0.0359
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:04:04
0.005 15:04:06
0.005 15:04:08
Slope: 0.0359
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:04:33
0.006 15:04:35
0.005 15:04:37
Slope: 0.0362
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:04:56
0.004 15:04:59
0.005 15:05:01
The calibration curve may not be linear.
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9984
Slope: 0.0371
Page 33
-------
a>
o
I
O
W
0.20
0.15
0.10
0.05
Concentration
_C3.-L_UiJ.Lei L-O-WXi v-ia. <-a. J-v-'-i- A*
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.012
0.022
0.041
0.079
0.182
Correlation Coefficient: 0.99840
Entered
Concentration
(mg/L)
0.25
0.50
1.00
2.00
5.00
Slope: 0.
Calculated
Concentration
(mg/L)
0.000
0.3151
0.5922
1.111
2.121
4.908
03712
Standard
Deviation
0.0009
0.0002
0.0005
0.0006
0.0009
0.0007
%RSD
347.1791
1.6548
2.1610
1.4366
1.0851
0.4110
No.: 122
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4. 920
4.914
4.968
4.934
0.0296
0.60
StndConc
mg/L
4.920
4.914
4.968
4.934
0.0296
0.60
BlnkCorr Peak
Signal Area
0.183 0.280
0.182 0.280
0.184 0.282
0.183
0.001
0.60
Bkgnd Time
Area
0.006 15:05:13
0.006 15:05:15
0.005 15:05:18
Page 34
-------
No.: 123
AS Loc.
Date:
02/01/2006
Repl
# :
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.148
2.118
2.137
2.134
0.0154
0.72
StndConc
mg/L
2.148
2.118
2.137
2.134
0.0154
0.72
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.080 0.177 0.006 15:05:44
0 079 0.176 0.005 15:05:46
o!o79 0.177 0.005 15:05:48
0.079
0.001
0.72
Element: Ni Seq,
Sample ID: std-10
No.: 124
AS Loc.
Date: 02/01/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
8.988
absorbance
8.885
absorbance
9.003
absorbance
8.959
0.0641
0.72
absorbance
StndConc
mg/L
8.988
is greater
8.885
is greater
9.003
is greater
8.959
0.0641
0.72
is greater
BlnkCorr
Signal
0.334
than that
0.330
than that
0.334
than that
0.333
0.002
0.72
than that
Peak Bkgnd Time
Area Area
0.431 0.006 15:06:19
of the highest standard.
0.427 0.006 15:06:21
of the highest standard.
0.431 0.005 15:06:23
of the highest standard.
of the highest standard.
Element: Ni Seq. No.: 125
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0065
0.0023
0.0043
0.0001
0.0058
StndConc
mg/L
-0.0065
0.0023
0.0043
0.0001
0.0058
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
Peak
Area
0.097
0.097
0.097
Bkgnd
Area
0.006
0.006
0..006
Time
15:09:
15:09:
15:09:
53
55
57
%RSD:
9583
9583
9582.80
Element: Ni Seq. No.: 126
Sample ID: cra-0.05
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.
0991
0852
0998
0947
0082
8.69
StndConc
mg/L
0.0991
0.0852
0.0998
0.0947
0.0082
8.69
BlnkCorr
Signal
0.004
0.003
0.004
0.004
0.000
8.69
Peak
Area
0.101
0
0
.100
.101
Bkgnd
Area
0.005
0.
0.
006
005
Time
15:
15:
15:
10
10
10
:19
:21
:23
Page 35
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0187
2 0.0294
3 0.0086
Mean: 0.0189
3D : 0.0104
%RSD: 54.77
Element: Ni Seq.
Sample ID: era- 0.1
Repl SampleConc
# mg/L
1 0.1378
2 0.1557
3 0.1283
Mean: 0.1406
3D : 0.0139
%RSD: 9-89
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0418
2 0.0314
3 0.0124
Mean: 0.0285
Si) : 0.0149
%RSD: 52.18
Element: Ni Seq
Sample ID: cra-0.1
Repl SampleConc
# mg/L
1 0.1277
2 0.1313
3 0.1104
Mean: 0.1232
SD : 0.0112
%RSD: 9.07
No. : 127
StndConc
mg/L
0.0187
0.0294
0.0086
0.0189
0.0104
54.77
No.: 128
StndConc
mg/L
0.1378
0.1557
0.1283
0.1406
0.0139
9.89
= :
. No. : 129
StndConc
mg/L
0.0418
0.0314
0.0124
0.0285
0.0149
52.18
. No. : 130
StndConc
mg/L
0.1277
0.1313
0.1104
0.1232
0.0112
9.07
AS LOG. :
BlnkCorr Peak
Signal Area
0.001 0.098
0.001 0.098
0.000 0.098
0.001
0.000
54.77
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.102
0.006 0.103
0.005 0.102
0.005
0.001
9.89
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.099
0.001 0.098
0.000 0.098
0.001
0.001
52.18
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.102
0.005 0.102
0.004 0.101
0.005
0.000
9.07
Date; 02/01/2006
Bkgnd Time
Area
0.006 15:10:39
0.005 15:10:42
0.006 15:10:44
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:11:04
0.005 15:11:06
0.006 15:11:08
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:11:21
0.005 15:11:23
0.006 15:11:25
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:11:59
0.006 15:12:01
0.006 15:12:03
Page 36
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0068
2 0.0050
3 -0.0031
Mean: 0.0029
SD : 0.0053
%RSD: 179.4
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 0.1121
2 0.1043
3 0.0726
Mean: 0.0963
SD : 0.0209
%RSD: 21.70
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0236
2 0.0335
3 0.0150
Mean: 0.0240
SD : 0.0093
%RSD: 38.65
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.110
2 1.082
3 1.065
Mean: 1.086
SD : 0.0227
%RSD: 2.09
. No. : 131
StndConc
mg/L
0.0068
0.0050
-0.0031
0.0029
0.0053
179.4
. No. : 132
StndConc
mg/L
0.1121
0.1043
0.0726
0.0963
0.0209
21.70
. No.: 133
StndConc
mg/L
0.0236
0.0335
0.0150
0.0240
0.0093
38.65
. No.: 134
StndConc
mg/L
1.110
1.082
1.065
1.086
0.0227
2.09
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
179.37
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 0.101
0.004 0.101
0.003 0.100
0.004
0.001
21.70
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.098
0.001 0.098
0.001 0.098
0.001
0.000
38.65
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.138
0.040 0.137
0.040 0.137
0.040
0.001
2.09
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:12:19
0.006 15:12:21
0.006 15:12:24
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:12:40
0.005 15:12:42
0.006 15:12:45
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:12:59
0.006 15:13:01
0.006 15:13:03
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:13:27
0.005 15:13:29
0.006 15:13:31
Page 37
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0294
2 0.0375
3 0.0290
Mean: 0.0320
SD : 0.0048
%RSD: 14.99
Element: Ni Seq
Sample ID: *038-1
Repl SampleConc
# mg/L
I 1.353
2 1.355
3 1.361
Mean: 1.356
SD : 0.0042
%RSD: 0.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0155
2 0.0348
3 0.0254
Mean: 0.0252
SD : 0.0096
%RSD: 38.22
Element : Ni Seq
Sample ID: s038-l
Repl SampleConc
# mg/L
1 2.234
2 2.194
3 2.237
Mean: 2.222
SD : 0.0238
%RSD: 1.07
. No. : 135 AS I
StndConc BlnkCorr
mg/L Signal
0.0294 0.001
0.0375 0.001
0.0290 0.001
0.0320 0.001
0.0048 0.000
14.99 14.99
. No. : 136 AS I
StndConc BlnkCorr
mg/L Signal
1.353 0.050
1.355 0.050
1.361 0.051
1.356 0.050
0.0042 0.000
0.31 0.31
. No. : 137 AS :
StndConc BlnkCorr
mg/L , Signal
0.0155 0.001
0.0348 0.001
0.0254 0.001
0.0252 0.001
0.0096 0.000
38.22 38.22
. No. : 138 AS
StndConc BlnkCorr
rng/L Signal
2.234 0.083
2.194 0.081
2.237 0.083
2.222 0.082
0.0238 0.001
1.07 1.07
JOG . :
Peak
Area
0.098
0.099
0.098
LOG. :
Peak
Area
0.147
0.148
0.148
LOG. :
Peak
Area
0.098
0.099
0.098
LOG. :
Peak
Area
0.180
0.179
0.180
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:13:43
0.005 15:13:45
.0.006 15:13:47
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:14:06
0.005 15:14:09
0.005 15:14:11
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:14:23
0.005 15:14:26
0.005 15:14:28
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:14:50
0.006 15:14:52
0.005 15:14:54
Page 38
-------
Element
Sample
Repl
#
1
2
3
Mean:
3D :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
- 3
Mean:
SD :
%RSD:
Elemenl
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0481
0.0263
0.0234
0.0326
0.0135
41.38
:: Ni Seq,
ID: sd038-l
SampleConc
mg/L
2.149
2.170
2.185
2.168
0.0183
0.84
;: Ni Seq
ID: ccb
SampleConc
mg/L
0.0452
0.0465
0.0396
0.0438
0,0036
8.32
-: Ni Seq
ID: ser038-
SampleConc
mg/L
0.5142
0.5086
0.5290
0.5173
0.0105
2.03
No.: 139
StndConc
mg/L
0.0481
0.0263
0.0234
0.0326
0.0135
41.38
. No.: 140
StndConc
mg/L
2.149
2.170
2.185
2.168
0.0183
0.84
. No.: 141
StndConc
mg/L
0.0452
0.0465
0.0396
0.0438
0.0036
8.32
. No. : 142
1
StndConc
mg/L
0.5142
0.5086
0.5290
0.5173
0.0105
2.03
AS I
BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.001
41.38
AS ]
BlnkCorr
Signal
0.080
0.081
0.081
0.080
0.001
0.84
AS :
BlnkCorr
Signal
0.002
0.002
0.001
0.002
0.000
8.32
AS
BlnkCorr
Signal
0.019
0.019
0.020
0.019
0.000
2.03
JOG . :
Peak
Area
0.099
0.098
0.098
LOG. :
Peak
Area
0.177
0.178
0.178
Loc. :
Peak
Area
0.099
0.099
0.099
Loc. :
Peak
Area
0.116
0.116
0.117
Date? C
Bkgnd
Area
0.005
0.005
0.005
Date: (
Bkgnd
Area
0.005
0.005
0.005
Date: i
Bkgnd
Area
0.005
0.005
0.005
Date:
Bkgnd
Area
0.005
0.005
0.005
12/01/2006
Time
15:15:08
15:15:10
15:15:12
)2/01/2006
Time
15:15:37
15:15:39
15:15:41
02/01/2006
Time
15:16:01
15:16:03
15:16:05
02/01/2006
Time
15:16:33
15:16:35
15:16:38
Page 39
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0339
2 0.0202
3 -0.0227
Mean: 0.0105
SD : 0.0295
%RSD: 282.4
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0025
2 0.0141
3 -0.0097
Mean: 0.0006
SD : 0.0122
%RSD: 2031
Element: Ni Seq,
Sample ID: ccv-1
Repl SampleConc
# mg/L
1 1.113
2 1.109
3 1.089
Mean: 1.104
SD : 0.0129
%RSD: 1.17
Element: Ni Seq
Sample ID: ccv-1
Repl SampleConc
# mg/L
1 0.9836
2 0.9625
3 1.004
Mean: 0.9835
SD : 0.0209
%RSD: 2.13
No.: 143
StndConc
mg/L
0.0339
0.0202
-0.0227
0.0105
0.0295
282.4
No.: 144
StndConc
mg/L
-0.0025
0.0141
-0.0097
0.0006
0.0122
2031
.No.: 145
StndConc
mg/L
1.113
1.109
1.089
1.104
0.0129
1.17
. No.: 146
StndConc
mg/L
0.9836
0.9625
1.004
0.9835
0.0209
2.13
AS I
BlnkCorr
Signal
0.001
0.001
-0.001
0.000
0.001
282.44
AS 1
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
2030.57
AS :
BlnkCorr
Signal
0.041
0.041
0.040
0.041
0.000
1.17
AS
BlnkCorr
Signal
0.037
0.036
0.037
0.037
0.001
2.13
ioc. :
Peak
Area
0.098
0.098
0.096
Joe. :
Peak
Area
0.097
0.098
0.097
LOG. :
Peak
Area
0.139
0.138
0.138
Loc. :
Peak
Area
0.134
0.133
0.135
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:17:03
0.005 15:17:05
0.007 15:17:07
Date: 02/01/2006
Bkgnd Time
Area
0.007 15:17:21
0.006 15:17:23
0.007 15:17:25
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:17:50
0.005 15:17:52
0.006 15:17:54
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:18:19
0.006 15:18:21
0.005 15:18:23
Page 40
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0002
2 -0.0004
3 -0.0027
Mean: -0.0010
SD : 0.0015
%RSD: 159.5
Element: Ni Seq.
Sample ID: 038-2
Repl SampleConc
# mg/L
1 2.404
2 2.397
3 2.360
Mean: 2.387
SD : 0.0239
%RSD: 1.00
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0045
2 0.0196
3 0.0186
Mean: 0.0112
SD : 0.0136
%RSD: 121.4
Element: Ni Seq.
Sample ID: 038-3
Repl SampleConc
# mg/L
1 2.161
2 2.145
3 2.144
Mean: 2.150
SD : 0.0098
%RSD: 0.46
No.: 147
StndConc
mg/L
0.0002
-0.0004
-0.0027
-0.0010
0.0015
159.5
No. : 148
StndConc
mg/L
2.404
2.397
2.360
2.387
0.0239
1.00
No.: 149
StndConc
mg/L
-0.0045
0.0196
0.0186
0.0112
0.0136
121.4
No.: 150
StndConc
mg/L
2.161
2.145
2.144
2.150
0.0098
0.46
AS LOG. :
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
159.47
AS LOG. :
BlnkCorr Peak
Signal Area
0.089 0.186
0.089 0.186
0.088 0.185
0.089
0.001
1.00
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.097
0.001 0.098
0.001 0.098
0.000
0.001
121.43
AS Loc. :
BlnkCorr Peak
Signal Area
0.080 0.177
0.080 0.177
0.080 0.177
0.080
0.000
0.46
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:18:45
0.006 15:18:47
0.006 15:18:49
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:19:11
0.005 15:19:14
0.006 15:19:16
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:19:42
0.006 15:19:44
0.006 15:19:46
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:20:03
0.005 15:20:05
0.006 15:20:07
Page 41
-------
Element
Sample
Repl
#
-\_
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: ccb
SampleConc
mg/L
0. 0243
0.0160
0.0213
0.0205
0.0042
20.40
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 038-4
SampleConc
mg/L
0.1126
0.1211
0.1312
0.1216
0.0093
7.64
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0191
0.0137
0.0393
0.0240
0.0135
56.13
, No. : 151
StndConc
mg/L
0.0243
0.0160
0.0213
0.0205
0.0042
20.40
. No. : 152
StndConc
mg/L
0.1126
0.1211
0.1312
0.1216
0.0093
7.64
. No.: 153
StndConc
mg/L
0.0191
0.0137
0.0393
0.0240
0.0135
56.13
Element: Ni Sej^-~*O7-r~l-S4.,
Sample^
Repl
#
1
2
3
Mean:
SD :
%RSD:
AS I
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
20.40
JOG . :
Peak
Area
0.098
0.098
0.098
AS Loc. :
BlnkCorr
Signal
0.004
0.004
0.005
0.005
0.000
7.64
Peak
Area
0.101
0.102
0.102
AS Loc. :
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.001
56.13
AS
Peak
Area
0.098
0.098
0.099
Loc. :
Date: 0
Bkgnd
Area
0.005
0.006
0.005
2/01/2006
Time
15:20:21
15:20:24
15:20:26
Date: 02/01/2006
Bkgnd
Area
0.005
0.005
0.005
Time
15:20:40
15:20:42
15:20:44
Date: 02/01/2006
Bkgnd
Area
0.006
0.005
0.005
Date:
Time
15:21:03
15:21:05
15:21:07
02/01/2006
ID: SamplellS \
\ S \ ^ : •
-\--- -^
SalB^xLeConc
mg//L\
/ 0.0694
/ 0.0843\<
1 0.0807/
\ 0.07^1
\0-j0t) 7 8
X^9.99
^
StndCorfCx
mg/L/ \
J0<0694 J
/0.0843 /
\ 0.0807/
X1.0783/
oxm-?8
s9>§9
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
9.99
Peak
Area
0.100
0.100
0.100
Bkgnd
Area
0.005
0.005
0.005
Time
15:21:23
15:21:25
15:21:31
Page 42
-------
Element: Ni Seq.
Sample ID: 203-f+pr
Repl SampleConc
# mg/L
1 0.0899
2 0.1382
3 0.1137
Mean: 0.1139
SD : 0.0241
%RSD: 21.19
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0105
2 0.0256
3 0.0086
Mean: 0.0149
SD : 0.0093
%RSD: 62.45
Element: Ni Seq,
Sample ID: 203-f+p]
Repl SampleConc
# mg/L
1 1.109
2 1.130
3 1.124
Mean: 1.121
SD : 0.0109
%RSD: 0.97
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0105
2 0.0353
3 0.0076
Mean: 0.0178
SD : 0.0153
%RSD: 85.82
No. : lt>5
Irb
StndConc
mg/L
0.0899
0.1382
0.1137
0.1139
0.0241
21.19
No. : 156
StndConc
mg/L
0.0105
0.0256
0.0086
0.0149
0.0093
62.45
. No. : 157
c Ifb
StndConc
mg/L
1.109
1.130
1.124
1.121
0.0109
0.97
. No.: 158
StndConc
mg/L
0.0105
0.0353
0.0076
0.0178
0.0153
85.82
AS LOG. :
BlnkCorr Peak
Signal Area
0.003 0.101
0.005 0.102
0.004 0.101
0.004
0.001
21.19
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0.001 0.098
0.000 0.098
0.001
0.000
62.45
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.138
0.042 0.139
0.042 0.139
0.042
0.000
0.97
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.098
0. 001 0.099
0.000 0.098
0.001
0.001
85.82
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:21:52
0.004 15:21:54
0.005 15:21:56
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:22:12
0.005 15:22:14
0.005 15:22:16
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:22:40
0.005 15:22:42
0.006 15:22:44
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:23:01
0.004 15:23:03
0.005 15:23:05
Page 43
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0189
2 0.0423
3 0.0472
Mean: 0.0362
SD : 0.0151
%RSD: 41.83
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0238
2 0.0216
3 0.0229
Mean: 0.0228
SD : 0.0011
%RSD: 4.77
Element: Ni Seq,
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.5731
2 0.5796
3 0.5672
Mean: 0.5733
SD : 0.0062
%RSD: 1.08
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0447
2 0.0335
3 0.0281
Mean: 0.0354
SD : 0.0085
%RSD: 23.86
No.: 159
StndConc
mg/L
0.0189
0.0423
0.0472
0.0362
0.0151
41.83
No.: 160
StndConc
mg/L
0.0238
0.0216
0.0229
0.0228
0.0011
4.77
. No. : 161
StndConc
mg/L
0.5731
0.5796
0.5672
0.5733
0.0062
1.08
. No.: 162
StndConc
mg/L
0.0447
0.0335
0.0281
0.0354
0.0085
23.86
AS I
BlnkCorr
Signal
0.001
0.002
0.002
0.001
0.001
41.83
AS I
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
4.77
AS :
BlnkCorr
Signal
0.021
0.022
0.021
0.021
0.000
1.08
AS
BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.000
23.86
,oc. :
Peak
Area
0.098
0.099
0.099
joe. :
Peak
Area
0.098
0.098
0.098
Loc. :
Peak
Area
0.119
0.119
0.118
Loc. :
Peak
Area
0.099
0.098
0.098
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:24:35
0.005 15:24:37
0.005 15:24:39
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:24:54
0.005 15:24:56
0.005 15:24:58
Date: 02/01/2006
Bkgnd Time
Area
0.004 15:25:24
0.004 15:25:26
0.005 15:25:28
Date: 02/01/2006
Bkgnd Time
Area
0.00.4 15:25:54
0.005 15:25:56
0.004 15:25:59
Page 44
-------
Element: Ni Seq. No.: 163 AS i
Sample ID: *203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.2977 0.2977 0.011
2 0.3029 0.3029 0.011
3 0.3013 0.3013 0.011
Mean: 0.3006 0.3006 0.011
SD : 0.0027 0.0027 0.000
%RSD: 0.89 0.89 0.89
Element: Ni Seq. No. : 164 AS ]
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0061 -0.0061 0.000
2 -0.0292 -0.0292 -0.001
3 -0.0218 -0.0218 -0.001
Mean: -0.0190 -0.0190 -0.001
SD : 0.0118 0.0118 0.000
%RSD: 61.86 61.86 61.86
Element: Ni Seq. No. : 165 AS :
Sample ID: s203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.303 1.303 0.048
2 1.310 1.310 0.049
3 1.346 1.346 0.050
Mean: 1.320 1.320 0.049
SD : 0.0229 0.0229 0.001
%RSD: 1.73 1.73 1.73
Element: Ni Seq. No.: 166 AS
Sample ID: s203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.314 1.314 0.049
2 1.262 1.262 0.047
3 1.250 1.250 0.046
Mean: 1.275 1.275 0.047
SD : 0.0341 0.0341 0.001
%RSD: 2.67 2.67 2.67
JOG . :
Peak
Area
0.108
0.108
0.108
Joe. :
Peak
Area
0.097
0.096
0.096
Loc. :
Peak
Area
0.146
0.146
0.147
Loc. :
Peak
Area
0.146
0.144
0.144
Dates 02/01/2006
Bkgnd Time
Area
0.006 15:28:11
0.006 15:28:13
0.006 15:28:15
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:28:39
0.007 15:28:42
0.007 15:28:44
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:29:18
0.005 15:29:21
0.005 15:29:23
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:29:41
0.007 15:29:44
0.007 15:29:46
Page 45
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc \
4i TtlQ/L
I 0.0034 /
2 -11. 33/
3 -6.31/
Mean: -5.8/82
SD : V^79
%RSD: X6-55
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0114
2 -0.0067
3 -0.0157
Mean: -0.0112
SD : 0.0045
%RSD: 40.12
Element: Ni Seq
No.: 167
/
•—/—
StendConc
\.0034
-\1.33
-6\319
-5.15182
5.6\9
96.55O
, No.: 168
StndConc
mg/L
-0.0114
-0.0067
-0.0157
-0.0112
0.0045
40.12
. No.: 169
AS Loc. :
BlnkCorr
Signal
0.000
-0.421
-0.235
-0.218
0.211
96.55
Peak
Area
0.097
-0.323
-0.137
AS Loc.:
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
40.12
Peak
Area
0.097
0.097
0.097
AS Loc. :
Date: 02/01/2JHH5
/ J
Bkgnd Time /
Area ^^
0.006 15(f30: 12
0.431 15:30-1 15
0.237 15:30:(£7
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:30:44
0.006 15:30:46
0.006 15:30:48
Date: 02/01/2006
Sample ID: sd203-l+3
Repl SampleConc
# mg/L
1 1.336
2 1.350
3 1.342
Mean: 1.343
SD : 0.0072
%RSD: 0.53
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
ft mg/L
1 0.0236
2 0.0146
3 -0.0020
Mean: 0.0121
SD : 0.0130
%RSD: 107.5
StndConc
mg/L
1.336
1.350
1.342
1.343
0.0072
0.53
.No.: 170
StndConc
mg/L
0.0236
0.0146
-0.0020
0.0121
0.0130
107.5
BlnkCorr
Signal
0.050
0.050
0.050
0.050
0.000
0.53
AS
BlnkCorr
Signal
0.001
0.001
0.000
0.000
0.000
107.50
Peak
Area
0.147
0.147
0.147
Loc. :
Peak
Area
0.098
0.098
0.097
Bkgnd Time
Area
0.005 15:31:12
0.005 15:31:14
0.005 15:31:16
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:31:42
0.005 15:31:45
0.006 15:31:47
Page 46
-------
Element: Ni Seq. No.: 171
AS Loc.
Date: 02/01/2006
DcUllp-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.2894
0.3029
0.3002
0.2975
0.0072
2.40
StndConc
mg/L
0.2894
0.3029
0.3002
0.2975
0.0072
2.40
BlnkCorr
Signal
0.011
0.011
0.011
0.011
0.000
2.40
Peak
Area
0.108
0.108
0.108
Bkgnd
Area
0.005
0.005
0.005
Time
15:32:
15:32:
15:32:
09
No.: 172
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0117
0.0086
0.0108
0.0104
0.0016
15.15
StndConc
mg/L
0.0117
0.0086
0.0108
0.0104
0.0016
15.15
: ==:=======
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
15.15
Peak
Area
0.098
0.098
0.098
Bkgnd
Area
0.005
0.005
0.005
Time
15:32:58
15:33:00
15:33:02
Element: Ni Seq. No.: 173
AS Loc.
Date: 02/01/2006
Repl
#
]_
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.3360
0.
0.
0.
0.
3290
3241
3297
0060
1.81
StndConc
mg/L
0.3360
0
0
0
0
.3290
.3241
.3297
.0060
1.81
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.012 0.110 0.005 15:33:34
0
0
0
0
012 0.109 0.005 15:33:36
.012 0.109 0.005 15:33:38
.012
.000
1.81
Element: Ni Seq. No.: 174
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.
0.
-0.
-0.
0.
3804
0018
0148
1311
2160
164.8
StndConc
mg/L
-0.3804
0.0018
-0.0148
-0.1311
0.2160
164.8
BlnkCorr
Signal
-0.014
0.000
-0.001
-0.005
0.008
164.76
Peak
Area
0.083
0.
0.
097
097
Bkgnd
Area
0.018
0.
0.
005
005
Time
15:
15:
15:
34:
34:
34:
01
03
05
Page 47
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0029
2 -0.0150
3 0.0157
Mean: -0.0007
SD : 0.0154
%RSD: 2141
Element: Ni Seq.
Sample ID: 203-7+9
Repl SampleConc
# mg/L
1 0.2816
2 0.2468
3 0.2377
Mean: 0.2554
SD : 0.0232
%RSD: 9.08
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0047
2 0.0085
3 0.0377
Mean: 0.0138
SD : 0.0217
%RSD: 156.9
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0052
2 -0.0330
3 -0.0232
Mean: -0.0205
SD : 0.0141
%RSD: 68.74
No.: 175
StndConc
mg/L
-0.0029
-0.0150
0.0157
-0.0007
0.0154
2141
No.: 176
StndConc
mg/L
0.2816
0.2468
0.2377
0.2554
0.0232
9.08
No.: 177
StndConc
mg/L
-0.0047
0.0085
0.0377
0.0138
0.0217
156.9
No.: 178
StndConc
mg/L
-0.0052
-0.0330
-0.0232
-0.0205
0.0141
68.74
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.097
0.001 0.098
0.000
0.001
2140.82
AS Loc. :
BlnkCorr Peak
Signal Area
0.010 0.108
0.009 0.106
0.009 0.106
0.009
0.001
9.08
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.098
0.001 0.099
0.001
0.001
156.88
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.096
-0.001 0.096
-0.001
0.001
68.74
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:34:14
0.005 15:34:16
0.004 15:34:18
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:34:40
0.006 15:34:42
0.006 15:34:44
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:35:02
0.005 15:35:04
0.004 15:35:06
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:35:13
0.007 15:35:15
0.006 15:35:17
Page 48
-------
Element: Ni Seq.
Sample ID: ccv-0.25
Repl SampleConc
# mg/L
1 0.2530
2 0.2688
3 0.2681
Mean: 0.2633
SD : 0.0090
%RSD: 3.40
Element: Ni Seq.
No.: 179
StndConc
mg/L
0.2530
0.2688
0.2681
0.2633
0.0090
3.40
No. : 180
AS
BlnkCorr
Signal
0.009
0.010
0.010
0.010
0.000
3.40
AS
jjoc. :
Peak
Area
0.107
0.107
0.107
LOG. :
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:35:40
0.005 15:35:42
0.005 15:35:44
Date: 02/01/2006
Sample ID: ccv-0.25
Repl SampleConc
# mg/L
1 0.2733
2 0.2549
3 0.2530
Mean: 0.2604
SD : 0.0112
%RSD: 4.31
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0,0231
2 0.0007
3 -0.0220
Mean: -0.0148
SD : 0.0134
%RSD: 90.90
Element: Ni Seq.
StndConc
mg/L
0.2733
0.2549
0.2530
0.2604
0.0112
4.31
No.: 181
StndConc
mg/L
-0.0231
0.0007
-0.0220
-0.0148
0.0134
90.90
No.: 182
BlnkCorr
Signal
0.010
0.009
0.009
0.010
0.000
4.31
AS
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
90.90
AS
Peak
Area
0.107
0.107
0.107
Loc. :
Peak
Area
0.096
0.097
0.096
Loc. :
Bkgnd Time
Area
0.005 15:36:14
0.006 15:36:16
0.006 15:36:18
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:36:38
0.005 15:36:40
0.006 15:36:42
Date: 02/01/2006
Sample ID: 203-10+12
Repl SampleConc
# mg/L
1 0.1472
2 0.1243
3 0.1614
Mean: 0.1443
SD : 0.0187
%RSD: 12.97
StndConc
mg/L
0.1472
0.1243
0.1614
0.1443
0.0187
12.97
BlnkCorr
Signal
0.005
0.005
0.006
0.005
0.001
12.97
Peak
Area
0.103
0.102
0.103
Bkgnd Time
Area
0.006 15:37:04
0.007 15:37:06
0.005 15:37:09
Page 49
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0184
2 0.0027
3 0.0268
Mean: 0.0037
SD : 0.0226
%RSD: 607.7
Element: Ni Seq
. No.: 183
StndConc
mg/L
-0.0184
0.0027
0.0268
0.0037
0.0226
607.7
. No.: 184
AS
BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
607.72
AS
LOG. :
Peak
Area
0.097
0.097
0.098
Loc. :
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:37:22
0.005 15:37:24
0.005 15:37:27
Date-: 02/01/2006
Sample ID: 203-13+15
Repl SampleConc
# mg/L
1 2.428
2 2.459
3 2.428
Mean: 2.438
SD : 0.0177
%RSD: 0.73
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0038
2 -0.0072
3 -0.0121
Mean: -0.0077
SD : 0.0042
%RS-D: 54.18
Element : Ni Seq
StndConc
mg/L
2.428
2.459
2.428
2.438
0.0177
0.73
. No. : 185
StndConc
mg/L
-0.0038
-0.0072
-0.0121
-0.0077
0.0042
54.18
.No.: 186
BlnkCorr
Signal
0.090
0.091
0.090
0.091
0.001
0.73
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
54.18
AS
Peak
Area
0.187
0.189
0.187
Loc. :
Peak
Area
0.097
0.097
0.097
Loc. :
Bkgnd Time
Area
0.006 15:37:50
0.005 15:37:52
0.005 15:37:54
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:38:12
0.005 15:38:14
0.005 15:38:17
Date: 02/01/2006
Sample ID: 203-16+18
Repl SampleConc
# mg/L
1 2.768
2 2.739
3 2.760
Mean: 2.755
SD : 0.0151
%RSD: 0.55
StndConc
mg/L
2.768
2.739
2.760
2.755
0.0151
0.55
BlnkCorr
Signal
0.103
0.102
0.102
0.102
0.001
0.55
Peak
Area
0.200
0.199
0.200
Bkgnd Time
Area
0.005 15:38:40
0.005 15:38:42
0.005 15:38:44
Page 50
-------
Element: Ni Seq.
Sample ID: ccb
No. : 187
AS Loc
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0074
0.0014
-0.0036
-0.0032
0.0044
139.2
StndConc
mg/L
-0.0074
0.0014
-0.0036
-0.0032
0.0044
139.2
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
139.15
Bkgnd Time
Area
0.006 15:39:09
0.005 15:39:11
0.005 15:39:13
Element: Ni Seq. No.: 188
Sample ID: d203-10+12
AS Loc.
Date: 02/01/2006
Repl £
# n
1
2
3
Mean:
SD :
%RSD:
SampleConc
tig/L
0.1492
0.1512
0.1548
0.1517
0.0028
1.87
StndConc
mg/L
0.1492
0.1512
0.1548
0.1517
0.0028
1.87
BlnkCorr Peak
Signal Area
0.006 0.103
0.006 0.103
0.006 0.103
0.006
0.000
1.87
Bkgnd Time
Area
0.006 15:39:39
0.006 15:39:42
0.006 15:39:44
Element: Ni Seq. No.: 189
Sample ID: ccb
AS Loc.
Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0112
-0.0153
-0.0225
-0.0163
0.0057
StndConc
mg/L
-0.0112
-0.0153
-0.0225
-0.0163
0.0057
BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
Peak
Area
0.097
0.097
0.096
Bkgnd
Area
0.005
0.005
0.005
Time
15:40:
15:40:
15:40:
06
08
10
%RSD:
35.16
35.16
35.16
Element: Ni Seq. No.: 190
Sample ID: 203-19+21
AS Loc.
Date: 02/01/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.157
absorbance
6.100
absorbance
6.187
absorbance
6.148
0.0443
0.72
absorbance
StndConc
mg/L
6.157
is greater
6.100
is greater
6.187
is greater
6.148
0.0443
0.72
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
229
that
226
that
230
that
228
002
.72
that
Peak
Area
0.
of
0.
of
0.
of
of
326
the
324
the
327
the
the
Bkgnd
Area
0.007
highest
Time
15:40:
31
standard.
0.006
highest
15:40:
33
standard.
0.005
highest
highest
15:40;
35
standard.
standard.
Page 51
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0032
2 0.0027
3 -0.0159
Mean: -0.0055
SD : 0.0095
%RSD: 173.4
Element : Ni Seq
. No. : 191
StndConc
mg/L
-0.0032
0.0027
-0.0159
-0.0055
0.0095
173.4
. No. : 192
AS
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
173.39
AS
LOG. :
Peak
Area
0.097
0.097
0.097
Loc. :
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:40:55
0.005 15:40:57
0.005 15:41:00
Date: 02/01/2006
Sample ID: 203-22+24
Repl SampleConc
# mg/L
1 2.115
2 2.106
3 2.129
Mean: 2.117
SD : 0.0117
%RSD: 0.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0036
2 -0.0056
3 -0.0159
Mean: -0.0059
SD : 0.0097
%RSD: 163.7
Element; Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0126
2 -0.0301
3 -0.0730
Mean: -0.0386
SD : 0.0311
%RSD: 80.55
StndConc
mg/L
2.115
2.106
2.129
2.117
0.0117
0.55
. No. : 193
StndConc
mg/L
0.0036
-0.0056
-0.0159
-0.0059
0.0097
163.7
. No. : 194
StndConc
mg/L
-0.0126
-0.0301
-0.0730
-0.0386
0.0311
80.55
BlnkCorr
Signal
0.079
0.078
0.079
0.079
0.000
0.55
AS
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
163.72
AS
BlnkCorr
Signal
0.000
-0.001
-0.003
-0.001
0.001
80.55
Peak
Area
0.176
0.175
0.176
Loc. :
Peak
Area
0.097
0.097
0.097
Loc. :
Peak
Area
0.097
0.096
0.095
Bkgnd Time
Area
0.006 15:41:24
0.006 15:41:27
0.006 15:41:29
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:41:49
0.005 15:41:51
0.005 15:41:53
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:42:24
0.005 15:42:26
0.007 15:42:28
Page 52
-------
Element
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
.: Ni Seq
ID: ccv-2
SampleConc
mg/L
1.999
2.017
2.015
2.010
0.0101
0.50
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
If
1
ID: ccb
SampleConc
mg/L
-0.0575
-0.0445
-0.0090
-0.0370
0.0251
67.82
: Ni Seq
ID: Sample
SampleConc
mg/L
-0.0259
. No. : 195
StndConc
mg/L
1.999
2.017
2.015
2.010
0.0101
0.50
. No. : 196
StndConc
mg/L
-0.0575
-0.0445
-0.0090
-0.0370
0.0251
67.82
. No. : 197
StndConc
mg/L
-0.0259
AS
BlnkCorr
Signal
0.074
0.075
0.075
0.075
0.000
0.50
AS
BlnkCorr
Signal
-0.002
-0.002
0.000
-0.001
0.001
67.82
AS
BlnkCorr
Signal
-0.001
LOG. :
Peak
Area
0.171
0.172
0.172
Loc. :
Peak
Area
0.095
0.096
0.097
Loc. :
Peak
Area
0.096
Date;
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.006
0.006
0.005
Date:
Bkgnd
Area
0.005
02/01/2
Time
15:42
15:42
15:42
006
:46
:49
:51
02/01/2006
Time
15:43
15:43
15:43
:09
:11
:13
02/01/2006
Time
15:43
:43
Auto-zero performed.
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0013
0.0000
-0.0126
-0.0046
0.0069
150.2
: Ni Seq
. No.: 198
StndConc
mg/L
-0.0013
0.0000
-0.0126
-0.0046
0.0069
150.2
. No. : 199
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
150.21
AS
Loc. :
Peak
Area
0.096
0.096
0.096
Loc. :
Date:
Bkgnd
Area
0.005
0.005
0.006
Date:
02/01/2006
Time
15:43
15:43
15:43
:53
:56
:58
02/01/2006
ID: 203-25+27
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
1.486
1.476
1.441
1.467
0.0239
1.63
StndConc
mg/L
1.486
1.476
1.441
1.467
0.0239
1.63
BlnkCorr
Signal
0.055
0.055
0.053
0.054
0.001
1.63
Peak
Area
0.151
0.151
0.150
Bkgnd
Area
0.005
0.005
0.007
Time
15:44
15:44
15:44
:19
:21
:23
Page 53
-------
Clement: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0279
2 -0.0268
3 -0.0243
Mean: -0.0264
SD : 0.0018
%RSD: 7.01
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0218
2 -0.0207
3 -0.0378
Mean: -0.0268
SD : 0.0096
%RSD: 35.79
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 -0.0562
. No. : 200
StndConc
mg/L
-0.0279
-0.0268
-0.0243
-0.0264
0.0018
7.01
. No.: 201
StndConc
mg/L
-0.0218
-0.0207
-0.0378
-0.0268
0.0096
35.79
. No. : 202
StndConc
mg/L
-0.0562
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
7.01
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
35.79
AS
BlnkCorr
Signal
-0.002
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.094
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.007
02/01/2006
Time
15:45:01
15:45:03
15:45:05
02/01/2006
Time
15:45:20
15:45:22
15:45:24
02/01/2006
Time
15:45:37
Auto-zero performed.
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0279
2 0.0077
3 0.0189
Mean: 0.0182
SD : 0.0101
%RSD: 55.55
Element : Ni Seq
. No.: 203
StndConc
mg/L
0.0279
0.0077
0.0189
0.0182
0.0101
55.55
. No. : 204
AS
BlnkCorr
Signal
0.001
0.000
0.001
0.001
0.000
55.55
AS
Loc. :
Peak
Area
0.095
0.094
0.095
Loc. :
Date:
Bkgnd
Area
0.006
0.007
0.006
Date:
02/01/2006
Time
15:45:49
15:45:51
15:45:53
02/01/2006
JSample ID: 203-28+30
Repl SampleConc
# mg/L
1 2.298
2 2.303
3 2.285
Mean: 2.295
SD : 0.0091
%RSD: 0.40
StndConc
mg/L
2.29.8
2.303
2.285
2.295
0.0091
0.40
BlnkCorr
Signal
0.085
0.085
0.085
0.085
0.000
0.40
Peak
Area
0.179
0.180
0.179
Bkgnd
Area
0.005
0.006
0.006
Time
15:46:17
15:46:19
15:46:21
Page 54
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0,0596
2 0.0236
3 0.0231
Mean: 0.0354
SD : 0.0210
%RSD: 59.16
Element: Ni Seq
. No.: 205
StndConc
mg/L
0.0596
0.0236
0.0231
0.0354
0.0210
59.16
. No.: 206
AS
BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.001
59.16
AS
LOG.:
Peak
Area
0.096
0.095
0.095
Loc. :
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:46:47
0.007 15:46:49
0.006 15:46:51
Date: 02/01/2006
Sample ID: 203-31+33
Repl SampleConc
# mg/L
1 0.2052
2 0.2222
3 0.2281
Mean: 0.2185
SD : 0.0119
%RSD: 5.43
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0241
2 0.0497
3 0.0306
Mean: 0.0348
SD : 0.0133
%RSD: 38.18
Element : Ni Seq
StndConc
mg/L
0.2052
0.2222
0.2281
0.2185
0.0119
5.43
. No.: 207
StndConc
mg/L
0.0241
0.0497
0.0306
0.0348
0.0133
38.18
. No.: 208
BlnkCorr
Signal
0.008
0.008
0.008
0.008
0.000
5.43
AS
BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
38.18
AS
Peak
Area
0.102
0.102
0.103
Loc. :
Peak
Area
0.095
0.096
0.095
Loc. :
Bkgnd Time
Area
0.006 15:47:29
0.005 15:47:31
0.006 15:47:34
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:47:59
0.006 15:48:01
0.006 15:48:03
Date: 02/01/2006
Sample ID: 203 i Irb
Repl SampleConc
# mg/L
1 0.1036
2 0.1022
3 0.1308
Mean: 0.1122
SD : 0.0161
%RSD: 14.39
StndConc
mg/L
0.1036
0.1022
0.1308
0.1122
0.0161
14.39
BlnkCorr
Signal
0.004
0.004
0.005
0.004
0.001
14.39
Peak
Area
0.098
0.098
0.099
Bkgnd Time
Area
0.007 15:48:24
0.006 15:48:26
0.006 15:48:28
Page 55
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.3672
2 0.0299
3 0.0431
Mean: -0.0981
SD : 0.2332
%RSD: 237.7
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 0.0220
. No. : 209 AS iaoc. :
StndConc BlnkCorr Peak
mg/L Signal Area
-0.3672 -0.014 0.081
0.0299 0.001 0.095
0.0431 0.002 0.096
-0.0981 -0.004
0.2332 0.009
237.7 237.73
. No.: 210 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.0220 0.001 0.095
Date: 02/01/2006
Bkgnd Time
Area
0.021 15:48:42
0.006 15:48:44
0.005 15:48:46
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:48:52
Auto- zero performed.
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0315
2 -0.3883
3 0.0005
Mean: -0.1187
SD : 0.2339
%RSD: 197.0
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0186
2 -0.0452
3 0.0290
Mean: 0.0008
SD : 0.0402
%RSD: 5147
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 0.1254
2 0.1479
3 0.1250
Mean: 0.1328
SD : 0.0131
%RSD: 9.87
. No.: 211 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.0315 0.001 0.096
-0.3883 -0.014 0.081
0.0005 0.000 0.095
-0.1187 -0.004
0.2339 0.009
197.0 197.03
. No.: 212 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.0186 0.001 0.096
-0.0452 -0.002 0.093
0.0290 0.001 0.096
0.0008 0.000
0.0402 0.001
5147 5146.59
. No.: 213 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.1254 0.005 0.100
0.1479 0.005 0.100
0.1250 0.005 0.100
0.1328 0.005
0.0131 0.000
9.87 9.87
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:49:01
0.020 15:49:03
0.006 15:49:05
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:49:13
0.008 15:49:15
0.005 15:49:17
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:49:31
0.005 15:49:33
0.005 15:49:35
Page 56
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0177
2 0.0234
3 0.0252
Mean: 0.0221
SD : 0.0040
%RSD: 17.89
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.102
2 1.092
3 1.059
Mean: 1.084
SD : 0.0223
%RSD: 2.05
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.6658
2 -0.8584
3 -1.004
Mean: -0.8428
SD : 0.1698
%RSD: 20.15
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0029
2 0.0034
3 0.0227
Mean: 0.0097
SD : 0.0113
%RSD: 116.8
, No. : 214
StndConc
mg/L
0.0177
0.0234
0.0252
0.0221
0.0040
17.89
. No. : 215
StndConc
mg/L
1.102
1.092
1.059
1.084
0.0223
2.05
. No. : 216
StndConc
mg/L
-0.6658
-0.8584
-1.004
-0.8428
0.1698
20.15
. No. : 217
StndConc
mg/L
0.0029
0.0034
0.0227
0.0097
0.0113
116.8
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.89
AS
BlnkCorr
Signal
0.041
0.041
0.039
0.040
0.001
2.05
AS
BlnkCorr
Signal
-0.025
-0.032
-0.037
-0.031
0.006
20.15
AS
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
116.76
LOG. :
Peak
Area
0.096
0.096
0.096
Loc. :
Peak
Area
0.136
0.136
0.134
Loc. :
Peak
Area
0.070
0.063
0.058
Loc. :
Peak
Area
0.095
0.095
0.096
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:49:56
0.005 15:49:59
0.005 15:50:01
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:50:15
0.005 15:50:17
0.007 15:50:19
Date: 02/01/2006
Bkgnd Time
Area
0.031 15:50:35
0.038 15:50:38
0.044 15:50:40
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:50:47
0.006 15:50:49
0.006 15:50:51
Page 57
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0220
2 0.0135
3 0.0360
Mean: 0.0238
SD : 0.0114
%RSD: 47.71
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.5416
2 0.5722
3 -0.3573
Mean: 0.2522
SD : 0.5280
%RSD: 209.4
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0050
2 0.0182
3 0.0317
Mean: 0.0183
SD : 0.0133
%RSD: 72.79
Element: Ni Seq
Sample ID: *203-2
Repl SampleConc
# mg/L
1 0.1458
2 0.1602
3 0.1526
Mean: 0.1528
SD : 0.0072
%RSD: 4.72
. No. : 218
StndConc
mg/L
0.0220
0.0135
0.0360
0.0238
0.0114
47.71
. No. : 219
StndConc
mg/L
0.5416
0.5722*
-0.3573"
0.25-22
0.5280
209.4
. No. : 220
StndConc
mg/L
0.0050
0.0182
0.0317
0.0183
0.0133
72.79
. No. : 221
StndConc
mg/L
0.1458
0.1602
0.1526
0.1528
0.0072
4.72
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.096
0.001 0.095
0.001 0.096
0.001
0.000
47.71
AS Loc. :
BlnkCorr Peak
Signal Area
0.020 0.115
0.021 0.116
-0.013-, 0.082
0.009 ^
0.020 -~
209.39
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.095
0.001 0.096
0.001 0.096
0.001
0.000
72.79
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.100
0.006 0.101
0.006 0.101
0.006
0.000
4.72
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:50:59
0.006 15:51:01
0.005 15:51:04
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:51:37
0.005 15:51:40
0.039 15:51:42
/I .. >•* a_ f-~ ff AJus—^if
/j-£jJ£ f xj g t-^-f & * -3 *^**-y*"
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:51:57
0.005 15:51:59
0.005 15:52:02
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:52:18
0.005 15:52:20
0.005 15:52:22
Page 58
-------
Element: Mi Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0247
2 0.0568
3 0.0514
Mean: 0.0443
SD : 0.0172
%RSD: 38.79
Element: Ni. Seq.
Sample ID: s203-2
Repl SampleConc
# mg/L
1 1.098
2 1.119
3 1.105
Mean: 1.107
SD : 0.0107
%RSD: 0.97
Element: Mi Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0359
2 0.0420
3 0.0279
Mean: 0.0353
SD : 0.0070
%RSD: 19.99
Element: Mi Seq.
Sample ID: sd.203-2
Repl SampleConc
# mg/L
1 1.115
2 1.102
3 1.065
Mean: 1.094
SD : 0.0258
%RSD: 2.36
No. '. 222
StndConc
mg/L
0.0247
0.0568
0.0514
0.0443
0.0172
38.79
No.: 223
StndConc
mg/L
1.098
1.119
1.105
1.107
0.0107
0.97
No.: 224
StndConc
mg/L
0.0359
0.0420
0.0279
0.0353
0.0070
19.99
No. : 225
StndConc
mg/L
1.115
1.102
1.065
1.094
0.0258
2.36
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.002 0.097
0.002
0.001
38.79
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.136
0.042 0.137
0.041 0.136
0.041
0.000
0.97
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.001 0.096
0.001
0.000
19.99
AS Loc. :
BlnkCorr Peak
Signal Area
0.041 0.136
0.041 0.136
0.040 0.135
0.041
0.001
2.36
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:52:38
0.004 15:52:40
0.004 15:52:42
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:53:01
0.005 15:53:04
0.005 15:53:06
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:53:24
0.005 15:53:26
0.005 15:53:28
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:53:55
0.006 15:53:57
0.007 15:53:59
Page 59
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0133
2 0.0043
3 -0.0036
Mean: -0.0042
SD : 0.0088
%RSD: 210.4
Element: Ni ^-SetfJ
No. : 226
StndConc
rng/L
-0.0133
0.0043
-0.0036
-0.0042
0.0088
210.4
AS Lo
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
210.36
c. :
Peak
Area
0.095
0.095
0.095
.".--N"O~7~2- - ~22 /"*•-. AS Loc. :
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:54:22
0.006 15:54:24
0.006 15:54:27
Date: 02/01/2006
Sample ID: ,s'er2,03-2 ' -, / ^
Repl S,ampleConc
# pg/L
1 / 0.2895
2 i 0.2758
3 i 0.2780
Mean: \ 0.2811
SD : \ 0. 0074
%RSD: \ 2.62
Element: Ni Se-q-
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0575
2 0.0301
3 0.0094
Mean: 0.0323
SD : 0.0241
%RSD: 74.68
Element : Ni Seq
Sample ID: 203-5
Repl SampleConc
# mg/L
1 0.1223
2 0.1510
3 0.1268
Mean: 0.1334
SD : 0.0154
StndConc
mg/L
0.2895
0.2758
0.2780
0.2811
0.0074
2.62
--*fo-rr"228
StndConc
mg/L
0.0575
0.0301
0.0094
0.0323
0.0241
74.68
.No.: 229
StndConc
mg/L
0.1223
0.1510
0.1268
0.1334
0.0154
BlnkCoxr
Signal,
0.011\
O.OlOj
0.010/
0.01)3
0 . Q-ti 0
2". 62
Pea*
Area
0.106
-------
Elements Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0382
2 0.0022
3 0.0115
Mean: 0.0173
SD : 0.0187
%RSD: 108.1
Element: Ni Seq.
Sample ID: 203-8
Repl SampleConc
# mg/L
1 0.1243
2 0.1459
3 0.1148
Mean: 0.1283
SD : 0.0160
%RSD: 12.44
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0346
2 0.0227
3 0.0470
Mean: 0.0348
SD : 0.0122
%RSD: 34.98
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0202
2 0.0180
3 0.0193
Mean: 0.0192
SD : 0.0011
%RSD: 5.67
No. : 230
StndConc
mg/L
0.0382
0.0022
0.0115
0.0173
0.0187
108.1
No.: 231
StndConc
mg/L
0.1243
0.1459
0.1148
0.1283
0.0160
12.44
No.: 232
StndConc
mg/L
0.0346
0.0227
0.0470
0.0348
0.0122
34.98
No.: 233
StndConc
mg/L
0.0202
0.0180
0.0193
0.0192
0.0011
. 5.67
AS :
BlnkCorr
Signal
0.001
0.000
0.000
0.001
0.001
108.09
AS
BlnkCorr
Signal
0.005
0.005
0.004
0.005
0.001
12.44
AS
BlnkCorr
Signal
0.001
0.001
0.002
0.001
0.000
34.98
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
5.67
Loc. :
Peak
Area
0.096
0.095
0.095
Loc. :
Peak
Area
0.100
0.100
0.099
Loc. :
Peak
Area
0.096
0.096
0.097
Loc. :
Peak
Area
0.096
0.096
0.096
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:56:24
0.006 15:56:26
0.006 15:56:28
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:56:49
0.005 15:56:51
0.006 15:56:53
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:57:07
0.006 15:57:10
0.005 15:57:12
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:57:51
0.005 15:57:53
0.005 15:57:56
Page 61
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 234
AS Loc. :
Date: 02/01/2006
ID: ccv-0.25
SampleConc
mg/L
0.2703
0.2840
0.2892
0.2811
0.0098
3.48
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0416
0.0479
0.0267
0.0387
0.0109
28.19
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 203-11
SampleConc
mg/L
0.1218
0.1103
0.1227
0.1183
0.0069
5.86
Element : Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0076
0.0268
0.0295
0.0213
0.0120
56.22
StndConc
mg/L
0.2703
0.2840
0.2892
0.2811
0.0098
3.48
. No. : 235
StndConc
mg/L
0.0416
0.0479
0.0267
0.0387
0.0109
28.19
. No.: 236
StndConc
mg/L
0.1218
0.1103
0.1227
0.1183
0.0069
5.86
. No. : 237
StndConc
mg/L
0.0076
0.0268
0.0295
0.0213
0.0120
56.22
BlnkCorr
Signal
0.010
0.011
0.011
0.010
0.000
3.48
Peak
Area
0.105
0.106
0.106
AS Loc. :
BlnkCorr
Signal
0.002
0.002
0.001
0.001
0.000
28.19
AS
BlnkCorr
Signal
0.005
0.004
0.005
0.004
0.000
5.86
AS
BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
56.22
Peak
Area
0.097
0.097
0.096
Loc. :
Peak
Area
0.100
0.099
0.100
Loc. :
Peak
Area
0.095
0.096
0.096
Bkgnd
Area
0.005
0.004
0.004
Date:
Bkgnd
Area
0.005
0.004
0.005
Date:
Bkgnd
Area
0.004
0.005
0.004
Date:
Bkgnd
Area
Time
15:59:
15:59:
15:59:
07
10
12
02/01/2006
Time
15:59:
15:59:
15:59:
28
30
32
02/01/2006
Time
15:59:
15:59:
15:59:
52
54
57
02/01/2006
Time
0.006 16:00:
0.005
0.005
16:00:
16:00:
10
12
14
Page 62
-------
Clement
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: 203-14
SampleConc
mg/L
0.1391
0.1090
0.1175
0.1219
0.0155
12.73
Element: Hi Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0159
0.0099
-0.0054
0.0068
0.0110
161.6
Element : Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: 203-17
SampleConc
mg/L
0.0939
0.0755
0.0508
0.0734
0.0216
29.44
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0175
-0.0079
0.0247
-0.0002
0.0221
9202
. No. : 238
StndConc
mg/L
0.1391
0.1090
0.1175
0.1219
0.0155
12.73
. No. : 239
StndConc
mg/L
0.0159
0.0099
-0.0054
0.0068
0.0110
161.6
. No.: 240
StndConc
mg/L
0.0939
0.0755
0.0508
0.0734
0.0216
29.44
. No. : 241
StndConc
mg/L
-0.0175
-0.0079
0.0247
-0.0002
0.0221
9202
AS
BlnkCorr
Signal
0.005
0.004
0.004
0.005
0.001
12.73
AS
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
161.63
AS
BlnkCorr
Signal
0.003
0.003
0.002
0.003
0.001
29.44
AS
BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
9202.21
LOG. :
Peak
Area
0.100
0.099
0.099
Loc. :
Peak
Area
0.096
0.095
0.095
Loc. :
Peak
Area
0.098
0.098
0.097
Loc. :
Peak
Area
0.094
0.095
0.096
Bate:
Bkgnd
Area
0.004
0.005
0.005
Date:
Bkgnd
Area
0.006
0.006
0.006
Date:
Bkgnd
Area
0.005
0.006
0.007
Date:
Bkgnd
Area
0.007
0.006
0.005
02/01/20
Time
16:00:
16:00:
16:00:
06
27
29
31
02/01/2006
Time
16:00:
16:00:
16:00:
53
55
57
02/01/2006
Time
16:01:
16:01:
16:01:
19
21
23
02/01/2006
Time
16:01:
16:01:
16:01:
40
42
44
Page 63
-------
Element: Ni Seq
Sample ID: 203-20
Repl SampleConc
# mg/L
1 0.0850
2 0.0746
3 0.0477
Mean: 0.0691
SD : 0.0192
%RSD: 27.83
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0121
2 -0.0232
3 0.0225
Mean: -0.0043
SD : 0.0239
%RSD: 559.6
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0092
2 0.0077
3 0.0142
Mean: 0.0043
SD : 0.0121
%RSD: 283.6
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.4584
2 0.5065
3 0.5040
Mean: 0.4896
SD : 0.0271
%RSD: 5.53
. No.: 242
StndConc
mg/L
0.0850
0.0746
0.0477
0.0691
0.0192
27.83
. No.: 243
StndConc
mg/L
-0.0121
-0.0232
0.0225
-0.0043
0.0239
559.6
. No. : 244
StndConc
mg/L
-0.0092
0.0077
0.0142
0.0043
0.0121
283.6
. No. : 245
StndConc
mg/L
0.4584
0.5065
0.5040
0.4896
0.0271
5.53
AS
BlnkCorr
Signal
0.003
0.003
0.002
0.003
0.001
27.83
AS
BlnkCorr
Signal
0.000
-0.001
0.001
0.000
0.001
559.56
AS
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
283.61
AS
BlnkCon
Signal
0.017
0.019
0.019
0.018
0.001
5.53
j_iOC « I
Peak
Area
0.098
0.098
0.097
Loc. :
Peak
Area
0.095
0.094
0.096
Loc. :
: Peak
Area
0.095
0.095
0.096
Loc. :
: Peak
Area
0.112
0.114
0.114
Date: 02/01/2006
Bkgnd Time
Area
0.006 16:01:59
0.006 16:02:01
0.007 16:02:03
Date: 02/01/2006
Bkgnd Time
Area
0.006 16:02:31
0.007 16:02:33
0.005 16:02:35
Date: 02/01/2006
Bkgnd Time
Area
0.006 16:02:45
0.005 16:02:47
0.005 16:02:49
Date: 02/01/2006
Bkgnd Time
Area
0.007 16:03:21
0.006 16:03:23
0.006 16:03:26
Page 64
-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0166
-0.0092
-0.0191
-0.0150
0.0052
34.44
:: Ni Seq
ID: 203-23
SampleConc
mg/L
0.0658
0.0690
0.0717
0.0688
0.0030
4.33
:: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0014
-0.0079
0.0049
-0.0015
0.0064
426.0
;: Ni Seq
ID: 203-26
SampleConc
mg/L
0.1004
0.0901
0.0894
0.0933
0.0061
6.59
. No . : 246
StndConc
mg/L
-0.0166
-0.0092
-0.0191
-0.0150
0.0052
34.44
. No.: 247
StndConc
mg/L
0.0658
0.0690
0.0717
0.0688
0.0030
4.33
. No.: 248
StndConc
mg/L
-0.0014
-0.0079
0.0049
-0.0015
0.0064
426.0
. No.: 249
StndConc
mg/L
0.1004
0.0901
0.0894
0.0933
0.0061
6.59
AS
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
34.44
AS
BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
4.33
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
426.01
AS
BlnkCorr
Signal
0.004
0.003
0.003
0.003
0.000
6.59
LOG. :
Peak
Area
0.094
0.095
0.094
Loc. :
Peak
Area
0.097
0.098
0.098
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.099
0.098
0.098
Dste i !
Bkgnd
Area
0.006
0.005
0.006
Date:
Bkgnd
Area
0.006
0.005
0.005
Date:
Bkgnd
Area
0.005
0.005
0.005
Date:
Bkgnd
Area
0.005
0.006
0.005
32/01/2006
Time
16:03:44
16:03:47
16:03:49
02/01/2006
Time
16:04:06
16:04:08
16:04:10
02/01/2006
Time
16:04:23
16:04:25
16:04:27
02/01/2006
Time
16:04:46
16:04:48
16:04:50
Page 65
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0043
2 0.0002
3 0.0014
Mean: -0.0009
SD : 0.0030
%RSD: 336.5
Element : Ni Seq
Sample ID: 203-29
Repl SampleConc
# mg/L
1 0.0755
2 0.0899
3 0.0829
Mean: 0.0828
SD : 0.0072
%RSD: 8.71
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0023
2 0.0090
3 0.0065
Mean: 0.0044
SD : 0.0060
%RSD: 135.9
Element: Ni Seq
Sample ID: 203-32
Repl SampleConc
# mg/L
1 0.0598
2 0.0787
3 0.0735
Mean: 0.0707
SD : 0.0098
%RSD: 13.82
. No. : 250
StndConc
mg/L
-0.0043
0.0002
0.0014
-0.0009
0.0030
336.5
. No. : 251
StndConc
mg/L
0.0755
0.0899
0.0829
0.0828
0.0072
8.71
. No. : 252
StndConc
mg/L
-0.0023
0.0090
0.0065
0.0044
0.0060
135.9
. No. : 253
StndConc
mg/L
0.0598
0.0787
0.0735
0.0707
0.0098
13.82
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
336.45
AS
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
8.71
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
135.95
AS
BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
13.82
LOG. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.098
0.098
0.098
Loc. :
Peak
Area
0.095
0.095
0.095
Loc. :
Peak
Area
0.097
0.098
0.098
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:05:06
0.005 16:05:08
0.005 16:05:10
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:05:26
0.005 16:05:28
0.005 16:05:30
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:05:45
0.005 16:05:47
0.005 16:05:49
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:06:03
0.005 16:06:05
0.005 16:06:07
Page 66
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0124
2 -0.0007
3 -0.0204
Mean: -0.0112
SD : 0.0099
%RSD: 88.45
Element: Ni Seq
Sample ID: 203-26
Repl SampleConc
# mg/L
1 0.1023
2 0.1104
3 0.0885
Mean: 0.1004
SD : 0.0111
%RSD: 11.07
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0050
2 0.0166
3 0.0182
Mean: 0.0099
SD : 0.0130
%RSD: 130.9
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0061
.2 0.0117
3 0.0038
Mean: 0.0031
SD : 0.0089
%RSD: 286.2
. No. : 254
StndConc
mg/L
-0.0124
-0.0007
-0.0204
-0.0112
0.0099
88.45
. No. : 255
dup
StndConc
mg/L
0.1023
0.1104
0.0885
0.1004
0.0111
11.07
. No.: 256
StndConc
mg/L
-0.0050
0.0166
0.0182
0.0099
0.0130
130.9
. No.: 257
StndConc
mg/L
-0.0061
0.0117
0.0038
0.0031
0.0089
286.2
AS
BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
88.45
AS
BlnkCorr
Signal
0.004
0.004
0.003
0.004
0.000
11.07
AS
BlnkCorr
Signal
0.000
0.001
0.001
0.000
0.000
130.95
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
286.16
.hoc. :
Peak
Area
0.095
0.095
0.094
Loc. :
Peak
Area
0.099
0.099
0.098
Loc. :
Peak
Area
0.095
0.096
0.096
Loc. :
Peak
Area
0.095
0.095
0.095
Date; 02/01/2006
Bfcgnd Time
Area
0.005 16:06:40
0.005 16:06:42
0,006 16:06:44
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:07:02
0.005 16:07:04
0.005 16:07:07
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:07:21
0.005 16:07:23
0.005 16:07:25
Date: 02/01/2006
Bkgnd Time
Area
0.005 16:07:53
0.005 16:07:55
0.005 16:07:57
Page 67
-------
Prep M©thod', (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-848 3010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-8463005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER
1
2
3
4
5
6
7
8
9
10
11
12
Set
Init'I
I y
Set
date
Ml
Set
time
ui£-
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QC-21
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OTHER
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CJP\
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Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
CT,
Method:
(check only one per page) -
ICP/FLM: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA20Q's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
iCP/FLAA: SW-8463005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: .
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: -EPA 200.9
iFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER: :
MATRIX: {check only one per page)
DRINKING WATER
AQUEOUS
OTHER:
Set
Inifl
Set
date-
.Lab #
Smp
Company
Aliquot
(mis)
Final
(mis)
Mcr
LFB
100
13
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31
2
10.
7
4
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10
11
12
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JG STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
CVM
LOT*
& 5VtoL>a.
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Set*
ethod:
(check oniy one per page) -
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
iCP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: 'EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER
AQUEOUS
OTHER:
Set
Inifl
Company
Aiiquot
(mis)
Final
ftnb)
Mcr
Vsl#
LFB
LRB
13
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^
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-------
Prep MetflOCS: (check oniy one per page) -
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
SCP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: -EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER: :
MATRIX: (check only one per page)
DRINKING WATER
1
2
B
4
5
6
7
8
9
10
11
12
Set
Inrt'I
U(
"'*#
/
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date
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(mis)
Final
(mis)
-------
PROJECT # 2005100307:
1 2 345
METHOD 29 FOR NICKEL
6789 10
11
12
SA#
3
2
1
6
5
4
9
8
7
12
11
10
15
14
13
18
17
16
21
20
19
24
23
22
27
26
25
30
29
28
33
32
31
SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger ,^
filter - -
probe rinse
RUN ID
Cond. 27:
BLANK
Cond. 27: Test
#1
Cond. 27: Test
#2
Cond. 27: Test
#3
Cond. 22:
BLANK
Cond. 22: Test
#1
Cond. 22: Test
#2
Cond. 22: Test
#3
Cond. 28: Test
#1
Cond. 28: Test
#2
Cond. 28: Test
#3
MDL
PH
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Sample
Fraction
(SF = SFA)
302
1 filter
99.0
305
1 filter
99.5
312
1 filter
95.0
319
1 filter
97.5
302
1 filter
99.5
300
1 filter
96.5
303
1 filter
97.0
306
1 filter
99.0
309
1 filter
96.5
302
1 filter
98.5
307
1 filter
97.0
300 y-
1 "filter
100,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
- ';ty
NA
20'
REAGENTS
FOR DIG.
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF+HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNQ3fB2£>2
•HF + Mto3>;
,^^NO3
MICRO-
Dig. BY
8.3.4.2
8-3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1 .2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1 .2
*s3C43'li
8.3,12,',
'8'J3&2 ''
Analytical
Fraction
(AF = AFA)
50
100
50
100
50
100
50
100
50
100
•50
100
50
100
50
100
50
100
50
100
50
100
, 50 ^.
''< 100 ?
Nl mg/L
( Ca1 or Ca2 )
< 0.074
0.100
0.192
16.772
0.123
7.629
0.084
14.025
< 0.074
0.100
0.149
0.717
0.120
0.418
0.098
0.375
0.157
3.529
0.111
4.538
< 0.074
7.053
0.0-75^ "x
x 0.07SP*
?/^
MG Nl
IN INITIAL
SAMPLE
0.004
0.010
0.010
1.677
0.006
0.763
0.004
1.403
0.004
0.010
0.007
0.072
0.006
0.042
0.005
0.038
0.008
0.353
0.006
0.454
0.004
0.705
sx 0,004 '
,; 0.008,^
TOTAL MG
PER RUN
0.014
1.687
0.769
1.407
0.014
0.079
0.048
0.042
0.361
0.459
0.709
' X \ \V
> 0,011
10 Samples that read
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
'5100AA
1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
2 INSTRUMENT SET-UP:
Date:
1/6/2006
Analyst: LK
(For Specific instrument settings, see current copy of method.)
3 CALIBRATION:
(Mg/L)
IDL= 0.027
MDL= 0.075
RL = 0.10
LDR ~ 0.10 to 8.0
4 STANDARD TRACEABILITY
Cal Curve:
Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.275
0.543
1.066
2.096
4.939
0.9993
% Rec.
110.0
108.6
106.6
104.8
98.8
QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM
Standard Name, Company, & Lot #
CPI QC-21 41M044
CPI QC-21 41M044
CPI05F011
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
SAMPLE
CCV
QCS
CCB
CRA
CRA
CRA
LRB
LFB
307-1+2
DUP
SPK
SERDIL
307-4+5
307-4+5
307-7+8
307-7+8
307-10+11
307-10+11
CCB
CCV
CCV
307-13+14
307-16+17
307-19+20
307-22+23
307-25+26
307-28+29
307-31+32
307-31+32
CCB
CCV
LRB
LFB
307-3
DUP
SPK
SERDIL
307-6
307-9
307-12
307-15
CCB
CCV
307-18
307-21
307-24
307-27
307-30
307-33
CCV
CCB
STD CONC
5.00
2.00
0.05
0.10
0.25
1.00
1.00
2/10
10.00
1 00
0.50
1.00
1 00
2/10
0 25
0 50
READING
Mg/L
4.943
2.043
-0.023
0068
0105
0.284
0052
0906
0059
0092
1.155
0262
12290
1.721
6.627
0803
10.710
1.409
-0.026
8.779
1.034
0070
0.682
0386
0.340
3.514
4.572
5.990
0.705
0.005
0.537
-0.003
1.023
0.055
0.065
1.020
0.225
0.224
0.182
0.117
0.091
0.026
0286
0.171
0.134
0.128
0.206
0.164
0.121
0.572
0061
BLK
0.016
-0.003
0.018
0028
-0.011
-0.042
-0.016
0.010
0.026
0.036
0.044
0.036
0.040
-0.027
0.007
-0.018
-0.018
-0.024
-0.030
-0.034
-0.032
-0.034
-0.015
0.034
0.021
-0001
0004
0.005
-0.002
-0.010
-0.009
0.002
0031
0.020
0.032
0.059
0.033
0027
0.028
0.026
0.022
0.014
0030
0050
0.053
0053
0.053
0.056
RESULT
4.943
2.043
-0.023
0.051
0.107
0.266
0.024
0.917
0.100
0.108
1.145
0.236
12.254
1.677
6.591
0.763
10.737
1.403
-0 008
8.797
1.058
0 100
0.717
0.418
0.375
3.529
4.538
5.969
0.705
0.001
0.533
-0.001
1.033
0.064
0.063
0.989
0.206
0.192
0.123
0084
0.065
-0.002
0260
0.149
0.120
0.098
0.157
0.111
0068
0519
0.005
DILI
1.0
1.0
1.0
1.0
1.0
10.0
1.0
10.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
OIL 2
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
QC
RESULTS
99
102
-0.023
103
107
106
0.024
92
7.1
105
3.1
-0.028
88
106
G.QQS
107
-0,001
103
1.9
93
3.9
0.026
104
104
0.081
Mg/L
0.100
12.254
16.772
6.591
7.629
10.737
14.025
(OVER LDR)
0.100
0.717
0.418
0.375
3.529
4.538
5.969
7.053
0.064
0.192
0.123
0.084
0.065
0.149
0.120
0.098
0.157
0.111
0.068
REP'T
mg/L
0.100
16.772
7.629
14.025
0.100
0.717
0.418
0.375
3.529
4.538
7.053
0.074
0.192
0.123
0.084
0.074
0.149
0.120
0.098
0.157
0.111
0.074
ICP
95-105%R)
95-105%R)
< MDL}
70-130%R)
70-130%R)
70-130%R)
< MDL)
80-120%R)
-10RPD, IFSA>20XMDL)
80-120%R)
<10%DIFF)
< MDL }
90-110%R 5
< MDL}
80-120%R)
<10 RPD, IF SA > 20X MDL)
80-120%R)
<1Q%DIFF)
;< MDL}
; 90-1 WAR)
90-110%R)
< MDL )
-------
Element: Ni Seq. No.: 77
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 78
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 79
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 80
Sample ID: CAL STD
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1 applied.
Correlation Coefficient: 0
AS
BlnkCorr
Signal
0.169
0.170
0.170
0.170
o.o.oo
0.03
AS
BlnkCorr
Signal
-0.004
-0.004
-0.004
-0.004
0.000
9.68
AS
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
49.09
AS
BlnkCorr
Signal
0.011
0.012
0.011
0.011
0.001
5.05
[0.25]
.9997
Loc. :
Peak
Area
0.072
0.072
0.072
Loc. :
Peak
Area
0.069
0.069
0.068
Loc. :
Peak
Area
0.067
0.068
0.067
Loc, : - —
Peak
Area
0.078
0.079
0.079
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:20:17
0.003 12:20:19
0.002 12:20:21
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:24:55
0.002 12:24:57
0.003 12:24:59
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:26:19
0.003 12:26:22
0.004 12:26:24
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:27:25
0.002 12:27:27
0.002 12:27:29
Slope: 0.0385
Page 21
-------
Element: Ni Seq. No . : 81
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 82
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
I
2
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 83
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 84
Sample ID: cal std 5
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
AS Loc. :
BlnkCorr Peak
Signal Area
0.022 0.090
0.023 0.091
0.021 0.089
0.022
0.001
3.88
[0.50]
.9995
AS Loc. :
BlnkCorr Peak
Signal Area
0.043 0.111
0.043 0.111
0.044 0.111
0.043
0.000
1.05
[1.00]
.9990
AS Loc. :
BlnkCorr Peak
Signal Area
0.085 0.153
0.086 0.153
0.085 0.153
0.085
0.000
0.54
[2.00]
.9979
AS Loc. :
BlnkCorr Peak
Signal Area
0.200 0.267
0.203 0.270
0.201 0.269
0.201
0.002
0.77
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:27:50
0.001 12:27:52
0.003 12:27:54
Slope: 0.0386
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:28:20
0.002 12:28:22
0.002 12:28:24
Slope: 0.0387
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:28:45
0.001 12:28:47
0.002 12:28:49
Slope: 0.0392
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:29:07
0.001 12:29:09
0.001 12:29:11
The calibration curve may not be linear.
Standard number 5 applied. [5.00]
Correlation Coefficient: 0.9993
Slope: 0.0408
Page 22
-------
Ni
0.3
0.2
0)
u
I
o
w
.0
0.1
Concentration
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5
Mean Signal
(Absorbance)
0.000
0.011
0.022
0.043
0.085
0.201
Correlation Coefficient: 0.99934
Entered
Calculated
Concentration Concentration Standard
fmg/L)
0.25
0.50
1.00
2.00
5.00
Slope:
(mg/L)
0.000
0.2750
0.5432
1.066
2.096
4.939
0.04075
Deviation
0.0005
0.0006
0.0009
0.0005
0.0005
0.0016
%RSD
49.0898
5.0484
3.8830
1.0492
0.5382
0.7728
Element: Ni Seq.
Sample ID: ccv
No.: 85
AS LOG,
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4.958
4.943
4.929
4.943
0.0143
0.29
StndConc
mg/L
4.958
4.943
4.929
4.943
0.0143
0.29
BlnkCorr
Signal
0
0
0
0
0
.202
.201
.201
.201
.001
0.29
Peak
Area
0
0
0
.270
.269
.268
Bkgnd
Time
Area
0.
0.
0.
002
002
001
12:
12:
12:
29
29
29
:22
:25
:27
Page 23
-------
Element: Ni Seq. No,: 86
Sample ID: qcs
AS LOG.
Date: 01/06/2006
Repl
#
I
2
3
Mean:
SD :
%RSD:
TTT fMrtr^i.fc
SampleConc
mg/L
2.075
2.063
1.990
2.043
0.0458
2.24
.* — HT ftp*
StndConc
mg/L
2.075
2.063
1.990
2.043
0.0458
2.24
•Kfrr— - 6^~
BlnkCorr Peak
Signal Area
0.085 0.152
0.084 0.152
0.081 0.149
0.083
0.002
2.24
— . AS Loc. :
Bkgnd
Area
0.003
0.003
0.005
Date:
Time
12:29:49
12:29:51
12:29:54
01/06/2006
Sample \CD: ccb
StndConc
mg/L
-0.1128
-0.123
-0.1301
-0.1222
BlnkCorr
Signal
-0.005
-0.005
-0.005
-0.005
0.000
7.20
Peak
Area
0.063
0.062
0.062
Bkgnd
Area
0.005
0.005
0.006
Time
12:30:22
12:30:24
12:30:26
Element: Ni S^q./No.: 88
Sample ID: ccb \ -
AS Loc.:
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc/'
mg/L
-0.
-0.
-0.
-0.
0.
2
f~
\ StndConc
/ W/L
04 97 /
0711
078/4
06£4
0/49
2f.46
\o
-0
-0
0
.0497
.0711
\0784
.0664
.Ck49
22.^6
BlnkCorr
Signal
-0.002
-0.003
-0.003
-0.003
0.001
22.46
Peak
Area
0.
0.
0.
066
065
064
Bkgnd
Time
Area
0.
0.
0.
002
003
004
12:31:
12:31:
12:31:
11
13
16
Element: 1/i Seq. No.: 89\ AS Loc.:
Sample ID/: Sample
Date: 01/06/2006
Repl SampleConc StndConc BJmkCorr Peak
# ^g/L mg/L Signal Area
---^.0X003 0.065
Bkgnd Time
Area
0.003 12:31:42
Auto-zero performed.
Element: Ni Seq. No.: 90
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0
.0258
.0318
.0102
.0226
.0112
49.46
StndConc
mg/L
-0
-0
-0
-0
0
.0258
.0318
.0102
.0226
.0112
49.46
BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.000
49.46
Peak
Area
0.
0.
0.
064
064
064
Bkgnd
Time
Area
0.
0.
0.
003
004
003
12
12
12
:31:51
:31:53
:31:55
Page 24
-------
Element: Ni Seq. No.: 91
Sample ID: Sample
AS Loc.
Date: 01/06/2006
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.0084 0.0084 0.000 0.065
Auto-zero performed.
Bkgnd Time
Area
0.002 12:31:58
Element: Ni Seq
Sample ID: ccb
No.: 92
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0204
-0.0235
-0.0095
-0.0178
0.0073
41.18
StndConc
mg/L
-0.0204
-0.0235
-0.0095
-0.0178
0.0073
41.18
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.064 0.003 12:32:07
-0.001 0.064 0.003 12:32:09
0.000 0.065 0.003 12:32:12
-0.001
0.000
41.18
Element: Ni Seq. No.: 93
Sample ID: Sample
AS Loc.:
Date: 01/06/2006
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 -0.0338 -0.0338 -0.001 0.064
Auto-zero performed.
Bkgnd Time
Area
0.003 12:32:27
Element: Ni Seq. No
Sample ID: ccb
94
AS Loc.:
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0230
0.0213
0.0043
0.0162
0.0104
63.98
StndConc
mg/L
0.0230
0.0213
0.0043
0.0162
0.0104
63.98
BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
63.98
Peak Bkgnd Time
Area Area
0.065 0.003 12:32:40
0.065 0.003 12:32:42
0.064 0.003 12:32:44
Element: Ni Seq. No.: 95
Sample ID: era 0.05
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
.0745
.0573
.0707
.0675
.0091
13.42
StndConc
mg/L
0
0
0
0
0
.0745
.0573
.0707
.0675
.0091
13.42
BlnkCorr
Signal
0.
0.
0.
0.
0.
13
003
002
003
003
000
.42
Peak
Area
0.
0.
0.
067
066
067
Bkgnd
Area
0.
0.
0.
003
003
002
Time
12:33:14
12:33:16
12:33:18
Page 25
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0007
2 -0.0028
3 -0.0044
Mean: -0.0026
SD : 0.0019
%RSD: 72.08
Element : Ni Seq
Sample ID: era 0.1
Repl SampleConc
# mg/L
1 0.1200
2 0.1026
3 0.0922
Mean: 0.1049
SD : 0.0140
%RSD: 13.36
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0010
2 0.0097
3 0.0184
Mean: 0.0090
SD : 0.0097
%RSD: 107.5
Element: Ni Seq
Sample ID: era 0.2
Repl SampleConc
# mg/L
1 0.2762
2 0.2831
3 0.2925
Mean: 0.2839
SD : 0.0082
%RSD: 2.87
. No. : 96
StndConc
mg/L
-0.0007
-0.0028
-0.0044
-0.0026
0.0019
72.08
. No.: 97
StndConc
mg/L
0.1200
0.1026
0.0922
0.1049
0.0140
13.36
. No. : 98
StndConc
mg/L
-0.0010
0.0097
0.0184
0.0090
0.0097
107.5
. No.: 99
5
StndConc
mg/L
0.2762
0.2831
0.2925
0.2839
0.0082
2.87
AS :
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
72.08
AS
BlnkCorr
Signal
0.005
0.004
0.004
0.004
0.001
13.36
AS
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
107.46
AS
BlnkCorr
Signal
0.011
0.012
0.012
0.012
0.000
2.87
Loc. :
Peak
Area
0.064
0.064
0.064
Loc. :
Peak
Area
0.069
0.068
0.068
Loc. :
Peak
Area
0.064
0.064
0.065
Loc. :
Peak
Area
0.075
0.075
0.076
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:33:36
0.003 12:33:39
0.003 12:33:41
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:34:03
0.004 12:34:05
0.004 12:34:07
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:34:31
0.003 12:34:33
0.003 12:34:35
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:34:49
O.OQ3 12:34:52
Q.0'03 12:34:54
Page 26
-------
Element: Ni Seq
Sample ID: ccb
No.: 100
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0241
0.0207
0.0387
0.0278
0.0096
34.42
StndConc
mg/L
0.0241
0.0207
0.0387
0.0278
0.0096
34.42
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.001 0.065 0.003 12:35:07
0.001 0.065 0.003 12:35:09
0.002 0.065 0.003 12:35:11
0.001
0.000
34.42
Element: Ni Seq. No.: 101
Sample ID: Irb
AS Loc.:
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
,0405
.0678
.0473
.0519
.0142
27.36
StndConc
mg/L
0
0
0
0
0
.0405
.0678
.0473
.0519
.0142
27.36
BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
27.36
Peak
Area
0.
0.
0.
065
067
066
Bkgnd
Time
Area
0.
0.
0.
003
002
003
12
12
12
:35:45
:35:47
:35:50
Element: Ni Seq. No.
Sample ID: ccb
102
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0834
0.0569
0.0684
0.0696
0.0132
19.04
StndConc
mg/L
0.0834
0.0569
0.0684
0.0696
0.0132
19.04
BlnkCorr Peak
Signal Area
0.003 0.067
0.002 0.066
0.003 0.067
0.003
0.001
19.04
Bkgnd Time
Area
0.002 12:36:09
0.003 12:36:11
0.002 12:36:13
Element: Ni Seq. No.: 103
Sample ID: Sample
AS Loc.
Date: 01/06/2006
Repl SampleConc StndConc
# mg/L mg/L
1 0.0673 0.0673
Auto-zero performed.
BlnkCorr Peak
Signal Area
0.003 0.067
Bkgnd Time
Area
0.002 12:36:20
Element: Ni Seq.
Sample ID: ccb
No.: 104
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
-0
-0
-0
0
.0038
.0075
.0299
.0112
.0171
152.6
StndConc
mg/L
0
-0
-0
-0
0
.0038
.0075
.0299
.0112
.0171
152.6
BlnkCorr
Signal
0,000
0.000
-0.001
0.000
0.001
152.65
Peak
Area
0.
0.
0.
067
066
065
Bkgnd
Time
Area
0.
0.
0.
002
002
003
12
12
12
:36:27
:36:30
:36:32
Page 27
-------
Element: Ni Seq.
Sample ID: Ifb
Repl SampleConc
# mg/L
1 0.9120
2 0.9023
3 0.9030
Mean: 0.9058
SD : 0.0054
%RSD: 0.60
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0478
2 -0.0440
3 -0.0328
Mean: -0.0415
SD : 0.0078
%RSD: 18.70
Element : Ni Seq
Sample ID: 307-1-2
Repl SampleConc
# mg/L
1 0.0604
2 0.0573
3 0.0581
Mean: 0.0586
SD : 0.0016
%RSD: 2.76
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0123
2 -0.0179
3 -0.0176
Mean: -0.0159
SD : 0.0031
%RSD: 19.67
No.: 105
StndConc
mg/L
0.9120
0.9023
0.9030
0.9058
0.0054
0.60
. No.: 106
StndConc
mg/L
-0.0478
-0.0440
-0.0328
-0.0415
0.0078
18.70
. No.: 107
StndConc
mg/L
0.0604
0.0573
0.0581
0.0586
0.0016
2.76
. No.; 108
StndConc
mg/L
-0.0123
-0.0179
-0.0176
-0.0159
0.0031
19.67
AS LOG. :
BlnkCorr Peak
Signal Area
0.037 0.104
0.037 0.103
0.037 0.103
0.037
0.000
0.60
AS LOG. :
BlnkCorr Peak
Signal Area
-0.002 0.065
-0.002 0.065
-0.001 0.065
-0.002
0.000
18.70
AS LOG. :
BlnkCorr Peak
Signal Area
0.002 0.069
0.002 0.069
0.002 0.069
0.002
0.000
2.76
AS LOG. :
BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.066
-0.001 0.066
-0.001
0.000
19.67
Date: 01/06/2006
Bkgnd Time
Area
0.002 12:36:45
0.003 12:36:48
0.003 12:36:50
Date: 01/06/2006
Bkgnd Time
Area
0.004 12:37:07
0.004 12:37:09
0.004 12:37:11
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:37:35
6.003 12:37:37
0.003 12:37:39
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:38:00
0.003 12:38:02
0.003 12:38:05
Page 28
-------
Element
Sample
Repl
#
1
2
3
Mean:
3D :
%RSD:
: Ni Seq.
ID: d307-l-2
SampleConc
mg/L
0.0965
0.0908
0.0876
0.0916
0.0045
4.91
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0077
0.0148
0.0072
0.0099
0.0042
42.66
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
No.: 109
StndConc
mg/L
0.0965
0.0908
0.0876
0.0916
0.0045
4.91
No.: 110
StndConc
mg/L
0.0077
0.0148
0.0072
0.0099
0.0042
42.66
No.: Ill
AS Loc. :
BlnkCorr
Signal
0.004
0.004
0.004
0,004
0.000
4.91
Peak
Area
0.070
0.070
0.070
AS Loc. : — -
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
42.66
AS
Peak
Area
0.067
0.067
0.067
Loc. :
Date: 01/06/2006
Bkgnd
Area
0.003
0.003
0.003
Time
12:38
12:38
:40
:42
12:38:44
Date: 01/06/2006
Bkgnd
Area
0.003
0.003
0.003
Date:
Time
12:38
12:39
12:39
:59
:02
-:04
01/06/2006
ID: s307-l-2
SampleConc
mg/L
1.147
1.162
1.154
1.155
0.0076
0.65
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
ing/L
0.0330
0.0233
0.0202
0.0255
0.0067
26.18
StndConc
mg/L
1.147
1.162
1.154
1.155
0.0076
0.65
No.: 112
StndConc
mg/L
0.0330
0.0233
0.0202
0.0255
0.0067
26.18
BlnkCorr
Signal
0.047
0.047
0.047
0.047
0.000
0.65
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
26.18
Peak
Area
0.113
0.114
0.114
Loc. :
Peak
Area
0.068
0.068
0.067
Bkgnd
Area
0.003
0.003
0.003
Date:
Bkgnd
Area
0.002
0.002
0.002
Time
12:39
12:39
12:39
:37
:39
:41
01/06/2006
Time
12:40
12:40
12:40
:33
:36
:38
Page 29
-------
Element: Ni Seq. No.: 113
Sample ID: ser307-l-2
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
n.
n.
0.
0.
0.
2770
2595
2486
2617
0143
5.47
StndConc
ing/L
0
0
0
0
0
.2770
.2595
.2486
.2617
.0143
5.47
BlnkCorr Peak Bkgnd Time
Signal Area Area
0
0
0
0
0
.011 0.078 0.001 12:41:10
.011 0.077 0.002 12:41:12
.010 0.077 0.002 12:41:14
.011
.001
5.47
Element: Ni Seq. No.: 114
Sample ID: ccb
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0336
0.0396
0.0354
0.0362
0.0030
8.36
StndConc
mg/L
0.0336
0.0396
0.0354
0.0362
0.0030
8.36
BlnkCorr Peak
Signal Area
0.001 0.068
0.002 0.068
0.001 0.068
0.001
0.000
8.36
Bkgnd Time
Area
0.002 12:42:02
0.002 12:42:04
0.002 12:42:06
Element: Ni Seq.
Sample ID: 307-4-5
No.: 115
AS Loc.
Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
12.27
absorbance
12.29
absorbance
12.32
absorbance
12.29
0.0270
0.22
absorbance
StndConc
mg/L
12.27
is greater
12.29
is greater
12.32
is greater
12.29
0.0270
0.22
is greater
BlnkCorr
Signal
0.506
than that
0.501
than that
0.502
than that
0.501
0.001
0.22
than that
Peak Bkgnd Time
Area Area
0.566 0.002 12:42:25
of the highest standard.
0.567 0.001 12:42:27
of the highest standard.
0.569 0.001 12:42:29
of the highest standard.
of the highest standard.
Element: Ni Seq. No.: 116
Sample ID: ccb
AS Loc,
Date: 01/06/2006
Repl
ft
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.
0415
0478
0420
0438
0035
7.92
StndConc
mg/L
0.
0.
0.
0.
0.
0415
0478
0420
0438
0035
7.92
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
7.92
Peak
Area
0.
0.
0.
068
068
068
Bkgnd
Time
Area
0.
0.
0.
002
002
002
12:
12:
12:
42:59
43:01
43:04
Page 30
-------
Element: Ni Seq. No.: 117
Sample ID: 307-4-5 xlO
AS LOG.
Date: 01/06/2006
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
1.723
1.733
1.708
1.721
0.0126
0.73
StndConc
mg/L
1.723
1.733
1.708
1.721
0.0126
0.73
BlnkCorr Peak
Signal Area
0.070 0.137
0.071 0.137
0.070 0.136
0.070
0.001
0.73
Bkgnd Time
Area
0.002 12:44:18
0.002 12:44:20
0.003 12:44:23
Element: Ni Seq.
Sample ID: ccb
No.: 118
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0405
0.0336
0.0343
0.0362
0.0038
10.52
StndConc
mg/L
0.0405
0.0336
0.0343
0.0362
0.0038
10.52
BlnkCorr Peak
Signal Area
0.002 0.068
0.001 0.068
0.001 0.068
0.001
0.000
10.52
Bkgnd Time
Area
0.002 12:45:05
0.00-2 12:45:08
0.002 12:45:10
Element: Ni Seq. No.: 119
Sample ID: 307-7-8
AS Loc.
Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.577
absorbance
6.615
absorbance
6.688
absorbance
6.627
0.0561
0.85
absorbance
StndConc
mg/L
is
is
is
is
6.577
greater
6.615
greater
6.688
greater
6.627
0.0561
0.85
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
268
that
270
that
273
that
270
002
.85
that
Peak
Area
0
of
0
of
0
of
of
.335
the
.336
the
.339
the
the
Bkgnd
Area
0.002
highest
Time
12:45:
30
standard.
0.002
highest
12:45:
32
standard.
0.001
highest
highest
12:45:
34
standard.
standard.
Element: Ni Seq. No.: 120
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0
.0304
.0366
.0540
.0403
.0122
30.38
StndConc
mg/L
0
0
0
0
0
.0304
.0366
.0540
.0403
.0122
30.38
BlnkCorr
Signal
0.001
0.001
0.002
0.002
0.000
30.38
Peak
Area
0.
0.
0.
068
068
069
Bkgnd
Time
Area
0.
0.
0.
002
002
001
12:
12:
12:
45:59
46:01
46:03
Page 31
-------
Element: Ni Seq. No.
Sample ID: 307-7-8 xlO
121
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.7891
0
0
0
0
.8236
.7970
.8032
.0181
2.25
StndConc
mg/L
0.7891
0
0
0
0
.8236
.7970
.8032
.0181
2.25
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.032 0.099 0.003 12:47:10
0
0
0
0
.034 0.100 0.002 12:47:12
.032 0.099 0.003 12:47:14
.033
.001
2.25
Element: Ni Seq
Sample ID: ccb
No.: 122
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0712
0.0059
-0.0151
-0.0268
0.0399
148.8
StndConc
mg/L
-0.0712
0.0059
-0.0151
-0.0268
0.0399
148.8
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.003 0.064 0.005 12:47:34
0.000 0.067 0.002 12:47:36
-0.001 0.066 0.003 12:47:38
-0.001
0.002
148.77
Element: Ni Seq. No.: 123
Sample ID: 307-10-11
AS Loc.
Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
10.67
absorbance
10.74
absorbance
10.73
absorbance
10.71
0.0385
0.36
absorbance
StndConc
mg/L
10.67
is greater
10.74
is greater
10.73
is greater
10.71
0.0385
0.36
is greater
BlnkCorr
Signal
0.435
than that
0.438
than that
0.437
than that
0.437
0.002
0.36
than that
Peak Bkgnd Time
Area Area
0.501 0.002 12:48:27
of the highest standard.
0.504 0.002 12:48:29
of the highest standard.
0.504 0,003 12:48:31
of the highest standard.
of the highest standard.
Element: Ni Seq.
Sample ID: ccb
No.: 124
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0038
0.0085
0.0146
0.0065
0.0094
145.1
StndConc
mg/L
-0.0038
0.0085
0.0146
0.0065
0.0094
145.1
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
145.08
Peak
Area
0.066
0.067
0.067
Bkgnd
Area
0.002
0.002
0.002
Time
12:4-9:03
12:49:05
12:49:08
Page 32
-------
Element: Ni Seq. No.: 125
Sample ID: 307-10-11 xlO
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.408
1.393
1.424
1.409
0.0156
1.11
StndConc
mg/L
1.408
1.393
1.424
1.409
0.0156
1.11
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.057 0.124 0.002 12:50:19
0.057 0.123 0.002 12:50:21
0.058 0.125 0.002 12:50:24
0.057
0.001
1.11
Element: Ni Seq. No.: 126
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0218
-0.0213
-0.0346
-0.0259
0.0075
29.07
StndConc
mg/L
-0.0218
-0.0213
-0.0346
-0.0259
0.0075
29.07
BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.066
-0.001 0.065
-0.001
0.000
29.07
Bkgnd Time
Area
0.003 12:50:55
0.003 12:50:57
0.003 12:50:59
Element: Ni Seq. No.: 127
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0200
-0.0028
-0.0310
-0.0179
0.0142
79.30
StndConc
mg/L
-0.0200
-0.0028
-0.0310
-0.0179
0.0142
79.30
BlnkCorr Peak
Signal Area
-0.001 0.066
0.000 0.066
-0.001 0.065
-0.001
0.001
79.30
Bkgnd Time
Area
0.003 12:51:21
0.003 12:51:23
0.003 12:51:25
Element: Ni Seq. No.: 128
Sample ID: ccv
AS Loc.
Date: 01/06/2006
Repl SampleConc
# mg/L
1 8.796
Sample absorbance
2 8.692
Sample, absorbance
3 8.850
Sample absorbance
Mean: 8.779
SD : 0.0802
%RSD: 0.91
Sample absorbance
StndConc BlnkCorr Peak Bkgnd Time
mg/L Signal Area Area
8.796 0.358 0.425 0.004 12:51:41
is greater than that of the highest standard.
8.692 0.354 0.421 0.004 12:51:43
is greater than that of the highest standard.
8.850 0.361 0.427 0.003 12:51:45
is greater than that of the highest standard.
8.779 0.358
0.0802 0.003
0.91 0.91
is greater than that of the highest standard.
Page 33
-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0159
2 -0.0292
3 -0.0256
Mean: -0.0236
SD : 0.0069
%RSD: 29.15
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 1.042
2 1.038
3 1.023
Mean: 1.034
SD : 0.0102
%RSD: 0.99
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0256
2 -0.0340
3 -0.0295
Mean: -0.0297
SD : 0.0042
%RSD: 14.10
Element: Ni Seq.
No.: 129
StndConc
mg/L
-0.0159
-0.0292
-0.0256
-0.0236
0.0069
29.15
No.: 130
StndConc
mg/L
1.042
1.038
1.023
1.034
0.0102
0.99
No.: 131
StndConc
mg/L
-0.0256
-0.0340
-0.0295
-0.0297
0.0042
14.10
No.: 132
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.065
-0.001 0.066
-0.001
0.000
29.15
AS Loc. :
BlnkCorr Peak
Signal Area
0.042 0.109
0.042 0.109
0.042 0.108
0.042
0.000
0.99
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.065
-0.001 0.065
-0.001
0.000
14.10
AS Loc. :
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:52:06
0.003 12:52:09
0.003 12:52:11
Date: 01/06/200€
Bkgnd Time
Area
0.004 12:52:33
0.004 12:52:35
0.004 12:52:37
Date: 01/06/2006
Bkgnd Time
Area
0.004 12:53:03
0.004 12:53:05
0.004 12:53:07
Date: 01/06/2006
Sample ID: 307-13-14
Repl SampleConc
# rng/L
1 0.0630
2 0.0711
3 0.0770
Mean: 0.0704
SD : 0.0070
%RSD: 9.95
StndConc
mg/L
0.0630
0.0711
0,0770
0.0704
0.0070
9.95
BlnkCorr Peak
Signal Area
0.003 0.069
0.003 0.069
0.003 0.070
0.003
0.000
9.95
Bkgnd Time
Area
0.004 12:53:28
0.004 12:53:30
0.003 12:53:32
Page 34
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0428
2 -0.0327
3 -0.0268
Mean: -0.0341
SD : 0.0081
%RSD: 23.87
Element: Ni Seq
. No. : 133
StndConc
mg/L
-0.0428
-0.0327
-0.0268
-0.0341
0.0081
23.87
.No.: 134
AS
BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
23.87
AS
iioc. :
Peak
Area
0.065
0.065
0.065
Loc. :
Date: 01/06/2006
Bkgnd Time
Area
0.004 12:54:57
0.004 12:54:59
0.004 12:55:01
Date: 01/06/2006
Sample ID: 307-16-17
Repl SampleConc
# mg/L
1 0.6813
2 0.68-68
3 0.6790
Mean: 0.6824
SD : 0.0041
%RSD: 0.59
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0295
2 -0.0358
3 -0.0292
Mean: -0.0315
SD : 0.0037
%RSD: 11.74
Element : Ni Seq
StndConc
mg/L
0.6813
0.6868
0.6790
0.6824
0.0041
0.59
.No.: 135
StndConc
mg/L
-0.0295
-0.0358
-0.0292
-0.0315
0.0037
11.74
. No.: 136
BlnkCorr
Signal
0.028
0.028
0.028
0.028
0.000
0.59
AS
BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
11.74
AS
Peak
Area
0.094
0.095
0.094
Loc. :
Peak
Area
0.065
0,065
0.065
Loc. :
Bkgnd Time
Area
0.004 12:55:18
0.004 12:55:20
0.004 12:55:22
Date: 01/06/2006
Bkgnd Time
Area
0.004 12:55:38
0.004 12:55:40
0.003 12:55:42
Date: 01/06/2006
Sample ID: 307-19-20
Repl SampleConc
# mg/L
1 0.3796
2 0.3901
3 0.3895
Mean: 0.3864
SD : 0.0059
%RSD: 1.52
StndConc
mg/L
0.3796
0.3901
0.3895
0.3864
0.0059
1.52
BlnkCorr
Signal
0.015
0.016
0.016
0.016
0.000
1.52
Peak
Area
0.082
0.082
0.082
Bkgnd Time
Area
0.004 12:56:03
0.003 12:56:05
0.003 12:56:07
Page 35
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0377
2 -0.0402
3 -0.0251
Mean: -0.0344
SD : 0.0081
%RSD: 23.58
Element: Hi Seq
. No. : 137
StndConc
mg/L
-0.0377
-0.0402
-0.0251
-0.0344
0.0081
23.58
.No.: 138
AS
BlnkCorr
Signal
-0.002
-0.002
-0.001
-0.001
0.000
23.58
AS
LOG . :
Peak
Area
0.065
0.065
0.066
Loc. :
Date-. 01/06/2006
Bkgnd Time
Area
0.004 12:56:31
0.004 12:56:33
0.004 12:56:35
Date: 01/06/2006
Sample ID: 307-22-23
Repl SampleConc
# mg/L
1 0.3391 ,
2 0.3337
3 0.3481
Mean: 0.3403
SD : 0.0073
%RSD: 2.14
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0051
2 -0.0117
3 -0.0271
Mean: -0.0146
SD : 0.0113
%RSD: 77.29
Element : Ni Seq
StndConc
mg/L
0.3391
0.3337
0.3481
0.3403
0.0073
2.14
. No. : 139
StndConc
mg/L
-0.0051
-0.0117
-0.0271
-0.0146
0.0113
77.29
. No. : 140
BlnkCorr
Signal
0.014
0.014
0.014
0,014
0:000
2.14
AS
BlnkCorr
Signal
0.000
0.000
-0.001
-0.001
0.000
77.29
AS
Peak
Area
0.080
0.080
0.081
Loc. :
Peak
Area
0.066
0.066
0.065
Loc. :
Bkgnd Time
Area
0.004 12:56:57
0.004 12:56:59
0.004 12:57:01
Date: 01/06/2006
Bkgnd Time
Area
0.003 12:57:20
0.003 12:57:22
0.003 12:57:24
.
Date: 01/06/2006
Sample ID: 307-25-26
Repl SampleConc
# mg/L
1 3.506
2 3.515
3 3.521
Mean: 3.514
SD : 0.0072
%RSD: 0.20
StndConc
mg/L
3.506
3.515
3.521
3.514
0.0072
0.20
BlnkCorr
Signal
0.143
0.143
0.143
0.143
0.000
0.20
Peak
Area
0.209
0.210
0.210
Bkgnd Time
Area
0.004 12:57:43
0.003 12:57:45
0.003 12:57:47
Page 36
-------
Element: Mi Seq. No.: 141
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr Peak Bkgnd Time
mg/L
0.0297
0.0412
0.0323
0. 0344
0.0060
17.49
mg/L
0.0297
0.0412
0.0323
0.0344
0.0060
17.49
Signal Area Area
0.001 0.068 0.002 12:59:40
0.002 0.068 0.001 12:59:42
0.001 0.068 0.002 12:59:44
0.001
0.000
17.49
Element: Ni Seq. No.
Sample ID: 307-28-29
142
AS LOG.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4.542
4.562
4.612
4.572
0.0359
0.78
StndConc
mg/L
4.542
4.562
4.612
4.572
0.0359
0.78
BlnkCorr Peak
Signal Area
0.185 0.252
0.186 0.252
0.188 0.254
0.186
0.001
0.78
Bkgnd Time
Area
0.002 13:01:03
0.002 13:01:05
0.002 13:01:07
Element: Ni Seq. No.: 143
Sample ID: ccb
AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%,RSD:
SampleConc
mg/L
0.0189
0.0256
0.0195
0.0213
0.0037
17.39
StndConc
mg/L
0.0189
0.0256
0.0195
0.0213
0.0037
17.39
BlnkCorr Peak
Signal Area
0.001 0.067
0.001 0.068
0.001 0.067
0.001
0.000
17.39
Bkgnd Time
Area
0.002 13:01:31
0.002 13:01:33
0.002 13:01:35
Element: Ni Seq. No.: 144
Sample ID: 307-31-32
AS Loc.
Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.948
absorbance
6.011
absorbance
6.011
absorbance
5.990
0.0362
0.61
absorbance
StndConc
mg/L
5.948
is greater
6.011
is greater
6,011
is greater
5.990
0.0362
0.61
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
242
that
245
that
245
that
244
001
.61
that
Peak
Area
0.
of
0.
of
0.
of
of
309
the
311
the
312
the
the
Bkgnd
Area
0.003
highest
Time
13:01:
standard.
0.002
highest
13:01:
54
56
standard.
0.003
highest
highest
13:01:
58
standard.
standard.
Page 37
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0054
2 -0.0107
3 0.0140
Mean: -0.0007
SD : 0.0130
%RSD: 1823
. No. : 145
StndConc
mg/L
-0.0054
-0.0107
0.0140
-0.0007
0.0130
1823
Element: Ni Seq. No. ; 146
Sample ID: 307-31-32 xlO
Repl SampleConc
f mg/L
1 0.6944
2 0.7131
3 0.7062
Mean: 0.7046
SD : 0.0095
%RSD: 1.34
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0062
2 -0.0023
3 0.0071
Mean: 0.0037
SD : 0.0052
%RSD: 141.3
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0143
2 0.0039
3 -0.0048
Mean: 0.0045
SD : 0.0095
%RSD: 212.5
StndConc
mg/L
0.6944
0.7131
0.7062
0.7046
0.0095
1.34
. No. : 147
StndConc
mg/L
0.0062
-0.0023
0.0071
0.0037
0.0052
141.3
. No. : 148
StndConc
mg/L
0.0143
0.0039
-0.0048
0.0045
0.0095
212.5
AS
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
1823.13
AS
BlnkCorr
Signal
0.028
0.029
0.029
0.029
0.000
1.34
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
141.33
AS
BlnkCorr
Signal
0,001
0.000
0.000
0.000
0.000
212.46
IjOC « >
Peak
Area
0.066
0.066
0.067
Loc. :
Peak
Area
0.095
0.096
0.095
Loc. :
Peak
Area
0.067
0.066
0.067
Loc. :
Peak
Area
0.067
0.067
0.066
Date:
Bkgnd
Area
0.003
0.003
0.002
Date:
Bkgnd
Area
0.003
0.003
0.003
Date:
Bkgnd
Area
0.003
0.003
0.002
Date:
Bkgnd
Area
0.003
0.003
0.003
01/06/2006
Time
13:02:46
13:02:48
13:02:50
01/06/2006
Time
13:03:22
13:03:25
13:03:27
01/06/2006
Time
13:03:43
13:03:46
13:03:48
01/06/2006
Time
13:04:16
13:04:19
13:04:21
Page 38
-------
Element: Ni Seq
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.5242
2 0.5521
3 0.5354
Mean: 0.5372
SD : 0.0140
%RSD: 2.61
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0123
2 0.0131
3 -0.0069
Mean: -0,0020
SD : 0.0134
%RSD: 662.0
Element: Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0061
2 -0.0005
3 -0.0023
Mean: -0.0030
SD : 0.0028
%RSD: 96.39
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0103
2 -0.0007
3 -0.0177
Mean: -0.0096
SD : 0.0086
%RSD: 89.41
. No. : 149
StndConc
mg/L
0.5242
0.5521
0.5354
0.5372
0.0140
2.61
. No. : 150
StndConc
mg/L
-0.0123
0.0131
-0.0069
-0.0020
0.0134
662.0
. No. : 151
StndConc
mg/L
-0.0061
-0.0005
-0.0023
-0.0030
0.0028
96.39
. No.: 152
StndConc
mg/L
-0.0103
-0.0007
-0.0177
-0.0096
0.0086
89.41
AS Loc. :
BlnkCorr Peak
Signal Area
0.021 0.088
0.022 0.089
0.022 0.088
0.022
0.001
2.61
AS Loc. :
BlnkCorr Peak
Signal Area
-0.001 0.066
0.001 0.067
0.000 0.066
0.000
0.001
662.01
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.067
0.000 0.066
0.000
0.000
96.39
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.067
-0.001 0.066
0.000
0.000
89.41
Date: 01/06/2006
Bkgnd Time
Area
0.004 13:04:34
0.003 13:04:36
0.003 13:04:38
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:04:55
0.002 13:04:57
0.003 13:04:59
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:05:15
0.003 13:05:17
0.003 13:05:19
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:05:35
0.003 13:05:37
0.003 13:05:39
Page 39
-------
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.023
2 1.020
3 1.025
Mean: 1.023
3D : 0.0027
%RSD: 0.26
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0103
2 -0.0084
3 -0.0072
Mean: -0.0086
SD : 0.0016
%RSD: 19.24
Element: Ni Seq
Sample ID: 307-3
Repl SampleConc
# mg/L
1 0.0679
2 0.0637
3 0.0553
Mean: 0.0623
SD : 0.0064
%RSD: 10.32
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0304
2 0.0159
3 0,0346
Mean: 0.0270
SD : 0.0098
%RSD: 36.36
. No.: 153
StndConc
mg/L
1.023
1.020
1.025
1.023
0.0027
0.26
. No.: 154
StndConc
mg/L
-0.0103
-0.0084
-0.0072
-0.0086
0.0016
18.24
, No.: 155
StndConc
mg/L
0.0679
0.0637
0.0553
0.0623
0.0064
10.32
. No. : 156
StndConc
mg/L
0.0304
0.0159
0,0346
0.0270
0.0098
36.36
AS LOG. :
BlnkCorr Peak
Signal Area
0.042 0.108
0.042 0.108
0.042 0.108
0.042
0.000
0.26
AS Loc. :
BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.066
0.000 0.066
0.000
0.000
18.24
AS Loc. :
BlnkCorr Peak
Signal Area
0.003 0.069
0.003 0.069
0.002 0.069
0.003
0.000
10.32
AS Loc. : •
BlnkCorr Peak
Signal Area
0.001 0.068
0.001 0.067
0.001 0.068
0.001
0.000
36.36
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:05:55
0.004 13:05:58
0.004 13:06:00
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:06:18
0.003 13:06:20
0.003 13:06:23
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:06:48
0.003 13:06:50
0.003 13:06:52
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:07:09
0.002 13:07:11
0.002 13:07:14
Page 40
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: d307-3
SampleConc
mg/L
0.0020
0.0583
0.0647
0.0416
0.0345
82.86
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean;
SD :
%RSD:
El ement
Sample
Repl
ID: ccb
SampleConc
mg/L
0.0309
0.0327
0.0284
0.0306
0.0021
6.99
: Ni Seq
ID: S307-3
SampleConc
mg/L
1.011
1.033
1.016
1.020
0.0113
1.11
: Ni Seq
ID: ccb
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.0166
0.0261
0.0171
0.0199
0.0054
26.91
. No. : 157
StndConc
mg/L
0.0020
0.0583
0.0647
0.0416
0.0345
82.86
. No.: 158
StndConc
mg/L
0.0309
0.0327
0.0284
0.0306
0.0021
6.99
.No.: 159
StndConc
mg/L
1.011
1.033
1.016
1.020
0.0113
1.11
. No. : 160
StndConc
mg/L
0.0166
0.0261
0.0171
0.0199
0.0054
26.91
AS
BlnkCorr
Signal
0.000
0.002
0.003
0.002
0.001
82.86
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
6.99
AS
BlnkCorr
Signal
0.041
0.042
0.041
0.042
0.000
1.11
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
26.91
Loc. :
Peak
Area
0.067
0.069
0.069
Loc. :
Peak
Area
0.068
0.068
0.068
Loc. :
Peak
Area
0,108
0.109
0.108
Loc. :
Peak
Area
0.067
0.068
0.067
Date: 01/06/2006
Bkgnd Time
Area
0.005 13:08:34
0.003 13:08:36
0.002 13:08:38
Date: 01/06/2006
Bkgnd Time
Area
0.001 13:09:06
0.001 13:09:08
0.001 13:09:10
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:09:41
0.002 13:09:43
0.002 13:09:45
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:09:59
0.003 13:10:01
0.003 13:10:03
Page 41
-------
Element: Ni Seq
. No.: 161 AS Loc.:
Date: 01/06/2006
Sample ID: ser307-3
Repl SampleConc
# mg/L
1 0.2258
2 0.2224
3 0.2281
Mean: 0.2254
SD : 0.0029
%RSD: 1.28
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0174
2 0.0458
3 0.0338
Mean: 0.0323
SD : 0.0143
%R^D: 44.09
Element: Ni Seq
Sample ID: 307-6
Repl SampleConc
# mg/L
1 0.2232
2 0.2288
3 0.2196
Mean: 0.2239
SD : 0.0046
%RSD: 2.07
Elements Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0604
2 0.0532
3 0.0619
Mean: 0.0585
SD : 0.0047
%RSD: 7.96
StndConc BlnkCorr Peak
mg/L Signal Area
0.2258 0.009 0.076
0.2224 0.009 0.076
0.2281 0.009 0.076
0.2254 0.009
0.0029 0.000
1.28 1.28
. No, : 162 AS Loc. :
StndConc BlnkCorr Peak
mg/L Signal Area
0.0174 0.001 0.067
0.0458 0.002 0.068
0.0338 0.001 0.068
0.0323 0.001
0.0143 0.001
44.09 44.09
. No.: 163 AS Loc.:
StndConc BlnkCorr Peak
mg/L Signal Area
0.2232 0.009 0.076
0.2288 0.009 0.076
0.2196 0.009 0.076
0.2239 0.009
0.0046 0.000
2.07 2.07
. No. : 164 AS Loc. :
StndConc BlnkCorr Peak
mg/L Signal Area
0.0604 0.002 0.069
0.0532 0.002 0.069
0.0619 0.003 0.069
0.0585 0.002
0.0047 0.000
7.96 7.96
Bkgnd Time
Area
0.003 13:10:59
0.004 13:11:01
0.003 13:11:03
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:11:54
0.002 13:11:56
0.002 13:11:58
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:12:19
0.002 13:12:21
0.002 13:12:23
Date: 01/06/2006
Bkgnd Time
Area
0.001 13:12:38
0.002 13:12:40
0.002 13:12:43
Page 42
-------
Element: Ni Seq
Sample ID: 307-9
Repl SampleConc
# mg/L
1 0.1782
2 0.1789
3 0.1879
Mean: 0.1817
SD : 0.0054
%RSD: 2.98
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0302
2 0.0313
3 0.0377
Mean: 0.0331
SD : 0.0041
%RSD: 12.29
Element: Ni Seq
Sample ID: 307-12
Repl SampleConc
# mg/L
1 0.1213
2 0.1155
3 0,1131
Mean: 0.1166
SD : 0.0042
%RSD: 3.61
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0141
2 0.0240
3 0.0419
Mean: 0.0266
SD : 0.0141
%RSD: 52.78
. No.: 165
StndConc
mg/L
0.1782
0.1789
0.1879
0.1817
0.0054
2.98
. No. : 166
StndConc
mg/L
0.0302
0.0313
0.0377
0.0331
0.0041
12.29
. No.: 167
StndConc
mg/L
0.1213
0.1155
0.1131
0.1166
0.0042
3.61
. No.: 168
StndConc
mg/L
0.0141
0.0240
0.0419
0.0266
0.0141
52.78
AS LOG. :
BlnkCorr Peak
Signal Area
0.007 0.074
0.007 0.074
0.008 0.074
0.007
0.000
2.98
AS Loc. :
BlnkCorr Peak
Signal Area
0.001 0.068
0.001 0.068
0.002 0.068
0.001
0.000
12.29
AS Loc. :
BlnkCorr Peak
Signal Area
0.005 0.071
0.005 0.071
0.005 0.071
0.005
0.000
3.61
AS Loc. :
BlnkCorr Peak
Signal Area
0,001 0.067
0.001 0.068
0.002 0.068
0.001
0.001
52.78
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:12:59
0.002 13:13:01
0.002 13:13:03
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:13:23
0.002 13:13:25
0.002 13:13:27
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:13:43
0.003 13:13:45
0,003 13:13:47
Date: 0^/06/2006
Bkgnd Time
Area
0.003 13:14:05
0.003 13:14:08
0.002 13:14:10
Page 43
-------
Element: Ni Seq.
Sample ID: 307-15
Repl SampleConc
# mg/L
I 0.0888
2 0.0926
3 0.0924
Mean: 0.0913
SD : 0,0021
%RSD: 2.34
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0499
2 0.0231
3 0.0097
Mean: 0.0276
SD ; 0.0205
%RSD: 74.23
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0414
2 0.0159
3 0.0208
Mean: 0.0260
SD : 0.0135
%RSD: 51.81
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2846
2 0.2928
3 0.2808
Mean: 0.2861
SD : 0.0061
%RSD: 2.14
No.: 169
StndConc
mg/L
0.0888
0.0926
0.0924
0.0913
0.0021
2.34
No.: 170
StndConc
mg/L
0.0499
0.0231
0.0097
0.0276
0.0205
74.23
No,: 171
StndConc
mg/L
0.0414
0.0159
0.0208
0.0260
0.0135
51.81
No. : 172
StndConc
mg/L
0.2846
0.2928
0.2808
0.2861
0.0061
2.14
AS Loc. :
BlnkCorr Peak
Signal Area
0.004 0.070
0.004 0.070
0.004 0.070
0.004
0.000
2.34
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.069
0.001 0.067
0.000 0.067
0.001
0.001
74.23
AS Loc. :
BlnkCorr Peak
Signal Area
0.002 0.068
0.001 0,067
0.001 0.067
0.001
0.001
51.81
AS Loc. :
BlnkCorr Peak
Signal Area
0.012 0.078
0.012 0.078
0,011 0.078
0.012
0.000
2.14
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:14:24
0.003 13:14:26
0.003 13:14:29
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:14:48
0,003 13:14:51
0.003 13:14:53
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:15:00
0.003 13:15:02
0.003 13:15:04
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:15:18
0.003 13:15:20
0.003 13:15:22
Page 44
-------
Element
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
: Ni Seq
ID: ccb
SampleConc
mg/L
0.0300
0.0241
0.0118
0.0220
0.0093
42.26
: Ni Seq
ID: 307-18
SampleConc
mg/L
0.1567
0.1776
0.1781
0.1708
0.0122
7.13
: Ni Seq
ID: ccb
SampleConc
rag/L
0.0110
0.0171
0.0146
0.0142
0.0031
21.47
: Ni Seq
ID: 307-21
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.1193
0.1469
0.1362
0.1341
0.0139
10.36
. No. : 173
StndConc
mg/L
0.0300
0.0241
0.0118
0.0220
0.0093
42.26
. No. : 174
StndConc
mg/L
0.1567
0.1776
0.1781
0.1708
0.0122
7.13
. No. : 175
StndConc
mg/L
0.0110
0.0171
0.0146
0.0142
0.0031
21.47
. No. : 176
StndConc
mg/L
0.1193
0.1469
0.1362
0.1341
0.0139
10.36
AS
BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
42.26
AS
BlnkCorr
Signal
0.006
0.007
0,007
0.007
0.000
7.13
AS
BlnkCorr
Signal
o.ooo
0.001
0.001
0.001
0.000
21.47
AS
BlnkCorr
Signal
0.005
0.006
0.006
0.005
0.001
10.36
LOG. :
Peak
Area
0.068
0.068
0.067
Loc. :
Peak
Area
0.073
0.074
0.074
Loc. :
Peak
Area
0.067
0.067
0.067
Loc. :
Peak
Area
0.071
0.073
0.072
Date:
Bkgnd
Area
0.003
0.003
0.003
Date:
Bkgnd
Area
0.003
0.003
0.003
Date:
Bkgnd
Area
0.004
0.003
0.003
Date:
Bkgnd
Area
0.004
0.003
0.003
01/06/2006
Time
13:15:
13:15:
13:15:
41
43
45
01/06/2006
Time
13:16:
13:16:
13:16:
00
03
05
01/06/2006
Time
13:16:
13:16:
13:16:
24
26
28
01/06/2006
Time
13:16:
13:17:
13:17:
59
01
03
Page 45
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0348
2 0.0236
3 0.0317
Mean: 0.0300
3D : 0.0058
%RSD: 19.17
Element: Ni Seq
Sample ID: 307-24
Repl SampleConc
# mg/L
1 0.1328
2 0.1147
3 0.1367
Mean: 0.1281
SD : 0.0117
%RSD: 9.16
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0420
2 0.0497
3 0.0568
Mean: 0.0495
SD : 0.0074
%RSD: 14.92
Element: Ni Seq,
Sample ID: 307-27
Repl SampleConc
# mg/L
1 0.2056
2 0.2175
3 0.1960
Mean: 0.2064
SD : 0.0108
%RSD: 5.22
. No. : 177
StndConc
mg/L
0.0348
0.0236
0.0317
0.0300
0.0058
19.17
. No. : 178
StndConc
mg/L
0.1328
0.1147
0.1367
0.1281
0.0117
9.16
. No. : 179
StndConc
mg/L
0.0420
0.0497
0.0568
0.0495
0.0074
14.92
. No. : 180
StndConc
mg/L
0.2056
0.2175
0.1960
0.2064
0.0108
5.22
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
19.17
AS
BlnkCorr
Signal
0.005
0.005
0.006
0.005
0.000
9.16
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
14.92
AS :
BlnkCorr
Signal
0.008
0.009
0.008
0.008
0.000
5.22
Loc. :
Peak
Area
0.068
0.068
0.068
Loc. :
Peak
Area
0.072
0.071
0.072
Loc. :
Peak
Area
0.068
0.069
0.069
Loc. :
Peak
Area
0.075
0.075
0.075
Date: 01/06/2006
Bkgnd Time
Area
0.003 13:17:25
0.003 13:17:27
0.003 13:17:29
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:18:03
0.002 13:18:06
0.002 13:18:08
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:18:28
0.002 13:18:30
0.001 13:18:32
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:19:12
0.002 13:19:14
0.003 13:19:16
Page 46
-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0519
2 0.0484
3 0.0596
Mean: 0.0533
SD : 0.0057
%RSD: 10.72
Element: Ni Seq
Sample ID: 307-30
Repl SampleConc
# mg/L
1 0,1743
2 0.1605
3 0.1585
Mean: 0.1644
SD : 0.0086
%RSD: 5.22
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0405
2 0.0655
3 0.0517
Mean: 0.0526
SD : 0.0125
%RSD: 23.77
Element: Ni Seq
Sample ID: 307-33
Repl SampleConc
# mg/L
1 0.1170
2 0.1124
3 0.1321
Mean: 0.1205
SD : 0.0103
%RSD: 8.55
. No. : 181
StndConc
mg/L
0.0519
0.0484
0.0596
0.0533
0.0057
10.72
. No. : 182
StndConc
mg/L
0.1743
0.1605
0.1585
0.1644
0.0086
5.22
. No. : 183
StndConc
mg/L
0.0405
0.0655
0.0517
0.0526
0.0125
23.77
. No, : 184
StndConc
mg/L
0.1170
0.1124
0.1321
0.1205
0.0103
8.55
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
10.72
AS
BlnkCorr
Signal
0.007
0.007
0.006
0.007
0.000
5.22
AS
BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
23,77
AS :
BlnkCorr
Signal
0.005
0.005
0.005
0.005
0.000
8.55
LOG. :
Peak
Area
0.069
0.069
0.069
LOG. :
Peak
Area
0.074
0.073
0.073
LOG. :
Peak
Area
0.068
0.069
0.069
LOG, :
Peak
Area
0.071
0.071
0.072
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:19:34
0.002 13:19:36
0.002 13:19:38
Date: 01/06/2006
Bkgnd Time
Area
0.001 13:20:11
0.002 13:20:14
0.002 13:20:16
Date: 01/06/2006
Bkgnd Time
Area
0,002 ^.3:20:44
0.001 13:20:46
0.001 13:20:48
Date: 01/06/2006
Bkgnd Time
Area
0.002 13:21:09
0.002 13:21:11
0.002 13:21:13
Page 47
-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0502
0.0606
0.0579
0.0562
0.0054
9.56
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0533
0.0560
0.0740
0.0611
0.0113
18.42
Element: Mi Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0533
0.0494
0.0553
0.0527
0.0030
5.71
: Ni Seq
ID: ccv
SampleConc
mg/L
0.5464
0.5782
0.5912
0.5719
0.0231
4.03
. No. : 185
StndConc
mg/L
0.0502
0.0606
0.0579
0.0562
0.0054
9.56
. No.: 186
StndConc
mg/L
0.0533
0.0560
0.0740
0.0611
0.0113
18.42
. No.: 187
StndConc
mg/L
0.0533
0.0494
0.0553
0.0527
0.0030
5.71
.No.: 188
StndConc
mg/L
0.5464
0.5782
0.5912
0.5719
0.0231
4.03
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
9.56
AS
BlnkCorr
Signal
0.002
0.002
0.003
0.002
0.000
18.42
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
5.71
AS
BlnkCorr
Signal
0.022
0.024
0.024
0.023
0.001
4.03
LOG. :
Peak
Area
0.069
0.069
0.069
LOG. :
Peak
Area
0.069
0.069
0.070
Loc. i
Peak
Area
0.069
0.069
0.069
Loc. :
Peak
Area
0.089
0.090
0.091
Date:
Bkgnd
Area
0.002
0.001
0.001
Date:
Bkgnd
Area
0.002
0.001
0.001
Date:
Bkgnd
Area
0.002
0.002
0.001
Date:
Bkgnd
Area
0.003
0.002
0.002
01/06/2006
Time
13:21:
13:21:
13:21:
33
36
38
01/06/2006
Time
13:21*
13:21:
13:21:
46
48
51
01/06/2006
Time
13:22:
13:22:
13:22:
07
10
12
01/06/2006
Time
13:22:
13:22:
13:22:
27
29
31
Page 48
-------
METALS PREP FORM
Set#
Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA200's, SW-8463010A
ICP/FLAA: EPA 200.7 r4.4
[CP/FLAA: SW-8463005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER I [AQUEOUS
OTHER:
1
2
ft
4
j»
R
7
8
9
10
11
12
Set
Inif
UL
Set
date
Uk
I
Set
time^
II*-
Lab#
16030 9
Smp#
3
,<
f
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(mis)
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(
-------
Prep Msthotiil {check oniy one per pags)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER I [AQUEOUS
OTHER:
Set I Set
Init'l date
Set
time
Lab#
Smp #
Company
Aliquot
(mis)
Final
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Page 1 of 1
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Met hod: (check only one per page)
Set*
ICP/FLAA: SM 3030 F, EPA 200.7 '82
IGP/FLAA: EPA 200's, SW-84S 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-8463005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
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S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
-------
Identification
Method Name: NI
Technique: Fl ame
Method Desc: Nickel
Remarks:
Element: Ni
Instrument Model: 5100
Instrument
Wavelength (nm): 232.0
Slit Width: 0.2
Signal Type: AA-BG
Signal Measurement: Time Average
Modified Spectrometer Settings: No
Modified Flame Settings: No
Read Time (sec): 1.0
Read Delay (sec): 0.0
Flame Type: Air/C2H2
Oxidant Flow (L/min): 10.0
Fuel Flow (L/min): 2.0
Calibration
Equations, Units, and Replicates:
Element Calibration Equation
Ni Linear, Zero Intercept
Replicates :
Calib.Std.
Calib.Std.
Calib.Std.
Calib.Std.
Calib.Std.
Autos ampler
Tray Type:
Wash
Fixed
1
2
3
4
5
Setup
Tray F
: 3
CAL
cal
cal
cal
cal
ID
STD
std
std
std
std
2
3
4
5
Frequency: Never
Duration: 1
Calibration Sample
Units Units
mg/L
mg/L
Max Max
Decimal Significant
Places Figures
4 4
Cone. (
mg/L)
0.25
0.50
1.00
2.00
5.00
A/S Loc
Location of Wash Solution: 0
Checks
Check correlation coefficient?
Recalibrate instrument periodically?
Analyze standards at end of run? . •- .
Check Precision?
.No
.No
.No
.No
Reanalyze samples beyond calibration range? ....No
Perform matrix check calculations? No
Page 53
-------
Quality Control
Concentration Units: Calibration ( mg/L)
Periodic Timing of Analyses
Count: Samples Interrupt sample to analyze QC: No
Frequency: Same for all QC's, 1
Maximum Retries After QC Failure
Maximum allowed reanalyses: 1 Action when maximum exceeded: Continue
Options
Results Display/Printed Log - Modified Settings: Yes
Method Header
Method Name Element Method Description
Date Technique Wavelength Lamp Current Sample Info File Name Calibration Equation
Slit Width Energy Results Data Set Name
Results Header
Element Sequence Number Autosampler Location Date
Sample ID
Column Headings
Concentration Data: Cone. - Sample Units Cone. - Calibration Units
Absorbance Data: Blank Corrected Signal Peak Area Bkgnd. Peak Area
Additional Parameters: Time
Data Categories
Data: Replicate Data Mean Data Statistics
Peaks: Last Replicates
Summary: Calibration Curve Calibration Summary
Peaks to Save: None
Page 54
-------
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PROJECT # 080033: METHOD 29 FOR NICKEL
date: 11/01/05
1 Method Detection Limit for Flame AA of Nickel: 0.075 mg/L
This MDL is calculated as per40CFR Part 136, Appendix B.
2 Detection for Impinger sample: 0.004 mg Ni
0.075 mg/L X "AF 2A" mis X "Initial Sample Volume" mis / "SF 2A" mis X 1 L /1000 mis
MLS OF
FINAL MLS ORIGINAL CONVERSION TO
MDL (AF2A) SAMPLE MLS USED "MG NI"
0.075 50 300 300 0.001 0.0038
Although the actual mis of "original sample" varied, the volume used is that which will yield the
highest value for the MDL.
2 Detection for filter & probe rinse sample: 0.007 mg Ni
0.075 mg/L X "AF 1A" mis X "Sample Volume" mis / "SF 1" mis X 1 L /1000 mis
MLS OF
FINAL MLS ORIGINAL CONVERSION TO
MDL (AF1A) SAMPLE MLS USED "MG NI"
0.075 100 10° 100 0.001 0.0075
(+ 1 filter)
3 Detection for TOTAL RUN sample: 0.011 mg Ni
= Impinger + filter & probe rinse
-------
Appendix F
Laboratory QA/QC Data for Ambient Air Samples
-------
PROJECT # 100016: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 10/4/05
BY ICP ON 10/5/05
IDL -
LOD =
MDL =
0.004
0.008
0.007
LOQ • 0.017
RL = 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
100016-1
100016-2
100016-3
100016-4
100016-5
100016-6
100016-7
100016-8
100016-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
0.211
4.01
0.092
0.107
0.012
0.012
0.044
0.029
0.017
0.015
-•• ' aooi : if
•MDL of 0.007 mg/L & > RL of 0.05 mg/L
= 100 X4.01/-4.0 = 100% Recovery, so okay
= FLAG "B"
13 10
13 5>
ap N*
20 S
=0.006
EXPLANATIONS:
Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
process were added, no filter.
Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
digestion process, again, no filter.
25 ml class A volumetric flask was used to measure the final volume.
mg/L as determined by average of three replicates on ICP.
The result is over the detection limits as quantified for nickel. Therefore the result may
be significant and must be "flagged" to indicate that it may be a false positive "hit", as
occurred in the LRB.
LRB =
LFB =
DILUTION =
READING =
FLAG "B" =
I BORDER TO FACILITATE FURTHER CALCULATIONS, IF A RE'ADINQ^IS
-------
Laboratory Work Order Report
LlMSNo. 2005100016 Date Rec'd 10/03/2005 02:37:49 Date Due 10/03/2005 12:00:00 AM
Project Code .NULL Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLINAVE.
CHICAGO IL 60623
Phone 254-2406 Fax 254-6661 Contact MR. FRANK ALTMAYER
Matrix Engineering Po No. -0- e-mail
Quoted Price: .NULL.
Client Notes: -o-
Order Comments: .NULL.
.NULL
Sample No. Comments Test Code Description Date Received Result
.NULL.
1 09/27/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - NORTH 10/03/2005 08:30:00 AM
Nl NICKEL
2 09/27/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - SOUTH 10/03/2005 08:30:00 AM
Nl NICKEL
3 09/28/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - NORTH 10/03/2005 08:30:00 AM
Nl NICKEL
4 09/28/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - SOUTH 10/03/2005 08:30:00 AM
Nl NICKEL
5 09/29/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - NORTH 10/03/2005 08:30:00 AM
Nl NICKEL
6 09/29/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - SOUTH 10/03/2005 08:30:00 AM
Nl NICKEL
7 09/30/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - NORTH 10/03/2005 08:30:00 AM
Nl NICKEL
8 09/30/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - SOUTH 10/03/2005 08:30:00 AM
Nl NICKEL
9 09/30/2005 WATTS NICKEL BARREL - ARTISTIC PLATING - BLANK 10/03/2005 08:30:00 AM
Nl NICKEL
Page 1
-------
MFTALS PREP FORM
Set#
Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
IV1M
1
2
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4
5
6
7
8
9
10
11
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Page 1 of 1
-------
Sample Information Detail Report
Document Name: 100505-2
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
100505-2
mL
9
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Sample Prep. Vol.
Sample ID
ccv 0.50
ccb
Ifb
Irb
100016-1
100016-2
100016-3
100016-4
100016-5
ccv 100
ccb
100016-6
100016-7
100016-8
100016-9
ccv 2
ccb
Aliquot Volume
Initial Sample Wt.
Diluted To Vol.
-------
Page
Date: 10/5/2005 1:55:54 PM
Analysis Begun
Jtart Time: 10/5/2005 1:42:39 PM Plasma On Time: 10/5/2005 10:43:51 AM
Logged In Analyst: sainmy Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sample Information File: C:\pe\sammy\Sample Information\100505-2.sif
Batch ID: 100505-2
Results Data Set: 100505-2
Results Library: C:\pe\sammy\Results\Results.mdb
Secnience No • 1 Autosampler Location: 0
£££mf CalL Blank 1 Date Collected: 10/5/2005 1:42:39 PM
Analyst: Data ***** ^^^
initial Sample Wt: Initial Sample Vol:
Dilution.: Sample Prep Vol:
Mean Data: Calib Blank 1
Mean Corrected Califc
Analyte Intensity Std.Dev. RSD Cone. Units
Yfo 328 937 2712250.8 12408.72 0-46% 10.0 mg/l
Ni 231.604t -114.0 1.31 1.15% [0.00] mg/L
,, . o Autosampler Location: 1
D- Cal 21+7 1 00 Date Collected: 10/5/2005 1:46:19 PM
Analyst: ' Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
ISfean Data: Cal 21+7 1.00
Mean Congested CaUD
Analvte Intensity Std.Dev. RSD Cone. Units
Yb 328.937 2688576.1 311.76 0.01% 9.91 mg/L
Hi 231.604t 7346.8 26.28 0-36% [1-00] mg/1
Calibration Summary
„ . 3 Autosampler Location: 9
Sample ID: cev 0.50 Date Collected: 10/5/2005 1:49:40 PM
Analyst: Data_Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: ccvO.50 i [) i tv -- „ „„,_
Mean Corrected Calib ' Sample
jfcnalyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev.
Yb 328.937 2709630.5 9,99 mg/L 0.019
Ni 231 604t -a-joji •> n ^n4 -mrr/T, 0.0047 0.504 ma/I, u.uu^/
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
fean Data: ccfa
-------
Date: 10/5/2005 2:14:46 PM
Method: Axr Fxxrer jsx
Mean Corrected
Analyte Intensity
Yb 328.937 2721073.2
.1 231.604t -3.3 (
Sequence No . : 5
Sample ' ** : 1S5
Analyst:
Initial Sample Wt:
Dilution.:
Mean Corrected
Analyte Intensity
Yb 328.937 2595058.7
Ni 231.604t 29476.3
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: Irb
Mean Corrected
Analyte Intensity
sx
Sequence No, : 7
Sample ID: 100016—1
inalyst:
Initial Sample Wt:
Dilution:
Mean Data: 100016-1
Mean Corrected
Analyte Intensity
Yb 328.937 2685211.6
Ni 231.6G4t 676.2
Sequence No . : 8
Sample ID: 100016-2
Analyst :
Initial Sample Wt:
Dilution:
Mean Data: 100016-2
Mean Corrected
Analyte Intensity
Yfa 328.937 2655450.5
Ni 231.604t 786.3
Sequence No . : 9
Sample ID: 100016-3
Analyst :
Initial Sample Wt:
Dilution:
Calib
Cone. Units
„, 10 . 0"ing/I,
" 0.000 mg/L
Calib
Cone. Units
9.57 mg/L
4.01 mg/L
, cisnc- Units
^ * — "*
Calib
Cone. Units
9.90 mg/L
0.092 mg/L
Calib
Cone- Units
9.79 rag/!
0.107 mg/L
--- • / _~ i- c" -"" ' Sample
Std Dev. Cone. Units Std.Dev. RSD
0.03 °-25%
0.0008 0.000 iug/L 0.0008 186.43%
Autosampler Location: 11
Date Collected: 10/5/2005 1:56:52 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Std.Bev. Cone. Units Std.Dev. RSD^
0.059 0.61%
0.016 4.01 mg/L 0.016 0.39%
Autosampler Location: 12
Date Collected: 10/5/2005 2:00:15 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
-/--/• £r U
>.c^7; .5* M«* /^/)™j^// S&jt4r^'
Std Dev. Cone. Units Std.Dev. RSD
0.069 °-72%
Autosampler Location: 13
Date Collected: 10/5/2O05 2:04:07 PM
Initial Sample Vol:
Sample Prep Vol:
Sample
Std Dev. Cone. Units Std.Dev. RSD
0.041 °-42%
0.0013 0.092 mg/L 0.0013 1.38%
Autosampler Location: 14
Date Collected: 10/5/2O05 2:07:59 PM
Data Type : Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev. RSD
0.093 0.95%
0.0003 0.107 mg/L 0.0003 0.25%
Autosampler Location: 15
Date Collected: 10/5 /2O05 2:11:52 PM
Data Type : Original
Initial Sample Vol:
Sample Prep Vol:
yfean Data: 100016-3
-------
Page
Date: 10/5/2005 2:33:50 EM
Analyte
Trs 328.937
ri 231.604t
Mean Corrected
Intensity
2667898.3
84.9
Calir.
Cone. Units
9.84 mg/L
0.012 mg/1
Std.Dev.
0.056
0.0003
Sample
Cone. Units
0.012 mg/L
Std.Dev.
0.0003
USD
0.57%
2.63%
„ . IQ Autosanpler Location: 16
D- 100016-4 Bate Collected: 10/5/2005 2:15:45 PM
Analyst: " Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sanple Prep Vol:
Mean Data: 100016-4
Mean Corrected Calii> Sample
Analyte Intensity Cone. Units St^D^" C™C' *"*•** Std-Dev" Q^%
sampler Location: 17
Collected^ 10/5/2005 2 ;19:40 EM
Analyst: Bata - " ' "
Initial Sample Wt: Initial Sanple
Dilution: San9?le Prep Vol:
Mean Data: 100016-5
Mean Corrected Calib Sanple
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. BSD
vs.. -As era-? ?7195>15 1 10.0 mcr/L 0-05 0.3^
SS^SIt 3,21:2 0.044^/L 0-0004 0.044mg/X, 0.0004 1.00^
„ , 12 Autosan5>ler Location: 18
D: cev 1.00 Bate Collected: 10/5/2005 2:23:34 PM
Analyst: ' Data "?!&>&'• Original
Initial Sanple Wt: Initial Sanple Vol:
Dilution: Sample Prep Vol:
M^~Data"cw~l~00 Y^'^To
Mean Corrected Calib ' Sanple
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. KSD
Xb 328.937 2720862.6 10.0 mg/L " na u-^
Mi 23l!604t 7350.6 1.00 mg/I,
Analyst: ° Bata. Type: Original
Initial Sanple Wt: Initial Sanple Vol:
Dilution: Sanple Prep Vol:
Mean Data: ccb ' J
Mean Corrected Calib Sanple
Analyte Intensity Cone. Units St
-------
Method: Air Filter Hi
Page 4
Date: 10/5/2005 2:52:54
0.00?'
0.0=!, 3.67,
,T ., t-
Wt:
Dilution:
Autosaimler Location: 21
Seated: 10/5/2005 2:34:51
Data
Vol:
Mean Data: 100016-7
SM.o.v.
„ ic
ioOO-16-8
Autosaiupler Location: 22
Bate SSleoted: 10/5/20O5 2:33:47
Wt:
Dilution:
Initial Sa^le Vol :
San^le Prep Vol:
ifean Data: 100016-8
Mean Corrected
Calib
c^mnle
Sample
00=0.
Analvst-
initial Sanple Wt:
Dilution:
».015mg/X
Initial Sanrole Vol:
Sample Erep Vol:
0.00
,.«
Mean Data: 100016-9
ifean Corrected.
xntensity
Calib
Cone. Units
Std.Dev.
Cone. ITnxts
KSD%
0.0007 133,70%
a ~,-,^s,^> -an - ifi
cri
Analvst-
Initial Sanple Wt:
Dilution:
&utasan5>ler Location: 24
Bate Sleoted: 10/5/2005 2:46:41
Dafca !E^S: Origxnax
Initial Sairple Vol:
Sainple Prep Vol:
Analyte
Yfo 328.937
Hi 231.604t
Mean Corrected
Intensity
2760845.2
189.4
Cone.
10.2
0.026
Calib ' S" Sanple
Units Std-Dersr. Cone. Uaits
rag/I, 0.04
mg/L 0.0005 0.026 mg/L
Std-Dev.
0.0005
RSD
0.40%
1.98%
. yst:
initial Sample Wt:
Dilution:
Autosanyler location: 25
Bate Collected: 10/5/2005 2:5O:32 PM
Bata Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: ccv 2
-------
Page
Date: 10/5/2005 2:56:52 EM
Method: Air Fxiter
Analyte
Yb 328.937
:i 231.604t
•kT Orf">
Secnienoe i^o. . j£u
Sample ID: eeb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: cob
analyte
Yb 328.931
Hi 231.604t
Nl
Mean Corrected
Intensity
2690135.1
14725.9
Calit
Cone. Units
9.92 mg/i
2.00 mg/L
Std.Dev. Cone.
0.018
0.013 2.00
Sample
Units
mg/L
Std.Dev. RSD
0.18%
0.013 0.65%
Axitosamoler Location: 26
Date Collected: 10/5/2005 2:53:52 iM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Corrected
Intensity
2710743.7
-0.8
Calib
Cone- Units
( 0.000 mg/L
Std..Dev. Cone.
0 . 053
0.0006 0.000
e t> kJv]
Sample /
Units
mg/L
Std.Dev. BSD
0.53%
0.0006 565.021
1C,
-------
PROJECT # 100305: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/7/05
BY ICP ON 11/9/05
IDL =
LOD =
MDL •
0.004
0.008
0.007
LOQ = 0.017
RL = 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
100305-1
100305-2
100305-3
100305-4
100305-5
100305-6
100305-7
100305-8
100305-9
100305-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.005
1.00
7.28
0.914
0.085
0.16
'^005, ;?;'
5.83
0.174
6.90
0.433
:MDL of 0.007 mg/L =0.006
= 100 x 1.00/1.00 = 100% Recovery, ( 80-120%)
= 0.006
= 0.006
LRB =
EXPLANATIONS:
Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
process were added, no filter.
Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
LFB = digestion process, again, no filter.
DILUTION = 25 ml class A volumetric flask was used to measure the final volume.
READING = mg/L as determined by average of three replicates on ICP.
IttORBERTQ FACILITATEF&RTHER^CSLQPLATIOI^S, IF A READING,IS
-------
Laboratory Work Order Report
LIMSNo. 2005100305 Date Rec'd 10/21/2005 01:55:38 Date Due 10/21/2005 12:00:00 AM
Project Code .NULL. Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLIN AVE.
CHICAGOIL 60623
Phone 254-2406
Matrix Engineering
Client Notes: -o-
Order Comments: .NULL
.NULL.
Sample No. Comments
.NULL
1 10/17/2005
2 10/17/2005
3 10/18/2005
4 10/18/2005
5 10/18/2005
6 10/19/2005
7 10/19/2005
8 10/20/2005
9 10/20/2005
10 10/20/2005
Fax 254-6661
PoNo. -0-
Contact MR. FRANK ALTMAYER
e-mail
Quoted Price: .NULL.
Test Code Description
10/17/05 ARTISTIC WOODS EAST #27
Nl NICKEL
10/17/05 ARTISTIC WOODS WEST #27
Nl NICKEL
10/18/05 ELITE SULFAMATE NORTH #22
Nl NICKEL
10/18/05 ELITE SULFAMATE SOUTH #22
Nl NICKEL
10/18/05 ELITE-BLANK
Nl NICKEL
10/19/05 ARTISTIC WOODS EAST #28
Nl NICKEL
10/19/05 ARTISTIC WOODS WEST #28
Nl NICKEL
10/20/05 ARTISTIC WOODS EAST #29
Nl NICKEL
10/20/05 ARTISTIC WOODS WEST #29
Nl NICKEL
10/20/05 ARTISTIC - BLANK
Nl NICKEL
Date Received
Result
10/21/200504:30:00 PM
10/21/2005 04:30:00 PM
10/21/2005 04:30:00 PM
10/21/2005 04:30:00 PM
10/21/200504:30:00 PM
10/21/200504:30:00 PM
10/21/200504:30:00 PM
10/21/200504:30:00 PM
10/21/200504:30:00 PM
10/21/2005 04:30:00 PM
Page 1
-------
Prep Method " {check only one per page)
Set
ICP/FLAA:
ICP/FLAA:
1C
lu
l<~
0"
P/FLAA:
P/FLAA:
P/FLAA:
FHER:
SM 3030 F, EPA 200.7 '82
EPA 200's, SW-846 301 OA
EPA 200.7 r4.4
SW-846 3005A
SW-846 301 5A MICROWAVE
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
DTHFR:
MATRIX: (check only one per page)
n
1
9
B
4
5
6
7
8
9
10
11
1?
RINK1NG WATER
Set
Inif!
>
f
J
Set
date
/;
/r
j
1
I
\/
I
V
Set
time
JO*
v
Lab#
l003.o^>
/
-*>
/
/
^
AQUEOUS
. fr~*^\ "
fat r$^
/ /./7/)
J*y /(sir
^
or
OTHER:
1 ' *•• \
Smp #
I
^
3
i/
•/r
7
-------
Sample Information Detail Report
Document Name: 110905-1
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
110905-1
ml
g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Sample Prep. Vol.
Sample ID
cri
icsab
ccv 1.00
ccb
Ifb
Irb
100305-1
100305-2
100305-3
100305-4
ccv 0.50
ccb
100305-5
100305-6
100305-7
100305-8
100305-9
100305-10
cri
icsab
ccv 2.00
ccb
Aliquot Volume
Initial Sample Wt.
Diluted To Vol.
-------
Analysis Begun
Start Time: 11/9/2005 4:45:12 EM Plasma On Time: 11/9/2005 4:03:48 EM
,ogged In Analyst: sammy . Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sample Information File: C:\pe\sammy\Sample Information\Untitled.SIF
Batch ID: 1.10905-1
Results Bata Set:
Results Library:
Method Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
Sequence No.: 1
Sample ID: Calib Blank
Analyst:
Initial Sample Wt:
Dilution:
Method Last Saved: 10/14/2005 11:13:33 AM
MSF File:
Autosampler Location:
Date Collected: 11/9/2005 4:45:12 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: Calib Blank 1
Net
Repl# Analyte Intensity
1 Mn 257
1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.610
.752
.610
.752
.610
.752
aan Data: Calib
Analyte
Mn 257.610
Cu 324.752
-175
2107
-178
2077
-207
2099
Blank 1
Mean Corrected
Intensity
-187.0
2094.8
.3
.5
.1
.8
.6
.3
Corrected
Intensity
-175
2107
-178
2077
-207
2099
Std.Dev.
17.86
15.33
.3
.5
.1
.8
.6
.3
RSD
9.55%
0.73%
Cone.
[0
[0
[0
[0
[0
[0
-UUJ
.00]
.00]
.00]
.00]
.00]
Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Calib
Analysis
Time
16:
16:
16:
16:
16:
16:
:4b
:46
;46
:46
:46
:46
:37
:37
:47
:47
:57
:57
Cone. Units
[0
[0
.00] mg/L
.00] mg/L
Sequence No.: 2
Sample ID: Calb Stdl
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 11/9/2005 4:47:36 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data:
Repl# Analyte
1 Mn 257
1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.610
.752
.610
.752
.610
.752
Mean Data: Calb
Analyte
Mn 257. 610
Cu 324.752
Calb Stdl
Net
Corrected
Intensity
592478.
201806.
592218.
201681.
595484.
202609.
Stdl
Mean Corrected
Intensity
'593580. 6
199937.6
6
3
1
9
1
0
Intensity
592665
199711
592405
199587
595671
200514
Std.Dev.
1815.10
503.20
.5
.5
.1
.0
.1
.1
RSD
0.31%
0.25%
Cone.
[5.
[5.
[5.
[5.
[5.
[5.
00]
00]
00]
00]
00]
00]
Calib .
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Calib
Analysis
Time
16:
16:
16:
16:
16:
16:
48:
48:
48:
48:
49:
49:
47
47
58
58
10
10
\._
Cone . Units
[5
[5
.00] mg/L
.00] mg/L
-------
Pt-MiiB3C
page
Calibration Summary
Analyte
Mn
Cu
257.610
324.752
Stds.
1
1
Equation
Lin
Lin
Thru 0
Thru 0
Intercept
0.0
0.0
Slope
118700
39990
Curvature
0,
0.
.00000
.00000
Corr
1.
1.
. Coef.
000000
000000
Reslope
Sequence No. : 3
Sample ID: bee
Analyst:
Initial Sample Wt:
Dilution:
Autosarnpler location:
Date Collected: 11/9/2005 4:49:49 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: bee
Net Corrected
Repl# Analyte
1 Mn 257.610
1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.752
.610
.752
.610
.752
Intensity Intensity
0.3 187.3
0.7 -2094.
-0.1 186.
0.0 -2094.
-0.6 186.
-0.3 -2095.
Mean Data: bee r\V-" ^
Analvte
Mn
Cu
257.610
324.752
Mean Corrected J^-p^^Cali
2
9
8
4
1
'- £).
b
Intensity /Conc^ Units
186.9 ,' 0.002 mg/L
-2094.7 \-0.052 n(g/L
Cone.
0.002
-0.
0.
-0.
' 0.
-0.
.eg
Std
0.
0.
052
002
052
002
052
Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
.Dev.
0000
0000
Cone.
0.002
-0.052
0.002
-0.052
0.002
-0.052
Sample
Cone. Units
0.002 mg/L
-0.052 mg/L
Sample Analysis
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std. Dev
0.0000
0.0000
Time
16:50:'48
16:
16:
16:
16:
16:
.
50:48
51:08
51:08
51:28
51:28
RSD
0.26%
0.02%
Method Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
Sequence No.: 4
Sample H>: cv
Analy s t:
Initial Sair^le Wt:
Dilution:
Method Last Saved: 10/14/2005 11:13:33 AM
MSF File:
Autosampler Location:
Date Collected: 11/9/2005 4:52:12 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: cv
Kepl# Analyte
1
I
2
2
3
3
4
4
5
5
6
6
7
7
8
8
9
9
•10
10
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
: Cu 324.
610
752
610
752
610
752
610
752
610 -"
752
610
752
610
752
610
752
610
752
610
752
Net
Corrected
Intensity
598424
204294
604424
206239
599957
204630
598337
203877
598531
203915
602386
205170
. 605520
206320
602017
205280
604689
205928
603873
206148
.2
.3
.9
.9
.0
.5
.2
.4
.9
.2
.3
.2
.2
.2
.7
.4
.8
.7
.9
.4
Intensity
598611
202199
' 604611
204145
600144
202535
598524
201782
598718
201820
602573
203075
605707
204225
602204
203185
604876
203833
604060
204053
.2
.5
.9
.1
.0
.7
.2
.5
.9
.3
.3
.4
.2 .
.4
.7
.5
.8
.9
.9
.5
Cone .
5.04
5.06
5.09
5.11
5.06
5.06
5.04
5.05
5.04
5.05
5.08
5.08
5.10
5.11
5.07
5.08
5.10
5.10
5.09
5.10
Calib.
Units
mg/L •
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Sample
Cone. Units
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
.04 mg/L
. 06 mg/L
.09 mg/L
.11 mg/L
. 0 6 mg/L
. 0 6 mg/L
.04 mg/L
.05 mg/L
. 0 4 mg/L
. 05 mg/L
. 08 mg/L
. 08 mg/L .
. 10 mg/L
.11 mg/L
. 07 mg/L
-.08 mg/L
. 10 mg/L
.10 mg/L
. 09 mg/L
.10 mg/L
Analysis
Time
16:53:23
16:53:23
16:53:34
<16:53:34
16:53:46
16:53:46
16:53:57
16:53:57
16:54:09
16:54:09
16:54:20
16:54:20
16:54:32
16:54:32
16:54:44
16:54:44
16:54:55
16:54:55
16:55: 07
.16:55:07
-------
Method: ?t-Mn3SC Page 3 Date: 11/9/2005 4:55:12 BM
Mean Data: crv ...
Mean Corrected Calib Sample ^-^'"'-^
Analvte Intensity Cone, Units Std.Dev. Cone. Units Std.Dev. /RSD\ !
Mn 257.610 602003.3 5.07 mg/1 0.024 5.07 mg/1 0.024 / 0.47%\/
Cu 324.752 203085.7 5.08mg/I 0.024 5.08mg/L 0.024/ 0.47%|
-------
Method: Air Filter Ni
Page
Date: 11/9/2005 5:11:01 PM_
Analysis Begun
Start Time- 11/9/2005 5:01:10 PM Plasma On Time: 11/9/2005 4:03:48 PM
Logged S Analyst: sam^ Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001AutoSampler Model: AS-91
Sample Information File: C:\pe\sammy\Sample Information\110905-1.sif
Batch ID: 110905-1
Results Data Set: 110905-1
Results Library: C:\pe\sammy\Results\Results.mdb
Method Loaded
Method Name: Air Filter Ni
IEC File:
Method Description: AIR FILTER Ni
Sequence No. : 1
Sample ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
Method Last Saved: 10/5/2005 1:33:13 PM
MSF File:
Autosampler Location: 0
Date Collected: 11/9/2005 5:01:10 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: Calib Blank 1
Mean Corrected
Analyte Intensity
Yb 328.937 2065904.8
Ni 231.604t -156.0
Std.Dev. RSD
452.16 0.02%
9.33 5.!
Calib
Cone. Units
10.0 mg/L
[0.00] mg/L
Sequence No.: 2
Sample ID: Cal 21+7 1.00
Vnalyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 1
Date Collected: 11/9/2005 5:04:19 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: Cal 21+7 1.00
Mean Corrected
Analyte
Yb 328.937
Ni 231.604t
Calibration Summary
Analyte Stds.
Ni 231.604 1
Intensity
2033238.9
6243.7
Equation
Lin Thru 0
Calib
Std.Dev. RSD Cone. Units
6742.11 0.33% 9-84 mg/L
22.77 0.36% [1.00] mg/L
Intercept Slope Curvature
0.0 6244 0.00000
y .413
Corr. Coef. / Reslope
1.000000 /
V t>VL
Sequence No.: 3
Sample ID: cri
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 9
Date Collected: 11/9/2005 5:07:40 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: cri
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2096613.2
153.3
Calib
Cone . Units
10.1 mg/L /
0.025 mg/L J
|-80 *! •
Std.Dev.
0.02
0.0028
Sample
Cone . Units
0.025 mg/L
Std.Dev. RSD
0.21%
0.0028 11.36%
Sequence No.: 4
Jample ID: icsab
Autosampler Location: 10
Date Collected: 11/9/2005 5:11:01 PM
-------
Date: 11/9/2005 5:27:51 EM
Method: Air Filte
Analyst :
Initial Sample Wt
Dilution:
Mean Data: iosab
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 5
Sample ID : ccv 1 .
Analyst :
Initial Sample Wt
Dilution:
Mean Data : ccv 1 .
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 6
Sample ID : cob
Analyst:
Initial Sample "Wt
Dilution:
Mean Data: cob
Analyte
¥b 328.937
Ni 231.604t
Sequence No . : 7
Sample ID: Ifb /ft
Analyst: ^
Initial Sample Wt
Dilution:
Mean Data: Ifb
Analyte
yb 328.937
Ni 231.604t
Sequence No. : 8
Sample ID: Irb
Analyst:
Initial Sample Wt
Dilution:
Mean Data: Irb
Analyte
Yb 328.937
Ni 231.604t
r JMX
Mean Corrected
Intensity
2022975.1
6186.9
00
00
Mean Corrected
Intensity
2126757.0
6260.5
:
Mean Corrected
Intensity
2263307.5
10.9
I.* tf«
Mean Corrected
Intensity
1812066.7
6268.5
:
Mean Corrected
Intensity
1839953.4
-31.0
Calib
Cone . Units
9.79 mg/L
0.991 mg/L
Calib
Cone. Units
10.3 mg/L
1.00 mg/L
Calib
Cone. Units
11.0 mg/L
0.002 mg/L
Calib
Cone. Units
8.77 mg/L
1.00 mg/L
Calib
Cone . Units
8.91 mg/L
-0.005 mg/L
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
/)fl*j, \tf" ^
f/t"3 Sample
Std.Dev. Cone. Units
0.076
0.0114 0.991 mg/L
Autosampler Location: 11
Date Collected: 11/9/2005 5:14:22
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
JY_ /
""joo^o ^ **~'
Sample
Std.Dev. Cone. Units
0.10
0.006 1.00 mg/L
Autosampler Location: 12
Date Collected: 11/9/2005 5:17:43
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/ ©o 7 piA
X' Sample
Std.Dev. Cone. Units
0.67
0.0035 0.002 mg/L
Autosampler Location: 13
Date Collected: 11/9/2005 5:21:06
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
lf)0*le $-£<& Dtf- •
1 Sample
Std.Dev. Cone. Units
0.072
0.009 1-00 mg/L
Autosampler Location: 14
Date Collected: 11/9/2005 5:24:28
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/^€>t ^
Sample
Std.Dev. Cone. Units
0.042
0.0025 -0.005 mg/L
Std.Dev. RSD
0.78%
0.0114 1.15%
PM
Std.Dev. RSD
0.94%
0.006 0.57%
PM
Std.Dev. RSD
6.10%
0.0035 202.41%
PM
Std.Dev. RSD
0.82%
0.009 0.90%
PM
Std.Dev. RSD
0.47%
0.0025 50.97%
Sequence No. : 9
Sample ID: 100305-1
Autosampler Location: 15
Date Collected: 11/9/2005 5:27:51 EM
-------
Method: Air Filter Ni
Page
Date: 11/9/2005 5:44:54 EM
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Mean Data: 100305-1 Samole
^^ -^SSS" «- 2£ «j.s. c»c..5L ««-. -%
Sf!J:SIt "SSi:S ?:»SS S:JS — „« o.o6S „.».
a ~ ~~<= w>, • l n Autosampler Location: 16
Sle ?of i.00305-2 Dat. Collected: 11/9/2005 5:31:15 PM
Analvst- Data "^^ O^111*1
^tlal'sample Wt: Initial Sample Vol:
Dilution: Sa^le Pre*> Vo1:
Mean Data: 100305-2 csamnle
Mean Corrected Calob Sample
^yte intensity Cone Units Std.Dev. Cone. Unxts Std.Dev. QRSD%
Yb 328 937 1688961.9 8.18 mg/1 0.049
2 Sl^Mt 5709.8 0.914 mg/1 0.0080 0.914 mg/L 0.0080 0.88o
., ___ w_ . 11 Autosampler Location: 17
SS^f £003^5-3 Bate Elected: 11/9/2005 5:34:40 PM
Analvst- Data Type: Original
Initial"Sample Wt: Initial Sample Vol:
Dilution: Sa"3?le Pre*> Vol:
Mean Data: 100305-3 Samole
^^ -^SS?4 =«=.£££ .««,. c—^SS. SM.,.V. „
SS:SJ, 1719^- o!iHSS .?i»i 0-0.5^ ....37J..1.
c ^,,=^^<=. -wn • 19 Autosampler Location: 18
SJe ?Df io03?5-4 ^te Elected: 11/9/2005 5:38:04 PM
Analyst- Data 'S^>e'- O^^^31
initial Sample Wt: Initial Sample Vol:
Dilution: San9?le PreP Vol:
Mean Data: 100305-4 n
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD^
Yb 328.937 1691084.4 8.19 mg/1 0.086 nnn9n i"?7*
Ni 231.604t 998.8 0.160 mg/1 0.0020 0.160 mg/L 0.0020 1.27»
q^mie-nr'ff. No • 13 Autosampler Location: 19
S?e ^f ^v 0 .50 Date Collected: 11/9/2005 5:41:29 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
^° o i ^.
Mean Corrected Calib 1°' Sample
Analyte Intensity Cone. Units Std-De- C°nC' UnltS S^d.Dev. RSD
SISlSJt 211360?7l 0^1 Sg O.Sill 0.493mg/L 0.0191 al,
^^r~~~~~~~~^^^^^ —4 -
-------
thod:
Filt.
Ni
Page
Date: 11/9/2005 6:01:59 EM
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: ccb / , <9
-------
Date: 11/9/2005 6:19:11 EM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 100305-9
Mean Corrected
Analyte Intensity
Yb 328.937 1721520.7
Ni 231.604t 2701.4
Sequence No . : 20
Sample ID: 100305-10
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 100305-10
Mean Corrected
Analyte Intensity
Yb 328.937 1709132.1
Ni 231.604t -28.7
Sequence No . : 21 _
Sample ID: -oas- (_£-~U l^P^
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: cri
Mean Corrected
'to.alyte Intensity
b 328.937 2342720.9
Ni 231.604t 12526.7
Sequence No. : 22 -
Sample ID: •a-CSSB Cj£~-£7
Analyst:
Initial Sample Wt:
Dilution :
Mean Data: icsab
Mean Corrected
Analyte Intensity
Yb 328.937 2101020.0
Ni 231.604t 8.7
Sequence No. : 23 /
Sample, ID: ecv 2.,00 \. j I
Analyst.,: /'" /Me) 6a^£'tA-fx'
Initial SSample''wt: ' \ ,/ '/
Dilution:\ / feW
A V
Mean Data: ^-eejti2^©0 /"' (/
\Mean Corrected?!
Analyte \ Intensity \.
Yb 328'. 937 N2,5^333'64 . 6
Ni 231.604t / 24.1
Calib
Cone. Units
8 . 33 mg/L
0.433 mg/L
Calib
Cone. Units
8.27 mg/L
-0.005 mg/L
Calib
Cone. Units
11.3 mg/L
2.01 mg/L
Calib
Cone. Units
10.2 mg/L
0.001 mg/L
2,
K,
\ Calib
Corie. Units
x 12 . 3\mg/L
^ ••-• ^
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.199
0.0113 0.433 mg/L
Autosampler Location: 26
Date Collected: 11/9/2005 6:05:17
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Sample
Std.Dev. Cone. Units
0.175
0.0018 -0.005 mg/L
Autosampler Location: 27
Date Collected: 11/9/2005 6:09:06
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
. ^ e*]_o i) £_, &^~
It/'-' ' i Sample
Std.Dev. Cone. Units
0.05
0.002 2.01 mg/L
Autosampler Location: 28
Date Collected: 11/9/2005 6:12:27
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/ 0e?l 0^-'
^- " Sample
Std.Dev. Cone. Units
0.05
0. 0023 0.001 mg/L
Autosampler Location: 29
Date Collected: 11/9/2005 6:15:49
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Sample
' Std.Dev. Cone. Units
/ 0.18
0.0018 0.004 mg/L
Std.Dev. RSD
2.39%
0.0113 2.62%
PM
Std.Dev. RSD
2.12%
0.0018 40.10%
PM
Std.Dev. RSD
0.42%
0.002 0.12%
PM
Std.Dev. RSD
0. 46%
0.0023 165.21%
£,nj_ ®? ^UUA -
PM
Std.Dev. RSD
1.44%
0.0018 46.07%
"•equence No. : 24
imple ID: ccb
Autosampler Location: 30
Date Collected: 11/9/2005 6:19:11 PM
-------
PROJECT # 110200: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/14/05
BY ICP ON 11/15/05
IDL = 0.004
LOD a 0.008
MDL = 0.007
LOQ = 0.017
RL = 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
110200-1
110200-2
110200-3
110200-4
110200-5
110200-6
110200-7
110200-8
110200-9
110200-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.001
1.80
0.202
0.144
I". . o;po
-------
Laboratory Work Order Report
LIMSNo 2005110200 Date Rec'd 11/11/2005 03:40:03 Date Due 11/11/2005 12:00:00 AM
Project Code .NULL Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLINAVE.
CHICAGO IL 60623
Phone
Matrix
254-2406
Engineering
Fax 254-6661
PoNo. iCh
Contact MR. FRANK ALTMAYER
e-mail
Quoted Price: NULL.
Client Notes: -o-
Order Comments: .NULL
.NULL.
Sample No. Comments
.NULL
1 11/07/2005
2 11/07/2005
3 11/07/2005
4 11/08/2005
5 11/08/2005
6 11/09/2005
7 11/09/2005
8 11/09/2005
9 11/10/2005
10 11/10/2005
Test Code Description
11/07/05 - ABQC - #14 EAST
Nl NICKEL
11/07/05 - ABQC - #14 WEST
Nl NICKEL
11/07/05-ABQC-BLANK
Nl NICKEL
11/08/05 - ABQC - #15 EAST
Nl NICKEL
11/08/05-ABQC-#15 WEST
Nl NICKEL
11/09/05 - ARTISTIC - #7 EAST
Nl NICKEL
11/09/05 - ARTISTIC - #7 WEST
Nl NICKEL
11/09/05 - ARTISTIC - BLANK
Nl NICKEL
11/10/05 - ARTISTIC - #24 - EAST
Nl NICKEL
11/10/05 - ARTISTIC - #24 - WEST
Nl NICKEL
Date Received
Result
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
11/11/200511:30:00 AM
11/11/200511:30:00 AM
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
11/11/2005 11:30:00 AM
Page 1
-------
PROJECT # 110077: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/11/05
BY ICP ON 11/15/05
IDL a 0.004
LOD - 0.008
MDL • 0.007
LOQ • 0.017
RL =t 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
110077-1
110077-2
110077-3
110077-4
110077-5
110077-6
110077-7
110077-8
110077-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.004
0.716
0.206
0.180
0.505
0.404
0.209
0.185
0.180
0.156
•' ' '|l 003 : '\
l$, USED,
LFB =
11/16/05LK
S/ LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 121
X/ USEPA/ NICEIW PROJECT 21 Analytical data/ METHOD 121-2
-------
Laboratory Work Order Report
LlWlSNo 2005110077 Date Rec'd 11/03/2005 03:59:05 Date Due 11/03/2005 12:00:00 AM
Project Code .NULL. Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLINAVE.
CHICAGO IL 60623
Phone 254-2406
Matrix Engineering
Client Notes: -o-
Fax 254-6661
PoNo. -0-
Contact MR. FRANK ALTMAYER
e-mail
Quoted Price: .NULL.
Test Code Description
Order Comments: .NULL.
.NULL.
Sample No. Comments
.NULL
1 10/31/2005 10/31/05-RELIABLE-CONDITION #3-EAST
Nl NICKEL
2 10/31/2005 10/31/05-RELIABLE-CONDITION #3-WEST
Nl NICKEL
3 11/01/2005 11/01/05-RELIABLE-CONDITION #6-EAST
Nl NICKEL
4 11/01/2005 11/01/05-RELIABLE-CONDITION #6-WEST
Nl NICKEL
5 11/02/2005 11/02/05 - RELIABLE - CONDITION #5 - EAST
Nl NICKEL
6 11/02/2005 11/02/05 - RELIABLE - CONDITION #5 - WEST
Nl NICKEL
7 11/03/2005 11/03/05 - RELIABLE - CONDITION #4 - EAST
Nl NICKEL
8 11/03/2005 11/03/05-RELIABLE-CONDITION #4-WEST
Nl NICKEL
9 10/31/2005 10/31/05-RELIABLE-BLANK
Nl NICKEL
Date Received Result
11/03/2005 03:50:00 PM
11/03/200503:50:00 PM
11/03/200503:50:00 PM
11/03/200503:50:00 PM
11/03/200503:50:00 PM
11/03/200503:50:00 PM
11/03/2005 03:50:00 PM
11/03/2005 03:50:00 PM
11/03/200503:50:00 PM
Page 1
-------
Set*
Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTH ER:
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:_
MATRIX: (check only one per page)
DRINKING WATER I lAQUEOUS
OTHER:
1
2
3
4
5
6
7
8
9
10
11
12
Set
Inifl
^
Set
date
/• //( j I
It M-'
Set
time
H'p
Lab#
no 200
Smp#
\
3u
4
Lf
^"
^
~1
$
Q
\o
Company
LFB
LRB
12FPBUP
J-EI^
...
Aliquot
(mis)
iR^c
/
.V
i/
Final
(mis)
,-^. 1 **-^
.
X
t
r)- • • • .: .:.'.•
;'./ '•' '' :- • '
Mcr
Vsl#
GSTDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
/" ^
4
LOT*
£>cT}^£i /]
'
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Set
Prep Method: {check only one per page)
1CP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: ,
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER
1
2
3
4
5
6
7
8
9
10
11
12
Set
Inif
LX
Set
date
fn
J*
Set
time
Cj£,
u
Lab#
ll$®ll
ft*-> ,
Smp#
/
A
^3
V
^
1
K
1
/
AQUEOUS
Company
1 C£3 L) i 2- ^***b
i_rEj fe-^
LRB
KJLM)
LFW«W-
•BW--
X
'
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
Cjp* I
'
LOT#
£)g"^£) ^
y\
OTHER:
^
Aliquot
_imlsl_
d
t*0#
^
^
'
\
Final
(mis)
\ ^cJ^
\
/
.fO*A &&K:
'
1—.,
J
Mcr
Vsl#
'<
Analyst:
Start Date:
i^
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Sample Information Detail Report
Document Name: 111505-1
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
111505-1
ml
g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
Sample No Sample Prep. Vol.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Sample ID
ccv 9r66— i,OO
ccb
Irb
110077-1
110077-2
110077-3
110077-4
110077-5
110077-6
<
Initial Sample Wt.
ccb
110077-7
110077-8
110077-9
•Ifb 2
Irb
110200-1
110200-2
110200-3
ccb
110200-4
110200-5
110200-6
110200-7
110200-8
110200-9
110200-10
ccvf f
ccb
Aliquot Volume
Diluted To Vol.
-------
Method: Air Filter Ni
Page
Date: 11/15/2005 1:56:12 PM
Analysis Begun
-art Time- 11/15/2005 1:45:50 PM Plasma On Time: 11/15/2005 11:32:42 AM
-art Time. j.j./±o/^uu3-L Technique: ICP Continuous
3000 DV, S/N 069N5083001AutosaI[pler Model: AS-91
Sample Information File: C:\pe\sammy\Sarnple Information\111505-l.sif
Batch ID: 111505-1
Results Data Set: 111505-1
Results Library: C:\pe\sammy\Results\Results.mdb
Shod 5±fAir Filter Ni Method Last Saved: 10/5/2005 1:33:13 PM
IEC File: MSF File:
Method Description: AIR FILTER Ni
Autosantpler Location: 0
! s- sirss^15'"" 1:45:5°M
-
Mean Data: Calib Blank 1
Mean Corrected
Analvte Intensity Std.Dev. RSD Cone. Units
^328 937 2071926.8 10795.50 0.52% 10.0 mg/L
£ 23i:604t -171-4 11-69 6.82% [0.00] zng/L
Autosampler Location: 1
,.00 -.
Mean Data: Cal 21+7 1.00
Mean Corrected
Analvte Intensity Std.Dev. RSD Cone Units
Yb 328 937 2041837.0 2473.23 0.12% 9.85 mg/L
2 23?:604t 6318.1 44.95 0.71% [1-00] mg/L
Calibration Summary
a^si. "-rs
Autosampler Location: 9
,.^ j- ^--^15/20051:52!51
£5?.=?^'
Mean Data: ccv 9-^6
. — „-
/L o.oo™ ..,»
• A Autosampler Location: 10
ID ccb ^te Collected: 11/15/2005 1:56:12 PM
-------
Method: Air Filter Ni
Page
Date: 11/15/2005 2:14:02 EM
Data Type: Original
Q m^w- Initial Sample Vol:
initial Sample Wt. Vol;
Dilution: v r
Mean Data: ccb Sample
-o c-..—
°-°°"
Autosampler Location: 11
2:00:03 M
,
Dilution: 1} V v r L
Mean Data: Ifb Sample
iS. «.«-
«/L o.o»23 »
.n . f- Autosampler Location: 12
Sequence No 6 Collected: 11/15/2005 2:03:24 PM
Sample ID: Irb Data original
ss w. «
Dilution:
Mean Data: Irb
« .. „-
«°»»0' -0.004 „,/,
Autosampler Location: 13
sir, Sir^^15/2005 2:07i17 ra
i Q ^i« wt-- Initial Sample Vol:
Initial Sample wt: -IT, _ xr«i •
Dilution: Sample Prep Vol.
Mean Data: 110077-1 Samole
. —•
»™» »-»«-/' ••»»» °-
0 Autosampler Location: 14
D ilo077-2 Date Collected: 11/15/2005 2:10:39 PM
. ' Data Type: Original
' sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol.
Mean Data: 110077-2 Samole
-4 •'S
S!!J:SIt
~„„ . Q Autosampler Location: 15
f iIo?77-3 ^te CoHected: 11/15/2005 2:14:02 PM
-------
Method: Air Filter Ni
Page
Date: 11/15/2005 2:31:04 PM
Data Type: Original
:, -_ w.. Initial Sarnple Vol:
Sample Wt. Vol.
Dilution: ^ r
Mean Data: 110077-3 Sample
"-S£ST = SS 3«.s. =-.»«. «"-- „»
° ^ ..0033 „.«..
= ~ .,. Autosaitmler Location: 16
Science No : 10 Collected: 11/15/2005 2:17:25 PM
Sample ID: 110077-4 Data original
Analyst: Initial Sample Vol:
initial sample Wt: Pr^Vol:
Dilution: *^ *
Mean Data: 110077-4 Sanple
0«. SSS «d.D-. a-.""- •«.«-• ».
"^4 0.404.,/L ..0024 0.60S
.. .. • Autosairroler Location: 17
Sequence No : 11 Collected: 11/15/2005 2:20:50 PM
Sample ID: 110077-5 ^^ ^^ Original
Initial Sait^le Vol:
Sanple Prep Vol:
Mean Data: 110077-5 Sainple
-iSS?4 =«;.5SS —•
l«t ""'in?:? »!;»SS
~ Autosaitroler Location: 18
ss ^roS^15/2005 2:24;14 M
ssf^ir!
Mean Data: 110077-6 Sairole
4 =-.«*. .«.-«. ,
/L o.o.» ..7,.
Autosanpler Location: 19
. j£ Siro*s^15/2005 2i27!39 m
^ ssr-wtr1
Mean Data: oev-iC"S~^ Sanmle
Autosampler Location: 20
Date Collected: 11/15/2005 2:31:04 PM
-------
Method: Air Filter Ni
Eage 4
Date: 11/15/2005 2:49:12 EM
Data Type: Original
i „ m,« wt • Initial Sample Vol:
initial Sample Wt. Vol;
Dilution: *^ ^
Mean Data: ccb Sample
. «-.««.
0.001 »»/.
_ Autosairpler Location: 21
Seguence No 15 Collected: 11/15/2005 2:35:01 EM
Sainple ID: 110077-7 Data Type; Qriginal
ssf
Mean Data: 110077-7 Sample
VT ,,• Autosarapler Location: 22
Sequence No 16 Collected: 11/15/2005 2:38:27 EM
san.pl. m: 110077-8 ^^ Original
W-- initial San^le Vol:
Mean Data: 110077-8 Sample
Mean Corrected caJ.ir> *-
intensity Cone Units Std.Dev. Cone. Units Std.Dev.
0°0?292 0.156mg/L 0.0022 1.44%
Autosampler Location: 23
Mean Data: 110077-9 Sanple
Mean Corrected Calib .*;
intensity Cone Units Std.Dev. Cone. Units Std.Dev. Q%
-0.003 mg/L 0.0002 6.21%
„ IQ Autosampler Location: 24
"
Mean Data: Ifb 2 Sample
~ XT^ . IQ Autosampler Location: 25
fan^le ID^irb Date Collected: 11/15/2005 2:49:12 EM
-------
•Method: Air Filter Ni
Page
Date: 11/15/2005 3:07:01 PM
Data Type: Original
Analyst: Initial Sample Vol:
initial Sample Wt. Vol;
Dilution: -^ *^
Mean Data: Irb Calib Sample
ar._-i,rj-e Intensity Cone. Units "„," 0.46%
•f"la~1-J _ „„-,„„,,-, n a C.K TV,rr/T. 0.044 , „„„
0.0011 -0.001 mg/L 0.0011 76.99%
Autosampler Location: 26
Sequence No : 20 Collected: 11/15/2005 2:53:04 PM
Sample ID: 110200-1 ^^ ^^ Original
Analyst: Initial Sample Vol:
initial Sample Wt. Sample Prep Vol:
Dilution: v
Mean Data: 110200-1 Calib Sample
analtH-e Intensity Cone. Units t> ' „ ' 0 20%
Y - ° °" -/T- °-°2° mg/1 0.0022 1.07%
^3:: = :===:==: = = ======= —= = = = —
-Autosampler Location: 27
Sequence No : 21 Date Collected: n/15/2005 2:56:25 PM
ID: J.XU3 Autosampler Location: 29
"* /\ ^ ^ftrfO Date Collected." 11/15/2005 3:0 j * jy HM
Data Type i Or/ic/inal
Mean Data: ccv e-r5« I'OC __,,^ Sample
0
0.0058 0
_Autosampler Location: 30
Sequence No..24 Collected: 11/15/2005 3:07:01 PM
Sample ID: cob
-------
Method: Air Filter Ni
Page
Data Type: Original
Date: 11/15/2005 3:24:30 PM
Mean Data: cob Corrected calib
^yte intensity Cone Units Std Dev. Cone. Umts Std.Dev.
S 23i:9604t 215°°°2:6 0^000 SL O.°o5°05 0.000 mg/L 0.0005
\J ______________ =====
Autosaitpler Location: 31
• =.« 15'2005 3:10!54 M
Mean Data: 110200-4 Samcle
S-
A
oc Autosairajler Location: 32
f iio200-5 Data Collected: 11/15/2005 3:14:17
Aalvst- Data Type: Orl^nal
Analyst. Initial Sample Vol:
S^e Prep Vol:
Mean Data: 110200-5 Sample
««•
0.042 TOft 0.0022
„ OT Autosanipler Location: 33
Sequence No. ^2^^ Date ^lected: 11/15/2005 3:17:41 PM
sanp . Data Type: Original
SiSalWeWt: Initial Sa^le Vol :
Dilution: SainPle Prep Vo1'
Mean Data: 110200-6 Saraole
conc.SSS .««,. o^-uSS. .«.»-.
»•«« •>•
Autosanpler Location: 34
°ate Collected: 11/15/2005 3:21:06 PM
Data Type: O^Q111*1
Wt: Initial Sa^le Vol :
Dilution: Sal^le PreP Vol:
Mean Data: 110200-7 Saraole
.«.»-. „-
./' »••»» »•«•
M . ,Q Autosaitpler Location: 35
T iioSo-8 °a^ Collected: 11/15/2005 3:24:30 PM
-------
paCT_ 7 Date: 11/15/2005 3:41:49 PM
Method: Air Filter Ni . f2S2 L '
Data Type: Original
Analyst: Initial Sample Vol:
Initial Sample Wt: Prep Vol:
Dilution: ^
Mean Data: 110200-8 Sample
^^ -iSS?1 c»0.SSS 3t*D.v. —.-if .«.»». »,
£^:t3o2, 213MS:2 o"o^S O.K »-™2»>"-
====r7~ Autosampler Location: 36
Sequence No : 30 Dafce Collected: n/15/2005 3:28:25 PM
Sample ID: 110200-9 Data ^^ original
Ana^3^= a ™i ~ w - initial Sample Vol:
initial Sample Wt. Vol.
Dilution: *^
Mean Data: 110200-9 Sample
^yle -££5?* —-SS .«.«. —.-if — ».
SlSiSJt uS3e!!:l S:'n5A S:SS ,.*** ».»« ..™.
==~_- Autosampler Location: 37
Sequence No : 31 ^ Date Collected: n/15/2005 3:31:51 PM
Sample ID: 110200-10 ( 1 ^^ Original
Iaa1^'- . _ V initial Sample Vol:
initial Sample Wt: Q San5,le Prep Vol:
Dilution: v
Mean Data: 110200-10 ,,// . \ s le
M,lyt« -iSsT1//=-».£«» -^j- c-^" Std-D'v- osss
SS',:S2t 2°"!S:i V o^SiiSSy o.S;0^ .....«« ».™» »•»•
=====77Autosampler Location: 38
Sequence No.: 32 Collected: 11/15/2005 3:35:17 PM
Sample ID: ocv*- O, .O^ Data Originai
^Y5*' . w. initial Sample Vol:
initial Sample Wt. Vol.
Dilution: . ^i / *" ^
Mean Data: ccv *• &'^ ^ Sample
^^ ""^SLTtT —-t" «**j- =—" SM-D- o!S.
Sy;:S;i, ""S:1. o"iS3S o.SiS ...«^,/L o.»o» "•«•
~ -., Autosampler Location: 39
Sequence No.: 33 Dafce Collected: n/15/2005 3:38:43 PM
Sample ID: ecb Dafca Type. Or±ginal
I^:, m, w. Initial Sample Vol:
initial Sample Wt. y Vol;
Dilution: co\V v
Mean Data: ccb Sample
^yt. "^SS?* =~.SS SM.r. <»-.-«. -••«• 0^%
Sf3?:"« 215456?:? »"™S/' o.SiS! O.»OO«/L o.oo051S6.4«
-------
PROJECT # 020072: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 02/06/06
BY ICP ON 02/09/06
IDL = 0.004
LOD = 0.008
MDL • 0.007
LOQ • 0.017
RL • 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
020072-1
020072-2
020072-3
020072-4
020072-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
2.16
J3.002
0.209
0.036
2.310
0.149
FURTHER'6AL'eUlATIONSl IF A':
is L;i#EN O:OMJSI§SED.'
-------
r "horatorv Work Order Report
LIMSNo ' 2006020072 Date Rec'd 02/03/2006 03:58:26 Date Due 02/03/2006 12:00:00 AM
Project Code .NULL Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLIN AVE.
CHICAGO IL 60623
Phone
Matrix
254-2406
Engineering
Fax 254-6661
PoNo. ;Qr
Contact MR. FRANK ALTMAYER
e-mail
Client Notes: -o-
Order Comments: .NULL.
.NULL.
Sample No. Comments
OSHA-ID-121
1 02/01/2006
2 02/01/2006
Test Code Description
ABQC-02/01/06-BLANK
3 02/01/2006
4 02/02/2006
5 02/02/2006
Nl NICKEL
ABQC - 02/01/06 - COND#10 - EAST
SERIAL #25082359
Nl NICKEL
ABQC - 02/01/06 - COND#10 - WEST
SERIAL #25093158
Nl NICKEL
ABQC - 02/02/06 - COND#13 - EAST
SERIAL #25082349
Nl NICKEL
ABQC - 02/02/06 - COND#13 - WEST
SERIAL #25082370
Nl NICKEL
Quoted Price: .NULL.
Date Received
Result
02/03/2006 03:00:00 PM
02/03/2006 03:00:00 PM
02/03/2006 03:00:00 PM
02/03/2006 03:00:00 PM
02/03/2006 03:00:00 PM
Page 1
-------
Prep MetflOd: (check only one per page) -
Set*
1CP/FLAA: SM 3030 F, EPA 200.7 '82
ICPJ'FLAA: EPA 200's, SW-846 3010A
ICPyFLAA: EPA 200-7 r4.4
iCP/FLM: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER:
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER: -
MATRIX:
DRINKING WATER
{check only one per page)
AQUEOUS
OTHER:
1
2
3
4
5
6
7
8
9
10
11
12
Set
Inif
l^L
Set
date
^
' ~
Set
time
f
Lab#
02f>t>"l£
Smp#
i
^
^
-I
?c
Company
LFB
LRB
LFM DUP
LFM
,,
Aliquot
(mis)
fi^
Final
(mis)
•-..•••.•••V-.,V),--"-
I ajl c.vs '
W- ^4l£L?i
Mcr
Vslf
t-
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
rf»f
1
LOT#
£>SHnU'^
Analyst:
Start Date:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Sample Information Detail Report
Document Name: 020906-1
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
020906-1
ml
g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
Sample No Sample Prep. Vol.
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample ID
cri
icsab
ccv 0.50
ccb
Ifb
Irb
020072-1
020072-2
020072-3
020072-4
020072-5
ccv 1
ccb
Aliquot Volume
Initial Sample Wt.
Diluted To Vol.
-------
Method: Air Filter Ni
Page
Date: 2/9/2006 4:43:20 EM
Analysis Begun
Start Time: 2/9/2006 4:32:26 EM Elasma On Time: 2/9/2006 3:02:06 EM
Logged In Analyst: sammy Technique: ICE Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sample Information File: C:\pe\sammy\Sample Information\020906-l.sif
Batch ID: 020906-1
Results Data Set: 020906-1
Results Library: C:\pe\saimny\ResultsYResults.mdb
Method Loaded
Method Name: Air Filter Ni Method Last Saved: 10/5/2005 1:33:13 EM
IEC File: MSF File:
Method Description: AIR FILTER Ni
Sequence No.: 1 Autosampler Location: 0
Sample ID: Calib Blank 1 Date Collected: 2/9/2006 4:32:26 EM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Erep Vol:
Mean Data: Calib Blank 1
Mean Corrected Calib
Analyte Intensity Std.Dev. RSD Cone. Units
Yb 328.937 4114830.8 15776.58 0.38% 10.0 mg/L
Ni 231.604t -130.9 3.97 3.03% [0.00] mg/L
Sequence No.: 2 Autosampler Location: 1
Sample ID: Cal 21+7 1.00 Date Collected: 2/9/2006 4:36:07 EM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Erep Vol:
Mean Data: Cal 21+7 1.00
Mean Corrected Calib
Analyte Intensity Std.Dev. RSD Cone. Units
Yb 328.937 4095641.1 50232.78 1.23% 9.95 mg/L
Ni 231.604t 9671.8 108.72 1.12% [1.00] mg/L
Calibration Summary
Analyte Stds. Equation Intercept Slope Curvature Corr. Coef. Reslope
Ni 231.604 1 Lin Thru 0 0.0 9672 0.00000 1.000000
Sequence No.: 3 Autosampler Location: 9
Sample ID: cri Date Collected: 2/9/2006 4:39:27 EM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Erep Vol:
Mean Data: cri
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 4081070.0 9.92 mg/L 0.027 0.27%
Ni 231.604t 242.6 0.025 mg/L 0.0005 0.025 mg/L 0.0005 2.06%
Sequence No.: 4 Autosampler Location: 10
Sample ID: icsab Date Collected: 2/9/2006 4:43:20 EM
-------
Date: 2/9/2006 5:01:07 PM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: icsab
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 5
Sample ID: ccv 0 . 51
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccv 0.5i
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 6
Sample ID : ccb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccb
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 7
Sample ID: Ifb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: Ifb
Analyte
Yb 328.937
Ni 231.604t
Sequence No . : 8
Sample ID: Irb
Analyst:
Initial Sample Wt :
Dilution:
Mean Data: Irb
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
3855502.9
9704.0
D
D
Mean Corrected
Intensity
4097861.2
4766.0
Mean Corrected
Intensity
4079669.8
-5.4
Mean Corrected
Intensity
3773785.3
20877.5
Mean Corrected
Intensity
3846235.8
-21.5
Calib
Cone. Units
9.37 mg/L
1.00 mg/L
Calib
Cone. Units
9.96 mg/L
0.493 mg/L
Calib
Cone. Units
9.91 mg/L
-0.001 mg/L
Calib
Cone. Units
9.17 mg/L
2:16 mg/L
Calib
Cone. Units
9.35 mg/L
-0.002 mg/L
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.068
0.002 1.00 mg/L
Autosampler Location: 11
Date Collected: 2/9/2006 4:46:40
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.064
0.0015 0.493 mg/L
Autosampler Location: 12
Date Collected: 2/9/2006 4:50:01
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.046
0.0006 -0.001 mg/L
Autosampler Location: 13
Date Collected: 2/9/2006 4:53:53
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units
0.046
0.012 2.16 mg/L
Autosampler Location: 14
Date Collected: 2/9/2006 4:57:15
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.147
0.0007 -0.002 mg/L
Std.Dev. RSD
0.73%
0.002 0.20%
PM
Std.Dev. RSD
0.65%
0.0015 0.30%
PM
Std.Dev. RSD
0.47%
0.0006 114.59%
PM
Std.Dev. RSD
0.50%
0.012 0.58%
PM
Std.Dev. RSD
1.57%
0.0007 31.72%
Sequence No. : 9
Sample ID: 020072-1
Autosampler Location: 15
Date Collected: 2/9/2006 5:01:07 PM
-------
Air Filter Ni
Page
Date: 2/9/2006 5:19:38 PM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 020072-1
Mean Corrected
Analyte Intensity
Yb 328.937 3834509.7
Ni 231.604t 16.0
Sequence No . : 10
Sample ID: 020072-2
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 020072-2
Mean Corrected
Analyte Intensity
Yb 328.937 3817011.8
Ni 231.604t 2026.2
Sequence No . : 11
Sample ID: 020072-3
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 020072-3
Mean Corrected
Analyte Intensity
Yb 328.937 3873178.7
.Ji 231.604t 347.7
Sequence No. : 12
Sample ID: 020072-4
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 020072-4
Mean Corrected
Analyte Intensity
Yb 328.937 4118867.8
Ni 231.604t 22338.0
Sequence No. : 13
Sample ID: 020072-5
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 020072-5
Mean Corrected
Analyte Intensity
Yb 328.937 3793834.3
Ni 231.604t 1445.2
Cone.
9.32
0.002
Cone.
9.28
0.209
Cone.
9.41
0.036
Cone.
10.0
2.31
Cone.
9.22
0.149
Calib
Units
mg/L
mg/L
Calib
Units
mg/L
mg/L
Calib
Units
mg/L
mg/L
Calib
Units
mg/L
mg/L
Calib
Units
mg/L
mg/L
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.084
0.0008 0.002 mg/L 0.0008
Autosampler Location: 16
Date Collected: 2/9/2006 5:05:00 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev.
0.085
0.0038 0.209 mg/L 0.0038
Autosampler Location: 17
Date Collected: 2/9/2006 5:08:24 PM
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.075
0.0005 0.036 mg/L 0.0005
Autosampler Location: 18
Date Collected: 2/9/2006 5:12:17 PM
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.07
0.033 2.31 mg/L 0.033
Autosampler Location: 19
Date Collected: 2/9/2006 5:15:44 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev.
0.137
0.0016 0.149 mg/L 0.0016
RSD
0.90%
50.28%
RSD
0.91%
1.80%
RSD
0.80%
1.47%
RSD
0.67%
1.44%
RSD
1.49%
1.07%
Sequence No.: 14
iample ID: ccv 1
Autosampler Location: 20
Date Collected: 2/9/2006 5:19:38 PM
-------
Date: 2/9/2006 5:26:11 PM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccv 1
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 15
Sample ID : ccb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccb
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
4126299.4
9429.0
Mean Corrected
Intensity
4027115.6
-13.0
Calib
Cone. Units
10 . 0 mg/L
0.975 mg/L
Calib
Cone. Units
9.79 mg/L
-0.001 mg/L
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Std.Dev. Cone.
0.07
0.0089 0.975
Autosarapler Location: 21
Date Collected: 2/9/2006
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Std.Dev. Cone.
0.057
0.0002 -0.001
Sample
Units Std.Dev.
mg/L 0.0089
5:23:04 PM
Sample
Units Std.Dev.
mg/L 0.0002
RSD
0.68%
0.92%
RSD
0.58%
11.76%
-------
PROJECT # 010218: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES IDL = 0.004
Digestion on 01/24/06
BY ICP ON 01/27/06
LOD =
MDL =
0.008
0.007
LOQ = 0.017
RL = 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
010218-1
010218-2
010218-3
010218-4
010218-5
Dilution
25
25
25
25
25
25
25
Reading
-0.001
1.98
2.16
0.238
/j>>AQ01% s
0.622
0.087
-------
'boratory Work Order Report
LIWU'lNo. : 2006010218 Date Rec'd 01/13/2006 03:01:36 Date Due 01/13/2006 12:00:00 AM
Project Code .NULL. Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLINAVE.
CHICAGO IL 60623
Phone
Matrix
254-2406
Engineering
Fax 254-6661
Po No. zQr
Contact MR. FRANK ALTMAYER
e-mail
Quoted Price:
.NULL
Client Notes: -o-
Order Comments: NULL
.NULL.
Sample No. Comments
ABQC
° "7
Test Code Description
1 01/11/2006 01/11/06 CONDITION #12 EAST-
SERIAL #25093149
Nl NICKEL
2 01/11/2006 01/11/06 CONDITION #12 WEST-
SERIAL #25093112
Nl NICKEL
3 01/11/2006 01/11/06 BLANK
SERIAL #25093138
Nl NICKEL
4 01/11/2006 01/11/06 CONDITION #11 EAST-
SERIAL #25093115
Nl NICKEL
5 01/11/2006 01/11/06 CONDITION #11 WEST-
SERIAL #25093146
Nl NICKEL
Date Received
Result
01/13/2006 01:30:OOPM
01/13/2006 01:30:OOPM
01/13/2006 01:30:OOPM
01/13/2006 01:30:00 PM
01/13/2006 01:30:OOPM
Page 1
-------
METALS PREP FORM
Prep Method.' (check only one per page)
Set*
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLM: EPA 200's, SW-846 301OA
ICP/FLM: EPA 200.7 r4.4
ICP/FLM: SW-846 3005A
ICP/FLM:" SW-846 3015A MICROWAVE
OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
iFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:
MATRIX: (check only one per page)
DRINKING WATER
OTHER:
S\QA FORMS \FM-041 \R02 \LK
Page 1 of 1
-------
Sample Information Detail Report
Document Name: 012706-1
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
012706-1
ml
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sample Prep. Vol.
Sample ID
cri
icb
icv
icsab
Ifb
Irb
010302-1
010302-2
010302-3
01 021 8-1 '
010218-2
010218-3
010218-4
010218-5
ccb
Aliquot Volume
Initial Sample Wt.
Diluted To Vol.
-------
Method: Pt-MnBEC
Page
Date: 1/27/2006 2:39:10 PM
Analysis Begun
dtart Time: 1/27/2006 2:28:40 PM Plasma On Time: 1/27/2006 2:02:19 PM
Logged In Analyst: sammy Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sample Information File:
Batch ID:
Results Data Set:
Results Library:
Method Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
Method Last Saved: 11/29/2005 2:09:00 PM
MSF File:
Sequence No.: 1
Sample ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 1/27/2006 2:28:40 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: Calib Blank 1
Net Corrected
Repl# Analyte Intensity Intensity
1 Mn 257.610 2926.8 2926.8
1 cu 324.752 9474.4 9474.4
2 Mn 257.610 2799.0 2799.0
2 Cu 324.752 9431.8 9431.8
3 Mn 257 610 2789.6 2789.6
3 Cu 324.752 9436.9 9436.9
Mean Data: Calib Blank 1
Mean Corrected
Analyte Intensity Std.Dev. RSD
Mn 257.610 2838.5 76.62 2.70%
Cu 324.752 9447.7 23.26 0.25%
Calib. Analysis
Cone. Units Time
[0.00] mg/L 14:30:06
[0.00] mg/L 14:30:06
[0.00] mg/L 14:30:16
[0.00] mg/L 14:30:16
[0.00] mg/L 14:30:26
[0.00] mg/L 14:30:26
Calib
Cone. Units
[0.00] mg/L
[0.00] mg/L
Sequence No.: 2
Sample ID: Calb Stdl
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 1/27/2006 2:31:19 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data:
Repl# Analyte
1 Mn 257.
1
2
2
3
3
Cu
Mn
Cu
Mn
Cu
324.
257.
324.
257.
324.
610
752
610
752
610
752
Mean Data: Calb
Analyte
An 257.610
Calb Stdl
Net
Intensity
1868576.8
494782.4
1874239.8
496392.3
1862604.1
492560.1
Stdl
Mean Corrected
Intensity
1865635.1
Corrected
Intensity
1865738.3
485334
1871401
486944
1859765
483112
Std.Dev.
5818.57
.7
.4
.6
.6
.4
RSD
0.31%
Cone.
[5.00]
[5
[5
[5
[5
[5
.00]
.00]
.00]
.00]
.00]
Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/1
Calib
Analysis
Time
14:32:31
14:32:31
14:32:44
14:32:44
14:32:57
14:32:57
Cone. Units
[5.00] mg/L
-------
Method: Pt-MnBEC
Cu 324.752
Calibration
Analyte
Mn 257.610
Cu 324.752
Summary
Stds.
1
1
485130.6
Equation
Lin Thru 0
Lin Thru 0
Page
1924.25 0.40%
Intercept
0.0
0.0
2
[5,
Slope
373100
97030
Date: 1/27/2006 2:J»:±u JtM
.00] mg/L
Curvature Corr. Coef. Reslope
0.00000 1.000000
0.00000 1.000000
=========— ============= '
Sequence No.: 3
Sample ID: bee
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 1/27/2006 2:33:19 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: bee
Repl# Analyte
1 Mn 257.610
1 Cu 324.752
2 Mn 257.610
2 Cu 324.752
3 Mn 257.610
3 Cu 324.752
Mean Data: bee
Analyte
Mn 257.610
Cu 324.752
Net
Intensity
0.3
1.2
0.2
0.1
-0.8
0.1
Mean Corrected
Intensity
-2838.6
-9447.2
. — ;———=====
Corrected
Intensity
-2838.2
-9446.5
-2838.3
-9447.6
-2839.3
-9447.6
Calib
Cone . Units
-0.008 mg/L
-0.097 mg/L
Calib .
Cone. Units
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
Std.Dev. Cone.
0.0000 -0.008
0.0000 -0.097
Sample
Cone. Units
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
Sample
Units Std
mg/L 0 .
mg/L 0 .
Analysis
Time
14:34:18
14:34:18
14:34:38
14:34:38
14:34:58
14:34:58
.Dev. RSD
0000 0.02%
0000 0.01%
.•fethod Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
Method Last Saved: 11/29/2005 2:09:00 PM
MSF File:
Sequence No.: 4
Sample ID: cv
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 1/27/2006 2:35:25 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: cv
Replf
1
1
2
2
3
3
4
4
5
5
6
6
7
7
8
8
Analyte
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257. 610
Cu 324.752
Net
Intensity
1873085.6
496646.8
1867976.6
494873.3
1863508.5
493612.2
1864524.6
493197.1
1858358.5
492295.2
1877872.2
497735.9
1870403.1
495019.6
1871306.3
496395.8
Corrected
Intensity
1870247.1
487199.1
1865138.1
485425.6
1860670.1
484164.5
1861686.1
483749.4
1855520.0
482847.6
1875033.7
488288.2
1867564.7
485571.9
1868467.8
486948.1
Calib .
Cone. Units
5.01 mg/L
5.02 mg/L
5.00 mg/L
5.00 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.97 mg/L
4.98 mg/L
5.03 mg/L
5.03 mg/L
5.01 mg/L
5.00 mg/L
5.01 mg/L
5.02 mg/L
Sample
Cone. Units
5.01 mg/L
5.02 mg/L
5.00 mg/L
5.00 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.97 mg/L
4.98 mg/L
5.03 mg/L
5.03 mg/L
5.01 mg/L
5.00 mg/L
5.01 mg/L
5.02 mg/L
Analysis
Time
14:36:37
14:36:37
14:36:50
14:36:50
14:37: 03
14:37:03
14:37:16
14:37: 16
14: 37:29
14:37:29
14:37:42
14:37:42
14:37:55
14:37:55
14:38:07
14:38 : 07
-------
Date: 1/27/2006 2:39:10 EM
Metnoa: ±-T:-M
9 Mn 257
9 Cu 324
10 Mn 257
10 Cu 324
.610
.752
.610
.752
1873916.8
497158.3
1872973.8
496581.7
1871078.4
487710.6
1870135.3
487134.0
5
5
5
5
.01 mg/L
.03 mg/L
.01 mg/L
.02 mg/L
Mean Data: cv
Analyte
Mn 257.610
Cu 324.752
Mean Corrected
Intensity
1866554.1
485903.9
Calib
Cone . Units
5.00 mg/L
5.01 mg/L
5.
5.
5.
5.
01
03
01
02
mg/L
mg/L
mg/L
mg/L
14
14
14
14
:38
:38
: Jb
:38
:20
:20
:33
:33
Sample
Std
0
0
.Dev.
.016
.019
Cone. Units
5.00 mg/L
5.01 mg/L
Std
0
0
.Dev.
.016
.019
RSD
0.31%
0.38%
-------
Method: NEW Al ROUTINE
Page 1
Date: 1/27/2006 2:50:42 EM
Analysis Begun
Jtart Time: 1/27/2006 2:46:25 EM Elasnia On Time: 1/27/2006 2:02:19 EM
Logged In Analyst: sammy Technique: ICE Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sanple Information File: C:\pe\sammy\Sample Information\012706-l.sif
Batch ID: 012706-1
Results Data Set: 012706-1
Results Library: C:\pe\sammy\Results\Results.mdb
Method Loaded
Method Name: NEW Al ROUTINE
IEC File: iec l.iec
Method Description: NEW Al ROUTINE
Sequence No. : 1
Sanple ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
Method Last Saved: 1/24/2006 10:55:40 AM
MSF File:
Autosampler Location: 0
Date Collected: 1/27/2006 2:46:25 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: Calib Blank 1
Mean Corrected
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Atit
>bt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mat
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Intensity
4117890.7
256
-73
63
4642
548
-65
-8
-70
1756
10
123
-174
-122
429
10364
-4
2907
2765
4195
134
277
394
18928
16
40
7
157
-10
1428
2921
2
-1615
10
-4
249
.5
.2
.9
.6
.4
.7
.6
.6
.5
.2
.1
.8
.2
.6
.6
.1
.0
.5
.9
.1
.6
.1
.2
.7
.3
.9
.4
.0
.1
.4
.9
.5
.2
.6
.5
Std.Dev.
27189.58
19
9
6
27
27
4
3
2
24
5
6
9
87
5
41
6
37
25
176
10
26
18
81
1
1
1
9
4
651
214
3
16
5
7
45
.65
.40
.58
.57
.19
.43
.22
.15
.00
.93
.84
.61
.84
.01
.92
.49
.66
.67
.09
.54
.22
.57
.30
.82
.75
.78
.00
.25
.59
.16
.78
.04
.93
.90
.56
RSD
0.66%
7
12
10
0
4
6
37
3
1
58
5
5
71
1
0
158
1
0
4
7
9
4
0
10
4
22
5
42
45
7
129
0
58
172
18
.66%
.85%
.30%
.59%
.96%
.73%
.39%
.05%
.37%
.24%
.56%
.50%
.91%
.17%
.40%
.89%
.30%
.93%
.20%
.86%
.44%
.71%
.43%
.85%
.34%
.54%
.72%
.57%
.63%
.33%
.71%
.99%
.24%
.06%
.26%
Cone.
10.00
[0
ro
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
LO
[0
[0
LO
[0
[0
[0
[0
[0
[0
[0
ro
[0
[0
[0
[0
[0
[0
[0
LO
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.UOJ
.00]
.00]
.00]
.OOJ
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Sequence No. : 2
Sample ID: CAL 21+7 1.00
Autosampler Location: 1
Date Collected: 1/27/2006 2:50:42 EM
-------
Method: NEW Al ROUTINE
Analyst:
Initial Sample Wt:
Dilution:
Date: 1/27/2006 3:03:29 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: CAL
Analyte
Yb
Agt
ft J +
CdT
crt
Ft
•VT-i 4-
NlT
Pbt
Znt
al +
f\j- 1
Ast
Bat
Bet
Ca 422.673t
K lOt
Lit
TUf_r +
Mgr
Mnt
Na 589.592t
o ra 4-
Set
Srt
Tit
rnl 4-
1 X 1
vt
As 193.696t
3e 196.026t
jfo 2 02. 03 It
21+7 1.00
Mean Corrected
Intensity
4046403.1
95041.2
40166.2
49380.5
106667.8
42506.0
9279.3
2736.1
16726.1
4728.1
367 . 8
38002.0
28299.1
1010496.8
268864.8
11407.1
715080.7
4208209.8
3897.5
198907.3
251031.5
490.7
353 .1
8487507.9
306680.8
203.0
78517.9
367.8
510.2
1948.8
Std.Dev.
19302.97
754.08
305.59
424.61
914.57
397.76
81.42
17.39
127.73
53.03
4.76
173.95
261.94
2177.09
1567.12
112.61
3900.11
48673.94
40.60
271.43
1113.18
47.51
16.13
67457.88
751.19
2.44
667.58
4.76
12.45
61.74
RSD
0.48%
0.79%
0.76%
0.86%
0.86%
0.94%
0.88%
0.64%
0.76%
1.12%
1.29%
0.46%
0.93%
0.22%
0.58%
0.99%
0.55%
1.16%
1.04%
0.14%
0.44%
9.68%
4.57%
0.79%
0.24%
1.20%
0.85%
1.29%
2.44%
3.17%
Calib
Cone. Units
9.83 mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[10.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
Sequence No.: 3
Sample ID: CAL MIX 2A
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 2
Date Collected: 1/27/2006 2:56:07 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: CAL MIX 2A
Mean Corrected
Analyte Intensity
Yb 4067094.8
Na 330.237t 2241.8
Na 589.592t 3034250.4
Std.Dev. RSD
35459.93 0.87%
44.33 1.98%
2758.62 0.09%
Calib
Cone. Units
9.88 mg/L
[10.00] mg/L
[10.00] mg/L
Sequence No.: 4
Sample ID: CAL MIX 3A
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 3
Date Collected: 1/27/2006 2:59:36 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data:
Analyte
Yb
Cot
Pt
CAL MIX 3A
Mean Corrected
Intensity
4147958.0
23079.7
2202.1
Std.Dev.
14777.51
44.33
4.06
RSD
0.36%
0.19%
0.18%
Calib
Cone. Units
10.1 mg/L
[2.00] mg/L
[10.00] mg/L
-------
Method: NEW Al ROUTINE
Page
Date: 1/27/2006 3:18:22 PM
Sequence No.: 5
Sample ID: CAL MIX 4A
Analyst:
Initial Sample Wt:
Jilution:
Autosampler Location: 4
Date Collected: 1/27/2006 3:03:29 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: CAL MIX 4A
Mean Corrected
Intensity
Analyte
Yb
Crt
Znt
Alt
Snt
4060531.2
259057.1
88216.4
49318.9
6487.2
Calib
Std.Dev. RSD Cone. Units
35403.43 0.87% 9.86 mg/L
638.80 0.25% [5.00] mg/L
161.26 0.18% [5.00] mg/L
834.86 1.69% [10.00] mg/L
95.49 1.47% [4.00] mg/L
Sequence No.: 6
Sample ID: CAL MIX 5A
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 5
Date Collected: 1/27/2006 3:07:04 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data:
Analyte
Yb
Fet
Nit
Pbt
Mgt
CAL MIX 5A
Mean Corrected
Intensity
4055412.3
427832
18761
27855
40359
.5
.0
.7
.3
Std.
30403
608
37
60
110
Dev.
.69
.40
.44
.95
.86
RSD
0.75%
0
0
0
0
.14%
.20%
.22%
.27%
Cone.
9.85
[10
[2
[10
[10
.00]
.00]
.00]
.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
Sequence No. : 7
Sample ID: CAL MIX 1A
Analyst:
.Initial Sample Wt:
Dilution:
Autosampler Location: 6
Date Collected: 1/27/2006 3:10:30 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: CAL MIX 1A
Analyte
Yb
Cdt
Cut
Bt
Bat
Ca 315.887t
Ca 422.673t
Mnt
Mean Corrected
Intensity
4012478.8
161962
432307
159042
57081
483590
5166298
825127
.3
.1
.5
.8
.2
.1
.9
Std.Dev.
29415.92
529
1619
333
147
1813
51964
5614
.89
.51
.28
.73
.89
.63
.58
RSD
0.73%
0
0
0
0
0
1
0
.33%
.37%
.21%
.26%
.38%
.01%
.68%
Cone.
9.74
[4
[4
[4
[2
[20
[20
[4
.00]
.00]
.00]
.00]
.00]
.00]
.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Sequence No. : 8
Sample ID: Ca+Na 50 ppm K 20ppm
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 7
Date Collected: 1/27/2006 3:14:46 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: Ca+Na 50 ppm K 20ppm
Analyte
Yb
Ca 315.887t
K 766.490 20t
Na 330.237t
Mean Corrected
Intensity
3966352.4
1199498.4
2047997.8
12293.0
Calib
Std.Dev. RSD Cone. Units
40190.91 1.01% 9.63 mg/L
2112.16 0.18% [50.00] mg/L
4664.99 0.23% [20.00] mg/L
166.10 1.35% [50.00] mg/L
-------
Method: NEW Al ROUTINE
Page
4
Date: 1/27/2006 3:25:55 EM
Sequence No.: 9
Sample ID: AsSbSeMo4ppmSi2ppm
Analyst:
Initial Sample Wt:
dilution:
Autosampler Location: 8
Date Collected: 1/27/2006 3:18:22 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: AsSbSeMo4ppmSi2ppm
Mean Corrected
Analyte
Yb
Ast
Sbt
Set
Sit
Tit
Mo 202.031t
Calibration
Analyte
Ag
Cd
Cr
Cu
Fe
Ni
Pb
Zn
Al
As
B
Ba
Be
Ca 315.887
"a 422.673
Jo
K 10
Summary
Stds.
1
2
2
2
2
2
2
2
2
2
2
2
1
2
2
2
1
K 766.490 20 1
Li
Mg
Mn
Na 330.237
Na 589.592
P
Sb
Se
Si
Sn
Sr
Ti
Tl
V
As 193.696
Se 196.026
Mo 202.031
1
2
2
2
2
1
2
2
1
1
1
1
2
1
1
1
2
Intensity
3967665.8
1560.2
2816.7
1506.2
22373.5
805.4
8421.5
Equation
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Std.Dev. RSD
6272.18 0.16%
26.48 1.70%
23.72 0.84%
44.21 2.94%
116.69 0.52%
8.13 1.01%
380.05 4.51%
Intercept
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Cone.
9.64
[4.00]
[4.00]
[4.00]
[2.00]
[4.00]
[4.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Slope Curvature
95040
40470
51720
108000
42780
9360
2785
17610
4930
388.7
39660
28490
1010000
24020
258300
11510
71510
102400
4208000
4035
205800
245.0
302900
220.2
691.6
375.2
11190
1622
8488000
306700
201.4
78520
367.8
510.2
2096
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
Corr. Coef. Reslope
1.000000
0.999998
0.999959
0.999995
1.000000
0.999991
0.999998
0.999950
0.999992
0.999909
0.999946
0.999994
1.000000
0.999996
0.999998
0.999989
1.000000
1.000000
1.000000
0.999994
0.999964
0.999855
0.999853
1.000000
0.997374
0.999892
1.000000
1.000000
1.000000
1.000000
0.999998
1.000000
1.000000
1.000000
0.999846
Sequence No.: 10
Sample ID: cri
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 9
Date Collected: 1/27/2006 3:22:21 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: cri
Analyte
Xb
Mean Corrected
Intensity
4006585.0
Calib
Cone . Units
9.73 mg/L
Std.Dev.
0.032
Sample
Cone. Units Std.Dev. RSD
0.33%
-------
Method: HEW Al ROUTINE
Agt
Cdt
Crt
"ut
Ff* +
Nit
PHt
Znt
Al t
Ast
Rt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
vt
As 193.696t
Se 196.026t
Mo 202.031t
2367.5
999.6
1200.6
2747.6
1117 6
226.9
50.7
478.1
560.2
36.5
4683.2
710.0
25176.9
2711.8
29300.0
279.5
16630.4
16116.6
86212.8
475.4
4929.6
40.0
54616.9
28.6
72.1
28.9
257.2
82.9
212445.7
7662.2
16.3
1884.4
36.5
44.4
139.1
Eage 5
0.025 mg/L
0.025 mg/L
0.023 mg/L
0.025 mg/L
^"0.024 mg/L ,S2-
0.027 mg/L
0.114 mg/L
0.094 mg/L
0.118 mg/L
0.025 mg/L
0.025 mg/L
0.113 mg/L
0.113 mg/L
0.024 mg/L
0.233 mg/L
0.157 mg/L
0.020 mg/L
0.118 mg/L
0.024 mg/L
0.163 mg/L
0.180 mg/L
0.130 mg/L
0.104 mg/L
0.077 mg/L
0.023 mg/L
0.051 mg/L
0.025 mg/L
0.025 mg/L
0.081 mg/L
0.024 mg/L
0.099 mg/L
0.087 mg/L
0.066 mg/L
0.0004
0.0001
0.0006
0.0008
/ 0.0012
^ 0.0005
0.0041
0.0002
0.0044
0.0198
0.0113
0.0002
0.0002
0.0005
0.0008
0.0003
0.0030
0.0021
0.0003
0.0009
0.0002
0.0103
0.0010
0.0085
0.0069
0.0041
0.0023
0.0015
0.0002
0.0016
0.0160
0.0003
0.0209
0.0042
0.0235
Date: 1/27/2006 3:30:24 EM
0.025 mg/L
0.025 mg/L
0.023 mg/L
0.025 mg/L
0.026 mg/L
0.024 mg/L
0.018 mg/L
0.027 mg/L
0.114 mg/L
0.094 mg/L
0.118 mg/L
0.025 mg/L
0.025 mg/L
0.113 mg/L
0.113 mg/L
0.024 mg/L
0.233 mg/L
0.157 mg/L
0.020 mg/L
0.118 mg/L
0.024 mg/L
0.163 mg/L
0.180 mg/L
0.130 mg/L
0.104 mg/L
0.077 mg/L
0.023 mg/L
0.051 mg/L
0.025 mg/L
0.025 mg/L
0.081 mg/L
0.024 mg/L
0.099 mg/L
0.087 mg/L
0.066 mg/L
0.0004
0.0001
0.0006
0.0008
0.0012
0.0005
0.0041
0.0002
0.0044
0.0198
0.0113
0.0002
0.0002
0.0005
0.0008
0.0003
0.0030
0.0021
0.0003
0.0009
0.0002
0.0103
0.0010
0.0085
0.0069
0.0041
0.0023
0.0015
0.0002
0. 0016
0.0160
0.0003
0.0209
0.0042
0.0235
1.46%
0.48%
2 . 48%
3.25%
4.73%
1.94%
22.55%
0.92%
3.91%
21.06%
9.58%
0.95%
0.89%
0 .40%
0.69%
1.19%
1.30%
1.34%
1.23%
0. 80%
0.73%
6.32%
0.57%
6.57%
6.63%
5.28%
10.10%
2.95%
0. 60%
6. 31%
19.75%
1.34%
21.06%
4.87%
35.42%
Sequence No.: 11
Sample ID: icb
Analyst:
Initial Sample Wt:
Dilution:
Autosanpler Location: 10
Date Collected: 1/27/2006 3:26:53 EM
Data Type: Original
Initial Sanple Vol:
Sample Erep Vol:
Mean Data: icb
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Ja 330.237t
Mean Corrected
Intensity Cone .
3974270
10
-16
-6
231
-61
-15
-3
4
-113
-9
1845
„ n
-229
-290
-3733
-3
-17
-30
-1619
-19
-130
-9
.8
.1
.3
.5
.6
•6
9.65
0.000
0.000
0.000
0.002
-0.001
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
. 8 X-"0 . 0 02"mcf/L
.1
.6
.5
.8
.6
.7
.8
.9
.9
.8
.9
.0
.6
.1
.4
.1
^i=g-re-ei"^
0.000
-0.023
-0.025
0.047
0.000
0.000
-0.012
-0.014
0.000
0.000
0.000
0.000
-0.005
-0.001
-0.037
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.055
.0006
.0002
.0002
.0005
.0002
.0007
.0013
.0000
.0035
.0012
.0049
.0000
.0000
.0003
.0001
.0004
.0004
.0001
.0000
.0039
.0000
.0333
Cone.
0.000
0.000
0.000
0.002
-0.001
-0.002
-0.001
0.000
-0.023
-0.025
0.047
0.000
0.000
-0.012
-0.014
0.000
0.000
0.000
0.000
-0.005
-0.001
-0.037
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0006
.0002
.0002
.0005
.0002
.0007
.0013
.0000
.0035
.0012
.0049
.0000
.0000
.0003
.0001
.0004
.0004
.0001
.0000
.0039
.0000
.0333
RSD
0.57%
545.83%
46.08%
177 .02%
23.44%
13.68%
38.97%
121.27%
9.17%
15.23%
4. 62%
10.56%
8.72%
18.10%
2.82%
0. 98%
121.79%
142.86%
31.17%
7.93%
83.41%
7.13%
89.40%
-------
Method: NEW Al ROUTINE
Na 589.592t
Pt
sbt
Set
Jit
q-n-f
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
634.
— 1
16.
-14.
12.
-1.
-2473.
-1562.
-1.
-48.
-9.
-17.
-167.
9
8
1
2
2
7
5
0
0
4
8
6
6
0.002
-0.008
0.023
-0.038
0.001
-0.001
0.000
-0.005
-0.005
-0.001
-0.027
-0.035
-0.080
Page 6
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0
0
0
0
0
0
0
0
0
0
0
.0008
.0024
.0025
.0208
.0008
.0041
.0000
.0001
.0073
.0003
.0012
.0113
.0035
0
-0
0
-0
0
-0
0
-0
-0
-0
-0
-0
-0
.002
.008
.023
.038
.001
.001
.000
.005
.005
.001
.027
.035
.080
Date: 1/27/2006 3:
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.0008
0.0024
0.0025
0.0208
0.0008
0.0041
0.0000
0.0001
0.0073
0.0003
0.0012
0.0113
0.0035
41:25 EM
39.05%
30.24%
10.63%
55.14%
73.54%
405.87%
5.00%
2.33%
155.12%
51.67%
4.62%
32.81%
4.39%
Sequence No.: 12
Sample ID: icv
Analyst:
Initial Sample Wt:
Dilution:
Autosampler location: 11
Date Collected: 1/27/2006 3:31:22 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: icv
Analyte
Yb
Agt
Cdt
Crt
Cut
Nit
DV\t
rDT
Znt
Alt
qx
Bat
Bet
Ca 315.887t
Ca 422.673t
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
t i
Sbt
Set
Sit
Snt
Srt
Tit
Tl t
-i- -L 1
vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity
3968670.3
46370.3
19458.3
23894.8
51634.5
22145.2
4549.4
1319.2
8262.2
13555.6
168.8
19392 .1
13804.8
505254.6
74714.7
855588.5
5535.6
356006.0
345117.4
1974038.9
11922.6
98678.0
284.5
820990.8
231.8
244.1
164.1
3140.0
1656.5
4164500.8
147722.7
93.9
38170.4
168.8
238.5
732.4
L Calib
Cone . Units
9.64 mg/L
0.488 mg/L
0.481 mg/L
0.462 mg/L
0.478 mg/L
0.518_mg/L
<;:;;"67486 mg/i 0,-
0.469 mg/L
2.75 mg/L
0.434 mg/L
0.489 mg/L
0.485 mg/L
0.500 mg/L
3.11 mg/L
3.31 mg/L
0.481 mg/L
4.98 mg/L
3.370 mg/L
0.469 mg/L
2.96 mg/L
0.479 mg/L
1.16 mg/L
2.71 mg/L
1.05 mg/L
0.353 mg/L
0.437 mg/L
0.281 mg/L
1.02 mg/L
0.491 mg/L
0.482 mg/L
0.466 mg/L
0.486 mg/L
0.459 mg/L
0.467 mg/L
0.349 mg/L
Std.Dev.
0.037
0.0046
0.0048
0.0051
0.0061
^ 0.0052
> 0.0022
0.0032
0.0048
0.037
0.0030
0.0057
0.0051
0.0008
0.032
0.012
0.0021
0.012
0.0080
0.0007
0.036
0.0050
0.047
0.007
0.031
0.0082
0.0276
0.0015
0.007
0.0008
0.0038
0.0174
0.0044
0.0032
0.0220
0.0261
Sample
Cone. Units
0.488 mg/L
0.481 mg/L
0.462 mg/L
0.478 mg/L
0.518 mg/L
0.486 mg/L
0.474 mg/L
0.469 mg/L
2.75 mg/L
0.434 mg/L
0.489 mg/L
0.485 mg/L
0.500 mg/L
3.11 mg/L
3.31 mg/L
0.481 mg/L
4.98 mg/L
3.370 mg/L
0.469 mg/L
2.96 mg/L
0.479 mg/L
1.16 mg/L
2.71 mg/L
1.05 mg/L
0.353 mg/L
0.437 mg/L
0.281 mg/L
1.02 mg/L
0.491 mg/L
0.482 mg/L
0.466 mg/L
0.486 mg/L
0.459 mg/L
0.467 mg/L
0.349 mg/L
Std.Dev.
0.0046
0.0048
0.0051
0.0061
0.0052
0.0022
0.0032
0.0048
0.037
0.0030
0.0057
0.0051
0.0008
0.032
0.012
0.0021
0.012
0.0080
0.0007
0.036
0.0050
0.047
0.007
0.031
0.0082
0.0276
0.0015
0.007
0.0008
0.0038
0.0174
0.0044
0.0032
0.0220
0.0261
RSD
0.39%
0.95%
0.99%
1.11%
1.27%
1.01%
0.46%
0.68%
1.01%
1.35%
0. 69%
1.16%
1.05%
0.16%
1.04%
0.36%
0.43%
0.24%
0.24%
0.16%
1.22%
1.04%
4.04%
0.27%
2.99%
2.32%
6.30%
0.52%
0. 69%
0.17%
0.78%
3.72%
0.91%
0.69%
4.71%
7.46%
Sequence No.: 13
Sample ID: icsab
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 12
Date Collected: 1/27/2006 3:36:13 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
-------
Method: NEW Al ROUTINE
Mean Data: icsab
Analyte
Yb
-gt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Ma 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
\s 193.696t
je 196.026t
Mo 202.031t
Sequence No.: 14
Sanple ID: Ifb
Analyst:
Initial Sanple Wt:
Dilution:
Date: 1/27/2006 3:47:22 EM
Mean Corrected
Intensity
3792405.4
96283.5
39115.5
47954.0
108463.4
7678013.6
9040.4
2656 7
17956.2
238317.6
362 .0
69836.6
26896.7
1019583.2
5492568.1
Saturated2
10788.5
1193681.7
1158775.9
5864783.1
478370.2
195541.6
8859.1
Saturated2
469.7
660.5
333.1
5938 .7
3261.0
8407451.4
360682.8
198.5
76386.6
362 0
470.3
1962.3
Calib
Cone. Units
9.21 mg/L
1.01 mg/L
0.966 mg/L
0.927 mg/L
1.00 mg/L
179 mg/L I Q
<-:0-."9"6~6 mgYjJ ''
1.02 mg/L
48.3 mg/L
0.931 mg/L
1.76 mg/L
0.944 mg/L
1.01 mg/L
229 mg/L
0.937 mg/L
16.7 mg/L
11.32 mg/L
1.39 mg/L
119 mg/L
0.950 mg/L
36.2 mg/L
2.13 mg/L
0.955 mg/L
0.888 mg/L
0.531 mg/L
2.01 mg/L
0.991 mg/L
1.18 mg/L
0.985 mg/L
0.973 mg/L
0.984 mg/L
0.922 mg/L
0.936 mg/L
Std.Dev.
0.020
0.006
0.0060
0.0047
0.005
1.9
0.0090
0.0123
0.003
0.29
0.0107
0.017
0.0045
0.000
2.6
0.0074
0.03
0.022
0.019
0.0
0.0055
0.17
0.050
0.0043
0.0212
0.0065
0.021
0.0030
0.008
0.0415
0.0053
0.0113
0.0352
0.0396
Sample
Cone. Units
1.01 mg/L
0.966 mg/L
0.927 mg/L
1.00 mg/L
179 mg/L
0. 966 mg/L
0.954 mg/L
1.02 mg/L
48.3 mg/L
0.931 mg/L
1.76 mg/L
0.944 mg/L
1.01 mg/L
229 mg/L
0.937 mg/L
16.7 mg/L
11.32 mg/L
1.39 mg/L
119 mg/L
0.950 mg/L
36.2 mg/L
2.13 mg/L
0.955 mg/L
0.888 mg/L
0.531 mg/L
2.01 mg/L
0.991 mg/L
1.18 mg/L
0.985 mg/L
0.973 mg/L
0.984 mg/L
0.922 mg/L
0.936 mg/L
Std.Dev.
0.006
0.0060
0.0047
0.005
1.9
0.0090
0.0123
0.003
0.29
0.0107
0.017
0.0045
0.000
2.6
0.0074
0.03
0.022
0.019
0.0
0.0055
0.17
0.050
0.0043
0.0212
0.0065
0.021
0.0030
0 . 008
0.0415
0.0053
0.0113
0.0352
0.0396
RSD
0 22%
0.61%
0.63%
0.51%
0.52%
1.09%
0.93%
1.29%
0.30%
0.61%
1.14%
0.98%
0.47%
0.03%
1.13%
0.79%
0.20%
0.19%
1.35%
0.03%
0.58%
0.47%
2.34%
0.45%
2.39%
1.23%
1.03%
0.30%
. 60%
4.21%
0.55%
1.14%
3.82%
4.23%
Autosainpler Location: 13
Date Collected: 1/27/2006 3:42:24 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: Ifb
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Ni f
iM-L 1
Pbt
Znt
Alt
Ast
Rt
£3 j
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
\ 766.490 20t
Mean Corrected
Intensity
3691064.0
-122.1
76124.4
98518.2
215406.0
86747.5
18525.0
5369.7
31608.0
207.9
698.4
2361.7
-33.5
1968453.9
50567.5
528805.5
22535.1
1019.0
809.2
Calib
Cone. Units
8 .96 mg/L
-0.001 mg/L
1.88 mg/L
1.90 mg/L
1.99 mg/L
2 . 03 mg/L
«~— ~~rT98 mg-'/'L 'i •-
C — ^TTSSnig/L
1.80 mg/L
0.042 mg/L
1.80 mg/L
0.060 mg/L
-0.001 mg/L
1.95 mg/L
2.11 mg/L
2.05 mg/L
1.96 mg/L
0.014 mg/L
0.008 mg/L
Std.Dev.
0.154
0.0006
0.018
0.016
0.005
0.035
0.016
0.013
0.015
0.0121
0.020
0.0143
0.0005
0.005
0.027
0.022
0.017
0.0018
0.0013
Sample
Cone. Units
-0.001 mg/L
1.88 mg/L
1.90 mg/L
1.99 mg/L
2.03 mg/L
1.98 mg/L
1.93 mg/L
1.80 mg/L
0.042 mg/L
1.80 mg/L
0.060 mg/L
-0 .001 mg/L
1.95 mg/L
2.11 mg/L
2.05 mg/L
1.96 mg/L
0.014 mg/L
0.008 mg/L
Std.Dev.
0.0006
0.018
0.016
0.005
0.035
0 .016
0.013
0.015
0.0121
0.020
0.0143
0.0005
0.005
0.027
0.022
0.017
0.0018
0.0013
RSD
1.72%
43.49%
0.95%
0.83%
0.27%
1.72%
0 . 80%
0.69%
0.82%
28.77%
1.11%
23.98%
41.64%
0.24%
1.26%
1.07%
0.87%
12.32%
16.35%
-------
Method: NEW Al I
Lit
Mgt
Mnt
Na 330.237t
la 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
vt
As 193.696t
Se 196.026t
Mo 202.031t
ROUTINE
7933601.0
7801.0
401402.8
-902.1
21207.1
-1.3
1063.9
578.2
2369.6
-7.6
Saturated2
635172.5
388.9
160302.6
698.4
839.3
4462.8
Page 8
1.89 mg/L
1.93 mg/L
1.95 mg/L
-3.68 mg/L
0.070 mg/L
-0.006 mg/L
1.54 mg/L
1.54 mg/L
0.212 mg/L
-0.005 mg/L
2.07 mg/L
1.93 mg/L
2.04 mg/L
1.899 mg/L
1.645 mg/L
2.129 mg/L
0.016
0.024
0.003
0.083
0.0025
0.0037
0.012
0.016
0.0218
0.0018
0.003
0.015
0.015
0.0211
0.0085
0.0104
Date: 1/27/2006 3:52:54 EM
1.89 mg/L
1.93 mg/L
1.95 mg/L
-3.68 mg/L
0.070 mg/L
-0.006 mg/L
1.54 mg/L
1.54 mg/L
0.212 mg/L
-0.005 mg/L
2.07 mg/L
1.93 mg/L
2.04 mg/L
1.899 mg/L
1.645 mg/L
2.129 mg/L
0.016
0.024
0.003
0.083
0.0025
0.0037
0.012
0.016
0.0218
0.0018
0.003
0.015
0.015
0.0211
0.0085
0.0104
0.84%
1.26%
0.14%
2.26%
3.56%
60.17%
0.79%
1.01%
10.28%
38.12%
0.13%
0.76%
0.74%
1.11%
0.52%
0.49%
Sequence No.: 15
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 14
Date Collected: 1/27/2006 3:48:21 EM
Data Type: Original
Initial Sample Vol:
Sanple Erep Vol:
Mean Data: Irb
Analyte
Yb
Agt
cat
Crt
Cut
Fet
Nit
'rrt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
p+
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity
3779385.1
-56.7
-36.0
120.7
403.6
1110.8
-13.1
-9
151
-42
-15
833
-11
-51
10701
105569
-14
2769
2653
-1134
263
102
279
25716
1
37
-10
386
-1
6111
-731
-0
48
-15
—5
-110
2
.4
.7
.8
.5
.7
.7
.2
.2
.1
.2
.1
.1
.6
.6
.4
.8
.9
.1
.7
.0
.5
.4
.9
.8
.3
.8
.3
.5
Calib
Cone. Units
9.18 mg/L
-0.001 mg/L
-0.001 mg/L
0.002 mg/L
0.004 mg/L
CU-02.fi, mg/L
/^-o.ooilHcr/L
^i»
0
-0
-0
0
0
0
0
0
-0
0
0
0
0
0
0
0
0
-0
0
-0
0
-0
-0
0
-0
-0
-0
--~ffQ-%-
.009
.009
.041
.021
.000
.000
.446
.409
.001
.039
.026
.000
.065
.000
1.14
.085
.009
.054
.028
. 035
.001
.001
.002
.004
.001
.043
.010
.053
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.070
0.0004
0.0004
0.0002
0.0001
0.0003
0.0012
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0028
.0003
.0055
.0115
.0012
.0001
.0001
.0042
.0030
.0006
.0009
.0005
.0001
.0036
.0000
0.086
.0015
.0070
.0095
.0013
.0000
.0031
.0001
.0009
.0054
.0003
.0121
.0101
.0161
Cone.
-0.001
-0.001
0.002
0.004
0.026
-0.001
-0.003
0.009
-0.009
-0.041
0.021
0.000
0.000
0.446
0.409
-0.001
0.039
0.026
0.000
0.065
0.000
1.14
0.085
0.009
0.054
-0.028
0.035
-0.001
0.001
-0.002
-0.004
0.001
-0.043
-0.010
-0.053
:=========:
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.0004
0.0004
0.0002
0.0001
0.0003
0.0012
0.0028
0.0003
0.0055
0.0115
0.0012
0.0001
0.0001
0.0042
0.0030
0.0006
0.0009
0.0005
0.0001
0.0036
0.0000
0.086
0.0015
0.0070
0.0095
0.0013
0.0000
0.0031
0.0001
0.0009
0.0054
0.0003
0.0121
0.0101
0.0161
RSD
0.76%
62.32%
39.78%
10.58%
2.56%
1.21%
85.84%
83 . 69%
3.11%
62 .94%
28.33%
5.76%
29.92%
154.11%
0.94%
0.74%
46.19%
2.44%
1.77%
22.96%
5.45%
5.54%
7.57%
1.78%
79.67%
17.74%
4.69%
0.11%
339.92%
8.18%
39.36%
141.49%
42.31%
28.33%
96.42%
30. 48%
Sequence No.: 16
Sanple ID: 010302-1
\nalyst:
Autosampler Location: 15
Date Collected: 1/27/2006 3:52:54 PM
Data Type: Original
-------
5UTINE
Page
Date: 1/27/2006 4:01:02 EM
Initial Sample Wt:
Dilution:
Initial Sample Vol:
Sample Prep Vol:
fean Data: 010302-1
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Pbt
Znt
Alt
Ast
•a a +
Bet
Ca 315.887t
Ca 422.673t
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
pt
Set
Sit
Snt
Srt
H +
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected Calib
Intensity Cone. Units
3805515.1
-139.6
-42.3
283.0
482.1
1908.1
3 5
-12.3
152.9
-172.1
-23.1
167.9
3.2
-257.2
6201.9
61910.1
-11.3
3395.4
3265.6
-1999.0
321.0
86.8
299.0
98724.1
-0.2
11.0
-11.7
925.4
-0.9
4107.3
-1439.4
-3.7
12.0
-23.1
-5.4
-199.9
9.24 mg/L
-0.001 mg/L
-0.001 mg/L
0.005 mg/L
0.004 mg/L
0 .J3_4_5__mg/L
-0.004 mg/L
0.009 mg/L
-0.035 mg/L
-0.059 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.258 mg/L
0.240 mg/L
-0.001 mg/L
0.047 mg/L
0.032 mg/L
0.000 mg/L
0.080 mg/L
0.000 mg/L
1.22 mg/L
0.326 mg/L
-0.001 mg/L
0.016 mg/L
-0.031 mg/L
0.083 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
-0.018 mg/L
0.000 mg/L
-0.063 mg/L
-0.011 mg/L
-0.095 mg/L
Std.Dev.
0 .041
0.0004
0.0002
0.0004
0.0001
0.0007
0.0017
0.0015
0.0003
0.0021
0.0057
0.0007
0.0004
0.0000
0.0028
0.0016
0.0007
0.0010
0.0007
0.0000
0.0010
0.0001
0.121
0.0027
0.0161
0.0052
0.0017
0.0024
0.0004
0.0000
0.0001
0.0060
0.0004
0.0060
0.0040
0.0034
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.005 mg/L
0.004 mg/L
0.045 mg/L
0.000 mg/L
-0.004 mg/L
0.009 mg/L
-0.035 mg/L
-0.059 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.258 mg/L
0.240 mg/L
-0.001 mg/L
0.047 mg/L
0.032 mg/L
0.000 mg/L
0.080 mg/L
0.000 mg/L
1.22 mg/L
0.326 mg/L
-0.001 mg/L
0.016 mg/L
-0.031 mg/L
0.083 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
-0.018 mg/L
0.000 mg/L
-0.063 mg/L
-0.011 mg/L
-0.095 mg/L
Std.Dev. RSD
0 44%
0.0004 26.52%
0.0002 14.45%
0.0004 6.82%
0.0001 3.32%
0.0007 1.67%
0.0017 444.97%
0.0015 33.07%
0.0003 3.84%
0.0021 5.92%
0.0057 9.60%
0.0007 15.46%
0.0004 396.98%
0.0000 7.48%
0.0028 1.07%
0.0016 0.68%
0.0007 73.67%
0.0010 2.07%
0.0007 2.32%
0.0000 0.75%
0.0010 1.29%
0.0001 18.67%
0.121 9.93%
0 . 0027 0 . 83%
0.0161 >999.9%
0.0052 32.50%
0.0017 5.44%
0.0024 2.88%
0.0004 77.65%
0.0000 2.53%
0.0001 2.10%
0.0060 33.23%
0.0004 248.08%
0.0060 9.60%
0.0040 37.45%
0.0034 3.57%
Sequence No.: 17
Sample ID: 010302-2
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 16
Date Collected: 1/27/2006 3:57:28 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010302-2
Analyte
Yb
Acrt
•f i-y i
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
"a 315.887t
Mean Corrected
Intensity
3705993.1
-125.1
-53.2
599.2
695.2
1273.6
-7.4
-11.5
137.1
852.7
-31.0
104.1
-6.8
-254.9
5591.7
Calib
Cone. Units
9.00 mg/L
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.006 mg/L
0.03.fi,,_mg/L
-~crTb~6~~4 mg/L
0.008 mg/L
0.173 mg/L
-0.080 mg/L
0.003 mg/L
0.000 mg/L
0.000 mg/L
0.233 mg/L
Std.Dev.
0.091
0.0004
0.0001
0.0005
0.0011
0.0003
0.0006
0.0030
0.0003
0.0044
0.0031
0.0004
0.0003
0.0000
0.0014
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.006 mg/L
0.030 mg/L
-0.001 mg/L
-0.004 mg/L
0.008 mg/L
0.173 mg/L
-0.080 mg/L
0.003 mg/L
0.000 mg/L
0.000 mg/L
0.233 mg/L
Std.Dev.
0..0004
0.0001
0.0005
0.0011
0.0003
0.0006
0.0030
0.0003
0.0044
0.0031
0.0004
0.0003
0.0000
0.0014
RSD
1 . 01 0
33.56%
5.96%
4.33%
16.36%
1.17%
78.45%
73.77%
3.40%
2.53%
3.95%
15.64%
126.44%
15.22%
0.61%
-------
Ca 422.673t
Cot
K lOt
K 766.490 20
jit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
L ROUTINE
53745.4
-18.1
3072.1
t 2946.5
-1982.3
321.9
184.7
402.0
107939.0
1.8
12.7
-17.1
1485.6
-1.6
3935.6
-1537.7
-0.1
29.6
-31.0
-9.5
-221.8
Page
0.208 mg/L
-0.002 mg/L
0.043 mg/L
0.029 mg/L
0.000 mg/L
0.080 mg/L
0.001 mg/L
1.64 mg/L
0.356 mg/L
0.008 mg/L
0.018 mg/L
-0.045 mg/L
0.133 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
0.000 mg/L
0.000 mg/L
-0.084 mg/L
-0.019 mg/L
-0.106 mg/L
10
0.0012
0.0007
0.0007
0.0002
0.0000
0.0052
0.0001
0.056
0.0017
0.0049
0.0090
0.0177
0.0028
0.0003
0.0000
0.0001
0.0095
0.0002
0.0033
0.0063
0.0009
Date
0.208 mg/L
-0.002 mg/L
0.043 mg/L
0.029 mg/L
0.000 mg/L
0.080 mg/L
0.001 mg/L
1.64 mg/L
0.356 mg/L
0.008 mg/L
0.018 mg/L
-0.045 mg/L
0.133 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
0.000 mg/L
0.000 mg/L
-0.084 mg/L
-0.019 mg/L
-0.106 mg/L
: 1/27/2006 4
0.0012
0.0007
0.0007
0.0002
0.0000
0.0052
0.0001
0.056
0.0017
0.0049
0.0090
0.0177
0.0028
0.0003
0.0000
0.0001
0.0095
0.0002
0.0033
0.0063
0.0009
:06:46 EM
0.60%
44.15%
1.66%
0.57%
0.98%
6.55%
6.10%
3.42%
0.48%
59.10%
48.72%
38.88%
2.09%
30.67%
1.55%
1.70%
>999.9%
58.12%
3.95%
33.63%
0.81%
Sequence No.: 18
Sample ID: 010302-3
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 17
Date Collected: 1/27/2006 4:02:02 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010302-3
Analyte
Yb
Agt
Cdt
Olwl )
Crt
:ut
Fet
Nit
PVi +
JrJJ 1
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mn +
1VJJ1 |
Ma 330.237t
Na 589.592t
Pt
01-,+
OJJ I
Set
Sit
q-nf
011 ]
^r-t
O J_ |
Tit
rrTI 4-
j. -L 1
\r+
v |
As 193.696t
Se 196.026t
Mo 202.031t
!
Mean Corrected
Intensity
3745097.8
-84.1
-53.1
984.0
601.9
2858.9
-11.6
-6.9
182.8
19.7
-32.0
160.7
1.5
-276.2
6074.6
59058.4
-12.2
4115.7
3812.5
-1716.3
313.9
67.6
387.3
98728.7
6.0
4. 6
-15.0
1086.9
-3.2
4237.1
-1562.0
-0.2
39.8
-32.0
-14.2
-228.6
Calib
Cone . Units
9.09 mg/L
-0.001 mg/L
-0.001 mg/L
0.019 mg/L
0.006 mg/L
0 ...Q62_mg/L
(--" -6. 001,,mg/L
•~--~~B=:Q:Q2 mg/L
0.010 mg/L
0.004 mg/L
-0.082 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.253 mg/L
0.229 mg/L
-0.001 mg/L
0.058 mg/L
0.037 mg/L
0.000 mg/L
0.078 mg/L
0.000 mg/L
1.58 mg/L
0.326 mg/L
0.027 mg/L
0.007 mg/L
-0.040 mg/L
0.097 mg/L
-0.002 mg/L
0.000 mg/L
-0.005 mg/L
-0.001 mg/L
0.001 mg/L
-0.087 mg/L
-0.028 mg/L
-0.109 mg/L
Std.Dev.
0.097
0.0007
0.0001
0.0021
0.0007
0.0003
0.0002
0.0035
0.0004
0.0030
0.0033
0.0003
0.0002
0.0000
0.0009
0.0016
0.0008
0.0020
0.0014
0.0000
0.0041
0.0001
0.085
0.0047
0.0077
0.0026
0.0144
0.0010
0.0022
0.0000
0.0001
0.0138
0.0004
0.0035
0.0086
0.0023
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.019 mg/L
0.006 mg/L
0.067 mg/L
-0.001 mg/L
-0.002 mg/L
0.010 mg/L
0.004 mg/L
-0.082 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.253 mg/L
0.229 mg/L
-0.001 mg/L
0.058 mg/L
0.037 mg/L
0.000 mg/L
0.078 mg/L
0.000 mg/L
1.58 mg/L
0.326 mg/L
0.027 mg/L
0.007 mg/L
-0.040 mg/L
0.097 mg/L
-0.002 mg/L
0.000 mg/L
-0.005 mg/L
-0.001 mg/L
0.001 mg/L
-0.087 mg/L
-0.028 mg/L
-0.109 mg/L
Std.Dev.
0.0007
0.0001
0.0021
0.0007
0.0003
0.0002
0.0035
0.0004
0.0030
0.0033
0.0003
0.0002
0.0000
0.0009
0.0016
0.0008
0.0020
0.0014
0.0000
0.0041
0.0001
0.085
0.0047
0.0077
0.0026
0.0144
0.0010
0.0022
0 .0000
0.0001
0.0138
0.0004
0.0035
0.0086
0.0023
RSD
1.07%
80.59%
6.69%
10 . 89%
13.02%
0.41%
19.21%
143.31%
3.52%
74.90%
3.97%
8.02%
465.93%
6.36%
0.37%
0.70%
80.06%
3.43%
3.80%
8.37%
5.23%
23.60%
5.37%
1.45%
28.31%
38.88%
36.01%
1.04%
113.23%
1.98%
2.83%
>999.9%
81.69%
3 . 97%
30.94%
2.14%
-------
Method: NEW Al ROUTINE
Page 11
Date: 1/27/2006 4:14:56 EM
Sequence No.: 19
Sample ID: 010218-1
\nalyst:
.nitial Sample Wt:
Dilution:
Autosampler Location: 18
Date Collected: 1/27/2006 4:06:46 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Analyte
Yb
Agt
Cdt
Crt
Cut
"NTi +
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
C 422
Cot
K lOt
K 766.4
Lit
Mgt
Mnt
>bt
jet
Sit
Srt
Tit
Tit
Vt
As 193.
Se 196.
Mo 202.
ba: 010218-1
Mean Corrected
Intensity
-57.7
527.3
750.1
2639.8
20206.5
-11.7
429.5
-193.4
-36.0
3303.1
152.4
-239.3
887t 5783.6
673t 56533.3
5 0
4ft 67 4
"
237t "JI'.I
-0.6
-10.7
0 7
4130.0
-2110.9
-2.9
54.0
696t -36.0
026t -9.9
031t -243.2
Calib
Cone . Units
9.19 mg/L
-0.001 mg/L
-0.001 mg/L
0.010 mg/L
0.007 mg/L
C" 2 . lj§.--3tig/L
-1)76 04 mg/L
0.024 mg/L
0.083 mg/L
0.005 mg/L
0.000 mg/L
0.241 mg/L
0.219 mg/L
0 000 mg/L
0 068 mg/L
0 046 mg/L
0 000 mg/L
0 075 ma/L
1.42 mg/L
0.357 mg/L
-0.001 mg/L
~n"n7T mg^
0.000 mg/L
0.000 mg/L
-0.007 mg/L
-0.014 mg/L
0.001 mg/L
-0.098 mg/L
-0.019 mg/L
-0.116 mg/L
Std.Dev.
0 . 0004
0.0003
0.0002
0.0004
0.0007
0.011
0.0036
0.0004
0.0031
0.0088
0.0014
0.0003
0.0000
0.0018
0 .0011
0.0008
0.0005
0.0004
0.0000
0.0007
0.0000
o-.'lli
o" 0007
0.0016
0.0000
0.0002
0.0114
0.0003
0.0093
0.0108
0.0013
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.010 mg/L
0.007 mg/L
0.062 mg/L
z . ID mg/ii
-0.004 mg/L
-0.03,9 mg/L
-0.093 mg/L
0.083 mg/L
0.005 mg/L
0.000 mg/L
0.241 mg/L
0.219 mg/L
0.000 mg/L
0.068 mg/L
0 .046 mg/L
0.000 mg/L
0.075 mg/L
°i°°426 mg/L
-0 .001 mg/L
o"o73 mg/L
0.000 mg/L
0.000 mg/L
-0.007 mg/L
-0.014 mg/L
0.001 mg/L
-0.098 mg/L
-0.019 mg/L
-0.116 mg/L
. — =•—
Std.Dev.
0.0004
0.0003
0.0002
0.0004
0.0007
0 Oil
0.0004
0.0031
0.0088
0.0014
0.0003
0.0000
•
0 . 0011
0 . 0008 .
0.0005
0.0004
0.0000
0.0007
0.0000
0.0081
0.0007
0.0016
0.0000
0.0002
0.0114
0.0003
0.0093
0.0108
0.0013
RSD
0.04%
19.14%
1.97%
6.09%
1.14%
1.46%
7.86%
9.54%
1.72%
5.20%
13.81%
• *° °
184 . 44 o
0.72%
0.77%
5.27%
0.96%
0.84%
629.25%
28.37%
0.98%
354.30%
0.66%
2.24%
79.38%
42.88%
9.54%
55.64%
1.14%
Sequence No.: 20
Sample ID: 010218-2
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 19
Date Collected: 1/27/2006 4:11:21 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010218-2
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
\st
Mean Corrected
Intensity
3746908.9
-111.3
-34.7
602.5
974.9
2777.3
2223.5
-17.2
514.0
-208.5
-31.3
Calib
Cone. Units
9.10 mg/L
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.009 mg/L
0.065....mg/L
^•^..XaS-mg/L"
^".006 mg/L
0.029 mg/L
-0.042 mg/L
-0.080 mg/L
Std.Dev.
0.088
0.0005
0.0003
0.0005
0.0002
0.0008
0.0023
0.0016
0.0004
0.0003
0.0102
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.009 mg/L
0.065 mg/L
0.238 mg/L
-0.006 mg/L
0.029 mg/L
-0.042 mg/L
-0.080 mg/L
Std.Dev.
0.0005
0.0003
0.0005
0.0002
0.0008
0.0023
0.0016
0.0004
0.0003
0.0102
RSD
0.97%
38.53%
36.02%
4.53%
1.70%
1.29%
0.96%
26.07%
1.39%
0.63%
12.66%
-------
Date: 1/27/2006 4:19:31 EM
Method: HEW Al ROD
Bt
Bat
Bet
-.a 315.887t
,a 422.673t
Cot
K 10t
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
— ===
TJ.KIS
726.2
1.4
-230.1
5208.5
50741.0
-8.4
6338.3
6126.4
-2186.3
284.0
495.0
373.1
133504.3
3.1
-4.4
-16.2
701.9
3.1
4569.9
-2126.3
-4.5
32.1
-31.3
-14.4
-246.6
0.018 mg/L
0.000 mg/L
0.000 mg/L
0.217 mg/L
0.196 mg/L
-0.001 mg/L
0.089 mg/L
0.060 mg/L
-0.001 mg/L
0.070 mg/L
0.002 mg/L
1.52 mg/L
0.441 mg/L
0.014 mg/L
-0.006 mg/L
-0.043 mg/L
0.063 mg/L
0.002 mg/L
0.001 mg/L
-0.007 mg/L
-0.022 mg/L
0.000 mg/L
-0.085 mg/L
-0.028 mg/L
-0.118 mg/L
0.0002
0.0001
0.0000
0.0007
0.0006
0.0002
0.0023
0.0014
0.0000
0.0009
0.0000
0.040
0.0022
0.0126
0.0055
0.0068
0.0024
0.0019
0.0000
0.0001
0.0078
0.0004
0.0108
0.0113
0.0025
0.018 mg/L
0.000 mg/L
0.000 mg/L
0.217 mg/L
0.196 mg/L
-0.001 mg/L
0.089 mg/L
0.060 mg/L
-0.001 mg/L
0.070 mg/L
0.002 mg/L
1.52 mg/L
0.441 mg/L
0.014 mg/L
-0.006 mg/L
-0.043 mg/L
0.063 mg/L
0.002 mg/L
0.001 mg/L
-0.007 mg/L
-0.022 mg/L
0.000 mg/L
-0.085 mg/L
-0.028 mg/L
-0.118 mg/L
0.0002
0.0001
0.0000
0.0007
0.0006
0.0002
0.0023
0.0014
0.0000
0.0009
0.0000
0.040
0.0022
0.0126
0.0055
0.0068
0.0024
0.0019
0.0000
0.0001
0.0078
0.0004
0.0108
0.0113
0.0025
0.90%
279.87%
15.04%
0.30%
0.30%
22 .03%
2.56%
2.42%
3.75%
1.26%
1.47%
2.65%
0.50%
89.01%
87.59%
15.73%
3.77%
99.73%
3.77%
1.41%
34.83%
105.95%
12.66%
40.06%
2.12%
Sequence No.: 21
Sattple ID: 010218-3
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 20
Date Collected: 1/27/2006 4:15:56 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010218-3
\nalyte
A
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
7t
Mean Corrected
Intensity Cone.
3627157
-109
-56
403
367
924
-8
-14
88
-171
-35
39
-26
-248
5398
50852
-22
3181
3040
-2052
286
4
404
83499
0
-3
-16
855
-4
3901
-1820
-3
57
.0
.2
.1
.4
.9
.3
.5
.7
.0
.8
.2
.4
.3
.2
.7
.5
.0
.9
.6
.4
.5
.0
.0
.3
.8
.1
.9
.2
.7
.3
.3
.2
.9
!
-0
-0
0
0
0
c-o
nror
0
-0
-0
0
-0
0
0
0
-0
0
0
0
0
0
0
0
-0
-0
0
-0
0
-0
-0
0
3.81
.001
.001
.008
.003
.022
fob"!
ro'oT
.005
.035
.090
.001
.001
.000
.225
.197
.002
.044
.030
.000
.071
.000
1.65
.276
.004
.004
.045
.076
.003
.000
.006
.016
.001
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
jngYL
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0-1 c -1
. 151
0.0004
0.0003
0.0005
0.0011
0.0003
0.0014
0.0012
0.0002
0.0073
0.0076
0.0003
0.0001
0.0000
0.0036
0.0015
0.0000
0.0014
0.0010
0.0000
0.0008
0.0001
0.062
0.0013
0.0104
0.0090
0.0156
0.0008
0.0016
0.0000
0.0002
0.0205
0.0007
Cone.
-0.001
-0.001
0.008
0.003
0.022
-0.001
-0.005
0.005
-0.035
-0.090
0.001
-0.001
0.000
0.225
0.197
-0.002
0.044
0.030
0.000
0.071
0.000
1.65
0.276
0.004
-0.004
-0.045
0.076
-0.003
0.000
-0.006
-0.016
0.001
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.0004
0.0003
0.0005
0.0011
0.0003
0.0014
0.0012
0.0002
0.0073
0.0076
0.0003
0.0001
0.0000
0.0036
0.0015
0.0000
0.0014
0.0010
0.0000
0.0008
0.0001
0.062
0.0013
0.0104
0.0090
0.0156
0.0008
0.0016
0.0000
0.0002
0.0205
0.0007
RSD
•1.71%
37.22%
21.62%
6.14%
32.17%
1.26%
152.01%
23.17%
4.64%
21.06%
8.42%
27.81%
7.43%
18.29%
1.62%
0.76%
0.79%
3.06%
3.29%
1.02%
1.17%
525.17%
3.75%
0.49%
294.26%
201.97%
34.57%
1.06%
54.27%
1.56%
2.62%
128.66%
91.10%
-------
Method: NEW Al ROUTINE
As 193.
Se 196.
Mo 202.
696t
026t
031t
-35
-9
-250
.2
.1
.0
-0.
-0.
-0.
096
018
119
Page
mg/L
mg/L
mg/L
13
0.0080
0.0051
0.0011
Date: 1/27/2006 4:28:43 EM
-0.096
-0.018
-0.119
mg/L
mg/L
mg/L
0.0080
0.0051
0.0011
8.42%
28.75%
0.91%
Sequence No.: 22
Sample ID: 010218-4
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 21
Date Collected: 1/27/2006 4:20:32 PM
Data Type: Original
Initial Sanqple Vol:
Sample Prep Vol:
Mean Data: 010218-4
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
la 330.237t
Na 589.592t
P+
Set
t
Srt
Tit
TM +
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity
3681821.8
-122.8
-53.6
1075.7
990.6
2680.5
5824.0
-9.4
1591.3
-38.1
-31.9
1527.5
64.3
-247.7
9757.9
94029.6
-12.1
9868.7
9549.9
-2188.2
431.5
1513.6
374.0
127085.3
11.0
-2.3
-17.1
1110.8
1590.4
9542.5
-1775.3
-1.7
34.9
-31.9
-16.7
-250.2
Calib
Cone. Units
8.94 mg/L
-0.001 mg/L
-0.001 mg/L
0.021 mg/L
0.009 mg/L
0 J163_ mg/L
(-"6.622jmg/L
-07003 mg/L
0.090 mg/L
-0.008 mg/L
-0.082 mg/L
0.039 mg/L
0.002 mg/L
0.000 mg/L
0.406 mg/L
0.364 mg/L
-0.001 mg/L
0.138 mg/L
0.093 mg/L
-0.001 mg/L
0.107 mg/L
0.007 mg/L
1.53 mg/L
0.420 mg/L
0.050 mg/L
-0.003 mg/L
-0.045 mg/L
0.099 mg/L
0.981 mg/L
0.001 mg/L
-0.006 mg/L
-0.008 mg/L
0.000 mg/L
-0.087 mg/L
-0.033 mg/L
-0.119 mg/L
Std.Dev.
0.070
0.0005
0.0001
0.0009
0.0005
0.0001
0.0008
0.0014
0.0003
0.0042
0.0130
0.0009
0.0002
0.0000
0.0004
0.0020
0.0002
0.0005
0.0003
0.0000
0.0035
0.0001
0.008
0.0029
0.0062
0.0072
0.0058
0.0015
0.0164
0.0000
0.0001
0.0118
0.0002
0.0137
0.0060
0.0022
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.021 mg/L
0.009 mg/L
0.063 mg/L
0.622 mg/L
-0.003 mg/L
0.090 mg/L
-0.008 mg/L
-0.082 mg/L
0.039 mg/L
0.002 mg/L
0.000 mg/L
0.406 mg/L
0.364 mg/L
-0.001 mg/L
0.138 mg/L
0.093 mg/L
-0.001 mg/L
0.107 mg/L
0.007 mg/L
1.53 mg/L
0.420 mg/L
0.050 mg/L
-0.003 mg/L
-0.045 mg/L
0.099 mg/L
0.981 mg/L
0.001 mg/L
-0.006 mg/L
-0.008 mg/L
0.000 mg/L
-0.087 mg/L
-0.033 mg/L
-0.119 mg/L
Std.Dev.
0.0005
0.0001
0.0009
0.0005
0.0001
0.0008
0.0014
0.0003
0.0042
0.0130
0.0009
0.0002
0.0000
0.0004
0.0020
0.0002
0.0005
0.0003
0.0000
0.0035
0.0001
0.008
0.0029
0.0062
0.0072
0.0058
0.0015
0.0164
0.0000
0.0001
0.0118
0.0002
0.0137
0.0060
0.0022
RSD
0.78%
39.64%
6.12%
4.56%
5.10%
0.22%
0.13%
41.44%
0.30%
54.50%
15.82%
2.28%
10.86%
3.33%
0.09%
0.54%
23.37%
0.37%
0.32%
1.51%
3.27%
0.98%
0.52%
0.70%
12.38%
212.22%
12.71%
1.47%
1.67%
0.54%
2 .19%
140.88%
43.93%
15.82%
18.22%
1.84%
Sequence No.: 23
Sample ID: 010218-5
Analyst:
Initial Sanple Wt:
Dilution:
Autosampler Location: 22
Date Collected: 1/27/2006 4:25:08 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010218-5
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Mit
Mean Corrected
Intensity
3730727.8
-92.6
-41.7
574.5
669.3
2270.4
816.6
Calib
Cone. Units
9.06 mg/L
001 mg/L
001 mg/L
0.011 mg/L
0.006 mg/L
0.053 mg/L
0.087 mg/L
Std.Dev.
0.043
0.0005
0.0003
0.0007
0.0002
0.0011
0.0014
Sample
Cone. Units
-0
001 mg/L
0.001 mg/L
0.011 mg/L
006 mg/L
0.053 mg/L
0.087 mg/L
0
Std.Dev.
0.0005
0.0003
0.0007
0.0002
0.0011
0.0014
RSD
0.48%
54.39%
29.
5.
3.
1.
1.
99%
06%
99%
-------
Method: NEW Al ROUTINE
Pbt
Knt
alt
•tt_L 1
\st
j T
Bat
Bet
Ca 315.887t
Ca 422.673t
PI~»+
k^O 1
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Sbt
. ,
CnH-
iDIl 1
^rt
L3 J_ 1
Tit
ml +
-L-L 1
vt
As 193.696t
Se 196.026t
Mo 202.031t
-9.2
805.6
-171.8
-33.5
476.3
55.7
-273.6
5833.3
56862.7
-8.6
4979.5
4802.2
-1504.5
321.0
2039.3
328.0
114040.5
4.9
-3.0
-16.8
991.2
24.4
6536.4
-2081.1
-1.0
0.1
-33.5
-18.9
-251.6
Page 14
-0.003 mg/L
0.046 mg/L
-0.035 mg/L
-0.086 mg/L
0.012 mg/L
0.002 mg/L
0.000 mg/L
0.243 mg/L
0.220 mg/L
-0.001 mg/L
0.070 mg/L
0.047 mg/L
0.000 mg/L
0.080 mg/L
0.010 mg/L
1.34 mg/L
0.376 mg/L
0.022 mg/L
-0.004 mg/L
-0.045 mg/L
0.089 mg/L
0.015 mg/L
0.001 mg/L
-0.007 mg/L
-0.005 mg/L
0.000 mg/L
-0.091 mg/L
-0.037 mg/L
-0.120 mg/L
0.0028
0.0003
0.0021
0.0080
0.0003
0.0001
0.0000
0.0028
0.0023
0.0004
0.0014
0.0010
0.0003
0.0017
0.0002
0.121
0.0046
0.0130
0.0029
0.0030
0.0025
0.0047
0.0000
0.0002
0.0202
0.0001
0.0085
0.0100
0.0012
Date: 1/27/2006 4:
-0.003 mg/L
0.046 mg/L
-0.035 mg/L
-0.086 mg/L
0.012 mg/L
0.002 mg/L
0.000 mg/L
0.243 mg/L
0.220 mg/L
-0.001 mg/L
0.070 mg/L
0.047 mg/L
0.000 mg/L
0.080 mg/L
0.010 mg/L
1.34 mg/L
0.376 mg/L
0.022 mg/L
-0.004 mg/L
-0.045 mg/L
0.089 mg/L
0.015 mg/L
0.001 mg/L
-0.007 mg/L
-0.005 mg/L
0.000 mg/L
-0.091 mg/L
-0.037 mg/L
-0.120 mg/L
0.0028
0.0003
0.0021
0.0080
0.0003
0.0001
0.0000
0.0028
0.0023
0.0004
0.0014
0.0010
0.0003
0.0017
0.0002
0.121
0.0046
0.0130
0.0029
0.0030
0.0025
0.0047
0.0000
0.0002
0.0202
0.0001
0.0085
0.0100
0.0012
33:38 PM
84.97%
0.65%
6.09%
9.27%
2.27%
5.95%
4.30%
1.16%
1.03%
51.69%
1.97%
2.13%
69.98%
2.18%
1.59%
9.04%
1.22%
58.41%
68.71%
6.75%
2.81%
30.87%
0.83%
2.30%
424.64%
>999.9%
9.27%
27.06%
1.02%
Sequence No.: 24
Sample ID: ccv
Analyst:
Initial Sanple Wt:
Dilution:
Autosanpler Location: 23
Date Collected: 1/27/2006 4:29:44 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: ccv 1.
Analyte
Yb
Aat
•* "y '
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K 10t
K 766.490 20t
Lit
Mat
J. J-^J I
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
<3nt
00
Mean Corrected
Intensity
3977408.4
191687
79572
98707
213710
88800
18940
5421
35268
34245
748
75838
56839
2109175
174365
2110837
22809
1736262
1685152
.2
.4
.5
.3
.6
.1
.9
.4
.1
.1
.1
.2
.4
.5
.0
.0
.0
.7
Cone.
9.66
2.02
1.97
1.91
1.98
2.08
^ 2.02
^--iris
2.00
6.95
1.92
1.91
1.99
2.09
7.26
8.17
1.98
24.3
16.46
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
"mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std
0
0
0
0
0
A °
,-° o
0
0
0
0
0
0
0
0
0
0
0
.Dev.
.021
.014
.010
.012
.016
.013
.011
.037
.017
.090
.006
.012
.011
.005
.044
.026
.012
0.04
.028
Cone.
2.02
1.97
1.91
1.98
2.08
2.02
1.95
2.00
6.95
1.92
1.91
1.99
2.09
7.26
8.17
1.98
24.3
16.46
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Saturated2
28420
417483
148
2227111
853
1137
725
12025
6372
.9
.3
.9
.6
.6
.1
.3
.2
.5
7.04
2.03
0.608
7.35
3.88
1.64
1.93
1.07
3.93
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0.
0
0
0
0
0
0
.038
.013
0692
.015
.061
.006
.045
.011
.065
7.04
2.03
0.608
7.35
3.88
1.64
1.93
1.07
3.93
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0.
0
0
0
0
0
0
.Dev.
.014
.010
.012
.016
.013
.011
.037
.017
.090
.006
.012
.011
.005
.044
.026
.012
0.04
.028
.038
.013
0692
.015
.061
.006
.045
.011
.065
RSD
0.21%
0.72%
0. 48%
0. 63%
0.82%
0.63%
0.55%
1. 92%
0.82%
1.30%
0.32%
0.64%
0.57%
0.24%
0.61%
0.31%
0. 60%
0.17%
0.17%
0.54%
0.64%
11.40%
0.21%
1.58%
0.38%
2.31%
1.04%
1.66%
-------
NEW Al ROUTINE
Page 15
Date: 1/27/2006 4:38:15 EM
Srt
Tit
Tit
Vt
\s 193.
Se 196.
Mo 202.
696t
026t
031t
Saturate
623268
396
158610
748
1056
3933
d2
.3
.3
.7
.1
.9
.7
2.03
1.97
2.02
2.034
2.071
1.877
mg/L
mg/L
mg/L
mg/L
mg/1
mg/L
0
0
0
0.
0.
0.
.005
.015
.013
0065
0390
0792
2.03
1.97
2.02
2.034
2.071
1.877
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.005
0.015
0.013
0.0065
0.0390
0.0792
0.27%
0.75%
0.62%
0.32%
1.88%
4.22%
Sequence No.: 25
Sample ID: cob
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 24
Date Collected: 1/27/2006 4:34:39 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: ccb
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
iC 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Ft
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity Cone.
3913552
55
-6
2
291
25
-16
-4
10
-161
-10
1352
-3
-74
-245
-3365
-0
54
23
-1043
-1
-102
5
-176
-2
33
-1
-10
4
-411
-683
0
-52
-10
3
-68
.4
.2
.6
.8
.2
.7
.5
.1
.2
.1
.9
.2
.1
.0
.2
.2
.9
.9
.6
.7
.8
.5
.0
.3
.8
.4
.0
.1
.4
.4
.1
.2
.5
.9
.3
.2
9.50
0.001
0.000
0.000
0.003
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
0,,-001-mg/L
X0.002 ,mg/L
WrBtfT
0.001
-0.033
-0.028
0.034
0.000
0.000
-0.010
-0.013
0.000
0.001
0.000
0.000
0.000
0.000
0.020
-0.001
-0.013
0.048
-0.003
-0.001
0.003
0.000
-0.002
0.001
-0.001
-0.030
0.006
-0.033
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.047
.0004
.0000
.0003
.0001
.0000
.0013
.0039
.0003
.0069
.0054
.0049
.0004
.0000
.0010
.0002
.0003
.0012
.0006
.0001
.0009
.0001
.0680
.0004
.0068
.0084
.0034
.0011
.0028
.0001
.0009
.0302
.0001
.0057
.0213
.0205
Cone.
0.001
0.000
0.000
0.003
0.001
-0.002
-0.001
0.001
-0.033
-0.028
0.034
0.000
0.000
-0.010
-0.013
0.000
0.001
0.000
0.000
0.000
0.000
0.020
-0.001
-0.013
0.048
-0.003
-0.001
0.003
0.000
-0.002
0.001
-0.001
-0.030
0.006
-0.033
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0004
0000
0003
0001
0000
0013
0039
0003
0069
0054
0049
0004
0000
0010
0002
0003
0012
0006
0001
0009
0001
0680
0004
0068
0084
0034
0011
0028
0001
0009
0302
0001
0057
0213
0205
RSD
0.50%
76.75%
27.80%
607.41%
2.38%
4.70%
76.13%
262.32%
53.44%
21.19%
19.38%
14.38%
367.33%
64.86%
9.47%
1.42%
337.15%
150.90%
278.20%
28.55%
195.18%
17.46%
332.78%
67.70%
54.00%
17.28%
132.41%
119.98%
102.30%
152.54%
39.98%
>999.9%
22.24%
19.38%
333.55%
63.09%
-------
PROJECT # 110325: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES IDL = 0.004 LOQ • 0.017
Digestion on 12/20/05 LOD = 0.008 RL« 0.050
BY ICP ON 12/30/05 MDL • 0.007 (AN DL in mg/L)
DATA:
Sample #
LRB
LFB
110325-1
110325-2
110325-3
110325-4
110325-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
0.75
0.064
0.288
,;^!|
0.049
0.060
=MDL of 0.007 mg/L =0.006
--100 x 0.749/0.80 = 96% Recovery, ( 80-120%)
= 0.006
EXPLANATIONS:
Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
~ process were added, no filter.
Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
digestion process, again, no filter.
DILUTION = 25 ml class A volumetric flask was used to measure the final volume.
READING = mg/L as determined by average of three replicates on ICP.
IN ORDER TO FAClLlT/iTE;FURTHER jSXfqiMtiONfe, IF -A'READINGS iflvlDL, THEN 0,QQ6/(^ USED. ,
12/31/05LK
SI LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 121
X/ USEPA/ NICEM/ PROJECT 21 Analytical data/METHOD 121-2
-------
Laboratory Work Order Report
LIMSNo. 2005110325 Date Rec'd 11/18/2005 03:03:23 Date Due 11/18/2005 12:00:00 AM
Project Code .NULL Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLINAVE.
CHICAGO IL 60623
Phone 254-2406
Matrix Engineering
Client Notes: -0-
Fax 254-6661
PoNo. rQi
Contact MR. FRANK ALTMAVER
e-mail
Quoted Price: .NULL
Order Comments: .NULL
.NULL
Sample No. Comments Test Code Description
ELITE FINISHING
1 11/15/2005 11/15/05 CONDITION #23-NORTH
Nl NICKEL
2 11/15/2005 11/15/05 CONDITION #23-SOUTH
Nl NICKEL
3 11/15/2005 11/15/05 BLANK
Nl NICKEL
4 11/16/2005 11/16/05 CONDITION #25-NORTH
Nl NICKEL
5 11/16/2005 11/16/05 CONDITION #25-SOUTH
Nl NICKEL
Date Received Result
11/18/2005 02:00:00 PM
11/18/2005 02:00:00 PM
11/18/200502:00:00 PM
11/18/200502:00:00 PM
11/18/200502:00:00 PM
Page 1
-------
PROJECT # 120034: METHOD 121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 12/20/05
BY ICP ON 12/30/05
IDL =
LOD =
MDL •
0.004
0.008
0.007
LOQ= 0.017
RL • 0.050
(All DL in mg/L)
DATA:
Sample #
LRB
LFB
120034-1
120034-2
120034-3
Dilution
25
25
25
25
25
Reading
-0.002
0.75
0.174
0.176
V^ %tf\
EXPLANATIONS:
-------
I joratory Work Order Report
LIMS No. 2005120034 Date Rec'd 12/05/2005 12:00:40 Date Due 12/05/2005 12:00:00 AM
Project Code .NULL Customer No. SCICON Client Type: REGULAR
Client Name SCIENTIFIC CONTROL LABS
3158S. KOLIN AVE.
CHICAGO IL 60623
Phone
Matrix
254-2406
Engineering
Fax
• 254-6661
Contact
Po No. ^2
MR. FRANK
e-mail
ALTMAYER
Client Notes: -
Order Comments: METHOD 10-121
Sample No.
ELITE
Comments
Test Code Description
1 12/01/2005 12/01/05 CONDITION #26 - NORTH (25082360)
Nl NICKEL
2 12/01/2005 12/01/05 CONDITION #26-SOUTH (25082350)
Nl NICKEL
3 12/01/2005 12/01/05 BLANK -(25082353)
Nl NICKEL
Quoted Price: .NULL.
Date Received
Result
12/05/2005 10:00:00 AM
12/05/2005 10:00:00 AM
12/05/2005 10:00:00 AM
TOf
Page 1
-------
METALS PREP FORM
Set#
Prep Method: (check only one per page)
ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA200's, SW-8463010A
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE
OTHER: .
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:
1
•
4
5
_L
8
10
11
DRINP
"Set
Jnifl
u
SPIKIN
- -
CINGW
Set
4o
3STDS
QC-21
QC-7
P
Sn
OTHER
fATER
Set
time
Lab#
\\6^
1
N
,
/
I
,
/
Smp#
I
4
e>
•..
I
^
AQUEOUS
Company
LFB
LRB
«W«IP
em
-
.,
PROVIDER
ff^}
LOT#
0 S' <
-a u
A
DTHF.R : ,/l W<. . I / U / «^(
Final
(mis)
--r^~
'
Analyst:
Start Date:
1 . ..•'*'.'.
• ' .
j. . '..; j :•• „, '-
. .. *
Mcr
Vsl#
S\QA FORMS \FM-041 1R02 \LK
Page 1 of 1
-------
Sample Information Detail Report
Document Name: 123005-1
File Description
Default Sample Information File
Parameters Common to All Samples
Batch ID
Volume Units
Weight Units
Parameters That Vary By Sample
123005-1
ml
9
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sample Prep. Vol.
Sample ID
cri
icb
icv
icsab
IfbNi
Irb
110325-1
110325-2
110325-3
110325-4
110325-5
120034-1
120034-2
120034-3
ccv 0.50
ccb
Aliquot Volume
Initial Sample Wt.
Diluted To Vol.
-------
Method: Air Filter Ni
Page 1
Date: 12/30/2005 12:09:05 PM
Analysis Begun
Jtart Time: 12/30/2005 11:58:14 AM Plasma On Time: 12/30/2005 11:12:33 AM
Logged In Analyst: sammy Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91
Sample Information File: C:\pe\sammy\Sample Information\123005-l.sif
Batch ID: 123005-1
Results Data Set: 123005-1
Results Library: C:\pe\sairany\Results\Results.mdb
Method Name? Air Filter Ni Method Last Saved: 10/5/2005 1:33:13 PM
IEC File: MSF File:
Method Description: AIR FILTER Ni
Sequence No • 1 Autosampler Location: 0
Sample ID: Calib Blank 1 Date Collected: 12/30/2005 11:58:14 AM
Analyst: Data Type: Original
Initial Sample Wfc: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: Calib Blank 1
Mean Corrected Calib
Analyte Intensity Std.Dev. RSD Cone. Units
Yb 328.937 2135095.0 11709.27 0.55% 10.0 mg/L
Ni 231.604t -114.1 2.73 2.39% [0.00] mg/L
Sequence No.: 2 Autosampler Location: 1
Sample ID: Cal 21+7 1.00 Date Collected: 12/30/2005 12:01:53 PM
Analyst: Data Type: Original
initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: Cal 21+7 1.00
Mean Corrected Calib
Analyte Intensity Std.Dev. RSD Cone. Units
Yb 328.937 2104392.6 2502.46 0.12% 9.86 mg/L
Ni 231.604t 6036.7 22.96 0.38% [1.00] mg/L
Calibration Summary
Analyte Stds. Equation Intercept Slope Curvature Corr. Coef. Reslope
Ni 231.604 1 Lin Thru 0 0.0 6037 0.00000 1.000000
Sequence No.: 3 Autosampler Location: 9
Sample ID: cri Date Collected: 12/30/2005 12:05:14 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: cri 104 I/O
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2102349.6 9.85 mg/L 0.010 0.10%
Ni 231.604t 157.1 0.026 Jng/L 0.0005 0.026 mg/L 0.0005 1.86%
C====================================================
Sequence No.: 4 Autosampler Location: 10
Sample ID: icb Date Collected: 12/30/2005 12:09:05 PM
-------
Method: Air Filter Ni
Page
Date: 12/30/2005 12:26:55 PM
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: icb
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2120464.3
-6.2
rpj?
Calib
Cone. Units
9.93 mg/L
-0.001 mg/L
Std.Dev.
0.040
0.0013
Sample
Cone. Units
-0.001 mg/L
Std.Dev. RSD
0.40%
0.0013 127.18%
Sequence No. : 5
Sample ID: icv
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 11
Date Collected: 12/"~ '""'
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
>:12:56 PM
Mean Data: icv
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2080725.7
6166.2
Calib
Cone. Units
9.75 mg/L
1.02 mg/L
!»?•"* *
Std.Dev.
0.032
0.005
Sample
Cone. Units
1.02 mg/L
Std.Dev. RSD
0.32%
0.005 0.50%
Sequence No.: 6
Sample ID: icsab
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 12
Date Collected: 12/30/2005 12:16:18 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: icsab
Analyte
Yb 328.937
li 231.604t
Mean Corrected
Intensity
2022525.0
5917.7
Calib
Cone. Units
9.47 mg/L
0.980 mg/L
— TA tr
A A N
Std.Dev.
0.048
0.0073
Sample
Cone. Units
0.980 mg/L
Std.Dev. RSD
0.51%
0.0073 0.75%
Sequence No.: 7
Sample ID: l£b Ni
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 13
Date Collected: 12/30/2005 12:19:40 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: l£b N
Analyte
Yb 328.937
Ni 231.604t
i
Mean Corrected
Intensity
1955004.8
4523.1
Calib &'
Cone. Units 1
9.16 mg/L
0.749 mg/L
-"$o
2 . I/
Std.Dev.
0.142
0.0049
Sample
Cone. Units
0.749 mg/L
Std.Dev.
0.0049
RSD
1.55%
0. 66%
Sequence No.: 8
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 14
Date Collected: 12/30/2005 12:23:02 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: Irb
Analyte
Yb 328.
Ni 231.
937
604t
Mean Corrected
Intensity
1969448.6
-11.1
Cone.
9.22
-0.002
Calib
Units
mg/L
mg/L ,
&
Std.Dev.
0.149
0.0013
Cone.
-0.002
Sample
Units
mg/L
Std
0.
.Dev.
0013
RSD
1 . 61%
71.21%
Sequence No.: 9
"Sample ID: 110325-1
Autosampler Location: 15
Date Collected: 12/30/2005 12:26:55 PM
-------
Ni
Page
Date: 12/30/2005 12:46:54 EM
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Mean Data: 110325-1
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2003331.9 9.38 mg/L 0.114 >-.iL»
Ni 231.604t 386.8 0.064 mg/L 0.0015 0.064 mg/L 0.0015 2.26%
q^mienae No • 10 Autosampler Location: 16
Sample ?D: lio325-2 Date Collected: 12/30/2005 12:30:48 EM
Analyst: Data ^yP31 Original
initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: 110325-2
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yh 328 937 2009889.4 9.41 mg/L 0.111 l.lbo
Ni 23l!604t 1736:7 0.288 mg/L 0.0003 0.288 mg/L 0.0003 0.10%
Secruence No • 11 Autosampler Location: 17
Sample ID: 110325-3 Date Collected: 12/30/2005 12:34:43 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: 110325-3
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2010062.0 9.41 mg/L 0.122 4^1*
li 231.604t -14.2 -0.002 mg/L 0.0011 -0.002 mg/L 0.0011 47.51%
Secruence No.: 12 Autosampler Location: 18
Sample ID: 110325-4 Date Collected: 12/30/2005 12:38:37 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: 110325-4
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2003577.7 9.38 mg/L 0.178 1-90.
Ni 231.604t 297.5 0.049 mg/L 0.0014 0.049 mg/L 0.0014 2.83%
Sequence No.: 13 Autosampler Location: 19
Sample ID: 110325-5 Date Collected: 12/30/2005 12:42:32 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: 110325-5
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 1997531.7 9.36 mg/L 0.149 ^ °
Ni 231.604t 361.3 0.060 mg/L 0.0015 0.060 mg/L 0.0015 2.56-s
Sequence No.: 14 Autosampler Location: 20
Sample ID: 120034-1 Date Collected: 12/30/2005 12:46:54 EM
-------
Method: Air Filter Ni
Page
Date: 12/30/2005 1:05:23 EM
Analyst:
Initial Sample Wt:
Dilution:
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 120034-1
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2005116.7 9.39 mg/L 0.167 1.78%
Ni231.604t 1050.5 0.174 mg/L 0.0009 0.174 mg/L 0.0009 0.53%
Sequence No.: 15 Autosampler Location: 21
Sample ID: 120034-2 Date Collected: 12/30/2005 12:51:06 EM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Erep Vol:
Mean Data: 120034-2
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2005263.4 9.39 mg/L 0.109 1.16%
Ni 231.604t 1063.0 0.176 mg/L 0.0004 0.176 mg/L 0.0004 0.24%
Sequence No.: 16 Autosampler Location: 22
Sample ID: 120034-3 Date Collected: 12/30/2005 12:55:02 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: 120034-3
Mean Corrected Calib Sample
Analyte Intensity Cone. Units Std.Dev. Cone. Units Std.Dev. RSD
Yb 328.937 2003607.7 9.38 mg/L 0.107 1.14%
Ai 231.604t 3.4 0.001 mg/L 0.0010 0.001 mg/L 0.0010 178.89%
Sequence No.: 17 Autosampler Location: 23
Sample ID: ccv 0.50 Date Collected: 12/30/2005 12:58:58 PM
Analyst: Data Type: Original
Initial Sample Wt: Initial Sample Vol:
Dilution: Sample Prep Vol:
Mean Data: ccv 0.50
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2175552.9
3098.7
Calib
Cone. Units
10.2 mg/L
0.513 mg/L
Std.Dev.
0.02
0.0022
Sample
Cone. Units
0.513 mg/L
Std.Dev. RSD
0.15%
0.0022 0.42%
Sequence No.: 18
Sample ID: ccb
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 24
Date Collected: 12/30/2005 1:02:25 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: ccb
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2163765.3
0.4
Calib
Cone. Units
10.1 mg/L
0.000 mg/L
Std.Dev.
0.07
0.0015
Sample
Cone. Units
0.000 mg/L
Std.Dev. RSD
0.67%
0.0015 >999.9%
-------
Appendix G
Plating Solution Laboratory Reports
-------
SCIENTIFIC CONTROL LABS
CompuFAX
November 11, 2005
Jeff's Project
Lab No:
110076
ELECTROLESS Nl
Dated: 11-1-05
Metallic Nickel
Sodium Hypophosphite
pH
Surface Tension
(dynes/cm)
Room Temp
Conditions 3/4/5/6
RELIABLE
0.81
3.42
4.99
75.0/75.2/75.3
68.6/68.7/68.8
( 190 F.)
Results in ounces per gallon
A.G.
AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
February 8, 2006
Jeffs Project Lab No: 020075
Condition 10
No Wetter
Nickel Solution ABQC (02-01-06)
Metallic Nickel 9.38
Nickel Sulfate 32.74
Nickel Chloride 8.34
Boric Acid 5.33
pH 3.92
Specific Gravity 1.200
Surface Tension
(dynes/cm) '68.0/68.0/68.2 (140F) 58.0/58.1/58.2
Room Temp
Iron (mg/L) 37.7
Condition 13
Wetter
Nickel Solutions ABQC (02-02-06)
Metallic Nickel 9.55
Nickel Sulfate 33.36
Nickel Chloride 8.46
Boric Acid 5.17
pH 4.18
Specific Gravity 1.200
Surface Tension
(dynes/cm) 43.1/43.2/43.4 (140F) 42.1/42.0/42.1
Room Temp
Iron (mg/L) 14.9
A.G. AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
January 20, 2006
Jeff's Project Lab No: 010217
ABQC
Condition 11/12
Nickel Solution NO WETTER 1 -11 -06
Metallic Nickel 8.22
Nickel Sulfate 28.52
Nickel Chloride 7.46
Boric Acid 4.51
pH 4.6
Specific Gravity 1.175
Surface Tension
(dynes/cm) 58.2/58.4/58.7 (140F) 57.3/57.4/57.4
Room Temp
A.G. AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
November 17, 2005
Jeffs Project
Nickel Solution
Metallic Nickel
Nickel Sulfate
Nickel Chloride
Boric Acid
pH
Specific Gravity
Surface Tension
(dynes/cm)
Room Temp
Lab No:
110199
ABQC
Condition 14/15
WETTER 11-7-05
11.40
42.96
7.30
8.00
3.88
1.245
37.6/37.8/37.8
(140F)
37.0/37.1/37.1
Condition 7 Condition 24
Artistic Woods Strike Artistic Woods Strike
No Wetter Wetter
Nickel Solutions 11-09-05 11-10-05
Metallic Nickel
Nickel Chloride
Hydrochloric Acid
Surface Tension
(dynes/cm)
Room Temp
Specific Gravity
3.17
12.70
34.61
60.3/60.3/60.5
1.105
3.34
13.35
33.97
50.9/50.8/50.7
1.105
A.G.
AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
October 4, 2005
Artistic Plating Co. Inc.
405 W. Cherry St.
Milwaukee, Wl. 53212
Attention: Mr. John Tinder Lab No: 100012
Gentlemen:
The solution samples submitted to us on October 3, 2005 have been
analyzed and are reported in ounces per gallon (unless otherwise noted)
as follows:
Conditions 18/19 Conditions 20/21
NO WETTER WETTER
NICKEL SOLNS 9/27-28 9/28-29
Metallic Nickel 8.34 8.42
Nickel Sulfate 30.49 31.34
Nickel Chloride 6.14 5.71
Boric Acid 5.70 6.11
pH 3.5 3.8
Specific Gravity 1.175 1.165
Surface Tension
(dynes/cm)
Room Temp 72.3 32.4
140 F 67.7 30.5
Surface tension measurements were conducted using a tensionmeter.
Please contact us at once if you should have any questions.
Yours very truly,
AG/FAX AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
November 23, 2005
Jeffs Project Lab No: 110323
Conditions 23/25
ELITE
Nickel Solutions 11-16-05
Metallic Nickel 7.73
Nickel Sulfamate 33.16
Nickel Chloride 0.68
Boric Acid 4.72
pH 3.3
Specific Gravity 1.220
Surface Tension
(dynes/cm)
Room Temp 46.1
135f 44.5
Results in ounces per gallon.
A.G. AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
December 8, 2005
Jeffs Project
Lab No:
120033
Nickel Solutions
Metallic Nickel
Nickel Sulfamate
Nickel Chloride
Boric Acid
pH
Specific Gravity
Surface Tension
(dynes/cm)
Room Temp
135f
Condition 26
ELITE
12-01-05
8.51
36.54
0.72
5.41
4.0
1.215
36.1
35.0
Results in ounces per gallon.
A.G.
AUDREY GLIVA
-------
SCIENTIFIC CONTROL LABS
CompuFAX
October 27, 2005
Jeff's Project Lab No: 100304
No Wetter Condition 22
Nickel Solution Elite (10-18-05)
Metallic Nickel 8.59
Nickel Sulfamate 36.75
Nickel Chloride 0.84
Boric Acid 5.62
pH 3.65
Specific Gravity 1.220
Surface Tension
(dynes/cm) 135F 39.0/39.1/39.2
Room Temp
Condition 27 Condition 28-29
Artistic Woods Strike Artistic Woods Strike
No Wetter Wetter
Nickel Solutions 10-17-05 10-20-05
Metallic Nickel 2.43 1.62
Nickel Chloride 9.72 6.48
Hydrochloric Acid 40.70 42.95
Surface Tension
(dynes/cm) 72.9/73.0/73.0 58.6/58.5/58.7*
Room Temp
* Acidic solution destroys wetting agent over time.
Surface tension of this solution measured in field at 38 dynes/cm (w/stalagmometer).
A.G. AUDREY GLIVA
-------
Appendix H
Sample Chain of Custodies
-------
||OD~?(0
'5SS.'koUN AVENUE
HICAGO ,'L 50623-4889
-———
PRESERVATIVE
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CONTROL^LASnBA-r TEL (773}254-2dC6
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-------
S.KOUN AVENUE
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COMF
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3158 S. KOL'N' AVENUE
CHICAGO iL 50623-438S
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TEL (773)254-2406
FAX (773}254.-S66-!
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received by: (Signature)
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-------
COMP
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3*58S.'KOUN AVENUE
-HfCAGO fL 50623-4389
(773)254-2406
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PRESERVATIVE
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-------
SAMPLIG
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(773)254-2406
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COMPANY
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3158S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
TESTIN G
CONSU LTING
CHAIN OF CUSTODY RECORD
Project No.
Project Name
SAMPLER (SIGNATURE)
Station
No.
Station Location
No. of
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Shipping No.:
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-------
COMPANY
SAMPLING ADDRESS
-K VTr
CONTROLS LABORATORIES, INC.
TESTING CONSULTING
3158 S.KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
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DATE
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No. of
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(7) Gallon
(8) VOC Vial
(9) Vials
(10) Other
A-None
B- HNO3
C-H2SO4
D- NaOH
E- Ascorbic
F- Na2S2O3
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-------
COMPANY
SAMPLING ADDKhSS
CONTROL LABORATORIES, INC.
3158 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
TESTING
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roject No.
Project Name
SAMPLER (SIGNATURE)
No. of
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Q-Glass (4) Pint (9) Vials
M-Metal Quart (10) Other
A- None
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Date/Time
Temperature of Samples
Shipping No.:
Remarks:
-------
^56 S. KOL'N AVENUE
CHICAGO ,'L 50623-4889
Www.sciwet.ccrn
TEL (773)254-2406
FAX (773)254-666-1
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COMPANY
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LABORATORIES, INC.
3158S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
TESTING - CONSULTING
CHAIN OF CUSTODY RECORD
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Project Narpe
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(9) Vials
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B- HNO3
C- H2SO4
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-------
Environmental Technology &
Engineering Corp.
13000 W. Bluemound Road
Elm Grove, Wisconsin 53122
: _//fMJei,
ETE Contact _
Phone: 262-784-2434
Fax: 262-784-2436
ETE Project No.
To:
SCL
Sample Media:
Analyze for:
A/,
Requested Analytical Methods: £7^
Attn:
Remarks Re: Conditions/Interferences/Other:
Desired Report Date
Submitted Date
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Relinquished by:
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Date:
Date:
Date:
Date:
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Time: ll-'OD
Time:
Time:
-------
Environmental Technology &
Engineering Corp.
13000 W. Bluemound Road
Elm Grove, Wisconsin 53122
ETE Contact:
Phone: 262-784-2434
Fax: 262-784-2436
ETE Project No.
To:
Sample Media:
Analyze for:
Requested Analytical Methods:
Attn:
Zj -
Remarks Re: Conditions/Interferences/Other:
Submitted Date
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Date: */J(l>'* Time:
Date: '5-7 ^ f iJ~ Time:
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-------
Environmental Technology &
Engineering Corp.
13000 W. Bluemound Road
Elm Grove, Wisconsin 53122
To:
Sample Media:
Analyze for:
Requested Analytical Methods:
ETE Contact:
Phone: 262-784-2434
Fax: 262-784-2436
ETE Project No.
,. ~4i?fip
Attn:
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Remarks Re: Conditions/Interferences/Other:
Desired Report Date
Submitted Date "z
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Sample
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Time:
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-------
COMP,
SAMPLING AC-CRESS,
CONTROL LABORATORIES, INC,
31555. KOUN/3 ,Uc
CHICAGO it 50623-4389
•www.s6weh.ccm
TEL (773)254-2406
FAX (773}254.-SS6J,
TESTING
CONSULTING
CHAIN OF CUSTODY RECORD
-------
SAMPLING ADDRESS
3<55S. KOUN AVENUE
CHICAGO fL 50623-4389
•www.sciwefc.corn
TEL (773)254-2406
FAX (773}254--S661
/ /CONTAINER
PRESERVATIVE
y: gnature)
«eceived by: (Signature)
-------
COft/IF
SAMPLING.ADCRE
"
3158 S. KOL'N AVENUE •
CHICAGO iL 50623-4889
www. sci web. corn
TEL (773)254-2406
FAX (773)254-6661
r-rojeci No. Project Nam
CONTAINER
-------
Project No.
Project .Nane
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3158 S.KOUN AVENUE "
CHICAGO fL 50623-4389
www.sc5wsb.corn
TEL (773)254-2406
FAX (773)254-6661
'CONTAINER PRESERVATIVE
VKOL (6)l/2Ga,. £%£3
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-------
COMPANY
SAMPLING ADDRESS
LABORATORIES, INC
3158 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
3reject No.
Project_Name
SAMPLER (BIGNAI Ukt)
V
ETE
Station
No.
DATE
X3MP.
Tatinrrbesation
of
c
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t
a
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CONTAINER
PRESERVATIVE
A- None
(1)2OZ. (6) 1/2 Gal. B-HNO3
(2) 4 OZ. (7) Gallon C- H2SO4
P-Plastic (3) 1/2 Pint (8) VOC Vial D- NaOH
G-Glass (4) Pint (9) Vials E- Ascorbic
M-Metal (5) Quart (10) Other F-Na2S2O3
G- Other
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ceiMfefflior Laboratory by:
RermquishedJpy^Sjgnature)
>—v—^ A_^-/OxL^>
Relinquished by: (Signature)
Date/Time
Temperature of Samples
Date/Time
Received by: (Signature)
Shipping No.:
-------
COMPANY
SAMPLING ADDRESS
CONTROLS LABORATORIES, INC.
TESTING CONSULTING
3158 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
roject No.
Project Name
AMPLER (SIGNATURE-'
tation
o.
U
DATE
TITCTE-
;ow:
ut
Ti
GRAB
Station Location
No. of
c
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t
a
i
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e
r
s
CONTAINER
(1)20Z.
(2)4OZ.
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
A- None
B-HNO3
C- H2SO4
P-Plastic (3) 1/2 Pint (8)VOCVial D-NaOH
G-Glass (4) Pint
M-Metal (5) Quart
(9) Vials
(10) Other
E- Ascorbic
F- Na2S2O3
G- Other
ViL
i_
IT" )
V
*/l/Br
ITF
V
>r
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
ReiinquihkXdWJ (SigrWure)
Date/Time
Received for Laboratory b
Date/Time
Temperature of Samples
Shipping No.:
Remarks:
-------
COMPANY
SAMPLING ADORES;
ORE
31 58 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
CONTROL LABORATOR.ES, INC.
TESTING
CONSULTING
CHAIN OF CUSTODY RECORD
3reject No.
Project Nam
SAMPLER (SIGNAI Ukb)
">
Station
No.
DATE
. /-NQ_AQ___
aidaALJ
IL JH
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No. of
c
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1 r
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CONTAINER
(1)20Z.
(2)4OZ.
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
A- None
B- HNO3
C- H2SO4
P-Plastic (3) 1/2 Pint (8) VOC Vial D- NaOH
G-Glass (4) Pint
M-Metal (5) Quart
(9) Vials
(10) Other
E- Ascorbic
F- Na2S2O3
G- Other
'Mi
5
X
I
tr^1 ATfiU
a
hM
-X
X
V0bk
fleft&c
X
Relinquished by: (Signature;)
Date/Time
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquis!
nature)
Date/Time
Date/Time
Temperature of Samples
Shipping No.:
Remarks
-------
COMPANY
SAMPLING ADDktSS
CONTROL LABORATORIES, INC.
TESTING CONSULTING
3158 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
Project No.
Project Name
SAMPLER (SIGNATU
Station
No.
DATE
Station Location
No. of
c
o
n
t
a
i
n
e
r
s
CONTAINER
(1)2OZ.
(2)40Z.
P-Plastic (3) 1/2 Pint
Q-Glass (4) Pint
M-Metal (5) Quart
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
(S)VOCVial
(9) Vials
(10) Other
A- None
B- HN03
C- H2SO4 ..
D- NaOH
E- Ascorbic
F- Na2S2O3
G- Other
Gr-S-A
V
A
V
X
X;
V,
V
X
Relinquished by: (Si
Date/Time
• " y
ignature
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinqui
Date/Time
Reiejvetf fctf Laboratory by
Date/Time
O '3-^
Temperature of Samples
Shipping No.:
Rema
L\\
-------
COMPANY I
'V PS!
SAMPLING ADDRESS
ciett
CONTROL
•
-------
COMF
^clett&tlc
Project No. Voject .Nans
3'5flS.KOUN AVENUE
CHICAGO fL 50623^389
•www.scJwet.ccrn
(773)254-2406
(773)254-6661
^^fCUlTof^§
——i i ^ T~ .
eceved by: (Signatur
Remarks:
-------
COMP/^'Y.
SAMPLI. ADCRE3S
3158S. KOL'N,
CHICAGO iL £0623-4389
www.sciweh.ccm
TEL (773)254-2406
CONTRDiy LABORATORIES. INC. FAX (773)
TESTING CONSULTING
I Project No. p-oject!
CHA1N OF CUSTODY RECORD
CONTAINER
PRESERVATIVE
A- 'None
' (J0-20Z. (6}1/ZGal. B-HNO3
(2) A CZ. (7) 3g||on C- H2SC4
P-P!astic (3)-1;2P:ni fS) VOC Via! D-NaOH
G-Glas3 (4) Pint {9} Vials E-Ascorbic
M-Me!a! (5) Quart (IC)Cfher F- K'a2S2O3
G- Ofher
Received by: (Signature)
Received fcr Laboratory by<
Remarks:
: ,
Relinqui
Date/Tin
1-0
Received by: (SignstLTe)
Temperature of Samples Shipping No.:
-------
^r • -L" /.
-^cieHZL+ic
jTojeciNo.
3' 56 S. KOUN AVENUE
CHICAGO ,-L £0623-4389
www.sawefc.com
TEL (773)254-2406
PAX (773)254-366-!
PRESERVATIVE
(•5J-20Z. ,'6>
-------
Ifitfc
3158'S. KOUN AVENUE
CHICAGO fL C0623-4389
•
— .
PRESERVATIVE
TEL (773)2=4-2406
(773J254-S661
££NSULTIN
Date/Time
*y*
Remarks:
Deceived by; (Signature)
——
for Laboratory.by.
mperalureofsampfes Shi
Rejfn^^^
• u=iwjirn- Received
c by: (S/gnaiLTei
ir.-^o
^
-------
COW \jy
SAMPLING. ADDRES
3'5SS.KOUN AVENUE
CHICAGO ,-L 60623-4369
Www.sciweb.com
TEL (773)2=4-2406
FAX (773)254^66-!
CHAJN^FCUSTOD?
~T~ ' —
eceved by; (Signature)
Date/1 me Received
Remarks:
-------
COMPANY
SAMPLING A:
CONTROLS LABORATORIES, INC.
TESTING — CONSU LTING
3158 S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
3roject No.
Project Name
SAMPLER (SIGNATURE)
Station
DATE
u
&AB-
atatiopi- Location
No. of
c
o
n
t
a
i
n
e
r
s
CONTAINER
(1)20Z.
(2)40Z.
P-plastic (3) 1/2 Pint
G-Glass (4) Pint
M'Metal (5) Quart
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
(8) VOC Vial
(9) Vials
(10) Other
A- None
B- HNO3
C- H2SO4
D- NaOH
E- Ascorbic
F- Na2S2O3
G- Other
t-MTt;
11
tut
ELfa
X
MK
Y
(Signature)
Date/Time
ul / JX
foj f (
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
^elinquishdd
'fjSignature)
Date/Time
eived for Laboratory by:
r\
U "^
Date/Time
Temperature of Samples
Shipping No.:
Remarks:
-------
COMPANY
SAMPLING ADDRESS
^
\tf .
vkc
CONTROL^ LABORATORIES, INC.
TESTING CONSULTING
3158 S. KOLIN AVENUE
CHICAGO !L 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
CHAIN OF CUSTODY RECORD
Project No.
Project Name
SAMPlL-k (SIGNATURE)
Station Location
CONTAINER
(1)20Z.
(2)40Z.
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
A- None
B-HNO3
C-H2SO4
p-plastic (3) 1/2 Pint (8) VOC Vial D- NaOH
G-Glass <4)pint
M-Metal (5) Quart
(9) Vials
(10) Other
E- Ascorbic
F- Na2S2O3
G- Other
i
A
tLllT
X
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished joy: (Signature)
I V y
Date/Time
Received for Laboratory by:
Date/Time
Temperature of Samples
Shipping No.:
Remarks:
-------
COMPANY
SAMPLING ADDRESS
£i\te
CONTROL LABORATORIES, INC.
3158S. KOLIN AVENUE
CHICAGO IL 60623-4889
www.sclweb.com
TEL (773)254-2406
FAX (773)254-6661
TESTING
CONSULTING
CHAIN OF CUSTODY RECORD
Project No.
Station
No.
No. of
c
0
n
t
a
i
n
e
r
s
CONTAINER
(1)2OZ.
(2) 4 OZ.
P-Plastic (3) 1/2 Pint
G-Glass (4) Pint
M-Metal (5) Quart
PRESERVATIVE
(6) 1/2 Gal.
(7) Gallon
(8) VOC Vial
(9) Vials
(10) Other
A" None
B- HNO3
C- H2SO4
D- NaOH
E- Ascorbic
F- Na2S2O3
G- Other
]L ^
X
V
to
V
X
lo
X
vc
nquished-by7(Signature)
/
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Reli
b (Signature)
Date/Time
ived for Laboratory by.
Date/Time
Temperature of Samples
Shipping No.:
Remarks:
-------
Appendix I
Process Data Sheets
-------
FROM .'SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20PM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank
Plating Type:
WUJ
L J,
Di
Rectifier Rated Capacity:
Run#
^
J
ConditionsRgcorded Dudtig Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone,
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
'
s:\cngineer\airt8tiiokTest process data wksht,wpd
5 1^ D-fctf
1
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATASHEET
Company Name _
Tank.
Plating Type;
Tank Dimensions:
W
Rectifier Rated Capacity:
Run#
[V W
\&- Or—'
Conditionsjtecoided
^
Freeboard Height:
Plating Solution Temperature
Plating Solution. Nickel Cone.
Plating Solution Boric Acid Cone,
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test-Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
PA 03
Inches
dynes/c
so
Volts
Amperes
A-hr
pcs. \ fa
ft2 J^
mill/test run
J&.-Q min/test run
acriii
sclhi
T
10? w«J
i
s-\engineeAairtstaok lest process data wkshtwpd
-------
FROM :SCIENTIFIC CONTROL LfiBS
FAX NO. :17732546661
Oct. 31 2005 09:20PM PI
NICKEL AIR TEST PROJECT
PROCESS DATASHEET
Plating Type: __
Tank Dimensions: L
Rectifier Rated Capacity:
W
(Unita
OjTgrating ConditioiiLBficgflM nun«R Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone,
mating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
oz/gal\
oz/gal X_
_JpH /
_ dynes/cm /
" " so /
Volts
Amperes
A-hr
A/ft2
min/test run
min/test run
acfiii
scfm
.gpm
s:\cngineer\airtstack lest process data wkshtwpd
-------
FROM : SCIENTIFIC CONTROL LflBS
FfiX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Manic.
Tank Identification,
Tank Dimensions; L
W
Rectifier Rated Capacity:
i
Run#
(TO
H
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
J , , ,
s:\cngineef\airtstaok lest process data wksllt,wpd
A
(Units J
.Inches
. ^
.ojr/gal
oz/gal
dynes/en;
SO
Volts
Amperes
A-hr
mill/test run
min/test nm
%
acfni
scfm
gP"1
-------
FROM : SCIENTIFIC CONTROL LfiBS
FflX NO. :17732546661
Oct. 31 2005 09:20fiM PI
NICKEL AIR TEST PROJECT
PROCESS DATASHEET
Company Name
Tank Identification
Tank Dimensions;
H
Rectifier Rated Capacity;
K\r\
it;
d During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone,
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
~ \1UO
min/test nin
min/test run
%
acfm
sclm
sApngineertai^tack lest process data wksht.wpd
-------
FROM :SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
lank identification
Plating Type;
Tank Dimensions; L __Ju) ^
Rectifier Rated Capacity: _ \$±.
H
(Units >\
----
i)/K
^ During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Inches
07/gal
oz/gal
pll
dynes/er
SO
Volts
Amperes
A-hr
A/ft2
pcs. \
ft2 —>
min/test run
min/test run
actm
scl'm
I
%r\
s:\cngineer\air\stock lest process data wkiht,wp
-------
FROM :SCIENTIFIC CONTROL LflBS
FOX NO. :17732546661
Oct. 31 2005 09:20P)M PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank identification
Plating Type;
Tank Dimensions; L
Rectifier Rated Capacity
: \ V.
Conditions Rftcorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Pitting Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
y w
-(TO1
inches
>
oz/gal
oz/gal
;pu
dynes/err
"so '
|J£ Volts
_j\J(i_ Amperes
s:\cngineeAairVitack lost process (fata wksht.wpd
-------
FROM : SCIENTIFIC CONTROL LflBS
FOX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank Identification
Plating Type; _
Tank Dimensions: L
Rectifier Rated Capacity:
-
Opgmting
.
During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
\\
bz/gal
.pi I
dynes/cm,
"so
[ Volts
Amperes
"A-hr
:A/ft2
II, ft2
|7-L/ min/test run
min/test run
acftii
scfm
.gpm
s;\Qngineer\airtstack lest process data wks!H,wpd
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO, :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank
Plating Type; _,
Tank Dimensions: L
Rectifier Rated Capacity:
Run#_
Operating ConditionLRcg^ed During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
mating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
(Units
Inches
07/gal
_ oz/gal
_"pH
dynes/err/
I'SG
A Volts
_JjOjL Amperes
A-hr
I PCS
ld_.^ ft2
' "-"i. i . .
mm/test ran
min/test nm
'.%
acfm
scfm
n /^ ,
S:\Qiiglneer\air\stack l«* process data wk*t,wpd
^^1 —J—f
-------
FROM : SCIENTIFIC CONTROL LABS
FAX NO. :17732546661
Oct. 31 2005 09:20AM PI
NICKEL AIR TEST PROJECT
PROCESS DATA
Company Name
Tank identification
Plating Type;
Tank Dimensions: L
Rectifier Rated Capacity:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
:t4
_ _ dynes/cm/.
" " SG /
(J..A Volts
JN^_ Amperes
f\?A A-hr
f\JA A/ft2
min/test run
min/test run
acfin
scfni
l(,O PM-fe
<3
s:\engineertairtstaok lest process data wksht
"Q
n
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20ftM PI
NICKEL AIR TEST PROJECT
PROCESS DATASHEET
Company Name
Tank Identification
Tank Dimensions; L
Rectifier Rated Capacity;
noting Conditions
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
,
Inches
.- — j« i • ••
30 F
oz/gal
oz/gal
dynes/cm
SG
^- Amperes
MA A-hr
min/test run
min/test run
%
acfm
scl'rn
gpm
PAD
lest pmcess daw wksht,wp
-------
FROM .'SCIENTIFIC CONTROL LflBS
FflX NO. :17732545661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank identification
Tank Dimensions; L _b_L>
Rectifier Rated Capacity:
W
Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Inches
oz/gal
oz/gal
pll
dynes/cm.
SO
Volts
Amperes
mill/test run
min/test run
%
actm
scfm
III
s:\engintjertairVstack lest Wess data wktlit.wpd
-------
:SCIENTIFIC CONTROL LflBS
FRX NO. :17732546661
Oct. 31 2005 09:20AM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Plating Type:
Tank Dimensions: L.
W
Rectifier Rated Capacity: __L2ik
\
Condition"
ftri Duritig Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated) Q ,
tu-- ^oa. K
'
s:\onginesr\air\stack test proce:
4, . x 9* 73 -—»••> ^ *
1'
Inches
oz/gal\
oz/gal. ^v
dynes/cm/
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
min/test run
min/test run
-------
FROM :SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20RM Pi
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Maine .
<-<
Tank Identification
Plating Type;
n. - T
Tank Dimensions: L
\3-\y
Rectifier Rated Capacity: J _ I
W
w
H
31
(Units
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampcre-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Wi thin Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
3/0
[.M'
6
s:\cngineer\airtstack lest process data wKS
I3o -/HV>
«&/
WS
Amperes
~ A-hr
A/ft2
_pcs.
ft2
_ min/test run
min/test nm
%
acfm
scfm
_gpm
\,ai
-------
FROM :SCIENTIFIC CONTROL LABS
FflX NO, :17732546661
Oct. 31 2005 09:20flM Pi
rsiCKELAU* TEST PROJECT
PROCESS DATA SHEET
Name
Tank Identification,
Tank Dimensions: L _J|(2__ W_
:ity: 1S\)
H
, >.
l5. J
I h )
Rectifier Rated Capacity:
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\engimser\airtstack lust process data wksht-wpd
^Ul^iH,*1
dyn<;s/cm
"SG
' Volts
Amperes
A-hr
^A/ft2
.PCS.
.ft2
min/test ran
mill/test run
acfin
scfm
_gpm
-------
FROM SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT /\
PROCESS DATA SHEET
Company Name ; l v ^ ^—
Tank Dimensions: L
W
Rectifier Rated Capacity
it: \o^L
Operating ConditionsRgcgnied During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH .
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\cngineer\airtstack test process data wksliuwpd
9xci i*"2-
/Hal
(Units_
.MO F
_oz/gal.
_ pll
dynes/cm
"_ SO
\ Volts
Amperes
' A-hr
A/ft2
pcs.
ft2
min/test am
min/test run
%
acfm
scfm
gpm ^A
_ [0^0
-------
FROM : SCIENTIFIC CONTROL LABS
FOX NO. :1773254S6S1
Oct. 31 2005 09:20fiM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
* -
Tank Identification
3
Operating Cnnrlifions Rcco^^ '>mnP Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Plating Type:
fa
Tan* 1 )imensions. L v
Rectifier Rated Capacity: _
•j e
w
uv
^i" H 0^*^3 (Units '«->— ,k^> ^ \)
\HH
s:\cnginwsr\airVstack test process data wksht,wp
-^
T'6'1
a ^7 J Inches
JX}^F
_ oz/gal
_oz/gal.
pll
_dynes/c
*_ SO
Volts
Amperes
A-hr
pcs,
.ft2
min/test mn
_il?O min/test run
acfm
so Cm
gpm
-------
FROM :SCl&iTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL All* TEST PROJECT
PROCESS DATA SHEET
Company Name
w . T
Plating Type:
Mo
Tank Dimensions: L
Rectifier Rated Capacity:
Oggrating C
^ During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
pcs.
ft2
mitt/test am
mm/itest run
acfin
scfm
.gpm
s:\cnBine*rtair\stack lest [irnoess data wkstiLwpd
Jwt
-------
FROM : SCIENTIFIC CONTROL LABS
FfiX NO. :17732546661
Oct. 31 2005 09:20fiM PI
MCKEL AIR TEST PROJECT
TROCISS DATA SHEET
Company Name
Plating Type:
Tank Dimensions: L
W
Rectifier Rated Capacity:
Rintf _ __.
- *LS
H
Operating Conditions Record l^riflg Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
(\v0
\s\
_
mill/test run
min/test i"un
%
acfm
scfm
-10:25
s:\engineer\airtstiick lest pmccss 'dau wkitit-wpd
^
7
-------
FROM :SCIENTIFIC CONTROL LflBS
FOX NO. :17732546661
Oct. 31 2005 09:20flM Pi
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification.
Plating Type;
Tank Dimensions: L
w
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Denkity
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\pngineer\airVitsck Lest praciss data wkstitwpd
qjnits Jig )
dynes/cm
'"___ SG
Volts
Amperes
' A-hr
A/ft2
pcs.
ft2
j PIT min/test run
min/test run
C&L V&
fbf&
-------
FROM :SCIENTIFIC CONTROL LftBS
FRX NO. :17732546S61
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
|i?o
Tank Dimensions
/•J-V
: L _£_ _
k
H
Rectifier Rated Capacity
it: \&\/
Operating Conditions Recorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Atnpere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
JM
3 (.1 ; Inches
W'F
______ oz/gal'
oz/gal
pll
dynes/cm
(AS
Volts
Amperes
A-hr
^A/ft2
pcs.
.ft2
min/test run
min/test nin
acfrn
scfm
.gpm
s:\cngineer\airlitflck test process data wksht.wpd
-------
FROM :SCIENTIFIC CONTROL LflBS
FOX NO. :17732546661
Oct. 31 2005 09:20fiM 'Pi
mCKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Tank Dtawta. L
Rectifier Rated Capacity;
Operating Conditions Recorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
} O)
F
p*1 >
Volts
Amperes
A-hr
>fe
pcs.
.ft2
min/test run
min/test run
acfm
scfm
K«L %0'ij
s:\cngineer\airtstack lestpraccss dau wkshtwpd
-------
FROM :SCIENTIFIC CONTROL LABS
FfiX NO. :17732546S61
Oct. 31 2005 09:20firi PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank Identification
Plating Type:
Tank Dimensions: L
Rectifier Rated Capacity:
Operating Conditions Bc;corded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Sohition Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\cnjjmcer\airtstack test process data wksfit-wpd
)
Inches
. . .
07/gal\
oz/gal. \
_
__ _ dynes/cm/
f 01 min/test run
tlD min/test run
^cku
-------
FROM :SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20fiM PI
413
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification,
Plating Type:
Tank Dimensions: L
Rectifier Rated Capacity:
Freeboard Height:
Plating Solution Temperature
Plating Solution "Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current, Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
>(_ 3'/Inches
i i|Q"" F
oz/gaT
oz/gal
. ^P"
dynes/cm
^_SG
' Volts
Amperes
' A-hr
A/ft2
pcs.
ft2
min/test run
min/test run
.%
acfm
scfm
.g?m
3^— 3;asr ^:5o
N
"m^ IJ
^
:\(inBinwr\airt.ita=k lest process dau wkshuwpd
s:\(i
-------
FROM : SCIENTIFIC CONTROL LABS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name.
Tank:
. •
Tank Dimensions:
Rectifier Rated Capacity:
Run#
T>M)
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Amperes
A-hr
A/ft2
-------
FROM :SCIENTIFIC CONTROL LRBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank identification
0-. ll
s: L_1y-
Tank Dimensions:
Rectifier Rated Capacity;
W
T6|hl
(units
Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Inches
-F
_ oz/gal \
__oz/gal V
_pll )
__ dynes/ci»
_ SG /
_ Volts
_ Amperes
_ A-hr
_A/fe
_pcs.
min/test ntn
min/test run
%
acfm
scfm
I»T m-jiH
s:\enginrtr\aii4tock Lest ifccciidau wks>it,wpd
-------
FROM :SCIENTIFIC CONTROL LflBS
FOX NO. :17732546661
Oct. 31 2005 09:20PM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank Identification,
Plating Type:
- Acv.
sions: L T Q_
Tank Dimensions
Rectifier Rated Capacity:
Run#J^>A
W
a'jro- v-Stf
: Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
dynes/cm
.... J i
SO
O " Volts
Amperes
mill/test run
min/test mn
acfm
scfm
.gpm
s:\ongineSrtaiiAstack WSt proces
-------
FROM : SCIENTIFIC CONTROL LfiBS
FRX NO. :17732546661
Oct. 31 2005 0g:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
Tank Dimensions: L
Rectifier Rated Capacity; _ \^_
Operating ConditjoniRccoided During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
pcs
ft2
mill/test run
min/test run
-------
FROM :SCIENTIFIC CONTROL LflBS
FfiX NO. :1773254SS61
Oct. 31 2005 09:20fiM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company N anie
Tank Identification.
Plating Type;
Tank Dimensions; L
-
Rectifier Rated Capacity; _'0VV__
'
Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Wi thin Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimate 1)
'1-
s:\cngineeAairtstiick test process data wkslltwpd
I
I
FV\a
(Units iV* )
pcs.
ft2
min/test ran
min/test run
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
WkVb [W^J
Tank Dimensions: L f-,\ W
i i
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
/HOD Amperes
>)3
A
trwa J
W/Urft2
\\Q' min/test run
I<5.t7 mm/test run
IVSf- H'.?v)
s:\en2ineer\air\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
LQ
\L
^
Tank Identification^
Plating Type:
Tank Dimensions: L
W
H
Rectifier Rated Capacity:
*
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration o f Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
. (Units
dynes/cm
SG
Volts
Amperes
A-hr
pcs.
ft2
min/test run
min/test run
acfm
scfm
gpm
R-.ot- DW
id'.U- I-.3&
s:\engineer\airN5tacl<: test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
Tank Identification,
Plating Type:
6(Tlf
N
Tani Dimensions: L
W
H
Rectifier Rated Capacity: ^ v 11X^ *&^0
(Units
Rua#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density "*
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
pcs.
ft2
min/test run
min/test run
%
acfm
scfm
s:\engineer\air\stack test process dam wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification
Plating Type:
Tank Dimensions: L T^ W ^ H '^> ^J . (Umts_\A )
Rectifier Rated Capacity: CT o ^
Run# L
Operating Conditions Recorded During Testing:.
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run fV , mm/test run
Duration of Test Run ^3__ min/test run
Capture Efficiency of Ventilation System
Ventilation Rate . _- acfin
Air Agitation Rate ' ANW" scfcl
Solution Circulation Rate (estimated) _ _0J SPm
s:\engineer\air\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Plating Type:
\Nft
Tank Dimensions: L _
W
H
(Units
Rectifier Rated Capacity:
MX
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy P arts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Vft . Volts
HQD Amperes
A-hr
A/ft2
min/test run
rain/test run
% -
acfm
scfm
s:\en°ineer\ai-Astack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
Tani Identification
Plating Type:
KnAcJ flMEul
KiVtU
Tank Dimensions: L_
w
H
(Units \ A )
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
'*' l\ -oA
U-° J Inches
IMP F
oz/gal
oz/gal
pH /
dynes/cpr
SG X
Volts
Amperes
A-hr
AVft2
.ft2
min/test run
Him/test run
.%
acfm
scfm
_gpm
s:\etigineer\airN£tack test process data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name A
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
C
Tanl Identification
Plating Type:
Tank Dimensions: L
W
H (H\) (Units
Rectifier Rated Capacity:
Run#_
Operating Conditions Recorded During Testing:
Freeboard Height:
P lating S o lution Temp eratur e ,
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Volts
Amperes
'A-hr
>S«r
QD
.ft2
mm/test run
min/test run
.%
acfm
scfm
_gpm
s:\engineer\air\stack test process data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification
Plating Type:
Tank Dimensions: L
W
H
(Units
WV
Rectifier Rated Capacity:
Run# ^>
Operating Conditions Recorded During Testing;
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
ft»k Ck &W&
i * \j
&3
&JP-T pcs.
^rq- ft2
ilk
_ min/test run
min/test run
~%
acfm
fovl, <**"/
jW
lib-
3:^-
m
^)
^
s:\engineer\air\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification
lib
Plating Type:
Tank Dimensions: L
w
H
(Units
V
Rectifier Rated Capacity:
.
Operating Conditions Recorded Plains: Testme
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
L|/\jC) Amperes
A-hr
A/ft2
pcs.
min/test run
min/test run
acfm
_|4Di scfm
_gpm
s:\ensineeT\air\stac~k test process data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Taak Identification
Hating TW=:
Tank Dimensions: L
tWK
Rectifier Rated Capacity:^ V
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
,
oz/gal\
oz/gal X
pH >
dynes/cr/
SG -/
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
mm/test run
mm/test run
acfm
scfm
,gpm
s:\engineer\air\stack test process data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
C
ft
Tank Identification
Plating Type:
Tank Dimensions: L
W
H
(Umts
Rectifier Rated Capacity?H^
\
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
\ 1 MVA vW
V I)S J r^i^w
IM1-JSC
F
oz/gal
oz/gal
^PH
d3/nes/c:
"SG /
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
mm/test run
min/test run
s:\engineer\air\stacktestprocess data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
nt
Tank Identification
Plating Type:
NvcUl
Tank Dimensions: L
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing:
1 Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated. Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
' V.
oz/gal \
oz/gal \^
:PH >
dynes/cm/
'SG X
Volts
Amperes
A-hr
^A/fr2
pcs.
> •
mm/test run
1 ^D min/test run
o/.
s:\en2iiieerVir\stacK test process data wksht.wpd
~IW* \6
-------
MCKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name \
1
Tank Identification
Plating Type: lAv^Al
Tank Dimensions: L
(Units
Rectifier Rated Capacity: \ \j
Run#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
5*01
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'^4ffl
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
Tank Identification
Plating Type:
Tank Dimensions : L
Oi
./•2
min/test run
min/test run
'%
acfm
scfhi
-------
FROM : SCIENTIFIC CONTROL LflBS
FPX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company "Name
71
Ac
Tank Dimensions: L
S§
W
^
Rectifier Rated Capacity
Rut»#
: I ^ °
Freeboard Height:
Plating Solution Temperature
Plating Solution "Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total S urface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
61" Off
(Units v
Inches
\1\ "F
oz/gal
_dynes/ctr
"_ SG
' Volts
__ Amperes
A-hr
U Rfs.
-------
FROM : SCIENTIFIC CONTROL LflBS
FPiX NO. : 17732546S61
Oct. 31 2005 03:20fiM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Rectifier Rated Capacity:
(Units, in )
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Pails
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
^
\3'D
KA
pcs.
.ft2
min/test run'
min/test am
!%
acfm
scfrn
.gpm
.^^:o8
->S f ift V.
-------
FROM : SCIENTIFIC CONTROL LABS
F;3X NO. :17732546661
Oct. 31 2005 09:20QM Pi
vote
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank
. — - - — - —
Plating Type:
- T
Tank Dimensions: L
W
w
H
n
Rectifier Rated Capacity: _
gjjjygtig Testing!
Operating Conditions
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Core.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate
S'\cngine«r\airt.itiick test process dau wkshtwpd
Ampere,
" A-hr
A/ft2
pcs.
ft2
min/test run
d-'°' min/test run
i b TI .3,1 // -> />
-------
FROM : SCIENTIFIC CONTROL LfiBS
FflX NO. :177325466S1
Oct. 31 2005 09:20f¥1 PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
PA ^f
Company Name £? ^ l..li—
Identification,
j/"
\
Plating Type:
Tank Dimensions: L
nMm
fllnits
Rectifier Rated Capacity:, i V.
Run*
Operating Coitions Rcr'"-fteri louring Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
a
;f
s data wk5ln.wpd
}
oz/gal
" IT
pll
dynes/cm
Volts
Amperes
pcs.
ft2
min/test run
min/test run
-------
FROM : SCIENTIFIC CONTROL LOBS
FfiX NO. : 17732546661
Oct. 31 2005 09:20RM PI
v\
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank
PlatingType:
Rectifier Rated Capacity:
__.__
J_ (Units JIL__)
noting Condition* Eccnrded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
*•
st
• - •
s:\cngin»ai*itaok lest process data wsT)t>p<
3'Y9")
a to
gAo
Inches
F
dynes/cm
'so
Volts
Amperes
A-hr
.PCS.
.ft2
mill/test run
min/test run
.gpm
ft
#05*
L^
-------
FROM .'SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20RM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name.
N ifrWi
Tank Dimensions; L
-^ ^ W ^rr? H v> I
Rectifier Rated Capacity
U HO -
ity: ') V M K
R
Operating Conditions Recorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Cuirent Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
(Units
Volts
Amperes
A-hr
A/ft2
^_pcs.
.ft2
min/test run'
min/test run
acfm
scfm
_gpm
s:\cngineer\aiiAstflck lest prnccSS data wkshtwpd
MR
-------
FROM .'SCIENTIFIC CONTROL .|_A8S
FflX NO. :17732546661
jcx. 31 2305 09:20fiM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name ^ ._
Tank Identification,
Plating Type:
Tank Dimensions:
W
±
Rectifier Rated Capacity:
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Pkting Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Crul""W <
(Units
iiA
U
u
Volts
Amperes
A-hr
A/ft2
pcs.
.ft2
mill/test run
mm/test run
acftn
scfm
.gPm
s:\engin«iltir\stack last process data wkslitwpd
DV
-------
FROK : SCIENTIFIC CONTROL LflBE
FAX NO. :17732546661
Oct. 31 2085 09:20flM
NICKEL A1K TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification,
Plating Type:
Tank Dimensions:
Rectifier Rated Capacity:
Operating Conditions Recorded During Testing
Freeboard Height:
Plating Solution Temperature
Dating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
1'Mating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
fk,&«"
£0u k*
[&u\\
-------
FROM : SCIENTIFIC CONTROL LPI3S
FflX NO. :17732546661
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name
Plating Type: _
Tank Dimensions:
Rectifier Rated Capacity:
*,. 3-v
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Pails
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Manic
Tank Identification
Plating Type; _
Tank Dimensions: L
Rectifier Rated Capacity;
Run#
min/test nm
min/test run
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone,
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\cngineer\airVitack test process data wks!lt,wpd
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO. : 177325466S1
Oct. 31 2805 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Tank identification
-
Tank Dimensions:
Rectifier Rated Capacity
: J^Y
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
ches
J\
oz/gal \
7
3/cnv.
/
Amperes
A-hr
A/ft2
lllin/test mn
__ i
S1
s:\cnjsine«r\airtstiick lest process data wkshtwptl
-------
FROM : SCIENTIFIC CONTROL LflBS FOX NO. : 17732546661 " Oct. 31 2005 09:20flM PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT
Company Name.
Tank Identification,
Plating Type:
Tank Dimensions: L
t't
Rectifier Rated Capacity:
2> . ?
Freeboard Height: ^ (U&r-'F
Plating Solution Temperature - ^^
Plating Solution Nickel Cone. — QZ/ ,
Plating Solution Boric Acid Cone. ^
Plating Solution PH — dynes/cm
Plating Solution Surface Tension gG
Plating Solution Specific Gravity -^JQ ' Volts
Plating Voltage 'ji^ Amperes
Average Amperage Applied -77^ ^
Calculated Ampere-Hr Usage 3^.. A/ft*
Calculated Cuirent Density "£ pcs.
Number of Dummy Paits Q t ff
Total Surface Area of Plated Parts -^- ^^ mn
Plating Period Within Test Run —— ^^ ^
Duration of Test Run —^ ^
Capture Efficiency of Ventilation System — ^^
Ventilation Rate ~ g(,|-m
Air Agitation Rate 3
Solution Circulation Rate (estimated)
s:\enBineer\airtstaok lest process data wksht,wpd
-------
FROM : SCIENTIFIC CONTROL LfiBS
FflX NO. :17732546661
Oct. 31 2005 09:20flM PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name.
Tank:
Plating Type:
Tank Dimensions; L
W
Rectifier Rated Capacity:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
k)/
dynes/cm
SO
Volts
min/test run
min/test run
acftn
scfm
st llroccs
-------
FROM : SCIENTIFIC CONTROL LflBS
FflX NO, :17732546661
Oct. 31 2005 09:20flM PI
NICKEL MB TEST PROJECT
PROCESS DATA SHEKT
Company Namc
— — — p j
Tank Dimensions; L
w
.H.U
Rectifier Rated Capacity:
Operating CQndjtionsJcgorded During Testing!
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
(Units..
.Inches
07/gal >v
.oz/gal \7
pll /
dynes/cny
'SG *
1-fO Volts
Amperes
ft2
min/test am
min/test run
s:\cnginrtr\aiiVttack lest process daU wkitlt-wpd
-------
FROM :SCIENTIFIC CONTROL LfiBS
FOX NO. :17732546661
Oct. 31 2005 09:20PM PI
A
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
Company Name
Co,
Tank Identification,
Plating Type;
Tank Dimensions; L
W
A )
Rectifier Rated Capacity:
Run#
•*-- VM- i
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
oz/gal
oz/gal.
pll
dynes/cm
mill/test ran
min/test run
acfm
scfffl
_gpm
s:\engincer\aii'\stack lest process data wk
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
p\
Tank Identification
Plating Type:
Tank Dimensions: L
W
H
Rectifier Rated Capacity: ' O Vp n
I: y.jt) "(0'^
* ....... . i 1f A \
Operating Conditions Recorded.During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone:
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Numb er o f Dummy P arts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
A
(fo\U\J
170
s:\engineer\air\stack test process data wkshtwpi
-------
I
J?
4
-t-
4
0.855-
ix
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
Tank Dimensions: L JV W_j>0' _ H
Rectifier Rated Capacity:
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\sngineer\airNstack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
U5
Tank Identification
Plating Type:
Tank Dimensions: L
W
H
(Units 1A
Rectifier Rated Capacity:
Run#
>- I'U
. Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
pcs.
ft2
mm/test run
min/test run
ox
s:\sngineer\airtstack test process daia wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
Tank Dimensions: L
w
(Units_
Rectifier Rated Capacity: \ 0^t?U$
9 Q'JV? -S'.lfo
Run# J? -«•,_, n
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
pcs.
ft2
min/test run
min/test run
s:\engineer\air\stack test process data wkshtwpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
Tank Dimensions: L
Rectifier Rated Capacity: | ^
Run#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Numb er of Dummy P arts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Inches
F, /
oz/gaf\
oz/gal \
PH V
dynes/crjy
SG X
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
min/test run
min/test run
acfm
scfm
gpm
s:\engineeAair\stack test process data wkshtwpd
-------
MCKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
lC>/l x"
Tank Identification t\.b|)J Nvc£j UNljfe
Plating Type: |A]&OJ NiC'W
u
Tank Dimensions: L
w
Rectifier Rated Capacity:
Run* 3 *|V*>
li'.Sl- 'iJl
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
Dl
Amperes
A-hr
A/ft2
pcs.
ft2 .
min/test run
min/test run
s:\enginesr\air\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Comp any Name
Tank Identification
Plating Type:
Tank Dimensions: L
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
' Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy P arts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
min/test run
min/test run
!°/°
acfrn
scfin
_gpm
s:\engineer\2ir\stack test process data wkstit.wpd
-------
MCKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
cr
Plating Type:
Tank Dimensions: L
W
(Sis'
(Units
Rectifier Rated Capacity: \Q N|
Run#_L_ ^"^ - 10'!S
10'-if~ liVi
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
min/test run
min/test run
'%
3.cfm
scfm
gpm
s:\engineerVir\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
Kckl
Tank Dimensions: L
w
Rectifier Rated Capacity:
-*
: t^ V
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating sSolution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts '
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
3
QTD
Inches
F
oz/gal\
oz/gal \
PH >
dynes/en/
SG ^
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
min/test run
min/test run
acfm
scfm
s:\engineer\air\stack test process data wksht.wpd
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
SWW
Plating Type:
Tank Dimensions: L
W
^
(Units
^^
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
s:\engineer\air\staclctestprocess data wkshtwpd
-------
Appendix J
Stack Test Schematics
-------
ARTISTIC PLATING - MILWAUKEE
CONDITIONS 18, 19, 20, & 21 STACK
SAMPLE POINT LOCATIONS
FIGURE 1
SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
12 in.
5ft.
3ft.
Notes: 24 sampling points to be used on this
round duct; 12 points along each of two
perpendicular traverses.
(bend in
duct to
scrubber)
(transition
from the
vent hood)
-------
ARTISTIC PLATING - MILWAUKEE
CONDITIONS 7, 24, 27, & 28 STACK
SAMPLE POINT LOCATIONS
FIGURE 2
SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.7
1.2
1.8
2.5
3.6
6.4
7.5
8.2
8.8
9.3
9.5
Stack Diameter:
5ft.
T
2ft.
10 in.
Notes: 24 sampling points to be used on this
round duct; 12 points along each of two
perpendicular traverses.
(bend in
duct to
scrubber)
(transition
from the
plenum)
-------
ABQC - MILWAUKEE
CONDITIONS 10, 11, 12, 13, & 14 STACK
SAMPLE POINT LOCATIONS
FIGURE 3
SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
1 ft.
3ft.
12 in.
Notes: 24 sampling points to be used on this
round duct; 12 points along each of two
perpendicular traverses.
(branch
entry from
other area
(transition
from the
plenum)
-------
ELITE FINISHING - MILWAUKEE
CONDITIONS 22, 23, & 25 STACK
SAMPLE POINT LOCATIONS
FIGURE 4
SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
4ft.
12 in.
Notes: 24 sampling points to be used on this
round duct; 12 points along each of two
perpendicular traverses.
(bend into
common
stack)
(transition
from the
plenum)
-------
RELIABLE PLATING - CHICAGO
CONDITIONS 22, 23, & 25 STACK
SAMPLE POINT LOCATIONS
FIGURES
SAMPLE PORT LOCATION
Point
Stack Diameter:
Distance (ft.
1
2
3
4
5
6
7
8
9
10
11
12
0.5
0.9
1.6
2.4
3.4
4.8
8.7
10.1
11.1
11.9
12.6
13.0
13.5 in.
7 in.
28 in.
Notes: 24 sampling points to be used on this
round duct; 12 points along each of two
perpendicular traverses.
(bend into
common
stack)
(transition
from the
plenum)
-------
-------
Enviromr 1
Technology 4
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