EPA/600/R-07/068
                                   April 2007
  Testing Nickel Emissions from
    Metal Finishing Operations
               (Phase 2)

             Final Report
National Risk Management Research Laboratory
     Office of Research and Development
     U.S. Environmental Protection Agency
          Cincinnati, Ohio 45268

                Prepared by

     Scientific Control Laboratories, Inc.
         3158 S. Kolin Avenue
             Chicago, IL 60623

       Under USEPA Order Number: EP-C-05-016

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                                    FOREWORD
The U.S. Environmental Protection Agency (EPA) is charged by Congress with protecting the
Nation's land, air, and water resources. Under a mandate of national environmental laws, the
Agency strives to formulate and implement actions leading to a compatible balance between
human activities and the ability of natural systems to support and nurture life. To meet this
mandate, EPA's research program is providing data and technical support for solving
environmental problems today and building a science knowledge base necessary to manage our
ecological resources wisely, understand how pollutants affect our health, and prevent or reduce
environmental risks in the future.

The National Risk Management Research Laboratory (NRMRL) is the Agency's center for
investigation of technological and management approaches for preventing and reducing risks
from pollution that threaten human health and the environment. The focus of the Laboratory's
research program is on methods and their cost-effectiveness for prevention and control of
pollution to air,  land, water, and subsurface resources; protection of water quality in public water
systems; remediation of contaminated sites, sediments and ground water; prevention and control
of indoor air pollution; and restoration of ecosystems. NRMRL collaborates with both public and
private sector partners to foster technologies that reduce the cost of compliance and to anticipate
emerging problems. NRMRL's research provides solutions to environmental problems by:
developing and  promoting technologies that protect and improve the environment; advancing
scientific and engineering information to support regulatory and policy decisions; and providing
the technical support and information transfer to ensure implementation of environmental
regulations and  strategies at the national, state, and community levels.

This publication has been produced as part of the Laboratory's strategic long-term research plan.
It is published and made available by EPA's Office of Research and Development to assist the
user community and to link researchers with their clients.
                                  Sally Gutierrez, Director
                                  National Risk Management Research Laboratory
                                           11

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                               PREFACE

This report provides an overview of nickel plating air emissions and waste release issues
within the nickel plating industry.  It is the objective of this report to assist the metal
finishing community and specifically, those involved with nickel plating operations, with
the management of environmental challenges that result from wastes that are potentially
generated by nickel plating. Both the  electrodeposition and electroless deposition
processes for nickel plating have been profiled to examine resultant waste streams and
potential releases.

Nickel plating practitioners are challenged to making a high-quality product that meets
the needs of the customer while being competitive within the market. Furthermore,
nickel plating practitioners must deal with environmental, regulatory, and technical,
requirements to protect human health and the environment. This report serves as an
advisory to nickel plating practitioners by providing technical information to reduce
environmental impacts and lower the liabilities associated with environmental releases.
                                NOTICE

This document has been reviewed in accordance with the U.S. Environmental Protection
Agency's peer and administrative review policies and approved for publication. Mention
of trade names or commercial products does not constitute endorsement or
recommendation for use.
                       ACKNOWLEDGMENTS

This report was developed for the U.S. Environmental Protection Agency (EPA),
Sustainable Technology Division in Cincinnati, Ohio under Contract No.: EP-C-05-016.
David Ferguson, Office of Research and Development (ORD), National Risk
Management Research Laboratory (NRMRL), Multimedia Technology Branch
coordinated the preparation of this report, and is the co-author with Frank Altmayer, Jeff
Zac and Jolie Zac of Scientific Control Laboratories, Inc. of Chicago, Illinois.
                                    in

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                               Table of Contents
                                                             Page Number
Section 0.0
Section 1.0

Section 2.0

Section 3.0

Section 4.0

Section 5.0

Section 6.0

Section 7.0
Foreword
Preface
Notice
Acknowl edgments
Table of Contents
Abstract

Project Description and Objectives

Project Organization

Procedure

Discussion of Sampling and Analytical Procedures

Summary of Results

Discussion of Results
Conclusions

Appendix A:
Appendix B:

Appendix C:
Appendix Dl
Appendix El
Appendix F:
Appendix G:
Appendix H:
Appendix I:
Appendix J:
11
iii
iii
iii
iv
v

1

6

7
12

28

36
                            Calculation Worksheets for Nickel Stack Emissions
                            Calculation Worksheets for Ambient Nickel Concentrations and
                            Field Log Sheets
                            Photographs
                           -2:  Stack Testing Field Data Sheets and Calibration Sheets
                           -4: Laboratory QA/QC Data for Stack Testing Samples
                            Laboratory QA/QC Data for Ambient Air Samples
                            Plating Solution Laboratory Report
                            Sample Chain of Custodies
                            Process Data Sheets
                            Stack Test Schematics
                                          iv

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ABSTRACT:

Nickel emissions from electroplating operations are of concern to EPA.  Therefore, EPA has
determined that it would be useful and important to obtain actual nickel emission data from
nickel plating operations using EPA-Approved testing methods (both Method 29 and Method
306A).  The five nickel plating processes tested in this project were: Electroless Nickel, Rack
Watts Nickel, Barrel Watts Nickel, Nickel Sulfamate, and Wood's Nickel Strike Plating. In
addition, by modifying some of the operating parameters (i.e. surface tension, agitation methods,
etc.), EPA can determine the impact of these operational changes on nickel emissions.

The stack testing was conducted over a two year  span from June of 2004 through January of
2006. Based on the stack testing results, it was concluded that:

          Nickel emissions from typically-operated Rack Watts Nickel and Rack Nickel
          Sulfamate tanks (wetting agent, no mesh pad, air agitation) are not very significant
          (<0.05 mg/dscm).

          Nickel emissions from uncontrolled and vented Electroless Nickel, Barrel Nickel, and
          Wood's Nickel Strike plating are significant (greater then 0.1 mg/dscm), but can be
          significantly reduced (49% to 92%) by employing eductors, wetting agents, or simple
          mesh pads.

       -  Wetting agents, simple mesh pads, and eductors can be used to reduce nickel
          emissions from these processes with varying degrees of success. Simple mesh pads
          were found to be the most favorable because they outperformed wetting agents and
          eductors, are less expensive, and are totally external to the plating process (no impact
          on the plating chemistry).

Although the results of the study indicate that USEPA Method 3 06 A and
USEPA Method 29 provide similar results when  measuring nickel emissions from Electroless
Nickel, Watts Nickel, and Wood's nickel strike, further testing needs to be conducted on a
controlled process or conducted simultaneously to determine whether Method 306A truly is an
acceptable alternative to Method 29 for measuring nickel emissions from nickel plating
processes in general.

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Section 1.0    PROJECT DESCRIPTION AND OBJECTIVES

Purpose and Background

The nickel plating industry is a large part of the metal finishing community in the United States.
It consists of job shops (independently owned plating businesses) and captive shops (metal
finishing operations contained in larger manufacturing facilities). There are over 3,000 U.S. job
shops that average fewer than 50 employees each with annual sales of, approximately $5 million.
Captive shops that support larger manufacturing facilities can vary in size depending on their
role within the company. The metal finishing industry is regulated for environmental protection
and occupational health and safety due to the nature of the processes and materials required to
satisfy industrial and public consumer demand. Nearly all manufactured products require some
type of surface finishing. Consumers demand products that have aesthetic appeal, will not
deteriorate, and have durability. The nickel plating industry provides a product that improves
appearance,  slows or prevents corrosion, changes magnetic properties, and increases strength and
resistance to wear for manufactured parts and products.

Most of the nickel plating industry is located in or near major metropolitan areas and may
generate air  emissions, water discharges, and solid wastes that add to overall pollution concerns.
Pollution abatement costs and expenditures for the metal finishing industry comprise nearly 20%
of its budget.  Industry representatives are working together with government, trade associations,
and professional organizations to encourage technological  advances that lead to more efficient,
cleaner production while reducing waste generation and control costs.

Nickel plating is most commonly applied though the utilization of aqueous chemical reagents by
means of electroplating or via a chemical reducing agent (a process that is referred to as
electroless plating). Typical constituents of nickel electroplating solutions include nickel sulfate
(or nickel sulfamate) nickel chloride, and boric acid, along with inorganic or organic additives
that modify the crystal structure of the nickel deposit. While a variety of formulations for nickel
plating exists, the Watts, Woods, and Sulfamate processes  comprise the majority of the
formulations used by the metal finishing industry.  Also, electroless nickel is used throughout the
industry and these process solutions are based on nickel sulfate plus a reducing agent containing
boron or phosphorus.  The phosphorus-based solutions produce nickel alloy deposits ranging
from about 4% to about  12% phosphorus.

Nickel emissions from electroplating operations  are of concern to EPA. Air  emission estimation
for electroplating is described in EPA's AP42 Manual.  As part of this manual, the AP42 states:
"Emissions from plating operations other than chromium electroplating can  be estimated using
the  emission factors and operating parameters for chromium electroplating." Based on this
theory, EPA developed a computer  based Metal Finishing Facility Risk Screening Tool
(MFFRST) which estimates emissions from electroplating operations.  The tool is believed to be
very accurate for chromium emissions, however, there was a need to validate air emissions for
other metals such as nickel.

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In Phase I of this project, it was determined that the MFFRST Model that used the AP42
methodology was not very accurate in estimating nickel emissions from nickel plating
operations. Therefore, EPA has determined that it would be useful and important to obtain more
actual nickel emission data from nickel plating operations to improve AP42 estimates using
EPA-Approved testing methods (both Method 29 and Method 306A).

In addition, by modifying some of the operating parameters from one test to another within the
plating process (i.e. surface tension, agitation methods, etc.) and then comparing the test results,
EPA can determine the effects of these operating parameters on nickel emissions.

Process, Site, Facilities Tested

Actual data was collected by stack testing various types of nickel plating processes, operating
under several different conditions, using EPA-Approved procedures. Similar testing was also
conducted in Phase 1 of this project in 2004.

For Phase 2, the exhausted air from five different types of nickel plating processes was sampled
and analyzed for nickel in order to obtain the nickel emissions from each process.  These nickel
plating processes were all production lines located in actual plating facilities.  Each nickel
plating process was tested several times under various conditions in order to observe the effects
of that condition on nickel emissions. There were a total of twenty-three (23)  actual stack tests
conducted during this phase.  The nickel plating processes that were tested were: Electroless
Nickel Plating, Rack Watts Nickel Plating, Barrel Watts Nickel Plating, Rack  Nickel Sulfamate
Plating, and Rack Woods Nickel Strike Plating.  The various conditions under which each of
these processes was tested are summarized in the Table 1.

Some nickel plating processes were tested more (varying more operating conditions) than other
nickel  plating processes (i.e. Rack Watts Nickel is tested under more operating conditions than
Woods Nickel Strike).  The total number of stack tests (23) was based solely on the budget of the
project. The decision on which plating processes were tested more than others was based on the
popularity of that process in the industry.  In other words, Rack Watts Nickel is far more
common in the industry than Woods Nickel Strike so more emphasis (i.e. more conditions were
varied) was given to Rack Watts Nickel.

The testing sites for each of these nickel plating processes were as follows:

1. Electroless Nickel Plating

Facility:       Reliable Plating Company
Site:          1538 West Lake Street
              Chicago, IL 60607

2. Rack Watts Nickel Plating

Facility:              America's Best Quality Coatings

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Site:          1602 S. First Street
              Milwaukee, WI 53204

3. Barrel Watts Nickel Plating

Facility:       Artistic Plating Company
Site:          405 W. Cherry Street
              Milwaukee, WI 53212

4. Rack Nickel Sulfamate Plating

Facility:       Elite Finishing, LLC
Site:          3270 S. 3rd Street
              Milwaukee, WI 53207

5. Rack Woods Nickel Strike Plating

Facility:       Artistic Plating Company
Site:          405 W. Cherry Street
              Milwaukee, WI 53212

The six (6) stack tests that were completed on nickel plating processes as Phase 1 of this project
are also included in Table 1 (identified as "Completed - Phase 1").

The actual nickel emission results from Phase 1 and Phase 2 were also used to estimate the
effects of several plating operating parameters on nickel emissions. Based on the operating
conditions selected and summarized in Table 1, we were able to estimate the effects of the
following operating conditions/parameters  on nickel emissions:

                    air agitation versus pump (eductor) agitation
                    the use of wetting agents to control the surface tension of the plating
                    solution
                    the use of simple mesh pads on the exhaust hood to control splashing
                    the ratio of nickel  emissions attributed to electrolysis (electroplating)
                    versus attributed to barrel transfer (entrainment from splashing) in barrel
                    plating
                    the ratio of nickel  emissions attributed to plating versus attributed to
                    agitation and evaporation in electroless nickel plating
                    the type of stack testing used  (Method 29 versus Method 306A)

Table 2 summarizes these selected process parameters and which tests were compared to each
other when estimating the effects of the selected parameter.

The data collected in Phase 1 was also used in Phase 2 to compare nickel emissions from various
nickel processes and  from same nickel processes operated under different conditions.  The results

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from Phase 1 and Phase 2 are comparable because identical sampling and testing methodologies
was used in both phases (i.e. Method 29, three individual test runs per stack test, etc.) and
because, in many cases, the same nickel plating site was tested in both Phase 1 and Phase 2
(except under different operating conditions).

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          TABLE 1
USEPA Nickel Project Process Summary

#
1
2
3
4
5
6

8
9
10
11
12
13
14
15
16
17
18
19
20
21

22
23
25
26

27
28
7
24
29


***

Process
Electroless Nickel
Electroless Nickel
Electroless Nickel
Electroless Nickel
Electroless Nickel
Electroless Nickel
NA
Rack Watts (bright) NA
Rack Watts (bright) NA
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Barrel Watts (dull)
Barrel Watts (bright)
Barrel Watts (dull)
Barrel Watts (dull)
Barrel Watts (dull)
Barrel Watts (dull)

Rack Sulfamate
Rack Sulfamate
Rack Sulfamate
Rack Sulfamate

Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack)


Surface Tension/
Wetting Agent
NA
NA



NA
Yes
Yes (30s) Yes
Yes (30s) No
No (45-60)
No (45-60)
No (45-60)No
Yes (30s) No
Yes
Yes
Yes (33) Yes
No (50s) Yes
No (45-60) Yes
No (45-60)
Yes (30s) No
Yes (30s) No

Yes (30s)
Yes (30s) Yes
Yes (30s) No
Yes (30s)
No
No (50-60)No
Yes (30s) Yes
No (50-60)No
Yes (30s)
Yes (30s)

Yes
Air Agitation/
Mesh Pad
No
No



No



Yes
Yes
No





Yes
No








No
No
Yes

No


Absolutely no barrel transfer during testing





Air
Air
Air




Air




Air
Air

NA

NA
NA
NA
NA

Air


Air

NA
NA
NA

Eductor



Eductor
Eductor
Air


Eductor
Eductor
Air
Air
Eductor



NA






Eductor
Eductor



NA


NA















High




High
High

High

High

High


High
High
High
High

High
High
High
High
Tank
Loadin;
Low
Low
High
High
High
High


High
High
High
High
High



High

High

High







High






                                         Status
                                                           Site
                                                                         Method
Completed- Phase 1
Completed- Phase 1
Phase 2 (USEPA-A)
Phase 2 (USEPA-B)
Phase 2 (SCL 3)
Phase 2 (SCL 4)
Completed- Phase 1
Completed- Phase 1
Phase 2 (USEPA- C)
Phase 2 (SCL 1)
Phase 2 (SCL 10)
Phase 2 (USEPA- D)
Phase 2 (SCL 2)
Phase 2 (SCL 2)
Completed- Phase 1
Completed- Phase 1
Phase 2 (USEPA-E)
Phase2(SCL-9)***
Phase 2 (USEPA-F)
Phase2(SCL-8)***
Phase 2 (SCL-5)
Phase 2 (SCL- 7)
Phase 2 (USEPA-G)
Phase 2 (USEPA-G)
Phase 2 (USEPA-I)
Phase 2 (USEPA-H)
Phase 2 (SCL-6)
Phase2(SCL-ll)
Phase 2 (USEPA-H)
Reliable
Reliable
Reliable
Reliable
Reliable
Reliable
SiteB
SiteB
ABQC
ABQC
ABQC
ABQC
ABQC
ABQC
Artistic
Artistic
Artistic
Artistic
Artistic
Artistic
Elite
Elite
Elite
Elite
Artistic
Artistic
Artistic
Artistic
Artistic
Method 29
Method 306A
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 306A
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 29
Method 306A
Method 29
Method 29
Method 29
Method 29
Method 306A

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TABLE 2
Nickel Plating Process Operating Condition/Parameter

Air Agitation versus Pump (Eductor) Agitation

The Use of Wetting agents

The Use of Simple Mesh Pads in Exhaust Hood

The Ratio of Nickel Emissions Attributed to Electrolysis
(electroplating) Versus Attributed to Barrel Transfer (entrainment
from splashing) in Barrel Plating

The Ratio of Nickel Emissions Attributed to Plating Versus
Attributed to Agitation/Evaporation in Electroless Nickel Plating

The Type of Stack Testing Method Used (Method 29 versus
Method 3 06 A)
Tests Compared to
Evaluate the Affect of the
Condition/Parameter on Nickel Emissions
3-4, 5-6
8-9, 10-11, 13-14
22-23
(Electroless Nickel)
(Rack Watts)
(Rack Sulfamate)

8-12, 10-13, 11-14,
16-17, 18-20, 19-21,
27-28, 7-24
(Rack Watts)
(Barrel Watts)
(Rack Woods Strike)

4-5, 3-6
11-12,9-13,8-14
16-20 17-18
23-25
7-27, 24-28
(Electroless Nickel)
(Rack Watts)
(Barrel Watts)
(Rack Sulfamate)
(Woods Nickel)

17-19, 16-21
(Barrel Watts)

1-6,
(Electroless Nickel)

1-2
14-15
22-26
28-29
(Electroless Nickel)
(Rack Watts)
(Rack Sulfamate)
(Rack Woods Strike)

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Project Objectives

The objectives of this project were to 1) develop actual nickel air emission data using EPA-
Approved Methods 29 and 306A that may also be used in the future to establish regulations
for nickel emissions and/or revise the AP-42 Methodology and consequently the MFFRST
Model, 2) compare the total nickel emissions obtained using EPA Method 29 and EPA
Method 306A to determine whether Method 306A is a viable alternative to Method 29 for
determining nickel emissions, and 3) evaluate the factors that affect nickel emissions such as
surface tension, product loading, type of process solution and type of agitation used in the
process.

Section 2.0   PROJECT ORGANIZATION

Contacts

Organization                     Contact

USEPA                         David Ferguson             (513-569-7518)
Scientific Control Laboratories, Inc. Frank Altmayer/Jeff Zak     (773-254-2406)
Artistic Plating Company          John Lindstedt             (414-271-8138)
ABQC Company                 Matthew Kirchner           (414-649-4900)
Elite Finishing                   Jaime Maliszewski          (414-489-9710)
Reliable Plating Company         Jim  Greenwell              (312-421-4747)
ETE                            Michael Huenink           (262-784-2434)

QA Managers

Linda Kenny
Scientific Control Laboratories, Inc.
3158 S. Kolin Avenue
Chicago, IL 60623
773-254-2406

Lauren Drees
EPA QA Manager

Project Participants and Responsibilities

Name                                        Responsibility

David Ferguson, USEPA                        USEPA Project Manager

Frank Altmayer, SCL                           Project Manager

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Name
                          Responsibility
Jeff Zak, P.E., SCL
Linda Kenny, SCL


Michael Huenink, ETE



John Lindstedt, Artistic

Jaime Maliszewski, Elite

Matthew Kirchner, ABQC

Jim Greenwell, Reliable

Chicago Plastics

Serfilco
                          Planning Coordination,
                          Sample Collection, Sample Custody,
                          Physical Measurement, Process
                          Measurements, Data Validation, Data
                          Reduction, Report Preparation

                          Analytical Measurements,
                          QA Manager

                          Sample Collection, Physical
                          Measurements, Process
                          Measurements

                          Testing Site Contact

                          Testing Site Contact

                          Testing Site Contact

                          Testing Site Contact

                          Mesh Pad Supplier

                          Eductor Supplier
Section 3.0
PROCEDURE
General Approach and Testing Methodology

Three (3) test runs were conducted on each of the twenty-three (23) different nickel plating
operations/conditions listed in Table 1 in order to measure the nickel concentration in the air
emitted from each of these processes. Twenty (20) of the tests were conducted in accordance
with EPA-Approved Method 29 of 40 CFR Part 60 Appendix A-8 (A copy of Method 29 is
included in Appendix A). All applicable operating parameters were observed and recorded
throughout the tests (i.e current density, temperature of plating solution, amperage, plating
solution concentration, tank dimensions, etc.).

The nickel emissions from the remaining three (3) processes/conditions were measured in
accordance with Method 306A of 40 CFR Part 63, Appendix A (with a couple of minor
deviations detailed in Section 4.0).  A copy of Method 306A of 40 CFR Part 63 Appendix A
is included in Appendix B of this QAPP. The purpose of these tests was to compare the
results obtained from Method 29 and Method 3 06A.

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The stack sampling was conducted during normal plating operations at the selected facilities.
Since normal plating operations at job-shop electroplating facilities are inherently non-steady
state, the stack sampling did not rely on steady state conditions of the plating operations.

In order to ensure that the ventilation systems on each of the nickel plating processes were
operating efficiently (capturing and exhausting all of the nickel emissions from the process),
the ambient air near each process was also monitored/tested during the test runs. The
ambient air was tested with two (2) OSHA-approved internal air monitors at each of the
processes. The arithmetic mean of the two results was compared to OSHA worker exposure
limits for nickel in order to grade the efficiency of the ventilation systems. If the average
nickel concentration in the ambient air was below OSHA worker exposure limits for nickel,
the ventilation system for that specific process was  deemed efficient.

Sampling/Monitoring Points

       1)    Sampling Port Locations for Nickel Emissions Testing
             The locations of the sampling ports in the exhaust stacks of each of the five
             individual nickel plating processes were determined in accordance with
             Section 8.1.2 of Method 29 of 40 CFRPart 60 Appendix A-8. Section 8.1.2
             of Method 29 references Section 8.2.1 of Method 5 of 40 CFRPart 60
             Appendix A which further references Method 1 of 40 CFR Part 60 Appendix
             A. Section 11.0 of Method 1 states that the sampling ports must be positioned
             at least two (2) stack or duct diameters downstream and a half diameter
             upstream from any flow disturbance. The exhaust systems from all five nickel
             plating testing sites were constructed so that they met this sampling port
             location requirement.

             The sampling point locations were recorded into the field log sheets included
             with Appendix D of this report.

       2)    Traverse Point Locations for Nickel Emissions Testing
             The location of the sampling (traverse) points within the exhaust stacks of
             each of the five individual nickel plating processes were determined in
             accordance with Section 11.0 of Methods 1 and 1A of 40 CFR Part 60
             Appendix A. Method 1 is to be used for ducts with diameters greater than 12
             inches. Method 1A is to be used for round ducts with a diameter less than 12
             inches. The traverse point locations  were documented and recorded on the
             field log sheets located in Appendix  D of this report.

       3)    Location of Ambient Air Monitors
             The ambient air monitors used to determine the effectiveness of the
             ventilation systems of each of the five nickel plating processes were
             positioned on stands or taped to columns at the perimeter of the nickel plating
             tanks.

       4)    Frequency of the  Sampling Events:

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             Three (3) stack tests were conducted at each of the 29 testing conditions listed
             in Table 1 with the exception of Condition 13 in which processing problems
             limited the testing to one (1) stack test (See page 32 for a detailed
             explanation). Otherwise, all three test runs were conducted within the same
             day under similar operating conditions.
Section 4.0   DISCUSSION OF SAMPLING/ANALYTICAL PROCEDURES

Sampling Procedures

The sampling procedures described in Section 8.0 of EPA Method 29 of 40 CFR Part 60
Appendix A-8 (which further references Section 8.5 of Method 5 of 40 CFR Part 60
Appendix A-3) were followed when sampling the air emitted from twenty (20) of the twenty
three nickel plating process scenarios listed in Table 1 for Phase 2. A copy of Method 5 of
40 CFR Part 60 Appendix A-3 was included in Appendix G of the approved QAPP.

The following parameters were recorded from each nickel plating processes throughout the
testing/sampling:

                        Temperature of Plating Solution
                    -   Current Density (where applicable)
                    -   Plating Bath Concentration, including surface tension
                        Tank Dimensions
                        Amperage/Voltage (where applicable)
                    -   Types  of Parts being Plated
                        Plating Time
                        Freeboard Height
                    -   Air Agitation Rate (where applicable)
                        Solution Circulation Rate

After the samples were collected from each test run, each sample container was marked with
the following data:

                        Nickel Plating Process Type
                        Site Location
                    -   Date
                    -   Run#

Scientific Control Laboratories was responsible for completing the chain of custodies for all
the samples taken at the site(s). The samples were in the custody of Scientific Control
personnel at all times from each site to the Scientific Control Laboratories where they were
analyzed for nickel.  There was no splitting of the samples.  Scientific Control Laboratories
was responsible for all sampling  and analysis.  Environmental Technology and Engineering
was subcontracted to supply the sampling equipment and calibration of sampling equipment.
                                         10

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Stack Testing Using USEPA Method 306A

The sampling procedure described in Section 8.0 of EPA Method 306A of 40 CFR Part 63
Appendix A (Included in Appendix C of approved QAPP) was followed when sampling the
air emitted from three of the twenty three nickel plating process scenarios listed in Table 1
(with the exception of the minor deviations listed below)..

The following factors were recorded from the nickel plating processes throughout the
Method 306A testing/sampling:

                       Temperature of Plating  Solution
                       Plating Bath Concentration
                       Tank Dimensions
                    -   Types of Parts being Plated
                       Freeboard
                       Air Agitation Rate (where applicable)
                       Solution Circulation Rate

After the samples were collected from each test run, each  sample container was marked with
the following data:

                    -   Nickel Plating Process Type
                       Site Location
                    -   Date
                    -   Run#

Scientific Control Laboratories, Inc. (SCL) was responsible for completing the chain of
custodies for all the 306A samples taken at the site.  The samples were in the custody of SCL
personnel at all times from the site to the SCL laboratory  where they were analyzed for
nickel. There will be no splitting of the samples. SCL was responsible for all sampling and
analysis; there were no subcontractors involved in this part of the project.

Modifications to Sampling Procedures in Method  306A

There were a few deviations to the EPA-Approved Method 306 A Procedure for this project.
These modifications were discussed in the approved Quality Assurance Project Plan (QAPP)
and include the following:

1) Section 8.1.1.9.1 B Instead of using 0. IN NaOH or 0. IN NaHCO3 as absorbing solution
   in the first impinger of the sampling train, a mixture of 5% HNO3 and 10% H2O2 was
   used. This absorbing solution is the recommended absorbing solution for nickel as
   stipulated in EPA-Approved Method 29 of Appendix A of 40 CFR Part 60.

2) The current Method 306A (dated October 17, 2000) is a revision of the original version
   of Method 306A (dated January 25,  1995). The author of the original method (Frank
                                         11

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   Clay of the USEPA) has been very critical of the new method. Mr. Clay has written an
   article, A Revised Method 306A- Second Review and Critique, that details the errors,
   omissions, and superfluous material that are found in the new 3 06A Method and offers
   some recommendations on how to improve the current method. After reading Mr. Clay's
   article and based on our experience of performing Method 306A, Scientific Control
   Laboratories concurred with Mr. Clay's opinion and included the following applicable
   recommendations (minor deviations) when using Method 306A.

   1.  A rocker switch was used to start and stop the sampling train instead of a bypass
       valve.
   2.  All runs were performed in a single day.
   3.  The cotton ball in the third impinger was omitted from the sampling train.
   4.  When recovering the sample, the tubing and nozzle (and the tubing between the first
       and second impinger) was rinsed three times in each direction with the absorbing
       solution instead of two.

A copy of Mr. Clay's article that justifies these recommendations is located in Appendix D of
the approved QAPP. It is SCL's opinion that these proposed modifications are minor
deviations that, in no way, affected the accuracy of the sampling results.

Ambient Air Monitoring

The sampling procedures as detailed in Section 5 (specifically Method 5.4) of OSHA-
Approved Method ID-121 were followed when monitoring the internal air near the five (5)
nickel plating processes. This sampling was conducted during all twenty-three (23) tests.  A
copy of OSHA Method ID-121 is included in Appendix F of the QAPP.  Scientific Control
Laboratories calibrated the air sampling pumps prior to each sampling.

Method 29 and Method 306A Field Blanks

Field Blanks were used to determine the quantity, if any, of nickel contamination in the
virgin scrubbant (HNO3/H2O2) and rinse (HNO3) materials.  The scrubbant material is used
to capture the nickel emitted from the various nickel plating processes. The  rinsejnaterial is
used to rinse the probe and scrubbers after the testing.  The nickel concentration present in
the virgin scrubbant and rinse materials, if any, is subtracted from the nickel concentrations
obtained from the actual testing.

Before testing, batches of virgin scrubbant and rinse materials were formulated at Scientific
Control Laboratories.

Laboratory Analyses

The samples obtained from the stack testing were analyzed for nickel in accordance with the
methods detailed in Section 11.0 of Method 29 of 40 CFR Part 60 Appendix A or Section  11
of Method 3 06A of 40 CFR Part 63 Appendix A. The analyses were conducted by Atomic
Absorption-AA (Section 11.1.2 of Method 29). Only total nickel emissions were measured
                                         12

-------
from the various nickel plating processes using Method 29. Particulates were not measured
as part of this project.

The samples obtained from the OSHA internal air monitoring were analyzed for nickel in
accordance with Section 6 of OSHA-Approved Method ID-121.  The analyses were
performed by ICAP-AES.

The QA/QC program(s) described in Sections 9.0 and 10.0 of Method 29 of 40 CFR Part 60
Appendix A-8 and Method 306A of 40 CFR Part 63 Appendix A were followed when
sampling the nickel plating system stacks.  The QA/QC program described in Sections 9.0
and 10.0 of Method 29 of 40 CFR Part 60 Appendix A were followed when analyzing the
resultant samples for nickel.

The laboratory QA/QC data for the stack testing samples is included in Appendix E of this
report.

The QA/QC program described in Section 6 of OSHA-Approved Method ID-121  was
followed when analyzing the filter samples from the internal air monitoring for nickel.  The
laboratory QA/QC data for the ambient air samples is included in Appendix F of this report.

Section 5.0  SUMMARY OF RESULTS

The results of the project are presented in the following tables:

                    Table 3.    Summary of Nickel Emissions Obtained from Phase 1 and Phase
                               2 Stack Testing

                    Table 4.    Comparison of Nickel Emissions (Air Agitation versus Eductors)

                    Table 5.    Effects of Wetting Agents on Nickel Emissions

                    Table 6.    Effects of Mesh Pads on Nickel Emissions

                    Table 7.    Effects of Barrel Transfer on Nickel Emissions from Watts Nickel
                               Barrel Plating

                    Table 8.    Effects of Product Loading on Nickel Emissions from Electroless
                               Nickel Plating

                    Table 9.    Nickel Emissions Method 29 Compared to Method 306A

                    Table 10A-10E
                               Operating Parameters Observed During Stack Testing for Nickel
                               Emissions

                    Table 11.   Ambient Air Nickel Concentrations Observed During Stack
                               Testing
                                         13

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The data presented in Table 3 is the actual nickel emission concentrations from each of the
three (3) individual test runs from all twenty-nine conditions (29) that were tested (including
the six conditions tested as part of Phase 1). The nickel emission concentrations were
calculated using the analytical data obtained in accordance with the Method 29 Stack Testing
procedure (or the  equivalent Method 306A Stack Testing Procedure) and were performed in
accordance with Section 12 of Method 29 of 40 CFR Part 60 Appendix A-8 (or the equivalent
Section 12 of Method 306A depending on which method was used for the sampling).  The data
used for these calculations for the twenty-three Phase 2 testing conditions is included in
Appendix A of this report. The data used for the calculations for the six Phase 1 testing
conditions is included in Appendix A of the Final Phase 1 Report. The average of the three (3)
test runs for each  of the twenty-nine (29) conditions is also reported in Table 3.

The data presented in Table 4 summarizes the effects of air agitation versus eductors on nickel
emissions in electroless nickel, Watts nickel, and nickel sulfamate solutions based on the
testing comparison protocol listed in Table 2.

The data presented in Table 5 summarizes the effects of wetting agents on nickel emissions in
Watts nickel, nickel sulfamate, and Woods nickel strike solutions based on the testing
comparison protocol listed in  Table 2.

The data presented in Table 6 summarizes the effects of mesh pads on nickel emissions in
electroless nickel, Watts nickel, nickel sulfamate,  and Woods nickel strike solutions based on
the testing comparison protocol  listed in Table 2.

The data presented in Table 7 summarizes the effects of barrel transfer on nickel emissions
from Watts nickel barrel plating based on the testing comparison protocol listed in Table 2.

The data presented in Table 8 summarizes the effects of product loading on nickel emissions
from Electroless Nickel Plating based on the testing comparison protocol listed in Table 2.

The data presented in Table 9 are the  stack test results obtained from testing the same process
(electroless nickel, Watts nickel, nickel sulfamate, and Woods nickel strike) using two different
sampling procedures (EPA Method 29 and EPA Method 306A).

The data presented in Table 10A through 10E are  the individual nickel plating process
operating parameters that were recorded during the stack tests.

The data presented in Table 11 are the ambient air nickel concentrations as calculated  using the
analytical  data obtained in accordance with OSHA-Approved Method ID-121.  These
calculations were performed in accordance with Section 7 of OSHA-Approved Method ID-
121. The  OSHA eight (8) hour, time-weighted average PEL for nickel is also included in the
table for comparison purposes. The data used for these calculations are included in Appendix B
of this report.
                                           14

-------
                                                                                 TABLE 3
                                                 Summary of Nickel Emissions Obtained from Phase 1 and Phase 2 Stack Testing
Surface Tension/
Process
Electroless Nickel
Electroless Nickel (306A)
Electroless Nickel
Electroless Nickel
Electroless Nickel NA
Electroless Nickel
NA
Rack Watts (bright) NA
Rack Watts (bright) NA
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright)
Rack Watts (bright) (306A)

Barrel Watts (dull)
Barrel Watts (bright)
Barrel Watts (dull)
Barrel Watts (dull)***
Barrel Watts (dull)
Barrel Watts (dull)***

Rack Sulfamate
Rack Sulfamate
Rack Sulfamate
Rack Sulfamate (306A)

Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack)
Woods Strike (Rack) (306A)

1
lits for the surface tension value
Wetting Agent*

NA


No
NA No
Yes
Yes (38) Yes
Yes (38) No
No (58)
No (57)
No (57) No
Yes (42) No
Yes (37)
Yes (37)

Yes (34) Yes
No (57) Yes
No (68)
No (68)
Yes (31) No
Yes (31)

Yes (39)
Yes (44) Yes
Yes (44) No
Yes (35)
No
No (73) No
Yes (30s) Yes
No (61) No
Yes (30s)
Yes (40-50s)
No

in the parenthMas
1 Mesh Pad





No



Yes
Yes
No


Yes


No
Yes
No








No

Yes

No


is dynes/cm





Air
Air
Air




Air


Air
Air

Air


NA
NA
NA
NA
NA
NA

Air


Air

NA
NA
NA
NA
Air Agitation/
Eductor



Eductor
Eductor
Air


Eductor
Eductor


Eductor

Air









Eductor
Eductor






NA










High




High


High
High

High


High
High
High
High
High
High

High


High

High
High
High
High
Tank
Loading
Low
Low

High
High
High


High
High


High

High









High
High






High




Run#l
0.478
0.060
0.011
0.024
0.142
0.124

0.048
0.016
0.043
0.057
0.051
0.015
0.003
0.014

0.080
0.975
0.009
0.056
0.009
0.023

0.022
0.018
0.004
0.031

0.614
0.129
0.063
0.048
0.400




Run #2
0.126
0.311
0.006
0.012
0.192
0.313

0.044
0.027
0.003
0.012
0.133
NA
0.004
0.008

0.061
1.495
<0.005
0.019
0.004
0.007

0.011
0.013
0.006
0.061

0.282
0.162
0.081
0.077
0.165



Results (mg/dscm)
Run #3
0.220
0.381
0.005
0.004
0.111
0.505

0.032
0.028
0.016
0.005
0.056
NA
0.003/0.037/0.008
0.012

0.118
0.921
0.023
0.228
0.012
0.009

0.010
0.020
0.006
0.053

0.515
0.252
0.236
0.071
0.218




Aver a;
0.275
0.251
0.007
0.013
0.148
0.314

0.041
0.024
0.021
0.025
0.080
0.015
0.011
0.011

0.086
1.130
0.012
0.101
0.008
0.013

0.014
0.017
0.005
0.048

0.470
0.181
0.127
0.065
0.261



1*
2*
3
4
5
8*
9*
10
11
12
13
14
15

16*
17*
18
19
20
21

22
23
25
26

27
28
7
24
29

*   Phase 1
* * The unit
*** Absolutely no barrel transfer during testing
                                                                                    15

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                                       Table 4
             Comparison of Nickel Emissions (Air Agitation versus Eductors)
Process:

Electroless Nickel
(No Mesh Pad)
6vs5
Electroless Nickel
(Mesh Pad)
3 vs4
Rack Watts
(No Mesh Pad, Wetting Agent)
8vs9
Rack Watts
(Mesh Pad, No Wetting Agent)
11 vslO
Rack Watts
(Mesh Pad, Wetting Agent)
14 vs 13
Rack Sulfamate
(No Mesh Pad, Wetting Agent)
22 vs 23
 Air Agitation
     0.124
     0.313
     0.505
     0.314
     0.011
     0.006
     0.005
     0.007

     0.048
     0.044
     0.032
     0.041

     0.057
     0.012
     0.005
     0.025

     0.003
     0.004
0.003/0.037/0.008
     0.011

     0.022
     0.011
     0.010
     0.014
Eductors

  0.142
  0.192
  0.111
  0.148

  0.024
  0.012
  0.004
  0.013

  0.016
  0.027
  0.028
  0.024

  0.043
  0.003
  0.016
  0.021

  0.015
   NA
   NA
  0.015

  0.043
  0.003
  0.016
  0.017
Results reported in mg/dscm
                                         16

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                                      Table 5
                    Effects of Wetting Agents on Nickel Emissions
No Wetter
0.051
0.133
0.056
0.080
0.043
0.003
0.016
0.021
0.057
0.012
0.005
0.025
0.975
1.495
0.921
1.130
0.009
<0.005
0.023
0.012
0.056
sfer) 0.019
0.228
0.101
0.614
0.252
0.515
0.470
0.063 (0.089)*
0.081 (0.159)*
0.236
0.127 (0.161)*
Wetter
0.048
0.044
0.032
0.041
0.015
NA
NA
0.015
0.003
0.004
0.003/0.037/0.008
0.011
0.080
0.061
0.118
0.086
0.009
0.004
0.012
0.008
0.023
0.007
0.009
0.013
0.129
0.162
0.252
0.181
0.048
0.047
0.071
0.065
Process:

Rack Watts
(No Mesh Pad, Air)
12vs8
Rack Watts
(Mesh Pad, Eductor)
10 vs 13
Rack Watts
(Mesh Pad, Air)
11 vs!4
Barrel Watts
(No Mesh Pad)
17vsl6
Barrel Watts
(Mesh Pad)
18vs20
Barrel Watts
(No Mesh Pad, No Transfer)
19vs21
Wood Strike
(No Mesh Pad)
27 vs 28
Wood Strike
(Mesh Pad)
7vs24
Results reported in mg/dscm
* Results adjusted to compensate for cfm difference between Condition 7 and 24 (See Table
10E)
                                        17

-------
                                           Table 6
                          Effects of Mesh Pads on Nickel Emissions
No Mesh Pad
0.142
0.192
0.111
0.148
0.124
0.313
0.505
0.314
0.051
0.133
0.056
0.080
0.016
0.027
0.028
0.024
0.048
0.046
0.032
0.041
0.080
0.061
0.118
0.086
0.975
1.495
0.921
1.130
0.018
0.013
0.020
0.017
0.614
0.282
0.515
0.470
0.129
0.162
0.252
0.181
Mesh Pads
0.024
0.012
0.004
0.013
0.011
0.006
0.005
0.007
0.057
0.012
0.005
0.025
0.015
NA
NA
0.015
0.003
0.004
0.003/0.037/0.008
0.011
0.009
0.004
0.012
0.008
0.009
O.005
0.023
0.012
0.004
0.006
0.006
0.005
0.063 (0.089)*
0.081(0.159)*
0.236
0.127 (0.161)*
0.048
0.077
0.071
0.065
Process:

Electroless Nickel
(Eductor)
5 vs 4
Electroless Nickel
(Air)
6 vs 3
Rack Watts
(No Wetting Agent, Air)
12 vs 11
Rack Watts
(Wetting Agent, Eductor)
9vsl3
Rack Watts
(Wetting Agent, Air)
8vsl4
Barrel Watts
(Wetting Agent)
16 vs 20
Barrel Watts
(No Wetting Agent)
17 vs 18
Nickel Sulfamate
(Wetting Agent, Eductor)
23 vs 25
Wood Strike
(No Wetting Agent)
27vs7
Wood Strike
(Wetting Agent)
28 vs 24
Results reported in mg/dscm
* Results adjusted to compensate for cfm difference between Condition 7 and 27 (See Table 10E)
                                              18

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                                       Table 7
     Effects of Barrel Transfer on Nickel Emissions from Watts Nickel Barrel Plating

Process:                       Barrel Transfer     No Barrel Transfer

Barrel Watts                        0.975                  0.056
(No Wetting Agent)                 1.495                  0.019
17vsl9                           0.921                  0.228
                                   1.130                  0.101

Barrel Watts                        0.080                  0.023
(Wetting Agent)                     0.061                  0.007
16vs21                            0.118                  0.009
                                   0.086                  0.013
Results reported in mg/dscm
                                          19

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                                       Table 8
      Effects of Product Loading on Nickel Emissions from Electroless Nickel Plating

Process:                     Low Tank Loading     High Tank Loading

Electroless Nickel               0.478(0.290)*             0.124
(NoMeshPad)                  0.126(0.078)*             0.313
1 vs 6                          0.220(0.135)*             0.505
                               0.277 (0.167)*             0.314
Results reported in mg/dscm
* Results adjusted to compensate for cfm difference between Condition 1 and 6 (See Table 10A)
                                         20

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                                       Table 9
                Nickel Emissions Method 29 Compared to Method 306A

Process:                        Method 29         Method 306A

Electroless Nickel                 0.478                 0.080
(No Mesh Pad)                    0.126                 0.311
1 vs 2                            0.220                 0.381
                                 0.277                 0.251

Rack Watts                       0.003                 0.014
(Wetting Agent, Mesh Pad, Air)     0.004                 0.008
14vsl5                     0.003/0.037/0.008            0.012
                                 0.011                 0.011

Rack Sulfamate                   0.022                 0.031
(Wetting Agent, No Mesh Pad)     0.011                 0.061
22 vs 26                          0.010                 0.053
                                 0.014                 0.048

Wood's Strike                     0.129                 0.400
(Wetting Agent, No Mesh Pad)      0.162                 0.165
28 vs 29                          0.252                 0.218
                                 0.181                 0.216
Results reported in mg/dscm
                                         21

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        Table 10A.  Operating Parameters Observed During Stack Testing of Electroless Nickel Process
Surface
Tension
35.0
35.0
35.0
39.1
39.1
39.1
68.7
68.7
68.7
68.7

68.7

68.7

68.7
68.7
68.7
68.7
68.7
68.7
Nickel Content
(oz/gal)
0.77
0.77
0.77
0.85
0.85
0.85
0.81
0.81
0.81
0.81

0.81

0.81

0.81
0.81
0.81
0.81
0.81
0.81
Time Actual
Plating (min)*
30
12
12
90
60
0
115
115
105
120

120

120

120
120
120
114
120
120
#of
Parts
88
40
166
3
1080
0
72-416
108-126
1-126
2,400
(barrel)
2,400
(barrel)
2,400
(barrel)
1****
1****
1****
15-100
i****
i****
Freeboard
Height (in)**
4
3
3
3
4
4
8
8
8
8

8

8

8
8
8
8
8
8
Average Surface
Area Plated (ft2)
25.7
5.56
23.0
0.52
13.0
0
5.8-22.3
27-31.5
12-31.5
17.7

17.7

17.7

12.0
12.0
12.0
3-16
12.0
12.0
Ventilation
(cfm)
1,214
1,240
1,227
NA
NA
NA
1,776
1,860
1,860
1,999

2,023

2,037

2,003
2,003
2,027
2,039
1,984
1,929
Emission
(mg/m3)
0.478
0.126
0.220
0.060
0.311
0.381
0.011
0.006
0.005
0.024

0.012

0.004

0.142
0.192
0.111
0.124
0.313
0.505
Condition 1, Run #1***
Condition 1, Run #2***
Condition 1, Run #3***

Condition 2, Run #1***
Condition 2, Run #2***
Condition 2, Run #3***

Condition 3, Run #1
Condition 3, Run #2
Condition 3, Run #3

Condition 4, Run #1

Condition 4, Run #2

Condition 4, Run #3
Conditions, Run#1
Condition 5, Run #2
Condition 5, Run #3

Condition 6, Run #1
Condition 6, Run #2
Condition 6, Run #3
* Out of 120 minute testing period
** Measured from vent to solution level (or foam blanket level, if applicable)
*** Phase 1 Testing
****! Dummy Part
                                                             22

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                 Table 10B. Operating Parameters Observed During Stack Testing of Rack Watts Nickel Process
Current Density
Amps
295
300
300
288
280
276
210
210
210
230
210
210
240
240
180
130
130
130-180
125-200
120-200
0
200
200-240
120-240
(Amps/ft2)
42.9
42.9
42.1
41.1
39.4
40.0
20-26
20-45
30
28.8
20.0
20-26
25.7
25.7

18.6
18.6

17-20
17-20
0
17
17-20
20-30
Time Actual
Plating (min)*
100
100
100
100
100
100
88
84
86
100
100
88
109
105
95
114
101
100
105
96
0
98
92
96
Surface
Tension***
38
38
38
38
38
38
58
58
58
57
57
57
57
57
57
42
42
42
37
37
37
37
37
37
Freeboard
Height (in)**
9-10.5
9.5-10.5
9.5
9.5
9.5
9.5
9
9
9
9
9
6
9
9
9
9
9
9
9
9
9
9
9
9
Ave Surface
Area Plated (ft2)
7.0
7.0
7.0
7.0
7.0
7.0
8.0-10.5
4.5-10.5
7.0
8.0
10.5
8.0-10.5
9.3
9.3

7.0
7.0

7.4-11.7
6-11.7
0
11.7
11.7-12.0
4.0-12.0
Nickel

Content (cfm)
Ventilation
10.9
10.9
10.9
10.9
10.9
10.9
9.4
9.4
9.4
8.2
8.2
8.2
8.2
8.2
8.2
9.6
9.6
9.6
11.4
11.4
11.4
11.4
11.4
11.4
261
271
264
272
275
262
2,190
2,200
2,171
2,168
2,184
2,193
2,350
2,362
2,355
2,158
2,161
2,159
2,114
2,112
2,129
NA
NA
NA
Emissior
(mg/m3)
0.048
0.044
0.032
0.016
0.027
0.028
0.043
0.003
0.016
0.057
0.012
0.005
0.051
0.133
0.056
0.015
0.037
0.008
0.003
0.004
0.003
0.014
0.008
0.012
Condition 8, Run #1****
Condition 8, Run #2****
Condition 8, Run #3****

Condition 9, Run #1****
Condition 9, Run #2****
Condition 9, Run #3****

Condition 10, Run #1
Condition 10, Run #2
Condition 10, Run #3

Condition 11, Run #1
Condition 11, Run #2
Condition 11, Run #3

Condition 12, Run #1
Condition 12, Run #2
Condition 12, Run #3

Condition 13, Run #1
Condition 14, Run #4
Condition 14, Run #5

Condition 14, Run #1
Condition 14, Run #2
Condition 14, Run #3

Condition 15, Run #1
Condition 15, Run #2
Condition 15, Run #3
 * Out of 120 minute testing period
 ** Measured from vent to solution level (or foam blanket level, if applicable)
 *** dynes/cm measured with tensiometer.
 **** Phase 1 Testing
                                                                 23

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               Table IOC. Operating Parameters Observed During Stack Testing of Barrel Watts Nickel Process
Surface
Tension
34
34
34
57
57
57
68
68
68
68
68
68
31
31
31
31
31
31
Current Density Amps Time Actual
(Amps/ft2)
3.35-3.78
3.50-3.72
3.50-3.72
1.82
1.82
1.82-2.46
5.28-7.46
5.28
5.28
5.28
5.28
5.28
1.56-16.9
5.28
5.28
5.28
5.28
5.28
Plating (min)
480-540
500-560
500-560
700
700
600-700
300-400
400
400
400
400
400
100-600
400
400
400
400
400
110
105
107
117
114
113
110
118
118
120
120
120
88
106
116
120
120
120
#of
Freeboard
Ave Surface
* Barrels*** Height (in)** Area Plated (ft
3
3
2
2
3
3
4
3
3
1
1
1
5
3
3
1
1
1
5
5
5
8.0
8.5
9
8
8
8
8
8
8
8
8
8
8
8
8
143
143
143
384
384
244-384
40-76
76
76
76
76
76
36-322
76
76
76
76
76
Nickel
2) Content
8.4
8.4
8.4
9.8
9.8
9.8
8.3
8.3
8.3
8.3
8.3
8.3
8.4
8.4
8.4
8.4
8.4
8.4
Ventilation
(cfm)
1,738
1,748
1,782
1,752
1,603
1,608
1,081
1,545
1,642
1,778
1,674
1,542
1,463
1,521
1,462
1,621
1,661
1,597
Emissions
(mg/m3)
0.080
0.061
0.118
0.975
1.495
0.721
0.009
O.005
0.023
0.056
0.019
0.228
0.009
0.004
0.012
0.023
0.007
0.009
Condition 16, Run #1****
Condition 16, Run #2****
Condition 16, Run #3****

Condition 17, Run #1****
Condition 17, Run #2****
Condition 17, Run #3****

Condition 18, Run #1
Condition 18, Run #2
Condition 18, Run #3

Condition 19, Run #1
Condition 19, Run #2
Condition 19, Run #3

Condition 20, Run #1
Condition 20, Run #2
Condition 20, Run #3

Condition 21, Run #1
Condition 21, Run #2
Condition 21, Run #3
* Out of 120 minute testing period
** Measured from vent to solution level (or foam blanket level, if applicable)
*** Number of barrels plated during testing time period.
**** Phase  1 Testing
                                                               24

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             Table 10D. Operating Parameters Observed During Stack Testing for Rack Nickel Sulfamate Process
urrent Density
(Amps/ft2)
Time Actual
Plating (min)
Surface
Tension***
Freeboard
Height (in)**
Average Surface
Area Plated (ft2)
Nickel
Content

(cfm)
Emission
(mg/m3)
Ventilation
39.6-61.9
31.9-75.5
27.5-66.9
35.1-61.9
34.8-56.3
37.2-61.9
26.4-59.7
27.7-47.7
41.7
35-61.9
16.9-49.5
25-61.9
96
96
96
98
90
64
75
45
99
88
77
85
39
39
39
44
44
44
44
44
44
35
35
35
8
9
9
9
9
9
9
9
9
9
9
9
14.7-26.6
5.56-26.6
14.7-26.4
9.4-24.0
17.8-23.0
9.4-24.50
9.40-22.7
9.40-24.0
24.0
9.4-26.6
9.4-24.0
17.8-26.6
8.59
8.59
8.57
7.73
7.73
7.73
7.73
7.73
7.73
8.51
8.51
8.51
3,789
3,950
3,815
4,237
4,011
4,024
3,706
3,568
3,639
NA
NA
NA
0.022
0.011
0.010
0.018
0.013
0.020
0.004
0.006
0.006
0.031
0.061
0.053
Condition 22, Run #1
Condition 22, Run #2
Condition 22, Run #3

Condition 23, Run #1
Condition 23, Run #2
Condition 23, Run #3

Condition 25, Run #1
Condition 25, Run #2
Condition 25, Run #3

Condition 26, Run #1
Condition 26, Run #2
Condition 26, Run #3
* Out of 120 minute testing period
** Measured from vent to solution level (or foam blanket level, if applicable)
*** dynes/cm measured with tensiometer.
                                                              25

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               Table 10E.  Operating Parameters Observed During Stack Testing for Wood's Nickel Strike Process
Condition?, Run#1
Condition 7, Run #2
Condition 7, Run #3

Condition 24, Run #1
Condition 24, Run #2
Condition 24, Run #3

Condition 27, Run #1
Condition 27, Run #2
Condition 27, Run #3

Condition 28, Run #1
Condition 28, Run #2
Condition 28, Run #3

Condition 29, Run #1
Condition 29, Run #2
Condition 29, Run #3
Current Density
(Amps/ft2)
25.6
25.6
25.6
25.6
25.6
25.6
4.9-25.6
25.6
25.6
25.6
25.6
25.6
25.6
25.6
25.6
Time Actual
Plating (min)*
120
120
120
120
120
120
119
120
120
120
120
120
120
120
120
Surface
Tension***
61
61
61
37-40
37-40
37-40
73
73
73
37-40
37-40
37-40
40-50
40-50
40-50
                                                                        Freeboard    Ave Surface
                                                                        Height (in)**  Area Plated (ft2)
                         Nickel
8.5
8.5
8.5

8.5
8.5
8.5

8.5
8.5
8.5

8.5
8.5
8.5

8.5
8.5
8.5
  12.5
  12.5
  12.5

  12.5
  12.5
  12.5

12.5-51.3
  12.5
  12.5

  12.5
  12.5
  12.5

  12.5
  12.5
  12.5
bntent      (cfm)
    Ventilation
 3.17         1,155
 3.17         1,610
 3.17          818
 3.34
 3.34
 3.34

 2.43
 2.43
 2.43

 1.62
 1.62
 1.62

 1.62
 1.62
 1.61
850
886
867

872
859
879

860
887
892

NA
NA
NA
          Emissions
          (mg/m3)

             0.063
             0.081
             0.236
0.048
0.077
0.071

0.614
0.282
0.515

0.129
0.162
0.252

0.400
0.165
0.218
* Out of 120 minute testing period
** Measured from vent to solution level (or foam blanket level, if applicable)
*** dynes/cm measured with tensiometer.
                                                                   26

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                     Table 11. Ambient Air Nickel Concentrations
Condition 3 (Reliable -
Condition 3 (Reliable -

Condition 4 (Reliable -
Condition 4 (Reliable -

Condition 5 (Reliable -
Condition 5 (Reliable -

Condition 6 (Reliable -
Condition 6 (Reliable -

Condition 10 (ABQC -
Condition 10 (ABQC -

Condition 11 (ABQC -
Condition 11 (ABQC-

Condition 12 (ABQC -
Condition 12 (ABQC -

Condition 13 (ABQC-
Condition 13 (ABQC-

Condition 14 (ABQC -
Condition 14 (ABQC -

Condition 15 (ABQC-
Condition 15 (ABQC -

Condition 18 (Artistic
Condition 18 (Artistic

Condition 19 (Artistic
Condition 19 (Artistic

Condition 20 (Artistic
Condition 20 (Artistic


Nickel Concentration
Ambient Air (mg/m3)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
East)
West)
North)
South)
North)
South)
North)
South)
0.0062
0.0053
0.0060
0.0053
0.0069
0.0063
0.0156
0.0122
0.0065
0.0012
0.0199
0.0029
0.0657
0.0074
0.0694
0.0047
0.0062
0.0043
0.0041
0.0013
0.0025
0.0031
0.0004
0.0004
0.0011
0.0009
OSHA Nickel
Concentration
Limit (mg/m3) V
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00

Adequa
entilatu
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
                                         27

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                  Table XI. Ambient Air Nickel Concentrations (Cont.)
                           Nickel Concentration
                           Ambient Air (mg/m3)
             OSHA Nickel
             Concentration
          Adequate
             Limit (mg/m )  Ventilation
Condition 21 (Artistic - North)
Condition 21 (Artistic - South)

Condition 22 (Elite - North)
Condition 22 (Elite - South)

Condition 23 (Elite - North)
Condition 23 (Elite - South)

Condition 25 (Elite - North)
Condition 25 (Elite - South)

Condition 26 (Elite - North)
Condition 26 (Elite - South)

Condition 7 (Artistic - East)
Condition 7 (Artistic - West)

Condition 24  (Artistic - East)
Condition 24  (Artistic - West)

Condition 27  (Artistic - East)
Condition 27  (Artistic - West)

Condition 28  (Artistic - East)
Condition 28  (Artistic - West)

Condition 29 (Artistic - East)
Condition 29 (Artistic - West)
0.0008
0.0008

0.0026
0.0046

0.0036
0.0089

0.0014
0.0017

0.0064
0.0064

0.1259
0.0139

0.0676
0.0120

0.3085
0.0398

0.1831
0.0054

0.2119
0.0133
1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00
Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes

Yes
Yes
                                          28

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Section 6.0    DISCUSSION OF RESULTS

Table 3

The results presented in Table 1 summarize the nickel emission data obtained from both Phase 1
and Phase 2 of this project.  The results from each of the three individual test runs along with the
average of the three tests runs from each condition tested are reported in the table. All of the
results were obtained using Method 29 stack testing except those identified as Method 306A.

Based on these results, it is apparent that the typically operated Rack Watts Nickel and the Rack
Nickel Sulfamate processes (wetting agent, no mesh pads,  air agitation) emit very little nickel;
less than 0.05 mg/dscm. These concentrations are not much higher than the MACT hexavalent
chromium limits that are based on the use of expensive composite mesh pad systems to reduce
the chromium emissions.  These results were expected due to the high efficiency of the Watts
Nickel and Nickel Sulfamate plating process (very little gassing). Furthermore, the Rack Watts
Nickel and the Rack Nickel Sulfamate solutions are typically operated with some kind of wetting
agent employed in order to maintain the quality of the plating (reduce pitting, etc.). Therefore,
platers need to add wetting agents to these solutions for quality purposes; the pollution control
effect is a secondary benefit.

Nickel emissions being emitted from uncontrolled Wood's Nickel Strike, Barrel Nickel, and
Electroless Nickel plating processes vary from 0.101 mg/dscm to 1.130 mg/dscm.
"Uncontrolled" is defined as no wetting agent, eductor system or mesh pads added to the
process. None of these solutions require a wetting agent for quality purposes.  Therefore, these
processes typically operate without one. Other reasons why the uncontrolled emissions are high
include:

                    The Wood's Nickel Strike process is intentionally very inefficient which
                    causes significant gassing.

                    Barrel Nickel plating has many mechanical/physical effects that increase
                    nickel emissions (see Discussion of Table VII).

                    The Electroless Nickel plating process is operated at very high
                    temperatures, has a very high air agitation rate, and produces a significant
                    amount of hydrogen gas as a by-product.

Paired Wilcoxon Signed-Rank tests were  conducted to  evaluate the effect  of employing an
eductor system, wetting agent or simple mesh pads at the exhaust hood.  The paired Wilcoxon
Signed Rank  Test (WSRT) is a non-parametric test that evaluates the median difference between
paired samples.

The results of the eductor system versus air agitation comparison was inconclusive (test statistic
value = 0.5256, p-value=0.5992,  n=6). There was insufficient information to conclude that
nickel emissions were reduced by the addition of an eductor system. The results of the wetting
                                           29

-------
agent versus no wetting agent comparison was statistically significant (test statistic value = 36, p-
value = 0.0078, n = 8). Nickel emissions were reduced by the addition of a wetting agent.  The
results of the mesh pad versus no mesh pad comparison were statistically significant (test statistic
value = 55, p-value = 0.002, n = 10. Nickel emissions were reduced by the addition of simple
mesh pads at the exhaust hood. The boxplots in Figure 1, 2, and 3, confirm the conclusions of the
inferential tests.  In each case, employing an operating parameter to reduce nickel emissions
consistently reduced between process variability, but only in the case of employing a wetting
agent or installing a mesh pad installed at the box hood was median nickel emissions reduced.
The investigation did not evaluate the interaction between these operating parameters,  therefore
no conclusions can be made regarding cumulative effect of employing more than one of these
operating parameters.

Figure 1. Boxplots of Nickel Emissions for Eductor System versus Air Agitation.
 w 5
               Eductor System
                                  Air Agitation
Figure  2.    Box  plots  of  Nickel Emissions for  Wetting  Agent   versus  No  Wetting
             Agent.
                     Wetting Agent
                                       No Wetting Agent
                                            30

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Figure 3. Box plots of Nickel Emissions for Mesh Pads and No Mesh Pads.
  E o"
  111
  ffl
                                  D
                                  No Mesh Pads
Tables 4 through 9 present the results summarized in Table 3, in a comparison manner that
illustrate the effects on nickel emissions of the operating conditions identified by this project (i.e.
the effects of wetting agents, the effects of mesh pads, eductors vs. air agitation, etc.).

The nickel emissions from the rack Watts nickel process operated with a wetting agent, a mesh
pad, and an eductor system (Condition  13) was only tested for one two-hour test run due to
quality issues caused by the eductor system.  The eductor system caused dullness and pitting in
the nickel finish in many of the parts that were plated in the nickel tank. Since most of the
testing conducted in this project was conducted on actual plating processes in operation, the
quality of the plated parts took precedence over the stack testing. When modifications to the
operating parameters of the nickel process (temp, current density, etc,) and to the eductor system
itself would not alleviate the plating problems, the eductor system was decommissioned and
replaced with the air agitation system. The two remaining test runs  during that day were
completed with the air agitation system in operation resulting in a total of five test runs
conducted on a rack Watts nickel process operated with a wetting agent, a mesh pad, and an air
agitation system (Condition 14).

It was later determined that the plating problems were caused by iron contamination in the nickel
solution that was directed at the parts by the eductors and then becoming embedded in the plating
finish causing the pitting and the dullness.  It is anticipated that once the iron contamination is
removed (via filtration), the eductor system can be used in the process without causing quality
problems; as others have used eductors on Watt's Nickel very successfully.

As with the Phase 1 testing, there was a comparably large difference in nickel emissions
measured within each of the three individual test runs of a condition tested. For example, the
nickel emission concentrations for the three tests runs on the Electroless Nickel process operated
with air agitation (Condition 6) were measured to be 0.124, 0.313, and 0.505 mg/dscm. The
main reason for these  differences within individual test runs may be the fact that operating

-------
parameters changed slightly from test run to test run. Because these tests were conducted, for the
most part, on nickel plating processes plating actual production parts, keeping all the operating
parameters constant during all three test runs was not possible. Attempts were made, however,
to minimize the operating parameter fluctuations where possible. Because of these differences
within the individual test runs, the average of the three were taken and also reported.

Table 4

Based on the results of this study and illustrated in Table 4, when the nickel emissions are
uncontrolled, the data shows nickel emissions are reduced by 53% when eductors are used for
agitation in place of air (See Condition 5 versus 6).  When the nickel emissions are low, whether
it is due to the nickel plating process itself having low emissions (as is the case with nickel
sulfamate) or the fact that the emissions are reduced by some other means (i.e., mesh pad), the
effects of using eductors instead of air agitation are negligible with an average reduction of 8%
(See Conditions 3 versus 4, 13 versus 14, and 22 versus 23). In fact, in many of these cases, the
nickel emissions measured with the eductors in operation were actually slightly higher than those
measured with the air agitation system operating. That said, we do not believe that using the
eductors actually increased the emissions; simply that eductors have very little effect on the
nickel emission when the emissions are low to begin with.  These unexpected results obtained
when emissions are low are probably due to the inherent error in the Method 29 procedure or the
fact that, in some of the cases, the surface tension of the plating solution was slightly higher
when the eductors were tested than when the air agitation system was tested. For example, the
surface tension  of the Watts Nickel solution when the eductors were tested was 42 dynes/cm
while the surface tension of the same solution when the air was operating was 37 dynes/cm.
Similarly, the surface tension of the Nickel Sulfamate solution when the eductors were tested
was 45 dynes per centimeter while the surface tension of the same solution when the air was
operating was 39 dynes per centimeter.  These small differences in surface tension could have
masked the emission reduction effects of the eductors because it is believed (and validated in this
study) that nickel emission of a plating solution are related to its surface tension; the emissions
increase as the surface tension increases.

Maintaining a constant surface tension within a plating solution is difficult because only a small
amount of wetting agent is needed to reduce the surface tension from about 70 to 40 dynes/cm.
To raise a surface tension in a solution to a specified level requires  considerable time to  allow the
surface tension to rise naturally or complicated carbon treatment.

Table 5

Based on the results of this study and illustrated in Table 5, the use of wetting agents to  reduce
the surface tension of a nickel plating solution significantly reduces the nickel emissions from
that process an average of 72% from uncontrolled tanks and an average of 42% for tanks
controlled with mesh pads. In all eight comparison studies  involving the use of wetting  agents
and encompassing Rack Watts Nickel, Barrel Watts Nickel, and Wood's Nickel  Strike plating
solutions, the nickel emissions measured with the wetting agent were 29% to 92% lower than the
nickel emissions measured without the wetting agent.
                                           32

-------
Several chemical suppliers were contacted to determine the availability of a wetting agent
specifically made for a Wood's nickel strike solution. None of these chemical manufacturers
could provide one nor did they believe one was developed yet. Therefore, a wetting agent that
was typically used in a Watts Nickel solution was used instead. Initial tests proved that this
wetting agent was successful in reducing the surface tension of the Wood's nickel strike solution
from 70 dynes/cm to 38 dynes/cm.  However, it was later discovered that the acidic nature of the
Wood's solution destroyed the wetting agent relatively quickly (within two to three days).
Moreover, the resultant decomposition products of the wetting agent formed a film on the plating
solution which adversely affected plating adhesion.

In Table 5, there are two results reported for some of the test runs of Condition 7. The results in
the parenthesis are results that have been modified to account for the air ventilation rate
fluctuations that occurred during the Condition 7 testing.  For all the other Wood's Nickel Strike
test runs, the ventilation rate measured during the testing was  818 to 892 cfm. The ventilation
rate for the three Condition 7 tests runs was measured to be 1155 cfm,  1610 cfm, and 818 cfm
respectively.  The blower for the Wood's Nickel Strike ventilation system is a variable speed
blower. It is believed that the speed was switched to "high" sometime during the first test run and
then switched back to "low"  after the second test run. To compensate for this dilution effect and
to provide a viable comparison, the nickel emissions from the first two test runs of Condition  7
were mathematically revised to reflect a ventilation rate of 818 cfm.

Table 6

Based on the results of this study and illustrated in Table 6, the use of simple mesh pads to
capture nickel emissions in the vent reduces the nickel emissions from that process. In all ten
comparison studies involving the use of mesh pads and encompassing Rack Watts Nickel, Barrel
Watts Nickel, Wood's Nickel Strike, Nickel Sulfamate, and Electroless Nickel plating solutions,
the nickel emissions measured with the mesh pad in place were significantly lower than the
nickel emissions measured without the mesh pad by an average of 88% for both  controlled and
uncontrolled conditions..

The mesh pad, based on this  study, was the most efficient in reducing nickel emissions;
outperforming the wetting agents and the eductor system as shown in Table 12..  Besides
providing better reduction efficiency, simple mesh pads are less expensive to purchase than the
eductor system and less expensive to use than the wetting agents. Moreover, mesh pads are
totally external to plating solution system. When contemplating using a wetting agent or an
eductor system, one needs to consider the effects of these items on the plating quality because
they are placed in the plating tank.  The mesh pad does not affect the plating at all since it is
installed in the ventilation system.
                                           33

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                   Table 12. Comparison of Nickel Emission Reductions
Condition
Uncontrolled
Tank
Partially
Controlled Tank
%Reduction of Nickel Emissions
Mesh Pads
83%
69%
Wetting Agent
69%
45%
Eductors
53%
8%
The composite mesh pads used in this project were supplied by Chicago Plastics and were easily
inserted in the face of the exhaust hoods; although some exhausts hoods had to be modified in
order to accommodate the composite mesh pads (See photos in Appendix C). The composite
mesh pads are constructed of intertwined polypropylene threads and are approximately three (3)
inches thick.  As stated above, these composite mesh pads were easily placed in the face of the
exhaust hood or directly in the exhaust duct (as was the case with Elite Finishing) and are
designed to capture mists and large particulates (greater than 8 microns).

Table 7

The stack testing results presented in Table 7 suggests that the majority of the nickel that is
emitted from barrel nickel operations is due to mechanical/physical sources such as splashing
produced during entry of the barrel into the tank, the large amounts of liquid leaving the barrel
during removal from the tank, splashing from filter pumps, etc and not from the electrolysis
involved in plating. These results are consistent in what was suggested in the Final Report for
the Phase 1 testing.

Table 8

Based on the results presented in Table  8, it appears that the chemical reaction involved in the
electroless plating process does increase the nickel emissions from an electroless nickel process.
In the Final Report for Phase 1 of this project, it was suggested that the majority of the emissions
from an electroless nickel plating process were due to the high temperature of the electroless
nickel plating solution and the violent air agitation required in the process and that the amount of
parts (or surface area of the parts) had little affect on the nickel emissions. In the Phase  1 testing
(Condition 1), parts were being plated for only 12-30 minutes  of the test run time (120 minutes).
In Phase 2 (Condition 6), however, parts were being plated for 114 to 120 minutes of the 120
minute test run. As illustrated in Table  8, the emissions measured in Phase 2 with the high tank
loading were higher than those measured during Phase 1 with  the low tank loading.  However, in
the year that elapsed between Phase 1 and Phase 2, the EN testing site switched EN solution
suppliers. The EN solution that was being used during Phase  1 of the study had a wetting agent
incorporated into the chemistry while the EN solution that was being used during Phase 2 did
not.  Consequently, the surface tension of the EN solution in process during Phase 1 was about
30 dynes/cm lower than the surface tension of the EN solution that was in process during Phase
2. Therefore, it is inconclusive as to the cause of the increased emissions observed during
                                           34

-------
Condition 6 as compared to Condition 1 (increased parts loading or increased surface tension, or
a combination of the two).

Part of the Phase 2 testing was to observe the effects of a mesh pad on the nickel emissions from
the electroless nickel plating process.  In order to accomplish this goal, the ventilation system for
the electroless nickel tank had to be modified to accept a mesh pad. The modification to the
ventilation system increased the ventilation flow rate.  The ventilation rate during Phase 1 was
1214 to  1240 cfm while the ventilation rate for Phase 2 was  1860 to 2039 cfm. Therefore, to
compensate for this  dilution effect and to provide a viable comparison, the nickel emissions from
the test runs of Condition 1 were mathematically revised to reflect  a ventilation rate of 2000 cfm.
The modified results are listed in parenthesis in Table 8.

Table 9

The results presented in Table 9 indicate that, although the individual test runs were not
consistent, the average of the three runs using Method 29 were within 10% of the average of the
three runs using Method 306A for the Electroless Nickel, Watts Nickel and Wood's Nickel
Strike processes. For the Nickel Sulfamate process, the emissions  measured by Method 306A
were actually higher than those measured by Method 29. The inconsistency within the three
individual test runs and the test runs on the Nickel Sulfamate process may have been due to the
changes in operating parameters during the individual test runs. Based on this testing, we
believe that Method 306A is a viable alternative to Method 29 for measuring nickel emissions.
However, we believe more testing is required.

In order to validate Method 306A as a viable alternative, a non-production process should be
tested in order to have absolute control over all the operating parameters to ensure that they are
constant and identical during both the Method 29 and Method 306A testing.  When testing
production processes, the operating parameters change slightly from test run to test run based on
the production needs. Another  option would be to test a  production process using Method 29
and Method 306A simultaneously.

The emissions from  the Woods Nickel Strike process measured with Method 306A were higher
than the emissions measured with Method 29. Both of these tests were conducted with wetting
agent in the Woods Nickel Strike solution. The wetting agent was added in the morning of the
first day. Method 29 was conducted on the first day while Method  306A was conducted on the
second day. As discussed earlier, it was discovered that the  acidic  nature of the Woods Strike
solution destroyed the wetting agent relatively quickly. Analysis on the first day using a
stalagmometer indicated that the surface tension was approximately 37 dynes/cm.  Analysis of
the Woods Nickel Strike solution three days later using a tensiometer indicated that the surface
tension was 59 dynes/cm. Therefore, the surface tension on the second day (Method 306A) may
have been higher than that on the first day  (Method 29); possibly in the 40-50 dynes/cm range.
This discovery may  explain why the Method 306A testing measured higher emissions.
                                           35

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Tables 10A through 10E

The purpose of Tables 10A through 10E is to summarize the working parameters observed and
recorded during the testing for all of the conditions tested.  As stated before, most of the testing
was conducting during actual processing. Therefore, many of the operating parameters did not
remain constant during all of the individual test runs within a condition. By comparing the
operating parameters from one test run to another, one may be able to explain why there was a
difference in nickel emissions measured from one test one to another.

Table 11

The results presented in Table 11 illustrate that the ventilation systems of all the nickel plating
processes were operating efficiently because the nickel concentrations in the ambient air near the
nickel plating tanks at the times of the testing were significantly below the OSHA eight hour,
time weighted average permissible exposure limit for nickel. This criteria was set-up prior to
testing in order to ensure that the ventilation systems were capturing the majority of nickel
emissions from the plating processes.

QA/QC Summary

The data generated has been evaluated in terms of quality objectives for precision, accuracy,
completeness, representativeness, and comparability, in accordance with EPA Methods 29 and
306A and OSHA Method ID-121.

Prior to analyses, demonstration of method performance and analyst capability was verified and
documented through various studies as MDL, LDR, QCS,  DOC, and Performance Evaluation
Samples.  The appropriate blanks (CCB and LRB), spikes  (LFM and LFM dups), and standards
(QCS, CCV, LFB) were incorporated into the analytical runs as is required  by EPA Methods 29
and 306A and OSHA Method ID-121.  These QC samples were evaluated to meet acceptable
criteria limits, as determined by the procedures and control charts. In order to maintain
consistency in applying the QC data, the "QA/QC Worksheet" was generated to condense the
QC values, limits, and qualifiers, if any. These worksheets are included in Appendices E and F.

All data is considered to be of acceptable quality and validity, as determined by the laboratory
QA Coordinator.
                                          36

-------
Section 7.0    CONCLUSIONS

Based on the stack testing results presented in Table 3, the following conclusions regarding
nickel emissions from nickel plating processes can be made:

       1)  Nickel emissions from typically-operated Rack Watts Nickel and Rack Nickel
          Sulfamate tanks (wetting agent, no mesh pad, air agitation) are not very significant
          (<0.05 mg/dscm).

       2)  Nickel emissions from uncontrolled (no eductors, mesh pads or wetting agents) and
          vented Electroless Nickel, Barrel Nickel, and Wood's Nickel Strike plating processes
          are significant (greater then 0.1 mg/dscm), but can be significantly reduced by 49% to
          92%. This can be accomplished by employing  eductors, wetting agents, or simple
          mesh pads.

       3)  The use of wetting agents in nickel plating processes significantly reduced nickel
          emissions.  The use of wetting agents to reduce the surface tension of a nickel plating
          solution reduces the nickel emissions from that process an average of 72% from
          uncontrolled tanks and an average of 42% for tanks controlled with mesh pads. At
          this time, however, there does not seem to be a  wetting agent specifically developed
          for the Wood's nickel strike solution. A Watt's  Nickel wetting agent can be
          successfully used to reduce the surface tension  of the Wood's nickel strike solution.
          However, the acidic nature (at least 10% by volume hydrochloric acid) of the Wood's
          solution destroys the wetting agent relatively quickly leaving a film on the solution
          surface that greatly affects the plating adhesion.

       4)  Nickel emissions were reduced an average of 15% using eductors  in lieu of air
          agitation for the various controlled and uncontrolled conditions...

       5)  Regardless of type of nickel process, using simple mesh pads to capture splashing and
          misting provides the best reduction of nickel emissions. These reductions averaged
          69% to 89% compared to 8% to 69% for other control methods as shown in Table 12.

       6)  Most of the nickel emissions from nickel barrel plating operations are generated from
          mechanical/physical sources such as splashing produced during entry of the barrel
          into the tank, the large amounts of liquid leaving the barrel during removal from the
          tank,  splashing from filter pumps, etc. and not from the electrolysis involved in
          plating.

       7)  The nickel  emissions from an electroless nickel process are generated from both the
          chemical reaction involved in the electroless plating process and the high solution
          temperature and high agitation rate required in the process.

       8)  Although the results presented in Table 9 indicate that USEPA Method 306A and
                                           37

-------
          USEPA Method 29 provide similar results when measuring nickel emissions from
          Electroless Nickel, Watts Nickel, and Wood's nickel strike, further testing needs to be
          conducted on a controlled process or conducted simultaneously to determine whether
          Method 306A truly is an acceptable alternative to Method 29 for measuring nickel
          emissions from nickel plating processes in general.
Three methods of reducing nickel emissions observed in this study are the use of wetting agents,
eductors, and simple mesh pads.  The implementation of simple mesh pads provide a better
reduction efficiency, they are cheaper to employ and do not affect the quality of the plating.

Due to the extreme number of variables involved in plating (tank dimensions, current density,
temperature, types of parts plated, plating times, chemical differences, etc.), the results presented
in this report should not be used as absolute for all Watt's Nickel, Wood's Nickel Strike,
Electroless Nickel, etc. processes "across the board" but rather as a relative guide or estimate for
these processes.  In the same manner, one cannot assign actual emission reduction efficiencies
for wetting agents, eductors, and mesh pads solely on the results of these tests. Instead, it is
much more accurate to state that these options reduce nickel emissions but the reduction
percentage from process to process will vary.  We base these project limitations or constraints on
the fact that even though extreme care was given to control the variables within the three tests
runs of a test condition, the results for each of these test runs did vary more than expected (see
Table 3). We would expect the results to vary even greater when the variables are not controlled
or, for example, from one Electroless Nickel tank to another.
                                            38

-------
                  Appendix A



Calculation Worksheets for Nickel Stack Emissions

-------
                                        NICKEL AIR EMISSIONS RESULTS
Test
Condition

3




4




5




6




7



Test Site

Reliable




Reliable




Reliable




Reliable




Artistic



Test
Date

10/31/05




1/3/05




' 1/2/05




' 1/1/06




11/9/05



Test


2
3
AVG


2
3
AVG


2
3
AVG

1
2
3
AVG


2
3
AVG
Exhaust Gas
Flow Rate

1 776 acfm
1860 acfm
1 860 acfm
1832 acfm

1 999 acfm
2023 acfm
2037 acfm
2020 acfm

2003 acfm
2063 acfm
2027 acfm
2031 acfm

2039 acfm
1 984 acfm
1929 acfm
1984 acfm

1 1 55 acfm
1610 acfm
81 8 acfm
1086 acfm
Amt. of Nickel
in Sample

0.033 mg.
0.017 mg.
0.017 mg.
0.022 mg.

0.079 mg.
0.039 mg.
0.014 mg.
0.044 mg.

0.477 mg.
0.655 mg.
0.372 mg.
0.501 mg.

0.420 mg.
1.028mg.
1.624 mg.
1.024mg.

0.225 mg.
0.257 mg.
0.597 mg.
0.360 mg.
Nickel Emissions
Rate

31.0mg/hr
16.3 mg/hr
16.2mq/hr
21 .2 mg/hr

74.7 mg/hr
37.4 mg/hr
13.4 mg/hr
41.8 mg/hr

456 mg/hr
631 mq/hr
358 mg/hr
482 mg/hr

405 mg/hr
1000 mg/hr
1568 mg/hr
991 mg/hr

118 mg/hr
211 mg/hr
31 3 mg/hr
214 mg/hr
Nickel Emissions
Concentration

0.0109 mg/dscm
0.0055 mg/dscm
0.0054 mg/dscm
0.0073 mg/dscm

0 0236 mg/dscm
0.01 17 mg/dscm
0.0042 mg/dscm
0.01 32 mg/dscm

0.1 42 mg/dscm
0.192 mg/dscm
0.111 mg/dscm
0.148 mg/dscm

0.124 mg/dscm
0.313 mg/dscm
0.505 mg/dscm
0.314 mg/dscm

0.0632 mg/dscm
0.0807 mg/dscm
0.2355 mg/dscm
0.1265 mg/dscm
Notes: acfm means actual cubic feet of exhaust air per minute
      mg/hr means milligrams per hour
      mg/dscm means milligrams per dry standard cubic meter of exhaust air
      < means less than the analytical limit of detection

-------
                                        NICKEL AIR EMISSIONS RESULTS
Test
Condition

10




11




12




13

14







Test Site

ABQC




ABQC




ABQC




ABQC

ABQC







Test
Date

2/1/06




1/12/06




1/11/06




2/2/06

11/7/05




2/2/06


Test

1
2
3
AVG

1
2
3
AVG

1
2
3
AVG

1

1
2
3
AVG

4
5
AVG
Exhaust Gas
Flow Rate

2190 acfm
2205 acfm
2171 acfm
21 89 acfm

2168 acfm
2 184 acfm
2 193 acfm
21 82 acfm

2350 acfm
2362 acfm
2355 acfm
2356 acfm

2158 acfm

21 14 acfm
21 12 acfm
2129 acfm
21 1 8 acfm

2161 acfm
2159 acfm
2160 acfm
Amt. of Nickel
in Sample

0.127 mg.
0.009 mg.
0.046 mg.
0.061 mg.

0.168 mg.
0.035 mg.
0.015 mg.
0.073 mg.

0.162 mg.
0.424 mg.
0.178 mg.
0.255 mg.

0.043 mg.

0.013 mg.
0.017 mg.
0.011 mg.
0.014mg.

0.109 mg.
0.023 mg.
0.066 mg.
Nickel Emissions
Rate

151 mg/hr
10.9 mg/hr
55.1 mg/hr
72.3 mg/hr

201 mg/hr
41.9 mg/hr
17.8 mg/hr
86.9 mg/hr

195 mg/hr
513 mg/hr
217 mg/hr
308 mg/hr

50.6 mg/hr

10.0 mg/hr
13.2 mg/hr
8.6 mg/hr
10.6 mg/hr

129 mg/hr
27.3 mg/hr
78.2 mg/hr
Nickel Emissions
Concentration

0.0427 mg/dscm
0.0031 mg/dscm
0.0158 mg/dscm
0.0205 mg/dscm

0.0570 mg/dscm
0.0118 mg/dscm
0.0050 mg/dscm
0.0246 mg/dscm

0.0510 mg/dscm
0.1333 mg/dscm
0.0564 mg/dscm
0.0802 mg/dscm

0.0145 mg/dscm

0.0029 mg/dscm
0.0038 mg/dscm
0.0025 mg/dscm
0.0031 mg/dscm

0.0369 mg/dscm
0.0078 mg/dscm
0.0224 mg/dscm
Notes: acfm means actual cubic feet of exhaust air per minute
      mg/hr means milligrams per hour
      mg/dscm means milligrams per dry standard cubic meter of exhaust air
      < means less than the analytical limit of detection

-------
                                         NICKEL AIR EMISSIONS RESULTS
Test
Condition
18



19



20




21




22



Test Site
Artistic



Artistic



Artistic




Artistic




Elite



Test
Date
9/27/05



9/28/05



9/29/05




9/30/05




10/18/05



Test
1
2
3
AVG

1
2
3
AVG
-i
2
3
AVG

1
2
3
AVG

1
2
3
AVG
Exhaust Gas
Flow Rate
1081 acfm
1 545 acfm
1 642 acfm
1423 acfm

1778 acfm
1674 acfm
1542 acfm
1 665 acfm
14fi? arfm
i too derm
1521 acfm
1462 acfm
1482 acfm

1621 acfm
1661 acfm
1597 acfm
1 626 acfm

3789 acfm
3950 acfm
3815 acfm
3851 acfm
Amt. of Nickel
in Sample
0.028 mg.
< 0.011 mg.
0.050 mg.
0.030 mg.

0.102 mg.
0.032 mg.
0.362 mg.
0.165 mg.

.(Jza mg.
0.011 mg.
0.036 mg.
0.025 mg.

0.038 mg.
0.012 mg.
0.014 mg.
0.021 mg.

0.065 mg
0.034 mg.
0.028 mg.
0.042 mg.
Nickel Emissions
Rate
15.5 mg/hr
< 13.2 mg/hr
60.4 mg/hr
29.7 mg/hr

161 mq/hr
51 mg/hr
567 mq/hr
260 mg/hr

23.2 mg/hr
8.9 mg/hr
29.1 mg/hr
20.4 mg/hr

60.1 mg/hr
19.4 mg/hr
22.5 mg/hr
34.0 mg/hr

138 mq/hr
72.2 mq/hr
59.6 mg/hr
89.9 mg/hr
Nickel Emissions
Concentration
0.0088 mg/dscm
< 0 0053 mg/dscm
0.0229 mg/dscm
0.0123 mg/dscm

0.0563 mg/dscm
0 0188 mq/dscm
0 2278 mq/dscm
0.1010 mg/dscm

0.0094 mg/dscm
0 0035 mq/dscm
0 0120 mg/dscm
0.0083 mg/dscm

0 0225 mg/dscm
0 0071 mg/dscm
0.0086 mg/dscm
0.0127 mg/dscm

0 0222 mg/dscm
0.0112 mg/dscm
0.0096 mg/dscm
0.0143 mg/dscm
Notes:  acfm means actual cubic feet of exhaust air per minute
       mg/hr means milligrams per hour
       mg/dscm means milligrams per dry standard cubic meter of exhaust air
       < means less than the analytical limit of detection

-------
                                        NICKEL AIR EMISSIONS RESULTS
Test
Condition

^_vJ




24




25




27




28



Test Site

Elite




Artistic




Elite




Artistic




Artistic



Test
Date

11/15/05




11/10/05




11/25/05




10/17/05




10/19/05



Test

1
2
3
AVG

1
2
3
AVG

1
2
3
AVG

1
2
3
AVG

1
2
3
AVG
Exhaust Gas
Flow Rate

4237 acfm
4011 acfm
4024 acfm
4091 acfm

850 acfm
886 acfm
861 acfm
866 acfm

3706 acfm
3568 acfm
3639 acfm
3638 acfm

872 acfm
859 acfm
879 acfm
870 acfm

860 acfm
887 acfm
892 acfm
880 acfm
Amt. of Nickel
in Sample

0.058 mg.
0.042 mg.
0.062 mg.
0.054 mg.

0.129 mg.
0.209 mg.
0.193 mg.
0.177 mg.

0.011 mg.
0.017 mg.
0.017 mg.
0.015 mg.

1.673 mg.
0.755 mg.
1.393 mg.
1.273mg.

0.347 mg.
0.445 mg.
0.695 mg.
0.496 mg.
Nickel Emissions
Rate

120 mg/hr
86.1 mg/hr
126 mg/hr
111 mg/hr

66.4 mg/hr
1 1 1 mg/hr
101 mg/hr
92.8 mg/hr

23.2 mq/hr
35.5 mg/hr
34.5 mg/hr
31.1 mg/hr

871 mg/hr
391 mg/hr
727 mg/hr
663 mg/hr

182 mg/hr
236 mg/hr
368 mg/hr
262 mg/hr
Nickel Emissions
Concentration

0.0175 mg/dscm
0.0134 mg/dscm
0.0195 mg/dscm
0.0168 mg/dscm

0.0479 mg/dscm
0.0765 mg/dscm
0.0713 mg/dscm
0.0652 mg/dscm

0.0039 mg/dscm
0.0062 mg/dscm
0.0060 mg/dscm
0.0054 mg/dscm

0.614 mg/dscm
0.282 mg/dscm
0.515 mg/dscm
0.470 mg/dscm

0.129 mg/dscm
0.162 mg/dscm
0.252 mg/dscm
0.181 mg/dscm
Notes: acfm means actual cubic feet of exhaust air per minute
      mg/hr means milligrams per hour
      mg/dscm means milligrams per dry standard cubic meter of exhaust air
      < means less than the analytical limit of detection

-------
 RELIABLE PLATING
               CONDITION 3
                                                   10/31/05
                                                        TABLE 3-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  76
  75
  75
  76
  76
  76
  77
  77
  77
  77
  77
  76
  77
  77
  77
  77
  77
  77
  77
  76
  76
  77
  77
  77

  77
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.35
0.308
13.5
0.994
5.0
24
108.13
0.99
1.003
0.033
56
-0.56


PITOT
DELP
INH20
0.16
0.16
0.17
0.16
0.15
0.24
0.13
0.08
0.07
0.07
0.06
0.06
0.25
0.32
0.31
0.28
0.25
0.20
0.20
0.31
0.34
0.34
0.33
0.31

106.89
2.41
1776
1671
2840
0.0109
31.0
102.4

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.90
0.90
0.95
0.90
0.84
1.34
0.73
0.45
0.39
0.39
0.34
0.34
1.40
1.79
1.74
1.57
1.40
1.12
1.12
1.74
1.90
1.90
1.85
1.74
1.16










N2
79.10%
METER
TEMP
DEGF
62
61
63
66
68
70
73
76
79
81
83
85
87
89
91
93
97
98
100
101
103
103
105
108
85








 STACK
VELOCITY
  AFPS

  27.08
  27.06
  27.89
  27.08
  26.22
  33.17
  24.44
  19.17
  17.93
  17.93
  16.60
  16.58
  33.89
  38.34
  37.73
  35.86
  33.89
  30.31
  30.31
  37.70
  39.48
  39.52
  38.93
  37.73

  29.78

-------
 RELIABLE PLATING
               CONDITION 3
                                                   10/31/05
                                                        TABLE 3-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  75
  74
  74
  75
  75
  75
  75
  75
  75
  74
  74
  74
  76
  76
  75
  75
  74
  74
  74
  74
  75
  75
  75
  74

  75
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.35
0.308
13.5
0.994
5.0
24
111.04
0.99
1.003
0.017
57
-0.54


PITOT
DELP
INH2O
0.33
0.35
0.33
0.30
0.28
0.27
0.31
0.34
0.35
0.35
0.35
0.33
0.17
0.21
0.24
0.16
0.14
0.25
0.12
0.07
0.05
0.05
0.07
0.08

110.07
2.38
1860
1756
2984
0.0055
16.3
100.3

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
1.85
1.96
1.85
1.68
1.57
1.51
1.74
1.90
1.96
1.96
1.96
1.85
0.95
1.18
1.34
0.90
0.78
1.40
0.67
0.39
0.28
0.28
0.39
0.45
1.28










N2
79.10%
METER
TEMP
DEGF
101
99
98
99
99
99
100
101
102
104 '
105
107
109
110
110
110
110
111
111
111
111
111
111
110
106








 STACK
VELOCITY
  AFPS

  38.86
  39.98
  38.82
  37.05
  35.79
  35.15
  37.66
  39.44
  40.02
  39.98
  39.98
  38.82
  27.92
  31.03
  33.14
  27.06
  25.29
  33.79
  23.41
  17.88
  15.13
  15.13
  17.90
  19.11

  31.18

-------
 RELIABLE PLATING
               CONDITION 3
10/31/05
TABLE 3-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  74
  74
  74
  74
  75
  75
  75
  75
  75
  76
  76
  75
  76
  76
  76
  76
  76
  75
  76
  77
  77
  77
  76
  76

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.35
0.308
13.5
0.994
5.0
24
111.50
0.99
1.003
0.017
57
-0.54


PITOT
DELP
INH20
0.18
0.18
0.19
0.17
0.16
0.23
0.13
0.09
0.09
0.08
0.07
0.06
0.32
0.33
0.31
0.29
0.24
0.25
0.32
0.36
0.36
0.34
0.34
0.33

110.52
2.37
1860
1754
2981
0.0054
16.2
100.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.01
1.01
1.06
0.95
0.90
1.29
0.73
0.50
0.50
0.45
0.39
0.34
1.79
1.85
1.74
1.62
1.34
1.40
1.79
2.02
2.02
1.90
1.90
1.85
1.26










N2
79.10%
METER
TEMP
DEGF
101
99
98
99
99
100
101
101
102
102
101
103
107
108
109
110
111
112
112
112
113
113
114
116
106








                           STACK
                          VELOCITY
                            AFPS

                            28.67
                            28.67
                            29.46
                            27.86
                            27.06
                            32.44
                            24.39
                            20.29
                            20.29
                            19.15
                            17.91
                            16.57
                            38.30
                            38.90
                            37.70
                            36.46
                            33.17
                            33.82
                            38.30
                            40.66
                            40.66
                            39.52
                            39.48
                            38.90

                            31.19

-------
 RELIABLE PLATING
               CONDITION 4
                                                    11/3/05
                                                        TABLE 4-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  80
  81
  82
  82
  83
  83
  83
  83
  83
  84
  84
  84
  84
  83
  83
  84
  85
  85
  84
  85
  86
  85
  85
  85

  84
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
29.25
0.308
13.5
0.994
5.0
24
120.00
0.99
1.003
0.079
39
-0.51


PITOT
DELP
INH20
0.35
0.34
0.34
0.31
0.27
0.23
0.32
0.34
0.35
0.36
0.36
0.34
0.21
0.24
0.24
0.23
0.20
0.24
0.17
0.15
0.13
0.11
0.10
0.09

118.41
1.53
1999
1867
3172
0.0236
74.7
101.5

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.96
1.90
1.90
1.74
1.51
1.29
1.79
1.90
1.96
2.02
2.02
1.90
1.18
1.34
1.34
1.29
1.12
1.34
0.95
0.84
0.73
0.62
0.56
0.50
1.40










N2
79.10%
METER
TEMP
DEGF
72
70
70
71
76
81
82
84
87
90
93
97
99
101
101
102
104
107
108
109
109
110
110
110
93








 STACK
VELOCITY
  AFPS

  40.20
  39.66
  39.70
  37.91
  35.41
  32.68
  38.55
  39.74
  40.32
  40.93
  40.93
  39.77
  31.26
  33.39
  33.39
  32.71
  30.53
  33.45
  28.12
  26.44
  24.64
  22.64
  21.59
  20.48

  33.52

-------
 RELIABLE PLATING
               CONDITION 4
11/3/05
TABLE 4-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  85
  86
  86
  86
  85
  85
  86
  86
  85
  86
  86
  86
  85
  85
  86
  86
  86
  85
  85
  85
  85
  84
  84
  85

  85
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
2
29.25
0.308
13.5
0.994
5.0
24
119.02
0.99
1.003
0.039
40
-0.51


PITOT
DELP
INH2O
0.25
0.26
0.24
0.23
0.20
0.25
0.17
0.11
0.10
0.09
0.09
0.10
0.35
0.36
0.35
0.33
0.35
0.27
0.32
0.35
0.37
0.36
0.36
0.34

117.74
1.57
2023
1882
3198
0.0117
37.4
100.1

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H2O
1.40
1.46
1.34
1.29
1.12
1.40
0.95
0.62
0.56
0.50
0.50
0.56
1.96
2.02
1.96
1.85
1.57
1.51
1.79
1.96
2.07
2.02
2.02
1.90
1.43










N2
79.10%
METER
TEMP
DEGF
109
105
108
108
108
109
110
111
111
111
112
112
112
113
114
115
118
119
120
120
121
121
121
121
114








                           STACK
                         VELOCITY
                           AFPS

                           34.14
                           34.84
                           33.48
                           32.77
                           30.53
                           34.14
                           28.18
                           22.66
                           21.59
                           20.50
                           20.50
                           21.61
                           40.39
                           40.96
                           40.43
                           39.26
                           40.43
                           35.48
                           38.62
                           40.39
                           41.53
                           40.93
                           40.93
                           39.81

                           33.92

-------
 RELIABLE PLATING
               CONDITION 4
                                                    11/3/05
                                                        TABLE 4-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  86
  87
  87
  87
  87
  86
  86
  87
  87
  88
  87
  87
  87
  87
  87
  86
  86
  87
  86
  85
  85
  86
  86
  85

  86
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.25
0.308
13.5
0.994
5.0
24
120.21
0.99
1.003
0.014
37
-0.53


PITOT
DELP
INH2O
0.35
0.35
0.34
0.30
0.27
0.27
0.33
0.36
0.38
0.37
0.36
0.35
0.24
0.28
0.28 ,
0.26
0.20
0.23
0.16
0.13
0.12
0.11
0.10
0.09

118.99
1.44
2036
1893
3217
0.0042
13.4
100.6

INHG
IN
IN
FT3
WIN

FT3






















MILLIGRAMS
ML
IN H20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H2O
1.96
1.96
1.90
1.68
1.51
1.51
1.85
2.02
2.13
2.07
2.02
1.96
1.34
1.57
1.57
1.46
1.12
1.29
0.90
0.73
0.67
0.62
0.56
0.50
1.45










N2
79.10%
METER
TEMP
DEGF
114
112
112
113
114
115
117
119
119
119
119
120
120
120
120
121
121
121
121
121
122
122
121
121
119








 STACK
VELOCITY
  AFPS

  40.42
  40.46
  39.88
  37.46
  35.54
  35.51
  39.26
  41.04
  42.16
  41.64
  41.04
  40.46
  33.51
  36.19
  36.19
  34.84
  30.56
  32.80
  27.33
  24.62
  23.65
  22.66
  21.61
  20.48

  34.14

-------
 RELIABLE PLATING
               CONDITION 5
                                                    11/2/05
                                                        TABLE 5-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  78
  78
  78
  77
  77
  78
  78
  77
  78
  79
  79
  78
  79
  79
  78
  79
  79
  80
  80
  81
  82
  81
  80
  79

  79
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
29.25
0.308
13.5
0.994
5.0
24
120.12
0.99
1.003
0.477
40
-0.45


PITOT
DELP
INH20
0.27
0.23
0.24
0.25
0.21
0.23
0.11
0.08
0.10
0.16
0.17
0.20
0.33
0.31
0.29
0.25
0.25
0.21
0.34
0.36
0.38
0.38
0.37
0.36

118.48
1.56
2003
1886
3205
0.1422
455.6
100.6

IN HG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.51
1.29
1.34
1.40
1.18
1.29
0.62
0.45
0.56
0.90
0.95
1.12
1.85
1.74
1.62
1.40
1.40
1.18
1.90
2.02
2.13
2.13
2.07
2.02
1.42










N2
79.10%
METER
TEMP
DEGF
65
65
66
69
72
76
78
81
83
84
87
90
92
97
98
99
101
103
105
108
108
109
109
111
90








 STACK
VELOCITY
  AFPS

  35.25
  32.53
  33.23
  33.88
  31.06
  32.53
  22.50
  19.17
  21.45
  27.16
  27.99
  30.34
  39.00
  37.80
  36.53
  33.95
  33.95
  31.14
  39.63
  40.81
  41.97
  41.93
  41.34
  40.74

  33.58

-------
 RELIABLE PLATING
               CONDITION 5
                                                    11/2/05
                                                                         TABLE 5-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  78
  78
  78
  79
  80
  81
  81
  80
  78
  77
  78
  78
  81
  82
  81
  80
  80
  80
  80
  79
  79
  79
  78
  79

  79
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.25
0.308
13.5
0.994
5.0
24
122.08
0.99
1.003
0.655
46
-0.44


PITOT
DELP
INH20
0.36
0.33
0.30
0.27
0.25
0.24
0.32
0.36
0.37
0.37
0.36
0.34
0.25
0.27
0.25
0.24
0.24
0.25
0.16
0.14
0.13
0.17
0.20
0.19

120.71
1.76
2063
1938
3293
0.1916
630.9
99.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
2.02
1.85
1.68
1.51
1.40
1.34
1.79
2.02
2.07
2.07
2.02
1.90
1.40
1.51
1.40
1.34
1.34
1.40
0.90
0.78
0.73
0.95
1.12
1.06
1.48










N2
79.10%
METER
TEMP
DEGF
104
101
102
102
102
102
104
107
108
109
110
109
110
111
112
113
113
113
114
115
114
114
114
114
109








 STACK
VELOCITY
  AFPS

  40.71
  38.97
  37.15
  35.28
  33.98
  33.32
  38.48
  40.78
  41.26
  41.22
  40.70
  39.55
  34.01
  35.38
  34.01
  33.29
  33.29
  33.98
  27.18
  25.40
  24.48
  27.99
  30.34
  29.59

  34.60

-------
 RELIABLE PLATING
               CONDITION 5
                                                    11/2/05
                                                        TABLE 5-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  80
  81
  81
  82
  81
  80
  81
  81
  81
  82
  82
  81
  81
  82
  83
  84
  84
  83
  83
  82
  83
  84
  84
  84

  82
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
3
29.25
0.308
13.5
0.994
5.0
24
119.96
0.99
1.003
0.372
36
-0.46


PITOT
DELP
INH20
0.30
0.28
0.28
0.25
0.26
0.26
0.15
0.11
0.10
0.13
0.15
0.17
0.35
0.33
0.30
0.26
0.23
0.20
0.29
0.34
0.36
0.36
0.35
0.35

118.66
1.41
2027
1900
3229
0.1107
357.5
100.0

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.68
1.57
1.57
1.40
1.46
1.46
0.84
0.62
0.56
0.73
0.84
0.95
1.85
1.85
1.68
1.46
1.29
1.12
1.62
1.90
2.02
2.02
1.96
1.96
1.43










N2
79.10%
METER
TEMP
DEGF
110
107
107
108
109
109
110
110
111
109
110
111
112
113
115
117
118
119
119
119
119
120
120
120
113








 STACK
VELOCITY
  AFPS

  37.21
  35.99
  35.99
  34.04
  34.68
  34.65
  26.34
  22.56
  21.51
  24.55
  26.37
  28.05
  40.24
  39.11
  37.33
  34.78
  32.71
  30.48
  36.70
  39.70
  40.89
  40.93
  40.35
  40.35

  33.98

-------
 RELIABLE PLATING
               CONDITION 6
                                                    11/1/05
                                                        TABLE 6-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  75
  75
  76
  77
  77
  77
  76
  76
  77
  77
  76
  76
  77
  77
  76
  75
  75
  75
  75
  76
  77
  77
  77
  78

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.30
0.308
13.5
0.994
5.0
24
121.38
0.99
1.003
0.420
46
-0.46


PITOT
DELP
INH20
0.37
0.36
0.33
0.31
0.25
0.24
0.37
0.38
0.39
0.40
0.41
0.37
0.26
0.28
0.26
0.23
0.25
0.27
0.12
0.09
0.09
0.11
0.13
0.14

119.95
1.77
2039
1929
3277
0.1236
405.2
99.6

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
2.04
1.98
1.82
1.71
1.38
1.32
2.04
2.09
2.15
2.20
2.26
2.04
1.43
1.54
1.43
1.27
1.38
1.49
0.66
0.50
0.50
0.61
0.72
0.77
1.47










N2
79.10%
METER
TEMP
DEGF
66
64
66
67
71
76
79
82
86
89
91
94
97
99
100
100
101
102
104
105
106
107
107
108
90








 STACK
VELOCITY
  AFPS

  41.13
  40.57
  38.88
  37.72
  33.87
  33.19
  41.17
  41.72
  42.30
  42.84
  43.33
  41.17
  34.54
  35.84
  34.51
  32.43
  33.81
  35.13
  23.42
  20.30
  20.32
  22.47
  24.42
  25.37

  34.18

-------
 RELIABLE PLATING
               CONDITION 6
                                                    11/1/05
                                                        TABLE 6-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  76
  77
  77
  78
  77
  76
  75
  75
  75
  74
  74
  74
  75
  75
  76
  75
  75
  74
  75
  75
  76
  77
  76
  76

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.30
0.308
13.5
0.994
5.0
24
117.02
0.99
1.003
1.028
45
-0.48


PITOT
DELP
INH20
0.18
0.21
0.23
0.21
0.24
0.24
0.11
0.07
0.07
0.09
0.12
0.12
0.37
0.39
0.35
0.31
0.27
0.23
0.31
0.37
0.42
0.43
0.43
0.41

115.86
1.80
1984
1879
3192
0.3133
1000.1
98.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.99
1.16
1.27
1.16
1.32
1.32
0.61
0.39
0.39
0.50
0.66
0.66
2.04
2.15
1.93
1.71
1.49
1.27
1.71
2.04
2.31
2.37
2.37
2.26
1.42










N2
79.10%
METER
TEMP
DEGF
99
98
99
99
101
101
102
102
103
103
103
104
107
108
109
110
111
112
113
113
114
115
117
118
107








 STACK
VELOCITY
  AFPS

  28.71
  31.04
  32.49
  31.07
  33.19
  33.15
  22.42
  17.89
  17.89
  20.26
  23.40
  23.40
  41.13
  42.22
  40.04
  37.65
  35.13
  32.40
  37.65
  41.13
  43.86
  44.42
  44.38
  43.33

  33.26

-------
   RELIABLE PLATING
                CONDITION  6
                                                      11/1/05
                                                         TABLE 6-3
   TEST NO.
   BAROMETRIC PRESSURE
   TIP DIAMETER
   STACK DIAMETER
   STACK AREA
   SAMPLING TIME PER POINT
   NUMBER OF POINTS
   METER VOLUME
   PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           CO2
           0.00%
   TEST
   POINT
     1
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  76
  76
  77
  78
  78
  78
  77
  76
  76
  76
  76
  75
  75
  75
  74
  75
 75
 75
 74
 74
 76
 75
 74
 74

 76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
         20.90%
3
29.30 IN HG
0.308 IN
13.5 IN
0.994 FT3
5.0 MiN
24
114.64 FT3
0.99
1.003




















1.624 MILLIGRAMS
45 ML
-0.45 IN H20
CO
0.00%
PITOT
DELP
INH2O
0.35
0.36
0.31
0.26
0.22
0.21
0.30
0.36
0.37
0.37
0.36
0.35
0.23
0.22
0.20
0.20
0.18
0.25
0.13
0.08
0.08
0.11
0.13
0.12

113.52 SCF
1.83 %VOL
1929 ACFM
1826 DSCFM
3103 M3/HR
0.5052 MG/DSCM
1567.5 MG/HR
99.5




ORIFICE
DELP
INH20
1.93
1.98
1.71
1.43
1.21
1.16
1.65
1.98
2.04
2.04
1.98
1.93
1.27
1.21
1.10
1.10
0.99
1.38
0.72
0.44
0.44
0.61
0.72
0.66
1.32










N2
79.10%
METER
TEMP
DEGF
110
109
108
108
108
108
109
109
110
110
111
111
111
112
112
112
112
111
111
110
111
111
110
111
110








 STACK
VELOCITY
  AFPS

  40.04
  40.61
  37.72
  34.57
  31.80
  31.07
  37.10
  40.61
  41.17
  41.17
  40.61
  40.00
  32:43
  31.71
  30.21
  30.24
 28.69
 33.81
 24.36
 19.11
 19.14
 22.42
 24.36
 23.40

 32.35

-------
 ARTISTIC
               CONDITION 7
                                                    11/9/05
                                                        TABLE 7-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  77
  11
  77
  76
  76
  76
  76
  76
  76
  77
  77
  76
  76
  76
  76
  76
  76
  75
  75
  74
  74
  73
  72
  72

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
29.05
0.308
10
0.545
5.0
24
128.22
0.99
1.003
0.225
17
-0.7


PITOT
DELP
INH20
0.11
0.14
0.18
0.19
0.19
0.17
0.16
0.14
0.12
0.10
0.09
0.08
0.23
0.25
0.29
0.35
0.50
0.54
0.60
0.60
0.58
0.56
0.54
0.52

125.73
0.63
1155
1097
1864
0.0632
117.8
100.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.62
0.78
1.01
1.06
1.06
0.95
0.90
0.78
0.67
0.56
0.50
0.45
1.29
1.40
1.62
1.96
2.80
3.02
3.36
3.36
3.25
3.14
3.02
2.91
1.69










N2
79.10%
METER
TEMP
DEGF
68
68
69
70
72
76
79
82
87
88
89
91
93
96
99
102
103
107
109
110
112
112
114
117
92








 STACK
VELOCITY
  AFPS

  22.52
  25.41
  28.81
  29.57
  29.57
  27.97
  27.14
  25.38
  23.50
  21.47
  20.37
  19.19
  32.54
  33.92
  36.53
  40.14
  47.97
  49.81
  52.50
  52.45
  51.57
  50.63
  49.67
  48.74

  35.31

-------
  ARTISTIC
               CONDITION 7
11/9/05
TABLE 7-2
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           CO2
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  71
  70
  70
  70
  69
  68
  68
  67
  67
  67
  67
  68
  69
  69
  70
  70
  70
  69
  69
  69
  69
  70
  70
  70

 69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
         20.90%
2
29.05 INHG
0.248 IN
10 IN
0.545 FT3
5.0 MIN
24
114.57 FT3
0.99
1.003




















0.257 MILLIGRAMS
22 ML
-1.175 INH20
CO
0.00%
PITOT
DELP
INH20
0.27
0.32
0.38
0.46
0.50
0.52
0.57
0.70
0.75
0.77
0.70
0.56
0.58
0.70
0.75
0.80
0.80
0.72
0.59
0.51
0.38
0.32
0.28
0.25

112.47 SCF
0.91 %VOL
1610 ACFM
1542 DSCFM
2620 M3/HR
0.0807 MG/DSCM
211.4 MG/HR
98.9




ORIFICE
DELP
INH20
0.62
0.74
0.87
1.06
1.15
1.20
1.31
1.61
1.73
1.77
1.61
1.29
1.33
1.61
1.73
1.84
1.84
1.66
1.36
1.17
0.87
0.74
0.64
0.58
1.26










N2
79.10%
METER
TEMP
DEGF
108
103
102
101
102
103
105
105
107
109
110
110
111
111
113
114
115
117
117
118
118
119
119
119
111








                           STACK
                         VELOCITY
                           AFPS

                           35.13
                           38.16
                           41.59
                           45.75
                           47.66
                           48.55
                           50.84
                           56.28
                           58.26
                           59.03
                           56.28
                           50.39
                           51.33
                           56.39
                           58.42
                           60.34
                           60.34
                           57.19
                           51.77
                           48.13
                           41.55
                           38.16
                           35.70
                           33.73

                           49.21

-------
 ARTISTIC
               CONDITION 7
                                                    11/9/05
                                                        TABLE 7-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  73
  73
  73
  73
  74
  74
  72
  71
  71
  70
  70
  70
  71
  72
  71
  72
  72
  71
  71
  72
  72
  73
  73
  73

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
3
29.05
0.308
10
0.545
5.0
24
91.28
0.99
1.003
0.5970
17
-0.26


PITOT
DELP
INH20
0.14
0.18
0.19
0.21
0.18
0.18
0.15
0.12
0.09
0.10
0.09
0.08
0.08
0.09
0.09
0.11
0.14
0.15
0.19
0.20
0.16
0.17
0.15
0.12

89.51
0.89
818
781
1327
0.2355
312.6
100.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.78
1.01
1.06
1.18
1.01
1.01
0.84
0.67
0.50
0.56
0.50
0.45
0.45
0.50
0.50
0.62
0.78
0.84
1.06
1.12
0.90
0.95
0.84
0.67
0.78










N2
79.10%
METER
TEMP
DEGF
107
104
103
105
107
108
109
109
109
110
111
112
112
113
113
113
114
115
117
118
118
119
119
120
112








 STACK
VELOCITY
  AFPS

  25.31
  28.70
  29.49
  31.00
  28.73
  28.73
  26.18
  23.39
  20.26
  21.33
  20.24
  19.08
  19.10
  20.28
  20.26
  22.42
  25.29
  26.15
  29.43
  30.23
  27.04
  27.89
  26.20
  23.44

  25.01

-------
 ABQC
              CONDITION 10
                                                     2/1/06
                                                        TABLE 10-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  68
  68
  68
  68
  68
  69
  69
  69
  69
  69
  68
  68
  69
  70
  70
  71
  71
  71
  71
  72
  72
  72
  72
  72

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
28.95
0.248
12
0.785
5.0
24
107.23
0.99
1.009
0.127
24
-1.21


PITOT
DELP
INH20
0.42
0.45
0.47
0.47
0.44
0.52
0.58
0.60
0.56
0.52
0.48
0.44
0.34
0.38
0.44
0.44
0.48
0.54
0.54
0.50
0.48
0.46
0.41
0.41

105.08
1.06
2190
2083
3539
0.0427
151.0
98.4

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.97
1.04
1.08
1.08
1.01
1.20
1.33
1.38
1.29
1.20
1.10
1.01
0.78
0.87
1.01
1.01
1.10
1.24
1.24
1.15
1.10
1.06
0.94
0.94
1.09










N2
79.10%
METER
TEMP
DEGF
52
48
50
51
53
56
61
65
69
74
78
82
84
87
89
90
92
94
97
99
101
102
102
104
78








 STACK
VELOCITY
  AFPS

  43.78
  45.31
  46.31
  46.31
  44.81
  48.76
  51.49
  52.37
  50.60
  48.76
  46.80
  44.81
  39.42
  41.72
  44.89
  44.93
  46.93
  49.78
  49.78
  47.94
  46.98
  45.99
  43.42
  43.42

  46.47

-------
 ABQC
               CONDITION 10
                                                      2/1/06
                                                        TABLE 10-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEG F

  72
  72
  72
  71
  72
  72
  72
  72
  72
  73
  73
  73
  71
  72
  72
  71
  71
  70
  70
  70
  71
  71
  71
  71

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
28.95 INHG
0.248 IN
12 IN
0.785 FT3
5.0 MIN
24
105.39 FT3
0.99
1.009




















0.009 MILLIGRAMS
30 ML
-1.23 INH2O
CO
0.00%
PITOT
DELP
INH2O
0.39
0.41
0.42
0.42
0.49
0.56
0.58
0.53
0.53
0.51
0.48
0.42
0.37
0.45
0.45
0.45
0.45
0.51
0.58
0.56
0.52
0.48
0.46
0.46

103.63 SCF
1.34 %VOL
2205 ACFM
2084 DSCFM
3541 M3/HR
0.0031 MG/DSCM
10.9 MG/HR
97.0




ORIFICE
DELP
INH2O
0.90
0.94
0.97
0.97
1.13
1.29
1.33
1.22
1.22
1.17
1.10
0.97
0.85
1.04
1.04
1.04
1.04
1.17
1.33
1.29
1.20
1.10
1.06
1.06
1.10










N2
79.10%
METER
TEMP
DEGF
100
99
98
99
99
100
102
103
104
106
107
108
109
109
109
110
110
111
111
112
112
112
113
113
107








 STACK
VELOCITY
  AFPS

  42.37
  43.42
  43.94
  43.90
  47.46
  50.74
  51.64
  49.36
  49.36
  48.47
  47.02
  43.98
  41.20
  45.48
  45.48
  45.44
  45.44
  48.33
  51.54
  50.64
  48.85
  46.93
  45.94
  45.94

  46.79

-------
   ABQC
                                 CONDITION  10
                                     2/1/06
                                                                           TABLE 10-3
   TEST NO.
   BAROMETRIC PRESSURE
   TIP DIAMETER
   STACK DIAMETER
   STACK AREA
   SAMPLING TIME PER POINT
   NUMBER OF POINTS
   METER VOLUME
   PITOT COEFFICIENT
   METER COEFFICIENT
   NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           C02
           0.00%
   TEST
   POINT
     1
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  72
  73
  72
  72
  73
  73
  73
  73
  73
  73
  72
  72
  73
  73
  72
  71
 71
 71
 71
 70
 70
 71
 71
 71

72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
         20.90%
3
28.95
0.248
12
0.785
5.0
24
104.75
0.99
1.009
0.046
24
-1.2


PITOT
DELP
INH20
0.37
0.43
0.44
0.44
0.48
0.54
0.56
0.52
0.50
0.46
0.44
0.42
0.34
0.40
0.40
0.42
0.48
0.51
0.56
0.58
0.48
0.48
0.46
0.42

103.03
1.08
2171
2056
3494
0.0158
55.1
97.8

INHG
IN
IN
FT3
MIN

FT3


MILLIGRAMS
ML
INH20
CO
0.00%
ORIFICE
DELP
INH2O
0.85
0.99
1.01
1.01
1.10
1.24
1.29
1.20
1.15
1.06
1.01
0.97
0.78
0.92
0.92
0,97
1.10
1.17
1.29
1.33
1.10
1.10
1.06
0.97
1.07
SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR

  N2
79.10%
       METER
        TEMP
        DEGF

        108
        105
        106
        106
        107
        108
        108
        108
        109
        109
        109
        110
        111
        111
        111
        112
        112
        112
        113
        113
        113
        113
        114
        114

        110
 STACK
VELOCITY
  AFPS

  41.24
  44.50
  44.98
  44.98
  47.02
  49.87
  50.79
  48.94
  47.99
  46.03
  44.98
  43.94
  39.57
 42.92
 42.88
 43.90
 46.93
 48.38
 50.69
 51.54
 46.89
 46.93
 45.94
 43.90

 46.07

-------
 ABQC
               CONDITION 11
1/12/06
TABLE 11-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  68
  68
  68
  68
  68
  68
  68
  68
  68
  69
  69
  69
  69
  69
  69
  69
  69
  68
  68
  68
  68
  68
  68
  68

 68
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.10
0.248
12
0.785
5.0
24
106.02
0.99
1.006
0.168
24
-1.08


PITOT
DELP
INH20
0.32
0.37
0.41
0.41
0.44
0.48
0.54
0.54
0.52
0.50
0.46
0.44
0.38
0.42
0.44
0.44
0.48
0.52
0.56
0.54
0.54
0.52
0.50
0.47

104.12
1.07
2168
2079
3533
0.0570
201.3
97.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.74
0.85
0.94
0.94
1.01
1.10
1.24
1.24
1.20
1.15
1.06
1.01
0.87
0.97
1.01
1.01
1.10
1.20
1.29
1.24
1.24
1.20
1.15
1.08
1.08










N2
79.10%
METER
TEMP
DEC F
47
47
47
48
51
57
59
64
69
73
78
82
85
86
89
92
96
97
99
101
102
103
106
108
79








                          STACK
                         VELOCITY
                           AFPS

                           38.11
                           40.98
                           43.13
                           43.13
                           44.68
                           46.67
                           49.50
                           49.50
                           48.58
                           47.68
                           45.73
                           44.73
                           41.56
                           43.70
                           44.73
                           44.73
                           46.71
                           48.58
                           50.41
                           49.50
                           49.50
                           48.58
                           47.63
                           46.18

                           46.01

-------
 ABQC
               CONDITION 11
1/12/06
                                                                         TABLE 11-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  68
  68
  68
  69
  69
  68
  68
  68
  68
  68
  68
  68
  69
  70
  69
  69
  69
  69
  68
  68
  68
  69
  69
  69

  69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.10
0.248
12
0.785
5.0
24
106.04
0.99
1.006
0.035
31
-1.11


PITOT
DELP
INH20
0.34
0.36
0.38
0.40
0.46
0.48
0.56
0.58
0.54
0.52
0.48
0.45
0.38
0.42
0.45
0.45
0.48
0.54
0.58
0.58
0.54
0.52
0.48
0.44

104.52
1.38
2184
2087
3546
0.0118
41.9
97.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.78
0.83
0.87
0.92
1.06
1.10
1.29
1.33
1.24
1.20
1.10
1.04
0.87
0.97
1.04
1.04
1.10
1.24
1.33
1.33
1.24
1.20
1.10
1.01
1.09










N2
79.10%
METER
TEMP
DEGF
101
101
101
102
102
104
105
104
106
108
109
110
111
111
111
112
112
112
112
113
114
114
114
115
109








                          STACK
                         VELOCITY
                           AFPS

                           39.30
                           40.42
                           41.53
                           42.64
                           45.73
                           46.67
                           50.41
                           51.30
                           49.50
                           48.58
                           46.67
                           45.19
                           41.56
                           43.74
                           45.23
                           45.23
                           46.71
                           49.55
                           51.30
                           51.30
                           49.50
                           48.62
                           46.71
                           44.73

                           46.34

-------
ABQC
                               CONDITION 11
                                   1/12/06
                                                                        TABLE 11-3
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  69
  69
  70
  70
  70
  70
  69
  69
  69
  69
  69
  69
  69
  69
  69
  70
  70
  69
  69
  68
  69
  69
  69
  69

  69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.10
0.248
12
0.785
5.0
24
107.37
0.99
1.006
0.015
26
-1.09


PITOT
DELP
INH20
0.42
0.44
0.45
0.47
0.50
0.54
0.56
0.54
0.52
0.50
0.48
0.44
0.37
0.40
0.42
0.42
0.44
0.50
0.57
0.55
0.53
0.50
0.45
0.45

105.88
1.14
2193
2098
3564
0.0050
17.8
98.5

iNHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.97
1.01
1.04
1.08
1.15
1.24
1.29
1.24
1.20
1.15
1.10
1.01
0.85
0.92
0.97
0.97
1.01
1.15
1.31
1.27
1.22
1.15
1.04
1.04
1.10










N2
79.10%
METER
TEMP
DEGF
110
109
108
109
109
109
110
111
111
111
111
112
113
113
113
114
114
115
116
116
117
118
118
119
113








 STACK
VELOCITY
  AFPS

  43.70
  44.73
  45.27
  46.27
  47.72
  49.60
  50.46
  49.55
  48.62
  47.68
  46.71
  44.73
  41.01
  42.64
  43.70
  43.74
  44.77
  47.68
  50.91
  49.96
  49.09
  47.68
  45.23
  45.23

  46.53

-------
 ABQC
                               CONDITION 12
                                   1/11/06
                                                                         TABLE 12-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  70
  70
  70
  70
  70
  71
  71
  70
  70
  70
  70
  70
  70
  70
  70
  70
  69
  69
  69
  69
  69
  69
  68
  68

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.20
0.248
12
0.785
5.0
24
113.80
0.99
1.006
0.162
25
-1.01


PITOT
DELP
INH2O
0.38
0.44
0.46
0.46
0.52
0.58
0.60
0.62
0.62
0.60
0.60
0.58
0.42
0.48
0.48
0.50
0.50
0.52
0.64
0.68
0.68
0.65
0.63
0.60

112.24
1.04
2350
2257
3835
0.0510
195.4
97.0

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.87
1.01
1.06
1.06
1.20
1.33
1.38
1.43
1.43
1.38
1.38
1.33
0.97
1.10
1.10
1.15
1.15
1.20
1.47
1.56
1.56
1.50
1.45
1.38
1.27










N2
79.10%
METER
TEMP
DEGF
58
52
56
57
58
60
65
69
73
77
79
84
88
90
92
93
95
97
99
101
102
103
106
107
82








 STACK
VELOCITY
  AFPS

  41.53
  44.68
  45.69
  45.69
  48.58
  51.35
  52.23
  53.04
  53.04
  52.18
  52.18
  51.30
  43.66
  46.67
  46.67
  47.63
  47.59
  48.53
  53.84
  55.50
  55.50
  54.26
  53.37
  52.08

  49.87

-------
 ABQC
                               CONDITION 12
                                   1/11/06
                                                                        TABLE 12-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  70
  69
  69
  69
  70
  70
  70
  71
  71
  70
  70
  69
  69
  70
  70
  70
  69
  69
  69
  69
  70
  70
  69
  69

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.20
0.248
12
0.785
5.0
24
113.49
0.99
1.006
0.424
30
-1.05


PITOT
DELP
INH2O
0.40
0.51
0.51
0.50
0.52
0.54
0.65
0.70
0.68
0.68
0.66
0.62
0.38
0.40
0.40
0.42
0.46
0.52
0.70
0.72
0.64
0.62
0.60
0.60

112.29
1.24
2362
2264
3847
0.1333
512.9
96.8

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.92
1.17
1.17
1.15
1.20
1.24
1.50
1.61
1.56
1.56
1.52
1.43
0.87
0.92
0.92
0.97
1.06
1.20
1.61
1.66
1.47
1.43
1.38
1.38
1.29










N2
79.10%
METER
TEMP
DEGF
98
99
100
101
102
102
103
104
106
107
109
110
111
111
111
111
112
112
112
113
113
114
114
114
108








 STACK
VELOCITY
  AFPS

  42.62
  48.06
  48.06
  47.59
  48.58
  49.50
  54.31
  56.41
  55.60
  55.55
  54.73
  52.99
  41.49
  42.61
  42.61
  43.66
  45.65
  48.53
  56.31
  57.11
  53.89
  53.04
  52.13
  52.13

  50.13

-------
 ABQC
              CONDITION  12
                                                    1/11/06
                                                        TABLE 12-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  68
  69
  69
  69
  68
  68
  69
  70
  70
  70
  70
  71
  70
  71
  71
  71
  71
  70
  70
  70
  71
  71
  71
  71

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
3
29.20
0.248
12
0.785
5.0
24
112.64
0.99
1.006
0.178
23
-1.02


PITOT
DELP
INH20
0.36
0.38
0.40
0.40
0.42
0.48
0.61
0.65
0.68
0.66
0.66
0.62
0.48
0.50
0.50
0.50
0.48
0.52
0.68
0.72
0.70
0.68
0.66
0.61

111.47
0.96
2355
2262
3843
0.0564
216.7
96.2

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.83
0.87
0.92
0.92
0.97
1.10
1.40
1.50
1.56
1.52
1.52
1.43
1.10
1.15
1.15
1.15
1.10
1.20
1.56
1.66
1.61
1.56
1.52
1.40
1.28










N2
79.10%
METER
TEMP
DEGF
103
102
102
102
103
104
104
105
107
108
109
110
112
111
112
112
113
113
113
114
116
118
118
119
110








 STACK
VELOCITY
  AFPS

  40.34
  41.49
  42.56
  42.56
  43.57
  46.58
  52.56
  54.31
  55.55
  54.73
  54.73
  53.09
  46.67
  47.68
  47.68
  47.68
  46.72
  48.58
  55.55
  57.16
  56.41
  55.60
  54.78
  52.66

  49.97

-------
ABQC
                               CONDITION 13
                                    2/2/06
                                                                        TABLE 13-1
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
TOTAL NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  71
  71
  72
  72
  72
  71
  71
  71
  71
  72
  72
  72
  70
  71
  70
  71
  70
  69
  69
  70
  69
  69
  70
  70

  71
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.10
0.248
12
0.785
5.0
24
106.57
0.99
1.009
0.043
25
-1.21


PITOT
DELP
INH20
0.37
0.41
0.44
0.44
0.42
0.47
0.56
0.56
0.54
0.50
0.49
0.43
0.34
0.37
0.40
0.42
0.45
0.54
0.56
0.52
0.52
0.48
0.45
0.40

104.97
1.11
2158
2058
3498
0.0145
50.6
99.5

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.85
0.94
1.01
1.01
0.97
1.08
1.29
1.29
1.24
1.15
1.13
0.99
0.78
0.85
0.92
0.97
1.04
1.24
1 .29 -
1.20
1.20
1.10
1.04
0.92
1.06










N2
79.10%
METER
TEMP
DEGF
45
48
49
50
54
58
61
67
72
75
78
81
85
87
89
91
93
94
96
98
100
101
102
103
78








 STACK
VELOCITY
  AFPS

  41.10
  43.27
  44.86
  44.86
  43.83
  46.32
  50.56
  50.56
  49.65
  47.82
  47.34
  44.35
  39.36
  41.10
  42.69
  43.79
  45.28
  49.56
  50.47
  48.68
  48.63
  46.73
  45.28
  42.69

  45.78

-------
 ABQC
              CONDITION 14
                                                    11/7/05
                                                        TABLE 14-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  73
  72
  72
  72
  73
  73
  73
  73
  74
  74
  73
  72
  71
  71
  72
  72
  73
  73
  72
  72
  73
  73
  72
  72

  73
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.40
0.308
12
0.785
5.0
24
159.07
0.99
1.006
0.013
34
-1.12


PITOT
DELP
INH20
0.38
0.41
0.46
0.46
0.46
0.48
0.50
0.47
0.45
0.42
0.39
0.37
0.38
0.42
0.44
0.44
0.47
0.50
0.52
0.50
0.48
0.46
0.44
0.39

158.59
1.00
2114
2034
3455
0.0029
10.0
98.6

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
2.13
2.30
2.58
2.58
2.58
2.69
2.80
2.63
2.52
2.35
2.18
2.07
2.13
2.35
2.46
2.46
2.63
2.80
2.91
2.80
2.69
2.58
2.46
2.18
2.49










N2
79.10%
METER
TEMP
DEGF
63
58
59
62
66
72
76
78
82
87
88
91
96
97
99
101
102
104
106
108
109
111
112
113
89








 STACK
VELOCITY
  AFPS

  41.50
  43.07
  45.62
  45.62
  45.66
  46.65
  47.61
  46.16
  45.21
  43.67
  42.05
  40.92
  41.43
  43.55
  44.62
  44.62
  46.16
  47.61
  48.51
  47.56
  46.65
  45.66
  44.62
  42.01

  44.86

-------
  ABQC
               CONDITION 14
11/7/05
TABLE 14-2
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           CO2
           0.00%
   TEST
   POINT
     1
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  69
  69
  69
  69
  69
  70
  70
  71
  71
  70
  70
  69
  71
  71
  70
  70
  70
  71
  71
  70
 70
 70
 71
 71

 70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.40
0.308
12
0.785
5.0
24
157.41
0.99
1.003
0.017
43
-1.12


PITOT
DELP
INH2O
0.42
0.44
0.46
0.46
0.48
0.50
0.53
0.51
0.47
0.44
0.42
0.41
0.32
0.37
0.41
0.41
0.43
0.45
0.52
0.49
0.47
0.44
0.44
0.43

156.93
1.27
2112
2035
3458
0.0038
13.2
97.6

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
2.35
2.46
2.58
2.58
2.69
2.80
2.97
2.86
2.63
2.46
2.35
2.30
1.79
2.07
2.30
2.30
2.41
2.52
2.91
2.74
2.63
2.46
2.46
2.41
2.50










N2
79.10%
METER
TEMP
DEGF
107
106
103
106
108
109
109
111
111
112
113
114
116
117
118
118
118
119
120
120
120
120
121
121
114








                          STACK
                         VELOCITY
                          AFPS

                          43.49
                          44.49
                          45.49
                          45.49
                          46.47
                          47.47
                          48.88
                          47.99
                          46.07
                          44.53
                          43.51
                          42.95
                          38.02
                          40.88
                          42.99
                          42.99
                          44.03
                          45.08
                          48.46
                          47.00
                          46.03
                          44.53
                          44.58
                          44.07

                          44.81

-------
  ABQC
              CONDITION  14
11/7/05
TABLE 14-3
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           CO2
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  71
  72
  72
  71
  71
  72
  73
  73
  72
  72
  72
  72
  73
  73
  73
  72
  72
  72
  72
  73
  73
  73
  73
  72

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
3
29.40
0.308
12
0.785
5.0
24
158.34
0.99
1.003
0.011
33
-1.1


PITOT
DELP
INH2O
0.35
0.41
0.45
0.45
0.46
0.47
0.52
0.49
0.47
0.45
0.45
0.42
0.41
0.44
0.44
0.45
0.47
0.49
0.52
0.50
0.48
0.45
0.40
0.40

157.94
0.97
2129
2049
3482
0.0025
8.6
97.5

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
IN H2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.96
2.30
2.52
2.52
2.58
2.63
2.91
2.74
2.63
2.52
2.52
2.35
2.30
2.46
2.46
2.52
2.63
2.74
2.91
2.80
2.69
2.52
2.24
2.24
2.53










N2
79.10%
METER
TEMP
DEGF
115
112
112
112
112
112
112
114
116
118
118
119
119
119
120
120
121
121
121
122
122
122
123
123
118








                          STACK
                         VELOCITY
                           AFPS

                           39.75
                           43.07
                           45.12
                           45.08
                           45.58
                           46.11
                           48.55
                           47.13
                           46.11
                           45.12
                           45.12
                           43.59
                           43.11
                           44.66
                           44.66
                           45.12
                           46.11
                           47.09
                           48.51
                           47.61
                           46.65
                           45.17
                           42.58
                           42.54

                          45.17

-------
ABQC
                              CONDITION 14
                                    2/2/06
                                                                        TABLE 14-4
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  71
  70
  70
  70
  70
  70
  70
  70
  70
  71
  71
  70
  70
  70
  70
  69
  69
  69
  69
  68
  68
  69
  69
  68

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.10
0.248
12
0.785
5.0
24
105.72
0.99
1.009
0.109
31
-1.21


PITOT
DELP
INH20
0.35
0.39
0.41
0.41
0.50
0.54
0.52
0.47
0.47
0.45
0.45
0.40
0.44
0.44
0.44
0.44
0.44
0.48
0.58
0.55
0.52
0.50
0.48
0.45

104.43
1.38
2161
2060
3501
0.0369
129.0
98.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H20
0.81
0.90
0.94
0.94
1.15
1.24
1.20
1.08
1.08
1.04
1.04
0.92
1.01
1.01
1.01
1.01
1.01
1.10
1.33
1.27
1.20
1.15
1.10
1.04
1.07










N2
79.10%
METER
TEMP
DEGF
93
92
92
93
94
97
98
99
100
101
102
102
103
105
107
108
109
110
110
110
110
111
111
111
103








 STACK
VELOCITY
  AFPS

  40.00
  42.16
  43.23
  43.23
  47.73
  49.61
  48.68
  46.28
  46.28
  45.33
  45.33
  42.69
  44.78
  44.78
  44.78
  44.74
  44.74
  46.73
  51.36
  49.97
  48.59
  47.69
  46.73
  45.20

  45.86

-------
 ABQC
              CONDITION  14
                                                     2/2/06
                                                        TABL E 14-5
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  69
  69
  68
  68
  68
  68
  68
  68
  69
  69
  68
  68
  69
  69
  70
  70
  70
  70
  70
  70
  71
  71
  70
  71

  69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.10
0.248
12
0.785
5.0
24
105.45
0.99
1.009
0.023
25
-1.19


PITOT
DELP
INH2O
0.43
0.45
0.45
0.45
0.43
0.48
0.56
0.56
0.50
0.48
0.45
0.42
0.35
0.38
0.40
0.42
0.48
0.52
0.56
0.54
0.50
0.45
0.45
0.40

104.24
1.12
2159
2065
3509
0.0078
27.3
98.5

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.99
1.04
1.04
1.04
0.99
1.10
1.29
1.29
1.15
1.10
1.04
0.97
0.81
0.87
0.92
0.97
1.10
1.20
1.29
1.24
1.15
1.04
1.04
0.92
1.07










N2
79.10%
METER
TEMP
DEGF
104
102
102
103
103
104
105
106
108
109
109
110
110
110
111
111
111
112
112
112
112
112
113
113
109








 STACK
VELOCITY
  AFPS

  44.22
  45.24
  45.20
  45.20
  44.18
  46.68
  50.42
  50.42
  47.69
  46.73
  45.20
  43.67
  39.90
  41.57
  42.69
  43.75
  46.77
  48.68
  50.52
  49.61
  47.78
  45.33
  45.28
  42.74

  45.81

-------
 ARTISTIC PLATING
              CONDITION 18
                                                    9/27/05
                                                        TABLE 18-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  72
  72
  72
  72
  72
  73
  73
  72
  74
  74
  75
  74
  73
  74
  75
  75
  75
  74
  74
  76
  77
  76
  75
  75

  74
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.35
0.370
12
0.785
5.0
24
113.85
0.99
1.003
0.028
20
-0.6


PITOT
DELP
INH20
0.05
0.05
0.05
0.05
0.04
0.04
0.04
0.05
0.05
0.06
0.07
0.07
0.15
0.14
0.14
0.13
0.11
0.11
0.21
0.29
0.30
0.34
0.38
0.39

112.72
0.83
1081
1039
1765
0.0088
15.5
95.1

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.50
0.55
0.50
0.50
0.44
0.44
0.44
0.50
0.55
0.61
0.72
0.72
1.65
1.54
1.54
1.43
1.21
1.21
2.31
3.19
3.30
3.30
3.30
3.30
1.41










N2
79.10%
METER
TEMP
DEGF
73
68
69
70
72
75
78
79
83
87
89
92
94
97
100
103
107
111
111
112
113
117
117
119
93








 STACK
VELOCITY
  AFPS

  14.27
  15.04
  14.27
  14.27
  13.45
  13.46
  13.46
  14.27
  15.07
  15.80
  17.20
  17.18
  26.07
  25.21
  25.24
  24.32
  22.37
  22.35
  30.88
  36.35
  37.01
  39.36
  41.58
  42.12

  22.94

-------
 ARTISTIC PLATING
              CONDITION 18
                                                    9/27/05
                                                        TABLE 18-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  75
  75
  75
  75
  74
  74
  75
  76
  77
  77
  76
  76
  77
  77
  76
  76
  76
  77
  77
  76
  77
  78
  78
  77

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.35
0.248
12
0.785
5.0
24
74.57
0.99
1.003
0.011
24
0.95


PITOT
DELP
INH20
0.14
0.14
0.12
0.11
0.11
0.12
0.37
0.38
0.41
0.41
0.40
0.39
0.13
0.14
0.20
0.23
0.27
0.24
0.26
0.27
0.29
0.27
0.27
0.26

73.79
1.51
1545
1474
2504
0.0053
13.2
97.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.31
0.31
0.26
0.24
0.24
0.26
0.81
0.84
0.90
0.90
0.88
0.86
0.29
0.31
0.44
0.51
0.59
0.53
0.57
0.59
0.64
0.59
0.59
0.57
0.54










N2
79.10%
METER
TEMP
DEGF
99
98
99
99
101
101
102
102
103
103
103
104
107
108
109
110
111
112
113
113
114
115
117
118
107








 STACK
VELOCITY
  AFPS

  25.22
  25.24
  23.36
  22.37
  22.35
  23.34
  41.03
  41.62
  43.27
  43.27
  42.70
  42.16
  24.36
  25.28
  30.19
  32.38
  35.08
  33.10
  34.46
  35.08
  36.39
  35.14
  35.14
  34.46

  32.79

-------
ARTISTIC PLATING
                              CONDITION 18
                                                   9/27/05
                                                                       TABLE 18-3
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          C02
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

 AVERAGE
STACK
TEMP
DEGF

  76
  77
  77
  77
  77
  78
  77
  77
  76
  75
  76
  76
  77
  77
  77
  78
  78
  78
  78
  77
  77
  77
  76
  76

  77
 DRY STANDARD VOLUME
 PERCENT WATER VAPOR
 FLOW RATE
 NICKEL CONCENTRATION
 NICKEL EMISSION RATE
 ISOKINETIC PERCENT
          02
        20.90%
3
29.35
0.248
12
0.785
5.0
24
77.92
0.99
1.003
0.050
27
-1.01


PITOT
DELP
INH2O
0.14
0.26
0.37
0.38
0.35
0.39
0.33
0.32
0.36
0.36
0.36
0.27
0.12
0.11
0.10
0.10
0.09
0.09
0.31
0.36
0.38
0.40
0.41
0.40

77.23
1.62
1642
1554
2641
0.0229
60.4
97.0

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR




ORIFICE
DELP
INH2O
0.31
0.57
0.81
0.84
0.77
0.86
0.73
0.70
0.79
0.79
0.79
0.59
0.26
0.24
0.22
0.22
0.20
0.20
0.68
0.79
0.84
0.88
0.90
0.88
0.62







N2
79.10%
METER
TEMP
DEGF
114
113
113
112
112
113
113
115
117
118
119
118
120
120
120
120
121
121
121
121
122
123
124
124
118





MG/DSCM
MG/HR





 STACK
VELOCITY
  AFPS

  25.31
  34.46
  41.10
  41.65
  39.98
  42.24
  38.82
  38.22
  40.51
  40.47
  40.51
  35.08
  23.41
  22.41
  21.37
  21.39
  20.29
  20.29
  37.66
  40.54
  41.65
  42.74
  43.23
  42.70

  34.83

-------
 ARTISTIC PLATING
              CONDITION 19
                                                    9/28/05
                                                                        TABLE 19-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
 '   5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  75
  75
  75
  75
  74
  74
  74
  74
  74
  74
  75
  75
  76
  76
  76
  75
  75
  74
  75
  76
  75
  74
  74
  75

  75
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.20
0.308
12
0.785
2.5
24
64.91
0.99
1.003
0.102
25
-1.08


PITOT
DELP
INH2O
0.10
0.10
0.09
0.08
0.09
0.08
0.22
0.46
0.54
0.62
0.60
0.58
0.26
0.31
0.40
0.45
0.45
0.42
0.31
0.35
0.37
0.40
0.42
0.40

63.94
1.81
1778
1678
2851
0.0563
161
96.4

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.52
0.52
0.47
0.42
0.47
0.42
1.14
2.39
2.81
3.22
3.12
3.02
1.30
1.61
2.08
2.34
2.34
2.18
1.61
1.82
1.92
2.08
2.18
2.08
1.75










N2
79.10%
METER
TEMP
DEGF
75
74
72
73
73
74
76
78
78
79
81
83
84
86
89
91
92
94
96'
98
99
100
101
102
85








 STACK
VELOCITY
  AFPS

  21.44
  21.44
  20.34
  19.17
  20.32
  19.15
  31.76
  45.93
  49.77
  53.32
  52.51
  51.62
  34.60
  37.78
  42.91
  45.47
  45.47
  43.89
  37.74
  40.14
  41.23
  42.83
  43.89
  42.87

  37.73

-------
 ARTISTIC PLATING
              CONDITION 19
                                                    9/28/05
                                                        TABLE 19-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  76
  76
  75
  75
  74
  73
  73
  73
  74
  73
  73
  73
  73
  73
  74
  74
  74
  73
  73
  74
  73
  73
  74
  74

  74
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
2
29.20
0.308
12
0.785
2.5
24
60.87
0.99
1.003
0.032
22
-0.96


PITOT
DELP
INH20
0.22
0.24
0.28
0.32
0.30
0.28
0.26
0.32
0.34
0.32
0.32
0.30
0.10
0.11
0.12
0.10
0.09
0.08
0.24
0.48
0.54
0.58
0.60
0.60

60.07
1.69
1674
1585
2693
0.0188
51
95.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.14
1.25
1.46
1.66
1.56
1.46
1.35
1.66
1.77
1.66
1.66
1.56
0.52
0.57
0.62
0.52
0.47
0.42
1.25
2.50
2.81
3.02
3.12
3.12
1.55










N2
79.10%
METER
TEMP
DEGF
100
98
99
99
99
99
100
101
102
104
105
105
108
109
110
110
110
110
110
110
111
111
112
113
106








 STACK
VELOCITY
  AFPS

  31.81
  33.24
  35.87
  38.35
  37.09
  35.80
  34.50
  38.27
  39.49
  38.27
  38.27
  37.06
  21.40
  22.44
  23.46
  21.42
  20.32
  19.14
  33.15
  46.92
  49.72
  51.53
  52.46
  52.46

  35.52

-------
ARTISTIC PLATING
                              CONDITION  19
                                                    9/28/05
                                                                        TABLE 19-3
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  72
  72
  72
  73
  72
  73
  73
  73
  72
  72
  72
  72
  71
  71
  71
  72
  72
  71
  71
  71
  71
  70
  70
  69

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.20
0.308
12
0.785
2.5
24
56.90
0.99
1.003
0.362
20
-0.952


PITOT
DELP
INH20
0.13
0.16
0.14
0.14
0.12
0.12
0.31
0.46
0.48
0.54
0.62
0.60
0.14
0.12
0.10
0.07
0.10
0.12
0.20
0.26
0.40
0.34
0.30
0.26

56.12
1.65
1542
1466
2492
0.2278
567
96.8

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.68
0.83
0.73
0.73
0.62
0.62
1.61
2.39
2.50
2.81
3.22
3.12
0.73
0.62
0.52
0.36
0.52
0.62
1.04
1.35
2.08
1.77
1.56
1.35
1.35










N2
79.10%
METER
TEMP
DEGF
102
101
100
102
102
101
102
101
102
102
103
105
107
108
108
108
109
109
109
110
110
111
111
112
106








 STACK
VELOCITY
  AFPS

  24.36
  27.04
  25.29
  25.32
  23.42
  23.44
  37.67
  45.89
  46.83
  49.67
  53.22
  52.36
  25.27
  23.39
  21.36
  17.88
  21.38
  23.39
  30.20
  34.43
  42.71
  39.34
  36.95
  34.37

  32.72

-------
ARTISTIC PLATING
              CONDITION 20
                                                    9/29/05
                                                                        TABLE 20-1
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
TOTAL NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          C02
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  60
  60
  60
  61
  61
  60
  60
  60
  61
  61
  62
  62
  63
  63
  63
  62
  63
  63
  63
  62
  62
  63
  63
  62

  62
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.50
0.308
12
0.785
5.0
24
109.24
0.99
1.003
0.029
18
-1.125


PITOT
DELP
INH20
0.10
0.12
0.11
0.12
0.14
0.14
0.26
0.32
0.32
0.36
0.36
0.34
0.12
0.13
0.11
0.11
0.10
0.10
0.30
0.38
0.38
0.40
0.42
0.40

108.57
0.77
1463
1445
2455
0.0094
23.2
95.1

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.52
0.62
0.57
0.62
0.73
0.73
1.35
1.66
1.66
1.87
1.87
1.77
0.62
0.67
0.57
0.57
0.52
0.52
1.56
1.98
1.98
2.08
2.18
2.08
1.22










N2
79.10%
METER
TEMP
DEGF
64
64
62
63
66
71
73
76
79
82
86
89
91
93
95
98
99
99
100
101
102
105
108
109
86








 STACK
VELOCITY
  AFPS

  20.99
  22.99
  22.01
  23.01
  24.85
  24.83
  33.84
  37.54
  37.58
  39.86
  39.89
  38.77
  23.05
  24.00
  22.07
  22.05
  21.05
  21.05
  36.45
  40.99
  40.99
  42.09
  43.13
  42.05

  31.05

-------
ARTISTIC PLATING
              CONDITION 20
                                                   9/29/05
                                                                        TABLE 20-2
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  63
  63
  63
  62
  62
  63
  63
  63
  64
  64
  63
  62
  63
  63
  63
  64
  64
  64
  64
  65
  65
  65
  65
  65

  64
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.50
0.308
12
0.785
5.0
24
111.32
0.99
1.003
0.011
20
-1.175


PITOT
DELP
INH20
0.12
0.12
0.13
0.11
0.11
0.10
0.26
0.32
0.37
0.40
0.42
0.38
0.17
0.19
0.20
0.24
0.27
0.29
0.24
0.28
0.30
0.30
0.30
0.26

110.94
0.84
1521
1495
2540
0.0035
8.9
93.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H20
0.62
0.62
0.68
0.57
0.57
0.52
1.35
1.66
1.92
2.08
2.18
1.98
0.88
0.99
1.04
1.25
1.40
1.51
1.25
1.46
1.56
1.56
1.56
1.35
1.27










N2
79.10%
METER
TEMP
DEGF
101
101
100
99
99
100
101
102
103
106
109
110
110
111
112
112
112
112
112
113
114
116
117
118
108








 STACK
VELOCITY
  AFPS

  23.06
  23.05
  24.00
  22.05
  22.05
  21.05
  33.94
  37.65
  40.52
  42.13
  43.13
  40.99
  27.44
  29.01
  29.76
  32.64
  34.61
  35.87
  32.64
  35.28
  36.52
  36.52
  36.52
  34.00

  32.27

-------
 ARTISTIC PLATING
              CONDITION  20
                                                    9/29/05
                                                                         TABLE 20-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  65
  65
  66
  66
  66
  66
  65
  66
  67
  67
  67
  67
  67
  67
  68
  68
  68
  67
  67
  68
  67
  67
  67
  67

  67
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
3
29.50
0.308
12
0.785
5.0
24
106.63
0.99
1.003
0.0360
18
-1.16


PITOT
DELP
INH2O
0.16
0.18
0.20
0.22
0.18
0.15
0.25
0.28
0.25
0.22
0.22
0.20
0.12
0.14
0.13
0.11
0.11
0.10
0.28
0.36
0.39
0.40
0.38
0.38

106.25
0.79
1462
1429
2428
0.0120
29.1
94.0

IN HG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.83
0.94
1.04
1.14
0.94
0.78
1.30
1.46
1.30
1.14
1.14
1.04
0.62
0.73
0.68
0.57
0.57
0.52
1.46
1.87
2.03
2.08
1.98
1.98
1.17










N2
79.10%
METER
TEMP
DEGF
104
102
101
102
103
103
103
106
108
109
109
110
111
111
112
112
112
112
113
113
113
115
115
118
109








 STACK
VELOCITY
  AFPS

  26.67
  28.29
  29.85
  31.31
  28.32
  25.85
  33.34
  35.32
  33.40
  31.34
  31.34
  29.88
  23.14
  25.00
  24.11
  22.18
  22,18
  21.13
  35.35
  40.12
  41.72
  42.25
  41.18
  41.18

  31.02

-------
ARTISTIC PLATING
              CONDITION 21
                                                    9/30/05
                                                                        TABLE 21-1
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
TOTAL NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  64
  64
  65
  66
  66
  66
  67
  67
  67
  68
  68
  68
  68
  67
  67
  68
  68
  68
  69
  69
  68
  69
  69
  69

  67
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
29.35
0.308
12
0.785
2.5
24
60.32
0.99
1.003
0.038
14
-1.05


PITOT
DELP
INH2O
0.09
0.11
0.10
0.09
0.09
0.09
0.28
0.36
0.39
0.40
0.42
0.45
0.10
0.16.
0.24
0.38
0.46
0.44
0.34
0.36
0.38
0.36
0.36
0.36

59.62
1.09
1621
1571
2670
0.0225
60.1
96.0

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.47
0.57
0.52
0.47
0.47
0.47
1.46
1.87
2.03
2.08
2.18
2.34
0.52
0.83
1.25
1.98
2.39
2.29
1.77
1.87
1.98
1.87
1.87
1.87
1.48










N2
79.10%
METER
TEMP
DEGF
64
63
64
66
68
69
69
69
70
71
73
75
77
79
81
82
84
85
87
89
90
91
92
93
77








 STACK
VELOCITY
  AFPS

  20.05
  22.16
  21.15
  20.08
  20.08
  20.08
  35.46
  40.21
  41.85
  42.42
  43.47
  45.00
  21.21
  26.80
  32.83
  41.35
  45.49
  44.49
  39.15
  40.28
  41.35
  40.28
  40.28
  40.28

  34.41

-------
ARTISTIC PLATING
              CONDITION 21
                                                    9/30/05
                                                                         TABLE 21-2
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  70
  70
  70
  70
  70
  71
  71
  71
  71
  71
  70
  70
  71
  72
  72
  71
  71
  71
  71
  72
  71
  71
  71
  70

  71
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.35
0.308
12
0.785
2.5
24
60.20
0.99
1.003
0.012
10
-1.07


PITOT
DELP
INH20
0.08
0.14
0.17
0.22
0.32
0.32
0.36
0.39
0.39
0.42
0.45
0.45
0.12
0.12
0.11
0.11
0.10
0.12
0.26
0.40
0.50
0.52
0.54
0.56

59.67
0.78
1661
1604
2726
0.0071
19.4
94.1

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.42
0.73
0.88
1.14
1.66
1.66
1.87
2.03
2.03
2.18
2.34
2.34
0.62
0.62
0.57
0.57
0.57
0.62
1.35
2.08
2.60
2.70
2.81
2.91
1.55










N2
79.10%
METER
TEMP
DEGF
93
92
92
92
93
93
95
97
98
98
99
99
101
101
102
104
105
105
104
105
107
108
108
109
100








 STACK
VELOCITY
  AFPS

  19.00
  25.14
  27.71
  31.52
  38.02
  38.05
  40.36
  42.01
  42.01
  43.59
  45.08
  45.08
  23.30
  23.32
  22.33
  22.31
  21.27
  23.30
  34.30
  42.58
  47.56
  48.51
  49.43
  50.29

  35.25

-------
  ARTISTIC  PLATING
               CONDITION  21
                   9/30/05
                        TABLE 21-3
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
            CO2
           0.00%
   TEST
   POINT
     1
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24
STACK
TEMP
DEGF

  72
  72
  72
  72
  73
  73
  73
  73
  74
  74
  74
  73
  74
  74
  75
  75
  75
  74
  74
  74
  74
  73
  73
 73













02
20.90%
3
29.35
0.308
12
0.785
2.5
24
57.75
0.99
1.003
0.014
11
-1.04



INHG
IN
IN
FT3
MIN

FT3


MILLIGRAMS
ML
INH20
CO N2
0.00% 79.10%
PITOT
DELP
INH20

 0.12
 0.12
 0.11
 0.11
 0.10
 0.11
 0.32
 0.44
 0.52
 0.54
 0.54
 0.56
 0.12
 0.13
 0.15
 0.15
 0.12
 0.11
 0.26
 0.34
0.38
0.45
0.45
0.46
ORIFICE
 DELP
 INH20

  0.62
  0.62
  0.57
  0.57
  0.52
  0.57
  1.66
  2.29
  2.70
  2.81
  2.81
  2.91
  0.62
  0.67
  0.78
  0.78
  0.62
  0.57
  1.35
  1.77
  1.98
 2.34
 2.34
 2.39
METER
TEMP
DEGF
 STACK
VELOCITY
  AFPS
104
102
101
101
101
101
102
102
103
103
105
106
109
110
110
110
111
111
112
112
112
113
114
117
23.31
23.32
22.33
22.33
21.31
22.35
38.12
44.70
48.64
49.57
49.57
50.43
23.37
24.32
26.15
26.15
23.39
22.37
34.40
39.33
41.58
45.21
45.21
45.71
AVERAGE
 73
                 1.45
                 107
              33.88
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
                 57.28
                  0.90
                  1597
                  1532
                 2604
                 0.0086
                  22.5
                  94.6
       SCF
       % VOL
       ACFM
       DSCFM
       M3/HR
       MG/DSCM
       MG/HR

-------
  ELITE
               CONDITION 22
10/18/05
TABLE 22-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  64
  64
  64
  63
  61
  62
  64
  63
  65
  65
  66
  66
  66
  66
  65
  65
  64
  64
  64
  63
  64
  64
  63
  64

  64
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
1
29.25
0.187
12
0.785
5.0
24
104.30
0.99
1.006
0.065
25
-4.1


PITOT
DELP
INH2O
1.00
1.05
1.05
1.15
1.20
1.25
1.55
1.60
1.60
1.55
1.40
1.40
1.40
1.40
1.35
1.45
1.40
1.35
1.65
1.70
1.85
1.80
1.85
1.60

103.39
1.13
3789
3652
6205
0.0222
137J
97.2

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.00
1.05
1.05
1.15
1.20
1.25
1.55
1.60
1.60
1.55
1.40
1.40
1.40
1.40
1.35
1.45
1.40
1.35
1.65
1.70
1.85
1.80
1.85
1.60
1.44










N2
79.10%
METER
TEMP
DEGF
72
74
76
78
80
83
87
91
95
99
114
118
119
121
122
122
123
122
124
125
124
125
127
128
106








                           STACK
                          VELOCITY
                            AFPS

                            67.20
                            68.86
                            68.86
                            71.99
                            73.40
                            74.99
                            83.66
                            84.92
                            85.08
                            83.74
                            79.66
                            79.66
                            79.66
                            79.66
                            78.15
                            80.99
                            79.51
                            78.08
                            86.32
                            87.53
                            91.40
                            90.16
                            91.31
                            85.00

                            80.41

-------
 ELITE
                               CONDITION 22
                                   11/18/05
                                                                         TABLE 22-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  65
  64
  64
  65
  65
  65
  64
  66
  64
  66
  65
  65
  65
  66
  65
  66
  66
  66
  67
  66
  66
  67
  67
  66

  65
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.25
0.187
12
0.785
5.0
24
108.08
0.99
1.006
0.034
23
-4.05


PITOT
DELP
INH20
1.50
1.60
1.40
1.45
1.45
1.40
1.60
1.75
1.85
1.90
1.90
1.75
1.60
1.70
1.75
1.90
1.80
1.65
1.35
1.30
1.25
1.25
1.20
1.15

107.39
1.00
3950
3802
6460
0.0112
72.2
96.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
1.50
1.60
1.40
1.45
1.45
1.40
1.60
1.75
1.85
1.90
1.90
1.75
1.60
1.70
1.75
1.90
1.80
1.65
1.35
1.30
1.25
1.25
1.25
1.15
1.56










N2
79.10%
METER
TEMP
DEGF
118
117
117
118
116
117
119
120
121
122
123
123
124
123
125
125
126
128
127
127
128
128
129
130
123








 STACK
VELOCITY
  AFPS

  82.35
  85.00
  79.51
  80.99
  80.99
  79.59
  85.00
  89.06
  91.40
  92.80
  92.71
  88.98
  85.08
  87.78
  88.98
  92.80
  90.33
  86.48
  78.30
  76.76
  75.27
  75.34
  73.82
  72.20

  83.81

-------
 ELITE
                               CONDITION 22
                                  10/18/05
                                                                        TABLE 22-3
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          C02
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  67
  66
  66
  67
  66
  66
  67
  67
  67
  66
  66
  67
  66
  67
  67
  66
  66
  66
  67
  68
  68
  67
  66
  66

  67
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.25
0.187
12
0.785
5.0
24
103.86
0.99
1.006
0.028
21
-4.1


PITOT
DELP
INH2O
1.05
1.10
1.10
1.10
1.15
1.20
1.55
1.65
1.70
1.80
1.65
1.70
1.95
1.90
1.90
1.80
1.75
1.65
1.40
1.25
1.25
1.20
1.15
1.10

103.25
0.95
3815
3666
6229
0.0096
59.6
96.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
1.05
1.10
1.10
1.10
1.15
1.20
1.55
1.65
1.70
1.80
1.65
1.70
1.95
1.90
1.90
1.80
1.75
1.65
1.40
1.25
1.25
1.20
1.15
1.10
1.46










N2
79.10%
METER
TEMP
DEGF
125
123
123
124
124
125
125
125
126
128
129
130
130
130
131
132
132
133
134
135
135
136
137
137
130








 STACK
VELOCITY
  AFPS

  69.03
  70.61
  70.61
  70.68
  72.20
  73.75
  83.90
  86.56
  87.87
  90.33
  86.48
  87.87
  94.02
  92.89
  92.89
  90.33
  89.06
  86.48
  79.74
  75.42
  75.42
  73.82
  72.20
  70.61

  80.95

-------
 ELITE
                                CONDITION 23
                                   11/15/05
                                                                         TABLE 23-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  69
  69
  69
  70
  71
  71
  70
  70
  71
  70
  70
  70
  70
  71
  71
  71
  71
  71
  71
  71
  71
  71
  72
  72

  71
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
         20.90%
1
29.30
0.187
12
0.785
5.0
24
118.44
0.99
1.003
0.058
30
-5.1


PITOT
DELP
INH20
1.05
1.10
1.20
1.30
1.40
1.60
2.00
2.15
2.45
2.60
2.50
2.25
2.25
2.30
2.25
2.15
2.00
1.85
1.60
1.50
1.45
1.45
1.40
1.35

116.96
1.19
4237
4028
6844
0.0175
119.8
99.6

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H2O
0.77
0.80
0.88
0.95
1.02
1.17
1.46
1.57
1.79
1.90
1.83
1.64
1.64
1.68
1.64
1.57
1.46
1.35
1.17
1.10
1.06
1.06
1.02
0.99
1.31










N2
79.10%
METER
TEMP
DEGF
56
58
60
62
66
69
71
75
80
84
88
90
92
97
98
99
102
103
103
106
108
110
111
111
87








 STACK
VELOCITY
  AFPS

  69.22
  70.85
  74.00
  77.10
  80.08
  85.61
  95.63
  99.15
  105.94
  109.03
  106.91
  101.43
  101.43
  102.64
  101.52
  99.24
  95.72
  92.06
  85.61
  82.89
  81.50
  81.50
  80.16
  78.71

  89.91

-------
 ELITE
                              CONDITION 23
                                 11/15/05
                                                                      TABLE 23-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  72
  72
  71
  71
  72
  72
  72
  72
  72
  71
  72
  72
  73
  73
  72
  72
  72
  72
  72
  72
  72
  72
  72
  72

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.30
0.187
12
0.785
5.0
24
112.09
0.99
1.003
0.0420
36
-4.85


PITOT
DELP
INH20
2.15
2.15
2.05
1.90
i.85
1.75
1.45
1.45
1.30
1.30
1.30
1.25
1.15
1.20
1.25
1.30
1.35
1.50
1.75
1.80
1.85
1.85
1.75
1.60

111.00
1.50
4011
3794
6446
0.0134
86.1
100.4

INHG
IN
IN
FT3
MIN

FT3












MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.57
1.57
1.50
1.39
1.35
1.28
1.06
1.06
0.95
0.95
0.95
0.91
0.84
0.88
0.91
0.95
0.99
1.10
1.28
1.31
1.35
1.35
1.28
1.17
1.16








  N2
79.10%
       METER
       TEMP
       DEGF
        114
 STACK
VELOCITY
  AFPS
107
104
105
107
108
109
109
110
111
112
113
114
117
117
118
118
118
118
118
119
119
120
120
120
99.36
99.33
96.90
93.29
92.14
89.62
81.58
81.58
77.24
77.17
77.24
75.74
72.72
74.28
75.74
77.24
78.71.
82.97
89.62
90.89
92.14
92.14
89.62
85.69
  85.12

-------
 ELITE
               CONDITION 23
11/15/05
                                                                          TABLE 23-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  73
  73
  73
  73
  72
  72
  73
  72
  72
  72
  72
  72
  72
  72
  73
  73
  73
  73
  72
  72
  72
  72
  73
  73

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
3
29.30
0.187
12
0.785
5.0
24
113.42
0.99
1.003
0.0620
31
-4.8


PITOT
DELP
INH20
1.05
1.10
1.15
1.25
1.40
1.50
1.75
1.85
1.85
1.90
1.85
1.75
2.10
2.15
2.15
1.90
1.80
1.75
1.60
1.60
1.45
1.30
1.25
1.10

112.36
1.28
4024
3811
6476
0.0195
126.2
101.2

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.77
0.80
0.84
0.91
1.02
1.10
1.28
1.35
1.35
1.39
1.35
1.28
1.53
1.57
1.57
1.39
1.31
1.28
1.17
1.17
1.06
0.95
0.91
0.80
1.17










N2
79.10%
METER
TEMP
DEGF
112
111
110
110
111
112
112
113
114
116
118
118
119
119
119
119
120
121
121
121
121
121
122
122
117








                            STACK
                          VELOCITY
                            AFPS

                            69.47
                            71.12
                            72.72
                            75.81
                            80.16
                            82.97
                            89.70
                            92.14
                            92.14
                            93.38
                            92.14
                            89.62
                            98.17
                            99.33
                            99.43
                            93.47
                            90.97
                            89.70
                            85.69
                            85.69
                            81.58
                            77.24
                            75.81
                            71.12

                            85.40

-------
ARTISTIC
              CONDITION 24
                                                   11/10/05
                                                                         TABLE 24-1
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
TOTAL NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          C02
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  74
  74
  75
  75
  75
  75
  76
  76
  76
  76
  76
  76
  76
  76
  76
  75
  75
  76
  77
  77
  76
  76
  77
  77

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.45
0.308
10
0.545
5.0
24
95.79
0.99
1.003
0.129
20
-0.31


PITOT
DELP
INH2O
0.10
0.10
0.11
0.13
0.14
0.15
0.18
0.19
0.19
0.18
0.14
0.12
0.18
0.20
0.23
0.23
0.23
0.22
0.17
0.12
0.09
0.09
0.09
0.08

95.00
0.98
850
815
1386
0.0479
66.4
102.3

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.56
0.56
0.62
0.73
0.78
0.84
1.01
1.06
1.06
1.01
0.78
0.67
1.01
1.12
1.29
1.29
1.29
1.23
0.95
0.67
0.50
0.50
0.50
0.45
0.85










N2
79.10%
METER
TEMP
DEGF
58
59
60
62
67
71
73
78
82
86
89
91
95
97
101
102
106
108
111
112
113
114
116
117
90








 STACK
VELOCITY
  AFPS

  21.27
  21.27
  22.33
  24.27
  25.19
  26.08
  28.59
  29.37
  29.37
  28.59
  25.21
  23.34
  28.59
  30.14
  32.32
  32.29
  32.29
  31.61
  27.81
  23.37
  20.22
  20.22
  20.24
  19.08

  25.96

-------
 ARTISTIC
               CONDITION  24
11/10/05
                                                                         TABLE 24-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  78
  78
  78
  78
  78
  78
  77
  75
  76
  78
  78
  77
  78
  78
  75
  73
  72
  72
  73
  73
  74
  75
  74
  74

  76
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
2
29.45
0.308
10
0.545
5.0
24
96.89
0.99
1.003
0.2090
17
-0.31


PITOT
DELP
INH20
0.17
0.20
0.22
0.22
0.23
0.21
0.17
0.16
0.15
0.14
0.12
0.11
0.11
0.15
0.16
0.13
0.14
0.13
0.18
0.20
0.19
0.16
0.14
0.13

96.43
0.82
886
852
1447
0.0765
110.7
99.5

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.95
1.12
1.23
1.23
1.29
1.18
0.95
0.90
0.84
0.78
0.67
0.62
0.62
0.84
0.90
0.73
0.78
0.73
1.01
1.12
1.06
0.90
0.78
0.73
0.92










N2
79.10%
METER
TEMP
DEGF
114
113
113
115
118
119
119
119
119
119
119
120
120
120
120
120
120
120
120
120
120
121
121
121
119








                           STACK
                          VELOCITY
                            AFPS

                            27.83
                            30.19
                            31.67
                            31.67
                            32.38
                            30.94
                            27.81
                            26.93
                            26.10
                            25.26
                            23.39
                            22.37
                            22.39
                            26.15
                            26.93
                            24.23
                            25.12
                            24.21
                            28.51
                            30.05
                            29.32
                            26.93
                            25.17
                            24.25

                            27.08

-------
  ARTISTIC
               CONDITION  24
                                                    11/10/05
TABLE 24-3
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           C02
           0.00%
   TEST
   POINT
     1
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  73
  74
  73
  73
  72
  73
  74
  74
  75
  74
  73
  73
  72
  72
  73
  72
  72
  71
  71
  72
  72
  72
 71
 71

 73
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.45
0.308
10
0.545
5.0
24
96.07
0.99
1.003
0.193
17
-0.32


PITOT
DELP
INH20
0.12
0.13
0.13
0.14
0.15
0.16
0.19
0.21
0.20
0.16
0.13
0.10
0.15
0.20
0.21
0.21
0.22
0.22
0.17
0.15
0.11
0.11
0.10
0.08

95.56
0.83
861
832
1414
0.0713
100.9
100.9

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.67
0.73
0.73
0.78
0.84
0.90
1.06
1.18
1.12
0.90
0.73
0.56
0.84
1.12
1.18
1.18
1.23
1.23
0.95
0.84
0.62
0.62
0.56
0.45
0.88










N2
79.10%
METER
TEMP
DEGF
112
110
110
110
110
111
111
111
112
113
114
115
118
117
117
118
118
119
119
119
119
120
120
119
115








      STACK
    VELOCITY
      AFPS

      23.27
      24.25
      24.23
      25.14
      26.00
      26.88
      29.32
      30.82
      30.11
      26.91
      24.23
      21.25
      26.00
      30.02
      30.80
      30.77
      31.49
      31.46
      27.66
      26.00
      22.27
      22.27
      21.21
      18.97

      26.31

-------
 ELITE
               CONDITION 25
                                                   11/25/05
                                                                         TABLE 25-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          CO2
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
'  23
   24

AVERAGE
STACK
TEMP
DEGF

  73
  73
  73
  73
  74
  74
  74
  74
  74
  74
  73
  73
  74
  74
  74
  74
  73
  73
  73
  73
  73
  72
  72
  72

  73
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
        20.90%
1
29.10
0.187
12
0.785
5.0
24
101.16
0.99
1.003
0.011
21
-4.85


PITOT
DELP
INH20
1.45
1.45
1.50
1.50
1.45
1.45
1.30
1.25
1.20
1.00
0.90
0.85
1.35
1.35
1.40
1.40
1.40
1.45
1.45
1.50
1.50
1.45
1.40
1.30

99.26
0.99
3706
3490
5930
0.0039
23.2
97.6

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.06
1.06
1.10
1.10
1.06
1.06
0.95
0.91
0.88
0.73
0.66
0.62
0.99
0.99
1.02
1.02
1.02
1.06
1.06
1.10
1.10
1.06
1.02
0.95
0.98










N2
79.10%
METER
TEMP
DEGF
68
70
71
73
76
80
84
88
91
92
96
99
101
104
108
110
111
113
117
118
118
119
119
120
98








 STACK
VELOCITY
  AFPS

  81.88
  81.88
  83.28
  83.28
  81.95
  81.95
  77.60
  76.09
  74.56
  68.06
  64.51
  62.69
  79.08
  79.08
  80.53
  80.53
  80.45
  81.88
  81.88
  83.28
  83.28
  81.80
  80.38
  77.45

  78.64

-------
 ELITE
               CONDITION 25
                                                    11/16/05
                                                        TABLE 25-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  71
  71
  71
  72
  72
  72
  72
  71
  70
  70
  71
  71
  71
  71
  72
  72
  72
  71
  71
  72
  72
  72
  73
  74

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
2
29.10
0.187
12
0.785
5.0
24
98.65
0.99
1.003
0.017
19
-4.9


PITOT
DELP
INH2O
1.20
1.25
1.25
1.25
1.30
1.35
1.35
1.40
1.40
1.40
1.35
1.30
1.35
1.35
1.40
1.40
1.40
1.40
1.25
1.05
0.95
0.90
0.90
0.85

97.02
0.91
3568
3373
5731
0.0062
35.5
98.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.88
0.91
0.91
0.91
0.95
0.99
0.99
1.02
1.02
1.02
0.99
0.95
0.99
0.99
1.02
1.02
1.02
1.02
0.91
0.77
0.69
0.66
0.66
0.62
0.91










N2
79.10%
METER
TEMP
DEGF
112
111
111
113
114
114
114
117
118
118
119
119
120
120
121
121
122
123
124
124
124
124
124
124
119








 STACK
VELOCITY
  AFPS

  74.34
  75.88
  75.88
  75.95
  77.45
  78.93
  78.93
  80.30
  80.23
  80.23
  78.86
  77.38
  78.86
  78.86
  80.38
  80.38
  80.38
  80.30
  75.88
  69.61
  66.21
  64.45
  64.51
  62.75

  75.70

-------
ARTISTIC
                              CONDITION  25
                                  11/16/05
                                                                        TABLE 25-3
TEST NO.
BAROMETRIC PRESSURE
TIP DIAMETER
STACK DIAMETER
STACK AREA
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME
PITOT COEFFICIENT
METER COEFFICIENT
NICKEL COLLECTED
WATER COLLECTED
STATIC PRESSURE

ORSAT RESULTS
          CO2
         0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  75
  75
  74
  75
  75
  75
  76
  75
  75
  75
  76
  76
  75
  75
  76
  76
  76
  76
  77
  77
  76
  76
  75
  74

  75
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
3
29.10
0.187
12
0.785
5.0
24
102.50
0.99
1.003
0.017
19
-5


PITOT
DELP
INH2O
1.40
1.40
1.45
1.45
1.40
1.35
1.15
1.05
0.95
0.95
0.90
0.85
1.30
1.35
1.35
1.35
1.40
1.40
1.45
1.45
1.50
1.40
1.40
1.35

100.86
0.88
3639
3415
5803
0.0060
34.5
101.3

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
1.02
1.02
1.06
1.06
1.02
0.99
0.84
0.77
0.69
0.69
0.66
0.62
0.95
0.99
0.99
0.99
1.02
1.02
1.06
1.06
1.10
1.02
1.02
0.99
0.94










N2
79.10%
METER
TEMP
DEGF
118
118
118
119
119
119
120
121
121
121
121
121
122
123
124
125
124
126
127
127
126
127
128
129
123








 STACK
VELOCITY
  AFPS

  80.60
  80.60
  81.95
  82.03
  80.60
  79.15
  73.12
  69.81
  66.40
  66.40
  64.69
  62.87
  77.67
  79.15
  79.23
  79.23
  80.68
  80.68
  82.18
  82.18
  83.51
  80.68
  80.60
  79.08

  77.21

-------
 ARTISTIC
               CONDITION  27
10/17/05
                                                                         TABLE 27-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  68
  69
  69
  70
  70
  71
  72
  72
  73
  73
  73
  73
  73
  73
  73
  74
  74
  74
  74
  74
  73
  73
  73
  73

  72
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
1
29.25
0.308
10
0.545
5.0
24
97.76
0.99
1.003
1.673
24
-0.31


PITOT
DELP
IN H2O
0.16
0.18
0.21
0.21
0.22
0.22
0.19
0.18
0.15
0.13
0.11
0.09
0.07
0.09
0.11
0.11
0.13
0.15
0.19
0.20
0.21
0.21
0.18
0.14

96.28
1.16
872
836
1420
0.6136
871.1
101.2

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.90
1.01
1.18
1.18
1.23
1.23
1.06
1.01
0.84
0.73
0.62
0.50
0.39
0.50
0.62
0.62
0.73
0.84
1.06
1.12
1.18
1.18
1.01
0.78
0.90










N2
79.10%
METER
TEMP
DEGF
62
63
64
67
69
72
76
80
83
87
89
91
93
95
97
98
98
101
102
102
103
105
107
109
88








                           STACK
                          VELOCITY
                            AFPS

                            26.85
                            28.51
                            30.79
                            30.82
                            31.55
                            31.58
                            29.37
                            28,59
                            26.12
                            24.32
                            22.37
                            20.24
                            17.85
                            20.24
                            22.37
                            22.39
                            24.34
                            26.15
                            29.43
                            30.19
                            30.91
                            30.91
                            28.62
                            25.24

                            26.66

-------
 ARTISTIC
              CONDITION 27
                                                   10/17/05
                                                                         TABLE 27-2
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
          C02
          0.00%
  TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
STACK
TEMP
DEGF

  74
  74
  74
  74
  74
  74
  74
  74
  73
  73
  74
  74
  74
  74
  75
  75
  75
  75
  75
  74
  74
  75
  75
  75

  74
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
2
29.25
0.308
10
0.545
5.0
24
95.80
0.99
1.003
0.755
31
-0.33


PITOT
DELP
IN H20
0.08
0.09
0.11
0.11
0.13
0.14
0.17
0.19
0.22
0.21
0.20
0.18
0.16
0.18
0.20
0.21
0.21
0.22
0.16
0.15
0.12
0.11
0.09
0.08

94.57
1.52
859
817
1388
0.2819
391.4
101.7

IN HG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
IN H2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
IN H20
0.45
0.50
0.62
0.62
0.73
0.78
0.95
1.06
1.23
1.18
1.12
1.01
0.90
1.01
1.12
1.18
1.18
1.23
0.90
0.84
0.67
0.62
0.50
0.45
0.87










N2
79.10%
METER
TEMP
DEGF
98
97
97
98
99
99
100
102
103
106
108
109
110
111
112
112
112
113
115
116
116
117
117
118
108








 STACK
VELOCITY
  AFPS

  19.11
  20.25
  22.39
  22.39
  24.34
  25.26
  27.84
  29.43
  31.64
  30.91
  30.19
  28.64
  27.01
  28.64
  30.22
  30.97
  30.97
  31.70
  27.03
  26.15
  23.39
  22.41
  20.27
  19.11

  26.26

-------
 ARTISTIC
              CONDITION  27
10/17/05
TABLE 27-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  76
  76
  76
  77
  77
  77
  77
  77
  78
  78
  78
  78
  78
  79
  79
  79
  79
  78
  78
  79
  79
  78
  78
  78

  78
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
3
29.25
0.308
10
0.545
5.0
24
96.74
0.99
1.003
1.393
29
-0.33


PITOT
DELP
INH2O
0.18
0.20
0.22
0.23
0.22
0.17
0.15
0.14
0.11
0.11
0.10
0.08
0.10
0.11
0.12
0.12
0.15
0.18
0.20
0.21
0.21
0.20
0.18
0.16

95.59
1.41
879
831
1412
0.5146
726.6
101.1

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
1.01
1.12
1.23
1.29
1.23
0.95
0.84
0.78
0.62
0.62
0.56
0.45
0.56
0.62
0.67
0.67
0.84
1.01
1.12
1.18
1.18
1.12
1.01
0.90
0.90










N2
79.10%
METER
TEMP
DEGF
109
108
108
108
109
110
110
111
112
113
115
116
118
118
118
119
120
120
120
121
121
122
123
123
116








                           STACK
                          VELOCITY
                            AFPS

                            28.71
                            30.25
                            31.73
                            32.47
                            31.76
                            27.92
                            26.22
                            25.33
                            22.48
                            22.48
                            21.43
                            19.17
                            21.43
                            22.50
                            23.50
                            23.50
                            26.27
                            28.75
                            30.31
                            31.08
                            31.08
                            30.31
                            28.75
                            27.11

                            26.86

-------
 ARTISTIC
               CONDITION  28
                                                    10/19/05
                                                        TABLE 28-1
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 TOTAL NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  69
  70
  70
  69
  69
  69
  69
  70
  70
  69
  68
  68
  68
  68
  69
  69
  68
  69
  69
  68
  69
  69
  69
  68

  69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          02
         20.90%
1
29.30
0.308
10
0.545
5.0
24
96.02
0.99
1.003
0.347
24
-0.33


PITOT
DELP
INH20
0.15
0.17
0.20
0.21
0.22
0.23
0.18
0.17
0.14
0.11
0.09
0.08
0.09
0.10
0.11
0.13
0.15
0.17
0.17
0.18
0.20
0.19
0.17
0.14

94.73
1.18
860
830
1411
0.1293
182.4
100.2

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.84
0.95
1.12
1.18
1.23
1.29
1.01
0.95
0.78
0.62
0.50
0.45
0.50
0.56
0.62
0.73
0.84
0.95
0.95
1.01
1.12
1.07
0.95
0.78
0.88










N2
79.10%
METER
TEMP
DEGF
63
63
66
68
70
73
78
81
83
87
89
91
93
95
97
99
100
101
102
103
106
108
108
109
89








 STACK
VELOCITY
  AFPS

  26.01
  27.71
  30.06
  30.77
  31.49
  32.20
  28.49
  27.71
  25.15
  22.27
  20.12
  18.97
  20.12
  21.21
  22.27
  24.21
  25.98
  27.69
  27.69
  28.46
  30.03
  29.27
  27.69
  25.10

  26.28

-------
  ARTISTIC
              CONDITION 28
10/19/05
TABLE 28-2
  TEST NO.
  BAROMETRIC PRESSURE
  TIP DIAMETER
  STACK DIAMETER
  STACK AREA
  SAMPLING TIME PER POINT
  NUMBER OF POINTS
  METER VOLUME
  PITOT COEFFICIENT
  METER COEFFICIENT
  NICKEL COLLECTED
  WATER COLLECTED
  STATIC PRESSURE

  ORSAT RESULTS
           C02
          0.00%
   TEST
   POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  69
  69
  68
  68
  68
  68
  69
  69
  68
  68
  68
  68
  68
  68
  69
  70
  70
  69
  69
  69
  70
  70
 70
 71

 69
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
        20.90%
2
29.30
0.308
10
0.545
5.0
24
98.03
0.99
1.003
0.445
25
-0.32


PITOT
DELP
INH20
0.10
0.11
0.13
0.15
0.17
0.17
0.18
0.20
0.21
0.20
0.17
0.14
0.16
0.19
0.21
0.21
0.22
0.20
0.18
0.17
0.15
0.13
0.11
0.10

96.93
1.20
887
856
1454
0.1621
235.7
99.5

INHG
IN
IN
FT3
MIN

FT3












MILLIGRAMS
ML
INH20
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH20
0.56
0.62
0.73
0.84
0.95
0.95
1.01
1.12
1.18
1.12
0.95
0.78
0.90
1.06
1.18
1.18
1.23
1.12
1.01
0.95
0.84
0.73
0.62
0.56
0.92








        N2
      79.10%
             METER
              TEMP
              DEGF
              107
     STACK
    VELOCITY
      AFPS
101
99
99
99
99
101
101
102
103
104
107
108
109
109
110
110
110
111
111
112
113
113
113
114
21.23
22.27
24.19
25.98
27.66
27.66
28.49
30.03
30.74
30.00
27.66
25.10
26.83
29.24
30.77
30.80
31.52
30.03
28.49
27.69
26.03
24.23
22.29
21.27
     27.09

-------
 ARTISTIC
              CONDITION  28
10/19/05
TABLE 28-3
 TEST NO.
 BAROMETRIC PRESSURE
 TIP DIAMETER
 STACK DIAMETER
 STACK AREA
 SAMPLING TIME PER POINT
 NUMBER OF POINTS
 METER VOLUME
 PITOT COEFFICIENT
 METER COEFFICIENT
 NICKEL COLLECTED
 WATER COLLECTED
 STATIC PRESSURE

 ORSAT RESULTS
           CO2
          0.00%
   TEST
  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24

AVERAGE
STACK
TEMP
DEGF

  70
  71
  71
  71
  71
  70
  70
  70
  70
  69
  70
  69
  70
  70
  70
  69
  69
  69
  70
  70
  69
  69
  69
  69

  70
DRY STANDARD VOLUME
PERCENT WATER VAPOR
FLOW RATE
NICKEL CONCENTRATION
NICKEL EMISSION RATE
ISOKINETIC PERCENT
          O2
         20.90%
3
29.30
0.308
10
0.545
5.0
24
98.63
0.99
1.003
0.695
24
-0.3


PITOT
DELP
INH2O
0.17
0.18
0.21
0.21
0.21
0.18
0.18
0.17
0.16
0.13
0.11
0.10
0.11
0.12
0.13
0.15
0.18
0.19
0.17
0.19
0.20
0.20
0.18
0.16

97.55
1.14
892
860
1461
0.2516
367.5
99.7

INHG
IN
IN
FT3
MIN

FT3






















MILLIGRAMS
ML
INH2O
CO
0.00%




























SCF
% VOL
ACFM
DSCFM
M3/HR
MG/DSCM
MG/HR





ORIFICE
DELP
INH2O
0.95
1.01
1.18
1.18
1.18
1.01
1.01
0.95
0.90
0.73
0.62
0.56
0.62
0.67
0.73
0.84
1.01
1.06
0.95
1.06
1.12
1.12
1.01
0.90
0.93










N2
79.10%
METER
TEMP
DEGF
104
102
101
101
102
103
105
107
108
109
109
110
110
110
111
111
111
112
112
113
113
113
114
114
109








                           STACK
                          VELOCITY
                            AFPS

                            27.71
                            28.54
                            30.83
                            30.83
                            30.83
                            28.51
                            28.51
                            27.71
                            26.88
                            24.21
                            22.29
                            21.23
                            22.29
                            23.28
                            24.23
                            26.01
                            28.49
                            29.27
                            27.71
                            29.30
                            30.03
                            30.03
                            28.49
                            26.86

                            27.25

-------
        SAMPLE PARTICULATE CALCULATION SHEET
TEST NO.
BAROMETRIC PRESSURE (Pb)
TIP DIAMETER (d)
STACK DIAMETER (D)
STACK AREA (As=PI*DA2/576)
SAMPLING TIME PER POINT
NUMBER OF POINTS
METER VOLUME (Vm)
PITOT COEFFICIENT (cp)
METER COEFFICIENT (GAMA)
PARTICULATE COLLECTED (Mn)
WATER COLLECTED (Vf-Vi)
STATIC PRESSURE (Ps)
ORSAT RESULTS
          C02
         6.40%

  POINT
    1
    2
    3
    4
    5
    6
    7
    8
    9
   10
   11
   12
   13
   14
   15
   16
   17
   18
   19
   20
   21
   22
   23
   24

AVERAGE
          O2
         13.40%
STACK
 TEMP
 DEGF

 275
 280
 278
 278
 280
 281
 282
 280
 280
 277
 276
 27.5
 282
 283
 282
 283
 280
 280
 280
 278
 279
 280
 277
 275

 279
(Tsavg)
DRY STANDARD VOLUME (Vmstd)
PERCENT WATER VAPOR %H2O)
FLOW RATE (Q)
PARTICULATE CONCENTRATION (cs)
PARTICULATE EMISSION RATE (ER)
LB PART PER 1000 LB GAS (EC)
ISOKINETIC PERCENT (I)
Sample
29.45
0.305
72
28.274
2.5
24
66.53
0.84
0.990
0.0500
32
-0.5


DELTA
P
INH2O
0.32
0.37
0.37
0.40
0.50
0.70
0.72
0.72
0.62
0.57
0.65
0.60
0.70
0.82
0.85
0.75
0.59
0.60
0.60
0.65
0.72
0.72
0.65
0.30

1NHG
IN
IN
FT2
MIN

FT3


GRAMS
ML
INH20
CO
0.00%





























ORIFICE
DELP
INH20
2.20
2.55
2.55
2.80
3.50
4.90
5.00
5.00
4.30
3.90
4.50
4.20
4.90
5.70
6.00
5.20
4.10
4.20
4.20
4.50
5.00
5.00
4.50
2.10
4.20
(DELH)
N2
80.20%
METER
TEMP
DEGF
35
38
40
41
43
44
44
44
45
46
47
48
50
53
56
60
62
65
67
70
72
74
75
75
54
(Tm)
                          65.51  SCF
                           2.25  % VOL
                          86905 ACFM
                          59651 DSCFM
                          101360 M3/HR
                          0.0118 GR/DSCF
                           6.08  LB/HR
                          0.0219
                          102.0
VELOCITY

  AFPS

  37.52
  40.48
  40.42
  42.03
  47.05
  55.71
  56.54
  56.46
  52.40
  50.14
  53.50
  51.37
  55.75
  60.38
  61.43
  57.74
  51.11
  51.54
  51.54
  53.58
  56.43
  56.46
  53.54
  36.32

  51.23
  (vsavg)

-------
            PARTICULATE SAMPLE CALCULATION FORMULA

 1.    DRY MOLECULAR WEIGHT (Md)     Ib/lb-mole

      Md  = .44*%CO2 + .32*%02 +  ,28*%N2 + .28*%CO

 2.    WATER VAPOR PERCENT (%H2O)

      Vw std  =  0.04707*(Vf - Vi)

           where: Vw std = standard cubic feet of water vapor
           Vf   = Final volume of impingers, ml
           Vi   = Initial volume of impingers, ml

      %H2O  =  Vw std * 100/(Vm std + Vwstd)

           where  Vm std = standard cubic feet of gas sampled

 3.    WET MOLECULAR WEIGHT (Ms)     Ib/lb-mole

      Ms = Md*(1 - %H20/100)  + 18*%H2O/100

4.    STACK PRESSURE (Ps)            in. Hg.

      Ps = Pb +  Pg/13.6

           where: Pb = barometric pressure (uncorrected), in. Hg
           Pg =  stack gauge pressure, in. H2O
           13.6  = specific gravity of mercury (Hg)

5.    AVERAGE STACK VELOCITY (vs)    feet per second

      Vs = Kp*Cp*DELP * (Tsavg/(Ps*Ms))A0.5

           where: Kp = 85.49 unit conversion
           Cp =  0.84, pitot tube calibration factor
           DELP = average of square root of velocity head, in. H2O
           Tsavg = average stack temperature,  deg R (460+F)
           Ps = stack pressure
           Ms =  wet molecular weight

-------
 6.    STACK GAS FLOW RATE (Qs)       std. cubic feet per minute

       Qs = 60*(1 -%H2O/100)*Vs*A*(528*Ps/Tsavg/29.92)

            where: A = stack area, ft2
            528 = std temperature, deg R
            29.92  =  std pressure, in. Hg

 7.    DRY GAS VOLUME (Vmstd)         dry std. cubic feet

       Vm std = (GAMAC*(Pb+ DELH/13.6)729.92) * Vm

            where: GAMAC = dry gas meter calibration factor corrected for
                          meter temperature (GAMA+(Tm-70)*.00012)
            Vm =  volume of dry gas metered, cubic feet
            Tm = average meter temperature, degrees F
            DELH  =  average orifice pressure drop, in.H2O

 8.    PARTICULATE  CONCENTRATION (cs)     grains per dry standard
                                            cubic foot
      Cs =  Mn*15.43A/mstd
            where:  Mn  = particulate captured, grams
            15.43  = grains per gram

 9.    EMISSION RATE (ER)               pounds per hour

      PMRA = Mn*A*60/(t*An*453.6)       AREA METHOD Ib/hr

      PMRC = Cs*Qs*607(15.43*453.6)      CONG. METHOD Ib/hr

      ER =  (PMRA +  PMRC)/2

            where: An = area of sampling nozzle,  square feet

10.   EMISSION CONCENTRATION (EC)   lb/1000 Ib exhaust gas

      EC = ER* 386700 * (1-%H2O/100)/(Qs*60*Ms)

           where: 386700  =  cubic feet per Ib mole *  1000

11.    ISOKINETIC SAMPLING PERCENTAGE (I)

      I = PMRA/PMRC

-------
PROJECT # 2005110201:  METHOD 306A FOR NICKEL
                                                                                              8
SA#
1
2
3
4
*
SAMPLE DESCRPTION
ABQC -CONDITION #15-
RUN#1
ABQC - CONDITION #15 -
RUN #2
ABQC -CONDITION #15-
RUN#3
ABQC -CONDITION #15-
BLANK
MDL ' '',
PH
<2.0
<2.0
<2.0
<2.0
<2.Q
Sample
Fraction
385.0
371.0
390.0
322.0

REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
-V-"HN03n
Analytical
Fraction
50.0
50.0
50.0
50.0
50.0
Nl mg/L
0.612
0.400
0.547
P 0.074"' "*",
x > " a
*K
0.075-;
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.031
0.020
0.027
. /0.004
"- Of@Q4
    Samples that read 
-------
                          LABORATORIES, INC.
                   TESTING 	 CONSULTING
                                                          Engineering Services
                                                          3158S. KolinAve.
                                                          Chicago IL 60623-4889
                                                          Phone: 773-254-2406
                                                          FAX: 773-254-6661
Company:  ABQC Corporation

Project Type:  Stack Test Analysis for Nickel Emissions
RESULTS:

Condition 15
SAMPLE I.D.
Test Run #1
Test Run #2
Test Run #3
Blank ( 5% HNO, 10% H?O7)
TEST CONC.1
0.612mg/L
0.400 mg/L
0.547 mq/L
0.074 mq/L
ACTUAL EMISSION 2
0.0138 mg/dscm
0.0083 mg/dscm
0.0120 mg/dscm
N/A
1 Analyzed by SCL
2 As calculated by SCL (see attached)
Section 1
       SUPPLEMENTAL CALCULATIONS FOR 306 STACK TEST REPORT
            Equation (taken from Method 306A, FR 1/25/95, Pg. 4992):
                                       460)
                                              bCt:

-------
                                                                        Page -2-
           LABORATORIES, INC.
           ABQC Corporation Nickel Emissions 306 Stack Test Report
Where:
Ccr Concentration in stack gas in mg/dscm
Mcr =Amount of Cr in sample from stack sampling in micrograms
Tm  =Dry gas meter temperature, ° F
Ym  =Dry gas meter correction factor
Vm  =Dry gas meter volume in ft3
Pbar =Barometric pressure in inches of Hg
Stack Test Results     Test Run #1
(385 ml in test trial #1 sample)

Mcr =(0.612 mg/L - 0.074 mg/L )x(50 ml) = 26.9 micrograms
Tm = 74.23 °F
Ym = 0.9817 (see calculation in section 2)
Vm =(2.011 m3)(35.315 ft3/m3) = 71.0185 ft3
Pbar = 29.9 in Hg
Ccr=  (26.9) (74.23 + 460)             = 0.0138 mg/dscm
    (499.8)(0.9817)(71.0185)(29.9)
Stack Test Results    Test Run #2
(371 ml in test trial #2 sample)

Mcr =(0.400 mg/L - 0.074 mg/L)x(50 ml_) = 16.3 micrograms
Tm = 78.1°F
Ym = 0.9817 (see calculation in section 2)
Vm = (2.048 m3)(35.315 ft3/m3) = 72.3251 ft3
Pbar = 29.84 in Hg

Ccr =  (16.3) (78.1 +460)              = 0.0083 mg/dscm
    (499.8)(0.9817)(72.3251 )(29.84)

-------
                                                                        Page -3-
           LABORATORIES, INC.
           ABQC Corporation Nickel Emissions 306 Stack Test Report


Stack Test Results     Test Run #3
(390 ml in test trial #3 sample)

Mcr =(0.547 mg/L - 0.074 mg/L)x(50 ml) = 23.65 micrograms
Tm = 80.13°F
Ym = 0.9817 (see calculation in section 2)
Vm = (2.060 m3)(35.315 ft3/m3) = 72.75 ft3
Pbar = 29.8 in Hg

Ccr =  (23.65U80.13 + 460)                 = 0.0120 mg/dscm
    (499.8)(0.9817)(72.75)(29.8)
Section 2

Calculation for Post Test Gas Meter Calibration (Taken 12/06/05):

The meter was run for 6 minutes with a critical orifice that allows 0.75 cfm. The meter
recorded a volume of 4.591 ft3.  The average temperature was 53.37° F and the
barometric pressure was 30.1 in. of mercury.  To calculate the standard volume of air
passed through the critical orifice:
      Vm(std) = (K,)(VJ Pbar + (AH/13.6)    From EPA Method 5
                            Tn
                              m
where:
K, = 17.64
Vm = volume of gas recorded from post test in ft3
Pbar = barometric pressure in inches of mercury
AH = average pressure differential across the orifice in inches of water provided on
      orifice calibration sheet
Tm = temperature in degrees R

-------
                                                                           Page -4-
   CONTROL^ LABORATORIES, INC.
           ABQC Corporation Nickel Emissions 306 Stack Test Report
      Vm(std) = M7.64M4.591V 30.1 +(1.97/13.6)1
                         53.37 + 460
      Vm(std) = 4.771 ft
To correct to standard conditions:


                        „ '  P bar
            V cr
                                   amb
where:
K' = factor from orifice calibration sheet provided with critical orifice by manufacturer
Pbar = barometric pressure in inches of mercury
0 = time in minutes
Tamb = ambient temperature in degrees R
            Vcr(std) =       0.5876 (30.1 K6)
                           /53.37 + 460
            Vcr(std) =      4.6836 ft3
the Y value for the post test is then:
                Y
                JL  m {after test )   ~TT
                                  cr
                                   i (std )

-------
                                                                          Page -5-
   CONTROL''LABORATORIES, INC.
           ABQC Corporation Nickel Emissions 306 Stack Test Report

Therefore,

            Ym(aftertesl) =   4.6836
                         4.771

            Ym(aftertest) =   0.9817


Post Ym value as compared to pretest Ym value

            Ym(pre,est)  =  0.9822      =1.0005
            Ym(a«ertest)     0-9817

Post Ym value as compared to manufacturer's Ym value

            Ym(manu)   =   0980:       =0.9983
            Ym(aftertest)     0.9817

*As provided on the meter calibration sheet provided with the meter by the manufacturer



Since the Y value is between 0.95 and 1.05, the gas meter is acceptable.

-------
PROJECT # 2005120032:  METHOD  306A FOR  NICKEL
                                                                                               8
SA#
1
2
3
4
*
SAMPLE DESCRPTION
12/01/2005 -CONDITION
#26 - RUN #1
12/01/2005 -CONDITION
#26 - RUN #2
12/01/2005 -CONDITION
#26 - RUN #3
12/01/2005 -BLANK
MOL
PH
<2.0
<2.0
<2.0
<2.0
<2.0
Sample
Fraction
397.0
395.0
388.0
360.0

REAGENTS FOR
DIG.
HN03
HNO3
HNO3
HNO3
HNO3
Analytical
Fraction
50.0
50.0
50.0
50.0
50-P;-\\
Nl mg/L
1.324
2.388
2.139
0.101
0.075
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.066
0.119
0.107
0.005
0,004
    Samples that read 
-------
               CONTROL' LABORATORIES, ING.
                   TESTING
                               CONSULTING
Company:   Elite Metal Finishing

Project Type: Stack Test Analysis for Nickel Emissions
                                                          Engineering Services
                                                          3158 S. KoBn Ave.
                                                          Chicago IL 60623-4889
                                                          Phone: 773-254-2406
                                                          FAX: 773-254-6661
RESULTS:

Condition 26
SAMPLE I.D.
Test Run #1
Test Run #2
Test Run #3
Blank ( 5% HNO,, 10% HA)
TEST CONC.1
1.324mg/L
2.388 mg/L
2.139mg/L
0.101 mg/L
ACTUAL EMISSION 2
0.0314 mg/dscm
0.0608 mg/dscm
0.0532 mg/dscm
N/A
1 Analyzed by SCL
2 As calculated by SCL (see attached)
Section 1
       SUPPLEMENTAL CALCULATIONS FOR 306 STACK TEST REPORT
            Equation (taken from Method 306A, FR 1/25/95, Pg. 4992):
C=f
                      (4998 MF
                               bar/

-------
                                                                        Page -2-
   CONTROLS LABORATORIES, INC.
          Elite Metal Finishing Nickel Emissions 306 Stack Test Report
Where:
Ccr Concentration in stack gas in mg/dscm
Mcr =Amount of Cr in sample from stack sampling in micrograms
Tm =Dry gas meter temperature, ° F
Ym =Dry gas meter correction factor
Vm =Dry gas meter volume in ft3
Pbar =Barometric pressure in inches of Hg
Stack Test Results     Test Run #1
(397 ml in test trial #1 sample)

Mcr =(1-324 mg/L - 0.101  mg/L )x(50 ml_) = 61.15 micrograms
Tm = 80.85 °F
Ym = 0.9817 (see calculation in section 2)
Vm =(2.048  m3)(35.315 ft3/m3) = 72.3251 ft3
Pbar = 29.68 in Hg
Ccr =  (61.15) (80.85+ 460)                  =  0.0314 mg/dscm
    (499.8)(0.9817)(72.3251)(29.68)
Stack Test Results    Test Run #2
(395 ml in test trial #2 sample)

Mcr =(2.388 mg/L - 0.101 mg/L)x(50 ml) = 114.35 micrograms
Tm = 84.17 °F
Ym = 0.9817 (see calculation in section 2)
Vm = (2.052 m3)(35.315 ft3/m3) = 72.4664 ft3
Pbar = 29.62 in Hg

Ccr=  (114.35) (84.17+ 460)                = 0.0608 mg/dscm
    (499.8)(0.9817)(69.89)(29.84)

-------
                                                                        Page -3-
    CONTROL LABORATORIES, INC.
          Elite Metal Finishing Nickel Emissions 306 Stack Test Report


Stack Test Results     Test Run #3
(388 ml in test trial #3 sample)

Mcr =(2.139 mg/L - 0.101 mg/L)x(50 ml_) = 101.9 micrograms
Tm = 84.1 °F
Ym = 0.9817 (see calculation in section 2)
Vm = (2.032 m3)(35.315 ft3/m3) = 71.7601 ft3
Pbar = 29.61 in Hg

Ccr =  (101.9) (84.1 +460)             = 0.0532 mg/dscm
    (499.8)(0.9817)(71.7601 )(29.61)
Section 2

Calculation for Post Test Gas Meter Calibration (Taken 12/06/05):

The meter was run for 6 minutes with a critical orifice that allows 0.75 cfm.  The meter
recorded a volume of 4.591 ft3.  The average temperature was 53.37° F and the
barometric pressure was 30.1 in. of mercury. To calculate the standard volume of air
passed through the critical orifice:
      Vm(std) = (MVJ Pbar + (AH/13.6)     From EPA Method 5
                              m
where:
K! = 17.64
Vm = volume of gas recorded from post test in ft3
Pbar = barometric pressure in inches of mercury
AH = average pressure differential across the orifice in inches of water provided on
      orifice calibration sheet
Tm = temperature in degrees R

-------
                                                                             Page -4-


   X-   rJ.-
   enIi,Ti&
    CONTROL^ LABORATORIES, INC.
           Elite Metal Finishing Nickel Emissions 306 Stack Test Report
       Vm(std) = (17.64)(4.591)[ 30.1 + (1.97/13.6)1
                          53.37 + 460
       Vm(std) = 4.771 ft3
To correct to standard conditions:
            V       =  K   ^ bar
            V  cr (std )
                                   amb
where:
K' = factor from orifice calibration sheet provided with critical orifice by manufacturer
Pbar = barometric pressure in inches of mercury
0 = time in minutes
Tamb = ambient temperature in degrees R
             Vcr(std) =      0.5876(30.1)(6)
                            /5S.37 + 460
             Vcr(std) =      4.6836 ft3
the Y value for the post test is then:
          Y
          -L  m (after test )   T7"
                             • (std )
                             i (std )

-------
                                                                           Page -5-
            TC
    CONTROL''LABORATORIES, INC.
           Elite Metal Finishing Nickel Emissions 306 Stack Test Report

Therefore,

             Ym(aftertest) =   4.6836
                         4.771

             Ym(aftertes<> =   0.9817


Post Ym value as compared to pretest Ym value

             Ym(pre,est)  =  0.9822      = 1.0005
             Ym(after»est>    0.9817

Post Ym value as compared to manufacturer's Ym value

             Ym(manu)  =   098Q:       =0.9983
             Ym(after.est)    0.9817

*As provided on the meter calibration sheet provided with the meter by the manufacturer



Since the Y value is between 0.95 and 1.05, the gas meter is acceptable.

-------
PROJECT # 2005100306:   METHOD  306A FOR NICKEL
                                                                                                  8
SA#
1
2
3
4
5
*
SAMPLE DESCRPTION
Condition 29; Run 1
Condition 29; Run 2
Condition 29; Run 3
Field Blank 0.1 N HNO3
Field Blank 5% HNO3 &
10%H202
MDL
PH
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
Sample
Fraction
355.0
356.0
378.0
332.0
288.0
288.0
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
HNO3
HNO3
Analytical
Fraction
50.0
50.0
50.0
50.0
50.0
50.0
Nl mg/L
15.9
6.51
7.83
- ""ub7
-------
                         LABORATORIES, INC.
                                                        Engineering Services
                                                        3158S. KolinAve.
                                                        Chicago IL 60623-4889
                                                        Phone: 773-254-2406
                                                        FAX: 773-254-6661
                   TESTING
                              CONSU LTING
Company:  Artistic Plating

Project Type: Stack Test Analysis for Nickel Emissions


RESULTS:

Condition 29
SAMPLE I.D.
Test Run #1
Test Run #2
Test Run #3
Blank ( 5% HNO,, 10% H,O9)
TEST CONC.1
15.9 mg/L
6.51 mg/L
7.83 mg/L
0.222 mg/L
ACTUAL EMISSION 2
0.3997 mg/dscm
0.1645 mg/dscm
0.2176 mg/dscm
N/A
1 Analyzed by SCL
2 As calculated by SCL (see attached)
Section 1
       SUPPLEMENTAL CALCULATIONS FOR 306 STACK TEST REPORT
            Equation (taken from Method 306A, FR 1/25/95, Pg. 4992):
                        (Mj(7> 460)
                                             ba,

-------
                                                                        Page -2-
    CONTROL'LABORATORIES, INC.
             Artistic Plating Nickel Emissions 306 Stack Test Report
Where:
Ccr Concentration in stack gas in mg/dscm
Mcr =Amount of Cr in sample from stack sampling in micrograms
Tm =Dry gas meter temperature, ° F
Ym =Dry gas meter correction factor
Vm =Dry gas meter volume in ft3
Pbar =Barometric pressure in inches of Hg
Stack Test Results     Test Run #1
(355 ml in test trial #1 sample)

Mcr =(15.9 mg/L - 0.222 mg/L )x(50 ml) = 783.9 micrograms
Tm = 75.96 °F
Ym = 0.9817 (see calculation in section 2)
Vm =(2.027 m3)(35.315 ft3/m3) = 71.5835 ft3
Pbar = 29.93 in Hg
Ccr=  (783.9) (75.96 + 460)            =  0.3997 mg/dscm
    (499.8)(0.9817)(71.5835)(29.93)
Stack Test Results    Test Run #2
(356 ml in test trial #2 sample)

Mcr =(6.51 mg/L - 0.222 mg/L)x(50 ml) = 314.4 micrograms
Tm = 75.08° F
Ym = 0.9817 (see calculation in section 2)
Vm = (1.979 m3)(35.315 ft3/m3) = 69.89 ft3
Pbar = 29.84 in Hg

Ccr=  (314.4) (75.08+ 460)                 = 0.1645 mg/dscm
    (499.8)(0.9817)(69.89)(29.84)

-------
                                                                        Page -3-
   CONTROL^ LABORATORIES, INC.
             Artistic Plating Nickel Emissions 306 Stack Test Report
Stack Test Results     Test Run #3
(378 ml in test trial #3 sample)

Mcr =(7.83 mg/L - 0.222 mg/L)x(50 ml) = 380.4 micrograms
Tm = 74.14 °F
Ym = 0.9817 (see calculation in section 2)
Vm = (1.808 m3)(35.315 ft3/m3) = 63.85 ft3
Pbar = 29.8 in Hg

Ccr =  (380.4H74.14 + 460)                  = 0.2176 mg/dscm
    (499.8)(0.9817)(63.85)(29.8)
Section 2

Calculation for Post Test Gas Meter Calibration (Taken 12/06/05):

The meter was run for 6 minutes with a critical orifice that allows 0.75 cfm. The meter
recorded a volume of 4.591 ft3.  The average temperature was 53.37° F and the
barometric pressure was 30.1 in. of mercury.  To calculate the standard volume of air
passed through the critical orifice:
      vm(std) = (K-,)(Vm) Ptor + fAH/13.6)    From EPA Method 5
                            Tm
where:
K, = 17.64
Vm = volume of gas recorded from post test in ft3
Pbar = barometric pressure in inches of mercury
AH = average pressure differential across the orifice in inches of water provided on
      orifice calibration sheet
Tm = temperature in degrees R

-------
                                                                             Page -4-
            LABORATORIES, INC.
              Artistic Plating Nickel Emissions 306 Stack Test Report
       Vm(std) = (17.64)(4.591)[ 30.1 + (1.97/13.6)1
                          53.37 + 460
       Vm(std) = 4.771 ft3
To correct to standard conditions:


                             ,   p ,    (M)
                          T, '  r bar  w
              Vcr(s,d~)
                                     amb
where:
K1 - factor from orifice calibration sheet provided with critical orifice by manufacturer
Pbar = barometric pressure in inches of mercury
0 = time in minutes
Tamb = ambient temperature in degrees R
             Vcr(std) =       0.5876 (30.1K6)
                            /5S.37 + 460
             Vcr(std) =      4.6836 ft3
the Y value for the post test is then:
                            V   ,   ^
                         	 r   cr (irf _)
               m (after test )   yr
                            K  m (std }

-------
                                                                            Page -5-
    CONTROLS LABORATORIES. INC.
              Artistic Plating Nickel Emissions 306 Stack Test Report

Therefore,

             Ym(aftertest) =   4.6836
                          4.771
             Ym(aftertest) =   0.9817
Post Ym value as compared to pretest Ym value

             Ym(pre,est)   =  0.9822      =1.0005
             Ym(after,est>     0.9817

Post Ym value as compared to manufacturer's Ym value

             Ym(manu)  =   098Q:       =0.9983
             ' m(after test)     0.001 /

*As provided on the meter calibration sheet provided with the meter by the manufacturer
Since the Y value is between 0.95 and 1.05, the gas meter is acceptable.

-------
                              Appendix B



Calculation Worksheets for Ambient Nickel Concentrations and Field Log Sheets

-------
Company Name:	Reliable- Electroless Nickel Plating
NAME/AREA
Condition 3
Conditon 3
Blank
Condition 4
Condition 4
Blank
Condition 5
Condition 5
Blank
Condition 6
Condition 6
Blank
-East
-West

-East
-West
-East
-West

-East
-West

Sample LPM Total Blank
PARAMETER Date mg/L Minutes Flowrate LITERS mg/L RESULTS (mg/m3) OS HA LI M
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
NI
0,21
0,18
0
0.18
0,16
0
0.21
0.19
0
0.51
0.40
0
420
420
0
377
376
0
378
377
0
409
409
0
2.0
2.0
0
2.0
2.0
0
2.0
2.0
0
2.0
2.0
0
840 0;|-®"p_* :&Q06200
o o;%^a"!;4|;^V'/-
754 o&^.^ttwewB,
752 0 '\fe*l^yHv$006IH8<
0 O^'-J^'v^'/'' '"."' ''
756 O^M";iV''iO,OOS'94^i
Tf\A n r^lf vW5^?^ ^ '5^* A fif^f^infV
0 0" "'•' "f^^''^', f * ','
8-18 0^ ^ ,^>, ''j^tOj6587,
818 0 ''f^J^f^'e"'^'^^^^,^^
o ol""',!^1!^ "'^ "* "
1.00
1.00

1.00
1.00
1.00
1.00

1.00
1.00

                                                                                                       3£F
Calculation: [(Sample (mg/L) - Blank (mg/L)) x 0.025 L] / [(Total Liters)/1! 000] = X (mg/m3)

-------
 PROJECT # 110077:  METHOD 121  FOR NICKEL

AIR FILTER CASSETTES                      IDL =     0.004            LOG =    0.017

Digestion on 11111/05                       LOD =     0.008             RL =    0.050
BY ICP ON 11/15/05                         MDL =     0.007                  (All DL in mg/L)


DATA:
Sample #
LRB
LFB
110077-1
110077-2
110077-3
110077-4
110077-5
1 1 0077-6
110077-7
110077-8
110077-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
-0,004
0.716
0.206
0.180
0.505
0.404
0.209
0,185
0.180
0.156
-0.003
 e
*> Ik
"5" gr
mi a
H te
= 0.006
                                                          = Q. 006

EXPLANATIONS:
               Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
               process were added, no filter.
               Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
               digestion process, again, no filter.
  DILUTION =   25 ml class A volumetric flask was used to measure the final volume.
  READING =   mg/L as determined by average of three replicates on ICP.
LRB =
LFB =
IN ORDER TO'JFAC1LITATE FURTHER"C^LCULAT!ONS, IF A READING IS 
-------
                                 AIR MONITORING DATASH
 DATE-
 COMPANY NAME.
                       full
 SAMPLER:
 TEST TYPE:   n     EMPLOYEE        J}\

 EMPLOYEE NAME/SS #        '

 AREA:'
                                          AREA
 PUMP SERIAL _

 PARAMETER(S)   f\fl

 MED1ATYPE    	

 SERIAL #       r"~"
                                                                     |6
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   LPM

 POST-CALIBRATION FLOW RATE
 Time (500 mL)	seconds  LPM
                                     2-0
 TOTAL SAMPLE TIME (MIN.)

 TOTAL LITERS SAMPLED
TESTTYPE:   o     -EMPLOYEE

EMPLOYEE NAME/SS #

AREA:
                                         AREA
PUMFSERIAL # .  ^

PARAM ETER(S)

MEDIA TYPE

SERIAL ?s
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
i!me(500mL)	seconds  LPM_
TCTAL SAMPLE TIME (MIN.)_

-------
                                AIR MONITORING DATA SHEET
           LABORATORIES. INC.                                             i.
                                                                    U
       TESTING 	 CONSULTING
          ^                                tnMpiM  m     n/iy
 DATE       ii> —
 COMPANY NAME

 SAMPLER:
             r**:fc*&***^**:iir&:ii:***^

 TESTTYPE:  D     EMPLOYEE        "X    AREA
                         -_    X
 EMPLOYEE NAME/SS # 	       	
 AREA:
 PUMP SERIAL #

 PARAMETER(S>

 MEDIA TYPE

 SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_
                                    --v
                                    "  '
TOTAL SAMPLE TIME (MIN.) _ T?  ^n )

TOTAL LITERS SAMPLED       "f 5" 3,
TESTTYPE:   n    -EMPLOYEE       


-------
                                 AIR MONITORING DATA SHEET
        ?DLK LABORATORIES. SNiZ^
 DATE
                                        r   o v
                                        (~ (XX^L I X\J"
 COMPANY NAME
 SAMPLER:

 TESTTYPE:   n     EMPLOYEE

 EMPLOYEE NAM E/SS #

 AREA:
                                         AREA
 PUMP SERIAL #

 PARAMETER(S)

 MEDIA TYPE

 SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL) _ seconds
                              LPM
                                      'I
 POST-CALIBRATION FLOW RATE'
 Time (500 mL) _ seconds  LPM
                                      ~")
                                      ^-
TOTAL SAMPLE TIME (MIN.)	

TOTAL LITERS SAMPLED

TESTTYPE:  D     "EMPLOYEE
                                         AREA
EMPLOYEE NAM E/SS #

AREA:
PUMP SERIAL 1_

PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                             LPM
                                       "N
                                        CTV
POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM
TOTAL SAMPLE TIME (MIN.)

TOTAL LITERS SAMPLED
                          -rOX?

-------
                               AIR MONITORING DATA SHEE
 DATE
 COMPANY NAME
 SAMPLER:
                                                            ^
 TEST TYPE:   a    EMPLOYEE

 EMPLOYEE NAME/SS #       "

 AREA:
 PUMP SERIAL #   ^(Sg

 PARAMETER(S)	

 MEDIATYPE	

 SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   LPM_

 POST-CALIBRATION FLOW RATE'
 Time (500 mL)	seconds  LPM_
TOTAL SAMPLE TIME (-MIN.)_

TOTAL LITERS SAMPLED
                           H09
                           sh
TESTTYPE:  D     -EMPLOYEE

EMPLOYEE NAME/SS #

AREA:
PUMP SERIAL*.

PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
                   JNk
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM_

POST-CALIBRATION FLOW RATE
Time (500 rnL)	seconds LPM_

                                       AREA
                                      ,( )
                                      AREA
                                  3-D
                                  3-0
TOTAL SAMPLE TIME (MIN.)_
                          M09-

-------
Company Name:	ABQC - Watts Nickel Rack
NAME/AREA
Condition
10
-East
Conditon 10- West
Blank
Condition
Condition
Blank
Condition
Condition
Blank
Condition
Condition
Blank
Condition
Condition
Blank
Condition
Condition
Blank

11
11

12
12

13
13

14
14

15
15


-East
-West

-East
-West

-East
-West

-East
-West

-East
-West

Sample LPM Total Blank
PARAMETER Date mg/L Minutes Flowrate LITERS mg/L RESULTS (mg/m3) OSHA LIM
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
NI
Ni
Ni
NI
Ni
Ni
NI
0.21
0.
04
0.002
0.
62
0.09

0
2.16
0.24

0
2.31
0.15
0.002
0
0

0
0

.20
.14
0
.13
.04
0
398
401
0
389
388
0
411
406
0
416
414
0
403
403
0
393
393
0
2.
2.

2.
2.

2.
2

2
2

2
2

2
2

0
0
0
0
0
0
.0
.0
0
.0
.0
0
.0
.0
0
.0
.0
0
796
802
0
778
776
0
822
812
0
832
828
0
806
806
0
786
786
0
0.002 >. v"j~ " _ ~'/JQ&$fjS$$i.
0.002 ^fV','*fy>^j$&Q\i&8'
0.002 '^•^1l"4t*/^"-*'> 'V, 1
o^t%"> 
-------
 PROJECT # 020072:
AIR FILTER CASSETTES
Digestion on 02/06/06
BY ICP ON 02/09/06

 DATA:
                               METHOD 121  FOR NICKEL
EXPLANATIONS:
     LRB =
                                        IDL =
                                       LOD =
                                       MDL =
0.004
0.008
0.007
LOQ=    0.017
 RL n     0.050
      (All DL in mg/L)
Sample #
LRB
LFB
020072-1
020072-2
020072-3
020072-4
020072-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
2,16
0.002 ;
0.209
0.036
2,310
0.149
                                        
-------
 PROJECT #010218:   METHOD 121  FOR  NICKEL
 AIR FILTER CASSETTES
 Digestion on 01124106
 BY ICP ON 01127106
                                         IDL =
                                         LOD =
0.004
0.008
0.007
LOQ=    0.017
 RL =     0.050
      (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
010218-1
010218-2
010218-3
010218-4
010218-5
Dilution
25
25
25
25
25
25
25
Reading
-0.001
1,98
2,16
0.238
\ ;.-o.ooi ••,
J. / L J
0.622
0.087
EXPLANATIONS:
     LRB =
                                          
-------
 PROJECT # 140200:   METHOD 121  FOR NICKEL
 AIR FILTER CASSETTES
 Digestion on 11/14/05
 BYICP ON 11115/05
 IDL =
LOD =
MDL ~
0.004
0.008
0.007
                                                                LOQ =    0.017
                                                                RL =     0.050
                                                                     (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
110200-1
110200-2
110200-3
110200-4
110200-5
110200-6
110200-7
110200-8
110200-9
110200-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.001
1.80
0.202
0.144
0.000 ;:
0.130
0.042
4.06
0.448
0.002
2.11
0.382
EXPLANATIONS:
                                         :MDL of 0.007 mg/L
                                                       = 0.006
                                         = 1 00 x 1 .00/1 00 = 90% Recovery. ( 80-120%)
                                                 IU  U
                                          = 0.006
                                              '«   I
                                         = 0.006
               Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
               process were added, no filter.
               Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
               digestion process, again, no filter.
  DILUTION =   25 ml class A volumetric flask was used to measure the final volume.
  READING =   mg/L as determined by average of three replicates on ICP.
LRB =
LFB =
IN ORDER TO' FACiMT^fE FURTHER CALCULATIONS, fF A READING IS 
-------
                               AIR MONITORING DATA SHEET
           LABORATORIES, INC.
              CONSULTING
 DATE
 COMPANY NAME
                                                      NO
 SAMPLER:
TESTTYPE:   D    EMPLOYEE

EMPLOYEE NAME/SS #_	

AREA:
                                    J^

                                        AREA

 PUMP SERIAL #_

 PARAMETER(S).

 MEDIA TYPE	

 SERIAL #	
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds '  LPM_
                                     'A>
                                (?h ) M 3
TOTAL SAMPLE TIME (M1N.)

TOTAL LITERS SAMPLED        T I b   i L 3
TESTTYPE:  D     -EMPLOYEE

EMPLOYEE NAME/SS #

AREA:
                                       AREA
                                            (l\Lao_
PUMP SERIAL #
PARAMETER(S)

MEDIA TYPE _

SERIALS	
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM_
                          U
TOTAL SAMPLE TIME (MIN.)
                                     [

TOTAL LITERS SAMPLED	QV&  ( L J

-------
                               AIR MONITORING DATA SHEET
    CONTROL^ LABORATORIES, INC.
 DATE
 COMPANY NAME
 SAMPLER:
 ********************************************************!«**
 TESTTYPE:   D

 EMPLOYEE NAME/SS #

 AREA:	
EMPLOYEE

       Mfc
                                       AREA
 PUMPSERIAL#_

 PARAMETER(S).

 MEDIA TYPE	^	

 SER,AL*_^M)llU3
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds
                            LPM
POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM

TOTAL SAMPLE TIME (MM)
TOTAL LITERS SAMPLED_
TESTTYPE:  D     EMPLOYEE

EMPLOYEE NAME/SS #	

AREA:
                                      AREA
PUMP SERIAL #
PARAMETER(S)_

MEDIA TYPE.

SERIAL #
                     KcU
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                           LPM
                                 0,0
POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM
                                /
                                /AVJN
TOTAL SAMPLE TIME (MM)

TOTAL LITERS SAMPLED _ -f T ^  / ^-. )

-------
^ 7^ci^±c.           •       AIR MONITORING DATA SHEET
            3iP LABORATC
                   ORIES, I
          rrsriRG — CONSUL
                   /
    DATE
    COMPANYNAME_

    SAMPLER:

   TESTTYPE:   n    EMPLOYEE       Jf    AREA

   EMPLOYEE NAME/SS #

   AREA:
PUMP SERIAL #

                 _  'M.Ckg/\_
   PARAM ETER(S)

   MEDIA TYPE

   SERIAL f.
   PRE-CALIBRATION FLOW RATE
   Time (500 mL)	seconds   LPM	

   POST-CALIBRATION FLOW RATE *
   Time (500 mL)	seconds  LPM	

   TOTAL SAMPLE TIME (MM)	  C
   TOTAL LITERS SAMPLED
   TESTTYPE:  a     EMPLOYEE       "V    AREA

   EMPLOYEE NAME/SS #

   AREA:
   PUMP SERIAL' 	

   PARAM ETER(S)	

   MEDIA TYPE     """"

   SERIAL #	Q SO J1
   PRE-CALIBRATION FLOW RATE
   Time (500 mL)	seconds  LPM	

   POST-CALIBRATION FLOW RATE
   Time (500 mL)	seconds LPM	

   TOTAL SAMPLE TIME (MIN.)	*"( Q  V

   TOTAL LITERS SAMPLED

-------
        TS^sTi S G "™- C G'S!£TU ^Ti N S
                                 AIR MONITORING DATA SHEET
                                  j>ri                    tc^~>
                                  -rf\J              ,      A  ;u
                                                          '   \ t ^"? "3- D
PRE-CALIBRATION
Time (500 mL)
FLOW RATE -^ -^
seconds LPM y- • \^/
POST-CALIBRATION FLOW RATE /% -,
Time (500 mL) seconds LPM «/x V_x
TOTAL SAMPLE TIME (MIN.)	 I I ^j	( AI'A )_
TOTAL LITERS SAMPLED	V&&    [L]

-------
                                AIR MONITORING DATA SHEET
 DATE
                 /i f
 COMPANY NAME
 SAMPLER:

 TESTTYPE:   a     EMPLOYEE

 EMPLOYEE NAME/SS #

 AREA:
                                        AREA
 PUMP SERIAL n

 PARAMETER(S)

 MEDIA TYPE

 SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds
                             LPM
 POST-CALIBRATION FLOW RATE
 Time (500 mL)	seconds  LPM^
                                         0
TOTAL SAMPLE TIME (WIN.)	
                         t 
TESTTYPE:   D    'EMPLOYEE

EMPLOYEE NAMEISS #

AREA:
                                 cxf
                                        AREA
                                             «il
PUMP' SERIAL #

PARAMETER(S)

MEDIA TYPE

SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM_
TOTAL SAMPLE TIME (MIN.)_

TOTAL LITERS SAMPLED
                                  L

-------
                                 AIR MONITORING DATA SHEET
         C.iy LABORATORIES. !NC,
        T £ S T i N'OT" «—:"™e"o~K 3 uHTJ"°KG  ^"^
 DATE
 COMPANY NAME

 SAMPLER:


 TEST TYPE:
                  EMPLOYEE        jX    AREA
 EMPLOYEE NAMEISS #_

 AREA:
 PUMP SERIALS

 PARAMETER(S)

 MEDIA TYPE

 SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                              LPM
                                     _ .
                                     *< v
 POST-CALIBRATION FLOW RATE
 Time (500 mL)	seconds  LPM_

 TOTAL SAMPLE TIME (MIN.)	

 TOTAL LITERS SAMPLED
                             \6 t
TESTTYPE:  D     EMPLOYEE

EMPLOYEE NAM EISS #      ~~

AREA:
                                         AREA
PUMP SERIAL #_

PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds   LPM

POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM
                                      5.
TOTAL SAMPLE TIME (MIN.)

TOTAL LITERS SAMPLED
                           "f S ^  / i A

-------
Company Name:
Artistic - Watts Nickel Barrel
NAME/AREA
Condition 18
Conditon 18
Blank
Condition 19
Condition 19
Blank
Condition 20
Condition 20
Dlor-lU
blank
Condition 21
Condition 21
Blank

-North
- South

-North
- South

-North
- South

-North
- South


Sample LPM Total Blank
PARAMETER Date mg/L Minutes Flowrate LITERS mg/L RESULTS (mg/m3) OSHA LIM
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ki:
NI
Ni
Ni
Ni

0.09
0.11
0.001
0.01
0.01
0.001
0.04
0.03
Orvn *i
.UU1
0.02
0.02
0.001

443
443
0
290
290
0
425
426

287
288
0

2.0
2.0
0
2.0
2.0
0
2.0
2.0

2.0
2,0
0

886
886
0
580
580
0
85,0
852

574
576
0

0.001 ^\ ;-„,-*' ^«$|00p|'i;

0.001 ^' ?'"'f "-'V^r!'?'
0.001 *W..'-'
0.001 "(\ ?'-;• . ' i \^j$$^M^
°->£' -"^-M.V'''''
0.001 • ' "-4;fOJ||^
0.001 ' " " *']
0.001",, \ Y^. '01(p^|8^Si
0.001 •"_' v-. ,' *'6-OOd8^
°k"V ;, :^ >r;, '-'vo;
?":"-,:!' VV "'^'^
1.00
1.00

1.00
1.00

1.00
1.00

1.00
1.00


Calculation: [(Sample (mg/L) - Blank (mg/L)) x 0.025 L] / [(Total Liters)/1000] = X (mg/m3)

-------
 PROJECT # 100016:  METHOD  121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 1014105
BY ICP ON 1015105
                            IDL =     0.004
                            LOD =     0.008
                            MDL =     0.007
LOQ =    0.017
 RL =     0.050
      (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
100016-1
100016-2
100016-3
100016-4
100016-5
100016-6
100016-7
100016-8
100016-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
0.211
4.01
0.092
0.107
0.012
0.012
0.044
0.029
0.017
0.015
0,001
EXPLANATIONS:
                                          •MDL of 0 007 mg/L & > RL of 0 05 mg/L

                                          : 100 x 4 01/4 0 = 100% Recovery so okay
                                                 ij*    -
                                             a?
                                           =0.006
     LRB =
     LFB =
   DILUTION =
   READING =
   FLAG "B" =
Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
process were added, no filter.
Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
digestion process, again, no filter.
25 ml class A volumetric flask was used to measure the final volume.
mg/L as determined by average of three replicates on ICP.
The result is  over the detection limits as quantified for nickel. Therefore the result may
be significant and must be "flagged" to indicate that it may be a false positive "hit", as
occurred in the LRB.
IN ORDER TO FACILITATE FURTHER CALQtILATIOKISv IF Af^EMSlNG IS'
-------
                                 AIR MONITORING DATA SHEET
 DATE
 COMPANY NAME

 SAMPLER:
                                            IA                             ^H *

 TEST TYPE:   n    EMPLOYEE         /\hcL/[

 EMPLOYEE NAME/SS#

 AREA:      IMr

 PUMP SERIAL #_

 PARAyETER(S)_

 MEDIA TYPE	

 SERIAL #
 PRE-CALIBRATION FLOW RATE             "\
 Time (500 mL)	seconds   LPM	
-------
                                 AIR MONITORING DATA SHEET
 DATE
 COMPANY

 SAMPLER:
 **-fc^^ifc^^***w:*:fe^**~w*&w;^

 TESTTYPE:   o     EMPLOYEE

 EMPLOYEE NAME/SS #

 AREA:	

 PUMP SERIAL #
 PARAMETER{S)__

 MEDIA TYPE	

 SERIAL #	
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   LPM_

 POST-CALIBRATION FLOW RATE'
 Time (500 mL)	seconds  LPM_
TOTAL SAMPLE TIME (.MIN.)

TOTAL LITERS SAMPLED
                           d3     _              I P U
TESTTYPE:  a     .EMPLOYEE              AREA

EMPLOYEE NAME/SS #__	             	

AREA:
PUMP'SERIAL /f

PARAWI ETER(S)

MEDIATYPE

SERIAL #
PRE-CALIBRATION FLOW RATE              J K
Time (500 mL)	seconds   LPM	**- V
POST-CALIBRATION FLOW RATE
Time {500 mi)	seconds  LPM	
                     ...	<59D

TOTAL LITERS SAMPLED
TOTAL SAMPLE TIME (MIN.)

                            O

-------
                                 AIR MONITORING DATASHEET
 DATE
 COMPANY NAME          V/Cu              o

 SAMPLER:
                                                  1 K   W
TEST TYPE:   n     EMPLOYEE       J&.    AREA

EMPLOYEE NAME/SS#       ;            	   '"'')

AREA:__

PUMP SERIAL #_

PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   LPM_
POST-CALIBRATION FLOW RATE'          O
Time (500 mL)	seconds   LPM    ^-
TOTAL SAMPLE TIME (MIN.)    H^CT

TOTAL LITERS SAMPLED
TEST TYPE:  o     EMPLOYEE        cV    AREA  tn,..^  ,

EMPLOYEE MAME/SS #

AREA:

PUMP 'SERIAL #_

PARAM ETER(S}_

MEDIA TYPE	

SERIAL #	
PRE-CALIBRATION FLOW RATE           !\ ^
Time (500 mL}	seconds  LPM    ***

POST-CALIBRATION FLOW RATE
Time (500 rnL)	seconds  LPM
                          /]-)
TOTAL SAMPLE TIME (Mt.N.)     ' &

-------
                                 AIR MONITORING DATA SHEET
     ~S?,'~R^'J-' LA3CRATQSi^£, INIX
 DATE
 COMPANY NAME_

 SAMPLER:
                                    Pbk    Co
 **»**^^^r***Tfe**:fc-T^*!fc;^

 TEST TYPE:  a     EMPLOYEE        ¥    AREA
 EMPLOYEE NAME/SS #

 AREA:

                                                  IjOtjU ,
 PUMP SERIAL #_

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 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds  LPM_

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 Time (500 mL)	seconds  LPM
                           ~\ 5? •*>.                          Q i
 TOTAL SAMPLE TIME (WIN.)	pKj T  fc\.\{\	              ^ v

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TESTTYPE:   D     EMPLOYEE       jC    AREA

EMPLOYEE NAME/SS #  _     .-~      . '   i

     ^
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PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
PRE-CALIBRATION FLOW RATE          O .
Time (500 mL)	^seconds   LPM     V
POST-CALIBRATION FLOW RATE
Time (500 mi)	seconds  LPM
TOTAL SAMPLE TIME (MIN.)
                          Q-\ ^

-------
Company Name:
Elite Finishing - Nickel Sulfamate Rack
NAME/AREA
Condition 22
Conditon 22
Blank
Condition 23
Condition 23
Blank


Condition 25
Condition 25
Blank

Condition 26
Condition 26
Blank
- North
- South

-North
- South



-North
- South


-North
- South

Sample LPM Total Blank
PARAMETER Date mg/L Minutes Flowrate LITERS mg/L RESULTS (mg/m3) OSHA LIM
Ni
Ni
Ni
Ni
Ni
Ni


Ni
Ni
W

Ni
Ni
NI
0.09
0.16
0
0.06
0.29
0.006


0.05
0.06
0.006

0.17
0.17
0.001
431
431
0
189
401
0


400
400
0

331
331
0
2.0
2.0
0
2.0
2.0
0


2.0
2.0
0

2.0
2.0
0
862
862
0
378
802
0


800
8i30
0

662
 ' >tyV$$4$
0 ,,,v'>t £?';&*;£&
0.006 il 'v v&tfW.r
0 006 '" ' V -. ''^$0$B8S3
o1 ' '"' r," ,,'A'-'- ;
l . /i'V ir" ''"J S ' *>'
, i j« »^^ v^'tj ^, ^. ..^ r^
0,006 ' Ji i' *A."; '-©IQO^T^1
o.ooe / _ '" -• " ' "'^ujjress'1
°V'^ «'>^ *'j
**"'>„,' •«..'* '",^j- •
0.001 .,ru'7.i: , '103^^82*
0.001 r> , (-,^A6"iOb"^|S
V/ "" *" < J^ t J-T1 "" "i 5
1.00
1.00

1.00
1.00



1.00
1,00


1.00
1.00

 Calculation: [(Sample (mg/L) - Blank (mg/L)) x 0.025 L] / [(Total Liters)/1000] = X (mg/m3)

-------
PROJECT # 100305:   METHOD 121  FOR NICKEL
AIR FILTER CASSETTES

Digestion on 11/7/05

BYICPON 11/9/05


DATA:
                          IDL=    0.004

                          LOD =    0.008

                          MDL B    0.007
LOQ=    0.017

 RL =     0 050

      (All DL in mg/L)
Sample #
LRB
LFB
100305-1
100305-2
100305-3
100305-4
100305-5
100305-6
100305-7
100305-8
100305-9
100305-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.005
1.00
7.28
0.914
0.085
0.16
;^vi«,db5:V
1 '•.,*„
5.83
0.174
6.90
0.433
- - ,-0.005 -> s
                                        :MDL of 0.007 mg/L          = 0.006



                                         100 x 1.00/1.00 = 100% Recovery. ( 80.120%)
                                         = 0.006
                                          = 0.006
 EXPLANATIONS:

     LRB =

                Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
process were added, no filter.
     LFB —
                digestion process, again, no filter.
   nil I ITIDN =    9Fi ml class A vnliimfitrin flask was
                                              tn
                                                        the final

-------
 PROJECTS 110325:
 AIR FILTER CASSETTES
 Digestion on 12/20/05
 BYICPON 12/30/05

 DATA:
                               METHOD 121  FOR NICKEL
EXPLANATIONS:
                                        IDL=     0.004
                                       LOD =    0.008
                                       MDL =    0.007
LOQ=   0.017
 RL =    0.050
      (All DL in mg/L)
Sample #
LRB
LFB
110325-1
110325-2
110325-3
110325-4
110325-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
0.75
0-064
0.288
"o,oo%-\>:
0.049
0.060
                                        
-------
 PROJECT #  120034:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES

Digest!on on 12/20/05

BYICP ON 12/30/05


DATA:
EXPLANATIONS:
                            IDL =    0.004

                           LOD =    0.008

                           MDL =    0.007
LOG =    0.017

 RL =     0.050

      (All DL in mg/L)
Sample #
LRB
LFB
120034-1
120034-2
120034-3
Dilution
25
25
25
25
25
Reading
-0.002
0.75
0.174
0.176
•':- Q.QQ% ' I
                                         
-------
                                  AIR MONITORING DATA SHEET
 DATE
-COMPANY NAME	[~L iTE   ) ' ' C" IN^ I   " V^*- S n I r\   /
                                                        ~	"   vj
 SAMPLER:
 w^^x^^r^^^^sr^^^^-^^THr^^^1*^

 TEST TYPE:   n     EMPLOYEE        ,X"    AREA
                            t
 EMPLOYEE NAME/SS #

 AREA:
 PUMP SERIAL
 PARAMETER(S)	f\A

 MEDIA TYPE	w

 SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   L'PM
 POST-CALIBRATION FLOW RATE'         -^  v
 Time (500 mL)	seconds  LPM   (7* D

 TOTAL SAMPLE TIME (MIN.)	 |S f  W\ 
-------
                                AIR MONITORING  DATA SHEET
     CONTRDiy L
            	 CONSULTING
 DATE
 COMPANY NAME
                         f
                         L
                             l
                             t
                                                                           -U
 SAMPLER:
 TESTTYPE:  n     EMPLOYEE
 EMPLOYEE NAME/SS #
 AREA:
                                         AREA
 PUMP SERIAL #_
 PARAMETER(S)_
 MEDIATYPE	
 SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                             LPM
POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM
                                    -
                                    /
TOTAL SAMPLE TIME (MM)
TOTAL LITERS SAMPLED
                            \ 0 /( g. . r^\
                            3 "70  L^ '
                                                      fo  -,
                                                               Q ^cV
TESTTYPE:   D    'EMPLOYEE
EMPLOYEE NAME/SS # _ _
AREA:
PUMP' SERIAL # ^
PARAM ETER(S)
MEDIA TYPE
SERIAL #
                                        AREA
                  i
                     l
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                             LPM
POST-CALIBRATION FLOW RATE         ^
                     seconds  LPM   c/"
Time (500 mL)
                             _| ^ u
TOTAL SAMPLE TIME (MIN.)
TOTAL LITERS SAMPLED _ ($\M CL-)

-------
                                AIR MONITORING DATA SHEET
 DATE
 COMPANY NAME
                       r\
 SAMPLER:
 ******************************* ******************************************^
 TESTTYPE:  D     EMPLOYEE

 EMPLOYEE NAMEISS #

 AREA:
                                         AREA
PUMP SERIAL #

PARAIVIETER(S)

MEDIA TYPE

SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL) _ seconds
                             LPM
POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM
TOTAL SAMPLE TIME (MM)

TOTAL LITERS SAMPLED
                               (*-
TESTTYPE:   a     -EMPLOYEE
EMPLOYEE NAM E/SS # _ *~
AREA:
PUMP SERIAL #
PARAM ETER(S)
                                        AREA
                              __
                        y Ivi^
                   /M6/<-l 1
MEDIA TYPE

SERIAL #
PRE-CALJBRATION FLOW RATE
Time (500 mL) _ seconds
                             LPM
                                     ^  -.
                                     e<>  V
POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM

TOTAL SAMPLE TIME (MIN.)	{j

TOTAL LITERS SAMPLED
                                  \ i>v

-------
                                 AIR MONITORING DATA SHEET
     C:GNTRDI>' LABORATORIES, I
 DATE
 COMPANY NAME
 SAMPLER:
            tHif^
 TESTTYPE:   o     EMPLOYEE

 EMPLOYEE NAME/SS #_ _   ' —

 AREA:
                                          AREA
 PUMP SERIAL#

 PARAM ETER(S)

 MEDIA TYPE

 SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM_
                                     rx
                                     (7-
TOTAL SAMPLE TIME (MDSf.)

TOTAL LITERS SAMPLED
TESTTYPE:  D     EMPLOYEE

EMPLOYEE NAME/SS #	"~

AREA:	K) v
                                         AREA
PUMP SERIAL #.

PARAM ETER(S)

MEDIA TYPE

SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                              LPM
POST-CALIBRATION FLOW RATE
Time (500 mL) _ seconds  LPM
                                        ~^
                                        Q
TOTAL SAMPLE TIME (MIN.)_

TOTAL LITERS SAMPLED

-------
Company Name:
Artistic - Woods
NAME/AREA
Condition
7-
East
Conditon 7 - West
Blank
Condition
Condition
Blank
Condition
Condition
Blank
Condition
Condition
Blank
Condition
Condition
Blank

24
24

27
27

28
28

29
29


-East
-West

-East
-West

- East
-West

-East
-West

Sample LPM Total Blank
PARAMETER Date mg/L Minutes Flowrate LITERS mg/L RESULTS (mg/m3) OSHA LIM
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
Ni
NI
Ni
Ni
NI
4.06
0.45
0.002
2.11
0.38
0.002
7.28
0.92
0
5. 83
0.17
0
6.9=
0.43
o
403
403
0
390
393
0
295
289
0
398
392
0
407
403
0
2.
2.

2
2,

2
2

2
2

2
2

0
0
0
0
.0
0
.0
.0
0
.0
.0
0
.0
.0
0
806
806
0
780
786
0
590
578
0
796
784
0
814
806
0
0.002 ,; _ -^ * ?"*-* «, vZf- ,!
0.002;- (% i\ 'mm,&p
0.002 • .{^ '•^'•'^X^^S'
°f^Sfi^|3"
0 5'\AlVff^^^C)*841f5
o '-^^VsT'^^P1^^

o^cf!€|||^^
o 7:JV.'£ t"V"'- "*
0 \*g .'-y.r^^'lA^I^
0 '\r/ .* '•-- ',Mv"'^M^7
0 &«, "' ;; ^'A;^4^-
1
1

1
1

1
1

1
1

1
1

.00
.00

.00
.00

.00
.00
J-IL rt
.00
.00

.00
.00

Calculation: [(Sample (mg/L) - Blank (mg/L)) x 0.025 L] / [(Total Liters)/1000] = X (mg/m3)

-------
 PROJECT # 110200:  METHOD 121 FOR  NICKEL
 AIR FILTER CASSETTES
 Digestion on 11/14/05
 BY ICP ON 11/15/05
                                     IDL =
                                     LOD =
                                     MDL =
0004
0.008
0.007
LOQ =    0.017
 RL =     0 050
      (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
110200-1
110200-2
110200-3
110200-4
110200-5
110200-6
110200-7
110200-8
110200-9
110200-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.001
1.80
0,202
0.144
•t' ;p.odo
0.130
0.042
4.06
0.448
' 0,002,° •/
2,11
0,382
EXPLANATIONS:
                                        
-------
 PROJECT #  100305:  METHOD 121  FOR NICKEL
 AIR FILTER CASSETTES
 Digestion on 11/7/05
 BYICP ON 11/9/05
                                      IDL =    0.004
                                     LOD =    0.008
                                     MDL =    0.007
LOQ=    0.017
 RL =     0.050
      (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
100305-1
100305-2
100305-3
100305-4
100305-5
100305-6
100305-7
100305-8
100305-9
100305-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.005
1.00
7.28
0.914
0.085
0.16
••• r9;0<3&
5.83
0.174
6.90
0.433
-0.005
EXPLANATIONS:
                                         =MDL of 0.007 mg/L          =0.006

                                         = 100 x 1.00/1,00 = 100% Recovery. ( 80-120%)
                                               f <**'  r
                                          = 0.006
                                          = 0.006
               Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
               process were added, no filter.
               Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
               digestion process, again, no filter.
   DILUTION =   25 ml class A volumetric flask was used to measure the final volume.
   READING =   mg/L as determined by average of three replicates on ICP
LRB =
LFB =
IN ORDER TO FACILITATE FURTHER CAtfcULATlOMS, IF A READING IS 
-------
^ " ^cleni±c .                     AIR MONITORING DATA SHEET
 COMPANY NAME

 SAMPLER:
                           :	        p
                          AM ^\ 11   I i£\^   L>
                      fc************************************ **************************************
   TESTTYPE:  D     EMPLOYEE              AREA

   EMPLOYEE NAMEISS #

   AREA:
   PUMP SERIAL #

   PARAMETER(S)

   MEDIA TYPE

   SERIAL #
   PRE-CALIBRATION FLOW RATE
   Time (500 mL)	seconds   LPM_

   POST-CALIBRATION FLOW RATE'
   Time (500 mL)	seconds  LPM_
   TOTAL SAMPLE TIME (MIN.)

                                      '  ^
   TOTAL LITERS SAMPLED
   TESTTYPE:   D     'EMPLOYEE           -    AREA

   EMPLOYEE NAME/SS #          \->
   AREA:
   PUMP' SERIAL #  £7^0^0^^

   PARAMETER(S)	\\J\i	

   MEDIA TYPE
   SERIAL #	
   PRE-CALIBRATION FLOW RATE
   Time (500 mL)	seconds   LPM
  POST-CALIBRATION FLOW RATE
  Time (500 mL) _ seconds  LPM

                              HU.>
TOTAL SAMPLE TIME (MIM.)

                           M/ o / L, J
    OTAL LITERS SAMPLED

-------
                                AIR MONITORING DATA SHEET
        S2L2-' LABORATORIES INC,
        :STIN s- — CONSU LTS N &
 DATE
                         M # U5T\
-------

                                 AIR MONITORING DATA SHEET
 DATE
 COMPANY NAME
 SAMPLER:
         ^^^*^**!^1^*

 TEST TYPE:   D    EMPLOYEE

 EMPLOYEE NAM E/SS #

 AREA:
                                         AREA

 PUfVIP SERIAL #

 P ARAIW ETER(S)

 MEDIA TYPE

 SERIAL #
                  j\i
 PRE-CALIBRATION FLOW RATE
 Time (500 mL) _ seconds
                              LPM
POST-CALIBRATION FLOW RATE.
Time (500 mL)	seconds  LPM
TOTAL SAMPLE TIME (MIN.)

TOTAL LITERS SAMPLED
                            <7 3 J
                             0 /  t)
TESTTYPE:  o     -EMPLOYEE

EMPLOYEE NAME/SS #_

AREA:
                                         AREA
PUWip-SERIAL#_

PARAMETER(S)_

MEDIA TYPE	

SERIAL #	
PRE-CALIBRATION FLOW RATE
Time (500 mL) _ seconds
                             LPM
                                     9-0
POST-CALIBRATION FLOW RATE
Time (500 rnL) _ seconds  LPM
TOTAL SAMPLE TIME (MIN.)

TOTAL LITERS SAMPLED
                                  ci     /
                                  .7   frvl
                              3 T O   L»

-------
                                 AIR MONITORING DATA SHEET
 DATE
COMPANY NAME

SAMPLER:
                                     M W
                                                                     £. &•&
 TESTTYPE:   D     EMPLOYEE       fN?/    AREA

 EMPLOYEE NAME/SS #

 AREA: __

 PUMP SERIAL #_

 PARAMETER(S)_

 MEDIA TYPE	

 SERIAL #
 PRE-CALIBRATION FLOW RATE
 Time (500 mL)	seconds   LPM_

 POST-CALIBRATION FLOW RATE
 Time (500 mL)	seconds  LPM_
                            '/Q  M>A
TOTAL SAMPLE TIME (MIN.) _

TOTAL LITERS SAMPLED        T J^>  ^"U
TESTTYPE:  a     EMPLOYEE              AREA

EMPLOYEE NAME/SS #

AREA:
PUMP'SERIAL #

PARAM ETER(S)

MEDIA TYPE

SERIAL #
PRE-CALIBRATION FLOW RATE
Time (500 mL)	seconds   LPM_

POST-CALIBRATION FLOW RATE
Time (500 mL)	seconds  LPM_
TOTAL SAMPLE TIME (MIN.}_

~O7AL LITERS SAMPLED

-------
                                  AIR MONITORING DATA SHE1
 DATE
                                  ei
 COMPANY NAME

 SAMPLER:
                ra*:fe"£iaHc:fc*w**i!ra7He^

 TEST TYPE:   u     EMPLOYEE       0^    AREA

                          . lr\
 EMPLOYEE NAME/SS #


 AREA:	


 PUMP SERIAL #
 PARAMETER(S)

 MEDIATYPE

 SERIAL #
 PRE-CALIBRATION FLOW RATE           Q /O
 Time (500 mL) _ seconds   LPM
 POST-CALIBRATION FLOW RATE
 Time (500 rnL)	seconds  LPM
 TOTAL SAMPLE TIME (WIN.)

 TOTAL LITERS SAMPLED
TESTTYPE:   D    EMPLOYEE               AREA

EMPLOYEE NAME/SS #

AREA:
PUMP SERIAL #

                        i\jl
P ARAM ETER(S)

MEDIATYPE

SERIAL #
PRE-CALIBRATION FLOW RATE
Time {500 mL)	seconds   LPM_

POST-CALI BRAT I ONFLOW RATE
Tims (500 mL)	seconds  LPM_

                             VffS
TOTAL SAMPLE TifvIE (WIN.)

TOTAL LITERS SAMPLED

-------
Appendix C



Photographs

-------
Reliable-EN

-------

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-------

-------

-------

-------

-------

-------

-------

-------
ABQC

-------

-------

-------

-------

-------
Artistic-Watts

-------

-------

-------

-------

-------

-------

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                    Appendix D



Stack Testing Field Data Sheets and Calibration Sheets

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                                             DATE OF TEST

                                             TEST ENGINEER    X?
                                                  Wash Bottle
                                                  Beaker No.
WATER COLLECTED

     Impinger No.
                        Final Wt. g     Initial Wt.  g      Collected  grams
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     Washings
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NOTES ;

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JOB NAME

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                          LABORATORY DATA SHEET
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-------
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-------
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-------
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-------
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-------
                          LABORATORY DATA SHEET
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-------
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-------
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-------
                    Appendix D - 2



Stack Testing Field Data Sheets and Calibration Sheets

-------
EnvtronmeL
  Technology &
PARTICIPATE FILuD DATA
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-------
                         LABORATORY DATA SHEET
                     PARTICULATE & WATER COLLECTED
JOB NAME
JOB NO.
                                             DATE OF TEST
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                                            /
-------
Environmc
  Technology &
    Engineering Corp.
                        PARTICULATE F,  _D  DATA
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-------
 Enviromr   ml
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                                        PARTICULATE  f    LD  DATA

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-------
                         LABORATORY DATA  SHEET
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                                              DATE OF TEST

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-------
JOB NAME

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-------
                         LABORATORY DATA SHEET
                     PARTICIPATE & WATER COLLECTED
JOB NAME

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RUN NO.
                                              DATE OF TEST
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                                       /
-------
Environm*
  Technology 4
     Engineering Corp.
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Environme
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                                    PARTICULATE Fl    D  DATA
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-------
JOB NAME

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-------
                          LABORATORY DATA SHEET
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-------
Environme
Technology 4
Engineering Corp
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-------
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                         PARTICULATE  Fl    D  DATA
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PARTICULATE  Fll   D  DATA
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-------
                         LABORATORY  DATA  SHEET
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-------
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-------
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                                         PARTICULATE  F   ID  DATA
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                                  OPERATOR.


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-------
Enviromnei
  Technology 4
     Engineering Corp.
PARTICULATE  Fll   D  DATA
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                                ASSUMED MOISTURE.
                                                                                                         PROCESS »€ICWT RATE
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-------
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-------
                         LABORATORY  DATA SHEET
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-------
                         LABORATORY DATA SHEET
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-------
Environmi    i
  Technology &
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PARTICULATE  Fu.LD  DATA
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-------
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-------
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-------
                         LABORATORY DATA SHEET

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-------
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-------
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-------
Environment
  Technology *
    Engineering Corp.
PART1CULATE FIL^J  DATA
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-------
Environmei.
  Technology
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PARTICULATE  FIL^D  DATA
                                AMBIENT TEMPERATURE
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                                PROBE LENGTH, ,
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-------
EnvironmeL
  Technology 4
     Engineering Corp.
PARTICULATE FIL..D DATA
                     » sr
LOCATION .

OPERATOR.

STACX NO.
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-------
                         LABORATORY DATA SHEET
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-------
                         LABORATORY DATA SHEET
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-------
JOB NAME

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-------
Enviromm
  Technology 4
    Engineering Corp.
            PART1CULATE  Fi_LD  DATA
                                            DATE
                                                        /'/
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-------
Environm<
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-------
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-------
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-------
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-------
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-------
Environmi
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-------
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-------
/ironnv   •'I
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                                        PARTICULATE  F   XD  DATA
                                          P» IMT   Aitr* s ftG,
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                         DATE
                                                    /oA?/yL.>^a
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-------
Environme
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-------
                         LABORATORY DATA SHEET
                     PARTIGULATE & WATER COLLECTED
JOB NAME

JOB NO.
                                             DATE OF TEST     /?>/
                                             TEST ENGINEER
RUN NO.
Sample Box
               ' $
                     STACK
                           Filter
Wash Bottle

Beaker No.
WATER COLLECTED

     Impinger No.
                        Final Wt. g     Initial Wt. g      Collected	grams
                             7/7
                                                                    /O
                                                O
                                                    TOTAL
PARTICULATE  COLLECTED
     Filter

     Washings
WATER COLLECTED

PARTICULATE COLLECTED
                         Final  Wt.  g    Jare. Wt.    g .       Collected   grams

ECTED
GRAMS

                                      GRAMS
NOTES:

-------
JOB NAME



JOB NO.






RUN NO.
Sample Box
                         LABORATORY  DATA  SHEET

                     PARTICIPATE & WATER  COLLECTED
STACK
                            Filter
                                                                >/f
                         DATE OF TEST     /t>
                                           I



                         TEST ENGINEER   /<7/f/
                              Wash Bottle   0 • >


                              Beaker No.
WATER  COLLECTED



     Impin^er  No.
    Final Wt
                     Initial  Wt.  g       Collected  grams
                                                     TOTAL
 PARTICULATE COLLECTED
      Filter



      Washings
                         Final Wt.  g      Tap-e-WtV
                                                             Collected  grams
 WATER COLLECTED
                                 GRAMS
 PARTICIPATE COLLECTED
 NOTES;
                                       GRAMS

-------
JOB NAME

JOB NO.
RUN NO.
Sample Box
                         LABORATORY DATA SHEET
                     PARTIGULATE & WATER COLLECTED
                                             DATE OF TEST     A? / "V ^'_'

                                             TEST ENGINEER   //J^/
                    STACK
                           Filter    & O fl €^'-1
                                                  Wash Bottle

                                                  Beaker No.
WATER COLLECTED

     Impinger No.
                        Final Wt.  g     Initial Wt.  g      Collected	grams
                             //
                                              too
                                                 0
                                             111
                                                    TOTAL
PARTICULATE COLLECTED



     Filter

     Washings
WATER COLLECTED

PARTICULATE COLLECTED
NOTES:
                        Final Wt. g     Tare Wt.   g       Collected  grams

ECTED
GRAMS

                                                    TOTAL
                                      GRAMS

-------
                       STACK TESTING CALIBRATION DATA
The probe tips, pitot tubes, dry gas meters, and sample box orifices used in the test efforts
were calibrated prior to the testing in accordance with the procedures outlined in the
Maintenance, Calibration, and Operation of Isokinetic Source-Sampling Equipment as
published by the US EPA as well as the applicable sections of EPA Methods 1 -4 and 29.
The values obtained were:
Test
Condition

3
4
5
6
7
10
11
12
13
14

18
19
20
21
22
23
24
25
27
28

Test
Date

10/31/05
11/3/05
11/2/05
11/1/05
11/09/05
2/1/06
1/12/06
1/11/06
2/2/06
11/7/05
2/206
9/27/05
9/28/05
9/29/05
9/30/05
10/18/05
11/15/05
11/10/05
11/16/05
10/17/05
10/19/05

Control
Box ID

2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
2
2
2
2
2

Orifice Coeff.
(AH@)

0,725
0.725
0.725
0.725
0.725
0.730
0.722
0.722
0.730
0.725
0.730
0.725
0.725
0.725
0.725
1.007
0.725
0.725
0.725
0.725
0.725

Dry Gas Meter
Coeff. (y)

1.003
1.003
1.003
1.003
1.003
1.009
1.006
1.006
1.009
1.003
1.009
1.003
1.003
1.003
1.003
1.006
1.003
1.003
1.003
1.003
1.003

Control Box
Calib. Date

9/25/05
9/25/05
9/25/05
9/25/05
9/25/05
1/31/06
11/29/05
11/29/05
1/31/06
9/25/05
1/31/06
9/25/05
9/25/05
9/25/05
9/25/05
10/11/05
9/25/05
9/25/05
9/25/05
9/25/05
9/25/05

Probe Tip
Diameters

0.308 in.
0.308 in.
0.308 in.
0.308 in.
0.248 in.,
0.308 in.
0.248 in.
0.248 in.
0.248 in.
0.248 in.
0.308 in.
0.248 in.
0.248 in.,
0.370 in.
0.308 in.
0.308 in.
0.308 in.
0.187 in.
0.187 in.
0.308 in.
0.187 in.
0.308 in.
0.308 in.

The flow measurements were made with standard pitot tubes which were carefully
inspected every 60 days (at the dates of control box calibrations listed in the above table).
The pitot tubes and associated tubing were also inspected throughout each day of test
efforts to avoid plugging of orifices or holes in the tubing. For all of the test efforts, the two
pitot tubes used had coefficients (Cp) of 0.99.

The dry gas meters installed in the control boxes were temperature compensating meters;
therefore, only a slight temperature correction need be  made to the volume of gas sampled.
The correction factors for the meters could best be described by the equation:

       Y = Y (as listed above)  + [(TM - 70) x 0.00012]

-------
                   VELOCITY TRAVERSE AND POINT SAMPLE TIME  CALCULATION SHEET
Plant
    :   £&&
                    Time:
                                                    Run #
Location:
                                                                                                   M3/min
Operators:	
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:	
Barometer:_
                                                                          Pre-Test Leak Check   Q
                                                                          M3/mrn x 35.315 =    	«	Flf/min -
                                                                          Critical Orifice Vacuum ^i^ ..in. Hg

                                                                          Post-Test Leak Check   O   M3/min
                                                                          M3/min x 35.315 =     __0	Ft3/min
                                                                          Critical Orifice Vacuum &.)*<£ in. Hg
                                                                                     M
                                                        Page 1

-------
                   • VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
                                                     Run #
                    Time:  //
I oration:
                             /If,
Operators:_
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:	
Barometer:_
                    rV
                             Pre-Test Leak Check	
                             M3/mrnx35.315 =
                             Critical Orifice Vacuum.
                                                                                                     M3/min
                                                  	FtVmin -
                                                  Jn. Hg
                                                                           Post-Test Leak Check  0    M3/min
                                                                           M3/min x 35.315 =        C  _ Ft^/min
                                                                           Critical Orifice Vacua m
                                                                                                       in. Hg
Traverse
          Cyclonic
                        Ap
                                  (AP
 5min
) avg
min. + sec.
sample time
                                                                running tirrie
gas meter
reading (L)
gas meter
temp.
                                                                                                vacuum (in.hg)
                                                                   n
                                                      V'.
                                                                                        -77,7
                       y/
                                                                    .*  //
                                                                 IT" //.
                              0, e
                                                       5"  -
                                                      ^ 0*3
                                                                                       77.3
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                                                                37 "
                                         19. L
                              0.
                                                           7
                              0
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                                 6 #3,3
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                                                           07
                                                                                Til
                              !t>  7O7f
                                           $-.3-7
                                               7/
                                               71
                                                                tot.
                                                        Page 1

-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
     : A*B
                     Time:
                              / 30
                                                     Run*
Location:
Operators:_
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:
Barometer:	&-J.
                                                                             Pre-Test Leak Check    O   M3/min
                                                                             M3/mrn x 35.315 =     _^_=_Ft3/min •
                                                                             Critical Orifice Vacuum Alr O  in. Hg

                                                                             Post-Test Leak Check   O   M3/min
                                                                             M3/min x 35.315 =        Q?^   Ft3/min
                                                                             Critical Orifice Vacuum
                                                                                                         in. Hg
Traverse
          Cyclonic
                        Ap
 Smln
) avg
min. + sec.
sample time
running tirri'e
min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
                                                                     O
                     O.
                              a

                                                                   1 ', //
                              0, G>7O g
                                                                     s //
                                                                                                   37*
                     0,^
                                           '$ t i
                                                                     / ? y j
                                                                                         71,
                               0,
                                                          /3
                                                                  .<"
-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEt I
Plant:
Date:
                                Run#
Time:
Location:
Operators:	i
Beginning Stack Temp.:    •—•'
Ending Stack Temp.:	•—•
Average Stack Temp.:    '-"~
Barometer:	
                                                      Pre-Test Leak Check    PS   M3/min
                                                      M3/min x 35.315 =        O   FtfVmin •
                                                      Critical Orifice Vacuum 3.Q, ti in. Hg
                                                                          Post-Test Leak Check	M3/min
                                                                          M3/min x 35.315 =      	
                                                                          Critical Orifice Vacuum    .-    in. Hg
                                                                                   .Fp/min
Traverse
Point #













Cyclonic
Flow Angle













Ap













&p~













(Ep) avg













min. + sec.
sample time








"




running time
min.
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1
a
3
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5"
6-






gas meter
reading (L)
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                                                              tot.
                                                                          tot
                                                                                 >D M3
                                                      Page 1

-------
                                               stack" test'cafe "sheet
                   VELOCITY TRAVERSE AND POINT SAMPLE TIME  CALCULATION SHEET
                                                                                 loU
Plant: /
                                                 Run#
                   Time:   ID'* 13.
Location :
Operators:_j2lJ
Beginning Stack Temp.:.
Ending Stack Temp.:	
                                                                      Pre-Test Leak Check   O   M3/min
                                                                      M3/min x 35.315 =      O   FtVmin -
Average Stack Temp.:
Barometer:	^X^/ (e>
                     Critical Orifice Vacuum,.

                     Post-Test Leak Check_
                     M3/min x 35.315 =
                     Critical Orifice Vacuum_
                                                                                                in. Hg
                                                                                               M3/rnin
                                                                                                  _Ft3/min
                                                                                                in. Hg
Traverse
         Cyclonic
                      Ap
                                            avg
min. + sec.
sample time
                                                            running time
gas meter
reading  (L)
gas meter
temp.
                                                                                          vacuum (in.hg)
                                                               o

                                                                                               , o
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                                                                  11
                                                      /3k
                                                      3L
                                                            ff?
                                                            tot.
                                                    Page 1

-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
                     Time:
Location :
Operators:   o ~2^it'-*-
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:	
Barometer:	
                                                    Run #
                                                      Pre-Test Leak Check	
                                                      M3/min x 35.315 =
                                                      Critical Orifice Vacuum_

                                                      Post-Test Leak Check_
                                                      M3/min x 35.315 =
                                                      Critical Orifice Vacuum,
                                               _M3/min
                                               —	Ft^/min -
                                                  in. Hg
                                                                                                     M3/rnin
                                                                                                        _FtJ/min
                                                                                                      in. Hg
Traverse
Point #
          Cyclonic
          Flow Angle
                       Ap
                         avg
min. + sec.
sample time
                                          running time
                                          min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
                                                                    ©
                                                                                       SrV.
                                                          &.
                                                                LCf
   y
                                                      5-  >i
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   7
                                            . 3/
                                                /3
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  _1_
   lo
                                                               V6. J 7
I, 
-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
                     Time:
                                                     Run*
Location :
Operators:   T5~2- t
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:
Barometer:	
                                                                            Pre-Test Leak Check_
                                                                            M3/min x 35.315 =
                                                                            Critical Orifice Vacuum
                                                                                                     _M3/min
                                                            	FtVmin -
                                                            Jn. Hg
                                                                            Post-Test Leak Check   O. M3/min
                                                                            M3/min x 35.315 =       Q .   FtrVmin
                                                                           Critical Orifice Vacuum
                                                                                                       in. Hg
Traverse
Point #
          Cyclonic
          Flow Angle
                        Ap
                                  (AP"
'•fAp x 5min
 (Ep) avg
min. + sec.
sample time
running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
                                                                &_
                                                                                A!±L
                                                                                         S-/, 1
   3
                                               / 3
  4-
                                                            5-
                                                                                S-/7
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                                                                3 I
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  _u_
                              0* f/X
                                                                                                      C)
                                                                5-l-SS
                                                                tot
                                                        Page 1

-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
PSant:     •"•"•
Date:
                                                    Run#
                     lime:
Location:	*~
Operators:
Beginning Stack Temp.:
Ending Stack Temp,:
Average Stack Temp.:     '~~~
Barometer:	
                                                                           Pre-Test Leak Check   ifS  M3/min
                                                                           M3/min x 35.315 =        O   FtrVmin -
                                                                           Critical Orifice Vacuum QO, f)  in. Hg
                                                                           Post-Test Leak Check	M /min
                                                                           M3/rnin x 35.315 =      	
                                                                           Critical Orifice Vacuum    .•    in. Hg
                                                                                                        .Ft^/min






Traverse
Point #













Cyclonic
Haw Angle













Ap
'












6F













'•f AD x Smln
(Ep) avg













min. + sec.
sample time








-




running time
min.
&
i

3

$-
6






gas meter
reading (L)
6CGf7J'
5-77

(c^'O
^^3,
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7c/£^






gas meter
temp.
f £..- V
5"3r X
o"3.-O
jf 7,3
5*3.7
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critical orifice
vacuum (in.hg)
So, &
3LO . 
si a o
3LCJ* O
'•*^ f*\ ^Y-
&{-\* * \~^
'^^i.X t Vj?
=SL(V, O






                                                              ot
                                                                                >b M3
                                                       agel

-------
                   VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
          /iS^ /7«Xtj
Date:   la/ 3LVc>^ T\rc\e.\    7
Plant:
                                                   Run #
1 ocation:
Operators:.
Beginning Stack Temp.:    & V.
Ending Stack Temp.:.
                                                                                                   M3/min
                                                                         Pre-Test Leak Check_
                                                                         M3/min x 35.315 =
                                                                         Critical Orifice Vacuum 3^1,0 in. Hg
                                                                                                      Ft^/min
Average Stack Temp.:
Barometer:     tsJLit y*
                                Post-Test Leak Check_
                                M3/min x 35.315 =
                                Critical Orifice Vacuum
                                                                                                   M3/min
                                                                                                       Ft3/min
                                                                                                    in. Hg
Traverse
Point #
         Cyclonic
         Flow Angle
                       Ap
Ap"x 5min
(pp) avg
min. + sec.
sample time
                     running time
                     min.
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
                                                                  o
                    '•/7
                                                   5"'  ^"
                                         5.3-3
                                                   5'  /V"
   3
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                                                    S"   37
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                                                                  o
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                                   7
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                                   =2.70
                                  77/3
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                                                                                     77.JT
                                                                                     77,
                                                   5'   "f
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                                                      Page 1

-------
                                                  slack test 'caic." sheet'
                    VELOCTTY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:  .Arli*-f-«*j
Date: iafaafas'    Time:	LL
                                                    Run#
Location:_
                                           _A'i  sl-nln
                                     ^
Operators:J
Beginning Stack Temp.:	Z
Ending Stack Temp.:
                       Pre-Test Leak Check	
                       M3/min x 35.315 =
                       Critical Orifice Vacuum_
                                                                                               O   M3/min
                                                                                                     _Ft3/min-
                                                                                                     _in. Hg
Average Stack Temp.:	
Barometer:    3.cf,S"Y
                                                                          Post-Test Leak Check    O   M3/min
                                                                          M3/min x 35.315 =         &   Ft^/min
                                                                          ' Critical Orifice Vacuum
                                                                                                      in. Hg
Traverse
Point #
          Cyclonic
          Flow Angle
                       Ap

                 avg
min. + sec.
sample time
                                 running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
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                                                       Page 1

-------
                                                  "stack" test' calc.'sfieet"
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:_
Date:
             ssryc-^
                     Time:
                                                     Run #
                                                                 3
Location:
                   yfr
Operators:  D"
             Wt
                                                                           Pre-Test Leak Check   C7  M3/min
                                                                           M3/mi;n x 35.315 =       &    FtVmin -
Beginning Stack Temp.:_
Ending Stack Temp.:	
Average Stack Temp.:	
Barometer:	
                                                                           Critical Orifice Vacuum
                                                                                                       in. Hg
                                                                           Post-Test Leak Check	M /min
                                                                           M3/min x 35.315 =     	
                                                                           Critical Orifice Vacuum        in. Hg
                                                                                                        _Ft3/min
Traverse
Point #
         Cyclonic
         Flow Angle
                       Ap
                                           (Ep) avg
         min. + sec.
         sample time
running time
gas meter
reading (L)
gas meter
temp.
critical orifice
vacuum (in.hg)
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                                                       Page 1

-------
                    VELOCITY TRAVERSE AND POINT SAMPLE TIME CALCULATION SHEET
Plant:
Date:
                               Run #
Time:
Location:	—
Operators:	i
Beginning Stack Temp.:    »—
Ending Stack Temp.:	•—•
                                                     Pre-Test Leak Check   (fS  M3/min
                                                     M3/min x 35.315 =        O    FtVmin -
                                                     Critical Orifice Vacuum 3.O, cJ in. Hg
Average Stack Temp.:    '~~
Barometer:	
                                                                         Post-Test Leak Check_
                                                                         M3/min x 35.315 =
                                                                         Critical Orifice Vacuum
                                                                              _M3/min
                                                                              	FtfVmin
                                                                               Jn. Hg





Traverse
Point #













Cyclonic
Flow Angle













Ap













fAp













(Ep) avg













min. + sec.
Sample time








-




mnning tirrie
min.
O
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                                                     Page 1

-------
                Appendix E



Laboratory QA/QC Data for Stack Testing Samples

-------
 NI  STACK TEST  PROJECT   P1

 A  When Samples received in house, they are logged in.
    IDs double checked by QA Coordinator when delivered to lab.
    Three samples per test run are received...  1) front half- or probe rinse
                                            2) filter
                                            3) back half- or impringer

 D  The Filter part of the sample run:
    1) these are large filter pads delivered in petrie dishes
    2) they are digested according to Method 29, sec 8.3.1.2.
    3) 4 rnls HF, and 6 rnls cone HN03 are the acids used.
    4) As long as the filter < 1 g, digestion is complete, in that the final solution is clear and colorless.
              Even though the procedure says to use 0.5 g sections; the chance of contamination is
              increased, and reagent use would double, conflicting with our pollution prevention
              philosophy.
    5) When the microwave digestions are completed, the digestion solution is quantitatively transferred
              to a 4-oz bottle and capped.
    6) A LRB and LFB is also included with this prep batch

 E  The Probe rinse part of the sample run:
    1) these are dellivered in quart glass jars.
    2) they are digested  according to Method 29, sec 8.3.3.
    3) the initial total volume of the sample is measured and recorded.
    4) the pH  is checked with  paper to insure it is < 2.0, and this is recorded.
    5) Since the sample  is to be analyzed for nickel only, the total volume is used.
              The sample is "quantitatively" transferred to an appropriate sized beaker.
    6) Reduce volume to about 20 mis, by evaporating on a hot plate.
              this may take a couple of days,  and sample  must be protected from contamination,
              by covering the beakers overnight.
    7) The 20 rnls is then quantitatively transferred to a microwave vessel.
    8) 4 rnls HF, and 6 rnls cone HN03 are added to each vessel and the samples are then microwaved.
    9) A LRB and LFB is also included with this prep batch.
    10) The digestate is then added to the corresponding "filter digestate" for the analytical fraction.
              The digestion sample is expected to be clear and colorless to be complete.

 F  This analytical fraction corresponds to "analytical fraction 1A":
    1)  includes the filter pad and the probe rinse.
    2)  When the digested solutions are combined, the final  volume is  adjusted to a convenient level
              with Dl water,  (usually 100 mis)
    3)  This sample is now ready for analysis by Flame AA.

 G  The impinger samples corresponds to "analytical fraction 2A":
    1)  dellivered in quart glass jars.
    2)  digested according to Method 29, sec 8.3.4. And 8.3.4.2
    3)  the initial total volume of the sample is measured and recorded.
    4)  the pH is checked with paper to insure it is < 2.0, and this is recorded.
    5)  Since the sample is to be analyzed for nickel only, the total volume is used.
              The sample is  "quantitatively" transferred to an appropriate sized beaker.
    6)  Reduce volume to about 20 mis, by evaporating on a hot plate.
              this may take a couple of days,  and sample must be protected  from contamination,
              by covering the beakers overnight.
    7)  The 20  rnls is then quantitatively transferred to a microwave vessel.


NI STACK  TEST  PROJECT   P2
                                                                                            3/29/2006LK
                                                                                              1 OF12
                                                                               S/LAB/CoWkSht/2005 METHOD 29-2

-------
    8)  10 rnls of 3% H2O2, and 10 rnls 50% HN03 are added to each vessel and the samples
              are then microwaved.
    9)  A LRB and LFB is also included with this prep batch.
    10) quantitatively transfer the digested sample to a labeled 4-oz bottle.
              For uniformity, the volume is adjusted to 50 rnls using a 50-ml class A graduate.
              The digestion sample is expected to be clear and colorless to be complete.
    11) This sample is now ready for analysis by Flame AA.

 I   The Microwave program is as follows:
              RAMP:    20 min
                        power = 1000 watts
                        temp = 170degC
              HOLD:    10 min
                        power = 700 watts
                        temp= 170degC
              VENT:     10 min

    The applications specialists at MILESTONE, determined that since the Microwave Digestion Unit
    has the capacity to monitor and control temperature, the program was set up a bit different than
    that stated in the Method 29.

J   Volumes were determined with Class A graduated cylinders, from 25 to 250-ml sizes.
    Because of the large volumes involved, measuring was to 0.2 rnls with the 25-ml only. The other
    two were 0.5. at best.

K   All pHs were checked and recorded as <2.0.

L   "QUANTITATIVELY"  means that the containers used to transfer or hold the sample were carefully
    rinsed with Dl, and those "rinses" were added to the sample base.

M   Procedure for Method 306A

N   For the calculation we are not concerned with volumes; just the actual mg of Nl present.
    The initial volume of sample, and evaporating it down, is of no consequence.
    If a portion of the initial volume was used, this would be taken  into account.
    The analytical fraction volume is used to adjust the mg/L Reading to just "MG".
                                                                                            3/29/2006LK
                                                                                              2 OF 12
                                                                              S/LAB/CoWkShU2005 METHOD 29-2

-------
PROJECT # 080033:  METHOD 29 FOR NICKEL

date:  11/01/05



  1   Method Detection Limit for Flame AA of Nickel:              0.075 mg/L


               This MDL is calculated as per 40CFR Part 136, Appendix B.





  2  Detection for Impinger sample:                            0.004 mg Ni


               0.075 mg/L X "AF 2A"  mis X "Initial Sample Volume" mis / "SF 2A" mis X 1 L / 1000 mis



                         FINAL MLS MLS OF ORIGINAL        CONVERSION TO
                  MDL     (AF2A)     SAMPLE    MLS USED    "MG NI"
                 0.075     50      300      300      0.001       0.0038


               Although the actual mis of "original sample" varied, the volume used is that which will yield the

               highest value for the MDL.





  2   Detection for filter & probe rinse sample:                   0.007 mg Ni


               0.075 mg/L X "AF 1A" mis  X "Sample Volume" mis / "SF 1" mis X 1 L / 1000 mis



                          FINAL MLS MLS OF ORIGINAL         CONVERSION TO
                   MDL     (AF1A)    SAMPLE   MLS USED    "MG NI"
                  0.075    100       °       100     0.001      0.0075
   3  Detection for TOTAL RUN sample:                        0.011 mg Ni


                = Impinger + filter & probe rinse

-------
Nl STACK  TEST  PROJECT


    H    The BLANK Sample batch
         1) dellivered in quart glass jars.
         2) digested according to Method 306A, sec 11.3.1.1
         3) the initial total volume of the sample is measured and recorded.
         4) the pH is checked with paper to insure it is < 2.0, and this is recorded.
         5) Since the sample is to be analyzed for nickel only, the total volume is used.
                   The sample is "quantitatively" transferred to an appropriate sized beaker.
         6) Reduce volume to aboutlOO mis, by evaporating on a hot plate.
                   When the volume is about 100 mis, add 10 mis cone HNO3.
                   Reflux the sample to near dryness
                   Add another 5 mis cone. HNO3, and complete the digestion
                   Quantitatively transfer the solution to a 50 ml volumetric flask.
                   Add 0.5 mis cone HNO3, and dilute to volume,  (do not add Ca(NO3)2-this is nc
         7) These solutions are now ready for Flame AA analysis.

-------
PROJECT # 2005110202:   METHOD  29 FOR NICKEL
  1         2           3456789         10
                                                                                             11
                                                                                                        12
12
SA#
2
3
1
39
4
38
6
7
5
9
10
8
12
13
11
15
16
14
18
19
17
21
22
20
24
25
23
27
28
26
30
31
29
33
34
32
36
37
35


SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger (
filter
probe rinse
RUN ID

Cond. 3: RUN
#1


BLANK


Cond. 3: RUN
#2


Cond. 3: RUN
#3


Cond. 6: RUN
#1


Cond. 6: RUN
#2


Cond. 6: RUN
#3


Cond. 5: RUN
#1


Cond. 5: RUN
#2


Cond. 5: RUN
#3


Cond. 4: RUN
#1

Cond. 4: RUN
#2

Cond. 4: RUN
#3

MDL^

PH
<2.0

<2.0
<20

<2.0
<20

<2.0
< 20

<2.0
< 20

<2.0
<20

<2.0
<20

<2.0
<20

<2.0
<20

<2.0
< 20

<2.0
<2 0
< 2 0
<20

<2.0
< 2.0
< 2 0

•k ^

Sample
Fraction
SF = SFA)
336
1 filter
100.0
300
1 filter
99.0
334
1 filter
98.0
344
1 filter
98.0
331
1 filter
97.0
334
1 filter
98.0
335
1 filter
97.0
325
1 filter
96.0
328
1 filter
97.0
223
1 filter
98.0
334
1 filter
97 0
325
1 filter
97.0
324
1 filter
96 0
••< ',soa
1 filter *
100,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
NA
20
X 20-
i NA-
,-, &
REAGENTS
FOR DIG.
HNO3 + H2O2
HF + HN03
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HN03
W03 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 +• H20
HF + HNO3
HF + HNO3
HNO3 + H20
HF + HNO3
HF + HNO3
HF + HN03
HF + HNO3
WO3 -f\H20
-fcj^KNpS
-»HF,-+~HNO3
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.1.2
8.3.42
93.12
8,3.1 2
Analytical
Fraction
AF = AFA)
50
100

50
100

50
100

50
100

50
100

50
100

50
100

50
100

50
100

50
100
•MBMMBHM^BH
50
100
50
100
50
100
. '. ri50 ,
• MO'Q

Nl mg/L
Ca1 or Ca2 )
< 0.074
0.447

0.078
0.106

< 0.074
0.285

0.087
0.274

0.087
4.306

< 0.074
10.394

0.100
16.344

< 0.074
4.878

< 0.074
6.664

< 0.074
3.829

0.090
0.895
0.106
0.483
< 0 074
0.249
0.075 ;
0.075 »

MG Nl
IN INITIAL
SAMPLE
0.004
0.045

0.004
0.011

0.004
0.029

0.004
0.027

0.004
0.431

0.004
1.039

0.005
1.634

0.004
0.488

0.004
0.666

0.004
0.383

0.005
0.090
0.005
0.048
0.004
0.025
0.004
0.008
-K
TOTAL MG
PER RUN

.048


.015


0.032


.032


.435


1.043


.639


0.492


0.670


0.387


0.094

.054

0.029

- (hull

1 0   Samples that read 
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
^5100 AA
 1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
 2 INSTRUMENT SET-UP:
   (For Specific instrument settings, see current copy of method.)
                             Date:
1/9/2006
                           Analyst:   LK
                                 (Mg/L)
                             IDL= 0.027
                            MDL= 0.075
                             RL = 0.10
                            LDR = 0.10 to 8.0
3
CALIBRA
Cal Curve:





Corr. Coef:
TION:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.237
0.517
1.019
2.069
4.966
0.9998
% Rec.
94.7
103.3 '
101.9
103.5
99.3

4
STANDARD TRACEABILITY
QC STANDARD

CCV CRA AAT
QCS LFM

Standard Name, Company, & Lot #
CPI QC-21 41M044
CPIQC-21 41M044
CPI05F011

(> 0.995 i
•5 <%AMPI F ANAI YTI^AL RUN
MAT-
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M29
M'9
M29
SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
202-1+3
SPK
202-4+38
CCB
202-14+16
202-17+19
202-23+25
202-26+28
202-32+34
CCB
CCV
LFB
DUP
DSER OIL
202-6
202-1 2
CCV
202-18
202-24
202-36
STD CONC
5.00
2.00
0.05
0.25
1.00
0.50
1.00
2/10
1.00
READING
Mg/L
4.981
2.043
-0.024
0.077
0.230
-0.015
0.431
1.431
0.096
-0.008
8.861
1.637
5.913
3.860
0.449
0.036
0.488
1.033
0.057
0.191
-0.024
0.032
-.091
0.052
0.028
0.078
BLK
0.056
-0.018
-0.018
-0.001
-0.015
-0.015
-0.030
0.006
-0.027
-0.011
-0.037
-0.008
-0.001
-0.006
0.003
-0.007
-0.036
-0.021
0.031
-0.035
-0.021
0.036
0.016
-0.020
0.027
-0.047
-0.035
0.059
-0.055
0.009
-0.039
-0.048
-0.048
-0.005
0.017
0.003
RESULT
4.981
2.043
-0.024
0.021
0.092
0.248
0.231
-0.014
1.623
0.447
0.434
1.425
0.282
0.106
0.285
0.274
0.029
4.974
8.862
1.039
13.115
1.634
5.949
0.666
3.829
0.895
0.483
0.249
0.057
0.433
0.472
0.010
1.053
0.051
0.030
1.114
0.216
0.238
,-OTJ7oN.
t -0.082 }
•^887"
0.087
0.029
1.082
0.052
0.100
0.048
0.033
0.051
0.090
0.106
0.074
-0.027
0.271
DILI
To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1~0
10.0
10.0
1.0
1.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
to
1.0
DIL2
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
To
QC
RESULTS
102
-0.024
42
9?
108
2.8
1.0
99
0.010
106
0,029
-0027

Mg/L
0.285
10.394
4.878
6664
0.895
0.249
IERUH ONCE
0.051
0.078
0087
0.052
0.048
0.051
Ktn
mq/L
0.285
10.394
4.878
6.664
0.895
0.249
!
0.074
0.078
0.087
0.074
0.074
0.074
— I
ICP

95-105%R )
95-1 05%R )
< MDL )
70-130%R )
70-1 30%R }
90-11 0%R)
90-11 0%R)
< MDL )
80-120%R )
«10RPD, IFSA»20XMDL)
80-120%R )
<10%DIFF)
< MDL )
90-11 0%R)
(< MDL )
{90-110%R )
; 90-1 1 0%R }
(< MDL j
(80-120%R)
(<10 RPD, IF SA > 2QX MDL)
(80-120%R)
(<10%DIFF)
< <10%DIFF)
{< MDL i
( 90-11 0%R)
(< MDL )
( 90-11 0%R)

-------
Method Name:  NI
Method Description: Nickel

Date: 01/09/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 15
Sample Info File: Untitled
                                Element: Ni
Calibration Equation: Zero Intercept:  Linear
Slit Width: 0.20 nm
Energy: 70
Results Data Set:
Element: Ni Seq. No.: 1
Sample ID; Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 2
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 3
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
AS :

BlnkCorr
Signal
0.074
0.075
0.075
0.075
0.000
0.46

AS !

BlnkCorr
Signal
0.008
0.004
0.009
0.007
0.003
40.94

AS

BlnkCorr
Signal
0.039
0.005
0.266
0.103
0.142
137.20

Loc. : 	

Peak
Area
0.074
0.075
0.075




Loc. : 	

Peak
Area
0.083
0.078
0.083




Loc. : 	

Peak
Area
0.121
0.087
"0.347




Date: 01/09/2006

Bkgnd Time
Area
0.000 08:35:00
0.000 08:35:02
0.000 08:35:04




Date: 01/09/2006

Bkgnd Time
Area
-0.009 08:36:44
-0.005 08:36:46
-0.009 08:36:48




Date: 01/09/2006

Bkgnd Time
Area
-0.044 08:36:57
-0.013 08:36:59
-0.275 08:37:01




                                            Page 1

-------
Element: Ni Seq. No,: 4
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 5
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 6
Sample ID: Calib Blank
Repl SampleConc StndConc,
$ mcf/L mg/L ^
1 / ,'
2
3
Mean :
SD : I
%RSD:
Auto-zero performed.-'
Element: Ni Seq. \ No.: 7
Sample ID: CAL STD \
Repl SampleConc StndConc
# mg/L mg/L
1 \
2 \
3 \
Mean :
SD : \
%RSD :
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.106 0.079
-0.097 0.088
-0.100 0.085
-0.101
0.005
4.53

AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 0.081
0.005 0.088
0.007 0.091
0.003
0.005
189.79

,AS"~~Eoc7 ": • -.; —

'*"' BlnkCorr Peak
/ Signal Area
0.000 0.087
-0.001 0.086
-0.003 0.084
-0.001
0.002
151.73

AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 0.090
0.005 0.091
0.003 0.089 „
0.004 /
0.001 X
24.43 /
Date: 01/09/2006

Bkgnd Time
Area
-0.005 08:38:11
-0.014 08:38:14
-0.011 08:38:17




Date: 01/09/2006
	 -W- 	 -/
\ \ \ '
Bkgnd Time \ A V \
Area kj J \ \01
-0.006 08:41:11 1^ , \ \J^
-0.014 08:41:13 \ K>
-0.016 08:41:15 Yfi-
^n
/
y

Date: 01/09/2006

Bkgnd Time
Area \
-0.01'B 08:41:35
-0.011 08:41:37
-0.009\ 08:41:39
|
I
•
i
i
Date: /01/09/2006

Bkgnd Time
Area
-d.005 08:42:24
/-0.005 08:42:26
/ -0.004 08:42:28 r- /
VfP
\ ^
\ \J 	
Standard number 1 applied'X.JO.25]
Correlation Coefficient:    ~
Slope: 0.0162
                                           Page 2

-------
Element: Ni Seq. No.: 36
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
i
o
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 37
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 38
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No^,: 39
Sample ID: "SAL-SID ^ \, v>
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1 applied.
Correlation Coefficient: 0
AS I

BlnkCorr
Signal
0.003
-0.001
-0.003
0.000
0.003
2081.21

AS :

BlnkCorr
Signal
-0.004
-0.003
-0.005
-0.004
0.001
20.40

AS :

BlnkCorr
Signal
-0.001
0.001
-0.001
0.000
0.001
187.21

AS
i- \~
-------
Element: Ni Seq. No.: 40
Sample ID: CAL STD
Repl SampleConc StndConc
# mg/L mg/L
-1

3
Mean:
SD :
%RSD:
Standard number 1 applied. [
Correlation Coefficient: 0.
Element: Ni Seq. No.: 41
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
i

3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 42
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
9
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 43
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
9
3
Mean:
SD :
%RSD:
Standard number 4 applied.
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.009 0.088
0.009 0.088
0.009 0.088
0.009
0.000
3.40
;o.25]
9998
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.018 0,097
0.021 0.100
0.020 0.099
0.020
0.001
6.26
[0.50]
.9998
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.039 0.118
0.038 0.117
0.039 0.118
0.039
0.000
1.06
[1.00]
.9998
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.078 0.157
0.079 0.158
0.078 0.157
0.078
0.000
0.56
[2.00]
Date: 01/09/2006

Bkgnd Time
Area
0.000 09:47:11
0.000 09:47:13
0.000 09:47:15



Slope: 0.0377
Date: 01/09/2006

Bkgnd Time
Area
0.001 09:47:29
-0.002 09:47:31
0.000 09:47:33



Slope: 0.0377
Date: 01/09/2006

Bkgnd Time
Area
0.000 09:48:03
0.001 09:48:05
0.000 09:48:07



Slope: 0.0377
Date: 01/09/2006

Bkgnd Time
Area
0.001 09:48:25
0.001 09:48:27
0.001 09:48:30




Correlation Coefficient:  0.9997
      Slope: 0.0377
Page 11

-------
Element: Ni    Seq. No,:  44
                                   AS Loc
                                                  Date: 01/09/2006
Repl
#
1
J.
3
Mean:
SD :
SampleConc StndConc
mg/L mg/L




BlnkCorr
Signal
0.188
0.188
0.189
0.188
0.001
Peak
Area
0.267
0.267
0.267


Bkgnd
Area
0.001
0.002
0.001


Time
09:48:47
09:48:49
09:48:51


                                 0.27
Standard number 5 applied.  [5.00]
Correlation Coefficient:   0.9998
                                                  Slope:  0.0378
                                                Ni
                     0.20
                                              Concentration


Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5

Mean Signal
(Absorbance)
0.000
0.009
0.020
0.039
0.078
0.188
Correlation Coefficient: 0.99978
Entered
Calculated


Concentration Concentration Standard
(mg/L)
0.25
0,50
l.QO
2.00
5.00
Slope:
(mg/L)
0.000
0.2368
0.5167
1.019
2.069
4.966
0.03784
Deviation
0.0009
0.0003
0.0012
0.0004
0.0004
0.0005

%RSD
187.2082
3. 3956
6.2608
1.0583
0.5556
0.2662

                                                                                     0
                                          Page  12

-------
Element
Sample
: Ni Seq.
ID: ccv
No.: 45
Repl SampleConc StndConc
# mg/L mg/L
l -^ nn? 5.002
j-
9
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
i
2
3
Mean:
SD :
%RSD:
4. 997
4.944
4.981
0.0317
0.64
: Ni Seq.
ID: qcs
SampleConc
mg/L
2. 020
2. 036
2.072
2.043
0.0267
1.31
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0. 0143
0. 0124
-0.0698
-0.0239
0.0419
175.3
4.997
4.944
4.981
0.0317
0.64
No.: 46

StndConc
mg/L
2.020
2.036
2.072
2.043
0.0267
1.31
No.: 47

StndConc
mg/L
-0.0143
0.0124
-0.0698
-0.0239
0.0419
175.3
AS Loc. : 	
BlnkCorr
Signal
0.189
0.189
0.187
0.188
0.001
0.64
Peak
Area
0.268
0.268
0.266



AS Loc. : 	

BlnkCorr
Signal
0.076
0.077
0.078
0.077
0.001
1.31
AS

BlnkCorr
Signal
-0.001
0.000
-0.003
-0.001
0.002
175.28

Peak
Area
0.155
0.156
0.157



Loc. : 	

Peak
Area
0.078
0.079
0.076



Date: 01/09/2006
Bkgnd
Area
0.001
0.001
0.001



Time
09:49:39
09:49:41
09:49:43

/
j
Date: 01/09/2006

Bkgnd
Area
0.001
0.001
0.001



Date:

Bkgnd
Area
-0.001
-0.003
0.001




Time
09:50:05
09:50:07
09:50:10


/
01/09/2006

Time
09:50:29
09:50:31
09:50:33


-J
Page 13

-------
Element: Ni    Seq.
Sample ID: Sample
                    No.:  48
                                  AS Loc.
Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1       0.0009     0.0009
Auto-zero performed.
       BlnkCorr
        Signal
         0.000
Peak
Area
0.079
                                                 Date: 01/09/2006
Bkgnd    Time
Area
-0.002  09:50:39
Element: Ni    Seq. No.: 49
                                  AS Loc.
                                                 Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0500
0.0695
0.1486
0.0560
0.1000
178.5
StndConc
mg/L
-0.0500
0.0695
0.1486
0.0560
0.1000
178.5
BlnkCorr
Signal
-0.002
0.003
0.006
0.002
0.004
178.50
Peak
Area
0.077
0.082
0.085



Bkgnd
Area
. 0.000
-0.005
-0.008



Ti
09:
09:
09:



me
50
50
50



:47
:49
:51

/
__!_—-
Element: Ni     Seq. No.:  50
                                  AS Loc.
                                                  Date:  01/09/2006
Repl
#
9
.£.
3
Mean:
SD :
SampleConc
mg/L
0. 0583
-0.0034
0.1755
0.0768
0.0909
StndConc
mg/L
0.0583
-0.0034
0.1755
0.0768
0.0909
BlnkCorr
Signal
0.002
0.000
0.007
0.003
0.003
Peak
Area
0.081
0.079
0.086


Bkgnd
Area
-0.002
0.001
-0.006


Time
09:51:
09:51:
09:51:


08
11
13

/
 %RSD:
           118.3
118.3
                               118.26
                     No,:  51
                                   AS Loc.
                                                  Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0028
-0
-0
-0
0

.0157
.0071
.0067
.0093
139.5
StndConc
mg/L
0.0028
-0
-0
-0
0

.0157
.0071
.0067
.0093
139.5
BlnkCorr
Signal
0.000
-0.
0.
0.
0.
139
001
000
000
000
.48
Peak Bkgnd Time
Area Area
0.079 -0.002 09:51:28
0.078 -0.001 09:51:31
0.079 -0.001 09:51:33


v/
                     No.: 52
                                   AS Loc.
                                                  Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 1333
0.1612
0.0901
0.1282
0.0358
27.92
StndConc
mg/L
0.1333
0.1612
0.0901
0.1282
0.0358
27.92
BlnkCorr
Signal
0.005
0.006
0.003
0.005
0.001
27.92
Peak
Area
0.084
0.085
0.082



Bkgnd
Area
-0.002
-0.003
-0.001



Time
09:53:
09
09



:53:
:53:



39
41
43



                                            Page 14

-------
Element: Ni Seq. No.: 53
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0336 0.0336
2 0.0624 0.0624
3 0.0113 0.0113
Mean: 0.0358 0.0358
SD : 0.0256 0.0256
%RSD: 71.61 71.61
Element: Ni Seq. No.: 54
Sample ID: era 0.25
Repl SampleConc StndConc
# mg/L mg/L
1 0.1925 0.1925
2 0.2165 0.2165
3 0.2287 0.2287
Mean: 0.2126 0.2126
SD : 0.0184- 0.0184
%RSD: 8.67 8.67
Element: Ni Seq. No.: 55
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0011 -0.0011
2 -0.0281 -0.0281
3 -0.0246 -0.0246
Mean: -0.0179 -0.0179
SD : 0.0147 0.0147
%RSD: 82.07 82. (T7
Element: Ni Seq. No.: 56
Sample ID: era 0.25
Repl SampleConc StndConc
# mg/L mg/L
1 0.2321 0.2321
2 0.2285 0.2285
3 0.2294 0.2294
Mean: 0.2300 0.230,0
SD : 0.0018 0.0018
%RSD: 0.80 0.80
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.080
0.002 0.081
0.000 0.079
0.001
0.001
71.61
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.007 0.086
0.008 0.087
0.009 0.088
0.008
0.001
8.67
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.001 0.078
-0.001
0.001
82.07
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.009 0.088
0.009 0.088
0.009 0.088
0.009
0.000
0.80
Date: 01/09/2006

Bkgnd Time (\ \ I
> \ li
Area .1 /•- V^^~
-0.004 09:54:42 4#^ ,
-0.005 09:54:45 f _, O • ( JT
-0.002 09:54:47 j^


./
Date: 01/09/2006

Bkgnd Time . \ -s
Area , jJ) [J^^
0.001 09:55:20 A U ffl^
0.000 09:55:22 tt f^
0.000 09:55:24 '• ^ Y1^^
^0 ^ \

J \
Date: 01/09/2006
1
Bkgnd Time /
Area -,
-0.001 09:56:18 ^ ,
0.000 09:56:20 \, \ L
0.000 09:56:22 y^ -fy^ w


J
Date: 01/09/2006 I
1
Bkgnd Time /
Area /
0.000 09:56:47 j/_
0.000 09:56:49
0.000 09:56:52

n i~^
& i
Page 15

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0392
2 -0.0343
3 -0.0201
Mean: -0.0312
SD : 0.0099
%RSD: 31.73
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0159
2 0.0509
3 -0.0378
Mean: -0.0009
SD : 0.0462
%RSD: 4903
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0-081
2 -0.0325
3 -0.0051
Mean: -0.0153
SD : 0.0150
%RSD: 98.46
Element : Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1. 621
2 1,607
3 1.596
Mean: 1.608
SD : 0.0124
%RSD: 0.77
No. : 57

StndConc
mg/L
-0.0392
-0.0343
-0.0201
-0.0312
0.0099
31.73
, No.: 58

StndConc
mg/L
-0.0159
0.0509
-0.0378
-0.0009
0.0462
4903
. No. : 59

StndConc
mg/L
-0.0081
-0.0325
-0.0051
-0.0153
0.0150
98.46
. No. : 60

StndConc
mg/L
1.621
1.607
1.596
1.608
0.0124
0.77
AS I

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
31.73
AS ]

BlnkCorr
Signal
-0.001
0.002
-0.001
0.000
0.002
4902.95
AS :

BlnkCorr
Signal
0.000
-0.001
0.000
-0.001
0.001
98.46
AS

BlnkCorr
Signal
0.061
0.061
0.060
0.061
0.000
0.77
,oc. : 	

Peak
Area
0.078
0.078
0.078



joe. : 	

Peak
Area
0,078
0.081
0.078



LOG, : 	

Peak
Area
0.079
0.078
0.079



Loc. : 	

Peak
Area
0.140
0.140
0.139



Date: 01/09/2006

Bkgnd Time
Area
0.000 09:57:40
0.000 09:57:42
-0.001 09:57:45


___
Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:03:38
-0.004 10:03:40
0.000 10:03:42



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:06:42
0.000 10:06:44
-0.001 10:06:47



Date: 01/09/2006

Bkgnd Time
Area
0.001 10:08:30
0.000 10:08:32
0.000 10:08:35



Page 16

-------
Element: Ni Seq. No.: 61
Sample ID: 202-1+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.4422 0.4422
2 0.4224 0.4224
3 0.4290 0.4290
Mean: 0.4312 0.4312
SD : 0.0101 0.0101
%RSD: 2.34 2.34
Element: Ni Seq. No.: 62
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0223 -0.0223
2 -0.0304 -0.0304
3 -0.0357 -0.0357
Mean: -0.0295 -0.0295
SD : 0.0068 0.0068
%RSD: 22.97 22.97
Element: Ni Seq. No.: 63
Sample ID: d202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.4099 0.4099
2 0.4021 0.4021
3 0.4023 0.4023
Mean: 0.4047 0.4047
SD : 0.0044 0.0044
%RSD: 1.10 1.10
Element: Ni Seq, No.: 64
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0228 -0.0228
2 0.0470 0.0470
3 -0.0051 -0.0051
Mean: 0.0064 0.0064
SD : 0.0363 0.0363
%RSD: 570.5 570.5
AS Lo

BlnkCorr
Signal
0.017
0.016
0.016
0.016
0.000
2.34
c. : 	

Peak
Area
0.096
0.095
0.095



AS LOG. : 	

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
22.97

Peak
Area
0.078
0.078
0.078



AS Loc. : 	

BliikCorr
Signal
0.016
0.015
0.015
0.015
0.000
1.10

Peak
Area
0.095
0.094
0.094



AS Loc. : 	

BlnkCorr
Signal
-0.001
0.002
0.000
0.000
0.001
570.46

Peak
Area
0.078
0.081
0.079



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:09:14
0.001 10:09:17
0.000 10:09:19



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:09:59
0.000 10:10:01
0.000 10:10:03



Date: 01/09/2006

Bkgnd Time
Area
0.001 10:10:29
0.001 10:10:31
0.001 10:10:33



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:10:50
-0.003 10:10:52
-0.001 10:10:54



Page 17

-------

Element: Ni Seq. No.: 65
Sample ID: s202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 1.419 1.419
2 1.419 1.419
3 1.455 1.455
Mean: 1-431 1.431
SD : 0.0204 0.0204
%RSD: 1-43 1.43
Element: Ni Seq. No.: 66
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0081 -0.0081
2 -0.0226 -0.0226
3 -0.0498 -0.0498
Mean: -0.0269 -0.0269
SD : 0.0212 0.0212
%RSD: 78.83 78.83
Element: Ni Seq. No.: 67
Sample ID: ser202-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.2490 0.2490
2 0.2584 0.2584
3 0.2584 0.2584
Mean: 0.2553 0.2553
SD : 0.0054 0.0054
%RSD: 2.12 2.12
Element: Ni Seq. No.: 68
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0092 -0.0092
2 -0.0237 -0.0237
3 0.0002 0.0002
Mean: -0.0109 -0.0109
SD : 0.0120 0.0120
%RSD: 110.3 110.3

AS Loc. : 	

BlnkCorr Peak
Signal Area
0.054 0.133
0.054 0.133
0.055 0.134
0.054
0.001
1.43
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.002 0.077
-0.001
0.001
78.83
AS Loc. : - —

BlnkCorr Peak
Signal Area
0.009 0.088
0.010 0.089
0.010 0.089
0.010
0.000
2.12
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
0.000 0.079
0.000
0.000
110.30

Date: 01/09/2006
	 • 	 '
Bkgnd Time
Area
0.001 10:11:14
0.001 10:11:16
0.000 10:11:18



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:11:34
0.000 10:11:36
0.000 10:11:38



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:12:34
0.000 10:12:36
0.000 10:12:39



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:12:52
0.000 10:12:54
-0.002 10:12:56



Page 18

-------
Element: Ni Seq. No.: 69
Sample ID: 202-4+38
Repl SampleConc StndConc
# mg/L mg/L
1 0.1234 0.1234
2 0.0758 0.0758
3 0.0873 0.0873
Mean: 0.0955 0.0955
SD : 0.0248 0.0248
%RSD: 25.98 25.98
Element: Ni Seq. No.: 70
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0460 -0.0460
2 -0.0325 -0.0325
3 -0.0285 -0.0285
Mean: -0.0356 -0.0356
SD : 0.0092 0.0092
%RSD: 25.69 25.69
Element: Ni Seq. No.: 71
Sample ID: 202-5+7
Repl SampleConc StndConc
ft mg/L mg/L
1 0.2487 0.2487
2 0.2356 0.2356
3 0.2635 0.2635
Mean: 0.2493 0.2493
SD : 0.0140 0.0140
%RSD: 5.61 5.61
Element: Ni Seq. No.: 72
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0355 -0.0355
2 -0.0216 -0.0216
3 -0.0513 -0.0513
Mean: -0.0361 -0.0361
SD : 0.0149 0.0149
%RSD: 41.13 41.13
AS Lo

BlnkCorr
Signal
0.005
0.003
0.003
0.004
0.001
25.98
c. : 	

Peak
Area
0.084
0.082
0.082



AS Loc. : 	

BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
25.69

Peak
Area
0.077
0.078
0.078



AS Loc. : 	

BlnkCorr
Signal
0.009
0.009
0.010
0.009
0.001
5.61

Peak
Area
0.088
0.088
0.089



AS Loc. : 	

BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
41.13

Peak
Area
0.078
0.078
0.077



Date: 01/09/2006

Bkgnd Time
Area
-0.004 10:13:28
-0.002 10:13:30
-0.002 10:13:32



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:13:47
0.000 10:13:49
-0.001 10:13:51



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:14:14
0.000 10:14:16
0.000 10:14:18



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:14:32
0.000 10:14:34
0.001 10:14:37



Page 19

-------
Element: Ni Seq.
Sample ID: 202-8+10
Repl SampleConc
# mg/L
I 0.2427
2 0.2428
3 0.2280
Mean: 0.2378
SD : 0.0085
%RSD: 3.58
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0368
2 -0.0027
3 -0.0435
Mean: -0.0031
SD : 0.0401
%RSD: 1285
Element: Ni Seq.
No.: 73

StndConc
mg/L
0.2427
0.2428
0.2280
0.2378
0.0085
3.58
No.: 74

StndConc
mg/L
0.0368
-0.0027
-0.0435
-0.0031
0.0401
1285
, No.: 75
AS 1

BlnkCorr
Signal
0.009
0.009
0.009
0.009
0.000
3.58
JOG. : 	

Peak
Area
0.088
0.088
0.088



AS Loc. : 	

BlnkCorr
Signal
0.001
0.000
-0.002
0.000
0.002
1284.97

Peak
Area
0.080
0.079
0-077



AS Loc. : 	
Date: 01/09/2006

Bkgnd Time
Area
0.000 10:14:59
0.001 10:15:02
0.001 10:15:04



Date: 01/09/2006

Bkgnd Time
Area
-0.003 10:15:20
-0.001 10:15:23
0.000 10:15:25



Date: 01/09/2006
Sample ID: 202-11+13
Repl SampleConc
# mg/L
1 4.321
2 4.294
3 4.295
Mean: 4.303
SD : 0.0153
%RSD: 0.35
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0251
2 -0.0573
3 -0.0277
Mean: -0.0367
SD : 0.0179
%RSD: 48.65
StndConc
mg/L
4.321
4.294
4.295
4.303
0.0153
0.35
. No.: 76

StndConc
mg/L
-0.0251
-0.0573
-0.0277
-0.0367
0.0179
48.65
BlnkCorr
Signal
0.163
0.162
0.163
0.163
0.001
0.35
AS

BlnkCorr
Signal
-0.001
-0.002
-0.001
-0.001
0.001
48.65
Peak
Area
0.243
0.241
0.242



Loc. : 	

Peak
Area
0.078
0.077
0.078



Bkgnd Time
Area
0.001 10:15:44
0.001 10:15:46
0.001 10:15:48



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:16:08
0.001 10:16:10
0.000 10:16:12



Page 20

-------
                    No.:  77
                                  AS LOG.
                                                 Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0435
0.0037
0.0164
-0.0078
0.0316
405.9
StndConc
mg/L
-0.0435
0.0037
0.0164
-0.0078
0.0316
405.9
BlnkCorr
Signal
-0.002
0.000
0.001
0.000
0.001
405.92
Peak
Area
0.077
0.079
0.080



Bkgnd
Area
0.000
-0.002
-0.003



Time
10:16:20
10:16:22
10:16:24





	 	
Element: Ni    Seq. No.: 78
                                  AS LOG.
                                                 Date: 01/09/2006
Repl
# :
i
9
3
Mean:
SD :
%RSD:

SampleConc
mg/L
4 . 959
4.957
4.981
4.966
0.0134
0.27

StndConc
mg/L
4.959
4.957
4.981
4.966
0.0134
0.27

BlnkCorr Peak Bkgnd Time
Signal Area Area
0.188 0.267 0.001 10:16:49
0.188 0.267 0.001 10:16:51
0.188 0.268 0.002 10:16:53
0.188
0.001
0.27

Element: Ni    Seq. No.: 79
AS LOG.
                                                  Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0201
0.
0.
-0.
0.

0152
0035
0005
0180
3822
StndConc
mg/L
-0.0201
0
0
-0
0

.0152
.0035
.0005
.0180
3822
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.078 -0.001 10:17:12
0.
0.
0.
0.
3821
001 0.080 -0.002 10:17:14
000 0.079 -0.001 10:17:16
000
001
.57
Element: Ni     Seq. No.:  80
                                   AS  Loc.
                                                  Date:  01/09/2006
Repl
#
i
-L
Sample
9
£*
S ample
^
O
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
8 . 833
absorbance
8. 899
absorbance
8.851
absorbance
8.861
0.0340
0.38
absorbance
StndConc
mg/L
8.833
is
is
is



is
greater
8.899
greater
8.851
greater
8.861
0.0340
0.38
greater
BlnkCorr
Signal
0.334
than
0.
than
0.
than
0.
0.
0
that
337
that
335
that
335
001
.38
than that
Peak
Area
0.413
of
0.
of
0.
of



of
the
416
the
414
the



the
Bkgnd

Area
0.002
Time
10:17:
highest standard.
0.001 10:17:
highest standard.
0.001 10:17:
highest



highest

34
36
38
standard.









standard.
                                            Page 21

-------
                    No.:  81
                                 AS  Loc.
                                                 Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0336
-0.0242
0.0387
-0.0064
0.0393
617.8
StndConc
mg/L
-0.0336
-0.0242
0.0387
-0.0064
0.0393
617.8
BlnkCorr
Signal
-0.001
-0.001
0.001
0.000
0.001
617.84
Peak
Area
0.078
0.078
0.080



Bkgnd
Area
0.000
0.000
-0.003



Time
10:18:00
10:18:02
10:18:04


	
Element: Ni    Seq. No.:  82
                                  AS Loc.
                                                 Date:  01/09/2006
Repl
#
"I
2
3
Mean:
SD :
%RSD:
SampleConc
rng/L
1. 026
1.032
1.041
1.033
0.0076
0.74
StndConc
mg/L
1.026
1.032
1.041
1.033
0.0076
0.74
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.039 0.118 0.001 10:19:09
0.039 0.118 0.001 10:19:11
0.039 0.118 0.000 10:19:14
0.039
0.000
0.74
Element: Ni    Seq. No.: 83
                                  AS Loc.
                                                 Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0408
-0. 0721
-0.0507
-0.0546
0.0160
29.31
StndConc
mg/L
-0.0408
-0.0721
-0.0507
-0.0546
0.0160
29.31
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.002 0.077 0.000 10:19:30
-0.003 0.076 0.001 10:19:32
-0.002 0.077 0.000 10:19:34
-0.002
0.001
29.31
Element: Ni    Seq. No.:  84
Sample  ID: 202-17+19
                                  AS Loc,
                                                 Date:  01/09/2006
Repl
  #
  1
Sample
  2
Sample
  3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
rng/L
   13.09
absorbance
   13.10
absorbance
   13.06
absorbance
   13.08
  0.0230
    0.18
absorbance
 StndConc
 mg/L
   13.09
is greater
   13.10
is greater
   13.06
is greater
   13.08
  0.0230
    0.18
is greater
BlnkCorr
 Signal
  0.495
than that
  0.496
than that
  0.494
than that
  0.495
  O.OOl
   0.18
than that
 Peak     Bkgnd    Time
 Area     Area
 0.574     0.001  10:19:59
of the highest standard.
 0.575     0.001  10:20:01
of the highest standard.
 0.573     0.001  10:20:04
of the highest standard.
of the highest standard.
                                           Page 22

-------
Element: Ni    Seq. No.: 85
                                  AS Loc.
                                                 Date: 01/09/2006
sampj-ts
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0163
0.0532
-0.0292
0.0026
0.0443
1709
StndConc
mg/L
-0.0163
0.0532
-0.0292
0.0026
0.0443
1709
BlnkCorr
Signal
-0.001
0.002
-0.001
0.000
0.002
1708.94
Peak
Area
0.078
0.081
0.078



Bkgnd
Area
-0.001
-0.003
0.000



Time
10:20:19
10:20:21
10:20:23


	 ===-==================
Element: Ni    Seq. Mo.:  86
Sample ID: 202-17+19  xlO
                                  AS  Loc.
                                                  Date:  01/09/2006
nc BlnkCorr
Signal
7 0.062
6 0.063
8 0.061
7 0.062
6 0.001
6 1.5-6
Peak
Area
0.141
0.142
0.140



Bkgnd
Area
0.001
0.000
0.001



Time
10:21:17
10:21:20
10:21:22



 Element:  Ni     Seq.  No,:  87
                                   AS Loc.
                                                  Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
	
SampleConc
mg/L
0.0551
-0.0445
-0.0306
-0.0067
0.0540
810.8

StndConc
mg/L
0.0551
-0.0445
-0.0306
-0.0067
0.0540
810.8

BlnkCorr
Signal
0.002
-0.002
-0.001
0.000
0.002
810.76

Peak
Area
0.081
0.077
0.07B




Bkgnd
Area
-0.003
0.000
0.000




Time
10:21:42
10:21:45
10:21:47




 Element:  Ni    Seq. No.: 88
                                   AS Loc.
                                                  Date: 01/09/2006
tJ dlllp U- ^
Repl
# :
1
J.
O
£.
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4 . 886
4 . 831
4.897
4.871
0.0352
0.72
StndConc
mg/L
4.886
4.831
4.897
4.871
0.0352
0.72
BlnkCorr Peak
Signal Area
0.185 0.264
0.183 0.262
0.185 0.264
0.184
0.001
0.72
Bkgnd Time
Area
0.001 10:22:10
0.001 10:22:12
0.001 10:22:14



                                            Page 23

-------
Element: Ni    Seq. No.: 89
                                  AS Loc.
                                                 Date: 01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0493
-0.0133
-0.0438
-0.0355
0.0194
54.78
StndConc
mg/L
-0.0493
-0.0133
-0.0438
-0.0355
0.0194
54.78
BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.001
0.001
54.78
Peak
Area
0.077
0.079
0.077



Bkgnd
Area
0.000
-0.001
0.001



Time
10:22:30
10:22:32
10:22:35


	 	 	 ======
Element: Ni    Seq. No.: 90
Sample ID: 202-23+25
                                  AS Loc.
                                                 Date: 01/09/2006
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   5.940
absorbance
   5.925
absorbance
   5.875
absorbance
   5.913
  0.0342
    0.58
absorbance
 StndConc
 mg/L
   5.940
is greater
   5.925
is greater
   5.875
is greater
   5.913
  0.0342
    0.58
is greater
BlnkCorr
 Signal
  0.225
than that
  0.224
than that
  0.222
than that
  0.224
  0.001
   0.58
than that
 Peak     Bkgnd    Time
 Area     Area
 0.304     0.001  10:23:00
of the highest standard.
 0.303     0.002  10:23:02
of the highest standard.
 0.301     0.001  10:23:04
of the highest standard.
of the highest standard.
 Element:  Ni     Seq.  No.:  91
                                   AS  Loc.
                                                  Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0631
0. 0004
-0.0012
-0.0213
0.0362
169.7
StndConc
mg/L
-0.0631
0.0004
-0.0012
-0.0213
0.0362
169.7
BlnkCorr
Signal
-0.002
0.000
0.000
-0.001
0.001
169.66
Peak
Area
0.077
0.079
0.079



Bkgnd
Area
0.001
-0.001
-0.002



Time
10:23:35
10:23:37
10:23:39



 Element:  Ni    Seq.  No.:  92
                           AS  Loc.
                                                  Date:  01/09/2006
Repl
ft
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.6306
0.
0.
0.
0.

6471
6575
6451
0135
2.10
StndConc
mg/L
0.6306
0.
0.
0.
0.

6471
6575
6451
0135
2.10
BlnkCorr Peak
Signal Area
0.024 0.103
0
0
0
0

.024 0.104
.025 0.104
.024
.001
2.10
Bkgnd Time
Area
0.001 10:24:34
0.001 10:24:37
0.001 10:24:39



                                            Page 24

-------
Element: Mi Seq. No.: 93
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0060 0.0060
2 0.0629 0.0629
3 0.0230 0.0230
Mean: 0.0306 0.0306
SD : 0.0292 0.0292
%RSD: 95.37 95.37
Element: Ni Seq. No.: 94
Sample ID: 202-26+28
Repl SampleConc StndConc
# mg/L mg/L
1 3 834 3.834
2 3.872 3.872
3 3.874 3.874
Mean: 3.860 3.860
SD : 0.0225 0.0225
%RSD: 0.58 0.58
Element: Ni Seq. No.: 95
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
I 0.0034 0.0034
2 0 0606 0.0606
3 0.0362 0.0362
Mean: 0.0334 0.0334
SD : 0.0287 0:0287
%RSD: 86.03 86.03
Element: Ni Seq. No.: 96
Sample ID: 202-29+31
Repl SampleConc StndConc
# mg/L mg/L
1 0.9253 0.9253
2 0.9260 0.9260
3 0.9332 0.9332
Mean: 0.9282 0.9282
SD : 0.0044 0.0044
%RSD: 0.47 0.47
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.001 0.080
0.001
0.001
95.37
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.145 0.224
0.147 0.226
0.147 0.226
0.146
0.001
0.58
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.001 0.080
0.001
0.001
86.03
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.035 0.114
0.035 0.114
0.035 0.114
0.035
0.000
0.47
Date: 01/09/2006

Bkgnd Time
Area
-0.002 10:25:18
-0.004 10:25:20
-0.002 10:25:22



Date: 01/09/2006
	
Bkgnd Time
Area
0.001 10:25:50
0.001 10:25:53
0.000 10:25:55



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:26:11
-0.004 10:26:13
-0.003 10:26:15



Date: 01/09/2006

Bkgnd Time
Area
0.001 10:26:38
0.000 10:26:40
0.000 10:26:42



Page 25

-------
Element: Ni Seq. No.: 97
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0491 -0.0491
2 -0.0371 -0.0371
3 -0.0171 -0.0171
Mean: -0.0345 -0.0345
SD : 0.0162 0.0162
%RSD: 46.89 46.89
Element: Ni Seq. No.: 98
Sample ID: 202-32+34
Repl SampleConc StndConc
# mg/L mg/L
1 0.4242 0.4242
2 0.4207 0.4207
3 0.5014 0.5014
Mean: 0.4488 0.4488
SD : 0.0456 0.0456
%RSD: 10.17 10.17
Element: Ni Seq. No.: 99
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.1494 0.1494
2 0.0253 0.0253
3 0.0136 0.0136
Mean: 0.0627 0.0627
SD : 0.0752 0.0752
%RSD: 119.9 119.9
Element: Ni Seq. No.: 100
Sample ID: 202-35+37
Repl SampleConc StndConc
# mg/L mg/L
1 0.2780 0.2780
2 0.3551 0.3551
3 0.3012 0.3012
Mean: 0.3114 0.3114
SD : 0.0395 0.0395
%RSD: 12.70 12.70
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.077
-0.001 0.078
-0.001 0.078
-0.001
0.001
46.89
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.016 0.095
0.016 0.095
0.019 0.098
0.017
0.002
10.17
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 0.085
0.001 0.080
0.001 0.080
0.002
0.003
119.90
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.011 0.090
0.013 0.092
0.011 0.090
0.012
0.001
12.70
Date: 01/09/2006

Bkgnd Time
Area
0.001 10:26:59
0.000 10:27:01
-0.001 10:27:03



Date: 01/09/2006
	 „ 	 , 	 •-—• • 	
Bkgnd Time
Area
0.000 10:27:42
0.000 10:27:44
-0.002 10:27:46



Date: 01/09/2006

Bkgnd Time
Area
-0.007 10:28:01
-0.002 10:28:03
-0.001 10:28:05



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:28:26
-0.002 10:28:28
0.000 10:28:30



Page 26

-------
Element: Ni    Seq. No.:  101
                                   AS  Loc.
                                                  Date: 01/09/2006
samp-Lt;
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0387
0.0108
-0.0341
-0.0207
0.0273
132.2
StndConc
mg/L
-0.0387
0.0108
-0.0341
-0.0207
0.0273
132.2
BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
132.22
Peak
Area
0.078
0.079
0.078



Bkgnd
Area
0.000
-0.002
0.000



T:
10
10
10



ime
:28:45
:28:47
:28:49


	 -====== 	
                     No.:  102
                                   AS Loc.
Repl
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0133
0.0193
0.0762
0.0362
0.0347
95.83
StndConc
mg/L
0.0133
0.0193
0.0762
0.0362
0.0347
95.83
BlnkCorr
Signal
0.001
0.001
0.003
0.001
0.001
95.83
Peak
Area
0.080
0.080
0.082



Bkgnd
Area
-0.003
-0.002
-0.005



Time
10:40:03
10:40:05
10:40:07


	 	 	
 Element:  Ni    Se.cf.''" No. : 103
                                   AS Loc.:  	
                                                   Date:  01/09/2006
Repl SampleConc
# mg/L I
i n.4fi?5
2
3
Mean:
SD :
%RSD:
0.
n.
0.
0.

4109
47,31
46'88
005f
:====—:==
StndConc BlnkCorr Peak
mg/L Signal \ Area
0.4625 0.018 I 0.097
0
0
0
0
x--^..
.4709
.4731
.4688
.0056
1.19 ,
0
0
0
0,

.018 / 0.097
. 018/ 0.097
. 018
v'OOO
1. 19
Bkgnd Time
Area
0.001 10:41:52
0.001 10:41:54
0.001 10:41:56
\ t— .0 t~{j^ -
! p i/3

 Element: Ni    Seq. No.:  104
                                   AS  Loc.
                                                   Date: 01/09/2006
Repl
#
I
J-
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 0009
0. 0194
0.0267
0.0157
0.0133
84.93
StndConc
mg/L
0.0009
0.0194
0.0267
0.0157
0.0133
84.93
BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.001
84.93
Peak
Area
0.079
0.080
0.080



Bkgnd
Area
-0.002
-0.002
-0.002



Time
10:42:27
10:42:29
10:42:31



                                             Page 27

-------
Element: Ni Seq.
Sample ID: ccv
No.: 105
Repl SampleConc StndConc
# mg/L mg/L
1 0.4758 0.4758
2 0.4903 0.4903
3 0.4981 0.4981
Mean: 0.4881
SD : 0.0113
%RSD: 2.32
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0097
2 -0.0285
3 -0.0239
Mean: -0.0207
3D : 0.0098
%RSD: 47.22
Element: Ni Seq.
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0140
2 -0.0012
3 -0.0157
Mean: -0.0103
SD : 0.0079
%RSD: 76.69
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0249
2 -0.0042
3 -0.0300
Mean: -0.0197
SD : 0.0137
%RSD: 69.22
0.4881
0.0113
2.32
No.: 106

StndConc
mg/L
-0.0097
-0.0285
-0.0239
-0.0207
0.0098
47.22
. No. : 107

StndConc
mg/L
-0.0140
-0.0012
-0.0157
-0.0103
0.0079
76.69
. No. : 108

StndConc
mg/L
-0.0249
-0.0042
-0.0300
-0.0197
0.0137
69.22
AS LOG. : 	
BlnkCorr
Signal
0.018
0.019
0.019
0.018
0.000
2.32
Peak
Area
0.097
0.098
0.098



AS Loc.: 	

BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
47.22

Peak
Area
0.079
0.078
0.078



AS Loc. : 	

BlnkCorr
Signal
-0.001
0.000
-0.001
0.000
0.000
76.69
AS

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
69.22

Peak
Area
0.078
0.079
0.078



Loc. : 	

Peak
Area
0.078
0.079
0.078



Date: 01/09/2006
Bkgnd Time / ;f/^-""
Area <-"'" '
0.001 10:42:53
0.000 10:42:55
0.000 10:42:57



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:43:14
0.000 10:43:16
0.000 10:43:18



Date: 01/09/2006

Bkgnd Time
Area
0.00-0 10:43:36
0.000 10:43:38
0.000 10:43:40



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:43:57
-0.002 10:43:59
-0.001 10:44:01



Page 28

-------
Element: Ni Seq.
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.016
2 1.047
3 1.035
Mean: 1.033
SD : 0.0158
%RSD: 1-53
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0700
2 -0.0536
3 0.0657
Mean: 0.0274
SD : 0.0701
%RSD: 256.0
Element: Ni Seq
Sample ID: 202-2
Repl SampleConc
# mg/L
1 0,1189
2 0.0636
3 0.0521
Mean: 0.0782
SD : 0.0357
%RSD: 45.66
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0048
2 0.0442
3 0.0417
Mean: 0.0270
SD : 0.0276
%RSD: 102.0
No.: 109

StndConc
mg/L
1.016
1.047
1.035
1.033
0.0158
1.53
No.: 110

StndConc
mg/L
0.0700
-0.0536
0.0657
0.0274
0.0701
256.0
. No. : 111

StndConc
mg/L
0.1189
0.0636
0.0521
0.0782
0.0357
45.66
. No. ; 112

StndConc
mg/L
-0.0048
0.0442
0.0417
0.0270
0.0276
102.0
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.038 0.117
0.040 0.119
0.039 0.118
0.039
0.001
1.53
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.082
-0.002 0.077
0.002 0.082
0.001
0.003
256.01
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.084
0.002 0.081
0.002 0.081
0.003
0.001
45.66
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
0.002 0.081
0.002 0.081
0.001
0.001
101.99
Date: 01/09/2006

Bkgnd Time
Area
0.001 10:44:23
0.000 10:44:25
0.000 10:44:27



Date: 01/09/2006

Bkgnd Time
Area
-0.004 10:44:40
0,000 10:44:43
-0.004 10:44:45


	
Date: 01/09/2006

Bkgnd Time
Area
-0.003 10:45:02
-0.001 10:45:04
0.000 10:45:06



Date: 01/09/2006

Bkgnd Time
Area
-0,001 10:45:21
-0.003 10:45:23
-0.003 10:45:25



Page 29

-------
Element: Ni Seq,
Sample ID: d202-2
Repl SampleConc
# mg/L
1 0.0331
2 0.0689
3 0.0696
Mean: 0.0572
SD : 0.0209
%RSD: 36.57
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0069
2 -0.0216
3 -0.0606
Mean: -0.0297
SD : 0.0278
%RSD: 93.53
Element: Ni Seq
Sample ID: s202-2
Repl SampleConc
# mg/L
1 1.089
2 1.078
3 1.086
Mean: 1.084
SD : 0.0055
%RSD: 0.50
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0447
2 -0.0233
3 -0.0316
Mean: -0.0332
SD : 0.0108
%RSD: 32.45
. No. : 113

StndConc
mg/L
0.0331
0.0689
0.0696
0.0572
0.0209
36.57
. No. : 114

StndConc
mg/L
-0.0069
-0.0216
-0.0606
-0.0297
0.0278
93.53
. No.: 115

StndConc
mg/L
1.089
1.078
1.086
1.084
0.0055
0.50
. No. : 116

StndConc
mg/L
-0.0447
-0.0233
-0.0316
-0.0332
0.0108
32.45
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.080
0.003 0.082
0.003 0.082
0.002
0.001
36.57
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.079
-0.001 0.078
-0.002 0.077
-0.001
0.001
93.53
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.120
0.041 0.120
0.041 0.120
0.041
0.000
0.50
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.077
-0.001 0.078
-0.001 0.078
-0.001
0.000
32.45
Date: 01/09/2006 .

Bkgnd Time
Area
0.000 10:46:14
-0.001 10:46:16
-0.001 10:46:18



Date: 01/09/2006

Bkgnd Time
Area
-0.002 10:46:34
-0.001 10:46:36
0.001 10:46:38



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:47:04
0.000 10:47:06
0.000 10:47:08



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:48:19
-0.001 10:48:21
0.000 10:48:23



Page 30

-------
Element: Ni Seq. No.: Ill
Sample ID: ser202-2
Repl SampleConc StndConc
# mg/L mg/L
1 0.1896 0.1896
2 0.1695 0.1695
3 0.1889 0.1889
Mean: 0.1827 0.1827
SD : 0.0114 0.0114
%RSD: 6.26 6.26
Element: Ni Seq. No.: 118
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0764 -0.0764
2 0.0027 0.0027
3 -0.0675 -0.0675
Mean: -0.0471 -0.0471
SD : 0.0433 0.0433
%RSD: 91.96 91.96
Element: Ni Seq. No.: 119
Sample ID: dser202-2
Repl SampleConc StndConc
# mg/L mg/L
1 0.1939 0.1939
2 0.1817 0.1817
3 0.1974 0.1974
Mean: 0.1910 0.1910
SD : 0.0083 0.0083
%RSD: 4.32 4.32
Element: Ni Seq. No.: 120
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0122 -0.0122
2 -0.0507 -0.0507
3 -0.0589 -0.0589
Mean: -0.0406 -0.0406
SD : 0.0249 0.0249
%RSD: 61.41 61.41
AS L

BlnkCorr
Signal
0.007
0.006
0.007
0.007
0.000
6.26
AS I

BlnkCorr
Signal
-0.003
0.000
-0.003
-0.002
0.002
91.96
AS !

BlnkCorr
Signal
0.007
0.007
0.007
0.007
0.000
4.32
AS

BlnkCorr
Signal
0.000
-0.002
-0.002
-0.002
q.ooi
61.41
ioc. : 	

Peak
Area
0.086
0.085
0.086



JOG. : 	

Peak
Area
0.076
0.079
0.076



LOG. : 	

Peak
Area
0.086
0.086
0.086



Loc. : 	

Peak
Area
0.079
0.077
0.077



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:49:21
0.000 10:49:23
-0.001 10:49:25



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:49:41
-0.002 10:49:43
0.000 10:49:45



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:50:10
0.000 10:50:12
0.000 10:50:14



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:50:35
0.000 10:50:37
0.000 10:50:39



Page 31

-------
Element: Ni    Seq. No.: 121
                                  AS Loc.
                                                 Date: 01/09/2006
Sample ID: ccb 	
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
-0.0237
-0.0375
-0.0451
-0.0354
0.0108
30.62
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 202-39
SampleConc
mg/L
0.0152
0.0617
0.0497
0.0422
0.0241
57.20
StndConc
mg/L
-0.0237
-0.0375
-0.0451
-0.0354
0.0108
30.62
. No. : 122

StndConc
mg/L
0.0152
0.0617
0.0497
0.0422
0.0241
57.20
BlnkCorr
Signal
-0.0.01
-0.001
-0.002
-0.001
0.000
30.62
AS

BlnkCorr
Signal
0.001
0.002
0.002
0.002
0.001
57.20
Peak
Area
0.078
0.078
0.077



Loc. : 	

Peak
Area
0.080
0.08-1
0.081



Bkgnd
Area
-0.001
0.000
0.000



Time
10:53:
10:53:
10:53:



11
13
15



Date: 01/09/2006

Bkgnd
Area
0.000
-0.001
-0.001




Time
10:53
10:53
10:53




:33
:36
:38



	 , m/nn/onnc
 Element:  Ni    Seq.  No.:  123
                                   AS Loc.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCD
SampleConc
mg/L
-0.0226
-0.0108
-0.0375
-0.0236
0.0134
56.60

StndConc
mg/L
-0.0226
-0.0108
-0.0375
-0.0236
0.0134
56.60

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
56.60

Peak
Area
0.078
0.079
0.078




Bkgnd
Area
-0.001
-0.001
0.000




Time
10:53:52
10:53:54
10:53:56


— ==============================
 Element: Ni    Seq. No*:  124
                                   AS Loc.
sampj-e
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0396
0.0440
0.0728
0.0521
0.0180
34.61
StndConc
mg/L
0.0396
0.0440
0.0728
0.0521
0.0180
34.61
BlnkCorr
Signal
0.001
0.002
0.003
0.002
0.001
34.61
Peak
Area
0.081
0.081
0.082



Bkgnd
Area
0.001
0.000
0.000



Time
10:54:13
10:54:15
10:54:17



                                            Page 32

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0444
2 -0.0433
3 -0.0253
Mean: -0.0376
SD : 0.0107
%RSD: 28.50
Element: Ni Seq,
Sample ID: 202-9
Repl SampleConc
# mg/L
1 0.0592
2 0.0543
3 0.0355
Mean: 0.0497
SD : 0.0125
%RSD: 25.15
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0627
2 -0.0403
3 -0.0626
Mean: -0.0552
SD : 0.0129
%RSD: 23.38
Element : Ni Seq
Sample ID: 202-12
Repl SampleConc
# mg/L
1 0.0108
2 0.0578
3 0.0272
Mean: 0.0319
SD : 0.0239
%RSD: 74.72
No.: 125

StndConc
mg/L
-0.0444
-0.0433
-0.0253
-0.0376
0.0107
28.50
. No. : 126

StndConc
mg/L
0.0592
0.0543
0.0355
0.0497
0.0125
25.15
. No. : 127

StndConc
mg/L
-0.0627
-0.0403
-0.0626
-0.0552
0.0129
23.38
. No.: 128

StndConc
mg/L
0-0108
0.0578
0.0272
0.0319
0.0239
74.72
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.077
-0.002 0.077
-0.001 0.078
-0.001
0.000
28.50
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.081
0.002 0.081
0.001 0.080
0.002
0.000
25.15
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.077
-0.002 a. 077
-0.002 0.077
-0.002
0.000
23.38
AS Loc. : 	

BlnkCorr" Peak
Signal Area
0.000 0,079
0.002 0.081
0.001 0.080
0.001
0.001
74.72
Date: 01/09/2006

Bkgnd Time
Area
0.000 10:54:31
0.000 10:54:33
-0.001 10:54:36



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:54:51
0.000 10:54:53
0.000 10:54:56



Date: 01/09/2006

Bkgnd Time
Area
0.000 10:55:11
-0.001 10:55:14
0.000 10:55:16



Date: 01/09/2006

Bkgnd Time
Area
0.001 10:55:43
-0.001 10:55:45
0.000 10:55:47



Page 33

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0756
2 -0.0567
3 -0.0891
Mean: -0.0738
SD : 0.0162
%RSD: 22.01
Element: Hi Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0574
2 -0.0944
3 -0.0627
Mean: -0.0715
SD : 0.0200
%RSD: 27.93
Element : Ni Seq
Sample ID: Sample
. No. : 129

StndConc
mg/L
-0.0756
-0.0567
-0.0891
-0.0738
0.0162
22.01
.No.: 130

StndConc
mg/L
-0.0574
-0.0-944
-0.0627
-0.0715
0.0200
27.93
. No. : 131

AS :

BlnkCorr
Signal
-0.003
-0,002
-0.003
-0.003
0.001
22.01
AS

BlnkCorr
Signal
-0.002
-0.004
-0.002
-0.003
0.001
27.93
AS

Loc. : 	

Peak
Area
0.076
0.077
0.076



Loc. : 	

Peak
Area
0.077
0.075
0.077



Loc. : 	

Date: 01/09/2006

Bkgnd Time
Area
0.001 10:56:02
0.000 10:56:04
0.001 10:56:06



Date: 01/09/2006

Bkgnd Time
Area
-0.001 10:58:09
0.001 10:58:11
0.000 10:58:13



Date: 01/09/2006

Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1      -0.0749    -0.0749
Aufco-zero performed.
BlnkCorr   Peak
 Signal    Area
 -0.003    0.076
Bkgnd    Time
Area
 0.000  10:58:58
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0368
0.0016
-0.0244
-0.0199
0.0196
98.59
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0042
0.0226
0.0005
0.0091
0.0118
129.6
.No.: 132

StndConc
mg/L
-0.0368
0.0016
-0.0244
-0.0199
0.0196
98.59
. No.: 133

StndConc
mg/L
0.0042
0.0226
0.0005
0.0091
0.0118
129.6
AS Loc. : 	

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.001
98.59
AS

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
129.55

Peak
Area
0.075
0.076
0.075



Loc. : 	

Peak
Area
0.076
0.077
0.076



Date: 01/09/2006

Bkgnd
Area
0.001
0.000
0.001



Date:

Bkgnd
Area
0.000
-0.001
0.000




Time
10:59:
10:59:
10:59:





05
07
10



01/09/2006

Time

11: 03:
11:03:
11:03:






17
19
21



                                           Page 34

-------
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 1.085
2 1.112
3 1-077
Mean: 1.091
SD : 0.0185
%RSD: 1-70
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2860
2 0.2812
3 0.3049
Mean: 0.2907
SD : 0.0125
%RSD: 4.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
ft mg/L
1 0.0382
2 -0.0004
3 0.0352
Mean: 0.0243
SD : 0.0214
%RSD: 88.08
Element: Ni \ Seq
Sample ID: ccv\
Repl SampleConcX
# mg/L
1 0.2361
2 0.2298
3 0.2255
Mean: 0.2305
SD : 0.0053
%RSD: 2.32 /
No.: 134

StndConc
mg/L
1.085
1.112
1.077
1.091
0.0185
1.70
. No. : 135

StndConc
mg/L
0.2860
0.2812
0.3049
0.2907
0.0125
4.31
. No.: 136

StndConc
mg/L
0.0382
-0.0004
0.0352
0.0243
0.0214
88.08
.No.: 137

.StndCoofc-
rag/L /
0\2361
0/2298
/. 225.5^
/0.2305\
/ 0.0053 >
2.32
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.117
0.042 0.118
0.041 0.117
0.041
0.001
1.70
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.011 0.087
0.011 0.087
0.012 0.088
0.011
0.000
4.31
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.078
0.000 0.076
0.001 0.078
0.001
0.001
88.08
- AS Loc. : 	
/
BlnkCorr Peak
Signal Area
0.009 0.085
0.009 0.085
0.009 0.085
0.009 ,-, \
v 0.000 \ \ ^
\ 2.32 \v\ \
\ 'xN
Date: 01/09/2006

Bkgnd Time
Area
0.000 11:03:45
0.000 11:03:47
0.001 11:03:50



Date: 01/09/2006

Bkgnd Time
Area
0.000 11:04:12
0.000 11:04:14
-0.001 11:04:16



Date: 01/09/2006

Bkgnd Time
Area
-0.002 11:04:29
0.000 11:04:31
-0.002 11:04:33



Date: 01/09/2006

Bkgnd Time
Area » /
0.000 / 11:04:50 ^J\ /
I „-„,-_ V \ /
0.000 0-1:^4:52 ^/ v/
0.000 li,:>0V:55 K° A
wo >.|
G\ -j ^
*vV\ \ \/
{\ \ /• ^
\) \s -J i
A A' ^
VJ ^r\
Page 35

-------
Element: Ni    Seq. No.: 138
                                  AS Loc.
                                                 Date: 01/09/2006
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:

: ID: ccfo
SampleConc
mg/L
-0.0163
-0.0424
-0.0603
-0.0396
0.0221
55.83


StndConc
mg/L
-0.0163
-0.0424
-0.0603
-0.0396
0.0221
55.83
===========

BlnkCorr
Signal
-0.001
-0.002
-0.002
-0.002
0.001
55.83


Peak
Area
0.076
0.075
0.074





Bkgnd
Area
-0.001
0.000
0.001





Time
11:05:11
11:05:13
11:05:15




Element: Ni    Seq. No.:  139
                                  AS Loc,: 	
£>aiup-i-<=
Repl
#
1
2
3
Mean:
SD :
%RSD:
=
SampleConc
mg/L
0.0145
-0.0011
0.0247
0.0127
0.0130
102.1

StndConc
mg/L
0.0145
-0.0011
0.0247
0.0127
0.0130
102.1

BlnkCorr
Signal
0.001
0.000
0.001
0.000
0.000
102.10
—
Peak
Area
0.077
0.076
0.077




Bkgnd
Area
0.. 001
0.001
0.001




Time
11:05:31
11:05:33
11:05:36




                     No.:  140
                                   AS  Loc.
                                                  Date:  01/09/2006
OdlUJJ-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
-0,0180
-0.0700
-0.0546
-0.0475
0.0267
56.14

StndConc
mg/L
-0.0180
-0.0700
-0.0546
-0.0475
0,0267
56.14

BlnkCorr
Signal
-0.001
-0.003
-0.002
-0.002
0.001
56.14
•
Peak
Area
0.076
0.074
0.074




Bkgnd
Area
-0.001
0.001
0.000




Time
11:05:50
11:05:52
11:05:54




                     No.: 141
AS Loc.
                                                  Date: 01/09/2006
Repl
#
]_
•)
£u
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0. 0412
0. 0686
0.0468
0.0522
0.0145
27.71
StndConc
mg/L
0.0412
0.0686
0.0468
0.0522
0.0145
27.71
BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
27.71
Peak Bkgnd Time
Area Area
0.078 -0.001 11:06:10
0.079 -0.001 11:06:12
0.078 0.000 11:06:14



                                            Page 36

-------
Element: Ni    Seq. No.: 142
                                  AS LOG,
                                                 Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
-0.0601
-0.0373
-0.0472
-0.0482
0.0114
23.72

StndConc
mg/L
-0.0601
-0.0373
-0.0472
-0.0482
0.0114
23.72

BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.002
0.000
23.72

Peak
Area
0.074
0.075
0.074




Bkgnd
Area
0.000
0.000
0.000




Time
11:06:28
11:06:30
11:06:33




Element: Ni    Seq. No.: 143
                                  AS LOG.
                                                 Date: 01/09/2006
Repl
#
i
r>
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0. 0?1 9.
o
0.
-0.
0.

0196
0000
0005
0204
3851
StndConc
mg/L
-0.0212
0
0
-0
0

.0196
.0000
.0005
.0204
3851
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.075 0.001 11:06:47
0.
0.
0.
0.
3850
001 0.077 0.000 11:06:49
OQO 0.076 0.001 11:06:51
000
001
.97
Element: Ni     Seq.  No.:  144
                                  AS  LOG.
                                                 Date:  01/09/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0534
-0. 0746
-0.0421
-0.0567
0.0165
29.13
StndConc
mg/L
-0.0534
-0.0746
-0.0421
-0.0567
0.0165
29.13
BlnkCorr Peak Bkgnd Time
Signal Area Area
-o!o02 0.074 0.000 11:07:07
-0.003 0.073 0.001 11:07:09
-0.002 0.075 0.000 11:07:11
-0.002
0.001
29.13
 Element:  Ni    Seq.
 Sample ID:  Sample
                     No.:  145
           AS  Loc.
                                                  Date:  01/09/2006
 Repl    SampleConc  StndConc
  #     mg/L        mg/L
  1      -0.0196    -0.0196
 Auto-zero performed.
       BlnkCorr   Peak
        Signal     Area
        -0.001     0.075
Bkgnd    Time
Area
-0.001  11:07:15
 Element:  Ni    Seq.  No.:  146
 Sample ID:  ccb
            AS Loc.
                                                  Date:  01/09/2006
„ 	 J- _ -,
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0253
0.0546
-0.0451
-0.0052
0.0528
StndConc
mg/L
-0.0253
0.0546
-0.0451
-0.0052
0.0528
BlnkCorr
Signal
-0.001
0.002
-0.002
0.000
0.002
Peak
Area
0.074
0.078
0.074


Bkgnd
Area
0.000
-0.003
0.001


Time
11:07:22
11:07:24
11:07:27


 %RSD:
            1006
1006   1006.49
                                            Page  37

-------
Element: Ni Seq,
Sample ID: 202-24
Repl SampleConc
# mg/L
1 0.0279
2 0.0186
3 0.0371
Mean: 0.0279
SD : 0.0093
%RSD: 33.30
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0788
2 -0.0244
3 -0.0044
Mean: 0.0167
SD : 0.0547
%RSD: 328.4
Element: Ni Seq
Sample ID: 202-27
Repl SampleConc
# mg/L
1 0.0580
2 0.0942
3 0.0520
Mean: 0.0680
SD : 0.0229
%RSD: 33.58
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0437
2 -0.0562
3 -0.0341
Mean: -0.0447
SD : 0.0111
%RSD: 24.81
, No. : 147

StndConc
mg/L
0.0279
0.0186
0.0371
0.0279
0.0093
33.30
. No.: 148

StndConc
mg/L
0.0788
-0.0244
-0.0044
0.0167
0.0547
328.4
. No.: 149

StndConc
mg/L
0.0580
0.0942
0.0520
0.0680
0.0229
33.58
, No. : 150

StndConc
mg/L
-0.0437
-0.0562
-0.0341
-0.0447
0.0111
24.81
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.001 0.076
0.001 0.076
0.001 0.077
0.001
0.000
33.30
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.078
-0.001 0.075
0.000 0.075
0.001
0.002
328.36
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.078
0.004 0.079
0.002 0.077
0.003
0.001
33.58
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.074
-0.002 0.073
-0.001 0.074
-0.002
0.000
24.81
Date: 01/09/2006

Bkgnd Time
Area
0.001 11:07:46
0.001 11:07:48
0.000 11:07:51



Date: 01/09/2006

Bkgnd Time
Area
-0.004 11:08:05
0.000 11:08:08
-0.001 11:08:10



Date: 01/09/2006

Bkgnd Time
Area
0.001 11:08:27
0.000 11:08:29
0.001 11:08:31



Date: 01/09/2006

Bkgnd Time
Area
0.001 11:08:46
0.001 11:08:49
0.001 11:08:51



Page 38

-------
Element: Ni Seq
Sample ID: 202-30
Repl SampleConc
# mg/L
1 0.0290
2 0.0638
3 0.0424
Mean: 0.0451
SD : 0.0176
%RSD: 38.96
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0277
2 -0.0357
3 -0.0507
Mean: -0.0381
SD : 0.0117
%RSD: 30.66
Element : Ni Seq
Sample ID: 202-33
Repl SampleConc
# mg/L
1 0.0608
2 0.0483
3 0.0933
Mean: 0.0675
SD : 0.0233
%RSD: 34.48
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0012
2 0.0049
3 0.0034
Mean: 0.0032
SD : 0.0019
%RSD: 58.53
. No.: 151

StndConc
mg/L
0.0290
0.0638
0.0424
0.0451
0.0176
38.96
.No.: 152

StndConc
mg/L
-0.0277
-0.0357
-0.0507
-0.0381
0.0117
30.66
. No. : 153

StndConc
mg/L
0.0608
0.0483
0.0933
0,0675
0.0233
34.48
. No.: 154

StndConc
mg/L
0.0012
0.0049
0.0034
0.0032
0.0019
58.53
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.077
0.002 0.078
0.002 0.077
0.002
0.001
38.96
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.074
-0.001 0.074
-0.002 0.074
-0.001
0.000
30.66
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.078
0.002 0.077
0.004 0.079
0.003
0.001
34.48
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.075
0.000 0.076
0.000 0.076
0.000
0.000
58.53
Date:

Bkgnd
Area
0.001
-0.001
0.000



Date:

Bkgnd
Area
0.001
0.001
0.001



Date:

Bkgnd
Area
-0.001
-0.001
-0.002



Date:

Bkgnd
Area
-0.001
-0.001
-0.001



01/09/2006

Time

11:09:08
11:09:10
11:09:12



01/09/2006

Time

11:09:29
11:09:31
11:09:33



01/09/2006

Time

11:09:48
11:09:51
11:09:53



01/09/2006

Time

11:1-0:08
11:10:10
11:10:12



Page 39

-------
Element: Ni Seq
Sample ID: 202-36
Repl SampleConc
# mg/L
1 0.1020
2 0.0831
3 0.0475
Mean: 0.0775
SD : 0.0276
%RSD: 35.65
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0581
2 0.0104
3 -0.0048
Mean: 0.0213
SD : 0.0328
%RSD: 154.4
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 0.0124
3 -0.0270
Mean: -0.0053
SD : 0.0200
%RSD: 377.6
Element: Ni Seq
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2641
2 0.2662
3 0.2665
Mean: 0.2656
SD : 0.0013
%RSD: 0.50
. No. : 155

StndConc
mg/L
0.1020
0.0831
0.0475
0.0775
0.0276
35.65
. No.: 156

StndConc
mg/L
0.0581
0.0104
-0.0048
0.0213
0.0328
154.4
. No.: 157

StndConc
mg/L
-0.0012
0.0124
-0.0270
-0.0053
0.0200
377.6
. No.: 158

StndConc
mg/L
0.2641
0.2662
0.2665
0.2656
0.0013
0.50
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 0.079
0.003 0.079
0.002 0.077
0.003
0.001
35.65
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.078
0.000 0.076
0.000 0.075
0.001
0.001
154.37
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.075
0.000 0.076
-0.001 0.074
0.000
0.001
377.55
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.010 0.085
0.010 0.086
0.010 0.086
0.010
0.000
0.50
Date: 01/09/2006

Bkgnd Time
Area
-0.002 11:10:29
-0.002 11:10:31
0.000 11:10:33



Date: 01/09/2006

Bkgnd Time
Area
-0.003 11:10:46
-0.001 11:10:48
0.000 11:10:51



Date: 01/09/2006

Bkgnd Time
Area
0.000 11:10:58
-0.001 11:11:00
0.000 11:11:03



Date: 01/09/2006

Bkgnd Time
Area
0.000 11:11:23
0.000 11:11:25
0.000 11:11:27



Page 40

-------


IE i

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Prep Method : (check on!y one per page)






ICP/FLAA: SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 301 OA
ICP/FLAA: EPA 200.7 r4.4
ICP/FLAA: SW-846 3005A
ICP/FLAA: SW-846 3015A MICROWAVE






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GFAA: EPA 200's, SW-846 3C
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-------
  METALS   PREP   FORM
                                                            Set#
, Prep Method:    (check only one per page)
    ICP/FLAA: SM 3030 F, EPA 200.7 '82
    ICP/FLAA: EPA 200's, SW-846 301OA
    ICP/FLAA: EPA 200.7 r4.4
    ICP/FLAA: SW-846 3005A
    ICP/FLAA: SW-846 3015A MICROWAVE
    OTHER:	.		
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:_____	
 MATRIX:        (check only one per page)
    DRINKING WATER
                                                               S\QA FORMS \FM-0411R02 \LK
                                                                      Page 1 of 1

-------
 MFTALS   PREP   FORM
                                                           Set#
Prep Method:    (check only one per page)
   ICP/FLAA: SM 3030 F, EPA 200.7 '82
   ICP/FLAA: EPA 200's, SW-846 301OA
   ICP/FLAA: EPA 200.7 r4.4
   ICP/FLAA: SW-846 3005A
   ICP/FLAA: SW-846 3015A MICROWAVE
   OTHER:	_	
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:____	
MATRIX:        (check only one per page)
   DRINKING WATER
AQUEOUS
OTHER:_
                                                              S\QA FORMS \FM-041 \R02 \LK
                                                                      Page 1 of 1

-------
PROJECT #  2006020074:   METHOD 29 FOR  NICKEL
                                                                 8
10
11
                                                                                                           12
SA#
8
15

9
16
o
10
17

11
18

12
19
C
13
20

14
21
7



SAMPLE
DESCRPTION
impinger
filter

impinger
filter

impinger
filter

impinger
filter

impinger
filter

impinger
filter

impinger
filter

im$n,ger 'f
- filtejfs *V

RUN ID
BLANK
Cond. 10-1
Cond. 10-2
Cond. 10-3
Cond. 13-1
Cond. 14-4
Cond. 14-5

;; ^lyiou

PH
<20

<20
<2.0

<20
<2.0

<20
<20

< 20
<2.0

< 20
<2.0

<2,0
<2.0

<2.0
; ^ „
X \i

Sample
Fraction
(SF - SFA)
302
1 filter
100.0
300
1 filter
99.0
309
1 filter
100.0
316
1 filter
98.0
306
1 filter
97.0
313
1 filter
99.0
310
1 filter
100.0
"v300
'}- f filter
100X0 -
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
MA
^2.
\ .. 100
Nl mg/L
( Ca1 or Ca2 )

0.136
< 0.074
1.401

0.217

0.595

0.558

1.213

0.358

0.075
IN INITIAL
SAMPLE
0.004
0.014
0.004
0.140
0.004
0.022

0.060

0.056
0.005
0.121

0.036
,,.0.004
' 0^008
TOTAL MG
PER RUN
0.017
0.144
0.026
0.063
0.060
0.126
0.040
;;O.Q11
  10  Samples that read 
-------
QA/QC WORK  SHEET for  NICKEL
FLAA METHOD SOP MET-040
   '5100 AA
  1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
  2 INSTRUMENT SET-UP:
  Date:
Analyst:
2/10/2006
   LK
    (For Specific instrument settings, see current copy of method.)
             (Mg/L)
        IDL= 0.027
       MDL= 0.075
        RL= 0.10
       LDR = 0.10 to 8.0
3
CALIBRATION:
Cal Curve:





Corr. Coef:
Cone
0.25
050
1 00
200
5.00
xxxxxxxxx
Abs
0.009
0.020
0.035
0.078
0.184

Result
0.245
0.537
0.956
2.097
4.964
0.9995

% Rec.
97,8
107.4
95.6
104.9
99.3

                                                               4 STANDARD TRACEABILITY
                                                                 QC STANDARD
                                                                 Calibration
                                                                                Standard Name, Company, & Lot #
                                                                                CPIQC-21 Lot # 05H062
                                                                 CCV, CRA, AAT
                                                                                CPIQC-21 Lot#05H062
                                                                 QCS, LFM
                                             ( > 0.995)
                                                                                CPl QC-19 Lot#05FO11
s SAMPLE ANALYTICAL RUN
MAT-RIX








121
-191







121
121

121
121




M29





M29
M29
9

M29
M29

SAMPLE

QCS
STD
CCB
CRA
CRA
LRB
LFB
218-1
218-2
218-3
218-4
218-5
CCB
CCV
LRB
LFB
072-1
072-2
072-3
072-4
072-5
CCB
CCV
LRB
LFB
"074-8
SPK
DUP
SER OIL
CCB
CCV
074-9
074-1 0
074-11
074-12
074-13
074-14
CCB
STD CONC
5.00
2.00
10.00

0.05
0.10

2.00






0.25

2.00






1.00

1.00

1.0
1.0
2/10

0.50







READING
Mg/L
4969
2 129
9.083
-0.004
0051
0.098
0.030
1.980
2.201
0.284
0061
0.676
0.144
0.001
0.249
0056
2.117
0.063
0262
0.086
2 357
0.179
-0.024
0 949
0023
1 076
0.058
1.113
1.030
0.226
-0019
0.510
0033
0058
0.031
0069
0.101
0.075
0.010
BLK



-0.007
-0004
-0.004
-0.006
-0 006
0.009
-0006
-0.005
0 006
-0.008
0.011
0.001
0 009
0004
0.010
-0.001
0007
-0.003
-0.001
-0.018
-0.024
-0006
-0.005
0.005
-0018
-0 008
-0.020
0.004
-0.019
-0013
-0024
-0 008
-0.011
0 003
0.001
-0 005
RESULT
4.969
2.129
9.083
0.003
0.055
0.102
0 036
1 986
2.192
0 290
0 066
0.671
0.151
-0 009
0.247
0.048
2.113
0.054
0.264
0.080
2360
0.180
-0 006
0.973
0.029
1.081
0053
1.131
1.038
0.246
-0.023
0 529
0.046
0.082
0039
0080
0 097
0 074
0.015
DILI








1.0
'.0
• .0
1.0
1.0




1.0
1.0
1.0
• .0
1.0




1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0


DIL2








1.0
1.0
• .0
1.0
1.0




1.0
1.0
' .0
1.0
1.0




1.0
1.0
1.0
• .0


1.0
1.0
'.0
'.0
1.0
1.0


QC
RESULTS
99
106
91
0.003
109
102
0.036
99





-0.009
99
0.048
106





-0.006
97
0.029
108

108
8.5
8.8
-0.023
106






0.015

Mg/L








2.192
0.290
0.066
0.671
0.151




0.054
0.264
0.080
2.360
0.180




0.053





0.046
0.082
0.039
0.080
0.097
0.074


mq/L








2.192
0.290
0.074
0.671
0.151




0.074
0.264
0.080
2.360
0.180



A J
<(Mo





0.074
0.082
0.074
0.080
0.097
0.074


ICP

























^TI_
/,o MJ
— ^











                                                                                         95-105%R)

                                                                                         95-105%R)

                                                                                         90-110%R)

                                                                                         20XMDL)

                                                                                         (<10%DIFF)

                                                                                         (
-------
QA/QC WORK SHEET for NICKEL P2
FLAA METHOD SOP MET-040
  Date:
Analyst:
2/10/2006
  LK










M29
M29
M29

M29
M29


3 IUU Hh
ccv
LRB
LFB
*074-1+15
SPK
DUP
SER OIL
CCB
CCV
CCV
074-2+16
074-3+17
074-4+18
074-5+19
074-6+20
074-7+21
CCB
CCV
1 	
2.00

0.50

1.0
1.0


0.25
0.10







2.00
2085
0.025
0 592
0.122
1.185
1.170
0236
-0.028
0.233
0.089
1.394
0.234
0.613
0.559
1 209
0.355
0.002
2078
0.010
0.001
0.019
-0.013
0.001
-0008
-0.011
0.006
-0028
-0 009
-0.007
0.017
0.018
0.001
-0004
-0003
0002
0002
2.075
0.024
0.574
0.136
1.184
1.178
0.247
-0.034
0.261
0 098
1.401
0.217
0595
0558
1.213
0358
0.000
2076



1.0
1.0
1.0
• .0



1.0
• .0
1.0
1.0
1.0
1.0





1.0
1.0
1.0
1.0



1.0
1.0
1.0
1.0
1.0
1.0


104
0.024
115

105
0.5
4.4
-0.034
104
98






0.000
104



0.136






1.401
0.217
0.595

1.213
0.358





0.136






1.401
0.217
0.595
0.558
1.213
0.358




















                                                                    90-110%R)

                                                                    20XMDL)

                                                                    <10%DIFF)

                                                                    (< MDL)

                                                                    (90-110%R)

                                                                    (90-110%R)
                                                                   (< MDL)

                                                                   ( 90-110%R )

-------
Method Name: NI
Method Description: Nickel

Date: 02/10/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni     Seq. No.:  24
Sample  ID: Calib  Blank
                                Element: Ni
                               Calibration Equation: Zero Intercept: Linear
                               Slit Width: 0.20 nm
                               Energy: 71
                               Results Data Set:
                                  AS Loc.
                                                 Date: 02/10/2006
Repl SampleConc StndCo
# mg/L mg/L
1
2
3

Mean:
SD :
%RSD:
Auto-zero performed.
	 . 	 ====:
nc BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.096
0.001 0.098
0 000
\J , \J \J \J
0.001
745.34


Bkgnd Time
Area
0.007 10:15:47
0.007 10:15:49
0.007 10:15:51






 Element:  Ni    Seq.  No.:  25
 Sample ID:  Calib Blank
                                   AS Loc.
        SampleConc  StndConc
        mg/L        mg/L
Repl
 #
 1
 2
 3
Mean:
SD   :
%RSD:
Auto-zero performed.
 Element: Ni    Seq. No.: 26
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
576.54
==—===— ===:==:—=—=====
Bkgnd Time
Area
0.007 10:15:57
0.007 10:15:59
0.007 10:16:01




                                   AS Loc.
                                                  Date: 02/10/2006
OCUU^J-^
Repl
#

3

Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L






BlnkCorr
Signal
0.001
0.001
0.001
n nm
U . U \J J-
0.000
48.75
Peak
Area
0.098
0.098
0.098




Bkgnd
Area
0.007
0.007
0.006




Time
10:20
10:21
10:21




:59
:02
:04




Auto-zero performed.
                                             Page 8

-------
Element:  Ni    Seq.  No.: 27
                                  AS Loc.
                                                 Date: 02/10/2006
Sample
Repl
ft
1
2
3

Mean:
SD :
ID: CAL STU
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.009
0.009
0.009
0 . 009

0. 000
*-. •-! /"\

Peak
Area
0.107
0.107
0.107




Bkgnd
Area
0.007
0.007
0.007




Time
10:21:53
10:21:55
10:21:57



O J\>-> LJ m
Standard number 1 applied. [0.25]
Correlation Coefficient:
                           0.9997
                                                  Slope:  0.0376
Element: Ni Seq. No.: 28
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3

Mean:
SD :
%RSD:
AS Loc. : 	
BlnkCorr
Signal
0.019
0. 020
0.021
n 090

0.001
3.10
Peak
Area
0.117
0.118
0.119




Date: 02/10/2006
Bkgnd
Area
0.007
0.007
0.006




Time
10:22:14
10:22:17
10:22:19




 Standard number 2 applied.  [0.50]
 Correlation Coefficient:   0.9998
                                                  Slope:  0.0376
 Element:  Ni    Seq.  No.: 29
 Sample ID:  cal std 3
                                   AS Loc.
                                                  Date: 02/10/2006
 Repl   SampleConc  StndConc
  #     mg/L        mg/L
  1
  2
  3
 Mean:
 SD   :
 %RSD:
 Standard number 3 applied.  [1.00]
 Correlation Coefficient:  0.9998
                              BlnkCorr
                               Signal
                                0.035
                                0.035
                                0.036
                                0.035
                                0.000
                                 0.64
Peak
Area
0.133
0.133
0.134
Bkgnd
Area
 0.007
 0.007
 0.007
 Time

10:22:47
10:22:49
10:22:51
                                                  Slope: 0.0376
 Element: Ni    Seq. No.: 30
                                   AS Loc.
                                                   Date:  02/10/2006
Sample iu: ca_L s L.U
Repl SampleConc
# mg/L

3
Mean:
SD :
%RSD:
i
StndConc
mg/L





Standard number 4 applied.
Correlation Coefficient: 0
BlnkCorr
Signal
0.078
0.078
0.077
0.078
0.000
0.52
[2.00]
.9997
Peak
Area
0.176
0.175
0.175




Bkgnd
Area
0.006
0.007
0.007



Slope:
Time
10:23:09
10:23:11
10:23:13



0.0376
                                             Page 9

-------
Element:  Ni    Seq.  No.:
                           31
                                    AS  Loc.
                                                     Date: 02/10/2006
O CULL^ J-<^ -l- J-' • •—".-•- — 	
Repl SampleConc
# mg/L
O
Z.
3
Mean:
SD :
%RSD:
StndConc
mg/L





Standard number 5 applied.
Correlation Coefficient: 0
BlnkCorr
Signal
0.185
0.183
0.184
0.184
0.001
0.39
[5.00]
.9995
Peak
Area
0.283
0.281
0.282




Bkgnd
Area
0.007
0.007
0.007



Slope:
Time
10:23:31
10:23:33
10:23:35



0.0371
                                                  Ni
               0)
               o

               re
               •s
               o
                      0.20
                      0.15
0.10
                      0.05
                                                 Concentration
Calibration data for Ni
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5

Mean Signal
(Absorbance)
0.000
0.009
0.020
0.035
0.078
0.184
Correlation Coefficient: 0.99953
Entered
Concentration
(mg/L)
0.25
0.50
1.00
2.00
5.00
Slope: 0.
Calculated
Concentration
(mg/L)
0.000
0.2445
0.5372
0.9560
2.097
4.964
03705

Standard
Deviation
0.0004
0.0003
0.0006
0.0002
0.0004
0.0007


%RSD
48.7522
3.6976
3.0989
0.6443
0.5235
0.3890

                                               Page 10

-------
                    No.:  32
                                  AS LOG.
                                                 Date:  02/10/2006
Repl
#
1
o
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4 . 946
4 .976
4.987
4.969
0. 0213
0.43
StndConc
mg/L
4.946
4.976
4.987
4.969
0.0213
0.43
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.183 0.281 0.007 10:23:53
0 184 0.282 0.006 10:23:55
0.185 0.283 0.007 10:23:58
0.184
0.001
0.43
Element: Ni    Seq. No.: 33
                                  AS LOG.
                                                 Date: 02/10/2006
Repl
#
-\_
9
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2 . 127
2 . 138
2.121
2.129
0.0083
0.39
StndConc
mg/L
2.127
2.138
2.121
2.129
0.0083
0.39
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.079 0.177 0.007 10:24:17
0.079 0.177 0.007 10:24:19
0.079 0.177 0.007 10:24:21
0.079
0.000
0.39
Element: Ni    Seq. No.: 34
                                  AS LOG.: 	
                                                 Date: 02/10/2006
Repl
#
i
j-
S amp 1 e
2
Sample
3
Sample
Mean :
SD :
%RSD :
Sample
SampleConc
mg/L
9. 081
absorbance
9.065
absorbance
9. 104
absorbance
9.083
0.0195
0.21
absorbance
StndConc
mg/L
9.081
is greater
9.065
is greater
9.104
is greater
9.083
0.0195
0.21
is greater
BlnkCorr
Signal
0.336
than
0.
than
0.
than
0.
0.
0
than
that
336
that
337
that
337
001
.21
that
Peak
Area
0.434
of
0.
of
0.
of



of
the
434
the
435
the



the
Bkgnd
Area
0.007
Time
10:24:
highest standard.
0.007 10:24:
highest standard.
0.007 10:24:
highest



highest
46
48
50
standard.









standard.
 Element: Ni     Seq.  No.:  35
 Sample  ID: ccb
                                  AS  LOG.
                                                  Date:  02/10/2006
 Repl
  #
  1
  2
  3
 Mean:
 SD   :
 %RSD:
SampleConc
mg/L
 -0.0093
  0.0052
 -0.0161
 -0.0067
  0.0109
   161.3
StndConc
mg/L
-0.0093
 0.0052
-0.0161
-0.0067
 0.0109
  161.3
BlnkCorr
 Signal
  0.000
  0.000
 -0.001
  0.000
  0.000
 161.34
Peak
Area
0.098
0.098
0.097
Bkgnd
Area
 0.007
 0.006
 0.007
 Time

10:25:22
10:25:24
10:25:27
                                           Page  11

-------
Elemen
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
t: Ni Seq
ID: -era^CTCf
SampleConc
mg/L
-0.0132
0.0144
-0.0120
-0. 0036
0.0156
431.9
. No.-: 36
3" ££^D
StndConc
mg/L
-0.0132
0.0144
-0.0120
-0.0036
0.0156
431.9
AS Lc
BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.001
431.92
)c. : 	
Peak
Area
0.097
0.098
0.098



Udue; u.
Bkgnd
Area
0.007
0.006
0.007



£,/ J_ W / £* ^ *~> -+s
Time
10:25:37
10:25:39
10:25:42



Element: Ni    Seq. No.: 37
Sample ID: cra-0.05
                                  AS Loc.
                                                 Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
0.0510
0.0508
0.0667
0.0562
0.0091
16.23
StndConc
mg/L
0.0510
0.0508
0.0667
0.0562
0.0091
16.23
BlnkCorr
Signal
0. 002
0.002
0.002
0.002
0. 000
16.23
BlnkCorr Peak
Signal Area
0.002 0.100
0.002 0.100
0.002 0.100
0.002
0.000
16.23
Bkgnd Time
Area
0.006 10:26:01
0.007 10:26:03
0.006 10:26:05



Element
Sample
Repl
1
2
3
Mean:
SD :
%RSD:
—
: Ni Seq
ID: era- 0.1
SampleConc
mg/L
0.0996
0 . 0801
0.1147
0.0981
0.0174
17.70

. No. : 38
StndConc
mg/L
0.0996
0.1147
0.0981
0.0174
17.70

AS
BlnkCorr
Signal
0.004
fl 003
0.004
0.004
0.001
17.70

Loc. : 	
Peak
Area
0.102
0 101
0.102




Date:
Bkgnd
Area
0.007
0.008
0.007




02/10/2006
Time
10:26:21
10:26:23
10:26:25




                     No.:  39
                                   AS  Loc.
                                                  Date:  02/10/2006
O cUU£J -L C
Repl
#
1
2
3
Mean:
SD :
%RSD:
j_ *_j , \~-\^*^
SampleConc
mg/L
0.0014
-0.0093
-0.0098
-0.0059
0.0063
107.0
StndConc
mg/L
0.0014
-0.0093
-0.0098
-0.0059
0.0063
107.0
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
107.03
Peak
Area
0.098
0.098
0.098



Bkgnd
Area
0.006
0.007
0.006



T
10
10
10



ime
:26:
:26:
:26:



44
47
49



                                            Page 12

-------
Element:  Ni    Seq. No.: 40
                                  AS LOG.
                                                 Date:  02/10/2006
sampj-e
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0239
0.0371
0.0285
0.0298
0.0067
22.44
StndConc
mg/L
0.0239
0.0371
0.0285
0.0298
0.0067
22.44
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
22.44
Peak
Area
0.099
0.099
0.099



Bkgnd
Area
0.007
0.006
0.007



Time
10:27:23
10:27:25
10:27:27


	 ===============
Element: Ni    Seq. No.:  41
                                  AS LOG.
•DdUlJJ-Lc;
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.988
1.962
1.990
1.980
0.0153
0.77
StndConc
mg/L
1.988
1.962
1.990
1.980
0.0153
0.77
BlnkCorr
Signal
0.074
0.073
0.074
0.073
0.001
0.77
Peak
Area
0.172
0.171
0.172



Bkgnd
Area
0.007
0.007
0.007



Time
10:27:
10:28:
10:28:






59
01
03



	 =:—===:===:= =====:::==:::::: 	
 Element:  Ni     Seq.  No.:  42
 Sample  ID: ccb
                                   AS Loc.
                                                  Date:  02/10/2006
 Repl
  #
  1
  2
  3
 Mean:
 SD  :
 %RSD:
SampleConc
mg/L
  0.0176
  0.0160
 -0.0058
  0.0093
  0.0131
   141.4
StndConc
mg/L
 0.0176
 0.0160
-0.0058
 0.0093
 0.0131
  141.4
BlnkCorr
 Signal
  0.001
  0.001
  0.000
  0.000
  0.000
 141.42
Peak
Area
0.099
0.099
0.098
Bkgnd    Time
Area
 0.006  10:28:26
 0.006  10:28:28
 0.007  10:28:30
                     No.:  43
                                   AS Loc.
                                                  Date: 02/10/2006
hJcu.LL£^-i- ^-
Repl
#
i
J-
0
£*
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2 . 192
2 . 213
2.199
2.201
0.0111
0.50
StndConc
mg/L
2.192
2.213
2.199
2.201
0.0111
0.50
BlnkCorr Peak
Signal Area
0.081 0.179
0.082 0.180
0.081 0.179
0.082
0.000
0.50
Bkgnd Time
Area
0.006 10:28:47
0.007 10:28:49
0.007 10:28:52



                                            Page 13

-------
Element: Ni    Seq. No.: 44
                                  AS LOG.
                                                 Date: 02/10/2006
Repl
#
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0. 0107
-0.0087
0.0010
-0.0061
0.0063
102.3
StndConc
mg/L
-0.0107
-0.0087
0.0010
-0.0061
0.0063
102.3
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.000 0.098 0.007 10:29:21
0 000 0.098 0.007 10:29:23
0.000 0.098 0.007 10:29:26
0.000
0.000
102.32
                    No.: 45
                                  AS LOG.
                                                  Date:  02/10/2006
Repl
#
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.7790
0.
0.
0.
0.

2898
2819
2836
0056
1.98
StndConc
mg/L
0.2790
0
0
0
0

.2898
.2819
.2836
.0056
1.98
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.010 0.108 0.007 10:29:45
0
0
0
0

Oil 0.109 0.007 10:29:4/
.010 0.108 0.007 10:29:49
.011
.000
1.98
 Element:  Ni     Seq.  No.:  46
                                   AS LOG.
                                                  Date:  02/10/2006
Repl
#
1
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0042
n nn4 Q
-0.0055
-0.0049
0.0006
13.01
StndConc
mg/L
-0.0042
0 0049
-0.0055
-0.0049
0.0006
13.01
BlnkCorr
Signal
0.000
0. 000
0.000
0.000
0.000
13.01
Peak
Area
0.098
0.098
0.098
Bkgnd
Area
0.007
0.007
0.007
Time
10:30:
10:30:
10:30:
10
12
14
 Element:  Ni    Seq.  No.:  47
                                   AS LOG.
                                                  Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0812
0. 0508
0.0508
0.0609
0.0175
28.73
StndConc
mg/L
0.0812
0.0508
0.0508
0.0609
0.0175
28.73
BlnkCorr Peak
Signal Area
0.003 0.101
0.002 0.100
0.002 0.100
0.002
0.001
28.73
Bkgnd Time
Area
0.006 10:30:34
0.007 10:30:36
0.007 10:30:39



                                            Page 14

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0025

3 0.0052
Mean: 0.0057
SD : 0.0035
%RSD: 61.08
Element: Ni Seq.
Sample ID: 218-4
Repl SampleConc
# mg/L
1 0.6766
2 0.6721
3 0.6801
Mean: 0.6763
SD : 0.0040
%RSD: 0.59
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0073
o n m 1 1
3 -0.0044
Mean: -0.0076
SD : 0.0033
%RSD: 44.18
Element: Ni Seq
Sample ID: 218-5
Repl SampleConc
# mg/L
1 0.1360
2 0.1481
3 0.1467
Mean: 0.1436
SD : 0.0066
%RSD: 4.60
No. : 48

StndConc
mg/L
0.0025
0.0093
0.0052
0.0057
0.0035
61.08
No.: 49

StndConc
mg/L
0.6766
0.6721
0.6801
0.6763
0.0040
0.59
. No. : 50

StndConc
mg/L
-0.0073
-0 0111
-0.0044
-0.0076
0.0033
44.18
. No. : 51

StndConc
mg/L
0.1360
0.1481
0.1467
0.1436
0.0066
4.60
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
61.08
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.025 0.123
0.025 0.123
0.025 0.123
0.025
0.000
0.59
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
44.18
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.103
0.005 0.103
0.005 0.103
0.005
0.000
4.60
Date: 02/10/2006

Bkgnd Time
Area
0.007 10:30:58
0.006 10:31:00
0.007 10:31:02



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:31:19
0.007 10:31:22
0.007 10:31:24



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:31:46
0.007 10:31:48
0.007 10:31:51



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:32:10
0.006 10:32:12
0.006 10:32:14



Page 15

-------

Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0095
2 0.0095
3 0.0131
Mean: 0.0107
SD : 0.0021
%RSD: 19.46
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0035
2 0.0037
3 -0.0035
Mean: 0.0013
SD : 0.0041
%RSD: 325.9
Element: Ni Seq
Sample ID: ccv-0.2!
Repl SampleConc
# mg/L
1 0.2678
2 0.2337
3 0.2443
Mean: 0.2486
SD : 0.0175
%RSD: 7.02
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0202
2 -0.0019
3 0.0081
Mean: 0.0088
SD : 0.0110
%RSD: 125.5

No.: 52

StndConc
mg/L
0.0095
0.0095
0.0131
0.0107
0.0021
19.46
No.: 53

StndConc
mg/L
0.0035
0.0037
-0.0035
0.0013
0.0041
325.9
. No. : 54

StndConc
mg/L
0.2678
0.2443
0.2486
0.0175
7.02
. No.: 55

StndConc
mg/L
0.0202
-0.0019
0.0081
0.0088
0.0110
125.5

AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
19.46
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
325.87
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.010 0.108
0 009 0 107
0.009 0.107
0.009
0.001
7.02
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.099
0.000 0.098
0.000 0.098
0.000
0.000
125.54

Date: 02/10/2006

Bkgnd Time
Area
0.007 10:32:39
0.007 10:32:41
0.006 10:32:44



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:32:54
0.007 10:32:56
0.007 10:32:59



Date: 02/10/2006
	
Bkgnd Time
Area
0.006 10:33:22
0.007 10:33:25
0.007 10:33:27



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:33:57
0.007 10:33:59
0.007 10:34:01



Page 16

-------
              Appendix E - 2




Laboratory QA/QC Data for Stack Testing Samples

-------
Element : Ni Seq
Sample ID: Irb

Repl SampleConc
# mg/L
1 0.0582
2 0.0577
3 0.0534
Mean: 0.0564
SD : 0.0027
BRSD: 4.73
Element : Ni Seq
Sample ID: ccb

Repl SampleConc
# mg/L
1 0.0055
2 0.0156
3 -0.0094
Mean: 0.0039
SD : 0.0126
%RSD: 322.8
Element: Ni Seq
Sample ID: Ifb

Repl SampleConc
# mg/L
1 2.127
2 2.101
3 2.122
Mean: 2.117
SD : 0.0136
%RSD: 0.64
Element: Ni Seq.
Sample ID: ccb

Repl SampleConc
# mg/L
1 0.0115
2 0.0158
3 0.0025
Mean: 0.0099
SD : 0.0068
%RSD: 68.64
. No. : 56

StndConc
mg/L
0.0582
0.0577
0.0534
0.0564
0.0027
4.73
. No. : 57

StndConc
mg/L
0.0055
0.0156
-0.0094
0.0039
0.0126
322.8
. No. : 58

StndConc
mg/L
2 .127
2 .101
2 .122
2 .117
0.0136
0.64
. No. : 59

StndConc
mg/L
0.0115
0.0158
0.0025
0.0099
0.0068
68.64
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
4 .73
AS

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
322.78
AS

BlnkCorr
Signal
0.079
0.078
0.079
0.078
0.001
0.64
AS

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
68.64
Loc. : 	

: Peak
Area
0.100
0.100
0.100



Loc. : 	

Peak
Area
0.098
0.099
0.098



Loc. : 	

Peak
Area
0.177
0.176
0.177



Loc. : 	

Peak
Area
0.098
0.099
0.098



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:34:20
0.007 10:34:23
0.007 10:34:25



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:34:43
0.006 10:34:45
0.007 10:34:47



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:35:00
0.007 10:35:02
0.007 10:35:05



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:35:19
0.006 10:35:22
0.007 10:35:24




-------
Element: Ni Seq
Sample ID: 072-1

Repl
#
1
2
3
Mean:
3D :
%RSD:

SampleConc
mg/L
0.0622
0.0656
0.0624
0.0634
0.0019
3.04
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0017
-0.0028
0.0007
-0.0013
0.0018
138.8
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 072-2
SampleConc
mg/L
0.2678
0.2550
0.2640
0.2623
0.0066
2 .51
Element: Ni Seq.
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
0.0005
0.0140
0.0050
0.0065
0.0069
106.1
. No. : 60
StndConc
mg/L
0.0622
0.0656
0.0624
0.0634
0.0019
3.04
. No. : 61

StndConc
mg/L
-0.0017
-0.0028
0.0007
-0.0013
0.0018
138.8
. No. : 62

StndConc
mg/L
0.2678
0.2550
0.2640
0.2623
0.0066
2 .51
. No. : 63

StndConc
mg/L
0.0005
0.0140
0.0050
0.0065
0.0069
106.1
AS
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
3.04
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
138.75
Loc. : 	
Peak
Area
0.100
0.100
0.100



Loc. : 	

Peak
Area
0.098
0 .098
0.098



AS LOG. : 	

BlnkCorr
Signal
0.010
0.009
0.010
0.010
0.000
2.51

Peak
Area
0 .108
0.107
0.108



AS Loc. : 	

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
106.08

Peak
Area
0.098
0.098
0.098



Date:
Bkgnd
Area
0.007
0.007
0 .007



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



02/10/2006
Time

10:35:
10:35:
10:35:





48
51
53



02/10/2006

Time

10:36:
10:36:
10:36:






12
14
16



02/10/2006

Time

10:36:
10:36:
10:36:






34
36
38



Date: 02/10/2006

Bkgnd
Area
0.007
0.006
0.007




Time

10:36:
10:37:
10:37:






58
01
03



Page 18

-------
Element: Ni Seq.
Sample ID: 072-3

Repl SampleConc
# mg/L
1 0.0833
2 0.0761
3 0.0990
Mean: 0.0862
SD : 0.0117
%RSD: 13.60
Element: Ni Seq.
Sample ID : ccb
Repl SampleConc
# mg/L
1 -0.0010
2 -0.0071
3 -0.0004
Mean: -0.0028
SD : 0.0037
%RSD: 131.2
Element: Ni Seq.
Sample ID: 072-4

Repl SampleConc
ft mg/L
1 2.339
2 2.365
3 2.369
Mean: 2.357
SD : 0.0163
%RSD: 0.69
Element: Ni Seq.
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0066
2 -0.0051
3 0.0099
Mean: -0.0006
SD : 0.0091
%RSD: 1512
No. : 64


StndConc
mg/L
0.0833
0.0761
0.0990
0.0862
0.0117
13 .60
No. : 65

StndConc
mg/L
-0.0010
-0.0071
-0.0004
-0.0028
0.0037
131.2
No . : 66


StndConc
mg/L
2.339
2 .365
2.369
2 .357
0.0163
0.69
No. : 67


StndConc
mg/L
-0.0066
-0.0051
0.0099
-0.0006
0.0091
1512
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.003 0.101
0 . 003 0 .101
0.004 0.102
0.003
0.000
13 .60
AS Loc. : 	

BlnkCorr Peak
Signal Area
0 . 000 0 .098
0.000 0.098
0.000 0.098
0 .000
0.000
131.18
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.087 0.185
0.088 0.186
0.088 0.186
0.087
0.001
0.69
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
1511.65
Date: 02/10/2006


Bkgnd Time
Area
0.007 10:37:21
0.007 10:37:23
0.006 10:37:25



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:37:44
0.007 10:37:47
0.007 10:37:49



Date: 02/10/2006


Bkgnd Time
Area
0.007 10:38:07
0.007 10:38:09
0.007 10:38:11



Date: 02/10/2006


Bkgnd Time
Area
0.007 10:38:32
0.007 10.-.38.-34
0.006 10:38:36



Page 19

-------
Element: Ni Seq.
Sample ID: 072-5

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.1799
0.1817
0.1761
0.1792
0.0029
1.59
Element: Ni Seq.
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID : ccb

SampleConc
mg/L
-0.0199
-0.0268
-0.0069
-0.0179
0.0101
56.43
: Ni Seq .
ID: ccb
SampleConc
mg/L
-0.0177
-0.0264
-0.0264
-0.0235
0.0050
21.26
: Ni Seq.
ID: ccv-1
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.9524
0.9413
0.9532
0.9490
0.0067
0.70
. No . : 68
StndConc
mg/L
0.1799
0.1817
0.1761
0.1792
0.0029
1.59
No. : 69

StndConc
mg/L
-0.0199
-0.0268
-0.0069
-0.0179
0.0101
56.43
No.: 70

StndConc
mg/L
-0.0177
-0.0264
-0.0264
-0.0235
0.0050
21.26
No. : 71

StndConc
mg/L
0.9524
0.9413
0.9532
0.9490
0.0067
0.70
AS
Loc. : 	
BlnkCorr Peak
Signal
0.007
0.007
0.007
0.007
0.000
1.59
AS

BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.000
56.43
AS

BlnkCorr
Signal
-0.001
-0.001
-0 .001
-0.001
0.000
21.26
AS

BlnkCorr
Signal
0.035
0.035
0.035
0.035
0.000
0.70
Area
0 .105
0.105
0.104



Loc. : 	

Peak
Area
0.097
0.097
0.098



Loc. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	

Peak
Area
0.133
0 .133
0.133



Date:
Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0 .007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



02/10/2006
Time

10:38:
10:38:
10:38:





51
53
55



02/10/2006

Time

10:39:
10:39:
10:39:






18
21
23



02/10/2006

Time

10:39:
10:39:
10:39:






45
47
49



02/10/2006

Time

10:41:
10:41:
10:41:






17
19
21



Page 20

-------
Element: Ni Seq. No.: 72
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 0.0007 0.0007
2 -0.0042 -0.0042
3 -0.0136 -0.0136
Mean: -0.0057 -0.0057
SD : 0.0072 0.0072
%RSD: 126.8 126.8
Element: Ni Seq. No.: 73
Sample ID: Irb

Repl SampleConc StndConc
# mg/L mg/L
1 0.0070 0.0070
2 0.0279 0.0279
3 0.0335 0.0335
Mean: 0.0228 0.0228
SD : 0.0140 0.0140
%RSD: 61.34 61.34
Element: Ni Seq. No.: 74
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0051 -0.0051
2 -0.0022 -0.0022
3 -0.0067 -0.0067
Mean: -0.0047 -0.0047
SD : 0.0023 0.0023
%RSD: 48.70 48.70
Element: Ni Seq. No.: 75
Sample ID: Ifb
Repl SampleConc StndConc
# mg/L mg/L
1 1.071 1.071
2 1.079 1.079
3 1 . 077 1 . 077
Mean: 1.076 1.076
SD : 0.0041 0.0041
%RSD: 0.38 0.38
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
-0.001 0.097
0.000
0.000
126.80
AS Loc, : 	


BlnkCorr Peak
Signal Area
0. 000 0 . 098
0.001 0.099
0.001 0.099
0.001
0.001
61.34
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.000 0.098
0.000 0.098
0.000
0.000
48.70
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.040 0.138
0.040 0.138
0.040 0.138
0.040
0.000
0.38
Date: 02/10/2006


Bkgnd Time
Area
0.006 10:42:59
0.007 10:43:01
0.007 10:43:04



Date: 02/10/2006


Bkgnd Time
Area
0.007 10:43:18
0.007 10:43:20
0.006 10:43:22



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:43:37
0.007 10:43:39
0.007 10:43:41



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:43:55
0.007 10:43:57
0.007 10:43:59




-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
BRSD:
:: Ni Seq
ID: ccb

SampleConc
mg/L
0.0138
-0 .0013
0.0028
0.0051
0.0078
153.2
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
i
2
3
Mean:
SD :
%RSD:
ID: 074-8
SampleConc
mg/L
0.0568
0.0573
0.0595
0.0579
0.0014
2.48
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0387
-0.0199
-0.0255
-0.0280
0.0096
34 .37
: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0129
-0.0342
-0.0313
-0.0175
0.0264
150.8
. No. : 76
StndConc
mg/L
0.0138
-0.0013
0.0028
0.0051
0.0078
153.2
. No. : 77

StndConc
mg/L
0.0568
0.0573
0.0595
0.0579
0.0014
2.48
. No.: 78

StndConc
mg/L
-0.0387
-0.0199
-0.0255
-0.0280
0.0096
34.37
. No. : 79

StndConc
mg/L
0.0129
-0.0342
-0.0313
-0.0175
0.0264
150.8
AS
BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
153.21
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
2 .48
Loc. : 	
Peak
Area
0.098
0.098
0.098



Loc. : 	

Peak
Area
0.100
0 .100
0.100



AS Loc. : 	

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
34.37

Peak
Area
0.097
0.097
0.097



AS Loc. : 	

BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.001
150.81

Peak
Area
0.098
0 .097
0.097



Date: 02/10/2006
Bkgnd Time
Area
0.006 10:44:20
0.006 10:44:22
0.007 10:44:24



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:44:40
0.007 10:44:42
0.007 10:44:45



Date: 02/10/2006

Bkgnd Time
Area
0.007 10:52:21
0.007 10:52:23
0.007 10:52:25



Date: 02/10/2006

Bkgnd Time
Area
0.005 10:52:34
0.007 10:52:36
0.007 10:52:38



Page 22

-------
Element: Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: Ifm

SampleConc
mg/L
1.115
1.109
1.116
1.113
0.0039
0.35
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
ID: ccb
SampleConc
mg/L
0.0045
-0.0253
-0.0035
-0.0081
0.0154
189.9
: Ni Seq
ID: dup Ifm

SampleConc
mg/L
1.025
1.024
1.040
1.030
0.0088
0.86
: Ni Seq.
ID: ccb

SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
-0.0091
-0.0304
-0.0197
-0.0197
0.0106
53.96
. No. : 80

StndConc
mg/L
1.115
1.109
1.116
1.113
0.0039
0.35
. No. : 81

StndConc
mg/L
0.0045
-0.0253
-0.0035
-0.0081
0.0154
189.9
. No. : 82

StndConc
mg/L
1.025
1.024
1.040
1.030
0.0088
0.86
. No. : 83

StndConc
mg/L
-0.0091
-0.0304
-0.0197
-0.0197
0.0106
53.96
AS

BlnkCorr
Signal
0.041
0.041
0.041
0.041
0.000
0.35
AS

BlnkCorr
Signal
0.000
-0.001
0.000
0.000
0.001
189.87
AS

BlnkCorr
Signal
0.038
0.038
0.039
0.038
0.000
0.86
Loc. : 	

Peak
Area
0.139
0.139
0.139



Loc. : 	

Peak
Area
0.098
0.097
0.098



Loc. : 	

Peak
Area
0.136
0.136
0.136



AS Loc. : 	

BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
53.96

Peak
Area
0.098
0.097
0.097



Date:

Bkgnd
Area
0.007
0.007
02/10/2006

Time

10:52:
10:52:
0.007 10:53:



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.006



Date :

Bkgnd
Area
0.006
0.007
0.007









55
58
00



02/10/2006

Time

10:53:
10:53:
10:53:






13
15
17



02/10/2006

Time

10:53:
10:53:
10:53:






36
38
40



02/10/2006

Time

10:53:
10:53:
10:53:






54
56
58




-------
Element: Ni Seq
Sample ID: ser
Repl SarapleConc
# mg/L
1 0 , ZZ^d
2 0 i ZXSX
3 0.2360
Mean: 0.2262
SE1 : 0.0105
%RSD: 4.65
Element: Ni Seq
Sample ID: ccb
Repl SarapleConc
# mg/L
1 -0.0118
Z 0,0198
3 0.0037
Mean: 0,0039
Se ; 0-0158
%RSD: 403.9
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
•L -0.0205
Z -0.0187
3 -0 , Oil 9
Mean: -0.0190
se : 0,0013
% ~ s e> 6 ,8S
Element: Ni Seq
Sample e : ccv-0.5
Repl SampleConc
# mg/L
1 0.5081
2 0.5158
3 0.5046
Mean: 0.5095
SE1 : 0.0057
%RSD: 1.13
. No. : 84

StndConc
mg/L
0.2274
0.2151
0.2360
0.2262
0.0105
4.65
. No. : 85

StndConc
mg/L
-0,0118
0,0198
0.0037
0.0039
0.0158
403.9
. No. : 86

StndConc
mg/L
-o,ozos
-0.0187
-0.0179
-0. OT90
0.0013
6 ,8S
. No. : 87

StndConc
mg/L
0.5081
0,5158
0.5046
0.5095
0.0057
1.13
AS Loc. : 	

BlnkCorr Peak
Signal Area
0,008 0.106
0,008 0,106
0,009 0.107
0,008
0,000
4.65
AS Loc. : 	

BlnkCorr Peak
Signal Area
0,000 0,098
0,OOT 0,099
0,000 0,098
0,000
0.001
403.87
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.097
-0,001, 0.097
-0,001 0,091
- 0 , 001,
0.000
6,85
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.019 0.117
0,OT9 0,117
0.019 0.117
0,0 19
0.000
1.13
Date: 02/10/2006

Bkgnd Time
Area
0,006 10:54:13
0,001 10:54:15
0,001 10:54:17



Date: 02/10/2006

Bkgnd Time
Area
0,001 10:57:50
0.006 10:57:52
0,001 10:57:55



Date: 02/10/2006

Bkgnd Time
Area
0,001 10:53:02
0.007 10:58:05
0,001 10:58:07



Date: 02/10/2006

Bkgnd Time
Area
0,001 10:58:32
0,001 10:58:34
0,001 10:58:36




-------
Element : Ni Seq
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0177
2 -0.0051
3 -0.0158
Mean: -0.0129
SD : 0.0068
%RSD: 52.77
Element : Ni Seq
Sample ID: 074-9

Repl SampleConc
# mg/L
1 0.0411
2 0.0310
3 0.0268
Mean: 0.0330
SD : 0.0073
%RSD: 22.24
Element: Ni Seq.
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0197
2 -0.0183
3 -0.0333
Mean: -0.0238
SD : 0.0083
%RSD: 34.77
Element: Ni Seq.
Sample ID: 074-10

Repl SampleConc
# mg/L
1 0.0582
2 0.0570
3 0.0584
Mean: 0.0579
SD : 0.0008
%RSD: 1.36
. No. : 88


StndConc
mg/L
-0. 0177
-0.0051
-0.0158
-0.0129
0.0068
52.77
. No. : 89


StndConc
mg/L
0.0411
0.0310
0.0268
0.0330
0.0073
22.24
. No. : 90


StndConc
mg/L
-0.0197
-0.0183
-0.0333
-0.0238
0.0083
34 .77
No. : 91


StndConc
mg/L
0.0582
0.0570
0.0584
0.0579
0.0008
1.36
AS Loc. : 	


BlnkCorr Peak
Signal Area
-0.001 0.097
0.000 0.098
-0.001 0.097
0.000
0.000
52.77
AS Loc. : 	


BlnkCorr Peak
Signal Area
0 . 002 0 . 099
0.001 0.099
0.001 0.099
0.001
0.000
22.24
AS Loc. : 	


BlnkCorr Peak
Signal Area
-0.001 0.097
-0.001 0.097
-0.001 0.097
-0.001
0.000
34 .77
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.002 0.100
0.002 0.100
0.002 0.100
0.002
0.000
1.36
Date :


Bkgnd
Area
0.007
0.006
0.007



Date :


Bkgnd
Area
0.007
0.007
0.007



Date :


Bkgnd
Area
0.007
0.007
0.007



Date : '


Bkgnd
Area
0.007
0.007
0.007



02/10/2006


Time

10:58:57
10:59:00
10:59:02



02/10/2006


Time

10:59:23
10:59:25
10:59:27



02/10/2006


Time

10:59:47
10:59:49
10:59:51



02/10/2006


Time

11:00:09
11:00:11
11:00:13




-------
 Element:  Ni     Seq. No.:  92
 Sample  ID: ccb
AS Loc.
Date: 02/10/2006

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0099
-0.0170
-0.0170
-0.0081
0.0155
192.6
StndConc
mg/L
0.0099
-0.0170
-0.0170
-0.0081
0.0155
192.6
BlnkCorr
Signal
0.
-0.
-0.
0.
0.
192
000
001
001
000
001
.59
Peak
Area
0.
0.
0.



.098
.097
.097



Bkgnd
Time
Area
0
0.
0.



.006
.007
.007



11
11
11



:00:
:00:
:00:



34
36
38



 Element: Ni     Seq. No.:  93
 Sample  ID: 074-11
AS Loc.
Date: 02/10/2006

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0227
0.0342
0.0364
0.0311
0.0074
23.71

StndConc
mg/L
0.0227
0.0342
0.0364
0.0311
0.0074
23.71

BlnkCorr Peak
Signal Area
0.001 0.099
0.001 0.099
0.001 0.099
0.001
0.000
23.71

Bkgnd Time
Area
0.007 11:00:54
0.007 11:00:57
0.007 11:00:59



Element: Ni    Seq. No.: 94
Sample ID: ccb
AS Loc.
Date: 02/10/2006

Repl
#
1
2
3
Mean:
SD :
%RSD:


SampleConc
mg/L
-0
-0
-0
-0
0

.0455
.0259
.0419
.0378
.0105
27.72
St
ndConc
mg/L
-0
-0
-0
-0
0

.0455
.0259
.0419
.0378
.0105
27.72
BlnkCorr
Signal
-0.
-0.
-0.
-0.
0.
27
002
001
002
001
000
.72
Peak Bkgnd Time
Area Area
0.096 0.007 11:01:16
0.097 0.007 11:01:18
0.096 0.007 11:01:20



Element: Ni    Seq. No.: 95
Sample ID: Sample
AS Loc.
Date:  02/10/2006
Repl   SampleConc  StndConc  BlnkCorr   Peak
 #     mg/L        mg/L       Signal    Area
 1      -0.0309    -0.0309    -0.001    0.097
Auto-zero performed.
               Bkgnd    Time
               Area
                0.007  11:01:45
Element: Ni    Seq. No.: 96
Sample ID:  ccb
AS Loc.
Date: 02/10/2006
~~
Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
-0.0173
-0.0009
-0.0153
-0.0112
0.0090
80.11
StndConc
mg/L
-0.0173
-0.0009
-0.0153
-0.0112
0.0090
80.11
BlnkCorr
Signal
-o,
0.
-0.
0.
0.
80
001
000
001
000
000
.11
Peak
Area
0.
0.
0.



.096
.097
.096



Bkgnd
Time
Area
0.
0.
0.



.007
.007
.007



11:
11:
11:



02:
02:
02:



07
09
11




-------
Element : Ni Seq
Sample ID: 074-12

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0670
0.0644
0.0754
0.0690
0.0058
8.36
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
0.0000
0.0061
0.0042
0.0034
0.0031
91.31
: Ni Seq.
ID: 074-13

SampleConc
mg/L
0.0958
0.1032
0.1032
0.1008
0.0043
4 .24
Element: Ni Seq.
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
-0.0152
0.0029
0.0152
0.0010
0.0153
1584
. No. : 97
StndConc
mg/L
0.0670
0.0644
0.0754
0.0690
0.0058
8.36
. No.: 98

StndConc
mg/L
0.0000
0.0061
0.0042
0.0034
0.0031
91.31
. No. : 99

StndConc
mg/L
0.0958
0.1032
0.1032
0.1008
0.0043
4.24
No. : 100

StndConc
ing/L
-0.0152
0.0029
0.0152
0.0010
0.0153
1584
AS
BlnkCorr
Signal
0.002
0.002
0.003
0.003
0.000
8.36
AS

BlnkCorr
S ignal
0.000
0.000
0.000
0.000
0.000
91.31
AS

BlnkCorr
Signal
0.004
0.004
0.004
0.004
0.000
4.24
Loc . : 	
Peak
Area
0.099
0.099
0.100



Loc. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	

Peak
Area
0.100
0.101
0.101



AS Loc. : 	

BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
1584.50

Peak
Area
0.096
0.097
0.097



Date:
Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
02/10/2006
Time

11:02:
11:02:
11:02:





36
38
41



02/10/2006

Time

0.007 11:03:
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



11:03:
11:03:






07
09
11



02/10/2006

Time

11:03:
11:03:
11:03:






26
28
30



02/10/2006

Time

11:03:
11:03:
11:03:






50
52
54




-------
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 074-14

SampleConc
mg/L
0.0729
0.0662
0.0861
0.0751
0.0101
13 .46
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
0.0011
-0.0042
-0.0126
-0.0052
0.0069
132 .3
: Ni Seq.
ID: ccb

SampleConc
mg/L
-0.0061
-0.0022
0.0381
0.0099
0.0245
246 .4
: Ni Seq.
ID: ccv-2

SampleConc
mg/L
2 .106
2.062
2.087
2.085
0.0216
1.04
. No. : 101

StndConc
mg/L
0.0729
0.0662
0.0861
0.0751
0.0101
13.46
. No. : 102

StndConc
mg/L
0.0011
-0.0042
-0.0126
-0.0052
0.0069
132 .3
. No. : 103

StndConc
mg/L
-0.0061
-0.0022
0.0381
0.0099
0.0245
246 .4
. No. : 104

StndConc
mg/L
2.106
2.062
2.087
2.085
0.0216
1.04
AS

BlnkCorr
Signal
0.003
0.002
0.003
0.003
0.000
13 .46
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
132.25
Loc . : 	

Peak
Area
0.100
0.099
0.100



Loc. : 	

Peak
Area
0.097
0.097
0.096



AS Loc. : 	

BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
246 .45

Peak
Area
0.097
0.097
0.098



AS Loc. : 	

BlnkCorr
Signal
0.078
0.076
0.077
0 . 077
0.001
1.04

Peak
Area
0.175
0.173
0.174



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.006



02/10/2006

Time

11:04:
11:04:
11:04:






25
27
29



02/10/2006

Time

11:04:
11:05:
11:05:






58
00
02



02/10/2006

Time

11:05:
11:05:
11:05:






35
37
40



Date: 02/10/2006

Bkgnd
Area
0.007
0.007
0.007




Time

11:06:
11:06:
11:06:






46
48
50



Page 28

-------
Elemeni
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
;: Ni Seq
ID: ccb

SampleConc
mg/L
0.0038
0.0002
-0.0004
0.0012
0.0023
187.5
;: Ni Seq.
ID: Irb

SampleConc
mg/L
0.0309
0.0150
0.0301
0.0253
0.0090
35.41
:: Ni Seq.
ID: ccb

SampleConc
mg/L
0.0067
0.0220
0.0269
0.0185
0.0106
56.93
: Ni Seq.
ID: Ifb

SampleConc
mg/L
0.5973
0.5800
0.5991
0.5921
0.0106
1.78
. No. : 105


StndConc
mg/L
0.0038
0.0002
-0.0004
0.0012
0.0023
187.5
. No.: 106


StndConc
mg/L
0.0309
0.0150
0.0301
0.0253
0.0090
35.41
No.: 107


StndConc
mg/L
0.0067
0.0220
0.0269
0.0185
0.0106
56.93
No. : 108


StndConc
mg/L
0.5973
0.5800
0.5991
0.5921
0.0106
1.78
AS


BlnkCori
Signal
0.000
0.000
0.000
0.000
0.000
187.55
AS


BlnkCorz
Signal
0.001
0.001
0.001
0.001
0.000
35.41
AS


BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
56.93
AS


BlnkCorr
Signal
0.022
0.021
0.022
0.022
0.000
1.78
Loc. : 	


: Peak
Area
0.097
0.097
0.097



Loc. : 	


: Peak
Area
0.098
0.097
0.098



Loc. : 	


Peak
Area
0.097
0.098
0.098



Loc. : 	


Peak
Area
0.119
0.118
0.119



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:07:28
0.007 11:07:30
0.007 11:07:33



Date: 02/10/2006


Bkgnd Time
Area
0.006 11:07:56
0.007 11:07:58
0.007 11:08:00



Date: 02/10/2006


Bkgnd Time
Area
0.006 11:08:41
0.007 11:08:44
0.006 11:08:46



Date: 02/10/2006


Bkgnd Time
Area
0.006 11:09:03
0.007 11:09:05
0.007 11:09:07




-------
Element: Ni    Seq. No.: 109
Sample ID: ccb
AS LOG.
Date: 02/10/2006

Repl
#
1
2
3
Mean:
SD ;
%RSD:

SampleConc
rag/It
0.0202
0.0101
0.0181
0.0161
0.0053
33.00
: StndConc
mg/L
0.0202
0.0101
0.0181
0.0161
0.0053
33.00
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
33
001 0.098
000 0.097
001 0.097
001
000
.00
Bkgnd Time
Area
0.006 11:09:23
0.006 11:09:25
0.006 11:09:27



Element: Ni    Seq. No.: 110
Sample ID: Ifb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:


SampleConc
mg/L
0
0
0
0
0

.6011
.6002
.5978
.5997
.0017
0.28
StndConc
mg/L
0
0
0
0
0

.6011
.6002
.5978
.5997
.0017
0.28
BlnkCorr
Signal
0.022
0.022
0.022
0.022
0.000
0.28
Peak
Area
0.
0.
0.



.119
.119
.119



Bkgnd
Time
Area
0.
0.
0.



.006
.006
.006



11
11
11



:09:
:09:
:09:



46
48
50



Element: Ni    Seq. No.: Ill
Sample ID: ccb
AS LOG.
Date: 02/10/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.0070
.0253
.0079
.0134
.0103
76.58
StndConc
mg/L
-0
-0
-0
-0
0

.0070
.0253
.0079
.0134
.0103
76.58
BlnkCorr Peak
Signal Area
0.
-0.
0.
0.
0.
76
000 0.097
001 0.096
000 0.097
000
000
.58
Bkgnd Time
Area
0 . 007 11: 10: 18
0.007 11:10:20
0.007 11:10:22



Element: Ni    Seq. No.: 112
Sample ID: 074-1+15
AS LOG.
Date: 02/10/2006

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.1152
0.1366
0 .1144
0.1221
0.0126
10.33
StndConc
mg/L
0
0
0
0
0

.1152
.1366
.1144
.1221
.0126
10.33
BlnkCorr
Signal
0.
0.
0.
0.
0.
10
004
005
004
005
000
.33
Peak
Area
0.
0.
0.



101
102
101



Bkgnd
Time
Area
0
0.
0.



.007
.006
.007



11:1
11:1
11:1



0:45
0:47
0:49



                                          Page 30

-------
Element: Ni Seq. No.: 113
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 0.0051 0.0051
2 -0.0013 -0.0013
3 0.0002 0.0002
Mean: 0.0013 0.0013
SD : 0.0033 0.0033
%RSD: 250.1 250.1
Element: Ni Seq. No.: 114
Sample ID: Ifm

Repl SampleConc StndConc
# mg/L mg/L
1 1.179 1.179
2 1.189 1.189
3 1.188 1.188
Mean: 1.185 1.185
SD : 0.0054 0.0054
%RSD: 0.46 0.46
Element: Ni Seq. No.: 115
Sample ID : ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0022 -0.0022
2 -0.0061 -0.0061
3 -0.0144 -0.0144
Mean: -0.0076 -0.0076
SD : 0.0063 0.0063
%RSD: 82.62 82.62
Element: Ni Seq. No.: 116
Sample ID: Ifm dup
Repl SampleConc StndConc
# mg/L mg/L
1 1.173 1.173
2 1.173 1.173
3 1.165 1.165
Mean: 1.170 1.170
SD : 0.0044 0.0044
%RSD: 0.38 0.38
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
250.08
AS


BlnkCorr
Signal
0.044
0. 044
0.044
0. 044
0.000
0.46
AS


BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
82.62
AS

BlnkCorr
Signal
0.043
0.043
0.043
0.043
0.000
0.38
Loc. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	


Peak
Area
0.141
0 . 141
0.141



Loc. : 	


Peak
Area
0.097
0.097
0.096



Loc. : 	

Peak
Area
0.140
0.140
0.140



Date: 02/10/2006

Bkgnd Time
Area
0.006 11:11:23
0.007 11:11:25
0.006 11:11:27



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:11:40
0.006 11:11:43
0.006 11:11:45



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:12:30
0.007 11:12:32
0.007 11:12:34



Date: 02/10/2006

Bkgnd Time
Area
0.007 11:12:57
0.007 11:12:59
0.007 11:13:01




-------
Element : Ni Seq
Sample

Rep I
#
1
2
3
Mean:
SD ;
%RSD:
ID: ccb

SampleConc
mg/L
-0.0170
-0.0193
0.0040
-0.0108
0.0128
119.0
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ser
SampleConc
mg/L
0.2375
0.2289
0.2428
0.2364
0.0070
2.97
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0097
0.0227
-0. 0144
0.0060
0.0189
313.6
: Ni Seq.
ID : ccb

SampleConc
mg/L
-0.0323
-0.0242
-0.0285
-0.0283
0.0041
14.34
.No.: 117

StndConc
mg/L
-0.0170
-0.0193
0.0040
-0.0108
0.0128
119.0
. No. : 118

StndConc
mg/L
0.2375
0.2289
0.2428
0.2364
0.0070
2.97
No. : 119

StndConc
mg/L
0.0097
0.0227
-0.0144
0.0060
0.0189
313.6
No. : 120

StndConc
mg/L
-0.0323
-0.0242
-0.0285
-0.0283
0.0041
14 . 34
AS

BlnkCorr
S ignal
-0.001
-0.001
0.000
0.000
0.000
119.03
AS

BlnkCorr
S ignal
0.009
0.008
0.009
0.009
0.000
2.97
AS

BlnkCorr
S ignal
0.000
0.001
-0.001
0.000
0.001
313.63
Loc. : 	

Peak
Area
0.096
0.096
0.097



Loc. : 	

Peak
Area
0.106
0.105
0.106



Loc. : 	

Peak
Area
0.097
0.098
0.096



AS Loc. : 	

BlnkCorr
S ignal
-0.001
-0.001
-0.001
-0.001
0.000
14 .34

Peak
Area
0.096
0.096
0.096



Date:

Bkgnd
Area
0.007
0.007
0.006



Date:

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.006
0.006
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



02/10/2006

Time

11:13:
11:13:
11:13:






33
35
38



02/10/2006

Time

11:13:
11:13:
11:13:






53
55
57



02/10/2006

Time

11:14:
11:14:
11:14:






11
14
16



02/10/2006

Time

11:14:
11:14:
11:14:






51
53
55




-------
Element: Ni Seq. No. : 121
Sample ID: ccv-0.25

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.2328
0.2453
0.2199
0.2327
0 . 0127
5.47
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ID: ccb

SampleConc
mg/L
-0.0256
-0.0292
-0.0179
-0.0242
0.0058
23.96
: Ni Seq.
ID: ccv-0.1
SampleConc
mg/L
0.0996
0.0917
0.0904
0.0939
0.0050
5.31
: Ni Seq.
ID : ccb

SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
-0.0415
-0.0305
-0.0226
-0.0315
0.0095
30.19
StndConc
mg/L
0.2328
0.2453
0.2199
0.2327
0.0127
5.47
. No. : 122

StndConc
mg/L
-0.0256
-0.0292
-0.0179
-0.0242
0.0058
23.96
No. : 123

StndConc
mg/L
0.0996
0.0917
0.0904
0.0939
0.0050
5.31
No. : 124

StndConc
mg/L
-0.0415
-0.0305
-0.0226
-0.0315
0.0095
30.19
AS
BlnkCorr
S ignal
0.009
0.009
0.008
0.009
0.000
5.47
AS

BlnkCorr
S ignal
-0.001
-0.001
-0.001
-0.001
0.000
23.96
AS

BlnkCorr
S ignal
0.004
0.003
0.003
0.003
0.000
5.31
Loc. : 	
Peak
Area
0.105
0.106
0.105



Loc. : 	

Peak
Area
0.096
0.096
0.096



Loc. : 	

Peak
Area
0.101
0.100
0.100



AS Loc. : 	

BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
30.19

Peak
Area
0.095
0.096
0.096



Date:
Bkgnd
Area
0.006
0.006
0.007



Date :

Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.006
0.007
0.007



Date:

Bkgnd
Area
0.007
0.007
0.007



02/10/2006
Time

11:15:
11:15:
11:15:





15
17
19



02/10/2006

Time

11:15:
11:15:
11:15:






37
39
41



02/10/2006

Time

11:15:
11:15:
11:16:






57
59
01



02/10/2006

Time

11:16:
11:16:
11:16:






15
17
20




-------
Element: Ni Seq. No.: 125
Sample ID : ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0285 -0.0285
2 -0.0227 -0.0227
3 -0.0395 -0.0395
Mean: -0.0303 -0.0303
SD : 0.0085 0.0085
%RSD: 28.18 28.18
Element: Ni Seq. No. : 126
Sample ID: Sample

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0197 -0.0197
Auto- zero performed.
Element: Ni Seq. No. : 127
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0123 -0.0123
2 -0.0020 -0.0020
3 0.0058 0.0058
Mean: -0.0028 -0.0028
SD : 0.0091 0.0091
%RSD: 320.2 320.2
Element: Ni Seq. No. : 128
Sample ID: Sample
Repl SampleConc StndConc
# mg/L mg/L
1 0.0072 0.0072
Auto- zero performed.
Element: Ni Seq. No.: 129
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0106 -0.0106
2 -0.0090 -0.0090
3 -0.0123 -0.0123
Mean: -0.0106 -0.0106
SD : 0.0016 0.0016
%RSD: 15.25 15.25
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.001 0.096
-0.001 0.096
-0.001 0.095
-0.001
0.000
28.18
AS Loc. : 	

BlnkCorr Peak
S ignal Area
-0.001 0.096
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
320.19
AS Loc. : 	
BlnkCorr Peak
Signal Area
0.000 0.096
AS Loc. : 	
BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
15.25
Date: 02/10/2006

Bkgnd Time
Area
0.007 11:16:28
0.007 11:16:30
0.007 11:16:32
Date: 02/10/2006

Bkgnd Time
Area
0.007 11:16:36
Date: 02/10/2006

Bkgnd Time
Area
0.007 11:16:44
0.007 11:16:46
0.007 11:16:48
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:52
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:16:58
0.007 11:17:00
0.007 11:17:02

-------
Element : Ni Seq
Sample ID: ccv-0.1

Repl SampleConc
# mg/L
1 0.1067
2 0.1085
3 0.0893
Mean: 0.1015
SD : 0.0106
%RSD: 10.41
Element : Ni Seq
Sample ID : ccb

Repl SampleConc
# mg/L
1 -0.0125
2 -0.0038
3 -0.0056
Mean: -0.0073
SD : 0.0046
%RSD: 62.79
Element: Ni Seq.
Sample ID: 074-2+K
Repl SampleConc
# mg/L
1 1.411
2 1.386
3 1.397
Mean: 1.398
SD : 0.0126
%RSD: 0.90
Element: Ni Seq.
Sample ID : ccb

Repl SampleConc
# mg/L
1 0.0063
2 0.0179
3 0.0265
Mean: 0.0169
SD : 0.0101
%RSD: 59.99
. No.: 130 AS Loc.: 	


StndConc BlnkCorr Peak
mg/L Signal Area
0.1067 0.004 0.100
0.1085 0.004 0.100
0.0893 0.003 0.100
0.1015 0.004
0.0106 0.000
10.41 10.41
. No. : 131 AS Loc. : 	


StndConc 'BlnkCorr Peak
mg/L Signal Area
-0.0125 0.000 0.096
-0.0038 0.000 0.096
-0.0056 0.000 0.096
-0.0073 0.000
0.0046 0.000
62.79 62.79
. No. : 132 AS Loc. : 	

StndConc BlnkCorr Peak
mg/L Signal Area
1.411 0.052 0.149
1.386 0.051 0.148
1.397 0.052 0.148
1.398 0.052
0.0126 0.000
0.90 0.90
. No. : 133 AS Loc. : 	


StndConc BlnkCorr Peak
mg/L Signal Area
0.0063 0.000 0.097
0.0179 0.001 0.097
0.0265 0.001 0.097
0.0169 0.001
0.0101 0.000
59.99 59.99
Date: 02/10/2006


Bkgnd Time
Area
0.006 11:17:20
0.007 11:17:23
0.007 11:17:25



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:17:39
0.007 11:17:41
0.007 11:17:43



Date: 02/10/2006

Bkgnd Time
Area
0.007 11:17:58
0.007 11:18:01
0.006 11:18:03



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:19:08
0.007 11:19:10
0.006 11:19:12




-------
Element: Ni Seq. No.: 134
Sample ID: 074-3+17

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.2393
0.2307
0.2307
0.2336
0.0050
2.14
Element: Ni Seq.
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
0 . 0217
0.0168
0.0141
0.0175
0.0038
21.94
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
0.2393
0.2307
0.2307
0.2336
0.0050
2.14
. No. : 135

StndConc
mg/L
0.0217
0.0168
0.0141
0.0175
0.0038
21.94
No. : 136
AS
BlnkCorr
S ignal
0.009
0.009
0.009
0.009
0.000
2.14
AS

BlnkCorr
S ignal
0.001
0.001
0.001
0.001
0.000
21.94
Loc. : 	
Peak
Area
0.105
0.105
0.105



Loc. : 	

Peak
Area
0.097
0.097
0.097



AS Loc. : 	
Date:
Bkgnd
Area
02/10/2006
Time

0.007 11:19:
0.007
11:19:
0.007 11:19:



Date:

Bkgnd
Area
0.006
0.007
0.007



Date:





33
35
37



02/10/2006

Time

11:19:
11:19:
11:19:






53
55
57



02/10/2006
ID: 074-4+18
SampleConc
mg/L
0.6003
0.5994
0.6388
0.6129
0.0225
3.67
: Ni Seq.
ID : ccb

SampleConc
mg/L
0.0188
-0.0108
-0.0038
0.0014
0.0155
1118
StndConc
mg/L
0.6003
0.5994
0.6388
0.6129
0.0225
3.67
No. : 137

StndConc
mg/L
0.0188
-0.0108
-0.0038
0.0014
0.0155
1118
BlnkCorr
Signal
0.022
0.022
0.024
0.023
0.001
3.67
Peak
Area
0.119
0.119
0.120



AS Loc. : 	

BlnkCorr
S ignal
0.001
0.000
0.000
0.000
0.001
1117 .51

Peak
Area
0.097
0.096
0.096



Bkgnd
Area
0.007
0.007
0.005



Date:

Bkgnd
Area
0.006
0.007
0.007



Time

11:20:
11:20:
11:20:





13
15
18



02/10/2006

Time

11:20:
11:20:
11:20:






47
49
51



Page 36

-------
Element: Ni Seq. No.: 138
Sample ID: 074-5+19

Repl SampleConc StndConc
# mg/L mg/L
1 0.5594 0.5594
2 0.5527 0.5527
3 0.5651 0.5651
Mean: 0.5591 0.5591
SD : 0.0062 0.0062
%RSD: 1.11 1.11
Element: Ni Seq. No.: 139
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0054 -0.0054
2 -0.0042 -0.0042
3 -0.0020 -0.0020
Mean: -0.0039 -0.0039
SD : 0.0017 0.0017
%RSD: 45.04 45.04
Element: Ni Seq. No.: 140
Sample ID: 074-6+20

Repl SampleConc StndConc
# mg/L mg/L
1 1.212 1.212
2 1.220 1.220
3 1.196 1.196
Mean: 1.209 1.209
SD : 0.0124 0.0124
%RSD: 1.03 1.03
Element: Ni Seq. No.: 141
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0087 -0.0087
2 0.0005 0.0005
3 -0.0013 -0.0013
Mean: -0.0031 -0.0031
SD : 0.0049 0.0049
%RSD: 155.9 155.9
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.021 0.117
0.020 0.117
0.021 0.117
0.021
0.000
1.11
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
45.04
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.045 0.141
0.045 0.142
0.044 0.141
0.045
0.000
1.03
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.096
0.000 0.096
0.000 0.096
0.000
0.000
155.91
Date: 02/10/2006


Bkgnd Time
Area
0.007 11:22:07
0.006 11:22:09
0.007 11:22:12



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:22:29
0.007 11:22:31
0.007 11:22:33



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:22:49
0.007 11:22:51
0.007 11:22:53



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:23:06
0.006 11:23:09
0.007 11:23:11




-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
;: Ni Seq.
ID: 074-7+21
SampleConc
mg/L
0.3496
0.3574
0.3588
0.3553
0.0050
1.39
:: Ni Seq.
ID: ccb

SampleConc
mg/L
0.0081
0.0040
-0.0058
0.0021
0.0071
338.8
: Ni Seq.
ID: ccb

SampleConc
mg/L
0.0070
-0.0108
0.0103
0.0022
0.0114
525.0
: Ni Seq.
ID: ccv-2

SampleConc
mg/L
2.072
2.062
2.100
2.078
0.0199
0.96
No. : 142

StndConc
mg/L
0.3496
0.3574
0.3588
0.3553
0.0050
1.39
No. : 143


StndConc
mg/L
0.0081
0.0040
-0.0058
0.0021
0.0071
338.8
No.: 144


StndConc
mg/L
0.0070
-0.0108
0.0103
0.0022
0.0114
525.0
No. : 145


StndConc
mg/L
2.072
2.062
2.100
2.078
0.0199
0.96
AS

BlnkCorr
Signal
0.013
0.013
0.013
0.013
0.000
1.39
AS


BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
338.80
AS


BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
525.00
AS


BlnkCorr
Signal
0.077
0.076
0.078
0.077
0.001
0.96
Loc. : 	

Peak
Area
0.109
0.110
0.110



Loc. : 	


Peak
Area
0.097
0.097
0.096



Loc. : 	


Peak
Area
0.097
0.096
0.097



Loc. : 	


Peak
Area
0.173
0.173
0.174



Date: 02/10/2006

Bkgnd Time
Area
0.007 11:23:27
0.006 11:23:29
0.006 11:23:31



Date: 02/10/2006


Bkgnd Time
Area
0.006 11:23:48
0.006 11:23:50
0.006 11:23:53



Date: 02/10/2006


Bkgnd Time
Area
0.005 11:25:05
0.006 11:25:07
0.006 11:25:09



Date: 02/10/2006


Bkgnd Time
Area
0.007 11:25:22
0.007 11:25:24
0.006 11:25:26




-------
Element: Ni Seq. No. : 146
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
tng/L
-0
-0
-0
-0
0

.0170
,0283
.0148
.0200
.0073
36.29
StndConc
mg/L
-0
-0
-0
-0
0

.0170
.0283
.0148
.0200
.0073
36.29
AS LOG. : 	
BlnkCorr Peak
Signal Area
-0.
-0.
-0.
-0.
0.
36
001 0.096
001 0.095
001 0.096
001
000
.29
Date: 02/10/2006
Bkgnd Time
Area
0.007 11:25:42
0.007 11:25:44
0.007 11:25:47




-------

1
tM


P rep Method : (check onJy one per page)






ICP/FLAA: -SM 3030 F, EPA 200.7 '82
ICP/FLAA: EPA 200's, SW-846 3010A
ICP/FLAA: EPA 200.7 r4.4
iCP/FLAA: SW-846 3005A
ICP/FLAA: S W-846 301 5A MICROWAVE
GFAA: SM3030E


\


GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9

GFAA: SW-846 3015A (NoHCL) M ICROWAVE
OTHF.R:

OTHER-



MATRIX: (check only one per page)

DRINKING WATER




1


2
3
4
5
6
7
8
9
10
14
12


Set
Init'l
iM-


y














Set
date


Its














Set
time
S1J/&

1.0














Lafa#


 '^f'/V
— 	 •""•'"" — ^"™'n




y
020^7 4
	 , 	 1 	







Smp #


/
a
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L^B •• ,
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loQ loo
LFM DUP  ; — V *^ >-*





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(mis)









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OTHER:



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(mis)

OcJ







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Analyst:



'9^1 L$.>
"




V










Mcr
Vsl#
f
i
A
0'
&
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f{
%
HP
is
(L
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13
i^
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10



Start Date:
S\QA FORMS \FM-041 \R02\LK
                 Page 1 of 1

-------
Prep Method:      (check only one Per
     ICP/FLAA:  SM3030 F, EPA 200.7'82
     1CP/FLAA:  EPA2QO's, SW-8463010A
     ICP/FLAA:  EPA 200.7 r4.4
     ICP/FLAA:  SW-8463005A
     ICP/FLAA:  SW-8463015A MICROWAVE
     OTHER:	-
GFAA: SM 3030 E                    -^
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:	:	
MATRIX:            (check only one per page)

DRINK




1


?
a
4
5
6
7
8
9
10
11
12


Set
Inifl
^

















(ING WATER
Set
date
/rO

rfK
e













Set
time,.
9'6A

-• £)
I


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t
"f 	 : 	








Lab#


.'i ?--• '-'i-~?i'














Smp#


f
n< 3^
3o? ioC,
Mi5 ^^
3^ 1/0









SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER



i




LOT*
^5"«£k
)
£ 	





OTHF.R: 	

Aliquot
(mis)

















«rvb
Final
(mis)
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Analyst:
Start Date:



















Mcr
Vsl#
^
o
>5
^
5"
^
?
?
f











                                                                                                           Page 1 of 1

-------
PROJECT #  2006010214:   METHOD 29 FOR  NICKEL
                                                                 8
9
                                                                                    10
                      11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19



SAMPLE
DESCRPTION
impinger
fitter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger , !>
"filter ; ,
prob&riflse '
RUN ID
Cond. 12:
RUN»1
Cond. 12:
RUN #2
Cond. 12:
RUN«3
BLANK
Cond. 11:
RUN #1
Cond. 11:
RUN 82

Cond. 11:
RUN #3

' MDL
PH
<2.0

<2.Q
<2,0

<2,0
<2.0

<2.0
<2,0

< 2-0
<2.Q

<2.0
<2.Q

<2.0
<2.0

<2.0
, ,


Sample
Fraction
(SF = SF*}
308
1 filter
98.0
316
1 filter
99.0
309
1 filter
98.0
304
1 filter
100.0
312
1 filter
96.0
312
1 filter
99.0
314
1 filter
980
,, 300\ ,
, 1, Wt^r ,
100,0
EVAP.
TO
20
NA
20
20 j
NA
20
20
Nft
20
20
NA
20
20
NA
20
20
NA
20
20
NA
70
'• A
/ S4"
20
REAGENTS
FOR DIG.
HN03 + H202
HF + HNO3
HF * HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 * H202
HF + HNO3
HF + HN03
HNO3 t- H2O2
HF » HNO3
HF + HNO3
HNO3 + H2O2
HF + HN03
HF * HNO3
HNO3 + H2O2
HF * HNO3
HF * MNO3
HNO3 + H2O2
HF + HN03
hF +• HN03
HN03 + H20?.'
HF + HN03 •
'HF*HN05
MICRO-
Dig. BY
8.3.4.2
8.3.12
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8,3.1.2
8.3.1.2
8.3.4.2
8.3.1,2
8.3.1.2
8.3.4 2
8.3.1.2
8.3.1-2
8.3.4.2
8.3.1 .2
8.3.1.2
8,3.4.2
831 2
83 1 2
83,1.2
83l"a'
, 03.13 .
Analytical
Fraction
(AF = AF4
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50-
, w s
Nf mg/L
( Ca1 or Ca2 )
< 0.074
1.792
< 0.074
4.409
< 0.074
1.949
< 0.074
0.170
0.083
1.845
< 0.074
0.522
0.104
0.306
, 0.D75> ,
. •" 3'$^ •
MG NI
IN INITIAL
SAMPLE
0.004
0.179
0.004
0.441
0.004
0.195
0.004
0.017
0.004
0.185
0.004
0.052
0.005
0.031
0,004*
O'.'oos;
TOTAL MG
PER RUN
0.183
0.445
0.199
0.021
0.189
0.056
0.036
0,011
 10   Samples that read 
-------
PROJECT # 2005110324:  METHOD 29 FOR NICKEL
                                                              8
10
11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19



SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filler
probe rinse
impinger
filter
probe rinse
impinger
filter
orobe rinse
impinge^ '•>.
filter •' •'
• probe'rinse" •
RUN ID
Cond. 23:
TEST#1
Cond. 23:
TEST #2
Cond. 23:
TEST #3
BLANK
Cond. 25:
TEST #1
Cond. 25:
TESTS2
Cond. 25:
TEST S3

. MDE •'
C
PH
<2.0

<2.0
<2.0

<2.0
<2.0

<2.Q
•=2.0

<2.0
<2.0

<2.0
<2.0

<2,0
<2,0

<2.0



Sample
Fraction
(SF = SFA)
314
1 filter
97.0
318
1 filter
95.0
320
1 filter
96.0
302
1 filter
100.0
303
1 filter
96.0
299
1 filter
95.0
308
1 filter
98.0
300.;.,
« filter,. '
- '100.0.-:
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
23
";20 ';-
-''NA';
.20 i',;
REAGENTS
FOR DIG.
HNO3 + H2O2
HF * HN03
HF t HN03
HNO3 + H2O2
HF * HNO3
HF + HNO3
HNO3 * H2O2
HF + HN03
HF * HN03
HNO3 + H2O2
HF * HN03
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HN03 * H2O2
HF + HNO3
HF + HNO3
HNO3 * H2O2
HF + HNO3
HF + HNO3
HSl03*H20a
$ff f |JW3'?
-' Hf-1-HNOS '
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1,2
8.3. 1-2
8.3.4 2
8.3.1.2
8.3.1.2
6.3.4.2
8.3.1-2
8.3.1.2
8,3.4.2
8.3.1-2
8.31 2
""-a-,3.4.2
8.3:1,2
. 8,ii.?*
Analytical
Fraction
(AF = AFA)
50
100
50
100
50
100
50
100
50
100
50
100
50
100
• ^m , **
•/io6\/
N! mg/L
( Ca1 or C32 )
0.297
0.617
0.101
0.557
0.083
0.769
< 0.074
0.157
< 0.074
0.258
0.099
0.308
< 0.074
0.326
.-\ 0.075
-,0,075 V
MG Nl
IN INITIAL
SAMPLE
0.015
0.062
, 	 0.005
0.056
0.004
0.077
^ 0.004
0.016
\ 0.004
0.026
0.005
0.031
0.004
0.033
OJ004
0.008-
TOTAL MG
PER RUN
0.077
0.061
0.081
0.019
0.030
0.036
0.036
0,011
 1 °   Samples that read 
-------
QA/QC WORK SHEET for NICKEL
F" AA METHOD SOP MET-040
    5100 AA

  1 CURRENT COPY OF METHOD AVAILABLE IN WIN LAB.
  2 INSTRUMENT SET-UP:
    (For Specific Instrument settings, see current copy of method.)
  Date:_
Analyst: _
2/2/2006
  LK
            (Mg/L)
       IDL= 0.027
      MDL- 0.075
       RL a 0.10
      LDRs 0.10 to s.o
  3 CALIBRATION:
Cal Curve:





Corr. Coef:
Cone
0.25
O.SO .
7.00
2.00
5.00
xxx»«xxx
Abs
0.009
0019
0.036
0.077
0.182

Result
0.248
0.511
0.974
2.097
4.963
0.9996
% Rec.
993
102.2
97.4
104.9
99.3

4 STANDARD TRACEABILITY

QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM

Standard Name, Company, & Lot #
CPIQC-21Lot#05H062
CP1 QC-21 Lot* 05H062
CPIQC-19Lot#05F011

                                         * 0.995)
  s SAMPLE ANALYTICAL RUN
MAT-R1X







M29
M29
*'nf*



M29



M29
M29
M29


M29
M29
M29
M29
M29


M29
M29
M29
M29
M29




M29
SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
LFB
203-1 1
203-10+12
203-23
203-22+24
CCB
CCV
\jj-yo&rt ^2-
W^ SPK
DUP
SER DIL
324-4+6
324-7+9
324-10+12
CCB
CCV
324-13+15
324-16+18
r 324-19+21
214-1+3
214-4+6
CCB
CCV
214-7+9
214-10+12
214-13+15 v/
214-J6+1S
214-19+21
CCB
CCV
LRB
LFB
'324-2
STD CONG
5.00
2.00

0.05
0.10

1.00





0.25
I-I+3
1.0
1.0
2/10




0.50






1.00






2.00

1.00

READING
Mg/L
4.936
2.085
-0.013
0.032
0.068
0-004
1.107
0.074
0.122
0.091
2.176
0.020
0.270
0.644
1.622
1.604
0.340
0.559
0.781
0.157
0.004
0.516
0.247
0.277
0.308
1.786
4.415
-0.026
0.952
1.925
0.157
1.836
0.530
0.305
0.004
2.090
0.068
1.073
0.294
BLK



-0.013
-0.020
-0.020
0,006
0.009
-0.002
0.015
0.005
0.033
0.020
0.027
0.019
0.019
0.026
0.002
0.012
0.000
-0.019
0.004
-0.01 1
-0.031
-0.018
-0.006
0.006
-0.030
-0.026
-0.024
-0,013
-0.009
0.009
-0.001
0.006
0,004
0.007
-0.026
-0.003
RESULT
4.936
2.085
-0.013
0.045
0.089
0.025
1,101
0.065
0.124
0,076
2.171
-0.014
0.251
0.617
1.603
1.585
0.315
0.557
0.769
0.157
0,023
0.512
0,258
0,308
0.326
1.792
4,409
0.004
0.978
1.949
0,170
1.845
0.522
0,306
-0.002
2,086
0.060
1.099
0.297
DILI







1.0
1.0
1.0
1.0


1.0
1.0
1,0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
10




1.0
DIL 2







1.0
t.o
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0




1.0
QC
RESULTS
99
104
-0.013
89
89
0.025
110




-0.014
100

99
11
1.9



0,023
102





0.004
98





-O.D02
104
0.060
115

Mg/L







0.065
0.124
0.076
2.171


0,617



0,557
0,769
0.157


0.258
0.308
0,326
1,792
4,409


1.949
0.170
1.845
0.522
0.306




0.297
REPT
mg/L
I






0.074
0.124
0.076
2.171


0.617



O.SS7
0.769
0.157


0.256
0.308
0.326
1.792
4.409


1.949
0.170
1.845
0.522
0.306




0.297
ICP







	 <«4 H
.ss.^3*/




























                                                                              (95-105%R)

                                                                              (95-105%R)
                                                                              (< MDL j

                                                                              ( 70-130%R }

                                                                              (70-130%R)

                                                                              (-= MOL )

                                                                              ( 80-12Q%R J

                                                                              m
                                                                              (< MDL)

                                                                              (90-110%R)



                                                                              ( 80-120%R)

                                                                              (<10 RPD, IF SA :• 20X MDL)
                                                                              (< MDL 1

                                                                              (90-110%R j
                                                                              (
-------
QA/QC WORK SHEET for NICKEL  p2

F'JVA METHOD SOP MET-040
    5100 AA
  Date:_

Analyst: _
2/2/2006
  LK
5 SAMPLE ANALYTICAL RUN
MAT-RSX





M29
M29
M29
M29



M29
M29
M29
NI29
M29


M28

j
M29
M29


SAMPLE
SPK
DUP
SER OIL
GCB
ccv
324-5
324-8
324-11
324-14
DUP
CCB
CCV
324-17
324-20
214-2
214-5
214-8
CCB
CCV
214-11
DUP
214-14
214-17
214-20
CCB
CCV
STD CONG
1.0
1.0
2(10

0.25






2.00






0.50






0.25
READING
Mg/L
1.246
1.188
0.229
-0.014
0.229
0.087
0.090
0.068
0,072
0.065
-0.009
2.072
0.081
0.057
0.077
0.049
0.060
-0.045
0.471
0.022
0.104
0.049
0.034
0.066
0.009
0.233
BLK
-0.017
0.005
-0.003
0.005
-0.014
-0.014
0.007
0.003
-0.003
-0.039
0.016
-0.009
-0.018
-0.009
0.007
-0.017
0.005
-0.004
-0.045
-0.050
-0.004
-0,035
-0.024
-0.039
0.011
0.009
RESULT
1.263
1.183
0.232
-0.019
0.243
0.101
0.083
0.065
0.074
0.104
-0,025
2.081
0.099
0.066
0,071
0.066
0.056
-0.041
0,516
0.072
0.108
0.083
0.058
0.104
-0.002
0.224
DILI
1.0
1,0
1.0


1.0
1.0
1.0
1,0
1.0


1,0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


OIL 2
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


1.0
1.0
1,0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


QC
RESULTS
97
6.6
8,3
-0.019
97




33.2
-0.025
104

1.4



-0.041
103

4Q.8
158


-0,002
90
Mg/L





0.101
0,083
0.065
0.074



0.099
0.066
0.071
0.066
0.056


0.072

0.083
0.058
0.104



REPT
mq/L





0.101
0.083
0.074
0.074



0.099
0.074
0.074
0.074
0.074


0.074

0,083
O.Q74
0.104



ICP


























                                                                       ( 80-120%R )


                                                                       (<10RPD, 1FSA>20XMDL)
                                                                       (< MDL )


                                                                       (SO-HOWR)
                                                                       (<10RPD. IFSA: 20XMDL)


                                                                       (< MDL }


                                                                       {90-1105'oR )
                                                                        MDL)


                                                                       j 90-110%R)





                                                                       (<10RPD, IF SA>20XMDL)
                                                                        MOL)


                                                                       ( 90-1KW4R }

-------
Method Name: NI
Method Description: Nickel
Date: 02/02/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
Element: Ni Seq. No.: 265
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seg. No.: 266
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
~Mea n :
;D :
%RSD:
Auto- zero performed.
Element: Ni Seq. No. : 267
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
2
3
Mean:
SD :
%RSD:
Eiement: N i

hi^^ '"

Calibration Equation: Zero Intercept:
S lit Width: 0.20 nm
Energy : 7 1
Results Data Set:
AS LOG. : 	
BlnkCorr Peak
S ignal Area
-0.011 0.096
-0.011 0.096
-0.011 0.095
-0.011
0.000
1.39

AS LOG. : 	
BlnkCorr Peak
S ignal Area
0.000 0.096
0.001 0.096
0.001 0.097
0.001
0.001
61.54

AS LOG. : 	
BlnkCorr Peak
S ignal Area
-0.001 0.096
-0.001 0.096
-0.001 0.096
-0.001
0.000
14.29
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:18:41
0.006 10:18:43
0.006 10:18:45




Date: 02/02/2006
Bkgnd Time
Area
0.005 10:18:53
0.006 10:18:55
0.005 10:18:57




Date: 02/02/2006
Bkgnd Time
Area
0.006 10:19:01
0.006 10:19:03
0.006 10:19:05



1 ^

Linear























Auto-zero performed
                                             Page 72

-------
Element: Ni Seq. No.: 268 AS Lo~. : 	
Sample ID: CAL STD

Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.009 0.105
2 0.009 0.105
3 0.009 0.105
Mean: 0.009
SD : 0.000
BRSD: 2.79
Standard number 1 applied. [0.25]
Correlation Coefficient: 0.9985

Element: Ni Seq. No.: 269 AS Loc. : 	
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.018 0.114
2 0.019 0.115
3 0.019 0.115
Mean: 0 . 019
SD : 0.000
BRSD: 1.99
Standard number 2 applied. [0.50]
Correlation Coefficient : 0.9988
Element: Ni Seq. No.: 270 AS Loc.: 	
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.036 0.131
2 0.036 0.132
3 0.036 0.131
Mean: 0 . 036
SD : 0.000
%RSD: 0.44
Standard number 3 applied. [1.00]
Correlation Coefficient : 0.9992
Element: Ni Seq. No.: 271 AS Loc.: 	
Sample ID: cal std 4
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.077 0.172
2 0.076 0.172
3 0.078 0.174
Mean: 0 . 077
SD : 0.001
%RSD: 1.58
Standard number 4 applied. [2.00]
Correlation Coefficient : 0.9996
Date: 02/02/2006

Bkgnd Time
Area
0.006 10:19:28
0.005 10:19:30
0.006 10:19:33
Slope: 0.0371

Date: 02/02/2006
Bkgnd Time
Area
0.006 10:19:58
0.006 10:20:00
0.006 10:20:02
Slope: 0.0370
Date: 02/02/2006
Bkgnd Time
Area
0.006 10:20:22
0.006 10:20:24
0.006 10:20:26
Slope: 0.0368
Date: 02/02/2006
Bkgnd Time
Area
0.005 10:20:46
0.006 10:20:49
0.005 10:20:51
Slope: 0.0367
Page 73

-------
Element:  Ni     Seq.  No.:  272
Sample  ID: cal  std 5
                      A5  Loc.
        Date: 02/02/2006
Repl    SampleConc
  #      mg/L
  1
  2
  3
Mean:
SD   :
%RSD:

«nc StndConc BlnkCorr Peak
mg/L Signal Area
0.182 0.278
0.183 0.279
0.181 0.277
0.182
0.001
0.50
• 5 applied. [5.00]
fficient: 0.9996

Bkgnd Time
Area
0.005 10:21:14
0.005 10:21:16
0.005 10:21:18




Slope: 0.0367
                                               Ni
(B
•e
o
                    0.20
                    Q.1S
                    0.10
                    0.05
                                             Concentration
Calibration data for Ni
       Standard ID
       Calib Blank
         CAL STD
        cal std 2
        cal std 3
        cal std 4
        cal std 5
             Mean Signal
             (Absorbance)
                0.000
                0.009
                0.019
                0.036
                0.077
                0.182
 Entered      Calculated
icentration C
  (mg/L)

   0.25
   0.50
   1.00
   2.00
   5.00
:entratic
(mg/L)
0.000
0.2482
0.5112
0 . 9742
2.097
4.963
>n Standard
Deviat ion
0.0001
0.0003
0.0004
0.0002
0.0012
0.0009

%RSD
14.2878
2.7920
1.9883
0.4437
1.5791
0.4990
     Correlation Coefficient: 0.99961    Slope:
                                      0.03669

-------
Element: Ni Seq. No.: 273 AS
Sample ID: ccv-5

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 4.904 4.904 0.180
2 4.946 4.946 0.181
3 4.959 4.959 0.182
Mean: 4.936 4.936 0.181
SD : 0.0291 0.0291 0.001
%RSD: 0.59 0.59 0.59
Element: Ni Seq. No. : 274 AS
Sample ID: gcs-2

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 2.092 2.092 0.077
2 2.073 2.073 0.076
3 2.091 2.091 0.077
Mean: 2.085 2.085 0.077
SD : 0.0109 0.0109 0.000
%RSD: 0.52 0.52 0.52
Element: Ni Seq. No.: 275 AS
Sample ID: ccb

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0067 -0.0067 0.000
2 -0.0213 -0.0213 -0.001
3 -0.0116 -0.0116 0.000
Mean: -0.0132 -0.0132 0.000
SD : 0.0074 0.0074 0.000
%RSD: 56.26 56.26 56.26
Element: Ni Seq. No.: 276 AS :
Sample ID: era- 0.05

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0464 0.0464 0.002
2 0.0112 0.0112 0.000
3 0.0371 0.0371 0.001
Mean; 0.0315 0.0315 0.001
SD : 0.0182 0.0182 0.001
%RSD: 57.81 57.81 57.81
Loc . : 	


Peak
Area
0.276
0.277
0.278



Loc. : 	


Peak
Area
0.172
0.172
0.172



Loc. : 	


Peak
Area
0.095
0.095
0.095



Loc. : 	


Peak
Area
0.097
0.096
0.097



Date: 02/02/2006


Bkgnd Time
Area
0.005 10:21:32
0.005 10:21:34
0.005 10:21:36



Date: 02/02/2006


Bkgnd Time
Area
0.006 10:22:04
0.007 10:22:06
0.006 10:22:08



Date: 02/02/2006


Bkgnd Time
Area
0.006 10:24:48
0.006 10:24:50
0.006 10:24:52



Date: 02/02/2006


Bkgnd Time
Area
0.006 10:25:22
0.007 10:25:24
0.006 10:25:26



Page 75

-------

Element: Ni Seq. No.: 277 AS
Sample ID: era- 0. 1

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0639 0.0639 0.002
2 0.0732 0.0732 0.003
3 0.0677 0.0677 0.002
Mean: 0.0682 0.0682 0.003
SD : 0.0047 0.0047 0.000
%RSD: 6.85 6.85 6.85
Element: Ni Seq. No.: 278 AS
Sample ID: ccb

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0193 -0.0193 -0.001
2 -0.0328 -0.0328 -0.001
3 -0.0091 -0.0091 0.000
Mean: -0.0204 -0.0204 -0.001
SD : 0.0119 0.0119 0.000
%RSD: 58.39 58.39 58.39
Element: Ni Seq. No.: 279 AS
Sample ID: Irb f+pr

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0026 0.0026 0.000
2 -0.0029 -0.0029 0.000
3 0.0128 0.0128 0.000
Mean: 0,0042 0.0042 0.000
SD : 0.0080 0.0000 0.000
%RSD: 189.8 189.8 189.78
Element: Ni Seq. No.: 280 AS :
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.0092 0.0092 0.000
2 0.0001 0.0001 0.000
3 0.0084 0.0084 0.000
Mean: 0.0059 0.0059 0.000
SD : 0.0051 0.0051 0.000
%RSD: 85.93 85.93 85.93

Loc. : 	

Peak
Area
0.098
0.098
0.098



Loc. : 	

Peak
Area
0.095
0.094
0.095



Loc. : 	

Peak
Area
0.096
0.096
0.096



Loc. : 	
Peak
Area
0,096
0.096
0.096




Date: 02/02/2006

Bkgnd Time
Area
0.007 10:25:50
0.007 10:25:52
0.007 10:25:54



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:26:16
0.007 10:26:18
0.006 10:26:20



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:26:55
0.007 10:26:57
0.007 10:26:59



Date: 02/02/2006
Bkgnd Time
Area
0.005 10:27:47
0.006 10:27:49
0.006 10:27:51



Page 76

-------
Element: Ni Seq. No.: 281
Sample ID: Ifb f+pr

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
1.063
1.093
1.107
1.088
0.0225
2.07
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0096
-0.0503
-0.0373
-0.0324
0.0208
64.12
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 203-11
SampleConc
mg/L
0.0640
0.0774
0.0792
0.0735
0.0083
11.23
Element: Ni Seq,
Sample
Repl
#
1
2
o
J
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0103
0.0088
-0.0045
-0.0020
0.0098
489.3
StndConc
mg/L
1.063
1.093
1.107
1.088
0.0225
2.07
.No.: 282

StndConc
mg/L
-0.0096
-0.0503
-0.0373
-0.0324
0.0208
64.12
. No . : 283

StndConc
mg/L
0.0640
0.0774
0.0792
0.0735
0.0083
11.23
. No. : 284

StndConc
mg/L
-0.0103
0.0088
-0.0045
-0.0020
0.0098
489.3
AS
BlnkCorr
Signal
0.039
0.040
0.041
0.040
0.001
2.07
AS

BlnkCorr
Signal
0.000
-0.002
-0.001
-0.001
0.001
64.12
AS

BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
11.23
Loc. : 	
Peak
Area
0.135
0.136
0.136



Loc. : 	

Peak
Area
0.095
0.094
0.094



Loc* : 	

Peak
Area
0.098
0.098
0.099



AS Loc. : 	

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
489.25

Peak
Area
0.095
0.096
0.095



Date:
Bkgnd
Area
0.007
0.006
0.006



Date:

Bkgnd
Area
0.006
0.008
0.007



Date:

Bkgnd
Area
0.006
0,005
0.005



Date:

Bkgnd
Area
0.006
0.005
0.006



02/02/2006
Time

10:29:10
10:29:12
10:29:14



02/02/2006

Time

10:31:33
10:31:36
10:31:38



02/02/2006

Time

10:32:05
10:32:07
10:32:09



02/02/2006

Time

10:32:26
10:32:28
10:32:30




-------
Element: Ni Seq
. No.: 285
AS
LOG. : 	
Date: 02/02/2006
Sample ID: 203-10+12

Repl SampleConc
# mg/L
1 0.1169
2 0.1113
3 0.1382
Mean: 0.1221
SD : 0.0142
%RSD: 11.65
Element: Ni Seq.
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0295
2 -0.0191
3 -0.0291
Mean: -0.0259
SD : 0,0059
%RSD: 22.78
StndConc
mg/L
0.1169
0.1113
0.1382
0.1221
0.0142
11.65
No.: 286

StndConc
mg/L
-0.0295
-0.0191
-0.0291
-0.0259
0.0059
22.78
Element: Ni Seq. No.: 287
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0534
2 -0.0420
3 -0.0626
Mean: -0.0527
SD : 0.0103
%RSD: 19.58
Element: Ni Seq.
Sample ID: Sample

StndConc
mg/L
-0.0534
-0.0420
-0.0626
-0.0527
0,0103
19.58
No.: 288

BlnkCorr Peak
Signal
0.004
0.004
0.005
0.004
0.001
11.65
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
22.78
AS

BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
19.58
AS

Area
0.100
0.100
0.101



LOG. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.094
0.094
0.093



Loc. : 	

Bkgnd Time
Area
0.006 10:32:50
0.006 10:32:52
0.005 10:32:54



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:33:13
0.006 10:33:15
0.006 10:.33:17



Date: 02/02/2006

Bkgnd Time
Area
0.007 10:33:35
0.007 10:33:37
0.007 10:33:39



Date: 02/02/2006


Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1      -0.0344    -0.0344
Auto-zero performed.
BlnkCorr   Peak
 Signal    Area
 -0.001    0.094
Bkgnd    Time
Area
 0.006  10:33:44
Element: Ni Seq. No.: 289
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0002
0.0341
0.0109
0.0151
0.0173
115.0
StndConc
ing/L
0.0002
0.0341
0.0109
0.0151
0.0173
115.0
AS Loc. : 	
BlnkCorr
Signal
o.ooo
0.001
0.000
0.001
0.001
114.98
Peak
Area
0.094
0.096
0.095



Date: 02/02/2006
Bkgnd
Area
0.006
0.005
0.006



Time
10:33:50
10:33:53
10:33:55



                                          Page 78

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD !
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

: : Ni Seq
ID: 203-23

SampleConc
mg/L
0.0973
0.0826
0.0926
0.0908
0.0075
8.30
: Ni Seq
ID: ccb

SampleConc
mg/L
-0.0026
-0.0080
0.0259
0.0051
0.0182
356.6
. No. : 290
StndConc
mg/L
0.0973
0.0826
0.0926
0.0908
0.0075
8.30
. No.: 291
StndConc
mg/L
-0.0026
-0.0080
0.0259
0.0051
0.0182
356.6
: Ni Seq. No. : 292
ID: 203-22+24
SampleConc
mg/L
2.168
2.173
2.187
2.176
0.0097
0.45
: Ni Seq.
ID: ccb

Repl SampleConc
# mg/L
1 0.0355
2
3
Mean:
SD :
%RSD:
0.0153
0.0492
0.0334
0.0171
51.14
StndConc
mg/L
2.168
2.173
2.187
2.176
0.0097
0.45
No.: 293
StndConc
mg/L
0.0355
0.0153
0.0492
0.0334
0.0171
51.14
AS
LOG, : 	
BlnkCorr Peak
Signal Area
0.004 0.098
0.003
0.003
0.003
0.000
8.30
AS
0.097
0.098



Loc. : 	
BlnkCorr Peak
Signal Area
0.000 0.094
0.000
0.001
0.000
0.001
356.64
AS
BlnkCorr
Signal
0.080
0.080
0.080
0.080
0.000
0.45
AS
BlnkCorr
Signal
0.001
0.001
0.002
0.001
0.001
51.14
0.094
0.095



Loc. : 	
Peak
Area
0.174
0.174
0.175



Loc. : 	
Peak
Area
0.096
0.095
0.096



Dare:
02/02/2006
Bkgnd Time
Area
0.006 10:34:
0.007
0.006



Date:
Bkgnd
Area
0.006
0.007
0.005



Date:
Bkgnd
Area
0.006
0.006
0.006



Date:
Bkgnd
Area
0.005
0.006
0.005



10:34:
10:34:



12
14
17



02/02/2006
Time
10:34:
10:34:
10:34:



34
36
38



02/02/2006
Time
10:34:
10:34:
10:35:



56
58
00


mui—im~ij—mm^j^ — — — ^^ ^ ^^^_^_,^_^ ^_^_^_^_^_^
02/02/2006
Time
10:35:
10:35:
10:35:



49
51
54



Page 79

-------
Element: Ni Seq. No.: 294
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 0.0149 0.0149
2 0.0288 0.0288
3 0.0155 0.0155
Mean: 0.0197 0.0197
SD : 0.0078 0.0078
%RSD: 39.73 39.73
Element: Ni Seq. No.: 295
Sample ID: ccv-0.25

Repl SampleConc StndConc
# mg/L mg/L
1 0,2672 0.2672
2 0.2671 0.2671
3 0.2767 0.2767
Mean: 0.2703 0.2703
SD : 0.0055 0.0055
%RSD: 2.04 2.04
Element: Ni Seq. No.: 296
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 0.0215 0.0215
2 0.0465 0.0405
3 0.0193 0.0193
Mean: 0.0271 0.0271
SD : 0.0116 0.0116
%RSD: 42.91 42.91
Element: Ni Seq. No.: 297
Sample ID: *324-l+3
Repl SampleConc StndConc
# mg/L mg/L
1 0.6406 0.6406
2 0.6395 0.6395
3 0.6519 0.6519
Mean: 0.6440 0.6440
SD : 0.0069 0.0069
%RSD: 1.07 1.07
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
39.73
AS


BlnkCorr
Signal
0.010
0.010
0.010
0.010
0.000
2.04
AS :

BlnkCorr
Signal
0.001
0. 001
0.001
0.001
0.000
42.91
AS :

BlnkCorr
Signal
0.024
0.023
0.024
0.024
0.000
1.07
Loc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	


Peak
Area
0.104
0.104
0.105



Loc. : 	

Peak
Area
0.095
0.096
0.095



Loc. : 	

Peak
Area
0.118
0.118
0.118



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:36:00
0.006 10:36:03
0.006 10:36:05



Date: 02/02/2006


Bkgnd Time
Area
0.006 10:36:29
0.005 10:36:32
0.005 10:36:34



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:36:53
0.005 10:36:56
0.005 10:36:58



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:37:30
0.006 10:37:32
0.006 10:37:34



Page 80

-------
Element: Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
0.0221
0.0175
0.0168
0.0188
0.0029
15.26
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 298

StndConc
mg/L
0.0221
0.0175
0.0168
0.0188
0.0029
15.26
. No. : 299
AS

BlnkCorr
S ignal
0.001
0.001
0.001
0.001
0.000
15.26
AS
Loc . : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	
Date:

Bkgnd
Area
0.006
0.006
0.006



Date:
02/02/2006

Time

10:37:
10:37:
10:37:






53
55
57



02/02/2006
ID: S324-1+3

SampleConc
mg/L
1.596
1.621
1.650
1.622
0.0270
1.66
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
0.0230
0,0171
0.0171
0.0191
0.0034
17.65
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
1.596
1.621
1.650
1.622
0.0270
1.66
. No.: 300

StndConc
mg/L
0.0230
0.0171
0.0171
0.0191
0.0034
17.65
. No. : 301
BlnkCorr
S ignal
0.059
0.059
0.061
0.060
0.001
1.66
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.65
Peak
Area
0.153
0.154
0.155



Loc. : 	

Peak
Area
0.095
0.095
0.095



AS Loc. : 	
Bkgnd
Area
0.006
0.006
Time

10:38:
10:38:
0.006 10:38:



Date:

Bkgnd
Area
0.006
0.006
0.006



Date:





18
20
23



02/02/2006

Time

10:38:
10:38:
10:38:






39
41
43



02/02/2006
ID: sd324-l+3
SampleConc
mg/L
1.596
1.613
1.602
1.604
0.0087
0.54
StndConc
mg/L
1.596
1.613
1.602
1,604
0.0087
0.54
BlnkCorr
Signal
0.059
0.059
0.059
0.059
0.000
0.54
Peak
Area
0.153
0.154
0.153



Bkgnd
Area
0.006
0.006
0.006



Time

10:39:
10:39:
10:39:





05
07
09



Page 81

-------


Element : Ni Seq
Sanple ID: ccb

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0408
0.0202
0.0162
0.0258
0.0132
51.25
. No.: 302
StndConc
mg/L
0.0408
0.0202
0.0162
0.0258
0.0132
51.25
Element: Ni Seq. No.: 303
Sample ID: ser324-l+3

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.3389
0.3537
0.3287
0.3404
0.0126
StndConc
mg/L
0.3389
0.3537
0.3287
0.3404
0.0126
3.69 3.69
Element: Ni Seq. No.: 304
Sample ID: ccb
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0217
0.0115
-0.0268
0.0021
0.0256
1202
: Ni Seq.
ID: 324-4+6

SampleConc
mg/L
0.5527
0.5795
0.5451
0.5591
0.0181
3.24
Stndeonc
mg/L
0.0217
0.0115
-0.0268
0.0021
0.0256
1202
No.: 305
StndConc
mg/L
0.5527
0.5795
0.5451
0.5591
0.0181
3.24
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
51.25
AS
BlnkCorr
Signal
0.012
0.013
0.012
0.012
0.000
Loc . : 	
Peak
Area
0.096
0.095
0.095



Loc. : 	
Peak
Area
0.107
0.107
0.106


Date:
Bkgnd
Area
0.005
0.006
0.007



Date:
Bkgnd
Area
0.007
0.006
0.007


02/02/2036
Time
10:39:
10:39:
10:39:



23
25
21



02/02/2006
Time
10:40:
10:40:
10:40:


00
02
04


3.69
AS Loc. : 	
BlnkCorr
Signal
0.001
0.000
-0.001
0.000
0.001
1202.00
Peak
Area
0.095
0.095
0.093



AS Loc. : 	
BlnkCorr
Signal
0.020
0.021
0.020
0.021
0.001
3.24
Peak
Area
0.115
0.116
0.114



Date:
Bkgnd
Area
0.006
0.006
0.008



02/02/2006
Time
10:40:
10:40:
10:40:



17
19
21



Date: 02/02/2006
Bkgnd
Area
0.006
0.006
0.006



Time
10:41:
10:41:
10:41:



12
14
16



Page 82

-------
Element: Ni Seq. No. : 306
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0071 -0.0071
2 0.0268 0.0268
3 0.0159 0.0159
Mean: 0.0118 0.0118
SD : 0.0173 0.0173
%RSD: 146.0 146.0
Element: Ni Seq. No.: 307
Sample ID: 324-7+9
Repl SampleConc StndConc
# mg/L mg/L
1 0.7695 0.7695
2 0.8041 0.8041
3 0.7678 0.7678
Mean: 0.7805 0.7805
SD : 0.0205 0.0205
%RSD: 2.62 2.62
Element: Ni Seq. No.: 308
Sample ID: ccb

Repl SampleConc StndConc
# rng/L mg/L
1 0.0288 0.0288
2 -0.0042 -0.0042
3 -0.0235 -0.0235
Mean: 0.0004 0.0004
SD : 0.0265 0.0265
%RSD: 7256 7256
Element: Ni Seq. No.: 309
Sample ID: 324-10+12
Repl SampleConc StndConc
# mg/L mg/L
1 0.1553 0.1553
2 0.1373 0.1373
3 0.1785 0.1785
Mean: 0.1570 0.1570
SD : 0.0207 0.0207
%RSD: 13.15 13.15
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.094
0.001 0.095
0.001 0.095
0.000
0.001
146.05
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.028 0.123
0.030 0.124
0.028 0.123
0.029
0.001
2.62
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.001 0.095
0.000 0.094
-0.001 0.094
0.000
0.001
7256.20
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 0.100
0.005 0.099
0.007 0.101
0.006
0.001
13.15
Date: 02/02/2006


Bkgnd Time
Area
0.007 10:41:38
0.006 10:41:41
0.006 10:41:43



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:42:02
0.006 10:42:04
0.007 10:42:06



Date: 02/02/2006


Bkgnd Time
Area
0.006 10:42:31
0.006 10:42:33
0.007 10:42:35



Date: 02/02/2006

Bkgnd Time
Area
0.007 10:43:07
0.007 10:43:09
0.006 10:43:11



Page 83

-------
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
-0.0217
-0.0237
-0.0106
-0.0187
0.0071
37.90
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
0.0016
-0.0078
0.0182
0.0040
0.0132
329.0
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD;
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-0.5
SampleConc
mg/L
0.5241
0.5166
0.5084
0.5164
0.0078
1.52
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0080
-0.0295
0.0036
-0.0113
0.0168
148.9
. No. : 310

StndConc
mg/L
-0.0217
-0.0237
-0.0106
-0.0187
0.0071
37.90
. No. : 311

StndConc
mg/L
0.0016
-0.0078
0.0182
0.0040
0.0132
329.0
. No. : 312

StndConc
mg/L
0.5241
0.5166
0.5084
0.5164
0.0078
1.52
No. : 313

StndConc
mg/L
-0.0080
-0.0295
0.0036
-0.0113
0.0168
148.9
AS

BlnkCorr
S ignal
-0.001
-0.001
0.000
-0.001
0.000
37.90
AS

BlnkCorr
Signal
0.000
0.000
0.001
0,000
0.000
329.00
Loc. : 	

Peak
Area
0.094
0.094
0.094



Loc. : 	

Peak
Area
0.094
0.094
0.095



AS LOG. : 	

BlnkCorr
Signal
0.019
0.019
0.019
0.019
0.000
1.52

Peak
Area
0.114
0.113
0.113



AS Loc. : 	

BlnkCorr
Signal
0.000
-0.001
0.000
0.000
0.001
148.91

Peak
Area
0.094
0.093
0.095



Date:

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.005
0.006
0.005



02/02/2006

Time

10:44:
10:44:
10:44:






00
02
04



02/02/2006

Time

10:44:
10:44:
10:44:






11
13
15



Date: 02/02/2006

Bkgnd
Area
0.006
0.006
0.006




Time

10:44:
10:44:
10:44:






36
38
40



Date: 02/02/2006

Bkgnd
Area
0.006
0.007
0.005




Time

10:45:
10:45:
10:45:






02
04
06



Page 84

-------

Element: Mi Seq.
. No. : 314
AS LOG. ; 	
Date: 02/02/2006
Sample ID: 324-13+15

Repl SampleConc
# mg/L
1 0.2248
2 0.2505
3 0.2649
Mean: 0.2467
SD : 0.0203
%RSD: 8.23
Element: Ni Seq.
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0270
2 -0.0443
3 -0.0366
Mean: -0.0360
SD : 0.0087
%RSD: 24.12
Element : Ni Seq .
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0071
2 -0.0421
3 -0.0430
Mean: -0.0307
SD : 0.0205
%RSD: 66.59
Element: Ni Seq.
StndConc
mg/L
0.2248
0.2505
0.2649
0.2467
0.0203
8.23
No.: 315

StndConc
mg/L
-0.0270
-0.0443
-0.0366
-0.0360
0.0087
24.12
No.: 316

StndConc
mg/L
-0.0071
-0.0421
-0.0430
-0.0307
0.0205
66.59
No. : 317
BlnkCorr Peak
Signal Area
0.008 0.103
0.009 0.104
0.010 0.104
0.009
0.001
8.23
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.001 0.093
-0.001
0.000
24.12
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.094
-0.002 0.093
-0.002 0.093
-0.001
0.001
66.59
AS LOG.: 	
Bkgnd Time
Area
0.007 10:45:23
0.006 10:45:25
0.006 10:45:27



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:45:43
0.007 10:45:45
0.007 10:45:47



Date: 02/02/2006

Bkgnd Time
Area
0.005 10:46:02
0.006 10:46:04
0.007 10:46:07



Date: 02/02/2006
Sample ID: 324-16+18

Repl SampleConc
# mg/L
1 0.2713
2 0.2871
3 0.2736
Mean: 0.2773
SD : 0.0086
%RSD: 3.08
StndConc
mg/L
0.2713
0.2871
0.2736
0.2773
0.0086
3.08
BlnkCorr Peak
Signal Area
0.010 0.104
0.011 0.105
0.010 0.104
0.010
0.000
3.08
Bkgnd Time
Area
0.006 10:46:26
0.006 10:46:28
0.006 10:46:30



Page 85

-------
Element: Ni Seq
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0392
2 -0.0459
3 -0.0290
Mean: -0.0380
SD : 0.0085
%RSD: 22.44
Element : Ni Seq
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0077
2 -0.0066
3 -0.0401
Mean: -0.0181
SD : 0.0191
%RSD: 105.2
Element : Ni Seq
. No. : 318

StndConc
mg/L
-0.0392
-0.0459
-0.0290
-0.0380
0.0085
22.44
. No. : 319

StndConc
mg/L
-0.0077
-0.0066
-0.0401
-0.0181
0.0191
105.2
. No.: 320
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.001 0.093
-0.001
0.000
22.44
AS Loc. : 	

BlnkCorr Peak
Signal Area
0,000 0.094
0.000 0.094
-0.001 0.093
-0.001
0.001
105.25
AS Loc. : 	
Date: 02/02/2055

Bkgnd Time
Area
0.007 10:46:51
0.007 10:46:53
0.006 10:46:55



Date: 02/02/2006

Bkgnd Time
Area
0.005 10:47:04
0.005 10:47:07
0.007 10:47:09



Date: 02/02/2006
Sample ID: 324-19+21
Repl SampleConc
# mg/L
1 0.3012
2 0.2984
3 0.3245
Mean: 0.3080
SD : 0.0143
StndConc
mg/L
0.3012
0.2984
0.3245
0.3080
0.0143
%RSD: 4.65 4.65
Element: Ni Seq. No.: 321
Sample ID: ccb

Repl SampleConc
# mg/L
1 -0.0073
2 -0.0031
3 -0.0075
Mean: -0.0060
SD : 0.0025
%RSD: 41.56

StndConc
mg/L
-0.0073
-0.0031
-0.0075
-0.0060
0.0025
41.56
BlnkCorr Peak
Signal Area
0.011 0.105
0.011 0.105
0.012 0.106
0.011
0.001
4.65
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.094
0.000 0.094
0.000
0.000
41.56
Bkgnd Time
Area
0.006 10:47:28
0.006 10:47:30
0.005 10:47:32



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:47:57
0.006 10:47:59
0.006 10:48:01



Page 86

-------
Element: Ni Seq
Sample ID: 214-1+3

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
1.791
1.772
1.795
1.786
0.0123
0.69
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD ;
%RSD:
ID : ccb

SampleConc
mg/L
0.0077
-0.0015
0.0111
0.0058
0.0065
112.6
Element : Ni Seq .
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
ft
1
2
3
Mean:
SD :
%RSD,-
ID: 214-4+6
SampleConc
mg/L
4.352
4.461
4.431
4.415
0.0564
1.28
: Ni Seq.
ID : ccb
SampleConc
mg/L
-0.0255
-0.0334
-0.0319
-0.0303
0.0042
13.78
. No.: 322
StndConc
mg/L
1.791
1.772
1.795
1.786
0.0123
0.69
. No.: 323

StndConc
mg/L
0.0077
-0.0015
0.0111
0.0058
0.0065
112.6
No.: 324

StndConc
mg/L
4.352
4.461
4.431
4.415
0.0564
1.28
No. : 325

StndConc
mg/L
-0.0255
-0.0334
-0.0319
-0.0303
0.0042
13.78
AS
BlnkCorr
Signal
0.066
0.065
0.066
0.066
0.000
0.69
AS

Loc . : 	
Peak
Area
0.160
0.159
0.160



Loc. : 	

BlnkCorr Peak
S ignal
0.000
0.000
0.000
0.000
0.000
112.55
AS

BlnkCorr
S ignal
0.160
0.164
0.163
0.162
0.002
1.28
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
13.78
Area
0.095
0.094
0.095



Loc. : 	

Peak
Area
0.254
0.258
0.257



Loc. : 	

Peak
Area
0.093
0.093
0.093



Date:
Bkgnd
Area
0.005
02/02/2006
Time

10:48:
0.006 10:48:
0.005



Date:

Bkgnd
Area
0.005
0.005
0.005



Date:

Bkgnd
Area
0.006
0.005
0.005



10:48:





18
20
22



02/02/2006

Time

10:48:
10:48:
10:48:






46
48
51



02/02/2006

Time

10:49:
10:49:
10:49:






08
10
12



Date: 02/02/2006

Bkqnd
Area
0.006
0.006
0.006




Time

10:50:
10:50:
10:50:






11
13
16



Page 87

-------
Element : Ni Seq
Sanple
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0098
-0.0332
-0.0363
-0.0264
0.0144
54.67
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-1.0
SampleConc
mg/L
0.9410
0.9500
0.9644
0.9518
0.0118
1.24
Element: Ni Seq.
Sample

Repl
#
1
2
3
Mean:
SD :
BRSD:
ID: ccb

SampleConc
mg/L
-0.0465
-0.0275
0.0033
-0.0236
0.0251
106.5
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 214-7+9
SampleConc
mg/L
1.910
1.915
1.949
1.925
0.0209
1.09
. No. : 326

StndConc
mg/L
-0.0098
-0.0332
-0.0363
-0.0264
0.0144
54.67
. No. : 327

StndConc
mg/L
0.9410
0.9500
0.9644
0.9518
0.0118
1.24
No.: 328

StndConc
mg/L
-0.0465
-0.0275
0.0033
-0.0236
0.0251
106.5
No.: 329

StndConc
mg/L
1.910
1.915
1.949
1.925
0.0209
1.09
AS

Loc , : 	

BlnkCorr Peak
Signal
0.000
-0.001
-0.001
-0.001
0.001
54.67
AS

BlnkCorr
Signal
0.035
0.035
0.035
0.035
0.000
1.24
AS

BlnkCorr
Signal
-0.002
-0.001
0.000
-0.001
0.001
106.53
Area
0.094
0.093
0.093



Loc. : 	

Peak
Area
0.129
0.129
0.130



Loc. : 	

Peak
Area
0.093
0.093
0.095



AS Loc. : 	

BlnkCorr
Signal
0.070
0.070
0.072
0.071
0.001
1.09

Peak
Area
0.164
0.165
0.166



Date:

Bkgnd
Area
0.006
0.007
0.006



Date:

Bkgnd
Area
0.007
0.006
0.005



Date:

Bkgnd
Area
0.003
0.006
0.005



02/02/2006

Time

10:50:
10:50:
10:50:






23
26
28



02/02/2006

Time

10:51:
10:51:
10:51:






02
04
06



02/02/2006

Time

10:51:
10:51:
10:51:






45
47
49



Date: 02/02/2006

Bkgnd
Area
0.006
0.007
0.006




Time

10:52:
10:52:
10:52:






33
35
37



Page 88

-------
Element: Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
-0.0126
-0.0235
-0.0042
-0.0134
0.0097
72.15
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 33G

StndConc
mg/L
-0.0126
-0.0235
-0.0042
-0.0134
0.0097
72.15
. No.: 331
AS

BlnkCorr
S ignal
0.000
-0.001
0.000
0.000
0.000
72.15
AS
Loc , : 	

Peak
Area
0.094
0.094
0.094



Loc, : 	
Date:

Bkgnd
Area
0.006
0.006
0.006



Date:
02/02/2006

Time

10:53:
10:53:
10:53:






32
34
37



02/02/2006
ID: 214-10+12

SampleConc
mg/L
0.1683
0,1424
0.1591
0.1566
0.0131
8.39
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
BRSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
0.0100
-0.0257
-0.0100
-0.0086
0.0179
209.0
: Ni Seq.
StndConc
mg/L
0.1683
0.1424
0.1591
0.1566
0.0131
8.39
. No. : 332

StndConc
mg/L
0.0100
-0.0257
-0.0100
-0.0086
0.0179
209.0
No.: 333
BlnkCorr
S ignal
0.006
0.005
0.006
0.006
0.000
8.39
Peak
Area
0.101
0.100
0.100



AS Loc. : 	

BlnkCorr
S ignal
0.000
-0.001
0.000
0.000
0.001
209.03

Peak
Area
0.095
0.093
0.094


Bkgnd
Area
0.006
Time

10:53:
0.006 10:54:
0.006



Date:

Bkgnd
Area
0.005
0.007
0.006


10:54:





59
01
03



02/02/2006

Time

10:54:
10:54:
10:54:





50
52
54



AS Loc. : 	 Date:
02/02/2006
ID: 214-13+15
SampleConc
mg/L
1.819
1.861
1.B28
1.836
0.0223
1.21
StndConc
mg/L
1.819
1.861
1.828
1.836
0.0223
1.21
BlnkCorr
Signal
0.067
0.068
0.067
0.067
0.001
1.21
Peak
Area
0.161
0.163
0.161



Bkgnd
Area
0.007
0.007
0.007



Time

10:55:
10:55:
10:55:





13
15
17



Page 89

-------
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
ID: ccb

SampleConc
mg/L
0.0122
0.0020
0.0113
0.0085
0.0056
66.41
: Ni Seq.
. No. : 334

StndConc
mg/L
0.0122
0.0020
0.0113
0.0085
0.0056
66.41
. No. : 335
AS

Loc. : 	

BlnkCorr Peak
Signal
0.000
0.000
0.000
0.000
0.000
66.41
AS
Area
0.095
0.094
0.095



Loc. : 	
Date:

Bkgnd
Area
02/02/2006

Time

0.006 10:55:
0.006
0.006



Date:
10:55:
10:55:




—

37
39
41



02/02/2006
ID: 214-16+18

SampleConc
mg/L
0.5226
0.5389
0.5288
0.5301
0.0082
1.54
: Ni Seq.
ID: ccb

SampleConc
mg/L
-0.0049
-0.0080
0.0115
-0.0005
0.0105
2156
: Ni Seq.
StndConc
mg/L
0.5226
0.5389
0.5288
0.5301
0.0082
1.54
. No. : 336

StndConc
mg/L
-0.0049
-0.0080
0.0115
-0.0005
0.0105
2156
No. : 337
BlnkCori
S ignal
0.019
0.020
0.019
0.019
0.000
1.54
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
2156.28
AS
Peak
Area
0.114
0.114
0.114



Loc. : 	

Peak
Area
0.094
0.094
0.095



Loc. : 	
Bkgnd
Area
0.007
0.007
0.007



Date:

Bkgnd
Area
0.006
0.006
0.006



Time

10:55:
10:56:
10:56:





59
01
03



02/02/2006

Time

10:56:
10:56:
10:56:






18
20
22



Date: 02/02/2006
ID: 214-19+21

SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.2877
0.3106
0.3176
0.3053
0.0156
5.13
StndConc
mg/L
0.2877
0.3106
0.3176
0.3053
0.0156
5.13
BlnkCorr
Signal
0.011
0.011
0.012
0.011
0.001
5.13
Peak
Area
0.105
0.106
0.106



Bkgnd
Area
0.007
0.006
0.006



Time

10:56:
10:56:
10:56:





39
41
43



Page 90

-------
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb

SampleConc
mg/L
0.0088
-0.0064
0.0140
0.0055
0.0106
193.8
Element : Ni Seq
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb

SampleConc
mg/L
-0.0091
-0.0069
0.0268
0.0036
0.0201
561.5
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccv-2
SampleConc
mg/L
2.099
2.063
2 .109
2.090
0. 0244
1.17
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
0.0060
0.0073
0.0082
0.0072
0.0011
15.32
. No. : 338

StndConc
mg/L
0.0088
-0.0064
0.0140
0.0055
0.0106
193.8
. No. : 339

StndConc
mg/L
-0.0091
-0.0069
0.0268
0.0036
0.0201
561.5
. No. : 340

StndConc
mg/L
2.099
2.063
2.109
2.090
0.0244
1.17
. No. : 341

StndConc
mg/L
0.0060
0.0073
0.0082
0.0072
0.0011
15.32
AS

BlnkCorr
S ignal
0.000
0.000
0.001
0.000
0.000
193.76
AS

BlnkCorr
S ignal
0.000
0.000
0.001
0.000
0.001
561.54
Loc. : 	

Peak
Area
0.095
0.094
0.095



Loc. : 	

Peak
Area
0.094
0.094
0.095



AS LOG. : 	

BlnkCorr
Signal
0 .077
0.076
0.077
0.077
0.001
1.17

Peak
Area
0.171
0.170
0.172



AS Loc. : 	

BlnkCorr
S ignal
0.000
0.000
0.000
0.000
0.000
15.32

Peak
Area
0.095
0.095
0.095



Date:

Bkgnd
Area
02/02/2006

Time

0.006 10:57
0.006
10:57
0.006 10:57



Date:

Bkgnd
Area
0.006
0.006
0.005



Date:

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.005
0.006
0.006







—

:25
:28
:30



02/02/2006

Time

10:57
10:57
10:57




—

:42
:45
:47



02/02/2006

Time

10:58
10:58
10:58






:01
:03
:05



02/02/2006

Time

10:58
10:58
10:58






:28
:30
:32




-------
Element : Ni Seq
Sample ID: Irb i
Repl SampleConc
# mg/L
1 0.0698
2 0.0656
3 0.0673
Mean: 0 . 0676
SD : 0.0021
%RSD: 3.13
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0414
2 0.0082
3 -0.0436
Mean: -0.0256
SD : 0.0293
%RSD: 114.5
Element: Ni Seq.
Sample ID: Ifb i
Repl SampleConc
# mg/L
1 1.086
2 1.079
3 1.056
Mean: 1.073
SD : 0.0159
%RSD: 1.48
Element : Ni Seq .
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0128
2 0.0038
3 -0.0002
Mean: -0.0030
SD : 0.0087
%RSD: 284.9
. No. : 342

StndConc
mg/L
0.0698
0.0656
0.0673
0.0676
0.0021
3.13
. No. : 343

StndConc
mg/L
-0.0414
0.0082
-0.0436
-0.0256
0.0293
114.5
. No. : 344

StndConc
mg/L
1.086
1.079
1.056
1.073
0.0159
1.48
No.: 345

StndConc
mg/L
-0.0128
0.0038
-0.0002
-0.0030
0.0087
264.9
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.097
0.002 0.097
0.002 0.097
0.002
0.000
3.13
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 0.093
0.000 0.095
-0.002 0.093
-0.001
0.001
114.45
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.040 0.134
0.040 0.134
0.039 0.133
0.039
0.001
1.48
AS Loc. I 	

BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.094
0.000
0.000
284.88
Date: 02/02/2006

Bkgnd Time
Area
0.006 10:58:52
0.006 10:58:54
0.006 10:58:56



Date: 02/02/2006

Bkgnd Time
Area
0.007 10:59:14
0.006 10:59:16
0.007 10:59:18



Date: 02/02/2006

Bkgnd Time
Area
0.006 10:59:39
0.006 10:59:41
0.006 10:59:43



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:00:01
0.005 11:00:03
0.006 11:00:05



Page 92

-------
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 324-2

SampleConc
mg/L
0.2935
0.3163
0.2716
0.2938
0.0223
7.60
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0206
-0.0301
-0.0002
-0.0170
0.0153
90.12
Element: Ni Seq.
Sample ID: s324-2
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.238
1.270
1.231
1.246
0.0207
1.66
: Ni Seq.
ID : ccb
SampleConc
mg/L
0.0080
-0.0097
0.0179
0.0054
0.0139
257.9
. No. : 346

StndConc
mg/L
0.2935
0.3163
0.2716
0.2938
0.0223
7.60
. No. : 347

StndConc
mg/L
-0.0206
-0.0301
-0.0002
-0.0170
0.0153
90.12
No. : 348
StndConc
mg/L
1.238
1.270
1.231
1.246
0.0207
1.66
No. : 349
StndConc
mg/L
0.0080
-0.0097
0.0179
0.0054
0.0139
257.9
AS

BlnkCorr
Signal
0.011
0.012
0.010
0.011
0.001
7.60
AS

BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.001
90.12
Loc. : 	

Peak
Area
0.105
0.106
0.104



Loc. : 	

Peak
Area
0.094
0.093
0.094



AS Loc. : 	
BlnkCorr
Signal
0.045
0.047
0.045
0.046
0.001
1.66
Peak
Area
0.140
0 . 141
0.140



AS Loc. : 	

BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
257.91

Peak
Area
0.095
0.094
0.095



Date:

Bkgnd
Area
0.006
02/02/2006

Time
11:00:
0.005 11:00:
0.006



Date:

Bkgnd
Area
0.006
0.006
0.005



Date:
Bkgnd
Area
0.006
0.005
0.007



11:00:




24
27
29



02/02/2006

Time
11:01:
11:01:
11:01:




15
17
19



02/02/2006
Time
11:01:
11:01:
11:01:



44
46
48



Date: 02/02/2006

Bkgnd
Area
0.005
0.005
0.005




Time
11:02:
11:02:
11:02:





05
07
09



Page 93

-------
Element: Ni Seq. No. : 350 AS
Sample ID: sd324-2

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.185 1.185 0.043
2 1.183 1.183 0.043
3 1.196 1.196 0.044
Mean: 1.188 1.188 0.044
SD ; 0.0070 0.0070 0.000
%RSD: 0.59 0.59 0.59
Element: Ni Seq. No.: 351 AS
Sample ID: ccb

Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0002 -0.0002 0.000
2 -0.0097 -0.0097 0.000
3 0.0013 0.0013 0.000
Mean: -0.0029 -0.0029 0.000
SD : 0.0059 0.0059 0.000
%RSD: 207.9 207.9 207.95
Element: Ni Seq. No.: 352 AS
Sample ID: ser324-2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.2275 0.2275 0.008
0.2461 0.2461 0.009
3 0.2124 0.2124 0.008
Mean: 0.2287 0.2287 0.008
SD : 0.0169 0.0169 0.001
%RSD: 7.39 7.39 7.39
Element: Ni Seq. No.: 353 AS
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0086 -0.0086 0.000
2 -0.0199 -0.0199 -0.001
3 -0.0128 -0.0128 0.000
Mean: -0.0137 -0.0137 -0.001
SD : 0.0057 0.0057 0.000
%RSD: 41.60 41.60 41.60
LOG. : 	


Peak
Area
0.138
0.138
0.138



LOG. : 	


Peak
Area
0.094
0.094
0.094



LOG. : 	

Peak
Area
0.103
0.103
0.102



Loc. : 	

Peak
Area
0.094
0.094
0.094



Date: 02/02/2006


Bkgnd Time
Area
0.006 11:02:29
0.005 11:02:31
0.005 11:02:33



Date: 02/02/2006


Bkgnd Time
Area
0.005 11:02:55
0.006 11:02:57
0.005 11:02:59



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:03:24
0.005 11:03:27
0.006 11:03:29



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:03:47
0.005 11:03:50
0.005 11:03:52



Page 94

-------
Element : Ni Seq
Sample ID : ccb

Repl SampleConc
# mg/L
1 -0.0022
2 0.0122
3 0.0060
Mean: 0.0053
SD : 0.0072
%RSD: 135.1
Element : Ni Seq
Sample ID: ccv-0.2E

Repl SampleConc
# mg/L
1 0.2277
2 0.2319
3 0.2260
Mean: 0.2285
SD : 0.0030
%RSD: 1.32
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0026
2 -0.0195
3 -0.0197
Mean: -0.0139
SD : 0.0098
%RSD: 70.72
Element: Ni Seq.
Sample ID: 324-5
Repl SampleConc
# mg/L
1 0.0842
2 0.1008
3 0.0755
Mean: 0.0868
SD : 0.0129
%RSD: 14.82
. No. : 354


StndConc
mg/L
-0.0022
0.0122
0.0060
0.0053
0.0072
135.1
. No.: 355
5

StndConc
mg/L
0.2277
0.2319
0.2260
0.2285
0.0030
1.32
. No. : 356

StndConc
mg/L
-0.0026
-0.0195
-0.0197
-0.0139
0.0098
70.72
. No. : 357

StndConc
mg/L
0.0842
0.1008
0.0755
0.0868
0.0129
14.82
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.095
0.000
0.000
135.09
AS Loc. : 	


BlnkCorr Peak
Signal Area
0.008 0.103
0.009 0.103
0.008 0.103
0.008
0.000
1.32
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.094
-0.001 0.094
-0.001 0.094
-0.001
0.000
70.72
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.097
0.004 0.098
0.003 0.097
0.003
0.000
14.82
Date:


Bkgnd
Area
0.005
0.005
0.005



Date:


Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.005
0.006
0.005



Date:

Bkgnd
Area
0.006
0.005
0.005



02/02/2006


Time

11:04:31
11:04:33
11:04:35



02/02/2006


Time

11:04:52
11:04:54
11:04:56



02/02/2006

Time

11:05:12
11:05:14
11:05:16



02/02/2006

Time

11:05:33
11:05:35
11:05:37



Page 95

-------
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0095
2 0.0100
3 0.0000
Mean: 0.0065
SD : 0.0056
%RSD: 86.70
Element : Ni Seq
Sample ID: 324-8
Repl SampleConc
# mg/L
1 0.0915
2 0.0842
3 0.0932
Mean: 0.0896
SD : 0.0048
%RSD: 5.31
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# »g/L
1 -0.0005
O f~\ /** f~\ i—i r-r
- : £ -0 . 0077
3 0.0175
Mean: 0.0031
SD : 0.0130
%RSD: 418.5
Element : Ni Seq .
Sample ID: 324-11
Repl SampleConc
# mg/L
1 0.0766
2 0.0620
3 0.0647
Mean: 0.0678
SD : 0.0078
%RSD: 11.44
. No. : 358

StndConc
mg/L
0.0095
0.0100
0.0000
0.0065
0.0056
86.70
. No. : 359

StndConc
mg/L
0.0915
0.0842
0.0932
0.0896
0.0048
5.31
. No. : 360

StndConc
mg/L
-0.0005
_ _ _
-0 . 0077
0.0175
0.0031
0.0130
418.5
. No. : 361

StndConc
mg/L
0.0766
0.0620
0.0647
0.0678
0.0078
11.44
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
86.70
AS

BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
5.31
AS

BlnkCorr
Signal
0.000

0 . 000
0.001
0.000
0.000
418 .47
AS :

BlnkCorr
Signal
0.003
0.002
0.002
0.002
0.000
11.44
LOG. : 	

Peak
Area
0.095
0.095
0.094



Loc. : 	

Peak
Area
0.098
0.097
0.098



Loc. : 	

Peak
Area
0.094

0 . 094
0.095



Loc. : 	

Peak
Area
0.097
0.097
0.097



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:05:58
0.005 11:06:00
0.005 11:06:03



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:06:22
0.006 11:06:24
0.006 11:06:26



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:06:52
r~\ r\ f~\ .*- 1 "1 /~l /"" ET ./!
0 . 006 1J- : Uo ; o4
0.005 11:06:56



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:07:10
0.005 11:07:13
0.005 11:07:15



Page 96

-------
Element : Ni Seq . No . : 362
Sample ID: ccb

Repl SampleConc StndConc
# mg/L mg/L
1 -0.0182 -0.0182
2 -0.0605 -0.0605
3 -0.0383 -0.0383
Mean: -0.0390 -0.0390
SD : 0.0212 0.0212
%RSD: 54.23 54.23
Element: Ni Seq. No.: 363
Sample ID: 324-14
Repl SampleConc StndConc
# mg/L mg/L
1 0.0609 0.0609
2 0.0751 0.0751
3 0.0591 0.0591
Mean: 0.0650 0.0650
SD : 0.0088 0.0088
BRSD: 13.51 13.51
Element: Ni Seq. No.: 364
Sample ID: ccb
Repl SampleConc StndConc
# mg/L mg/L
1 -0.0027 -0.0027
2 0.0071 0.0071
3 -0.0122 -0.0122
Mean: -0.0026 -0.0026
SD : 0.0097 0.0097
%RSD: 369.8 369.8
Element: Ni Seq. No.: 365
Sample ID: dup 324-14
Repl SampleConc StndConc
# mg/L mg/L
1 0.0746 0.0746
2 0.0711 0.0711
3 0.0696 0.0696
Mean: 0.0718 0.0718
SD : 0.0025 0.0025
%RSD: 3.52 3.52
AS Loc. : 	


BlnkCorr Peak
Signal Area
-0.001 0.094
-0.002 0.092
-0.001 0.093
-0.001
0.001
54.23
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.097
0.003 0.097
0.002 0.097
0.002
0.000
13.51
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.094
0.000 0.095
0.000 0.094
0.000
0.000
369.79
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.097
0.003 0.097
0.003 0.097
0.003
0.000
3.52
Date: 02/02/2006


Bkgnd Time
Area
0.006 11:07:29
0.008 11:07:31
0.007 11:07:33



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:07:49
0.005 11:07:51
0.006 11:07:53



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:08:05
0.005 11:08:07
0.006 11:08:10



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:08:27
0.005 11:08:29
0.006 11:08:31




-------
                Appendix E - 3



Laboratory QA/QC Data for Stack Testing Samples

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0184
2 0.0153
3 0.0148
Mean: 0.0162
SD : 0.0020
%RSD: 12.16
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0151
2 -0.0018
3 -0.0086
Mean: -0.0085
SD : 0.0067
%RSD: 78.22
Element: Ni Seq.
Sample ID: ccv-2
Repl SampleConc
# mg/L
1 2.056
2 2.089
3 2.071
Mean: 2.072
SD : 0.0169
%RSD: 0.82
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0109
2 -0.0421
3 -0.0002
Mean: -0.0177
SD : 0.0218
%RSD: 122.7
No. : 366 AS ]

StndConc BlnkCorr
mg/L Signal
0.0184 0.001
0.0153 0.001
0.0148 0.001
0.0162 0.001
0.0020 0.000
12.16 12.16
No. : 367 AS '.

StndConc BlnkCorr
mg/L Signal
-0.0151 -0.001
-0.0018 0.000
-0.0086 0.000
-0.0085 0.000
0.0067 0.000
78.22 78.22
No. : 368 AS

StndConc BlnkCorr
mg/L Signal
2.056 0.075
2.089 0.077
2.071 0.076
2.072 0.076
0.0169 0.001
0.82 0.82
No. : 369 AS

StndConc BlnkCorr
mg/L Signal
-0.0109 0.000
-0.0421 -0.002
-0.0002 0.000
-0.0177 -0.001
0.0218 0.001
122.7 122.73
L,oc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.094
0.094
0.094



Loc. : 	

Peak
Area
0.170
0.171
0.170



Loc. : 	

Peak
Area
0.094
0.093
0.094



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:08:45
0.005 11:08:47
0.005 11:08:49



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:16:25
0.005 11:16:27
0.005 11:16:30



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:16:45
0.005 11:16:48
0.005 11:16:50



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:18:32
0.006 11:18:35
0.005 11:18:37



Page 98

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: 324-17
SampleConc
mg/L
0.0671
0.1088
0.0665
0.0808
0.0243
30.02
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID : ccb
SampleConc
mg/L
-0.0162
0.0117
-0.0215
-0.0087
0.0178
205.1
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: 324-20
SampleConc
mg/L
0.0558
0.0667
0.0483
0.0569
0.0093
16.26
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0170
0.0133
-0.0108
0.0065
0.0151
231.6
, No.: 370

StndConc
mg/L
0.0671
0.1088
0.0665
0.0808
0.0243
30.02
. No. : 371

StndConc
mg/L
-0.0162
0.0117
-0.0215
-0.0087
0.0178
205.1
. No. : 372

StndConc
mg/L
0.0558
0.0667
0.0483
0.0569
0.0093
16.26
. No.: 373

StndConc
mg/L
0.0170
0.0133
-0.0108
0.0065
0.0151
231.6
AS Loc. : 	

BlnkCorr
Signal
0.002
0.004
0.002
0.003
0.001
30.02

Peak
Area
0.097
0.098
0.097



AS Loc. : 	

BlnkCorr
Signal
-0.001
0.000
-0.001
0.000
0.001
205.15
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
16.26
AS

BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.001
231.56

Peak
Area
0.094
0.095
0.094



Loc. : 	

Peak
Area
0.096
0.097
0.096



Loc. : 	

Peak
Area
0.095
0.095
0.094



Date: 02/02/2006

Bkgnd
Area
0.006
0.004
0.006




Time
11:18:50
11:18:52
11:18:54



Date: 02/02/2006

Bkgnd
Area
0.006
0.005
0.006



Date:

Bkgnd
Area
0.005
0.006
0.006



Date:

Bkgnd
Area
0.005
0.005
0.005




Time
11:19:23
11:19:26
11:19:28



02/02/2006

Time

11:19:50
11:19:52
11:19:55



02/02/2006

Time

11:20:15
11:20:17
11:20:19



Page 99

-------
Element: Ni Seq
Sample ID: 214-2
Repl SampleConc
# mg/L
1 0.0944
2 0.0740
3 0.0636
Mean: 0.0774
SD : 0.0157
%RSD: 20.26
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0175
2 -0.0277
3 -0.0071
Mean: -0.0174
SD : 0.0103
%RSD: 59.06
Element: Ni Seq
Sample ID: 214-5
Repl SampleConc
# mg/L
1 0.0350
2 0.0607
3 0.0507
Mean: 0.0488
SD : 0.0130
%RSD: 26.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0007
2 0.0168
3 -0.0026
Mean: 0.0045
SD : 0.0107
%RSD: 237.3
. No.: 374

StndConc
mg/L
0.0944
0.0740
0.0636
0.0774
0.0157
20.26
. No. : 375

StndConc
mg/L
-0.0175
-0.0277
-0.0071
-0.0174
0.0103
59.06
. No. : 376

StndConc
mg/L
0.0350
0.0607
0.0507
0.0488
0.0130
26.55
. No. : 377

StndConc
mg/L
-0.0007
0.0168
-0.0026
0.0045
0.0107
237.3
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.098
0.003 0.097
0.002 0.097
0.003
0.001
20.26
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.094
-0.001 0.093
0.000 0.094
-0.001
0.000
59.06
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.002 0.096
0.002
0.000
26.55
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.094
0.001 0.095
0.000 0.094
0.000
0.000
237.27
Date: 02/02/2006

Bkgnd Time
Area
0.005 11:20:45
0.005 11:20:48
0.006 11:20:50



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:21:08
0.006 11:21:10
0.005 11:21:12



Date: 02/02/2006

Bkgnd Time
Area
0.007 11:21:24
0.006 11:21:26
0.006 11:21:28



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:21:42
0.004 11:21:44
0.005 11:21:46



Page 100

-------
Element: Ni Seq
Sample ID: 214-8
Repl SampleConc
# mg/L
1 0.0496
2 0.0645
3 0.0667
Mean: 0.0603
SD : 0.0093
%RSD: 15.47
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0166
2 0.0035
3 0.0007
Mean: -0.0041
SD : 0.0109
%RSD: 263.2
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0357
2 -0.0454
3 -0.0529
Mean: -0.0447
SD : 0.0086
%RSD: 19.24
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.4736
2 0.4539
3 0.4856
Mean: 0.4711
SD : 0.0160
%RSD: 3.40
. No. : 378

StndConc
mg/L
0.0496
0.0645
0.0667
0.0603
0.0093
15.47
. No. : 379

StndConc
mg/L
-0.0166
0.0035
0.0007
-0.0041
0.0109
263.2
. No. : 380

StndConc
mg/L
-0.0357
-0.0454
-0.0529
-0.0447
0.0086
19.24
. No. : 381

StndConc
mg/L
0.4736
0.4539
0.4856
0.4711
0.0160
3.40
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.096
0.002 0.097
0.002 0.097
0.002
0.000
15.47
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.094
0.000 0.095
0.000 0.094
0.000
0.000
263.17
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.093
-0.002 0.093
-0.002 0.092
-0.002
0.000
19.24
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.017 0.112
0.017 0.111
0.018 0.112
0.017
0.001
3.40
Date: 02/02/2006

Bkgnd Time
Area
0.006 11:22:02
0.006 11:22:04
0.006 11:22:06



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:22:21
0.005 11:22:23
0.005 11:22:25



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:22:52
0.006 11:22:54
0.006 11:22:56



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:23:12
0.007 11:23:15
0.005 11:23:17



Page 101

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0689
2 -0.0290
3 -0.0518
Mean: -0.0499
SD : 0.0200
%RSD: 40.15
Element: Ni Seq
Sample ID: 214-11
Repl SampleConc
# mg/L
1 0.0427
2 -0.0027
3 0.0252
Mean: 0.0217
SD : 0.0229
%RSD: 105.5
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0250
2 -0.0233
3 -0.0556
Mean: -0.0346
SD : 0.0182
%RSD: 52.47
Element: Ni Seq
Sample ID: 214-14
Repl SampleConc
# mg/L
1 0.0527
2 0.0811
3 0.0117
Mean: 0.0485
SD : 0.0349
%RSD: 72.01
. No.: 382

StndConc
mg/L
-0.0689
-0.0290
-0.0518
-0.0499
0.0200
40.15
. No. : 383

StndConc
mg/L
0.0427
-0.0027
0.0252
0.0217
0.0229
105.5
. No. : 384

StndConc
mg/L
-0.0250
-0.0233
-0.0556
-0.0346
0.0182
52.47
. No.: 385

StndConc
mg/L
0.0527
0.0811
0.0117
0.0485
0.0349
72.01
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 0.092
-0.001 0.093
-0.002 0.092
-0.002
0,001
40.15
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.096
0.000 0.094
0.001 0.095
0.001
0.001
105.53
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.093
-0.001 0.094
-0.002 0.092
-0.001
0.001
52.47
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.096
0.003 0.097
0.000 0.095
0.002
0.001
72.01
Date: 02/02/2006

Bkgnd Time
Area
0.007 11:23:35
0.005 11:23:37
0.006 11:23:39



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:23:50
0.007 11:23:53
0.006 11:23:55



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:24:12
0.005 11:24:14
0.006 11:24:16



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:24:32
0.004 11:24:34
0.007 11:24:36



Page 102

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0221
2 -0.0341
3 -0.0146
Mean: -0.0236
3D : 0.0098
%RSD: 41.74
Element: Ni Seq
Sample ID: 214-17
Repl SampleConc
# mg/L
1 0.0279
2 0.0335
3 0.0403
Mean: 0.0339
SD : 0.0062
%RSD: 18.30
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0292
2 -0.0518
3 -0.0345
Mean: -0.0385
SD : 0.0118
%RSD: 30.74
Element: Ni Seq
Sample ID: 214-20
Repl SampleConc
# mg/L
1 0.0434
2 0.0731
3 0.0804
Mean: 0.0656
SD : 0.0196
%RSD: 29.87
. No. : 386

StndConc
mg/L
-0.0221
-0.0341
-0.0146
-0.0236
0.0098
41.74
. No.: 387

StndConc
mg/L
0.0279
0.0335
0.0403
0.0339
0.0062
18.30
. No. : 388

StndConc
mg/L
-0.0292
-0.0518
-0.0345
-0.0385
0.0118
30.74
. No.: 389

StndConc
mg/L
0.0434
0.0731
0.0804
0.0656
0.0196
29.87
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
41.74
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
18.30
AS

BlnkCorr
Signal
-0.001
-0.002
-0.001
-0.001
0.000
30.74
AS

BlnkCorr
Signal
0.002
0.003
0.003
0.002
0.001
29.87
Loc. : 	

Peak
Area
0.094
0.093
0.094



Loc. : 	

Peak
Area
0.095
0.096
0.096



Loc. : 	

Peak
Area
0.093
0.092
0.093



Loc. : 	

Peak
Area
0.096
0.097
0.097



Date: 02/02/2006

Bkgnd Time
Area
0.005 11:24:48
0.006 11:24:50
0.006 11:24:52



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:25:10
0.006 11:25:12
0.006 11:25:14



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:25:26
0.006 11:25:28
0.006 11:25:30



Date: 02/02/2006

Bkgnd Time
Area
0.006 11:25:43
0.005 11:25:45
0.005 11:25:48



Page 103

-------
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0388
-0.0224
-0.0520
-0.0377
0.0148
39.21
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0237
-0.0707
-0.0569
-0.0504
0.0242
47.92
Element: Ni Seq
Sample
Repl
#
1
ID: Sample
SampleConc
mg/L
-0.0350
. No. : 390

StndConc
mg/L
-0.0388
-0.0224
-0.0520
-0.0377
0.0148
39.21
. No. : 391

StndConc
mg/L
-0.0237
-0.0707
-0.0569
-0.0504
0.0242
47.92
. No. : 392

StndConc
mg/L
-0.0350
AS

BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
39.21
AS

BlnkCorr
Signal
-0.001
-0.003
-0.002
-0.002
0.001
47.92
AS

BlnkCorr
Signal
-0.001
Loc. : 	

Peak
Area
0.093
0.094
0.092



Loc. : 	

Peak
Area
0.094
0.092
0.092



Loc. : 	

Peak
Area
0.093
Date:

Bkgnd
Area
02/02/2006

Time

0.006 11:26:
0.005
0.007



Date :

Bkgnd
Area
0.005
0.007
0.006



Date:

Bkgnd
Area
0.006
11:26:
11:26:






01
03
05



02/02/2006

Time

11:26:
11:26:
11:26:






14
16
18



02/02/2006

Time

11:26:



22
Auto- zero performed.


Element: Ni Seq
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0053
-0.0071
-0.0106
-0.0041
0.0083
201.8

. No. : 393

StndConc
mg/L
0.0053
-0.0071
-0.0106
-0.0041
0.0083
201.8
: Ni Seq. No. : 394


AS Loc. : 	

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
201.80

Peak
Area
0.093
0.093
0.093



AS Loc. : 	

Date:

Bkgnd
Area
0.006
0.006
0.006





02/02/2006

Time

11:26:
11:26:
11:26:






29
31
34



Date: 02/02/2006
ID: 214-11 dup
SampleConc
mg/L
0.1052
0.1077
0.0995
0.1042
0.0042
4.03
StndConc
mg/L
0.1052
0.1077
0.0995
0.1042
0.0042
4.03
BlnkCorr
Signal
0.004
0.004
0.004
0.004
0.000
4.03
Peak
Area
0.097
0.097
0.097



Bkgnd
Area
0.005
0.005
0.005



Time

11:26:
11:26:
11:26:





51
53
56



Page 104

-------
Element: Ni    Seq. No.:  395
Sample ID: ccb
AS  LOG.
Date: 02/02/2006
Repl J
# r
1
2
3
Mean:
SD :
%RSD:
3ampleConc
ag/L
0.0224
0.0073
0.0044
0.0114
0.0097
85.26
StndConc
mg/L
0.0224
0.0073
0.0044
0.0114
0.0097
85.26
BlnkCorr Peak
Signal Area
0.001 0.094
0.000 0.093
0.000 0.093
0.000
0.000
85.26
Bkgnd Time
Area
0.005 11:27:11
0.006 11:27:13
0.006 11:27:15



Element: Ni    Seq. No.: 396
Sample ID: ccb
AS Loc.
Date: 02/02/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0029
0.0277
-0.0031
0.0092
0.0163
178.0
StndConc
mg/L
0.0029
0.0277
-0.0031
0.0092
0.0163
178.0
BlnkCorr Peak
Signal Area
0.000 0.093
0.001 0.094
0.000 0.093
0.000
0.001
177.97
Bkgnd Time
Area
0.005 11:27:35
0.005 11:27:38
0.006 11:27:40



Element: Ni    Seq. No.:  397
Sample ID: ccv-0.25
AS Loc.
Date: 02/02/2006
Repl
#
1
2
~ 3
Mean:
SD :
%RSD:
Samp
mg/I
0.
0.
0.
0.
0.

>leConc
i
2425
2233
2335
2331
0096
4.11
St
mg
0
0
0
0
0

ndConc
/L
.2425
.2233
.2335
.2331
.0096
4.11
BlnkCorr
Signal
0.009
0.008
0.009
0.009
0.000
4.11
Pe
Ar
0.
0.
0.



ak
ea
102
101
102



Bk
Ar
0
0
0



gnd
ea
.006
.006
.006



Time

11:28
11:28
11:28





:01
:03
:05



                                         Page  105

-------
Prep Method,"      (check only one per page)  - -
     ICP/FLAA:  SM 3030 E^PA 200.7 '82
     1CP/FLM:  EPA 2pd!s, SW-846 3010A
     ICP/FLAA:  EPX200.7r4.4
     |CP/FLAA;ydW-846 3005A
     ICP/FLA#C  SW-846 3015A MICROWAVE
     OTHE
GFAA:
GFAA: SPA 200's, SW-846 3020A
      EPA 200.9
      SW-846 3015A (NoHCL) MICROWAVE
OTH ER:	;	_
MATRIX;             (check only one per page)

DRINKING WATER




1


2
3
4
5
6
7
8
9
10
11
12

Set
Inifl
L^

















Set
date
^
















Set
time
$
















Lab#


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&* / #*s ^ /Z-/
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Smp#

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L?
^
/(x
/^
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/^
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AQUEOUS
Company
LFB
LRB

USS3«P
LFM









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OTHER:

Aliquot
(mis)


I^IL





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/

Final
(mis)




































Mcr
Vsl#
€>
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^
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*



                                                                                 Analyst:

                                                                               Start Date:
                                                                                                  S\QA FORMS \FM-041 \R02 \LK
                                                                                                              Page 1 of 1

-------
 Prep M©fhod: •    (check only one per page)
ICP/FLAA: SM 3Q3Qtf~EPA 200.7 '82
ICP/FLAA: EPA 3do's, SW-846 301OA
ICP/FLAA: EBA 2O0.7 r4.4
!CP/FLAAySW-846 3005A
ICP/FLAX: SW-846 3015A MICROWAVE
OTHE
                                              GFAA:
                                              GFAA:yPA 200's, SW-846 3020A
                                              GFAA! EPA 200.9
                                                    SW-846 3015A (NoHCL) MICROWAVE
                                                HER:	:	
 IVIATRIX:            (check only one per page)
     DRINKING WATER                    I    lAQUEOUS
                                                                   OTHER:
      Set
      Init'I
       Set
       date
           Set
          time
Company
Aliquot
 (mis)
Final
(mis)
 Mcr
Vslf
                                              LFB
                                                                                                      3.
                                                                                                      \0
it
           ^ ..'),
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                 o
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            o
                 o
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                                    4
 8
        •£2.
                             7
        ii.
                                    )0
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11
                               Us
12
                                                  ii
                                                                                                      O
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
sp\




LOT#
A~fl£>ka.




                                                                          Analyst:

                                                                        Start Date:
                                                                                         S\QA FORMS \FM-041 \R02 UK
                                                                                                    Page 1 of 1

-------
                                                                                           Self |
Prep Method:      (check only one per page)  - -
     ICP/FLAA:  SM 3030 F, EPA 200.7 '82
     ICP/FLAA:  EPA 200's, SW-846 3010A
     ICP/FLAA:  EPA 200.7 r4.4
     ICP/FLAA:  SW-846 3005A
     ICP/FLAA:  SW-846 3015A MICROWAVE
     OTHER:     ;	.	
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: -EPA 200.9
 FAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:	:	
MATRIX:            {check only one per page)
     DRINKING WATER                           AQUEOUS
                           OTHER:
SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
Cfa)
*



LOT*
£>.5"H OL^a.




                                                                               Analyst: _

                                                                              Start Date:
                                                                                                S\QA FORMS \FM-041 \R02 \LK
                                                                                                           Page 1 of 1

-------
PROJECT  #  2005110201:   METHOD 306A  FOR  NICKEL
     Samples that read  ,,
PH
<2.0
<2.0
<2.0
<2.0
»k42:0 * -
Sample
Fraction
385.0
371.0
390.0
322.0
/^",
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
. - HNOSt
Analytical
Fraction
50.0
50.0
50.0
50.0
':, 50.0xj/;;
7
Nl mg/L
0.612
0.400
0.547
'V~ j,0.0f4
0.075
8
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.031
0.020
0.027
j 
-------
QA/QC WORK SHEET for NICKEL
F' AA METHOD SOP MET-040
    5100 AA
 1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
 2 INSTRUMENT SET-UP:
                                                              Date:   1/5/2006
                                                            Analyst:   LK
  (For Specific instrument settings, see current copy of method.)
3 CALIBRATION:
      (Mg/U
 IDL= 0.027
MDL= 0.075
 RL = 0.10
LDR = 0.10 to 8.0
                                        4 STANDARD TRACEABILITY
Cai Curve:





Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.226
0.488
1.022
2.072
4.968
0.9998
% Rec.
90.5
97.6
102.2
103.6
99.4

                                          QC STANDARD
                                          Calibration
                                          CCV CRA, AAT
                                          QCS, LFM
                                                      Standard Name, Company, & Lot #
                                                      CPI QC-21 41M044
                                                      CPI QC-21 41M044
                                                      CPI 05F011
ff SAMPI ,,F ANALYTICAL RUN
MAT-
RIX
306
121
121
121
121
121
121
121
SAMPLE
CCV
QCS
CCV
CCB
CRA
CRA
CRA
LRB
201-3
CCV
LRB
LFB
SPK
SER OIL
325-2
325-3
034-1
034-2
034-3
CCV
STD CONC
5.00
2.00
10.00
0.05
0.10
0.25
0.50
0.80
1.00
2/10
2.00
READING
Mg/L
4.975
2.080
9.137
-0.051
0.025
0.082
0.229
-0.023
1.067
0.617
1.509
0.336
0.547
0.051
0.584
-0.030
0.762
0.036
0.045
1.033
0.226
0.271
-0.014
0.054
0.083
0.158
0.155
-0.020
2.173
0.004
BLK
-0.061
-0.004
-0.028
-0.021
-0.043
-0.006
0.009
0.043
-0.001
0.000
0.036
0.036
0.031
-0.005
-0.001
0.009
0.029
0.005
0.006
0.008
0.029
0.032
0.008
0.010
0.005
0.000
RESULT
4.975
2.080
9.137
0.010
0.028
0.110
0.250
0.020
1 073
0.612
0.576
1.500
0.293
0.547
0.015
0.548
-0.062
0.766
0038
0.036
1.004
0.221
0.265
-0.023
0.024
0.150
0.146
-0.025
2.173
0004
D1L1
1 0
1.0
1.0
-To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
OIL 2
1 0
1.0
1.0
~0
.0
1.0
1.0
1.0
-To
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0

QC
RESULTS
100
104
91
0.010
57
110
100
0.020
107
110
-0.062
96
10.0
109
0004

Mg/L
0.015
0.038
0.265 /
-0.023 /
0.024 /
0.146\
-0.025X
\

REP'T
mg/L
0.074
0.074
> \
0.265
0.074
0.074
0.146
0.074
,
ICP
— .- C'tS 2~-
, 9^ '1
0.064
V
0.288 N
, -0.002
\ 0.049
i 0.176
j 0.001 /
95-1 05%R 5
95-105%R)
90-1 10%R)
< MDL }
70-1 30%R)
70-130%R )
70-1 30%R)
< MDL )
80-1 20%R)
<10 RPD, IF SA > 20X MDL)
80-1 20%R)
<10%DIFF)
(< MDL )
(90-110%R)
(< MDL )
! W1-120%R)
(«10 RPD, IF SA > 20X MDL)
! »">-120%R)
(<10%DIFF)
y*-
/
( 90-11 0%R )
(< MDL )

-------
Method Name:  NI
Method Description: Nickel

Date: 01/05/2006      ,
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 15
Sample Info File: Untitled
                                Element:  Ni
                                Calibration Equation: Zero Intercept: Linear
                                Slit Width: 0.20 nm
                                Energy: 70
                                Results Data Set:
Element: Ni    Seq. No.: 1
Sample ID: Calib Blank
                                  AS Loc.
                                                 Date: 01/05/2006
Repl
#
i
-L
0
C*
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
-0.056
-0.056
-0.056
-0.056
0.000
0.14
Peak
Area
-0.056
-0.056
-0.056



Bkgnd
Area
0.143
0.143
0.143



Time
11:29:20
11:29:22
11:29:24



Auto-zero performed.
Element: Ni    Seq. No.: 2
Sample ID: Calib Blank
                                  AS Loc.
                                                 Date: 01/05/2006
Repl
1
2
3

Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
-0.069
-0.076
0.083
-0.020
0.090
439.78
Peak
Area
-0.124
-0.131
0.028



Bkgnd
Area
0.200
0.208
0.050



Time
11:36:48
11:36:50
11:36:52



Auto-zero performed.
Element: Ni     Seq. No.:  3
Sample ID: Calib Blank
                                  AS  Loc.
                                                  Date:  01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
0.155
0.155
0.155
0.155
0.000
0.03
Peak
Area
0.079
0.079
0.079



Bkgnd
Area
0.000
0.000
0.000



Time
11:36:55
11:36:58
11:37:00



Auto- zero performed.
                                            Page 1

-------
Element: Ni    Seq. No.:  4
Sample ID: Calib Blank
                                  AS Loc.
                                                 Date: 01/05/2006
       SampleConc
       mg/L
Repl
 #
 1
 2
 3
Mean:
SD   :
%RSD:
Auto-zero performed
                  StndConc
                  mg/L
BlnkCorr
 Signal
  0.000
  0.000
  0.000
  0.000
  0.000
 769.44
                                        Peak
                                        Area
                                        0.079
                                        0.078
                                        0.079
                                                Bkgnd
                                                Area
                                                  0.000
                                                  0.000
                                                  0.000
 Time

11:37:05
11:37:09
11:37:11
Element: Ni     Seq. No.:  5
Sample  ID: Calib Blank
                                  AS Loc.
                                                 Date:  01/05/2006
Repl
       SampleConc  StndConc
       mg/L        mg/L
 1
 2
 3
Mean:
SD  :
%RSD:
Auto-zero performed.
                              BlnkCorr
                               Signal
                                0.000
                                0.000
                                0.000
                                0.000
                                0.000
                               446.30
                                        Peak
                                        Area
                                        0.079
                                        0.078
                                        0.078
                                                 Bkgnd
                                                 Area
                                                  0.000
                                                  0.000
                                                  0.000
                             Time

                             11:37:16
                             11:37:18
                             11:37:20
 Element:  Ni    Seq.  No.:  6
 Sample ID:  CAL STD
                                   AS Loc.
                                                  Date:  01/05/2006
                              .BlnkCorr
                               Signal
                               -0.160
                               -0.161
                               -0.162
                               -0.161
                                0.001
                                 0.67
                                         Peak
                                         Area
                                        -0.081
                                        -0.083
                                        -0.084
Bkgnd
Area
0.168
0.170
0.171
Time

13,: 37: 55
11:37:57
11:38:00
Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1
 2
 3
Mean:
SD   :

Nfcalibration because standard abs.' and cone, values are not in the same order.
Standard number 1 not applied. []
 Element: Ni    Seq. No.: 7
 Sample ID: Calib Blank
                                   AS Loc.
                                                  Date: 01/05/2006
        SampleConc
        mg/L
 Repl
  #
  1
  2
  3
 Mean:
 SD   :
 %RSD:
 Auto-zero performed.
                    StndConc
                    mg/L
 BlnkCorr
  Signal
  -0.172
  -0.172
  -0.172
  -0.172
   0.000
     0.04
                                         Peak
                                         Area
                                        -0.093
                                        -0.093
                                        -0.093
                                                  Bkgnd
                                                  Area
                                                   0.170
                                                   0.170
                                                   0.169
  Time

 11:38:17
 11:38:19
 11:38:21
                                             Page 2

-------
===	                            _ _____         01/05/2006
Element: Ni    Seq. No.: 8        AS LOG..
Sample ID: Calib Blank               	
                                                 Bkgnd    Time
                                                 Area
                                                   0.169   11:38:30
                                                   0.169   11:38:32
                                                   0.170   11:38:34
Repl
#
I
0
3
Mean
SD
%RSD
SampleConc StndConc
mg/L mg/L


.
.
.
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
91.65
Peak
Area
-0.093
-0.093
-0.094



Auto-zero performed.
                                   AS  Loo.:  —    Date:  01/05/2006

 Sample  ID:  CAL STD                     ____________________________

 Repl    slmpleconc  StndConc  BlnkCorr   Peak     Bkgnd    Time

  *     -"        -"1       SJ?SS    -o"B5    "?172  .1:33:50
  J                             0.009    -0.085     0.172  11:38:52
  3                             0.009    -0.085     0.172  11:38:54
 Mean:
 SD  :                           0.000
 %RSD:                            1.45
 Standard number 1 applied.  [0,25]                 en ^~. n n^4Q
 Correlation Coefficient:  1.0000                 Slope. 0.0349
                   T No.: 10       AS Loc.: —   Date: 01/05/2006
 Sample ID: cal std 2                 _____________________________

 Repl   SampleConc  StndConc  BlnkCorr   Peak     Bkgnd    Time
                                        _

  i                             0,019   -0.075     0.172  11:39:30
  3                             0.019   -0.075     0.172  11:39:32
 Mean:                          0.019
 SD   :                          °-000
 %RSD:                           °'23
 Standard number 2 applied.  [0.50]
 Correlation Coefficient:  0.9957                  Slope:  0.0371
          M    Seq. No.:  11       AS  Loc.:—    Date:  01/05/2006
 Sample ID: cal std 3

 Repl   SampleConc  StndConc   BlnkCorr   Peak     Bkgnd    Time
  ,     _/L        »9/L        Signal    _A».<     Area^  ^^

  ,                              0.039    -0.054      0.173  11:40:03
  3                              0.039    -0.054      0.173  11:40:05
 Mean:                           0.039
 SD   :                           °-°00
 %RSD:                            O-30
 Standard number  3  applied.  [1.00]
 Correlation  Coefficient:   0.9981                 Slope: 0.0388
                                             Page 3

-------
Element: Ni Seq. No.: i:
Sample ID: cal std 4
Repl SampleConc StndCon>
# mg/L mg/L
1
2
3

Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient:
	 — , 	 =
2 AS LOG. : 	
c BlnkCorr Peak
Signal Area
0.080 -0.013
0.080 -0.014
0.079 -0.014
0 080

0. 000
0.58
[2.00]
0.9995

Date: ui/uo/^uuu
Bkgnd Time
Area
0.173 11:40:32
0.173 11:40:35
0.173 11:40:37




Slope: 0.0396
t-v j_ . ni/nc:/Of\n£
Element: Ni     Seq.  No.:  13       AS Loc.
Sample ID: cal  std 5

Repl
 #
 1
 2
 3
Mean
SD
%RSD.
Standard number 5 applied.  [5.00]
Correlation  Coefficient:   0.9998
                                                   Date:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
0.190
0.193
0.191
0.191
0.002
0.82
Peak
Area
0.097
0.100
0.097



Bkgnd
Area
0.175
0.175
0.175



Time
11:41:03
11:41:05
11:41:07



Slope: 0.0385
               o>
               u
               (0
                     0.20
                     0.15
                     0.10
                      0.05
                                               Concentration
                                              Page 4

-------
Calibration data for Ni
       Standard ID
       Calib Blank
         CAL STD
        cal std 2
        cal std 3
        cal std 4
        cal std 5
Mean Signal
(Absorbance)
   0,000
   0.009
   0.019
   0.039
   0.080
   0.191
   Entered      Calculated
Concentration Concentration
    (mg/L)         (mg/L)
     	         0.000
     Correlation Coefficient:  0.99976
     0.25
     0.50
     1.00
     2.00
     5.00
 Slope:
0.2263
0.4880
 .022
 ,072
 .968
                                                   0.03850
Standard
Deviation
0.0001
0.0001
0.0000
0.0001
0.0005
0.0016

%RSD
91.6515
1.4487
0.2288
0.2985
0.5762
0.8188
Element: Ni     Seq.  No.:  14
                                  AS  Loc.
                                                  Date:  01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
4.993
4.941
4.991
4.975
0.0293
0.59

StndConc
mg/L
4.993
4.941
4.991
4/975
0.0293
0.59

BlnkCorr
Signal
0.192
0.190
0.192
0.192
0.001
0.59

Peak
Area
0.099
0.097
0.099




Bkgnd
Area
0.175
0.175
0.174




Time
11:41:21
11:41:23
11:41:25




                     No.:  15
                                   AS Loc.
                                                  Date:  01/05/2006
Repl
#
i
-L
0
<£.
3
Mean:
.SD :
%RSD:
SampleConc
mg/L
2.084
2. 074
2.083
2.080
0.0057
0.27
StndConc
mg/L
2.084
2.074
2.083
2.080
0.0057
0.27
BlnkCorr
Signal
0.080
0
0
0
0

.080
.080
.080
.000
0.27
Peak
Area
-0.013
-0.
-0.



014
013



Bkgnd
Area
0.173
0.
0.



173
174



Time
11:41:
11:
11:



41:
41:



47
49
51



                     No.: 16
                                   AS Loc.:  	
                                                  Date: 01/05/2006
Repl
#
1
JL
Sample
o
£*
Sample
Q
O
Sample
Mean:
SD :
arjqn •
O i\KJ LJ .
Sample
SampleConc
mg/L
9 . 064
absorbance
9. 159
absorbance
9. 187
absorbance
9.137
0.0644
0.71
absorbance
S
m
is
is
is



is
tndConc
g/L
9.064
greater
9.159
greater
9.187
greater
9.137
0.0644
0.71
greater
Blnk'
Sig:
0.
than
0.
than
0.
than
0.
0.
0
than
Corr
rial
349
that
353
that
354
that
352
002
.71
that
Pe
Ar
0.
of
0.
of
0.
of



of
ak
ea
256
the
259
the
260
the



the
Bkgnd
Area
0.17
highest
0.17
highest
0.17
highest



highest
6
st
6
st
7
st



st
Time
11:42:
andard.
11:42:
andard.
11:42:
andard.



:andard.
13
15
17





                                             Page 5

-------
                   No.: 17
                                 AS LOG.
                                                Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:

ID: ccb
SampleConc
mg/L
-0.0624
-0.0536
-0.0673
-0.0611
0.0070
11.39
===========— ~

StndConc
mg/L
-0.0624
-0.0536
-0.0673
-0.0611
0.0070
11.39


BlnkCorr
Signal
-0.002
-0.002
-0.003
-0.002
0. 000
11.39


Peak
Area
-0.096
-0.095
-0.096





Bkgnd
Area
0.171
0.171
0.172





Time
11:43:44
11:43:46
11:43:48


_

                    No.:  18
                                 AS  Loc.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ecu
SampleConc
mg/L
-0.0525
-0.0570
-0.0445
-0.0514
0.0063
12.33
StndConc
mg/L
-0.0525
-0.0570
-0.0445
-0.0514
0.0063
12.33
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0. 000
12.33
Peak
Area
-0.095
-0.096
-0.095



Bkgnd
Area
0.171
0.171
0.170



Ti
11:
11:
11:



me
45:
45:
45:



51
53
55



Element: Ni    Seq.
Sample ID: Sample
                    No.: 19
Repl
       SampleConc  StndConc
       mg/L        mg/L
 1      -0.0485    -0.0485
Auto-zero performed.
                                  AS Loc.:  	
BlnkCorr   Peak
 Signal    Area
 -0.002   -0.095
                                                 Date:  01/05/2006
Bkgnd    Time
Area
 0.170  11:46:00
Element: Ni    Seq. No.: 20
                                  AS Loc.
                                                 Date: 01/05/2006
sample .
Repl i
# '1
1
2
3
Mean :
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
ng/L
-0.0030
-0.0078
0.0000
-0.0036
0.0039
109.9
: Ni Seq
ID: 0.05 pp
SampleConc
mg/L
0.0273
0.0198
0.0271
0.0247
0.0043
17.24
StndConc
mg/L
-0.0030
-0.0078
0.0000
-0.0036
0.0039
109.9
. No. : 21
m
StndConc
mg/L
0.0273
0.0198
0.0271
0.0247
0.0043
17.24
BlnkCorr
Signal
0.000
.0 . 000
0.000
0.000
0.000
109.95
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.24
Peak
Area
-0.095
-0.096
-0.095

Loc. : 	

Peak
Area
-0.094
-0.095
-0.094



Bkgnd
Area
0.171
0.171
0.171

Date:
	
Bkgnd
Area
0.172
0.172
0.172



Time
11:46:12
11:46:14
11:46:16

01/05/2006
	 , 	 , 	 — 	 '
Time
11:46:43
11:46:45
11:46:47



                                            Page 6

-------
Element: Ni    Seq.  No.: 22
                                  AS LOG.
                                                 Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
T?1 ornf^n
ID: ccb
SampleConc
mg/L
-0.0356
-0.0158
-0.0321
-0.0279
0.0106
37.97
t- ; Ni Sec

StndConc
mg/L
-0.0356
-0.0158
-0.0321
-0.0279
0.0106
37.97
r. No. : 23

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
37,97
AS

Peak
Area
-0.097
-0.096
-0.097



LOG. : 	

Bkgnd
Area
0.171
0.171
0.171



Date:

Time
11:47
11:47
11:47




:05
:07
:09


	
01/05/2006
 Sample  ID:  0.10 ppm
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0813
0.0829
0.0829
0.0823
0.0009
1.10
StndConc
mg/L
0.0813
0.0829
0.0829
0.0823
0.0009
1.10
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
1.10
Peak
Area
-0.092
-0.092
-0.092



                                                  Bkgnd
                                                  Area
                                                   0.171
                                                   0.171
                                                   0.171
 Time

11:47:35
11:47:38
11:47:40
 Element: Ni    Seq.  No.: 24
                                   AS Loc.
                                                  Date: 01/05/2006
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0186
-0.0233
-0.0207
-0.0208
0.0023
11.27

StndConc
mg/L
-0.0186
-0. 0233
-0.0207
-0.0208
0.0023
11.27

BlnkCorr Peak
Signal Area
-0.001 -0.096
Ofini — n OQ 6
»UUJ- \j • 
-------
Element: Ni    Seq. No.: 26
Sample ID: ccb
                                  AS LOG.
                                                 Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0408
-0.0439
-0.0443
-0.0430
0.0019
4.45
StndConc
mg/L
-0.0408
-0.0439
-0.0443
-0.0430
0.0019
4.45
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
4.45
Peak
Area
-0.097
-0.097
-0.097



                                                 Bkgnd
                                                 Area
                                                  0.169
                                                  0.169
                                                  0.169
 Time

11:50:50
11:50:52
11:50:54
Element: Ni     Seq. No.:  27
                                  AS  LOG.
                                                  Date:  01/05/2006
aampxe
Repl
#
1
2
3
Mean:
SD :
%RSD:

j.u . -LJ-J-I
SampleConc
mg/L
-0.0273
-0.0226
-0.0198
-0.0232
0.0038
16.26

StndConc
mg/L
-0.0273
-0.0226
-0.0198
-0.0232
0.0038
16.26

BlnkCorr
Signal
-0.001
-0,001
-0.001
-0.001
0.000
16.26

Peak
Area
-0.096
-0.096
-0.096




Bkgnd
Area
0.170
0.170
0.169




Ti:
11:
11:
11:



-1 /AC
me
51:
51:
51:



/or
41
44
46



lAC
 Element:  Ni    Seq.  No.:  28
                                   AS Loc.
Ddmp-LC:
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0.0071
-0.0078
-0.0021
-0.0057
0.0031
55.13
StndConc
mg/L
-0.0071
-0 . 0078
-0.0021
-0.0057
0.0031
55.13
BlnkCorr Peak
Signal Area
0.000 -0.096
On nn — n OQfi
. U U U \j * \J ^ \J
0.000 -0.095
0.000
0.000
55.13
Bkgnd Time
Area
0.167 11:52:23
0.167 11:52:25
0.167 11:52:27



                     No.: 29
                                   AS Loc.
                                                  Date: 01/05/2006
Repl
# :
1
-L
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1 . 073
1.073
1.054
1.067
0.0110
1.03
StndConc
mg/L
1.073
1.073
1.054
1.067
0.0110
1.03
BlnkCorr Peak
Signal Area
0.041 -0.054
0.041 -0.054
0.041 -0.055
0.041
0.000
1.03
Bkgnd Time
Area
0.169 11:52:49
0.170 11:52:51
0.170 11:52:53



                                             Page 8

-------
                         30
                                 AS LOG.
                                                Date:  01/05/2006
Repl SampleConc
# mg/L
1 -0.0330
2 -0.0349
3 -0.0403
Mean: -0.0361
SD : 0.0038
%RSD: 10.49
Element : Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 -0.0466
StndConc
mg/L
-0.0330
-0.0349
-0.0403
-0.0361
0.0038
10.49
. No. : 31

StndConc
mg/L
-0.0466
BlnkCorr Peak
Signal Area
-0.001 -0.097
-0.001 -0.097
-0.002 -0.097
-0.001
0.000
10.49
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.097
Bkgnd Time
Area
0.168 11:53:11
0.169 11:53:13
0.168 11:53:15



Date: 01/05/2006

Bkgnd Time
Area
0.169 11:53:21
Auto-zero performed.
Element: Ni    Seq. No.: 32
                                  AS Loc.
                                                 Date: 01/05/2006
Repl
1
7
i£<
3
Mean:
SD :

%RSD:
SampleConc
mg/L
-0.0019
0. 0080
0.0068
0.0043
0.0054
126.0
StndConc
mg/L
-0.0019
0.0080
0.0068
0.0043
0.0054
126.0
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
126.02
Peak
Area
-0.097
-0.097
-0.097



Bkgnd
Area
0.169
0.169
0.168



Time
11:53:
11:53:
11:~"



53:



29
31
33



                    No.: 33
                                  AS Loc.
                                                 Date: 01/05/2006
Repl SampleConc StndConc BlnkCorr Peak Bkgnd Time
& mcr/L mq/L Signal Area Area
? 0 ,106 I 6106 0024 -0.074 0.172 11:54:02
7
3
Mean:
SD :
%RSD:
0.
0.
0.
0.

6184
6210
6167
0054
0.88
0.
0.
0.
0.

6184
6210
6167
0054
0.88
0
0
0
0

.024 -0.073 0.172 11:54:04
.024 -0.073 0.171 11:54:06
.024
.000
0.88
 Element: Ni     Seq. No.:  34
                                  AS Loc.
                                                  Date:  01/05/2006
Repl
#
]_
2
3
Mean:
3D :
%RSD:
SampleConc
mg/L
0. 0512
0.0382
0.0533
0.0476
0.0082
17.21
StndConc
mg/L
0.0512
0.0382
0.0533
0.0476
0.0082
17.21
BlnkCorr Peak
Signal Area
0.002 -0.095
0.001 -0.096
0.002 -0.095
0.002
0.000
17.21
Bkgnd Time
Area
0.166 11:56:01
0.167 11:56:03
0.166 11:56:05



                                            Page 9

-------
Element: Ni Seq.
Sample ID: d201-l
Repl SampleConc
# mg/L
1 0.6243
2 0.6255
3 0.6219
Mean: 0.6239
SD : 0.0019
%RSD: 0.30
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0109
2 0.0099
3 0.0075
Mean: 0.0094
SD : 0.0018
%RSD: 18.89
Element: Ni Seq.
Sample ID: $201-1
Repl SampleConc
# mg/L
1 1.497


3 1.513
Mean: 1.509
SD : 0.0107
%RSD: 0.71
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0422
2 0.0453
3 0.0412
Mean: 0.0429
SD : 0.0022
%RSD: 5.06
No.: 35

StndConc
mg/L
0.6243
0.6255
0.6219
0.6239
0.0019
0.30
No.: 36

StndConc
mg/L
0.0109
0.0099
0.0075
0.0094
0.0018
18.89
. NO. : 37

StndConc
mg/L
1.497
1 R 1 *7

1.513
1.509
0.0107
0.71
. No. : 38

StndConc
mg/L
0.0422
0.0453
0.0412
0.0429
0.0022
5.06
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.024 -0.073
0.024 -0.073
0.024 -0.073
0.024
0.000
0.30
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
18.89
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.058 -0.039
0 Q5Q _Q 039

0.058 -0.039
0.058
0.000
0.71
AS Loc. : 	

BlnkCorr Peak
Signal Area
0. 002 . -0.095
0.002 -0.095
0.-002 -0.096
0.002
0.000
5.06
Date: 01/05/2006

Bkgnd Time
Area
0.170 11:56:34
0.171 11:56:36
0.171 11:56:38



Date: 01/05/2006

Bkgnd Time
Area
0.167 11:58:31
0.167 11:58:34
0.167 11:58:36



Date: 01/05/2006

Bkgnd Time
Area
0.170 11:58:55
0.170 11:58:57

0.169 11:58:59



Date: 01/05/2006

Bkgnd Time
Area
0.167 12:00:03
0.167 12:00:05
0.167 12:00:07



Page 10

-------
Element: Ni    Seq. No.: 39
Sample ID: ser201-l
                                  AS LOG.
                                                 Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.3399
0.3356
0.3309
0.3355
0.0045
1.35
StndConc
mg/L
0.3399
0.3356
0.3309
0.3355
0.0045
1.35
BlnkCorr
Signal
0.013
0.013
0.013
0.013
0.000
1.35
Peak
Area
-0.084
-0.084
-0.084



                                                 Bkgnd
                                                 Area
                                                  0.169
                                                  0.168
                                                  0.169
 Time

12:00:54
12:00:56
12:00:58
Element: Ni    Seq. No.: 40
                                  AS  Loc.
                                                  Date:  01/05/2006
OdXllp-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0031
0.0035
-0.0017
-0.0005
0.0035
751.2
StndConc
mg/L
-0.0031
0.0035
-0.0017
-0.0005
0.0035
751.2
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
751.25
Peak
Area
-0.097
-0.097
-0.097



Bkgnd
Area
0.168
0.168
0.168



Time
12:02:05
12:02:07
12:02:09


- >- 	 ======
                     No.:  41
                                   AS Loc.
                                                  Date: 01/05/2006
Repl
# :
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.4000
n "3 Q Q1
0.3999
0.3999
0.0002
0.04
StndConc
mg/L
0.4000
0 -5QQ7
0.3999
0.3999
0.0002
.0.04
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.015 -0.082 0.171 12:02:30
0.015 -0.082 0.171 12:02:32
0.015 -0.082 0.171 12:02:34
0.015
0.000
0.04
 Element:  Ni    Seq. No.: 42
                                   AS Loc.
                                                  Date: 01/05/2006
Repl
#
i
J,
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0-0023 0.0023 0.000
0
-0
0
0
.0017
.0040
.0000
.0035
9.632E+14
0.
-0.
0.
0.
0017
0040
0000
0035
9.632E+14
0
0
0
0
.000
.000
.000
.000
Peak
Area
-0.097
-0.
-0.


962646678436614
097
097


.50
Bkgnd Time
Area
0.169 12:02:56
0.169 12:02:58
0.169 12:03:01



                                            Page 11

-------
Element: Ni Seq.
Sample ID: 201-3
Repl SampleConc
# mg/L
1 0.5461
2 0,5548
3 0.5406
Mean: 0.5472
SD : 0.0072
%RSD: 1.31
Element: Ni Seq,
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0109
2 0.0361
3 0.0606
Mean: 0.0359
SD : 0.0248
%RSD: 69.20
Element: Ni Seq
Sample ID: 201-4
Repl SampleConc
# mg/L
1 0.0582
2 0.0493
3 0.0462
Mean: 0.0512
SD : 0,0062
%RSD: 12.13
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0361
2 0.0340
3 0.0375
Mean: 0.0359
SD : 0.0017
%RSD: 4.87
No.: 43

StndConc
mg/L
0.5461
0.5548
0.5406
0.5472
0.0072
1.31
. No. : 44

StndConc
mg/L
0.0109
0.0361
0.0606
0.0359
0.0248
69.20
. No. : 45

StndConc
mg/L
0.0582
0.0493
0.0462
0.0512
0.0062
12.13
.No.: 46

StndConc
mg/L
0.0361
0.0340
0.0375
0.0359
0.0017
4.87
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.021 -0.076
0.021 -0.076
0.021 -0.076
0.021
0.000
1.31
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.001 -0.096
0.002 -0.095
0.001
0.001
69.20
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.095
0.002 -0.095
0.002 -0.095
0.002
0.000
12.13
AS Loc.: 	

BlnkCorr Peak
Signal Area
0,001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
4.87
Date: 01/05/2006

Bkgnd Time
Area
0.171 12:03:20
0.171 12:03:22
0.171 12:03:24



Date: 01/05/2006

Bkgnd Time
Area
0.168 12:03:43
0.167 12:03:45
0.166 12:03:47



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:04:07
0.169 12:04:09
0.170 12:04:11



Date: 01/05/2006

Bkgnd Time
Area
0.167 12:04:25
0.167 12:04:28
0.167 12:04:30



Page 12

-------
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.5743
2 0.5901
3 0.5878
Mean: 0.5841
SD : 0.0085
%RSD: 1-46
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0549
2 0.0212
3 0.0181
Mean: 0.0314
SD : 0.0204
%RSD: 65.06
Element : Mi Seq
Sample ID: Irb af
Repl SampleConc
# mg/L
1 -0.0327
o -o 0?76
3 -0.0307
Mean: -0.0303
SD : 0.0025
%RSD: 8.38
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0033
2 -0.0096
3 -0.0007
Mean: -0.0045
SD : 0.0046
%RSD: 100.8
No.: 47

StndConc
mg/L
0.5743
0.5901
0.5878
0.5841
0.0085
1.46
. No . : 48

StndConc
mg/L
0.0549
0.0212
0.0181
0.0314
0.0204
65.06
. No.: 49

StndConc
mg/L
-0.0327
-0.0276
-0.0307
-0.0303
0.0025
8.38
. No.: 50

StndConc
mg/L
-0.0033
-0.0096
-0.0007
-0.0045
0,0046
100.8
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.022 -0.075
0.023 -0.074
0.023 -0.074
0.022
0.000
1.46
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.095
0.001 -0.096
0.001 -0.096
0.001
0.001
65.06
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.098
-0.001 -0.098
-0.001 -0.098
-0.001
0.000
8.38
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
100.81
Date: 01/05/2006

Bkgnd Time
Area
0.167 12:04:54
0.167 12:04:56
0.167 12:04:58



Date: 01/05/2006

Bkgnd Time
Area
0.165 12:05:30
0.167 12:05:32
0.167 12:05:34



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:06:14
0.170 12:06:16
0.170 12:06:18



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:06:40
0.169 12:06:42
0.169 12:06:44



Page 13

-------
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 0.7627
2 0.7591
3 0.7634
Mean: 0.7618
SD : 0.0023
%RSD: 0.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 -0.0033
3 0.0002
Mean: -0.0014
SD : 0.0017
%RSD: 120.8
Element: Ni Seq
Sample ID: 325-1
Repl SampleConc
# mg/L
1 0.0351
9 0. D38Q
• 3 0.0346
Mean: 0.0362
SD : 0.0024
%RSD: 6.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0118
2 0.0047
3 0.0101
Mean: 0.0089
SD : 0.0037
%RSD: 41.92
. No. : 51

StndConc
mg/L
0.7627
0.7591
0.7634
0.7618
0.0023
0.31
. No. : 52

StndConc
mg/L
-0.0012
-0.0033
0.0002
-0.0014
0.0017
120.8
. No. : 53

StndConc
mg/L
0.0351
0. 0389
0.0346
0.0362
0.0024
6.55
. No.: 54

StndConc
mg/L
0.0118
0.0047
0.0101
0.0089
0.0037
41.92
AS :

BlnkCorr
Signal
0.029
0.029
0.029
0.029
0.000
0.31
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
120.80
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
6.55
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
41.92
Loc. : 	

Peak
Area
-0.068
-0.068
-0.068



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Loc. : 	

Peak
Area
-0.096
-0.096
-0.096



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Date: 01/05/2006

Bkgnd
Area
0.171
0.171
0.171



Date:

Bkgnd
Area
0.168
0.168
0.168



Date:

Bkgnd
Area
0.171
0.171
0.171



Date:

Bkgnd
Area
0.169
0.169
0.169




Time

12: 07: 10
12:07:13
12:07:15



01/05/2006

Time
12:07:55
12:07:57
12:07:59



01/05/2006

Time

12:08:17
12:08:19
12:08:21



01/05/2006

Time

12:08:37
12:08:39
12:08:41



Page 14

-------
Element: Mi Seq
Sample ID: d325-l
Repl SampleConc
# mg/L
1 0.0386
2 0.0519
3 0.0455
Mean: 0.0453
SD : 0.0067
%RSD: 14.75
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0281
2 0.0316
3 0.0278
Mean: 0.0292
SD : 0.0021
%RSD: 7.24
Element: Hi Seq.
Sample ID: s325-l
Repl SampleConc
# mg/L
1 1.033
2 1.041
3 1.025
Mean: 1.033
SD : 0.0081
%RSD: 0.78
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0054
2 0.0047
3 O.OQ63
Mean: 0.0054
SD : 0.0008
%RSD: 14.39
. No. : 55

StndConc
mg/L
0.0386
0.0519
0.0455
0.0453
0.0067
14.75
. No. : 56

StndConc
mg/L
0.0281
0.0316
0.0278
0.0292
0.0021
7.24
. No. : 57

StndConc
mg/L
1.033
1.041
1.025
1.033
0.0081
0.78
No.: 58

StndConc
mg/L
0.0054
0.0047
0.0063
0.0054
0.0008
14.39
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.096
0.002 -0.095
0.002 -0.095
0.002
0.000
14.75
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
7.24
AS Loc.: 	

BlnkCorr Peak
Signal Area
0.040 -0.057
0.040 -0.057
0.039 -0.058
0.040
0.000
0.78
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
14.39
Date: 01/05/2006

Bkgnd Time
Area
0.171 12:08:57
0.171 12:08:59
0.172 12:09:01



Date: 01/05/2006

Bkgnd Time
Area
0.168 12:09:38
0.168 12:09:40
0.168 12:09:42



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:10:53
0.170 12tlO:56
0.170 12:10:58



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:12:25
0.169 12:12:27
0.169 12:12:30



Page 15

-------
Element: Ni Seq.
Sample ID: ser325-l
Repl SampleConc
tt mg/L
1 0.2262
2 0.2286
3 0.2296
Mean: 0.2281
SD : 0.0018
%RSD: 0.78
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0069
2 0.0033
3 0.0078
Mean: 0.0060
SD : 0.0024
%RSD: 39.80
Element: Ni Seq.
Sample ID: 325-2
Repl SampleConc
# mg/L
1 0.2673
2 0.2708
: . 3 0.2734
! Mean: 0.2705
SD : 0.0031
%RSD: 1.13
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0111
2 0.0080
3 0.0054
Mean: 0.0082
SD : 0.0029
%RSD: 35.15
No . : 59

StndConc
mg/L
0.2262
0.2286
0.2296
0.2281
0.0018
0.78
No.: 60

StndConc
mg/L
0.0069
0.0033
0.0078
0.0060
0.0024
39.80
No.: €1

StndConc
mg/L
0.2673
0.2708
0.2734
0.2705
0.0031
1.13
No.: 62

StndConc
mg/L
0.0111
0.0080
0.0054
0.0082
0.0029
35.15
AS

BlnkCorr
Signal
0.009
0.009
0.009
0.009
0.000
0.78
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
39.80
AS

BlnkCorr
Signal
0.010
0.010
0.011
0.010
0.000
1.13
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
35.15
Loc. i 	

Peak
Area
-0.088
-0.088
-0.088



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Loc. : 	

Peak
Area
-0.087
-0.087
-0.087



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:12:51
0.169 12:12:54
0.169 12:12:56



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:13:50
0.169 12:13:52
0.169 12:13:54



Date: 01/05/2006

Bkgnd Time
Area
0.171 12:14:08
0.171 12:14:10
0.171 12:14:12



Date: 01/05/2006

Bkgnd Time
Area
0.169 12:14:53
0.169 12:14:56
0.168 12:14:58



Page 16

-------
Element: Ni Seq
Sample ID: 325-3
Repl SampleConc
# mg/L
1 -0.0162
2 -0.0134
3 -0.0134
Mean: -0.0143
SD : 0.0016
%RSD: 11.22
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0281
2 0.0311
3 0.0288
Mean: 0.0294
SD : 0.0015
%RSD: 5.26
Element: Ni Seq
Sample ID: 325-4
Repl SampleConc
# mg/L
1 0.0566
2 0.05.00
3 0.0540
Mean: 0.0536
SD : 0.0033
%RSD: 6.21
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0301
2 0.0262
3 0.0396
Mean: 0.0320
SD : 0.0069
%RSD: 21.55
. No.: 63

StndConc
mg/L
-0.0162
-0.0134
-0.0134
-0.0143
0.0016
11.22
. No.: 64

StndConc
mg/L
0.0281
0.0311
0.0288
0.0294
0.0015
5.26
. No. : 65

StndConc
mg/L
0.0566
0.0500
0.0540
0.0536
0.0033
6.21
. No.: 66

StndConc
mg/L
0.0301
0.0262
0.0396
0.0320
0.0069
21.55
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.098
-0.001 -0.098
-0.001 -0.098
-0.001
0.000
11.22
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.001 -0.096
0.001
0.000
5.26
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.095
0.002 -0.095
0.002 -0.095
0.002
0.000
6.21
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.096
0.001 -0.096
0.002 -0.096
0.001
0.000
21.55
Date: 01/05/2006

Bkgnd Time
Area
0.171 12:15:13
0.171 12:15:15
0.171 12:15:17



Date: 01/05/2006

Bkgnd Time
Area
0.167 12:15:41
0.167 12:15:44
0.167 12:15:46



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:16:07
0.170 12:16:09
0.170 12:16:11



Date: 01/05/2006

Bkgnd Time
Area
0.168 12:16:29
0.167 12:16:32
0.167 12:16:34



Page 17

-------
Element: Ni Seq
Sample ID: 325-5
Repl SampleConc
# mg/L
1 0.0832
2 0.0862
3 0.0794
Mean: 0.0829
SD : 0.0034
%RSD: 4.10
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0104
2 0.0061
3 0.0075
Mean: 0.0080
SD : 0.0022
%RSD: 27.75
Element: Ni Seq
Sample ID: 034-1
Repl SampleConc
# mg/L
1 0.1549
2 0.1577
3 0.1624
Mean: 0.1584
SD : 0.0038
%RSD: 2.38
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0099
2 0.0061
3 0.0127
Mean: 0.0096
SD : 0.0033
%RSD: 34.69
. No . : 67

StndConc
mg/L
0.0832
0.0862
0.0794
0.0829
0.0034
4.10
. No. : 68

StndConc
mg/L
0.0104
0.0061
0.0075
0.0080
0.0022
27.75
. No.: 69

StndConc
mg/L
0.1549
0.1577
0.1624
0.1584
0.0038
2.38
. No.: 70

StndConc
mg/L
O.OQ99
0.0061
0.0127
0.0096
0.0033
34.69
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.003 -0.094
0.003 -0.094
0.003 -0.094
0.003
0.000
4.10
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
27.75
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 -0.091
0.006 -0.091
0.006 -0.091
0.006
0.000
2.38
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.097
0.000 -0.097
0.000 -0.097
0.000
0.000
34.69
Date: 01/05/2006

Bkgnd Time
Area
0.169 12:16:51
0.169 12:16:53
0.169 12:16:55



Date: 01/05/2006

Bkgnd Time
Area
0.168 12:17:17
0.168 12:17:19
0.168 12:17:21



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:17:53
0.170 12:17:56
0.170 12:17:58



Date: 01/05/2006

Bkgnd Time
Area
0.168 12:18:17
0.168 12:18:20
0.167 12:18:22



Page 18

-------
Element: Ni Seq
Sample ID: 034-2
Repl SampleConc
# mg/L
1 0.1518
2 0.1539
3 0.1603
Mean: 0.1553
SD : 0.0044
%RSD: 2.86
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0122
2 0.0061
3 -0.0026
Mean: 0.0052
SD : 0.0074
%RSD: 142.4
Element : Ni Seq
Sample ID: 034-3
Repl SampleConc
# mg/L
1 -0.0182
2 -0.0141
3 -0.0268
Mean: -0.0197
SD : 0.0065
%RSD: 32.83
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0012
2 -0.0023
3 0.0026
Mean: -0.0003
SD : 0.0026
%RSD: 884.5
. No. : 71

StndConc
mg/L
0.1518
0.1539
0.1603
0.1553
0.0044
2.86
. No.: 72

StndConc
mg/L
0.0122
0.0061
-0.0026
0.0052
0.0074
142.4
. No. : 73

StndConc
mg/L
-0.0182
-Q.0141
-0.0268
-0.0197
0.0065
32.83
. No.: 74

StndConc
mg/L
-0.0012
-0.0023
0.0026
-0.0003
0.0026
884.5
AS

BlnkCorr
Signal
0.006
0.006
0.006
0.006
0.000
2.86
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0,000
142.40
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
32.83
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
884.53
Loc. : 	

Peak
Area
-0.091
-0.091
-0.091



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Loc. : 	

Peak
Area
-0.098
-0.098
-0.09-8



Loc. : 	

Peak
Area
-0.097
-0.097
-0.097



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:18:41
0.170 12:18:44
0.170 12:18:46



Date: 01/05/2006

Bkgnd Time
Area
0.167 12:19:08
0.167 12:19:11
0.167 12:19:13



Date: 01/05/2006

Bkgnd Time
Area
0.170 12:19:28
0.169 12:19:30
0.170 12:19:32-



Date: 01/05/2006

Bkgnd Time
Area
0.167 12:19:51
0.167 12:19:53
0.167 12:19:55



Page 19

-------
Element: Ni    Seq.
Sample ID: ccv
No.:  75
                                  AS LOG.
                                                 Date: 01/05/2006
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.165
2.182
2.172
2.173
0.0088
0.41
StndConc
mg/L
2.165
2.182
2.172
2.173
0.0088
0.41
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.083 -0.014 0.169 12:20:13
0.084 -0.013 0.169 12:20:15
0.084 -0.013 0.168 12:20:17
0.084
0.000
0.41
Element: Ni    Seq.
Sample ID: ccb
No.:  76
AS Lo c.
                                                 Date: 01/05/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
-0
0
0

.0082
.0024
.0002
.0035
.0043
122.8
StndConc
mg/L
0
0
-0
0
0

.0082
.0024
.0002
.0035
.0043
122.8
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
122.78
Peak
Area
-0.
-0.
-0.



097
097
097



Bkgnd
Time
Area
0.
0.
0.



166
167
167



12
12
12



:20:34
:20:36
:20:38



                                          Page 20

-------
                                                           if351
                                                           p.
                                                                                             Set*
Prep Method:      {check only one per page)
     ICP/FLAA: SM 3030 F, EPA 200.7 '82
     ICP/FLAA: EPA 200's, SW-846 301OA
     ICP/FLAA: EPA 200.7 r4.4
     ICP/FLAA: SW-846 3005A
     ICP/FLAA: SW-846 3015A MICROWAVE
     OTHER:	
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:	
MATRIX:            (check only one per page)

DRINKING WATER




1


2
3
4
5
6
7
8
9
10
11
12

Set
Inif
u

















Set
date
iltf
















Set
time
II *f

^
^
t----^£-"
£~^. J, ' L^f











Lab#
4^ e>v U

llDluDl














Smp#
'fit*&

/
£
3
*^j













AQUEOUS
Company
LFB
LRB
&
4=R«**» lit
y^ tft>
^











&
OTHER:
' \
Aliquot
(mis)

















Final
(mis)
5/0




\




1
K














'&^ '^^s
'













Mcr
Vsl#



/


(


"







SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
ri>\
" i



LOT#
&T&£* \ \




                                                                               Analyst:

                                                                             Start Date:
                                                                                               S\QA FORMS XFM-041 \R02 \LK
                                                                                                           Page 1 of 1

-------
PROJECT #2005100014:  METHOD
  1         2           34567
29 FOR NICKEL
    8       9         10
11
12
SA#
2
3
1
5
6
4
8
9
7
11
12
10
14
15
13
17
18
16
20
21
19
23
24
22
26
27
25
29
30
28
32
33
31
35
36
34
38
39
37



SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
"s,'jm{3in§ei't ' *
filter- ",'
probe rinse
RUN ID

BLANK


»1
Cond. 18: Tes
#2
Cond. 18: Tes
#3

#1

#2

#3

#1

Cond. 20: Test
#2

#3

#1


#2


#3

' ^ * > r% ^--^
;'-'M0L' -•"

PH
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
•£•:*


Sample
Fraction
(SF = SFA)
296
1 filter
97.5
305
1 filter
100.0
311
1 filter
99.0
334
1 filter
97.0
315
1 filter
101.0
320
1 filter
100.0
313
1 filter
98.0
301
1 filter
96.0
301
1 filter
100.0
297
1 filter
100.0
'299
1 filter
98.0
303
1 filter
97.0
298
1 filter
99.0
^a
'M mer^
100.0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
2Q >
NA '
20
REAGENTS
FOR DIG.
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HN03
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HN03 + H2O2
HF + HNO3
HF + HN03
HN03 + H2O2
HF + HN03
HF + HN03
HNO3 + H2O2
HF + HN03
HF + HN03
HN03 + H2O2
HF + HN03
HF + HNO3
HNO3 + H2O2
HF + HN03
HF + HN03
HNO3,*|i?'p|-
HF -tTHNO^
HF t HN03
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
';S^:2 ,
aB 2 :
8312
Analytical
Fraction
(AF = AFA)
50
100

50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
50
100
'SOI - '
100
Nl mg/L
( Ca1 or Ca2 )
< 0.074
< 0.074
0.109
0.224
< 0.074
< 0.074
0.245
0.380
0.378
0.829
0.229
0.210
< 0.074
3.580
0.172
0.205
0.080
< 0.074
0,100
0.312
0.170
0.299
0.083
< 0.074
0.127
< 0.074
V-0,075
0.075
MGNI
IN INITIAL
SAMPLE
0.004
0.007
0.005
0.022
0.004
0.007
0.012
0.038
0.019
0.083
0.011
0.021
0.004
0.358
0.009
0.021
0.004
0.007
0.005
0.031
0.009
0.030
0.004
0.007
0.006
0.007
0.004
0.008
TOTAL MG
PER RUN
< 0.011
0.028
< 0.011
0.050
0.102
0.032
0.362
0.029
0.011
0.036
0.038
0.012
0.014
0.011
10  Samples that read 
-------
PROJECT # 2005100306:  METHOD 306A FOR NICKEL
                                                                                                   8
SA#
1
2
3
4
5
*
SAMPLE DESCRPTION
Condition 29; Run 1
Condition 29; Run 2
Condition 29; Run 3
Field Blank 0.1 NHN03
Field Blank 5% HNO3 &
10% H202
' MDL
PH
<2.0
<2.0
<2.0
<2.0
<2.0
"<2:0
Sample
Fraction
355.0
356.0
378.0
332.0
288.0
288:0
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
HNO3
, HNCX=r \*
Analytical
Fraction
50.0
50.0
50.0
50.0
50.0
,'V"* '50.0*' '
\» < -
Nl mg/L
15.9
6.51
7.83
^ ': '" A074 ' : :
0.222
" 0.075^
TOTAL WIG Nl
(OR IN INITIAL SAMPLE)
0.795
0.326
0.392
" -y<'». '•'•'•" -^
:•: ••• 0,0.04 v • ••'•""*
0.011
0.004
    Samples that read MDL,.so'that'these affected samples should result as*"< DL"

#8  Is the amount of Nl in the 50 ml aliquot, or the 355 ml original sample, whichever you prefer,
    because they are the MG value will not change. (The volumes have been negated in the calculation.)
                                                                                                        11/7/05LK
                                                                            S/ LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 306
                                                                        XI USEPA/ NICEM/ PROJECT 21 Analytical data/ METHOD 306-2

-------
QA/QC WORK SHEET  for NICKEL
FLAA METHOD SOP MET-040
•"E5100 AA
  i CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
 2 INSTRUMENT SET-UP:
                        Date:
                      Analyst:
11/8/2005
LK
   (For Specific instrument settings, see current copy of method.)
                            (Mg/L)
                        IDL= 0.027
                       MDL= 0.075
                        RL s/aitb
                      LDR =0:16 to 8.0
 3 CALIBRATION:
4 STANDARD TRACEABILITY
Cal Curve:





Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.287
0.568
1.161
2.151
4.885
0.9977
% Rec.
114.8
113.6
116.1
107.6
97.7

                                              QC STANDARD
                                              Calibration
                                              CCV, CRA, AAT
                                              QCS, LFM
                                                           Standard Name, Company, & Lot #
                                                           CPI QC-21 41M044
                                                           CPI QC-21 41M044
                                                           CPI05F011
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
























SAMPLE
CCV
QCS
CCB
CRA
014-1+3
014-1+3
SPK
DUP
SERDIL
014-25+27
014-31+33
014-31+33
014-31+33
014-31+33
014-2
SPK
DUP
SER OIL
306-1
306-1
306-1
306-1
306-1
CCV
CCB
STD CONG
5.00
2.00

0.10


0.75

2/10






1.00

2110





5.00

READING
Mg/L
4.875
2.014
-0.005
0.098
-0.138
-0.130 -
0.612
0.532
0.121
-0.117
-0.245
-0.171
-0.104
-0.120
0.081
1.048
0.999
0.312
29.570
11.960
5.818
3.046
1.688
4.766
0.056
BLK

-0.005

0.044
0.100
-0.100
0.009
-0.055
0.025
-0.072
-0.033
-0.062
0.073
-0.045
0.026
0.015
-0.014
0.075

0.025
0.121
0.008
0.101
0.056

RESULT
4.875
2.019
-0.005
0.054
-0.239
-0.030
0.603
0.588
0.096
-0.045
-0.212
-0.109
-0.177
-0.075
0.055
1.033
1.013
0.237
29.570
11.936
5.697
3.038
1.587
4.710
0.056
DILI




1.0
2.0
1.0
1.0
1.0
1.0
1.0
2.0
2.0
4.0
1.0
1.0
1.0
1.0
1.0
10.0
25.0
50.0
100.0


DIL2




1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0


QC
RESULTS
98
101
-0.005
54


112
2.6
20.2






111
2.0
14.6





94
0.056
Mg/L




-0239
-0.059 /


REP'T
mg/L




r™*^
<0,150 )
v^ ,^f'ff


ICP








(Apparently, cannot expect much better)
-0.045
I -0.212
-0.218
-0.354
-0.301
0.055


<0.100



<0.300
<0.100


£. , o '? 5*







(Apparently, cannot expect much better)
29.570
119.355
142.423
151.900
158.670






159









                                                                                (80-120%R)
                                                                                («--10 RPD, IF SA > 20X MDL)
                                                                                (<10%DIFF7?)
                                                                                80-120%R)
                                                                                <10RPD, IFSA>20XMDL)
                                                                                <10%DIFF??}
                                                                                90-110%R)
                                                                                < MDL)

-------
Element: Ni Seq. No.: 142
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 143
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 144
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
Element: Ni Seq. No.: 145
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto- zero performed.
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.132
0.000 -0.133
0.000
0.001
110.91

AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.005 -0.137
-0.004 -0.137
-0.004
0.000
2.03

AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.136
0.001 -0.135
0.001 -0.136
0.001
0.000
26.84

AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.135
0.001 -0.135
0.001 -0.135
0.001
0.000
11.87

Date: 11/08/2005

Bkgnd Time
Area
0.162 07:54:36
0.162 07:54:38
0.163 07:54:40




Date: 11/08/2005

Bkgnd Time
Area
0.166 07:55:17
0.167 07:55:20
0.167 07:55:22




Date: 11/08/2005

Bkgnd Time
Area
0.165 08:12:50
0.165 08:12:52
0.165 08:12:54




Date: 11/08/2005

Bkgnd Time
Area
0.163 08:19:40
0.163 08:19:42
0.163 08:19:44




Page 37

-------
Element: Ni Seq. No.: 146 AS LOG.: 	
Sample ID: Calib Blank
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.000 -0.135
2 0.000 -0.135
3 0.000 -0.135
Mean: 0.000
SD : 0.000
%RSD: 444.45
Auto-zero performed.
Element: Ni Seq. No.: 147 AS LOG.: 	
Sample ID: CAL STD
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.009 -0.126
2 0.010 -0.125
3 0.009 -0.126
Mean: 0.009
SD : 0.000
%RSD: 4.29
Standard number 1 applied. [0.25]
Correlation Coefficient: 0.9983
Element: Ni Seq. No.: 148 AS LOG.: 	
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.019 -0.116
2 0.018 -0.116
3 0.019 -0.116
Mean: 0.019
SD : 0.000
%RSD: 0.51
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9986
Element: Ni Seq. No.: 149 AS LOG.: 	
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr Peak
# mg/L mg/L Signal Area
1 0.037 -0.098
2 0.038 -0.097
3 0.038 -0.097
Mean: 0.038
SD : 0.001
%RSD: 1.72
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9987
Date: 11/08/2005

Bkgnd Time
Area
0.162 08:20:03
0.162 08:20:05
0.162 08:20:07




Date: 11/08/2005

Bkgnd Time
Area
0.162 08:20:28
0.162 08:20:30
0.161 08:20:32




Slope: 0.0352
Date: 11/08/2005

Bkgnd Time
Area
0.161 08:20:46
0.161 08:20:48
0.161 08:20:50




Slope: 0.0351
Date: 11/08/2005

Bkgnd Time
Area
0.160 08:21:02
0.159 08:21:04
0.159 08:21:06




Slope: 0.0351
Page 38

-------
Element: Ni     Seq.  No.:  150

Sample ID: cal  std 4
AS LOG.
               Date:  11/08/2005
Repl SampleConc StndCon
# mg/L mg/L
1
2
3
Mean :
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient:
c BlnkCorr Peak
Signal Area
0.070 -0.065
0.070 -0.065
0.070 -0.065
0.070
0.000
0.64
[2.00]
0.9996
Bkgnd
Area
0.159
0.160
0.160




Slope:
Time

08:21:25
08:21:27
08:21:29




0.0347
Element: Ni     Seq.  No.:  151

Sample ID: cal  std  5
AS Loc.
                                                  Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.159
0.159
0.159
0.159
0.000
0.11
Peak
Area
0.024
0.024
0.025



Bkgnd
Area
0.161
0.161
0.161



Time

08:21:44
08:21:47
08:21:49



The calibration  curve may not be linear.

Standard number  5  applied.  [5.00]

Correlation Coefficient:   0.9977
               Slope:  0.0326
                                                Ni
              0)
              u
              o
              U)
              .0
                    0.20
                    0.15
                    0.10
                    0.05
                                              Concentration
                                           Page 39

-------
Calibration data for Ni
Entered Calculated
Mean Signal Concentration Concentration Standard
Standard ID (Absorbance) (mg/L) (mg/L) Deviation %RSD
Calib Blank 0.000 	 0.000 0.0002 444.4487
CAL STD 0.009 0.25 0.2870 0.0004 4.2884
cal std 2
cal std 3
cal std 4
cal std 5




Correlation Coefficient
0.019
0.038
0.070
0.159
: 0.99773
0.50
1.00
2.00
5.00
Slope:
0.5682 0.0001 0.5070
1.161 0.0007 1.7235
2.151 0.0004 0.6363
4.885 0.0002 0.1080
0.03261

Element : Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 4.857
2 4.888
3 4.879
Mean: 4.875
SD : 0.0158
%RSD: 0.32
Element: Ni Seq
Sample ID: QCS
Repl SampleConc
# mg/L
1 2.015
2 2.016
3 2.010
Mean: 2.014
SD : 0.0033
%RSD: 0.16
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0025
2 0.0019
3 -0.0194
Mean: -0.0050
SD : 0.0125
%RSD: 250.4
. No.: 152

StndConc
mg/L
4.857
4.888
4.879
4.875
0.0158
0.32
. No.: 153

StndConc
mg/L
2.015
2.016
2.010
2.014
0.0033
0.16
. No. : 154

StndConc
mg/L
0.0025
0.0019
-0.0194
-0.0050
0.0125
250.4
AS

BlnkCorr
Signal
0.158
0.159
0.159
0.159
0.001
0.32
AS

BlnkCorr
Signal
0.066
0.066
0.066
0.066
0.000
0.16
Loc. : 	

Peak
Area
0.023
0.024
0.024



Loc. : 	

Peak
Area
-0.069
-0.069
-0.069



AS LOG. : 	

BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
250.39

Peak
Area
-0.135
-0.135
-0.136



Date: 11/08/2005

Bkgnd Time
Area
0.161 08:22:02
0.161 08:22:04
0.160 08:22:06



Date: 11/08/2005

Bkgnd Time
Area
0.163 08:22:19
0.163 08:22:21
0.163 08:22:23



Date: 11/08/2005

Bkgnd Time
Area
0.162 08:22:39
0.162 08:22:41
0.162 08:22:43



Page 40

-------
Element: Ni Seq
Sample ID: CRA-0.1
Repl SampleConc
# mg/L
1 0.0936
2 0.1051
3 0.0958
Mean: 0.0982
SD : 0.0061
%RSD: 6.20
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0382
2 0.0384
3 0.0548
Mean: 0.0438
SD : 0.0095
%RSD: 21.75
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 -0.1622
2 -0.1306
3 -0.1218
Mean: -0.1382
SD : 0.0212
%RSD: 15.38
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0960
2 0.1061
3 0.0989
Mean: 0.1004
SD : 0.0052
%RSD: 5.16
. No. : 155

StndConc
mg/L
0.0936
0.1051
0.0958
0.0982
0.0061
6.20
. No. : 156

StndConc
mg/L
0.0382
0.0384
0.0548
0.0438
0.0095
21.75
. No. : 157

StndConc
mg/L
-0.1622
-0.1306
-0.1218
-0.1382
0.0212
15.38
. No. : 158

StndConc
mg/L
0.0960
0.1061
0.0989
0.1004
0.0052
5.16
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.132
0.003 -0.132
0.003 -0.132
0.003
0.000
6.20
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.134
0.001 -0.134
0.002 -0.133
0.001
0.000
21.75
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.005 -0.140
-0.004 -0.139
-0.004 -0.139
-0.005
0.001
15.38
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.132
0.003 -0.131
0.003 -0.132
0.003
0.000
5.16
Date: 11/08/2005

Bkgnd Time
Area
0.162 08:23:10
0.161 08:23:13
0.161 08:23:15



Date: 11/08/2005

Bkgnd Time
Area
0.161 08:23:32
0.161 08:23:34
0.161 08:23:36



Date: 11/08/2005

Bkgnd Time
Area
0.182 08:24:09
0.181 08:24:12
0.181 08:24:14



Date: 11/08/2005

Bkgnd Time
Area
0.159 08:24:30
0.159 08:24:32
0.159 08:24:34



Page 41

-------
Element: Ni    Seq. No.: 159
Sample ID: CCB
AS LOG.
                                                 Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0983
0.1120
0.1223
0.1109
0.0120
10.86
StndConc
mg/L
0.0983
0.1120
0.1223
0.1109
0.0120
10.86
BlnkCorr Peak
Signal Area
0.003 -0.132
0.004 -0.131
0.004 -0.131
0.004
0.000
10.86
Bkgnd Time
Area
0.158 08:27:22
0.158 08:27:24
0.158 08:27:26



Element: Ni    Seq. No.: 160
Sample ID: Sample
AS LOG.
               Date: 11/08/2005
Repl   SampleConc  StndConc  BlnkCorr   Peak
 #     mg/L        mg/L       Signal    Area
 1       0.1004     0.1004     0.003   -0.132
Auto-zero performed.
               Bkgnd    Time
               Area
                0.158  08:27:29
Element: Ni    Seq. No.: 161
Sample ID: CCB
                                  AS Loc.
                                                 Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample

Repl
#
1
2
3
Mean:
SD :
%RSD:

SampleConc
mg/L
0.0244
0.0047
0.0111
0.0134
0.0100
74.99
: Nor- --.-.., Seq.
ID: 014-1+a,..

SampleConc
mg/L
-0.1064
-0.1345
-0.1479
-0.1296
0.0211
16.32

StndConc
mg/L
0.0244
0.0047
0.0111
0.0134
0.0100
74.99
No.: 162
X2
X
StndConc
mg/L\
-0.1064
-0.1345
-0.1479\
-0.1296 \
0.0211 '
16.32

BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
74.99
AS


BlnkCorr
Signal
-0.003
-0.004
-0.005
-0.004
s 0.001
\ 16.32
\
Peak
Area
-0.131
-0.132
-0.131



Loc. : 	


Peak
Area
-0.135
-0.136
-0.136




Bkgnd
Area
0.159
0.159
0.158



Date:


Bkgnd
Area
0.170
0.171
0.171




Time

08:27:37
08:27:39
08:27:41



11/08/2005


Time

08:28:09
08:28:11
08:28:13




Element: Ni    Seq. No.: 163
Sample ID: CCB
AS Loc.
Date: 11/08/2005
Repl
. #
,1
2
\
Mean:
SD K.
%RSD:
SampleConc
mg/L
-0.
-0.
-0.
-0.
0.

0958
1025
1017
1000
0037
3.69
StndConc /BlnkCorr
mg/L
-0.
-0.
-0.
-0.
0.

0958
1025
1017 .
100 O/
0037
3. -6 9
/ Signal
/ -0.003
/ -0.003
•' -0.003
-0.003
0.000
3.69
Peak
Area
-0
-0
-0



.135
.135
.135



Bkgnd
Time
Area
0.
0.
0.



161
161
161



08
08
08



:28:49
:28:51
:28:53



                                           Page  42

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: 014-1+3
SampleConc
mg/L
0.6075
0.6089
0.6208
0.6124
0.0073
1.19
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0160
0.0096
0.0016
0.0091
0.0072
79.12
: Ni Seq
ID: 014-1+3
SampleConc
mg/L
0.5500
0.5316
0.5154
0.5323
0.0173
3.26
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0515
-0.0562
-0.0584
-0.0554
0.0036
6.43
. No.: 164
X2 SPK
StndConc
mg/L
0.6075
0.6089
0.6208
0.6124
0.0073
1.19
. No. : 165

StndConc
mg/L
0.0160
0.0096
0.0016
0.0091
0.0072
79.12
. No.: 166
X2 SD
StndConc
mg/L
0.5500
0.5316
0.5154
0.5323
0.0173
3.26
. No.: 167

StndConc
mg/L
-0.0515
-0.0562
-0.0584
-0.0554
0.0036
6.43
AS
BlnkCorr
Signal
0.020
0.020
0.020
0.020
0.000
1.19
AS

BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
79.12
AS

BlnkCorr
Signal
0.018
0.017
0.017
0.017
0.001
3.26
AS

BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
6.43
LOG. : 	
/f^>
Peak
Area
-0.112
-0.112
-0.111



LOG. : 	

Peak
Area
-0.131
-0.131
-0.132



LOG. : 	

Peak
Area
-0.114
-0.114
-0.115



LOG. : 	

Peak
Area
-0.133
-0.133
-0.134



Date: 11/08/2005
uA •^V/'H- //*>
Bkgnd Time
Area
0.170 08:30:39
0.170 08:30:42
0.170 08:30:44



Date: 11/08/2005

Bkgnd Time
Area
0.158 08:31:00
0.158 08:31:02
0.158 08:31:04



Date: 11/08/2005

Bkgnd Time
Area
0.173 08:31:59
0.173 08:32:01
0.172 08:32:04



Date: 11/08/2005

Bkgnd Time
Area
0.160 08:32:24
0.160 08:32:26
0.160 08:32:28



Page 43

-------
Element: Ni Seq
Sample ID: 014-1+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1159
0.1103
0.1368
0.1210
0.0140
11.53
Element: Ni Seq
Sample ID: 014-1+3
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1571
0.1952
0.2223
0.1915
0.0328
17.11
Element: Ni Seq
Sample ID: CCB
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0246
0.0260
0.0236
0.0247
0.0012
5.00
. No.: 168
SER
StndConc
mg/L
0.1159
0.1103
0.1368
0.1210
0.0140
11.53
. No.: 169
SER
StndConc
mg/L
0.1571
0.1952
0.2223
0.1915
0.0328
17.11
. No. : 170
StndConc
mg/L
0.0246
0.0260
0.0236
0.0247
0.0012
5.00
Element: Ni Seq. No.: 171
Sample ID: 014-25+27
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.1021
-0.1148
-0.1325
-0.1165
0.0152
13.09
StndConc
mg/L
-0.1021
-0.1148
-0.1325
-0.1165
0.0152
13.09
AS
Loc . : 	
BlnkCorr Peak
Signal Area
0.004 -0.128
0.004
0.004
0.004
0.000
11.53
AS
BlnkCorr
Signal
0.005
0.006
0.007
0.006
0.001
17.11
AS
BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
5.00
-0.128
-0.127



Loc. : 	
Peak
Area
-0.127
-0.125
-0.124



Loc. : 	
Peak
Area
-0.131
-0.131
-0.131



AS LOG. : 	
BlnkCorr
Signal
-0.003
-0.004
-0.004
-0.004
0.000
13.09
.Peak
Area
-0.135
-0.135
-0.136



Date:
Bkgnd
Area
0.162
0.163
0.162



Date:
Bkgnd
Area
0.160
0.160
0.159



Date:
Bkgnd
Area
0.157
0.157
0.158



11/08/2005
Time
08:33:
08:33:
08:33:



02
05
07



11/08/2005
Time
08:33:
08:33:
08:33:



31
34
36



11/08/2005
Time
08:33:
08:33:
08:33:



54
56
59



Date: 11/08/2005
Bkgnd
Area
0.179
0.179
0.179



Time
08:34:
08:34:
08:34:



35
37
39



Page 44

-------
Element: Ni    Seq. No.: 172
Sample ID: CCB
AS LOG.
               Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2 ,•"
3/
Me.an :
SD :
%RSD:
Element
Sample
Rep\l
# \ /
1 \ /
2 A

'Mean :
jgfo :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0724
-0.0595
-0.0826
-0.0715
0.0116
16.24
: Ni Seq
StndConc
mg/L
-0.0724
-0.0595
-0.0826
-0.0715
0.0116
16.24
. No. : 173
BlnkCorr
Signal
-0.002
-0.002
-0.003
-0.002
0.000
16.24
_S
/ AS
Peak
Area
-0.134
-0.134
-0.134



Loc. : 	
Bkgnd Time
Area
0.161 08:34:54
0.160 08:34:56
0.160 08:34:58



Date: 11/08/2005
ID: 014-31+33 /
SampleConc
mg/L --.
-0.2463
-0.2430
-0.2453
-0.2449 /
0.0017 /
0.69/
: Ni / Seq
ID:/CCB
/
Ej.ampleConc/
mg/L
-0.0502 /
-0.0314/
-0.0168
,.-0.0,328
0"."0168
51.08
: Ni Seq
StndCq.nc
mg/L/
-0.^463
-0, 2430
/0.2453
/-0.2449
0.0017
0.69
j No. : 174

StndConc
mg/L
-0.0502
-0.0314
-0.0168
-0.0328
0.0168
51.08
. No. : 175
BlnkCorr
Signal
-0.008
-0.008
-0.008
-0.008
0.000
0.69
AS

BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.001
51.08
AS
Peak
Area
-0.140
-0.140
-0.140



Loc. : 	

Peak
Area
-0.133
-0.133
-0.132



Loc. : 	
Bkgnd Time
Area
0.186 08:35:31
0.186 08:35:34
0.186 08:35:36



Date: 11/08/2005

Bkgnd Time
Area
0.160 08:35:48
0.160 08:35:51
0.159 08:35:53



Date: 11/08/2005
ID: 014-31+33 X2
SampleConc
mg/L
-0.1678
-0.1850
-0.1593
-0.1707
0.0131
7.66
StndConc
mg/L
-0.1678
-0.1850
-0.1593
-0.1707
0.0131
7.66
BlnkCorr
Signal
-0.005
-0.006
-0.005
-0.006
0.000
7.66
Peak
Area
-0.137
-0.138
-0.137



Bkgnd Time
Area \^
0.175 08:38:2A
0.175 08:38:23\
0.176 08:38:26 \



         Page  45

-------
Element
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0769
-0.0449
-0.0636
-0.0618
0.0161
26.00
: Ni Seq
. No. : 176
StndConc
mg/L
-0.0769
-0.0449
-0.0636
-0.0618
0.0161
26.00
. No.: 177
AS
BlnkCorr
Signal
-0.003
-0.001
-0.002
-0.002
0.001
26.00
AS
Loc.
: 	 Date: 11/08/2005 \ .
Peak
Area
-0
-0
-0



Loc.
.134
.133
.134



Bkgnd
Area
0.160
0.160
0.160



Time

08:38:
08:38:
08:38:



\ 1 V S '
ho, i/^
43 / / f\r
46 /
48 / /
/
/
^/
: 	 Date: 11/08/2005
rs.
ID: 014-31+33 2 M .J\ '
1 1 r,-A-!J¥> 	
SampleConc
mg/L
-0.0972
-0.1185
-0.0970
-0.1043
0.0124
11.87
: Ni Seq
ID: CCB
SampleConc
mg/L
0.1019
0.0765
0.0392
0.0725
0.0316
43.52
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0500
0.0556
0.0474
0.0510
0.0042
8.21
StndConc
mg/L
-0.0972
-0.1185
-0.0970
-0.1043
0.0124
11.87
.No.: 178

StndConc
mg/L
0.1019
0.0765
0.0392
0.0725
0.0316
43.52
. No.: 179

StndConc
mg/L
0.0500
0.0556
0.0474
0.0510
0.0042
8.21
BlnkCorr
Signal
-0.003
-0.004
-0.003
-0.003
0.000
11.87
AS

BlnkCorr
Signal
0.003
0.002
0. 001
0.002
0.001
43.52
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
8.21
Peak
~-?c
-0
-0
-0



Loc.

se^
.135-x
.136
.135



: 	

Peak
Area
-0
-0
-0



Loc.

.128
.129
.130



Bkgnd
Area
0.172
\0.172
""5^172
\
\
\
	 1
Date : 1
__J
Bkgnd /
Area /
0.15B
0.156
0./56
X


Time

08:39:
08:39:
08:39:




\
36
38
40 ,

\
	 \ 	 JLLS -
jl/08/2005 \ (^7 n
1
Time

08:39:
08:40:
08: 40:



i\A _/ ^ .4 1
\ ^ \ fy /
V i \¥
59 \\f
01 rp
03 v



: 	 Date: 11/08/2005

Peak
Area
-0
-0
-0



.130
.130
.130




Bkgnd
Area
0.156
0.157
0.157




Time

08:40:
08:40:
08:40:






18
20
23



Page 46

-------
Element: Ni Seq
. No. : 180
AS Loc. : 	
Date: 11/08/2005
Sample ID: 014-31+33 X4
Repl SampleConc
# mg/L
1 -0.1290
2 -0.1157
3 -0.1181
Mean: -0.1209
SD : 0.0071
%RSD: 5.87
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0509
2 -0.0330
3 -0.0507
Mean: -0.0448
SD : 0.0102
%RSD: 22.84
Element: Ni Seq
Sample ID: 014-2
Repl SampleConc
# mg/L
1 0.0806
2 0.0822
3 0.0785
Mean: 0.0805
SD : 0.0018
%RSD: 2.30
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0049
2 0.0234
3 0.0498
Mean: 0.0260
SD : 0.0226
%RSD: 86.67
StndConc
mg/L
-0.1290
-0.1157
-0.1181
-0.1209
0.0071
5.87
. No.: 181

StndConc
mg/L
-0.0509
-0.0330
-0.0507
-0.0448
0.0102
22.84
. No.: 182

StndConc
mg/L
0.0806
0.0822
0.0785
0.0805
0.0018
2.30
. No. : 183

StndConc
mg/L
0.0049
0.0234
0.0498
0.0260
0.0226
86.67
BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.004 -0.135
-0.004 -0.136
-0.004
0.000
5.87
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.133
-0.001 -0.133
-0.002 -0.133
-0.001
0.000
22.84
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.129
0.003 -0.129
0.003 -0.129
0.003
0.000
2.30
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.131
0.001 -0.131
0.002 -0.130
0.001
0.001
86.67
Bkgnd Time
Area
0.169 08:41:32
0.168 08:41:34
0.168 08:41:36



Date: 11/08/2005

Bkgnd Time
Area
0.159 08:41:55
0.159 08:41:57
0.159 08:41:59



Date: 11/08/2005

Bkgnd Time
Area
0.160 08:42:29
0.160 08:42:31
0.160 08:42:34



Date: 11/08/2005

Bkgnd Time
Area
0.158 08:42:55
0.157 08:42:57
0.157 08:43:00



Page 47

-------
Element: Ni Seq
Sample ID: 014-2 S
Repl SampleConc
# mg/L
1 0.9949
2 1.005
3 0.9961
Mean: 0.9986
SD : 0.0054
%RSD: 0.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0117
2 0.0016
3 -0.0326
Mean: -0.0142
SD : 0.0173
%RSD: 121.4
Element: Ni Seq
Sample ID: 014-2 s:
Repl SampleConc
# mg/L
1 1.057
2 1.044
3 1.043
Mean: 1.048
SD : 0.0080
%RSD: 0.76
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0287
2 0.0121
3 0.0035
Mean: 0.0148
SD : 0.0128
%RSD: 86.84
. No. : 184

StndConc
mg/L
0.9949
1.005
0.9961
0.9986
0.0054
0.54
. No. : 185

StndConc
mg/L
-0.0117
0.0016
-0.0326
-0.0142
0.0173
121.4
. No. : 186
D
StndConc
mg/L
1.057
1.044
1.043
1.048
0.0080
0.76
. No. : 187

StndConc
mg/L
0.0287
0.0121
0.0035
0.0148
0.0128
86.84
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.032 -0.099
0.033 -0.099
0.032 -0.099
0.033
0.000
0.54
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.132
0.000 -0.132
-0.001 -0.133
0.000
0.001
121.41
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.034 -0.097
0.034 -0.098
0.034 -0.098
0.034
0.000
0.76
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.131
0.000 -0.131
0.000 -0.132
0.000
0.000
86.84
Date: 11/08/2005

Bkgnd Time
Area
0.162 08:44:53
0.162 08:44:55
0.162 08:44:57



Date: 11/08/2005

Bkgnd Time
Area
0.159 08:45:09
0.160 08:45:11
0.160 08:45:13



Date: 11/08/2005

Bkgnd Time
Area
0.161 08:45:35
0.161 08:45:37
0.161 08:45:39



Date: 11/08/2005

Bkgnd Time
Area
0.159 08:45:57
0.159 08:45:59
0.159 08:46:02



Page 48

-------
Element: Ni    Seq. No.: 188
Sample ID: 014-2 SER
AS LOG.: 	
               Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.

3187
3136
3029
3117
0081
2.58
StndConc
mg/L
0.
0.
0.
0.
0.

3187
3136
3029
3117
0081
2.58
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
2
010 -0.121
010 -0.121
010 -0.122
010
000
.58
Bkgnd Time
Area
0.156 08:46:59
0.157 08:47:02
0.156 08:47:04



Element: Ni    Seq. No.: 189
Sample ID: CCB
AS LOG.
               Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.

0742
0781
0722
0749
0030
4.04
StndConc
mg/L
0.
0.
0.
0.
0.

0742
0781
0722
0749
0030
4.04
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.
0.
0.
0.
0.
4
002 -0.129 0.157 08:47:18
003 -0.129 0.156 08:47:20
002 -0.129 0.157 08:47:22
002
000
.04
Element: Ni    Seq. No.: 190
Sample ID: 306-1
AS Loc.
Date: 11/08/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
29.56
absorbance
29.58
absorbance
29.58
absorbance
29.57
0.0111
0.04
absorbance
StndConc
mg/L

is

is

is



is
29.56
greater
29.58
greater
29.58
greater
29.57
0.0111
0.04
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
964
that
965
that
965
that
964
000
.04
that
Peak
Area
0.
of
0.
of
0.
of



of
832
the
833
the
833
the



the
Bkgnd
Area


0.177
highest
Time

08:48:


30
standard.
0.177
highest
08:48:
32
standard.
0.177
highest



highest
08:48:
34
standard.









standard.
Element: Ni    Seq. No.: 191
Sample ID: 306-1 X10
AS Loc.
               Date: 11/08/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
11.93
absorbance
12.02
absorbance
11.94
absorbance
11.96
0.0531
0.44
absorbance
StndConc
mg/L
11.93
is
is
is


is
greater
12.02
greater
11.94
greater
11.96
0.0531
0.44
greater
BlnkCorr
Signal
0.389
than
0.
than
0.
than
0.
0.
0
than
that
392
that
389
that
390
002
.44
that
Peak
Area
0.257
of
0.
of
0.
of


of
the
260
the
258
the


the
Bkgnd
Area
0.164
Time
08:55:
highest standard.
0.164 08:55:
highest standard.
0.164 08:55:
highest


highest
00
02
04
standard.






standard.
                                          Page  49

-------
Element: Ni    Seq. No.:  192
Sample ID: CCB
                           AS LOG.
                                                 Date: 11/08/2005
Repl
#
I
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0254
0.0119
0.0361
0.0245
0.0121
49.56
StndConc
mg/L
0.0254
0.0119
0.0361
0.0245
0.0121
49.56
BlnkCorr Peak
Signal Area
0.001 -0.131
0.000 -0.131
0.001 -0.130
0.001
0.000
49.56
Bkgnd Time
Area
0.157 08:56:26
0.158 08:56:28
0.158 08:56:30



Element: Ni    Seq. No.:
Sample ID: 306-1 X25
                  193
                AS LOG.
                                                 Date: 11/08/2005
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   5.781
absorbance
   5.852
absorbance
   5.823
absorbance
   5.818
  0.0357
    0.61
absorbance
 StndConc
 mg/L
   5.781
is greater
   5.852
is greater
   5.823
is greater
   5.818
  0.0357
    0.61
is greater
BlnkCorr
 Signal
  0.189
than that
  0.191
than that
  0.190
than that
  0.190
  0.001
   0.61
than that
 Peak     Bkgnd    Time
 Area     Area
 0.057     0.160  08:56:48
of the highest standard.
 0.059     0.159  08:56:50
of the highest standard.
 0.058     0.159  08:56:52
of the highest standard.
of the highest standard.
Element: Ni    Seq. No.: 194
Sample ID: CCB
                           AS LOG.
                               Date: 11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.1366
0.1337
0.0929
0.1211
0.0244
20.18
StndConc
mg/L
0.1366
0.1337
0.0929
0.1211
0.0244
20.18
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.004 -0.127 0.154 08:57:06
0.004 -0.127 0.153 08:57:08
0.003 -0.129 0.155 08:57:10
0.004
0.001
20.18
Element: Ni    Seq. No.
Sample ID: 306-1 X50
                  195
                AS LOG.
                    Date:  11/08/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.035
3.055
3.049
3.046
0.0104
0.34
StndConc
mg/L
3.035
3.055
3.049
3.046
0.0104
0.34
BlnkCorr Peak
Signal Area
0.099 -0.033
0.100 -0.032
0.099 -0.032
0.099
0.000
0.34
Bkgnd Time
Area
0.160 08:58:18
0.159 08:58:20
0.160 08:58:22



                                           Page  50

-------
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0006
2 0.0160
3 0.0074
Mean: 0.0080
SD : 0.0077
%RSD: 96.38
Element : Ni Seq
. No. : 196

StndConc
mg/L
0.0006
0.0160
0.0074
0.0080
0.0077
96.38
. No. : 197
AS

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
96.38
AS
LOG. : 	

Peak
Area
-0.132
-0.131
-0.131



LOG. : 	
Date: 11/08/2005

Bkgnd Time
Area
0.159 08:58:35
0.159 08:58:37
0.158 08:58:39



Date: 11/08/2005
Sample ID: 306-1 X100
Repl SampleConc
# mg/L
1 1.687
2 1.676
3 1.701
Mean: 1.688
SD : 0.0123
%RSD: 0.73
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.1130
2 0.1169
3 0.0740
Mean: 0.1013
SD : 0.0237
%RSD: 23.40
Element: Ni Seq
Sample ko: CCV
Repl SampleConc/
# mg/L\ /
1 2 . uSfj
2 2.8^2^
3 2./33\
Mean: 2/311 \
SD : 0/4776
%RSD: /20. 67
StndConc
mg/L
1.687
1.676
1.701
1.688
0.0123
0.73
. No. : 198

StndConc
mg/L
0.1130
0.1169
0.0740
0.1013
0.0237
23.40
. No. : 199
s
/-
StndConc
mg/L
2.036
2.862
2.033
2.311
\fl.4776
20.67
BlnkCorr
Signal
0.055
0.055
0.055
0.055
0.000
0.73
Peak
Area
-0.077
-0.077
-0.076



AS LOG. : 	

BlnkCorr
Signal
0.004
0.004
0.002
0.003
0.001
23.40

Peak
Area
-0.128
-0.128
-0.129



ex AS LOG. : — -
V) tury1
BlnkCorr
Signal
0.066
0.093
0.066
0.075
0.016
20.67
WT 3
MPeak
Area
-0.065
-0.038
-0.065



Bkgnd Time
Area
0.157 09:00:56
0.157 09:00:58
0.157 09:01:00



Date: 11/08/2005

Bkgnd Time
Area
0.155 09:01:13
0.155 09:01:15
0.155 09:01:17



Date: 11/08/2005
CiA-j-vA-litLX
Bkgnd Time
Area
0.160 09:02:00
0.133 09:02:02
0.160 09:02:04



"
                                Page 51

-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -1.265
2 0.0057
3 0.0287
Mean: -0.4100
SD : 0.7401
%RSD: 180.5
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0267
2 0.0281
3 0.0090
Mean: 0.0213
SD : 0.0106
%RSD: 49.96

Element: Ni ,/'Seq
Sample ID: CCV
Repl SampleConc
# >g/L
1 / 4.763
2 / 4.753
3 / 4.782
Meap.: 4 . 766
SD / : 0.0145
%R$D: 0.30
Element: Ni Seq,
Sample ID: CCB
Repl SampleConc
# 1 mg/L
11 0.0533
2 \ 0.0708
3 \ 0.0429
Mean\: 0.0556
SD \ 0.0141
%RSD:\ 25.32
. No. : 200

StndConc
mg/L
-1.265
0.0057
0.0287
-0.4100
0.7401
180.5
. No. : 201

StndConc
mg/L
0.0267
0.0281
0.0090
0.0213
0.0106
49.96

. No. : 202

StndConc
mg/L
4.763
4.753
4.782
4.766
0.0145
0.30
. No. : 203

StndConc
mg/L
0.0533
0.0708
0.0429
0.0556
0.0141
25.32
AS

BlnkCon
Signal
-0.041
0.000
0.001
-0.013
0.024
180.50
AS

BlnkCon
Signal
0.001
0.001
0.000
0.001
0.000
49.96
'" 	 - 	 	
AS

BlnkCorr
Signal
0.155
0.155
0.156
0.155
0.000
0.30
AS

BlnkCorr
Signal
0.002
0.002 ,
0.00 1/
0.002
0.-000
,x25 . 32
Loc. : 	

: Peak
Area
-0.173
-0.131
-0.131



Loc. : 	

: Peak
Area
-0.131
-0.131
-0.131




Loc. : ~~-==" — 	 --•

Peak
Area
0.024
0.023
0.024


/
Loc. : / —
/
E*eak
/Area
/-0.130
/ -0.129
-0.130



Date: 11/08/2005

Bkgnd Time
Area
0.172 09:02:21
0.158 09:02:23
0.159 09:02:25



Date: 11/08/2005

Bkgnd Time
Area
0.158 09:02:42
0.158 09:02:44
0.158 09:02:46




.- Date: 11/08/2005

BJcgnd Time
Area
/ 0.160 09:03:03
/ 0.160 09:03:05
' 0.160 09:03:07



Date: 11/08/2005

Bkgnd Time
Area
0.157 09:03:24
0.156 09:03:26
0.156 09:03:29



Page 52

-------
 METALS   PREP    FORM
                                                                Set*
Prep Method:    (check only one per page)
    ICP/FLAA: SM 3030 F, EPA 200.7 '82
    ICP/FLAA: EPA 200's, SW-846 3010A
    ICP/FLAA: EPA 200.7 r4.4
    ICP/FLAA: SW-846 3005A
    ICP/FLAA: SW-846 3015A MICROWAVE
    OTHER:	
                                  GFAA: SM3030E
                                  GFAA: EPA 200's, SW-846 3020A
                                  GFAA: EPA 200.9
                                  GFAA: SW-846 3015A (NoHCL) MICROWAVE
                                  OTHER:   	
MATRIX:         (check only one per page)
   DRINKING WATER    \ \          \   lAQUEOU
                                                      OTHER:
    Set
    Inifl
         Set
        date
Set
time
Lab#
Smp#
Company
Aliquot
 (mis)
Final
(mis)
Mcr
Vsl#
                                   LFB
                                   LRB
                                  I rrnfl ni IP
                                  LI IV! LJ\Jl
 5

10
11
1?
                                             \
GSTDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
/'pl




LOT*
&S^o\\




                                                       Analyst:

                                                      Start Date:
                                                                   S\QA FORMS \FM-041 \R02 \LK
                                                                           Page 1 of 1

-------
QA/QC WORK SHEET for NICKE
FLAA METHOD SOP  MET-040              A
PE5100AA                                      ^1A
                               Date:
11/7/2005
                             Analyst:    LK
 * CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
   INSTRUMENT SET-UP:
   (For Specific instrument settings, see current copy of method.)
 3 CALIBRATION:
                                     (Mcj/U
                               IDL= 0.027
                              MDL= 0.075
                               RL = 0.10
                             LDR = 0.10 to 8.0
4 STANDARD TRACEABILITY
Cal Curve:





Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.324
0.601
1.102
2.144
4.897
0.9981
% Rec.
129.6
120.2
110.2
107.2
97.9

                                                          QC STANDARD
                                                          Calibration
                                                          CCV, CRA, AAT
                                                          QCS, LFM
                                                                            Standard Name, Company, &Lot#
                                                                            CPIQC-21 41M044
                                                                            CPIQC-21 41M044
                                                                            CPI41M044
                                         (> 0.995
5 SAMPLE ANALYTICAL RUN
MAT-
RIX



































SAMPLE
CCV
QCS
CCB
CRA
CRA
LRB
LFB
014-1+3
SPK
DUP
SER DIL
CCB
CCV
014-4+6
014-7+9
014-10+12
014-13+15
014-16+18
014-19+21
CCB
CCV
014-22+24
014-25+27
014-28+30
014-31+33
014-34+36
014-37+39
CCB
CCV
LRB
LFB
014-2
SPK
DUP
SER DIL
CCB
CCV
STD CONG
500
200

0.25
0.10

3.50

3 5

3/10

1.00







050
'
t
\g/T
\?)/
wr
— T 	

200

200

4.0

5/10

5 00
READING
Mg/L
4 958
2.125
0.050
0323
0.178
0.043
3 337
-0.162
3.418
3469
1 082
0.010
0.921
0.241
-0.066
0.398
0.772,
0.247
3.526
-0.054
^ 0.465
i 0.133
*&> -0.168
0.272^
~X-0 168 )
-0.057
-0.124
0.015
2004
0080
1.876
0018
4.178
4239
2.494
-0075
4693
BLK
0.050
0.050

0039
0.090
0018
0.017
0013
0.104
-0.014
0.111
-0.049
-0.049
0.017
-0.045
0018
-0.058
0.038
-0 054
0.029
0029
-0.072
0.028
-0.040
0.011
-0.037
-0.077
-0062
-0.062
0026
0.026
0.012
-0.047
-0085
-0.074
-0.074
0 033
RESULT
4.909
2.076
0.050
0.284
0.088
0.025
3320
-0.175
3.314
3.483
0.971
0059
0969
0.224
-0.021
0.380
0.829
0.210
3.580
-0.083
0.436
0.205
-0.196
0.312
-0.180
-0019
-0046
0.077
2.066
0.054
1.850
0.007
4.225
4.324
2.568
-0.001
4.660
D1L1







1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0




1.0
1.0
1.0
1.0


DIL 2







1.0
10
10
10


10
10
1.0
1.0
10
1.0


10
1.0
1.0
1.0
1.0
1.0




1.0
1.0
10
10


QC RESULTS
98
' • 104
•0.050
114
88
0.025
95

100
5.0
24
0.010
97






-0.054
^ -87






0.015
103
0.054
93

105
2.3
' |1 0
(•0,075
93

Wlg/L







• -0.175

.,-- . O J aj



0.224
-0.021
0.380
0.829
0.210
3.580


REP'T
mg/L






^
 . lS~a



0.224
<0.100
0.380
0.829
0.210
3.580

See explanation below
0.205
j. -Q/M. -;
0.312
-0.180 ,-
-0.019
-0.046




0.007





0.20§
<^foo
0.312
*/5

- , 3t> /






, CJ> -5





                                                                                                     ;95-105%R)

                                                                                                     (95-105%R)

                                                                                                     {< MDL )

                                                                                                     (70-130%R)

                                                                                                     (70-130%R)

                                                                                                     (« MDL )

                                                                                                     (80-120%R)
                                                                                                     {< MDL )

                                                                                                     (90-110%R)


                                                                                                     iff.
                                                                                                     (< MDL )

                                                                                                     (90-110%R)

                                                                                                       MDL )

                                                                                                     (80-120%R)
                                                                                                     (80-120%R )

                                                                                                     (<10RPD, IFSA>

                                                                                                     (<10%DIFF)

                                                                                                     {< MDL)

                                                                                                     (90-110%R)
  The CCV at 0.50 ppm was low for indicated limits which is from SM 3111B. The previous CCV and following CCV were within limits. The limits for EPA is +/- 20%, for which
  this would be acceptable. In view of these observations, the CCV being out of limits appears to be an isolated occurrance and does not reflect on the degradation of the
  curve Therefore no corrective action was taken at this point.  	-.?=—•*>.
                                         -""•"'     "*
        RERUN:
                       Due to failed SER \
                       Due to failed SER (see^p?)

-------
QA/QC WORK SHEET for NICKEL  p2
FLAA METHOD SOP MET-040
PE5100 AA
i CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
  'NSTRUMENT SET-UP:
  (For Specific instrument settings, see current copy of method.)
  Date:
Analyst:
 11/7/2005
LK
      (Mg/U
  IDL= 0.027
 MDL= 0.075
  RL = 0.10
 LDR = 0.10 to 8.0
5 SAMPLE ANALYTICAL RUN
MAT-
RIX
































SAMPLE
014-5
014-8
014-11
014-14
014-17
014-20
CCB
CCV
014-23
014-26
014-29
014-32
014-35
014-38
CCB
CCV
LRB
LFB
306-1
SPK
DUP
SERDIL
306-1
306-1
CCB
CCV
306-2
306-3
306-3
306-4
306-5
CCB
CCV
STD CONC







025







1.00

1.00

1.5

5/10



0.50






10.00
READING
Mg/L
0.061
0.028
0.183
0.349
0.185
-0034
0.045
0.198
0.136
0.119
0.069
0.127
0.069
0.143
-0.041
1.006
-0018
0.894
28.900
27.710
27.870
16.270
11.630
5.725
-0.030
0.494
6.587
24.450
3 069
-0.012
0.145
-0.076
10.090
BLK
-0.048
0.046
-0.062
-0.029
-0.044
0.019
0.019
-0.050
-0.036
0039
-0.031
-0.044
-0.014
0.015
0.051
0.051
-0.013
0.061
-0.096
0.146
0.008
-0.008
0.078
-0.030
0.062
-0.022
0.075
0.022
-0064
0.086
-0.076


RESULT
0.109
-0.018
0.245
0.378
0.229
-0.053
0.026
0.248
0.172
0.080
0.100
0.170
0.083
0.127
-0.092
0.955
-0.004
0.832
2ff396"\
f/27.5651
j 27.862 /
[ 16.278'
V1-1T552
5.755
-0.092
0.515
6.513
24.428
3.133
-0.098
0.222
-0.076
10.090
DILI
1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0




1.0
1.0
1.0 .-"
1.0
10.0
25.0


1.0
1.0
25.0
1.0
1.0


DIL2
1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0




14 '
j.oK-u
T^WI.O
I 1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0


QC RESULTS






0.045
99






-0.041
95
-0.004
f\ 83
w
Vs" 88
\ 1.1
''>, 18,1


-0.030
103





~M?M-:
101
Mg/L
0.109
-0.018
0.245
0.378
0.229
-0.053


0.172
0.080
0.100
0.170
0.083
0.127




28.996



115.516
143.875


6.513
24.428
78.335
-0.098
0.222

REPT
mg/L
0.109
<0.100
0.245
0.378
0.229
<0.100


0.172
<0.100
0.100
0.170
<0.100
0.127









J*f


6.51

78.335
<0.100
0.222

ICP























/ 5 j x-







So close, and last CCB, so accepted)



            (< MOL)
            (90-110%R')
            '< MDL)
            ;90-110%R)
            .< MDL)
            ; 80-120%R j

            80-120%R }
            '<10RPD, IFSAs
            <10%D1FF)
             MDL.)
            { 90-110%R)

-------
Method-Name: NI
Method Description: Nickel

Date: 11/07/2005
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
                                Element: Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 64
Results Data Set:
Element: Ni    Seq. No.: 1
Sample ID: Calib Blank
                                  AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L






BlnkCorr
Signal
-0.139
-0.138
-0.138
-0.138
0.000
0.14
Peak
Area
-0.139
-0.138
-0.138



Bkgnd
Area
0.167
0.166
0.166



Time

14:41:59
14:42:01
14:42:03



Auto-zero performed.
Element: Ni    Seq. No.: 2
Sample ID: Calib Blank
  AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.001
0.000
0.001
0.001
0. 000
39.86
Peak
Area
-0.138
-0.138
-0.138



Bkgnd
Area
0.166
0.166
0.165



Time

14:42:
14:42:
14:42:





08
10
12



Auto-zero performed.
Element: Ni    Seq. No.: 3
Sample ID: CAL STD
  AS Loc.
                                                 Date: 11/07/2005
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1
StndConc
mg/L






applied.
Correlation Coefficient: 1
BlnkCorr
Signal
0.011
0.012
0.011
0.011
0.000
2.32
[0.25]
.0000
Peak
Area
-0.127
-0.126
-0.126





Bkgnd
Area
0.164
0.165
0.164




Slope:
Time

14:42:53
14:42:55
14:42:58




0.0456
                                           Page  1

-------
Element: Ni Seq. No . : 4
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 5
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 6
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 7
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient: 0
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.019 -0.119
0.019 -0.119
0.020 -0.118
0.019
0.000
1.94
[0.50]
.9717
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.021 -0.117
0.021 -0.117
0.021 -0.117
0.021
0.000
0.83
[0.50]
.9952
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.040, -0.098
0.039 -0.099
0.038 -0.100
0.039
0.001
2.58
[1.00]
.9948
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.075 -0.063
0.076 -0.062
0.076 -0.062
0.075
0.001
0.94
[2.00]
.9983
Date: 11/07/2005

Bkgnd Time
Area
0.166 14:43:31
0.166 14:43:33
0.166 14:43:35



Slope: 0.0399
Date: 11/07/2005

Bkgnd Time
Area
0.164 14:44:27
0.164 14:44:29
0.164 14:44:32




Slope: 0.0430
Date: 11/07/2005

Bkgnd Time
Area
0.165 14:44:51
0.166 14:44:53
0.166 14:44:55




Slope: 0.0398
Date: 11/07/2005

Bkgnd Time
Area
0.166 14:45:13
0.166 14:45:15
0.166 14:45:17




Slope: 0.0383
Page 2

-------
Element: Ni    Seq. No.:
Sample ID: cal std 5
                                  AS  LOG.
                                                  Date:  11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.171
0.173
0.173
0.172
0.001
0.77
Peak
Area
0.033
0.036
0.035



Bkgnd
Area
0.167
0.168
0.168



Time
14:45:42
14:45:44
14:45:46



The calibration curve may not be  linear.
Standard number 5 applied.  [5.00]
Correlation Coefficient:  0.9981
Slope:  0.0352
                                               Mi
                    0.20
                                              Concentration
Calibration data for Ni


Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5

Mean Signal
(Absorbance)
0.000
0.011
0.021
0.039
0.075
0.172
Correlation Coefficient: 0.99808
Entered
Calculated


Concentration Concentration Standard
(mg/L)
	
0.25
0.50
1.00
2.00
5.00
Slope:
(mg/L)
0.000
0.3241
0.6010
1.102
2.144
4.897
0.03518
Deviation
0.0003
0.0003
0.0002
0.0010
0.0007
0.0013

%RSD
39.8601
2.3187
0.8347
2.5761
0.9419 '
0.7710

                                            Page 3

-------
Element: Ni Seq.
Sample ID: CCV
Repl SampleConc
# mg/L
1 5.024
2 4.946
3 4.904
Mean: 4.958
SD : 0.0609
%RSD: 1.23
Element: Ni Seq.
Sample ID: QCS
Repl SampleConc
# mg/L
I 2.113
2 2.123
3 2.140
Mean: 2.125
SD : 0.0133
%RSD: 0.63
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0549
2 0.0540
3 0.0395
Mean: 0.0495
SD : 0.0086
%RSD: 17.44
Element: Ni • Seq.
Sample ID: CCV-0.25
Repl SampleConc
# mg/L
1 0.3323
2 0.3154
3 0.3213
Mean: 0.3230
SD : 0.0086
%RSD: 2.66
No. : 9

StndConc
mg/L
5.024
4.946
4.904
4.958
0.0609
1.23
No. : 10

StndConc
mg/L
2.113
2.123
2.140
2.125
0.0133
0.63
No.: 11

StndConc
mg/L
0.0549
0.0540
0.0395
0.0495
0.0086
17.44
No. : 12

StndConc
mg/L
0.3323
0.3154
0.3213
0.3230
0.0086
2.66
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.177 0.039
0.174 0.036
0.173 0.035
0.174
0.002
1.23
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.074 -0.063
0.075 -0.063
0.075 -0.063
0.075
0.000
0.63
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.136
0.002 -0.136
0.001 -0.136
0.002
0.000
17.44
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.012 -0.126
0.011 -0.127
0.011 -0.126
0.011
0.000
2.66
Date: 11/07/2005

Bkgnd Time
Area
0.165 14:46:00
0.165 14:46:02
0.165 14:46:04



Date: 11/07/2005

Bkgnd Time
Area
0.164 14:46:24
0.164 14:46:26
0.165 14:46:29



Date: 11/07/2005

Bkgnd Time
Area
0.165 14:46:51
0.164 14:46:53
0.165 14:46:55



Date: 11/07/2005

Bkgnd Time
Area
0.164 14:47:14
0.165 14:47:16
0.164 14:47:18



Page 4

-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0433
2 0.0283
3 0.0458
Mean: 0.0392
SD : 0.0095
%RSD: 24.17
Element: Ni Seq
Sample ID: CRA-0.1
Repl SampleConc
# mg/L
1 0.1648
2 0.1816
3 0.1869
Mean: 0.1778
SD : 0.0115
%RSD: 6.47
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0821
2 0.0848
3 0.1040
Mean: 0.0903
SD : 0.0119
%RSD: 13.21
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 0.0477
. No. : 13

StndConc
mg/L
0.0433
0.0283
0.0458
0.0392
0.0095
24.17
. No. : 14

StndConc
mg/L
0.1648
0.1816
0.1869
0.1778
0.0115
6.47
. No. : 15

StndConc
mg/L
0.0821
0.0848
0.1040
0.0903
0.0119
13.21
. No.: 16

StndConc
mg/L
0.0477
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.136
0.001 -0.137
0.002 -0.136
0.001
0.000
24.17
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 -0.132
0.006 -0.131
0.007 -0.131
0.006
0.000
6.47
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.135
0.003 -0.135
0.004 -0.134
0.003
0.000
13.21
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.136
Date: 11/07/2005

Bkgnd Time
Area
0.164 14:47:32
0.165 14:47:34
0.165 14:47:36



Date: 11/07/2005

Bkgnd Time
Area
0.163 14:47:58
0.163 14:48:00
0.162 14:48:02



Date: 11/07/2005

Bkgnd Time
Area
0.163 14:48:14
0.163 14:48:16
0.163 14:48:18



Date: 11/07/2005

Bkgnd Time
Area
0.165 14:48:37
Auto-zero performed.
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0023
2 -0.0196
3 -0.0019
Mean: -0.0079
SD : 0.0101
%RSD: 127.5
. No. : 17

StndConc
mg/L
-0.0023
-0.0196
-0.0019
-0.0079
0.0101
127.5
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.136
-0.001 -0.137
0.000 -0.136
0.000
0.000
127.50
Date: 11/07/2005

Bkgnd Time
Area
0.165 14:48:52
0.165 14:48:54
0.165 14:48:56



Page 5

-------
Element: Ni Seq
Sample ID: LRB
Repl SampleConc
# mg/L
1 0.0414
2 0.0342
3 0.0534
Mean: 0.0430
SD : 0.0097
%RSD: 22.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0017
2 0.0110
3 0.0443
Mean: 0.0179
SD : 0.0238
%RSD: 132.9
Element: Ni Seq
Sample ID: LFB
Repl SampleConc
# mg/L
1 3.326
2 3.343
3 3.340
Mean: 3.337
SD : 0.0091
%RSD: 0.27
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 - 0.0154
2 0.0272
3 0.0097
Mean: 0.0174
SD : 0.0089
%RSD: 51.18
. No. : 18
StndConc
mg/L
0.0414
0.0342
0.0534
0.0430
0.0097
22.54
. No. : 19

StndConc
mg/L
-0.0017
0.0110
0.0443
0.0179
0.0238
132.9
. No. : 20

StndConc
mg/L
3.326
3.343
3.340
3.337
0.0091
0.27
. No. : 21

StndConc
mg/L
0.0154
0.0272
0.0097
0.0174
0.0089
51.18
AS
BlnkCorr
Signal
0.001
0.001
0.002
0.002
0.000
22.54
AS

BlnkCorr
Signal
0.000
0.000
0.002
0.001
0.001
132.93
AS

BlnkCorr
Signal
0.117
0.118
0.118
0.117
0.000
0.27
AS

BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
51.18
Loc. : 	
Peak
Area
-0.135
-0.135
-0.134



Loc. : 	

Peak
Area
-0.136
-0.136
-0.135



Loc. : 	

Peak
Area
-0.019
-0.018
-0.019



Loc . : 	

Peak
Area
-0.136
-0.135
-0.136



Date: 11/07/2005
Bkgnd Time
Area
0.165 14:49:09
0.166 14:49:11
0.166 14:49:13



Date: 11/07/2005

Bkgnd Time
Area
0.165 14:49:32
0.165 14:49:35
0.163 14:49:37



Date: 11/07/2005

Bkgnd Time
Area
0.166 14:49:52
0.165 14:49:54
0.165 14:49:56



Date: 11/07/2005

Bkgnd Time
Area
0.164 14:50:16
0.164 14:50:18
0.164 14:50:20



Page 6

-------
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 -0.1686
2 -0.1597
3 -0.1589
Mean: -0.1624
SD : 0.0054
%RSD: 3.32
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0108
2 0.0139
3 0.0131
Mean: 0.0126
SD : 0.0016
%RSD: 12.55
Element: Ni Seq
Sample ID: 014-1+3
Repl SampleConc
# mg/L
1 3.407
2 3.437
3 3.410
Mean: 3.418
SD : 0.0166
%RSD: 0.48
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.1036
2 0.1021
3 0.1076
Mean: 0.1044
SD : 0.0028
%RSD: 2.73
. No. : 22

StndConc
mg/L
-0.1686
-0.1597
-0.1589
-0.1624
0.0054
3.32
. No. : 23

StndConc
mg/L
0.0108
0.0139
0.0131
0.0126
0.0016
12.55
. No.: 24
SPK
StndConc
mg/L
3.407
3.437
3.410
3.418
0.0166
0.48
. No.: 25

StndConc
mg/L
0.1036
0.1021
0.1076
0.1044
0.0028
2.73
AS :

BlnkCorr
Signal
-0.006
-0.006
-0.006
-0.006
0.000
3.32
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
12.55
AS
,3 / 10
Peak
Area
-0.016
-0.015
-0.016



Loc. : 	

Peak
Area
-0.132
-0.133
-0.132



Date: 11/07/2005

Bkgnd Time
Area
0.188 14:50:39
0.188 14:50:41
0.188 14:50:43



Date: 11/07/2005

Bkgnd Time
Area
0.164 14:51:01
0.164 14:51:03
0.164 14:51:05



Date: 11/07/2005

Bkgnd Time
Area
0.186 14:53:06
0.186 14:53:08
0.185 14:53:10



Date: 11/07/2005

Bkgnd Time
Area
0.161 14:53:40
0.161 14:53:42
0.161 14:53:44



Page 7

-------
Element: Ni    Seq. No.: 26
SampleXlD: 014-1+3 SD
       SafhpleConc
       mg/E
          10\35
       absorb
          -10.47
       absorbXnc
          1JK41
       abao'rbance
         /10.41
        "" 0.0629
           0.60
       absorbance
is greater
is greater
                                  AS LOG.
                                                 Date: 11/07/2005
BlnkCorr
 Signal
  0.364
than that
  9.368
than that
  0.366
than that
  0.366
  0.002
   0.60
than that
 Peak     Bkgn|    Time
 Area     Area
 0.228     0.190  14:54:16
of the highest standard.
 0.232     0.190  14:54:18
of the highest standard.
 0.230     0.191  14:54:21
of the highest standard.
                     of the highest standard.
Element: Ni    Seq. No.:
Sample ID: SD RE-SET
                         27
                                  AS LOG.
                                                 Date:  11/07/2005
Repl
tt
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.471
3.497
3.439
3.469
0.0287
0.83
StndConc
mg/L
3.471
3.497
3.439
3.469
0.0287
0.83
BlnkCorr Peak
Signal Area
0.122 -0.014
0.123 -0.013
0.121 -0.015
0.122
0.001
0.83
Bkgnd Time
Area
0.183 14:55:21
0.183 14:55:23
0.183 14:55:25



Element: Ni    Seq. No.: 28
Sample ID: CCB
                AS LOG.
                                                  Date:  11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0065
-0.0413
0.0070
-0.0136
0.0249
.183.7
StndConc
mg/L
-0.0065
-0.0413
0.0070
-0.0136
0.0249
183.7
BlnkCorr Peak
Signal Area
0.000 -0.136
-0.001 -0.138
0.000 -0.136
0.000
0.001
183.72
Bkgnd Time
Area
0.164 14:55:41
0.165 14:55:43
0.164 14:55:45



Element: Ni    Seq. No.: 29
Sample ID: 014-1+3SER
                AS LOG.
                                                  Date:  11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.175
1.021
1.050
1.082
0.0822
7.60
StndConc
mg/L
1.175
1.021
1.050
1.082
0.0822
7.60
BlnkCorr
Signal
0.
0.
0.
0.
0.
7
041
036
037
038
003
.60
Peak
Area
-0.
-0.
-0.



095
100
099



Bkgnd
Time
Area
0
0
0



.171
.176
.175



14
14
14



:57:
:57:
:57:




13
15
17



                                            Page 8

-------
Element: Ni    Seq.
Sample ID: CCB
                    No.: 30
              AS LOG.:  	
                                                 Date: 11/07/2005
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0
0
0
0
0

.1131
.1209
.0989
.1110
.0112
10.08
StndConc
mg/L
0
0
0
0
0

.1131
.1209
.0989
.1110
.0112
10.08
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
10
004 -0.132
004 -0.132
003 -0.133
004
000
.08
Bkgnd Time
Area
0.162 14:57:56
0.161 14:57:58
0.162 14:58:01



Element: Ni    Seq. No.: 31
Sample ID: Sample
              AS LOG.:  	
                                                 Date: 11/07/2005
Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1       0.0797     0.0797
Auto-zero performed.
         BlnkCorr   Peak
          Signal    Area
           0.003   -0.133
Bkgnd    Time
Area
 0.162  14:59:25
Element: Ni    Seq. No.
Sample ID: CCB
                         32
              AS LOG.:  	
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0247
0.0190
-0.0125
0.0104
0.0201
193.1
StndConc
mg/L
0.0247
0.0190
-0.0125
0.0104
0.0201
193.1
BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.133
0.000 -0.134
0.000
0.001
193.12
Bkgnd Time
Area
0.162 14:59:31
0.162 14:59:34
0.162 14:59:36



Element: Ni    Seq. No.: 33
Sample ID: CCV
              AS LOG.:  	
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
Samp
mg/L
0.
0.
0.
0.
0.

leConc

9477
9422
8717
9205
0424
4.61
Stn
mg/
0.
0.
0.
0.
0.

.dConc
L
9477
9422
8717
9205
0424
4.61
Blnk
Sig
0.
0.
0.
0.
0.
4
Corr Peak
nal Area
033 -0.100
033 -0.100
031 -0.103
032
001
.61
Bkgnd Time
Area
0.166 14:59:50
0.167 14:59:52
0.169 14:59:54



Element: Ni    Seq.
Sample ID: CCB
No.: 34
                                  AS LOG.: 	
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.0603
.0416
.0449
.0489
.0100
20.35
StndConc
mg/L
-0
-0
-0
-0
0

.0603
.0416
.0449
.0489
.0100
20.35
BlnkCorr
Signal
-0.002
-0.001
-0.002
-0.002
0.000
20.35
Peak
Area
-0.
-0.
-0.



135
135
135



Bkgnd
Time
Area
0.
0.
0.



164
164
164



15:
15:
15:



00:09
00:11
00:14



                                           Page 9

-------
Element: Ni Seq.
Sample ID: 014-4+6
Repl SampleConc
# mg/L
1 0.2426
2 0.2456
3 0.2346
Mean: 0.2409
SD : 0.0057
%RSD: 2.36
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0070
2 0.0215
3 0.0221
Mean: 0.0169
SD : 0.0085
%RSD: 50.49
Element: Ni Seq.
Sample ID: 014-7+9
Repl SampleConc
# mg/L
1 -0.0728
2 -0.0462
3 -0.0791
Mean: -0.0660
SD : 0.0175
%RSD: 26.44
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0502
2 -0.0378
3 -0.0466
Mean: -0.0449
SD : 0.0064
%RSD: 14.16
No.: 35

StndConc
mg/L
0.2426
0.2456
0.2346
0.2409
0.0057
2.36
No.: 36

StndConc
mg/L
0.0070
0.0215
0.0221
0.0169
0.0085
50.49
No.: 37

StndConc
mg/L
-0.0728
-0.0462
-0. 0791
-0.0660
0.0175
26.44
No. : 38

StndConc
mg/L
-0.0502
-0.0378
-0.0466
-0.0449
0.0064
14.16
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.009 -0.125
0.009 -0.125
0.008 -0.125
0.008
0.000
2.36
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.000 -0.133
0.001 -0.133
0.001 -0.133
0.001
0.000
50.49
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.003 -0.136
-0.002
0.001
26.44
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.135
-0.002 -0.135
-0.002
0.000
14.16
Date: 11/07/2005

Bkgnd Time
Area
0.188 15:00:36
0.188 15:00:38
0.188 15:00:40



Date: 11/07/2005

Bkgnd Time
Area
0.163 15:00:55
0.162 15:00:57
0.163 15:00:59



Date: 11/07/2005

Bkgnd Time
Area
0.186 15:01:17
0.186 15:01:19
0.186 15:01:21



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:01:31
0.165 15:01:34
0.165 15:01:36



Page 10

-------
Element: Ni Seq
. No. : 39
AS LOG. : 	
Date: 11/07/2005
Sample ID: 014-10+12
Repl SampleConc
# mg/L
1 0.3958
2 0.4095
3 0.3897
Mean: 0.3984
SD : 0.0101
%RSD: 2.54
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0245
2 0.0040
3 0.0260
Mean: 0.0182
SD : 0.0123
%RSD: 67.72
Element: Ni Seq
StndConc
mg/L
0.3958
0.4095
0.3897
0.3984
0.0101
2.54
. No. : 40

StndConc
mg/L
0.0245
0.0040
0.0260
0.0182
0.0123
67.72
. No.: 41
BlnkCorr Peak
Signal Area
0.014 -0.119
0.014 -0.119
0.014 -0.120
0.014
0.000
2.54
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.001 -0.132
0.000 -0.133
0.001 -0.132
0.001
0.000
67.72
AS LOG. : 	
Bkgnd Time
Area
0.186 15:02:03
0.185 15:02:05
0.185 15:02:07



Date: 11/07/2005

Bkgnd Time
Area
0.162 15:02:19
0.162 15:02:21
0.162 15:02:23



Date: 11/07/2005
Sample ID: 014-13+15
Repl SampleConc
# mg/L
1 0.7715
2 0.7641
3 0.7791
Mean: 0.7715
SD : 0.0075
%RSD: 0.97
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0760
2 -0.0504
3 -0.0460
Mean: -0.0575
SD : 0.0162
%RSD: 28.23
StndConc
mg/L
0.7715
0.7641
0.7791
0.7715
0.0075
0.97
. No. : 42

StndConc
mg/L
-0.0760
-0.0504
-0.0460
-0.0575
0.0162
28.23
BlnkCorr Peak
Signal Area
0.027 -0.106
0.027 -0.106
0.027 -0.106
0.027
0.000
0.97
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.002 -0.135
-0.002
0.001
28.23
Bkgnd Time
Area
0.189 15:02:44
0.189 15:02:46
0.190 15:02:48



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:03:02
0.165 15:03:05
0.165 15:03:07



Page 11

-------
Element : Ni Seq
. No. : 43
AS
LOG. : 	
Date: 11/07/2005
Sample ID: 014-16+18
Repl SampleConc
# mg/L
1 0.2519
2 0.2513
3 0.2384
Mean: 0.2472
SD : 0.0076
%RSD: 3.09
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0272
2 0.0500
3 0.0352
Mean: 0.0375
SD : 0.0116
%RSD: 30.91
Element : Ni Seq
StndConc
mg/L
0.2519
0.2513
0.2384
0.2472
0.0076
3.09
. No. : 44

StndConc
mg/L
0.0272
0.0500
0.0352
0.0375
0.0116
30.91
. No. : 45
BlnkCorr
Signal
0.009
0.009
0.008
0.009
. 0.000
3.09
AS

BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
30.91
AS
Peak
Area
-0.124
-0.124
-0.125



Loc. : 	

Peak
Area
-0.132
-0.132
-0.132



Loc. : 	
Bkgnd Time
Area
0.188 15:03:32
0.188 15:03:35
0.189 15:03:37



Date: 11/07/2005

Bkgnd Time
Area
0.162 15:03:54
0.162 15:03:56
0.162 15:03:58



Date: 11/07/2005
Sample ID: 014-19+21
Repl SampleConc
# mg/L
1 3.520
2 3.569
3 3.488
Mean: 3.526
SD : 0.0409
%RSD: 1.16
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0612
2 -0.0538
3 -0.0454
Mean: -0.0535
SD : 0.0079
%RSD: 14.76
StndConc
mg/L
3.520
3.569
3.488
3.526
0.0409
1.16
. No. : 46

StndConc
mg/L
-0.0612
-0.0538
-0.0454
-0.0535
0.0079
14.76
BlnkCorr
Signal
0.124
0.126
0.123
0.124
0.001
1.16
AS

BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
14.76
Peak
Area
-0.009
-0.008
-0.011



Loc. : 	

Peak
Area
-0.135
-0.135
-0.135



Bkgnd Time
Area
0.190 15:04:22
0.191 15:04:24
0.190 15:04:27



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:04:41
0.164 15:04:43
0.164 15:04:45



Page 12

-------
Element: Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.4529
2 0.4721
3 0.4709
Mean: 0.4653
SD : 0.0108
%RSD: 2.32
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0200
2 0.0430
3 0.0241
Mean: 0.0290
SD : 0.0123
%RSD: 42.22
Element: Ni Seq
. No. : 47

StndConc
mg/L
0.4529
0.4721
0.4709
0.4653
0.0108
2.32
. No. : 48

StndConc
mg/L
0.0200
0.0430
0.0241
0.0290
0.0123
42.22
. No. : 49
AS

BlnkCorr
Signal
0.016
0.017
0.017
0.016
0.000
2.32
AS

BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
42.22
AS
Loc. : 	

Peak
Area
-0.117
-0.117
-0.117



Loc. : 	

Peak
Area
-0.133
-0.132
-0.132



Loc. : 	
Date: 11/07/2005

Bkgnd Time
Area
0.164 15:05:05
0.165 15:05:07
0.164 15:05:09



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:05:25
0.162 15:05:27
0.161 15:05:29



Date: 11/07/2005
Sample ID: 014-22+24
Repl SampleConc
# mg/L
1 0.1449
2 0.1479
3 0.1068
Mean: 0.1332
SD : 0.0229
%RSD: 17.18
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0688
2 -0.0789
3 -0.0688
Mean: -0.0722
SD : 0.0058
%RSD: 8.06
StndConc
mg/L
0.1449
0.1479
0.1068
0.1332
0.0229
17.18
. No. : 50

StndConc
mg/L
-0.0688
-0.0789
-0.0688
-0.0722
0.0058
8.06
BlnkCorr
Signal
0.005
0.005
0.004
0.005
0.001
17.18
AS

BlnkCorr
Signal
-0.002
-0.003
-0.002
-0.003
0.000
8.06
Peak
Area
-0.128
-0.128
-0.130



Loc. : 	

Peak
Area
-0.136
-0.136
-0.136



Bkgnd Time
Area
0.190 15:05:45
0.190 15:05:47
0.191 15:05:49



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:06:04
0.166 15:06:07
0.165 15:06:09



Page 13

-------
Element: Ni Seq.
No . : 51
AS LOG. : 	
Date: 11/07/2005
Sample ID: 014-25+27
Repl SampleConc
# mg/L
1 -0.1614
2 -0.1827
3 -0.1612
Mean: -0.1684
SD : 0.0123
%RSD: 7.33
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0308
2 0.0253
3 0.0264
Mean: 0.0275
SD : 0.0029
%RSD: 10.58
Element: Ni Seq.
StndConc
mg/L
-0.1614
-0.1827
-0.1612
-0.1684
0.0123
7.33
No. : 52

StndConc
mg/L
0.0308
0.0253
0.0264
0.0275
0.0029
10.58
No. : 53
BlnkCorr Peak
Signal Area
-0.006 -0.139
-0.006 -0.140
-0.006 -0.139
-0.006
0.000
7.33
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 -0.132
0.001 -0.132
0.001 -0.132
0.001
0.000
10.58
AS Loc. : 	
Bkgnd Time
Area
0.186 15:06:26
0.187 15:06:28
0.187 15:06:30



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:06:47
0.161 15:06:49
0.162 15:06:51



Date: 11/07/2005
Sample ID: 014-28+30
Repl SampleConc
# mg/L
1 0.2789
2 0.2498
3 0.2873
Mean: 0.2720
SD : 0.0197
%RSD: 7.23
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0433
2 -0.0335
3 -0.0441
Mean: -0.0403
SD : 0.0059
%RSD: 14.74
StndConc
mg/L
0.2789
0.2498
0.2873
0.2720
0.0197
7.23
No.: 54

StndConc
mg/L
-0.0433
-0.0335
-0.0441
-0.0403
0.0059
14.74
BlnkCorr Peak
Signal Area
0.010 -0.123
0.009 -0.125
0.010 -0.123
0.010
0.001
7.23
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.134
-0.002 -0.135
-0.001
0.000
14.74
Bkgnd Time
Area
0.189 15:07:14
0.190 15:07:16
0.190 15:07:18



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:07:35
0.165 15:07:37
0.165 15:07:39



Page 14

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
. No.: 55
AS
LOG. : 	
Date:
11/07/2005
ID: 014-31+33
SampleConc
mg/L
-0.1722
-0.1656
-0.1673
-0.1684
0.0035
2.05
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0352
0.0508
0.0186
0.0114
0.0434
380.6
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
StndConc
mg/L
-0.1722
-0.1656
-0.1673
-0.1684
0.0035
2.05
. No. : 56

StndConc
mg/L
-0.0352
0.0508
0.0186
0.0114
0.0434
380.6
. No. : 57
BlnkCorr
Signal
-0.006
-0.006
-0.006
-0.006
0.000
2.05
AS

BlnkCorr
Signal
-0.001
0.002
0.001
0.000
0.002
380.64
AS
Peak
Area
-0.139
-0.139
-0.139



Loc. : 	

Peak
Area
-0.135
-0.132
-0.133



Loc. : 	
Bkgnd
Area
0.190
0.191
0.192



Date:

Bkgnd
Area
0.164
0.162
0.161



Date:
Time

15: 07:
15:07:
15:08:





57
59
01



11/07/2005

Time

15:08:
15:08:
15:08:






14
16
18



11/07/2005
ID: 014-34+36
SampleConc
mg/L
-0.0567
-0.0580
-0.0551
-0.0566
0.0014
2.52
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCB
SampleConc
mg/L
-0.0251
-0.0335
-0.0536
-0.0374
0.0147
39.21
StndConc
mg/L
-0.0567
-0.0580
-0.0551
-0.0566
0.0014
2.52
. No. : 58

StndConc
mg/L
-0.0251
-0.0335
-0.0536
-0.0374
0.0147
39.21
BlnkCorr
Signal
-0.002
-0.002
-0.002
-0.002
0.000
2.52
AS

BlnkCorr
Signal
-0.001
-0.001
-0.002
-0.001
0.001
39.21
Peak
Area
-0.135
-0.135
-0.135



Loc. : 	

Peak
Area
-0.134
-0.134
-0.135



Bkgnd
Area
0.186
0.186
0.187



Date:

Bkgnd
Area
0.164
0.165
0.165



Time

15:08:
15:08:
15:08:





33
36
38



11/07/2005

Time

15:08:
15:08:
15:08:






54
56
58



Page 15

-------
Element: Ni    Seq. No.:
Sample ID: 014-37+39
                         59
              AS LOG.: 	
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.1196
.1373
.1137
.1235
.0123
9.93
StndConc
mg/L
-0.
-0.
-0.
-0.
0.

1196
1373
1137
1235
0123
9.93
BlnkCorr Peak
Signal Area
-0
-0
-0
-0
0

.004 -0.138
.005 -0.138
.004 -0.137
.004
.000
9.93
Bkgnd Time
Area
0.189 15:09:13
0.189 15:09:15
0.189 15:09:17



Element: Ni    Seq.
Sample ID: CCB
                    No.: 60
              AS LOG.: 	
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean :
SD :
%RSD:
SampleConc
mg/L
-0.0715
-0.0823
-0.0776
-0.0771
0.0054
7.04
StndConc
mg/L
-0.0715
-0.0823
-0.0776
-0.0771
0.0054
7.04
BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.003 -0.136
-0.003 -0.136
-0.003
0.000
7.04
Bkgnd Time
Area
0.165 15:09:33
0.166 15:09:36
0.166 15:09:38



Element: Ni    Seq. No.: 61
Sample ID: Sample
              AS LOG.
Date: 11/07/2005
Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1       0.0217     0.0217
Auto-zero performed.
         BlnkCorr   Peak
          Signal    Area
           0.001   -0.133
Bkgnd    Time
Area
 0.161  15:09:50
Element: Ni    Seq. No.: 62
Sample ID: CCB
              AS LOG.
                             Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleCo
mg/L
-0.0013
0.0207
0.0243
0.0146
0.0139
95.32
nc StndConc
mg/L
-0.0013
0.0207
0.0243
0.0146
0.0139
95.32
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.000 -0.133 0.162 15:10:00
0.001 -0.132 0.162 15:10:02
0.001 -0.132 0.162 15:10:04
0.001
0.000
95.32
Element: Ni    Seq.
Sample ID: CCV
No.: 63
                                  AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.019
2.012
1.981
2.004
0.0201
1.00
StndConc
mg/L
2.019
2.012
1.981
2.004
0.0201
1.00
BlnkCorr
Signal
0
0
0
0
0

.071
.071
.070
.070
.001
1.00
Peak
Area
-0.
-0.
-0.



062
062
063



Bkgnd
Time
Area
0.
0.
0.



165
165
166



15:
15:
15:



10
10
10



:18
:20
:22



                                           Page  16

-------
                 Appendix E - 4




Laboratory QA/QC Data for Stack Testing Samples

-------
Element
Sample
: Ni Seq,
ID: CCB
Repl SampleConc
# mg/L
1 -0.0909
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
-0. 0401
-0.0555
-0.0622
0.0260
41.86
: Ni Seq
ID: I LRB
SampleConc
mg/L
1.860
1.878
1.891
1.876
0.0153
0.82
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: CCB
SampleConc
mg/L
0.0137
0.0388
0.0247
0.0257
0.0126
48.89
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: I LFB
SampleConc
mg/L
0.1021
0.0962
0.0405
0.0796
0.0340
42.70
. No.: 64
StndConc
mg/L
-0.0909
-0.0401
-0.0555
-0.0622
0.0260
41.86
. No. : 65

StndConc
mg/L
1.860
1.878
1.891
1.876
0.0153
0.82
. No.: 66

StndConc
mg/L
0.0137
0.0388
0.0247
0.0257
0.0126
48.89
. No. : 67

StndConc
mg/L
0.1021
0.0962
0.0405
0.0796
0.0340
42.70
AS LOG. : 	
BlnkCorr
Signal
-0.003
-0.001
-0.002
-0.002
0.001
41.86
Peak
Area
-0.136
-0.134
-0.134



AS Loc. : 	

BlnkCorr
Signal
0.065
0.066
0.067
0.066
0.001
0.82

Peak
Area
-0.067
-0.066
-0.066



AS Loc. : 	

BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
48.89
AS

BlnkCorr
Signal
0.004
0.003
0.001
0.003
0.001
42.70

Peak
Area
-0.132
-0.131
-0.132



Loc. : 	

Peak
Area
-0.129
-0.129
-0.131



Date: 11/07/2005
Bkgnd
Area
0.165
0.165
0.164



Time
15:10:33
15:10:35
15:10:37



Date: 11/07/2005

Bkgnd
Area
0.168
0.168
0.167



Date:

Bkgnd
Area
0.162
0.161
0.162



Date:

Bkgnd
Area
0.165

Time
15:11:01
15:11:03
15:11:05



11/07/2005

Time
15:11:18
15:11:20
15:11:22



11/07/2005

Time
15:11:40
0.166 15:11:42
0.167



15:11:45



Page 17

-------
Element: Ni    Seq. No.: 68
Sample ID: CCB
                                  AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD
%RSD:
SampleConc
mg/L
-0.0658
-0.0394
-0.0432
-0.0494
0.0143
28.90
StndConc
mg/L
-0.0658
-0.0394
-0.0432
-0.0494
0.0143
28.90
BlnkCorr Peak
Signal Area
-0.002 -0.135
-0.001 -0.134
-0.002 -0.134
-0.002
0.001
28.90
Bkgnd Time
Area
0.164 15:11:59
0.164 15:12:01
0.165 15:12:03



Element: Ni
Sample ID: I
  Seq.  No.:  69
014-2
                                  AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0110
0.0314
0.0120
0.0181
0.0115
63.34
StndConc
mg/L
0.0110
0.0314
0.0120
0.0181
0.0115
63.34
BlnkCorr Peak
Signal Area
0.000 -0.132
0.001 -0.131
0.000 -0.132
0.001
0.000
63.34
Bkgnd Time
Area
0.167 15:12:21
0.167 15:12:23
0.168 15:12:25



Element: Ni    Seq.
Sample ID: CCB
                    No.: 70
                     AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0270
0.0129
-0.0053
0.0115
0.0162
140.5
StndConc
mg/L
0.0270
0.0129
-0.0053
0.0115
0.0162
140.5
BlnkCorr Peak
Signal Area
0.001 -0.132
0.000 -0.132
0.000 -0.133
0.000
0.001
140.50
Bkgnd Time
Area
0.162 15:12:48
0.162 15:12:50
0.162 15:12:52



Element: Ni    Seq.
Sample ID: 014-2 S
                    No. : 71
                                                 Date: 11/07/2005

                             BlnkCorr
                              Signal
                               0.253
                             than that
                               0.253
                             than that
                               0.253
                             than that
                               0.253
                               0.000
                                0.14
                             than that
                           Peak
                           Area
                           0.120
                          of the
                           0.120
                          of the
                           0.121
                          of the
   Bkgnd    Time
   Area
    0.167  15:14:04
highest standard.
    0.166  15:14:06
highest standard.
    0.166  15:14:08
highest standard.
                          of the highest standard.
                                           Page 18

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: 014-2 S
SampleConc
mg/L
4.198
4.177
4.159
4.178
0.0196
0.47
: Ni Seq.
ID: CCB
SampleConc
mg/L
-0.0373
-0.0555
-0.0489
-0.0472
0.0092
19.56
: Ni Seq.
ID: 014-2 SD
SampleConc /
mg/L /
-0.0888/
-0.0080''
0.00/17
-0.0317
0/0497
/156.8
: Ni Seq.
ID: 014-2 SD
SampleConc
mg/L
4.240
4.225
4.251
4.239
0.0129
0.30
No.: 72

StndConc
mg/L
4.198
4.177
4.159
4.178
0.0196
0.47
No. : 73

StndConc
mg/L
-0.0373
-0.0555
-0.0489
-0.0472
0.0092
19.56
No. : 74
/ L
StndConc
mg/L
-0.0888
-0.0080
0.0017
-0.0317
0.0497
156.8
No.: 75

StndConc
mg/L
4.240
4.225
4.251
4.239
0.0129
0.30
AS

BlnkCorr
Signal
0.148
0.147
0.146
0.147
0.001
0.47
AS

BlnkCorr
Signal
-0.001
-0.002
-0.002
-0.002
0.000
19.56
•, AS
lA
BlnkCorr
Signal
-0.003
0.000
0.000
-0.001
0.002
156.81
AS

BlnkCorr
Signal
0.149
0.149
0.150
0.149
0.000
0.30
Loc. : 	

Peak
Area
0.015
0.014
0.014



Loc. : 	

Peak
Area
-0.134
-0.134
-0.134



Loc. : 	

Peak
Area
-0.136
-0.133
-0.132



Loc. : 	

Peak
Area
0.017
0.016
0.017



Date:

Bkgnd
Area
0.168
0.169
0.169



Date:

Bkgnd
Area
0.164
0.164
0.164



Date:

Bkgnd
Area
0.165
0.163
0.161



Date:

Bkgnd
Area
0.165
0.165
0.165



11/07/2005

Time
15:14:
15:14:
15:14:




29
31
33



11/07/2005

Time
15:15:
15:15:
15:15:




00
02
05



11/07/2005

Time
15:15:
15:15:
15:15:




13
16
18



11/07/2005

Time
15:15:
15:15:
15:15:




33
35
37



Page 19

-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.1029
2 -0.0865
3 -0.0652
Mean: -0.0849
SD : 0.0189
%RSD: 22.24
Element: Ni Seq.
Sample ID: 014-2 SI
Repl SampleConc
# mg/L
1 2 . 493
2 2 . 469
3 2.521
Mean: 2.494
SD : 0.0256
%RSD: 1.03
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0857
2 -0.0614
3 -0.0745
Mean: -0.0739
SD : 0.0122
%RSD: 16.48
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0797
2 -0.0751
3 -0.0700
Mean: -0.0749
SD : 0.0049
%RSD: 6.48
No . : 76

StndConc
mg/L
-0.1029
-0.0865
-0.0652
-0.0849
0.0189
22.24
. No. : 77
3R
StndConc
mg/L
2.493
2.469
2.521
2.494
0.0256
1.03
. No. : 78

StndConc
mg/L
-0.0857
-0.0614
-0.0745
-0.0739
0.0122
16.48
. No. : 79

StndConc
mg/L
-0.0797
-0.0751
-0.0700
-0.0749
0.0049
6.48
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.003 -0.136
-0.002 -0.135
-0.003
0.001
22.24
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.088 -0.045
0.087 -0.046
0.089 -0.044
0.088
0.001
1.03
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.136
-0.002 -0.135
-0.003 -0.135
-0.003
0.000
16.48
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.003 -0.135
-0.002 -0.135
-0.003
0.000
6.48
Date: 11/07/2005

Bkgnd Time
Area
0.165 15:16:38
0.165 15:16:40
0.165 15:16:43



Date: 11/07/2005

Bkgnd Time
Area
0.163 15:17:00
0.163 15:17:02
0.164 15:17:04



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:17:55
0.166 15:17:57
0.165 15:17:59



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:18:46
0.166 15:18:48
0.165 15:18:50



Page 20

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCV
SampleConc
mg/L
4.699
4.681
4.700
4.693
0.0103
0.22
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0392
0.0342
0.0255
0.0330
0.0069
21.03
: Ni Seq
ID: 014-5
SampleConc
mg/L
0.0892
0.0570
0.0376
0.0613
0.0260
42.46
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.0635
-0.0458
-0.0338
-0.0477
0.0149
31.27
. No. : 80

StndConc
mg/L
4.699
4.681
4.700
4.693
0.0103
0.22
. No. : 81

StndConc
mg/L
0.0392
0.0342
0.0255
0.0330
0.0069
21.03
. No. : 82

StndConc
mg/L
0.0892
0.0570
0.0376
0.0613
0.0260
42.46
. No. : 83

StndConc
mg/L
-0.0635
-0.0458
-0.0338
-0.0477
0.0149
31.27
AS :

BlnkCorr
Signal
0.165
0.165
0.165
0.165
0.000
0.22
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
21.03
AS

BlnkCorr
Signal
0.003
0.002
0.001
0.002
0.001
42.46
AS

BlnkCorr
Signal
-0.002
-0.002
-0.001
-0.002
0.001
31.27
LOG. : 	

Peak
Area
0.033
0.032
0.033



LOG. : 	

Peak
Area
-0.131
-0.131
-0.132



LOG. : 	

Peak
Area
-0.129
-0.131
-0.131



LOG. : 	

Peak
Area
-0.135
-0.134
-0.134



Date: :

Bkgnd
Area
0.167
0.168
0.168



Date:

Bkgnd
Area
0.161
0.161
0.161



Date:

Bkgnd
Area
0.164
0.165
0.165



Date:

Bkgnd
Area
0.165
0.165
0.165



11/07/2005

Time
15:19:13
15:19:15
15:19:17



11/07/2005

Time

15:19:32
15:19:34
15:19:36



11/07/2005

Time

15:20:02
15:20:04
15:20:06



11/07/2005

Time

15:20:16
15:20:18
15:20:20



Page 21

-------
Element: Ni Seq
Sample ID: 014-8
Repl SampleConc
# mg/L
1 0.0468
2 0.0270
3 0.0108
Mean: 0.0282
SD : 0.0180
%RSD: 63.82
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0565
2 0.0451
3 0.0365
Mean: 0.0460
SD : 0.0100
%RSD: 21.77
Element: Ni Seq
Sample ID: 014-11
Repl SampleConc
# mg/L
1 0.1795
2 0.1981
3 0.1713
Mean: 0.1830
SD : 0.0137
%RSD: 7.51
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0734
2 -0.0470
3 -0.0650
Mean: -0.0618
SD : 0.0135
%RSD: 21.86
. No. : 84

StndConc
mg/L
0.0468
0.0270
0.0108
0.0282
0.0180
63.82
. No.: 85

StndConc
mg/L
0.0565
0.0451
0.0365
0.0460
0.0100
21.77
. No . : 86

StndConc
mg/L
0.1795
0.1981
0.1713
0.1830
0.0137
7.51
. No. : 87

StndConc
mg/L
-0.0734
-0.0470
-0.0650
-0.0618
0.0135
21.86
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.131
0.001 -0.132
0.000 -0.132
0.001
0.001
63.82
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.131
0.001 -0.131
0.002
0.000
21.77
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 -0.126
0.007 -0.126
0.006 -0.127
0.006
0.000
7.51
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.134
-0.002 -0.135
-0.002
0.000
21.86
Date: 11/07/2005

Bkgnd Time
Area
0.166 15:20:41
0.166 15:20:43
0.166 15:20:45



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:20:58
0.161 15:21:01
0.161 15:21:03



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:21:19
0.166 15:21:22
0.166 15:21:24



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:21:35
0.165 15:21:37
0.165 15:21:39



Page 22

-------
Element: Ni Seq
Sample ID: 014-14
Repl SampleConc
# mg/L
1 0.3378
2 0.3445
3 0.3650
Mean: 0.3491
SD : 0.0142
%RSD: 4.06
Element : Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
I -0.0776
2 -0.0563
3 0.0473
Mean: -0.0288
SD : 0.0668
%RSD: 231.7
Element: Ni Seq
Sample ID: 014-17
Repl SampleConc
# mg/L
1 0.1774
2 0.2074
3 0.1690
Mean: 0.1846
SD : 0.0202
%RSD: 10.94
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0156
2 -0.0352
3 -0.0812
Mean: -0.0440
SD : 0.0337
%RSD: 76.56
. No.: 88

StndConc
mg/L
0.3378
0.3445
0.3650
0.3491
0.0142
4.06
. No. : 89

StndConc
mg/L
-0.0776
-0.0563
0.0473
-0.0288
0.0668
231.7
. No. : 90

StndConc
mg/L
0.1774
0.2074
0.1690
0.1846
0.0202
10.94
. No.: 91

StndConc
mg/L
-0.0156
-0.0352
-0.0812
-0.0440
0.0337
76.56
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.012 -0.121
0.012 -0.120
0.013 -0.120
0.012
0.000
4.06
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.135
0.002 -0.131
-0.001
0.002
231.74
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.006 -0.126
0.007 -0.125
0.006 -0.127
0.006
0.001
10.94
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.001 -0.134
-0.003 -0.135
-0.002
0.001
76.56
Date: 11/07/2005

Bkgnd Time
Area
0.166 15:21:53
0.167 15:21:55
0.167 15:21:57



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:22:11
0.165 15:22:13
0.162 15:22:15



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:22:33
0.164 15:22:35
0.164 15:22:37



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:22:50
0.164 15:22:53
0.165 15:22:55



Page 23

-------
Element: Ni Seq.
Sample ID: 014-20
Repl SampleConc
# mg/L
1 -0.0354
2 -0.0403
3 -0.0264
Mean: -0.0340
SD : 0.0070
%RSD: 20.67
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0544
2 0 . 0494
3 0.0612
Mean: 0.0188
SD : 0.0636
%RSD: 339.1
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0502
2 0.0401
3 0.0439
Mean: 0.0447
SD : 0.0051
%RSD: 11.37
Element: Ni Seq.
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.1977
2 0.2030
3 0.1928
Mean: 0.1978
SD : 0.0051
%RSD: 2.60
No.: 92

StndConc
mg/L
-0.0354
-0.0403
-0.0264
-0.0340
0.0070
20.67
No.: 93

StndConc
mg/L
-0.0544
0.0494
0.0612
0.0188
0.0636
339.1
No.: 94

StndConc
mg/L
0.0502
0.0401
0.0439
0.0447
0.0051
11.37
. No. : 95

StndConc
mg/L
0.1977
0.2030
0.1928
0.1978
0.0051
2.60
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.134
-0.001 -0.134
-0.001 -0.133
-0.001
0.000
20.67
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.134
0.002 -0.131
0.002 -0.130
0.001
0.002
339.09
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.131
0.001 -0.131
0.002 -0.131
0.002
0.000
11.37
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.007 -0.126
0.007 -0.125
0.007 -0.126
0.007
0.000
2.60
Date: 11/07/2005

Bkgnd Time
Area
0.165 15:23:09
0.166 15:23:11
0.166 15:23:14



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:23:31
0.162 15:23:34
0.162 15:23:36



Date: 11/07/2005

Bkgnd Time
Area
0.162 15:23:46
0.162 15:23:48
0.162 15:23:50



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:24:23
0.165 15:24:26
0.165 15:24:28



Page 24

-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0768
2 -0.0709
3 -0.0030
Mean: -0.0503
SD : 0.0410
%RSD: 81.57
Element: Ni Seq
Sample ID: 014-23
Repl SampleConc
# mg/L
1 0.1498
2 0.1394
3 0.1192
Mean: 0.1361
SD : 0.0156
%RSD: 11.43
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0489
2 -0.0384
3 -0.0211
Mean: -0.0361
SD : 0.0140
%RSD: 38.81
Element: Ni Seq
Sample ID: 014-26
Repl SampleConc
# mg/L
1 0.1247
2 0.1160
3 0.1160
Mean: 0.1189
SD : 0.0050
%RSD: 4.25
. No. : 96

StndConc
mg/L
-0.0768
-0.0709
-0.0030
-0.0503
0.0410
81.57
. No. : 97

StndConc
mg/L
0.1498
0.1394
0.1192
0.1361
0.0156
11.43
. No. : 98

StndConc
mg/L
-0.0489
-0.0384
-0.0211
-0.0361
0.0140
38.81
. No. : 99

StndConc
mg/L
0.1247
0.1160
0.1160
0.1189
0.0050
4.25
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.002 -0.135
0.000 -0.133
-0.002
0.001
81.57
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.005 -0.127
0.005 -0.128
0.004 -0.128
0.005
0.001
11.43
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.134
-0.001 -0.134
-0.001 -0.133
-0.001
0.000
38.81
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 -0.128
0.004 -0.128
0.004 -0.128
0.004
0.000
4.25
Date: 11/07/2005

Bkgnd Time
Area
0.165 15:24:44
0.165 15:24:46
0.163 15:24:48



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:25:11
0.165 15:25:13
0.165 15:25:15



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:25:41
0.164 15:25:43
0.164 15:25:46



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:26:31
0.165 15:26:33
0.164 15:26:35



Page 25

-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
ft mg/L
1 0.0388
2 0.0382
3 0.0407
Mean: 0.0392
3D : 0.0013
%RSD: 3.30
Element: Ni Seq.
Sample ID: 014-29
Repl SampleConc
ft mg/L
1 0.0734
2 0.0475
3 0.0856
Mean: 0.0688
SD : 0.0194
%RSD: 28.21
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
ft mg/L
1 -0.0407
2 -0.0106
3 -0.0424
Mean: -0.0312
SD : 0.0179
%RSD: 57.16
Element: Ni Seq.
Sample ID: 014-32
Repl SampleConc
ft mg/L
1 0.1148
2 0.1278
3 0.1373
Mean: 0.1266
SD : 0.0113
%RSD: 8.89
No. : 100

StndConc
mg/L
0.0388
0.0382
0.0407
0.0392
0.0013
3.30
No.: 101

StndConc
mg/L
0.0734
0.0475
0.0856
0.0688
0.0194
28.21
No.: 102

StndConc
mg/L
-0.0407
-0.0106
-0.0424
-0.0312
0.0179
57.16
No.: 103

StndConc
mg/L
0.1148
0.1278
0.1373
0.1266
0.0113
8.89
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.001 -0.131
0.001 -0.131
0.001 -0.131
0.001
0.000
3.30
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.130
0.002 -0.131
0.003 -0.130
0.002
0.001
28.21
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.134
0.000 -0.133
-0.001 -0.134
-0.001
0.001
57.16
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 -0.129
0.004 -0.128
0.005 -0.128
0.004
0.000
8.89
Date: 11/07/2005

Bkgnd Time
Area
0.162 15:27:51
0.162 15:27:53
0.162 15:27:55



Date: 11/07/2005

Bkgnd Time
Area
0.167 15:28:14
0.168 15:28:16
0.168 15:28:18



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:28:35
0.164 15:28:37
0.164 15:28:39



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:29:26
0.165 15:29:29
0.165 15:29:31



Page 26

-------
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0719
2 -0.0338
3 -0.0251
Mean: -0.0436
SD : 0.0249
%RSD: 57.03
Element: Ni Seq.
Sample ID: 014-35
Repl SampleConc
# mg/L
1 0.0622
2 0.0694
3 0.0749
Mean: 0.0688
SD : 0.0064
%RSD: 9.28
Element: Ni Seq.
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0548
2 -0.0452
3 0.0568
Mean: -0.0144
SD : 0.0619
%RSD: 430.1
Element: Ni Seq.
Sample ID: 014-38
Repl SampleConc
# mg/L
1 0.1420
2 0.1298
3 0.1555
Mean: 0.1425
SD : 0.0128
%RSD: 9.01
No.: 104

StndConc
mg/L
-0.0719
-0.0338
-0.0251
-0.0436
0.0249
57.03
No.: 105

StndConc
mg/L
0.0622
0.0694
0.0749
0.0688
0.0064
9.28
No. : 106

StndConc
mg/L
-0.0548
-0.0452
0.0568
-0.0144
0.0619
430.1
No.: 107

StndConc
mg/L
0.1420
0.1298
0.1555
0.1425
0.0128
9.01
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.003 -0.135
-0.001 -0.134
-0.001 -0.133
-0.002
0.001
57.03
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.002 -0.130
0.002 -0.130
0.003 -0.130
0.002
0.000
9.28
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.002 -0.134
-0.002 -0.134
0.002 -0.131
-0.001
0.002
430.09
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.005 -0.128
0.005 -0.128
0.005 -0.127
0.005
0.000
9.01
Date: 11/07/2005

Bkgnd Time
Area
0.165 15:29:45
0.165 15:29:47
0.165 15:29:49



Date: 11/07/2005

Bkgnd Time
Area
0.166 15:30:08
0.166 15:30:10
0.166 15:30:12



Date: 11/07/2005

Bkgnd Time
Area
0.165 15:30:23
0.166 15:30:25
0.162 15:30:28



Date: 11/07/2005

Bkgnd Time
Area
0.163 15:30:43
0.163 15:30:45
0.163 15:30:47



Page 27

-------
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0059
2 0.0234
3 0.0160
Mean: 0.0151
SD : 0.0088
%RSD: 58.21
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
If mg/L
1 -0.0183
2 -0.0532
3 -0.0515
Mean: -0.0410
SD : 0.0197
%RSD: 48.10
Element: Ni Seq
Sample ID: CCV
Repl SampleConc
# mg/L
1 0.9857
2 0.9861
3 1.046
Mean: 1.006
SD : 0.0346
%RSD: 3.44
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0574
2 0.0521
3 0.0441
Mean: 0.0512
SD : 0.0067
%RSD: 13.08
. No. : 108

StndConc
mg/L
0.0059
0.0234
0.0160
0.0151
0.0088
58.21
. No. : 109

StndConc
mg/L
-0.0183
-0.0532
-0.0515
-0.0410
0.0197
48.10
. No. : 110

StndConc
mg/L
0.9857
0.9861
1.046
1.006
0.0346
3.44
. No. : 111

StndConc
mg/L
0.0574
0.0521
0.0441
0.0512
0.0067
13.08
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.132
0.001 -0.132
0.001 -0.132
0.001
0.000
58.21
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.002 -0.134
-0.002 -0.134
-0.001
0.001
48.10
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.035 -0.098
0.035 -0.098
0.037 -0.096
0.035
0.001
3.44
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.131
0.002 -0.131
0.002
0.000
13.08
Date: 11/07/2005

Bkgnd Time
Area
0.162 15:30:59
0.162 15:31:02
0.163 15:31:04



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:31:16
0.165 15:31:18
0.165 15:31:20



Date: 11/07/2005

Bkgnd Time
Area
0.166 15:31:52
0.166 15:31:54
0.163 15:31:56



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:32:11
0.161 15:32:14
0.162 15:32:16



Page 28

-------
Element: Ni Seq
Sample ID: B-LRB
Repl SampleConc
# mg/L
1 0.0027
2 -0.0093
3 -0.0462
Mean: -0.0176
SD : 0.0255
%RSD: 144.5
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 -0.0175
2 -0.0048
3 -0.0173
Mean: -0.0132
SD : 0.0073
%RSD: 55.38
Element: Ni Seq
Sample ID: B-LFB
Repl SampleConc
# mg/L
1 0.9021
2 0.9004
3 0.8781
Mean: 0.8935
SD : 0.0134
%RSD: 1.50
Element: Ni Seq
Sample ID: CCB
Repl SampleConc
# mg/L
1 0.0549
2 0.0614
3 0.0671
Mean: 0.0612
SD : 0.0061
%RSD: 9.95
. No. : 112

StndConc
mg/L
0.0027
-0.0093
-0.0462
-0.0176
0.0255
144.5
. No. : 113

StndConc
mg/L
-0.0175
-0.0048
-0.0173
-0.0132
0.0073
55.38
. No. : 114

StndConc
mg/L
0.9021
0.9004
0.8781
0.8935
0.0134
1.50
. No. : 115

StndConc
mg/L
0.0549
0.0614
0.0671
0.0612
0.0061
9.95
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.000 -0.132
0.000 -0.133
-0.002 -0.134
-0.001
0.001
144.55
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 -0.133
0.000 -0.133
-0.001 -0.133
0.000
0.000
55.38
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.032 -0.101
0.032 -0.101
0.031 -0.102
0.031
0.000
1.50
AS Loc.: 	

BlnkCorr Peak
Signal Area
0.002 -0.131
0.002 -0.130
0.002 -0.130
0.002
0.000
9.95
Date: 11/07/2005

Bkgnd Time
Area
0.165 15:32:30
0.166 15:32:32
0.166 15:32:34



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:32:55
0.164 15:32:57
0.164 15:32:59



Date: 11/07/2005

Bkgnd Time
Area
0.167 15:33:11
0.167 15:33:13
0.168 15:33:15



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:33:32
0.161 15:33:34
0.161 15:33:37



Page 29

-------
Element:  Ni    Seq
Sample ID: 306-1
                    No.: 116
AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean :
SD :
%RSD:
Sample
SampleConc
mg/L
28.91
absorbance
28.88
absorbance
28.93
absorbance
28.91
0.0244
0.08
absorbance
StndConc
mg/L
28.91
is greater
28.88
is greater
28.93
is greater
28.91
0.0244
0.08
is greater
BlnkCorr
Signal
1.
than
1.
than
1.
than
1.
0.
0
than
017
that
016
that
018
that
017
001
.08
that
Peak
Area
0.
of
0.
of
0.
of



of
885
the
884
the
885
the



the
Bkgnd
Area

0.182
highest
Time

15:34:
standard.
0.182
highest
15:34:
standard.
0.182
highest



highest
15:34:


13

15

17
standard.









standard.
Element: Ni    Seq.
Sample ID: CCB
                    No.: 117
AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleCon
mg/L
-0.0257
-0.1198
-0.1413
-0.0956
0.0615
64.33
c StndConc
mg/L
-0.0257
-0.1198
-0.1413
-0.0956
0.0615
64.33
BlnkCorr Peak
Signal Area
-0.001 -0.133
-0.004 -0.137
-0.005 -0.138
-0.003
0.002
64.33
Bkgnd Time
Area
0.166 15:35:25
0.168 15:35:27
0.170 15:35:30



Element: Ni    Seq.
Sample ID: 306-1 S
                    No.: 118
AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
27.67
absorbance
27.74
absorbance
27.70
absorbance
27.71
0.0319
0.12
absorbance
StndConc
mg/L

is

is

is



is
27.67
greater
27.74
greater
27.70
greater
27.71
0.0319
0.12
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
974
that
976
that
975
that
975
001
.12
that
Peak
Area
0.
of
0.
of
0.
of



of
841
the
843
the
842
the



the
Bkgnd
Area


0.181
highest
Time

15:35:
standard.
0.181
highest
15:35:
standard.
0.181
highest



highest
15:35:


45

48

50
standard.









standard.
Element: Ni    Seq. No.: 119
Sample ID: CCB
AS Loc.
               Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.

1546
1441
1378
1455
0085
5.81
StndConc
mg/L
0.
0.
0.
0.
0.

1546
1441
1378
1455
0085
5.81
BlnkCorr
Signal
0.005
0.005
0.005
0.005
0.000
5.81
Peak
Area
-0.
-0.
-0.



127
127
128



Bkgnd
Time
Area
0.
0.
0.



162
162
162



15:
15:
15:



36:12
36:14
36:16



                                           Page 30

-------
Element: Ni    Seq. No.
Sample ID: 306-1 SD
                         120
                                  AS Loc.
                                                 Date: 11/07/2005
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   27.91
absorbance
   27.82
absorbance
   27.88
absorbance
   27.87
  0.0433
    0.16
absorbance
 StndConc
 mg/L
   27.91
is greater
   27.82
is greater
   27.88
is greater
   27.87
  0.0433
    0.16
is greater
BlnkCorr
 Signal
  0.982
than that
  0.979
than that
  0.981
than that
  0.980
  0.002
   0.16
than that
 Peak     Bkgnd    Time
 Area     Area
 0.849     0.179  15:36:32
of the highest standard.
 0.846     0.179  15:36:34
of the highest standard.
 0.848     0.180  15:36:36
of the highest standard.
of the highest standard.
Element: Ni    Seq. No.: 121
Sample ID: CCB
                           AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
0.
0.
0.
0.
0.
StndConc
mg/L
0025
0061
0167
0084
0074
0.
0.
0.
0.
0.
0025
0061
0167
0084
0074
BlnkCorr
Signal
0.
0.
0.
0.
0.
000
000
001
000
000
Peak
Area
-0.
-0.
-0.


132
132
132


Bkgnd
Area
0
0
0


.166
.166
.166


Time

15:37:17
15:37:19
15:37:21


%RSD:
          87.95
                     87.95
                         87.95
Element: Ni    Seq. No.: 122
Sample ID: 306-1 SER
                           AS Loc.
                                                 Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
16.24
absorbance
16.28
absorbance
16.29
absorbance
16.27
0.0272
0.17
absorbance
S
m

is

is

is



is
tndConc
g/L
16.24
greater
16.28
greater
16.29
greater
16.27
0.0272
0.17
greater
Blnk
Sig
0.
than
0.
than
0.
than
0.
0.
0
than
Corr
nal
571
that
573
that
573
that
572
001
.17
that
Pe
Ar
0.
of
0.
of
0.
of



of
ak
ea
439
the
440
the
440
the



the
Bkgnd
Area
0.17
highest
0.17
highest
0.17
highest



highest


0
st
1
st
1
st



st
Time

15:37:
andard.
15:38:
andard.
15:38:
andard.



andard.


59

01

03





Element: Ni    Seq. No.:  123
Sample ID: CCB
                           AS  Loc.
                                                 Date:  11/07/2005
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
0.0215
-0.0321
-0.0131
-0.0079
0.0272
StndConc
mg/L
0.0215
-0.0321
-0.0131
-0.0079
0.0272
BlnkCorr
Signal
0.001
-0.001
0.000
0.000
0.001
Peak
Area
-0.132
-0.134
-0.133


Bkgnd
Area
0.165
0.165
0.165


Time

15:38
15:38
15:38




:22
:24
:26


%RSD:
           343.1
                      343.1
                        343.14
                                           Page 31

-------
Element: Ni    Seq. No.:
Sample ID: 306-1 X10
                         124
                           AS LOG.
                                                 Date: 11/07/2005
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
3D   :
%RSD:
Sample
SampleConc
mg/L
   11.65
absorbance
   11.61
absorbance
   11.63
absorbance
   11.63
  0.0227
    0.20
absorbance
 StndConc
 mg/L
   11.65
is greater
   11.61
is greater
   11.63
is greater
   11.63
  0.0227
    0.20
is greater
BlnkCorr
 Signal
  0.410
than that
  0.408
than that
  0.409
than that
  0.409
  0.001
   0.20
than that
 Peak     Bkgnd    Time
 Area     Area
 0.277     0.166  15:39:05
of the highest standard.
 0.276     0.167  15:39:08
of the highest standard.
 0.277     0.168  15:39:10
of the highest standard.
of the highest standard.
Element: Ni    Seq.
Sample ID: CCB
                    No.: 125
                           AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0

.0823
.0703
.0825
.0784
.0070
8.89
StndConc
mg/L
0.
0.
0.
0.
0.

0823
0703
0825
0784
0070
8.89
BlnkCorr Peak
Signal Area
0
0
0
0
0

.003 -0.130
.002 -0.130
.003 -0.130
.003
.000
8.89
Bkgnd Time
Area
0.161 15:40:11
0.161 15:40:13
0.161 15:40:15



Element: Ni    Seq. No.: 126
Sample ID: 306-1 X25
                                  AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.726
absorbance
5.741
absorbance
5.708
absorbance
5.725
0.0165
0.29
absorbance
StndConc
mg/L

is

is

is



is
5.726
greater
5.741
greater
5.708
greater
5.725
0.0165
0.29
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
201
that
202
that
201
that
201
001
.29
that
Peak
Area
0.
of
0.
of
0.
of



of
069
the
069
the
068
the



the
Bkgnd
Area


0.166
highest
Time

15:40:


37
standard.
0.166
highest
15:40:
39
standard.
0.167
highest



highest
15:40:
41
standard.









standard.
Element: Ni    Seq. No.: 127
Sample ID: CCB
                           AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.0570
.0257
.0072
.0300
.0252
84.01
StndConc
mg/L
-0
-0
-0
-0
0

.0570
.0257
.0072
.0300
.0252
84.01
BlnkCorr
Signal
-0.002
-0.001
0.000
-0.001
0.001
84.01
Peak
Area
-0.
-0.
-0.



135
133
133



Bkgnd
Time

Area
0
0
0



.165
.164
.164



15:40:
15:40:
15:40:



55
57
59



                                           Page 32

-------
Element: Ni    Seq.
Sample ID: CCB
                    No.: 128
AS LOG.
               Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0635
0.0660
0.0576
0.0624
0.0043
6.89
StndConc
mg/L
0.0635
0.0660
0.0576
0.0624
0.0043
6.89
BlnkCorr Peak
Signal Area
0.002 -0.130
0.002 -0.130
0.002 -0.131
0.002
0.000
6.89
Bkgnd Time
Area
0.161 15:41:39
0.161 15:41:41
0.161 15:41:43



Element: Ni    Seq. No.: 129
Sample ID: CCV
AS LOG.
               Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0

.5086
.4838
.4892
.4939
.0130
2.63
StndConc
mg/L
0.
0.
0.
0.
0.

5086
4838
4892
4939
0130
2.63
BlnkCorr Peak
Signal Area
0.
0.
0.
0.
0.
2
018 -0.115
017 -0.116
017 -0.115
017
000
.63
Bkgnd Time
Area
0.163 15:42:01
0.164 15:42:03
0.164 15:42:05



Element: Ni    Seq. No.: 130
Sample ID: CCB
AS Loc.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0150
-0.0110
-0.0386
-0.0215
0.0149
69.14
StndConc
mg/L
-0.0150
-0.0110
-0.0386
-0.0215
0.0149
69.14
BlnkCorr Peak
Signal Area
-0.001 -0.133
0.000 -0.133
-0.001 -0.134
-0.001
0.001
69.14
Bkgnd Time
Area
0.164 15:42:22
0.163 15:42:24
0.164 15:42:26



Element: Ni    Seq. No.: 131
Sample ID: 306-2
AS Loc.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.557
absorbance
6.589
absorbance
6.615
absorbance
6.587
0.0288
0.44
absorbance
StndConc
mg/L
6.557
is greater
6.589
is greater
6.615
is greater
6.587
0.0288
0.44
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
231
that
232
that
233
that
232
001
.44
that
Peak
Area
0
of
0
of
0
of



of
.098
the
.099
the
.100
the



the
Bkgnd
Area

0.171
highest
Time

15:42:


39
standard.
0.171
highest
15:42:
42
standard.
0.171
highest



highest
15:42:
44
standard.









standard.
                                           Page  33

-------
Element: Mi     Seq.  No.:  132
Sample  ID: CCB
AS  LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0793
0.0751
0.0692
0.0745
0.0051
6.79
StndConc
mg/L
0.0793
0.0751
0.0692
0.0745
0.0051
6.79
BlnkCorr Peak
Signal Area
0.003 -0.130
0.003 -0.130
0.002 -0.130
0.003
0.000
6.79
Bkgnd Time
Area
0.161 15:42:56
0.162 15:42:58
0.161 15:43:00



Element: Ni     Seq. No.:  133
Sample ID: 306-3
AS  LOG.
Date: 11/07/2005
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
24.44
absorbance
24.47
absorbance
24.45
absorbance
24.45
0.0189
0.08
absorbance
StndConc
mg/L

is

is

is



is
24.44
greater
24.47
greater
24.45
greater
24.45
0.0189
0.08
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
860
that
861
that
860
that
860
001
.08
that
Peak
Area
0
of
0
of
0
of



of
.727
the
.728
the
.728
the



the
Bkgnd
Area


0.176
highest
Time

15:43:


18
standard.
0.176
highest
15:43:
20
standard.
0.176
highest



highest
15:43:
22
standard.









standard.
Element: Ni    Seq. No.: 134
Sample ID: CCB
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0384
0.0240
0.0046
0.0223
0.0170
76.12
StndConc
mg/L
0.0384
0.0240
0.0046
0.0223
0.0170
76.12
BlnkCorr Peak
Signal Area
0.001 -0.131
0.001 -0.132
0.000 -0.132
0.001
0.001
76.12
Bkgnd Time
Area
0.164 15:43:43
0.164 15:43:45
0.165 15:43:48



Element: Ni    Seq. No.: 135
Sample ID: 306-3 X25
AS LOG.
Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
3.083
3.065
3.059
3.069
0. 0124
0.40
StndConc
mg/L
3.083
3.065
3.059
3.069
0.0124
0.40
BlnkCorr Peak
Signal Area
0.108 -0.024
0.108 -0.025
0.108 -0.025
0.108
0.000
0.40
Bkgnd Time
Area
0.164 15:44:42
0.165 15:44:45
0.165 15:44:47



                                           Page  34

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: CCB
SampleConc
mg/L
-0.1093
-0.0679
-0.0162
-0.0644
0.0467
72.42
: Ni Seq
ID: 306-4
SampleConc
mg/L
0.0127
-0.0183
-0.0289
-0.0115
0.0216
188.6
: Ni Seq
ID: CCB
SampleConc
mg/L
0.0835
0.0926
0.0821
0.0861
0.0057
6.61
: Ni Seq
ID: 306-5
SampleConc
mg/L
0.1306
0.1487
0.1567
0.1453
0.0133
9.18
. No. : 136

StndConc
mg/L
-0.1093
-0.0679
-0.0162
-0.0644
0.0467
72.42
. No. : 137

StndConc
mg/L
0.0127
-0.0183
-0.0289
-0.0115
0.0216
188.6
. No. : 138

StndConc
mg/L
0.0835
0.0926
0.0821
0.0861
0.0057
6.61
. No. : 139

StndConc
mg/L
0.1306
0.1487
0.1567
0.1453
0.0133
9.18
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.004 -0.136
-0.002 -0.135
-0.001 -0.133
-0.002
0.002
72.42
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 -0.132
-0.001 -0.133
-0.001 -0.134
0.000
0.001
188.57
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 -0.130
0.003 -0.129
0.003 -0.130
0.003
0.000
6.61
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 -0.128
0.005 -0.127
0.006 -0.127
0.005
0.000
9.18
Date: 11/07/2005

Bkgnd Time
Area
0.168 15:44:59
0.166 15:45:01
0.165 15:45:04



Date: 11/07/2005

Bkgnd Time
Area
0.167 15:45:18
0.167 15:45:21
0.168 15:45:23



Date: 11/07/2005

Bkgnd Time
Area
0.161 15:45:38
0.161 15:45:40
0.161 15:45:42



Date: 11/07/2005

Bkgnd Time
Area
0.164 15:45:57
0.165 15:46:00
0.165 15:46:02



Page 35

-------
Element: Ni    Seq. No.: 140
Sample ID: CCB
                           AS LOG.
                                                 Date: 11/07/2005
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.0432
.0378
.1481
.0764
. 0622
81.43
StndConc
mg/L
-0
-0
-0
— 0
0

.0432
.0378
.1481
.0764
.0622
81.43
BlnkCorr
Signal
-0.002
-0.001
-0.005
-0.003
0.002
81.43
Peak
Area
-0.
-0.
-0.



134
134
138



Bkgnd
Time

Area
0.
0.
0.



165
165
169



15:46:
15:46:
15:46:



12
14
16



Element: Ni    Seq. No.: 141
Sample ID: CCV
                           AS LOG.
                                                 Date: 11/07/2005
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   10.04
absorbance
   10.00
absorbance
   10.22
absorbance
   10.09
  0.1181
    1.17
absorbance
 StndConc
 mg/L
   10.04
is greater
   10.00
is greater
   10.22
is greater
   10.09
  0.1181
    1.17
is greater
BlnkCorr
 Signal
  0.353
than that
  0.352
than that
  0.360
than that
  0.355
  0.004
   1.17
than that
 Peak     Bkgnd    Time
 Area     Area
 0.221     0.169  15:46:38
of the highest standard.
 0.219     0.169  15:46:40
of the highest standard.
 0.227     0.170  15:46:42
of the highest standard.
of the highest standard.
                                          Page 36

-------
                                                                                           Set*
Prep Method :      (check only one per page)
     ICP/FLAA:  SU 3030 F, EPA 200.7 '82
     ICP/FLAA:  EPA 200's, SW-846 301OA
     ICP/FLAA:  EPA 200.7 r4.4
     ICP/FLAA:  SW-846 3005A
     ICP/FLAA:  SW-846 3015A MICROWAVE
     OTH ER:	
                                                 GFAA: SM3030E
                                                 GFAA: EPA 200's, SW-846 3020A
                                                 GFAA: EPA 200.9
                                                 GFAA: SW-846 3015A (NoHCL) MICROWAVE
                                                 OTHER:	
MATRIX:             (check only one per page)
     DRINKING WATER                       I   (AQUEOUS
                                                                             OTHER:
SPIKING STDS
QC-21
QC-7
P
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OTHER
PROVIDER
<^P \




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                                                                              Start Date:
                                                                                                S\QA FORMS \FM-041 \R02 \LK
                                                                                                           Page 1 of 1

-------
ME
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A: SM 3030 F, EPA 200.7 '82
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               Page 1 of 1

-------
METALS PREP FORM
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Page 1 of 1

-------
PROJECT  #
  1         2
2005110203:
   345
METHOD 29  FOR  NICKEL
   6789         10
11
12
SA#
2
3
1
5
6

8
9
7
11
12
10
14
15

17
18
16
20
21
19
23
24

26
27

29
30

32
33




SAMPLE
DESCRPT1ON
impinger
filter
probe rinse
impinger
filter

impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter

impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter

impinger
filter

impinger
filter

impinger
filter

impinger
'filte'K\ •

RUN ID

Cond. 14:
TEST #1


Cond. 14:
TEST #2


Cond. 14:
TEST #3

BLANK

Cond. 7: TEST
#1
Cond. 7: TEST
#2

Cond. 7: TEST
#3
BLANK
Cond. 24:
TESTS1

Cond. 24:
TEST #2


Cond. 24:
RUN #3


/' MDL -/

PH
<2.0

<2.0
<20

<20
<20

<2.0
<20

<2.0
<20


<20

<2.0
<20

<2.0
<2.0

< 20
<20

<20
<20

<20
< 2 C

<20



Sample
Fraction
(SF = SFA)
313
1 filter
92.0
315
1 filter
94 0
312
1 filter
97.0
298
1 filter
98.0
296
1 filter
97 0
296
1 filter
98.0
297
1 filter
96.0
299
1 filter

298
1 filter
99.0
300
1 filter
100.0

1 filter
97 0
3ti0
;- 1 filter
- 180,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
•~ ;NA",
^20- =
REAGENTS
FOR DIG.
HNO3 -v H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3

HF + HNO3
HF + HNO3
HN03 * H202
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3

HF + HNO3
HF + HNO3
HNO3 + H202
HF + HN03
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF +• HNO3

HF + HNO3
HF + HNO3

HF + HNO3
HF + HNO3

HF + HN03
HF + HNO3

•'H|!*HN03
HJi& HN03
MICRO-
Dig. BY
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2

8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2

8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2

8.3.1.2
8.3.1.2

8.3.1.2
8.3.1.2

8.3.1.2
8.3.1.2

' 8.3,15
8,3.12-
Analytical
Fraction
(AF = AF.O
50
100
50
100

100
50
100
50
100
50
100
50
100
50
100
50
100
50
100

50
100

- 50V
£:t100>
\ «
Nl mg/L
( Ca1 or Ca2 )
0.135
0.265
0.101
0.319
0.111
0.256
0.080
0.159
0.101
2.434

2.763
< 0.074
-6.164
0.084
0.183
0.095
1.472

2.277
< 0.074
2.123
' , 0.075" *
,/' 0.075
MGNI
IN INITIAL
SAMPLE
0.007
0.027
0.005
0.032

0.026
0.004
0.016
0.005
0.243

0.276
0.004
0.616
0.004
0.018

0.147

0.228
0.004
0.212
* 0.004
'* -o;oos
^ o ;; -
TOTAL MG
PER RUN
0.033
0.037
0.031
0.020
0.248
0.280
0.620
0.023
0.152
0.232

0.216

o;on
  10  Samples that read 
-------
PROJECT  #  2005120032:   METHOD 306A FOR NICKEL
                                                                                                8
SA#
1
2
3
4
*
SAMPLE DESCRPTION
12/01/2005 -CONDITION
#26 - RUN #1
12/01/2005 -CONDITION
#26 - RUN #2
12/01/2005 - CONDITION
#26 - RUN #3
12/01/2005 -BLANK
'\WZfc;>~J
PH
<2.0
<2.0
<2.0
<2.0
" ~^2^"
Sample
Fraction
397.0
395.0
388.0
360.0
- "<;
REAGENTS FOR
DIG.
HNO3
HNO3
HNO3
HNO3
~ ' ' KiiJOS
Analytical
Fraction
50.0
50.0
50.0
50.0
-x; 50.o ,;;
Nl mg/L
1.324
2.388
2.139
0.101
~'sr 0.075 "'.,
TOTAL MG Nl
(OR IN INITIAL SAMPLE)
0.066
0.119
0.107
0.005
0,004
    Samples that read 
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
r    5100 AA

  1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
  2 INSTRUMENT SET-UP:
                                                                       Date: _
                                                                     Analyst:
     2/1/2006
       LK
(For Specific instrument settings, see current copy of method.)
      (Mfl/L)
 tDL- 0.027
MDL= 0.075
 RL = 0.10
LDR = 0.10 to 8.0
3
CALIBRATION:
Cal Curve:





Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Abs
0.012
0.022
0.041
0.079
0.182

Result
0.315
0.592
1.111
2.121
4.908
0.9984
% Rec.
126.0
118.4
111.1
106.1
98.2

                                                     4 STANDARD TRACEABILITY
                                                       QC STANDARD
                                                                    Standard Name, Company, & Lot #
                                                       Calibration
                                                                    CPIQC-21 Lot#05H062
                                                       CCV. CRA, AAT
                                                                    CPIQC-21 Lot#05H062
                                                       QCS, LFM
                                                                    CPIQC-19Lot#05F011
                                     > 0.935)
s SAMPLE ANALYTICAL RUN
MAT-RIX








M2^
20XMDL)
<10%DIFF)
20XMDL)
(<10%DIFF)
(< MDL )
(90-110%R)
^
2/^
(< MDL )
( 90-11 0%R)



-------
QA/QC WORK SHEET for NICKEL  P2
FKAA METHOD SOP MET-040
    5100 AA
  Date:
Analyst:
2/1/2006
  LK
* QAMPI F ANALYTICAL RUN
MAT-RIX
M29




M29



M29
M29


M29
M29
M29
M29


M29


M29
WI29


SAMPLE
203-31+33
LRB
LFB
CCB
CCV
*203-2
SPK
DUP
SER DiL
203-5
203-8
CCB
CCV
203-1 1
203-14
203-17
203-20
CCB
CCV
203-23
203-26
DUP
703 29
203-32
CCB
CCV
STD CONC


1 00

050

1.0
1.0




025





050






1.00
READING
Mg/L
0.219
0.112
1.084
0024
0542
0 153
1.119
1.094
0.281
0 133
0.128
0019
0.281
0.118
0 122
0073
0069
0004
0490
0069
0.093
0.100
0083
0071
0003
0.940
BLK
0.035
0.035
0022
0.010
0024
0018
0.025
0035
-0.004
0032
0.017
0035
0019
0039
0.021
0.007
0000
-0.004
0004
-0.015
-0 002
-0.011
-0.001
0004
0010
0003
RESULT
0 183
0.077
1.062
0.014
0518
0.135
1.094
1 059
0.285
0.101
0.111
-0.016
0.262
0.080
0.101
0067
0069
0009
0485
0.084
0.095
0.112
0.084
0.066
-0.007
0937
DILI
1.0




1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0


1.0
1.0

1.0
1.0


DIL 2
1.0




1.0
• .0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
-.0


1.0
1.0

1.0
-.0


QC
RESULTS

0.077
106
0.014
104

96
3.3
30.4


-0.016
105




0.009
97


16.3


-0.007
94

Mg/L
0.183




0.135



0.101
0.111


0.080
0.101
0.067
0.069


0.084
0.095

0.084
0.066



REPT
mq/L
0.183




0.135



0.101
0.111


0.080
0.101
0.074
0.074


0.084
0.095

0.084
0.074



!££

o . c "I V



Q. *&!>







, i>TJ





a£> / L> 5;






                                                                       20XMDL)
                                                                       <10%DIFF)
                                                                       ;< MDL }
                                                                        90-110%R)
                                                                       (< MDL)
                                                                       (90-110%R)
                                                                       ;< MDL )
                                                                       ( 90-110%R)

-------
Method Name: NI
Method Description: Nickel

Date: 02/01/2006
Technique: Flame
Wavelength: 232.0 nm
Lamp Current: 20
Sample Info File: Untitled
                                Element:  Ni
Calibration Equation: Zero Intercept: Linear
Slit Width: 0.20 nm
Energy: 71
Results Data Set:
Element: Ni     Seq. No.:  115
  AS Loc.
                                                 Date:  02/01/2006
Repl
#
i
j.
0
£,
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
232.33
Peak
Area
0.097
0.097
0.098



Bkgnd
Area
0.006
0.006
0.006



Time
15:02:30
15:02:32
15:02:34



Auto-zero performed.
 Element:  Ni    Seq.  No.:  116
 Sample ID:  Calib Blank
  AS Loc.
                                                  Date:  02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc
mg/L mg/L





BlnkCorr
Signal
-0.001
0.000
0.000
0.000
0.001
347.18
Peak
Area
0.096
0.098
0.098



Bkgnd
Area
0.007
0.006
0.006



Time
15:02:39
15:02:41
15:02:43



Auto- zero performed.
 Element:  Ni    Seq.  No.:  117
 Sample ID:  CAL STD
  AS  Loc.
                                                  Date:  02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr
mg/L mg/L Signal
0.012
0.012
0.012
0.012
0.000
1.65
Peak
Area
0.109
0.109
0.109



Bkgnd
Area
0.005
0.005
0.005



Time
15:03:16
15:03:18
15:03:20



 Standard number 1 applied. [0.25]
 Correlation Coefficient:  0.9991
                  Slope:  0.0358
                                            Page  32

-------
Element; Ni Seq. No.: 118 AS :
Sample ID: cal std 2
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
I 0.022
2 0.023
3 0.022
Mean: 0.022
SD : 0.000
%RSD: 2.16
Standard number 2 applied. [0.50]
Correlation Coefficient: 0.9987
Element: Ni Seq. No.: 119 AS
Sample ID: cal std 3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.041
2 0.042
3 0.041
Mean: 0.041
SD : 0.001
%RSD: 1-44
Standard number 3 applied. [1.00]
Correlation Coefficient: 0.9982
Element: Ni Seq. No.: 120 AS
Sample ID: cal std 4
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.079
2 0.078
3 0.079
Mean: 0.079
SD : 0.001
%RSD: 1-09
Standard number 4 applied. [2.00]
Correlation Coefficient: 0.9973
Element: Ni Seq. No.: 121 AS
Sample ID: cal std 5
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.182
2 0.182
3 0.183
Mean: 0.182
SD : 0.001
%RSD: 0.41
Loc. : 	
Peak
Area
0.119
0.120
0.119
Loc. : 	
Peak
Area
0.138
0.139
0.139
Loc. : 	
Peak
Area
0.176
0.175
0.177
Loc. : 	
: Peak
Area
0.279
0.279
0.280
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:03:35
0.004 15:03:37
0.005 15:03:39
Slope: 0.0359
Date: 02/01/2006
Bkgnd Time
Area
0.006 15:04:04
0.005 15:04:06
0.005 15:04:08
Slope: 0.0359
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:04:33
0.006 15:04:35
0.005 15:04:37
Slope: 0.0362
Date: 02/01/2006
Bkgnd Time
Area
0.005 15:04:56
0.004 15:04:59
0.005 15:05:01
The calibration curve may not be linear.
Standard number 5 applied. [5.00]
Correlation Coefficient:  0.9984
Slope: 0.0371
                                           Page  33

-------
a>
o



I
O
W
        0.20
        0.15
0.10
        0.05
                                   Concentration
_C3.-L_UiJ.Lei L-O-WXi v-ia. <-a. J-v-'-i- A*
Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5

Mean Signal
(Absorbance)
0.000
0.012
0.022
0.041
0.079
0.182
Correlation Coefficient: 0.99840
Entered
Concentration
(mg/L)
0.25
0.50
1.00
2.00
5.00
Slope: 0.
Calculated
Concentration
(mg/L)
0.000
0.3151
0.5922
1.111
2.121
4.908
03712

Standard
Deviation
0.0009
0.0002
0.0005
0.0006
0.0009
0.0007


%RSD
347.1791
1.6548
2.1610
1.4366
1.0851
0.4110

          No.:  122
                 AS Loc.
                                          Date:  02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4. 920
4.914
4.968
4.934
0.0296
0.60
StndConc
mg/L
4.920
4.914
4.968
4.934
0.0296
0.60
BlnkCorr Peak
Signal Area
0.183 0.280
0.182 0.280
0.184 0.282
0.183
0.001
0.60
Bkgnd Time
Area
0.006 15:05:13
0.006 15:05:15
0.005 15:05:18



                                   Page 34

-------
                    No.:  123
                                  AS  Loc.
                                                 Date:
                                                       02/01/2006
Repl
# :
i
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
2.148
2.118
2.137
2.134
0.0154
0.72
StndConc
mg/L
2.148
2.118
2.137
2.134
0.0154
0.72
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.080 0.177 0.006 15:05:44
0 079 0.176 0.005 15:05:46
o!o79 0.177 0.005 15:05:48
0.079
0.001
0.72
Element: Ni    Seq,
Sample ID: std-10
                    No.: 124
                                  AS Loc.
                                                 Date:  02/01/2006
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   8.988
absorbance
   8.885
absorbance
   9.003
absorbance
   8.959
  0.0641
    0.72
absorbance
 StndConc
 mg/L
   8.988
is greater
   8.885
is greater
   9.003
is greater
   8.959
  0.0641
    0.72
is greater
BlnkCorr
 Signal
  0.334
than that
  0.330
than that
  0.334
than that
  0.333
  0.002
   0.72
than that
 Peak     Bkgnd    Time
 Area     Area
 0.431     0.006  15:06:19
of the highest standard.
 0.427     0.006  15:06:21
of the highest standard.
 0.431     0.005  15:06:23
of the highest standard.
of the highest standard.
Element: Ni    Seq. No.: 125
                           AS Loc.
                                                 Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0065
0.0023
0.0043
0.0001
0.0058
StndConc
mg/L
-0.0065
0.0023
0.0043
0.0001
0.0058
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
Peak
Area
0.097
0.097
0.097


Bkgnd
Area
0.006
0.006
0..006


Time
15:09:
15:09:
15:09:



53
55
57


%RSD:
            9583
                       9583
                       9582.80
Element: Ni     Seq. No.:  126
Sample  ID: cra-0.05
                           AS  Loc.
                                                 Date:  02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.

0991
0852
0998
0947
0082
8.69
StndConc
mg/L
0.0991
0.0852
0.0998
0.0947
0.0082
8.69
BlnkCorr
Signal
0.004
0.003
0.004
0.004
0.000
8.69
Peak
Area
0.101
0
0



.100
.101



Bkgnd
Area
0.005
0.
0.



006
005



Time
15:
15:
15:



10
10
10



:19
:21
:23



                                           Page 35

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0187
2 0.0294
3 0.0086
Mean: 0.0189
3D : 0.0104
%RSD: 54.77
Element: Ni Seq.
Sample ID: era- 0.1
Repl SampleConc
# mg/L
1 0.1378
2 0.1557
3 0.1283
Mean: 0.1406
3D : 0.0139
%RSD: 9-89
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0418
2 0.0314
3 0.0124
Mean: 0.0285
Si) : 0.0149
%RSD: 52.18
Element: Ni Seq
Sample ID: cra-0.1
Repl SampleConc
# mg/L
1 0.1277
2 0.1313
3 0.1104
Mean: 0.1232
SD : 0.0112
%RSD: 9.07
No. : 127

StndConc
mg/L
0.0187
0.0294
0.0086
0.0189
0.0104
54.77
No.: 128

StndConc
mg/L
0.1378
0.1557
0.1283
0.1406
0.0139
9.89
= 	 :
. No. : 129

StndConc
mg/L
0.0418
0.0314
0.0124
0.0285
0.0149
52.18
. No. : 130

StndConc
mg/L
0.1277
0.1313
0.1104
0.1232
0.0112
9.07
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.001 0.098
0.001 0.098
0.000 0.098
0.001
0.000
54.77
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.102
0.006 0.103
0.005 0.102
0.005
0.001
9.89
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.099
0.001 0.098
0.000 0.098
0.001
0.001
52.18
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.102
0.005 0.102
0.004 0.101
0.005
0.000
9.07
Date; 02/01/2006

Bkgnd Time
Area
0.006 15:10:39
0.005 15:10:42
0.006 15:10:44



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:11:04
0.005 15:11:06
0.006 15:11:08



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:11:21
0.005 15:11:23
0.006 15:11:25



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:11:59
0.006 15:12:01
0.006 15:12:03



Page 36

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0068
2 0.0050
3 -0.0031
Mean: 0.0029
SD : 0.0053
%RSD: 179.4
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 0.1121
2 0.1043
3 0.0726
Mean: 0.0963
SD : 0.0209
%RSD: 21.70
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0236
2 0.0335
3 0.0150
Mean: 0.0240
SD : 0.0093
%RSD: 38.65
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.110
2 1.082
3 1.065
Mean: 1.086
SD : 0.0227
%RSD: 2.09
. No. : 131

StndConc
mg/L
0.0068
0.0050
-0.0031
0.0029
0.0053
179.4
. No. : 132

StndConc
mg/L
0.1121
0.1043
0.0726
0.0963
0.0209
21.70
. No.: 133

StndConc
mg/L
0.0236
0.0335
0.0150
0.0240
0.0093
38.65
. No.: 134

StndConc
mg/L
1.110
1.082
1.065
1.086
0.0227
2.09
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
179.37
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 0.101
0.004 0.101
0.003 0.100
0.004
0.001
21.70
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.098
0.001 0.098
0.001 0.098
0.001
0.000
38.65
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.138
0.040 0.137
0.040 0.137
0.040
0.001
2.09
Date: 02/01/2006

Bkgnd Time
Area
0.006 15:12:19
0.006 15:12:21
0.006 15:12:24



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:12:40
0.005 15:12:42
0.006 15:12:45



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:12:59
0.006 15:13:01
0.006 15:13:03



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:13:27
0.005 15:13:29
0.006 15:13:31



Page 37

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0294
2 0.0375
3 0.0290
Mean: 0.0320
SD : 0.0048
%RSD: 14.99
Element: Ni Seq
Sample ID: *038-1
Repl SampleConc
# mg/L
I 1.353
2 1.355
3 1.361
Mean: 1.356
SD : 0.0042
%RSD: 0.31
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0155
2 0.0348
3 0.0254
Mean: 0.0252
SD : 0.0096
%RSD: 38.22
Element : Ni Seq
Sample ID: s038-l
Repl SampleConc
# mg/L
1 2.234
2 2.194
3 2.237
Mean: 2.222
SD : 0.0238
%RSD: 1.07
. No. : 135 AS I

StndConc BlnkCorr
mg/L Signal
0.0294 0.001
0.0375 0.001
0.0290 0.001
0.0320 0.001
0.0048 0.000
14.99 14.99
. No. : 136 AS I

StndConc BlnkCorr
mg/L Signal
1.353 0.050
1.355 0.050
1.361 0.051
1.356 0.050
0.0042 0.000
0.31 0.31
. No. : 137 AS :

StndConc BlnkCorr
mg/L , Signal
0.0155 0.001
0.0348 0.001
0.0254 0.001
0.0252 0.001
0.0096 0.000
38.22 38.22
. No. : 138 AS

StndConc BlnkCorr
rng/L Signal
2.234 0.083
2.194 0.081
2.237 0.083
2.222 0.082
0.0238 0.001
1.07 1.07
JOG . : 	

Peak
Area
0.098
0.099
0.098



LOG. : 	

Peak
Area
0.147
0.148
0.148



LOG. : 	

Peak
Area
0.098
0.099
0.098



LOG. : 	

Peak
Area
0.180
0.179
0.180



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:13:43
0.005 15:13:45
.0.006 15:13:47



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:14:06
0.005 15:14:09
0.005 15:14:11



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:14:23
0.005 15:14:26
0.005 15:14:28



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:14:50
0.006 15:14:52
0.005 15:14:54



Page 38

-------
Element
Sample
Repl
#
1
2
3
Mean:
3D :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
- 3
Mean:
SD :
%RSD:
Elemenl
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: ccb
SampleConc
mg/L
0.0481
0.0263
0.0234
0.0326
0.0135
41.38
:: Ni Seq,
ID: sd038-l
SampleConc
mg/L
2.149
2.170
2.185
2.168
0.0183
0.84
;: Ni Seq
ID: ccb
SampleConc
mg/L
0.0452
0.0465
0.0396
0.0438
0,0036
8.32
-: Ni Seq
ID: ser038-
SampleConc
mg/L
0.5142
0.5086
0.5290
0.5173
0.0105
2.03
No.: 139

StndConc
mg/L
0.0481
0.0263
0.0234
0.0326
0.0135
41.38
. No.: 140

StndConc
mg/L
2.149
2.170
2.185
2.168
0.0183
0.84
. No.: 141

StndConc
mg/L
0.0452
0.0465
0.0396
0.0438
0.0036
8.32
. No. : 142
1
StndConc
mg/L
0.5142
0.5086
0.5290
0.5173
0.0105
2.03
AS I

BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.001
41.38
AS ]

BlnkCorr
Signal
0.080
0.081
0.081
0.080
0.001
0.84
AS :

BlnkCorr
Signal
0.002
0.002
0.001
0.002
0.000
8.32
AS

BlnkCorr
Signal
0.019
0.019
0.020
0.019
0.000
2.03
JOG . : 	

Peak
Area
0.099
0.098
0.098



LOG. : 	

Peak
Area
0.177
0.178
0.178



Loc. : 	

Peak
Area
0.099
0.099
0.099



Loc. : 	

Peak
Area
0.116
0.116
0.117



Date? C

Bkgnd
Area
0.005
0.005
0.005



Date: (

Bkgnd
Area
0.005
0.005
0.005



Date: i

Bkgnd
Area
0.005
0.005
0.005



Date:

Bkgnd
Area
0.005
0.005
0.005



12/01/2006

Time
15:15:08
15:15:10
15:15:12



)2/01/2006

Time
15:15:37
15:15:39
15:15:41



02/01/2006

Time
15:16:01
15:16:03
15:16:05



02/01/2006

Time
15:16:33
15:16:35
15:16:38



Page 39

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0339
2 0.0202
3 -0.0227
Mean: 0.0105
SD : 0.0295
%RSD: 282.4
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0025
2 0.0141
3 -0.0097
Mean: 0.0006
SD : 0.0122
%RSD: 2031
Element: Ni Seq,
Sample ID: ccv-1
Repl SampleConc
# mg/L
1 1.113
2 1.109
3 1.089
Mean: 1.104
SD : 0.0129
%RSD: 1.17
Element: Ni Seq
Sample ID: ccv-1
Repl SampleConc
# mg/L
1 0.9836
2 0.9625
3 1.004
Mean: 0.9835
SD : 0.0209
%RSD: 2.13
No.: 143

StndConc
mg/L
0.0339
0.0202
-0.0227
0.0105
0.0295
282.4
No.: 144

StndConc
mg/L
-0.0025
0.0141
-0.0097
0.0006
0.0122
2031
.No.: 145

StndConc
mg/L
1.113
1.109
1.089
1.104
0.0129
1.17
. No.: 146

StndConc
mg/L
0.9836
0.9625
1.004
0.9835
0.0209
2.13
AS I

BlnkCorr
Signal
0.001
0.001
-0.001
0.000
0.001
282.44
AS 1

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
2030.57
AS :

BlnkCorr
Signal
0.041
0.041
0.040
0.041
0.000
1.17
AS

BlnkCorr
Signal
0.037
0.036
0.037
0.037
0.001
2.13
ioc. : 	

Peak
Area
0.098
0.098
0.096



Joe. : 	

Peak
Area
0.097
0.098
0.097



LOG. : 	

Peak
Area
0.139
0.138
0.138



Loc. : 	

Peak
Area
0.134
0.133
0.135



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:17:03
0.005 15:17:05
0.007 15:17:07



Date: 02/01/2006

Bkgnd Time
Area
0.007 15:17:21
0.006 15:17:23
0.007 15:17:25



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:17:50
0.005 15:17:52
0.006 15:17:54



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:18:19
0.006 15:18:21
0.005 15:18:23



Page 40

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0002
2 -0.0004
3 -0.0027
Mean: -0.0010
SD : 0.0015
%RSD: 159.5
Element: Ni Seq.
Sample ID: 038-2
Repl SampleConc
# mg/L
1 2.404
2 2.397
3 2.360
Mean: 2.387
SD : 0.0239
%RSD: 1.00
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0045
2 0.0196
3 0.0186
Mean: 0.0112
SD : 0.0136
%RSD: 121.4
Element: Ni Seq.
Sample ID: 038-3
Repl SampleConc
# mg/L
1 2.161
2 2.145
3 2.144
Mean: 2.150
SD : 0.0098
%RSD: 0.46
No.: 147

StndConc
mg/L
0.0002
-0.0004
-0.0027
-0.0010
0.0015
159.5
No. : 148

StndConc
mg/L
2.404
2.397
2.360
2.387
0.0239
1.00
No.: 149

StndConc
mg/L
-0.0045
0.0196
0.0186
0.0112
0.0136
121.4
No.: 150

StndConc
mg/L
2.161
2.145
2.144
2.150
0.0098
0.46
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
159.47
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.089 0.186
0.089 0.186
0.088 0.185
0.089
0.001
1.00
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
0.001 0.098
0.001 0.098
0.000
0.001
121.43
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.080 0.177
0.080 0.177
0.080 0.177
0.080
0.000
0.46
Date: 02/01/2006

Bkgnd Time
Area
0.006 15:18:45
0.006 15:18:47
0.006 15:18:49



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:19:11
0.005 15:19:14
0.006 15:19:16



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:19:42
0.006 15:19:44
0.006 15:19:46



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:20:03
0.005 15:20:05
0.006 15:20:07



Page 41

-------
Element
Sample
Repl
#
-\_
2
3
Mean:
SD :
%RSD:
: Ni Seq.
ID: ccb
SampleConc
mg/L
0. 0243
0.0160
0.0213
0.0205
0.0042
20.40
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 038-4
SampleConc
mg/L
0.1126
0.1211
0.1312
0.1216
0.0093
7.64
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0191
0.0137
0.0393
0.0240
0.0135
56.13
, No. : 151

StndConc
mg/L
0.0243
0.0160
0.0213
0.0205
0.0042
20.40
. No. : 152

StndConc
mg/L
0.1126
0.1211
0.1312
0.1216
0.0093
7.64
. No.: 153

StndConc
mg/L
0.0191
0.0137
0.0393
0.0240
0.0135
56.13
Element: Ni Sej^-~*O7-r~l-S4.,
Sample^
Repl
#
1
2
3
Mean:
SD :
%RSD:
AS I

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
20.40
JOG . : 	

Peak
Area
0.098
0.098
0.098



AS Loc. : 	

BlnkCorr
Signal
0.004
0.004
0.005
0.005
0.000
7.64

Peak
Area
0.101
0.102
0.102



AS Loc. : 	

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.001
56.13
AS

Peak
Area
0.098
0.098
0.099



Loc. : 	
Date: 0

Bkgnd
Area
0.005
0.006
0.005



2/01/2006

Time
15:20:21
15:20:24
15:20:26



Date: 02/01/2006

Bkgnd
Area
0.005
0.005
0.005




Time
15:20:40
15:20:42
15:20:44



Date: 02/01/2006

Bkgnd
Area
0.006
0.005
0.005



Date:

Time
15:21:03
15:21:05
15:21:07



02/01/2006
ID: SamplellS \
\ S \ ^ : 	 • 	
-\--- -^ 	
SalB^xLeConc
mg//L\
/ 0.0694
/ 0.0843\<
1 0.0807/
\ 0.07^1
\0-j0t) 7 8
X^9.99
	 ^
StndCorfCx
mg/L/ \
J0<0694 J
/0.0843 /
\ 0.0807/
X1.0783/
oxm-?8
s9>§9
BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
9.99
Peak
Area
0.100
0.100
0.100



Bkgnd
Area
0.005
0.005
0.005



Time
15:21:23
15:21:25
15:21:31



Page 42

-------
Element: Ni Seq.
Sample ID: 203-f+pr
Repl SampleConc
# mg/L
1 0.0899
2 0.1382
3 0.1137
Mean: 0.1139
SD : 0.0241
%RSD: 21.19
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0105
2 0.0256
3 0.0086
Mean: 0.0149
SD : 0.0093
%RSD: 62.45
Element: Ni Seq,
Sample ID: 203-f+p]
Repl SampleConc
# mg/L
1 1.109
2 1.130
3 1.124
Mean: 1.121
SD : 0.0109
%RSD: 0.97
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0105
2 0.0353
3 0.0076
Mean: 0.0178
SD : 0.0153
%RSD: 85.82
No. : lt>5
Irb
StndConc
mg/L
0.0899
0.1382
0.1137
0.1139
0.0241
21.19
No. : 156

StndConc
mg/L
0.0105
0.0256
0.0086
0.0149
0.0093
62.45
. No. : 157
c Ifb
StndConc
mg/L
1.109
1.130
1.124
1.121
0.0109
0.97
. No.: 158

StndConc
mg/L
0.0105
0.0353
0.0076
0.0178
0.0153
85.82
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.003 0.101
0.005 0.102
0.004 0.101
0.004
0.001
21.19
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0.001 0.098
0.000 0.098
0.001
0.000
62.45
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.138
0.042 0.139
0.042 0.139
0.042
0.000
0.97
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.098
0. 001 0.099
0.000 0.098
0.001
0.001
85.82
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:21:52
0.004 15:21:54
0.005 15:21:56



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:22:12
0.005 15:22:14
0.005 15:22:16



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:22:40
0.005 15:22:42
0.006 15:22:44



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:23:01
0.004 15:23:03
0.005 15:23:05



Page 43

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0189
2 0.0423
3 0.0472
Mean: 0.0362
SD : 0.0151
%RSD: 41.83
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0238
2 0.0216
3 0.0229
Mean: 0.0228
SD : 0.0011
%RSD: 4.77
Element: Ni Seq,
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.5731
2 0.5796
3 0.5672
Mean: 0.5733
SD : 0.0062
%RSD: 1.08
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0447
2 0.0335
3 0.0281
Mean: 0.0354
SD : 0.0085
%RSD: 23.86
No.: 159

StndConc
mg/L
0.0189
0.0423
0.0472
0.0362
0.0151
41.83
No.: 160

StndConc
mg/L
0.0238
0.0216
0.0229
0.0228
0.0011
4.77
. No. : 161

StndConc
mg/L
0.5731
0.5796
0.5672
0.5733
0.0062
1.08
. No.: 162

StndConc
mg/L
0.0447
0.0335
0.0281
0.0354
0.0085
23.86
AS I

BlnkCorr
Signal
0.001
0.002
0.002
0.001
0.001
41.83
AS I

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
4.77
AS :

BlnkCorr
Signal
0.021
0.022
0.021
0.021
0.000
1.08
AS

BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.000
23.86
,oc. : 	

Peak
Area
0.098
0.099
0.099



joe. : 	

Peak
Area
0.098
0.098
0.098



Loc. : 	

Peak
Area
0.119
0.119
0.118



Loc. : 	

Peak
Area
0.099
0.098
0.098



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:24:35
0.005 15:24:37
0.005 15:24:39



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:24:54
0.005 15:24:56
0.005 15:24:58



Date: 02/01/2006

Bkgnd Time
Area
0.004 15:25:24
0.004 15:25:26
0.005 15:25:28



Date: 02/01/2006

Bkgnd Time
Area
0.00.4 15:25:54
0.005 15:25:56
0.004 15:25:59



Page 44

-------
Element: Ni Seq. No.: 163 AS i
Sample ID: *203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 0.2977 0.2977 0.011
2 0.3029 0.3029 0.011
3 0.3013 0.3013 0.011
Mean: 0.3006 0.3006 0.011
SD : 0.0027 0.0027 0.000
%RSD: 0.89 0.89 0.89
Element: Ni Seq. No. : 164 AS ]
Sample ID: ccb
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 -0.0061 -0.0061 0.000
2 -0.0292 -0.0292 -0.001
3 -0.0218 -0.0218 -0.001
Mean: -0.0190 -0.0190 -0.001
SD : 0.0118 0.0118 0.000
%RSD: 61.86 61.86 61.86
Element: Ni Seq. No. : 165 AS :
Sample ID: s203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.303 1.303 0.048
2 1.310 1.310 0.049
3 1.346 1.346 0.050
Mean: 1.320 1.320 0.049
SD : 0.0229 0.0229 0.001
%RSD: 1.73 1.73 1.73
Element: Ni Seq. No.: 166 AS
Sample ID: s203-l+3
Repl SampleConc StndConc BlnkCorr
# mg/L mg/L Signal
1 1.314 1.314 0.049
2 1.262 1.262 0.047
3 1.250 1.250 0.046
Mean: 1.275 1.275 0.047
SD : 0.0341 0.0341 0.001
%RSD: 2.67 2.67 2.67
JOG . : 	

Peak
Area
0.108
0.108
0.108



Joe. : 	

Peak
Area
0.097
0.096
0.096



Loc. : 	

Peak
Area
0.146
0.146
0.147



Loc. : 	

Peak
Area
0.146
0.144
0.144



Dates 02/01/2006

Bkgnd Time
Area
0.006 15:28:11
0.006 15:28:13
0.006 15:28:15



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:28:39
0.007 15:28:42
0.007 15:28:44



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:29:18
0.005 15:29:21
0.005 15:29:23



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:29:41
0.007 15:29:44
0.007 15:29:46



Page 45

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc \
4i TtlQ/L
I 0.0034 /
2 -11. 33/
3 -6.31/
Mean: -5.8/82
SD : V^79
%RSD: X6-55
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0114
2 -0.0067
3 -0.0157
Mean: -0.0112
SD : 0.0045
%RSD: 40.12
Element: Ni Seq
No.: 167
/
•—/—
StendConc
\.0034
-\1.33
-6\319
-5.15182
5.6\9
96.55O
, No.: 168

StndConc
mg/L
-0.0114
-0.0067
-0.0157
-0.0112
0.0045
40.12
. No.: 169
AS Loc. : 	

BlnkCorr
Signal
0.000
-0.421
-0.235
-0.218
0.211
96.55

Peak
Area
0.097
-0.323
-0.137



AS Loc.: 	

BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
40.12

Peak
Area
0.097
0.097
0.097



AS Loc. : 	
Date: 02/01/2JHH5
/ J
Bkgnd Time /
Area ^^
0.006 15(f30: 12
0.431 15:30-1 15
0.237 15:30:(£7



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:30:44
0.006 15:30:46
0.006 15:30:48



Date: 02/01/2006
Sample ID: sd203-l+3
Repl SampleConc
# mg/L
1 1.336
2 1.350
3 1.342
Mean: 1.343
SD : 0.0072
%RSD: 0.53
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
ft mg/L
1 0.0236
2 0.0146
3 -0.0020
Mean: 0.0121
SD : 0.0130
%RSD: 107.5
StndConc
mg/L
1.336
1.350
1.342
1.343
0.0072
0.53
.No.: 170

StndConc
mg/L
0.0236
0.0146
-0.0020
0.0121
0.0130
107.5
BlnkCorr
Signal
0.050
0.050
0.050
0.050
0.000
0.53
AS

BlnkCorr
Signal
0.001
0.001
0.000
0.000
0.000
107.50
Peak
Area
0.147
0.147
0.147



Loc. : 	

Peak
Area
0.098
0.098
0.097



Bkgnd Time
Area
0.005 15:31:12
0.005 15:31:14
0.005 15:31:16



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:31:42
0.005 15:31:45
0.006 15:31:47



Page 46

-------
Element: Ni    Seq. No.: 171
                                  AS Loc.
                                                 Date: 02/01/2006
DcUllp-LC
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.2894
0.3029
0.3002
0.2975
0.0072
2.40
StndConc
mg/L
0.2894
0.3029
0.3002
0.2975
0.0072
2.40
BlnkCorr
Signal
0.011
0.011
0.011
0.011
0.000
2.40
Peak
Area
0.108
0.108
0.108



Bkgnd
Area
0.005
0.005
0.005



Time
15:32:
15:32:
15:32:






09




                    No.: 172
                                  AS  Loc.
                                                  Date:  02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0117
0.0086
0.0108
0.0104
0.0016
15.15
StndConc
mg/L
0.0117
0.0086
0.0108
0.0104
0.0016
15.15
: 	 ==:=======
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
15.15
Peak
Area
0.098
0.098
0.098



Bkgnd
Area
0.005
0.005
0.005



Time
15:32:58
15:33:00
15:33:02



 Element:  Ni     Seq.  No.:  173
                                   AS Loc.
                                                  Date:  02/01/2006
Repl
#
]_
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.3360
0.
0.
0.
0.

3290
3241
3297
0060
1.81
StndConc
mg/L
0.3360
0
0
0
0

.3290
.3241
.3297
.0060
1.81
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.012 0.110 0.005 15:33:34
0
0
0
0

012 0.109 0.005 15:33:36
.012 0.109 0.005 15:33:38
.012
.000
1.81
 Element: Ni    Seq. No.: 174
                                   AS Loc.
                                                  Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.
0.
-0.
-0.
0.
3804
0018
0148
1311
2160
164.8
StndConc
mg/L
-0.3804
0.0018
-0.0148
-0.1311
0.2160
164.8
BlnkCorr
Signal
-0.014
0.000
-0.001
-0.005
0.008
164.76
Peak
Area
0.083
0.
0.



097
097



Bkgnd
Area
0.018
0.
0.



005
005



Time
15:
15:
15:



34:
34:
34:



01
03
05



                                            Page 47

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0029
2 -0.0150
3 0.0157
Mean: -0.0007
SD : 0.0154
%RSD: 2141
Element: Ni Seq.
Sample ID: 203-7+9
Repl SampleConc
# mg/L
1 0.2816
2 0.2468
3 0.2377
Mean: 0.2554
SD : 0.0232
%RSD: 9.08
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0047
2 0.0085
3 0.0377
Mean: 0.0138
SD : 0.0217
%RSD: 156.9
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0052
2 -0.0330
3 -0.0232
Mean: -0.0205
SD : 0.0141
%RSD: 68.74
No.: 175

StndConc
mg/L
-0.0029
-0.0150
0.0157
-0.0007
0.0154
2141
No.: 176

StndConc
mg/L
0.2816
0.2468
0.2377
0.2554
0.0232
9.08
No.: 177

StndConc
mg/L
-0.0047
0.0085
0.0377
0.0138
0.0217
156.9
No.: 178

StndConc
mg/L
-0.0052
-0.0330
-0.0232
-0.0205
0.0141
68.74
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.097
0.001 0.098
0.000
0.001
2140.82
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.010 0.108
0.009 0.106
0.009 0.106
0.009
0.001
9.08
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.098
0.001 0.099
0.001
0.001
156.88
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.097
-0.001 0.096
-0.001 0.096
-0.001
0.001
68.74
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:34:14
0.005 15:34:16
0.004 15:34:18



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:34:40
0.006 15:34:42
0.006 15:34:44



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:35:02
0.005 15:35:04
0.004 15:35:06



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:35:13
0.007 15:35:15
0.006 15:35:17



Page 48

-------
Element: Ni Seq.
Sample ID: ccv-0.25
Repl SampleConc
# mg/L
1 0.2530
2 0.2688
3 0.2681
Mean: 0.2633
SD : 0.0090
%RSD: 3.40
Element: Ni Seq.
No.: 179

StndConc
mg/L
0.2530
0.2688
0.2681
0.2633
0.0090
3.40
No. : 180
AS

BlnkCorr
Signal
0.009
0.010
0.010
0.010
0.000
3.40
AS
jjoc. : 	

Peak
Area
0.107
0.107
0.107



LOG. : 	
Date: 02/01/2006

Bkgnd Time
Area
0.006 15:35:40
0.005 15:35:42
0.005 15:35:44



Date: 02/01/2006
Sample ID: ccv-0.25
Repl SampleConc
# mg/L
1 0.2733
2 0.2549
3 0.2530
Mean: 0.2604
SD : 0.0112
%RSD: 4.31
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0,0231
2 0.0007
3 -0.0220
Mean: -0.0148
SD : 0.0134
%RSD: 90.90
Element: Ni Seq.
StndConc
mg/L
0.2733
0.2549
0.2530
0.2604
0.0112
4.31
No.: 181

StndConc
mg/L
-0.0231
0.0007
-0.0220
-0.0148
0.0134
90.90
No.: 182
BlnkCorr
Signal
0.010
0.009
0.009
0.010
0.000
4.31
AS

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
90.90
AS
Peak
Area
0.107
0.107
0.107



Loc. : 	

Peak
Area
0.096
0.097
0.096



Loc. : 	
Bkgnd Time
Area
0.005 15:36:14
0.006 15:36:16
0.006 15:36:18



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:36:38
0.005 15:36:40
0.006 15:36:42



Date: 02/01/2006
Sample ID: 203-10+12
Repl SampleConc
# mg/L
1 0.1472
2 0.1243
3 0.1614
Mean: 0.1443
SD : 0.0187
%RSD: 12.97
StndConc
mg/L
0.1472
0.1243
0.1614
0.1443
0.0187
12.97
BlnkCorr
Signal
0.005
0.005
0.006
0.005
0.001
12.97
Peak
Area
0.103
0.102
0.103



Bkgnd Time
Area
0.006 15:37:04
0.007 15:37:06
0.005 15:37:09



Page 49

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0184
2 0.0027
3 0.0268
Mean: 0.0037
SD : 0.0226
%RSD: 607.7
Element: Ni Seq
. No.: 183

StndConc
mg/L
-0.0184
0.0027
0.0268
0.0037
0.0226
607.7
. No.: 184
AS

BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
607.72
AS
LOG. : 	

Peak
Area
0.097
0.097
0.098



Loc. : 	
Date: 02/01/2006

Bkgnd Time
Area
0.006 15:37:22
0.005 15:37:24
0.005 15:37:27



Date-: 02/01/2006
Sample ID: 203-13+15
Repl SampleConc
# mg/L
1 2.428
2 2.459
3 2.428
Mean: 2.438
SD : 0.0177
%RSD: 0.73
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0038
2 -0.0072
3 -0.0121
Mean: -0.0077
SD : 0.0042
%RS-D: 54.18
Element : Ni Seq
StndConc
mg/L
2.428
2.459
2.428
2.438
0.0177
0.73
. No. : 185

StndConc
mg/L
-0.0038
-0.0072
-0.0121
-0.0077
0.0042
54.18
.No.: 186
BlnkCorr
Signal
0.090
0.091
0.090
0.091
0.001
0.73
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
54.18
AS
Peak
Area
0.187
0.189
0.187



Loc. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	
Bkgnd Time
Area
0.006 15:37:50
0.005 15:37:52
0.005 15:37:54



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:38:12
0.005 15:38:14
0.005 15:38:17



Date: 02/01/2006
Sample ID: 203-16+18
Repl SampleConc
# mg/L
1 2.768
2 2.739
3 2.760
Mean: 2.755
SD : 0.0151
%RSD: 0.55
StndConc
mg/L
2.768
2.739
2.760
2.755
0.0151
0.55
BlnkCorr
Signal
0.103
0.102
0.102
0.102
0.001
0.55
Peak
Area
0.200
0.199
0.200



Bkgnd Time
Area
0.005 15:38:40
0.005 15:38:42
0.005 15:38:44



Page 50

-------
Element: Ni    Seq.
Sample ID: ccb
          No. :  187
                                  AS Loc
                                                 Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0074
0.0014
-0.0036
-0.0032
0.0044
139.2
StndConc
mg/L
-0.0074
0.0014
-0.0036
-0.0032
0.0044
139.2
BlnkCorr Peak
Signal Area
0.000 0.097
0.000 0.097
0.000 0.097
0.000
0.000
139.15
Bkgnd Time
Area
0.006 15:39:09
0.005 15:39:11
0.005 15:39:13



Element: Ni    Seq. No.: 188
Sample ID: d203-10+12
                        AS Loc.
                                                 Date: 02/01/2006
Repl £
# n
1
2
3
Mean:
SD :
%RSD:
SampleConc
tig/L
0.1492
0.1512
0.1548
0.1517
0.0028
1.87
StndConc
mg/L
0.1492
0.1512
0.1548
0.1517
0.0028
1.87
BlnkCorr Peak
Signal Area
0.006 0.103
0.006 0.103
0.006 0.103
0.006
0.000
1.87
Bkgnd Time
Area
0.006 15:39:39
0.006 15:39:42
0.006 15:39:44



Element: Ni    Seq. No.: 189
Sample ID: ccb
                        AS Loc.
                            Date: 02/01/2006
Repl
#
1
2
3
Mean:
SD :
SampleConc
mg/L
-0.0112
-0.0153
-0.0225
-0.0163
0.0057
StndConc
mg/L
-0.0112
-0.0153
-0.0225
-0.0163
0.0057
BlnkCorr
Signal
0.000
-0.001
-0.001
-0.001
0.000
Peak
Area
0.097
0.097
0.096


Bkgnd
Area
0.005
0.005
0.005


Time

15:40:
15:40:
15:40:




06
08
10


%RSD:
35.16
35.16
                               35.16
Element: Ni    Seq. No.: 190
Sample ID: 203-19+21
                        AS Loc.
                            Date: 02/01/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.157
absorbance
6.100
absorbance
6.187
absorbance
6.148
0.0443
0.72
absorbance
StndConc
mg/L
6.157
is greater
6.100
is greater
6.187
is greater
6.148
0.0443
0.72
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
229
that
226
that
230
that
228
002
.72
that
Peak
Area
0.
of
0.
of
0.
of



of
326
the
324
the
327
the



the
Bkgnd
Area

0.007
highest
Time

15:40:


31
standard.
0.006
highest
15:40:
33
standard.
0.005
highest



highest
15:40;
35
standard.









standard.
                                           Page  51

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0032
2 0.0027
3 -0.0159
Mean: -0.0055
SD : 0.0095
%RSD: 173.4
Element : Ni Seq
. No. : 191

StndConc
mg/L
-0.0032
0.0027
-0.0159
-0.0055
0.0095
173.4
. No. : 192
AS

BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
173.39
AS
LOG. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:40:55
0.005 15:40:57
0.005 15:41:00



Date: 02/01/2006
Sample ID: 203-22+24
Repl SampleConc
# mg/L
1 2.115
2 2.106
3 2.129
Mean: 2.117
SD : 0.0117
%RSD: 0.55
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0036
2 -0.0056
3 -0.0159
Mean: -0.0059
SD : 0.0097
%RSD: 163.7
Element; Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0126
2 -0.0301
3 -0.0730
Mean: -0.0386
SD : 0.0311
%RSD: 80.55
StndConc
mg/L
2.115
2.106
2.129
2.117
0.0117
0.55
. No. : 193

StndConc
mg/L
0.0036
-0.0056
-0.0159
-0.0059
0.0097
163.7
. No. : 194

StndConc
mg/L
-0.0126
-0.0301
-0.0730
-0.0386
0.0311
80.55
BlnkCorr
Signal
0.079
0.078
0.079
0.079
0.000
0.55
AS

BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
163.72
AS

BlnkCorr
Signal
0.000
-0.001
-0.003
-0.001
0.001
80.55
Peak
Area
0.176
0.175
0.176



Loc. : 	

Peak
Area
0.097
0.097
0.097



Loc. : 	

Peak
Area
0.097
0.096
0.095



Bkgnd Time
Area
0.006 15:41:24
0.006 15:41:27
0.006 15:41:29



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:41:49
0.005 15:41:51
0.005 15:41:53



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:42:24
0.005 15:42:26
0.007 15:42:28



Page 52

-------
Element
Sample
Repl
#
1
2
3
Mean :
SD :
%RSD:
.: Ni Seq
ID: ccv-2
SampleConc
mg/L
1.999
2.017
2.015
2.010
0.0101
0.50
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
If
1
ID: ccb
SampleConc
mg/L
-0.0575
-0.0445
-0.0090
-0.0370
0.0251
67.82
: Ni Seq
ID: Sample
SampleConc
mg/L
-0.0259
. No. : 195

StndConc
mg/L
1.999
2.017
2.015
2.010
0.0101
0.50
. No. : 196

StndConc
mg/L
-0.0575
-0.0445
-0.0090
-0.0370
0.0251
67.82
. No. : 197

StndConc
mg/L
-0.0259
AS

BlnkCorr
Signal
0.074
0.075
0.075
0.075
0.000
0.50
AS

BlnkCorr
Signal
-0.002
-0.002
0.000
-0.001
0.001
67.82
AS

BlnkCorr
Signal
-0.001
LOG. : 	

Peak
Area
0.171
0.172
0.172



Loc. : 	

Peak
Area
0.095
0.096
0.097



Loc. : 	

Peak
Area
0.096
Date;

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.006
0.006
0.005



Date:

Bkgnd
Area
0.005
02/01/2

Time

15:42
15:42
15:42



006



:46
:49
:51



02/01/2006

Time

15:43
15:43
15:43






:09
:11
:13



02/01/2006

Time

15:43



:43
Auto-zero performed.
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0013
0.0000
-0.0126
-0.0046
0.0069
150.2
: Ni Seq
. No.: 198

StndConc
mg/L
-0.0013
0.0000
-0.0126
-0.0046
0.0069
150.2
. No. : 199
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
150.21
AS
Loc. : 	

Peak
Area
0.096
0.096
0.096



Loc. : 	
Date:

Bkgnd
Area
0.005
0.005
0.006



Date:
02/01/2006

Time

15:43
15:43
15:43






:53
:56
:58



02/01/2006
ID: 203-25+27
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
1.486
1.476
1.441
1.467
0.0239
1.63
StndConc
mg/L
1.486
1.476
1.441
1.467
0.0239
1.63
BlnkCorr
Signal
0.055
0.055
0.053
0.054
0.001
1.63
Peak
Area
0.151
0.151
0.150



Bkgnd
Area
0.005
0.005
0.007



Time

15:44
15:44
15:44





:19
:21
:23



Page 53

-------
Clement: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0279
2 -0.0268
3 -0.0243
Mean: -0.0264
SD : 0.0018
%RSD: 7.01
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0218
2 -0.0207
3 -0.0378
Mean: -0.0268
SD : 0.0096
%RSD: 35.79
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 -0.0562
. No. : 200

StndConc
mg/L
-0.0279
-0.0268
-0.0243
-0.0264
0.0018
7.01
. No.: 201

StndConc
mg/L
-0.0218
-0.0207
-0.0378
-0.0268
0.0096
35.79
. No. : 202

StndConc
mg/L
-0.0562
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
7.01
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
35.79
AS

BlnkCorr
Signal
-0.002
Loc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.094
Date:

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.007
02/01/2006

Time

15:45:01
15:45:03
15:45:05



02/01/2006

Time

15:45:20
15:45:22
15:45:24



02/01/2006

Time

15:45:37
Auto-zero performed.
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0279
2 0.0077
3 0.0189
Mean: 0.0182
SD : 0.0101
%RSD: 55.55
Element : Ni Seq
. No.: 203

StndConc
mg/L
0.0279
0.0077
0.0189
0.0182
0.0101
55.55
. No. : 204
AS

BlnkCorr
Signal
0.001
0.000
0.001
0.001
0.000
55.55
AS
Loc. : 	

Peak
Area
0.095
0.094
0.095



Loc. : 	
Date:

Bkgnd
Area
0.006
0.007
0.006



Date:
02/01/2006

Time

15:45:49
15:45:51
15:45:53



02/01/2006
JSample ID: 203-28+30
Repl SampleConc
# mg/L
1 2.298
2 2.303
3 2.285
Mean: 2.295
SD : 0.0091
%RSD: 0.40
StndConc
mg/L
2.29.8
2.303
2.285
2.295
0.0091
0.40
BlnkCorr
Signal
0.085
0.085
0.085
0.085
0.000
0.40
Peak
Area
0.179
0.180
0.179



Bkgnd
Area
0.005
0.006
0.006



Time

15:46:17
15:46:19
15:46:21



Page 54

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0,0596
2 0.0236
3 0.0231
Mean: 0.0354
SD : 0.0210
%RSD: 59.16
Element: Ni Seq
. No.: 205

StndConc
mg/L
0.0596
0.0236
0.0231
0.0354
0.0210
59.16
. No.: 206
AS

BlnkCorr
Signal
0.002
0.001
0.001
0.001
0.001
59.16
AS
LOG.: 	

Peak
Area
0.096
0.095
0.095



Loc. : 	
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:46:47
0.007 15:46:49
0.006 15:46:51



Date: 02/01/2006
Sample ID: 203-31+33
Repl SampleConc
# mg/L
1 0.2052
2 0.2222
3 0.2281
Mean: 0.2185
SD : 0.0119
%RSD: 5.43
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0241
2 0.0497
3 0.0306
Mean: 0.0348
SD : 0.0133
%RSD: 38.18
Element : Ni Seq
StndConc
mg/L
0.2052
0.2222
0.2281
0.2185
0.0119
5.43
. No.: 207

StndConc
mg/L
0.0241
0.0497
0.0306
0.0348
0.0133
38.18
. No.: 208
BlnkCorr
Signal
0.008
0.008
0.008
0.008
0.000
5.43
AS

BlnkCorr
Signal
0.001
0.002
0.001
0.001
0.000
38.18
AS
Peak
Area
0.102
0.102
0.103



Loc. : 	

Peak
Area
0.095
0.096
0.095



Loc. : 	
Bkgnd Time
Area
0.006 15:47:29
0.005 15:47:31
0.006 15:47:34



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:47:59
0.006 15:48:01
0.006 15:48:03



Date: 02/01/2006
Sample ID: 203 i Irb
Repl SampleConc
# mg/L
1 0.1036
2 0.1022
3 0.1308
Mean: 0.1122
SD : 0.0161
%RSD: 14.39
StndConc
mg/L
0.1036
0.1022
0.1308
0.1122
0.0161
14.39
BlnkCorr
Signal
0.004
0.004
0.005
0.004
0.001
14.39
Peak
Area
0.098
0.098
0.099



Bkgnd Time
Area
0.007 15:48:24
0.006 15:48:26
0.006 15:48:28



Page 55

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.3672
2 0.0299
3 0.0431
Mean: -0.0981
SD : 0.2332
%RSD: 237.7
Element: Ni Seq
Sample ID: Sample
Repl SampleConc
# mg/L
1 0.0220
. No. : 209 AS iaoc. : 	

StndConc BlnkCorr Peak
mg/L Signal Area
-0.3672 -0.014 0.081
0.0299 0.001 0.095
0.0431 0.002 0.096
-0.0981 -0.004
0.2332 0.009
237.7 237.73
. No.: 210 AS Loc.: 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.0220 0.001 0.095
Date: 02/01/2006

Bkgnd Time
Area
0.021 15:48:42
0.006 15:48:44
0.005 15:48:46



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:48:52
Auto- zero performed.
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0315
2 -0.3883
3 0.0005
Mean: -0.1187
SD : 0.2339
%RSD: 197.0
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0186
2 -0.0452
3 0.0290
Mean: 0.0008
SD : 0.0402
%RSD: 5147
Element : Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 0.1254
2 0.1479
3 0.1250
Mean: 0.1328
SD : 0.0131
%RSD: 9.87
. No.: 211 AS Loc.: 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.0315 0.001 0.096
-0.3883 -0.014 0.081
0.0005 0.000 0.095
-0.1187 -0.004
0.2339 0.009
197.0 197.03
. No.: 212 AS Loc.: 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.0186 0.001 0.096
-0.0452 -0.002 0.093
0.0290 0.001 0.096
0.0008 0.000
0.0402 0.001
5147 5146.59
. No.: 213 AS Loc.: 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.1254 0.005 0.100
0.1479 0.005 0.100
0.1250 0.005 0.100
0.1328 0.005
0.0131 0.000
9.87 9.87
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:49:01
0.020 15:49:03
0.006 15:49:05



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:49:13
0.008 15:49:15
0.005 15:49:17



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:49:31
0.005 15:49:33
0.005 15:49:35



Page 56

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0177
2 0.0234
3 0.0252
Mean: 0.0221
SD : 0.0040
%RSD: 17.89
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.102
2 1.092
3 1.059
Mean: 1.084
SD : 0.0223
%RSD: 2.05
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.6658
2 -0.8584
3 -1.004
Mean: -0.8428
SD : 0.1698
%RSD: 20.15
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0029
2 0.0034
3 0.0227
Mean: 0.0097
SD : 0.0113
%RSD: 116.8
, No. : 214

StndConc
mg/L
0.0177
0.0234
0.0252
0.0221
0.0040
17.89
. No. : 215

StndConc
mg/L
1.102
1.092
1.059
1.084
0.0223
2.05
. No. : 216

StndConc
mg/L
-0.6658
-0.8584
-1.004
-0.8428
0.1698
20.15
. No. : 217

StndConc
mg/L
0.0029
0.0034
0.0227
0.0097
0.0113
116.8
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
17.89
AS

BlnkCorr
Signal
0.041
0.041
0.039
0.040
0.001
2.05
AS

BlnkCorr
Signal
-0.025
-0.032
-0.037
-0.031
0.006
20.15
AS

BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
116.76
LOG. : 	

Peak
Area
0.096
0.096
0.096



Loc. : 	

Peak
Area
0.136
0.136
0.134



Loc. : 	

Peak
Area
0.070
0.063
0.058



Loc. : 	

Peak
Area
0.095
0.095
0.096



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:49:56
0.005 15:49:59
0.005 15:50:01



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:50:15
0.005 15:50:17
0.007 15:50:19



Date: 02/01/2006

Bkgnd Time
Area
0.031 15:50:35
0.038 15:50:38
0.044 15:50:40



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:50:47
0.006 15:50:49
0.006 15:50:51



Page 57

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0220
2 0.0135
3 0.0360
Mean: 0.0238
SD : 0.0114
%RSD: 47.71
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.5416
2 0.5722
3 -0.3573
Mean: 0.2522
SD : 0.5280
%RSD: 209.4
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0050
2 0.0182
3 0.0317
Mean: 0.0183
SD : 0.0133
%RSD: 72.79
Element: Ni Seq
Sample ID: *203-2
Repl SampleConc
# mg/L
1 0.1458
2 0.1602
3 0.1526
Mean: 0.1528
SD : 0.0072
%RSD: 4.72
. No. : 218

StndConc
mg/L
0.0220
0.0135
0.0360
0.0238
0.0114
47.71
. No. : 219

StndConc
mg/L
0.5416
0.5722*
-0.3573"
0.25-22
0.5280
209.4
. No. : 220

StndConc
mg/L
0.0050
0.0182
0.0317
0.0183
0.0133
72.79
. No. : 221

StndConc
mg/L
0.1458
0.1602
0.1526
0.1528
0.0072
4.72
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.096
0.001 0.095
0.001 0.096
0.001
0.000
47.71
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.020 0.115
0.021 0.116
-0.013-, 0.082
0.009 ^
0.020 	 -~
209.39
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.095
0.001 0.096
0.001 0.096
0.001
0.000
72.79
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.100
0.006 0.101
0.006 0.101
0.006
0.000
4.72
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:50:59
0.006 15:51:01
0.005 15:51:04



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:51:37
0.005 15:51:40
0.039 15:51:42
/I .. >•* a_ f-~ ff AJus—^if
/j-£jJ£ f xj g t-^-f & * -3 *^**-y*"


Date: 02/01/2006

Bkgnd Time
Area
0.005 15:51:57
0.005 15:51:59
0.005 15:52:02



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:52:18
0.005 15:52:20
0.005 15:52:22



Page 58

-------
Element: Mi Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0247
2 0.0568
3 0.0514
Mean: 0.0443
SD : 0.0172
%RSD: 38.79
Element: Ni. Seq.
Sample ID: s203-2
Repl SampleConc
# mg/L
1 1.098
2 1.119
3 1.105
Mean: 1.107
SD : 0.0107
%RSD: 0.97
Element: Mi Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0359
2 0.0420
3 0.0279
Mean: 0.0353
SD : 0.0070
%RSD: 19.99
Element: Mi Seq.
Sample ID: sd.203-2
Repl SampleConc
# mg/L
1 1.115
2 1.102
3 1.065
Mean: 1.094
SD : 0.0258
%RSD: 2.36
No. '. 222

StndConc
mg/L
0.0247
0.0568
0.0514
0.0443
0.0172
38.79
No.: 223

StndConc
mg/L
1.098
1.119
1.105
1.107
0.0107
0.97
No.: 224

StndConc
mg/L
0.0359
0.0420
0.0279
0.0353
0.0070
19.99
No. : 225

StndConc
mg/L
1.115
1.102
1.065
1.094
0.0258
2.36
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.002 0.097
0.002
0.001
38.79
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.136
0.042 0.137
0.041 0.136
0.041
0.000
0.97
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.096
0.002 0.097
0.001 0.096
0.001
0.000
19.99
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.041 0.136
0.041 0.136
0.040 0.135
0.041
0.001
2.36
Date: 02/01/2006

Bkgnd Time
Area
0.005 15:52:38
0.004 15:52:40
0.004 15:52:42



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:53:01
0.005 15:53:04
0.005 15:53:06



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:53:24
0.005 15:53:26
0.005 15:53:28



Date: 02/01/2006

Bkgnd Time
Area
0.006 15:53:55
0.006 15:53:57
0.007 15:53:59



Page 59

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0133
2 0.0043
3 -0.0036
Mean: -0.0042
SD : 0.0088
%RSD: 210.4
Element: Ni ^-SetfJ
No. : 226

StndConc
rng/L
-0.0133
0.0043
-0.0036
-0.0042
0.0088
210.4
AS Lo

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
210.36
c. : 	

Peak
Area
0.095
0.095
0.095



.".--N"O~7~2- - ~22 /"*•-. AS Loc. :
Date: 02/01/2006

Bkgnd Time
Area
0.006 15:54:22
0.006 15:54:24
0.006 15:54:27



Date: 02/01/2006
Sample ID: ,s'er2,03-2 ' -, / ^
Repl S,ampleConc
# pg/L
1 / 0.2895
2 i 0.2758
3 i 0.2780
Mean: \ 0.2811
SD : \ 0. 0074
%RSD: \ 2.62
Element: Ni Se-q-
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0575
2 0.0301
3 0.0094
Mean: 0.0323
SD : 0.0241
%RSD: 74.68
Element : Ni Seq
Sample ID: 203-5
Repl SampleConc
# mg/L
1 0.1223
2 0.1510
3 0.1268
Mean: 0.1334
SD : 0.0154
StndConc
mg/L
0.2895
0.2758
0.2780
0.2811
0.0074
2.62
--*fo-rr"228

StndConc
mg/L
0.0575
0.0301
0.0094
0.0323
0.0241
74.68
.No.: 229

StndConc
mg/L
0.1223
0.1510
0.1268
0.1334
0.0154
BlnkCoxr
Signal,
0.011\
O.OlOj
0.010/
0.01)3
0 . Q-ti 0
2". 62
Pea*
Area
0.106 
-------
Elements Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0382
2 0.0022
3 0.0115
Mean: 0.0173
SD : 0.0187
%RSD: 108.1
Element: Ni Seq.
Sample ID: 203-8
Repl SampleConc
# mg/L
1 0.1243
2 0.1459
3 0.1148
Mean: 0.1283
SD : 0.0160
%RSD: 12.44
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0346
2 0.0227
3 0.0470
Mean: 0.0348
SD : 0.0122
%RSD: 34.98
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0202
2 0.0180
3 0.0193
Mean: 0.0192
SD : 0.0011
%RSD: 5.67
No. : 230

StndConc
mg/L
0.0382
0.0022
0.0115
0.0173
0.0187
108.1
No.: 231

StndConc
mg/L
0.1243
0.1459
0.1148
0.1283
0.0160
12.44
No.: 232

StndConc
mg/L
0.0346
0.0227
0.0470
0.0348
0.0122
34.98
No.: 233

StndConc
mg/L
0.0202
0.0180
0.0193
0.0192
0.0011
. 5.67
AS :

BlnkCorr
Signal
0.001
0.000
0.000
0.001
0.001
108.09
AS

BlnkCorr
Signal
0.005
0.005
0.004
0.005
0.001
12.44
AS

BlnkCorr
Signal
0.001
0.001
0.002
0.001
0.000
34.98
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
5.67
Loc. : 	

Peak
Area
0.096
0.095
0.095



Loc. : 	

Peak
Area
0.100
0.100
0.099



Loc. : 	

Peak
Area
0.096
0.096
0.097



Loc. : 	

Peak
Area
0.096
0.096
0.096



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:56:24
0.006 15:56:26
0.006 15:56:28



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:56:49
0.005 15:56:51
0.006 15:56:53



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:57:07
0.006 15:57:10
0.005 15:57:12



Date: 02/01/2006

Bkgnd Time
Area
0.005 15:57:51
0.005 15:57:53
0.005 15:57:56



Page 61

-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
. No. : 234
AS Loc. : 	
Date: 02/01/2006
ID: ccv-0.25
SampleConc
mg/L
0.2703
0.2840
0.2892
0.2811
0.0098
3.48
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0416
0.0479
0.0267
0.0387
0.0109
28.19
Element : Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: 203-11
SampleConc
mg/L
0.1218
0.1103
0.1227
0.1183
0.0069
5.86
Element : Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0076
0.0268
0.0295
0.0213
0.0120
56.22
StndConc
mg/L
0.2703
0.2840
0.2892
0.2811
0.0098
3.48
. No. : 235

StndConc
mg/L
0.0416
0.0479
0.0267
0.0387
0.0109
28.19
. No.: 236

StndConc
mg/L
0.1218
0.1103
0.1227
0.1183
0.0069
5.86
. No. : 237

StndConc
mg/L
0.0076
0.0268
0.0295
0.0213
0.0120
56.22
BlnkCorr
Signal
0.010
0.011
0.011
0.010
0.000
3.48
Peak
Area
0.105
0.106
0.106



AS Loc. : 	

BlnkCorr
Signal
0.002
0.002
0.001
0.001
0.000
28.19
AS

BlnkCorr
Signal
0.005
0.004
0.005
0.004
0.000
5.86
AS

BlnkCorr
Signal
0.000
0.001
0.001
0.001
0.000
56.22

Peak
Area
0.097
0.097
0.096



Loc. : 	

Peak
Area
0.100
0.099
0.100



Loc. : 	

Peak
Area
0.095
0.096
0.096



Bkgnd
Area
0.005
0.004
0.004



Date:

Bkgnd
Area
0.005
0.004
0.005



Date:

Bkgnd
Area
0.004
0.005
0.004



Date:

Bkgnd
Area
Time
15:59:
15:59:
15:59:




07
10
12



02/01/2006

Time

15:59:
15:59:
15:59:






28
30
32



02/01/2006

Time

15:59:
15:59:
15:59:






52
54
57



02/01/2006

Time

0.006 16:00:
0.005
0.005



16:00:
16:00:






10
12
14



Page 62

-------
Clement
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: 203-14
SampleConc
mg/L
0.1391
0.1090
0.1175
0.1219
0.0155
12.73
Element: Hi Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0159
0.0099
-0.0054
0.0068
0.0110
161.6
Element : Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: 203-17
SampleConc
mg/L
0.0939
0.0755
0.0508
0.0734
0.0216
29.44
Element: Ni Seq
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
-0.0175
-0.0079
0.0247
-0.0002
0.0221
9202
. No. : 238

StndConc
mg/L
0.1391
0.1090
0.1175
0.1219
0.0155
12.73
. No. : 239

StndConc
mg/L
0.0159
0.0099
-0.0054
0.0068
0.0110
161.6
. No.: 240

StndConc
mg/L
0.0939
0.0755
0.0508
0.0734
0.0216
29.44
. No. : 241

StndConc
mg/L
-0.0175
-0.0079
0.0247
-0.0002
0.0221
9202
AS

BlnkCorr
Signal
0.005
0.004
0.004
0.005
0.001
12.73
AS

BlnkCorr
Signal
0.001
0.000
0.000
0.000
0.000
161.63
AS

BlnkCorr
Signal
0.003
0.003
0.002
0.003
0.001
29.44
AS

BlnkCorr
Signal
-0.001
0.000
0.001
0.000
0.001
9202.21
LOG. : 	

Peak
Area
0.100
0.099
0.099



Loc. : 	

Peak
Area
0.096
0.095
0.095



Loc. : 	

Peak
Area
0.098
0.098
0.097



Loc. : 	

Peak
Area
0.094
0.095
0.096



Bate:

Bkgnd
Area
0.004
0.005
0.005



Date:

Bkgnd
Area
0.006
0.006
0.006



Date:

Bkgnd
Area
0.005
0.006
0.007



Date:

Bkgnd
Area
0.007
0.006
0.005



02/01/20

Time

16:00:
16:00:
16:00:



06



27
29
31



02/01/2006

Time

16:00:
16:00:
16:00:






53
55
57



02/01/2006

Time

16:01:
16:01:
16:01:






19
21
23



02/01/2006

Time

16:01:
16:01:
16:01:






40
42
44



Page 63

-------
Element: Ni Seq
Sample ID: 203-20
Repl SampleConc
# mg/L
1 0.0850
2 0.0746
3 0.0477
Mean: 0.0691
SD : 0.0192
%RSD: 27.83
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0121
2 -0.0232
3 0.0225
Mean: -0.0043
SD : 0.0239
%RSD: 559.6
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0092
2 0.0077
3 0.0142
Mean: 0.0043
SD : 0.0121
%RSD: 283.6
Element: Ni Seq
Sample ID: ccv-0.5
Repl SampleConc
# mg/L
1 0.4584
2 0.5065
3 0.5040
Mean: 0.4896
SD : 0.0271
%RSD: 5.53
. No.: 242

StndConc
mg/L
0.0850
0.0746
0.0477
0.0691
0.0192
27.83
. No.: 243

StndConc
mg/L
-0.0121
-0.0232
0.0225
-0.0043
0.0239
559.6
. No. : 244

StndConc
mg/L
-0.0092
0.0077
0.0142
0.0043
0.0121
283.6
. No. : 245

StndConc
mg/L
0.4584
0.5065
0.5040
0.4896
0.0271
5.53
AS

BlnkCorr
Signal
0.003
0.003
0.002
0.003
0.001
27.83
AS

BlnkCorr
Signal
0.000
-0.001
0.001
0.000
0.001
559.56
AS

BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
283.61
AS

BlnkCon
Signal
0.017
0.019
0.019
0.018
0.001
5.53
j_iOC « I

Peak
Area
0.098
0.098
0.097



Loc. : 	

Peak
Area
0.095
0.094
0.096



Loc. : 	

: Peak
Area
0.095
0.095
0.096



Loc. : 	

: Peak
Area
0.112
0.114
0.114



Date: 02/01/2006

Bkgnd Time
Area
0.006 16:01:59
0.006 16:02:01
0.007 16:02:03



Date: 02/01/2006

Bkgnd Time
Area
0.006 16:02:31
0.007 16:02:33
0.005 16:02:35



Date: 02/01/2006

Bkgnd Time
Area
0.006 16:02:45
0.005 16:02:47
0.005 16:02:49



Date: 02/01/2006

Bkgnd Time
Area
0.007 16:03:21
0.006 16:03:23
0.006 16:03:26



Page 64

-------
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0166
-0.0092
-0.0191
-0.0150
0.0052
34.44
:: Ni Seq
ID: 203-23
SampleConc
mg/L
0.0658
0.0690
0.0717
0.0688
0.0030
4.33
:: Ni Seq
ID: ccb
SampleConc
mg/L
-0.0014
-0.0079
0.0049
-0.0015
0.0064
426.0
;: Ni Seq
ID: 203-26
SampleConc
mg/L
0.1004
0.0901
0.0894
0.0933
0.0061
6.59
. No . : 246

StndConc
mg/L
-0.0166
-0.0092
-0.0191
-0.0150
0.0052
34.44
. No.: 247

StndConc
mg/L
0.0658
0.0690
0.0717
0.0688
0.0030
4.33
. No.: 248

StndConc
mg/L
-0.0014
-0.0079
0.0049
-0.0015
0.0064
426.0
. No.: 249

StndConc
mg/L
0.1004
0.0901
0.0894
0.0933
0.0061
6.59
AS

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
34.44
AS

BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
4.33
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
426.01
AS

BlnkCorr
Signal
0.004
0.003
0.003
0.003
0.000
6.59
LOG. : 	

Peak
Area
0.094
0.095
0.094



Loc. : 	

Peak
Area
0.097
0.098
0.098



Loc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.099
0.098
0.098



Dste i !

Bkgnd
Area
0.006
0.005
0.006



Date:

Bkgnd
Area
0.006
0.005
0.005



Date:

Bkgnd
Area
0.005
0.005
0.005



Date:

Bkgnd
Area
0.005
0.006
0.005



32/01/2006

Time
16:03:44
16:03:47
16:03:49



02/01/2006

Time
16:04:06
16:04:08
16:04:10



02/01/2006

Time

16:04:23
16:04:25
16:04:27



02/01/2006

Time

16:04:46
16:04:48
16:04:50



Page 65

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0043
2 0.0002
3 0.0014
Mean: -0.0009
SD : 0.0030
%RSD: 336.5
Element : Ni Seq
Sample ID: 203-29
Repl SampleConc
# mg/L
1 0.0755
2 0.0899
3 0.0829
Mean: 0.0828
SD : 0.0072
%RSD: 8.71
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0023
2 0.0090
3 0.0065
Mean: 0.0044
SD : 0.0060
%RSD: 135.9
Element: Ni Seq
Sample ID: 203-32
Repl SampleConc
# mg/L
1 0.0598
2 0.0787
3 0.0735
Mean: 0.0707
SD : 0.0098
%RSD: 13.82
. No. : 250

StndConc
mg/L
-0.0043
0.0002
0.0014
-0.0009
0.0030
336.5
. No. : 251

StndConc
mg/L
0.0755
0.0899
0.0829
0.0828
0.0072
8.71
. No. : 252

StndConc
mg/L
-0.0023
0.0090
0.0065
0.0044
0.0060
135.9
. No. : 253

StndConc
mg/L
0.0598
0.0787
0.0735
0.0707
0.0098
13.82
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
336.45
AS

BlnkCorr
Signal
0.003
0.003
0.003
0.003
0.000
8.71
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
135.95
AS

BlnkCorr
Signal
0.002
0.003
0.003
0.003
0.000
13.82
LOG. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.098
0.098
0.098



Loc. : 	

Peak
Area
0.095
0.095
0.095



Loc. : 	

Peak
Area
0.097
0.098
0.098



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:05:06
0.005 16:05:08
0.005 16:05:10



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:05:26
0.005 16:05:28
0.005 16:05:30



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:05:45
0.005 16:05:47
0.005 16:05:49



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:06:03
0.005 16:06:05
0.005 16:06:07



Page 66

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0124
2 -0.0007
3 -0.0204
Mean: -0.0112
SD : 0.0099
%RSD: 88.45
Element: Ni Seq
Sample ID: 203-26
Repl SampleConc
# mg/L
1 0.1023
2 0.1104
3 0.0885
Mean: 0.1004
SD : 0.0111
%RSD: 11.07
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0050
2 0.0166
3 0.0182
Mean: 0.0099
SD : 0.0130
%RSD: 130.9
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0061
.2 0.0117
3 0.0038
Mean: 0.0031
SD : 0.0089
%RSD: 286.2
. No. : 254

StndConc
mg/L
-0.0124
-0.0007
-0.0204
-0.0112
0.0099
88.45
. No. : 255
dup
StndConc
mg/L
0.1023
0.1104
0.0885
0.1004
0.0111
11.07
. No.: 256

StndConc
mg/L
-0.0050
0.0166
0.0182
0.0099
0.0130
130.9
. No.: 257

StndConc
mg/L
-0.0061
0.0117
0.0038
0.0031
0.0089
286.2
AS

BlnkCorr
Signal
0.000
0.000
-0.001
0.000
0.000
88.45
AS

BlnkCorr
Signal
0.004
0.004
0.003
0.004
0.000
11.07
AS

BlnkCorr
Signal
0.000
0.001
0.001
0.000
0.000
130.95
AS

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
286.16
.hoc. : 	

Peak
Area
0.095
0.095
0.094



Loc. : 	

Peak
Area
0.099
0.099
0.098



Loc. : 	

Peak
Area
0.095
0.096
0.096



Loc. : 	

Peak
Area
0.095
0.095
0.095



Date; 02/01/2006

Bfcgnd Time
Area
0.005 16:06:40
0.005 16:06:42
0,006 16:06:44



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:07:02
0.005 16:07:04
0.005 16:07:07



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:07:21
0.005 16:07:23
0.005 16:07:25



Date: 02/01/2006

Bkgnd Time
Area
0.005 16:07:53
0.005 16:07:55
0.005 16:07:57



Page 67

-------
Prep  M©thod',      (check only one per page)
     ICP/FLAA: SM 3030 F, EPA 200.7 '82
     ICP/FLAA: EPA 200's, SW-848 3010A
     ICP/FLAA: EPA 200.7 r4.4
     ICP/FLAA: SW-8463005A
     ICP/FLAA: SW-846 3015A MICROWAVE
     OTHER:	
GFAA:  SM3030E
GFAA:  EPA 200's, SW-846 3020A
GFAA:  EPA 200.9
GFAA:  SW-846 3015A (NoHCL) MICROWAVE
OTHER:	
MATRIX:             (check only one per page)

DRINKING WATER




1


2
3
4
5
6
7
8
9
10
11
12

Set
Init'I
I y
















Set
date
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time
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QC-21
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                                                                                  Analyst:

                                                                                Start Date:
                                                                                                   S\QA FORMS \FM-041 \R02 \LK
                                                                                                              Page 1 of 1

-------
                                                        CT,
Method:
                        (check only one per page) -
      ICP/FLM:  SM 3030 F, EPA 200.7 '82
      ICP/FLAA:  EPA20Q's, SW-846 3010A
      ICP/FLAA:  EPA 200.7 r4.4
      iCP/FLAA:  SW-8463005A
      ICP/FLAA:  SW-846 3015A MICROWAVE
      OTHER:        	.
                                       GFAA: SM3030E
                                       GFAA: EPA 200's, SW-846 3020A
                                       GFAA: -EPA 200.9
                                        iFAA: SW-846 3015A (NoHCL) MICROWAVE
                                       OTHER:	:	
 MATRIX:            {check only one per page)
      DRINKING WATER
                                       AQUEOUS
                                               OTHER:
       Set
       Inifl
    Set
    date-
.Lab #
Smp
Company
Aliquot
 (mis)
Final
(mis)
                                                                             Mcr
                                                LFB
                                                                   100
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10
11
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QC-21
QC-7
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Sn
OTHER
PROVIDER
CVM




LOT*
& 5VtoL>a.




                                                                           Analyst:

                                                                         Start Date:
                                                                                          S\QA FORMS \FM-041 \R02 \LK
                                                                                                     Page 1 of 1

-------
                                                                                         Set*
ethod:
                         (check oniy one per page) -
      ICP/FLAA:  SM 3030 F, EPA 200.7 '82
      ICP/FLAA:  EPA 200's, SW-846 301OA
      ICP/FLAA:  EPA 200.7 r4.4
      iCP/FLAA:  SW-846 3005A
      ICP/FLAA:  SW-846 3015A MICROWAVE
      OTHER:	
                                     GFAA: SM 3030 E
                                     GFAA: EPA 200's, SW-846 3020A
                                     GFAA: 'EPA 200.9
                                     GFAA: SW-846 3015A (NoHCL) MICROWAVE
                                     OTHER:		
  MATRIX:           (check only one per page)
      DRINKING WATER
                                     AQUEOUS
        OTHER:
       Set
       Inifl
                                       Company
Aiiquot
 (mis)
Final
ftnb)
 Mcr
Vsl#
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QC-21
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PROVIDER
£j£>\
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-------
 Prep MetflOCS:      (check oniy one per page)  -
     ICP/FLAA:  SM 3030 F, EPA 200.7 '82
     ICP/FLAA:  EPA 200's, SW-846 301OA
     ICP/FLAA:  EPA 200.7 r4.4
     SCP/FLAA:  SW-846 3005A
     ICP/FLAA:  SW-846 3015A MICROWAVE
     OTHER:	
GFAA:  SM 3030 E
GFAA:  EPA 200's, SW-846 3020A
GFAA: -EPA 200.9
GFAA:  SW-846 3015A (NoHCL) MICROWAVE
OTH ER:	:	
MATRIX:            (check only one per page)

DRINKING WATER




1


2
B
4
5
6
7
8
9
10
11
12

Set
Inrt'I
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date
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Set
time
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Final
(mis)

-------
PROJECT #  2005100307:
  1         2           345
                                            METHOD 29  FOR  NICKEL
                                               6789         10
11
12
SA#
3
2
1
6
5
4
9
8
7
12
11
10
15
14
13
18
17
16
21
20
19
24
23
22
27
26
25
30
29
28
33
32
31



SAMPLE
DESCRPTION
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger
filter
probe rinse
impinger ,^
filter - -
probe rinse
RUN ID
Cond. 27:
BLANK

Cond. 27: Test
#1

Cond. 27: Test
#2
Cond. 27: Test
#3
Cond. 22:
BLANK
Cond. 22: Test
#1

Cond. 22: Test
#2

Cond. 22: Test
#3

Cond. 28: Test
#1
Cond. 28: Test
#2

Cond. 28: Test
#3
MDL
PH
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0
<2.0

<2.0



Sample
Fraction
(SF = SFA)
302
1 filter
99.0
305
1 filter
99.5
312
1 filter
95.0
319
1 filter
97.5
302
1 filter
99.5
300
1 filter
96.5
303
1 filter
97.0
306
1 filter
99.0
309
1 filter
96.5
302
1 filter
98.5
307
1 filter
97.0
300 y-
1 "filter
100,0
EVAP.
TO
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
20
NA
20
- ';ty
NA
20'
REAGENTS
FOR DIG.
HNO3 + H202
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HNO3 + H2O2
HF + HNO3
HF + HNO3
HN03 + H202
HF + HNO3
HF+HNO3
HNO3 + H202
HF + HNO3
HF + HNO3
HNQ3fB2£>2
•HF + Mto3>;
,^^NO3
MICRO-
Dig. BY
8.3.4.2
8-3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1 .2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1.2
8.3.4.2
8.3.1.2
8.3.1 .2
*s3C43'li
8.3,12,',
'8'J3&2 ''
Analytical
Fraction
(AF = AFA)
50
100
50
100
50
100
50
100
50
100
•50
100
50
100
50
100
50
100
50
100
50
100
, 50 ^.
''< 100 ?
Nl mg/L
( Ca1 or Ca2 )
< 0.074
0.100
0.192
16.772
0.123
7.629
0.084
14.025
< 0.074
0.100
0.149
0.717
0.120
0.418
0.098
0.375
0.157
3.529
0.111
4.538
< 0.074
7.053
0.0-75^ "x
x 0.07SP*
?/^
MG Nl
IN INITIAL
SAMPLE
0.004
0.010
0.010
1.677
0.006
0.763
0.004
1.403
0.004
0.010
0.007
0.072
0.006
0.042
0.005
0.038
0.008
0.353
0.006
0.454
0.004
0.705
sx 0,004 '
,; 0.008,^
TOTAL MG
PER RUN
0.014
1.687
0.769
1.407
0.014
0.079
0.048
0.042
0.361
0.459
0.709
' X \ \V
> 0,011
10   Samples that read 
-------
QA/QC WORK SHEET for NICKEL
FLAA METHOD SOP MET-040
  '5100AA
 1 CURRENT COPY OF METHOD AVAILABLE IN WINLAB.
 2 INSTRUMENT SET-UP:
                                                                Date:
                              1/6/2006
                                                              Analyst:   LK
  (For Specific instrument settings, see current copy of method.)
3 CALIBRATION:
                           (Mg/L)
                      IDL= 0.027
                      MDL= 0.075
                      RL = 0.10
                     LDR ~ 0.10 to 8.0
4 STANDARD TRACEABILITY
Cal Curve:





Corr. Coef:
Cone
0.25
0.50
1.00
2.00
5.00
xxxxxxxxx
Result
0.275
0.543
1.066
2.096
4.939
0.9993
% Rec.
110.0
108.6
106.6
104.8
98.8

QC STANDARD
Calibration
CCV, CRA, AAT
QCS, LFM

Standard Name, Company, & Lot #
CPI QC-21 41M044
CPI QC-21 41M044
CPI05F011

5 SAMPLE ANALYTICAL RUN
MAT-
RIX








M29
M29
M29
M29

M29
M29
M29
M29



M29
M29
M29
M29
M29
M29
M29
M29




M29
M29
M29
M29
M29
M29
M29
M29


M29

M29
M29
M29


SAMPLE
CCV
QCS
CCB
CRA
CRA
CRA
LRB
LFB
307-1+2
DUP
SPK
SERDIL
307-4+5
307-4+5
307-7+8
307-7+8
307-10+11
307-10+11
CCB
CCV
CCV
307-13+14
307-16+17
307-19+20
307-22+23
307-25+26
307-28+29
307-31+32
307-31+32
CCB
CCV
LRB
LFB
307-3
DUP
SPK
SERDIL
307-6
307-9
307-12
307-15
CCB
CCV
307-18
307-21
307-24
307-27
307-30
307-33
CCV
CCB
STD CONC
5.00
2.00

0.05
0.10
0.25

1.00


1.00
2/10







10.00
1 00









0.50

1.00


1 00
2/10





0 25






0 50

READING
Mg/L
4.943
2.043
-0.023
0068
0105
0.284
0052
0906
0059
0092
1.155
0262
12290
1.721
6.627
0803
10.710
1.409
-0.026
8.779
1.034
0070
0.682
0386
0.340
3.514
4.572
5.990
0.705
0.005
0.537
-0.003
1.023
0.055
0.065
1.020
0.225
0.224
0.182
0.117
0.091
0.026
0286
0.171
0.134
0.128
0.206
0.164
0.121
0.572
0061
BLK



0.016
-0.003
0.018
0028
-0.011
-0.042
-0.016
0.010
0.026
0.036
0.044
0.036
0.040
-0.027
0.007
-0.018
-0.018
-0.024
-0.030
-0.034
-0.032
-0.034
-0.015
0.034
0.021
-0001
0004
0.005
-0.002
-0.010
-0.009
0.002
0031
0.020
0.032
0.059
0.033
0027
0.028
0.026
0.022
0.014
0030
0050
0.053
0053
0.053
0.056
RESULT
4.943
2.043
-0.023
0.051
0.107
0.266
0.024
0.917
0.100
0.108
1.145
0.236
12.254
1.677
6.591
0.763
10.737
1.403
-0 008
8.797
1.058
0 100
0.717
0.418
0.375
3.529
4.538
5.969
0.705
0.001
0.533
-0.001
1.033
0.064
0.063
0.989
0.206
0.192
0.123
0084
0.065
-0.002
0260
0.149
0.120
0.098
0.157
0.111
0068
0519
0.005
DILI








1.0
1.0
1.0
1.0
1.0
10.0
1.0
10.0
1.0
10.0



1.0
1.0
1.0
1.0
1.0
1.0
1.0
10.0




1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0


OIL 2








1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0



1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0




1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0


1.0
1.0
1.0
1.0
1.0
1.0



QC
RESULTS
99
102
-0.023
103
107
106
0.024
92

7.1
105
3.1






-0.028
88
106








G.QQS
107
-0,001
103

1.9
93
3.9




0.026
104






104
0.081

Mg/L








0.100



12.254
16.772
6.591
7.629
10.737
14.025

(OVER LDR)

0.100
0.717
0.418
0.375
3.529
4.538
5.969
7.053




0.064



0.192
0.123
0.084
0.065


0.149
0.120
0.098
0.157
0.111
0.068



REP'T
mg/L








0.100




16.772

7.629

14.025



0.100
0.717
0.418
0.375
3.529
4.538

7.053




0.074



0.192
0.123
0.084
0.074


0.149
0.120
0.098
0.157
0.111
0.074



ICP



















































                                                                           95-105%R)
                                                                           95-105%R)
                                                                           < MDL}
                                                                           70-130%R)
                                                                           70-130%R)
                                                                           70-130%R)
                                                                           < MDL)
                                                                           80-120%R)

                                                                           -10RPD, IFSA>20XMDL)
                                                                           80-120%R)
                                                                           <10%DIFF)
                                                                           < MDL }
                                                                           90-110%R 5
                                                                           < MDL}
                                                                           80-120%R)

                                                                           <10 RPD, IF SA > 20X MDL)
                                                                           80-120%R)
                                                                           <1Q%DIFF)
                                                                           ;< MDL}
                                                                           ; 90-1 WAR)
                                                                           90-110%R)
                                                                           < MDL )

-------
Element: Ni Seq. No.: 77
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 78
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 79
Sample ID: Calib Blank
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Auto-zero performed.
Element: Ni Seq. No.: 80
Sample ID: CAL STD
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 1 applied.
Correlation Coefficient: 0
AS

BlnkCorr
Signal
0.169
0.170
0.170
0.170
o.o.oo
0.03

AS

BlnkCorr
Signal
-0.004
-0.004
-0.004
-0.004
0.000
9.68

AS

BlnkCorr
Signal
-0.001
0.000
-0.001
-0.001
0.000
49.09

AS

BlnkCorr
Signal
0.011
0.012
0.011
0.011
0.001
5.05
[0.25]
.9997
Loc. : 	

Peak
Area
0.072
0.072
0.072




Loc. : 	

Peak
Area
0.069
0.069
0.068




Loc. : 	

Peak
Area
0.067
0.068
0.067




Loc, : - —

Peak
Area
0.078
0.079
0.079





Date: 01/06/2006

Bkgnd Time
Area
0.003 12:20:17
0.003 12:20:19
0.002 12:20:21




Date: 01/06/2006

Bkgnd Time
Area
0.002 12:24:55
0.002 12:24:57
0.003 12:24:59




Date: 01/06/2006

Bkgnd Time
Area
0.003 12:26:19
0.003 12:26:22
0.004 12:26:24




Date: 01/06/2006

Bkgnd Time
Area
0.003 12:27:25
0.002 12:27:27
0.002 12:27:29




Slope: 0.0385
Page 21

-------
Element: Ni Seq. No . : 81
Sample ID: cal std 2
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 2 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 82
Sample ID: cal std 3
Repl SampleConc StndConc
# mg/L mg/L
I
2
3
Mean:
SD :
%RSD:
Standard number 3 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 83
Sample ID: cal std 4
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
Standard number 4 applied.
Correlation Coefficient: 0
Element: Ni Seq. No.: 84
Sample ID: cal std 5
Repl SampleConc StndConc
# mg/L mg/L
1
2
3
Mean:
SD :
%RSD:
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.022 0.090
0.023 0.091
0.021 0.089
0.022
0.001
3.88
[0.50]
.9995
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.043 0.111
0.043 0.111
0.044 0.111
0.043
0.000
1.05
[1.00]
.9990
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.085 0.153
0.086 0.153
0.085 0.153
0.085
0.000
0.54
[2.00]
.9979
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.200 0.267
0.203 0.270
0.201 0.269
0.201
0.002
0.77
Date: 01/06/2006

Bkgnd Time
Area
0.002 12:27:50
0.001 12:27:52
0.003 12:27:54




Slope: 0.0386
Date: 01/06/2006

Bkgnd Time
Area
0.002 12:28:20
0.002 12:28:22
0.002 12:28:24




Slope: 0.0387
Date: 01/06/2006

Bkgnd Time
Area
0.002 12:28:45
0.001 12:28:47
0.002 12:28:49




Slope: 0.0392
Date: 01/06/2006

Bkgnd Time
Area
0.002 12:29:07
0.001 12:29:09
0.001 12:29:11



The calibration curve may not be linear.
Standard number 5 applied.  [5.00]
Correlation Coefficient:  0.9993
Slope:  0.0408
                                           Page 22

-------
                                               Ni
                    0.3
                    0.2
             0)
             u



            I
             o
             w
            .0
                    0.1
                                              Concentration
Calibration  data for Ni


Standard ID
Calib Blank
CAL STD
cal std 2
cal std 3
cal std 4
cal std 5

Mean Signal
(Absorbance)
0.000
0.011
0.022
0.043
0.085
0.201
Correlation Coefficient: 0.99934
Entered
Calculated


Concentration Concentration Standard
fmg/L)
	
0.25
0.50
1.00
2.00
5.00
Slope:
(mg/L)
0.000
0.2750
0.5432
1.066
2.096
4.939
0.04075
Deviation
0.0005
0.0006
0.0009
0.0005
0.0005
0.0016

%RSD
49.0898
5.0484
3.8830
1.0492
0.5382
0.7728

Element: Ni     Seq.

Sample ID: ccv
No.: 85
AS LOG,
                                                   Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4.958
4.943
4.929
4.943
0.0143
0.29
StndConc
mg/L
4.958
4.943
4.929
4.943
0.0143
0.29
BlnkCorr
Signal
0
0
0
0
0

.202
.201
.201
.201
.001
0.29
Peak
Area
0
0
0



.270
.269
.268



Bkgnd
Time
Area
0.
0.
0.



002
002
001



12:
12:
12:



29
29
29



:22
:25
:27



                                            Page  23

-------
Element: Ni    Seq. No,: 86
Sample ID: qcs
                                  AS LOG.
                                                 Date: 01/06/2006
Repl
#
I
2
3
Mean:
SD :
%RSD:
TTT fMrtr^i.fc
SampleConc
mg/L
2.075
2.063
1.990
2.043
0.0458
2.24
.* — HT 	 ftp*
StndConc
mg/L
2.075
2.063
1.990
2.043
0.0458
2.24
•Kfrr— - 6^~
BlnkCorr Peak
Signal Area
0.085 0.152
0.084 0.152
0.081 0.149
0.083
0.002
2.24
— . AS Loc. : 	
Bkgnd
Area
0.003
0.003
0.005



Date:
Time

12:29:49
12:29:51
12:29:54



01/06/2006
Sample \CD: ccb
                   StndConc
                   mg/L
                   -0.1128
                   -0.123
                   -0.1301
                   -0.1222
                             BlnkCorr
                              Signal
                              -0.005
                              -0.005
                              -0.005
                              -0.005
                               0.000
                                7.20
Peak
Area
0.063
0.062
0.062
Bkgnd
Area
 0.005
 0.005
 0.006
 Time

12:30:22
12:30:24
12:30:26
Element: Ni    S^q./No.: 88
Sample ID: ccb   \  -
                                  AS Loc.: 	
                                                  Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc/'
mg/L
-0.
-0.
-0.
-0.
0.
2
f~
\ StndConc
/ W/L
04 97 /
0711
078/4
06£4
0/49
2f.46
\o

-0
-0
0

.0497
.0711
\0784
.0664
.Ck49
22.^6
BlnkCorr
Signal
-0.002
-0.003
-0.003
-0.003
0.001
22.46
Peak
Area
0.
0.
0.



066
065
064



Bkgnd
Time

Area
0.
0.
0.



002
003
004



12:31:
12:31:
12:31:



11
13
16



Element: 1/i    Seq. No.: 89\      AS Loc.:
Sample ID/: Sample
                                                  Date:  01/06/2006
Repl   SampleConc  StndConc  BJmkCorr   Peak
 #    ^g/L        mg/L       Signal    Area
                            ---^.0X003    0.065
                                                  Bkgnd    Time
                                                  Area
                                                   0.003   12:31:42
Auto-zero performed.
Element: Ni    Seq. No.:  90
Sample ID: ccb
                                  AS Loc.
                                                  Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0
-0
-0
-0
0

.0258
.0318
.0102
.0226
.0112
49.46
StndConc
mg/L
-0
-0
-0
-0
0

.0258
.0318
.0102
.0226
.0112
49.46
BlnkCorr
Signal
-0.001
-0.001
0.000
-0.001
0.000
49.46
Peak
Area
0.
0.
0.



064
064
064



Bkgnd
Time
Area
0.
0.
0.



003
004
003



12
12
12



:31:51
:31:53
:31:55



                                           Page 24

-------
Element: Ni    Seq. No.: 91
Sample ID: Sample
                                  AS Loc.
                                                 Date: 01/06/2006
Repl   SampleConc  StndConc  BlnkCorr   Peak
 #     mg/L        mg/L       Signal    Area
 1       0.0084     0.0084     0.000    0.065
Auto-zero performed.
               Bkgnd    Time
               Area
                0.002  12:31:58
Element: Ni    Seq
Sample ID: ccb
                    No.: 92
                                  AS Loc.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0204
-0.0235
-0.0095
-0.0178
0.0073
41.18
StndConc
mg/L
-0.0204
-0.0235
-0.0095
-0.0178
0.0073
41.18
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.001 0.064 0.003 12:32:07
-0.001 0.064 0.003 12:32:09
0.000 0.065 0.003 12:32:12
-0.001
0.000
41.18
Element: Ni    Seq. No.: 93
Sample ID: Sample
AS Loc.:  	
                                                 Date:  01/06/2006
Repl   SampleConc  StndConc  BlnkCorr   Peak
 #     mg/L        mg/L        Signal    Area
 1      -0.0338    -0.0338     -0.001    0.064
Auto-zero performed.
               Bkgnd    Time
               Area
                0.003  12:32:27
Element: Ni     Seq. No
Sample  ID: ccb
                          94
AS Loc.: 	
                                                 Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0230
0.0213
0.0043
0.0162
0.0104
63.98
StndConc
mg/L
0.0230
0.0213
0.0043
0.0162
0.0104
63.98
BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
63.98
Peak Bkgnd Time
Area Area
0.065 0.003 12:32:40
0.065 0.003 12:32:42
0.064 0.003 12:32:44



 Element:  Ni     Seq.  No.:  95
 Sample  ID:  era 0.05
AS Loc.
                                                  Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0

.0745
.0573
.0707
.0675
.0091
13.42
StndConc
mg/L
0
0
0
0
0

.0745
.0573
.0707
.0675
.0091
13.42
BlnkCorr
Signal
0.
0.
0.
0.
0.
13
003
002
003
003
000
.42
Peak
Area
0.
0.
0.



067
066
067



Bkgnd
Area
0.
0.
0.



003
003
002



Time

12:33:14
12:33:16
12:33:18



                                           Page 25

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0007
2 -0.0028
3 -0.0044
Mean: -0.0026
SD : 0.0019
%RSD: 72.08
Element : Ni Seq
Sample ID: era 0.1
Repl SampleConc
# mg/L
1 0.1200
2 0.1026
3 0.0922
Mean: 0.1049
SD : 0.0140
%RSD: 13.36
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0010
2 0.0097
3 0.0184
Mean: 0.0090
SD : 0.0097
%RSD: 107.5
Element: Ni Seq
Sample ID: era 0.2
Repl SampleConc
# mg/L
1 0.2762
2 0.2831
3 0.2925
Mean: 0.2839
SD : 0.0082
%RSD: 2.87
. No. : 96

StndConc
mg/L
-0.0007
-0.0028
-0.0044
-0.0026
0.0019
72.08
. No.: 97

StndConc
mg/L
0.1200
0.1026
0.0922
0.1049
0.0140
13.36
. No. : 98

StndConc
mg/L
-0.0010
0.0097
0.0184
0.0090
0.0097
107.5
. No.: 99
5
StndConc
mg/L
0.2762
0.2831
0.2925
0.2839
0.0082
2.87
AS :

BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
72.08
AS

BlnkCorr
Signal
0.005
0.004
0.004
0.004
0.001
13.36
AS

BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.000
107.46
AS

BlnkCorr
Signal
0.011
0.012
0.012
0.012
0.000
2.87
Loc. : 	

Peak
Area
0.064
0.064
0.064



Loc. : 	

Peak
Area
0.069
0.068
0.068



Loc. : 	

Peak
Area
0.064
0.064
0.065



Loc. : 	

Peak
Area
0.075
0.075
0.076



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:33:36
0.003 12:33:39
0.003 12:33:41



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:34:03
0.004 12:34:05
0.004 12:34:07



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:34:31
0.003 12:34:33
0.003 12:34:35



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:34:49
O.OQ3 12:34:52
Q.0'03 12:34:54



Page 26

-------
Element: Ni    Seq
Sample ID: ccb
                    No.:  100
              AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0241
0.0207
0.0387
0.0278
0.0096
34.42
StndConc
mg/L
0.0241
0.0207
0.0387
0.0278
0.0096
34.42
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.001 0.065 0.003 12:35:07
0.001 0.065 0.003 12:35:09
0.002 0.065 0.003 12:35:11
0.001
0.000
34.42
Element: Ni    Seq. No.: 101
Sample ID: Irb
              AS Loc.: 	
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0

,0405
.0678
.0473
.0519
.0142
27.36
StndConc
mg/L
0
0
0
0
0

.0405
.0678
.0473
.0519
.0142
27.36
BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
27.36
Peak
Area
0.
0.
0.



065
067
066



Bkgnd
Time
Area
0.
0.
0.



003
002
003



12
12
12




:35:45
:35:47
:35:50



Element: Ni    Seq. No.
Sample ID: ccb
     102
                                  AS Loc.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0834
0.0569
0.0684
0.0696
0.0132
19.04
StndConc
mg/L
0.0834
0.0569
0.0684
0.0696
0.0132
19.04
BlnkCorr Peak
Signal Area
0.003 0.067
0.002 0.066
0.003 0.067
0.003
0.001
19.04
Bkgnd Time
Area
0.002 12:36:09
0.003 12:36:11
0.002 12:36:13



Element: Ni    Seq. No.: 103
Sample ID: Sample
              AS Loc.
                                                 Date: 01/06/2006
Repl   SampleConc  StndConc
 #     mg/L        mg/L
 1       0.0673     0.0673
Auto-zero performed.
         BlnkCorr   Peak
          Signal    Area
           0.003    0.067
Bkgnd    Time
Area
 0.002  12:36:20
Element: Ni    Seq.
Sample ID: ccb
No.: 104
                                  AS Loc.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
-0
-0
-0
0

.0038
.0075
.0299
.0112
.0171
152.6
StndConc
mg/L
0
-0
-0
-0
0

.0038
.0075
.0299
.0112
.0171
152.6
BlnkCorr
Signal
0,000
0.000
-0.001
0.000
0.001
152.65
Peak
Area
0.
0.
0.



067
066
065



Bkgnd
Time
Area
0.
0.
0.



002
002
003



12
12
12



:36:27
:36:30
:36:32



                                           Page 27

-------
Element: Ni Seq.
Sample ID: Ifb
Repl SampleConc
# mg/L
1 0.9120
2 0.9023
3 0.9030
Mean: 0.9058
SD : 0.0054
%RSD: 0.60
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0478
2 -0.0440
3 -0.0328
Mean: -0.0415
SD : 0.0078
%RSD: 18.70
Element : Ni Seq
Sample ID: 307-1-2
Repl SampleConc
# mg/L
1 0.0604
2 0.0573
3 0.0581
Mean: 0.0586
SD : 0.0016
%RSD: 2.76
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0123
2 -0.0179
3 -0.0176
Mean: -0.0159
SD : 0.0031
%RSD: 19.67
No.: 105

StndConc
mg/L
0.9120
0.9023
0.9030
0.9058
0.0054
0.60
. No.: 106

StndConc
mg/L
-0.0478
-0.0440
-0.0328
-0.0415
0.0078
18.70
. No.: 107

StndConc
mg/L
0.0604
0.0573
0.0581
0.0586
0.0016
2.76
. No.; 108

StndConc
mg/L
-0.0123
-0.0179
-0.0176
-0.0159
0.0031
19.67
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.037 0.104
0.037 0.103
0.037 0.103
0.037
0.000
0.60
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.002 0.065
-0.002 0.065
-0.001 0.065
-0.002
0.000
18.70
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.002 0.069
0.002 0.069
0.002 0.069
0.002
0.000
2.76
AS LOG. : 	

BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.066
-0.001 0.066
-0.001
0.000
19.67
Date: 01/06/2006

Bkgnd Time
Area
0.002 12:36:45
0.003 12:36:48
0.003 12:36:50



Date: 01/06/2006

Bkgnd Time
Area
0.004 12:37:07
0.004 12:37:09
0.004 12:37:11



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:37:35
6.003 12:37:37
0.003 12:37:39



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:38:00
0.003 12:38:02
0.003 12:38:05



Page 28

-------
Element
Sample
Repl
#
1
2
3
Mean:
3D :
%RSD:
: Ni Seq.
ID: d307-l-2
SampleConc
mg/L
0.0965
0.0908
0.0876
0.0916
0.0045
4.91
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0077
0.0148
0.0072
0.0099
0.0042
42.66
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
No.: 109

StndConc
mg/L
0.0965
0.0908
0.0876
0.0916
0.0045
4.91
No.: 110

StndConc
mg/L
0.0077
0.0148
0.0072
0.0099
0.0042
42.66
No.: Ill
AS Loc. : 	

BlnkCorr
Signal
0.004
0.004
0.004
0,004
0.000
4.91

Peak
Area
0.070
0.070
0.070



AS Loc. : — -

BlnkCorr
Signal
0.000
0.001
0.000
0.000
0.000
42.66
AS

Peak
Area
0.067
0.067
0.067



Loc. : 	
Date: 01/06/2006

Bkgnd
Area
0.003
0.003
0.003




Time

12:38
12:38



:40
:42
12:38:44






Date: 01/06/2006

Bkgnd
Area
0.003
0.003
0.003



Date:

Time

12:38
12:39
12:39






:59
:02
-:04



01/06/2006
ID: s307-l-2
SampleConc
mg/L
1.147
1.162
1.154
1.155
0.0076
0.65
Element: Ni Seq.
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
ing/L
0.0330
0.0233
0.0202
0.0255
0.0067
26.18
StndConc
mg/L
1.147
1.162
1.154
1.155
0.0076
0.65
No.: 112

StndConc
mg/L
0.0330
0.0233
0.0202
0.0255
0.0067
26.18
BlnkCorr
Signal
0.047
0.047
0.047
0.047
0.000
0.65
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
26.18
Peak
Area
0.113
0.114
0.114



Loc. : 	

Peak
Area
0.068
0.068
0.067



Bkgnd
Area
0.003
0.003
0.003



Date:

Bkgnd
Area
0.002
0.002
0.002



Time

12:39
12:39
12:39





:37
:39
:41



01/06/2006

Time

12:40
12:40
12:40






:33
:36
:38



Page 29

-------
Element: Ni    Seq. No.:  113
Sample ID: ser307-l-2
                           AS LOG.
                                                 Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
n.
n.
0.
0.
0.

2770
2595
2486
2617
0143
5.47
StndConc
ing/L
0
0
0
0
0

.2770
.2595
.2486
.2617
.0143
5.47
BlnkCorr Peak Bkgnd Time
Signal Area Area
0
0
0
0
0

.011 0.078 0.001 12:41:10
.011 0.077 0.002 12:41:12
.010 0.077 0.002 12:41:14
.011
.001
5.47
Element: Ni    Seq. No.: 114
Sample ID: ccb
                           AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0336
0.0396
0.0354
0.0362
0.0030
8.36
StndConc
mg/L
0.0336
0.0396
0.0354
0.0362
0.0030
8.36
BlnkCorr Peak
Signal Area
0.001 0.068
0.002 0.068
0.001 0.068
0.001
0.000
8.36
Bkgnd Time
Area
0.002 12:42:02
0.002 12:42:04
0.002 12:42:06



Element: Ni    Seq.
Sample ID: 307-4-5
             No.: 115
                                  AS Loc.
                               Date:  01/06/2006
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD  :
%RSD:
Sample
SampleConc
mg/L
   12.27
absorbance
   12.29
absorbance
   12.32
absorbance
   12.29
  0.0270
    0.22
absorbance
 StndConc
 mg/L
   12.27
is greater
   12.29
is greater
   12.32
is greater
   12.29
  0.0270
    0.22
is greater
BlnkCorr
 Signal
  0.506
than that
  0.501
than that
  0.502
than that
  0.501
  0.001
   0.22
than that
 Peak     Bkgnd    Time
 Area     Area
 0.566     0.002  12:42:25
of the highest standard.
 0.567     0.001  12:42:27
of the highest standard.
 0.569     0.001  12:42:29
of the highest standard.
of the highest standard.
Element: Ni    Seq. No.: 116
Sample ID: ccb
                           AS Loc,
                               Date:  01/06/2006
Repl
ft
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.
0.
0.
0.
0.

0415
0478
0420
0438
0035
7.92
StndConc
mg/L
0.
0.
0.
0.
0.

0415
0478
0420
0438
0035
7.92
BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
7.92
Peak
Area
0.
0.
0.



068
068
068



Bkgnd
Time
Area
0.
0.
0.



002
002
002



12:
12:
12:



42:59
43:01
43:04



                                           Page  30

-------
Element: Ni    Seq. No.: 117
Sample ID: 307-4-5 xlO
              AS LOG.
                                                 Date: 01/06/2006
Repl SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
1.723
1.733
1.708
1.721
0.0126
0.73
StndConc
mg/L
1.723
1.733
1.708
1.721
0.0126
0.73
BlnkCorr Peak
Signal Area
0.070 0.137
0.071 0.137
0.070 0.136
0.070
0.001
0.73
Bkgnd Time
Area
0.002 12:44:18
0.002 12:44:20
0.003 12:44:23



Element: Ni    Seq.
Sample ID: ccb
No.: 118
                                  AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.0405
0.0336
0.0343
0.0362
0.0038
10.52
StndConc
mg/L
0.0405
0.0336
0.0343
0.0362
0.0038
10.52
BlnkCorr Peak
Signal Area
0.002 0.068
0.001 0.068
0.001 0.068
0.001
0.000
10.52
Bkgnd Time
Area
0.002 12:45:05
0.00-2 12:45:08
0.002 12:45:10



Element: Ni    Seq. No.: 119
Sample ID: 307-7-8
              AS Loc.
Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
6.577
absorbance
6.615
absorbance
6.688
absorbance
6.627
0.0561
0.85
absorbance
StndConc
mg/L

is

is

is



is
6.577
greater
6.615
greater
6.688
greater
6.627
0.0561
0.85
greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
268
that
270
that
273
that
270
002
.85
that
Peak
Area
0
of
0
of
0
of



of
.335
the
.336
the
.339
the



the
Bkgnd
Area


0.002
highest
Time

12:45:


30
standard.
0.002
highest
12:45:
32
standard.
0.001
highest



highest
12:45:
34
standard.









standard.
Element: Ni    Seq. No.: 120
Sample ID: ccb
              AS Loc.
Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0
0
0
0
0

.0304
.0366
.0540
.0403
.0122
30.38
StndConc
mg/L
0
0
0
0
0

.0304
.0366
.0540
.0403
.0122
30.38
BlnkCorr
Signal
0.001
0.001
0.002
0.002
0.000
30.38
Peak
Area
0.
0.
0.



068
068
069



Bkgnd
Time
Area
0.
0.
0.



002
002
001



12:
12:
12:



45:59
46:01
46:03



                                           Page  31

-------
Element: Ni    Seq. No.
Sample ID: 307-7-8 xlO
                         121
                                  AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
0.7891
0
0
0
0

.8236
.7970
.8032
.0181
2.25
StndConc
mg/L
0.7891
0
0
0
0

.8236
.7970
.8032
.0181
2.25
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.032 0.099 0.003 12:47:10
0
0
0
0

.034 0.100 0.002 12:47:12
.032 0.099 0.003 12:47:14
.033
.001
2.25
Element: Ni    Seq
Sample ID: ccb
                    No.: 122
                           AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0712
0.0059
-0.0151
-0.0268
0.0399
148.8
StndConc
mg/L
-0.0712
0.0059
-0.0151
-0.0268
0.0399
148.8
BlnkCorr Peak Bkgnd Time
Signal Area Area
-0.003 0.064 0.005 12:47:34
0.000 0.067 0.002 12:47:36
-0.001 0.066 0.003 12:47:38
-0.001
0.002
148.77
Element: Ni    Seq. No.:  123
Sample ID: 307-10-11
                           AS Loc.
                                                 Date:  01/06/2006
Repl
 #
 1
Sample
 2
Sample
 3
Sample
Mean:
SD   :
%RSD:
Sample
SampleConc
mg/L
   10.67
absorbance
   10.74
absorbance
   10.73
absorbance
   10.71
  0.0385
    0.36
absorbance
 StndConc
 mg/L
   10.67
is greater
   10.74
is greater
   10.73
is greater
   10.71
  0.0385
    0.36
is greater
BlnkCorr
 Signal
  0.435
than that
  0.438
than that
  0.437
than that
  0.437
  0.002
   0.36
than that
 Peak     Bkgnd    Time
 Area     Area
 0.501     0.002  12:48:27
of the highest standard.
 0.504     0.002  12:48:29
of the highest standard.
 0.504     0,003  12:48:31
of the highest standard.
of the highest standard.
 Element:  Ni     Seq.
 Sample  ID: ccb
             No.: 124
                                  AS  Loc.
                                                  Date:  01/06/2006
 Repl
  #
  1
  2
  3
 Mean:
 SD   :
 %RSD:
SampleConc
mg/L
 -0.0038
  0.0085
  0.0146
  0.0065
  0.0094
   145.1
 StndConc
 mg/L
 -0.0038
  0.0085
  0.0146
  0.0065
  0.0094
   145.1
BlnkCorr
 Signal
  0.000
  0.000
  0.001
  0.000
  0.000
 145.08
 Peak
 Area
 0.066
 0.067
 0.067
Bkgnd
Area
 0.002
 0.002
 0.002
 Time

12:4-9:03
12:49:05
12:49:08
                                           Page 32

-------
Element: Ni    Seq. No.: 125
Sample ID: 307-10-11 xlO
AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
1.408
1.393
1.424
1.409
0.0156
1.11
StndConc
mg/L
1.408
1.393
1.424
1.409
0.0156
1.11
BlnkCorr Peak Bkgnd Time
Signal Area Area
0.057 0.124 0.002 12:50:19
0.057 0.123 0.002 12:50:21
0.058 0.125 0.002 12:50:24
0.057
0.001
1.11
Element: Ni    Seq. No.: 126
Sample ID: ccb
AS Loc.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0218
-0.0213
-0.0346
-0.0259
0.0075
29.07
StndConc
mg/L
-0.0218
-0.0213
-0.0346
-0.0259
0.0075
29.07
BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.066
-0.001 0.065
-0.001
0.000
29.07
Bkgnd Time
Area
0.003 12:50:55
0.003 12:50:57
0.003 12:50:59



Element: Ni    Seq. No.: 127
Sample ID: ccb
AS Loc.
                                                  Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
-0.0200
-0.0028
-0.0310
-0.0179
0.0142
79.30
StndConc
mg/L
-0.0200
-0.0028
-0.0310
-0.0179
0.0142
79.30
BlnkCorr Peak
Signal Area
-0.001 0.066
0.000 0.066
-0.001 0.065
-0.001
0.001
79.30
Bkgnd Time
Area
0.003 12:51:21
0.003 12:51:23
0.003 12:51:25



Element: Ni     Seq. No.:  128
Sample ID: ccv
AS Loc.
                                                  Date:  01/06/2006
Repl SampleConc
# mg/L
1 8.796
Sample absorbance
2 8.692
Sample, absorbance
3 8.850
Sample absorbance
Mean: 8.779
SD : 0.0802
%RSD: 0.91
Sample absorbance
StndConc BlnkCorr Peak Bkgnd Time
mg/L Signal Area Area
8.796 0.358 0.425 0.004 12:51:41
is greater than that of the highest standard.
8.692 0.354 0.421 0.004 12:51:43
is greater than that of the highest standard.
8.850 0.361 0.427 0.003 12:51:45
is greater than that of the highest standard.
8.779 0.358
0.0802 0.003
0.91 0.91
is greater than that of the highest standard.
                                           Page 33

-------
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0159
2 -0.0292
3 -0.0256
Mean: -0.0236
SD : 0.0069
%RSD: 29.15
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 1.042
2 1.038
3 1.023
Mean: 1.034
SD : 0.0102
%RSD: 0.99
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0256
2 -0.0340
3 -0.0295
Mean: -0.0297
SD : 0.0042
%RSD: 14.10
Element: Ni Seq.
No.: 129

StndConc
mg/L
-0.0159
-0.0292
-0.0256
-0.0236
0.0069
29.15
No.: 130

StndConc
mg/L
1.042
1.038
1.023
1.034
0.0102
0.99
No.: 131

StndConc
mg/L
-0.0256
-0.0340
-0.0295
-0.0297
0.0042
14.10
No.: 132
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.065
-0.001 0.066
-0.001
0.000
29.15
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.042 0.109
0.042 0.109
0.042 0.108
0.042
0.000
0.99
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.066
-0.001 0.065
-0.001 0.065
-0.001
0.000
14.10
AS Loc. : 	
Date: 01/06/2006

Bkgnd Time
Area
0.003 12:52:06
0.003 12:52:09
0.003 12:52:11



Date: 01/06/200€

Bkgnd Time
Area
0.004 12:52:33
0.004 12:52:35
0.004 12:52:37



Date: 01/06/2006

Bkgnd Time
Area
0.004 12:53:03
0.004 12:53:05
0.004 12:53:07



Date: 01/06/2006
Sample ID: 307-13-14
Repl SampleConc
# rng/L
1 0.0630
2 0.0711
3 0.0770
Mean: 0.0704
SD : 0.0070
%RSD: 9.95
StndConc
mg/L
0.0630
0.0711
0,0770
0.0704
0.0070
9.95
BlnkCorr Peak
Signal Area
0.003 0.069
0.003 0.069
0.003 0.070
0.003
0.000
9.95
Bkgnd Time
Area
0.004 12:53:28
0.004 12:53:30
0.003 12:53:32



Page 34

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I -0.0428
2 -0.0327
3 -0.0268
Mean: -0.0341
SD : 0.0081
%RSD: 23.87
Element: Ni Seq
. No. : 133

StndConc
mg/L
-0.0428
-0.0327
-0.0268
-0.0341
0.0081
23.87
.No.: 134
AS

BlnkCorr
Signal
-0.002
-0.001
-0.001
-0.001
0.000
23.87
AS
iioc. : 	

Peak
Area
0.065
0.065
0.065



Loc. : 	
Date: 01/06/2006

Bkgnd Time
Area
0.004 12:54:57
0.004 12:54:59
0.004 12:55:01



Date: 01/06/2006
Sample ID: 307-16-17
Repl SampleConc
# mg/L
1 0.6813
2 0.68-68
3 0.6790
Mean: 0.6824
SD : 0.0041
%RSD: 0.59
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0295
2 -0.0358
3 -0.0292
Mean: -0.0315
SD : 0.0037
%RSD: 11.74
Element : Ni Seq
StndConc
mg/L
0.6813
0.6868
0.6790
0.6824
0.0041
0.59
.No.: 135

StndConc
mg/L
-0.0295
-0.0358
-0.0292
-0.0315
0.0037
11.74
. No.: 136
BlnkCorr
Signal
0.028
0.028
0.028
0.028
0.000
0.59
AS

BlnkCorr
Signal
-0.001
-0.001
-0.001
-0.001
0.000
11.74
AS
Peak
Area
0.094
0.095
0.094



Loc. : 	

Peak
Area
0.065
0,065
0.065



Loc. : 	
Bkgnd Time
Area
0.004 12:55:18
0.004 12:55:20
0.004 12:55:22



Date: 01/06/2006

Bkgnd Time
Area
0.004 12:55:38
0.004 12:55:40
0.003 12:55:42



Date: 01/06/2006
Sample ID: 307-19-20
Repl SampleConc
# mg/L
1 0.3796
2 0.3901
3 0.3895
Mean: 0.3864
SD : 0.0059
%RSD: 1.52
StndConc
mg/L
0.3796
0.3901
0.3895
0.3864
0.0059
1.52
BlnkCorr
Signal
0.015
0.016
0.016
0.016
0.000
1.52
Peak
Area
0.082
0.082
0.082



Bkgnd Time
Area
0.004 12:56:03
0.003 12:56:05
0.003 12:56:07



Page 35

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0377
2 -0.0402
3 -0.0251
Mean: -0.0344
SD : 0.0081
%RSD: 23.58
Element: Hi Seq
. No. : 137

StndConc
mg/L
-0.0377
-0.0402
-0.0251
-0.0344
0.0081
23.58
.No.: 138
AS

BlnkCorr
Signal
-0.002
-0.002
-0.001
-0.001
0.000
23.58
AS
LOG . : 	

Peak
Area
0.065
0.065
0.066



Loc. : 	
Date-. 01/06/2006

Bkgnd Time
Area
0.004 12:56:31
0.004 12:56:33
0.004 12:56:35



Date: 01/06/2006
Sample ID: 307-22-23
Repl SampleConc
# mg/L
1 0.3391 ,
2 0.3337
3 0.3481
Mean: 0.3403
SD : 0.0073
%RSD: 2.14
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0051
2 -0.0117
3 -0.0271
Mean: -0.0146
SD : 0.0113
%RSD: 77.29
Element : Ni Seq
StndConc
mg/L
0.3391
0.3337
0.3481
0.3403
0.0073
2.14
. No. : 139

StndConc
mg/L
-0.0051
-0.0117
-0.0271
-0.0146
0.0113
77.29
. No. : 140
BlnkCorr
Signal
0.014
0.014
0.014
0,014
0:000
2.14
AS

BlnkCorr
Signal
0.000
0.000
-0.001
-0.001
0.000
77.29
AS
Peak
Area
0.080
0.080
0.081



Loc. : 	

Peak
Area
0.066
0.066
0.065



Loc. : 	
Bkgnd Time
Area
0.004 12:56:57
0.004 12:56:59
0.004 12:57:01



Date: 01/06/2006

Bkgnd Time
Area
0.003 12:57:20
0.003 12:57:22
0.003 12:57:24


.
Date: 01/06/2006
Sample ID: 307-25-26
Repl SampleConc
# mg/L
1 3.506
2 3.515
3 3.521
Mean: 3.514
SD : 0.0072
%RSD: 0.20
StndConc
mg/L
3.506
3.515
3.521
3.514
0.0072
0.20
BlnkCorr
Signal
0.143
0.143
0.143
0.143
0.000
0.20
Peak
Area
0.209
0.210
0.210



Bkgnd Time
Area
0.004 12:57:43
0.003 12:57:45
0.003 12:57:47



Page 36

-------
Element: Mi    Seq. No.: 141
Sample ID: ccb
         AS Loc.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc StndConc BlnkCorr Peak Bkgnd Time
mg/L
0.0297
0.0412
0.0323
0. 0344
0.0060
17.49
mg/L
0.0297
0.0412
0.0323
0.0344
0.0060
17.49
Signal Area Area
0.001 0.068 0.002 12:59:40
0.002 0.068 0.001 12:59:42
0.001 0.068 0.002 12:59:44
0.001
0.000
17.49
Element: Ni    Seq. No.
Sample ID: 307-28-29
142
                                  AS LOG.
                                                 Date: 01/06/2006
Repl
#
1
2
3
Mean:
SD :
%RSD:
SampleConc
mg/L
4.542
4.562
4.612
4.572
0.0359
0.78
StndConc
mg/L
4.542
4.562
4.612
4.572
0.0359
0.78
BlnkCorr Peak
Signal Area
0.185 0.252
0.186 0.252
0.188 0.254
0.186
0.001
0.78
Bkgnd Time
Area
0.002 13:01:03
0.002 13:01:05
0.002 13:01:07



Element: Ni    Seq. No.: 143
Sample ID: ccb
         AS Loc.
                                                 Date:  01/06/2006
Repl
#
1
2
3
Mean:
SD :
%,RSD:
SampleConc
mg/L
0.0189
0.0256
0.0195
0.0213
0.0037
17.39
StndConc
mg/L
0.0189
0.0256
0.0195
0.0213
0.0037
17.39
BlnkCorr Peak
Signal Area
0.001 0.067
0.001 0.068
0.001 0.067
0.001
0.000
17.39
Bkgnd Time
Area
0.002 13:01:31
0.002 13:01:33
0.002 13:01:35



Element: Ni    Seq. No.: 144
Sample ID: 307-31-32
         AS Loc.
                        Date: 01/06/2006
Repl
#
1
Sample
2
Sample
3
Sample
Mean:
SD :
%RSD:
Sample
SampleConc
mg/L
5.948
absorbance
6.011
absorbance
6.011
absorbance
5.990
0.0362
0.61
absorbance
StndConc
mg/L
5.948
is greater
6.011
is greater
6,011
is greater
5.990
0.0362
0.61
is greater
BlnkCorr
Signal
0.
than
0.
than
0.
than
0.
0.
0
than
242
that
245
that
245
that
244
001
.61
that
Peak
Area
0.
of
0.
of
0.
of



of
309
the
311
the
312
the



the
Bkgnd
Area

0.003
highest
Time

13:01:
standard.
0.002
highest
13:01:


54

56
standard.
0.003
highest



highest
13:01:
58
standard.









standard.
                                           Page 37

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0054
2 -0.0107
3 0.0140
Mean: -0.0007
SD : 0.0130
%RSD: 1823
. No. : 145
StndConc
mg/L
-0.0054
-0.0107
0.0140
-0.0007
0.0130
1823
Element: Ni Seq. No. ; 146
Sample ID: 307-31-32 xlO
Repl SampleConc
f mg/L
1 0.6944
2 0.7131
3 0.7062
Mean: 0.7046
SD : 0.0095
%RSD: 1.34
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0062
2 -0.0023
3 0.0071
Mean: 0.0037
SD : 0.0052
%RSD: 141.3
Element : Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0143
2 0.0039
3 -0.0048
Mean: 0.0045
SD : 0.0095
%RSD: 212.5
StndConc
mg/L
0.6944
0.7131
0.7062
0.7046
0.0095
1.34
. No. : 147
StndConc
mg/L
0.0062
-0.0023
0.0071
0.0037
0.0052
141.3
. No. : 148
StndConc
mg/L
0.0143
0.0039
-0.0048
0.0045
0.0095
212.5
AS
BlnkCorr
Signal
0.000
0.000
0.001
0.000
0.001
1823.13
AS
BlnkCorr
Signal
0.028
0.029
0.029
0.029
0.000
1.34
AS
BlnkCorr
Signal
0.000
0.000
0.000
0.000
0.000
141.33
AS
BlnkCorr
Signal
0,001
0.000
0.000
0.000
0.000
212.46
IjOC « >
Peak
Area
0.066
0.066
0.067


Loc. : 	
Peak
Area
0.095
0.096
0.095



Loc. : 	
Peak
Area
0.067
0.066
0.067



Loc. : 	
Peak
Area
0.067
0.067
0.066



Date:
Bkgnd
Area
0.003
0.003
0.002


Date:
Bkgnd
Area
0.003
0.003
0.003



Date:
Bkgnd
Area
0.003
0.003
0.002



Date:
Bkgnd
Area
0.003
0.003
0.003



01/06/2006
Time
13:02:46
13:02:48
13:02:50


01/06/2006
Time
13:03:22
13:03:25
13:03:27



01/06/2006
Time
13:03:43
13:03:46
13:03:48



01/06/2006
Time
13:04:16
13:04:19
13:04:21



Page 38

-------
Element: Ni Seq
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.5242
2 0.5521
3 0.5354
Mean: 0.5372
SD : 0.0140
%RSD: 2.61
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0123
2 0.0131
3 -0.0069
Mean: -0,0020
SD : 0.0134
%RSD: 662.0
Element: Ni Seq
Sample ID: Irb
Repl SampleConc
# mg/L
1 -0.0061
2 -0.0005
3 -0.0023
Mean: -0.0030
SD : 0.0028
%RSD: 96.39
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0103
2 -0.0007
3 -0.0177
Mean: -0.0096
SD : 0.0086
%RSD: 89.41
. No. : 149

StndConc
mg/L
0.5242
0.5521
0.5354
0.5372
0.0140
2.61
. No. : 150

StndConc
mg/L
-0.0123
0.0131
-0.0069
-0.0020
0.0134
662.0
. No. : 151

StndConc
mg/L
-0.0061
-0.0005
-0.0023
-0.0030
0.0028
96.39
. No.: 152

StndConc
mg/L
-0.0103
-0.0007
-0.0177
-0.0096
0.0086
89.41
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.021 0.088
0.022 0.089
0.022 0.088
0.022
0.001
2.61
AS Loc. : 	

BlnkCorr Peak
Signal Area
-0.001 0.066
0.001 0.067
0.000 0.066
0.000
0.001
662.01
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.067
0.000 0.066
0.000
0.000
96.39
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.067
-0.001 0.066
0.000
0.000
89.41
Date: 01/06/2006

Bkgnd Time
Area
0.004 13:04:34
0.003 13:04:36
0.003 13:04:38



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:04:55
0.002 13:04:57
0.003 13:04:59



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:05:15
0.003 13:05:17
0.003 13:05:19



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:05:35
0.003 13:05:37
0.003 13:05:39



Page 39

-------
Element: Ni Seq
Sample ID: Ifb
Repl SampleConc
# mg/L
1 1.023
2 1.020
3 1.025
Mean: 1.023
3D : 0.0027
%RSD: 0.26
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 -0.0103
2 -0.0084
3 -0.0072
Mean: -0.0086
SD : 0.0016
%RSD: 19.24
Element: Ni Seq
Sample ID: 307-3
Repl SampleConc
# mg/L
1 0.0679
2 0.0637
3 0.0553
Mean: 0.0623
SD : 0.0064
%RSD: 10.32
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0304
2 0.0159
3 0,0346
Mean: 0.0270
SD : 0.0098
%RSD: 36.36
. No.: 153

StndConc
mg/L
1.023
1.020
1.025
1.023
0.0027
0.26
. No.: 154

StndConc
mg/L
-0.0103
-0.0084
-0.0072
-0.0086
0.0016
18.24
, No.: 155

StndConc
mg/L
0.0679
0.0637
0.0553
0.0623
0.0064
10.32
. No. : 156

StndConc
mg/L
0.0304
0.0159
0,0346
0.0270
0.0098
36.36
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.042 0.108
0.042 0.108
0.042 0.108
0.042
0.000
0.26
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.000 0.066
0.000 0.066
0.000 0.066
0.000
0.000
18.24
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.003 0.069
0.003 0.069
0.002 0.069
0.003
0.000
10.32
AS Loc. : 	 •

BlnkCorr Peak
Signal Area
0.001 0.068
0.001 0.067
0.001 0.068
0.001
0.000
36.36
Date: 01/06/2006

Bkgnd Time
Area
0.003 13:05:55
0.004 13:05:58
0.004 13:06:00



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:06:18
0.003 13:06:20
0.003 13:06:23



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:06:48
0.003 13:06:50
0.003 13:06:52



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:07:09
0.002 13:07:11
0.002 13:07:14



Page 40

-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: d307-3
SampleConc
mg/L
0.0020
0.0583
0.0647
0.0416
0.0345
82.86
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean;
SD :
%RSD:
El ement
Sample
Repl
ID: ccb
SampleConc
mg/L
0.0309
0.0327
0.0284
0.0306
0.0021
6.99
: Ni Seq
ID: S307-3
SampleConc
mg/L
1.011
1.033
1.016
1.020
0.0113
1.11
: Ni Seq
ID: ccb
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.0166
0.0261
0.0171
0.0199
0.0054
26.91
. No. : 157

StndConc
mg/L
0.0020
0.0583
0.0647
0.0416
0.0345
82.86
. No.: 158

StndConc
mg/L
0.0309
0.0327
0.0284
0.0306
0.0021
6.99
.No.: 159

StndConc
mg/L
1.011
1.033
1.016
1.020
0.0113
1.11
. No. : 160

StndConc
mg/L
0.0166
0.0261
0.0171
0.0199
0.0054
26.91
AS

BlnkCorr
Signal
0.000
0.002
0.003
0.002
0.001
82.86
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
6.99
AS

BlnkCorr
Signal
0.041
0.042
0.041
0.042
0.000
1.11
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
26.91
Loc. : 	

Peak
Area
0.067
0.069
0.069



Loc. : 	

Peak
Area
0.068
0.068
0.068



Loc. : 	

Peak
Area
0,108
0.109
0.108



Loc. : 	

Peak
Area
0.067
0.068
0.067



Date: 01/06/2006

Bkgnd Time
Area
0.005 13:08:34
0.003 13:08:36
0.002 13:08:38



Date: 01/06/2006

Bkgnd Time
Area
0.001 13:09:06
0.001 13:09:08
0.001 13:09:10



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:09:41
0.002 13:09:43
0.002 13:09:45



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:09:59
0.003 13:10:01
0.003 13:10:03



Page 41

-------
Element: Ni Seq
. No.: 161 AS Loc.: 	
Date: 01/06/2006
Sample ID: ser307-3
Repl SampleConc
# mg/L
1 0.2258
2 0.2224
3 0.2281
Mean: 0.2254
SD : 0.0029
%RSD: 1.28
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0174
2 0.0458
3 0.0338
Mean: 0.0323
SD : 0.0143
%R^D: 44.09
Element: Ni Seq
Sample ID: 307-6
Repl SampleConc
# mg/L
1 0.2232
2 0.2288
3 0.2196
Mean: 0.2239
SD : 0.0046
%RSD: 2.07
Elements Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0604
2 0.0532
3 0.0619
Mean: 0.0585
SD : 0.0047
%RSD: 7.96
StndConc BlnkCorr Peak
mg/L Signal Area
0.2258 0.009 0.076
0.2224 0.009 0.076
0.2281 0.009 0.076
0.2254 0.009
0.0029 0.000
1.28 1.28
. No, : 162 AS Loc. : 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.0174 0.001 0.067
0.0458 0.002 0.068
0.0338 0.001 0.068
0.0323 0.001
0.0143 0.001
44.09 44.09
. No.: 163 AS Loc.: 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.2232 0.009 0.076
0.2288 0.009 0.076
0.2196 0.009 0.076
0.2239 0.009
0.0046 0.000
2.07 2.07
. No. : 164 AS Loc. : 	

StndConc BlnkCorr Peak
mg/L Signal Area
0.0604 0.002 0.069
0.0532 0.002 0.069
0.0619 0.003 0.069
0.0585 0.002
0.0047 0.000
7.96 7.96
Bkgnd Time
Area
0.003 13:10:59
0.004 13:11:01
0.003 13:11:03



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:11:54
0.002 13:11:56
0.002 13:11:58



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:12:19
0.002 13:12:21
0.002 13:12:23



Date: 01/06/2006

Bkgnd Time
Area
0.001 13:12:38
0.002 13:12:40
0.002 13:12:43



Page 42

-------
Element: Ni Seq
Sample ID: 307-9
Repl SampleConc
# mg/L
1 0.1782
2 0.1789
3 0.1879
Mean: 0.1817
SD : 0.0054
%RSD: 2.98
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0302
2 0.0313
3 0.0377
Mean: 0.0331
SD : 0.0041
%RSD: 12.29
Element: Ni Seq
Sample ID: 307-12
Repl SampleConc
# mg/L
1 0.1213
2 0.1155
3 0,1131
Mean: 0.1166
SD : 0.0042
%RSD: 3.61
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0141
2 0.0240
3 0.0419
Mean: 0.0266
SD : 0.0141
%RSD: 52.78
. No.: 165

StndConc
mg/L
0.1782
0.1789
0.1879
0.1817
0.0054
2.98
. No. : 166

StndConc
mg/L
0.0302
0.0313
0.0377
0.0331
0.0041
12.29
. No.: 167

StndConc
mg/L
0.1213
0.1155
0.1131
0.1166
0.0042
3.61
. No.: 168

StndConc
mg/L
0.0141
0.0240
0.0419
0.0266
0.0141
52.78
AS LOG. : 	

BlnkCorr Peak
Signal Area
0.007 0.074
0.007 0.074
0.008 0.074
0.007
0.000
2.98
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.001 0.068
0.001 0.068
0.002 0.068
0.001
0.000
12.29
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.005 0.071
0.005 0.071
0.005 0.071
0.005
0.000
3.61
AS Loc. : 	

BlnkCorr Peak
Signal Area
0,001 0.067
0.001 0.068
0.002 0.068
0.001
0.001
52.78
Date: 01/06/2006

Bkgnd Time
Area
0.002 13:12:59
0.002 13:13:01
0.002 13:13:03



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:13:23
0.002 13:13:25
0.002 13:13:27



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:13:43
0.003 13:13:45
0,003 13:13:47



Date: 0^/06/2006

Bkgnd Time
Area
0.003 13:14:05
0.003 13:14:08
0.002 13:14:10



Page 43

-------
Element: Ni Seq.
Sample ID: 307-15
Repl SampleConc
# mg/L
I 0.0888
2 0.0926
3 0.0924
Mean: 0.0913
SD : 0,0021
%RSD: 2.34
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0499
2 0.0231
3 0.0097
Mean: 0.0276
SD ; 0.0205
%RSD: 74.23
Element: Ni Seq.
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0414
2 0.0159
3 0.0208
Mean: 0.0260
SD : 0.0135
%RSD: 51.81
Element: Ni Seq.
Sample ID: ccv
Repl SampleConc
# mg/L
1 0.2846
2 0.2928
3 0.2808
Mean: 0.2861
SD : 0.0061
%RSD: 2.14
No.: 169

StndConc
mg/L
0.0888
0.0926
0.0924
0.0913
0.0021
2.34
No.: 170

StndConc
mg/L
0.0499
0.0231
0.0097
0.0276
0.0205
74.23
No,: 171

StndConc
mg/L
0.0414
0.0159
0.0208
0.0260
0.0135
51.81
No. : 172

StndConc
mg/L
0.2846
0.2928
0.2808
0.2861
0.0061
2.14
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.004 0.070
0.004 0.070
0.004 0.070
0.004
0.000
2.34
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.069
0.001 0.067
0.000 0.067
0.001
0.001
74.23
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.002 0.068
0.001 0,067
0.001 0.067
0.001
0.001
51.81
AS Loc. : 	

BlnkCorr Peak
Signal Area
0.012 0.078
0.012 0.078
0,011 0.078
0.012
0.000
2.14
Date: 01/06/2006

Bkgnd Time
Area
0.003 13:14:24
0.003 13:14:26
0.003 13:14:29



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:14:48
0,003 13:14:51
0.003 13:14:53



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:15:00
0.003 13:15:02
0.003 13:15:04



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:15:18
0.003 13:15:20
0.003 13:15:22



Page 44

-------
Element
Sample
Repl
#
I
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
: Ni Seq
ID: ccb
SampleConc
mg/L
0.0300
0.0241
0.0118
0.0220
0.0093
42.26
: Ni Seq
ID: 307-18
SampleConc
mg/L
0.1567
0.1776
0.1781
0.1708
0.0122
7.13
: Ni Seq
ID: ccb
SampleConc
rag/L
0.0110
0.0171
0.0146
0.0142
0.0031
21.47
: Ni Seq
ID: 307-21
SampleConc
# mg/L
1
2
3
Mean:
SD :
%RSD:
0.1193
0.1469
0.1362
0.1341
0.0139
10.36
. No. : 173

StndConc
mg/L
0.0300
0.0241
0.0118
0.0220
0.0093
42.26
. No. : 174

StndConc
mg/L
0.1567
0.1776
0.1781
0.1708
0.0122
7.13
. No. : 175

StndConc
mg/L
0.0110
0.0171
0.0146
0.0142
0.0031
21.47
. No. : 176

StndConc
mg/L
0.1193
0.1469
0.1362
0.1341
0.0139
10.36
AS

BlnkCorr
Signal
0.001
0.001
0.000
0.001
0.000
42.26
AS

BlnkCorr
Signal
0.006
0.007
0,007
0.007
0.000
7.13
AS

BlnkCorr
Signal
o.ooo
0.001
0.001
0.001
0.000
21.47
AS

BlnkCorr
Signal
0.005
0.006
0.006
0.005
0.001
10.36
LOG. : 	

Peak
Area
0.068
0.068
0.067



Loc. : 	

Peak
Area
0.073
0.074
0.074



Loc. : 	

Peak
Area
0.067
0.067
0.067



Loc. : 	

Peak
Area
0.071
0.073
0.072



Date:

Bkgnd
Area
0.003
0.003
0.003



Date:

Bkgnd
Area
0.003
0.003
0.003



Date:

Bkgnd
Area
0.004
0.003
0.003



Date:

Bkgnd
Area
0.004
0.003
0.003



01/06/2006

Time

13:15:
13:15:
13:15:






41
43
45



01/06/2006

Time

13:16:
13:16:
13:16:






00
03
05



01/06/2006

Time

13:16:
13:16:
13:16:






24
26
28



01/06/2006

Time

13:16:
13:17:
13:17:






59
01
03



Page 45

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0348
2 0.0236
3 0.0317
Mean: 0.0300
3D : 0.0058
%RSD: 19.17
Element: Ni Seq
Sample ID: 307-24
Repl SampleConc
# mg/L
1 0.1328
2 0.1147
3 0.1367
Mean: 0.1281
SD : 0.0117
%RSD: 9.16
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0420
2 0.0497
3 0.0568
Mean: 0.0495
SD : 0.0074
%RSD: 14.92
Element: Ni Seq,
Sample ID: 307-27
Repl SampleConc
# mg/L
1 0.2056
2 0.2175
3 0.1960
Mean: 0.2064
SD : 0.0108
%RSD: 5.22
. No. : 177

StndConc
mg/L
0.0348
0.0236
0.0317
0.0300
0.0058
19.17
. No. : 178

StndConc
mg/L
0.1328
0.1147
0.1367
0.1281
0.0117
9.16
. No. : 179

StndConc
mg/L
0.0420
0.0497
0.0568
0.0495
0.0074
14.92
. No. : 180

StndConc
mg/L
0.2056
0.2175
0.1960
0.2064
0.0108
5.22
AS

BlnkCorr
Signal
0.001
0.001
0.001
0.001
0.000
19.17
AS

BlnkCorr
Signal
0.005
0.005
0.006
0.005
0.000
9.16
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
14.92
AS :

BlnkCorr
Signal
0.008
0.009
0.008
0.008
0.000
5.22
Loc. : 	

Peak
Area
0.068
0.068
0.068



Loc. : 	

Peak
Area
0.072
0.071
0.072



Loc. : 	

Peak
Area
0.068
0.069
0.069



Loc. : 	

Peak
Area
0.075
0.075
0.075



Date: 01/06/2006

Bkgnd Time
Area
0.003 13:17:25
0.003 13:17:27
0.003 13:17:29



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:18:03
0.002 13:18:06
0.002 13:18:08



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:18:28
0.002 13:18:30
0.001 13:18:32



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:19:12
0.002 13:19:14
0.003 13:19:16



Page 46

-------
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
I 0.0519
2 0.0484
3 0.0596
Mean: 0.0533
SD : 0.0057
%RSD: 10.72
Element: Ni Seq
Sample ID: 307-30
Repl SampleConc
# mg/L
1 0,1743
2 0.1605
3 0.1585
Mean: 0.1644
SD : 0.0086
%RSD: 5.22
Element: Ni Seq
Sample ID: ccb
Repl SampleConc
# mg/L
1 0.0405
2 0.0655
3 0.0517
Mean: 0.0526
SD : 0.0125
%RSD: 23.77
Element: Ni Seq
Sample ID: 307-33
Repl SampleConc
# mg/L
1 0.1170
2 0.1124
3 0.1321
Mean: 0.1205
SD : 0.0103
%RSD: 8.55
. No. : 181

StndConc
mg/L
0.0519
0.0484
0.0596
0.0533
0.0057
10.72
. No. : 182

StndConc
mg/L
0.1743
0.1605
0.1585
0.1644
0.0086
5.22
. No. : 183

StndConc
mg/L
0.0405
0.0655
0.0517
0.0526
0.0125
23.77
. No, : 184

StndConc
mg/L
0.1170
0.1124
0.1321
0.1205
0.0103
8.55
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
10.72
AS

BlnkCorr
Signal
0.007
0.007
0.006
0.007
0.000
5.22
AS

BlnkCorr
Signal
0.002
0.003
0.002
0.002
0.001
23,77
AS :

BlnkCorr
Signal
0.005
0.005
0.005
0.005
0.000
8.55
LOG. : 	

Peak
Area
0.069
0.069
0.069



LOG. : 	

Peak
Area
0.074
0.073
0.073



LOG. : 	

Peak
Area
0.068
0.069
0.069



LOG, : 	

Peak
Area
0.071
0.071
0.072



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:19:34
0.002 13:19:36
0.002 13:19:38



Date: 01/06/2006

Bkgnd Time
Area
0.001 13:20:11
0.002 13:20:14
0.002 13:20:16



Date: 01/06/2006

Bkgnd Time
Area
0,002 ^.3:20:44
0.001 13:20:46
0.001 13:20:48



Date: 01/06/2006

Bkgnd Time
Area
0.002 13:21:09
0.002 13:21:11
0.002 13:21:13



Page 47

-------
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0502
0.0606
0.0579
0.0562
0.0054
9.56
Element: Ni Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0533
0.0560
0.0740
0.0611
0.0113
18.42
Element: Mi Seq
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
Element
Sample
Repl
#
1
2
3
Mean:
SD :
%RSD:
ID: ccb
SampleConc
mg/L
0.0533
0.0494
0.0553
0.0527
0.0030
5.71
: Ni Seq
ID: ccv
SampleConc
mg/L
0.5464
0.5782
0.5912
0.5719
0.0231
4.03
. No. : 185

StndConc
mg/L
0.0502
0.0606
0.0579
0.0562
0.0054
9.56
. No.: 186

StndConc
mg/L
0.0533
0.0560
0.0740
0.0611
0.0113
18.42
. No.: 187

StndConc
mg/L
0.0533
0.0494
0.0553
0.0527
0.0030
5.71
.No.: 188

StndConc
mg/L
0.5464
0.5782
0.5912
0.5719
0.0231
4.03
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
9.56
AS

BlnkCorr
Signal
0.002
0.002
0.003
0.002
0.000
18.42
AS

BlnkCorr
Signal
0.002
0.002
0.002
0.002
0.000
5.71
AS

BlnkCorr
Signal
0.022
0.024
0.024
0.023
0.001
4.03
LOG. : 	

Peak
Area
0.069
0.069
0.069



LOG. : 	

Peak
Area
0.069
0.069
0.070



Loc. i

Peak
Area
0.069
0.069
0.069



Loc. : 	

Peak
Area
0.089
0.090
0.091



Date:

Bkgnd
Area
0.002
0.001
0.001



Date:

Bkgnd
Area
0.002
0.001
0.001



Date:

Bkgnd
Area
0.002
0.002
0.001



Date:

Bkgnd
Area
0.003
0.002
0.002



01/06/2006

Time

13:21:
13:21:
13:21:






33
36
38



01/06/2006

Time

13:21*
13:21:
13:21:






46
48
51



01/06/2006

Time

13:22:
13:22:
13:22:






07
10
12



01/06/2006

Time

13:22:
13:22:
13:22:






27
29
31



Page 48

-------
 METALS   PREP    FORM
                                                             Set#
Prep Method:    (check only one per page)
   ICP/FLAA: SM 3030 F, EPA 200.7 '82
   ICP/FLAA: EPA200's, SW-8463010A
   ICP/FLAA: EPA 200.7 r4.4
   [CP/FLAA: SW-8463005A
   ICP/FLAA: SW-846 3015A MICROWAVE
   OTHER:	
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:  	
MATRIX:        (check only one per page)
   DRINKING WATER               I  [AQUEOUS
                  OTHER:



1


2
ft
4
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      ICP/FLAA:  SW-846 3015A MICROWAVE
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                              GFAA:  EPA 200.9
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      IGP/FLAA: EPA 200's, SW-84S 301OA
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                                                                                         S\QA FORMS \FM-041 \R02 \LK
                                                                                                    Page 1 of 1

-------

-------
Identification
Method Name:  NI
Technique:  Fl ame
Method Desc:  Nickel

Remarks:
    Element:  Ni
    Instrument Model: 5100
Instrument
Wavelength (nm):  232.0
Slit Width:       0.2

Signal Type:  AA-BG
Signal Measurement: Time Average
Modified Spectrometer  Settings: No

Modified Flame Settings: No
    Read Time  (sec):  1.0
    Read Delay (sec):  0.0

    Flame Type: Air/C2H2
    Oxidant Flow  (L/min): 10.0
    Fuel Flow  (L/min):  2.0
Calibration
Equations,  Units,  and Replicates:
Element Calibration Equation
Ni Linear, Zero Intercept
Replicates :

Calib.Std.
Calib.Std.
Calib.Std.
Calib.Std.
Calib.Std.
Autos ampler
Tray Type:
Wash
Fixed

1
2
3
4
5
Setup
Tray F

: 3

CAL
cal
cal
cal
cal




ID
STD
std
std
std
std






2
3
4
5



Frequency:  Never
Duration:  1
Calibration  Sample
   Units     Units
                                          mg/L
             mg/L
       Max       Max
     Decimal  Significant
      Places    Figures
        4          4
                                   Cone.  (
         mg/L)
          0.25
          0.50
          1.00
          2.00
          5.00
A/S Loc
                                           Location of Wash Solution:  0
Checks
Check correlation coefficient?
Recalibrate instrument periodically?

Analyze standards  at end of run? . •- .

Check Precision?  	
       .No

       .No

       .No

       .No
Reanalyze samples beyond calibration range? ....No

Perform matrix check calculations? 	No
                                         Page 53

-------
Quality Control
Concentration Units: Calibration (   mg/L)

Periodic Timing of Analyses
Count: Samples                                    Interrupt  sample to analyze QC: No
Frequency: Same for all QC's, 1

Maximum Retries After QC Failure
Maximum allowed reanalyses:  1               Action when maximum exceeded: Continue
Options
Results Display/Printed Log - Modified Settings:  Yes
Method Header
Method Name   Element   Method Description
Date   Technique   Wavelength   Lamp Current    Sample  Info File Name   Calibration Equation
  Slit Width   Energy   Results Data Set  Name
Results Header
Element   Sequence Number   Autosampler Location   Date
Sample ID
Column Headings
Concentration Data:  Cone.  - Sample  Units    Cone. - Calibration Units
Absorbance Data:  Blank Corrected Signal    Peak Area   Bkgnd. Peak Area
Additional Parameters:  Time
Data Categories
Data: Replicate Data   Mean Data   Statistics
Peaks: Last Replicates
Summary:  Calibration Curve  Calibration Summary

Peaks to  Save:  None
                                         Page 54

-------
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-------
PROJECT # 080033:  METHOD 29 FOR NICKEL

date:  11/01/05



  1   Method Detection Limit for Flame AA of Nickel:             0.075 mg/L


               This MDL is calculated as per40CFR Part 136, Appendix B.





  2   Detection for Impinger sample:                           0.004 mg Ni


               0.075 mg/L X "AF 2A" mis X "Initial Sample Volume" mis / "SF 2A" mis X 1 L /1000 mis


                                  MLS OF
                        FINAL MLS   ORIGINAL          CONVERSION TO
                  MDL     (AF2A)    SAMPLE    MLS USED    "MG NI"
                 0.075     50      300       300      0.001      0.0038


               Although the actual mis of "original sample" varied, the volume used is that which will yield the

               highest value for the MDL.





  2   Detection for filter & probe rinse sample:                   0.007 mg Ni


               0.075 mg/L X "AF 1A" mis X "Sample Volume" mis / "SF 1" mis X  1 L /1000 mis


                                 MLS OF
                        FINAL MLS   ORIGINAL           CONVERSION TO
                 MDL     (AF1A)    SAMPLE    MLS USED    "MG NI"

                 0.075     100     10°       100      0.001      0.0075
                                 (+ 1 filter)





 3   Detection for TOTAL RUN sample:                         0.011 mg Ni


              = Impinger + filter & probe rinse

-------
               Appendix F



Laboratory QA/QC Data for Ambient Air Samples

-------
 PROJECT # 100016:   METHOD  121 FOR NICKEL
AIR FILTER CASSETTES
Digestion on 10/4/05
BY ICP ON 10/5/05
 IDL -
LOD =
MDL =
                                                   0.004
                                                   0.008
                                                   0.007
LOQ •    0.017
 RL =     0.050
      (All DL in mg/L)
 DATA:
Sample #
LRB
LFB
100016-1
100016-2
100016-3
100016-4
100016-5
100016-6
100016-7
100016-8
100016-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
0.211
4.01
0.092
0.107
0.012
0.012
0.044
0.029
0.017
0.015
-•• ' aooi : if
                                          •MDL of 0.007 mg/L & > RL of 0.05 mg/L

                                          = 100 X4.01/-4.0 = 100% Recovery, so okay
                                          = FLAG "B"
                                           13  10
                                           13   5>
                                          ap N*
                                          20  S
                                           =0.006
EXPLANATIONS:
                Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
                process were added, no filter.
                Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
                digestion process, again, no filter.
                25 ml class A volumetric flask was used to measure the final volume.
                mg/L as determined by average of three replicates on ICP.
                The result is over the detection limits as quantified for nickel. Therefore the result may
                be significant and must be "flagged" to indicate that it may be a false positive "hit", as
                occurred in the LRB.
  LRB =
  LFB =
DILUTION =
READING =
FLAG "B" =
I BORDER TO FACILITATE FURTHER CALCULATIONS, IF A RE'ADINQ^IS 
-------
Laboratory Work Order Report

LlMSNo.       2005100016   Date Rec'd 10/03/2005 02:37:49   Date Due   10/03/2005 12:00:00 AM
Project Code       .NULL  Customer No. SCICON         Client Type: REGULAR
Client Name   SCIENTIFIC CONTROL LABS
             3158S. KOLINAVE.
             CHICAGO                 IL    60623

Phone     254-2406         Fax  254-6661        Contact MR. FRANK ALTMAYER
Matrix     Engineering       Po No. -0-                    e-mail
                                                                   Quoted Price:  .NULL.
Client Notes: -o-
Order Comments:   .NULL.
                  .NULL
  Sample No.    Comments      Test Code   Description                         Date Received       Result
.NULL.
        1    09/27/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - NORTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        2    09/27/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - SOUTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        3    09/28/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - NORTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        4    09/28/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - SOUTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        5    09/29/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - NORTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        6    09/29/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - SOUTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        7    09/30/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - NORTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        8    09/30/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - SOUTH 10/03/2005 08:30:00 AM
                        Nl           NICKEL
        9    09/30/2005   WATTS NICKEL BARREL - ARTISTIC  PLATING - BLANK 10/03/2005 08:30:00 AM
                        Nl           NICKEL
 Page 1

-------
MFTALS   PREP   FORM
                                                          Set#
Prep Method:    (check only one per page)
   ICP/FLAA: SM 3030 F, EPA 200.7 '82
   ICP/FLAA: EPA 200's, SW-846 301OA
   ICP/FLAA: EPA 200.7 r4.4
   ICP/FLAA: SW-846 3005A
   ICP/FLAA: SW-846 3015A MICROWAVE
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:    	
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S\QA FORMS \FM-041 \R02 \LK
                                                                    Page 1 of 1

-------
                          Sample Information Detail Report
                          Document Name: 100505-2
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
100505-2
mL
9
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Sample Prep. Vol.

















                                              Sample ID
                                              ccv 0.50
                                              ccb
                                              Ifb
                                              Irb
                                              100016-1
                                              100016-2
                                              100016-3
                                              100016-4
                                              100016-5
                                              ccv 100
                                              ccb
                                              100016-6
                                              100016-7
                                              100016-8
                                              100016-9
                                              ccv 2
                                              ccb

                                              Aliquot Volume
                                                                                Initial Sample Wt.
                                              Diluted To Vol.

-------
                                                Page
                                                                           Date: 10/5/2005 1:55:54  PM
Analysis Begun

Jtart Time: 10/5/2005 1:42:39 PM                  Plasma On Time: 10/5/2005 10:43:51 AM
Logged In Analyst: sainmy                          Technique:  ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

Sample Information File: C:\pe\sammy\Sample Information\100505-2.sif
Batch ID: 100505-2
Results Data Set: 100505-2
Results Library: C:\pe\sammy\Results\Results.mdb


Secnience No  • 1                                   Autosampler Location:  0
£££mf CalL Blank 1                          Date Collected: 10/5/2005 1:42:39 PM
Analyst:                                          Data *****  ^^^
initial Sample Wt:                                Initial  Sample Vol:
Dilution.:                                         Sample Prep Vol:


Mean Data: Calib Blank 1
                   Mean Corrected                               Califc
Analyte               Intensity       Std.Dev.   RSD       Cone. Units
Yfo 328 937           2712250.8      12408.72    0-46%        10.0 mg/l
Ni 231.604t             -114.0          1.31    1.15%       [0.00] mg/L


         ,,   . o                                   Autosampler Location:  1
        D- Cal 21+7 1 00                          Date Collected:  10/5/2005 1:46:19 PM
Analyst:  '                                        Data Type:  Original
Initial Sample Wt:                                Initial  Sample Vol:
Dilution:                                         Sample Prep Vol:


ISfean Data: Cal 21+7 1.00
                   Mean Congested                                CaUD
Analvte               Intensity       Std.Dev.   RSD        Cone. Units
Yb 328.937           2688576.1         311.76    0.01%         9.91 mg/L
Hi 231.604t             7346.8          26.28    0-36%       [1-00] mg/1


Calibration  Summary





         „   . 3                                   Autosampler Location: 9
Sample ID: cev  0.50                               Date Collected:  10/5/2005 1:49:40 PM
Analyst:                                          Data_Type:  Original
Initial  Sample Wt:                                 Initial Sample Vol:
Dilution:                                          Sample Prep Vol:


Mean Data:  ccvO.50                                        i [) i  tv    --  „ „„,_
                   Mean Corrected          Calib          '                Sample
jfcnalyte                Intensity      Cone. Units      Std.Dev.      Cone. Units       Std.Dev.
Yb  328.937            2709630.5         9,99 mg/L         0.019
Ni  231 604t              -a-joji •>        n ^n4 -mrr/T,        0.0047       0.504 ma/I,         u.uu^/
Analyst:
Initial Sample Wt:
Dilution:
                                                   Data Type: Original
                                                   Initial Sample Vol:
                                                   Sample Prep Vol:
 fean Data: ccfa

-------
                                                                           Date:  10/5/2005  2:14:46 PM
Method: Axr Fxxrer jsx 	
Mean Corrected
Analyte Intensity
Yb 328.937 2721073.2
.1 231.604t -3.3 (
Sequence No . : 5
Sample ' ** : 1S5
Analyst:
Initial Sample Wt:
Dilution.:
Mean Corrected
Analyte Intensity
Yb 328.937 2595058.7
Ni 231.604t 29476.3
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: Irb
Mean Corrected
Analyte Intensity
sx
Sequence No, : 7
Sample ID: 100016—1
inalyst:
Initial Sample Wt:
Dilution:
Mean Data: 100016-1
Mean Corrected
Analyte Intensity
Yb 328.937 2685211.6
Ni 231.6G4t 676.2
Sequence No . : 8
Sample ID: 100016-2
Analyst :
Initial Sample Wt:
Dilution:
Mean Data: 100016-2
Mean Corrected
Analyte Intensity
Yfa 328.937 2655450.5
Ni 231.604t 786.3
Sequence No . : 9
Sample ID: 100016-3
Analyst :
Initial Sample Wt:
Dilution:
Calib
Cone. Units
„, 10 . 0"ing/I,
" 0.000 mg/L

Calib
Cone. Units
9.57 mg/L
4.01 mg/L

, cisnc- Units
^ * — "*

Calib
Cone. Units
9.90 mg/L
0.092 mg/L

Calib
Cone- Units
9.79 rag/!
0.107 mg/L

--- • / _~ i- c" -"" ' Sample
Std Dev. Cone. Units Std.Dev. RSD
0.03 °-25%
0.0008 0.000 iug/L 0.0008 186.43%
Autosampler Location: 11
Date Collected: 10/5/2005 1:56:52 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Std.Bev. Cone. Units Std.Dev. RSD^
0.059 0.61%
0.016 4.01 mg/L 0.016 0.39%
Autosampler Location: 12
Date Collected: 10/5/2005 2:00:15 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
	 	 -/--/• 	 £r 	 U
>.c^7; .5* M«* /^/)™j^// S&jt4r^'
Std Dev. Cone. Units Std.Dev. RSD
0.069 °-72%
Autosampler Location: 13
Date Collected: 10/5/2O05 2:04:07 PM
Initial Sample Vol:
Sample Prep Vol:
Sample
Std Dev. Cone. Units Std.Dev. RSD
0.041 °-42%
0.0013 0.092 mg/L 0.0013 1.38%
Autosampler Location: 14
Date Collected: 10/5/2O05 2:07:59 PM
Data Type : Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev. RSD
0.093 0.95%
0.0003 0.107 mg/L 0.0003 0.25%
Autosampler Location: 15
Date Collected: 10/5 /2O05 2:11:52 PM
Data Type : Original
Initial Sample Vol:
Sample Prep Vol:
yfean Data: 100016-3

-------
                                                 Page
                                                                            Date: 10/5/2005 2:33:50  EM
Analyte
Trs 328.937
 ri 231.604t
Mean Corrected
   Intensity
  2667898.3
       84.9
      Calir.
Cone. Units
 9.84 mg/L
0.012 mg/1
Std.Dev.
  0.056
 0.0003
      Sample
Cone. Units

0.012 mg/L
Std.Dev.

 0.0003
 USD
0.57%
2.63%
         „   . IQ                                   Autosanpler Location: 16
        D- 100016-4                                Bate Collected: 10/5/2005 2:15:45 PM
Analyst:  "                                         Data Type: Original
Initial Sample Wt:                                 Initial Sample Vol:
Dilution:                                          Sanple Prep Vol:


Mean Data: 100016-4
                   Mean Corrected          Calii>                          Sample
Analyte                Intensity      Cone. Units      St^D^"      C™C' *"*•**       Std-Dev"   Q^%




                                                       sampler Location: 17
                                                        Collected^ 10/5/2005 2 ;19:40 EM

Analyst:                                           Bata        - "  '  "
Initial Sample Wt:                                 Initial Sanple
Dilution:                                          San9?le Prep Vol:


Mean Data: 100016-5
                   Mean Corrected          Calib                          Sanple
Analyte                Intensity      Cone. Units      Std.Dev.      Cone. Units       Std.Dev.    BSD
vs..  -As era-?            ?7195>15 1        10.0 mcr/L          0-05                                   0.3^
SS^SIt               3,21:2       0.044^/L        0-0004       0.044mg/X,        0.0004   1.00^


          „  , 12                                  Autosan5>ler Location: 18
         D: cev  1.00                                Bate Collected: 10/5/2005 2:23:34 PM
 Analyst:  '                                         Data "?!&>&'• Original
 Initial  Sanple  Wt:                                 Initial Sanple  Vol:
Dilution:                                         Sample Prep Vol:


M^~Data"cw~l~00                                  Y^'^To
                   Mean Corrected          Calib                    '      Sanple
Analyte                Intensity      Cone. Units      Std.Dev.      Cone. Units       Std.Dev.    KSD
 Xb  328.937           2720862.6        10.0 mg/L          "  na                                   u-^
Mi  23l!604t              7350.6        1.00 mg/I,




Analyst:    °                                      Bata. Type: Original
 Initial  Sanple  Wt:                                 Initial Sanple Vol:
Dilution:                                         Sanple Prep Vol:


Mean Data:  ccb                                                     '     J
                   Mean Corrected          Calib                           Sanple
Analyte               Intensity      Cone. Units      St
-------
Method: Air Filter Hi
                                                 Page   4
                                                                            Date: 10/5/2005 2:52:54
                                                       0.00?'
                                                                                       0.0=!,   3.67,
        ,T    ., t-
               Wt:
Dilution:
                                                   Autosaimler Location: 21
                                                        Seated: 10/5/2005 2:34:51
                                                   Data
                                                                  Vol:
Mean Data:  100016-7
                                                                                      SM.o.v.
         „    ic
           ioOO-16-8
                                                   Autosaiupler Location: 22
                                                   Bate SSleoted: 10/5/20O5 2:33:47
               Wt:
Dilution:
                                                   Initial Sa^le Vol :
                                                   San^le Prep Vol:
ifean Data:  100016-8
                    Mean Corrected
                                            Calib
                                                                            c^mnle
                                                                            Sample
                                      00=0.
Analvst-
initial Sanple Wt:
Dilution:
                                                                     ».015mg/X
                                                   Initial Sanrole Vol:
                                                   Sample Erep Vol:
                                                                                        0.00
                                                                                                 ,.«
 Mean Data: 100016-9
ifean Corrected.
   xntensity
      Calib
Cone. Units
                                                       Std.Dev.
                                                                     Cone. ITnxts

                                                                                                  KSD%

                                                                                        0.0007 133,70%
a ~,-,^s,^> -an  -  ifi
           cri
Analvst-
Initial Sanple Wt:
Dilution:
                                                   &utasan5>ler Location: 24
                                                   Bate Sleoted:  10/5/2005 2:46:41
                                                   Dafca !E^S:  Origxnax
                                                   Initial  Sairple Vol:
                                                   Sainple Prep Vol:
Analyte
Yfo 328.937
Hi 231.604t
Mean Corrected
Intensity
2760845.2
189.4
Cone.
10.2
0.026
Calib ' S" Sanple
Units Std-Dersr. Cone. Uaits
rag/I, 0.04
mg/L 0.0005 0.026 mg/L
Std-Dev.
0.0005
RSD
0.40%
1.98%
    . yst:
 initial Sample Wt:
 Dilution:
                                                    Autosanyler location: 25
                                                    Bate Collected: 10/5/2005 2:5O:32 PM
                                                    Bata Type:  Original
                                                    Initial Sample Vol:
                                                    Sample Prep Vol:
 Mean Data: ccv 2

-------
Page
                          Date: 10/5/2005 2:56:52 EM
Method: Air Fxiter
Analyte
Yb 328.937
:i 231.604t
•kT Orf">
Secnienoe i^o. . j£u
Sample ID: eeb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: cob
analyte
Yb 328.931
Hi 231.604t
Nl
Mean Corrected
Intensity
2690135.1
14725.9
Calit
Cone. Units
9.92 mg/i
2.00 mg/L
Std.Dev. Cone.
0.018
0.013 2.00
Sample
Units
mg/L
Std.Dev. RSD
0.18%
0.013 0.65%
Axitosamoler Location: 26
Date Collected: 10/5/2005 2:53:52 iM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Corrected
Intensity
2710743.7
-0.8
Calib
Cone- Units
( 0.000 mg/L
Std..Dev. Cone.
0 . 053
0.0006 0.000
e t> kJv]
Sample /
Units
mg/L
Std.Dev. BSD
0.53%
0.0006 565.021
                                   1C,

-------
PROJECT # 100305:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/7/05
BY ICP ON 11/9/05
                                          IDL =
                                          LOD =
                                          MDL •
                                                    0.004
                                                    0.008
                                                    0.007
LOQ =    0.017

 RL =     0.050
      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
100305-1
100305-2
100305-3
100305-4
100305-5
100305-6
100305-7
100305-8
100305-9
100305-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.005
1.00
7.28
0.914
0.085
0.16
'^005, ;?;'
5.83
0.174
6.90
0.433

                                         :MDL of 0.007 mg/L          =0.006


                                         = 100 x 1.00/1.00 = 100% Recovery, ( 80-120%)
                                          = 0.006
                                          = 0.006
     LRB =
EXPLANATIONS:
                Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
                process were added, no filter.
                Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
     LFB =      digestion process, again, no filter.
  DILUTION =    25 ml class A volumetric flask was used to measure the final volume.
  READING =    mg/L as determined by average of three replicates on ICP.

IttORBERTQ FACILITATEF&RTHER^CSLQPLATIOI^S, IF A READING,IS 
-------
Laboratory Work Order Report
LIMSNo.      2005100305  Date Rec'd 10/21/2005 01:55:38   Date Due   10/21/2005 12:00:00 AM
Project Code        .NULL.  Customer No.  SCICON          Client Type: REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLIN AVE.
             CHICAGOIL     60623
Phone    254-2406
Matrix    Engineering

Client Notes: -o-

Order Comments:   .NULL
                  .NULL.
  Sample No.    Comments
.NULL
        1   10/17/2005

        2   10/17/2005

        3   10/18/2005

        4   10/18/2005

        5   10/18/2005

        6   10/19/2005

        7   10/19/2005

        8   10/20/2005

        9   10/20/2005

        10   10/20/2005
   Fax  254-6661
   PoNo.  -0-
Contact MR. FRANK ALTMAYER
         e-mail
                      Quoted Price:  .NULL.
     Test Code   Description


10/17/05 ARTISTIC WOODS EAST #27
 Nl            NICKEL
10/17/05 ARTISTIC WOODS WEST #27
 Nl            NICKEL
10/18/05 ELITE SULFAMATE NORTH #22
 Nl            NICKEL
10/18/05 ELITE SULFAMATE SOUTH #22
 Nl            NICKEL
10/18/05 ELITE-BLANK
 Nl            NICKEL
10/19/05 ARTISTIC WOODS EAST #28
 Nl            NICKEL
10/19/05 ARTISTIC WOODS WEST #28
 Nl            NICKEL
10/20/05 ARTISTIC WOODS EAST #29
 Nl            NICKEL
10/20/05 ARTISTIC WOODS WEST #29
 Nl            NICKEL
10/20/05 ARTISTIC - BLANK
 Nl            NICKEL
                          Date Received
Result
                          10/21/200504:30:00 PM
                          10/21/2005 04:30:00 PM
                          10/21/2005 04:30:00 PM
                          10/21/2005 04:30:00 PM
                          10/21/200504:30:00 PM
                          10/21/200504:30:00 PM
                          10/21/200504:30:00 PM
                          10/21/200504:30:00 PM
                          10/21/200504:30:00 PM
                          10/21/2005 04:30:00 PM
  Page 1

-------
Prep Method "      {check only one per page)
                                                                                                 Set





ICP/FLAA:
ICP/FLAA:
1C
lu
l<~
0"
P/FLAA:
P/FLAA:
P/FLAA:
FHER:
SM 3030 F, EPA 200.7 '82
EPA 200's, SW-846 301 OA
EPA 200.7 r4.4
SW-846 3005A
SW-846 301 5A MICROWAVE





GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A

GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
DTHFR:

MATRIX: (check only one per page)

n




1


9
B
4
5
6
7
8
9
10
11
1?

RINK1NG WATER
Set
Inif!

>


















f
J




Set
date
/;
/r
j






1







I
\/
I
V




Set
time
JO*











v




Lab#


l003.o^>
/







-*>






/
/
	 ^ 	






AQUEOUS
. fr~*^\ "
fat r$^
/ /./7/)

J*y /(sir
^
or
OTHER:
1 	 ' *•• \
Smp #


I
^
3
i/
•/r

7

-------
Sample Information Detail Report
Document Name: 110905-1
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
        110905-1
        ml
        g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22

Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

Sample Prep. Vol.
                   Sample ID
                   cri
                   icsab
                   ccv 1.00
                   ccb
                   Ifb
                   Irb
                   100305-1
                   100305-2
                   100305-3
                   100305-4
                   ccv 0.50
                   ccb
                   100305-5
                   100305-6
                   100305-7
                   100305-8
                   100305-9
                   100305-10
                   cri
                   icsab
                   ccv 2.00
                   ccb

                   Aliquot Volume
                                                     Initial Sample Wt.
                                                                               Diluted To Vol.

-------
 Analysis Begun

 Start Time: 11/9/2005 4:45:12 EM                  Plasma On Time: 11/9/2005 4:03:48 EM
 ,ogged In Analyst: sammy             .             Technique: ICP Continuous
 Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

 Sample Information File: C:\pe\sammy\Sample Information\Untitled.SIF
 Batch ID: 1.10905-1
 Results Bata Set:
 Results Library:
Method Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
 Sequence No.:  1
 Sample  ID:  Calib Blank
 Analyst:
 Initial Sample Wt:
 Dilution:
Method Last  Saved:  10/14/2005  11:13:33 AM
MSF File:
Autosampler Location:
Date Collected: 11/9/2005  4:45:12 EM
Data Type: Original
Initial  Sample Vol:
Sample Prep Vol:
Replicate Data: Calib Blank 1
Net
Repl# Analyte Intensity
1 Mn 257
1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.610
.752
.610
.752
.610
.752
aan Data: Calib
Analyte
Mn 257.610
Cu 324.752



-175
2107
-178
2077
-207
2099
Blank 1
Mean Corrected
Intensity
-187.0
2094.8
.3
.5
.1
.8
.6
.3




Corrected
Intensity
-175
2107
-178
2077
-207
2099

Std.Dev.
17.86
15.33
.3
.5
.1
.8
.6
.3

RSD
9.55%
0.73%
Cone.
[0
[0
[0
[0
[0
[0

-UUJ
.00]
.00]
.00]
.00]
.00]

Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Calib
Analysis
Time
16:
16:
16:
16:
16:
16:

:4b
:46
;46
:46
:46
:46

:37
:37
:47
:47
:57
:57

Cone. Units


[0
[0
.00] mg/L
.00] mg/L






Sequence No.:  2
Sample ID: Calb  Stdl
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 11/9/2005 4:47:36 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data:
Repl# Analyte
1 Mn 257
1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.610
.752
.610
.752
.610
.752
Mean Data: Calb

Analyte
Mn 257. 610
Cu 324.752




Calb Stdl
Net
Corrected
Intensity
592478.
201806.
592218.
201681.
595484.
202609.
Stdl
Mean Corrected
Intensity
'593580. 6
199937.6
6
3
1
9
1
0





Intensity
592665
199711
592405
199587
595671
200514


Std.Dev.
1815.10
503.20
.5
.5
.1
.0
.1
.1


RSD
0.31%
0.25%
Cone.
[5.
[5.
[5.
[5.
[5.
[5.


00]
00]
00]
00]
00]
00]


Calib .
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

Calib
Analysis
Time
16:
16:
16:
16:
16:
16:


48:
48:
48:
48:
49:
49:


47
47
58
58
10
10
\._

Cone . Units


[5
[5
.00] mg/L
.00] mg/L







-------
         Pt-MiiB3C
page
Calibration Summary
Analyte
Mn
Cu
257.610
324.752
Stds.
1
1
Equation
Lin
Lin
Thru 0
Thru 0
Intercept
0.0
0.0
Slope
118700
39990
Curvature
0,
0.
.00000
.00000
Corr
1.
1.
. Coef.
000000
000000
Reslope


 Sequence No. :  3
 Sample ID:  bee
 Analyst:
 Initial Sample Wt:
 Dilution:
  Autosarnpler location:
  Date Collected: 11/9/2005 4:49:49 EM
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
Replicate Data: bee
Net Corrected
Repl# Analyte
1 Mn 257.610





1 Cu 324
2 Mn 257
2 Cu 324
3 Mn 257
3 Cu 324
.752
.610
.752
.610
.752
Intensity Intensity
0.3 187.3
0.7 -2094.
-0.1 186.
0.0 -2094.
-0.6 186.
-0.3 -2095.
Mean Data: bee r\V-" ^



Analvte
Mn
Cu
257.610
324.752


Mean Corrected J^-p^^Cali
2
9
8
4
1
'- £).
b
Intensity /Conc^ Units
186.9 ,' 0.002 mg/L
-2094.7 \-0.052 n(g/L


Cone.
0.002
-0.
0.
-0.
' 0.
-0.
.eg

Std
0.
0.
052
002
052
002
052


Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L


.Dev.
0000
0000


Cone.
0.002
-0.052
0.002
-0.052
0.002
-0.052

Sample
Cone. Units
0.002 mg/L
-0.052 mg/L
Sample Analysis
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L


Std. Dev
0.0000
0.0000
Time
16:50:'48
16:
16:
16:
16:
16:


.


50:48
51:08
51:08
51:28
51:28


RSD
0.26%
0.02%
Method Loaded
Method Name:  Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
Sequence No.:  4
Sample H>: cv
Analy s t:
Initial Sair^le Wt:
Dilution:
 Method Last Saved: 10/14/2005 11:13:33 AM
 MSF File:
 Autosampler Location:
 Date Collected:  11/9/2005 4:52:12 PM
 Data Type:  Original
 Initial Sample Vol:
 Sample Prep Vol:
Replicate Data: cv
Kepl# Analyte
1
I
2
2
3
3
4
4
5
5
6
6
7
7
8
8
9
9
•10
10
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
Cu 324.
Mn 257.
: Cu 324.
610
752
610
752
610
752
610
752
610 -"
752
610
752
610
752
610
752
610
752
610
752
Net
Corrected
Intensity
598424
204294
604424
206239
599957
204630
598337
203877
598531
203915
602386
205170
. 605520
206320
602017
205280
604689
205928
603873
206148
.2
.3
.9
.9
.0
.5
.2
.4
.9
.2
.3
.2
.2
.2
.7
.4
.8
.7
.9
.4
Intensity
598611
202199
' 604611
204145
600144
202535
598524
201782
598718
201820
602573
203075
605707
204225
602204
203185
604876
203833
604060
204053
.2
.5
.9
.1
.0
.7
.2
.5
.9
.3
.3
.4
.2 .
.4
.7
.5
.8
.9
.9
.5
Cone .
5.04
5.06
5.09
5.11
5.06
5.06
5.04
5.05
5.04
5.05
5.08
5.08
5.10
5.11
5.07
5.08
5.10
5.10
5.09
5.10
Calib.
Units
mg/L •
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

Sample
Cone. Units
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
.04 mg/L
. 06 mg/L
.09 mg/L
.11 mg/L
. 0 6 mg/L
. 0 6 mg/L
.04 mg/L
.05 mg/L
. 0 4 mg/L
. 05 mg/L
. 08 mg/L
. 08 mg/L .
. 10 mg/L
.11 mg/L
. 07 mg/L
-.08 mg/L
. 10 mg/L
.10 mg/L
. 09 mg/L
.10 mg/L
Analysis
Time
16:53:23
16:53:23
16:53:34
<16:53:34
16:53:46
16:53:46
16:53:57
16:53:57
16:54:09
16:54:09
16:54:20
16:54:20
16:54:32
16:54:32
16:54:44
16:54:44
16:54:55
16:54:55
16:55: 07
.16:55:07

-------
Method:  ?t-Mn3SC	Page   3	Date:  11/9/2005 4:55:12 BM

Mean Data:  crv                                                                                     ...
                    Mean Corrected           Calib                          Sample                 ^-^'"'-^
Analvte                Intensity      Cone,  Units      Std.Dev.      Cone. Units       Std.Dev.  /RSD\ !
Mn 257.610             602003.3         5.07  mg/1         0.024        5.07 mg/1          0.024 /  0.47%\/
Cu 324.752             203085.7         5.08mg/I         0.024        5.08mg/L          0.024/   0.47%|

-------
Method: Air Filter Ni
                                                Page
                                                                           Date: 11/9/2005 5:11:01 PM_
Analysis Begun

Start Time- 11/9/2005 5:01:10 PM                  Plasma On Time: 11/9/2005 4:03:48 PM
Logged S Analyst: sam^                          Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001AutoSampler Model: AS-91

Sample Information File: C:\pe\sammy\Sample Information\110905-1.sif
Batch ID: 110905-1
Results Data Set: 110905-1
Results Library: C:\pe\sammy\Results\Results.mdb
Method Loaded
Method Name: Air Filter Ni
IEC File:
Method Description: AIR FILTER Ni
Sequence No. : 1
Sample ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
             Method Last Saved:  10/5/2005 1:33:13 PM
             MSF File:
             Autosampler Location:  0
             Date Collected:  11/9/2005 5:01:10 PM
             Data Type:  Original
             Initial Sample Vol:
             Sample Prep Vol:
Mean Data: Calib Blank 1
                   Mean Corrected
Analyte               Intensity
Yb 328.937           2065904.8
Ni 231.604t             -156.0
Std.Dev.    RSD
 452.16   0.02%
   9.33   5.!
       Calib
 Cone.  Units
  10.0  mg/L
[0.00]  mg/L
Sequence No.: 2
Sample ID: Cal 21+7 1.00
 Vnalyst:
Initial Sample Wt:
Dilution:
             Autosampler Location: 1
             Date Collected: 11/9/2005 5:04:19 EM
             Data Type: Original
             Initial Sample Vol:
             Sample Prep Vol:
Mean Data: Cal 21+7 1.00
Mean Corrected
Analyte
Yb 328.937
Ni 231.604t
Calibration Summary
Analyte Stds.
Ni 231.604 1
Intensity
2033238.9
6243.7

Equation
Lin Thru 0
Calib
Std.Dev. RSD Cone. Units
6742.11 0.33% 9-84 mg/L
22.77 0.36% [1.00] mg/L

Intercept Slope Curvature
0.0 6244 0.00000


y .413
Corr. Coef. / Reslope
1.000000 /
V t>VL
Sequence No.: 3
Sample ID:  cri
Analyst:
Initial Sample Wt:
Dilution:
             Autosampler Location: 9
             Date Collected: 11/9/2005 5:07:40 PM
             Data Type: Original
             Initial Sample Vol:
             Sample Prep Vol:
Mean Data: cri
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2096613.2
153.3
Calib
Cone . Units
10.1 mg/L /
0.025 mg/L J
|-80 *! •
Std.Dev.
0.02
0.0028
Sample
Cone . Units
0.025 mg/L
Std.Dev. RSD
0.21%
0.0028 11.36%
Sequence No.:  4
 Jample ID:  icsab
             Autosampler Location: 10
             Date Collected: 11/9/2005  5:11:01 PM

-------
                                                                          Date: 11/9/2005 5:27:51 EM
Method: Air Filte
Analyst :
Initial Sample Wt
Dilution:
Mean Data: iosab
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 5
Sample ID : ccv 1 .
Analyst :
Initial Sample Wt
Dilution:
Mean Data : ccv 1 .
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 6
Sample ID : cob
Analyst:
Initial Sample "Wt
Dilution:
Mean Data: cob
Analyte
¥b 328.937
Ni 231.604t
Sequence No . : 7
Sample ID: Ifb /ft
Analyst: ^
Initial Sample Wt
Dilution:
Mean Data: Ifb
Analyte
yb 328.937
Ni 231.604t
Sequence No. : 8
Sample ID: Irb
Analyst:
Initial Sample Wt
Dilution:
Mean Data: Irb
Analyte
Yb 328.937
Ni 231.604t
r JMX
Mean Corrected
Intensity
2022975.1
6186.9
00
00
Mean Corrected
Intensity
2126757.0
6260.5
:
Mean Corrected
Intensity
2263307.5
10.9
I.* tf«
Mean Corrected
Intensity
1812066.7
6268.5
:
Mean Corrected
Intensity
1839953.4
-31.0

Calib
Cone . Units
9.79 mg/L
0.991 mg/L

Calib
Cone. Units
10.3 mg/L
1.00 mg/L

Calib
Cone. Units
11.0 mg/L
0.002 mg/L

Calib
Cone. Units
8.77 mg/L
1.00 mg/L

Calib
Cone . Units
8.91 mg/L
-0.005 mg/L
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
/)fl*j, \tf" ^
f/t"3 Sample
Std.Dev. Cone. Units
0.076
0.0114 0.991 mg/L
Autosampler Location: 11
Date Collected: 11/9/2005 5:14:22
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
JY_ / 	
""joo^o ^ **~'
Sample
Std.Dev. Cone. Units
0.10
0.006 1.00 mg/L
Autosampler Location: 12
Date Collected: 11/9/2005 5:17:43
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/ ©o 7 piA
X' Sample
Std.Dev. Cone. Units
0.67
0.0035 0.002 mg/L
Autosampler Location: 13
Date Collected: 11/9/2005 5:21:06
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
lf)0*le $-£<& Dtf- •
1 Sample
Std.Dev. Cone. Units
0.072
0.009 1-00 mg/L
Autosampler Location: 14
Date Collected: 11/9/2005 5:24:28
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/^€>t ^
Sample
Std.Dev. Cone. Units
0.042
0.0025 -0.005 mg/L

Std.Dev. RSD
0.78%
0.0114 1.15%
PM
Std.Dev. RSD
0.94%
0.006 0.57%
PM
Std.Dev. RSD
6.10%
0.0035 202.41%
PM
Std.Dev. RSD
0.82%
0.009 0.90%
PM
Std.Dev. RSD
0.47%
0.0025 50.97%
Sequence No. :  9
Sample ID: 100305-1
Autosampler Location: 15
Date Collected: 11/9/2005 5:27:51 EM

-------
Method: Air Filter Ni
                                            Page
                                                                    Date: 11/9/2005 5:44:54 EM
Analyst:
Initial  Sample Wt:
Dilution:
                                              Data Type:  Original
                                              Initial Sample Vol :
                                              Sample Prep Vol:
Mean Data: 100305-1                                                   Samole
^^          -^SSS"    «- 2£      «j.s.      c»c..5L     ««-.   -%

Sf!J:SIt         "SSi:S        ?:»SS        S:JS       —  „«        o.o6S   „.».

a ~  ~~<= w>, •  l n                               Autosampler Location: 16
Sle ?of i.00305-2                             Dat. Collected: 11/9/2005 5:31:15 PM
Analvst-                                       Data "^^ O^111*1
^tlal'sample Wt:                              Initial Sample Vol:
Dilution:                                      Sa^le Pre*> Vo1:

Mean Data: 100305-2                                                   csamnle
                 Mean Corrected         Calob                        Sample
^yte             intensity     Cone Units      Std.Dev.      Cone.  Unxts     Std.Dev.   QRSD%
Yb 328 937          1688961.9        8.18 mg/1        0.049
2 Sl^Mt            5709.8       0.914 mg/1       0.0080      0.914  mg/L        0.0080   0.88o

.,    ___ w_ .  11                               Autosampler Location: 17
SS^f £003^5-3                             Bate Elected: 11/9/2005 5:34:40 PM
Analvst-                                       Data Type: Original
Initial"Sample Wt:                              Initial Sample Vol:
Dilution:                                      Sa"3?le Pre*> Vol:

Mean Data: 100305-3                                                   Samole
^^          -^SS?4    =«=.£££      .««,.     c—^SS.     SM.,.V.    „

SS:SJ,         1719^-       o!iHSS       .?i»i      0-0.5^        ....37J..1.

c ^,,=^^<=. -wn •  19                               Autosampler Location: 18
SJe ?Df io03?5-4                             ^te Elected: 11/9/2005 5:38:04 PM
Analyst-                                       Data 'S^>e'- O^^^31
initial Sample Wt:                              Initial Sample Vol:
Dilution:                                      San9?le PreP Vol:

Mean Data: 100305-4                                                      n
                 Mean Corrected         Calib                        Sample
Analyte             Intensity     Cone. Units      Std.Dev.     Cone.  Units      Std.Dev.    RSD^
Yb 328.937          1691084.4        8.19 mg/1        0.086                       nnn9n   i"?7*
Ni 231.604t             998.8       0.160 mg/1       0.0020      0.160  mg/L        0.0020   1.27»

q^mie-nr'ff. No •  13                               Autosampler Location: 19
S?e ^f ^v 0 .50                             Date Collected: 11/9/2005 5:41:29 PM
Analyst:                                       Data Type: Original
Initial Sample Wt:                              Initial Sample Vol:
Dilution:                                      Sample Prep Vol:

	                  ^°              o   i ^.
                 Mean Corrected         Calib  1°'                   Sample
Analyte             Intensity     Cone. Units      Std-De-     C°nC'  UnltS      S^d.Dev.   RSD
SISlSJt         211360?7l       0^1 Sg       O.Sill      0.493mg/L        0.0191   al,


^^r~~~~~~~~^^^^^ —4 -

-------
   thod:
             Filt.
                   Ni
                                                Page
                                                                           Date: 11/9/2005  6:01:59 EM
Analyst:
Initial Sample Wt:
Dilution:
                                                  Data Type: Original
                                                  Initial  Sample Vol:
                                                  Sample Prep Vol:
Mean Data:  ccb                                    / , <9
-------
                                                                            Date:  11/9/2005 6:19:11 EM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 100305-9
Mean Corrected
Analyte Intensity
Yb 328.937 1721520.7
Ni 231.604t 2701.4
Sequence No . : 20
Sample ID: 100305-10
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: 100305-10
Mean Corrected
Analyte Intensity
Yb 328.937 1709132.1
Ni 231.604t -28.7
Sequence No . : 21 _
Sample ID: -oas- (_£-~U l^P^
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: cri
Mean Corrected
'to.alyte Intensity
b 328.937 2342720.9
Ni 231.604t 12526.7
Sequence No. : 22 -
Sample ID: •a-CSSB Cj£~-£7
Analyst:
Initial Sample Wt:
Dilution :
Mean Data: icsab
Mean Corrected
Analyte Intensity
Yb 328.937 2101020.0
Ni 231.604t 8.7

Sequence No. : 23 /
Sample, ID: ecv 2.,00 \. j I
Analyst.,: /'" /Me) 6a^£'tA-fx'
Initial SSample''wt: ' \ ,/ '/
Dilution:\ / feW
A V
Mean Data: ^-eejti2^©0 /"' (/
\Mean Corrected?!
Analyte \ Intensity \.
Yb 328'. 937 N2,5^333'64 . 6
Ni 231.604t / 24.1




Calib
Cone. Units
8 . 33 mg/L
0.433 mg/L





Calib
Cone. Units
8.27 mg/L
-0.005 mg/L





Calib
Cone. Units
11.3 mg/L
2.01 mg/L





Calib
Cone. Units
10.2 mg/L
0.001 mg/L


2,


K,
\ Calib
Corie. Units
x 12 . 3\mg/L
^ ••-• ^
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :

Sample
Std.Dev. Cone. Units
0.199
0.0113 0.433 mg/L
Autosampler Location: 26
Date Collected: 11/9/2005 6:05:17
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:

Sample
Std.Dev. Cone. Units
0.175
0.0018 -0.005 mg/L
Autosampler Location: 27
Date Collected: 11/9/2005 6:09:06
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
. ^ e*]_o i) £_, &^~
It/'-' ' i Sample
Std.Dev. Cone. Units
0.05
0.002 2.01 mg/L
Autosampler Location: 28
Date Collected: 11/9/2005 6:12:27
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
/ 0e?l 0^-'
^- " Sample
Std.Dev. Cone. Units
0.05
0. 0023 0.001 mg/L

Autosampler Location: 29
Date Collected: 11/9/2005 6:15:49
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:


Sample
' Std.Dev. Cone. Units
/ 0.18
0.0018 0.004 mg/L





Std.Dev. RSD
2.39%
0.0113 2.62%
PM





Std.Dev. RSD
2.12%
0.0018 40.10%
PM





Std.Dev. RSD
0.42%
0.002 0.12%
PM





Std.Dev. RSD
0. 46%
0.0023 165.21%
£,nj_ ®? ^UUA -
PM





Std.Dev. RSD
1.44%
0.0018 46.07%
"•equence No. :  24
 imple ID:  ccb
Autosampler Location: 30
Date Collected: 11/9/2005 6:19:11 PM

-------
PROJECT # 110200:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/14/05
BY ICP ON 11/15/05
                                         IDL =     0.004
                                         LOD a    0.008
                                         MDL =    0.007
LOQ =    0.017

 RL =     0.050

      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
110200-1
110200-2
110200-3
110200-4
110200-5
110200-6
110200-7
110200-8
110200-9
110200-10
Dilution
25
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.001
1.80
0.202
0.144
I". . o;po
-------
Laboratory Work Order Report
LIMSNo       2005110200  Date Rec'd 11/11/2005 03:40:03   Date Due   11/11/2005 12:00:00 AM
Project Code        .NULL  Customer No.  SCICON          Client Type: REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLINAVE.
             CHICAGO                  IL     60623
Phone
Matrix
254-2406
Engineering
Fax 254-6661
PoNo. iCh
Contact MR. FRANK ALTMAYER
e-mail
                                                                     Quoted Price:  NULL.
Client Notes: -o-

Order Comments:   .NULL
                  .NULL.
  Sample No.    Comments
.NULL
 1   11/07/2005



 2   11/07/2005

 3   11/07/2005

 4   11/08/2005

 5   11/08/2005

 6   11/09/2005

 7   11/09/2005

 8   11/09/2005

 9   11/10/2005

10   11/10/2005
     Test Code  Description


11/07/05 - ABQC - #14 EAST
 Nl            NICKEL

11/07/05 - ABQC - #14 WEST
 Nl            NICKEL
11/07/05-ABQC-BLANK
 Nl            NICKEL
11/08/05 - ABQC - #15 EAST
 Nl            NICKEL
11/08/05-ABQC-#15 WEST
 Nl            NICKEL
11/09/05 - ARTISTIC - #7 EAST
 Nl            NICKEL
11/09/05 - ARTISTIC - #7 WEST
 Nl            NICKEL
11/09/05 - ARTISTIC - BLANK
 Nl            NICKEL
11/10/05 - ARTISTIC - #24 - EAST
 Nl            NICKEL
11/10/05 - ARTISTIC - #24 - WEST
 Nl            NICKEL
                                                                Date Received
Result
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/200511:30:00 AM
                                                                         11/11/200511:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
                                                                         11/11/2005 11:30:00 AM
  Page 1

-------
PROJECT # 110077:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES
Digestion on 11/11/05
BY ICP ON 11/15/05
                                         IDL a     0.004

                                         LOD -    0.008

                                         MDL •    0.007
LOQ •   0.017

 RL =t    0.050

      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
110077-1
110077-2
110077-3
110077-4
110077-5
110077-6
110077-7
110077-8
110077-9
Dilution
25
25
25
25
25
25
25
25
25
25
25
Reading
-0.004
0.716
0.206
0.180
0.505
0.404
0.209
0.185
0.180
0.156
•' ' '|l 003 : '\
                                        l$, USED,
     LFB =
                                                                               11/16/05LK
                                                         S/ LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 121
                                                     X/ USEPA/ NICEIW PROJECT 21 Analytical data/ METHOD 121-2

-------
Laboratory Work Order Report
LlWlSNo       2005110077  Date Rec'd 11/03/2005 03:59:05    Date Due    11/03/2005 12:00:00 AM
Project Code       .NULL.  Customer No. SCICON         Client Type:  REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLINAVE.
             CHICAGO                  IL     60623
Phone    254-2406
Matrix    Engineering

Client Notes: -o-
                          Fax  254-6661
                          PoNo. -0-
Contact MR. FRANK ALTMAYER
         e-mail
                      Quoted Price:  .NULL.
                            Test Code  Description
Order Comments:   .NULL.
                  .NULL.
  Sample No.    Comments
.NULL
        1   10/31/2005   10/31/05-RELIABLE-CONDITION #3-EAST
                         Nl            NICKEL
        2   10/31/2005   10/31/05-RELIABLE-CONDITION #3-WEST
                         Nl            NICKEL
        3   11/01/2005   11/01/05-RELIABLE-CONDITION #6-EAST
                         Nl            NICKEL
        4   11/01/2005   11/01/05-RELIABLE-CONDITION #6-WEST
                         Nl            NICKEL
        5   11/02/2005   11/02/05 - RELIABLE - CONDITION #5 - EAST
                         Nl            NICKEL
        6   11/02/2005   11/02/05 - RELIABLE - CONDITION #5 - WEST
                         Nl            NICKEL
        7   11/03/2005   11/03/05 - RELIABLE - CONDITION #4 - EAST
                         Nl            NICKEL
        8   11/03/2005   11/03/05-RELIABLE-CONDITION #4-WEST
                         Nl            NICKEL
        9   10/31/2005   10/31/05-RELIABLE-BLANK
                         Nl            NICKEL
                          Date Received       Result

                          11/03/2005 03:50:00 PM

                          11/03/200503:50:00 PM

                          11/03/200503:50:00 PM

                          11/03/200503:50:00 PM

                          11/03/200503:50:00 PM

                          11/03/200503:50:00 PM

                          11/03/2005 03:50:00 PM

                          11/03/2005 03:50:00 PM

                          11/03/200503:50:00 PM
  Page 1

-------
                                                                                           Set*
       Method:      (check only one per page)
     ICP/FLAA:  SM 3030 F, EPA 200.7 '82
     ICP/FLAA:  EPA 200's, SW-846 3010A
     ICP/FLAA:  EPA 200.7 r4.4
     ICP/FLAA:  SW-846 3005A
     ICP/FLAA:  SW-846 3015A MICROWAVE
     OTH ER:	
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:_	
MATRIX:            (check only one per page)
     DRINKING WATER                      I    lAQUEOUS
                           OTHER:



1


2
3
4
5
6
7
8
9
10
11
12

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date
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H'p
















Lab#


no 200














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QC-21
QC-7
P
Sn
OTHER
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£>cT}^£i /]
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                                                                              Analyst:

                                                                            Start Date:
                                                                                              S\QA FORMS \FM-041 \R02 \LK
                                                                                                          Page 1 of 1

-------
                                                                                              Set
Prep Method:      {check only one per page)
     1CP/FLAA: SM 3030 F, EPA 200.7 '82
     ICP/FLAA: EPA 200's, SW-846 301OA
     ICP/FLAA: EPA 200.7 r4.4
     ICP/FLAA: SW-846 3005A
     ICP/FLAA: SW-846 3015A MICROWAVE
     OTHER:	,	
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:	
MATRIX:             (check only one per page)

DRINKING WATER




1


2
3
4
5
6
7
8
9
10
11
12


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Company
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QC-21
QC-7
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OTHER
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£)g"^£) ^




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Start Date:



i^
                                                                                                 S\QA FORMS \FM-041 \R02 \LK
                                                                                                             Page 1 of 1

-------
                          Sample Information Detail Report
                          Document Name: 111505-1
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
                       111505-1
                       ml
                       g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
 19
20
21
22
23
24
 25
 26
 27
 28
 29
 30
 31
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
 39
 Sample No  Sample Prep. Vol.
 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
 11
 12
 13
 14
 15
 16
 17
Sample ID
ccv 9r66— i,OO
ccb

Irb
110077-1
110077-2
110077-3
110077-4
110077-5
110077-6
<
                                                                               Initial Sample Wt.
 ccb
 110077-7
 110077-8
 110077-9
•Ifb 2
 Irb
 110200-1
 110200-2
 110200-3
 ccb
 110200-4
 110200-5
 110200-6
 110200-7
 110200-8
 110200-9
 110200-10
 ccvf f
 ccb
                                   Aliquot Volume
                                                                                Diluted To Vol.

-------
Method: Air Filter Ni
                                           Page
                                                                    Date: 11/15/2005 1:56:12 PM
Analysis Begun

  -art Time- 11/15/2005 1:45:50 PM               Plasma On Time: 11/15/2005 11:32:42 AM
  -art Time. j.j./±o/^uu3-L                       Technique: ICP Continuous
                         3000 DV, S/N 069N5083001AutosaI[pler Model: AS-91

Sample Information File: C:\pe\sammy\Sarnple Information\111505-l.sif
Batch ID:  111505-1
Results Data Set:  111505-1
Results Library: C:\pe\sammy\Results\Results.mdb



Shod 5±fAir Filter Ni                     Method Last Saved: 10/5/2005 1:33:13 PM

IEC File:                                     MSF File:
Method Description:  AIR FILTER Ni


                                             Autosantpler Location:  0

                     !                       s- sirss^15'"" 1:45:5°M


              -


Mean Data: Calib Blank 1
                  Mean Corrected
Analvte              Intensity     Std.Dev.   RSD       Cone. Units
^328 937          2071926.8      10795.50   0.52%        10.0 mg/L
£ 23i:604t           -171-4         11-69   6.82%       [0.00] zng/L


                                              Autosampler Location:  1
                   ,.00                        -.





Mean Data: Cal 21+7 1.00
                  Mean Corrected
Analvte              Intensity     Std.Dev.   RSD       Cone Units
 Yb 328 937          2041837.0      2473.23    0.12%        9.85 mg/L
 2 23?:604t            6318.1        44.95    0.71%       [1-00] mg/L


 Calibration Summary


                      a^si.     "-rs


                                              Autosampler Location: 9

                   ,.^                       j- ^--^15/20051:52!51

                                              £5?.=?^'


 Mean Data: ccv 9-^6

                                                                        .      —  „-

                                                                      /L       o.oo™   ..,»


            • A                               Autosampler Location: 10
       ID ccb                                ^te Collected: 11/15/2005 1:56:12 PM

-------
Method: Air Filter Ni
                                           Page
                                                                  Date: 11/15/2005 2:14:02 EM
                                            Data Type: Original
       Q m^w-                            Initial Sample Vol:
initial Sample Wt.                                       Vol;
Dilution:                                       v     r


Mean Data: ccb                                                     Sample
                                                -o        c-..—

                                                 °-°°"

                                            Autosampler Location: 11

                                                                     2:00:03 M

                                                                             ,
Dilution:                 1} V                    v     r                       L


Mean Data: Ifb                                                     Sample
                                                                  iS.      «.«-

                                                                  «/L       o.o»23   »


         .n  . f-                               Autosampler Location: 12
 Sequence No   6                                   Collected: 11/15/2005 2:03:24 PM
 Sample ID: Irb                                Data      original

 ss w. «
 Dilution:


 Mean Data: Irb

                                   «               ..                              „-

                                                 «°»»0'      -0.004 „,/,


                                             Autosampler  Location: 13

                                             sir, Sir^^15/2005 2:07i17 ra
      i Q ^i« wt--                            Initial Sample Vol:
 Initial Sample wt:                            -IT,  _  xr«i •
 Dilution:                                    Sample Prep  Vol.


 Mean Data: 110077-1                                                Samole
                                                                      .     —•

                                                  »™»       »-»«-/'       ••»»»  °-

             0                               Autosampler Location:  14
        D  ilo077-2                           Date Collected:  11/15/2005 2:10:39 PM
        . '                                   Data Type: Original
        ' sample Wt:                            Initial Sample Vol:
 Dilution:                                    Sample Prep Vol.


 Mean Data: 110077-2                                                 Samole

                  -4                                  •'S

 S!!J:SIt

 ~„„ . Q                               Autosampler Location: 15
         f iIo?77-3                           ^te CoHected: 11/15/2005 2:14:02 PM

-------
Method: Air Filter Ni
                                      Page
                                                           Date: 11/15/2005 2:31:04 PM
                                        Data Type: Original
      :,   -_ w..                          Initial Sarnple Vol:
       Sample Wt.                                   Vol.
Dilution:                                   ^    r


Mean Data: 110077-3                                            Sample

               "-S£ST      = SS     3«.s.     =-.»«.     «"--  „»

                                             °               ^      ..0033  „.«..



=      ~   .,.                           Autosaitmler Location: 16
Science No : 10                               Collected: 11/15/2005 2:17:25 PM
Sample ID: 110077-4                         Data     original
Analyst:                                 Initial Sample Vol:
initial sample Wt:                               Pr^Vol:
Dilution:                                   *^    *


Mean Data: 110077-4                                            Sanple

                              0«. SSS     «d.D-.     a-.""-    •«.«-•   ».

                                            "^4      0.404.,/L      ..0024  0.60S



       ..    ..                   •        Autosairroler Location: 17
Sequence No :  11                               Collected: 11/15/2005 2:20:50 PM
Sample  ID: 110077-5                         ^^ ^^ Original

                                        Initial Sait^le Vol:
                                        Sanple Prep Vol:



Mean Data: 110077-5                                            Sainple

               -iSS?4   =«;.5SS                —•

       l«t        ""'in?:?      »!;»SS


        ~                                Autosaitroler Location:  18

                                        ss ^roS^15/2005 2:24;14 M

                                        ssf^ir!



Mean Data:  110077-6                                            Sairole

                          4                           =-.«*.     .«.-«.     ,

                                                             /L       o.o.»   ..7,.



                                        Autosanpler Location: 19

                .                        j£ Siro*s^15/2005 2i27!39 m


                                     ^ ssr-wtr1


 Mean Data:  oev-iC"S~^                                        Sanmle






                                        Autosampler Location: 20
                                        Date Collected:  11/15/2005 2:31:04 PM

-------
Method: Air Filter Ni
                                                Eage   4
                                                                          Date: 11/15/2005 2:49:12 EM
                                                  Data Type: Original
      i „ m,« wt •                                 Initial  Sample Vol:
initial Sample Wt.                                            Vol;
Dilution:                                           *^     ^



Mean Data: ccb                                                           Sample

                                                             .      «-.««.

                                                                    0.001 »»/.



         _                                        Autosairpler Location:  21
Seguence No   15                                       Collected:  11/15/2005  2:35:01 EM
Sainple ID: 110077-7                               Data Type; Qriginal


                                                  ssf




Mean Data: 110077-7                                                       Sample








         VT     ,,•                                  Autosarapler Location:  22
Sequence No    16                                       Collected:  11/15/2005 2:38:27 EM
san.pl. m: 110077-8                               ^^       Original

               W--                                initial San^le Vol:





Mean Data: 110077-8                                                       Sample
                   Mean Corrected         caJ.ir>                             *-
                       intensity      Cone  Units       Std.Dev.       Cone. Units      Std.Dev.

                                                       0°0?292       0.156mg/L        0.0022   1.44%



                                                  Autosampler Location: 23









 Mean Data:  110077-9                                                      Sanple
                    Mean Corrected          Calib                             .*;
                       intensity      Cone   Units       Std.Dev.      Cone. Units      Std.Dev.  Q%

                                                                    -0.003 mg/L        0.0002   6.21%



          „    IQ                                 Autosampler Location:  24





         "



 Mean Data: Ifb 2                                                          Sample







 ~        XT^ . IQ                                  Autosampler  Location: 25
 fan^le ID^irb                                    Date Collected: 11/15/2005 2:49:12  EM

-------
•Method: Air Filter Ni
                                                  Page
                                                                             Date: 11/15/2005 3:07:01  PM
                                                    Data Type: Original
 Analyst:                                            Initial Sample Vol:
 initial Sample Wt.                                             Vol;
 Dilution:                              -^            *^



 Mean Data: Irb                              Calib                          Sample

 ar._-i,rj-e                Intensity      Cone. Units         "„,"                                  0.46%
 •f"la~1-J    _            „„-,„„,,-,  n         a C.K TV,rr/T.         0.044                                   , „„„
                                                         0.0011      -0.001 mg/L         0.0011  76.99%



                                                    Autosampler Location:  26
 Sequence No  : 20                                        Collected: 11/15/2005  2:53:04 PM
 Sample ID: 110200-1                                ^^ ^^ Original

 Analyst:                                           Initial Sample Vol:
 initial Sample Wt.                                 Sample Prep Vol:
 Dilution:                                             v



 Mean Data: 110200-1                         Calib                           Sample

 analtH-e                Intensity      Cone. Units      t>   '  „  '                                  0 20%

     Y                 	  -        ° °" -/T-          °-°2°              mg/1        0.0022   1.07%

                                                                             	^3:: = :===:==: = = ======= —= = = = —

           -Autosampler Location:  27
 Sequence No  :  21                                  Date Collected:  n/15/2005 2:56:25 PM
        ID: J.XU3                                   Autosampler Location:  29
                 "*   /\   ^ ^ftrfO                          Date Collected." 11/15/2005 3:0 j * jy HM
                                                     Data Type i Or/ic/inal






  Mean Data:  ccv e-r5«   I'OC                  __,,^                           Sample


                                                                                                   0
                                                                                          0.0058   0



           _Autosampler Location: 30
  Sequence No..24                                        Collected:  11/15/2005 3:07:01 PM
  Sample  ID:  cob

-------
Method: Air Filter Ni
                                               Page
                                                 Data Type: Original
                                                                          Date:  11/15/2005  3:24:30 PM
Mean Data: cob          Corrected          calib
^yte               intensity      Cone  Units      Std Dev.      Cone. Umts      Std.Dev.
S 23i:9604t          215°°°2:6       0^000 SL         O.°o5°05       0.000 mg/L        0.0005
                                          \J                             ______________ =====
                                                 Autosaitpler Location: 31
                             •                    =.«               15'2005 3:10!54 M



Mean Data: 110200-4                                                      Samcle
                                                                          S-
                                                                           A

               oc                                 Autosairajler Location:  32
          f iio200-5                              Data  Collected:  11/15/2005 3:14:17
 Aalvst-                                         Data  Type: Orl^nal
 Analyst.                                          Initial  Sample Vol:
                                                  S^e Prep Vol:

 Mean Data: 110200-5                                                       Sample
                                                                         ««•
                                                                    0.042 TOft        0.0022

          „    OT                                  Autosanipler Location:  33
 Sequence No. ^2^^                               Date ^lected:  11/15/2005  3:17:41  PM
 sanp     .                                        Data Type:  Original
 SiSalWeWt:                                Initial Sa^le Vol :
 Dilution:                                        SainPle Prep Vo1'

 Mean Data:  110200-6                                                       Saraole
                                     conc.SSS      .««,.       o^-uSS.       .«.»-.
                                                                                       »•««    •>•

                                                  Autosanpler Location:  34
                                                  °ate Collected: 11/15/2005 3:21:06 PM
                                                  Data Type: O^Q111*1
                Wt:                                Initial Sa^le Vol :
 Dilution:                                        Sal^le PreP Vol:

 Mean Data: 110200-7                                                      Saraole
                                                                                     .«.»-.   „-
                                                                           ./'        »••»»   »•«•

          M   . ,Q                                 Autosaitpler Location: 35
          T iioSo-8                              °a^ Collected: 11/15/2005 3:24:30 PM

-------
                                      paCT_  7               Date: 11/15/2005 3:41:49 PM
Method: Air Filter Ni   	.	f2S2	L	'

                                       Data Type: Original
Analyst:                                 Initial Sample Vol:
Initial Sample Wt:                               Prep Vol:
Dilution:                                  ^


Mean Data: 110200-8                                           Sample

^^          -iSS?1   c»0.SSS    3t*D.v.     —.-if     .«.»».  »,


£^:t3o2,        213MS:2     o"o^S      O.K      »-™2»>"-


====r7~                         Autosampler Location: 36
Sequence No : 30                          Dafce Collected: n/15/2005 3:28:25 PM
Sample ID: 110200-9                        Data ^^ original

Ana^3^= a ™i ~ w -                         initial Sample Vol:
initial  Sample Wt.                                   Vol.
Dilution:                                  *^


Mean Data: 110200-9                                            Sample

^yle         -££5?*   —-SS     .«.«.     —.-if     —  ».

SlSiSJt        uS3e!!:l      S:'n5A        S:SS      ,.***       ».»«   ..™.


==~_-                          Autosampler Location: 37
Sequence No :  31                ^        Date Collected: n/15/2005 3:31:51 PM
Sample ID: 110200-10             (  1        ^^     Original

Iaa1^'-    .  _                V         initial Sample Vol:
initial Sample Wt:                  Q       San5,le Prep Vol:
Dilution:                                   v


Mean Data:  110200-10            ,,//     .   \                  s   le

M,lyt«         -iSsT1//=-».£«»     -^j-     c-^"     Std-D'v-  osss

 SS',:S2t        2°"!S:i  V  o^SiiSSy   o.S;0^     .....««      ».™»  »•»•


=====77Autosampler Location: 38
 Sequence No.:  32                              Collected: 11/15/2005 3:35:17 PM
 Sample ID:  ocv*- O, .O^                     Data      Originai

^Y5*'   .  w.                          initial Sample Vol:
 initial Sample Wt.                                   Vol.
Dilution:                           . ^i /    *"     ^



Mean Data:  ccv *• &'^ ^                                        Sample

 ^^          ""^SLTtT   —-t"     «**j-     =—"    SM-D-  o!S.

 Sy;:S;i,       ""S:1.      o"iS3S      o.SiS     ...«^,/L      o.»o»  "•«•


        ~   -.,                          Autosampler Location: 39
 Sequence No.: 33                          Dafce Collected:  n/15/2005 3:38:43 PM
 Sample  ID: ecb                            Dafca Type. Or±ginal

   I^:, m,  w.                          Initial Sample Vol:
 initial Sample Wt.                     y           Vol;
 Dilution:                           co\V     v


 Mean Data: ccb                                               Sample

 ^yt.         "^SS?*   =~.SS     SM.r.     <»-.-«.     -••«•  0^%

 Sf3?:"«       215456?:?      »"™S/'       o.SiS!     O.»OO«/L      o.oo051S6.4«

-------
PROJECT # 020072:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES
Digestion on 02/06/06
BY ICP ON 02/09/06
                                        IDL =    0.004

                                        LOD =    0.008
                                        MDL •    0.007
LOQ •   0.017

 RL •    0.050
      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
020072-1
020072-2
020072-3
020072-4
020072-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
2.16
J3.002
0.209
0.036
2.310
0.149
                                       FURTHER'6AL'eUlATIONSl IF A':
                                                        is L;i#EN O:OMJSI§SED.'

-------
r "horatorv Work Order Report

LIMSNo  '     2006020072  Date Rec'd 02/03/2006 03:58:26   Date Due    02/03/2006 12:00:00 AM
Project Code       .NULL  Customer No. SCICON         Client Type:  REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLIN AVE.
             CHICAGO                  IL     60623
Phone
Matrix
254-2406
Engineering
Fax 254-6661
PoNo. ;Qr
Contact MR. FRANK ALTMAYER
e-mail
Client Notes: -o-

Order Comments:   .NULL.
                  .NULL.
  Sample No.    Comments
OSHA-ID-121
        1   02/01/2006

        2   02/01/2006
     Test Code   Description
ABQC-02/01/06-BLANK
        3   02/01/2006
        4   02/02/2006
         5   02/02/2006
 Nl            NICKEL
ABQC - 02/01/06 - COND#10 - EAST
SERIAL #25082359
 Nl            NICKEL
ABQC - 02/01/06 - COND#10 - WEST
SERIAL #25093158
 Nl            NICKEL
ABQC - 02/02/06 - COND#13 - EAST
SERIAL #25082349
 Nl            NICKEL
ABQC - 02/02/06 - COND#13 - WEST
SERIAL #25082370
 Nl            NICKEL
                                                                    Quoted Price:  .NULL.
Date Received
                                                                  Result
                                                 02/03/2006 03:00:00 PM
02/03/2006 03:00:00 PM
                                                                        02/03/2006 03:00:00 PM
                                                                        02/03/2006 03:00:00 PM
                                                                        02/03/2006 03:00:00 PM
   Page 1

-------
Prep MetflOd:      (check only one per page) -
                                                                                          Set*
    1CP/FLAA: SM 3030 F, EPA 200.7 '82
    ICPJ'FLAA: EPA 200's, SW-846 3010A
    ICPyFLAA: EPA 200-7 r4.4
    iCP/FLM: SW-846 3005A
    ICP/FLAA: SW-846 3015A MICROWAVE
    OTHER:      	
GFAA: SM3030E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:	-
MATRIX:
     DRINKING WATER
                       {check only one per page)
                                                AQUEOUS
                           OTHER:



1


2
3
4
5
6
7
8
9
10
11
12

Set
Inif
l^L
















Set
date
^
' ~















Set
time
f
















Lab#


02f>t>"l£














Smp#

	
i
^
^
-I
?c










Company
LFB
LRB

LFM DUP
LFM









,,


Aliquot
(mis)


fi^














Final
(mis)





















•-..•••.•••V-.,V),--"-

I ajl c.vs '
W- ^4l£L?i











Mcr
Vslf






t-










SPIKING STDS
QC-21
QC-7
P
Sn
OTHER
PROVIDER
rf»f
1



LOT#
£>SHnU'^




                                                                             Analyst:

                                                                           Start Date:
                                                                                             S\QA FORMS \FM-041 \R02 \LK
                                                                                                        Page 1 of 1

-------
                          Sample Information Detail Report
                          Document Name: 020906-1
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
                       020906-1
                       ml
                       g
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
Sample No Sample Prep. Vol.
1
2
3
4
5
6
7
8
9
10
11
12
13
Sample ID
cri
icsab
ccv 0.50
ccb
Ifb
Irb
020072-1
020072-2
020072-3
020072-4
020072-5
ccv 1
ccb

Aliquot Volume
                                                                               Initial Sample Wt.
                                                                               Diluted To Vol.

-------
Method: Air Filter Ni
Page
                                                                           Date:  2/9/2006 4:43:20 EM
Analysis Begun

Start Time: 2/9/2006 4:32:26 EM                   Elasma On Time: 2/9/2006 3:02:06 EM
Logged In Analyst: sammy                          Technique: ICE Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

Sample Information File: C:\pe\sammy\Sample Information\020906-l.sif
Batch ID: 020906-1
Results Data Set: 020906-1
Results Library: C:\pe\saimny\ResultsYResults.mdb


Method Loaded
Method Name: Air Filter Ni                        Method Last Saved: 10/5/2005 1:33:13 EM
IEC File:                                         MSF File:
Method Description: AIR FILTER Ni


Sequence No.: 1                                   Autosampler Location: 0
Sample ID: Calib Blank 1                          Date Collected: 2/9/2006 4:32:26 EM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Erep Vol:


Mean Data: Calib Blank 1
                   Mean Corrected                                Calib
Analyte               Intensity      Std.Dev.   RSD        Cone. Units
Yb 328.937           4114830.8      15776.58   0.38%        10.0 mg/L
Ni 231.604t             -130.9          3.97   3.03%       [0.00] mg/L


Sequence No.: 2                                   Autosampler Location: 1
Sample ID: Cal 21+7 1.00                          Date Collected: 2/9/2006 4:36:07 EM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Erep Vol:


Mean Data: Cal 21+7 1.00
                   Mean Corrected                                Calib
Analyte               Intensity      Std.Dev.   RSD        Cone. Units
Yb 328.937           4095641.1      50232.78   1.23%        9.95 mg/L
Ni 231.604t             9671.8        108.72   1.12%       [1.00] mg/L


Calibration Summary

Analyte        Stds.   Equation        Intercept      Slope    Curvature      Corr. Coef.    Reslope
Ni 231.604       1     Lin Thru 0            0.0       9672      0.00000        1.000000


Sequence No.: 3                                   Autosampler Location: 9
Sample ID: cri                                    Date Collected: 2/9/2006 4:39:27 EM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Erep Vol:


Mean Data: cri
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937           4081070.0        9.92 mg/L         0.027                                  0.27%
Ni 231.604t              242.6       0.025 mg/L        0.0005       0.025 mg/L        0.0005   2.06%


Sequence No.: 4                                   Autosampler Location: 10
Sample ID: icsab                                  Date Collected: 2/9/2006 4:43:20 EM

-------
                         Date:  2/9/2006 5:01:07  PM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: icsab
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 5
Sample ID: ccv 0 . 51
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccv 0.5i
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 6
Sample ID : ccb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccb
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 7
Sample ID: Ifb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: Ifb
Analyte
Yb 328.937
Ni 231.604t
Sequence No . : 8
Sample ID: Irb
Analyst:
Initial Sample Wt :
Dilution:
Mean Data: Irb
Analyte
Yb 328.937
Ni 231.604t

Mean Corrected
Intensity
3855502.9
9704.0
D
D
Mean Corrected
Intensity
4097861.2
4766.0

Mean Corrected
Intensity
4079669.8
-5.4

Mean Corrected
Intensity
3773785.3
20877.5

Mean Corrected
Intensity
3846235.8
-21.5

Calib
Cone. Units
9.37 mg/L
1.00 mg/L

Calib
Cone. Units
9.96 mg/L
0.493 mg/L

Calib
Cone. Units
9.91 mg/L
-0.001 mg/L

Calib
Cone. Units
9.17 mg/L
2:16 mg/L

Calib
Cone. Units
9.35 mg/L
-0.002 mg/L
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.068
0.002 1.00 mg/L
Autosampler Location: 11
Date Collected: 2/9/2006 4:46:40
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.064
0.0015 0.493 mg/L
Autosampler Location: 12
Date Collected: 2/9/2006 4:50:01
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.046
0.0006 -0.001 mg/L
Autosampler Location: 13
Date Collected: 2/9/2006 4:53:53
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units
0.046
0.012 2.16 mg/L
Autosampler Location: 14
Date Collected: 2/9/2006 4:57:15
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Sample
Std.Dev. Cone. Units
0.147
0.0007 -0.002 mg/L

Std.Dev. RSD
0.73%
0.002 0.20%
PM
Std.Dev. RSD
0.65%
0.0015 0.30%
PM
Std.Dev. RSD
0.47%
0.0006 114.59%
PM
Std.Dev. RSD
0.50%
0.012 0.58%
PM
Std.Dev. RSD
1.57%
0.0007 31.72%
Sequence No. :  9
Sample ID:  020072-1
Autosampler Location: 15
Date Collected: 2/9/2006 5:01:07 PM

-------
        Air Filter Ni
Page
                                                                           Date:  2/9/2006 5:19:38 PM
Analyst:
Initial Sample Wt:
Dilution:

Mean Data: 020072-1
Mean Corrected
Analyte Intensity
Yb 328.937 3834509.7
Ni 231.604t 16.0
Sequence No . : 10
Sample ID: 020072-2
Analyst:
Initial Sample Wt:
Dilution:

Mean Data: 020072-2
Mean Corrected
Analyte Intensity
Yb 328.937 3817011.8
Ni 231.604t 2026.2
Sequence No . : 11
Sample ID: 020072-3
Analyst:
Initial Sample Wt:
Dilution:

Mean Data: 020072-3
Mean Corrected
Analyte Intensity
Yb 328.937 3873178.7
.Ji 231.604t 347.7
Sequence No. : 12
Sample ID: 020072-4
Analyst:
Initial Sample Wt:
Dilution:

Mean Data: 020072-4
Mean Corrected
Analyte Intensity
Yb 328.937 4118867.8
Ni 231.604t 22338.0
Sequence No. : 13
Sample ID: 020072-5
Analyst:
Initial Sample Wt:
Dilution:

Mean Data: 020072-5
Mean Corrected
Analyte Intensity
Yb 328.937 3793834.3
Ni 231.604t 1445.2

Cone.
9.32
0.002

Cone.
9.28
0.209

Cone.
9.41
0.036

Cone.
10.0
2.31

Cone.
9.22
0.149

Calib
Units
mg/L
mg/L

Calib
Units
mg/L
mg/L

Calib
Units
mg/L
mg/L

Calib
Units
mg/L
mg/L

Calib
Units
mg/L
mg/L
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.084
0.0008 0.002 mg/L 0.0008
Autosampler Location: 16
Date Collected: 2/9/2006 5:05:00 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev.
0.085
0.0038 0.209 mg/L 0.0038
Autosampler Location: 17
Date Collected: 2/9/2006 5:08:24 PM
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.075
0.0005 0.036 mg/L 0.0005
Autosampler Location: 18
Date Collected: 2/9/2006 5:12:17 PM
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Sample
Std.Dev. Cone. Units Std.Dev.
0.07
0.033 2.31 mg/L 0.033
Autosampler Location: 19
Date Collected: 2/9/2006 5:15:44 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol :
Sample
Std.Dev. Cone. Units Std.Dev.
0.137
0.0016 0.149 mg/L 0.0016

RSD
0.90%
50.28%

RSD
0.91%
1.80%

RSD
0.80%
1.47%

RSD
0.67%
1.44%

RSD
1.49%
1.07%
Sequence No.:  14
 iample ID:  ccv 1
  Autosampler Location:  20
  Date Collected:  2/9/2006 5:19:38 PM

-------
Date: 2/9/2006 5:26:11 PM
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccv 1
Analyte
Yb 328.937
Ni 231.604t
Sequence No. : 15
Sample ID : ccb
Analyst:
Initial Sample Wt:
Dilution:
Mean Data: ccb
Analyte
Yb 328.937
Ni 231.604t

Mean Corrected
Intensity
4126299.4
9429.0

Mean Corrected
Intensity
4027115.6
-13.0

Calib
Cone. Units
10 . 0 mg/L
0.975 mg/L

Calib
Cone. Units
9.79 mg/L
-0.001 mg/L
Data Type: Original
Initial Sample Vol :
Sample Prep Vol :
Std.Dev. Cone.
0.07
0.0089 0.975
Autosarapler Location: 21
Date Collected: 2/9/2006
Data Type: Original
Initial Sample Vol :
Sample Prep Vol:
Std.Dev. Cone.
0.057
0.0002 -0.001

Sample
Units Std.Dev.
mg/L 0.0089
5:23:04 PM
Sample
Units Std.Dev.
mg/L 0.0002

RSD
0.68%
0.92%

RSD
0.58%
11.76%

-------
PROJECT # 010218:  METHOD  121 FOR NICKEL
AIR FILTER CASSETTES                      IDL =    0.004
Digestion on 01/24/06
BY ICP ON 01/27/06
LOD =
MDL =
                                                   0.008
                                                   0.007
LOQ =    0.017
 RL =     0.050
      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
010218-1
010218-2
010218-3
010218-4
010218-5
Dilution
25
25
25
25
25
25
25
Reading
-0.001
1.98
2.16
0.238
/j>>AQ01% s
0.622
0.087
                                        
-------
   'boratory Work Order Report
 LIWU'lNo.  :     2006010218  Date Rec'd 01/13/2006 03:01:36    Date Due    01/13/2006 12:00:00 AM
 Project Code       .NULL.  Customer No.  SCICON         Client Type: REGULAR
 Client Name   SCIENTIFIC CONTROL LABS
              3158S. KOLINAVE.
              CHICAGO                  IL      60623
Phone
Matrix

254-2406
Engineering

Fax 254-6661
Po No. zQr

Contact MR. FRANK ALTMAYER
e-mail
Quoted Price:


.NULL
Client Notes: -o-
Order Comments:    NULL
                  .NULL.
  Sample No.    Comments
ABQC
                                               °  "7
                            Test Code  Description
        1   01/11/2006  01/11/06 CONDITION #12 EAST-
                       SERIAL #25093149
                         Nl            NICKEL
        2   01/11/2006  01/11/06 CONDITION #12 WEST-
                       SERIAL #25093112
                         Nl            NICKEL
        3   01/11/2006  01/11/06 BLANK
                       SERIAL #25093138
                         Nl            NICKEL
        4   01/11/2006  01/11/06 CONDITION #11 EAST-
                       SERIAL #25093115
                         Nl            NICKEL
        5   01/11/2006  01/11/06 CONDITION #11 WEST-
                       SERIAL #25093146
                         Nl            NICKEL
                                                                        Date Received
Result
                                                                        01/13/2006 01:30:OOPM
                                                                        01/13/2006 01:30:OOPM
                                                                        01/13/2006 01:30:OOPM
                                                                        01/13/2006 01:30:00 PM
                                                                        01/13/2006 01:30:OOPM
 Page 1

-------
 METALS   PREP   FORM
Prep Method.'    (check only one per page)
                                                           Set*
   ICP/FLAA: SM 3030 F, EPA 200.7 '82
   ICP/FLM: EPA 200's, SW-846 301OA
   ICP/FLM: EPA 200.7 r4.4
   ICP/FLM: SW-846 3005A
   ICP/FLM:" SW-846 3015A MICROWAVE
   OTHER:
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
 iFAA: SW-846 3015A (NoHCL) MICROWAVE
OTHER:	
MATRIX:         (check only one per page)
   DRINKING WATER
                                                 OTHER:
                                                           S\QA FORMS \FM-041 \R02 \LK
                                                                   Page 1 of 1

-------
                          Sample Information Detail Report
                          Document Name: 012706-1
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
012706-1
ml
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sample Prep. Vol.
















                                              Sample ID
                                              cri
                                              icb
                                              icv
                                              icsab
                                              Ifb
                                              Irb
                                              010302-1
                                              010302-2
                                              010302-3
                                              01 021 8-1 '
                                              010218-2
                                              010218-3
                                              010218-4
                                              010218-5
                                              ccb
                                              Aliquot Volume
                                             Initial Sample Wt.
                                                                                Diluted To Vol.

-------
Method: Pt-MnBEC
                                                Page
                                                                           Date:  1/27/2006 2:39:10  PM
Analysis Begun

dtart Time: 1/27/2006 2:28:40 PM                  Plasma On Time: 1/27/2006 2:02:19 PM
Logged In Analyst: sammy                          Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

Sample Information File:
Batch ID:
Results Data Set:
Results Library:
Method Loaded
Method Name: Pt-MnBEC
IEC File:
Method Description: Axial Performance Test
                                                  Method Last Saved:  11/29/2005  2:09:00  PM
                                                  MSF File:
Sequence No.:  1
Sample ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
                                                  Autosampler Location:
                                                  Date Collected: 1/27/2006 2:28:40 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Replicate Data: Calib Blank 1
Net Corrected
Repl# Analyte Intensity Intensity
1 Mn 257.610 2926.8 2926.8
1 cu 324.752 9474.4 9474.4
2 Mn 257.610 2799.0 2799.0
2 Cu 324.752 9431.8 9431.8
3 Mn 257 610 2789.6 2789.6
3 Cu 324.752 9436.9 9436.9
Mean Data: Calib Blank 1
Mean Corrected
Analyte Intensity Std.Dev. RSD
Mn 257.610 2838.5 76.62 2.70%
Cu 324.752 9447.7 23.26 0.25%
Calib. Analysis
Cone. Units Time
[0.00] mg/L 14:30:06
[0.00] mg/L 14:30:06
[0.00] mg/L 14:30:16
[0.00] mg/L 14:30:16
[0.00] mg/L 14:30:26
[0.00] mg/L 14:30:26

Calib
Cone. Units
[0.00] mg/L
[0.00] mg/L
 Sequence No.:  2
 Sample ID:  Calb Stdl
 Analyst:
 Initial Sample Wt:
 Dilution:
                                                  Autosampler Location:
                                                  Date Collected: 1/27/2006 2:31:19 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Replicate Data:
Repl# Analyte
1 Mn 257.





1
2
2
3
3
Cu
Mn
Cu
Mn
Cu
324.
257.
324.
257.
324.
610
752
610
752
610
752
Mean Data: Calb





Analyte
An 257.610
Calb Stdl
Net
Intensity
1868576.8
494782.4
1874239.8
496392.3
1862604.1
492560.1
Stdl
Mean Corrected
Intensity
1865635.1
Corrected
Intensity
1865738.3
485334
1871401
486944
1859765
483112


Std.Dev.
5818.57
.7
.4
.6
.6
.4


RSD
0.31%
Cone.
[5.00]
[5
[5
[5
[5
[5


.00]
.00]
.00]
.00]
.00]


Calib.
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/1

Calib
Analysis
Time
14:32:31
14:32:31
14:32:44
14:32:44
14:32:57
14:32:57


Cone. Units
[5.00] mg/L

-------
Method: Pt-MnBEC
Cu 324.752
Calibration
Analyte
Mn 257.610
Cu 324.752

Summary
Stds.
1
1
485130.6

Equation
Lin Thru 0
Lin Thru 0
Page
1924.25 0.40%

Intercept
0.0
0.0
2
[5,

Slope
373100
97030
Date: 1/27/2006 2:J»:±u JtM
.00] mg/L

Curvature Corr. Coef. Reslope
0.00000 1.000000
0.00000 1.000000
	 =========— ============= 	 '
Sequence No.:  3
Sample ID: bee
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location:
Date Collected: 1/27/2006 2:33:19 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Replicate Data: bee
Repl# Analyte
1 Mn 257.610
1 Cu 324.752
2 Mn 257.610
2 Cu 324.752
3 Mn 257.610
3 Cu 324.752
Mean Data: bee
Analyte
Mn 257.610
Cu 324.752
Net
Intensity
0.3
1.2
0.2
0.1
-0.8
0.1

Mean Corrected
Intensity
-2838.6
-9447.2
. 	 — 	 	 ;———=====
Corrected
Intensity
-2838.2
-9446.5
-2838.3
-9447.6
-2839.3
-9447.6

Calib
Cone . Units
-0.008 mg/L
-0.097 mg/L
Calib .
Cone. Units
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L

Std.Dev. Cone.
0.0000 -0.008
0.0000 -0.097
Sample
Cone. Units
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L
-0.008 mg/L
-0.097 mg/L

Sample
Units Std
mg/L 0 .
mg/L 0 .
Analysis
Time
14:34:18
14:34:18
14:34:38
14:34:38
14:34:58
14:34:58

.Dev. RSD
0000 0.02%
0000 0.01%
 .•fethod Loaded
 Method Name: Pt-MnBEC
 IEC File:
 Method Description: Axial Performance Test
Method Last Saved: 11/29/2005 2:09:00 PM
MSF File:
 Sequence No.:  4
 Sample  ID:  cv
 Analyst:
 Initial Sample Wt:
 Dilution:
Autosampler Location:
Date Collected:  1/27/2006 2:35:25 PM
Data Type: Original
Initial  Sample Vol:
Sample Prep Vol:
Replicate Data: cv
Replf
1
1
2
2
3
3
4
4
5
5
6
6
7
7
8
8
Analyte
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257.610
Cu 324.752
Mn 257. 610
Cu 324.752
Net
Intensity
1873085.6
496646.8
1867976.6
494873.3
1863508.5
493612.2
1864524.6
493197.1
1858358.5
492295.2
1877872.2
497735.9
1870403.1
495019.6
1871306.3
496395.8
Corrected
Intensity
1870247.1
487199.1
1865138.1
485425.6
1860670.1
484164.5
1861686.1
483749.4
1855520.0
482847.6
1875033.7
488288.2
1867564.7
485571.9
1868467.8
486948.1
Calib .
Cone. Units
5.01 mg/L
5.02 mg/L
5.00 mg/L
5.00 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.97 mg/L
4.98 mg/L
5.03 mg/L
5.03 mg/L
5.01 mg/L
5.00 mg/L
5.01 mg/L
5.02 mg/L
Sample
Cone. Units
5.01 mg/L
5.02 mg/L
5.00 mg/L
5.00 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.99 mg/L
4.97 mg/L
4.98 mg/L
5.03 mg/L
5.03 mg/L
5.01 mg/L
5.00 mg/L
5.01 mg/L
5.02 mg/L
Analysis
Time
14:36:37
14:36:37
14:36:50
14:36:50
14:37: 03
14:37:03
14:37:16
14:37: 16
14: 37:29
14:37:29
14:37:42
14:37:42
14:37:55
14:37:55
14:38:07
14:38 : 07

-------
Date: 1/27/2006 2:39:10 EM
Metnoa: ±-T:-M
9 Mn 257
9 Cu 324
10 Mn 257
10 Cu 324
.610
.752
.610
.752
1873916.8
497158.3
1872973.8
496581.7
1871078.4
487710.6
1870135.3
487134.0
5
5
5
5
.01 mg/L
.03 mg/L
.01 mg/L
.02 mg/L
Mean Data: cv

Analyte
Mn 257.610
Cu 324.752


Mean Corrected
Intensity
1866554.1
485903.9
Calib
Cone . Units
5.00 mg/L
5.01 mg/L
5.
5.
5.
5.

01
03
01
02

mg/L
mg/L
mg/L
mg/L

14
14
14
14

:38
:38
: Jb
:38

:20
:20
:33
:33

Sample
Std
0
0
.Dev.
.016
.019
Cone. Units
5.00 mg/L
5.01 mg/L

Std
0
0
.Dev.
.016
.019
RSD
0.31%
0.38%

-------
Method: NEW Al ROUTINE
                                                Page   1
                                                                           Date: 1/27/2006 2:50:42 EM
Analysis Begun

 Jtart Time: 1/27/2006 2:46:25 EM                  Elasnia On Time: 1/27/2006 2:02:19 EM
Logged In Analyst: sammy                          Technique: ICE Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

Sanple Information File: C:\pe\sammy\Sample Information\012706-l.sif
Batch ID: 012706-1
Results Data Set: 012706-1
Results Library: C:\pe\sammy\Results\Results.mdb
Method Loaded
Method Name: NEW Al ROUTINE
IEC File: iec l.iec
Method Description: NEW Al ROUTINE
Sequence No. : 1
Sanple ID: Calib Blank 1
Analyst:
Initial Sample Wt:
Dilution:
Method Last Saved: 1/24/2006 10:55:40 AM
MSF File:
Autosampler Location: 0
Date Collected: 1/27/2006 2:46:25 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: Calib Blank 1
Mean Corrected
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Atit
>bt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mat
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Intensity
4117890.7
256
-73
63
4642
548
-65
-8
-70
1756
10
123
-174
-122
429
10364
-4
2907
2765
4195
134
277
394
18928
16
40
7
157
-10
1428
2921
2
-1615
10
-4
249
.5
.2
.9
.6
.4
.7
.6
.6
.5
.2
.1
.8
.2
.6
.6
.1
.0
.5
.9
.1
.6
.1
.2
.7
.3
.9
.4
.0
.1
.4
.9
.5
.2
.6
.5
Std.Dev.
27189.58
19
9
6
27
27
4
3
2
24
5
6
9
87
5
41
6
37
25
176
10
26
18
81
1
1
1
9
4
651
214
3
16
5
7
45
.65
.40
.58
.57
.19
.43
.22
.15
.00
.93
.84
.61
.84
.01
.92
.49
.66
.67
.09
.54
.22
.57
.30
.82
.75
.78
.00
.25
.59
.16
.78
.04
.93
.90
.56
RSD
0.66%
7
12
10
0
4
6
37
3
1
58
5
5
71
1
0
158
1
0
4
7
9
4
0
10
4
22
5
42
45
7
129
0
58
172
18
.66%
.85%
.30%
.59%
.96%
.73%
.39%
.05%
.37%
.24%
.56%
.50%
.91%
.17%
.40%
.89%
.30%
.93%
.20%
.86%
.44%
.71%
.43%
.85%
.34%
.54%
.72%
.57%
.63%
.33%
.71%
.99%
.24%
.06%
.26%
Cone.
10.00
[0
ro
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
[0
LO
[0
[0
LO
[0
[0
[0
[0
[0
[0
[0
ro
[0
[0
[0
[0
[0
[0
[0
LO
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.UOJ
.00]
.00]
.00]
.OOJ
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
 Sequence No. :  2
 Sample  ID:  CAL 21+7  1.00
Autosampler Location:  1
Date Collected:  1/27/2006  2:50:42  EM

-------
Method: NEW Al ROUTINE

Analyst:
Initial Sample Wt:
Dilution:
                                                                           Date:  1/27/2006 3:03:29 EM
             Data Type: Original
             Initial Sample Vol:
             Sample Prep Vol:
Mean Data: CAL
Analyte
Yb
Agt
ft J +
CdT
crt
Ft
•VT-i 4-
NlT
Pbt
Znt
al +
f\j- 1
Ast
Bat
Bet
Ca 422.673t
K lOt
Lit
TUf_r +
Mgr
Mnt
Na 589.592t
o ra 4-
Set
Srt
Tit
rnl 4-
1 X 1
vt
As 193.696t
3e 196.026t
jfo 2 02. 03 It
21+7 1.00
Mean Corrected
Intensity
4046403.1
95041.2
40166.2
49380.5
106667.8
42506.0
9279.3
2736.1
16726.1
4728.1
367 . 8
38002.0
28299.1
1010496.8
268864.8
11407.1
715080.7
4208209.8
3897.5
198907.3
251031.5
490.7
353 .1
8487507.9
306680.8
203.0
78517.9
367.8
510.2
1948.8

Std.Dev.
19302.97
754.08
305.59
424.61
914.57
397.76
81.42
17.39
127.73
53.03
4.76
173.95
261.94
2177.09
1567.12
112.61
3900.11
48673.94
40.60
271.43
1113.18
47.51
16.13
67457.88
751.19
2.44
667.58
4.76
12.45
61.74

RSD
0.48%
0.79%
0.76%
0.86%
0.86%
0.94%
0.88%
0.64%
0.76%
1.12%
1.29%
0.46%
0.93%
0.22%
0.58%
0.99%
0.55%
1.16%
1.04%
0.14%
0.44%
9.68%
4.57%
0.79%
0.24%
1.20%
0.85%
1.29%
2.44%
3.17%
Calib
Cone. Units
9.83 mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[10.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
[1.00] mg/L
 Sequence No.:  3
 Sample ID:  CAL MIX 2A
 Analyst:
 Initial Sample Wt:
 Dilution:
              Autosampler Location:  2
              Date Collected:  1/27/2006 2:56:07  EM
              Data Type:  Original
              Initial Sample Vol:
              Sample Prep Vol:
 Mean Data: CAL MIX 2A
                    Mean Corrected
 Analyte               Intensity
 Yb                   4067094.8
 Na 330.237t             2241.8
 Na 589.592t          3034250.4
 Std.Dev.   RSD
35459.93   0.87%
   44.33   1.98%
 2758.62   0.09%
        Calib
  Cone.  Units
   9.88  mg/L
[10.00]  mg/L
[10.00]  mg/L
 Sequence No.: 4
 Sample ID: CAL MIX 3A
 Analyst:
 Initial Sample Wt:
 Dilution:
              Autosampler Location: 3
              Date Collected: 1/27/2006 2:59:36 PM
              Data Type: Original
              Initial Sample Vol:
              Sample Prep Vol:
Mean Data:
Analyte
Yb
Cot
Pt
CAL MIX 3A
Mean Corrected
Intensity
4147958.0
23079.7
2202.1

Std.Dev.
14777.51
44.33
4.06

RSD
0.36%
0.19%
0.18%
Calib
Cone. Units
10.1 mg/L
[2.00] mg/L
[10.00] mg/L

-------
Method: NEW Al ROUTINE
                                                Page
                                                                           Date: 1/27/2006 3:18:22 PM
Sequence No.: 5
Sample ID: CAL MIX 4A
Analyst:
Initial Sample Wt:
 Jilution:
                                                  Autosampler Location: 4
                                                  Date Collected: 1/27/2006 3:03:29 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Mean Data: CAL MIX 4A
                   Mean Corrected
                      Intensity
Analyte
Yb
Crt
Znt
Alt
Snt
                     4060531.2
                      259057.1
                       88216.4
                       49318.9
                        6487.2
                             Calib
 Std.Dev.    RSD        Cone.  Units
35403.43   0.87%        9.86  mg/L
  638.80   0.25%      [5.00]  mg/L
  161.26   0.18%      [5.00]  mg/L
  834.86   1.69%     [10.00]  mg/L
   95.49   1.47%      [4.00]  mg/L
Sequence No.: 6
Sample ID: CAL MIX 5A
Analyst:
Initial Sample Wt:
Dilution:
                                                  Autosampler Location: 5
                                                  Date Collected: 1/27/2006 3:07:04 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Mean Data:

Analyte
Yb
Fet
Nit
Pbt
Mgt
CAL MIX 5A







Mean Corrected
Intensity
4055412.3
427832
18761
27855
40359
.5
.0
.7
.3
Std.
30403
608
37
60
110
Dev.
.69
.40
.44
.95
.86
RSD
0.75%
0
0
0
0
.14%
.20%
.22%
.27%
Cone.
9.85
[10
[2
[10
[10
.00]
.00]
.00]
.00]

Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
Sequence No. : 7
Sample  ID: CAL MIX 1A
Analyst:
 .Initial Sample Wt:
Dilution:
                                                  Autosampler Location: 6
                                                  Date Collected: 1/27/2006 3:10:30 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Mean Data: CAL MIX 1A

Analyte
Yb
Cdt
Cut
Bt
Bat
Ca 315.887t
Ca 422.673t
Mnt
Mean Corrected
Intensity
4012478.8
161962
432307
159042
57081
483590
5166298
825127
.3
.1
.5
.8
.2
.1
.9
Std.Dev.
29415.92
529
1619
333
147
1813
51964
5614
.89
.51
.28
.73
.89
.63
.58
RSD
0.73%
0
0
0
0
0
1
0
.33%
.37%
.21%
.26%
.38%
.01%
.68%
Cone.
9.74
[4
[4
[4
[2
[20
[20
[4
.00]
.00]
.00]
.00]
.00]
.00]
.00]
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Sequence No. : 8
Sample  ID: Ca+Na 50 ppm K 20ppm
Analyst:
Initial Sample Wt:
Dilution:
                                                  Autosampler Location: 7
                                                  Date Collected: 1/27/2006 3:14:46 PM
                                                  Data Type: Original
                                                  Initial Sample Vol:
                                                  Sample Prep Vol:
Mean Data:  Ca+Na 50 ppm K 20ppm
Analyte
Yb
Ca  315.887t
K 766.490  20t
Na  330.237t
                   Mean Corrected
                      Intensity
                     3966352.4
                     1199498.4
                     2047997.8
                       12293.0
                             Calib
 Std.Dev.   RSD        Cone. Units
40190.91   1.01%        9.63 mg/L
 2112.16   0.18%     [50.00] mg/L
 4664.99   0.23%     [20.00] mg/L
  166.10   1.35%     [50.00] mg/L

-------
Method: NEW Al ROUTINE
Page
                                                       4
                                                                           Date: 1/27/2006 3:25:55 EM
Sequence No.: 9
Sample ID: AsSbSeMo4ppmSi2ppm
Analyst:
Initial Sample Wt:
 dilution:
  Autosampler Location:  8
  Date Collected: 1/27/2006 3:18:22 EM
  Data Type: Original
  Initial Sample Vol:
  Sample Erep Vol:
Mean Data: AsSbSeMo4ppmSi2ppm
Mean Corrected
Analyte
Yb
Ast
Sbt
Set
Sit
Tit
Mo 202.031t
Calibration
Analyte
Ag
Cd
Cr
Cu
Fe
Ni
Pb
Zn
Al
As
B
Ba
Be
Ca 315.887
"a 422.673
Jo
K 10








Summary
Stds.
1
2
2
2
2
2
2
2
2
2
2
2
1
2
2
2
1
K 766.490 20 1
Li
Mg
Mn
Na 330.237
Na 589.592
P
Sb
Se
Si
Sn
Sr
Ti
Tl
V
As 193.696
Se 196.026
Mo 202.031
1
2
2
2
2
1
2
2
1
1
1
1
2
1
1
1
2
Intensity
3967665.8
1560.2
2816.7
1506.2
22373.5
805.4
8421.5

Equation
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Lin Thru 0
Std.Dev. RSD
6272.18 0.16%
26.48 1.70%
23.72 0.84%
44.21 2.94%
116.69 0.52%
8.13 1.01%
380.05 4.51%

Intercept
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Cone.
9.64
[4.00]
[4.00]
[4.00]
[2.00]
[4.00]
[4.00]

Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

Slope Curvature
95040
40470
51720
108000
42780
9360
2785
17610
4930
388.7
39660
28490
1010000
24020
258300
11510
71510
102400
4208000
4035
205800
245.0
302900
220.2
691.6
375.2
11190
1622
8488000
306700
201.4
78520
367.8
510.2
2096
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000










Corr. Coef. Reslope
1.000000
0.999998
0.999959
0.999995
1.000000
0.999991
0.999998
0.999950
0.999992
0.999909
0.999946
0.999994
1.000000
0.999996
0.999998
0.999989
1.000000
1.000000
1.000000
0.999994
0.999964
0.999855
0.999853
1.000000
0.997374
0.999892
1.000000
1.000000
1.000000
1.000000
0.999998
1.000000
1.000000
1.000000
0.999846
Sequence No.:  10
Sample ID: cri
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location:  9
  Date Collected:  1/27/2006 3:22:21 EM
  Data Type:  Original
  Initial Sample Vol:
  Sample Erep Vol:
Mean Data: cri

Analyte
Xb

Mean Corrected
Intensity
4006585.0

Calib
Cone . Units
9.73 mg/L


Std.Dev.
0.032

Sample
Cone. Units Std.Dev. RSD
0.33%

-------
Method: HEW Al ROUTINE
Agt
Cdt
Crt
"ut
Ff* +
Nit
PHt
Znt
Al t
Ast
Rt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
vt
As 193.696t
Se 196.026t
Mo 202.031t
2367.5
999.6
1200.6
2747.6
1117 6
226.9
50.7
478.1
560.2
36.5
4683.2
710.0
25176.9
2711.8
29300.0
279.5
16630.4
16116.6
86212.8
475.4
4929.6
40.0
54616.9
28.6
72.1
28.9
257.2
82.9
212445.7
7662.2
16.3
1884.4
36.5
44.4
139.1
Eage 5
0.025 mg/L
0.025 mg/L
0.023 mg/L
0.025 mg/L

^"0.024 mg/L ,S2-
0.027 mg/L
0.114 mg/L
0.094 mg/L
0.118 mg/L
0.025 mg/L
0.025 mg/L
0.113 mg/L
0.113 mg/L
0.024 mg/L
0.233 mg/L
0.157 mg/L
0.020 mg/L
0.118 mg/L
0.024 mg/L
0.163 mg/L
0.180 mg/L
0.130 mg/L
0.104 mg/L
0.077 mg/L
0.023 mg/L
0.051 mg/L
0.025 mg/L
0.025 mg/L
0.081 mg/L
0.024 mg/L
0.099 mg/L
0.087 mg/L
0.066 mg/L
0.0004
0.0001
0.0006
0.0008
/ 0.0012
^ 0.0005
0.0041
0.0002
0.0044
0.0198
0.0113
0.0002
0.0002
0.0005
0.0008
0.0003
0.0030
0.0021
0.0003
0.0009
0.0002
0.0103
0.0010
0.0085
0.0069
0.0041
0.0023
0.0015
0.0002
0.0016
0.0160
0.0003
0.0209
0.0042
0.0235
Date: 1/27/2006 3:30:24 EM
0.025 mg/L
0.025 mg/L
0.023 mg/L
0.025 mg/L
0.026 mg/L
0.024 mg/L
0.018 mg/L
0.027 mg/L
0.114 mg/L
0.094 mg/L
0.118 mg/L
0.025 mg/L
0.025 mg/L
0.113 mg/L
0.113 mg/L
0.024 mg/L
0.233 mg/L
0.157 mg/L
0.020 mg/L
0.118 mg/L
0.024 mg/L
0.163 mg/L
0.180 mg/L
0.130 mg/L
0.104 mg/L
0.077 mg/L
0.023 mg/L
0.051 mg/L
0.025 mg/L
0.025 mg/L
0.081 mg/L
0.024 mg/L
0.099 mg/L
0.087 mg/L
0.066 mg/L
0.0004
0.0001
0.0006
0.0008
0.0012
0.0005
0.0041
0.0002
0.0044
0.0198
0.0113
0.0002
0.0002
0.0005
0.0008
0.0003
0.0030
0.0021
0.0003
0.0009
0.0002
0.0103
0.0010
0.0085
0.0069
0.0041
0.0023
0.0015
0.0002
0. 0016
0.0160
0.0003
0.0209
0.0042
0.0235
1.46%
0.48%
2 . 48%
3.25%
4.73%
1.94%
22.55%
0.92%
3.91%
21.06%
9.58%
0.95%
0.89%
0 .40%
0.69%
1.19%
1.30%
1.34%
1.23%
0. 80%
0.73%
6.32%
0.57%
6.57%
6.63%
5.28%
10.10%
2.95%
0. 60%
6. 31%
19.75%
1.34%
21.06%
4.87%
35.42%
Sequence No.:  11
Sample ID: icb
Analyst:
Initial Sample Wt:
Dilution:
Autosanpler Location: 10
Date Collected: 1/27/2006 3:26:53 EM
Data Type: Original
Initial Sanple Vol:
Sample Erep Vol:
Mean Data: icb
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Ja 330.237t
Mean Corrected
Intensity Cone .
3974270
10
-16
-6
231
-61
-15
-3
4
-113
-9
1845
„ n
-229
-290
-3733
-3
-17
-30
-1619
-19
-130
-9
.8
.1
.3
.5
.6
•6
9.65
0.000
0.000
0.000
0.002
-0.001
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
. 8 X-"0 . 0 02"mcf/L
.1
.6
.5
.8
.6
.7
.8
.9
.9
.8
.9
.0
.6
.1
.4
.1
^i=g-re-ei"^
0.000
-0.023
-0.025
0.047
0.000
0.000
-0.012
-0.014
0.000
0.000
0.000
0.000
-0.005
-0.001
-0.037
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.055
.0006
.0002
.0002
.0005
.0002
.0007
.0013
.0000
.0035
.0012
.0049
.0000
.0000
.0003
.0001
.0004
.0004
.0001
.0000
.0039
.0000
.0333
Cone.

0.000
0.000
0.000
0.002
-0.001
-0.002
-0.001
0.000
-0.023
-0.025
0.047
0.000
0.000
-0.012
-0.014
0.000
0.000
0.000
0.000
-0.005
-0.001
-0.037
Sample
Units

mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

.0006
.0002
.0002
.0005
.0002
.0007
.0013
.0000
.0035
.0012
.0049
.0000
.0000
.0003
.0001
.0004
.0004
.0001
.0000
.0039
.0000
.0333
RSD
0.57%
545.83%
46.08%
177 .02%
23.44%
13.68%
38.97%
121.27%
9.17%
15.23%
4. 62%
10.56%
8.72%
18.10%
2.82%
0. 98%
121.79%
142.86%
31.17%
7.93%
83.41%
7.13%
89.40%

-------
Method: NEW Al ROUTINE
Na 589.592t
Pt
sbt
Set
Jit
q-n-f
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
634.
— 1
16.
-14.
12.
-1.
-2473.
-1562.
-1.
-48.
-9.
-17.
-167.
9
8
1
2
2
7
5
0
0
4
8
6
6
0.002
-0.008
0.023
-0.038
0.001
-0.001
0.000
-0.005
-0.005
-0.001
-0.027
-0.035
-0.080
Page 6
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0
0
0
0
0
0
0
0
0
0
0
.0008
.0024
.0025
.0208
.0008
.0041
.0000
.0001
.0073
.0003
.0012
.0113
.0035
0
-0
0
-0
0
-0
0
-0
-0
-0
-0
-0
-0
.002
.008
.023
.038
.001
.001
.000
.005
.005
.001
.027
.035
.080
Date: 1/27/2006 3:
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.0008
0.0024
0.0025
0.0208
0.0008
0.0041
0.0000
0.0001
0.0073
0.0003
0.0012
0.0113
0.0035
41:25 EM
39.05%
30.24%
10.63%
55.14%
73.54%
405.87%
5.00%
2.33%
155.12%
51.67%
4.62%
32.81%
4.39%
Sequence No.:  12
Sample ID: icv
Analyst:
Initial Sample Wt:
Dilution:
Autosampler location: 11
Date Collected: 1/27/2006 3:31:22 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: icv

Analyte
Yb
Agt
Cdt
Crt
Cut
Nit
DV\t
rDT
Znt
Alt

qx
Bat
Bet
Ca 315.887t
Ca 422.673t
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
t i
Sbt
Set
Sit
Snt
Srt
Tit
Tl t
-i- -L 1
vt
As 193.696t
Se 196.026t
Mo 202.031t

Mean Corrected
Intensity
3968670.3
46370.3
19458.3
23894.8
51634.5
22145.2
4549.4
1319.2
8262.2
13555.6
168.8
19392 .1
13804.8
505254.6
74714.7
855588.5
5535.6
356006.0
345117.4
1974038.9
11922.6
98678.0
284.5
820990.8
231.8
244.1
164.1
3140.0
1656.5
4164500.8
147722.7
93.9
38170.4
168.8
238.5
732.4

L Calib
Cone . Units
9.64 mg/L
0.488 mg/L
0.481 mg/L
0.462 mg/L
0.478 mg/L
0.518_mg/L
<;:;;"67486 mg/i 0,-
0.469 mg/L
2.75 mg/L
0.434 mg/L
0.489 mg/L
0.485 mg/L
0.500 mg/L
3.11 mg/L
3.31 mg/L
0.481 mg/L
4.98 mg/L
3.370 mg/L
0.469 mg/L
2.96 mg/L
0.479 mg/L
1.16 mg/L
2.71 mg/L
1.05 mg/L
0.353 mg/L
0.437 mg/L
0.281 mg/L
1.02 mg/L
0.491 mg/L
0.482 mg/L
0.466 mg/L
0.486 mg/L
0.459 mg/L
0.467 mg/L
0.349 mg/L


Std.Dev.
0.037
0.0046
0.0048
0.0051
0.0061
^ 0.0052
> 0.0022
0.0032
0.0048
0.037
0.0030
0.0057
0.0051
0.0008
0.032
0.012
0.0021
0.012
0.0080
0.0007
0.036
0.0050
0.047
0.007
0.031
0.0082
0.0276
0.0015
0.007
0.0008
0.0038
0.0174
0.0044
0.0032
0.0220
0.0261

Sample
Cone. Units
0.488 mg/L
0.481 mg/L
0.462 mg/L
0.478 mg/L
0.518 mg/L
0.486 mg/L
0.474 mg/L
0.469 mg/L
2.75 mg/L
0.434 mg/L
0.489 mg/L
0.485 mg/L
0.500 mg/L
3.11 mg/L
3.31 mg/L
0.481 mg/L
4.98 mg/L
3.370 mg/L
0.469 mg/L
2.96 mg/L
0.479 mg/L
1.16 mg/L
2.71 mg/L
1.05 mg/L
0.353 mg/L
0.437 mg/L
0.281 mg/L
1.02 mg/L
0.491 mg/L
0.482 mg/L
0.466 mg/L
0.486 mg/L
0.459 mg/L
0.467 mg/L
0.349 mg/L


Std.Dev.
0.0046
0.0048
0.0051
0.0061
0.0052
0.0022
0.0032
0.0048
0.037
0.0030
0.0057
0.0051
0.0008
0.032
0.012
0.0021
0.012
0.0080
0.0007
0.036
0.0050
0.047
0.007
0.031
0.0082
0.0276
0.0015
0.007
0.0008
0.0038
0.0174
0.0044
0.0032
0.0220
0.0261


RSD
0.39%
0.95%
0.99%
1.11%
1.27%
1.01%
0.46%
0.68%
1.01%
1.35%
0. 69%
1.16%
1.05%
0.16%
1.04%
0.36%
0.43%
0.24%
0.24%
0.16%
1.22%
1.04%
4.04%
0.27%
2.99%
2.32%
6.30%
0.52%
0. 69%
0.17%
0.78%
3.72%
0.91%
0.69%
4.71%
7.46%
Sequence No.: 13
Sample ID: icsab
Analyst:
Initial Sample Wt:
Dilution:
Autosampler  Location: 12
Date Collected:  1/27/2006 3:36:13 EM
Data Type: Original
Initial  Sample Vol:
Sample Prep  Vol:

-------
Method: NEW Al ROUTINE
Mean Data: icsab

Analyte
Yb
 -gt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K  lOt
K 766.490  20t
Lit
Mgt
Mnt
Ma 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
\s 193.696t
 je 196.026t
Mo 202.031t
 Sequence No.:  14
 Sanple ID:  Ifb
 Analyst:
 Initial Sanple Wt:
 Dilution:
                                                                           Date:  1/27/2006 3:47:22 EM
Mean Corrected
Intensity
3792405.4
96283.5
39115.5
47954.0
108463.4
7678013.6
9040.4
2656 7
17956.2
238317.6
362 .0
69836.6
26896.7
1019583.2
5492568.1
Saturated2
10788.5
1193681.7
1158775.9
5864783.1
478370.2
195541.6
8859.1
Saturated2
469.7
660.5
333.1
5938 .7
3261.0
8407451.4
360682.8
198.5
76386.6
362 0
470.3
1962.3
Calib
Cone. Units
9.21 mg/L
1.01 mg/L
0.966 mg/L
0.927 mg/L
1.00 mg/L
179 mg/L I Q
<-:0-."9"6~6 mgYjJ ''
1.02 mg/L
48.3 mg/L
0.931 mg/L
1.76 mg/L
0.944 mg/L
1.01 mg/L
229 mg/L
0.937 mg/L
16.7 mg/L
11.32 mg/L
1.39 mg/L
119 mg/L
0.950 mg/L
36.2 mg/L
2.13 mg/L
0.955 mg/L
0.888 mg/L
0.531 mg/L
2.01 mg/L
0.991 mg/L
1.18 mg/L
0.985 mg/L
0.973 mg/L
0.984 mg/L
0.922 mg/L
0.936 mg/L
Std.Dev.
0.020
0.006
0.0060
0.0047
0.005
1.9
0.0090
0.0123
0.003
0.29
0.0107
0.017
0.0045
0.000
2.6
0.0074
0.03
0.022
0.019
0.0
0.0055
0.17
0.050
0.0043
0.0212
0.0065
0.021
0.0030
0.008
0.0415
0.0053
0.0113
0.0352
0.0396
Sample
Cone. Units
1.01 mg/L
0.966 mg/L
0.927 mg/L
1.00 mg/L
179 mg/L
0. 966 mg/L
0.954 mg/L
1.02 mg/L
48.3 mg/L
0.931 mg/L
1.76 mg/L
0.944 mg/L
1.01 mg/L
229 mg/L
0.937 mg/L
16.7 mg/L
11.32 mg/L
1.39 mg/L
119 mg/L
0.950 mg/L
36.2 mg/L
2.13 mg/L
0.955 mg/L
0.888 mg/L
0.531 mg/L
2.01 mg/L
0.991 mg/L
1.18 mg/L
0.985 mg/L
0.973 mg/L
0.984 mg/L
0.922 mg/L
0.936 mg/L
Std.Dev.
0.006
0.0060
0.0047
0.005
1.9
0.0090
0.0123
0.003
0.29
0.0107
0.017
0.0045
0.000
2.6
0.0074
0.03
0.022
0.019
0.0
0.0055
0.17
0.050
0.0043
0.0212
0.0065
0.021
0.0030
0 . 008
0.0415
0.0053
0.0113
0.0352
0.0396
RSD
0 22%
0.61%
0.63%
0.51%
0.52%
1.09%
0.93%
1.29%
0.30%
0.61%
1.14%
0.98%
0.47%
0.03%
1.13%
0.79%
0.20%
0.19%
1.35%
0.03%
0.58%
0.47%
2.34%
0.45%
2.39%
1.23%
1.03%
0.30%
. 60%
4.21%
0.55%
1.14%
3.82%
4.23%
Autosainpler Location: 13
Date Collected: 1/27/2006 3:42:24 EM
Data Type: Original
Initial Sample Vol:
Sample Erep Vol:
Mean Data: Ifb

Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Ni f
iM-L 1
Pbt
Znt
Alt
Ast
Rt
£3 j
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
\ 766.490 20t

Mean Corrected
Intensity
3691064.0
-122.1
76124.4
98518.2
215406.0
86747.5
18525.0
5369.7
31608.0
207.9
698.4
2361.7
-33.5
1968453.9
50567.5
528805.5
22535.1
1019.0
809.2

Calib
Cone. Units
8 .96 mg/L
-0.001 mg/L
1.88 mg/L
1.90 mg/L
1.99 mg/L
2 . 03 	 mg/L
«~— ~~rT98 mg-'/'L 'i •-
C — ^TTSSnig/L
1.80 mg/L
0.042 mg/L
1.80 mg/L
0.060 mg/L
-0.001 mg/L
1.95 mg/L
2.11 mg/L
2.05 mg/L
1.96 mg/L
0.014 mg/L
0.008 mg/L


Std.Dev.
0.154
0.0006
0.018
0.016
0.005
0.035
0.016
0.013
0.015
0.0121
0.020
0.0143
0.0005
0.005
0.027
0.022
0.017
0.0018
0.0013

Sample
Cone. Units
-0.001 mg/L
1.88 mg/L
1.90 mg/L
1.99 mg/L
2.03 mg/L
1.98 mg/L
1.93 mg/L
1.80 mg/L
0.042 mg/L
1.80 mg/L
0.060 mg/L
-0 .001 mg/L
1.95 mg/L
2.11 mg/L
2.05 mg/L
1.96 mg/L
0.014 mg/L
0.008 mg/L


Std.Dev.
0.0006
0.018
0.016
0.005
0.035
0 .016
0.013
0.015
0.0121
0.020
0.0143
0.0005
0.005
0.027
0.022
0.017
0.0018
0.0013


RSD
1.72%
43.49%
0.95%
0.83%
0.27%
1.72%
0 . 80%
0.69%
0.82%
28.77%
1.11%
23.98%
41.64%
0.24%
1.26%
1.07%
0.87%
12.32%
16.35%

-------
Method: NEW Al I
Lit
Mgt
Mnt
Na 330.237t
la 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
vt
As 193.696t
Se 196.026t
Mo 202.031t
ROUTINE
7933601.0
7801.0
401402.8
-902.1
21207.1
-1.3
1063.9
578.2
2369.6
-7.6
Saturated2
635172.5
388.9
160302.6
698.4
839.3
4462.8
Page 8
1.89 mg/L
1.93 mg/L
1.95 mg/L
-3.68 mg/L
0.070 mg/L
-0.006 mg/L
1.54 mg/L
1.54 mg/L
0.212 mg/L
-0.005 mg/L
2.07 mg/L
1.93 mg/L
2.04 mg/L
1.899 mg/L
1.645 mg/L
2.129 mg/L
0.016
0.024
0.003
0.083
0.0025
0.0037
0.012
0.016
0.0218
0.0018
0.003
0.015
0.015
0.0211
0.0085
0.0104
Date: 1/27/2006 3:52:54 EM
1.89 mg/L
1.93 mg/L
1.95 mg/L
-3.68 mg/L
0.070 mg/L
-0.006 mg/L
1.54 mg/L
1.54 mg/L
0.212 mg/L
-0.005 mg/L
2.07 mg/L
1.93 mg/L
2.04 mg/L
1.899 mg/L
1.645 mg/L
2.129 mg/L
0.016
0.024
0.003
0.083
0.0025
0.0037
0.012
0.016
0.0218
0.0018
0.003
0.015
0.015
0.0211
0.0085
0.0104
0.84%
1.26%
0.14%
2.26%
3.56%
60.17%
0.79%
1.01%
10.28%
38.12%
0.13%
0.76%
0.74%
1.11%
0.52%
0.49%
Sequence No.:  15
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 14
Date Collected: 1/27/2006 3:48:21 EM
Data Type: Original
Initial Sample Vol:
Sanple Erep Vol:
Mean Data: Irb
Analyte
Yb
Agt
cat
Crt
Cut
Fet
Nit

'rrt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
p+
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity
3779385.1
-56.7
-36.0
120.7
403.6
1110.8
-13.1
-9
151
-42
-15
833
-11
-51
10701
105569
-14
2769
2653
-1134
263
102
279
25716
1
37
-10
386
-1
6111
-731
-0
48
-15
—5
-110
2
.4
.7
.8
.5
.7
.7
.2
.2
.1
.2
.1
.1
.6
.6
.4
.8
.9
.1
.7
.0
.5
.4
.9
.8
.3
.8
.3
.5
Calib
Cone. Units
9.18 mg/L
-0.001 mg/L
-0.001 mg/L
0.002 mg/L
0.004 mg/L
CU-02.fi, mg/L
/^-o.ooilHcr/L
^i»
0
-0
-0
0
0
0
0
0
-0
0
0
0
0
0
0
0
0
-0
0
-0
0
-0
-0
0
-0
-0
-0
--~ffQ-%-
.009
.009
.041
.021
.000
.000
.446
.409
.001
.039
.026
.000
.065
.000
1.14
.085
.009
.054
.028
. 035
.001
.001
.002
.004
.001
.043
.010
.053
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.070
0.0004
0.0004
0.0002
0.0001
0.0003
0.0012
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.0028
.0003
.0055
.0115
.0012
.0001
.0001
.0042
.0030
.0006
.0009
.0005
.0001
.0036
.0000
0.086
.0015
.0070
.0095
.0013
.0000
.0031
.0001
.0009
.0054
.0003
.0121
.0101
.0161
Cone.
-0.001
-0.001
0.002
0.004
0.026
-0.001
-0.003
0.009
-0.009
-0.041
0.021
0.000
0.000
0.446
0.409
-0.001
0.039
0.026
0.000
0.065
0.000
1.14
0.085
0.009
0.054
-0.028
0.035
-0.001
0.001
-0.002
-0.004
0.001
-0.043
-0.010
-0.053
:=========:
Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0.0004
0.0004
0.0002
0.0001
0.0003
0.0012
0.0028
0.0003
0.0055
0.0115
0.0012
0.0001
0.0001
0.0042
0.0030
0.0006
0.0009
0.0005
0.0001
0.0036
0.0000
0.086
0.0015
0.0070
0.0095
0.0013
0.0000
0.0031
0.0001
0.0009
0.0054
0.0003
0.0121
0.0101
0.0161
RSD
0.76%
62.32%
39.78%
10.58%
2.56%
1.21%
85.84%
83 . 69%
3.11%
62 .94%
28.33%
5.76%
29.92%
154.11%
0.94%
0.74%
46.19%
2.44%
1.77%
22.96%
5.45%
5.54%
7.57%
1.78%
79.67%
17.74%
4.69%
0.11%
339.92%
8.18%
39.36%
141.49%
42.31%
28.33%
96.42%
30. 48%
Sequence No.: 16
Sanple ID: 010302-1
\nalyst:
Autosampler  Location:  15
Date Collected:  1/27/2006  3:52:54 PM
Data Type: Original

-------
                5UTINE
                                                Page
                                                                           Date:  1/27/2006 4:01:02 EM
Initial Sample Wt:
Dilution:
Initial Sample Vol:
Sample Prep Vol:
fean Data: 010302-1
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Pbt
Znt
Alt
Ast
•a a +
Bet
Ca 315.887t
Ca 422.673t
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
pt

Set
Sit
Snt
Srt
H +
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected Calib
Intensity Cone. Units
3805515.1
-139.6
-42.3
283.0
482.1
1908.1
3 5
-12.3
152.9
-172.1
-23.1
167.9
3.2
-257.2
6201.9
61910.1
-11.3
3395.4
3265.6
-1999.0
321.0
86.8
299.0
98724.1
-0.2
11.0
-11.7
925.4
-0.9
4107.3
-1439.4
-3.7
12.0
-23.1
-5.4
-199.9
9.24 mg/L
-0.001 mg/L
-0.001 mg/L
0.005 mg/L
0.004 mg/L
0 .J3_4_5__mg/L
-0.004 mg/L
0.009 mg/L
-0.035 mg/L
-0.059 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.258 mg/L
0.240 mg/L
-0.001 mg/L
0.047 mg/L
0.032 mg/L
0.000 mg/L
0.080 mg/L
0.000 mg/L
1.22 mg/L
0.326 mg/L
-0.001 mg/L
0.016 mg/L
-0.031 mg/L
0.083 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
-0.018 mg/L
0.000 mg/L
-0.063 mg/L
-0.011 mg/L
-0.095 mg/L
Std.Dev.
0 .041
0.0004
0.0002
0.0004
0.0001
0.0007
0.0017
0.0015
0.0003
0.0021
0.0057
0.0007
0.0004
0.0000
0.0028
0.0016
0.0007
0.0010
0.0007
0.0000
0.0010
0.0001
0.121
0.0027
0.0161
0.0052
0.0017
0.0024
0.0004
0.0000
0.0001
0.0060
0.0004
0.0060
0.0040
0.0034

Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.005 mg/L
0.004 mg/L
0.045 mg/L
0.000 mg/L
-0.004 mg/L
0.009 mg/L
-0.035 mg/L
-0.059 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.258 mg/L
0.240 mg/L
-0.001 mg/L
0.047 mg/L
0.032 mg/L
0.000 mg/L
0.080 mg/L
0.000 mg/L
1.22 mg/L
0.326 mg/L
-0.001 mg/L
0.016 mg/L
-0.031 mg/L
0.083 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
-0.018 mg/L
0.000 mg/L
-0.063 mg/L
-0.011 mg/L
-0.095 mg/L

Std.Dev. RSD
0 44%
0.0004 26.52%
0.0002 14.45%
0.0004 6.82%
0.0001 3.32%
0.0007 1.67%
0.0017 444.97%
0.0015 33.07%
0.0003 3.84%
0.0021 5.92%
0.0057 9.60%
0.0007 15.46%
0.0004 396.98%
0.0000 7.48%
0.0028 1.07%
0.0016 0.68%
0.0007 73.67%
0.0010 2.07%
0.0007 2.32%
0.0000 0.75%
0.0010 1.29%
0.0001 18.67%
0.121 9.93%
0 . 0027 0 . 83%
0.0161 >999.9%
0.0052 32.50%
0.0017 5.44%
0.0024 2.88%
0.0004 77.65%
0.0000 2.53%
0.0001 2.10%
0.0060 33.23%
0.0004 248.08%
0.0060 9.60%
0.0040 37.45%
0.0034 3.57%
Sequence No.: 17
Sample ID:  010302-2
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 16
Date Collected: 1/27/2006 3:57:28 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010302-2

Analyte
Yb
Acrt
•f i-y i
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
"a 315.887t
Mean Corrected
Intensity
3705993.1
-125.1
-53.2
599.2
695.2
1273.6
-7.4
-11.5
137.1
852.7
-31.0
104.1
-6.8
-254.9
5591.7
Calib
Cone. Units
9.00 mg/L
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.006 mg/L
0.03.fi,,_mg/L
-~crTb~6~~4 mg/L
0.008 mg/L
0.173 mg/L
-0.080 mg/L
0.003 mg/L
0.000 mg/L
0.000 mg/L
0.233 mg/L

Std.Dev.
0.091
0.0004
0.0001
0.0005
0.0011
0.0003
0.0006
0.0030
0.0003
0.0044
0.0031
0.0004
0.0003
0.0000
0.0014

Sample
Cone. Units

-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.006 mg/L
0.030 mg/L
-0.001 mg/L
-0.004 mg/L
0.008 mg/L
0.173 mg/L
-0.080 mg/L
0.003 mg/L
0.000 mg/L
0.000 mg/L
0.233 mg/L


Std.Dev.

0..0004
0.0001
0.0005
0.0011
0.0003
0.0006
0.0030
0.0003
0.0044
0.0031
0.0004
0.0003
0.0000
0.0014


RSD
1 . 01 0
33.56%
5.96%
4.33%
16.36%
1.17%
78.45%
73.77%
3.40%
2.53%
3.95%
15.64%
126.44%
15.22%
0.61%

-------

Ca 422.673t
Cot
K lOt
K 766.490 20
jit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
L ROUTINE
53745.4
-18.1
3072.1
t 2946.5
-1982.3
321.9
184.7
402.0
107939.0
1.8
12.7
-17.1
1485.6
-1.6
3935.6
-1537.7
-0.1
29.6
-31.0
-9.5
-221.8
Page
0.208 mg/L
-0.002 mg/L
0.043 mg/L
0.029 mg/L
0.000 mg/L
0.080 mg/L
0.001 mg/L
1.64 mg/L
0.356 mg/L
0.008 mg/L
0.018 mg/L
-0.045 mg/L
0.133 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
0.000 mg/L
0.000 mg/L
-0.084 mg/L
-0.019 mg/L
-0.106 mg/L
10
0.0012
0.0007
0.0007
0.0002
0.0000
0.0052
0.0001
0.056
0.0017
0.0049
0.0090
0.0177
0.0028
0.0003
0.0000
0.0001
0.0095
0.0002
0.0033
0.0063
0.0009
Date
0.208 mg/L
-0.002 mg/L
0.043 mg/L
0.029 mg/L
0.000 mg/L
0.080 mg/L
0.001 mg/L
1.64 mg/L
0.356 mg/L
0.008 mg/L
0.018 mg/L
-0.045 mg/L
0.133 mg/L
-0.001 mg/L
0.000 mg/L
-0.005 mg/L
0.000 mg/L
0.000 mg/L
-0.084 mg/L
-0.019 mg/L
-0.106 mg/L
: 1/27/2006 4
0.0012
0.0007
0.0007
0.0002
0.0000
0.0052
0.0001
0.056
0.0017
0.0049
0.0090
0.0177
0.0028
0.0003
0.0000
0.0001
0.0095
0.0002
0.0033
0.0063
0.0009
:06:46 EM
0.60%
44.15%
1.66%
0.57%
0.98%
6.55%
6.10%
3.42%
0.48%
59.10%
48.72%
38.88%
2.09%
30.67%
1.55%
1.70%
>999.9%
58.12%
3.95%
33.63%
0.81%
Sequence No.:  18
Sample ID: 010302-3
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 17
Date Collected: 1/27/2006 4:02:02 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010302-3
Analyte
Yb
Agt
Cdt
Olwl )
Crt
:ut
Fet
Nit
PVi +
JrJJ 1
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mn +
1VJJ1 |
Ma 330.237t
Na 589.592t
Pt
01-,+
OJJ I
Set
Sit
q-nf
011 ]
^r-t
O J_ |
Tit
rrTI 4-
j. -L 1
\r+
v |
As 193.696t
Se 196.026t
Mo 202.031t
!
Mean Corrected
Intensity
3745097.8
-84.1
-53.1
984.0
601.9
2858.9
-11.6
-6.9
182.8
19.7
-32.0
160.7
1.5
-276.2
6074.6
59058.4
-12.2
4115.7
3812.5
-1716.3
313.9
67.6
387.3
98728.7
6.0
4. 6
-15.0
1086.9
-3.2
4237.1
-1562.0
-0.2
39.8
-32.0
-14.2
-228.6
Calib
Cone . Units
9.09 mg/L
-0.001 mg/L
-0.001 mg/L
0.019 mg/L
0.006 mg/L
0 ...Q62_mg/L
(--" -6. 001,,mg/L
•~--~~B=:Q:Q2 mg/L
0.010 mg/L
0.004 mg/L
-0.082 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.253 mg/L
0.229 mg/L
-0.001 mg/L
0.058 mg/L
0.037 mg/L
0.000 mg/L
0.078 mg/L
0.000 mg/L
1.58 mg/L
0.326 mg/L
0.027 mg/L
0.007 mg/L
-0.040 mg/L
0.097 mg/L
-0.002 mg/L
0.000 mg/L
-0.005 mg/L
-0.001 mg/L
0.001 mg/L
-0.087 mg/L
-0.028 mg/L
-0.109 mg/L
Std.Dev.
0.097
0.0007
0.0001
0.0021
0.0007
0.0003
0.0002
0.0035
0.0004
0.0030
0.0033
0.0003
0.0002
0.0000
0.0009
0.0016
0.0008
0.0020
0.0014
0.0000
0.0041
0.0001
0.085
0.0047
0.0077
0.0026
0.0144
0.0010
0.0022
0.0000
0.0001
0.0138
0.0004
0.0035
0.0086
0.0023
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.019 mg/L
0.006 mg/L
0.067 mg/L
-0.001 mg/L
-0.002 mg/L
0.010 mg/L
0.004 mg/L
-0.082 mg/L
0.004 mg/L
0.000 mg/L
0.000 mg/L
0.253 mg/L
0.229 mg/L
-0.001 mg/L
0.058 mg/L
0.037 mg/L
0.000 mg/L
0.078 mg/L
0.000 mg/L
1.58 mg/L
0.326 mg/L
0.027 mg/L
0.007 mg/L
-0.040 mg/L
0.097 mg/L
-0.002 mg/L
0.000 mg/L
-0.005 mg/L
-0.001 mg/L
0.001 mg/L
-0.087 mg/L
-0.028 mg/L
-0.109 mg/L
Std.Dev.
0.0007
0.0001
0.0021
0.0007
0.0003
0.0002
0.0035
0.0004
0.0030
0.0033
0.0003
0.0002
0.0000
0.0009
0.0016
0.0008
0.0020
0.0014
0.0000
0.0041
0.0001
0.085
0.0047
0.0077
0.0026
0.0144
0.0010
0.0022
0 .0000
0.0001
0.0138
0.0004
0.0035
0.0086
0.0023
RSD
1.07%
80.59%
6.69%
10 . 89%
13.02%
0.41%
19.21%
143.31%
3.52%
74.90%
3.97%
8.02%
465.93%
6.36%
0.37%
0.70%
80.06%
3.43%
3.80%
8.37%
5.23%
23.60%
5.37%
1.45%
28.31%
38.88%
36.01%
1.04%
113.23%
1.98%
2.83%
>999.9%
81.69%
3 . 97%
30.94%
2.14%

-------
Method: NEW Al ROUTINE
                                                Page  11
                                                                           Date: 1/27/2006 4:14:56 EM
Sequence No.: 19
Sample ID: 010218-1
\nalyst:
.nitial Sample Wt:
Dilution:
Autosampler Location: 18
Date Collected: 1/27/2006 4:06:46 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Analyte
Yb
Agt
Cdt
Crt
Cut
"NTi +
Pbt
Znt
Alt
Ast
Bt
Bat
Bet

C 422

Cot
K lOt
K 766.4
Lit
Mgt
Mnt
>bt
jet
Sit
Srt
Tit
Tit
Vt
As 193.
Se 196.
Mo 202.
ba: 010218-1
Mean Corrected
Intensity
-57.7
527.3
750.1
2639.8
20206.5
-11.7
429.5
-193.4
-36.0
3303.1
152.4
-239.3
887t 5783.6
673t 56533.3
5 0
4ft 67 4


"
237t "JI'.I
-0.6
-10.7
0 7
4130.0
-2110.9
-2.9
54.0
696t -36.0
026t -9.9
031t -243.2
Calib
Cone . Units
9.19 mg/L
-0.001 mg/L
-0.001 mg/L
0.010 mg/L
0.007 mg/L
C" 2 . lj§.--3tig/L
-1)76 04 mg/L
0.024 mg/L
0.083 mg/L
0.005 mg/L
0.000 mg/L
0.241 mg/L
0.219 mg/L
0 000 mg/L
0 068 mg/L
0 046 mg/L
0 000 mg/L
0 075 ma/L
1.42 mg/L
0.357 mg/L
-0.001 mg/L
~n"n7T mg^
0.000 mg/L
0.000 mg/L
-0.007 mg/L
-0.014 mg/L
0.001 mg/L
-0.098 mg/L
-0.019 mg/L
-0.116 mg/L
Std.Dev.
0 . 0004
0.0003
0.0002
0.0004
0.0007
0.011
0.0036
0.0004
0.0031
0.0088
0.0014
0.0003
0.0000
0.0018
0 .0011
0.0008
0.0005
0.0004
0.0000
0.0007
0.0000
o-.'lli
o" 0007
0.0016
0.0000
0.0002
0.0114
0.0003
0.0093
0.0108
0.0013
Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.010 mg/L
0.007 mg/L
0.062 mg/L
z . ID mg/ii
-0.004 mg/L
-0.03,9 mg/L
-0.093 mg/L
0.083 mg/L
0.005 mg/L
0.000 mg/L
0.241 mg/L
0.219 mg/L
0.000 mg/L
0.068 mg/L
0 .046 mg/L
0.000 mg/L
0.075 mg/L
°i°°426 mg/L
-0 .001 mg/L
o"o73 mg/L
0.000 mg/L
0.000 mg/L
-0.007 mg/L
-0.014 mg/L
0.001 mg/L
-0.098 mg/L
-0.019 mg/L
-0.116 mg/L
. 	 — =•—
Std.Dev.
0.0004
0.0003
0.0002
0.0004
0.0007
0 Oil

0.0004
0.0031
0.0088
0.0014
0.0003
0.0000
•
0 . 0011
0 . 0008 .
0.0005
0.0004
0.0000
0.0007
0.0000
0.0081
0.0007
0.0016
0.0000
0.0002
0.0114
0.0003
0.0093
0.0108
0.0013
	 	 	
RSD
0.04%
19.14%
1.97%
6.09%
1.14%

1.46%
7.86%
9.54%
1.72%
5.20%
13.81%

• *° °
184 . 44 o
0.72%
0.77%
5.27%
0.96%
0.84%
629.25%
28.37%
0.98%
354.30%
0.66%
2.24%
79.38%
42.88%
9.54%
55.64%
1.14%
 Sequence No.:  20
 Sample ID:  010218-2
 Analyst:
 Initial Sample Wt:
 Dilution:
 Autosampler Location:  19
 Date Collected:  1/27/2006 4:11:21 PM
 Data Type:  Original
 Initial Sample Vol:
 Sample Prep Vol:
Mean Data: 010218-2

Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
\st
Mean Corrected
Intensity
3746908.9
-111.3
-34.7
602.5
974.9
2777.3
2223.5
-17.2
514.0
-208.5
-31.3
Calib
Cone. Units
9.10 mg/L
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.009 mg/L
0.065....mg/L
^•^..XaS-mg/L"
^".006 mg/L
0.029 mg/L
-0.042 mg/L
-0.080 mg/L

Std.Dev.
0.088
0.0005
0.0003
0.0005
0.0002
0.0008
0.0023
0.0016
0.0004
0.0003
0.0102

Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.012 mg/L
0.009 mg/L
0.065 mg/L
0.238 mg/L
-0.006 mg/L
0.029 mg/L
-0.042 mg/L
-0.080 mg/L


Std.Dev.
0.0005
0.0003
0.0005
0.0002
0.0008
0.0023
0.0016
0.0004
0.0003
0.0102


RSD
0.97%
38.53%
36.02%
4.53%
1.70%
1.29%
0.96%
26.07%
1.39%
0.63%
12.66%

-------
                                                                           Date:  1/27/2006 4:19:31 EM
Method: HEW Al ROD
Bt
Bat
Bet
-.a 315.887t
,a 422.673t
Cot
K 10t
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
	 — ===
TJ.KIS
726.2
1.4
-230.1
5208.5
50741.0
-8.4
6338.3
6126.4
-2186.3
284.0
495.0
373.1
133504.3
3.1
-4.4
-16.2
701.9
3.1
4569.9
-2126.3
-4.5
32.1
-31.3
-14.4
-246.6

0.018 mg/L
0.000 mg/L
0.000 mg/L
0.217 mg/L
0.196 mg/L
-0.001 mg/L
0.089 mg/L
0.060 mg/L
-0.001 mg/L
0.070 mg/L
0.002 mg/L
1.52 mg/L
0.441 mg/L
0.014 mg/L
-0.006 mg/L
-0.043 mg/L
0.063 mg/L
0.002 mg/L
0.001 mg/L
-0.007 mg/L
-0.022 mg/L
0.000 mg/L
-0.085 mg/L
-0.028 mg/L
-0.118 mg/L

0.0002
0.0001
0.0000
0.0007
0.0006
0.0002
0.0023
0.0014
0.0000
0.0009
0.0000
0.040
0.0022
0.0126
0.0055
0.0068
0.0024
0.0019
0.0000
0.0001
0.0078
0.0004
0.0108
0.0113
0.0025

0.018 mg/L
0.000 mg/L
0.000 mg/L
0.217 mg/L
0.196 mg/L
-0.001 mg/L
0.089 mg/L
0.060 mg/L
-0.001 mg/L
0.070 mg/L
0.002 mg/L
1.52 mg/L
0.441 mg/L
0.014 mg/L
-0.006 mg/L
-0.043 mg/L
0.063 mg/L
0.002 mg/L
0.001 mg/L
-0.007 mg/L
-0.022 mg/L
0.000 mg/L
-0.085 mg/L
-0.028 mg/L
-0.118 mg/L

0.0002
0.0001
0.0000
0.0007
0.0006
0.0002
0.0023
0.0014
0.0000
0.0009
0.0000
0.040
0.0022
0.0126
0.0055
0.0068
0.0024
0.0019
0.0000
0.0001
0.0078
0.0004
0.0108
0.0113
0.0025

0.90%
279.87%
15.04%
0.30%
0.30%
22 .03%
2.56%
2.42%
3.75%
1.26%
1.47%
2.65%
0.50%
89.01%
87.59%
15.73%
3.77%
99.73%
3.77%
1.41%
34.83%
105.95%
12.66%
40.06%
2.12%

Sequence No.:  21
Sattple ID: 010218-3
Analyst:
Initial Sample Wt:
Dilution:
Autosampler Location: 20
Date Collected: 1/27/2006 4:15:56 EM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: 010218-3
\nalyte
A
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
Snt
Srt
Tit
Tit
7t
Mean Corrected
Intensity Cone.
3627157
-109
-56
403
367
924
-8
-14
88
-171
-35
39
-26
-248
5398
50852
-22
3181
3040
-2052
286
4
404
83499
0
-3
-16
855
-4
3901
-1820
-3
57
.0
.2
.1
.4
.9
.3
.5
.7
.0
.8
.2
.4
.3
.2
.7
.5
.0
.9
.6
.4
.5
.0
.0
.3
.8
.1
.9
.2
.7
.3
.3
.2
.9
!
-0
-0
0
0
0
c-o
nror
0
-0
-0
0
-0
0
0
0
-0
0
0
0
0
0
0
0
-0
-0
0
-0
0
-0
-0
0
3.81
.001
.001
.008
.003
.022
fob"!
ro'oT
.005
.035
.090
.001
.001
.000
.225
.197
.002
.044
.030
.000
.071
.000
1.65
.276
.004
.004
.045
.076
.003
.000
.006
.016
.001
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
jngYL
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.
0-1 c -1
. 151
0.0004
0.0003
0.0005
0.0011
0.0003
0.0014
0.0012
0.0002
0.0073
0.0076
0.0003
0.0001
0.0000
0.0036
0.0015
0.0000
0.0014
0.0010
0.0000
0.0008
0.0001
0.062
0.0013
0.0104
0.0090
0.0156
0.0008
0.0016
0.0000
0.0002
0.0205
0.0007
Cone.
-0.001
-0.001
0.008
0.003
0.022
-0.001
-0.005
0.005
-0.035
-0.090
0.001
-0.001
0.000
0.225
0.197
-0.002
0.044
0.030
0.000
0.071
0.000
1.65
0.276
0.004
-0.004
-0.045
0.076
-0.003
0.000
-0.006
-0.016
0.001

Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

Std.Dev.
0.0004
0.0003
0.0005
0.0011
0.0003
0.0014
0.0012
0.0002
0.0073
0.0076
0.0003
0.0001
0.0000
0.0036
0.0015
0.0000
0.0014
0.0010
0.0000
0.0008
0.0001
0.062
0.0013
0.0104
0.0090
0.0156
0.0008
0.0016
0.0000
0.0002
0.0205
0.0007

RSD
•1.71%
37.22%
21.62%
6.14%
32.17%
1.26%
152.01%
23.17%
4.64%
21.06%
8.42%
27.81%
7.43%
18.29%
1.62%
0.76%
0.79%
3.06%
3.29%
1.02%
1.17%
525.17%
3.75%
0.49%
294.26%
201.97%
34.57%
1.06%
54.27%
1.56%
2.62%
128.66%
91.10%

-------
Method: NEW Al ROUTINE
As 193.
Se 196.
Mo 202.
696t
026t
031t
-35
-9
-250
.2
.1
.0
-0.
-0.
-0.
096
018
119
Page
mg/L
mg/L
mg/L
13
0.0080
0.0051
0.0011
Date: 1/27/2006 4:28:43 EM
-0.096
-0.018
-0.119
mg/L
mg/L
mg/L
0.0080
0.0051
0.0011
8.42%
28.75%
0.91%
Sequence No.: 22
Sample ID: 010218-4
Analyst:
Initial Sample Wt:
Dilution:
                              Autosampler  Location:  21
                              Date Collected:  1/27/2006  4:20:32 PM
                              Data Type: Original
                              Initial  Sanqple Vol:
                              Sample Prep  Vol:
Mean Data: 010218-4
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
K 766.490 20t
Lit
Mgt
Mnt
la 330.237t
Na 589.592t
P+

Set

t
Srt
Tit
TM +
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity
3681821.8
-122.8
-53.6
1075.7
990.6
2680.5
5824.0
-9.4
1591.3
-38.1
-31.9
1527.5
64.3
-247.7
9757.9
94029.6
-12.1
9868.7
9549.9
-2188.2
431.5
1513.6
374.0
127085.3
11.0
-2.3
-17.1
1110.8
1590.4
9542.5
-1775.3
-1.7
34.9
-31.9
-16.7
-250.2
Calib
Cone. Units
8.94 mg/L
-0.001 mg/L
-0.001 mg/L
0.021 mg/L
0.009 mg/L
0 J163_ mg/L
(-"6.622jmg/L
-07003 mg/L
0.090 mg/L
-0.008 mg/L
-0.082 mg/L
0.039 mg/L
0.002 mg/L
0.000 mg/L
0.406 mg/L
0.364 mg/L
-0.001 mg/L
0.138 mg/L
0.093 mg/L
-0.001 mg/L
0.107 mg/L
0.007 mg/L
1.53 mg/L
0.420 mg/L
0.050 mg/L
-0.003 mg/L
-0.045 mg/L
0.099 mg/L
0.981 mg/L
0.001 mg/L
-0.006 mg/L
-0.008 mg/L
0.000 mg/L
-0.087 mg/L
-0.033 mg/L
-0.119 mg/L
Std.Dev.
0.070
0.0005
0.0001
0.0009
0.0005
0.0001
0.0008
0.0014
0.0003
0.0042
0.0130
0.0009
0.0002
0.0000
0.0004
0.0020
0.0002
0.0005
0.0003
0.0000
0.0035
0.0001
0.008
0.0029
0.0062
0.0072
0.0058
0.0015
0.0164
0.0000
0.0001
0.0118
0.0002
0.0137
0.0060
0.0022

Sample
Cone. Units
-0.001 mg/L
-0.001 mg/L
0.021 mg/L
0.009 mg/L
0.063 mg/L
0.622 mg/L
-0.003 mg/L
0.090 mg/L
-0.008 mg/L
-0.082 mg/L
0.039 mg/L
0.002 mg/L
0.000 mg/L
0.406 mg/L
0.364 mg/L
-0.001 mg/L
0.138 mg/L
0.093 mg/L
-0.001 mg/L
0.107 mg/L
0.007 mg/L
1.53 mg/L
0.420 mg/L
0.050 mg/L
-0.003 mg/L
-0.045 mg/L
0.099 mg/L
0.981 mg/L
0.001 mg/L
-0.006 mg/L
-0.008 mg/L
0.000 mg/L
-0.087 mg/L
-0.033 mg/L
-0.119 mg/L

Std.Dev.
0.0005
0.0001
0.0009
0.0005
0.0001
0.0008
0.0014
0.0003
0.0042
0.0130
0.0009
0.0002
0.0000
0.0004
0.0020
0.0002
0.0005
0.0003
0.0000
0.0035
0.0001
0.008
0.0029
0.0062
0.0072
0.0058
0.0015
0.0164
0.0000
0.0001
0.0118
0.0002
0.0137
0.0060
0.0022

RSD
0.78%
39.64%
6.12%
4.56%
5.10%
0.22%
0.13%
41.44%
0.30%
54.50%
15.82%
2.28%
10.86%
3.33%
0.09%
0.54%
23.37%
0.37%
0.32%
1.51%
3.27%
0.98%
0.52%
0.70%
12.38%
212.22%
12.71%
1.47%
1.67%
0.54%
2 .19%
140.88%
43.93%
15.82%
18.22%
1.84%
Sequence No.:  23
Sample  ID:  010218-5
Analyst:
Initial Sanple Wt:
Dilution:
                               Autosampler Location: 22
                               Date Collected: 1/27/2006 4:25:08 PM
                               Data Type: Original
                               Initial Sample Vol:
                               Sample Prep Vol:
Mean Data:  010218-5
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Mit
Mean Corrected
   Intensity
  3730727.8
      -92.6
      -41.7
      574.5
      669.3
     2270.4
      816.6
      Calib
Cone. Units
 9.06 mg/L
  001 mg/L
  001 mg/L
0.011 mg/L
0.006 mg/L
0.053 mg/L
0.087 mg/L
Std.Dev.
  0.043
 0.0005
 0.0003
 0.0007
 0.0002
 0.0011
 0.0014
                                                                           Sample
                                                                     Cone.  Units
                              -0
  001 mg/L
0.001 mg/L
0.011 mg/L
  006 mg/L
0.053 mg/L
0.087 mg/L
0
Std.Dev.

 0.0005
 0.0003
 0.0007
 0.0002
 0.0011
 0.0014
  RSD
 0.48%
54.39%
29.
 5.
 3.
 1.
 1.
99%
06%
99%

-------
Method: NEW Al ROUTINE
Pbt
Knt
alt
•tt_L 1
\st
j T
Bat
Bet
Ca 315.887t
Ca 422.673t
PI~»+
k^O 1
K lOt
K 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Sbt

. ,
CnH-
iDIl 1
^rt
L3 J_ 1
Tit
ml +
-L-L 1
vt
As 193.696t
Se 196.026t
Mo 202.031t
-9.2
805.6
-171.8
-33.5
476.3
55.7
-273.6
5833.3
56862.7
-8.6
4979.5
4802.2
-1504.5
321.0
2039.3
328.0
114040.5
4.9
-3.0
-16.8
991.2
24.4
6536.4
-2081.1
-1.0
0.1
-33.5
-18.9
-251.6
Page 14
-0.003 mg/L
0.046 mg/L
-0.035 mg/L
-0.086 mg/L
0.012 mg/L
0.002 mg/L
0.000 mg/L
0.243 mg/L
0.220 mg/L
-0.001 mg/L
0.070 mg/L
0.047 mg/L
0.000 mg/L
0.080 mg/L
0.010 mg/L
1.34 mg/L
0.376 mg/L
0.022 mg/L
-0.004 mg/L
-0.045 mg/L
0.089 mg/L
0.015 mg/L
0.001 mg/L
-0.007 mg/L
-0.005 mg/L
0.000 mg/L
-0.091 mg/L
-0.037 mg/L
-0.120 mg/L
0.0028
0.0003
0.0021
0.0080
0.0003
0.0001
0.0000
0.0028
0.0023
0.0004
0.0014
0.0010
0.0003
0.0017
0.0002
0.121
0.0046
0.0130
0.0029
0.0030
0.0025
0.0047
0.0000
0.0002
0.0202
0.0001
0.0085
0.0100
0.0012
Date: 1/27/2006 4:
-0.003 mg/L
0.046 mg/L
-0.035 mg/L
-0.086 mg/L
0.012 mg/L
0.002 mg/L
0.000 mg/L
0.243 mg/L
0.220 mg/L
-0.001 mg/L
0.070 mg/L
0.047 mg/L
0.000 mg/L
0.080 mg/L
0.010 mg/L
1.34 mg/L
0.376 mg/L
0.022 mg/L
-0.004 mg/L
-0.045 mg/L
0.089 mg/L
0.015 mg/L
0.001 mg/L
-0.007 mg/L
-0.005 mg/L
0.000 mg/L
-0.091 mg/L
-0.037 mg/L
-0.120 mg/L
0.0028
0.0003
0.0021
0.0080
0.0003
0.0001
0.0000
0.0028
0.0023
0.0004
0.0014
0.0010
0.0003
0.0017
0.0002
0.121
0.0046
0.0130
0.0029
0.0030
0.0025
0.0047
0.0000
0.0002
0.0202
0.0001
0.0085
0.0100
0.0012
33:38 PM
84.97%
0.65%
6.09%
9.27%
2.27%
5.95%
4.30%
1.16%
1.03%
51.69%
1.97%
2.13%
69.98%
2.18%
1.59%
9.04%
1.22%
58.41%
68.71%
6.75%
2.81%
30.87%
0.83%
2.30%
424.64%
>999.9%
9.27%
27.06%
1.02%
Sequence No.: 24
Sample ID:  ccv
Analyst:
Initial Sanple Wt:
Dilution:
Autosanpler Location: 23
Date Collected: 1/27/2006 4:29:44 PM
Data Type: Original
Initial Sample Vol:
Sample Prep Vol:
Mean Data: ccv 1.

Analyte
Yb
Aat
•* "y '
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K 10t
K 766.490 20t
Lit
Mat
J. J-^J I
Mnt
Na 330.237t
Na 589.592t
Pt
Sbt
Set
Sit
<3nt
00


Mean Corrected
Intensity
3977408.4
191687
79572
98707
213710
88800
18940
5421
35268
34245
748
75838
56839
2109175
174365
2110837
22809
1736262
1685152
.2
.4
.5
.3
.6
.1
.9
.4
.1
.1
.1
.2
.4
.5
.0
.0
.0
.7
Cone.
9.66
2.02
1.97
1.91
1.98
2.08
^ 	 2.02
^--iris
2.00
6.95
1.92
1.91
1.99
2.09
7.26
8.17
1.98
24.3
16.46

Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

"mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L


Std
0
0
0
0
0
A °
,-° o
0
0
0
0
0
0
0
0
0
0

0


.Dev.
.021
.014
.010
.012
.016
.013
.011
.037
.017
.090
.006
.012
.011
.005
.044
.026
.012
0.04
.028


Cone.
2.02
1.97
1.91
1.98
2.08
2.02
1.95
2.00
6.95
1.92
1.91
1.99
2.09
7.26
8.17
1.98
24.3
16.46

Sample
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L


Std
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
Saturated2
28420
417483
148
2227111
853
1137
725
12025
6372
.9
.3
.9
.6
.6
.1
.3
.2
.5
7.04
2.03
0.608
7.35
3.88
1.64
1.93
1.07
3.93
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0.
0
0
0
0
0
0
.038
.013
0692
.015
.061
.006
.045
.011
.065
7.04
2.03
0.608
7.35
3.88
1.64
1.93
1.07
3.93
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0
0
0.
0
0
0
0
0
0


.Dev.
.014
.010
.012
.016
.013
.011
.037
.017
.090
.006
.012
.011
.005
.044
.026
.012
0.04
.028

.038
.013
0692
.015
.061
.006
.045
.011
.065


RSD
0.21%
0.72%
0. 48%
0. 63%
0.82%
0.63%
0.55%
1. 92%
0.82%
1.30%
0.32%
0.64%
0.57%
0.24%
0.61%
0.31%
0. 60%
0.17%
0.17%

0.54%
0.64%
11.40%
0.21%
1.58%
0.38%
2.31%
1.04%
1.66%

-------
        NEW Al ROUTINE
Page  15
                                                                           Date: 1/27/2006 4:38:15 EM
Srt
Tit
Tit
Vt
\s 193.
Se 196.
Mo 202.




696t
026t
031t
Saturate
623268
396
158610
748
1056
3933
d2
.3
.3
.7
.1
.9
.7

2.03
1.97
2.02
2.034
2.071
1.877

mg/L
mg/L
mg/L
mg/L
mg/1
mg/L

0
0
0
0.
0.
0.

.005
.015
.013
0065
0390
0792

2.03
1.97
2.02
2.034
2.071
1.877

mg/L
mg/L
mg/L
mg/L
mg/L
mg/L

0.005
0.015
0.013
0.0065
0.0390
0.0792

0.27%
0.75%
0.62%
0.32%
1.88%
4.22%
Sequence No.: 25
Sample ID: cob
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location:  24
  Date Collected: 1/27/2006 4:34:39 EM
  Data Type: Original
  Initial Sample Vol:
  Sample Erep Vol:
Mean Data: ccb
Analyte
Yb
Agt
Cdt
Crt
Cut
Fet
Nit
Pbt
Znt
Alt
Ast
Bt
Bat
Bet
Ca 315.887t
Ca 422.673t
Cot
K lOt
iC 766.490 20t
Lit
Mgt
Mnt
Na 330.237t
Na 589.592t
Ft
Sbt
Set
Sit
Snt
Srt
Tit
Tit
Vt
As 193.696t
Se 196.026t
Mo 202.031t
Mean Corrected
Intensity Cone.
3913552
55
-6
2
291
25
-16
-4
10
-161
-10
1352
-3
-74
-245
-3365
-0
54
23
-1043
-1
-102
5
-176
-2
33
-1
-10
4
-411
-683
0
-52
-10
3
-68
.4
.2
.6
.8
.2
.7
.5
.1
.2
.1
.9
.2
.1
.0
.2
.2
.9
.9
.6
.7
.8
.5
.0
.3
.8
.4
.0
.1
.4
.4
.1
.2
.5
.9
.3
.2
9.50
0.001
0.000
0.000
0.003
Calib
Units
mg/L
mg/L
mg/L
mg/L
mg/L
0,,-001-mg/L
X0.002 ,mg/L
WrBtfT
0.001
-0.033
-0.028
0.034
0.000
0.000
-0.010
-0.013
0.000
0.001
0.000
0.000
0.000
0.000
0.020
-0.001
-0.013
0.048
-0.003
-0.001
0.003
0.000
-0.002
0.001
-0.001
-0.030
0.006
-0.033
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.047
.0004
.0000
.0003
.0001
.0000
.0013
.0039
.0003
.0069
.0054
.0049
.0004
.0000
.0010
.0002
.0003
.0012
.0006
.0001
.0009
.0001
.0680
.0004
.0068
.0084
.0034
.0011
.0028
.0001
.0009
.0302
.0001
.0057
.0213
.0205
Cone.

0.001
0.000
0.000
0.003
0.001
-0.002
-0.001
0.001
-0.033
-0.028
0.034
0.000
0.000
-0.010
-0.013
0.000
0.001
0.000
0.000
0.000
0.000
0.020
-0.001
-0.013
0.048
-0.003
-0.001
0.003
0.000
-0.002
0.001
-0.001
-0.030
0.006
-0.033
Sample
Units

mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Std.Dev.

0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

0004
0000
0003
0001
0000
0013
0039
0003
0069
0054
0049
0004
0000
0010
0002
0003
0012
0006
0001
0009
0001
0680
0004
0068
0084
0034
0011
0028
0001
0009
0302
0001
0057
0213
0205
RSD
0.50%
76.75%
27.80%
607.41%
2.38%
4.70%
76.13%
262.32%
53.44%
21.19%
19.38%
14.38%
367.33%
64.86%
9.47%
1.42%
337.15%
150.90%
278.20%
28.55%
195.18%
17.46%
332.78%
67.70%
54.00%
17.28%
132.41%
119.98%
102.30%
152.54%
39.98%
>999.9%
22.24%
19.38%
333.55%
63.09%

-------
PROJECT # 110325:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES                      IDL =    0.004             LOQ •    0.017
Digestion on 12/20/05                         LOD  =    0.008             RL«     0.050
BY ICP ON 12/30/05                           MDL  •    0.007                   (AN DL in mg/L)

DATA:
Sample #
LRB
LFB
110325-1
110325-2
110325-3
110325-4
110325-5
Dilution
25
25
25
25
25
25
25
Reading
-0.002
0.75
0.064
0.288
,;^!|
0.049
0.060
                                          =MDL of 0.007 mg/L          =0.006

                                          --100 x 0.749/0.80 = 96% Recovery, ( 80-120%)
                                           = 0.006
EXPLANATIONS:
                Laboratory Reagent Blank, where a beaker containing reagents used during the digestion
         ~      process were added, no filter.
                Laboratory Fortified Blank, where LRB is essentially spiked with nickel and carried the
                digestion process, again, no filter.
   DILUTION =    25 ml class A volumetric flask was used to measure the final volume.
   READING =    mg/L as determined by average of three replicates on ICP.
IN ORDER TO FAClLlT/iTE;FURTHER jSXfqiMtiONfe, IF -A'READINGS iflvlDL, THEN 0,QQ6/(^ USED. ,
                                                                                 12/31/05LK
                                                          SI LAB/ CoWkSh/ Nl STACK TESTS/ 2005 METHOD 121
                                                       X/ USEPA/ NICEM/ PROJECT 21 Analytical data/METHOD 121-2

-------
Laboratory Work Order Report

LIMSNo.      2005110325  Date Rec'd  11/18/2005 03:03:23   Date Due   11/18/2005 12:00:00 AM
Project Code        .NULL  Customer No.  SCICON          Client Type: REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLINAVE.
             CHICAGO                  IL     60623
Phone     254-2406
Matrix     Engineering

Client Notes: -0-
Fax  254-6661
PoNo. rQi
Contact MR. FRANK ALTMAVER
         e-mail
                      Quoted Price:  .NULL
Order Comments:   .NULL
                  .NULL
  Sample No.     Comments      Test Code  Description
ELITE FINISHING
        1    11/15/2005  11/15/05 CONDITION #23-NORTH
                         Nl            NICKEL
        2    11/15/2005  11/15/05 CONDITION #23-SOUTH
                         Nl            NICKEL
        3    11/15/2005  11/15/05 BLANK
                         Nl            NICKEL
        4    11/16/2005  11/16/05 CONDITION #25-NORTH
                         Nl            NICKEL
        5    11/16/2005  11/16/05 CONDITION #25-SOUTH
                         Nl            NICKEL
                                              Date Received       Result

                                              11/18/2005 02:00:00 PM

                                              11/18/2005 02:00:00 PM

                                              11/18/200502:00:00 PM

                                              11/18/200502:00:00 PM

                                              11/18/200502:00:00 PM
 Page 1

-------
 PROJECT # 120034:  METHOD 121  FOR NICKEL
AIR FILTER CASSETTES
Digestion on 12/20/05
BY ICP ON 12/30/05
 IDL =
LOD =
MDL •
                                                    0.004
                                                    0.008
                                                    0.007
LOQ=    0.017
 RL •     0.050
      (All DL in mg/L)
DATA:
Sample #
LRB
LFB
120034-1
120034-2
120034-3
Dilution
25
25
25
25
25
Reading
-0.002
0.75
0.174
0.176
V^ %tf\
EXPLANATIONS:
                                         
-------
I  joratory Work Order Report

LIMS No.      2005120034   Date Rec'd 12/05/2005 12:00:40   Date Due    12/05/2005 12:00:00 AM
Project Code        .NULL  Customer No.  SCICON          Client Type:  REGULAR
Client Name  SCIENTIFIC CONTROL LABS
             3158S. KOLIN AVE.
             CHICAGO                  IL     60623
Phone
Matrix
254-2406
Engineering
Fax
• 254-6661
Contact
Po No. ^2
MR. FRANK
e-mail
ALTMAYER

Client Notes: -
Order Comments:   METHOD 10-121
  Sample No.
ELITE
               Comments
Test Code   Description
        1   12/01/2005  12/01/05 CONDITION #26 - NORTH (25082360)
                         Nl            NICKEL
        2   12/01/2005  12/01/05 CONDITION #26-SOUTH (25082350)
                         Nl            NICKEL
        3   12/01/2005  12/01/05 BLANK -(25082353)
                         Nl            NICKEL
                                                                     Quoted Price:  .NULL.
                                            Date Received
Result
                                            12/05/2005 10:00:00 AM
                                            12/05/2005 10:00:00 AM
                                            12/05/2005 10:00:00 AM
                                               TOf
 Page 1

-------
METALS   PREP   FORM
                                                       Set#
Prep Method:    (check only one per page)
   ICP/FLAA: SM 3030 F, EPA 200.7 '82
   ICP/FLAA: EPA200's, SW-8463010A
   ICP/FLAA: EPA 200.7 r4.4
   ICP/FLAA: SW-846 3005A
   ICP/FLAA: SW-846 3015A MICROWAVE
   OTHER:	.	
GFAA: SM 3030 E
GFAA: EPA 200's, SW-846 3020A
GFAA: EPA 200.9
GFAA: SW-846 3015A (NoHCL) MICROWAVE
OTH ER:		



1
•
4
5
_L
8
10
11


DRINP
"Set
Jnifl
u










SPIKIN
- -
CINGW
Set
4o













3STDS
QC-21
QC-7
P
Sn
OTHER
fATER
Set
time

















Lab#


\\6^


	 1
N


, 	 	 	
/

I
,

/








Smp#





I

4


e>
•..
I
^









AQUEOUS

Company
LFB
LRB

«W«IP
em







-

.,



PROVIDER
ff^}




LOT#
0 S' <
-a u





A
DTHF.R : ,/l W<. . I / U / «^(
Final
(mis)


	 	 	 --r^~




	 '









Analyst:
Start Date:

1 . ..•'*'.'.
• ' .
j. . '..; j :•• „, '-








. .. *






Mcr
Vsl#


















S\QA FORMS \FM-041 1R02 \LK
                                                                 Page 1 of 1

-------
                          Sample Information Detail Report
                          Document Name: 123005-1
File Description
Default Sample Information File

Parameters Common to All Samples

Batch ID
Volume Units
Weight Units

Parameters That Vary By Sample
123005-1
ml
9
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Sample No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
A/S Location
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Sample Prep. Vol.
















                                              Sample ID
                                              cri
                                              icb
                                              icv
                                              icsab
                                              IfbNi
                                              Irb
                                              110325-1
                                              110325-2
                                              110325-3
                                              110325-4
                                              110325-5
                                              120034-1
                                              120034-2
                                              120034-3
                                              ccv 0.50
                                              ccb

                                              Aliquot Volume
                                             Initial Sample Wt.
                                             Diluted To Vol.

-------
Method: Air Filter Ni
                                                Page   1
                                                                           Date: 12/30/2005 12:09:05 PM
Analysis Begun

 Jtart Time: 12/30/2005 11:58:14 AM                Plasma On Time: 12/30/2005 11:12:33 AM
Logged In Analyst: sammy                          Technique: ICP Continuous
Spectrometer Model: Optima 3000 DV, S/N 069N5083001Autosampler Model: AS-91

Sample Information File: C:\pe\sammy\Sample Information\123005-l.sif
Batch ID: 123005-1
Results Data Set: 123005-1
Results Library: C:\pe\sairany\Results\Results.mdb



Method Name? Air Filter Ni                        Method Last Saved: 10/5/2005 1:33:13 PM
IEC File:                                         MSF File:
Method Description: AIR FILTER Ni


Sequence No  • 1                                   Autosampler Location: 0
Sample ID: Calib Blank 1                          Date Collected: 12/30/2005 11:58:14 AM
Analyst:                                          Data Type: Original
Initial Sample Wfc:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: Calib Blank 1
                   Mean Corrected                                Calib
Analyte               Intensity      Std.Dev.   RSD        Cone. Units
Yb 328.937           2135095.0      11709.27   0.55%        10.0 mg/L
Ni 231.604t             -114.1          2.73   2.39%       [0.00] mg/L


Sequence No.: 2                                   Autosampler Location: 1
Sample ID: Cal 21+7 1.00                          Date Collected: 12/30/2005 12:01:53 PM
Analyst:                                          Data Type: Original
 initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: Cal 21+7 1.00
                   Mean Corrected                                Calib
Analyte               Intensity      Std.Dev.   RSD        Cone. Units
Yb 328.937           2104392.6       2502.46   0.12%        9.86 mg/L
Ni 231.604t             6036.7         22.96   0.38%       [1.00] mg/L


Calibration  Summary

Analyte        Stds.   Equation        Intercept      Slope    Curvature      Corr. Coef.    Reslope
Ni 231.604       1     Lin Thru 0             0.0       6037      0.00000         1.000000


Sequence No.: 3                                   Autosampler Location: 9
Sample ID: cri                                    Date Collected: 12/30/2005 12:05:14 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: cri                                        104  I/O
                   Mean Corrected          Calib                           Sample
Analyte               Intensity      Cone. Units      Std.Dev.       Cone.  Units      Std.Dev.   RSD
Yb 328.937           2102349.6         9.85 mg/L         0.010                                   0.10%
Ni 231.604t              157.1       0.026 Jng/L        0.0005        0.026  mg/L        0.0005    1.86%

                                              C====================================================
Sequence No.: 4                                   Autosampler Location: 10
 Sample ID: icb                                    Date Collected: 12/30/2005 12:09:05 PM

-------
Method: Air Filter Ni
Page
                                                                           Date: 12/30/2005 12:26:55 PM
Analyst:
Initial Sample Wt:
Dilution:
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
Mean Data: icb

Analyte
Yb 328.937
Ni 231.604t

Mean Corrected
Intensity
2120464.3
-6.2
	 	 	 rpj?

Calib
Cone. Units
9.93 mg/L
-0.001 mg/L


Std.Dev.
0.040
0.0013

Sample
Cone. Units
-0.001 mg/L


Std.Dev. RSD
0.40%
0.0013 127.18%
Sequence No. : 5
Sample ID: icv
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location: 11
  Date Collected: 12/"~ '""'
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
>:12:56 PM
Mean Data: icv
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
Intensity
2080725.7
6166.2
Calib
Cone. Units
9.75 mg/L
1.02 mg/L
!»?•"* *
Std.Dev.
0.032
0.005
Sample
Cone. Units
1.02 mg/L
Std.Dev. RSD
0.32%
0.005 0.50%
Sequence No.: 6
Sample ID: icsab
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location: 12
  Date Collected: 12/30/2005 12:16:18 PM
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
Mean Data: icsab

Analyte
Yb 328.937
li 231.604t

Mean Corrected
Intensity
2022525.0
5917.7

Calib
Cone. Units
9.47 mg/L
0.980 mg/L
— TA tr
A A N

Std.Dev.
0.048
0.0073

Sample
Cone. Units
0.980 mg/L


Std.Dev. RSD
0.51%
0.0073 0.75%
Sequence No.: 7
Sample ID: l£b Ni
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location: 13
  Date Collected: 12/30/2005 12:19:40 PM
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
Mean Data: l£b N

Analyte
Yb 328.937
Ni 231.604t
i
Mean Corrected
Intensity
1955004.8
4523.1

Calib &'
Cone. Units 1
9.16 mg/L
0.749 mg/L
-"$o
2 . I/
Std.Dev.
0.142
0.0049

Sample
Cone. Units
0.749 mg/L


Std.Dev.
0.0049


RSD
1.55%
0. 66%
Sequence No.: 8
Sample ID: Irb
Analyst:
Initial Sample Wt:
Dilution:
  Autosampler Location: 14
  Date Collected: 12/30/2005 12:23:02 PM
  Data Type: Original
  Initial Sample Vol:
  Sample Prep Vol:
Mean Data: Irb

Analyte
Yb 328.
Ni 231.


937
604t
Mean Corrected
Intensity
1969448.6
-11.1

Cone.
9.22
-0.002
Calib
Units
mg/L
mg/L ,


&

Std.Dev.
0.149
0.0013

Cone.
-0.002
Sample
Units
mg/L

Std
0.

.Dev.
0013

RSD
1 . 61%
71.21%
Sequence No.: 9
"Sample ID: 110325-1
  Autosampler Location: 15
  Date Collected: 12/30/2005 12:26:55 PM

-------
                   Ni
                                                Page
                                                                           Date: 12/30/2005 12:46:54 EM
Analyst:
Initial Sample Wt:
Dilution:
                                                  Data Type: Original
                                                  Initial Sample Vol :
                                                  Sample Prep Vol :
Mean Data: 110325-1
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937           2003331.9        9.38 mg/L         0.114                                  >-.iL»
Ni 231.604t              386.8       0.064 mg/L        0.0015       0.064 mg/L        0.0015   2.26%


q^mienae No  • 10                                  Autosampler Location: 16
Sample ?D: lio325-2                               Date Collected: 12/30/2005 12:30:48 EM
Analyst:                                          Data ^yP31 Original
initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: 110325-2
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yh 328 937           2009889.4        9.41 mg/L         0.111                                  l.lbo
Ni 23l!604t             1736:7       0.288 mg/L        0.0003       0.288 mg/L        0.0003   0.10%


Secruence No  • 11                                  Autosampler Location: 17
Sample ID: 110325-3                               Date Collected: 12/30/2005 12:34:43 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: 110325-3
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937           2010062.0        9.41 mg/L         0.122                                 4^1*
 li 231.604t              -14.2      -0.002 mg/L        0.0011      -0.002 mg/L        0.0011  47.51%


Secruence No.: 12                                  Autosampler Location: 18
Sample ID: 110325-4                               Date Collected: 12/30/2005 12:38:37 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: 110325-4
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937           2003577.7        9.38 mg/L         0.178                                  1-90.
Ni 231.604t              297.5       0.049 mg/L        0.0014       0.049 mg/L        0.0014   2.83%


Sequence No.: 13                                  Autosampler Location: 19
Sample ID: 110325-5                               Date Collected: 12/30/2005 12:42:32 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data: 110325-5
                   Mean Corrected          Calib                          Sample
Analyte               Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937           1997531.7        9.36 mg/L         0.149                                  ^    °
Ni 231.604t              361.3       0.060 mg/L        0.0015       0.060 mg/L        0.0015   2.56-s


Sequence No.: 14                                  Autosampler Location:  20
Sample ID: 120034-1                               Date Collected: 12/30/2005 12:46:54 EM

-------
Method: Air Filter Ni
                             Page
                                                                           Date: 12/30/2005 1:05:23 EM
Analyst:
Initial  Sample Wt:
Dilution:
                               Data Type: Original
                               Initial  Sample Vol:
                               Sample Prep Vol:
Mean Data:  120034-1
                   Mean Corrected          Calib                          Sample
Analyte                Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937            2005116.7         9.39 mg/L         0.167                                  1.78%
Ni231.604t            1050.5       0.174 mg/L        0.0009       0.174 mg/L        0.0009   0.53%


Sequence No.: 15                                  Autosampler Location: 21
Sample ID:  120034-2                               Date Collected: 12/30/2005 12:51:06 EM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Erep Vol:


Mean Data:  120034-2
                   Mean Corrected          Calib                          Sample
Analyte                Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937            2005263.4         9.39 mg/L         0.109                                  1.16%
Ni 231.604t            1063.0       0.176 mg/L        0.0004       0.176 mg/L        0.0004   0.24%


Sequence No.: 16                                  Autosampler Location: 22
Sample ID:  120034-3                               Date Collected: 12/30/2005 12:55:02 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:


Mean Data:  120034-3
                   Mean Corrected          Calib                          Sample
Analyte                Intensity      Cone. Units      Std.Dev.      Cone. Units      Std.Dev.   RSD
Yb 328.937            2003607.7         9.38 mg/L         0.107                                  1.14%
Ai 231.604t               3.4       0.001 mg/L        0.0010       0.001 mg/L        0.0010 178.89%


Sequence No.: 17                                  Autosampler Location: 23
Sample ID:  ccv 0.50                               Date Collected: 12/30/2005 12:58:58 PM
Analyst:                                          Data Type: Original
Initial Sample Wt:                                Initial Sample Vol:
Dilution:                                         Sample Prep Vol:
Mean Data: ccv 0.50
Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
   Intensity
  2175552.9
     3098.7
      Calib
Cone. Units
 10.2 mg/L
0.513 mg/L
Std.Dev.
   0.02
 0.0022
      Sample
Cone. Units

0.513 mg/L
                                                Std.Dev.   RSD
                                                          0.15%
                                                 0.0022   0.42%
Sequence No.: 18
Sample ID: ccb
Analyst:
Initial Sample Wt:
Dilution:
                               Autosampler Location: 24
                               Date Collected: 12/30/2005 1:02:25 PM
                               Data Type: Original
                               Initial Sample Vol:
                               Sample Prep Vol:
Mean Data: ccb

Analyte
Yb 328.937
Ni 231.604t
Mean Corrected
   Intensity
  2163765.3
        0.4
      Calib
Cone. Units
 10.1 mg/L
0.000 mg/L
Std.Dev.
   0.07
 0.0015
                                     Sample
                               Cone.  Units

                               0.000  mg/L
                 Std.Dev.    RSD
                           0.67%
                  0.0015 >999.9%

-------
           Appendix G



Plating Solution Laboratory Reports

-------
                       SCIENTIFIC CONTROL LABS
                                CompuFAX
                               November 11, 2005
Jeff's  Project
            Lab No:
110076
ELECTROLESS Nl
Dated: 11-1-05

Metallic Nickel
Sodium Hypophosphite
pH
Surface Tension
(dynes/cm)
Room Temp
  Conditions 3/4/5/6
  RELIABLE
       0.81
       3.42
       4.99
75.0/75.2/75.3
68.6/68.7/68.8
( 190 F.)
Results in ounces per gallon
A.G.
            AUDREY GLIVA

-------
                        SCIENTIFIC CONTROL LABS
                                   CompuFAX
                                  February 8, 2006
 Jeffs Project                                Lab No:    020075

                     Condition 10
                       No Wetter
 Nickel Solution      ABQC (02-01-06)

 Metallic Nickel            9.38
 Nickel Sulfate             32.74
 Nickel Chloride            8.34
 Boric Acid                5.33
 pH                       3.92
 Specific Gravity           1.200
 Surface Tension
 (dynes/cm)          '68.0/68.0/68.2          (140F)      58.0/58.1/58.2
 Room Temp
 Iron (mg/L)                37.7
                     Condition 13
                        Wetter
Nickel Solutions    ABQC (02-02-06)

Metallic Nickel             9.55
Nickel Sulfate            33.36
Nickel Chloride            8.46
Boric Acid                5.17
pH                       4.18
Specific Gravity            1.200
Surface Tension
(dynes/cm)           43.1/43.2/43.4           (140F)     42.1/42.0/42.1
Room Temp
Iron (mg/L)                14.9
A.G.                                        AUDREY GLIVA

-------
                       SCIENTIFIC CONTROL LABS
                                 CompuFAX
                               January 20, 2006
Jeff's  Project                               Lab No:    010217

                       ABQC
                   Condition 11/12
Nickel Solution   NO WETTER 1 -11 -06
Metallic Nickel            8.22
Nickel Sulfate           28.52
Nickel Chloride           7.46
Boric Acid                4.51
pH                      4.6
Specific Gravity           1.175
Surface Tension
(dynes/cm)          58.2/58.4/58.7          (140F)     57.3/57.4/57.4
Room Temp
A.G.                                     AUDREY GLIVA

-------
                       SCIENTIFIC CONTROL LABS
                                 CompuFAX
                                November 17, 2005
Jeffs  Project
Nickel Solution

Metallic Nickel
Nickel Sulfate
Nickel Chloride
Boric Acid
pH
Specific Gravity
Surface Tension
(dynes/cm)
Room Temp
                        Lab No:
            110199
     ABQC
 Condition 14/15
WETTER 11-7-05

     11.40
     42.96
     7.30
     8.00
     3.88
     1.245

 37.6/37.8/37.8
  (140F)
37.0/37.1/37.1
                     Condition 7          Condition 24
                Artistic Woods Strike Artistic Woods Strike
                      No Wetter             Wetter
Nickel Solutions       11-09-05             11-10-05
Metallic Nickel
Nickel Chloride
Hydrochloric Acid
Surface Tension
(dynes/cm)
Room Temp
Specific Gravity
     3.17
     12.70
     34.61

 60.3/60.3/60.5

   1.105
    3.34
    13.35
    33.97

50.9/50.8/50.7

    1.105
A.G.
                        AUDREY GLIVA

-------
                            SCIENTIFIC CONTROL LABS
                                            CompuFAX
                                           October 4, 2005
 Artistic Plating Co. Inc.
 405 W. Cherry St.
 Milwaukee, Wl. 53212
Attention:  Mr. John Tinder                                Lab No:      100012
 Gentlemen:

 The solution samples submitted to us on October 3,  2005 have been
 analyzed and are reported in ounces per gallon (unless otherwise noted)
 as follows:

                         Conditions 18/19 Conditions 20/21
                         NO WETTER       WETTER
 NICKEL  SOLNS             9/27-28            9/28-29

 Metallic Nickel                8.34               8.42
 Nickel Sulfate                30.49             31.34
 Nickel Chloride                6.14               5.71
 Boric Acid                    5.70               6.11
 pH                            3.5               3.8
 Specific Gravity               1.175              1.165

 Surface Tension
 (dynes/cm)
 Room Temp                  72.3               32.4

 140 F                        67.7               30.5
Surface tension measurements were conducted using a tensionmeter.

Please contact us at once if you should have any questions.


                                                       Yours very truly,


AG/FAX                                                AUDREY GLIVA

-------
                       SCIENTIFIC CONTROL LABS
                                CompuFAX
                               November 23, 2005


Jeffs  Project                               Lab No:    110323
                                          Conditions 23/25
                                            ELITE
Nickel Solutions                            11-16-05

Metallic Nickel                                7.73
Nickel Sulfamate                              33.16
Nickel Chloride                               0.68
Boric Acid                                    4.72
pH                                           3.3
Specific Gravity                               1.220
Surface Tension
(dynes/cm)
Room Temp                                  46.1
135f                                        44.5
Results in ounces per gallon.
A.G.                                     AUDREY GLIVA

-------
                       SCIENTIFIC CONTROL LABS
                                CompuFAX
                               December 8, 2005
Jeffs Project
                     Lab No:
120033
Nickel Solutions

Metallic Nickel
Nickel Sulfamate
Nickel Chloride
Boric Acid
pH
Specific Gravity
Surface Tension
(dynes/cm)
Room Temp
135f
Condition 26
  ELITE
 12-01-05

   8.51
  36.54
   0.72
   5.41
   4.0
   1.215
   36.1
   35.0
Results in ounces per gallon.
A.G.
                    AUDREY GLIVA

-------
                        SCIENTIFIC CONTROL LABS
                                  CompuFAX
                                October 27, 2005


Jeff's Project                               Lab No:    100304
                      No Wetter Condition 22
Nickel Solution      Elite (10-18-05)

Metallic Nickel            8.59
Nickel Sulfamate         36.75
Nickel Chloride            0.84
Boric Acid                5.62
pH                       3.65
Specific Gravity           1.220
Surface Tension
(dynes/cm) 135F     39.0/39.1/39.2
Room Temp
                      Condition 27          Condition 28-29
                 Artistic Woods Strike  Artistic Woods Strike
                      No Wetter            Wetter
Nickel Solutions        10-17-05              10-20-05

Metallic Nickel            2.43                  1.62
Nickel Chloride           9.72                  6.48
Hydrochloric Acid         40.70                42.95
Surface Tension
(dynes/cm)          72.9/73.0/73.0        58.6/58.5/58.7*
Room Temp


* Acidic solution destroys wetting agent over time.
Surface tension of this solution measured in field at 38 dynes/cm (w/stalagmometer).

A.G.                                       AUDREY GLIVA

-------
       Appendix H




Sample Chain of Custodies

-------
         ||OD~?(0
                                     '5SS.'koUN AVENUE
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            fcX: (Signature)   ^

-------
                 S.KOUN AVENUE
          JNC-
'^'•t/te*  /

-------
 COMF
 SAMPLING ADDRESS
                                                                                                          3158 S. KOL'N' AVENUE
                                                                                                          CHICAGO iL 50623-438S
                                                                                                          www.sciwet.ccm
                                                                                                          TEL (773)254-2406
                                                                                                          FAX (773}254.-S66-!
                                                    ^^^LCySTODY^ECDRD
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                                                ?cr UboraJory by:
                                                    t-^--^t__^xyo
-------
COMP
SAMPLING
                                                                                                        3*58S.'KOUN AVENUE
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                                                                                                       Received iy;(Sfgnak..r6i

-------
SAMPLIG
                                                                                                               N AVENUE
                                                                                                     HICAGO ,L £0623-4389
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                                                                                                        (773)254-2406
                                                                                                        (773}254-S66-!
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                                                ^\r^\ , lui ^>^

-------
COMPANY
SAMPLING ADDRuoS
                              .
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                                                                 CONTROL^ LABORATORIES, INC.
                                                                                            3158S. KOLIN AVENUE
                                                                                            CHICAGO  IL 60623-4889
                                                                                            www.sclweb.com
                                                                                            TEL (773)254-2406
                                                                                            FAX (773)254-6661
                                                                      TESTIN G
                                                                                    CONSU LTING
                                                   CHAIN OF CUSTODY RECORD
Project No.
Project Name
SAMPLER (SIGNATURE)
Station
No.
                                  Station Location
                         No. of
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                                                                                                                        PRESERVATIVE
                                                                                        lass
                                                                                        etal
                                           (6) 1/2 Gal.
                                           (7) Gallon
                                           (8) VOC Vial
                                           (9) Vials
                                           (10) Other
                                          A- None
                                          B- HNO3
                                          C- H2SO4
                                          D- NaOH
                                          E- Ascorbic
                                          F- Na2S2O3
                                          G- Other

                                                                                   V
                                              V
                                                                      X
Relinquishes by: (Signature)
                   Date/Time
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Relinquished by: (Signature)
               Date/Time
                                                                                                Received by: (Signature)
 RelinquishldlDyt (Signature)
                   Date/Time
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Date/Time
Temperature of Samples
Shipping No.:
 Remarks:


-------
COMPANY	
SAMPLING ADDRESS
             -K VTr
                                                               CONTROLS LABORATORIES, INC.

                                                                     TESTING 	  CONSULTING
                                                                                                       3158 S.KOLIN AVENUE
                                                                                                       CHICAGO IL 60623-4889
                                                                                                       www.sclweb.com
                                                                                                       TEL (773)254-2406
                                                                                                       FAX (773)254-6661
                                                 CHAIN OF CUSTODY RECORD
reject No.   Project Name
tation
o.
       DATE
                             tation Location
No. of
  c
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                                                                                                                  (9) Vials
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                                                                                                          A-None
                                                                                                          B- HNO3
                                                                                                          C-H2SO4
                                                                                                          D- NaOH
                                                                                                          E- Ascorbic
                                                                                                          F- Na2S2O3

                                                                                                          G'°ther
      Wo-
'>\
-------
COMPANY
SAMPLING ADDKhSS

                                                                CONTROL  LABORATORIES, INC.
                                                                                           3158 S. KOLIN AVENUE

                                                                                           CHICAGO  IL 60623-4889
                                                                                           www.sclweb.com

                                                                                           TEL (773)254-2406
                                                                                           FAX (773)254-6661
                                                                     TESTING
                                                                                   CONSU LTING
                                                  CHAIN OF CUSTODY RECORD
 roject No.
Project Name
SAMPLER (SIGNATURE)
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                                                                                                Q-Glass  (4) Pint    (9) Vials
                                                                                                M-Metal    Quart   (10) Other
                                                                                                               A- None
                                                                                                               B- HN03
                                                                                                               C- H2SO4
                                                                                                               D- NaOH
                                                                                                               E- Ascorbic
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Relinquished by: (Signature)
  Date/Time
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                                Date/Time
                              ceived for Laboratory by
                              Date/Time
           Temperature of Samples
         Shipping No.:
 Remarks:

-------
      ^56 S. KOL'N AVENUE
      CHICAGO ,'L 50623-4889
      Www.sciwet.ccrn
      TEL (773)254-2406
      FAX (773)254-666-1
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-------
COMPANY
SAMPLING ADDRESS
                                                                             LABORATORIES, INC.
                                                                                                3158S. KOLIN AVENUE
                                                                                                CHICAGO IL 60623-4889
                                                                                                www.sclweb.com
                                                                                                TEL (773)254-2406
                                                                                                FAX (773)254-6661
                                                                     TESTING  - CONSULTING
                                                  CHAIN OF CUSTODY RECORD
 3roject No.
      Project Narpe
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                                                                                                          (7) Gallon
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                                                                                                          (9) Vials
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                                          B- HNO3
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                                          E- Ascorbic
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                                                                      y
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-------
Environmental Technology &
      Engineering Corp.
13000 W. Bluemound Road
Elm Grove, Wisconsin 53122
           :  _//fMJei,
                          ETE Contact  _
                          Phone: 262-784-2434
                          Fax:  262-784-2436
                                            ETE Project No.
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Requested Analytical Methods:  £7^
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Desired Report Date
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-------
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 13000 W. Bluemound Road
 Elm Grove, Wisconsin 53122
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                                            Phone: 262-784-2434
                                            Fax: 262-784-2436
                                             ETE Project No.
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-------
Environmental Technology &
       Engineering Corp.
13000 W. Bluemound Road
Elm Grove, Wisconsin 53122
To:
Sample Media:

Analyze for: 	
Requested Analytical Methods:
      ETE Contact:
      Phone:  262-784-2434
      Fax: 262-784-2436
                                            ETE Project No.


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-------
COMP,
SAMPLING AC-CRESS,
                                                           CONTROL  LABORATORIES, INC,
31555. KOUN/3    ,Uc
CHICAGO  it 50623-4389
•www.s6weh.ccm
TEL (773)254-2406
FAX (773}254.-SS6J,
                                                                TESTING
                                                                            CONSULTING
                                              CHAIN OF CUSTODY RECORD


-------
SAMPLING ADDRESS
                                                                                                      3<55S. KOUN AVENUE
                                                                                                      CHICAGO fL 50623-4389
                                                                                                      •www.sciwefc.corn
                                                                                                      TEL (773)254-2406
                                                                                                      FAX (773}254--S661
/   /CONTAINER
                                                                                                                    PRESERVATIVE
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                                     «eceived by: (Signature)

-------
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                                                                                                       3158 S. KOL'N AVENUE •
                                                                                                       CHICAGO iL 50623-4889
                                                                                                       www. sci web. corn
                                                                                                       TEL (773)254-2406
                                                                                                       FAX (773)254-6661
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                                                                                                   CONTAINER

-------
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-------
COMPANY
SAMPLING ADDRESS
                                                                           LABORATORIES, INC
                                                                                                     3158 S. KOLIN AVENUE

                                                                                                     CHICAGO IL 60623-4889

                                                                                                     www.sclweb.com

                                                                                                     TEL (773)254-2406

                                                                                                     FAX (773)254-6661
                                                 CHAIN OF CUSTODY RECORD
3reject No.
           Project_Name
SAMPLER (BIGNAI Ukt)
                  V
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Station
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                                                                             (2) 4 OZ.   (7) Gallon   C- H2SO4
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                                                                      G-Glass (4) Pint    (9) Vials    E- Ascorbic
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                                                                       Date/Time
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                                                                       Date/Time
                                                                Received by: (Signature)
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-------
COMPANY
SAMPLING ADDRESS
                                                               CONTROLS LABORATORIES, INC.
                                                                    TESTING  	 CONSULTING
                                                                                                     3158 S. KOLIN AVENUE
                                                                                                     CHICAGO IL 60623-4889
                                                                                                     www.sclweb.com
                                                                                                     TEL (773)254-2406
                                                                                                     FAX (773)254-6661
                                                  CHAIN OF CUSTODY RECORD
 roject No.
      Project Name
AMPLER (SIGNATURE-'
 tation
 o.
                                             U
      DATE
TITCTE-
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                                                s
                                                                                                  CONTAINER
                                                                                                      (1)20Z.
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                                                                                                                     PRESERVATIVE
                                                                                                               (6) 1/2 Gal.
                                                                                                               (7) Gallon
                                                                                                                   A- None
                                                                                                                   B-HNO3
                                                                                                                   C- H2SO4
                                                                                               P-Plastic (3) 1/2 Pint  (8)VOCVial D-NaOH
                                                                                               G-Glass (4) Pint
                                                                                               M-Metal (5) Quart
                                                                                                               (9) Vials
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                                                                                                           E- Ascorbic
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                                                                                                Date/Time
                                                                                        Received by: (Signature)
 ReiinquihkXdWJ (SigrWure)
                               Date/Time
                                  Received for Laboratory b
                                                    Date/Time
                                                                  Temperature of Samples
                                                                              Shipping No.:
 Remarks:

-------
COMPANY
SAMPLING ADORES;
           ORE
                                                                                                   31 58 S. KOLIN AVENUE
                                                                                                   CHICAGO IL 60623-4889
                                                                                                   www.sclweb.com
                                                                                                   TEL (773)254-2406
                                                             CONTROL  LABORATOR.ES, INC.
                                                                  TESTING
                                                                               CONSULTING
                                               CHAIN OF CUSTODY RECORD
3reject No.
           Project Nam
SAMPLER (SIGNAI Ukb)
    ">
Station
No.
      DATE
                               . /-NQ_AQ___
                               aidaALJ
                              IL JH
                                             ^jSttj&f^EQGq^Qn
                                                              No. of
                                                                c
                                                                o
                                                                n
                                                                t
                                                                a

                                                                n
                                                                e
                                                                1 r
                                                                s
                                                                                                CONTAINER
                                                                                                   (1)20Z.
                                                                                                   (2)4OZ.
                                                                                                                 PRESERVATIVE
                                                                                                             (6) 1/2 Gal.
                                                                                                             (7) Gallon
                                                   A- None
                                                   B- HNO3
                                                   C- H2SO4
                                                                                            P-Plastic (3) 1/2 Pint (8) VOC Vial  D- NaOH
                                                                                            G-Glass (4) Pint
                                                                                            M-Metal (5) Quart
                                                                                                             (9) Vials
                                                                                                             (10) Other
                                                   E- Ascorbic
                                                   F- Na2S2O3
                                                   G- Other
      'Mi
                                                               5
X
                                                                    I
                                                                                          tr^1 ATfiU
                                                                                                               a
hM
                                                                    -X
                                                                    X
      V0bk
                              fleft&c
                                                                    X

Relinquished by: (Signature;)
                              Date/Time
                                                                    Relinquished by: (Signature)
                                                                                             Date/Time
                                    Received by: (Signature)
 Relinquis!
                 nature)

                               Date/Time
                                                                    Date/Time
                                                                               Temperature of Samples
                                 Shipping No.:
Remarks

-------
COMPANY
SAMPLING ADDktSS
                                                                CONTROL LABORATORIES, INC.
                                                                     TESTING 	  CONSULTING
                                                                                                3158 S. KOLIN AVENUE
                                                                                                CHICAGO IL 60623-4889
                                                                                                www.sclweb.com
                                                                                                TEL (773)254-2406
                                                                                                FAX (773)254-6661
                                                  CHAIN OF CUSTODY RECORD
Project No.
      Project Name
SAMPLER (SIGNATU
Station
No.
DATE
Station Location
No. of
  c
  o
  n
  t
  a
  i
  n
  e
  r
  s
                                                                                                   CONTAINER
                                                                                                       (1)2OZ.
                                                                                                       (2)40Z.
                                                                                                P-Plastic (3) 1/2 Pint
                                                                                                Q-Glass (4) Pint
                                                                                                M-Metal (5) Quart
                                                                                                               PRESERVATIVE
                                                                                                          (6) 1/2 Gal.
                                                                                                          (7) Gallon
                                                                                                          (S)VOCVial
                                                                                                          (9) Vials
                                                                                                          (10) Other
                                                                                                                           A- None
                                                                                                                           B- HN03
                                                                                                                           C- H2SO4 ..
                                                                                                                           D- NaOH
                                                                                                                           E- Ascorbic
                                                                                                                           F- Na2S2O3
                                                                                                                           G- Other
                                                                                             Gr-S-A
                                                                      V
                                                                      A
                                                                      V
                                                                       X
                                                                       X;
                                                                      V,
                                                                      V
                                                                      X
Relinquished by: (Si
                               Date/Time
             • " y
                                              ignature
                        Relinquished by: (Signature)
                                                                                                Date/Time
                                          Received by: (Signature)
Relinqui
                        Date/Time
                                        Reiejvetf fctf Laboratory by
                        Date/Time
                         O '3-^
                 Temperature of Samples
                                                                                                 Shipping No.:
Rema
                                                                 L\\

-------
COMPANY I
'V  PS!
SAMPLING ADDRESS
                                                                   ciett
                                                                 CONTROL
                                                         •
-------
    COMF
            ^clett&tlc
   Project No.    Voject .Nans
                                                                                                      3'5flS.KOUN AVENUE
                                                                                                      CHICAGO fL  50623^389
                                                                                                      •www.scJwet.ccrn
                                                                                                          (773)254-2406
                                                                                                          (773)254-6661
^^fCUlTof^§
  ——i         i ^    T~	.
                                       eceved by: (Signatur
Remarks:

-------
COMP/^'Y.	
SAMPLI.   ADCRE3S
                                                                                                            3158S. KOL'N,
                                                                                                            CHICAGO iL £0623-4389
                                                                                                            www.sciweh.ccm
                                                                                                            TEL (773)254-2406
                                                                   CONTRDiy LABORATORIES. INC.    FAX (773)
                                                                        TESTING  	  CONSULTING
I Project No.    p-oject!
                                                     CHA1N OF CUSTODY RECORD
                                                                                                        CONTAINER
                                                                                                                          PRESERVATIVE
                                                                                                                                A- 'None
                                                                                                          '  (J0-20Z.   (6}1/ZGal.   B-HNO3
                                                                                                            (2) A CZ.   (7) 3g||on    C- H2SC4
                                                                                                    P-P!astic (3)-1;2P:ni fS) VOC Via!  D-NaOH
                                                                                                    G-Glas3  (4) Pint    {9} Vials     E-Ascorbic
                                                                                                    M-Me!a!  (5) Quart   (IC)Cfher    F- K'a2S2O3
                                                                                                                                G- Ofher
                                          Received by: (Signature)
                                          Received fcr Laboratory by<
 Remarks:








: ,

Relinqui
Date/Tin
1-0
                                                                                                               Received by: (SignstLTe)
                                                                                    Temperature of Samples   Shipping No.:

-------
                                                                      ^r •    -L" /.
                                                                     -^cieHZL+ic
jTojeciNo.
 3' 56 S. KOUN AVENUE

 CHICAGO ,-L  £0623-4389

www.sawefc.com

TEL (773)254-2406
PAX (773)254-366-!
                                                                                                                           	

                                                                                                                            PRESERVATIVE
                                                                                                             (•5J-20Z.   ,'6>
-------
                Ifitfc
                                                                        3158'S. KOUN AVENUE

                                                                        CHICAGO fL C0623-4389

                                                                        •
                                                                                    	—	.
                                                                                    PRESERVATIVE
                                                                        TEL (773)2=4-2406
                                                                           (773J254-S661
                                                   ££NSULTIN
Date/Time
*y*
Remarks:
                                      Deceived by; (Signature)


                                             ——

                                             for Laboratory.by.
                                                 mperalureofsampfes  Shi
Rejfn^^^
                     •   u=iwjirn-   Received
                                                                              c by: (S/gnaiLTei
                                       ir.-^o
                                                ^

-------
    COW   \jy
    SAMPLING. ADDRES
                                                                                                        3'5SS.KOUN AVENUE
                                                                                                        CHICAGO  ,-L 60623-4369
                                                                                                        Www.sciweb.com
                                                                                                        TEL (773)2=4-2406
                                                                                                        FAX (773)254^66-!
                                                   CHAJN^FCUSTOD?
                                                                ~T~	'	—
                                        eceved by; (Signature)
                                                                                             Date/1 me  Received
Remarks:

-------
COMPANY
SAMPLING A:
                                                                CONTROLS LABORATORIES,  INC.
                                                                      TESTING —  CONSU LTING
                                                                                 3158 S. KOLIN AVENUE
                                                                                 CHICAGO IL 60623-4889
                                                                                 www.sclweb.com
                                                                                 TEL (773)254-2406
                                                                                 FAX (773)254-6661
                                                  CHAIN OF CUSTODY RECORD
3roject No.
            Project Name
SAMPLER (SIGNATURE)
Station
       DATE
                                                         u
                                 &AB-
                                   atatiopi- Location
                                         No. of
                                           c
                                           o
                                           n
                                           t
                                           a
                                           i
                                           n
                                           e
                                           r
                                           s
                                                                                                     CONTAINER
                                                                                                        (1)20Z.
                                                                                                        (2)40Z.
                                                                                                 P-plastic (3) 1/2 Pint
                                                                                                 G-Glass (4) Pint
                                                                                                 M'Metal (5) Quart
                                                                                                                       PRESERVATIVE
                                                                                                                  (6) 1/2 Gal.
                                                                                                                  (7) Gallon
                                                                                                                  (8) VOC Vial
                                                                                                                  (9) Vials
                                                                                                                  (10) Other
                                                      A- None
                                                      B- HNO3
                                                      C- H2SO4
                                                      D- NaOH
                                                      E- Ascorbic
                                                      F- Na2S2O3
                                                      G- Other
                       t-MTt;
            11
tut
ELfa
                                                                       X
                                              MK
                                                                       Y
              (Signature)
        Date/Time
        ul /  JX
          foj  f (
                                        Received by: (Signature)
Relinquished by: (Signature)
                                                                                                 Date/Time
                                                                                                Received by: (Signature)
^elinquishdd
'fjSignature)
                               Date/Time
                    eived for Laboratory by:
                                       r\
                                       U "^
                                                                       Date/Time
           Temperature of Samples
                                                                                                         Shipping No.:
Remarks:

-------
COMPANY
SAMPLING ADDRESS
                     ^
                    \tf .
                                                                          vkc
                                                                CONTROL^ LABORATORIES, INC.
                                                                      TESTING  	  CONSULTING
                                                                                           3158 S. KOLIN AVENUE
                                                                                           CHICAGO !L 60623-4889
                                                                                           www.sclweb.com
                                                                                           TEL (773)254-2406
                                                                                           FAX (773)254-6661
                                                  CHAIN OF CUSTODY RECORD
Project No.
Project Name
SAMPlL-k (SIGNATURE)
                                              Station Location
                                                                                                    CONTAINER
                                                                                                        (1)20Z.
                                                                                                        (2)40Z.
                                                                                                          PRESERVATIVE
                                                                                                     (6) 1/2 Gal.
                                                                                                     (7) Gallon
                                                                                    A- None
                                                                                    B-HNO3
                                                                                    C-H2SO4
                                                                                                p-plastic (3) 1/2 Pint (8) VOC Vial  D- NaOH
                                                                                                G-Glass  <4)pint
                                                                                                M-Metal  (5) Quart
                                                                                                     (9) Vials
                                                                                                     (10) Other
                                                                                    E- Ascorbic
                                                                                    F- Na2S2O3
                                                                                    G- Other
                i
                                                                      A
                        tLllT
                                                           X
Relinquished by: (Signature)
                  Date/Time
Received by: (Signature)
Relinquished by: (Signature)
                                                                                    Date/Time
                                                                                                           Received by: (Signature)
Relinquished joy: (Signature)
      I  V  y
                               Date/Time
                           Received for Laboratory by:
                               Date/Time
                                                                                 Temperature of Samples
                                 Shipping No.:
Remarks:

-------
COMPANY
SAMPLING ADDRESS
    £i\te
                                                                 CONTROL  LABORATORIES, INC.
                                                                                                        3158S. KOLIN AVENUE
                                                                                                        CHICAGO IL 60623-4889
                                                                                                        www.sclweb.com
                                                                                                        TEL (773)254-2406
                                                                                                        FAX (773)254-6661
                                                                      TESTING
                                                                                    CONSULTING
                                                   CHAIN OF CUSTODY RECORD
Project No.
Station
No.
                                                                  No. of
                                                                    c
                                                                    0
                                                                    n
                                                                    t
                                                                    a
                                                                    i
                                                                    n
                                                                    e
                                                                    r
                                                                    s
                                                                                                     CONTAINER
                                                                                                         (1)2OZ.
                                                                                                         (2) 4 OZ.
                                                                                                 P-Plastic (3) 1/2 Pint
                                                                                                 G-Glass  (4) Pint
                                                                                                 M-Metal  (5) Quart
                                                                          PRESERVATIVE
                                                                     (6) 1/2 Gal.
                                                                     (7) Gallon
                                                                     (8) VOC Vial
                                                                     (9) Vials
                                                                     (10) Other
                                                                                                                             A" None
                                                                                                                             B- HNO3
                                                                                                                             C- H2SO4
                                                                                                                             D- NaOH
                                                                                                                             E- Ascorbic
                                                                                                                             F- Na2S2O3
                                                                                                                             G- Other

                        ]L	^


                                                                        X
                                                                        V
       to
                        V
                                                                        X
       lo
                                                                        X
                         vc
nquished-by7(Signature)
          /
                                Date/Time
                                         Received by: (Signature)
                           Relinquished by: (Signature)
                                                                                                   Date/Time
                                                                                                             Received by: (Signature)
 Reli
            b  (Signature)
                                Date/Time
ived for Laboratory by.
                                                                        Date/Time
                                                                                   Temperature of Samples
                                                                                                      Shipping No.:
 Remarks:

-------
    Appendix I



Process Data Sheets

-------
FROM .'SCIENTIFIC  CONTROL LflBS
                               FflX NO. :17732546661
                                                                       Oct.  31 2005 09:20PM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET


Tank

Plating Type:
                                             WUJ
                         L J,
     Di

Rectifier Rated Capacity:

Run#
                                                     ^
                                                             J
                  ConditionsRgcorded Dudtig Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone,
         Plating Solution Boric Acid Cone,
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate  (estimated)
                           '
        s:\cngineer\airt8tiiokTest process data wksht,wpd
                                               5 1^ D-fctf
                                                     1
                                                  
-------
FROM : SCIENTIFIC  CONTROL LflBS
                                       FflX NO.  :17732546661
                                                                      Oct. 31 2005 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATASHEET
Company Name _

Tank.
         Plating Type;
         Tank Dimensions:
                                     W
         Rectifier Rated Capacity:
         Run#
                         [V W
                         \&- Or—'
                  Conditionsjtecoided
                                                        ^
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution. Nickel Cone.
         Plating Solution Boric Acid Cone,
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test-Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                                              PA 03
                                                                         Inches
                                                                 dynes/c
                                                                 so
                                                                 Volts
                                                                 Amperes
                                                                 A-hr
                                                                 pcs. \ fa
                                                                 ft2   J^
                                                                 mill/test run
                                                            J&.-Q min/test run
                                                                 acriii
                                                                 sclhi
                                                                                             T
                                  10?  w«J
                                                       i
         s-\engineeAairtstaok lest process data wkshtwpd

-------
FROM :SCIENTIFIC CONTROL LfiBS
                               FAX NO.  :17732546661
                                                                       Oct.  31  2005  09:20PM   PI
         NICKEL AIR TEST PROJECT
         PROCESS DATASHEET
Plating Type: __	

Tank Dimensions: L

Rectifier Rated Capacity:
                                      W
                                                                      (Unita
         OjTgrating ConditioiiLBficgflM nun«R Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone,
         Plating Solution Boric Acid Cone,
         mating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture  Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                            	oz/gal\
                                                            	oz/gal  X_
                                                            _JpH        /
                                                                _ dynes/cm /
                                                            "	" so     /
                                                                  Volts
                                                                  Amperes
                                                                  A-hr
                                                                  A/ft2
                                                                 min/test run
                                                                 min/test run

                                                                 acfiii
                                                                 scfm
                                                                 .gpm
         s:\cngineer\airtstack lest process data wkshtwpd

-------
FROM : SCIENTIFIC CONTROL LflBS
FfiX NO.  :17732546661
                                                                       Oct.  31  2005 09:20flM  PI
        NICKEL AIR TEST PROJECT
        PROCESS DATA SHEKT
         Company Manic.
        Tank Identification,
Tank Dimensions; L
                                     W
         Rectifier Rated Capacity:
                  i
         Run#
    (TO
                                                      H
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                           J   , ,    ,
        s:\cngineef\airtstaok lest process data wksllt,wpd
               A
                                                              (Units J
                                   .Inches
                                   .      ^
                                   .ojr/gal
                                    oz/gal
                                    dynes/en;
                                    SO
                                    Volts
                                    Amperes
                                    A-hr
                                   mill/test run
                                   min/test nm
                                   %
                                   acfni
                                   scfm
                                   gP"1

-------
FROM : SCIENTIFIC CONTROL  LfiBS
                              FflX NO. :17732546661
                                                                       Oct.  31 2005 09:20fiM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATASHEET
         Company Name
         Tank Identification
         Tank Dimensions;
                                                      H
Rectifier Rated Capacity;
                               K\r\
                            it;
                                   d During Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone,
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture  Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                      ~  \1UO
                                                                  min/test nin
                                                                  min/test run
                                                                  %
                                                                  acfm
                                                                  sclm
         sApngineertai^tack lest process data wksht.wpd

-------
FROM :SCIENTIFIC CONTROL LflBS
FflX NO.  :17732546661
                                                                       Oct.  31 2005 09:20flM  PI
        NICKEL AIR TEST PROJECT
        PROCESS DATA SHEKT
        Company Name
        lank identification

        Plating Type;	
Tank Dimensions; L __Ju)	  ^

Rectifier Rated Capacity: _ \$±.
               H
                                                                      (Units >\
                                                                            ----
                                                                                                      i)/K
                             ^      During Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone,
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                          Inches
                                    07/gal
                                    oz/gal
                                    pll
                                    dynes/er
                                    SO
                                    Volts
                                    Amperes
                                    A-hr
                                    A/ft2
                                    pcs. \
                                    ft2 —>
                                    min/test run
                                    min/test run

                                    actm
                                    scl'm
                                         I
               %r\
        s:\cngineer\air\stock lest process data wkiht,wp
-------
FROM :SCIENTIFIC CONTROL LflBS
                              FOX NO.  :17732546661
                                                                       Oct.  31 2005 09:20P)M  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
Company Name

Tank identification

Plating Type;

Tank Dimensions; L

Rectifier Rated Capacity
                              : \  V.
                  Conditions Rftcorded During Testing!
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Pitting Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture  Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                        y  w
                                                           -(TO1
 inches
>
 oz/gal
 oz/gal
;pu
                                                                  dynes/err
                                                              	"so     '
                                                             |J£   Volts
                                                           _j\J(i_ Amperes
         s:\cngineeAairVitack lost process (fata wksht.wpd

-------
FROM : SCIENTIFIC CONTROL  LflBS
                              FOX NO.  :17732546661
                                                                       Oct.  31 2005 09:20flM  PI
        NICKEL AIR TEST PROJECT
        PROCESS DATA SHEKT
         Company Name

         Tank Identification

         Plating Type; _

         Tank Dimensions: L

         Rectifier Rated Capacity:
                                  -
Opgmting
                                               .
                                     During Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone,
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                                             \\
                                                                  bz/gal
                                                                 .pi I
                                                                  dynes/cm,
                                                                 "so
                                                                 [ Volts
                                                                  Amperes
                                                                 "A-hr
                                                                 :A/ft2
                                                             II,  ft2
                                                            |7-L/  min/test run
                                                                  min/test run
                                                                  acftii
                                                                  scfm
                                                                 .gpm
         s;\Qngineer\airtstack lest process data wks!H,wpd

-------
FROM : SCIENTIFIC CONTROL LflBS
                              FflX NO,  :17732546661
                                                                      Oct.  31 2005 09:20flM  PI
        NICKEL AIR TEST PROJECT
        PROCESS DATA SHEET
Company Name

Tank

Plating Type; _,

Tank Dimensions: L

Rectifier Rated Capacity:

Run#_

Operating ConditionLRcg^ed During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
mating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total  Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                      (Units
                                                                         Inches
                                                                       	07/gal
                                                                       _ oz/gal
                                                                       _"pH
                                                                          dynes/err/
                                                                       I'SG
                                                                       A Volts
                                                                   _JjOjL Amperes
                                                                          A-hr
                                                                      I    PCS
                                                                   ld_.^  ft2
                                                                   ' "-"i. i    .  .
                                                                          mm/test ran
                                                                          min/test nm
                                                                         '.%
                                                                          acfm
                                                                          scfm
                     n        /^   ,
         S:\Qiiglneer\air\stack l«* process data wk*t,wpd
                 ^^1	—J—f

-------
FROM : SCIENTIFIC CONTROL LABS
                                      FAX NO.  :17732546661
                                                                      Oct.  31  2005 09:20AM  PI
        NICKEL AIR TEST PROJECT
        PROCESS DATA

        Company Name

        Tank identification

        Plating Type;

        Tank Dimensions: L
         Rectifier Rated Capacity:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture  Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                               :t4
                       _ _    dynes/cm/.
                        "	" SG    /
                       (J..A   Volts
                      JN^_ Amperes
                       f\?A   A-hr
                       f\JA  A/ft2
                             min/test run
                             min/test run

                             acfin
                             scfni
                  l(,O  PM-fe
                   <3
         s:\engineertairtstaok lest process data wksht
"Q
                                                              n

-------
FROM : SCIENTIFIC CONTROL LflBS
                                      FflX NO.  :17732546661
                                                                      Oct. 31 2005 09:20ftM   PI
        NICKEL AIR TEST PROJECT
        PROCESS DATASHEET
         Company Name
         Tank Identification
         Tank Dimensions; L
         Rectifier Rated Capacity;
         noting Conditions
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
         ,
      Inches
  .- — j« i • ••
  30  F
       oz/gal
       oz/gal
	 dynes/cm
       SG
   ^- Amperes
  MA  A-hr
       min/test run
       min/test run
       %
       acfm
       scl'rn
       gpm
                                                                                            PAD
                     lest pmcess daw wksht,wp
-------
FROM .'SCIENTIFIC CONTROL LflBS
                              FflX NO.  :17732545661
                                                                       Oct.  31 2005 09:20flM   PI
NICKEL AIR TEST PROJECT
PROCESS DATA SHEKT
         Company Name
         Tank identification
         Tank Dimensions; L _b_L>

         Rectifier Rated Capacity:
                             W
                                           Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone,
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                 Inches

                                                                  oz/gal
                                                                  oz/gal
                                                                  pll
                                                                  dynes/cm.
                                                                  SO
                                                                  Volts
                                                                  Amperes
                                                                  mill/test run
                                                                  min/test run
                                                                  %
                                                                  actm
                                                                  scfm
                                                                                           III
         s:\engintjertairVstack lest Wess data wktlit.wpd

-------
         :SCIENTIFIC CONTROL LflBS
                     FRX NO.  :17732546661
                                                                          Oct. 31 2005  09:20AM  PI
            NICKEL AIR TEST PROJECT
            PROCESS DATA SHEET
            Company Name
            Plating Type:
            Tank Dimensions: L.
                   W
            Rectifier Rated Capacity: __L2ik
                     \
Condition"
                                     ftri Duritig Testing!
            Freeboard Height:
            Plating Solution Temperature
            Plating Solution Nickel Cone.
            Plating Solution Boric Acid Cone.
            Plating Solution pH
            Plating Solution Surface Tension
            Plating Solution Specific Gravity
            Plating Voltage
            Average Amperage Applied
            Calculated Ampere-Hr Usage
            Calculated Current Density
            Number of Dummy Parts
            Total Surface Area of Plated Parts
            Plating Period Within Test Run
            Duration of Test Run
            Capture Efficiency of Ventilation System
            Ventilation Rate
            Air Agitation Rate
            Solution Circulation  Rate (estimated)   Q ,
                  tu-- ^oa.                K
                                '
            s:\onginesr\air\stack test proce:

4,  .  x 9* 73   -—»••>     ^  *
                                     1'
                                                        Inches

                                                        oz/gal\
                                                        oz/gal.  ^v

                                                        dynes/cm/
                                                         Volts
                                                         Amperes
                                                         A-hr
                                                         A/ft2
                                                         pcs.
                                                         ft2
                                                         min/test run
                                                         min/test run

-------
FROM :SCIENTIFIC CONTROL  LflBS
                                       FflX NO.  :17732546661
                                                              Oct. 31  2005 09:20RM   Pi
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET
Company Maine .
                                       <-<
         Tank Identification
Plating Type;
     n.     -    T
Tank Dimensions: L
                        \3-\y
Rectifier Rated Capacity: J _ I
                                     W
                                     w
H
                                                 31
                                                                      (Units
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampcre-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Wi thin Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation  Rate (estimated)
              3/0
               [.M'

                6
         s:\cngineer\airtstack lest process data wKS
                                  I3o -/HV>
                                «&/
                                   WS
                                                                      	Amperes
                                                                      ~	A-hr
                                                                           A/ft2
                                                                          _pcs.
                                                                           ft2
                                                                          _ min/test run
                                                                           min/test nm
                                                                           %
                                                                           acfm
                                                                           scfm
                                                                          _gpm
                                         \,ai

-------
FROM :SCIENTIFIC CONTROL  LABS
FflX NO,  :17732546661
                                                               Oct.  31 2005 09:20flM   Pi
        rsiCKELAU* TEST PROJECT
        PROCESS DATA SHEET
                 Name
         Tank Identification,
Tank Dimensions: L _J|(2__  W_

                  :ity:  1S\)
                                                      H
                        ,     >.

                       l5. J
                                                                     I h    )
         Rectifier Rated Capacity:
         Operating Conditions Recorded During Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
         s:\engimser\airtstack lust process data wksht-wpd

                            ^Ul^iH,*1
                                    dyn<;s/cm
                                   "SG
                                   ' Volts
                                    Amperes
                                    A-hr
                                   ^A/ft2
                                   .PCS.
                                   .ft2
                                    min/test ran
                                    mill/test run

                                    acfin
                                    scfm
                                   _gpm

-------
FROM SCIENTIFIC CONTROL LflBS
                              FflX NO.  :17732546661
                                                                      Oct. 31  2005 09:20flM  PI
NICKEL AIR TEST PROJECT     /\
PROCESS DATA SHEET

Company Name	;  l  v ^ ^—
Tank Dimensions: L
                                     W
Rectifier Rated Capacity
                            it:  \o^L
         Operating ConditionsRgcgnied During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH   .
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
         s:\cngineer\airtstack test process data wksliuwpd
   9xci i*"2-
                                                                                   /Hal
                                                             (Units_
                                                           .MO  F
                                                          	_oz/gal.
                                                          _      pll
                                                          	 dynes/cm
                                                          	"_ SO
                                                          	\ Volts
                                                          	Amperes
                                                              '   A-hr
                                                                 A/ft2
                                                                  pcs.
                                                                  ft2
                                                                  min/test am
                                                                  min/test run
                                                                  %
                                                                  acfm
                                                                  scfm

                                                                  gpm     ^A
                                                                     _ [0^0

-------
FROM : SCIENTIFIC CONTROL LABS
                                       FOX  NO.  :1773254S6S1
                                                                      Oct.  31 2005  09:20fiM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
                   *   -
         Tank Identification
                3
         Operating Cnnrlifions Rcco^^ '>mnP Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
Plating Type:
fa
Tan* 1 )imensions. L v
Rectifier Rated Capacity: _
•j e
w
uv
^i" H 0^*^3 (Units '«->— ,k^> ^ \)
                     \HH
          s:\cnginwsr\airVstack test process data wksht,wp
                -^
T'6'1
 a ^7 J Inches
  JX}^F
  _      oz/gal
  	_oz/gal.
  	pll
  	_dynes/c
  	*_ SO
  	Volts
  	Amperes
         A-hr
         pcs,
        .ft2
         min/test mn
   _il?O min/test run
         acfm
         so Cm
         gpm

-------
FROM :SCl&iTIFIC CONTROL  LflBS
                                       FflX NO.  :17732546661
                                                                       Oct.  31 2005 09:20flM  PI
        NICKEL All* TEST PROJECT
        PROCESS DATA SHEET
         Company Name
         w  .   T
         Plating Type:
                                                                                       Mo
         Tank Dimensions: L
         Rectifier Rated Capacity:
         Oggrating C
                                  ^ During Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation  Rate (estimated)
 pcs.
 ft2
 mitt/test am
 mm/itest run

 acfin
 scfm
.gpm
         s:\cnBine*rtair\stack lest [irnoess data wkstiLwpd
                                                                                                         Jwt

-------
FROM : SCIENTIFIC  CONTROL LABS
                                       FfiX NO.  :17732546661
                                                              Oct.  31  2005 09:20fiM   PI
MCKEL AIR TEST PROJECT
TROCISS DATA SHEET
         Company Name
         Plating Type:
Tank Dimensions: L
                             W
         Rectifier Rated Capacity:

         Rintf _ __.
                                       - *LS
                                             H
         Operating Conditions Record l^riflg Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation  Rate (estimated)
                                                                          (\v0
                                                                             \s\
                                                                    _
                                                                  mill/test run
                                                                  min/test i"un
                                                                  %
                                                                  acfm
                                                                  scfm
                                                      -10:25
          s:\engineer\airtstiick lest pmccss 'dau wkitit-wpd
                                                 ^
                                                 7

-------
FROM :SCIENTIFIC CONTROL LflBS
  FOX NO.  :17732546661
                                                                       Oct.  31 2005 09:20flM   Pi
        NICKEL AIR TEST PROJECT
        PROCESS DATA SHEET
        Company Name
        Tank Identification.

        Plating Type;	
        Tank Dimensions: L
w
        Rectifier Rated Capacity:
        Run#
         Operating Conditions Recorded During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Denkity
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
        s:\pngineer\airVitsck Lest praciss data wkstitwpd
                                                                      qjnits Jig   )
                              	 dynes/cm
                              	'"___ SG
                              	Volts
                              	Amperes
                                  '   A-hr
                              	A/ft2
                              	pcs.
                                	ft2
                              j PIT  min/test run
                                     min/test run
C&L   V&
     fbf&

-------
FROM :SCIENTIFIC CONTROL  LftBS
                                       FRX NO.  :17732546S61
                                                                      Oct. 31  2005 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET
         Company Name
                                                                 |i?o
         Tank Dimensions
                   /•J-V

               : L _£_ _
                                              k
                                                      H
Rectifier Rated Capacity
                            it:   \&\/
         Operating Conditions Recorded During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Atnpere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture  Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                         JM
                                                         3 (.1 ; Inches
                                                          W'F
                                                          ______ oz/gal'
                                                          	 oz/gal
                                                          	pll
                                                          	 dynes/cm
(AS
                                                                 Volts
                                                                 Amperes
                                                                 A-hr
                                                                 ^A/ft2
                                                                 pcs.
                                                                 .ft2
                                                                 min/test run
                                                                 min/test nin

                                                                 acfrn
                                                                 scfm
                                                                 .gpm
         s:\cngineer\airlitflck test process data wksht.wpd

-------
FROM :SCIENTIFIC CONTROL LflBS
                                      FOX NO.  :17732546661
      Oct.  31 2005 09:20fiM  'Pi
         mCKEL AIR TEST PROJECT
         PROCESS DATA SHEET
         Company Name
         Tank Identification
         Tank Dtawta. L
         Rectifier Rated Capacity;
         Operating Conditions Recorded During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
} O)
         F
         p*1   >
         Volts
         Amperes
         A-hr
         >fe
         pcs.
         .ft2
         min/test run
         min/test run

         acfm
         scfm
K«L   %0'ij
         s:\cngineer\airtstack lestpraccss dau wkshtwpd

-------
FROM :SCIENTIFIC CONTROL LABS
FfiX NO.  :17732546S61
                                                                       Oct.  31 2005  09:20firi  PI
         NICKEL A1K TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
         Tank Identification

         Plating Type:

         Tank Dimensions: L

         Rectifier Rated Capacity:
         Operating Conditions Bc;corded During Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Sohition Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
         s:\cnjjmcer\airtstack test process data wksfit-wpd
                           )
Inches
                                       .  .  .
                                    07/gal\
                                    oz/gal.  \
                            _
                            __ _ dynes/cm/
                              f 01   min/test run
                              tlD  min/test run
                                                         ^cku

-------
FROM :SCIENTIFIC CONTROL LflBS
                                      FflX NO.  :17732546661
                                                                      Oct.  31 2005 09:20fiM  PI
                                                413
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET
         Company Name
         Tank Identification,

         Plating Type:	
         Tank Dimensions: L
         Rectifier Rated Capacity:
          Freeboard Height:
          Plating Solution Temperature
          Plating Solution "Nickel Cone.
          Plating Solution Boric Acid Cone.
          Plating Solution pH
          Plating Solution Surface Tension
          Plating Solution Specific Gravity
          Plating Voltage
          Average Amperage Applied
          Calculated Ampere-Hr Usage
          Calculated Current, Density
          Number of Dummy Parts
          Total Surface Area of Plated Parts
          Plating Period Within Test Run
          Duration of Test Run
          Capture Efficiency of Ventilation System
          Ventilation Rate
          Air Agitation Rate
          Solution Circulation Rate (estimated)
                                                       >(_ 3'/Inches
                                                        i i|Q"" F
                                                               oz/gaT
                                                               oz/gal
                                                        .	^P"
                                                        	 dynes/cm
                                                        	^_SG
                                                        	' Volts
                                                        	Amperes
                                                           '    A-hr
                                                               A/ft2
                                                               pcs.
                                                               ft2
                                                               min/test run
                                                               min/test run
                                                               .%
                                                               acfm
                                                               scfm
                                                               .g?m
                                                 3^—  3;asr         ^:5o
                                                                                              N
                                                                                                 "m^ IJ
^
:\(inBinwr\airt.ita=k lest process dau wkshuwpd
           s:\(i

-------
FROM : SCIENTIFIC CONTROL LABS
                                      FflX NO.  :17732546661
                                                                     Oct. 31 2005 09:20flM   PI
         NICKEL A1K TEST PROJECT
         PROCESS DATA SHEKT
         Company Name.

         Tank:
               .     •
         Tank Dimensions:
         Rectifier Rated Capacity:
         Run#
                                                                                                   T>M)
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
	Amperes
    A-hr
    A/ft2

-------
FROM :SCIENTIFIC  CONTROL LRBS
                                     FflX NO.  :17732546661
                                                                   Oct. 31 2005 09:20flM  PI
        NICKEL A1K TEST PROJECT
        PROCESS DATA SHEKT
        Company Name
        Tank identification

    0-. ll
s: L_1y-
         Tank Dimensions:

         Rectifier Rated Capacity;
                                    W
T6|hl
                                                                   (units
                                          Testing:
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation  Rate (estimated)
                                                Inches

                                                -F
                                               _ oz/gal \
                                               __oz/gal  V
                                               _pll      )
                                               __ dynes/ci»
                                               _ SG   /
                                               _ Volts
                                               _ Amperes
                                               _ A-hr
                                               _A/fe
                                               _pcs.
                                                 min/test ntn
                                                 min/test run
                                                 %
                                                 acfm
                                                 scfm
                                                                        I»T     m-jiH
         s:\enginrtr\aii4tock Lest ifccciidau wks>it,wpd

-------
FROM :SCIENTIFIC CONTROL LflBS
                                      FOX  NO.  :17732546661
                                                                      Oct. 31 2005 09:20PM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
         Tank Identification,

         Plating Type:
                                                             -  Acv.
sions: L   T Q_
         Tank Dimensions

         Rectifier Rated Capacity:

         Run#J^>A
                                     W
      a'jro-  v-Stf
                                           : Testing!
          Freeboard Height:
          Plating Solution Temperature
          Plating Solution Nickel Cone.
          Plating Solution Boric Acid Cone.
          Plating Solution pH
          Plating Solution Surface Tension
          Plating Solution Specific Gravity
          Plating Voltage
          Average Amperage Applied
          Calculated Ampere-Hr Usage
          Calculated Current Density
          Number of Dummy Parts
          Total Surface Area of Plated Parts
          Plating Period Within Test Run
          Duration of Test Run
          Capture  Efficiency of Ventilation System
          Ventilation Rate
          Air Agitation Rate
          Solution Circulation Rate (estimated)
                                                       dynes/cm
                                                 	....	  J       i
                                                 	 SO
                                                  O   " Volts
                                                       Amperes
                                                       mill/test run
                                                       min/test mn

                                                       acfm
                                                       scfm
                                                      .gpm
           s:\ongineSrtaiiAstack WSt proces

-------
FROM : SCIENTIFIC CONTROL LfiBS
                                       FRX  NO.  :17732546661
                                                                      Oct.  31  2005 0g:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET

         Company Name

         Tank Identification

         Plating Type:

         Tank Dimensions: L

         Rectifier Rated Capacity; _ \^_
Operating ConditjoniRccoided During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone,
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                          pcs
                                                                          ft2
                                                                          mill/test run
                                                                          min/test run

-------
FROM :SCIENTIFIC  CONTROL LflBS
                                       FfiX  NO.  :1773254SS61
                                                                       Oct. 31 2005 09:20fiM   PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET
         Company N anie
         Tank Identification.

         Plating Type;	
         Tank Dimensions; L
                                -
         Rectifier Rated Capacity; _'0VV__
                                       '
                                             Testing!
          Freeboard Height:
          Plating Solution Temperature
          Plating Solution Nickel Cone,
          Plating Solution Boric Acid Cone.
          Plating Solution pH
          Plating Solution Surface Tension
          Plating Solution Specific Gravity
          Plating Voltage
          Average Amperage Applied
          Calculated Ampere-Hr Usage
          Calculated Current Density
          Number of Dummy Parts
          Total Surface Area of Plated Parts
          Plating Period Wi thin Test Run
          Duration of Test  Run
          Capture Efficiency of Ventilation System
          Ventilation Rate
          Air Agitation Rate
          Solution Circulation Rate  (estimate 1)
                       '1-
           s:\cngineeAairtstiick test process data wkslltwpd



                             I


                             I
          FV\a
                                                                       (Units   iV*  )
pcs.
ft2
min/test ran
min/test run

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Tank Identification
Plating Type:
WkVb  [W^J
Tank Dimensions: L   f-,\     W	
                     i           i

Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation  Rate (estimated)
    /HOD  Amperes
                >)3
                                                                   A
                                                               trwa J
W/Urft2
   \\Q'   min/test run
   I<5.t7   mm/test run
                                                             IVSf- H'.?v)
s:\en2ineer\air\stack test process data wksht.wpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
LQ
\L
                                      ^
Tank Identification^
Plating Type:
Tank Dimensions: L
                             W
                        H
Rectifier Rated Capacity:
                                                   *
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration o f Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                . (Units
                                             dynes/cm
                                             SG
                                             Volts
                                             Amperes
                                             A-hr
                                             pcs.
                                             ft2
                                             min/test run
                                             min/test run

                                             acfm
                                             scfm
                                             gpm
                                                  R-.ot- DW
                                                  id'.U- I-.3&
s:\engineer\airN5tacl<: test process data wksht.wpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
Tank Identification,

Plating Type:	
                                                                    6(Tlf
                        N
Tani Dimensions: L
W
                                             H
Rectifier Rated Capacity: ^ v   11X^ *&^0
                                                             (Units
Rua#
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density         "*
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation  Rate (estimated)
                                                                  pcs.
                                                                  ft2
                                                                  min/test run
                                                                  min/test run
                                                                  %
                                                                  acfm
                                                                  scfm
s:\engineer\air\stack test process dam wkshtwpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification
Plating Type:

Tank Dimensions: L  T^      W   ^       H   '^>  ^J  . (Umts_\A	)

Rectifier Rated Capacity: CT o ^

Run#	L

Operating Conditions Recorded During Testing:.

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run                               fV  , mm/test run
Duration of Test Run                                         ^3__ min/test run
Capture Efficiency of Ventilation System
Ventilation Rate           .                                  _-	acfin
Air Agitation Rate                                       '     ANW"   scfcl
 Solution Circulation Rate (estimated) _                         _0J	SPm
 s:\engineer\air\stack test process data wksht.wpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Plating Type:
                  \Nft
Tank Dimensions: L _
                             W
                                              H
(Units
Rectifier Rated Capacity:
                                                    MX
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy P arts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                             Vft  .  Volts
                                                            HQD  Amperes
                                                                   A-hr
                                                                   A/ft2
                                                                   min/test run
                                                                   rain/test run
                                                                   % -
                                                                   acfm
                                                                   scfm
 s:\en°ineer\ai-Astack test process data wksht.wpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
Tani Identification

Plating Type:
                            KnAcJ    flMEul
                              KiVtU
Tank Dimensions: L_
                             w
H
(Units \ A	)
Rectifier Rated Capacity:
Run#
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation  Rate (estimated)
                                                          '*' l\ -oA
                                                             U-° J Inches
                                                           IMP   F
                                                           	oz/gal
                                                                  oz/gal
                                                                  pH       /
                                                                  dynes/cpr
                                                                  SG  X
                                                                  Volts
                                                                  Amperes
                                                                  A-hr
                                                                  AVft2
                                                                 .ft2
                                                                  min/test run
                                                                  Him/test run
                                                                 .%
                                                                  acfm
                                                                  scfm
                                                                 _gpm
s:\etigineer\airN£tack test process data wkshtwpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET

Company Name  A
-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name _
                                         C
Tanl Identification
Plating Type:
Tank Dimensions: L
                             W
H          (H\) (Units
Rectifier Rated Capacity:

Run#_

Operating Conditions Recorded During Testing:

Freeboard Height:
P lating S o lution Temp eratur e  ,
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                  Volts
                                                                  Amperes
                                                                 'A-hr
                                              >S«r
                                                           QD
                    .ft2
                    mm/test run
                    min/test run
                    .%
                    acfm
                    scfm
                    _gpm
s:\engineer\air\stack test process data wkshtwpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification
Plating Type:
Tank Dimensions: L
                             W
                                             H
(Units
             WV
Rectifier Rated Capacity:

Run#   ^>

Operating Conditions Recorded During Testing;

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                         ft»k   Ck &W&
                                                                          i *                 \j
                                                           &3
                                                           &JP-T pcs.
                                                            ^rq- ft2
                                                            ilk
   _ min/test run
    min/test run
   ~%
    acfm
fovl,  <**"/
       jW
      lib-
      3:^-
 m
 ^)
^
 s:\engineer\air\stack test process data wksht.wpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Tank Identification

                                                                  lib
Plating Type:
Tank Dimensions: L
                              w
H
(Units
                                                                     V
Rectifier Rated Capacity:
                                        .
Operating Conditions Recorded Plains: Testme

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                            L|/\jC)   Amperes
                                                                   A-hr
                                                                   A/ft2
                                                                   pcs.
                                                                   min/test run
                                                                   min/test run
                                                                   acfm
                                                            _|4Di   scfm
                                                                   _gpm
 s:\ensineeT\air\stac~k test process data wkshtwpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
Taak Identification
Hating TW=:
Tank Dimensions: L
               tWK
Rectifier Rated Capacity:^ V
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
     ,
oz/gal\
oz/gal  X
pH      >
dynes/cr/
SG  -/
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
mm/test run
mm/test run

acfm
scfm
,gpm
 s:\engineer\air\stack test process data wkshtwpd

-------
NICKEL AIR TEST PROJECT
PROCESS DATA SHEET
Company Name
C
                                        ft
Tank Identification
Plating Type:
Tank Dimensions: L
W
                                              H
                         (Umts
Rectifier Rated Capacity?H^
       \
Operating Conditions Recorded During Testing:

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                     \ 1  MVA      vW
                     V  I)S  J    r^i^w
             IM1-JSC
                                                                   F
                                                                   oz/gal
                                                                   oz/gal
                                                                  ^PH
                                                                   d3/nes/c:
                                                                  "SG   /
                                                                   Volts
                                                                   Amperes
                                                                   A-hr
                                                                   A/ft2
                                                                   pcs.
                                                                   ft2
                                                                   mm/test run
                                                                   min/test run
s:\engineer\air\stacktestprocess data wkshtwpd

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name
                        nt
Tank Identification

Plating Type:	
                               NvcUl
 Tank Dimensions: L
 Rectifier Rated Capacity:
 Run#
 Operating Conditions Recorded During Testing:
1 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated. Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                                                   '    V.
                                                                 oz/gal \
                                                                 oz/gal  \^
                                                                 :PH       >
                                                                 dynes/cm/
                                                                 'SG   X
                                                                 Volts
                                                                 Amperes
                                                                 A-hr
                                                                 ^A/fr2
                                                                 pcs.
                                                                 >  •
                                                                 mm/test run
                                                           1 ^D  min/test run
                                                                 o/.
 s:\en2iiieerVir\stacK test process data wksht.wpd
    ~IW*     \6

-------
 MCKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name	\
                    1
 Tank Identification	

 Plating Type:     lAv^Al
 Tank Dimensions: L
    (Units
 Rectifier Rated Capacity:    \ \j
 Run#
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
5*01
     Sva
     »er\2jj-\gtadk test process dara.v^sht.wpd
     • "v*"i t> /TQ -^       M J
             aiM- »a;si
            "%?
            ^y«
              j0/ m>
                                                                  m
                                                                                j
                                 S-0
    n^(Q4    iQ4-  r.3
    >.D        ^-^
                 qnfi
                 i^
                                                                                  t./
                                                          to
                                                            vo
                                                                       '^4ffl

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name _
 Tank Identification
 Plating Type:
 Tank Dimensions : L
                    Oi
                    ./•2
                                                                  min/test run
                                                                  min/test run
                                                                 '%
                                                                  acfm
                                                                  scfhi

-------
FROM : SCIENTIFIC CONTROL LflBS
                                      FPX NO.  :17732546661
                                                                      Oct.  31 2005 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
Company "Name
                                                71
                                                                                   Ac
         Tank Dimensions: L
                    S§
W
                                            ^
Rectifier Rated Capacity
         Rut»#
                              :    I  ^  °
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution "Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total S urface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation  Rate (estimated)

                   61" Off
                                                                      (Units  v
                                                                Inches
                                                          \1\   "F
                                                          	oz/gal

                                                          	_dynes/ctr
                                                          	"_ SG
                                                          	' Volts
                                                          __	Amperes
                                                                 A-hr
                                                                                           U Rfs.

-------
FROM : SCIENTIFIC CONTROL LflBS
                                      FPiX NO.  : 17732546S61
                                                                     Oct. 31 2005 03:20fiM   PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
         Rectifier Rated Capacity:
                                                                     (Units, in   )
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Pails
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
          Ventilation Rate
          Air Agitation Rate
          Solution Circulation Rate (estimated)
                       ^
\3'D
KA
 pcs.
.ft2
 min/test run'
 min/test am
!%
 acfm
 scfrn
.gpm
                                                                                                   .^^:o8
                                                                                                    ->S  f ift V.

-------
   FROM : SCIENTIFIC CONTROL  LABS
                                           F;3X NO.   :17732546661
                                                                           Oct.  31  2005 09:20QM   Pi
vote
             NICKEL A1K TEST PROJECT
             PROCESS DATA SHEKT
Company Name

Tank
                                             . — - - — - —
             Plating Type:
                         -    T
             Tank Dimensions: L
                                          W
                                          w
                                                          H
                                                          n
             Rectifier Rated Capacity:  _
                          gjjjygtig Testing!
             Operating Conditions
             Freeboard Height:
             Plating Solution Temperature
             Plating Solution Nickel Cone.
             Plating Solution Boric Acid Core.
             Plating Solution pH
             Plating Solution Surface Tension
             Plating Solution Specific Gravity
             Plating Voltage
             Average Amperage Applied
             Calculated Ampere-Hr Usage
             Calculated Current Density
             Number of Dummy Parts
             Total Surface Area of Plated Parts
             Plating Period Within Test Run
             Duration of Test Run
             Capture Efficiency of Ventilation System
             Ventilation Rate
             Air Agitation Rate
             Solution Circulation Rate
             S'\cngine«r\airt.itiick test process dau wkshtwpd
                                                               	Ampere,
                                                               "	A-hr
                                                                   A/ft2
                                                                   pcs.
                                                                   ft2
                                                                   min/test run
                                                              d-'°' min/test run
                                                                   i b TI .3,1  // -> />

-------
FROM : SCIENTIFIC CONTROL LfiBS
                                      FflX NO.  :177325466S1
                                                                      Oct.  31  2005 09:20f¥1  PI
NICKEL A1K TEST PROJECT
PROCESS DATA SHEKT

                    PA  ^f
Company Name	  £? ^ l..li—
              Identification,
                                                             j/"
                                                              \
         Plating Type:
         Tank Dimensions: L
                                             nMm
                                                                      fllnits
         Rectifier Rated Capacity:,  i V.
         Run*
 Operating Coitions Rcr'"-fteri louring Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                 a
                                ;f
                            s data wk5ln.wpd
                                                                }

                                                                          oz/gal
                                                                         "  IT
                                                                          pll
                                                                          dynes/cm
                                                                          Volts
                                                                          Amperes
                                                                          pcs.
                                                                          ft2
                                                                          min/test run
                                                                          min/test run

-------
FROM : SCIENTIFIC CONTROL LOBS
                                     FfiX NO.  : 17732546661
                                                                    Oct. 31 2005 09:20RM   PI
                            v\
        NICKEL A1K TEST PROJECT
        PROCESS DATA SHEKT
         Company Name

         Tank

         PlatingType:
         Rectifier Rated Capacity:
                                        __.__


                                                                 J_ (Units JIL__)
         noting Condition* Eccnrded During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                               *•
                                  st
                   •               -  •
          s:\cngin»ai*itaok lest process data wsT)t>p<
3'Y9")
                                                    a to
                                                    gAo
Inches
F
          dynes/cm
         'so
          Volts
          Amperes
          A-hr
         .PCS.
         .ft2
          mill/test run
          min/test run
         .gpm
ft
                                                                                #05*
                             L^

-------
FROM .'SCIENTIFIC  CONTROL LflBS
                              FflX NO.  :17732546661
Oct.  31 2005 09:20RM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name.
                               N ifrWi

Tank Dimensions; L
                              -^ ^    W  ^rr?        H  v> I
Rectifier Rated Capacity
                U HO -
                            ity:   ') V M K
                 R
         Operating Conditions Recorded During Testing!

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Cuirent Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                             (Units
                                                                  Volts
                                                                  Amperes
                                                                  A-hr
                                                                  A/ft2
                                                             ^_pcs.
                                                                 .ft2
                                                                 min/test run'
                                                                 min/test run
                                                                  acfm
                                                                  scfm
                                                                 _gpm
         s:\cngineer\aiiAstflck lest prnccSS data wkshtwpd
                MR

-------
FROM .'SCIENTIFIC CONTROL .|_A8S
                              FflX NO.  :17732546661
                                                                       jcx.  31 2305 09:20fiM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET

         Company Name	^	._
        Tank Identification,
         Plating Type:
Tank Dimensions:
                            W
                                            ±

        Rectifier Rated Capacity:
         Operating Conditions Recorded During Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Pkting Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                             Crul""W  <
(Units
                                                                    iiA
                              U
                                                                                             u
                                                                  Volts
                                                                  Amperes
                                                                  A-hr
                                                                  A/ft2
                                                                  pcs.
                                                                 .ft2
                                                                  mill/test run
                                                                  mm/test run

                                                                  acftn
                                                                  scfm
                                                                 .gPm
        s:\engin«iltir\stack last process data wkslitwpd

                                                                                                  DV

-------
FROK : SCIENTIFIC  CONTROL LflBE
FAX NO.  :17732546661
                                                                    Oct. 31 2085 09:20flM
        NICKEL A1K TEST PROJECT
        PROCESS DATA SHEET
        Company Name
        Tank Identification,

        Plating Type:	
        Tank Dimensions:
        Rectifier Rated Capacity:
        Operating Conditions Recorded During Testing

        Freeboard Height:
        Plating Solution Temperature
        Dating Solution Nickel Cone.
        Plating Solution Boric Acid Cone.
        1'Mating Solution pH
        Plating Solution Surface Tension
        Plating Solution Specific Gravity
        Plating Voltage
        Average Amperage Applied
        Calculated Ampere-Hr Usage
        Calculated Current Density
        Number of Dummy Parts
        Total Surface Area of Plated Parts
        Plating Period Within Test Run
        Duration of Test Run
        Capture Efficiency of Ventilation System
        Ventilation Rate
        Air Agitation Rate
        Solution Circulation Rate (estimated)
                                                   fk,&«"
                                              £0u k*


                                               [&u\\

-------
FROM : SCIENTIFIC CONTROL LPI3S
           FflX NO.  :17732546661
        NICKEL A1K TEST PROJECT
        PROCESS DATA SHEKT
        Company Name
        Plating Type: _
        Tank Dimensions:
        Rectifier Rated Capacity:
*,.  3-v
        Operating Conditions Recorded During Testing:

        Freeboard Height:
        Plating Solution Temperature
        Plating Solution Nickel Cone.
        Plating Solution Boric Acid Cone.
        Plating Solution pH
        Plating Solution Surface Tension
        Plating Solution Specific Gravity
        Plating Voltage
        Average Amperage Applied
        Calculated Ampere-Hr Usage
        Calculated Current Density
        Number of Dummy Pails
        Total Surface Area of Plated Parts
        Plating Period Within Test Run
        Duration of Test Run
        Capture Efficiency of Ventilation System
        Ventilation Rate
        Air Agitation Rate
        Solution Circulation Rate (estimated)

-------
FROM : SCIENTIFIC  CONTROL LflBS
                                       FflX NO.  :17732546661
                                                                       Oct.  31 2005 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEET

         Company Manic

         Tank Identification

         Plating Type; _

         Tank Dimensions: L

         Rectifier Rated Capacity;

         Run#
min/test nm
min/test run
         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone,
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
         s:\cngineer\airVitack test process data wks!lt,wpd

-------
FROM : SCIENTIFIC CONTROL LflBS
                                       FflX NO.  : 177325466S1
                                                                       Oct.  31 2805 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
         Tank identification
                     -
         Tank Dimensions:
Rectifier Rated Capacity
                              : J^Y

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation  Rate (estimated)
                                                                            ches
                                                                               J\
                                                                           oz/gal  \

                                                                                   7
                                                                               3/cnv.
                                                                                  /
                                                                           Amperes
                                                                           A-hr
                                                                           A/ft2
                                                                           lllin/test mn
                                                                                 __     i
                                                                           S1
         s:\cnjsine«r\airtstiick lest process data wkshtwptl

-------
FROM : SCIENTIFIC CONTROL LflBS         FOX NO.  : 17732546661 "         Oct. 31  2005 09:20flM  PI
         NICKEL A1K TEST PROJECT
         PROCESS DATA SHEKT
         Company Name.
         Tank Identification,

         Plating Type:	
         Tank Dimensions: L
                                                                                          t't
         Rectifier Rated Capacity:

                 2> .       ?
          Freeboard Height:                                      ^  (U&r-'F
          Plating Solution Temperature                                 -	^^
          Plating Solution Nickel Cone.                                 —    QZ/   ,
          Plating Solution Boric Acid Cone.	 ^
          Plating Solution PH                                         —    dynes/cm
          Plating Solution Surface Tension                              	gG
          Plating Solution Specific Gravity                               -^JQ  ' Volts
          Plating Voltage                                              'ji^ Amperes
          Average Amperage Applied                                  -77^  ^
          Calculated Ampere-Hr Usage                                   3^.. A/ft*
          Calculated Cuirent Density                                     "£   pcs.
          Number of Dummy Paits                                       Q t  ff
          Total Surface Area of Plated Parts                             -^- ^^ mn
          Plating Period Within Test Run                               —— ^^ ^
          Duration of Test Run                                        —^   ^
          Capture  Efficiency of Ventilation System                      —	^^
          Ventilation Rate                                               ~   g(,|-m
          Air Agitation Rate                                             3
          Solution Circulation Rate (estimated)                         	
          s:\enBineer\airtstaok lest process data wksht,wpd

-------
FROM : SCIENTIFIC CONTROL LfiBS
                                       FflX  NO.  :17732546661
                                                                       Oct.  31  2005 09:20flM  PI
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
Company Name.

Tank:
         Plating Type:
         Tank Dimensions; L
                                     W
         Rectifier Rated Capacity:
Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                                   k)/
                                                                           dynes/cm
                                                                           SO
                                                                           Volts
                                                                           min/test run
                                                                           min/test run
                                                                           acftn
                                                                           scfm
                       st llroccs

-------
FROM : SCIENTIFIC CONTROL  LflBS
                                       FflX NO,  :17732546661
                                                                       Oct.  31 2005 09:20flM   PI
         NICKEL MB TEST PROJECT
         PROCESS DATA SHEKT
Company Namc

                                          —          — — p   j
Tank Dimensions; L
                                     w
.H.U
         Rectifier Rated Capacity:
Operating CQndjtionsJcgorded During Testing!

Freeboard Height:
Plating Solution Temperature
Plating Solution Nickel Cone.
Plating Solution Boric Acid Cone.
Plating Solution pH
Plating Solution Surface Tension
Plating Solution Specific Gravity
Plating Voltage
Average Amperage Applied
Calculated Ampere-Hr Usage
Calculated Current Density
Number of Dummy Parts
Total Surface Area of Plated Parts
Plating Period Within Test Run
Duration of Test Run
Capture Efficiency of Ventilation System
Ventilation Rate
Air Agitation Rate
Solution Circulation Rate (estimated)
                                                                      (Units..
                                                                          .Inches

                                                                           07/gal  >v
                                                                          .oz/gal   \7
                                                                           pll        /
                                                                           dynes/cny
                                                                          'SG     *
                                                                    1-fO   Volts
                                                                           Amperes
                                                                           ft2
                                                                           min/test am
                                                                           min/test run
         s:\cnginrtr\aiiVttack lest process daU wkitlt-wpd

-------
FROM :SCIENTIFIC CONTROL LfiBS
                              FOX NO.  :17732546661
Oct.  31 2005  09:20PM  PI
                                                                                   A
         NICKEL AIR TEST PROJECT
         PROCESS DATA SHEKT
         Company Name
                                                         Co,
         Tank Identification,

Plating Type;	

Tank Dimensions; L
                                     W
                                                                               A  )
         Rectifier Rated Capacity:
         Run#
                 •*--      VM-   i
         Operating Conditions Recorded During Testing:

         Freeboard Height:
         Plating Solution Temperature
         Plating Solution Nickel Cone.
         Plating Solution Boric Acid Cone.
         Plating Solution pH
         Plating Solution Surface Tension
         Plating Solution Specific Gravity
         Plating Voltage
         Average Amperage Applied
         Calculated Ampere-Hr Usage
         Calculated Current Density
         Number of Dummy Parts
         Total Surface Area of Plated Parts
         Plating Period Within Test Run
         Duration of Test Run
         Capture Efficiency of Ventilation System
         Ventilation Rate
         Air Agitation Rate
         Solution Circulation Rate (estimated)
                                                                 oz/gal
                                                                 oz/gal.
                                                                 pll
                                                                 dynes/cm
                                                                 mill/test ran
                                                                 min/test run

                                                                 acfm
                                                                 scfffl
                                                                _gpm
        s:\engincer\aii'\stack lest process data wk

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name
                                    p\
 Tank Identification

 Plating Type:
Tank Dimensions: L
                              W
H
Rectifier Rated Capacity:   '  O Vp n


          I:   y.jt) "(0'^
          *   .......   . i 1f A \

 Operating Conditions Recorded.During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone:
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Numb er o f Dummy P arts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
A
(fo\U\J
                                                   170
s:\engineer\air\stack test process data wkshtwpi

-------
                  I
                      J?
4
-t-
                4
                     0.855-
                                    ix

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name
 Tank Identification

 Plating Type:
 Tank Dimensions: L  JV      W_j>0' _ H

 Rectifier Rated Capacity:
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation  Rate (estimated)
 s:\sngineer\airNstack test process data wksht.wpd

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
  Company Name
                                              U5
 Tank Identification
 Plating Type:
 Tank Dimensions: L
W
H
                                                                (Units 1A
 Rectifier Rated Capacity:
 Run#
                            >-  I'U
. Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                                                   pcs.
                                                                   ft2
                                                                   mm/test run
                                                                   min/test run
                                                                   ox
s:\sngineer\airtstack test process daia wksht.wpd

-------
  NICKEL AIR TEST PROJECT
  PROCESS DATA SHEET
  Company Name
 Tank Identification
 Plating Type:
 Tank Dimensions: L
w
(Units_
 Rectifier Rated Capacity:   \ 0^t?U$
       9       Q'JV? -S'.lfo
 Run#  J?     -«•,_,    n
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                     pcs.
                                     ft2
                                     min/test run
                                     min/test run
 s:\engineer\air\stack test process data wkshtwpd

-------
  NICKEL AIR TEST PROJECT
  PROCESS DATA SHEET
  Company Name
  Tank Identification
 Plating Type:
 Tank Dimensions: L
 Rectifier Rated Capacity:  | ^

 Run#
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Numb er of Dummy P arts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
Inches
 F,   /
 oz/gaf\
 oz/gal \
 PH      V
 dynes/crjy
 SG   X
 Volts
 Amperes
 A-hr
 A/ft2
 pcs.
 ft2
 min/test run
 min/test run

 acfm
 scfm
 gpm
s:\engineeAair\stack test process data wkshtwpd

-------
  MCKEL AIR TEST PROJECT
  PROCESS DATA SHEET
Company Name
                                                            lC>/l   x"
Tank Identification     t\.b|)J    Nvc£j   UNljfe

Plating Type:	|A]&OJ    NiC'W
                                                    u

Tank Dimensions: L
                              w
 Rectifier Rated Capacity:

 Run*   3      *|V*>
      	     li'.Sl-   'iJl
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                                                                   Dl
                                                                 Amperes
                                                                 A-hr
                                                                 A/ft2
                                                                 pcs.
                                                                 ft2  .
                                                                 min/test run
                                                                 min/test run
s:\enginesr\air\stack test process data wksht.wpd

-------
  NICKEL AIR TEST PROJECT
  PROCESS DATA SHEET

  Comp any Name

  Tank Identification

  Plating Type:

  Tank Dimensions: L

  Rectifier Rated Capacity:

  Run#
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
' Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy P arts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
 min/test run
 min/test run
!°/°
 acfrn
 scfin
_gpm
s:\engineer\2ir\stack test process data wkstit.wpd

-------
  MCKEL AIR TEST PROJECT
  PROCESS DATA SHEET
  Company Name
 Tank Identification
                                       cr
 Plating Type:
 Tank Dimensions: L
W
(Sis'
(Units
 Rectifier Rated Capacity:  \Q N|

 Run#_L_        ^"^ -  10'!S
                     10'-if~ liVi
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
                                    min/test run
                                    min/test run
                                    '%
                                    3.cfm
                                    scfm
                                    gpm
s:\engineerVir\stack test process data wksht.wpd

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name
Tank Identification

Plating Type:	
                              Kckl
 Tank Dimensions: L

                             w
Rectifier Rated Capacity:
                          -*
                      :   t^ V
 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating sSolution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts '
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
3
                                                            QTD
Inches
F
oz/gal\
oz/gal  \
PH     >
dynes/en/
SG    ^
Volts
Amperes
A-hr
A/ft2
pcs.
ft2
min/test run
min/test run
                                                                  acfm
                                                                  scfm
s:\engineer\air\stack test process data wksht.wpd

-------
 NICKEL AIR TEST PROJECT
 PROCESS DATA SHEET
 Company Name
Tank Identification
                                               SWW
 Plating Type:
Tank Dimensions: L
                              W


^
                                                              (Units
                        ^^
 Rectifier Rated Capacity:

 Run#

 Operating Conditions Recorded During Testing:

 Freeboard Height:
 Plating Solution Temperature
 Plating Solution Nickel Cone.
 Plating Solution Boric Acid Cone.
 Plating Solution pH
 Plating Solution Surface Tension
 Plating Solution Specific Gravity
 Plating Voltage
 Average Amperage Applied
 Calculated Ampere-Hr Usage
 Calculated Current Density
 Number of Dummy Parts
 Total Surface Area of Plated Parts
 Plating Period Within Test Run
 Duration of Test Run
 Capture Efficiency of Ventilation System
 Ventilation Rate
 Air Agitation Rate
 Solution Circulation Rate (estimated)
s:\engineer\air\staclctestprocess data wkshtwpd

-------
     Appendix J



Stack Test Schematics

-------
ARTISTIC PLATING - MILWAUKEE
CONDITIONS 18, 19, 20, & 21 STACK

         SAMPLE POINT LOCATIONS
                                         FIGURE 1
                                 SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
12 in.
                                                           5ft.
                                                           3ft.
 Notes:  24 sampling points to be used on this
        round duct; 12 points along each of two
        perpendicular traverses.
                                                                   (bend in
                                                                   duct to
                                                                  scrubber)
                                         (transition
                                          from the
                                         vent hood)

-------
 ARTISTIC PLATING - MILWAUKEE
 CONDITIONS 7, 24, 27, & 28 STACK

         SAMPLE POINT LOCATIONS
                                          FIGURE 2
                                 SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.7
1.2
1.8
2.5
3.6
6.4
7.5
8.2
8.8
9.3
9.5
Stack Diameter:
                                                             5ft.
                                                             T
                                                             2ft.
10 in.
 Notes:  24 sampling points to be used on this
        round duct;  12 points along each of two
        perpendicular traverses.
                                                                    (bend in
                                                                     duct to
                                                                    scrubber)
                                          (transition
                                           from the
                                           plenum)

-------
 ABQC - MILWAUKEE
 CONDITIONS 10, 11, 12, 13, & 14 STACK

         SAMPLE POINT LOCATIONS
                                           FIGURE 3
                                  SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
                                                              1 ft.
                                                              3ft.
12 in.
 Notes:  24 sampling points to be used on this
        round duct;  12 points along each of two
        perpendicular traverses.
                                                                     (branch
                                                                     entry from
                                                                     other area
                                           (transition
                                            from the
                                            plenum)

-------
 ELITE FINISHING - MILWAUKEE
 CONDITIONS 22, 23, & 25 STACK

         SAMPLE POINT LOCATIONS
                                           FIGURE 4
                                  SAMPLE PORT LOCATION
Point
1
2
3
4
5
6
7
8
9
10
11
12
Distance (ft.)
0.5
0.8
1.4
2.1
3.0
4.3
7.7
9.0
9.9
10.6
11.2
11.5
Stack Diameter:
                                                              4ft.
12 in.
 Notes:  24 sampling points to be used on this
        round duct; 12 points along each of two
        perpendicular traverses.
                                                                     (bend into
                                                                      common
                                                                       stack)
                                           (transition
                                            from the
                                            plenum)

-------
 RELIABLE PLATING - CHICAGO
 CONDITIONS 22, 23, & 25 STACK

         SAMPLE POINT LOCATIONS
                                              FIGURES
                                     SAMPLE PORT LOCATION
           Point
Stack Diameter:
Distance (ft.
1
2
3
4
5
6
7
8
9
10
11
12
0.5
0.9
1.6
2.4
3.4
4.8
8.7
10.1
11.1
11.9
12.6
13.0
  13.5 in.
                                                              7 in.
                                                             28 in.
 Notes:  24 sampling points to be used on this
        round duct;  12 points along each of two
        perpendicular traverses.
(bend into
 common
  stack)
                                              (transition
                                              from the
                                              plenum)

-------
-------
Enviromr   1
  Technology 4
PART1CULATE F   ^D DATA
'- t.ool
Engineering Corp.
/
\
i







(J
CROSS SECTION
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TEMPERATURE
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