&EPA
United States Office of Pollution March 1999
Environmental Prevention and Toxics EPA 745-R-99-005
Protection Agency Washington, DC 20460
EPCRA Section 313
Look-up Tables for Estimating Toxic
Release Inventory Air Emissions from
Chemical Distribution Facilities
Section 313 of the
Emergency Planning
and Community
Right-to-Know Act
Toxic Chemical Release
Inventory
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Preface
The Environmental Protection Agency (EPA) is making this document available to help facilities
in Standard Industrial Classification 5169 (chemical and allied products — wholesale) in
calculating air emissions that are required to be reported under Section 313 of the Emergency
Planning and Community Right-to-Know Act (EPCRA, or Title III of the Superfund
Amendments and Reauthorization Act of 1986, Public Law 99-499). The EPCRA Section 313
program is also referred to as the Toxics Release Inventory or TRI.
This document is intended solely for guidance and does not alter any statutory or regulatory
requirements. The document should be used in conjunction with the statute and regulations but
does not supersede them.
This document is intended to supplement Toxic Chemical Release Inventory Forms and
Instructions (Revised 1998 Version) and should be used in conjunction with the EPCRA Section
313 Industry Guidance Chemical Distribution Facilities (EPA 745-B-99-005) .
The look-up tables in this document were developed for the National Association of Chemical
Distributors1 by the IT Corporation2 (Project number 776338-04). The methodology used to
derive these look-up tables was reviewed by EPA=s Toxics Release Inventory Branch. EPA
believes that in the limited situations described in this document that the look-up tables provide
reasonable estimates of certain air releases. These look-up tables are intended to provide
simplified estimations of air releases from liquid bulk storage, blending, and container filling
operations based primarily on annual chemical throughput quantity. These tables provide
individual chemical distributors nationwide with a simplified method for deriving these values.
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Table of Contents
Page
1.0 Introduction/B ackground 1-1
2.0 Applicability - When to Use the Look-up Tables and When Not to Use the
Look-up Tables 2-1
3.0 How to Use the Look-up Tables 3-1
Appendices
A - Look-up Table for 54 EPCRA section 313 Chemicals A-l
B - City Correction Factors B-l
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1.0 Introduction and Background
By July 1, 1999, hundreds of chemical distributors throughout the country will be required, for
the first time, to submit estimates of toxic chemical releases and other waste management
quantities to the U.S. Environmental Protection Agency (EPA) under Section 313 of the
Emergency Planning and Community Right-to-Know Act (EPCRA) and Section 6607 of the
Pollution Prevention Act (PPA). Also known as the Toxic Release Inventory (TRI), EPCRA
Section 313 and PPA Section 6607 require individual facilities that exceed certain thresholds to
prepare estimates of annual quantities of specifically listed chemicals released to air, water, or
land on-site, otherwise managed as waste on-site or transferred off site to other facilities for
further waste management. While amounts of listed toxic chemicals may be released or
otherwise managed as waste in many different forms, such as spills to land, transfers to a POTW,
etc., it is expected that the majority of wastes at chemical distribution facilities will be in the form
of fugitive or stack release to air.
To assist their members with TRI reporting, the National Association of Chemical Distributors
(NACD) contracted with IT Corporation (IT) to develop look-up tables for simplifying estima-
tion of air releases from liquid bulk storage, blending, and container filling operations based
primarily on annual chemical throughput quantity. The methodology used to derive these look-
up tables was reviewed by EPA=s Toxics Release Inventory Branch and modifications were made
at the Agency=s request. EPA believes that in the limited situations described in this document
the look-up tables provide reasonable estimates of certain air releases.
These tables provide individual chemical distributors nationwide with a simplified method for
deriving these values rather than applying algorithms conventionally used for estimating air
emissions from similar types of operations. It is anticipated that the use of these tables will also
reduce the likelihood of reporting errors associated with misapplication of the conventional
estimation approaches which can sometimes be fairly complicated.
Figure 1 is a diagram of liquid bulk storage, blending, and container filling operations that
identifies air emission sources from these common operations. The conventional approach for
estimating annual air emissions from these sources is to utilize AP-42 algorithms for storage tank
emissions (A3 in Figure 1), Synthetic Organic Chemical Manufacturing Industry (SOCMI)
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emission factors for leaks from piping components (A2, A4, and A6 in Figure 1), and a standard
engineering calculation for estimating releases during liquids blending and container filling (A5
and Al in Figure 1).
The premise of the look-up table approach is that liquid bulk storage and container filling
operations are very similar among chemical distribution facilities, especially in terms of air
emission sources and approaches available for estimating air emissions. IT Corporation used
conventional AP-42 and SOCMI algorithms to estimate air emissions from typical variations of
the liquid bulk storage and container filling operations at chemical distribution facilities. The
results were consolidated into a tabular format as a function of chemical throughput.
Appendix A of this document contains the Look-up Tables for 54 EPCRA section 313 chemicals.
Prototypes of these tables were developed, field tested, and modified by IT in the latter part of
1998, with on-going input from EPA and NACD. Appendix B contains Look-up Table
correction factors for numerous cities (i.e., City Correction Factors) that must be used in
conjunction with the Look-up Tables to compensate for climate variations across the country.
Section 2 of this document summarizes the applicability of the Look-up Tables - indicating when
they should be used and when they should not be used. The reader is urged to carefully review
this section to understand the limitations of the tables and to ensure that they apply to his or her
specific situation. Section 3 presents detailed instructions on how to use the Look-up Tables and
where the results from the tables provide values to assist you in determining which form to use
(Form R or Form A) and if Form R is required, where to enter the certain values.
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FIGURE 1: LIQUID BULK STORAGE AND CONTAINER FILLING PROCESS
A,
A-- A,;.
Warehouse or
Customer
Rail Car
A, = air em isstons from container filing
Aj. = air emissions from pumps, valves, and other piping components
used to deliver liquid to container filling operations from rail
carsrtank trucks, storage tanks, or blending tanks
A, = air emissions from storage tanks (>orking & breathing losses)
At = air emissions from pumps, valwes, and other piping components
used to deliver liquid from «ilcarstenk trucks to storage tanks
As = air emissions from blendingtanks
A; = air emissions from pumps, valves, and other piping components
used to deliver liquid from storage tanks to blending tanks
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2.0 Applicability - When to Use the Look-up Tables and When Not to Use
the Look-up Tables
The Look-up Tables were designed to facilitate estimation of chemical releases to air from a
common operation among chemical distributors - liquid bulk storage and container filling. As
outlined in Figure 1, there are three variations of this process.
1. Unloading of the chemical by pumping from a railcar or tanker truck directly into
shipping containers such as tank trucks, 55-gallon drums, 5-gallon pails, or 1-
gallon cans.
2. Unloading of the chemical by pumping from a railcar or tanker truck to a
dedicated fixed-roof, outdoor storage tank and then pumping the chemical from
the storage tank into shipping containers such as tank trucks, 55-gallon drums, 5-
gallon pails, or 1-gallon cans.
3. Unloading of the chemical by pumping from a railcar or tanker truck to a
dedicated fixed-roof, outdoor storage tank and then pumping the chemical to a
closed, indoor blending tank on a batch basis, then pumping the chemical from the
indoor blending tank into shipping containers such as tank trucks, 55-gallon
drums, 5-gallon pails, or 1-gallon cans.
When processing liquid bulk chemicals at your facility, you may utilize any and all of these
process variations depending on the chemical in question. The Look-up Tables can be used to
address air emissions from any combination of these three process variations. However, the
following caveats must be recognized to prevent an inappropriate use of the Look-up Tables.
• The Look-up Tables apply only to air releases. Releases of EPCRA section 313
chemicals to land and water, as well as other on-site waste management activities and off-
site transfers for further waste management, are not covered under this table, but must be
included as part of any Form R submittal.
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The Look-up Tables apply only to the liquid bulk storage and container filling process as
described above. You may generate air releases of EPCRA section 313 chemicals from
other sources at your facility (e.g., spills and other chemical processing). These estimates
must be included with air release estimates developed using the Look-up Tables.
The Look-up Tables do not apply to the repackaging of gases or pressurized liquids.
If Appendix A does not contain a Look-up Table for a chemical for which you must
prepare a report, you must rely on more conventional air release estimation techniques
such as AP-42 algorithms and SOCMI emission factors.
The Look-up Tables assume that you are not using air emission control devices (e.g.,
scrubbers, thermal oxidizers, etc) that would reduce air releases from the individual
sources noted in Figure 1. However, the Look-up Tables can be used in these situations
to estimate the amount of a chemical entering the control device. The chemical releases
from the control device can then be estimated by applying the estimated control efficiency
of the control device to the estimated amount entering the device.
There are Look-up Tables for a number of chemicals that are part of the TRI Certain
glycol ether chemical compound category3 (e.g., Glycol Ether DB, Glycol Ether DE,
Glycol Ether DM and Glycol Ether EB). Release estimates of these chemicals must be
made individually; however, they must be aggregated for all glycol ethers processed at
your facility and submitted on one Form R for Glycol Ethers. As such, the individual
Look-up Tables for these glycol ether compounds are marked to indicate the need to
aggregate the release estimates.
3This category is limited to glycol ethers derived from ethylene glycol, diethylene glycol, and
triethylene glycol. It does NOT include glycol ethers derived from propylene glycol, dipropylene
glycol, or tripropylene glycol. For further information, see AToxics Release Inventory: List of
Toxic Chemicals Within the Glycol Ethers Category® (EPA-745-R-95-006).
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3.0 How to Use the Look-up Tables
Please read the instructions presented in this section thoroughly prior to attempting to use the
Look-up Tables presented in Appendix A. The first half of this section presents the basics for
using the tables. However, other critical issues are covered latter in this section and must be
understood in order to properly utilize the look-up tables. These issues include chemical
mixtures, geographical correction factors, and distinguishing stack source releases from fugitive
source releases. Examples are provided throughout to demonstrate proper use of the tables.
Figure 1 identifies six sources of air releases from a typical liquid bulk storage and container
filling operation at a typical chemical distribution facility.
Al = Air releases from container filling.
A2 = Air releases from pumps, valves, and other piping components used to deliver
liquid to container filling operations from rail cars/tank trucks, storage tanks, or
blending tanks.
A3 = Air releases from storage tanks (working and breathing losses).
A4 = Air releases from pumps, valves, and other piping components used to deliver
liquid to storage tanks from rail cars/tank trucks.
A5 = Air releases from blending tanks.
A6 = Air releases from pumps, valves, and other piping components used to deliver
liquid to blending operations from storage tanks.
The Look-up Tables in Appendix A can be used to calculate air releases from each of these
sources based simply on the amount of the chemical passing through the liquid bulk storage and
container filling process (i.e., the chemical throughput) and selecting the size of storage tank
involved.
Example 1: If you processed 1 million pounds of toluene through your liquid bulk storage and
container filling operation during the reporting year utilizing a 10,000 gallon storage tank, air
emissions from sources A1 through A6 could be read directly from the Toluene Look-up Table
(reprinted on the following page) under the 1 million pound throughput column.
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A 1=93 Ib
A2=ll Ib
A3=161 Ib
A4=3 Ib
A5=93 Ib
A6=ll Ib
Please note that in Example 1, the value for A3 is taken from the row for the 10,000 gallon
storage tank because this was the capacity of the tank used in the example. In general for A3,
use the row corresponding to the storage tank size that is closest to the tank you use for the
chemical in question (i.e., 5000, 10,000, or 25,000 gallons).
General Note #1. EPCRA section 313 requires that facilities report fugitive and stack releases
separately. Sources A2, A4, A6, and sometimes Al pertain to fugitive releases. Sources A3, A5,
and sometimes Al pertain to stack emissions. The last portion of Section 3 provides detailed
instructions for separately calculating stack and fugitive releases using the Look-up Tables.
General Note # 2. EPCRA section 313 reporting is in pounds of the particular listed chemical .
You may be tracking throughput information in gallons for liquid mixtures. If so, you will need
to determine the weight of the EPCRA section 313 chemical in the mixture and then use the
poundage of the particular chemical when using the tables.
General Note #3. If all or a portion of the equipment at your facility is exposed to the
environment or is not in an atmospherically controlled environment, then you will need to apply a
geographic correction factor provided in Appendix B for your release estimates. This subject is
discussed in detail later in Section 3.
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Toluene Look-up Table
Air Emissions (in pounds) from bulk unloading, storage, blending and
container filling operations at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks -
delivery of liquid to container
filling
A3 - Storage tank working +
breathing losses (pick closest
tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks -
delivery of liquid to storage tank
A5 - Blending/mixing tank
emissions
A6 - Piping component leaks -
delivery of liquid to
blending/mixing tank
Throughput (1,000 Ib/yr)
50
5
1
43
72
168
1
5
1
100
9
1
47
77
173
1
9
2
250
23
O
61
91
187
1
23
3
500
47
6
85
114
210
1
47
6
750
70
8
108
137
234
2
70
9
1,000
93
11
131
161
257
3
93
11
2,000
187
22
171
254
350
6
187
22
3,000
280
33
187
320
443
9
253
33
5,000
466
56
218
351
630
14
284
56
10,000
933
112
296
429
826
28
362
111
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Example 2: Assume you processed 1.4 million pounds of toluene utilizing a 20,000 gallon
storage tank. To derive a proper release estimate for Al - A6, you would have to interpolate the
values under the 1 million and 2 million pound columns. Please note that for A3 in this
example you would use the 25,000 gallon row.
Al= 93 +[(1,400,000-1,000,000)/(2,000,000 - 1,000,000)]x [187-93]
= 93 + 0.4 x[187-93]
= 131
A2=ll + 0.4 x [22-11]
= 15
A3=257 + 0.4 x [350-257]
= 294
A4=3 + 0.4 x [6-3]
= 4
A5=93 + 0.4 x[ 187-93]
= 131
A6=ll + 0.4 x [22-11]
= 15
Examples 1 and 2 assumed that the entire amount of toluene processed during the year went
through liquid storage, liquid blending and container filling steps. It is more likely however, that
the liquid bulk storage and container filling operation at your facility bypasses one or two of these
steps for all or a portion of the annual chemical throughput.
Example 3: For the facility in Example 2 that processed 1.4 million pounds of toluene during
the reporting year, a more likely scenario would be that while all of the 1.4 million pounds
passed through the storage tank and container filling steps in Figure 1, only 10% or 140,000
pounds passed through the liquid blending. To address this scenario, you would simply use the
1.4 million throughput value to look-up emission values for Al, A2, A3, andA4, while using the
140,000 pound throughput value to look-up emission values for A5 andA6.
Al= 131 (from Example 2)
A2=15 (from Example 2)
A3 =294 (from Example 2)
A4=4 (from Example 2)
A5=9 +[(140,000-100,000)/(250,000 - 100,000)]x [23-9]
= 9 + 0.27 x [23-9]
= 13
A6=2 + 0.27x [3-2]
= 2
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As discussed in Section 2, the Look-up Tables recognize three process variations associated with
liquid bulk storage and container filling:
1. Unloading of the chemical by pumping from a railcar or tanker truck directly into
shipping containers such as tank trucks, 55-gallon drums, 5-gallon pails, or 1-
gallon cans. In this scenario only Al and A2 are applicable and A3, A4, A5, and
A6 do not apply.
2. Unloading of the chemical by pumping from a railcar or tanker truck to a
dedicated fixed-roof, outdoor storage tank and then pumping the chemical from
the storage tank into shipping containers such as tank trucks, 55-gallon drums, 5-
gallon pails, or 1-gallon cans. In this scenario only Al, A2, A3, and A4 are
applicable and A5, and A6 do not apply.
3. Unloading of the chemical by pumping from a railcar or tanker truck to a
dedicated fixed-roof, outdoor storage tank and then pumping the chemical to a
closed, indoor blending tank on a batch basis, then pumping the chemical from the
indoor blending tank into shipping containers such as tank trucks, 55-gallon
drums, 5-gallon pails, or 1-gallon cans. In this scenario Al, A2, A3, A4, A5 and
A6 are applicable.
When processing liquid bulk chemicals at your facility, you may utilize any and all of these
process variations depending on the chemical in question. To utilize the look-up tables, simply
think of the liquid bulk storage and container filling operation as consisting of three steps storage
(A3 and A4), blending (A5 and A6) and container filling (Al and A2). Determine the amount of
the chemical in question that passes through each step, and then utilize the corresponding
throughput values in the Look-up Table to determine the chemical=s air emissions from the
individual sources (A1-A6). The following examples demonstrate how to utilize the tables when
a combination of steps are used at a facility for a given chemical.
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Example 4: A facility processes 500,000 pounds of toluene during the reporting year. Their
process consists of unloading tank trucks directly into totes and drums and then shipping the
totes to their customers. No storage tanks are utilized for processing the toluene and no
blending is performed.
Al=47lb
A2=6lb
A3=N/A
A4=N/A
A5=N/A
A6=N/A
Example 5: A facility processes 5 million pounds of toluene during the reporting year. Twenty
percent (20%) of the toluene is repackaged into totes, drums and bottles directly from a tank car
(Process Variation Number 1 described above). Sixty percent (60%) is repackaged into totes
and drums from a 10,000 gallon storage tank (Process Variation Number 2 described above).
The remaining twenty percent (20%) is repackaged into drums after storage and blending
(Process Variation Number 3 described above).
Looking at the process in terms of storage, blending and container filling, it is apparent that:
• 100% of the throughput (5 million pounds) in this example passes through the container
filling step. Therefore, from the toluene Look-up Table, Al = 466 Ib. AndA2 = 56 Ib.
• 80% of the throughput (4 million pounds) passes through the storage tank. Therefore,
A3 = 320+[(4 million - 3 million)/(5 million- 3 million)] x [351-320]
= 320 + 0.5 x (351-320)
= 336 Ib.
A4 = 9 + 0.5 x (14-9)
= 12 Ib.
• 20% of the throughput (1 million pounds) passes through the blending step. Therefore,
from the toluene Look-up Table, Al = 93 Ib. AndA2 = 11 Ib.
Mixtures of Chemicals
Each of the Look-up Tables in Appendix A was created assuming the processing of pure
chemicals through the liquid bulk storage and container filling process. This is a reasonable
assumption given that chemical distributors primarily deal with these chemicals in pure form.
There are situations however, where mixtures of chemicals are stored in storage tanks, blended in
mixing tanks and repackaged into different containers. The Look-up Tables can be utilized in
these situations by imagining the mixtures are Aun-mixed® and using the throughput of the
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chemical of concern only to determine air emissions. In other word, we assume that the mixture
is an ideal mixture and the component chemicals of the mixture behave as they do in their pure
state. The assumption of an ideal mixture works very well for most organic chemicals, but is not
as reliable for more polar chemical compounds.
Geographic Correction Factors
Air emissions of the same chemical in identical processes at different geographical locations
across the country will vary significantly due to ambient temperature variations. The Look-up
Tables in Appendix A were developed for Louisville, Kentucky. To utilize these tables in
different locations, a set of correction factors was developed for 73 cities across the U.S., with at
least one from each state. These factors are presented in Appendix B.
The correction factor for Louisville, Kentucky is equal to 1.00. For cities with warmer climates,
the factor is >1.00. For cities with colder climates, the factor is <1.00.
The Geographic Correction factors are to be applied only to Al (air emissions from container
filling), A3 (air emissions from storage tanks), and A5 (air emissions from blending tanks). Air
emissions from pumps, valves, and other piping components are not a function of ambient
temperature and thus the Geographic Correction Factors must not be applied to these emission
sources.
To use the Geographic Correction Factors, simply review the list of cities in Appendix B, choose
the correction factor for the city nearest your facility, and then multiply the results obtained from
the Look-up Tables in Appendix A for A1, A3, and A5 by the selected correction factor.
Example 6: Suppose the facility addressed in Example 1 was located in Joliet, Illinois. A
review of Appendix B would indicated the Chicago, Illinois is the nearest city for which a
Geographic Correction Factor is available and that factor is equal to 0.81. Therefore, air
emissions of toluene from this facility would be:
Al=93lbx0.81 = 75 Ib
A2=ll Ib
A3=161lbx0.81 = 130 Ib
A4=3 Ib
A5=93lbx0.81 = 75 Ib
A6=ll Ib
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Reporting Point and Non-Point Source Air Emissions Form R
EPA Form R requires separate reporting of aggregate point source air emissions (i.e., stack
emissions) and aggregate non-point source emissions (i.e., fugitive emissions). Point source
releases are those which occur through stacks, vents, ducts, pipes, or other confined air streams.
Non-point source releases are those which do not occur through stacks, vents, ducts, pipes, or
other confined air streams. The quantity of the fugitive air emissions should be reported in
section 5.1 Column A (Total Release). The quantity of the stack air emissions should be reported
in section 5.2 Column A (Total Release). You should enter AO@4 in both section 5.1 Column B
(Basis of Estimate) and section 5.2 Column B (Basis of Estimate).
For the liquid bulk storage and container filling process, the following generalizations can be
made regarding point and non-point emissions.
• Al= Air emissions from container filling. These are point source emissions when a
local exhaust ventilation system is used to capture emissions from the filling operation.
Otherwise, they are typically a non-point source, especially when filling is conducted
outside.
• A2= Air emissions from pumps, valves, and other piping components used to deliver
liquid to container filling operations from rail cars/tank trucks, storage tanks, or
blending tanks. These are always non-point sources.
• A3= Air emissions from storage tanks (working and breathing losses). These are
almost always point-sources.
4 AO@ means that, among other factors, Athe estimate is based on ... approaches such as
engineering calculations (e.g., estimating volalization using published mathematical formulas) or
best engineering judgement.® See AToxic Chemical Release Inventory Reporting Forms and
Instructions® page 34.
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• A4= Air emissions from pumps, valves, and other piping components used to deliver
liquid to storage tanks from rail cars/tank trucks. These are always non-point sources.
• A5= Air emissions from blending tanks. These will be point sources if the blending
tank is covered or is local exhaust ventilation is used to capture emissions. If the blend
tank is an open-top variety, then A5 will be considered a non-point source.
• A6= Air emissions from pumps, valves, and other piping components used to deliver
liquid to blending operations from storage tanks. These are always non-point sources.
After determining A1-A6 using the Look-up Tables and applying the appropriate Geographic
Correction Factor, categorize each source as point or non-point and sum for these categories.
These estimates need not be rounded to more than two significant figures and should be record in
Section 5.1 and 5.2 of Form R. Warning! If you are aware of other sources of air emissions of a
subject chemical from your facility in addition to those described herein, you must include these
estimates with point and non-point estimates for Al - A6. For example, if you had a spill of
toluene during the year that resulted in fugitive air emissions, you must include the amount
released to air from this incident with the non-point source total from Al - A6.
Example 7: The facility addressed in Example 6 utilizes a covered blend tank for toluene and
performs container filling outdoors.
A 1 = 75 Ib (non-point source)
A2=lllb (non-point source)
A3=130 Ib (point source)
A4=3 Ib (non-point source)
A5=75 Ib (point source)
A6=ll Ib (non-point source)
Total point source emissions= 130 + 75 = 205, Rounding to 2 significant figures yields 200 Ib
Total non-point source emissions= 75+11+3+11=100, Rounding to 2 significant figures yields
100 Ib.
Form R provides the option of reporting Range Codes in section 5.1 and 5.2. in lieu of numerical
values when estimates are below 1000 pounds for the year for either point (stack) or non-point
(fugitive) emissions of a given chemical. The range codes are as follows:
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• Range Code A: for releases between 1 and 10 pounds per year.
• Range Code B: for releases between 11 and 499 pounds per year.
• Range Code C: for releases between 500 and 999 pounds per year.
Example 8: For the facility addressed in Example 7, point source emissions equaled 200
pounds and thus could be reported as KB@ in Section 5.2 of the toluene Form R. Similarly, non-
point source emissions equaled 100 pounds and thus could be reported as KB@ in Section 5.1 of
the toluene Form R.
In addition to reporting air emissions in Section 5.1 and 5.2 of Form R, air emissions for the
facility must also be included as part of Section 8.1, Total Environmental Releases. The value
reported in Section 8.1 must also include any other releases of the chemical to the environment
such as releases to water or land or transfers off-site for disposal. Please refer to the AToxic
Chemical Release Inventory Reporting Forms and Instructions: Revised 1998 Version® for
details. Please note that you cannot use range codes for completing Section 8.1 although you
may for Sections 5.1 and 5.2.
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Appendix A Look-up Tables
A-l
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1,1,1-Trichloroethane Look-up Table
(CAS No. 71-55-6; Methyl chloroform)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
21
1
329
548
1,179
1
22
1
100
42
1
351
571
1,201
1
44
2
250
104
3
418
637
1,267
1
111
3
500
209
6
529
748
1,378
1
221
6
750
313
8
639
859
1,489
2
332
9
1,000
418
11
750
969
1,600
3
443
11
2,000
835
22
1,193
1,412
2,043
6
886
22
3,000
1,253
33
1,277
1,855
2,486
9
1,329
33
5,000
2,088
56
1,424
2,403
3,371
14
1,877
56
10,000
4,176
112
1,793
2,772
5,586
28
2,246
111
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1,2,4-Trimethylbenzene Look-up Table
(CAS No. 95-63-6)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
3
6
13
1
1
1
100
1
1
4
6
14
1
1
2
250
1
o
6
5
1
15
1
2
o
J
500
3
6
7
9
17
1
4
6
750
4
8
8
11
19
2
5
9
1,000
6
11
10
12
20
o
J
1
11
2,000
11
22
13
20
28
6
15
22
3,000
17
33
15
25
35
9
20
33
5,000
29
56
17
28
50
14
22
56
10,000
57
112
23
34
65
28
29
111
A-3
-------
1,2-Dichlorobenzene Look-up Table
(CAS No. 95-50-1)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
3
5
12
1
1
1
100
1
1
3
5
12
1
1
2
250
1
o
J
4
6
13
1
1
o
J
500
2
6
5
7
14
1
2
6
750
4
8
6
8
15
2
3
9
1,000
5
11
7
9
16
o
J
4
11
2,000
9
22
11
14
21
6
9
22
3,000
14
33
12
18
25
9
13
33
5,000
24
56
14
23
34
14
18
56
10,000
47
112
17
27
55
28
22
111
A-4
-------
1,2-Dichloroethane Look-up Table
(CAS No. 107-06-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
11
1
135
227
507
1
10
1
100
21
1
145
237
517
1
20
2
250
54
o
6
175
267
547
1
51
o
J
500
107
6
226
318
598
1
101
6
750
161
8
276
368
649
2
152
9
1,000
214
11
327
419
699
o
5
203
11
2,000
429
22
509
622
902
6
405
22
3,000
643
33
542
824
1,104
9
608
33
5,000
1,072
56
610
1,023
1,509
14
807
56
10,000
2,143
112
779
1,192
2,404
28
976
111
A-5
-------
2-Ethoxyethanor Look-up Table
(CAS No. 110-80-5; Glycol Ether EE)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
7
12
30
1
1
1
100
2
1
8
13
31
1
2
2
250
4
o
6
10
15
33
1
4
o
J
500
8
6
14
19
37
1
8
6
750
12
8
18
23
41
2
12
9
1,000
16
11
22
27
44
o
5
15
11
2,000
33
22
30
42
60
6
31
22
3,000
49
33
32
55
75
9
44
33
5,000
81
56
37
61
106
14
49
56
10,000
163
112
50
73
144
28
62
111
a Report under Glycol Ether chemical category
A-6
-------
Aqua ammonia (28%) Look-up Table
(CAS No. 7664-41-7)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
17
1
402
645
1,235
1
22
1
100
35
1
423
666
1,257
1
44
2
250
87
o
6
489
732
1,322
1
109
o
J
500
174
6
598
841
1,431
1
218
6
750
260
8
707
950
1,540
2
327
9
1,000
347
11
816
1,059
1,649
o
5
436
11
2,000
694
22
1,019
1,494
2,085
6
871
22
3,000
1,041
33
1,092
1,837
2,521
9
1,214
33
5,000
1,735
56
1,237
1,982
3,392
14
1,359
56
10,000
3,471
112
1,600
2,345
4,391
28
1,722
111
A-7
-------
Benzene Look-up Table
(Cas No. 71-43-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
14
1
137
227
494
1
14
1
100
28
1
151
241
508
1
28
2
250
70
o
6
193
282
550
1
70
o
J
500
140
6
262
352
620
1
139
6
750
209
8
332
422
690
2
209
9
1,000
279
11
402
491
759
o
5
279
11
2,000
558
22
525
770
1,038
6
557
22
3,000
838
33
571
975
1,316
9
762
33
5,000
1,396
56
664
1,068
1,874
14
855
56
10,000
2,792
112
896
1,300
2,478
28
1,087
111
A-8
-------
Butyl acrylate Look-up Table
(CAS No. 141-32-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
10
17
41
1
1
1
100
2
1
11
18
43
1
2
2
250
4
o
6
14
22
46
1
6
o
J
500
9
6
20
27
51
1
11
6
750
13
8
25
33
57
2
17
9
1,000
18
11
31
38
62
o
5
22
11
2,000
36
22
41
60
84
6
44
22
3,000
54
33
45
78
106
9
62
33
5,000
89
56
52
85
150
14
69
56
10,000
179
112
71
103
201
28
87
111
A-9
-------
Carbitola Look-up Table
(CAS No. 111-90-0; Glycol Ether DE; Polysolv DE)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
2
33
1
1
2
9
1
33
5,000
3
56
1
2
3
14
1
56
10,000
5
112
1
2
4
28
2
111
a Report under Glycol Ether chemical category
A-10
-------
Carbon Disulfide Look-up Table
(Cas No. 75-15-0)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
38
1
642
1,041
2,060
1
39
1
100
75
1
681
1,080
2,099
1
79
2
250
188
o
6
800
1,199
2,218
1
197
o
J
500
376
6
997
1,396
2,415
1
395
6
750
564
8
1,194
1,593
2,612
2
592
9
1,000
752
11
1,392
1,791
2,810
o
5
789
11
2,000
1,505
22
2,119
2,580
3,599
6
1,579
22
3,000
2,257
33
2,251
3,370
4,389
9
2,368
33
5,000
3,762
56
2,514
4,186
5,968
14
3,185
56
10,000
7,525
112
3,172
4,844
9,554
28
3,843
111
A-ll
-------
Cumene Look-up Table
(CAS No. 98-82-8; Isopropyl benzene)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
2
1
8
14
34
1
1
1
100
5
1
9
15
35
1
2
2
250
12
o
6
12
18
38
1
5
o
J
500
23
6
17
22
42
1
9
6
750
35
8
21
27
47
2
14
9
1,000
47
11
26
32
52
o
5
19
11
2,000
94
22
34
51
70
6
38
22
3,000
141
33
37
64
89
9
50
33
5,000
235
56
43
70
127
14
57
56
10,000
469
112
59
85
165
28
72
111
A-12
-------
Cyclohexanol Look-up Table
(CAS No. 108-93-0)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
2
6
1
1
1
1
1
6
750
3
8
1
1
1
2
1
9
1,000
4
11
1
1
1
o
5
i
11
2,000
9
22
1
1
2
6
1
22
3,000
13
33
1
2
2
9
1
33
5,000
22
56
1
2
3
14
1
56
10,000
44
112
1
2
4
28
2
111
A-13
-------
Cyclohexane Look-up Table
(CAS No. 110-82-7)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
18
1
155
254
551
1
18
1
100
35
1
172
272
568
1
35
2
250
88
o
6
225
325
621
1
88
o
J
500
177
6
313
413
709
1
176
6
750
265
8
401
501
797
2
264
9
1,000
353
11
489
589
885
o
5
352
11
2,000
706
22
600
940
1,237
6
704
22
3,000
1,060
33
659
1,110
1,589
9
873
33
5,000
1,766
56
776
1,227
2,292
14
990
56
10,000
3,532
112
1,069
1,520
2,835
28
1,284
111
A-14
-------
Bis(2-ethylhexyl) phthalate Look-up Table
(CAS No. 117-81-7; DEHP)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
1
1
1
1
0
1
100
0
1
1
1
1
1
0
2
250
0
o
6
i
i
i
i
i
o
J
500
0
6
1
1
1
1
1
6
750
0
8
1
1
1
2
1
9
1,000
0
11
1
1
1
o
5
i
11
2,000
0
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
1
28
1
111
A-15
-------
Dichlorobenzene (mixed isomers) Look-up Table
(CAS No. 25321-22-6)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
4
7
16
1
1
1
100
1
1
4
7
16
1
1
2
250
2
o
6
5
8
17
1
2
o
J
500
3
6
7
9
19
1
3
6
750
5
8
8
11
21
2
5
9
1,000
6
11
10
13
22
o
3
6
11
2,000
13
22
15
19
28
6
13
22
3,000
19
33
16
25
35
9
19
33
5,000
32
56
19
31
47
14
25
56
10,000
64
112
24
37
75
28
30
111
A-16
-------
Dichloromethane Look-up Table
(CAS No. 75-09-2; Methylene chloride)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
47
1
925
1,499
2,944
1
49
1
100
94
1
973
1,548
2,993
1
98
2
250
234
o
6
1,120
1,694
3,139
1
244
o
J
500
469
6
1,364
1,938
3,383
1
488
6
750
703
8
1,608
2,182
3,627
2
732
9
1,000
937
11
1,852
2,426
3,871
o
5
976
11
2,000
1,874
22
2,828
3,402
4,847
6
1,952
22
3,000
2,812
33
3,000
4,378
5,824
9
2,928
33
5,000
4,686
56
3,325
5,562
7,776
14
4,111
56
10,000
9,372
112
4,139
6,375
12,636
28
4,925
111
A-17
-------
Dimethyl phthalate Look-up Table
(CAS No. 131-11-3)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
0
0
0
1
0
1
100
1
1
0
0
0
1
0
2
250
1
o
6
0
0
0
1
0
o
J
500
1
6
0
0
0
1
0
6
750
1
8
0
0
0
2
0
9
1,000
1
11
0
0
0
o
5
0
11
2,000
1
22
0
0
0
6
0
22
3,000
1
33
0
0
0
9
0
33
5,000
1
56
0
0
0
14
0
56
10,000
1
112
0
0
0
28
0
111
A-18
-------
Dimethylformamide Look-up Table
(CAS No. 68-12-2; NJV-Dimethylformamide)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
4
7
16
1
1
1
100
1
1
4
7
17
1
1
2
250
2
o
6
6
8
18
1
2
o
J
500
5
6
8
10
20
1
4
6
750
7
8
10
12
22
2
6
9
1,000
10
11
12
14
24
o
5
8
11
2,000
19
22
16
22
32
6
16
22
3,000
29
33
17
30
40
9
24
33
5,000
48
56
20
33
56
14
26
56
10,000
97
112
27
39
76
28
33
111
A-19
-------
Ethylene glycol Look-up Table
(CAS No. 107-21-1)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
2
28
1
111
A-20
-------
Ethylbenzene Look-up Table
(CAS No. 100-41-4)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
2
1
16
27
64
1
2
1
100
4
1
17
28
66
1
4
2
250
9
o
6
23
34
71
1
9
o
J
500
18
6
31
42
80
1
18
6
750
27
8
40
51
88
2
26
9
1,000
36
11
49
60
97
o
5
35
11
2,000
72
22
64
95
132
6
70
22
3,000
108
33
70
120
167
9
95
33
5,000
179
56
82
132
237
14
107
56
10,000
358
112
111
161
311
28
136
111
A-21
-------
Ethyl acrylate Look-up Table
(CAS No. 140-88-5)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
7
1
68
114
263
1
7
1
100
13
1
75
121
270
1
14
2
250
33
o
6
96
142
291
1
35
o
J
500
66
6
131
177
326
1
70
6
750
99
8
166
212
361
2
105
9
1,000
132
11
201
247
395
o
J
140
11
2,000
265
22
269
386
535
6
279
22
3,000
397
33
293
503
675
9
396
33
5,000
662
56
339
550
954
14
443
56
10,000
1,324
112
456
666
1,292
28
559
111
A-22
-------
Formic acid Look-up Table
(CAS No. 64-18-6)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
3
1
33
56
130
1
3
1
100
6
1
36
59
133
1
5
2
250
14
o
6
44
67
140
1
13
o
J
500
28
6
57
80
154
1
26
6
750
42
8
70
93
167
2
40
9
1,000
55
11
83
106
180
o
5
53
11
2,000
111
22
129
159
233
6
105
22
3,000
166
33
138
212
285
9
158
33
5,000
277
56
155
261
391
14
207
56
10,000
554
112
199
305
617
28
251
111
A-23
-------
Butyl Carbitola Look-up Table
(CAS No. 112-34-5; Glycol Ether DB)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
0
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
1
28
1
111
a Report under Glycol Ether chemical category
A-24
-------
Glycol Ether DB Acetate" Look-up Table
(CAS No. 124-17-4)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
1
1
1
1
0
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
1
28
1
111
a Report under Glycol Ether chemical category
A-25
-------
Glycol Ether DE Acetate" Look-up Table
(CAS No. 112-15-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
2
56
1
1
1
14
1
56
10,000
4
112
1
1
1
28
1
111
a Report under Glycol Ether chemical category
A-26
-------
Methyl Carbitol" Look-up Table
(CAS No. 111-77-3; Glycol Ether DM)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
2
2
1
9
1,000
1
11
1
1
2
o
5
i
11
2,000
2
22
1
2
2
6
1
22
3,000
3
33
1
2
3
9
2
33
5,000
5
56
1
2
4
14
2
56
10,000
10
112
2
3
6
28
2
111
a Report under Glycol Ether chemical category
A-27
-------
Butyl Cellosolve" Look-up Table
(CAS No. 111-76-2; Glycol Ether EB)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
2
4
1
1
1
100
1
1
1
2
4
1
1
2
250
4
o
6
i
2
4
1
1
o
J
500
7
6
2
3
5
1
1
6
750
11
8
2
3
5
2
2
9
1,000
15
11
3
4
6
o
5
2
11
2,000
30
22
4
6
8
6
4
22
3,000
44
33
4
7
10
9
6
33
5,000
74
56
5
8
14
14
6
56
10,000
148
112
7
10
19
28
8
111
a Report under Glycol Ether chemical category
A-28
-------
Glycol Ether EB Acetate" Look-up Table
(CAS No. 112-07-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
3
1
1
1
100
1
1
1
1
3
1
1
2
250
1
o
6
i
2
4
1
1
o
J
500
1
6
2
2
4
1
1
6
750
1
8
2
3
5
2
1
9
1,000
2
11
2
o
3
5
o
5
2
11
2,000
4
22
3
5
7
6
3
22
3,000
5
33
4
6
8
9
5
33
5,000
9
56
4
7
12
14
6
56
10,000
17
112
6
8
16
28
7
111
a Report under Glycol Ether chemical category
A-29
-------
Glycol Ether EE Acetate" Look-up Table
(CAS No. 111-15-9)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
4
6
15
1
1
1
100
1
1
4
6
15
1
1
2
250
2
o
6
5
1
16
1
2
o
J
500
3
6
7
9
18
1
4
6
750
5
8
9
11
20
2
5
9
1,000
7
11
10
13
22
o
J
1
11
2,000
14
22
14
20
29
6
15
22
3,000
20
33
16
27
36
9
22
33
5,000
34
56
18
30
51
14
24
56
10,000
68
112
24
36
71
28
30
111
a Report under Glycol Ether chemical category
A-30
-------
2-Methoxyethanola Look-up Table
(CAS No. 109-86-4; Glycol Ether EM)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
9
15
37
1
1
1
100
2
1
10
16
38
1
2
2
250
5
o
6
13
19
41
1
5
o
J
500
10
6
17
24
46
1
9
6
750
15
8
22
28
50
2
14
9
1,000
20
11
27
33
55
o
5
19
11
2,000
41
22
37
52
74
6
37
22
3,000
61
33
40
69
92
9
55
33
5,000
102
56
46
76
129
14
61
56
10,000
205
112
62
91
180
28
77
111
a Report under Glycol Ether chemical category
A-31
-------
Polysolv TEa Look-up Table
(CAS No. 112-50-5; Glycol Ether TE)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
1
1
1
1
0
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
1
28
1
111
a Report under Glycol Ether chemical category
A-32
-------
A-33
-------
Sulfuric acid (98%) Look-up Table
(CAS No. 7664-93-9)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
0
0
0
1
0
1
100
0
1
0
0
0
1
0
2
250
0
o
6
0
0
0
1
0
o
J
500
0
6
0
0
0
1
0
6
750
0
8
0
0
0
2
0
9
1,000
0
11
0
0
0
o
5
0
11
2,000
0
22
0
0
0
6
0
22
3,000
0
33
0
0
0
9
0
33
5,000
0
56
0
0
0
14
0
56
10,000
0
112
0
0
0
28
0
111
A-34
-------
Hydrochloric acid (32%) Look-up Table
(CAS No. 7647-01-0)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
16
28
66
1
1
1
100
2
1
18
29
68
1
3
2
250
6
o
6
22
34
72
1
7
o
J
500
11
6
29
40
79
1
14
6
750
17
8
36
47
85
2
20
9
1,000
22
11
42
54
92
o
5
27
11
2,000
44
22
64
81
120
6
55
22
3,000
67
33
69
109
147
9
82
33
5,000
111
56
78
130
201
14
103
56
10,000
222
112
101
153
308
28
126
111
A-35
-------
n-Hexane Look-up Table
(CAS No. 110-54-3)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
34
1
265
429
892
1
34
1
100
68
1
299
463
926
1
67
2
250
170
o
6
400
564
1,027
1
169
o
J
500
340
6
569
732
1,195
1
337
6
750
510
8
737
901
1,364
2
506
9
1,000
679
11
905
1,069
1,532
o
5
674
11
2,000
1,359
22
1,017
1,743
2,206
6
1,348
22
3,000
2,038
33
1,129
1,862
2,880
9
1,467
33
5,000
3,397
56
1,354
2,087
4,200
14
1,692
56
10,000
6,794
112
1,916
2,649
4,762
28
2,253
111
A-36
-------
Hexyl Carbitola Look-up Table
(CAS No. 112-59-4)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
1
1
1
1
0
1
100
0
1
1
1
1
1
0
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
1
28
1
111
a Report under Glycol Ether chemical category
A-37
-------
Hexyl Cellosolve" Look-up Table
(CAS No. 112-25-4)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
2
2
1
9
1,000
1
11
1
1
2
o
5
i
11
2,000
2
22
1
2
2
6
1
22
3,000
3
33
1
2
3
9
2
33
5,000
5
56
1
2
4
14
2
56
10,000
10
112
2
3
6
28
2
111
a Report under Glycol Ether chemical category
A-38
-------
Methyl ethyl keytone Look-up Table
(CAS No. 78-93-3; MEK)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
15
1
119
197
431
1
13
1
100
29
1
132
210
444
1
26
2
250
73
o
6
172
249
483
1
65
o
J
500
147
6
237
315
549
1
131
6
750
220
8
302
380
614
2
196
9
1,000
293
11
368
445
679
o
5
261
11
2,000
586
22
459
707
941
6
523
22
3,000
879
33
502
849
1,202
9
665
33
5,000
1,465
56
589
936
1,725
14
752
56
10,000
2,931
112
807
1,154
2,169
28
970
111
A-39
-------
Methanol Look-up Table
(Cas No. 67-56-1)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
8
1
75
123
264
1
8
1
100
16
1
83
131
272
1
16
2
250
41
o
6
106
154
295
1
39
o
J
500
81
6
145
193
334
1
78
6
750
122
8
184
232
373
2
117
9
1,000
163
11
223
271
412
o
5
156
11
2,000
325
22
274
427
568
6
312
22
3,000
488
33
300
506
724
9
391
33
5,000
814
56
352
558
1036
14
443
56
10,000
1627
112
482
688
1286
28
573
111
A-40
-------
Methyl methacrylate Look-up Table
(CAS No. 80-62-6)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
6
1
59
100
232
1
6
1
100
13
1
65
106
238
1
12
2
250
32
o
6
83
124
256
1
30
o
J
500
65
6
113
154
286
1
60
6
750
97
8
143
184
316
2
90
9
1,000
130
11
173
214
346
o
5
119
11
2,000
259
22
235
333
465
6
239
22
3,000
389
33
255
439
585
9
345
33
5,000
648
56
294
479
824
14
385
56
10,000
1,295
112
394
578
1,127
28
484
111
A-41
-------
Methyl isobutyl keytone Look-up Table
(CAS No. 108-10-1; MIBK)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
2
1
30
50
118
1
3
1
100
4
1
33
54
122
1
7
2
250
9
o
6
44
64
132
1
17
o
J
500
18
6
61
81
149
1
35
6
750
28
8
78
99
167
2
52
9
1,000
37
11
96
116
184
o
5
69
11
2,000
74
22
120
185
254
6
139
22
3,000
110
33
132
224
323
9
178
33
5,000
184
56
155
247
462
14
201
56
10,000
368
112
213
305
582
28
259
111
A-42
-------
Methyl tert butyl ether Look-up Table
(CAS No. 1634-04-4; MTBE)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
50
1
457
732
1,464
1
53
1
100
100
1
510
785
1,516
1
106
2
250
250
o
6
668
943
1,675
1
264
o
J
500
499
6
932
1,207
1,939
1
528
6
750
749
8
1,196
1,471
2,203
2
792
9
1,000
998
11
1,460
1,735
2,467
o
5
1,056
11
2,000
1,996
22
1,742
2,790
3,522
6
2,111
22
3,000
2,994
33
1,918
3,194
4,578
9
2,515
33
5,000
4,990
56
2,270
3,546
6,689
14
2,867
56
10,000
9,981
112
3,149
4,426
8,059
28
3,746
111
A-43
-------
n-Butyl alcohol Look-up Table
(Cas No. 71-36-3)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
6
9
23
1
0.7
1
100
2
1
6
10
24
1
1
2
250
6
o
6
8
12
26
1
3
o
J
500
12
6
12
15
29
1
7
6
750
17
8
15
19
32
2
10
9
1,000
23
11
18
22
36
o
5
13
11
2,000
46
22
23
36
49
6
27
22
3,000
69
33
25
43
62
9
34
33
5,000
115
56
30
47
89
14
39
56
10,000
230
112
41
59
112
28
50
111
A-44
-------
Naphthalene Look-up Table
(CAS No. 91-20-3)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
2
6
1
22
3,000
1
33
1
2
2
9
1
33
5,000
2
56
1
2
3
14
2
56
10,000
4
112
2
2
5
28
2
111
A-45
-------
Nitric acid (65%) Look-up Table
(CAS No. 7697-37-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
2
3
8
1
1
1
100
1
1
2
o
5
8
1
1
2
250
1
o
3
2
4
9
1
1
o
J
500
1
6
3
4
9
1
1
6
750
2
8
4
5
10
2
2
9
1,000
2
11
4
6
11
o
J
3
11
2,000
4
22
7
8
13
6
5
22
3,000
6
33
8
11
16
9
8
33
5,000
11
56
9
15
21
14
12
56
10,000
21
112
11
17
34
28
14
111
A-46
-------
Phenol Look-up Table
(CAS No. 108-95-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
2
1
1
o
J
500
1
6
1
1
2
1
1
6
750
1
8
1
1
2
2
1
9
1,000
1
11
1
1
2
o
5
i
11
2,000
3
22
1
2
3
6
1
22
3,000
4
33
1
2
3
9
2
33
5,000
7
56
2
3
5
14
2
56
10,000
15
112
2
3
7
28
3
111
A-47
-------
Phosphoric acid (50%) Look-up Table
(CAS No. 7664-38-2)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
0
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
2
250
1
o
6
i
i
i
i
i
o
J
500
1
6
1
1
1
1
1
6
750
1
8
1
1
1
2
1
9
1,000
1
11
1
1
1
o
5
i
11
2,000
1
22
1
1
1
6
1
22
3,000
1
33
1
1
1
9
1
33
5,000
1
56
1
1
1
14
1
56
10,000
1
112
1
1
2
28
1
111
A-48
-------
sec-Butyl alcohol Look-up Table
(CAS No. 78-92-2; 2-Butanol)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
2
1
19
32
75
1
2
1
100
5
1
21
34
77
1
4
2
250
12
o
6
27
40
84
1
11
o
J
500
23
6
38
51
94
1
22
6
750
35
8
49
62
105
2
32
9
1,000
46
11
60
73
116
o
5
43
11
2,000
92
22
75
116
159
6
87
22
3,000
138
33
82
140
203
9
111
33
5,000
230
56
97
155
289
14
125
56
10,000
461
112
133
191
364
28
161
111
A-49
-------
Styrene Look-up Table
(CAS No. 100-42-5)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
1
1
10
17
41
1
1
1
100
2
1
11
18
42
1
2
2
250
6
o
6
14
21
46
1
5
o
J
500
12
6
20
27
51
1
11
6
750
18
8
25
32
56
2
16
9
1,000
24
11
31
38
62
o
5
22
11
2,000
48
22
41
59
84
6
43
22
3,000
72
33
45
77
105
9
61
33
5,000
120
56
52
84
149
14
68
56
10,000
240
112
70
103
200
28
87
111
A-50
-------
Triethylamine Look-up Table
(CAS No. 121-44-8)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
16
1
98
164
369
1
12
1
100
31
1
110
175
381
1
24
2
250
79
o
J
146
211
416
1
59
o
J
500
157
6
204
270
475
1
118
6
750
236
8
263
328
534
2
177
9
1,000
314
11
322
387
593
o
J
235
11
2,000
628
22
382
623
828
6
471
22
3,000
942
33
421
706
1,064
9
554
33
5,000
1,570
56
499
784
1,534
14
633
56
10,000
3,140
112
695
981
1,824
28
829
111
A-51
-------
tert-Butyl alcohol Look-up Table
(Cas No. 75-65-0)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
8
1
47
79
182
1
5
1
100
17
1
52
84
188
1
11
2
250
41
o
6
68
100
204
1
27
o
J
500
83
6
95
127
230
1
53
6
750
124
8
121
153
257
2
80
9
1,000
165
11
148
180
283
o
5
106
11
2,000
331
22
183
286
389
6
212
22
3,000
496
33
200
339
495
9
266
33
5,000
826
56
236
375
707
14
301
56
10,000
1,653
112
324
463
877
28
389
111
A-52
-------
Tetrachloroethylene Look-up Table
(CAS No. 127-18-4; Perchloroethylene)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
3
1
45
78
188
1
3
1
100
6
1
48
81
191
1
6
2
250
15
o
6
56
89
199
1
14
o
J
500
30
6
70
103
213
1
28
6
750
45
8
85
117
227
2
42
9
1,000
60
11
99
131
241
o
5
56
11
2,000
120
22
155
188
298
6
113
22
3,000
180
33
186
244
354
9
169
33
5,000
301
56
204
354
467
14
279
56
10,000
602
112
251
401
749
28
326
111
A-53
-------
Toluene Look-up Table
(Cas No. 108-88-3)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
5
1
43
72
168
1
5
1
100
9
1
47
77
173
1
9
2
250
23
o
6
61
91
187
1
23
o
J
500
47
6
85
114
210
1
47
6
750
70
8
108
137
234
2
70
9
1,000
93
11
131
161
257
o
5
93
11
2,000
187
22
171
254
350
6
187
22
3,000
280
33
187
320
443
9
253
33
5,000
466
56
218
351
630
14
284
56
10,000
933
112
296
429
826
28
362
111
A-54
-------
Trichloroethylene Look-up Table
(CAS No. 79-01-6)
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
11
1
153
259
588
1
10
1
100
22
1
163
269
597
1
20
2
250
55
o
6
192
299
627
1
49
o
J
500
109
6
242
348
676
1
99
6
750
164
8
291
397
726
2
148
9
1,000
219
11
340
446
775
o
5
197
11
2,000
438
22
537
644
972
6
394
22
3,000
657
33
604
841
1,169
9
591
33
5,000
1,095
56
670
1,145
1,563
14
895
56
10,000
2,190
112
834
1,309
2,549
28
1,060
111
A-55
-------
Xylene (mixed isomers) Look-up Table
(Cas No. 1330-20-7; includes individual isomers )
Air Emissions (in pounds) from bulk unloading, storage, blending and container filling operations
at a typical chemical distribution facility in Louisville, KY
Type of Air Release (Ib)
Al- Container filling emissions
A2 - Piping component leaks - delivery
of liquid to container filling
A3 - Storage tank working + breathing
losses (pick closest tank size)
5,000 gallon tank
10,000 gallon tank
25,000 gallon tank
A4 - Piping component leaks - delivery
of liquid to storage tank
A5 - Blending/mixing tank emissions
A6 - Piping component leaks - delivery
of liquid to blending/mixing tank
Throughput (1,000 Ib/yr)
50
2
1
10
17
42
1
1
1
100
4
1
11
18
43
1
2
2
250
9
o
6
15
22
46
1
6
o
J
500
18
6
20
27
52
1
11
6
750
27
8
26
33
57
2
17
9
1,000
35
11
32
39
63
o
5
23
11
2,000
71
22
42
61
86
6
45
22
3,000
106
33
45
78
108
9
62
33
5,000
177
56
53
86
154
14
69
56
10,000
354
112
72
104
203
28
88
111
A-56
-------
Appendix B City Correction Factors
B-l
-------
City
Homer
Birmingham
Montgomery
Little Rock
Fort Smith
Phoenix
Tucson
Bakersfield
San Francisco
Long Beach
Los Angeles
Sacramento
Santa Maria
Denver
Grand Junction
Wilmington
Miami
Atlanta
Savannah
Honolulu
Des Moine
Boise
Chicago
Springfield
Indianapolis
Wichita
Louisville
Baton Rouge
Lake Charles
New Orleans
Boston
Baltimore
Portland
Detroit
Grand Rapids
St. Paul
St. Louis
Jackson
Billings
State
AK
AL
AL
AR
AR
AZ
AZ
CA
CA
CA
CA
CA
CA
CO
CO
DE
FL
GA
GA
HI
IA
ID
IL
IL
IN
KS
KY
LA
LA
LA
MA
MD
ME
Ml
Ml
MN
MO
MS
MT
City Factor
0.52
1.21
1.31
1.21
1.18
1.67
1.53
1.38
1.02
1.29
1.2
1.21
1.07
0.91
0.97
0.93
1.69
1.17
1.34
1.79
0.83
0.9
0.81
0.91
0.88
1.04
1
1.4
1.41
1.42
0.84
0.97
0.71
0.79
0.77
0.71
0.99
1.31
0.77
B-2
-------
City
Raleigh
Bismarck
Lincoln
Concord
Newark
Roswell
Las Vegas
Buffalo
New York
Cleveland
Columbus
Toledo
Oklahoma City
Tulsa
Astoria
Portland
Philadelphia
Pittsburgh
Providence
Columbia
Sioux Falls
Memphis
Amarillo
Corpus Christi
Dallas
Houston
Midland-Odessa
Salt Lake City
Richmond
Burlington
Seattle
Green Bay
Charleston
Huntington
Cheyenne
State
NC
ND
NE
NH
NJ
NM
NV
NY
NY
OH
OH
OH
OK
OK
OR
OR
PA
PA
Rl
SC
SD
TN
TX
TX
TX
TX
TX
UT
VA
VT
WA
Wl
WV
WV
WY
City Factor
1.11
0.66
0.87
0.73
0.92
1.27
1.45
0.75
0.91
0.81
0.87
0.8
1.15
1.15
0.81
0.89
0.93
0.83
0.83
1.27
0.74
1.19
1.11
1.59
1.36
1.44
1.34
0.93
1.06
0.69
0.83
0.68
0.96
0.97
0.77
B-3
------- |