Evaluation of Diffusion Denuder Coatings for
Removing Acid Gases from Ambient Air

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                                            EPA-454/R-02-011
                                            April 2002
   Evaluation of Diffusion Denuder Coatings
  for Removing Acid Gases from Ambient Air
                            By:
                        Dennis R. Fitz
College of Engineering-Center for Environmental Research and Technology
                    University of California
                     Riverside, CA 92521
                        Prepared For:
            Office of Air Quality Planning & Standards
           Emissions, Monitoring, and Analysis Division
                Assistance Agreement #GX828663
              U.S. Environmental Protection Agency
            Office of Air Quality Planning and Standards
           Emissions, Monitoring, and Analysis Division
                Research Triangle Park, NC 27711

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University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings


Acknowledgments

The author would like to thank John Pisano, who did a marvelous job of constructing the test
apparatus, supervising the experiments and organizing the data. Irina Malkina operated the test
system, and her dedication resulted in nearly 100% data capture with all runs being completed
within a tight schedule.

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University of California, Riverside, CE-CERT                    Evaluation of Diffusion Denuder Coatings


Table of Contents

Acknowledgments	i

1.     Introduction	1
      1.1    Background	1
      1.2    Approach	1

2.     Experimental	2
      2.1    Coated Filters andDenuders	2
      2.2    Test Gas Generation, Measurement and Data Recording	3
      2.3    Experimental Matrix	8

3.     Results and Discussion	10
      3.1    Removal Efficiency	10
      3.2    MgO-Coated Annual Denuder	10
      3.3    Sodium Carbonate-Coated Annular Denuder	12
      3.4    Sodium Chloride-Coated Annular Denuder	15
      3.5    Magnesium Oxide-Coated Honeycomb Denuder	16
      3.6    Sodium Carbonate-Coated Honeycomb Denuder	18
      3.7    Sodium Chloride Denuders	19
      3.8    Filter Testing	20
      3.9    Additional QC Tests to Evaluate the NOy Analyzer Memory Effect	25


4.     Summary and Conclusions	28

5.     Recommendations and Future Research	29
      5.1    Recommendations	29
      5.2    Future Research	30

References   	32

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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
Tables

Table 1.      Test matrix for denuder evaluation	9
Table 2.      Matrix of tests for evaluation	9
Table 3.      Summary of removal efficiency for denuders	11
Table 4.      Summary of filter data	22
Table 5.      Data showing the first ten minutes after injection of zero air	27
Table 6.      Summary of removal efficiencies	28

Figures

Figure 1.     Schematic diagram of the apparatus to expose denuders and filters	3
Figure 2.     Photograph of the test apparatus	4
Figure 3.     Plot of the pH titration curve for diffusion tube B	5
Figure 4.     Plot of the TDL NO2 and FDSTCb  concentrations when
             sampling from diffusion tube B	6
Figure 5.     Plot of the pH titration curve for diffusion tube A	7
Figure 6.     Summary of removal efficiency tests for MgO-coated annular denuders	11
Figure 7.     Summary of removal efficiency tests for sodium
             carbonate coated annular denuders	13
Figure 8.     Time series plot of FDSTCb collection efficiencies, low humidity	13
Figure 9.     Time series plot of FDSTCb removal efficiencies, high humidity	14
Figure 10.    Time series plot of HONO removal efficiencies
             and concentrations, low humidity	15
Figure 11.    Summary of removal efficiency tests for sodium chloride-
             coated annular denuders	16
Figure 12.    Summary of removal efficiency tests for the magnesium oxide-
             coated honeycomb denuders	17
Figure 13.    Time series plot of HONO removal efficiencies,
             high concentrations, high humidity	17
Figure 14.    Summary of removal efficiency tests for the sodium carbonate-
             coated honeycomb denuders	18
Figure 15.    Time series plot of HONO removal efficiencies and concentrations,
             high concentration, low humidity	19
Figure 16.    Removal efficiency of sodium chloride-coated annual and honeycomb
             denuders for  10 ppb of nitric acid at 30% RH	20
Figure 17.    Summary of removal efficiency tests of the replicate nylon filters
             for removing NO2, HONO, and PAN	21
Figure 18.    Summary of removal efficiency tests of the NaCl-coated quartz filters
             for removing NO2, HONO, and PAN	23
Figure 19.    Summary of removal efficiency tests of the replicate Na2(CO3)-coated
             quartz filters  for removing NO2,  HONO, and PAN	24
Figure 20.    NOy measurements at the outlet  of each  denuder with NaCl coated filters added to
             scrub any remaining nitric  acid	26
Figure 21.    Response of the chemiluminescent  NOy analyzer to  a  change in  concentration
             from 45 to zero ppb	26
                                           in

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University of California, Riverside, CE-CERT                      Evaluation of Diffusion Denuder Coatings
Appendices
Appendix A
       Times series plots of concentration and efficiency for all denuders tested

Appendix B
       Time series plots of concentration and efficiency for all filters tested.
                                             IV

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University of California, Riverside, CE-CERT                      Evaluation of Diffusion Denuder Coatings



1. Introduction

1.1 Background

Diffusion  denuders have been  developed to concurrently remove nitric acid and permit particles
to pass unattenuated. The particulate matter may then be collected on specialized  filters that
minimize  further  volatilization. This  technique allows the measurement  of nitric acid and
particulate nitrate with  a minimum of removal  artifacts caused  by  the  volatilization and
condensation of ammonium nitrate. There is  a significant body of literature describing the
suitability of using  such  denuders and filters for this purpose in  studies using ambient air
(Allegrini et al., 1994). There  is, however, little information on the quantitative testing of these
substrates to remove nitric acid while allowing other nitrogenous gases, such as nitrogen dioxide,
nitrous  acid, and  peroxyacetyl  nitrate,  to pass  through  freely.  Removal inefficiency of the
denuder for nitric  acid will bias  the  nitric  acid low and the  particulate nitrate high, while
collecting the other nitrogenous species will bias both high. In addition, there is little published
information on the removal efficiency of an aluminum honeycomb denuder that is currently
offered as a commercial product.

The primary objectives were to:

•      Determine  the short-term  efficiency and capacity of  chemically  coated  filters and
       diffusion denuders that are  currently used in EPA's National PM2.5 Chemical  Speciation
       Network to  collect nitric  acid  and related nitrogenous species under ambient  air
       conditions.

•      Assess the potential interferences associated with the collection of gases on reactive
       filters that follow these denuders that were not efficiently removed by the denuders.

1.2 Approach

The efficiency of magnesium oxide  (MgO), sodium  chloride (NaCl),  and  sodium carbonate
(Na2CC>3) coated substrates in  collecting nitrogenous species was determined by challenging the
substrates to synthetically  generated gases. The removal efficiency was determined by measuring
concentration before and after the  challenged substrate with a chemiluminescent NOy analyzer.
This type of analyzer has been shown to quantitatively  measure all  species  of reactive odd
nitrogen containing compounds (Winer et al.,  1974). The gases tested included:

•   Nitrogen dioxide (NC>2)
•   Nitric  acid (HNO3)
•   Nitrous acid (HONO)
•   Peroxyacetyl nitrate (PAN)

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University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings



2. Experimental

2.1 Coated Filters and Denuders

Filters and Denuders.  Both honeycomb  and annular denuders were  evaluated.  The annular
denuders were manufactured by URG (Chapel Hill, NC) and identified as part number URG-
2000-242-3CSS. These were 3-channel Teflon-coated stainless steel denuders with a length of
242 mm. Teflon adapters  supplied by URG (URG-2000-30AE-7) were used on the inlet and
outlet of the  denuders  to  provide a 3/8 inch female pipe fitting. Honeycomb denuders, part
number 8382, were manufactured by Met One (Grants Pass, OR) and were supplied in  their
stainless steel housing (part number 8370).

Five combinations of denuders and coating types were tested for the removal efficiency.

•  Honeycomb with a MgO coating.
•  Honeycomb with a Na2COs coating.
•  Annular with a MgO coating.
•  Annular with a Na2COs coating.
•  Annular with a NaCl coating.

47mm diameter quartz fiber filters (Pallflex QAT) were coated as  described below while 47mm
diameter Nylasorb nylon filters (Fisher part number 09-751-15) were used as is.

Coating Methods. The honeycomb denuders were coated and extracted according to directions
provided by the manufacturer. The denuder was cleaned with methanol and dipped in a slurry of
MgO  in methanol (50g/160ml). They were then drained and partially dried with dry and filtered
compressed air. They were then allowed to  dry in a rack overnight and sealed in polyethylene
bags until used. A  similar technique was used for the carbonate coating except the coating
solution consisted of lOg of sodium carbonate dissolved in 1000 ml of deionized water to which
10 g of glycerol had been added.

Annular denuders were coated using a methodology developed by the Research Triangle Institute
that is the basis of the recommended procedure by the manufacturer. Approximately 5ml of the
MgO  slurry described above was added to the denuder with the outlet capped.  The  other cap was
installed and the denuder gently rolled to distribute the coating mixture.  The excess mixture was
then poured out, and the denuder was subsequently dried using dry, filtered compressed air. The
denuders were then capped for storage. The carbonate coating solution was the same as that used
for the honeycomb denuder and applied in a similar manner. The NaCl coating solution consisted
of 9% (w/w) NaCl dissolved in a 50/50 methanol-water solution (v/v) with  1% (v/v) added
glycerol.

Quartz filters were coated by being dipped in the coating solution, allowing  the excess to drip
out, and then  dried on aluminum foil set on the bench top. The coating solution consisted of 2%
(w/w) sodium carbonate or sodium chloride in a 50/50 methanol/water solution containing 1%
(v/v) glycerol.

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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
2.2 Test Gas Generation, Measurement and Data Recording

Test Gas Exposure System. Figure 1 shows a schematic diagram of the apparatus used to expose
the denuders to various test gases. Figure 2  is a photograph of the  assembly. Notice that the
denuders were positioned to minimize sample line length. The exposed surface of all connecting
plumbing was PFA Teflon. The system was designed to simultaneously challenge five denuders.
Purified air was humidified by splitting the flow and directing a portion through a bubbler filled
with distilled water and maintained at a constant 20°C. After the bubbler,  the humidified and
dried air streams were remixed. Rotameters and needle valve were used to adjust and monitor the
flow to maintain the desired humidity and total flow rate. A General Eastern model Hygro MI
chilled mirror sensor was used to measure the dew point. Temperature of the  laboratory was
monitored with a thermocouple. The relative humidity (RH) of the test gas was calculated from
the dew point and the laboratory temperature. Flow through all denuders was set and maintained
by needle  valves and rotameters. A ThermoEnvironmental model 42C chemiluminescent NOX
analyzer was used to monitor the test gas concentration. A zero, span, and converter efficiency
check  was  performed  on   the  instrument  before  and  after  each   experiment using  a
ThermoEnvironmetal model  46 dilution calibrator. The  calibrator was supplied with ultra zero
grade air and a cylinder of NO calibration gas in nitrogen. Gas phase titration of NO with ozone
was used  to test the  converter efficiency. In addition,  the background concentration  of the
humidified air was checked before each experiment. All zero checks gave a concentration of less
than 0.3 ppb NOX.
           14/35
           L/min
    70 L/min Pure Air
I
J I
J \
r\






• 56/35
1 L/min
r1
r








J
(-4



\
-)










Test Gas
NO2 , 60&300 ppb (NO 2 Cyl)
HNO3 6&30 ppb (Diffusion Tube)
HONO 2&10ppb (Fluidized Bed)
PAN 2&10 ppb (Photolysis Chamber)










— r>
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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
        Figure 2. Photograph of the test apparatus.

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University of California, Riverside, CE-CERT
      Evaluation of Diffusion Denuder Coatings
Test Gas Generation and Purity Verification.

Nitrogen dioxide was generated by dilution of a 97.4 ppm compressed gas cylinder source in
ultrapure N2 (Scott Research Laboratories, San Bernardino, CA). Flow was maintained with a
McMillan Company model 50 (0-50ml range) electron volumetric flow sensor.

Nitric acid vapor was generated with one of two VICI Metronics (Santa Clara, CA) diffusion
vials (one model B for low range and one  model C for high range) filled with reagent grade
constant boiling (70%) nitric acid. The vials were maintained at 40°C in a water bath.

For  the low-level HNOs  concentrations  the  diffusion rate was  determined by standard pH
titration using NaOH as the base solution.  Figure 3 is a plot of the pH titration of diffusion tube
B, the lower concentration source for the FDSTCb measurements employed in this experiment.
  01
  _3
  ro
                      Concentration of used NaOH solution is 1 .OE-03 +/- 2E-5 mol/l
                      Volume of used NaOH solution 10.0 +/-0.2 ml
                      Time from start to point of inflexion 548 +/- 5
                   -- 0.25
          Diffusion rate 1.15 +/- 0.03 micrograms HNO3/min
                                                                         0.35
                                                                       -- -0.25
                                                                         -0.35
     200     250     300     350     400     450
                                  time (minutes)
500
550
600
       Figure 3. Plot of the pH titration curve for diffusion tube B.

This diffusion rate as determined by the  pH titration was also challenged by using the same
diffusion source as the source gas to a mid-infrared tunable diode laser. The tunable diode laser
system was operational for two-channel monitoring, one for NC>2 and the other for FINOs. Figure
4 depicts this investigation of the HNOs acid diffusion  source. The TDL was calibrated for HNOs
using another diffusion tube source that generated 60 ppbV at 5 L/min. This source is used as
part of the normal TDL systems  calibration. The  diffusion tube source  used for the low
concentrations was investigated  for confirmation of the FINOs diffusion rate and for possible
contamination of NC>2. The diffusion tube FINOs was mixed with zero air and sampled by the
TDL at 7 L/min, resulting in a mixing ratio of 68.7 ppbV with a standard deviation of 3.9 ppbV.

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University of California, Riverside, CE-CERT
                                               Evaluation of Diffusion Denuder Coatings
This measured value from the TDL was within a single standard deviation of the pH titration
determined value for the HNCb diffusion tube B. Notice  that during the measurement of the
HNOs diffusion source, simultaneous values of NO2 on average -0.3, were below the MDL of the
tunable diode laser (1.0 ppbV) and had a standard deviation  of 0.7.
ou
75 -
70
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60 -
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3 45-
rt A „»,
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15 -
10 -
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Average 68. 7 ppbVHNOS m f
• _f • •
• •
HNO3 Standard
deviation 3.9


» ppb N02
• ppb HN03
^ *
Injection of Diffusion •• *
~ TubeHNOS »
•
*** » *
» • ****** *
•
m Ambient Air Measurement '
1.15 micrograms ^
HNO3/min at 7 slm
yields 65 ppbVHNOS •
• •
Average -0.3 ppbV
Zero Air NO2 Standard Deviation 0.7 *- •
-
&• * * • • » ^" » *
! ! ! Mill ! ! ! ! ! ! !
•




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^.^^- "
i i ITI i i i i u.
8:25     8:48    8:58     9:08     9:18    9:28     9:38     9:48
                            PSTTime(hh:mm)
                                                                             9:58
       Figure 4. Plot of the TDL NO2 and HNO3 concentrations when sampling from diffusion tube B.
The lack of NO2 was also confirmed from the observation of the normal concentrated aqueous
acid (70% by weight) in the diffusion tubes throughout the experiment. The solution is colorless
and only becomes yellow as a result of photochemical or thermal decomposition that yields NO2.
                           2HNO3
2NO2 + H2O
                                                 O2
The color of the solution showed no observable changes throughout the period of use. Although
NO was an unlikely interferent, NO measurements were conducted throughout the experiment as
a matter of the normal operational cycle of the TECO 42 with associated NOy converter. There
was never any detectable amount of NO.

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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
Therefore, we concluded that there was no generation of NO2 from this diffusion source and that
the diffusion rate measured was consistent within the estimated errors of the two independent
techniques.

For the higher HNCb  concentrations,  the diffusion rate was determined again by standard pH
titration using NaOH as the base solution. Figure 5 is a plot of the pH titration of diffusion tube
A, the higher concentration source for the FDSTCb measurements  employed in this experiment.

This diffusion rate determined by the pH titration was challenged by repeating the pH test as the
rate was far too high to be in the linear range of the tunable diode laser.  The repeat test yielded a
similar diffusion rate within the uncertainty of the measurement. Again  we saw no discoloration
of the 70%  aqueous solution HNOs in the diffusion tube used for the high concentration during
the experiments.
    14
  Q.
Concentration o
Volume of used
Time from start


**&*&*&




Diffus

fused NaOH solu
NaOH solution 10
o point of inflexior



ion is 1 .OE-03 +/- 2E-5 mol/l
.0 +/- 0.2 ml
1 1 13 +/- 2 minutes
I

*i^r< •
**
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ion rate 5.85 +/- (

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).15 mocrograms

'•
X.
*••«

HNO3/min






***^*->











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'"*••• •

	


0)
n n^ *^
- O.Ob „
"53
Q.
n n^
"53
•a
n 1 R
n 9^
n ^c
0 90 100 110 120 130 140
time (minutes)
       Figure 5. Plot of the pH titration curve for diffusion tube A.

Nitrous acid was generated using the method of reacting hydrochloric acid vapor generated in a
diffusion tube with stirred granular sodium  nitrite (Febo et al., 1995). Rotameters and needle
valves were used to maintain the various flow rates of this generation system. The HONO
concentration was stabilized  by controlling both the flow rate and operating temperature of the
oven  that  contained  the HONO  generating equipment. This  system has been  used in our
laboratory for several years and has been found be to a stable and clean source of nitrous acid.

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University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings
Regular maintenance on the HONO generating system requires a regular change of the sodium
nitrite.

The purity of the nitrous acid source was determined by measuring the total NOX concentration
and then adding a NaCl  coated filter (to remove any nitric acid and determine the amount of
nitric acid by difference), followed by adding a sodium carbonate coated filter (to remove the
HONO, thus leaving residual NO2). These tests showed that the HONO contained approximately
3% of nitric acid and NO2. The NO2  concentrations were verified several times using a TDLAS
and a luminol-based NO2 analyzer.  In addition, the NO channel of the NOX analyzer showed
about 3% NO in the test mixture.

Peroxyacetyl nitrate was generated in a 5 m3 Teflon chamber (Carter et al., 1995) by photolyzing
a mixture of 2ppm acetaldehyde,  SOppb chlorine, and SOppb NO2. Acetaldehyde was maintained
in excess to limit the amount of NO2 remaining and the formation of HNOs. The concentration
was verified with a gas chromatograph with a luminol detector (Fitz et al., 2001) calibrated with
PAN generated in hexane (Holdren and Spicer, 1984). The PAN mixture was delivered to the test
apparatus using a Teflon diaphragm  pump  (Virtual  Industries part #VMP1625MX-24-50-NC).
The flow rate was adjusted to obtain the desired concentration.

Analyzer Control and Data Logging. A Campbell model CR10 data logger was used to operate
the solenoid valves in  the test apparatus and to log the data from the NOX analyzer.  The data
logger was programmed to alternate  between sampling  the concentration of the test gas before
and after each denuder.  Each sampling interval was six minutes, thus allowing  the test gas
concentration below the denuder to be determined once per hour. The data logger recorded the
NOX concentrations as one-minute averages. Data from the fourth minute  of averaging were
reported.

2.3 Experimental Matrix

A total of 21 denuder exposures were conducted varying the test gas concentration (from highest
potential ambient to approximately 20% of that value), relative humidity, and length of exposure.
Many of the 24-hour exposures showed  no  change in removal efficiency, and the next 24-hour
period of testing was considered a replication of the first. A number of additional replicates were
included. Table 1 shows the test  matrix used. Experiment #2 used the same denuders that were
used in Experiment #1  without recoating. These denuders,  therefore, were exposed to nitric acid
for two weeks. One test experiment  (#5) was done using  three denuders coated with the NaCl
solution  to further evaluate this  method for selectivity for nitric acid.  Table 2  shows the test
matrix used for testing the nylon and sodium chloride and sodium carbonate coated quartz filters.

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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
        Table 1. Test matrix for denuder evaluation.
Exp#
1
2
O
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Test
Length,
Hours
124
124
165
47
22
24
188
49
46
25
160
42
23
20
71
25
71
15
8
12
19
Test Gas
HNO3
HNO3
HNO3
HNO3
HNO3
HNO3
HNO3
NO2
NO2
NO2
NO2
HONO
HONO
HONO
HONO
HONO
HONO
PAN
PAN
PAN
PAN
Cone
High
High
High
Low
Low
Low
High
High
High
Low
Low
High
High
High
Low
Low
Low
High
High
Low
Low
RH
Low
Low
Low
Low
Low
High
High
High
Low
Low
High
Low
High
High
High
Low
Low
Low
High
High
Low
Comments

Using spent denuder for another week
Repeat of experiment 1

All denuders NaCl coated








Repeat of 13


Repeat of 16




        Table 2. Matrix of tests for filter evaluation.
Exp#
22
23
24
24
26
27
Test Gas
NO2
NO2
HONO
HONO
PAN
PAN
Concentration
High
High
High
High
High
High
RH
Low
High
High
Low
Low
High

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University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings



3. Results and Discussion

3.1 Removal Efficiency

The  results of the experiments  will be  described by  the  efficiency  of denuders and filters,
expressed as a percentage, to collect the test gas (whether removal of the test gas is desirable or
not). Removal efficiency is defined as follows:

E=  100*(Ci-C2)/Ci

where  Ci is  the  concentration of the test gas prior to the  denuder or filter and €2 is the
concentration after.

3.2 MgO-Coated Annular Denuder

Table 3 summarizes all the experiments  performed exposing the annular denuders to the test
gases (the other  denuders  are included  in this summary table). For nitric acid  the  removal
efficiency is generally over 80% even for tests periods of nearly  eight days at 46ppb. The low-
concentration tests had generally lower efficiencies, but these are subject to more error due to
zero drift than are the high concentrations. The low-concentration,  high-humidity test showed
significantly lower removal efficiency than the others. The removal  efficiency for NC>2  was
consistently about 5%, indicating that this species is not readily removed. This few percent could
be due to minor impurities in the NC>2 such as HONO  in the  compressed gas cylinder. HONO
was removed nearly as effectively as nitric acid. Results from these two acid gases agreed in that
the lowest removal efficiency was the case with low concentration and high humidity. PAN was
removed with variable efficiencies, ranging from 40 to  80%. There was not any apparent trend
with either humidity  or concentration. Note that the PAN tests were conducted for less than 24
hours due to the volume of the PAN mixture available in the chamber.

Figure  6 summarizes the results of all the experiments by presenting the initial denuder removal
efficiency and the efficiency after 1, 4, and 24 hours (or the  last test point if the exposure lasted
less than 24 hours) and the average for the  exposure  period for all four test gases.  Appendix A
contains the detailed time  series  plots. Except for a few outliers, there is little difference in
removal efficiency as the testing progresses. This indicated that the  denuder has capacity to
remove high  concentrations of nitric and nitrous acids.  The  high-RH,  low-concentration test
indicated that the denuder was initially somewhat effective in removing NO2, but the efficiency
dropped to background within four hours. This was likely a valid result particular to the coating
material since the MgO-coated honeycomb denuder also showed  this behavior for only this test
condition. Experiment #18 showed an unexplainable steep drop off in the removal efficiency for
PAN during the last two hours of the test.
                                           10

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University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
        Table 3. Summary of removal efficiency for denuders.
Exp
#
1
2
3
4
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Test
Gas
HNO3
HNO3
HNO3
HNO3
HNO3
HNO3
NO2
NO2
NO2
NO2
HONO
HONO
HONO
HONO
HONO
HONO
PAN
PAN
PAN
PAN
Ave
Cone,
ppb
51.5
49.6
51.0
9.6
7.9
46.3
69.2
76.4
16.7
16.3
30.2
30.8
30.8
9.2
8.6
7.7
14.8
3.8
25.2
25.2
RH
30%
30%
30%
30%
70%
70%
70%
30%
30%
70%
30%
70%
70%
70%
30%
30%
30%
70%
70%
30%
Period Average Efficiency (%)
Annular
MgO
95.1
91.2
92.5
82.1
63.2
83.0
4.0
5.7
5.4
5.3
92.5
87.2
83.8
76.7
82.3
85.2
69.5
62.6
80.3
38.6
Annular
Na2CO3
84.1
26.6
76.7
81.2
64.3
77.4
3.9
5.3
4.9
4.5
85.9
88.1
85.3
78.3
80.7
72.8
27.4
22.7
32.7
9.0
Annular
NaCl
66.5
57.3
59.5
59.7
52.9
61.5
3.2
4.8
4.7
3.9
6.5
20.7
24.1
25.1
26.3
25.1
26.9
22.8
32.7
8.8
Honeycomb
MgO
92.4
88.0
89.9
82.3
52.1
79.6
2.0
4.4
2.1
3.6
91.9
79.2
85.3
66.6
80.5
81.0
77.6
66.9
80.5
44.2
Honeycomb
Na2CO3
93.1
87.9
90.0
81.4
64.9
82.1
0.0
3.0
1.7
2.2
60.3
86.8
78.4
70.0
79.3
79.9
27.7
19.9
32.4
4.5
                                               10   11   12   13   14   15  16   17   18  19  20   21   22
                                              Experiment Number
        Figure 6. Summary of removal efficiency tests for the MgO coated annular denuders.
                                                 11

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University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings
3.3 Sodium Carbonate-Coated Annular Denuder

Table 3 summarizes all the experiments performed exposing this denuder to the test gases. For
nitric acid the removal efficiency is generally over 70% even for tests periods of nearly 15 total
days (the denuders were not recoated after Experiment #1) at 50 ppb. As with the  magnesium
oxide coating, the removal efficiency for NC>2 was low (5%)  and that for HONO was high
(typically  80%).  PAN,  however,  was  collected at significantly  lower efficiency  than the
magnesium oxide coating.

Figure 7 summarizes the results of all the experiments by presenting the initial denuder removal
efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if the exposure lasted
less than 24 hours) and the average for the exposure period for all the four test gases. Appendix
A contains the detailed time series plots. During Experiment #1 the nitric acid removal efficiency
at 24 hours dropped appreciably and was less than 40% when the same denuder was started for
Experiment #2.  Figure 8 is a time series plot  of the nitric acid concentration before and after the
denuder and the calculated denuder efficiency. After about two days  of sampling 50 ppb of nitric
acid, the denuder removal efficiency started to drop, and the efficiency dropped from  nearly 90%
to 50% over  the next five days. This denuder had apparently used up much of its adsorption
capacity. This drop-off in  removal efficiency was not  observed  in the parallel  experiment that
used the magnesium oxide coated  annular denuder, even after  13  days  of exposure, thus
indicating that magnesium oxide coating has a much higher capacity  than carbonate. A  similar
efficiency drop-off was also observed in the  replicate test (Experiment #3). Experiment #7 was
similar to Experiments #1 and #3, but at high humidity instead of low.  Figure 9 is the time series
plot  of efficiency for this test and a slower drop off is noted after  two days. It appears that
humidity aids the carbonate in adsorbing nitric acid. This might be due to increasing the mass
transfer of carbonate to the surface of the  denuder.  Figure  10 shows  a similar  drop-off in
efficiency when HONO was the test gas and the RH was low. The efficiency drop was much less
under high RH conditions.
                                           12

-------
University of California, Riverside, CE-CERT
                                                                Evaluation of Diffusion Denuder Coatings
                 HN03
                                        NO2
                                                        MONO
                                                                           PAN
                                                                   17  18   19  20   21  22
                           HRH   HRH  HRH  LRH  LRH  HRH  LRH  HRH  HRH  HRH  LRH  LRH  LRH  HRH  HRH   LRH
                                         Experiment Number
Figure 7. Summary of removal efficiency tests for the sodium carbonate coated annular denuder.
     100.0
      90.0
      80.0
  I
.fc
m
      70.0
      50.0
  H,  40-°
  O
  I
      30.0
      20.0
      10.0
                                                                        • HNO3
                                                                        - Efficiency
                                            ..%•*•
                                                                                       100.0%
                                                                                       95.0%
                                                                                       90.0%
                                                                                       85.0%
                                                                                       80.0%  "
                                                                                       75.0%
                                                                                     70.0%
                                                                                       65.0%
                                                                                       60.0%
                                                                                       55.0%
Effi
                                                                                       50.0%
       28-Mar
                                              31 -Mar
                                            Date (2001)
                                                                                  3-Apr
        Figure 8. Time series plot of HNO3 removal efficiencies and concentrations and before and after
        the sodium carbonate coated annular denuders under low humidity conditions.
                                                   13

-------
University of California, Riverside, CE-CERT
                                                              Evaluation of Diffusion Denuder Coatings
     100.0
      90.0
      80.0
      70.0



   g
   Q.

   3  60.0
   •s
   t:

   m

   g
   o
   o
50.0
      40.0
      30.0
      20.0
      10.0 -
0.0


 24-Apr
                                                                           HNO3


                                                                           Efficiency
                          26-Apr
                                       28-Apr


                                       Date (2001)
30-Apr
2-May
                                                                                          100.0%
                                                                                          90.0%
                                                                                          80.0%
                                                                                          70.0%
                                                                                          60.0%   o
                                                                                    50.0%
                                                                                          40.0%
                                                                                          30.0%
                                                                                          20.0%
                                                                                          10.0%
                                                                                          0.0%
        Figure 9. Time series plot of HNO3 removal efficiencies and concentrations and before and after

        the sodium carbonate coated annular denuders under high humidity conditions.
                                                    14

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
HONO Concentration (ppbV)






30 0 -



• HONO

"'--_
"-
-
.



• •








30 0%



21 -May 22-May 23-May
Date (2001)
       Figure 10. Time series plot of MONO removal efficiencies and concentrations and before and
       after the sodium carbonate coated annular denuders under low humidity conditions.
3.4 Sodium Chloride-Coated Annular Denuder

Table 3 summarizes all the experiments performed exposing this type of denuder to the test
gases. For nitric acid the removal efficiency, with the period average ranging from 53 to 67%, is
significantly lower than for the annular denuders with sodium carbonate  or magnesium  oxide
coatings. The removal efficiency for NC>2 was as low and similar to that observed with the other
two coating materials while that for HONO and PAN was much lower, approximately 25%.
These results show that NaCl coating, while somewhat less efficient in scrubbing nitric acid, is
much less efficient in removing HONO and PAN and, therefore, more selective.

Figure  11  summarizes the results of all the experiments by presenting the initial denuder removal
efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if the exposure lasted
less than  24  hours)  and the average for the exposure  period for all of the four test gases.
Appendix A contains the detailed time series plots. For nitric acid the efficiency tends to drop
somewhat in the removal  efficiency but remains at a  constant level during the 13  days  of
exposure conducted during tests #1 and #2. For other test gases the removal efficiency remains
fairly constant without any clear-cut trends.
                                           15

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
                                    10  11  12  13  14  15  16  17  18  19  20  21  22
                                    LC  LC  HC
                                   Experiment Number
       Figure 11. Summary of removal efficiency tests for the sodium chloride coated annular denuders.
3.5 Magnesium Oxide-Coated Honeycomb Denuder

Table 3 summarizes all the experiments performed exposing the honeycomb denuders to the test
gases.  The period average removal  efficiencies for all of the test gases were  similar to  that
obtained for this coating on annular denuders. The low-concentration/high-humidity experiment
(#15) with nitric acid also showed significantly lower removal efficiency than the others.

Figure 12 summarizes the results of all the experiments by presenting the initial denuder removal
efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if the exposure lasted
less than 24 hours) and the average for the exposure period for all four subject gases. Appendix
A contains the detailed  time  series plots. With several exceptions  during the PAN and HONO
testing, the removal efficiencies generally did not go down with sampling time. Experiment #11
showed a significant initial adsorption efficiency  of NC>2 at low concentrations and high RH
followed by a rapid drop in efficiency. This is consistent with the behavior of the similarly coated
annular denuder. Figure  13  shows the time series plot for Experiment #13 with HONO as the test
gas (high RH, high  concentration).  In this figure the removal  efficiency  slowly and steadily
dropped as a function of time. This phenomenon was not observed in the replicate test (#14), but
it was  in the low-concentration/high-humidity test (#15). Slow drops in removal efficiency were
also observed for all of the PAN exposure tests.
                                            16

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
            LRH  LRH  LRH  LRH
                           HRH  HRH  HRH  LRH  LRH  HRH LRH  HRH  HRH  HRH  LRH  LRH  LRH  HRH  HRH LRH
                                      Experiment Number
        Figure 12.  Summary of removal  efficiency tests for the magnesium oxide coated  honeycomb
        denuders.



>"
.a
Q.
a.
c
o
1
Concen
MONO










30 0 -



n n -
• MONO
- Efficiency
" ~ - _
_
— —





• ••"**







30 0%



n no/.




I
o
s
3
C
Q




       23-May
 24-May
                                         Date (2001)
        Figure 13.  Time series  plot of MONO  removal efficiencies and concentrations  and before and
        after the magnesium oxide  coated  honeycomb denuders under high concentration and  humidity
        conditions.
                                                17

-------
University of California, Riverside, CE-CERT
                                 Evaluation of Diffusion Denuder Coatings
3.6 Sodium Carbonate-Coated Honeycomb Denuder

Table 3 summarizes all the experiments performed exposing the honeycomb denuders to the test
gases.  The period average removal efficiencies for all of the test gases  were similar to that
obtained for this coating on  annular denuders. The low-concentration/high-humidity test with
nitric acid also showed significantly lower removal efficiency than the others.

Figure 14 summarizes the results of all the experiments by presenting the initial denuder removal
efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if the exposure lasted
less than 24 hours) and the average for the exposure period for all four test gases. Appendix A
contains the detailed time series plots. A noticeable difference was that the removal efficiency for
nitric acid in Experiment #2  did  not drop, as was the case  for the  similarly  coated  annular
denuder. This indicates that the honeycomb denuder has higher capacity than the annular denuder
does. For  HONO Experiment #12  (low RH, high  concentration) and  #15  (high RH, low
concentration) the removal efficiency for HONO  starting dropping almost immediately. Figure
15 shows the time series plot of concentration and removal efficiency for Experiment #12. This
drop-off is similar to that observed with the magnesium oxide  coated denuder sampling HONO
in Tests #13 (see Figure  9) and #15. Only slight drop-offs were observed in the other HONO
tests.
          LRH  LRH  LRH  LRH
            10  11  12 13  14  15  16  17  18  19  20  21  22

HRH  HRH HRH LRH  LRH  HRH  LRH HRH  HRH  HRH  LRH  LRH  LRH  HRH HRH LRH
LC  HC HC HC  LC  LC  HC HC  HC  LC  LC  LC  LC  LC  HC HC
           Experiment Number
       Figure  14. Summary of removal efficiency tests for the sodium carbonate coated honeycomb
       denuders.
                                            18

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings


70 0 -
|
1
0)
o
c
O
1 300 -




-
~ _
~
- - - _ . MONO
- _ - _ - Efficiency
™ _
-





70 0%



- 30 0%



21-May 22-May 23-May
Date (2001)
       Figure 15. Time series plot of MONO removal efficiencies and concentrations and before and
       after the  sodium  carbonate  coated  honeycomb denuder under high concentration and low
       humidity conditions.
3.7 Sodium Chloride Denuders

While sodium chloride appeared to be a more selective denuder coating for nitric acid compared
with sodium chloride  or carbonate, the  removal efficiency when used to coat annular denuders
was never more than 80% and rapidly stabilized to about 60%. Clearly this would be a problem
in sampling ambient air as two or three denuders in series would be required. Experiment #1 with
nitric acid showed that the honeycomb denuder design appeared to have higher capacity to adsorb
nitric acid than the annular ones when sodium carbonate was the coating substrate. Therefore, a
test was conducted (Experiment  #5) to  determine  the  efficiency  of sodium chloride-coated
honeycomb denuders.  A combination of low concentration and humidity was used as this was
generally the combination that led  to  the lowest overall removal  efficiencies for nitric  acid
(regardless of the denuder type or coating substrate). Figure 16 shows the results. The removal
efficiency for the  annular denuders drop from 80% and stabilize  after 16 hours  to  55% as
previously observed. The efficiency of the honeycomb denuder, however, remains near 80%. A
sodium  chloride-coated honeycomb denuder may therefore be a viable combination with which
to determine nitric acid concentrations in the air.
                                           19

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
Denuder Efficiency



80.0%

?n n%


55 0%

HNO3 Concentration Approximately 10 ppb

• Annular Denuder 2
—»— Honeycomb Denude

: t • % % , ^—^ 	
i *:**»*»**»» 4 » * 4 % % * * % %
• »
«
• #
»
•
• »
•
• »
• • • • »
• • • 1 *

12:00 16:00 20:00 0:00 4:00 8:00 12:0(
                              Time (Data Taken April 19-20, 2001)

       Figure 16. The removal efficiency of sodium chloride coated annular and honeycomb denuders
       for 10 ppb of nitric acid at 30% RH.
3.8 Filter Testing

Nylon. Figure 17  summarizes the results of all the experiments by presenting the initial filter
removal efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if the exposure
lasted  less than 24  hours)  and the average for the exposure period for all  three test  gases.
Appendix B contains the detailed time series plots. Although high initial  removal efficiency was
observed for Experiments #22 and #24, the efficiency immediately dropped and remained stable
there after. Nylon filters appear to have a small efficiency (10-20%) to collect NO2 and HONO
but almost no affinity for PAN. These  results for NC>2 and HONO are consistent with those
previously reported  (Perrino et al., 1990).  There was no significance difference in  removal
efficiency due  to RH.  Table 4 list the overall collection efficiency determined by the NOX
analyzer and compares the  amount of nitrate found on the filter with that  calculated from the
average concentration difference before and after the filter. For NO2 the amount of nitrate on the
nylon  filter was  about half of that calculated. It is  likely that the NO2 retained by the filter
decomposed to both  nitrate and nitrite. In the absence of ozone, the nitrite would not be oxidized
to nitrate and therefore would not be accounted for in the chemical analysis. For HONO even less
was found on the filter compared to  the calculated amount,  thus indicating  that most of the
HONO was retained as nitrite. With PAN this pattern was reversed, with the amount found on
the filter being greater than the amount calculated.  This may be due to measurement errors due to
low PAN concentrations and possible hang up of nitrogenous species in the NOX analyzer.
                                            20

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings

Filter 1
Filter 2
100-
8C



•STc 6(
™s
= 8
S>
3 4(
.2m 40 -
E

2(
(
0-
I Mr~i^"-)^ I Ur-iMr-i MUNU , DAM KAN |













r- 	 -*^









*



1
^ ^^^^±











» Initial

• 1 Hour

A 4 Hours

x 24 Hours
— *— Period Average













— 	 	 1__
« 	 1
LKH1 HKH ' HKH ' LKH LKH HKH1 '















21 HC22 HC 23 HC 24 HC 2&C HC26 27
LRH HRH HRH LRH LRH HRH
HC HC Exp
-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
Table 4. Summary of filter data.
Filter
Type

Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Nylon
Nylon
NaCI Qz
C03-Qz
CO3-Qz
Test
Gas

N02
N02
NO2
N02
N02
N02
NO2
NO2
N02
NO2
MONO
MONO
MONO
MONO
MONO
MONO
MONO
MONO
MONO
MONO
PAN
PAN
PAN
PAN
PAN
PAN
PAN
PAN
PAN
PAN
Nominal
Cone,
ppb
30
30
30
30
30
29
29
29
29
29
25
25
25
25
25
26
26
26
26
26
9
9
9
9
9
9
9
9
9
9
RH


30
30
30
30
30
70
70
70
70
70
70
70
70
70
70
30
30
30
30
30
30
30
30
30
30
70
70
70
70
70
Period Ave
Efficiency
%
17
14
8
3
4
12
11
6
5
3
29
23
45
68
71
13
11
32
82
83
5
6
NA
2
5
2
2
NA
3
4
Nitrate
Collected,
ugN
11.1
11.5
9.3
4.7
6.0
15.2
14.2
13.1
11.2
11.3
2.3
1.2
0.6
0.6
0.8
7.7
4.6
0.9
0.8
1.1
12.5
13.5
13.5
12.1
11.9
15.7
15.2
15.8
14.9
14.5
N from
Concentration
Difference, ugN
26.1
20.6
30.0
12.5
13.7
31.3
27.7
16.1
13.4
8.9
43.2
33.4
60.2
86.9
93.0
18.0
16.4
45.9
114.8
116.5
1.5
1.8
NA
0.7
1.5
0.9
0.9
NA
1.3
1.7
                                                   22

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
NaCl Coated Quartz. Figure 18 summarizes the results of all the experiments by presenting the
initial filter removal efficiency and the efficiency after 1, 4, and 24 hours (or the last test point if
the exposure lasted less than 24 hours) and the average for the exposure period for all three test
gases. Appendix B contains the detailed time series plots. NaCl coated filters also appear to have
a small efficiency (less than 10%) to collect NO2 while they were relatively efficient in removing
HONO  (30-50%). There was no data available for PAN  due to equipment failure. Table 4
compares  the  amount  of  nitrate  found on the  filter  with  that calculated  from  the NOX
concentration difference before and after the filter. The results are similar to that observed for the
nylon filter.
100 N02 HONO

"aT
5)
ency (percen
i C
U C
in





nHy


/\
N

PAN






• Initial
• 1 Hour
A 4 Hours
x 24 Hours
— x— Period Average





21 22 23 24 25
LRH HRH HRH LRH
HC HC HC HC
Experiment Number

26 27
LRH HRH
HC HC
       Figure 18. Summary of removal efficiency tests of the NaCl coated quartz filters for removing
       NO2, HONO and PAN.
          Coated Quartz. Figure 19 summarizes the results of all the experiments by presenting
the initial filter removal efficiency and the efficiency after 1, 4, and 24 hours (or the last test
point if the exposure lasted less than 24 hours) and the average for the exposure period for all
three test gases. Appendix B  contains the detailed time series plots. The removal efficiency is
very low for NC>2 and PAN while that for HONO is nearly 80%. These results also appear to be
independent of the RH. Table 4 compares the amount of nitrate found on the filter with  that
calculated  from the NOX concentration  difference before and after the  filter.  The  results are
similar to that observed for the nylon filter and NaCl coated filters.
                                            23

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
Efficiency (percentage)
NJ -fc* (J> CO O
000000
Summary of Experimental Results Quartz Filter (Filter 4) NaC2CO3 Coated
NO2 HO NO PAN



/
/
1 *
1

/






\~-^^*
21 22 23 24 25 26 27
LRH HRH HRH LRH LRH HRH
HC HC HC HC HC HC
Experiment Number


• Initial
• 1 Hour
A 4 Hours
X 24 Hours
—X— Period Average


Summary of Experimental Results Quartz Filter (Filter 5) NaC2CO3 Coated
NO2 . MONO PAN

"aT
ency (percent
^ c
D C
' 	 '
E
11J




/
/
* *
i
t^\






\
\^<

• Initial
• 1 Hour
A 4 Hours
X 24 Hours
X Period Average

21 22 23 24 25 26 27
LRH HRH HRH LRH LRH HRH
HC HC HC HC HC HC
Experiment Number
       Figure 19. Summary of removal efficiency tests of the replicate Na2(CO3) coated quartz filters for
       removing NO2, MONO and PAN.
                                              24

-------
University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings
3.9 Additional QC Checks to Evaluate the NOy Analyzer Memory Effect

It is likely that the reported nitric acid removal efficiencies were biased low due to the time lag of
the analyzer when switched from measuring nitric acid the before denuder to measuring it after
the denuder. This  is known  as the  "memory effect" and has  been routinely reported when
measuring NOy in  the atmosphere. It was  necessary to sample repeatedly before  and after the
denuder to characterize the removal of nitric acid. We could have sampled only after the denuder
and allowed the analyzer to  reach its  actual zero point, but then we  could not monitor  any
changes in the input concentration. In addition, as nitric acid penetrated some of the denuders,
the memory  effect would again become significant.

We did perform two experiments to evaluate the memory effect. In the first we stopped the
routine cycling between before and after the denuder and sampled  only after the denuder. In
addition we  added NaCl coated  filters after the denuders, which have been shown to be specific
in removing nitric acid (Perino et al.,  1990). By doing this we expected to scrub out most of the
HNOs  prior to the entrance  of the  TECO  NOy converter. The HNCb source response  was
measured  prior to the experiment and found to be on  average  49.4  ppbV with  a standard
deviation of 1.4 ppbV. The test  was conducted at 30% humidity. Figure 20 shows  the results of
four hours of sequentially sampling below all five denuders at a six-minute cycling interval. All
one-minute  data are illustrated here  since we do not  expect  a  need for the instrument to
equilibrate since the sample is expected to  be free of any nitric acid. Each of the denuder paths
displayed  similar response, with initial values of about 0.8 ppbV  of NOy and dropping to 0.5
ppbV after approximately 4 hours. This 0.3  ppbV drop is likely from  the converter volatizing
deposited HNCb on its interior surfaces over the four-hour period.  This  shows that there are no
nitrogenous  species exiting the denuder other than perhaps nitric acid.

In the second  experiment we measured the response time for the NOy  analyzer after it cycled
from measuring nitric acid to zero air. Figure 21 shows the result. The  instrument sampled the
high diffusion source HNCb for a period of 24  hours  and yielded an average concentration of
45.52 ppbV. After the introduction of zero  air at 10:29 the HNCb measured value goes down to
the 0.8 level after five minutes. After  35 minutes the HNOs level is down to 0.65 ppbV. Table 5
lists the data found on Figure 21 and calculated the theoretical denuder efficiency as a function of
time.  As a  result of the long delay  in the  TECO analyzer, the efficiency measurement was
recorded by  taking the fifth minute point after measuring the concentration of the exit gas from
the denuder.

If we had waited longer, as 35  minutes, we would still be at 0.65 ppbV or  1.4% of the input
concentration.  This memory  effect clearly biased the efficiencies  lower  but represented on
average less than  1.8% of the original target  gas. To facilitate  the  measurements  with  the
chemiluminescent analyzer to a point where the memory effect was reduced to 1% of the input
concentration would have required 3 hours  between point instead of the 12 minutes employed in
the study. This would have reduced the resolution of the efficiency experiment and is clearly time
wise, beyond the scope of the experiment.
                                           25

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
             HNO3 Source 49.4

            Standard Deviation 1.4 ppbV
                                              Time (PST) (hh:mm)
        Figure 20. NOy Measurements at the outlet of each denuder with NaCI  coated  filters added to
        scrub out any remaining nitric acid.
   n
    o

   13

   'c
    o
   O
   «
   O
50 •
40-
30
20
9:
Injection of
/ Zero Air
	 	 ^_ ^ 	 I

Average Concentration 45.52 ppbV



X


Concentration
5 Minutes
After Zero
Air Injection
I S
iO 9:57 10:04 10:12 10:19 10:26 10:33 10:40 10:48
Concentration
35 Minutes
After ^ero
Air Injection
N^
10:55 11:02 11
                                          time (PST) (hh:mm)



        Figure 21.  Response of the chemiluminescent NOy analyzer to  a  change in average injection
        concentration from 45 ppbV of HNO3to zero air.
                                               26

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
        Table 5. Data showing  the first ten minutes after injection of zero air into the Teco 42  NOy
        converter.
Time
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
HNO3
(ppbV)
47.31
47.05
2.72
1.36
1.00
0.91
0.81
0.80
0.76
0.80
0.78
% Of Input
Concentration
103.9%
103.4%
6.0%
3.0%
2.2%
2.0%
1.8%
1.8%
1.7%
1.8%
1.7%
                                                 27

-------
University of California, Riverside, CE-CERT
Evaluation of Diffusion Denuder Coatings
4. Summary and Conclusions

Table 6 summarizes the removal efficiency for both the filters and denuders by averaging all the
test  results  for  a given  test gas  and sampling  medium.  These averages  provide  a robust
comparison  of each sampling method and allows for a direct comparison between  methods.
Based on this table and the previously described data the following conclusions may be drawn:

       Table 6. Summary of removal efficiencies.
Test
Gas
HNO3
NO2
HONO
PAN
Nylon
Filter
NA
14
13
3.8
Na2C03
Filter
NA
3.8
76
3.5
NaCl
Filter
NA
7.0
39
NA
Annular
MgO
85
5.1
85
63
Annular
Na2CO3
68
4.6
82
23
Annular
NaCl
60
4.2
21
23
Honeycomb
MgO
81
3.0
81
67
Honeycomb
Na2CO3
83
1.7
76
21
Nitric Acid

Both  magnesium oxide  and sodium  carbonate  coated  denuders were  generally efficient at
removing nitric acid while the sodium chloride coated annular denuder was not. None of the tests
showed over 95% efficiency, but this may have been due to residual nitric acid in the sampling
lines of the test apparatus. While the removal efficiencies for both the annular and honeycomb
denuders were similar,  the  honeycomb design possessed a much higher capacity. This was
evidenced by  breakthrough using the carbonate coated  annular  denuder but not with  the
carbonate coated honeycomb denuder when both were exposed to SOppb of nitric acid over
several days.

Nitrogen Dioxide

Except for the nylon filter and perhaps the sodium chloride-coated  filter, none of the sampling
media removed more than  a few percent of nitrogen dioxide.  Since NO2 is often a dominant
nitrogenous species, the use of this filter for selectively collecting nitrate may, based on our data,
produce a positive bias.

Nitrous Acid

Both carbonate and magnesium oxide-coated denuders and carbonate  coated filters effectively
removed nitrous acid. Sodium chloride was less efficient and nylon  was even less  effect in
removing this  gas.  Trace impurities  of nitric acid (typically  3%) in the HONO no  doubt
contributed to the apparent removal efficiency.

Peroxyacetyl Nitrate

Magnesium  oxide was more efficient in removing PAN  compared with sodium carbonate or
sodium  chloride, which were about equally efficient. Neither nylon  nor carbonate coated  filters
removed a significant amount of PAN.
                                           28

-------
University of California, Riverside, CE-CERT                      Evaluation of Diffusion Denuder Coatings


5. Recommendations and Future Research

5.1 Recommendations

The recommendations based on this study depend on whether the objective is to measure nitric
acid or total particulate nitrate.

Nitric Acid

When measuring nitric acid it is expected that denuders are renewed after each sampling period,
presumably no longer than 24 hours. The denuder would be expected to be efficient and selective
in removing this acid and easily extracted. While both annular and honeycomb denuders with
either carbonate of magnesium oxide coating would be efficient, the carbonate coating is less
efficient at removing PAN and is therefore preferred. In either case nitrous acid is also efficiently
collected and, therefore, the results will be biased high since the nitrite (and also PAN) collected
will be  readily  oxidized to nitrate by ambient concentrations of ozone (Perrino et al., 1990). It
should be noted that the honeycomb denuder holders were constructed of stainless steel, and
some of the removal efficiency for  nitric acid in particular may be due to these surfaces. If this
denuder is to be used to measure nitric acid (as opposed to removing it for measuring particulate
nitrate), the recovery of nitric acid  by the denuder itself should be evaluated. Sodium chloride-
coated annular denuders were found to not be sufficiently efficient in removing nitric acid under
these conditions.

If measuring particulate nitrate is desired using the  same  denuder to quantify nitric acid as the
gaseous  stripper, the carbonate-coated  filter is recommended over  the  nylon.  Although the
carbonate-coated filter efficiently removes nitrous acid, this  already has been removed by the
denuder. Particulate nitrate collected on nylon filters will likely be biased  high  due to the
collection of nitrogen dioxide.

Particulate Nitrate

When measuring particulate nitrate it is only  necessary  to remove the nitric acid and  allow
particles to  pass through.  In this case the denuder  does not need to be changed regularly and
preferably it is  only renewed for cleaning purposes. Selectivity is not necessary, and depending
on  the  filter medium used, not even  necessarily desirable. A  denuder that  strips all of the
nitrogenous gases would allow any filter that quantitatively traps ammonium nitrate be used to
collect particulate  nitrate. Based on two weeks of  exposure to  over  SOppb of nitric acid, the
annular denuder coated with magnesium oxide and the honeycomb with either coating can be
used for at least 16,800 ppb-hours. From past measurements in Claremont,  CA, the highest daily
average  we observed using a tunable  diode laser absorption  spectrometer was 12ppb.  This
concentration corresponds to two months of sampling under these conditions. Since this was the
highest  daily concentration observed in the peak smog season in a location that likely has the
highest  nitric acid  concentrations in the United States, this denuder should be  capable of being
effective for significantly  longer periods for  other parts of the  country. The magnesium oxide
coating is likely to have greater capacity than the carbonate. Because of this potential and its
ability to remove more PAN than carbonate, this coating  is recommended for this  application.
                                            29

-------
University of California, Riverside, CE-CERT                      Evaluation of Diffusion Denuder Coatings
The honeycomb design is also likely to have more capacity, but this would require further
evaluation

With a magnesium oxide denuder to strip nitric acid, the best choice of a filter to collect nitrate
would be the carbonate coated since it is less likely to collect NO2 than nylon filters. Sodium
chloride coated filters may also be suitable, but we did not have results for this substrate on either
nitric acid or PAN.

5.2 Future Research

Previous research has shown that denuders coated with sodium chloride, sodium carbonate and
magnesium oxide are all nearly 100% efficient in removing nitric acid from ambient air (Febo et
al., 1990).  Future research should focus testing removal efficiency using spiked  ambient air.
Since ambient air will contain a variety of nitrogenous species, the use of a chemiluminescent
NOX analyzer for determining concentration before and  after a test substrate would clearly not be
useful. More  selective methods  should be  used,  such  as tunable  diode  laser absorption
spectrometers (TDLAS).

For nitric acid measurement both magnesium oxide and sodium carbonate-coated denuders will
bias the results high.  Sodium  chloride coating appears  to be, as reported previously (Perrino et
al., 1990), much more selective in removing nitric acid,  having very little affinity for nitrous acid
and  slightly more for PAN.  In our studies the nitric acid removal efficiency of the  sodium
chloride-coated annular denuder was lower than the other substrates. The desirable  selectivity of
the NaCl coating also may result in  an apparent lower removal efficiency compared with  other
coating substrates if significant amounts of other nitrogenous species are present in the nitric acid
test gas (since  the chemiluminescent analyzer will also respond to them).  Although we  have
shown that our nitric acid source appears to contain little contamination, using a TDLAS to test
efficiency would be a more quantitative approach.

Since the honeycomb denuder design  appeared to possess greater efficiency and  capacity, we
recommend evaluating the use of sodium chloride coatings in removing nitric  acid. As previously
mentioned, the  effect of the stainless steel denuder holder must first be  evaluated. Evaluation of
the lower capacity annular denuder showed a peculiar initial loss in denuder efficiency removal
efficiency followed  by stabilization.  Additional  or substitute  wetting agent may  result in
maintaining high removal efficiency. Using longer annular denuder sections may also increase
the removal efficiency.

Both nylon and sodium chloride-coated filters appeared  to collect small amounts of NC>2, HONO,
and  PAN. Further evaluation is needed to confirm the significance of this,  preferably using
spiked ambient air. The use of a TDLAS as a detector would provide a quantitative result since it
would  be more selective and have  less sample hangup  than  a chemiluminescent  analyzer.
Carbonate-coated filters showed a high removal efficiency for HONO and, therefore, should be
avoided for collecting particulate nitrate without an effective nitric  acid denuder, as the results
are likely to be biased high.  Additional testing is  recommended to determine  the  efficiency of
sodium chloride coated filters for collecting nitric acid. A more rigorous analysis of impurities
and  sample line hold up (if  a chemiluminescent analyzer  was used for measurements) would
provide a more  accurate removal efficiency determination.
                                            30

-------
University of California, Riverside, CE-CERT                      Evaluation of Diffusion Denuder Coatings
Analysis of filter extracts by  a method quantifying total  nitrogen would improve the mass
balance when removal is compared with adsorption. Although the NOX analyzer showed low
removal efficiencies of PAN by the various filters, a significant amount of nitrate was found on
these filters after sampling. Further evaluation is needed to determine the fate of PAN on these
filters.
                                            31

-------
University of California, Riverside, CE-CERT                     Evaluation of Diffusion Denuder Coatings
References

Allegrini, I; Febo, A.; Perrino, C.; and Masia, P. (1994) Measurement of atmospheric nitric acid
in gas phase and nitrate in particulate matter by means of annular denuuders. Intern. J. Anal.
Chem. 54, 183-201.

Carter, W.P.L.;  Luo,  D.;  Malkina,  I.L.;  and  Fitz, D. (1995) "The University of California,
Riverside  Environmental  Chamber  Data Base for  Evaluating  Oxidant  Mechanisms.  Indoor
Chamber Experiments through 1993,' Report  submitted to the U.S. Environmental  Protection
Agency, EPA/AREAL, Research Triangle Park, NC, March 20.

Febo, A.; Perrino, C.; Gherardi, M.; Sparapani, R. Evaluation of a  High-Purity and High-Stability
Continuous Generation System for Nitrous Acid; Environ. Sci. Technol. 1995, 29, 2390-2395.

Fitz., D.R.; Pankratz,  D.V.; Bumiller, K.; Smith M.  (2001) Measurement of NO2 and PAN by
Gas Chromatography with Luminol Detection. To be submitted to  Atmospheric Environment.

Holdren, M.W.;  Spicer, C.W. Field Compatible Calibration Procedure for Peroxyacetyl Nitrate.
Environ. Sci. Technol.  1984, 18:113-116.

Perrino, C.;  DeSantis, F.;  and Febo, A. (1990) Criteria for the  choice of a denuder sampling
technique  devoted to the measurement of atmospheric nitrous  and nitric acid. Atmos. Environ.
24A, 617-626.

Winer, A.M; Peters,  J.W.; Smith, J.P.; and Pitts, J.N., Jr. (1974)  Response of commercial
chemiluminescent NO-NOX analyzers to  other nitrogen-containing  compounds. Environ. Sci.
Technol. 8, 1118-1121
                                           32

-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO.
EPA-454/R-02-011
2
4. TITLE AND SUBTITLE
Evaluation of Diffusion Denuder Coatings for Removing Acid
Gases from Ambient Air

7. AUTHOR(S)
Dennis R.Fitz
9. PERFORMING ORGANIZATION NAME AND ADDRESS
College of Engineering-Center for Environmental Research and
Technology
University of California, Riverside, CA 92521

12. SPONSORING AGENCY NAME AND ADDRESS
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
April 2002
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
Assistance agreement #
GX82866301
13. TYPE OF REPORT AND PERIOD COVERED
Final, life of project 1 yr.
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
This report represents an initial study of the efficiency and capacity of denuders used in EPA's National
PM2.5 Chemical Speciation Trends Network. Additional work is needed to clarify uncertainty and
allow for additional quantitative results.
16. ABSTRACT
This study evaluated the efficiency and capacity of several commonly used denuder styles and coatings,
with an emphasis on denuders used in EPA's National PM2.5 Chemical Speciation Trends Network
(STN). Denuder styles included annular and honeycomb denuders coated with either magnesium oxide,
sodium carbonate, or sodium chloride. Collection filters included nylon or filters impregnated with
sodium carbonate (N^CC^) or sodium chloride (NaCl). Denuder coatings and reactive filters were
tested for their removal efficiency of nitric acid, nitrogen dioxide (NO2), nitrous acid (HNO2), and
peroxyacetly nitrate (PAN). Most important to the STN is the ability to collect ammonium nitrate with
minimal bias and interference from other nitrogen gases, such as, NO2, HNO2, and PAN. Results
indicated that MgO denuders were most efficient for removing HNO3, HNO2, and PAN with the largest
capacity and that honeycomb denuders had larger capacity than annular denuders. Nylon filters
adsorbed slightly more NO2 than those coated with Na^O;, or NaCl, but both of the latter adsorbed
significantly larger amounts of HNO2 Results suggest that a MgO coated honeycomb or annular
denuder followed by a Na2CO3 or nylon filter will minimize interferences for the collection of
ammonium nitrate. The choice between Na2CO3 and nylon may be based on expected concentrations of
HNO7, with nylon having a lower affinity for HNO7 than Na,CO3
17.
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
nitric acid, denuders, nylon filters, impregnated
filters, sodium carbonate, ammonium nitrate
18. DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
Air Pollution control
19. SECURITY CLASS (Report)
Unclassified
20. SECURITY CLASS (Page)
Unclassified
c. COSATI Field/Group

21. NO. OF PAGES
32 + appendices
22. PRICE
EPA Form 2220-1 (Rev. 4-77)    PREVIOUS EDITION IS OBSOLETE

-------
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HNO3 Concentration (ppbV)
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Denuder Efficiency

-------
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                                                                              HNO3

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     28-Mar
                                                31-Mar


                                              Date (2001)
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-------
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-------
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-------
    EPA Denuder Efficiency Evaluation Denuder 5
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-------
              EPA Denuder Efficiency Evaluation Denuder 1
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-------
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                                                8-Apr

                                              Date (2001)
                                                                                              100.0%
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-------
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-------
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-------
               EPA Denuder Efficiency Evaluation Denuder 1
Experiment 3 (Repeat of Experiment 1, Low Humidity, High HNO3 Concentration)
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Denuder Efficiency
                           Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 4

                Experiment 3 (Repeat of Experiment 1, Low Humidity, High HNO3 Concentration)
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                                              Date (2001)

-------
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   10-Apr
                             EPA Denuder Efficiency Evaluation Denuder 3

             Experiment 3 (Repeat of Experiment 1, Low Humidity, High HNO3 Concentration)
13-Apr
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                                                                                        80.0%
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                                         Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 2

                Experiment 3 (Repeat of Experiment 1, Low Humidity, High HNO3 Concentration)
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                                                                              HNO3

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                                                       -- 90.0%
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                                                         80.0%
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                                                               Q
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                                                         0.0%
                                              Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 5

                Experiment 3 (Repeat of Experiment 1, Low Humidity, High HNO3 Concentration)
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13-Apr
                                                                              HNO3

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16-Apr
                                                       -- 90.0%
                                                        85.0%
                                                        100.0%
                                                        95.0%
                                                        80.0%  u

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                                                               3

                                                        70.0%  S
                                                               Q
                                                        65.0%
                                                        60.0%
                                                        55.0%
                                                        50.0%
                                              Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 4 (Low Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
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c.r\ n _
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17-Apr 18-Apr 19-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 4 (Low Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)

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•i nn no/.
17-Apr 18-Apr 19-Apr
Denuder Efficiency
               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 4 (Low Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n
-inn
1 U.U
n n
• HNO3
- Efficiency


_
-
- _ _ _ - — -
—



.
• • •

qn noA
an no/
yn r\%.
en noA o
0)
|o
en no/ jS
i»
0)
•c
AH n% ni
Q
on noA
on no/
-i n no/
1 U.Uvo
n no/.
17-Apr 18-Apr 19-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 4 (Low Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
on n _
70 0
fin n
c.r\ n _
40 0
on n
on n _
-inn
1 U.U
n n
• HNO3
- Efficiency









.
*••** •••••••••

qn noA
an no/
7D n%
en noA o
0)
'o
en no/ Uj
i»
0)
•c
AH n°A ni
Q
on noA
on no/
-i n no/
1 U.Uvo
n no/.
17-Apr 18-Apr 19-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 4 (Low Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
on n
70 0
en n
c.r\ n -
40 0
on n
on n -
10 0
n n



• HN03
- Efficiency









- 50.0%
- 0.0%
o
0)
'o
.en no/ Uj
i«
0)
3
c
0)
a
- -100.0%
- -150.0%
onn no/.
17-Apr 18-Apr 19-Apr
               Date (2001)

-------
Experiment 5: Investigation of NaCI Coated Denuders
   (Low Humidity, Low HNO3 Acid Concentration)
Denuder Efficiency
1 UU.U /O
qc no/
an n% _
oc (\OL
an no/
jc no/
70 n%
RE; n% -
fin n%
cc n%
en n%
HNO3 Concentration Approximately 10

l Annular Denuder 2
	 Honeycomb Denuder

1 l ,
A
' A - . * * , , A '* , ,
• i
i
• i
•
• i
1 ,
• i i
ii,
' • ' •
• ii" ii
•••:••
12:00 16:00 20:00 0:00 4:00 8:00 12:OC
      Time (Data Taken April 19-20, 2001)

-------
EPA Denuder Efficiency Evaluation Denuder 4
HNO3 Concentration (ppbV)
on n
yu.u
on n
7n n
Rn n
en n
4n n
on n
on n
m n
n n
• HN03
- Efficiency










on no/
oU.Uvo
fin n%
4n n%
on n%
n n%
.on n%
4n n%
fin n%
.an n%
•i nn no/.
19-Apr 20-Apr
Denuder Efficiency
            Date (2001)

-------
EPA Denuder Efficiency Evaluation Denuder 3
HNO3 Concentration (ppbV)
on n -
on n
70 0
60 0
en n
40 0

on n
-inn
n n
• HN03
- Efficiency


-
-
_ - - -






an n%
on n%
7n n%
fin n%
en n%
4n n%
on n%
on n%
1 n n%
n no/.
19-Apr 20-Apr
Denuder Efficiency
            Date (2001)

-------
EPA Denuder Efficiency Evaluation Denuder 2
HNO3 Concentration (ppbV)
on n -
on n
70 0
60 0
en n
40 0

on n
-inn
n n
• HN03
- Efficiency


-
-
~ -






an n%
on n%
7n n%
fin n%
en n%
4n n%
on n%
on n%
1 n n%
n no/.
19-Apr 20-Apr
Denuder Efficiency
            Date (2001)

-------
EPA Denuder Efficiency Evaluation Denuder 1
HNO3 Concentration (ppbV)
on n _
on n
oU.U
70 0
60 0
en n
40 0
on n
on n
m n
n n
• HN03
- Efficiency











on no/
on no/
oU.Uvo
yn (]%.
fin no/ o
.92
'o
£
en noA LLI
i_

-------
EPA Denuder Efficiency Evaluation Denuder 5
HNO3 Concentration (ppbV)
on n -
on n
70 0
60 0
en n
40 0

on n
-inn
n n
• HN03











- 50.0%
- 0.0%
o
c
0)
'o
£
en r\o/n LU
•c
i
- -100.0%
- -150.0%
onn no/.
19-Apr 20-Apr
            Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 6 (High Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n -
10.0
n n
• HNO3
- Efficiency



_ __ -~ -_--_- ~--~







qn n%
an no/
?n n%
fin n% o
0)
|o
en no/ Uj
i»
0)
•c
Af\ Cl°/n fll
Q
on n%
on no/
- 10.0%
n no/.
22-Apr 23-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 6 (High Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0

c.r\ n -
40 0
on n
on n -
10.0
n n
• HNO3
- Efficiency



~ - _
-
- - _ _ -





qn r\o/n
an no/
yn noA
>
en no/ o
DU.U/O g
a>
|o
en no/ jS
i»
0)
•c
AH n% ni
Q
on noA
on no/
- 10.0%
n no/.
22-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 6 (High Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n -
10.0
n n
• HNO3
- Efficiency




^
"





qn (\OL
an no/
yn no/
en noA o
0)
'o
Kn no/ JS
i»
0)
•c
AH n°A ni
Q
on noA
on no/
- 10.0%
n no/.
22-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 6 (High Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n -
10.0
n n
• HNO3
- Efficiency



_--___- -- - -







qn n%
an no/
?n n%
fin n% o
0)
|o
en no/ Uj
i»
0)
•c
An n% ni
Q
on n%
on no/
- 10.0%
n no/.
22-Apr 23-Apr
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 6 (High Humidity, Low HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n -
10.0
n n
• HNO3
- Efficiency



~--~ " ~ - -_ - _ -







qn no/.
an no/
jn no/
en no/. o
0)
|o
Kn no/ JS
i»
0)
•c
Af\ C\OL Q<
Q
on no/
on no/
- 10.0%
n no/.
22-Apr
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 7 (High Humidity, High HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
on n _
70 0
fin n
50 0
40 0
on n
on n _
10.0
n n
• HNO3
- Efficiency

-=~-«— ^^-rf^^-^^^^^-^^^^^^^,^^



****.« --"'V>^^w*^^Vxv^; r . '-'V~- » • .




qn noA
an no/
yn noA
en noA o
0)
|o
50 0% IS
i_
0)
•c
AC\ nOA fi«
Q
on (]%.
on no/
- 10.0%
n no/.
24-Apr 26-Apr 28-Apr 30-Apr 2-May
Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 7 (High Humidity, High HNO3 Concentration)
HNO3 Concentration (ppbV)
nn n
on n
70 0
fin n
c.r\ n -
40 0
on n
on n
10.0
n n
• HNO3
- Efficiency

*"^"e" "i*w-^-
•v ~ -f ~


***» rf/V^ lA^.vV^^tf^^A^^'.'^ii^^X,^^**1^*1*'**' v*« •*



•• "• "* "^
Qn n%
on n%
7n r\%.
en n% o
a>
'o
en no/ H]
1»
0)
•c
AH n°A ni
Q
on n%
on no/
- 10.0%
n no/.
24-Apr 26-Apr 28-Apr 30-Apr 2-May
Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 7 (High Humidity, High HNO3 Concentration)
HNO3 Concentration (ppbV)
Qn n
on n _
70 0
60.0
cn n
40 0
on n
20.0
-inn
n n

• HNO3
- Efficiency



-
•s.
B
™~~ ^^^^^^^~*
ta 	
-*wy ~- ^•^•"NVrv^v-vvw^v^v^




24-Apr 26-Apr 28-Apr 30-Apr
Date (2001)



%A

Qn
on
?n
60
cn
4n
on
20
m
n r
0%
0%
0%
0%
0%
0%
0%
0%
0%
Denuder Efficiency
2-May

-------
                                 EPA Denuder Efficiency Evaluation Denuder 2

                            Experiment 7 (High Humidity, High HNO3 Concentration)
   100.0
    90.0
    80.0
    70.0


|


1  60.0
c
o
5

£
>;'
                      26-Apr
                        28-Apr


                         Date (2001)
30-Apr
                                                                                           100.0%
                                                                                           90.0%
                                                                                           80.0%
                                                                                           70.0%
                                                                                           60.0%
                             50.0%
                                                                          J.0%
                                                                                           30.0%
                                                                                           20.0%
                >
                o

                0)
                'o


                s
                L.
                0)
                •c

                c
                0)
                a
                                                                                         -- 10.0%
                                                                                           o.c
2-May

-------
   100.0
    90.0
    80.0
    70.0
    60.0
c
o

    50.0
o

o

O   40.0
 CO
o
    30.0
    20.0
    10.0
     0.0
                                  EPA Denuder Efficiency Evaluation Denuder 5

                             Experiment 7 (High Humidity, High HNO3 Concentration)
                                                                                  HN03

                                                                                - Efficiency
      24-Apr     25-Apr     26-Apr     27-Apr     28-Apr     29-Apr     30-Apr     1-May     2-May


                                               Date (2001)
100.0%
90.0%
80.0%
70.0%
60.0%  u

       0)
50.0%  LU
       i_
       0)

       3

40.0%  S
       Q
30.0%
20.0%
10.0%
0.0%

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 8 (High Humidity, High NO2 Concentration)




f
Q.
o
ration (|
Concent
\j
OJ
O






qn n
an n

70.0
fin n
en n
40 0
on n
on n
m n

n n
5-N
• NO2
- Efficiency











lay 6-May 7-May
Date (2001)

90 0%
on no/.

- 70.0%
60 0%
en no/,
^.n n%.
on no/,

1 n n%

n n%





r i
Efficien
L.
0)
•D
C
0)
a






-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 8 (High Humidity, High NO2 Concentration)




f
Q.
o
ration (|
Concent
\j
OJ
o





on n
on n _
70 n
fin n
en n
40 0
on n
on n
m n

o.o -
5-N
• NO2
- Efficiency


-s ,«t • % % t • • • •••• 1 1 ••• 1 1 ••••*t
*






lay 6-May 7-May
Date (2001)

qn noA
an no/
7n n%
en noA o
a>
'o
E
en noA LLI
i»
0)
•c
4n n% a)
on noA
on noA
1 n n%

- 0.0 /u

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 8 (High Humidity, High NO2 Concentration)





f
Q.
o
C
O
5
Concent
VJ
OJ
o





on 0
an n

70 0
en 0
en 0
40 0
on n
90 0
100
0 0
5-N
• NO2
- Efficiency











lay 6-May 7-May
Date (2001)

- 90.0%


- 70.0%
o
c
- 50.0% o
it
LU
0)
•c
c
0)
- 30.0% °

- 10.0%
1 n n%.


-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 9 (Low Humidity, High NO2 Concentration)






f
Q.
o
ration (|
Concent
\j
OJ
o
2






Qn n

on n

70 0
fin n
c.r\ n -
40 0
^n n
on n
-inn

On
7-N

• N02
- Efficiency










"
-
lay 8-May 9-May
Date (2001)

qn n%

sn n%

?n n%
Rn n% o
0)
|o
en no/ H]
1»
0)
•c
40 0% ^
Q
•in no/
on n%
•in n%

Ono/.


-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 9 (Low Humidity, High NO2 Concentration)





f
Q.
o
ration (|
Concent
\j
OJ
O






qn n
80.0


fin n
en n
40 0
on n
on n
m n

n n
7-N
• NO2
- Efficiency










—

lay 8-May 9-May
Date (2001)

90 0%
- 80.0%

7n n%
fin n% o
a>
'o
E
en n% LLJ
i»
0)
•c
c
40 0% ^
Q
on n%

1 n n%

n n%


-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 9 (Low Humidity, High NO2 Concentration)




f
Q.
o
ration (|
Concent
\j
OJ
O






qn n
800

fin n
en n
40 0

on n
m n

n n
7-N
• NO2
- Efficiency


.....*••••* *••..... .*•*** •••••"







™
lay 8-May 9-May
Date (2001)

Qn n%
- 80 0%
7n n%
Rn n%
en n%
4n n%
on n%
on n%
1 n n%

n n%





r i
Efficien
L.
0)
•c
c
*1>
a






-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 9 (Low Humidity, High NO2 Concentration)





f
Q.
o
ration (|
Concent
\j
OJ
O






qn n
80.0


fin n
en n
40 0
on n
on n
m n

n n
7-N
• NO2
- Efficiency



. • *





-
~ ~ - — _ _

lay 8-May 9-May
Date (2001)

90 0%
- 80.0%

7n n%
en 0% o
0)
'o
E
en n% LLJ
i»
0)
•c
c
40 0% ^
Q
on n%

1 n n%

n n%


-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 9 (Low Humidity, High NO2 Concentration)




f
Q.
o
ration (|
Concent
\j
OJ
O






qn n
80.0

fin n
en n
40 0
on n
on n
m n

n n
7-N
• NO2
- Efficiency

	 j 	 • 	









lay 8-May 9-May
Date (2001)

90 0%
- 80.0%
7n n%
en n% o
a>
'o
E
en n% LLJ
i»
0)
•c
c
40 0% ^
Q
on n%

1 n n%

n n%


-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 10 (Low Humidity, Low NO2 Concentration)
AC n
40 0

f
Q.
Q. on n
0
S p50
c
0)
o
c
,9 on n
OJ
O
15.0
m n
c n

n n
9-N


• N02
- Efficiency






_
"
lay 10-May
qn n%
an no/
7n no/.
Rn n% o
0)
|o
en no/ jS
i»
0)
•c
An n°/, ni
Q
- 30.0%
on no/
m n%



               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 10 (Low Humidity, Low NO2 Concentration)

AC n
40 0
oc n
f
Q.
Q. on n
0
S p50
c
0)
o
c
,9 on n
OJ
O
•i c n
m n
c n
n n
9-N
• NO2
- Efficiency










~ - - _ - - - .----
lay 10-May

qn n%
an no/
7n n°A
fin no/, o
a>
|o
en no/ jS
i»
0)
•c
AC\ Cl°/n fll
Q
30 0%
on no/n
m n%


               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 10 (Low Humidity, Low NO2 Concentration)

AC n
40 0
oc n
f
Q.
Q. on n
0
S p50
c
0)
o
c
,9 on n
OJ
O
15.0
m n
c n

n n
9-N
• NO2
- Efficiency









^

lay 10-May

qn n%
an no/
7n n°A
en noA o
0)
|o
en no/ jS
i»
0)
•c
An n% ni
Q
- 30.0%
on no/
m n%



               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 10 (Low Humidity, Low NO2 Concentration)

AC n
40 0
oc n
f
Q.
o. on n
0
S 250
c
0)
o
c
,9 on n
OJ
O
-\ c n
m n
c n

n n
9-N
• NO2
- Efficiency










_

lay 10-May

qn n%
an no/
yn noA
fin n% o
0)
|o
en no/ jS
i»
0)
•c
c
a
on noA
on no/
m n%

n noA

               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 10 (Low Humidity, Low NO2 Concentration)

AC n
40 0
oc n
f
Q.
Q. ^.n n
0
?
2 05 n
c
o
c
,9 on n
OJ
O
-\ c n
m n
c n

.u -
9-N
• NO2
- Efficiency










_ _
	 — 	 — 	 T 	 '
lay 10-May

qn n%
an no/
7n n°A
en noA o
0)
|o
en no/ jS
i»
0)
•c
An n% ni
Q
30 0%
on no/n
m n%

.U%
               Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 1

                            Experiment 11 (High Humidity, Low NO2 Concentration)
   50.0
   45.0
   40.0
   35.0
1 30.0


o


£  25.0

0)
o
c

O  20.0
   15.0
   10.0
    5.0
    0.0
  100.0%
  90.0%
  80.0%
  70.0%
  60.0%   u

         0)
  50.0%  u
         i_
         0)

         =

  40.0%   S
        Q
-- 30.0%
  20.0%
  10.0%
  0.0%
     10-May     11-May     12-May      13-May     14-May     15-May     16-May     17-May     18-May


                                              Date (2001)

-------
   50.0
   45.0
   40.0
   35.0
   30.0


o


|  25.0

0)
o
c

O  20.0
   15.0
   10.0
    5.0
    0.0 4-
                                  EPA Denuder Efficiency Evaluation Denuder 4

                             Experiment 11 (High Humidity, Low NO2 Concentration)
                                                                               NO2

                                                                               Efficiency
  100.0%
  90.0%
  80.0%
  70.0%
  60.0%
         0)
  50.0%
         i_
         0)
         •c


  40.0%  S
         Q
  30.0%
  20.0%
  10.0%
4- 0.0%
     10-May     11-May     12-May     13-May     14-May      15-May     16-May     17-May     18-May


                                              Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 3

                             Experiment 11 (High Humidity, Low NO2 Concentration)
   50.0
   45.0
   40.0
   35.0
   30.0


o


|  25.0

0)
o
c

O  20.0
   15.0
   10.0
    5.0
    0.0
                                                                              NO2

                                                                              Efficiency
100.0%
90.0%
80.0%
70.0%
60.0%
       0)
50.0%
       i_
       0)
       •c


40.0%  S
       Q
30.0%
20.0%
10.0%
0.0%
     10-May     11-May     12-May     13-May      14-May      15-May     16-May     17-May     18-May


                                              Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 2

                             Experiment 11 (High Humidity, Low NO2 Concentration)
   50.0
   45.0
   40.0
   35.0
   30.0


o


|  25.0

0)
o
c

O  20.0
   15.0
   10.0
    5.0
    0.0
                                                                              NO2

                                                                              Efficiency
100.0%
90.0%
80.0%
70.0%
60.0%
       0)
50.0%
       i_
       0)
       •c


40.0%  S
       Q
30.0%
20.0%
10.0%
0.0%
     10-May     11-May     12-May     13-May      14-May      15-May     16-May     17-May     18-May


                                              Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 5

                            Experiment 11 (High Humidity, Low NO2 Concentration)
   50.0
   45.0
   40.0
   35.0
   30.0


o


|  25.0

0)
o
c

O  20.0
   15.0
   10.0
    5.0
    0.0
100.0%
90.0%
80.0%
70.0%
60.0%
       0)
50.0%
       i«
       0)
       •c


40.0%  S
       Q
30.0%
20.0%
10.0%
0.0%
     10-May     11-May     12-May      13-May     14-May     15-May     16-May     17-May     18-May


                                              Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 12 (Low Humidity, High HONO Concentration)
MONO Concentration (ppbV)
an n
yu.u
an n
yn n
fin n
en n
4n n
30 0
on n
10, n
n n

• MONO












an no/
yu.u /o
an no/
yn n%
fin n%
en no/
4n n%
30 0%
on no/
m n%
n no/.
21 -May
Denuder Efficiency
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 12 (Low Humidity, High HONO Concentration)
MONO Concentration (ppbV)

90.0
an n
7n n
fin n
en n
4n n
30 0
on n
m n
n n
• MONO











- 90.0%
an no/
?n n%
fin n% o
0)
'o
en no/ Uj
i«
0)
•c
An n% ni
Q
30 0%
on no/
m n%
n no/.
21 -May 22-May 23-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 12 (Low Humidity, High HONO Concentration)
AC n
40 0
oc n
f
Q.
•f 30.0
o
|
0)
o
0
O on n
o
O
1 K n
m n
c n
n n
• HONO
- Efficiency









"•--"-- 	 -'- ___ __ 	 --
~
on n%
an 0%
TO n%.
- 60.0% g
a>
|o
en no/ jS
i»
0)
•c
AC\ nOA fi«
Q
30 0%
on no/
m n%
n no/.
21 -May 22-May 23-May
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 12 (Low Humidity, High HONO Concentration)
HONO Concentration (ppbV)
90
80
70
60
50
40
30
20
10
0
n


n
n
n
o

n
n

~ ~ ~ ~ - - _


"---.
-


• HONO
- Efficiency
-_


.



..


21 -May 22-May


on
on
?n
fin
en
4n
30
on
m
n r
0%
0%
0%
0%
0%
0%
0%
0%
0%
Denuder Efficiency
23-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 5

Experiment 12 (Low Humidity, High HONO Concentration)
MONO Concentration (ppbV)
on n
an n
70 0
en n
en n
40 0
30 0
on n
m n
n n

-
~ _
~--
- - - _ _ • nor
~ - _ - _ - Effic
^JO
;iency
~~-__






21 -May 22-May 23-May
                                                               100.0%
                                                                D.0%
                                                               80.0%
                                                               60.0%
                                                               50.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
                                                               30.0%
                                                               20.0%
                                                                J.0%
                                                               0.0%
                  Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 13 (High Humidity, High HONO Concentration)
MONO Concentration (ppbV)
900
sn n
7n n
fin n
en n
4n n
30 0
on n
m n
On
• MONO
- Efficiency
~ ~ - - -









- 90 0%
sn n%
7n n%
fin n%
en no/
4n n%
30 0%
on n%
m n%
n no/.
23-May 24-May
Denuder Efficiency
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 13 (High Humidity, High HONO Concentration)
MONO Concentration (ppbV)
on n
on n
yn n
en n
en n
4D n
300
on n
m n
n n
• MONO
- Efficiency

~ ~ -
- _
— —







on noA
on noA
yn no/
en noA o
0)
'o
Kn no/ JS
i»
0)
•c
AC\ nOA fi«
Q
- 30 0%
on no/
m n%
n no/.
23-May 24-May
                 Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 3

                           Experiment 13 (High Humidity, High HONO Concentration)
   50.0
   45.C
    3.0
   35.0


f
Q.
Q.
*•* 30 0
c
o

0)
o

o
o
O
I
    5.0
   20.0
   15.0
   10.0
    5.0
    0.0
                                                                               HONO

                                                                               Efficiency
    23-May
24-May
                      100.0%
                     90.0%
                     80.0%
                     70.C
                     60.C
                       D.0%
                     30.C
                     20.0%
                       J.0%
                     0.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
                                              Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 13 (High Humidity, High HONO Concentration)
HONO Concentration (ppbV)
90 0
an n
70 n
fin n
c.r\ n -
4n n
30 0
on n
m n
n n

-------..

• HONO
— Efficiency








90 0%
an no/
yn no/
fin n% o
0)
|o
en no/ jS
i»
0)
•c
Af\ HO/. fi«
Q
30 0%
on no/
m n%
n no/.
23-May 24-May
                 Date (2001)

-------
      EPA Denuder Efficiency Evaluation Denuder 5

Experiment 13 (High Humidity, High HONO Concentration)
MONO Concentration (ppbV)
on n
an n
70 0
en n
en 0
40 0
300
on n
m n
n n


~ ~ ~ — —



• nor
- Effic
^JO
;iency






23-May 24-May


                                                                100.0%
                                                                90.C
                                                                80.0%
                                                                70.C
                                                                60.0%
                                                                50.0%
                                                                 J.0%
                                                                30.0%
                                                                20.0%
                                                                 J.0%
                                                                0.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
                  Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 14 (High Humidity, High HONO Concentration)
MONO Concentration (ppbV)
qn n
Rn n
?n n
Rn n
en n
4n n
30 0
on n
m n
On
• MONO
- Efficiency
™ ™ ™ • ™ ™ • •




• ' . • *




qn n%
RD n%
7n n%
Rn n%
en no/
4n n%
30 0%
on n%
m n%
n no/.
24-May 25-May
Denuder Efficiency
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 14 (High Humidity, High HONO Concentration)
HONO Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
30 0
on n
m n
n n
• HONO
- Efficiency

^ ^ ^ ^ ^




•
	

. .

qn noA
an no/
7D n%
en noA o
0)
|o
en no/ jS
i»
0)
•c
AH n°A ni
Q
30 0%
on no/
m n%
n no/.
24-May 25-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 14 (High Humidity, High HONO Concentration)
AC n
40 0
oc n
f
Q.
•^ 30 0
o
|
0)
o
0
O on n
o
O
1 K n
m n
c n
n n
• HONO
- Efficiency




'
.••.....*..•••...•".
*
--" - " -"--" "--


Qn n%
on 0%
TO n%.
60 0% ""
a>
|o
en no/ jS
i_
0)
•c
AH n°A ni
Q
30 0%
on no/
m n%
n no/.
24-May 25-May
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 14 (High Humidity, High HONO Concentration)
HONO Concentration (ppbV)
on n
an n
yn n
fin n
Kn n
4n n
•?n n
on n -
m n
n n

_ ~
^

• HONO
— Efficiency



• . • *




on noA
an no/
?n n%
fin n% o
0)
'o
Kn no/ Uj
i»
0)
•c
An n°A ni
Q
•?n no/
on no/
m n%
n no/.
24-May 25-May
                 Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 5

                           Experiment 14 (High Humidity, High HONO Concentration)
   100.0
   90.0
   80.0
   70 0


f
Q.


•f 60.0

o
5

£
0)
o

o
o

O
z
O
I
50.0
 D.O
   30.0
   20.0
    10.0
    0.0
     24-May
                                                                     25-May
                                                                                           100.0%
                                                                                          90.C
                                                                                          80.0%
                                                                                          70.0%
                                                                                          60.0%
50.0%
                                                                                          30.0%
                                                                                          20.0%
                                                                                            J.0%
                                                                                          0.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
                                              Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 15 (High Humidity, Low HONO Concentration)
MONO Concentration (ppbV)
qn n
on n
OU.U
7n n
fin n
en n
4n n
on n
on n
m n
On
• MONO
- Efficiency

	 ~~~~~ 	 — -_-_







qn n%
on no/
oU.Uvo
7n n%
fin n%
en no/
4n n%
on n%
on n%
m n%
n no/.
25-May 26-May 27-May 28-May
Denuder Efficiency
                 Date (2001)

-------
   100.0
   90.0
   80.0
   70 0


f
Q.


•f 60.0

o
5

£
0)
o

o
o

O
z
O
I
50.0
 J.O
   30.0
   20.0
    10.0
    0.0
                                 EPA Denuder Efficiency Evaluation Denuder 4

                           Experiment 15 (High Humidity, Low HONO Concentration)
                                                                              MONO

                                                                              Efficiency
     25-May
                          26-May
        27-May


Date (2001)
28-May
                                                                                           100.0%
                                                                                           90.C
                                                                                           80.0%
                                                                                           70.0%
                                                                                           60.0%
                50.0%
                  J.0%
                                                                                           30.0%
                                                                                           20.0%
                                                                                            J.0%
                                                                                           0.0%
                                                       >
                                                       o

                                                       0)
                                                       'o


                                                       s
                                                       L.
                                                       0)
                                                       •c

                                                       c
                                                       0)
                                                       a

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 15 (High Humidity, Low HONO Concentration)
MONO Concentration (ppbV)
qn n
an n
7n n
en n
en n
4n n
on n
on n
m n
n n
• MONO
- Efficiency







__- _ -_-__ 	 	 " -~ ~~~~~~-_-~__ __-

	
qn noA
an no/
yn no/
fifl n% o
a>
|o
en no/ jS
i»
0)
•c
AC\ nOA fi«
Q
on noA
on no/
m n%
n no/.
25-May 26-May 27-May 28-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 15 (High Humidity, Low HONO Concentration)
MONO Concentration (ppbV)
an n
yu.u
on n
7D n
fin n
en n

on n
on n
-inn
n n

• MONO
- Efficiency

_~ ~ ""-"-—___ -
~_~— —_~—_ _






••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••a
an no/
yu.u /o
on noA
70 0%
>
cn r\Q/n o
0)
|o
^n n% LU
k.
0)
•o
AC\ C\°/n m
Q
30 0%
on no/n
1 n n%.
n no/_
25-May 26-May 27-May 28-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 5
Experiment 15 (High Humidity, Low HONO Concentration)
MONO Concentration (ppbV)
an n
yu.u
an n
7n n
en 0
en n
40 0
on n
on n
100
0 0

• MONO
- Efficiency
— 	 	 	 	
	 	 -^
"~ 	 -"-_
-- _




••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••c*
an no/
yu.u /o
an no/
7n no/.
>
en n°/, o
0)
|o
en no/ Uj
i«
0)
•c
c
Q
on no/
on no/
10 0%
n no/.
25-May 26-May 27-May 28-May
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 16 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
qn n
sn n
?n n
fin n
en n
4n n
on n
on n
10 0

• MONO
- Efficiency
~ .. - -----
_ —







qn n%
an no/
7r\ n%
fin n%
Kn no/
4n n%
on n%
on n%
1 0 0%

.0 H 	 	 	 1 	 •- u.ir/o
29-May 30-May
Denuder Efficiency
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 16 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
on n
an n
yn n
en n
Kn n
4n n
on n
on n
100

• MONO
- Efficiency

_ ( •
-







on noA
an no/
7D n%
en noA o
0)
|o
Kn no/ JS
i»
0)
•c
AH n°A ni
Q
on noA
on no/
1 0 0%

0.0 -I 	 1 	 L U.U7o
29-May 30-May
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 16 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
on n
on n
10 0
n n
• MONO
- Efficiency






-
_ - _ - -
^


qn noA
an no/
7D n%
en noA o
0)
|o
en no/ jS
i»
0)
•c
AH n°A ni
Q
on noA
on no/
1 0 0%
n no/.
29-May 30-May
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 16 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
on n
an n
yn n
en n
Kn n
4n n
on n
on n
10 0


-____ ~ ~ .. ~ .
- -
• MONO
— Efficiency







on noA
an no/
yn no/
en noA o
0)
|o
Kn no/ JS
i»
0)
•c
AC\ nOA fi«
Q
on no/
on no/
1 0 0%

0.0 -I 	 1 	 L U.U7o
29-May 30-May
                Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 5

                           Experiment 16 (Low Humidity, Low MONO Concentration)
   100.0
   90.0
   80.0
   70 0


f
Q.

•f 60.0

o
5
£
0)
o

o
o

O
z
O
I
50.0
 D.O
   30.0
   20.0
    10.0
    0.0
     29-May
                                                          30-May
                                                                                          100.0%
                                                                                          90.0%
                                                                                          80.0%
                                                                                          70.C
                                                                                          60.0%
50.0%
 J.0%
                                                                                          30.0%
                                                                                          20.0%
                                                                                          10.0%
                                                                                          0.0%
>
o

0)
'o


s
L.
0)
•c

C
0)
a
                                              Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 1

                           Experiment 17 (Low Humidity, Low MONO Concentration)
   100.0
   90.0
   80.0
   70 0


f
Q.


•f 60.0

o
5

£
0)
o

o
o

O
z
O
I
50.0
 D.O
   30.0
   20.0
    10.0
    0.0
                                                                                 MONO

                                                                                 Efficiency
                                                                                          100.0%
                                                                                          95.0%
                                                                                          90.C
                                                                                          85.0%
                                                                                           D.0%
                     5.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
                                                                                           J.0%
                                                                                          55.0%
     30-May
                                   31 -May
1-Jun
                                              Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 17 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
on n
an n
yn n
en n
Kn n
4n n
on n
on n
100

• MONO
- Efficiency

~--~-___-
-__~_-~_ __







on noA
an no/
yn no/
en noA o
0)
|o
Kn no/ JS
i»
0)
•c
AC\ nOA fi«
Q
on no/
on no/
- 1 0 0%

0.0 -I 	 1 	 1 	 L U.U7o
30-May 31 -May 1-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 17 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
on n
on n
zu.u
100
n n
• MONO
- Efficiency







-_ -^ 	


qn noA
an no/
yn r\%.
en noA o
0)
|o
en no/ jS
i»
0)
•c
AH n% ni
Q
on noA
on no/
ZU.U /o
1 0 0%
n no/.
30-May 31 -May 1-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 17 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
qn n
an n
7n n
en n
en n
4n n
on n
on n
100


_- ---__
-
~-~_- _ _ •HOMO
~~~_ _~_ — Efficiency
~-
-





qn noA
an no/
yn no/
en noA o
0)
'o
Kn no/ JS
i»
0)
•c
AC\ nOA fi«
Q
on no/
on no/
- 1 0 0%

0.0 -I 	 - — 	 , 	 , 	 L 0.0%
30-May 31 -May 1-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 5
Experiment 17 (Low Humidity, Low MONO Concentration)
MONO Concentration (ppbV)
on n
an n
7n n
en n
en n
4n n
on n
on n
100


~_-~~-~--__
_--~_-_~~_

• MONO
- Efficiency




•
on noA
an no/
yn no/
en no/.
en noA
4n n%
on noA
on no/
- 1 0 0%

0.0 -I 	 1 	 1 	 L U.U7o
30-May 31 -May 1-Jun
Denuder Efficiency
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 18 (Low Humidity, Low PAN Concentration)
AC. n
40 n
oc n
f
Q.
Q. on n
c
.0
?
re
i PR n
0)
o
Oon n
z
<
Q.
•i c n
-inn
1 U.U
c n
On
• PAN
- Efficiency
—
_ - -
-



'••'•-.• 	 	 .
•
•

qn r\%.
an no/
7r\ n%
en n%
Kn no/
4n n%
on noA
on no/
ZU.Uvo
m n%
n no/.
18-Jun 19-Jun
Denuder Efficiency
               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 18 (Low Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
-\ c n
m n
c n
n n
• PAN
- Efficiency

-
—
-



• • • •
• s

. •
• •
on n%
on 0%
TO n%.
fin n% o
0)
|o
^n n% LU
k.
0)
•o
40 0%. fli
Q
30 0%
on no/
m n%
n no/.
18-Jun 19-Jun
               Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 18 (Low Humidity, Low PAN Concentration)
AC n
4n n
oc n
f
Q.
Q. on n
c
.0
?
re
i PR n
0)
o
Oon n
z
<
Q.
•i c n
m n
c n
n n
• PAN
- Efficiency



-
_ -
—
^
• • • _
' .
• . • ••....
. . • •
• •..•.'

AC (\OL
4n n%
•2C no/
on no/ o
0)
|o
OK n% UJ
i»
0)
•c
on noA S
Q
1 ^ n%
1 n n%
c noA
n no/.
18-Jun 19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 18 (Low Humidity, Low PAN Concentration)
AC n
4n n
oc n
f
Q.
Q. on n
c
.0
?
re
i PR n
0)
o
Oon n
z
<
Q.
•i c n
m n
c n
n n



• PAN
- Efficiency
- - _ _
-
_

."••*'•••...
• • •


AC (\OL
4D 0%
•2C no/
on no/ o
0)
|o
OK n% UJ
i»
0)
•c
on noA S
Q
1 ^ n%
1 n n%
c noA
n no/.
18-Jun 19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 18 (Low Humidity, Low PAN Concentration)
AC n
4n n
oc n
f
Q.
Q. on n
c
.0
?
re
i oc n
0)
o
Oon n
z
<
Q.
•i c n
m n
c n
n n



-
- »PAN
_ - Efficiency
^

••••..
••••.. •
. • • •
• • • •
•'•••..

AC (\OL
4D 0%
•2C noA
on no/ o
0)
|o
oc no/ m
i»
0)
•c
on noA S
Q
1 ^ n%
1 n n%
c noA
n no/.
18-Jun 19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 19 (High Humidity, Low PAN Concentration)
AC. n
Ar\ n
oc n
f
Q.
Q. on n
c
.0
ID
i OK n
c ^'U

en n% o
0)
|o
en no/ jS
i»
0)
•c
AH n% ni
Q
30 0%

m n%
n no/.
19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 19 (High Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. *?n n
^5 OU.U
c
.0
ID
i OK n
c ^'U
a)
o
Oon n
Q.
-\ c n
m n
c n
n n
• PAN
- Efficiency


-
- _





• •••••••
on noA
an no/
7n n°A
en no/ o
OU.U/o g
0)
|o
en no/ jS
i»
0)
•c
AH n°A ni
Q
30 0%
on no/
m n%
n no/.
19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 19 (High Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
-\ c n
m n
c n
n n
• PAN
- Efficiency







— _ —
-
'•
on noA
an no/
7n n%
en noA o
0)
|o
Kn no/ JS
i»
0)
•c
c
a
30 0%
on no/n
m n%
n no/_
19-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 2
Experiment 19 (High Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
-\ c n
m n
c n
n n



• PAN
- Efficiency




- -

••
on no/,
«0 0%
TO n%.
en no/, o
0)
|o
^n n% LU
k.
0)
•o
40 0%. fli
Q
30 0%
on no/
m n%
n no/.
19-Jun 20-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 19 (High Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
•£ 25-°
0)
o
Oon n
Q.
-\ c n
m n
c n
n n




• PAN
- Efficiency


_
_
*•
on noA
an no/
7n n%
fin n% o
a>
'o
£
cn no/, UJ
k.
0)
•D
40 0%. fli
Q
30 0%
on no/
m n%
n no/.
19-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 1
Experiment 20 (High Humidity, High PAN Concentration)
PAN Concentration (ppbV)
qn n
sn n
7n n
en n
en n
4n n
on n
on n
m n
On
• PAN
- Efficiency
-
-
-



• •
•
••••••.-.
•
• •••••••••••
qn n%
sn n%
7n n%
fin n%
en no/
4n n%
on n%
on n%
•in n%
n no/.
21-Jun
Denuder Efficiency
                 Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 4
Experiment 20 (High Humidity, High PAN Concentration)
PAN Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
on n
on n
m n
n n
• PAN
- Efficiency

-
-




* * * •
• • 9
, •
qn noA
an no/
7D n%
en noA o
0)
|o
en no/ jS
i»
0)
•c
AH n°A ni
Q
on noA
on no/
m n%
n no/.
21-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 3
Experiment 20 (High Humidity, High PAN Concentration)
PAN Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
on n
on n
m n
n n
• PAN
- Efficiency






_ ~
' • •
• •• . ••.*.
•*••.••*

qn noA
an no/
yn r\%.
en noA o
0)
'o
en no/ jS
i»
0)
•c
AH n°A ni
Q
on noA
on no/
m n%
n no/.
21-Jun
                Date (2001)

-------
     EPA Denuder Efficiency Evaluation Denuder 2
Experiment 20 (High Humidity, High PAN Concentration)
PAN Concentration (ppbV)
qn n
an n
yn n
en n
en n
4n n
on n
on n
m n
n n



• PAN
— Efficiency



~ ~ —
• • .
• * .
• ••••••
••-.......

qn noA
an no/
yn r\%.
en noA o
0)
|o
en no/ jS
i»
0)
•c
AC\ nOA fi«
Q
on noA
on no/
m n%
n no/.
21-Jun
                Date (2001)

-------
   100.0
    90.0
    80.0
    70.0


|

S  60.0
c
o
5

£
0)
o

o
o

z
<
Q.
50.0
 D.O
    30.0
   20.0
    10.0
    0.0
                                 EPA Denuder Efficiency Evaluation Denuder 5

                            Experiment 20 (High Humidity, High PAN Concentration)
                                                                                            100.0%
                                                                                           90.0%
                                                                                           80.0%
                                                                                           70.C
                                                                                           60.0%
50.0%
                                                                                           30.0%
                                                                                           20.0%
                                                                                             J.0%
                                                                                           0.0%
>
o

0)
'o


s
L.
0)
•c

c
0)
a
     21-Jun
                                              Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 1
Experiment 21 (Low Humidity, High PAN Concentration)
PAN Concentration (ppbV)
qn n
an n
7n n
en n
en n
4D n
on n
on n
10 0
n n


• PAN
- Efficiency



— — _ ~ _

*•.'.'.'••• 	 	

qn no/
an no/
7n no/.
en noA o
0)
'o
en no/ jS
i»
0)
•c
AH n% ni
Q
on noA
on no/
1 0 0%
n no/.
22-Jun 23-Jun 23-Jun
Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 4
Experiment 21 (Low Humidity, High PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
-\ c n
•inn
I U.U
c n
n n
• PAN
- Efficiency





• - _ _
,
V
• • s



Qn n%
on 0%
TO 0%.
>
en n°/* O
0)
|o
^n n% LU
k.
0)
•D
40 0%. m
Q
on (]%.
on no/
ZU.U /o
•\ n noA
n no/.
22-Jun
                Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 3
Experiment 21 (Low Humidity, High PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
-\ c n
m n
c n
n n
• PAN
- Efficiency





•B
' •
*""•••'.•...

_ -
on noA
an no/
7n n°A
fin n% o
0)
|o
en no/ H]
i»
0)
•c
An n% ni
Q
30 0%
on no/
m n%
n no/.
22-Jun
                Date (2001)

-------
                                 EPA Denuder Efficiency Evaluation Denuder 2

                            Experiment 21 (Low Humidity, High PAN Concentration)
   50.0
   40.0
S 30.0
c
.0
?
0)
o


O  20.0
   10.0
   0.0

    22-Jun
                                                                            • PAN

                                                                            - Efficiency
                                                                                            -- 90.0%
80.0%
                                                                                            -- 70.0%
60.0%
100.0%
       a>
50.0%  UJ

       0)

       3

40.0%  S
       Q
                                                                                            -- 30.0%
20.0%
                                                                                            -- 10.0%
0.0%
                                             Date (2001)

-------
    EPA Denuder Efficiency Evaluation Denuder 5
Experiment 21 (Low Humidity, Low PAN Concentration)
AC n
40 0
oc n
f
Q.
Q. on n
C
.0
ID
i OK n
c ^'U
0)
o
Oon n
Q.
•\ K n
m n
c n
n n
• PAN
- Efficiency







" " "* ' % * » * % 1 t . • -
» • *
-" --- _ _ ~
on no/,
on 0%
70 C\°/n
>
en n°/^ O
0)
|o
^n n% LU
k.
0)
•D
40 0%. m
Q
on no/.
on no/
m n%
n no/.
22-Jun
               Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 22: Low Humidity NO2 Test for Filter 1
NO2 Concentration (ppbV)
qn n
an n
7n n
en n
en n

on n
on n
m n
n n


• N02
- Efficiency




.... • •
"* *••*••••*•• •
~ ~ — ~ — ~ ™ ~ « — —

qn noA
an no/
7n no/.
en noA »_
o
c
0)
'o
en noA c
LU
i»
0)
H
4n n% iZ
on noA
on no/
m n%
n no/.
23-Jun 24-Jun 24-Jun
Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 22: Low Humidity NO2 Test for Filter 4
NO2 Concentration (ppbV)
Qn n
on n _
70 0
fin n
c.r\ n _
40 0
on n
on n _
-inn
n n
• NO2
- Efficiency










— ~~ _ _ ~ — ~ ~ — ~ —
qn noA
an no/
yn r\%.
fin n% -^
o
c
0)
'o
en noA c
LU
i»
0)
£
4n n% iZ
on noA
on no/
m n%
n no/.
23-Jun 24-Jun 24-Jun
Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 22: Low Humidity NO2 Test for Filter 3
NO2 Concentration (ppbV)
on n
on n
70 0
en n
c.r\ n -
40 0
^n n
on n
-inn
n n
• N02
- Efficiency





•
•*••*•• .

"•• • • • , ••••

• •™ ™ ~ ™ ™ ~

on no/.
on n%

fin n%
en n%
4n n%
^n n%
on n%
1 n n%
n no/.
23-Jun 24-Jun 24-Jun
Date (2001)
Filter Efficiency

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 22: Low Humidity NO2 Test for Filter 2
NO2 Concentration (ppbV)
Qn n
on n
70 0
fin n

4n n
30 0
on n
-inn
n n

• NO2
- Efficiency




."•'•••

----- - _ ~ - - - _ - - -

qn r\%.
on r\OL
?n n%
Rn n%
en n%
4n n%
on n%
on n%
•in n%
n no/.
23-Jun 24-Jun 24-Jun
Date (2001)
Filter Efficiency

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 22: Low Humidity NO2 Test for Filter 5
NO2 Concentration (ppbV)
Qn n
an n
70 0
en n
c.r\ n -
40 0
on n
on n
-inn
n n

• NO2
- Efficiency








•»••**%***%%

\ + *

>

~ ~ - - - -___-_-___
23-Jun 24-Jun
Date (2001)

Qn
on

en
c:n
4n
on
on
-in
n r
24-Jun
0%
0%
0%
0%
0%
0%
0%
0%
0%
o/
Denuder Efficiency

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 23: High Humidity NO2 Test for Filter 1
NO2 Concentration (ppbV)
qn n
an n
7n n
en n
en n

on n
on n
m n
n n


• N02
- Efficiency



• • •





qn noA
an no/
7n no/.
en noA »_
o
c
0)
'o
en noA 'f
LU
i»
0)
£
4n n% iZ
on noA
on no/
m n%
n no/.
24-Jun 25-Jun 25-Jun
Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 23: High Humidity NO2 Test for Filter 4
NO2 Concentration (ppbV)
Qn n
an n
70 0
fin n
c.r\ n -
40 0

on n
-inn
n n
• NO2
- Efficiency







^•••••••« «. i % I •
• •••••••>%%«••


- _ -
qn noA
an no/
yn noA
en noA »_
o
c
0)
'o
en noA c
LU
i_
0)
£
4n n% iZ
on no/.
on no/
m n%
n no/.
24-Jun 25-Jun 25-Jun
Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 23: High Humidity NO2 Test for Filter 3
NO2 Concentration (ppbV)
on n
on n
70 0
en n
c.r\ n -
40 0

on n
-inn
n n
• N02
- Efficiency





.
	 »%•.%••.:••.•••**• '•

-~-~~_---- _- -~--~--__
on no/.
on n%
7n n%
fin n%
en n%
4n n%
on n%
on n%
1 n n%
n no/.
24-Jun 25-Jun 25-Jun
Date (2001)
Filter Efficiency

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 23: High Humidity NO2 Test for Filter 2
NO2 Concentration (ppbV)
Qn n
on n
70 0
fin n

40 0
on n
OU.U
on n
1 n n
n n

• NO2
- Efficiency




•
	 •.•*.•••••••••


qn r\%.
on r\OL
?n n%
Rn n%
en n%
4n n%
on no/
oU.Uvo
on n%
1 n no/.
n no/.
24-Jun 25-Jun 25-Jun
Date (2001)
Filter Efficiency

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 23: High Humidity NO2 Test for Filter 5
HNO3 Concentration (ppbV)
Qn n
an n
70 0
fin n
c.r\ n -
40 0

on n
-inn
n n
• NO2
- Efficiency









- - - ~ -_- ~- ~ ~ - --------
qn noA
an no/
yn r\%.
en noA o
0)
|o
en no/ jS
i»
0)
•c
Af\ HO/. fi«
Q
on no/.
on no/
m n%
n no/.
24-Jun 25-Jun 25-Jun
Date (2001)

-------
  EPA Denuder Efficiency Evaluation Filter Section
Experiment 24: High Humidity HONO Test for Filter 1
MONO Concentration (ppbV)
qn n
on n
7n n
fin n
en n
4n n
on n
20 0
m n
n n

-

• MONO
- Efficiency
- ~ - ~
.

•
""•.•"'• •
• • * *
**•• • „ •••••
	 ••::.*

on ncv
en r\Q/
Ar\ r\Q/n
on no/.
On%
_on no/.
40 0%
-60 0%
80 0%
-i nn no/_
26-Jun 27-Jun 27-Jun
Date (2001)
Filter Efficiency

-------
  EPA Denuder Efficiency Evaluation Filter Section
Experiment 24: High Humidity HONO Test for Filter 4
MONO Concentration (ppbV)
qn n
an n
?n n
fin n
en n
4n n
on n
on n
10.0
n n
• MONO
- Efficiency

----- ~~ ----- ~ ~ -




m
....
	 • — * — 	 	

on n%
fin n%
4n n%
on n%
n n%
on r\%.
4n n%
-fin n%
- -80.0%
i nn no/.
26-Jun 27-Jun 27-Jun
Date (2001)
Filter Efficiency

-------
  EPA Denuder Efficiency Evaluation Filter Section
Experiment 24: High Humidity HONO Test for Filter 3
MONO Concentration (ppbV)
on n
on n
70 0
en n
c.r\ n -
40 0
^n n
on n
-inn
1U.U
n n
• MONO
- Efficiency

~ - - - - _



•
• •
•
.
•
* • • • • •

on no/.
Rn n%
4n n%
on n%
n n%
on n%
-4n n%
Rn n%
on no/
-oU.Uvo
•i nn no/
26-Jun 27-Jun 27-Jun
Date (2001)
Filter Efficiency

-------
  EPA Denuder Efficiency Evaluation Filter Section
Experiment 24: High Humidity HONO Test for Filter 2
MONO Concentration (ppbV)
an n
on n
?n n
en n
en n
4n n
on n
on n
•in n
n n

• MONO
- Efficiency
-
— _
•

•
• •
•
' * . . ' * • . • • . '
' ' ' • . .-.
' ' • •*...•

so n%
fin n%
4n n%
on n%
On%
.on n%
4n n%
fin n%
on n%
•i nn no/.
26-Jun 27-Jun 27-Jun
Date (2001)
Filter Efficiency

-------
  EPA Denuder Efficiency Evaluation Filter Section
Experiment 24: High Humidity HONO Test for Filter 5
MONO Concentration (ppbV)
qn n
an n
7n n
en n
en n
4D n
on n
on n
m n
n n
• MONO
- Efficiency


- -
- -



•



qn no/
an no/
7n no/.
en noA o
a>
|o
en no/ jS
i»
0)
•c
AC\ nOA fi«
Q
on noA
on no/
m n%
n no/.
26-Jun 27-Jun 27-Jun
Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 25: Low Humidity MONO Test for Filter 1
MONO Concentration (ppbV)
an n
on n
7n n
en n
en n
4n n
on n
on n
•in n
n n



• MONO
- Efficiency

^ ^

• • • •
:••••• 	 •...:•
• ••*...•.. • •. •
•

so n%
en n%
AD n%
on n%
On%
.on no/.
4n n%
en n%
on n%
•i nn no/.
27-Jun 28-Jun
Filter Efficiency
               Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 25: Low Humidity MONO Test for Filter 4
MONO Concentration (ppbV)

90.0
an n
?n n
fin n
en n
4n n
on n
on n
m n
n n
• MONO
- Efficiency





•
* . . ' •





- 80.0%
fin n%
4n n%
on n%
n n%
on n%
4n n%
-fin n%
sn n%
•i nn no/.
27-Jun 28-Jun
Filter Efficiency
              Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 25: Low Humidity MONO Test for Filter 3
MONO Concentration (ppbV)
on n
on n
7n n
en n
en n
4n n
•in n
on n
m n
n n
• MONO
- Efficiency


" ---.___-


• •
• •
••••••••-..
• .
• ' • ....'•. ' • .

on no/.
Rn n%
4n n%
on n%
n n%
on r\%.
-4n n%
Rn n%
.an no/
•i nn no/.
27-Jun 28-Jun
Filter Efficiency
               Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 25: Low Humidity MONO Test for Filter 2
MONO Concentration (ppbV)
an n
on n
7n n
en n
en n
4n n
on n
on n
•in n
n n

• MONO
- Efficiency


- _ _ -


' • ' ' .
. ' '
• • • • • •



so n%
en n%
4n n%
on n%
On%
.on n%
4n n%
en n%
on n%
•i nn no/.
27-Jun 28-Jun
Filter Efficiency
              Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 25: Low Humidity MONO Test for Filter 5
MONO Concentration (ppbV)
qn n
an n
7n n
en n
en n
4n n
on n
on n
m n
n n
• MONO
- Efficiency

- ~ _ _ ~~----~-_~
-



.
• •
* . *



qn noA
an no/
yn no/
en (")OA o
0)
|o
Kn no/ JS
i»
0)
•c
AH n% ni
Q
on noA
on no/
m n%
n no/.
27-Jun 28-Jun
               Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 26: Low Humidity PAN Test for Filter 1
18.0
16.0
14.0
£1
a.
S 12.0
c
o
re
| 10.0
0)
o
c
O 8.0
1
6.0
4.0
2.0
0.0
28-



• PAN
- Efficiency

•
• \

• •
• «
' * * *" ' '• '. %


— — ~ _
Jun 29-Jun
- 90.0%
- 80.0%
- 70.0%
- 60.0%

- 50.0%
- 40.0%
- 20.0%
- 10.0%
- 0.0%

>
o
f

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 26: Low Humidity PAN Test for Filter 4
-ion
1R n
14. n
f
Q.
Q. -ion
c
.0
?
re
i inn
0)
o
OR n
z
<
Q.
6n
4 n
9 n
n n
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qn n%
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28-Jun 29-Jun
Filter Efficiency
              Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 26: Low Humidity PAN Test for Filter 3
MONO Concentration (ppbV)
on n
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- Efficiency









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28-Jun 29-Jun
Filter Efficiency
              Date (2001)

-------
 EPA Denuder Efficiency Evaluation Filter Section
Experiment 26: Low Humidity PAN Test for Filter 2
18.0
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Jun 29-Jun
- 90.0%
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-------
EPA Denuder Efficiency Evaluation Filter Section
Experiment 26: Low Humidity Pan Test for Filter 5
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28-Jun 29-Jun
             Date (2001)

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     29-Jun
                                EPA Denuder Efficiency Evaluation Filter Section

                                Experiment 27: High Humidity Pan Test for Filter 1
%   •
                                                     30-Jun

                                               Date (2001)
                                                                                                 100.0%
                                                                                                80.0%
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                                                                                                20.0%
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-------
                               EPA Denuder Efficiency Evaluation Filter Section

                              Experiment 27: High Humidity Pan Test for Filter 4
   18.0
   15.0
   12.0
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     29-Jun
%   «
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                                                                                                -20.0%
                                              Date (2001)

-------
   18.0
                                EPA Denuder Efficiency Evaluation Filter Section

                                Experiment 27: High Humidity Pan Test for Filter 2
                                                                                              -- 90.0%
   15.0
5- 12.0
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     29-Jun
0.0%
                                               Date (2001)

-------
   18.0
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 •  12.0
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CL   6.0
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     29-Jun
                                 EPA Denuder Efficiency Evaluation Filter Section

                                Experiment 27: High Humidity Pan Test for Filter 5
                                                                               • PAN

                                                                               - Efficiency
•   %
        *.   •
                                               Date (2001)
                                                                                                 100.0%
                                                                                                 80.0%
                                                                                                 60.0%
                                                                                                 40.0%
                                                                                                        o

                                                                                                        a>
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                                                                                                        •c

                                                                                                        C
                                                                                                        0)
                                                                                                        a
                                                                                                 20.0%
                                                                                                 0.0%
                                                                                                 -20.0%

-------
United States                             Office of Air Quality Planning and Standards                       Publication No. EPA-454R-02-011
Environmental Protection                  Emissions Monitoring & Analysis Division                        April 2002
Agency                                  Research Triangle Park, NC

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