Case Study: U.S. Demonstration ^ of Ventilation Air Methane Oxidation Technology U.S. EPA Coalbed Methane JTBEACH PROGRAM JULY 2010 Project Overview Methane (CH4) released to the atmosphere from gassy underground coal mine ventilation systems constitutes a major source of greenhouse gas emissions. As concern over climate change grows worldwide, mitigating ventilation air methane (VAM) emissions is drawing increasing attention. Field demonstrations of VAM oxidation technology have paved the way for the emergence of a new industry focused on capturing the energy embodied in VAM exhaust flows and putting it to beneficial use. The first such demonstration in North America was carried out by CONSOL Energy1, using a MEGTEC Systems2 single-bed VOCSIDIZER™ (commercial-sized units are twin-bed). Project Specifications Name: VAM Oxidation Demonstration project Site: Windsor Mine, West Liberty, West Virginia Host: CONSOL Energy Funding Agencies: USDOE and USEPA Dates of Operation: Feb. 2007 - Oct. 2008 Equipment: MEGTEC Systems VOCSIDIZER™ Efficiency: >95% End Use: Abatement only Emission Reduction: 14,849 tonnes CO2e CONSOL conducted the project at their abandoned Windsor coal mine to (1) demonstrate that the oxidizer can reliably convert very low concentrations of methane present in mine ventilation exhaust air to carbon dioxide and water and (2) determine CONSOL Energy is the largest producer of high-Btu coal in the United States, with 17 bituminous coal mines in six states. CONSOL is a recognized pioneer in the production and use of coal mine methane and they provided the host site and extensive engineering support for the VAM demonstration project. the quantity of useful energy that can be produced by the oxidation reaction. Given that the project was conducted at an abandoned mine, drained methane from the closed workings was diluted to simulate typical VAM concentrations. VAM Oxidation Project Site (Photo courtesy: CONSOL Energy) Technology Design Electric heating elements are used to preheat ceramic heat transfer material in the VOCSIDIZER's™ core up to or above the oxidation temperature of methane (1,000°C or 1,832°F), at which point the preheating system is turned off and VAM inflow is initiated. As a safety feature, methane cannot enter the oxidizer unless the electric preheaters are turned off. Ducting conveys the (simulated) ventilation exhaust flow into the oxidizer core where it encounters the preheated heat exchange material (ceramic pieces with a high surface area to volume ratio) and oxidizes the methane, releasing heat, water, and carbon dioxide. This heat is transferred to the bed, thereby maintaining its temperature at or above the temperature MEGTEC Systems manufactures oxidizers for industrial air pollutant emission control. They adapted their technology to abate VAM emissions at gassy underground coal mines. Their VAM oxidation system (VOCSIDIZER™) has been operating successfully in the field, including at the largest commercial-scale VAM-to-power project in the world (West Cliff mine in Australia). ------- necessary to support auto-thermal operation. To preclude cooling of the bed, dampers and valves redirect the flow of incoming ventilation exhaust air from one side of the bed to the other, typically on a timeframe of every two or three minutes. This flow-reversal process, which is managed by a programmable logic controller, maintains the hot area of the bed in the middle of the oxidizer, where it is available to support oxidation of a constant stream of VAM overtime. It should be noted that the oxidation process is flameless and, following the initial bed preheating, requires no auxiliary fuel so long as adequate inflow methane concentrations are maintained. Project Operation The project commenced processing methane on February 11, 2007 and all components were found to perform as required, with the exception of the air compressor and two methane sensors - one for mine gas and one for the simulated VAM entering the oxidizer. Both had an unacceptably long response time and the VAM sensor showed an inaccurate reading. Therefore, the methane analyzers (both mine gas and VAM inflow) and the compressor were replaced. Initially the system was run under six different combinations of methane concentration and airflow to test the effect of changes in each on bed temperature, methane conversion, and bed pressure drop. Following those parametric tests, the system operated at a constant methane concentration of 0.6 percent and inlet airflow of 30,000 scfm. From May through November of 2007, the system ran unattended for a total of 1,301 hours, with availability in one month reaching nearly 60 percent. During this period, some shutdowns were experienced due to equipment problems and operational problems. The system's remote unattended location meant that longer shutdown-response times were incurred than would have been the case at an active mine with on-site maintenance staff available. Following a bed rebuild, the system ran unattended for a total of 2,833 hours from May through October of 2008, reflecting an improved availability of 64 percent overall and a peak of almost 95 percent in one month, thus evidencing substantially improved performance as compared with the initial operational period. Overall during the project, the performance of the oxidizer bed itself was as expected. Inlet temperatures were essentially steady and outlet temperatures fluctuated with the actuation of the flow reversal valves. CONSOL characterizes the overall operation of the bed as being "very stable" and evidenced a methane destruction efficiency of better than 95 percent. The system operated safely and all mechanical and logical safeties performed as designed. CONSOL estimates that a commercial-scale system at one of their mines could produce enough energy to generate 3.3 to 8.2 MW of electricity (or 11 to 27 MW of thermal power). To improve long-term system availability, MEGTEC is investigating other, better- performing ceramic media that may be employed in place of that used in the demonstration. Taking all of their experience with this demonstration project into account, CONSOL hopes to move the unit to an active mine and is optimistic that availability can ultimately be increased to 97 percent. For further information, contact: Dr. Jayne Somers, Program Manager Coalbed Methane Outreach Program U.S. Environmental Protection Agency Washington, DC USA E-mail: somers.iavne@epa.gov Website: http://www.epa.gov/coalbed www.epa.gov/cmop ------- |