PRODUCT AND PRODUCT GROUP DISCHARGES
SUBJECT TO EFFLUENT LIMITATIONS AND STANDARDS
for the
ORGANIC CHEMICALS, PLASTICS, AND SYNTHETIC FIBERS
POINT SOURCE CATEGORY - 40 CFR 414
April 2005
Office of Water
U.S. Environmental Protection Agency
1200 Pennsylvania Ave., N.W.
Washington, D.C. 20460
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Table of Contents
Section Page
Introduction 1
1 Summary of the 40 CFR 414 2
1.1 Regulated Parameters 3
1.2 Requirements for Direct and Indirect Dischargers 3
2. Identifying and Classifying Products Whose Production May be Subject to the OCPSF
Regulation 5
2.1 The SIC Manual and Codes 5
2.2 Industrial Categories Applicable to Chemicals and Allied Products 6
2.3 Part 414 Applicability to Production of Chemicals and Chemical Products 6
2.4 Applicability of Wastewater from On-Site Auxiliary Operations 8
2.5 General Discussion of OCPSF-Related Products Whose Manufacture May Not
Be Regulated by Part 414 8
2.5.1 Products Classified and Previously Reported under Specific SIC
Codes That Are Not Subject to Part 414 8
2.5.2 Products Listed in Part 414 That Are Regulated by Another Industrial
Category Are Not Subject to Part 414 in Certain Circumstances 10
2.5.2.1 Organic Chemicals Regulated by the Iron and Steel Category
(40 CFR 420) 10
2.5.2.2 Organic Chemicals Regulated by the Pesticides Chemicals
Category (40 CFR 455) 11
2.5.2.3 Organic Chemicals Regulated by the Pharmaceutical Category. 11
2.5.2.4 Products Regulated by the Plastics Molding & Forming
Category (40 CFR 463) 12
2.5.2.5 Organic Chemicals Regulated by the Soap and Detergent
Category (40 CFR 417) 12
2.5.3 Organic Chemical Manufacturing Processes Not Subject to Part 414. . . 13
2.6 Synthetic Fibers 13
3. Identifying and Classifying Products Subject to Part 414 at a Plant 15
4. An example to Demonstrate the Use of Tables 2-5 to 2-8 and the Appendix 17
OCPSF products classified under:
SYNTHETIC FIBERS (Subparts B, C) 18
PLASTICS (Subparts D, E) 20
ORGANIC CHEMICALS (Subparts F, G) 29
APPENDIX - Combined List of Organic Chemical Products Applicable to Subparts F, G, and H
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Index of Tables
Table Description Page
1-1 Summary of 40 CFR part 414 4
2-1 Industrial Categories that May Apply to the Production of Certain Chemicals and
Allied Products 6
2-2 Applicability of Subparts of 40 CFR 414 to Manufacture of Products and Product
Groups 7
2-3 SIC Codes and Product Groups Specified as Not Subject to Part 424 9
2-4 Synthetic Fiber Definitions 13
2-5 Combined List of Synthetic Fibers 18
2-6 Combined List of Plastics 21
2-7 Commodity Organic Chemicals - Subpart F 29
2-8 Bulk Organic Chemicals - Subpart G 30
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DISCLAIMER
The discussion in this document is intended solely as guidance. The statutory provisions
and regulations of the U.S. Environmental Protection Agency (EPA) described in this document
contain legally binding requirements. This document is not a regulation itself, nor does it change
or substitute for those provisions and regulations. Thus, it does not impose legally binding
requirements on EPA, States or the regulated community. This guidance does not confer legal
rights or impose legal obligations upon any member of the public.
While EPA has made every effort to ensure the accuracy of the discussion in this
guidance, the obligations of the regulated community are determined by statutes, regulations or
other legally binding requirements. In the event of a conflict between the discussion in this
document and any statute or regulation, this document would not be controlling.
The general descriptions provided here may not apply to particular situations based upon
the circumstances. Interested parties are free to raise questions and objections about the
substance of this guidance and the appropriateness of the application of this guidance to a
particular situation. EPA and other decision-makers retain the discretion to adopt approaches on
a case-by-case basis that differ from those described in this guidance where appropriate.
Mention of trade names or commercial products does not constitute an endorsement or
recommendation for their use.
This document may be revised periodically without public notice. EPA welcomes public
input on this document at any time.
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Introduction
Rules of the U.S. Environmental Protection Agency regulate discharges from the
production of organic chemicals, plastics and synthetic fibers. Under the Clean Water Act, EPA
has promulgated effluent limitations and pretreatment standards controlling these discharges.
These regulations are codified in the Code of Federal Register at 40 CFR Subchapter N. EPA
has established limitations and standards in a number of different industry classes and categories
that address production of organic chemicals. These include the Soap and Detergent
Manufacturing Point Source Category (40 CFR Part 417), Petroleum Refining Point Source
Category (40 CFR Part 419), the Iron and Steel Point Source Category (40 CFR Part 420), the
Pharmaceutical Manufacturing Point Source Category (40 CFR Part 439), the Pesticide
Chemicals Point Source Category (40 CFR Part 455) and the Plastics Moulding and Forming
Point Source Category (40 CFR Part 463). EPA has also promulgated regulations specific to the
production of organic chemicals, plastics and synthetic fibers. These regulations for the Organic
Chemicals, Plastics and Synthetic Fibers Point Source Category are codified at 40 CFR Part 414.
The Part 414 regulations apply to discharges from the manufacture of certain organic
chemical products by manufacturers who report data to the U.S. Department of Commerce for
their facilities under the specific Federal classification codes that are identified in the Part 414
regulations. This document will aid the reader in determining whether the regulations in Part
414 apply to its discharges. It first explains how a facility determines whether Part 414 or one of
the other subchapter N regulations noted above applies to its operation. Next, it provides an
extensive list of products that may be subject to the Part 414 requirements.
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1. Summary of 40 CFR 414
This regulation (Title 40 of the Code of Federal Regulations, Part 414) establishes
restrictions on wastewater discharges from facilities manufacturing organic chemicals, plastics
and synthetic fibers (OCPSF). The Part 414 regulations are one of a number of regulations
codified at 40 CFR Subchapter N establishing effluent limitations, pretreatment standards, and
new source performance standards for classes and categories of industrial operations.
The OCPSF regulation applies to process wastewater discharges resulting from the
manufacture of seven products or product groups at facilities included within five specified U.S.
Department of Commerce Bureau of the Census Standard Industrial Classification system (SIC)
groups.1 The regulation, however, does not apply to discharges from the manufacture of those
seven products or product groups if included in six other SIC subgroups. Which process
wastewaters are subject to this regulation is explained in 40 CFR 414.11. This guidance
provides further explanation of how to determine whether or not a particular wastewater is
subject to the OCPSF regulation. In addition, the Appendix to this guidance provides additional
help in determining when the regulation applies with respect to the manufacture of organic
chemicals. EPA intends this guidance to assist EPA and Regional permitting authorities,
publicly owned treatment works (POTWs) and regulated industrial sources in interpreting and
implementing the OCPSF regulations.
The currently applicable regulations may be found in any edition of the Code of Federal
Regulations dated July, 1996 or later. Other documents that may be useful in understanding this
regulation are:
• Final Development Document for the OCPSF category, Volume II.
EPA# 440/1-87/009, October, 1987 (NTIS Accession No. PB88-171335).
This document gives a listing of OCPSF products applicable to Subpart H.
SIC codes are four digit numerical codes assigned by the U.S. government to business establishments to
identify the primary business of the establishment. The classification was developed to facilitate the collection,
presentation, and analysis of data; and to promote uniformity and comparability in the presentation of statistical data
collected by various agencies of the federal government, state agencies, and private organizations. The classification
covers all economic activities: agriculture, forestry, fishing, hunting, and trapping; mining; construction;
manufacturing; transportation; communications, electric, gas, and sanitary services; wholesale trade; retail trade;
finance, insurance, and real estate; personal, business, professional, repair, recreation, and other services; and public
administration.
The Office of Management and Budget published several editions of an official U.S. guide to the SIC codes
assigned to establishments by the Federal government, the Standard Industrial Classification Manual. Until 1997,
manufacturers reported data on their operations annually to the Census Bureau in the U. S. Department of Commerce
using SIC codes to identify their classification of industrial activity. Subsequently, in mid-1997, the Office of OMB
announced the establishment of a new economic classification system that replaced the 1987 Standard Industrial
Classification Manual with a revised classification system — the North American Industrial Classification System
(NAIC). NAIC was developed jointly by the U.S., Canada, and Mexico to provide new comparability in statistics
about business activity across North America. The NAIC codes assigned to chemical and allied products production
correspond in large part to the earlier SIC codes. See also discussion at page 3, infra.
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• Supplement to the Development Document for the OCPSF category.
EPA# 821/R-93-007, 1993 (NTIS Accession No. PB93-214336).
Among other things, this document describes the rationale for deleting phenol and 2,4-
dimethylphenol from the pollutants regulated under Subpart K.
The 2002 U.S. NAIC Manual, North American Industry Classification System - United
States, 2002., includes definitions for each industry, tables showing correspondence between
2002 NAIC and 1997 NAIC for codes that changed, and a comprehensive index is also available
on its web site. To order the 1400-page 2002 Manual, in print, call NTIS at (800) 553-6847 or
(703) 605-6000, or check the NTIS web site. The 1250-page, 1997Manual, showing
correspondence between 1997 NAIC and 1987 SIC, is also available. The 2002 and 1997
versions of NAIC are available on CD-ROMs, which can be ordered at NTIS.
Also available from the U.S. Bureau of Census on its website are lists of 2002 NAICS
codes (with links to definitions), 1997 NAIC codes, tables showing correspondence between the
1007 NAIC and SIC, tables showing correspondence between 1997 NAIC and 2002 NAIC, and
other files for downloading.
1.1 Regulated Parameters
The regulations at Part 414 establish effluent limitations for three conventional pollutants
— five-day biochemical oxygen demand (BOD5), total suspended solids (TSS) and pH in
Subparts B through H — for direct dischargers (point sources discharging directly to surface
waters) as well as limitations and pretreatment standards for certain toxic pollutants2 at Subpart I
through K for direct and indirect dischargers (point sources discharging to a POTW). The
limitations for direct dischargers differ depending on whether the discharger employs biological
treatment (Subpart I) or non-biological treatment (Subpart J) as its "end of process" treatment.
Indirect dischargers are subject to the pretreatment standards in Subpart K. It should be noted
that Subparts I, J, and K differ, not only with respect to the specific priority pollutants listed, but
in the numerical limits for a particular priority pollutant as well.
1.2 Requirements for Direct and Indirect Dischargers
Both new and existing direct dischargers manufacturing over 5 million pounds of
OCPSF products per year are subject to effluent limitations for BOD5, TSS, pH, and other
selected toxic priority pollutants. Direct dischargers that manufacture not more than 5 million
pounds of OCPSF products per year are subject only to effluent limitations for BOD5 and TSS
and pH, but are not subject to effluent limitations for toxic priority pollutants.
2 Section 414.10(c) defines priority pollutants as the "toxic pollutants" listed at 40 CFR 401.15. This is in
error. The "65 compounds and classes of compounds" listed at section 401.15 were given legal definition in the
1977 Amendments to the Clean Water Act (CWA). Since analysis of nebulous "classes of compounds" is
impractical, EPA specified 126 (originally 129) chemicals to provide analytically explicit examples of the "65
compounds and classes of compounds" and developed methods to analyze for the specified chemicals, which
became widely known by the collective term "priority pollutants." The pollutant parameters regulated in Part 414
are listed in the Appendix of 40 CFR 123.
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New and existing indirect dischargers must comply with the pretreatment standards in
Subpart K if they manufacture products or product groups specified in 40 CFR 414.11.
The categorical pretreatment standards at Subpart K do not restrict the discharge of the
conventional pollutants: BOD5, TSS, and pH.
Table 1-1 summarizes the requirements of the OCPSF regulation for both direct and
indirect dischargers.
Table 1-1. Summary of 40 CFR Part 414
Type of Discharger
Direct: Manufactures up to 5xl06 Ibs./yr of OCPSF products.
Direct: Manufactures over 5xl06 Ibs./yr of OCPSF products
and uses end-of-pipe, biological* treatment technology.
Direct: Manufactures over 5xl06 Ibs./yr of OCPSF products
and does not use end-of-pipe, biological* treatment
technology.
Indirect: Any production of OCPSF products.
Regulated
Parameters
BOD5 , TSS, pH
BOD5 , TSS, pH
T Priority pollutants
BOD5 , TSS, pH
'J' Priority pollutants
'K' Priority pollutants
Applicable
Subpart(s)
B through H
B through H
I
B through H
J
K
* The regulation does not define "end-of-pipe, biological treatment." Biological treatment technology employs
microorganisms to biochemically oxidize or degrade organic materials in wastewater. Non-biological treatment
technologies, often described as "physical-chemical treatment," do not employ microorganisms but remove materials
from wastewater by a physical process (e.g., steam stripping) or a chemical process (e.g., addition of a chemical
precipitant) process. Process wastewater in a plant manufacturing OCPSF products may be treated at the "end-of-
pipe," "in-plant," or a combination of both. End-of-pipe treatment refers to the application of a treatment technology
to process wastewater immediately before final discharge to receiving waters. In-plant treatment refers to the
application of a treatment technology to process wastewater prior to its flow to a facility's end-of-pipe treatment
system.
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2 Identifying and Classifying Products Whose Production May be Subject to the
OCPSF Regulation
EPA receives frequent questions from various permitting authorities and the regulated
community about how to determine which industrial category regulated by 40 CFR Subchapter
N applies to discharges associated with the manufacture of particular chemical products. In many
cases, the inquirer asks a two-part question.
(1) Regulations for which industrial category, if any, apply to the manufacture of my
product(s)? and
(2) If there are applicable regulations, what effluent limitations or pretreatment standards
apply to the manufacture of my product?
Part 414 is unique among EPA's effluent guidelines and standards regulation because it
defines the scope and applicability of the regulation in terms of both types of product and how
the manufacture of the product is classified in the U.S. Census Bureau Standard Industrial
Classification (SIC) codes.
2.1 The SIC Manual and Codes
The SIC Manual (and its successor NAIC Manual) associates SIC codes with a generic
description of a group of products of commerce. Typically, this is followed by a list of product
groups and individual products that are illustrative of "important products of this industry." The
first two digits of the code identify the major industry group, the third digit identifies the
industry group, and the fourth digit identifies the industry.
SIC codes were created to classify manufacturing activity for the collection of economic
data. For this reason, SIC codes are often technically ambiguous in classifying the products of
commerce. For example, a product marketed into different segments of the economy (end uses),
or associated with different types of manufacturing activity (industrial categories), may be
reported under more than one SIC code. Thus, SIC codes are useful for broadly classifying
products into an industrial category, but may not be entirely appropriate in all cases.
2.2 Industrial Categories Applicable to Chemicals and Allied Products
The SIC Manual classified chemicals and allied products under Major Group 28, which is
further broken down into industrial groups and subgroups of products. Wastewater discharges
associated with the manufacture of some of these product groups may be subject to regulation
under provisions of EPA's guidelines and standards regulations at 40 CFR Subchapter N. Table
2-1 summarizes industrial categories of chemicals and allied products that may be subject to
those regulations.
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Table 2-1. Industrial Categories that May Apply to the Production of Certain Chemicals
and Allied Products
SIC
Industrial
Group
281
282
283
284
285
286
287
289
Products
Industrial Inorganic Chemicals
Plastic Materials and Synthetic Resins
Synthetic Rubber
Cellulosic and Other Manmade Fibers
Drugs (Pharmaceuticals)
Soap, Detergents and Cleaning Preparations
Paints, Varnishes, Lacquers and Enamels
Paints, Varnishes, Lacquers and Enamels
Gum and Wood Chemicals
Agricultural Chemicals (Pesticides)
Miscellaneous Chemicals
SIC code(s)
Classification
2812,2819
2821
2822
2823, 2824
2833,2834
2843
2851
2865, 2869
2861,2899
2879
2899
Maybe
Subject to
40CFR
Part 415
Part 4 14
Part 428
Part 4 14
Part 439
Part 417
Part 446
Part 4 14
Part 454
Part 455
Part 4 14
2.3 Part 414 Applicability to Production of Chemicals and Chemical Products
As noted previously, Part 414's requirements apply only to discharges associated with the
manufacture of products and SIC codes specified at 40 CFR414.11. See also the discussion in
the preamble to the final regulations at 52 FR 42569 (Nov. 5, 1987) and its amendment at 58 FR
36893 (July 9, 1993). The SIC classification of a product should remain consistent with the SIC
code under which it has been historically reported.3
In determining what products and product groups should be subject to Part 414, EPA
relied on the following sources:
a.
b.
c.
Responses of plants to the 1983 Clean Water Act section 308 Questionnaire.
Domestic chemical production data.4
Products listed in the 1987 SIC Manual as representative examples of particular
SIC codes.
Part 414 applies to process wastewater discharges from facilities which:
1) Manufacture the organic chemicals, plastics and synthetic fibers (or generic
groups of these products) listed in Subparts B through H; and
Either to the Census Bureau, to EPA in a '308' Questionnaire, or in the application for the existing permit.
Published in magazines such as Chemical & Engineering News, Chemical Week, or in catalogs such as the
one published by Aldrich Chemical Co.
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2) Report their production, either previously under the following SIC codes,5 or
currently under the corresponding NAICS codes.6
SIC Codes and NAIC Codes Applicable to Part 414
Products
Organic chemicals
Plastics
Synthetic fibers
SIC Codes
2865, 2869, 2899*
2821
2823, 2824
NAICS Codes
325132,325192,325199
325211
325221, 325222
* Part 414 is not applicable to products that are reported under SIC 2899568 and SIC 2899597. EPA
did not subject discharges from those operations to Part 414. See Section 414. ll(c)(3)(i) and (ii).
Table 2-2 provides a summary of products and product groups whose production may be
subject to subparts of Part 414.
Table 2-2. Applicability of Subparts of 40 CFR 414 to Manufacture of Products and
Product Groups
Subpart
Manufactured Products
B
Applies only to cellulosic manmade fiber (Rayon) manufactured by the Viscose® process,
generally classified and reported under SIC 2823.
Applies to all other synthetic fibers (except Rayon) generally classified and reported under SIC
2823 or under SIC 2824. Section 414.30 includes a list of products subject to this subpart. The
products whose production may be subject to this subpart are not limited to the synthetic fibers
listed in section 414.30 as examples.
D
Applies to any plastic product generally classified and reported under SIC 28213 (Thermoplastic
Resins). Section 414.40 includes a list of products subject to this subpart. The products whose
production may be subject to this subpart are not limited to the plastic products listed in section
414.40 as examples.
Applies to any plastic product generally classified and reported under SIC 28214 (Thermosetting
Resins). Section 414.50 includes a list of products subject to this subpart. The products whose
production may be subject to this subpart are not limited to the plastic products listed section
414.50 as examples.
Applies to commodity organic chemicals and commodity organic chemical groups generally
classified and reported under SIC 2865 (Cyclic Crudes and Intermediates, Dyes and Organic
Pigments) and SIC 2869 (Industrial Organic Chemicals, Not Elsewhere Classified). Section
414.60 includes a list of products subject to this subpart The products whose production may be
subject to this subpart are limited to the specific organic chemicals and organic chemical groups
listed in section 414.60.
5 Section 414.11 (a) and the 1987 SIC Manual.
6 The 1997 NAICS Manual.
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G
Applies to bulk organic chemicals and bulk organic chemical groups generally classified and
reported under SIC 2865 (Cyclic Crudes and Intermediates, Dyes and Organic Pigments) and SIC
2869 (Industrial Organic Chemicals, Not Elsewhere Classified). The products whose production
may be subject to this subpart are limited to the specific organic chemicals and organic chemical
groups listed in section 414.70.
H
Applies to all other organic chemicals and organic chemical groups not specifically listed in
Subpart F or Subpart G that are generally classified and reported under SIC 2865 (Cyclic Crudes
and Intermediates, Dyes and Organic Pigments) and SIC 2869 (Industrial Organic Chemicals, Not
Elsewhere Classified). The OCPSF Development Document (Vol. II, Appendix II-A, Table VII)
lists a number of representative examples of organic chemicals and organic chemical groups that
may be subject to Subpart H. The products, however, whose production may be subject to this
subpart are not limited to the organic chemicals and organic chemical groups listed as examples in
the OCPSF Development Document (Vol. II, Appendix II-A, Table VII).
2.4 Applicability of Wastewater from On-Site Auxiliary Operations7
Wastewater from on-site auxiliary operations at a facility manufacturing OCPSF products
are subject to Part 414. Such on-site auxiliary operations include: research laboratories;
technical service support labs; bench-scale operations and pilot plants engaged in various stages
of product development related to existing manufacturing activities at the facility.
2.5 General Discussion of OCPSF-Related Products Whose Manufacture May Not Be
Regulated by Part 414
As specified in Section 414.11, discharges of wastewater from some products listed in
Part 414 may not be subject to this regulation under certain conditions. These conditions include
the following:
• Products whose manufacture were properly classified and previously reported under
specific SIC codes not subject to Part 414.
• Manufacture of products regulated by other industrial categories.
Manufacture of products by a fermentation process.
Manufacture of products solely by extraction from animal or plant raw materials.
2.5.1 Products Classified and Previously Reported under Specific SIC Codes That Are
Not Subject to Part 414
EPA initially proposed8 to extend the applicability of Part 414 to the manufacture of
certain products that were sometimes reported under SIC codes specified for Industrial Groups
284 and 289. EPA, in the final regulation, did not adopt this approach and has specifically
excluded these from the scope of Part 414 at section 414.1 l(c). Part 414 does not apply to
products that were properly classified and previously reported under specified subgroups of SIC
2843 (surfactants), SIC 2891 (adhesives) and SIC 2899 (sizes). Table 2-3 summarizes the
excluded SIC codes and product groups.
7 Section414.ll(b).
8 50 FR 29068 (July 17, 1985) and 51 FR 44082 (Dec. 8, 1986).
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Table 2-3. SIC Codes and Product Groups Specified as Not Subject to Part 414
SIC Code1
2843-085
2891-42
2891-411
2891-424
2891-433
2891-44
2891-441
2891-443
2891-445
2891-447
2891-453
2891-454
2891-455
2891-457
891-461
2891-465
2891-471
2891-448
2891-481
2891-483
2899-56S3
2S99-5973
Product group
Bulk surfactants (surface active agents)
Adhesives, synthetic resin and rubber, including bonding and laminating adhesives.
Epoxy adhesives.
Phenolic, modified phenolic and resorcinol adhesives.
Urea and modified urea adhesives
Vinyl-type adhesives
Polyvinyl acetate adhesive, latex type
Polyvinyl acetate adhesive, solvent type
Polyvinyl chloride and copolymer adhesives
Other vinyl polymer type adhesives
Acrylic adhesives
Cyanoacrylate adhesives
Polyester adhesives
Urethane adhesives
Styrenic adhesives
Hot melt adhesives, including polyamide, polyolefin, and other hot melts.
Adhesive films, all types, including pressure-sensitive structural and non-structural
Rubber and synthetic resin combination adhesives.
Rubber cement, latex type.
Rubber cement, solvent type
Sizes. Textile, paper and all other types of sizes (dextrine, glue, gum, industrial,
rosin, animal, vegetable, and synthetic plastic materials).
Industrial chemical specialties, including fluxes (for brazing, soldering, galvanizing,
and welding), insulation products (heat, electrical, other), plastic wood preparations,
and embalming preparations.
1. SIC codes assigned to these product classifications are from the 1992 Census of Manufacturers.
2. Section 414. ll(c) specifically states that Part 414 does not apply to the manufacture of OCPSF products reported
under SIC group 28914 and its subgroups. The table also lists some of the other subgroups of SIC 2891 that are not
subject to Part 414.
3. Part 414 is not applicable to discharges from the manufacture of products in SIC Codes 2899-568 and 2899-597
under section 414.1 l(c)(3)(I) &(ii). Other organic chemicals classified in SIC 2899 may be subject to part 414.
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2.5.2 Products Listed in Part 414 That Are Regulated by Another Industrial Category
Are Not Subject to Part 414 in Certain Circumstances9
As shown in Table 2-1, some chemical products are not subject to Part 414 when they are
regulated by other industrial categories and have been previously reported under SIC codes for
those industrial categories. Although formerly classified in the same umbrella Industrial Groups
(282, 286) as other products whose manufacture may be subject to Part 414, synthetic rubber
(SIC 2822) and gum and wood chemicals (SIC 2861) are not subject to the Part 414 regulation.
In addition, the manufacture of products classified under Industrial Groups 281 (inorganic
chemicals), 283 (pharmaceuticals), 285 (paints, varnishes, lacquers) and 287 (fertilizers,
pesticides), are also not subject to Part 414. Further, there may be some organic chemicals or
related products specifically listed in subparts of Part 414 that may not, in fact, be subject to Part
414 if the product meets certain conditions described in section 414.11.
Part 414 is not applicable to discharges of process wastewater from the manufacture of
products which are subject to a regulation already promulgated for another industrial category.
However, the manufacture of such products may be subject to Part 414 if:
(1) The manufacturing facility has previously reported these products under SIC codes 2865,
2869, or 2821 and
(2) The process wastewater associated with the manufacture of Part 414 products at the
facility is segregated and treated in a separate treatment system, or discharged separately
to a POTW.
2.5.2.1 Organic Chemicals Regulated by the Iron and Steel Category (40 CFR 420)
Coal tar is a byproduct of the manufacture of coke, which is used in a blast furnace to
convert iron ore to pig iron. A number of organic chemicals and other products may be
recovered from coal tar by distillation. When organic chemicals are recovered from coal tar
crudes as coke oven byproducts at coke plants and such operations have been previously
reported under SIC 3312, the associated process wastewater is regulated by Part 420 because of
the exclusion noted at Section 414.1 l(d). When organic chemicals in coal tar crudes are
recovered from purchased coal tar at off-site manufacturing facilities (i.e., not at coke plants) and
are included within SIC 2865, the associated process wastewater is regulated by Part 414.
These distinctions are illustrated in Figure 2-1.
9 Section 414.ll(d).
10
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Figure 2-1.
~™^, -,- SIC 2865, 2869
Processed at an OCPSF facility
Coal Tar >• Organic Chemicals
Processed at a steel-making facility
>- Organic Chemicals
Coal->- Coke Ovens >* Coke >* to blast furnace
2.5.2.2 Organic Chemicals Regulated by the Pesticides Chemicals Category (40 CFR 455)
Subparts A and B of Part 455 are applicable only to process wastewater associated with
the final step in the manufacture of products that are listed as "organic pesticide active
ingredients"10 and have been previously reported under SIC 2879. Organic chemicals being
manufactured at the same facility, as an intermediate (or intermediate precursor) in the synthesis
of an "organic pesticide active ingredient," are specifically excluded from regulation as an
organic pesticide chemical (Section 455.20(c)). Process wastewater associated with the
synthesis of intermediates in the manufacture of "organic pesticide active ingredients" is subject
to Part 414. These distinctions are illustrated in Figure 2-2.
Figure 2-2
SIC 2865, 2869 SIC 2879
Organic Chemicals ^Intermediates > °rf nif Pesticidf
Active Ingredients
2.5.2.3 Organic Chemicals Regulated by the Pharmaceutical Category (40 CFR 439)
Part 414 does not apply to discharges associated with the production of organic
chemicals that are manufactured as pharmaceutical (medicinal) products or intermediates
provided that the manufacture of such organic chemicals represents more than 50 percent of the
total flow of process wastewater otherwise subject to Part 414 at the pharmaceutical
manufacturing facility.11
10 40 CFR 455.50, Table 1.
1:L40CFR439.0(c)(ll).
11
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2.5.2.4 Products Regulated by the Plastics Molding & Forming Category (40 CFR 463)
The applicability of Part 414 to plastics production rather than plastics processing is
often confused. Plastic products reported under SIC 2821 involve the polymerization of various
liquid or gaseous monomers (reactive organic chemicals) into a solid polymeric material, which
is typically shipped off-site as pellets or other form. The manufacture of synthetic fibers
reported under SIC 2823 involves extruding a melt of such a polymeric material through a
spinneret. Cellulosic synthetic fibers, also reported under SIC 2823, are derived by physically
modifying cellulose, a naturally occurring polymeric material, through chemical processing.
The manufacture of plastic processing products involves melting the solid polymeric
material received from the plastic producer and using mechanical techniques (injection molding,
calendering, extrusion, etc.) to reform it into sheets, film, tubes, rods, or special shapes. Part 414
is not applicable to process wastewater associated with plastic processing products previously
reported under SIC 3081-3089 (formerly SIC 3079), which are regulated by Part 463. These
distinctions are illustrated in Figure 2-3.
Figure 2-3
SIC 2865, 2869 SIC 2813, 2814 SIC 2824
Organic Chemicals ; >• Plastics ;—>* Synthetic Fibers
(Monomers) Polymerization (Po|ymers) Spinning (Polymer filaments)
Processing only
SIC 3081 - 3089
Film, Sheet, Molded Forms, etc.
2.5.2.5 Organic Chemicals Regulated by the Soap and Detergent Category (40 CFR 417)
Part 414 is not applicable to fatty acids manufactured by the "splitting" of animal fats
(tallow, grease), "natural" glycerin obtained as a co-product, or to alkaline salts of fatty acids
obtained by subsequent processing. Such organic chemicals are regulated by Part 417 and, if
reported under SIC 2843, would be exempted by Section 414.1 l(d).
Bulk surface active agents (surfactants) are regulated by part 417 and, if reported under
SIC 2843, would be exempted by both Section 414. ll(c)(l) and section 414.ll(d). Detergents
are blends of surfactants and other ingredients which are also regulated by Part 417 and should
be entitled to the same exemption from Part 414.
12
-------
Part 417 is largely without categorical pretreatment standards, except for the pretreatment
standards for new sources (PSNS) in Subparts O, Q, and R. Thus, with the exception of products
subject to PSNS in these subparts, the Section 414.1 l(d) exclusion of products regulated by Part
417 applies only to direct dischargers subject to Part 414.
12
2.5.3 Organic Chemical Manufacturing Processes Not Subject to Part 414
Part 414 is not applicable to organic chemicals when manufactured solely by:
a. Extraction from plant or animal raw materials. Extraction is defined as the
separation of raw material components by their selective solubility in a solvent.
Examples: Palm oil extracted from crushed seeds of the oil palm tree.
Fragrance chemicals extracted from flower petals.
Agar extracted from seaweed.
b. Fermentation
Examples: Citric acid, Glutamic acid, Ethanol ("natural")
2.6 Synthetic Fibers
Fibers are made in several forms, each suitable for a particular use. Single filaments
(monofilament) may be woven into sheer curtains, knitted into hosiery and used directly for
fishing line or brushes, for example. Continuous strands of two or more filaments may be
twisted together to form filament yarn. Monofilament with larger cross-sectional area (40 denier
or less) is sometimes classified with yarns. Large groups of untwisted continuous filaments are
called tow. Tow can be cut into any desired length, after which it is called staple, a form that is
suitable for textile spinning. Defined in terms of their monomer(s) composition, some
commercially important synthetic fibers are presented in Table 2-4.
Table 2-4. Synthetic Fiber Definitions*
Synthetic Fiber
Acrylic
Modacrylic
Rayon (Viscose ® )
Acetate (Triacetate)
Saran
Definition
Formed from synthetic copolymer composed of at least 85% by weight
acrylonitrile. Co-monomer differs from one manufacturer to another, but
an example of a co-monomer would be methyl methacrylate.
Formed from synthetic polymer composed of less than 85%, but at least
35% by weight acrylonitrile.
Formed from regenerated cellulose (via xanthate) in which substituents
have not replaced more than 15% of the hydroxyl groups.
Formed from cellulose acetate, where not less than 92% of the hydroxyl
groups are acetylated.
Formed from synthetic polymer composed of at least 80% by weight
vinylidene chloride.
Section 414. ll(e).
13
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Nylons
Formed from synthetic polymer having recurring amide groups
connected by an aliphatic chain.
Nylon 6: Polymer from caprolactam
Nylon 66: Polymer from adipic acid + hexamethylene diamine
Nylon 11: Polymer from 11-Aminoundecanoic acid
Nylon 12: Polymer from dodecanolactam
Nylon 6/12: Polymer from caprolactam + dodecanolactam
Polyesters
Polyethylene terephthalate
Polybutylene terephthalate
Formed from synthetic polymer having recurring ester groups. For
example: dihydric alcohol (glycol) + terephthalic acid (TPA).
PET: Polymer from ethylene glycol + dimethyl terephthalate (DMT)
or TPA.
PBT: Polymer from 1,4-butylene glycol + DMT or TPA.
Kodel: Polymer from l,4-di(hydroxymethyl) cyclohexane + DMT.
Spandex
Formed from synthetic block copolymer composed of at least 85% by
weight of a segmented polyurethane.
Vinyon
Formed from synthetic polymer composed of at least 85% by weight
vinyl chloride.
From FTC Regulations, Section 7[c] of the Textile Fiber Products Identification Act.
14
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3. Identifying and Classifying Products Subject to Part 414 at a Plant
Every NPDES permit applicant or industrial discharger to a POTW should develop a list
of the products that are manufactured at its facility and include intermediate products of the
manufacturing process. Such a list will help the manufacturer, the permitting authority, or the
pretreatment program at a POTW to determine which products on the list may be subject to Part
414 (i.e., OCPSF products). Some may be identified as OCPSF products by comparing their
chemical names to the names of products and product groups listed as illustrative examples in
Subparts B through G, products listed in the Development Document,13 and under SIC codes
applicable to Part 414 in the SIC Manual. But these listings of OCPSF products are not
convenient references, even for a chemist. Moreover, a fair number of OCPSF products will not
be found there, since the applicability of the Part 414 is not limited just to the illustrative
products or product groups specifically listed in Subparts C,D,E, and H. As explained
previously, another way to identify an OCPSF product is to determine whether it has been
previously reported to the Census Bureau, or to the Permitting Authority, under an SIC code
regulated by Part 414.
Users, especially those unfamiliar with chemical names (nomenclature), may have
difficulty finding and recognizing the names of the plant's products among the OCPSF products
listed in various subparts of the regulation and the Development Document. To find a product
on the listings of organic chemicals in Subparts F, G, and H, for example, a user must know to
search under aliphatics, aromatics, or amine and amides. Even for someone who is familiar with
chemical nomenclature, locating a particular product on these lists is not straightforward because
the ordering is not entirely alphabetical.
In designing a useful reference to OCPSF products, it was assumed that users would be
able to tentatively classify products as an organic chemical, plastic (resin) or synthetic fiber. To
make it easier for the user to recognize the names of products subject to Part 414 on the list of
products submitted by the facility, names commonly used throughout the OCPSF industry for an
organic chemical listed under Subparts F, G, and H were compiled and tabulated in alphabetical
order. Since a subpart was designated for each product, finding a product on the facility's list
among those listed in Part 414 at once identifies it as an OCPSF product and assigns a subpart.
Products that cannot be found among the three tabulated groups may still be identified as an
OCPSF product, if the product is closely related to a product or product group that is listed.
Plant personnel familiar with chemical nomenclature can be helpful in establishing these
connections, or the user may contact EPA.14
To use the reference tables, the user should first decide whether the products and
intermediate products manufactured at the plant are classified as synthetic fibers, plastics or
organic chemicals. Once classified, individual products may then be searched in the appropriate
table.
13 EPA 440/1-87/009, Oct. 1987,Volume II, Appendix III-A, pp. III-A2 through III-A25.
Office of Water, Engineering & Analysis Division. Phone (202) 566-1000.
15
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Synthetic fibers are listed in Table 2-5, which combines Rayon (Subpart B) and all other
synthetic fibers (Subpart C). The index of synthetic fibers in Subpart C is based on generic
names recognized in commerce, which are discussed in Section 2.6 (p. 13).
Plastics are listed in Table 2-6, which combines Thermoplastic (Subpart D) and Thermosetting
(Subpart E) resins. For quick reference, plastic products regulated in Subparts D and E have
been indexed separately.
Organic chemicals are listed in the Appendix, which combines products classified in
Commodity (Subpart F), Bulk (Subpart G), and Specialty (Subpart H). These regulatory
classifications were based on annual domestic production.15 For quick reference, organic
chemical products regulated in Subpart F were indexed in Table 2-7, and those regulated in
Subpart G were indexed in Table 2-8. Users may first identify as many OCPSF products as
possible from Tables 2-7 and 2-8, and then refer to the combined listing in the Appendix to
confirm other OCPSF products regulated in Subpart H. Alternatively, the Appendix may be
consulted directly, particularly if the user needs cross-referencing to find an organic chemical
product.
15 OCPSF Development Document, Vol. I, p. IV-5.
16
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4. An Example to Demonstrate the Use of Tables 2-5 to 2-8 and the Appendix
A permit applicant submitted the following list of products manufactured at the plant.
Product
Search and Classification Logic
Acetone
Identified as an organic chemical. Found in Table 2-7 under "Acetone."
p-Aminopheno\
Identified as an organic chemical, but not found in Tables 2-7 or 2-8.
Found in the Appendix under "Amino-."
p-Dodecylphenol
Identified as an organic chemical, but not found in Tables 2-7 or 2-8. Not
found in the Appendix under "Dodecyl-." Found in the Appendix under "-
phenol."
Formalin
Identified as an organic chemical. Found in Table 2-7 under
"Formaldehyde."
Melamine
Identified as an organic chemical. Found in Table 2-8 under "Melamine."
Mesityl oxide
Identified as an organic chemical, but not found in Tables 2-7 or 2-8.
Found in the Appendix under "Mesityl-."
Methylisobutyl ketone
Identified as an organic chemical. Found in Table 2-8 under "KETONES,"
and also in the Appendix under "Methyl-."
Melamine-formaldehyde
resins
Identified as a plastic by the term "resins." Found in Table 2-6 under
"Melamine."
Phenol
Identified as an organic chemical. Found in Table 2-7 under "Phenol."
Phenol-formaldehyde
resins
Identified as a plastic by the term "resins." Found in Table 2-6 under
"Phenolic."
17
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SYNTHETIC FIBERS
Index to Synthetic Fibers — Subpart C
Acrylic and Modacrylic
Cellulose acetate
Fluorocarbon
Polyamide (aliphatic)
Polyamide (alicyclic)
Polyaramid (aromatic)
Polybenzimidazole (PBI)
Polyester
Polyolefin
Polyphenylene sulfide
Polyurethane (Spandex)
Polyvinyl chloride (PVC)
Monofilaments:
Nylon
Polycarbonate
Polyethylene
Polystyrene
Polystyrene-Acrylonitrile
Polyvinylidene chloride
Table 2-5. Combined List of Synthetic Fibers
Synthetic Fiber a
Acrylic and Modacrylic
Acrylonitrile-Polyvinylpyrrolidone
Cellulose acetate
Fluorocarbon
Polyamide (aliphatic): Nylon 6
Polyamide (aliphatic): Nylon 66
Polyamide (cyclic aliphatic)
Polyaramid (ar = aromatic)
Polybenzimidazole (PBI)
Polyester
Polyolefin: d
Polyethylene and copolymers
Polypropylene
Polyphenylene sulfide
Polyurethane (Spandex)
Subpart b
C
C*
C
C
C
C
C
C
C
C
C
C
C**
C
Remarks, Tradenames °
Tradenames: Acrilan, Aress, Bi-Loft, Creslan,
Fina, Zefran.
Tradenames: Kynar, Tefzel, Teflon, Halar
Tradenames: Anso, Anso-X, AnsolV, Camalon,
Caprolan, Crepset, Enka, Enkasheer, Enkatron,
Enkalure, Enkaloft, Enkalon, Hanover, Multishear,
Phase 7, Shareen, Softalon, Starbrite, Zantrel,
Zeftron.
Tradenames: Antron, Blue C, Cantrece, Cerex,
Cordura, DuPont, Hyten, Wellon, Wei/strand
Tradenames: Quiana
Tradenames: Kevlar, Nomex
Tradenames: ACE, Angelette, Angelrest, Avlin,
EOF, Encron, Enka, Fortrel, Hollofil, Kodel, Polar
Guard, Reemay, Serene, Sontara, Superba,
Trevira, Wellene.
Tradenames: Cleerspan, DC-100, DC-700,
Gloxpan, Lycra.
18
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Table 2-5. Synthetic Fibers (continued)
Synthetic Fiber a
Subpart
Remarks, Tradenames
Polyvinyl chloride (PVC)
£**
Tradenames: Vinyon
Rayon (Viscose)
B
Monofilaments:
Nylon 6 and copolymers
Nylon 66 and copolymers
Nylon 612 and copolymers
Nylon 11 and copolymers
Nylon 12 and copolymers
Polycarbonate
Polyethylene
Polystyrene
Polystyrene-Acrylonitrile
Polyvinylidene chloride
C
C
C*
C*
C*
£**
C**
£**
C**
£**
Tradenames: Acrylast
Tradenames: Saran
Explanatory Notes and Footnotes for Table 2-5.
Listing of Synthetic Fibers adapted from:
(1) Table II in Vol. II, Appendix III-A, Final Development Document for Effluent Limitations
Guidelines and Standards for the Organic Chemicals, Plastics and Synthetic Fibers.
EPA 440/1-87/009, October 1987.
(2) OCPSF Product/Process File compiled by the Engineering & Analysis Division of EPA's
Office of Water Regulations and Standards, 1976-1983.
(3) SRI Directory of Chemical Producers, 1986 Edition, pp. 653-659.
Subpart notations:
* = Neither Table II of the OCPSF Development Document, Vol. II, Appendix III-A, nor the
Federal Register notice for the final regulation (52 FR 52, November 5, 1987) provide a complete
listing of synthetic fibers that may be subject to Part 414. Additional products that may be
subject to Part 414 were identified from those shown in the 1986 SRI Directory of Chemical
Producers.
C* = Indicates the appropriate Subpart for a product not specifically identified in Table II (cited
above) that may be classified within a "product group" that was listed in Table II. Such products
are implied as OCPSF by belonging to a "product group" that was listed in Table II.
C** = Indicates the appropriate Subpart for a product that is not specifically identified in Table II
(cited above) and is not classifiable within any of the "product groups" that were listed in Table
II. Such products are implied as OCPSF by being commercially available synthetic fibers.
Tradenames from:
(1) SRI Directory of Chemical Producers, 1986 Edition.
(2) Man-Made Fibers Fact Book, 1978 Edition, Education Dept, The Man-Made Fiber
Producers Association, Inc., 1150 Seventeenth St. NW, Washington, DC 20036.
Primarily filament yarn and staple, but may include monofilament and film.
19
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PLASTICS
Index to Thermoplastic Resins — Subpart D
Abietic acid derivatives :
ABS
ABS/SAN
Acrylic
Cellulose
Fatty acid:
Fluorocarbon
lonomer
Methylvinyl ether copolymers
Nitrite
Petroleum hydrocarbon
Phenoxy
Polyacrylic acid 2
Polyamides (Nylons)
Polybutene (Polybutylene)
Polybutenyl succinic anhydride
Polycarbonate
Polyester (saturated)
Polyester (unsaturated):
Polyether ether ketones (PEEK)
Polyethylene copolymers
Polyethylene
Polyimide (polyphthalimide)
Polystyrene
Polystyrene copolymers
Polystyrene terpolymers
Polysulfone
Polyvinyl acetate (PVAc)
Polyvinyl acetate copolymers
Polyvinyl alcohol (PVA)
Polyvinyl butyral (PVB)
Polyvinyl chloride (PVC)
Polyvinyl chloride copolymers
Polyvinylidene chloride
Polyvinyl ether-Maleic anhydride
Polyvinyl formal
Polyvinylpyrrolidone-Styrene
Polyvinyltoluene
Polyvinyltoluene copolymers
Rosin modified or unmodified :
Silicone :
Vinyl resins (unspecified)
Index to Thermosetting Resins — Subpart E
Alkyds, modified and unmodified
Epoxy
Fumaric acid polyester
Furan (Polyfurfuryl alcohol)
Ketone-Formaldehyde
Melamine
Phenolic
Polyacetal (Acetal)3
Polyacrylamide 3
Polyimide
Polyurethane
Triazone
Urea
1 Classified in commerce as a thermosetting resin.
2 Classified in commerce as an organic chemical.
3 Classified in commerce as a thermoplastic resin.
20
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Table 2-6. Combined List of Plastics
Plastics (Resins)3
Remarks,Tradenamesc,
Subpartb Cross-references
Abietic acid derivatives
[D] An alkyd modifier. Classified in commerce as a
thermosetting Resin (Subpart E). See Alkyd
resins.
ABS (Acrylonitrile-[Poly]Butadiene-Styrene) D
SAN (Polystyrene-Acrylonitrile) D
ABS/SAN (Physical blend) D
Tradenames: Absinol, Abson, Arylon Cycolac,
Arylon T, Blendex, Cycoloy, Cycopac, Cycovin,
Decoloy, Dylel, Kralastic, Lustran, Luran,
Marbon, Tybrene.
Tradenames: Absinol, Acrylafil, Lustran, Tyril
Alkyds, modified and unmodified
Alkyds, Glycerophthalic
Alkyds, Maleic
Alkyds, Phthalic
Alkyds, Rosin (terpene ester)
Abietic acid ester modified
Fatty acid ester modified
Alkyds, Styrenated
E
E*
E*
E*
E*
[D]
[D]
E*
Tradenames: Alftalat, Alkydal, Aroflat, Aroplaz,
Styresol, Styretex, Trak-less.
Alkyd modifiers. Classified in commerce as
Thermosetting Resins (Subpart E).
Alkylphenol-Acetylene
Acrylic resins: D
Polymethylmethacrylate D*
Polyacrylate esters (latex) D*
Polymethacrylate esters (latex) D*
Polyacrylate - Methacrylate esters (latex) D
Tradenames: Acrylic MF, Acrylite, Plexiglas,
Acronal, Acralene.
Cellulose resins:
Cellulose acetate
Cellulose acetate butyrate
Cellulose acetate phthalate
Cellulose acetate propionate
Cellulose nitrate (Nitrocellulose)
Cellulose sponge
D
D
D*
D
X
X
OCPSF not applicable (414.11d)
An explosive reported under SIC 2892.
OCPSF not applicable. Product deleted
[55 FR 42339 (Oct. 18, 1990)]. May be
reported under SIC 3089.
Dicyanodiamide resins
Epoxy resins: E
Epoxy, modified E*
Epoxy, unmodified E*
Epoxy, brominated E*
Epoxy, cycloalkenyl E*
5,5-Dimethylhydantoin - Formaldehyde E*
Epoxy, phenoxy (unmodified) E*
Tradenames: Araldite, Aroflint, Bakelite,
Bekipex EP, Capon, Cardolite, Cardon, DEH,
DEN, Der, Epiall, Epichlor, Epi-cure, Epi-Rez,
Epi-Tex, Epocryl, Epon, Eponol, Epotuf,
Hydantoin, Kopox, Kopoxite, Pedigree, Polox,
Polyset, Polytool, Quatrex, Tactix.
21
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Plastics (Resins)3 Subpartb
Fatty acid resins
Fumaric acid polyester resins
Furan (Polyfurfuryl alcohol) resins
Fluorocarbon resins:
Polytetrafluoroethylene (PTFE)
Polytetrafluoroethylene + Ethylene
Fluorinatedpolyethylene-propylene
Polychlorotrifluoroethylene
Polychlorotrifluoroethylene + Ethylene
Polychlorotrifluoroethylene +
Vinylidene fluoride
Polyvinylidene fluoride
Perfluoroalkoxy
Glyoxal + Urea + Formaldehyde (textile)
lonomer resins:
Polyethylene + Acrylic acid
Polyethylene + Methacrylic acid
Ketone-Form aldehyde resins
Acetone + Formaldehyde
Cyclohexanone + Formaldehyde
Melamine resins
Melamine + Formaldehyde
Melamine + Phenol + Formaldehyde
Melamine + Urea + Formaldehyde
Methylated melamine + Formaldehyde
Methylvinyl ether copolymers:
Methyl vinyl ether + Maleic anhydride
Methyl vinyl ether + Monobutyl maleate
Methyl vinyl ether + Monobutyl maleate
Nitrile (Acrylonitrile copolymer)
Petroleum Hydrocarbon resins
Phenolic resins:
Alkylphenol - Formaldehyde
Amylphenol - Formaldehyde
Butylphenol - Formaldehyde
Nonylphenol - Formaldehyde
Cresol - Formaldehyde
Cresylic acid - Formaldehyde
Phenol - Formaldehyde
[D]
E
E
D
D*
D*
D*
D*
D*
D*
D*
D*
[E]
Q**
D**
Q**
E
E*
E*
E
E*
E*
E*
E*
D
D*
D*
Q**
D
E
E*
E*
E*
E*
E*
E*
E*
Remarks,Tradenamesc, Cross-references
Classified in commerce as Thermosetting
Resins (Subpart E). See Alkyd resins.
Tradenames: Fluon, Halon, Teflon.
Tradenames: Tefzel
Tradenames: Teflon-FEP
Tradenames: Kel-F81, Aclar, Aclon.
Tradenames: Halar
Tradenames: Aclar, Aclon, Kel-F82.
Tradenames: Foraflon, Kynar.
Tradenames: Teflon-PFA
Textile finishing agent. OCPSF not applicable,
if previously reported under SIC 2843
(41 4.1 1c).
Tradenames: Surly n
See Polyethylene copolymers
See Polyethylene copolymers
Tradenames: Admino, Amres, Avisco,
Beckamine, Cascomel, Catadec, Cymel,
Kauramin, Luvipol, Melmac, Meltron, Resamin,
Resimene, Resloom, Syn-U-Tex, Uformite.
Tradenames: Gantrez
Tradenames: Barex, Cycopac, Lopac.
Tradenames: Adtac
Tradenames: Acrylon, Adlock, Aerodux,
Amberol, Amres, Bakelite, Beckacite,
Beckopol, Cascophen, Castastock, Catacol,
Catacore, Catacote, Catafilm, Cataform,
Durez, Durite, Dyphen, Dyphenite, Foundrez,
Genal, Hycar, Kastor, Kauresin, Phenall,
Phenolls, Phenuren, Poly-phen, Polytool,
Pyroloy, Resinex, Thor, Valite, Vulkadur.
22
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Plastics (Resins)3
Subpartb Remarks,Tradenamesc, Cross-references
Phenolic resins (continued):
Phenol - Formaldehyde, rosin modified
(Rosin Resins)
Phenol - Resorcinol - Formaldehyde
Phenol-Terpene (polyterpene)
Resorcinol - Formaldehyde
Phenoxy resins
E*
E*
E*
E*
Polyacetal (Acetal resin, Polyoxymethylene)
PET, as bottle-grade resins
PET, as plastic bottles
Polyalkylene isophthalate
Polyoxybenzoate
[E] Tradenames: Celcon, Delrin.
Classified in commerce as a Thermoplastic
Resin (Subpart D).
Polyamides (aliphatic)
Dimer acid-based polyamide
Epichlorohydrin-based polyamide
Nylon 6
Nylon 9
Nylon 11
Nylon 12
Nylon 66
Nylon 6/12
Polyaramides (ar = aromatic)
Polyacrylic acid
Polybutadiene
Polybutenes (Polybutylene)
Polybutene-1
Polybutenylsuccinic anhydride
Polycarbonate
Polyester resins, saturated
Polybutylene terephthalate (PBT)
(polytetramethylene terephthalate)
Polyethylene terephthalate (PET)
PET as film
D
D*
D*
D
D*
D
D
D
D
D
[D]
[D]
D
D*
D
D
D
D
D*
X*
Tradenames: Isonamid
Tradenames: Capron, Dymetrol, Elvamide,
Ertalon, Felor, Fosta, Herox, Milvex,
Moleculoy, Platamid, Texalon, Tynex,
Versalon, Vydyne, Vylor, Wellamid,
Well-blend, X-tal, Xylon.
Tradenames: Kevlar
See Acrylic acid. Regulated in OCPSF as a
PLASTIC, but classified in commerce as an
organic chemical.
OCPSF not applicable, if previously reported
as an elastomer under SIC 2822 (414. 11c).
Tradenames: Calibre, Lexan, Merlon.
Tradenames: Celanx, Gafite, Gaftuf, Valox,
VCT.
OCPSF not applicable. Regulated by
D*
X*
D*
D
40 CFR463 (414.11d) and reported under
SIC 3081. Tradenames: Cronar, Mylar,
Estar, Melinex, Scotchpak, Scotchpar.
Tradenames: Kodapak, Cleartuf.
OCPSF not applicable. Regulated by
40 CFR 463 and reported under SIC 3085
(414.11d).
Tradenames: Advaco
23
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Plastics (Resins)3
Subpartb Remarks,Tradenamesc, Cross-references
Polyester resins, unsaturated
[D] Classified in commerce as Thermosetting
Resins (Subpart E).
Tradenames: Alpolit, Aropol, Astroloy, Atlac,
AZ Rez, CoRezyn, Cypor, Derakane, Dion,
Dypol, Fostercast, Genpol, GlidpolGlykon,
Isolite, Koplac, MR/Marco, Multron, Pedigree,
Pleogen, Polylite, Polytool, Selectron, Silmar,
Stypol, Synolite, Tere-cast, Usslaminac,
Valbond, Valglas, Vibramix, Vibrin.
Polyether ether ketones (PEEK)
Polyethylene
Polyethylene, high density (HOPE)
Polyethylene, low density (LDPE)
Polyethylene, ultra-high MW
Chlorinated polyethylene
Polyethylene Wax (low Molecular Wt.)
Polyethylene wax (low MW, emulsion)
Polyethylene scrap
Compounded Polyethylene resins:
From resins produced in same plant
From purchased resins
Polyethylene copolymers
Ethylene + Acrylic acid
Ethylene + Ethyl acrylate (EEA)
Ethylene + Maleic anhydride (EMA)
Ethylene + Methacrylic acid
Ethylene + Vinyl acetate
Ethylene + Vinyl chloride
Polyimides (polyphthalimides)
Polyimide
Polyimide-foam
Polyamide-imide
Polyether-imide
Polyimides
Polyimide
Polyester-imide
Polye ster-amide -imide
D**
D
D
D
D*
D
D
[D]
D
D
X*
D
D*
D
D*
D*
D
D
D
D
X*
D*
D*
[D]
E*
E*
E*
Tradenames: Alathon, Bakelite, Dylan, El Rey,
Eltex, Ethron, Fortiflex, Hex One, Hi-fax,
Hostalen, Lupolen, Marlex, Microthen, 1900,
Norchem, Paxon, Petrothene, Poly-Eth,
Poly-The, Pow'r-pak.
OCPSF not applicable, if formulated as a floor
wax and previously reported under SIC 2842.
OCPSF not applicable. Regulated by 40 CFR
463 (414.11d)and reported under SIC 3087.
Tradenames: Acralen
Tradenames: Kapton, Mill, Polyimide 2080,
Pyre-ML1, Pyre, Ultratherm, Vespel, Xu218,
Xu218HP.
Classify as SIC 3086: Foamed plastics.
Tradenames: Al Polymer, A1600 Series,
Torlon, Tritherm, XWE-960A.
Tradenames: Ultem
Classified in commerce as Thermosetting
resins (Subpart E).
Tradenames: RI-7271, Skybond 700, Skybond,
RI-7271, Thermid.
Tradenames: Imidex, Teritherm, Isomid.
Tradenames: Enamel Omega.
24
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Plastics (Resins)3
Subpartb Remarks,Tradenamesc, Cross-references
Polyisobutylene
Poly(alpha)Olefms
Polyphenylene oxide (PPO)
Polydimethyl-o-phenol
Polyphenylene sulfide
Polypropylene (PP) resins
D*
D
D*
D*
D*
D
Tradenames: Noryl
Tradenames: A-fax, Alprodur, Avi-sun, Dypro,
EIRex, Fortilene, Hercocel, Hostalen,
LeRexene, Luparen, Moplen, Orlane, Olefil,
Oleflo, Oleflow, Oleform, Olemer, Oletemp,
Olex, Plasti-Glas, Poly-pro, Pow'r-pak, Procon,
Pro-fax, Profit.
Polystyrene (PS)
Polystyrene, crystal
Polystyrene, expandable
D
D
D
Tradenames: Bipak, Cerex, Dylene, Evenglo,
E-Z Flow, Forar, Fostafoam, Fostarene,
Fosta Tuf-Flex, Jet Flow, Lustrex, Pelaspan,
Pelaspan-Pac, Polyfibre, Polytone, Pow'r-pak,
Styron, Styropor, Styrospan, Styrotherm,
Superdense, Superflex, Superflow, Verelite.
Polystyrene copolymers
Styrene + Acrylonitrile (SAN)
Styrene + Acrylic (latex)
Styrene + Acrylate ester (latex)
Styrene + Allyl alcohol
Styrene + Butadiene resins
Styrene + [<50%]Butadiene (impact)
Styrene + [>50%]Butadiene (latex)
D
D
D
D*
D*
D
D
X*
See ABS resins.
Tradenames: K-Resin
SBR elastomer. OCPSF not applicable.
Regulated by 40 CFR 419 (414.11d) and
reported under SIC 2822.
Styrene + Divinylbenzene
Styrene + Methylmethacrylate
Styrenesulfonate + Maleic anhydride
Polystyrene terpolymers
Styrene + Acrylonitrile + Acrylate ester
Styrene + Butadiene + Vinyltoluene
Styrene + Two Methacrylate esters
Styrene + Butadiene + Methyl methacrylate
Polysulfone resins
Polysulfone
Polyarylsulfone
Polyethersulfone
Polyphenylsulfone
D
D
D
D
D
D
D
D*
D
D
D*
D*
D*
Tradenames: Udel
Tradenames: Astral 360
Tradenames: Victrex
Tradenames: Radel
25
-------
Plastics (Resins)3
Polyurethane prepolymers d
Polyurethane resins d
Polyurethane moulding resins
Polyurethane foams (cellular)
Polyurethane surface coatings
Polyurethane adhesives, sealants
Poly vinyl acetate resin (PVAc)
Polyvinyl acetate copolymers
Vinyl acetate + Aery late ester
Vinyl acetate + n-Butyl acrylate
Vinyl acetate + Ethylene
Vinyl acetate + 2-Ethylhexyl acrylate
Vinyl acetate + Methacrylate ester
Vinyl acetate + Vinyl chloride
Polyvinyl alcohol resins (PVA)
Polyvinyl butyral resins (PVB)
Polyvinyl chloride resins (PVC)
Chlorinated PVC
Polyvinyl chloride copolymers:
Vinyl chloride + Acrylate ester (latex)
Vinyl chloride + Methacrylate ester
Vinyl chloride + Ethylene
Vinyl chloride + Vinylidene chloride
Vinyl chloride + Vinyl acetate
Polyvinylidene chloride
Polyvinylidene chloride copolymers
Polyvinyl ether + Maleic anhydride
Polyvinyl formal
Polyvinylpyrrolidone copolymers
l-Vinyl-2-pyrrolidone + Styrene
Polyvinyltoluene
Polyvinyltoluene copolymers:
Vinyltoluene + Acrylate ester
Vinyltoluene + Butadiene
Vinyltoluene + Methacrylate ester
Rosin resins, derivative
Rosin resins, modified
Subpartb
E
E
E*
X*
[E*]
X*
D
D
D
D
D
D
D
D
D
D*
D
D
D
D
D
D
D
D
D
D
D
D
D*
D
D*
D
D
D
[D]
[D]
Remarks,Tradenamesc, Cross-references
OCPSF not applicable. Regulated by 40 CFR
463 and reported under SIC 3086 (414.1 1d).
OCPSF not applicable, if previously reported
under SIC 2851 . Not regulated by 40 CFR 446.
OCPSF not applicable, if previously reported
under SIC 2891 (414. 11c).
See Polyvinyl chloride copolymers.
Tradenames: Elvanol, Gelvatol, Vinol.
Tradenames: Butacite, Butvar
Tradenames: Abson, Bakelite, Dacovin,
Exon, Genclor, Geon, Hostaphan, Intamix,
Irvinil, Kohinoor, Luvitherm, Pliovic,
Polytrend, Rucon, Vestolit, Vinuron, Vygen,
Vxgen.
Tradenames: Acrylivin
See Polyvinyl acetate copolymers.
See Methylvinyl ether copolymers.
Classified in commerce as Thermosetting
Resins (Subpart E). See Alkyd resins.
26
-------
Plastics (Resins)3
Subpartb Remarks,Tradenamesc, Cross-references
SAN (Styrene + Acrylonitrile)
D
See ABS resins.
Silicone resins
Silicone rubbers
Vinyl polybutadiene
Vinyl resins (unspecified)
Vinyltoluene resins
[D] Classified in commerce as Thermosetting
Resins (Subpart E).
[D] OCPSF not applicable (414.11d). Regulated by
40 CFR 428.30 and reported under SIC 2822.
Triazone resins:
Acetoguanamine-Formaldehyde
Benzoguanamine-Formaldehyde
Urea resins
Urea-Formaldehyde (Methylol)
Urea-Melamine-Formaldehyde
E*
E*
E
E
E*
Tradenames: Aerolite, Amres, Cascamite,
Casco-Resin, Catabox, Fabroz, Foundrez,
Fporka, Foundrez, Fporka, Kaurit, Polyria,
Resamin, Resimene, Styplast, Syn-U-Tex,
Uformite.
X*
D*
D
OCPSF not applicable (414.11d). Regulated by
40 CFR 428.30 and reported under SIC 2822.
See Polyvinyltoluene copolymers
Explanatory Notes and Footnotes for Table 2-6
Footnotes:
a. Listing of Plastics (Resins) adapted from:
(1) Tables III and IV in Vol. II, Appendix III-A, Final Development Document for Effluent
Limitations Guidelines and Standards for the Organic Chemicals, Plastics and Synthetic
Fibers. EPA 440/1-87/009, October 1987.
(2) OCPSF Product/Process File compiled by the Engineering & Analysis (formerly
Industrial Technology) Division of EPA's Office of Science & Technology (formerly
Water Regulations & Standards), 1976-1983.
(3) SRI Directory of Chemical Producers, 1986 Edition, pp. 908-934.
b. Subpart notations:
D = Subpart D, Thermoplastic Resins, 40 CFR Part 414.40.
E = Subpart E, Thermosetting Resins, 40 CFR Part 414.50.
[ ] = Indicates a change in the status of a product since promulgation of the OCPSF regulation.
These include changes in product classification prompted by published amendments to the
OCPSF regulation, and corrections for errors in the listings of products in Table V, VI or VII of
the OCPSF Development Document.
X = OCPSF regulation is not applicable to the product.
* = The product was not listed in Table III or IV in the OCPSF Development Document, or in FR
52, Nov. 5,1987, pp. 42572-42574. These additional products were selected from those shown in
the 1986 SRI Directory of Chemical Producers.
-------
Explanatory notes and footnotes for Table 2-6 (continued)
Subpart notations for products which are not listed in the OCPSF Dev. Document.
D* = Neither Table III or IV of the OCPSF Development Document, Vol. II, Appendix III-A, nor
the Federal Register notice for the final regulation (52 FR 52, November 5, 1987) provide a
complete listing of plastic products that may be subject to Part 414. Additional products that may
be subject to Part 414 were identified from those shown in the 1986 SRI Directory of Chemical
Producers. Such products are implied as OCPSF by belonging to a "product group" that was
listed.
D** = Indicates the appropriate Subpart for a plastic product not specifically identified in either
Table III or IV (cited above) that may be classified within a "product group" that was listed.
Such products are implied as OCPSF by belonging to a "product group" that was listed in Table
III or IV.
c. Tradenames taken from:
(1) 1986 SRI Directory of Chemical Producers.
(2) Facts and Figures of the Plastics Industry, 1979 Edition, The Society of the Plastics
Industry, 355 Lexington Ave., New York, NY.
d. Polyurethanes
Since water must be rigorously excluded from the process, the formation of polyurethane
resins or prepolymers from diisocyanates and polyols produces no wastewater directly. An
indirect source of wastewater is blowdown from caustic scrubbers, which capture
isocyanates vented from polyurethane processes.
28
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ORGANIC CHEMICALS
Table 2-7. Commodity Organic Chemicals — Subpart F
Organic Chemicals
*CAS Number
Acetaldehyde
Acetic acid (glacial)
Acetic anhydride
Acetone
Acrylonitrile
Adipic acid
Benzene
Butadiene
Butylenes, mixed
Cumene
Cyclohexane
Dimethyl terephthalate (DMT)
Ethylbenzene
Ethylene
Ethylene dichloride (1,2-Dichloroethane)
Ethylene glycol
Ethylene oxide
Formaldehyde (Formalin)
Isopropanol (Isopropyl alcohol)
Methanol
Phenol
Pitches (from coal tar)
Polypropylene glycol (PPG)
Propylene
Propylene oxide
Pyrolysis gasoline
Styrene
Terephthalic acid (TPA)
Toluene
Vinyl acetate
Vinyl chloride (1-Chloroethene)
Xylenes, mixed
m-Xylene, crude (mixed with p-Xylene)
o-Xylene
yp-Xylene
75-07-0
64-19-7
108-24-7
67-64-1
107-13-1
124-04-9
1076-43-3
106-99-0
68477-42-9
98-82-8
110-82-7
120-61-6
100-41-4
74-85-1
107-06-2
107-21-1
75-21-8
50-00-0
67-63-0
67-56-1
108-95-2
6599-6-93-2
25322-69-4
115-07-1
75-56-9
68606-10-0
100-42-5
100-21-0
108-88-3
108-05-4
75-01-4
1330-20-7
108-38-3
95-47-6
106-42-3
* CAS = Chemical Abstract Service
29
-------
Table 2-8. Bulk Organic Chemicals - Subpart G
Organic Chemicals CAS Number
Acetates (Acetic acid esters)
n-Butyl acetate 123-86-4
Isobutyl acetate 110-19-0
Isopropyl acetate 108-21-4
n-Propyl acetate 109-60-4
Acetone cyanohydrin 75-86-5
Acetylene 74-86-2
ACIDS:
Acrylic acid 79-10-7
Benzoic acid 65-85-0
n-Butyric acid 107-92-6
Butyric acid anhydride 106-31-0
Cyanuric acid 108-80-5
Dimer acid (Dilinoleic acid) 6144-28-1
Ethylenediaminetetraacetic acid (EDTA) 60-00-4
Isophthalic acid 121-91-5
Metanilic acid 121-47-1
Methacrylic acid 79-41-4
2-Naphthalenesulfonic acid 120-18-3
Nitrilotriacetic acid (NTA) 139-13-9
Oxalic acid 144-62-7
Phthalic acid 88-99-3
Propionic (Propanoic) acid 79-09-4
Salicylic acid 69-72-7
Trimellitic acid 528-44-9
Acrylates (Acrylic acid esters)
Ethyl acrylate 140-88-5
2-Ethylhexyl acrylate 103-11-7
Methyl acrylate 96-33-3
Adiponitrile (1,4-Dicyanobutane) 111-69-3
ALCOHOLS:
n-Butanol (n-Butyl alcohol) 71-36-3
n-Decanol (n-Decyl alcohol) 112-30-1
Diacetone alcohol 123-42-2
1-Dodecanol (Lauryl alcohol) 112-53-8
Ethanol (Ethyl alcohol, "synthetic" only) 64-17-5
2-Ethylhexanol 104-76-7
Isobutanol (Isobutyl alcohol) 78-83-1
n-Propanol (n-Propyl alcohol) 71-23-8
ALDEHYDES:
n-Butyraldehyde 123-72-8
2-Ethylbutyraldehyde 97-96-1
2-Ethylhexanal (2-Ethylhexaldehyde) 123-05-7
30
-------
Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
CAS Number
ALDEHYDES (continued):
Isobutyraldehyde
Propionaldehyde
78-84-2
123-38-6
Alkylates (Alkylbenzenes):
Dodecylbenzene (branched,"hard")
Dodecylbenzene (linear,"soft")
123-01-3
123-01-3
Alkylphenols, mixed
/>-fert-Butylphenol
/>-Dodecylphenol
Nonylphenol
Allyl chloride
98-54-4
104-43-8
25154-52-3
107-05-1
AMINES:
n-Butylamine
sec-Butylamine
fert-Butylamine
Dimethylamine
Diphenylamine (N-Phenylaniline)
Ethylamine
Ethylene diamine
Hexamethylenediamine (1,6-Hexanediamine)
Isopropylamine
Melamine
Methylamine
o-Phenylenediamine
Toluene diamines (Tolylene diamines, mixed isomers)
Trimethylamine
109-73-9
513-49-5
75-64-9
124-40-3
122-39-4
75-04-7
107-15-3
124-09-4
75-31-0
108-78-1
74-89-5
95-54-5
25376-45-8
75-50-3
Aniline:
N,N-Diethyla«/7/'«e
2,6-Dimethyla«/7/'«e
4-(N-Hydroxyethylethylamino)-2-hydroxyethyl aniline
4,4'-Methylenebis(dia«/7/'«e) (MDA)
Methylene dianiline (MDA)
4,4'-Methylenebis(N,N-dimethyla«/7/'«e)
Nitroa«/7/'«es, mixed
Polymeric MDA (oligomers)
62-53-3
91-66-7
87-62-7
*
101-77-9
101-77-9
101-61-1
Benzoic acid
m-Aminobenzoic acid
p-Ammobenzoic acid
ra-Benzenedisulfonic acid, diSodium
Benzyl chloride
Bisphenol A
65-85-0
99-05-8
150-13-0
831-59-4
100-44-7
80-05-7
* CAS Number not readily identified
31
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Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
BTX (Benzene, Toluene, Xylenes)
n-Butane
Butenes:
1-Butene
2-Butene (cis)
2-Butene (trans)
yp-fert-Butylphenol
Caprolactam
Carbon disulfide
Carbon tetrachloride
Cellulose ethers:
Carboxymethylcellulose, Sodium
Carboxymethyl hydroxyethyl cellulose, Sodium
CFC's (Chlorofluorocarbons):
Chlorodifluoromethane (HCFC-22)
Fluorotrichloromethane (CFC-11)
Chlorinated paraffins (wax), 35-64% Chlorine
Chlorobenzene
Chlorobenzenes, mixed
Chloroethanes:
Chloroethane (Ethyl chloride)
1,1-Dichloroethane (Methylene chloride)
1,1,1 -Trichloroethane (Methylchloroform)
1 , 1 ,2-Trichloroethane (beta-Trichloroethane)
Chlor oethylenes :
1,1-Dichloroethylene (Vinylidene chloride)
Tetrachloroethylene (Perchloroethylene)
Trichloroethylene (TCE)
Chlorophenols:
6-Chloro-m-cresol (2-Chloro-5 -methyl phenol)
2,4-Dichlorophenol
Chloroform (Trichloromethane)
Chloroprene (2-Chloro- 1 ,3-butadiene)
Coal tar products:
Creosote oil (low boiling)
Naphthalene
Pitches/Tars (refined, road materials)
Cresylic acid (mixture of o-, m-, p-Cresol)
Cresols, mixed (from coal tar condensate)
CAS Number
68475-70-7
106-97-8
106-98-9
590-18-1
624-64-6
98-54-4
105-60-2
75-15-0
56-23-5
9004-32-4
*
75-46-6
75-69-4
63449-39-8
108-90-7
25321-22-6
75-00-3
75-34-3
71-55-6
79-00-5
75-35-4
127-18-4
79-01-6
615-74-7
120-83-2
67-66-3
126-99-8
70321-80-1
91-20-3
65996-93-2
1319-77-3
1319-77-3
* CAS Number not readily identified
32
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Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
Cresols (from hydrocarbon processes):
Cresols, mixed (Cresylic acids)
ra-Cresol
o-Cresol
yO-Cresol
Cumene hydroperoxide
Cyanogen (Ethanedinitrile)
Cyanogen chloride
Cyanuric acid
Cyanuric chloride
Cyclohexanol
Cyclohexanone
Cyclohexanol-Cyclohexanone (mixture)
Cyclohexene
Diethylene glycol ethers:
Diethylene glycol, diethyl ether (bis[2-Ethoxyethyl] ether)
Diethylene glycol, dimethyl ether (bis[2-Methoxyethyl] ether)
Diethylene glycol, monoethyl ether (2-[2-Ethoxyethoxy] ethanol)
Diethylene glycol, monomethyl ether (2-[2-Methoxyethoxy] ethanol)
Dimer acid (Dilinoleic acid)
Dimethylformamide (DMF)
Dinitrotoluenes, mixed
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diols:
1,4-Butanediol
2,2,4-Trimethyl- 1 ,3 -pentanediol
N,N-Dimethylformamide
1,4-Dioxane
p-Dodecylphenol
Epichlorohydrin
Ethane
Ethanolamines:
Monoethanolamine
Diethanolamine
ETHERS:
Diethyl ether
Methyl-tert-butyl ether (MTBE)
CAS Number
1319-77-3
108-39-4
95-48-7
106-44-5
80-15-9
460-19-5
506-77-4
108-80-5
108-77-0
108-93-0
108-94-1
*
10-83-8
112-36-7
111-96-6
111-90-0
111-77-3
6144-28-1
68-12-2
104-38-8
121-14-2
606-20-2
74829-49-5
144-19-4
68-12-2
123-91-1
104-38-8
106-89-8
74-84-0
141-43-5
111-42-2
60-29-7
1634-04-4
* CAS Number not readily identified
33
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Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
CAS Number
Ethylene glycol ethers:
Ethylene glycol, dimethyl ether (1,2-Dimethoxyethane)
Ethylene glycol, monobutyl ether (2-Butoxyethanol)
Ethylene glycol, monoethyl ether (2-Ethoxyethanol)
Ethylene glycol, monomethyl ether (2-Methoxyethanol)
Ethylene glycol, monophenyl ether (2-Phenoxyethanol)
110-71-4
111-76-2
110-80-5
109-86-4
122-99-6
Fatty nitriles
Formate, Sodium (Formic acid salt)
68514-68-1
23102-86-5
GLYCOLS:
Diethylene glycol
Dipropylene glycol
Polybutylene (Polyoxybutylene) glycol
Polyethylene glycol (PEG) (Polyether polyols)
Propylene glycol (1,2-Propanediol)
111-46-6
110-98-5
5190-06-1
25322-68-3
4254-15-3
Glyoxal
n-Hexane
Hydrocarbons C-5 (concentrate)
Hydrocarbons C-9 (concentrate) C7 to C9
Isobutylene (2-Methylpropene)
107-22-2
110-54-3
68476-43-7
68920-06-9
115-11-7
Isocyanates:
Methylenebis(4-phenyl/5ocya«ate) (MDI)
Methylenediphenyldi/'socyanafe (MDI)
Polymethylene polyphenyleneisocyanate (PAPI)
PAPI (polymeric MDI)
Tolylene diisocyanates (TDI), mixed
2,4-Tolylene diisocyanate
2,6-Tolylene diisocyanate
101-68-8
101-68-8
9016-87-9
9016-87-9
26471-62-5
584-84-9
91-08-7
Isophorone
Isoprene (2-Methyl-l,3-butadiene)
78-59-1
78-79-5
KETONES:
Methyl ethyl ketone (MEK)
Methyl isobutyl ketone (MIBK)
78-93-3
108-10-1
34
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Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
CAS Number
Maleic anhydride
Melamine
Methane
Methyl chloride (Chloromethane)
108-31-6
108-78-1
74-82-8
74-87-3
Methylenebis-
4,4'-Methylenebis(dianiline)
Methylene dianiline (MDA)
Polymeric methylene dianiline
4,4'-Methylene bis(N,N-dimethylaniline)
101-77-9
101-77-9
25214-70-4
101-61-1
Methylene chloride (Dichloromethane)
Methyl methacrylate (MMA)
a-Methylstyrene
Naphtha solvent (made in chemical plant)
Naphthalene
2-Naphthalenesulfonic acid (beta)
Nitrobenzene
yp-Nitrophenol
75-09-2
80-62-6
98-83-9
8052-41-3
91-20-3
120-18-3
98-95-3
100-02-7
Nitrotoluenes:
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Dinitrotoluenes (mixed isomers)
o-Nitrotoluene
yp-Nitrotoluene
121-14-2
606-20-2
25321-14-6
88-72-2
99-99-0
Nonylphenol
Nylon salt
Olefins (alpha)
Organo-Tin compounds
25154-52-3
64743-02-8
Oxo Process Chemicals:
n-Butyraldehyde
n-Butanol
2-Ethylhexanol
Isobutanol (2-Methyl-l-propanol)
Isobutyraldehyde
Propionic acid (Propanoic acid)
123-72-8
71-36-3
104-76-7
78-83-1
78-84-2
79-09-4
35
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Table 2-8. Organic Chemicals - Subpart G (continued)
Organic Chemicals
CAS Number
Oxo Process Chemicals (continued):
n-Propanol
Propionaldehyde
71-23-8
123-38-6
n-Paraffins(C-9toC-16)
Pentaerythritol
n-Pentane
1-Pentene
Pentenes, mixed
Perchloroethylene (Tetrachloroethylene)
o-Phenylenediamine
Phosgene
64771-72-8
115-77-5
109-66-0
109-67-1
25377-72-4
127-18-4
95-54-5
75-44-5
Phthalates:
Butyl, Octyl phthalate
Di-n-butyl phthalate
Di(2-ethylhexyl) phthalate
Diisobutyl phthalate
Diisodecyl phthalate
Diiso-octyl phthalate
Dimethyl phthalate
Ditridecyl phthalate
84-78-6
84-74-2
117-81-7
84-69-5
26761-40-0
117-84-0
31-11-3
85-44-9
Phthalic anhydride
Pine oil, synthetic (Terpineols)
Propane
Propylene dichloride (1,2-Dichloropropane)
Sorbitol
Stearate(wax), Calcium
Tetraethyl Lead (TEL)
Tetrahydrofuran (THF)
1,2,3,4-Tetrahydronaphthalene (Tetralin)
1-Tetralol/l-Tetralone mixture
1,2,3,4-Tetrahydro-1 -naphthol (1 -Tetralol)
1 -Tetralone (3,4-Dihydro-2 [2H] -naphthalenone)
Tetramethyl Lead (TML)
85-44-9
8002-09-3
74-98-6
78-87-5
50-70-4
2223-93-0
78-00-2
109-99-9
119-64-2
*
529-33-9
529-34-0
75-74-1
Toluenediamines (Tolylenediamines)
2,4-Tolylenediamine (2,4-Diaminotoluene)
Tri-/?-cresyl phosphate (Tritolylphosphate)
Vinylidene chloride (1,1-Dichloroethene)
25376-45-8
95-80-7
1330-78-5
75-35-4
* CAS Number not readily identified
36
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Specialty Organic Chemicals - Subpart H
Individual and groups of organic chemicals subject to the effluent limitations for Subpart
H are not listed in 40 CFR 414. However, a list of such organic chemicals may be found in the
OCPSF Development Document, Volume II, Appendix II-A, Table VII.
The specialty organic chemicals listed in the OCPSF Development Document, as well as
other organic chemicals appropriate for Subpart H, have been integrated into the combined list of
organic chemical products tabulated in the Appendix of this guidance. The combined list in the
Appendix includes organic chemicals applicable to Subparts F, G, and H.
37
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APPENDIX
-------
An Introduction to Organic Chemical Nomenclature
OCPSF plants name organic chemical products in several ways: Common, Systematic,
Acronym, Generic, etc. Some examples follow.
Common
Acetaldehyde
Acetic acid
Acetone (Dimethyl ketone)
Benzoic acid
Cresol (Cresylic acid)
Dimer acid (Dilinoleic acid)
Ethylene
Ethylene dichloride
Ethylene glycol monoethyl ether
Methyl ethyl ketone
Phenol (Tar acid)
Phthalic acid
Vinylidene chloride
Systematic
Ethanal
Ethanoic acid
2-Propanone
Benzenecarboxylic acid
Hydroxytoluene
Ethene
1 ,2-Dichloroethane
2-Ethoxyethanol
2-Butanone
Hydroxybenzene
Benzene- 1 ,2-dicarboxylic
acid
1 , 1 -Dichloroethene
Acronym
DMK
EDC
MEK
Generic
Aldehyde
Aliphatic
carboxylic acid
Ketone
Aromatic
carboxylic acid
Phenolic
Fatty acid
Olefin
Chloroalkane
Glycol ether
Ketone
Phenolic
Aromatic
dicarboxylic acid
Chloroalkene
A user would presumably experience more difficulty in identifying and classifying
organic chemical OCPSF products than fiber or plastic products, because of the sheer number of
entries and complexity of the names. For this reason, an innovative effort was made to compile
and order the combined list of organic chemical OCPSF products in such a way that users trying
to find a product need only key on its chemical name. Entries were avoided that would require
the user to have a knowledge of the structure or nomenclature of organic chemicals. Entries on
the list were ordered by a product's common chemical name and variations of it, wherein the
name is repeated within the names of other products. By simply looking at the chemical name,
or some part of it, the user can find the product in one or more places (by cross-reference) in the
combined list.
11
-------
Criteria Used to Compile and Order the Combined List of Organic Chemicals
1. Products are listed in alphabetical order, using the common name. In determining order,
locants (numbers) and other designations in the product name were not considered. For
example, the 2- of 2-Butene was ignored, as was the tert- of tert-Buty\ alcohol.
Alternate names frequently used are shown parenthetically immediately after the
common name.
2. Product Name Groups
a. Products that have the name of a parent chemical incorported as a prefix or suffix
within their respective names are grouped with the parent chemical. For example,
listed under Benzene are: Benzenesulfonic acid and Divinylbenzene. In referring
to this name group, the index shows a line entry of : Benzene, Benzene-,
-benzene. To find this name group in the index, the user must recognize the
parent name "benzene" within the product name.
b. Products sharing a common suffix within their names were grouped together. For
example, listed under Acetates are: Ethyl acetate and Vinyl acetate. In referring
to this name group, the index shows a line entry of: -acetate. To find this name
group in the index, the user must recognize the suffix "acetate" within the product
name.
c. Products sharing a common generic suffix in their names were grouped together.
For example, listed under ACIDS, ALCOHOLS, and ALDEHYDES respectively
are: Acetic acid, Ethyl alcohol, and Renzaldehyde. To find these name groups in
the index, the user must recognize the generic suffixes "acid", "alcohol," and
"aldehyde" within the product names.
d. Products were also grouped together under non-specific commercial names, such
as Coal Tar Products, Flavors and Fragrances (Aroma), CFC's, etc.
3. All Subpart F and Subpart G products were listed individually, as well as being
referenced to one or more name groups. Generally, Subpart H products were listed under
name groups. Only Subpart H products that do not fit under a name group were listed
individually.
in
-------
Index to Organic Chemical Products Classified in Subparts F,G,H
Product Name-, -name-, -name Page
Acetal A-l
Acetaldehyde
Acetaldol
Acetamide, -acetamide, Acetamido-, -acetamido-
Acetanilide, -acetanilide
-acetate
Acetic acid, -acetic acid, -acetic- A-2
Acetoacetanilide, Acetoacet-
-acetoacetate
Acetone, Acetone-, -acetone
Acetonitrile
Acetophenone
Acetylacetone, -acetylacetonate
Acetyl chloride, -acetyl chloride
Acetylene
Acetylenic alcohols (-ynol), Acetylenic diols (-yndiol)
ACIDS (-ic,-oic) A-3
Acrolein, -acrolein A-4
Acrylamide, -acrylamide
-acrylate, Acrylic acid, -acrylic acid, -acrylic-
Acrylonitrile
-adipate, Adipic acid
Adiponitrile
ALCOHOLS (-ol)
Alcohol sulfates A-5
ALDEHYDES (-al)
n-Alkanes A-6
Alkoxyalkanols
Alkylamines
Alkylates (alkylbenzenes)
Alkylates (for gasoline)
Alkylbromides
Alkylphenols
Allene
Allyl-
AMIDES (-amide)
AMINES (-amine) A-7
Aminobenzoic acid
Aminophenols
Ammonium salts (Quaternary)
Amyl chloride
Aniline, -aniline, Anilino- A-9
IV
-------
Product Name-, -name-, -name Page
Anilides, -anilide
Anisidine, -anisidine, Anisidino-
Anisole, -anisole
Anthranilic acid, -anthranilic acid
Anthraquinone, -anthraquinone
-anthrone
Aspirin A-10
Azelaic acid, -azelaic-, -azelate
Aziridine, -aziridine
Azobenzene,-azobenzene
Azobis-
Azoxybenzene
Benzene, Benzene-, -benzene
-benzidine
Benzil
Benzilic acid
-benzimidazole A-l 1
-benzoate
Benzoic acid, -benzoic acid
Benzoin
Benzofuran, -benzofuran
Benzonitrile
Benzophenone, -benzophenone
Benzoquinone
-benzothiazole
-benzothiazolesulfenamide
Benzotriazole, -benzotriazole A-12
Benzotri-, -benzotri-
Benzoyl-, -benzoyl-
Benzyl-, -benzyl-
Biphenyl, -biphenyl
Biphenylamine, -aminobiphenyl
Bisphenol A, -Bisphenol A
Bromobenzene, -bromobenzene
Bromoethylbenzene, -bromoethylbenzene
Bromomethanes, -bromomethane
BTX (benzene, toluene, xylene)
Butadiene, -butadiene A-13
Butane, Butane-, -butane
Butanol
Butene (Butylene), -butene
Butoxy-
Butyl-, Butylene (Butene)
v
-------
Product Name-, -name-, -name Page
Butyraldehyde
-butyrate, Butyric acid, Butyric acid-
Butyrolactone
Caprolactam
-carbamate
-carbinol
Carbon-
-carbonate
Castor oil A-14
Cellulose-, -cellulose
Cetyl-
Chelating agents
Chloral, Chloral- A-15
Chloramine
Chlorendo-, -chlorendo-
-chloride A-16
Chlorinated paraffins
-chloroacetate, Chloroacetic acid
Chlorobenzene, -chlorobenzene
Chloro-( )-cresol
Chloroethane, -chloroethane
-chloroethylene
Chlorofluorocarbons (CFC's)
Chloroform, -chloroformate, -chlorothioformate A-17
-chlorohydrin
Chloromethanes
Chloronitrobenzene, -chloronitrobenzene
Chlorophenol, -chlorophenol
Chloropicrin
Chloroprene
Chloropropane, -chloropropane
Chlorotoluene A-l 8
Choline chloride
-citrate, Citric acid
Coal tar products
-coconates, Coconut oil-
Concentrates (Hydrocarbon)
Cresol (Cresylic acid), -cresol, Cresyl- A-19
Cumene, Cumene-, Cumic-
Cyanamide
-cyanoacetate
Cyanogen, Cyanogen-
-cyanurate
Cyanuric-
VI
-------
Product Name-, -name-, -name Page
Cyclamen aldehyde
-cycloheptadiene
Cyclohexane, Cyclohexane-, -cyclohexane, Cyclohexyl-
-cyclooctadiene
-cyclopentadiene
Cyclopentane, Cyclopentanol, Cyclopentyl- A-20
Cyclopropane-, -cyclopropane, Cyclopropyl-
Decane, -decanoate, Decanoic_acid, Decanol
Decene
Decyl-
Diacetone alcohol
-diazene
Dibenzylazocarboxylate
Dichloro-
Diethano-, Diethyl-
Diiso-
Dimer acid
Dimethylhexadiene, Dimethylhexane-, Dimethylhexyne
Dimethylphthalate, Dimethylterephthalate A-21
Dinitros obenzene
Dinitrotoluene
-diol
Dioxane
Dioxolane, -dioxolane, -dioxolane-
Diphenylamine, -diphenylamine
Dipropylene glycol
-dithiocarbamate, -dithiocarbamato-
Disalazane
Dodecane, -dodecanoate, Dodecanoic acid, Dodecanol A-22
Dodecene
Dodecyl-
Dyes
Epichlorohydrin
Epoxidized-
Erythritol- A-23
Ethane, -ethane
Ethanol, -ethanol
Ethanolamine, -ethanolamine, -aminoethanol
ETHERS A-24
Ethoxy-, -ethoxylate
Ethyl- A-25
Ethylbenzene, -ethylbenzene
Ethy Ibuty ral dehy de
Ethylene, -ethylene
vn
-------
Product Name-, -name-, -name Page
Ethylenediamine, Ethylenediamine-, -ethylenediamine
Ethylene dichloride
Ethylene glycol
Ethylene oxide
Ethylene-
Ethylenimine
Ethylhexaldehyde
-ethylhexanoate, Ethylhexanoic acid, Ethylhexanol, Ethylhexanoyl-
Fats
Fatty acids, salts, esters A-26
Fatty amides, amines, nitriles
Flavor & Fragrance Chemicals
Fluorocarbons A-29
Formaldehyde, Formaldehyde-
-formate, Formic acid
Furan, -furan
Furfural, Furfuryl-
-furoate, Furoic acid, Furoyl-
Glucoheptonic-
Glutamic-
Glycerine, Glyceryl-
Glycidol, Glycidyl-
Glycine
Glycolic acid, Glycolonitrile
GLYCOLS, Monoethers, Diethers A-30
GLYCOL Polyethers, Esters A-31
Glyoxal
-guanidine-
Guar
Heptachlor-
Heptane, Heptene, -hexadecanoate, Hexadecanoic acid, Hexadecene
Hexamethylene-
Hexamethylphosphoramide
Hexane
-hexanoate, Hexanoic acid
Hexene
Hexyl-
-hydantoin
Hydrazine, Hydrazine-, -hydrazine A-32
Hydrocarbons C-4
Hydrocarbons C-5, C-6, C-7, C-9, C-8 to C-18
-hydroperoxide
Hydroquinone, -hydroquinone A-33
Vlll
-------
Product Name-, -name-, -name Page
Imidazole, -imidazole
Indene
Isatoic anhydride
Isobutanol
Isobutylene, -isobutylene
Isobutyraldehyde
-isobutyrate, Isobutyric acid, -isobutyric acid
-isocyanate, -isothiocyanate
-isocyanurate, Isocyanuric acid, -isocyanuric acid
Isophorone
-isophthalate, Isophthalic acid, Isophthalo-, Isophthaloyl- A-34
Isoprene
Isopropanol, -isopropanol, Isopropyl-
Isovalerone
Ketene, -ketene
KETONES
-lactate, Lactic acid
-laurate, Laurie acid, Lauroyl-, Lauryl-
Lignin A-35
Lutidine
-maleate, Maleic acid, -maleic acid
Mannitol
Melamine
Menthane
-mercaptan (-thiol)
Mercapto-
Mesitylene, Mesityl- A-36
Metal Alky Is
Metanilic-
-methacrylate
-methacrylamide, Methacrylic acid
Methallyl-
Methane, -methane
Methanol
Methionine
Methoxy- Methylal A-37
Methylamine, -methylamine
-methylate
Methyl-
Methylenebis-, Methylene-
Morpholine, Morpholine-, -morpholino-, Morpholinyl- A-38
-myristate, Myristic acid
Myristyl-
IX
-------
Product Name-, -name-, -name Page
Nadic anhydride, -nadic anhydride
Naphtha
Naphthalene, -naphthalene, -naphthalene-
Naphthalenesulfonic acid, -naphthalenesulfonic acid
-napthenate, Naphthenic acid A-39
-naphthoate, Naphthoic acid
Neopentyl-, -neopentyl-
-nitrile
Nitrilo-
-nitrite
Nitroaniline, -nitroaniline
Nitrobenzene, -nitrobenzene
Nitrophenol, -nitrophenol
Nitroso( )amine, -nitroso( )amine
Nitrotoluene, -nitrotoluene A-40
Nonene
Nonylphenol, -nonylphenol
Nylon salt
Olefins (-ene)
Oleamide, -oleate, Oleic acid
Organo-Metallics
-oxalate, Oxalic acid
Oxo Process Chemicals (Acids, Alcohols A-41
Oxo Process Chemicals (Aldehydes)
-palmitate, Palmitic acid, Palmitoyl-
-pamoate, Pamoic acid
Paraffins
Pentachlorophenol (PCP)
Pentaerythritol, -pentaerythritol
Pentane A-42
Pentene, -pentene
Perchloroethylene
-peroxide, -peroxy-
-peroxy carbonate
Perylene-
Petroleum sulfonate
Phenethyl-
Phenetidine
Phenol, -phenol, -phenolate, Phenolsulfonic-
Phenoxyethanol A-43
-phenylacetate, -phenylacetic acid, Phenylacetyl-
Phenylenediamine, -phenylenediamine
Phenylethyl-
x
-------
Product Name-, -name-, -name Page
Phosgene
-phosphate
Phosphines A-44
-phosphinic, -phosphino-, -phosphite
-phosphonate, -phosphonic-, -phosphono-
-phosphonium- A-45
-phosphorothioate, -phosphorothioic-
-phthalate, Phthalic acid A-46
Phthalic anhydride, -phthalic anhydride
Phthalimide, -phthalimide, Phthalo-, Phthaloyl-
Picoline
Picric acid
Pigments
Pinane, Pine oil, Pinene A-47
Piperazine, -piperazine
Piperylene
Pitch
Pivalic acid, Pivaloyl-
Poly-
Propane, -propane A-48
Propanol, -propanol
Propene (Propylene), -propene
Propionaldehyde
-propionate, Propionic acid, -propionitrile
-propoxylate
Propyl-, Propylene- A-49
Pyridine, -pyridine
Pyrimidine
Pyrogallol
Pyrolysis gasoline
Pyrone
Pyrrole
Pyrrolidinone, -pyrrolidinone, -pyrrolidone
Quinaldine
Quinoline, -quinoline
Quinone, Quinone-, -quinone-, -quinoxaline
-ricinoleate
Resorcinol, Resorcylic-
Salicylaldehyde
Salicylanilide
-salicylate, Salicylic acid
-sebacate, Sebacic acid A-50
Semicarbazide, -semicarbazide
XI
-------
Product Name-, -name-, -name Page
-silane
Silicone-
Solvents
Sorbic acid, Sorbitol
Soybean oil
Spirogermanium
Starch
Stearamide
-stearate
Stearic acid, Stearyl- A-51
Stilbene, -stilbene
Styrene, Styrene-, -styrene
-succinate, Succinic acid, -succinic acid
Succinic anhydride, -succinic anydride, -succinimide
Succinonitrile
Sulfanilic-, -sulfanilic-
-sulfate, -sulfide
-sulfoethoxylate, -sulfosuccinate
Sulfolane, Sulfolene
-sulfonamide
-sulfone, -sulfonic acid, -sulfoxide A-52
-tallowate
Tars
-terephthalate, Terephthalic acid, -terephthalic acid, Terephthaloyl-
Terpene oil
Tetra-( )-ammonium-, Tetra-
Tetralin
Tetralol, Tetralone, -tetralone
-thiazole
Thiobis-
-thiodipropionamide
-thiodipropionate, Thiodipropionic acid A-53
-thionocarbamate
Thiophene, Thiophene-, -thiophene, -thiophenol
-thiourea
Thiram
Toluene, -toluene
Toluenesulfonic acid, Toluenesulfonyl-
-toluate, Toluic acid
Toluidine, -toluidine
Tolylenediamine, Tolylene- A-54
Toxaphene
Triacetin
-triazine
xn
-------
Product Name-, -name-, -name Page
Triazole, -triazole
Tri-
-trimellitate, Trimellitic acid
Trimethylpentane-
Trimethylolpropane, Trimethylolpropane-
-triphenyl
Triphenylmethane, -triphenylmethane
-urea
Urethane- A-55
Vegetable oil
Vinyl-, Vinylidene-
Wax
-xanthate
Xylene, Xylenesulfonic-
Xylenol
Xylidine
Abbreviations and Explanatory Notes
Xlll
-------
Combined List of OCPSF Organic Chemical Products
Organic chemical product3
Subpartb Remarks and Cross-references
Acetal (1,1-Diethoxyethane)
Acetaldehyde
Acetaldol (3-Hydroxybutyraldehyde)
H
F
H
See ALDEHYDES
See ALDEHYDES
Acetamides H*
Acetamidothymol H
(2-Isopropyl-5-methyl-6-acetara'c/ophenol)
N-mQthylacetamide H*
Acetanilide H
Acetanilides H
p-Aminoacetanilide H
p-Methy\acetanilide ( p-Acetotoluidide) H*
p-Nitroacetanilide H
Acetates (acetic acid esters):
Amyl acetates
Amyl acetate
Isoamyl (isopentyl) acetate
Benzyl acetate
2-Butoxyethyl acetate
2-(2-butoxyethoxy) ethyl acetate
n-Butyl acetate
fert-Butyl psracetate
Diazoacetic ester (Ethyl diazoacetate)
Dodecylguanidine acetate
2-(2-ethoxyethoxy) ethyl acetate
Ethyl acetate
Ethyl bmmoacetate
Ethyl oxaloacetate, sodium
(Ketosuccinic acid, ethyl ester, salt)
Ethylene glycol diacetates
2-Ethylhexyl acetate
Glyceryl triacetate (Triacetin)
Isobutyl acetate
Isopropyl acetate
Methallylidene diacetate
(Methacrolein diacetate)
2-Methoxyethyl acetate
Methyl acetate
n-Propyl acetate
Propylene glycol ether acetates
Triethylene glycol diacetate
H
H*
H
H
H
H
G
H*
H
H
H
H
H*
H
H
H*
H*
G
G
H
H
H
G
H*
H*
See Flavors & Fragrances
See Flavors & Fragrances
See GLYCOL Esters
See GLYCOL Esters
See Peroxyesters
See Guanidines
See GLYCOL Esters
See GLYCOL Esters
See GLYCOL Esters
See GLYCOL Esters
See GLYCOL Esters
A-l
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Acetates, esters (continued)
Vinyl acetate F
Acetates, salts: Calcium, Chromium, Cobalt, H
Copper, Lead, Magnesium, Manganese,
Sodium, Zinc.
Ammonium acetate H*
Sodium ftuoroacetate H
Acetic acid F
Chloroacetic acid (MCA) H
Cyanoacetic acid H
Dehydmacetic acid (Methylacetopyranone) H*
Iminodiaceft'c acid (Diglycine) H
Nitrilotriaceft'c acid (NTA) G
Pemcetic acid H
Phenoxyaceft'c acid H*
Phenylacetic acid and esters H*
Thioaceft'c acid H*
Thiopheneaceft'c acid H
Trichloroaceft'c acid H
Trifluoroaceft'c acid H
Acetic anhydride F
Trifluoroaceft'c anhydride H*
See ACIDS Monocarboxylic
See Chelating agents
See Hydroperoxides
See Flavors & Fragrances
Acetoacetanilide
Acetoacetanilides
Acetoacet-o-anisidine
(o-MQthoxyacetoacetanilide)
Acetoacet-o-toluidide
Acetoacet-m-xylidide
Acetoacetates:
Ethyl acetoacetate (Acetoacetic ester)
Methyl acetoacetate
H
H
H*
H*
H*
H
H
Acetone
Acetone cyanohydrin
Chlomacetone
Hexafluoroacefcwe
F
G
H
H*
See KETONES
Acetonitrile
Acetophenone
Acetylacetone (2,4-Pentanedione)
Acetylacetonates, metal salts:
(Chromium, Cobalt, Copper, Zinc)
Acetyl chloride
Dichloroace/^/ chloride
Acetylene
Acetylenic alcohols
H
H
H**
H**
H
H*
G
H
See Nitriles
See KETONES, Flavors & Fragrances
See KETONES
A-2
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Acetylenic alcohols (continued)
3-Methylbuty«-3-o/ H
Methylpenty«o/ (3 -Methyl-1 -pentyn-3 -ol) H
Propargyl alcohol (2-Propy«-l-o/) H*
Acetylenic diols H
l,4-Buty«e^/o/(2-Butyne-l,4-diol) H
See ALCOHOLS
See ALCOHOLS
See ALCOHOLS
See Diols
ACIDS (aliphatic monocarboxylic)
Acetic acid F
Acrylic acid G
Butyric acid G
Chloroacetic acid H
Crotonic acid (fra«s-2-Butenoic acid) H
Decanoic acid (Capric acid) H*
Dodecanoic acid (Laurie acid) H
Ethylbutyric acid H
2-Ethylhexanoic acid H
2-Ethylhexanoates, metal salts: H**
(Chromium, Cobalt, Lead, Tin, Zinc)
Formic acid H
Gallic acid (3,4,5-trihydroxybenzoic acid) H*
Heptanoic acid (Enanthic acid) H*
Hexanoic acid (Caproic acid) H
Isobutyric acid H*
Metanilic acid G
Methacrylic acid G
Neodecanoic acid H*
Neoheptanoic acid H*
Neopentanoic acid (Pivalic acid) H
Octanoic acid (Caprylic acid) H*
Pelargonic acid (Nonanoic acid) H*
Propanoic acid (Propionic acid) G
2-Hydmxypropionic acid (Lactic acid) H
Sorbic acid (2,4-Hexadienoic acid) H
n-Valeric acid (Pentanoic acid) H*
See Acetic acid
See Oxo Acids
See Oxo Acids
See
See
See
Oxo Acids
Oxo Acids
Oxo Acids
See Oxo Acids
See Oxo Acids
ACIDS (aliphatic dicarboxylic)
Adipic acid F
Azelaic acid H*
Decanedioic acid (Sebacic acid) H*
Fumaric acid H
Glutaric acid H*
Maleic acid H
Malic acid (Hydroxysuccinic acid) H
Malonic acid (Propanedioic acid) H*
Oxalic acid G
Succinic acid H*
Ketosuccinic acid (Oxaloacetic acid) H*
A-3
-------
Organic chemical product"
Acrolein
Methacrolein
Acrylamide
N-MQthylolacrylamide
Polyacrylamide
Polyacrylamide-Acrylic acid (copolymer)
Acrylates (acrylic acid esters):
n-Butyl acrylate
Diethylaminoethyl acrylate
Dodecenyl acrylate (Lauryl acrylate)
Ethyl acrylate
Ethylene glycol diacrylates
2-Ethylhexyl acrylate
Hydroxyethyl acrylate
Hydroxypropyl acrylate
Isobornyl acrylate
Isobutyl acrylate
Isodecyl acrylate
Methoxyethyl acrylate
Methyl acrylate
Methyl 2-cyanoacrylate
Pentaerythritol acrylates
Phenoxyethyl acrylate
Propylene glycol diacrylates
Tetraethylene glycol diacrylate
Tetrahydrofurfuryl acrylate
Tripropylene glycol diacrylate
Acrylic acid
Polyacrylic acid
Polyacrylate, sodium
Acrylonitrile
Adipates (adipic acid esters)
Di(2-Ethylhexyl) adipate
Diisodecyl adipate
Diisopropyl adipate
Ditridecyl adipate
n-Octyl, n-Decyl adipate
Adipic acid
Adiponitrile
ALCOHOLS
Amyl alcohols
n-Amyl alcohol (1-pentanol)
tert-Amyl alcohol (2-Methyl-2-butanol)
Isoamyl alcohol (Isopentanol)
Subpartb
H
H
H
H*
H*
H*
H
H*
H*
G*
H*
G*
H*
H*
H*
H*
H*
H*
G*
H
H*
H*
H*
H*
H*
H*
G
[H]
[H*]
F
H
H
H
H*
H
H
F
G
H
H*
H*
H
Remarks and Cross-References
See GLYCOL Esters
Tradename: Mecrylate
See GLYCOL Esters
See GLYCOL Esters
OCPSF has designated these two polymers as
PLASTICS (Subpart D), but they are classified in
commerce as an organic chemical.
Use: Plasticizers
See Oxo Alcohols
See Oxo Alcohols
A-4
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Benzyl alcohol H
m-Phenoxy&enzy/ alcohol H
a-Methy\benzyl alcohol H*
Butyl alcohol (n-Butanol) G
n-Decanol (n-Decyl alcohol) G
Diacetone alcohol G
1-Dodecanol (Dodecyl alcohol) G*
Ethyl alcohol (Ethanol, by fermentation) X
Ethyl alcohol (Ethanol, by synthesis) G
2-Ethylhexanol (2-Ethylhexyl alcohol, C-8) G
Hexadecanol (Hexadecyl or Cetyl alcohol) H
n-Hexanol (n-Hexyl alcohol) H*
2-Hexanol (1-methyl H*
Isobutanol (Isobutyl alcohol) G
Isodecanol (Isodecyl alcohol) H
Isohexanol (Isohexyl alcohol) H*
Isononanol (Isononyl alcohol) H*
Iso-octanol (Iso-octyl alcohol) H
Isopentyl alcohol (Isoamyl alcohol) H
Isopropyl alcohol (Isopropanol) F
Lauryl alcohol (Dodecanol) G*
3-Methylbutyn-3-ol H
Methylpentynol H
1-Octadecanol (Octadecyl alcohol) H*
n-Octanol (n-Octyl alcohol) H*
Primary alcohols (C12- CIS) ->
Propargyl alcohol H*
n-Propanol (n-Propyl alcohol) G
1-Tetradecanol (Myristyl alcohol) H*
1-Tridecanol (Tridecyl alcohol) H*
Tribromoneopentyl alcohol H
See Flavors & Fragrances
See Oxo Alcohols
OCPSF not applicable (414.11e)
See Oxo Alcohols
See Oxo Alcohols
See Oxo Alcohols
See Oxo Alcohols
See Oxo Alcohols
See Oxo Alcohols
See Oxo Alcohols
See 1-Dodecanol
See Acetylenic alcohols
See Acetylenic alcohols
See Stearyl alcohol
See Flavors & Fragrances
Dodecanol, Tetradecanol, Hexadecanol, Octadecanol
See Acetylenic alcohols
See Oxo Alcohols
Alcohol Sulfates:
Hexyl alcohol sulfate, sodium
Lauryl alcohol sulfate, sodium
Octyl alcohol sulfate, sodium
[H] Surface active agents. May be regulated by Part 417,
[H] if reported under SIC 2843 (414.11 c)
[HI Surface active agent.
ALDEHYDES
Acetaldehyde F
Chloroacetaldehyde H
Trichlomacetaldehyde (Chloral) H
3-Hydro~xyacetaldehyde (Acetaldol) H
Phenylacetaldehyde, dimethylacetal H
Benzaldehyde H
o-Anisaldehyde (o-Methoxybenzaldehyde) H*
m-Phsnoxybenzaldehyde H
m-Rmmobenzaldehyde H*
See Flavors & Fragrances
A-5
-------
Organic chemical product"
Benzaldehydes (continued)
Chlorobenzaldehyde
p-Dimethy\ammobenzaldehyde
n-Butyraldehyde
Crotonaldehyde (fra«s-2-Butenal)
Cyclamen aldehyde
2-Ethy Ibuty ral dehy de
2-Ethylhexanal (2-Ethylhexaldehyde)
Formaldehyde
Isobutyraldehyde
Propionaldehyde
Salicylaldehyde
n-Valeraldehyde
n-Alkanes
Alkoxyalkanols
Alkylamines
Alkylates (alkylbenzenes):
Dodecylbenzene (branched, "hard")
Dodecylbenzene (linear, "soft")
Alkylbenzenesulfonic acids, salts
Dodecylbenzenesulfonate, Sodium
Alkylates (for gasoline)
Alkyl bromides:
Bromomethanes
Butyl bromide (1-Bromobutane)
Ethyl bromide (1-Bromoethane)
Alkylphenols, mixed
Allene (Propyne)
Allyl chloride
Allyl alcohol
Allylnitrile
Allylsulfonate, sodium
Alpha-olefins
AMIDES
Aceiamide
N,N-Dimethylacetom/'t/e
fluomacetamide
Thioacetamide
Arylamides
Benzamide (an arylamide)
N,N-Diethanol stearamide
N,N'-Ethylene bis(o\Qamide)
Subpartb
H
H*
G
H
H
G
H*
F
G
G
H
H
->
->
->
G*
G*
[G]
[H]
X
H
H*
H
G
H
G
H
H
H**
->
H
H*
H
H
H
H
H
H*
Remarks and Cross-References
See Oxo Aldehydes
See Flavors & Fragrances
See Oxo Aldehydes
Three commercial forms: Formalin (aq. 35-55% soln);
Trioxane (cyclic trimer); Paraformaldehyde (polymeric)
See Oxo Aldehydes
See Oxo Aldehydes
See Flavors & Fragrances
See Oxo Aldehydes
See Hydrocarbons
See GLYCOL, monoethers
See AMINES
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.1 1c).
A refinery product regulated by Part 419 and reported
under SIC 291 1 . OCPSF not applicable (414.1 1 c).
See Methyl bromide, Dibromomethane, Bromoform
See Phenol
See Olefins, alpha
See Benzamide
A-6
-------
Organic chemical product"
Subpartb Remarks and Cross-References
AMIDES (continued)
N,N'-Ethylene bis(stQaramide)
Formamide
N-MQthylformamide
N,N-Dimethyl/orraa»7/t/e (DMF)
Long-chain amides, N-ethoxysulfates
H
H
H*
G
[H]
Surface active agent. May be regulated by Part 417,
if reported under 2843 (414.11 c).
(Nicotinic acid amide)
Oxamide
Steammide
X
H*
H*
Medicinal chemical (Vitamin). Regulated by Part 439
and reported under SIC 2833 (414.11d).
AMINES
n-Amyla™«e
Benzylaffwne
N,N-Dimethylbenzyla™«e
N-Ethyl-N-phenyl benzylamine
N-Methylbenzylara/'«e
Biphenylara'nes (^4ra/'«obiphenyls)
l,4-Butanediara/'«e (l,4-Diara/'«obutane)
Butylamines:
n-Butylara'«e
N-Ethyl-n-butyla™«e
sec-Butylamine
tert-Rutylamine
Tri-n-butylara/'«e
N-EHhylcyclohexylamine
N-Methy\cyclohexylamine
Cyclopropylamine
Dicyclohexylara/'«e
Diethyl-2-chloroethyl amine
(N-[2-chloroethyl] diethylam/'«e)
N,N-Diisopropylethylara/«e
Dimethylbutylam/'«e
N,N-Dimethyl-l,3-propanediara/«e
Diphenylamine (N-Phenylaniline)
Di-n-propylamine
Dodecylamine
H
H
H
H*
H
H*
H
H*
G
H*
H*
G
G
H*
H
H*
H*
H*
H
H
H
H*
H*
H*
G
H
H*
G
H*
H
See Biphenyl
See Methylamines
See Diphenylamine
A-7
-------
Organic chemical product"
Subpartb Remarks and Cross-References
AMINES (continued)
Ethylamine G
Ethylene diamine G
Polyethylene polyamines H
2-Heptylamine (2-Aminoheptane) H*
l,6-Hexanediara/«e G
Hexamethylenetetra™«e H
n-Hexylamine H*
Hydro-xylamine H
Isobutyla™«e H*
4-Isopropoxydiphenylam/'«e H
Isopropylara/'«e G
Mechlorethara'ne H
(bis [2-chloroethyl] methylamine)
Melamine G
Methylamine G*
N-Methylhydroxylara'«e : HC1 H
N-l-Naphthylethylenedia/M/«e : 2HC1 H
NitawH'nes (Tetryl, RDX, HMX, NQ) X
Pentylara/'«e (Amylamine) H*
Phenethylara/'«e (p-^4ra/'«oethylbenzene) H*
Phenylethyla™«e (a-Methylbenzylara/'«e) H*
Phenylenediara/'«e ->
See Ethyleneamines
See Ethyleneamines
See Methylamines
Explosives. Regulated by Part 457 and reported under
SIC 2892 (414.11d).
See Phenylenediamines
Phenylhydroxyla™«e
N-Phenyl-2-naphthylara/'«e
n-Propylara/'«e
Tetramethylenedia»7/«e
Toluene diamines (TDA)
Triallylara/'«e
Triethylara/'«e
Triethylenediara/'«e
Trimethyla™«e
ra-Aminobenzoic acid
/7-Aminobenzoic acid
Aminobenzotrifluoride
2-Aminoethanol (Monoethanolamine)
2-Aminoethyl hydrogen sulfate
Aminophenols:
o-, p-Aminophenol
m-Dimethy\aminophenol
N-stearoyl-p-aminophenol
Ammonium salts (quaternary salts)
Amyl chloride
H
H
H
H
G
H
H
H
G
G
G
H**
G
H
H
H
H*
->
H
See Tolylene diamines
See Methylamines
See Benzole acid
See Benzole acid
See Ethanolamines
Used for rubber processing.
See Tetraalkylammonium salts.
A-8
-------
Organic chemical product"
Aniline
^4«/7/«omethanesulfonic acid
o-, m-, p-Chloroaniline
3,4-Dichloroaniline
N,N-Diethylo«/7/«e
2,6-DiQthylcmi7ine
2,6-DimQthylaniline
N,N-Dimethyla«/7/«e
N,N-Dimethyl-4-nitrosoa«/7/'«e
2,4-Dinitroa«/7/«e
N-Ethyla«/7/'«e
N,N-Ethylbenzyla«/7/'«e
(N-Ethyl-N-phenylbenzylamine)
o-Ethy\aniline (o-Aminoethylbenzene)
4-Fluoro-3 -nitroanilme
4-(N-Hydroxyethylethylamino)-
2-hydroxy ethyl aniline
N-Methyla«/7/'«e
p-(Phenylazo) aniline
Nitroanilines, mixed
p-Nitroaniline
o-, m-Nitmaniline
4,4'-O~xydianilme
2,4,5 -Trimethy la«/7/'«e
Anilides:
Malodia«/7/'Je
Salicylanilide
Anisidine (o-, p-Methoxy aniline)
Dianisidine (di [methoxy phenyl] amine)
o-^4«/5/J/'«omethanesulfonic acid
Anisole (Methoxybenzene)
o-, p-Nitmanisole
Anthranilic acid (o-Aminobenzoic acid)
N-phsnylanthranilic acid
Anthraquinone
1 -Amino-2-bromo-4-hy droxy-
anthraquinone
\,5-Dich\omanthraquinone
Anthrones:
1 6, 1 7-Dihydroxy violanthrone
(Dihydmxydibenzanthrone)
Arylesters
Subpartb
G
H*
H
H
G
H*
G
H
H
H
H*
H*
H*
H
G
H
H
G
H
H*
H*
H
H
H
H
H
H*
H
H
H
H
H
H
H*
H**
->
Remarks and Cross-References
See Xylidine
Dye intermediate
Dye intermediate
See Nitroaniline
See Nitroaniline
See Nitroaniline
Dye intermediate
Dye intermediate
Dye intermediate
See Benzole Acid
Dye intermediate
Dye intermediate
Pigment intermediate.
See Benzoates
A-9
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Aspirin (technical grade)
Aspirin (medicinal grade)
[H] Amended classification [55 FR 42337 (Oct. 18, 1990)]
X Medicinal chemical. See Salicylic acid. Reported under
SIC 2833 and regulated by Part 439 (414.11 d).
Azelaic acid
Polyazelaic anhydride
Azelates (azelaic acid esters):
Di(2-ethylhexyl) azelate
Di(n-hexyl) azelate
Aziridine (Ethylenimine)
2-MethylazTridine
1 -Aziridinesthanol
(N-Hydroxyethyl- oziridine)
Azobenzene (Diphenyldiazene)
4'-Aminoazo/>e«ze«e-4-sulfonic acid
2,3'-Dimethyl-4'-aminoazo/>e«ze«e
2,2'4'-Trihydroxy-5-chloroazo6e«ze«e-
2,2'-copper complex
1,1 '-^zobis(fbrmamide)
(Azodicarbonamide)
2,2'-^zobis(isobutyronitrile)(AIBN)
^4zoxy benzene
See ACIDS, Dicarboxylic
Used as a plasticizer for plastic products.
H*
H
H
H*
H*
H
H
H*
H*
H
H
H Used in rubber processing.
H*
H
Used in rubber processing.
Benzene F
Benzenediazonium chlorides H
ra-Benzenedisulfonic acid, diSodium G
Benzene phosphorus dichloride H**
Benzene phosphorus thiodichloride H**
Benzenesulfonic acid H
ra-Benzenedisulfonic acid, disodium G
Dodscylbenzene sulfonic acid, sodium H
Benzenesulfonyl chloride H*
1,4-Dibutoxybenzene H
l,4-Diethoxy/>e«ze«e H
m-Dimstho-xy benzene H*
p-Dimethoxybenzene (Hydroquinone ether) H*
Diisopropyl/?e«ze«e H
Divinylbenzene H
Fluorobenzene H*
Isobutylbenzene H*
l,3,5-Triisopropyl6enzene H*
Dye intermediate
Surface active agents. Regulated by Part 417,
if reported under SIC 2843 (414.11 c).
Surface active agent
Benzidines:
3,3'-Dich\ombenzidine : 2HC1
Benzil (1,2-Diphenylethanedione)
Benzilic acid
H
H
H
A-10
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Benzimidazoles:
6-Nitmbenzimidazole
H
Benzoates (benzoic acid esters):
n-Butyl benzoate
fert-Butyl perbenzoate
Benzyl benzoate
2,4-Di-tert-butylpheny 1-3,5 -di-
fert-butyl-4-hydroxy benzoate
Diethylene glycol, dibenzoate
Methyl benzoate
Propylene glycol, dibenzoate
Resorcinol monobenzoate
Benzoate salts:
Ammonium benzoate
Sodium benzoate
Benzoic acid
m-, p-Aminobenzoic acid
o-Aminobenzoic acid
p-tert-Butylbenzoic acid
Chlombenzoic acids
Diaminobenzoic acid
m-(N,N-dimethylamino) benzoic acid
3,5-Dinitrobenzoic acid
/>-Hydroxy benzoic acid
/>-Hydroxy benzoic acid esters (Parabens)
m-, o-, p-Nitmbenzoic acid
Thiobenzoic acid
Benzoin (Benzoylphenylcarbinol)
Benzofurans
Dibenzofuran
Benzonitrile
Benzophenone
2-Hydmxy-4-octy\oxybenzophenone
2-Hydro-xy-4-mQtho~xybenzophenone
Benzoquinone (Quinone)
p-Benzoquinone dioxime
Benzothiazoles:
2,2'-Dithio-bis(benzothiazole)(MBTS)
2-Mercaptobenzothiazole (MBT)
2-Msrcaptobenzothiazole, Zinc salt
2-(morpho\inothio)benzothiazole
Benzothiazolesulfenamides:
N-tert-Butyl-2-benzothiazole-sulfenamide
H*
H
H
H
H
H*
H*
H*
H*
H
G
G
H
H
H
H
H
H
H
H*
H
H*
H
H
H
H
H
H
H
H
H
H*
H*
H*
H
H*
See Peroxyesters
See Flavors & Fragrances
See GLYCOL Esters
See GLYCOL Esters
See Anthranilic acid
See Carbinols
See Flavor & Fragrances
Pigment intermediate
See Quinone
Used in rubber processing.
Used in rubber processing.
Used in rubber processing.
Used in rubber processing.
A-ll
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Benzothiazolesulfenamides (continued):
N-Cyclohexyl-2-benzothiazole-
sulfenamide
N-Oxydiethylene-2-benzothiazole-
sulfenamide
H Used in rubber processing.
H* Used in rubber processing.
Benzotriazole
1 -Hy droxy benzotriazole
Benzotrichloride
o-, p-Chlorobenzotrichloride
Benzotrifluoride
Benzoyl chloride
Chlorobenzoyl chloride
Benzyl chloride
a-Ethy\benzyl chloride
o-, p-Msthylbenzyl chloride
Benzyl cyanide
Benzyl dichloride (benzal chloride)
H
H*
H
H
H
H
H
G
H
H*
H
H
Biphenyl
Butyl biphenyl
Decabromobiphenyl
Dscabromobiphenyl oxide
Hexabmmobiphenyl
Isopropylbiphenyl
Tetrabromo-tetramethyl-
dihydmxy biphenyl
H
H*
H
H
H
H*
H
See ETHERS
Biphenylamines (aminobiphenyls) H
2-Biphenylamine (2-Aminobiphenyl) H
4-Biphenylamine (4-Aminobiphenyl) H
2,4'-Biphenyldiamine (2,4'-Diammobiphenyl) H
2-Nitro-4'-aminobiphenyl H
See AMINES
Bisphenol A
Tetrachloro bisphenol A
Bromobenzene
Hsxabromobenzene
Bromoethylbenzenes
Dibromoethylbenzene
Bromomethanes:
Bromochloromethane
Bromodichlommethane
Bromotriftuorome thctne
Dibromodifluommethane
Dibromomethane
G
H
H
H
H
H*
H
H
H
H
H
BTX (Benzene, Toluene, o-, m-, p-Xylenes)
A-12
-------
Organic chemical product"
Butadiene
2-Ch\ombutadiene
Hsxachlorobutadiene
Hexaftuombutadiene
n-Butane
1 ,4-Dibmmobutane
1,4-Butanediol
n-Butanol (Butyl alcohol)
sec-Butanol
fert-Butanol
1-Butene
2-Butene (cis & trans)
trans- 1 ,4-Dichloro-2-butene
2-Butoxyethanol
Butyl, octyl phthalate
n-Butyl acetate
n-Butyl acrylate
n-Butylamine
sec-Butylamine
fert-Butylamine
n-Butyl bromide
n-Butyl chloride (1-Chlorobutane)
Butylenes (mixed)
p-tert-Butylpheno\
n-Butyraldehyde
n-Butyraldehy de-aniline condensate
Butyrates (butyric acid esters)
n-Butyric acid
Butyric acid anhydride
Butyrolactone (gamma and beta)
Caprolactam
Carbamates
Carbinols:
Benzoylphenyl carbinol (Benzoin)
Methyl cyclohexyl carbinol
Methyl isobutyl carbinol
4,4'-bis (N,N-Dimethylaniline) carbinol
Carbon disulfide
Carbon tetrabromide
Carbon tetrachloride
Carbon tetrafluoride
Carbonates:
Ethylene carbonate (Glycol carbonate)
Diethylcar/>o«afe
Subpartb
F
H
H
H*
G
H*
G
G
G
G
G
G
H
G
G
G
H
G
G
G
H*
H
F
G
G
H*
H
G
G
H
G
H
H
H
H
H
G
H
G
H
H
H
Remarks and Cross-References
See Hydrocarbons C-4
See Hydrocarbons C-4
See Diols
See ALCOHOLS
See Hydrocarbons C-4
See Hydrocarbons C-4
See GLYCOL Monoethers
See Phthalates
See Acetates
See Acrylates
See AMINES
See AMINES
See AMINES
See Alkyl bromides
See Hydrocarbons C-4
See Phenol
See ALDEHYDES
Used in rubber processing.
See ACIDS
A-13
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Carbonates (continued):
Diphsnylcarbonate
H*
Castor oil
X Vegetable oil extracted from plants (414.11e).
Should be reported under SIC 2076.
Cellulose acetate butyrate
Cellulose Ethers:
Carboxymethyl cellulose, sodium
Carboxymethyl hydroxy ethyl
cellulose, sodium
Ethyl cellulose
Hydroxybutyl cellulose
Hydroxybutyl methyl cellulose
Hydroxyethyl cellulose
Hydroxyethyl ethyl cellulose
Hydroxyethyl methyl cellulose
Hydroxypropyl cellulose
Hydroxypropyl methyl cellulose
Methyl cellulose
Cellulose sponge
Cellulose, oxidized (market pulp)
Cellulose nitrate (Nitrocellulose)
Cellulose tetranitrate
Cetyl bromide (1-Bromohexadecane)
Chelating agents:
Diethylenetriaminepentaacetic acid
(DTP A) Metal salts: Iron [Ferric], Sodium
N,N-Dihydroxyethylg/jc/'«e
Ethanoldigfycine
Ethylenediaminetetracetic acid (EDTA)
and its metal salts (Cobalt, Copper, Iron,
Manganese, Potassium, Zinc)
N-Hydroxyethylethylenediamine-
triacetic acid (HETA) and its metal
salts (Iron, Manganese, Sodium, Zinc)
Nitrilotriacetic acid (NT A) and its metal
salts (Sodium)
Sodium glucoheptonate
Chloral hydrate (trichloroacetaldehyde)
Chloramine
Chlorendic acids & salts
Chlorendo compounds:
Bromo(cWore«£/o)cyclooctadiene
Chlorendocyclooctadiene
bis(cWore«Jo)cyclooctadiene
->
G
G
H
H*
H*
H
H*
H*
H*
H
H
X
X
X
X
H
H
H
H
G
H
G
H
H
H
H
H
H
H
See PLASTICS
Product deleted [55 FR 42339 (Oct. 18,
Should be reported under SIC 3089.
Regulated by Part 430 and reported
under SIC 2611 (414.1 1d).
Explosives. Regulated by Part 457 and
reported under SIC 2892 (414.1 1 .d).
See ALDEHYDES
Pesticide intermediates - not regulated
Pesticide intermediates - not regulated
Pesticide intermediates - not regulated
Pesticide intermediates - not regulated
1990)].
by Part 455.
by Part 455.
by Part 455.
by Part 455.
A-14
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Chlorendo compounds (continued)
bis(cWore«£/o)cyclopentadiene
H Pesticide intermediate - not regulated by Part 455.
H Pesticide intermediate - not regulated by Part 455.
Chlorides:
Acetyl chloride
Allyl chloride
Amyl chloride
Benzsnediazonium chlorides
Benzene phosphorus dichloride
Benzenssulfonyl chloride
Benzotrichloride
Benzoyl chloride
Benzyl chloride
Benzyl dichloride (Benzal chloride)
n-Butyl chloride (1-Chlorobutane)
Carbon tstrachloride
Choline chloride
Cyanogen chloride
Cyclohexyl chloride
Cyclopentyl chloride
n-Dodecyl chloride
Ethyl chloride
Ethylene dichloride
2-Ethylhexanoyl chloride
Ethyl phosphonothioic dichloride
2-Furoyl chloride
n-Hexyl chloride
Isophthaloyl chloride
Isopropyl chloride
Methallyl chloride
Methyl chloride
Methylene chloride
Methylmagnesium chloride
Palmitoyl chloride
Phenacetyl chloride
Phthaloyl chloride
Pivaloyl chloride
n-Propyl chloride
Propylene dichloride
Terephthaloyl chloride
Tetrakis(Hydroxymethyl)-
phosphonium chloride
Triethylene glycol dichloride
Trimethylbenzylammonium chloride
Vinyl chloride
H
G
H
H
H**
H*
H
H
G
H
H
G
H
G
H*
H*
H*
G
F
H*
H
H*
H*
H
H
H
G
G
H**
H*
H
H
H*
H
H
H
See Dyes, Azoic diazo
See Phosphorus organics
See Benzene
See Cyclohexane
See Chloroethanes
See Chloroethanes
See Phosphonic acid
See Methane
See Organo-Metallics
See Chloropropanes
See Chloropropanes
H See Phosphonium salts
H* See GLYCOLS
H** See Tetraalkylammonium salts
F
A-15
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Chlorides (continued)
Vinylidene chloride
See Chloroethylenes
Chlorinated paraffins (wax, 35-64% Cl) G
Chlorinated paraffin sulfonate H
Chloroacetates (esters and salts):
Ethyl chloroacetate
Methyl chloroacetate
Sodium chloroacetate (salt)
Chloracetic acid
H
H*
H
H
Chlorobenzene
Chlorobenzenes (mixed isomers)
o-, m-, p-Dichlorobenzene
Psntachlorobenzene
Tetrachlorobenzene
Trichlorobenzene
G
G
H
H
H*
H
Chloro-m-cresol
Chloroethanes:
Chloroethane (Ethyl chloride)
\,2-Dichloroethcme (Ethylene di chloride)
Hexachloroethcme
See Chlorophenols
1,1. 2,2-T 'etrachloroethcme
Tetrafluorodichloroethane
1,1,1-Tnchloroethane (Methylchloroform)
1,1,2-Trichloroethane
1 ,2,2-Trifluoro- 1 , 1 ,2-tnchloroe thane
G
F
H
H
H
H
G
H
H
H
Chloroethylenes:
\,2-Dichloroethylene H
Tetrachloroethylene (Perchloroethylene) G
^Inchloroethylene G
1, \-Dichloroethylene (Vinylidene chloride) H
See Vinylidene chloride
Chlorofluorocarbons (CFC's):
Chlorodifluororae^awe (HCFC-22) G
Chloropentafluoroe^ane (CFC-115) H*
Chlorotrifluororae^awe (CFC-13 ) H
Chlorotrifluoroe%/e«e (CFC-123) H*
Dichlorodifluorome^awe (CFC-12 ) H
Dichlorofluororae^ane (HCFC-21) H
l,2-Dichlorotetrafluoroe^a«e (CFC-114) H*
1,1 -Difluoro-1,1,2-trichloroe^a«e H*
Trichlorofluororae^/7a«e (CFC-11 ) G
"Freon" is a DuPont Trademark
Production of this CFC restricted or banned in U.S.
Production of this CFC restricted or banned in U.S.
A-16
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Chloroform (trichloromethane)
Chloroformates:
Benzyl chloroformate
sec-Butyl chloroformate
Ethyl chloroformate
Ethyl chlorctf/H'oformate
2-Ethylhexyl chloroformate
Isobutyl chloroformate
Isopropyl chloroformate
Methyl chloroformate
Phenyl chloroformate
G
H
H*
H*
H*
H*
H*
H*
H*
H*
H*
Chlorohydrins:
Dichlorohydrin (2,3-Dichloropropanol) H
Ethylene chlorohydrin (2-Chloroethanol) H
Monochlorohydrin H
(3 -Chloro-1,2-propanediol)
Propylene chlorohydrin (2-Chloropropanol) H
Chloromethanes
Carbon tetrachloride, Chloroform, Methyl chloride,
Methylene chloride.
Chloronitrobenzenes:
/•-Chloronitrobenzene (PNCB)
(4-Chloronitrobenzene)
2,5-Diethoxy-4-chloronitrobenzene
o-Chloronitrobenzene (ONCB)
m-Chloronitrobenzene
Dichloronitrobenzenes
H Dye intermediate
H
[H]
H
H
Pesticide intermediate - not regulated by Part 455.
Chlorophenols:
o-Chlorophenol
2-Chloro-5-mQthylphenol
(6-Chloro-m-cresol)
2,4-Dichlorophenol
2,3-Dichlorophenol
3,4-Dichlorophenol
3,5 -Dichlorophenol
Tetrachlorophenol
2,4,6-rTrichlorophenol
3,4,5-rTnchlorophenol
H
G
G
H*
H*
H*
H
H
H
Chloropicrin (Trichloronitromethane)
Chloroprene (2-Chloro-l,3-butadiene)
X Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11d).
Chloropropanes:
1-Chloropropane (n-Propyl chloride)
\,2-Dichloropropane (Propylene di chloride)
H
H
H
A-17
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Chlorosulfonic acid
o-, m-, p-Chlorotoluene
X
H
Inorganic chemical. May be regulated by Part 415,
if reported under SIC 2819 (414.11d)
Choline chloride (non-medicinal, feed-grade) H
Choline chloride (medicinal-grade) X
Poultry and swine nutrition factor.
Medicinal chemical. Regulated by Part 439 and
reported under SIC 2833 (414.11 d).
Citrates (citric acid esters):
Diethylcarbamazine citrate
Polyglycerol citrate
Triethyl citrate
Citric acid
H
H*
H
X
Made by fermentation process (414.11e).
Coal Tar (from production of coke) X
Coal Tar Crudes (from distillation of coal tar):
Distillate oils:
Creosote oil G
Light oil H*
Naphthalene G
Methylnaphthalene H
Solvent naphtha H*
Tar acids:
Cresols, mixed (Cresylic acids) G
Cresylic acids, mixed G
Tar bases: Pyridines, "natural" H*
Tars (road materials & other) G
Pitches (of tar) F
Coal tar products (miscellaneous) G
Coke by-product. May be regulated by Part 420,
if reported under SIC 3312 (414.11d).
Same as Cresols, mixed.
Coconates (coconut oil esters)
Methyl coconate
Coconut oil acid esters
Coconut oil alkyl amines (fatty amines)
Coconut oil amide
[H*]
[H*]
[H*]
[H*]
[H*1
See fatty acid esters (derivatives of "natural" fatty
acids). Surface active agents. May be regulated by
Part 417, if reported under SIC 2843 (414.11 c).
Surface active agent
Surface active agent
Concentrates, C5 & C9 ->
Cresols (from hydrocarbon processes):
Cresols, mixed (Cresylic acid) G
o-, m-,p-Cresol (Cresylic acid isomers) G
Cresols, mixed (from coal tar condensate) G
Cresols:
2,6-Di-tert-butyl-p-cre50/ (BHT) H*
(Butylated hydroxytoluene)
Dinitro-p-creso/ H*
4,6-Dinitro-o-creso/ (DNOC) [X]
Cresoxide, Sodium (Cresylic acid salt) H*
Cresyl esters H**
See Hydrocarbons
See Coal tar products
Pesticide active ingredient. Regulated by Part 455
and reported under SIC 2879.
A-18
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Cresyl ethers
Cresylic acid (o-, m-, p-Cresol mixture)
H**
G
See Cresols (cresylic acid)
Cumene (Isopropylbenzene) F
Cumenesulfonic acid, Salts X
Cumene hydroperoxide G
Cumic alcohol (p-Isopropylbenzyl alcohol) H*
Surface active agent. Regulated by Part 417,
if reported under SIC 2843 (414.11 c)
See Hydroperoxides
See Flavors & Fragrances
Cyanamide, Calcium H
Cyanoacetates:
Ethyl cyanoacetate H
2-Ethylhexyl cyanoacetate H*
Cyanogen (Ethanedinitrile) G
Cyanogen chloride G
Cyanurates (cyanuric acid esters):
Triallylcyararafe H*
Triphenylcjararafe
(2,4,6-Triphenoxy-s-triazine) H
Cyanuric acid (2,4,6-Trihydroxy-s-triazine) G
Cyanuric chloride (2,4,6-Trichloro-s-triazine) G
See isocyanuric acid (tautomeric ketone)
Cyclamen aldehyde H
Cyclic aromatic sulfonates ->
Cycloheptadienes:
Tetrabromophenylhexachloro-
bicycloheptadiene H
Cyclohexane F
1,2-Cyclohexanedicarbo-xylic anhydride H
(Tetrahydrophthalic anhydride)
\,4-CyclohexanedimQthanol H*
Pentabromochlorocjc/o/2exa«e H*
1 -Isopropyl-4-methylcyc/o/7exa«e H*
(p-Menthane)
Cyclohexanol G
Cyclohexanol-Cyclohexanone (mixture) G
Cyclohexanone G
Cyclohexanone oxime H*
See Flavors & Fragrances
See Sulfonic acids, salts
Pesticide intermediate - not regulated by Part 455.
See Hydrocarbons C-6
See Phthalic anydride
Cyclohexene G
4-Vinyl-\-cyclohexene H
Cyclohexylamine (Aminocyclohexane) H*
Cyclohexyl chloride (Chlomcyclohexane) H*
Cyclonite (RDX) X
Cyclooctadiene H
Cyclopentadiene dimer H
Methylcyclopentadiene dimer H*
Cyclopentane H
See Hydrocarbons C-6
See AMINES
Explosive. Regulated by Part 457 and reported under
SIC 2892 (414.11c).
A-19
-------
Organic chemical product"
Cyclopentanol (Cyclopentyl alcohol)
Cyclopentyl bromide
Cyclopentyl chloride
Cyclopropanes
Cyclopropane carboxylic acid
Cy clopropy 1 amine
Methyl-3-(2,2-dichlorovinyl)-
2,2-dimethylcyclopropane carboxylate
Decaborane
n-Decane
Decanoates (Decanoic acid esters)
Decanoic acid (Caproic acid)
1-Decanol
1-Decene
Diacetone alcohol
Diazenes:
(2-Methylphenyl)(3-methyl-4-
aminophenyl) diazene
Dibenzylazocarboxylate
Dibutyl phthalate
Dicarboxylic acids & salts
1,2-Dichloroethane (Ethylene di chloride)
1 , 1 -Dichloroethane
Dichloronitrobenzenes
2,4-Dichlorophenol
Dicyclopentadiene
Diethanolamine
N,N-Diethylaniline
Diethyl ether
Diethylene glycol
Di(2-Ethylhexyl) phthalate
Diisobutyl phthalate
Diisodecyl phthalate
Dimer acid (Dilinoleic acid)
Dimer acid, ammonium salt
Trimer acid (Trilinoleic acid )
2,6-Dimethylaniline (2,6-Xylidine)
N,N-Dimethylfbrmamide (DMF)
Dimethylhexanes :
2,5-Dimethyl-2,4-hexadiene
2,5-Dimethyl-2,5-hexanediol
2, 5 -Dimethy lhexane-2, 5 -dihy draper oxi de
2,5-Dimethyl-2,5-di-(tert-butylperoxy)
hexane
Subpartb
H*
H*
H*
H
H*
H*
H*
[H]
H*
H*
H*
G
H*
G
H
H
G
->
F
G
H
G
H
G
G
G
G
G
G
G
G
H
H*
G
G
H
H*
H*
H
Remarks and Cross-References
See AMINES
Inorganic chemical. May be regulated by Part 415,
if reported under SIC 2819 (41 4.11 d).
See ACIDS Carboxylic
See ALCOHOLS
See Olefins (alpha)
See ALCOHOLS
Dye intermediate
See Phthalates
See ACIDS Dicarboxylic
See Chloroethanes
See Chloroethanes
See Chloronitrobenzenes
See Chlorophenols
See Cyclopentadiene dimer
See Ethanolamines
See Aniline
See ETHERS
See GLYCOLS
See Phthalates
See Phthalates
See Phthalates
Tradenames: AZ Dimer Acid, Versadyme,
Empol, Crodym, Unidyme, Hystrene.
See Xylidines
See AMIDES
See Diols & Peroxyesters
See Hydroperoxides
See Peroxides
A-20
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Dimethylhexanes (continued):
2,5-Dimethyl-3-hexyn-2,5-diol
2,5-Dimethyl-2,5-di-(tert-butylperoxy)
hex-3-yne
H* See Diols
H See Peroxides
Dimethyl phthalate
Dimethyl terephthalate (DMT)
G See Phthalates
F See Terephthalic Acid
Dinitrosobenzene
Dinitrotoluenes (mixed isomers)
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diols:
1,4-Butanecft'o/
2,3-Dibromo-l,4-butanet//'o/
1,3-ButaneJ/o/
1 ,2,4-Butanefr/o/
1 ,4-Butenecft'o/ (2-Butene- 1 ,4-diol)
1 ,4-ButyneJ/o/ (2-Butyne- 1 ,4-diol)
2,5-Dimethyl-2,5-hexaned/o/
1,6-HexaneJ/o/
2,2-Dimethyl- 1 ,3 -pentanediol
2,2,4-Trimethyl-l ,3-pentaned/o/
3-Chloro- 1 ,2-propaned/o/
1,4-Dioxane (p-Dioxane)
1,3-Dioxolane
a-Bromoacetoxymethyl dioxolane
2,2-Dimethyl-l,3-J/'oxo/a«e-4-methanol
Diphenylamine
Diphenylamine-acetone condensate
p-Nitrosodiphenylamine
N-Nitmsodiphenylamine
Octyldiphenylamine
Dipropylene glycol
Disalazanes
Dithiocarbamates (N,N-Dialkyl-):
Di-n-hutyldithiocarbamate, metal salts
Diethyldithiocarbamate, Zinc
2-DimQthylaminoQthyldithiocarbamate,
Sodium
DimQthyldithiocarbamate, Metal salts
Dithiophosphates, sodium salt
H
G
G
G
G
H
H
H
H
H
H*
H
H*
G
H*
G
H
H
H*
G
H*
H
H
H*
G
H
H
H
H*
[X]
See Nitrotoluenes
See Acetylenic diols
See Dimethylhexane
See Hexamethylene glycol
See GLYCOLS, Neopentyl
See Trimethylpentane
See AMINES
Used in rubber processing.
See Nitrosamines. Used in rubber processing.
Used in rubber processing.
See GLYCOLS
See Silanes
Used in rubber processing.
Used in rubber processing.
Used in rubber processing.
Inorganic chemical. May be regulated by Part 415,
Dithiophosphate esters
Ditridecyl phthalate
if reported under SIC 281 9. Removed from OCPSF
applicability [55 FR 42336 (Oct. 18, 1990)].
Phosphorodithioic acid esters.
See Phthalates
A-21
-------
Organic chemical product"
n-Dodecane
Dodecanoates (dodecanoic acid esters)
Dodecanoic acid (Laurie acid)
1-Dodecanol (Lauryl alcohol)
Dodecene, non-linear (Propylene tetramer)
1-Dodecene, linear (Ethylene oligomer)
n-Dodecyl bromide
n-Dodecyl chloride
n-Dodecyl lactate
p-Dodecylphenol
Dodecyl sulfate triethanolamine salt
Dyes, organic and dye intermediates
Acid Dyes
Methyl Red (C.I. Acid Red 2)
Anthraquinones
Azoic (Azo) dyes
Azoic coupling components
Anisoles (Methoxybenzenes)
1 ,2-Dimethoxybenzene (Veratrole)
Naphthol a(mine) s(ulfonates)
Nitroanisoles
Hydrazobenzene
Azoic diazo components
Anilines
Anisidines (Methoxyanilines)
Benzenediazonium chloride
Diazenes
Nitroanilines
Phenetidines (Ethoxyanilines)
Basic dyes
Cationic dyes
Direct dyes
Disperse dyes
Fiber Reactive dyes
Fisher's base
Fluorescent dyes
/?/X4-amino-2-sulfonic acid) stilbene
Fluorescein sodium
Mordant dyes
Solvent dyes
Sulfur dyes
Vat dyes
Vat Blue 6
Epichlorohydrin
Epoxidized esters
Linseed oil, epoxidized
Subpartb
H*
H*
H
G*
H
H
H*
H*
H*
H
[H]
H
H*
H
H
H*
H*
H
H
H*
H
H
H*
H
H
H
H
H
H
H*
H*
H
H*
H*
H
H*
H*
H*
H*
H*
H*
H*
H
G
H
H*
Remarks and Cross-References
See ACIDS Carboxylic
See ALCOHOLS
See Olefins (alpha)
See Phenol
Surface active agent. May be regulated by Part 417, if
reported under SIC 2843 (414.11c).
See Anthraquinone
See Anisole
Dye intermediate
See Aniline
See Diazenes
See Nitroaniline
Dye intermediates
Dye intermediate
Used as a plasticizer in plastic products.
A-22
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Epoxidized esters (continued):
Soybean (Soya) oil, epoxidized
Tallate esters, epoxidized
Erythritol anhydride
Ethane
1 ,2-Diethoxy ethane
1 , 1 -Diftuoroethane
1 ,2-Dimethoxy ethane
1 ,2-Diphenoxy ethane
Hexafluoroe^awe
lodoethane (Ethyl iodide)
Niiioethane
Ethanol (Ethyl alcohol) "natural"
Ethanol (Ethyl alcohol) "synthesis"
2-Bromoe thanol
2-Butoxy ethanol
2-(2-Butoxyethoxy) ethanol
2-Ethoxye^/7a«o/
2-(2-Ethoxyethoxy) ethanol
2-Mercaptoe thanol
2-Methoxy e thanol
2-(2-methoxyethoxy) ethanol
2-Phenoxye^/7a«o/
2-Propoxye^/7a«o/
Trifluoroe^/7a«o/
Ethanolamines (Aminoethanols):
Aminoethyle^2a«o/a™«e
tert-Rutylaminoethanol
( tert-Butyle^/2a«o/a™«e)
tert-Rutylaminodiethanol
Diethanolamine (2,2'-Iminodiethanol)
ra-Chlorophenyl Diethanolamine
H*
H*
H
G
H
H
G
H
H*
H*
H
X
G
H
G
H
G
G
H*
G
G
G
H
H
H
H*
H*
G
H*
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
See GLYCOL diethers
See GLYCOL diethers
See GLYCOL diethers
Made by fermentation process (414.1 1e).
See ALCOHOLS
See GLYCOL monoethers
See GLYCOL monoethers
See GLYCOL monoethers
See GLYCOL monoethers
See MERCAPTANS
See GLYCOL monoethers
See GLYCOL monoethers
See GLYCOL monoethers
See GLYCOL monoethers
(N,N-Dihydroxyethyl-m-chloroaniline)
N-Methyl Diethanolamine H*
N-Phenyl/'ra'«o diethanol
(N,N-Dihydroxy ethyl aniline) H*
2-(Diethyla™«o) ethanol H*
2-(Diethyla™«oethoxy) ethanol H*
2-(Dimethylara/'«o) ethanol H
2-(Methyla™«o) ethanol H*
Monoethanolamine (2-Aminoethanol) G
Ethanolamine N-thioglycolate H*
Ethanolamine N-sulfite H*
N-Ethy\ethanolamine H*
A-23
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Ethanolamines (continued)
^Inethanolamine
Trimethylammoethylethanolamine
H
H
ETHERS
Butyl (Di-n-butyl) ether H*
Ethyl (Diethyl) ether G
Isopropyl (Diisopropyl) ether H
Methyl (Dimethyl) ether H
Methyl-tert-butyl ether (MTBE) [G]
Chloroalkyl ethers:
bis(2-Chloroethoxy) methane H
2-Chloroethyl vinyl ether H
2,2'-Dichloroethyl ether H*
/>/X2-Chloroisopropyl) ether H
Chloromethyl methyl ether H
Dichloromethyl methyl ether H
Crown ethers (lonophores) H
Phenyl ether (Diphenyl ether, Diphenyl oxide) H
2-Chloro-4-trifluoromethyl-3-
carboxy-4'-nitrodiphenyl ether H
Polybrominated diphenyl ethers H*
Decabromodiphenyl ether H
Polychlorinated diphenyl ethers H
Polyphenyl ethers (Polyaryl ethers) H
bis(2,3 -Dibromopropylether)-
3,3'-bis(tetrabromophenyl) diether H
Vinyl ethers H
n-Butyl vinyl ether H*
Ethyl vinyl ether H*
Isobutyl vinyl ether H*
Methyl vinyl ether H*
A refinery petrochemical regulated by Part 419,
if reported under SIC 2911 (414.11d).
Pesticide intermediate - not regulated by Part 455.
See Polyvinyl pyrrolidinone
2-Ethoxyethanol
2-(2-Ethoxyethoxy) ethanol
bis(2-Ethoxyethyl) ether
Ethoxylates (ethylene oxide adducts):
Nonylphenol, ethoxylated
Polyoxyalkylene amines
Polyethylene glycol monostearate
Polyglycerol (Glycerol ethoxylate)
G See GLYCOL monoethers
G See GLYCOL monoethers
G See GLYCOL diethers
[G*] Surface active agents. Regulated by Part 417,
[H] if reported under SIC 2843 (414.11c).
[H] Surface active agent
[H] Surface active agent
Ethyl acetate
Ethyl acrylate
Ethylate, Sodium (caustic ethanol)
Ethyl bromide
Ethyl chloride (Chloroethane)
Ethyl ether (Diethyl ether)
H
G*
H*
H
G
G
See Acetates
See Acrylates
See Alkyl bromides
See Chloroethanes
See ETHERS
A-24
-------
Organic chemical product"
Ethyl iodide
Ethyl orthoformate
Ethylbenzene
Bromoethy 1 be nze me
Dibmmoethylbenzene
Tribromoethylbenzene
2-Ethylbutyraldehyde
Ethylene (Ethene)
fra«5-6/5(n-propylsulfonyl) ethylene
1 , 1 -Difiuoroethylene
Trifluomethylene
Ethyleneamines :
Ethylenediamine
N,N-DiQthylethylenediamine
Diethylene diamine (Piperazine)
Ethylenediamine dihydroiodide
Ethylenediamine-N,N'-distearic acid
(N,N'-Ethylenebis stearamide)
Ethylenediaminetetraacetic acid
Ethylenediaminetetraacetonitrile
N-Hydro-xyQthylethylenediamine-
triacetic acid
N,N,N',N'-Tetramethyle^/7j/e«ediara/'«e
N,N,N',N'-Tetrakis(2-hydroxypropyl)
ethylenediamine
Triethylene diamine
(l,4-Diazabicyclo[2.2.2] octane)
Polyethylene (Polyalkylene) polyamines
Diethylene triamine
Diethylenetriaminepentaacetic acid
Triethylene tstramine
Tetraethylene peniamine
Psntaethylene hsxamine
Ethylene dichloride (1,2-Dichloroethane)
Ethylene dibromide (1,2-Dibromoethane)
Ethylene glycol
Ethylene oxide
Ethylenimine (Aziridine)
2-Ethylhexaldehyde(2-Ethylhexanal)
2-Ethylhexanoic acid
2-Ethylhexanoates, metal salts
2-Ethylhexanol
2-Ethylhexanoyl chloride
Subpartb
H
H
F
H
H
H
G
F
H
H*
H*
G
H*
H*
H*
H
G
H*
H
H
H*
H
H
H
H
H
H
H*
F
H
F
F
H*
G*
H
H*
G
H*
Remarks and Cross-References
See ALDEHYDES
See AMINES
See Piperazine
See Chelating Agents, EDTA
See Nitriles
See Chelating Agents
See AMINES
See Chelating Agents
See Chloroethanes
See GLYCOLS
See Aziridine.
See ALDEHYDES and Oxo
See ACIDS and Oxo Acids
See ACIDS, salts
Aldehydes
See ALCOHOLS and Oxo Alcohols
Fats (or vegetable oils), sulfurized
H May be reported under SIC 2899.
A-25
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Fatty Acids "synthetic"
[X] OCPSF amended. [55 FR 42337 (Oct. 18, 1990)].
Fatty acids "natural" (from animal fat)
X
Fatty acids "natural" (from fish oils or vegetable oils):
Coconut oil acids (C-8 to C-20)
Linoleic acid (9,12-Octadecadienoic acid)
Margaric acid (Heptadecanoic acid)
Myristic acid (Tetradecanoic acid)
Oleic acid (cis-9-Octadecenoic)
Palmitic acid (Hexadecanoic acid)
Ricinoleic acid
(12-Hydroxy-9-octadecenoic acid)
Stearic acid (Octadecanoic acid)
12-Hydroxystearic acid
Fatty Acids, metal salts
Ammonium stearate
Calcium stearate (wax)
Cobalt tallate (Tall oil acid)
Zinc stearate
Fatty acid esters
Coconates (Coconut oil esters)
Glyceryl esters of mixed fatty acids
Myristates (Myristic acid esters)
Oleates (Oleic acid esters)
Palmitates (Palmitic acid esters)
Sebacates (Sebasic acid esters)
Stearates (Stearic acid esters)
Tallowates (tallow acid esters)
H*
H*
H*
H*
H*
H*
H*
G*
H*
H
H*
G
H*
H
H
[H*]
[H]
[H*]
[H*]
[H*]
[H*]
[H*]
[H*]
Regulated by Part 417 and reported under
SIC 2843 (414.11d).
May be reported under SIC 2899.
May be reported under SIC 2899.
May be reported under SIC 2899.
Surface active agents. Regulated by Part 417,
if reported under SIC 2843 (414.11c).
See Glycerin
Surface active agent. See Myristates.
Surface active agent. See Oleates.
Surface active agent. See Palmitates.
Surface active agent. See Sebacates.
Surface active agent. See Stearates.
Surface active agent. See Tallowates.
Fatty amides:
Coconut oil amide
Oleamide
Fatty amines
Fatty nitriles
[H*]
[H*]
[G]
[G]
Surface active agents. Regulated by Part 417,
if reported under SIC 2843 (414.11c).
Surface active agent
Surface active agent. See Nitriles
Flavor & Fragrance (aroma) chemicals:
Acetophenone H
Acetyl butyryl (2,3-Hexanedione) H*
Acetyl propionyl (2,3-Pentanedione) H*
Alloocimene H*
Allyl alcohol esters H*
Allyl alpha-ionone H*
4-Allyl veratrole H*
Anethole (Isoestragole) H*
/•-Anisaldehyde H*
Anisyl alcohol and esters H*
Benzoic acid esters (benzoates) H*
See KETONES
See Benzoates
A-26
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Flavor & Fragrance (aroma) chemicals (continued):
Benzophenone (Diphenyl ketone) H*
Benzyl alcohol H
Benzyl alcohol esters H*
Benzyl acetate H
Benzyl benzoate H
Butyl butyryl lactate H*
Camphene H
Caryophyllene H
cc-Cedrene (Vertofix Coeur) H
Cedryl alcohol (Cedrol) and esters H*
Cinnamic acid and esters (cinnamates) H*
Ethyl a,b-epoxy-b-methylc/>7«amafe H
Cinnamyl alcohol and esters H*
Hydmcitmamyl alcohol and esters H*
Cinnamaldehyde H*
Citral (Geranial) H*
Citral dimethyl acetal H*
Citronellal H*
Hydroxycitronellal H*
Methoxycitronellal H*
Citronellol (Citronellyl alcohol) H
Citronellyl alcohol esters H*
Coumarin (Benz[a]pyrone) H
Hydmcoumarin H*
Cresyl (Tolyl) esters and ethers H*
Cuminyl alcohol (Cuminol) and esters H*
Cyclamen aldehyde H
Cyclohexyl (Cyclohexanol) esters & ethers H*
Dihydromyrcenol H*
Diphenylmethane H*
Ethyl esters (cinnamate, crotonate, formate, H*
hexanoate, myristate, propionate, etc.)
Eugenyl alcohol (Eugenol) and esters H
Fenchyl alcohol (Fenchol) and esters H*
Furfuryl alcohol esters H*
Furfuryl mercaptan and thioesters H*
Geranonitrile (Citralva) H
Geranyl alcohol (Geraniol) and esters H
Guaiacwood alcohol esters H*
Hexanoates (Hexanoic acid esters) H*
Allyl hexanoate H*
Ethyl hexanoate H*
Hexenyl alcohol (Hexenol) esters H*
Hexyl alcohol (Hexanol) esters H*
Hydratropaldehyde H*
Hydratropic alcohol and esters H*
See KETONES
See ALCOHOLS
See Acetates
See Benzoates
See ACIDS, Hexanoic
A-27
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Flavor & Fragrance chemicals (continued)
a-Hexylcinnamaldehyde H
Indole H*
lonone H
Methylionones H
Isobutyl alcohol esters H*
Isopentyl(Isoamyl) alcohol esters H*
Isosafrole H
Isovaleric acid esters (isovalerates) H*
J/-Limonene (Dipentene) H
Linalyl alcohol (Linalool) and esters H*
^/-Menthol H
6-Myrcene H
/>-Methylanisole H*
Methyl anthranilate H*
Methyl hexyl ketone (2-Octanone) H*
Neryl alcohol (Nerol) and esters H*
Nonyl alcohol and esters H*
Nopol (Nopyl alcohol) and esters H*
Ocimenyl alcohol (Ocimenol) & esters H*
Octyl alcohol (Octanol) and esters H*
Phenethyl alcohol and esters H*
Dimsthylphenethyl alcohol & esters H*
Methylphenethyl alcohol and esters H*
Phenylacetic acid esters (phenylacetates) H*
Phenylethyl alcohol and esters H*
Pinane H
2-Pinanol H
Pine oil, synthetic G
a-Terpineol H
Dihydmterpineol H*
Terpinolene H*
a-Terpinyl esters H*
Pinene (alpha, beta) H
Piperonal (Heliotropin) H
Pyrones (e.g. Coumarin) H
Rhodinol (Citronellol + Geraniol) H*
Saccharin (Benzosulfimide) H
Salicylic acid esters (Salicylates) H*
Benzyl salicylate H*
Methyl salicylate H
Thymol H*
Tolyl(Cresyl) esters and ethers H*
Tricyclodecenyl alcohol and esters H*
Tricyclodecenyl propionate H
n-Undecanal H*
See KETONES
See a-Methylbenzyl alcohol
See Salicylic acid
A-28
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Flavor & Fragrance chemicals (continued)
2-Undecanone H*
n-Undecanal H*
2-Undecanone H*
Vanillin H*
Ethyl vanillin H
Vetivenyl alcohol (Vetivenol) & esters H*
Fluorocarbons (Freons)
Formaldehyde
Formaldehydesulfoxylate, sodium
Formate, sodium (Formic acid salt)
Formic acid
H
G
H
See Chlorofluorocarbons
See ALDEHYDES. Three commercial forms:
Formalin [hydrate (35-50% soln)]; Trioxane (cyclic
trimer); and polymer (paraformaldehyde).
See ACIDS
Furan (Furfuran)
bis(chlorendo)/Mra«
Polytetrahydrq/Mra«
Furfural (2-Furfuraldehyde)
Furfuryl alcohol
2-Furoyl chloride
2-Furoic acid and esters (furcates)
H*
H
H*
H
H
H*
H*
Pesticide intermediate. See Chlorendic acid
See GLYCOLS.
See Flavors & Fragrances.
Glucoheptonic acid, sodium salt
Glutamic acid, monosodium salt
H
X
Fermentation product.OCPSF not applicable (414.11e)
Glycerine, "synthetic"
Glycerine, "natural" (from animal fats)
Glyceryl esters of mixed fatty acids
Glycidol
Glycidyl esters and ethers
Glycine
Glycolic acid (Hydroxyacetic acid)
Glycolonitrile (Hydroxyacetonitrile)
[H]
H
H*
H
H
H
OCPSF not applicable (414.11d). Regulated by
Part 417 and reported under SIC 2841.
See Fatty acid esters
GLYCOLS:
Diethylene glycol G
Dipropylene glycol (l,l'-Oxydi-2-propanol) G
Ethylene glycol F
Neopentyl glycol (Dimethylpentanediol) H*
Polybutylene (Polyoxybutylene) glycol G
Polyether polyols:
Polyethylene glycol (PEG) G
Polypropylene glycol (PPG) F
Polyglycerol (Glycerol ethoxylate) H
Polytetramethylene ether glycol
(Polytetrahydrofuran) H*
Propylene glycol G
See Diols
Used in non-urethane products.
Used in urethane products.
See Furan
A-29
-------
Organic chemical product" Subpartb Remarks and Cross-References
GLYCOLS (continued):
Tetraethylene glycol H
Triethylene glycol (Triglycol) H
Triethylene glycol dichloride H*
Tripropylene glycol H
GLYCOL monoethers:
Ethylene glycol, monobutyl ether
(2-Butoxyethanol) G
Ethylene glycol, monoethyl ether
(2-Ethoxyethanol) G
Ethylene glycol, monohexyl ether H*
Ethylene glycol, monomethyl ether
(2-Methoxyethanol) G
Ethylene glycol, monophenyl ether
(2-Phenoxyethanol) G
Ethylene glycol, monopropyl ether
(2-Propoxyethanol) H
Diethylene glycol, monobutyl ether
(2-[2-Butoxyethoxy] ethanol) H
Diethylene glycol, monoethyl ether
(2-[2-Ethoxyethoxy] ethanol) G
Diethylene glycol, monomethyl ether
(2-[2-Methoxyethoxy] ethanol) G
Diethylene glycol, monophenyl ether
(2-[2-Phenoxyethoxy] ethanol) H*
Triethylene glycol, monoethyl ether
(Ethoxytriglycol) H
Triethylene glycol, monobutyl ether
(Butoxytriglycol) H*
Propylene glycol, monoisobutyl ether
(l-Isobutoxy-2-propanol) H*
Propylene glycol, monomethyl ether
(l-Methoxy-2-propanol) H*
Ethylene glycol, diethyl ether
(1,2-Diethoxy ethane) H
GLYCOL diethers:
Ethylene glycol, dimethyl ether
(1,2-Dimethoxy ethane) G
Ethylene glycol, diphenyl ether
(1,2-Diphenoxy ethane) H
Diethylene glycol, diethyl ether
(bis [2-Ethoxyethyl] ether) G
Diethylene glycol, dimethyl ether
(bis [2-Methoxyethyl] ether) G
A-30
-------
Organic chemical product"
Triethylene glycol, dimethyl ether
Polypropylene glycol, glycerol triether
(Glycerol tri[Polyoxypropylene] ether)
GLYCOL polyethers:
Polypropylene glycol, sorbitol polyether
(Sorbitol polyoxypropylene ether)
GLYCOL esters:
2-Butoxyethyl acetate
2-(2-Butoxyethoxy) ethyl acetate
Butylphthalyl butylglycolate
(phthalate ester of 2-Butoxy ethanol)
Diethylene glycol dibenzoate
2-(2-Ethoxyethoxy) ethyl acetate
Ethylene glycol diacetate
2-Methoxyethyl acetate
Polypropylene glycol (polyol), polyester
Propylene glycol dibenzoate
Propylene glycol methyl ether acetate
(l-Methoxy-2-propyl acetate)
Propylene glycol, fatty acid monoester
Propylene glycol, monolaurate
Triethylene glycol diacetate
Tripropylene glycol diacrylate
Glyoxal
Glyoxal-Formaldehyde mixtures
Guanidines:
Dodscylguanidine acetate
Guar derivatives
Heptachlor epoxide
n-Heptane
Heptene
Hexadecanoates (hexadecanoic acid esters)
Hexadecanoic acid (Palmitic acid)
1-Hexadecene
Hexamethylene diamine
Hexamethylene glycol
Hexamethyleneimine (Hexahydroazepin)
Hexamethylene tetramine
Hexamethylene glycol (1,6-Hexanediol)
Hexamethylene biuret-urethane
n-Hexane
Hexanoates (hexanoic acid esters)
Hexanoic acid
1-Hexene
Subpartb
H
H
H*
H
H
H
H
H
H
H
H*
H*
H*
H*
H*
H*
H*
G
H
H
H
H
H
H
->
->
H*
G
H
H
H
H
H
G
H*
H
H*
Remarks and Cross-References
See Acetates
See Acetates
See Phthalates
See Benzoates
See Acetates
See Acetates
See Acetates
See Benzoates
See Acetates
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.1 1c).
See Laurates
See Acetates
See Acrylates
Textile finishing agent.
Textile finishing agent.
Pesticide intermediate - not regulated by Part 455.
See Hydrocarbons C-7
See Hydrocarbons C-7
See Palmitates
See Fatty acids, "natural" (from vegetable oils)
See Olefins (alpha)
See AMINES, Hexanediamine
See Diols
Used in rubber processing.
See AMINES
See Diols
Adhesive & sealant. Part 414 not applicable, if
reported under SIC 2891 (414. 11c).
See Flavors & Fragrances
See ACIDS, Carboxylic
See Olefins (alpha)
A-31
-------
Organic chemical product"
n-Hexyl chloride
Hydantoins
1 ,3 -Dibromo-5 ,5 -dimethylhydantoin
5 , 5 -Dimethylhydantoin
5-Ethy\-5-methy\hydantoin
Hydrazine
Hydrazine monoacetate
Hydrazine monohydrate
1 ,2-Dipheny \hydrazine (Hy drazobenzene)
Dimethylhydrazine
Diphsnylhydrazine
Methylhydrazine
Phenylhydmzine
Hydrocarbons C-4:
n-Butane (saturated C-4)
1,3-Butadiene
Butylenes (mixed)
1-Butene
2-Butene (cis & trans)
Isobutylene
Hydrocarbons C-5 (concentrate)
Cyclopentadiene
Isoprene (2-Methyl- 1 ,3-butadiene)
Isopentane
n-Pentane
Pentenes (mixed)
1-Pentene
Hydrocarbons C-6:
Cyclohexane
Cyclohexene
n-Hexane
Methylcyclopentane
2-Methylpentane
Hydrocarbons C-7:
n-Heptane
Heptene
Heptenes (mixed isomers)
Methylcyclohexane
Hydrocarbons C-9 (concentrate)
Nonene (Propylene trimer)
Napthenes (Cycloparaffms)
n-Paraffms(C-8toC-18)
Subpartb
H*
H
H*
H*
H*
X
H
X
H
H
H
H
H*
[G]
[F]
[F]
[G]
[G]
[G]
[G]
[H]
[G]
[H]
[G]
[G]
[G]
[F]
[G]
[G]
[H]
[H]
[H]
[H]
[H*]
[H]
[G]
[H]
[H*]
[G]
Remarks and Cross-References
Inorganic chemical. May be regulated by Part 415,
if reported under SIC 2819 (414.1 1d).
Inorganic chemical
See Benzene
Petrochemical refinery products. May be regulated by
Part 419, if reported under SIC 291 1 (414. 11c).
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Petrochemical refinery products. May be regulated by
Part 41 9, if reported under SIC 291 1 (41 4.1 1 c).
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Petrochemical refinery products. May be regulated by
Part 41 9, if reported under SIC 291 1 (41 4.1 1 c).
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Petrochemical refinery products. May be regulated by
Part 41 9, if reported under SIC 291 1 (41 4.1 1 c).
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
Petrochemical refinery products. May be regulated by
Part 41 9, if reported under SIC 291 1 (414.11c).
Part 414 not applicable, if reported under SIC 291 1 .
Part 414 not applicable, if reported under SIC 291 1 .
A-32
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Hydroperoxides:
fert-Butyl hydroperoxide H*
Cumene hydroperoxide G
Dihydroterpinyl hydroperoxide H
(p-Methan-8-hydroperoxide)
2,5 -Dimethy lhexane-2,5-dihydroperoxide H *
Peracetic acid (Acetyl hydroperoxide) H
Pinane hydroperoxide H
See Acetic acid
Hydroquinone
2-Chlorohydroquinone
2,5-Di-tert-\)uty\hydroquinone
Imidazole
1,1 -Carbonyldiimidazole
2-Ethyl-4-mQthylimidazole
Indene (Indonaphthene)
Isatoic anhydride
Isobutanol (Isobutyl alcohol)
H
H
H*
H*
H*
H
H**
H
G
See ALCOHOLS
Isobutylene
Isobutylene Oligomers:
Diisobutylene (dimer)
Triisobutylene (trimer)
Isobutyraldehyde
Isobutyrates (isobutyric acid esters):
Isobutyl isobutyrate
Phenoxyethyl isobutyrate
Isobutyric acid
a-Hydro-xyisobutyric acid
H
H
G
H*
H
H*
H*
See Hydrocarbons C-4
See ALDEHYDES
See ACIDS carboxylic
Isocyanates:
p-Chlorophenyl/socya«afe H
Cyclohexyl isocyanate H*
3,4-Dichlorophenyl isocyanate H*
HQxyl-\,6-diisocyanate H
(Hexamethylene diisocyanate)
Methylene bis(4-pheny\isocyanate) MDI G
Methylisocyanate (MIC) H
Phenyl iso^/w'ocyanate H**
PAPI (Polymeric MDI) G*
Tolylene diisocyanates (TDI), mixed G
See Methylenebis-
Isocyanurates (isocyanuric acid esters): H
Dichlomisocyanurate, sodium H*
(Dichloro-s-triazine-2,4,6[lH,3H,5H]-trione, salt)
Isocyanuric acid
(s-triazine-2,4,6[lH,3H,5H]-trione)
See Cyanuric acid (tautomer of isocyanuric acid)
A-33
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Trichloroisocyanuric acid [H*]
(Trichloro-s-triazine-2,4,6[lH,3H,5H]-trione)
Isophorone G
Isophthalates (isophthalic acid esters):
Diphenyl isophthalate H*
Isophthalic acid G
Isophthalonitrile H*
Isophthaloyl chloride H
Isoprene G
Isopropanol (Isopropyl alcohol) F
HsxaRuoroisopropanol H*
Isopropyl acetate G
Isopropyl chloride H
Isovalerone (Diisobutyl ketone) H*
Used in pesticide applications. May be regulated by
Part 455, if reported under SIC 2879 (414.11d).
See KETONES
See Hydrocarbons C-5
See ALCOHOLS
See Acetates
See KETONES
Ketene
Diketene
KETONES:
Acetone
Acetophencwe
Benzophencwe (Diphenyl ketone)
Diisoamyl ketone
Diisobutyl ketone (Isovalerone)
Endrin ketone
2-Heptano«e (Methyl amyl ketone)
1,1,1,3,3,3-Hexafluoro-2-propano«e
2-Hexano«e (Methyl butyl ketone)
Isophorone
Methyl tert-butyl ketone
(3,3-Dimethyl-2-butanone)
Methylcyclohexancwe
Methyl ethyl ketone (MEK)
Methyl hexyl ketone
5-Methyl-3-heptano«e
Methyl isoamyl ketone (MIAK)
Methyl isobutyl ketone (MIBK)
Methyl isobutenyl ketone
Michler's ketone
Pentanone
Propiophenong (Phenylethyl ketone)
H
H
F
H
H*
H*
H*
H
H
H
H
G
H*
H
G
H*
H
H*
G
H
H
H*
H*
See Flavors & Fragrances
See Flavors & Fragrances
See Flavors & Fragrances
See Mesityl oxide
See Dyes
Lactic acid (2-Hydroxy/>ro/>/'o«/'c acid)
Lactates (Lactic acid esters):
Myristyl lactate
Laurates (Laurie acid esters):
Propylene glycol monolaumte
Laurie acid
H
H*
H*
H
See ACIDS
See GLYCOL Esters
See ACIDS, Dodecanoic
A-34
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Lauroyl (dodecanayl) chloride
Lauryl alcohol
Laurylsulfonate, sodium
Lauryl alcohol sulfate
H*
H*
[H]
[HI
See ALCOHOLS, Dodecanol
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11 c).
Lignosulfonic acid (Lignosulfate)
Lignin sulfonic acid, Calcium salt
Lignin sulfonic acid, Fe-Cr salt
Lignin derivatives
X
[G]
[H]
[H]
Byproduct of the wood pulping process, but not
regulated by Part 430.
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Lutidines (Dimethylpyridines)
Maleates (Maleic acid esters):
Diallyl maleate
Di-n-butyl maleate
Di(2-ethylhexyl) maleate
Maleic acid
Maleic anhydride
Alkylmaleic anhydride
Maleic hydrazide
H* See Pyridines
H*
H*
H*
H
G
H
H
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
See ACIDS, Dicarboxylic
Mannitol H
Melamine (2,4,6-Triamino-s-fr/'az/«e) G
p-Menthane (l-Isopropyl-4-methylcyclohexane) H*
MERCAPTANS (thiols):
Amyl mercaptan H
Butyl mercaptan H*
Cyclohexyl mercaptan H*
Dodecyl mercaptan H
1,2-Ethaneditfz/o/ H*
Ethylmercaptan H*
Hexadecyl mercaptan H*
2-Hydroxyethyl mercaptan H*
Isopropyl mercaptan H*
Methyl mercaptan H*
tert-Nonyl mercaptan H*
Octadecyl mercaptan H*
n-Octyl mercaptan H*
tert-Octyl mercaptan H*
Perchloromethyl mercaptan H
Propyl mercaptan H*
Tetradecyl mercaptan H*
Tridecyl mercaptan H*
2,4,4-Trimethyl-2-pentaneffeo/ H*
See AMINES
See Cyclohexane
Used in rubber processing.
Used in rubber processing.
Used in rubber processing.
See Trimethylpentane
Mercaptoacetic acid
Mercaptoacetates (esters)
Mercaptobenzothiazoles
Mercaptopropionic acids
(esters)
H**
H**
H*
H**
H**
See Benzothiazoles
A-35
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Mesityl aldehyde
Mesityl oxide
Mesitylene (1,3,5-Trimethylbenzene)
Metal Alkyls:
Dimethylzinc
Tetraethyl lead (TEL)
Tetramethyl lead (TML)
Tributylalurninum
Triethylaluminum
Triethyl borane
Trimethyl aluminum
Trimethylgallium
H*
H
H*
H*
G
G
H*
H
H*
H*
H*
See KETONES
See Organo-Metallics
Production restricted since the mid 70's
by phase out of leaded gasoline.
Metanilic acid
Methacrylates (Methacrylic acid esters):
Allyl methacrylate
n-Butyl methacrylate
Cyclohexyl methacrylate
Diethylene glycol dimethacrylate
2-Ethylhexyl methacrylate
n-Hexyl methacrylate
Isobornyl methacrylate
Isobutyl methacrylate
Isodecyl methacrylate
Isopropyl methacrylate
Lauryl (Dodecyl) methacrylate
Methyl methacrylate (MMA)
Neopentyl glycol dimethacrylate
Stearyl methacrylate
Tetraethylene glycol dimethacrylate
Tetrahydrofurfuryl methacrylate
H*
H*
H*
H*
H*
H*
H*
H*
H*
H*
H*
G
H*
H*
H*
H*
Methacrylamides H
Dimethylaminopropyl methacrylamide H
Methacrylic acid G
Methallyl chloride H
Methane
Chlommethane (Methyl chloride)
/>/X2-Chloroethoxy) methane
Chlomftuommethanes
Diphsnylmethane
lodomethane (Methyl iodide)
Nitromethane
Trichloronitroraethane (Chloropicrin)
Triftuoromethane
Methanol
G
G
H
->
H*
H*
H
X
H*
See ETHERS, Chloroalkyl
See Chlorofluorocarbons
See Flavors & Fragrances
Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11d).
A-36
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Methionine
2-Meth oxyeth anol
2-(2-Methoxyethoxy) ethanol
bis(2-Methoxyethyl) ether
Methyl acrylate
Methylal (Dimethoxymethane, formal)
Methylamines:
Dimethylamine
Methylamine
Trimethylamine
X
G
G
G
G*
H
G
G
G*
G
Medicinal chemical. Regulated by Part 439 and
reported under SIC 2833 (414.1 1d).
See GLYCOLS monoethers
See GLYCOLS monoethers
See GLYCOLS diethers
See Acrylates
See AMINES
See AMINES
See AMINES
Methylates:
Magnesium methylate H
Sodium methylate (caustic methanol) H
a-Methylbenzyl alcohol (Styralyl) H*
Methyl bromide H
Methyl tert-butyl ether (MTBE) G
Methylbutynol H
Methyl chloride (Chloromethane) G
Methyl chloroform (1,1,1 -Trichloroethane) G
Methylcyclohexane H
Methylcyclohexanol H
Methylcyclopentane H
Methyl ethyl ketone (MEK) G
Methyl ethyl ketone oxime H*
Methyl formate H
Methyl iodide (lodomethane) H
Methyl isobutyl ketone (MIBK) G
(5-Methyl-2-hexanone)
Methyl methacrylate (MAA) G
2-Methylpentane H
2-Methyl-l-pentanol H
4-Methyl-2-pentanol H
Methylpentynol H
cc-Methylstyrene G
tert-Amyl-a-methylstyrene H
Methylene chloride (Dichloromethane) G
See Flavors & Fragrances
See ETHERS
See Acetylenic Alcohols
See Methane
See Chloroethylenes
See Hydrocarbons C-7
See Hydrocarbons C-6
See KETONES
See KETONES
See Methacrylic acid
See Hydrocarbons C-6
See Acetylenic alcohols
Methylene dianiline (MDA)
4,4'-Methylenebis (N,N-dimethylaniline)
Polymeric MDA (oligomers)
Methylenediphenyldiisocyanate (MDI)
(Methylenebis[4-phenylisocyanate])
Polymethylene polyphenyleneisocyanate
(PAPI, Polymeric MDI)
G
G
G
G
G*
See Methylenebis-
See Isocyanates, Methylenebis-
See Isocyanates
A-37
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Methylenebis-
4,4'-Methylenebis (dianiline) G
4,4'-Methylenebis(N,N-dimethylaniline) G
4,4'-Methylenebis(3-hydroxy-
2-naphthalenecarboxylic acid) H*
2,2'-Methylenebis(6-tert-butyl-p-cresol) H*
2,2'-Methy lenebis [6-( 1 -methyl-
cyclohexyl)-p-cresol] H*
Methylenebis thioacetic acid H**
Methylenebis thiocyanate H**
Methylenebis thiopropionic acid H**
See Methylene dianiline
See Methylene dianiline
See Naphthalene (Pamoic acid)
Used in rubber processing
Used in rubber processing
Morpholine
Morpholine disulfide
4-Mor/>/2o//'«yl-2-benzothiazyl disulfide
Myristates (Myristic acid esters)
Isopropyl myristate
Methyl myristate
Myristyl myristate
Myristic acid
Myristyl alcohol
H
H*
H*
[H*]
[H*]
[H*]
[H*]
->
H*
Used in rubber processing.
Used in rubber processing.
See Fatty acid esters. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Used as a plasticizer.
See Fatty Acids.
See ALCOHOLS: Tetradecanol
Nadic anhydride
7-Methylnadic anhydride
Naphthas, solvent
Naphthalene
Methylnaphthalene
Bromonaphthalene
Chlomnaphthalenes
2-Ch\omnaphthalene
Psntachloronaphthalene
3-Hydroxy-2-«ap/rf/2a/e«e carboxamide
3-Hydroxy-2-«ap/rf/2a/e«ecarboxylic acid
4,4'-Methylenebis (3-hydroxy-2-
naphthalenecarboxylic acid)
1,4,5, 8-Naphthalene tetracarboxylic acid
cc-Naphthol (\-Hydro~xynaphthalene)
p-Naphthol (2-Hydmxy naphthalene)
\-Nitronaphthalene
Polynaphthalene sulfonate, Sodium
2-Naphthalenesulfonic acid (beta)
1-Naphthalenesulfonic acid (alpha)
Naphthalenesulfonic acid-
formaldehyde condensates
H*
H
->
G
H
H
H
H*
H
H
H
H
H*
H*
H
H
H
H
H
G
H
H*
See Solvents
See Coal tar products
See Coal tar products
Pamoic acid. See Methylenebis-
See Tetralin
A-38
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Tetrahydronaphthalenesulfonic acid H*
Naphthenic acids ->
(Cyclopentanecarboxylic acids)
Naphthenates (Naphthenic acid salts) H
Calcium, Cobalt, Zinc naphthenates H*
Copper, Lead naphthenates H
Naphthoic acid (Naphthalene carboxylic acid) H*
Napthoates (Napthoic acid esters) H*
Petrochemical refinery product. May be regulated by
Part 419, if reported under SIC 2911 (414.11 c).
See Naphthalene
Neopentyl glycol
Dibmmoneopentyl glycol
Nitriles:
Acetonitrile
Ethylenediaminetetraacefc>«/Yn7e
Iminodiacetonitrile
Benzo«/Yr/7e
n-Butyro«/Yr/7e
Fatty nitriles
Isobutyro«/Yr/7e
Succmonitrile
Nitrilotriacetic acid (NTA)
Nitrites:
n-Butyl«/Yr/Ye
Isoamyl«/YnYe
Isobutyl«/Yr/Ye
Nitroanilines, mixed
2-Bromo-4,6-di«/Yroa«/7/'«e
2,6-Dibromo-4-«/Yroa«/7/'«e
2,6-Dichloro-4-«/Yroa«/7/'«e (DCNA)
Chloronitrobenzenes
Nitrophenols:
/>-Nitrophenol (4-Nitrophenol)
o-Nitrophenol (2-Nitrophenol)
2-Amino-4-nitrophenol
2-Chloronitrophenol
2,4,6-rTrinitrophenol (Picric acid)
Nitrosamines:
DiroYrosopentamethylenetetraffl/ng
H*
H
H
H*
H*
H**
H
[G]
H*
H
G
H**
H**
H**
G
H
H*
[H*]
See GLYCOLS, Diols
See Ethylenediamine
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
See Acetic acid, Chelating Agents
See Aniline
Used as a dye intermediate
Used as a dye intermediate
Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11c).
/>-Nitroaniline
o-, ra-Nitroaniline
Nitrobenzene
o-. p-, m-Dinitrobenzene
H
H*
G
H
See Aniline
See Aniline
See Chloronitrobenzenes
Pesticide intermediate. Not regulated by 40 CFR 455.
G*
H
H
H
H
H Used in rubber processing.
A-39
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Nitrosamines (continued):
N-Nitrosodiphsnylamine
Nitrotoluenes:
o,p-Nitrotoluene
m-Nitrotoluene
4-Nitrotoluene-2-sulfonic acid
Dinitrotoluenes, mixed
2,4-Dinitrotoluene
2,6-Dinitrotoluene
H See Diphenylamine. Used in rubber processing.
G
H*
H
G
G
G
See Dinitrotoluene
Nonene, non-linear (Propylene trimer)
1-Nonene, linear
Nonenes (mixed isomers)
Nonylphenol
2,4-Dinonylphenol
Nylon salt
[H]
[H]
[H]
G
H*
G
See Hydrocarbons C-9
See Olefins, alpha
See Olefins, alpha
See Phenol
Olefins, alpha (C6-C10, Cl 1 & higher)
Linear ethylene oligomers:
1-Dodecene (C-12)
1-Eicosene (C-20)
1-Heptene (C-7)
1-Hexene (C-6)
1-Hexadecene (C-16)
1-Nonene (C-9)
1-Octene (C-8)
1-Tetradecene (C-14)
Olefins (alpha), epoxidized
Poly alpha olefins (PAO)
[G]
[H]
[H*]
[H*]
[H*]
[H*]
[H]
[H*]
[H*]
H
H*
Petrochemical refinery products. May be regulated by
Part 419, if reported under SIC 2911 (414.11 c).
Oleamide
Oleates (Oleic acid esters & salts)
n-Butyl oleate
n-Decyl oleate
Glyceryl mono-oleate
Glyceryl inoleate
Methyl oleate
n-Propyl oleate
Propyleneglycol mono-oleate
Sorbitan oleate, ethoxylated
(Sorbitol monooleate)
Oleic acid
Organometalli cs
Organo-Tin compounds
Triorganotin compounds
Organo-Phosphorus chlorides
Oxalates (Oxalic acid esters & salts):
Ammonium oxalate
[H*]
[H*]
H*
H*
H*
H*
H*
H*
[H*]
[H]
H
->
X
X
H*
See Fatty amides
See Fatty acid esters
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Surface active agent
See Fatty Acids
See Metal alkyls
Pesticide active ingredients. Regulated by Part 455
and reported under SIC 2879 (414.11d).
See Benzene
A-40
-------
Organic chemical product"
Oxalates (continued)
Ethyl oxalate
Oxalic acid
Oxo process organic chemicals
Oxo Acids:
2-Ethylhexanoic acid
Heptanoic acid (Enanthic acid)
Neodecanoic acid
Neoheptanoic acid
Neopentanoic acid (Pivalic acid)
Pelargonic acid (Nonanoic acid)
Propionic acid
n-Valeric acid (Pentanoic acid)
Oxo Alcohols:
n-Amyl alcohol (n-Pentanol)
n-Butanol
2-Ethylhexanol
2-Hexanol
2-Heptanol
Isoamyl (Isopentyl) alcohol
Isobutanol
Isodecanol (Isodecyl alcohol)
Isononanol (Isononyl alcohol)
Iso-octanol (Isooctyl alcohol)
Neopentyl glycol
n-Propanol
1-Tridecanol (C-13)
Trimethylolpropane
Oxo Aldehydes:
n-Butyraldehyde
2-Ethylhe'aaldehyde
Isobutymldehyde
Pmpionaldehyde
n-Vs&sraldehyde
Palmitates (Palmitic acid esters)
Isopropyl palmitate
Methyl palmitate
Propylene glycol monopalmitate
Palmitic acid
Palmitoyl chloride
Subpartb Remarks and Cross-References
H
G See ACIDS, Dicarboxylic
H
H*
H*
H*
H
H
G
H*
H
G
G
H*
H*
H
G
H
H*
H
H*
G
H*
H
G
H*
G
G
H
H* See Fatty acid esters
H* Used as a plasticizer in plastic products.
H*
[H*] Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.1 1c).
H*
H*
Pamoic acid
(4,4'-Methylenebis-[3-hydroxy- 2-naphthalene
Pamoate, diSodium
n-Paraffins (C-8 to C-18)
H* See Methylenebis-. See Naphthalene.
carboxylic acid])
H*
[G] See Hydrocarbons
A-41
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Pentachlorophenol (PCP) and metal salts X
Pentaerythritol (Tetramethylol methane) G
Tripentaerythritol H*
n-Pentane [G]
Pentenes, mixed [G]
1-Pentene [G]
Dipentene (d, /-Limonene) H*
Perchloroethylene (tetrachloroethylene) G
Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11 d).
See Hydrocarbons C-5.
See Hydrocarbons C-5
See Hydrocarbons C-5
See Flavors & Fragrances
See Chloroethylenes
Peroxides:
Acetyl (Diacetyl) peroxide H
Benzoyl peroxide H
Di-tert-butyl peroxide H
Dicumyl peroxide H*
bis(cc,a-Dimethylbenzyl) peroxide H
2,5-Dimethyl-2,5-di-
(tert-butyl/>erary)hexane H
2,5-Dimethyl-2,5-di (tert-butylperoxy)-
hex-3-yne H
Lauroyl (Dilauroyl) peroxide H*
Methyl ethyl ketone peroxide H
2,4-Pentanedione peroxide
See Dimethylhexanes
See Dimethylhexanes
(Acetylacetone peroxide)
Succinic acid peroxide
Peroxycarbonates:
tert-Butyl />eraryisopropyl carbonate
Di-sec-Butyl perfoxy]di carbonate
Di(2-ethylhexyl) peroxydicarbonate
Di-n-Pmpy\peroxycarbonate
Peroxyesters
tert-Butyl peroxyacetate
tert-Butyl peroxybenzoate
tert-Butyl peroxyisobutyrate
tert-Butyl peroxypivalate
a-Cumyl peroxyneodecanoate
2,5-Dimethylhexane-2,5-
diperoxy(2-ethylhexanoate)
Perylene tetracarboxylic acid diimide
Petroleum sulfonates, metal salts
H
H*
H*
H*
H
H*
H
H*
H
H*
H
H*
H*
H
G Surface active agent. Part 414 not applicable, if
Phenethyl alcohol esters
o-, p-Phenetidine (o-, p-Ethoxyaniline)
H
previously reported under SIC 2843 (414.11c).
See Flavors & Fragrances
Used as a dye intermediate
Phenol
Alkylphenols, mixed
Amylphenol
F
G
H
A-42
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Phenols (continued):
p-Anilinophenol H*
/>-Benzyloxy/>/2e«o/ H
o-SQC-Butylphenol H*
p-tert-Butylphenol G
2,4-Di-tert-pentyl/>/2e«o/ H*
p-Dodscylphenol H
o, p-lsopmpy\phenol H
p-Msthoxyphenol (Hydroquinone diether) H*
p-Nitmsophenol (p-Quinone oxime) H*
Nonylphenol G
Octylphenol H
tert-Pentylphenol H*
Phenolate, sodium (Sodium phenate) H
Phenolsulfonic acids H
Phenol, styrenated H*
Used in rubber processing.
Used in rubber processing.
2-Phenoxyethanol
Phenylacetic acid, potassium salt
4-Methoxyphenylacetic acid
Phenylacetyl chloride
G
H
H*
H
See GLYCOL monoethers
See Flavors & Fragrances
Phenylenediamines
m-, />-Phenylenediamine
o-Phenylenediamine
N,N'-Bis(l ,4-dimethylpentyl)-p-
phenylenediamine
N,N'-Bis(l -methylheptyl)-p-
phenylenediamine
N-(l,3-Dimethylbutyl)-N'-phenyl-p-
phenylenediamine
N,N'-Diphenyl-p-phenylenediamine
N-Isopropyl-N'-phenyl-p-
phenylenediamine
m-Nitro-p-phenylenediamine
4-Nitro-o-phenylenediamine
See AMINES
H
G
H* Used in rubber processing.
H* Used in rubber processing.
H* Used in rubber processing.
H Used in rubber processing.
H* Used in rubber processing.
H*
H
Phenylethyl alcohol and esters
Phenylethyl bromide
Phosgene
Phosphate, tri-organo esters:
Cresyldiphenyl phosphate
Di(2-ethylhexyl) phosphate
(Di[2-Ethylhexyl] phosphoric acid)
/>-Nitrophenyl phosphate
Phenyl phosphate
Phosphate esters of ethoxylated alcohols
-> See Flavors & Fragrances
H*
G
H
H*
H*
H*
H* Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11 c).
A-43
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Phosphate, tri-organo esters (continued):
Thiamine pyrophosphate
Tri(2-butoxyethyl) phosphate
Tri-n-butyl phosphate
Tri(4-bromophenyl) phosphate
Tri(2-chloroethyl) phosphate
Tri-p-cresyl phosphate
(tri-p-Tolyl phosphate)
Tri(2,3-dibromopropyl) phosphate
Tri(2,3-dichloropropyl) phosphate
Tri(2-ethylhexyl) phosphate
Tri(2,4,6-tribromophenyl) phosphate
Tri(2-ethylhexyl) phosphate
Tri(isopropylphenyl) phosphate
Triphenyl phosphate
X
H*
H*
H
H
H
H
H
H*
H
H
H
H
Medicinal chemical (Vitamin). Regulated by Part 439
and reported under SIC 2833 (414.11d).
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Phosphines:
1,2-\)is(Dipheny\phosphino) ethane
Diphenylcyclohexyl phosphine
Phosphinic acids:
Benzene phosphinic acid
Diphenyl phosphinic acid
H
H*
H*
H*
H*
Phosphites (Phosphorous acid esters):
Diphenyl phosphite H**
Diphenyl isodecyl phosphite H**
Diphenyl iso-octyl phosphite H**
Diphenyl nonyl phosphite H**
Tetraphenyl (dipropylene glycol)
phosphite H**
Tridecyl phosphite H**
Tri(2-ethylhexyl) phosphite H**
Trimethyl phosphite H**
Tri(nonylphenyl) phosphite H**
Used in rubber processing.
Phosphonic acid esters (phosphonates)
Benzene phosphonic acid H*
/>/X2-Chloroethyl)-1 -hydroxy ethyl H
phosphonic acid
/>/X2-Chloroethyl)vinyl phosphonate H
Diethyl 2-bromoethyl phosphonate H
Diethyl 2-hydroxyethyl phosphonate H
Dimethyl methylphosphonate H*
Dipolyoxyethylene hydroxymethyl
phosphonate H*
Ethyl phosphonic acid H*
Ethyl phosphonic dichloride H*
Ethyl phosphono^/H'oic dichloride H
2-Hydroxyethyl-1,1 -diphosphonic acid H
A-44
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Phosphonic acid esters (continued)
Nitrilotris(methylene) triphosphonic acid H
Triethylphosphonoacetate H*
Phosphonium salts:
Tetrabutyl phosphonium silanate H
Tetrabutyl phosphonium salts H*
Tetrakis(Hydroxymethyl)-
phosphonium bromide H
Tetrakis(Hydroxymethyl)-
phosphonium chloride H
Tetrakis(Hydroxymethyl)-
phosphonium hydroxide H
Tetrakis(Hydroxymethyl)-
phosphonium sulfate H
Phosphorodithioic acid esters:
O,O-Diethyl phosphorochlondodithioate H*
(Diethylchlorothiophosphate)
Diethyl phosphorodithioic acid H*
O,O-Dimethyl phosphorochlorodithioate H*
Dimethyl phosphorodithioic acid H*
Di-n-propylphosphorochloridothioate H*
Di-n-pmpy\phosphorodithioic acid H*
Phosphorotrithioic acid,
S,S,S-tributyl ester (DBF) X
Pesticide intermediate. OCPSF js applicable.
Not regulated by 40 CFR 455.
Pesticide intermediate. OCPSF js applicable.
Pesticide intermediate. OCPSF js applicable.
Pesticide intermediate. OCPSF js applicable.
Pesticide intermediate. OCPSF js applicable.
Pesticide intermediate. OCPSF js applicable.
Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11 d).
Phthalates (Phthalic acid esters):
Phthalates, one-alcohol:
Diallyl phthalate
Di-n-butyl phthalate
Dicyclohexyl phthalate
Diethyl phthalate
Di(2-Ethylhexyl) phthalate
Diisobutyl phthalate
Diisodecyl phthalate
Diisononyl phthalate
Diiso-octyl phthalate
Di-n-hexyl phthalate
Di(2-Methoxyethyl) phthalate
Dimethyl phthalate
Di-n-octyl phthalate
Diphenyl phthalate
Ditridecyl phthalate
Phthalates, two-alcohol:
Butyl, benzyl phthalate
Butyl, octyl phthalate
Butylphthalyl butylglycolate
Decyl, isononyl phthalate
Used as a plasticizer in plastic products.
H*
G
H
H
G
G
G
H
G
H
H
G
H
H
G
H
G
H
H
Used as a plasticizer in plastic products.
See GLYCOL Esters
A-45
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Phthalates, two-alcohol (continued):
Decyl, octyl phthalate H
2-Ethylhexyl, hexyl phthalate H
Phthalates, mixed-alcohol: H
2-Ethylhexyl, hexyl, isodecyl phthalate H
Heptyl, nonyl, undecyl phthalate H
Hexyl, heptyl, nonyl, undecyl phthalate H
Phthalic acid G
4-MQthylphthalic acid H*
Phthalic anhydride G
Hexahydro/>/rf/2a//'c anhydride H
(1,2-Cyclohexanedicarboxylic anhydride)
4-Methy\phthalic anhydride H*
Tetrabromo/>/rf/2a//'c anhydride H
Tetrachlomphthalic anhydride H
Tetrahydro/>/rf/2a//'c anhydride H
Phthalimide H
Tetrahydmphthalimide H*
Phthalocyanines ->
Phthaloyl chloride H
See Pigments
Picolines (methylpyridines)
2-Picoline
Picric acid (2,4,6-Trinitrophenol)
H
H
H
See Pyridine
See Nitrophenols
Pigments, organic
Blue 1 (Victoria blue)
Pigment Blue 15 (a & b forms)
(Copper phthalocyanine blue)
Brown 5 (Monoazo brown)
Drug and cosmetic colors
Fluorescent pigments
Food, drug and cosmetic colors
Green 1 (Brilliant green)
Pigment Green 7
(Copper phthalocyanine green)
Green 36 (Phthalo green [Cl,Br])
Orange 5 (Dinitraniline orange)
Orange 13 (Pyrazolone orange)
Orange 16 (Dianisidine orange)
Orange 34 (Diarylide orange)
Orange 46 (Ethyl red lake C)
Red 3 (Toluidine red)
Red 4 (Orthochlor red)
Red 17 (Naphthol red medium)
Red 23 (Naphthol red dark)
Red 48 (Permanent red)
Red 49 (Lithol red, salt)
H
H*
H
H*
H*
H*
H*
H*
H
H*
H*
H*
H*
H*
H*
H*
H*
H*
H*
H*
H*
A-46
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Pigments, organic (continued):
Red 52 (Red 2G, salt) H*
Red 53 (Red Lake C, salt) H*
Red 57 (Lithol rubine, salt) H*
Red 81 (Rhodamine Y) H*
Red 112 (Naphthol red FOR) H*
Violet 1 (Rhodamine B) H*
Violet 19 (Quinacridone violet) H*
Red 112 (Naphthol red FOR) H*
Violet 1 (Rhodamine B) H*
Violet 19 (Quinacridone violet) H*
Violet 23 (Dioxazine violet) H*
Yellow 1 (Hansa yellow G) H*
Yellow 3 (Hansa yellow 1OG) H*
Pigment Yellow 12 (Diarylide yellow AAA) H
Yellow 13 (Diarylide yellow AAMX) H*
Yellow 14 (Diarylide yellow AAOT) H*
Yellow 17 (Diarylide yellow AAOA) H*
Yellow 74 (Hansa yellow 64) H*
Yellow 83 (Diarylide yellow HR) H*
Pinane
Pinane hydroperoxide
Pine oil, "synthetic"
Pine oil, "natural"
Pinene
H See Flavors & Fragrances
H See Hydroperoxides
G See Flavors & Fragrances
X Solvent extracted from pine wood stumps (414.11e).
Regulated by Part 454 and reported under SIC 2861.
H See Flavors & Fragrances
Piperadine (Hexahydropyridine)
Piperazine (Diethylene diamine)
N-Aminoethyl/>//>eraz/'«e
N-Methy\piperazine
Piperylene (1,3-Pentadiene)
Pitch Tar residues
Pivalic acid (Neopentanoic acid)
Pivaloyl chloride
H*
H
H*
X*
H*
->
H
H*
See Ethylene diamine
Medicinal chemical. Regulated by Part 439 and
reported under SIC 2833 (414.11d).
See Coal tar products
See ACIDS and Oxo Acids
Polyacrylic acid
Polyacrylate, sodium
-> See Acrylic acid. Regulated in Part 414 as a PLASTIC,
H* but considered an organic chemical in commerce.
Polybenzylalkylbenzenes H
Polyethylbenzene (polybenzyl aromatics) H
Polyether polyols ->
Polybutylene glycol G
Polyethylene glycol (PEG) G
Polypropylene glycol (PPG) F
See GLYCOLS
See GLYCOLS
See GLYCOLS
See GLYCOLS
Polyisoprene solution
[H] Rubber sealant. Part 414 is not applicable,
if reported under SIC 2891 (414.11c).
A-47
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Polymeric MDA
Polymeric MDI
Polymeric plasticizers
(complex linear polyesters)
Polysulfide polyether
Polyphosphates, chlorinated
Potassium pyrophosphate
Polyvinyl pyrrolidinone
Polyvinyl pyrrolidinone lonophore
(Crown polyether)
Quaternized complex ether
G See Methylenedianiline
G* See Methylenediphenyldiisocyanate
H** Used as a plasticizer in plastic products.
[H]
X
X
H
H
H
Rubber sealant. Part 414 is not applicable,
if reported under SIC 2891 (414.11c).
Fertilizer chemicals. OCPSF not applicable (414.11d)
Fertilizer chemical. Regulated by 40 CFR 418 and
reported under SIC 2874.
Propane G
Nitropropane H
l,2,3-Trichloro/>ro/>a«e H*
Propanol (n-Propyl alcohol) G
2-Chloropropanol (Propylene chlorohydrin) H
2,3-Dibmmopropanol H
2,3-Dichloro/>ropa«o/ (Dichlorohydrin) H
l-(Dimethylamino)-2-propa«o/ H*
2-Methyl-2-nitro-1 -propanol H*
See ALCOHOLS
See Chlorohydrins
See Chlorohydrins
Propene (Propylene)
1 -Chloro-2-methyl/>ro/>e«e
3-Chloro-2-methyl/>ro/>e«e
\,3-Dich\ompropene
l,2,3-Trichloro/>ro/?e«e
Trifluoropropene
F
H
H
[H]
H*
H*
Used in pesticide applications, but not regulated by
40 CFR 455.
Propionaldehyde
Propionic acid (Propanoic acid)
3,3'-rThiodipropionic acid and esters
Propionates (esters & salts):
Benzyl propionate
Calcium, sodium propionate
Propionitriles:
3 -Aminopropionitrile
Propoxylates (Propylene oxide adducts)
Alcohols (fatty) propoxylates
Alcohols (linear alkyl) propoxylates
Alkylphenol propoxylates
Polyoxyalkylene amines
G
G
H*
H*
H
[H]
[H*]
[H*]
[H*]
[HI
See ALDEHYDES
See ACIDS
See Thiodipropionates
See Flavors & Fragrances
Surface active agents. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Surface active agent
Surface active agent
Surface active agent
n-Propyl chloride (1-Chloropropane)
H See Chloropropanes
A-48
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Propylene (Propene) F
Hexafiuompropylene H*
Propylene dichloride (1,2-Dichloropropane) G
Propylene glycol (1,2-Propanediol) G
Propylene oxide F
HsxaRuoropropylene oxide H
Pyridines, "natural" ->
Pyridines, "synthetic" (and substituted) H
Pyridine H
2-Amino-6-methylpjn't//'«e H
2-Ch\ompyridine H
2-Cyanopyridine H
Lutidines (Dimethylpyridines) H*
Picolines (Msthylpyridines) H
Pyridinethione-N-oxide, Zinc H
N-Vinylpyridine H*
Pyrimidines H
Pyrogallol (1,2,3-Trihydroxybenzene) H**
Pyrolysis Gasoline F
Pyrones (e.g., Coumarin) H
Pyrroles H
Pyrrolidones H
2-Pyrrolidinone H*
N-Methyl-2-pyrrolidone (NMP) H*
1 - Viny 1-2-pyrrolidinone H*
GLYCOLS
See Coal tar products
See Flavors & Fragrances
Quinaldine (2-MQthylquinoline)
Quinoline (Benzo[b]pyridine)
8-Hydroxyqumoline
8-Hydroxy^M/'«o//'«e, Copper
l,2-Dihydro-2,2,4-trimethyl^M/'«o//«e
Quinone (Benzoquinone)
p-Benzogw/>?o«edioxime
(p-Quinone dioxime)
Quinoxalines:
2,3-DichlorogM;>7o.ra/;>7e
H
H*
H
X
H
H
H
H
Pesticide active ingredient. Tradename: Copper 8.
Regulated by Part 455 and reported under SIC 2879
(414.11d).
Used in rubber processing.
Used in rubber processing.
Ricinoleates (Ricinoleic acid esters) H*
Methyl ricinoleate H*
Resorcinol (1,3-Dihydroxybenzene) H
Resorcylic acid (2,4-Dihydroxybenzoic acid) H
Salicylaldehyde
Salicylanilide
Salicylic acid (o-hydroxybenzoic acid)
H See ALDEHYDES
H SeeAnilides
H See Aspirin.
A-49
-------
Organic chemical product"
Subpartb Remarks and Cross-References
Salicylic acid esters (salicylates)
H* See Flavors & Fragrances
Sebacates (sebacic acid esters)
Di(2-Ethylhexyl) sebacate
Di(n-butyl) sebacate
Sebacic acid
Semicarbazide: HC1
Silanes:
Dichlorodimethyl5/7a«e
Disalazanes (Iminosilanes):
Hexamethylflfoa/azane (HMDS)
Ethyl silicate (Tetraethoxy5/7a«e)
Trichlorophenyl5/7a«e
Trimethylsilyl iodide (Iodotrimethyl5/7a«e)
Silicone fluids
Silicone resins
Silicone rubber
H* See Fatty acid esters
H Used as a plasticizer in plastic products.
H*
-> See Fatty Acids, "natural"
H
H**
H
H*
H**
H**
H**
H**
-> See PLASTICS
-> See PLASTICS
Sodium thiosulfate
Solvents:
Hydrocarbon solvent
Naphtha solvent
[H] Inorganic chemical. Regulated by Part 415,
if reported under SIC 2819 (414.11d).
[H] Petrochemical refinery products. Regulated by
\G\ Part 419, if reported under SIC 2911 (414.11 c).
Sorbic acid and salts
Sorbitol
Sorbitol esters, ethoxylated
Soybean oil acid esters, epoxidized
Soybean oil, brominated
H
G
[H*]
H*
H
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Used as a plasticizer in plastic products.
Spirogermanium
Starch derivatives
X Medicinal chemical. May be regulated by Part 439,
if reported under SIC 2833 (414.11d).
[H] Adhesive applications. Part 414 is not applicable, if
reported under SIC 2891 (414.11c).
Stearamide
Stearates (stearic acid esters)
n-Butyl 9,10-epoxy-octadecanoate
n-Butyl stearate
Glyceryl monostearate
Isobutyl stearate
Isocetyl stearate
Isopropyl stearate
Methyl-12-hydroxy stearate
Methyl stearate
Starch stearate
Tridecyl stearate
Polyethylene glycol stearate
Propylene glycol monostearate
H*
[H*]
H
H
[H]
H*
H*
H
H
H
H
H*
[H]
[H*]
See AMIDES
See Fatty acid esters
Used as a plasticizer in plastic products.
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11 c).
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Surface active agents. May be regulated by Part 417,
if previously reported under SIC 2843 (414.11c).
A-50
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Organic chemical product"
Subpartb Remarks and Cross-References
Stearates (continued):
Stearate, metal salts (except Calcium salt) H
Calcium stearate G
Stearic acid H
Stearyl alcohol H*
Stilbene H
bis(4-Amino-2-sulfonic acid) stilbene
triazine chloride [H]
bis(4-Amino-2-sulfbnic acid) stilbene H*
bis(4-Nitro-2-sulfonic acid) stilbene H*
See ALCOHOLS, Octadecanol
Textile brightener
Used as an intermediate in dye synthesis.
Used as an intermediate in dye synthesis.
Styrene
Chlomstyrene
Styrene oxide (Epoxyethylbenzene)
Succinic acid
Sulfosuccinic acid esters
Succinic anhydride
Alksnylsuccinic anhydride
DodecenyLracc/>?/'c anhydride (DDSA)
n-TetradecenylsHcc/rac anhydride
Succinimides
Succinonitrile
F
H
H
H
[H*]
H
H
H
H*
H
H
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Sulfanilic acid (p-Aminobenzenesulfonic acid) H
2,5-Dichloro5M//o«/7/'c acid H*
Sulfates: ->
Diethyl sulfate H
Dimethyl sulfate H
Sulfides:
Diethyl sulfide H*
Methyl sulfide (Dimethyl sulfide) H
Sulfoethoxylates of long-chain esters [H]
Sulfosuccinate diesters, ethoxylates [H*]
n-Propyl oleate sulfoethoxylate [H*]
Sulfolane H
Sulfolene H
Sulfonamides:
Toluenesulfonamide H
3-n-Butylamino-4-methoxy-
benzenesulfonamide H
Sulfones:
bis(4-Chlorophenyl) sulfone H
Sulfonic acid salts (sulfonates):
Renzenesulfonic acid, salts H
Naphthalene5M//o«/'c acid, salts ->
Toluenesulfonic acids, salts ->
See Alcohol sulfates
Surface active agents. May be regulated by Part 417,
if previously reported under SIC 2843 (414.11c).
Surface active agent
See Benzene
See Naphthalenesulfonic acid and Tetralin
See Toluene
A-51
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Organic chemical product"
Subpartb Remarks and Cross-References
Sulfoxides:
Dimethyl sulfoxide
H
Tall oil
Tall oil, except skimming
Tallowates (Tallow fatty acid esters)
Methyl tallowate
Tannic acid (tannin)
Tars & Pitches
X
X
[H*]
H*
H
Byproduct of wood pulping process, but not regulated
by Part 430. Used as a raw material by facilities
subject to Part 414.
Regulated by Part 454, if reported under SIC 2861
(414.11d)
See Fatty acid esters
See Coal tar products
Terephthalic acid (TPA)
2,5-Dianilino terephthalic acid
Terephthalic acid, dimethyl ester (DMT)
Terephthaloyl chloride
F
H
F
H
Used as an intermediate in dye synthesis.
See Dimethyl terephthalate
Terpene oil (Terpineol, Pinene)
Tetraalkylammonium (quaternary) salts:
Tetrabutylammonium salts
Tetraethylammonium salts
Tetraethylammonium chloride
(medical grade)
Tetramethylammonium salts
Tetrapropylammonium salts
Trimethylbenzylammonium chloride
H See Flavors & Fragrances
H**
H**
Medicinal chemical. Regulated by Part 439 and
reported under SIC 2833 (414.11d).
H**
H**
[H**]
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
1 , 1 ,2,2-Tetrabromoethane
Tetrachloroethylene (Perchloroethylene)
Tetraethyl Lead (TEL)
Tetrafluoroethylene
Tetrahydrofuran (THF)
Tetralin (1,2,3,4-Tetrahydronaphthalene)
Tetramethyl Lead (TML)
1-Tetralol, 1 -Tetral one (mixture)
Tetralone
6-Methoxy tetralone- 1
H
G
G
H
H
H
G
G
H*
H*
See Chloroethylenes
See Metal Alkyls
See Metal Alkyls
Thiazoles:
2-Amino-5-nitro^/2/azo/e H
2-Amino^/2/azo/e nitrate H
3-Trichloromethyl-5-chloro-l,2,4-
thiadiazole H
4,4'-Thiobis(6-tert-butyl-m-cresol)
Thiodipropionamides, -propionitriles:
N,N'-Dilauryl thiodipropionamide
3,3'-Thiodipropionitrile
H* Used in rubber processing.
H**
H**
A-52
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Organic chemical product"
Subpartb Remarks and Cross-References
Thiodipropionates (Thiopropionic acid esters):
Dilauryl thiodipropionate
Dimethyl ^thiodipropionate
Dimethyl thiodipropionate
Dimyristyl thiodipropionate
Distearyl thiodipropionate
Ditridecyl thiodipropionate
3,3'-Thiodipropionic acid
Thionocarbamates
Thiophene (Thiofuran)
Tetrahydro^/2/o/>/2e«e
Thiopheneacetic acid
Thiophenols:
2-Aminothiophenol
Thioureas:
\,3-Di-n-\)uty\thiourea
\,3-DiQthylthiourea
N,N'-Diphenyk/MOHrea
Ethylthiourea
Thiram (bis[dimethylthiocarbamyl]disulfide)
Toluene
p-Bromotoluene
Diaminotoluene
Dinitrotoluene
Pentabmmotoluene
m-Phenoxy toluene
a-Toluenesulfonic acid (Benzylsulfonic acid)
o, />-Toluenesulfonic acid
/•-Toluenesulfonic acid salts
a-(N-Ethylanilino)-/'-to/Me«esulfonic acid
/•-Toluene sulfonyl chloride
Vinyltoluene
Toluates (Toluic acid esters):
Methyl-p-toluate
Toluic acid (Methylbenzoic acid)
Toluidines:
w-Toluidine
o-, />-Toluidine
N,N-Dimethyl-p-fc>/H/'d/>?e
N-Ethy\-m-toluidine
Toluidines (m-, o-, p-isomer mix)
Tolylenediamines (TDA) (Diaminotoluene)
2,4-Tolylenediamine
H**
H**
H**
H
H**
H**
H**
H
H**
H**
H**
H
H* Used in rubber processing.
H* Used in rubber processing.
H
H
H
F
H*
G See Tolylenediamines
G See Dinitrotoluenes
H*
H
H
H*
[H*] Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.1 1c).
H*
H
H*
H*
H
H
H*
H*
H*
H
G See AMINES
G
A-53
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Organic chemical product"
Subpartb Remarks and Cross-References
Tolylenediamines (continued):
2,6-Tolylenedi(diazonium chloride) H
Tolylene diisocyanates (TDI) G
2,4-Toluene diisocyanate G
2,6-Toluene diisocyanate G
Toxaphene (Polychlorocamphene) X
Triacetin ->
s-Triazines ->
Triazoles:
1,2,4-Triazole H*
Tolylfr/'azo/e H
1,1,1 -Trichloroethane (Methyl chloroform) G
Trichloroethylene (Trichloroethene) G
Tri-p-cresyl phosphate H
Tricyclodecenyl esters H
Tridecyl alcohol sulfate, sodium [H]
Triethanolamine H
Triethylene glycol H
Triglycol dichloride
(Triethylene glycol dichloride) H
Trimellitates (Trimellitic acid esters):
Tri(2-ethylhexyl) trimellitate H*
Triisononyl trimellitate H*
Triiso-octyl trimellitate H*
Trimellitic acid G
(1,2,4-Benzene tricarboxylic acid)
Trimellitic acid 1,2-anhydride H*
Used as an intermediate in dye synthesis.
See Isocyanates
Pesticide active ingredient. Regulated by Part 455 and
reported under SIC 2879 (414.11d).
See Acetates
See Cyanuric acid, Isocyanuric acid
See Chloroethanes
See Chloroethylenes
See Phosphate esters
See Flavors & Fragrances
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
See Ethanolamines
See GLYCOLS
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Used as a plasticizer in plastic products.
Trimesic acid (1,3,5-Benzene tricarboxylic acid) H
Trimethylpentane -
2,2,4-Trimethyl-\,3-pentanediol G
2,2,4-Trimethylpentanediol-
1,3-diisobutyrate H*
2,4,4-Trimethyl-2-pentanethio[ H*
See Diols
Used as a plasticizer in plastic products.
See MERCAPTANS
Trimethylolpropane H*
Trimethylolpropane triacrylate H*
Trimethylolpropane trimethacrylate H*
Trimethylolpropane trioleate H*
Trimethylol propane
tri (3-mercaptopropionate) H*
See Oxo Alcohols
Trimethyl phosphite H**
Triphenylmethane H
Polychlorinated triphenyls H
Ureas:
N,N'-DiphenylMrea (Diphenylcarbamide) H*
See Phosphites
A-54
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Organic chemical product"
Subpartb Remarks and Cross-References
Ureas (continued)
Dimethylol dihydroxyethylene urea
Urethane prepolymers
Vegetable oils, Sulfated
Polyethylene Wax (latex emulsion)
H**
[G]
[H]
Regulated in Part 414 as both an organic chemical
and a plastic product. See PLASTICS, Polyurethane.
Surface active agent. May be regulated by Part 417,
if reported under SIC 2843 (414.11c).
Vinyl acetate
Vinyl bromide
Vinyl chloride
Vinyl fluoride
Vinylidene chloride
Vinyltoluene
Waxes, as emulsions and dispersions
F
H
F
H*
G
H*
X
See Acetates
See Chloroethylenes
See Toluene
Part 414 not applicable.
Product was deleted.
[55 FR 42336 (Oct. 18, 1990)].
May be reported under SIC 2842.
See PLASTICS, Polyethylene
Xanthates
Ethylthioxanthate, Sodium
Isopropylxanthate, Zinc
Xylenes, mixed
o-Xylene
ra-Xylene, crude (contains p-xylene)
/•-Xylene
Xylene sulfonic acid, sodium
Xylenols, mixed
2,4-Xylenol
2,5-Xylenol
3,4-Xylenol
3,5-Xylenol
H
H*
H*
F
F
F
F
H
H
H
H
H
H
Xylidines, mixed
2,6-Xylidine (2,6-dimethylaniline)
H
H
See Aniline
A-55
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Abbreviations and Explanatory Notes
Column Header Notations
(a) Listing in organic chemical products column adapted from:
1. Tables V, VI and VII in Volume II, Appendix III-A, Final Development Document for Effluent
Limitations Guidelines and Standards for the Organic Chemicals, Plastics and Synthetic Fibers. EPA
440/1-87/009, October, 1987.
2. OCPSF Product/Process File compiled by the Industrial Technology Division of EPA's Office of Water
Regulations and Standards, 1976-1983.
3. 1986 SRI Directory of Chemical Producers.
(b) Subpart column notations:
F = Subpart F - Commodity Organic Chemicals.
G = Subpart G - Bulk Organic Chemicals.
H = Subpart H - Specialty Organic Chemicals.
[ ] = Indicates a change in the status of a product since promulgation of the OCPSF regulation, or the
product's classification is conditioned by the definitions of applicability given at 40 CFR 414.11
Changes in product classification were prompted by amendments to the OCPSF Regulation [e.g., 55 FR
42332 (Oct. 18, 1990)] and by corrections for errors in the listings of products in Table V, VI, or VII of
the OCPSF Development Document.
X = The OCPSF regulation is not applicable to the product. Reason noted in "Remarks" column.
* = The product was not listed in Table V, VI, or VII in the OCPSF Development Document,
Vol. II, Appendix III-A. These additional products were selected from those shown in the 1986 SRI
Directory of Chemical Producers as being manufactured by two or more plants. A single asterisk
indicates the appropriate Subpart for an organic chemical that was not specifically listed in the OCPSF
Dev. Doc., but can be classified within a product group that was listed.
** = Indicates an appropriate Subpart for a chemical of commerce that was unlisted in the OCPSF Dev.
Doc. and cannot be classified within an OCPSF product group that was listed. Such products are implied
as OCPSF by the global title of Table VII E, "Other Organic Chemicals and Chemical Groups."
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