HEALTHY AIR
A CDMMUMITV AMD BUSINESS LEADEIS GUIDE
Could your family
      be affected?
    One electroplating
 shop switched from a
 vapor degreaser parts
  washing system that
    used solvents to a
   water-based power
    washing system. It
  saves approximately
 $12,600 per year and
  has reduced toxic air
    emissions by 90%.
   — Pollution Prevention
        Resource Center

    One electroplating
   shop replaced their
 toxic cleaning solvent
   with a water-based
        solution. This
 completely eliminated
   toxic air emissions,
    reduced air permit
   fees, and created a
   more pleasant work
        environment.

      Annual savings:
      $8,440 per year
        — Kansas Small
             Business
         Environmental
            Assistance
              Program

  One firm used a low-
  concentration plating
    solution  in 5 nickel
      tanks and saved
$1,300 in disposal and
      feedstock costs.
            — U.S. EPA
                                                                                                   9/12/2005
                                     OWNER/OPERATOR INFORMATION SHEET
           Reducing Air Pollution from:
              Electroplating  Operations
Why should my electroplating
shop reduce air pollution?
  People who are exposed to toxic air
pollutant at sufficient concentrations, for
sufficient durations, may increase their
chances of getting cancer or
experiencing other serious health effects,
such as reproductive problems, birth
defects, and aggravated asthma.
  Pollution prevention safeguards the
health of your employees, customers,
and families by using materials,
processes, or practices that reduce or
eliminate air pollution at the source.
For example, covering containers of
cleaning solvents prevents vapors from
affecting your employees.
  Pollution prevention practices also
save money on waste disposal, materials
usage, and the cost of air pollution
controls.
  You may already be regulated by
federal, state, local, and Tribal agencies
and may already voluntarily implement
pollution prevention practices. However,
increasing pollution prevention efforts
can further minimize impacts  on human
health and the environment.

Why should I be concerned about
air pollution from my
electroplating shop?
•  Electroplating operations can
   produce emissions of toxic air
   pollutants, including heavy metals
   and cyanide.
•  Degreasing and cleaning solutions
   can release toxic air pollutants and
   volatile organic compounds (VOC).
   Chemicals in these substances can
   react in the air to form ground-level
   ozone (smog), which has been linked
   to a number of respiratory effects.
•  Plating processes generate heavy
   metals such as hexavalent chromium
   and cadmium. While federal, state,
   local, and Tribal regulations limit the
   amount of emissions from
   electroplating shops, dangerous
   releases of toxic air pollutants can
   occur if an electroplating shop is not
   in compliance with regulations.
•  Cyanide has been a key component
   of plating solutions for years. It can
   impact the nervous system, heart, and
   lungs.

How can I reduce air pollution
from my electroplating shop?

Substitute Materials
•  Use cleaners such as water-based
   cleaners that have a lower toxic air
   pollutant  and VOC content.
•  Use degreasing solvents with a lower
   toxic air pollutants and VOC content.
•  If you are a chromium electroplater,
   switch from hexavalent chromium-
   bearing solutions, which can cause
   cancer, to trivalent chromium ones,
   which do not cause cancer.
•  Replace the cyanide in plating
   solutions  with less toxic compounds
   like zinc chloride and pyro-phosphate
   copper.

Lower Emissions at the Source
•  Cover containers of cleaning solvents
   and used  shop towels. This will
   reduce emissions of toxic air
   pollutants and VOC as well as the
  EPA 's Sector Strategies Program has an Environmental Management
  System (EMS) available for electroplating shops to use. An EMS helps
 electroplating shops integrate environmental decision making into day-
                           to-day operations.
                                                                 — U.S. EPA

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                         OWNER/OPERATOR INFORMATION  SHEET
                                          Electroplating Operations
                                                                                                              9/12/2005
   amount of solvent lost to evaporation. This reduces
   the amount of new solvent purchased.
•  Securely cover all containers to reduce the chance of
   spills when transferring materials.
•  Use funnels or pumps to avoid spills when
   dispensing materials.
•  Install ventilation hoods over plating baths to help
   protect workers from evaporative plating solutions.

Change Cleaning Procedures
•  Mandate a "clean as you go" policy to reduce the
   amount of solvent needed for removing heavy build-
   up.
•  Mechanically clean parts with a wire brush or
   sandblasting equipment to reduce solvent use.
•  Use old solvent as a pre-wash or wipe for cleaning
   equipment or parts.
•  Switch to a water-based cleaning system like
   ultrasonic cleaners, manual parts washers, automatic
   spray equipment, steam cleaners, or baths with
   agitation.
•  Clean parts with hot water and detergent at high
   pressures in a pressurized washer.

Recycle Materials
•  Use an on-site distillation unit to clean dirty cleaning
   liquid. This makes the solvent available for reuse in
   the production process. An on-site distillation
   reduces the costs of both solvent disposal and fresh
   solvent purchase.
•  Use old solvent for cleaning very dirty parts.
•  Reuse plating bath solution and rinse water.
•  Reduce bath dumps by continuously filtering bath
   solutions.

Change Production Processes
•  Review and streamline production processes to
   reduce overall cleaning solvent and degreaser use.
   For example, evaluate your solvent quality,
   consolidate parts washing processes, and service
   units only when necessary. These steps can greatly
   reduce solvent waste.
•  Lower emissions of toxic air pollutants such as
   cyanide, chromium and other heavy metals by using
   alternative electrocoating technologies like thermal
   spray coating, vapor deposition, and chemical
   vapor deposition.
•  Minimize chemical usage and its associated
   emissions by using the lowest concentration of
   chemicals in the bath that will produce the desired
   results.
•  If possible, use mechanical scraping instead of a
   chemical solution to remove undesired buildup on
   the metal.
•  Change baths and rinses based on bath/rinse
   quality, not to meet an arbitrary schedule.

What do  I need to consider before converting
to alternative plating processes?
  Converting to alternative plating processes may
result in high costs from research and development
and new equipment, but these alternative processes
often reduce operating costs.
  Some alternative processes may be more labor
intensive, which results in higher labor costs, but these
processes can significantly reduce the amount of toxic
air pollutants emitted.
  Check with your state, local, or Tribal pollution
prevention office for funding possibilities.

What else can  I do to  reduce air pollution?
  Your community may already have groups working
for cleaner air. Your expertise and knowledge can be
very helpful to these groups.
  Many pollution prevention offices offer free on-site
assessments for interested businesses. A list of these
small business assistance programs can be found at
www.epa.gov/smallbusiness. This site provides
information about assistance and technical help,
environmental experts, environmental regulations and
laws, funding, and cost-saving opportunities.
  Sponsor employee awards for good ideas, great
efforts, and dedication to  pollution prevention. For
example, you could provide a cash award for workers
who implement a work practice that reduces both
costs and pollution.
                HEALTHY   AIR:   A  COMMUNITY  AND  BUSINESS LEADERS  GUIDE

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   HEALTHY AIR
   » CDHMUmll «»0 iUSHISS UHOIIS Gtlml

  Could your family
        be affected?

    One company uses
active carbon filtration
  to regenerate plating
                baths.
   Capital costs: $9,192
     Maintenance costs:
              $7,973/yr
   Reduction in plating
     bath disposal and
       fresh chemicals
      purchased: 47%
   Savings from reduced
waste disposal: $67,420
     Savings in chemical
    purchases: $55,000
          — Illinois Waste
             Management
            and Research
                 Center

   P2/Finance is a user-
   friendly series of free
      software programs
        designed to help
business people analyze
    the costs of pollution
      prevention, energy
    efficiency, and other
     projects to enhance
   resource efficiency. It
     enables the user to
  compare costs/savings
    of business-as-usual
          practices with
   alternative scenarios.
         — Tellus Institute
                                        OWNER/OPERATOR INFORMATION SHEET
                                                         Electroplating Operations
                                                                                                          9/12/05
                           Resources

   National Association of Metal Finishers: www.namf.org, (407) 281-6445
   EPA Air Toxics Web Site: www.epa.gov/ttn/atw/
   National Emission Standards for Hazardous Air Pollutants: Chromium Electroplat-
   ing: www. epa.gov/ttn/atw/chrome/chromepg. html
   Owner/Operator Information Sheet for Metal Operations.
   EPA's Sector Strategies Partnership Program for the Metal Finishing Sector:
   www.epa.gov/sectors/metalfmishing/index.html
   Fabricated metal products sector notebook:
   www.epa.gov/compliance/resources/publications/assistance/sectors/notebooks/fabm
   etsn.pdf
   U.S. EPA Office of Research and Development Capsule Report: Approaching Zero
   Discharge in Surface Finishing. EPA 625/R-99/008, November 2000. Guidance on
   controls and process changes: www.pfonline.com/magjmages/625R99008AZD.pdf
   P2/Finance (Tellus Institute): www.tellus.org/b&s/software/p2.html
   Electroplating and metal finishing: www.cdphe.state.co.us/ap/P2/el_met.htm
   Plating process:
   www.wmrc.uiuc.edu/main_sections/info_services/library_docs/manuals/fmishing/pl
   ating.htm
   Electroplating and metal finishing industry:
   www.engext.ksu.edu/ppi/publications/manual/Metalfinish/contents.html
   Options for industry: www. dep. state, ct. us/wst/p2/industry/optindex. htm
   Community-Based Projects: www.epa.gov/air/toxicair/community.html

Topic Hubs
•  Metal fabrication and machining:
   www.newmoa.org/prevention/topichub/toc.cfm?hub=23&subsec=7&nav=7

•  Machining and metal fabrication:
   www.pprc. org/hubs/subsection. cfm ?hub =23&subsec=4&nav=4

•  Plating: www.pprc.org/hubs/subsection.cfm?hub=24&subsec=4&nav=4

Toxicity of Solvents

•  Integrated Risk Information Systems (IRIS): www.epa.gav/iris

•  Air Toxics Health Effects Notebooks: www.epa.gov/ttn/atw/hapindex.html

Alternatives
•  Finding an Alternative to Solvent Degreasing:
   www.pprc.org/cpc/Contents/Baseline/EPA%20Publications/Solvent%20Degreasing
   %20Alternatives.pdf

•  Biochemical substitutions:
   www.carbohydrateeconomy.org/library/admin/uploadedfiles/BiochemicalJSubstituti
   on_in_the_Metal_Plating_.html

•  Solvent Alternatives Guide: www.sage.rti.org

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