United States Environmental Protection Agency < r Comprehensive Disinfectants and Disinfection Byproducts Rules (Stage 1 and Stage 2): Quick Reference Guide Overview of the Rules Titles* Purpose General Description Utilities Covered >• Stage 1 Disinfectants and Disinfection Byproducts Rule (Stage 1 DBPR) 63 FR 69390, December 16, 1998, Vol. 63, No. 241 > Stage 2 Disinfectants and Disinfection Byproducts Rule (Stage 2 DBPR) 71 FR 388, January 4, 2006, Vol.71, No. 2 Improve public health protection by reducing exposure to disinfection byproducts. Some disinfectants and disinfection byproducts (DBPs) have been shown to cause cancer and reproductive effects in lab animals and suggested bladder cancer and reproductive effects in humans. The DBPRs require public water systems (PWSs) to: > Comply with established maximum contaminant levels (MCLs) and operational evaluation levels (OELs) for DBPs, and maximum residual disinfection levels (MRDLs) for disinfectant residuals. ^ Conduct an initial evaluation of their distribution system. In addition, PWSs using conventional filtration are required to remove specific percentages of organic material that may react to form DBPs through the implementation of a treatment technique. The DBPRs apply to all sizes of community water systems (CWSs) and nontransient noncommunity water systems (NTNCWSs) that add a disinfectant other than ultraviolet (UV) light or deliver disinfected water, and transient noncommunity water systems (TNCWSs) that add chlorine dioxide. This document provides a summary of federal drinking water requirements; to ensure full compliance, please consult the federal regulations at 40 CFR 141 and any approved state requirements. Overview This table shows how the requirements for the Stage 2 DBPR build on the existing requirements established in the Stage 1 DBPR. For more information on changes in monitoring requirements, see Table 1. Coverage TTHM & HAAS MCL Compliance Regulated Contaminants & Disinfectants Operational Evaluation All CWSs and NTNCWSs that add disinfectant other than UV light and TNCWSs that treat with chlorine dioxide. Consecutive systems that deliver water treated with a disinfectant other than UV light. MCL compliance is calculated using the running annual average (RAA) of all samples from all monitoring locations across the system. MCL compliance is calculated using the locational RAA (LRAA) for each monitoring location in the distribution system. Stage 1 DBPR S ^ Stage 2 DBPR S S S Contaminants Total Trihalomethanes (TTHM) 5 Haloacetic Acids (HAAS) Bromate Chlorite S /; /; /; s s Regulated under Stage 1 DBPR1 Regulated under Stage 1 DBPR Disinfectants Chlorine/chloramines Chlorine dioxide If an operational evaluation level (OEL) is exceeded, systems must evaluate practices and identify DBP mitigation actions. s £ Regulated under Stage 1 DBPR Regulated under Stage 1 DBPR s For More Info: See Table 3 and Table 4. See Table 2. See Table 5. 1. A new analytical method for bromate was approved with the Stage 2 DBPR. ------- Stage 1 DBPR Stage 2 DBPR DO •< m c c i^i| H X c§ O Number of Samples Based on source water type, population, and number of treatment plants or wells. Based on source water type and population. Sample Locations At location of maximum residence time.1 Based on Initial Distribution System Evaluation (IDSE) requirements.2 Compliance Calculation RAA must not exceed the MCL for TTHM or HAAS. LRAA must not exceed the MCL for TTHM or HAAS. DO c *i_ O •4—• 'c o QJ O) OL Eligibility TTHM/HAA5 All systems need TTHM RAA < 0.040 mg/L and HAAS < 0.030 mg/L. Subpart H systems also need source water TOC RAA at location prior to treatment < 4.0 mg/L.3-4 The Stage 2 DBPR left eligibility unchanged but specifies that Subpart H systems must take source water TOC samples every 30 days. Subpart H systems on reduced monitoring must take source water TOC samples every 90 days to qualify for reduced monitoring. Bromate5 Source water bromide RAA < 0.05 mg/L. With the Stage 2 DBPR specified entry point to distribution system bromate RAA < 0.0025 mg/L. 1Subpart H systems serving >_ 10,000 must have at least 25 percent of samples at the location of maximum residence time; the remaining samples must be representative of average residence time. 2AII systems are required to satisfy their IDSE requirement by July 10, 2010. 3Subpart H systems are water systems that use surface water or ground water under the direct influence of surface water (GWUDI). 4Ground water systems serving < 10,000 must meet these RAA for 2 years; can also qualify for reduced monitoring if the TTHM RAA is < 0.020 mg/L and a HAAS RAA < 0.015 mg/L for 1 year. 5A new analytical method for bromate was established with the Stage 2 DBPR. Table 2. Regulated Contaminants and Disinfectants Regulated Contaminants TTHM Chloroform Bromodichloromethane Dibromochloromethane Bromoform HAAS Monochloroacetic acid Dichloroacetic acid Trichloroacetic acid Bromoacetic acid Dibromoacetic acid Bromate (plants that use ozone)1 Chlorite (plants that use chlorine dioxide) Regulated Disinfectants Chlorine Chloramines Chlorine dioxide Stage 1 DBPR MCL (mg/L) 0.080 0.060 0.010 1.0 MRDL3 (mg/L) 4.0asCI2 4.0asCI2 0.8 MCLG (mg/L) - Zero 0.06 Zero Zero 0.3 - Zero 0.8 MRDLG3 (mg/L) 4 4 0.8 Stage 2 DBPR MCL (mg/L) Unchanged2 Unchanged2 Unchanged2 Unchanged2 MRDL (mg/L) Unchanged2 Unchanged2 Unchanged2 MCLG (mg/L) 0.07 Unchanged2 Unchanged2 Unchanged2 0.07 Unchanged2 0.2 - Unchanged2 Unchanged2 MRDLG (mg/L) Unchanged2 Unchanged2 Unchanged2 1A new analytical method for bromate was established with the Stage 2 DBPR. 2Stage 2 DBPR did not revise the MCL or MRDL for this contaminant/disinfectant. 3Stage 1 DBPR included MRDLs and MRDLGs for disinfectants, which are similar to MCLs and MCLGs. ------- Table 3. Compliance Determination TTHM/HAA5 Bromate1 Chlorite Chorine dioxide Chlorine/chloramines DBP precursors (TOC sample set)* Stage 1 DBPR RAA RAA Daily/follow-up monitoring Daily/follow-up monitoring RAA Monthly for TOC and alkalinity Stage 2 DBPR LRAA Unchanged2 Unchanged2 Unchanged2 Unchanged2 Every 30 days for TOC and alkalinity 1A new analytical method for bromate was established with the Stage 2 DBPR. 2Stage 2 DBPR did not change the compliance requirements for this contaminant/disinfectant. *TOC sample set is comprised of source water alkalinity, source water TOC, and treated TOC. Table 4. Compliance with MCLs and MRDLs (Routine Monitoring) Contaminant/ Disinfectant TTHM/HAA5 Bromate3 Chlorite Chlorine dixoide Chorine/ Chloramines DBP precursors (TOC sample set)* Coverage Source Water Subpart H Ground water Population <500 500 - 3,300 3,301 -9,999 10,000-49,000 50,000 - 249,999 250,000 - 999,999 1 ,000,000 - 4,999,999 > 5,000,000 <500 500 - 9,999 10,000-99,999 100,000-499,999 > 500,000 Systems that use ozone as a disinfectant Systems that use chlorine dioxide as a disinfectant Systems that use chlorine dioxide as a disinfectant All systems Systems that use conventional filtration Stage 1 DBPR Monitoring Frequency Per year2 Per quarter Per year2 Per quarter Monthly Daily (at entrance to distribution system); monthly (in distribution system) Daily Total Distribution System Monitoring Locations 1 per treatment plant 1 per treatment plant 4 per treatment plant 1 per treatment plant 1 at entry point to distribution system 1 at entry point to distribution system; 3 in distribution system 1 at entry point to distribution system Same location and frequency as Total Coliform Rule (TCR) sampling Monthly 1 per source water source Stage 2 DBPR Monitoring Frequency1 Per year2 Per quarter Per year2 Per quarter Total Distribution System Monitoring Locations 2 2 4 8 12 16 20 2 4 6 8 Unchanged4 Unchanged4 Unchanged4 Unchanged4 Unchanged4 1AII systems must monitor during the month of highest DBP concentrations. Systems on quarterly monitoring, except Subpart H systems serving 500 - 3,300, must take dual sample sets every 90 days at each monitoring location. Systems on annual monitoring and Subpart H systems serving 500 - 3,300 are required to take individual TTHM and HAAS samples (instead of a dual sample set) at the locations with the highest TTHM and HAAS concentrations, respectively. If monitoring annually, only one location with a dual sample set per monitoring period is needed if the highest TTHM and HAAS concentrations occur at the same location and in the same month. 2Ground water systems serving < 10,000 and Subpart H systems serving < 500 must increase monitoring to quarterly if an MCL is exceeded. 3A new analytical method for bromate was established with the Stage 2 DBPR. 4Stage 2 DBPR did not revise the monitoring frequency or location requirements for this contaminant/disinfectant. *TOC sample set is comprised of source water alkalinity, source water TOC, and treated TOC. ------- Table 5. Operational Evaluation Levels (OELs) Applies to: Purpose of establishing OELs: OEL calculations: OELs are exceeded: If an OEL is exceeded, a system must: The operational evaluation must include: OEL requirements take effect: All systems subject to Stage 2 DBPR monitoring requirements that conduct compliance monitoring and collect samples quarterly. To reduce peaks in DBP levels and exposure to high DBP levels. ^ Calculated for both TTHMs and HAASs at each monitoring location using Stage 2 DBPR compliance monitoring results. ^ OEL is determined by the sum of the two previous quarter's TTHM or HAAS result plus twice the current quarter's TTHM or HAAS result at that location, divided by four. > OEL=(Q1 +Q2 + 2Q3)/4 During any quarter in which the OEL is greater than the TTHM or HAAS MCL. ^- Conduct an operational evaluation. ^- Submit a written report of the evaluation to the state no later than 90 days after being notified of the analytical results that caused the exceedance(s). ^- Keep a copy of the operational evaluation report and make it publically available upon request. ^- An examination of the treatment and distribution systems' operational practices that may contribute to TTHM and HAAS formation. ^ Steps to minimize future exceedances. When the system begins compliance monitoring for the Stage 2 DBPR. « I For additional information on the DBPRs: Call the Safe Drinking Water Hotline at 1-800- 426-4791; visit the EPA web site at http://water. epa.gov/drink: or contact your state drinking water representative. Table 6. Standard Monitoring Compliance Dates If You are a System Serving: At least 1 00,000 people or part of a combined distribution system (CDS) serving at least 100,000 people. 50,000 to 99,999 people or part of a CDS serving 50,000 to 99,999 people. 1 0,000 to 49,999 people or part of a CDS serving 10,000 to 49,999 people. Less than 10,000 people or part of a CDS serving less than 10,000 people. Schedule1 1 2 3 4 Begin LRAA TTHM & HAAS Monitoring By: April 1,2012 October 1, 2012 October 1, 2013 October 1, 201 32 1Your schedule is determined by the largest system in your CDS. 2Systems not conducting Cryptosporidium monitoring under Long Term 2 Enhanced Surface Water Treatment Rule (LT2ESWTR) must begin LRAATTHM/HAA5 monitoring by this date. Systems conducting Cryptosporidium monitoring under LT2ESWTR must begin LRAATTHM/HAA5 monitoring by October 1, 2014. Table 7. TOC Removal Subpart H systems that use conventional filtration treatment are required to remove specific percentages of organic materials, measured as total organic carbon (TOC), that may react with disinfectants to form DBFs. Removal must be achieved through a treatment technique (enhanced coagulation or enhanced softening) unless a system meets alternative criteria. Systems practicing softening must meet TOC removal requirements for source water alkalinity greater than 120 mg/L CaC03. Source Water TOC (mg/L) > 2.0 to 4.0 > 4.0 to 8.0 >8.0 Source Water Alkalinity, mg/L as CaCO3 0-60 35.0% 45.0% 50.0% > 60 to 120 25.0% 35.0% 40.0% > 120 15.0% 25.0% 30.0% Office of Water (4606M) EPA 816-F-10-080 http://water.epa.gov/drink August 2010 ------- |