c/EPA
EPA/600/R-09/132
October 2009
Measurement of Emissions from Produced Water Ponds:
Upstream Oil and Gas Study #1
Final Report
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EPA/600/R-09/132
October 2009
Measurement of Emissions from Produced Water Ponds:
Upstream Oil and Gas Study #1
by
Eben Thoma
Air Pollution Prevention and Control Division
National Risk Management Research Laboratory
Research Triangle Park, NC 27711
National Risk Management Research Laboratory
Office of Research and Development U.S. Environmental Protection Agency
Cincinnati, Ohio 45268
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Table of Contents
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
List of Appendices ii
List of Tables iii
List of Figures vii
List of Acronyms ix
Executive Summary xi
1. Introduction 1
1.1 Background 1
1.2 Phase 1 Project and Report Description 2
2. Description of Test Sites and Measurement Methods 5
2.1 The Williams Rulison and EnCana Benzel Test Sites 5
2.2 Description of EPA OTM 10 Measurements 9
2.3 OP-FTIR VOC Analysis and Calculation of Estimated VOC Flux 13
2.4 Description of SUMMA Canister Measurements 16
2.5 Description of Water Sampling 17
3. Results and Discussion 21
3.1 Results Summary Approach 21
3.2 AM Flux Summary for the Williams Rulison Facility 23
3.3 AM Flux Summary for the EnCana Benzel Facility 29
3.4 Results of OP-FTIR VOC Concentration Analysis and Estimated VOC
Fluxes Using Ratio Method 34
3.5 Results of Canister Measurements 39
3.6 Summary of Water Analysis Results 52
4. Summary 57
5. Quality Assurance/Quality Control 59
5.1 Instrument Calibration 59
5.2 Assessment of DQI Goals 59
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5.2.1 DQI Check for Analyte PIC Measurement
5.2.2 DQI Checks for TO-15 Can Measurements
5.2.3 DQI Checks for Ambient Wind Speed and Wind Direction
Measurements
5.2.4 DQI Checks for the Topcon Theodolite
5.2.5 QC Checks of OP-FTIR Instrument Performance
5.2.6 Difficulties Encountered
5.3 Estimate of Uncertainty for OTM 10 Emission Measurements
5.4 EPA and ARCADIS Audits and Corrective Actions
6. References
61
62
62
62
63
63
64
68
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Table of Contents
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
List of Appendices
Appendix A: OTM 10 Alkane Mixture Flux Values
Appendix B: ERG SUMMA Canister Data
Appendix C: EPA R8 Water Analysis
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List of Tables
Table of Contents
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table E-1. Summary of AM Emission Flux Results from William Rulison and EnCana
Benzel Sites xii
Table E-2. Summary of Estimated select VOC Emission Rates from William Rulison
and EnCana Benzel Sites xii
Table 2-1. Optical Configuration Details for the Williams Facility Setup 11
Table 2-2. Optical Configuration Details for the EnCana Facility Setup 11
Table2-3. Instrument Operation Time Periods for the EPA OTM 10 Method 13
Table 2-4. Periods of OP-FTIR VOC Analysis 14
Table 2-5. Detection Limits for Optimal OP-FTIR Setup with Clean, Fully Populated
Retroreflector Arrays 15
Table 2-6. Periods of SUMMA Canister/ OP-FTIR VOC Analysis 16
Table 2-7. SUMMA Canisters Deployed at the Williams Rulison and EnCana Benzel
Facilities 18
Table 3-1. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the Williams Rulison Facility on August 6, 2008 24
Table 3-2. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the Williams Rulison Facility on August 7, 2008 25
Table 3-3. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the Williams Rulison Facility on August 8, 2008 26
Table 3-4. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the Williams Rulison Facility on August 9, 2008 27
Table 3-5. Summary Table of the Mass Emission Flux Results(g/s) for the
Configuration used at the EnCana Benzel Facility on August 12, 2008 30
Table 3-6. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the EnCana Benzel Facility on August 13, 2008 31
Table 3-7. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the EnCana Benzel Facility on August 14, 2008 32
Table 3-8. Summary Table of the Mass Emission Flux Results (g/s) for the
Configuration used at the EnCana Benzel Facility on August 15, 2008 33
Table 3-9. Summary of OP-FTIR VOC Concentration Determinations (concentrations
in ppb) 35
Table 3-10. Summary of OP-FTIR VOC to AM Mass Concentration Ratio Calculations
37
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-11. Summary of the Average Mass Concentration Ratios of VOC to Alkane
Mixture, for the Williams and EnCana sites 38
Table 3-12. Estimated Emission Flux Values (g/s) of select VOCs from the Williams and
EnCana Sites 38
Table 3-13. Comparison of Canister and OP-FTIR Results 39
Table 3-14. Summary Canister Summary from the Williams and EnCana Sites 41
Table 3-15. Summary Water Analysis from the Williams Site 55
Table 3-16. Summary Water Analysis from the EnCana Site 55
Table 4-1. AM Emission Flux Results from William Rulison and EnCana Benzel Sites 57
Table 4-2. Summary of Estimated VOC Emission Rates (in grams per second) from
William Rulison and EnCana Benzel Sites 58
Table 5-1. Instrumentation Calibration Frequency and Description 60
Table 5-2. Measurement Quality Objectives for the Project 60
Table 5-3. Results of Flux Values Calculated by the VRPM Fit Explorer Program With
a Fixed Peak Plume Concentration Location and Varying Values of the oy
Parameter 66
Table 5-4. Results of Flux Values Calculated by the VRPM Fit Explorer Program with a
Fixed oy Parameter and Varying Peak Plume Concentration Locations 67
Table A-1. Relative Absorption Factor (AF) of Select Hydrocarbon Species in the
2804.2 cm"1 to 3001.2 cm"1 Spectral Range (values are normalized to n-
Octane) A-7
Table A-2. Summary Data Table of VRPM Plane A123 for August 6, 2008 at the
Williams Rulison Facility A-14
Table A-3. Summary Data Table of VRPM Plane A456 for August 6, 2008 at the
Williams Rulison Facility A-15
Table A-4. Summary Data Table of VRPM Plane E123 for August 6, 2008 at the
Williams Rulison Facility A-16
Table A-5. Summary Data Table of VRPM Plane E456 for August 6, 2008 at the
Williams Rulison Facility A-17
Table A-6. Summary Data Table of VRPM Plane A123 for August 7, 2008 at the
Williams Rulison Facility A-18
Table A-7. Summary Data Table of VRPM Plane A456 for August 7, 2008 at the
Williams Rulison Facility A-21
Table A-8. Summary Data Table of VRPM Plane E123for August 7, 2008 at the
Williams Rulison Facility A-24
IV
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October 2009 (Rev. 0.6)
Table A-9. Summary Data Table of VRPM Plane E456 for August 7, 2008 at the
Williams Rulison Facility A-27
Table A-10. Summary Data Table of VRPM Plane A123 for August 8, 2008 at the
Williams Rulison Facility A-30
Table A-11. Summary Data Table of VRPM Plane A456 for August 8, 2008 at the
Williams Rulison Facility A-32
Table A-12. Summary Data Table of VRPM Plane E123for August 8, 2008 at the
Williams Rulison Facility A-34
Table A-13. Summary Data Table of VRPM Plane E456 for August 8, 2008 at the
Williams Rulison Facility A-36
Table A-14. Summary Data Table of VRPM Plane A123 for August 9, 2008 at the
Williams Rulison Facility A-38
Table A-15. Summary Data Table of VRPM Plane A456 for August 9, 2008 at the
Williams Rulison Facility A-40
Table A-16. Summary Data Table of VRPM Plane E123for August 9, 2008 at the
Williams Rulison Facility A-42
Table A-17. Summary Data Table of VRPM Plane E456 for August 9, 2008 at the
Williams Rulison Facility A-44
Table A-18. Summary Data Table of VRPM Plane A123 for August 12, 2008 at the
EnCana Benzel Facility A-47
Table A-19. Summary Data Table of VRPM Plane A456 for August 12, 2008 at the
EnCana Benzel Facility A-49
Table A-20. Summary Data Table of VRPM Plane E123 for August 12, 2008 at the
EnCana Benzel Facility A-51
Table A-21. Summary Data Table of VRPM Plane E456 for August 12, 2008 at the
EnCana Benzel Facility A-54
Table A-22. Summary Data Table of VRPM Plane A123 for August 13, 2008 at the
EnCana Benzel Facility A-57
Table A-23. Summary Data Table of VRPM Plane A456 for August 13, 2008 at the
EnCana Benzel Facility A-61
Table A-24. Summary Data Table of VRPM Plane E123 for August 13, 2008 at the
EnCana Benzel Facility A-66
Table A-25. Summary Data Table of VRPM Plane E456 for August 13, 2008 at the
EnCana Benzel Facility A-69
Table A-26. Summary Data Table of VRPM Plane A123 for August 14, 2008 at the
EnCana Benzel Facility A-72
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Table A-27. Summary Data Table of VRPM Plane A456 for August 14, 2008 at the
EnCana Benzel Facility A-76
Table A-28. Summary Data Table of VRPM Plane E123 for August 14, 2008 at the
EnCana Benzel Facility A-80
Table A-29. Summary Data Table of VRPM Plane E456 for August 14, 2008 at the
EnCana Benzel Facility A-83
Table A-30. Summary Data Table of VRPM Plane A123 for August 15, 2008 at the
EnCana Benzel Facility A-86
Table A-31. Summary Data Table of VRPM Plane A456 for August 15, 2008 at the
EnCana Benzel Facility A-88
Table A-32. Summary Data Table of VRPM Plane E123 for August 15, 2008 at the
EnCana Benzel Facility A-90
Table A-33. Summary Data Table of VRPM Plane E456 for August 15, 2008 at the
EnCana Benzel Facility A-92
VI
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List of Figures
Table of Contents
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 2-1. Williams Rulison Facility
Figure 2-2 Details of the Site Layout for Williams Rulison Facility
Figure 2-3. EnCana Benzel Facility
Figure 2-4. Four Corner Configuration
Figure 2-5. Location of Water Sampling Points at the Williams Facility
Figure 2-6. Location of Water Sampling Points at the EnCana Facility
Figure 3-1. Time Series of Mass Emission Flux for August 6, 2008 at the Williams
Rulison Facility
Figure 3-2. Time Series of Mass Emission Flux for August 7, 2008 at the Williams
Rulison Facility
Figure 3-3. Time Series of Mass Emission Flux for August 8, 2008 at the Williams
Rulison Facility
Figure 3-4. Time Series of Mass Emission Flux for August 9, 2008 at the Williams
Rulison Facility
Figure 3-5. Time Series of Mass Emission Flux for August 12, 2008 at the EnCana
Benzel Facility
Figure 3-6. Time Series of Mass Emission Flux for August 13, 2008 at the EnCana
Benzel Facility
Figure 3-7. Time Series of Mass Emission Flux for August 14, 2008 at the EnCana
Benzel Facility
Figure 3-8. Time Series of Mass Emission Flux for August 15, 2008 at the EnCana
Benzel Facility
Figure 3-9. Summary of Downwind Canisters SNMOC Analysis for the Williams Facility
Figure 3-10. Summary of Downwind Canisters SNMOC Analysis for the EnCana Facility
Figure 3-11. Williams 8/7/08, Canister TNAPC11 and OP-FTIR Path E4.
Figure 3-12. Williams 8/8/08, Canisters 648 and 926 Compared to OP-FTIR Path E4 and
Canister 3639A Compared to OP-FTIR Path A1
Figure 3-13.
Figure 3-14. EnCana 8/12/08, Canister ER029 Compared to OP-FTIR Path E1
Williams 8/9/08, Canister ER047 Compared to OP-FTIR Path E4 and
Canisters ER038 and ER001 Compared to OP-FTIR Path A1
6
7
8
10
19
20
24
25
26
27
30
31
32
33
42
43
45
46
47
48
VII
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October 2009 (Rev. 0.6)
Figure 3-15. EnCana 8/13/08, Canister 3255 Compared to OP-FTIR Path E1 and
Canisters ER043 and 444 Compared to OP-FTIR Path A4 49
Figure 3-16. EnCana 8/13/08, Canister TNAPC20 Compared to OP-FTIR Path E1 and
Canisters 3254 and 167601 Compared to OP-FTIR Path A4 50
Figure 3-17. EnCana 8/14/08, Canister ER061 Compared to OP-FTIR Path E1 and
Canisters ER064 and ER069 Compared to OP-FTIR Path A4 51
Figure 3-18. EnCana 8/14/08, Canister 15280 Compared to OP-FTIR Path E1 and
Canisters 988 and 3248 Compared to OP-FTIR Path A4 53
Figure 3-19. EnCana 8/15/08, Canister ER021 Compared to OP-FTIR Path A1 and
Canisters ER085 and ER114 Compared to OP-FTIR Path A4 54
Figure A-1. Comparison of the Absorption Bands of Several Species in the C-H Stretch
Region A-4
Figure A-2. Summa Canister SNMOC Analysis Showing Compound Distribution
(Section 3.5) A-8
Figure A-3. Estimation of Contribution to AM Band, SNMOC Result Multiplied by AF A-9
Figure A-4. Normalized Concentration vs. Molecular Weight for the Distribution of
Figure A-3 A-10
VIM
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October 2009 (Rev. 0.6)
List of Acronyms
AM
CCF
DQI
ECPB
EPA
GC-MS
MDL
MCR
NOUT
OAQPS
OP-FTIR
ORD
ORS
OTM10
PAC
PI
PIC
QA
QAPP
QC
RSD
S
SOUT
SNMOC
SOP
SPIN
SPOUT
AM
TAM
TO
UOGEM1
VOA
VOC
VRPM
Alkane Mixture
Concordance Correlation Factor
Data Quality Indicator(s)
Emissions Characterization and Prevention Branch
Environmental Protection Agency
Gas Chromatography-Mass Spectroscopy
Minimum detection limit
Mass Concentration Ratio
North Pond Outlet
EPA Office of Air Quality Planning and Standards
Open-Path Fourier Transform Infrared
Office of Research and Development
Optical Remote Sensing
EPA ORS Test Method OTM 10
Path averaged concentration
Principal Investigator
Path integrated concentration
Quality Assurance
Quality Assurance Project Plan
Quality Control
Relative Standard Deviation
South
South Pond Outlet
Speciated non-methane organic compounds
Standard Operating Procedures
Skim Pond Inlet
Skim Pond Outlet
Sum of Squared Errors
Alkane Mixture
Time Averaging Method
Toxic Organic
Upstream Oil and Gas Emission Measurement study, Phase 1
Volatile Organics Analysis
Volatile Organic Compound
Vertical Radial Plume Mapping
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Executive Summary
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Executive Summary
Significant uncertainty exists regarding air pollutant emissions from upstream oil and
gas production operations. Oil and gas operations present unique and challenging
emission testing issues due to the large variety and quantity of potential emission
sources. To improve emission knowledge for this sector, a project team with
representatives from United States Environmental Protection Agency's (EPA) Office of
Air Quality Planning and Standards (OAQPS), EPA Office of Research and
Development (ORD) and their contractors, EPA Region 8, and the states of Colorado
and Wyoming was formed and is working to define and execute a multi-phased
research effort. This report summarizes Phase I of the effort, which helps address an
immediate need of EPA Region 8 and states to improve understanding of volatile
organic compound (VOC) emissions from oil and gas produced water evaporation
ponds. Phase I field measurements focused on a subset of VOCs that are commonly
found in oil and gas production operations and are quantifiable using area source
measurement method EPA OTM 10 (EPA, 2006) and related techniques. This subset
includes mixture of alkanes, benzene, toluene, xylenes, methanol, and methane.
This report presents emission flux estimates from the holding evaporation ponds at the
Williams Rulison and EnCana Benzel facilities in Western Colorado acquired August 6-
9 and 12-15, 2008, respectively. The primary measurement approach was EPA OTM
10 using two open-path Fourier transform infrared (OP-FTIR) instruments deployed
around the ponds to provide mass emission flux estimates for an alkane mixture (AM)
by spectroscopic analysis of the infrared absorption features in the C-H stretch spectral
region around 2900 cm"1. The AM was chosen for analysis since it was robustly
quantifiable by the utilized methodology whereas other species of interest were
frequently below detection limits of the OP-FTIRs so could not be used for standard
OTM 10 flux measurements. Estimates of emission flux for select VOCs, which were
quantifiable by OP-FTIR using time averaging techniques, were also produced. These
estimates utilized a VOC to AM mass concentration ratio calculation determined when
the AM concentrations were relatively high.
Table E-1 presents a summary of the AM emission flux results from the two sites. The
values in the table represent the average of all valid 20-minute AM flux estimates
calculated over a four-day period at each site with standard deviation in parenthesis
and number of values indicated. The uncertainty estimate for the individual flux
measurements comprising this average is estimated at ± 40%. The uncertainty in the
overall average is likely driven by the temporal variability in the source emissions.
XI
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Executive Summary
Measurement of Emissions
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October 2009 (Rev. 0.6)
Table E-1. Summary of AM Emission Flux Results from William Rulison and EnCana
Benzel Sites
Site
Williams
Wlliams
EnCana
Source
Evaporation Pond
Skim Pond
Evaporation Pond
Average AM Flux
[g/s]
0.20 (0.33)
0.90(0.58)
0.07 (0.06)
Number of
Values
27
15
65
Table E-2 presents a summary of emission flux estimates for select VOCs produced
using a mass concentration ratio technique. For this estimate, the compound to AM
mass concentration ratio and AM emission flux results for similar time periods were
utilized to produce the emission rates estimate. The values of Table E-2 include
underlying uncertainty in AM flux measurement average in addition to significant VOC
to AM concentration ratio uncertainty so the values should be considered estimates.
Table E-2. Summary of Estimated select VOC Emission Rates from William Rulison and
EnCana Benzel Sites
Site
Williams
Williams
EnCana
Source Area
Evaporation Pond
Skim Pond
Evaporation Pond
Benzene
(9/s)
0.018
0.078
0.029
Toluene
(g/s)
0.040
0.181
0.023
m-Xylene
(g/s)
0.016
0.072
0.017
o-Xylene
(g/s)
0.040
0.182
0.014
p-Xylene
(g/s)
0.020
0.088
0.014
Methanol
(g/s)
0.001
0.006
0.002
Methane
(g/s)
0.017
0.074
0.007
To provide supporting information, the concentration of the AM and select VOCs were
determined using one-hour SUMMA canister sampling deployed at positions around
the ponds. The canisters were analyzed with EPA Method TO-15 and SNMOC
analysis and were compared to OP-FTIR measurements for similar time periods.
Additionally, water samples were taken during the campaign and these results are
included as supporting information.
Note that the emission estimates presented in this report represent a snapshot in time
consisting of day-time observations over consecutive four-day periods at each facility
during the month of August. Diurnal and seasonal effects in addition to changing
process variables were not evaluated as part of this study. Since these variables may
have a significant effect on emissions, extrapolation of the results contained in this
report involves significant uncertainty. As a specific example, methanol-water
concentrations are known to vary seasonally so the emission data contained in this
report is may not be typical.
XII
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1. Introduction
1.1 Background
EPA Region 8 and, in particular the State of Colorado, is home to numerous oil and gas
production operations (also called upstream operations). In recent years, Colorado has seen
ozone levels that exceed national ambient air quality standards with levels increasing at
several sites. It is thought that emissions of volatile organic carbon (VOC) ozone precursor
compounds from upstream oil and gas operations may contribute in part to these
exceedance episodes. With the continued increase in oil and gas production operations
coupled with new lowered ozone standards, the potential for exceedance episodes may
increase. Emissions of VOCs including hazardous air pollutants (HAPS) is a general concern
to the public and press prompting regular inquiries to the affected state agencies and Region
8. In addition to air quality issues, emissions from upstream oil and gas operations include a
significant proportion of methane which is a potent greenhouse gas and could become a key
concern if regulating agencies moves to greenhouse gas emissions quantification, reporting
and control.
Significant uncertainty exists regarding air pollutant emissions from upstream oil and gas
production operations which start with well completion and work-over activities, to well-site
operations through to midstream production and waste handling. Models exist to estimate
emissions from some of these emission sources such as: amine units, glycol dehydrators
and oil/condensate storage tanks. These modeled emissions represent only a fraction of the
emissions and may underestimate these emissions from oil and gas production activities.
The Texas Commission on Environmental Quality is currently conducting a project to
compare modeled emissions from condensate tanks to actual emission measurements.
Development and application of tools to quantify both VOC and methane emissions would
help the regulatory community, citizens, and industry better assess emission contributions
from upstream oil and gas operations in Colorado, the other states in Region 8, and in
Region 6 which also has the same concerns. Data collected in our field testing can be used
to develop a more robust inventory of oil and gas operation emissions from which mitigation
options can be quantified and compared. This can ultimately lead to more effective control of
ozone precursors and greenhouse gases and protection of air quality.
Oil and gas fields provide very unique and challenging testing issues due to their large
variety and quantity of emissions sources. For example, one 30 mile by 15 mile section of
Garfield County in Colorado contains over 3,000 well sites and Weld County in Colorado
contains over 20,000 well sites. Producing oil or gas well sites each require various
combinations of supporting process equipment such as separators, dehydrators, generators,
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Measurement of Emissions
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natural gas powered pneumatic devices, injection wells, heaters, compressors/engines,
storage tanks, land farms, and produced water ponds. In addition to all these potential
emissions sources, there are also a variety of activities such as well drilling, well completion,
well work-over, and loading/unloading of oil/produced water into trucks which have the
potential to generate organic emissions. There is little or no data regarding the emissions
from most of these sources and activities.
A project team with representatives from EPA OAQPS, EPA ORD and their contractors, EPA
Region 8, and the states of Colorado and Wyoming are working to define and execute a
multi-phased research effort to address this important issue. Phase I of the of the upstream
oil and gas emissions measurement program (UOGEM1) helps address the immediate need
of Region 8 and states to improve understanding of VOC emissions from oil and gas
produced water evaporation ponds (produced water generally refers to water that this co-
emitted with oil and gas as part of the production process). These emissions data will help
stakeholders increase understanding regarding the accuracy of their emission inventories
and further residual risk knowledge and potential environmental impact of this source
category. This report may also provide a basis for future protocols for testing this source
category.
1.2 Phase 1 Project and Report Description
Phase I of UOGEM1 involved a two-week testing project designed to improve understanding
of VOC emissions from oil and gas produced water evaporation ponds. The field campaign
was conducted at the Williams Rulison and EnCana Benzel facilities in Western Colorado
from August 6-9 and 12-15, 2008 respectively. The measurement campaign focused on a
subset of VOCs that are commonly found in oil and gas production operations and are
quantifiable using EPA area source method OTM 10 and related techniques. This subset
includes mixture of alkanes, benzene, toluene, xylenes, methanol, and methane.
This report presents emission flux estimates from the holding evaporation ponds at the
Williams Rulison and EnCana Benzel facilities in Western Colorado acquired August 6-9 and
12-15, 2008, respectively. The primary measurement approach was OTM 10 using two
open-path Fourier transform infrared (OP-FTIR) instruments deployed in a four corners
configuration to provide mass emission flux estimates for an alkane mixture (AM) by
spectroscopic analysis of the infrared absorption features in the C-H stretch spectral region
around 2900 cm"1. The AM, further described in Appendix A, was chosen for analysis since it
was robustly quantifiable by the utilized methodology whereas other species of interest were
frequently below detection limits of the OP-FTIRs so could not be used for standard OTM 10
flux measurements. Estimates of emission flux for select VOCs, which were quantifiable by
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Measurement of Emissions
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October 2009 (Rev. 0.6)
OP-FTIR using time averaging techniques, were also produced. These estimate utilized a
VOC to AM mass concentration ratio calculation based on the AM flux data for similar time
periods. These estimates were produced when AM concentrations were relatively high. To
provide supporting information, the concentration of an estimated AM along with select
speciated VOCs were determined using SUMMA canister sampling with EPA Method TO-15
and SNMOC analysis. These results were compared to the OP-FTIR measurements to help
inform overall results. Water samples from the ponds were also acquired and analyzed to
help support the overall study.
Section 2 of the report provides a description of the Williams Rulison and EnCana Benzel
facilities, information of the measurement methods used, and the location of the
measurement configurations used at each site. Section 3 presents the results of the OTM 10
AM flux surveys conducted at each site along with supporting canister and water sampling
information. Section 4 presents a summary of the findings, and Section 5 discusses quality
assurance/quality control of the measurements and uncertainty extimations.
Appendix A presents information on the AM calculation and the OTM 10 measurements
collected during the campaign. Appendix B contains the results of the SUMMA canister
analysis and Appendix C contains the results of the water analysis.
The Phase 1 project was conducted by ARCADIS U.S., Inc. (ARCADIS), Durham, NC, under
EPA ORD contract No. EP-C-04-023, Work Assignment No. 4-49. ARCADIS executed the
field campaign, analyzed the OP-FTIR and OTM 10 data, and produced data tables and
descriptions in Section 3.2, 3.3 and 3.4 and AM concentration data tables in Appendix A.
ARCADIS provided parts of Section 5, contributed to the descriptions in Section 2, and
provided wind direction summaries included Section 3.5. The Summa canister laboratory
analysis contained in Appendix B was performed by Eastern Research Group Inc.,
Morrisville, NC under subcontract to ARCADIS.
EPA Personnel were primary authors on the body and summary sections of the report,
produced the canister and water data summary analyses and comparative descriptions and
graphs of Section 3.5 and 3.6, the uncertainty discussion and simulations in Section 5, and
the AM descriptions and graphs in Appendix A. The water analysis contained in Appendix C
was performed by EPA Region 8.
This report has been reviewed by the Office of Research & Development, U.S. EPA, and
approved for publication. Approval does not signify that the contents necessarily reflect the
views and policies of the agency nor does mention of trade names or commercial products
constitute endorsement or recommendation for use.
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2. Description of Test Sites and Measurement Methods
The following section describes the two test sites and the utilized measurement methods.
Section 2.1 describes the Williams Rulison and EnCana Benzel facilities and shows the
layout of each site. Section 2.2 describes the EPA OTM 10, Vertical Radial Plume Mapping
(VRPM) method used to assess mass emission flux of the alkane mixture (AM) from the
sites. Section 2.3 describes emission flux estimates for select VOCs that were quantifiable
by OP-FTIR using extended time averaging techniques. Section 2.4 describes the
supporting SUMMA canister concentration measurements made at each of the ponds.
Section 2.5 describes supplemental water sampling activities conducted on site. Detailed
information on OTM 10 averaging periods and data analysis and OP-FTIR spectral analysis
is contained in Sections 3 and Appendix A.
2.1 The Williams Rulison and EnCana Benzel Test Sites
The two test sites chosen for this study were selected based on logistical and access factors.
The first site, the Williams Rulison Facility, was tested from August 6-9, 2008 and is shown in
Figures 2-1 and 2-2. The second site, the EnCana Benzel Facility, was tested from August
12-15, 2008 and is shown in Figure 2-3.
The Williams Rulison facility had a complex layout compared to the EnCana Benzel Facility,
and Figure 2-2 identifies the details that surround the large evaporation apron and the two
evaporation holding ponds. As explained by Williams personnel, water from the oil and gas
production operations is delivered by truck or a small pipe line to Tank A where the first
stage of oil-water separation occurs, then to Tank E for the second stage of separation). Oil
from both stages is pumped to Tank B, oil sales. The water is passed through to the Tank G
at then enters the skim pond. The water passes through the skim pond operation and then
into the north evaporation pond (North Pond) where aeration is employed to assist aerobic
bio-treatment of the water. Water exits the North Pond at its west side and enters the South
Pond. At the east side of the South Pond, water is pumped back into the North Pond. Some
water from the South Pond is also pumped to Tank C, the frac water loadout. This water is
trucked back to the field to be used again in drilling operations. The large evaporation apron
to the north of the North Pond is used to evaporate water through misting sprayers. This
process occurs infrequently and was not performed during the test period. Since the misting
operation was not used during the study, no estimate of emission from this potential source
could be made. The evaporation apron had shallow pockets of standing water (likely to be
rain water). Note the figures presented below are stock satellite images and are not
representative of site conditions during the study. For example, there was very little standing
water in the evaporation apron during the study.
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 2-1. Williams Rulison Facility
Location:
Site Process Description:
Dimensions of Ponds:
Approximately 2 miles north of Rulison, CO (Lat: 39.508858; Long: -
107.918335). The magnetic declination was calculated to be -15.8525°
Water is trucked into the facility. The receiving tanks are heated to induce
separation. Then the water flows to heated polishing tanks before entering
the oil-water separators. At the outlet of the oil-water separators, the water
is injected with aerobic bacteria to reduce hydrocarbons. There is extensive
separation prior to ponds.
There are two ponds at the site. The exact dimensions of the ponds are not
known. However, we estimated that the first pond has a surface area about
of 3.1 acres, and the second pond has a surface area of about 2.7acres.
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
ClFntKOlMdMl
tt CUfnUff wparjttr
FI itadtlf C**
0*
Figure 2-2 Details of the Site Layout for Williams Rulison Facility
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 2-3. EnCana Benzel Facility
Location:
Site Process Description:
Dimensions of Pond:
Approximately 10 miles south of Rifle, CO. (Lat: 39.500149; Long: -
107.739334). The magnetic declination was calculated to be -15.6575°
Water is piped into facility via a pipeline. There will be some separation prior
to the facility. There is only one stage of separation using chemical
demulsifying agents prior to the pond. Minimal separation prior to ponds.
There is one pond at the site with dimensions of 350' x 150' and a surface
area of 1.2 acres.
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
The daily incoming flow (volume) for the Williams facility for August 6, 7 and 8, 2008 was
4700, 6400, and 4900 barrels per day, respectively, into Building A as shown in Figure 2-2.
On each day of testing, ARCADIS personnel also took a number of flow measurements from
the meter located outside of Building A. The flow rates were highly variable, and ranged as
follows: August 6, from a reverse flow reading at one point to 6.2 barrels/min; August 7, from
2.3 to 15.5 barrels/min; and August 8, from 1.7 to 14.9 barrels/min.
The second site, the EnCana Benzel Facility, was tested from August 12-15, 2008 and is
shown in Figure 2-3. Water is piped into tanks on the northern side of the pond, which can
be seen under the red line connecting the scissor jack and the EPA FTIR (ID E123). These
tanks are where the one-stage separation using chemical demulsifying agents occurs prior to
the water bring pumped into the pond. The brown areas north of the pond and tanks are
racks of used pipes, another likely source of hydrocarbons. A neighboring facility can be
seen north of the pipe racks. No in coming flow information was available to be recorded
during monitoring at the Benzel facility. EnCana later provided an estimate of-285 barrels
per day average throughput during the week of the study.
2.2 Description of EPA OTM 10 Measurements
The estimate of alkane mixture (AM) mass emission flux from facility sources was produced
using EPA method OTM 10 with open-path Fourier transform infrared (OP-FTIR)
spectroscopy deployed in a four corner configuration. The measurement approach includes
two steps: (1) acquisition and analysis of path-integrated concentration (PIC) data of air
pollutants along multiple plane-configured optical paths using OP-FTIR, and (2) the
analytical approach which calculates the mass emission flux estimate for the upwind source.
The approach utilizes the vertical radial plume mapping (VRPM) plane-integrating computer
algorithm with the acquired multi-path PIC data and wind vector information as primary
inputs.
The acquisition of PIC data was accomplished using a three-beam OTM 10 setup for each
flux plane. Utilizing both the ARCADIS (A) and EPA (E) OP-FTIR instruments, a four corner
configuration was set up around the pond sources (Figure 2-4). In this configuration, 4 flux
planes provide continuous measurement coverage under changing wind directions. The flux
planes are labeled with a letter (A or E) representing the OP-FTIR system along with the
beam paths (123 or 456) to form unique identifiers. Alternating scans were made between
the two VRPM planes of each OP-FTIR. The red lines in Figures 2-1 and 2-3 show the actual
placement of this configuration at the William Rulison and EnCana Benzel facilities,
respectively. At both facilities, the position of the VRPM planes were chosen to maximize the
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Measurement of Emissions
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October 2009 (Rev. 0.6)
capture of emissions from the ponds taking into account the suspected source locations and
site constraints.
A123
E123
Figure 2-4. Four Corner Configuration
Tables 2-1 and 2-2 present details of the placement of the optical components for the four
corner configurations at the Williams and EnCana Benzel facilities.
The acquired OP-FTIR data must be analyzed to produce a PIC value. For this project, OP-
FTIR data reduction focused on the PIC values of the AM by spectroscopic analysis of the
infrared absorption features in the C-H stretch spectral region around 2900 cm"1. The AM is
composed of a variety of hydrocarbons but the infrared signature for fuel base mixtures is
usually dominated by C-4 to C-8 alkanes (butane, pentane, hexane, heptane, octane). The
AM analysis was executed for a combined group of compounds since performing spectral
analysis of each individual species was not possible due to the similarity in the shapes of
their absorption bands. The spectral analysis of the AM is further described in Appendix A.
The AM was chosen for analysis since it was robustly quantifiable whereas other species of
interest were frequently below detection limits of the OP-FTIRs so could not be used for
standard OTM 10 flux measurements. Estimates of emission flux for select VOCs, which
were quantifiable by OP-FTIR using extended time averaging were also produced and is
described in Section 2.3.
10
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 2-1. Optical Configuration Details for the Williams Facility Setup
Mirror
Number
A1
A2
A3
A4
A5
A6
E1
E2
E3
E4
E5
E6
OP-FTIR to
Retroreflector
Distance (m)
142.3
142.0
142.8
185.3
187.6
187.2
148.3
150.2
149.7
219.1
220.3
220.6
Approximate
Retroreflector
Height (m)
1
4.8
8.6
1
2.9
8.1
1
4.4
8.2
1
3.5
8.7
Optical Path
Angle from
North (deg)
148.5
148.8
148.5
32.4
32.3
33.3
232.2
232.5
232.3
328.2
328.4
328.5
Table 2-2. Optical Configuration Details for the EnCana Facility Setup
Mirror
Number
A1
A2
A3
A4
A5
A6
E1
E2
E3
E4
E5
E6
OP-FTIR to
Retroreflector
Distance (m)
128.4
129.3
129.9
109.7
109.7
110.1
104.1
104.1
104.4
74.0
80.2
81.2
Approximate
Retroreflector
Height (m)
1
3.7
9.3
1
5.2
9.5
1
3.9
9.4
1
4.2
8.2
Optical Path
Angle from
North (deg)
334.2
333.9
334.1
54.4
54.4
54.9
268.2
268.2
268.8
154.2
154.6
154.9
11
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Measurement of Emissions
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October 2009 (Rev. 0.6)
The OTM 10 analytical procedure was used to produce the AM flux estimate by inputting the
multi-beam AM PIC values along with wind information and configuration data into the
VRPM algorithm. The VRPM method is generally discussed in EPA OTM 10 "Optical remote
sensing for emission characterization from non-point sources" which describes direct
measurement of pollutant mass emission flux from area sources using ground-based optical
remote sensing (ORS). The VRPM computer algorithm uses a smooth basis function
minimization routine of a bivarate Gaussian function to generate mass emission flux
information from species concentration and wind data. For this measurement campaign, the
VRPM configuration utilized a three-beam configuration which leads to a reduced form of the
bivarate Gaussian in polar coordinates (r, 6). The standard deviation in the crosswind
direction was set at one half the length of vertical plane (r,) for this project.
~Xri)2 (r-sm8-m }2
—ii_JZ__|_A z>
2 ' ~
(2-1)
Where:
A = normalizing coefficient, adjusts for the peak value of the bivariate surface;
mz = peak location in Cartesian coordinates;
az = vertical standard deviation in Cartesian coordinates;
ri = length of VRPM plane;
A, mz, and crzare the unknown parameters to be retrieved by the fitting procedure. An error
function (SSE) for minimization is defined as:
PAC, - \ G(r, ft, 4 cr ) Jr / r (2-2)
Where PAC, is the measured path-averaged concentration (PAC) value for the ;* beam. The
SSE function is minimized using the Simplex method to solve for the three unknown
parameters. This process is for determining the vertical gradient in concentration. It allows an
accurate integration of concentrations across the vertical plane as the long-beam ground
level PAC provides a direct integration of concentration at the lowest level.
12
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Once the parameters of the function are found for a specific run, the VRPM procedure
calculates the concentration values for every square elementary unit in a vertical plane.
Then, the VRPM procedure integrates the values, incorporating wind speed data at each
height level to compute the flux. This enables the direct calculation of the flux in grams per
second (g/s), using wind speed data in meters per second (m/s). Further information on the
VRPM method for area source emission measurements in general can be found in
Hashmonay and Yost 1999, Thoma et al. 2005, U.S. EPA 2006, U.S. EPA 2007 with specific
details of this deployment in U.S. EPA 2008. An analysis of OTM 10 measurement
uncertainty for this project is contained in Section 5.3.
Table 2-3 describes the instrument operation time periods for the OTM 10 measurements for
this study. The instrument operational times represent those periods when instrumentation
was operating within acceptable limits. Note that valid flux data time periods represent a
subset of instrument operation time periods when data acceptance criteria were met. Valid
flux data time periods are detailed in Appendix A. As it requires 1 to 2 hours to get the
equipment set up and operational each day, the start time for operation was usually in the
mid morning. The end time was dictated primarily by site access limitation (no night work) or
by weather events (8/9). Additional information on equipment operational requirements and
data quality indicators is contained in Section 5 and Appendix A.
Table 2-3. Instrument Operation Time Periods for the EPA OTM 10 Method
Williams Rulison
EnCana Benzel
Date
8/6/2008
8/7/2008
8/8/2008
8/9/2008
8/12/2008
8/13/2008
8/14/2008
8/15/2008
Start Time
14:20
10:20
10:20
11:40
12:00
10:20
9:20
9:40
End Time
16:40
17:40
16:40
15:00
18:20
17:40
16:20
14:20
2.3 OP-FTIR VOC Analysis and Calculation of Estimated VOC Flux
As discussed in previous sections, the AM was chosen for flux analysis since it was present
at high enough concentrations to be quantified at standard OTM 10 time resolution (30
second integration time) whereas other species of interest were frequently below the OP-
13
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
FTIR detection limits on one or more optical paths so could not be used for OTM 10 flux
measurements. Using a time-averaging approach, many of these compounds could be
quantified and estimates of emission flux for select VOCs were produced using a mass
concentration ratio calculation based on the AM flux data for similar time periods.
Analysis of the OP-FTIR data was performed to determine concentrations of benzene,
toluene, m-xylene, o-xylene, p-xylene, methanol, and methane. The select VOC analysis
was done for time periods when relatively high alkane mixture (AM) emissions were
detected. Table 2-4 presents a summary of the time periods when the analysis was
performed. The table also indicates the measurement path from which the data was
collected. Here the term VOC represents one or more of the target compounds listed above
and is not inclusive of all VOCs. Note that methane did not require the time averaging
method.
Table 2-4. Periods of OP-FTIR VOC Analysis
Measurement Path
EPA-806J353-M4
EPA-807J356-M4
ARC-807J102-M4
EPA-807J022-M4
EPA-808J153-M4
ARC-808J004-M4
EPA-808J153-M4
ARC-808J004-M1
ARC-812J513-M4
ARC-812J513-M1
ARC-813_0922-M4
ARC-813_0922-M4
ARC-813_0922-M4
EPA-813J021-M1
ARC-813J536-M4
ARC-814-0908-M4
ARC-814-0908-M4
ARC-814-0908-M4
ARC-81 5-091 8-M4
Site
Williams
Williams
Wlliams
Williams
Wlliams
Wlliams
Wlliams
Wlliams
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
Compound
Analyzed
Methane
VOC
VOC/methane
Methane
VOC/methane
VOC
VOC/methane
VOC
VOC/methane
VOC/methane
VOC/methane
Methane
VOC
VOC
VOC/methane
VOC/methane
Methane
VOC/methane
Methane
Start Time
(MDT)
8/6/2008 16:00
8/7/2008 14:01
8/7/2008 14:02
8/7/2008 16:01
8/8/200813:27
8/8/2008 16:00
8/8/2008 16:01
8/8/2008 16:02
8/12/200817:02
8/12/200817:04
8/13/200811:08
8/13/200813:20
8/13/200815:00
8/13/200815:25
8/13/200815:52
8/14/200810:22
8/14/200815:00
8/14/200815:59
8/15/200813:00
End Time
(MDT)
8/6/2008 16:40
8/7/200815:59
8/7/2008 14:58
8/7/200817:40
8/8/2008 14:24
8/8/2008 16:46
8/8/2008 16:50
8/8/2008 16:49
8/12/200818:16
8/12/200818:27
8/13/200812:05
8/13/200814:30
8/13/200815:26
8/13/200816:13
8/13/200816:51
8/14/200811:19
8/14/200816:10
8/14/2008 16:56
8/15/200814:00
14
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
The VOC analysis was done using the time-averaging method (TAM), which is a post-
measurement analysis technique for determining multi-hour concentration averages and
detection limits. This method may facilitate comparison with time-integrated point-sample
collection techniques (such as one-hour canister samples). The method can produce
significantly lower instrument detection limits and can be applied to any ORS measurement
technology that produces a set of response-signal (single-beam) spectra. As discussed,
analysis of the OP-FTIR data for select VOC using a standard averaging period (30
seconds) resulted in minimum detection limits too high to robustly quantify the target VOC
compounds.
The TAM consists of two steps. The first step is performed once for all target compounds
that are analyzed in a single measurement set. This procedure involves determining, for
each target compound, the individual measurements in the measurement set in which the
spectra indicate background or zero levels of the target species. These measurements are
averaged to produce a specific time-averaged background spectrum for each compound.
The second step involves performing a Classical Least Squares analysis on the single-beam
spectrum that is the average of the entire measurement set covering the time-averaging
period, and the background single beam spectrum selected in the first step of the procedure
for the target compound. The analysis is repeated for each target compound using the
respective co-added background determined in step one. The resulting concentration
determination is the time-averaged result, and the detection limit is determined from the
standard error of the regression fit.
Table 2-5 provides a comparison of estimated minimum detection limits (MDL) of OP-FTIR
for select VOC compounds measured in this study. The first column presents typical MDL
using a 1-minute averaging time, while the second column shows typical MDL using the
TAM with 30-minute time resolution.
Table 2-5. Detection Limits for Optimal OP-FTIR Setup with Clean, Fully Populated
Retroreflector Arrays
Species
Benzene
Toluene
m-Xylene
o-Xylene
p-Xylene
Methanol
MDLs, 200 meters
1 minute (ppb)
60
80
44
40
64
12
MDLs, 200 meters
30 minute Avg. (ppb)
12
16
12
12
16
3
15
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
The results of the VOC concentration analysis, which can be found in Section 3.4 of this
document, were used with the measured average alkane mixture emissions fluxes from the
Williams and EnCana sites to calculate an estimated emissions flux for each VOC. More
information on this calculation, as well as the estimated VOC flux values, can be found in
Section 3.4.
Additional concentration analysis of the OP-FTIR data for benzene, toluene, m-xylene, o-
xylene, and p-xylene was performed for six time periods that SUMMA canisters were
deployed near the OP-FTIR measurement path. This analysis was done to compare the
concentration determinations from the two measurement methods. Table 2-6 presents a
summary of the six SUMMA canister deployment periods used for this comparison. The
results of this comparison are presented in Section 3.4 of this document. Section 3.5
contains a detailed comparison of the OP-FTIR AM and SUMMA canister AM data along
with sampling location information and wind summaries.
Table 2-6. Periods of SUMMA Canister/ OP-FTIR VOC Analysis
SUMMA ID
TNAPC11
926,648
ER047
TNAPC20
ER069, ER064
988,3248
Site
Williams
Williams
Williams
EnCana
EnCana
EnCana
Date
8/7/2008
8/8/2008
8/9/2008
8/13/2008
8/14/2008
8/14/2008
Start Time
(MDT)
16:13
13:25
14:00
15:52
10:32
16:09
End Time
(MDT)
17:13
14:25
15:00
16:52
11:32
17:09
2.4 Description of SUMMA Canister Measurements
In addition to EPA OTM 10 flux and related open-path measurements, evacuated SUMMA
canister samples were collected at both sites to provide supporting information on the AM
and select VOC concentration levels in areas near the observing OTM 10 planes. Time-
integrated (1 hour) SUMMA canister samples with EPA TO-15 and SNMOC analysis were
utilized since this approach yields lower method detection limits (MDL) for most compounds
compared to the in situ path-integrated measurements acquired with OP-FTIR using
standard 30 second time integration, thus providing useful information on concentrations of
trace VOCs. A manual sample collection system was used with canister placement at an
approximate 1 m height in many cases near the location of the lowest beam paths of the
respective VRPM planes (paths 1 or 4 shown in Figure 2-4). Three samples were collected
16
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
at a time: two canisters were co-located near the midpoint of the downwind VRPM plane,
and one canister was deployed near the midpoint of the upwind VRPM plane. On some
days, two sets of samples were collected, one in the morning and one in the afternoon. A
total of 28 canister samples were collected between the two sites.
The exact locations along the optical path were decided at the time of deployment by field
personnel, and an attempt was made to initiate sampling when the meteorological conditions
were most conducive to representative plume capture (i.e., when the wind was blowing
across the open path beam at or near 90°). The vertical placement of the sample inlet and
inlet funnel was one meter above ground level, approximately equal to the height of the
ground level OP-FTIR optical beams. In some cases the position of the canisters were
separated by from the location of OP-FTIR planes. The exact placement of the canisters
along with wind information for the sampling time period is contained in Section 3.5.
Air was drawn into the evacuated canister using a calibrated critical orifice that is between
the inlet and canister. The critical orifices were chosen to allow only a specified amount of air
to enter the can over a given time. To avoid losses of VOCs to condensed water in the
canisters, the pressure of the air sample in the canister did not exceed atmospheric
pressure. The samples were analyzed by TO-15 and SNMOC with data presented in
Appendix B. Table 2-7 shows the date, sampling time, and identification (ID) for the canister
measurements.
2.5 Description of Water Sampling
Water sampling was conducted at the Williams Rullison site during August 7 and 8, 2008.
These samples were collected at four different sites around the water treatment facility: Skim
Pond Inlet (SP IN), Skim Pond outlet to the North Pond (SP OUT), North Pond outlet o the
South Pond (N OUT) and South Pond outlet to the North Pond (S OUT). Figure 2-5 shows
the location of each sampling point. For each sample, a Williams employee took a large grab
sample directly from each header pipe exit. From each grab sample, two VOA (Volatile
Organics Analysis) sample containers were filled with a minimum amount of head space.
The sample containers were 40 ml amber glass with a teflon/silcon septa. The samples were
then immediately put on ice. The samples were shipped over-night to the EPA R8 lab in
Denver for analysis of volatile organics by EPA SW-846 Method 8260 "Volatile Organic
Compounds by Gas Chromatography/Mass Spectrometry (capillary column technique). The
dates and times of the sampling along with a results summary are contained in Section 3.6.
17
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 2-7. SUMMA Canisters Deployed at the Williams Rulison and EnCana Benzel Facilities
Site
Williams Rulison
EnCana Benzel
Date
Deployed
8/7/2008
8/7/2008
8/8/2008
8/8/2008
8/9/2008
8/9/2008
8/12/2008
8/12/2008
8/13/2008
8/13/2008
8/13/2008
8/13/2008
8/14/2008
8/14/2008
8/14/2008
8/14/2008
8/15/2008
8/15/2008
Start Time
16:13
16:13
13:25
13:25
-14:00
-14:00
-11:00
-11:00
11:07
11:07
15:52
15:52
10:33
10:33
16:09
16:09
11:09
11:09
End Time
17:13
17:13
14:25
14:25
15:00
15:00
-12:00
-12:00
12:07
12:07
16:52
16:52
11:33
11:33
17:09
17:09
12:09
12:09
Summa ID
TNAPC-171
2431, 9731
TNAPC-1 1
3639A
926, 648
ER001.ER038
ER047
ER029
659, 167604
3255
ER043, 444
TNAPC20
167601,3254
ER061
ER069, ER064
15280
988, 3248
ER021
ER085, ER114
Invalid due to zero final pressure in the canister
18
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 2-5. Location of Water Sampling Points at the Williams Facility
Water sampling was conducted at the Williams Rullison site during August 12 through
August 14, 2008. These samples were collected at four different sites around the
evaporation pond: grass mesa inlet to the pond (Grass), west side of pond (W), south side of
pond (S), and east side of pond (E). Figure 2-6 shows the location of each sampling point.
For W, S, and E locations, a peristaltic pump was used to pull sample from approximately 2
to 6 inches below the surface of the water. Two VOAs sample containers were filled directly
from the peristaltic tubing exit for each point. For the Grass sample point, an EnCana
employee took a large grab sample directly from each header pipe exit. From the grab
sample, two VOA sample containers were filled with a minimum amount of head space. The
samples were then immediately put on ice. The samples were shipped over-night to the EPA
R8 lab in Denver for analysis of volatile organics by EPA SW-846 Method 8260 "Volatile
Organic Compounds by Gas Chromatography/Mass Spectrometry (capillary column
technique). The dates and times of the sampling along with a results summary are contained
in Section 3.6.
19
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 2-6. Location of Water Sampling Points at the EnCana Facility
20
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
3. Results and Discussion
3.1 Results Summary Approach
For this study, the OTM 10 VRPM calculation produces a moving average AM flux value for
each of the four vertical planes (Figure 2-4). Each flux value represents an average from a
time interval of approximately 4 minutes. These primary flux values are summarized in
Appendix A along with data quality indicators. To calculate the net flux for the source within
the four vertical plane configurations, the measured fluxes for the two downwind vertical
planes are added together and the fluxes of the two upwind vertical planes are subtracted as
backgrounds. Since the individual flux planes for each OP-FTIR are measured sequentially
and the upwind and downwind plane pairs are not time synchronized, it is necessary to
average several successive primary flux values to ensure that the net flux calculation will be
composed of temporally comparable results. This is accomplished by creating a 20-minute
average time period for each flux plane which is used in the net flux calculation and
summary tables contained in this section. For each average reported in the tables, the
following information is provided: time the measurement was made (hounminute), wind
speed (m/s), wind direction with respect to north (degrees), and the AM flux value for each of
the four VRPM planes (A123, A456, E123, or E456) in g/s. Additional low and high range net
flux calculations and uncertainty estimates contained in the tables are described below. Note
that missing values in the tables and graphs are a result of data which did not pass
acceptance criteria, see Appendix A for details.
Minimum Net Flux
As a way to express a low-range net flux estimate, a minimum net flux calculation is given.
This value is the result of adding all four of the VRPM flux values (2 upwind and 2
downwind). The upwind planes represent background conditions (ideally zero flux) and are
therefore given a negative value in these calculations. The Sum of All 4 Planes result is
entered here and represents the minimum net flux of the target area within the 4-corner
configuration. In the time series graphs, the vertical bars represent the range of possible
mass emission fluxes with the minimum net flux represented by the lower end of the vertical
bar.
Since the upwind planes are assigned a negative value, the Sum of All 4 Planes may in
some cases be negative if there is a strong interfering upwind source (external source). This
is caused by incomplete capture of the upwind plume by the downwind planes due to plume
trajectory and dilution as it moves across the cross the configuration. When this situation
occurs, these are not good conditions for estimating the flux from the target source contained
within the four corners configuration. When this situation occurs, the Minimum Net Flux for
21
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
target source is defined to be zero since a negative value (a sink) is not physically
meaningful.
Maximum Net Flux
As a way to express a high-range net flux estimate, a maximum net flux calculation is given.
This value is the sum of the two downwind VRPM flux values, and therefore represents the
maximum net flux possible (assuming that none of the upwind mass is captured by the
downwind vertical planes). In the time series graphs, the maximum net flux values are
represented by the upper end of the vertical bars.
Estimated Net Flux
This is the mean of the Maximum Net Flux and the Minimum Net Flux. When the difference
between the maximum and minimum net flux is large there is a large uncertainty associated
with the estimated net flux.
Combined Uncertainty
A combined uncertainty estimate was produced for each 20-minute flux measurement. This
uncertainty estimate was produced by propagating individual estimates of uncertainty for
each measurement plane to a combination of all four planes using an assumption of ± 20%
uncertainty for each individual plane measurement. This assumption is based on tracer
release OTM 10 performance data and is further described in Section 5.3. When a sum or
difference of two or more independent random variables is calculated, the propagated
combined absolute uncertainty is the square root of the sum of the squares of the individual
absolute uncertainties.
External Flux
This represents the absolute values of the sum of the upwind plane fluxes. In cases when
the minimum net flux is positive, the range of the vertical bars represents the external flux.
Since the top of the vertical bar represents the flux of everything captured by the downwind
VRPM configuration, and the bottom of the vertical bar represents this same flux less the
background (external contributors), then the vertical bar itself represents the range of flux
from external sources.
22
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
3.2 AM Flux Summary for the Williams Rulison Facility
The following tables and figures are time series graphs of the calculated mass emission
fluxes for the AM during each day of sampling and at various contributing sources
(evaporation versus skim pond). Tables 3-1 through 3-4 are summary tables of mass
emission flux results (20-minute period averages) for the configurations used during each
day of sampling at the Williams Rulison facility. These values were calculated as described
in Sections 2.2 and 3.1. Figures 3-1 through 3-4 are time series graphs of calculated mass
emission fluxes for the AM during each day of sampling. For each reported average in the
tables, the following information is provided: time the measurement was made, wind speed,
wind direction, and the flux value for each of the fourVRPM planes (A123, A456, E123, or
E456). Also shown are the calculated values for: minimum net flux, maximum net flux,
estimated net flux, combined uncertainty and external flux.
Table 3-1 and Figure 3-1 show the first day of sampling at the Williams Rulison facility
(August 6) when winds were generally steady from the SSW. All of the estimated net flux
values had very small vertical bars (relatively low external flux, typically smaller than the
combined uncertainty) associated with them and the combined uncertainty is slightly higher
than the individual 20% assigned uncertainty. Therefore, this time period is valid for
calculating the net flux from the main evaporation pond (North Pond). They ranged from
about 0 g/s to 0.2 g/s, for an average of about 0.07 g/s over the 1.5 hours of valid data
collection on all fourVRPM planes.
Table 3-2 and Figure 3-2 show the second day of sampling (August 7). At 14:30, there is a
large vertical bar when the wind shifted to a more easterly direction thus impacting the E456
VRPM plane to the west of the skim pond. These external emissions appear to be coming
from the skim pond, and had an average flux of 1.1 g/s. The time period prior to 14:30 was
an ideal (low combined uncertainty and external flux) time for monitoring net emissions from
the North Pond, which had an average flux of 0.56 g/s.
Table 3-3 and Figure 3-3 show the third day of sampling at William Rulison (August 8).
Before 11:00 am, the winds were from the SE and the flux from the skim pond was 0.24 g/s.
The winds then shifted to the SW, presenting good conditions for monitoring the North Pond.
The average net flux from the North Pond throughout the day was 0.10 g/s. At the end of the
day, the wind shifted to the SE again for the final 20-minute averaging period, resulting in a
flux of 1.8 g/s for the skim pond. Averaging the morning and afternoon fluxes for the skim
pond resulted in a daily average flux of 1.1 g/s
Table 3-4 and Figure 3-4 show results from the final day of sampling at William Rulison
(August 9). The prevailing winds had an easterly component during the beginning of the
measurement period (up until 13:30). The winds were then from the south for the remainder
of the period. The average flux for the skim pond, determined up to 13:30, was 0.56 g/s. The
rest of the day showed very little influence from the skim pond and provided good conditions
for monitoring the North Pond. The average flux value for the evaporation pond was 0.13 g/s.
23
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-1. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the Williams Rulison Facility on August 6,2008
Time
15:10
15:30
15:50
16:10
16:30
Wind
speed
1.7
1.9
2.4
2.0
2.0
Wind
Direction
174.8
179.3
179.1
202.6
231.1
A123
-0.010
-0.020
-0.017
0.000
0.000
A456
0.030
0.028
0.005
0.000
0.000
E123
-0.015
0.000
0.000
-0.005
0.000
E456
0.022
0.178
0.000
0.052
0.083
Minimum
Net Flux
0.027
0.186
0.000
0.047
0.083
Maximum
Net Flux
0.052
0.206
0.005
0.052
0.083
Estimated
Net Flux
0.040
0.196
0.003
0.050
0.083
Combined
Uncertainty
0.0195
0.0598
0.0061
0.0131
0.0166
External
Flux
0.025
0.020
0.017
0.005
0.000
u_
c
'w
UJ
(0
f~_
— — *-
•
f
15:10 15:30 15:50 16:10 16:30
Time
- 300.0
- 240.0
- 120.0
- 60.0
Figure 3-1. Time Series of Mass Emission Flux for August 6, 2008 at the Williams Rulison Facility
24
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-2. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration
at the Williams Rulison Facility on August 7,2008
used
Time
11:30
12:10
12:30
12:50
13:10
14:10
14:30
15:10
15:30
15:50
16:30
16:50
17:10
17:30
Wind
speed
1.1
1.0
1.3
1.1
1.1
1.4
2.4
1.3
1.3
1.7
2.6
2.8
1.7
1.3
Wind
Direction
113.2
95.6
191.3
196.5
187.9
157.1
115.9
34.0
21.0
60.5
66.0
74.3
60.4
87.6
A123
0.000
0.010
0.000
0.000
0.000
0.003
0.080
0.235
0.242
0.188
0.568
0.306
0.210
0.140
A456
0.155
0.000
0.015
0.035
0.080
1.035
2.637
-0.015
-0.005
0.295
0.375
0.470
0.017
0.650
E123
-0.003
-0.010
-0.005
0.000
0.000
0.000
-0.010
0.350
0.226
0.038
0.010
-0.013
0.010
-0.030
E456
-0.123
-0.440
0.227
0.503
1.480
-0.200
-1.536
-1.088
-0.895
-1.104
-0.265
-0.350
-1.898
-1.410
Minimum
Net Flux
0.029
0.000
0.237
0.538
1.560
0.838
1.171
0.000
0.000
0.000
0.688
0.413
0.000
0.000
Maximum
Net Flux
0.155
0.010
0.242
0.538
1.560
1.038
2.717
0.585
0.468
0.521
0.953
0.776
0.237
0.790
Estimated
Net Flux
0.092
0.005
0.240
0.538
1.56
0.938
1.94
0.293
0.234
0.261
0.821
0.595
0.119
0.395
Combined
Uncertainty
0.0483
0.0880
0.0458
0.101
0.296
0.279
0.611
0.233
0.190
0.231
0.146
0.132
0.382
0.312
External
Flux
0.126
0.450
0.005
0.000
0.000
0.200
1.546
1.103
0.900
1.104
0.265
0.363
1.898
1.440
360
Time
Figure 3-2. Time Series of Mass Emission Flux for August 7, 2008 at the Williams Rulison Facility
25
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-3. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the Williams Rulison Facility on August 8,2008
Time
10:30
10:50
11:10
11:30
12:10
12:30
12:50
13:10
13:30
13:50
14:10
14:30
15:10
15:30
16:30
Wind
speed
1.2
1.1
1.4
1.7
3.5
4.3
4.2
4.5
4.6
3.8
3.0
2.7
1.9
2.8
3.5
Wind
Direction
154.1
103.2
170.0
204.9
256.8
251.5
250.2
245.7
246.0
245.9
244.7
226.8
211.1
228.6
136.5
A123
0.000
0.020
0.000
-0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.237
A456
0.048
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.757
E123
0.000
0.000
-0.010
-0.010
0.028
0.005
0.002
0.000
0.008
0.010
0.006
-0.007
-0.010
-0.010
0.000
E456
0.020
-0.238
0.020
0.047
0.040
0.078
0.025
0.136
0.053
0.108
0.178
0.090
0.092
0.280
-1.853
Minimum
Net Flux
0.068
0.000
0.010
0.034
0.068
0.083
0.027
0.136
0.061
0.118
0.184
0.083
0.082
0.270
0.141
Maximum
Net Flux
0.068
0.112
0.020
0.047
0.068
0.083
0.027
0.136
0.061
0.118
0.184
0.090
0.092
0.280
1.994
Estimated
Net Flux
0.068
0.056
0.015
0.041
0.068
0.083
0.027
0.136
0.061
0.118
0.184
0.087
0.087
0.275
1.068
Combined
Uncertainty
0.0104
0.0512
0.0045
0.0098
0.0099
0.0161
0.0051
0.0272
0.0108
0.0217
0.0356
0.0181
0.0185
0.0560
0.5129
External
Flux
0.000
0.238
0.010
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.010
0.010
1.853
2500
_2.000
3
! 1.500
•| 1.000
= 0.500
0.000
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-4. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the Williams Rulison Facility on August 9,2008
Time
11:50
12:10
12:30
12:50
13:10
13:50
14:10
14:30
14:50
Wind
speed
2.7
2.6
2.5
1.7
1.2
1.0
1.9
2.9
3.0
Wind
Direction
85.4
92.8
91.2
106.1
93.9
163.8
167.9
154.7
144.9
A123
0.220
0.088
0.045
0.015
0.010
0.000
0.000
0.000
0.000
A456
0.307
0.383
0.158
0.115
0.093
0.025
0.018
0.108
0.273
E123
-0.012
0.000
-0.030
-0.025
-0.013
-0.100
-0.038
0.000
0.000
E456
-0.325
-0.380
-0.797
-0.688
-0.525
0.040
0.094
0.044
-0.070
Minimum
Net Flux
0.190
0.091
0.000
0.000
0.000
0.000
0.074
0.152
0.203
Maximum
Net Flux
0.527
0.471
0.203
0.130
0.103
0.065
0.112
0.152
0.273
Estimated
Net Flux
0.359
0.281
0.102
0.065
0.052
0.033
0.093
0.152
0.238
Combined
Uncertainty
0.0997
0.1093
0.1631
0.1397
0.1070
0.0221
0.0208
0.0233
0.0564
External
Flux
0.337
0.380
0.827
0.713
0.538
0.100
0.038
0.000
0.070
Cfl
B)
"""' n j.nn -
X U-4U'J
_3
c
o n Tm
tit
0
Ml
n TIO -
tn
CD
s
n -mo
A AAA
<
I
^_ -*- — ^
T
1
/^ I
T
1
- 315.0
- 270.0
- 225.0
o>
u
•\ on 0 "-
lOU.'J a)
- 135.0
- 45.0
r\ A
• Flux Avg
11:50 12:10 12:30 12:50 13:10 13:30 13:50 14:10 14:30 14:50
Time
Figure 3-4. Time Series of Mass Emission Flux for August 9, 2008 at the Williams Rulison Facility
27
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
One observation made during this field campaign was that lower emissions were measured
for the skim pond in the morning, than in the afternoon. Also, there was a very good
correlation (Pearson correlation of 0.87) between the external flux (primarily skim pond) and
the combined uncertainty. This reaffirms that in time periods with large external flux
interfering with the estimation of the net flux from the north pond, the uncertainty is large.
The 4-day average flux from the evaporation pond (North Pond) was 0.20 g/s (SD of ± 0.33).
The flux value for the evaporation pond was found by averaging (27) 20-minute averaged
flux values over 4 days. See Section 5.3 for additional discussion on OTM 10 measurement
uncertainty. The average flux value from the evaporation pond is found using the "Estimated
Net Flux" values from Table 3-1 through 3-4 during the following time periods, which were
ideal for characterizing emissions from the evaporation pond based on prevailing wind
direction during the time of the measurements:
• August6: 15:10 to 16:30
• August 7: 11:30 to 14:10
• Augusts: 11:10to 15:30
• August 9: 13:50 to 14:50
The 3-day average flux from the skim pond (no external sources were detected by the
VRPM configuration on Day 1 of sampling) was 0.90 g/s (SD of ± 0.572). The value for the
skim pond was found by averaging (15) 20-minute averaged flux values over a 3 day period.
The average flux value from the Skim Pond is found using the "External Flux" value shown in
Tables 3-1 through 3-4 during periods described as being ideal for characterizing emissions
from the pond.
• August 6: No Measurements
• August 7: 14:30 to 17:30
• August 8: 10:30, 10:50, 16:30
• August 9: 11:50 to 13:10
28
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Note that no valid measurements were obtained from the South Evaporation pond.
Emissions from this pond are expected to be very low and this is supported by the Water
sampling measurements described in Section 3.6 and Appendix C which indicate non
detects for volatile organic concentrations in the ponds. For subsequent summary tables, the
North Pond is referred to as Evaporation Pond.
3.3 AM Flux Summary for the EnCana Benzel Facility
Tables 3-5 through 3-8 are summary tables of mass emission flux results (20-minute period
averages) for the configurations used during each day of sampling at the EnCana Benzel
facility. These values were calculated as described in Sections 2.2 and 3.1. Figures 3-5
through 3-8 are time series graphs of calculated mass emission fluxes for AMs (total
alkanes) during each day of sampling. For each reported average in the tables, the following
information is provided: time the measurement was made, wind speed, wind direction, and
the flux value for each of the four VRPM planes (A123, A456, E123, or E456). Also shown
are the calculated values for: minimum net flux, maximum net flux, estimated net flux,
combined uncertainty and external flux.
Table 3-5 and Figure 3-5 show the first day of sampling at the EnCana Benzel facility
(August 12). Winds were northerly and there were lower emissions in the early afternoon
than were seen later in the day. The conditions were good for measuring the emissions from
the evaporation pond, as the background (external) emissions were small. The average flux
from the evaporation pond was 0.12 g/s.
Table 3-6 and Figure 3-6 show the second day of sampling (August 13). Winds were from
the NW for the majority of the day, providing good conditions for monitoring the evaporation
pond. The average flux for the day from the pond was 0.06 g/s. The largest external
emissions (largest vertical bars) were seen between 14:30 and 15:50, when the winds were
coming from the N, indicating a possible source contribution from that direction.
29
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-5. Summary Table of the Mass Emission Flux Results(g/s) for the Configuration used
the EnCana Benzel Facility on August 12, 2008
at
Time
12:10
12:30
12:50
13:10
13:30
13:50
14:10
15:30
15:50
16:10
16:30
16:50
17:10
17:30
17:50
18:10
Wind
speed
2.3
2.4
2.6
1.8
2.1
4.3
3.8
1.9
2.0
1.7
3.4
2.2
1.7
2.5
3.0
1.6
Wind
Direction
13.6
5.4
345.4
290.3
302.2
318.5
297.1
335.8
318.4
11.8
352.9
2.1
336.9
248.5
233.9
301.0
A123
0.065
0.034
0.003
0.000
0.000
0.000
0.000
0.017
0.030
0.007
0.096
0.130
0.056
0.073
0.158
0.063
A456
0.015
0.060
0.074
0.033
0.000
0.000
0.000
0.070
0.065
0.042
0.085
0.130
0.255
0.210
0.068
0.085
E123
-0.020
-0.020
-0.025
-0.006
-0.020
-0.024
-0.015
-0.007
-0.015
-0.037
-0.038
0.000
0.000
0.000
0.000
0.000
E456
-0.010
-0.015
-0.008
0.013
0.002
0.010
0.024
-0.003
-0.007
0.007
-0.005
-0.010
-0.012
0.000
0.000
0.000
Minimum
Net Flux
0.050
0.059
0.044
0.040
0.000
0.000
0.009
0.077
0.073
0.019
0.138
0.250
0.299
0.283
0.226
0.148
Maximum
Net Flux
0.080
0.094
0.077
0.046
0.002
0.010
0.024
0.087
0.095
0.056
0.181
0.260
0.311
0.283
0.226
0.148
Estimated
Net Flux
0.065
0.077
0.061
0.043
0.001
0.005
0.017
0.082
0.084
0.038
0.160
0.255
0.305
0.283
0.226
0.148
Combined
Uncertainty
0.0141
0.0147
0.0158
0.0133
0.0040
0.0055
0.0057
0.0146
0.0147
0.0114
0.0286
0.0368
0.0523
0.0445
0.0344
0.0212
External
Flux
0.030
0.035
0.033
0.006
0.020
0.024
0.015
0.010
0.022
0.037
0.043
0.010
0.012
0.000
0.000
0.000
0350
0300
0250
0200
J60..Q
S o
0150
0050
0000
Tim«
Figure 3-5. Time Series of Mass Emission Flux for August 12, 2008 at the EnCana Benzel Facility
30
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-6. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the EnCana Benzel Facility on August 13, 2008
Time
10:30
10:50
11:10
11:30
11:50
12:30
12:50
13:10
13:30
13:50
14:10
14:30
14:50
15:10
15:50
16:10
16:30
17:30
Wind
speed
1.6
1.6
1.6
1.7
1.4
1.3
1.7
1.3
2.2
2.7
1.4
2.5
2.9
4.0
3.9
4.0
2.5
1.7
Wind
Direction
346.1
328.3
314.1
325.1
335.3
288.5
303.1
304.9
3.0
8.0
349.6
19.5
15.9
8.1
326.0
304.3
289.5
250.9
A123
0.006
0.005
0.000
0.000
0.000
0.020
0.015
-0.020
0.098
0.117
0.080
0.033
0.004
0.007
-0.010
0.001
-0.013
0.000
A456
0.004
0.038
0.043
0.040
0.055
0.020
0.036
0.056
0.053
0.024
0.020
0.066
0.053
0.035
0.014
0.117
0.048
0.000
E123
-0.017
-0.017
-0.018
-0.010
-0.017
-0.010
-0.007
-0.010
-0.014
-0.010
-0.018
-0.028
-0.068
-0.025
-0.040
-0.006
0.000
0.000
E456
-0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-0.004
0.000
0.000
-0.008
-0.005
-0.008
0.012
0.018
0.010
0.010
Minimum
Net Flux
0.000
0.026
0.025
0.030
0.038
0.030
0.044
0.026
0.133
0.131
0.082
0.063
0.000
0.009
0.000
0.130
0.045
0.010
Maximum
Net Flux
0.010
0.043
0.043
0.040
0.055
0.040
0.051
0.056
0.151
0.141
0.100
0.099
0.057
0.042
0.026
0.136
0.058
0.010
Estimated
Net Flux
0.005
0.035
0.034
0.035
0.047
0.035
0.048
0.041
0.142
0.136
0.091
0.081
0.029
0.026
0.013
0.133
0.052
0.010
Combined
Uncertainty
0.0081
0.0079
0.0063
0.0055
0.0115
0.0060
0.0081
0.0121
0.0225
0.0241
0.0169
0.0159
0.0173
0.0100
0.0108
0.0239
0.0101
0.0020
External
Flux
0.022
0.017
0.018
0.010
0.017
0.010
0.007
0.030
0.018
0.010
0.018
0.036
0.073
0.033
0.050
0.006
0.013
0.000
Tin*
Figure 3-6. Time Series of Mass Emission Flux for August 13, 2008 at the EnCana Benzel Facility
31
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-7. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the EnCana Benzel Facility on August 14, 2008
Time
9:30
9:50
10:10
10:30
10:50
11:10
11:30
11:50
12:10
12:30
13:10
13:50
14:10
14:50
15:10
15:30
15:50
16:10
Wind
speed
1.1
1.5
1.8
1.5
1.2
1.3
1.7
1.8
1.5
2.2
1.5
1.8
2.5
3.2
2.6
2.5
1.9
3.9
Wind
Direction
15.3
56.4
36.3
349.1
329.6
328.8
325.4
332.9
352.9
1.7
181.0
99.0
43.6
234.2
274.0
309.1
318.4
305.9
A123
0.010
0.032
0.013
0.014
0.005
0.012
0.014
0.010
0.018
0.065
0.083
0.028
0.030
0.003
-0.008
-0.006
0.000
0.000
A456
0.020
0.020
0.040
0.063
0.066
0.058
0.075
0.028
-0.010
0.000
-0.023
0.025
-0.006
0.030
0.050
0.076
0.085
0.057
E123
0.000
0.000
0.000
-0.002
0.000
0.000
-0.005
-0.004
-0.005
-0.018
0.003
-0.010
-0.020
0.000
0.000
0.000
0.000
0.000
E456
-0.003
0.000
-0.008
-0.007
0.000
-0.003
0.000
0.000
-0.002
-0.005
-0.003
-0.016
-0.025
0.007
0.006
0.000
0.000
0.003
Minimum
Net Flux
0.027
0.052
0.045
0.068
0.071
0.067
0.084
0.034
0.001
0.042
0.060
0.027
0.000
0.040
0.048
0.070
0.085
0.060
Maximum
Net Flux
0.030
0.052
0.053
0.077
0.071
0.070
0.089
0.038
0.018
0.065
0.086
0.053
0.030
0.040
0.056
0.076
0.085
0.060
Estimated
Net Flux
0.029
0.052
0.049
0.073
0.071
0.069
0.087
0.036
0.010
0.054
0.073
0.040
0.015
0.040
0.052
0.073
0.085
0.060
Combined
Uncertainty
0.0054
0.0075
0.0096
0.0131
0.0132
0.0119
0.0155
0.0061
0.0043
0.0136
0.0172
0.0084
0.0089
0.0062
0.0102
0.0152
0.0170
0.0114
External
Flux
0.003
0.000
0.008
0.009
0.000
0.003
0.005
0.004
0.017
0.023
0.026
0.026
0.051
0.000
0.008
0.006
0.000
0.000
360
Time
Figure 3-7. Time Series of Mass Emission Flux for August 14, 2008 at the EnCana Benzel Facility
32
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-8. Summary Table of the Mass Emission Flux Results (g/s) for the Configuration used
at the EnCana Benzel Facility on August 15, 2008
Time
9:50
10:10
10:30
10:50
11:10
11:30
11:50
12:10
12:30
12:50
13:10
13:30
13:50
Wind
speed
1.9
1.2
1.9
1.5
1.7
2.1
2.3
2.2
2.2
3.1
2.4
3.3
3.8
Wind
Direction
19.0
13.0
27.5
32.5
50.2
30.1
332.0
350.0
351.3
327.6
301.6
321.3
301.7
A123
0.057
0.053
0.055
0.056
0.052
0.073
0.018
0.007
0.004
0.000
0.000
0.000
0.000
A456
0.000
0.010
0.016
0.004
0.003
0.018
0.058
0.056
0.028
0.036
0.030
0.035
0.016
E123
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-0.002
-0.010
-0.015
0.000
0.000
0.000
E456
0.000
0.000
-0.004
0.000
0.000
0.000
0.000
0.000
0.004
-0.002
-0.002
0.000
0.000
Minimum
Net Flux
0.057
0.063
0.067
0.060
0.055
0.091
0.076
0.061
0.026
0.019
0.028
0.035
0.016
Maximum
Net Flux
0.057
0.063
0.071
0.060
0.055
0.091
0.076
0.063
0.036
0.036
0.030
0.035
0.016
Estimated
Net Flux
0.057
0.063
0.069
0.060
0.055
0.091
0.076
0.062
0.031
0.028
0.029
0.035
0.016
Combined
Uncertainty
0.0114
0.0108
0.0121
0.0112
0.0106
0.0150
0.0121
0.0115
0.0069
0.0082
0.0060
0.0070
0.0080
External
Flux
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.002
0.010
0.017
0.002
0.000
0.000
360
-• 300
-• 240
180 S
-• 120
9:50 10:10 10:30 10:50 11:10 11:30 11:50 12:10 12:30 12:50 13:10 13:30 13:50
Time
Figure 3-8. Time Series of Mass Emission Flux for August 15, 2008 at the EnCana Benzel Facility
33
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-7 and Figure 3-7 show the third day of sampling at EnCana Benzel (August 14).
Winds shifted to the east, then the south, where larger external interferences were seen.
Most of the day provided good data for the evaporation pond, because even when the
vertical bars were larger, they were small compared to the net flux. The average flux for the
day from the pond was 0.05 g/s.
Table 3-8 and Figure 3-8 show the final day of sampling at EnCana Benzel (August 15).
Although there was a wind shift from NE to NW, all winds had a northerly component and
were good for estimating flux from the evaporation pond. The average flux for the day from
the pond was 0.05 g/s
The 4-day average flux from the evaporation pond was 0.07 g/s (SD of ± 0.06). The flux
value for the evaporation pond was found by averaging (65) 20-minute averaged flux values
over the four days of measurements. The average flux value from the evaporation pond is
found by averaging the "Estimated Net Flux" values in the above tales. See Section 5.3 for
additional discussion on OTM 10 measurement uncertainty.
3.4 Results of OP-FTIR VOC Concentration Analysis and Estimated VOC Fluxes Using Ratio
Method
As discussed in Section 2.3, analysis of the OP-FTIR data was performed using the time-
averaging method (TAM) to determine the concentration of benzene, toluene, m-p-xylene, o-
xylene, methanol for time periods when relatively high alkane mixture (AM) emissions were
detected. This purpose of the analysis was to help estimate the select VOC emissions from
the source areas. Methane was also quantified without using the TAM. Table 3-9 presents
the average VOC concentration in ppb, for each analysis period. The table includes the
corresponding AM concentration for each period, and the determined molecular weight of the
AM, which is shown in parenthesis.
34
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-8. Summary of OP-FTIR VOC Concentration Determinations (concentrations in ppb)
Site
Williams
Williams
Williams
Williams
Williams
Williams
Williams
Williams
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
Start Time
8/6/2008 16:00
8/7/2008 14:01
8/7/2008 14:02
8/7/2008 16:01
8/8/200813:27
8/8/2008 16:00
8/8/2008 16:01
8/8/2008 16:02
8/12/200817:02
8/12/200817:04
8/13/200811:08
8/13/200813:20
8/13/200815:00
8/13/200815:25
8/13/200815:52
8/14/200810:22
8/14/200815:00
8/14/200815:59
8/15/200813:00
End Time
16:40
15:59
14:58
17:40
14:24
16:46
16:50
16:49
18:16
18:27
12:05
14:30
15:26
16:13
16:51
11:19
16:10
16:56
14:00
Benzene
NA
42
200
NA
22
ND
70
ND
ND
64
70
NA
47
82
68
ND
NA
70
NA
Toluene
NA
250
230
NA
44
160
170
38
61
60
101
NA
ND
ND
49
41
NA
ND
NA
m-Xylene
NA
220
ND
NA
ND
ND
130
ND
42
42
53
NA
ND
ND
43
ND
NA
ND
NA
o-Xylene
NA
ND
ND
NA
35
98
69
36
25
44
ND
NA
ND
31
44
24
NA
ND
NA
p-Xylene
NA
78
ND
NA
21
ND
49
ND
29
17
ND
NA
ND
ND
34
ND
NA
27
NA
Methanol
NA
6.1
19
NA
4.5
16
18
6.7
15
18
12
NA
13
ND
6.4
8.7
NA
22
NA
Methane
299
NA
630
829
10
NA
21
NA
19
24
52
67
NA
NA
26
110
105
2.0
175
Alkane Mixture
209(114)
2649(114)
1086(114)
1103(114)
85(113)
449(110)
1606(107)
210(114)
288(106)
490(111)
123(114)
140(111)
90(112)
123(113)
118(113)
101 (114)
134(114)
64(114)
53(112)
*NA denotes periods when VOC or methane concentrations were not analyzed
*ND denotes time periods that concentrations were not detected above minimum detection limits of OP-FTIR
35
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
The VOC concentrations presented above were then used with the corresponding AM
concentration data from the same time period to produce a mass concentration ratio (MCR)
for each VOC to AM, using the following formula:
MCR =
ConcVOC
FT1R
Conc,AM
FTIR
VOC
AM
(3-1)
Where:
MCR = mass concentration ratio between the VOC and the alkane mixture
for a particular time period
Cone, VOCFTIR = the average VOC concentration for the date and time period
selected, as measured by the OP-FTIR;
Conc,AMFTiR = the average AM concentration for the date and time period
selected, as measured by the OP-FTIR;
MWVoc = the molecular weight of the VOC/SNMOC;
MWAM = the molecular weight of the AMs, as determined from the
OP-FTIR measurements
The results of these calculations are shown in Table 3-10.
The MCR results for the individual time periods in Table 3-10 were used to produce an
average MCR for each compound for each of the two sites. Table 3-11 presents the average
MCR with ± one standard deviation shown. The average excludes ND readings and the
standard deviation should not be considered a robust indicator of uncertainty due to the low
number of entries. It is evident that a considerable amount of variation exists in the
calculated mass concentration ratios so there is a significant amount of uncertainty in the
average value. The EnCana facility seems to possess a somewhat higher mass
concentration ration compared to the Williams facility.
36
-------
Table 3-10. Summary of OP-FTIR VOC to AM Mass Concentration Ratio Calculations
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Site
Williams
Williams
Williams
Wlliams
Wlliams
Wlliams
Williams
Williams
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
EnCana
Start Time
8/6/2008 16:00
8/7/200814:01
8/7/200814:02
8/7/200816:01
8/8/200813:27
8/8/2008 16:00
8/8/2008 16:01
8/8/2008 16:02
8/12/200817:02
8/12/200817:04
8/13/200811:08
8/13/200813:20
8/13/200815:00
8/13/200815:25
8/13/200815:52
8/14/200810:22
8/14/200815:00
8/14/200815:59
8/15/200813:00
End Time
8/6/2008 16:40
8/7/200815:59
8/7/200814:58
8/7/200817:40
8/8/200814:24
8/8/200816:46
8/8/2008 16:50
8/8/2008 16:49
8/12/200818:16
8/12/200818:27
8/13/200812:05
8/13/200814:30
8/13/200815:26
8/13/200816:13
8/13/200816:51
8/14/200811:19
8/14/200816:10
8/14/2008 16:56
8/15/200814:00
Benzene
NA
0.011
0.126
NA
0.179
ND
0.032
ND
ND
0.092
0.390
NA
0.364
0.461
0.398
ND
NA
0.749
NA
Toluene
NA
0.076
0.171
NA
0.422
0.299
0.091
0.146
0.184
0.102
0.664
NA
ND
ND
0.339
0.328
NA
ND
NA
m-Xylene
NA
0.078
ND
NA
ND
ND
0.081
ND
0.147
0.083
0.405
NA
ND
ND
0.346
ND
NA
ND
NA
o-Xylene
NA
ND
ND
NA
0.390
0.213
0.043
0.161
0.088
0.087
ND
NA
ND
0.239
0.354
0.223
NA
ND
NA
p-Xylene
NA
0.028
ND
NA
0.234
ND
0.031
ND
0.102
0.034
ND
NA
ND
ND
0.273
ND
NA
0.397
NA
Methanol
NA
0.001
0.005
NA
0.015
0.010
0.003
0.009
0.016
0.011
0.027
NA
0.0413
ND
0.015
0.024
NA
0.097
NA
Methane
0.201
NA
0.082
0.107
0.017
NA
0.002
NA
0.010
0.007
0.060
.0692
NA
NA
0.031
0.153
0.110
0.004
0.473
*NA denotes periods when concentrations were not analyzed for a particular compound
*ND denotes time periods that concentrations were not detected above minimum detection limits of OP-FTIR
37
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-11. Summary of the Average Mass Concentration Ratios of VOC to Alkane Mixture, for the
Williams and EnCana sites
Site
Williams
EnCana
Benzene
0.087±0.079
0.409±0.211
Toluene
0.201 ±0.1 34
0.323±0.215
m-Xylene
0.080±0.002
0.245±0.154
o-Xylene
0.202±0.144
0.198±0.113
p-Xylene
0.098±0.118
0.201±0.165
Methanol
0.007±0.005
0.033±0.030
Methane
0.082±0.080
0.102±0.148
The average mass concentration ratio for each VOC from the Williams site was then multiplied by
the average AM flux value from the Williams Evaporation Pond (0.20 g/s) and Skim Pond (0.90 g/s)
to produce an estimated flux for each VOC for these sources. The average mass concentration
ratio for each VOC from the EnCana site was multiplied by the average AM flux value from the
EnCana Evaporation Pond (0.07 g/s) to produce an estimated VOC flux from this source. A
summary of the estimated VOC emissions flux values from each source area are presented below
in Table 3-12. It is noted that the values of Table E-2 include underlying uncertainty in AM flux
measurement average and additionally VOC to AM concentration ratio uncertainty so the values
should be considered estimates.
Table 3-12. Estimated Emission Flux Values (g/s) of select VOCs from the Williams and EnCana Sites
Site
Williams
Williams
EnCana
Source Area
Evaporation
Pond
Skim Pond
Evaporation
Pond
Benzene
(g/s)
0.018
0.078
0.029
Toluene
(g/s)
0.040
0.181
0.023
m-Xylene
(g/s)
0.016
0.072
0.017
o-Xylene
(g/s)
0.040
0.182
0.014
p-Xylene
(g/s)
0.020
0.088
0.014
Methanol
(g/s)
0.001
0.006
0.002
Methane
(g/s)
0.017
0.074
0.007
Table 3-12 shows that the largest emission flux values for these compounds were from the Williams
Skim Pond, with lower emissions found from the evaporation ponds at both sites. As discussed in
the next section, the presence of these VOCs are also recorded in the SUMMA canister sampling
with values near the Williams skin pond showing elevated results.
The results of Table 3-12 reflect an analysis that was conducted during times conducive to AM flux
estimation. During other time periods, the concentrations of the select VOCs could be much lower,
and in many cases below the detection limit of the OP-FTIR TAM method. An attempt was made to
compare the concentrations determined by the OP-FTIR TAM with SUMMA canister values for the
exact time periods that the canisters were acquired. Table 3-13 presents six canister results from
the Williams and EnCana facilities with OP-FTIR TAM analyses conducted during the canister
sampling periods. The SUMMA canister results are labeled (S) with the TO-15 analysis listed first
38
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
and the SNMOC result in parenthesis. The OP-FTIR TAM result is labeled (F). The derivation of the
SUMMA canister AM results is discussed in Section 3.5 and Appendix A.
Table 3-13. Comparison of Canister and OP-FTIR Results
Benzene (S)
Benzene (F)
Toluene (S)
Toluene (F)
m-,o-,p-Xylene (S)
m-,o-,p-Xylene (F)
AM(S)
AM(F)
Canister
TNAPC11
(Williams)
203 (1 75)
17
1210(993)
42
271 11 (1916)1
91
6654
536
Canisters
926,648
(Williams)
88.8 (57.8)
23
221 (200)
63
177(105)
53
546
82
Canister ER047
(Williams)
8.1 (4.7)
36
16.7(11.4)
62
15.7(11.6)
79
164
509
Canister
TNAPC20
(Encana)
1.3(1.0)
(ND)
4.1 (3.5)
(ND)
5.1 (5.0)
31 2
58.2
27
Canisters ER069,
ER064 (Encana)
2.3(1.5)
(ND)
3.2 (2.9)
42
1 .9 (2.0)
302
19.4
86
Canisters
988, 3248
(Encana)
2.5 (2.0)
66
4.6 (4.3)
ND
2.6 (2.8)
402
33.5
54
1 estimated value
2 m-,p-Xlene below minimum detection limit of OP-FTIR TAM
(ND) below the minimum detection limits of OP-FTIR TAM
In general, it is difficult to compare the concentrations determined by the OP-FTIR TAM and
SUMMA canister methods since the former integrates over an extended area, and the latter is a
point sampling approach. In some cases, the canister may be located very close to the source
(such as the Skim Pond at the Williams site), while the corresponding path-averaged concentration
measurement from the OP-FTIR measures this area but additionally integrate clean air from both
sites of the source. Conversely, at times when the concentrations measured with the OP-FTIR are
larger than canister values, the canister location may not have been located within the plume but
plume was captured by the spatially extended OP-FTIR measurement beam. In some cases, the
canisters were not located in close enough proximity to the OP-FTIR beam to allow robust
comparisons. In some cases similar concentrations are measured by the two methods but at slightly
offset time periods due to changes in wind direction. For example, elevated values similar to
TNAPC11 were measured by the OP-FTIR beam just before the canister was acquired (Table
3-10). These factors are further explored in Section 3.5 which compares OP-FTIR AM and SUMMA
canister AM results in the context of sampling location and wind direction.
3.5 Results of Canister Measurements
As described in Section 2.4, SUMMA canister samples were collected during the field campaign to
help inform the OTM 10 results. The one-hour canister samples were analyzed using U.S. EPA
39
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Compendium Method TO-15, and speciated non-methane organic compounds (SNMOC) method.
The results of the laboratory analyses are contained in Appendix B of this document.
Table 3-14 summarizes the SUMMA canisters data for several important compounds. The
concentrations were determined by TO-15 except for the AM estimation which was derived from a
42 compound summation of the SNOMC results as described in Appendix A. The approximate
position of the canister with respect to local source is indicated by the upwind/downwind column
entry and the OP-FTIR optical path used for comparison is also shown. These comparisons are
described and later in this section. Collocated canister entries represent average values of the
analyses. The collocated canisters produced the same concentrations to within 10% with the
exception of the ER085, ER114 pair which differed by approximately 40%.
It can be seen that the upwind canisters reflect generally lower values than the downwind canisters.
The Williams canisters recorded higher concentrations than the EnCana canisters but this was
primarily due to the location of the Williams canisters in very close proximity to the skim pond
source and inlet to the North pond. These factors are further discussed later in this section.
Figures 3-9 and 3-10 summarize 42 of the most prevalent species measured by SNMOC analysis
of the downwind canisters. Figure 3-9 (Williams facility) presents the average of four downwind
canisters (TNAPC-11, 648, 926, ER047) with the average of three upwind canisters (3639A,
ER038, ER001)subtracted. Figure 3-10 (EnCana facility) presents the average of six downwind
canisters (3248, 988, 3254, 167601, 444, ER043) with the average of three upwind canisters
(ER061, 3255, ER029) subtracted. Figure 3-10 is included for completeness but should not be
emphasized since the upwind versus downwind canister signal levels at the EnCana facility were
extremely low (single digit ppb) so the results are less certain especially with regard to the low mass
compounds which can be affected disproportionately by background variation. An optimized subset
of canisters was employed for the EnCana analysis in an attempt to increase signal levels. Overall,
the Williams distribution (Figure 3-9) has a much higher degree of certainty due to the higher
concentration levels and is likely similar to the actual distribution at the EnCana facility
In addition to providing speciation information, the SUMMA canister samples can be compared to
the OP-FTIR measurements along selected paths to help inform the study. In the following figures,
OP-FITR time series graphs of AM concentrations for ground-level beam paths are presented along
with SUMMA canister AM estimates based on SNMOC analysis (described in Appendix A). The
comparisons of OP-FITR and SUMMA canister are summarized in Table 3-14. The approximate
location of the SUMMA canisters and OP-FTIR beam paths are noted in the associated images and
the wind rose for the 1 hour SUMMA canister sampling period is also presented.
40
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-14. Summary Canister Summary from the Williams and EnCana Sites
Site Date
Williams
Rulison
EnCana
Benzel
8/7
8/8
8/8
8/9
8/9
8/12
8/12
8/13
8/13
8/13
8/13
8/14
8/14
8/14
8/14
8/15
8/15
Sampling
Mid-point
(hnmin)
16:43
13:55
13:55
14:301
14:301
11:301
11:301
11:37
11:37
16:22
16:22
11:03
11:03
16:39
16:39
11:39
11:39
Summa ID
TNAPC-1 1
3639A
926, 648
ER001, ER038
ER047
ER029
659, 167604
3255
ER043, 444
TNAPC20
167601, 3254
ER061
ER069, ER064
15280
988, 3248
ER021
ER085, ER114
Upwind /
Downwind
d
u
d
u
d
u
d
u
d
u2
d
u
d
u2
d
u2
d
Benzene
(ppbv)
203
1.4
88.8
0.6
8.1
0.5
2.3
0.3
2.2
1.3
1.5
0.3
2.3
1.1
2.5
4.3
1.9
Toluene
(ppbv)
1210
4.8
221
1.1
16.7
1.1
3.7
0.7
5.7
4.1
5.2
0.4
3.2
2.0
4.6
7.3
3.4
m-,o-,p-
Xylene
(ppbv)
27113
3.1
177
0.7
15.7
1.2
2.3
0.7
6.5
5.1
8.5
0.2
1.9
1.2
2.6
2.7
2.1
Octane
(ppbv)
1160
0.5
72.6
0.4
11.6
0.6
0.9
0.4
2.0
2.0
2.8
0.1
0.4
0.4
0.8
0.6
0.4
AM
Estimate
(ppbv)
6654
47.5
546
27.5
164
15.6
28.5
21.4
50.6
58.2
60.0
10.7
19.4
26.0
33.5
85.1
28.6
OP-FTIR
Plane
E4
A1
E4
A1
E4
E1
-
E1
A4
E1
A4
E1
A4
E1
A4
A1
A4
1 approximate time
2 upwind affected by source, see detailed description
3 estimated value
A1-ARCADIS OP-FTIR beam 1 (of A123)
A4 - ARCADIS OP-FTIR beam 4 (of A456)
E1 - EPA OP-FTIR beam 1 (of E123)
E4 - EPA OP-FTIR beam 4 (of E456)
All results above 50 ppb required dilution of SUMMA canister.
41
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
cnn
°- yinn _
nt ration (p
$ i
D C
age Conce
51 S
3 C
Ol
inn
n -
_nnn
<$?
-
_ .
[L.
n
-
n
PI
nL. n n
Miinnniii-iii
l-l
l-l
1-1
.n
^^^^^^^^^J^^
Figure 3-9. Summary of Downwind Canisters SNMOC Analysis for the Williams Facility
42
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
7 n -
6n
Q_
£
"^T R n
o
"g
4-1
£ A n -
o
o
o
at Q n
o) J-u
S
at
9 n
1 n
n n
i-i
. .
n.
i-i
._.
[]
-
Hn_n_
-
i— i
•
'
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 3-11 shows canister TNAPC11 in close proximity to the skim pond and inlet of the skim pond
into the North evaporation pond. The close proximity of the canister sample to large sources can
yield highly variable results small changes in wind direction can greatly affect measured
concentrations. Although E4 is significantly lower than TNAPC11 during the canister sampling
period, E4 registered similar concentrations at neighboring time periods. Concentrations during this
time period were amongst the highest recorded during the study.
In a similar fashion to Figure 3-11, Figure 3-12 shows elevated concentrations for 648, 926
compared to OP-FTIR path E4 for the sampling time period, believed to be due to the proximity of
the canister to the pond inlet (local source). Under slightly different wind conditions after 15:00, the
E4 path is elevated. In comparisons, the upwind canister 3639A is in good agreement with
neighboring OP-FTIR plane (A1). It is noted some number of the A1 points are below MDL.
In Figure 3-13, wind is from the SE resulting in reduced sampling of the previously discussed strong
sources for the canister which is slightly NW of this position. The wind direction in this case provided
enhanced average concentrations measured by OP-FTIR path E4 with high temporal variability
noted as the wind direction changes over short timer periods. The upwind canisters ER038 and
ER001 are in good agreement with OP-FTIR path A4.
In Figure 3-14 presents the only available comparison from the EnCana facility on 8/12/08. This
represents primarily and upwind comparison and shows good agreement between the canister and
OP-FITR result.
Figure 3-15 presents the first of two comparisons from 8/13/08 and shows relatively good
agreement in both upwind and downwind concentrations. As opposed to the previous Williams
results, the temporal profile of the downwind OP-FTIR results is more stable indicating more
developed plumes which aids in the comparison of canister to OP-FTIR.
Figure 3-16 presents the second comparison from 8/13/08. In this case the upwind and downwind
canister show very similar results. This is explained by the fact that the TNAPC20 upwind canister is
located too close to the pond edge and under these wind conditions, is being significantly impacted
by emissions from the pond. The variability in wind conditions is also evident in the OP-FTIR data.
Figure 3-17 presents the first of two comparisons from 8/14/08. This is an informative case which
shows good agreement for the upwind case however the downwind canisters ER064 and ER069
significantly lower than OP-FTIR A4 result. The inlet to the pond at the EnCana is located toward
the North West portion of the Pond (Section 2.5) and is expected to be a high contributor to the
overall source signature. Under the indicated wind directions and canister placements, this portion
of the source is not effectively sampled by the canisters but is robustly captured by the OP-FTIR.
44
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/07 16:13:10 - 17:13:10
,.-- "NORTH--,
10000
7000-
•« 5000
o
o
3000-
-0-E4FTIR 8/7/08
-A-TNAPC11 (E4)
14:00
15:00
16:00
Time (hrmin)
17:00
Figure 3-11. Williams 8/7/08, Canister TNAPC11 and OP-FTIR Path E4.
45
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/D8 13:25:00 -14:25:00
.---•"""NORTH--,
800
•« 400
o
O
d V \,o
/ ~ a
-0-E4FTIR 8/8/08
^A- 648,926 (E4)
-•-A1 FTIR 8/8/08
-A-3639A(A1)
6 k fl
y
13:00
14:00
15:00
16:00
Time (hrmin)
Figure 3-12. Williams 8/8/08, Canisters 648 and 926 Compared to OP-FTIR Path E4 and Canister 3639A
Compared to OP-FTIR Path A1
46
-------
Colorado - 2008/08/09 14:00:00 -15:00:00
.---""""NORTH--,
T
1 nnn
I UUU
900 -
800-
„ 700 -
Q.
Q.
^ 600 -
o
•£ 500-
8
c
Q 400 -
"*• 300 <
200-
100,-
l
n -
/?
-^
m^m
0
1
- -^ ^-^ai
/
J
r
/
/
6
1
A
U 6/ \
MX
4 "
I
N k
I
9
-0-E4FTIR
8/9/08
-£s- ER047 (E4)
9
-^A1 FTIR
8/9/08
I -^-ER038, ER001 (A1)
I
/
I
A
/
/ \
/ \ R
I
H
i i
/ \
0 \
jj
0
9
I
I
\ I
\ 1
V
\
^~~f*~^
(
o
/
0
/
I .
*--*
X*.
\_^*-« *^
1
9
\l
I
?
I
o
1
— . _^
^
-•
12:00
13:00
14:00
15:00
Time (hrmin)
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 3-13. Williams 8/9/08, Canister ER047 Compared to OP-FTIR Path E4 and Canisters ER038 and ER001
Compared to OP-FTIR Path A1
47
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
100
80-
r so-
o
30
10
-0-E1 FTIR 8/12/08
-A-ER029(E1)
10:30
11:30
Colorado - 200B/08/12 11:00:00 -12:00:00
V
V
..feoyitu---'
12:30
Time (hrmin)
13:30
0
A
Figure 3-14. EnCana 8/12/08, Canister ER029 Compared to OP-FTIR Path E1
48
-------
500
100-
E1 FTIR 8/1 3/08
M FTIR 8/1 3/08
ER043, 444 (A4)
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado-200B/DB/13 11:07:00- 12:07:00
f\
\/\
V
l!
10:00
11:00
12:00
Time (hr:Min)
13:00
Figure 3-15. EnCana 8/13/08, Canister 3255 Compared to OP-FTIR Path E1 and Canisters ER043 and 444
Compared to OP-FTIR Path A4
49
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/13 15:52:00 -16:52:00
400-
300-
200-
100-
n .
-o-E1 FTIR 8/13/08
^A-TNAPC20(E1)
-«-A4 FTIR 8/1 3/08
-A- 3254, 167601 (A4) T
? I
ri /I?
\ / ? /
\ / i /
v^ n
^ M „!
x^^V0^ ir
y
i
^
I-
xxi
I
lU «! I
I
I I
/
/
/ f
I
/ liN,L
jv LU lAJ "Jk ,
Hir = I"" Y¥^ \
i/% Lxxx.^W*^ 7\ S \ui\^
14:00
15:00
16:00
Time (hr:Min)
17:00
Figure 3-16. EnCana 8/13/08, Canister TNAPC20 Compared to OP-FTIR Path E1 and Canisters 3254 and
167601 Compared to OP-FTIR Path A4
50
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/14 10:32:45 -11:32:45
_,,- "NORTH--,,_
200
o
E1 FTIR 8/14/08
-A4FTIR 8/14/08
- ER064, ER069 (A4)
o -
9:00
10:00
11:00
Time (hrMin)
12:00
Figure 3-17. EnCana 8/14/08, Canister ER061 Compared to OP-FTIR Path E1 and Canisters ER064 and ER069
Compared to OP-FTIR Path A4
51
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Figure 3-18 presents the second comparison from 8/14/08. Note the change in canister placements
and wind conditions compared to Figure 3-17. Here the OP-FTIR A4 path registers similar
concentrations to Figure 3-17 prior to canister sampling and reduced values comparable to the
canister as winds obtain SW components. At this time signal begins to appear of the E1 path.
Figure 3-19 presents a comparison from 8/15/08. In this case the canister ER021 is in close
proximity to the pond inlet and is clearly impacted by a local source so is not a true upwind canister.
It is noted that E1 OP-FTIR beam path (not shown) was characteristically low for this time period.
The ER021 canister is most easily compared to the A1 OP-FTIR path under this wind direction and
relatively good agreement is evident. Agreement is relatively good for the A4 path and it is
interesting the note the how the concentration changes between the A4 and A1 paths as a
consequence of wind direction variations overtime.
3.6 Summary of Water Analysis Results
As discussed in Section 2.5, water samples were taken and analyzed to provide supporting
information for the study. The results are presented in Tables 3-15 and 3-16 for the Williams and
EnCana Facilities respectively. All samples were analyzed for volatile organics by EPA SW-846
Method 8260 "Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry (capillary
column technique)". Due to the high levels of VOCs in the Skim Pond Inlet and Outlet samples,
some of the compounds exceeded the calibration range. Further information on the analysis can be
found in Appendix C.
Table 3-15 shows a summary of the results for the three highest concentration compounds for the
skim pond inlet and exit. All results presented in Table 3-15 exceeded the calibration range and are
considered estimates. For samples taken from the north and south pond outlet headers, all
compounds analyzed were under the detection limit (<2.5 ug/L).
Table 3-16 shows a summary of the results from the EnCana facility for the three highest
concentration compounds for the evaporation pond inlet and subsurface samples. All results
presented in Table 3-16 exceeded the calibration range and are considered estimates.
At both sites, a strong gradient in concentration from the inlet to outlet (or pond edges) is evident.
The three highest compounds (benzene, toluene, and m-, p-xylenes were also found in relatively
high concentrations compared in the other analyses.
52
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/14 16:09:00 -17:09:00
-o-E1 FTIR 8/14/08
-A-15280(E1)
-m-M FTIR 8/14/08
988, 3248 (A4)
14:00
15:00 16:00
Time (hrMin)
17:00
Figure 3-18. EnCana 8/14/08, Canister 15280 Compared to OP-FTIR Path E1 and Canisters 988 and 3248
Compared to OP-FTIR Path A4
53
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Colorado - 2008/08/15 11:09:00 - 12:09:00
,---"""" "NORTH - -,
10:00
-0-A1 FTIR 8/1 5/08
M FTIR 8/1 5/08
, ER114(A4)
11:00 12:00
Time (hrmin)
13:00
Figure 3-19. EnCana 8/15/08, Canister ER021 Compared to OP-FTIR Path A1 and Canisters ER085 and ER114
Compared to OP-FTIR Path A4
54
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 3-15. Summary Water Analysis from the Williams Site
Sample No
Date
Time (hrmin)
Benzene
(ug/L)
Toluene
(ug/L)
m,p-Xylene
(ug/L)
Skim Pond Inlet
SP IN-1
SP IN-2
8/7/2008
8/8/2008
13:34
11:02
19,000
16,200
50,000
29,400
40,400
16,300
Skim Pound Outlet
SP OUT-1
SP OUT-2
SP OUT-2 Dup
SP OUT-3
SP OUT-4
8/7/2008
8/8/2008
8/8/2008
8/8/2008
8/8/2008
13:45
11:04
11:04
11:35
11:51
15,000
7,470
10,700
11,300
12,000
33,400
16,200
21,900
23,600
27,400
24,100
8,850
11,000
11,900
16,100
Table 3-16. Summary Water Analysis from the EnCana Site
Sample No
Date
Time
(hrmin)
Benzene
(ug/L)
Toluene
(ug/L)
m,p-Xylene
(ug/L)
Grass Mesa Inlet
Grass-1
Grass-2
Grass-3
8/12/2008
8/13/2008
8/14/2008
16:30
16:50
10:45
13,700
7,930
12,500
36,400
18,500
30,900
22,500
8,180
18,300
West Side
W-1
W-2
W-3
W-3 Dup
8/12/2008
8/13/2008
8/14/2008
8/14/2008
14:45
15:30
11:15
11:15
642
564
694
729
1,370
1,430
1,710
1,800
756
933
1,000
1,070
South Side
S-1
S-2
8/12/2008
8/13/2008
15:20
15:15
382
804
716
1,920
314
1,100
East Side
E-1
E-2
8/12/2008
8/13/2008
15:40
14:50
605
550
1,320
1,340
689
804
55
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
This page intentionally left blank.
56
-------
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
4. Summary
A measurement campaign was conducted at the Williams Rulison and EnCana Benzel facilities in
Western Colorado from August 6-9 and 12-15, 2008, respectively. The purpose of the study was to
increase knowledge of VOC emissions form the produced water ponds at the facilities. The
measurement approach used EPA method OTM 10 with two OP-FTIRs deployed in a four corners
configuration to provide mass emission flux estimate of measurements for an alkane mixture. Table
4-1 presents a summary of the AM emission flux results from the two sites. The values in the table
represent the average of all valid 20-minute AM flux estimates calculated over a four-day period at
each site with standard deviation in parenthesis and number of values indicated. The uncertainty
estimate for the individual flux measurements comprising this average is estimated at ± 40%
(section 5.3). The uncertainty in the overall average is likely driven by the temporal variability in the
source emissions.
Table 4-1. AM Emission Flux Results from William Rulison and EnCana Benzel Sites
Site
Williams
Williams
EnCana
Source
Evaporation Pond
Skim Pond
Evaporation Pond
Average AM Flux
[g/s]
0.20 (0.33)
0.90 (0.58)
0.07 (0.06)
Number of
Values
27
15
65
The results show that the major AMs emissions source from the Williams facility was from the Skim
Pond. The emissions from the Skim Pond were on average about 5 times the emissions from the
Evaporation Pond. The results also show that the emissions from the Evaporation Ponds at the two
sites were comparable (0.20 g/s and 0.07 g/s for the Williams and EnCana sites, respectively).
The OP-FTIR TAM data were used to estimate concentrations of select VOC at the sites. The VOC
concentrations were ratioed to AM concentrations and measured fluxes from the same time period
to produce an estimate of the VOC emissions from the sites. Table 4-2 presents the results of these
calculations. The values of Table 4-2 include underlying uncertainty in AM flux measurement
average in addition to significant VOC to AM concentration ratio uncertainty so the values should be
considered estimates
In addition to the OP-FTIR measurements, VOC concentrations were determined using SUMMA
canister samples and EPA Method TO-15 and SNMOC analysis. These values were compared to
the OP-FTIR data to provide supporting information for the study. Water samples were also
acquired and analyzed to help support the study. These data showed a strong concentration
gradient between the inlet on outlet (or pond edges) for both facilities.
57
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 4-2. Summary of Estimated VOC Emission Rates (in grams per second) from William Rulison
and EnCana Benzel Sites
Site
Williams
Williams
EnCana
Source Area
Evaporation
Pond
Skim Pond
Evaporation
Pond
Benzene
(g/s)
0.016
0.078
0.029
Toluene
(g/s)
0.036
0.181
0.023
m-Xylene
(g/s)
0.014
0.072
0.017
o-Xylene
(g/s)
0.036
0.182
0.014
p-Xylene
(g/s)
0.018
0.088
0.014
Methanol
(g/s)
0.001
0.006
0.002
Methane
(g/s)
0.015
0.074
0.007
The overall AM emission rate estimates for the produced water pond sources at the Williams facility
was -16 times higher than for the EnCana facility. The incoming flow estimates were -5300 barrels
per day for the Willams facility and - 300 barrels per day for the EnCana facility, a factor of -18.
Combining the emission estimates of benzene, toluene and m-,o-,p-xylene, the Williams facility was
- 7.5 times higher than the EnCana, although these estimates contain additional uncertainty.
Differences in emissions between the facilities could be due to many variables including: differences
produced water input to the ponds, pond size and aeration differences, transportation and water
treatment differences etc.
Note that the emission estimates presented in this report represent a snapshot in time consisting of
day-time observations over consecutive four-day periods at each facility during the month of
August. Diurnal and seasonal effects in addition to changing process variables such as
(concentration of hydrocarbons in the waste water, use of spray operations, changes in separation
and biotreatment, etc.) were not evaluated as part of this study. Since these variables may have a
significant effect on emissions, extrapolation of the results contained in this report would include
significant uncertainty. As a specific example, methanol water concentrations are known to vary
seasonally so the emission data contained in this report is may not be typical.
58
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
5. Quality Assurance/Quality Control
This document reports the results from Phase I of a multi-phase research effort to identify and
quantify select VOC and methane emissions from oil and gas field operations. These data are not
intended for direct use in enforcement activities, litigation, or human studies. These data were
collected in conformance with the quality requirements of NRMRL QA Category III.
The basic objective of this phase of the project was to improve knowledge of emission rates
produced water evaporation ponds. The approach used EPA Method OTM -10 in conjunction with
canister sampling. The following sections describe the procedures used to ensure that the data met
the project data quality indicators (DQI) and was acceptable for use in meeting these study
objectives.
5.1 Instrument Calibration
As stated in the ECPB Optical Remote Sensing Facility Manual (USEPA, 2004), all equipment is
calibrated annually and or cal-checked as part of standard operating procedures. Certificates of
calibration are kept on file. Maintenance records are kept for any equipment adjustments or repairs
in bound project notebooks that include the data and description of maintenance performed.
Instrument calibration procedures and frequency are listed in Table 5-1 and further described in the
text.
5.2 Assessment of DQI Goals
The critical measurements associated with this project and the established data quality indicator
(DQI) goals in terms of accuracy, precision, and completeness are listed in Table 5-2. More
information on the procedures used to assess DQI goals can be found in Section 10 of the ECPB
Optical Remote Sensing Facility Manual (USEPA, 2004).
59
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Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Table 5-1. Instrumentation Calibration Frequency and Description
Instrument
IMACC, Inc. OP-FTIR
AIL, Inc. OP-FTIR
R.M. Young
Meteorological Head
R.M. Young
Meteorological Head
Topcon Model GTS-
21 1D Theodolite
Topcon Model GTS-
21 1D Theodolite
Measurement
Analyte PIC
Analyte PIC
Wind Speed in
miles/hour
Wind direction in
degrees from North
Distance
Measurement
Angle Measurement
Calibration Date
Pre-deployment and
in-field checks
Pre-deployment and
in-field checks
July 21, 2008
July 21, 2008
June 17, 2008
June 17, 2008
Calibration Detail
MOP-6802 and 6823 of the ECPB Optical
Remote Sensing Facility Manual
MOP-6802 and 6823 of the ECPB Optical
Remote Sensing Facility Manual
APPCD Metrology Lab Cal. Records on
file
APPCD Metrology Lab Cal. Records on
file
Calibration of distance measurement.
Actual distance=43.105 ft
Measured distance= 42.5 ft
Calibration of angle measurement.
Actual angle= 360°
Measured angle= 358°58'48"
Measured angle= 359°00'20"
Measured angle= 359°01'08"
Table 5-2. Measurement Quality Objectives for the Project
Measurement
Parameter
Analyte PIC
Cannister
Measurements
Ambient Wind
Speed
Ambient Wind
Direction
Distance
Measurement
Prevailing Wind
Direction
Analysis Method
OP-FTIR: Nitrous Oxide
Concentrations
TO-15/SNMOC
R.M. Young Met heads
post-deployment
calibration in EPA
Metrology Lab
R.M. Young Met heads
post-deployment
calibration in EPA
Metrology Lab
Theodolite- Topcon
R.M. Young Met heads
Accuracy
±25%, 15%,
10%a
±30 of audit
± 1 m/s
±10°
± 1m
N/A
Precision
± 10%
±25
± 1 m/s
±10°
±1 m
N/A
Detection
Limit
See Table 4-2 of
QAPP (EPA,
2008)
See Tables 4-3
and 4-4 of QAPP
(EPA, 2008)
0.2 m/s
5 deg
0.1 m
N/A
Completeness
90%
90%
90%
90%
100%
NA
a. The accuracy acceptance criterion of ±2 5% is for pathlengths of less than 50m, ± 15% is for pathlengths
between 50 and 100m, and ± 10% is for pathlengths greater than 100m.
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5.2.1 DQI Check for Analyte PIC Measurement
The precision and accuracy of the concentration data may be checked by looking at the analyzed
nitrous oxide concentrations. The known atmospheric background nitrous oxide concentration is
around 315 ppbv (this is an average value, as the value exhibits a slight seasonal variation). The
acceptable range of nitrous oxide concentrations is 315 ppb ± 25% for pathlengths of less than
50m, 315 ppb ±15% for pathlengths between 50 and 100m, and 315 ppb ± 10% is for pathlengths
greater than 100m. Verifying this background concentration provides a good QC check of the data
collected. Obviously, this method is not valid for data collected at a site that is a source of nitrous
oxide.
The precision of the analyte PIC measurements was evaluated by calculating the relative standard
deviation (RSD) from one data subset collected near the surface of the suspected source. A subset
is defined as the data collected along one particular path length during one particular survey in one
survey sub-area.
The accuracy of the analyte PIC measurements was evaluated by comparing the calculated nitrous
oxide concentrations from one data subsets to the background value of 315 ppb. The number of
calculated nitrous oxide concentrations that failed to meet the DQI accuracy criterion was recorded.
Overall, a total of two datasets were analyzed for each OP-FTIR instrument. Based on the DQI
criterion set forth for precision of ± 10%, all of the data subsets from the ARCADIS OP-FTIR were
found to be acceptable, for a completeness of 100%. The range of calculated relative standard
deviations for the data subsets was 1.8 to 3.2 ppb, which represents 0.57 to 1.02% RSD. Based on
the DQI criterion set forth for precision of ± 10%, all of the data subsets from the EPA OP-FTIR
were found to be acceptable, for a completeness of 100%. The range of calculated relative
standard deviations for the data subsets was 3.6 to 3.7 ppb, which represents 1.14 to 1.17% RSD.
Each data point (calculated nitrous oxide concentration) in the data subsets was analyzed to assess
whether or not it met the DQI criterion for accuracy of ± 10% (315 ± 32 ppb), as the path lengths
used for measurements were greater than 100 meters. A total of 138 data points were analyzed
from the ARCADIS OP-FTIR, and 138 of the points met the DQI criteria for accuracy for a
completeness of 100%. A total of 136 data points were analyzed from the EPA OP-FTIR, and 89 of
the points met the DQI criteria for accuracy for a completeness of 65%. It should be noted that all of
the analyzed data points from the EPA OP-FTIR were within ± 14% of the DQI criterion for accuracy
of 315 ppb (range of analyzed nitrous oxide concentrations was 335 to 357 ppb).
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5.2.2 DQI Checks for TO-15 Can Measurements
A field audit (Technical Systems Audit) was conducted by EPA quality staff from OAQPS at the start
of the Williams Rulison sampling campaign. An audit report was not generated.
The QC data associated with the ERG TO-15 and SNMOC analyses of these samples were
evaluated according measurement audit goals: accuracy ± 30 percent; precision ± 25 percent; and
90 percent completeness. The accuracy could not be assessed since laboratory control sample
results were not included in the ERG laboratory reports. A number of field duplicate analyses were
conducted by the laboratory, with a resulting precision of more than 98 percent. All samples were
analyzed and reported, resulting in 100 percent completeness.
5.2.3 DQI Checks for Ambient Wind Speed and Wind Direction Measurements
The meteorological head DQIs are checked annually as part of the routine calibration procedure.
The R.M. Young Meteorological heads used in the current study were calibrated by the EPA
Metrology Lab on July 21, 2008. Due to field studies requiring the equipment, a post calibration
assessment of the R.M. Yong Meteorological heads by the EPA Meteorology lab could not be
performed. Both heads did successfully pass a post deployment certified calibration test performed
by the manufactures (R.M. Young) conducted on May 13, 2009.
Additionally, a couple of reasonableness checks were performed in the field on the measured wind
direction data. While data collection was occurring, the field team leader compares wind direction
measured with the heads to the forecasted wind direction for that particular day. Another
reasonableness check involved confirming a magnetic north reading by manually setting the vane
to magnetic north using a hand held compass. The output wind direction during this manual test
should be very close to 360°.
The Wind Sonic anemometer was used in place of the 10-meter R.M. Young Meteorological head
when the wireless transmitter failed on the last day at the Williams Rulison facility. This instrument
was intended only as an emergency back-up and was therefore not calibrated prior to the field
campaign. There are no moving parts in this anemometer, nor is there an auto northing feature.
There is a yellow dot on the Wind Sonic that must be pointed north. Prior to use, the theodolite
compass was used to verify that the instrument was pointing to magnetic north.
5.2.4 DQI Checks for the Topcon Theodolite
A calibration check was performed before the field campaign on June 17, 2008. The calibration of
distance measurement was done at the EPA facility using a tape measure. The actual distance was
43.105 feet, and the measured distance was 42.5 feet. The results indicate accuracy and precision
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fall well within the DQI goals. The calibration of angle measurement was also performed. The actual
angle was 360°, and the measured angles were 358°58'48", 359°00'20" and 359°01 '08". The
results indicate accuracy and precision fall well within the DQI goals.
Additionally, there are several internal checks in the theodolite software that prevent data collection
from occurring if the instrument is not properly aligned on the object being measured, or if the
instrument has not been balanced correctly. When this occurs, it is necessary to re-initialize the
instrument to collect data.
5.2.5 QC Checks of OP-FTIR Instrument Performance
Several diagnostic checks were performed on the OP-FTIR instrumentation prior to deployment to
the field, and during the duration of each field campaign. These checks involve assessing the
electronic noise of the instrument, the strength of the instrument signal, and features in the collected
data spectrum. The results of these tests are used to determine whether or not the instrument is
functioning properly. More information on the diagnostic checks that are performed as part of a
typical ORS field campaign can be found in MOP 6802 and 6823 of the ECPB Optical Remote
Sensing Facility Manual (USEPA, 2004).
In addition to the QC checks performed on the OP-FTIR, the quality of the instrument signal
(interferogram) was checked constantly during the field campaigns. This was done by ensuring that
the intensity of the signal is at least 5 times the intensity of the stray light signal (the stray light signal
is collected as background data prior to actual data collection, and measures internal stray light
from the instrument itself). In addition to checking the strength of the signal, checks were done
constantly in the field to ensure that the data were being collected and stored to the data collection
computer. During the campaign, a member of the field team monitored the data collection computer
to make sure these checks were completed.
Prior to instrument deployment, a series of QC checks were performed on the IMACC OP-FTIRs to
assess the instrument performance. The single beam ratio, baseline stability, noise equivalent
absorbance, ZPD stability, saturation, random baseline noise, and stray light diagnostic tests were
performed at the EPA facility. The results of the tests indicated that the ARCADIS and EPA OP-
FTIR instruments were operating within the acceptable criteria range.
5.2.6 Difficulties Encountered
During the two-week measurement campaign, the project encountered some problems with
instrumentation and data telemetry. As mentioned in Section 3.2, the R.M. Young meteorological
station was employed to collect wind data until mid-morning (10:30 a.m.) on August 9, 2008. At that
time, the wireless transmitter failed in the 10-meter head and the emergency backup Wind Sonic
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anemenometer was put in place. A compass was used to establish magnetic north (there is no auto
north feature on the Wind Sonic) and the software was modified for use in the field.
During this time, an R.M. Young meteorological station was employed to collect wind data until mid-
morning (10:30 a.m) on August 9, 2008. At that time, the 10-meter head transmitter failed and a
Wind Sonic anemometer was put in place and was used for the remainder of the sampling.
There were some seal integrity issues with both the EPA and ARCADIS OP-FTIR instruments. For
the EPA OP-FTIR, the liquid nitrogen would run out much sooner than expected. The field protocol
was modified to ensure that the liquid nitrogen was checked more frequently.
During the evening of August 10, 2008, unexpected and severe wind gusts (estimated at 70-80
mph) knocked over the OP-FTIR and orbital scanner. On the morning of August 11, 20 minutes of
data was collected and analyzed to ensure that the instrument was working properly before being
deployed to the EnCana Benzel site.
5.3 Estimate of Uncertainty for OTM 10 Emission Measurements
There are four primary sources of uncertainty for OTM 10 emissions estimates from the produced
water pond sources for this project: (1) baseline flux measurement uncertainty for the combination
of multiple measurement planes discussed in Section 3.1 (Combined Uncertainty); (2) uncertainty
due to assignment of interfering sources; (3) additional uncertainty associated with 3-beam OTM 10
configuration; and (4) uncertainty due to the variability of source. These sources of uncertainty will
be discussed in this section.
Combined Flux Uncertainty
As discussed in Section 3.1, a combined uncertainty estimate was produced for each 20-minute flux
measurement. This uncertainty estimate was calculated by propagating individual estimates of
uncertainty for each OTM 10 measurement plane to a combination of all four planes using a base
assumption of ± 20% uncertainty for each plane. The ± 20% total uncertainty number is an estimate
on previous tracer release studies of OTM 10 performance in a close-coupled area source
measurement scenario. For this project, the average calculated combined uncertainty expressed as
a percentage of the net flux value were typically in the 20% to 30% range however several values
exhibited very high values of uncertainty. For example, Williams 8/7/09 12:10 shows a very low net
flux (0.005 g/s) with a large combined uncertainty (0.0880 g/s) due to a high external flux from the
interfering source (0.450 g/s). There is a similar value for EnCana 8/12/09 13:30 which shows a
very low net flux (0.001 g/s) with a large combined uncertainty (0.004 g/s) due to a high external flux
(0.02 g/s). Excluding these two outlier values, a meaningful metric of uncertainty can be produced
by taking the average value of the combined uncertainty expressed as a percentage of the
individual flux measurements value for each facility. For the Williams Evaporation Pond this value is
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32.7% and for the EnCana facility this value is 26.8%. Note that the skim pond facility is expressed
as the external source so this calculation cannot be done for this source however due its strength, it
is less affected by interfering sources so a 25% to 30% combined uncertainty assumption would
seem reasonable.
Uncertainty Due to Assignment of Interfering Sources
As discussed in the combined uncertainty section above and also in the text and graphs of Section
3, interfering sources can cause significant uncertainty with regard to emission flux estimates. This
is especially true when the interfering source is strong in comparison to the source being evaluated.
An example of this would be evaluation of the Williams North pond with potential interference from
the skim pond. To first order, interfering sources are accounted for in the combined uncertainty
estimation however there are cases were assignment of the interfering source can come into
question due to uncertainties in wind direction. An example of this would be the 13:10 value from
8/7/09 which shows a high value for emissions from the North Pond (1.56 g/s) compared to the
overall average (0.20 g/s) and was produced during a period when the direction was changing. In
this particular case, this effect may have been exaggerated due to the close proximity of the skim
pond source and the relatively strong source associated with the inlet to the North pond from the
skim pond. It is difficult to estimate the overall uncertainty associated with this effect however it is
partially reflected in the standard deviation of the results of the combined average.
Uncertainty Due to 3-beam OTM 10 Approach
As discussed in Section 2, the OTM 10 measurement configurations for this project consisted of
three measurement paths which extended from the OP-FTIR instrument to the scissor lift. The 3-
beam OTM 10 approach was chosen for this project since it was decided that it was more important
to obtain a larger number of measurement cycles as opposed to fewer number of cycles with a five
beam approach since the horizontal spatial location of the plume was not of primary importance.
Due to the convergence of the optical beams at the instrument location, the use of a 3-beam
measurement approach can introduce additional uncertainty in the flux if the emission zone is
relatively small and located nearthe ends of the configuration. For this project the key suspected
emission areas are thought to provide relatively well-developed plumes from spatially and were
generally well-centered on the optical configuration (i.e. location of Williams skim pond), however a
discussion of general uncertainty associated with the three beam approach is warranted.
To produce this uncertainty discussion, we used the VRPM Fit Explorer program (described by
Abichou et al., 2009) to run a series of simulations to assess the variability in flux results from the
OTM 10 method as a result of assuming different ayand peak plume concentration locations. In this
simulation program, a downwind concentration field is generated from an area source using EPA
ISC Gaussian dispersion model and then analyzed using OTM 10 algorithms and optical beam
geometries.
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In analyzing the PIC data using the 3-beam approach, the peak plume concentration was assumed
to be centered along the crosswind axis of the OTM 10 configuration, and the ay parameter
(horizontal dispersion coefficient) of the measured plume was assumed to be equal to 1/4the length
of the OTM 10 configurations. It was necessary to make these assumptions because the 3-beam
OTM 10 approach does not include two intermediate surface beam paths which are used to obtain
information on the horizontal location and dispersion of the plume.
To investigate the effect of assuming fixed ay and lateral plume size parameters in the OTM 10
VRPM calculation, as simulation was performed which presented three different plume size
scenarios using VRPM Fit Explorer program. For this simulation, the OTM 10 plane configuration
parameters were set near the average values used in this study (plane length = 140 m,
retroreflector heights 1 m, 4m, 9m). The plume size parameter in the OTM 10 calculation was fixed
at 70 m and the ay parameter was varied (7m, 70 m, and 700 m). The simulated plumes were
centered on the configuration with the upwind location of the source set to 50 m and stability class
set to three with winds normal to the plane. The results are shown in Table 5-3 for three different
staring plume sizes with values compared to 1.0 for a perfect reconstruction of the simulated flux.
Table 5-3. Results of Flux Values Calculated by the VRPM Fit Explorer Program With a Fixed Peak
Plume Concentration Location and Varying Values of the ay Parameter
ay Value
oy= 7 m
oy = 70 m
oy = 700 m
40 m x 40 m
0.97
1.03
1.04
70 m x 70 m
0.92
0.99
1.00
100 m x 100 m
0.86
0.93
0.94
The results of the simulation show that the OTM 10 calculation is relatively insensitive to the choice
of the ay parameter and that the choice of setting this parameter to 1/4the value of the OTM 10
plane length is a reasonable assumption and likely will not lead to a large source of error.
As discussed previously, a potentially larger source of error when using the three-beam OTM 10
approach occurs in situations where the plume is relatively small in comparison to the OTM 10
plane and passes through the plane near its edges. At the position of the OP-FTIR, the three optical
beam paths are close together forming the vertex of the OTM 10 triangle. At the position of the
retroreflectors, the beams are the separated by the largest amount. The flux estimate for plumes
intersecting the OTM 10 plane near the OP-FTIR instrument will be overestimated. The flux
estimate for plumes intersecting the OTM 10 plane near the scissor lift and retroreflectors will be
underestimated.
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Table 5-4 presents the results of a second simulation which investigates variation of the plume
center location as it intersects the OTM 10 plane with the ay parameter assumed to be 70 m and
other parameters the same as the previous simulation.
Table 5-4. Results of Flux Values Calculated by the VRPM Fit Explorer Program with a Fixed ay
Parameter and Varying Peak Plume Concentration Locations
Peak Plume
Concentration Location (m)
30
50
70
90
110
40 m x 40 m
2.01
1.44
1.03
0.77
0.60
70 m x 70 m
N/A
1.318
0.99
0.76
N/A
100 m x 100 m
N/A
N/A
0.93
N/A
N/A
N/A- Simulation results not included because plume would not be located within the confines of the OTM 10
configuration plane
The results of the simulation show that the 3-beam OTM 10 calculation is dependent upon the peak
plume concentration location along the OTM 10 configuration plane. For the smallest plume size at
a location close to the OP-FTIR instrument and convergence of the measurement paths (peak
concentration location at 40 m), the OTM 10-derived flux values from the simulation was 200%
higher than simulated values. The simulation shows underestimation of results as the 40 m x40 m
plume intersects the OTM plane closer to the scissor lift (up to 40 % underestimation). The OTM 10-
derived flux values from the simulation agrees better with control values as the plume becomes
larger and is more centered on the optical configuration.
When assessing the contribution to overall measurement uncertainty caused by using the 3-beam
measurement approach, several factors must be considered. The general pond emission sources
for this project are relatively large spatially with well-developed plumes (more like the 100 m by 100
m case). The Williams skim pond source would represent a smaller source however it was well-
centered on the OTM 10 plane which decreases the likely hood of the near edge intersections
(highly overestimated or underestimated 40 m by 40 m cases). Some of the inherent uncertainty
discussed in this section is likely also evident (and accounted for) in the assumption of ± 20% single
plane OTM 10 accuracy based on tracer release performance results. It is also noted that over the
course of a 20 minute average measurement cycle, the plume intersection point meanders
somewhat due to wind direction variation leading to an averaging effect. With these factors taken
into account, the added uncertainty fora single plane measurement for this project due to use of the
3-beam approach is estimated to be within ± 20 %.
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Based on this analysis and the preceding combined uncertainty analysis a reasonable estimate of
the overall uncertainty in a single 20 minute OTM flux calculation for this project is estimated to be
within ±40%.
Uncertainty Due to the Variability of Source
As discussed in several sections of this report, significant variability in emissions from the assessed
sources is evident and expressed as the relatively large standard deviation in emission flux results
compared to the average value for the source. Some of this variability is due to uncertainty in the
measurement approach but a significant amount of the variability is believed to be due to changes
in emissions from the source due to changes in a number of emissions controlling variables such as
make-up of the source, variable input load, meteorological conditions driving the emissions, and
changes in process variables to name a few. This level of variability is evident in the standard
deviation of the average results. A limitation of this data set is related to potential lack of sufficient
measurement time to provide a robust estimate of average emissions.
5.4 EPA and ARCADIS Audits and Corrective Actions
Although a Technical Systems Audit (TSA) was not required for this QA Category III project, there
was an attempt to perform one to help support the overall quality of the effort. Unfortunately, the trip
planning and time constraints of the QA auditor was fixed near the planned project start-up at the
Williams facility (August 4th - 6th 2008). Due to a transportation truck break-down enroot to the field
location from the North Carolina EPA facility, the set up of the project was delayed precluding
execution of a thorough audit however significant QA checks were made on August 6, 2008. The
auditor did not find any issues that required corrective actions. An audit report was not generated.
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6. References
Hashmonay, R.A., and M.G. Yost. (1999), Innovative approach for estimating fugitive gaseous
fluxes using computed tomography and remote optical sensing techniques, J. Air Waste Manage.
Assoc., 49, 966-972.
Thoma, E. D., Shores, R. C., Thompson, E. L, Harris, D. B., Thorneloe, S. A., Varma, R.,
Hashmonay, R. A.; Modrak, M. T., Natschke, D. F., Gamble, H.A.. (2005) "Open path tunable diode
laser absorption spectroscopy for acquisition of fugitive emission flux data." J. Air and Waste
Manage. Assoc. 55, 658-668.
U.S. EPA (2004). "ECPB Optical Remote Sensing Facility Manual", U.S. EPA National Risk
Management Research Laboratory, Air Pollution Prevention and Control Division, Emissions
Characterization and Prevention Branch, Contract No. EP-C-04-023, Work Assignment 0-33, April
2004.
U.S. EPA (2006), EPA Test Method (OTM 10), "Optical Remote Sensing for Emission
Characterization from Non-Point Sources." U.S. EPA Technology Transfer Network Emission
Measurement Center, Web Site; http://www.epa.gov/ttn/emc/prelim/otm10.pdf.
U.S. EPA (2007) "Measurement of Total Site Mercury Emissions from a Chlor-alkali Plant Using
Open-Path UV-DOAS", EPA/R-07/077; U.S. Environmental Protection Agency, Office of Research
and Development, Work Assignment No. 2-052, July, 2007a, available at
http://www.epa.gov/ord/NRMRL/pubs/600r07077/600r07077.pdf.
U.S. EPA (2008). "Measurement of Emissions from Produced Water Ponds: Upstream Oil and Gas
Study #1", Category III Quality Assurance Project Plan, Work Assignment No. 4-49, July 2008,
Version 2.0.
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Appendix A: OTM 10 Alkane Mixture Flux Values
A-1
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A-2
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Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
APPENDIX A: . OTM 10 Alkane Mixture Flux Values
This appendix contains single plane OTM 10 VRPM measurement data of alkane mixture (AM)
emissions acquired in this project. These single plane values are combined to provide the total flux
estimate discussed in Section 3. The acquisition description and data quality indicators leading to
selection of valid Individual plane data points are described in the following text and tables. The
appendix contains the following sections:
A-1: Alkane Mixture (AM) Measurement by OP-FTIR
A-2: OTM 10 Flux Measurement Sequence Description
A-3: Acceptable Data Criteria and Emission Flux Correction Factors
A-4: Individual Flux Plane Results
A-1 Alkane Mixture (AM) Measurement by OP-FTIR
To utilize the EPA Method OTM 10 measurement method, the airborne pollutants of interest must
be present at sufficient concentrations to be robustly quantified by the open-path instruments. In
many cases involving petroleum-base fuel mixtures, it is not possible to individually quantify
specific compounds due to the convolved nature of their spectral absorption features or by the lack
of sufficient concentrations to exceed minimum detection levels at standard OTM 10 time
resolutions. For these cases, a special OP-FTIR analysis technique can be employed which
focuses on the combined absorption of a mixture of hydrocarbons by quantifying the infrared
absorbance of the in the C-H stretch infrared vibrational region around 2900 cm"1. This procedure
is called the alkane mixture (AM) calculation since these compounds predominantly contribute the
infrared absorption profile for these sources.
The use of OTM 10 for estimation of emission fluxes requires the conversion of the volume path-
integrated concentrations (VPIC) to mass path-integrated concentrations (MPICs). This conversion
requires an estimate of the mean molecular weight measured gas mixture. The AM procedure
described below provides a means for estimation of the average molecular weight by assuming
that the mixture can be approximated by a combination of C-4, C-5, C-6, C-7, and C-8 alkanes.
This assumption is further discussed later in this section.
It is first noted that the infrared absorption features many hydrocarbon species in the C-H stretch
region are relatively similar. For example, Figure A-1 shows C-4 to C-8 (n-butane to n-octane)
along with several other species present in fuel-base mixtures. For the n-butane to n-octane series,
the similarity is greatest between the components with consecutive carbon numbers (e.g. butane
and pentane) and the similarities decrease for components with greater difference in carbon
numbers (e.g. C-4 and C-8, butane and octane). The similarity in band shapes of these and other
hydrocarbons with significant C-H stretch signal makes it impossible to include all of the
A-3
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Measurement of Emissions from
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October 2009 (Rev. 0.6)
components of the mixture in the classic least squares (CIS) regression fit of measured
absorbance to calibrated reference absorbance spectra to determine the concentration of the
individual compounds.
n-butane
n-pentane
n-hexane
n-heptane
n-octane
2-methylpentane
2,2,4-trimthylpentane
2-methy I heptane
n-decane
3-methylhexane
1-nonene
3CED
2950 2900 2S5
Wavenumber (cm'1)
Figure A-1 . Comparison of the Absorption Bands of Several Species in the C-H Stretch Region
A-4
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Appendix A
Measurement of Emissions from
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October 2009 (Rev. 0.6)
For the AM analysis, the primary region of spectral analysis is 2804.2 to 3001.2 cm"1. This region
fully encumbers the main bands of the alkane mixture. To approximate the mixture, two
representative analytes n-butane and n-octane (highlighted in Figure A-1) are chosen for analysis
and the system is then approximated in terms of these bounding surrogates.
The mean molecular mass of the alkane mixture, Mm*, is estimated as
* f V f Arbitrated \\/f V f Arbitrated
butane butane octane octane /A A \
mix — ^ IM- I )
V (-1 Arbitrated
mix
where Mtatane=58.12 g/mole (molecular mass of butane),
Moctane = 114.23 g/mole (molecular mass of octane),
vCbutaneted and ^tLT* are the butane and octane determinations from the analysis of
the arbitration-chosen region. As explained in the in Appendix E of the QAPP, arbitration
refers to the process of determining concentrations when multiple spectral regions were
utilized to perform the analysis. Due to the low AM signal levels encountered for this project,
only the 2804.2 to 3001.2 cm"1 spectral region was required for analysis.
The mass path-integrated concentration of the alkane mixture, mCmix , is given as
m-A _ L(T, P) • M mix ^v A Arbitrated
Where L(T) is Loschmidt's Number at temperature, 7 and pressure P,
296K P
L(T) = 2.4793jd025 • - • - molecules/m3,
T l-atm
and A is Avogadro's number, 6. 0220X1 023 molecules/mole. The numerical solution is
-5
/' p \
^ = 4.1171XW-5 .M — - — - \vCAm^rated[PPm] (A-2)
T )\\-atm)
A-5
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Appendix A
Measurement of Emissions from
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October 2009 (Rev. 0.6)
The procedure for converting the volume PICs of alkane vapor mixtures from petroleum-base fuels
to mass PIC is summarized by Equations A-1 and A-2. Additional information on this analysis and
associated QA procedures can be found in Appendix E of the Quality Assurance Project Plan
(QAPP) (EPA, 2008), Procedure to Convert OP-FTIR Volume Concentration Determinations of
Alkane Mixture that Originate from Petroleum-Based Fuels to Mass Concentrations.
The central assumption of the AM procedure is that the complex mix of hydrocarbons emitted from
the source can be approximated by the previously described two-component estimation which
utilizes n-butane and n-octane as bounding surrogates. The assumption excludes alkanes with
carbon numbers less than 4 (methane, ethane and propane) as these are not expected to be
significant components of the airborne mixture (for this project) because these species are gases
at standard atmospheric conditions would likely have separated from the liquid prior to the waste
water treatment step. Alkanes with higher carbon numbers than C-8 (nonane, decane, etc.) have
low vapor pressures and therefore are likely to be less prevalent in the airborne mixture. Other
branched chain alkanes, and alkenes can have significant spectral contribution to the analysis
band but are generally present at lower concentrations in the airborne mixture. Aromatic
compounds are present at significant levels in the airborne mixture for this project but have leas
spectral contribution to the 2804.2 to 3001.2 cm"1analysis region.
These assumptions may be more or less valid depending on the exact nature of the source under
evaluation but information can be informed by supplemental sampling such as SUMMA canister
analysis (presented below) and through FTIR spectral analysis. Information regarding this
assumption is present in the first level of OP-FTIR spectral analysis which, through the CIS fitting,
provides an estimate of the quality of spectral match of the hydrocarbon mix to the utilized
bounding reference spectra in addition to information in the fingerprint region. For petroleum-base
fuel mixes there are typically a large number of hydrocarbons which posses similar broad infrared
absorption features in the 2804.2 to 3001.2 cm"1 analysis region but in most cases, these species
are present at lower levels and serve to provide an enhanced baseline to the main constituents
such as octane. Aromatic compounds such as BTEX in particular have little infrared adsorption
features in the primary analysis region and be individually quantified in other spectral regions if
present at high enough concentrations.
A table summarizing the relative spectral contributions of a number of species prevalent in the
SNMOC SUMMA canister analysis for this project is contained in Table A-1. This relative
absorption factor was determined by integrating the area under the absorption curve from 2804.2
cm"1 to 3001.2 cm"1 using quality assured reference spectra or through estimation if spectra were
unavailable. The table was normalized to n-octane.
A-6
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-1. Relative Absorption Factor (AF) of Select Hydrocarbon Species in the 2804.2 cm to
3001.2 cm'1 Spectral Range (values are normalized to n-Octane)
Species
Methane
Ethane
Propane
n-Butane
n-Pentane
n-Hexane
n-Heptane
n-Octane
n-Nonane2
n-Decane2
Isobutane
Isopentane
Cyclopentane2
2-Methylpentane
3-Methylpentane
2,2-Dimethylbutane
2,3-Dimethylbutane1
Cyclohexane
Methylcyclopentane3
2-Methylhexane2
3-Methylhexane2
AF
0.032
0.244
0.425
0.553
0.680
0.779
0.888
1.000
1.093
1.195
0.536
0.637
0.715
0.753
0.737
0.729
0.729
0.853
0.766
0.868
0.868
Species
2,4-Dimethylpentane2
2,3-Dimethylpentane2
Methylcyclohexane3
2-Methylheptane2
3-Methylheptane2
2,2,4-Trimethylpentane
2,2,3-Trimethylpentane1
2,3,4-Trimethylpentane1
1-Heptene
1-Nonene2
Benzene
Toluene
m-Xylene
o-Xylene
p-Xylene
Ethylbenzene
1 ,3,5-Trimethylbenzene
1 ,2,3-Trimethylbenzene1
1 ,2,4-Trimethylbenzene1
o-Ethyltoluene
m-Ethyltoluene1
AF
0.715
0.715
0.766
0.971
0.971
0.924
0.924
0.924
0.596
0.613
0.004
0.093
0.192
0.204
0.212
0.230
0.296
0.296
0.296
0.323
0.323
1 estimate based on AF value of close isomer
2estimate based on uncalibrated spectra (NIST Database)
3 estimate not based on spectra (significant uncertainty)
Calculated values from DOE/PNNL Infrared Spectral Library R9, 2005
A-7
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
As described in Section 3.5, the summa canister SNMOC analysis provides an approximate
distribution of hydrocarbons with the Williams analysis being the most robust due to good signal
levels. Figure A-2 and A-3 estimate the contribution of the various species to the AM analysis
region by presenting the SNMOC analysis (Figure A-2) and the same distribution multiplied by the
AF value for each compound from Table A-1. It can be seen in Figure A-3 that the contribution to
the AM band from benzene, toluene, and m-, o-, p-xylenes are limited even though they are preset
at high levels in the airborne mixture. Note that there is significant uncertainty in estimate regarding
methylcyclohexane due to lack of reference spectra.
500 -
400 -
300 -
200 -
100 -
_jjlO
-
PI
_
,ji
n
-
n
-
n I I n n n n n I I
-
-
i-i
•n
Figure A-2. Summa Canister SNMOC Analysis Showing Compound Distribution (Section 3.5)
A-8
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
.Q
C
O
ts
m
o 200 -
|
O
•o
c
s
nil
,-C^* 0^" ^ -rf^" 4^"
^y\8>V»
1-1
-
-
i-i
1
-
I-,
1
1-1
n n n n n n nil
Figure A-3. Estimation of Contribution to AM Band, SNMOC Result Multiplied by AF
For purpose of comparison with OP-FTIR AM data, a summation of the 42 compounds modified by
the AF factor was produced for each canister and this constitutes the SNMOC AM estimation
utilized in Section 3.5 of the report. The molecular weight estimates from the OP-FTIR processing
were very close to the octane values. For the time periods of downwind canister sampling, the
average MWs by OP-FTIR AM method was 111 amu and 113 amu for the Williams and EnCana
facilities respectively. The average MW using the distribution of A-2 was 103 amu and taking into
account the AF as in Figure A-3, the average MW was 108 amu. Figure A-4 illustrates the latter by
plotting the normalized concentration vs. molecular weight.
A-9
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
25
20
15
I
o
o
Jj 10
ns
o
O
8
Q
o
o
00
20 30 40 50 60 70 80 90 100
Molecular Weight (amu)
110
120
130
140
150
160
Figure A-4. Normalized Concentration vs. Molecular Weight for the Distribution of Figure A-3
A-2 OTM10 Measurement Sequence Description
The 3-beam OTM 10 setup used for this project is described in Section 2 of this report. The OP-
FTIR system acquires data on a single measurement path using a 30 second integration time
starting with the lowest path (path 1) and then sequentially moving to the middle path (path 2) and
highest path (path 3) completing the flux plan. The OP-FITR then rotates 90° to produce the
measurement on the adjacent plan (paths 4,5,6) before returning to the 1,2,3 plane and repeating.
There are two OP-FTIRs utilized each producing two of the four measured planes. The OP-FITRs
are labeled (E) for EPA unit and (A) for the ARCADIS unit leading two a unique identifier for each
of the four paths (E123, E456, A123, A456)
As a standard OTM procedure to reduce analytical noise, each flux calculation presented consists
of an average of five consecutive flux plane measurements for an individual measurement plane.
A-10
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
To create this five-cycle value, individual beam PIC data for each path is averaged and processed
as a single VRPM calculation using the average wind data for the measurement time period. A
default value of five cycles is used however some data points contain a lower number of averages
due to consecutive point data availability.
The OP-FTIR data and meteorological data had a measurement averaging time of 30 seconds. A
single plane measurement requires approximately two minutes to complete. This includes a 30
second integration time for OP-FTIR (and meteorological data) each of the three measurement
paths and time for the scanner to reposition the OP-FTIR to a new path. Since each OP-FTIR
measured two separate three-beam flux planes in an interwoven fashion (e.g., A123 then A456,
then A123 etc.), an approximate 20 minute time period is required to complete a five-cycle
individual plane measurement. The data is displayed as a moving average. In this procedure, a
subsequent five-cycle average contains four of the five values form the preceding average,
excluding the earliest cycle and replacing it with the most recent cycle.
The fundamental units of emission flux produced by the EPA OTM 10, VRPM method are grams
per second. In order to calculate the total alkane mixture (AM) flux values for a given plane, the
FluxCalc VRPM software calculated the average AM molecular weight of the three beams as an
input variable.
A-3 Acceptable Data Criteria and Emission Flux Correction Factors
The total AM mass emission flux was calculated when (1) the criteria for valid target compound
detection and OP-FTIR Data Quality Indicators (DQIs) were met; and (2) the vertical capture
criteria were met. When these criteria were met, all total flux calculations are reported. In some
instances, failure to meet these criteria does not necessarily indicate an inaccurate flux calculation.
When such exceptions are made, the flux calculations are reported and are flagged accordingly.
Only data which met all of the following criteria were deemed acceptable and included in the data
presented:
1. Prevailing wind speed > 1 m/s but < 8 m/s. Sections 3.2. and 3.3 present the summary tables
of calculated flux values for each VRPM plane during each day of sampling at the Williams
Rulison and EnCana Benzel facilities, respectively. Flux values for data collected during
periods where the prevailing wind speed was < 1 m/s or> 8 m/s were not calculated and are
shaded as follows in those tables:
Medium orange.
A-11
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
2. Assessment of valid target compound detection
Prior to inputting the concentration data into the flux calculation software, the average
concentration along each beam path was compared to the instrument minimum detection limit
(MDL). For this project, the general definition of the term "minimum detection limit (MDL)" for
OP-FTIR data is based around the uncertainty in the quantification of the measured species as
determined by standard classical least squares (CIS) spectral analysis procedures. The
standard error (a) in the regression fit of the measured spectrum to the calibrated reference
spectrum forms a basis for the defined MDL. Some multiple of a is used a as threshold for
quantification depending on the type of analysis used in this project. For example, for single-
path time averaging method (TAM) estimation of trace VOC concentrations, we define an MDL
threshold of 6a. This means that the determined concentration must exceed six times the
standard error in the CLS to be counted. For AM concentrations associated with the five cycle
rolling average AM flux determination, the average measured concentration for all three optical
paths must exceed eight times the average standard error for the paths in order for the flux
plane ensemble concentration to be judged valid allowing an AM flux calculation to be
executed.
If this measured concentration was not above the MDL (meaning that the ratio of the average
concentration to the MDL of the OP-FTIR instrument was < 1), the flux was not calculated and
are shaded as follows in those tables:
Dark
orange
In the vast majority of cases, the reason for "below MDL" determinations is due to lack of sufficient
AM concentration, usually occurring on the upwind background measurement planes (no source
signal present). In these instances there is negligible AM flux through the planes and values of
zero flux have been assigned to these entries to aid in calculation of the four plane estimate. The
moving average flux values presented in Tables 3-1 through 3-8 of the report include periods of
zero flux values in the averaging. The values in these tables were used to calculate the average
AM flux value from each source presented in Table 4-1. Additional calculations were performed to
evaluate the average AM flux value from each source after removing the zero flux values from the
calculations. The results showed that the average AM flux value from each source did not change
significantly when zero flux values were not included in the calculations.
A-12
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
3. Vertical capture criteria
There are two instances in which vertical integration of the concentration was limited to the
height of the scissor jack (i.e., no extrapolation occurred above the scissor jack). If the average
concentration on the top beam (beams # 3 or# 6, depending on the VRPM plane) was higher
than the average concentration of the middle beam (beams # 2 or # 5) - indicating that the
plume was not being captured by the plane - the concentrations along those two top beams
were switched to allow the software to calculate the flux. These flux values are in green font in
the summary tables of calculated flux values in Sections 3.2 and 3.3.
The second case where integration of the concentration was limited to the height of the scissor
jack occurred when all three beam concentrations were very similar. This indicated that the
plume was homogeneous and very diluted vertically. These flux values in the tables in
Sections 3.2 and 3.3 are in red font.
For the remaining data, the vertical gradient was extrapolated to a height where the extrapolated
concentration was zero (as described in EPA OTM 10).
4. The CCF > 0.80.
The Concordance Correlation Factor (CCF) is used in the VRPM method to represent the level of
fit for the reconstruction in the path-integrated domain (predicted versus measured PAC). However,
a poor CCF value (CCF< 0.80) at the end of the fitting procedure does not necessarily indicate an
inaccurate flux calculation. Therefore, hydrocarbon flux values were reported when then
corresponding CCF value of the reconstruction was greater than 0.80 and are shaded as follows in
the summary tables of calculated flux values in Sections 3.2. and 3.3:
Light orange.
A-4: Individual Flux Plane Results
This section presents individual plane AM flux estimates for the test campaigns conducted at the
Williams Rulison facility (Tables A-2 through A-17) and the EnCana Benzel facility (Tables from
August 12-15. Each table presents the time (hr:min:sec), AM flux value (g/sec), wind direction
(w.r.t. N), rotated wind direction (w.r.t VRPM plane), wind speed (m/s), and Concordance
Correlation Factor (CCF). As described in Section A-3, AM flux values were calculated for data
which met a series of quality control criteria pertaining to valid target compound detection and
vertical plume capture, and instrument DQIs. That section also described the flags that were added
to flux values that did not meet the optimal data criteria, but that could still prove useful in
understanding the source and magnitude of hydrocarbon emissions being generated from these
sites.
A-13
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-2. Summary Data Table of VRPM Plane A123 for Augusts, 2008 at the Williams Rulison
Facility
Time
15:15:02
15:20:48
15:25:35
15:30:23
15:35:06
15:39:47
15:44:31
15:49:18
15:54:02
15:58:50
16:03:32
16:08:11
16:12:52
16:17:30
16:22:11
16:26:52
16:31:30
Flux
[g/sec]
-0.01
-0.01
-0.01
-0.01
-0.03
-0.04
-0.04
-0.02
-0.01
Wind Direction
[degrees]
156.2
150.6
150.0
155.1
170.6
173.6
176.3
170.1
167.5
162.9
169.4
177.1
203.5
224.7
224.8
214.9
223.2
Rotated Wind
Direction
[degrees]
97.2
91.6
91.0
96.1
111.6
114.6
117.3
111.1
108.5
103.9
110.4
118.1
144.5
165.7
165.8
155.9
164.2
Wind
Speed
2.0
2.0
1.9
1.9
1.8
2.3
2.4
2.4
2.4
2.3
2.1
2.0
1.7
1.6
1.8
1.6
1.4
CCF
0.97
0.84
0.91
0.59
0.86
0.41
0.40
0.00
0.44
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-14
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-3. Summary Data Table of VRPM Plane A456 for Augusts, 2008 at the Williams Rulison
Facility
Time
15:18:25
15:23:09
15:27:57
15:32:42
15:37:26
15:42:09
15:46:54
15:51:40
15:56:26
16:01:10
16:05:51
16:10:32
16:15:11
16:19:54
16:24:33
16:29:13
16:33:47
Flux
fe/sec]
0.03
0.03
0.04
0.02
0.02
0.02
Wind Direction
[degrees]
152.5
147.9
152.4
164.4
173.9
176.8
172.3
170.2
164.1
166.0
172.2
187.6
215.8
224.3
221.5
216.4
201.6
Rotated Wind
Direction
[degrees]
29.5
24.9
29.4
41.4
50.9
53.8
49.3
47.2
41.1
43.0
49.2
64.6
92.8
101.3
98.5
93.4
78.6
Wind
Speed
2.0
1.9
1.9
1.6
2.1
2.4
2.3
2.5
2.4
2.2
1.9
1.8
1.6
1.7
1.6
1.4
1.2
CCF
1.00
0.85
0.81
0.99
0.63
0.00
0.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-15
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-4. Summary Data Table of VRPM Plane E123 for August 6,2008 at the Williams Rulison
Facility
Time
14:37:26
14:41:54
14:46:23
14:50:53
14:55:21
14:59:49
15:04:18
15:08:51
15:13:23
15:17:51
15:22:22
15:26:54
15:31:24
15:35:56
15:40:26
15:44:53
15:49:21
15:53:48
15:58:15
16:02:43
16:07:09
16:11:36
16:16:02
16:20:31
16:24:59
16:29:28
Flux
[g/sec]
-0.01
-0.01
-0.02
-0.02
-0.02
-0.02
-0.01
-0.01
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
198.2
183.4
183.4
185.4
199.0
173.5
170.3
166.9
158.9
152.7
148.6
150.0
163.9
172.7
173.6
176.3
169.7
165.6
162.8
166.2
176.9
188.9
221.1
225.7
221.5
216.4
Rotated Wind
Direction
[degrees]
236.2
221.4
221.4
223.4
237.0
211.5
208.3
204.9
196.9
190.7
186.6
188.0
201.9
210.7
211.6
214.3
207.7
203.6
200.8
204.2
214.9
226.9
259.1
263.7
259.5
254.4
Wind
Speed
2.5
2.7
2.7
2.4
2.0
1.6
1.8
1.6
2.0
2.1
1.9
1.9
1.7
1.9
2.3
2.5
2.4
2.5
2.3
2.1
2.0
1.7
1.5
1.7
1.6
1.4
CCF
0.00
0.00
0.00
1.00
1.00
1.00
1.00
1.00
0.97
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.97
0.87
0.93
0.94
0.62
0.02
A-16
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-5. Summary Data Table of VRPM Plane E456 for August 6,2008 at the Williams Rulison
Facility
Time
14:39:41
14:44:10
14:48:38
14:53:08
14:57:35
15:02:04
15:06:36
15:11:06
15:15:38
15:20:08
15:24:37
15:29:09
15:33:42
15:38:12
15:42:39
15:47:08
15:51:34
15:56:02
16:00:30
16:04:58
16:09:24
16:13:51
16:18:18
16:22:46
16:27:15
16:31:44
Flux
[g/sec]
0.18
0.13
0.09
0.07
0.10
0.09
0.21
0.32
0.36
0.06
0.05
0.07
0.08
0.13
0.07
0.05
Wind Direction
[degrees]
189.0
183.4
177.5
192.0
178.9
172.0
168.2
160.1
153.9
151.8
148.3
153.9
164.5
176.7
177.0
171.3
168.9
165.0
164.7
170.2
181.8
209.7
225.8
223.8
215.1
223.6
Rotated Wind
Direction
[degrees]
311.0
305.4
299.5
314.0
300.9
294.0
290.2
282.1
275.9
273.8
270.3
275.9
286.5
298.7
299.0
293.3
290.9
287.0
286.7
292.2
303.8
331.7
347.8
345.8
337.1
345.6
Wind
Speed
2.5
2.7
2.7
2.2
1.6
1.7
1.7
2.0
2.1
2.0
1.8
1.9
1.7
2.2
2.4
2.3
2.5
2.4
2.3
2.0
1.8
1.9
1.7
1.7
1.5
1.4
CCF
0.99
0.98
0.99
0.97
0.73
0.83
0.00
0.00
0.00
0.00
0.13
0.08
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.92
0.97
0.95
0.61
0.81
0.84
0.95
A-17
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-6. Summary Data Table of VRPM Plane A123 for August?, 2008 at the Williams Rulison
Facility
Time
11:13:19
11:18:12
11:23:01
11:27:54
11:32:45
11:37:37
11:42:29
11:47:26
11:52:26
11:57:23
12:02:15
12:07:14
12:12:13
12:17:03
12:21:55
12:26:47
12:31:44
12:36:37
12:41:22
12:46:18
12:51:14
12:56:07
13:01:01
13:05:58
13:10:55
13:15:53
13:20:50
13:25:48
13:30:46
Flux
fe/sec]
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
91.9
100.1
100.6
98.5
107.3
101.0
99.5
90.9
92.9
91.7
82.4
83.0
111.9
150.4
163.7
159.6
167.9
184.3
181.6
180.5
192.4
168.8
159.6
163.9
152.0
154.1
161.4
166.0
179.1
Rotated Wind
Direction
[degrees]
32.9
41.1
41.6
39.5
48.3
42.0
40.5
31.9
33.9
32.7
23.4
24.0
52.9
91.4
104.7
100.6
108.9
125.3
122.6
121.5
133.4
109.8
100.6
104.9
93.0
95.1
102.4
107.0
120.1
Wind
Speed
0.4
0.7
0.6
0.9
1.1
1.2
1.2
1.1
1.2
1.3
0.8
0.6
0.6
0.5
0.7
1.1
1.2
1.0
1.0
1.0
1.0
1.0
1.1
0.9
0.8
0.8
0.9
1.0
1.1
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.75
0.00
-0.01
-0.01
0.00
0.00
0.00
0.88
0.90
0.98
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-18
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Time
13:35:44
13:40:45
13:45:47
13:50:48
13:55:49
14:00:53
14:05:56
14:11:01
14:16:10
14:21:20
14:26:26
14:31:27
14:36:29
14:41:35
14:46:33
14:51:31
14:56:29
15:01:29
15:06:22
15:11:19
15:16:21
15:21:19
15:26:17
15:31:14
15:36:12
15:41:12
15:46:06
15:51:02
15:55:57
16:00:52
Flux
[g/sec]
0.01
0.02
0.03
0.08
0.19
0.17
0.13
0.13
0.10
0.06
0.13
0.33
0.42
0.45
0.31
0.14
0.07
0.05
0.11
0.28
0.31
0.47
Wind Direction
[degrees]
170.2
184.0
196.5
192.6
197.7
194.5
177.0
135.8
126.7
114.1
105.1
102.4
83.3
64.0
0.8
0.8
353.6
345.0
18.9
18.3
19.5
21.3
7.6
351.3
348.5
347.7
25.1
54.3
67.8
68.4
Rotated Wind
Direction
[degrees]
111.2
125.0
137.5
133.6
138.7
135.5
118.0
76.8
67.7
55.1
46.1
43.4
24.3
5.0
301.8
301.8
294.6
286.0
319.9
319.3
320.5
322.3
308.6
292.3
289.5
288.7
326.1
355.3
8.8
9.4
Wind
Speed
1.4
1.4
1.5
1.3
1.0
1.1
1.1
1.2
2.0
2.5
2.7
2.7
1.6
1.3
1.7
1.7
2.0
1.6
0.9
1.1
1.1
1.2
1.2
1.2
1.2
1.2
1.1
1.5
2.0
2.2
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.43
0.76
0.72
0.51
0.99
1.00
1.00
1.00
0.99
0.06
0.00
0.00
-0.01
0.01
0.00
0.95
0.93
0.51
0.19
0.11
-0.01
-0.01
A-19
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Time
16:05:47
16:10:42
16:15:36
16:20:31
16:25:26
16:30:20
16:35:16
16:40:13
16:45:06
16:50:02
16:54:57
16:59:55
17:04:50
17:09:43
17:14:38
17:19:34
17:24:33
17:29:28
Flux
[g/sec]
0.57
0.65
0.61
0.66
0.56
0.60
0.45
0.35
0.22
0.21
0.37
0.38
0.26
0.19
0.18
0.00
0.00
0.14
Wind Direction
[degrees]
65.9
46.8
29.7
27.5
39.7
52.4
65.2
63.9
64.2
61.7
61.5
55.3
54.0
42.4
30.1
25.5
39.9
68.1
Rotated Wind
Direction
[degrees]
6.9
347.8
330.7
328.5
340.7
353.4
6.2
4.9
5.2
2.7
2.5
356.3
355.0
343.4
331.1
326.5
340.9
9.1
Wind
Speed
2.2
1.9
1.8
1.9
2.1
2.2
2.5
2.5
2.5
2.3
2.3
2.1
1.7
1.4
1.0
0.8
0.8
1.1
CCF
0.98
0.74
0.92
0.93
0.94
0.99
0.97
1.00
1.00
0.93
0.92
0.78
1.00
0.53
0.00
0.00
0.00
0.00
A-20
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-7. Summary Data Table of VRPM Plane A456 for August?, 2008 at the Williams Rulison
Facility
Time
11:15:44
11:20:35
11:25:26
11:30:19
11:35:09
11:40:03
11:44:57
11:49:58
11:54:56
11:59:48
12:04:41
12:09:39
12:14:41
12:19:28
12:24:21
12:29:16
12:34:08
12:38:56
12:43:51
12:48:43
12:53:39
12:58:32
13:03:27
13:08:27
13:13:26
13:18:24
13:23:21
13:28:15
13:33:12
Flux
[g/sec]
0.00
0.00
0.00
0.12
0.19
0.18
0.21
0.11
0.22
0.08
0.00
0.00
0.00
0.00
0.03
0.02
0.01
0.02
0.02
0.01
0.09
0.08
0.07
0.00
0.00
Wind Direction
[degrees]
105.2
99.6
99.9
105.3
102.8
100.9
92.8
89.1
92.8
88.6
75.0
87.4
134.8
157.9
162.5
157.6
179.6
195.0
178.2
186.0
182.4
161.9
161.1
157.4
149.3
154.6
165.8
171.8
173.7
Rotated Wind
Direction
[degrees]
342.2
336.6
336.9
342.3
339.8
337.9
329.8
326.1
329.8
325.6
312.0
324.4
11.8
34.9
39.5
34.6
56.6
72.0
55.2
63.0
59.4
38.9
38.1
34.4
26.3
31.6
42.8
48.8
50.7
Wind
Speed
0.5
0.8
0.7
1.1
1.1
1.2
1.3
1.0
1.4
1.1
0.7
0.6
0.4
0.6
0.9
1.2
1.0
0.8
0.9
1.0
0.9
1.1
1.0
0.9
0.7
0.8
1.0
1.1
1.2
CCF
0.00
0.00
0.00
0.54
0.03
0.04
0.05
0.40
0.04
0.99
0.00
0.00
0.00
0.00
0.00
0.28
0.26
0.26
0.69
0.67
0.99
0.42
0.42
0.18
0.00
0.00
0.00
0.00
0.00
A-21
-------
Time
13:38:14
13:43:14
13:48:20
13:53:21
13:58:22
14:03:25
14:08:26
14:13:35
14:18:44
14:23:51
14:28:54
14:33:54
14:39:00
14:44:01
14:49:00
14:54:00
14:58:56
15:03:56
15:08:50
15:13:50
15:18:51
15:23:47
15:28:43
15:33:41
15:38:39
15:43:38
15:48:33
15:53:30
15:58:23
16:03:19
Flux
[g/sec]
0.29
1.06
2.79
3.08
4.00
2.44
1.03
0.19
-0.21
-0.02
-0.05
-0.01
0.00
0.00
-0.02
-0.05
0.08
0.53
0.62
0.73
Wind Direction
[degrees]
176.8
191.9
197.0
193.5
194.4
190.2
148.6
127.5
120.7
107.0
103.4
97.0
76.1
45.9
0.8
0.8
345.3
356.7
16.8
20.1
19.4
13.1
357.2
345.0
349.9
1.5
37.9
65.2
69.1
71.5
Rotated Wind
Direction
[degrees]
53.8
68.9
74.0
70.5
71.4
67.2
25.6
4.5
357.7
344.0
340.4
334.0
313.1
282.9
237.8
237.8
222.3
233.7
253.8
257.1
256.4
250.1
234.2
222.0
226.9
238.5
274.9
302.2
306.1
308.5
Wind
Speed
1.4
1.4
1.5
1.1
1.1
1.1
1.1
1.6
2.5
2.6
2.7
2.2
1.5
1.2
1.7
1.7
2.1
1.3
1.1
1.1
1.2
1.2
1.2
1.2
1.2
1.1
1.2
1.8
2.1
2.4
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.61
0.50
0.67
0.63
0.82
0.94
0.99
0.92
0.96
0.86
0.00
0.03
0.04
0.04
0.04
0.03
0.00
0.00
0.00
0.02
0.04
0.93
1.00
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-22
-------
Time
16:08:13
16:13:08
16:18:03
16:22:58
16:27:52
16:32:48
16:37:45
16:42:38
16:47:34
16:52:27
16:57:24
17:02:21
17:07:14
17:12:10
17:17:04
17:22:03
17:27:01
17:31:56
Flux
[g/sec]
0.19
0.01
0.00
0.03
0.15
0.43
0.89
0.68
0.57
0.42
0.21
0.07
0.01
0.01
-0.02
0.00
0.20
1.10
Wind Direction
[degrees]
57.8
36.8
26.7
31.9
45.5
59.4
65.2
64.9
63.6
58.4
55.9
55.9
50.6
36.8
16.7
33.6
46.6
83.4
Rotated Wind
Direction
[degrees]
294.8
273.8
263.7
268.9
282.5
296.4
302.2
301.9
300.6
295.4
292.9
292.9
287.6
273.8
253.7
270.6
283.6
320.4
Wind
Speed
2.0
1.8
1.9
1.9
2.1
2.4
2.5
2.5
2.2
2.3
2.2
2.0
1.5
1.2
1.0
0.8
0.9
1.5
CCF
0.96
1.00
0.60
0.10
0.02
0.03
0.30
0.07
0.11
0.73
0.93
0.89
0.86
0.69
0.20
0.00
0.96
0.98
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-23
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-8. Summary Data Table of VRPM Plane E123 for August 7,2008 at the Williams Rulison
Facility
Time
10:32:12
10:36:37
10:41:02
10:45:26
10:49:51
10:54:19
10:58:45
11:03:12
11:07:37
11:12:04
11:16:31
11:20:58
11:25:27
11:29:54
11:34:20
11:38:48
11:43:19
11:47:47
11:52:15
11:56:42
12:01:14
12:05:40
12:10:09
12:14:35
12:19:02
12:23:30
12:27:56
12:32:22
12:36:51
Flux
[g/sec]
-0.03
-0.02
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
-0.02
Wind Direction
[degrees]
79.9
70.4
68.1
94.4
46.1
24.3
34.1
56.1
45.4
74.7
101.7
96.9
103.8
106.3
103.2
101.7
98.4
89.6
90.1
92.6
88.2
82.4
84.9
127.9
156.9
164.0
160.5
163.6
187.1
Rotated Wind
Direction
[degrees]
117.9
108.4
106.1
132.4
84.1
62.3
72.1
94.1
83.4
112.7
139.7
134.9
141.8
144.3
141.2
139.7
136.4
127.6
128.1
130.6
126.2
120.4
122.9
165.9
194.9
202.0
198.5
201.6
225.1
Wind
Speed
1.7
1.4
0.9
0.6
0.3
0.6
0.5
0.5
0.6
0.3
0.5
0.8
0.7
1.2
1.0
1.1
1.3
1.0
1.2
1.3
1.0
0.7
0.6
0.4
0.6
0.9
1.2
1.1
0.9
CCF
0.94
0.74
0.85
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.99
0.00
0.00
0.00
0.00
0.74
0.00
0.00
0.00
A-24
-------
Time
12:41:17
12:45:46
12:50:12
12:54:43
12:59:10
13:03:38
13:08:08
13:12:37
13:17:08
14:07:51
14:13:18
14:17:48
14:22:17
14:26:48
14:31:17
14:35:47
14:40:16
14:44:48
14:49:20
14:53:53
14:58:24
15:02:56
15:07:27
15:12:12
15:16:32
15:21:05
15:25:36
15:30:06
15:34:36
15:39:11
Flux
[g/sec]
0.00
0.00
-0.04
-0.20
0.47
0.88
1.13
2.16
0.88
0.22
0.18
0.12
0.06
0.16
0.26
0.30
0.35
Wind Direction
[degrees]
188.7
180.1
191.5
172.7
159.8
161.6
154.0
147.1
156.2
153.3
135.0
123.7
110.9
103.3
103.3
92.4
72.5
4.8
0.8
357.9
345.4
347.8
18.9
17.9
19.6
22.1
10.8
354.6
341.4
346.8
Rotated Wind
Direction
[degrees]
226.7
218.1
229.5
210.7
197.8
199.6
192.0
185.1
194.2
191.3
173.0
161.7
148.9
141.3
141.3
130.4
110.5
42.8
38.8
35.9
23.4
25.8
56.9
55.9
57.6
60.1
48.8
32.6
19.4
24.8
Wind
Speed
0.7
1.0
1.1
1.0
1.1
1.0
0.9
0.8
0.7
1.0
1.6
2.5
3.0
2.8
2.6
1.9
1.4
1.6
1.7
1.8
2.4
1.4
0.9
1.2
1.1
1.2
1.2
1.1
1.2
1.2
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.02
0.05
0.13
0.10
0.07
0.41
0.06
0.04
0.03
0.66
1.00
0.92
0.86
0.97
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-25
-------
Time
15:43:42
15:48:11
15:52:41
15:57:10
16:01:42
16:06:13
16:10:42
16:15:12
16:19:45
16:24:15
16:28:48
16:33:12
16:37:43
16:42:13
16:46:44
16:51:09
16:55:38
17:00:09
17:04:41
17:09:11
17:13:42
17:18:13
17:22:47
17:27:16
17:31:45
Flux
[g/sec]
0.28
0.05
-0.07
-0.11
-0.12
-0.06
0.00
0.09
0.09
0.06
0.01
-0.02
-0.01
-0.01
-0.02
-0.01
-0.01
-0.01
-0.03
0.02
0.06
0.00
0.00
-0.01
-0.05
Wind Direction
[degrees]
355.3
36.7
63.2
70.5
72.7
64.8
44.6
28.0
25.3
31.7
47.9
61.0
67.0
64.7
62.9
58.9
59.9
56.4
55.2
42.4
31.6
14.6
36.6
51.7
83.5
Rotated Wind
Direction
[degrees]
33.3
74.7
101.2
108.5
110.7
102.8
82.6
66.0
63.3
69.7
85.9
99.0
105.0
102.7
100.9
96.9
97.9
94.4
93.2
80.4
69.6
52.6
74.6
89.7
121.5
Wind
Speed
1.1
1.3
1.7
2.1
2.5
2.1
1.9
1.9
1.9
2.0
2.2
2.4
2.6
2.5
2.3
2.3
2.2
2.1
1.8
1.4
1.1
0.8
0.8
1.0
1.4
CCF
1.00
0.99
0.99
0.19
0.97
0.24
0.94
0.99
0.99
1.00
1.00
1.00
0.58
0.87
0.06
0.02
0.02
0.75
0.25
1.00
0.99
0.00
0.00
0.89
0.98
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-26
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-9. Summary Data Table of VRPM Plane E456 for August 7,2008 at the Williams Rulison
Facility
Time
10:34:25
10:38:50
10:43:15
10:47:38
10:52:06
10:56:31
11:00:59
11:05:25
11:09:52
11:14:17
11:18:46
11:23:14
11:27:41
11:32:08
11:36:36
11:41:04
11:45:33
11:50:03
11:54:29
11:59:00
12:03:28
12:07:55
12:12:23
12:16:49
12:21:18
12:25:42
12:30:11
12:34:40
12:39:05
Flux
[g/sec]
-0.11
-0.50
-0.32
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.18
-0.19
-0.19
-0.27
-0.20
-0.28
-0.47
-0.44
0.00
0.00
0.00
0.00
0.04
0.29
0.27
0.31
Wind Direction
[degrees]
78.3
69.1
69.5
129.7
25.2
33.2
49.1
49.2
45.3
100.1
98.7
101.0
99.8
107.1
100.0
99.1
90.7
89.7
92.9
88.2
78.9
78.6
108.0
153.3
163.6
160.8
161.2
178.6
196.3
Rotated Wind
Direction
[degrees]
200.3
191.1
191.5
251.7
147.2
155.2
171.1
171.2
167.3
222.1
220.7
223.0
221.8
229.1
222.0
221.1
212.7
211.7
214.9
210.2
200.9
200.6
230.0
275.3
285.6
282.8
283.2
300.6
318.3
Wind
Speed
1.6
1.2
0.9
0.4
0.6
0.5
0.4
0.5
0.5
0.4
0.8
0.6
0.9
1.2
1.1
1.2
1.3
1.0
1.3
1.1
0.8
0.6
0.5
0.5
0.7
1.0
1.3
1.0
0.8
CCF
0.84
0.56
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.89
0.89
0.96
0.96
0.88
0.97
1.00
0.97
0.00
0.00
0.00
0.00
0.99
0.08
0.14
0.10
A-27
-------
Time
12:43:33
12:48:48
12:52:27
12:56:56
13:01:23
13:05:55
13:10:24
13:14:53
14:11:05
14:15:33
14:20:02
14:24:34
14:29:04
14:33:34
14:38:03
14:42:34
14:47:05
14:51:38
14:56:09
15:00:41
15:05:12
15:09:45
15:14:14
15:18:50
15:23:22
15:27:52
15:32:22
15:36:56
15:41:27
15:46:01
Flux
[g/sec]
0.34
0.40
0.16
1.11
1.51
1.45
0.00
0.00
-0.07
-0.33
-0.66
-1.62
-2.02
-1.77
-1.61
-1.92
-1.48
-1.43
-1.65
-1.00
-1.25
-1.14
-1.11
-0.94
-0.80
-0.62
-1.02
-1.14
-1.32
-1.38
Wind Direction
[degrees]
180.7
186.2
188.8
167.6
161.6
163.1
145.1
158.9
136.9
126.7
116.3
104.4
102.4
100.0
80.2
62.8
0.8
0.8
351.3
337.8
18.0
16.8
20.1
19.2
16.8
4.3
347.6
345.9
343.7
20.8
Rotated Wind
Direction
[degrees]
302.7
308.2
310.8
289.6
283.6
285.1
267.1
280.9
258.9
248.7
238.3
226.4
224.4
222.0
202.2
184.8
122.8
122.8
113.3
99.8
140.0
138.8
142.1
141.2
138.8
126.3
109.6
107.9
105.7
142.8
Wind
Speed
0.9
1.0
1.0
1.0
1.2
0.9
0.9
0.7
1.1
2.1
2.6
2.9
2.7
2.4
1.5
1.3
1.7
1.7
2.1
2.2
0.9
1.1
1.1
1.2
1.3
1.2
1.2
1.2
1.2
1.2
CCF
0.88
1.00
0.97
0.24
0.41
0.32
0.00
0.00
0.99
1.00
1.00
0.99
1.00
1.00
1.00
1.00
0.99
0.98
0.98
1.00
1.00
1.00
1.00
0.99
1.00
1.00
0.99
0.87
0.55
0.69
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-28
-------
Time
15:50:27
15:54:57
15:59:27
16:04:01
16:08:29
16:13:01
16:17:30
16:22:01
16:26:33
16:31:01
16:35:28
16:40:01
16:44:30
16:48:55
16:53:24
16:57:54
17:02:26
17:06:57
17:11:29
17:16:01
17:20:30
17:25:03
17:29:31
17:34:02
Flux
[g/sec]
-1.72
-0.58
-0.52
-0.23
-0.23
-0.24
-0.24
-0.20
-0.20
-0.34
-0.32
-0.30
-0.30
-0.35
-0.32
-0.48
-0.95
-2.18
-2.54
-1.92
0.00
0.00
-1.65
-1.17
Wind Direction
[degrees]
53.9
68.5
71.8
71.4
55.5
37.8
23.2
29.8
41.1
55.0
66.4
66.2
65.4
61.8
57.0
57.9
57.1
52.5
37.1
14.6
26.4
39.8
74.3
89.5
Rotated Wind
Direction
[degrees]
175.9
190.5
193.8
193.4
177.5
159.8
145.2
151.8
163.1
177.0
188.4
188.2
187.4
183.8
179.0
179.9
179.1
174.5
159.1
136.6
148.4
161.8
196.3
211.5
Wind
Speed
1.5
2.0
2.3
2.3
2.0
1.8
1.9
1.9
2.1
2.2
2.6
2.6
2.5
2.2
2.3
2.2
2.1
1.6
1.2
1.0
0.7
0.8
1.1
1.8
CCF
0.95
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.90
0.85
0.94
0.93
0.97
1.00
0.99
0.95
0.03
0.01
0.01
0.00
0.00
0.96
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-29
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-10. Summary Data Table of VRPM Plane A123 for Augusts, 2008 at the Williams Rulison
Facility
Time
10:17:11
10:23:21
10:28:32
10:33:39
10:38:48
10:43:56
10:49:05
10:54:12
10:59:20
11:04:28
11:09:37
11:14:46
11:19:54
11:25:03
11:30:12
11:35:24
11:40:32
11:45:38
11:50:48
11:55:59
12:01:08
12:06:16
12:11:24
12:16:30
12:21:39
12:26:48
12:31:55
12:37:04
12:42:11
12:47:09
12:52:18
12:57:28
13:02:38
Flux
[g/sec]
0.01
0.00
0.00
0.01
0.02
0.02
0.03
0.00
0.00
0.00
0.00
-0.01
Wind Direction
[degrees]
123.8
137.3
146.4
150.1
131.0
104.7
91.4
81.4
78.2
93.0
118.8
139.6
150.3
163.9
190.3
203.6
226.2
240.6
241.6
242.8
249.0
246.7
247.0
248.3
247.3
244.3
245.4
243.5
233.4
236.5
233.3
235.2
232.4
Rotated Wind
Direction
[degrees]
64.8
78.3
87.4
91.1
72.0
45.7
32.4
22.4
19.2
34.0
59.8
80.6
91.3
104.9
131.3
144.6
167.2
181.6
182.6
183.8
190.0
187.7
188.0
189.3
188.3
185.3
186.4
184.5
174.4
177.5
174.3
176.2
173.4
Wind
Speed
1.2
1.4
1.4
1.2
1.1
1.1
1.1
1.1
1.0
0.7
0.8
1.4
1.5
1.6
1.5
1.9
2.1
2.6
2.5
2.6
2.4
2.6
2.9
3.1
3.4
3.6
3.6
3.4
3.2
3.1
3.4
3.3
3.2
CCF
0.96
-0.01
0.00
0.00
0.32
0.04
0.00
0.00
0.41
0.00
0.00
0.89
0.97
0.44
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-30
-------
Time
13:07:37
13:12:46
13:17:54
13:23:03
13:28:14
13:33:24
13:38:35
13:43:44
13:48:54
13:54:03
13:59:16
14:04:26
14:09:36
14:14:45
14:19:56
14:25:05
14:30:16
14:35:27
14:40:37
14:45:46
14:50:57
14:56:06
15:01:14
15:06:25
15:11:36
15:16:48
15:21:56
15:27:06
15:32:17
16:18:48
16:23:54
16:29:03
16:34:14
Flux
[g/sec]
0.00
0.04
0.13
0.54
Wind Direction
[degrees]
229.2
227.3
225.1
232.1
232.1
232.7
231.6
234.1
234.1
236.2
236.2
237.4
226.4
223.0
232.5
206.8
201.2
188.0
154.0
143.6
149.1
153.8
161.9
174.2
180.4
196.8
214.9
208.7
150.1
126.4
107.8
107.8
107.8
Rotated Wind
Direction
[degrees]
170.2
168.3
166.1
173.1
173.1
173.7
172.6
175.1
175.1
177.2
177.2
178.4
167.4
164.0
173.5
147.8
142.2
129.0
95.0
84.6
90.1
94.8
102.9
115.2
121.4
137.8
155.9
149.7
91.1
67.4
48.8
48.8
48.8
Wind
Speed
3.4
3.3
3.1
3.5
3.5
3.3
3.3
3.3
3.2
3.2
3.0
3.1
2.2
1.7
1.9
1.8
1.8
1.9
2.4
2.7
2.0
1.9
1.9
1.6
1.4
1.5
1.3
1.5
2.2
3.2
3.7
3.7
3.7
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.88
0.63
0.99
-0.01
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-31
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-11. Summary Data Table of VRPM Plane A456 for Augusts, 2008 at the Williams Rulison
Facility
Time
10:20:44
10:25:54
10:31:04
10:36:12
10:41:20
10:46:29
10:51:38
10:56:44
11:01:52
11:07:01
11:12:11
11:17:19
11:22:27
11:27:36
11:32:45
11:37:55
11:43:05
11:48:12
11:53:21
11:58:32
12:03:42
12:08:48
12:13:55
12:19:04
12:24:12
12:29:21
12:34:28
12:39:36
12:44:35
12:49:42
12:54:51
13:00:01
13:05:09
Flux
[g/sec]
0.05
0.05
0.05
0.04
0.06
0.09
0.10
0.12
0.00
0.00
0.00
Wind Direction
[degrees]
134.6
143.7
149.2
147.2
111.3
98.1
81.4
87.1
75.3
108.3
120.1
146.7
150.2
176.4
194.1
217.1
232.3
242.2
239.9
243.9
247.8
248.0
250.2
249.9
245.2
245.5
245.3
237.3
234.2
236.7
233.5
230.4
231.7
Rotated Wind
Direction
[degrees]
11.6
20.7
26.2
24.2
348.3
335.1
318.4
324.1
312.3
345.3
357.1
23.7
27.2
53.4
71.1
94.1
109.3
119.2
116.9
120.9
124.8
125.0
127.2
126.9
122.2
122.5
122.3
114.3
111.2
113.7
110.5
107.4
108.7
Wind
Speed
1.3
1.3
1.4
1.1
1.1
1.2
1.1
1.2
0.9
0.8
0.9
1.5
1.7
1.6
1.7
2.0
2.4
2.6
2.4
2.6
2.5
2.5
3.0
3.2
3.6
3.5
3.5
3.2
3.1
3.1
3.3
3.3
3.3
CCF
0.82
0.77
0.48
0.79
0.13
0.08
0.05
0.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-32
-------
Time
13:10:11
13:15:19
13:20:27
13:25:37
13:30:47
13:35:58
13:41:08
13:46:17
13:51:27
13:56:38
14:01:49
14:06:59
14:12:10
14:17:18
14:22:30
14:27:39
14:32:50
14:38:00
14:43:10
14:48:19
14:53:30
14:58:39
15:03:50
15:08:58
15:14:10
15:19:20
15:24:29
15:29:40
16:21:20
16:26:27
16:31:37
Flux
[g/sec]
0.36
1.32
3.59
Wind Direction
[degrees]
227.4
228.2
220.0
232.4
233.5
232.6
232.5
231.7
236.9
235.4
237.7
236.1
225.7
225.5
226.3
206.4
198.9
169.4
146.0
150.9
148.9
157.3
170.0
191.4
187.1
198.3
215.2
196.1
126.4
107.8
107.8
Rotated Wind
Direction
[degrees]
104.4
105.2
97.0
109.4
110.5
109.6
109.5
108.7
113.9
112.4
114.7
113.1
102.7
102.5
103.3
83.4
75.9
46.4
23.0
27.9
25.9
34.3
47.0
68.4
64.1
75.3
92.2
73.1
3.4
344.8
344.8
Wind
Speed
3.3
3.2
3.2
3.7
3.4
3.4
3.4
3.2
3.3
3.1
3.0
2.9
2.0
1.8
1.8
1.7
2.0
2.0
2.6
2.1
2.0
2.0
1.6
1.4
1.5
1.5
1.3
1.4
3.2
3.7
3.7
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.91
0.13
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-33
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-12. Summary Data Table of VRPM Plane E123 for August 8,2008 at the Williams Rulison
Facility
Time
10:35:02
10:39:29
10:43:55
10:48:21
10:52:45
10:57:10
11:01:37
11:06:02
11:10:28
11:14:55
11:19:22
11:23:48
11:28:14
12:04:50
12:10:11
12:14:39
12:19:04
12:23:24
12:27:50
12:32:13
12:36:36
12:41:03
12:45:28
12:49:53
12:54:14
12:58:36
13:03:02
13:07:27
13:11:49
13:16:14
13:20:38
13:25:05
13:29:30
Flux
[g/sec]
0.00
0.00
0.00
-0.01
-0.01
-0.01
-0.01
0.03
0.03
0.03
0.02
n fy?
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
Wind Direction
[degrees]
154.6
128.4
106.1
91.3
81.5
73.0
73.9
99.9
126.1
137.0
143.9
153.3
179.7
248.8
248.2
247.2
247.0
247.9
245.5
245.1
243.5
233.3
231.6
234.9
230.5
234.2
233.0
228.7
225.5
227.4
219.9
235.4
233.7
Rotated Wind
Direction
[degrees]
192.6
166.4
144.1
129.3
119.5
111.0
111.9
137.9
164.1
175.0
181.9
191.3
217.7
286.8
286.2
285.2
285.0
285.9
283.5
283.1
281.5
271.3
269.6
272.9
268.5
272.2
271.0
266.7
263.5
265.4
257.9
273.4
271.7
Wind
Speed
1.0
1.1
1.2
1.1
1.2
1.3
0.8
0.7
0.9
1.4
1.6
1.7
1.5
2.6
2.6
3.0
3.2
3.5
3.7
3.6
3.4
3.1
2.8
3.2
3.5
3.5
3.2
3.2
3.3
3.3
3.3
3.6
3.3
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
1.00
0.99
0.98
0.84
0.83
0.92
0.74
0.04
0.00
0.00
0.00
0.00
0.00
0.99
0.94
1.00
1.00
1.00
1.00
1.00
0.00
0.04
0.10
A-34
-------
Time
13:33:59
13:38:23
13:42:48
13:47:13
13:51:36
13:56:02
14:00:28
14:04:51
14:09:11
14:13:37
14:18:04
14:22:28
14:26:48
14:31:14
14:40:00
14:44:30
14:48:51
14:53:15
14:57:42
15:06:33
15:10:58
15:15:24
15:19:49
15:24:15
15:28:39
16:21:30
16:25:54
16:30:20
Flux
[g/sec]
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.00
0.00
0.00
0.00
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
Wind Direction
[degrees]
231.3
233.0
234.3
232.7
238.1
233.8
237.5
240.2
229.1
213.6
228.0
227.5
206.9
209.9
165.5
150.5
149.3
151.8
152.9
180.8
187.6
196.8
216.0
210.6
191.0
126.4
107.8
107.8
Rotated Wind
Direction
[degrees]
269.3
271.0
272.3
270.7
276.1
271.8
275.5
278.2
267.1
251.6
266.0
265.5
244.9
247.9
203.5
188.5
187.3
189.8
190.9
218.8
225.6
234.8
254.0
248.6
229.0
164.4
145.8
145.8
Wind
Speed
3.3
3.5
3.3
3.1
3.2
3.1
3.0
3.3
2.6
1.4
1.5
1.9
1.8
2.1
2.1
2.4
2.2
2.0
2.0
1.6
1.4
1.5
1.4
1.4
1.4
3.2
3.7
3.7
CCF
0.12
0.91
0.98
1.00
1.00
1.00
0.99
0.99
1.00
1.00
0.95
0.96
0.02
0.02
0.00
0.00
0.00
0.00
0.00
1.00
0.48
0.46
0.41
0.41
0.18
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-35
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-13. Summary Data Table of VRPM Plane E456 for August 8,2008 at the Williams Rulison
Facility
Time
10:37:16
10:41:42
10:46:09
10:50:34
10:54:59
10:59:25
11:03:50
11:08:17
11:12:44
11:17:08
11:21:40
11:26:02
11:30:28
12:08:02
12:12:27
12:16:52
12:21:15
12:25:37
12:30:03
12:34:26
12:38:52
12:43:15
12:47:43
12:52:04
12:56:26
13:00:51
13:05:16
13:09:39
13:14:04
Flux
[g/sec]
0.02
-0.10
-0.16
-0.21
-0.38
-0.34
0.00
0.00
-0.02
0.02
0.03
0.05
0.06
0.03
0.04
0.05
0.07
0.10
0.09
0.08
0.05
0.02
0.02
0.03
0.03
0.13
0.14
0.14
0.12
Wind Direction
[degrees]
145.1
111.1
100.5
86.5
79.8
73.6
81.1
120.4
134.1
144.9
149.4
163.7
186.5
250.7
250.0
249.4
248.2
244.9
244.5
246.3
243.6
232.3
235.0
234.4
233.5
239.0
233.0
225.1
227.1
Rotated Wind
Direction
[degrees]
267.1
233.1
222.5
208.5
201.8
195.6
203.1
242.4
256.1
266.9
271.4
285.7
308.5
12.7
12.0
11.4
10.2
6.9
6.5
8.3
5.6
354.3
357.0
356.4
355.5
1.0
355.0
347.1
349.1
Wind
Speed
1.0
1.2
1.2
1.1
1.3
1.1
0.7
0.8
1.0
1.5
1.6
1.6
1.6
2.5
2.8
3.1
3.4
3.7
3.7
3.6
3.3
2.9
3.0
3.2
3.4
3.5
3.3
3.3
3.1
CCF
0.96
0.96
0.98
0.98
0.98
0.97
0.00
0.00
0.70
0.92
1.00
0.97
1.00
0.87
0.84
0.60
0.83
0.94
0.85
0.91
1.00
0.99
0.98
0.96
0.86
0.35
1.00
1.00
0.97
A-36
-------
Time
13:18:26
13:22:54
13:27:19
13:31:45
13:36:14
13:40:36
13:45:03
13:49:27
13:53:53
13:58:15
14:02:41
14:07:03
14:11:27
14:15:52
14:20:18
14:24:38
14:29:01
15:04:21
15:08:47
15:13:09
15:17:38
15:22:03
15:26:27
15:30:52
16:19:18
16:23:44
16:28:09
16:32:34
Flux
[g/sec]
0.15
0.06
0.04
0.05
0.06
0.06
0.06
0.10
0.12
0.20
0.21
0.22
0.14
0.14
0.11
0.09
0.07
0.10
0.09
0.09
0.09
0.22
0.20
0.42
-0.43
-0.74
-2.41
-2.41
Wind Direction
[degrees]
222.5
228.7
233.1
233.1
233.4
237.3
224.3
236.1
237.5
234.9
237.6
234.4
220.6
221.7
230.0
219.5
209.5
167.2
179.0
187.1
198.3
215.2
211.7
182.4
124.8
126.4
107.8
107.8
Rotated Wind
Direction
[degrees]
344.5
350.7
355.1
355.1
355.4
359.3
346.3
358.1
359.5
356.9
359.6
356.4
342.6
343.7
352.0
341.5
331.5
289.2
301.0
309.1
320.3
337.2
333.7
304.4
246.8
248.4
229.8
229.8
Wind
Speed
3.4
3.6
3.4
3.4
3.4
3.6
3.0
3.1
3.4
2.9
3.1
2.9
1.8
1.5
1.8
1.8
1.9
1.8
1.5
1.6
1.5
1.3
1.2
1.5
2.9
3.2
3.7
3.7
CCF
0.99
0.93
0.83
0.95
0.97
0.99
0.97
0.89
0.93
0.97
0.98
0.82
0.67
0.79
0.87
0.95
0.98
0.81
0.66
0.94
0.90
0.90
0.98
0.98
0.80
0.97
1.00
0.98
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-37
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-14. Summary Data Table of VRPM Plane A123 for August 9, 2008 at the Williams Rulison
Facility
Time
11:45:33
11:50:33
11:55:23
12:00:21
12:05:21
12:10:20
12:15:19
12:20:17
12:25:15
12:30:15
12:35:15
12:40:15
12:45:14
12:50:12
12:55:11
13:00:11
13:05:13
13:10:14
13:15:08
13:20:08
13:25:12
13:30:11
13:35:12
13:40:07
13:45:06
13:50:09
13:55:10
14:00:10
14:05:12
Flux
[g/sec]
0.27
0.23
0.16
0.14
0.09
0.06
0.06
0.07
0.04
0.03
0.04
0.02
0.01
0.01
0.02
0.01
0.01
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
65.9
69.8
79.4
84.4
93.2
97.1
89.4
81.3
85.8
71.8
79.9
94.2
108.8
119.0
106.9
103.0
95.5
79.0
108.3
135.1
153.1
188.7
174.2
229.5
197.4
160.3
171.9
180.8
156.1
Rotated Wind
Direction
[degrees]
6.9
10.8
20.4
25.4
34.2
38.1
30.4
22.3
26.8
12.8
20.9
35.2
49.8
60.0
47.9
44.0
36.5
20.0
49.3
76.1
94.1
129.7
115.2
170.5
138.4
101.3
112.9
121.8
97.1
Wind
Speed
2.3
2.0
2.0
2.1
2.1
2.2
2.0
1.8
1.5
1.0
1.1
1.0
0.9
1.3
1.3
1.4
1.3
1.0
0.8
1.0
0.5
0.6
0.4
0.4
0.4
1.1
0.9
1.4
1.7
CCF
1.00
0.98
0.89
1.00
0.79
1.00
0.93
0.91
0.93
0.96
0.99
0.98
0.99
0.97
0.97
0.99
0.99
0.99
0.00
0.96
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
A-38
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Time
14:10:13
14:15:14
14:20:15
14:25:16
14:30:18
14:35:17
14:40:19
14:45:14
14:50:13
Flux
[g/sec]
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
172.9
169.6
158.9
159.9
155.4
149.0
146.7
144.3
143.5
Rotated Wind
Direction
[degrees]
113.9
110.6
99.9
100.9
96.4
90.0
87.7
85.3
84.5
Wind
Speed
1.9
2.2
2.8
2.9
2.9
3.0
3.1
3.0
2.8
CCF
0.99
0.00
0.00
0.00
0.00
0.00
0.98
1.00
1.00
A-39
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-15. Summary Data Table of VRPM Plane A456 for August 9, 2008 at the Williams Rulison
Facility
Time
11:48:03
11:52:54
11:57:52
12:02:52
12:07:49
12:12:50
12:17:48
12:22:46
12:27:46
12:32:44
12:37:43
12:42:43
12:47:43
12:52:42
12:57:41
13:02:42
13:07:44
13:12:43
13:17:36
13:22:38
13:27:41
13:32:42
13:37:37
13:42:38
13:47:37
13:52:40
13:57:41
14:02:42
14:07:42
Flux
[g/sec]
0.25
0.23
0.44
0.38
0.42
0.42
0.31
0.34
0.19
0.06
0.04
0.04
0.08
0.16
0.18
0.13
0.11
0.00
0.04
0.00
0.00
0.00
0.00
0.00
0.00
0.03
0.02
0.02
0.03
Wind Direction
[degrees]
65.8
73.7
81.0
89.5
95.9
95.3
82.7
85.3
79.3
73.5
89.4
93.5
116.8
114.6
104.2
99.3
86.7
81.7
122.8
144.8
168.0
180.4
110.2
254.3
167.4
155.6
175.6
162.2
167.0
Rotated Wind
Direction
[degrees]
302.8
310.7
318.0
326.5
332.9
332.3
319.7
322.3
316.3
310.5
326.4
330.5
353.8
351.6
341.2
336.3
323.7
318.7
359.8
21.8
45.0
57.4
347.2
131.3
44.4
32.6
52.6
39.2
44.0
Wind
Speed
2.1
2.0
2.0
2.2
2.3
2.1
1.9
1.7
1.4
0.9
1.0
0.8
1.2
1.4
1.3
1.3
1.2
0.9
1.0
0.8
0.5
0.6
0.2
0.3
0.8
1.0
1.0
1.5
1.7
CCF
0.69
0.60
0.25
0.10
0.03
0.06
0.06
0.39
0.36
0.71
0.95
0.96
0.73
0.58
0.67
0.97
0.82
0.00
0.70
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.02
0.39
0.56
A-40
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Time
14:12:43
14:17:44
14:22:44
14:27:46
14:32:48
14:37:48
14:42:50
14:47:44
14:52:42
Flux
[g/sec]
0.02
0.03
0.07
0.05
0.28
0.25
0.30
0.27
Wind Direction
[degrees]
175.9
161.2
158.5
161.9
151.1
147.0
146.5
143.1
148.5
Rotated Wind
Direction
[degrees]
52.9
38.2
35.5
38.9
28.1
24.0
23.5
20.1
25.5
Wind
Speed
2.0
2.5
2.8
3.0
2.8
3.1
3.0
2.9
3.2
CCF
0.00
0.96
0.99
0.65
0.94
0.97
0.75
0.07
0.35
A-41
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-16. Summary Data Table of VRPM Plane E123 for August 9,2008 at the Williams Rulison
Facility
Time
10:14:24
10:19:53
10:24:20
10:28:49
10:33:16
10:37:44
10:42:11
10:46:41
10:51:10
10:55:36
11:00:05
11:04:32
11:09:02
11:13:32
11:18:01
11:22:29
11:26:58
11:31:27
11:35:56
11:40:24
11:44:52
11:49:19
11:53:47
11:58:14
12:02:43
12:07:10
12:11:39
12:16:07
12:20:38
Flux
[g/sec]
-0.03
-0.04
-0.03
-0.03
-0.03
-0.03
-0.02
-0.01
-0.01
-0.02
-0.02
-0.02
Wind Direction
[degrees]
85.1
85.2
84.2
84.3
86.4
86.7
93.1
96.2
99.9
96.2
95.3
90.3
82.6
86.3
89.6
94.4
90.4
85.7
79.9
68.7
67.9
66.6
76.5
83.4
87.2
100.1
96.8
88.8
80.4
Rotated Wind
Direction
[degrees]
123.1
123.2
122.2
122.3
124.4
124.7
131.1
134.2
137.9
134.2
133.3
128.3
120.6
124.3
127.6
132.4
128.4
123.7
117.9
106.7
105.9
104.6
114.5
121.4
125.2
138.1
134.8
126.8
118.4
Wind
Speed
2.9
2.9
2.7
2.5
2.4
2.3
2.3
2.2
2.1
2.0
1.9
1.7
1.8
1.6
1.7
1.7
1.8
2.1
2.1
2.2
2.3
2.1
2.1
2.0
2.2
2.3
2.3
2.0
1.7
CCF
0.82
0.67
0.19
0.05
0.05
0.03
0.00
0.00
0.00
0.00
0.00
0.90
0.72
0.00
0.00
0.00
0.00
0.00
0.36
0.32
0.19
0.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-42
-------
Time
12:25:09
12:29:38
12:34:06
12:38:33
12:43:01
12:47:31
12:52:01
12:56:25
13:00:54
13:05:21
13:09:46
13:40:36
13:44:58
13:49:23
13:53:44
13:58:06
14:02:32
14:06:57
14:11:20
14:15:42
14:20:08
14:24:33
14:28:55
14:33:18
14:37:41
14:42:07
14:46:27
14:50:51
Flux
[g/sec]
-0.05
-0.04
-0.06
-0.04
-0.05
-0.01
-0.04
0.00
0.00
-0.12
-0.11
-0.07
-0.10
-0.02
-0.02
-0.01
Wind Direction
[degrees]
79.6
79.4
77.6
96.7
88.2
112.6
121.6
108.5
104.0
93.6
67.8
269.7
209.4
153.7
157.9
186.0
166.9
158.9
173.7
169.6
158.4
161.2
157.0
149.5
147.3
145.2
141.6
144.4
Rotated Wind
Direction
[degrees]
117.6
117.4
115.6
134.7
126.2
150.6
159.6
146.5
142.0
131.6
105.8
307.7
247.4
191.7
195.9
224.0
204.9
196.9
211.7
207.6
196.4
199.2
195.0
187.5
185.3
183.2
179.6
182.4
Wind
Speed
1.6
1.1
1.0
1.1
0.7
1.0
1.5
1.3
1.4
1.3
1.2
0.3
0.4
1.1
1.0
1.2
1.4
1.7
2.0
2.2
2.6
2.8
3.2
3.0
3.0
2.9
2.9
2.9
CCF
0.00
0.78
0.87
0.87
0.88
0.89
0.99
0.00
0.00
0.98
0.00
0.00
0.00
1.00
0.42
0.77
0.79
0.95
0.96
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-43
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-17. Summary Data Table of VRPM Plane E456 for August 9,2008 at the Williams Rulison
Facility
Time
10:17:39
10:22:07
10:26:35
10:31:04
10:35:30
10:40:01
10:44:27
10:48:56
10:53:24
10:57:52
11:02:18
11:06:50
11:11:19
11:15:47
11:20:16
11:24:45
11:29:13
11:33:43
11:38:11
11:42:39
11:47:07
11:51:34
11:56:02
12:00:30
12:04:59
12:09:27
12:13:55
12:18:24
12:22:54
Flux
[g/sec]
-0.24
-0.26
-0.21
-0.16
-0.22
-0.21
-0.22
-0.24
-0.26
-0.18
-0.19
-0.18
-0.24
-0.24
-0.35
-0.40
-0.45
-0.46
-0.46
-0.38
-0.33
-0.30
-0.29
-0.22
-0.29
-0.51
-0.37
-0.51
-0.80
Wind Direction
[degrees]
87.0
82.7
83.6
84.9
88.6
88.2
93.2
97.3
99.0
97.4
94.8
88.3
82.9
89.5
97.1
95.8
88.7
78.2
76.1
69.8
66.8
67.2
75.9
86.6
95.1
98.2
93.7
79.3
81.6
Rotated Wind
Direction
[degrees]
209.0
204.7
205.6
206.9
210.6
210.2
215.2
219.3
221.0
219.4
216.8
210.3
204.9
211.5
219.1
217.8
210.7
200.2
198.1
191.8
188.8
189.2
197.9
208.6
217.1
220.2
215.7
201.3
203.6
Wind
Speed
2.9
2.8
2.6
2.4
2.4
2.2
2.3
2.1
2.1
1.9
1.7
1.8
1.6
1.7
1.7
1.8
1.9
2.0
2.1
2.3
2.1
2.0
2.0
2.2
2.1
2.4
2.0
1.8
1.7
CCF
1.00
1.00
1.00
1.00
0.99
0.99
0.99
1.00
0.99
0.97
0.97
0.97
0.99
0.93
0.97
0.98
0.98
1.00
1.00
0.99
0.99
1.00
1.00
0.98
0.98
1.00
0.96
0.96
1.00
A-44
-------
Time
12:27:25
12:31:53
12:36:19
12:40:49
12:45:19
12:49:45
12:54:12
12:58:41
13:03:09
13:07:32
13:42:50
13:47:12
13:51:34
13:55:57
14:00:21
14:04:47
14:09:11
14:13:33
14:17:55
14:22:21
14:26:42
14:31:09
14:35:30
14:39:56
14:44:17
14:48:41
14:53:04
Flux
[g/sec]
-0.71
-0.79
-0.89
-0.79
-0.74
-0.71
-0.56
-0.64
-0.59
-0.46
0.00
0.00
0.02
0.06
0.10
0.07
0.11
0.10
0.09
0.06
0.10
0.05
0.01
0.00
-0.06
-0.13
-0.02
Wind Direction
[degrees]
81.8
70.9
85.5
95.5
95.2
119.8
114.5
104.6
101.1
77.2
234.8
170.6
152.2
166.7
175.8
160.6
171.7
174.4
162.4
158.9
162.4
152.8
148.8
147.9
144.8
141.9
147.2
Rotated Wind
Direction
[degrees]
203.8
192.9
207.5
217.5
217.2
241.8
236.5
226.6
223.1
199.2
356.8
292.6
274.2
288.7
297.8
282.6
293.7
296.4
284.4
280.9
284.4
274.8
270.8
269.9
266.8
263.9
269.2
Wind
Speed
1.4
1.0
1.0
1.0
0.7
1.3
1.4
1.3
1.5
1.2
0.4
0.9
1.0
1.0
1.2
1.8
1.9
2.0
2.6
2.8
3.1
3.1
3.0
3.0
2.9
3.0
3.3
CCF
1.00
0.99
0.94
0.98
0.94
0.90
0.69
0.64
0.96
0.95
0.00
0.00
0.91
1.00
0.99
1.00
1.00
0.98
0.99
1.00
1.00
1.00
0.99
0.98
0.98
0.94
0.94
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-45
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Calculated Flux Values for the EnCana Benzel Facility
Tables A-18 through A-33 present the summary tables of calculated flux values for each VRPM
plane during each day of sampling at the EnCana Benzel facility. These values were calculated as
described in Sections 2.3 and 3.1. Each table presents the time, flux value, wind direction, rotated
wind direction, wind speed, and CCF (used to represent the level of fit for the reconstruction in the
path-integrated domain, i.e., predicted versus measured path-averaged concentration). As
described in Section 3.1.1, flux values were calculated for data which met a series of quality control
criteria pertaining to horizontal and vertical plume capture and instrument DQIs. That section also
described the flags that were added to flux values that did not meet the optimal data criteria, but
that could still prove useful in understanding the source and magnitude of hydrocarbon emissions
being generated from these sites. The input files used to calculate the AM (total alkanes)
concentration values can be found in Appendix A.
A-46
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-18. Summary Data Table of VRPM Plane A123 for August 12, 2008 at the EnCana Benzel Facility
Time
12:11:21
12:16:44
12:21:10
12:25:31
12:29:52
12:34:15
12:38:38
12:42:57
12:47:21
12:51:43
12:56:06
13:00:28
13:04:52
13:09:15
13:13:41
13:18:05
13:22:29
13:26:54
13:31:36
13:36:11
13:40:54
13:45:23
13:50:04
13:54:43
14:00:00
15:23:59
15:29:21
15:33:42
15:46:48
15:51:10
15:55:32
15:59:52
16:04:17
Flux
[g/sec]
0.07
0.06
0.06
0.05
0.04
0.01
0.01
0.01
0.01
0.01
0.03
0.03
0.04
0.02
0.07
0.06
Wind Direction
[degrees]
49.8
51.8
49.1
39.5
36.8
19.7
14.0
11.2
5.8
337.0
336.8
339.6
333.0
303.1
289.0
316.9
328.1
327.6
346.2
354.1
356.7
344.2
337.0
322.6
311.6
1.4
349.7
5.1
78.6
26.4
26.0
17.4
333.7
Rotated Wind
Direction
[degrees]
345.8
347.8
345.1
335.5
332.8
315.7
310.0
307.2
301.8
273.0
272.8
275.6
269.0
239.1
225.0
252.9
264.1
263.6
282.2
290.1
292.7
280.2
273.0
258.6
247.6
297.4
285.7
301.1
14.6
322.4
322.0
313.4
269.7
Wind
Speed
1.8
2.0
1.9
2.0
2.0
2.1
2.3
2.4
2.2
2.3
2.1
2.1
2.1
2.0
2.1
2.1
2.7
2.9
3.8
3.8
3.1
2.6
2.4
2.0
1.7
1.5
1.8
2.5
0.5
2.1
1.4
1.8
1.1
CCF
0.93
0.94
0.78
0.14
1.00
0.99
1.00
0.98
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.95
0.96
0.59
1.00
0.13
0.77
0.72
0.95
A-47
-------
Time
16:08:38
16:12:59
16:17:19
16:21:41
16:26:00
16:30:20
16:34:40
16:39:01
16:43:22
16:47:41
16:52:01
16:56:21
17:00:43
17:05:06
17:09:29
17:13:50
17:18:11
17:22:35
17:26:59
17:31:23
17:35:43
17:40:06
17:44:29
17:48:52
17:53:13
17:57:35
18:01:56
18:06:19
18:10:40
Flux
[g/sec]
-0.01
-0.01
-0.01
0.00
0.07
0.14
0.12
0.15
0.13
0.11
0.11
0.17
0.11
0.06
0.03
0.05
0.03
0.02
0.06
0.13
0.08
0.20
0.21
0.17
0.11
0.10
0.08
0.04
0.07
Wind Direction
[degrees]
283.6
282.8
288.8
309.2
352.2
13.4
17.6
20.0
24.8
28.2
22.6
15.3
11.3
350.4
342.4
346.5
350.9
5.7
10.9
14.1
16.2
17.1
18.0
21.6
22.9
11.5
6.5
358.8
9.8
Rotated Wind
Direction
[degrees]
219.6
218.8
224.8
245.2
288.2
309.4
313.6
316.0
320.8
324.2
318.6
311.3
307.3
286.4
278.4
282.5
286.9
301.7
306.9
310.1
312.2
313.1
314.0
317.6
318.9
307.5
302.5
294.8
305.8
Wind
Speed
1.3
1.6
1.5
1.4
2.0
2.4
2.4
2.6
2.1
1.9
1.8
1.5
1.3
1.5
1.7
2.0
2.1
2.1
2.6
2.7
2.7
2.8
2.8
2.6
2.4
2.5
2.1
1.4
1.4
CCF
0.57
0.64
0.58
0.64
0.99
0.99
1.00
0.98
0.99
0.92
0.03
0.02
0.02
0.02
0.01
0.03
0.47
0.56
0.84
0.96
0.94
0.99
0.99
0.99
0.95
0.97
0.99
0.98
0.98
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-48
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-19. Summary Data Table of VRPM Plane A456 for August 12, 2008 at the EnCana Benzel Facility
Time
12:14:31
12:18:57
12:23:20
12:27:41
12:32:03
12:36:25
12:40:49
12:45:10
12:49:31
12:53:55
12:58:17
13:02:41
13:07:04
13:11:29
13:15:52
13:20:17
13:24:41
13:29:23
13:33:54
13:38:42
13:43:12
13:47:36
13:52:27
13:57:44
14:02:17
15:27:10
15:31:31
15:35:52
15:49:01
15:53:21
15:57:42
16:02:03
16:06:28
Flux
[g/sec]
0.01
0.02
0.03
0.06
0.07
0.08
0.07
0.06
0.08
0.08
0.08
0.07
0.06
0.06
0.07
0.08
0.07
0.06
0.04
0.04
0.03
Wind Direction
[degrees]
50.9
50.0
47.4
39.2
25.5
15.3
13.2
5.8
348.6
335.5
339.8
339.1
300.0
285.1
302.1
320.4
328.8
332.0
351.0
354.1
351.7
338.8
327.3
316.1
308.1
349.9
10.5
5.1
30.6
26.0
15.9
359.2
302.8
Rotated Wind
Direction
[degrees]
85.9
85.0
82.4
74.2
60.5
50.3
48.2
40.8
23.6
10.5
14.8
14.1
335.0
320.1
337.1
355.4
3.8
7.0
26.0
29.1
26.7
13.8
2.3
351.1
343.1
24.9
45.5
40.1
65.6
61.0
50.9
34.2
337.8
Wind
Speed
2.1
1.9
1.9
2.1
2.0
2.3
2.3
2.3
2.5
2.1
2.1
2.1
2.1
2.1
2.0
2.6
3.0
3.0
3.9
3.7
2.9
2.5
2.2
1.9
1.6
1.8
2.4
2.5
1.4
1.7
1.7
1.4
1.1
CCF
1.00
1.00
0.94
0.79
0.88
0.96
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.94
0.99
0.94
0.94
0.94
1.00
1.00
1.00
A-49
-------
Time
16:10:49
16:15:09
16:19:30
16:23:49
16:28:10
16:32:29
16:36:49
16:41:12
16:45:30
16:49:50
16:54:11
16:58:32
17:02:53
17:07:16
17:11:39
17:16:00
17:20:22
17:24:46
17:29:11
17:33:32
17:37:54
17:42:16
17:46:40
17:51:02
17:55:24
17:59:45
18:04:07
18:08:29
Flux
[g/sec]
0.04
0.04
0.06
0.08
0.11
0.08
0.07
0.06
0.07
0.10
0.17
0.25
0.16
0.22
0.33
0.31
0.31
0.32
0.23
0.13
0.06
0.08
0.06
0.04
0.07
0.09
0.10
0.07
Wind Direction
[degrees]
277.4
292.5
291.2
333.2
2.5
15.7
18.3
20.5
27.6
21.2
21.5
13.0
359.3
347.6
344.0
350.1
354.3
10.1
15.7
11.8
18.6
15.9
21.7
21.9
16.7
8.5
4.5
2.1
Rotated Wind
Direction
[degrees]
312.4
327.5
326.2
8.2
37.5
50.7
53.3
55.5
62.6
56.2
56.5
48.0
34.3
22.6
19.0
25.1
29.3
45.1
50.7
46.8
53.6
50.9
56.7
56.9
51.7
43.5
39.5
37.1
Wind
Speed
1.6
1.6
1.5
1.6
2.3
2.4
2.6
2.4
2.0
1.9
1.8
1.4
1.4
1.6
1.9
2.1
2.1
2.3
2.8
2.6
2.7
2.9
2.7
2.4
2.4
2.3
1.7
1.2
CCF
0.99
0.99
1.00
1.00
0.99
0.99
1.00
1.00
0.85
1.00
0.40
0.92
0.88
0.99
1.00
1.00
0.94
0.99
0.98
0.98
1.00
1.00
1.00
0.89
0.97
1.00
1.00
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-50
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-20. Summary Data Table of VRPM Plane E123 for August 12, 2008 at the EnCana Benzel Facility
Time
11:16:41
11:22:10
11:26:39
11:31:12
11:35:51
11:40:19
11:44:46
11:49:23
11:54:02
11:58:28
12:02:53
12:07:22
12:11:48
12:16:14
12:20:39
12:25:05
12:29:29
12:33:54
12:38:20
12:42:47
12:47:12
12:51:36
12:55:59
13:00:29
13:04:57
13:09:17
13:13:45
13:18:09
13:22:36
13:27:01
13:31:24
13:35:48
13:40:12
Flux
[g/sec]
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.03
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.03
-0.02
-0.02
-0.03
-0.02
-0.02
0.00
0.01
0.00
-0.01
-0.01
-0.03
-0.03
-0.03
Wind Direction
[degrees]
50.4
47.9
44.7
43.4
24.0
12.7
13.4
14.4
25.5
25.2
29.7
35.9
47.0
51.0
49.1
41.3
36.6
19.7
14.0
11.4
5.8
339.9
336.8
339.6
333.0
304.1
292.6
316.9
328.5
327.6
344.7
353.8
356.2
Rotated Wind
Direction
[degrees]
232.4
229.9
226.7
225.4
206.0
194.7
195.4
196.4
207.5
207.2
211.7
217.9
229.0
233.0
231.1
223.3
218.6
201.7
196.0
193.4
187.8
161.9
158.8
161.6
155.0
126.1
114.6
138.9
150.5
149.6
166.7
175.8
178.2
Wind
Speed
1.6
1.8
1.9
2.1
2.0
2.2
2.9
2.8
2.1
2.1
2.1
2.0
1.8
2.0
1.9
2.0
2.0
2.1
2.3
2.4
2.2
2.3
2.1
2.1
2.1
2.1
2.1
2.1
2.8
2.9
3.7
3.8
3.4
CCF
0.14
0.04
0.80
0.12
0.85
0.36
0.24
0.03
0.00
0.00
0.00
0.00
0.05
0.08
0.45
0.60
0.98
1.00
1.00
0.94
0.92
0.99
0.82
0.91
1.00
0.95
0.77
0.90
1.00
0.94
0.95
1.00
0.98
A-51
-------
Time
13:44:37
13:49:03
13:53:26
13:57:52
14:02:18
14:06:46
14:11:09
14:15:37
14:20:03
14:24:28
14:28:56
14:33:22
14:37:50
14:42:16
14:46:41
14:51:10
14:55:37
15:00:03
15:04:28
15:08:54
15:13:20
15:17:45
15:22:15
15:26:42
15:31:12
15:35:39
15:49:05
15:53:32
15:57:54
16:02:20
16:06:47
16:11:13
16:15:39
16:20:02
16:24:28
Flux
[g/sec]
-0.03
-0.03
-0.02
-0.01
-0.01
-0.02
-0.02
-0.01
-0.04
-0.06
-0.11
-0.09
-0.07
-0.05
-0.07
-0.02
-0.02
-0.02
-0.02
-0.01
-0.02
-0.01
-0.01
-0.01
-0.01
-0.02
-0.01
-0.01
-0.02
-0.04
-0.03
-0.06
-0.07
-0.09
Wind Direction
[degrees]
348.0
338.1
322.8
309.6
304.7
315.0
325.6
335.1
336.8
342.4
350.5
68.2
117.2
23.0
25.8
25.1
22.2
18.8
22.8
10.6
357.4
0.2
1.4
350.7
359.2
5.1
26.0
27.0
16.1
353.8
299.6
277.6
293.7
293.2
340.1
Rotated Wind
Direction
[degrees]
170.0
160.1
144.8
131.6
126.7
137.0
147.6
157.1
158.8
164.4
172.5
250.2
299.2
205.0
207.8
207.1
204.2
200.8
204.8
192.6
179.4
182.2
183.4
172.7
181.2
187.1
208.0
209.0
198.1
175.8
121.6
99.6
115.7
115.2
162.1
Wind
Speed
2.9
2.5
2.1
1.9
1.6
1.5
1.9
2.2
2.7
2.9
2.1
0.9
0.8
1.4
2.3
2.0
2.4
2.5
2.2
2.6
2.1
2.0
1.5
1.7
1.9
2.5
1.6
1.7
1.8
1.4
1.1
1.6
1.6
1.5
1.7
CCF
0.99
0.58
0.00
0.06
0.98
0.77
0.68
0.82
0.25
0.17
0.44
0.43
0.31
0.84
0.97
0.99
0.98
0.99
1.00
0.83
0.44
0.55
0.65
0.69
0.00
0.97
0.99
0.96
0.99
0.10
0.16
0.06
0.11
0.08
0.21
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-52
-------
Time
16:28:55
16:33:21
16:37:48
16:42:14
16:46:41
16:51:09
16:55:35
17:00:01
17:04:27
17:08:54
17:13:20
17:17:46
17:22:13
17:26:39
17:31:05
17:35:31
17:39:59
17:44:25
17:48:51
17:53:20
17:57:47
18:02:13
18:06:39
Flux
[g/sec]
-0.03
Wind Direction
[degrees]
5.5
16.7
19.7
21.5
26.4
21.8
17.6
14.8
352.9
344.5
346.4
351.3
1.8
10.4
14.5
16.1
17.4
17.7
21.3
22.8
11.4
6.4
358.9
Rotated Wind
Direction
[degrees]
187.5
198.7
201.7
203.5
208.4
203.8
199.6
196.8
174.9
166.5
168.4
173.3
183.8
192.4
196.5
198.1
199.4
199.7
203.3
204.8
193.4
188.4
180.9
Wind
Speed
2.3
2.4
2.6
2.3
1.9
1.9
1.7
1.3
1.5
1.6
2.0
2.1
2.1
2.5
2.8
2.6
2.8
2.8
2.6
2.4
2.5
2.0
1.4
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-53
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-21. Summary Data Table of VRPM Plane E456 for August 12, 2008 at the EnCana Benzel Facility
Time
11:19:57
11:24:24
11:28:59
11:33:37
11:38:06
11:42:30
11:47:08
11:51:48
11:56:13
12:00:39
12:05:07
12:09:35
12:14:00
12:18:25
12:22:51
12:27:16
12:31:40
12:36:07
12:40:32
12:45:45
12:49:23
12:53:49
12:58:12
13:02:44
13:07:08
13:11:30
13:15:52
13:20:20
13:24:47
13:29:08
13:33:34
13:37:59
13:42:24
Flux
[g/sec]
-0.01
-0.02
-0.02
-0.02
-0.02
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.02
-0.02
-0.01
-0.01
-0.01
-0.01
0.00
-0.01
-0.01
0.01
0.03
0.02
0.02
0.01
0.00
-0.01
-0.01
-0.01
Wind Direction
[degrees]
48.6
44.0
45.9
39.6
17.3
13.4
10.8
19.7
25.6
27.8
33.3
42.3
50.9
47.9
46.1
35.5
31.0
18.0
13.9
4.1
350.7
335.5
339.8
339.1
290.6
285.1
302.1
320.4
328.8
331.9
350.9
353.8
355.9
Rotated Wind
Direction
[degrees]
163.6
159.0
160.9
154.6
132.3
128.4
125.8
134.7
140.6
142.8
148.3
157.3
165.9
162.9
161.1
150.5
146.0
133.0
128.9
119.1
105.7
90.5
94.8
94.1
45.6
40.1
57.1
75.4
83.8
86.9
105.9
108.8
110.9
Wind
Speed
1.7
1.9
2.1
2.2
2.0
2.9
2.8
2.6
2.1
2.1
2.0
1.9
2.1
1.9
1.9
2.1
2.0
2.2
2.3
2.3
2.4
2.1
2.1
2.1
2.1
2.1
2.0
2.6
3.0
3.0
3.9
4.0
3.1
CCF
0.00
0.00
0.00
0.00
0.85
0.91
0.37
0.29
0.57
0.88
1.00
0.93
0.75
0.94
0.72
0.72
0.70
0.89
0.95
0.92
0.96
0.96
1.00
1.00
0.46
1.00
0.98
1.00
0.92
0.89
0.94
0.96
0.99
A-54
-------
Time
13:46:50
13:51:15
13:55:40
14:00:05
14:04:30
14:08:56
14:13:23
14:17:49
14:22:15
14:26:42
14:31:09
14:35:35
14:40:03
14:44:28
14:48:56
14:53:22
14:57:50
15:02:15
15:06:41
15:11:07
15:15:33
15:20:02
15:24:28
15:28:59
15:33:24
15:46:46
15:51:18
15:55:45
16:00:06
16:04:32
16:08:59
16:13:25
16:17:48
16:22:14
16:26:40
Flux
[g/sec]
0.00
0.02
0.03
0.04
0.04
0.02
0.01
0.01
0.00
0.00
-0.01
-0.01
-0.01
-0.02
-0.01
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
-0.01
-0.01
-0.01
0.00
0.01
0.01
0.01
0.00
-0.01
Wind Direction
[degrees]
344.1
334.1
319.2
312.9
307.9
319.9
335.4
342.5
343.1
342.3
13.0
100.8
105.1
19.8
25.6
23.2
21.9
22.2
12.7
0.9
0.1
3.8
1.4
349.7
23.2
78.6
26.0
22.9
15.0
326.3
282.0
284.5
291.2
314.5
356.0
Rotated Wind
Direction
[degrees]
99.1
89.1
74.2
67.9
62.9
74.9
90.4
97.5
98.1
97.3
128.0
215.8
220.1
134.8
140.6
138.2
136.9
137.2
127.7
115.9
115.1
118.8
116.4
104.7
138.2
193.6
141.0
137.9
130.0
81.3
37.0
39.5
46.2
69.5
111.0
Wind
Speed
2.5
2.3
2.0
1.7
1.4
1.6
2.0
2.2
3.1
2.5
1.3
0.7
0.8
2.0
2.0
2.1
2.5
2.5
2.0
2.4
2.1
1.8
1.5
1.8
2.3
0.5
2.1
1.3
1.8
1.1
1.3
1.7
1.5
1.4
2.0
CCF
0.86
0.79
0.74
0.93
0.98
0.98
0.97
0.65
0.95
0.97
0.97
0.94
0.91
0.95
0.91
0.77
0.95
0.93
0.82
0.77
0.82
0.69
0.61
0.46
0.72
0.85
0.91
0.87
0.85
0.85
0.91
0.85
0.72
0.74
0.68
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-55
-------
Time
16:31:07
16:35:34
16:40:01
16:44:26
16:48:55
16:53:21
16:57:47
17:02:13
17:06:41
17:11:07
17:15:33
17:19:59
17:24:25
17:28:51
17:33:18
17:37:45
17:42:12
17:46:37
17:51:03
17:55:32
17:59:58
18:04:25
Flux
[g/sec]
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.02
-0.02
-0.02
0.01
0.00
Wind Direction
[degrees]
14.5
17.8
19.2
26.5
24.4
23.1
12.4
3.0
347.9
343.6
349.1
352.5
9.8
14.5
12.2
18.5
16.0
21.6
21.6
17.1
8.5
4.0
Rotated Wind
Direction
[degrees]
129.5
132.8
134.2
141.5
139.4
138.1
127.4
118.0
102.9
98.6
104.1
107.5
124.8
129.5
127.2
133.5
131.0
136.6
136.6
132.1
123.5
119.0
Wind
Speed
2.5
2.5
2.6
2.0
1.9
1.8
1.5
1.4
1.5
1.8
2.1
2.1
2.3
2.7
2.6
2.7
2.9
2.7
2.4
2.4
2.2
1.6
CCF
0.92
0.00
0.89
0.85
0.86
0.86
0.89
0.17
0.51
0.57
0.58
0.45
0.93
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-56
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-22. Summary Data Table of VRPM Plane A123 for August 13, 2008 at the EnCana Benzel Facility
Time
09:33:15
09:38:38
09:42:59
09:47:22
09:51:46
09:56:08
10:00:32
10:04:54
10:09:16
10:13:37
10:18:18
10:22:22
10:26:46
10:31:09
10:35:30
10:39:53
10:44:17
10:48:41
10:53:06
10:57:29
11:01:53
11:06:15
11:10:41
11:15:06
11:19:31
11:23:52
11:28:15
11:32:41
11:37:05
11:41:29
11:45:50
11:50:13
11:54:38
Flux
[g/sec]
0.01
0.00
0.02
0.03
0.03
0.04
0.03
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
14.0
17.7
23.8
18.4
19.2
19.3
19.6
13.5
14.2
10.2
2.1
356.5
341.3
336.6
354.6
350.1
356.9
357.7
346.4
343.8
347.6
346.2
345.3
356.7
358.9
344.3
340.4
338.9
332.1
334.6
343.4
345.8
331.7
Rotated Wind
Direction
[degrees]
310.0
313.7
319.8
314.4
315.2
315.3
315.6
309.5
310.2
306.2
298.1
292.5
277.3
272.6
290.6
286.1
292.9
293.7
282.4
279.8
283.6
282.2
281.3
292.7
294.9
280.3
276.4
274.9
268.1
270.6
279.4
281.8
267.7
Wind
Speed
1.3
1.2
1.2
1.3
1.3
1.4
1.5
1.4
1.4
1.2
0.9
0.9
0.9
0.8
1.0
1.1
1.0
1.2
1.2
1.2
1.3
1.3
1.1
1.3
1.2
0.9
0.9
0.9
1.0
1.2
1.4
1.5
1.0
CCF
0.16
0.32
0.29
0.28
0.25
0.51
0.48
0.70
0.97
0.91
0.99
1.00
0.00
0.03
0.01
0.01
0.02
0.01
0.03
0.00
0.11
0.02
0.03
0.64
0.59
0.73
0.75
0.00
0.91
0.00
0.00
0.00
0.00
A-57
-------
Time
11:58:58
12:03:20
12:07:42
12:12:05
12:16:24
12:20:48
12:25:09
12:29:33
12:33:56
12:38:21
12:42:42
12:47:07
12:51:31
12:55:55
13:00:17
13:04:39
13:09:02
13:13:23
13:17:47
13:22:09
13:26:30
13:30:53
13:35:15
13:39:37
13:43:59
13:48:20
13:52:42
13:57:03
14:01:27
14:05:50
14:10:14
14:14:38
14:19:01
14:23:23
14:27:46
Flux
[g/sec]
0.00
0.00
0.00
0.00
0.00
0.00
0.03
0.03
0.02
0.02
0.01
0.01
0.00
-0.01
-0.01
-0.04
-0.04
0.04
0.11
0.12
0.11
0.11
0.14
0.13
0.11
0.09
0.10
0.07
0.07
0.07
0.08
0.08
0.03
Wind Direction
[degrees]
334.8
330.2
132.0
73.8
93.5
68.7
23.4
32.8
33.2
29.0
19.9
14.5
26.8
31.6
14.2
345.6
334.7
320.9
345.1
29.3
45.8
47.3
46.0
45.8
37.3
35.4
40.2
54.7
56.4
49.2
41.3
31.4
21.4
12.2
359.4
Rotated Wind
Direction
[degrees]
270.8
266.2
68.0
9.8
29.5
4.7
319.4
328.8
329.2
325.0
315.9
310.5
322.8
327.6
310.2
281.6
270.7
256.9
281.1
325.3
341.8
343.3
342.0
341.8
333.3
331.4
336.2
350.7
352.4
345.2
337.3
327.4
317.4
308.2
295.4
Wind
Speed
0.9
0.4
0.2
0.4
0.5
0.5
0.7
0.8
1.3
1.5
1.4
1.5
0.9
1.0
0.9
0.9
0.9
1.1
1.1
1.6
1.9
2.4
2.4
2.0
1.8
2.0
1.7
1.8
2.3
2.5
2.9
3.1
3.2
3.3
3.1
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.97
0.97
0.86
0.90
0.93
0.93
0.88
0.99
0.74
0.96
0.84
0.97
0.99
0.95
0.98
0.99
0.98
1.00
0.99
1.00
1.00
0.98
0.98
0.95
0.97
0.96
0.70
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-58
-------
Time
14:32:09
14:36:31
14:40:52
14:45:15
14:49:38
14:54:01
14:58:22
15:02:46
15:07:09
15:11:31
15:15:52
15:42:56
15:46:19
15:48:41
15:51:04
15:53:26
15:55:48
15:58:11
16:00:33
16:02:53
16:05:15
16:07:37
16:09:59
16:12:20
16:14:42
16:17:03
16:19:24
16:21:46
16:24:06
16:26:26
16:28:49
16:31:09
16:33:29
16:35:51
16:38:12
Flux
[g/sec]
0.01
0.01
0.01
0.00
0.00
0.01
0.01
0.01
0.01
-0.02
-0.02
-0.02
-0.01
-0.01
0.00
0.01
0.01
0.00
0.00
-0.02
-0.02
-0.02
-0.04
-0.02
0.00
0.01
0.01
Wind Direction
[degrees]
358.1
355.1
326.6
310.9
296.4
279.1
293.3
306.1
320.0
354.4
351.8
182.0
173.3
176.7
167.9
156.1
122.9
77.5
61.6
10.9
342.0
341.5
335.4
324.1
326.8
323.4
318.2
336.3
353.8
18.7
49.1
26.7
13.4
8.8
333.0
Rotated Wind
Direction
[degrees]
294.1
291.1
262.6
246.9
232.4
215.1
229.3
242.1
256.0
290.4
287.8
118.0
109.3
112.7
103.9
92.1
58.9
13.5
357.6
306.9
278.0
277.5
271.4
260.1
262.8
259.4
254.2
272.3
289.8
314.7
345.1
322.7
309.4
304.8
269.0
Wind
Speed
3.0
2.5
1.9
2.1
2.1
2.2
2.5
1.5
1.1
1.3
1.5
1.0
2.6
2.4
2.5
2.0
1.1
0.9
1.0
1.2
1.9
3.2
4.1
3.7
3.5
3.4
2.7
1.8
1.4
1.1
1.1
1.1
0.7
0.7
0.7
CCF
0.01
0.10
0.13
0.12
0.09
0.30
0.00
0.00
0.79
0.93
0.88
0.89
0.89
0.90
0.93
0.97
0.98
0.98
0.98
0.98
0.93
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.17
0.91
0.93
0.99
1.00
0.95
0.47
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-59
-------
Time
16:40:32
16:42:53
16:45:15
16:47:35
16:49:58
16:52:18
16:54:39
16:57:01
16:59:24
17:01:44
17:04:05
17:06:30
17:08:52
17:11:13
17:13:36
17:16:00
17:18:23
17:20:45
17:23:07
17:25:27
17:27:52
17:30:15
17:32:37
17:34:59
17:37:22
17:39:42
17:42:03
17:44:25
17:46:47
Flux
[g/sec]
0.00
0.01
0.01
0.00
0.00
Wind Direction
[degrees]
308.2
292.6
290.1
286.9
295.7
307.6
314.8
334.4
348.5
358.6
5.1
359.4
320.0
294.8
280.6
264.6
264.4
267.9
282.3
300.8
306.2
313.0
308.8
307.6
312.9
316.3
313.6
317.6
317.4
Rotated Wind
Direction
[degrees]
244.2
228.6
226.1
222.9
231.7
243.6
250.8
270.4
284.5
294.6
301.1
295.4
256.0
230.8
216.6
200.6
200.4
203.9
218.3
236.8
242.2
249.0
244.8
243.6
248.9
252.3
249.6
253.6
253.4
Wind
Speed
0.5
0.6
1.1
1.5
1.7
2.2
2.3
2.5
2.8
2.6
2.4
1.9
1.6
2.0
2.3
2.4
2.4
1.8
1.2
1.5
2.2
2.1
2.5
2.7
3.0
2.9
3.1
3.7
4.5
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.32
0.32
0.24
0.36
0.41
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-60
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-23. Summary Data Table of VRPM Plane A456 for August 13, 2008 at the EnCana Benzel Facility
Time
09:36:27
09:40:49
09:45:10
09:49:33
09:53:57
09:58:21
10:02:42
10:07:05
10:11:26
10:15:49
10:20:12
10:24:34
10:28:58
10:33:20
10:37:42
10:42:06
10:46:29
10:50:54
10:55:18
10:59:42
11:04:03
11:08:29
11:12:55
11:17:17
11:21:41
11:26:04
11:30:29
11:34:54
11:39:16
Flux
[g/sec]
0.04
0.03
0.02
0.03
0.02
0.03
0.03
0.03
0.03
0.02
0.02
0.05
0.05
0.05
0.04
0.04
0.04
0.05
0.04
0.04
0.04
0.04
0.04
0.04
Wind Direction
[degrees]
13.7
18.4
22.0
18.6
18.7
19.4
15.7
14.0
11.7
1.6
358.5
349.8
338.6
341.1
345.9
354.5
357.3
353.2
345.7
344.6
349.7
342.4
354.0
1.5
352.7
343.1
337.6
335.2
329.5
Rotated Wind
Direction
[degrees]
48.7
53.4
57.0
53.6
53.7
54.4
50.7
49.0
46.7
36.6
33.5
24.8
13.6
16.1
20.9
29.5
32.3
28.2
20.7
19.6
24.7
17.4
29.0
36.5
27.7
18.1
12.6
10.2
4.5
Wind
Speed
1.3
1.1
1.2
1.2
1.3
1.4
1.4
1.4
1.3
0.9
0.8
0.9
0.8
0.8
1.0
1.1
1.1
1.2
1.1
1.2
1.4
1.1
1.3
1.3
1.1
0.8
0.8
1.0
1.1
CCF
1.00
1.00
0.99
0.95
0.95
0.87
0.81
0.91
0.85
0.90
0.98
0.00
0.00
0.00
0.00
0.00
0.99
0.96
0.92
0.97
0.94
0.99
1.00
1.00
1.00
0.99
1.00
1.00
1.00
A-61
-------
Time
11:43:40
11:48:02
11:52:26
11:56:48
12:01:09
12:05:31
12:09:55
12:14:15
12:18:36
12:22:58
12:27:21
12:31:45
12:36:09
12:40:31
12:44:55
12:49:19
12:53:43
12:58:06
13:02:29
13:06:51
13:11:13
13:15:36
13:19:58
13:24:20
13:28:41
13:33:04
13:37:25
13:41:47
13:46:09
13:50:32
Flux
[g/sec]
0.06
0.07
0.05
0.04
0.03
0.00
0.00
0.00
0.00
0.00
0.02
0.02
0.02
0.04
0.05
0.03
0.02
0.04
0.03
0.02
0.06
0.08
0.09
0.07
0.07
0.04
0.03
0.01
0.03
0.03
Wind Direction
[degrees]
340.7
346.2
337.9
332.0
325.8
4.3
110.1
74.4
94.8
39.4
32.4
31.6
26.7
19.4
18.2
17.2
25.4
11.4
353.3
341.6
326.3
330.1
0.9
44.6
48.5
44.4
43.1
48.8
37.2
36.0
Rotated Wind
Direction
[degrees]
15.7
21.2
12.9
7.0
0.8
39.3
145.1
109.4
129.8
74.4
67.4
66.6
61.7
54.4
53.2
52.2
60.4
46.4
28.3
16.6
1.3
5.1
35.9
79.6
83.5
79.4
78.1
83.8
72.2
71.0
Wind
Speed
1.4
1.5
1.2
1.0
0.7
0.1
0.3
0.4
0.4
0.6
0.8
1.0
1.4
1.5
1.5
1.3
0.9
1.0
0.9
0.8
1.0
1.2
1.2
1.6
2.0
2.4
2.2
1.7
1.9
1.7
CCF
1.00
0.98
1.00
0.96
0.95
0.00
0.00
0.00
0.00
0.00
0.80
0.81
0.90
0.98
0.95
0.98
0.96
0.98
0.87
1.00
1.00
0.91
0.79
0.98
0.51
0.99
1.00
1.00
1.00
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-62
-------
Time
13:54:53
13:59:16
14:03:38
14:08:03
14:12:27
14:16:49
14:21:11
14:25:34
14:29:57
14:34:19
14:38:42
14:43:04
14:47:26
14:51:50
14:56:12
15:00:33
15:04:58
15:09:21
15:13:42
15:45:08
15:47:30
15:49:53
15:52:15
15:54:36
15:56:59
15:59:22
16:01:43
16:04:04
16:06:25
16:08:48
Flux
[g/sec]
0.03
0.02
0.01
0.02
0.02
0.03
0.04
0.06
0.09
0.08
0.06
0.07
0.07
0.04
0.03
0.03
0.02
0.04
0.05
0.03
0.04
0.03
0.08
0.10
0.12
0.15
Wind Direction
[degrees]
46.9
59.3
55.5
42.9
36.4
29.4
17.1
3.0
358.3
358.7
348.8
313.8
310.7
290.7
284.9
297.4
319.3
347.0
346.7
170.1
176.1
172.1
161.6
149.2
91.2
90.2
29.8
351.0
342.6
340.7
Rotated Wind
Direction
[degrees]
81.9
94.3
90.5
77.9
71.4
64.4
52.1
38.0
33.3
33.7
23.8
348.8
345.7
325.7
319.9
332.4
354.3
22.0
21.7
205.1
211.1
207.1
196.6
184.2
126.2
125.2
64.8
26.0
17.6
15.7
Wind
Speed
1.7
2.1
2.5
2.6
2.9
3.2
3.3
3.0
3.1
2.8
2.0
2.2
2.1
2.0
2.3
2.1
1.4
1.0
1.5
2.1
2.7
2.4
2.3
1.6
0.9
1.1
1.1
1.5
2.4
3.8
CCF
1.00
0.99
0.99
1.00
0.99
0.99
0.98
0.99
0.97
0.99
1.00
0.99
0.98
0.97
0.95
0.97
0.97
0.96
0.95
0.00
0.00
0.00
0.00
0.91
0.74
0.76
0.89
0.83
0.87
0.94
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-63
-------
Time
16:11:10
16:13:30
16:15:50
16:18:14
16:20:35
16:22:56
16:25:17
16:27:38
16:29:58
16:32:19
16:34:40
16:37:00
16:39:21
16:41:43
16:44:05
16:46:25
16:48:48
16:51:08
16:53:28
16:55:50
16:58:13
17:00:34
17:02:54
17:05:17
17:07:41
17:10:04
17:12:24
17:14:47
17:17:11
17:19:35
Flux
[g/sec]
0.15
0.14
0.12
0.08
0.07
0.06
0.06
0.05
0.05
0.03
0.05
0.03
0.03
0.02
0.03
0.05
0.06
0.06
0.07
0.06
0.06
0.05
0.05
0.04
0.03
0.03
0.03
Wind Direction
[degrees]
325.3
327.2
325.0
320.1
319.9
351.9
359.9
33.0
37.0
22.4
10.9
354.0
317.6
279.7
292.8
287.5
287.0
300.9
310.7
326.1
342.9
351.2
0.1
5.2
338.6
303.3
287.5
270.2
262.8
264.5
Rotated Wind
Direction
[degrees]
0.3
2.2
360.0
355.1
354.9
26.9
34.9
68.0
72.0
57.4
45.9
29.0
352.6
314.7
327.8
322.5
322.0
335.9
345.7
1.1
17.9
26.2
35.1
40.2
13.6
338.3
322.5
305.2
297.8
299.5
Wind
Speed
3.9
3.6
3.5
3.2
2.2
1.6
1.2
1.1
1.0
0.8
0.7
0.6
0.6
0.4
0.8
1.3
1.6
2.0
2.3
2.3
2.6
2.7
2.4
2.3
1.6
1.8
2.2
2.3
2.4
2.2
CCF
0.95
0.98
0.99
1.00
0.97
0.99
0.97
0.97
0.97
0.98
0.84
0.97
1.00
0.86
0.77
0.82
0.77
0.87
0.90
0.92
0.96
0.96
0.96
0.98
0.99
0.99
0.99
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-64
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Time
17:21:56
17:24:18
17:26:42
17:29:04
17:31:27
17:33:47
17:36:10
17:38:31
17:40:53
17:43:14
17:45:37
Flux
[g/sec]
Wind Direction
[degrees]
274.7
294.2
301.8
311.2
309.7
307.2
308.6
315.3
314.5
313.9
318.5
Rotated Wind
Direction
[degrees]
309.7
329.2
336.8
346.2
344.7
342.2
343.6
350.3
349.5
348.9
353.5
Wind
Speed
1.4
1.2
1.8
2.2
2.3
2.6
2.8
2.9
3.1
3.2
4.2
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-65
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-24. Summary Data Table of VRPM Plane E123 for August 13, 2008 at the EnCana Benzel Facility
Time
10:30:58
10:35:22
10:39:50
10:44:14
10:48:38
10:53:01
10:57:24
11:01:49
11:06:11
11:10:35
11:14:58
11:19:21
11:23:44
11:28:09
11:32:31
11:36:54
11:41:17
11:45:41
11:50:03
11:54:27
11:58:50
12:03:14
12:07:37
12:12:01
12:16:25
12:20:48
12:25:12
12:29:36
12:34:00
12:38:25
12:42:47
12:47:12
12:51:35
Flux
[g/sec]
-0.01
-0.02
-0.02
-0.02
-0.02
-0.02
-0.01
-0.02
-0.01
-0.02
-0.02
-0.02
-0.01
-0.01
0.00
-0.01
-0.01
-0.02
-0.02
-0.02
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
-0.01
-0.01
-0.01
Wind Direction
[degrees]
336.6
354.4
349.9
356.1
357.4
346.4
343.7
347.5
346.3
344.9
356.6
359.0
344.7
340.6
339.6
331.9
333.9
343.5
345.7
331.3
334.7
329.9
130.8
73.8
94.1
67.9
25.8
32.8
33.4
28.7
20.0
14.4
27.1
Rotated Wind
Direction
[degrees]
158.6
176.4
171.9
178.1
179.4
168.4
165.7
169.5
168.3
166.9
178.6
181.0
166.7
162.6
161.6
153.9
155.9
165.5
167.7
153.3
156.7
151.9
312.8
255.8
276.1
249.9
207.8
214.8
215.4
210.7
202.0
196.4
209.1
Wind
Speed
0.8
1.0
1.1
1.0
1.2
1.2
1.2
1.3
1.3
1.1
1.3
1.2
0.9
0.9
0.9
1.0
1.2
1.4
1.5
1.0
0.9
0.4
0.2
0.4
0.5
0.5
0.7
0.8
1.3
1.5
1.4
1.5
0.9
CCF
0.74
0.89
0.04
0.03
0.98
0.76
0.92
0.93
0.86
1.00
0.99
0.99
0.93
0.78
0.00
1.00
0.98
0.88
0.71
0.93
0.81
0.00
0.00
0.00
0.00
0.00
0.00
0.94
0.96
0.99
0.00
0.53
0.64
A-66
-------
Time
12:55:59
13:00:21
13:04:45
13:09:10
13:13:32
13:17:56
13:22:18
13:26:43
13:31:06
13:35:29
13:39:51
13:44:16
13:48:39
13:53:03
13:57:26
14:01:50
14:06:13
14:10:36
14:15:15
14:19:23
14:23:47
14:28:10
14:32:33
14:36:57
14:41:21
14:45:45
14:50:08
14:54:31
14:58:55
15:03:20
15:07:44
15:12:07
15:16:33
15:21:21
15:25:23
Flux
[g/sec]
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.02
-0.01
-0.02
-0.02
-0.02
-0.01
-0.01
-0.01
-0.01
-0.02
-0.02
-0.03
-0.02
-0.02
-0.02
-0.05
-0.04
-0.05
-0.06
-0.12
-0.07
-0.04
-0.05
-0.01
-0.04
Wind Direction
[degrees]
31.6
13.6
345.3
334.2
321.5
345.6
30.1
46.9
46.9
46.3
46.2
37.2
35.4
39.6
54.7
56.4
48.5
41.2
31.2
20.2
11.0
359.1
358.2
356.9
321.3
310.9
294.0
278.8
295.1
309.5
328.5
352.4
352.4
352.6
330.2
Rotated Wind
Direction
[degrees]
213.6
195.6
167.3
156.2
143.5
167.6
212.1
228.9
228.9
228.3
228.2
219.2
217.4
221.6
236.7
238.4
230.5
223.2
213.2
202.2
193.0
181.1
180.2
178.9
143.3
132.9
116.0
100.8
117.1
131.5
150.5
174.4
174.4
174.6
152.2
Wind
Speed
1.0
0.9
0.9
0.9
1.1
1.1
1.6
1.9
2.4
2.4
2.0
1.8
1.9
1.7
1.9
2.4
2.5
2.9
3.2
3.3
3.2
3.1
3.0
2.3
1.9
2.1
2.1
2.2
2.4
1.5
1.0
1.4
1.6
1.5
1.0
CCF
0.56
0.38
0.00
0.99
0.67
0.69
0.79
0.98
0.94
0.99
0.76
0.52
0.44
0.01
0.03
0.01
0.58
0.96
0.83
0.97
0.96
1.00
0.97
0.10
0.01
0.00
0.00
0.62
0.97
1.00
0.94
0.94
0.00
0.00
0.96
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-67
-------
Time
15:29:48
15:34:14
15:38:40
15:43:05
15:47:30
15:51:56
15:56:21
16:00:47
16:05:11
16:09:36
16:13:59
16:18:25
16:22:49
16:27:12
16:35:14
16:39:38
16:44:03
16:48:28
16:52:51
17:00:53
17:05:18
17:09:43
17:14:07
17:18:30
17:22:55
17:27:20
Flux
[g/sec]
-0.03
-0.07
-0.16
-0.08
-0.04
-0.02
-0.02
-0.01
-0.02
0.00
0.00
-0.01
0.00
-0.01
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
300.9
295.6
225.1
190.7
166.3
157.9
148.3
5.2
350.8
331.0
328.3
332.6
334.1
357.2
352.2
320.5
312.9
321.7
329.2
343.1
331.4
315.7
283.3
281.4
283.4
296.1
Rotated Wind
Direction
[degrees]
122.9
117.6
47.1
12.7
348.3
339.9
330.3
187.2
172.8
153.0
150.3
154.6
156.1
179.2
174.2
142.5
134.9
143.7
151.2
165.1
153.4
137.7
105.3
103.4
105.4
118.1
Wind
Speed
1.9
1.1
0.8
1.6
1.4
1.7
1.1
0.8
2.2
2.9
3.2
2.6
1.9
1.3
0.6
0.7
1.2
1.5
1.6
2.1
2.1
1.7
1.7
1.9
2.1
1.9
CCF
1.00
0.50
0.65
0.98
1.00
1.00
0.99
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.82
0.68
0.59
0.96
0.00
0.00
0.00
1.00
0.99
0.97
0.85
0.68
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-68
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-25. Summary Data Table of VRPM Plane E456 for August 13, 2008 at the EnCana Benzel Facility
Time
10:33:10
10:37:33
10:42:01
10:46:24
10:50:48
10:55:12
10:59:36
11:04:01
11:08:23
11:12:46
11:17:08
11:21:32
11:25:55
11:30:19
11:34:42
11:39:04
11:43:29
11:47:51
11:52:15
11:56:38
12:01:00
12:05:25
12:09:48
12:14:12
12:18:37
12:22:59
12:27:24
12:31:47
12:36:11
Flux
[g/sec]
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
340.7
347.0
354.4
357.4
353.6
345.7
344.5
349.8
342.5
353.5
1.7
353.0
343.1
338.9
336.0
329.5
340.5
346.1
339.1
332.2
327.9
355.9
110.0
74.2
94.8
39.6
32.4
31.8
26.6
Rotated Wind
Direction
[degrees]
95.7
102.0
109.4
112.4
108.6
100.7
99.5
104.8
97.5
108.5
116.7
108.0
98.1
93.9
91.0
84.5
95.5
101.1
94.1
87.2
82.9
110.9
225.0
189.2
209.8
154.6
147.4
146.8
141.6
Wind
Speed
0.8
1.0
1.1
1.1
1.2
1.1
1.2
1.4
1.1
1.3
1.3
1.1
0.8
0.8
1.0
1.1
1.3
1.5
1.3
1.0
0.7
0.1
0.3
0.4
0.4
0.6
0.8
1.0
1.4
CCF
0.82
0.82
0.57
0.97
0.82
0.92
-0.04
0.97
0.78
0.99
0.97
0.95
0.90
0.52
0.72
0.75
0.88
0.95
1.00
0.85
0.88
0.00
0.00
0.00
0.00
0.00
0.52
0.41
0.99
A-69
-------
Time
12:40:35
12:44:58
12:49:23
12:53:46
12:58:09
13:02:32
13:06:57
13:11:20
13:15:43
13:20:06
13:24:29
13:28:54
13:33:16
13:37:39
13:42:03
13:46:27
13:50:50
13:55:14
13:59:38
14:04:01
14:08:24
14:12:46
14:17:10
14:21:34
14:25:58
14:30:21
14:34:45
14:39:08
14:43:32
14:47:55
Flux
[g/sec]
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
0.00
-0.01
Wind Direction
[degrees]
19.5
18.2
17.6
25.4
11.2
352.9
341.6
325.8
332.0
2.6
45.0
48.5
44.3
43.1
48.9
36.7
36.6
46.7
59.8
54.9
43.0
36.1
28.0
16.3
2.2
358.2
357.8
343.3
312.4
309.8
Rotated Wind
Direction
[degrees]
134.5
133.2
132.6
140.4
126.2
107.9
96.6
80.8
87.0
117.6
160.0
163.5
159.3
158.1
163.9
151.7
151.6
161.7
174.8
169.9
158.0
151.1
143.0
131.3
117.2
113.2
112.8
98.3
67.4
64.8
Wind
Speed
1.5
1.5
1.3
0.9
1.0
0.9
0.8
1.0
1.2
1.2
1.6
2.0
2.4
2.2
1.7
2.0
1.7
1.6
2.2
2.5
2.6
2.9
3.2
3.3
3.1
3.1
2.7
1.9
2.1
2.1
CCF
0.00
0.00
0.00
0.00
0.75
0.74
0.80
0.96
-0.06
0.77
0.82
0.88
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.20
0.33
0.43
0.44
0.87
0.70
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-70
-------
Time
14:52:18
14:56:42
15:01:08
15:05:31
15:09:56
15:14:20
15:18:46
15:23:11
15:27:34
15:32:00
15:36:26
15:40:52
15:45:17
15:49:42
15:54:09
15:58:33
16:02:57
16:07:23
16:11:47
16:16:12
16:20:36
16:25:00
16:58:40
17:03:06
17:07:30
17:11:54
17:16:18
17:20:43
17:25:07
17:29:31
Flux
[g/sec]
-0.01
0.00
-0.01
-0.01
-0.01
0.00
-0.01
-0.01
0.01
0.01
0.02
0.02
0.02
0.01
0.01
0.00
0.00
0.02
0.03
0.02
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
Wind Direction
[degrees]
287.6
287.3
299.9
318.7
351.5
346.5
348.6
349.1
308.9
308.3
271.9
191.3
184.3
158.1
154.7
127.7
2.1
330.7
327.0
330.1
334.7
336.0
338.6
340.5
322.3
297.7
282.2
279.4
289.7
303.3
Rotated Wind
Direction
[degrees]
42.6
42.3
54.9
73.7
106.5
101.5
103.6
104.1
63.9
63.3
26.9
306.3
299.3
273.1
269.7
242.7
117.1
85.7
82.0
85.1
89.7
91.0
93.6
95.5
77.3
52.7
37.2
34.4
44.7
58.3
Wind
Speed
2.0
2.5
2.0
1.3
1.1
1.6
1.4
1.3
1.5
1.6
0.9
1.5
1.3
1.5
1.5
0.5
1.6
2.6
3.2
2.9
2.3
1.4
2.1
2.0
1.9
1.5
1.8
2.0
1.9
2.0
CCF
0.83
0.99
0.88
0.89
0.93
1.00
1.00
0.98
0.97
0.98
0.59
0.46
0.68
0.43
0.30
0.83
0.41
0.45
0.67
0.96
0.88
0.94
0.99
0.64
0.94
0.89
0.90
0.86
0.95
0.91
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-71
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-26. Summary Data Table of VRPM Plane A123 for August 14, 2008 at the EnCana Benzel Facility
Time
09:18:50
09:24:10
09:28:31
09:32:54
09:37:16
09:41:38
09:45:58
09:50:21
09:54:42
09:59:04
10:03:28
10:07:51
10:12:14
10:16:35
10:20:58
10:25:22
10:29:44
10:34:05
10:38:27
10:42:48
10:47:09
10:51:30
10:55:51
11:00:15
11:04:36
11:08:59
11:13:20
11:17:43
11:22:04
Flux
[g/sec]
0.03
0.03
0.02
0.01
0.03
0.02
0.03
0.04
0.04
0.03
0.02
0.01
0.01
0.02
0.02
0.01
0.01
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.02
0.02
Wind Direction
[degrees]
48.8
32.3
14.3
15.3
11.9
11.4
6.9
12.6
13.0
3.8
5.5
357.8
349.9
345.7
351.6
353.6
0.5
1.7
358.4
0.3
350.0
347.3
349.8
355.4
356.8
2.6
10.6
11.1
7.0
Rotated Wind
Direction
[degrees]
344.8
328.3
310.3
311.3
307.9
307.4
302.9
308.6
309.0
299.8
301.5
293.8
285.9
281.7
287.6
289.6
296.5
297.7
294.4
296.3
286.0
283.3
285.8
291.4
292.8
298.6
306.6
307.1
303.0
Wind
Speed
1.0
1.2
1.4
1.2
1.3
1.4
1.3
1.4
1.5
1.4
1.5
1.7
1.9
1.8
1.9
1.7
1.6
1.5
1.4
1.2
1.2
1.1
1.3
1.5
1.5
1.4
1.7
1.6
1.6
CCF
0.97
0.98
0.84
0.91
0.00
0.45
0.94
0.90
0.91
0.94
0.44
0.77
0.00
0.00
0.89
0.64
0.94
0.97
0.91
0.92
0.82
0.94
0.92
0.92
0.79
0.15
0.13
0.03
0.05
A-72
-------
Time
11:26:26
11:30:47
11:35:08
11:39:32
11:43:54
11:48:15
11:52:36
11:57:00
12:01:21
12:05:44
12:10:05
12:14:30
12:18:54
12:23:17
12:27:39
12:32:03
12:36:26
12:40:49
12:45:11
12:49:33
12:53:56
12:58:17
13:02:39
13:07:00
13:11:24
13:15:47
13:20:09
13:24:30
13:28:53
13:33:15
Flux
[g/sec]
0.02
0.02
0.01
0.00
0.01
0.01
0.01
0.01
0.01
-0.01
0.02
0.03
0.04
0.07
0.08
0.07
0.04
-0.01
0.00
0.00
0.00
0.00
0.05
0.08
0.12
0.11
0.00
0.00
-0.01
0.00
Wind Direction
[degrees]
6.8
3.9
354.8
345.7
13.9
34.3
110.5
142.3
146.5
165.1
155.1
134.5
112.3
76.0
53.9
65.8
61.3
200.8
205.4
205.7
182.3
142.0
96.5
81.8
67.7
50.4
6.0
229.2
225.9
254.6
Rotated Wind
Direction
[degrees]
302.8
299.9
290.8
281.7
309.9
330.3
46.5
78.3
82.5
101.1
91.1
70.5
48.3
12.0
349.9
1.8
357.3
136.8
141.4
141.7
118.3
78.0
32.5
17.8
3.7
346.4
302.0
165.2
161.9
190.6
Wind
Speed
1.7
1.6
1.3
1.1
0.8
0.5
0.3
0.8
1.3
1.4
1.1
0.9
0.9
1.0
1.2
0.9
0.5
0.4
0.6
0.6
0.5
0.6
1.0
1.2
1.3
1.3
0.3
0.4
0.4
0.3
CCF
0.03
0.15
0.06
0.98
0.97
0.98
0.94
0.96
1.00
0.99
0.98
0.98
1.00
1.00
0.99
1.00
1.00
1.00
0.00
0.00
0.00
1.00
0.99
0.99
0.98
0.97
0.00
0.00
1.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-73
-------
Time
13:37:38
13:42:01
13:46:23
13:50:46
13:55:08
13:59:30
14:03:51
14:08:14
14:12:36
14:16:58
14:21:20
14:25:41
14:30:02
14:34:26
14:38:47
14:43:09
14:47:30
14:51:53
14:56:15
15:00:37
15:04:59
15:09:21
15:13:42
15:18:03
15:22:26
15:26:49
15:31:10
15:35:31
15:39:55
15:44:19
Flux
[g/sec]
0.03
0.06
0.06
0.01
0.01
0.00
0.00
0.02
0.05
0.05
0.03
0.02
-0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.00
-0.02
-0.02
-0.01
-0.01
-0.01
0.00
0.00
0.00
Wind Direction
[degrees]
24.2
18.7
10.8
346.7
336.3
277.3
228.1
200.9
138.1
128.9
178.8
220.8
250.7
263.1
280.7
313.7
318.1
338.7
347.5
344.5
339.0
336.7
330.0
336.7
341.9
350.5
354.5
3.2
352.7
345.9
Rotated Wind
Direction
[degrees]
320.2
314.7
306.8
282.7
272.3
213.3
164.1
136.9
74.1
64.9
114.8
156.8
186.7
199.1
216.7
249.7
254.1
274.7
283.5
280.5
275.0
272.7
266.0
272.7
277.9
286.5
290.5
299.2
288.7
281.9
Wind
Speed
1.0
2.6
2.7
2.1
1.6
1.0
1.2
0.8
0.9
0.7
0.8
1.4
1.6
2.3
2.2
1.9
1.8
1.4
1.8
1.6
1.5
1.7
1.4
1.8
1.8
2.0
2.2
2.5
2.1
2.4
CCF
0.81
0.91
0.97
0.85
0.74
1.00
0.95
0.97
0.50
0.62
0.63
0.62
0.98
0.00
0.00
1.00
0.97
1.00
1.00
1.00
0.98
0.99
0.02
0.01
0.02
0.02
0.01
0.01
0.01
0.01
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-74
-------
Time
15:48:41
15:53:02
15:57:25
16:01:49
16:06:12
16:10:35
16:14:57
16:19:22
16:23:44
16:28:08
16:32:30
16:36:54
16:41:15
16:45:37
16:50:00
Flux
[g/sec]
0.01
0.00
Wind Direction
[degrees]
343.1
333.4
340.2
340.4
344.3
346.3
337.2
323.2
297.6
285.9
269.0
273.4
264.4
313.5
315.8
Rotated Wind
Direction
[degrees]
279.1
269.4
276.2
276.4
280.3
282.3
273.2
259.2
233.6
221.9
205.0
209.4
200.4
249.5
251.8
Wind
Speed
2.5
2.7
2.8
2.7
2.8
2.7
2.5
2.3
2.1
2.4
2.8
2.8
2.0
1.9
2.2
CCF
0.20
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-75
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-27. Summary Data Table of VRPM Plane A456 for August 14, 2008 at the EnCana Benzel Facility
Time
09:22:01
09:26:21
09:30:42
09:35:04
09:39:27
09:43:48
09:48:09
09:52:32
09:56:53
10:01:15
10:05:39
10:10:03
10:14:25
10:18:47
10:23:10
10:27:33
10:31:54
10:36:15
10:40:38
10:45:45
10:49:21
10:53:42
10:58:04
11:02:25
11:06:48
11:11:10
11:15:31
11:19:54
11:24:15
Flux
[g/sec]
0.01
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.04
0.05
0.06
0.06
0.06
0.06
0.07
0.07
0.07
0.07
0.06
0.06
0.06
0.05
0.05
0.06
0.07
0.08
Wind Direction
[degrees]
37.8
23.0
14.1
9.3
11.7
9.7
13.6
10.2
8.2
3.7
4.8
352.7
345.9
350.5
349.4
357.6
2.8
1.6
359.6
356.6
347.5
348.2
353.6
352.8
1.8
7.2
13.9
7.8
3.0
Rotated Wind
Direction
[degrees]
72.8
58.0
49.1
44.3
46.7
44.7
48.6
45.2
43.2
38.7
39.8
27.7
20.9
25.5
24.4
32.6
37.8
36.6
34.6
31.6
22.5
23.2
28.6
27.8
36.8
42.2
48.9
42.8
38.0
Wind
Speed
1.1
1.3
1.4
1.2
1.5
1.4
1.3
1.4
1.5
1.4
1.6
1.8
1.8
1.8
1.7
1.6
1.6
1.4
1.3
1.3
1.2
1.2
1.4
1.5
1.5
1.5
1.7
1.5
1.6
CCF
1.00
0.76
0.88
0.85
0.87
0.92
0.93
0.85
0.78
0.95
1.00
0.88
1.00
0.96
0.91
0.90
0.86
0.96
0.60
0.58
0.75
0.93
0.98
0.92
0.74
0.98
0.96
0.93
0.91
A-76
-------
Time
11:28:37
11:32:58
11:37:20
11:41:42
11:46:04
11:50:26
11:54:47
11:59:10
12:03:32
12:07:55
12:12:18
12:16:41
12:21:05
12:25:27
12:29:51
12:34:14
12:38:36
12:42:59
12:47:21
12:51:45
12:56:05
13:00:28
13:04:50
13:09:12
13:13:35
13:17:58
13:22:20
13:26:42
13:31:05
13:35:27
Flux
[g/sec]
0.07
0.07
0.08
0.07
0.04
0.03
0.01
-0.01
-0.01
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.02
-0.01
-0.04
-0.01
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
9.6
2.1
351.4
356.5
25.2
72.1
140.1
135.5
155.5
164.2
139.9
128.3
85.0
63.5
50.9
63.5
85.6
209.7
203.9
198.5
163.5
109.9
88.1
77.4
61.7
41.7
310.3
227.3
231.8
318.5
Rotated Wind
Direction
[degrees]
44.6
37.1
26.4
31.5
60.2
107.1
175.1
170.5
190.5
199.2
174.9
163.3
120.0
98.5
85.9
98.5
120.6
244.7
238.9
233.5
198.5
144.9
123.1
112.4
96.7
76.7
345.3
262.3
266.8
353.5
Wind
Speed
1.7
1.4
1.3
1.0
0.7
0.4
0.5
1.1
1.4
1.3
0.9
0.9
0.9
1.1
1.1
0.8
0.2
0.6
0.7
0.5
0.6
0.8
1.0
1.3
1.3
0.8
0.3
0.5
0.3
0.2
CCF
1.00
0.46
0.29
0.88
0.86
0.87
0.91
0.98
0.95
0.93
0.95
0.99
0.96
0.96
0.98
1.00
1.00
0.00
0.00
0.00
0.00
0.69
0.09
0.89
0.98
0.00
0.00
0.99
0.00
0.99
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-77
-------
Time
13:39:50
13:44:12
13:48:34
13:52:57
13:57:19
14:01:41
14:06:02
14:10:24
14:14:47
14:19:09
14:23:30
14:27:51
14:32:13
14:36:36
14:40:58
14:45:20
14:49:41
14:54:04
14:58:25
15:02:48
15:07:09
15:11:31
15:15:52
15:20:15
15:24:37
15:29:00
15:33:21
15:37:43
15:42:06
15:46:30
Flux
[g/sec]
0.01
0.03
0.03
0.03
0.01
0.00
0.00
-0.01
-0.01
-0.01
-0.01
0.00
0.01
0.01
0.01
0.02
0.03
0.04
0.05
0.05
0.05
0.05
0.05
0.05
0.06
0.09
0.10
0.08
0.09
0.09
Wind Direction
[degrees]
23.5
11.1
358.3
338.7
320.0
240.0
223.4
163.1
133.1
156.4
206.6
233.9
259.4
263.9
295.6
318.9
327.4
342.7
345.6
339.0
343.0
330.0
332.6
337.6
353.6
349.2
359.1
358.3
350.8
345.5
Rotated Wind
Direction
[degrees]
58.5
46.1
33.3
13.7
355.0
275.0
258.4
198.1
168.1
191.4
241.6
268.9
294.4
298.9
330.6
353.9
2.4
17.7
20.6
14.0
18.0
5.0
7.6
12.6
28.6
24.2
34.1
33.3
25.8
20.5
Wind
Speed
2.0
2.9
2.3
1.8
1.2
1.3
1.0
0.8
0.9
0.8
1.2
1.4
2.0
2.3
2.0
2.0
1.5
1.6
1.7
1.6
1.5
1.7
1.5
1.9
1.8
2.1
2.5
2.2
2.3
2.6
CCF
0.84
0.85
0.85
0.92
0.99
0.99
0.99
0.98
0.96
0.97
0.98
1.00
1.00
1.00
0.87
0.89
0.99
1.00
0.99
0.99
1.00
0.99
0.96
0.97
0.97
0.99
0.99
1.00
1.00
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-78
-------
Time
15:50:51
15:55:13
15:59:37
16:04:00
16:08:24
16:12:47
16:17:09
16:21:32
16:25:54
16:30:18
16:34:42
16:39:03
16:43:26
16:47:48
16:52:12
Flux
[g/sec]
0.09
0.08
0.08
0.07
0.06
0.05
0.05
0.04
0.03
0.02
0.01
0.01
0.02
0.03
0.02
Wind Direction
[degrees]
339.7
333.1
341.3
341.6
346.1
346.7
327.3
313.6
292.1
277.5
272.5
263.0
292.8
317.8
309.8
Rotated Wind
Direction
[degrees]
14.7
8.1
16.3
16.6
21.1
21.7
2.3
348.6
327.1
312.5
307.5
298.0
327.8
352.8
344.8
Wind
Speed
2.7
2.7
2.8
2.9
2.7
2.8
2.2
2.2
2.2
2.6
2.7
2.3
1.7
2.2
2.2
CCF
0.99
0.97
0.90
0.91
0.96
0.97
0.94
0.97
0.99
0.99
0.99
1.00
0.89
0.99
0.99
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-79
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-28. Summary Data Table of VRPM Plane E123 for August 14, 2008 at the EnCana Benzel Facility
Time
09:22:29
09:27:55
09:32:18
09:36:43
09:41:07
09:45:32
09:49:55
09:54:20
09:58:44
10:03:09
10:07:32
10:11:57
10:16:24
10:20:48
10:25:12
10:29:38
10:34:05
10:38:30
10:42:56
10:47:22
10:51:48
10:56:14
11:00:40
11:05:07
11:09:33
11:13:59
11:18:23
11:22:50
11:27:15
11:31:40
11:36:05
11:40:31
11:44:56
Flux
[g/sec]
-0.01
-0.01
-0.01
Wind Direction
[degrees]
34.7
17.4
15.2
12.2
11.1
6.6
12.8
13.8
3.1
5.4
358.5
350.4
345.7
351.5
353.6
0.5
1.8
358.6
0.4
349.8
347.7
351.2
354.9
357.1
4.7
11.3
9.0
6.1
8.6
2.2
353.1
349.6
26.5
Rotated Wind
Direction
[degrees]
216.7
199.4
197.2
194.2
193.1
188.6
194.8
195.8
185.1
187.4
180.5
172.4
167.7
173.5
175.6
182.5
183.8
180.6
182.4
171.8
169.7
173.2
176.9
179.1
186.7
193.3
191.0
188.1
190.6
184.2
175.1
171.6
208.5
Wind
Speed
1.2
1.4
1.2
1.3
1.4
1.3
1.3
1.5
1.4
1.5
1.7
1.9
1.8
1.9
1.7
1.6
1.5
1.4
1.2
1.2
1.1
1.3
1.5
1.5
1.5
1.8
1.6
1.6
1.7
1.5
1.3
1.1
0.8
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.24
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.57
0.95
0.00
0.00
0.00
0.00
A-80
-------
Time
11:49:22
11:53:47
11:58:13
12:02:39
12:07:01
12:11:27
12:15:54
12:20:19
12:24:45
12:29:08
12:33:34
12:37:59
12:42:25
12:46:51
12:51:13
12:55:39
13:00:05
13:04:32
13:08:57
13:13:18
13:17:44
13:22:10
13:26:36
13:31:01
13:35:26
13:39:50
13:44:15
13:48:40
13:53:04
13:57:29
14:01:53
14:06:19
14:10:44
14:15:11
14:19:36
Flux
[g/sec]
-0.01
-0.01
0.00
0.00
0.00
-0.01
-0.01
-0.01
-0.01
-0.01
-0.03
-0.03
0.00
0.00
0.00
0.00
0.01
0.00
0.00
-0.01
0.00
0.00
-0.02
0.00
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.02
-0.05
-0.01
-0.01
Wind Direction
[degrees]
52.2
136.0
137.7
151.6
165.8
146.4
133.1
90.1
68.7
52.3
63.7
66.3
209.4
203.1
197.9
167.5
116.2
88.2
78.0
63.0
42.2
317.2
228.6
229.9
318.7
23.3
11.1
357.7
338.5
318.3
238.5
222.1
159.0
133.6
159.6
Rotated Wind
Direction
[degrees]
234.2
318.0
319.7
333.6
347.8
328.4
315.1
272.1
250.7
234.3
245.7
248.3
31.4
25.1
19.9
349.5
298.2
270.2
260.0
245.0
224.2
139.2
50.6
51.9
140.7
205.3
193.1
179.7
160.5
140.3
60.5
44.1
341.0
315.6
341.6
Wind
Speed
0.4
0.3
1.0
1.4
1.4
0.9
0.9
0.8
1.1
1.2
0.8
0.3
0.6
0.7
0.6
0.6
0.8
1.0
1.2
1.3
0.9
0.3
0.5
0.3
0.2
1.9
2.9
2.3
1.8
1.1
1.3
0.9
0.9
0.9
0.8
CCF
0.04
0.01
0.01
0.02
0.02
0.96
0.95
1.00
0.93
0.01
0.75
0.19
0.00
0.00
0.00
0.00
0.97
0.87
0.79
0.94
0.00
0.00
0.03
0.00
0.01
0.01
1.00
0.90
1.00
0.75
0.66
0.81
0.86
0.22
0.61
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-81
-------
Time
14:24:02
14:28:27
14:32:52
14:37:17
14:41:40
14:46:05
14:50:30
14:54:54
14:59:17
15:03:42
15:08:07
15:12:33
15:16:55
15:21:20
15:25:44
15:30:08
15:34:32
15:38:54
15:43:18
15:47:40
15:52:04
15:56:27
16:00:50
16:05:13
16:09:38
16:14:02
Flux
[g/sec]
0.01
0.03
0.02
0.02
0.00
0.00
Wind Direction
[degrees]
211.9
237.1
261.6
269.0
299.6
319.0
331.7
346.4
345.3
336.4
340.9
327.8
334.8
337.7
350.1
350.7
3.0
352.6
348.3
344.1
337.1
337.0
341.3
344.0
347.6
343.2
Rotated Wind
Direction
[degrees]
33.9
59.1
83.6
91.0
121.6
141.0
153.7
168.4
167.3
158.4
162.9
149.8
156.8
159.7
172.1
172.7
185.0
174.6
170.3
166.1
159.1
159.0
163.3
166.0
169.6
165.2
Wind
Speed
1.3
1.4
2.1
2.3
1.9
1.9
1.4
1.7
1.6
1.6
1.6
1.6
1.6
2.0
1.8
2.1
2.5
2.0
2.4
2.6
2.7
2.8
2.8
2.9
2.7
2.7
CCF
0.95
0.84
0.70
0.71
0.99
0.88
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-82
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-29. Summary Data Table of VRPM Plane E456 for August 14, 2008 at the EnCana Benzel Facility
Time
09:25:41
09:30:05
09:34:31
09:38:54
09:43:18
09:47:42
09:52:07
09:56:32
10:00:55
10:05:20
10:09:45
10:14:11
10:18:35
10:22:59
10:27:24
10:31:51
10:36:17
10:40:44
10:45:09
10:49:35
10:54:01
10:58:27
11:02:53
11:07:19
11:11:44
11:16:09
11:20:35
11:25:01
11:29:27
11:33:51
11:38:17
11:42:42
11:47:08
Flux
[g/sec]
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
25.3
14.5
9.1
12.8
10.1
13.0
10.1
8.4
4.1
5.1
352.7
345.8
350.4
349.3
357.2
2.3
1.3
359.8
356.3
347.3
347.9
354.9
353.0
1.7
8.5
12.9
6.9
4.2
7.5
0.8
348.2
6.1
30.4
Rotated Wind
Direction
[degrees]
140.3
129.5
124.1
127.8
125.1
128.0
125.1
123.4
119.1
120.1
107.7
100.8
105.4
104.3
112.2
117.3
116.3
114.8
111.3
102.3
102.9
109.9
108.0
116.7
123.5
127.9
121.9
119.2
122.5
115.8
103.2
121.1
145.4
Wind
Speed
1.3
1.4
1.2
1.5
1.4
1.3
1.4
1.5
1.4
1.6
1.8
1.8
1.8
1.7
1.6
1.6
1.4
1.3
1.3
1.2
1.2
1.4
1.5
1.4
1.6
1.7
1.5
1.6
1.6
1.4
1.2
0.9
0.6
CCF
0.00
0.00
0.00
0.73
0.00
0.00
0.00
0.00
0.00
0.91
0.85
0.77
0.78
0.80
0.77
0.87
0.88
0.87
0.83
0.67
1.00
0.81
0.57
0.30
0.80
0.76
0.47
0.81
0.80
0.87
1.00
0.75
0.81
A-83
-------
Time
11:51:33
11:55:59
12:00:25
12:04:51
12:09:14
12:13:40
12:18:05
12:22:32
12:26:54
12:31:20
12:35:46
12:40:12
12:44:38
12:49:04
12:53:26
12:57:51
13:02:17
13:06:42
13:11:04
13:15:31
13:19:57
13:24:23
13:28:48
13:33:12
13:37:36
13:42:01
13:46:27
13:50:52
13:55:17
13:59:41
14:04:05
14:08:30
14:12:57
14:17:23
14:21:47
Flux
[g/sec]
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
-0.02
-0.02
-0.02
-0.03
-0.02
-0.02
-0.03
-0.01
Wind Direction
[degrees]
93.4
143.5
140.0
163.9
158.7
134.2
117.6
80.2
54.4
59.7
64.6
189.1
208.9
206.6
184.5
150.2
97.2
81.2
68.6
51.4
14.0
232.0
227.6
257.0
23.6
18.7
10.5
346.3
336.3
275.6
228.7
200.8
136.3
137.0
188.9
Rotated Wind
Direction
[degrees]
208.4
258.5
255.0
278.9
273.7
249.2
232.6
195.2
169.4
174.7
179.6
304.1
323.9
321.6
299.5
265.2
212.2
196.2
183.6
166.4
129.0
347.0
342.6
12.0
138.6
133.7
125.5
101.3
91.3
30.6
343.7
315.8
251.3
252.0
303.9
Wind
Speed
0.3
0.7
1.2
1.4
1.2
0.9
0.9
0.9
1.2
0.9
0.6
0.3
0.6
0.6
0.6
0.7
1.0
1.1
1.3
1.3
0.4
0.3
0.4
0.3
0.9
2.6
2.7
2.1
1.6
1.0
1.1
0.7
0.9
0.7
0.8
CCF
0.82
0.95
0.96
0.96
0.97
0.89
0.91
0.93
0.96
0.90
0.93
0.90
0.00
0.00
0.00
0.98
0.89
0.85
0.99
0.41
0.00
0.00
0.92
0.00
0.99
0.98
0.96
0.40
0.50
0.63
0.79
0.88
0.67
0.93
1.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-84
-------
Time
14:26:13
14:30:38
14:35:03
14:39:28
14:43:51
14:48:18
14:52:41
14:57:05
15:01:30
15:05:53
15:10:19
15:14:44
15:19:06
15:23:30
15:27:54
15:32:20
15:36:42
15:41:05
15:45:29
15:49:51
15:54:15
15:58:37
16:03:00
16:07:26
16:11:49
16:16:14
Flux
[g/sec]
0.00
0.04
0.08
0.05
0.02
0.01
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
Wind Direction
[degrees]
225.4
256.8
261.8
284.9
319.5
320.4
340.6
345.4
344.5
342.7
333.4
330.2
340.2
348.1
350.5
357.7
3.4
351.4
346.7
341.1
331.7
341.0
340.6
343.6
347.1
328.6
Rotated Wind
Direction
[degrees]
340.4
11.8
16.8
39.9
74.5
75.4
95.6
100.4
99.5
97.7
88.4
85.2
95.2
103.1
105.5
112.7
118.4
106.4
101.7
96.1
86.7
96.0
95.6
98.6
102.1
83.6
Wind
Speed
1.5
1.7
2.3
2.1
2.0
1.7
1.5
1.8
1.5
1.6
1.8
1.5
1.8
1.7
2.0
2.4
2.3
2.2
2.6
2.6
2.7
2.9
2.8
2.6
2.8
2.3
CCF
0.97
0.79
0.94
0.85
0.94
1.00
1.00
0.99
1.00
1.00
0.83
1.00
0.96
1.00
0.94
0.99
0.92
0.98
0.85
0.93
1.00
1.00
0.50
1.00
0.89
0.94
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-85
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-30. Summary Data Table of VRPM Plane A123 for August 15, 2008 at the EnCana Benzel Facility
Time
09:29:09
09:34:31
09:38:53
09:43:15
09:47:39
09:52:01
09:56:23
10:00:45
10:05:08
10:09:30
10:13:50
10:18:12
10:22:33
10:26:54
10:31:15
10:35:36
10:40:01
10:44:21
10:48:41
10:53:01
10:57:24
11:01:46
11:06:07
11:10:30
11:14:51
11:19:13
11:23:36
11:27:57
11:32:19
11:36:42
11:41:05
11:45:27
11:49:50
Flux
[g/sec]
0.04
0.05
0.06
0.05
0.07
0.06
0.05
0.05
0.04
0.04
0.04
0.07
0.06
0.05
0.06
0.05
0.04
0.04
0.07
0.07
0.06
0.06
0.07
0.06
0.03
0.04
0.06
0.07
0.07
0.09
0.05
0.02
0.01
Wind Direction
[degrees]
60.9
41.7
48.3
67.1
74.3
64.6
73.2
72.0
53.1
45.5
28.7
16.5
4.8
1.6
8.4
31.8
32.6
34.1
45.3
37.9
42.0
55.0
55.6
57.5
52.2
35.8
29.8
21.9
17.2
14.9
19.2
2.1
352.0
Rotated Wind
Direction
[degrees]
356.9
337.7
344.3
3.1
10.3
0.6
9.2
8.0
349.1
341.5
324.7
312.5
300.8
297.6
304.4
327.8
328.6
330.1
341.3
333.9
338.0
351.0
351.6
353.5
348.2
331.8
325.8
317.9
313.2
310.9
315.2
298.1
288.0
Wind
Speed
0.8
1.0
0.9
0.8
1.2
1.2
1.2
1.2
1.5
1.3
1.5
1.7
1.5
1.5
1.4
1.1
1.2
1.3
1.4
1.3
1.2
1.3
1.4
1.5
1.6
1.5
1.5
1.6
1.6
2.0
2.0
2.3
2.2
CCF
0.99
0.98
0.91
1.00
1.00
0.69
0.80
0.98
0.76
0.79
0.60
0.59
0.88
0.94
0.81
0.70
0.74
0.86
0.98
0.71
0.14
0.95
0.99
0.85
0.95
0.94
0.98
0.95
0.92
0.90
1.00
0.95
0.95
A-86
-------
Time
11:54:11
11:58:33
12:02:56
12:07:17
12:11:40
12:16:02
12:20:23
12:24:46
12:29:08
12:33:30
12:37:51
12:42:13
12:46:35
12:50:56
12:55:18
12:59:36
13:03:58
13:08:18
13:12:41
13:17:00
13:21:22
13:25:43
13:30:06
13:34:28
13:38:49
13:43:13
13:47:34
13:51:55
13:56:17
14:00:41
Flux
[g/sec]
0.01
0.00
0.00
0.01
0.01
0.01
0.01
0.01
Wind Direction
[degrees]
351.9
345.4
339.4
348.2
335.5
316.0
310.4
302.7
302.6
316.4
320.0
333.3
348.4
351.5
346.3
346.7
351.6
347.0
347.4
342.5
340.5
341.4
344.8
348.2
347.5
346.6
344.1
343.1
341.0
344.7
Rotated Wind
Direction
[degrees]
287.9
281.4
275.4
284.2
271.5
252.0
246.4
238.7
238.6
252.4
256.0
269.3
284.4
287.5
282.3
282.7
287.6
283.0
283.4
278.5
276.5
277.4
280.8
284.2
283.5
282.6
280.1
279.1
277.0
280.7
Wind
Speed
2.5
2.4
2.4
2.3
2.0
1.9
1.7
1.8
2.4
1.8
1.3
1.4
2.1
2.4
3.0
3.6
4.1
3.8
3.7
3.8
3.7
3.6
3.9
4.1
4.3
4.8
4.7
4.7
4.8
5.0
CCF
1.00
1.00
0.93
0.65
0.45
0.01
0.01
0.08
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-87
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-31. Summary Data Table of VRPM Plane A456 for August 15, 2008 at the EnCana Benzel Facility
Time
09:32:20
09:36:42
09:41:04
09:45:28
09:49:50
09:54:11
09:58:34
10:02:56
10:07:18
10:11:40
10:16:01
10:20:23
10:24:44
10:29:05
10:33:25
10:37:48
10:42:10
10:46:30
10:50:51
10:55:13
10:59:35
11:03:57
11:08:19
11:12:40
11:17:03
11:21:25
11:25:47
11:30:09
11:34:31
11:38:53
11:43:16
11:47:37
11:52:01
Flux
[g/sec]
-0.01
-0.01
-0.01
0.00
0.00
0.01
0.00
0.01
0.01
0.01
0.01
0.02
0.01
0.02
0.01
0.02
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.02
0.02
0.03
0.04
0.06
0.07
Wind Direction
[degrees]
41.1
38.1
50.0
72.4
69.2
65.1
77.8
61.5
45.9
38.2
21.5
9.6
4.6
355.4
17.8
34.9
33.5
37.9
41.3
33.3
53.2
50.8
53.9
58.0
41.7
26.5
25.9
18.0
16.2
15.5
13.5
356.8
350.6
Rotated Wind
Direction
[degrees]
76.1
73.1
85.0
107.4
104.2
100.1
112.8
96.5
80.9
73.2
56.5
44.6
39.6
30.4
52.8
69.9
68.5
72.9
76.3
68.3
88.2
85.8
88.9
93.0
76.7
61.5
60.9
53.0
51.2
50.5
48.5
31.8
25.6
Wind
Speed
1.0
0.9
0.8
1.1
1.2
1.2
1.2
1.4
1.4
1.3
1.7
1.6
1.5
1.4
1.1
1.0
1.3
1.3
1.2
1.2
1.1
1.3
1.5
1.5
1.5
1.6
1.5
1.7
1.7
2.1
2.2
2.1
2.5
CCF
0.82
1.00
1.00
0.98
0.93
0.78
0.98
0.95
0.86
0.99
0.89
0.88
0.97
1.00
0.88
0.98
1.00
0.86
0.84
0.00
0.97
0.99
0.99
0.99
0.99
0.96
0.97
1.00
0.99
0.89
0.98
0.82
1.00
A-88
-------
Time
11:56:23
12:00:45
12:05:06
12:09:29
12:13:51
12:18:13
12:22:35
12:26:57
12:31:19
12:35:41
12:40:02
12:44:25
12:48:45
12:53:07
12:57:27
13:01:48
13:06:08
13:10:28
13:14:51
13:19:11
13:23:33
13:27:55
13:32:17
13:36:39
13:41:02
13:45:24
13:49:44
13:54:07
13:58:29
14:02:52
Flux
[g/sec]
0.06
0.07
0.07
0.05
0.05
0.04
0.03
0.03
0.03
0.02
0.03
0.03
0.04
0.04
0.04
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.04
0.04
0.04
0.04
Wind Direction
[degrees]
350.0
340.6
342.2
347.0
320.4
314.3
304.1
296.0
309.6
319.8
329.9
342.2
353.7
347.4
347.9
352.1
349.3
346.2
343.4
342.9
339.9
342.5
344.0
349.7
347.2
345.8
342.7
343.6
344.7
339.0
Rotated Wind
Direction
[degrees]
25.0
15.6
17.2
22.0
355.4
349.3
339.1
331.0
344.6
354.8
4.9
17.2
28.7
22.4
22.9
27.1
24.3
21.2
18.4
17.9
14.9
17.5
19.0
24.7
22.2
20.8
17.7
18.6
19.7
14.0
Wind
Speed
2.3
2.5
2.2
2.1
1.8
1.7
1.8
2.2
2.1
1.5
1.3
1.7
2.2
2.8
3.4
3.8
3.9
3.7
3.7
3.8
3.5
3.8
4.1
4.3
4.6
4.8
4.6
5.0
5.0
5.0
CCF
0.98
0.89
0.66
0.81
0.80
0.98
1.00
0.99
0.98
0.98
0.94
0.96
0.96
0.95
0.99
0.97
0.99
0.99
0.99
1.00
0.99
0.97
1.00
0.99
0.98
1.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-89
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-32. Summary Data Table of VRPM Plane E123 for August 15, 2008 at the EnCana Benzel Facility
Time
09:46:14
09:51:26
09:55:38
09:59:51
10:04:03
10:08:16
10:12:28
10:16:41
10:20:53
10:25:06
10:29:18
10:33:31
10:37:44
10:41:56
10:46:09
10:50:21
10:54:34
10:58:47
11:03:03
11:07:12
11:11:26
11:15:38
11:19:51
11:24:03
11:28:16
11:32:29
11:36:41
11:40:54
11:45:06
11:49:19
11:53:31
11:57:44
12:01:57
Flux
[g/sec]
Wind Direction
[degrees]
72.6
66.1
71.3
77.1
56.4
45.8
35.8
20.0
7.6
3.5
354.6
18.9
36.4
33.3
38.2
42.7
35.2
49.0
51.7
53.7
56.6
49.5
31.3
27.8
20.8
16.8
15.4
19.3
2.7
352.9
351.4
347.4
340.5
Rotated Wind
Direction
[degrees]
254.6
248.1
253.3
259.1
238.4
227.8
217.8
202.0
189.6
185.5
176.6
200.9
218.4
215.3
220.2
224.7
217.2
231.0
233.7
235.7
238.6
231.5
213.3
209.8
202.8
198.8
197.4
201.3
184.7
174.9
173.4
169.4
162.5
Wind
Speed
1.2
1.2
1.2
1.2
1.5
1.4
1.3
1.7
1.6
1.4
1.4
1.1
1.0
1.3
1.3
1.2
1.3
1.2
1.3
1.5
1.5
1.5
1.5
1.5
1.6
1.7
2.0
1.9
2.3
2.1
2.3
2.4
2.4
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
A-90
-------
Time
12:06:09
12:10:22
12:14:35
12:18:47
12:23:01
12:27:13
12:31:26
12:35:38
12:39:52
12:44:04
12:48:17
12:52:30
12:56:42
13:00:56
13:05:08
13:09:21
13:13:33
13:17:47
13:22:00
13:26:14
13:30:27
13:34:39
13:38:53
13:43:07
13:47:19
13:51:32
13:55:45
14:00:03
14:04:15
Flux
[g/sec]
-0.01
-0.01
-0.02
-0.02
-0.02
-0.02
-0.02
Wind Direction
[degrees]
344.6
343.3
316.1
313.9
304.1
293.8
311.3
319.1
330.6
338.6
353.7
346.6
347.6
350.4
349.9
346.1
346.1
342.8
338.8
341.7
343.9
349.7
347.9
346.2
344.3
343.9
341.7
345.6
339.2
Rotated Wind
Direction
[degrees]
166.6
165.3
138.1
135.9
126.1
115.8
133.3
141.1
152.6
160.6
175.7
168.6
169.6
172.4
171.9
168.1
168.1
164.8
160.8
163.7
165.9
171.7
169.9
168.2
166.3
165.9
163.7
167.6
161.2
Wind
Speed
2.3
2.1
1.8
1.7
1.9
2.3
2.1
1.5
1.2
1.7
2.2
2.7
3.3
3.7
3.9
3.8
3.8
3.8
3.6
3.7
4.0
4.1
4.4
4.7
4.8
4.7
4.9
5.0
5.0
CCF
0.00
0.00
0.00
1.00
1.00
0.00
0.00
0.00
0.10
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-91
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
Table A-33. Summary Data Table of VRPM Plane E456 for August 15, 2008 at the EnCana Benzel Facility
Time
09:49:18
09:53:31
09:57:43
10:01:57
10:06:09
10:10:22
10:14:34
10:18:47
10:22:59
10:27:11
10:31:24
10:35:36
10:39:49
10:44:02
10:48:14
10:52:27
10:56:40
11:00:52
11:05:05
11:09:18
11:13:31
11:17:44
11:21:56
11:26:09
11:30:21
11:34:34
11:38:47
11:42:59
11:47:12
11:51:24
11:55:37
11:59:49
12:04:02
Flux
[g/sec]
-0.02
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
70.3
63.0
77.1
64.6
49.0
44.3
26.3
13.7
4.2
359.9
8.4
32.9
33.9
34.7
44.2
41.7
37.1
59.0
55.2
54.1
56.5
40.8
27.3
24.0
17.2
17.3
15.4
14.2
357.1
350.2
352.6
343.0
343.2
Rotated Wind
Direction
[degrees]
185.3
178.0
192.1
179.6
164.0
159.3
141.3
128.7
119.2
114.9
123.4
147.9
148.9
149.7
159.2
156.7
152.1
174.0
170.2
169.1
171.5
155.8
142.3
139.0
132.2
132.3
130.4
129.2
112.1
105.2
107.6
98.0
98.2
Wind
Speed
1.2
1.2
1.1
1.4
1.5
1.3
1.6
1.7
1.4
1.5
1.4
1.1
1.2
1.2
1.3
1.2
1.3
1.2
1.3
1.5
1.5
1.5
1.6
1.5
1.7
1.7
2.1
2.3
2.1
2.5
2.3
2.6
2.3
CCF
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.37
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.99
0.97
0.96
0.97
A-92
-------
Time
12:08:15
12:12:27
12:16:40
12:20:53
12:25:06
12:29:18
12:33:31
12:37:45
12:41:57
12:46:10
12:50:23
12:54:35
12:58:49
13:03:01
13:07:14
13:11:26
13:15:40
13:19:53
13:24:06
13:28:19
13:32:31
13:36:46
13:40:59
13:45:12
13:49:24
13:53:38
13:57:56
14:02:08
14:06:21
Flux
[g/sec]
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
-0.01
0.00
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Wind Direction
[degrees]
349.0
330.1
314.5
308.5
299.5
300.7
316.7
319.9
335.4
346.2
353.4
346.9
346.9
353.2
346.6
349.5
340.6
340.6
340.4
343.1
345.4
349.3
347.3
345.1
342.5
343.0
344.8
342.4
340.8
Rotated Wind
Direction
[degrees]
104.0
85.1
69.5
63.5
54.5
55.7
71.7
74.9
90.4
101.2
108.4
101.9
101.9
108.2
101.6
104.5
95.6
95.6
95.4
98.1
100.4
104.3
102.3
100.1
97.5
98.0
99.8
97.4
95.8
Wind
Speed
2.3
2.0
1.8
1.8
1.9
2.3
1.7
1.3
1.4
1.9
2.4
2.9
3.6
4.0
3.8
3.8
3.7
3.8
3.5
3.8
4.1
4.2
4.6
4.7
4.6
4.9
4.9
5.1
4.9
CCF
0.87
0.88
0.99
0.89
1.00
1.00
1.00
0.99
0.93
1.00
0.96
0.99
0.98
0.99
1.00
1.00
0.87
0.97
1.00
0.99
0.84
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
A-93
-------
Appendix A
Measurement of Emissions from
Produced Water Ponds
October 2009 (Rev. 0.6)
This page intentionally left blank.
A-94
-------
Appendix B
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Appendix B: ERG SUM MA Canister Data
B-1
-------
Appendix B
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
This page intentionally left blank.
B-2
-------
Eastern Research Group
601 Keystone Park Drive
Suite 700
Morrisville, NC 27560
September 24, 2008
Mark Modrak
ARCADIS
4915 Prospectus Drive
Durham, NC 27713
Project Name: Lagoon
Dear Mark Modrak,
This report contains the analytical results for the sample(s) received under chain(s) of custody
by Eastern Research Group on 08/21/08 08:11.
The test results in this report are in compliance with NELAC accreditation requirements for the
certified parameters. All analyses were performed as described in the US EPA-approved QAPP,
under the contract for NMOC, UATMP, PAMS, HAPS, and NATTS support (US EPA Contract No.
68-D-03-049). This cover page is an integral part of this report, and any exceptions or
comments are noted on the last page.
The issuance of the final Certificate of Analysis takes precedence over any previous Report. If
you have any questions, please contact me at 919-468-7930.
Sincerely,
Laura Van Enwyck
Program Manager
laura.vanenwyck@erg.com
The information contained in this report and its attachment(s) are intended only for the use of the individual to whom it is addressed
and may contain information that is privileged, confidential, or exempt from disclosure. If the reader of this message is not the
intended recipient, you are hereby notified that any dissemination, distribution, or copying of this report is strictly prohibited. If you
have received this report in error, please notify laura.vanenwyck@ erg.com and delete the report without retaining any copies.
Page 1 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
ANALYTICAL REPORT FOR SAMPLES
SampleName
ARCADIS TNAPC11
ARCADIS 926
ARCADIS 3639A
ARCADIS 648
ARCADIS ER038
ARCADIS ER001
ARCADIS ER047
ARCADIS C1 167604
ARCADIS C2 659
ARCADIS ER029
ARCADIS 3255
ARCADIS TNAPC20
ARCADIS C1 ER043
ARCADIS C2 444
ARCADIS C1 167601
ARCADIS C2 3254
ARCADIS ER061
ARCADIS 15280
ARCADIS C1 ER064
ARCADIS C2 ER069
ARCADIS C1 988
ARCADIS C2 3248
ARCADIS ER021
Eastern Research Group
LabNumber
8082101-04
8082101-05
8082101-06
8082101-07
8082101-08
8082101-09
8082101-10
8082101-11
8082101-12
8082101-13
8082101-14
8082101-15
8082101-16
8082101-17
8082101-18
8082101-19
8082101-20
8082101-21
8082101-22
8082101-23
8082101-24
8082101-25
8082101-26
Matrix
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Sampled
08/07/08 00:00
08/08/08 00:00
08/08/08 00:00
08/08/08 00:00
08/09/08 00:00
08/09/08 00:00
08/09/08 00:00
08/12/0800:00
08/12/0800:00
08/12/0800:00
08/13/08 12:07
08/13/08 16:52
08/13/0812:07
08/13/0812:07
08/13/08 16:52
08/13/08 16:52
08/14/0811:32
08/14/0817:09
08/1 4/08 1 1 :32
08/1 4/08 1 1 :32
08/14/0817:09
08/14/0817:09
08/15/08 12:09
Received
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 2 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
ARCADIS C1 ER114
ARCADIS C2 ER085
FAX: (919)544-5690
8082101-27
8082101-28
Air
Air
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
08/15/0812:09 08/21/0808:11
08/15/0812:09
08/21/0808:11
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 3 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS TNAPC11
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-04
Canister*: TNAPC11
Sampled: 08/07/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 15:15
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.517
0.415
0.459
0.723
0.046
ND
ND
ND
ND
ND
ND
0.205
ND
ND
ND
ND
0.107
ND
ND
ND
0.727
ND
ND
ND
ND
ND
ND
ND
203
0.054
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1210
ug/m3 Flag
0.55
0.72
2.27
1.50
0.32
ND U
ND U
ND U
ND U
ND U
ND U
1.15
ND U
ND U
ND U
ND U
0.82
ND U
ND U
ND U
2.15
ND U
ND U
ND U
ND U
ND U
ND U
ND U
650.00 D-01
0.34
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
4,570.00 D-01
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
1.43
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
3.28
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 4 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS TNAPC11
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-04
Canister*: TNAPC11
Sampled: 08/07/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 15:15
Air Toxics by EPA Compendium Method TO- 15
Results
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
ppbv
ND
ND
1160
ND
ND
216
2300
ND
ND
ND
411
395
388
ND
ND
ND
ND
ND
ND
ug/m3
ND
ND
5,430.00
ND
ND
940.00
10,000.00
ND
ND
ND
1,790.00
1,950.00
1,910.00
ND
ND
ND
ND
ND
ND
Flag
u
u
D-01
U
U
D-01
D-01, E
U
U
U
D-01
D-01
D-01
U
U
U
U
U
U
MDL
ppbv
0.040
0.056
0.714
0.048
0.064
1.14
2.71
0.040
0.168
0.072
1.14
2.28
2.28
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 5 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 926
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-05
Canister #: 926
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 16:19
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.330
0.177
0.505
0.644
ND
ND
ND
ND
ND
ND
ND
0.332
ND
ND
ND
ND
0.134
ND
ND
ND
0.700
ND
ND
ND
ND
ND
ND
ND
95.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
220
ug/m3
0.35
0.31
2.50
1.33
ND
ND
ND
ND
ND
ND
ND
1.87
ND
ND
ND
ND
1.03
ND
ND
ND
2.07
ND
ND
ND
ND
ND
ND
ND
304.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
831.00
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
D-01
u
u
u
u
u
u
u
u
u
u
u
D-01
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
1.04
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
2.40
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 6 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 926
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-05
Canister #: 926
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 16:19
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
74.9
0.042
ND
11.7
166
ND
ND
ND
24.6
22.3
20.8
ND
ND
ND
ND
ND
ND
ND
ND
351.00
0.29
ND
50.90
722.00
ND
ND
ND
107.00
110.00
102.00
ND
ND
ND
ND
ND
ND
u
u
D-01
U
U
D-01
U
U
U
0.040
0.056
0.522
0.048
0.064
0.064
1.98
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 7 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Ascription: ARCADIS 3639A
•ressure @ Receipt: 8" Hg
Comments:
Lab
ID: 8082101-06 Sampled: 08/08/08 00:00
Canister*: 3639A Received: 08/21/08 08:11
Air Toxics
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1, 1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
lethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.931
0.313
0.429
0.557
0.014
ND
0.029
ND
0.030
ND
0.395
0.246
ND
ND
0.073
0.037
0.081
ND
ND
ND
0.632
ND
ND
ND
ND
ND
ND
0.013
1.36
0.080
ND
ND
ND
ND
ND
ND
ND
0.057
ND
ND
4.78
ug/m3
0.99
0.54
2.13
1.15
0.10
ND
0.06
ND
0.08
ND
0.91
1.38
ND
ND
0.25
0.12
0.62
ND
ND
ND
1.87
ND
ND
ND
ND
ND
ND
0.07
4.35
0.50
ND
ND
ND
ND
ND
ND
ND
0.23
ND
ND
18.10
Analyzed: 08/27/08 17:26
by EPA Compendium Method TO- 15
MDL
Flag ppbv
0.018
0.038
0.010
0.016
0.006
U 0.010
0.010
U 0.008
0.008
U 0.044
0.040
0.006
U 0.018
U 0.010
0.036
0.008
0.014
U 0.010
U 0.014
U 0.010
0.056
U 0.014
U 0.014
U 0.012
U 0.014
U 0.010
U 0.018
0.010
0.020
0.008
U 0.026
U 0.020
U 0.042
U 0.014
U 0.008
U 0.024
U 0.014
0.032
U 0.030
U 0.016
0.046
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 8 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 3639A
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-06
Canister #: 3639A
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 17:26
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrach loroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1/2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.536
0.068
ND
0.566
2.32
ND
0.210
ND
0.788
0.284
0.767
ND
ND
ND
ND
ND
ND
ND
ND
2.51
0.46
ND
2.46
10.10
ND
0.90
ND
3.43
1.40
3.78
ND
ND
ND
ND
ND
ND
0.010
0.014
0.010
0.012
0.016
0.016
0.038
0.010
0.042
0.018
0.016
0.032
0.032
0.030
0.022
0.024
0.030
0.060
0.034
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 9 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 648
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-07
Canister #: 648
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 18:29
Analvte
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-1,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Air Toxics
Results
ppbv ug/m3
0.367 0.39
0.409 0.71
0.420 2.08
0.622 1.29
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
0.175 0.99
ND ND
ND ND
ND ND
ND ND
0.073 0.56
ND ND
ND ND
ND ND
0.998 2.95
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
82.6 264.00
0.047 0.30
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
222 838.00
by EPA Compendium Method TO-15
MDL
Flag ppbv
0.072
0.152
0.040
0.064
U 0.024
U 0.040
U 0.040
U 0.032
U 0.032
U 0.176
U 0.160
0.024
U 0.072
U 0.040
U 0.144
U 0.032
0.056
U 0.040
U 0.056
U 0.040
0.224
U 0.056
U 0.056
U 0.048
U 0.056
U 0.040
U 0.072
U 0.040
D-01 0.876
0.032
U 0.104
U 0.080
U 0.168
U 0.056
U 0.032
U 0.096
U 0.056
U 0.128
U 0.120
U 0.064
D-01 2.01
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 10 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
491 5 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX:
Description: ARCADIS 648
Pressure @ Receipt: 8" Hg
Comments:
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
(91 9) 544-5690 SITE CODE:
Lab ID: 8082101-07
Canister #: 648
Lagoon
Sampled:
Received:
Analyzed:
08/08/08 00:00
08/21/0808:11
08/27/08 18:29
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
70.3
ND
ND
10.5
142
ND
0.145
ND
21.0
17.8
16.7
ND
ND
ND
ND
ND
ND
ND
ND
329.00
ND
ND
45.70
618.00
ND
0.62
ND
91.40
87.70
82.30
ND
ND
ND
ND
ND
ND
u
u
D-01
U
U
D-01
U
U
U
0.040
0.056
0.438
0.048
0.064
0.064
1.66
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 11 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER038
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-08
Canister #: ER038
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 19:35
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.192
0.197
0.451
0.705
0.012
ND
ND
0.010
ND
ND
0.380
0.201
ND
ND
0.050
0.031
0.071
ND
ND
ND
0.663
ND
ND
ND
ND
ND
ND
0.009
0.547
0.086
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.18
ug/m3 Flag
0.21
0.34
2.24
1.46
0.08
ND U
ND U
0.04
ND U
ND U
0.87
1.13
ND U
ND U
0.17
0.10
0.55
ND U
ND U
ND U
1.96
ND U
ND U
ND U
ND U
ND U
ND U
0.05 U
1.75
0.54
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
4.46
MDL
ppbv
0.018
0.038
0.010
0.016
0.006
0.010
0.010
0.008
0.008
0.044
0.040
0.006
0.018
0.010
0.036
0.008
0.014
0.010
0.014
0.010
0.056
0.014
0.014
0.012
0.014
0.010
0.018
0.010
0.020
0.008
0.026
0.020
0.042
0.014
0.008
0.024
0.014
0.032
0.030
0.016
0.046
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 12 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER038
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-08
Canister #: ER038
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 19:35
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrach loroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1/2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.461
0.031
ND
0.072
0.563
ND
ND
ND
0.115
0.098
0.142
ND
ND
ND
ND
ND
ND
ND
ND
2.16
0.21
ND
0.31
2.45
ND
ND
ND
0.50
0.48
0.70
ND
ND
ND
ND
ND
ND
0.010
0.014
0.010
0.012
0.016
0.016
0.038
0.010
0.042
0.018
0.016
0.032
0.032
0.030
0.022
0.024
0.030
0.060
0.034
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 13 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER001
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-09
Canister #: ER001
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 20:38
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.377
0.571
0.393
0.667
ND
ND
ND
ND
ND
ND
ND
0.203
ND
ND
ND
ND
0.112
ND
ND
ND
0.928
ND
ND
ND
ND
ND
ND
ND
0.628
0.107
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.11
ug/m3
0.40
0.99
1.95
1.38
ND
ND
ND
ND
ND
ND
ND
1.14
ND
ND
ND
ND
0.86
ND
ND
ND
2.74
ND
ND
ND
ND
ND
ND
ND
2.01
0.68
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.19
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 14 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER001
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-09
Canister #: ER001
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 20:38
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.380
ND
ND
0.087
0.559
ND
0.111
ND
0.134
0.106
0.148
ND
ND
ND
ND
ND
ND
ND
ND
1.78
ND
ND
0.38
2.43
ND
0.47
ND
0.58
0.52
0.73
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 15 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER047
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-10
Canister #: ER047
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 21:42
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.391
0.302
0.471
0.644
ND
ND
ND
ND
ND
ND
ND
0.219
ND
ND
ND
ND
0.078
ND
ND
ND
0.765
ND
ND
ND
ND
ND
ND
ND
8.13
0.086
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.7
ug/m3 Flag
0.42
0.52
2.33
1.33
ND U
ND U
ND U
ND U
ND U
ND U
ND U
1.23
ND U
ND U
ND U
ND U
0.60
ND U
ND U
ND U
2.26
ND U
ND U
ND U
ND U
ND U
ND U
ND U
26.00
0.54
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
63.10
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 16 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER047
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-10
Canister #: ER047
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 21:42
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
11.6
ND
ND
0.855
13.5
ND
ND
ND
2.19
2.61
1.72
ND
ND
ND
ND
ND
ND
ND
ND
54.30
ND
ND
3.72
58.70
ND
ND
ND
9.53
12.90
8.47
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 17 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 167604
Pressure @ Receipt: 8" Hg
Comments: Col 1 w/659 - downwind
Lab ID: 8082101-11
Canister #: 167604
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 22:45
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.377
0.125
0.392
0.571
ND
ND
ND
ND
ND
ND
ND
0.218
ND
ND
ND
ND
0.070
ND
ND
ND
0.439
ND
ND
ND
ND
ND
ND
ND
2.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.41
ug/m3 Flag
0.40
0.22 U
1.94
1.18
ND U
ND U
ND U
ND U
ND U
ND U
ND U
1.23
ND U
ND U
ND U
ND U
0.54
ND U
ND U
ND U
1.30
ND U
ND U
ND U
ND U
ND U
ND U
ND U
6.72
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
12.90
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 18 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 167604
Pressure @ Receipt: 8" Hg
Comments: Col 1 w/659 - downwind
Lab ID: 8082101-11
Canister #: 167604
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 22:45
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.815
ND
ND
0.235
1.74
ND
ND
ND
0.391
0.259
0.326
ND
ND
ND
ND
ND
ND
ND
ND
3.82
ND
ND
1.02
7.57
ND
ND
ND
1.70
1.28
1.61
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 19 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 659
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167604 - downwind
Lab ID: 8082101-12
Canister #: 659
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 00:51
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.437
0.269
0.394
0.547
ND
ND
ND
ND
ND
ND
ND
0.220
ND
ND
ND
ND
0.082
ND
ND
ND
0.422
ND
ND
ND
ND
ND
ND
ND
2.54
0.061
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.01
ug/m3
0.47
0.46
1.95
1.13
ND
ND
ND
ND
ND
ND
ND
1.24
ND
ND
ND
ND
0.63
ND
ND
ND
1.25
ND
ND
ND
ND
ND
ND
ND
8.13
0.39
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.10
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 20 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 659
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167604 - downwind
Lab ID: 8082101-12
Canister #: 659
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 00:51
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.914
ND
ND
0.312
2.05
ND
ND
ND
0.514
0.314
0.398
ND
ND
ND
ND
ND
ND
ND
ND
4.28
ND
ND
1.36
8.92
ND
ND
ND
2.24
1.55
1.96
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 21 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER029
Pressure @ Receipt: 8" Hg
Comments: upwind canister
Lab ID: 8082101-13
Canister #: ER029
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 02:58
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.792
0.315
0.423
0.666
ND
ND
ND
ND
ND
ND
ND
0.219
ND
ND
ND
ND
0.141
ND
ND
ND
0.593
ND
ND
ND
ND
ND
ND
ND
0.491
0.095
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.07
ug/m3
0.85
0.54
2.10
1.38
ND
ND
ND
ND
ND
ND
ND
1.23
ND
ND
ND
ND
1.08
ND
ND
ND
1.75
ND
ND
ND
ND
ND
ND
ND
1.57
0.60
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.04
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 22 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER029
Pressure @ Receipt: 8" Hg
Comments: upwind canister
Lab ID: 8082101-13
Canister #: ER029
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 02:58
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrach loroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1/2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.595
0.057
ND
0.152
0.971
ND
ND
ND
0.263
0.150
0.218
ND
ND
ND
ND
ND
ND
ND
ND
2.79
0.39
ND
0.66
4.23
ND
ND
ND
1.14
0.74
1.07
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 23 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 3255
Pressure @ Receipt: 8" Hg
Comments: upwind
Lab ID: 8082101-14
Canister #: 3255
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 04:01
Analvte
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trich lorotrif luoroetha ne
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-1,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Air Toxics
Results
ppbv ug/m3
0.709 0.76
0.424 0.73
0.428 2.12
0.651 1.35
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
0.249 1.40
ND ND
ND ND
ND ND
ND ND
ND ND
0.050 0.20
ND ND
ND ND
0.754 2.23
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
0.339 1.09
0.103 0.65
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
0.690 2.61
by EPA Compendium Method TO-15
MDL
Flag ppbv
0.072
0.152
0.040
0.064
U 0.024
U 0.040
U 0.040
U 0.032
U 0.032
U 0.176
U 0.160
0.024
U 0.072
U 0.040
U 0.144
U 0.032
U 0.056
0.040
U 0.056
U 0.040
0.224
U 0.056
U 0.056
U 0.048
U 0.056
U 0.040
U 0.072
U 0.040
0.080
0.032
U 0.104
U 0.080
U 0.168
U 0.056
U 0.032
U 0.096
U 0.056
U 0.128
U 0.120
U 0.064
0.184
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 24 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
491 5 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX:
Description: ARCADIS 3255
Pressure @ Receipt: 8" Hg
Comments: upwind
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
(91 9) 544-5690 SITE CODE:
Lab ID: 8082101-14
Canister #: 3255
Lagoon
Sampled:
Received:
Analyzed:
08/13/08 12:07
08/21/0808:11
08/28/08 04:01
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.373
0.040
ND
0.083
0.530
ND
ND
ND
0.156
0.086
0.114
ND
ND
ND
ND
ND
ND
ND
ND
1.75
0.27
ND
0.36
2.31
ND
ND
ND
0.68
0.42
0.56
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 25 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS TNAPC20
Pressure @ Receipt: 8" Hg
Comments: upwind single summa canister
Lab ID: 8082101-15
Canister #: TNAPC20
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/28/08 05:04
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
ethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.382
0.244
0.434
0.635
ND
ND
ND
ND
ND
ND
ND
0.239
ND
ND
ND
ND
0.102
ND
ND
ND
0.185
ND
ND
ND
ND
ND
ND
ND
1.29
0.087
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.10
ug/m3
0.41
0.42
2.15
1.31
ND
ND
ND
ND
ND
ND
ND
1.35
ND
ND
ND
ND
0.78
ND
ND
ND
0.55
ND
ND
ND
ND
ND
ND
ND
4.13
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.50
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 26 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS TNAPC20
Pressure @ Receipt: 8" Hg
Comments: upwind single summa canister
Lab ID: 8082101-15
Canister #: TNAPC20
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/28/08 05:04
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
2.01
ND
ND
0.454
4.36
ND
ND
ND
0.738
0.646
0.727
ND
ND
ND
ND
ND
ND
ND
ND
9.41
ND
ND
1.98
19.00
ND
ND
ND
3.21
3.18
3.58
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 27 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER043
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/444 - downwind
Lab ID: 8082101-16
Canister #: ER043
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 06:07
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.646
0.486
0.462
0.645
ND
ND
ND
ND
ND
ND
ND
0.247
ND
ND
ND
ND
0.092
ND
ND
ND
0.795
ND
ND
ND
ND
ND
ND
ND
2.22
0.048
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.83
ug/m3
0.69
0.84
2.29
1.33
ND
ND
ND
ND
ND
ND
ND
1.39
ND
ND
ND
ND
0.71
ND
ND
ND
2.35
ND
ND
ND
ND
ND
ND
ND
7.11
0.30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
22.00
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 28 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER043
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/444 - downwind
Lab ID: 8082101-16
Canister #: ER043
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 06:07
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
2.03
ND
ND
0.560
5.76
ND
ND
ND
1.02
0.926
1.06
ND
ND
ND
ND
ND
ND
ND
ND
9.50
ND
ND
2.44
25.10
ND
ND
ND
4.44
4.56
5.22
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 29 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 444
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER043 - downwind
Lab ID: 8082101-17
Canister #: 444
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/0808:13
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.634
0.316
0.447
0.574
ND
ND
ND
ND
ND
ND
ND
0.250
ND
ND
ND
ND
0.135
ND
ND
ND
0.283
ND
ND
ND
ND
ND
ND
ND
2.20
0.093
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.55
ug/m3 Flag
0.68
0.55
2.22
1.19
ND U
ND U
ND U
ND U
ND U
ND U
ND U
1.41
ND U
ND U
ND U
ND U
1.04
ND U
ND U
ND U
0.84
ND U
ND U
ND U
ND U
ND U
ND U
ND U
7.04
0.59
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
21.00
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 30 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 444
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER043 - downwind
Lab ID: 8082101-17
Canister #: 444
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/0808:13
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
1.91
ND
ND
0.506
5.30
ND
ND
ND
0.947
0.836
0.949
ND
ND
ND
ND
ND
ND
ND
ND
8.94
ND
ND
2.20
23.10
ND
ND
ND
4.12
4.12
4.67
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 31 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 167601
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3254
Lab ID: 8082101-18
Canister*: 167601
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 11:37
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.354
0.264
0.417
0.588
0.011
ND
ND
ND
ND
ND
ND
0.237
ND
ND
ND
ND
0.102
ND
ND
ND
0.347
ND
ND
ND
ND
ND
ND
ND
1.35
0.047
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.37
ug/m3
0.38
0.46
2.07
1.22
0.08
ND
ND
ND
ND
ND
ND
1.33
ND
ND
ND
ND
0.78
ND
ND
ND
1.03
ND
ND
ND
ND
ND
ND
ND
4.32
0.30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20.30
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 32 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 167601
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3254
Lab ID: 8082101-18
Canister*: 167601
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 11:37
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
2.92
ND
ND
0.652
7.51
ND
ND
ND
1.14
1.25
1.32
ND
ND
ND
ND
ND
ND
ND
ND
13.70
ND
ND
2.84
32.70
ND
ND
ND
4.96
6.16
6.50
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 33 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 3254
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167601
Lab ID: 8082101-19
Canister #: 3254
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 13:42
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.464
0.924
0.451
0.644
ND
ND
ND
ND
ND
ND
ND
0.269
ND
ND
ND
ND
0.089
ND
ND
ND
1.71
ND
ND
ND
ND
ND
ND
ND
1.55
0.093
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.95
ug/m3
0.50
1.59
2.24
1.33
ND
ND
ND
ND
ND
ND
ND
1.51
ND
ND
ND
ND
0.68
ND
ND
ND
5.05
ND
ND
ND
ND
ND
ND
ND
4.96
0.59
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
18.70
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 34 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 3254
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167601
Lab ID: 8082101-19
Canister #: 3254
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 13:42
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
2.69
ND
ND
0.676
7.24
ND
ND
ND
1.15
1.22
1.38
ND
ND
ND
ND
ND
ND
ND
ND
12.60
ND
ND
2.94
31.50
ND
ND
ND
5.00
6.01
6.80
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 35 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER061
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-20
Canister #: ER061
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 15:47
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.525
0.834
0.494
0.680
ND
ND
ND
ND
ND
ND
ND
0.299
ND
ND
ND
ND
0.115
ND
ND
ND
1.72
ND
ND
ND
ND
ND
ND
ND
0.267
0.119
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.413
ug/m3
0.56
1.44
2.45
1.41
ND
ND
ND
ND
ND
ND
ND
1.68
ND
ND
ND
ND
0.88
ND
ND
ND
5.08
ND
ND
ND
ND
ND
ND
ND
0.86
0.75
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.56
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 36 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER061
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-20
Canister #: ER061
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 15:47
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.074
ND
ND
0.068
0.155
ND
ND
ND
0.075
0.046
0.085
ND
ND
ND
ND
ND
ND
ND
ND
0.35
ND
ND
0.30
0.67
ND
ND
ND
0.33
0.23
0.42
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 37 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 15280
Pressure @ Receipt: 8" Hg
Comments: Waypoint 207, upwind canister
Lab ID: 8082101-21
Canister #: 15280
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 16:50
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.370
0.329
0.464
0.692
ND
ND
ND
ND
ND
ND
ND
0.245
ND
ND
ND
ND
0.100
ND
ND
ND
0.230
ND
ND
ND
ND
ND
ND
ND
1.06
0.102
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.01
ug/m3
0.40
0.57
2.30
1.43
ND
ND
ND
ND
ND
ND
ND
1.38
ND
ND
ND
ND
0.77
ND
ND
ND
0.68
ND
ND
ND
ND
ND
ND
ND
3.39
0.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.59
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 38 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS 15280
Pressure @ Receipt: 8" Hg
Comments: Waypoint 207, upwind canister
Lab ID: 8082101-21
Canister #: 15280
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 16:50
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.417
ND
ND
0.183
1.03
ND
ND
ND
0.216
0.117
0.164
ND
ND
ND
ND
ND
ND
ND
ND
1.95
ND
ND
0.80
4.48
ND
ND
ND
0.94
0.58
0.81
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 39 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER064
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER069
Lab ID: 8082101-22
Canister #: ER064
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 17:52
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.420
0.362
0.537
0.715
ND
ND
ND
ND
ND
ND
ND
0.321
ND
ND
ND
ND
0.108
ND
ND
ND
0.557
ND
ND
ND
ND
ND
ND
ND
2.49
0.112
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.28
ug/m3
0.45
0.62
2.66
1.48
ND
ND
ND
ND
ND
ND
ND
1.81
ND
ND
ND
ND
0.83
ND
ND
ND
1.65
ND
ND
ND
ND
ND
ND
ND
7.97
0.71
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
12.40
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 40 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER064
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER069
Lab ID: 8082101-22
Canister #: ER064
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 17:52
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.368
ND
ND
0.222
1.70
ND
ND
ND
0.326
0.148
0.214
ND
ND
ND
ND
ND
ND
ND
ND
1.72
ND
ND
0.97
7.40
ND
ND
ND
1.42
0.73
1.05
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 41 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 ER069
Pressure @ Receipt: 8" Hg
Comments: Col 2 W/ER064
Lab ID: 8082101-23
Canister #: ER069
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 19:57
Air Toxics by EPA Compendium Method TO- 15
Results
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.362
0.375
0.491
0.648
ND
ND
ND
ND
ND
ND
ND
0.296
ND
ND
ND
ND
0.102
ND
ND
ND
0.618
ND
ND
ND
ND
ND
ND
ND
2.13
0.109
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.03
ug/m3
0.39
0.65
2.43
1.34
ND
ND
ND
ND
ND
ND
ND
1.67
ND
ND
ND
ND
0.78
ND
ND
ND
1.83
ND
ND
ND
ND
ND
ND
ND
6.82
0.69
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.40
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 42 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 ER069
Pressure @ Receipt: 8" Hg
Comments: Col 2 W/ER064
Lab ID: 8082101-23
Canister #: ER069
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 19:57
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.422
ND
ND
0.199
1.54
ND
ND
ND
0.294
0.178
0.226
ND
ND
ND
ND
ND
ND
ND
ND
1.98
ND
ND
0.87
6.70
ND
ND
ND
1.28
0.88
1.11
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 43 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 988
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3248 - waypoint 208
Lab ID: 8082101-24
Canister #: 988
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 22:03
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.471
0.329
0.498
0.694
ND
ND
ND
ND
ND
ND
ND
0.313
ND
ND
ND
ND
0.119
ND
ND
ND
0.657
ND
ND
ND
ND
ND
ND
ND
2.26
0.120
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.51
ug/m3 Flag
0.50
0.57
2.47
1.44
ND U
ND U
ND U
ND U
ND U
ND U
ND U
1.76
ND U
ND U
ND U
ND U
0.91
ND U
ND U
ND U
1.94
ND U
ND U
ND U
ND U
ND U
ND U
ND U
7.23
0.76
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
17.00
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 44 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl 988
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3248 - waypoint 208
Lab ID: 8082101-24
Canister #: 988
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 22:03
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.787
ND
ND
0.287
2.26
ND
ND
ND
0.428
0.298
0.291
ND
ND
ND
ND
ND
ND
ND
ND
3.68
ND
ND
1.25
9.83
ND
ND
ND
1.86
1.47
1.43
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 45 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 3248
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/988 - waypoint 209
Lab ID: 8082101-25
Canister #: 3248
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/30/08 00:08
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.575
0.383
0.514
0.641
ND
ND
ND
ND
ND
ND
ND
0.278
ND
ND
ND
ND
0.118
ND
ND
ND
0.633
ND
ND
ND
ND
ND
ND
ND
2.81
0.158
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.74
ug/m3
0.61
0.66
2.55
1.33
ND
ND
ND
ND
ND
ND
ND
1.57
ND
ND
ND
ND
0.91
ND
ND
ND
1.87
ND
ND
ND
ND
ND
ND
ND
9.00
1.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.90
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 46 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 3248
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/988 - waypoint 209
Lab ID: 8082101-25
Canister #: 3248
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/30/08 00:08
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.836
ND
ND
0.267
2.16
ND
ND
ND
0.434
0.139
0.208
ND
ND
ND
ND
ND
ND
ND
ND
3.91
ND
ND
1.16
9.40
ND
ND
ND
1.89
0.69
1.02
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 47 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER021
Pressure @ Receipt: 8" Hg
Comments: Waypoint 212, upwind canister
Lab ID: 8082101-26
Canister #: ER021
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0802:13
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.522
0.736
0.520
0.682
ND
ND
ND
ND
ND
ND
ND
0.314
ND
ND
ND
ND
0.104
ND
ND
ND
1.18
ND
ND
ND
ND
ND
ND
ND
4.28
0.087
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.29
ug/m3
0.56
1.27
2.58
1.41
ND
ND
ND
ND
ND
ND
ND
1.77
ND
ND
ND
ND
0.80
ND
ND
ND
3.49
ND
ND
ND
ND
ND
ND
ND
13.70
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
27.50
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 48 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS ER021
Pressure @ Receipt: 8" Hg
Comments: Waypoint 212, upwind canister
Lab ID: 8082101-26
Canister #: ER021
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0802:13
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.583
ND
ND
0.280
2.27
ND
ND
ND
0.440
0.161
0.205
ND
ND
ND
ND
ND
ND
ND
ND
2.73
ND
ND
1.22
9.88
ND
ND
ND
1.91
0.79
1.01
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 49 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER114
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER085 - waypoint 210
Lab ID: 8082101-27
Canister*: ER114
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0803:16
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.439
0.791
0.491
0.648
ND
ND
ND
ND
ND
ND
ND
0.280
ND
ND
ND
ND
0.119
ND
ND
ND
1.23
ND
ND
ND
ND
ND
ND
ND
1.00
0.136
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.87
ug/m3
0.47
1.36
2.43
1.34
ND
ND
ND
ND
ND
ND
ND
1.58
ND
ND
ND
ND
0.91
ND
ND
ND
3.64
ND
ND
ND
ND
ND
ND
ND
3.20
0.86
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.06
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 50 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS Cl ER114
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER085 - waypoint 210
Lab ID: 8082101-27
Canister*: ER114
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0803:16
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.223
ND
ND
0.133
0.860
ND
ND
ND
0.180
0.099
0.125
ND
ND
ND
ND
ND
ND
ND
ND
1.04
ND
ND
0.58
3.74
ND
ND
ND
0.78
0.49
0.62
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 51 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: MarkModrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 ER085
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER114 - waypoint 211
Lab ID: 8082101-28
Canister #: ER085
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/08 05:21
Air Toxics by EPA Compendium Method TO-15
Results MDL
Vnalvte
cetylene
ropylene
ichlorodifluoromethane
hloromethane
ichlorotetrafluoroethane
inyl chloride
,3-Butadiene
romomethane
hloroethane
cetonitrile
crolein
richlorofluoromethane
crylonitrile
,1-Dichloroethene
ichloromethane
arbon Disulfide
richlorotrifluoroethane
ans-l,2-Dichloroethylene
,1-Dichloroethane
ethyl tert-Butyl Ether
lethyl Ethyl Ketone
hloroprene
s-l,2-Dichloroethylene
romochloromethane
hloroform
thyl tert-Butyl Ether
,2-Dichloroethane
,1,1-Trichloroethane
enzene
arbon Tetrachloride
2rt-Amyl Methyl Ether
,2-Dichloropropane
thyl Acrylate
romod ichloromethane
richloroethylene
ethyl Methacrylate
s-l,3-Dichloropropene
ethyl Isobutyl Ketone
ans-l,3-Dichloropropene
,1,2-Trichloroethane
oluene
Eastern Research Group
ppbv
0.672
0.489
0.522
0.740
ND
ND
ND
ND
ND
ND
ND
0.319
ND
ND
ND
ND
0.149
ND
ND
ND
0.690
ND
ND
ND
ND
ND
ND
ND
2.70
0.118
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.89
ug/m3 Flag
0.72
0.84
2.59
1.53
ND U
ND U
ND U
ND U
ND U
ND U
ND U
1.80
ND U
ND U
ND U
ND U
1.14
ND U
ND U
ND U
2.04
ND U
ND U
ND U
ND U
ND U
ND U
ND U
8.64
0.74
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
ND U
18.50
ppbv
0.072
0.152
0.040
0.064
0.024
0.040
0.040
0.032
0.032
0.176
0.160
0.024
0.072
0.040
0.144
0.032
0.056
0.040
0.056
0.040
0.224
0.056
0.056
0.048
0.056
0.040
0.072
0.040
0.080
0.032
0.104
0.080
0.168
0.056
0.032
0.096
0.056
0.128
0.120
0.064
0.184
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 52 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 1 3:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
Lagoon
Description: ARCADIS C2 ER085
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER114 - waypoint 211
Lab ID: 8082101-28
Canister #: ER085
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/08 05:21
Analvte
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethylbenzene
p-Dichlorobenzene
o-Dichlorobenzene
1,2,4-Trichlorobenzene
Hexachloro-l,3-butadiene
Air Toxics by EPA Compendium Method TO-15
Results MDL
ppbv ug/m3 Flag ppbv
ND
ND
0.509
ND
ND
0.536
2.43
ND
ND
ND
0.690
0.188
0.367
ND
ND
ND
ND
ND
ND
ND
ND
2.38
ND
ND
2.33
10.60
ND
ND
ND
3.00
0.93
1.81
ND
ND
ND
ND
ND
ND
0.040
0.056
0.040
0.048
0.064
0.064
0.152
0.040
0.168
0.072
0.064
0.128
0.128
0.120
0.088
0.096
0.120
0.240
0.136
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 53 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP1)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Eastern Research Group
Source
0.346
0.251
0.400
0.587
ND
ND
ND
ND
ND
ND
ND
0.213
ND
ND
ND
ND
0.083
ND
ND
ND
0.428
ND
ND
ND
ND
ND
ND
ND
2.15
ND
ND
ND
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-11 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/12/08 Analyzed: 08/27/08
0.38 8.77
ND
0.39 1.87
0.57 2.75
ND
ND
ND
ND
ND
ND
ND
0.22 2.42
ND
ND
ND
ND
0.07 16.8
ND
ND
ND
0.44 2.51
ND
ND
ND
ND
ND
ND
ND
2.10 2.35
ND
ND
ND
ND
ND
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 54 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP1) Continued
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethyl benzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8H2903-DUP2)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
Eastern Research Group
Source
ND
ND
ND
3.22
ND
ND
0.738
ND
ND
0.220
1.69
ND
ND
ND
0.385
0.271
0.326
ND
ND
ND
ND
ND
ND
Source
0.442
0.308
0.403
0.596
ND
ND
ND
ND
ND
ND
ND
0.212
ND
Units
Quality Control
: 8082101-11 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-12 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/12/08
ND
ND
ND
3.41
ND
ND
0.82
ND
ND
0.24
1.74
ND
ND
ND
0.39
0.26
0.33
ND
ND
ND
ND
ND
ND
: 08/12/08
0.44
0.27
0.39
0.55
ND
ND
ND
ND
ND
ND
ND
0.22
ND
RPD
Analyzed: 08/27/08
5.67
9.93
6.86
3.08
1.52
4.64
0.0306
Analyzed: 08/28/08
1.12
13.5
2.31
8.63
3.61
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 55 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP2) Continued
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
Eastern Research Group
Source
ND
ND
ND
0.103
ND
ND
ND
0.435
ND
ND
ND
ND
ND
ND
ND
2.20
0.076
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.64
ND
ND
0.802
ND
ND
0.314
1.91
ND
ND
Units
Quality Control
: 8082101-12 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/12/08 Analyzed: 08/28/08
ND
ND
ND
0.08 23.0
ND
ND
ND
0.42 2.87
ND
ND
ND
ND
ND
ND
ND
2.54 14.1
0.06 23.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.01 9.70
ND
ND
0.91 13.0
ND
ND
0.31 0.640
2.05 6.98
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 56 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP2) Continued
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Dichloro benzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8H2903-DUP3)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
Eastern Research Group
Source
ND
0.495
0.293
0.378
ND
ND
ND
ND
ND
ND
Source
0.582
0.423
0.438
0.616
ND
ND
ND
ND
ND
ND
ND
0.240
ND
ND
ND
ND
0.116
ND
ND
ND
0.891
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-12 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-16 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/12/08 Analyzed: 08/28/08
ND
0.51 3.69
0.31 6.86
0.40 4.97
ND
ND
ND
ND
ND
ND
: 08/13/08 Analyzed: 08/28/08
0.65 10.4
0.49 13.9
0.46 5.26
0.65 4.52
ND
ND
ND
ND
ND
ND
ND
0.25 3.12
ND
ND
ND
ND
0.09 23.1
ND
ND
ND
0.80 11.3
ND
ND
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 57 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP3) Continued
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8H2903-DUP4)
Acetylene
Propylene
Eastern Research Group
Source
ND
ND
2.12
0.060
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.68
ND
ND
1.86
ND
ND
0.537
5.52
ND
ND
ND
0.993
0.861
1.02
ND
ND
ND
ND
ND
ND
Source
0.560
0.340
Units
Quality Control
: 8082101-16 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-17 Prepared
ppbv
ppbv
Source
Result
: 08/13/08
ND
ND
2.22
0.05
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.83
ND
ND
2.03
ND
ND
0.56
5.76
ND
ND
ND
1.02
0.93
1.06
ND
ND
ND
ND
ND
ND
: 08/13/08
0.63
0.32
RPD
Analyzed: 08/28/08
4.66
22.0
2.71
8.97
4.19
4.11
2.86
7.33
3.16
Analyzed: 08/28/08
12.4
7.29
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 58 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP4) Continued
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
Eastern Research Group
Source
0.442
0.592
ND
ND
ND
ND
ND
ND
ND
0.281
ND
ND
ND
ND
0.101
ND
ND
ND
0.308
ND
ND
ND
ND
ND
ND
ND
1.78
0.078
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-17 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/13/08 Analyzed: 08/28/08
0.45 1.03
0.57 3.21
ND
ND
ND
ND
ND
ND
ND
0.25 11.5
ND
ND
ND
ND
0.14 28.4
ND
ND
ND
0.28 8.49
ND
ND
ND
ND
ND
ND
ND
2.20 21.3
0.09 17.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 59 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP4) Continued
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Eastern Research Group
Source
ND
5.34
ND
ND
1.86
ND
ND
0.506
5.06
ND
ND
ND
0.910
0.811
0.910
ND
ND
ND
ND
ND
ND
Source
0.554
0.393
0.479
0.664
ND
ND
ND
ND
ND
ND
ND
0.272
ND
ND
Units
Quality Control
: 8082101-17 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-18 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/13/08
ND
5.55
ND
ND
1.91
ND
ND
0.51
5.30
ND
ND
ND
0.95
0.84
0.95
ND
ND
ND
ND
ND
ND
: 08/13/08
0.35
0.26
0.42
0.59
ND
ND
ND
ND
ND
ND
ND
0.24
ND
ND
RPD
Analyzed: 08/28/08
3.81
2.72
0.0198
4.58
3.90
3.06
4.18
Analyzed: 08/29/08
44.0
39.5
13.7
12.1
13.6
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 60 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1) Continued
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
Eastern Research Group
Source
ND
ND
ND
ND
ND
ND
0.328
ND
ND
ND
ND
ND
ND
ND
1.52
0.047
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.58
ND
ND
3.06
ND
ND
0.703
7.96
ND
ND
ND
Units
Quality Control
: 8082101-18 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/13/08 Analyzed: 08/29/08
ND
ND
0.10
ND
ND
ND
0.35 5.72
ND
ND
ND
ND
ND
ND
ND
1.35 11.9
0.05 0.851
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.37 3.82
ND
ND
2.92 4.77
ND
ND
0.65 7.57
7.51 5.79
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 61 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1) Continued
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Dichloro benzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP2)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
Eastern Research Group
Source
1.28
1.34
1.46
ND
ND
ND
ND
ND
ND
Source
0.429
0.855
0.427
0.625
ND
ND
ND
ND
ND
ND
ND
0.239
ND
ND
ND
ND
0.091
ND
ND
ND
1.66
ND
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-18 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-19 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/13/08
1.14
1.25
1.32
ND
ND
ND
ND
ND
ND
: 08/13/08
0.46
0.92
0.45
0.64
ND
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
ND
0.09
ND
ND
ND
1.71
ND
ND
ND
ND
ND
ND
RPD
Analyzed: 08/29/08
11.2
6.99
10.2
Analyzed: 08/29/08
7.86
7.77
5.46
2.99
12.0
1.88
2.89
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 62 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP2) Continued
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP3)
Acetylene
Propylene
Dichlorodifluoromethane
Eastern Research Group
Source
ND
1.51
0.094
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.97
ND
ND
2.64
ND
ND
0.633
6.96
ND
ND
ND
1.13
1.16
1.33
ND
ND
ND
ND
ND
ND
Source
0.392
0.368
0.454
Units
Quality Control
: 8082101-19 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-22 Prepared
ppbv
ppbv
ppbv
Source
Result
: 08/13/08
ND
1.55
0.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.95
ND
ND
2.69
ND
ND
0.68
7.24
ND
ND
ND
1.15
1.22
1.38
ND
ND
ND
ND
ND
ND
: 08/14/08
0.42
0.36
0.54
RPD
Analyzed: 08/29/08
2.49
1.18
0.438
1.79
6.53
4.02
2.35
5.20
3.64
Analyzed: 08/29/08
7.05
1.53
16.7
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 63 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP3) Continued
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Eastern Research Group
Source
0.644
ND
ND
ND
ND
ND
ND
ND
0.308
ND
ND
ND
ND
0.108
ND
ND
ND
0.513
ND
ND
ND
ND
ND
ND
ND
2.28
0.135
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-22 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/14/08 Analyzed: 08/29/08
0.72 10.5
ND
ND
ND
ND
ND
ND
ND
0.32 4.14
ND
ND
ND
ND
0.11 0.186
ND
ND
ND
0.56 8.23
ND
ND
ND
ND
ND
ND
ND
2.49 8.74
0.11 18.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 64 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP3) Continued
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethyl benzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP4)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Eastern Research Group
Source
3.02
ND
ND
0.352
ND
ND
0.185
1.54
ND
ND
ND
0.297
ND
0.174
ND
ND
ND
ND
ND
ND
Source
0.449
0.401
0.509
0.686
ND
ND
ND
ND
ND
ND
ND
0.291
ND
ND
ND
ND
Units
Quality Control
: 8082101-22 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-23 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/14/08
3.28
ND
ND
0.37
ND
ND
0.22
1.70
ND
ND
ND
0.33
0.15
0.21
ND
ND
ND
ND
ND
ND
: 08/14/08
0.36
0.38
0.49
0.65
ND
ND
ND
ND
ND
ND
ND
0.30
ND
ND
ND
ND
RPD
Analyzed: 08/29/08
8.09
4.30
18.6
10.4
9.37
20.4
Analyzed: 08/29/08
21.4
6.85
3.60
5.79
1.60
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 65 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP4) Continued
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
Eastern Research Group
Source
0.106
ND
ND
ND
0.724
ND
ND
ND
ND
ND
ND
ND
2.12
0.144
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.03
ND
ND
0.390
ND
ND
0.183
1.54
ND
ND
ND
0.316
0.173
Units
Quality Control
: 8082101-23 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/14/08 Analyzed: 08/29/08
0.10 3.93
ND
ND
ND
0.62 15.9
ND
ND
ND
ND
ND
ND
ND
2.13 0.451
0.11 27.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.03 0.00991
ND
ND
0.42 7.71
ND
ND
0.20 8.49
1.54 0.299
ND
ND
ND
0.29 7.48
0.18 2.68
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 66 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP4) Continued
1,2,4-Trimethyl benzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Dichloro benzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP5)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Eastern Research Group
Source
0.227
ND
ND
ND
ND
ND
ND
Source
0.479
ND
0.504
0.676
ND
ND
ND
ND
ND
ND
ND
0.267
ND
ND
ND
ND
0.135
ND
ND
ND
0.542
ND
ND
ND
ND
ND
ND
ND
3.01
Units
Quality Control
: 8082101-23 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-24 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/14/08
0.23
ND
ND
ND
ND
ND
ND
: 08/14/08
0.47
0.33
0.50
0.69
ND
ND
ND
ND
ND
ND
ND
0.31
ND
ND
ND
ND
0.12
ND
ND
ND
0.66
ND
ND
ND
ND
ND
ND
ND
2.26
RPD
Analyzed: 08/29/08
0.619
Analyzed: 08/29/08
1.68
1.34
2.61
16.0
12.6
19.2
28.4
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 67 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP5) Continued
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethyl benzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP6)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Eastern Research Group
Source
0.147
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.91
ND
ND
0.894
ND
ND
0.248
2.38
ND
ND
ND
0.464
0.289
0.300
ND
ND
ND
ND
ND
ND
Source
0.523
0.368
0.507
0.707
ND
Units
Quality Control
: 8082101-24 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-25 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/14/08
0.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.51
ND
ND
0.79
ND
ND
0.29
2.26
ND
ND
ND
0.43
0.30
0.29
ND
ND
ND
ND
ND
ND
: 08/14/08
0.58
0.38
0.51
0.64
ND
RPD
Analyzed: 08/29/08
20.3
8.42
12.7
14.6
4.99
8.12
3.13
3.08
Analyzed: 08/30/08
9.52
3.86
1.41
9.78
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 68 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP6) Continued
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
Eastern Research Group
Source
ND
ND
ND
ND
ND
ND
0.311
ND
ND
ND
ND
0.114
ND
ND
ND
0.828
ND
ND
ND
ND
ND
ND
ND
3.16
0.163
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.97
ND
Units
Quality Control
: 8082101-25 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/14/08 Analyzed: 08/30/08
ND
ND
ND
ND
ND
ND
0.28 11.1
ND
ND
ND
ND
0.12 3.63
ND
ND
ND
0.63 26.7
ND
ND
ND
ND
ND
ND
ND
2.81 11.8
0.16 2.86
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.74 4.59
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 69 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP6) Continued
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP7)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
Eastern Research Group
Source
ND
0.829
ND
ND
0.276
2.27
ND
ND
ND
0.456
0.135
0.192
ND
ND
ND
ND
ND
ND
Source
0.417
0.917
0.540
0.684
ND
ND
ND
ND
ND
ND
ND
0.324
ND
ND
ND
ND
0.091
ND
Units
Quality Control
: 8082101-25 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-27 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/14/08
ND
0.84
ND
ND
0.27
2.16
ND
ND
ND
0.43
0.14
0.21
ND
ND
ND
ND
ND
ND
: 08/15/08
0.44
0.79
0.49
0.65
ND
ND
ND
ND
ND
ND
ND
0.28
ND
ND
ND
ND
0.12
ND
RPD
Analyzed: 08/30/08
0.769
3.31
5.10
5.01
2.85
7.86
Analyzed: 08/30/08
5.02
14.8
9.46
5.36
14.5
26.2
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 70 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP7) Continued
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Eastern Research Group
Source
ND
ND
1.40
ND
ND
ND
ND
ND
ND
ND
1.33
0.186
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.93
ND
ND
0.259
ND
ND
0.120
0.922
ND
ND
ND
0.184
ND
0.129
ND
Units
Quality Control
: 8082101-27 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result
: 08/15/08
ND
ND
1.23
ND
ND
ND
ND
ND
ND
ND
1.00
0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.87
ND
ND
0.22
ND
ND
0.13
0.86
ND
ND
ND
0.18
ND
ND
ND
RPD
Analyzed: 08/30/08
13.1
28.6
31.0
3.18
15.2
10.5
6.98
2.14
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 71 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP7) Continued
Chloromethyl benzene
p-Dichlorobenzene
o-Dichloro benzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
Duplicate (B8I0101-DUP8)
Acetylene
Propylene
Dichlorodifluoromethane
Chloromethane
Dichlorotetrafluoroethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Acetonitrile
Acrolein
Trichlorofluoromethane
Acrylonitrile
1,1-Dichloroethene
Dichloromethane
Carbon Disulfide
Trichlorotrifluoroethane
trans- 1,2-Dichloroethylene
1,1-Dichloroethane
Methyl tert-Butyl Ether
Methyl Ethyl Ketone
Chloroprene
cis-l,2-Dichloroethylene
Bromochloromethane
Chloroform
Ethyl tert-Butyl Ether
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
tert-Amyl Methyl Ether
Eastern Research Group
Source
ND
ND
ND
ND
ND
Source
0.628
0.435
0.548
0.633
ND
ND
ND
ND
ND
ND
ND
0.314
ND
ND
ND
ND
0.098
ND
ND
ND
0.450
ND
ND
ND
ND
ND
ND
ND
2.26
0.128
ND
Units
Quality Control
: 8082101-27 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
: 8082101-28 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
: 08/15/08 Analyzed: 08/30/08
ND
ND
ND
ND
ND
: 08/15/08 Analyzed: 08/30/08
0.67 6.69
0.49 11.7
0.52 4.84
0.74 15.6
ND
ND
ND
ND
ND
ND
ND
0.32 1.55
ND
ND
ND
ND
0.15 41.7
ND
ND
ND
0.69 42.1
ND
ND
ND
ND
ND
ND
ND
2.70 18.1
0.12 8.07
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 72 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Air Toxics by EPA Compendium Method TO- 15 -
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP8) Continued Source
1,2-Dichloropropane
Ethyl Acrylate
Bromodichloromethane
Trichloroethylene
Methyl Methacrylate
cis-l,3-Dichloropropene
Methyl Isobutyl Ketone
trans- 1,3-Dichloropropene
1,1,2-Trichloroethane
Toluene
Dibromochloromethane
1,2-Dibromoethane
n-Octane
Tetrachloroethylene
Chlorobenzene
Ethyl benzene
m,p-Xylene
Bromoform
Styrene
1,1,2,2-Tetrachloroethane
o-Xylene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
m-Dichlorobenzene
Chloromethyl benzene
p-Dichlorobenzene
o-Di chlorobenzene
1,2,4-Trichlorobenzene
Hexachloro- 1,3-butadiene
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.86
ND
ND
0.564
ND
ND
0.507
2.44
ND
ND
ND
0.682
0.204
0.331
ND
ND
ND
ND
ND
ND
Units
Quality Control
: 8082101-28 Prepared
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
ppbv
Source
Result RPD
08/15/08 Analyzed: 08/30/08
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.89 0.687
ND
ND
0.51 10.3
ND
ND
0.54 5.49
2.43 0.395
ND
ND
ND
0.69 1.05
0.19 7.96
0.37 10.5
ND
ND
ND
ND
ND
ND
RPD
Limit Notes
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 73 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Notes and Definitions
U Under Detection Limit
E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is
considered an estimate (CLP E-flag).
D-01 This result obtained by diluting and reanalyzing the sample.
ND Analyte NOT DETECTED at or above the Method Detection Limit (MDL)
NR Not Reported
MDL Method Detection Limit
RPD Relative Percent Difference
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 74 of 75
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/24/08 13:45
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Items for Project Manager Review
LabNumber
8082101-05
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-05
B8I0101-DUP8
8082101-05
8082101-05
8082101-07
8082101-07
8082101-07
8082101-07
B8I0101-DUP1
B8I0101-DUP1
B8I0101-DUP7
B8I0101-DUP8
8082101-04
Eastern Research
Analysis
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
TO-15
Group
Analyte
m,p-Xylene
(Air)
(Air)
1,2,4-Trimethyl benzene
1,3,5-Trimethyl benzene
Benzene
Ethyl benzene
m,p-Xylene
n-Octane
o-Xylene
Benzene
Trichlorotrifluoroethane
n-Octane
Toluene
Benzene
m,p-Xylene
n-Octane
Toluene
Propylene
Acetylene
Carbon Tetrachloride
Methyl Ethyl Ketone
Toluene
Exception
D-01: This result obtained by diluting and reanalyzing the
sample.
VERSION 5.85:2863
Result calculations based on MDL
U-Flags used
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
This is a modified report
D-01: This result obtained by diluting and reanalyzing the
sample.
Exceeds RPD control limit
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
Exceeds RPD control limit
Exceeds RPD control limit
Exceeds RPD control limit
Exceeds RPD control limit
D-01: This result obtained by diluting and reanalyzing the
sample.
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 75 of 75
-------
Eastern Research Group
601 Keystone Park Drive
Suite 700
Morrisville, NC 27560
September 25, 2008
Mark Modrak
ARCADIS
4915 Prospectus Drive
Durham, NC 27713
Project Name: Lagoon
Dear Mark Modrak,
This report contains the analytical results for the sample(s) received under chain(s) of custody
by Eastern Research Group on 08/21/08 08:11.
The test results in this report are in compliance with NELAC accreditation requirements for the
certified parameters. All analyses were performed as described in the US EPA-approved QAPP,
under the contract for NMOC, UATMP, PAMS, HAPS, and NATTS support (US EPA Contract No.
68-D-03-049). This cover page is an integral part of this report, and any exceptions or
comments are noted on the last page.
The issuance of the final Certificate of Analysis takes precedence over any previous Report. If
you have any questions, please contact me at 919-468-7930.
Sincerely,
Laura Van Enwyck
Program Manager
Page 1 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535 FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
ANALYTICAL REPORT FOR SAMPLES
SampleName
ARCADIS TNAPC11
ARCADIS 926
ARCADIS 3639A
ARCADIS 648
ARCADIS ER038
ARCADIS ER001
ARCADIS ER047
ARCADIS C1 167604
ARCADIS C2 659
ARCADIS ER029
ARCADIS 3255
ARCADIS TNAPC20
ARCADIS C1 ER043
ARCADIS C2 444
ARCADIS C1 167601
ARCADIS C2 3254
ARCADIS ER061
ARCADIS 15280
ARCADIS C1 ER064
Eastern Research Group
LabNumber
8082101-04
8082101-05
8082101-06
8082101-07
8082101-08
8082101-09
8082101-10
8082101-11
8082101-12
8082101-13
8082101-14
8082101-15
8082101-16
8082101-17
8082101-18
8082101-19
8082101-20
8082101-21
8082101-22
Matrix
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Sampled
08/07/08 00:00
08/08/08 00:00
08/08/08 00:00
08/08/08 00:00
08/09/08 00:00
08/09/08 00:00
08/09/08 00:00
08/12/0800:00
08/12/0800:00
08/12/0800:00
08/13/08 12:07
08/13/0816:52
08/13/0812:07
08/13/08 12:07
08/13/08 16:52
08/13/0816:52
08/14/0811:32
08/14/08 17:09
08/1 4/08 1 1 :32
Received
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 2 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
ARCADIS C2 ER069
ARCADIS C1 988
ARCADIS C2 3248
ARCADIS ER021
ARCADIS C1 ER114
ARCADIS C2 ER085
FAX: (919)544-5690
8082101-23
8082101-24
8082101-25
8082101-26
8082101-27
8082101-28
Air
Air
Air
Air
Air
Air
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE:
08/14/0811:32
08/14/08 17:09
08/14/08 17:09
08/15/0812:09
08/15/0812:09
08/15/08 12:09
Lagoon
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
08/21/0808:11
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
PageS of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC11
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-04
Canister #: TNAPC11
Sampled: 08/07/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 15:15
Speciated Non-Methane Organic Compounds by GC/FID
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
rans-2-Pentene
s-2-Pentene
-Methyl-2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.46
0.953
118
1.26
289
ND
292
42.5
ND
520
0.738
1.04
ND
899
1.13
ND
724
1.01
1.56
1.02
2.40
89.0
1.03
ND
69.6
185
625
413
ND
ND
ND
1560
ND
ND
650
113
1050
1670
Results
ppbv
0.73
0.48
59.00
0.42
96.30
ND
73.00
10.60
ND
130.00
0.19
0.26
ND
180.00
0.23
ND
145.00
0.20
0.31
0.20
0.48
14.80
0.21
ND
13.90
30.80
104.00
68.80
ND
ND
ND
260.00
ND
ND
108.00
16.10
175.00
278.00
ug/m3
0.84
0.51
72.70
0.72
174.00
ND
174.00
24.40
ND
310.00
0.42
0.60
ND
532.00
0.65
ND
428.00
0.56
0.90
0.59
1.38
52.40
0.58
ND
40.00
109.00
368.00
243.00
ND
ND
ND
918.00
ND
ND
374.00
66.30
560.00
960.00
MDL
Flag PPbC
0.560
0.880
0.720
0.560
1.44
U 1.44
0.640
1.12
U 1.52
0.880
U 1.04
U 1.52
U 1.60
E 1.36
0.960
U 1.60
0.800
U 1.60
1.52
U 1.52
1.60
1.12
U 1.60
U 3.44
0.640
1.60
0.640
1.44
U 3.44
U 3.44
U 3.44
D-01 32.8
U 3.44
U 3.44
1.04
1.92
D-01 34.3
D-01 31.4
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 4 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC11
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-04
Canister #: TNAPC11
Sampled: 08/07/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 15:15
Speciated Non-Methane Organic Compounds by GC/FID
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
sopropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
-Tridecene
Eastern Research Group
ppbC
1030
224
1030
453
ND
3440
8350
297
11.8
6950
2700
2290
ND
9730
1010
13400
22.8
1930
335
7370
172
855
308
1110
743
2260
610
140
1700
ND
3250
253
124
97.7
15.0
1240
51.1
434
ND
Results
ppbv ug/m3
147.00 604.00
32.00 131.00
147.00 604.00
64.70 260.00
ND ND
491.00 2,020.00
1,190.00 4,800.00
37.10 174.00
1.48 6.91
993.00 3,750.00
338.00 1,580.00
286.00 1,340.00
ND ND
1,220.00 5,690.00
126.00 549.00
1,680.00 7,290.00
2.85 12.20
241.00 1,050.00
37.20 193.00
819.00 4,300.00
21.50 106.00
107.00 597.00
34.20 169.00
123.00 608.00
82.60 407.00
251.00 1,240.00
67.80 334.00
17.50 97.70
189.00 930.00
ND ND
325.00 1,900.00
28.10 138.00
12.40 68.20
9.77 53.70
1.36 8.62
113.00 722.00
4.26 29.40
36.20 252.00
ND ND
Flag
D-01
D-01
U
D-01
D-01
D-01
D-01
D-01
U
D-01
D-01
D-01
D-01
D-01
D-01
D-01
D-01
D-01
D-01
U
D-01
D-01
U
MDL
ppbC
25.7
3.12
32.8
3.12
1.76
28.6
21.4
2.48
1.44
47.1
25.7
28.6
2.48
34.3
30.0
44.3
2.00
24.3
2.56
24.3
2.56
45.7
1.52
21.4
37.1
28.6
2.32
1.60
34.3
1.60
28.6
1.76
1.44
0.960
1.36
24.3
3.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Pages of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC11
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-04
Canister #: TNAPC11
Sampled: 08/07/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 15:15
Analvte
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
133 10.20
78800 ND
33200 ND
112000 ND
77.30
ND
ND
ND
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 6 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 926
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-05
Canister #: 926
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 16:19
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.39
ND
44.0
1.25
84.3
ND
66.4
27.6
ND
118
ND
ND
ND
236
ND
ND
164
ND
ND
ND
0.907
15.1
0.961
ND
20.2
30.8
105
68.1
ND
ND
ND
150
ND
ND
105
14.7
349
177
ppbv
0.70
ND
22.00
0.42
28.10
ND
16.60
6.90
ND
29.50
ND
ND
ND
47.20
ND
ND
32.80
ND
ND
ND
0.18
2.52
0.19
ND
4.04
5.13
17.50
11.40
ND
ND
ND
25.00
ND
ND
17.50
2.10
58.20
29.50
ug/m3
0.80
ND
27.10
0.72
50.80
ND
39.50
15.90
ND
70.30
ND
ND
ND
140.00
ND
ND
97.00
ND
ND
ND
0.52
8.89
0.54
ND
11.60
18.10
61.80
40.10
ND
ND
ND
88.30
ND
ND
60.40
8.62
186.00
102.00
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 7 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 926
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-05
Canister #: 926
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 16:19
Speciated Non-Methane Organic Compounds by GC/FID
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
sopropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
-Tridecene
Eastern Research Group
ppbC
91.2
27.4
92.2
52.7
ND
273
680
20.9
1.34
1370
145
102
ND
459
56.8
739
1.56
116
15.8
398
8.87
51.4
17.6
64.8
50.7
153
46.4
7.58
114
ND
307
16.9
10.8
8.67
1.49
208
4.98
129
ND
Results
ppbv
13.00
3.91
13.20
7.53
ND
39.00
97.10
2.61
0.17
196.00
18.10
12.80
ND
57.40
7.10
92.40
0.20
14.50
1.76
44.20
1.11
6.43
1.96
7.20
5.63
17.00
5.16
0.95
12.70
ND
30.70
1.88
1.08
0.87
0.14
18.90
0.42
10.80
ND
ug/m3
53.50
16.10
54.10
30.30
ND
160.00
391.00
12.20
0.78
739.00
84.90
59.70
ND
269.00
30.90
402.00
0.83
63.10
9.08
232.00
5.46
35.90
9.63
35.50
27.80
83.70
25.40
5.29
62.40
ND
179.00
9.25
5.94
4.77
0.86
121.00
2.86
75.00
ND
MDL
Flag PPbC
1.44
3.12
1.84
3.12
U 1.76
1.60
1.20
2.48
U 1.44
D-01 34.5
1.44
1.60
U 2.48
1.92
1.68
2.48
U 2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
U 1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
U 3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
PageS of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 926
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-05
Canister #: 926
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 16:19
Speciated Non-Methane Organic Compounds by GC/FID
Analvte
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Results
ppbC ppbv ug/m3
Flag
54.8
7270
2260
9530
4.22
ND
ND
ND
31.90
ND
ND
ND
MDL
ppbC
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 9 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3639A
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-06
Canister #: 3639A
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 17:26
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
rans-2-Butene
is-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
soprene
rans-2-Pentene
is-2-Pentene
-Methyl-2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
-Methylhexane
Eastern Research Group
ppbC
2.09
2.91
40.1
1.15
29.2
ND
18.9
4.22
ND
29.3
0.783
0.808
ND
69.3
1.56
2.73
31.6
0.500
3.16
1.70
3.88
3.86
1.82
ND
2.87
5.80
22.4
13.2
0.446
0.424
ND
16.8
0.626
ND
11.0
2.23
6.53
8.19
6.37
ppbv
1.05
1.46
20.10
0.38
9.73
ND
4.73
1.06
ND
7.33
0.20
0.20
ND
13.90
0.31
0.55
6.32
0.10
0.63
0.34
0.78
0.64
0.36
ND
0.57
0.97
3.73
2.20
0.07
0.07
ND
2.80
0.10
ND
1.83
0.32
1.09
1.37
0.91
ug/m3
1.20
1.55
24.70
0.66
17.60
ND
11.30
2.43
ND
17.40
0.45
0.47
ND
41.00
0.90
1.57
18.70
0.28
1.82
0.98
2.23
2.27
1.02
ND
1.65
3.41
13.20
7.77
0.26
0.24
ND
9.89
0.36
ND
6.32
1.31
3.48
4.71
3.74
MDL
Flag PPbC
0.140
0.220
0.180
0.140
0.360
U 0.360
0.160
0.280
U 0.380
0.220
0.260
0.380
U 0.400
0.340
0.240
0.400
0.200
0.400
0.380
0.380
0.400
0.280
0.400
U 0.860
0.160
0.400
0.160
0.360
U 0.860
U 0.860
U 0.860
0.460
U 0.860
U 0.860
0.260
0.480
0.480
0.440
0.360
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 10 of 110
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CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3639A
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-06
Canister #: 3639A
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 17:26
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
sopropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
-Tridecene
-Tridecane
Eastern Research Group
ppbC
2.64
6.15
1.82
3.20
7.05
13.3
1.26
1.16
22.7
2.30
2.33
0.510
4.39
3.03
12.4
ND
4.07
0.356
2.48
0.823
0.745
1.03
2.70
2.03
1.71
1.57
ND
4.48
ND
3.41
0.834
0.773
1.50
ND
3.34
0.532
2.39
ND
0.859
ppbv
0.38
0.88
0.26
0.40
1.01
1.90
0.16
0.15
3.24
0.29
0.29
0.06
0.55
0.38
1.55
ND
0.51
0.04
0.28
0.10
0.09
0.11
0.30
0.23
0.19
0.17
ND
0.50
ND
0.34
0.09
0.08
0.15
ND
0.30
0.04
0.20
ND
0.07
ug/m3
1.55
3.61
1.05
1.87
4.14
7.65
0.74
0.68
12.20
1.35
1.36
0.29
2.57
1.65
6.74
ND
2.21
0.21
1.45
0.51
0.52
0.56
1.48
1.11
0.94
0.86
ND
2.45
ND
1.99
0.46
0.43
0.83
ND
1.95
0.31
1.39
ND
0.50
MDL
Flag PPbC
0.780
0.460
0.780
0.440
0.400
0.300
0.620
0.360
0.660
0.360
0.400
U 0.620
0.480
0.420
0.620
U 0.500
0.340
U 0.640
0.340
0.640
0.640
0.380
0.300
0.520
0.400
0.580
U 0.400
0.480
U 0.400
0.400
0.440
0.360
0.240
U 0.340
0.340
U 0.840
0.840
U 0.840
0.840
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 11 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3639A
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-06
Canister #: 3639A
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 17:26
Analvte
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
466
181
648
ND
ND
ND
ND
ND
ND
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 12 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 648
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-07
Canister #: 648
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 18:29
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.55
0.749
40.8
1.55
79.8
ND
63.2
27.5
ND
112
ND
ND
ND
231
ND
ND
166
ND
ND
ND
1.10
14.9
1.43
ND
20.8
31.3
107
69.0
ND
ND
ND
148
ND
ND
106
14.2
345
174
ppbv
0.78
0.38
20.40
0.52
26.60
ND
15.80
6.88
ND
28.00
ND
ND
ND
46.20
ND
ND
33.20
ND
ND
ND
0.22
2.48
0.29
ND
4.16
5.22
17.80
11.50
ND
ND
ND
24.70
ND
ND
17.70
2.03
57.50
29.00
ug/m3
0.89
0.40
25.10
0.89
48.10
ND
37.60
15.80
ND
66.70
ND
ND
ND
137.00
ND
ND
98.20
ND
ND
ND
0.63
8.77
0.80
ND
12.00
18.40
63.00
40.60
ND
ND
ND
87.10
ND
ND
60.90
8.33
184.00
100.00
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 13 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 648
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-07
Canister #: 648
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 18:29
Speciated Non-Methane Organic Compounds by GC/FID
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
sopropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
-Tridecene
Eastern Research Group
ppbC
88.1
25.8
89.0
50.1
ND
261
651
20.7
1.48
1430
137
92.7
ND
433
55.2
714
1.27
112
16.3
368
13.4
47.7
19.1
61.7
49.0
144
43.0
8.30
109
ND
284
19.2
10.3
7.58
1.42
196
4.08
116
ND
Results
ppbv
12.60
3.69
12.70
7.16
ND
37.30
93.00
2.59
0.19
204.00
17.10
11.60
ND
54.10
6.90
89.30
0.16
14.00
1.81
40.90
1.68
5.96
2.12
6.86
5.44
16.00
4.78
1.04
12.10
ND
28.40
2.13
1.03
0.76
0.13
17.80
0.34
9.67
ND
ug/m3
51.70
15.10
52.20
28.80
ND
153.00
374.00
12.10
0.87
771.00
80.20
54.20
ND
253.00
30.00
388.00
0.68
60.90
9.37
215.00
8.25
33.30
10.50
33.80
26.80
78.80
23.50
5.79
59.70
ND
166.00
10.50
5.67
4.17
0.82
114.00
2.35
67.50
ND
MDL
Flag PPbC
1.44
3.12
1.84
3.12
U 1.76
1.60
1.20
2.48
1.44
D-01 28.9
1.44
1.60
U 2.48
1.92
1.68
2.48
U 2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
U 1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
U 3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 14 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 648
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-07
Canister #: 648
Sampled: 08/08/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 18:29
Speciated Non-Methane Organic Compounds by GC/FID
Analvte
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Results
ppbC ppbv ug/m3
Flag
46.5
7020
2140
9160
3.58
ND
ND
ND
27.00
ND
ND
ND
MDL
ppbC
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 15 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER038
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-08
Canister*: ER038
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 19:35
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl-2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.04
0.554
55.9
0.583
27.6
ND
11.7
2.87
4.30
13.4
ND
ND
ND
25.7
0.255
ND
9.84
0.371
ND
ND
0.420
1.03
0.755
ND
0.925
1.59
7.17
3.90
ND
ND
ND
7.57
ND
ND
4.90
0.728
2.30
6.63
ppbv
0.52
0.28
28.00
0.19
9.20
ND
2.93
0.72
0.48
3.35
ND
ND
ND
5.14
0.05
ND
1.97
0.07
ND
ND
0.08
0.17
0.15
ND
0.19
0.27
1.20
0.65
ND
ND
ND
1.26
ND
ND
0.82
0.10
0.38
1.11
ug/m3
0.60
0.30
34.40
0.34
16.60
ND
6.97
1.65
1.06
7.98
ND
ND
ND
15.20
0.15
ND
5.82
0.21
ND
ND
0.24
0.61
0.42
ND
0.53
0.94
4.22
2.30
ND
ND
ND
4.46
ND
ND
2.82
0.43
1.23
3.81
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.140
0.220
0.180
0.140
0.360
0.360
0.160
0.280
0.380
0.220
0.260
0.380
0.400
0.340
0.240
0.400
0.200
0.400
0.380
0.380
0.400
0.280
0.400
0.860
0.160
0.400
0.160
0.360
0.860
0.860
0.860
0.460
0.860
0.860
0.260
0.480
0.480
0.440
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 16 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER038
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-08
Canister*: ER038
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 19:35
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n- Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
3.19
1.05
2.31
1.55
ND
4.56
14.5
0.340
0.308
6.06
1.74
1.20
ND
4.35
0.459
3.60
ND
0.906
0.399
2.88
0.217
0.750
0.473
0.605
0.681
4.73
0.754
ND
1.33
ND
5.11
0.386
0.568
1.50
ND
5.29
0.341
3.28
ppbv
0.46
0.15
0.33
0.22
ND
0.65
2.07
0.04
0.04
0.87
0.22
0.15
ND
0.54
0.06
0.45
ND
0.11
0.04
0.32
0.03
0.09
0.05
0.07
0.08
0.53
0.08
ND
0.15
ND
0.51
0.04
0.06
0.15
ND
0.48
0.03
0.27
ug/m3
1.87
0.62
1.36
0.89
ND
2.68
8.34
0.20
0.18
3.27
1.02
0.70
ND
2.55
0.25
1.96
ND
0.49
0.23
1.68
0.13
0.52
0.26
0.33
0.37
2.59
0.41
ND
0.73
ND
2.98
0.21
0.31
0.83
ND
3.08
0.20
1.91
MDL
Flag PPbC
0.360
0.780
0.460
0.780
U 0.440
0.400
0.300
U 0.620
U 0.360
0.660
0.360
0.400
U 0.620
0.480
0.420
0.620
U 0.500
0.340
U 0.640
0.340
U 0.640
0.640
0.380
0.300
0.520
0.400
0.580
U 0.400
0.480
U 0.400
0.400
U 0.440
0.360
0.240
U 0.340
0.340
U 0.840
0.840
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 17 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER038
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-08
Canister*: ER038
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 19:35
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
1.21
269
155
424
ND
0.09
ND
ND
ND
ND
0.70
ND
ND
ND
0.840
0.840
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 18 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER001
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-09
Canister*: ER001
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 20:38
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.29
0.803
53.6
1.69
26.6
ND
10.9
ND
ND
13.7
ND
ND
ND
9.18
ND
ND
10.3
ND
ND
ND
ND
1.16
ND
ND
1.74
2.27
7.24
4.42
ND
ND
ND
7.49
ND
ND
4.87
1.08
2.49
6.60
ppbv
1.15
0.40
26.80
0.56
8.87
ND
2.73
ND
ND
3.43
ND
ND
ND
1.84
ND
ND
2.06
ND
ND
ND
ND
0.19
ND
ND
0.35
0.38
1.21
0.74
ND
ND
ND
1.25
ND
ND
0.81
0.15
0.42
1.10
ug/m3
1.32
0.43
33.00
0.97
16.00
ND
6.49
ND
ND
8.16
ND
ND
ND
5.43
ND
ND
6.09
ND
ND
ND
ND
0.68
ND
ND
1.00
1.34
4.26
2.60
ND
ND
ND
4.41
ND
ND
2.80
0.63
1.33
3.79
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 19 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER001
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-09
Canister*: ER001
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 20:38
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
4.59
1.62
2.51
1.24
ND
4.40
12.9
ND
ND
7.03
1.57
1.16
ND
4.39
0.721
3.60
ND
1.02
0.988
3.00
ND
ND
0.721
ND
0.786
ND
ND
ND
1.69
ND
4.32
ND
ND
ND
ND
4.31
ND
2.96
ppbv
0.66
0.23
0.36
0.18
ND
0.63
1.84
ND
ND
1.00
0.20
0.15
ND
0.55
0.09
0.45
ND
0.13
0.11
0.33
ND
ND
0.08
ND
0.09
ND
ND
ND
0.19
ND
0.43
ND
ND
ND
ND
0.39
ND
0.25
ug/m3
2.69
0.95
1.47
0.71
ND
2.58
7.42
ND
ND
3.79
0.92
0.68
ND
2.57
0.39
1.96
ND
0.56
0.57
1.75
ND
ND
0.40
ND
0.43
ND
ND
ND
0.93
ND
2.52
ND
ND
ND
ND
2.51
ND
1.72
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 20 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER001
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-09
Canister*: ER001
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 20:38
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
1.26
235
187
422
ND ND
0.10 0.73
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 21 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER047
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-10
Canister*: ER047
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 21:42
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.51
ND
50.3
1.06
30.5
ND
19.5
ND
ND
31.5
ND
ND
ND
43.9
ND
ND
61.5
ND
ND
ND
ND
6.01
ND
ND
7.23
15.4
61.6
38.5
ND
ND
ND
74.4
ND
ND
52.6
6.13
27.9
73.8
ppbv
0.76
ND
25.20
0.35
10.20
ND
4.88
ND
ND
7.88
ND
ND
ND
8.78
ND
ND
12.30
ND
ND
ND
ND
1.00
ND
ND
1.45
2.57
10.30
6.42
ND
ND
ND
12.40
ND
ND
8.77
0.88
4.65
12.30
ug/m3
0.87
ND
31.00
0.61
18.40
ND
11.60
ND
ND
18.80
ND
ND
ND
26.00
ND
ND
36.40
ND
ND
ND
ND
3.54
ND
ND
4.16
9.07
36.30
22.70
ND
ND
ND
43.80
ND
ND
30.20
3.60
14.90
42.40
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 22 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER047
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-10
Canister*: ER047
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 21:42
Speciated Non-Methane Organic Compounds by GC/FID
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
sopropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
-Tridecene
Eastern Research Group
ppbC
31.7
10.6
32.9
20.5
ND
69.6
245
5.18
ND
79.5
31.4
23.8
ND
93.4
5.80
78.9
ND
14.2
4.55
73.4
3.77
11.0
4.31
10.1
10.0
27.3
10.3
ND
15.3
ND
68.9
3.88
3.22
2.79
ND
67.4
2.47
53.8
ND
Results
ppbv
4.53
1.51
4.70
2.93
ND
9.94
35.00
0.65
ND
11.40
3.93
2.98
ND
11.70
0.73
9.86
ND
1.78
0.51
8.16
0.47
1.38
0.48
1.12
1.11
3.03
1.14
ND
1.70
ND
6.89
0.43
0.32
0.28
ND
6.13
0.21
4.48
ND
ug/m3
18.60
6.22
19.30
11.80
ND
40.80
141.00
3.03
ND
42.90
18.40
13.90
ND
54.70
3.15
42.90
ND
7.72
2.62
42.90
2.32
7.68
2.36
5.53
5.47
14.90
5.64
ND
8.37
ND
40.20
2.12
1.77
1.53
ND
39.30
1.42
31.30
ND
MDL
Flag PPbC
1.44
3.12
1.84
3.12
U 1.76
1.60
1.20
2.48
U 1.44
2.64
1.44
1.60
U 2.48
1.92
1.68
2.48
U 2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
U 1.60
1.92
U 1.60
1.60
1.76
1.44
0.960
U 1.36
1.36
U 3.36
3.36
U 3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 23 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER047
Pressure @ Receipt: 8" Hg
Comments:
Lab ID: 8082101-10
Canister*: ER047
Sampled: 08/09/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 21:42
Speciated Non-Methane Organic Compounds by GC/FID
Analvte
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Results
ppbC ppbv ug/m3
Flag
27.7
1750
663
2410
2.13
ND
ND
ND
16.10
ND
ND
ND
MDL
ppbC
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 24 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167604
Pressure @ Receipt: 8" Hg
Comments: Col 1 w/659 - downwind
Lab ID: 8082101-11
Canister #: 167604
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 22:45
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.31
ND
26.4
0.914
17.5
ND
9.90
ND
ND
13.1
ND
ND
ND
11.8
ND
ND
11.5
ND
ND
ND
ND
1.38
ND
ND
1.17
2.14
8.46
4.47
ND
ND
ND
9.65
ND
ND
5.64
1.14
7.96
7.15
ppbv
0.66
ND
13.20
0.31
5.83
ND
2.48
ND
ND
3.28
ND
ND
ND
2.36
ND
ND
2.30
ND
ND
ND
ND
0.23
ND
ND
0.23
0.36
1.41
0.75
ND
ND
ND
1.61
ND
ND
0.94
0.16
1.33
1.19
ug/m3
0.75
ND
16.30
0.53
10.50
ND
5.90
ND
ND
7.80
ND
ND
ND
6.98
ND
ND
6.80
ND
ND
ND
ND
0.81
ND
ND
0.67
1.26
4.98
2.63
ND
ND
ND
5.68
ND
ND
3.24
0.67
4.25
4.11
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 25 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167604
Pressure @ Receipt: 8" Hg
Comments: Col 1 w/659 - downwind
Lab ID: 8082101-11
Canister #: 167604
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 22:45
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
4.54
1.36
3.06
1.80
ND
6.05
16.0
ND
ND
18.6
3.03
1.88
ND
8.22
2.12
11.9
ND
2.55
ND
6.80
ND
1.35
0.786
1.43
1.43
2.93
1.72
ND
2.87
ND
6.44
0.838
ND
ND
ND
7.78
ND
6.92
ppbv
0.65
0.19
0.44
0.26
ND
0.86
2.29
ND
ND
2.66
0.38
0.24
ND
1.03
0.27
1.49
ND
0.32
ND
0.76
ND
0.17
0.09
0.16
0.16
0.33
0.19
ND
0.32
ND
0.64
0.09
ND
ND
ND
0.71
ND
0.58
ug/m3
2.66
0.80
1.80
1.03
ND
3.55
9.20
ND
ND
10.00
1.77
1.10
ND
4.81
1.15
6.47
ND
1.39
ND
3.97
ND
0.94
0.43
0.78
0.78
1.60
0.94
ND
1.57
ND
3.76
0.46
ND
ND
ND
4.53
ND
4.03
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 26 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167604
Pressure @ Receipt: 8" Hg
Comments: Col 1 w/659 - downwind
Lab ID: 8082101-11
Canister #: 167604
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/27/08 22:45
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
2.73
267
191
457
ND
0.21
ND
ND
ND
ND
1.59
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 27 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 659
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167604 - downwind
Lab ID: 8082101-12
Canister #: 659
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 00:51
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
rans-2-Pentene
s-2-Pentene
-Methyl-2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.28
ND
26.7
0.861
17.7
ND
9.99
ND
ND
16.3
ND
ND
ND
22.1
0.833
ND
16.2
ND
1.64
1.08
1.97
2.24
ND
ND
2.44
3.51
14.1
7.61
ND
ND
ND
11.9
ND
ND
7.76
1.98
9.46
7.42
ppbv
0.64
ND
13.40
0.29
5.90
ND
2.50
ND
ND
4.08
ND
ND
ND
4.42
0.17
ND
3.24
ND
0.33
0.22
0.39
0.37
ND
ND
0.49
0.59
2.35
1.27
ND
ND
ND
1.98
ND
ND
1.29
0.28
1.58
1.24
ug/m3
0.74
ND
16.50
0.50
10.70
ND
5.95
ND
ND
9.71
ND
ND
ND
13.10
0.48
ND
9.58
ND
0.94
0.62
1.13
1.32
ND
ND
1.40
2.07
8.30
4.48
ND
ND
ND
7.01
ND
ND
4.46
1.16
5.05
4.27
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 28 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 659
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167604 - downwind
Lab ID: 8082101-12
Canister #: 659
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 00:51
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
6.32
2.64
4.30
2.24
1.09
7.44
16.9
ND
0.738
22.7
3.57
2.87
ND
9.50
2.57
15.0
ND
3.71
ND
7.99
ND
1.43
0.662
2.12
1.75
3.79
1.46
ND
4.09
ND
7.74
0.790
ND
ND
ND
7.19
ND
4.98
ppbv
0.90
0.38
0.61
0.32
0.14
1.06
2.41
ND
0.09
3.24
0.45
0.36
ND
1.19
0.32
1.88
ND
0.46
ND
0.89
ND
0.18
0.07
0.24
0.19
0.42
0.16
ND
0.45
ND
0.77
0.09
ND
ND
ND
0.65
ND
0.42
ug/m3
3.71
1.55
2.52
1.29
0.64
4.37
9.72
ND
0.43
12.20
2.09
1.68
ND
5.56
1.40
8.16
ND
2.02
ND
4.67
ND
1.00
0.36
1.16
0.96
2.07
0.80
ND
2.24
ND
4.51
0.43
ND
ND
ND
4.19
ND
2.90
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 29 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 659
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167604 - downwind
Lab ID: 8082101-12
Canister #: 659
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 00:51
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
1.89
333
197
529
ND ND
0.15 1.10
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 30 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER029
Pressure @ Receipt: 8" Hg
Comments: upwind canister
Lab ID: 8082101-13
Canister*: ER029
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 02:58
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.51
1.05
21.0
0.978
12.3
ND
4.66
ND
ND
5.46
ND
ND
ND
4.31
ND
ND
4.38
ND
ND
ND
ND
1.04
ND
ND
1.11
1.07
5.27
2.53
ND
ND
ND
4.56
ND
ND
2.84
0.693
2.38
4.28
ppbv
0.76
0.53
10.50
0.33
4.10
ND
1.17
ND
ND
1.37
ND
ND
ND
0.86
ND
ND
0.88
ND
ND
ND
ND
0.17
ND
ND
0.22
0.18
0.88
0.42
ND
ND
ND
0.76
ND
ND
0.47
0.10
0.40
0.71
ug/m3
0.87
0.56
12.90
0.56
7.41
ND
2.77
ND
ND
3.25
ND
ND
ND
2.55
ND
ND
2.59
ND
ND
ND
ND
0.61
ND
ND
0.64
0.63
3.10
1.49
ND
ND
ND
2.68
ND
ND
1.63
0.41
1.27
2.46
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 31 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER029
Pressure @ Receipt: 8" Hg
Comments: upwind canister
Lab ID: 8082101-13
Canister*: ER029
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 02:58
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
3.74
1.48
2.60
1.41
ND
4.89
12.1
ND
ND
6.29
2.15
1.72
ND
6.20
1.05
7.52
ND
1.88
ND
4.14
ND
0.680
ND
0.984
1.35
1.80
0.978
ND
1.92
ND
3.48
0.672
ND
ND
ND
3.72
ND
2.70
ppbv
0.53
0.21
0.37
0.20
ND
0.70
1.73
ND
ND
0.90
0.27
0.22
ND
0.78
0.13
0.94
ND
0.24
ND
0.46
ND
0.09
ND
0.11
0.15
0.20
0.11
ND
0.21
ND
0.35
0.07
ND
ND
ND
0.34
ND
0.23
ug/m3
2.19
0.87
1.53
0.81
ND
2.87
6.96
ND
ND
3.39
1.26
1.01
ND
3.63
0.57
4.09
ND
1.02
ND
2.42
ND
0.48
ND
0.54
0.74
0.99
0.54
ND
1.05
ND
2.03
0.37
ND
ND
ND
2.17
ND
1.57
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 32 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER029
Pressure @ Receipt: 8" Hg
Comments: upwind canister
Lab ID: 8082101-13
Canister*: ER029
Sampled: 08/12/08 00:00
Received: 08/21/0808:11
Analyzed: 08/28/08 02:58
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
157
159
316
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 33 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3255
Pressure @ Receipt: 8" Hg
Comments: upwind
Lab ID: 8082101-14
Canister #: 3255
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 04:01
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.78
1.08
36.9
1.27
25.7
ND
10.6
ND
ND
12.8
ND
ND
ND
7.32
ND
ND
7.92
ND
ND
ND
ND
1.19
ND
ND
1.37
1.73
6.59
3.11
ND
ND
ND
6.10
ND
ND
3.11
1.39
2.07
3.88
ppbv
0.89
0.54
18.50
0.42
8.57
ND
2.65
ND
ND
3.20
ND
ND
ND
1.46
ND
ND
1.58
ND
ND
ND
ND
0.20
ND
ND
0.27
0.29
1.10
0.52
ND
ND
ND
1.02
ND
ND
0.52
0.20
0.35
0.65
ug/m3
1.02
0.58
22.70
0.73
15.50
ND
6.31
ND
ND
7.62
ND
ND
ND
4.33
ND
ND
4.68
ND
ND
ND
ND
0.70
ND
ND
0.79
1.02
3.88
1.83
ND
ND
ND
3.59
ND
ND
1.79
0.82
1.10
2.23
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 34 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3255
Pressure @ Receipt: 8" Hg
Comments: upwind
Lab ID: 8082101-14
Canister #: 3255
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 04:01
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
4.00
1.13
2.05
1.34
ND
4.11
10.1
ND
ND
4.71
1.71
1.39
ND
4.08
0.856
3.80
ND
1.35
ND
2.86
ND
ND
ND
0.896
ND
1.30
ND
ND
1.16
ND
2.29
ND
ND
ND
ND
0.896
ND
ND
ppbv
0.57
0.16
0.29
0.19
ND
0.59
1.44
ND
ND
0.67
0.21
0.17
ND
0.51
0.11
0.48
ND
0.17
ND
0.32
ND
ND
ND
0.10
ND
0.14
ND
ND
0.13
ND
0.23
ND
ND
ND
ND
0.08
ND
ND
ug/m3
2.35
0.66
1.20
0.77
ND
2.41
5.81
ND
ND
2.54
1.00
0.81
ND
2.39
0.47
2.07
ND
0.73
ND
1.67
ND
ND
ND
0.49
ND
0.71
ND
ND
0.64
ND
1.34
ND
ND
ND
ND
0.52
ND
ND
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 35 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 3255
Pressure @ Receipt: 8" Hg
Comments: upwind
Lab ID: 8082101-14
Canister #: 3255
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 04:01
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
186
126
311
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 36 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC20
Pressure @ Receipt: 8" Hg
Comments: upwind single summa canister
Lab ID: 8082101-15
Canister #: TNAPC20
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/28/08 05:04
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.43
0.777
52.0
1.04
32.6
ND
13.9
ND
ND
18.5
ND
ND
ND
19.7
ND
ND
21.0
ND
ND
ND
ND
1.93
ND
ND
2.25
4.45
19.3
11.6
ND
ND
ND
29.4
ND
ND
16.2
2.13
6.23
23.2
ppbv
0.72
0.39
26.00
0.35
10.90
ND
3.48
ND
ND
4.63
ND
ND
ND
3.94
ND
ND
4.20
ND
ND
ND
ND
0.32
ND
ND
0.45
0.74
3.22
1.93
ND
ND
ND
4.90
ND
ND
2.70
0.30
1.04
3.87
ug/m3
0.82
0.42
32.00
0.60
19.60
ND
8.28
ND
ND
11.00
ND
ND
ND
11.70
ND
ND
12.40
ND
ND
ND
ND
1.14
ND
ND
1.29
2.62
11.40
6.83
ND
ND
ND
17.30
ND
ND
9.31
1.25
3.32
13.30
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 37 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC20
Pressure @ Receipt: 8" Hg
Comments: upwind single summa canister
Lab ID: 8082101-15
Canister #: TNAPC20
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/28/08 05:04
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
11.1
4.00
9.43
5.81
ND
24.2
65.3
ND
ND
24.5
7.98
5.33
ND
23.6
3.44
31.8
ND
5.52
1.11
12.7
ND
1.64
1.40
4.37
2.95
7.44
1.97
ND
6.85
ND
8.82
0.976
ND
ND
ND
7.36
ND
7.57
ppbv
1.59
0.57
1.35
0.83
ND
3.46
9.33
ND
ND
3.50
1.00
0.67
ND
2.95
0.43
3.98
ND
0.69
0.12
1.41
ND
0.21
0.16
0.49
0.33
0.83
0.22
ND
0.76
ND
0.88
0.11
ND
ND
ND
0.67
ND
0.63
ug/m3
6.51
2.35
5.53
3.34
ND
14.20
37.50
ND
ND
13.20
4.67
3.12
ND
13.80
1.87
17.30
ND
3.00
0.64
7.42
ND
1.14
0.77
2.39
1.61
4.07
1.08
ND
3.75
ND
5.14
0.53
ND
ND
ND
4.29
ND
4.40
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 38 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS TNAPC20
Pressure @ Receipt: 8" Hg
Comments: upwind single summa canister
Lab ID: 8082101-15
Canister #: TNAPC20
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/28/08 05:04
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
5.12
570
216
786
ND ND
0.39 2.98
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 39 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER043
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/444 - downwind
Lab ID: 8082101-16
Canister*: ER043
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 06:07
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.11
1.19
40.2
1.10
28.9
ND
13.3
ND
ND
17.8
ND
ND
ND
14.9
ND
ND
18.3
ND
ND
ND
ND
1.83
ND
ND
2.53
3.91
16.0
9.23
ND
ND
ND
20.2
ND
ND
13.7
2.16
8.38
19.7
ppbv
1.06
0.60
20.10
0.37
9.63
ND
3.33
ND
ND
4.45
ND
ND
ND
2.98
ND
ND
3.66
ND
ND
ND
ND
0.31
ND
ND
0.51
0.65
2.67
1.54
ND
ND
ND
3.37
ND
ND
2.28
0.31
1.40
3.28
ug/m3
1.21
0.64
24.80
0.63
17.40
ND
7.92
ND
ND
10.60
ND
ND
ND
8.81
ND
ND
10.80
ND
ND
ND
ND
1.08
ND
ND
1.45
2.30
9.42
5.43
ND
ND
ND
11.90
ND
ND
7.88
1.27
4.47
11.30
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 40 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER043
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/444 - downwind
Lab ID: 8082101-16
Canister*: ER043
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 06:07
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
9.34
3.56
7.38
1.68
2.90
17.5
50.0
ND
1.11
33.0
7.12
5.48
ND
21.9
3.75
39.9
ND
7.37
ND
17.6
0.966
3.00
1.43
5.41
3.72
8.48
2.95
ND
9.63
ND
16.7
1.94
1.24
ND
ND
18.9
ND
15.7
ppbv
1.33
0.51
1.05
0.24
0.36
2.50
7.14
ND
0.14
4.71
0.89
0.69
ND
2.74
0.47
4.99
ND
0.92
ND
1.96
0.12
0.38
0.16
0.60
0.41
0.94
0.33
ND
1.07
ND
1.67
0.22
0.12
ND
ND
1.72
ND
1.31
ug/m3
5.48
2.09
4.33
0.97
1.70
10.30
28.70
ND
0.65
17.80
4.17
3.21
ND
12.80
2.04
21.70
ND
4.01
ND
10.30
0.60
2.09
0.78
2.96
2.04
4.64
1.61
ND
5.27
ND
9.74
1.06
0.68
ND
ND
11.00
ND
9.13
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 41 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER043
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/444 - downwind
Lab ID: 8082101-16
Canister*: ER043
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/08 06:07
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
9.34
564
304
868
ND ND
0.72 5.43
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 42 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 444
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER043 - downwind
Lab ID: 8082101-17
Canister #: 444
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/0808:13
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.70
1.15
41.0
0.946
29.3
ND
13.2
ND
ND
17.9
ND
ND
ND
16.0
ND
ND
18.4
ND
ND
ND
ND
1.82
ND
ND
2.11
3.46
15.0
9.40
ND
ND
ND
20.0
ND
ND
12.8
2.34
8.99
19.3
ppbv
0.85
0.58
20.50
0.32
9.77
ND
3.30
ND
ND
4.48
ND
ND
ND
3.20
ND
ND
3.68
ND
ND
ND
ND
0.30
ND
ND
0.42
0.58
2.50
1.57
ND
ND
ND
3.33
ND
ND
2.13
0.33
1.50
3.22
ug/m3
0.98
0.61
25.30
0.54
17.70
ND
7.86
ND
ND
10.70
ND
ND
ND
9.46
ND
ND
10.90
ND
ND
ND
ND
1.07
ND
ND
1.21
2.04
8.83
5.53
ND
ND
ND
11.80
ND
ND
7.36
1.37
4.80
11.10
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 43 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 444
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER043 - downwind
Lab ID: 8082101-17
Canister #: 444
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/0808:13
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
8.65
3.21
7.99
1.77
2.48
17.8
49.8
ND
ND
32.2
7.63
4.93
ND
21.9
3.73
38.2
ND
6.99
1.36
16.6
ND
2.80
1.88
4.76
2.95
9.53
2.88
ND
8.95
ND
15.1
1.33
1.11
ND
ND
15.4
ND
11.1
ppbv
1.24
0.46
1.14
0.25
0.31
2.54
7.11
ND
ND
4.60
0.95
0.62
ND
2.74
0.47
4.78
ND
0.87
0.15
1.84
ND
0.35
0.21
0.53
0.33
1.06
0.32
ND
0.99
ND
1.51
0.15
0.11
ND
ND
1.40
ND
0.93
ug/m3
5.08
1.88
4.69
1.02
1.45
10.40
28.60
ND
ND
17.40
4.47
2.89
ND
12.80
2.03
20.80
ND
3.80
0.78
9.70
ND
1.95
1.03
2.61
1.61
5.22
1.58
ND
4.90
ND
8.81
0.73
0.61
ND
ND
8.97
ND
6.46
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 44 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 444
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER043 - downwind
Lab ID: 8082101-17
Canister #: 444
Sampled: 08/13/08 12:07
Received: 08/21/0808:11
Analyzed: 08/28/0808:13
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
5.14
543
248
791
ND ND
0.40 2.99
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 45 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167601
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3254
Lab ID: 8082101-18
Canister*: 167601
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 11:37
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.33
ND
11.8
0.998
9.16
ND
7.36
ND
ND
12.2
ND
ND
ND
20.0
ND
ND
22.9
ND
ND
ND
ND
2.09
ND
ND
2.56
5.36
23.0
14.3
ND
ND
ND
32.0
ND
ND
20.6
2.41
7.07
28.9
ppbv
0.67
ND
5.90
0.33
3.05
ND
1.84
ND
ND
3.05
ND
ND
ND
4.00
ND
ND
4.58
ND
ND
ND
ND
0.35
ND
ND
0.51
0.89
3.83
2.38
ND
ND
ND
5.33
ND
ND
3.43
0.34
1.18
4.82
ug/m3
0.76
ND
7.27
0.57
5.52
ND
4.38
ND
ND
7.27
ND
ND
ND
11.80
ND
ND
13.50
ND
ND
ND
ND
1.23
ND
ND
1.47
3.16
13.50
8.42
ND
ND
ND
18.80
ND
ND
11.80
1.41
3.77
16.60
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 46 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167601
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3254
Lab ID: 8082101-18
Canister*: 167601
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 11:37
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n- Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
12.9
4.06
12.7
7.84
ND
30.8
89.5
ND
1.58
32.2
11.1
7.29
3.05
33.4
4.78
53.6
ND
8.68
1.53
19.7
0.856
2.82
2.56
7.17
4.32
12.7
2.69
ND
12.6
ND
14.4
2.28
0.728
ND
ND
13.4
ND
7.14
ppbv
1.84
0.58
1.81
1.12
ND
4.40
12.80
ND
0.20
4.60
1.39
0.91
0.38
4.18
0.60
6.70
ND
1.09
0.17
2.19
0.11
0.35
0.28
0.80
0.48
1.41
0.30
ND
1.40
ND
1.44
0.25
0.07
ND
ND
1.22
ND
0.60
ug/m3
7.57
2.38
7.45
4.51
ND
18.10
51.50
ND
0.93
17.40
6.50
4.27
1.75
19.50
2.60
29.20
ND
4.72
0.88
11.50
0.53
1.97
1.40
3.92
2.36
6.95
1.47
ND
6.90
ND
8.40
1.25
0.40
ND
ND
7.80
ND
4.15
MDL
Flag PPbC
1.44
3.12
1.84
3.12
U 1.76
1.60
1.20
U 2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
U 2.00
1.36
U 2.56
1.36
U 2.56
2.56
1.52
1.20
2.08
1.60
2.32
U 1.60
1.92
U 1.60
1.60
1.76
U 1.44
U 0.960
U 1.36
1.36
U 3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 47 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 167601
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3254
Lab ID: 8082101-18
Canister*: 167601
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 11:37
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
3.12
646
264
909
ND ND
0.24 1.81
ND ND
ND ND
ND ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 48 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3254
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167601
Lab ID: 8082101-19
Canister #: 3254
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 13:42
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.95
1.15
12.3
2.59
9.98
ND
7.78
ND
ND
12.8
ND
ND
ND
15.9
ND
ND
24.6
ND
ND
ND
ND
2.63
ND
ND
3.17
5.98
23.4
14.1
ND
ND
ND
29.0
ND
ND
19.6
2.28
6.55
28.4
ppbv
1.48
0.58
6.15
0.86
3.33
ND
1.95
ND
ND
3.20
ND
ND
ND
3.18
ND
ND
4.92
ND
ND
ND
ND
0.44
ND
ND
0.63
1.00
3.90
2.35
ND
ND
ND
4.83
ND
ND
3.27
0.33
1.09
4.73
ug/m3
1.70
0.61
7.58
1.49
6.01
ND
4.63
ND
ND
7.62
ND
ND
ND
9.40
ND
ND
14.50
ND
ND
ND
ND
1.55
ND
ND
1.82
3.52
13.80
8.30
ND
ND
ND
17.10
ND
ND
11.30
1.34
3.49
16.30
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 49 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3254
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167601
Lab ID: 8082101-19
Canister #: 3254
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 13:42
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n- Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
n-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
14.9
4.80
11.9
8.10
ND
29.4
84.9
ND
1.38
30.0
10.7
6.79
3.01
31.6
5.04
50.7
ND
9.03
1.67
19.3
1.33
2.24
2.52
7.78
5.34
13.2
3.66
ND
13.3
ND
15.5
2.51
1.96
1.18
ND
14.5
1.20
11.4
ppbv
2.13
0.69
1.70
1.16
ND
4.20
12.10
ND
0.17
4.29
1.34
0.85
0.38
3.95
0.63
6.34
ND
1.13
0.19
2.14
0.17
0.28
0.28
0.86
0.59
1.47
0.41
ND
1.48
ND
1.55
0.28
0.20
0.12
ND
1.32
0.10
0.95
ug/m3
8.74
2.82
6.98
4.66
ND
17.20
48.80
ND
0.81
16.20
6.26
3.97
1.73
18.50
2.74
27.60
ND
4.91
0.96
11.30
0.82
1.56
1.38
4.26
2.92
7.23
2.00
ND
7.28
ND
9.04
1.37
1.08
0.65
ND
8.44
0.69
6.63
MDL
Flag PPbC
1.44
3.12
1.84
3.12
U 1.76
1.60
1.20
U 2.48
U 1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
U 2.00
1.36
U 2.56
1.36
U 2.56
U 2.56
1.52
1.20
2.08
1.60
2.32
U 1.60
1.92
U 1.60
1.60
1.76
1.44
0.960
U 1.36
1.36
U 3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 50 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3254
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/167601
Lab ID: 8082101-19
Canister #: 3254
Sampled: 08/13/08 16:52
Received: 08/21/0808:11
Analyzed: 08/29/08 13:42
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
7.24
653
374
1030
ND ND
0.56 4.21
ND ND
ND ND
3.36
3.36
ND
ND
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 51 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER061
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-20
Canister*: ER061
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 15:47
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
;opentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
3.04
1.16
18.1
2.43
13.8
ND
5.91
1.73
ND
7.22
ND
ND
ND
ND
0.862
ND
4.63
ND
ND
ND
ND
0.893
ND
ND
0.870
1.14
3.69
1.50
ND
0.966
ND
3.10
ND
ND
2.23
0.865
1.40
2.02
ppbv
1.52
0.58
9.05
0.81
4.60
ND
1.48
0.43
ND
1.81
ND
ND
ND
ND
0.17
ND
0.93
ND
ND
ND
ND
0.15
ND
ND
0.17
0.19
0.62
0.25
ND
0.16
ND
0.52
ND
ND
0.37
0.12
0.23
0.34
ug/m3
1.75
0.62
11.20
1.40
8.31
ND
3.52
1.00
ND
4.30
ND
ND
ND
ND
0.50
ND
2.74
ND
ND
ND
ND
0.53
ND
ND
0.50
0.67
2.17
0.88
ND
0.56
ND
1.82
ND
ND
1.28
0.51
0.75
1.16
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 52 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER061
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-20
Canister*: ER061
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 15:47
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
i-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
Eastern Research Group
ppbC
5.08
ND
ND
ND
ND
1.52
3.78
ND
0.671
3.27
ND
ND
ND
1.63
ND
1.80
ND
0.787
ND
1.56
ND
ND
ND
ND
ND
ND
ND
ND
0.729
ND
1.04
0.666
ND
ND
ND
0.880
ND
ppbv
0.73
ND
ND
ND
ND
0.22
0.54
ND
0.08
0.47
ND
ND
ND
0.20
ND
0.23
ND
0.10
ND
0.17
ND
ND
ND
ND
ND
ND
ND
ND
0.08
ND
0.10
0.07
ND
ND
ND
0.08
ND
ug/m3
2.98
ND
ND
ND
ND
0.89
2.17
ND
0.39
1.76
ND
ND
ND
0.95
ND
0.98
ND
0.43
ND
0.91
ND
ND
ND
ND
ND
ND
ND
ND
0.40
ND
0.61
0.37
ND
ND
ND
0.51
ND
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 53 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER061
Pressure @ Receipt: 10" Hg
Comments:
Lab ID: 8082101-20
Canister*: ER061
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 15:47
Analvte
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
ND
101
208
309
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 54 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 15280
Pressure @ Receipt: 8" Hg
Comments: Waypoint 207, upwind canister
Lab ID: 8082101-21
Canister #: 15280
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 16:50
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.05
ND
48.3
1.17
27.8
ND
9.87
ND
ND
12.2
ND
ND
ND
11.8
ND
ND
9.66
ND
0.668
ND
0.708
0.964
ND
ND
2.07
2.18
7.57
4.16
ND
ND
ND
7.58
ND
ND
4.56
1.22
5.33
5.71
ppbv
0.53
ND
24.20
0.39
9.27
ND
2.47
ND
ND
3.05
ND
ND
ND
2.36
ND
ND
1.93
ND
0.13
ND
0.14
0.16
ND
ND
0.41
0.36
1.26
0.69
ND
ND
ND
1.26
ND
ND
0.76
0.17
0.89
0.95
ug/m3
0.60
ND
29.80
0.67
16.70
ND
5.88
ND
ND
7.27
ND
ND
ND
6.98
ND
ND
5.71
ND
0.38
ND
0.41
0.57
ND
ND
1.19
1.28
4.46
2.45
ND
ND
ND
4.46
ND
ND
2.62
0.72
2.84
3.28
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 55 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 15280
Pressure @ Receipt: 8" Hg
Comments: Waypoint 207, upwind canister
Lab ID: 8082101-21
Canister #: 15280
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 16:50
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
4.32
2.13
3.62
1.17
ND
5.31
12.3
ND
ND
13.5
2.08
1.41
0.745
5.14
1.58
9.02
ND
2.14
ND
3.13
ND
ND
ND
1.17
ND
1.46
ND
ND
2.01
ND
2.19
ND
ND
ND
ND
2.00
ND
2.82
ppbv
0.62
0.30
0.52
0.17
ND
0.76
1.76
ND
ND
1.93
0.26
0.18
0.09
0.64
0.20
1.13
ND
0.27
ND
0.35
ND
ND
ND
0.13
ND
0.16
ND
ND
0.22
ND
0.22
ND
ND
ND
ND
0.18
ND
0.24
ug/m3
2.53
1.25
2.12
0.67
ND
3.12
7.07
ND
ND
7.28
1.22
0.83
0.43
3.01
0.86
4.91
ND
1.16
ND
1.83
ND
ND
ND
0.64
ND
0.80
ND
ND
1.10
ND
1.28
ND
ND
ND
ND
1.16
ND
1.64
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 56 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS 15280
Pressure @ Receipt: 8" Hg
Comments: Waypoint 207, upwind canister
Lab ID: 8082101-21
Canister #: 15280
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 16:50
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
244
104
348
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 57 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER064
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER069
Lab ID: 8082101-22
Canister*: ER064
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 17:52
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.05
0.710
21.1
1.29
16.1
ND
7.28
ND
ND
9.47
ND
ND
ND
6.07
ND
ND
8.03
ND
ND
ND
ND
0.951
ND
ND
1.50
1.62
7.14
3.44
ND
ND
ND
7.04
ND
ND
4.40
1.06
9.83
6.13
ppbv
1.03
0.36
10.60
0.43
5.37
ND
1.82
ND
ND
2.37
ND
ND
ND
1.21
ND
ND
1.61
ND
ND
ND
ND
0.16
ND
ND
0.30
0.27
1.19
0.57
ND
ND
ND
1.17
ND
ND
0.73
0.15
1.64
1.02
ug/m3
1.18
0.38
13.00
0.74
9.70
ND
4.34
ND
ND
5.64
ND
ND
ND
3.59
ND
ND
4.75
ND
ND
ND
ND
0.56
ND
ND
0.86
0.95
4.20
2.02
ND
ND
ND
4.14
ND
ND
2.53
0.62
5.24
3.52
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 58 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER064
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER069
Lab ID: 8082101-22
Canister*: ER064
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 17:52
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
3.77
1.33
2.31
1.81
ND
5.55
15.0
ND
ND
21.1
2.11
1.30
ND
5.43
1.88
13.3
ND
3.10
ND
2.95
ND
ND
ND
1.44
1.08
1.68
1.12
ND
2.26
ND
2.12
ND
ND
ND
ND
ND
ND
ND
ppbv
0.54
0.19
0.33
0.26
ND
0.79
2.14
ND
ND
3.01
0.26
0.16
ND
0.68
0.24
1.66
ND
0.39
ND
0.33
ND
ND
ND
0.16
0.12
0.19
0.12
ND
0.25
ND
0.21
ND
ND
ND
ND
ND
ND
ND
ug/m3
2.21
0.78
1.36
1.04
ND
3.26
8.62
ND
ND
11.40
1.23
0.76
ND
3.18
1.02
7.23
ND
1.69
ND
1.72
ND
ND
ND
0.79
0.59
0.92
0.61
ND
1.24
ND
1.24
ND
ND
ND
ND
ND
ND
ND
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 59 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER064
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER069
Lab ID: 8082101-22
Canister*: ER064
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 17:52
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
206
76.2
282
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 60 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER069
Pressure @ Receipt: 8" Hg
Comments: Col 2 W/ER064
Lab ID: 8082101-23
Canister*: ER069
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 19:57
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.93
ND
20.8
1.19
16.1
ND
7.33
ND
ND
8.55
ND
ND
ND
6.19
ND
ND
7.80
ND
ND
ND
ND
0.941
ND
ND
1.46
1.57
6.82
3.46
ND
ND
ND
7.79
ND
ND
4.32
1.12
8.69
6.42
ppbv
0.97
ND
10.40
0.40
5.37
ND
1.83
ND
ND
2.14
ND
ND
ND
1.24
ND
ND
1.56
ND
ND
ND
ND
0.16
ND
ND
0.29
0.26
1.14
0.58
ND
ND
ND
1.30
ND
ND
0.72
0.16
1.45
1.07
ug/m3
1.11
ND
12.80
0.68
9.70
ND
4.36
ND
ND
5.09
ND
ND
ND
3.66
ND
ND
4.61
ND
ND
ND
ND
0.55
ND
ND
0.84
0.92
4.01
2.04
ND
ND
ND
4.59
ND
ND
2.48
0.66
4.64
3.69
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 61 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER069
Pressure @ Receipt: 8" Hg
Comments: Col 2 W/ER064
Lab ID: 8082101-23
Canister*: ER069
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 19:57
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
4.28
1.92
2.27
1.77
ND
5.53
15.2
ND
ND
19.8
1.94
1.06
ND
5.07
1.64
12.7
ND
2.74
ND
2.86
ND
ND
ND
1.38
1.09
2.16
0.947
ND
2.84
ND
2.34
ND
ND
ND
ND
1.62
ND
1.23
ppbv
0.61
0.27
0.32
0.25
ND
0.79
2.17
ND
ND
2.83
0.24
0.13
ND
0.63
0.21
1.59
ND
0.34
ND
0.32
ND
ND
ND
0.15
0.12
0.24
0.11
ND
0.32
ND
0.23
ND
ND
ND
ND
0.15
ND
0.10
ug/m3
2.51
1.13
1.33
1.02
ND
3.24
8.74
ND
ND
10.70
1.14
0.62
ND
2.97
0.89
6.91
ND
1.49
ND
1.67
ND
ND
ND
0.76
0.60
1.18
0.52
ND
1.55
ND
1.36
ND
ND
ND
ND
0.94
ND
0.72
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 62 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER069
Pressure @ Receipt: 8" Hg
Comments: Col 2 W/ER064
Lab ID: 8082101-23
Canister*: ER069
Sampled: 08/14/08 11:32
Received: 08/21/0808:11
Analyzed: 08/29/08 19:57
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
205
87.8
293
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 63 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 988
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3248 - waypoint 208
Lab ID: 8082101-24
Canister #: 988
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 22:03
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.27
0.920
12.7
1.24
12.0
ND
10.2
1.99
ND
17.6
ND
ND
ND
18.0
ND
ND
18.6
ND
ND
ND
ND
1.84
ND
ND
2.48
3.31
14.0
8.05
ND
ND
ND
17.4
ND
ND
10.1
1.49
12.0
13.9
ppbv
0.64
0.46
6.35
0.41
4.00
ND
2.55
0.50
ND
4.40
ND
ND
ND
3.60
ND
ND
3.72
ND
ND
ND
ND
0.31
ND
ND
0.50
0.55
2.33
1.34
ND
ND
ND
2.90
ND
ND
1.68
0.21
2.00
2.32
ug/m3
0.73
0.49
7.83
0.71
7.23
ND
6.07
1.14
ND
10.50
ND
ND
ND
10.60
ND
ND
11.00
ND
ND
ND
ND
1.08
ND
ND
1.43
1.95
8.24
4.74
ND
ND
ND
10.20
ND
ND
5.81
0.87
6.40
7.99
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 64 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 988
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3248 - waypoint 208
Lab ID: 8082101-24
Canister #: 988
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 22:03
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
6.54
2.45
5.62
3.30
ND
11.2
31.4
ND
0.706
30.1
3.84
2.61
0.883
11.1
2.09
18.6
ND
3.73
ND
6.40
ND
1.36
0.964
1.70
1.36
3.44
0.983
ND
2.99
ND
4.45
0.693
ND
ND
ND
3.82
ND
3.22
ppbv
0.93
0.35
0.80
0.47
ND
1.60
4.49
ND
0.09
4.30
0.48
0.33
0.11
1.39
0.26
2.33
ND
0.47
ND
0.71
ND
0.17
0.11
0.19
0.15
0.38
0.11
ND
0.33
ND
0.45
0.08
ND
ND
ND
0.35
ND
0.27
ug/m3
3.84
1.44
3.30
1.90
ND
6.57
18.10
ND
0.41
16.20
2.25
1.53
0.51
6.50
1.14
10.10
ND
2.03
ND
3.74
ND
0.95
0.53
0.93
0.74
1.88
0.54
ND
1.64
ND
2.60
0.38
ND
ND
ND
2.22
ND
1.87
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 65 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl 988
Pressure @ Receipt: 10" Hg
Comments: Col 1 w/3248 - waypoint 208
Lab ID: 8082101-24
Canister #: 988
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/29/08 22:03
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
345
138
482
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 66 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3248
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/988 - waypoint 209
Lab ID: 8082101-25
Canister #: 3248
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/30/08 00:08
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
sopentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
1.51
1.65
12.4
1.38
12.1
ND
10.5
ND
ND
16.5
ND
ND
ND
16.0
ND
ND
18.7
0.936
ND
ND
ND
1.84
ND
ND
2.87
3.54
15.4
8.20
ND
ND
ND
18.0
ND
ND
11.0
1.88
12.1
14.5
ppbv
0.76
0.83
6.20
0.46
4.03
ND
2.63
ND
ND
4.13
ND
ND
ND
3.20
ND
ND
3.74
0.19
ND
ND
ND
0.31
ND
ND
0.57
0.59
2.57
1.37
ND
ND
ND
3.00
ND
ND
1.83
0.27
2.02
2.42
ug/m3
0.87
0.88
7.64
0.79
7.29
ND
6.25
ND
ND
9.83
ND
ND
ND
9.46
ND
ND
11.10
0.52
ND
ND
ND
1.08
ND
ND
1.65
2.08
9.07
4.83
ND
ND
ND
10.60
ND
ND
6.32
1.10
6.46
8.34
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 67 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3248
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/988 - waypoint 209
Lab ID: 8082101-25
Canister #: 3248
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/30/08 00:08
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
7.19
2.60
6.48
3.84
ND
11.8
32.7
ND
ND
31.0
4.47
3.15
1.03
11.4
2.05
18.2
ND
3.64
ND
6.05
0.644
1.15
ND
1.91
1.52
2.16
1.70
ND
2.76
ND
4.12
ND
ND
ND
ND
1.34
ND
ND
ppbv
1.03
0.37
0.93
0.55
ND
1.69
4.67
ND
ND
4.43
0.56
0.39
0.13
1.43
0.26
2.28
ND
0.46
ND
0.67
0.08
0.14
ND
0.21
0.17
0.24
0.19
ND
0.31
ND
0.41
ND
ND
ND
ND
0.12
ND
ND
ug/m3
4.22
1.53
3.80
2.21
ND
6.92
18.80
ND
ND
16.70
2.62
1.84
0.59
6.67
1.12
9.90
ND
1.98
ND
3.53
0.40
0.80
ND
1.05
0.83
1.18
0.93
ND
1.51
ND
2.40
ND
ND
ND
ND
0.78
ND
ND
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 68 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 3248
Pressure @ Receipt: 8" Hg
Comments: Col 2 w/988 - waypoint 209
Lab ID: 8082101-25
Canister #: 3248
Sampled: 08/14/08 17:09
Received: 08/21/0808:11
Analyzed: 08/30/08 00:08
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
344
160
504
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 69 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER021
Pressure @ Receipt: 8" Hg
Comments: Waypoint 212, upwind canister
Lab ID: 8082101-26
Canister*: ER021
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0802:13
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
;obutene/l-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
;opentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.88
1.07
153
2.23
99.6
ND
47.7
ND
ND
64.3
ND
ND
ND
ND
1.14
ND
50.8
0.676
ND
ND
ND
3.45
ND
ND
4.60
6.97
29.0
16.0
ND
1.22
ND
33.1
ND
ND
19.3
2.24
22.6
22.8
ppbv
1.44
0.54
76.50
0.74
33.20
ND
11.90
ND
ND
16.10
ND
ND
ND
ND
0.23
ND
10.20
0.14
ND
ND
ND
0.58
ND
ND
0.92
1.16
4.83
2.67
ND
0.20
ND
5.52
ND
ND
3.22
0.32
3.77
3.80
ug/m3
1.66
0.57
94.30
1.28
60.00
ND
28.40
ND
ND
38.30
ND
ND
ND
ND
0.66
ND
30.00
0.38
ND
ND
ND
2.03
ND
ND
2.64
4.10
17.10
9.42
ND
0.70
ND
19.50
ND
ND
11.10
1.31
12.10
13.10
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 70 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER021
Pressure @ Receipt: 8" Hg
Comments: Waypoint 212, upwind canister
Lab ID: 8082101-26
Canister*: ER021
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0802:13
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
9.98
3.43
7.18
4.74
ND
13.3
34.2
ND
0.907
46.0
3.34
2.01
1.27
7.94
2.07
18.2
ND
3.99
1.20
3.31
ND
2.24
ND
1.34
ND
2.16
1.14
ND
2.66
ND
1.90
ND
ND
ND
ND
1.69
ND
1.70
ppbv
1.43
0.49
1.03
0.68
ND
1.90
4.89
ND
0.11
6.57
0.42
0.25
0.16
0.99
0.26
2.28
ND
0.50
0.13
0.37
ND
0.28
ND
0.15
ND
0.24
0.13
ND
0.30
ND
0.19
ND
ND
ND
ND
0.15
ND
0.14
ug/m3
5.86
2.01
4.21
2.72
ND
7.80
19.70
ND
0.53
24.80
1.95
1.18
0.73
4.65
1.13
9.90
ND
2.17
0.69
1.93
ND
1.56
ND
0.73
ND
1.18
0.62
ND
1.46
ND
1.11
ND
ND
ND
ND
0.98
ND
0.99
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 71 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS ER021
Pressure @ Receipt: 8" Hg
Comments: Waypoint 212, upwind canister
Lab ID: 8082101-26
Canister*: ER021
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0802:13
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
763
246
1010
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 72 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER114
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER085 - waypoint 210
Lab ID: 8082101-27
Canister*: ER114
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0803:16
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
ans-2-Butene
s-2-Butene
-Methyl-1-butene
;opentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
ans-2-Pentene
s-2-Pentene
-Methyl- 2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
3.54
1.00
15.6
2.58
12.6
ND
7.44
2.25
ND
10.1
ND
ND
ND
ND
1.08
ND
11.1
1.38
ND
ND
ND
1.02
ND
ND
1.36
1.47
7.09
3.71
ND
0.706
ND
7.65
ND
ND
4.82
0.990
5.72
5.73
ppbv
1.77
0.50
7.80
0.86
4.20
ND
1.86
0.56
ND
2.53
ND
ND
ND
ND
0.22
ND
2.22
0.28
ND
ND
ND
0.17
ND
ND
0.27
0.25
1.18
0.62
ND
0.12
ND
1.28
ND
ND
0.80
0.14
0.95
0.96
ug/m3
2.03
0.53
9.61
1.48
7.59
ND
4.43
1.29
ND
6.01
ND
ND
ND
ND
0.62
ND
6.56
0.77
ND
ND
ND
0.60
ND
ND
0.78
0.87
4.17
2.18
ND
0.41
ND
4.50
ND
ND
2.77
0.58
3.05
3.29
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
0.560
0.880
0.720
0.560
1.44
1.44
0.640
1.12
1.52
0.880
1.04
1.52
1.60
1.36
0.960
1.60
0.800
1.60
1.52
1.52
1.60
1.12
1.60
3.44
0.640
1.60
0.640
1.44
3.44
3.44
3.44
1.84
3.44
3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 73 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER114
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER085 - waypoint 210
Lab ID: 8082101-27
Canister*: ER114
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0803:16
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
i-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
5.16
1.12
2.22
2.20
ND
4.14
11.6
ND
1.16
13.6
1.94
0.966
0.716
4.09
1.15
7.65
ND
1.70
0.640
2.21
ND
1.42
ND
0.780
ND
1.22
ND
ND
1.44
ND
1.88
ND
ND
ND
ND
2.04
ND
1.82
ppbv
0.74
0.16
0.32
0.31
ND
0.59
1.66
ND
0.15
1.94
0.24
0.12
0.09
0.51
0.14
0.96
ND
0.21
0.07
0.25
ND
0.18
ND
0.09
ND
0.14
ND
ND
0.16
ND
0.19
ND
ND
ND
ND
0.19
ND
0.15
ug/m3
3.03
0.66
1.30
1.26
ND
2.43
6.67
ND
0.68
7.34
1.14
0.57
0.41
2.39
0.63
4.16
ND
0.93
0.37
1.29
ND
0.99
ND
0.43
ND
0.67
ND
ND
0.79
ND
1.10
ND
ND
ND
ND
1.19
ND
1.06
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document.
This analytical report must be reproduced in its entirety.
Page 74 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS Cl ER114
Pressure @ Receipt: 8" Hg
Comments: Col 1 W/ER085 - waypoint 210
Lab ID: 8082101-27
Canister*: ER114
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/0803:16
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
182
186
368
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 75 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER085
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER114 - waypoint 211
Lab ID: 8082101-28
Canister*: ER085
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/08 05:21
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
thylene
cetylene
thane
ropylene
ropane
ropyne
sobutane
sobutene/1-Butene
,3-Butadiene
-Butane
rans-2-Butene
is-2-Butene
-Methyl-1-butene
;opentane
-Pentene
-Methyl-1-butene
-Pentane
;oprene
rans-2-Pentene
is-2-Pentene
-Methyl-2-butene
,2-Dimethylbutane
yclopentene
-Methyl-1-pentene
yclopentane
,3-Dimethylbutane
-Methylpentane
-Methylpentane
-Methyl-1-pentene
-Hexene
-Ethyl- 1-butene
-Hexane
ans-2-Hexene
s-2-Hexene
lethylcyclopentane
,4-Dimethylpentane
enzene
yclohexane
Eastern Research Group
ppbC
2.14
1.42
23.4
1.47
19.2
ND
14.0
1.83
ND
28.3
1.45
2.07
ND
ND
2.71
5.54
34.0
1.06
4.83
3.08
4.28
5.83
1.50
ND
4.53
8.46
29.1
16.6
ND
2.01
ND
20.3
ND
ND
14.0
3.31
12.0
10.5
ppbv
1.07
0.71
11.70
0.49
6.40
ND
3.50
0.46
ND
7.08
0.36
0.52
ND
ND
0.54
1.11
6.80
0.21
0.97
0.62
0.86
0.97
0.30
ND
0.91
1.41
4.85
2.77
ND
0.34
ND
3.38
ND
ND
2.33
0.47
2.00
1.75
ug/m3
1.23
0.76
14.40
0.85
11.60
ND
8.34
1.05
ND
16.90
0.83
1.19
ND
ND
1.56
3.19
20.10
0.59
2.78
1.77
2.46
3.43
0.84
ND
2.60
4.98
17.10
9.77
ND
1.16
ND
11.90
ND
ND
8.05
1.94
6.40
6.04
MDL
Flag PPbC
0.560
0.880
0.720
0.560
1.44
U 1.44
0.640
1.12
U 1.52
0.880
1.04
1.52
U 1.60
U 1.36
0.960
1.60
0.800
U 1.60
1.52
1.52
1.60
1.12
U 1.60
U 3.44
0.640
1.60
0.640
1.44
U 3.44
U 3.44
U 3.44
1.84
U 3.44
U 3.44
1.04
1.92
1.92
1.76
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 76 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER085
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER114 - waypoint 211
Lab ID: 8082101-28
Canister*: ER085
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/08 05:21
Speciated
Non-Methane Organic Compounds by GC/FID
Results
Vnalvte
-Methylhexane
,3-Dimethylpentane
-Methylhexane
-Heptene
,2,4-Trimethylpentane
-Heptane
lethylcyclohexane
,2,3-Trimethylpentane
,3,4-Trimethylpentane
oluene
-Methylheptane
-Methylheptane
-Octene
-Octane
thylbenzene
n-Xylene/p-Xylene
tyrene
-Xylene
-Nonene
-Nonane
;opropylbenzene
-Pinene
-Propylbenzene
n-Ethyltoluene
-Ethyltoluene
,3,5-Trimethylbenzene
-Ethyltoluene
-Pinene
,2,4-Trimethylbenzene
-Decene
-Decane
,2,3-Trimethylbenzene
i-Diethylbenzene
-Diethylbenzene
-Undecene
-Undecane
-Dodecene
-Dodecane
Eastern Research Group
ppbC
8.04
4.32
6.98
1.67
4.96
8.84
17.7
ND
1.92
32.9
3.48
3.21
0.779
6.65
4.07
18.9
0.925
5.62
ND
3.77
1.46
ND
1.28
2.64
1.95
2.21
1.52
ND
4.13
ND
2.38
1.07
ND
ND
ND
2.32
ND
ND
ppbv
1.15
0.62
1.00
0.24
0.62
1.26
2.53
ND
0.24
4.70
0.44
0.40
0.10
0.83
0.51
2.36
0.12
0.70
ND
0.42
0.18
ND
0.14
0.29
0.22
0.25
0.17
ND
0.46
ND
0.24
0.12
ND
ND
ND
0.21
ND
ND
ug/m3
4.72
2.53
4.10
0.96
2.90
5.19
10.20
ND
1.12
17.70
2.04
1.88
0.45
3.89
2.21
10.30
0.49
3.06
ND
2.20
0.90
ND
0.70
1.45
1.07
1.21
0.83
ND
2.26
ND
1.39
0.59
ND
ND
ND
1.35
ND
ND
Flag
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
MDL
ppbC
1.44
3.12
1.84
3.12
1.76
1.60
1.20
2.48
1.44
2.64
1.44
1.60
2.48
1.92
1.68
2.48
2.00
1.36
2.56
1.36
2.56
2.56
1.52
1.20
2.08
1.60
2.32
1.60
1.92
1.60
1.60
1.76
1.44
0.960
1.36
1.36
3.36
3.36
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 77 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Description: ARCADIS C2 ER085
Pressure @ Receipt: 10" Hg
Comments: Col 2 W/ER114 - waypoint 211
Lab ID: 8082101-28
Canister*: ER085
Sampled: 08/15/08 12:09
Received: 08/21/0808:11
Analyzed: 08/30/08 05:21
Analvte
l-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Speciated Non-Methane Organic Compounds by GC/FID
Results MDL
ppbC ppbv uq/m3 Flag ppbC
ND
ND
435
198
633
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.36
3.36
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 78 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP1)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2, 3- Di methy 1 buta ne
2-Methylpentane
3-Methylpentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Eastern Research Group
Source
1.21
ND
26.3
1.14
17.8
ND
9.63
ND
ND
13.4
ND
ND
ND
11.4
ND
ND
11.5
ND
ND
ND
ND
1.13
ND
ND
1.68
2.03
8.33
4.32
ND
ND
ND
9.18
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-11 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/12/08
1.31
ND
26.40
0.91
17.50
ND
9.90
ND
ND
13.10
ND
ND
ND
11.80
ND
ND
11.50
ND
ND
ND
ND
1.38
ND
ND
1.17
2.14
8.46
4.47
ND
ND
ND
9.65
ND
ND
Analyzed: 08/27/08
8.10
0.330
22.0
2.02
2.73
2.32
3.35
0.0174
20.0
35.8
5.47
1.58
3.41
5.03
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 79 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP1) Continued
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Trimethyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
Eastern Research Group
Source
5.14
ND
7.88
7.15
4.48
ND
3.13
ND
ND
5.91
16.4
ND
ND
18.2
3.24
2.06
ND
8.25
2.00
12.4
ND
3.02
ND
7.10
ND
ND
ND
1.48
ND
2.50
ND
ND
2.96
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-11 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/12/08
5.64
ND
7.96
7.15
4.54
ND
3.06
ND
ND
6.05
16.00
ND
ND
18.60
3.03
1.88
ND
8.22
2.12
11.90
ND
2.55
ND
6.80
ND
ND
ND
1.43
ND
2.93
ND
ND
2.87
ND
Analyzed: 08/27/08
9.18
0.934
0.0699
1.31
2.07
2.39
2.65
2.04
6.64
9.22
0.437
5.68
3.91
16.9
4.20
3.51
16.0
3.26
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30
30 I
30 I
30
30
30
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 80 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP1) Continued
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8H2903-DUP2)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3-Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
Eastern Research Group
Source
6.73
ND
ND
ND
ND
7.35
ND
6.56
ND
ND
267
188
456
Source
1.58
ND
26.2
1.22
17.2
ND
9.79
ND
ND
16.2
ND
ND
ND
21.7
1.22
ND
15.9
ND
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-11 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-12 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/12/08
6.44
ND
ND
ND
ND
7.78
ND
6.92
ND
ND
267.00
191.00
457.00
08/12/08
1.28
ND
26.70
0.86
17.70
ND
9.99
ND
ND
16.30
ND
ND
ND
22.10
ND
ND
16.20
ND
1.64
ND
Analyzed: 08/27/08
4.42
5.62
5.46
0.255
1.30
0.388
Analyzed: 08/28/08
21.0
1.86
34.9
3.08
2.04
0.548
1.61
2.47
30
30 I
30 I
30 I
30 I
30
30 I
30
30 I
30 I
200
30
200
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30
30
30 I
30
30 I
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 81 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP2) Continued
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3-Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Trimethylpentane
n- Heptane
Methyl cyclohexane
2,2,3-Tri methyl pentane
2,3,4-Trimethylpentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Eastern Research Group
Source
ND
2.25
ND
ND
2.11
3.52
13.3
7.36
ND
ND
ND
10.8
ND
ND
6.95
ND
8.46
7.17
5.04
ND
3.69
ND
ND
6.58
15.5
ND
ND
20.7
3.37
1.89
ND
8.37
2.23
14.2
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-12 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/12/08
1.97
2.24
ND
ND
2.44
3.51
14.10
7.61
ND
ND
ND
11.90
ND
ND
7.76
1.98
9.46
7.42
6.32
ND
4.30
ND
ND
7.44
16.90
ND
ND
22.70
3.57
2.87
ND
9.50
2.57
15.00
Analyzed: 08/28/08
0.223
14.5
0.341
6.34
3.23
9.53
11.0
11.1
3.37
22.6
15.1
12.3
8.80
9.05
5.68
41.0
12.7
14.1
5.28
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30
30 I
30 I
30
30
30
30 I
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 82 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP2) Continued
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8H2903-DUP3)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Eastern Research Group
Source
ND
3.78
ND
7.33
ND
ND
ND
2.12
ND
3.83
ND
ND
3.70
ND
7.26
ND
ND
ND
ND
6.93
ND
4.64
ND
ND
314
181
496
Source
1.90
1.28
39.2
1.10
28.5
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-12 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-16 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/12/08
ND
3.71
ND
7.99
ND
ND
ND
2.12
ND
3.79
ND
ND
4.09
ND
7.74
ND
ND
ND
ND
7.19
ND
4.98
ND
ND
333.00
197.00
529.00
08/13/08
2.11
1.19
40.20
1.10
28.90
ND
Analyzed: 08/28/08
1.95
8.64
0.283
0.945
10.0
6.36
3.73
7.19
5.61
8.12
6.53
Analyzed: 08/28/08
10.7
7.84
2.44
0.0907
1.22
30 I
30
30 I
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30
30 I
30 I
200
30
200
30
30
30
30
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 83 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP3) Continued
Isobutane
Isobutene/1-Butene
1,3-Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n- Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
Eastern Research Group
Source
12.8
ND
ND
17.4
ND
ND
ND
15.1
ND
ND
18.1
ND
ND
ND
ND
2.09
ND
ND
2.40
3.54
15.9
9.04
ND
ND
ND
20.4
ND
ND
13.4
ND
8.72
19.7
9.14
3.58
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-16 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
13.30
ND
ND
17.80
ND
ND
ND
14.90
ND
ND
18.30
ND
ND
ND
ND
1.83
ND
ND
2.53
3.91
16.00
9.23
ND
ND
ND
20.20
ND
ND
13.70
2.16
8.38
19.70
9.34
3.56
Analyzed: 08/28/08
3.59
2.08
1.33
0.853
13.2
5.23
10.2
0.958
2.06
0.881
2.23
3.94
0.167
2.14
0.308
30
30 I
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 84 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP3) Continued
3-Methylhexane
1-Heptene
2,2,4-Trimethylpentane
n- Heptane
Methyl cyclohexane
2,2,3-Tri methyl pentane
2,3,4-Trimethylpentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
Eastern Research Group
Source
7.45
ND
2.84
17.7
50.8
ND
ND
32.8
7.33
5.60
ND
21.3
4.07
38.6
ND
7.04
ND
17.2
ND
ND
ND
5.04
3.40
8.04
2.88
ND
9.15
ND
16.1
ND
ND
ND
ND
18.3
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-16 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
7.38
ND
2.90
17.50
50.00
ND
ND
33.00
7.12
5.48
ND
21.90
3.75
39.90
ND
7.37
ND
17.60
ND
3.00
ND
5.41
3.72
8.48
2.95
ND
9.63
ND
16.70
1.94
ND
ND
ND
18.90
Analyzed: 08/28/08
1.07
2.09
1.22
1.59
0.662
2.92
2.19
2.43
8.24
3.42
4.57
2.28
7.20
9.08
5.34
2.36
5.13
3.66
3.49
30
30 I
30
30
30
30 I
30 I
30
30
30
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 85 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP3) Continued
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8H2903-DUP4)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
Eastern Research Group
Source
ND
15.5
ND
9.05
554
299
853
Source
1.65
ND
40.0
1.11
29.1
ND
12.9
ND
ND
17.5
ND
ND
ND
16.1
ND
ND
18.1
ND
ND
ND
ND
1.69
ND
ND
2.66
3.74
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-16 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-17 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
ND
15.70
ND
9.34
564.00
304.00
868.00
08/13/08
1.70
1.15
41.00
0.95
29.30
ND
13.20
ND
ND
17.90
ND
ND
ND
16.00
ND
ND
18.40
ND
ND
ND
ND
1.82
ND
ND
2.11
3.46
Analyzed: 08/28/08
1.14
3.11
1.85
1.65
1.78
Analyzed: 08/28/08
3.46
2.65
15.7
0.643
2.31
2.17
0.535
1.85
7.07
22.9
7.76
30 I
30
30 I
30
200
30
200
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 86 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP4) Continued
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Trimethyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
Eastern Research Group
Source
15.0
8.93
ND
ND
ND
19.9
ND
ND
12.9
1.99
8.75
18.9
8.57
3.23
7.63
ND
2.63
17.4
49.4
ND
ND
32.0
6.90
4.88
ND
21.3
3.52
37.3
ND
6.85
ND
16.5
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-17 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
15.00
9.40
ND
ND
ND
20.00
ND
ND
12.80
2.34
8.99
19.30
8.65
3.21
7.99
ND
2.48
17.80
49.80
ND
ND
32.20
7.63
4.93
ND
21.90
3.73
38.20
ND
6.99
ND
16.60
ND
2.80
Analyzed: 08/28/08
0.540
5.09
0.912
0.745
16.2
2.69
2.52
0.941
0.528
4.57
5.83
1.97
0.897
0.722
9.96
1.02
2.88
5.74
2.44
1.98
0.779
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30
30
30
30 I
30
30
30
30 I
30 I
30
30
30
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 87 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8H2903 - Summa Canister Prep
Duplicate (B8H2903-DUP4) Continued
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
Eastern Research Group
Source
ND
4.78
3.60
9.80
2.88
ND
8.20
ND
15.3
ND
ND
ND
ND
14.7
ND
11.1
ND
4.59
533
245
778
Source
1.43
1.11
12.6
0.961
9.67
ND
8.35
ND
ND
13.2
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-17 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-18 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
1.88
4.76
2.95
9.53
2.88
ND
8.95
ND
15.10
ND
ND
ND
ND
15.40
ND
11.10
ND
5.14
543.00
248.00
791.00
08/13/08
1.33
ND
11.80
1.00
9.16
ND
7.36
ND
ND
12.20
ND
Analyzed: 08/28/08
0.336
20.1
2.81
0.0694
8.71
1.30
4.72
0.576
11.1
1.90
1.10
1.64
Analyzed: 08/29/08
7.11
6.76
3.78
5.43
12.7
7.59
30 I
30
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30
30 I
30
200
30
200
30
30
30
30
30
30 I
30
30 I
30 I
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 88 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1) Continued
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n- Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2, 2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
Eastern Research Group
Source
ND
ND
21.4
ND
ND
24.0
ND
ND
ND
ND
2.69
ND
ND
2.85
6.02
24.0
14.9
ND
ND
ND
32.2
ND
ND
20.8
2.60
7.08
29.5
13.6
4.98
12.8
8.26
ND
31.5
90.8
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-18 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
ND
ND
20.00
ND
ND
22.90
ND
ND
ND
ND
2.09
ND
ND
2.56
5.36
23.00
14.30
ND
ND
ND
32.00
ND
ND
20.60
2.41
7.07
28.90
12.90
4.06
12.70
7.84
ND
30.80
89.50
Analyzed: 08/29/08
6.74
4.52
24.9
10.8
11.7
4.14
3.91
0.420
1.06
7.62
0.141
1.89
5.01
20.5
0.732
5.33
2.17
1.51
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30
30
30
30
30 I
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 89 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1) Continued
2,2,3-Tri methyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Eastern Research Group
Source
ND
1.74
32.6
11.5
7.27
3.23
34.3
5.30
54.3
ND
9.58
ND
20.0
ND
2.57
3.07
7.52
4.76
12.8
3.68
ND
13.4
ND
15.1
2.17
ND
1.10
ND
13.7
ND
9.78
ND
ND
675
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-18 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
ND
1.58
32.20
11.10
7.29
3.05
33.40
4.78
53.60
ND
8.68
ND
19.70
ND
2.82
2.56
7.17
4.32
12.70
2.69
ND
12.60
ND
14.40
2.28
ND
ND
ND
13.40
ND
7.14
ND
ND
646.00
Analyzed: 08/29/08
10.0
1.20
3.27
0.247
5.80
2.77
10.4
1.28
9.79
1.53
9.43
18.4
4.67
9.83
1.39
31.0
6.13
4.99
4.86
1.53
31.2
4.48
30 I
30
30
30
30
30
30
30
30
30 I
30
30 I
30
30 I
30
30
30
30
30
30
30 I
30
30 I
30
30
30 I
30
30 I
30
30 I
30
30 I
30 I
200
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 90 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP1) Continued
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP2)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
Eastern Research Group
Source
277
953
Source
2.90
ND
11.9
2.55
9.28
ND
7.55
ND
ND
11.9
ND
ND
ND
13.5
ND
ND
23.6
ND
ND
ND
ND
2.33
ND
ND
3.12
5.57
23.5
14.0
ND
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-18 Prepared
ppbC
ppbC
: 8082101-19 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
264.00
909.00
08/13/08
2.95
1.15
12.30
2.59
9.98
ND
7.78
ND
ND
12.80
ND
ND
ND
15.90
ND
ND
24.60
ND
ND
ND
ND
2.63
ND
ND
3.17
5.98
23.40
14.10
ND
ND
ND
Analyzed: 08/29/08
5.08
4.66
Analyzed: 08/29/08
1.54
3.60
1.75
7.30
2.99
7.00
16.1
4.06
12.1
1.72
7.02
0.515
0.916
30
200
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 91 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP2) Continued
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2, 2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Trimethyl pentane
2, 3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
Eastern Research Group
Source
30.5
ND
ND
20.6
2.38
6.78
28.8
14.8
4.69
12.2
8.29
ND
29.9
87.7
ND
1.47
30.0
10.3
7.48
3.50
31.9
4.98
50.7
ND
9.03
ND
19.8
ND
ND
2.69
7.75
5.62
13.2
3.69
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-19 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
29.00
ND
ND
19.60
2.28
6.55
28.40
14.90
4.80
11.90
8.10
ND
29.40
84.90
ND
ND
30.00
10.70
6.79
3.01
31.60
5.04
50.70
ND
9.03
ND
19.30
ND
ND
2.52
7.78
5.34
13.20
3.66
Analyzed: 08/29/08
4.80
4.99
4.43
3.45
1.40
1.02
2.44
2.38
2.25
1.66
3.22
0.113
3.82
9.57
14.9
0.835
1.14
0.0493
0.0886
2.25
6.53
0.348
5.20
0.190
0.761
30
30 I
30 I
30
30
30
30
30
30
30
30
30 I
30
30
30 I
30
30
30
30
30
30
30
30
30 I
30
30 I
30
30 I
30 I
30
30
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 92 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP2) Continued
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP3)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3-Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Eastern Research Group
Source
ND
13.5
ND
14.7
2.55
2.22
1.50
ND
14.5
ND
10.8
ND
7.10
654
362
1020
Source
1.86
ND
20.6
1.07
15.7
ND
6.94
1.38
ND
9.38
ND
ND
ND
6.30
ND
ND
8.19
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-19 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-22 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/13/08
ND
13.30
ND
15.50
2.51
1.96
1.18
ND
14.50
ND
11.40
ND
7.24
653.00
374.00
1,030.00
08/14/08
2.05
ND
21.10
1.29
16.10
ND
7.28
ND
ND
9.47
ND
ND
ND
6.07
ND
ND
8.03
Analyzed: 08/29/08
0.888
4.94
1.42
12.6
23.6
0.352
5.18
1.87
0.139
3.30
1.10
Analyzed: 08/29/08
9.31
2.64
18.3
2.26
4.70
0.987
3.75
1.95
30 I
30
30 I
30
30
30
30
30 I
30
30 I
30
30 I
30
200
30
200
30
30 I
30
30
30
30 I
30
30
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 93 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP3) Continued
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3-Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Tri methyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
Eastern Research Group
Source
ND
ND
ND
ND
1.25
ND
ND
1.73
1.88
7.03
3.45
ND
ND
ND
8.15
ND
ND
4.80
ND
9.68
6.31
3.66
ND
3.58
ND
2.35
5.78
15.1
ND
ND
20.2
1.72
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-22 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
ND
ND
ND
ND
ND
ND
ND
1.50
1.62
7.14
3.44
ND
ND
ND
7.04
ND
ND
4.40
ND
9.83
6.13
3.77
ND
2.31
ND
ND
5.55
15.00
ND
ND
21.10
2.11
ND
ND
Analyzed: 08/29/08
13.9
14.9
1.53
0.349
14.7
8.74
1.58
2.80
2.93
43.2
4.01
0.864
4.38
20.0
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30 I
30
30 I
30
30
30
30 I
30 I
30
30
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 94 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP3) Continued
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP4)
Ethylene
Acetylene
Ethane
Eastern Research Group
Source
5.37
1.99
12.4
ND
2.61
ND
3.06
ND
ND
ND
ND
ND
1.92
ND
ND
1.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
208
70.8
278
Source
1.60
ND
20.9
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-22 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-23 Prepared
ppbC
ppbC
ppbC
08/14/08
5.43
1.88
13.30
ND
3.10
ND
2.95
ND
ND
ND
1.44
ND
1.68
ND
ND
2.26
ND
2.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
206.00
76.20
282.00
08/14/08
1.93
ND
20.80
Analyzed: 08/29/08
1.02
5.58
6.31
17.3
3.86
13.7
13.2
0.856
7.44
1.32
Analyzed: 08/29/08
18.9
0.777
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
200
30
200
30
30 I
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 95 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP4) Continued
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Di methyl pentane
Benzene
Eastern Research Group
Source
1.61
15.5
ND
6.74
ND
ND
8.74
ND
ND
ND
5.85
ND
ND
7.67
ND
ND
ND
ND
ND
ND
ND
2.06
1.76
6.69
3.36
ND
ND
ND
7.96
ND
ND
4.74
ND
8.44
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-23 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
1.19
16.10
ND
7.33
ND
ND
8.55
ND
ND
ND
6.19
ND
ND
7.80
ND
ND
ND
ND
ND
ND
ND
1.46
ND
6.82
3.46
ND
ND
ND
7.79
ND
ND
4.32
ND
8.69
Analyzed: 08/29/08
30.2
3.55
8.33
2.15
5.68
1.69
34.0
1.95
3.20
2.16
9.09
2.92
30
30
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 96 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP4) Continued
Cyclohexane
2-Methylhexane
2,3-Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Tri methyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
Eastern Research Group
Source
6.51
4.27
ND
2.62
ND
ND
5.32
15.3
ND
ND
20.7
2.34
ND
ND
5.17
1.88
12.7
ND
2.77
ND
2.85
ND
ND
ND
1.48
ND
1.89
ND
ND
2.58
ND
2.04
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-23 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
6.42
4.28
ND
2.27
ND
ND
5.53
15.20
ND
ND
19.80
1.94
ND
ND
5.07
ND
12.70
ND
2.74
ND
2.86
ND
ND
ND
1.38
ND
2.16
ND
ND
2.84
ND
2.34
ND
ND
Analyzed: 08/29/08
1.27
0.257
14.3
3.95
0.236
4.34
18.8
2.01
0.0550
0.798
0.630
7.11
13.4
9.41
13.9
30
30
30 I
30
30 I
30 I
30
30
30 I
30 I
30
30
30 I
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
30
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 97 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP4) Continued
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP5)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
Eastern Research Group
Source
ND
ND
1.57
ND
ND
ND
ND
208
83.6
291
Source
1.26
0.953
12.5
1.55
12.0
ND
10.1
1.39
ND
16.8
ND
ND
ND
17.7
ND
ND
18.2
ND
ND
ND
ND
2.02
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-23 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-24 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
ND
ND
1.62
ND
ND
ND
ND
205.00
87.80
293.00
08/14/08
1.27
0.92
12.70
1.24
12.00
ND
10.20
1.99
ND
17.60
ND
ND
ND
18.00
ND
ND
18.60
ND
ND
ND
ND
1.84
ND
Analyzed: 08/29/08
3.19
1.34
4.93
0.504
Analyzed: 08/29/08
0.395
3.52
1.79
22.7
0.326
0.858
35.3
4.35
1.78
2.10
9.39
30 I
30 I
30
30 I
30 I
30 I
30 I
200
30
200
30
30
30
30
30
30 I
30
30
30 I
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 98 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP5) Continued
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2, 2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Trimethyl pentane
2, 3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
Eastern Research Group
Source
ND
2.27
3.17
14.7
8.19
ND
ND
ND
19.4
ND
ND
10.9
ND
13.1
14.9
6.99
ND
5.98
3.87
ND
12.6
35.9
ND
ND
31.8
4.46
3.01
ND
11.5
2.47
19.3
ND
4.17
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-24 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
ND
2.48
3.31
14.00
8.05
ND
ND
ND
17.40
ND
ND
10.10
ND
12.00
13.90
6.54
ND
5.62
3.30
ND
11.20
31.40
ND
ND
30.10
3.84
2.61
ND
11.10
2.09
18.60
ND
3.73
ND
Analyzed: 08/29/08
8.68
4.32
4.52
1.66
11.2
7.40
8.40
6.96
6.56
6.10
16.1
11.8
13.2
5.44
15.1
14.1
3.23
16.4
3.96
11.3
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30 I
30
30
30 I
30
30
30 I
30 I
30
30
30
30 I
30
30
30
30 I
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 99 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP5) Continued
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP6)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3-Butadiene
Eastern Research Group
Source
6.36
ND
ND
ND
1.90
ND
3.35
ND
ND
3.30
ND
4.50
ND
ND
ND
ND
3.85
ND
ND
ND
ND
363
142
505
Source
1.71
1.33
12.3
0.868
12.4
ND
10.5
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-24 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-25 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
6.40
ND
ND
ND
1.70
ND
3.44
ND
ND
2.99
ND
4.45
ND
ND
ND
ND
3.82
ND
ND
ND
ND
345.00
138.00
482.00
08/14/08
1.51
1.65
12.40
1.38
12.10
ND
10.50
ND
ND
Analyzed: 08/29/08
0.580
11.5
2.62
9.78
1.18
0.860
5.11
3.28
4.59
Analyzed: 08/30/08
12.6
21.1
1.08
45.9
2.17
0.390
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30 I
30 I
200
30
200
30
30
30
30
30
30 I
30
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 100 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP6) Continued
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl-l-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3-Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
Eastern Research Group
Source
17.6
ND
ND
ND
16.0
ND
ND
19.0
ND
ND
ND
ND
1.82
ND
ND
2.46
3.60
14.8
8.20
ND
ND
ND
18.2
ND
ND
11.0
ND
13.0
14.8
7.18
ND
6.10
3.68
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-25 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
16.50
ND
ND
ND
16.00
ND
ND
18.70
ND
ND
ND
ND
1.84
ND
ND
2.87
3.54
15.40
8.20
ND
ND
ND
18.00
ND
ND
11.00
ND
12.10
14.50
7.19
ND
6.48
3.84
ND
Analyzed: 08/30/08
6.47
0.263
1.53
0.765
15.4
1.57
3.68
0.0122
1.36
0.245
7.30
1.93
0.139
6.03
4.26
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30 I
30
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 101 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP6) Continued
n- Heptane
Methyl cyclohexane
2,2,3-Trimethylpentane
2,3,4-Trimethylpentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
Eastern Research Group
Source
12.5
34.3
ND
ND
32.4
4.40
3.48
ND
11.8
2.25
18.9
ND
3.94
ND
6.17
ND
ND
ND
1.63
ND
1.79
ND
ND
2.37
ND
3.86
ND
ND
ND
ND
1.40
ND
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-25 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
11.80
32.70
ND
ND
31.00
4.47
3.15
ND
11.40
2.05
18.20
ND
3.64
ND
6.05
ND
ND
ND
1.91
ND
2.16
ND
ND
2.76
ND
4.12
ND
ND
ND
ND
ND
ND
ND
ND
Analyzed: 08/30/08
5.24
4.68
4.26
1.67
9.89
3.29
9.11
3.87
8.13
1.96
15.7
18.9
15.3
6.50
30
30
30 I
30 I
30
30
30
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 102 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP6) Continued
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP7)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3-Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
2-Methyl-l-butene
n-Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
3-Methylpentane
2-Methyl-l-pentene
Eastern Research Group
Source
ND
349
161
511
Source
4.07
ND
15.7
2.54
13.1
ND
7.19
2.45
ND
10.5
ND
ND
ND
ND
ND
ND
10.4
ND
ND
ND
ND
1.20
ND
ND
1.46
1.62
6.92
3.64
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-25 Prepared
ppbC
ppbC
ppbC
ppbC
: 8082101-27 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/14/08
ND
344.00
160.00
504.00
08/15/08
3.54
1.00
15.60
2.58
12.60
ND
7.44
2.25
ND
10.10
ND
ND
ND
ND
1.08
ND
11.10
ND
ND
ND
ND
ND
ND
ND
1.36
ND
7.09
3.71
ND
Analyzed: 08/30/08
1.53
0.846
1.32
Analyzed: 08/30/08
14.1
0.691
1.52
3.42
3.49
8.60
3.39
6.21
7.51
2.38
1.93
30 I
200
30
200
30
30 I
30
30
30
30 I
30
30
30 I
30
30 I
30 I
30 I
30 I
30 I
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30
30
30
30
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 103 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP7) Continued
l-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2-Methylhexane
2,3-Dimethylpentane
3-Methylhexane
1-Heptene
2,2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Tri methyl pentane
2,3,4-Tri methyl pentane
Toluene
2-Methylheptane
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
Eastern Research Group
Source
ND
ND
7.64
ND
ND
4.93
ND
5.76
5.86
5.14
ND
2.31
ND
ND
4.34
11.6
ND
ND
13.7
1.47
ND
ND
3.49
ND
7.79
ND
1.95
ND
2.05
ND
ND
ND
ND
ND
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-27 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/15/08
ND
ND
7.65
ND
ND
4.82
ND
5.72
5.73
5.16
ND
2.22
ND
ND
4.14
11.60
ND
ND
13.60
1.94
ND
ND
4.09
ND
7.65
ND
1.70
ND
2.21
ND
ND
ND
ND
ND
Analyzed: 08/30/08
0.0523
2.22
0.610
2.28
0.369
3.88
4.57
0.570
0.337
27.8
15.9
1.80
13.7
7.66
30 I
30 I
30
30 I
30 I
30
30 I
30
30
30
30 I
30
30 I
30 I
30
30
30 I
30 I
30
30
30 I
30 I
30
30 I
30
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30 I
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 104 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP7) Continued
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Duplicate (B8I0101-DUP8)
Ethylene
Acetylene
Ethane
Propylene
Propane
Propyne
Isobutane
Isobutene/1-Butene
1,3- Butadiene
n- Butane
trans-2-Butene
cis-2-Butene
3-Methyl-l-butene
Isopentane
1-Pentene
Eastern Research Group
Source
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.83
ND
ND
ND
ND
179
185
364
Source
2.29
1.29
23.8
1.63
19.0
ND
14.1
1.80
ND
28.2
1.44
1.71
ND
ND
2.48
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-27 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
: 8082101-28 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/15/08
ND
ND
ND
ND
ND
1.88
ND
ND
ND
ND
2.04
ND
ND
ND
ND
182.00
186.00
368.00
08/15/08
2.14
1.42
23.40
1.47
19.20
ND
14.00
1.83
ND
28.30
1.45
2.07
ND
ND
2.71
Analyzed: 08/30/08
10.9
1.57
0.614
1.09
Analyzed: 08/30/08
6.81
9.52
1.81
10.0
0.727
0.527
1.82
0.357
0.763
18.7
8.87
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30 I
30
30 I
30 I
30 I
30 I
200
30
200
30
30
30
30
30
30 I
30
30
30 I
30
30
30
30 I
30 I
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document
This analytical report must be reproduced in its
entirety.
Page 105 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP8) Continued
2-Methyl-l-butene
n- Pentane
Isoprene
trans-2-Pentene
cis-2-Pentene
2-Methyl-2-butene
2,2-Dimethylbutane
Cyclopentene
4-Methyl-l-pentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
3-Methyl pentane
2-Methyl- 1-pentene
1-Hexene
2-Ethyl-l-butene
n-Hexane
trans-2-Hexene
cis-2-Hexene
Methyl cyclopentane
2,4- Dimethyl pentane
Benzene
Cyclohexane
2-Methylhexane
2,3- Dimethyl pentane
3-Methylhexane
1-Heptene
2, 2,4-Tri methyl pentane
n- Heptane
Methyl cyclohexane
2,2,3-Trimethyl pentane
2, 3,4-Tri methyl pentane
Toluene
2-Methylheptane
Eastern Research Group
Source
6.10
33.6
ND
5.56
2.78
5.02
5.85
ND
ND
4.18
7.98
28.6
16.7
ND
ND
21.4
21.4
ND
4.14
13.9
3.25
12.6
10.9
8.86
4.74
9.15
6.98
6.98
8.91
18.1
ND
1.80
33.1
3.26
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-28 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/15/08
5.54
34.00
ND
4.83
3.08
4.28
5.83
ND
ND
4.53
8.46
29.10
16.60
ND
ND
ND
20.30
ND
ND
14.00
3.31
12.00
10.50
8.04
4.32
6.98
ND
4.96
8.84
17.70
ND
1.92
32.90
3.48
Analyzed: 08/30/08
9.62
1.22
14.0
10.4
16.0
0.205
7.94
5.82
1.46
0.0901
5.31
0.603
2.01
5.22
3.74
9.71
9.47
26.9
33.9
0.823
2.40
6.24
0.406
6.62
30
30
30 I
30
30
30
30
30 I
30 I
30
30
30
30
30 I
30 I
30
30
30 I
30
30
30
30
30
30
30
30
30
30
30
30
30 I
30
30
30
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 106 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Analyte
Result
Speciated Non-Methane Organic Compounds by
Batch B8I0101 - Summa Canister Prep
Duplicate (B8I0101-DUP8) Continued
3-Methylheptane
1-Octene
n-Octane
Ethyl benzene
m-Xylene/p-Xylene
Styrene
o-Xylene
1-Nonene
n-Nonane
Isopropyl benzene
a-Pinene
n-Propyl benzene
m-Ethyltoluene
p-Ethyltoluene
1,3,5-Tri methyl benzene
o-Ethyltoluene
b-Pinene
1,2,4-Tri methyl benzene
1-Decene
n-Decane
1,2,3-Tri methyl benzene
m-Di ethyl benzene
p-Di ethyl benzene
1-Undecene
n-Undecane
1-Dodecene
n-Dodecane
1-Tridecene
n-Tridecane
SNMOC (Sum of Knowns)
Sum of Unknowns
TNMOC
Eastern Research Group
Source
2.96
ND
6.67
4.28
19.3
ND
5.70
ND
3.48
ND
ND
ND
2.74
ND
2.58
ND
ND
3.63
ND
3.25
ND
ND
ND
ND
2.12
ND
ND
ND
204
688
188
876
Units
Source
Result
RPD
RPD
Limit Notes
GC/FID - Quality Control
: 8082101-28 Prepared
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
ppbC
08/15/08
3.21
ND
6.65
4.07
18.90
ND
5.62
ND
3.77
ND
ND
ND
2.64
ND
2.21
ND
ND
4.13
ND
2.38
ND
ND
ND
ND
2.32
ND
ND
ND
ND
435.00
198.00
633.00
Analyzed: 08/30/08
7.94
0.255
5.13
2.14
1.39
8.03
3.87
15.4
12.8
30.9
9.01
45.2
5.39
32.3
30
30 I
30
30
30
30 I
30
30 I
30
30 I
30 I
30 I
30
30 I
30
30 I
30 I
30
30 I
30
30 I
30 I
30 I
30 I
30
30 I
30 I
30 I
30
200
30
200
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 107 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Notes and Definitions
U Under Detection Limit
E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is
considered an estimate (CLP E-flag).
D-01 This result obtained by diluting and reanalyzing the sample.
ND Analyte NOT DETECTED at or above the Method Detection Limit (MDL)
NR Not Reported
MDL Method Detection Limit
RPD Relative Percent Difference
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 108 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Items for Project Manager Review
LabNumber
8082101-04
8082101-04
8082101-04
8082101-04
8082101-07
8082101-05
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
B8H2903-DUP2
B8I0101-DUP8
B8I0101-DUP6
Eastern Research
Analysis
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
Group
Analyte
n-Undecane
2-Methylheptane
1,3,5-Trimethyl benzene
1,2,4-Trimethyl benzene
Toluene
Toluene
Toluene
3-Methyl heptane
o-Xylene
3-Methyl hexane
n-Octane
n-Nonane
n- Hexane
n- Heptane
n-Decane
(Air)
(Air)
p-Ethyltoluene
3-Methylheptane
n-Decane
Propylene
Exception
D-01: This result obtained by diluting and reanalyzing the
sample.
This is a modified report
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
U-Flags used
Result calculations based on MDL
VERSION 5.85:2863
D-01: This result obtained by diluting and reanalyzing the
sample.
Exceeds RPD control limit
Exceeds RPD control limit
Exceeds RPD control limit
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 109 of 110
-------
CERTIFICATE OF ANALYSIS
ARCADIS
4915 Prospectus Drive
Durham, NC27713
ATTN: Mark Modrak
PHONE: (919)544-4535
FAX: (919)544-5690
FILE#: 3530.00.007
REPORTED: 09/25/08 07:21
SUBMITTED: 08/21/08
AQS SITE CODE:
SITE CODE: Lagoon
Items for Project Manager Review
LabNumber
B8I0101-DUP5
B8I0101-DUP4
B8I0101-DUP4
B8I0101-DUP3
B8I0101-DUP1
8082101-04
B8H2903-DUP2
B8I0101-DUP8
B8H2903-DUP1
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
8082101-04
B8I0101-DUP1
Analysis
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
SNMOC
Analyte
Isobutene/1-Butene
Propylene
Cyclopentane
3-Methylhexane
o-Ethyltoluene
2-Methylhexane
Propylene
2,2,4-Trimethylpentane
Cyclopentane
m-Xylene/p-Xylene
m-Ethyltoluene
Methyl cyclohexane
Ethyl benzene
Cyclohexane
Benzene
a-Pinene
n-Dodecane
Exception
Exceeds PJ>D control limit
Exceeds PJ>D control limit
Exceeds PJ>D control limit
Exceeds PJ>D control limit
Exceeds PJ>D control limit
D-01: This result obtained by diluting and reanalyzing the
sample.
Exceeds PJ>D control limit
Exceeds PJ>D control limit
Exceeds PJ>D control limit
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
D-01: This result obtained by diluting and reanalyzing the
sample.
Exceeds PJ>D control limit
Eastern Research Group
The results in this report apply only to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 110 of 110
-------
D i recto ry: g:\MASSSPEG4 P AIA\N 8 H -
injection Log
Line Viaf FileName Multiplier SampieName
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
N8h~QQ1 .d
N8h~002.d
N8h~Q03,d
N8h~G04.d
N8h~GQ5,d
N8b~006.d
N8h~QQ7.d
N8ti~QOS.d
N8h~QQ9.d
N 8 h~01 0.,d
NBh~011.d
N8h~Gl2,d
N8li-0l3.d
N8h~014.d
N3li-015.d
N8h~016.d
NSh-017,d
N8h~018.d
N8h-019.d
N8h~020.d
1.
1.
1.
S.
8.
2.
8.
2.
8.
8.
8.
8.
8,
8.
8,
8.
8,
8.
8.
8.
SNMOC
5
BLK
8082101-04
8082101-05
8082101-06
8082101-07
8082101-08
8082101-09
8082101-10
8082101-11
8082101-11
8082101-12
8082101-12
8082101-13
8082101-14
8082101-15
8082101-16
8082101-16
8082101-17
21 21 NSh-021 .d
8082101-17
Misc Info Injected
QC 27 Aug 2008
QC 27 Aug 2008
QC 27 Aug 2008
TNAPC11 ARGADIS 27 Aug 2008
926ARCADIS 27Aug2008
3639A ARCADIS 27 Aug 2008
648 ARCADIS 27 Aug 2008
ER038ARCADIS 27Aug20G8
ER001 ARCADIS 27 Aug 2008
ER047 ARCADIS 27 Aug 2008
167604 ARCADIS DO,.. 27 Aug 2008
167604 ARCADIS DO,... 27 Aug 2008
659 ARCADIS DOWNW,.. 28 Aug 2008
659 ARCADIS DOWNW... 28 Aug 2008
E R02 9 ARCAD IS U P WIN D 28Aug2008
3255 ARCADIS UPWIND 28 Aug 2008
TNAPC20 ARCADIS U... 28 Aug 2008
ER043 ARCADIS DOW... 28 Aug 2008
ER043 AR C AD IS DO W... 28 Au g 20 08
444 ARCADIS DOWNW... 28 Aug 2008
444 ARCADIS DOWNW... 28 Aug 2008
11:19
13:01
14:11
15:15
16:19
17:26
18:29
19:35
20:38
21:42
22:45
23:48
00:51
01:54
02:58
04:01
05:04
06:07
07:10
08:13
09:15
Pagel
28 Aug 2008 11:45
-------
Evaluate Cont. i nu i ng Cal ib rat ion Rep
D a t a Path.
Dstn File
Acq On
Operator
Sample
^sc
ALS V^al
C : \ EELS d c h era \ 1 \ DAT A \
N8H-002.U
21 Aug 2008 1:01 pm
RDL
5.00
ig fl) ; (Sig fi2)
Sample Multiplier; 1
Quant Time: Aug 21 13:56:31 2008
Quant Method
Quant Title
Ql.ast Updatf:
Response via
C;\msd c h em\1\MET HO DS\N 310 4 ,M
TO-15 by Selective Ion Anaiys.
Wed. Aug 06 09:23:31 2009
Initial
Kin .
Max,
1 IS
2
3
4
5
6
7
B
9
"1 0
11
12
13
1 a
15
1G
17
18
19
20
21
22
23
24
25
26
27
28
29
30 IS
31
32
33
34
35
36
37
38
39
40
41
42
43
RRF : 0.000 Kin. Rel. Area : IS
RRF Dev ; 30% Max. Rel, Area : 5001
Compound
IS-HEXAKE-d.14
ACETYLEX'S
PRGFYLENE
D ICTiLGRODI FLUORGMETHANE
CHLO ROM ETHANE
0 1 C H LOROT ET RA F LIJO RO E T HA
VINYL CHLORIDE
1, 3-BUTADTENE
BROKGM ETHANE
CH LOR OET HAKE
Ethanol
ACETOMITRILE
Ac roll. 1 en
T R I C H LO RO F LUOROME T HP.NE
ACRYLGlsilTRILE
1 , 1 - D I C F-l LOHO E T HE N E
ME T H YL EN E C EH ,O RIDE,
C AR 30 M D I S U L F 1 DE
T R 1 CH LOR OT R I FLU 0 ROE T HANE
TRANS- 1, 2-DICHLOROETHYLEN1
1 , ] -01CHLOROETHANE
MSTHYL TERT -BUTYL ETHER
K ETHYL ETHYL KETONE
CHLOROPREME
CTS-1, 2-DICHLORGETHYLENE
B ROMG C E TT.O ROME THAN E
CHLOROFORM
ETHYL TERT BUTYL ETETBR
1, 2-DICHLOROETHAME
IS-1,4-DIF LUORO BE K Z E ME
1,1, 1-TRICHLOROETHANE
BENZENE
CAK30S TETRACHLORI DE
TERT-AMYL METHYL ETHER
1 , 2-DICIJLGROPROPANE
ETHYL ACRYLATE
BROMODICHLOROMETHANE
TR I C E ILO RGET H YL EN E
MET]! Y L ME TI i AC R YLAT E
CI3-1 , 3-D7CHLOROPROFELNS
METHYL IS03LTTYL KETOME
TRANS - 1 , 3-DICHLOROPROPENE
1 , 1 , 2 - T R 1 C H LO RO'ETHAN E
Amount
7
4
5
4
4
4
4
•;•,
4
j\
&
4
4
4
5
5
A
4
5
5-
4
4
5
5
5
5
&
5
7
5
5
5
4
5
4
5
5
4
5
5
c
4
.500
. 900
.010
. 8 0 0
.810
.880
.930
.050
,940
.930
.810
.660
.900
.900
.270
.270
.900
.900
-030
,070
.800
.960
.130
.170
.080
-090
,580
.040
,500
.070
.030
.040
.600
.030
, 650
.270
.030
, G20
.270
.270
.520
-970
Max, H
Calc.
7
r?
5
4
5
4
4
5
4
-1
4
3
4
4
5
5
5
z
4
4
3
3
5
4
4
4
4
5
7
3
3
4
3
3
3
4
3
4
3
q.
3
4
.500
.811
.893
.558
. 662
.581
.767
.234
.603
.597
.873
.631
.861
.914
.170
. 61 9
-169
,866
. 969
.942
.963
.926
-127
,805
,708
-639
.011
.027
.500
.894
.777
.001
.681
,985
-808
.167
-694
,031
,711
-2V 2
.987
-046
. . T . Dev
0 , 5 Grain
% r>e v Are a % Dev f jm j n 3
0 . 0
-18.6
-17.
5.
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6,
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1
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0.
1.
2 .
17.
20.
i
7.
7.
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12.
0.
0,
23.
24,
20.
20.
20.
18.
20.
26,
12.
29.
-C .
27.
1 8 ,
2
8
3
0
B
3
6
5
7
2
5
8
0
1
3
9
d
3
0
2
9
6
0
8
9
6
7
6
0
8
6
66
74
79
60
-7 s.
59
59
55
59
61
53
b3
62
54
62
72
65
67
61
i 7
49
64
60
59
56
50
61
~? £*
59
55
62
54
56
48
57
55
62
49
65
49
58
0.
0.
0.
0.
0.
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0.
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00
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00
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00
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
GO
00
00
00
00
00
00
44 IS IS-CHLOROEF.NEE^E-dT)
7 . 5-00
7.500
0.0
0 . 00
-------
45
46
41
48
49
50
51
52
53
51
55
56
57
58
59
60
61
62
63
64
65
TOLUENE
DIB EC MQC H LO ROM E T Ai THE
1 , 3-DISKOMOETJIANE
H -OCTANE
T E T R AC H LO E<0 ET H YL-EN E
GHLOROBEKZEME
VTHYLBENZES3
M, P-XYLENE
BROMOFORM
STYRENE
1,1,2, 2 - T ET RACE LORO ETHANE
0 - XYLEWE
1, 3, 5-TRTM5THYLBENZ5NE
1,2, 4-TRIMSTHYL3EN2ENE
m. - U1CHLOROBE&ZENE
CHLOROMETHYLBENZEWE
p - DICHLOR03ENZENE
o •- DICHLOROBENZESE
Mapthalerte
1,2,4- TRTCKLGROBENZENE
HEXAC • ILOKO- 1 , 3 -BUTADI ENE
5.
5.
"1 ,
•S .
5,
5.
It.
10.
5.
5.
5.
5.
5.
5.
5.
5.
5.
4 .
5 ,
5,
110
210
960
930
000
040
090
030
020
060
030
030
OBO
010
160
130
080
340
110
080
3,
4.
4.
3.
4.
4,
4.
8.
4 .
a r
5.
4 ^
/^
£._ ^
/I ^
4 _
4,
4 .
4.
4,
979
80S
552
867
441
672
281
63 -S
716
041
124
307
105
017
849
922
668
622
326
14-3
22.
8.
21.
11.
7
15-
13.
6 .
20.
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14.
19,
19.
o ,
5.
8.
6.
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18.
-
y
2
6
2
3
a
g
1
1
9
4
2
8
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1
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3
d
52
57
57
49
57
58
50
51
57
44
59
51
•55
4b
57
52
55
56
59
55
0,
0.
a.
0.
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0.
0.
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0.
0.
0.
0.
0.
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
DO
00
00
00
00
00
f) = Out of Ranqe
0807005-M Wed Aug 27 13:57:47 2008
SPCC's out = 0 CCC's out =
-------
t)
2)
3)
<)
5)
0)
7)
8}
9)
10}
11}
12)
13)
1 4)
IS)
15}
17)
15)
19)
•20)
21)
22)
?3)
?41
25)
26)
2V)
26)
29)
30)
31)
3?)
33)
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35!
36>
37)
40)
41)
42)
43)
44)
4Ei
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Nfir'nc
IS-KEXAKE-d1i
ACETYLENE
PROPVLENC
DICHLOROUiF-'LUOROMETHANE
OHLCROMEYHANE
DiCHLORCTCrRAFLUOaOETHA.
VINYL CHLORIDE
1,3-BUTADl':Nn
BROMOM ETHANE
CHLGROETHANJ;
Ethanol
ACETGNITRILE
Data Re Name N3H-OG3.D
Operator RDL
Dole Acquired 6/27/200514:1'.
ACCi McBrad Fife N6104.M
S0«i»l3Na.-ne BLK
Instrument Hsrae MSD_*
Sample Multiplier 1
large! I
1 Kia COROFLUCiROt.! C 1 H ANE
ACHYUJNITRILE
METHYLEiNiT CHLORIDE
CARBON DlSlfl_rir>E
rRICH LDROTRI FLUORQeTHANE
TRANS-1.2-DSCHLOROLTS1YLEN
f,1-OlCHI,,QRQETHANE
METHYL TtiRT-BUTYL ETHER
METHYL ETHYL KFHTONE
Cl I10ROPRENE
CIS- 1 , 2-DICHLOROE1 H YL=WE
ETHYL fi:RT BUTYL ETHEft
1 ,2-OICHLOROETHA,NE
JS-T.+-DIFLUOROE3ENZENE
1 . 1 ,1 -TR ICHLOHOi-'Tt (ANE
BENZENE
C;AR3OK TETSACHLORIDE
Ttitr.AMYL METHYL ETHI;R
1,,2-DICHiOROPROPANE
ETH'tt. ACRY1.AT1E
BROMODICHLOHOME1HANE
UfciHYL METKACRYLA.f-
CtS-1 ,3-DICHLOROPROPEiNE
METHYL igosuTYL KETONL;
TRANS-1,3-n£CHLOROPROPf:N[J
1.1,2-TRlCHLOROETHftNE
IS-CHLQRQBEM2i!ME-tJ5
TOLUENE
01 SHOMOCKLOROMETAKNE
t.2-Oll?Rf><1OETHANE
N-OCIANE
TETRACHLOROETHYLENE
CHLOROBENZt.NE
ETI lYtBENZEhJE
SO)
51 )
52)
53) BROMDFORM
55) 1,1.2,2-rtTRflCHLOROETHAMI'.
55) o - XYLENS
57) 1^.5-TRIMtTHYLBENZENE
58) 1,2.1-TRLMCTHYLBENZENE
59) m - DICHLOROBENZENE
-30} CHLOROMETI IVlBENZEfJE
61} P-DICHLOROBEN.ZENE
62} 3 - DICHLOKOGENZENE
63} Na-jthafena
64} 1,2,4-TRICHLOROBEh'ZSME
65) I IEXACHLORO-1.S-BUTADIENE
iSponsa AmourA'pptw Mill ,'pp'jv
33277S
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
387MS
0
0
0
0
0
0
0
0
0
0
0
0
0
479345
0
0
D
0
0
0
0
0
0
0
0
0
0
0
0
0
0
G
G
D
D
First Rs
S=e£ne
/.SCO
O.OOO
0,000
O.DOO
D.DGO
0.000
0.000
D.OQG
D.ODO
0.000
0,000
O.OOC
0.000
0.000
0.000
o.ooO'
o.ooo
O.ODO
o.ooo
o.coo
o.coo
0.003
o.coo
o.ooo
o.ooo
o.ooo
0.000
O.COO
0,000
7. sea
o.ooo
o.ooo
U.QOO
o.oco
0.000
0.000
o.ooo
0.000
O.ODO
O.OOO
o.ooo
o.coo
0.000
7,500
0.000
o.ooo
0.000
0.000
o.oeo
o.oeo
Q.OGO
O.DGO
O.DGG
O.OOG
0.000
0.000
o.ooo
o.ooo
0.000
0.000
o.eoo
0.000
o.coo
o.coo
O.CC'S
IKttfew
HI A
0 009
0 019
0 005
0 003
0,003
0 005
0005
DOOi
oooi
rwA
0.07.2
0.020
0.003
o.oou
0.005
0.018
0.004
O.C07
0.005
o.oo/
C.COS
0.026
0.007
G.C07
O.OCS
Cf.rjrjj'
C'.OCi
O.OCi1
M'A
0-.OC5
oo to
G 004
0 013
0,010
0.021
0.007
0.004
0.012
0,007
0.016
O.C-07
c.oos
N.'A
0.023
G 005
0007
G.GG5
0,006
0.003
0.008
0.019
0,005
0,021
0.003
o.ooe
0.015
0.018
0.015
00!1
0.0":?,
0.015
N/A
O.D3O
0,017
?jae i or i
C:lM5DCHE*HCUSTftPTC20QSSIM_TOX.CRt
-------
Data Path : C:\msd chemVUDATA\
Data Fie : N8H-Q03.D
Signal(s): FID1A.CH
CURRENT R.F.
13417
TOTAL AREA COUNT
111139
TOTAL PPBC
8.28
Total ppbC must be less than 20.
-------
Psrta Fik Name
Date Acquired 8/27/2B08 11:19
Sai'rtpfft Hismc SNMOC
1)
2)
3)
1)
5}
0
7)
8)
9)
10)
11)
12)
13)
14)
16)
16)
17)
18)
1-9)
21)
22)
23)
24)
26)
26)
23)
29)
30)
31)
32)
33)
34)
36)
36)
3?)
5*}
3S)
40)
41)
•12}
43}
4*)
45}
46)
47)
48)
43)
50)
51)
52)
53)
54)
66)
57)
53)
59)
60)
61}
92)
63)
04!
65!
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69)
70)
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72}
73)
75)
77)
78)
79)
60}
BfRlp'
821
Name
ithylene
Ethane
Propane
Prapyns
Iscdutans
lsQbutene,J1-!lu
3-Me[hyl>1'FlulCnc
Isapentene
2-Mathyl-1-TVuloim
[ioprene
(ran s-2-Ps
cis-2-Pen;ene
Cyckjperrians
2,3-Dimemyltxjln/vi
3-MoUiyfsrenlane
2-MfiQlyf'-'
1 -Hexena
2-EthyM-Butene
clis-3-Huitcnc;
Benzen*
Gydohaxane
1.4-Oiflucrobenzen*
1-Heptane
2,2,4-Trimethyipsntanc
2,2.3-YriroclfTylpentane
2.3.1-Trira
Toluene
t-Octsne
Ethylbeiisstnft
Sfyrene
BFB
Isopr?
alpha-Pinens
re-Ethyttoiusne
p-Elhyttolue«>
1 -tecene
1,2,3-T;ii:i«lf
1-Undecene
n-Undscane
n-Dodecane
1-Tridecsne
Rc1 Tim^j
5.57
£.73
5.86
8.05
9.21
o.oc
10.60
11.6ii
11.99
1Z.17
12.61
13.16
0,00
15.11
18. M
15.01
16.19
15.37
15.53
16.84
o on
17.67
0 00
0.00
"8.86
T6.07
1S.17
1573
20.0*
20.04
20.18
0.00
20.54
O.CO
o.co
21 f1
21.88
Z2.1-*
23,17
23,35
23 61
23.fi 1
2389
24.32
24.49
24,$2
?5 53
000
27.10
27.30
27. n
26.03
0:00
24,07
30.3?
31.12
31 .*5
32.14
3? 35
a? 72
32.92
33.23
33. L6
0.00
34.5'1
34.88
34.9 1
35.15
35.S6
30.89
33.08
33.31
36.49
37.C&
37 93
33.16
0.00
S9.SS
ooo
41.41
O.DO
42 SO-
Target Response
285462
4947^54
323W4
39335*
541225
o.oo
341990
4U207
1581
547182
337310
481767
0.00
330145
330145
5270
344009
477633
333370
456113
0
5-15B70
0
0
270774
53.59
28-0733
6436SB
7670S4
767054
8.H4234
0
4S1042
0
0
34 -ays/
526874
3*8564
544709
653535
333835
63233-t
334SG3
2528
393S30
3-179*4
*OtS70
0
321647
48330*
320753
332590
0
383332
6385/4
313349
434681
4038&2
319473
1392
316705
566721
429501
0
360581
31635?
456261
305027.63
416528.
1762
47071 G
2454
351303
?9S014
435923
27H13S
0
334&S5
0-
427/02
0 C-ii
414409
R,F. 1.0CE*14
CalU must be 70-130
•>e. TsrsjelConc. Cal
p pbC %
22.31 20.00 111.54
25.6S 25.00 103.78
42.29 4Q.oa W5.7J
40,00 10S.W
25,00 107.53
31.3* SO.BD KH.46
30.36
24.35 25,00 83.SB
33.Se KO.OO 95,65
2».96 30.00 9S.86
24,49 2S.OD 97.9«
24 J$ 25.00 98.93
27.45 30.DO 91.51
26.18 30.05 E7.2S
-------
Directory: g:\MASS SPEC 4 DATA\N8H#
Injection Log
Line Vial FileName Multiplier SampleName
1
2
3
4
5
6
7
11
12
13
14
15
16
17
18
19
20
21
22
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
N8h#00l.d
N8h#002.d
N8h#OQ3,d
N8h#OQ4.d
N8h#Q05,d
N8h#006.d
N8h#007,d
N8rt#008.d
N8h#Q09.d
NSh#010,d
N8ti#OH.d
N8h#Q12.d
N8h#013.d
N8h#014,d
N8hrf»1S.d
N8h#017.d
N8h#018.d
N8h#019.d
N8h#020,d
N8h#021.d
N8h#022.d
1.
1.
1.
8.
8,
8.
8,
8,
8,
8,
8.
8,
0.
8,
8.
8.
8.
8,
8.
1,
SNMOC
5
BLK
8082101-18
8082101-18
8082101-19
8082101-19
8082101-20
8082101-21
8082101-22
8082101-22
8082101-23
8082101-23
8082101-24
8082101-24
8082101-25
8082101-25
8082101-26
8082101-27
8062101-27
8082101-28
8082101-28
Misc Info
QC
QC
QC
167601 ArcadisCI
167601 Areadis R1
3254 Arcadis C2
3254 Arcadis R2
ER061 Arcadis
15280 Arcadis Upwind
ER064 Arcadis C1
ERO&4 Arcadis R1
Arcadis C2
Arcadis R2
988 Arcadis C1
988 Arcadis R1
3248 Arcadis C2
3248 Arcadis R2
ER021 Arcadis Upwind
ER114 ArcadisCI
ER114 Arcadis R1
Arcadis C2
ER085 Arcadis R2
injected
29 Aug
29 Aug
2S Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
29 Aug
30 Aug
30 Aug
30 Aug
30 Aug
30 Aug
200808:14
09:24
10:35
11:37
12:40
13:42
14:45
15:47
16:50
17^52
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
2008
18:55
19:57
21:00
22:03
23:05
00:08
01:10
02:13
03:16
04:18
30 Aug 05:21
30 Aug
Page 1
01 Sep Oi:33
-------
Evaluate Continuing Calibration Report
Data Path
Data File
Acq On
Operator
Sample
Wise
ALS Vial
C:\msdchem\l\DATA\
N8HttQ02,D
29 Aug 2008 9:24 am
RDL
5.00
QC {Sig #1); (Sig If 2}
2 Sample Multiplier:
Quant Time Aug 29 10:20:19 2008
Ouant Method : C:\MSDCHEK\1\METHODS\N8104.M
Quant Title ; TO-15 by Selective Ion Analysis
QLast Update : Wed Aug 06 09:23:31 2008
Response via : Initial Calibration
Kin. ERF
Max. RRF Dev
0.000 Min. Rel.
301 Max. Rel.
Area : II Max,
Area : 5001
Compound
Amount
Calc.
R.T. Dev Q.SOmln
%Dev Area! Dev(man)
1 IS
2
3
4
5
6
7
8
B
1 0
11
12
13
14
15
16
17
18
15
20
21
22
23
24
25
26
27
23
29
30 IS
31
32
33
34
35
36
37
36
39
40
41
42
43
44 IS
I5-HEXANE-dl4
ACETYLENE
PROPYLENE
DICHLORODIFUJOROMETHANE
CHLOROMETHANE
DICHLQROTETRAFLUOROETHA
VINYL CHLORIDE
1, 3 -BUTADIENE
BROMOM ETHANE
CHLORO ETHANE
Ethanol
ACETQNITRILE
Aero 11 en
TRICHLOROFLUOROMETHANE
ACRYLONITR1LE
1, 1-DICHLOROETHENE
METHYLENE CHLORIDE
CARBON DI SOL FIDE
T R I C H LO ROT R I FLUO RO ET H AN E
TRAMS- 1, 2-DICHLOROETHYLEN
1, 1-DICHLORQETHANE
METHYL TERT- BUTYL ETHER
METHYL ETHYL KETQtIE
CHLORO PRENE
CIS-1, 2-DICHI.OROETHYLENE
BROMOCHLOROMETHANE
CHLOROFORM
ETHYL TERT BUTYL ETHER
1 , 2 -DICHLORO ETHANE
I S- 1 , 4 -DI FLUOROBEN ZENE
1,1, 1-TRICHLOROETHANE
BENZENE
CARBON TETRACHLQRIOE
TERT-AMYL METHYL ETHER
1 , 2 - DI CHLORO PROPANE
ETHYL ACRYLATE
B, RO MO D I C H LO ROM E THAN E
T H I CHLO ROE T H Y LE N E
METHYL METHAC P.YLATE
CIS-1 , 3-DICHLOROPROPENE
METHYL ISOBUTYL KETOHE
TRAHS-1 , 3-D1CKLOROPROPEME
1,1, 2-TRlCHLORQETHANE
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45
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1,2-DIBROMOETHANE
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-------
Data Fife Name NBHBOttl D
Operator RDL
Dale fejuirud B/24/S008 10 35
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Sams** Name BLK
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C:\WSDCHEM\CU5TRPT\ZOOaSIM TOXCRT
-------
Data Path: C:\msdehern\1\DATA\
Data File : NSHSQD3.D
Signal(s) :FID1A.CH
CURRENT R.F.
13417
TOTAL AREA COUNT
64284
TOTAL PPBC
4.79
Total ppbC must be less than 20.
-------
Data Fll® Name
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#tlSNMOC_QC-04,CRT
-------
Directory: g:\MASS SPEC 4 D ATAIN8IL
Injection Log
Line Vial Filename Multiplier SampieName
1
2
3
4
5
6
1
2
3
4
5
6
N8ilOQl,d
N8ii002,d
N8)IQQ3,d
N8ilQG4.d
NSilGGS.d
N8ilGQ6,ct
1.
1.
1,
142.8
87,6
104-4
SNMOC
5
BLK
8082101-04
8082101-07
8082101-05
Misc Info
QC
QC
QC
Arcadis Dilution
Arcadis Dilution
Arcadis Dilution
Injected
12Sep2008Q8'1l'
12Sep20080lJ *9
12Sep2008 10 28
12 Sop 2008 1*,38
12Sep200a 1247
12Sep2008 13-56
Page 1
15Sep2008 10:06
-------
fiat a i/ach
. ata File
A_-q On
Operacor
Sample
Misc
ALS Vial
Quant: Time
Evaluate Continuing Calibration Report.
C •; \iTisdchem\ 1 \DATA\
N8IL002.D
12 Sep 2008 S»: J9 am
RDL
5.00
QC {Sig 811; (Sig S2)
2 Sample Multiplier: 1
Sep 15 01 • f5 •
""One
Quant Method : C:\ssd-n.i.i 1 '*E14 LJUJ8104.M
Quant Title : TO- 15 Lv _tl.± t v.- Ton Analysis
QLast Update ; Wed S« r j< K j. siu 2008
Response via : Initial ^djibia'iur
Mm, RP.F : 0.000 Mm. Rcl. Area : 11 Max. R.T, Dev O.SOmin
Max. RRF Dev : 30% Max. Rel . Area : 500%
Compound Amount tale. %Dev Area! Dev
1 IS
™>
3
•1
5
6
7
8
P
] 0
1 1
12
1 3
11
13
I. €»
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18
19
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21
22
2 3
24
23
26
27
28
29
30 IS
31
32
33
34
35
36
3?
38
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4 I
•12
13
IS-HEXAN£-dl4
ACETYLENE
PROPYLENE
DICHLORQDIFLUGROMETHANE
CHLOROMETHANE
D I CHLQROTETRAFLUOROF-TH A
VINYL CHLORIDE
I, 3- BUTADIENE
BROMOMETHANE-
CH LORD ETHANE
Ethanol
ACETONITRILE
Acrolien
TFICHLOROFLUQROMETHANE
ACRYLONITRILE
lt 1-DlCHLQRGETHEHE
MfclTHYLENE CHLORIDE
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-------
45
46
47
48
49
50
51
52
53
54
55
56
57
5B
59
60
61
62
63
64
65
TOLUENE
DIBRQMQCHLQROMETAHNE
1 , 2 - D I B ROMO E T t IAN E
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p - DICHLOROBENZENE
0 - DICHLORQBENZENE
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5
5
4
4
5
5
5
10
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0807005.H Won Sep 15 09:02:42 2006
SPCC's out = 0 CCC's out = 0
-------
Oaia Fife Mams NBILOQ3.B
Operator RDL
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C:',MSDCHEM',C«STRPT\20SSSIM IOK.CKT
-------
Data Path : C:\msdchem\1\DATA\
Dats File; N8IL003.D
: FID1A.CH
CURRENT R.F.
12797
TOTAL AREA COUNT
39664
TOTAL PPBC
3,10
Total ppbC must be than .20,
-------
Data FHe Name
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Sample Name SNMOC
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-------
Appendix C
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
Appendix C: EPA R8 Water Analysis
C-1
-------
Appendix C
Measurement of Emissions
from Produced Water Ponds
October 2009 (Rev. 0.6)
This page intentionally left blank.
C-2
-------
U.S. Environmental Protection Agency
Region 8
Technical and Management Services
Ref: 8TMS-L
MEMORANDUM
SUBJECT: Analytical Results—
FROM:
Garfield County CBM / R8080111
Vicente Marti, Organic and Inorganic Chemist
Steven Callio, Laboratory Quality Assurance Officer
THRU: Tony Medrano, Acting Director
Laboratory Services Program
JQ. Michael Copeland, 1595 Wynkoop Street
Air Enforcement Program
Attached are the analytical results for Garfield County CBM R8080111. The table below
shows the number of containers received , the work order number(s) assigned, and the date
12-Aug-2008
8808007
15
Total
15
These samples were prepared, analyzed, and verified by the Technical and Management Services
Laboratory according to the requirements of the Laboratory Services Request (LSR) and procedures
found in the laboratory Quality Management Plan dated March 31, 2003.
Note: The laboratory herewith transmits this deliverable to the program/project partner for
determination of "final data usability" to include data validation and data quality asessment per and in
accordance with EPA QA/G-8, Guidance on Environmental Data Verification and Data Validation,
November 2002, EPA/240/R-02/004.
Page 1 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111 Certificate of Analysis
Case Comments
Narrative Garfield County Samples
LSRR8080111
Analyst: Vicente C. Marti
Samples Received:
Two sets of fifteen water samples each were received. The first set on August 12, 2008 and the second set on August
15, 2008. Samples were to be analyzed for volatile organics by SW-846 method 8260. The samples were received iced
at2±2 C.
Extraction and Analysis:
Samples were prepared and extracted according to SW-846 method 8260 for water samples. Five ml of the samples
were analyzed by method 8260, "Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry (capillary
column technique)," from Test Methods for Evaluating Solid Waste, SW-846. The method was calibrated from 2.50
Hg/L to 100 ng/L. Samples were analyzed well within the 7 days holding time.
Analyst Notes:
The GC/MS system maintained a passing tune during the entire analysis. Continuing calibration standards (CCV)
were determined at the beginning, during and end of the test, with greater than 90% of all 66 compounds within the
QC limits.
Due to the high content of hydrocarbons, samples had to be diluted prior to analysis of the BTEX compounds. Since
only two dilutions could be made (only two vials per station were received), some of the compounds that exceeded the
calibration range will be J qualified. Surrogates recoveries were within limits for most samples. Hydrocarbons
(alkanes) from C4 to C13 and with branches were observed in all samples and at high concentrations. No laboratory
duplicate, matrix spike and matrix spike duplicates were supplied. The compound 1,2,3-trichloropropane had high
recovery on the Laboratory Control Sample. This compound was not found in any of the samples. The compound
acetone was a TIC (tentatively identified compound) on samples from stations S-l, E-l, W-2, S-2, Grass-3, W-3 dup,
W-3 Low, and W-4 High/
Due to multiple instances of detection in blank samples the compounds benzene, toluene, ethylbenzene, m/p xylenes,
o-xylene, 1,2,4-trimethylbenzene and napthalene have been j-qualified as estimated values (did not effect samples
8808007-05, 8808007-06, 8808007-10, 8808007-11, 8808007-12, and 8808007-13 from the 8/12/08 sample set).
Values for analytes with low Q-values were not reported for some samples due to questionable identification. The
values for these analytes were considered "non-detect".
For samples 8808009-10 from the 8/15/08 sample set (1,2-dichloroethane, 1,2-dichloropropane, 2-chlorotoluene, and
tert-butylbenzene) and sample 8808009-06 of the same sample set (2-chlorotoluene), some analytes were detected in
sample dilution analysis however, due to lack of detection in non-diluted samples and the low detection values
obtained from the dilutions, these analytes were considered "non-detect".
For the QC samples associated with the 8/12/08 sample set, the CCV2 sample had low recovery for bromomethane and
2,2-dichloropropane (effected samples were j-qualified as estimated) and high recovery for chlorobenzene-d5 in CCV1
(did not effect data as this analyte was not detected in any of the samples).
For the QC samples associated with the 8/15/08 sample set, the CCV2 and CCV3 samples had low recovery for
bromomethane and 2,2-dichloropropane and the CCV1 sample had low recovery for dichlorodifluoromethane,
chloromethane, and trichlorofluoromethane. All effected data was j-qualified as estimated for these analytes. In
addition, there was high recovery for 1,2,3-trichlropropane in the SRM2 sample, dichlorodifluoromethane in the blank
spike, and low recovery in CCV3 for bromoform. However, this did not effect any of the reported data so no
qualifications were necessary.
Page 2 of 30 Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B
Station ID: SP-IN-1 Date / Time Sampled:
EPA Tag No.: GF080408-9 Matrix: Water
3/07/08 13:34
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-03 A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
5.57
<2.50
<2.50
<2.50
<2.50
<2.50
19000
46.2
<2.50
<2.50
53.2
<2.50
<2.50
50000
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
1170
<2.50
40400
5810
<2.50
<2.50
71.4
92.5
<2.50
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Qual- Report
ifier Limit
J 2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
J 2500
2
2
2
2
2
2
.50
.50
.50
.50
.50
.50
J 2500
2
2
2
2
2
2
2
.50
.50
.50
.50
.50
.50
.50
J 250
2
.50
J 2500
J 2500
2
2
2
2
2
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1000
1
1
1
1
1
1
1000
1
1
1
1
1
1
1
100
1
1000
1000
1
1
1
1
1
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 3 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B 1,1,2,2-Tetrachloroethane 9.38
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenz ene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2,4-Trimethylbenz ene
sec-Butylbenzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
SP-OUT-1
: GF080408-2
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1,2-Dichloroethane
77.9
<2.50
<2.50
<2.50
2.70
1550
15.2
28.1
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
197
<2.50
74.5%
94.5%
106%
102%
Date / Time Sampled:
Matrix: Water
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
15000
67.5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
08/07/08 13:45
Qual-
Units ifler
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
2.50
2.50
2.50
2.50
2.50
2.50
250
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
250
2.50
1
1
1
1
1
1
100
1
1
1
1
1
1
1
1
1
100
1
1
1
1
1
Certificate of Analysis
08/12/2008 VCM 0800245
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Workorder 8808007
Lab Number: 8808007-04 A
Report
Limit
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
500
2.50
Page 4 of 30
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
200
1
Analyzed
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Trichloroethene
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
46.4
4.98
<2.50
33400
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
1440
<2.50
24100
3420
<2.50
<2.50
70.9
94.9
<2.50
<2.50
81.2
<2.50
<2.50
<2.50
2.61
2700
16.2
57.4
<2.50
<2.50
31.1
<2.50
<2.50
<2.50
<2.50
276
<2.50
95.6%
99.4%
108%
88.0%
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
1000
2.50
2.50
2.50
2.50
2.50
2.50
2.50
500
2.50
1000
500
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
500
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
500
2.50
1
1
1
1
1
400
1
1
1
1
1
1
1
200
1
400
200
1
1
1
1
1
1
1
1
1
1
1
200
1
1
1
1
1
1
1
1
1
200
1
1
1
1
1
Certificate of Analysis
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
Page 5 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: N-OUT-1
EPA Tag No.: GF080408-1
Date / Time Sampled:
Matrix: Water
08/07/08 13:54
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-05 A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropyl benzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
Qual- Report
Units ifler Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 6 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenzene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1 ,2,4- Trimethy Ibenzene
sec-Butyl benzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromqfluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
S-OUT-1
: GF080408-5
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
95.3%
100%
101%
102%
Date / Time Sampled:
Matrix: Water
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
08/07/08 14:04
Qual-
Units ifler
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
08/13/2008
08/13/2008
08/13/2008
08/13/2008
Workorder
Lab Number:
Report
Limit
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
8808007
8808007-06 A
Analyzed
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 7 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Trichloroethene
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
92.2%
97.8%
101%
105%
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
Page 8 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: SP-IN-2
EPA Tag No.: GF080408-4
Date / Time Sampled:
Matrix: Water
08/08/0811:02
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-07 A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
16200
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
29400
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
1100
<2.50
16300
2640
<2.50
<2.50
77.2
95.9
<2.50
<2.50
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Qual- Report
ifler Limit
J 2
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
J 1000
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
J 1000
2
2
2
2,
2,
2,
2
.50
.50
.50
.50
.50
.50
.50
J 1000
2,
.50
J 1000
J 1000
2
2
2,
2,
2
2
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
400
1
1
1
1
1
1
400
1
1
1
1
1
1
1
400
1
400
400
1
1
1
1
1
1
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 9 of30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenz ene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2,4-Trimethylbenz ene
sec-Butylbenzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
SP-OUT-2
: GF080408-10
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
82.7
<2.50
<2.50
<2.50
3.10
1820
16.1
63.0
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
158
<2.50
96.4%
99.8%
105%
87.2%
Date / Time Sampled:
Matrix: Water
Results
<2.50
10.1
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
7470
<2.50
<2.50
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
08/08/0811:04
Qual-
Units ifler
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L
2,
2
2
2,
2,
.50
.50
.50
.50
.50
1000
2
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1
1
1
1
1
400
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Workorder 8808007
Lab Number: 8808007-08 A
Report
Limit
2,
2,
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1000
2,
2
.50
.50
Page 10 of 30
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
400
1
1
Analyzed
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
08/12/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
16200
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
568
<2.50
8850
1460
<2.50
<2.50
67.3
89.8
<2.50
<2.50
76.2
<2.50
<2.50
<2.50
2.24
1190
11.8
60.7
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
183
<2.50
81.0%
84.8%
106%
106%
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
1000
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1000
2.50
1000
1000
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1000
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
400
1
1
1
1
1
1
1
400
1
400
400
1
1
1
1
1
1
1
1
1
1
1
400
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
08/12/2008 VCM 0800245
Page 11 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: SP-OUT-2 DUP
EPA Tag No.: GF080408-11
Date / Time Sampled:
Matrix: Water
08/08/0811:04
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-09 A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
10700
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
21900
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
684
<2.50
11000
1760
<2.50
<2.50
60.0
73.2
<2.50
<2.50
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Qual- Report
ifler Limit
J 2
2,
2,
J 2
2
2
2,
2,
2,
2
2
J 2
2,
2,
2,
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
J 1000
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
J 1000
2
2
2
2,
2,
2,
2
.50
.50
.50
.50
.50
.50
.50
J 1000
2,
.50
J 1000
J 1000
2
2
2,
2,
2
2
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
400
1
1
1
1
1
1
400
1
1
1
1
1
1
1
400
1
400
400
1
1
1
1
1
1
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 12 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenz ene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2,4-Trimethylbenz ene
sec-Butylbenzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
N-OUT-2
: GF080408-3
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
67.3
<2.50
<2.50
<2.50
101
1220
11.6
21.9
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
167
<2.50
80.2%
85.3%
106%
105%,
Date / Time Sampled:
Matrix: Water
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
08/08/0811:12
Qual-
Units ifler
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2
2
2,
2,
.50
.50
.50
.50
.50
1000
2
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1
1
1
1
1
400
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
08/13/2008
08/13/2008
08/13/2008
08/13/2008
Workorder
Lab Number:
Report
Limit
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
8808007
8808007-10 A
Analyzed
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 13 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Trichloroethene
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
92.7%
97.8%
101%
104%
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
Page 14 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: N-OUT-2 LOW
EPA Tag No.: GF080408-7
Date / Time Sampled:
Matrix: Water
08/08/0811:12
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-11 A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropyl benzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
Qual- Report
Units ifler Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 15 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenzene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1 ,2,4- Trimethy Ibenzene
sec-Butyl benzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromqfluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
N-OUT-2 HIGH
: GF080408-13
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
90.
95.
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
5%
6%
101%
104%
Date / Time Sampled:
Matrix: Water
Results
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Lzmrt 70-7.30
Limit 70-130
Limit 70-130
Limit 70-130
08/08/0811:12
Qual-
Units ifler
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
08/13/2008
08/13/2008
08/13/2008
08/13/2008
Workorder
Lab Number:
Report
Limit
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
8808007
8808007-12 A
Analyzed
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 16 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Trichloroethene
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
90.7%
96.9%
101%
103%
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
Page 17 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: S-OUT-2
EPA Tag No.: GF080408-12
Date / Time Sampled:
Matrix: Water
08/08/0811:19
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-13A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1 ,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropyl benzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
Qual- Report
Units ifler Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
1 08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 18 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
Surrogate:
Surrogate:
Surrogate:
Surrogate:
Station ID:
EPA Tag No.
Method
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA 8260B
1,3,5-Trimethylbenzene
2-Chlorotoluene
1 ,2,3- Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1 ,2,4- Trimethy Ibenzene
sec-Butyl benzene
p-Isopropyltoluene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
n-Butyl Benzene
1 ,2-Dichlorobenzene
1 ,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1 ,2,4- Trichlorobenzene
Naphthalene
1 ,2,3- Trichlorobenzene
Dibromqfluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
SP-OUT-3
: GF080408-6
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1,2-Dichloroethane
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
88.
95.
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
7%
6%
101%
106%
Date / Time Sampled:
Matrix: Water
Results
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
11300
75.9
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Lzmrt 70-130
Limit 70-130
Limit 70-130
Limit 70-130
08/08/0811:35
Qual-
Units ifler
ug/L J
ug/L
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
08/13/2008
08/13/2008
08/13/2008
08/13/2008
Workorder
Lab Number:
Report
Limit
2,
2,
2
2
2
2,
2,
2,
2
2
2
2,
2,
2,
2
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
1250
2,
.50
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
500
1
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
8808007
8808007-14 A
Analyzed
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 19 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B Trichloroethene
EPA 8260B Dibromomethane
EPA 8260B 1,2-Dichloropropane
EPA 8260B Bromodichloromethane
EPA8260B cis-l,3-Dichloropropene
EPA 8260B Toluene
EPA 8260B trans-1,3-Dichloropropene
EPA 8260B Tetrachloroethene
EPA 8260B 1,1,2- Trichloroethane
EPA 8260B Chlorodibromomethane
EPA 8260B 1,3-Dichloropropane
EPA 8260B 1,2-Dibromoethane (EDB)
EPA 8260B Chlorobenzene
EPA 8260B Ethylbenzene
EPA 8260B 1,1,1,2- Tetrachloroethane
EPA 8260B m,p-Xylene
EPA 8260B o-Xylene
EPA 8260B Styrene
EPA 8260B Bromoform
EPA 8260B Isopropylbenzene
EPA 8260B n-Propyl Benzene
EPA 8260B Bromobenzene
EPA 8260B 1,1,2,2- Tetrachloroethane
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
23600
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
750
<2.50
11900
1850
<2.50
<2.50
69.3
78.4
<2.50
<2.50
72.7
<2.50
<2.50
<2.50
111
1340
1.29
24.6
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
178
<2.50
81.9%
84.0%
105%
101%
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
1250
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1250
2.50
1250
1250
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1250
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
1
500
1
1
1
1
1
1
1
500
1
500
500
1
1
1
1
1
1
1
1
1
1
1
500
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
Page 20 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Station ID: SP-OUT-4
EPA Tag No.: GF080408-8
Date / Time Sampled:
Matrix: Water
08/08/0811:51
Certificate of Analysis
Workorder 8808007
Lab Number: 8808007-15A
Method
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
Parameter
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans- 1 ,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1,1- Trichloroethane
1 , 1 -Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans- 1 ,3-Dichloropropene
Tetrachloroethene
1 , 1 ,2- Trichloroethane
Chlorodibromomethane
1 ,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1 , 1 , 1 ,2- Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1 , 1 ,2,2- Tetrachloroethane
Results
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
12000
75.8
<2.50
<2.50
<2.50
<2.50
<2.50
27400
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
1050
<2.50
16100
2460
<2.50
<2.50
76.2
94.7
<2.50
<2.50
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Qual- Report
ifler Limit
J 2
2,
2,
J 2
2
2
2,
2,
2,
2
2
J 2
2,
2,
2,
2
2
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
J 1250
2,
2
2
2
2,
2,
.50
.50
.50
.50
.50
.50
J 1250
2
2
2,
2,
2,
2
2
.50
.50
.50
.50
.50
.50
.50
J 1250
2,
.50
J 1250
J 1250
2
2,
2,
2
2
2,
.50
.50
.50
.50
.50
.50
Dilution
Factor Analyzed
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
500
1
1
1
1
1
1
500
1
1
1
1
1
1
1
500
1
500
500
1
1
1
1
1
1
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
08/13
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
/2008
By
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
VCM
Batch
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
0800245
Page 21 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
EPA 8260B 1,3,5-Trimethylbenzene
EPA 8260B 2-Chlorotoluene
EPA 8260B 1,2,3-Trichloropropane
EPA 8260B 4-Chlorotoluene
EPA 8260B tert-Butylbenzene
EPA 8260B 1,2,4-Trimethylbenzene
EPA 8260B sec-Butylbenzene
EPA 8260B p-Isopropyltoluene
EPA 8260B 1,3-Dichlorobenzene
EPA 8260B 1,4-Dichlorobenzene
EPA 8260B n-Butyl Benzene
EPA 8260B 1,2-Dichlorobenzene
EPA 8260B l,2-Dibromo-3-chloropropane
EPA 8260B Hexachlorobutadiene
EPA 8260B 1,2,4-Trichlorobenzene
EPA 8260B Naphthalene
EPA 8260B 1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
82.5
<2.50
<2.50
<2.50
111
1940
16.0
28.4
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
170
<2.50
80.6%
87.1%
105%
102%
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L J
ug/L J
ug/L J
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L J
ug/L
Limit 70-130
Limit 70-130
Limit 70-130
Limit 70-130
2.50
2.50
2.50
2.50
2.50
1250
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
1
1
1
1
1
500
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Certificate of Analysis
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
08/13/2008 VCM 0800245
(Note: "J" Qualifier indicates an estimated value.
Page 22 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source %REC RPD
Units Level Result %REC Limits RPD Limit
Batch 0800245 - Default Prep VOC
Method Blank (0800245-BLK1)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dichloroethene
Methylene chloride
trans- 1,2-Dichloroethene
1, 1-Dichloroethane
cis- 1,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1, 1-Trichloroethane
1, 1-Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1,2-Dichloropropane
Bromodichloromethane
cis- 1,3-Dichloropropene
Toluene
trans- 1,3-Dichloropropene
Tetrachloroethene
1, 1,2-Trichloroethane
Chlorodibromomethane
1,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1,1, 1,2-Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1, 1,2,2-Tetrachloroethane
1,3,5-Trimethylbenzene
2-Chlorotoluene
1,2,3-Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
n-Butyl Benzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed: 08/12/08
ug/L 70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Page 23 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source
Units Level Result
%REC
%REC RPD
Limits RPD Limit
Batch 0800245 - Default Prep VOC
Method Blank (0800245-BLK1)
1,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1,2,4-Trichlorobenzene
Naphthalene
1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobemene
Method Blank Spike (0800245-BS1)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dichloroethene
Methylene chloride
trans- 1,2-Dichloroethene
1, 1-Dichloroethane
cis- 1,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1, 1-Trichloroethane
1, 1-Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1,2-Dichloropropane
Bromodichloromethane
cis- 1,3-Dichloropropene
Toluene
trans- 1,3-Dichloropropene
Tetrachloroethene
1, 1,2-Trichloroethane
Chlorodibromomethane
1,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1,1, 1,2-Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
20.7
20. 8
19.7
20.8
48.1
49.9
50.4
50.0
51.0
51.2
50.9
50.7
51.6
50.5
52.3
49.4
50.9
49.8
51.1
50.9
54.4
51.2
49.5
54.2
50.8
51.8
51.4
54.0
51.7
52.7
52.1
50.3
52.2
51.0
51.8
50.7
52.3
50.9
104
52.9
52.7
53.9
53.6
52.2
51.5
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed
ug/L
"
"
"
"
"
20.0
20.0
20.0
20.0
Prepared & Analyzed
ug/L 50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
100
50.0
50.0
50.0
50.0
50.0
50.0
08/12/08
104
104
98.6
104
08/12/08
96.2
99.9
101
100
102
102
102
101
103
101
105
98.8
102
99.5
102
102
109
102
99.0
108
102
104
103
108
103
105
104
101
104
102
104
101
105
102
104
106
105
108
107
104
103
70-130
70-130
70-130
70-130
70-130
70-130
70-750
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Page 24 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source
Units Level Result
%REC
%REC RPD
Limits RPD Limit
Batch 0800245 - Default Prep VOC
Method Blank Spike (0800245-BS1)
1, 1,2,2-Tetrachloroethane
1,3,5-Trimethylbenzene
2-Chlorotoluene
1,2,3-Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
n-Butyl Benzene
1,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1,2,4-Trichlorobenzene
Naphthalene
1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
Reference (0800245-SRM1)
Vinyl chloride
1, 1-Dichloroethene
trans- 1 ,2-Dichloroethene
cis-l,2-Dichloroethene
1,1, 1-Trichloroethane
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Toluene
Tetrachloroethene
1, 1,2-Trichloroethane
Chlorobenzene
Ethylbenzene
m,p-Xylene
o-Xylene
Styrene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
1,2,4-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
49.4
53.9
51.7
50.7
52.2
53.5
51.6
53.3
53.0
50.9
50.8
52.0
51.2
53.3
52.4
50.9
49.7
50.6
19.6
19.4
19.9
19.9
8.05
14.0
11.0
11.6
7.14
5.04
7.37
13.0
12.6
16.0
6.43
18.7
22.2
3.41
18.3
3.47
16.9
16.3
11.7
9.32
19.3
19.4
19.7
21.4
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed
ug/L 50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
20.0
20.0
20.0
Prepared & Analyzed
ug/L 8.70
13.4
11.0
12.0
7.25
5.35
7.91
13.2
12.7
16.3
6.72
18.9
22.1
3.51
19.0
3.00
17.9
14.9
11.3
8.90
20.0
20.0
20.0
20.0
08/12/08
98.8
108
103
101
104
107
103
107
106
102
102
104
102
107
105
102
99.4
101
98.2
96.8
99.6
99.6
08/12/08
92.5
105
99.8
96.4
98.5
94.2
93.2
98.6
99.4
98.2
95.7
99.0
101
97.2
96.5
116
94.3
109
104
105
96. 6
97.1
98.7
107
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-750
70-750
70-750
70-750
Page 25 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source
Units Level Result
%REC
%REC RPD
Limits RPD Limit
Batch 0800245 - Default Prep VOC
Reference (0800245-SRM2)
Dichlorodifluoromethane
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dichloroethane
2,2-Dichloropropane
Bromochloromethane
1, 1-Dichloropropene
Dibromomethane
cis- 1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,3-Dichloropropane
1,1, 1,2-Tetrachloroethane
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1, 1,2,2-Tetrachloroethane
1,3,5-Trimethylbenzene
2-Chlorotoluene
1,2,3-Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
1,3-Dichlorobenzene
Hexachlorobutadiene
Naphthalene
1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
42.4
<2.50
45.7
15.8
15.9
48.1
9.83
10.2
33.6
33.6
<2.50
10.5
17.9
15.6
18.2
8.13
16.6
23.4
57.2
<2.50
28.9
5.20
<2.50
20.2
20.2
20.2
79.5
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed
ug/L 0.00
0.00
0.00
0.00
0.00
0.00
38.5
0.00
42.2
15.3
16.1
45.8
9.11
9.91
31.1
31.0
0.00
0.00
18.5
9.73
16.8
7.64
15.6
21.8
49.3
0.00
27.6
5.78
0.00
20.0
20.0
20.0
20.0
08/12/08
110
108
103
98.6
105
108
103
108
108
96.5
160
108
106
107
107
116
105
90.0
101
101
101
97.6
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Page 26 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source %REC RPD
Units Level Result %REC Limits RPD Limit
Batch 0800245 - Default Prep VOC
Reference (0800245-SRM3)
Chloroform
Bromodichloromethane
Bromoform
Surrogate: Dibromofluoromethane
Surrogate: l,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
HOLDING BLANK (8808007-01)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dichloroethene
Methylene chloride
trans- 1,2-Dichloroethene
1, 1-Dichloroethane
cis- 1,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1, 1-Trichloroethane
1, 1-Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1,2-Dichloropropane
Bromodichloromethane
cis- 1,3-Dichloropropene
Toluene
trans- 1,3-Dichloropropene
Tetrachloroethene
1, 1,2-Trichloroethane
Chlorodibromomethane
1,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
Ethylbenzene
1,1, 1,2-Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1, 1,2,2-Tetrachloroethane
1,3,5-Trimethylbenzene
2-Chlorotoluene
41.2
21.0
39.2
20. 4
20.2
19.7
21.1
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed: 08/12/08
ug/L 40.4 102 70-130
21.8 96.2 70-130
40.7 96.3 70-130
20.0 702 70-130
20.0 101 70-130
20.0 98.5 70-130
20.0 106 70-130
Prepared & Analyzed: 08/12/08
ug/L 70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Page 27 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source %REC RPD
Units Level Result %REC Limits RPD Limit
Batch 0800245 - Default Prep VOC
HOLDING BLANK (8808007-01)
1,2,3-Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
n-Butyl Benzene
1,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1,2,4-Trichlorobenzene
Naphthalene
1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
Trip Blank (8808007-02)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dichloroethene
Methylene chloride
trans- 1,2-Dichloroethene
1, 1-Dichloroethane
cis- 1,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
Carbon tetrachloride
1,1, 1-Trichloroethane
1, 1-Dichloropropene
Benzene
1,2-Dichloroethane
Trichloroethene
Dibromomethane
1,2-Dichloropropane
Bromodichloromethane
cis- 1,3-Dichloropropene
Toluene
trans- 1,3-Dichloropropene
Tetrachloroethene
1, 1,2-Trichloroethane
Chlorodibromomethane
1,3-Dichloropropane
1,2-Dibromoethane (EDB)
Chlorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
20.7
27.2
19.8
20.7
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed: 08/12/08
ug/L 70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
20.0 104 70-130
20.0 106 70-130
20.0 98.8 70-130
20.0 103 70-130
Prepared & Analyzed: 08/12/08
ug/L 70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Page 28 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Volatile Organic Compounds by EPA Method 8260B - Quality Control
Certificate of Analysis
Analyte
Result
Reporting
Limit
Spike Source %REC RPD
Units Level Result %REC Limits RPD Limit
Batch 0800245 - Default Prep VOC
Trip Blank (8808007-02)
Ethylbenzene
1,1, 1,2-Tetrachloroethane
m,p-Xylene
o-Xylene
Styrene
Bromoform
Isopropylbenzene
n-Propyl Benzene
Bromobenzene
1, 1,2,2-Tetrachloroethane
1,3,5-Trimethylbenzene
2-Chlorotoluene
1,2,3-Trichloropropane
4-Chlorotoluene
tert-Butylbenzene
1,2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
n-Butyl Benzene
1,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
Hexachlorobutadiene
1,2,4-Trichlorobenzene
Naphthalene
1,2,3-Trichlorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1 ,2-Dichloroethane-d4
Surrogate: Toluene-d8
Surrogate: 4-Bromofluorobenzene
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
<2.50
20. 8
21.4
19.6
20.6
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
Prepared & Analyzed: 08/12/08
ug/L 70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
20.0 104 70-130
20.0 107 70-130
20.0 98.2 70-130
20.0 103 70-130
NOTE:
%REC is percent recovery, Result (less sample contribution) divided by the Spike Level
RPD is the Relative Percent Difference (difference between the Result and the Source Result) divided by their average
Page 29 of 30
Print Date : 06-Oct-2008
-------
Project: Garfield County CBM LSR No: R8080111
Certificate of Analysis
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Page 30 of 30
Print Date : 06-Oct-2008
-------
Report To: Air Enforcement Program
1595 Wynkoop Street
Denver, CO 80202
Client Contact:
(303) 312-6010
None
Mail Instructions:
Report Instructions:
8808007
Date Due: 09/26/2008
TAT: 45
FAX
EMAIL
I EOF
Invoice To: Air Enforcement Program
1595 Wynkoop Street
Denver, CO 80202
Invoice Contact:
(303) 312-6010
Date/Initials:
Date/Initials:
Date/Initials:
Proofing
Report
Sub Report
Invoice
Date/Initials:
Date/Initials:
Date/Initials:
Format Correct?
Report to: vs. C.O.C.
Attention: vs. C.O.C.
Phone: vs. C.O.C.
Project Name & Number, PO Number
Sample ID: vs. C.O.C.
Sample Type: vs. C.O.C.
Date/Time Sampled vs. C.O.C.
Date/Time Received vs. C.O.C.
Test Name vs. C.O.C. & Benchsheet
Hold times
Method vs. Benchsheet
Units vs. Benchsheet
Reporting Limit vs. Benchsheet
Date Analyzed
Results vs. Benchsheet
Qualifiers
Page 1 of 1
Print Date : 06-Oct-2008
------- |