United States EPA- 600 / R~ 00~ 100
Environmental Protection
Agency November 2000
v/EPA Research and
Development
PB2002-100136
LONG-TERM PERFORMANCE OF
EPA-CERTIFIED PHASE 2 WOODSTOVES,
KLAMATH FALLS AND PORTLAND,
OREGON: 1998-1999
Prepared for
Office of Air Quality Planning and Standards
Prepared by
National Risk Management
Research Laboratory
Research Triangle Park, NC 27711
REPRODUCED BY:
U.S. Department of Commerce
National Technical Information Service
Springfield, Virginia 22161
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NRMRL-RTP-195
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before comp
REPORT NO.
EPA-600/SR-00/100
. TITLE AND SUBTITLE
Long-term Performance of EPA-certified Phase 2
Woodstoves, Klamath Falls and Portland, Oregon:
1998/1999
5. REPORT DATE
November 2000
6. PERFORMING ORGANIZATION CODE
PB2002-100136
7. AUTHOR(S)
L. H. Fisher, J. E. Houck, and P. E. Tiegs (OMNI), and
J. McGaughey (Eastern Research)
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
OMNI Environmental Services, Inc., 5465 SW Wes-
tern Ave., Suite G, Beaverton, OR 97005
Eastern Research Group, 900 Perimeter Park,
Morrisville, NO 27560
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D7-0001, WA 2-04
(Eastern Research)
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air Pollution Prevention and Control Division
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; 1/98- 12/99
14. SPONSORING AGENCY CODE
EPA/600/13
IS.SUPPLEMENTARYNOTESAPPCD project officer R. C. McCrillis is no longer with the
Agency. For details', contact John Kinsey, Mail Drop 61, 919/541-4121.
is. ABSTRACT -j/he report gives results of an evaluation of the condition and air emissions
from old phase-2-certified wood heaters installed in homes and used regularly for
home heating since the 1992/1993 heating season or earlier. (NOTE: Wood stoves
have been identified as a major source of particulate and polycyclic organic matter
(POM) emissions. For this reason, new source performance standards (NSPS) were
promulgated for wood heaters. Wood heaters sold after July 1, 1992, had to be certi-
fied for low emissions, meet the most stringent requirements of the NSPS, and are
referred to as phase-2 certified. Of concern has been the fact that laboratory and
field studies have shown that certified wood heaters can physically degrade with use,
commensurately increasing their air emissions.) Sixteen stoves were evaluated in
the study, eight each in Klamath Falls and Portland, Oregon. An extensive data base
from 43 week-long test runs was developed. The particulate emission factors of the
certified phase 2 stoves evaluated in this study appear to have increased with use
but, on average, after about 7 years they still have lower emissions than uncertified
conventional stoves.. In addition, it was clear from the results that the emission
rates for phase 2 stove models reported as part of the NSPS certification process do
not represent emission levels of the same stove models in homes after extended use.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Pollution
Wood
Combustion
Emission
Particles
Polycyclic Compounds
Organic Compounds
Measurement
Pollution Control
Stationary Sources
Woodstoves
Particulate
Polycyclic Organic
Matter
13 B
11L
2 IB
14G
07C
18. DISTRIBUTION STATEMENT
Release to Public
EPA Form 222O-1 (9-73)
19. SECURITY CLASS (This Report)
Unclassified
21. NO. OF PAGES
2O. SECURITY CLASS (This page)
Unclassified
22. PRICE
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FOREWORD
The U. S. Environmental Protection Agency is charged by Congress with pro-
tecting the Nation's land, air, and water resources. Under a mandate of national
environmental laws, the Agency strives to formulate and implement actions lead-
ing to a compatible balance between human activities and the ability of natural
systems to support and nurture life. To meet this mandate, EPA's research
program is providing data and technical support for solving environmental pro-
blems today and building a science knowledge base necessary to manage our eco-
logical resources wisely, understand how pollutants affect our health, and pre-
vent or reduce environmental risks in the future.
The National Risk Management Research Laboratory is the Agency's center for
investigation of technological and management approaches for reducing risks
from threats to human health and the environment. The focus of the Laboratory's
research program is on methods for the prevention and control of pollution to air,
land, water, and subsurface resources; protection of water quality in public water
systems; remediation of contaminated sites and groundwater; and prevention and
control of indoor air pollution. The goal of this research effort is to catalyze
development and implementation of innovative, cost-effective environmental
technologies; develop scientific and engineering information needed by EPA to
support regulatory and policy decisions; and provide technical support and infor-
mation transfer to ensure effective implementation of environmental regulations
and strategies.
This publication has been produced as part of the Laboratory's strategic long-
term research plan. It is published and made available by EPA's Office of Re-
search and Development to assist the user community and to link researchers
with their clients.
E. Timothy Oppelt, Director
National Risk Management Research Laboratory
EPA REVIEW NOTICE
This report has been peer and administratively reviewed by the U.S. Environmental
Protection Agency, and approved for publication. Mention of trade names or
commercial products does not constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Information
Service, Springfield, Virginia 22161.
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EPA-600/R-00-100
November 2000
Long - Term Performance of EPA-Certified Phase 2 Woodstoves,
Klamath Falls and Portland, Oregon: 1998/1999
Prepared by:
Lawrence H. Fisher,
James E. Houck, and
Paul E. Tiegs
OMNI Environmental Services, Inc.
5465 SW Western Avenue, Suite G
Beaverton, OR 97005
and
James McGaughey
Eastern Research Group, Inc.
900 Perimeter Park
Morrisville, NC 27560
EPA Contract 68-D7-0001, WA 2-04
EPA Project Officer: Robert C. McCrillis
National Risk Management Research Laboratory
Research Triangle Park, NC 27711
Prepared for:
U.S. Environmental Protection Agency
Office of Research and Development
Washington, DC 20460
PROTECTED UNDER INTERNATIONAL COPYRIGHT
ALL RIGHTS RESERVED
NATIONAL TECHNICAL INFORMATION SERVICE
U.S. DEPARTMENT OF COMMERCE
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Disclaimer
The U.S. Environmental Protection Agency through its Office of Research and
Development funded and managed the research described here under Contract No. 68-D7-0001
to Eastern Research Group, Inc. It has been subjected to the Agency's peer and administrative
review and has been approved for publication as an EPA document. Mention of trade names or
commercial products does not constitute endorsement or recommendation for use.
11
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Executive Summary
Woodstoves have been identified as a major source of participate and polycyclic organic
matter (POM) emissions. For this reason, new source performance standards (NSPS) were
promulgated for wood heaters. Wood heaters sold after July 1, 1992, had to be certified for low
emissions, meet the most stringent requirements of the NSPS, and are referred to as Phase 2
certified. Of concern has been the fact that laboratory and field studies have shown that certified
wood heaters can physically degrade with use and their air emissions commensurately increase.
The objective of this study was to evaluate the condition and air emissions from old
phase 2 certified wood heaters installed in homes and used regularly for home heating since the
1992/1993 heating season or earlier. Study stoves were inspected and their conditions were
documented. Particulate and POM samples were collected from the stoves during normal in-
home use with an automated woodstove emission sampler (AWES). The AWES was developed
specifically for the in-home collection of air emission samples from residential wood burning
appliances and data developed from its use have previously been used to calculate particulate
emission factors published in AP-42. In addition to data obtained from the use of the AWES,
ancillary information such as the history of each woodstove, installation characteristics and
cordwood properties were compiled for the study.
Sixteen stoves were evaluated in the study, eight in Klamath Falls, Oregon, and eight in
Portland, Oregon. All 16 stoves showed the effects of use. However, only six were degraded to
the point that it was speculated that their condition would significantly affect air emissions.
An extensive data base from 43 week-long test runs was developed. No direct statistical
correlation between emissions and wood moisture, burn rate or the conditions of the stoves could
be made due to the number of variables associated with the real-world in-home use of
woodstoves. However, the particulate emissions for stoves in homes in Portland were on the
average higher than for stoves in homes in Klamath Falls. This result is consistent with the
average higher fuel moisture content and burn rate characteristic of the Portland portion of the
study as compared to the Klamath Falls portion.
The particulate emission factors of the certified Phase 2 stoves evaluated in this study
appear to have increased with use, but on the average, after about seven years they still have
lower emissions than uncertified conventional stoves. In addition, it was clear from the results
that the emission rates for Phase 2 stove models reported as part of the NSPS certification
process do not represent emission levels of same stove models inhomes after extended use.
iii
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The data demonstrate that particulate emissions can not be used as a surrogate
measurement for POM emissions of woodstoves. Further, POM emission factors, as based on
the 7-PAH and 16-PAH values, determined from the in-home use of woodstoves in this study
were lower than the POM emission factors previously published in AP-42. This observation is
significant because the AP-42 emission factors are the basis for the national emission inventory
of POM for which residential wood combustion was identified as the single largest source.
IV
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Table of Contents
Page
Executive Summary iii
List of Tables vi
List of Figures vii
Section 1.0 Introduction 1
Section 2.0 Methodology 3
2.1 Automated Woodstove Emission Sampler 3
2.2 Woodstoves, Fuel, and Ambient Temperature 5
2.3 Field Measurements, Laboratory Support, and Data Reduction 8
Section 3.0 Results and Discussion 24
3.1 Condition of Stoves 24
3.2 Particulate Matter Emissions 31
3.3 Polycyclic Organic Matter Emissions 47
Section 4.0 Conclusions 56
Section 5.0 Acknowledgments 57
Section 6.0 References 58
Appendix A Photographs of Woodstoves A-l
Appendix B Quality Assurance History — Automated Woodstove Emission Sampler . .. . B-l
Appendix C Summary of Automated Emissions Sampler Data by Test C-l
Appendix D Organic Compound Analysis Data D-l
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List of Tables
Table Page
2-1 Home Code, Model, and Chimney Characteristics for Klamath Falls Woodstoves 6
2-2 Home Code, Model, and Chimney Characteristics for Portland Woodstoves 7
2-3 Wood Data for Klamath Falls Homes 9
2-4 Wood Data for Portland Homes 10
2-5 Principal Field and Laboratory Measurements 12
2-6 Derived Parameters 16
2-7 7-PAH and 16-PAH Surrogates for POM 21
3-1 Home Code, Model, and Condition for Klamath Falls Woodstoves 25
3-2 Home Code, Model, and Condition for Portland Woodstoves 28
3-3 Individual Test Results for Klamath Falls Stoves KF01 - KF04 32
3-4 Individual Test Results for Klamath Falls Stoves KF05 - KF08 34
3-5 Individual Test Results for Portland Stoves P01 - P04 36
3-6 Individual Test Results for Portland Stoves P05 - P08 38
3-7 Average Fuel Moisture, Paniculate Emissions, Burn Rate, and Outdoor Temperature for
Stoves in Klamath Falls 40
3-8 Average Fuel Moisture, Particulate Emissions, Burn Rate, and Outdoor Temperature for
Stoves in Portland 41
3-9 Summary of Particulate Emission Results 43
3-10 Comparison of Average Particulate Emission Factors (5H Adjusted) to AP-42 Values . 44
3-11 Comparison of Particulate Emission Factors of Stoves in Current Study
to Particulate Emission Factors for the Same Stoves from Previous Studies 45
3-12 Comparison of Stove Particulate Emission Rates to U.S. EPA Certification Values ... 46
3-13 Organic Compound Emission Factors and Rates For Stoves in Klamath Falls Homes . 48
3-14 Organic Compound Emission Factors and Rates for Stoves in Portland Homes 50
3-15 Organic Compound Emission Factors and Rates for Overall Study 52
3-16 Comparison of POM Emission Factors for Stoves in Current Study
to AP-42 POM Emission Factors 54
VI
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List of Figures
Figure Page
2-1 Schematic Diagram of the Automated Woodstove Emission Sampler 4
2-2 Flow Chart Summarizing Analysis Procedures 15
vn
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Section 1.0
Introduction
Residential wood combustion (RWC) has been identified as a major source of particulate
matter (PM) and polycyclic organic matter (POM) air emissions. During 1997, RWC contributed
an estimated 12% of the sum of the total PM10 emissions attributed to all fuel combustion,
industrial process, and transportation sources combined (1). RWC was also identified as the
largest single source of POM during 1990 (2). Approximately 72% of the cordwood burned
annually in the United States in the category of residential wood combustion is in
woodstoves (2). (The remaining 28% is mostly burned in fireplaces.) There were an estimated
9.3 million woodstoves in homes during the 1997-1998 heating season (3).
Due to the level of emissions attributed to woodstoves, standards of performance were
promulgated for new residential wood heaters (4). All wood heaters sold after July 1, 1992, have
to meet the most stringent Phase 2 particulate emission limits of the standards. These standards
were 4.1 gram per hour for catalytic stoves and 7.5 grams per hour for non-catalytic stoves. The
limits for catalytic stoves were set lower than non-catalytic stoves since the presumed
deterioration of the catalyst over time was estimated to result in emissions from catalytic wood
heaters over their useful lifetimes approximately equal to non-catalyic wood heaters.
Furthermore, there has been concern about the overall physical deterioration of wood
stoves with use and the commensurate increase in air emissions. This concern has been
confirmed in both laboratory (5,6) and in-home studies (7-9). Physical degradation coupled with
higher PM emissions has been documented for some stoves. Not only are accurate airshed
inventories of PM and POM fundamentally important for health and environmental assessments,
state and local agencies in areas of PM10 nonattainment have been directed to take performance
degradation into consideration in their State Implementation Plans (SIPs) when calculating
credits from replacing non-certified stoves with certified stoves (10). The replacement of non-
certified stoves with Phase 2 certified stoves remains a viable option for reducing airshed
pollutant levels and obtaining PM10 SIP credits because, as of 1997, more than 80% of the
woodstoves in use were still older non-certified units (11). In addition, because over 90% of the
PM10 emissions from residential wood combustion are also PM25, emission credits may be very
important for possible future PM25 nonattainment areas.
The primary objective of the study was to select Phase 2 stoves that were installed in
homes prior to the fall of 1992 in order to assess the level of long-term degradation and potential
1
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increase in PM and POM air emissions of older Phase 2 certified stoves under actual in-home
usage. Woodstoves in homes in both Portland, Oregon, and Klamath Falls, Oregon, were
selected because Portland is in U.S. climate zone three and Klamath Falls is in U.S. climate zone
two. The average heating degree day (HDD) value for Portland is 4109 and the average HDD for
Klamath Falls is 6600. The intent behind the selection of stoves in the two climatologically
dissimilar cities was to produce results more widely applicable to woodstove usage in the nation
as a whole than if homes in a single city were selected. In addition, nine Phase 2 stoves installed
in homes in Klamath Falls were previously studied during the 1989-1990 and 1991-1992 heating
seasons (8,12,13). Therefore, a secondary objective of the study was to utilize as many of these
homes as possible in the current study to help document phase 2 stove degradation and
commensurate emission increase.
Sixteen homes were targeted for study during the 1998-1999 heating season. Two in the
study group were homes in Klamath Falls that had phase 2 woodstoves that were part of the
earlier studies. Emission samples were collected for three one-week periods from woodstoves in
each home using the Automated Woodstove Emission Sampler (AWES) previously developed by
OMNI Environmental Services, Inc., for similar studies. Samples collected with the AWES were
analyzed for particulate matter and organic compounds. The specific organic compounds
analyzed included the seven and sixteen POM compounds needed to calculate the 7-PAH and
16-PAH values, respectively, which are used as surrogate indicators for POM. The PM and
POM surrogate emission factors (mass of pollutant emissions per unit mass of fuel) were
compared against their emission factors tabulated in AP-42 for woodstoves (14). The PM
emission rates (mass of pollutant emissions per time of stove operation) measured under actual
in-home use for each woodstove model were compared against their certified emission values
listed by the U.S. Environmental Protection Agency (15). The PM emissions from this study and
from the previous studies were compared for the stoves in the Klamath Falls homes that were
part of earlier studies. Cordwood tree species, cordwood moisture, the amount of cordwood
burned, burn rates, ambient temperature during testing, a description of woodstove use in each
home, chimney characteristics, and the condition of the stoves were also documented as part of
the study. Photographs of each stove's installation and components that showed degradation
have been included as Appendix A.
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Section 2.0
Methodology
The basis of the study was the use of the AWES for sample and data collection. A
description of the AWES is provided in Section 2.1. Woodstove selection and inspection and
cordwood characterization are discussed in Section 2.2. Details of the field sampling program,
supporting laboratory procedures and data reduction are provided in Section 2.3.
2.1 Automated Woodstove Emission Sampler
The AWES was developed to quantify emissions of particles for residential wood burning
appliances while they are in normal in-home use. It is small in size and operates unattended in
home settings. Due to the temporal variability in emissions from wood burning appliances, the
AWES is also designed to collect long-term integrated samples necessary to provide mean
values. Studies conducted with the AWES have provided the majority of the data base used for
paniculate emission factors development by the U.S. Environmental Protection Agency for
residential wood combustion (14). The AWES has been used to quantify emissions from
woodstoves, masonry heaters, pellet stoves, and fireplaces (5-8,12,13,16-36). Due to its extensive
use, the AWES has undergone U.S. Environmental Protection Agency supported quality
assurance evaluations during the period 1986 to 1992 (Appendix B).
A schematic diagram of the AWES is shown in Figure 2-1. Detailed descriptions of its
principles of operation, supporting laboratory requirements, calibration, associated data reduction
and uncertainty estimates have been published in U.S. Environmental Protection Agency and
U.S. Department of Energy reports (16,19) and quality assurance plans (Appendix B).
For sampling purposes, the AWES is placed adjacent to the wood-burning appliance in study
homes. For woodstove applications, a stainless steel inlet probe is typically attached to the
chimney (stove pipe) 30 cm above the flue collar of the stove. Sample is withdrawn at a rate of
approximately one liter per minute. The flow rate is maintained by a calibrated orifice.
Paniculate samples, including condensible particles, are captured with a heated filter followed by
an XAD-2® resin cartridge. All interconnecting tubing, holders and hardware exposed to the
sample are made either of stainless steel or Teflon® to maintain sample integrity. After sample
collection, the chimney gas is passed through silica gel to protect downstream components from
condensate. The oxygen content of the chimney gas is measured with an electrochemical cell.
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Room
Temperature
Thermocouple
Signal Processor
(PCLD-789 and
PCLD-7115 Boards)
Communication Cable
Data Logging System
(AMD K6 266 MHz PC
wfthPCL-711
Data Aquistition Board)
Flue Thennoconple
Exhanst Return
AWES
Heated Chamber
ThennostBt
and Heater
| Fitter
Rotometer
Inlet
Calibration
Gas Inlet
Port
Residential
Woodstove
Figure 2-1
Schematic Diagram of the Automated Woodstove Emission Sampler
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The sample flow is then returned to the wood-burning appliance chimney above the point where
the sample was withdrawn. Room temperature and chimney gas temperature are measured with
type K thermocouples. The chimney gas temperature is measured within the chimney at the same
location as the sample is withdrawn.
A key component of the AWES is the data logging system. The system records date, time,
oxygen content, room temperature, and chimney gas temperature at regular intervals. The oxygen
content of the chimney gas, along with the mass of wood burned, allows for the estimation of
total chimney gas flow during sampling which is needed for the subsequent calculation of
emission rates and emission factors. The record of chimney gas temperatures allows for the total
time of appliance operation over the course of the sampling duration to be determined. In
addition to data recording, the system is programed to control the sampling frequency, sampling
duration and sampling period. For this study, the AWES was programed to sample for two
minutes once every 15 minutes for one week. The system is further programed to turn the
sampling pump on during the programmed two minute sampling time only if the woodstove is in
operation as determined by the chimney temperature in order to avoid collection of sample
material when the appliance is not in operation. A threshold chimney temperature of 100°F
(38 °C) was used as an indicator of woodstove operation.
2.2 Woodstoves, Fuel, and Ambient Temperature
A total of 16 woodstoves, eight in Klamath Falls and eight in Portland, were targeted for
study. One home in Klamath Falls was dropped from the study after one week due to a family
crisis. An additional home was added to the study in Portland to replace the dropped home. Out
of the nine possible phase 2 certified woodstoves that were part of previous studies in Klamath
Falls two were included in this study. An attempt was made to include the other seven in the
current study but it was not possible either due to stove replacement since the last studies or an
unwillingness of the current home occupants to participate in this study. Tables 2-1 and 2-2 list
the home codes, woodstove models, and chimney characteristics for all installations. The
chimney characteristics were documented because draft and commensurate fire intensity which is
affected by chimney height have been implicated in the degradation of woodstove components.
A photograph of each stove was taken to illustrate its installation (Appendix A).
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Table 2-1
Home Code, Model, and Chimney Characteristics for Klamath Falls Woodstoves
Home Code
KF01
KF02b
KF03C
KF04
KF05
KF06
KF07
KF08
Stove Model1
Quadrafire
2100
Non-Catalytic
Pacific Energy
Super 27
Non-Catalytic
Haughs
171E
Non-Catalytic
Earthstove
1003C
Catalytic
Pacific Energy
Super 27
Non-Catalytic
Waterford
104MKII
Non-Catalytic
Earthstove
1400HT
Non-Catalytic
Country
T-Top
Non-Catalytic
Chimney Characteristics
8 Foot Vertical Rise
Single Story Home
27 Foot Vertical Rise
Two Story A-Frame
14 Foot Vertical Rise
Two Story Home
14 Foot Vertical Rise
Single Story Home
18 Foot Vertical Rise
Single Story Home
21 Foot Vertical Rise
Two Story Home
14 Foot Vertical Rise
Single Story Home
20 Foot Vertical Rise
Two Story A-Frame
a All stoves were installed prior to the 1992/1993 heating season.
b Stove in home KF02 in this study was referred to as Home 3 or CK03 in the 1990 Energy, Mines
and Resources Canada (EMRC) Study03'.
c Stove designated as KF03 in this study was referred to as H-5 or WK05 in the 1990 Wood
Heating Alliance (WHA) Study02'. Additionally, this stove was referred to as KF04 in the 1992
Bonneville Power Administration (BPA) study'8'.
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Table 2-2
Home Code, Model, and Chimney Characteristics for Portland Woodstoves
Home
Code
P01
P02
P03
P04
P05
P06
P07
P08
Stove*
Trailblazer
Genesis 2000
Catalytic
Lopi
Answer Series
Non-Catalytic
Lopi
380-96
Non-Catalytic
Lopi
Flush Bay-96b
Catalytic
Lopi
Flex-95
Catalytic
Pacific Energy
Super 27
Non-Catalytic
Lopi
520-96
Non-Catalytic
Vermont Castings
Defiant Encored0
Catalytic
Chimney/House
8 Foot Vertical Rise
Single Story Manufactured Home
15 Foot Vertical Rise
Single Story Home
1 1 Foot Vertical Rise
Single Story Manufactured Home
22 Foot Vertical Rise
Two Story Home
22 Foot Vertical Rise
Two Story Home
10 Foot Vertical Rise
Single Story Home
13 Foot Vertical Rise
Single Story Home
24 Foot Vertical Rise
Two Story Home
a All stoves were installed prior to the 1992/1993 heating season.
b Lopi Flush Bay-96 is now called Freedom.
c The Vermont Castings Defiant Encore stove was installed when stove was EPA Phase I certified.
Since the installation, the stove has been added to EPA Phase n certification list without changes
to the stove's design.
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Each stove was inspected and the home occupants were interviewed regarding its
historical and current usage. A description was made and photographs were taken of any
components that showed degradation (Appendix A).
Participants in the study were either provided with, or reimbursed for the cost of locally
available cordwood fuel. Fuel moisture was measured with a Delmhorst moisture meter. If the
meter indicated that the wood moisture was greater than 30% (dry basis), the moisture content
was determined through drying/gravimetric analysis in the laboratory. Average fuel moisture by
week and by home was based on measurements on approximately 10% of the cordwood fuel
pieces. Pre-weighed bundles of wood were provided to the occupants of each home prior to each
week of sampling. A portable spring scale was used to measure the wood weight. The unused
pieces of each bundle were weighed at the end of the sampling week. The amount of wood
burned during the week-long tests was calculated by adding the weights of the bundles used
(including the weight of wood used in the partly consumed bundles).
Wood Data for Klamath Falls are compiled in Table 2-3. Wood Data for Portland are
compiled in Table 2-4. Lodgepole pine, ponderosa pine, juniper and Douglas fir cordwood was
used in the Klamath Falls appliances. Douglas fir, maple, alder, oak, birch, lodgepole pine and
cherry cordwood was used in the Portland appliances. The mass burned, percentage of the wood
burned, and moisture content of cordwood by species in each home during each sampling week
are shown in Tables 2-3 and 2-4. The average wood moisture by cordwood tree species ranged
from 9.8% to 26.8% on a dry basis (9.0% to 21.1% on a wet basis) for Klamath Falls and from
18.1% to 112.1% on a dry basis (15.3% to 52.8% on a wet basis) for Portland.
The elemental composition (carbon, oxygen, nitrogen and hydrogen) was determined for
each species of wood by proximate/ultimate analysis (ASTM D3178). Elemental data were used
to calculate the stoichiometric volume of gas produced from a given mass of wood burned during
sampling which is, in turn, were used in conjunction with AWES oxygen measurements to
estimate the total chimney gas flow.
Average outdoor temperatures were calculated for each sampling week as an indicator of
heating demand. The average values were calculated from the daily average temperatures
recorded at nearby weather stations for Klamath Falls (37) and Portland (38). The recorded daily
average temperatures were simply the average of the daily high and low temperatures in each
location.
2.3 Field Measurements, Laboratory Support, and Data Reduction
The principal field and laboratory measurements with associated uncertainties used to
calculate the emission and ancillary results are listed in Table 2-5. Fuel measurements as
discussed in Section 2.2, infield measurements made by the AWES, laboratory measurements
made on the collected samples, and measurements associated with AWES calibration are
included in this table.
8
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Table 2-3
Wood Data for Klamath Falls Homes
Home Code
KF01
KF02
KF03a
KF04a
KF05
KF06a
KF07
KF08
Sampling
Week
A
B
C
A
B
C
B
C
A
B
A
B
C
A
A
B
C
A
B
C
Mass Burned
(Wetlbs)
296.3
319.4
170.3
432.7
457.3
313.8
280.0
14.7
346.9
18.3
203.0
203.0
467.0
303.2
155.7
379.3
277.5
349.2
294.5
496.5
525.1
522.1
567.6
Species
Lodgepole
Lodgepole
Ponderosa
Ponderosa
Ponderosa
Ponderosa
Lodgepole
Juniper
Lodgepole
Juniper
Lodgepole
Douglas Fir
Lodgepole
Juniper
Juniper
Juniper
Lodgepole
Lodgepole
Lodgepole
Lodgepole
Ponderosa
Ponderosa
Ponderosa
% Species
100
100
100
100
100
100
95
5
95
5
50
50
100
100
100
100
100
100
100
100
100
100
100
Moisture
% (Dry Basis)
20.2
24.5
31.4
20.8
21.5
19.6
14.6
13.2
18.8
18.3
21.8
21.4
19.5
10.4
9.8
11.3
11.7
12.6
11.7
15.8
26.8
25.4
15.7
a There are no data for week A for KF03 and week C for KF04 due to loss of sample and/or laboratory
data. There are no data for weeks B and C for KF06 due to death in the family.
-------
Table 2-4
Wood Data for Portland Homes
Home Code
P01
P02
P03
P04
P05
Sampling
Week
A
B
C
A
B
C
A
B
C
A
B
C
A
B
C
Mass Burned
(Wetlbs)
573.1
557.1
570.3
51.8
13.0
194.3
227.5
110.1
110.1
71.6
160.4
94.0
94.0
184.1
286.3
200.7
53.5
53.5
36.0
36.0
42.0
42.0
Species
Douglas Fir
Douglas Fir
Douglas Fir
Maple
Douglas Fir
Alder
Oak
Douglas Fir
Oak
Douglas Fir
Douglas Fir
Douglas Fir
Birch
Oak
Oak
Oak
Lodgepole
Cherry
Lodgepole
Cherry
Lodgepole
Cherry
% Species
100
100
100
20
5
75
100
50
50
100
100
50
50
100
100
100
50
50
50
50
50
50
Moisture
% (Dry Basis)"
24.0
21.0
22.8
105.3
36.4
106.6
18.5
35.4
19.1
18.3
18.3
19.8
27.0
18.3
18.5
18.4
20.6
18.1
19.8
18.2
19.3
18.8
(Continued)
See equation 6.
10
-------
Table 2-4 (continued)
Wood Data for Portland Homes
Home Code
P06
P07
P08b
Sampling
Week
A
B
C
A
B
C
A
B
Mass Burned
(Wetlbs)
181.7
48.4
678.4
164.4
41.1
616.3
155.0
38.7
581.1
214.6
53.7
804.9
227.9
57.0
854.7
894.4
46.7
419.9
16.8
151.1
Species
Maple
Douglas Fir
Alder
Maple
Douglas Fir
Alder
Maple
Douglas Fir
Alder
Maple
Douglas Fir
Alder
Maple
Douglas Fir
Alder
Douglas Fir
Douglas Fir
Oak
Douglas Fir
Oak
% Species
20
5
75
20
5
75
20
5
75
20
5
75
20
5
75
100
10
90
10
90
Moisture
% (Dry Basis)1
105.3
36.4
106.6
104.2
38
112.1
101.1
35.4
107.9
105.3
36.4
106.6
104.2
38
112.1
24.8
21.8
25.1
21.9
25.4
1 See equation 6.
b There are no data for week C for P08 due to loss of sample data.
11
-------
Table 2-5
Principal Field and Laboratory Measurements
Parameters
1. Wood Fuel Weight
2. Wood Fuel Moisture
3. C, O, N, H Composition of Wood
4. Mass of Particles Collected on Filter
5. Mass of Particles Collected in Probe and
Connecting Tubing
6. Mass of Semi-Volatiles Collected on XAD-2®
7. Sample Flow Rate
Units
kg
% by Mass
(Dry Basis)
% by Mass
mg
mg
mg
1/min
Method of Determination
Spring Scale
ASTMD2016(>30%)
Delmhorst Model RC Moisture Meter ( <30%)
ASTMD3178
Analytical Balance
Removal/Solvent Evaporation/Analytical Balance
Extraction/Solvent Evaporation/Analytical
Balance
Bubble Flow Meter/Digital Timer
Estimated
Precision
±0.1%
±10%
±1%
Absolute
±1%
Absolute
±0.3%
± 0.3%
± 0.3%
±3%
Estimated
Accuracy
±0.1%
±5%
±1%
Absolute
±1%
Absolute
±0.3%
± 0.3%
± 0.3%
±2%
(Continued)
-------
Table 2-5 (continued)
Principal Field and Laboratory Measurements
Parameters
8. Chimney Gas O2
9. Mean Barometric Pressure (for Flow
Calibration)
10. Duration of Sampling
1 1. Temperature (Chimney, Ambient)
12. Sampling Period
13. POM Compounds Contained in
Particles
14. POM Compounds Contained in
Vapor Phase
Units
% by Volume
in.Hg
min
op
min
"g
"g
Method of Determination
AWES/Electrochemical Sensor
Mercury Barometer
Data Logger Internal Clock
Type K Thermocouple
Data Logger Internal Clock
EPA SW-846 Method 8270C
EPA SW-846 Method 8270C
Estimated
Precision
± 0.8%
absolute
±0.5 mm
Hg
±0.1%
±4°For
± 0.75%
(Whichever
is Greatest)
±0.1%
±20%
±20%
Estimated
Accuracy
± 0.8% Absolute
± 0.5 mm Hg
±0.1%
±4°For
± 0.75%
(Whichever
is Greatest)
±0.1%
±20%
±20%
-------
Laboratory measurements were made on three AWES sample components:
1. The probe and interconnecting tubing;
2. The heated filter; and
3. The XAD-2® resin cartridge.
For this study since both PM and POM surrogates were measured, the sample material
was split into two portions for analysis. Figure 2-2 is a flow chart summarizing the analysis
procedures. The sample probe and tubing connecting the probe to the heated filter were rinsed
with a 50/50 mixture of methylene chloride and methanol. A stainless steel wire brush was used
to remove material from the sample probe prior to the 50/50 methylene chloride/methanol
mixture rinse. Both the removed material and solvent rinse were collected in a single beaker.
One half of the mixture was taken to dryness and weighed to calculate its PM content. One half
was combined with the XAD-2® extract and reduced to 5 mL volume for organic compound
analysis by gas chromatography/mass spectrometry (SW-846 Method 8270C).
The pre-weighed filter was placed in a desiccator until a constant weight was achieved.
The difference between pre-and post-weights allowed for the mass of particles collected on the
filter to be determined. The filter was spiked and then extracted with methylene chloride,
reduced in volume to 5 mL and analyzed for organic compounds by SW-846 Method 8270C.
Surrogates and matrix spikes were added to the XAD-2® resin cartridge for the POM
determination. The resin was then extracted with a Soxhlet extractor using methylene chloride.
One half of the extract was evaporated to dryness for mass (PM) determination and one half was
added to the probe and interconnecting tubing rinse for organic compound analysis by SW 846
Method 8270C.
The masses of PM and POM surrogates contained in each of the three components were
added to obtain the total mass captured with the AWES system.
Table 2-6 lists the intermediate and final parameters derived from the field and laboratory
measurements. Except for the POM compound emission factors and rates (items 10 and 11 in
Table 2-6), the precision and accuracy uncertainties for the intermediate and final derived
parameters were determined from the estimated uncertainties of the principal field and laboratory
measurements shown in Table 2.5 following standard propagation of error procedures (16,19).
The uncertainties for the POM compound emission factors and rates shown in Table 2-6 were
estimated from data from similar studies (23,25,39,40).
14
-------
Probe/Interconnecting
Tubing
Glass Fiber
Fitter
XAO-2
Cartridge
Rinse WHh 50/50
Methylene Chlorkte/Methanol
Dry
Weigh
Add Surrogates
and Matrix Spike
•XAO-2 and Rinse
Reduce Volume to 5ml
Dry
Weigh
Combine with
Probe And Tubing Rinse*
Figure 2-2
Flow Chart Summarizing Analysis Procedures
15
-------
Table 2-6
Derived Parameters
Parameters
1. Mass Particles/Volume of
Chimney Gas
2.Mass Particles/Mass Dry
Wood Burned
3. Mass Particles/Time of Stove
Operation
4. Dry Mass of Wood Burned
5. Percent of Time Stove in
Operation
6. Mean Fuel Moisture by
Species
7. Mean Wood Burn Rate
8. Mean Chimney Gas Oxygen
Concentration
9. Mean Chimney Gas
Temperature
10. Mass of POM
Compounds/Mass Dry Wood
Burned
11. Mass of POM
Compounds/Time of Stove
Operation
Units
g/m3
g/kg
(Dry)
g/hr
kg
%
%(Dry
Basis)
kg/hr
(Dry)
%by
Volume
°F
Hg/kg
(Dry)
Hg/kg
(Dry)
Method of Determination
AWES Data Logger
System/Lab Support
AWES Data Logger
System/Lab Support
AWES Data Logger
System/Lab Support
Fuel Scale
Type K Thermocouple/Data
Logger
<30% - Delmhorst Moisture
Meter
>30% - Gravimetric Analysis
Fuel Scale/Data Logger
Electrochemical Sensor/Data
Logger
Type K Thermocouple/Data
Logger
AWES Data Logging System/
Lab Support
AWES Data Logging System/
Lab Support
Estimated
Precision
±8%
±16%
±20%
±0.1%
±3%
<±2%
Absolute
±4%
±0.1%
± 0.3%
Absolute
±4 "For
± 0.75%
(Whichever
is Greatest)
±50%
±50%
Estimated
Accuracy
±5%
±17%
±18%
±0.1%
±3%
<±2%
Absolute
±2%
±0.1%
± 0.69%
Absolute
Uncorrected
± 0.2%
Absolute
Corrected
± 4 °F or
± 0.75%
(Whichever
is Greatest)
±50%
±50%
16
-------
The following formulas were used to calculate the derived parameters listed in Table 2-6.
Mass of particles/volume of chimney gas = / v \ (V
(FRXSDJ
where:
MP = Mass of particles collected by the AWES (sum of the particles collected on
the probe and interconnecting tubing, on the filter, and on the XAD-2®
resin)
FR = Flow rate of the AWES, and
SD = Sampling duration of the AWES.
Mass of particles/mass dry wood burned = -,—p =r (2)
(FR)(SD)(l - [%O2/20.9% J)
where:
(TF)
Mass paniculate emissions (MP) = (M P), yon^
Total chimney gas volume (TF) =
20.9%
S V = Volume of chimney gas per unit mass of dry wood from the stoichiometric
combustion of wood, obtained from proximate/ultimate analysis data and a
small correction for carbon monoxide levels characteristic of EPA-
certified Phase 2 woodstove emissions,
MDW = Mass of dry wood burned during sampling (see equation 4), and,
%O2 = Percent of oxygen in chimney gas measured with the AWES.
17
-------
Mass participate emissions/time of stove operations =
(MP)(SV)(MDW)(100)
(3)
(FR)(SD)(SP)(WO)(l -[% 02/20.9% ])
where:
SP = Sampling period (usually one week), and,
WO = Percent of time stove in operation (see equation 6).
A ( MWW ^
Dry mass of wood burned = V X \ ^ __ (4)
"~j \\ + MDCiy
where:
i = the wood species,
Xj = the fraction of the total wood of the i* species used,
MDQ = the mean moisture content (dry basis) of species i (see equation 6), and
MWW = Mass of wet wood burned. The wood used for the duration of the testing
was pre-weighed. Fuel use was the difference between amount of weighed
wood at the start of the test, and the amount of weighed wood remaining at
the end of the test. The data were summed over the time periods of
interest.
Fraction of time stove was in operation
The woodstove was determined to be in operation whenever chimney gas temperatures
exceeded 38° C (100° F). Temperature was determined continuously by a thermocouple
and the value was recorded every fifteen minutes. The fraction of time the stove was
operating was calculated as follows:
18
-------
Percent of time woodstove operates (WO) =
# of readings where Tf > 100°F V1/VVJ/
A i(JU%. (%}
Total # of readings w
Mean fuel moisture by species
Mean fuel moisture was determined each week by successive measurements of fuel
stockpiled for immediate burning. The average moisture for each species of fuel wood
was determined from at least ten percent or more of the total wood pieces for each species
of wood for each sampling week.
n
Average weekly fuel moisture (dry basis) for species i (MDQ) = — XMCj (6)
n j»,
where:
= Moisture value of the j* measurement (n > 6).
When a moisture meter reading exceeded 30 percent moisture (dry basis), a sample was
taken and moisture determined by the standard oven drying technique (ASTM D2016) In
these cases:
WBD-WAD
MDC, = — (6a)
where:
MDCj = Dry basis moisture content of species i,
WBD = Weight of sample before drying, and
WAQ = Weight of sample after oven drying.
19
-------
Mean Wood Burn Rate
(MDW)(100)
Mean wood bum rate = (SP)(WO) (7)
where:
MDN = Mass of dry wood burned during sampling (see equation 4),
SP = Sampling period, and
WO = Percent of time stove in operation (see equation 6).
Mean Chimney Gas Oxygen Content in Percent
1 n
i T--I
Mean chimney gas oxygen content in percent (% O2) = — XChi (8)
n i=i
where:
O2; = oxygen concentration of the chimney gas of the i* reading (%), and
n = total number of valid readings.
Chimney oxygen was recorded every fifteen minutes and averaged over each sampling
week or fraction of the sampling week of interest.
Mean Chimney Gas Temperature
1 "
Mean chimney gas temperature (Tf) = — V (Tr) (9)
n i
where:
(Tf)j = Mean chimney gas temperature for the i* valid reading, and
n = Number of valid readings in the sampling period.
20
-------
Mass of POM compounds / mass of dry wood burned
The mass of each individual 7-PAH and 16-PAH compound's emissions were
summed to get the 7-PAH and 16-PAH POM surrogate mass emission values,
respectively. By substituting these values for the particulate mass emission value
(MP) in equation 2, the emission factors (mass POM surrogate/ mass of dry wood)
for the 7-PAH and 16-PAH POM surrogates were calculated. The seven and 16
individual compounds that make up the 7-PAH and 16-PAH surrogates are listed
in Table 2-7 and the calculations conducted according to Equation (10).
Table 2-7
7-PAH and 16-PAH Surrogates for POM
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene*
Benzo(a)pyrene*
Benzo(b)fluoranthene*
Benzo(g,h,i)perylene
Benzo(k)fluoranthene*
Chrysene*
Dibenzo(a,h)anthracene*
Fluoranthene
Fluorene
Indeno( 1 ,2,3-cd)pyrene*
Naphthalene
Phenanthrene
Pyrene
* 7-PAH Compounds
21
-------
(PAH)(SV)
Mass of POM/mass dry wood burned = -,—p 77 (10)
(FR)(SD)(!-[%O2/20.9% J)
where:
(TF)
(PAH)
Mass of PAH emissions (PAH) =
Total chimney gas volume (TF) = ——-
20.9%
SV = Volume of chimney gas per unit mass of dry wood from the stoichiometric
combustion of wood, obtained from proximate/ultimate analysis data and a
small correction for carbon monoxide levels characteristic of EPA-
certified Phase 2 woodstove emissions,
MDW = Mass of dry wood burned during sampling (see equation 4), and
%O2 = Percent of oxygen in chimney gas measured with the AWES.
Mass of POM compounds/time of stove operation
The 7-PAH and 16-PAH POM surrogate mass emission values were substituted for the
particulate mass emission value (MP) in equation 3 to calculate the emission rates (mass
POM surrogate/ time of stove operation) for the 7-PAH and 16-PAH surrogates.
Mass particulate emissions/time of stove operations =
(PAH)(SV)(MDW)(100)
(FR)(SD)(SP)(WO)(l-[%02/20.9%])
where:
SP = Sampling period (usually one week), and
WO = Percent of time stove in operation (see equation 6).
22
(11)
-------
In the conduct of field measurements, laboratory support and data reduction tasks, the
quality assurance procedures that have been developed for previous U.S. EPA studies (see
Appendix B) were followed. In addition a project specific quality assurance plan was developed
and approved for this study. Two key quality assurance activities were an independent check of
10% of the data reduction and the processing of field blanks.
23
-------
Section 3.0
Results and Discussion
The results are presented in three sections. The condition of the stoves along with their
history and current use and a description the home settings is provided in Section 3.1. Particulate
emission results are presented Section 3.2. POM emission results are presented in Section 3.3.
3.1 Condition of Stoves
Table 3-1 lists the home code, stove model, and a summary of the stove condition and
usage for homes in Klamath Falls. Photographs of these stoves and degraded components are
provided in Appendix A. A narrative description for the stoves in Klamath Falls by home code
(home codes KF01 through KF08) follows.
KF01 The QuadraFire 2100 (Appendix A, Photograph 1) was installed September 10, 1991 and
has been owned and operated by the same person. It is located in a dusty environment in
a ceramic shop with poor insulation. It is in overall good condition except for the
ceramic blanket which is pushed up partially blocking the exhaust flow (Appendix A,
Photograph 2). The blanket installation was repaired before testing was conducted for
this study. The stove is used as the primary heat source for the small business and is
usually operated for more than 16 hours per day during the heating season. The chimney
is cleaned and inspected once per year. The owners of the business live adjacent to the
shop and use an oil furnace as a supplemental heating source when the shop is
unoccupied.
The owner typically burns two to three cords of lodgepole pine cordwood a year, and
feels that the stove has heated the shop well. However, the owner noted that the stove
was difficult to light, and sometimes initially difficult to keep burning. These problems
were probably due to the ceramic blanket partially blocking the exhaust flow.
KF02 The Pacific Energy Super 27 (Appendix A, Photograph 3) was provided to the
homeowner as part of the 1990 Wood Heating Alliance (WHA) study (12). The home is
a two-story A-frame style. The previous owners had the baffle replaced (Appendix A,
Photograph 4) approximately six years prior to the study with an identical baffle because
the baffle assembly had degraded to the point that the stove would not heat the home
adequately. The baffle was replaced by a professional installer. Otherwise, the
24
-------
Table 3-1
Home Code, Model, and Condition for Klamath Falls Woodstoves
Home Code
KF01
KF02"
KF03C
KF04
KF05
KF06
KF07
KF08
Stove Model'
Quadrafire
2100
Non-Catalytic
Pacific Energy
Super 27
Non-Catalytic
Haughs
171E
Non-Catalytic
Earthstove
1003C
Catalytic
Pacific Energy
Super 27
Non-Catalytic
Waterford
104 MKn
Non-Catalytic
Earthstove
1400HT
Non-Catalytic
Country
T-Top
Non-Catalytic
Stove Condition and Usage
Impaired / Normal Wear11
Minimal Use during Heating Season
Impaired / Normal Wear*1
Extensive Use during Heating Season
Normal Wear
Extensive Use during Heating Season
Normal Wear
Extensive Use during Heating Season
Impaired
Regular Use during Heating Season
Impaired
Regular Use during Heating Season
Normal Wear
Extensive Use during Heating Season
Normal Wear
Extensive Use during Heating Season
a All stoves were installed prior to the 1992/1993 heating season.
b Stove in home KF02 in this study was referred to as Home 3 or CK03 in the 1990 Energy, Mines
and Resources Canada (EMRC) Study (13).
c Stove designated as KF03 in this study was referred to as H-5 or WK05 in the 1990 Wood
Heating Alliance (WHA) Study (12). Additionally, this stove was referred to as KF04 in the 1992
Bonneville Power Administration (BPA) study (8).
d The stove was impaired by use but was repaired and in the "normal wear" condition at the time of this
study.
25
-------
installation has not changed since the WHA study. The chimney system is inspected and
cleaned once a year.
The owner typically burns five cords of lodgepole pine or ponderosa pine each burning
season. The unit is used as the primary heat source and fired 24 hours per day. The
owner feels that it heats the home well.
KF03 The Haughs 17 IE woodstove (Appendix A, Photograph 5) was given to the current
owner as part of the 1990 WHA study (12) and was also used in the 1992 Bonneville
Administration (BPA) study (19). It is in overall good condition showing only normal
wear, with the exception of cracking along the rear level of secondary air ports
(Appendix A, Photograph 6). The unit has been operated and maintained by the same
home owners that participated in the 1990 and 1992 studies and there have been no
changes in the installation of this unit.
They feel that the stove has heated the home well. Approximately five cords of mixed
juniper, cedar, and lodgepole pine are burned per heating season.
KF04 The Earthstove model 1003-C (Appendix A, Photograph 7) was installed in early 1992.
It is designed for mobile home installation getting its combustion air from outside the
home. It is in good overall condition. The owner felt that the catalytic combustor was no
longer working and needed replacement. Visual inspection did reveal some thermal
wear. However, temperatures observed in the flue and at the installed catalyst
temperature indicator during testing showed that the catalyst was in proper working order.
The door gasket was in good condition, as were the refractory elements.
The owner felt that the unit heated the home well. It is used as the primary heat source,
and fired 24 hours per day. Typically, four to five cords of Douglas fir are burned per
heating season.
KF05 The Pacific Energy Super 27 (Appendix A, Photograph 8) was installed November 23,
1991, and has been owned and operated by the same person. It is in overall fair
condition with the exception that the front right portion of the baffle area and the ceramic
blanket are degraded (Appendix A, Photograph 9). The stove is used as the primary heat
source and operated for more than 16 hours per day during the heating season. The
chimney is cleaned and inspected once per year.
The owner uses the stove as the primary heat source during the burning season, and feels
that it heats the home well. Typically two to three cords of juniper are burned per year.
KF06 The Waterford MKII (Appendix A, Photograph 10) was installed on July 12, 1991, and
has been operated by the same owners. The chimney is cleaned and inspected once per
year. It is in good operating condition except for the front portion of the baffle which is
26
-------
in a severely degraded state (Appendix A, Photograph 11). Such degradation is probably
either the result of thermal or chemical breakdown of the baffle material. Chemical
breakdown such as was seen on the baffle can be caused by burning trash. Thermal
breakdown can be caused by intense fire conditions such as can be caused by a strong
draft which is in turn can be caused by a tall chimney. It is interesting to note that the
chimney in this home is tall (approximately 21 feet total vertical rise).
This stove and a Phase I certified woodstove located in another part of the house are used
as the primary heat sources during the burning season. The owner feels that the
Waterford stove does a good job of heating the section of house in which it is located.
Three to four cords of mixed lodgepole pine and Douglas fir are burned in the stove
annually.
KF07 The Earthstove 1400 HT (Appendix A, Photograph 12) insert was installed early 1992,
and has been owned and operated by the same person. The stove is fitted with a stainless
steel flue collar and stainless steel lined flue. The refractory elements show some wear
(Appendix A, Photograph 13). The steel components of the stove are in good condition.
However, the secondary inlet tube shows some warping (Appendix A, Photograph 14).
The door gasket is in fair condition, with some degradation on the combustion side of the
glass seal.
The owner typically burns three to five cords of lodgepole pine per year. The stove is
used as the primary source of heat. The owner feels that the unit has done a great job
heating the home, and mentioned that it can easily overheat the house.
KF08 The Country T-Top woodstove (Appendix A, Photograph 15) was installed during the
1992/1993 heating season. The stove is the only source of heat for the home and is fired
continuously during the burning season. The firebox is in overall good condition. The
secondary air tubes show some flaking on their surfaces. The door gasket is in usable but
degraded condition.
The stove is used as the primary heat source for the home. The owner burns four to five
cords of lodgepole pine per winter, and is satisfied with the performance of the stove.
Table 3-2 lists the home code, stove model, and a summary of the stove condition and
usage for homes in Portland. Photographs of these stoves and degraded components are provided
in Appendix A. A narrative description for the stoves in Portland by home code (home codes
P01 through P08) follows.
27
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Table 3-2
Home Code, Model, and Condition for Portland Woodstoves
Home
P01
P02
P03
P04
P05
P06
P07
P08
Stove1
Trailblazer
Genesis 2000
Catalytic
Lopi
Answer Series
Non-Catalytic
Lopi
380-96
Non-Catalytic
Lopi
Flush Bay-96b
Catalytic
Lopi
Flex-95
Catalytic
Pacific Energy
Super 27
Non-Catalytic
Lopi
520-96
Non-Catalytic
Vermont Castings
Defiant Encore0
Catalytic
Stove Condition and Usage
Impaired
Extensive Use All Year Long
Impaired
Minimal Use during Heating Season
Normal Wear
Minimal Use during Heating Season
Normal Wear
Minimal Use during Heating Season.
Normal Wear
Minimal Use during Heating Season
Normal Wear
Extensive Use during Heating Season
Normal Wear
Extensive Use during Heating Season
Normal Wear
Regular Use during Heating Season
a All stoves were installed prior to the 1992/1993 heating season.
b Lopi Flush Bay-96 is now called Freedom.
c The Vermont Castings Defiant Encore stove was installed when stove was EPA Phase I certified.
Since the installation, the stove has been added to EPA Phase n certification list without changes
to the stove's design.
28
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P01 The Genesis 2000 (Appendix A, Photograph 16) was installed on September of 1991.
The unit has been used as the primary heat source in the home since installation and is
operated 24 hours a day. The unit is in overall fair condition. The baffle (Appendix A,
Photograph 17) and catalyst (Appendix A, Photograph 18) are operational but show
significant thermal degradation.
The stove is used as the primary source of heat in this home and is actually fired 24 hours
per day, all year long. The unit is used all year long not just in the burning season due to
the fact that the home is located at higher elevation outside the Portland metropolitan area
where the climate is cooler. The homeowner does not like to restart the stove. Hence,
even in the summer it is allowed to operate in the "dampered down" mode during the
daytime. Approximately twelve cords of wood are burned per year.
P02 The LOPI Answer series (Appendix A, Photograph 19) was installed in 1991 and has
been owned and operated by the same person. The baffle refractory is in good condition.
The firebox side and rear refractory show some degradation. The door and window
gasket are in good condition, as is the front secondary air tube. However, the support for
the front secondary air tube has degraded to the point where it has lost structural strength
(Appendix A, Photograph 20). The rear secondary air tube is partially blocked by creosote
(Appendix A, Photograph 21). The creosote buildup indicates that the unit is typically
operated with combustion air restricted (the damper shutdown). The thermal degradation
of the front secondary air tube support indicates that the unit receives most of its
combustion air though the front of the unit.
The unit is used part time by the owners who feel satisfied about the stove's ability to
heat their home. They typically burn one to two cords of mixed oak and Douglas fir per
year.
P03 The LOPI 380-96 (Appendix A, Photograph 22) was installed in October of 1992, and
owned and operated by the same person. Overall the stove is in excellent condition. It is
only used part-time during the burning season. The door and window gaskets are still in
excellent condition, as are the fire brick, fire brick hangers, and secondary air tubes.
The primary heat source for the home is a heat pump. The owner is satisfied with the
performance of the stove. One to two cords of mixed Douglas fir and birch are burned
each year.
P04 The LOPI Flushbay-96 (Appendix A, Photograph 23) was installed in 1992 by the
existing owner. It is equipped with a flexible stainless steel flue pipe at the flue collar
that leads to a solid vertical stainless steel liner. The unit's door and glass seals are in
excellent condition. The firebox refractory is in good condition. However, the secondary
air tube shows signs of warping and flaking (Appendix A, Photograph 24), but is still in
good functional condition.
29
-------
The unit is used part time by the owner who feels satisfied about the stove's ability to
heat the home. Typically, one to two cords of oak are burned per year.
P05 The LOPI Flex-95 (Appendix A, Photograph 25) was installed in November of 1990, and
has been owned and operated by the same person. The baffle refractory and baffle
supports, along with the secondary air tube, are all in good condition. The side and rear
fire brick show cracks, but no visible sign of thermal degradation. It is likely that the
cracks in the fire brick are from physical impact. The catalyst is in good operating
condition but shows fly ash accumulation. The Interam seal surrounding the catalyst has
been disturbed and dislodged in places (Appendix A, Photograph 26). This is apparently
from removing and replacing the catalyst without replacing the Interam seal.
The owner typically bums one to two cords of mixed cherry and lodgepole pine per year.
The stove is used part time during the heating season. The owner is satisfied with its
performance.
P06 The Pacific Energy Super 27 (Appendix A, Photograph 27) was installed in 1990. After
the initial installation, the stove was temporarily removed for floor repair and replaced
back into the original installation configuration. The door gasket is in good condition,
while the fire brick shows some thermal wear. The unit is in fair operational condition
except for a sagging baffle (Appendix A, Photograph 28). Although the baffle sags, there
are no visible cracks in it.
At the time of this study, the stove was the home's only source of heat. An oil furnace in
the home was not operational. The owner typically burns one to two cords per year.
However, three to four cords were burned during the study year due to the oil furnace not
being in service. The owner feels that the stove heats the home well.
P07 The LOPI 520-96 (Appendix A, Photograph 29) is in overall good condition. It was
installed in October 1992. It is used extensively during the heating season. The stove
was the only working source of heat in the home at the time of the study, and was used 24
hours a day. The door gasket and baffle are all in good condition, while the secondary air
tube shows signs of flaking (Appendix A, Photograph 30). However, the air tube is still
in good operational condition.
The owner typically burns two to three cords per winter, but burned four to five cords
during the winter of the current study because an oil furnace which is normally used was
not operational during the study period. The owner is satisfied with the heating
performance of the stove.
P08 The Vermont Castings Defiant Encore (Appendix A, Photograph 31) is in good working
condition, including the door gaskets and refractory elements. It was installed in 1989.
The unit has a top vented exhaust rising about four feet where it is connected to a terra
30
-------
cotta lined masonry chimney. The chimney cap allows rain into the chimney. The water
makes its way to the connection where it drips out into the back left corner of the stove.
The unit is used as a secondary heat source for the home. The owners indicated that they
are happy with the stove. They typically burn one to two cords of oak per year.
Out of the sixteen stoves inspected, six degraded to the point of probably impairing
emission performance. Two of these were repaired by the homeowner prior to conducting
emission testing for this study. Consequently, the emission results of this study represent
emissions from 12 units in the "normal wear" condition and from four units in a significantly
degraded condition. Because there were so many variables (burn rate, cordwood tree species,
wood moisture, chimney height, historical burning practices, and stove model) there was no clear
cause and effect relationship observed. It was, however, noted by the inspector, that in general,
routine stove maintenance had not been done and that this maintenance and/or minor repairs
would have kept all stoves in acceptable working condition.
3.2 Participate Matter Emissions
The results for each of the 43 valid one-week testing runs are summarized in Appendix C
and in Tables 3-3 through 3-6. Emissions were determined for a range of normal wood burning
practices such as occur in actual home installations. For example, week-long averages of burn
rates ranged from 0.6 dry kg of wood per hour to 2.0 dry kg of wood per hour and average wood
moisture contents ranged from 9.8% to 105.0% on a dry basis (8.9% to 51.2% on a wet basis). It
should be noted that not only are the emission results representative of the range of actual
emissions from the in-home use of woodstoves, they also represent credible mean values for each
set of conditions since they inherently average the emissions from a considerable mass of wood
combusted over numerous burn cycles during each sampling week. The amount of wood burned
over the one-week tests ranged from 77.3 kg to 517.4 kg (58.8 kg to 325.4 kg on a dry basis).
Not surprisingly, emission factors and emission rates calculated for the week-long tests
were variable. The factors ranged from 1.9 g/ dry kg to 20.8 g/dry kg and the rates ranged from
1.7 g/hr to 40.3 g/hr. There was no clear relationship between the condition of an individual
stove and its particulate emissions, hi addition, there was no clear statistical relationship (no R2
values greater than 0.9) between emission factors and either burn rate or fuel moisture for
catalytic stoves, non-catalytic stoves or for both categories combined. While it is a generally
accepted fact that lower burn rates, wet wood and degraded stoves tend to produce higher
emission factors, there were, as previously discussed, so many inherent variables that the effects
of individual parameters were unable to be determined.
Average fuel moisture, particulate emissions, burn rate and outdoor temperature are
shown in Table 3-7 for Klamath Falls and in Table 3-8 for Portland. A summary of particulate
emission results by stove grouping (catalytic, non-catalytic and all stoves) and city are presented
31
-------
Table 3-3
Individual Test Results for Klamath Falls Stoves KF01 - KF04
Home Code
Stove Model
Week
Start Date
End Date
Total Data Collection Hours
% Time Stove Burned
Avg. Stack Temp. (°F)
Avg. %O2 (Flue >100 °F)
Fuel Mass (Wet kg)
Fuel Moisture (% Dry Basis)
AWES Flow Rate (l/min)
Sample Time (mint/Cycle (min)
Indoor Ambient Temp. (°F)
Outdoor Ambient Temp. (°F)
KF01
Quadrafire
2100
Non-Catalytic
A
1 1/25/98
12/02/98
168.0
54.9
478
15.87
134.5
20.2
0.985
2/15
70
37
B
12/04/98
12/10/98
141.0
66.3
493
15.54
145.0
24.5
0.985
2/15
62
17
C
12/10/98
12/16/98
142.8
30.3
482
16.29
77.3
31.4
0.985
2/15
72
30
KF02
Pacific Energy
Super 27
Non-Catalytic
A
11/08/98
11/15/98
168.0
100.0
448
14.53
196.4
20.8
1.124
2/15
67
33
B
12/02/98
12/09/98
168.0
97.5
412
14.52
207.6
21.5
1.124
2/15
57
22
C
12/09/98
12/16/98
168.0
79.6
374
15.15
142.5
19.6
1.124
2/15
54
29
KF03"
Haughs
171E
Non-Catalytic
B
1 1/22/98
11/29/98
168.0
85.0
430
17.58
133.8
14.5
1.038
2/15
75
38
C
12/06/98
12/13/98
168.0
95.2
475
16.52
165.8
18.8
1.038
2/15
71
23
KF04"
Earthstove
1003-C
Catalytic
A
1 1/14/98
11/21/98
168.0
100.0
398
15.42
184.4
21.6
1.042
2/15
75
37
B
12/02/98
12/09/98
167.0
100.0
510
12.59
212.2
19.5
1.042
2/15
71
2
U)
to
(Continued)
-------
Table 3-3 (continued)
Individual Test Results for Klamath Falls Stoves KF01 - KF04
Home Code
Stove Model
Week
Rinse Particulate (g)
XAD-2® Particulate (g)
Filter Particulate (g)
Total Particulate (g)
(Blank Subtracted)
Fuel Mass (Dry kg)
Burn Rate (kg (Dry)/hr)
Emission Factor (g/kg (Dry))
Emission Rate (g/hr)
Concentration (mg/m3)
KF01
Quadrafire
2100
Non-Catalytic
A
91.2
57.0
139.0
287.2
111.9
1.2
7.8
9.5
395
B
163.1
41.4
102.4
343.4
116.5
1.2
8.7
10.8
466
C
39.2
6.1
29.9
75.2
58.8
1.4
4.8
6.5
221
KF02
Pacific Energy
Super 27
Non-Catalytic
A
307.2
103.0
136.3
546.5
162.6
1.0
5.7
5.5
362
B
193.6
126.4
159.6
479.6
170.9
1.0
5.1
5.3
326
C
250.5
42.9
87.7
381.1
119.1
0.9
5.5
4.9
317
KF031
Haughs
171E
Non-Catalytic
B
60.4
30.4
55.0
145.8
116.8
0.8
3.7
3.0
123
C
88.4
17.2
7.4
113.0
139.6
0.9
1.9
1.7
85
KF04'
Earths tove
1002-C
Catalytic
A
461.9
448.3
386.5
1296.7
151.6
0.9
17.5
15.8
926
B
439.7
458.8
687.7
1586.2
177.6
1.1
14.2
15.1
1,139
u>
" There are no data for week A for KF03 and week C for KF04 due to loss of sample and/or laboratory data.
-------
Table 3-4
Individual Test Results for Klamath Falls Stoves KF05 - KF08
Home Code
Stove Model
Week
Start Date
End Date
Total Data Collection Hours
% Time Stove Burned
Avg. Stack Temp. (°F)
Avg. %O2(FIue>100°F)
Fuel Mass (Wet kg)
Fuel Moisture (% Dry Basis)
AWES Flow Rate (1/min)
Sample Time (min)/Cycle
(min)
Indoor Ambient Temp. (°F)
Outdoor Ambient Temp. (°F)
KF05
Pacific Energy
Super 27
Non-Catalytic
A
1 1/08/98
11/15/98
168.0
89.7
446
16.28
137.7
10.4
1.069
2/15
75
33
B
1 1/22/98
11/25/98
78.5
96.2
404
16.73
70.7
9.8
1.069
2/15
74
40
C
12/08/98
12/15/98
168.0
91.1
470
15.71
172.2
11.3
1.069
2/15
63
28
KF06
Waterford
104.MKII
Non-
Catalytic
Aa
1 1/10/98
11/17/98
168.0
100.0
431
16.00
126.0
11.7
1.145
2/15
77
35
KF07
Earthstove 1400HT
Non-Catalytic
A
1 1/08/98
1 1/16/98
168.3
99.7
424
16.72
158.5
12.6
1.109
2/15
75
33
B
11/22/98
1 1/29/98
168.0
95.4
457
16.83
133.7
11.7
1.109
2/15
70
38
C
12/06/98
12/13/98
168.0
98.7
484
15.64
225.4
15.8
1.109
2/15
74
23
KF08
Country T-Top
Non-Catalytic
A
11/08/98
11/15/98
168.0
100.0
384
16.47
238.4
26.8
1.058
2/15
79
33
B
11/22/98
11/30/98
172.8
98.3
428
17.48
237.1
25.4
1.058
2/15
75
38
C
12/05/98
12/13/98
171.0
99.7
446
16.08
257.7
25.7
1.058
2/15
74
21
(Continued)
-------
Table 3-4 (continued)
Individual Test Results for Klamath Falls Stoves KF05 - KF08
Home Code
Stove Model
Week
Rinse Particulate (g)
XAD-2* Particulate (g)
Filter Particulate (g)
Total Particulate (g)
(Blank Subtracted)
Fuel Mass (Dry kg)
Burn Rate (kg (Dry)/hr)
Emission Factor (g/kg (Dry))
Emission Rate (g/hr)
Concentration (mg/m3)
KF05
Pacific Energy
Super 27
Non-Catalytic
A
147.4
92.4
69.0
308.8
124.7
0.8
5.2
4.3
240
B
128.1
24.6
41.3
194.0
64.4
0.9
7.2
6.1
300
C
74.0
49.6
68.7
192.3
154.7
1.0
2.8
2.8
147
KF06
Waterford
104.MKII
Non-Catalytic
A"
214.0
83.1
157.6
454.6
112.8
0.7
6.0
4.0
295
KF07
Earthstove 1400HT
Non-Catalytic
A
265.6
123.0
233.3
621.9
140.8
0.8
9.9
8.3
418
B
202.2
103.7
154.0
459.9
119.7
0.7
7.9
5.9
324
C
313.1
93.1
232.5
638.7
194.7
1.2
8.2
9.7
434
KF08
Country T-Top
Non-Catalytic
A
313.5
95.3
153.2
561.9
188.0
1.1
8.9
9.9
395
B
236.4
26.2
342.0
604.5
189.0
1.1
12.3
13.6
421
C
212.0
65.5
89.0
366.5
205.0
1.2
5.2
6.3
254
u>
' There are no data for weeks B and C for KF06 due to death in the family.
-------
Table 3-5
Individual Test Results for Portland Stoves P01 - P04
Home Code
Stove Model
Week
Start Date
End Date
Total Data Collection Hours
% Time Stove Burned
Avg. Stack Temp. (°F)
Avg. %O2 (Flue >100 °F)
Fuel Mass (Wet kg)
Fuel Moisture (% Dry Basis)
AWES Flow Rate (1/min)
Sample Time (min)/Cycle (min)
Indoor Ambient Temp. (°F)
Outdoor Ambient Temp. (°F)
P01
HES Trailblazer
2000-C
Catalytic
A
01/11/99
01/19/99
171.3
100.0
413
14.66
260.2
24.0
1.058
2/15
80
47
B
01/19/99
01/26/99
168.3
100.0
443
14.44
252.9
21.0
1.058
2/15
71
42
C
01/26/99
02/02/99
168.0
100.0
457
13.90
258.9
22.8
1.058
2/15
72
45
P02
LOPI
Answer Series
Non-Catalytic
A
01/13/99
01/20/99
168.0
54.9
311
18.13
117.6
101.2
1.124
2/15
76
48
B
01/20/99
01/27/99
166.8
68.8
339
16.50
103.3
18.5
1.124
2/15
78
41
C
01/27/99
02/03/99
168.0
65.2
324
17.00
99.9
26.7
1.124
2/15
71
45
P03
LOPI
380-96
Non-Catalytic
A
01/12/99
01/19/99
168.8
20.1
356
17.65
32.5
18.3
1.069
2/15
80
48
B
01/19/99
01/26/99
168.8
35.1
370
17.89
72.8
18.3
1.069
2/15
74
42
C
01/26/99
02/02/99
168.0
40.9
367
17.76
85.4
23.3
1.069
2/15
74
45
P04
LOPI
Flushbay-96
Catalytic
A
01/13/99
01/20/99
168.3
56.6
285
17.16
83.6
18.3
1.145
2/15
77
48
B
01/20/99
01/27/99
168.0
69.6
327
16.70
130.0
18.5
1.145
2/15
75
41
C
01/27/99
02/03/99
168.0
69.5
279
17.62
91.1
18.4
1.145
2/15
75
45
O\
(Continued)
-------
Table 3-5 (continued)
Individual Test Results for Portland Stoves P01 - P04
Home Code
Stove Model
Week
Rinse Particulate (g)
XAD-2* Particulate (g)
Filter Particulate (g)
Total Particulate (g)
(Blank Subtracted)
Fuel Mass (Dry kg)
Burn Rate (kg (Dry)/hr)
Emission Factor (g/kg
(Dry))
Emission Rate (g/hr)
Concentration (mg/m3)
P01
HES Trailblazer
2000-C
Catalytic
A
428.5
262.2
625.3
1,316.0
209.8
1.2
15.0
18.4
908
B
376.7
260.2
506.5
1,143.4
209.0
1.2
12.9
16.0
803
C
682.1
230.9
385.5
1,298.5
210.9
1.3
13.5
16.9
913
P02
LOPI
Answer Series
Non-Catalytic
A
201.4
75.3
182.2
458.9
58.5
0.6
19.4
12.3
553
B
272.5
232.4
335.2
840.1
87.2
0.8
17.5
13.3
814
C
271.8
96.1
199.9
567.8
78.9
0.7
14.3
10.3
577
P03
LOPI
380-96
Non-Catalytic
A
49.0
11.9
(5.0)
55.8
27.5
0.8
5.9
4.7
192
B
81.0
14.6
13.5
109.1
61.5
1.0
7.1
7.4
215
C
85.9
23.2
1.3
110.4
69.2
1.0
5.8
5.8
188
P04
LOPI
Flushbay-96
Catalytic
A
97.4
34.5
47.9
179.8
70.7
0.7
5.4
4.0
206
B
118.2
39.3
71.2
228.7
109.7
0.9
5.0
4.7
213
C
133.7
27.4
50.7
211.8
77.0
0.7
5.9
3.9
198
U)
-J
-------
Table 3-6
Individual Test Results for Portland Stoves P05 - P08
Home Code
Stove Model
Week
Start Date
End Date
Total Data Collection Hours
% Time Stove Burned
Avg. Stack Temp. (°F)
Avg. %O2 (Flue >100 °F)
Fuel Mass (Wet kg)
Fuel Moisture (% Dry Basis)
AWES Flow Rate (1/min)
Sample Time (min)/Cycle (min)
Indoor Ambient Temp. (°F)
Outdoor Ambient Temp. (°F)
P05
LOPI
Flex-95
Catalytic
A
01/14/99
01/21/99
167.3
12.0
334
18.50
48.6
19.3
1.038
2/15
73
48
B
01/22/99
01/29/99
168.0
19.9
403
18.12
32.7
19.0
1.038
2/15
72
42
C
01/30/99
02/06/99
168.0
20.1
372
18.32
38.1
19.0
1.038
2/15
70
44
P06
Pacific Energy
Super 27
Non-Catalytic
A
01/23/99
01/30/99
168.0
82.7
475
15.52
412.5
100.8
1.042
2/15
71
42
B
01/30/99
02/06/99
168.0
84.5
464
15.55
373.1
105.0
1.042
2/15
69
44
C
02/07/99
02/14/99
166.8
91.6
485
14.07
351.7
101.2
1.042
2/15
72
41
P07
LOPI
520/96
Non-Catalytic
A
01/20/99
01/27/99
168.0
100.0
348
15.14
487.2
101.2
1.109
2/15
69
41
B
01/27/99
02/03/99
168.0
100.0
327
15.14
517.4
105.0
1.109
2/15
69
45
C
02/03/99
02/10/99
168.0
100.0
342
14.13
406.1
24.8
1.109
2/15
71
41
P08'
Vermont Castings
Defiant Encore
Catalytic
A
01/22/99
01/29/99
133.3
98.3
343
16.93
211.8
24.8
1.078
2/15
71
42
B
01/29/99
02/05/99
97.8
38.4
383
16.72
76.2
25.0
1.078
2/15
74
44
U)
oo
(Continued)
-------
Table 3-6 (continued)
Individual Test Results for Portland Stoves P05 - P08
Home Code
Stove
Week
Rinse Particulate (g)
XAD-2* Particulate (g)
Filter Particulate (g)
Total Particulate (g)
(Blank Subtracted)
Fuel Mass (Dry kg)
Burn Rate (kg (Dry)/hr)
Emission Factor (g/kg (Dry))
Emission Rate (g/hr)
Concentration (mg/m3)
P05
LOPI
Flex-95
Catalytic
A
37.6
6.0
-15.5
28.1
40.7
2.0
7.0
14.3
169
B
51.8
3.9
-5.7
50.0
27.5
0.8
6.4
5.3
180
C
19.2
6.4
6.4
32.0
32.0
0.9
4.4
4.2
114
P06
Pacific Energy
Super 27
Non-Catalytic
A
233.0
69.2
286.2
588.3
205.4
1.5
9.1
13.5
508
B
284.5
355.7
322.6
962.8
182.0
1.3
14.7
18.9
813
C
313.0
109.3
362.8
785.1
174.9
1.1
8.7
10.0
616
P07
LOPI
520/96
Non-Catalytic
A
334.2
326.3
974.1
1634.6
242.2
1.4
18.4
26.6
1,097
B
407.6
313.1
916.5
1637.2
252.4
1.5
18.5
27.7
1,099
C
503.1
367.9
1238.7
2109.7
325.4
1.9
20.8
40.3
1,416
P08'
Vermont
Castings
Defiant Encore
Catalytic
A
370.8
182.7
252.9
806.4
169.8
1.3
17.7
23.0
714
B
105.0
33.9
73.4
212.3
61.0
1.6
15.5
25.2
657
* There are no data for week C for P08 due to loss of sample data.
-------
Table 3-7
Average Fuel Moisture, Particulate Emissions, Burn Rate, and Outdoor
Temperature for Stoves in Klamath Falls
Home
Code
KF01
KF02
KF03
KF04"
KF05
KF06
KF07
KF08
All
Stoves
Catalytic
Stoves
Non-
Catalytic
Stoves
Number
of Runs
3
3
2
2
3
1
3
3
20
2
18
Fuel
Moisture
%
(Dry Basis)
25.37 + 4.61
20.63 ± 0.78
16.55
20.55
10.55+0.62
11.70
13.37 ±1.76
25.97 + 0.60
18.68 ±6.09
20.55
18.47 + 6.38
Average
Burn Rate
kg (Dry)/hr
1.27 + 0.09
0.97+0.05
0.85
1.00
0.90 ± 0.08
0.70
0.90 + 0.22
1.13+0.05
1.00 ±0.19
1.0
0.99 ±0.19
Emission
Factor
g/kg(Dry)
7.10 + 1.67
5.43 ± 0.25
2.80
15.85
5.07 ±1.80
6.00
8.67 + 0.88
8.80 ±2.90
7.43 ± 3.73
15.9
6.49 ± 2.53
Emission
Rate
g/hr
8.93 + 1.80
5.23 ± 0.25
2.35
15.45
4.40 ±1.35
4.00
7.97 + 1.57
9.93 + 2.98
7.45 ±3. 94
15.5
6.56 + 3.06
Outdoor"
Temperature
°F
28+4
n=22
28 ±7
n=24
31+5
n=16
30 ±7
n=16
34 ±4
n=20
35 ±5
n=8
31±5
n=25
31+4
n=24
31±2
n=155
30 ±3
n=16
31+2
n=139
" Catalytic Stove
b The outdoor temperature is the average of the high and low for each day over the sample period.
The value "n" is the number of days averaged over the sample period.
Values are followed by "± Standard Deviation".
40
-------
Table 3-8
Average Fuel Moisture, Particulate Emissions, Burn Rate, and Outdoor
Temperature for Stoves in Portland
Home
Code
P01"
P02
P03
P04'
P05'
P06
P07
P08"
All Stoves
Catalytic
Stoves
Non-
Catalytic
Stoves
Number
of Runs
3
3
3
3
3
3
3
2
23
11
12
Fuel
Moisture
%
(Dry Basis)
22.60 ±1.23
48.80 ± 37.20
19.97 ± 2.36
18.40 ±0.08
19.10 ±0.14
102.33 ±1.89
77.00 ± 36.94
24.90
42.37 ± 35.77
20.92 ± 2.59
62.03 ± 40.47
Average
Burn Rate
kg (Dry)/hr
1.23 ±0.05
0.70 ± 0.08
0.93+0.09
0.77± 0.09
1.23 ±0.54
1.30 + 0.16
1.60 ±0.22
1.45
1.14 + 0.38
1.15 ±0.38
1.13 ±0.37
Emission
Factor
g/kg(Dry)
13.80 ±0.88
17.07 + 2.10
6.27 + 0.59
5.43 ± 0.37
5.93 + 1.11
10.83 + 2.74
19.23 ±1.11
16.60
11. 69 ±5.42
9.88 ±4.78
13.35 ±5.44
Emission
Rate
g/hr
17. 10 ±0.99
11.97 ±1.25
5.97 ±1.11
4.20 + 0.36
7.93 ±4.52
14.13 ±3.66
3 1.53 ±6.22
24.10
14.20 ± 9.30
12.35 ±7.80
15.90 ± 10.20
Outdoor"
Temperature
°F
45 ±4
n=25
45 ±4
n=24
45+4
n=24
45 ±4
n=24
44+4
n=24
42 ±3
n=24
43+3
n=24
43 ±4
n=16
44±1
n=185
44±1
n=89
44±1
n=96
' Catalytic Stove
b The outdoor temperature is the average of the high and low for each day over the sample period.
The value "n" is the number of days averaged over the sample period.
Values are followed by "± Standard Deviation".
41
-------
in Table 3-9. One significant result of this study is the difference in average emissions between
stoves tested in Portland and Klamath Falls. On the average, emission factors and emission rates
for stoves in Portland (11.69 g/kg and 14.20 g/hr, respectively) were considerably higher than for
stoves in Klamath Falls (7.43 g/kg and 7.45 g/hr, respectively). This observation is consistent
with the fact that the moisture was more than two times higher, on the average, for wood burned
in Portland than for wood burned in Klamath Falls. In addition, the differences are consistent
with the fact that the burn rates for woodstoves in Portland were, on the average, slightly higher
than for woodstoves in Klamath Falls. The increased burn rate would tend to make the
differences between emission rates relatively higher than emission factors for the two cities as
seen in the values of the two cities. (Higher burn rates tend to decrease emission factors but
increase emission rates.)
A comparison of average particulate emission factors for study stoves with U.S. EPA
emission factor values tabulated in AP-42 (14) is provided in Table 3-10. A key finding of this
study is illustrated in the table. The average emission factors for the old catalytic and non-
catalytic stoves (10.8 g/kg and 9.23 g/kg) evaluated in this study were higher than the respective
emission factors (8.1 g/kg and 7.3 g/kg) for newer units of both types listed in AP-42, but were
lower than the emission factor listed in AP-42 for conventional uncertified stoves (15.3 g/kg). In
other words, particulate emissions of the certified stoves evaluated in this study appear to have
become higher with use. but after about seven years they still on the average have lower
emissions than uncertified conventional stoves.
A comparison of current and past emission factors for the two stoves in Klamath Falls
that were part of earlier studies is provided in Table 3-11. Fuel type, fuel moisture, burn rates
and the number of week-long tests used to calculate the mean emission factors for current and
past studies are also included in the table for comparison purposes. As can be seen, the emission
performance of the stove in home KF02 degraded with time. The emission performance of the
stove in home KF03 in the current study remained about the same as reported in the 1991/1992
heating season study. However, the emission factor for the same stove in the 1989/1990 heating
season study was higher than for either of the two later studies. The higher emission factor in the
1989/1990 study cannot be readily explained. However, it is probably simply a reflection of the
variability often seen in woodstove emissions when different fuels are burned and different
burning patterns are used.
A comparison between average emission rates based on multiple week-long tests for each
stove and the U.S. EPA certification value for each model is provided in Table 3-12. Another
key finding of this study is that there is no correlation between actual emission rates of older
stoves and their original certification value, that is, emission rates reported in the certification
process do not represent emission levels of stoves in homes after extended use.
42
-------
Table 3-9
Summary of Participate Emission Results
Klamath Falls
Portland
Overall Study
Stove Group
All Stoves
(8 Stoves, 20 Runs)
Catalytic Stoves
(1 Stove, 2 Runs)
Non-Catalytic Stoves
(7 Stoves, 18 Runs)
All Stoves
(8 Stoves, 23 Runs)
Catalytic Stoves
(4 Stoves, 11 Runs)
Non-Catalytic Stoves
(4 Stoves, 12 Runs)
All Stoves
(16 Stoves, 43 Runs)
Catalytic Stoves
(5 Stoves, 13 Runs)
Non-Catalytic Stoves
(11 Stoves, 30 Runs)
Average
Fuel Moisture"
%
(Dry Basis)
18.68 ±6.09
20.55
18.47 ±6.38
42.37 ± 35.77
20.92 ± 2.59
62.03 ±40.47
3 1.35 ±29.00
20.86 ± 2.42
35.89 ±33.69
Burn Rate
kg (Dry)/hr
1.00 ±0.19
1.0
0.99 ±0.19
1.14±0.38
1.15 ±0.38
1.1 3 ±0.37
1.07 ±0.31
1.12±0.36
1.05 ±0.29
Emission Factor
g/kg (Dry)
7.43 ± 3.73
15.9
6.49 ± 2.53
11. 69 ±5.42
9.88 ±4.78
13.35 ±5.44
9.71 ±5.17
10.80±4.94
9.23 ± 5.20
Emission Rate
g/hr
7.45 ± 3.94
15.5
6.56 ± 3.06
14.20 ±9.30
12.35 ±7.80
15.90 ±10.20
11. 06 ±8.05
12.83 ±7.26
10.30 ±8.26
Outdoor
Temperature °F
31±2
n=155
30 ±3
n=16
31±2
n=139
44 ±1
n=185
44 ±1
n=89
44 ±1
n=96
37 ±8
n=340
41±6
n=105
36 ±8
n=235
* Values are followed by "± Standard Deviation".
-------
Table 3-10
Comparison of Average Participate Emission Factors (5H Adjusted) to
AP-42 Values
>•>
•a
&
r-l
•^1
=1
•<
Stove Group
All Stoves
(16 Stoves, 43 Runs)
Catalytic Stoves
(5 Stoves, 13 Runs)
Non-Catalytic Stoves
11 Stoves, 30 Runs)
Catalytic
Non-Catalytic
Conventional
Measurement Technique
AWES Sampler
AWES Sampler
AWES Sampler
AWES and VPI Sampler"
AWES and VPI Sampler"
[ AWES and VPI Sampler"
Method 5H Equivalent
Emission Factor"
g/kg (Dry)
9.71
10.80
9.23
8.1
7.3
15.3
'' Reference 14.
h The VPI sampler is a sampling train consisting of: a condensate trap, dual filter pack, DrieRite dessicant
trap, and evacuated canister developed by Jaasma, et al., at the Virgina Polytechnic Institute and State
University.
44
-------
Table 3-11
Comparison of Particulate Emission Factors of Stoves in Current Study
to Particulate Emission Factors for the Same Stoves from Previous Studies
Home Code/
Stove Model
KF02
Pacific Energy
Super 27
Non-Catalytic
KF03
Haughs
171E
Non-Catalytic
Study
Current
EMRC"
Current
BPAb
WHAC
Heating
Season
1998/1999
1989/1990
1998/1999
1991/1992
1989/1990
Fuel
Ponderosa
Red Fir
95% Lodgepole
5% Juniper
Douglas Fir
Lodgepole
Juniper
Fuel Moisture
% (Dry Basis)"
20.63 ±0.78
16.9 ±0.63
16.55
13.9
16.3
Burn Rate
kg (Dry)/hr
0.97 ± 0.05
1.21 ±0.24
0.85
1.15
0.88
Emission Factor
g/kg (Dry)
5.43 ±0.25
(n=3)
2.78 ±0.10
(n=4)
2.80
(n=2)
2.77
(n=l)
7.0
(n=2)
"Reference 13.
"References.
'Reference 12.
d Values are followed by "± Standard Deviation".
-------
Table 3-12
Comparison of Stove Particulate Emission Rates to U.S. EPA Certification
Values3
Home Code
KF01
KF02
KF03
KF04
KF05
KF06
KF07
KF08
P01
P02
P03
P04
P05
P06
P07
P08
Stove Model
Quadrafire 2100
Pacific Energy Super 27
Haughs 171E
Earthstove 1003-C
Pacific Energy Super 27
Waterford 104.MKH
Earthstove 1400HT
Country T-Top
HES Trailblazer 2000-C
LOPI Answer Series
LOPI 380-96
LOPEFlushbay-96b
LOPI Flex-95
Pacific Energy Super 27
LOPI 520/96
Vermont Castings
Defiant Encore0
Catalytic
No
No
No
Yes
No
No
No
No
Yes
No
No
Yes
Yes
No
No
Yes
Number
of Runs
3
3
2
2
3
1
3
3
3
3
3
3
3
3
3
2
Emission Rate (g/hr)
Study
Average*
8.93 ± 1.80
5.23 ± 0.25
2.35
15.45
4.40 ±1.35
4.00
7.97 ±1.57
9.93 ± 2.98
17. 10 ±0.99
11.97 ±1.25
5.97 ±1.11
4.20 ± 0.36
7.93 ±4.52
14.13 ±3.66
3 1.53 ±6.22
24.10
Certification
Value
3.6
3.4
4.5
3.7
3.4
2.9
6.6
5.7
3.1
3.3
1.9
5.2
4.1
3.4
7.4
1.6
* The certification threshold for phase 2 certified catalytic stoves is 4.1 g/hr and for non-catalytic stoves is
7.5 g/hr.
b Lopi Flush Bay-96 is now called Freedom. The certification value shown in the table is for the Freedom.
c The Vermont Castings Defiant Encore stove was installed when stove was EPA Phase I certified. Since
the installation, the stove has been added to EPA Phase n certification list without changes to the stove's
design.
d Values are followed by "± Standard Deviation".
46
-------
3.3 Polycyclic Organic Matter Emissions
The analytical results for 40 individual organic compounds and compound categories are
provided in Appendix D. The average emission factors and rates for these compounds and
compound categories by stove type (catalytic, non-catalytic and both combined) for Klamath
Falls stoves, for Portland stoves and for the overall study are provided in Tables 3-13,3-14, and
3-15, respectively. Among the 40 compounds and compound categories are the seven and 16
polycyclic aromatic hydrocarbons (PAH) that make up the 7-PAH and 16-PAH POM surrogates.
The seven and 16 PAH compounds' emissions are summed and their total emissions used as
surrogates of POM. The average emission factors and rates for these two surrogates are included
in Tables 3-13, 3-14 and 3-15.
A key finding of this study is that total particulate emissions cannot be used as a surrogate
measurement for woodstove POM emissions. In comparing the average 7-PAH and 16-PAH
values between Klamath Falls and Portland shown in Tables 3-13 and 3-14, it is clear that the
POM emissions, as indicated by the surrogates, were higher for the Klamath Falls stoves than for
the Portland stoves even though the particulate emissions were higher for the Portland stoves.
This finding is significant because it has been suggested that total particulate emissions can be
used as a surrogate measurement for POM emissions, and for the New Source Performance
Standards (NSPS) for wood heaters it is noted that the same control techniques used to reduce
particulate emission are known to reduce POM emissions'4'. A possible explanation of the lack
of correlation between particulate and POM emissions is that conifer cordwood was burned
exclusively in Klamath Falls whereas a mixture of conifer and deciduous cordwood was burned
in Portland. Cordwood from conifers has a higher resin content than cordwood from deciduous
trees. Resin is chemically comprised of condensed aromatic rings, hence it is closer in structure
to POM compounds then cellulose or lignin. It is generally believed that, if all else is equal, the
higher the aromatic compound content in a fuel the more POM emissions will be produced upon
its combustion. In any event, this study finds that total particulate emissions cannot be used as a
surrogate for POM emissions in woodstoves although control techniques for PM may, in fact,
reduce POM.
A comparison of overall average emission factors measured in this study for the 7-PAH
and 16-PAH surrogates emitted from catalytic and non-catalytic stoves with the 7-PAH and
16-PAH emission factors listed for them in AP-42 (14) is provided in Table 3-16. The 7-PAH
and 16-PAH data for catalytic and non-catalytic stoves in AP-42 are based on laboratory (not
inhome) tests with a limited number of stoves. The AP-42 7-PAH and 16-PAH values for
catalytic stoves are based on laboratory tests on seven stoves of which only one became a phase 2
certified model. The AP-42 values for non-catalytic stoves are based on laboratory tests on five
stoves none of which became phase 2 certified. (The AP-42 7-PAH and 16-PAH values for
conventional stoves, shown in Table 3-16 for completeness, were based on laboratory tests on
one stove [40].) Residential wood combustion has been identified, based on the AP-42 emission
factors, as the single, largest source of POM nationwide (2). As can be seen in Table 3-16, the
47
-------
Table 3-13
Organic Compound Emission Factors and Rates For Stoves in
Klamath Falls Homes
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene t
2-Methylnaphthalene
1 -Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene t
Pentadecane
Acenaphthene t
Dibenzofuran
C3-alkylnaphthalenes
-luorene t
-leptadecane
Octadecane
All Stoves
Average
Emission Rate
8 Stoves
20 Runs
Hg/hr
159,922
28,460
9,702
170,260
37,900
42,070
164
45,957
80,541
161,273
0
2,987
4,970
81,892
13,813
10,739
6,292
13,441
11,825
21,069
0
1,216
9,535
6,153
6,011
0
0
All Stoves
Average
Emission
Factor
8 Stoves
20 Runs
Hg/kg (Dry)
158,134
28,394
9,613
168,964
37,708
41,994
120
46,396
81,517
156,220
0
3,017
5,039
80,967
13,763
10,722
6,259
13,403
11,819
21,160
0
1,219
9,521
6,334
6,049
0
0
Non-Catalytic
Average
Emission Rate
7 Stoves
18 Runs
fig/hr
146,381
23,284
7,761
160,703
34,891
33,527
182
36,579
68,023
121,448
0
2,545
4,271
81,767
11,540
9,703
5,757
12,070
9,417
20,895
0
1,022
8,626
6,836
5,703
0
0
Non-Catalytic
Average
Emission
Factor
7 Stoves
18 Runs
ug/kg(Dry)
144,568
23,134
7,680
158,889
34,597
33,537
134
36,852
68,792
116,622
0
2,558
4,306
80,769
11,523
9,691
5,720
12,030
9,449
21,028
0
1,027
8,602
7,038
5,755
0
0
Catalytic
Average
Emission Rate
1 Stove
2 Runs
Hg/hr
281,792
75,044
27,175
256,278
64,987
118,957
0
130,353
193,204
519,699
0
6,967
11,267
83,021
34,266
20,066
11,104
25,775
33,498
22,634
0
2,969
17,710
0
8,778
0
0
Catalytic
Average
Emission
Factor
1 Stove
2 Runs
ug/kg(Dry)
280,228
75,735
27,014
259,643
65,710
118,102
0
132,295
196,043
512,599
0
7,155
11,628
82,750
33,918
20,001
11,110
25,760
33,152
22,347
0
2,944
17,793
0
8,695
0
0
(Continued)
48
-------
Table 3-13
(Continued)
Phenanthrene t
Anthracene t
Carbazole
Fluoranthene t
Pyrenet
Benzo(a)anthracene*t
Chrysene*t
Benzo(b)fluoranthene*t
Benzo(k)fluoranthene*t
Benzo(a)pyrene*t
[ndeno(l,2,3-cd)pyrene*t
Dibenzo(a,h)anthracene*t
Benzo(g,h,i)perylene t
7-PAH
16-PAH
AH Stoves
Average
Emission Rate
8 Stoves
20 Runs
Hg/hr
26,201
4,648
0
9,185
6,482
1,592
1,739
977
142
432
0
0
0
4,882
161,587
All Stoves
Average
Emission
Factor
8 Stoves
20 Runs
jig/kg(Dry)
26,466
4,744
0
9,339
6,608
1,624
1,783
1,028
153
460
0
0
0
5,049
161,600
Non-Catalytic
Average
Emission Rate
7 Stoves
18 Runs
Hg/hr
26,086
4,532
0
9,357
6,534
1,685
1,832
974
141
440
0
0
0
5,073
160,969
Non-Catalytic
Average
Emission
Factor
7 Stoves
18 Runs
|ig/kg(Dry)
26,413
4,649
0
9,533
6,675
1,723
1,884
1,030
154
474
0
0
0
5,264
161,115
Catalytic
Average
Emission Rate
1 Stove
2 Runs
|ig/hr
27,227
5,692
0
7,643
6,015
753
897
1,004
152
361
0
0
0
3,168
167,148
Catalytic
Average
Emission
Factor
1 Stove
2 Runs
|ig/kg(Dry)
26,940
5,595
0
7,588
6,006
736
877
1,013
143
340
0
0
0
3,109
165,973
* 7-PAH
t 16-PAH
49
-------
Table 3-14
Organic Compound Emission Factors and Rates for Stoves in Portland Homes
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene t
2-Methylnaphthalene
1 -Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene t
Pentadecane
Acenaphthene t
Dibenzofuran
C3-alkylnaphthalenes
Fluorene t
rleptadecane
Octadecane
?henanthrene t
All Stoves
Average
Emission Rate
8 Stoves
23 Runs
|ig/hr
161,197
43,433
15,008
288,925
58,355
36,454
0
100,976
148,328
42,786
0
5,948
7,749
92,300
16,167
10,446
7,340
14,066
7,225
17,432
0
541
11,553
2,333
5,520
0
0
16,323
All Stoves
Average
Emission
Factor
8 Stoves
23 Runs
ug/kg(Dry)
129,649
33,818
11,813
228,837
46,327
26,559
0
79,142
116,373
28,971
0
4,575
6,068
76,911
12,566
8,625
6,043
11,449
5,433
14,950
0
423
9,348
1,545
4,433
0
0
13,556
Non- Catalytic
Average
Emission Rate
4 Stoves
12 Runs
Hg/hr
153,252
42,412
14,463
246,889
55,553
42,873
0
93,721
134,439
61,377
0
6,515
7,969
83,124
17,788
10,770
7,332
12,659
8,793
16,577
0
215
11,317
1,854
5,053
0
0
15,219
Non-Catalytic
Average
Emission
Factor
4 Stoves
12 Runs
fig/kg (Dry)
130,978
34,146
11,933
209,798
46,037
34,265
0
77,008
111,970
42,469
0
5,298
6,584
75,044
14,619
9,322
6,408
11,057
7,143
15,233
0
146
9,775
1,358
4,379
0
0
13,378
Catalytic
Average
Emission Rate
4 Stoves
11 Runs
ug/hr
169,864
44,547
15,602
334,783
61,413
29,452
0
108,890
163,480
22,505
0
5,329
7,509
102,310
14,398
10,092
7,349
15,602
5,515
18,365
0
896
11,810
2,855
6,030
0
0
17,528
Catalytic
Average
Emission
Factor
4 Stoves
11 Runs
ug/kg(Dry)
128,199
33,460
11,681
249,607
46,644
18,152
0
81,469
121,177
14,245
0
3,786
5,504
78,947
10,327
7,865
5,646
11,875
3,568
14,643
0
725
8,882
1,748
4,492
0
0
13,751
(Continued)
50
-------
Table 3-14
(Continued)
Anthracene t
Carbazole
Fluoranthene t
Pyrenet
Benzo(a)anthracene*t
Chrysene*t
Benzo(b)fluoranthene*t
Benzo(k)fluoranthene*t
Benzo(a)pyrene*t
Indeno( 1 ,2,3-cd)pyrene*t
Dibenzo(a,h)anthracene*t
Benzo(g,h,i)perylene t
7-PAH
16-PAH
All Stoves
Average
Emission Rate
8 Stoves
23 Runs
Hg/hr
3,201
0
5,752
5,230
599
659
839
166
384
0
0
0
2,648
148,946
All Stoves
Average
Emission
Factor
8 Stoves
23 Runs
ug/kg(Dry)
2,563
0
4,693
4,321
480
520
677
136
335
0
0
0
2,148
123,998
Non-Catalytic
Average
Emission Rate
4 Stoves
12 Runs
Hg/hr
2,903
0
5,530
5,159
553
606
999
168
395
0
0
0
2,722
136,501
Non-Catalytic
Average
Emission
Factor
4 Stoves
12 Runs
ug/kg(Dry)
2,494
0
4,904
4,602
438
465
805
138
367
0
0
0
2,214
122,393
Catalytic
Average
Emission Rate
4 Stoves
11 Runs
Mg/hr
3,526
0
5,993
5,307
648
717
665
165
373
0
0
0
2,567
162,523
Catalytic
Average
Emission
Factor
4 Stoves
11 Runs
ug/kg(Dry)
2,639
0
4,463
4,015
525
580
536
133
300
0
0
0
2,075
125,750
•7-PAH
t 16-PAH
51
-------
Table 3-15
Organic Compound Emission Factors and Rates for Overall Study
Toluene
•n,p-Xylene
j-Xylene
Phenol
Benzofiiran
C3-alkylbenzenes
Decane
5-Cresol
•n,p-Cresol
C4-alkylbenzenes
Jndecane
Z-Ethylphenol
2,3-Dimethylphenol
Naphthalene t
2-Methylnaphthalene
1 -Methylnaphthalene
Biphenyl
Tetradecane
C2-alky [naphthalenes
Acenaphthylene t
'entadecane
Acenaphthene t
Dibenzofuran
23 -alkylnaphthalenes
'luorene t
leptadecane
Octadecane
'henanthrene t
All Stoves
Average
Emission Rate
16 Stoves
43 Runs
Hg/hr
160,559
35,946
12,355
229,593
48,128
39,262
82
73,466
114,435
102,030
0
4,468
6,360
87,096
14,990
10,593
6,816
13,754
9,525
19,251
0
879
10,544
4,243
5,766
0
0
21,262
All Stoves
Average
Emission
Factor
16 Stoves
43 Runs
ug/kg(Dry)
143,891
31,106
10,713
198,901
42,018
34,276
60
62,769
98,945
92,595
0
3,796
5,553
78,939
13,165
9,673
6,151
12,426
8,626
18,055
0
821
9,435
3,939
5,241
0
0
20,01 1
Non-Catalytic
Average
Emission Rate
11 Stoves
30 Runs
CS/hr
149,816
32,848
11,112
203,796
45,222
38,200
91
65,150
101,231
91,413
0
4,530
6,120
82,445
14,664
10,237
6,544
12,364
9,105
18,736
0
618
9,972
4,345
5,378
0
0
20,653
Non-Catalytic
Average
Emission
Factor
11 Stoves
30 Runs
ug/kg(Dry)
137,773
28,640
9,807
184,343
40,317
33,901
67
56,930
90,381
79,545
0
3,928
5,445
77,907
13,071
9,506
6,064
11,544
8,296
18,130
0
587
9,189
4,198
5,067
0
0
19,895
Catalytic
Average
Emission Rate
5 Stoves
13 Runs
Hg/hr
225,828
59,796
21,389
295,530
63,200
74,205
0
119,622
178,342
271,102
0
6,148
9,388
92,666
24,332
15,079
9,227
20,689
19,507
20,500
0
1,933
14,760
1,428
7,404
0
0
22,378
Catalytic
Average
Emission
Factor
5 Stoves
13 Runs
ug/kg(Dry)
204,213
54,598
19,347
254,625
56,177
68,127
0
106,882
158,610
263,422
0
5,471
8,566
80,849
22,123
13,933
8,378
18,818
18,360
18,495
0
1,834
13,338
874
6,594
0
0
20,345
(Continued)
52
-------
Table 3-15
(Continued)
Anthracene t
Carbazole
•Huoranthene t
>yrenet
3enzo(a)anthracene*t
Chrysene*t
3enzo(b)fluoranthene*t
3enzo(k)fluoranthene*t
Jenzo(a)pyrene*t
ndeno( 1 ,2,3-cd)pyrene*t
)ibenzo(a,h)anthracene*t
3enzo(g,h,i)perylene t
7-PAH
16-PAH
All Stoves
Average
Emission Rate
16 Stoves
43 Runs
ug/hr
3,924
0
7,468
5,856
1,095
1,199
908
154
408
0
0
0
3,765
155,267
All Stoves
Average
Emission
Factor
16 Stoves
43 Runs
ug/kg(Dry)
3,654
0
7,016
5,465
1,052
1,152
852
144
398
0
0
0
3,598
142,799
Non-Catalytic
Average
Emission Rate
11 Stoves
30 Runs
Hg/hr
3,717
0
7,443
5,847
1,119
1,219
987
155
418
0
0
0
3,897
148,735
Non-Catalytic
Average
Emission
Factor
11 Stoves
30 Runs
ug/kg(Dry)
3,572
0
7,218
5,639
1,080
1,175
918
146
421
0
0
0
3,739
141,754
Catalytic
Average
Emission Rate
5 Stoves
13 Runs
ug/hr
4,609
0
6,818
5,661
701
807
835
158
367
0
0
0
2,868
164,835
Catalytic
Average
Emission
Factor
5 Stoves
13 Runs
ug/kg(Dry)
4,117
0
6,025
5,010
631
729
774
138
320
0
0
0
2,592
145,861
* 7-PAH
t 16-PAH
53
-------
Table 3-16
Comparison of POM Emission Factors for Stoves in Current Study
to AP-42 POM Emission Factors
PAH Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene*
Benzo(a)pyrene*
Benzo(b)fluoranthene*
Benzo(g,h,i)perylene
Benzo(k)fluoranthene*
Chrysene*
Dibenzo(a,h)anthracene*
Fluoranthene
Fluorene
Indeno( 1 ,2,3-cd)pyrene*
Naphthalene
Phenanthrene
Pyrene
7-PAH Total
16-PAH Total
Catalytic Stoves
Current
Study
g/kg
(Dry)
0.002
0.018
0.004
0.001
0.000
0.001
0.000
0.000
0.001
0.000
0.006
0.007
0.000
0.081
0.020
0.005
0.003
0.146
AP-42
g/kg(Dry)
0.003
0.034
0.004
0.012
0.002
0.002
0.001
0.001
0.005
0.001
0.006
0.007
0.002
0.093
0.024
0.005
0.025
0.202
Non-Catalytic Stoves
Current
Study
g/kg(Dry)
0.001
0.018
0.004
0.001
0.000
0.001
0.000
0.000
0.001
0.000
0.007
0.005
0.000
0.078
0.020
0.006
0.003
0.142
AP-42
g/kg(Dry)
0.005
0.016
0.004
<0.001
0.003
0.002
0.010
<0.001
0.005
0.002
0.004
0.007
0.010
0.072
0.059
0.004
0.024
0.205
Conventional Stoves
Current
Study
g/kg(Dry)
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
AP-42
g/kg(Dry)
0.005
0.106
0.007
0.010
0.002
0.003
0.002
0.001
0.006
0.000
0.010
0.012
0.000
0.144
0.039
0.012
0.022
0.359
nd - No Data
* 7-PAH Subset Compounds
54
-------
average 7-PAH and 16-PAH emission factors for a total of 16 older phase 2 certified stoves
tested for a total of approximately 43 weeks under actual in-home usage were lower than
corresponding AP-42 values. This suggests that estimates of national emissions of 7-PAH and
16-PAH from woodstoves are too high and new emission factors for AP-42 should be developed.
55
-------
Section 4.0
Conclusions
Out of the 16 stoves inspected all showed the effects of use. However, only six were
degraded to the point that it was speculated that their condition would significantly affect air
emissions. Routine maintenance or minor repairs could have kept all units in good operating
condition if they had been done.
An extensive data base was developed from the 43 week-long test runs on 16 homes in
the two cities of Klamath Falls and Portland. No direct statistical correlation between emissions
and wood moisture, burn rate or stove condition could be made due to the number of variables
associated with real-world in-home use of woodstoves.
The particulate emissions for stoves in Portland homes were on the average higher than
for stoves in Klamath Falls homes. This result is consistent with the average higher fuel
moisture content and burn rate characteristics of the Portland portion of the study as compared
with the Klamath Falls portion of the study.
The particulate emission factors of the certified phase 2 stoves evaluated in this study
appear to have become higher with use, but after about seven years, on the average, they still
have lower emissions than uncertified conventional stoves.
The emission rates for phase 2 stove models reported as part of the NSPS certification
process do not represent emission levels of the same stove models in-homes after extended use.
Particulate emissions can not be used as a surrogate measure of POM emissions for
woodstoves. POM emission factors, as based on the 7-PAH and 16-PAH surrogates, determined
from the in-home use of woodstoves in this study, were lower than the POM emission factors
tabulated in AP-42.
56
-------
Section 5.0
Acknowledgments
The participation of the following people is acknowledged:
Members of the volunteer homes.
Project Officer Robert McCrillis of the U.S. Environmental Protection Agency.
Jared Sorenson of OMNI Environmental Services, Inc., for locating volunteer homes,
field sampling, and project coordination and implementation.
Richard Sparwasser of OMNI Environmental Services, Inc., for field work coordination.
Bruce Davis and Francesca Volland of OMNI Environmental Services, Inc., for
laboratory analysis and sampling support.
Andrew Scott of OMNI Environmental Services, Inc., for laboratory analysis and editing
assistance.
David McClure of OMNI Environmental Services, Inc., for project quality control/quality
assurance and manuscript reviewing.
Pam Blackburn of OMNI Environmental Services, Inc., for administrative support.
James Gillam of Ash Brothers Chimney Sweep for his involvement in locating homes in
Klamath Falls, Oregon, and replacing flue pipes of the test stoves.
57
-------
Section 6.0
References
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59
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19. Simons, C.A., Christiansen, P.D., Houck, I.E. and Pritchett, L.C., 1988, Woodstove
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21. Simons, C.A. and Jones S.K., 1989, Performance Evaluation of the Best Existing Stove
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Medford and Klamath Falls, Oregon, OMNI Environmental Services Inc. report to U.S.
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(BEST) Hybrid Woodstoves in Their Second Year of Use, OMNI Environmental
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25. Barnett, S.G. and Fields, P.G., 1991, In-home Performance of Exempt Pellet Stoves in
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Department of Environmental Quality, DOE/BP-04123-2.
26. Barnett, S.G., 1991, In-Home Performance: Comparison of a Conventional Fireplace with
a Retrofit Firecrest Masonry Insert in the Zagelow Residence, Vancouver, Washington,
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27. Barnett, S.G., 1991, In-home Evaluation of Emissions from Masonry Fireplaces and
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28. Barnett, S.G., 1992, In-home Evaluation of Emissions from a Tulikivi KTU 2100
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60
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29. Barnett, S.G., McCrillis, R.C., and Crooks, R.B., 1992, Evaluation of Emissions from
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30. Barnett, S.G., 1992, In-Home Evaluation of Emissions from a Grundofen Masonry
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62
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Appendix A
Photographs of Woodstoves
A-l
-------
Contents of Appendix A
Each stove involved in the study was inspected and photographed to document the stove's
condition and installation. A photograph of each stove is presented in this appendix. For those
stoves that showed degradation or had replacement parts, additional photographs documenting
the stove's condition have been included.
Klamath Falls Photographs
Photograph
1 KF01. Non-Catalytic Quadrafire 2100 A-4
2 KF01. Displaced Ceramic Blanket in the Non-Catalytic Quadrafire 2100 A-5
3 KF02. Non-Catalytic Pacific Energy Super 27 A-6
4 KF02. Replaced Smoke Baffle in the Non-Catalytic Pacific Energy Super 27 A-6
5 KF03. Non-Catalytic Haughs 17 IE A-7
6 KF03. Cracks in the Rear Secondary Air Ports in the Non-Catalytic Haughs 17 IE. . A-7
7 KF04. Catalytic Earthstove 1003c A-8
8 KF05. Non-Catalytic Pacific Energy Super 27 A-8
9 KF05. Degraded Baffle and Ceramic Blanket in the Non-Catalytic
Pacific Energy Super 27 A-9
10 KF06. Non-Catalytic Waterford MKH A-10
11 KF06. Degraded Baffle in the Non-Catalytic Waterford MKH A-l 1
12 KF07. Non-Catalytic Earthstove 1400HT A-12
13 KF07. Worn Refractory Elements in the Non-Catalytic Earthstove 1400HT A-12
14 KF07. Warped Secondary Inlet Tube in the Non-Catalytic Earthstove 1400HT. ... A-13
15 KF08. Non-Catalytic Country T-Top A-13
A-2
-------
Portland Photographs
Photograph
16 P01. Catalytic Trailblazer Genesis 2000 A-14
17 POL Cracked Baffle in the Catalytic Trailblazer Genesis 2000 A-14
18 POL Degraded Catalyst in the Catalytic Trailblazer Genesis 2000 A-15
19 P02. Non-Catalytic Lopi Answer Series A-15
20 P02. Degraded Support for the Front Secondary Air Tube in the Non-Catalytic
Lopi Answer Series A-16
21 P02. Creosote Deposits on the Secondary Air Tube in the Non-Catalytic
Lopi Answer Series A-16
22 P03. Non-Catalytic Lopi 380-96 A-17
23 P04. Catalytic Flush Bay-96 (Now Freedom) A-18
24 P04. Warped and Flaking Secondary Air Tube in the Catalytic Flush Bay-96 A-18
25 P05. Catalytic Lopi Flex-95 A-19
26 P05. Disturbed Catalyst Interam Seal in the Catalytic Flex-95 A-19
27 P06. Non-Catalytic Pacific Energy Super 27 A-20
28 P06. Sagging Baffle in the Non-Catalytic Pacific Energy Super 27 A-21
29 P07. NoiT-Catalytic Lopi 520-96 A-21
30 P07. Flaking Secondary Air Tube in the Non-Catalytic Lopi 520-96 A-22
31 P08. Catalytic Vermont Castings Defiant Encore A-22
A-3
-------
Photograph 1
KFO1. Non-Catalytic Quadrafire 2100.
A-4
-------
-------
Photograph 2
KF01. Displaced Ceramic Blanket in the Non-Catalytic Quadrafire 2100
A-5
-------
-------
Photograph 3
KF02. Non-Catalytic Pacific Energy Super 27.
Photograph 4
KF02. Replaced Smoke Baffle in the Non-Catalytic Pacific Energy Super 27.
A-6
-------
-------
Photograph 5
KF03. Non-catalytic Haughs 171E.
Photograph 6
KF03. Cracks in the rear secondary air ports in the non-catalytic Haughs 171E.
A-7
-------
-------
Photograph 7
KF04. Catalytic Earthstove 1003C.
Photograph 8
KF05. Non-catalytic Pacific Energy Super 27.
A-8
-------
-------
Photograph 9
KF05. Degraded baffle and ceramic blanket in the non-catalytic Pacific Energy Super 27.
A-9
-------
-------
Photograph 10
KF06. Non-catalvtic Waterford MKII.
A-10
-------
-------
Photograph 11
KF06, Degraded baffle in the non-catalytic \\aterford MKII.
-------
-------
Photograph 12
KF07. Non-catalvtic Earthstove 1400HT.
Photograph 13
KFO". Worn refracton elements in the non-catalvtie Earthstove 1400HT.
A-12
-------
-------
Photograph 14
KF07. Warped secondary inlet tube in the non-catalytic Earthstove 1400HT.
Photograph 15
KF08. Non-catalytic Country T-Top.
A-13
-------
-------
Photograph 16
P01. Catalytic Trailblazer Genesis 2000.
Photograph 17
P01. Cracked baffle in the Catalytic Trailblazer Genesis 2000.
A-14
-------
-------
Photograph 18
P01. Degraded catalyst in the Catalytic Trailblazer Genesis 2(100.
Photograph 19
P02. Non-catahtic Lopi Answer Series.
A-15
-------
-------
Photograph 20
P02. Degraded support for the front secondary air tube in the non-catalytic Lopi Answer Series.
Photograph 21
P02. Creosote deposits on the secondary air tube in the non-catalytic Lopi Answer Series.
A-16
-------
-------
Photograph 22
P03. Non-catalytic Lopi 380-96.
A-17
-------
-------
Photograph 23
P04. Catalytic Flush Bay-96 (now Freedom).
Photograph 24
P04. Warped and flaking secondary air tube in the Catahtic Flush Bay-96.
A-18
-------
-------
Photograph 25
P05. Catalytic Lopi Flex-95.
Photograph 26
P05. Disturbed catalyst interam seal in the Catalytic Fle\-95.
A-19
-------
-------
Photograph 27
P06. Non-catalytic Pacific Energy Super 27.
A-20
-------
-------
Photograph 28
P06. Sagging baffle in the non-catalytic Pacific Energy Super 27
Photograph 29
P07. Non-catalytic Lopi 520-96.
A-: i
-------
-------
Photograph 30
P07. Flaking secondary air tube in the non-catalytic Lopi 520-96.
Photograph 31
P08. Catalytic Vermont Castings Defiant Encore.
A-::
-------
-------
Appendix B
Quality Assurance History — Automated Woodstove Emission Sampler
B-l
-------
Appendix B
Quality Assurance History — Automated Woodstove Emission Sampler
1. Quality Assurance Plan for: The Northeast Cooperative Woodstove Study, Vol. n,
EPA/600/7-87-026b (NTIS PB88-140777), November 1987.
• RTI1 Review and Acceptance of Quality Assurance Plan, February 1986
• RTI Interim Audit of Data Quality, December 1986
• RTI Final Technical System and Performance Evaluation Audit, April 1987
• RTI Final Audit of Data Quality, November 1987
2. Quality Assurance Plan for: Field Performance of Advanced Technology Woodstoves in
Glens Falls, New York, 1988-1989, Vol. H, EPA/600/7-90-019b (NTIS PB91-125658),
October 1990.
• RTI Review and Acceptance of Quality Assurance Plan, December 1988
• RTI Technical Systems and Performance Evaluation Audit, February 1989
• RTI Second Performance Audit, May 1989
RTI Interim Audit of Data Quality, November 1989
3. Quality Assurance Plan for: Woodstove Emission Sampling Methods Comparability
Analysis and In-situ Evaluation of New Technology Woodstoves, EPA/600/7-89-002
(NTIS DE89-001551), January 1989.
• RTI Review and Acceptance of Quality Assurance Plan, March 1987
RTI Final Audit Report, April 1987
4. Technical system and performance evaluation audits were conducted by RTI on
automated emission sampler protocols and data for masonry heaters. Final audit reports
were completed April 1992. The audits were conducted to support the inclusion of
masonry heater data in section 1.10 of AP-42.
1 Research Triangle Institute (RTI) was under contract with the U.S. EPA to provide
independent third party quality assurance audits.
B-2
-------
Appendix C
Summary of Automated Emissions Sampler Data by Test
C-l
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location: Klamath Falls, Oregon USA
Test Run Number: Week B
Test Period Start Date/Time: 12/04/98 05:47:00 PM
Test Period End Date/Time: 12/10/98 02:32:00 PM
Stove Model Tested. KF01: Quadrafire 2100 Non-Catalytic
Stove Type: New Tech/Non-Catalytic
O
to
Time
Total Tell Period
141.00 Hounj
Slow Opening Time (le, Flue-
G»» Temperature Over 100 13 6 Hours
Degrees?)
Stove Opiri«ngjlme During
TMI Period (le. Flue-Gas
Temperature Over 100
Degrees F)
eo.J%
ESS Settings
ESS Sampling Rate O.US L/Minule
Sample Cyde Duration 15.00 Mlnutei
Sample Time Par Simple 120
Cycw
Fuel
Total Fuel Uied
Average Fuel MolMure
Total Fuel Burned
149.0 KG Wilti Moisture
24.8% Percent Dry BaiU
11M KODfy
Average Temperatures
Fkw-Ga> Temperature (at 1 loot above Hue
collar)
Test FaOUty Ambient Temperature
Particulate Emissions
Emmion Factor
Emission Rate
Concentration
4«1 Degree*F 2M DegreesC
•2 Degrees F IT DegreesC
10.1 a/Hour
4M Mg/M3
Breakdown of Particulate Sample
Rinse
XAD-2
Filter
4T.S%
12.1%
40.5%
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 15.54 Percent
Te«t Notes:
Ten Nott Number 1: Stolchlomelric Volumi Is Based on 11.5% of Futl Carbon Esnsrallng Carbon
Monoxide and U.S% of Fuel Carbon Generating Gabon Dioxide
Ten Note Number 2: STP (or this tsst It: 1.00 Atnracphire and U Degree! F (20 Degrael C)
File: Kf01-b3.123 Printed: 07/26/99 at 02:50:23 PM
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF01: Quadrafire2100 Non-Catalytic
WeekB
1000
o
8
1^
i
g
N
3
§
I
§
2
§
§
3
a.
<
g
^
i
a.
§
fi
o
d
s
Test Period
• Flue-OM Temperature
• Oxygen Concentration
File: Kf01-b3.123 Printed: 07/26/99 at 02:50:15 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location: Klamath Falls, Oregon USA
Test Run Number: Wftok B
Test Period Start Date/Time: 12/04/98 05:47:00 PM
Test Period End Date/Time: 12/10/98 02:32:00 PM
Stove Model Tested. KF01: Quadratic 2100 Non-Catalytic
Stove Type: New Tech/Non-Calalylic
n
Time
Total Tosi Period
Slove Operating Tims (ie, Flue-
Cat Tempenilurs Over tOO
Oogrees F)
Slovo Operating Time Outing
TBSI Period (K>. Flue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rale
Sample Cyclo Duration
Sample Time Per Sample
Cyclo
141.00 Hours
«3.5 Hours
„. ...
°B"""
08BS UlAnulo
15.00 UinulCS
120 Seconds
Average Temperatures
Fiu« Gas Tefiipcraiwu (
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF01: Quadrafire 2100 Non-Catalytic
WeekB
n
1000
(T
O BOO
8. 600
§
q, 400
LL
200
S
§
8
3
S
a.
9.
5?
S
§
N
y;
5
I
2
s
2
S
Test Period
8
8
I*.
§
8
S
6
s
- Flue-Gat Temperature
Oxygen Concentration
File: Kf01-b3.123 Printed: 07/26/99 at 02:52:42 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Dale/Time:
Stove Model Tested:
Klamath Falls. Oregon USA
WoekC
12/10/98 04:02:00 PM
12/16/98 02:32:00 PM
KF01: Quadraflre 2100 Non-Catalytic
Stove Type: New Tech/Non-Catalytic
n
ON
Time
Total Tost Period
142.75 Hours
Slovo Operating Time (co, Fluo-
Oas Temperature Ovor 100 43.25 Hours
Degrees f)
Stove Operation Time During
Toil Period (le,Flue-Gas
Temperature Ovor 100
Degrees F)
30.3%
ESS Settings
ESS Sampling Rato
Sarnpte Cydo Duration
Sample Time Per Sample
Cycle
O.MS UI.tmula
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at 1 loot abovo flue
collar)
Test Facility Ambient Temperature
Particulate Emissions
Emisiion Factor
Emission Rale
Concentration
482 Degrees F 250 Degrees C
72 Degrees f 22 Degree* C
4.1 G/Kg
«.S GtHajl
221 MQ/M3
Fuel
Total Fuel Died
Avarago Fuol Moisture
Total Fuel Burned
Average Bum Rate During
Slovo Operation
77.3 KGWIUlWoisturo
31.4% Percent Dry Basis
5B.B KG Dry
1.4 KG/Hour(dry)
Breakdown of Particulate Sample
Rinse
XAD-2
Filter
52.1%
8.1%
Total
100%
Average Flue-Gas Concentrations
O««jen (AWES) 1S.29 Pereenl
Test Notes:
Tost Note Number 1: Slolchlomtlrlc Volumo li Bated on 11.1% of Fuel Carbon Generating Carbon
Monoxide and BS-SV. of Fuel Carbon Generating Cation (Noidde
Te>< Note Number 2: STP lor Ihlt tin la: 1.00 Aimotphere and M D«gre»« F (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF01: Quadraflre 2100 Non-Catalytic
WeekC
1000
e
a
E
8.
.«
800
600
400
200
Z
8
i
S
8
§
s
Z
Z
§
5
T«»t Period
8
s
Z
S
I
z
§
h-
i
- Flue-Gas Temperature
- Oxygen Concentration
1
File: Kf01-c3.123 Printed: 07/26/99 at 02:52:58 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Tost Run Number:
Test Period Start Date/Time:
Test Period End Dale/Time:
Stove Model Tested:
Stove Type:
Klamath Falls. Oregon USA
Week A
11/08/98 12:01:54 PM
11/15/98 11:47:00 AM
KF02: Pacific Energy Standard 27 Non-Catalytic
New Tech/Non-Calalytic
o
CO
Time
Total Test Pencxi
Stove Operating Tana {«, Flue-
Gas Temperature Over 100
Degrees F)
Slow Operawg Time During
Tost Period (ie, Flue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Ralo
Sample Cydo Duration
Sample Time Per Sample
Cydo
1U.OO Hours
168 Hours
100.0%
1,124 bfytlnuto
15.00 Minutes
120 Seconds
Average Temperatures
Ruo-Gas Tcmperaiufo (at 1 fool aoova flue
collar)
Tosi Facility Ambient Temperature
Paniculate Emissions
Emission Factor
Emission Rale
ConcenIra lion
Ml OegreasF 231 Degrees C
•7 Degrees F II Degrees C
57 GIKg
5.5 GHour
312 M»'M3
Fuel
Total Futi UswJ
Avciago Fuel llc.slui«
Total Fuol Burned
Average Bum Rale Dunng
StoveOperalion
1M.4 KG With Moishirti
20.*% Percent Dry Basis
163.6 KG Dry
1.0 KG/Hour(dry)
Breakdown of Paniculate Sample
Rmst)
XAO-2
Filter
Total
Average Flue-Gas Concentrations
Oxygen (AWES) 14.53 Percent
Test Notes:
Tosi Noll Number 1: Stolchlomelrlc Volume Is Bmod on 11.5% of Fuel Curbon Generating Cirbon
Mononlda and SB.5% of Fuol Carbon Of ntrttlng Gabon Dloxld«
Toil Nolo Number 2: STP for this test Is: 1.00 Almoiphoro >nd 18 Digress F (20 Degrees C)
-------
l/\ld
66/92/ZO :
UO|t«J)U80UOO IWBAXQ -X
poped itsi
3 5
I i
5 S
S S
g S
2 £
£
£
•n
£
•o
s
>
g
|
en
S
u
suo|)ej)ueouoo uaBAxo
pue ejntBjaduiaj. sco-eni j
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time.
Stove Model Tested:
Stove Type:
Klamalh Falls. Oregon USA
WeekB
12/02/9809:47:00 AM
12/09/98 09:32:00 AM
KF02: Pacific Energy Standard 27 Non-Catalytic
New Tech/Non-Catalytic
O
o
Time
Total Test Period
168.00 Houis
Slow Operating Time (ie, flue-
Gas Ternperalure Over 100 163.7S Hours
Degrees F)
Stova Oporaiing Timo During
Ten Penod (w. Flue-Gas
Temperature Over 100
DerjracsF)
97.1%
ESS Settings
ESS Sampling Rato
Sampii Cycle Duration
SamplD Tirnu Per Samplo
Cydo
1.124 l/Minulo
15.00 l.lnutes
120 Soconds
Average Temperatures
Flus-Gas rcmpenturo (•" 1 'oat above Due
collar)
Tusl Faality AmCKinl Toniperaiure
Particulate Emissions
Emission Factor
Emission Rale
Concuntraiion
412 OeflrwsF 211 Degrees C
57 Degress F 14 Degrees C
S.I
S.l
126
G/Hour
MglM3
Fuel
Tobl Fuel U»ed
Avemg« Fuel l.tosluie
Total Fuel Burned
Average Bum Rat« During
Stove Operation
207.6 KGWilhUmsture
2t.SU Percent Dry Basis
170.8 KG Dry
1.0
Breakdown of Particulate Sample
Rmso
XAO-2
Filter
Total
40.4%
Z».4%
J1.3S
100%
Average Flue-Gas Concentrations
O«yg«n (AWES) 14 52 Percent
Test Notes:
T»t Note Numbor V. Siolctilo
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF02: Pacific Energy Standard 27 Non-Catalytic
WeekB
n
8
8
2
8
I
< tt.
s s
8 ?
s s
§
s
f
s
^
3
5
s
a
Q.
S
i
29
- 20
15 £.
K
10
Test Period
<> Flue-Gal Temperature
Oxygen Concentration
File: Kf02-b3.123 Printed: 07/26/99 at 02:53:54 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
WcekC
12/09/9811:02:01 AM
12/16/98 10:45:00 AM
KF02: Pacific Energy Standard 27 Non-Catalytic
New Tech/Non-Catalytic
n
>__t
to
Time
Total Tell Penod 168.00 Houre
Slow Operating Time (la, Flue-
Gas Temperature Over 100 111.79 Hours
Degrees F)
Slave OporatlngTImo During
Tetl Period (10. Flue-Gas
Temperature Over 100
Degree* F)
ESS Settings
ESS Sampling Rala
Sample Cycte Duration
Sample Time Per Sample
Cycle
1.124 Ul.dnulo
15.00 (Mules
120 Second!
Average Temperatures
Flue-Gas Temperature (al 1 fool above flue
collar)
Tost Facility Atnblonl Temperature
Particutate Emissions
Emission Factor
Emission Rate
Concentration
J74 Degnxj*F 110 DegraesC
(4 DcfireojF 12 Degrees C
IS QKg
4.» GJHcojr
317 f.t»l.t3
Fuel
ToUl Fuel Usixl
Average Fuel Moisture
Total Fuel Burned
Average Burn Rale During
Slave Operation
142.S KG With Moisture
19.t% Percent Dry Rasis
1H.1 KG Dry
0,1 KG/Hom (dry)
Breakdown of Particulate Sample
Rinse
XAO-2
Filter
Total
85.7%
11.3%
23.0%
100%
Average Flue-Gas Concentrations
Onygen (AWES) 16.1S Percent
Test Notes:
Test Not* Number 1; StolchlonMlrlc Volume It Bated on 11.1% of Fuel Carbon Generating Carbon
Monoxide and M S% o> Fuel Carbon Generating Gabon Dioxide
Test Note Number 2; STP lot uils lest It: 1.00 Aunotpheit and MOeflrMiF (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF02: Pacific Energy Standard 27 Non-Catalytic
WeekC
1000
g> too
I
g. 600
<0
400
200
o
i—*
U)
o
Pi
2
5
a
8
3
§
i
I
5
<
5
0-
|
Test Period
2
5
i
5
Q.
8
I
i
3
Flue-Gas Temperature
Oxygen Concentration
File: Kf02-c3.123 Printed: 07/26/99 at 02:54:15 PM
-------
AWES-Emissions Results
Protect Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start DateHlme:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
WeekB
11/22/98 12:01:56 PM
11/29/98 11:46:56 AM
KF03: Haughs 171E Non-Catalytic
New Tech/Non-Calalytic
n
Time
Total Test Period
Slovo Operating Time («, Fluo-
Gjs Temperaluro Ov«r 100
Degrees F)
Slovo Operating Timo During
Twl Period (ie FlwO'Gss
Temperature Ovor 100
Degrees F)
ESS Settings
ESS Sampling Ftato
Sampli) Cycle Duration
Sample Tima Per Sample
Cycta
1B8.00 Hours
142.79 Hours
1.03* L'MmuIo
1S.OO Minutes
120 Seconds
Average Temperatures
Flue-Gas Tempcratufe (at 1 fool above flue
Test Fac*ly AmOtOnl TemporalufB
Particulate Emissions
Emission Factor
Emission Rate
Concentration
430 Degrees F 221 Degrees C
7J Degrees F 24 OogreefC
3.7 G/Kg
3.0 GHour
123 MglMt
Fuel
Total Fuel Used
Ai«raoe Fuel Mo siu
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF03: Haughs 171E Non-Catalytic
WeekB
n
1000
200
a
f 3
8 8
S 3
s
3 S
i !
25
- 20
15
10
- 5
a. <
I i
? *?
Teit Period
Flue-Gas Tamperatura
- Oxygen Concentration
File: Kf03-b3.123 Printed: 07/26/99 at 02:59:12 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location;
Test Run Number:
Test Period Start Date/Time.
Test Period End Date/Time:
Stove Model Tested:
Slove Type:
Klamalh Falls. Oregon USA
WockC
12/06/98 12:17:02 PM
12/13/98 12:02:02 PM
KF03:Haughs171E Non-Catalytic
New Tech/Non-Catalytic
n
K-t
a\
Time
Total Test Peood
Stove Operating Time (IB. Flua-
Gas Temperature Over 100
Degrees F)
Stove Operating Time During
Teal Penod (ie. f iue-<3as
Temparature Ovor 100
DograesF)
ESS Settings
ESS Sampling Raw
Sample Cyclu Duration
Sample Tmio Per Sample
Cycle
111.00 Hours
110 Houn
1.0U UMmula
15.00 Minutes
120 Seconds
Average Temperatures
Flua-Gas Temperature (ni t fool above dun
collar)
Test Facility Ainbienl Temperature
Particulate Emissions
475 DeflrooaF 246 OagreosC
71 Degrees F 22 DograesC
Emission Raw
Concentration
IS G/Kg
1.7 G/Hour
tS
Fuel
Total Fua Utod
Avoraga Fuel Moisture
Total Fuel Burned
Avoraos Bum Raid Ounng
S(ov«0poration
1«S 8 KG Mm Manure
18.8% Porcsnt Dry Basis
13B.O KG Dry
0.« KQ/Hour(dry)
Breakdown of Particulate Sample
Rinse
XAO-2
Filler
7«.2%
Total
B.S%
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 11.52 Percent
Test Notes:
T««t Note Numb«t 1: Stokhlonulrtc Volume li B*itd on 11 ,S% of Fuel Cirbon GtiMrallng Carbon
Monoxldo and M.S% ef Fu«l C»rbon 0«n«rallns Cabon Dio»W«
Tail Noll Numlxf 2: STP for this usl Is: 1.00 Almotpheie and (I Oigrm F (20 Digram C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF03: Haughs 171E Non-Catalytic
WeekC
1000
£> 800
a
C
§. 600
400
200
O
t—'
-J
S
x
S
8
I
s
8
5
&
S
9
I-
5?
2
£
s
S
8
a
Test Period
- Flue-Gas Temperature
- Oxygen Concentration
File: Kf03-c3.123 Printed: 07/26/99 at 02:59:33 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
Week A
11H4/9812:32:01 PM
1V21/98 12:17:01 PM
KF04: Earthstove 1003-C
Catalytic
n
>—»
oo
Time
Total Test Period
Sieve Operating TMne fie. Flue-
Gai Temperature Over 100
Degrees F)
Stovo Operating Time Dunng
Test Period (ie, Flue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rate
Sample Cycle Duration
Sample Timo PorSampla
Cycle
168 00 Hours
1(0 Hours
1.04! UMinulo
15.00 Mmulot
120 Seconds
Average Temperatures
Flue-Cat Temperature (at 1 tool abova flue
collar)
Te>l Facility Ambtent Temperature
Paniculate Emissions
Emission Factor
tmlttion ftite
Conconlrabon
1M DonreosF 203 DeyeosC
Jt DcsroosF 24 Degree* C
17.9 G/Kg
14.9 GAHour
Fuel
Total Fuel Used
Avenge Fu
Tout Fuul Burned
Averaoe Bum Rate During
Sloi-«Operalion
1(4.4 KG Witfi Moature
21.6% Porcanl Dry Baiis
1S1.9 KG Dry
09 KG Hour (dry)
Breakdown of Paniculate Sample
Rinse
XAQ.2
Filial
34.1%
Total
Average Flue-Gas Concentrations
Oxygen (AWES) 19.42 Percem
Test Notes:
Tost Noto Number 1: Slokhlomxrlc Volume For TM* Tell ll Band on 2.0% of Fuel Carbon Generating
Carbon Monoxide and ia.0% of Fuel Carbon Generating Carbon Dioxide
Toil Not* Number 2: STP (or this left If. 1.00 Almoiphore and It Dagreil F (20 DegreMC)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF04: Earthstove 1003-C
Week A
1000
200
o
VO
a.
I
5
5
o.
5
s:
5
1^
r;
S
c
5
3
S
S -
I I
S
1
2:
-
S
80
i
s:
z
o
5
3 2
I I
is o
25
20
15
- 10
- 5
o
i
Test Period
«- Flue-Gas Temperature
-*- Oxygen Concentration
File: Kf04-a3.123 Printed: 07/26/99 at 02:59:51 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Tost Run Number:
Tost Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamalh Falls, Oregon USA
WeekB
12/02/98 12:47:00 PM
12/09/98 11:32:00 AM
KF04: Earthstove 1003-C
Catalytic
o
to
o
Time
Total Test Ponod
Stova Operating Tune lie, Flue-
Gas Temperature Over ICO
Degrees F)
Stov'a Operating Trno During
Tosi Period (ie. Flue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rats
Sample Cycle Durauon
Sample Time Per Sample
Cycle
167.00 Hours
167 Hours
100.0%
1.042 UMmute
15.09 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at t loot above flue
coil*)
Test Facility Ambtenl Temperature
Particulate Emissions
Emission Factor
Emission Raid
Concentration
510 Degrees F m Degree* C
71 Degree* F 22 Degrees C
14.2 Q/Kg
15.1 a/Hour
1191 M&U3
Fuel
Total Fuel Used
Average Fuel Moisiura
Total Fuel Burned
Aveoge Bum Rate Ounng
Stove Operation
212.2 KG With Moisture
19. JV. Pcrtonl Dry Basra
1TT.« KG Dry
1.1 KG'Hour(Ory)
Breakdown of Particulate Sample
Rinse
XAO-2
filer
27.7%
2M%
43.4%
Total
Average Flue-Gas Concentrations
Oxygen (AWES) 12.i« Porconl
Test Notes:
Test Note Number 1: Slolchlomeiric Volume For Thlt Tell It B»ed on 2.0% of Fuel Carfaon OenenUng
Carbon Monoxide and M.OK of Fuel Carbon Generating Cirbon Dioxide
Test Note Number 2: STP for this leit Is: 1.00 Almospnort and 88 Degrees F (20 Degree* C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF04: Earthstove 1003-C
WeekB
1000
« 800
s
9 600
§
LL
400
200
0
to
I
3
s
s
i
s
S
M
f?
S
a.
§
i^
i
s
«*
r-
i
i
8
3
S
a.
8
3
s
Test Period
-» Flue-Ga* Temperature
* Oxygen Concentration
File: Kf04-b3.123 Printed: 07/26/99 at 03:00:11 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamaih Falls, Oregon USA
Week A
11/08/98 12:01:54 PM
11/15/98 11:46:54 AM
KFOS: Pacific Energy Super Series-27 Non-Catalytic
New Tech/Non-Calalytic
o
to
to
Time
Total Tosi Period
ie«.00 Hours
Slave Operating Timo (m. Fluo-
G»i T«™eratune Over 100 150.7S Hours
DogreejF)
Slave Operating Time During
Teal Period (ie, Fluo-Gas .. ,..
Temperature Over 100 "J A
Dogrsos F)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample rime Per Sample
Cyclo
1.0K* UMinute
15,00 Minuies
120 Seconds
Average Temperatures
Flue-Gas Temperature (311 (cot above Hue
collar)
Test Facility AmlXenl Temperature
Particulate Emissions
Emission Factor
Emission Rate
Concentration
44* Degree* F HO D«9rc
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF05: Pacific Energy Super Series-27 Non-Catalytic
Week A
p
to
u>
1000 -
I
§
800
600
400
200
a
«o
i
O.
X
o.
a
s
(M
5 5
Test Period
2355
?. ?. ?. ?
2 5 * 5
a « * S
O O O Ci
i i I i
c c c c
Flue-Oas Temperature
Oxygen Concentration
File: Kf05-a3.123 Printed: 07/26/99 at 03:08:31 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Dato/Tlmo:
Stove Model Tested:
Stove Type:
Klamalh Falls, Oregon USA
WeekB
11/22/98 12:01:55PM
11/25/98 06:16:55 PM
KF05: Pacific Energy Super Sorlos-27 Non-Catalytic
New Tech/Non-Calalytic
n
to
Time
Foul Test Period
Stove Operating Time (lo, Run-
Gas Temperature Over 100
Degree! F)
Stove Operating Time During
Tetl Penoa (ie.Tlue-Gas
Temperature Over 100
DegroetF)
ESS Settings
ESS Sampling Rate
Sample Cycta Duration
Sample Time Per Sample
Cycle
78.SO Hours
75.S Hours
11.1%
1.0M LMnuIo
15,09 Minutes
120 Seconds
Average Temperatures
Fluo-Gas Temperature (al 1 loolabovo Hue
collar)
Tosl Facility AniMeni Tcmp«ralura
Particulate Emissions
Emission Factor
Emission Rale
Concentration
404 Doo/OosF 207 Dep/euC
74 0«greasF 23 DBgronC
7.2
(.1
100
GiHour
Fuel
Total Fuel Used
Average Fuel Muniuiu
Total Fuel Bunicd
AVCJJBO Bum Rato During
Stove Opefali on
70.7 KG Wilh Moislufo
• 8% Percent Dry Basis
«4.4 KG Dry
0,« K&Vtour(
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF05: Pacific Energy Super Series-27 Non-Catalytic
Week B
o
to
1000
U. 800
£
2
600
•= 400
200
25
20
- 15
- 10
- 5
11/22/98 12:31:55 PM 11/23/98 04:01:55 PM 11/24/98 07:31:55 PM
11/23/98 02:18:55 AM 11/24/98 05:46:55 AM 11/25/98 09:16:95 AM
Test Period
- Flue-Gas Temperature
- Oxygen Concentration
File: Kf05-b3.123 Printed: 07/26/99 at 03:08:52 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls. Oregon USA
WcekC
12/08/98 12:17:01 PM
12/15/98 12:02:01 PM
KF05: Pacific Energy Super Serlos-27 Non-Catalytic
New Tech/Non-Catalytic
n
to
o\
Time
Total Tost Poncd
Stove Operating Time (ie. Flue-
Gas Temperature Over too
Degrees F)
Stove Operating Time During
Test Period (.0 Fluo-Gjs
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rale
Sample Cycta Duration
Sartiple Time Per Sample
Cycle
1(1.00 Hours
151 Hours
1.069 l/Mirwto
15.00 Minutes
120 Seconds
Average Temperatures
Flue Gas Temperature (at 1 fool above flue
collar)
Tail Facility Ambient Temperature
Paniculate Emissions
Emission Factor
Emission fate
Concentrauon
470 Degree: F 243 Degrees C
II Degrees F 17 Degrees C
J.I G/Kg
2.1 OHour
H7 Mg/M3
Fuel
Total Fuel Usod
Total Fuel Burned
Average Bum Rale Dunng
Stove operation
172.2 KG I'.lth Moisture
11.1% Potent Dry Basis
1C4.7 KG Dry
1,0 KG/Hour(dry)
Breakdown of Participate Sample
Ruiio
XAD2
Filler
l*.f%
Total
It.TK
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 1S.71 Percent
Test Notes:
T«sl Note Number 1: Slotchkmwtrtc Volume Is a«id on 11.9% of FIM) Carbon GtmnUng Carbon
Monoildi and M.SK of Fual Carbon Generating Cabon DkucMe
Ted Note Number 2: STP for this tost l<: 1.00 Atmotphoro and 6B Oegrco F (20 DegriM C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF05: Pacific Energy Super Serles-27 Non-Catalytic
WeekC
n
to
-J
• Flue-Gas Temperature
- Oxygen Concentration
File: Kf05-c3.123 Printed: 07/26/99 at 03:09:10 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location.
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested.
Stove Type;
Klamalh Falls. Oregon USA
Week A
11/10/98 12:17:00 PM
11/17/98 12:02:00 PM
KF06: Waterford 104.MKII
New TectVNon-Calalytic
n
t^
oo
Time
Tola! Test Ponod
Stove Operating Time (la. Flue-
Gaj Temperature Over 100
Degrees F)
Stovn Operating Time During
Te»l Period (a. Flue-Gas
Temperature Over 100
DegnieiF)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample Time Per Samplo
Cycle
1M.OO Hours
1M Hours
1.145 UMInulo
1S.OO Minutes
120 Seconds
Average Temperatures
Rue-Gas Temperature (al 1 loot above flua
collar)
Tosl Faolily Ambtonl TemparaUiro
Particulate Emissions
Emission Factor
Emission Rjlo
Concenlrauon
431 DBflroasf 222 OegreilC
77 DojfucsF 21 Degrees C
•4.0 G/Hour
2»5
Fuel
Toul FUDI Used
Avataga Fu«i Moisture
Tolal Fuel Burned
Avwaoa Bum Rate During
Stove Operation
126.0 KG With Moisture
11.7% Percent Dry Basis
112.8 KG Dry
0.7 KGfHour(dry)
Breakdown of Particulate Sample
Rinse
XAO-2
Filler
Total
47.1%
18.3K
34.7%
100%
Average Flue-Gas Concentrations
Oiygen (AWES) 18,00 Percent
Test Notes:
Test Mold Number 1: Stolchlomstrlc Volume It Bated on 11.5% of Full Carbon Generating Carbon
Monculdi and 80.5% of Fuel Carbon Gdnintlng Gabon Dioxide
Test Nol« Number 2: STP (or Uils lot! It: 1.00 Atmosphere end M Degree* F (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF06: Waterford 104.MKI!
Week A
O
to
3
s
8
3
8
S
s
s
s
£
8
o.
8
8
1
8
t^
T^
s
I
I
Test Period
- Flue-Gas Temperature
- Oxygen Concentration
File: Kf06-a3.123 Printed: 07/26/99 at 03:09:27 PM
-------
AUddn Hnnli IVxhna
DWO-SKp
Atom hei|lu Hindi Alcove Deplli
2 feoi vtztical to t footfuraiMtal
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fraject No MLS-04-5
Due
LPGBt
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Purl A: Fltor
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i i
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it
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: 61
: 62
61
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6f j 72 M i
69 ; 3t 72 ,
70 • 7| 71 ; :
70 ! 1$ 73 i !
70 s 71 71 i > :
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70 i 71 i 7J !
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219 1 224 ! 22i 1 !
151 1*2 ; 163 ! i
131 ! 135 i 134 i 1
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7i : 77 71 : '
MA i NA NA i
li: ' 117 11* 1 :
l» 132 i US : i
106 ' hb ! U2 : ! i '
m IH i U5 ! '
?7 99 ' 101 • ;
19 73 94 :
129 IM 1J6
1SI 1*4 I Wt
19) i 116 199
1J4 : JJS 140 !
123 j 124 125
41 1 94 96 : :
W f 92 Mi
IO$ s lii ; 116 i 1 :
1J7 141 142 j i \
I9J (97 ' MO 1 ' '
Ii3 137 1 139 i i : ' ;
IJS I2b '•- 123 ; :
» 93 ' 95 ;
» i 91 »
123 | 1Z? »» i ;
US 149 lit |
166 I 170 172 i f *
112 13S tJ7 i j =
114 113 Hi ' i '
107 HO ; Itl : ! •
91 100 101 •
IM ; 111 111 '
1)7 : 119 120
IN j 127 121 !
I4J i 147 HI
1 1 1 l
« ' « « = ... ! ;
22* 2M j 119 f
IM = 190 1 IM i
100 • 102 i IO4
«6 ! o QO
n '• *4 « =
K6 f! M :
111 121 i JO i -
Ui 141 US = i ;
M 92 11 ! !
t u Ret- wall
~4 — -, *
f ( I : i
[I : 1
1 ' ! !
• 1 ! ! ' ! f
• I : !
S I i : ; :
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• > [ :
1
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: r
:
: -
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1 ' :
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j
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1
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; :
-
-"- : -
C-30
-------
n
U)
AWES-Emissions Results
Project Name:
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test
Time
Tola! T«il Ponod
Slova Operating Tima (a. Flue-
Gai Ternpeiature Over 100
DoflressF)
Stove Qperalinp Time During
Test Period (to. Flue-Gas
Temporaiuro Over 100
ESS Settings
ESS Sampling Ftale
Sampla Cycle Duration
Samplo Tima Per Sample
Cycle
Fuel
Tout Fu«l Used
Average Fuel Molsluru
Total Fuel Uumod
Period End Date/Time:
Stove Model Tested:
Stove Type:
16«» Hours
1(7.75 Hours
M.7%
1.101 UMmutQ
15.00 Minutes
120 Seconds
1S8.5 KG With Moisture
12.8% Percent Dry Basis
140.8 KG Dry
ERG/EPA
Klamath Falls, Oregon USA
Week A
11/08/98 12:01:54 PM
11/16/9802:32:01 PM
KF07; Earthstove 1400HT Non-Catalytic
New Tech/Non-Catalytic
Average Temperatures
FUHJ-GJS Temperaturo (all tool at>o/e due ,,A n,*.™.. c •><• ru»nw»r
fjM*r\ 4*4 wwgrpct r iziv ueo/ev*v
i.VM»f |
Tost Facility Ambient Temperature 75 Degree! F 24 Degrees C
Particulate Emissions
Emission Factor ».» G/KO
Emission Rale a.) G/Hour
Concenlraiion 418 Mg/M3
Breakdown of Particulate Sample
Rinse 42.7%
XAD2 1B.8%
FMer J7.6V.
Total "on
Average Flue-Gas Concentrations
Oxygon (AWES) 14.72 Percent
Test Notes:
Totl Nou Numb«r 1: Slolchlomotrlc Volumt li Ba$od on11.»% of Fuel Carbon Gantrallng Carbon
Monoxld* and aa.9% ol Full Carbon Generating Cibon DIoxMe
Tell Note Number 2: STP lor this lei 11>: 1.00 Atmoiphef e ano* fa Oegre«c F (20 Oegr*» C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF07: Earthstove 1400HT Non-Catalytic
Week A
1000
J» 800
3
£ 600
400
200
o
U)
to
a
f.
3
0 g
1 1
I I
Teat Period
I
S
2
s
25
- 20
is
- 10
- 5
- Flue-Ga* Temperature
- Oxygen Concentration
File: Kf07-a3.123 Printed: 07/26/99 at 03:09:53 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time'.
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
WeekB
11/22/9812:01:54PM
11/29/98 11:46:54 AM
KF07: Earthstove 1400HT Non-Catalytic
New Tech/Non-Catalytic
n
OJ
OJ
Time
Total Tail Penod
1(1.00 Hours
SIOv« Operating Tune (ic. FKie-
Gas Temperature Over 100 160.29 Hours
Degreoir)
Stovo OpsrawiQ Timo Owing
Toil Ponod (io. Flue-Gas
Tompcraluru Over 100
Degree* F)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Samplo Ttnio Fw Sample
Cycle
ii.4%
1.109 UMinuie
15.00 Minutes
120 Seconds
Average Temperatures
Fluo-Gas T&iTipcniiure (at 1 loot above fluo
collar)
Tcsi Faoiily Ambient Temperature
Particulate Emissions
Emission Factor
Emi&yon Rat6
Contenlr.ilnxi
4S7 Degress F 216 Deo/MiC
70 Degrees F 2t OogromC
7.B a/Kg
».« CVHour
324
Fuel
Tool Fuel Used
Avenge Fuel Moisture
Total Fuel Burned
Average Bum Rato During
Stovo Operation
113.7 KG Wim Maisluro
11.7% Percent Dry Bans
119.7 KG Dry
0.7 KG/Hour(dry)
Breakdown of Particulate Sample
Rinse
XAD-2
Filler
44.0%
I2.S%
Total
100%
Average Flue-Gas Concentrations
O»ygen (AWES) 1».»3 Pctconl
Test Notes:
Ton Nolt Number 1: Slo4chlomelilc Volum. ft Bittd on 11.5% of Fuel Carbon GwnraUna Ciikon
Monatlde «nd I«.S% of Fuel Carbon Generaltng C«bon Dioxide
TetI Note Number 2: STP for Ihli toil It: 1.00 Atmosphor. and e« OdgriH F (20 Degree* C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF07: Earthstove 1400HT Non-Catalytic
WeekB
n
t
OJ
1000
u._
¥
I
SL
a
3
H
800
600
400
200
a.
s
?.
10
y^
N
.
5
3
?
a>
5.
°
I I
s s
3
s
K
S
25
20
- 13
10
- s
Test Period
- Flue-Gas Temperature
- Oxygen Concentration
File: Kf07-b3.123 Printed: 07/26/99 at 03:15:51 PM
-------
AWES-Emissions Results
Prolect Name: ERG/EPA
Residence Location: Klamalh Falls, Oregon USA
Test Run Number:
Test Period Start Dale/Time:
Test Period End Dale/Time:
Stove Model Tested:
Stove Type:
WookC
12/06/98 12:01:54PM
12/13/98 11:47:28 AM
KF07: Earthstove 1400HT Non-Catalytic
New Tech/Non-Calalylic
O
u»
Ul
Time
Total Test Ported
168.00 Houis
Slavs Opcraiing Tims (la. Fluo-
Gas Temperature Over tOO 185.75 Hour*
Degrees F)
Stove OperalngTIme Ounng
Tost Penod (16. Figs-Gas
Tcmperaiuia Over 100
Degrees F)
88.7%
ESS Settings
ESS Sampling Ralo
Sample Cyde Duration
Sample Time Per Sample
Cyde
1.10* UMinulu
15.00 MtnulBS
120 Seconds
Average Temperatures
Fluo GJS Temperature (al 1 tool above flue
collar)
Test Facility AmWem Temperature
Particulate Emissions
Emission Factor
414 Degrees F 251 Oogroeg C
74 Degrees F 1) OegraeiC
Concentration
(.7 G/Hour
434 MO/M3
Fuel
Total Fuel Used
AvoraQS Fuel Mm&Ujro
Total Fuel Burned
Average Bum Hjla Ounng
StoveOporation
223.4 KG Will) Moisture
13.8% Parcunl Dry Basis
1(4.7 KG Dry
Breakdown of Particulate Sample
Rmsu
XAD-2
Filtor
Total
4«.0%
14.6%
31.4%
100%
Average Flue-Gas Concentrations
O«ygen (AWES) 15.M Percent
Test Notes:
T«t Nate Numbor 1: Stolchlomstflc Volume li Bu«d on 11.5% of Fu«l Carbon OcmnUng Carbon
Monoid* and 88.SM of Fuel Carbon Generating Cabon Dioxide
Test Note Number 2: STP tor Ink lest Is: 1.00 Atmosphere and 61 Dagraet F (20 Degree! C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF07: Earthstove 1400HT Non-Catalytic
WeekC
o
LO
O\
f
3
3
s
0.
5
5
3
s
5 5
Teit Period
- Flue-Gas Temperature
- Oxygen Concentration
3
5
c
5
s
Q
I
a
N
??
8
I
File: Kf07-c3.123 Printed: 07/26/99 at 03:16:09 PM
-------
AWES-Emissions Results
Prolect Nama: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Tesl Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
Week A
11/08/98 12:01:54 PM
11/15/98 11:46:54 AM
KFOS: Country T-Top Non-Catalytic
New Tech/Non-Catalytic
O
Time
Total Tesl Penod
Siovo Operating Time W. Flue
Gas Temperature Over 100
Degree* P)
Slavs Operating Time Ounno
Toil Period (ie Flue-Gas
Tomporalura Over 100
DeoTeesF,
ESS Settings
ESS Sampling Rate
Sample Cycle Duration
Sample Tints Per Sample
Cycle
1C8.00 Hours
1H Hours
100.0%
I.OSi UMinuto
1S.OO Minutes
120 Seconds
Average Temperatures
Flue-Gas Tcrnpomluiu (al I loot above (u8
Tesi Faoicty Ambient Tamperamro
Partlculate Emissions
Emitsion Faclor
Emift&ion Ftata
Coriccnlratdn
3M OogrMsF 1M DegreesC
7» DogrejjF 2< Degrees C
MS
Fuel
Total Fuol Used
Average Fuul Motsturo
Tola! Fuel Burned
Avenge Bum Rale During
Stove operation
238.4 KG Will. Moisture
26.8% Percent Dry Bails
11B 0 KG Dry
1.1
Breakdown of Paniculate Sample
XAD-2
Filler
55.8V.
1T.OK
27.1%
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 1&47 Percent
Test Notes:
Test Noto Number 1: SlolchlomtUlc Volume If Bisod on 11.1% of Fuel Carton Of ranting Carbon
Monoxide and M.Vk ol Fuel Carbon Gemming Gabon Dioxide
Test Noto Number 2: STP (or this lest Is: 1.00 Atmosphere and 88 Degree* f (20 Oegreee C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF08: Country T-Top Non-Catalytic
Week A
o
U)
oo
200
•s
n
rj
<
s
u>
3
T-
i
s
s:
1 i I
U>
»-
S
&
1
25
- 20
15
- 10
- 5
J
Test Period
-o Flue-Gas Temperature
- Oxygen Concentration
File: Kf08-a3.123 Printed: 07/26/99 at 03:16:28 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
WoekB
11/22/98 12:01:53PM
11/30/98 06:06:43 PM
KF08: Country T-Top Non-Catalytic
New Tech/Non-Calalytic
n
u»
VO
Time
Total Tgit Pcnod
171.75 Hoor»
Stove Oporaling Time ( Bated on 11.3% of Fuel Carbon QmiaUng Carbon
Monould* and 88.5% of Fuel Carbon Generating Cabon DIoxMe
Test Note Numbw 2: STP for this last It: 1.00 Almoiphera and 88 Degrees F (20 Degien C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF08: Country T-Top Non-Catalytic
WeekB
n
.k
o
1000
200
2
n
8
u>
a.
8
5
3
n
10
$
a.
n
»
to
^
s
a.
8
3
a.
s
u>
T^
3
I
3
8
S
8.
25
- 20
15 £.
- 10
Test Period
- Flue-Gas Temperature
- Oxygen Concentration
File: Kf08-b3.123 Printed: 07/26/99 at 03:16:45 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Dale/Time:
Stove Model Tested:
Stove Type:
Klamath Falls, Oregon USA
WeekC
12/05/98 07:24:15 PM
12/13/98 11:55:09 AM
KFOB: Country T-Top Non-Catalytic
New Tech/Non-Catalylic
n
Time
Total TMI Penod
Stova operating Tlmo (ie. Flue-
Gas Temperature Over 100
OegicglF)
Stove Operating Tim* During
Test Period (». Flue-Gas
Temperature Over 100
Oegroos F)
ESS Settings
ESS Sampling Rslo
Sample Cycle Duration
Sample Time Per Sample
Cycle
171.00 Hours
170.5 Hours
1.058 UMmuta
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at 1 toot above fluo
collar)
Tell Facility Ambient Temperature
Particulate Emissions
Emiuion Factor
Emission Rale
Concontratkxi
441 DegnxnF 230 DoflrietC
74 Degrees F 24 Dogmas C
5.2 G/Kg
«.l G/Hour
2M Mg.%43
Fuel
Total Fudl U$cd
Average Fuel MOISIUIO
Total FM«I Burned
Awrage Bum Rale During
Stove oporatton
257.7 KG Witt) Mcistum
2s.7% Porconl Dry Ba*u
20S.O KG Dry
1.2
Breakdown of Particulate Sample
Rinio
XAO-2
Filler
S7.8S
17.9%
24.3%
Total
Average Flue-Gas Concentrations
Oxygon (AWES) 10 08 Pofcent
Test Notes:
Ton Note Number 1: Stolchloroeirlc Volume It B»*d on 11.8% of Fuel Cifbon Gen«r*Ung Carbon
Mono.ldt and 8« i% of Fuel Catbon Genentlng Gabon Dioxide
Test Note Number 2: STP for this tut It: 1.00 Almosphir* and tl Degreet f (20 Degree* C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
KF08: Country T-Top Non-Catalytic
WeekC
n
.U
to
1000
I
m
^
s
s
s
8
3
a
3
I
g
s
i I
1 i
1
s
3
Test Period
• Flue-Gas Temperature
- Oxygen Concentration
File: Kf08-c3.123 Printed: 07/26/99 at 03:17:02 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
Week A
01/11/99 08:42:00 AM
01/19/99 12:17:58 PM
P01: HES Trailblazer 2000-C
Catalytic
O
Time
ToW Ttsl Period
171,25 Hours
Stove Operating Time (ie. Flue-
Gas TlltXXiralura Over 100 171.25 Hours
Degreas F)
Slovo Operating Time During
Test Period (ie, Flue-Gas 100 D%
Temporawo Over 100 10"-0%
Degrees F)
ESS Settings
ESS Sampling Rale
Samplo Cydo Duration
Sample Tlmo Per Sample
Cydo
1.051 UMnuto
15.00 Minulos
120 Seconds
Average Temperatures
FUm-Gas Temperature (at 1 tool above HIM
collar)
Test Facility Ambionl Temperature
Particulate Emissions
Emistion Factor
Emission Rala
Concentration
411 D«gr«MF 212 DtflfMSC
10 DegroatF 27 Degreas C
1S.O
18.4
90S
G/Hour
IJig.t.\3
Fuel
Total Fuel Used
Average Fuel Moisture
Total Fuel Burned
Average Bum Rale During
Slove Opera lion
200.2
24.0%
208.8
1.2
KG VViUi Moisture
Percent Dry Basis
KG Dry
KfiHour(oVy)
Breakdown of Particulate Sample
Rimo
XAD-2
Filler
Total
Average Flue-Gas Concentrations
Oiy-gen (AWES) 14.60 Percent
Test Notes:
Ten Note Numbor 1: Slolchlomelrlc Volume For This T«t Is Based on 2.0% of Fuel Carbon Gsneritlng
Carbon Monoildo «nd »B.O% of Fuel Carbon QmeraUng Carbon Dk»lde
Test Noli Number 2: STP (or (Ms test Is: 1.00 Almotphera and U Degrees F (20 Degrees C)
-------
O
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P01: HES Trallblazer 2000-C
Week A
8
S
1
i
£
8
|
!
i
5
a
si
I
S
s
5
O
Test Period
Flue-Gas Temperature
Oxygen Concentration
File: P01-A3.123 Printed: 07/26/99 at 03:32:34 PM
-------
AWES-Emissions Results
Protect Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stova Model Tested:
Stove Type:
Portland, Oregon USA
WeekB
01/19/9901:32.01 PM
01/26/99 01:32:5rPM
P01: HES Trallblazer 2000-C
Catalytic
o
Time
Total Toil Ponod
Stovo Operating Time (i«,
Flue-GJi Temporaiura Ovur
1000egr*«F)
Stove Operating Tlmo Duong
T«sl Penal (l«,TKio-Gas
Tompcfaiuro Ovor 100
Degree) F)
ESS Settings
ESS Sampling Kale
Sjinplu Cycle Duration
Sample Time Par Sample
Cyda
iet.2B Hours
U8.25 Houn
100.0%
1.051 UMinult)
19.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Tgmpenihira (ul 1 loot above flue
collar)
Test Family Amttonl Temperamra
Particulate Emissions
Emission Factor
Emission Rato
Ccnconlnition
443 OogreuF 22* Dogmas C
71 DogrcosF 22 DooraesC
U.O G'Hour
803 M0/M3
Fuel
Total Fuel Used
Average Fuol fitoisture
TgUI Fuel Burned
Avoragp Bum Rale During
Stovo operation
2i2.» KG VV.lli Moiiluiu
21,0% PQ'Ccnl Dry Basis
209.0 KOI Dry
1J KfiHouf(dry)
Breakdown of Particulate Sample
Rinse
XAD-2
Filler
32.*%
22.t%
44.1%
Total
100%
Average Flue-Gas Concentrations
O.ygon (AWES) 14.44 Pwcunl
Test Notes:
TetI Not* Number 1: StoicMometrlc Volume For Tttl* Tett Is B»ed on 2,0% of Fuel Carbon Qwienllng
Carbon Mononlde and to 0% of Fuel Carbon Generating Carbon DlaxUl
Ted Hole Number 2: STP for tWi ted It: 1.00 Atnwephere and M Oe«reee F (20 DegraM C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P01: HES Trallblazer 2000-C
WeekB
1200
n
-K
ON
s
a
i
I
c
S
3
555
Test Period
5
3
2 Z
s £
- Flu«-Gas Temperature
• Oxygen Concentration
File: P01-B3.123 Printed: 07/26/99 at 03:49:46 PM
-------
AWES-Emissions Results
Prolect Name: ERG/EPA
Residence Location: Portland. Oregon USA
Test Run Number:
Test Period Start Date/Time:
Test Period End Dale/Time:
Stove Model Tested:
Stove Type:
WeekC
01/26/99 02:47:01 PM
02/02/99 02:32:57 PM
P01: HES Trallblazer 2000-C
Catalytic
n
^
-J
Time
Total Tosl Period
Stow Operating Time (le, Flue-
Gas Tamperalura Over 100
DegrMtF)
Stov* Operating Timo Outing
Ton Period {». Flue-Gas
Temperature Over 100
Degnwf P)
ESS Settings
ESS Sampling FUilo
Sample Cycle Duration
Sainplu Tlm« Par Siimpla
Cyci*
168.00 Hours
161 Hours
100.0%
1.058 U'Minule
15.00 Minulos
120 Seconds
Average Temperatures
Flua-Gas Temperature (at 1 loot abovo DUD
collar)
Tosl Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Rala
Conccnuabon
4*7 DooraosF 1M Degrees C
72 OegreuF 22 DegroosC
13.S G/Kfl
16.9 OHour
til M»/M3
Fuel
Av«rag« Fuel M«»iu
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P01: HES Trailblazer 2000-C
WeekC
1000
n
.K
oo
s
s
s
a s? s
2 5 8
f
&
s
2
z
8
Test Period
Flue-G«a Temperature
- Oxygen Concentration
File: P01-c3.123 Printed: 07/26/99 at 03:50:21 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time;
Test Period End Dale/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
Week A
01/13/99 02:02:45 PM
01/20/99 01:47:50 PM
P02: Lop I Answer Series
New Tech/Non-Catalytic
n
^
VO
Time
Total Test Period
Slova Operating Time (10. f loo-
Gat Temperature Over 100
Degree* F)
Siova Operating Time During
Toil Period (is. Flue-Gas
Temperature Over 100
Degnsef F)
ESS Settings
ESS Sampling Rate
Sample Cycle Duration
Sample Time Par Sample
Cycta
168.00 HOUR,
12.23 Hour*
*«.»%
1.114 L'Winulo
15.00 MmuUM
120 Seconds
Average Temperatures
Flue-Gas Temperature (al 1 loot above Hue
collar)
Te»l Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Ralo
Concentration
111 Degrees F us Degree! C
76 Degrees F 24 Degree! C
1*4 G/Kg
12.3 G/Hour
333 Mg/M3
Fuel
Totiil Fuel Used
Average Fuel Moisture
Total Fuel Burned
_
Slova Operation
117.8 KG Witti Moisture
101,2% Percent Dry Basis
5B.S KG Dry
O.I KG'Hout (dry)
Breakdown of Participate Sample
Rinse
XAD-2
Filler
Total
43.«%
11.4%
39.7%
loo%"
Average Flue-Gas Concentrations
Oxygen (AWES) 1I.U Percent
Test Notes:
Tttt Note Number 1: Stolchlonnlrlc Volume Is Bated on 11.4% of Fuel Carbon Generating Carbon
Monoilde and U.SK of Full Carbon Generating Cabon Dioxide
Test Note Number 2: STP tor lni« leit It: 1.00 Abnoipneie and II Degrees f (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P02: Lopl Answer Series
Week A
o
i!/>
o
1000
8
s:
*
T!
3
2
a
s
s
i
5
i
§
a
1
3
T-
S
S
I
S
K
i
Test Period
-e- Flue-Oas Temperature
- Oxygen Concentration
25
- 20
- 15
- 10
3
8
File: P02-a3.123 Printed: 07/26/99 at 03:51:40 PM
-------
n
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location: Portland. Oregon USA
Test Run Number: Week B
Test Period Start Dale/Time: 01/20/99 02:48:21 PM
Test Period End DaleHlme: 01/27/99 02:32:52 PM
Stove Model Tested: P02: Lopl Answer Series
Stove Type: New Tech/Non-Catalytic
Time
Total Test Period 166.75 Hours
Slow Operating Time (IB. Flue-
Gas Temperature Ovof too 114.75 Hours
Degrees?)
Slow Operating Time During
Test Portoa (ie. Flue-Gas .„ ..,
TowperalureOvef 100 ™-B1*
Degrees F)
ESS Settings
ESS Sampling Kato 1.124 UUinula
Sample Cyde Duration 1>,00 Minutes
Samplo Time Por Sample m SKOnaa
Fuel
Total Fuel Used 103,1 KG Wilti Motilure
Av«fage Fud I.Wisluio U5% Percent Dry Bans
Total Pud Bumod 17.2 KG Dry
Av»rago Bum Ralo Duong „. Ktvunnrinivi
Stovotooflralion "•• KGftHour(ary)
Average Temperatures
Ftoe-G3sTompcfiHurotal1too.aOov.tluo ,„ DegrocsF 1T« Degrees C
Test Facility AmDionl Tomporaluro T> DegioejF 25 DagreosC
Participate Emissions
Emssxx) Facttx 17.5 G/Kg
Emission Ralo 13.1 G/Hour
Concentration 114 Mg/M3
Breakdown of Particulate Sample
Rinse 33.4%
XAO-2 27.7%
Filtci }«.»%
Total 100%
Average Flue-Gas Concentrations
Oxygen (AWES) 14.50 Percent
Test Notes:
Test Not* Numtnr 1: Slokhlomttrlc Volunw li Band on 11.S* of Fuel CJrtxxi OcnwaUng CarDOn
Moflould* and U.S% of Fu«l Cifbon OtneraUng Gabon Dloilda
T«sl Not* Numbir 2; STP for IMl tell It: 1.00 Alntosphtr* and M Dtgra*) f (20 DagrMf C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P02: Lopl Answer Series
WeekB
o
Lft
to
I
S
s
z
S
8
8
i
5
5
o
^
O»
8
8
in
rj
Test Period
ci
i
$
a
s
I
- Flue-Gas Temperature
- Oxygen Concentration
File: P02-b3.123 Printed: 07/26/99 at 03:51:58 PM
-------
n
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location: Portland, Oregon USA
Test Run Number: Week C
Test Period Start Date/Time: 01/27/99 03:47:00 PM
. Test Period End Date/Time: 02/03/99 03:32:51 PM
Stove Model Tested: P02: Lopi Answer Series
Stove Type: New Tech/Non-Catalylic
Time
Total Test Period 1H.OO Hour*
Slow Operating Time (io, Fluo-
GaiTomporsiuro Over 100 109.5 Hours
Degree* F)
Stovo Operating Time During
T«tP«iodp».nuo-G3* ,s™
Temperature Over 100 •"*
Degree* F)
ESS Settings
ESS Sampling Rate 1.124 1/Mmuln
Sample Cydo Duration 15.00 Mmulcs
SOTpftTirnePerSaflipl* „„ 5^^^
Fuel
ToUl Fuel Used («.9 KG With MoiMuia
Avsraju Fu.0*» Temperature (al t looUbove «u« JM p^^,, 1M o^g^c
Tosl Facility Ambient Tamporalura 71 DooroetF 22 OogrOMC
Particulate Emissions
Enuswon Factor 14.1 QKo
EmissKxi Rale 10.J G-Httur
Concwnlion SI7 Mg.
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P02: Lopl Answer Series
WeekC
o
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
WockA
01/12/99 09:17:01 AM
01/19/99 09:48:01 AM
P03: Lopl 380-96 Non-Catalytic
New Tech/Non-Catalytic
o
Time
Tola! Tcsi Penod
Stove Operating Timo (10. Flua-
Gas Temperature Over 100
Degrees F)
Stove Operating Time During
Tost Period (le. Flue-Gas
Temperature Ovor 100
Degrees F)
ESS Settings
ESS Sampling Ram
Sample Cycle Duration
Sample Time Per Sampla
Cycle
1M.7S Hours
34 Hour)
10.1%
1.068 UMnulo
1S.OO Mnulos
120 Seconds
Average Temperatures
Fluo-Gas Tempetalura (al 1 tool »t»v« Bus
collar)
Test Facility Amttont Tcmparaluru
Partlculate Emissions
Emission Factor
£m!»ston Raid
Concentration
IM Oegm«sF 110 OagnxaC
SO Degr««iF 2t DegreoiC
».B G/Kg
4,7 G/Houl
1M
Fuel
Total Fuel Died
Averago Fuol Moisture
Total Fuol BumM
Averaga Burn Raw Ounng
SlovoOperaUoo
12.5 KG wuti Moisture
10.3V. Percent Dry Basis
27.5 KG Dry
O.B KGHoor (dry)
Breakdown of Particulate Sample
XAO-2
Filler
Total
11.1%
-*.0%
INK
Average Flue-Gas Concentrations
Oxygen (AWES) 1?.«s Percent
Test Notes;
Tost Holt Number 1: StolchlomXrlc Volum* Is EUttd on 11.4% o( Fu«l Carbon Gentrallng Carbon
Monoiide and 11.1% of Pud Caibon Gunnllng Cabon Dlo«ld«
Ttil Nol. Number 2: STP foi thto Hit Is: 1.00 Atmof plure (rut M Oigrtet F (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P03: Lopi 380-96 Non-Catalytic
Week A
1000
o
u\
ON
25
20
- 15 £
- 10
- 5
f
5
5
00
f
5
5
i
Test Period
I
S
!
•s
8
S
5
1
o
§
a
3
8
?
8
i i i
5
i
i
- Flue-Oat Temperature
- Oxygen Concentration
File: P03-a3.123 Printed: 07/26/99 at 03:55:16 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
WeokB
01/19/99 11:17:10 AM
01/26/99 11:48:00 AM
P03: Lopl 380-96 Non-Catalytic
New Tech/Non-Catalytic
n
Time
ToUl Test Period
Siovo Operating Timo (la. Flua-
Gas Temperature Over 100
Degree* F)
Stove Oporaling nme During
Test Penod(i«. Rue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Raw
Sample Cycle Duration
Sample Timo Per Sample
Cycle
1W.75 Hour*
59.25 Hours
31.1%
1.0W L/Mmula
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (al 1 loo) above due
collar)
Test Facility Ambient Tomparalura
Particulate Emissions
Emission Factor
Emission Rale
Concentration
370 Degrees F III
74 Degrees F 24 Degrees C
7.1 0/Kfj
7.4 O/HOW
21S Mg.'M3
Fuel
Total Fuel Usod
Average Fuel Moisture
Tola! Fuel Burned
72.8 KG With Moisture
11.)% Percent Dry Baas
»1.5 KG Dry
Breakdown of Particulate Sample
Rinse
XAD-2
Filter
Total
74.2%
11.4%
12.4%
100%
Average Flue-Gas Concentrations
Oxygon (AWES) 17.M Percent
Test Notes:
T»f Noto Numbir 1: Sloichiomebic Volum« It Bated en 11.*% at Fuel Ctrbon Generating Caiban
Monoilde tnd M.SV. of Fuel Carbon Generating Canon Dioxide
Ted Note Number 2: STP (or tWi twl Is: 1.00 Atmosphere and «B Degrees F (20 Dlgrew C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P03: Lopl 380-96 Non-Catalytic
WeekB
n
C/l
oo
3
S
5
(M
£J
5
£
1
s
o>
c
5
a
8
ci
o
Test Period
8
3
8
«0
T^
s
3
sj
3
o- Flue-Gat Temperature
-x- Oxygen Concentration
File: P03-b3.123 Printed: 07/26/99 at 03:55:38 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
WeekC
01/26/99 12:32:01 PM
02/02/99 12:17:58 PM
P03: Lopl 380-96 Non-Catalytic
New Tech/Non-CatalyUc
n
i!/>
VO
Time
ToUM Test Period 161.00 Hours
Slov* Operating Tim* (IB, Fluo-
Gas Temperature Over 100 (8.75 Hauls
Degroo» F)
Slova Operating Tuna During
Tot* Period (ie.Tluo-Gas
Tamporalura Ovor 100
DeflrooiF)
ESS Settings
ESS Sampling Halo
Samplq Cycle Durjton
Sample Tlmo Per Sample
Cycle
40.»%
1.069 lAtnulo
1S.OO I.U/iulos
120 Seconds
Average Temperatures
Flue-Gat Temperaluio (a! 1 fool above Qua
collar)
Ta$l Facility Ambienl Temperature
Paniculate Emissions
Ml DegieatF 1M 0«grmsC
74 DuaruasF 21 Degrees C
5.8 QKg
S.1 CVHour
Conconlralion
Fuel
Tolal Fuel Used
Awraga Fuel MoiUuie
Total Fuel Bumod
Avoragg Bum Ratg During
Stove Operation
IS.4 KG Will) Moisture
23.]% Purcom Dry Basis
llJt KG Dry
1.0 K
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P03: Lopl 380-96 Non-Catalytic
WeekC
1000
o
o\
o
s
I
z
I
i
s
S
s
25
20
15
- 10
3
8
3
s
a
i^
i
3
8
g
6
Test Period
Flue-Gat Temperature
• Oxygen Concentration
File: P03-C3.123 Printed: 07/26/99 at 03:56:00 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
Week A
01/13/9911:02:01 AM
01/20/9911:02:58 AM
P04: Lopl Flushbay-96 Catalytic
Catalytic
n
Time
Total Test Period
168.25 Hours
Slow Operating Tlmo (le, Fluo-
Gas Tomporaturo Over 100 95.25 Hours
Degrees F)
Slove Operating Time During
Test Period (is, Flue-Gas
Temperature Over 100
Degrees F)
56.8%
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample Time Par Sampla
Cycle
1.145 UMnule
1S.OO Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at 1 fool above flue
collar)
Test Facility Aniblonl Temperature
Participate Emissions
Emission Factor
Emission Rale
Concentration
285 Degrees F 141 DogreflfC
77 Degress F 25 Degrees C
9.4 G/Kg
4.0 G/Hour
208 Mg/M3
Fuel
Total Fuel Used
Average Fuel Moisture
Total Fuel Burned
Average Bum Rate During
StoveOperallon
83.8 KG With Moisture
18.3% Percent Dry Basis
70.7 KG Dry
0.7 KG/Hour(dry)
Breakdown of Particulate Sample
Rinse
XAD-2
Filter
54.2%
11.2%
24.6%
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 17.16 Percent
Test Notes:
Tact Main Number 1: Slolchlomalric Volume For Thit Ttit It B»«d on 2.0% of Fuel Carbon Generating
Carbon Monoxide and 98.0% of Fuel Carbon Gwierillng Carbon Dloxld*
Test Noli Number 2: STP for this tost Is: 1.00 Atmosphoro and 68 D«gr»< F (20 D«grses C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P04: Lopl Flushbay-96 Catalytic
Week A
1000
o
0\
to
5
r.
5
at
£
5
S
s
X
i
^
g
Ol
u>
8
3
555
Test Period
8
a
i
9
8
3
25
- 20
- 10
8
- Flue-Gas Temperature
- Oxyyen Concentration
File: P04-a3.123 Printed: 07/26/99 at 03:56:18 PM
-------
AWES-Emissions Results
Project Namo: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
WeekB
01/20/99 01:17:00 PM
01/27/99 01.02:58 PM
P04: Lopl Flushbay-96 Catalytic
Catalytic
O
ON
Time
Total Test Period
SlOve Operating Timg (toFluo-
Gas Temperature Over 100
Oegreiu F)
Stove Operating Time During
Tosl Period (le,Flue-Gas
Temperature Ovor 100
Degree! F)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample rime Per Sample
Cycle
1(1.00 Hours
117 Hours
1.145 LAtnuM
19.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (311 tool above Due
collar)
Test Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Rale
Concentfatioo
321 DegceatF 1(4 Degrees C
79 Degrees F 24 OogrowC
».0 QKg
47 GVHour
213
Fuel
Total Fuel Used
Average Fu«f l.tas'.us
Total Fuel Burned
Average Bum Rale Ounng
Slave Opera lion
130.0 KG Wilt) Manure
11.$% Percent Dry Bi»Si&
10».7 KG Dry
I.I KGiHour(dry)
Breakdown of Particulate Sample
Rinso
XAD-2
Filler-
Total
51.7%
17.2%
31.1%
100%
Average Flue-Gas Concentrations
O«ys*n (AWES) 1«.70 Percent
Test Notes:
TMI Not* Number 1: Slolchlomatrlc Volume For This Test I* S»i»d on 2.0% of Fuel Carbon Generating
Carbon Monoilde and U.0% of Fuel Carbon OenenUno Carbon Dioxide
Tttt Note Number 2: STP for this Mil t»: 1.00 Atmotphtre and M Degree* F {20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P04: Lopl Flushbay-96 Catalytic
WeekB
n
4
1000
Q.
§
e
5
5
o
T^
«
O
S
Z
s
z
o
S
s
in
8
s
te
2
8
5
2
I
c
5
Te*t Period
-&- Flue-Gas Temperature
* Oxygen Concentration
File: P04-b3.123 Printed: 07/26/99 at 03:56:42 PM
-------
AWES-Emissions Results
Project Name; ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Portland. Oregon USA
WaekC
01/27/99 02:32:00 PM
02/03/99 02:17:58 PM
P04: Lopl Flushbay-96 Catalytic
Stove Type: Catalytic
o
0\
u\
Time
Total Test Period 1«a.OO Hours
Stove Operating Time (la, Flua-
Oat Temperature Over 100 11HJS Hours
Degrees!)
Slow OporallngTIm* Ounnrj
Ton Period (ie. Flue-Gas
Temperalure Ovor 100
Degrees F)
ESS Settings
ESS Sampling Rate)
Sample Cycle Duration
Sample Time Par Sample
Cyclu
81,5%
1.145 UMmuic
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (ai 1 foot above flue
collar)
Test Facility AmtKonl Temperature
Particulate Emissions
Emission Factor
Emission Rale
Con centra lion
lit Dogma F 117 Degrees C
T» Degrees F 14 Degress C
M
}.«
1M
Fuel
Total Fuel Used
Avorago Fud Moisture
Tata) Fuel Burned
Avorago Bum Rata Dunng
Slovoopflration
11.1 KG W,U) l.loiskiio
IS.4K Percent Dry Bans
77.0 KG Dry
0.7 KG/Hour(ary)
Breakdown of Particulate Sample
Rmso
XAO-2
Filter
•3.1%
Total
2J.»%
100K
Average Flue-Gas Concentrations
O
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P04: Lopl Flushbay-96 Catalytic
WeekC
o
6\
ON
1000
I
3
I
5
8
S*
£
o
*"I
si
s
i
e
o
r^
0)
in
S
o
<
CO
u>
1
»
s
8
Test Period
Flue-Gas Temperature
- Oxygen Concentration
File: P04-c3.123 Printed: 07/26/99 at 03:57:01 PM
-------
AWES-Emissions Results
Prolect Name: ERG/EPA
Residence Location:
Test Run Number:
Tesl Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland. Oregon USA
Week A
01/14/99 09:33:02 AM
01/21/99 08:32:58 AM
P05: Lopl Flex-95 Catalytic
Catalytic
O
Time
Total Test Period
Slove Operating Time (le, Flue-
Gas Temperature Qvor 100
Degrees F)
Slove Operating Time During
T«*t Period (le, Flue-Gas
Temperature Over 100
0 ogfe« F)
ESS Settings
ESS Sampling Rala
Sample Cycle Duration
Sample Tlruu Per Sample
Cyclo
197.25 Hours
20 Hourt
12.0%
1.031 L/Mmut«
1S.OO Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at 1 toot above flue
collar)
Toil Facility Ambient Temperature
Participate Emissions
Emunon Factor
Emission Rale
Concentration
334 DtgrenF IN DegreesC
71 Degrees F 21 Degrees C
7.0 G/Kfl
14.3 G/Hour
188
Fuel
Tout Fuel Used
Avorago Fuel Moisture
Total Fuel Burned
Average Bum Rate Dunng
Slovo Operation
4S.« KG With Moisture
19.1% Percent Dry Basl*
40.7 KG Dry
2.0 KG/Hour (dry)
Breakdown of Particulate Sample
Rmse
XAD-2
Filler
J1.4S
-55.2%
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) U.SO Percent
Test Notes:
T«l Noll Numbnc 1: Stolchlomalrlc Volunu For Thlt TM| I* Sand on 2.0% ol Fu»l Carbon Generating
Carbon Mono«lde and »8.0% of Fuel Carbon Gerantlng Carbon Dioxide
Tott Nol< Number 2: STP (or tills Kit Is: 1.00 Almoipher* and 88 Degrees F (20 Dtgiees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P05: Lopi Flex-95 Catalytic
Week A
o
ON
oo
1000
S
O.
S
<
o»
u>
i
000
Test Period
8
i
3
s
S
S
Flue-Gas Temperature
- Oxygen Concentration
File: P05-a3.123 Printed: 07/26/99 at 03:57:22 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
WeekB
01/22/99 03:32:02 PM
01/29/99 03:17:54 PM
P05: Lopl Flax-95 Catalytic
Catalytic
n
ON
VO
Time
Toial Test Period
16SOO Hours
Slav* Operating Tma (w. Flue-
Gat, Tempcraum Over 100 31.3 Hours
OegnjgiF)
Slave Operating Timo During
Tut P«iod (i». Fluo-Gjs
Tempwwuro Ovor tOO
Degrees F)
ESS Settings
ESS Sampling Rate
Samplo Cycle Duration
Sampi* T«TK. Por Sample
1.0JB L/Minule
1S.OO Minutes
Average Temperatures
fluo-GjsT(jmpuralura(al 1 lool above flue
collar)
Tesl Facility Ambicnl Temperature
Particulate Emissions
Emiuion F.icitx
Emission Rale
Concentration
401 Degrees F 206 Dogma C
n OogreejF 22 DognMtC
1.4 G/Kg
S.J G/Haur
110 M04.13
Fuel
Total Fuel Used
Avurage Fuel Mofslura
Total Fuel Burned
Avuraaa Bum Rale During
Stove Operation
32.7 KG Wlh MwswrB
19.0V. Percent Dry Bans
27.6 KG Dry
Q.» K(V»(our (dry)
Breakdown of Particulate Sample
RlllM
XAO-2
Filler
Total
103.6%
7.1%
-11.4%
100U
Average Flue-Gas Concentrations
Q>yg*n (AWES) 18.12 Percenl
Test Notes:
Tott Nol» Number 1: Slokhloirutric Votume Fo< This TeM It B«ttd on 2.0% of Fuel Carbon Generating
Carbon MwunUe and H.0% of Fuel C«rtwo Oenentlng Carbon OloxU*
Test Note Number 2: STP for thlt t»t Is: 1.00 Atmotprure end M Degree* f (20 Degite* C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P05: Lopl Flex-95 Catalytic
WeekB
I
o
re (F)
3
o
pe
8
3
Flue T
g
o
n
-Li
o
0
0
0
£
3
8
3
5
3
Test Period
o- Flue-Gas Temperature
-x Oxygen Concentration
File: P05-b3.123 Printed: 07/26/99 at 03:57:42 PM
-------
AWES-Emissions Results
Prolect Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland. Oregon USA
WeekC
01/30/99 11:02:01 AM
02/06/99 10:48:00 AM
POS: Lopl Flex-95 Catalytic
Catalytic
n
Time
Total Test Period 188.00 Hours
Slove Operating Tlmo (to, Flue-
Gas Temperaturo Over 100 33.T5 Hours
Degree* F)
Stovo Operating Time Owing
Ti«lPBnod
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P05: Lopi Flex-95 Catalytic
WeekC
1000
O
•Ij
to
25
- 20
15 £,
S
- 10
- 5
3
5
8
<
5
8
s
s
<
m
u>
i
<
00
<
s
N
8
?
S
8
S
S
T«*t Period
Flua-Oas Temperature
Oxygen Concentration
File: P05-c3.123 Printed: 07/26/99 at 03:58:24 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland. Oregon USA
Week A
01/23/99 10:47:01 AM
01/30/9910:32:59 AM
P06: Pacific Energy Super-27 Non-Catalytic
New Tech/Non-Catalytic
0
-Ll
u>
Time
Total Test Period
Stove Operating Time (la. Flue-
Gas Temperature Over 100
Degrees fl
Stovo Operating Time Ounng
Test Period (le, Rue-Gas
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample Time Per Sample
Cycle
1M.OO Hours
1J» Hoots
82.7%
1.042 UMInule
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at t tool above flue
collar)
Test Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Ralo
Concentration
471 Degrees F 241 Degrees C
71 DegrecsF 22 DegrcesC
t.1 aKg
11.t GMour
309
Fuel
Tout Fuel Used
Avorago Fuel Moisture
Total Fuel Burned
Average Bum Rale During
Stove Operation
412.S KGWilhMolsluro
100.1% Poreenl Dry Basil
209.4 KG Dry
1.S KOHour(dry)
Breakdown of Particulate Sample
Rinso
XAD-2
Filter
M.6%
11.7%
4M*
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 1S.S2 Percent
Test Notes:
Test Note Number 1: Slorchlometrlc Volume bt Based on 11.S* of Fuel Carbon Generating Carbon
Monoxide and M.S% of Fuel Carbon Generating Gabon Dioxide
Test Note Number 2; STP (or this lest Is: 1.00 Atmosphere and 81 Degrees F (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P06: Pacific Energy Super-27 Non-Catalytic
Week A
1000
n
25
- 20
15 e
I
10 J?
- 5
" Flue-Gat Temperature
-* Oxygen Concentration
File: P06-a3.123 Printed: 07/26/99 at 03:58:41 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Data/Time:
Stove Model Tested:
Stove Type:
Portland. Oregon USA
WeekB
01/30/99 04:17:00 PM
02/06/99 04:02:57 PM
P06: Pacific Energy Super-27 Non-Catalytic
New Tech/Non-Calalytic
O
Time
Total TO*I Ported
Stove Operating Time (le.Fluo-
G» Temperature Over 100
Degrees F)
Slavs Oporaiuiqjima Danny
TeW Ponod (w.Tiue-G«
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Rale
Sample Cycle Duration
Sample Tim« Par Sample
Cycle
168.00 Hours
142 Hours
84.5%
1.042 L/Mmuls
15.00 Mmutei
120 Seconos
Average Temperatures
Flue-Gas Temperature (al l fool above Hue
collar)
Test Faculty Ambient Temperature
Particulate Emissions
Emission Factor
Emission Rale
Concentration
4(4 Degrees F 240 Degree* C
M DegwuF 21 Degrees C
14.7 G/KO
1».» G/Hour
113 M0/M3
Fuel
Total Fuel Used
Average Fuel Moisture
Tola! Fuel Burned
Average Bum Rate During
Stove Operation
373.1 KG With Moisture
105.0% Percent Dry Basil
182.0 KGDty
1.) K&Hour(dry)
Breakdown of Particulate Sample
Rinse
XAD-2
Filler
Total
2MK
M.*%
33.SV.
100%
Average Flue-Gas Concentrations
Oxygon (AWES) 15.55 Percent
Test Notes:
Test Note Number 1: Stolchtometrlc Volume!« Based on 11.5% of Fuel Carbon Generating Carbon
Monoxide and M.SX of Fuel Carbon Generating Cabon Dioxide
Test Note Number 2: STP for this lest Is: 1.00 Atmosphere and U Degrees F (20 Degreet C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P06: Pacific Energy Super-27 Non-Catalytic
WeekB
1000
o
-ij
o\
I
8
s
§
I
CO
S
o
«
9
6
$
^
Q.
&
8
6
^
5
at
o
Test Period
&>
II
;
t
s
- Flue-Qa* Temperature
- Oxygen Concentration
File: P06-b3.123 Printed: 07/26/99 at 03:59:00 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Portland, Oregon USA
WeekC
02/07/9912:47:00 PM
02/14/99 11:17:58 AM
P06: Pacific Energy Super-27 Non-Catalytic
Stove Type: New Tech/Non-Catalylic
n
Time
Tout Test Period
Stove Operating Timo (10. Flue
Gas Toroporalure Over 100
Dogroos r)
Slova Operating Time Ounng
Test P«nod (lo, Flua-Ga*
Temperature Over 100
Degreet F)
ESS Settings
ESS Sampling Rale
Samplo Cyda Duration
Samplo Time Per Sample
Cyda
1W.7S Hours
112.75 Hours
Bl.8%
1.042 UMinulo
1100 Minutes
120 Seconds
Average Temperatures
Flue-Gas Tempcralui* (si 1 toot above Hue
coter)
Test Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Rale
Conccnifitijon
4t> OcgrociF 252
72 Degrees F 22 Dogmas C
8.7 Q/Kg
10.0 G/Hour
sit
Fuel
Tout Fuel Used
Average Fuel Moisture
Total Fuel Burned
Average Bum FUta Ounng
Siovfl Operation
3S1.7 KG Wild Moisture
101 -2% Percent Dry Bans
174.» KG Dry
1.1 KOHour(dry)
Breakdown of Particulate Sample
Rjriso
XAO-2
Filler
Total
ttlV.
100%
Average Flue-Gas Concentrations
Oxygm(AWES) 14.07 Percent
Test Notes:
Tttt Not* Number 1: Stotchlomalrlc VohtiiM It Based on 11 ,»* of Fuel CMttan GomnUng Carbon
Monoxld* and U.1% of Fud Carbon OtaianUng Cabon Oloilde
Tost Now Numotr 2: STP for this nit l«: 1.90 Atmotphore and «l Oagrtai t (20 Dtgnts C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P06: Pacific Energy Super-27 Non-Catalytic
WeekC
1000
n
ij
00
§
fj
£
•f
«^
3
2
3
8
S
I
Test Period
n
5
§
i
8
A
5
i
a
S
~e- Flue-Gas Temperature
-H- Oxygen Concentration
File: P06-C3.123 Printed: 07/26/99 at 03:59:17 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Type:
Portland, Oregon USA
Week A
01/20/99 09:17:00 AM
01/27/99 09:02:58 AM
P07: Lopl 520/96 Non-Catalytic
New Tech/Non-Catalytic
n
Time
Total Toil Period
Slovo Oporaung Time (la, Fiuo-
Gai Temperature Over 100
Degrees r|
Slovo OporaUnoJime Dunng
T»st P«nod (ie.Fioa-Gii
Temperature Over 100
Degrees F)
ESS Settings
ESS Sampling Ralu
Sample Cyclo Ouralion
Sample Time Per Sample
Cyd*
148.00 Hours
168 Hours
1000%
1.108 L/Mmule
1S.OO Minutes
110 Second!
Average Temperatures
Fkio-Gjj Temperature (at 1 loot atxim Hue
collar)
Test Facility Ambient Temperature
Particulate Emissions
Emission Factor
Emission Rale
Cancentrauon
Ml OtgrcwF 171
(• Degree* F 21 Dogmas C
11.4 OKg
J«.l Q/Hour
10»7
Fuel
Total Furt Used
Averagu Pud Moisture
Tout Fud Burned
Aversnp Bum Rale Ounng
Slovo Opofa lion
KG With Masluro
Ptrccnl Dry Basis
J42J KG Dry
1.4 KQHour(dry)
Breakdown of Particulate Sample
Rinse
XAO-2
Filler
20.4%
20.0%
M.t*
Total
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 15.14 Percent
Test Notes:
Test Nou Number 1: StaichlomaUfe Volume Is Bued on 11 J% oiFud C»rt>on G«n*nUng Carbon
MonpiW. and M.S% of Fu»l C«faon Gtmratlng Ctbon Uoxldi
Tail NoU Number 2: STP (or this tost Is; 1.00 Atmosphere ind 68 Degree* F (10 Oegriet C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P07: Lop) 520/96 Non-Catalytic
Week A
1000
n
oo
o
200
a
8
i
a.
§
00
s
s
3
S
s
s
5 5
Test Period
E
v.
5
2
s
25
- 20
15
- 10
- 5
s
5
8
I
-«- Flue-Gas Temperature
-x- Oxygen Concentration
File: P07-a3.123 Printed: 07/26/99 at 04:00:03 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Tost Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Stove Typo:
Portland, Oregon USA
WeekB
01/27f99 11:32:01 AM
02/03«9 11:17:59 AM
P07: Lopl 520/96 Non-Catalytic
New Tech/Non-Catalytic
n
00
Time
Total Test Period
Stov* Operating Tima (ie. Flue-
CM Temperature Over ICO
Degrees F)
Stove Operating Time Ouiing
Test Period (10. Flue-Gas
Tomporalure Over too
Degrees F)
ESS Settings
ESS Sampling Rate
Sample Cycle Duration
Sample Time Per Sample
Cycle
168.00 Hours
1(1 Hours
1011.0%
1.101 LAfcrtute
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Ga> Temperature (at t fool abovofluo
collar)
Teat Facility Ambient Temperature
Particulate Emissions
Emtiion Factor
Emission Ratq
Concentration
127 Degrees F 1(4 Degrees C
II Degrees F 21 Degrees C
18,5 WKg
ar.T &Hour
1011 Mg/M3
Fuel
Total Fuel Used
Average Fud Motslure
Total Fuel Burned
Averaoa Bum RMi During
Slovaoporalion
517.4
103.0% Percent Dry Basis
2S3.4 KG Dry
1.S KG/Hour (dry)
Breakdown of Particulate Sample
Rinse I4.IH
XAD-2 tl.1%
Filler M.0%
Total 100%
Average Flue-Gas Concentrations
Oxygon (AWES) 15.14 Percent
Test Notes:
Tost Note Number 1: Slolchlometrlc Volume I* Bated on 11.8% of Fuel Carbon Generating Carbon
Monoxide and 88.5% of Fuel Cirbon Generating Cabon Dioxide
Test Note Number 2: STP (or 1nl« tost It: 1.00 Atmosphere and 81 Dtgreil F (20 Degries C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P07: Lopl 520/96 Non-Catalytic
WeekB
p
oo
to
1000
g too
3
600
400
200
§
a
i
23
- 20
15
- 10
— 5
Test Period
Flue-Gia Temperature
- Oxygen Concentration
File: P07-b3.123 Printed: 07/26/99 at 04:00:21 PM
-------
AWES-Emissions Results
Prolect Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Dale/Time:
Test Period End Datemme:
Stove Model Tested:
Portland, Oregon USA
WeekC
02/03/99 12:32:01 PM
02/10/99 12:17:57 PM
P07: Lopl 520/96 Non-Catalytic
Stove Type: New TecWNon-Catalytic
o
oo
Time
Total TcH Penod
16B.OO Hours
Slrwe Operating Time do.
Fluo-Gas Temperature Over 1U Hours
100 OogrenF)
Siovo Opoiating Tvre During
Tott Perms (fc.Flue-Gas 1M 0%
Temperature Over 100 100-0*
Degrees F)
ESS Settings
ESS Sampling Rate 1.109 UMmule
Sample Cycle Duration 14.00 Minutes
Sample Time Per Sample 1M Sceonds
Average Temperatures
FM Gat T«mp«aiuro (at 1 loot above «u«
coto)
Tesi Facility Amt»«nl TwnperatMfo
Partlculate Emissions
Emlulon Faclof
Emission Rale
Concentration
M2 DeflftesF 172 0«gn«sC
71 DsgrwsF XI 0*grt«aC
20.8 a«g
40.1 axout
Hie Mg>t43
Fuel
ToUil Fuel Uiod
Average Fuel Moisluro
Total FuOl Bumod
Average Bum Rate During
Stove operation
<06.1 KG WiUi Moisture
24.1% Percent Dry Basis
JJJ.4 KG Dry
1.» K&'llour (dry)
Breakdown of Participate Sample
Rinsa
XAO-2
Finer
Total
23.B%
17.4%
16.7%
100%
Average Flue-Gas Concentrations
Oxygen (AWES) 14.11 Pvtcani
Test Notes:
Tell Note Number 1: SlokMontetrte Volume Is Based on 11.5% of Fuel Carton Genenttng Cartoon
Monoxide and M.S% of Fuel Carbon Oenerallng Cabon UoxMe
Ted Note Number 2: STP for Itila led Is: 1.00 Atmosphere and M Degree! f (20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
POT: Lopl 520/96 Non-Catalytic
WeekC
n
oo
z
5
8
5
3
o
3
s
f
&
2
S
«
5
3
S
ft
h^
3
ft
8
s
3
is
Test Period
• Flue-Gas Temperature
• Oxygen Concentration
File: P07-C3.123 Printed: 07/26/99 at 04:00:44 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Dale/Time:
Stove Model Tested:
Portland. Oregon USA
Week A
01/22/99 10:47:02 AM
01/29/99 11:02:56 AM
POB: Vermont Castings Defiant Encore Catalytic
Stove Type: Catalytic
O
oo
Time
Total Test Period
Slovt Operating Tim* (le, Flue-
Gat Twnperature Over 100
OegrMt F)
Stova OperatmgTime During
T*tl PMod (le.Flue-Gas
Temperature Over 100
Oagrett F)
ESS Settings
ESS Sampling Rate
Samp* Cycle Duration
Sample Time Per Sample
Cycle
11JJJ Hours
131 Hours
g».JV.
LOTS LJ.knulO
18.00 Minutes
120 Seconds
Average Temperatures
Flue-Gat Toinpcraiuru fat 1 loot above Hue
collar)
Test Factory AmOwni Tanp«raiufo
Particulate Emissions
Emission Factor
Ernssion Ram
Concentration
343 DeflreesF 1N DegreesC
71 Degreei F 22 DegraetC
17.7
2J.O
714
G/Kg
GtiHour
M0IM3
Fuel
Total Fuel Used
Average Fuel Moisture
Total Fuel Burned
Average Bum Rate During
Stove Operaton
211.1 KG Will) Moisture
24.8% Purconl Dry Basis
169.8 KG Dry
1.1 KG/Hour(
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P08: Vermont Castings Defiant Encore Catalytic
Week A
O
oo
OS
1000
IL 800
600
400
200
01/22/99 11:17:02 AM 01/24/99 08:33:01 PM 01/26/99 12:02:59 AM 01/27/9908:17:58 AM 01/28/99 12:32:58 PM
01/24/99 06:48:01 AM 01/25/99 10:17:58 AM 01/26/99 07:36:53 PM 01/27/99 10:47:58 PM 01/29/99 02:17:56 AM
TMt Period
• Flue-Cat Temperature
• Oxygen Concentration
File: P08-a3.123 Printed: 07/26/99 at 04:01:00 PM
-------
AWES-Emissions Results
Project Name: ERG/EPA
Residence Location:
Test Run Number:
Test Period Start Date/Time:
Test Period End Date/Time:
Stove Model Tested:
Portland. Oregon USA
WeekB
01/29/99 01:17:01 PM
02/05/99 02:14:37 PM
P08: Vermont Castings Defiant Encore Catalytic
Stove Type: Catalytic
o
oo
-J
Time
Total Test Penod «T.7» Hours
Slave Operating Time (is. Fluo-
Gai Temperature Over (DO 17.1 Hours
DegnresF)
Slavs Operating Timo During
Toll Poriod (le, Flue-Gat
Temperature Over 100
Oegr§«« F)
38.4%
ESS Settings
ESS Sampling Rats
Sample Cycle Duration
Sample Tim« Per Sample
Cycle
1.0TI UMnute
15.00 Minutes
120 Seconds
Average Temperatures
Flue-Gas Temperature (at 1 fool above Hue
collar)
Tost Facility Ambiont Temperature
Particulate Emissions
Emission Factor
Emission Rdto
Concentration
3*3 OagnMsF 1»S DegrHiC
T4 Degrees F 23 OogroeiC
UJ GVKg
2U GMour
IS7 Mg/M3
Fuel
Total Fuel Used
Aviraea Fuel (.vasiine
Total Fuel Burned
Average Burn Rate During
Stova Operation
7«.a KG S'.'itti Moisture
25.0% Percent Dry flaws
•1.0 KG Dry
1.6 KG/Hour(dry)
Breakdown of Particulate Sample
Rinsq
XAO-2
fact
Total
Average Flue-Gas Concentrations
OnygtHi (AWES) 11.72 Percent
Test Notes:
T«| Nol* Numbtr 1: Sloichlomatilc Volume For TN» Test It Bated en J.OH at Fuel Carbon OineraUng
Carbon Monoxide and »0.0% of Fuel Carbon GtmraUflg Carbon OloxWe
Ted Note Numbtr 2: STP (or this tesl It: 1.00 Atmetphere and H Oegreet F(20 Degrees C)
-------
Flue-Gas Temperature and Flue-Gas Oxygen Concentrations
P08: Vermont Castings Defiant Encore Catalytic
WeekB
n
oo
oo
1000
800
600
I
0>
IT
25
20
- 19
10
200
01/29/99 01:47:01 PM 01/30/99 05:18:17 PM 02/01/99 08:48:03 PM 02/04/99 11:48:01 PM
01/30/99 03:32:01 AM 02/01/99 07:03:17 AM 02/04/99 10:09:13 AM 02/05/99 01:29:37 PM
TMt Period
• Flue-Gas Temperature * Oxygen Concentration
File: P08-b3.123 Printed: 07/26/99 at 04:01:18 PM
-------
Appendix D
Organic Compound Analysis Data
D-l
-------
Contents of Appendix D
Organic Compound Analysis Data by Test - Klamath Falls D-3
Blank Data - Klamath Falls D-25
Organic Compound Analysis Data by Test - Portland D-39
Blank Data - Portland D-64
D-2
-------
Organic Compound Analysis Data by Test - Klamath Falls
D-3
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD/ Rinse
11/15/98
ENG1091.D
01/27/99
107.99
130.63
92.26
103.73
126.50
103.61
102.39
102.98
97.21
114.19
102.88
KF01-A
Filter
11/15/98
ENG1113.D
01/29/99
% Recovery
120.69
115.39
87.61
85.99
93.38
94.91
% Recovery
115.50
90.42
91.04
95.14
92.72
Omni - SVOC Compounds
Episode KF-A
TOTAL
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkj [naphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aikylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthcnc
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours= 168 Dry Fuel (kg)= 11 1.9
XAD
Mg
5751
864
306
6651
1296
0
0
1470
2341
4238
0
100
195
2296
343
277
188
343
311
517
0
0
295
52
145
0
0
629
94
0
193
136
0
0
0
0
0
0
0
0
Filter
Mg
0
0
0
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
5751
864
306
6667
1296
0
0
1470
2341
4238
0
100
195
2296
343
277
188
343
311
517
0
0
295
52
145
0
0
629
94
0
193
136
0
0
0
0
0
0
0
0
Total - Blank
Mg
5738
860
306
6647
1287
0
0
1456
2313
4238
0
100
195
2296
318
272
185
343
306
517
0
0
295
52
145
0
0
629
94
0
193
136
0
0
0
0
0
0
0
0
ug/hr
189138.053
28347.634
10086.484
219100.844
42422.564
0.000
0.000
47993.204
76241.951
139694.505
0.000
3296.237
6427.661
75681.591
10482.032
8965.763
6098.038
11306.091
10086.484
17041.543
0.000
0.000
9723.898
1714.043
4779.543
0.000
0.000
20733.328
3098.462
0.000
6361.737
4482.882
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(ig/kg (Dry)
156070.637
23391.556
8323.042
180794.967
35005.735
0.000
0.000
39602.448
62912.405
115271.411
0.000
2719.948
5303.899
62450.014
8649.436
7398.260
5031.904
9329.423
8323.042
14062.133
0.000
0.000
8023.848
1414.373
3943.925
0.000
0.000
17108.475
2556.751
0.000
5249.500
3699.130
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-4
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
Omni • SVOC Compounds
Episode KF-B
KF01-B
XAD/ Rinse Filter TOTAL
12/15/98 12/15/98
ENG1092.D ENG1114.D
01/27/99 01/29/99
Hours=
XAD
Toluene 4734
m,p-Xylene 704
o-Xylene 237
Phenol 4510
Benzofuran 905
C3-alkyibenzenes 1051
Decane 0
o-Cresol 925
m,p-Cresol 1674
C4-aIkylbenzenes 8129
Undecane 0
2-Ethylphenol 76
2,3-Dimethylphenol 113
Naphthalene 1834
2-Methylnaphthalene 255
1-Methylnaphthalene 224
Biphenyl 152
Tetradecane 255
C2-alkylnaphthalenes 279
Acenaphthylene 389
Pentadecane 0
Acenaphthene 0
Dibenzofuran 245
C3-alkylnaphthalenes 274
Fluorene 118
Heptadecane 0
Octadecane 0
Phenanthrene 532
Anthracene 85
Carbazole 0
Fluoranthene 164
Pyrene 112
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(1.2r3-cd)pyrene 0
Dibenz(a,n)anthracene 0
Benzo(g,h,i)perylene 0
8270 Surrogate Compounds
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5 •
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dIO
Pyrene-dlO
85.34
91.92
94.63
89.95
113.67
97.99
79.16
91.61
86.03
104.20
99.45
% Recovery
120.43
111.96
111.66
93.70
103.52
82.55
% Recovery
124.46
97.75
95.74
92.36
84.07
Lab Surrogate Compounds
Target Compounds
141 Dry Fuel (kg)= 11 6.5
liter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
0
0
12
11
13
15
19
0
8
0
0
0
TOTAL
Mg
4734
704
237
4510
905
1051
0
925
1674
8129
0
76
113
1834
255
224
152
255
279
389
0
0
245
274
118
0
0
540
85
0
176
123
13
15
19
0
8
0
0
0
Total - Blank
Mg
4721
700
237
4490
896
1051
0
912
1647
8129
0
76
113
1834
230
219
149
255
274
389
0
0
245
274
118
0
0
540
85
0
176
123
13
15
19
0
8
0
0
0
Hg/hr
148062.987
21953.843
7432.944
140818.219
28100.918
32962.126
0.000
28602.721
51654.255
254946.837
0.000
2383.560
3543.977
57519.067
7213.405
6868.416
4673.032
7997.471
8593.361
12200.064
0.000
0.000
7683.845
8593.361
3700.791
0.000
0.000
16935.821
2665.824
0.000
5519.823
3857.604
407.714
470.439
595.890
0.000
250.901
0.000
0.000
0.000
Hg/kg (Dry)
118973.313
17640.610
5972.606
113151.911
22579.981
26486.116
0.000
22983.194
41505.835
204857.882
0.000
1915.266
2847.698
46218.398
5796.200
5518.991
3754.930
6426.222
6905.039
9803.139
0.000
0.000
6174.213
6905.039
2973.703
0.000
0.000
13608.470
2142.074
0.000
4435.353
3099.707
327.611
378.013
478.817
0.000
201.607
0.000
0.000
0.000
D-5
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobcnzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylplienol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(gji,i)perylene
Omni - SVOC Compounds
Episode KF-C
KF01-C
XAD/ Rinse
12/15/98
ENG1090.D
01/27/99
Filter
12/15/98
ENG1115.D
01/29/99
TOTAL
8270 Surrogate Compounds
105.74
101.92
92.81
88.40
94.09
78.21
% Recovery
110.83
103.47
93.36
88.56
94.14
84.75
Lab Surrogate Compounds
99.12
88.35
77.70
86.16
77.75
% Recovery
114.52
90.45
92.11
88.90
83.41
Target Compounds
Hours=
XAD
Mg
1599
223
76
1404
369
297
38
302
447
898
0
24
38
966
121
95
92
121
88
189
0
15
98
76
62
0
0
244
45
0
104
68
12
13
0
0
0
0
0
0
142.75Dry Fuel (kg)=58.80
Filter
MS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
6
7
0
0
0
0
0
0
TOTAL
"g
1599
223
76
1404
369
297
38
302
447
898
0
24
38
966
121
95
92
121
88
189
0
15
98
76
62
0
0
244
45
0
108
68
18
20
0
0
0
0
0
0
Total - Blank
Mg
1586
219
76
1383
360
297
38
289
420
898
0
24
38
966
96
90
89
121
83
189
0
15
98
76
62
0
0
244
45
0
108
68
18
20
0
0
0
0
0
0
ug/hr
136593.044
18861.208
6545.442
119109.823
31004.726
25578.899
3272.721
24889.905
36172.181
77339.567
0.000
2066.982
3272.721
83196.016
8267.927
7751.182
7665.057
10421.033
7148.312
16277.481
0.000
1291.864
8440.175
6545.442
5339.703
0.000
0.000
21014.314
3875.591
0.000
9301.418
5856.448
1550.236
1722.485
0.000
0.000
0.000
0.000
0.000
0.000
Mg/kg (Dry)
100484.648
13875.245
4815.153
87623.120
22808.621
18817.113
2407.577
18310.254
26610.058
56894.838
0.000
1520.575
2407.577
61203.134
6082.299
5702.155
5638.798
7666.231
5258.654
11974.526
0.000
950.359
6209.014
4815.153
3928.151
0.000
0.000
15459.177
2851.078
0.000
6842.586
4308.295
1140.431
1267.146
0.000
0.000
0.000
0.000
0.000
0.000
D-6
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-dl4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
XAD/Rinse
11/15/98
ENG1059.D
01/14/99
Omni - SVOC Compounds
Episode KF-A
KF02-A
Filter TOTAL
11/15/98
ENG1076.D
01/18/99
Hours=
XAD
15862
2268
812
18496
4304
0
0
3719
6062
6781
0
223
349
11748
1700
1377
794
1700
1001
2894
0
187
1214
0
718
0
0
3109
461
0
995
785
204
182
0
0
0
0
0
0
8270 Surrogate Compounds
% Recovery
117.76
124.69
116.04
93.58
104.13
96.22
% Recovery
113.07
100.82
102.72
112.83
93.10
Lab Surrogate Compounds
Target Compounds
168 Dry Fuel (kg)= 162.6
Filter TOTAL Total - Blank
t»g
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
0
0
7
8
16
19
61
0
32
0
0
0
ug
15871
2268
812
18496
4304
0
0
3719
6062
6781
0
223
349
11748
1700
1377
794
1700
1001
2894
0
187
1214
0
718
0
0
3113
461
0
1001
793
220
201
61
0
32
0
0
0
Mg
15858
2264
812
18476
4295
0
0
3705
6035
6781
0
223
349
11748
1675
1372
791
1700
996
2894
0
187
1214
0
718
0
0
3113
461
0
1001
793
220
201
61
0
32
0
0
0
ug/hr
158681.609
22654.506
8125.203
184878.383
42977.520
0.000
0.000
37073.739
60388.669
67853.449
0.000
2231.429
3492.236
117555.274
16760.732
13728.791
7915.068
17010.893
9966.382
28958.543
0.000
1871.198
12147.779
0.000
7184.601
0.000
0.000
31149.946
4612.954
0.000
10016.414
7935.081
2201.410
2011.288
610.391
0.000
320.205
0.000
0.000
0.000
jig/kg (Dry)
164080.041
23425.225
8401.627
191168.044
44439.638
0.000
0.000
38335.008
62443.123
70161.859
0.000
2307.343
3611.044
121554.567
17330.941
14195.852
8184.343
17589.612
10305.443
29943.728
0.000
1934.857
12561.052
0.000
7429.024
0.000
0.000
32209.684
4769.889
0.000
10357.178
8205.037
2276.303
2079.713
631.157
0.000
331.099
0.000
0.000
0.000
D-7
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
Omni - SVOC Compounds
Episode KF-B
KF02-B2
XAD /Rinse Filter TOTAL
12/15/98 12/15/98
ENG1096.D ENG1116.D
01/28/99 01/29/99
Hours=
XAD
Toluene 17956
m,p-Xylene 2566
o-Xylene 802
Phenol 13920
Benzofuran 4791
C3-alkylbenzenes 4578
Decane 0
o-Cresol 2618
m,p-Cresol 5539
C4-alkylbenzenes 13491
Undecane 0
2-Ethylphenol 178
2,3-Dimethylphenol 266
Naphthalene 13793
2-Methy (naphthalene 2116
1-Methylnaphthalene 1777
Biphenyl 897
Tetradecane 2116
C2-alkyInaphthalenes 1409
Acenaphthylene 4347
Pentadecane 0
Acenaphthene 322
Dibenzofuran 1235
C3-alkyInaphthalenes 1123
Fluorene 986
Heptadecane 0
Octadecane 0
Phenanthrene 4798
Anthracene 790
Carbazole 0
Fluoranthene 1566
Pyrene 1022
Benzo(a)anthracene 293
Chrysene 340
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2>3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
5270 Surrogate Compounds
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
74.56
90.54
85.50
87.74
99.39
95.59
74.77
87.76
78.61
102.98
93.67
% Recovery
110.00
106.96
89.54
88.58
102.57
74.88
% Recovery
106.81
98.23
92.31
88.03
77.39
Lab Surrogate Compounds
Target Compounds
168 Dry Fuel (kg)= 170.9
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
2
0
14
13
50
62
134
33
87
0
0
0
TOTAL
fg
17956
2566
802
13920
4791
4578
0
2618
5539
13491
0
178
266
13793
2116
1777
897
2116
1409
4347
0
322
1235
1123
986
0
0
4808
793
0
1580
1035
344
401
134
33
87
0
0
0
Total - Blank
fig
17943
2562
802
13900
4782
4578
0
2605
5512
13491
0
178
266
13793
2091
1773
894
2116
1404
4347
0
322
1235
1123
986
0
0
4808
793
0
1580
1035
344
401
134
33
87
0
0
0
Mg/hr
198158.266
28294.125
8857.099
153508.327
52811.282
50558.354
0.000
28769.007
60873.230
148991.427
0.000
1965.790
2937.641
152326.644
23092.512
19580.594
9873.125
23368.606
15505.445
48007.244
0.000
3556.092
13639.049
12402.148
10889.152
0.000
0.000
53098.420
8757.705
0.000
17449.148
11430.296
3799.055
4428.550
1479.864
364.444
960.808
0-000
0.000
0.000
Hg/kg (Dry)
190059.195
27137.695
8495.094
147234.176
50652.793
48491.946
0.000
27593.167
58385.236
142901.889
0.000
1885.445
2817.575
146100.790
22148.681
18780.302
9469.594
22413.490
14871.711
46045.105
0.000
3410.749
13081.598
11895.250
10444.093
0.000
0.000
50928.195
8399.763
0.000
16735.971
10963.120
3643.781
4247.547
1419.380
349.549
921.538
0.000
0.000
0.000
D-8
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-TribromophenoI
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthraccne-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkyIbenzenes
Decane
o-Cresol
m,p-Cresol
C4-aIkylbenzenes
Undecane
2-Ethylphenol
2,3-DimethyIphenol
Naphthalene
2-MethyInaphthalene
1-Meth) (naphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a (anthracene
Chrysene
Benzo(b)f1uoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1^3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
XAD/ Rinse
12/15/98
ENG1097.D
01/28/99
79.28
90.32
73.06
81.82
91.17
89.38
83.15
83.35
74.89
102.04
87.54
Hours=
XAD
Mg
20489
2738
864
14714
5144
4025
0
2387
5005
6663
0
149
218
15368
2550
2112
1044
2550
1520
6062
0
397
1273
1281
1317
0
0
6902
1217
0
2338
1551
446
531
0
0
0
0
0
0
Filter
12/15/98
ENG1117.D
01/29/99
% Recovery
112.09
116.35
106.12
101.23
121.01
97.83
% Recovery
99.13
108.02
106.60
106.17
98.78
168 Dryi
Filter
Mg
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
0
0
6
8
59
76
195
63
145
0
0
0
Omni - SVOC Compounds
Episode KF-C
KF02-C
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
:l(kg)=119.10
TOTAL Total - Blank
Hg ug ug/hr fig/kg (Dry)
20489 20477 262383.544 294865.926
2738 2734 35032.310 39369.216
864 864 11070.927 12441.479
14719 14699 188346.717 211663.537
5144 5135 65797.700 73943.279
4025 4025 51574.633 57959.435
0 0 0.000 0.000
2387 2373 30406.610 34170.867
5005 4978 63785.969 71682.501
6663 6663 85376.840 95946.265
0 0 0.000 0.000
149 149 1909.222 2145.579
218 218 2793.359 3139.169
15368 15368 196918.997 221297.043
2550 2526 32367.087 36374.045
2112 2107 26998.199 30340.504
1044 1041 13338.930 14990.254
2550 2550 32674.612 36719.642
1520 1515 19412.564 21815.787
6062 6062 77675.882 87291.949
0 0 0.000 0.000
397 397 5086.989 5716.744
1273 1273 16311.679 18331.021
1281 1281 16414.188 18446.220
1317 1317 16875.476 18964.615
0 0 0.000 0.000
0 0 0.000 0.000
6906 6906 88490.538 99445.431
1217 1217 15594.119 17524.629
0 0 0.000 0.000
2344 2344 30035.016 33753.271
1559 1559 19976.361 22449.381
505 505 6470.855 7271.929
608 608 7790.653 8755.115
195 195 2498.647 2807.973
63 63 807.255 907.191
145 145 1857.968 2087.980
0 0 0.000 0.000
0 0 0.000 0.000
0 0 0.000 0.000
D-9
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-die
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkyIbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-MethyInaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkyInaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
XADonly*
11/15/98
ENG1072.D
01/15/99
Episode KF
KF03-A
Filter
11/15/98
ENG1077.D
01/18/99
•A
TOTAL
* - DCM/MeOH sample void
5270 Surrogate Compounds
89.74
96.72
98.11
90.86
96.58
107.06
% Recovery
118.97
124.90
106.17
99.53
110.30
102.23
Lob Surrogate Compounds
99.33
97.46
80.79
98.87
109.04
% Recovery
124.12
104.86
105.73
113.29
103.87
Target Compounds
XAD
ug
1734
426
114
2759
689
481
0
578
1015
655
0
25
40
2000
275
217
128
275
103
439
0
0
169
0
78
0
0
281
38
0
29
33
0
0
0
0
0
0
0
0
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
1734
426
114
2759
689
481
0
578
1015
655
0
25
40
2000
275
217
128
275
103
439
0
0
169
0
78
0
0
281
38
0
29
33
0
0
0
0
0
0
0
0
Total - Blank
Pg
OMNI
Sample Lost.
D-10
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
XAD/Rinse
12/15/98
ENG1099.D
01/28/99
Hours=
XAD
Toluene 1951
m,p-Xylene 459
o-Xylene 115
Phenol 2994
Benzofuran 592
C3-alkylbenzenes 565
Decane 0
o-Cresol 577
m,p-Cresol 1369
C4-alk} Ibenzenes 442
Undecane 0
2-Ethylphenol 39
23-Dimethylphenol 56
Naphthalene 1871
2-MethyInaphthalene 240
1-Methylnaphthalene 194
Biphenyl 160
Tetradecane 240
C2-alkylnaphthalenes 198
Acenaphthylene 636
Pentadecane 0
Acenaphthene 34
Dibenzofuran 173
C3-alkylnaphthalenes 181
Fluorene 168
Heptadecane 0
Octadecane 0
Phenanthrene 509
Anthracene 103
Carbazole 0
Fluoranthene 202
Pyrene 181
Benzo(a)anthracene 34
Chrysene 40
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
lndeno(lj,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Omni - SVOC Compounds
Episode KF-B
KF03-B
Filter TOTAL
12/15/98
ENG1131.D
02/02/99
8270 Surrogate Compounds
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobipbenyl
2,4,6-TribromophenoI
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
93.77
100.35
75.36
93.34
105.71
94.64
69.52
101.79
86.93
110.51
95.20
% Recovery
141.25
138.59
130.90
115.12
119.20
105.42
% Recovery
135.93
125.48
119.07
132.36
102.99
Lab Surrogate Compounds
Target Compounds
168 Dry Fuel (kg)=l 16.8
•ilter
|ig
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15
12
21
24
52
0
17
0
0
0
TOTAL
"g
1951
459
115
2994
592
565
0
577
1369
442
0
39
56
1871
240
194
160
240
198
636
0
34
173
181
168
0
0
509
103
0
217
194
54
64
52
0
17
0
0
0
Total - Blank
Mg
1938
455
115
2974
583
565
0
563
1341
442
0
39
56
1871
215
189
157
240
193
636
0
34
173
181
168
0
0
509
103
0
217
194
54
64
52
0
17
0
0
0
ug/hr
40078.262
9409.499
2378.225
61502.968
12056.567
11684.323
0.000
11642.963
27732.172
9140.656
0.000
806.529
1158.092
38692.688
4446.247
3908.561
3246.794
4963.252
3991.282
13152.619
0.000
703.127
3577.678
3743.119
3474.277
0.000
0.000
10526.231
2130.062
0.000
4487.607
4011.962
1116.732
1323.534
1075.371
0.000
351.564
0.000
0.000
0.000
ug/kg (Dry)
49019.134
11508.620
2908.772
75223.377
14746.210
14290.924
0.000
14240.337
33918.812
11179.802
0.000
986.453
1416.446
47324.458
5438.139
4780.504
3971.106
6070.481
4881.678
16086.775
0.000
859.985
4375.805
4578.154
4249.337
0.000
0.000
12874.478
2605.248
0.000
5488.727
4906.972
1365.858
1618.795
1315.271
0.000
429.992
0.000
0.000
0.000
D-ll
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
Episode KF-C
KF03-C
XAD /Rinse FUter TOTAL
12/15/98 12/15/98
ENG1100.D ENG1125.D
01/28/99 02/01/99
8270 Surrogate Compounds
% Recovery
102.41 122.34
111.92 118.32
74.77 103.72
85.53 98.58
103.28 112.03
99.24 103.66
Lab Surrogate Compounds
% Recovery
78.46 112.88
92.69 101.47
79.19 107.34
108.05 108.62
95.48 109.12
Target Compounds
Hours= 168 Dry Fuel (kg)= 1 39.60
XAD Filter TOTAL Total - Blank
K
1694
306
85
2731
533
601
0
391
747
378
0
22
34
1850
202
165
136
202
128
368
0
26
170
95
94
0
0
437
88
0
158
134
26
28
0
0
0
0
0
0
g Cg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Mg
1694
306
85
2731
533
601
0
391
747
378
0
22
34
1850
202
165
136
202
128
368
0
26
170
95
94
0
0
437
88
0
158
134
26
28
0
0
0
0
0
0
Mg
1681
302
85
2711
524
601
0
377
720
378
0
22
34
1850
178
161
133
202
123
368
0
26
170
95
94
0
0
437
88
0
158
134
26
28
0
0
0
0
0
0
)ig/hr
25056.599
4501.542
1266.990
40409.542
7810.623
8958.368
0.000
5619.475
10732.154
5634.381
0.000
327.927
506.796
27575.674
2653.227
2399.829
1982.467
3010.965
1833.410
5485.323
0.000
387.550
2533.981
1416.048
1401.142
0.000
0.000
6513.821
1311.708
0.000
2355.112
1997.373
387.550
417.362
0.000
0.000
0.000
0.000
0.000
0.000
|ig/kg (Dry)
28746.019
5164.365
1453.546
46359.581
8960.686
10277.428
0.000 •
6446.906
12312.393
6464.007
0.000
376.212
581.419
31636.011
3043.897
2753.188
2274.373
3454.310
2103.367
6293.001
0.000
444.614
2907.093
1624.552
1607.451
0.000
0.000
7472.939
1504.848
0.000
2701.886
2291.473
444.614
478.815
0.000
0.000
0.000
0.000
0.000
0.000
D-12
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-MethyInaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthaIenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
Episode KF-A
KF04-A
XAD/Rinse Filter TOTAL
11/15/98 11/15/98
ENG1072.D ENG1078.D
01/14/99 01/18/99
8270 Surrogate Compounds
89.09
114.80
119.59
114.11
109.74
120.63
95.41
117.35
83.97
121.33
119.81
% Recovery
116.48
111.83
114.39
93.52
93.67
97.51
Lab Surrogate Compounds
% Recovery
108.38
96.37
89.94
103.51
104.41
Target Compounds
Hours=
XAD
Mg
14749
5015
1411
17952
4470
6030
0
9414
13869
23047
0
586
1005
4527
1662
1099
650
1473
1662
1025
0
147
1104
1599
426
0
0
1270
228
0
366
314
0
0
0
0
0
0
0
0
168
Filter
Mg
0
0
0
164
0
0
0
29
96
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20
6
0
21
24
27
32
66
0
0
0
0
0
Dry Fuel (kg)= 15 1.6
TOTAL
Mg
14749
5015
1411
18115
4470
6030
0
9443
13965
23047
0
586
1005
4527
1662
1099
650
1473
1599
1025
0
147
1104
0
426
0
0
1290
234
0
387
338
27
32
66
0
0
0
0
0
Total - Blank
Mg
14736
5010
1411
18095
4461
6030
0
9429
13937
23047
0
586
1005
4527
1637
1094
647
1473
1595
1025
0
147
1104
0
426
0
0
1290
234
0
387
338
27
32
66
0
0
0
0
0
Mg/hr
179154.602
60909.647
17154.394
219992.028
54235.117
73310.413
0.000
114634.144
169440.668
280196.533
0.000
7124.362
12218.402
55037.519
19902.014
13300.430
7865.976
17908.166
19391.395
12461.554
0.000
1787.169
13422.006
0.000
5179.144
0.000
0.000
15683.322
2844.882
0.000
4704.997
4109.274
328.256
389.044
802.403
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
198670.956
67544.889
19023.122
243957.041
60143.264
81296.544
0.000
127121.909
187898.827
310719.973
0.000
7900.460
13549.424
61033.077
22070.057
14749.323
8722.863
19859.006
21503.812
13819.064
0.000
1981.856
14884.143
0.000
5743.338
0.000
0.000
17391.798
3154.791
0.000
5217.539
4556.921
364.014
431.424
889.813
0.000
0.000
0.000
0.000
0.000
D-13
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD /Rinse
12/15/98
ENG1099.D
02/01/99
86.79
99.05
89.05
153.34
158.40
129.50
87.90
159.57
121.04
159.44
134.05
KF04-B2
Filter
12/15/98
ENG1139.D
02/03/99
% Recovery
138.58
131.78
113.54
97.78
110.39
123.34
% Recovery
141.60
111.71
109.56
114.25
124.46
Omni - SVOC Compounds
Episode KF-B
TOTAL
Hours=
XAD
Mg
Toluene 40487
m,p-Xylene 9393
o-Xylene 3916
Phenol 30789
Bcnzofuran 7982
C3-alkylbenzenes 17330
Decane 0
o-Cresol 15383
m,p-Cresol 22843
C4-alkylbenzenes 79931
Undecane 0
2-Ethylphenol 717
23-Dimethylphenol 1086
Naphthalene 11687
2-Methylnaphthalene 5144
1-Methylnaphthalene 2830
Biphenyl 1514
Tetradecane 3542
C2-alkylnaphthalenes 5144
Acenaphthylene 3454
Pentadecane 0
Acenaphthene 437
Dibenzofuran 2316
C3-alky (naphthalenes 5017
Fluorene 1303
Heptadecane 0
Octadecane 0
Phenanthrene 3825
Anthracene 847
Carbazole 0
Fluoranthene 912
Pyrene 595
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
167 Dry Fuel (kg)=l 77.6
Filter
Mg
0
0
0
34
0
0
0
9
27
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
257
52
0
201
239
124
148
127
32
76
0
0
0
TOTAL
MS
40487
9393
3916
30822
7982
17330
0
15392
22870
79931
0
717
1086
11687
5144
2830
1514
3542
5017
3454
0
437
2316
0
1303
0
0
4082
899
0
1114
834
124
148
127
32
76
0
0
0
Total - Blank
t»g
40474
9389
3916
30802
7974
17330
0
15379
22843
79931
0
717
1086
11687
5120
2825
1510
3542
5012
3454
0
437
2316
0
1303
0
0
4082
899
0
1114
834
124
148
127
32
76
0
0
0
|ig/hr
384430.139
89178.598
37194.950
292563.550-
75738.645
164603.803
0.000
146072.815
216967.378
759200.609
0.000
6810.209
10315.045
111005.461
48630.783
26832.414
14342.282
33642.624
47604.977
32806.782
0.000
4150.713
21997.831
0.000
12376.154
0.000
0.000
38771.652
8538.882
0.000
10580.995
7921.499
nn. 111
1405.734
1206.271
303.942
721.863
0.000
0.000
0.000
ug/kg (Dry)
361784.530
83925.358
35003.909
275329.523
71277.112
154907.494
0.000
137468.110
204186.491
714478.413
0.000
6409.041
9707.417
104466.468
45766.092
25251.799
13497.422
31660.839
44800.713
30874.235
0.000
3906.207
20702.006
0.000
11647.113
0.000
0.000
36487.732
8035.882
0.000
9957.700
7454.867
1108.398
1322.926
1135.214
286.038
679.340
0.000
0.000
0.000
D-14
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-<15
2-FluorobiphenyI
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fhiorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-aIkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkyIbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-MethyInaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnapbthalenes
Accnaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
XAD/ Rinse
11/15/98
ENG1073.D
01/15/99
98.16
110.15
100.25
94.88
130.45
110.91
101.84
92.27
77.67
117.22
109.81
Hours=
XAD
Mg
4108
1293
422
6532
1512
2425
0
2314
4951
4038
0
171
292
1957
391
359
129
391
629
221
0
0
245
561
97
0
0
298
56
0
89
74
0
0
0
0
0
0
0
0
Filter
11/15/98
ENG1079.D
01/18/99
% Recovery
96.76
93.83
110.34
96.08
111.77
96.17
% Recovery
104.54
100.55
106.00
106.40
97.61
168 Dry
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Omni - SVOC Compounds
Episode KF-A
KF05-A
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
icl (kg)= 124.7
TOTAL Total - Blank
fig |ig
4108 4095
1293 1289
422 422
6532 6511
1512 1503
2425 2425
0 0
2314 2300
4951 4924
4038 4038
0 0
171 171
292 292
1957 1957
391 367
359 354
129 126
391 391
629 624
221 221
0 0
0 0
245 245
561 561
97 97
0 0
0 0
298 298
56 56
0 0
89 89
74 74
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
56584.390
17811.301
5831.163
89968.490
20768.337
33508.461
0.000
31781.221
68039.448
55796.769
0.000
2362.865
4034.833
27041.673
5071.177
4891.544
1741.058
5402.807
8622.383
3053.761
0.000
0.000
3385.391
7751.854
1340.338
0.000
0.000
4117.741
773.804
0.000
1229.795
1022.526
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ng/kg(Dry)
68475.934
21554.452
7056.616
108875.899
25132.925
40550.462
0.000
38460.232
82338.339
67522.789
0.000
2859.435
4882.777
32724.641
6136.915
5919.531
2106.952
6538.239
10434.428
3695.527
0.000
0.000
4096.851
9380.952
1622.018
0.000
0.000
4983.108
936.423
0.000
1488.244
1237.416
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-15
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD/ Rinse
12/15/98
ENG1124.D
02/01/99
124.80
120.95
80.96
115.59
124.11
107.66
90.32
116.69
99.50
120.27
103.99
KF05-B
Filter
12/15/98
ENG1126.D
02/01/99
% Recovery
138.88
140.86
112.58
105.69
121.04
113.65
% Recovery
138.91
111.35
104.25
118.40
113.14
Hours=
XAD
Toluene 2423
m,p-Xylene 600
o-Xylene 192
Phenol 3921
Benzofuran 836
C3-alkyIbenzenes 1402
Decane 0
o-Cresol 1349
m,p-Cresol 2625
C4-alkylbenzenes 2695
Undecane 0
2-EthyIphenol 83
2,3-Dimethylpbenol 134
Naphthalene 1368
2-Methylnaphthalene 266
1-Methylnaphthalene 220
Biphenyl 166
Tetradecane 266
C2-alkylnaphthalenes 422
Acenaphthylene 526
Pentadecane 0
Acenaphthene 43
Dibenzofuran 365
C3-alkylnaphthalenes 625
Fluorene 305
Heptadecane 0
Octadecane 0
Phenanthrene 1846
Anthracene 442
Carbazole 0
Fluoranthene 897
Pyrene 568
Benzo(a)anthracene 181
Chrysene 197
Benzo(b)fluoranthene 135
Benzo(k)fluoranthene 34
Benzo(a)pyrene 70
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Omni • SVOC Compounds
Episode KF-B
KF05-B
Filter TOTAL
12/15/98
ENG1126.D
02/01/99
8270 Surrogate Compounds
% Recovery
138.88
140.86
112.58
105.69
121.04
113.65
Lab Surrogate Compounds
% Recovery
138.91
111.35
104.25
118.40
113.14
Target Compounds
78.5 Dry Fuel (kg)=64.4
Filter TOTAL Total - Blank
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Mg
2423
600
192
3921
836
1402
0
1349
2625
2695
0
83
134
1368
266
220
166
266
422
526
0
43
365
625
305
0
0
1846
442
0
897
568
181
197
135
34
70
0
0
0
Mg
2410
596
192
3901
827
1402
0
1335
2598
2695
0
83
134
1368
242
215
163
266
417
526
0
43
365
625
305
0
0
1846
442
0
897
568
181
197
135
34
70
0
0
0
pg/hr
75919.615
18775.141
6048.368
122888.970
26052.084
44165.685
0.000
42055.056
81841.975
84897.660
0.000
2614.659
4221.257
43094.619
7623.463
6772.912
5134.812
8379.509
13136.298
16570.007
0.000
1354.582
11498.199
19688.697
9608.084
0.000
0.000
58152.535
13923.846
0.000
28257.218
17893.088
5701.847
6205.877
4252.759
1071.065
2205.134
0.000
0.000
0.000
|ig/kg (Dry)
89119.424
22039.492
7099.971
144255.134
30581.645
51844.578
0.000
49366.984
96071.479
99658.443
0.000
3069.258
4955.188
50587.291
8948.921
7950.488
6027.579
9836.418
15420.249
19450.961
0.000
1590.098
13497.340
23111.884
11278.599
0.000
0.000
68263.260
16344.724
0.000
33170.176
21004.080
6693.202
7284.866
4992.167
1257.286
2588.531
0.000
0.000
0.000
D-16
-------
Omni - SVOC Compounds
Episode KF-C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Bipbenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluorajithene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
KF05-C
XAD /Rinse Filter TOTAL
12/15/98 12/15/98
ENG1132.D ENG1127.D
02/02/99 02/01/99
8270 Surrogate Compounds
% Recovery
104.13 101.63
132.62 128.05
85.27 100.15
92.06 111.96
134.17 128.06
118.57 102.86
Lab Surrogate Compounds
% Recovery
101.46 89.47
113.89 120.72
84.74 122.94
130.49 108.45
118.70 109.89
Target Compounds
Hours= 168 Dry Fuel (kg)= 154.70
XAD
Mg
4102
820
255
6099
1275
1016
0
985
1932
509
0
71
103
2834
404
313
230
404
424
536
0
45
272
348
133
0
0
518
102
0
172
151
0
0
0
0
0
0
0
0
Filter
ug
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
MS
4102
820
255
6099
1275
1016
0
985
1932
509
0
71
103
2834
404
313
230
404
424
536
0
45
272
348
133
0
0
518
102
0
172
151
0
0
0
0
0
0
0
0
Total - Blank
"8
4089
816
255
6079
1266
1016
0
971
1904
509
0
71
103
2834
380
308
226
404
419
536
0
45
272
348
133
0
0
518
102
0
172
151
0
0
0
0
0
0
0
0
Hg/hr
60505.749
12074.515
3773.286
89952.176
18733.255
15033.955
0.000
14368.081
28173.868
7531.775
0.000
1050.601
1524.112
41935.264
5622.936
4557.537
3344.167
5978.069
6200.027
7931.299
0.000
665.874
4024.838
5149.425
1968.028
0.000
0.000
7664.949
1509.314
0.000
2545.118
2234.377
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
59885.096
11950.657
3734.580
89029.468
18541.093
14879.740
0.000
14220.696
27884.867
7454.515
0.000
1039.824
1508.478
41505.102
5565.257
4510.787
3309.863
5916.747
6136.428
7849.942
0.000
659.044
3983.552
5096.604
1947.840
0.000
0.000
7586.324
1493.832
0.000
2519.011
2211.457
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-17
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FluorophenoI
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD /Rinse
11/15/98
ENG1063.D
01/14/99
104.39
107.00
89.55
108.53
114.40
103.90
99.06
107.34
91.65
100.31
98.32
KF06-A
Filter
11/15/98
ENG1080.D
01/18/99
% Recovery
94.27
95.29
93.60
95.98
101.02
84.01
% Recovery
98.81
101.97
98.87
108.24
83.47
Omni - SVOC Compounds
Episode KF-A
TOTAL
5270 Surrogate Compounds
Lab Surrogate Compounds
Hours=
XAD
Mg
Toluene 10425
m,p-Xy!ene 1282
o-Xylene 448
Phenol 7227
Benzofuran 1751
C3-alkylbenzenes 1175
Decane 0
o-Cresol 2488
m,p-CresoI 3918
C4-alkylbenzenes 7260
Undecane 0
2-Elhylphenol 188
2,3-Dimethylphenol 353
Naphthalene 3907
2-Methylnaphthalene 550
1-Methylnaphthalene 429
Biphenyl 320
Tetradecane 550
C2-alkylnaphthalenes 256
Acenaphthylene 1012
Pentadecane 0
Acenaphthene 0
Dibenzofuran 446
C3-alkylnaphthalenes 195
Fluorene 249
Heptadecane 0
Octadecane 0
Phenanthrene 892
Anthracene 150
Carbazole 0
Fluoranthene 297
Pyrene 230
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Target Compounds
168 Dry Fuel (kg)=l 12.8
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
4
9
10
25
0
11
0
0
0
TOTAL
Hg
10425
1282
448
7227
1751
1175
0
2488
3918
7260
0
188
353
3907
550
429
320
550
256
1012
0
0
446
195
249
0
0
892
150
0
300
234
9
10
25
0
11
0
0
0
Total - Blank
fg
10412
1278
448
7207
1742
1175
0
2475
3891
7260
0
188
353
3907
526
425
317
550
251
1012
0
0
446
195
249
0
0
892
150
0
300
234
9
10
25
0
11
0
0
0
Mg/hr
92263.808
11324.736
3969.860
63863.356
15436.377
10412.022
0.000
21931.706
34479.301
64333.005
0.000
1665.924
3128.037
34621.081
4661.041
3766.051
2809.031
4873.712
2224.185
8967.631
0.000
0.000
3952.138
1727.953
2206.463
0.000
0.000
7904.276
1329.194
0.000
2658.389
2073.543
79.752
88.613
221.532
0.000
97.474
0.000
0.000
0.000
tig/kg (Dry)
137550.016
16883.300
5918.403
95209.659
23013.074
15522.596
0.000
32696.532
51402.911
95909.827
0.000
2483.615
4663.384
51614.283
6948.839
5614.556
4187.798
7265.896
3315.891
13369.249
0.000
0.000
5891.981
2576.090
3289.469
0.000
0.000
11783.962
1981.608
0.000
3963.216
3091.308
118.896
132.107
330.268
0.000
145.318
0.000
0.000
0.000
D-18
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Bipbenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-aIkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aIkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
Episode KF-A
KF07-A
XAD / Rinse Filter TOTAL
11/15/98 11/15/98
ENG1056.D ENG1081.D
01/13/99 01/18/99
5270 Surrogate Compounds
106.28
116.57
106.51
100.49
1 12.42
112.78
104.42
104.35
88.27
111.82
110.00
% Recovery
93.18
99.94
95.44
84.57
91.81
86.27
% Recovery
104.21
93.25
89.59
100.20
87.32
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
Mg
11732
2003
659
16277
2769
3431
0
4206
8800
9251
0
311
492
4608
794
618
349
794
686
926
0
0
568
586
285
0
0
1090
162
0
323
233
0
0
0
0
0
0
0
0
168.25 Dry Fuel (kg)=140.8
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
11
3
0
26
23
28
32
68
0
23
0
0
0
TOTAL
Mg
11732
2003
659
16277
2769
3431
0
4206
8800
9251
0
311
492
4608
794
618
349
794
686
926
0
0
568
586
285
0
0
1101
165
0
349
255
28
32
68
0
23
0
0
0
Total - Blank
Mg
11719
1999
659
16257
2761
3431
0
4192
8772
9251
0
311
492
4608
769
613
345
794
681
926
0
0
568
586
285
0
0
1101
165
0
349
255
28
32
68
0
23
0
0
0
Mg/hr
157190.252
26813.151
8839.353
218059.725
37034.072
46020.970
0.000
56228.478
117661.310
124086.272
0.000
4171.531
6599.335
61808.403
10314.814
8222.342
4627.582
10650.146
9134.445
12420.699
0.000
0.000
7618.744
7860.183
3822.785
0.000
0.000
14768.023
2213.192
0.000
4681.235
3420.387
375.572
429.225
912.103
0.000
308.505
0.000
0.000
0.000
ug/kg (Dry)
187453.923
31975.458
10541.184
260042.531
44164.202
54881.339
0.000
67054.087
140314.516
147976.469
0.000
4974.671
7869.898
73708.309
12300.714
9805.381
5518.526
12700.607
10893.090
14812.043
0.000
0.000
9085.573
9373.496
4558.782
0.000
0.000
17611.295
2639.295
0.000
5582.509
4078.910
447.880
511.863
1087.709
0.000
367.902
0.000
0.000
0.000
D-19
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
Omni - SVOC Compounds
Episode KF-B
KF07-B
XAD/ Rinse Filter TOTAL
12/15/98 12/15/98
ENG1133.D ENG1131.D
02/02/99 02/02/99
Hours=
XAD
Toluene 8914
m,p-Xylene 1248
o-Xylene 407
Phenol 10504
Benzofuran 1668
C3-alkylbenzenes 1542
Decane 0
o-Cresol 2942
m,p-Cresol 4725
C4-alkylbenzenes 6682
Undecane 0
2-Ethylphenol 192
2,3-Dimethylphenol 399
Naphthalene 3249
2-Methylnaphthalene 420
l-Methylnaphthalene 352
Biphenyl 226
Tetradecane 420
C2-alkylnaphthaIenes 414
Acenaphthylene 575
Pentadecane 0
Acenaphthene 0
Dibenzofuran 388
C3-alkylnaphthalenes 208
Fluorene 185
Heptadecane 0
Octadecane 0
Phenanthrene 750
Anthracene 123
Carbazole 0
Fluoranthene 238
Pyrene 208
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(lJ,3-cd)pyrenc 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
8270 Surrogate Compounds
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6- Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
92.46
100.91
77.25
84.52
98.01
114.32
89.74
86.21
81.88
101.74
109.16
% Recovery
141.25
138.59
130.90
115.12
119.20
105.42
% Recovery
135.93
125.48
119.07
132.36
102.99
Lab Surrogate Compounds
Target Compounds
168 Dry Fuel (kg)=l 19.7
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15
12
21
24
52
0
17
0
0
0
TOTAL
Mg
8914
1248
407
10504
1668
1542
0
2942
4725
6682
0
192
399
3249
420
352
226
420
414
575
0
0
388
208
185
0
0
750
123
0
254
220
21
24
52
0
17
0
0
0
Total • Blank
Mg
8901
1244
407
10484
1659
1542
0
2929
4697
6682
0
192
399
3249
396
347
222
420
409
575
0
0
388
208
185
0
0
750
123
0
• 254
220
21
24
52
0
17
0
0
0
(Jg/hr
114212.167
15962.244
5222.374
134524.251
21287.269
19785.997
0.000
37583.130
60269.020
85739.321
0.000
2463.626
5119.723
41689.173
5081.229
4452.491
2848.568
5389.182
5248.037
7378.047
0.000
0.000
4978.578
2668.928
2373.806
0.000
0.000
9623.539
1578.260
0.000
3259.172
2822.905
269.459
307.953
667.232
0.000
218.134
0.000
0.000
0.000
Hg/kg (Dry)
153041.102
21388.960
6997.835
180258.726
28524.344
26512.682
0.000
50360.340
80758.798
114888.287
0.000
3301.190
6860.285
55862.324
6808.704
5966.213
3817.001
7221.353
7032.222
9886.376
0.000
0.000
6671.155
3576.289
3180.834
0.000
0.000
12895.273
2114.825
0.000
4367.199
3782.613
361.068
412.649
894.072
0.000
292.293
0.000
0.000
0.000
D-20
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobipbenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimcthylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aJkyInaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aJkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)nuoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
Episode KF-C
KF07-C
XAD /Rinse Filter TOTAL
12/15/98 12/15/98
ENG1134.D ENG1140.D
02/02/99 02/03/99
8270 Surrogate Compounds
84.57
104.07
91.75
86.76
95.12
99.98
84.91
83.81
78.09
100.40
96.43
% Recovery
116.80
118.43
121.48
95.61
107.59
106.34
% Recovery
128.41
98.07
101.18
108.57
104.97
Lab Surrogate Compounds
Target Compounds
Hours= 168 Dry Fuel (kg)=l 97.70
XAD
Mg
11561
1666
548
15789
2621
2295
0
3826
8713
6533
0
260
488
5939
789
632
312
789
611
1091
0
115
524
409
319
0
0
1475
236
0
426
307
0
0
0
0
0
0
0
0
Filter
Mg
0
0
0
7
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
40
9
0
66
55
51
55
101
20
41
0
0
0
TOTAL
Mg
11561
1666
548
15796
2621
2295
0
3826
8713
6533
0
260
488
5939
789
632
312
789
611
1091
0
115
524
409
319
0
0
1515
245
0
492
361
51
55
101
20
41
0
0
0
Total - Blank
eg
11548
1662
548
15776
2612
2295
0
3813
8686
6533
0
260
488
5939
764
627
309
789
606
1091
0
115
524
409
319
0
0
1515
245
0
492
361
51
55
101
20
41
0
0
0
Mg/hr
174521.555
25117.321
8281.764
238418.085
39474.394
34683.665
0.000
57624.757
131268.984
98731.323
0.000
3929.304
7375.002
89754.374
11546.109
9475.668
4669.827
11923.927
9158.301
16487.965
0.000
1737.961
7919.059
6181.098
4820.954
0.000
0.000
22895.753
3702.614
0.000
7435.452
5455.688
770.748
831.199
1526.384
302.254
619.621
0.000
0.000
0.000
Hg/kg (Dry)
148737.926
21406.515
7058.225
203194.451
33642.489
29559.538
0.000
49111.336
111875.444
84144.862
0.000
3348.793
6285.427
76494.158
9840.299
8075.743
3979.912
10162.299
7805.264
14052.050
0.000
1481.197
6749.106
5267.909
4108.711
0.000
0.000
19513.159
3155.593
0.000
6336.947
4649.670
656.879
708.399
1300.877
257.599
528.079
0.000
0.000
0.000
D-21
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-d5
2-FIuorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalenc
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aIkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Omni - SVOC Compounds
Episode KF-A
XAD /Rinse
11/15/98
ENG1066.D
01/15/99
99.80
115.80
103.21
98.71
113.94
102.30
106.08
100.46
94.16
110.55
103.81
Hours=
XAD
14591
2417
842
15830
3594
5071
0
3858
6672
20980
0
309
449
7836
1277
1076
578
1277
1055
2002
0
0
846
892
523
0
0
2142
329
0
679
472
151
133
0
0
0
0
0
0
KF08-A
Filter
11/15/98
ENG1082.D
01/18/99
% Recovery
97.21
102.18
104.05
87.87
99.63
85.72
% Recovery
102.79
96.87
95.66
100.30
90.44
TOTAL
5270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
168 Dry Fuel (kg)= 188
Filter TOTAL Total - Blank
fg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
0
3
4
9
12
47
0
23
0
0
0
MS
14591
2417
842
15830
3594
5071
0
3858
6672
20980
0
309
449
7836
1277
1076
578
1277
1055
2002
0
0
846
892
523
0
0
2145
329
0
682
476
160
145
47
0
23
0
0
0
Mg
14579
2413
842
15810
3585
5071
0
3844
6644
20980
0
309
449
7836
1253
1071
575
1277
1050
2002
0
0
846
892
523
0
0
2145
329
0
682
476
160
145
47
0
23
0
0
0
fig/hr
257767.402
42663.608
14887.177
279532.384
63385.427
89658.996
0.000
67964.736
117470.788
370941.772
0.000
5463.346
7938.649
138546.221
22153.958
18936.065
10166.421
22578.296
18564.769
35396.827
0.000
0.000
14957.900
15771.214
9247.023
0.000
0.000
37925.172
5816.961
0.000
12058.260
8416.029
2828.917
2563.706
830.994
0.000
406.657
0.000
0.000
0.000
Hg/kg (Dry)
230525.782
38154.792
13313.856
249990.576
56686.668
80183.568
0.000
60782.022
105056.128
331739.550
0.000
4885.964
7099.669
123904.247
19812.662
16934.845
9092.004
20192.155
16602.790
31655.986
0.000
0.000
13377.105
14104.465
8269.770
0.000
0.000
33917.127
5202.207
0.000
10783.907
7526.598
2529.949
2292.766
743.172
0.000
363.680
0.000
0.000
0.000
D-22
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
XAD/Rinse
12/15/98
ENG1135J)
02/02/99
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Antljracene-dlO
Pyrene-dlO
97.61
1 14.80
86.69
88.53
96.59
109.19
99.99
96.85
89.72
104.31
111.02
% Recovery
124.10
121.06
161.55
88.21
113.81
113.18
% Recovery
121.58
92.15
101.63
123.16
113.41
Hours=
XAD
Toluene 12776
m,p-Xylene 2249
o-Xylene 782
Phenol 13084
Benzofuran 2468
C3-alkylbenzenes 4079
Dccane 0
o-Cresol 3132
m,p-Cresol 4946
C4-alkylbenzenes 17248
Undecane 0
2-EtbylphenoI 194
2,3-Dimethylphenol 332
Naphthalene 4456
2-MetbylnaphthaIene 636
1-Methylnaphthalene 487
Biphenyl 257
Tetradecane 636
C2-alkylnaphthalenes 512
Acenaphthylene 705
Pentadecane 0
Acenaphthene 0
Dibenzofuran 261
C3-alkylnapbthalenes 0
Fluorene 136
Heptadecane 0
Octadecane 0
Pbenanthrene 329
Anthracene 0
Carbazole 0
Fluoranthene 106
Pyrene 86
Benzo(a)antbracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Omni - SVOC Compounds
Episode KF-B
KF08-B
Filter TOTAL
12/15/98
ENG1141.D
02/03/99
8270 Surrogate Compounds
% Recovery
124.10
121.06
161.55
88.21
113.81
113.18
Lab Surrogate Compounds
% Recovery
121.58
92.15
101.63
123.16
113.41
Target Compounds
172.75 Dry Fuel (kg)= 189
Filter
fg
0
0
0
252
0
0
0
77
608
0
0
14
74
0
0
0
0
0
0
197
0
0
253
0
159
0
0
643
158
0
251
176
64
62
99
0
0
0
0
0
TOTAL
Pg
12776
2249
782
13336
2468
4079
0
3209
5553
17248
0
208
406
4456
636
487
257
636
512
902
0
0
514
0
295
0
0
972
158
0
357
262
64
62
99
0
0
0
0
0
Total - Blank
Mg
12764
2245
782
13316
2460
4079
0
3195
5526
17248
0
208
406
4456
612
482
253
636
507
902
0
0
514
0
295
0
0
972
158
0
357
262
64
62
99
0
0
0
0
0
pg/hr
287951.093
50646.365
17641.629
300404.008
55496.685
92020.723
0.000
72078.012
124664.505
389108.466
0.000
4692.403
9159.209
100525.703
13806.492
10873.741
5707.586
14347.923
11437.731
20348.785
0.000
0.000
11595.649
0.000
6655.090
0.000
0.000
21927.959
3564.421
0.000
8053.787
5910.623
1443.816
1398.697
2233.403
0.000
0.000
0.000
0.000
0.000
Hg/kg (Dry)
258807.708
45520.472
15856.129
270000.270
49879.894
82707.352
0.000
64783.033
112047.273
349726.994
0.000
4217.487
8232.210
90351.547
12409.144
9773.215
5129.924
12895.777
10280.124
18289.294
0.000
0.000
10422.059
0.000
5981.532
0.000
0.000
19708.641
3203.668
0.000
7238.667
5312.411
1297.688
1257.136
2007.362
0.000
0.000
0.000
0.000
0.000
D-23
-------
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-dl4
Toluene-d8
Bipbenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkyibenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkyIbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1^3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
XAD/ Rinse
12/15/98
ENG1138.D
02/03/99
93.76
104.36
86.76
85.43
92.75
104.96
84.97
93.20
76.58
98.71
102.96
Hours=
XAD
Mg
11642
1684
549
14419
2767
2147
0
2448
4274
6747
0
140
212
8342
989
732
457
989
542
1674
0
101
657
316
406
0
0
2102
298
0
740
513
163
166
0
0
0
0
0
0
Filter
12/15/98
ENG1142.D
02/03/99
% Recovery
108.59
107.40
110.15
97.85
118.73
106.37
% Recovery
92.61
98.61
109.85
107.76
105.66
171
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
8
37
0
19
0
0
0
Omni - SVOC Compounds
Episode KF-C
KF08-C
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Dry Fuel (kg)= 205.00
TOTAL
Mg
11642
1684
549
14419
2767
2147
0
2448
4274
6747
0
140
212
8342
989
732
457
989
542
1674
0
101
657
316
406
0
0
2102
298
0
740
513
170
174
37
0
19
0
0
0
Total - Blank
Mg
11629
1680
549
14398
2758
2147
0
2434
4247
6747
0
140
212
8342
964
728
453
989
538
1674
0
101
657
316
406
0
0
2102
298
0
740
513
170
174
37
0
19
0
0
0
ug/hr
199790.811
28863.063
9432.037
247363.324
47383.529
36886.308
0.000
41817.081
72965.137
115916.123
0.000
2405.255
3642.244
143318.853
16561.901
12507.327
7782.719
16991.410
9243.052
28759.981
0.000
1735.220
11287.519
5429.005
6975.240
0.000
0.000
36113.190
5119.758
0.000
12713.492
8813.543
2920.667
2989.389
635.675
0.000
326.428
0.000
0.000
0.000
fig/kg (Dry)
166323.338
24028.137
7852.052
205926.857
39446.192
30707.387
0.000
34812.194
60742.559
96498.716
0.000
2002.345
3032.122
119311.143
13787.574
10412.193
6479.016
14145.136
7694.725
23942.322
0.000
1444.549
9396.718
4519.578
5806.800
0.000
0.000
30063.776
4262.134
0.000
10583.822
7337.163
2431.419
2488.629
529.191
0.000
271.747
0.000
0.000
0.000
D-24
-------
Blank Data - Klamath Falls
D-25
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name: XAD Cleaning Blk (190mL)
Sample Type: Blank
Sample Date: 12/07/99
File Name: ENG1067.D
Analysis Date: 1/15/1999
8270 Surrogate Compounds
% Recovery
2-Fluorophenol NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-FIuorobiphenyl NA
2,4,6-Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
rig
Toluene 4.56
m,p-Xylene 0.00
o-Xylene 0.00
Phenol 0.00
Benzofuran 0.00
1,2,4-Trimethylbenzene 0.00
Decane 0.00
o-Cresol 0.00
m,p-Cresol 0.00
1,4-Diethylbenzene 0.00
UOecane 0.00
2-Ethylphenol 0.00
1,2,4,5-Tetramethylbenzene 0.00
2,3-Dimethylphenol 0.00
Naphthalene 0.00
2-Methylnaphthalene 0.00
1-Methylnaphthalene 0.00
Biphenyl 0.00
Tetradecane 0.00
1-Ethylnaphthalene 0.00
2,6-Dimethylnaphthalene 0.00
Acenaphthylene 0.00
Pentadecane 0.00
Acenaphtbene 0.00
Dibenzofuran 0.00
2,3,5-TrimethyInaphthalene 0.00
Fluorene 0.00
Heptadecane 0.00
Octadecane 0.00
Phenanthrene 0.00
Anthracene 0.00
Carbazole 0.00
Fluoranthene 0.00
Pyrene 0.00
Benzo(a)anthracene 0.00
Chrysene 0.00
Benzo(b)fluoranthene 0.00
Benzo(k)fluoranthene 0.00
Benzo(a)pyrene 0.00
I0eno(l,23-cd)pyrene 0.00
D-26
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name: XAD Cleaning Blk (200mL)
Sample Type: Blank
Sample Date: 12/07/99
File Name: ENG1068.D
Analysis Date: 01/15/99
8270 Surrogate Compounds
% Recovery
2-FIuorophenol NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-Fluorobiphenyl NA
2,4,6-Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
Mg
Toluene 7.66
m,p-Xylene 0.00
o-Xylene 0.00
Phenol 0.00
Benzofuran 0.00
1,2,4-TrimethyIbenzene 0.00
Decane 0.00
o-Cresol 0.00
m,p-Cresol 0.00
1,4-DiethyIbenzene 0.00
UOecane 0.00
2-Ethylphenol 0.00
1,2,4,5-Tetramethylbenzene 0.00
2,3-Dimethylphenol 0.00
Naphthalene 0.00
2-Methylnaphthalene 0.00
1-Methy (naphthalene 0.00
Biphenyl 0.00
Tetradecane 0.00
1-Ethylnaphthalene 0.00
2,6-Dimethylnaphthalene 0.00
Acenaphthylene 0.00
Pentadecane 0.00
Acenaphthene 0.00
Dibenzofuran 0.00
2,3,5-Trimethylnaphthalene 0.00
Fluorene 0.00
Heptadecane 0.00
Octadecane 0.00
Phenanthrene 0.00
Anthracene 0.00
Carbazole 0.00
Fluoranthene 0.00
Pyrene 0.00
Benzo(a)anthracene 0.00
Chrysene 0.00
Benzo(b)fluoranthene 0.00
Benzo(k)fluoranthene 0.00
Benzo(a)pyrene 0.00
I0eno(l,2,3-cd)pyrene 0.00
D-27
-------
Omni -Blanks
Episode A, B, and C of KF
Sample Name: KF-RB-MeOH
Sample Type: Blank
Sample Date: 12/04/99
File Name: ENG1069.D
Analysis Date: 1/15/1999
8270 Surrogate Compounds
% Recovery
2-Fluorophenol NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-Fluorobiphenyl NA
2,4,6- Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
Mg
Toluene 0.00
m,p-Xylene 0.00
o-Xylene 0.00
Phenol 0.00
Benzofuran 0.00
1,2,4-Trimethylbenzene 0.00
Decane 0.00
o-Cresol 0.00
m,p-Cresol 0.00
1,4-Diethylbenzene 0.00
UOecane 0.00
2-Ethylphenol 0.00
1,2,4,5-Tetramethylbenzene 0.00
2,3-Dimethylphenol 0.00
Naphthalene 0.00
2-Methylnaphthalene 0.00
1-Methylnaphthalene 0.00
Biphenyl 0.00
Tetradecane 0.00
l-Ethylnaphthalene 0.00
2,6-Dimethylnaphthalene 0.00
Acenaphthylene 0.00
Pentadecane 0.00
Acenaphthene 0.00
Dibenzofuran 0.00
2,3,5-Trimethylnaphthalene 0.00
Fluorene 0.00
Heptadccane 0.00
Octadecane 0.00
Phenanthrene 0.00
Anthracene 0.00
Carbazole 0.00
Fluoranthene 0.00
Pyrene 0.00
Benzo(a)anthracene 0.00
Chrysene 0.00
Benzo(b)fluoranthene 0.00
Benzo(k)fluoranthene 0.00
Benzo(a)pyrene 0.00
I0eno(lr23-cd)pyrene 0.00
D-28
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethy Ibenzene
Decane
o-Cresol
m,p-CresoI
1,4-Die thy Ibenzene
UOecane
2-Ethylphenol
1,2,4,5-Tetramethylbenzene
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradccane
1-Ethylnaphthalene
2,6-Diraethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Trimethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
KF-RB-MeC12
Blank
12/04/99
ENG1070.D
01/15/99
8270 Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
NA
Lab Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
Target Compounds
Filter
Mg
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-29
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethylbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-Ethylphenol
1,2,4,5-Tetramethylbenzene
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
1 -Ethy Inaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Triniethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
KFB1-B Filter
Filter
12/15/98
ENG1111.D
01/29/99
8270 Surrogate Compounds
% Recovery
107.03
108.58
81.20
82.41
90.61
95.65
Lab Surrogate Compounds
% Recovery
115.40
88.02
91.18
96.27
101.85
Target Compounds
Filter
MS
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-30
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
KFB-B MeOH/MeC12
Rinse
12/21798
ENG1086.D
01/27/99
$270 Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
NA
Lab Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
Target Compounds
Rinse
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethylbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-Ethylphenol
1,2,4^-Tetramethy Ibenzene
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
1-Ethylnaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Trimethylnaphthalcne
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Bcnzo(k)fluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-31
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
KFB-B-XAD
XAD
12/28/98
ENG1093.D
01/27/99
8270 Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
NA
Lab Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
Target Compounds
XAD
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethylbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-EthyIpbenol
1,2,4,5-Tetramethylbenzene
2,3-DimethyIphenol
Naphthalene
2-Methylnaphthalene
1 -Methylnaph thalene
Biphenyl
Tetradecane
1-Ethylnaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Trimethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-32
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribroraophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethylbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-Ethylphenol
1,2,4,5-Tetramethylbenzene
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
1-Ethylnaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2.3,5-Trimethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
KFB1-C-F
Filter
12/28/98
ENG1112.D
01/29/99
8270 Surrogate Compounds
% Recovery
101.74
111.77
84.98
94.40
93.66
103.76
Lab Surrogate Compounds
% Recovery
105.30
93.78
92.51
107.40
110.22
Target Compounds
Filter
Mg
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-33
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Bipbenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
KFB-C MeC12/MeOH
Rinse
12/30/98
ENG1102.D
01/28/99
8270 Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
NA
Lab Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
Target Compounds
Rinse
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimethy Ibenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-EthyIphenol
1,2,4,5-Tetrarnethylbenzene
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
1 -Ethy Inaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Trimethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrcne
I0eno(l,2,3-cd)pyrene
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-34
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name: KFB-C XAD
Sample Type: XAD
Sample Date: 12/28/98
File Name: ENG1106.D
Analysis Date: 01/29/99
8270 Surrogate Compounds
% Recovery
2-FIuorophenoI NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-Fluorobiphenyl NA
2,4,6-Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
XAD
Mg
Toluene 13
m,p-Xylene 4
o-Xylene 0
Phenol 20
Benzofuran 9
1,2,4-Trimethylbenzene 0
Decane 0
o-Cresol 14
m,p-Cresol 27
1,4-Dietbylbenzene 0
UOecane 0
2-Ethylphenol 0
1,2,4,5-Tetramethylbenzene 0
2,3-Dimethylphenol 0
Naphthalene 24
2-Methylnaphthalene 5
1-Methylnaphthalene 3
Biphenyl 0
Tetradecane 5
1-Ethylnaphthalene 0
2,6-Dimethylnaphthalene 0
Acenaphthylene 0
Pentadecane 0
Acenaphthene 0
Dibenzofuran 0
2,33-Trimethylnaphthalene 0
Fluorene 0
Heptadecane 0
Octadecane 0
Phenanthrene 0
Anthracene 0
Carbazole 0
Fluoranthene 0
Pyrene 0
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
I0eno(l,2,3-cd)pyrene 0
D-35
-------
Omni -Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terpbenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
KFLB-BC FUter
Filter
12/15/98
ENG1107.D
01/29/99
8270 Surrogate Compounds
% Recovery
111.58
107.33
92.53
89.54
100.76
105.03
Lab Surrogate Compounds
% Recovery
120.33
99.40
99.13
104.85
106.93
Target Compounds
Rinse
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-TrimethyIbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethylbenzene
UOecane
2-Ethylphenol
1,2,4,5-Tetramethylbenzene
2,3-DimethylphenoI
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
1-Ethylnaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-TrimethylnaphthaIene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-36
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluoropbenol
Phenol-d6
Nitrobenzene-d5
2-FluorobiphenyI
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
1,2,4-Trimetbylbenzene
Decane
o-Cresol
m,p-Cresol
1,4-Diethy Ibenzene
UOecane
2-Ethylphenol
1 ,2,4,5-Tetramethylbenzene
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
1-Ethylnaphthalene
2,6-Dimethylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
2,3,5-Trimethylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzol klfluoranthene
Benzo(a)pyrene
I0eno(l,2,3-cd)pyrene
KFRB-BC MeC12 BLK
Blank
ENG1101.D
01/28/99
8270 Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
NA
Lab Surrogate Compounds
% Recovery
NA
NA
NA
NA
NA
Target Compounds
Blank
MS
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-37
-------
Omni - Blanks
Episode A, B, and C of KF
Sample Name: Omni: KF-A-LB-F
Sample Type: Filter
Sample Date:
File Name: ENG10S3.D
Analysis Date: 01/18/99
8270 Surrogate Compounds
% Recovery
2-FIuorophenol 94.66
Phenol-d6 92.25
Nitrobenzene-dS 111.54
2-Fluorobiphenyl 92.71
2,4,6-Tribromophenol 102.41
p-Terphenyl-dl4 97.32
Lab Surrogate Compounds
% Recovery
Toluene-d8 104.21
Bipbenyl-dlO 93.01
Fluorene-dlO 95.95
Anthracene-dlO 103.58
Pyrene-dlO 95.29
Target Compounds
Blank
MS
Toluene 7.16
m,p-Xylene 0.00
o-Xylene 0.00
Phenol 0.00
Benzofuran 0.00
1,2,4-Trimethylbenzene 0.00
Decane 0.00
o-Cresol 0.00
m,p-Cresol 0.00
1,4-Diethylbenzene 0.00
UOecane 0.00
2-EthylphenoI 0.00
1,2,4,5-Tetramethylbenzene 0.00
2,3-DimethylphenoI 0.00
Naphthalene 0.00
2-MethylnaphthaIene 0.00
1-Methylnaphthalene 0.00
Biphenyl 0.00
Tetradecane 0.00
l-Ethylnaphthalene 0.00
2,6-Dimethylnaphthalene 0.00
Acenaphthylene 0.00
Pentadecane 0.00
Acenapbthene 0.00
Dibenzofuran 0.00
2,3,5-TrimethylnaphthaIene 0.00
Fluorene 0.00
Heptadecane 0.00
Octadecane 0.00
Pbenanthrene 0.00
Anthracene 0.00
Carbazole 0.00
Fluoranthene 0.00
Pyrene 0.00
Benzo(a)anthracene 0.00
Chrysene 0.00
Benzo(b)fluoranthene 0.00
Benzo(k)nuoranthene 0.00
Benzo(a)pyrene 0.00
I0eno(l,2,3-cd)pvrene 0.00
D-38
-------
Organic Compound Analysis Data by Test - Portland
D-39
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-dl4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD/ Rinse
01/22/99
ENG1200.D
03/29/99
105.07
106.46
110.56
100.07
112.89
94.49
117.09
109.60
97.72
104.47
93.36
Filter
01/22/99
ENG1191.D
03/26/99
% Recovery
100.50
97.11
119.27
93.99
111.83
102.69
% Recovery
101.50
98.16
97.23
104.77
101.44
P01-A
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Hours=
XAD
Mg
Toluene 23005
m,p-Xylene 6819
o-Xylene 2339
Phenol 46533
Benzofuran 10421
C3-alkylbenzenes 972
Decane 0
o-Cresol 18323
m,p-Cresol 26016
C4-alkylbenzenes 778
Undecane 0
2-Ethylphenol 1163
23-Dimethylphenol 1331
Naphthalene 13352
2-Methylnaphthalene 2500
1-Methylnaphthalene 1782
Biphenyl 1212
Tetradecane 2500
C2-alkylnaphthalenes 209
Acenaphthylene 3188
Pentadecane 0
Acenaphthene 308
Dibenzofuran 1918
C3-alkylnaphthalenes 145
Fluorene 1183
Heptadecane 0
Octadecane 0
Phenanthrene 2564
Anthracene 619
Carbazole 0
Fluoranthene 896
Pyrene 712
Benzo(a)anthracene 176
Chrysene 185
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2t3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Target Compounds
171.25 Dry Fuel (kg)=209 8
Filter
Mg
0
0
0
173
0
0
0
31
86
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15
6
0
32
38
64
71
158
46
87
0
0
0
TOTAL
Mg
23005
6819
2339
46707
10421
972
0
18354
26102
778
0
1163
1331
13352
2500
1782
1212
2500
209
3188
0
308
1918
145
1183
0
0
2579
625
0
929
749
240
256
158
46
87
0
0
0
Total - Blank
Mg
22987.81
6818.55
2338.87
46679.77
10420.90
971.71
0.00
18345.42
26081.68
777.77
0.00
1163.22
1331.14
13346.77
2500.36
1782.48
1211.76
2500.36
208.70
3188.44
0.00
307.60
1917.97
145.20
1182.86
0.00
0.00
2576.29
625.43
0.00
928.76
749.47
239.94
256.32
157.83
46.40
86.87
0.00
0.00
0.00
ug/hr
321762.469
95439.865
32737.376
653380.990
145862.286
13601.113
0.000
256782.514
365067.649
10886.517
0.000
16281.696
18632.088
186815.955
34997.767
24949.535
16961.115
34997.767
2921.193
44628.885
0.000
4305.505
26846.001
2032.378
16556.599
0.000
0.000
36060.566
8754.201
0.000
12999.938
10490.400
3358.462
3587.734
2209.161
649.465
1215.927
0.000
0.000
0.000
|ig/kg (Dry)
262825.864
77958.331
26740.935
533702.467
119144.975
11109.824
0.000
209748.161
298198.919
8892.455
0.000
13299.410
15219.285
152597.240
28587.294
20379.577
13854.381
28587.294
2386.124
36454.299
0.000
3516.874
21928.671
1660.111
13523.959
0.000
0.000
29455.422
7150.711
0.000
10618.765
8568.894
2743.299
2930.576
1804.513
530.504
993.208
0.000
0.000
0.000
D-40
-------
Omni - SVOC Compounds
EpisodeB
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD/ Rinse
01/28/99
ENG1237.D
04/01/99
83.03
89.68
95.09
78.25
94.63
76.34
94.30
85.49
75.20
80.78
72.54
Filter
01/28/99
ENG1223.D
03/31/99
% Recovery
94.35
89.48
96.60
90.93
122.35
103.04
% Recovery
85.44
91.25
93.85
101.01
97.74
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkyIbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,23-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P01-B
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
fg
19902
4897
1697
37781
7657
1286
0
13559
17160
2992
0
889
1245
12125
1908
1453
925
1908
567
2537
0
210
1618
189
945
0
0
2412
509
0
827
743
155
173
0
0
0
0
0
0
168.25 Dry Fuel (kg)=209
Filter
Mg
0
0
0
15
0
0
0
0
10
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
6
0
37
44
60
70
180
42
102
0
0
0
TOTAL
Mg
19902
4897
1697
37796
7657
1286
0
13559
17170
2992
0
889
1245
12125
1908
1453
925
1908
567
2537
0
210
1618
189
945
0
0
2422
514
0
864
787
215
244
180
42
102
0
0
0
Total - Blank
eg
19884.81
4897.22
1696.90
37768.83
7656.88
1285.78
0.00
13550.49
17149.16
2992.28
0.00
889.22
1245.45
12119.78
1908.39
1452.85
925.40
1908.39
566.69
2537.03
0.00
210.24
1617.77
189.05
944.56
0.00
0.00
2419.11
514.22
0.00
863.56
786.85
215.19
243.54
180.34
42.16
102.10
0.00
0.00
0.00
fig/hr
277623.588
68372.984
23691.424
527312.964
106902.228
17951.535
0.000
189186.402
239429.561
41776.990
0.000
12414.926
17388.464
169211.414
26644.161
20284.098
12920.056
26644.161
7911.894
35420.976
0.000
2935.285
22586.643
2639.439
13187.561
0.000
0.000
33774.625
7179.329
0.000
12056.672
10985.678
3004.395
3400.206
2517.833
588.621
1425.478
0.000
0.000
0.000
tig/kg (Dry)
223652.605
55081.040
19085.730
424801.506
86120.067
14461.694
0.000
152407.913
192883.629
33655.399
0.000
10001.422
14008.086
136316.131
21464.444
16340.799
10408.353
21464.444
6373.795
28535.016
0.000
2364.655
18195.722
2126.323
10623.853
0.000
0.000
27208.721
5783.643
0.000
9712.813
8850.024
2420.330
2739.194
2028.358
474.191
1148.361
0.000
0.000
0.000
D-41
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
XAD /Rinse
02/19/99
ENG1273.D
04/06799
77.17
91.32
56.28
55.86
55.60
55.09
81.58
59.68
45.44
55.57
53.89
Filter
02/19/99
ENG1242.D
04/01799
% Recovery
92.06
97.33
92.04
95.19
124.12
108.85
% Recovery
97.44
90.96
96.71
102.62
102.31
P01-C
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Hours=
XAD
Mg
Toluene 23179
m,p-Xylene 5384
o-Xylene 1837
Phenol 54925
Benzofuran 8312
C3-alkylbenzenes 5081
Decane 0
o-Cresol 15101
m,p-Cresol 23531
C4-alkylbenzenes 2408
Undecane 0
2-Ethylphenol 909
2,3-Dimethylphenol 1179
Naphthalene 13918
2-Methylnaphthalene 1873
1-Methylnaphthalene 1368
Biphenyl 1006
Tetradecane 1873
C2-alkylnaphthalenes 1226
Acenaphthylene 2710
Pentadecane 0
Acenaphthene 201
Dibenzofuran 1484
C3-alkylnaphthalenes 573
Fluorene 843
Heptadecane 0
Octadecane 0
Phenanthrene 2552
Anthracene 514
Carbazole 0
Fluoranthene 737
Pyrene 778
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
Target Compounds
168 Dry Fuel (kg)=210.9
Filter
Mg
0
0
0
41
0
0
0
0
26
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13
6
0
36
38
59
69
198
44
112
0
0
0
TOTAL
Mg
23179
5384
1837
54966
8312
5081
0
15101
23557
2408
0
909
1179
13918
1873
1368
1006
1873
1226
2710
0
201
1484
573
843
0
0
2564
520
0
774
816
59
69
198
44
112
0
0
0
Total - Blank
Mg
23162.24
5383.62
1836.55
54939.30
8312.09
5081.38
0.00
15092.30
23536.09
2407.73
0.00
909.34
1179.13
13913.59
1873.02
1367.69
1006.02
1873.02
1226.45
2709.89
0.00
200.81
1484.35
573.21
842.54
0.00
0.00
2561.29
520.08
0.00
773.61
815.94
58.91
68.58
198.32
44.12
111.84
0.00
0.00
0.00
|ig/hr
302037.174
70202.768
23948.736
716412.182
108390.215
66261.538
0.000
196804.611
306912.203
31396.962
0.000
11857.855
15375.935
181434.153
24424.307
17834.770
13118.569
24424.307
15992.991
35337.149
0.000
2618.576
19356.024
7474.697
10986.778
0.000
0.000
33399.395
6781.878
0.000
10087.927
10639.913
768.190
894.288
2586.106
575.328
1458.401
0.000
0.000
0.000
jig/kg (Dry)
240871.035
55985.868
19098.831
571330.149
86439.900
52842.785
0.000
156949.324
244758.812
25038.702
0.000
9456.498
12262.124
144691.568
19478.093
14223.016
10461.902
19478.093
12754.219
28180.953
0.000
2088.283
15436.198
5960.982
8761.824
0.000
0.000
26635.618
5408.467
0.000
8045.001
8485.203
612.623
713.184
2062.389
458.817
1163.057
0.000
0.000
0.000
D-42
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-dfi
Nitrobenzene-d5
2-Fluorobipbenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toiuene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-aIkylbenzenes
Undecane
2-Ethylphenol
2,3-DimethyIphenol
Naphthalene
2-Methylnaphthalene
1-Methy (naphthalene
Biphenyl
Tetradecane
C2-aIkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alky (naphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P02-A
XAD/Rinse
01/22/99
ENG1206.D
03/30/99
94.34
89.65
94.51
85.84
92.04
91.25
101.43
89.97
77.44
89.38
84.58
Hours=
XAD
Mg
4897
1012
379
8058
1594
1262
0
2665
3819
514
0
184
265
3606
420
346
256
420
268
813
0
0
347
0
221
0
0
532
117
0
209
193
0
0
0
0
0
0
0
0
Filter
01/22/99
ENG1192.D
03/26/99
% Recovery
98.50
96.42
106.45
98.29
114.04
98.08
% Recovery
86.92
108.78
104.81
105.57
96.27
168 Di
Filter
Mg
0
0
0
70
0
0
0
7
24
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
0
0
10
11
12
13
25
0
17
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
'uel (kg)=58.5
TOTAL Total - Blank
Mg ug ug/hr ug/kg(Dry)
4897 4879.75 130335.462 205882.325
1012 1011.83 27025.428 42690.284
379 379.49 10135.971 16011.124
8128 8101.08 216375.431 341793.982
1594 1593.93 42573.001 67249.759
1262 1262.28 33714.811 53257.060
0 0.00 0.000 0.000
2672 2663.14 71131.018 112360.972
3842 3821.80 102078.195 161246.184
514 514.25 13735.337 21696.805
0 0.00 0.000 0.000
184 184.37 4924.422 7778.785
265 265.00 7078.006 11180.658
3606 3600.97 96179.946 151929.110
420 419.57 11206.486 17702.146
346 345.93 9239.602 14595.189
256 255.69 6829.341 10787.858
420 419.57 11206.486 17702.146
268 267.98 7157.600 11306.388
813 813.48 21727.607 34321.667
0 0.00 0.000 0.000
0 0.00 0.000 0.000
347 346.53 9255.627 14620.504
0 0.00 0.000 0.000
221 220.78 5896.913 9314.965
0 0.00 0.000 0.000
0 0.00 0.000 0.000
536 533.28 14243.618 22499.703
117 116.51 3111.919 4915.692
0 0.00 0.000 0.000
219 218.54 5837.084 9220.457
204 204.02 5449.263 8607.841
12 11.97 319.712 505.028
13 12.57 335.738 530.343
25 24.87 664.264 1049.294
0 0.00 0.000 0.000
17 16.63 444.178 701.639
0 0.00 0.000 0.000
0 0.00 0.000 0.000
0 0.00 0.000 0.000
D-43
-------
Omni - SVOC Compounds
EpisodeB
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-FluorobiphenyI
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Flnorene-dlO
An(hracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alky (naphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P02-B
XAD/Rinse
01/28/99
ENG1241J)
04/01/99
79.99
81.71
81.77
82.32
86.94
79.49
89.95
89.13
72.16
86.17
82.01
Hours=
XAD
ug
9788
2269
902
15958
2981
1329
0
5953
9154
3092
0
516
712
5141
812
663
463
812
586
1080
0
0
677
195
384
0
0
903
204
0
300
296
0
0
0
0
0
0
0
0
Filter
01/28/99
ENG1227.D
03/31/99
% Recovery
95.19
90.49
103.50
82.53
111.91
97.72
% Recovery
95.84
84.47
87.72
102.82
93.77
166.75 Di
Filter
ug
0
0
0
20
0
0
0
0
14
0
0
0
0
0
0
0
0
0
0
8
0
0
4
0
0
0
0
38
10
0
41
39
27
30
56
17
32
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
ruel (kg)=87.2
TOTAL Total - Blank
ug ug Mg/hr ug/kgCDry)
9788 9770.38 154353.667 203393.185
2269 2268.61 35839.780 47226.394
902 901.50 14242.008 18766.819
15979 15951.58 252005.026 332069.241
2981 2981.01 47094.363 62056.657
1329 1328.66 20990.334 27659.148
0 0.00 0.000 0.000
5953 5943.95 93903.254 123737.145
9168 9147.42 144512.068 190424.824
3092 3092.08 48849.061 64368.837
0 0.00 0.000 0.000
516 515.65 8146.302 10734.454
712 711.59 11241.786 14813.401
5141 5135.69 81134.263 106911.333
812 811.74 12823.969 16898.256
663 662.85 10471.786 13798.765
463 462.94 7313.583 9637.173
812 811.74 12823.969 16898.256
586 585.59 9251.223 12190.418
1088 1088.21 17191.676 22653.622
0 0.00 0.000 0.000
0 0.00 0.000 0.000
681 680.79 10755.204 14172.227
195 195.36 3086.321 4066.873
384 383.95 6065.689 7992.812
0 0.00 0.000 0.000
0 0.00 0.000 0.000
941 937.73 14814.374 19521.031
214 213.54 3373.531 4445.332
0 0.00 0.000 0.000
341 340.98 5386.844 7098.292
335 335.31 5297.269 6980.258
27 26.68 421.494 555.406
30 30.37 479.789 632.222
56 55.90 883.115 1163.689
17 16.95 267.778 352.854
32 32.30 510.279 672.400
0 0.00 0.000 0.000
0 0.00 0.000 0.000
0 0.00 0.000 0.000
D-44
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Uimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno( 1,23-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P02-C
XAD/Rinse
02/19/99
ENG1261.D
04/02/99
75.86
77.52
68.62
74.05
78.34
65.84
87.92
70.02
63.05
71.94
68.59
Hours=
XAD
"g
5068
1243
454
7015
1786
1093
0
2604
3813
0
0
0
0
3557
552
421
249
552
0
721
0
0
331
0
0
0
0
540
0
0
205
211
0
0
0
0
0
0
0
0
Filter
02/19/99
ENG1243.D
04/01/99
% Recovery
85.53
77.70
79.07
84.11
104.55
90.76
% Recovery
87.28
87.21
81.24
89.43
87.42
168 Di
Filter
"g
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
9
32
0
19
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
ruel (kg)=78.9
TOTAL Total - Blank
Mg "g
5068 5050.26
1243 1243.07
454 453.60
7015 6988.43
1786 1786.11
1093 1093.47
0 0.00
2604 2595.59
3813 3792.52
0 0.00
0 0.00
0 0.00
0 0.00
3557 3551.82
552 551.57
421 421.28
249 248.63
552 551.57
0 0.00
721 721.28
0 0.00
0 0.00
331 331.25
0 0.00
0 0.00
0 0.00
0 0.00
540 536.57
0 0.00
0 0.00
205 204.63
211 210.60
8 8.06
9 9.06
32 31.75
0 0.00
19 19.10
0 0.00
0 0.00
0 0.00
91657.870
22560.650
8232.449
126833.986
32416.358
19845.539
0.000
47107.723
68830.972
0.000
0.000
0.000
0.000
64462.474
10010.520
7645.869
4512.420
10010.520
0.000
13090.611
0.000
0.000
6011.902
0.000
0.000
0.000
0.000
9738.283
0.000
0.000
3713.858
3822.209
146.282
164.431
576.235
0.000
346.649
0.000
0.000
0.000
Mg*g(Dry)
127384.606
31354.422
11441.323
176271.796
45051.724
27581.005
0.000
65469.542
95660.157
0.000
0.000
0.000
0.000
89588.891
13912.457
10626.104
6271.288
13912.457
0.000
18193.116
0.000
0.000
8355.243
0.000
0.000
0.000
0.000
13534.107
0.000
0.000
5161.459
5312.043
203.300
228.524
800.842
0.000
481.766
0.000
0.000
0.000
D-45
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-FluorobiphenyI
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkyIbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2»3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P03-A
XAD /Rinse
01/22/99
ENG1208.D
03/30/99
97.03
100.35
88.73
96.67
109.91
101.89
96.67
94.40
83.23
100.92
104.16
Hours=
XAD
Ug
495
132
43
1043
156
175
0
324
538
127
0
25
38
339
47
38
29
47
34
68
0
0
55
0
26
0
0
66
12
0
20
23
0
0
0
0
0
0
0
0
Filter
01/22/99
ENG1193.D
03/26/99
% Recovery
98.12
97.69
94.79
96.15
108.50
101.18
% Recovery
94.92
97.24
99.58
101.32
101.20
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
168.75 Dry Fuel (kg)=27.5
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
495
132
43
1043
156
175
0
324
538
127
0
25
38
339
47
38
29
47
34
68
0
0
55
0
26
0
0
66
12
0
20
23
0
0
0
0
0
0
0
0
Total - Blank
Mg
477.65
131.63
42.52
1016.22
155.93
174.92
0.00
315.58
517.06
127.06
0.00
25.39
37.84
334.11
46.54
37.75
29.28
46.54
34.04
67.78
0.00
0.00
54.92
0.00
26.09
0.00
0.00
62.84
12.32
0.00
19.70
22.55
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
(ig/hr
40612.355
11191.886
3615.278
86404.453
13258.002
14872.633
0.000
26832.298
43963.204
10803.320
0.000
2158.793
3217.359
28407.817
3957.079
3209.707
2489.542
3957.079
2894.263
5763.018
0.000
0.000
4669.592
0.000
2218.311
0.000
0.000
5342.993
1047.512
0.000
1674.999
1917.321
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
jig/kg (Dry)
50279.043
13855.816
4475.798
106970.729
16413.715
18412.667
0.000
33219.010
54427.472
13374.762
0.000
2672.637
3983.165
35169.540
4898.957
3973.692
3082.111
4898.957
3583.165
7134.750
0.000
0.000
5781.064
0.000
2746.321
0.000
0.000
6614.749
1296.845
0.000
2073.688
2373.689
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-46
-------
Omni - SVOC Compounds
Episode B
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-EthyIphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Pbenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P03-B
XAD/Rinse
01/28/99
ENG1211.D
03/30/99
83.73
78.89
90.66
84.28
105.59
101.71
81.05
90.57
76.14
98.17
95.98
Filter
01/28/99
ENG1228.D
03/31/99
% Recovery
80.84
78.53
91.45
85.81
103.32
92.58
% Recovery
77.90
90.50
89.56
95.41
93.08
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
"g
197
43
10
235
51
16
0
53
95
59
0
0
0
172
21
17
16
21
0
52
0
0
24
0
0
0
0
44
8
0
15
15
0
0
0
0
0
0
0
0
168.75 Dry Fuel (kg)=6 1.5
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
197
43
10
235
51
16
0
53
95
59
0
0
0
172
21
17
16
21
0
52
0
0
24
0
0
0
0
44
8
0
15
15
0
0
0
0
0
0
0
0
Total - Blank
Mg
179.37
43.10
9.85
207.89
51.12
16.39
0.00
44.15
74.91
58.72
0.00
0.00
0.00
166.78
20.52
17.45
15.82
20.52
0.00
51.68
0.00
0.00
24.33
0.00
0.00
0.00
0.00
40.57
8.13
0.00
15.21
14.57
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ug/hr
12166.849
2923.517
668.136
14101.390
3467.522
1111.750
0.000
2994.739
5081.221
3983.037
0.000
0.000
0.000
11312.857
1391.892
1183.651
1073.087
1391.892
0.000
3505.507
0.000
0.000
1650.329
0.000
0.000
0.000
0.000
2751.904
551.466
0.000
1031.710
988.298
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
|ig/kg (Dry)
11723.151
2816.903
643.770
13587.143
3341.069
1071.207
0.000
2885.528
4895.920
3837.785
0.000
0.000
0.000
10900.302
1341.133
1140.486
1033.954
1341.133
0.000
3377.669
0.000
0.000
1590.145
0.000
0.000
0.000
0.000
2651.548
531.355
0.000
994.086
952.257
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-47
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobipbenyl
2,4,6-TribromophenoI
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracenc-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-aIkylbenzencs
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthenc
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(lA3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P03-C
XAD/Rinse
02/19/99
ENG126S.D
04/06/99
82.28
82.56
75.50
68.64
77.78
71.11
74.33
72.40
60.46
64.39
66.07
Filter
02/19/99
ENG1247.D
04/01/99
% Recovery
82.81
74.85
81.76
79.50
99.64
99.45
% Recovery
84.25
86.41
83.84
83.25
93.35
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
"g
1382
251
90
2026
322
222
0
488
909
223
0
34
46
660
76
61
51
76
47
90
0
0
80
0
29
0
0
92
16
0
33
33
8
0
0
0
0
0
0
0
168 Dry Fuel (kg)=69.2
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
1382
251
90
2026
322
222
0
488
909
223
0
34
46
660
76
61
51
76
47
90
0
0
80
0
29
0
0
92
16
0
33
33
8
0
0
0
0
0
0
0
Total - Blank
fg
1364.56
250.81
89.64
1999.04
322.02
221.60
0.00
479.69
888.73
222.57
0.00
33.74
45.94
655.65
75.64
61.08
51.19
75.64
46.64
90.33
0.00
0.00
79.71
0.00
28.50
0.00
0.00
88.83
16.25
0.00
32.56
33.40
8.19
0.00
0.00
0.00
0.00
0.00
0.00
• o.oo
fig/hr
71869.072
13209.739
4721.188
105286.063
16960.250
11671.298
0.000
25264.463
46807.909
11722.386
0.000
1777.029
2419.582
34531.979
3983.831
3216.981
2696.091
3983.831
2456.450
4757.529
0.000
0.000
4198.191
0.000
1501.047
0.000
0.000
4678.526
855.860
0.000
1714.880
1759.122
431.353
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(ig/kg (Dry)
71438.458
13130.591
4692.900
104655.226
16858.630
11601.368
0.000
25113.087
46527.453
11652.150
0.000
1766.382
2405.085
34325.076
3959.961
3197.706
2679.937
3959.961
2441.732
4729.023
0.000
0.000
4173.037
0.000
1492.053
0.000
0.000
4650.494
850.732
0.000
1704.605
1748.582
428.769
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-48
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-TerphenyI-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-MethyInaphthalcne
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Flnorene
Heptadecane
Octadccane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P04-A
XAD/Rinse
01/22/99
ENG1208.D
03/31/99
98.69
92.87
94.66
95.27
95.42
93.42
105.68
94.24
81.75
92.32
87.99
Hours=
XAD
Mg
2776
750
272
4448
886
0
0
1340
2140
0
0
0
0
1509
0
155
126
241
0
198
0
0
0
0
0
0
0
227
0
0
0
0
0
0
0
0
0
0
0
0
Filter
01/22/99
ENG1194.D
03/26799
% Recovery
108.68
99.63
121.40
1 14.96
124.83
119.48
% Recovery
98.40
114.74
111.33
127.64
114.54
168.25 Di
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
'uel (kg)=70.7
TOTAL Total - Blank
Mi Hg
2776 2758.62
750 750.23
272 271.97
4448 4420.86
886 885.52
0 0.00
0 0.00
1340 1331.14
2140 2119.43
0 0.00
0 0.00
0 0.00
0 0.00
1509 1504.54
0 0.00
155 155.38
126 126.29
241 240.71
0 0.00
198 198.40
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
227 224.01
0 0.00
0 0.00
0 0.00
0 0.00 ,
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
0 0.00
61517.869
16730.304
6064.994
98586.209
19747.302
0.000
0.000
29684.732
47263.783
0.000
0.000
0.000
0.000
33551.593
0.000
3465.010
2816.296
5367.889
0.000
4424.366
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4995.475
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
82998.082
22572.029
8182.710
133009.585
26642.474
0.000
0.000
40049.759
63766.892
0.000
0.000
0.000
0.000
45266.812
0.000
4674.889
3799.664
7242.197
0.000
5969.224
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6739.747
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-49
-------
Omni - SVOC Compounds
Episode B
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphtbene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadccanc
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l ,2,3-cd)pyrene
Dibcnz(a,h)anthracenc
Benzo(g,h4)perylene
P04-B
XAD/Rinse
01/28/99
ENG1211J)
04/02/99
88.66
79.26
69.84
79.69
84.36
75.30
89.43
79.31
68.61
80.40
76.89
Hours=
XAD
3059
701
250
4769
932
0
0
1574
2399
0
0
0
0
1556
0
154
0
236
0
274
0
0
243
0
0
0
0
296
0
0
0
0
0
0
0
0
0
0
0
0
Filter
01/28/99
ENG1229.D
04/01/99
% Recovery
86.57
80.24
92.32
87.04
105.94
94.13
% Recovery
84.26
85.08
92.16
95.74
96.64
168 Drj
Filter
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
5270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
liter
jig
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
3059
701
250
4769
932
0
0
1574
2399
0
0
0
0
1556
0
154
0
236
0
274
0
0
243
0
0
0
0
296
0
0
0
0
0
0
0
0
0
0
0
0
Total - Blank
Mg
3041.59
701.34
249.66
4741.90
931.88
0.00
0.00
1564.82
2378.34
0.00
0.00
0.00
0.00
1551.53
0.00
153.63
0.00
235.65
0.00
274.18
0.00
0.00
242.94
0.00
0.00
0.00
0.00
293.15
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Hg/hr
62170.137
14335.398
5103.053
96924.494
19047.639
0.000
0.000
31984.940
48613.298
0.000
0.000
0.000
0.000
31713.292
0.000
3140.199
0.000
4816.689
0.000
5604.243
0.000
0.000
4965.697
0.000
0.000
0.000
0.000
5991.990
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Hg/kg (Dry)
66385.058
15307.289
5449.023
103495.641
20339.003
0.000
0.000
34153.409
51909.113
0.000
0.000
0.000
0.000
33863.344
0.000
3353.094
0.000
5143.244
0.000
5984.191
0.000
0.000
5302.354
0.000
0.000
0.000
0.000
6398.226
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-50
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluoropbenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-aIkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alky [naphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1^2,3-cd)pyrene
Dihenz(a,h)anthracene
Benzo(g,h,i)perylene
P04-C
XAD/ Rinse Filter
02/19/99 02/19/99
ENG1265.D ENG1248.D
04/06/99 04/01/99
% Recovery
69.07 87.54
77.78 79.22
57.18 80.23
56.45 87.89
57.39 106.04
53.33 95.62
% Recovery
71.16 88.79
58.26 94.85
47.74 88.07
56.96 91.63
55.04 88.73
Hours=
XAD
Mg
2523
766
262
4235
760
340
0
1470
2260
0
0
0
196
1100
0
130
87
166
0
133
0
0
148
0
0
0
0
166
0
0
0
0
0
0
0
0
0
0
0
0
168
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Dry Fuel (kg)=77
TOTAL
fg
2523
766
262
4235
760
340
0
1470
2260
0
0
0
196
1100
0
130
87
166
0
133
0
0
148
0
0
0
0
166
0
0
0
0
0
0
0
0
0
0
0
0
Total - Blank
Mg
2505.44
765.99
261.86
4208.06
759.51
340.41
0.00
1460.88
2239.14
0.00
0.00
0.00
195.87
1095.58
0.00
129.54
86.82
165.93
0.00
133.47
0.00
0.00
147.56
0.00
0.00
0.00
0.00
163.29
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Mg/hr
46168.404
14115.100
4825.363
77543.031
13995.691
6272.825
0.000
26920.021
41261.223
0.000
0.000
0.000
3609.348
20188.542
0.000
2387.068
1599.855
3057.636
0.000
2459.487
0.000
0.000
2719.127
0.000
0.000
0.000
0.000
3008.988
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
70107.075
21433.887
7327.351
117749.688
21252.564
9525.333
0.000
40878.258
62655.484
0.000
0.000
0.000
5480.823
30656.455
0.000
3624.781
2429.392
4643.044
0.000
3734.750
0.000
0.000
4129.015
0.000
0.000
0.000
0.000
4569.171
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-51
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobipbenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylenc
o-Xylene
Phenol
Benzofuran
C3-alkyIbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aIkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Bcnzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pvrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P05-A
XAD/ Rinse Filter
01/22/99 01/22/99
ENG1209J) ENG1195.D
03/30/99 03/26799
% Recovery
88.19 98.87
90.09 93.32
97.37 99.22
88.69 98.26
110.81 102.92
103.07 100.31
% Recovery
87.55 96.34
95.84 101.61
73.96 101.18
105.18 98.65
94.92 102.80
Hours=
XAD
MS
960
254
88
1919
300
419
0
557
954
290
0
35
54
599
80
62
51
80
63
98
0
0
85
38
38
0
0
112
23
0
44
35
0
0
0
0
0
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
167.25 Dry Fuel (kg)=40.7
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
Mg
960
254
88
1919
300
419
0
557
954
290
0
35
54
599
80
62
51
80
63
98
0
0
85
38
38
0
0
112
23
0
44
35
0
0
0
0
0
0
0
0
Total - Blank
Mg
943.20
253.74
88.06
1892.35
299.79
418.98
0.00
548.09
933.15
290.26
0.00
35.43
54.11
594.12
80.16
61.99
51.18
80.16
63.46
97.78
0.00
0.00
85.46
37.79
38.40
0.00
0.00
109.11
23.09
0.00
43.60
35.39
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ug/hr
480336.452
129220.284
44845.662
963703.017
152671.825
213370.830
0.000
279121.720
475218.364
147818.552
0.000
18043.173
27556.197
302563.076
40822.487
31569.186
26064.058
40822.487
32317.802
49795.694
0.000
0.000
43521.579
19245.032
19555.683
0.000
0.000
55565.639
11758.873
0.000
22203.848
18022.802
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Mg/kg (Dry)
236208.950
63545.016
22053.181
473907.980
75077.482
104926.660
0.000
137260.139
233692.093
72690.850
0.000
8872.862
13550.961
148787.597
20074.756
15524.377
12817.190
20074.756
15892.515
24487.395
0.000
0.000
21402.054
9463.885
9616.649
0.000
0.000
27324.808
5782.511
0.000
10918.904
8862.844
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-52
-------
Omni - SVOC Compounds
EpisodeB
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
NUrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decanc
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indenod J,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P05-B
XAD/ Rinse
01/28/99
ENG1212.D
03/30/99
86.42
81.83
90.34
89.79
104.24
91.66
78.91
90.03
81.98
95.15
89.88
Filter
01/28/99
ENG1230.D
04/01/99
% Recovery
92.53
85.80
96.90
93.19
113.63
107.93
% Recovery
96.76
97.64
94.23
102.56
109.58
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
Mg
289
51
16
438
96
0
0
94
172
0
0
0
0
481
42
35
33
42
14
118
0
0
49
0
29
0
0
99
21
0
43
40
0
0
0
0
0
0
0
0
168 Dry Fuel (kg)=27.5
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
ME
289
51
16
438
96
0
0
94
172
0
0
0
0
481
42
35
33
42
14
118
0
0
49
0
29
0
0
99
21
0
43
40
0
0
0
0
0
0
0
0
Total - Blank
Mg
272.18
51.19
16.01
411.06
95.88
0.00
0.00
84.92
151.73
0.00
0.00
0.00
0.00
475.84
41.63
34.93
33.09
41.63
14.00
117.61
0.00
0.00
49.07
0.00
29.40
0.00
0.00
95.52
20.72
0.00
43.13
40.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
pg/hr
28741.624
5405.554
1690.622
43407.053
10124.722
0.000
0.000
8967.370
16022.362
0.000
0.000
0.000
0.000
50247.682
4396.039
3688.533
3494.233
4396.039
1478.370
12419.363
0.000
0.000
5181.687
0.000
3104.577
0.000
0.000
10086.707
2187.988
0.000
4554.435
4229.194
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
35081.709
6597.960
2063.554
52982.171
12358.124
0.000
0.000
10945.473
19556.719
0.000
0.000
0.000
0.000
61331.768
5365.756
4502.183
4265.022
5365.756
1804.482
15158.938
0.000
0.000
6324.710
0.000
3789.412
0.000
0.000
12311.723
2670.633
0.000
5559.094
5162.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-53
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobeniene-d5
2-FIuorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkyInaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthaIenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P05-C
XAD/ Rinse
02/19/99
ENG1213.D
03/30/99
80.23
82.24
86.20
88.77
105.14
109.92
74.12
89.05
79.31
93.09
102.75
Filter
02/19/99
ENG1249.D
04/01/99
% Recovery
82.19
76.03
82.64
82.84
104.57
103.04
% Recovery
82.75
90.24
90.36
89.97
102.18
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
Mg
270
46
14
434
84
48
0
77
130
117
0
0
0
400
34
28
29
34
0
91
0
0
36
0
22
0
0
82
16
0
31
31
0
0
0
0
0
0
0
0
168
Filter
fg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Dry Fuel (kg)=32
TOTAL
Mg
270
46
14
434
84
48
0
77
130
117
0
0
0
400
34
28
29
34
0
91
0
0
36
0
22
0
0
82
16
0
31
31
0
. 0
0
0
0
0
0
0
Total - Blank
"g
252.85
45.79
13.91
407.37
84.11
47.80
0.00
68.02
109.27
116.62
0.00
0.00
0.00
394.97
33.72
27.98
29.31
33.72
0.00
90.74
0.00
0.00
35.88
0.00
22.34
0.00
0.00
78.40
16.15
0.00
30.69
30.65
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ug/hr
33114.559
5996.898
1821.726
53351.306
11015.486
6260.138
0.000
8908.255
14310.571
15273.165
0.000
0.000
0.000
51727.337
4416.148
3664.407
3838.591
4416.148
0.000
11883.785
0.000
0.000
4699.032
0.000
2925.763
0.000
0.000
10267.674
2115.088
0.000
4019.323
4014.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
34919.720
6323.804
1921.033
56259.625
11615.968
6601.395
0.000
9393.867
15090.677
16105.745
0.000
0.000
0.000
54547.130
4656.883
3864.164
4047.843
4656.883
0.000
12531.601
0.000
0.000
4955.189
0.000
3085.254
0.000
0.000
10827.392
2230.387
0.000
4238.427
4232.903
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-54
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Taluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-aIkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-DimethyIphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIky (naphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-<:d)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P06-A
XAD/Rinse
01/22/99
ENG1217.D
03/31/99
83.78
77.14
75.58
81.30
85.40
79.07
92.80
86.52
75.04
81.20
78.43
Hours=
XAD
Mg
9477
1743
658
13136
3209
1008
0
3885
5364
853
0
305
311
6925
844
722
484
844
325
1360
0
113
872
0
381
0
0
1074
200
0
361
331
0
0
0
0
0
0
0
0
Filter
01/22/99
ENG1196.D
03/26/99
% Recovery
95.94
93.60
110.00
93.56
116.98
108.48
% Recovery
97.62
99.50
99.67
108.51
104.41
168 Dry
Filter
Mg
0
0
0
85
0
0
0
10
31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
0
0
0
35
7
0
47
50
40
45
71
21
39
0
0
0
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
TOTAL
Mg
9477
1743
658
13221
3209
1008
0
3895
5395
853
0
305
311
6925
844
722
484
844
325
1360
0
113
872
9
381
0
0
1110
207
0
408
382
40
45
71
21
39
0
0
0
Total - Blank
Mg
9459.94
1742.76
658.22
13193.59
3209.25
1008.16
0.00
3886.44
5374.81
853.36
0.00
305.15
310.54
6920.65
843.90
722.48
484.27
843.90
325.22
1359.98
0.00
112.59
871.82
9.39
381.20
0.00
0.00
1106.45
207.33
0.00
408.05
381.85
40.44
45.42
71.49
20.52
38.72
0.00
0.00
0.00
Hg/hr
217070.822
39989.931
15103.728
302744.354
73640.481
23133.563
0.000
89179.501
123332.117
19581.473
0.000
7002.070
7125.751
158803.458
19364.400
16578.258
11112.215
19364.400
7462.603
31206.538
0.000
2583.526
20005.062
215.466
8747.138
0.000
0.000
25388.957
4757.461
0.000
9363.246
8762.053
927.949
1042.222
1640.433
470.859
888.482
0.000
0.000
0.000
Mg/kg (Dry)
147039.490
27088.390
10230.967
205073.049
49882.608
15670.219
0.000
60408.433
83542.741
13264.103
0.000
4743.064
4826.843
107570.328
13117.063
11229.785
7527.195
13117.063
5055.020
21138.693
0.000
1750.030
13551.034
145.952
5925.138
0.000
0.000
17197.978
3222.610
0.000
6342.478
5935.242
628.574
705.981
1111.197
318.950
601.840
0.000
0.000
0.000
D-55
-------
Omni - SVOC Compounds
Episode B
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-FluorobiphenyI
2,4,6-Tribromophenol
p-Terphenyl-dl4
Tolaene-d8
Biphenyl-dlO
Fluorene-dlO
Anthraccne-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnapbthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthaIenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P06-B
XAD/ Rinse
01/28/99
ENG1257J)
04/02/99
90.29
83.33
85.38
76.36
89.73
79.24
85.84
82.81
72.23
96.06
74.90
Filter
01/28/99
ENG1231.D
04/01/99
% Recovery
93.52
87.09
89.17
87.37
118.21
97.44
% Recovery
85.95
94.43
96.33
92.42
100.40
TOTAL
8270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
Hours=
XAD
fig
9025
2169
836
15194
3578
2738
0
4756
7122
1033
0
383
473
6539
1016
838
520
1016
605
1186
0
0
822
0
391
0
0
1148
242
0
404
334
0
0
0
0
0
0
0
0
168 Dry Fuel (kg)= 182
Filter
Mg
0
0
0
7
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
16
5
0
44
45
34
39
70
18
38
0
0
0
TOTAL
Mg
9025
2169
836
15201
3578
2738
0
4756
7122
1033
0
383
473
6539
1016
838
520
1016
605
1186
0
0
822
0
391
0
0
1164
248
0
448
379
34
39
70
18
38
0
0
0
Total - Blank
Cg
9007.47
2169.15
835.85
15173.85
3578.36
2738.28
0.00
4747.15
7101.72
1032.54
0.00
383.09
473.28
6534.66
1016.42
838.41
519.81
1016.42
604.55
1185.74
0.00
0.00
821.75
0.00
391.03
0.00
0.00
1161.21
247.92
0.00
448.14
379.40
33.53
39.12
70.06
17.63
37.86
0.00
0.00
0.00
Hg/hr
176415.014
42483.697
16370.467
297186.109
70083.656
53630.343
0.000
92974.890
139090.114
20222.722
0.000
7502.976
9269.384
127984.010
19907.005
16420.606
10180.693
19907.005
11840.361
23223.207
0.000
0.000
16094.313
0.000
7658.484
0.000
0.000
22742.777
4855.615
0.000
8777.007
7430.705
656.699
766.181
1372.154
345.291
741.504
0.000
0.000
0.000
)ig/kg (Dry)
137780.463
33179.849
12785.366
232102.920
54735.469
41885.400
0.000
72613.567
108629.645
15793.984
0.000
5859.838
7239.407
99955.757
15547.409
12824.524
7951.141
15547.409
9247.345
18137.369
0.000
0.000
12569.689
0.000
5981.290
0.000
0.000
17762.152
3792.245
0.000
6854.859
5803.395
512.883
598.389
1071.655
269.673
579.116
0.000
0.000
0.000
D-56
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Antbracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methy (naphthalene
Biphenyl
Tetradecane
C2-alkyInaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3- alky (naphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P06-C
XAD/ Rinse
02/19/99
ENG1267.D
04/06/99
Filter
02/19/99
ENG1250.D
04/01/99
TOTAL
8270 Surrogate Compounds
72.15
83.46
59.85
56.61
53.80
48.41
% Recovery
91.47
88.30
83.78
84.80
120.48
97.78
Lab Surrogate Compounds
77.56
57.07
47.92
53.58
47.00
% Recovery
89.54
90.00
92.05
97.60
93.46
Target Compounds
Hours=
XAD
Mg
13516
3023
1060
20752
4580
2994
0
6644
9952
2456
0
415
541
7925
918
690
502
918
636
1264
0
0
880
320
363
0
0
1311
199
0
362
277
0
0
0
0
0
0
0
0
166.75 Dry Fuel (kg)=174.9
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13
0
0
41
42
45
50
91
29
50
0
0
0
TOTAL
Mg
13516
3023
1060
20752
4580
2994
0
6644
9952
2456
0
415
541
7925
918
690
502
918
636
1264
0
0
880
320
363
0
0
1323
199
0
403
319
45
50
91
29
50
0
0
0
Total - Blank
Mg
13498.92
3023.23
1059.64
20725.20
4579.94
2994.39
0.00
6635.07
9931.47
2456.36
0.00
415.15
541.24
7920.52
917.96
689.70
502.04
917.96
635.53
1264.37
0.00
0.00
880.27
319.78
362.81
0.00
0.00
1320.17
198.99
0.00
402.96
318.65
45.09
49.90
91.05
29.12
49.83
0.00
0.00
0.00
ug/hr
171853.028
38488.355
13490.142
263849.877
58306.632
38121.197
0.000
84470.230
126436.277
31271.606
0.000
5285.222
6890.457
100835.129
11686.432
8780.483
6391.407
11686.432
8090.851
16096.533
0.000
0.000
11206.605
4071.078
4618.888
0.000
0.000
16806.916
2533.316
0.000
5130.032
4056.692
574.035
635.271
1159.146
370.723
634.379
0.000
0.000
0.000
Hg/kg (Dry)
150257.121
33651.717
11794.903
230693.187
50979.530
33330.698
0.000
73855.280
110547.665
27341.860
0.000
4621.054
6024.568
88163.685
10217.856
7677.084
5588.231
10217.856
7074.115
14073.763
0.000
0.000
9798.327
3559.486
4038.455
0.000
0.000
14694.875
2214.967
0.000
4485.367
3546.908
501.899
555.439
1013.482
324.136
554.660
0.000
0.000
0.000
D-57
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alky (benzenes
Decane
o-Cresol
m,p-CresoI
C4-alkylbenzenes
Undecane
2-Ethylpbenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1 -Methylnaphthalene
Biphenyl
Tetradecane
C2-alky (naphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aIkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluorantbene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P07-A
XAD only*
01/22/99
ENG1219.D
03/31/99
Filter
01/22/99
ENG1197.D
03/26799
TOTAL
•Rinse was combined with P08-A XAD
8270 Surrogate Compounds
89.24
98.75
92.68
87.52
94.54
83.99
% Recovery
110.12
107.67
116.80
75.74
110.01
121.18
Lab Surrogate Compounds
99.53
91.51
81.04
92.71
84.59
% Recovery
96.91
74.80
89.58
109.61
117.09
Target Compounds
Hours=
XAD
Mi
8728
2681
1037
17405
2992
4443
0
7126
10570
6924
0
614
0
904
4240
901
655
452
721
909
0
0
774
292
388
0
0
984
213
0
340
300
0
0
0
0
0
0
0
0
168 Dry Fuel (kg)=242.2
Filter
f»g
0
0
0
138
0
0
0
42
81
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
120
23
0
151
165
82
99
149
35
72
0
0
0
TOTAL
"g
8728
2681
1037
17543
2992
4443
0
7168
10652
6924
0
614
0
904
4240
901
655
452
721
909
0
0
774
292
388
0
0
1104
236
0
491
465
82
99
149
35
72
0
0
0
Total - Blank
Mg
8711.03
2680.77
1036.83
17516.00
2991.71
4442.85
0.00
7159.46
10631.09
6924.10
0.00
613.69
0.00
898.70
4239.66
901.10
655.22
451.75
721.18
908.51
0.00
0.00
774.31
292.47
387.69
0.00
0.00
1101.04
236.23
0.00
491.01
465.09
81.51
98.99
148.51
34.51
72.44
0.00
0.00
0.00
ug/hr
141556.370
43563.169
16848.741
284639.289
48616.020
72197.400
0.000
116342.978
172757.816
112518.320
0.000
9972.613
0.000
14604.095
68895.513
14643.096
10647.485
7341.048
11719.352
14763.510
0.000
0.000
12582.727
4752.709
6300.057
0.000
0.000
17892.170
3838.795
0.000
7979.033
7557.826
1324.557
1608.612
2413.324
560.796
1177.168
0.000
0.000
0.000
Hg/kg (Dry)
98276.987
30244.184
11697.414
197613.795
33752.179
50123.798
0.000
80772.326
119938.916
78117.018
0.000
6923.590
0.000
10139.045
47831.429
10166.122
7392.128
5096.599
8136.282
10249.721
0.000
0.000
8735.690
3299.618
4373.881
0.000
0.000
12421.825
2665.124
0.000
5539.527
5247.100
919.588
1116.795
1675.475
389.338
817.261
0.000
0.000
0.000
D-58
-------
Omni - SVOC Compounds
Episode B
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-EthylphenoI
2,3-DimethyIphenol
Naphthalene
2-Methylnaphthalene
l-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C 3- alky [naphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluorantbene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P07-B
XAD/ Rinse Filter* TOTAL
01/28/99 01/28/99
ENG1259.D ENG1232.D
04/02/99 04/01/99
* - This sample evaporated almost 75% faster than the rest of the other samples. There is a possibility that
the sample surrogate recoveries are off due to premature loss of sample.
8270 Surrogate Compounds
% Recovery
75.99 29.43
86.01 27.98
67.48 29.23
75.65 27.52
67.30 34.68
70.57 30.31
Lab Surrogate Compounds
% Recovery
97.62 30.73
86.58 26.80
72.04 27.84
92.47 28.86
67.64 28.96
Target Compounds
Hours= 168 Dry Fuel (kg)=252.4
XAD
"g
16662
5848
1747
20973
6975
5618
0
11242
14554
8090
0
886
1397
8529
1596
1213
855
1596
1428
1653
0
0
1426
0
623
0
0
1585
338
0
449
373
0
0
0
0
0
0
0
0
Filter
Mg
0
0
0
43
0
0
0
16
32
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
24
6
0
37
36
20
24
33
0
0
0
0
0
TOTAL
Mg
16662
5848
1747
21016
6975
5618
0
11258
14586
8090
0
886
1397
8529
1596
1213
855
1596
1428
1653
0
0
1426
0
623
0
0
1609
345
0
485
409
20
24
33
0
0
0
0
0
Total - Blank
Mg
16644.44
5848.39
1746.81
20989.25
6974.69
5617.81
0.00
11249.11
14565.85
8090.32
0.00
885.59
1396.61
8524.11
1595.82
1213.45
854.80
1595.82
1427.86
1652.71
0.00
0.00
1425.79
0.00
622.97
0.00
0.00
1606.04
344.85
0.00
485.13
409.18
20.43
24.01
33.37
0.00
0.00
0.00
0.00
0.00
Mg/hr
281710.782
98985.278
29565.141
355247.640
118048.151
95082.661
0.000
190393.643
246530.192
136930.433
0.000
14988.804
23637.929
144272.423
27009.602
20537.906
14467.677
27009.602
24166.842
27972.478
0.000
0.000
24131.807
0.000
10543.903
0.000
0.000
27182.578
5836.662
0.000
8210.931
6925.461
345.782
406.374
564.795
0.000
0.000
0.000
0.000
0.000
Hg/kg (Dry)
187706.512
65954.811
19699.528
236704.804
78656.580
63354.461
0.000
126861.054
164265.358
91238.020
0.000
9987.179
15750.172
96130.056
17996.749
13684.598
9639.947
17996.749
16102.592
18638.322
0.000
0.000
16079.247
0.000
7025.501
0.000
0.000
18112.004
3889.022
0.000
5471.020
4614.499
230.398
270.771
376.328
0.000
0.000
0.000
0.000
0.000
D-59
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-FIuorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-dS
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xy!ene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1 -Methy [naphthalene
Biphenyl
Tetradecane
C2-alkylnaphthaJenes
Acenaphthylenc
Penladecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)an thracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P07-C
XAD/ Rinse
02/19/99
ENG1268.D
04/06/99
77.62
89.45
47.64
53.66
46.02
52.56
91.22
60.06
51.76
52.69
57.04
Hours=
XAD
Mg
18321
6950
2124
34148
7447
6815
0
14790
20427
17124
0
860
1296
7065
1216
907
538
1216
1072
1028
0
0
798
530
371
0
0
965
185
0
242
222
0
0
0
0
0
0
0
0
Filter
02/19/99
ENG1251.D
04/02/99
% Recovery
85.97
85.10
91.94
82.43
140.18
127.89
% Recovery
81.62
86.80
95.98
90.95
125.83
168 Dr>
Filter
t»g
0
0
0
347
0
0
0
99
224
0
0
0
0
10 .
0
0
0
0
0
0
0
0
0
0
0
0
0
140
28
0
154
194
78
96
142
0
0
0
0
0
TOTAL
8270 Surrogate Compounds
Lot Surrogate Compounds
Target Compounds
icl (kg)=325.4
TOTAL Total - Blank
ug ug ug/hr Mg/kg(Dry)
18321 18303.56 349421.313 180573.003
6950 6949.93 132676.576 68564.243
2124 2124.49 40557.251 20959.067
34495 34467.62 657998.829 340038.858
7447 7447.20 142169.633 73470.039
6815 6814.92 130099.188 67232.307
0 0.00 0.000 0.000
14889 14879.91 284062.646 146797.127
20651 20630.68 393846.842 203531.107
17124 17124.48 326912.267 168940.838
0 0.00 0.000 0.000
860 860.35 16424.380 8487.747
1296 1296.23 24745.481 12787.903
7074 7069.26 134954.627 69741.488
1216 1216.34 23220.353 11999.751
907 907.07 17316.281 8948.661
538 537.72 10265.261 5304.854
1216 1216.34 23220.353 11999.751
1072 1072.44 20473.252 10580.112
1028 1028.13 19627.359 10142.973
0 0.00 0.000 0.000
0 0.00 0.000 0.000
798 798.37 15241.160 7876.286
530 530.09 10119.602 5229.581
371 370.95 7081.564 3659.592
0 0.00 0.000 0.000
0 0.00 0.000 0.000
1105 1102.13 21040.044 10873.017
213 213.10 4068.153 2102.329
0 0.00 0.000 0.000
395 395.20 7544.505 3898.829
416 416.14 7944.257 4105.412
78 78.21 1493.056 771.577
96 95.98 1832.292 946.887
142 142.31 2716.747 1403.953
0 0.00 0.000 0.000
0 0.00 0.000 0.000
0 0.00 0.000 0.000
0 0.00 0.000 0.000
0 0.00 0.000 0.000
D-60
-------
Omni - SVOC Compounds
Episode A
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P08-A
XAD/ Rinse*
01722/99
ENG1220.D
03/31/99
Filter
01/22/99
ENG1222J>
03/31/99
TOTAL
*P07-A Rinse was combined with P08-A XAD:
sample PB1-A
87.83
90.79
78.05
82.91
84.98
80.00
109.88
97.32
80.78
86.10
86.24
Hours=
XAD
"g
22683
6549
2177
25887
7958
9102
0
11613
15831
14186
0
859
1243
9949
1570
1175
896
1570
1478
1495
0
0
1300
599
540
0
0
1039
195
0
0
0
0
0
0
0
0
0
0
0
% Recovery
96.16
87.59
103.81
85.30
108.95
97.11
% Recovery
90.59
93.47
91.11
95.87
92.94
P08-A Rinse was combined with FBI
$270 Surrogate Compounds
Lab Surrogate Compounds
Target Compounds
133.25 Dry Fuel (kg)=169.S
Filter TOTAL
"g
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
7
13
17
33
0
21
0
0
0
Mg
22683
6549
2177
25887
7958
9102
0
11613
15831
14186
0
859
1243
9949
1570
1175
896
1570
1478
1495
0
0
1300
599
540
0
0
1039
195
0
4
7
13
17
33
0
21
0
0
0
!
Total - Blank
"g
22.67
6.55
2.18
25.86
7.96
9.10
0.00
11.60
15.81
14.19
0.00
0.86
1.24
9.94
1.57
1.17
0.90
1.57
1.48
1.49
0.00
0.00
1.30
0.60
0.54
0.00
0.00
1.04
0.19
0.00
0.00
0.01
0.01
0.02
0.03
0.00
0.02
0.00
0.00
0.00
ug/hr
645.992
186.645
62.120
736.893
226.824
259.309
0.000
330.547
450.513
404.351
0.000
24.506
35.334
283.245
44.738
33.340
25.646
44.738
42.173
42.458
0.000
0.000
37.044
17.097
15.388
0.000
0.000
29.635
5.414
0.000
0.000
0.285
0.285
0.570
0.855
0.000
0.570
0.000
0.000
0.000
-A XAD, see
jig/kg (Dry)
498.952
144.161
47.980
569.162
175.195
200.285
0.000
255.309
347.968
312.313
0.000
18.928
27.292
218.773
34.555
25.751
19.808
34.555
32.574
32.794
0.000
0.000
28.612
13.206
11.885
0.000
0.000
22.890
4.182
0.000
0.000
0.220
0.220
0.440
0.660
0.000
0.440
0.000
0.000
0.000
D-61
-------
Omni - SVOC Compounds
Episode B
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-MethylnaphthaIene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alky Inap hthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-aIkylnaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzofbjfluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
P08-B
XAD/ Rinse Filter TOTAL
01/28/99 01/28/99
ENG1260.D ENG1233.D
04/02/99 04/01/99
8270 Surrogate Compounds
% Recovery
79.75 93.94
75.61 89.76
65.03 90.34
77.65 93.92
74.69 123.56
74.05 94.53
Lab Surrogate Compounds
% Recovery
86.49 89.21
78.13 94.44
68.51 98.94
75.09 89.67
73.20 92.59
Target Compounds
Hours=
XAD
Mg
2160
590
226
3829
738
0
0
1433
2074
0
0
0
0
828
191
0
0
191
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
97.75
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Dry Fuel (kg)=61
TOTAL
Mg
2160
590
226
3829
738
0
0
1433
2074
0
0
0
0
828
191
0
0
191
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Total - Blank
Mg
2143.05
589.83
226.07
3801.60
737.62
0.00
0.00
1424.54
2053.35
0.00
0.00
0.00
0.00
822.87
190.71
0.00
0.00
190.71
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-3.18
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ug/hr
254382.642
70013.538
26834.784
451254.544
87556.391
0.000
0.000
169094.631
243735.143
0.000
0.000
0.000
0.000
97675.670
22637.509
0.000
0.000
22637.509
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-377.470
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ug/kg (Dry)
156639.688
43111.821
16523.896
277866.330
53914.079
0.000
0.000
104122.396
150083.341
0.000
0.000
0.000
0.000
60145.167
13939.364
0.000
0.000
13939.364
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-232.432
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
D-62
-------
Omni - SVOC Compounds
Episode C
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Taluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-aIkylbenzenes
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzenes
Undecane
2-Ethylphenol
23-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIkyInaphthalenes
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkyInaphthalenes
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
XAD/Rinse
02/19/99
ENG1271J)
04/06/99
82.43
99.89
76.23
60.90
68.65
53.20
90.15
62.79
58.61
55.57
P08-C
Filter TOTAL
02/19/99
ENG12S2.D
04/02/99
8270 Surrogate Compounds
% Recovery
87.83
82.84
88.62
78.33
119.35
91.81
Lab Surrogate Compounds
% Recovery
80.99
84.00
86.63
88.86
54.09 83.42
Target Compounds
XAD Filter TOTAL
MS Mg "g
7073 0 7073
2439 0 2439
912 0 912
13715 0 13715
2144 0 2144
1437 0 1437
0 00
5024 0 5024
7133 0 7133
1119 0 1119
0 00
402 0 402
604 0 ' 604
2239 0 2239
498 0 498
354 0 354
245 0 245
498 0 498
611 0 611
308 0 308
0 00
0 00
310 0 310
988 0 988
0 00
0 00
0 00
299 0 299
62 0 62
0 00
75 0 75
73 0 73
0 66
0 77
0 00
0 00
0 00
0 00
0 00
0 00
Total - Blank
Mg
Lost Sample
D-63
-------
Blank Data - Portland
D-64
-------
Omni - Blanks
Episode A, B, and C of P
Sample Name: DCM 076 MeC12 Blank
Sample Type: Blank
Sample Date: 02/22/99
File Name: ENG1185.D
Analysis Date: 03/26/99
8270 Surrogate Compounds
% Recovery
2-Fluorophenol NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-Fluorobiphenyl NA
2,4,6-Tribromopbenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-dS NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
Mg
Toluene 0
m,p-Xylene 0
o-Xylene 0
Phenol 0
Benzofuran 0
C3-alkylbenzene 0
Decane 0
o-Cresol 0
m,p-Cresol 0
C4-alkylbenzene 0
Undecane 0
2-Ethylphenol 0
2,3-Dimethylphenol 0
Naphthalene 0
2-Methylnaphthalene 0
1-Methylnaphthalene 0
Biphenyl 0
Tetradecane 0
C2-alkylnaphthalene 0
Acenaphthylene 0
Pentadecane 0
Acenaphthene 0
Dibenzofuran 0
C3-alkylnaphthaIene 0
Fluorene 0
Heptadecane 0
Octadecane 0
Phenanthrene 0
Anthracene 0
Carbazole 0
Fluoranthene 0
Pyrene 0
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
D-65
-------
Omni -Blanks
Episode A, B, and C of P
Sample Name: SDM 026 MeOH/MeCI2 Blank
Sample Type: Blank
Sample Date: 02/09/99
File Name: ENG1189.D
Analysis Date: 03/26799
8270 Surrogate Compounds
% Recovery
2-Fluorophenol NA
Phenol-d6 NA
Nitrobenzene-d5 NA
2-Fluorobiphenyl NA
2,4,6-Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
Mg
Toluene 0
m,p-Xylene 0
o-Xylene 0
Phenol 0
Benzofuran 0
C3-alkylbenzene 0
Decane 0
o-Cresol 0
m,p-Cresol 0
C4-alkylbenzene 0
Undecane 0
2-Ethylphenol 0
2,3-Dimethylphenol 0
Naphthalene 0
2-Methylnaphthalene 0
1-Methylnaphthalene 0
Biphenyl 0
Tetradecane 0
C2-alkylnaphthalene 0
Acenaphthylene 0
Pentadecane 0
Acenaphthene 0
Dibenzofuran 0
C3-alkylnaphthalene 0
Fluorene 0
Heptadecane 0
Octadecane 0
Phenanthrene 0
Anthracene 0
Carbazole 0
Fluoranthene 0
Pyrene 0
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluorantbene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,23-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
D-66
-------
Omni -Blanks
Episode A, B, and C of P
Sample Name: SDM 028 MeOH/MeCI2 Blank
Sample Type: Blank
Sample Date: 02/22/99
File Name: ENG1190.D
Analysis Date: 03/26/99
8270 Surrogate Compounds
% Recovery
I-Fluorophenol NA
Phenol-d6 NA
Nitrobenzene-dS NA
2-Flnorobiphenyl NA
2,4,6-Tribromophenol NA
p-Terphenyl-d!4 NA
Lab Surrogate Compounds
% Recovery
Toluene-d8 NA
Biphenyl-dlO NA
Fluorene-dlO NA
Anthracene-dlO NA
Pyrene-dlO NA
Target Compounds
Blank
Mg
Toluene 0
m,p-Xylene 0
o-Xylene 0
Phenol 0
Benzofuran 0
C3-alkylbenzene 0
Decane 0
o-Cresol 0
m,p-Cresol 0
C4-alkylbenzene 0
Undecane 0
2-EthyIphenol 0
2,3-Dimethylphenol 0
Naphthalene 0
2-Methylnaphthalene 0
1-Methylnaphthalene 0
Biphenyl 0
Tetradecane 0
C2-alkylnaphthalene 0
Acenaphthylene 0
Pentadecane 0
Acenaphthene 0
Dibenzofuran 0
C3-alkylnaphthalene 0
Fluorene 0
Heptadecane 0
Octadecane 0
Phenanthrene 0
Anthracene 0
Carbazole 0
Fluoranthene 0
Pyrene 0
Benzo(a)anthracene 0
Chrysene 0
Benzo(b)fluoranthene 0
Benzo(k)fluoranthene 0
Benzo(a)pyrene 0
Indeno(l,2,3-cd)pyrene 0
Dibenz(a,h)anthracene 0
Benzo(g,h,i)perylene 0
D-67
-------
Omni - Blanks
Episode A, B, and C of P
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyi-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzomran
C3-alkylbenzene
Decane
o-Cresol
m,p-Cresol
C4-alkyIbenzene
Undecane
2-Ethylphenol
2.3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-aIky (naphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzofa)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Rinse
Not used dne to analytical error.
PB1-A
XAD/Rinse* Filter
TOTAL
ENG1179.D ENG1253.D ENG1182.D
03/25/99 04/02/99
•PB1-B XAD cc
8270 Surrogate Compounds
% Recovery % Recovery 1
0.00 77.17
0.00 75.69
0.00 83.37
0.00 70.38
0.00 96.01
0.00 81.73
Lab Surrogate Compounds
% Recovery % Recovery ",
0.00 77.93
0.00 76.93
0.00 67.11
0.00 81.35
0.00 77.03
Target Compounds
Rinse XAD/Rinse
f»g Mg
0 18
0 0
0 0
0 931
0 0
0 0
0 0
0 357
0 967
0 249
0 0
0 46
0 123
0 0
0 0
0 0
0 0
0 0
0 249
0 0
0 0
0 0
0 0
0 203
0 83
0 0
0 0
0 376
0 77
0 0
0 175
0 156
0 30
0 33
0 0
0 0
0 0
0 0
0 0
0 0
03/25/99
unbined wit
fc Recovery
89.32
88.18
104.02
101.12
109.70
116.52
fc Recovery
86.81
108.88
101.67
114.56
111.62
Filter
"g
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
"g
18
0
0
931
0
0
0
357
967
249
0
46
123
0
0
0
0
0
249
0
0
0
0
203
83
0
0
376
77
0
175
156
30
33
0
0
0
0
0
0
D-68
-------
Omni - Blanks
Episode A, B, and C of P
Sample Name: PB2-B
Sample Type: XAD/Rinse Filter TOTAL
Sample Date:
File Name: ENG1180.D ENG1183.D
Analysis Date: 03/25/99 03/25/99
8270 Surrogate Compounds
% Recovery % Recovery
2-Fluorophenol 85.88 87.15
Phenol-d6 84.84 83.04
Nitrobenzene-d5 98.14 105.85
2-Fluorobiphenyl 94.14 103.41
2,4,6-Tribromophenol 103.12 107.22
p-Terphenyl-dl4 100.76 113.94
Lab Surrogate Compounds
% Recovery % Recovery
Toluene-d8 84.74 86.74
Biphenyl-dlO 101.37 107.01
Fluorene-dlO 82.16 102.79
Anthracene-dIO 97.26 103.48
Pyrene-dlO 94.99 • 106.65
Target Compounds
XAD/Rinse Filter
Mg Mg Mg
Toluene 35 0 35
m,p-Xylene 00 0
o-Xylene 00 0
Phenol 54 0 54
Benzofuran 00 0
C3-alkylbenzene 00 0
Decane 00 0
o-Cresol 18 0 18
m,p-Cresol 41 0 41
C4-alkylbenzene 00 0
Undecane 00 0
2-Ethylphenol 00 0
2,3-Dimethylphenol 00 0
Naphthalene 10 0 10
2-Melhylnaphthalene 00 0
1-Methylnaphthalene 00 0
Biphenyl 00 0
Tetradecane 00 0
C2-alkylnaphthalene 00 0
Acenaphthylene 00 0
Pentadecane 00 0
Acenaphthene 00 0
Dibenzofuran 00 0
C3-alkylnaphthalene 00 0
Fluorene 00 0
Heptadecane 00 0
Octadecane 00 0
Phenanthrene 00 0
Anthracene 00 0
Carbazole 00 0
Fluoranthene 00 0
Pyrene 00 0
Benzo(a)anthracene 00 0
Chrysene 00 0
Benzo(b)fluoranthene 00 0
Benzo(k)fluoranthene 00 0
Benzo(a)pyrene 00 0
Indeno(l,2,3-cd)pyrene 00 0
Dibenz(a,h)anthracene 00 0
Benzo(g,h,i)perylene 00 0
D-69
-------
Omni - Blanks
Episode A, B, and C of P
Sample Name:
Sample Type:
Sample Date:
File Name:
Analysis Date:
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d!4
Toluene-d8
Biphenyl-dlO
Fluorene-dlO
Anthracene-dlO
Pyrene-dlO
Toluene
m,p-Xylene
o-Xylene
Phenol
Benzofuran
C3-alkylbenzene
Decane
o-Cresol
m,p-Cresol
C4-alkylbenzene
Undecane
2-Ethylphenol
2,3-Dimethylphenol
Naphthalene
2-Methylnaphthalene
1-Methylnaphthalene
Biphenyl
Tetradecane
C2-alkylnaphthalene
Acenaphthylene
Pentadecane
Acenaphthene
Dibenzofuran
C3-alkylnaphthalene
Fluorene
Heptadecane
Octadecane
Phenanthrene
Anthracene
Carbazole
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indenod J,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
PB1-C
XAD/Rinse
ENG1181.D
03/25/99
% Recovery
80.58
78.66
97.43
90.29
104.87
97.96
% Recovery
78.24
92.07
78.92
93.84
96.83
XAD/Rinse
Hg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
Filter
ENG1184.D
03/25/99
% Recovery
92.61
90.81
99.61
102.87
106.30
116.30
% Recovery
94.74
106.66
99.81
109.90
114.26
Filter
Mg
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
TOTAL
D-70
-------
Omni - Blanks
Episode A, B, and C of P
D-71
-------
------- |